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Sample records for catalysts technical progress

  1. Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report 10, July 1, 1995--September 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    McCormick, R.L.

    1995-12-07

    This document is the tenth quarterly technical progress report under Contract No. DE-AC22-92PC92110 {open_quotes}Development of Vanadium-Phosphate Catalysts for Methanol Production by Selective Oxidation of Methane{close_quotes}. Activities focused on testing of additional modified and promoted catalysts and characterization of these materials. Attempts at improving the sensitivity of our GC based analytical systems were also made with some success. Methanol oxidation studies were initiated. These results are reported. Specific accomplishments include: (1) Methane oxidation testing of a suite of catalysts promoted with most of the first row transition metals was completed. Several of these materials produced low, difficult to quantify yields of formaldehyde. (2) Characterization of these materials by XRD and FTIR was performed with the goal of correlating activity and selectivity with catalyst properties. (3) We began to characterize catalysts prepared via modified synthesis methods designed to enhance acidity using TGA measurements of acetonitrile chemisorption and methanol dehydration to dimethyl ether as a test reaction. (4) A catalyst prepared in the presence of naphthalene methanol as a structural disrupter was tested for activity in methane oxidation. It was found that this material produced low yields of formaldehyde which were difficult to quantify. (5) Preparation of catalysts with no Bronsted acid sites. This was accomplished by replacement of exchangeable protons with potassium, and (6) Methanol oxidation studies were initiated to provide an indication of catalyst activity for decomposition of this desired product and as a method of characterizing the catalyst surface.

  2. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, April--June 1992

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Gutterman, C. [Foster Wheeler Development Corp., Livingston, NJ (United States); Chander, S. [Pennsylvania State Univ., University Park, PA (United States)

    1992-08-26

    Research in this project centers upon developing a new approach to the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates all aspects of the coal liquefaction process including coal selection, pretreatment, coal swelling with catalyst impregnation, coal liquefaction experimentation, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. The project is being carried out under contract to the United States Department of Energy. On May 28, 1992, the Department of Energy authorized starting the experimental aspects of this projects; therefore, experimentation at Amoco started late in this quarterly report period. Research contracts with Auburn University, Pennsylvania State University, and Foster Wheeler Development Corporation were signed during June, 1992, so their work was just getting underway. Their work will be summarized in future quarterly reports. A set of coal samples were sent to Hazen Research for beneficiation. The samples were received and have been analyzed. The literature search covering coal swelling has been up-dated, and preliminary coal swelling experiments were carried out. Further swelling experimentation is underway. An up-date of the literature on the liquefaction of coal using dispersed catalysts is nearing completion; it will be included in the next quarterly report.

  3. Technology development for cobalt F-T catalysts. Quarterly technical progress report No. 4, July 1, 1993--September 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Singleton, A.H.

    1993-12-14

    The goal of this project is the development of a commercially viable, cobalt-based Fischer-Tropsch (F-T) catalyst for use in a slurry bubble column reactor. Cobalt-based catalysts have long been known as being active for F-T synthesis. They typically possess greater activity than iron-based catalysts, historically the predominant catalyst being used commercially for the conversion of syngas based on coal, but possess two disadvantages that somewhat lessen its value: (1) cobalt tends to make more methane than iron does, and (2) cobalt is less versatile with low H2/CO ratio syngas due to its lack of water-gas shift activity. Therefore, the major objectives of this work are (1) to develop a cobalt-based F-T catalyst with low ( < 5 %) methane selectivity, (2) to develop a cobalt-based F-T catalyst with water-gas shift activity, and (3) to combine both these improvements into one catalyst. It will be demonstrated that these catalysts have the desired activity, selectivity, and life, and can be made reproducibly. Following this experimental work, a design and a cost estimate will be prepared for a plant to produce sufficient quantities of catalyst for scale-up studies.

  4. Technology development for cobalt F-T catalysts. Quarterly technical progress report No. 5, October 1, 1993--December 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Singleton, A.H.

    1994-05-31

    The goal of this project is the development of a commercially viable, cobalt-based Fischer-Tropsch (F-T) catalyst for use in a slurry bubble column reactor. Cobalt-based catalysts have long been known as being active for F-T synthesis. They typically possess greater activity than iron-based catalysts, historically the predominant catalyst being used commercially for the conversion of syngas based on coal, but possess two disadvantages that somewhat lessen its value: (1) cobalt tends to make more methane than iron does, and (2) cobalt is less versatile with low H{sub 2}/CO ratio syngas due to its lack of water-gas shift activity. Therefore, the major objectives of this work are (1) to develop a cobalt-based F-T catalyst with low (< 5 %) methane selectivity, (2) to develop a cobalt-based F-T catalyst with water-gas shift activity, and (3) to combine both these improvements into one catalyst. It will be demonstrated that these catalysts have the desired activity, selectivity, and life, and can be made reproducibly. Following this experimental work, a design and a cost estimate will be prepared for a plant to produce sufficient quantities of catalyst for scale-up studies.

  5. Catalyst dispersion and activity under conditions of temperature-staged liquefaction. Technical progress report, October--December 1991

    Energy Technology Data Exchange (ETDEWEB)

    Davis, A.; Schobert, H.H.; Mitchell, G.D.; Artok, L.

    1992-02-01

    The general objectives of this research are (1) to investigate the use of highly dispersed catalysts for the pretreatment of coal by mild hydrogenation, (2) to identify the active forms of the catalysts under reaction conditions and (3) to clarify the mechanisms of catalysis. The ultimate objective is to ascertain if mild catalytic hydrogenation resulting in very limited or no coal solubilization is an advantageous pretreatment for the transformation of coal into transportable fuels. The experimental program will focus upon the development of effective methods of impregnating coal with catalysts, evaluating the conditions under which the catalysts are most active and establishing the relative impact of improved impregnation on conversion and product distributions obtained from coal hydrogenation.

  6. Catalyst dispersion and activity under conditions of temperature- staged liquefaction. Technical progress report, July--September 1991

    Energy Technology Data Exchange (ETDEWEB)

    Davis, A.; Schobert, H.H.; Mitchell, G.D.; Artok, L.

    1992-02-01

    The general objectives of this research are (1) to investigate the use of highly dispersed catalysts for the pretreatment of coal by mild hydrogenation, (2) to identify the active forms of catalysts under reaction conditions and (3) to clarify the mechanisms of catalysis. The ultimate objective is to ascertain if mild catalytic hydrogenation resulting in very limited or no coal solubilization is an advantageous pretreatment for the transformation of coal into transportable fuels. The experimental program will focus upon the development of effective methods of impregnating coal with catalysts, evaluating the conditions under which the catalysts are most active and establishing the relative impact of improved impregnation on conversion and product distributions obtained from coal hydrogenation.

  7. Development of precipitated iron Fischer-Tropsch catalysts. Quarterly technical progress report, 1 July 1995--30 September 1995

    Energy Technology Data Exchange (ETDEWEB)

    Bukur, D.B.

    1995-12-20

    The following accomplishments were made on task 4. Reproducibility of Catalyst Preparation: (1) Five slurry reactor tests were completed. Three tests were conducted using catalyst C (100 Fe/3 Cu/4 K/16 SiO{sub 2}) from three different batches (runs SB-2695, SB-2145 and SA-2715), and two tests were conducted with catalyst B (100 Fe/5 Cu/6 K/24 SiO{sub 2}) from two different preparation batches (runs SA-2615 and SB-2585). Performance of catalysts from different batches (activity, selectivity and deactivation rates) was similar to that of catalysts from the original batch (synthesized during DOE Contract DE- AC22-89PC89868). Thus, another major objective of the present contract, demonstration of reproducibility of catalyst preparation procedure and performance, has been accomplished. With these tests the work on Task 4 has been successfully completed. Two fixed bed reactor tests of catalysts B and C synthesized using potassium silicate solution as the source of potassium promoter were completed during this period (Task 5. The Effect of Source of Potassium and Basic Oxide Promoter). Activity of catalysts prepared using potassium silicate as the source of potassium promotion was somewhat higher, and their methane selectivities were higher than those of the corresponding catalysts prepared by incipient wetness impregnation using KHCO{sub 3} as the source of potassium promoter. However, these differences were not large, and may have been caused by experimental artifacts (e.g. existence of local hot spots in a reactor). A slurry reactor test (SA-2405) of catalyst with nominal composition 100 Fe/5 Cu/2 Ca/24 SiO{sub 2} was completed (Task 5). In general, the catalyst activity, space-time-yield, and hydrocarbon selectivities in this run during testing at:260{degrees}C, 2.17 MPa (300 psig), 2-2.6 Nl/g-cat/h and H{sub 2}CO=0.67 were quite good, and comparable to the best results obtained in our Laboratory.

  8. Catalyst dispersion and activity under conditions of temperature- staged liquefaction. Technical progress report, January--March 1992

    Energy Technology Data Exchange (ETDEWEB)

    Davis, A.; Schobert, H.H.; Mitchell, G.D.; Artok, L.

    1992-07-01

    Two coals, a Texas subbituminous C and a Utah high volatile A bituminous, were used to examine the effects of solvent swelling and catalyst impregnation on liquefaction conversion behavior in temperature staged reactions for 30 minutes each at 275{degree} and 425{degree}C in H{sub 2} and 95:5 H{sub 2}:H{sub 2}S atmospheres. Methanol, pyridine, tetrahydrofuran, and tetrabutylammonium hydroxide were used as swelling agents. Molybdenum-based catalyst precursors were ammonium tetrathiomolybdate, molybdenum trisulfide, molybdenum hexacarbonyl, and bis(tricarbonylcyclopentadienyl-molybdenum). Ferrous sulfate and bis(dicarbonylcyclo-pentadienyliron) served as iron-based catalyst precursors. In addition, ion exchange was used for loading iron onto the subbituminous coal. For most experiments, liquefaction in H{sub 2}:H{sub 2}S was superior to that in H{sub 2}, regardless of the catalyst precursor. The benefit of the H{sub 2}S was greater for the subbituminous, presumably because of its higher iron content relative to the hvab coal. Tetrabutylammonium hydroxide was the only swelling agent to enhance conversion of the hvab coal significantly; it also caused a remarkable increase in conversion of the subbituminous coal. The combined application of solvent swelling and catalyst impregnation also improves liquefaction, mainly through increased oil yields from the hvab coal and increased asphaltenes from the subbituminous. A remarkable effect from use of ammonium tetrathiomolybdate as a catalyst precursor is substantial increase in pristane and phytane yields. Our findings suggest that these compounds are, at least in part, bound to the coal matrix.

  9. Selective methane oxidation over promoted oxide catalysts. Quarterly technical progress report, September 8, 1992--November 30, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Klier, K.; Herman, R.G.; Sun, Q.; Sarkany, J.

    1993-01-01

    Support effects on catalytic reactions, especially of highly exothermic oxidation reactions, can be very significant. Since we had shown that a MoO{sub 3}/SiO{sub 2} catalyst, especially when used in a double bed configuration with a Sr/La{sub 2}O{sub 3} catalyst, can selectively oxidize methane to formaldehyde, the role of the SiO{sub 2} support was investigated. Therefore, partial oxidation of methane by oxygen to form formaldehyde, carbon oxides, and C{sub 2} products (ethane and ethene) has been studied over silica catalyst supports (fumed Cabosil and Grace 636 silica gel) in the 630-780{degrees}C temperature range under ambient pressure. When relatively high gas hourly space velocities (GHSV) were utilized, the silica catalysts exhibit high space time yields (at low conversions) for methane partial oxidation to formaldehyde, and the C{sub 2} hydrocarbons were found to be parallel products with formaldehyde. In general, the selectivities toward CO were high while those toward CO{sub 2} were low. Based on the present results obtained by a double catalyst bed experiment, the observations of product composition dependence on the variation of GHSV (i.e. gas residence time), and differences in apparent activation energies of formation of C{sub 2}H{sub 6}, and CH{sub 2}O, a reaction mechanism is proposed for the activation of methane over the silica surface. This mechanism can explain the observed product distribution patterns (specifically the parallel formation of formaldehyde and C{sub 2} hydrocarbons).

  10. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, July--September 1992

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Gutterman, C. [Foster Wheeler Development Corp., Livingston, NJ (United States); Chander, S. [Pennsylvania State Univ., University Park, PA (United States)

    1992-12-31

    The experimental study of coal swelling ratios have been determined with a wide variety of solvents. Only marginal levels of coal swelling were observed for the hydrocarbon solvents, but high levels were found with solvents having heteroatom functionality. Blends were superior to pure solvents. The activity of various catalyst precursors for pyrene hydrogenation and coal conversion was measured. Higher coal conversions were observed for the S0{sub 2}-treated coal than the raw coal, regardless of catalyst type. Coal conversions were highest for Molyvan-L, molybdenum naphthenate, and nickel octoate, respectively. Bottoms processing consists of a combination of the ASCOT process coupling solvent deasphalting with delayed coking. Initial results indicate that a blend of butane and pentane used near the critical temperature of butane is the best solvent blend for producing a yield/temperature relationship of proper sensitivity and yet retaining an asphalt phase of reasonable viscosity. The literature concerning coal swelling, both alone and in combination with coal liquefaction, and the use of dispersed or unsupported catalysts in coal liquefaction has been updated.

  11. Quarterly Technical Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Ayman I. Hawari

    2002-12-30

    This report presents the progress made during the first quarter of phase 2 for the project entitled ''Development and Validation of Thermal Neutron Scattering Laws from Applications and Safety Implications in Generation IV Reactor Designs.'' (B204) THIS IS NOT A FINAL REPORT

  12. Technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    This report summarizes experimental and theoretical work in basic nuclear physics carried out between October 1, 1995, the closing of our last Progress Report, and September 30, 1996 at the Nuclear Physics Laboratory of the University of Colorado, Boulder, under contracts DE-FG03-93ER-40774 and DE-FG03-95ER-40913 with the United States Department of Energy. The experimental contract supports broadly-based experimental research in intermediate energy nuclear physics. This report includes results from studies of Elementary Systems involving the study of the structure of the nucleon via polarized high-energy positron scattering (the HERMES experiment) and lower energy pion scattering from both polarized and unpolarized nucleon targets. Results from pion- and kaon-induced reactions in a variety of nuclear systems are reported under the section heading Meson Reactions; the impact of these and other results on understanding the nucleus is presented in the Nuclear Structure section. In addition, new results from scattering of high-energy electrons (from CEBAF/TJNAF) and pions (from KEK) from a broad range of nuclei are reported in the section on Incoherent Reactions. Finally, the development and performance of detectors produced by the laboratory are described in the section titled Instrumentation.

  13. Technical progress report

    International Nuclear Information System (INIS)

    This report summarizes experimental and theoretical work in basic nuclear physics carried out between October 1, 1995, the closing of our last Progress Report, and September 30, 1996 at the Nuclear Physics Laboratory of the University of Colorado, Boulder, under contracts DE-FG03-93ER-40774 and DE-FG03-95ER-40913 with the United States Department of Energy. The experimental contract supports broadly-based experimental research in intermediate energy nuclear physics. This report includes results from studies of Elementary Systems involving the study of the structure of the nucleon via polarized high-energy positron scattering (the HERMES experiment) and lower energy pion scattering from both polarized and unpolarized nucleon targets. Results from pion- and kaon-induced reactions in a variety of nuclear systems are reported under the section heading Meson Reactions; the impact of these and other results on understanding the nucleus is presented in the Nuclear Structure section. In addition, new results from scattering of high-energy electrons (from CEBAF/TJNAF) and pions (from KEK) from a broad range of nuclei are reported in the section on Incoherent Reactions. Finally, the development and performance of detectors produced by the laboratory are described in the section titled Instrumentation

  14. New method of magnetic characterization of zeolite-cobalt catalysts. Quarterly technical progress report No. 1, September 1-November 30, 1985

    Energy Technology Data Exchange (ETDEWEB)

    1985-01-01

    This report describes the work carried out during the project period from September 1, 1985 through November 30, 1985. Phase I of the activity consists of modification of the existing WILKS Nuclear Quadrupole Resonance (NQR) Spectrometer system for zerofield Nuclear Magnetic Resonance (NMR) studies. Phase II is the experimental investigation of nuclear magnetic resonance absorption of the transition metal cobalt in Co-ZSM-5 catalysts. 4 figs.

  15. New method of magnetic characterization of zeolite-cobalt catalysts. Second quarterly technical progress report, December 1, 1985-February 28, 1986

    Energy Technology Data Exchange (ETDEWEB)

    Murty, A.N.

    1986-03-31

    This report describes the work carried out during the project period from December 1, 1985 through February 28, 1986. The results of our investigations on a series of cobalt and cobalt thoria catalysts physically admixed with the medium pore zeolite ZSM-5 are presented. The preparation of the catalysts and the catalytic measurements were carried out at the Pittsburgh Energy Technology Centre of the Department of Energy and the Zero-field Nuclear Magnetic Resonance experiments were made at Grambling State University using a modified Wilks Nuclear Quadrupole Resonance spectrometer, described in the previous report. The catalytic measurements revealed that the hydrocarbon yields increase from about 35% to 60% as the cobalt metal loading in ZSM-5 increases from 3 wt % to 9 wt %. When a small amount of the promoter Thoria (0.4 wt %) is added, the hydrocarbon yields increased significantly (by about 25%), for the same weight percents of cobalt in Co-ZSM-5. The primary objective of our project is to examine the effect on the Ferromagnetic character of the cobalt metal due to the (1) concentration of Co metal in ZSM-5, (2) presence of the promoter Thoria, and (3) catalytic activity. 12 refs.

  16. Technical progress of catalyst for oxidation of ethylene to ethylene oxide%乙烯氧化制环氧乙烷催化剂的技术进展

    Institute of Scientific and Technical Information of China (English)

    李胜利; 曹志涛; 张晓琳

    2013-01-01

    The silver catalyst is the core of direct oxidation of ethylene and oxide to ethylene oxide.The performance of silver catalyst,especially the selectivity,affects the economic benefit of production significantly.The technology progress and industrial application of silver catalyst around the world are introduced,and some rationalization proposals are presented for the research of silver catalyst in our country.%银催化剂是乙烯和氧气直接氧化反应生产环氧乙烷的核心,其性能尤其是选择性在很大程度上影响着生产的经济效益.介绍了国内外银催化剂的技术进展和工业应用情况,同时,对我国银催化剂的研发重点提出了一些建议.

  17. Concluding remarks: progress toward the design of solid catalysts.

    Science.gov (United States)

    Gates, Bruce C

    2016-07-01

    The 2016 Faraday Discussion on the topic "Designing New Heterogeneous Catalysts" brought together a group of scientists and engineers to address forefront topics in catalysis and the challenge of catalyst design-which is daunting because of the intrinsic non-uniformity of the surfaces of catalytic materials. "Catalyst design" has taken on a pragmatic meaning which implies the discovery of new and better catalysts on the basis of fundamental understanding of the catalyst structure and performance. The presentations and discussion at the meeting illustrate the rapid progress in this understanding linked with improvements in spectroscopy, microscopy, theory, and catalyst performance testing. The following text includes a statement of recurrent themes in the discussion and examples of forefront science that evidences progress toward catalyst design. PMID:27222485

  18. From powder to technical body: the undervalued science of catalyst scale up.

    Science.gov (United States)

    Mitchell, Sharon; Michels, Nina-Luisa; Pérez-Ramírez, Javier

    2013-07-21

    Progress in catalysis has been, is, and will always be motivated by societal needs (e.g. environment, energy, chemicals, fuels), with the ultimate aim of improving process efficiency on a technical scale. Technical catalysts are often complex multicomponent millimetre-sized bodies consisting of active phases, supports, and numerous additives in shaped forms suitable for their commercial application. They can differ strongly in composition, structure, porosity, and performance from research catalysts, i.e. laboratory-developed materials constituted by a single bulk or supported active phase in powder form, which are the predominant focus of academic investigations. The industrial manufacture of heterogeneous catalysts, encompassing the upscaled preparation, formulation, and structuring, is encircled by secrecy and is decisive for the overall process viability. Yet despite the tremendous relevance, understanding the added complexity of these multicomponent systems and the consequences for the respective structure-property-function relationships has been largely neglected. Accordingly, our review examines the intricacies of the scale up of heterogeneous catalysts. While emphasising the lack of fundamental knowledge we point out the multiple functions that additives could provide by enhancing the mass and heat transfer properties, acting as co-catalysts, or imparting improved chemical, mechanical, or thermal stability. Recent exemplary studies developing rational approaches to prepare, characterise, and evaluate technical catalysts are analysed in detail and new directions for research in this field are put forward. PMID:23648466

  19. Progress report : Technical Physics Division

    International Nuclear Information System (INIS)

    The research and development work carried out in the Technical Physics Division of the Bhabha Atomic Research Centre, Bombay, is reported. Some of the achievements are: (1) fabrication of mass spectrometers for heavy water analysis and lithium 6/7 isotope ratio measurement, (2) fabrication of electronic components for mass spectrometers, (3) growing of sodium iodide crystals for radiation detectors, (4) development of sandwich detectors comprising of NaI(Tl) and CaI(Na), (5) fabrication of mass spectrometer type leak detectors and (6) fabrication of the high vacuum components of the vacuum system of the variable energy cyclotron based at Calcutta. (M.G.B.)

  20. Technical progress in pipeline design and construction

    Energy Technology Data Exchange (ETDEWEB)

    Hausken, K.B.

    1995-12-31

    This paper considers the technical progress in offshore pipeline construction with limitation to some general subjects covering pipeline design, installation and start-up. In future the use of limit state pipeline design philosophy, may be implemented as an alternative to the stress based design commonly used to day giving a potential for further optimisation of the pipeline design and consequently reduction of the initial investment. Comprehensive research and development efforts in Norway in the second half of the 1970`s, made it technically feasible to cross the deep water Norwegian Trench in the 1980`s. In addition, the development of several offshore pipeline systems until to day including gas distribution systems to the European continent, have brought Norway to the forefront of technical expertise

  1. Technical Progress and New Logistics Technologies

    OpenAIRE

    Abel, I.; Szekely, I.

    1989-01-01

    The objective of this paper is to study new developments in logistics technologies as a prerequisite and as a consequence of technical progress in the case of the United States. Logistics is used here to denote all systematic actions aimed at bringing materials form primary producers through all intermediate steps to the end user, i.e. logistics includes transportation, handling, storage, as well as all related information processing. The rapid growth of transport and communication outpu...

  2. Technical progress and its strategic consequences

    International Nuclear Information System (INIS)

    The history of energy during recent decades has shown that technical progress can have consequences for the organisation of markets, company strategies and the economy in general, confounding all forecasts and going beyond simple technical change. As a consequence for example, improvements in the techniques concerning the exploration and production of hydrocarbons have led to the petrol 'counter-crisis', the reduction in the power of OPEC and undreamed of gains in wealth for certain countries. The progress in gas turbines has led to the reversal of the age-old tendency towards increases in the size of electricity production units and encouraged the liberation of this sector. When looking at the future it is therefore judicious to try and understand the forces at work, and the major trends which result. This is the aim of the articles in this edition of the Revue de l'Energie, published on the occasion of the European colloquium on 'Technical progress faced with the challenges of the energy sector in the future' organised by the Association of Energy Economists. (authors)

  3. Works Technical Department progress report, August 1965

    Energy Technology Data Exchange (ETDEWEB)

    1965-09-17

    This document details the activities of the Savannah River Works Technical Department during the month of August 1965. Topics discussed are: Reactor Technology, Separations Technology, Engineering Assistance, Health Physics, Laboratories Overview, and Technical Papers Issued.

  4. Solar thermal power systems. Annual technical progress report, FY 1978

    Energy Technology Data Exchange (ETDEWEB)

    1979-06-01

    A technical progress report on the DOE Solar Thermal Power Systems Program is given. Emphasis is on the technical progress of the projects rather than on activities and individual contractor efforts. Each project description indicates its place in the prior to FY 1978 is given; the significant achievements and real progress of each project during FY 1978 are described; and future project activities as well as anticipated significant achievements for each project are forecast. (WHK)

  5. Alkali/TX{sub 2} catalysts for CO/H{sub 2} conversion to C{sub 1}-C{sub 4} alcohols. Final technical progress report, September 1, 1988--August 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Klier, K.; Herman, R.G.; Richards-Babb, M.; Bastian, R.; Kieke, M.

    1993-03-01

    The objective of this research is to determine the patterns of variations of catalyst activity and selectivity for the synthesis of alcohols from H{sub 2}/CO synthesis gas. Since the source of carbon can be coal-derived synthesis gas, this research makes a contribution to the technology for high quality clean transportation fuels and for basic chemicals from coal. Catalysts prepared were principally based on MoS{sub 2}, RuS{sub 2}, TaS{sub 2}, and NbS{sub 2}. Catalytic testing of these materials was carried out both before and after surface doping with Cs. In alcohol synthesis activation of hydrogen by the catalyst surface is essential. Knowledge of transition metal disulfide surface properties is important before the mechanism of hydrogen dissociation can be addressed. The electronic structures of MoS{sub 2}, RuS{sub 2}, and NbS{sub 2} were studied both theoretically and experimentally. Experimental valence bands were obtained by high resolution electron spectroscopy for chemical analysis (HR-ESCA, also referred to as x-ray photoelectron spectroscopy) and theoretical valence bands were calculated using solid state extended Hueckel theory. Comparison of two-dimensional (2-D) MoS{sub 2} theoretical valence bands with the experimental HR-ESCA valence bands of polycrystalline MoS{sub 2} led to parametrization of the S 3s, S 3p, and Mo 4d atomic ionization potentials and Slater-type coefficients and exponents. The S 3s and S 3p parameters obtained for MoS{sub 2} were used to obtain the NbS{sub 2} and RuS{sub 2} theoretical valence bands.

  6. Discovery of technical methanation catalysts based on computational screening

    DEFF Research Database (Denmark)

    Sehested, Jens; Larsen, Kasper Emil; Kustov, Arkadii;

    2007-01-01

    Methanation is a classical reaction in heterogeneous catalysis and significant effort has been put into improving the industrially preferred nickel-based catalysts. Recently, a computational screening study showed that nickel-iron alloys should be more active than the pure nickel catalyst and at ...

  7. Fine particle clay catalysts for coal liquefaction. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Olson, E.S.

    1995-08-01

    In an effort to develop new disposable catalysts for direct coal liquefaction, several types of clay-supported pyrrhotite catalysts were prepared and tested. These included iron-pillared montmorillonite, mixed iron/alumina-pillared montmorillonite, iron-impregnated montmorillonite, and iron oxometallate-impregnated montmorillonite.

  8. Solar lease grant program. Technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    1981-04-01

    Progress on a lease program for the installation of a solar water heater with no installation charge is reported. Information on the announcement of the program, the selection of participants, the contractural agreement, progress on installation of equipment, monitoring, and evaluation is summarized. The status of the budget concerned with the program is announced. Forms used for applications for the program and an announcement from Resource Alternatives for Cilco customers are presented.

  9. Technical progress and its factors in Russia’s economy

    Directory of Open Access Journals (Sweden)

    Simon György Jr.

    2010-01-01

    Full Text Available In this paper long-term growth in Russia’s economy is viewed in the context of technical progress, based on both neoclassical and endogenous theories. The dynamics of economic growth with some aspects of catch-up development are examined, as well as capital deepening. TFP is quantified in terms of both output and productivity increases to reveal the leading role of embodied technical progress in productivity growth. An endogenous growth model helped to discern three complex factors of technical progress in the Russian economy, to which at the macro level a factor related to natural wealth (oil and gas resources was added. This enabled the author to conclude that the most important macroeconomic factor of Russia’s technical progress in the half century from the early 1960s to the late 2000s was its immobile component. At the manufacturing level the situation was more complicated, as the initial leadership of creative technical progress was superseded by the dominance of the mobile factor. The collapse of the Soviet Union made the Russian economy more service-oriented and radically changed the conditions of economic modernization, in which technology transfer ensured by FDI began to play a more prominent part, particularly after the default of 1998.

  10. Progress in Bimodal Polyethylene Produced by Metallocene Catalyst

    Institute of Scientific and Technical Information of China (English)

    FENG YuTao

    2001-01-01

    @@ The external new ways, kinds and recant advances of bimodal Polyethylene produced by metallocene catalyst were reviewed. For example, U.S.Pat.No 4939217 discloses an olefin polymerization supported catalyst comprising at least two different metallocenes each having different olefin polymerization termination rate constants in the presence of hydrogen. U.S.Pat. No.5077255 discloses an olefin polymerization supported catalyst comprising at least one metallocene of a metal, a non-metallocene transition metal and an alumoxane. The supported product is highly useful for the polymerization of olefins especially ethylene and especially for the copolymerization of ethylene and other mono and diolefins. U.S.Pat.No.5986024 discloses a process is provided for preparing polymer compositions which are multimodal in nature. The process involves contacting, under polymerization conditions, a selected addition polymerizable monomer with a metallocene catalyst having two or more distinct and chemically different active sites, and a catalyst activator.

  11. Progress in Bimodal Polyethylene Produced by Metallocene Catalyst

    Institute of Scientific and Technical Information of China (English)

    FENG; YuTao

    2001-01-01

    The external new ways, kinds and recant advances of bimodal Polyethylene produced by metallocene catalyst were reviewed. For example, U.S.Pat.No 4939217 discloses an olefin polymerization supported catalyst comprising at least two different metallocenes each having different olefin polymerization termination rate constants in the presence of hydrogen. U.S.Pat. No.5077255 discloses an olefin polymerization supported catalyst comprising at least one metallocene of a metal, a non-metallocene transition metal and an alumoxane. The supported product is highly useful for the polymerization of olefins especially ethylene and especially for the copolymerization of ethylene and other mono and diolefins. U.S.Pat.No.5986024 discloses a process is provided for preparing polymer compositions which are multimodal in nature. The process involves contacting, under polymerization conditions, a selected addition polymerizable monomer with a metallocene catalyst having two or more distinct and chemically different active sites, and a catalyst activator.  ……

  12. Climate Change and Technical Progress: Impact of Informational Constraints

    OpenAIRE

    Bondarev, Anton; Clemens, Christiane; Greiner, Alfred

    2013-01-01

    In this paper we analyse a growth model that includes environmental and economic variables as well as technological progress under different informational constraints on the behavior of economic agents. To simulate the informationally constrained economy, we make use of the non-linear model predictive control technique. We compare models with exogenous and endogenous technical change as well as directed and undirected endogenous technical change under different informational structures. We sh...

  13. Progress report [of] Technical Physics Division

    International Nuclear Information System (INIS)

    Activities of the Technical Physics Division of the Bhabha Atomic Research Centre, Bombay, over the last few years are reported. This division is engaged in developing various technologies supporting the development of nuclear technology. The various fields in which development is actively being carried out are : (i) vacuum technology, (ii) mass spectrometry, (iii) crystal technology, (iv) cryogenics, and (v) magnet technology. For surface studies, the field emission microscope and the Auger electron spectrometer and other types of spectrometers have been devised and perfected. Electromagnets of requisite strength to be used in MHD programme and NMR instruments are being fabricated. Various crystals such as NaI(Tl), Ge, Fluorides, etc. required as windows and prisms in X and gamma-ray spectroscopy, have been grown. In the cryogenics field, expansion engines required for air liquefaction plants, vacuum insulated dewars, helium gas thermometers etc. have been constructed. In addition to the above, the Division provides consultancy and training to personnel from various institutions and laboratories. Equipment and systems perfected are transferred to commercial organizations for regular production. (A.K.)

  14. Plan and Design Meticulously and Promoting Technical Progress

    Institute of Scientific and Technical Information of China (English)

    Miao Chengwu

    1994-01-01

    @@ Plan and design is the key link in captial construction, and the soul of engineering construction. China Petroleum Planning & Engineering Institute (CPPEI) is one of the main undertakers for planning and designing of petroleum industry,the only leading multi-functional institute with the first class design certificate. Now it has been an organization under the China National Petroleum Corporation(CNPC)for making development strategy planning, project evaluations and technical consulting, drawing up project development plan and providing technical recommendations. It can complete plan and design for the oil and gas field facilities, pipeline construction,petroleum relinery and petro-chemical industry engineering at home and abroad. It is also a center of servicing for new technical development and scientific research. Since CPPEI was established in 1978,it has meticulously conducted on planning and designing for the technical progress of petroleum engineering.

  15. Swallowable Wireless Capsule Endoscopy: Progress and Technical Challenges

    Directory of Open Access Journals (Sweden)

    Guobing Pan

    2012-01-01

    Full Text Available Wireless capsule endoscopy (WCE offers a feasible noninvasive way to detect the whole gastrointestinal (GI tract and revolutionizes the diagnosis technology. However, compared with wired endoscopies, the limited working time, the low frame rate, and the low image resolution limit the wider application. The progress of this new technology is reviewed in this paper, and the evolution tendencies are analyzed to be high image resolution, high frame rate, and long working time. Unfortunately, the power supply of capsule endoscope (CE is the bottleneck. Wireless power transmission (WPT is the promising solution to this problem, but is also the technical challenge. Active CE is another tendency and will be the next geneion of the WCE. Nevertheless, it will not come true shortly, unless the practical locomotion mechanism of the active CE in GI tract is achieved. The locomotion mechanism is the other technical challenge, besides the challenge of WPT. The progress about the WPT and the active capsule technology is reviewed.

  16. Solar thermal power systems. Annual technical progress report, FY 1979

    Energy Technology Data Exchange (ETDEWEB)

    Braun, Gerald W.

    1980-06-01

    The Solar Thermal Power Systems Program is the key element in the national effort to establish solar thermal conversion technologies within the major sectors of the national energy market. It provides for the development of concentrating mirror/lens heat collection and conversion technologies for both central and dispersed receiver applications to produce electricity, provide heat at its point of use in industrial processes, provide heat and electricity in combination for industrial, commercial, and residential needs, and ultimately, drive processes for production of liquid and gaseous fuels. This report is the second Annual Technical Progress Report for the Solar Thermal Power Systems Program and is structured according to the organization of the Solar Thermal Power Systems Program on September 30, 1979. Emphasis is on the technical progress of the projects rather than on activities and individual contractor efforts. Each project description indicates its place in the Solar Thermal Power Systems Program, a brief history, the significant achievements and real progress during FY 1979, also future project activities as well as anticipated significant achievements are forecast. (WHK)

  17. Making fired bricks with spent equilibrium catalyst-a technical feasibility study

    Science.gov (United States)

    Chou, M.-L.; Chen, L.-M.; Lai, Y.-C.; Chou, S.-F.

    2009-01-01

    Fluid catalytic cracking in an oil refinery uses a catalyst, such as an alumino-silicate zeolite, in the conversion of heavy hydrocarbons to light hydrocarbons. A small fraction of the catalyst is continually replaced with fresh catalyst to maintain activity. In North America, more than 400 tons of spent alumino-silicate equilibrium catalyst (spent e-cat), and worldwide, more than 1,100 tons, are generated daily, most of which is disposed of in landfills (municipal and on-site facilities). In this study, three spent e-cat samples were tested in a value-added application that would utilize this waste in the manufacturing of fired bricks. The results of this study indicate that spent e-cat is a technically feasible raw material substitute for the clay and shale commonly used in fired brick production. Fired bricks produced with up to 30 wt% of spent e-cat showed good physical appearance and their water absorption properties met the ASTM C 62 specifications for building bricks of either the moderate-or severe-weathering grade.

  18. International Linear Collider-A Technical Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Elsen, Eckhard; /DESY; Harrison, Mike; /Brookhaven; Hesla, Leah; /Fermilab; Ross, Marc; /Fermilab; Royole-Degieux, Perrine; /Paris, IN2P3; Takahashi, Rika; /KEK, Tsukuba; Walker, Nicholas; /DESY; Warmbein, Barbara; /DESY; Yamamoto, Akira; /KEK, Tsukuba; Yokoya, Kaoru; /KEK, Tsukuba; Zhang, Min; /Beijing, Inst. High Energy Phys.

    2011-11-04

    The International Linear Collider: A Technical Progress Report marks the halfway point towards the Global Design Effort fulfilling its mandate to follow up the ILC Reference Design Report with a more optimised Technical Design Report (TDR) by the end of 2012. The TDR will be based on much of the work reported here and will contain all the elements needed to propose the ILC to collaborating governments, including a technical design and implementation plan that are realistic and have been better optimised for performance, cost and risk. We are on track to develop detailed plans for the ILC, such that once results from the Large Hadron Collider (LHC) at CERN establish the main science goals and parameters of the next machine, we will be in good position to make a strong proposal for this new major global project in particle physics. The two overriding issues for the ILC R&D programme are to demonstrate that the technical requirements for the accelerator are achievable with practical technologies, and that the ambitious physics goals can be addressed by realistic ILC detectors. This GDE interim report documents the impressive progress on the accelerator technologies that can make the ILC a reality. It highlights results of the technological demonstrations that are giving the community increased confidence that we will be ready to proceed with an ILC project following the TDR. The companion detector and physics report document likewise demonstrates how detector designs can meet the ambitious and detailed physics goals set out by the ILC Steering Committee. LHC results will likely affect the requirements for the machine design and the detectors, and we are monitoring that very closely, intending to adapt our design as those results become available.

  19. Environmental Research Division technical progress report, January 1984-December 1985

    Energy Technology Data Exchange (ETDEWEB)

    1986-05-01

    Technical progress in the various research and assessment activities of Argonne National Laboratory's Environmental Research Division is reported for the period 1984 to 1985. Textual, graphic, and tabular information is used to briefly summarize (in separate chapters) the work of the Division's Atmospheric Physics, Environmental Effects Research, Environmental Impacts, Fundamental Molecular Physics and Chemistry, and Waste Management Programs. Information on professional qualifications, awards, and outstanding professional activities of staff members, as well as lists of publications, oral presentations, special events organized, and participants in educational programs, are provided in appendices at the end of each chapter.

  20. Environmental Research Division technical progress report, January 1984-December 1985

    International Nuclear Information System (INIS)

    Technical progress in the various research and assessment activities of Argonne National Laboratory's Environmental Research Division is reported for the period 1984 to 1985. Textual, graphic, and tabular information is used to briefly summarize (in separate chapters) the work of the Division's Atmospheric Physics, Environmental Effects Research, Environmental Impacts, Fundamental Molecular Physics and Chemistry, and Waste Management Programs. Information on professional qualifications, awards, and outstanding professional activities of staff members, as well as lists of publications, oral presentations, special events organized, and participants in educational programs, are provided in appendices at the end of each chapter

  1. Service-Learning: A Catalyst for Constructing Democratic Progressive Communities.

    Science.gov (United States)

    Varlotta, Lori E.

    1996-01-01

    Argues that higher education's traditional "closed" communities contrast sharply with democratic progressive ones that are more inclusive, empowering, and diverse. Drawing on feminism and postmodernism, demonstrates why service-learning is well suited to connect relational, experiential, and constructive epistemologies with democratic progressive…

  2. OTEC support services. Quarterly technical progress report No. 17, 15 May 1982-14 August 1982

    Energy Technology Data Exchange (ETDEWEB)

    None

    1982-08-01

    Progress relative to accomplishments and relative to meetings, conferences, etc. are reported in the areas of OTEC commercialization support, program technical engineering and instrumentation analysis, technical and management services, OTEC system integration, and transmission subsystem considerations. (LEW)

  3. OTEC support services. Quarterly technical progress report No. 11, 15 November 1980-14 February 1981

    Energy Technology Data Exchange (ETDEWEB)

    None

    1981-02-01

    Technical engineering and management support services for the Ocean Thermal Energy Conversion Program are listed along with their objectives. Progress is reported on the following: technical assessments, OTEC system integration, environment and siting considerations, and transmission subsystem considerations. (MHR)

  4. Theoretical particle physics: Technical progress report, May 1987-May 1988

    International Nuclear Information System (INIS)

    This Technical Progress Report outlines the research of the Task B High Energy Theory Group at Indiana University during 1987-88. We have been active in a variety of areas/emdash/superstrings, lattice gauge theory, quarkonium and neutrino physics. The following pages provide brief summaries of the progress we were able to make in these areas during the past year. In superstring theory, rules were developed for calculating string amplitudes to the one loop level for a wide variety of topologies; the stability of the string vacuum was investiagted for bosonic strings. We continued our mathematical studies of supergroups. In lattice gauge theory, we have been particularly interested in calculating, from first principles, QCD effects on weak interaction processes (of special interest here is the search for a better understanding of the mysterious /DELTA/I = /1/2/ rule). At the same time, we have been trying to develop more efficient algorithms to reduce the amount of computing necessary in lattice calculations. In more phenomenological work, we have been studying various aspects of bound quark-antiquark systems, including a new wave equation which incorporates relativitic kinematics. We have also been trying to find ways of experimentally distinguishing between Dirac and Majorana neutrinos

  5. Progress on Porous Ceramic Membrane Reactors for Heterogeneous Catalysis over Ultrafine and Nano-sized Catalysts

    Institute of Scientific and Technical Information of China (English)

    JIANG Hong; MENG Lie; CHEN Rizhi; JIN Wanqin; XING Weihong; XU Nanping

    2013-01-01

    Heterogeneous catalysts with ultrafine or nano particle size have currently attracted considerable attentions in the chemical and petrochemical production processes,but their large-scale applications remain challenging because of difficulties associated with their efficient separation from the reaction slurry.A porous ceramic membrane reactor has emerged as a promising method to solve the problem concerning catalysts separation in situ from the reaction mixture and make the production process continuous in heterogeneous catalysis.This article presents a review of the present progress on porous ceramic membrane reactors for heterogeneous catalysis,which covers classification of configurations of porous ceramic membrane reactor,major considerations and some important industrial applications.A special emphasis is paid to major considerations in term of application-oriented ceramic membrane design,optimization of ceramic membrane reactor performance and membrane fouling mechanism.Finally,brief concluding remarks on porous ceramic membrane reactors are given and possible future research interests are also outlined.

  6. FY 1992 work plan and technical progress reports

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-11-01

    The Desert Research Institute (DRI) is a division of the University of Nevada System devoted to multidisciplinary scientific research. For more than 25 years, DRI has conducted research for the US Department of Energy`s Nevada Field Office (DOE/NV) in support of operations at the Nevada Test Site (NTS). During that time, the research program has grown from an early focus on hydrologic studies to include the areas of geology, archaeology, environmental compliance and monitoring, statistics, database management, public education, and community relations. The range of DRI`s activities has also expanded to include a considerable amount of management and administrative support in addition to scientific investigations. DRI`s work plan for FY 1992 reflects a changing emphasis in DOE/NV activities from nuclear weapons testing to environmental restoration and monitoring. Most of the environmental projects from FY 1991 are continuing, and several new projects have been added to the Environmental Compliance Program. The Office of Technology Development Program, created during FY 1991, also includes a number of environmental projects. This document contains the FY 1992 work plan and quarterly technical progress reports for each DRI project.

  7. Studies of supported metal catalysts. Progress report, September 1, 1979-August 31, 1980

    International Nuclear Information System (INIS)

    Research was carried out on four separate catalyst systems: Co-Al2O3; Mo-Al2O3; Co/Mo/Al2O3; and Ni. Work was completed on the interactions between cobalt and γ-Al2O3. Work was begun on the combined Co/Mo/Al2O3 system. A separate study is in progress on support interactions between nickel and a variety of supports; particular emphasis has been on the effect of preparation method

  8. Inventors Center of Michigan Technical Assessment Program. Final progress report

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-31

    The Technical Assessment Program at the Inventors Center of Michigan is designed to provide independent inventors with a reliable assessment of the technical merits of their proposed inventions. Using faculty from within Ferris State University`s College of Technology an assessment process examines the inventor`s assumptions, documentation, and prototypes, as well as, reviewing patent search results and technical literature to provide the inventor with a written report on the technical aspects of the proposed invention. The forms for applying for a technical assessment of an invention are included.

  9. Recent progress in non-precious catalysts for metal-air batteries

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Ruiguo; Lee, Jang-Soo; Cho, Jaephil [Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan (Korea, Republic of); Liu, Meilin [School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, NW Atlanta, GA (United States)

    2012-07-15

    Electrical energy storage and conversion is vital to a clean, sustainable, and secure energy future. Among all electrochemical energy storage devices, metal-air batteries have potential to offer the highest energy density, representing the most promising systems for portable (electronics), mobile (electrical vehicles), and stationary (micro-grids) applications. To date, however, many fundamental issues are yet to be overcome to realize this potential. For example, efficient catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) at the air-electrode are yet to be developed to significantly reduce the polarization loss in metal-air batteries, which severely hinders the rate capability, energy efficiency, and operational life. In this progress report, a brief overview is first presented of the critical issues relevant to air-electrodes in metal-air batteries. Some recent advancements in the development of non-precious catalysts for ORR in Li-air and Zn-air batteries are then highlighted, including transition metal oxides, low-dimensional carbon-based structures, and other catalysts such as transition-metal macrocycles and metal nitrides. New directions and future perspectives for metal-air batteries are also outlined. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  10. Enzyme catalysts for a biotechnology-based chemical industry. Quarterly progress report, April 1--July 1, 1998

    Energy Technology Data Exchange (ETDEWEB)

    Arnold, F.H.

    1998-07-08

    The goal of this research is to engineer enzymes to be efficient and economically attractive catalysts for the chemical industry. The author is attempting to demonstrate generally-applicable approaches to enzyme improvement as well as develop specific catalysts for potential industrial application. Progress on three tasks are described: Random mutagenesis of pNB esterase--improved activity and stability; Directed evolution of subtilisin E to enhance thermostability; and Methods for invitro recombination.

  11. Enzyme catalysts for a biotechnology-based chemical industry. Quarterly progress report, April 1--June 28, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Arnold, F.H.

    1996-07-22

    The goal of this research is to engineer enzymes to be efficient and economically attractive catalysts for the chemical industry. The author is attempted to demonstrate generally-applicable approaches to enzyme improvement as well as develop specific catalysts for potential industrial application. The paper describes the progress in two projects: (a) Random mutagenesis of pNB esterase: Improved activity and stability; and (2) Subtilisin mutants exhibiting improved ligase activity in organic solvents.

  12. Monitoring the Durability Performance of Concrete in Nuclear Waste Containment. Technical Progress Report No. 3

    Energy Technology Data Exchange (ETDEWEB)

    Ulm, Franz-Josef

    2000-03-31

    OAK-B135 Monitoring the Durability Performance of Concrete in Nuclear Waste Containment. Technical Progress Report No. 3(NOTE: Part II A item 1 indicates ''PAPER'', but a report is attached electronically)

  13. Responsive copolymers for enhanced petroleum recovery. Quarterly technical progress report, December 22, 1993--March 21, 1994

    Energy Technology Data Exchange (ETDEWEB)

    McCormick, C.; Hester, R.

    1994-06-01

    The overall goal of this research is the development of advanced water-soluble copolymers for use in enhanced oil recovery. This report summarizes technical progress for the following tasks: advanced copolymer synthesis; and characterization of molecular structure of copolymers.

  14. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 1, Final technical report, October 1, 1991--September 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., (United States); Gutterman, C. [Foster Wheeler Development Corp., Livingston, NJ (United States); Chander, S. [Pennsylvania State Univ., (United States)

    1994-12-31

    The overall objective of this project was to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrated coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. Heterofunctional solvents were the most effective in swelling coals. Also solvent blends such as isopropanol/water were more effective than pure solvents alone. Impregnating slurry catalysts simultaneously during coal swelling showed that better uptake was achieved with nonswelling solvent and higher impregnation temperature. Some enhancement in initial coal conversion was seen liquefying SO{sub 2}-treated Black Thunder coal with slurry catalysts, and also when hydrogen donor liquefaction solvents were used. Noncatalytic reactions showed no benefit from SO{sub 2} treatment. Coupling coal swelling and SO{sub 2} treatment with slurry catalysts was also not beneficial, although high conversion was seen with continuous operation and long residence time, however, similar high conversion was observed with untreated coal. SO{sub 2} treatment is not economically attractive unless it provides about 17% increase in coal reactivity. In most cases, the best results were obtained when the coal was untreated and the slurry catalyst was added directly into the reactor. Foster Wheeler`s ASCOT process had better average liquid yields than either Wilsonville`s vacuum tower/ROSE combination or delayed coking process. This liquid product also had good quality.

  15. Verification of Steelmaking Slags Iron Content Final Technical Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    J.Y. Hwang

    2006-10-04

    The steel industry in the United States generates about 30 million tons of by-products each year, including 6 million tons of desulfurization and BOF/BOP slag. The recycling of BF (blast furnace) slag has made significant progress in past years with much of the material being utilized as construction aggregate and in cementitious applications. However, the recycling of desulfurization and BOF/BOP slags still faces many technical, economic, and environmental challenges. Previous efforts have focused on in-plant recycling of the by-products, achieving only limited success. As a result, large amounts of by-products of various qualities have been stockpiled at steel mills or disposed into landfills. After more than 50 years of stockpiling and landfilling, available mill site space has diminished and environmental constraints have increased. The prospect of conventionally landfilling of the material is a high cost option, a waste of true national resources, and an eternal material liability issue. The research effort has demonstrated that major inroads have been made in establishing the viability of recycling and reuse of the steelmaking slags. The research identified key components in the slags, developed technologies to separate the iron units and produce marketable products from the separation processes. Three products are generated from the technology developed in this research, including a high grade iron product containing about 90%Fe, a medium grade iron product containing about 60% Fe, and a low grade iron product containing less than 10% Fe. The high grade iron product contains primarily metallic iron and can be marketed as a replacement of pig iron or DRI (Direct Reduced Iron) for steel mills. The medium grade iron product contains both iron oxide and metallic iron and can be utilized as a substitute for the iron ore in the blast furnace. The low grade iron product is rich in calcium, magnesium and iron oxides and silicates. It has a sufficient lime value and

  16. Recent Progress in Cobalt-Based Heterogeneous Catalysts for Electrochemical Water Splitting.

    Science.gov (United States)

    Wang, Jiahai; Cui, Wei; Liu, Qian; Xing, Zhicai; Asiri, Abdullah M; Sun, Xuping

    2016-01-13

    Water electrolysis is considered as the most promising technology for hydrogen production. Much research has been devoted to developing efficient electrocatalysts for hydrogen production via the hydrogen evolution reaction (HER) and oxygen production via the oxygen evolution reaction (OER). The optimum electrocatalysts can drive down the energy costs needed for water splitting via lowering the overpotential. A number of cobalt (Co)-based materials have been developed over past years as non-noble-metal heterogeneous electrocatalysts for HER and OER. Recent progress in this field is summarized here, especially highlighting several important bifunctional catalysts. Various approaches to improve or optimize the electrocatalysts are introduced. Finally, the current existing challenges and the future working directions for enhancing the performance of Co-implicated electrocatalysts are proposed. PMID:26551487

  17. Evaporation by mechanical vapor recompression. Technical progress report, September 1-December 31, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Iverson, C.H.; Coury, G.E.

    1979-01-01

    Progress to date in the development of a study of the application of the technologies of mechanical vapor recompression and falling film evaporators as applied to the beet sugar industry is reported. Progress is reported in the following areas: technical literature search and plant visitations of existing applications of VR/FFE.

  18. The Science and Engineering of Durable Ultralow PGM Catalysts- 2012 DOE-EERE-FCT annual progress report

    Energy Technology Data Exchange (ETDEWEB)

    Garzon, Fernando H. [Los Alamos National Laboratory

    2012-07-16

    Minimizing the quantity of Pt group metals used in polymer membrane fuel cells (PEMFCs) is one of the remaining grand challenges for fuel cell commercialization. Tremendous progress has been achieved over the last two decades in decreasing the Pt loading required for efficient fuel cell performance. Unfortunately, the fluctuations in the price of Pt represent a substantial barrier to the economics of widespread fuel cell use. Durability and impurity tolerance are also challenges that are tightly coupled to fuel cell Pt electrode loading. Traditional approaches to decreasing the amount of Pt required for good performance include: (1) Increasing mass activity by decreasing Pt particle size by supporting on carbon; (2) Alloy formulation Pt-Co, Pt-Cr alloys to improve mass activity; (3) Increasing Pt utilization by optimization of electronic and ionic contact of the Pt particles; (4) Improving conductivity of the electronic and ionic conducting constituents of the membrane electrode assembly; and (5) Improving reactant to and product mass transport away from the electroactive sites. Recent novel approaches include the nanoengineering of core shell catalysts and Pt particles of unusual geometries such as nanowires/whiskers. The success of the aforementioned approaches has been great; however further advances using such approaches have been hampered by a lack of underlining scientific understanding of the catalyst activity, particle growth mechanisms, and optimization strategies for designing composite electrodes The objectives of this report are: (1) Development of durable, high mass activity Platinum Group Metal (PGM) cathode catalysts-enabling lower cost fuel cells; (2) Elucidation of the fundamental relationships between PGM catalyst shape, particle size and activity to help design better catalysts; (3) Optimization of the cathode electrode layer to maximize the performance of PGM catalysts-improving fuel cell performance and lowering cost; (4) Understanding the

  19. Conjoint utility analysis of technical maturity and project progress of construction project

    Directory of Open Access Journals (Sweden)

    Ma Wei

    2016-01-01

    Full Text Available In this paper, taking construction project as the research object, the relationship between the project maturity index calculated by the construction project technical risks with different fine degree and the project progress index is studied, and the equilibrium relationship between the Party A’s utility curve and the Party B’s cost curve of using project maturity index and project progress index as the research variables is analyzed. The results show that, when the construction project technical risk division is more precise, the conjoint utility of the project's technical maturity index and the project progress is higher, and the project’s Party A and Party B two sides are closer to the optimal equilibrium. This shows that the construction project technical risk must be finely divided, and managed and controlled respectively, which will help to improve the conjoint utility of the project Party A and Party B two sides.

  20. Chesterfield/Marlboro Technical College, AACC Progress Report.

    Science.gov (United States)

    Chesterfield-Marlboro Technical Coll., Cheraw, SC.

    In 1996, South Carolina's Chesterfield-Marlboro Technical College (CMTC) participated in the Exploring America's Communities project sponsored by the American Association of Community Colleges (AACC). The project works to strengthen the teaching and learning of American history, literature, and culture at community colleges. The primary goal of…

  1. Environmental Research Division technical progress report: January 1986--October 1987

    Energy Technology Data Exchange (ETDEWEB)

    1988-07-01

    Technical process in the various research activities of Argonne National Laboratory's Environmental Research Division is reported for the period 1986-1987. Textual, graphic, and tabular information is used to briefly summarize (in separate chapters) the work of the Division's Atmospheric Physics, Environmental Effects Research, Fundamental Molecular Physics and Chemistry, and Organic Geochemistry and Environmental Instrumentation Programs. Information on professional qualifications, awards, and outstanding professional activities of staff members, as well as lists of publications, oral presentations, special events organized, and participants in educational programs, are provided in appendices at the end of each chapter. Individual projects under each division are processed separately for the data bases.

  2. Environmental Research Division technical progress report: January 1986--October 1987

    International Nuclear Information System (INIS)

    Technical process in the various research activities of Argonne National Laboratory's Environmental Research Division is reported for the period 1986-1987. Textual, graphic, and tabular information is used to briefly summarize (in separate chapters) the work of the Division's Atmospheric Physics, Environmental Effects Research, Fundamental Molecular Physics and Chemistry, and Organic Geochemistry and Environmental Instrumentation Programs. Information on professional qualifications, awards, and outstanding professional activities of staff members, as well as lists of publications, oral presentations, special events organized, and participants in educational programs, are provided in appendices at the end of each chapter. Individual projects under each division are processed separately for the data bases

  3. Quarterly technical progress report, February 1, 1996--April 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-28

    This report from the Amarillo National REsource Center for PLutonium provides research highlights and provides information regarding the public dissemination of information. The center is a a scientific resource for information regarding the issues of the storage, disposition, potential utilization and transport of plutonium, high explosives, and other hazardous materials generated from nuclear weapons dismantlement. The center responds to informational needs and interpretation of technical and scientific data raised by interested parties and advisory groups. Also, research efforts are carried out on remedial action programs and biological/agricultural studies.

  4. Technical progress report, 1 April-30 June 1981

    Energy Technology Data Exchange (ETDEWEB)

    None

    1981-01-01

    This report describes the technical accomplishments during the quarter ending June 1981, on the commercial nuclear waste management programs under the direction of the Office of Nuclear Waste Isolation (ONWI). The ONWI program is organized into 8 tasks entitled: systems, waste package, site, repository, regulatory and institutional, test facilities and excavations, land acquisition, and program management. Principal investigators in each of these areas have submitted summaries of quarterly highlights for inclusion in this report. Separate abstracts have been prepared for 5 of these tasks for inclusion in the Energy Data Base. (DMC)

  5. Solar hot water space heating system. Technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Van Dam, T

    1979-08-13

    A retrofit solar heating system was installed on Madison Hall at Jordan College, Cedar Springs, Michigan. The system provides heating and domestic water preheating for a campus dormitory. Freeze protection is provided by a draindown system. The building and solar system, construction progress, and design changes are described. Included in appendices are: condensate trap design, structural analysis, pictures of installation, operating instructions, maintenance instructions, and as-built drawings. (MHR)

  6. Crystalline Repository Project. Technical progress report, October 1982-March 1983

    International Nuclear Information System (INIS)

    This document reports the progress being made periodically on the development of a geologic repository in crystalline rock for the permanent disposal of high-level nuclear waste. The reporting elements are arranged by the work breakdown structure so that related studies are presented together. The studies are reported by the Office of Crystalline Respository Development (OCRD), a prime contractor of the US Department of Energy Repository Project Office. The studies include work by other prime contractors and by subcontractors to OCRD

  7. The superconducting super collider: Scientific motivation and technical progress

    International Nuclear Information System (INIS)

    The author summarizes the case for new physics at the TeV scale, and reviews speculations about new phenomena which may occur there. He then discusses in brief the physics prospects of a multi-TeV hadron collider, and mention some of the processes which may be studied in detail with such an instrument. Finally, he reports progress toward the design and construction of the SSC

  8. First quarter technical progress report for Thermally Modified Sand

    Energy Technology Data Exchange (ETDEWEB)

    Gilfilian, R.E.

    1994-02-28

    This report documents progress on a project to demonstrate suitability of Thermally Modified Sand (TMS) for large scale use by demonstrating its performance on icy roadways maintained by the State of Alaska Department of Transportation. This report deals primarily with the startup of the project and includes initial observations of the effectiveness of the use of the TMS versus the typical salt/sand combination.

  9. Technical Progress Has Positive,Differentiated Effects on Energy Efficiency of Chinese Industries

    Institute of Scientific and Technical Information of China (English)

    李廉水; 周勇

    2007-01-01

    The rebound effects of technological advancement on energy consumption make it very complicated to measure the impact of technological advancement on energy efficiency.This article,taking 35 industries as samples,utilizes the non-parameter DEA-Malmquist productivity approach to subcategorise technological advancement into three parts:science-technological(sci-tech)progress,pure technical efficiency and efficiency of scale.The panel technique is then used to work out each subcategory’s contribution to energy efficiency individually.Findings show that technological efficiency (calculated by multiplying the results of pure technical efficiency and scale efficiency)is the principal factor in the improvement of energy efficiency while the contribution from sci-tech progress is comparatively less.Overtime,however,the effect of sci-tech progress is gradually heightened while the effect of technical efficiency slowly diminishes.

  10. Quarterly technical progress report, October 1-December 30, 1983

    Energy Technology Data Exchange (ETDEWEB)

    1984-04-01

    Several new initiatives were begun in coal preparation, including a project to develop a liquid CO/sub 2/ coalescence process that will produce a superclean coal containing less than 1% ash. Another new project in this area is focusing on chemical coal cleaning for the removal of harmful trace elements, such as arsenic, lead, and zinc. Milestones were reached in both of our major electron beam flue gas cleanup projects. In the area of coal-water mixtures, our major industrial contracts are now approaching critical milestones. The analysis of our in-house combustion testing of micronized coal-water mixtures in PETC's 700-horsepower oil-designed boiler has been completed. By reducing the coal particle size from 90% minus 200 mesh down to 87% minus 19 microns, the carbon conversion efficiency increased from a level of 96% to 98%. Combustion tests with a commercially available CWM showed that combustion air enriched to 23% oxygen reduced the needed air preheat temperature from 370/sup 0/ to 200/sup 0/F. Work also got underway in the new projects selected last summer to investigate advanced direct liquefaction processes. At Kerr-McGee, three scoping runs on their 350 pound/day integrated bench-scale unit were successfully completed. The objective of these runs was to evaluate subbituminous coal process options in terms of catalyst performance, distillate yields, and generation of coke precursors. Cities Service began its project on the characterization of hydrogen donor solvents in two-stage liquefaction. 7 figures, 33 tables.

  11. Progress report of Technical Physics Division: April 1980 - March 1982

    International Nuclear Information System (INIS)

    Activities, with an individual summary of each, of the Technical Physics Division (TPD) of the Bhabha Atomic Research Centre (BARC), Bombay are reported for the period April 1980 - March 1982. The major thrust of the TPD's work has been in: (i) design and fabrication of instruments, devices and equipment and (ii) development of techniques in the frontline research and technology areas like vacuum science, surface analysis, cryogenics and crystal growing. The Division also provided custombuilt electronics equipment, vacuum systems and glass components and devices to the various Divisions of BARC and other units of the DAE. Training and manpower development activities and technology transfer activities are also reported. Lists of seminars, colloquia, publications during the period of the report are given. (M.G.B.)

  12. Progress report for 1978-79, Technical Physics Division

    International Nuclear Information System (INIS)

    The research and development activities of the Technical Physics Division (TPD) of the Bhabha Atomic Research Centre, Bombay, during the calendar years 1978 and 1979 are reported. The TPD's major areas of work are electronics instrumentation, crystal technology, mass spectrometers, cryogenic equipment and vacuum equipment. Some of the major achievements are: (1) fabrication of various electronic instruments and components for the pulsed nuclear magnetic resonance spectrometers, (2) growth of large size NaI(Tl) and Ge crystals, (3) growth of CsI, KDP and arsenic selenide crystals, (4) fabrication of quadrupole mass filters and (5) fabrication of mass spectrometers for gas analysis and D/H analysis in water samples. (M.G.B.)

  13. Quarterly technical progress report, April-June 1982

    Energy Technology Data Exchange (ETDEWEB)

    None

    1984-04-01

    Progress reports are presented for the following tasks: (1) preparation of low-rank coals; application of liquefaction processes to low-rank coals; (2) slagging fixed-bed gasification; (3) atmospheric fluidized-bed combustion of low-rank coal; (4) ash fouling and combustion modification for low-rank coal; (5) combined flue gas cleanup/simultaneous SO/sub x/-NO/sub x/ control; (6) particulate control and hydrocarbons and trace element emissions from low-rank coals; (7) waste characterization and disposal; and (9) exploratory research.

  14. Technical Change Theory and Learning Curves: Patterns of Progress in Energy Technologies

    OpenAIRE

    Jamasb, Tooraj

    2006-01-01

    This paper presents a comparative analysis of energy technology learning and progress within the framework of Schumpeter?s invention-innovation-diffusion paradigm. We estimate learning by doing and research rates for a range of energy technologies in four stages of technical progress. Emerging and mature technologies respond slowly to research and development (R&D) and capacity expansion; evolving technologies exhibit high learning-by-doing and research rates; reviving technologies exhibit co...

  15. Optimization of Rhodium-Based Catalysts for Mixed Alcohol Synthesis -- 2011 Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Gerber, Mark A.; Gray, Michel J.; Albrecht, Karl O.; Rummel, Becky L.

    2011-10-01

    Pacific Northwest National Laboratory has been conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). In recent years, this research has primarily involved the further development of catalysts containing rhodium and manganese based on the results of earlier catalyst screening tests. Research during FY 2011 continued to examine the performance of RhMn catalysts on alternative supports including selected zeolite, silica, and carbon supports. Catalyst optimization continued using both the Davisil 645 and Merck Grade 7734 silica supports. Research also was initiated in FY 2011, using the both Davisil 645 silica and Hyperion CS-02C-063 carbon supports, to evaluate the potential for further improving catalyst performance, through the addition of one or two additional metals as promoters to the catalysts containing Rh, Mn, and Ir.

  16. SCR Catalyst Research Progress%SCR催化剂的研究进展

    Institute of Scientific and Technical Information of China (English)

    杨玲; 李茂; 李建军

    2012-01-01

    With the emission of NOx into atmosphere, catalyst as the core of the SCR technology has become a research focus. This paper mainly introduces the principle of SCR catalyst, vanadium-titanium-based SCR catalyst, low-temperature SCR catalyst, the SCR catalyst for resistance to water and sulfur and sulfu- ric acid SCR catalyst.%随着大气中的NOx排放量的增加,作为SCR技术的核心——催化剂也就成为了研究重点,本文主要介绍SCR催化剂的反应原理,钒钛系SCR催化剂,低温SCR催化剂,抗水、抗硫的SCR催化剂,硫酸化的SCR催化剂。

  17. Technical progress report, October 1, 1980-September 30, 1981

    International Nuclear Information System (INIS)

    Progress during the 12-month period, October 1, 1980 to September 30, 1981 on the University of Wisconsin Plasma Physics contract is described. Most of the work centers around two major experimental devices, the Levitated Octupole and Tokapole II. A major upgrade of the Octupole is underway to include 2 MW of ICRH and 1.8 MW of neutral beam heating. Meanwhile, gun optimization and low field operation has resulted in the attainment of 35% beta, a factor of 9 above the single fluid ballooning limit. The ICRH experiment is well underway, and the first neutral beam source has been installed. The Tokapole is operating reliably at the full design field of 10 kG with 12 msec discharges. Low q (approx. 0.4) discharges with flat current profiles are obtained at reduced (approx. 3kG) toroidal field. The device is presently being used to study shear Alfven wave heating, ECRH startup, poloidal ohmic heating, and plasma transport

  18. Technical progress report, November 1, 1983-October 31, 1984

    International Nuclear Information System (INIS)

    Progress on theoretical high-energy physics and field theory is briefly described. Research topics include consistency of the canonically-realized Salam-Weinberg theory, supergravity Kaluza-Klein theory, a simple supergravity GUT, a mechanism for fermion mass generation was considered and applied to the lepton sector of the Weinberg-Salam model, an N=1 locally supersymmetric theory, a local topological charge density for 2d U(1) lattice gauge fields, the 2d O(3) sigma-model, Minkowski space-time, quantum field theory, non-Abelian gauge theories and algebraic topology, the semiclassical approximation in quantum field theory, the origin of the CP violation, and others. Publications are listed

  19. TECHNICAL TRAINING SEMINAR: High Temperature Superconductors: Progress and Issues

    CERN Multimedia

    Davide Vitè

    2002-01-01

    Monday 24 June from 14:30 to 15:30 - Training Centre Auditorium - bldg. 593-11 High Temperature Superconductors: Progress and Issues Prof. Jan Evetts / UNIVERSITY OF CAMBRIDGE, Department of Materials Science and Metallurgy, UK Grappling with grain boundaries: Current transport processes in granular High Temperature Superconductors (HTS) The development of High Temperature Superconductors, seen from a materials scientist's point of view, is relevant to the superconductivity community at CERN: their possible high current applications can include high performance magnets for future accelerators. There is an urgent need to develop a quantitative description of HTS conductors in terms of their complex anisotropy, inhomogeneity and dimensionality. This is essential both for the practical specification of a conductor and for charting routes to conductor optimisation. The critical current, the n-value, dissipation and quenching characteristics are amongst most important parameters that make up an engineering specifi...

  20. Advanced thermal barrier coating system development. Technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-04

    The objectives of the program are to provide an improved TBC system with increased temperature capability and improved reliability relative to current state of the art TBC systems. The development of such a coating system is essential to the ATS engine meeting its objectives. The base program consists of three phases: Phase 1: Program Planning--Complete; Phase 2: Development; Phase 3: Selected Specimen--Bench Test. Work is currently being performed in Phase 2 of the program. In Phase 2, process improvements will be married with new bond coat and ceramic materials systems to provide improvements over currently available TBC systems. Coating reliability will be further improved with the development of an improved lifing model and NDE techniques. This will be accomplished by conducting the following program tasks: II.1 Process Modeling; II.2 Bond Coat Development; II.3 Analytical Lifing Model; II.4 Process Development; II.5 NDE, Maintenance and Repair; II.6 New TBC Concepts. A brief summary of progress made in each of these 6 areas is given.

  1. Amarillo National Resource Center for Plutonium. Quarterly technical progress report, May 1--July 31, 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    Progress is reported on research projects related to the following: Electronic resource library; Environment, safety, and health; Communication, education, training, and community involvement; Nuclear and other materials; and Reporting, evaluation, monitoring, and administration. Technical studies investigate remedial action of high explosives-contaminated lands, radioactive waste management, nondestructive assay methods, and plutonium processing, handling, and storage.

  2. Technical Adequacy and Acceptability of Curriculum-Based Measurement and the Measures of Academic Progress

    Science.gov (United States)

    January, Stacy-Ann A.; Ardoin, Scott P.

    2015-01-01

    Curriculum-based measurement in reading (CBM-R) and the Measures of Academic Progress (MAP) are assessment tools widely employed for universal screening in schools. Although a large body of research supports the validity of CBM-R, limited empirical evidence exists supporting the technical adequacy of MAP or the acceptability of either measure for…

  3. Cassini RTG Program. Monthly technical progress report, 27 November--31 December 1995

    International Nuclear Information System (INIS)

    This monthly technical progress report provided information on the following tasks: spacecraft integration and liaison; engineering support; safety analysis; qualified unicouple fabrication; ETG fabrication, assembly, and test; ground support equipment (GSE); RTG shipping and launch support; designs, reviews, and mission applications; project management, quality assurance, and reliability, and contractor acquired government owned (CAGO) property acquisition

  4. Development of improved iron Fischer-Tropsch catalysts. Final technical report: Project 6464

    Energy Technology Data Exchange (ETDEWEB)

    Bukur, D.B.; Ledakowicz, S.; Koranne, M. [Texas A and M Univ., College Station, TX (United States). Dept. of Chemical Engineering] [and others

    1994-02-28

    Despite the current worldwide oil glut, the United States will ultimately require large-scale production of liquid (transportation) fuels from coal. Slurry phase Fischer Tropsch (FT) technology, with its versatile product slate, may be expected to play a major role in production of transportation fuels via indirect coal liquefaction. Texas A&M University (TAMU) with sponsorship from the US Department of Energy, Center for Energy and Mineral Resources at TAMU, Texas Higher Education Coordinating Board, and Air Products and Chemicals, Inc., has been working on development of improved iron FT catalysts and characterization of hydrodynamic parameters in two- and three-phase bubble columns with FT derived waxes. Our previous studies have provided an improved understanding of the role of promoters (Cu and K), binders (silica) and pretreatment procedures on catalyst activity, selectivity and longevity (deactivation). The objective of the present contract was to develop improved catalysts with enhanced slurry phase activity and higher selectivity to liquid fuels and wax. This was accomplished through systematic studies of the effects of pretreatment procedures and variations in catalyst composition (promoters and binders). The major accomplishments and results in each of these two main areas of research are summarized here.

  5. Recent progress of ordered mesoporous silica-supported chiral metallic catalysts

    Directory of Open Access Journals (Sweden)

    LIU Rui

    2013-02-01

    Full Text Available Recently,ordered silica-based mesoporous chiral organometallics-functionalized heterogeneous catalysts have attracted extensive research interest due to their excellent properties,such as easy preparation,high activity and convenient recycle.This review mainly summarizesthe generally prepared strategy and the silica-based organometallics-functionalized heterogeneous catalysts reported in the literatures.

  6. Stockholm international conference 2003 on geological repositories: Political and technical progress

    International Nuclear Information System (INIS)

    The conference reviewed global progress made as well as current perspectives on the activities to develop geologic repositories. The objectives were to review the progress in policy making as well as technical issues and to strengthen international co-operation on waste management and disposal issues. The first day of the conference addressed the policy aspects of geological repositories and the second day featured the more technical issues. Session 1: International progress in performing long-term safety studies and security of geological disposal were discussed and reviewed with examples from OECD/NEA, Belgium, Sweden, USA, Switzerland and Russia. Session 2: Views on stakeholder involvement and decision making process were presented by international organisations and national implementers from Japan, United Kingdom, Belgium and OECD/NEA. Session 3: Views on stakeholder involvement and decision making process were presented by regional and local stakeholders from France, Finland, Korea and Sweden. Session 4: International instruments assisting in the implementation of geological repositories were discussed, for example ICRP and IAEA/NEA safety documents, Joint Convention, Safeguard agreements, Nuclear Liability Conventions, etc. Session 5: The contribution of Research, Development and Demonstration was discussed with overviews of the progress achieved on scientific and technical issues over the past four years. Progress and key issues were presented from Switzerland, USA, Finland, Japan, Sweden and IAEA. Each of the papers and poster presentations have been analysed and indexed separately

  7. Appraisement on Contributive Ratio of Scientific and Technical Progresses in Milk Productive Enterprises by Model C2GS2

    Institute of Scientific and Technical Information of China (English)

    SUN Futian; SUN Liqun; YANG Guanglin

    2008-01-01

    Scientific and technical progress has been the driving forces of enterprises development. Milk productive enterprises are developing faster and growing better. It is very important to measure the contributive ratio of scientific and technical progress in milk productive enterprises. And the appraisement could help to develop milk productive enterprises. The model C2GS2 was established to appraise the contributive ratio of scientific and technical progress in milk productive enterprises in the research. And the appraisement on the contributive ratio of scientific and technical progress in milk productive enterprises was made by the model. In the results of appraisement, science and technology play a main role in milk productive enterprises. It is shown that our milk productive enterprises are developed by scientific and technical progress while not by input of productive factors.

  8. Development of superior asphalt recycling agency: Phase 1, Technical feasibility. Technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Bullin, J.A.; Glover, C.J.; Davison, R.R.; Lin, Moon-Sun; Chaffin, J.; Liu, Meng; Eckhardt, C.

    1996-04-01

    About every 12 years, asphalt roads must be reworked, and this is usually done by placing thick layers (hot-mix overlays) of new material on top of failed material, resulting in considerable waste of material and use of new asphalt binder. A good recycling agent is needed, not only to reduce the viscosity of the aged material but also to restore compatibility. Objective is to establish the technical feasibility (Phase I) of determining the specifications and operating parameters for producing high quality recycling agents which will allow most/all the old asphalt-based road material to be recycled. It is expected that supercritical fractionation can be used. The advanced road aging simulation procedure will be used to study aging of blends of old asphalt and recycling agents.

  9. PROGRESS IN CATALYST AND PROCESS DEVELOPMENT FOR LOW SULFUR AND LOW AROMATICS DIESEL PRODUCTION

    Institute of Scientific and Technical Information of China (English)

    ZHOUYong; HANChong-ren

    2003-01-01

    The article includes three parts:①The development and performance of FH-DS catalyst for deep and ultra -deep distillate HDS;②The single stage HDS/HDA hydrotreating process for the production of low sulfur and low aromatics diesels from straight run and coker AGO by using highly active base metal catalyst at moderate pressure;③A two-stage aromatics saturation system utilizing noble metal catalyst in the second stage developed for production of low sulfur and low aromatics diesel from LCO.FDA catalyst developed by FRIPP has high activity for aromatics saturation together with high tolerance for sulfur and nitrogen in the feed.The process is effective in reducing density and increasing cetane number.

  10. Liquefaction of coals using ultra-fine particle, unsupported catalysts: In situ particle generation by rapid expansion of supercritical fluid solutions. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    1994-05-01

    The research conducted by Textron Defense Systems (TDS) represents a potential new and innovative concept for dispersed coal liquefaction. The technical approach is generation of ultra-fine catalyst particles from supercritical solutions by rapid expansion of either catalyst only, or mixtures of catalyst and coal material in supersaturated solvents. The process of rapid expansion of supercritical fluid solutions was developed at Battelle`s Pacific Northwest Laboratories for the intended purpose of providing a new analytical technique for characterizing supercritical fluids. The concept forming the basis of this research is that ultra-fine particles can be generated from supercritical solutions by rapid expansion of either catalyst or catalyst/coal-material mixtures in supersaturated solvents, such as carbon dioxide or water. The focal point of this technique is the rapid transfer of low vapor pressure solute (i.e., catalyst), dissolved in the supercritical fluid solvent, to the gas phase as the solution is expanded through an orifice. The expansion process is characterized by highly nonequilibrium conditions which cause the solute to undergo extremely rapid supersaturation with respect to the solvent, leading to nucleation and particle growth resulting in nanometer size catalyst particles. A supercritical expansion system was designed and built by TDS at their Haverhill facility.

  11. Technical progress report for ICRF [Ion Cyclotron Range of Frequencies] edge modeling

    International Nuclear Information System (INIS)

    This report describes the technical progress covering the period from May 15, 1989 to the present for the DOE sponsored grant, ''ICRF Edge Modeling.'' Progress in the areas of antenna design, and kinetic modeling of ions and electrons is cited. The design of antennas for CIT and C-MOD is currently an ongoing activity. Ion kinetic modeling indicates the impurity ion heating is not an important impurity production mechanism. The development of a quasilinear model for electron heating is presented. The relevant professional activities sponsored by this grant are given

  12. Decontamination Systems Information and Research Program. Quarterly technical progress report, January 1--March 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-05-01

    West Virginia University (WVU) and the US DOE Morgantown Energy Technology Center (METC) entered into a Cooperative Agreement on August 29, 1992 entitled ``Decontamination Systems Information and Research Programs.`` Stipulated within the Agreement is the requirement that WVU submit to METC a series of Technical Progress Reports on a quarterly basis. This report comprises the first Quarterly Technical Progress Report for Year 2 of the Agreement. This report reflects the progress and/or efforts performed on the sixteen (16) technical projects encompassed by the Year 2 Agreement for the period of January 1 through March 31, 1994. In situ bioremediation of chlorinated organic solvents; Microbial enrichment for enhancing in-situ biodegradation of hazardous organic wastes; Treatment of volatile organic compounds (VOCs) using biofilters; Drain-enhanced soil flushing (DESF) for organic contaminants removal; Chemical destruction of chlorinated organic compounds; Remediation of hazardous sites with steam reforming; Soil decontamination with a packed flotation column; Use of granular activated carbon columns for the simultaneous removal of organics, heavy metals, and radionuclides; Monolayer and multilayer self-assembled polyion films for gas-phase chemical sensors; Compact mercuric iodide detector technology development; Evaluation of IR and mass spectrometric techniques for on-site monitoring of volatile organic compounds; A systematic database of the state of hazardous waste clean-up technologies; Dust control methods for insitu nuclear and hazardous waste handling; Winfield Lock and Dam remediation; and Socio-economic assessment of alternative environmental restoration technologies.

  13. Optimization of Rhodium-Based Catalysts for Mixed Alcohol Synthesis – 2012 Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Gerber, Mark A.; Gray, Michel J.; Albrecht, Karl O.; Thompson, Becky L.

    2012-11-01

    Pacific Northwest National Laboratory has been conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). In recent years, this research has primarily involved the further development of catalysts containing rhodium and manganese based on the results of earlier catalyst screening tests. Testing continued in FY 2012 to further improve the Ir-promoted RhMn catalysts on both silica and carbon supports for producing mixed oxygenates from synthesis gas. This testing re-examined selected alternative silica and carbon supports to follow up on some uncertainties in the results with previous test results. Additional tests were conducted to further optimize the total and relative concentrations of Rh, Mn, and Ir, and to examine selected promoters and promoter combinations based on earlier results. To establish optimum operating conditions, the effects of the process pressure and the feed gas composition also were evaluated.

  14. Recent progress in the development of solid catalysts for biomass conversion into high value-added chemicals

    Science.gov (United States)

    Hara, Michikazu; Nakajima, Kiyotaka; Kamata, Keigo

    2015-06-01

    In recent decades, the substitution of non-renewable fossil resources by renewable biomass as a sustainable feedstock has been extensively investigated for the manufacture of high value-added products such as biofuels, commodity chemicals, and new bio-based materials such as bioplastics. Numerous solid catalyst systems for the effective conversion of biomass feedstocks into value-added chemicals and fuels have been developed. Solid catalysts are classified into four main groups with respect to their structures and substrate activation properties: (a) micro- and mesoporous materials, (b) metal oxides, (c) supported metal catalysts, and (d) sulfonated polymers. This review article focuses on the activation of substrates and/or reagents on the basis of groups (a)-(d), and the corresponding reaction mechanisms. In addition, recent progress in chemocatalytic processes for the production of five industrially important products (5-hydroxymethylfurfural, lactic acid, glyceraldehyde, 1,3-dihydroxyacetone, and furan-2,5-dicarboxylic acid) as bio-based plastic monomers and their intermediates is comprehensively summarized.

  15. Decontamination Systems Information and Research Program. Quarterly technical progress report, January 1--March 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-04-01

    This reports reports the progress/efforts performed on six technical projects: 1. systematic assessment of the state of hazardous waste clean-up technologies; 2. site remediation technologies (SRT):drain- enhanced soil flushing for organic contaminants removal; 3. SRT: in situ bio-remediation of organic contaminants; 4. excavation systems for hazardous waste sites: dust control methods for in-situ nuclear waste handling; 5. chemical destruction of polychlorinated biphenyls; and 6. development of organic sensors: monolayer and multilayer self-assembled films for chemical sensors.

  16. Heber geothermal binary demonstration project quarterly technical progress report, October 1, 1981--December 31, 1981

    Energy Technology Data Exchange (ETDEWEB)

    Lacy, R.G.; Allen, R.F.; Alsup, R.A.; Liparidis, G.S.; Van De Mark, G.D.

    1983-08-01

    The purpose of this quarterly technical progress report is to document work completed on the nominal 65 Megawatt (Mwe gross) Heber Geothermal Binary Demonstration Project, located at Heber, California, during the period of October 1, 1981, through December 31, 1981. The work was performed by San Diego Gas and Electric Company under the support and cooperation of the U.S. Department of Energy, the Electric Power Research Institute, the Imperial Irrigation District, the California Department of Water Resources, and the Southern California Edison Company. Topics covered in this quarterly report include progress made in the areas of Wells and Fluid Production and Injection Systems, Power Plant Design and Construction, Power Plant Demonstration, and Data Acquisition and Dissemination.

  17. An innovative catalyst system for slurry-phase Fischer-Tropsch synthesis: Cobalt plus a water-gas-shift catalyst. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Satterfield, C.N.; Yates, I.C.; Chanenchuk, C.

    1991-07-01

    The feasibility of using a mechanical mixture of a Co/MgO/SiO{sub 2} Fischer-Tropsch catalyst and a Cu-ZnO/Al{sub 2}O{sub 3} water-gas-shift (WGS) catalyst for hydrocarbon synthesis in a slurry reactor has been established. Such a mixture can combine the superior product distribution from cobalt with the high activity for the WGS reaction characteristic of iron. Weight ratios of Co/MgO/SiO{sub 2} to Cu-ZnO/Al{sub 2}O{sub 3} of 0.27 and 0.51 for the two catalysts were studied at 240{degrees}C, 0.79 MPa, and in situ H{sub 2}/CO ratios between 0.8 and 3.0. Each catalyst mixture showed stable Fischer-Tropsch activity for about 400 hours-on-stream at a level comparable to the cobalt catalyst operating alone. The Cu-ZnO/Al{sub 2}O{sub 3} catalyst exhibited a very slow loss of activity under these conditions, but when operated alone it was stable in a slurry reactor at 200--220{degrees}C, 0.79--1.48 MPa, and H{sub 2}/CO in situ ratios between 1.0 and 2.0. The presence of the water-gas-shift catalyst did not affect the long-term stability of the primary Fischer-Tropsch selectivity, but did increase the extent of secondary reactions, such as l-alkene hydrogenation and isomerization.

  18. Projects at the component development and integration facility. Quarterly technical progress report, April 1, 1994--June 30, 1994

    International Nuclear Information System (INIS)

    This quarterly technical progress report presents progress on the projects at the Component Development and Integration Facility (CDIF) during the third quarter of FY94. The CDIF is a major Department of Energy test facility in Butte, Montana, operated by MSE, Inc. Projects in progress include: Biomass Remediation Project; Heavy Metal-Contaminated Soil Project; MHD Shutdown; Mine Waste Technology Pilot Program; Plasma Projects; Resource Recovery Project; and Spray Casting Project

  19. Projects at the Component Development and Integration Facility. Quarterly technical progress report, January 1, 1994--March 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-08-01

    This quarterly technical progress report presents progress on the projects at the Component Development and Integration Facility (CDIF) during the second quarter of FY94. The CDIF is a major US Department of Energy test facility in Butte, Montana, operated by MSE, Inc. Projects in progress include: Biomass Remediation Project; Heavy Metal-Contaminated Soil Project; MHD Shutdown; Mine Waste Technology Pilot Program; Plasma Projects; Resource Recovery Project; Sodium Sulfide/Ferrous Sulfate Project; and Spray Casting Project.

  20. Intelligent distributed control for nuclear power plants. Second annual technical progress report, September 1990--September 1991

    Energy Technology Data Exchange (ETDEWEB)

    Klevans, E.H.; Edwards, R.M.; Ray, A.; Lee, K.Y.; Garcia, H.E.: Chavez, C.M.; Turso, J.A.; BenAbdennour, A.

    1991-12-31

    In September of 1989 work began on the DOE University Program grant DE-FG07-89ER12889. The grant provides support for a three year project to develop and demonstrate Intelligent Distributed Control (IDC) for Nuclear Power Plants. The body of this Second Annual Technical Progress report covers the period from September 1990 to September 1991. It summarizes the second year accomplishments while the appendices provide detailed information presented at conference meetings. These are two primary goals of this research. The first is to combine diagnostics and control to achieve a highly automated power plant as described by M.A. Schultz, a project consultant during the first year of the project. This philosophy, as presented in the first annual technical progress report, is to improve public perception of the safety of nuclear power plants by incorporating a high degree automation where greatly simplified operator control console minimizes the possibility of human error in power plant operations. A hierarchically distributed control system with automated responses to plant upset conditions is the focus of our research to achieve this goal. The second goal is to apply this research to develop a prototype demonstration on an actual power plant system, the EBR-II steam plant.

  1. Advanced thermally stable jet fuels: Technical progress report, October 1994--December 1994

    Energy Technology Data Exchange (ETDEWEB)

    Schobert, H.H.; Eser, S.; Song, C.; Hatcher, P.G.; Boehman, A.; Coleman, M.M.

    1995-02-01

    There are five tasks within this project on thermally stable coal-based jet fuels. Progress on each of the tasks is described. Task 1, Investigation of the quantitative degradation chemistry of fuels, has 5 subtasks which are described: Literature review on thermal stability of jet fuels; Pyrolytic and catalytic reactions of potential endothermic fuels: cis- and trans-decalin; Use of site specific {sup 13}C-labeling to examine the thermal stressing of 1-phenylhexane: A case study for the determination of reaction kinetics in complex fuel mixtures versus model compound studies; Estimation of critical temperatures of jet fuels; and Surface effects on deposit formation in a flow reactor system. Under Task 2, Investigation of incipient deposition, the subtask reported is Uncertainty analysis on growth and deposition of particles during heating of coal-derived aviation gas turbine fuels; under Task 3, Characterization of solid gums, sediments, and carbonaceous deposits, is subtask, Studies of surface chemistry of PX-21 activated carbon during thermal degradation of jet A-1 fuel and n-dodecane; under Task 4, Coal-based fuel stabilization studies, is subtask, Exploratory screening and development potential of jet fuel thermal stabilizers over 400 C; and under Task 5, Exploratory studies on the direct conversion of coal to high quality jet fuels, are 4 subtasks: Novel approaches to low-severity coal liquefaction and coal/resid co-processing using water and dispersed catalysts; Shape-selective naphthalene hydrogenation for production of thermally stable jet fuels; Design of a batch mode and a continuous mode three-phase reactor system for the liquefaction of coal and upgrading of coal liquids; and Exploratory studies on coal liquids upgrading using mesopores molecular sieve catalysts. 136 refs., 69 figs., 24 tabs.

  2. Alternative formulations of regenerable flue gas cleanup catalysts. Progress report, September 1, 1990--August 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, M.B.; White, M.G.

    1991-12-31

    The major source of man-made SO{sub 2} in the atmosphere is the burning of coal for electric power generation. Coal-fired utility plants are also large sources of NO{sub x} pollution. Regenerable flue gas desulfurization/NO{sub x} abatement catalysts provide one mechanism of simultaneously removing SO{sub 2} and NO{sub x} species from flue gases released into the atmosphere. The purpose of this project is to examine routes of optimizing the adsorption efficiency, the adsorption capacity, and the ease of regeneration of regenerable flue gas cleanup catalysts. We are investigating two different mechanisms for accomplishing this goal. The first involves the use of different alkali and alkaline earth metals as promoters for the alumina sorbents to increase the surface basicity of the sorbent and thus adjust the number and distribution of adsorption sites. The second involves investigation of non-aqueous impregnation, as opposed to aqueous impregnation, as a method to obtain an evenly dispersed monolayer of the promoter on the surface.

  3. Volume 1, 1st Edition, Multiscale Tailoring of Highly Active and Stable Nanocomposite Catalysts, Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Veser, Goetz

    2009-08-31

    Nanomaterials have gained much attention as catalysts since the discovery of exceptional CO oxidation activity of nanoscale gold by Haruta. However, many studies avoid testing nanomaterials at the high-temperatures relevant to reactions of interest for the production of clean energy (T > 700°C). The generally poor thermal stability of catalytically active noble metals has thus far prevented significant progress in this area. We have recently overcome the poor thermal stability of nanoparticles by synthesizing a platinum barium-hexaaluminate (Pt-BHA) nanocomposite which combines the high activity of noble metal nanoparticles with the thermal stability of hexaaluminates. This Pt-BHA nanocomposite demonstrates excellent activity, selectivity, and long-term stability in CPOM. Pt-BHA is anchored onto a variety of support structures in order to improve the accessibility, safety, and reactivity of the nanocatalyst. Silica felts prove to be particularly amenable to this supporting procedure, with the resulting supported nanocatalyst proving to be as active and stable for CPOM as its unsupported counterpart. Various pre-treatment conditions are evaluated to determine their effectiveness in removing residual surfactant from the active nanoscale platinum particles. The size of these particles is measured across a wide temperature range, and the resulting “plateau” of stability from 600-900°C can be linked to a particle caging effect due to the structure of the supporting ceramic framework. The nanocomposites are used to catalyze the combustion of a dilute methane stream, and the results indicate enhanced activity for both Pt-BHA as well as ceria-doped BHA, as well as an absence of internal mass transfer limitations at the conditions tested. In water-gas shift reaction, nanocomposite Pt-BHA shows stability during prolonged WGS reaction and no signs of deactivation during start-up/shut-down of the reactor. The chemical and thermal stability, low molecular weight, and

  4. 负载型柴油氧化脱硫催化剂的研究进展%Progress on Supported Catalysts for Oxidative Desulfurization of Diesel

    Institute of Scientific and Technical Information of China (English)

    谢颖; 黄克明; 梁朝林

    2011-01-01

    In this paper, the progresses on the supported catalysts for oxidative desulfurization of diesel were discussed, mainly including transition metal catalysts and supported heteropoly acid catalysts. The two kinds of catalysts were compared in support type, catalytic activity and industrial application. It was concluded that zeolite and activated carbon as the supports were suitable to the oxidative desulfurization catalysts. The supported heteropoly acid catalysts had a good industrial prospect due to their high activity, low active component loss, easy separation and multiple reuse for the oxidative desulfurization of diesel.%介绍了负载型柴油氧化脱硫催化剂的研究进展,主要包括负载型过渡金属催化剂和负载型杂多酸催化剂,从催化剂的载体种类、催化活性和工业应用等方面比较了这两种催化剂的优缺点.通过比较得出,分子筛和活性炭更适合作为氧化脱硫催化剂的载体;负载型杂多酸催化剂具有活性高、活性组分不易流失、便于分离回收循环使用的优点,具有很好的工业应用前景.

  5. PFBC HGCU Test Facility. Technical progress report: Third Quarter, CY 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-10-01

    This is the sixteenth Technical Progress Report submitted to the Department of Energy (DOE) in connection with the cooperative agreement between the DOE and Ohio Power Company for the Tidd PFBC (pressurized fluidized-bed combustion) Hot Gas Clean Up Test Facility (HGCU). This report covers the period of work completed during the Third Quarter of CY 1993. During this quarter, the Advanced Particle Filter (APF) was operated for a total of 1295 hours. This represents 58% availability during July, August, September, and including June 30 of the previous quarter. The operating dates and times since initial operation are summarized. The APF operating temperatures and differential pressures are provided. Details of the APF runs during this quarter are included in this report.

  6. Power systems development facility. Quarterly technical progress report, January 1, 1994--March 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-07-01

    This quarterly technical progress report summarizes work completed during the last quarter of the Second Budget Period, January 1 through March 31, 1994, entitled {open_quotes}Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.{close_quotes} The objective of this project is to evaluate hot gas particulate control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size.

  7. MHD air heater technology development. Annual technical progress report, January 1, 1980-December 31, 1980

    Energy Technology Data Exchange (ETDEWEB)

    None

    1981-03-01

    Progress on the technology development of the directly-fired high temperature air heater (HTAH) for MHD power plants is described in detail. The objective of task 1 is to continue development of ceramic materials technology for the directly-fired HTAH. The objectives of task 2 are to demonstrate the technical feasibility of operating a directly-fired HTAH (including both the heater matrix and valves), to continue obtaining information on life and corrosion resistance of HTAH materials, and to obtain design information for full-scale studies and future design work. The objectives of task 3 are to begin the identification of HTAH control requirements and control system needs, and to continue full-scale study efforts incorporating updated materials and design information in order to identify development needs for the HTAH development program. (WHK)

  8. Energy conservation in citrus processing. Technical progress report, October 1, 1979-March 31, 1980

    Energy Technology Data Exchange (ETDEWEB)

    1980-06-15

    The Sunkist Citrus Plant in Ontario, California, processes about 6 million pounds of citrus fruit per day to make products which include frozen concentrated juice; chilled, pasteurized, natural strength juice; molasses from peel; dried meal from peel; pectin; citrus oil; and bioflavonoids. The energy intensive operations at the plant include concentration, drying, and refrigeration. The objective of the two-year two-phase project is to identify an economically viable alternative to the existing method of meeting energy requirements. Progress on the technical work of Phase I is reported. The following are summarized: requirements (energy price projection, atmospheric emission requirements, citrus juice quality constraints, economic evaluations); characterization (basic citrus processing operations, energy consumption and fruit processed vs time, identification and measurement of energy uses, energy balance for a typical citrus juice evaporator); and thermodynamic analysis (heat pump model, thermal evaporator, and co-generation model).

  9. Research and Test Reactor Conversion to Low Enriched Uranium Fuel: Technical and Programmatic Progress

    International Nuclear Information System (INIS)

    The U.S Department of Energy (DOE) initiated a program - the Reduced Enrichment for Research and Test Reactors (RERTR) - in 1978 to develop the technology necessary to reduce the use of High Enriched Uranium (HEU) fuel in research reactors by converting them to low enriched uranium (LEU) fuel. In 2004, the reactor conversion program became the driving pilar of the Global Threat Reduction Initiative (GTRI), a program established by the U.S. DOE's National Nuclear Security Administration. The overall GTRI objectives are the conversion, removal or protection of vunerable civilian radiological and nuclear material. As part of the GTRI, the Conversion Program has accelerated the schedules and plans for conversion of additional research reactors operating with HEU. This paper provides an update on the progress made since 2007 and describes current technical challenges that the program faces. (author)

  10. Solar heating and hot water system for the central administrative office facility. Technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    1978-11-01

    Progress on the solar heating and hot water system for the central administrative office facility of the Lincoln Housing Authority, Lincoln, NE is covered. An acceptance test plan is presented and the results of the test are tabulated. A complete blueprint of the system as built is provided. The monitoring system is drawn and settings and installation are described. An operation and maintenance manual discusses procedures for start up, shut down and seasonal changeover and include a valve list and pictures and specifications of components and materials used. Photographs of the final installation are included, and technical data and performance data are given. Finally, there is a brief description of system design and operation and a discussion of major maintenance problems encountered and their solutions. (LEW)

  11. The effects of environmental regulation and technical progress on CO2 Kuznets curve: An evidence from China

    International Nuclear Information System (INIS)

    Based on environmental Kuznets curve theory, a panel data model which takes environmental regulation and technical progress as its moderating factors was developed to analyse the institutional and technical factors that affect the path of low-carbon economic development. The results indicated that there was a CO2 emission Kuznets curve seen in China. Environmental regulation had a significant moderating effect on the curve, and the inflection of CO2 emissions could come substantially earlier under stricter environmental regulation. Meanwhile, the impact of technical progress on the low-carbon economic development path had a longer hysteresis effect but restrained CO2 emission during its increasing stage and accelerated its downward trend during the decreasing stage which was conducive to emission reduction. Strict environmental regulation could force the high-carbon emitting industries to transfer from the eastern regions to the central or the western regions of China, which would make the CO2 Kuznets curve higher in its increasing stage and lower in its decreasing stage than that under looser regulation. Furthermore, energy efficiency, energy structure, and industrial structure exerted a significant direct impact on CO2 emissions; we should consider the above factors as essential in the quest for low-carbon economic development. - Highlights: • Estimate moderating effect of environmental regulation and technical progress on EKC. • There was a CO2 emission Kuznets curve in effect in China. • Environmental regulation presents significant moderating effect on EKC. • Technical progress moderates the relationship between income and CO2 emissions

  12. Novel catalysts for methane activation. Final progress report, September 30, 1992--April 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Hirschon, A.S.; Du, Y.; Wu, H.J.; Malhotra, R.; Wilson, R.B.

    1996-06-11

    This final report summarizes the results of our research under Contract No. DE-AC22-92PC92112, Novel Catalysts for Methane Activation. In this research we prepared and tested fullerene soots for converting methane into higher hydrocarbons. We conducted the methane conversions using dehydrocoupling conditions, primarily in the temperature regimes of 600{degrees}-1000{degrees}C and atmospheric pressures. The research was divided into three sections. The first section focused on comparing fullerene soots with other forms of carbon such as acetylene black and Norit-A. We found that the fullerene soot was indeed more reactive than the other forms of carbon. However, due to its high reactivity, it was not selective. The second section focused on the effect of metals on the reactivity of the soots, including both transition metals and alkali metals. We found that potassium could enhance the selectivities of fullerene soot to higher hydrocarbons, but the effect was unique to fullerene soot and did not improve the performance of other forms of carbon. The third part focused on the use of co-feeds for methane activation to enhance the selectivities and lower the temperature threshold of methane activation.

  13. Catalytic Epoxidation of a Technical Mixture of Methyl Oleate and Methyl Linoleate in Ionic Liquids Using MoO(O22•2QOH (QOH = 8-quinilinol as Catalyst and NaHCO3 as co-Catalyst

    Directory of Open Access Journals (Sweden)

    Chuan-Lei Fan

    2009-08-01

    Full Text Available The oxo-diperoxo molybdenum(VI complex MoO(O22•2QOH (QOH = 8-quinilinol was prepared and characterized by elemental analysis, IR and UV-Vis spectra. The ionic liquids (ILs [bmim][BF4], [hydemim][BF4], and [bmim][PF6] were characterized by 1H-NMR and UV-Vis spectra. The epoxidation of a technical mixture of methyl oleate and methyl linoleate with H2O2, in [bmim][BF4], [hydemim][BF4] and [bmim][PF6], catalyzed by MoO(O22•2QOH (QOH = 8-quinilinol and with NaHCO3 as co-catalyst has been studied for the first time. It was found that high conversions of methyl oleate and methyl linoleate to their respective oxidation products, as well as the total selectivity of their oxidation products to oxirane in [hydemim][BF4] were obtained. Also, the IL phases containing the Mo(VI catalyst can be readily recycled by washing with diethyl ether and drying, and the Mo(VI catalyst can be reused at least five times.

  14. MHD Integrated Topping Cycle Project. Fourteenth quarterly technical progress report, November 1, 1990-- January 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    1992-02-01

    This fourteenth quarterly technical progress report of the MHD Integrated Topping Cycle Project presents the accomplishments during the period November 1, 1990 to January 31, 1991. Testing of the High Pressure Cooling Subsystem electrical isolator was completed. The PEEK material successfully passed the high temperature, high pressure duration tests (50 hours). The Combustion Subsystem drawings were CADAM released. The procurement process is in progress. An equipment specification and RFP were prepared for the new Low Pressure Cooling System (LPCS) and released for quotation. Work has been conducted on confirmation tests leading to final gas-side designs and studies to assist in channel fabrication.The final cathode gas-side design and the proposed gas-side designs of the anode and sidewall are presented. Anode confirmation tests and related analyses of anode wear mechanisms used in the selection of the proposed anode design are presented. Sidewall confirmation tests, which were used to select the proposed gas-side design, were conducted. The design for the full scale CDIF system was completed. A test program was initiated to investigate the practicality of using Avco current controls for current consolidation in the power takeoff (PTO) regions and to determine the cause of past current consolidation failures. Another important activity was the installation of 1A4-style coupons in the 1A1 channel. A description of the coupons and their location with 1A1 channel is presented herein.

  15. Long-Term Testing of Rhodium-Based Catalysts for Mixed Alcohol Synthesis – 2013 Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Gerber, Mark A.; Gray, Michel J.; Thompson, Becky L.

    2013-09-23

    The U.S. Department of Energy’s Pacific Northwest National Laboratory has been conducting research since 2005 to develop a catalyst for the conversion of synthesis gas (carbon monoxide and hydrogen) into mixed alcohols for use in liquid transportation fuels. Initially, research involved screening possible catalysts based on a review of the literature, because at that time, there were no commercial catalysts available. The screening effort resulted in a decision to focus on catalysts containing rhodium and manganese. Subsequent research identified iridium as a key promoter for this catalyst system. Since then, research has continued to improve rhodium/manganese/iridium-based catalysts, optimizing the relative and total concentrations of the three metals, examining baseline catalysts on alternative supports, and examining effects of additional promoters. Testing was continued in FY 2013 to evaluate the performance and long-term stability of the best catalysts tested to date. Three tests were conducted. A long-term test of over 2300 hr duration at a single set of operating conditions was conducted with the best carbon-supported catalyst. A second test of about 650 hr duration at a single set of operating conditions was performed for comparison using the same catalyst formulation on an alternative carbon support. A third test of about 680 hr duration at a single set of operating conditions was performed using the best silica-supported catalyst tested to date.

  16. Generation and focusing of pulsed intense ion beams. Technical progress report, 20 August 1981-30 September 1982

    International Nuclear Information System (INIS)

    The progress on this contract is described in two parts. The first deals with the technical operation of the LION accelerator which is the exact equivalent to one line of PBFA-I. The second part is concerned with the experimental results on the ion diode mounted at the front end of the LION accelerator

  17. Final Technical Progress Report: Development of Low-Cost Suspension Heliostat; December 7, 2011 - December 6, 2012

    Energy Technology Data Exchange (ETDEWEB)

    Bender, W.

    2013-01-01

    Final technical progress report of SunShot Incubator Solaflect Energy. The project succeeded in demonstrating that the Solaflect Suspension Heliostat design is viable for large-scale CSP installations. Canting accuracy is acceptable and is continually improving as Solaflect improves its understanding of this design. Cost reduction initiatives were successful, and there are still many opportunities for further development and further cost reduction.

  18. 二硝基甲苯液相加氢催化剂研究进展%Research Progress in the Catalysts for Liquid Phase Hydrogenation of Dinitrotoluene

    Institute of Scientific and Technical Information of China (English)

    李贵贤; 张雪梅; 高云艳; 王天烽; 王广; 宋维维

    2011-01-01

    Toluenediisocynate(TDI) which was produced by tolylenediamine ( TDA) had a variety application as an intermediate in the polyurethane manufacture. The research progress of catalysis hydrogenation of dinitrotolu-ene( DNT) producing TDA was introduced. All kinds of catalyst on dinitrotoluene catalysis hydrogenation performance were analyzed, the advantages and disadvantages of various catalyst were emphasized. The development trend of hydrogenation catalyst on the crystal catalyst to amorphous catalyst was put forward.%甲苯二胺(TDA)作为甲苯二异氰酸酯(TDI)的合成中间体,广泛应用于聚氨酯工业中.本综述介绍了二硝基甲苯(DNT)液相加氢制TDA催化剂在国内外的研究进展,对各类催化剂催化DNT加氢性能进行了分析,指出了各类催化剂的优缺点,提出了DNT液相加氢催化剂由晶态向非晶态方向的发展趋势.

  19. Concept and progress in coupling of dehydrogenation and hydrogenation reactions through catalysts

    Indian Academy of Sciences (India)

    C V Pramod; C Raghavendra; K Hari Prasad Reddy; G V Ramesh Babu; K S Rama Rao; B David Raju

    2014-03-01

    This review focuses on the importance of coupling of catalytic reactions which involves dehydrogenation and hydrogenation simultaneously and the study of catalytic materials that are designed, adopted and/or modified for these reactions. The special features of these reactions are minimization of H2 utilization and reduction in production cost. Structural and textural properties also play a decisive role in this kind of coupled reactions. This particular review although not comprehensive discusses the significant progress made in the area of coupled reactions and also helps future researchers or engineers to find out the improvements required in areas such as advancements in catalytic material preparation, design of the new reactors and the application of new technologies.

  20. [Chemical risk in operating rooms and technical progress: the obligations and responsibilities of law].

    Science.gov (United States)

    Oddo, Antonio

    2013-01-01

    We are going to consider the specific applications of the new legal system and of the most recent body of laws to those work environments of particular risk, such as healthcare facilities and in particular operating rooms. In such environments, volatile chemicals classified as "dangerous" are used with consequent exposure to "chemical risk", both of those persons professionally involved, depending on the type of activity, and of the patients to whom such activities are addressed in the same environment. Once the chemical risk is framed in the existing regulatory system, it must be specifically evaluated the application of the same principle to the particular chemical risk arising from the use of anesthetic agents in the operating room, for example sevoflurane and desflurane, being careful to test wether and how much this risk can be eliminated or reduced to minimum in relation to the new achievements of the technical progress. So, as soon as the quality of "dangerous chemical agent" of the "volatile chemicals" and of the "volatile liquid anesthetic" (sevoflurane and desflurane) as well--which are characterized by a lower degree of toxicity and for this reason are mostly used in current chemical practice, preferable to some anesthetic gases such as nitrous oxide--is legally verified, it is necessary to relate the scientific and technical data which result from the current "state of art" also to the other binding regulations that are imposed for the "prevention and protection from chemical agents", according to the relative Title IX of the TUSL (Unique text for Safety and Health at Work). PMID:24640081

  1. Cooperative research in coal liquefaction. Technical progress report, May 1, 1993--April 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, G.P. [ed.

    1994-10-01

    Accomplishments for the past year are presented for the following tasks: coliquefaction of coal with waste materials; catalysts for coal liquefaction to clean transportation fuels; fundamental research in coal liquefaction; and in situ analytical techniques for coal liquefaction and coal liquefaction catalysts some of the highlights are: very promising results have been obtained from the liquefaction of plastics, rubber tires, paper and other wastes, and the coliquefaction of wastes with coal; a number of water soluble coal liquefaction catalysts, iron, cobalt, nickel and molybdenum, have been comparatively tested; mossbauer spectroscopy, XAFS spectroscopy, TEM and XPS have been used to characterize a variety of catalysts and other samples from numerous consortium and DOE liquefaction projects and in situ ESR measurements of the free radical density have been conducted at temperatures from 100 to 600{degrees}C and H{sub 2} pressures up to 600 psi.

  2. Establishment of an Institute for Fusion Studies. Technical progress report, November 1, 1991--October 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Hazeltine, R.D.

    1992-07-01

    The Institute for Fusion Studies is a national center for theoretical fusion plasma physics research. Its purposes are: (1) to conduct research on theoretical questions concerning the achievement of controlled fusion energy by means of magnetic confinement--including both fundamental problems of long-range significance, as well as shorter-term issues; (2) to serve as a center for information exchange, nationally and internationally, by hosting exchange visits, conferences, and workshops; (3) and to train students and postdoctoral research personnel for the fusion energy program and plasma physics research areas. The theoretical research results that are obtained by the Institute contribute mainly to the progress of national and international efforts in nuclear fusion research, whose goal is the development of fusion power.as a basic energy source. In addition to its primary focus on fusion physics, the Institute is also involved with research in related fields, such as advanced computing techniques, nonlinear dynamics, plasma astrophysics, and accelerator physics. The work of EFS scientists continued to receive national and international recognition. Numerous invited papers were given during the past year at workshops, conferences, and scientific meetings. Last year IFS scientists published 95 scientific articles in technical journals and monographs.

  3. Jointly sponsored research program quarterly technical progress report, January--March 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-08-01

    Progress reports are presented for the following tasks: Development and demonstration of a practical electric downhole steam generator for thermal recovery of heavy oil and tar; wetting behavior of selected crude oil/brine/rock systems; coal gasification, power generation, and product market study; impact of leachate from clean coal technology waste on the stability of clay liners; investigation of coprocessing of heavy oil, automobile shredder residue, and coal; injection into coal seams for simultaneous CO{sub 2} mitigation and enhanced recovery of coalbed methane; optimization of carbonizer operations in the FMC coke process; chemical sensor and field screening technology development; demonstration of the Koppelman ``Series C`` Power River Basin coal as feed; remote chemical sensor development; market assessment and technical feasibility study of PFBC ash use; solid-state NMR analysis and interpretation of naturally and artificially matured kerogens; Crow{trademark} field demonstration with Bell Lumber and Pole; ``B`` series pilot plant tests; and in-situ treatment of manufactured gas plant contaminated soils demonstration program.

  4. MHD air heater development technology. Technical progress report, April 1, 1980-June 30, 1980

    Energy Technology Data Exchange (ETDEWEB)

    None

    1980-07-01

    Technology development for the directly-fired high temperature air heater (HTAH) for MHD power plants is described. Work is being done under three tasks as described in the following. (1) materials selection, evaluation, and development: The objective of this task is to continue development of ceramic materials technology for the directly-fired HTAH. The scope of the work will include compilation of materials data, materials selection for testing and design studies, materials property determination, liaison with refractory manufacturers and other organizations to encourage development of materials and fabrication technology, establishment of preliminary HTAH material specifications, analyses of test materials, and development of criteria for thermal stress limits for crack-tolerant refractory materials. (2) operability, performance, and materials testing: The objectives of this task are to demonstrate the technical feasibility of operating a directly-fired HTAH (including both the heater matrix and valves), to continue obtaining information on life and corrosion resistance of HTAH materials, and to obtain design information for full-scale studies and future design work. (3) full-scale design concepts: The objectives of this task are to begin the identification of HTAH control requirements and control system needs, and to continue full-scale study efforts incorporating updated materials and design information in order to identify development needs for the HTAH development program. Progress is described. (WHK)

  5. PFBC HGCU Test Facility. Technical progress report No. 24, Third quarter, CY 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-01

    This is the twenty-fourth and final Technical Progress Report submitted to the Department of Energy (DOE) in connection with the cooperative agreement between the DOE and Ohio Power Company for the Tidd PFBC Hot Gas Clean Up Test Facility. This report covers the work completed during the Third Quarter of CY 1995. All activity this quarter was directed toward the completion of the program final report. A draft copy of the final report was forwarded to DOE during this quarter, and DOE submitted their comments on the report to AEPSC. DOE requested that Westinghouse write an appendix to the report covering the performance of the fail-safe regenerator devices during Tad operation, and Westinghouse subsequently prepared the appendix. Additional DOE comments were incorporated into the report, and it will be issued in camera-ready form by the end of October, 1995, which is the program end date. Appendix 1 presents the results of filter candle posttest examination by Westinghouse performed on selected filter candles following final shutdown of the system.

  6. MHD Integrated Topping Cycle Project. Sixteenth quarterly technical progress report, May 1991--July 1991

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-01

    The Magnetohydrodynamics (MHD) Integrated Topping Cycle (ITC) Project represents the culmination of the proof-of-concept (POC) development stage in the US Department of Energy (DOE) program to advance MHD technology to early commercial development stage utility power applications. The project is a joint effort, combining the skills of three topping cycle component developers: TRW, Avco/TDS, and Westinghouse. TRW, the prime contractor and system integrator, is responsible for the 50 thermal megawatt (50 MW{sub t}) slagging coal combustion subsystem. Avco/TDS is responsible for the MHD channel subsystem (nozzle, channel, diffuser, and power conditioning circuits), and Westinghouse is responsible for the current consolidation subsystem. The ITC Project will advance the state-of-the-art in MHD power systems with the design, construction, and integrated testing of 50 MW{sub t} power train components which are prototypical of the equipment that will be used in an early commercial scale MHD utility retrofit. Long duration testing of the integrated power train at the Component Development and Integration Facility (CDIF) in Butte, Montana will be performed, so that by the early 1990`s, an engineering data base on the reliability, availability, maintainability and performance of the system will be available to allow scaleup of the prototypical designs to the next development level. This Sixteenth Quarterly Technical Progress Report covers the period May 1, 1991 to July 31, 1991.

  7. Technical Progress of Rubber Additives%橡胶助剂技术进展

    Institute of Scientific and Technical Information of China (English)

    齐琳; 梁诚

    2013-01-01

    In this review, the development and application of rubber additives are presented, including antioxidant 4030, antioxidant 4050, accelerator TBSI and TBZTD, anti-reversion agent Perkalink900, peptizer, homogenizing agent and resorcinol resin. The technical progress of production processes of several rubber additives is reviewed, for example, 4-aminodiphenylamine from nitrobenzene, antioxidant DTPD from mixed amine, and thiazole accelerators through clean process. The growth of China rubber additive industry relies strongly on continuous technological innovation.%介绍防老剂4030和4050等防护体系助剂,促进剂TBSI和TBZTD、抗硫化返原剂Perkalink900等硫化体系助剂,以及塑解剂、均匀剂、间苯二酚树脂等加工助剂的开发和应用。综述对氨基二苯胺硝基苯法工艺、混合胺合成防老剂DTPD工艺、噻唑类促进剂清洁工艺等进展。我国橡胶助剂工业应不断科技创新,才能够做大做强。

  8. Isobutanol-methanol mixtures from synthesis gas. Quarterly technical progress report, 1 January--31 March 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-04-20

    A series of CuMgCeO{sub x} catalysts have been prepared. Range of Cu dispersion, determined by N{sub 2}O titration, was 19-48% and are among the highest reported in the literature for Cu-based methanol and higher alcohol synthesis catalysts. Kinetics of MeOH and EtOH coupling reactions on Cu/ZnO and K-Cu/MgO/CeO{sub 2} catalysts indicate that Cu promotes alcohol dehydrogenation. Acetaldehyde is a reactive intermediate. High-pressure isobutanol synthesis studies have been carried out on K- and Cs-promoted Cu/MgO/CeO{sub 2} catalysts. The K promoter is more active than Cs for CO conversion, but the Cs promoter activates the C{sub 1} to C{sub 2} step more effectively. Catalysts with high alkali loading resulted in low conversions. Temperature programmed surface reaction studies of MeOH, EtOH, and acetaldehyde on MgO/CeO{sub 2}-based Cu catalysts show evolution of acetone, crotonaldehyde, methyl ethyl ketone, H2, carbon oxides. Neither EtOH nor acetaldehyde produces propionaldehyde or 1- propanol, suggesting that these C{sub 3} species can only form via reactions involving C{sub 1} and C{sub 2} oxygenate species.

  9. Novel nanodispersed coal liquefaction catalysts: Molecular design via microemulsion-based synthesis. Final technical report, October 1990--December 1994

    Energy Technology Data Exchange (ETDEWEB)

    Osseo-Asare, K.; Boakye, E.; Vittal, M. [and others

    1995-04-01

    This report described the synthesis of Molybdenum Sulfides in microemulsions by acidification of ammonium tetrathiomolybdate. Molybdenum Sulfides have been shown to be potential coal liquefaction catalysts. The importance of particle size, temperature effects, and coal surface chemistry to impregnation are discussed.

  10. Catalysts and process developments for two-stage liquefaction. Final technical report, October 1, 1989--September 30, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Cronauer, D.C.; Swanson, A.J.; Sajkowski, D.J.

    1992-12-31

    Research in this project centered upon developing and evaluating catalysts and process improvements for coal liquefaction in the two-stage, close-coupled catalytic process. The major results are summarized here and they are described in more detail under each Task. In tasks for coal pretreatment and beneficiation, it was shown for coal handling that drying of both lignite or subbituminous coals using warm air, vacuum oven or exposing to air for long time was detrimental to subsequent liquefaction. Both laboratory and bench-scale beneficiations indicated that in order to achieve increased liquefaction yield for Illinois No. 6 bituminous coal, size separation with in sink-float technique should be used. For subbituminous coal, the best beneficiation was aqueous SO{sub 2} treatment, which reduced mineral matter. In the case of lignite, the fines should be rejected prior to aqueous SO{sub 2} treatment and sink-float gravity separation. In liquefying coals with supported catalysts in both first and second stages, coal conversion was highest (93%) with Illinois No. 6 coal, which also had the highest total liquid yield of 80%, however, the product contained unacceptably high level of resid (30%). Both low rank coals gave lower conversion (85--87%) and liquid yields (57--59%), but lighter products (no resid). The analysis of spent first stage catalysts indicated significant sodium and calcium deposits causing severe deactivation. The second stage catalysts were in better condition showing high surface areas and low coke and metal deposits. The use of dispersed catalyst in the first stage would combat the severe deactivation.

  11. Power systems development facility. Quarterly technical progress report, July 1--September 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    This quarterly technical progress report summarizes work completed during the Second Quarter of the Second Budget Period, July 1 through September 30, 1993, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scaleup of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the existing Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/Pressurized Circulating Fluidized Bed Gas Source. Hot Gas Cleanup Units to mate to all gas streams; Combustion Gas Turbine; and Fuel Cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during this reporting period was continuing the detailed design of the facility.

  12. Advanced Coal Conversion Process Demonstration Project. Final technical progress report, January 1, 1995--December 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1995 through December 31, 1995. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal Process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal Process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,5000 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. During this reporting period, the primary focus for the ACCP Demonstration Project team was to expand SynCoal market awareness and acceptability for both the products and the technology. The ACCP Project team continued to focus on improving the operation, developing commercial markets, and improving the SynCoal products as well as the product`s acceptance.

  13. Enzyme catalysts for a biotechnology-based chemical industry. Quarterly progress report, January 1--April 1, 1998

    Energy Technology Data Exchange (ETDEWEB)

    Arnold, F.H.

    1998-04-20

    The goal of this research is to engineer enzymes to be efficient and economically attractive catalysts for the chemical industry. The author is attempting to demonstrate generally-applicable approaches to enzyme improvement as well as develop specific catalysts for potential industrial application. The research is focused on the following areas: (1) Random mutagenesis of pNB esterase: improved activity and stability; (2) Directed evolution of subtilisin E to enhance thermostability; and (3) Methods for in vitro recombination.

  14. Configurational diffusion of asphaltenes in fresh and aged catalyst extrudates. Final technical report, September 20, 1991--September 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Guin, J.A.

    1998-12-31

    The overall objective of this project was to investigate the diffusion of coal and petroleum asphaltenes in the pores of a supported catalyst. Experimental measurements together with mathematical modeling was conducted to determine how the diffusion rate of asphaltenes, as well as some model compounds, depended on molecule sizes and shapes. The process of diffusion in the pores of a porous medium may occur by several mechanisms. Hindered diffusion occurs when the sizes of the diffusion molecules are comparable to those of the porous pores through which they are diffusing. Hindered diffusion phenomena have been widely observed in catalytic hydrotreatment of asphaltenes, heavy oils, coal derived liquids, etc. Pore diffusion limitations can be greater in spent catalysts due to the deposition of coke and metals in the pores. In this work, a general mathematical model was developed for the hindered diffusion-adsorption of solute in a solvent onto porous materials, e. g. catalysts, from a surrounding bath. This diffusion model incorporated the nonuniformities of pore structures in the porous media. A numerical method called the Method of Lines was used to solve the nonlinear partial differential equations resulting from the mathematical model. The accuracy of the numerical solution was verified by both a mass balance in the diffusion system and satisfactory agreement with known solutions in several special cases.

  15. Savannah River Plant, Works Technical Department monthly progress report for March 1956

    International Nuclear Information System (INIS)

    This document details activities of the Works Technical Department during the month of March 1956. It covers reactor technology, separations technology, engineering assistance and heavy water technology

  16. Savannah River Plant, Works Technical Department monthly progress report for March 1956

    Energy Technology Data Exchange (ETDEWEB)

    None

    1956-04-18

    This document details activities of the Works Technical Department during the month of March 1956. It covers reactor technology, separations technology, engineering assistance and heavy water technology.

  17. 介孔催化剂在烯烃歧化中的研究进展%Progress in the Mesoporous Catalysts for Olefin Metathesis

    Institute of Scientific and Technical Information of China (English)

    桑磊; 陈胜利; 袁桂梅; 李睿; 冯军伟; 郑敏

    2012-01-01

    主要介绍了近年来以介孔分子筛和介孔Al2O3为载体的介孔催化剂在烯烃歧化中的研究进展,包括介孔载体的合成、介孔催化剂的制备及其在烯烃歧化中的应用,并展望了介孔催化剂的发展前景.以介孔分子筛为载体的钨基和钼基催化剂以及以介孔 Al2O3为载体的铼基和钼基催化剂在烯烃歧化反应中,通常表现出比以普通SiO2和Al2O3为载体的相应催化剂更高的活性和选择性以及更长的使用寿命.%The recent progress in the heterogeneous catalysts with siliceous mesoporous molecular sieves or mesoporous alumina as supports for metathesis of olefins were reviewed, which included synthesis of the mesoporous supports, preparation of the catalysts and their application to the olefin metathesis. The future applications of the mesoporous catalysts to the olefin metathesis were discussed. The obtained results indicated that the siliceous mesoporous molecular sieves MCM-41, MCM-48, HMS and SBA-15 and mesoporous alumina supported WO3, MoO3 or Re2O, catalysts usually exhibited considerably higher activity, selectivity and working life-span in the olefin metathesis than those of the corresponding catalysts based on conventional silica or alumina support.

  18. Development of a solar desiccant dehumidifier. Volume 1. Summary. Volume 2. Detailed technical information. Technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Gunderson, M.E.; Hwang, K.C.; Railing, S.M.

    1978-03-31

    Research and development work aimed at the development of a solar desiccant dehumidifier is described in detail. The system features a rotary bed of granular silica gel and a rotary regenerator. The dehumidifier can be used for air conditioning through adiabatic saturation of the process airstream. Detailed technical information is presented in the appendices: (A) management, (B) review of the literature: state-of-the-art survey and SERI meeting, (C) review of the literature: adsorbent survey, (D) design requirements and evaluation criteria, (E) design requirements and evaluation criteria, single-family house model, (F) design requirements and evaluation criteria, economic model, (G) design requirements and evaluation criteria: conventional system models for comparison, (H) candidate cooling subsystems, (I) subsystem computer model, (J) subsystem performance map, and (K) subsystem preliminary design. (WHK)

  19. Learning Progressions: Tools for Assessment and Instruction for All Learners. Technical Report #1307

    Science.gov (United States)

    Sáez, Leilani; Lai, Cheng-Fei; Tindal, Gerald

    2013-01-01

    Conceptually, learning progressions hold promise for improving assessment and instruction by precisely outlining what students know and don't know at particular stages of knowledge and skill development. Based upon a synthesis of the literature, a rationale for the use of learning progressions maps to clarify how learning progresses in…

  20. Hydrogen production by supercritical water gasification of biomass. Phase 1 -- Technical and business feasibility study, technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-01

    The nine-month Phase 1 feasibility study was directed toward the application of supercritical water gasification (SCWG) for the economical production and end use of hydrogen from renewable energy sources such as sewage sludge, pulp waste, agricultural wastes, and ultimately the combustible portion of municipal solid waste. Unique in comparison to other gasifier systems, the properties of supercritical water (SCW) are ideal for processing biowastes with high moisture content or contain toxic or hazardous contaminants. During Phase I, an end-to-end SCWG system was evaluated. A range of process options was initially considered for each of the key subsystems. This was followed by tests of sewage sludge feed preparation, pumping and gasification in the SCW pilot plant facility. Based on the initial process review and successful pilot-scale testing, engineering evaluations were performed that defined a baseline system for the production, storage and end use of hydrogen. The results compare favorably with alternative biomass gasifiers currently being developed. The results were then discussed with regional wastewater treatment facility operators to gain their perspective on the proposed commercial SCWG systems and to help define the potential market. Finally, the technical and business plans were developed based on perceived market needs and the projected capital and operating costs of SCWG units. The result is a three-year plan for further development, culminating in a follow-on demonstration test of a 5 MT/day system at a local wastewater treatment plant.

  1. Deactivation by carbon of iron catalysts for indirect liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Bartholomew, C.H.

    1991-01-10

    Although promoted cobalt and iron catalysts for Fischer-Tropsch (FT) synthesis of gasoline feedstock were first developed more than three decades ago, a major technical problem still limiting the commercial use of these catalysts today is carbon deactivation. This report describes recent progress in a fundamental, three-year investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for FT synthesis, the objectives of which are to: determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation over a range of CO concentrations, CO:H{sub 2} ratios, and temperatures; and model the rates of deactivation of the same catalysts in fixed-bed reactors. To accomplish the above objectives, the project is divided into the following tasks: (1) determine the kinetics of reaction and of carbon deactivation during CO hydrogenation on Fe and Fe/K catalysts coated on monolith bodies. (2) Determine the reactivities and types of carbon deposited during reaction on the same catalysts from temperature-programmed-surface-reaction spectroscopy (TPSR) and transmission electron microscopy (TEM). Determine the types of iron carbides formed at various temperatures and H{sub 2}/CO ratios using x-ray diffraction and Moessbauer spectroscopy. (3) Develop mathematical deactivation models which include heat and mass transport contributions for FT synthesis is packed-bed reactors. Progress to date is described. 48 refs., 3 figs., 1 tab.

  2. Exxon catalytic coal gasification process development program. Quarterly technical progress report, January 1-March 31, 1979

    Energy Technology Data Exchange (ETDEWEB)

    1979-05-01

    This report covers the activites for the Exxon Catalytic Coal Gasification Development Program during the quarter January 1-March 31, 1979. Construction of a bench apparatus to study reactions of product and recycle gas in furnace and heat exchanger tubes was completed and checkout of the apparatus was begun. A Startup and Initial Operation Schedule, a Checkout Test Plan, and an Initial Startup Plan were developed for the Process Develoment Unit (PDU). The PDU will be started up in a sequential manner, with the gasification system being started up on a once-through basis first. The gas separation system will be started up next, followed by the catalyst recovery system. The programmable controller, which handles valve sequencing, alarming, and other miscellaneous functions on the PDU, was programmed and checkout was completed on the coal feed, gas feed, and filter systems. Work continued on defining the cause of the breakdown of char and lime during digestion in the prototype catalyst recovery unit. It was concluded that both the lime and char particles are fragile and will break down to fines if handled roughly. Removal of the potassium from the char by water washing does not cause the char particles to disintegrate. The perferred processing sequence for catalyst recovery in the PDU has been identified. Bench scale tests confirmed that the change in catalyst from K/sub 2/CO/sub 3/ to KOH was not responsible for the differences in fluidized bed densities between the present and the predevelopment operations of the FBG. Work was completed on a revised offsites facilities definition and cost estimate to update the CCG Commercial Plant Study Design prepared during the predevelopment program.

  3. Methane coupling by membrane reactor. Quarterly technical progress report, September 25, 1995--December 24, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-15

    The performance of the third type of catalytic membrane reactor configuration, with catalyst deposited in the membrane and no catalyst or inert materials in the tube side, was evaluated. The C{sub 2} selectivity obtained was about 10% due to the gas phase reaction in the empty tube side of the reactor. The membrane reactor with an oxygen-permeable dense membrane has been built. The use of a dense membrane will eliminate the loss of hydrocarbon from the tube side to the shell side, as observed in the Vycor glass membrane reactor. Also, air can be used as the oxygen source without contaminating the product. La/MgO was synthesized and will be used as the catalyst for the dense membrane reactor. This catalyst was reported in the literature to show significant improvement of C{sub 2} selectivity and yield for oxidative coupling of methane in a packed-bed reactor by using the operation mode of staged-feed of oxygen. A reactor mode for methane oxidative coupling in reactors with both distributed oxygen feed and C{sub 2} product removal was developed based on the general model of cross-flow reactors reported in the last quarterly report. A distributed oxygen feed could give rise to much higher C{sub 2} yield than the co-feed reactor as long as the space time is long enough. In the case of a two-membrane reactor, where oxygen is supplied by one membrane and products are removed through the other membrane, a high separation factor of C{sub 2} product to methane for the product-removal membrane is critical to achieve high C{sub 2} yield.

  4. Savannah River Plant Works Technical Department progress report, July 1960: Deleted Version

    Energy Technology Data Exchange (ETDEWEB)

    1960-08-17

    This progress report by the Atomic Energy Division of the Savannah River Plant covers: Reactor Technology; Separation Technology; Engineering Assistance; Health Physics; and General Laboratory work. (JT)

  5. Savannah River Plant Works Technical Department monthly progress report for May 1958: Deleted Version

    Energy Technology Data Exchange (ETDEWEB)

    1958-06-17

    This progress report by the Atomic Energy Division of the Savannah River Plant covers: Reactor Technology; Separation Technology; Engineering Assistance; Health Physics; and General Laboratory Work. (JT)

  6. Savannah River Ecology Laboratory, Annual Technical Progress Report of Ecological Research, June 30, 2002

    International Nuclear Information System (INIS)

    The Savannah River Ecology Laboratory (SREL) is a research unit of The University of Georgia (UGA) and has been conducting ecological research on the Savannah River Site (SRS) near Aiken, South Carolina for 50 years. The overall mission of the Laboratory is to acquire and communicate knowledge of ecological processes and principles. SREL conducts fundamental and applied ecological research, as well as education and outreach programs, under a Cooperative Agreement with the U.S. Department of Energy (DOE). The Laboratory's research mission during the 2002 fiscal year was fulfilled with the publication of 76 journal articles and book chapters by faculty, technical staff, students, and visiting scientists. An additional 50 journal articles have been submitted or are in press. Other noteworthy events took place as faculty members, staff, and graduate students received awards. These are described in the section titled Special Accomplishments of Faculty, Staff, Students, and Administration on page 51. Notable scientific accomplishments include work conducted on contaminant transport, stable isotopes, sandhills ecology, and phytoremediation: (1) A collaborative study between Dr. Tom Hinton at SREL and scientists at SRTC demonstrated the feasibility of using illite clay to sequester 137Cs in sediments along the P and R reactor cooling canal system, where approximately 3, 000 acres of land are contaminated. Overall, the study showed significant decreases in cesium concentrations and bioavailability following the addition of illite with no sign of harm to the ecosystem. While the cesium remains sequestered from the biosphere, its radioactivity decays and the process progresses from contaminant immobilization to remediation. (2) SREL's stable isotope laboratory is now fully functional. Stable isotope distributions in nature can provide important insights into many historical and current environmental processes. Dr. Christopher Romanek is leading SREL's research in this area

  7. Savannah River Ecology Laboratory, Annual Technical Progress Report of Ecological Research, June 30, 2002

    Energy Technology Data Exchange (ETDEWEB)

    Paul M. Bertsch, (Director)

    2002-06-30

    The Savannah River Ecology Laboratory (SREL) is a research unit of The University of Georgia (UGA) and has been conducting ecological research on the Savannah River Site (SRS) near Aiken, South Carolina for 50 years. The overall mission of the Laboratory is to acquire and communicate knowledge of ecological processes and principles. SREL conducts fundamental and applied ecological research, as well as education and outreach programs, under a Cooperative Agreement with the U.S. Department of Energy (DOE). The Laboratory's research mission during the 2002 fiscal year was fulfilled with the publication of 76 journal articles and book chapters by faculty, technical staff, students, and visiting scientists. An additional 50 journal articles have been submitted or are in press. Other noteworthy events took place as faculty members, staff, and graduate students received awards. These are described in the section titled Special Accomplishments of Faculty, Staff, Students, and Administration on page 51. Notable scientific accomplishments include work conducted on contaminant transport, stable isotopes, sandhills ecology, and phytoremediation: (1) A collaborative study between Dr. Tom Hinton at SREL and scientists at SRTC demonstrated the feasibility of using illite clay to sequester 137Cs in sediments along the P and R reactor cooling canal system, where approximately 3,000 acres of land are contaminated. Overall, the study showed significant decreases in cesium concentrations and bioavailability following the addition of illite with no sign of harm to the ecosystem. While the cesium remains sequestered from the biosphere, its radioactivity decays and the process progresses from contaminant immobilization to remediation. (2) SREL's stable isotope laboratory is now fully functional. Stable isotope distributions in nature can provide important insights into many historical and current environmental processes. Dr. Christopher Romanek is leading SREL's research

  8. High-Efficiency Nitride-Based Solid-State Lighting. Final Technical Progress Report

    International Nuclear Information System (INIS)

    In this final technical progress report we summarize research accomplished during Department of Energy contract DE-FC26-01NT41203, entitled ''High-Efficiency Nitride-Based Solid-State Lighting''. Two teams, from the University of California at Santa Barbara (Principle Investigator: Dr. Shuji Nakamura) and the Lighting Research Center at Rensselaer Polytechnic Institute (led by Dr. N. Narendran), pursued the goals of this contract from thin film growth, characterization, and packaging/luminaire design standpoints. The UCSB team initially pursued the development of blue gallium nitride (GaN)-based vertical-cavity surface-emitting lasers, as well as ultraviolet GaN-based light emitting diodes (LEDs). In Year 2, the emphasis shifted to resonant-cavity light emitting diodes, also known as micro-cavity LEDs when extremely thin device cavities are fabricated. These devices have very directional emission and higher light extraction efficiency than conventional LEDs. Via the optimization of thin-film growth and refinement of device processing, we decreased the total cavity thickness to less than 1 (micro)m, such that micro-cavity effects were clearly observed and a light extraction efficiency of over 10% was reached. We also began the development of photonic crystals for increased light extraction, in particular for so-called ''guided modes'' which would otherwise propagate laterally in the device and be re-absorbed. Finally, we pursued the growth of smooth, high-quality nonpolar a-plane and m-plane GaN films, as well as blue light emitting diodes on these novel films. Initial nonpolar LEDs showed the expected behavior of negligible peak wavelength shift with increasing drive current. M-plane LEDs in particular show promise, as unpackaged devices had unsaturated optical output power of ∼ 3 mW at 200 mA drive current. The LRC's tasks were aimed at developing the subcomponents necessary for packaging UCSB's light emitting diodes, and packaging them to produce a white light

  9. Enhanced catalysis by solvent improvement. Quarterly technical progress report, 1 April-30 June 1983

    Energy Technology Data Exchange (ETDEWEB)

    Garg, D.; Miller, R.N.; Givens, E.N.; Tarrer, A.R.; Guin, J.A.; Curtis, C.W.

    1983-11-01

    This report describes the results from liquefaction solvent modification, coal liquefaction with original and modified solvents, catalyst selection, coal pretreatment, and pretreatment followed by liquefaction experiments. The effect of liquefaction reaction conditions on product distribution is also covered in this report. Significant removal of nitrogen compounds from coal-derived liquefaction solvent was obtained by treating it with anhydrous hydrochloric acid or silica gel. The removal of nitrogen compounds with HCl or silica gel was also accompanied by 25 to 40% removal of oxygen compounds. Treating liquefaction solvent with aqueous NaOH or zeolite removed significant amounts of phenolic compounds. Oxygen removal was also accompanied by a partial removal of nitrogen compounds. Sequential treatment of coal-derived liquefaction solvent with HCl followed by silica gel or NaOH followed by HCl resulted in complete removal of nitrogen compounds. Liquefying coals in the presence of coal-derived liquefaction solvents modified by the removal of nitrogen or oxygen compounds or both significantly increased the oil yield in the absence of catalyst. The overall coal conversion, however, decreased only slightly with these treated solvents. A significant increase in the oil yield was also noted during catalytic liquefaction with the pretreated solvents. The overall coal conversion also increased during catalytic liquefaction of coal. At a concentration level of 250 ppM metal based on coal molybdenum catalyst was more active than nickel. At this level the activity of molybdenum was also higher than that noted with 1 wt% iron or zinc. Combination of metals such as iron and molybdenum or zinc and molybdenum yielded significantly higher oil yield compared to individual metals alone. 1 ref., 2 figs., 28 tabs.

  10. Hydrodynamic models for slurry bubble column reactors. Fourth technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Gidaspow, D.

    1995-07-01

    The objective of this investigation is to convert our ``learning gas-solid-liquid`` fluidization model into a predictive design model. The IIT hydrodynamic model computes the phase velocities and volume fractions of gas, liquid and particulate phases. Model verification involves a comparison of these computed velocities and volume fractions to experimental values. The simulation of Air Product methanol reactors described in this paper are continuing. Granular temperatures and viscosities have been computed. Preliminary measurements of granular temperatures using the Air Product catalysts were obtained using our CCD camera.

  11. Studies relevant to the catalytic activation of carbon monoxide. Technical progress report, September 1991

    Energy Technology Data Exchange (ETDEWEB)

    Ford, P.C.

    1992-06-04

    Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.

  12. THE OPTIMAL ALLOCATION ABOUT CAPITAL AND LABOR IN THE ECONOMIC GROWTH WITH AN ENDOGENOUS TECHNICAL PROGRESS MODEL

    Institute of Scientific and Technical Information of China (English)

    刘金山; 李楚霖; 胡适耕

    2002-01-01

    In this paper, the balanced economic growth path was considered in a new growth model with endogenous technical progress. It is not only obtained the optimal allocation about capital and labor between a goods-producing sector and a R&D Sector,but also the optimal value of saving rates. By discussing the effect of parameters, it are also got the following results: When the rate of time preference (discount factor) rising, the fractions of Capital and labor in the goods-producing sector will increase , the fractions in R&D sector and the saving rates will decrease; When the population grows rapidly, the result will be contrary.

  13. GT-MHR COMMERCIALZATION STUDY. TECHNICAL PROGRESS AND COST MANAGEMENT REPORT FOR THE PERIOD MAY 1 THROUGH MAY 31, 2003

    International Nuclear Information System (INIS)

    A271 GT-MHR COMMERCIALZATION STUDY TECHNICAL PROGRESS AND COST MANAGEMENT REPORT FOR THE PERIOD MAY 1 THROUGH MAY 31, 2003. Petten advised GA the start of the HFR-EU2 irradiation is being delayed until late July 2004. HFR-EU1 (pebble fuel) is also delayed until February/March 2004. The reason for the delays was implementation of new financial regulations at Petten that delayed the contracts for capsule fabrication. Review of the MHR-2 Fuel Product Specification was completed. Revision of the specification to incorporate the review results is in progress. Detailed test matrices have been drafted for capsule irradiation tests and for post-irradiation heating tests proposed for development and qualification of advanced coated-particle fuels capable of meeting anticipated VHTR fuel performance requirements

  14. Measurements of scattering processes in negative ion - atom collisions. Technical progress report - year 1, April 1, 1995--March 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Kvale, T.J.

    1995-12-01

    This Technical Progress Report describes the progress made on the research objectives during the past twelve months. The objective of this research project is to provide absolute cross section measurements of various scattering processes which occur in negative ion collisions with atomic (specifically, noble gas and atomic hydrogen) targets at intermediate energies. These processes include: elastic scattering, single- and double-electron detachment, and target-inelastic processes of excitation and ionization. Total cross sections for single- and double-electron detachment were recently published in Physical Review A from this research project. The researchers were successful this past year in acquiring the first cross section measurements of target excitation for H{sup -} impact on helium target atoms.

  15. Proceedings of the technical review on advances in geothermal reservoir technology---Research in progress

    Energy Technology Data Exchange (ETDEWEB)

    Lippmann, M.J. (ed.)

    1988-09-01

    This proceedings contains 20 technical papers and abstracts describing most of the research activities funded by the Department of Energy (DOE's) Geothermal Reservoir Technology Program, which is under the management of Marshall Reed. The meeting was organized in response to several requests made by geothermal industry representatives who wanted to learn more about technical details of the projects supported by the DOE program. Also, this gives them an opportunity to personally discuss research topics with colleagues in the national laboratories and universities.

  16. EDS coal liquefaction process development: Phase V. Final technical progress report, Volume I

    Energy Technology Data Exchange (ETDEWEB)

    None

    1984-02-01

    All objectives in the EDS Cooperative Agreement for Phases III-B through V have been achieved for the RCLU pilot plants. EDS operations have been successfully demonstrated in both the once-through and bottoms recycle modes for coals of rank ranging from bituminous to lignitic. An extensive data base detailing the effects of process variable changes on yields, conversions and product qualities for each coal has been established. Continuous bottoms recycle operations demonstrated increased overall conversion and improved product slate flexibility over once-through operations. The hydrodynamics of the liquefaction reactor in RCLU were characterized through tests using radioactive tracers in the gas and slurry phases. RCLU was shown to have longer liquid residence times than ECLP. Support work during ECLP operations contributed to resolving differences between ECLP conversions and product yields and those of the small pilot plants. Solvent hydrogenation studies during Phases IIIB-V of the EDS program focused on long term activity maintenance of the Ni-MO-10 catalyst. Process variable studies for solvents from various coals (bituminous, subbituminous, and lignitic), catalyst screening evaluations, and support of ECLP solvent hydrogenation operations. Product quality studies indicate that highly cyclic EDS naphthas represent unique and outstanding catalytic reforming feedstocks. High volumes of high octane motor gasoline blendstock are produced while liberating a considerable quantity of high purity hydrogen.

  17. Solar thermal hydrogen production process. Annual technical progress report, January-December, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Parker, G.H.

    1979-01-01

    Westinghouse is currently under contract to DOE for technology development of the Sulfur Cycle, a hybrid thermochemical-electrochemical process for the production of hydrogen and oxygen from water. Operational studies have been conducted and have resulted in definitions of operating modes for solar/hydrogen plants and in assessments of the day/night and annual variations in performance that will influence the operating modes and the sizing of plant subsystems. Conceptual design studies have been conducted for process components that interface with the solar receiver. From related trade-off studies, a preferred configuration emerged that involves an intermediate working fluid (e.g., hot gas) between the solar receiver and the sulfuric acid decomposition reactor. The design of the reactor has been based on a shell and tube type heat exchanger configuration with catalyst placement on the shell side. A number of candidate materials for structural use in the acid decomposition reactor also have been evaluated experimentally. Screening tests and endurance tests with potential catalysts (to accelerate the rate of sulfur trioxide cracking) have been conducted with encouraging results. Approximately three dozen candidate materials for use in constructing the acid vaporizer have been tested for corrosion resistance to the expected environment. Detailed discussions of the results obtained during 1979 are presented.

  18. University of Florida, University research program in robotics. Annual technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Crane, C.D. III; Tulenko, J.S.

    1994-05-01

    Progress is reported in the areas of environmental hardening, database, world modeling, vision, man-machine interface, advanced liquid metal reactor inspection robot, and articulated transporter/manipulator system (ATMS) development.

  19. University of Florida, University research program in robotics. Annual technical progress report

    International Nuclear Information System (INIS)

    Progress is reported in the areas of environmental hardening, database, world modeling, vision, man-machine interface, advanced liquid metal reactor inspection robot, and articulated transporter/manipulator system (ATMS) development

  20. Advanced thermal barrier coating system development. Technical progress report, March 1, 1997--May 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-06-13

    Objectives of this program are to provide an improved thermal barrier coating system with improved reliability and temperature capability. This report describes progress in manufacturing, bonding, deposition, non-destructive evaluation, repair, and maintenance.

  1. Information and Communications Technical Support Services to the Office of Environment, Safety, and Health. Progress report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-12-01

    Progress is reported on the following tasks: development of safety publications, conference support, planning and reporting, MORT A/I video, print products, special graphics, and SAFE software development.

  2. Amarillo National Resource Center for Plutonium. Quarterly technical progress report, May 1, 1997--July 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-09-01

    Progress summaries are provided from the Amarillo National Center for Plutonium. Programs include the plutonium information resource center, environment, public health, and safety, education and training, nuclear and other material studies.

  3. Theoretical particle physics. Technical progress report, May 1, 1985-April 30, 1986

    International Nuclear Information System (INIS)

    Research activities during this past year included theoretical work in lattice gauge theory, EMC effect, supersymmetry and supergravity, weak interactions including CP violation, and superstrings. Progress in all these areas is reported

  4. High energy physics. Technical progress report, November 1, 1982 - October 25, 1983

    International Nuclear Information System (INIS)

    Progress is reported in the following areas: quantum field theory, gauge theories, dynamical symmetry breaking, supersymmetry, magnetic monopoles, cosmology and particle physics, and phenomenological studies. 34 publications under this contract are listed

  5. Research in elementary particle physics. Technical progress report, June 1, 1983-May 31, 1984

    International Nuclear Information System (INIS)

    Under this contract, research has been performed on both the theoretical and experimental properties of elementary particles. A brief description of the work which is either in progress or has been completed is given. Publications are listed

  6. Technical progress report for the quarter 1 October-31 December 1980

    Energy Technology Data Exchange (ETDEWEB)

    1981-01-01

    This report describes the technical accomplishments on the commercial nuclear waste management programs and on the geologic disposal of nuclear wastes. The program is organized into eight tasks: systems, waste package, site, repository, regulatory and institutional, test facilities and excavations, land acquisition, and program management. (DLC)

  7. Developing Technical Writing Skills in the Physical Chemistry Laboratory: A Progressive Approach Employing Peer Review

    Science.gov (United States)

    Gragson, Derek E.; Hagen, John P.

    2010-01-01

    Writing formal "journal-style" lab reports is often one of the requirements chemistry and biochemistry students encounter in the physical chemistry laboratory. Helping students improve their technical writing skills is the primary reason this type of writing is a requirement in the physical chemistry laboratory. Developing these skills is an…

  8. Atmospheric Effects of Nuclear Energy Centers (AENEC) Program. Annual technical progress report, July 1975--September 1976

    Energy Technology Data Exchange (ETDEWEB)

    Patrinos, A. A.; Hoffman, H. W. [comps.

    1977-04-01

    The Technical Memorandum contains information of a preliminary nature from the six participants of the Program describing their activities and presenting the results obtained during the reporting period. The birth of the Program, its definition and evolution are described, and a complete breakdown of responsibilities and tasks assigned to the six AENEC participants is presented.

  9. Association Euratom - DTU, Technical University of Denmark, Department of Physics - Annual Progress Report 2012

    DEFF Research Database (Denmark)

    The programme of the Research Unit of the Fusion Association Euratom – DTU, Technical University of Denmark covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction with the plasma equilibrium...

  10. Association Euratom - DTU, Technical University of Denmark, Department of Physics - Annual Progress Report 2013

    DEFF Research Database (Denmark)

    The programme of the Research Unit of the Fusion Association Euratom – DTU, Technical University of Denmark covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction with the plasma equilibrium...

  11. Technical progress report for the quarter 1 October-31 December 1980

    International Nuclear Information System (INIS)

    This report describes the technical accomplishments on the commercial nuclear waste management programs and on the geologic disposal of nuclear wastes. The program is organized into eight tasks: systems, waste package, site, repository, regulatory and institutional, test facilities and excavations, land acquisition, and program management

  12. Atmospheric Effects of Nuclear Energy Centers (AENEC) Program. Annual technical progress report, July 1975--September 1976

    International Nuclear Information System (INIS)

    The Technical Memorandum contains information of a preliminary nature from the six participants of the Program describing their activities and presenting the results obtained during the reporting period. The birth of the Program, its definition and evolution are described, and a complete breakdown of responsibilities and tasks assigned to the six AENEC participants is presented

  13. Advanced thermally stable jet fuels. Technical progress report, January 1995--March 1995

    Energy Technology Data Exchange (ETDEWEB)

    Schobert, H.H.; Eser, S.; Song, C. [and others

    1995-06-01

    Quantitative structure-property relationships have been applied to study the thermal stability of pure hydrocarbons typical of jet fuel components. A simple method of chemical structure description in terms of Benson groups was tested in searching for structure-property relationships for the hydrocarbons tested experimentally in this program. Molecular connectivity as a structure-based approach to chemical structure-property relationship analysis was also tested. Further development of both the experimental data base and computational methods will be necessary. Thermal decomposition studies, using glass tube reactors, were extended to two additional model compounds: n-decane and n-dodecane. Efforts on refining the deposit growth measurement and characterization of suspended matter in stressed fuels have lead to improvements in the analysis of stressed fuels. Catalytic hydrogenation and dehydrogenation studies utilizing a molybdenum sulfide catalyst are also described.

  14. Progress in Diesel Oxidation Catalysts%柴油车氧化催化技术研究进展

    Institute of Scientific and Technical Information of China (English)

    王建强; 王远; 刘双喜; 高继东; 马杰; 高海洋

    2012-01-01

    Tightening emission standards for heavy-duty in use diesel required a new effective diesel emission control system. Since 1989, Diesel Oxidation Catalysts (DOCs) have been adopted by Diesel passenger vehicles in Europe and a number of studies on the use of such catalysts to meet current legislation limits have been published. The primary purposes are oxidation of CO, unburned hydrocarbons, and NO, while active hydrocarbon oxidation could be also used to generate exotherms required for downstream components. The main advances for catalysts in the last decade are systematically reviewed. Special attentions are given to the structure of DOCs, fundamental reaction, and the DOCs catalysts deactivation and regeneration. DOCs consist of case package, monolith, damping layer, and catalysts. The precious metal component of the catalyst is typically regarded as the active site for the reaction. The most common precious metals used for DOCs are Pt and Pd. Catalyst deactivation is becoming a constant concern for catalytic converters, because it is a natural phenomenon caused by several methods, including sintering of active sites, poisoning by sulfurous compounds, and washcoat covered by carbon oxidation products. At last, the development tendency for DOC technology is proposed.%柴油车氧化催化剂(DOC)主要作用在于氧化尾气中的CO、碳氢化合物(HC)和NOx;此外,氧化过程产生一定的热量,有助于下游组分的起燃.本文综述了近年来柴油车氧化催化技术的研究进展.柴油车氧化催化器由壳体、减振层、载体及催化剂四部分构成,其中催化剂是整个催化器的核心部分,决定着DOC的主要性能指标.DOC常用的活性组分有铂、铑和钯等贵金属,助剂为铈、镧等稀土元素和铜、铁、铬、锰等过渡金属,以及碱金属和碱土金属氧化物.本文论述了柴油车氧化催化技术反应过程原理, 包括CO氧化、HC氧化和NOx氧化反应机理;对柴油车氧化催化

  15. Microwave plasma source for neutral-beam injection systems. Quarterly technical progress report

    International Nuclear Information System (INIS)

    The overall program is described and the technical and programmatic reasons for the decision to pursue both the RFI and ECH sources into the current hydrogen test stage is discussed. We consider the general characteristics of plasma sources in the parameter regime of interest for neutral beam applications. The operatonal characteristics, advantages and potential problems of RFI and ECH sources are discussed. In these latter two sections we rely heavily on experience derived from developing RFI and ECH ion engine sources for NASA

  16. Experimental Program Final Technical Progress Report: 15 February 2007 to 30 September 2012

    Energy Technology Data Exchange (ETDEWEB)

    Kinney, Edward R. [University of Colorado, Boulder, CO

    2014-09-12

    This is the final technical report of the grant DE-FG02-04ER41301 to the University of Colorado at Boulder entitled "Intermediate Energy Nuclear Physics" and describes the results of our funded activities during the period 15 February 2007 to 30 September 2012. These activities were primarily carried out at Fermilab, RHIC, and the German lab DESY. Significant advances in these experiments were carried out by members of the Colorado group and are described in detail.

  17. Amarillo National Resource Center for Plutonium. Quarterly technical progress report, November 1, 1997--January 31, 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This report provides information on projects conducted by the Amarillo National Resource Center for Plutonium, a consortium of Texas A&M University, Texas Tech University, and the University of Texas. Progress is reported for four major areas: (1) plutonium information resource; (2) environmental, safety, and health; (3) communication, education, training, and community involvement; and (4) nuclear and other material studies. Environmental, safety, and health projects reported include a number of studies on high explosives. Progress reported for nuclear material studies includes storage and waste disposal investigations.

  18. Research progress in CO2 methanation catalysts%二氧化碳甲烷化催化剂的研究进展

    Institute of Scientific and Technical Information of China (English)

    崔凯凯; 周桂林; 谢红梅

    2015-01-01

    CO2 methanation is one of the effective ways to realize resource recycling on greenhouse gas,CO2. This article was aimed to review the research progress in catalysts for catalytic CO2 hydrogenation to produce methane in the past few years. The Ni-based catalysts were widely studied in literature. The effects of Al2O3,SiO2 and La2O3 supports and CeO2,La2O3 additives on the performance of Ni-based CO2 methanation catalysts were mainly introduced,together with the effects of the structures , electronic performances and chemical properties of supports and additives on the performance of the Ni-based methanation catalysts. The Co-based CO2 methanation catalysts with ordered mesoporous structures also exhibited superior catalytic activities comparing with the studied Ni-based CO2 methanation catalysts. The results indicated that the novel structure was also a key factor to affect the catalytic performance of catalytic CO2 methanation. And CO2 methanation performance at low temperature can be improved by the modulation of catalyst structures and composition,which could lay a foundation for the industrialization of CO2 methanation process.%CO2催化加氢甲烷化反应是温室气体 CO2资源化利用的有效途径之一。本文回顾了 CO2催化加氢甲烷化催化剂的研究现状,其中 Ni基催化剂是研究最为广泛的CO2甲烷化催化剂。重点介绍了 Al2O3、SiO2和La2O3载体及CeO2和La2O3助剂等对Ni基催化剂CO2甲烷化性能的影响,阐述了载体的结构、电子性能、化学性能和助剂等对Ni基催化剂CO2甲烷化性能的影响。结合几种非Ni基CO2甲烷化催化剂的对比研究发现,具有有序介孔结构的Co基催化剂也表现出了优越的CO2甲烷化性能。由此表明,催化剂新颖的结构也是影响CO2甲烷化性能的重要因素,通过催化剂结构、组成等的调变,能实现 CO2低温高效甲烷化,为 CO2甲烷化工业化进程奠定基础。

  19. Accelerator research studies: Technical progress report, June 1, 1988--May 31, 1989

    International Nuclear Information System (INIS)

    This report discusses research progress in the following general topics: Study of transport and longitudinal compression of intense, high-brightness beams; study of collective ion acceleration by intense electron beams and pulse powered plasma focus; and study of microwave sources and parameter scaling for high-frequency electron-positron supercollider linacs

  20. Projects at the Western Environmental Technology Office. Quarterly technical progress report, January 1--March 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-01

    This quarterly report briefly describes recent progress in eight projects. The projects are entitled Biomass Remediation Project; Heavy Metal-Contaminated Soil Project; MHD Shutdown; Mine Waste Technology Program; Plasma Projects; Resource Recovery Project; Spray Casting Project; and Watervliet Arsenal Project.

  1. Savannah River Ecology Laboratory annual technical progress report of ecological research, period ending July 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Vaitkus, M.R.; Wein, G.R. [eds.; Johnson, G.

    1993-11-01

    This progress report gives an overview of research programs at the Savannah River Site. Topics include; environmental operations support, wood stork foraging and breeding, defense waste processing, environmental stresses, alterations in the environment due to pollutants, wetland ecology, biodiversity, pond drawdown studies, and environmental toxicology.

  2. Experimental studies of elementary particle interactions at high energies: Technical progress report

    International Nuclear Information System (INIS)

    This paper discusses progress of experiments at CERN and Fermilab. At CERN, data accumulation and analysis is discussed for the UA-6 experiment, which involves proton-antiproton collisions. At Fermilab, the testing of a collider detector for the Tevatron is discussed

  3. Chemistry of gaseous lower-valent actinide halides. Technical progress report

    International Nuclear Information System (INIS)

    Objective is to provide thermochemical data for key actinide halide and oxyhalide systems. Progress is reported on bond dissociation energies of gaseous ThCl4, ThCl3, ThCl2, and ThCl; bond dissociation energies of ruthenium fluorides; and mass spectroscopy of UF6

  4. Energy conservation in citrus processing. Technical progress report No. 2, April 1, 1980-February 28, 1981

    Energy Technology Data Exchange (ETDEWEB)

    Leo, M.A.; Lari, R.I.; Moore, N.R.; Broussard, M.R.; Gyamfi, M.

    1981-03-15

    Systems that reduce energy usage and are economically viable in the citrus fruit processing industry are identified. The preliminary results of Phase I are presented. Alternative systems to be considered are classified and denoted as central, modular, integrated, and combined. Progress is reported on the central and modular systems. (MCW)

  5. Dissolved organic matter and lake metabolism. Technical progress report, 1 July 1975--30 June 1976

    Energy Technology Data Exchange (ETDEWEB)

    Wetzel, R. G.

    1976-01-01

    Progress is reported in the following areas of research: interactions of dissolved organic matter with inorganic nutrient cycling; regulation of the photosynthetic and decompositional metabolism of micro- and macroflora; regulatory mechanisms of growth and rates of carbon cycling; and fate of detrital dissolved and particulate organic matter. (HLW)

  6. Capture and isotopic exchange method for water and hydrogen isotopes on zeolite catalysts up to technical scale for pre-study of processing highly tritiated water

    International Nuclear Information System (INIS)

    Highly tritiated water (HTW) may be generated at ITER by various processes and, due to the excessive radio toxicity, the self-radiolysis and the exceedingly corrosive property of HTW, a potential hazard is associated with its storage and process. Therefore, the capture and exchange method for HTW utilizing Molecular Sieve Beds (MSB) was investigated in view of adsorption capacity, isotopic exchange performance and process parameters. For the MSB, different types of zeolite were selected. All zeolite materials were additionally coated with platinum. The following work comprised the selection of the most efficient zeolite candidate based on detailed parametric studies during the H2/D2O laboratory scale exchange experiments (about 25 g zeolite per bed) at the Tritium Laboratory Karlsruhe (TLK). For the zeolite, characterization analytical techniques such as Infrared Spectroscopy, Thermogravimetry and online mass spectrometry were implemented. Followed by further investigation of the selected zeolite catalyst under full technical operation, a MSB (about 22 kg zeolite) was processed with hydrogen flow rates up to 60 mol*h-1 and deuterated water loads up to 1.6 kg in view of later ITER processing of arising HTW. (authors)

  7. Capture and isotopic exchange method for water and hydrogen isotopes on zeolite catalysts up to technical scale for pre-study of processing highly tritiated water

    Energy Technology Data Exchange (ETDEWEB)

    Michling, R.; Braun, A.; Cristescu, I.; Dittrich, H.; Gramlich, N.; Lohr, N. [Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen (Germany); Glugla, M.; Shu, W.; Willms, S. [ITER Organization, Saint-Paul-lez-Durance (France)

    2015-03-15

    Highly tritiated water (HTW) may be generated at ITER by various processes and, due to the excessive radio toxicity, the self-radiolysis and the exceedingly corrosive property of HTW, a potential hazard is associated with its storage and process. Therefore, the capture and exchange method for HTW utilizing Molecular Sieve Beds (MSB) was investigated in view of adsorption capacity, isotopic exchange performance and process parameters. For the MSB, different types of zeolite were selected. All zeolite materials were additionally coated with platinum. The following work comprised the selection of the most efficient zeolite candidate based on detailed parametric studies during the H{sub 2}/D{sub 2}O laboratory scale exchange experiments (about 25 g zeolite per bed) at the Tritium Laboratory Karlsruhe (TLK). For the zeolite, characterization analytical techniques such as Infrared Spectroscopy, Thermogravimetry and online mass spectrometry were implemented. Followed by further investigation of the selected zeolite catalyst under full technical operation, a MSB (about 22 kg zeolite) was processed with hydrogen flow rates up to 60 mol*h{sup -1} and deuterated water loads up to 1.6 kg in view of later ITER processing of arising HTW. (authors)

  8. Measurements of scattering processes in negative ion-atom collisions. Technical progress report, 1 September 1991--31 August 1992

    Energy Technology Data Exchange (ETDEWEB)

    Kvale, T.J.

    1992-04-01

    This Technical Progress Report describes the progress made on the research objectives during the past twelve months. This research project is designed to provide measurements of various scattering processes which occur in H{sup {minus}} collisions with atomic (specifically, noble gas and atomic hydrogen) targets at intermediate energies. These processes include: elastic scattering,single- and double-electron detachment, and target excitation/ionization. For the elastic and target inelastic processes where H{sup {minus}} is scattered intact, the experimental technique of Ion Energy-Loss Spectroscopy (IELS) will be employed to identify the final target state(s). In most of the above processes, cross sections are unknown both experimentally and theoretically. The measurements in progress will provide either experimentally-determined cross sections or set upper limits to those cross sections. In either case, these measurements will be stringent tests of our understanding in energetic negative ion-atom collisions. This series of experiments required the construction of a new facility and the initial ion beam was accelerated through the apparatus in April 1991.

  9. Measurements of scattering processes in negative ion-atom collisions. Technical progress report, 1 September 1992--31 August 1993

    Energy Technology Data Exchange (ETDEWEB)

    Kvale, T.J.

    1993-05-01

    This Technical Progress Report describes the progress made on the research objectives during the past twelve months. This research project is designed to provide measurements of various scattering processes which occur in H{sup {minus}} collisions with atomic (specifically, noble gas and atomic hydrogen) targets at intermediate energies. These processes include elastic scattering, single- and double-electron detachment, and target excitation/ionization. For the elastic and target inelastic processes where H{sup {minus}} is scattered intact, the experimental technique of Ion Energy-Loss Spectroscopy (IELS) will be employed to identify the final target state(s). In most of the above processes, cross sections are unknown both experimentally and theoretically. The measurements in progress will provide either experimentally determined cross sections or set upper limits to those cross sections. In either case, these measurements will be stringent tests of our understanding in energetic negative ion - atom collisions. In addition secondary negative particle emission yields for H{sup 0} on Cu in the 3 to 50 keV range are shown.

  10. PROGRESS IN STUDY OF THE CATALYSTS FOR METHANE ACTIVATION AND CONVERSION%甲烷活化及转化催化剂研究进展

    Institute of Scientific and Technical Information of China (English)

    王晓红; 黄伟; 谢克昌

    2001-01-01

    评述了近年来CH4活化转化的几条重要途径,其中包括CH4与CO2重整制合成气,CH4氧化偶联制高碳烃,CH4非氧同系化.分析了各途径的催化剂研究现状、催化机理及影响催化剂活性的诸多因素,并探索了CH4活化转化的新方法.%A comprehensive review is carried out on some important ways about the activation and conversion of methane which include the reforming of methane with carbon dioxide, the oxidative coupling of methane and the homologation of methane. The recent progress in the catalysts study and the catalitic mechenism are analized. The factors affecting the reactivity of those catalysts are also illustrated. And a new way of methane conversion is probed.

  11. Association Euratom - DTU, Technical University of Denmark, Department of Physics - Annual Progress Report 2011

    DEFF Research Database (Denmark)

    The programme of the Research Unit of the Fusion Association Euratom – DTU, Technical University of Denmark (until 31-12- 2011: Association Euratom – Risø DTU) covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport......, and its interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. Within fusion technology there are activities related to development of high...

  12. [Tampa Electric Company IGCC project]. Final public design report; Technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    This final Public Design Report (PDR) provides completed design information about Tampa Electric Company`s Polk Power Station Unit No. 1, which will demonstrate in a commercial 250 MW unit the operating parameters and benefits of the integration of oxygen-blown, entrained-flow coal gasification with advanced combined cycle technology. Pending development of technically and commercially viable sorbent for the Hot Gas Cleanup System, the HGCU also is demonstrated. The report is organized under the following sections: design basis description; plant descriptions; plant systems; project costs and schedule; heat and material balances; general arrangement drawings; equipment list; and miscellaneous drawings.

  13. Association Euratom - Risø National Laboratory, Technical University of Denmark - Annual Progress Report 2007

    DEFF Research Database (Denmark)

    Michelsen, Poul; Korsholm, Søren Bang; Juul Rasmussen, Jens

    with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. The activities in technology on investigations of radiation damage of fusion reactor materials have been......The programme of the Research Unit of the Fusion Association Euratom - Risø National Laboratory, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction...

  14. Solar-powered irrigation systems. Technical progress report, July 1977--January 1978

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-02-28

    Dispersed solar thermal power systems applied to farm irrigation energy needs are analyzed. The 17 western states, containing 84% of nationwide irrigated croplands and consuming 93% of nationwide irrigation energy, have been selected to determine were solar irrigation systems can compete most favorably with conventional energy sources. Financial analysis of farms, according to size and ownership, was accomplished to permit realistic comparative analyses of system lifetime costs. Market potential of optimized systems has been estimated for the 17-state region for near-term (1985) and intermediate-term (2000) applications. Technical, economic, and institutional factors bearing on penetration and capture of this market are being identified.

  15. [Review of draft Crystalline Repository Project reports]: Technical progress report, CY 1985-1986

    International Nuclear Information System (INIS)

    During the period (CY 1985-86) of this report, the Wisconsin Radioactive Waste Review Board provided technical services under the contract with DOE. These included Participation in the development of variables and screening techniques that would be used in identifying those rock bodies in the Area Recommendation Report (ARR); reviewing and commenting on the report and developing a procedure in which local residents could have input into the process; sought resumption of negotiations with DOE on a full Consultation and Cooperation (CandC) agreement; and Participating in workshops and provided comments on two major DOE transportation documents, ''Transportation Business Plan: Strategy Options Document,'' and ''Transportation Institutional Plan.''

  16. Exxon catalytic coal-gasification process development program. Quarterly technical progress report, October-December 1979

    Energy Technology Data Exchange (ETDEWEB)

    Euker, Jr, C. A.

    1980-03-01

    Work continued on the catalyst recovery screening studies to evaluate the economic impacts of alternative processing approaches and solid-liquid separation techniques. Equipment specifications have been completed for two cases with countercurrent water washing using rotary-drum filters for the solid-liquid separations. Material and energy balances have been completed for an alternative methane recovery process configuration using low pressure stripping which requires 26% less horsepower than the Study Design system. A study has been initiated to identify trace components which might be present in the CCG gas loop and to assess their potential impacts on the CCG process. This information will be used to assist in planning an appropriate series of analyses for the PDU gasifier effluent. A study has been initiated to evaluate the use of a small conventional steam reformer operating in parallel with a preheat furnace for heat input to the catalytic gasifier which avoids the potential problem of carbon laydown. Preliminary replies from ten manufacturers are being evaluated as part of a study to determine the types and performance of coal crushing equipment appropriate for commercial CCG plants. A material and energy balance computer model for the CCG reactor system has been completed. The new model will provide accurate, consistent and cost-efficient material and energy balances for the extensive laboratory guidance and process definition studies planned under the current program. Other activities are described briefly.

  17. Enzyme catalysts for a biotechnology-based chemical industry. Quarterly progress report, September 29--December 28, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Arnold, F.H.

    1998-01-15

    The goal of this research is to engineer enzymes to be efficient and economically attractive catalysts for the chemical industry. The author is attempting to demonstrate generally-applicable approaches to enzyme improvement as well as develop specific catalysts for potential industrial application. In this report attention is focused on random mutagenesis of pNB esterase -- improved activity and stability. The most thermostable esterases obtained by sequential random mutagenesis (6H7) and random mutagenesis plus recombination (6sF9) each contain 9 amino acid mutations and a number of silent mutations, relative to the wild-type sequence. Eight of the mutations are present in both genes, for a total of ten potentially adaptive mutations. Because several of these mutations occurred in the same generation, it is difficult to identify the mutations responsible for the increases in activity and stability. In order to aid in this identification, the thermostable genes were recombined with the wild-type gene, in hopes of removing neutral mutations. The gene from the first-generation variant, with five amino acid substitutions was also recombined with wild-type.

  18. Fischer-Tropsch synthesis: Moessbauer studies of pretreated ultrafine iron oxide catalysts. Partial quarterly progress report, April--June 1992

    Energy Technology Data Exchange (ETDEWEB)

    Chenshi Huang; Davis, B.H. [Kentucky Univ., Lexington, KY (United States). Center for Applied Energy Research; Rao, K.R.P.M.; Huffman, G.P.; Huggins, F.E. [Kentucky Univ., Lexington, KY (United States). Inst. for Mining and Minerals Research

    1992-09-01

    Moessbauer spectroscopy indicates that a 24 hour-pretreatment in CO at 260{degrees}C and 8 atm. in a tetralin solvent almost completely converts uftrafine iron oxide (about 3 nm) to iron carbide. However, pretreatment in hydrogen under the same conditions resulted in reduction of about 33% of the iron to metallic Fe; the remainder was Fe{sub 3}O{sub 4}. Exposure of the CO pretreated catalyst to a 1:1 HDCO synthesis gas resulted in the gradual reoxidation of the carbides to Fe{sub 3}O{sub 4}. During the first 2 hours of exposure of the H{sub 2} pretreated sample to synthesis gas,.the metallic Fe was converted to iron carbides. Further exposure of the H{sub 2} pretreatment sample to synthesis gas did not result in a composition change of the catalyst. Therefore, it is concluded that iron carbides with different oxidation characteristics were formed in these two cases.

  19. Accelerator research studies: Technical progress report for the period June 1, 1986 to May 31, 1987

    International Nuclear Information System (INIS)

    Progress is reported in the study of instabilities and emittance growth in periodic focusing systems for intense beams, collective ion acceleration by intense electron beams and pulse-powered plasma focus, and microwave sources and parameter scaling for high-frequency linacs. Results of a solenoid lens realignment are reported. Theoretical work with particle simulation codes is underway. Laser-controlled collective ion acceleration was demonstrated, a time-resolved Thomson spectrometer was developed, and theoretical studies have led to the development of improved analytical and simulation models describing the equilibrium state and the collective acceleration mechanism in an electron beam with co-moving ions. Progress is reported in the development of a gyroklystron electron gun, and theoretical work on frequency scaling and wakefield effects resulting in codes for quick evaluation of different parameter regimes for electron-positron colliders is discussed. Studies of quadrupole wakefield effects have commenced

  20. Nuclear structure theory. Technical progress report, September 1, 1982-August 31, 1984

    International Nuclear Information System (INIS)

    Research progress is reported. Spectral Averaging studies are outlined including the theory of level densities for interacting nucleons, the properties of single-particle nuclear excitations, spectral distributions for fixed symmetries, and applications to the secular behavior of fluctuation measures in complex nuclei. Collective States research is described, in particular the boson-fermion symmetries which are related to the U(5) limit of the interacting boson model. Nuclear Reaction studies are described including the statistical theory of pion absorption, direct reactions at intermediate energies, and the properties of the off-shell πN t-matrix. Progress is reported on the quark theory of nuclear matter and the construction of models for a Fermi fluid which, near the nuclear ground state, is a fluid of nucleons composed of quarks, and, at high densities or temperatures, is a quark fluid. Applications of formal scattering theory to the study of phase-conjugate optics are discussed. Publications are listed

  1. Oxidation catalyst

    Science.gov (United States)

    Ceyer, Sylvia T.; Lahr, David L.

    2010-11-09

    The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

  2. U.C. Davis high energy particle physics research: Technical progress report -- 1990

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-12-31

    Summaries of progress made for this period is given for each of the following areas: (1) Task A--Experiment, H1 detector at DESY; (2) Task C--Experiment, AMY detector at KEK; (3) Task D--Experiment, fixed target detectors at Fermilab; (4) Task F--Experiment, PEP detector at SLAC and pixel detector; (5) Task B--Theory, particle physics; and (6) Task E--Theory, particle physics.

  3. AFR spent fuel storage program. Technical progress report, January 1981-March 1981

    International Nuclear Information System (INIS)

    Work on this project is focused on developing design and licensing information for the model facility. Deliverables were submitted to DOE for facility modification, security design, and licensing documentation. Work is essentially complete on the high-density rack design with deliverable planned for April 30, 1981. A continuing program for completion of design and licensing information development was initiated by AGNS in February 1981. Progress to date is satisfactory

  4. High energy particle physics at Purdue. Annual technical progress report, March 1980-March 1981

    International Nuclear Information System (INIS)

    Progress is reported in these areas: study of electron-positron annihilation using the High Resolution Spectrometer; proton decay experiment; a study of rare processes in meson spectroscopy using the SLAC Hybrid Bubble Chamber System; theory of fundamental problems in gravitational, electromagnetic, weak and strong interactions; experimental neutrino and antineutrino physics; chi production; development of a colliding beam detector; internal target experiment; and theory of elementary particles with an underlying basis of relativistic quantum field theory

  5. Biomass power for rural development. Technical progress report, January 1--March 31, 1998

    Energy Technology Data Exchange (ETDEWEB)

    Neuhauser, E.

    1998-11-01

    Brief progress reports are presented on the following tasks: design packages for retrofits at the Dunkirk Station; fuel supply and site development plans; major equipment guarantees and project risk sharing; power production commitment; power plant site plan, construction and environmental permits; and experimental strategies for system evaluation. The paper then discusses in more detail the following: feedstock development efforts; clone-site testing and genetic studies; and efforts at outreach, extension and technology transfer.

  6. Index to Nuclear Safety. A technical progress review by chronology, permuted title, and author. Vol. 11, No. 1--Vol. 17, No. 6

    Energy Technology Data Exchange (ETDEWEB)

    Cottrell, W.B.; Klein, A.

    1977-02-23

    This index to Nuclear Safety covers articles in Nuclear Safety Vol. 11, No. 1 (Jan.-Feb. 1970), through Vol. 17, No. 6 (Nov.-Dec. 1976). The index includes a chronological list of articles (including abstract) followed by KWIC and Author Indexes. Nuclear Safety, a bimonthly technical progress review prepared by the Nuclear Safety Information Center, covers all safety aspects of nuclear power reactors and associated facilities. The index lists over 350 technical articles in the last six years of publication.

  7. Index to Nuclear Safety. A technical progress review by chronology, permuted title, and author. Vol. 11, No. 1--Vol. 17, No. 6

    International Nuclear Information System (INIS)

    This index to Nuclear Safety covers articles in Nuclear Safety Vol. 11, No. 1 (Jan.-Feb. 1970), through Vol. 17, No. 6 (Nov.-Dec. 1976). The index includes a chronological list of articles (including abstract) followed by KWIC and Author Indexes. Nuclear Safety, a bimonthly technical progress review prepared by the Nuclear Safety Information Center, covers all safety aspects of nuclear power reactors and associated facilities. The index lists over 350 technical articles in the last six years of publication

  8. Advanced coal conversion process demonstration. Technical progress report for the period July 1, 1995--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1995 through September 30, 1995. The ACCP Demonstration Project is a US Department of Energy (DOE) Clean Coal Technology Project. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the cola is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

  9. Indiana University High Energy Physics Group, Task E: Technical progress report, December 1, 1988--November 30, 1989

    International Nuclear Information System (INIS)

    This progress report for Task E of the Indiana University High Energy Physics Group covers the period June 1, 1988 to May 31, 1989. During this time we worked on several aspects of the development of the Large Volume Detector (LVD) at the Gran Sasso Laboratory in Italy. We finished our gas flow studies for the recirculating and purification system for the limited streamer gas and aided, on a consulting basis, our colleagues at Frascati with the technical specifications for the gas system which they plan to buy from industry. Our major efforts were devoted to design of the tracking trigger, plans for cabling of the whole detector, and learning about the L3 database system. 3 refs., 2 figs., 2 tabs

  10. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 4

    Energy Technology Data Exchange (ETDEWEB)

    Smit, F.J.; Hogsett, R.F.; Jha, M.C.

    1993-11-04

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effective replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. This cost-share contract is a 48-month program which started on September 30, 1992. This report discusses the technical progress made during the 4th quarter of the project from July 1 to September 30, 1993.

  11. Engineering support services for the DOE/GRI coal gasification research program. Quarterly technical progress report, January-March 1982

    Energy Technology Data Exchange (ETDEWEB)

    Bostwick, L.E.; Ethridge, T.R.; Starr, D.W.; Koneru, P.B.; Hubbard, D.A.; Shah, K.V.; Smith, M.R.; Ward, W.E.; Wong, E.W.

    1982-05-01

    Kellogg continued to actively monitor operations at BI-GAS, Westinghouse and IGT (for peat gasification). Pilot plant/PDU test runs which were monitored and reported included BI-GAS Tests G-18, G-18A and G-18B; Westinghouse PDU Test TP-032-1 and CFSF Test TP-M003; and Peatgas Pilot Plant Test No. 5. Kellogg also monitored winterization/maintenance activities at BI-GAS and Westinghouse and precommissioning of the IGT Wet Carbonization PDU. The final report on the Hygas Data Base Evaluation was issued, while final revisions were completed for the reports concerning PDU data base evaluations of Peatgas and single-stage peat gasification. Efforts toward completion of the brochure describing the DOE/GRI Joint Program proceeded. Normal MPC activities continued. Several technical progress reports were issued during this quarter.

  12. Hydrodynamic models for slurry bubble column reactors. Seventh technical progress report, January--March 1996

    Energy Technology Data Exchange (ETDEWEB)

    Gidaspow, D.

    1996-04-01

    The objective of this investigation is to convert our ``learning gas solid-liquid`` fluidization model into a predictive design model. The IIT hydrodynamic model computes the phase velocities and the volume fractions of gas, liquid and particulate phase. Model verification involves a comparison of these computed velocities and volume fractions to experimental values. A hydrodynamic model for multiphase flows, based on the principles of mass, momentum and energy conservation for each phase, was developed and applied to model gas-liquid, gas-liquid-solid fluidization and gas-solid-solid separation. To simulate the industrial slurry bubble column reactors, a computer program based on the hydrodynamic model was written with modules for chemical reactions (e.g. the synthesis of methanol), phase changes and heat exchangers. In the simulations of gas-liquid two phases flow system, the gas hold-ups, computed with a variety of operating conditions such as temperature, pressure, gas and liquid velocities, agree well with the measurements obtained at Air Products` pilot plant. The hydrodynamic model has more flexible features than the previous empirical correlations in predicting the gas hold-up of gas-liquid two-phase flow systems. In the simulations of gas-liquid-solid bubble column reactors with and without slurry circulation, the code computes volume fractions, temperatures and velocity distributions for the gas, the liquid and the solid phases, as well as concentration distributions for the species (CO, H{sub 2}, CH{sub 3}0H, ... ), after startup from a certain initial state. A kinetic theory approach is used to compute a solid viscosity due to particle collisions. Solid motion and gas-liquid-solid mixing are observed on a color PCSHOW movie made from computed time series data. The steady state and time average catalyst concentration profiles, the slurry height and the rates of methanol production agree well with the measurements obtained at an Air Products` pilot plant.

  13. Advanced thermally stable jet fuels. Technical progress report, August 1992--October 1992

    Energy Technology Data Exchange (ETDEWEB)

    Schobert, H.H.; Eser, S.; Song, C.; Hatcher, P.G.; Walsh, P.M.; Coleman, M.M.; Bortiatynski, J.; Burgess, C.; Dutta, R.; Gergova, K.; Lai, W.C.; Li, J.; McKinney, D.; Parfitt, D.; Peng, Y.; Sanghani, P.; Yoon, E.

    1993-02-01

    The Penn State program in advanced thermally stable coal-based jet fuels has five borad objectives: (1) development of mechanisms of degradation and solids formation; (2) quantitative measurement of growth of sub-micrometer and miocrometer-sized particles suspended in fuels during thermal stressing; (3) characterization of carbonaceous deposits by various instrumental and microscopic methods; (4) elucidation of the role of additives in retarding the formation of carbonaceous solids; and (5) assessment of the potential of production of high yields of cycloalkanes by direct liquefaction of coal. Pyrolysis of four isomers of butylbenzene was investigated in static microautoclave reactors at 450{degrees}C under 0.69 MPa of UHP N{sub 2}. Thee rates of disappearance of substrates were found to depend upon the bonding energy of C{alpha}-C{beta} bond in the side chain in the initial period of pyrolysis reactions. Possible catalytic effects of metal surfaces on thermal degradation and deposit formation at temperatures >400{degrees}C have been studied. Carbon deposition depends on the composition of the metal surfaces, and also depends on the chemical compositions of the reactants. Thermal stressing of JP-8 was conducted in the presence of alumina, carbonaceous deposits recovered from earlier stressing experiments, activated carbon, carbon black, and graphite. The addition of different solid carbons during thermal stressing leads to different reaction mechanisms. {sup 13}C NMR spectroscopy, along with {sup 13}C-labeling techniques, have been used to examine the thermal stability of a jet fuel sample mixed with 5% benzyl alcohol. Several heterometallic complexes consisting of two transition metals and sulfur in a single molecule were synthesized and tested as precursors of bimetallic dispersed catalysts for liquefaction of a Montana subbituminous and Pittsburgh No. 8 bituminous coals.

  14. Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark. Annual progress report 2010

    International Nuclear Information System (INIS)

    The programme of the Research Unit of the Fusion Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. Within fusion technology there are activities related to development of high temperature superconductors. Other activities are system analysis, initiative to involve Danish industry in ITER contracts and public information. A summary is presented of the results obtained in the Research Unit during 2010. (Author)

  15. Association Euratom - Risoe National Laboratory, Technical Univ. of Denmark. Annual progress report 2007

    Energy Technology Data Exchange (ETDEWEB)

    Michelsen, P.K.; Korsholm, S.B.; Rasmussen, J.J. (eds.)

    2008-04-15

    The programme of the Research Unit of the Fusion Association Euratom - Risoe National Laboratory, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. The activities in technology on investigations of radiation damage of fusion reactor materials have been phased out during 2007. Minor activities are system analysis, initiative to involve Danish industry in ITER contracts and public information. A summary is presented of the results obtained in the Research Unit during 2007. (Author)

  16. Progress report [of] Technical Physics and Prototype Engineering Division, April 1982 - March 1984

    International Nuclear Information System (INIS)

    The work done by the Technical Physics and Prototype Engineering Division of the Bhabha Atomic Research Centre (BARC) at Bombay during the period from April 1982 to March 1984 is described in the form of summaries. The main thrust of the work of the Division is towards designing, developing, fabricating and if needed, producing on a large scale various instruments, equipment and components required for the programmes of the BARC and the Department of Atomic Energy. The summaries describing the work are grouped under the headings:(1) vacuum, (2) surface analysis, (3) mass spectrometry, (4) electronics, (5) cryogenics, (6) crystals and detectors, (7) glass technology and devices, and (8) optoelectronics. A list of publications of the staff-members of the Division during the report period is given. (M.G.B.)

  17. Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark. Annual progress report 2008

    Energy Technology Data Exchange (ETDEWEB)

    Korsholm, S.B.; Michelsen, P.K.; Rasmussen, J.J.; Westergaard, C.M. (eds.)

    2009-04-15

    The programme of the Research Unit of the Fusion Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. New activities in technology related to development of high temperature superconductors have been initiated in 2008. Minor activities are system analysis, initiative to involve Danish industry in ITER contracts and public information. A summary is presented of the results obtained in the Research Unit during 2008. (Author)

  18. Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark. Annual progress report 2009

    International Nuclear Information System (INIS)

    The programme of the Research Unit of the Fusion Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. Within fusion technology there are activities related to development of high temperature superconductors. Minor activities are system analysis, initiative to involve Danish industry in ITER contracts and public information. A summary is presented of the results obtained in the Research Unit during 2009. (Author)

  19. Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark. Annual progress report 2008

    International Nuclear Information System (INIS)

    The programme of the Research Unit of the Fusion Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. New activities in technology related to development of high temperature superconductors have been initiated in 2008. Minor activities are system analysis, initiative to involve Danish industry in ITER contracts and public information. A summary is presented of the results obtained in the Research Unit during 2008. (Author)

  20. Association Euratom - Risoe National Laboratory, Technical Univ. of Denmark. Annual progress report 2007

    International Nuclear Information System (INIS)

    The programme of the Research Unit of the Fusion Association Euratom - Risoe National Laboratory, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. The activities in technology on investigations of radiation damage of fusion reactor materials have been phased out during 2007. Minor activities are system analysis, initiative to involve Danish industry in ITER contracts and public information. A summary is presented of the results obtained in the Research Unit during 2007. (Author)

  1. Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark. Annual progress report 2010

    Energy Technology Data Exchange (ETDEWEB)

    Korsholm, S.B.; Michelsen, P.K.; Rasmussen, J.J.; Westergaard, C.M. (eds.)

    2011-04-15

    The programme of the Research Unit of the Fusion Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. Within fusion technology there are activities related to development of high temperature superconductors. Other activities are system analysis, initiative to involve Danish industry in ITER contracts and public information. A summary is presented of the results obtained in the Research Unit during 2010. (Author)

  2. Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark. Annual progress report 2009

    Energy Technology Data Exchange (ETDEWEB)

    Korsholm, S.B.; Michelsen, P.K.; Rasmussen, J.J.; Westergaard, C.M. (eds.)

    2010-04-15

    The programme of the Research Unit of the Fusion Association Euratom - Risoe National Laboratory for Sustainable Energy, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. Within fusion technology there are activities related to development of high temperature superconductors. Minor activities are system analysis, initiative to involve Danish industry in ITER contracts and public information. A summary is presented of the results obtained in the Research Unit during 2009. (Author)

  3. Theoretical nuclear physics. Task B. Technical progress report, August 1, 1982-September 30, 1983

    International Nuclear Information System (INIS)

    Progress is reported on the following studies: (a) double delta interactions in pion double charge exchange; (b) isovector correlations in pion-nucleus scattering; (c) nuclear structure effects in pion single charge exchange; (d) a perspective on sequential transfer reactions; (e) inelastic and charge exchange scattering theory; (f) magnitude of the first order DWBA description of the two nuclear transfer reactions; (g) nonlocality effects on deuteron transfer reactions; (h) evaluation of external radial integrals in inelastic electron scattering; (i) experimental observables as a function of Dirac invariant amplitudes; (j) Dirac shell-model wavefunctions in inelastic electron scattering; and (k) impulse approximation Dirac theory of inelastic proton nucleus collective excitations. Publications are listed

  4. Salt Repository Project technical progress report for the quarter 1 January--31 March 1987

    International Nuclear Information System (INIS)

    This document reports the progress being made each quarter on the development of a geologic repository in salt for the permanent disposal of high-level nuclear waste. The reporting elements are arranged by the work breakdown structure so that related studies are presented together. The studies are reported by the Office of Nuclear Waste Isolation, a prime contractor of the US Department of energy (DOE) Salt Repository Project Office. The studies include work by other DOE prime contractors and by contractors to the Office of Nuclear Waste Isolation. 23 refs., 1 fig

  5. High energy particle physics at Purdue. Annual technical progress report, March 1983-March 1984

    International Nuclear Information System (INIS)

    Progress is reported in these areas: a study of electron-positron annihilation using the High Resolution Spectrometer; experimental study of proton decay; gamma ray astrophysics; the DUMAND project; fundamental problems in the theory of gravitational, electromagnetic, weak, and strong interactions; chi production by hadrons; study of collective phenomena; search for the onset of collective phenonmena; work on the Collider Detector at Fermilab; search for a deconfined quark-gluon phase of strongly interacting matter at the FNAL proton-antiproton collider; and development of an electrodeless drift chamber

  6. Salt repository project: Technical progress report for the quarter 1 April--30 June 1987

    International Nuclear Information System (INIS)

    This document reports the progress being made each quarter on the development of a geologic repository in salt for the permanent disposal of high-level nuclear waste. The reporting elements are arranged by the work breakdown structure so that related studies are presented together. The studies are reported by the Office of Nuclear Waste Isolation, a prime contractor of the US Department of Energy (DOE) Salt Repository Project Office. The studies include work by other DOE prime contractors and by contractors to the Office of Nuclear Waste Isolation

  7. Decontamination Systems Information and Research Program. Quarterly technical progress report, July 1--September 30, 1993

    International Nuclear Information System (INIS)

    Progress reports are presented for the following projects: systematic assessment of the state of hazardous waste clean-up technologies; site remediation technologies--drain-enhanced soil flushing (DESF) for organic contaminants removal; excavation systems for hazardous waste sites; chemical destruction of polychlorinated biphenyls; development of organic sensors--monolayer and multilayer self-assembled films for chemical sensors; Winfield Lock and Dam remediation; Winfield cleanup survey; assessment of technologies for hazardous waste site remediation--non-treatment technologies and pilot scale test facility implementation; assessment of environmental remediation storage technology; assessment of environmental remediation excavation technology; assessment of environmental remediation monitoring technology; and remediation of hazardous sites with steam reforming

  8. Nuclear structure theory. Annual technical progress report, September 1, 1980-August 31, 1981

    International Nuclear Information System (INIS)

    This report summarizes progress during the past year in the following areas of nuclear structure and reaction theory: (1) statistical spectroscopy, including: random matrix methods, with applications to fluctuations in spectra and in strength distributions; group symmetries in spectral-distribution theory; electromagnetic and β transitions, limits to time-reversal symmetry breaking in the nucleon-nucleon interaction; (2) meson scattering and absorption by nuclei, including: general scattering theory with absorption, multiple scattering theory and its reactive content, statistical theory of absorption; and (3) meson currents in electromagnetic transitions

  9. Status report on technical progress for LEU-based 99Mo production at Argonne National Laboratory

    International Nuclear Information System (INIS)

    Currently, most of the world's supply of 99Mo is produced from the fissioning 235U in high- enriched uranium (HEU) targets. Conversion of these targets to low-enriched uranium (LEU) would ease worldwide concern over the use and transport of this weapons-grade material. This paper documents our progress in three development areas: (1) the chemistry of iodine and its recovery from irradiated uranium targets, (2) alternate uranium metal target dissolution methods compatible with existing alkaline ion exchange processes and, (3) a small-foot-print dissolver for the LEU-modified Cintichem process. (author)

  10. Decontamination Systems Information and Research Program. Quarterly technical progress report, July 1--September 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-10-01

    Progress reports are presented for the following projects: systematic assessment of the state of hazardous waste clean-up technologies; site remediation technologies--drain-enhanced soil flushing (DESF) for organic contaminants removal; excavation systems for hazardous waste sites; chemical destruction of polychlorinated biphenyls; development of organic sensors--monolayer and multilayer self-assembled films for chemical sensors; Winfield Lock and Dam remediation; Winfield cleanup survey; assessment of technologies for hazardous waste site remediation--non-treatment technologies and pilot scale test facility implementation; assessment of environmental remediation storage technology; assessment of environmental remediation excavation technology; assessment of environmental remediation monitoring technology; and remediation of hazardous sites with steam reforming.

  11. Plasma physics research (Tokapole II). Technical progress report, October 1, 1981-December 31, 1983

    International Nuclear Information System (INIS)

    Progress during the 27-month period, October 1, 1981 to December 31, 1983 on Tokapole II research is described. Tokapole II is a 4-node poloidal divertor tokamak that can also be run as an octupole. Research during this period has concentrated on studies of discharges with safety factor q less than one and on the identification of the shear Alfven wave resonance. Other topics include measurements of the loop voltage reduction through ECRH startup, plasma gun refueling, fluctuations and transport, pumped limiter studies, plasma-wall interactions, diagnostic development, polarization of electron cyclotron emission, and poloidal ohmic heating

  12. GPHS-RTGs in support of the Cassini RTG Program. Semi annual technical progress report, September 26, 1994--April 2, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-04-20

    The technical progress achieved during the period 26 September 1994 through 2 April 1995 on Contract DE-AC03-91SF18852 Radioisotope Thermoelectric Generators and Ancillary Activities is described herein. Monthly technical activity for the period 27 February 1995 through 2 April 1995 is included in this progress report. The report addresses tasks, including: spacecraft integration and liaison; engineering support; safety; qualified unicouple production; ETG Fabrication, assembly, and test; ground support equipment; RTG shipping and launch support; designs, reviews, and mission applications; project management, quality assurance, reliability, contract changes, CAGO acquisition (operating funds), and CAGO maintenance and repair; and CAGO acquisition (capital funds).

  13. Engineering support services for the DOE/GRI coal gasification research program. Final technical progress report, October 1978-November 1982

    Energy Technology Data Exchange (ETDEWEB)

    Bostwick, L.E.

    1982-01-01

    The agreement between the United States Government Department of Energy and the Gas Research Institute for the Joint Coal Gasification Research Program provided for one or more technical evaluation contractors. Pullman Kellogg (now the M.W. Kellogg Company) was selected as evaluation contractor to assess, and report to the DOE/GRI Operating Committee on, the relative merits of the active programs covered by the agreement. This report includes the period from 1 October 1978 to 30 November 1982. The objective was to provide engineering support for the DOE/GRI high Btu coal gasification program. This support generally consisted of assistance in developing or advancing each process to its maximum potential. Kellogg monitored and evaluated the startup and operational activities of all pilot plant projects within the combined DOE/GRI program. Kellogg evaluated proposals to determine their technical feasibility as potential processes or as viable processing operations for commercial-scale gasification of coal. Kellogg also recorded observations on the reliability, maintainability, and availability of the equipment used in the pilot plant or PDU facilities. Kellogg performed design reviews, data analyses, and engineering evaluations of proposals, cost estimates and monthly progress reports to provide information considered essential to the overall objectives of the combined DOE/GRI program.

  14. Technical Progress Report on Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Bill Stanley; Patrick Gonzalez; Sandra Brown; Jenny Henman; Ben Poulter; Sarah Woodhouse Murdock; Neil Sampson; Tim Pearson; Sarah Walker; Zoe Kant; Miguel Calmon; Gilberto Tiepolo

    2006-06-30

    The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas reductions. The research described in this report occurred between April 1st and July 30th 2006. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: emerging technologies for remote sensing of terrestrial carbon; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility studies; and Task 6: development of new project software screening tool. Work is being carried out in Brazil, Belize, Chile, Peru and the USA.

  15. Technical progress report, Contracts DE-AC02-81ER40014, 40015 and 40016

    International Nuclear Information System (INIS)

    This Progress Report summarizes work carried out at the Nuclear Physics Laboratory of the University of Colorado from November 1, 1980 through July 31, 1981, under contracts between the University of Colorado and the United States Department of Energy. The shorter report period of nine months is due to a change to an earlier submission date this year for our proposal for support to begin February 1, 1982. Cyclotron operation, research, and development have been supported under contract DE-AC02-81ER40014. The AVF cyclotron has continued to provide reliable and versatile beams of protons, deuterons, 3He and 4He. A wide variety of research results in direct reactions, nuclear structure, and compound reaction mechanisms can be noted in this Progress Report, correlated in many cases to current problems in intermediate energy physics. Theoretical work on nuclear reactions, carried out under contract DE-AC02-81ER40015, has been well matched to our experimental programs in low and intermediate energy physics. One important result has been the recasting of the DWBA in an eikonal expansion suited to high energy reactions. Our efforts in intermediate energy physics, under contract DE-AC02-81ER40016, have emphasized pion scattering studies at LAMPF and TRIUMF and proton induced charge exchange reactions at IUCF. Data for an important test of hadronic charge symmetry have been completed at two energies, using elastic pion-deuteron scattering

  16. Dissolved organic matter and lake metabolism. Technical progress report, 1 July 1979-30 June 1980

    Energy Technology Data Exchange (ETDEWEB)

    Wetzel, R.G.

    1980-01-01

    Progress in research to evaluate the impact of utilization of fossil fuels on surface water is reported. Analyses of regulatory mechanisms of growth and rates of carbon cycling center on evaluation of quantitative control interactions among the microflora of the pelagial zones of several lakes of progressively greater eutrophy, littoral photosynthetic producer-decomposer complex, and allochthonous inorganic-organic influxes and their biotic processing. The underlying thesis is that quantification of the dynamic carbon fluxes among these components and their rate control mechanisms by physical and chemical factors are fundamental to elucidation of the rate functions of lake eutrophication. A major portion of the research has been directed towards the fate and nutrient mechanisms regulating qualitative and quantitative utilization and losses of organic carbon synthesized within lakes and their drainage basins. It has become increasingly apparent that the wetland and littoral flora, and attendant epiphytic and benthic microflora, have major regulatory controls on biogeochemical cycling of whole lake systems. A major effort on factors regulating the metabolism of littoral macrophytes and attached algae has been coupled to integrated studies on their decomposition and the fate of detrital dissolved and particulate organic matter. These organic products are being coupled to influences on enzymatic activity and inorganic nutrient cycling.

  17. Bioconversion of coal derived synthesis gas to liquid fuels. Quarterly technical progress report, 1 April--30 June 1994

    Energy Technology Data Exchange (ETDEWEB)

    Jain, M.K.; Worden, R.M.; Grethlein, A.

    1994-07-18

    The overall objective of the project is to develop an integrated two-stage fermentation process for conversion of coal-derived synthesis gas to a mixture of alcohols. This is achieved in two steps. In the first step, Butyribacterium methylotrophicum converts carbon monoxide (CO) to butyric and acetic acids. Subsequent fermentation of the acids by Clostridium acetobutylicum leads to the production of butanol and ethanol. The tasks for this quarter were: development/isolation of superior strains for fermentation of syngas; evaluation of bioreactor configuration for improved mass transfer of syngas; recovery of carbon and electrons from H{sub 2}-CO{sub 2}; initiation of pervaporation for recovery of solvents; and selection of solid support material for trickle-bed fermentation. Technical progress included the following. Butyrate production was enhanced during H{sub 2}/CO{sub 2} (50/50) batch fermentation. Isolation of CO-utilizing anaerobic strains is in progress. Pressure (15 psig) fermentation was evaluated as a means of increasing CO availability. Polyurethane foam packing material was selected for trickle bed solid support. Cell recycle fermentation on syngas operated for 3 months. Acetate was the primary product at pH 6.8. Trickle bed and gas lift fermentor designs were modified after initial water testing. Pervaporation system was constructed. No alcohol selectivity was shown with the existing membranes during initial start-up.

  18. Crystalline Repository Project: Technical progress report for the period October 1, 1982--May 28, 1986

    International Nuclear Information System (INIS)

    This document reports the progress made on the development of a second geologic repository in crystalline rocks during the duration of the Crystalline Repository Project from its inception in October 1982 to its termination in May 1986. The reporting elements are arranged by the work breakdown structure so that related studies are presented together. The studies are reported by the Office of Waste Technology Development (OWTD), successor to the Office of Crystalline Repository Development. OWTD is a prime contractor of the US Department of Energy (DOE) Repository Technology Program Office, itself the successor to the Crystalline Repository Project Office. The studies include work by other DOE prime contractors and by contractors to the Office of Crystalline Repository Development. 151 refs

  19. Repository Technology Program: Technical progress report for the period May 29, 1986--June 30, 1987

    International Nuclear Information System (INIS)

    This document reports the progress made in the 13-month period from May 29, 1986--June 30, 1987, on the development of a second geologic repository in rocks other than those being considered for a first repository. Subsequent periods will be covered in reports to be issued on a semiannual basis. The reporting elements are arranged by the work breakdown structure so that related studies are presented together. The studies are reported by the Office of Waste Technology Development (OWTD), a prime contractor of the US. Department of Energy (DOE) Repository Technology Program (RTP) Office in the Repository Technology and Transportation Division (RTTD) of the Office of Geologic Repositories (OGR). The studies include work by other DOE prime contractors and by contractors to the OWTD. 50 refs

  20. Imaging polarimeter/interferometer arrays for tokamak measurements. Technical progress report FY 84

    International Nuclear Information System (INIS)

    The Task IIIB program has continued to make significant strides during the last year. Laboratory test studies continued in our development efforts on imaging polarimeter and interferometer arrays in support of the tokamak measurements carried out under Task IIIA. This work ensures that the system optics and resolution are completely understood prior to attempting actual tokamak measurements. New microbolometer designs and fabrication techniques increased their sensitivity by over an order of magnitude compared with the previous devices. In addition, the development of sensitive monolithic integrated Schottky diode detector arrays has shown rapid progress. Heterodyne noise temperature of less than 90000K have already been achieved at 94 GHz with extension into the submillimeter region anticipated during the coming year

  1. Waste Isolation Safety Assessment Program. Technical progress report for FY-1978

    International Nuclear Information System (INIS)

    Associated with commercial nuclear power production in the United States is the generation of potentially hazardous radioactive wastes. The Department of Energy (DOE) is seeking to develop nuclear waste isolation systems in geologic formations that will preclude contact with the biosphere of waste radionuclides in concentrations which are sufficient to cause deleterious impact on humans or their environments. Comprehensive analyses of specific isolation systems are needed to assess the expectations of meeting that objective. The Waste Isolation Safety Assessment Program (WISAP) has been established at the Pacific Northwest Laboratory (operated by Battelle Memorial Institute) for developing the capability of making those analyses. Progress on the following tasks is reported: release scenario analysis, waste form release rate analysis, release consequence analysis, sorption-desorption analysis, and societal acceptance analysis

  2. Dissolved organic matter and lake metabolism. Technical progress report, 1 July 1976--30 June 1977

    Energy Technology Data Exchange (ETDEWEB)

    Wetzel, R.G.

    1977-01-01

    Progress is reported on investigations on the qualitative and quantitative cycling of particulate and dissolved organic matter within lakes and their drainage basins. Interactions of dissolved organic matter with inorganic nutrient cycling and regulation of the photosynthetic and decompositional metabolism of micro- and macroflora remain the focal point of these studies. Major efforts were directed towards the sources fates, pathways, and interactions of dissolved organic matter in inorganic chemical cycling; allochthonous sources, metabolism en route, and inputs to the lake systems of increasing stages of eutrophication; and the relationships of these compounds to the nutrient physiology and metabolism of phytoplankton, sessile algae, macrophytes, and bacterial populations. Results of studies carried out in a freshwater lake in Michigan (Lawrence Lake) are reported. 165 references.

  3. Waste Isolation Safety Assessment Program. Technical progress report for FY-1978

    Energy Technology Data Exchange (ETDEWEB)

    Brandstetter, A.; Harwell, M.A.; Howes, B.W.; Benson, G.L.; Bradley, D.J.; Raymond, J.R.; Serne, R.J.; Schilling, A.H.

    1979-07-01

    Associated with commercial nuclear power production in the United States is the generation of potentially hazardous radioactive wastes. The Department of Energy (DOE) is seeking to develop nuclear waste isolation systems in geologic formations that will preclude contact with the biosphere of waste radionuclides in concentrations which are sufficient to cause deleterious impact on humans or their environments. Comprehensive analyses of specific isolation systems are needed to assess the expectations of meeting that objective. The Waste Isolation Safety Assessment Program (WISAP) has been established at the Pacific Northwest Laboratory (operated by Battelle Memorial Institute) for developing the capability of making those analyses. Progress on the following tasks is reported: release scenario analysis, waste form release rate analysis, release consequence analysis, sorption-desorption analysis, and societal acceptance analysis. (DC)

  4. Savannah River Ecology Laboratory. Annual technical progress report of ecological research

    International Nuclear Information System (INIS)

    The Savannah River Ecology Laboratory (SREL) is a research unit of the University of Georgia (UGA). The overall mission of the Laboratory is to acquire and communicate knowledge of ecological processes and principles. SREL conducts basic and applied ecological research, as well as education and outreach programs, under a contract with the U.S. Department of Energy (DOE) at the Savannah River Site (SRS) near Aiken, South Carolina. Significant accomplishments were made during the past year in the areas of research, education and service. The Laboratory's research mission was fulfilled with the publication of two books and 143 journal articles and book chapters by faculty, technical and students, and visiting scientists. An additional three books and about 80 journal articles currently are in press. Faculty, technician and students presented 193 lectures, scientific presentations, and posters to colleges and universities, including minority institutions. Dr. J Vaun McArthur organized and conducted the Third Annual SREL Symposium on the Environment: New Concepts in Strewn Ecology: An Integrative Approach. Dr. Michael Newman conducted a 5-day course titled Quantitative Methods in Ecotoxicology, and Dr. Brian Teppen of The Advanced Analytical Center for Environmental Sciences (AACES) taught a 3-day short course titled Introduction to Molecular Modeling of Environmental Systems. Dr. I. Lehr Brisbin co-hosted a meeting of the Crocodile Special Interest Group. Dr. Rebecca Sharitz attended four symposia in Japan during May and June 1996 and conducted meetings of the Executive Committee and Board of the International Association for Ecology (ENTECOL)

  5. Indiana University high energy physics, Task A. Technical progress report, April 1991--April 1992

    Energy Technology Data Exchange (ETDEWEB)

    Brabson, B.; Crittenden, R.; Dzierba, A.; Hanson, G.; Martin, H.; Marshall, T.; Mir, R.; Mouthy, T.; Ogren, H.; Rust, D.; Teige, S.; Zieminska, D.; Zieminski, A.

    1992-10-01

    During this reporting period the group has been carrying out programs in several areas. These are presented in this paper is follows: The group was a collaborator in the Mark II experiment at the SLC and completed analysis on the experiment. Three students completed their theses this reporting period; the group is the prime mover in (E672), a high mass dimuon experiment which now in its final data collection period. Our group is also a collaborator in the DO collider experiment which is now preparing for the first data run in 1992; the group is a collaborator in the OPAL experiment at LEP which is now taking data. The group also is working on the development of a major offline facility shift and on a silicon vertex chamber for 1993; the group is the prime mover in the construction of a major new experiment (E852) in precision meson spectroscopy. A test run is presently underway and data taking will begin in 1993; and the group is a prime mover in the tracking design of the SDC experiment. The SDC has completed the Technical Design report. Construction will begin in 1993.

  6. Savannah River Ecology Laboratory. Annual technical progress report of ecological research

    Energy Technology Data Exchange (ETDEWEB)

    Smith, M.H.

    1996-07-31

    The Savannah River Ecology Laboratory (SREL) is a research unit of the University of Georgia (UGA). The overall mission of the Laboratory is to acquire and communicate knowledge of ecological processes and principles. SREL conducts basic and applied ecological research, as well as education and outreach programs, under a contract with the U.S. Department of Energy (DOE) at the Savannah River Site (SRS) near Aiken, South Carolina. Significant accomplishments were made during the past year in the areas of research, education and service. The Laboratory`s research mission was fulfilled with the publication of two books and 143 journal articles and book chapters by faculty, technical and students, and visiting scientists. An additional three books and about 80 journal articles currently are in press. Faculty, technician and students presented 193 lectures, scientific presentations, and posters to colleges and universities, including minority institutions. Dr. J Vaun McArthur organized and conducted the Third Annual SREL Symposium on the Environment: New Concepts in Strewn Ecology: An Integrative Approach. Dr. Michael Newman conducted a 5-day course titled Quantitative Methods in Ecotoxicology, and Dr. Brian Teppen of The Advanced Analytical Center for Environmental Sciences (AACES) taught a 3-day short course titled Introduction to Molecular Modeling of Environmental Systems. Dr. I. Lehr Brisbin co-hosted a meeting of the Crocodile Special Interest Group. Dr. Rebecca Sharitz attended four symposia in Japan during May and June 1996 and conducted meetings of the Executive Committee and Board of the International Association for Ecology (ENTECOL).

  7. Optimal design and routing of power lines; ecological, technical and economic perspectives (OPTIPOL). Progress report 2009

    Energy Technology Data Exchange (ETDEWEB)

    Bevanger, K.; Bartzke, G.; Broeseth, H.; Gjershaug, J.O.; Hanssen, F.; Jacobsen, K.-O.; Kvaloey, P.; May, R.; Nygaard, T.; Pedersen, H.C.; Reitan, O.; Refsnaes, S.; Stokke, S.; Vang, R.

    2009-12-15

    From 2009 inclusive, NINA has received economic support for research on power lines and wildlife from the Norwegian Research Council (NFR) through the RENERGI Programme. The project is named 'Optimal design and routing of power lines; ecological, technical and economic perspectives' (OPTIPOL). It is scheduled for 5 years (2009-1013) and is part of the activities within CEDREN, i.e. the Centre for environmental design of renewable energy (cf. http://www.cedren.no). With a grid close to 200 000 km overhead power-lines, the associated rights-of-way (ROW) affect huge land areas in Norway. The overall goal is to develop predict-ing tools for optimal routing of power lines from an environmental perspective and assess technical and economic solutions to minimize conflicts with wildlife and habitat conservation. Thus, the OPTIPOL rationale is based on the belief that the negative effects of electricity transmission and distribution can be reduced with respect to birds and mammals. OPTIPOL has several ambitious objectives, and is divided into sub-projects and specific tasks. From the first of November a PhD-student became part of the project, a position that will be held for 4 years. The main objective of the PhD-activities will be to assess how and why different wildlife species use deforested areas below power lines, evaluate possible positive and negative effects of power-line ROWs, and assess the possibilities for quality improvement. Another part of the project is dedicated the effects of linear structures on movement patterns and distribution in the landscape in native deer species. Here we will examine how different spatial scales influence the processes that guide movement patterns, and responses to linear structures. Another focus will be small game species, with mountain hare, capercaillie, black grouse and hazel grouse as model species. The main objective will be to assess the impact of transforming ROW habitats into attractive small-game foraging

  8. Biomass power for rural development. Technical progress report, April 1, 1997--June 30, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Neuhauser, E.

    1997-08-01

    Detailed task progress reports and schedules are provided for the DOE/USDA sponsored Biomass Power for Rural Development project. The focus of the project is on developing commercial energy crops for power generation by the year 2000. The New York based Salix Consortium project is a multi-partner endeavor, implemented in three stages. Phase-I, Final Design and Project Development, will conclude with the preparation of construction and/or operating permits, feedstock production plans, and contracts ready for signature. Field trials of willow (Salix) have been initiated at several locations in New York (Tully, Lockport, King Ferry, La Fayette, Massena, and Himrod) and co-firing tests are underway at Greenidge Station (NYSEG) and Dunkirk Station (NMPC). Phase-H of the project will focus on scale-up of willow crop acreage, construction of co-firing facilities at Dunkirk Station (NMPC), and final modifications for Greenidge Station. Cofiring willow is also under consideration for GPU`s Seward Station where testing is under way. There will be an evaluation of the energy crop as part of the gasification trials occurring at BED`s McNeill power station. Phase-III will represent fullscale commercialization of the energy crop and power generation on a sustainable basis.

  9. University of Tennessee Space Institute. Quarterly technical progress report, April-June 1983

    Energy Technology Data Exchange (ETDEWEB)

    1984-05-01

    The major activities discussed in this quarterly report are concerned with the initiation of testing in the DOE Coal Fired Flow Facility in the LMF1D test series. This test series is designed to provide basic data on seed/slag interaction as a function of diffuser exit temperature and slag carryover rate for the coal fired MHD system with slag screen installed. During the quarter two shakedown tests and three tests in the test series were conducted. Data is reported on the flow train performance, including the combustor, the slag screen, radiant furnace and the materials test module. Analysis of data from the LMF1C test series continues and a summary of the NO/sub x/ data analysis is provided. A summary of the results of application of advanced diagnostic equipment provided by UTSI, Mississippi State University and the Babcock and Wilcox Company is included. In Task 2 the arrival on site of the low temperature air heater is reported. A progress report on the procurement, engineering and installation of the superheater components is included.

  10. Technical progress report during Phase 1 of the continuous fiber ceramic composites program

    Energy Technology Data Exchange (ETDEWEB)

    Richerson, D.W.

    1994-03-15

    United States industry has a critical need for materials that are lightweight, strong, tough, corrosion resistant and capable of performing at high temperatures; such materials will enable substantial increase in energy efficiency and reduction in emissions of pollutants. Continuous fiber ceramic composites (CFCCs) are an emerging class of materials which have the potential for the desired combination of properties to meet the industrial needs. A $10 billion annual market has been estimated for CFCC products by the year 2010, which equates to over 100,000 industrial sector jobs. The CFCC program began in the spring of 1992 as a three-phase 10-year effort to assess potential applications of CFCC materials, develop the necessary supporting technologies to design, analyze and test CFCC materials, conduct materials and process development guided by the applications assessment input, fabricate test samples and representative components to evaluate CFCC material capabilities under application conditions, and analyze scaleability and manufacturability plus demonstrate pilot-scale production engineering. DOE awarded 10 Phase I cooperative agreements to industry-lead teams plus identified generic supporting technology projects. This document highlights the broad progress and accomplishments on these contracts and support technology projects during Phase I.

  11. Capillary electrokinetic separations with optical detection. Technical progress report, February 1, 1993--January 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Sepaniak, M.J.

    1993-10-01

    This program seeks the development of capillary electrokinetic separation techniques and associated optical methods of detection. Fundamental studies of pertinent separation and band broadening mechanisms are being conducted, with the emphasis on understanding systems that include highly-ordered assemblies as running buffer additives. The additives include cyclodextrins, affinity reagents, and soluble (entangled) polymers and are employed with capillary electrophoresis, CE and/or micellar electrokinetic capillary chromatography, MECC modes of separation. The utility of molecular modeling techniques for predicting the effects of highly ordered assemblies on the retention behavior of isomeric compounds is under investigation. The feasibility of performing separations using a non-aqueous solvent/fullerene electrochromatographic system is being explored. The analytical methodologies associated with these capillary separation techniques are being advanced through the development of retention programming instumentation/techniques and new strategies for performing optical detection. The advantages of laser fluorimetry are extended through the inclusion of fluorogenic, reagents in the running buffer. These reagents include oligonucleotide intercalation reagents for detecting DNA fragments. Chemiluminescence detection using post-capillary reactors/flow cells is also in progress. Successful development of these separation and detection systems will fill current voids in the capabilities of capillary separation techniques.

  12. Nuclear structure theory. Technical progress report, September 1, 1984-August 31, 1985

    International Nuclear Information System (INIS)

    This report summarizes progress in the following areas of research: Spectral Averaging, including the theory of level densities and partition functions for interacting nucleons, spectral distributions for fixed symmetries, general studies of distributions (in particular of strength distributions) considered as multivariate processes, and applications to the secular behavior of fluctuation measures; spectral and strength fluctuations, including study of the transitions between different fluctuation patterns (i.e., between different types of quantum chaos) as a conserved symmetry is gradually broken, application of these results to determining values of, or upper bounds for, the goodness of symmetries in complex nuclei, reduction of values or bounds to statements about the nuclear Hamiltonian, in particular for time-reversal symmetry, and specific studies of quantum chaos; statistical theory of pion absorption, including analysis of the (π,p) inclusive reaction; and quark theory of nuclear matter, involving development of models which show two limiting behaviors - that of a Fermi gas of nucleons (quark clusters) at low density and of a Fermi gas of quarks at high density. Both variational and exact solutions of one model have been found. 9 refs

  13. Dissolved organic matter and lake metabolism. Technical progress report, 1 July 1978--30 Jun 1979

    Energy Technology Data Exchange (ETDEWEB)

    Wenzel, R.G.

    1979-01-01

    Progress is reported in continuing investigations focused on integrated studies of the qualitative and quantitative cycling and metabolism of particulate and dissolved organic carbon in lakes and their inflow sources (surface and subsurface). Emphasis is placed on the sources, fates, and interactions of dissolved and particulate organic matter in relation to: (a) inorganic chemical cycling, (b) allochthonous loading to the lake system, and (c) the coupled nutrient physiology and metabolism of phytoplankton, bacterial populations, macrophytes, and attendant sessile algal-bacterial communities. Regulatory mechanisms of growth and rates of carbon and nutrient cycling are being evaluated among the (a) inorganic-organic influxes of allochthonous sources as they are controlled by wetland-littoral communities, (b) the littoral photosynthetic producer-decomposer complex, and (c) the microflora of the pelagial zone. Quantification of carbon fluxes among these components and control mechanisms is fundamental to elucidation of the rate functions of lake eutrophication. The integrated studies addressing these multifacted objectives are summarized in three summary diagrams.

  14. Dissolved organic matter and lake metabolism. Technical progress report, 1 July 1977--30 June 1978

    Energy Technology Data Exchange (ETDEWEB)

    Wetzel, R.G.

    1978-01-01

    Interactions of dissolved organic matter with inorganic nutrient cycling and regulation of the photosynthetic and decompositional metabolism of micro- and macroflora remains the focal point of these studies. Major efforts are directed towards the sources, fates, pathways, and interactions of dissolved organic matter in inorganic chemical cycling; allochthonous sources, metabolism en route, and inputs to the lake systems of increasing stages of eutrophication; and the relationships of these compounds to the nutrient physiology and metabolism of phytoplankton, sessile algae, macrophytes, and bacterial populations of the littoral zones and wetlands of the drainage basin. Analyses of regulatory mechanisms of growth and rates of carbon cycling center on evaluation of quantitative control interactions among the microflora of the pelagial zones of seversal lakes of progressively greater eutrophy, littoral photosynthetic producer-decomposer complex, and allochthonous inorganic--organic influxes and their biotic processing. The underlying thesis is that quantification of the dynamic carbon fluxes among these components and their rate control mechanisms by physical and chemical factors are fundamental to elucidation of the rate functions of lake eutrophication.

  15. Proton resonance spectroscopy. Quarterly technical progress report, December 1992--November 1995

    Energy Technology Data Exchange (ETDEWEB)

    Shriner, J.F. Jr.

    1995-11-01

    Work on chaos in the low-lying levels of nuclei has continued on several fronts. The major effort has been study of the {sup 29}Si(p,{gamma}) reaction with the goal of establishing a complete level scheme for {sup 30}P and analyzing the eigenvalue fluctuations for evidence of chaos. These measurements are in progress, and the current status is described. A related topic is the search for different signatures of chaos which do not require the extremely high degree of completeness and purity necessary for eigenvalue analyses; those efforts are discussed in Sections 2 and 3. The possibility of studying both parity violation and time-reversal invariance violation with charged particle resonances has been explored by performing calculations using experimentally measured resonance parameters. Large enhancements are indeed available; the results are discussed in Sections 4 and 5. Preparations for an experimental study of parity violation using these techniques are ongoing. An undergraduate project searching for experimental evidence of a parity dependence of level density is discussed in Section 6. A number of improvements to the operation of the TUNL KN accelerator have been implemented in the past three years. These are described in Section 7.

  16. Improved methods for water shutoff. Final technical progress report, October 1, 1997--September 30, 1998

    Energy Technology Data Exchange (ETDEWEB)

    Seright, R.S.; Liang, J.T.; Schrader, R.; Hagstrom, J. II; Liu, J.; Wavrik, K.

    1998-10-01

    In the United States, more than 20 billion barrels of salt water are produced each year during oilfield operations. A tremendous economic incentive exists to reduce water production if that can be accomplished without significantly sacrificing hydrocarbon production. This three-year research project had three objectives. The first objective was to identify chemical blocking agents that will (a) during placement, flow readily through fractures without penetrating significantly into porous rock and with screening out or developing excessive pressure gradients and (b) at a predictable and controllable time, become immobile and resistant breakdown upon exposure to moderate to high pressure gradients. The second objective was to identify schemes that optimize placement of the above blocking agents. The third objective was to explain why gels and other chemical blocking agents reduce permeability to one phase (e.g., water) more than that to another phase (e.g., oil or gas). The authors also wanted to identify conditions that maximize this phenomenon. This project consisted of three tasks, each of which addressed one of the above objectives. This report describes work performed during the third and final period of the project. During this three-year project, they: (1) Developed a procedure and software for sizing gelant treatments in hydraulically fractured production wells; (2) Developed a method (based on interwell tracer results) to determine the potential for applying gel treatments in naturally fractured reservoirs; (3) Characterized gel properties during extrusion through fractures; (4) Developed a method to predict gel placement in naturally fractured reservoirs; (5) Made progress in elucidating the mechanism for why some gels can reduce permeability to water more than that to oil; (6) Demonstrated the limitations of using water/oil ratio diagnostic plots to distinguish between channeling and coning; and (7) Proposed a philosophy for diagnosing and attacking water

  17. Technical Progress Report on Single Pass Flow Through Tests of Ceramic Waste Forms for Plutonium Immobilization

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, P; Roberts, S; Bourcier, W

    2000-12-01

    This report updates work on measurements of the dissolution rates of single-phase and multi-phase ceramic waste forms in flow-through reactors at Lawrence Livermore National Laboratory. Previous results were reported in Bourcier (1999). Two types of tests are in progress: (1) tests of baseline pyrochlore-based multiphase ceramics; and (2) tests of single-phase pyrochlore, zirconolite, and brannerite (the three phases that will contain most of the actinides). Tests of the multi-phase material are all being run at 25 C. The single-phase tests are being run at 25, 50, and 75 C. All tests are being performed at ambient pressure. The as-made bulk compositions of the ceramics are given in Table 1. The single pass flow-through test procedure [Knauss, 1986 No.140] allows the powdered ceramic to react with pH buffer solutions traveling upward vertically through the powder. Gentle rocking during the course of the experiment keeps the powder suspended and avoids clumping, and allows the system to behave as a continuously stirred reactor. For each test, a cell is loaded with approximately one gram of the appropriate size fraction of powdered ceramic and reacted with a buffer solution of the desired pH. The buffer solution compositions are given in Table 2. All the ceramics tested were cold pressed and sintered at 1350 C in air, except brannerite, which was sintered at 1350 C in a CO/CO{sub 2} gas mixture. They were then crushed, sieved, rinsed repeatedly in alcohol and distilled water, and the desired particle size fraction collected for the single pass flow-through tests (SPFT). The surface area of the ceramics measured by BET ranged from 0.1-0.35 m{sup 2}/g. The measured surface area values, average particle size, and sample weights for each ceramic test are given in the Appendices.

  18. Solvent refined coal (SRC) process. Quarterly technical progress report, January 1980-March 1980. [In process streams

    Energy Technology Data Exchange (ETDEWEB)

    1981-01-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) project at the SRC Pilot Plant in Fort Lewis, Wahsington, and the Process Development Unit (P-99) in Harmarville, Pennsylvania. After the remaining runs of the slurry preheater survey test program were completed January 14, the Fort Lewis Pilot Plant was shut down to inspect Slurry Preheater B and to insulate the coil for future testing at higher rates of heat flux. Radiographic inspection of the coil showed that the welds at the pressure taps and the immersion thermowells did not meet design specifications. Slurry Preheater A was used during the first 12 days of February while weld repairs and modifications to Slurry Preheater B were completed. Two attempts to complete a material balance run on Powhatan No. 6 Mine coal were attempted but neither was successful. Slurry Preheater B was in service the remainder of the quarter. The start of a series of runs at higher heat flux was delayed because of plugging in both the slurry and the hydrogen flow metering systems. Three baseline runs and three slurry runs of the high heat flux program were completed before the plant was shut down March 12 for repair of the Inert Gas Unit. Attempts to complete a fourth slurry run at high heat flux were unsuccessful because of problems with the coal feed handling and the vortex mix systems. Process Development Unit (P-99) completed three of the four runs designed to study the effect of dissolver L/D ratio. The fourth was under way at the end of the period. SRC yield correlations have been developed that include coal properties as independent variables. A preliminary ranking of coals according to their reactivity in PDU P-99 has been made. Techniques for studying coking phenomenona are now in place.

  19. Nuclear Physics Laboratory, University of Colorado technical progress report, 1976 and proposal for continuation of contract

    Energy Technology Data Exchange (ETDEWEB)

    1976-11-01

    This report summarizes the work carried out at the Nuclear Physics Laboratory of the University of Colorado during the period November 1, 1975 to November 1, 1976. The low energy nuclear physics section is dominated by light-ion reaction studies which span a wide range. These include both two-neutron and two-proton transfer reactions, charge exchange and inelastic scattering, as well as single nucleon transfer reactions. The nuclei studied vary widely in their mass and characteristics. These reaction studies have been aided by the multi-use scattering chamber which now allows the energy-loss-spectrometer beam preparation system (beam swinger) to shift from charged particle studies to neutron time-of-flight studies with a minimum loss of time. The intermediate energy section reflects the increase in activity accompanying the arrival of LAMPF data and the initiation of (p,d) studies at the Indiana separated-sector cyclotron. The nucleon removal results provided by the ..pi.. beam at EPICS previous to completion of the spectrometer have shown that nuclear effects dominate this process, so that the widely used free interaction picture is inadequate. The section entitled ''Other Activities'' reveals continuing activities in new applications of nuclear techniques to problems in medicine and biology. Reactions important to astrophysics continue to be investigated and our trace-element program remains at a high level of activity. The theoretical section reports new progress in understanding magnitudes of two-step reactions by inclusion of finite-range effects. A new finite-range program which is fast and economical has been completed. Intermediate energy results include calculations of ..pi..-..gamma.. angular correlations, low energy ..pi..-nucleus interactions, as well as (p,d) and nucleon scattering calculations for intermediate energies.

  20. Theory of high-energy-collision processes. Technical progress report, January 1-December 31, 1981

    International Nuclear Information System (INIS)

    Progress is described in the following areas: (1) several years ago, surprisingly simple expressions were obtained for the differential cross sections of e+e- → μ+μ-γ and e+e- → e+e-γ at high energies. Such simple expressions were generalized to twelve other similar radiative processes in QED and QCD. Afterwards, it was found that these results can be derived easily with the help of helicity amplitudes. This method is being investigated for many other radiative processes; (2) in the two-dimensional Ising model, the horizontal and vertical interaction energies are usually taken to be different. When this idea of different interactions in different directions is applied to the Z2 lattice gauge theory in four dimensions, a limiting case is found which is exactly solvable. Contrary to numerical calculations at the symmetry point, the phase transition is found to be of second order; (3) on the subject of supersymmetry, general helicity and spin sum rules were obtained for massless and massive supermultiplets, and a functional integral approach was found as a natural setting for Witten's criterion for the occurrence of dynamic symmetry breaking of supersymmetry. A systematic and exhaustive analysis of explicit soft breaking of global supersymmetry has also been carried out using the methods of superfields; (4) the renormalization of the massless Thirring model in the neighborhood of g = -π/2 was studied. The results are consistent with those found previously by placing the model on a lattice; and (5) in studying the effect of laboratory temperature on scattering processes, it was found that transport phenomena play an important role. As a preparation for this study, an exactly solvable case of the nonlinear Boltzmann equation has been found and studied

  1. Heterogeneous catalytic process for alcohol fuels from syngas. Sixteenth quarterly technical progress report, October--December, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    The principal objectives of this project are to discover and evaluate novel heterogeneous catalysts for conversion of syngas to oxygenates having use as fuel enhancers, to explore novel reactor and process concepts applicable in this process, and to develop the best total process for converting syngas to liquid fuels. Among our previous best catalysts was the family consisting of potassium-promoted Pd on a Zn/Cr spinel oxide prepared via controlled pH precipitation. We have now examined the effect of potassium promotion on (1) a Zn/Cr/O spinel and (2) on ZnO; these two individual components are used together to make our best support. The presence of excess zinc oxide has a beneficial effect on the performance of Zn/Cr spinel oxide catalysts (1) promoted with cesium and (2) promoted with both cesium and palladium. The presence of the excess zinc oxide results in a more active and selective catalyst to total alcohols and increased isobutanol rates, demonstrating the effectiveness of zinc oxide addition to the spinel support. Potassium addition promotes higher alcohol synthesis on a commercial Zn/Cr spinel oxide methanol synthesis catalyst. Incremental potassium levels (1, 3 and 5 wt%) result in an increase in total alcohol selectivity, while isobutanol. rates are maximized at 1 wt% potassium. The commercial catalyst promoted with potassium is slightly less active for isobutanol synthesis and less selective to total alcohols when compared with our spinel formulation promoted with potassium and containing excess ZnO. Surface science studies have shown that the surface of these catalysts is predominately ZnO and alkali. With use, the ZnO is reduced to Zn metal, and Cr migrates to the surface giving increased surface acidity. In addition tends to lower the overall acidity. Hydrogen can be observed on the catalyst surface by surface science studies. Hydrogen on the active catalyst is associated with the palladium.

  2. Final Technical Progress Report Long term risk from actinides in the environment: Modes of mobility; FINAL

    International Nuclear Information System (INIS)

    The key source of uncertainty in assessing actinide mobility is the relative importance of transport by: (1) wind erosion, (2) water erosion, and (3) vertical migration. Each of these three processes depends on several environmental factors and they compete with one another. A scientific assessment of the long-term risks associated with actinides in surface soils depends on better quantifying each of these three modes of mobility. The objective from our EMSP study was to quantify the mobility of soil actinides by wind erosion, water erosion, and vertical migration at three semiarid sites where actinide mobility is a key technical, social and legal issue. This EMSP project was the first to evaluate all three factors at a site. The approach has been to investigate both short- and long-term issues based on field and lab studies and model comparisons. Our results demonstrate the importance of incorporating threshold responses into a modeling framework that accounts for environmental factors and natural disturbances that trigger large changes in actinide mobility. The study measured erosional losses of sediment and fallout cesium (an actinide analogue) from field plots located near WIPP in 1998. The results highlight the large effect of burning as a disturbance on contaminant transport and mobility via runoff and erosion. The results show that runoff, erosion, and actinide transport are (1) strongly site specific-differences in radionuclide transport between WIPP and Rocky Flats differed by a factor of twelve because of soil and vegetation differences, and (2) are strongly impacted by disturbances such as fire, which can increase runoff, erosion, and actinide transport by more than an order of magnitude. In addition, a laboratory experiment using soil columns was conducted to investigate the vertical transport of contaminants in sandy soils. Nine columns of soil collected from the vicinity of the WIPP site were prepared. The column consisted of a piece of PVC pipe 20 cm

  3. Final Technical Progress Report Long term risk from actinides in the environment: Modes of mobility

    International Nuclear Information System (INIS)

    The key source of uncertainty in assessing actinide mobility is the relative importance of transport by: (1) wind erosion, (2) water erosion, and (3) vertical migration. Each of these three processes depends on several environmental factors and they compete with one another. A scientific assessment of the long-term risks associated with actinides in surface soils depends on better quantifying each of these three modes of mobility. The objective from our EMSP study was to quantify the mobility of soil actinides by wind erosion, water erosion, and vertical migration at three semiarid sites where actinide mobility is a key technical, social and legal issue. This EMSP project was the first to evaluate all three factors at a site. The approach has been to investigate both short- and long-term issues based on field and lab studies and model comparisons. Our results demonstrate the importance of incorporating threshold responses into a modeling framework that accounts for environmental factors and natural disturbances that trigger large changes in actinide mobility. The study measured erosional losses of sediment and fallout cesium (an actinide analogue) from field plots located near WIPP in 1998. The results highlight the large effect of burning as a disturbance on contaminant transport and mobility via runoff and erosion. The results show that runoff, erosion, and actinide transport are (1) strongly site specific-differences in radionuclide transport between WIPP and Rocky Flats differed by a factor of twelve because of soil and vegetation differences, and (2) are strongly impacted by disturbances such as fire, which can increase runoff, erosion, and actinide transport by more than an order of magnitude. In addition, a laboratory experiment using soil columns was conducted to investigate the vertical transport of contaminants in sandy soils. Nine columns of soil collected from the vicinity of the WIPP site were prepared. The column consisted of a piece of PVC pipe 20 cm

  4. Savannah River Ecology Laboratory Annual Technical Progress Report of Ecological Research, June 30, 2001

    Energy Technology Data Exchange (ETDEWEB)

    Bertsch, Paul M.; Janecek, Laura; Rosier, Brenda

    2001-06-30

    The Savannah River Ecology Laboratory (SREL) is a research unit of the University of Georgia (UGA) and has been conducting ecological research on the Savannah River Site (SRS) in South Carolina for 50 years. The overall mission of the Laboratory is to acquire and communicate knowledge of ecological processes and principles. SREL conducts fundamental and applied ecological research, as well as education and outreach programs, under a Cooperative Agreement with the U.S. Department of Energy (DOE) SRS near Aiken, South Carolina. The Laboratory's research mission during the 2001 fiscal year was fulfilled with the publication of one book and 83 journal articles and book chapters by faculty, technical staff, students, and visiting scientists. An additional 77 journal articles have been submitted or are in press. Other noteworthy events took place as faculty members and graduate students received awards. These are described in the section Special Accomplishments of Faculty, Staff, Students, and Administration on page 54. Notable scientific accomplishments include work conducted on contaminant transport, global reptile decline, phytoremediation, and radioecology. Dr. Domy Adriano authored the second edition of his book ''Trace Elements in Terrestrial Environments: Biogeochemistry, Bioavailability, and Risks of Metals'', which was recently published by Springer-Verlag. The book provides a comprehensive treatment of many important aspects of trace elements in the environment. The first edition of the book, published in 1986, has become a widely acclaimed and cited reference. International attention was focused on the problem of reptile species decline with the publication of an article on this topic in the journal ''Bioscience'' in August, 2000. The article's authors included Dr. Whit Gibbons and a number of other SREL herpetologists who researched the growing worldwide problem of decline of reptile species. Factors related

  5. Final Technical Progress Report Long term risk from actinides in the environment: Modes of mobility

    Energy Technology Data Exchange (ETDEWEB)

    Thomas B. Kirchner

    2002-03-22

    The key source of uncertainty in assessing actinide mobility is the relative importance of transport by: (1) wind erosion, (2) water erosion, and (3) vertical migration. Each of these three processes depends on several environmental factors and they compete with one another. A scientific assessment of the long-term risks associated with actinides in surface soils depends on better quantifying each of these three modes of mobility. The objective from our EMSP study was to quantify the mobility of soil actinides by wind erosion, water erosion, and vertical migration at three semiarid sites where actinide mobility is a key technical, social and legal issue. This EMSP project was the first to evaluate all three factors at a site. The approach has been to investigate both short- and long-term issues based on field and lab studies and model comparisons. Our results demonstrate the importance of incorporating threshold responses into a modeling framework that accounts for environmental factors and natural disturbances that trigger large changes in actinide mobility. The study measured erosional losses of sediment and fallout cesium (an actinide analogue) from field plots located near WIPP in 1998. The results highlight the large effect of burning as a disturbance on contaminant transport and mobility via runoff and erosion. The results show that runoff, erosion, and actinide transport are (1) strongly site specific-differences in radionuclide transport between WIPP and Rocky Flats differed by a factor of twelve because of soil and vegetation differences, and (2) are strongly impacted by disturbances such as fire, which can increase runoff, erosion, and actinide transport by more than an order of magnitude. In addition, a laboratory experiment using soil columns was conducted to investigate the vertical transport of contaminants in sandy soils. Nine columns of soil collected from the vicinity of the WIPP site were prepared. The column consisted of a piece of PVC pipe 20 cm

  6. Optimal design and routing of power lines; ecological, technical and economic perspectives (OPTIPOL). Progress report 2012

    Energy Technology Data Exchange (ETDEWEB)

    Bevanger, Kjetil; Bartzke, Gundula; Broeseth, Henrik; Dahl, Espen Lie; Gjershaug, Jan Ove; Hanssen, Frank; Jacobsen, Karl-Otto; Kleven, Oddmund; Kvaloey, Paal; May, Roel; Meaas, Roger; Nygaaard, Torgeir; Resnaes, Steinar; Stokke, Sigbjoern; Thomassen, Joern

    2012-07-01

    birds in the database, compared to only 117 a year earlier. WP5 - 'A Least Cost Path (LCP) toolbox for optimal route routing of power lines', has developed an LCP-pilot to demonstrate the LCP method, based on the impact studies were undertaken prior to construction of a 420 kV transmission line in Central Norway 2005. Relevant economic, ecological and technological environment criteria based on suggestions from interested users (NGOs, government, industry, etc.), was used. LCP-pilot and a fuzzy-logic approach of this was demonstrated in the first dialogue-based workshop, 23.-24. april 2012. The seminar, which had an emphasis on criteria definitions were followed up with a working seminar that focused criterion values ??on 20 november 2012. Lecture - 'A Least Cost Path (LCP) Toolbox for Optimal Routing of Power Lines, -was presented and submitted as contributions to the conference report from 'The 10th ROW Conference' in Arizona, 'The 32nd Annual Conference of the International Association for Impact Assessment (IAIA12) ' in Porto, Portugal, and 'The ESRI European User Conference' in Oslo. WP6 - 'Birds and camouflaging of power lines', has almost completed the final report, 'Power line camouflaging. An assessment of the ecological and technical challenges'. 'Because of the budget situation in CEDREN However, completion of the report postponed until the end of April 2013. WP7 - 'Effect of line marking / modifications remedial measures against bird mortality' has almost completed the final report 'Opportunities and limitations in terms of reducing mortality in birds due to collision and electrocution.' Due to overall budget situation in CEDREN the report deferred to the end of april 2013. WP8, 'guidelines for technological solutions that may reduce mortality in birds because of the power line's', has focused topics relating to the labeling, design, insulation, camouflage and wiring. The results, which are presented in the notes and articles, will be implemented in

  7. Fundamental characterization of alternate fuel effects in continuous combustion systems. Summary technical progress report, August 15, 1978-January 31, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Blazowski, W.S.; Edelman, R.B.; Wong, E.

    1980-02-27

    The overall objective of this contract is to assist in the development of fuel-flexible combustion systems for gas turbines as well as Rankine and Stirling cycle engines. The primary emphasis of the program is on liquid hydrocarbons produced from non-petroleum resources. Fuel-flexible combustion systems will provide for more rapid transition of these alternative fuels into important future energy utilization centers (especially utility power generation with the combined cycle gas turbine). The specific technical objectives of the program are: (a) develop an improved understanding of relationships between alternative fuel properties and continuous combustion system effects, and (b) provide analytical modeling/correlation capabilities to be used as design aids for development of fuel-tolerant combustion systems. This is the second major report of the program. Key experimental findings during this reporting period concern stirred combustor soot production during operation at controlled temperature conditions, soot production as a function of combustor residence time, an improved measurement technique for total hydrocarbons and initial stirred combustor results of fuel nitrogen conversion. While the results to be presented concern a stirred combustor which utilizes premixed fuel vapor/oxidant mixtures, a new combustor which combusts liquid fuel injected into the reactor as a spray has been developed and will be described. Analytical program progress includes the development of new quasiglobal models of soot formation and assessment of needs for other submodel development.

  8. Feed-in tariffs versus quotas: how to promote renewable s and stimulate technical progress for cost decrease?

    International Nuclear Information System (INIS)

    Incentive schemes for the development of renewable energy sources may focus on quantities (defining national targets and setting up bidding systems, or quota systems providing for green certificate trading), or they may focus on prices (feed-in tariffs). Whatever the system chosen, the role of the public authorities is quite specific: to stimulate technical progress and speed up the technological learning processes so that ultimately renewable energy technologies will be able to compete with conventional technologies, once the environmental costs have been internalized. A comparison of instruments must thus take into account the characteristics of the innovation process and adoption conditions (uncertainties regarding cost curves, learning effects) which means also looking at dynamic efficiency criteria. The paper concludes that a system of feed-in tariffs is more efficient than a bidding system, but highlights the theoretical interest of green certificate trading which must be confirmed through practice, given the influence of market structures and rules on the performance of this type of approach. (author)

  9. Distribution of marine birds on Georges Bank and adjacent waters. Technical progress report, 1 January--31 August 1978

    Energy Technology Data Exchange (ETDEWEB)

    Powers, K.D.

    1978-10-01

    The work accomplished during the period covered in this technical progress report demonstrates the importance, interest, and necessity of a distribution study of marine birds in the Georges Bank area on a national and international scale. Cooperation was extended by the U.S. National Marine Fisheries Service, U.S. Fish and Wildlife Service, U.S. Coast Guard, and by the Canadian Wildlife Service, Halifax, N.S., AltantNIRO, Kaliningrad, USSR, and Federal Republic of Germany. Two sampling methods, fixed-area and total bird counts, were effectively employed, which allow comparable data bases with marine bird distribution information being collected in the North Pacific, Bering and Chukchi Seas (Outer Continental Shelf Energy Assessment Program), and in the North Atlantic and Canadian Arctic (CWS and The Seabird Group). A marine bird data retrieval bank is being developed for MBO seabird data at the USFWS Migratory Bird and Habitat Research Laboratory. A food habits bibliography and prey item/bird species summary table for marine birds in the western North Atlantic has been prepared from existing literature. Unpublished NMFS data on zooplankton/ichthyoplankton, and ground fish is being made available for possible correlations in distribution of selected prey items with bird species.

  10. Bench-scale testing of the micronized magnetite process. Second quarterly technical progress report, October 1994--December 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-01-19

    This document contains the Quarterly Technical Progress Report for the Micronized Magnetite Testing Project being performed at PETC`s Process Research Facility (PRF). This second quarterly report covers the period from October, 1994 through December, 1994. The main accomplishments of Custom Coals and the project subcontractors, during this period, included: (1) Submitted all overdue project documents and kept up with routine reporting requirements; (2) Worked with CLI Corporation, the design subcontractor, and completed the circuit design and finalized all design drawings; (3) Specified and procured all of the process equipment for the circuit, as well as a number of ancillary equipment, instruments, and supplies; (4) Assisted Vangura Iron Inc. in detailing and constructing the structural and platework steel; (5) Subcontracted Rizzo & Sons to perform the circuit mechanical and electrical installation, and prepared for January 23rd installation start date; (6) Organized and prepared for coal and magnetite procurement; (7) Specified and organized an operating personnel plan for the commissioning and testing tasks in the project; (8) Assessed analytical challenges for project, and began to research problem areas. This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the abovementioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  11. Gas turbine demonstration of pyrolysis: derived fuels. Third technical progress report, July 1, 1979-December 31, 1981

    Energy Technology Data Exchange (ETDEWEB)

    Jasas, G.; Kasper, J.

    1982-01-01

    The objective of this program is to demonstrate the feasibility of utilizing pyrolytic oil and char as a fuel for a combustion turbine engine. This is the first phase of an extended program with the ultimate goal of commercializing a gas turbine engine and electrical generating system which is independent of petroleum-based fuels. Maximum use of existing technology and current production engine hardware (Teledyne CAE Model J69-T-29 Turbojet Engine) is being incorporated for a sequence of test evaluations rating from isolated combustor component tests to full scale engine demonstration tests. The technical goals to be achieved during the course of this project are: pyrolytic fuel characterization in terms of its properties and constituents; pyrolytic fuel combustion technology in gas turbine application in terms of pyrolytic oil atomization, quantity of char burned, emissions, performance and associated combustion system aerothermodynamics; pyrolytic fuel (oil and char slurry) handling, mixing, and storage technology; and engine materials compatibility with the the pyrolytic fuel and its combustion products. Progress achieved during the period from July 1979 through Deember 1981 in design, analysis, an project management hardware fabrication and procurement, fuel chemistry and properties, and combustor rig tests are summarized.

  12. Index to Nuclear Safety: a technical progress review by chronology, permuted title, and author, Volume 18 (1) through Volume 22 (6)

    Energy Technology Data Exchange (ETDEWEB)

    Cottrell, W.B.; Passiakos, M.

    1982-06-01

    This index to Nuclear Safety covers articles published in Nuclear Safety, Volume 18, Number 1 (January-February 1977) through Volume 22, Number 6 (November-December 1981). The index is divided into three section: a chronological list of articles (including abstracts), a permuted-title (KWIC) index, and an author index. Nuclear Safety, a bimonthly technical progress review prepared by the Nuclear Safety Information Center, covers all safety aspects of nuclear power reactors and associated facilities. Over 300 technical articles published in Nuclear Safety in the last 5 years are listed in this index.

  13. Index to Nuclear Safety. A technical progress review by chronology, permuted title, and author. Vol 11, No. 1 through Vol. 16, No. 6

    International Nuclear Information System (INIS)

    This index to Nuclear Safety covers articles in Nuclear Safety Vol. 11, No. 1 (Jan.-Feb. 1970) through Vol. 16, No. 6 (Nov.-Dec. 1975). Included in the index is a chronological list of articles (including abstract) followed by both a KWIC index and an Author Index. Nuclear Safety is a bimonthly technical progress review prepared by the Nuclear Safety Information Center and covers all safety aspects of nuclear power reactors and associated facilities. The index lists over 300 technical articles in the last six years of publication

  14. Index to Nuclear Safety: a technical progress review by chronology, permuted title, and author. Vol. 11(1)--Vol. 18(6)

    Energy Technology Data Exchange (ETDEWEB)

    Cottrell, W.B.; Klein, A.

    1978-04-11

    This index to Nuclear Safety covers articles published in Nuclear Safety, Vol. 11, No. 1 (January-February 1970), through Vol. 18, No. 6 (November-December 1977). It is divided into three sections: a chronological list of articles (including abstracts) followed by a permuted-title (KWIC) index and an author index. Nuclear Safety, a bimonthly technical progress review prepared by the Nuclear Safety Information Center (NSIC), covers all safety aspects of nuclear power reactors and associated facilities. Over 450 technical articles published in Nuclear Safety in the last eight years are listed in this index.

  15. Index to Nuclear Safety. A technical progress review by chronology, permuted title, and author. Vol 11, No. 1 through Vol. 16, No. 6

    Energy Technology Data Exchange (ETDEWEB)

    Cottrell, W.B.; Klein, A.

    1976-04-01

    This index to Nuclear Safety covers articles in Nuclear Safety Vol. 11, No. 1 (Jan.-Feb. 1970) through Vol. 16, No. 6 (Nov.-Dec. 1975). Included in the index is a chronological list of articles (including abstract) followed by both a KWIC index and an Author Index. Nuclear Safety is a bimonthly technical progress review prepared by the Nuclear Safety Information Center and covers all safety aspects of nuclear power reactors and associated facilities. The index lists over 300 technical articles in the last six years of publication.

  16. Index to Nuclear Safety: a technical progress review by chronology, permuted title, and author, Volume 18 (1) through Volume 22 (6)

    International Nuclear Information System (INIS)

    This index to Nuclear Safety covers articles published in Nuclear Safety, Volume 18, Number 1 (January-February 1977) through Volume 22, Number 6 (November-December 1981). The index is divided into three section: a chronological list of articles (including abstracts), a permuted-title (KWIC) index, and an author index. Nuclear Safety, a bimonthly technical progress review prepared by the Nuclear Safety Information Center, covers all safety aspects of nuclear power reactors and associated facilities. Over 300 technical articles published in Nuclear Safety in the last 5 years are listed in this index

  17. Isobutanol-methanol mixtures from synthesis gas. Quarterly technical progress report, 1 April--30 June 30 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-25

    A series of CuMgCeO{sub x} catalysts have been prepared by coprecipitating the corresponding metal nitrates with a mixed solution of potassium carbonate and potassium hydroxide. Kinetic studies of methanol and ethanol coupling reactions on K-Cu/MgO/CeO{sub 2} and MgO/CeO{sub 2} catalysts indicate that Cu enhances the rates of alcohol dehydrogenation. The cross-coupling reactions of acetaldehyde and {sup 13}C-labeled methanol produce singly-labeled propionaldehyde, suggesting that it forms by the condensation of acetaldehyde and a reactive intermediate derived from methanol. Isobutyraldehyde, a precursor to isobutanol, forms via the condensation of propionaldehyde and a reactive C{sub 1} intermediate resulting from methanol. CO{sub 2}, one of the reaction products, poisons both basic and metal sites on Ce-containing CuMgO{sub x} catalysts, resulting in decreases in the rates of both alcohol dehydrogenation (Cu sites) and chain-growth condensation reactions (basic sites). CO{sub 2} inhibits ethanol dehydrogenation on both low-Cu and high-Cu CuMgCeO{sub x} catalysts; however, CO{sub 2} has no effect on the activity of low-Cu Ce-free Cu-MgO{sub x} catalysts, suggesting that the Cu on CuMgCeO{sub x} catalysts is more likely to be oxidized by CO{sub 2} to Cu{sup +} species that can be subsequently stabilized by CeO{sub 2}. CO{sub 2} effects on high-pressure isobutanol synthesis from CO/H{sub 2} have been studied on low- and high-Cu CuMgCeO{sub x} catalysts at 320{degrees}C and 4.5 MPa. CO{sub 2} addition and removal on low- and high-Cu catalysts show similar directional effects on CO conversion. CO conversion is lower at all space velocities in the presence of CO{sub 2}, and removal Of CO{sub 2} from the feed partially recovers CO conversion. CO{sub 2} decreases methanol and isobutanol productivities on both catalysts. Addition of 1-propanol to CO/H{sub 2} feed increases isobutanol production, suggesting that 1-propanol is a precursor to isobutanol.

  18. Research progress of catalysts for producing N-phosphonomethyl glycine by air (oxygen) catalytic oxidation%空气(氧气)催化氧化合成草甘膦催化剂的研究进展

    Institute of Scientific and Technical Information of China (English)

    陈丹; 李国儒; 黄敏建; 陈标华; 银凤翔

    2014-01-01

    用于空气(氧气)催化氧化双甘膦合成草甘膦的催化剂主要有活性炭催化剂、贵金属催化剂和过渡金属催化剂。本文分别概述了这3种催化剂的研究进展,分析比较了这些催化剂的优点和缺点:活性炭催化剂成本低廉、制备简单但是套用次数少,副产甲醛含量高;贵金属催化剂不仅收率高、产品质量好,而且催化剂可多次套用,但是成本过高,制备和再生也困难;过渡金属催化剂属均相催化,催化剂和产物易分离,但是产品收率较低。最后结合国内现状,认为开发一种催化效果更优、生产成本更低廉、使用和再生简单且环境友好的催化剂是国内草甘膦生产企业亟待解决的问题。%There are mainly three kinds of catalysts used for producing N-phosphonomethyl glycine by air (oxygen) catalytic oxidation:activated carbon,noble metal and transition metal catalysts. The research progress of these catalysts and their relative merits for applications in N-phosphonomethyl glycine synthesis are summarized and analyzed in this paper. Activated carbon catalysts are low cost and can be simply prepared,but they possess short working life and leave too much formaldehyde as by-product. Noble metal catalysts have long operation life and the obtained product is high yield with good quality,but the catalysts are high cost and difficult to be prepared and regenerated. Transition metal catalysts belong to homogeneous catalysts and can be easily separated from products but with low yield. Hence,to address the domestic problems faced by glyphosate enterprises,catalysts,which are low cost,environmental friendly and easily prepared and regenerated,with high activities are urgently required.

  19. Final Technical Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    J.Y. Hwang; R.C. Greenlund

    2002-12-31

    Michigan Technological University has demonstrated major inroads in establishing the viability of utilizing aluminum smelting by-product waste materials in lightweight concrete product applications. The research identified key elements of producing various forms of lightweight concrete products through utilizing various procedures and mixture components with the by-product materials. A process was developed through pilot plant testing that results in additional aluminum recovery at finer sizes, a clean returnable salt product through spray drying technology, and a low-salt-content oxide product with enough aluminum metal content that it can be used to form lightweight cementitious mixtures. Having three distinct products aids in generating favorable process economics. Revenue projections from aluminum recovery and salt recovery are enough to cover processing costs and create a cost-free oxide product to market for lightweight concrete applications. This supply side commercialization strategy offers aluminum by-product recyclers a potentially no cost product, which has been demonstrated through this project to create desirable and marketable lightweight concrete products of various forms. Environmental benefits to the public are tremendous. At best, all dross and salt cake materials have the potential to be completely recycled and utilized. At worst, disposal sites would see a reduced amount of material: a post processed oxide product with little salt and no hydrogen sulfide or ammonia gas generating capability, which, if isolated from high alkali conditions, would pose no reactivity concerns. The US aluminum industry has historically, along with the steel industry, been a leader in recycling metal. The findings from this project, increased metal recovery, improved salt recycling, and demonstrated end uses for oxide residues, will go a long way in helping the aluminum industry obtain 100% material utilization and zero discharge.

  20. Annual technical progress report

    International Nuclear Information System (INIS)

    During the present contract period Phaedrus has begun operation as a true tandem mirror. This was accomplished by achieving the rf sustained mode in which the plug densities were built up by a combination of central cell gas puffing and plug ICRH following stream gun turn off. It was demonstrated that the tandem mirror plasma could be sustained by plug ICRH for up to 1 msec following decay of the external plasma. In this mode plasma characteristics were no longer dominated by problems associated with a high conductivity stream gun plasma in the external region (as was the case in many previous experiments in Phaedrus). Among these problems were (1) line tying which significantly reduced instabilities in a way that would not apply to reactors and (2) low electron temperatures which had been held to approx. 20 eV

  1. 1995 technical progress report

    International Nuclear Information System (INIS)

    Summaries of the researches are grouped into programs as follows: research and development which covers all the PNRI research projects in 1994; scientific and technological services; and the nuclear regulations, licensing and safeguards of the institute

  2. 1997 technical progress report

    International Nuclear Information System (INIS)

    This report presents the on-going research and development projects of the Philippine Nuclear Research Institute (PNRI) in the fields of agriculture, environment and industry, scientific and technological services and nuclear regulations, licensing and safeguards

  3. Technical Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Paul D. Ronney

    2004-08-26

    An ignition source was constructed that is capable of producing a pulsed corona discharge for the purpose of igniting mixtures in a test chamber. The corona generator can also be used as the ignition source for one cylinder on a test engine. The first tests were performed in a cylindrical shaped chamber to study the characteristics of the corona and analyze various electrode geometries. Next a test chamber was constructed that closely represented the dimensions of the combustion chamber of the test engine at USC. Combustion tests were performed in this chamber and various electrode diameters and geometries were tested. Higher peak pressures and faster pressure rise times were realized consistently in all test chambers versus standard spark plug ignition. A test engine was purchased for the project that has two spark plug ports per cylinder to The data acquisition and control system hardware for the USC engine lab was updated with new equipment. New software was also developed to perform the engine control and data acquisition functions including cylinder pressure monitoring. A ceramic corona electrode has been designed that fits in the new test engine and is capable of withstanding the pressures and temperatures encountered inside the combustion chamber. The corona ignition system was tested on the engine and an increase in both peak pressure and IMEP were seen in the initial test. There are issues that must be addressed before on-engine testing can continue such as EMF interference from the corona generator and electrical insulation on portions of the piston and cylinder head to prevent arcing. The EMF issue can be solved with proper shielding and grounding and various ceramic coatings are being researched for electrical insulation.

  4. 1996 technical progress report

    International Nuclear Information System (INIS)

    Summaries of the researches are grouped into programs as follows: research and development in food and agriculture; research and development in health, environment and industry which includes all the PNRI research projects in 1996; scientific and technological services; and the nuclear regulations, licensing and safeguards of the institute

  5. 1999 technical progress report

    International Nuclear Information System (INIS)

    This report presents the on-going research and development projects of the Philippine Nuclear Research Institute (PNRI) in the fields of agriculture, environment and industry, scientific and technological services and nuclear regulations, licensing and safeguards

  6. GPHS-RTGs in support of the Cassini Mission. Semi annual technical progress report, 1 April 1996--29 September 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-20

    This technical progress report discusses work on the Radioisotope Generators and Ancillary Activities for the Cassini spacecraft. The Cassini spacecraft is expected to launch in October 1997, and will explore Saturn and its moons. This progress report discusses issues in: spacecraft integration and liason, engineering support, safety, qualified unicouple fabrication, ETG fabrication and testing, ground support equipment, RTG shipping and launch support, designs, reviews and mission application. Safety analysis of the RTGs during reentry and launch accidents are covered. This report covers the period of April 1 to September 29, 1996.

  7. GPHS-RTGs in support of the Cassini Mission. Semi annual technical progress report, 1 April 1996--29 September 1996

    International Nuclear Information System (INIS)

    This technical progress report discusses work on the Radioisotope Generators and Ancillary Activities for the Cassini spacecraft. The Cassini spacecraft is expected to launch in October 1997, and will explore Saturn and its moons. This progress report discusses issues in: spacecraft integration and liason, engineering support, safety, qualified unicouple fabrication, ETG fabrication and testing, ground support equipment, RTG shipping and launch support, designs, reviews and mission application. Safety analysis of the RTGs during reentry and launch accidents are covered. This report covers the period of April 1 to September 29, 1996

  8. 无机碳材料负载固相金属催化剂研究进展%Research progress in inorganic carbon material supported solid metal catalyst

    Institute of Scientific and Technical Information of China (English)

    杨玉; 许佩瑶; 汪黎东

    2016-01-01

    综述了无机碳材料纳米碳管、活性炭纤维和膨胀石墨作为固相金属催化剂载体的国内外研究进展,探讨催化剂的不同负载方法,分析无机碳材料负载固相金属催化剂活性的影响因素及其应用领域。发现无机碳材料负载固相金属催化剂已经应用于催化加氢、光催化、电催化、水处理及大气处理方面,将其用于烟气脱硫副产物亚硫酸盐的处理,不仅能解决催化剂浪费问题,还能避免二次污染的发生。%The research progress in carbon nanotube materials,activated carbon fiber and expanded graphite as solid phase metallic catalyst carriers at home and abroad was reviewed. The different loading methods of the catalysts were discussed. The influence factors of the activity of the solid phase metallic catalysts sup-ported on inorganic carbon materials and their application fields were analyzed. It was found that the solid phase metallic catalysts supported on inorganic carbon materials were applied in the catalytic hydrogenation, photocatalysis,electro-catalysis,water treatment and air treatment. The solid phase metallic catalysts sup-ported on inorganic carbon materials were used for the treatment of by-product sulfite from flue gas desul-furization,which could solve the problem of the catalyst waste,and secondary pollution.

  9. Determination of optimum electrolyte composition for molten carbonate fuel cells. Quarterly technical progress report, October--December 1987

    Energy Technology Data Exchange (ETDEWEB)

    Yuh, C.Y.; Pigeaud, A.

    1987-12-31

    The goal of this program is the development of a molten carbonate fuel cell (MCFC) anode which is more tolerant of sulfur contaminants in the fuel than the current state-of-the-art nickel-based anode structures. This program addresses two different but related aspects of the sulfur contamination problem. The primary aspect is concerned with the development of a sulfur tolerant electrocatalyst for the fuel oxidation reaction. A secondary issue is the development of a sulfur tolerant water-gas-shift reaction catalyst and an investigation of potential steam reforming catalysts which also have some sulfur tolerant capabilities. These two aspects are being addressed as two separate tasks.

  10. 一步酯交换法合成碳酸二甲酯催化剂研究进展%Progress in Research on Synthesis of Dimethyl Carbonate Catalysts by One-step Transesterification

    Institute of Scientific and Technical Information of China (English)

    陈久标

    2012-01-01

    综述了一步酯交换法合成碳酸二甲酯催化剂的研究进展,阐述了所用催化剂的组成、性质和催化活性,从反应产物分析推测了反应机理.适宜孔径的碱性沸石分子筛等多孔材料将是合成多相催化剂载体的首选材料.制备高活性、高选择性、高稳定性的多相催化剂将是今后催化剂研究的方向.%The progress in research on synthesis of dimethyl carbonate catalysts by one-step tranaeaterification is reviewed. The catalyst compositions, characteristics and catalytic activity arc presented. The reaction mechanisms are conjectured in terms of reaction products. The porous materials will be the preferred material for synthesis of heterogeneous catalyst carrier, such as zeolite molecular sieve with suitable pore size. The preparation of heterogeneous catalyst with high activity, high selectivity and high stability is an important issue for further research work.

  11. Progress in supported catalyst study for the copolymerization of carbon dioxide with epoxides%CO2和环氧化合物共聚负载型催化剂的研究进展

    Institute of Scientific and Technical Information of China (English)

    母佳利; 范文俊; 陕绍云; 蒋丽红; 王亚明; 贾庆明

    2013-01-01

    Aliphatic polycarbonates made from carbon dioxide and epoxides are biodegrable polymeric materials,which is to develop environment-friendly materials with a bright prospect.Supporting catalyst strategy was a good choice to achieve catalyst recycles use.The paper gives an overview the recent progress in research of supported catalysts for such a copolymerization process.Provide guidance on the supported catalysts for the further study.%CO2与环氧化合物共聚生成脂肪族聚碳酸酯,其塑料具有生物可降解性,是一类具有发展前景的环境友好型材料.为了实现该过程中催化剂的循环使用,对催化剂进行负载化是一个有效的途径.对CO2和环氧化合物共聚中负载型催化剂的研究进展进行了综述,为该领域负载型催化剂的进一步研究提供指导.

  12. PILOT TESTING OF MERCURY OXIDATION CATALYSTS FOR UPSTREAM OF WET FGD SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    Gary M. Blythe

    2003-05-01

    This document summarizes progress on Cooperative Agreement DE-FC26-01NT41185, ''Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems,'' during the time period January 1, 2003 through March 31, 2003. The objective of this project is to demonstrate at pilot scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion. The project is being funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-01NT41185. EPRI, Great River Energy (GRE), and City Public Service (CPS) of San Antonio are project cofunders. URS Group is the prime contractor. The mercury control process under development uses catalyst materials applied to honeycomb substrates to promote the oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone flue gas desulfurization (FGD) systems. Oxidized mercury is removed in the wet FGD absorbers and co-precipitates with the byproducts from the FGD system. The current project is testing previously identified, effective catalyst materials at a larger, pilot scale and in a commercial form, to provide engineering data for future full-scale designs. The pilot-scale tests will continue for up to 14 months at each of two sites to provide longer-term catalyst life data. This is the sixth full reporting period for the subject Cooperative Agreement. During this period, project efforts included continued operation of the pilot unit with three catalysts, conducting catalyst activity measurements, and procuring the fourth catalyst, all for the GRE Coal Creek pilot unit site. Laboratory efforts were also conducted to support catalyst selection for the second pilot unit site, at CPS' Spruce Plant. This technical progress report provides an update on these efforts.

  13. Heterogeneous catalytic process for alcohol fuels from syngas. Quarterly technical progress report No. 8, October--December 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    The novel heterogeneous catalysts for conversion of syngas to oxygenates having use as fuel enhancers, to explore novel reactor and process concepts applicable in this process, and to develop the best total process for converting syngas to liquid fuels. Our current targets for isobutanol-producing catalysts are to produce an equimolar mixture of methanol and isobutanol with a productivity for isobutanol of > 50 g/Kg-hr. Reactor system modifications, undertaken to improve data quality, have been completed. The changes should help eliminate differences between the two reactors and allow for more accurate determination of higher molecular weight products. To calibrate our new reactor system, we have retested our ``best`` isobutanol catalyst, 10-DAN-54 (a promoted Zn/Cr/Mn spinel oxide). Under standard test conditions (400{degrees}C, 1000 psi, 12000 GHSV and syngas ratio = 1:1), this catalyst produces 200--252 g/kg-hr of total alcohols (total alcohol selectivities of 57--68%) with an isobutanol rate of 94--130 g/kg-hr and a MeOH/i-BuOH product mole ratio of 3. These results compare with a productivity of 112 g/kg-hr of total alcohols (total alcohol selectivity of 86%) with an isobutanol rate of 38 g/kg-hr and a MeOH/i-BuOH product mole ratio of 3 observed in the original microreactor system configuration. It should be remembered that the test apparatus is designed for screening only. Detailed, more reliable data for kinetic modeling must be generated using larger catalyst charges (> 10g) and in larger scale test equipment.

  14. Synthesis Research Progress on Ruthenium Indenylidene Catalysts Used in Olefin Metathesis%用于烯烃复分解反应的钌茚基催化剂的合成研究进展

    Institute of Scientific and Technical Information of China (English)

    开铖; Francis Verpoort

    2016-01-01

    基于钌金属的烯烃复分解反应现今已成为一种至关重要且快速有效的催化反应类型,在聚合领域以及现代有机合成的应用方面起着改革性的推进作用。作为烯烃复分解反应催化剂的一种,钌茚基催化剂在该领域得到成功应用。结合近年来钌茚基催化剂在烯烃复分解反应中的合成研究进展,简述了其发展过程,介绍了该领域创新性的研究成果,重点论述了一些新型钌茚基催化剂的合成方法,并且探讨了辅助配体的结构对催化剂稳定性和活性的影响,最后对其发展方向以及应用前景进行了展望。%Olefin metathesis based on ruthenium has already become an important and effective catalytic reaction and has revolutionized a variety of applications not only in polymer science but also in modern organic synthesis.Ru-thenium indenylidene catalysts,a family of ruthenium olefin metathesis catalysts,have played a pivotal role in the suc-cess story of this technology.In this review,the recent synthesis research progress on ruthenium indenylidene cata-lysts is discussed.Firstly,the development of ruthenium indenylidene catalysts is introduced followed by an overview of the innovative work on the design of ruthenium indenylidene catalysts till today.Moreover,the synthesis of some novel important ruthenium indenylidene catalysts is highlighted.In addition,the relation between the structure of an-cillary ligands and the stability as well as activity of catalysts is discussed.Finally,the development directions and ap-plication prospects of ruthenium indenylidene catalysts are proposed.

  15. 催化氧化脱硫分子筛催化剂研究进展%Research progress of molecular sieve catalyst for catalytic oxidative desulfurization

    Institute of Scientific and Technical Information of China (English)

    宋华; 穆金城

    2011-01-01

    The advance in catalytic oxidative desulfurization over molecular sieve, including TS molecular sieve catalyst, SBA molecular sieve catalyst, HMS molecular sieve catalyst, MCM molecular sieve catalyst, ZSM-5 molecular sieve catalyst, and aluminophosphate molecular sieve catalyst is summarized. Among these molecular sieve catalysts, SBA, HMS, MCM, aluminophosphate mesoporous molecular sieves catalysts have higher desulfurization rate of macromolecule sulfides and therefore have good prospect. The research of molecular sieve catalyst for oxidative desulfurization should be focused on developing large pore size general molecular sieve, investigating the mechanism and reducing the cost of oxidative desulfurization.%综述了催化氧化脱硫分子筛催化剂的研究进展.介绍了TS分子筛催化剂、SBA分子筛催化剂,HMS分子筛催化剂、MCM分子筛催化剂、ZSM-5分子筛催化剂和磷酸铝分子筛催化剂上油品的氧化脱硫方法,其中SBA、HMS、MCM和磷酸铝介孔分子筛催化剂对大分子的硫化物脱除率较高,具有很好的发展前景.今后分子筛催化氧化脱硫技术研究的重要方向是进一步开发通用性好的大孔径分子筛,研究脱硫机理和降低成本.

  16. Technical reliability of geological disposal for high-level radioactive wastes in Japan. The second progress report. Part 1. Geological environment of Japan

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    Based on the Advisory Committee Report on Nuclear Fuel Cycle Backend Policy submitted to the Japanese Government in 1997, JNC documents the progress of research and development program in the form of the second progress report (the first one published in 1992). It summarizes an evaluation of the technical reliability and safety of the geological disposal concept for high-level radioactive wastes (HLW) in Japan. The present document, the part 1 of the progress report, describes first in detail the role of geological environment in high-level radioactive wastes disposal, the features of Japanese geological environment, and programs to proceed the investigation in geological environment. The following chapter summarizes scientific basis for possible existence of stable geological environment, stable for a long period needed for the HLW disposal in Japan including such natural phenomena as volcano and faults. The results of the investigation of the characteristics of bed-rocks and groundwater are presented. These are important for multiple barrier system construction of deep geological disposal. The report furthermore describes the present status of technical and methodological progress in investigating geological environment and finally on the results of natural analog study in Tono uranium deposits area. (Ohno, S.)

  17. Technical reliability of geological disposal for high-level radioactive wastes in Japan. The second progress report. Part 1. Geological environment of Japan

    International Nuclear Information System (INIS)

    Based on the Advisory Committee Report on Nuclear Fuel Cycle Backend Policy submitted to the Japanese Government in 1997, JNC documents the progress of research and development program in the form of the second progress report (the first one published in 1992). It summarizes an evaluation of the technical reliability and safety of the geological disposal concept for high-level radioactive wastes (HLW) in Japan. The present document, the part 1 of the progress report, describes first in detail the role of geological environment in high-level radioactive wastes disposal, the features of Japanese geological environment, and programs to proceed the investigation in geological environment. The following chapter summarizes scientific basis for possible existence of stable geological environment, stable for a long period needed for the HLW disposal in Japan including such natural phenomena as volcano and faults. The results of the investigation of the characteristics of bed-rocks and groundwater are presented. These are important for multiple barrier system construction of deep geological disposal. The report furthermore describes the present status of technical and methodological progress in investigating geological environment and finally on the results of natural analog study in Tono uranium deposits area. (Ohno, S.)

  18. For the acceleration of scientific and technical progress in coal mining a central authority is required for conception and realization of a single technical branch policy

    Energy Technology Data Exchange (ETDEWEB)

    Markov, L.

    1988-02-01

    Discusses scientific and technical developments in Bulgarian coal mining. Until 1988, research, investigations and design were largely carried out by the Minproekt and Minstroi institutes and by higher schools of mining, usually according to a national plan determined by the Energetika association, state power and mining associations and the Association of Engineers and Technicians. After 1. January, 1988, when self-management is planned to be introduced, individual enterprises will carry out their own research, together with research institutes and other organizations. Experience acquired by the FRG, UK and France may be evaluated and advantageously applied to Bulgarian conditions. Recommendations for the future include: importing equipment and technology from abroad; basing domestic research and design around local problems and requirements; forming a central commission and several working groups to evaluate and plan research work; using experienced technical personnel for experimental introduction of new technologies; establishing experimental laboratories and mine fields in large mines and associations. 2 refs.

  19. Oxygenated octane enhancers: Syngas to isobutylene. Technical progress report No. 17, April 1, 1995--June 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Barger, P.T.; Kurek, P.R.

    1996-01-18

    The goals of this project are to develop a catalyst and process for the conversion of syngas to isobutanol. The research will identify and optimize key catalyst and process characteristics. In addition, the commercial potential of the new process will be evaluated by an economic analysis. The effects of temperature, pressure and methanol/ethanol molar feed ratio on the performance of the 2% Pt on Zn/Mn/Zr Oxide catalyst has been evaluated in a series of pilot plant tests. Temperature has been varied from 325{degrees}C to 375{degrees}C, pressure from 30 psig to 300 psig and MeOH/EtOH ratio from 1 0/1 to 1 /1. Raising temperature increases alcohol conversion, but reduces selectivity and productivity to the desired branched C4 oxygenates. The higher pressure operation shifts the product ratio from isobutyraldehyde to isobutanol. Decreasing the feed ratio from 10/1 to 7/1 increases methanol conversion as well as selectivity to each of the iC4 oxygenates. However, further reduction of the feed ratio to 4/1 does not give additional improvement. Based on these findings a pilot plant test at optimized conditions is planned using the 2% Pt on Zn/Mn/Zr oxide catalyst. The effects of H{sub 2}, CO and CO{sub 2} co-feeds on the performance of the cztalyst have also been evaluated using the reference catalyst. Co-feeding H{sub 2} has very little effect, whereas CO has a deleterious effect. CO{sub 2} addition results in higher CO formation, but no substantial change in CO{sub 2} selectivity. Therefore, it appears that the use of a CO{sub 2} recycle would not be effective for reducing the formation of carbon oxide products. A copper-lined reactor has been constructed that gives acceptable blank activity at temperatures up to 450{degrees}C and used to evaluate the activity of the 2% Pt on Zn/Mn/Zr oxide catalyst for methanol-only conversion. At temperatures greater than 350{degrees}C, minimal branched C4 oxygenates are formed. Instead, the primary products are CO and CO{sub 2}.

  20. Oxygenated octane enhancers: Syngas to isobutylene. Technical progress report No. 18, July 1, 1995--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Barger, P.T.; Spehlmann, B.C.

    1996-03-28

    The goals of this project are to develop a catalyst and process for the conversion of syngas to isobutanol. The research will identify and optimize key catalyst and process characteristics. In addition, the commercial potential of the new process will be evaluated by an economic analysis. The combination of the best conditions from independent process variable studies has afforded the best performance to date with the 2% Pt on Zn/Mn/Zr oxide catalyst. At 325{degrees}C, 300 psig, 7/1 MeOH/EtOH molar feed ratio and 1 hr{sup {minus}1} MEOH WH 22.20% selectivity to isobutanol is obtained with 55 and 97% conversions of methanol and ethanol, respectively. The results of this run will be used as a basis for the economic evaluation of a higher alcohols process. The ability of the Pt on Zn/Mn/Zr oxide catalyst to produce isobutanol in the presence of high partial pressures of H{sub 2} has been investigated. Such operation could allow the integration of a higher alcohol process with a conventional methanol synthesis plant by placing it within the methanol synthesis recycle loop. However, higher alcohol yields are severely suppressed by a large H{sub 2} cofeed, even at pressures as low as 50 psig. Elimination of the H{sub 2} co-feed did not restore the performance of the catalyst to expected levels, suggesting that the high H{sub 2} partial pressure has caused degradation of the catalyst. No further testing of high H{sub 2} conditions is planned. The commercial system has been modeled using the product slate obtained from the ``best case`` pilot plant conditions combined with the assumption of equilibrium CO, H{sub 2}O, CO{sub 2} and H{sub 2} makes. A stand-alone isobutanol plant processing 500 MT/D synthesis gas-derived methanol can yield 92 MT/D isobutanol and additional 20 MT/D assuming complete hydrogenation of isobutyraldehyde which accumulates in the liquid recycle loop. The economic analyses of this system are pending.

  1. Model catalyst studies of SMSI and the role of D-electrons in chemisorption and catalysis. Progress report, January 15, 1985-January 14, 1986

    International Nuclear Information System (INIS)

    Electron spectroscopic studies of the surface composition, electronic structure and chemisorption properties of model Rh/TiO2 catalysts fabricated on well characterized single-crystal supports have provided evidence that argues strongly against the simple charge transfer model of strong metal-support interaction that involves the transfer of electrons from surface Ti3+ ions that are created by high temperature reduction. The presence of surface Ti3+ ions does appear to be necessary in order to facilitate the migration of sub-oxides over the catalyst particles in the SMSI state, but hydrogen is not necessary if Ti3+ defect sites exist prior to high temperature annealing. A newly constructed electron beam evaporation source is now being used for in situ deposition of Rh onto TiO2 supports, giving greater control over catalyst loading and particle size. TEM studies of catalyst morphology, performed in parallel with the electron spectroscopic studies, are continuing. 3 figs

  2. Progress of catalysts in synthesis of dimethyl carbonate from methanol and carbon dioxide%甲醇和二氧化碳合成碳酸二甲酯催化剂的研究进展

    Institute of Scientific and Technical Information of China (English)

    师艳宁; 高伟; 王淑莉; 金洗郎; 李剑利; 史真

    2012-01-01

    碳酸二甲酯是一种重要的绿色化工产品,甲醇和二氧化碳直接合成碳酸二甲酯是符合“绿色化学”的合成路线.综述了近年来该路线合成碳酸二甲酯催化剂的研究进展,简述了各类催化剂的催化机理、催化效能及发展趋势.%Dimethyl carbonate is a kind of important green chemical product. Direct synthesis of dimethyl carbonate from methanol and carbon dioxide is a type of green synthetic route. In this paper, the recent progresses of catalysts in synthesis of dimethyl carbonate were reviewed. The mechanisms, catalytic effect and development tendency of the catalysts were discussed.

  3. 负载型催化剂催化二氧化碳和环氧化合物共聚的研究进展%Progress in Supported Catalyst for the Copolymerization of Carbon Dioxide and Epoxides

    Institute of Scientific and Technical Information of China (English)

    母佳利; 胡庭维; 陕绍云; 蒋利红; 王亚明; 贾庆明

    2013-01-01

    The active component/species of catalyst supported on inorganic or polymers supporters strategy is a good choice to achieve catalyst recycles use,which can improve the thermodynamic performance and mechanical behavior of the aliphatic polycarbonates synthesized directly from carbon dioxide and epoxides.The recent progress in research of supported catalysts for such a copolymerization process was reviewed.Focused on the various immobilization approaches,catalytic efficiency,properties of the products,drawbacks andadvantages,these systems include carboxylic zinc systems,metal-salen complexes and rare earth ternary catalyst systems and so on,providing the guidance on the supported catalysts for the further study.%为了实现二氧化碳与环氧化合物共聚制备脂肪族聚碳酸酯过程中催化剂的循环利用,提高产物的热力学和力学性能,对其均相催化剂进行载化,即将活性组分/中心负载在无机或高分子载体上是一条有效的途径.文中综述了二氧化碳和环氧化合物共聚中负载型催化剂的研究进展,重点对羧酸锌催化体系、SalenMX催化体系、稀土三元催化体系等不同负载型催化剂的制备方法、催化效率、产物性能及优缺点进行了系统阐述,为负载型催化剂的进一步研究提供了参考.

  4. Heterogeneous catalytic process for alcohol fuels from syngas. Fifteenth quarterly technical progress report, July--September 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-31

    The principal objectives of this project are to discover and evaluate novel heterogeneous catalysts for conversion of syngas to oxygenates having use as fuel enhancers, to explore novel reactor and process concepts applicable in this process, and to develop the best total process for converting syngas to liquid fuels. The previous best catalysts consisted of potassium-promoted Pd on a Zn/Cr spinel oxide prepared via controlled pH precipitation. The authors have now examined the effect of cesium addition to the Zn/Cr spinel oxide support. Surprisingly, cesium levels required for optimum performance are similar to those for potassium on a wt% basis. The addition of 3 wt% cesium gives isobutanol rates > 170 g/kg-hr at 440 C and 1,500 psi with selectivity to total alcohols of 77% and with a methanol/isobutanol mole ratio of 1.4: this performance is as good as their best Pd/K catalyst. The addition of both cesium and palladium to a Zn/Cr spinel oxide support gives further performance improvements. The 5 wt% cesium, 5.9 wt% Pd formulation gives isobutanol rates > 150 g/kg-hr at 440 C and only 1,000 psi with a selectivity to total alcohols of 88% and with a methanol/isobutanol mole ratio of 0.58: this is their best overall performance to date. The addition of both cesium and palladium to a Zn/Cr/Mn spinel oxide support that contains excess Zn has also been examined. This spinel was the support used in the synthesis of 10-DAN-54, the benchmark catalyst. Formulations made on this support show a lower overall total alcohol rate than those using the spinel without Mn present, and require less cesium for optimal performance.

  5. Design, Synthesis, and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals. Technical Progress Report

    International Nuclear Information System (INIS)

    promoter. The kinetic behavior of these materials, specifically the effects of H2, CO, and CO2 on the rates and selectivities of Fischer-Tropsch synthesis reactions has led to a new proposal for the nature of rate-determining steps on Fe and Co Fischer-Tropsch catalysts, and more specifically to the roles of hydrogen-assisted and alkali-assisted dissociation of CO in determining rates and CO2 selectivities. Finally, we have started an exploratory study of the use of colloidal precipitation methods for the synthesis of small Fe and Co clusters using recently developed methods. During this period, we have had to restrict manpower assigned to this project because some irregularities in reporting and communications have led to the interruption of funding during this period. This has led to less than optimal productivity and to significant disruptions of the technical work. These issues have also led to significant underspending of project funds during this reporting period and to our consequent request for a no-cost extension of one year, which we understand has been granted

  6. Technical reliability of geological disposal for high-level radioactive wastes in Japan. The second progress report. Introductory part and summaries

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    Based on the Advisory Committee Report on Nuclear Fuel Cycle Backend Policy submitted to the Japanese Government in 1997, JNC documents the progress of research and development program in the form of the second progress report (the first one published in 1992). It summarizes an evaluation of the technical reliability and safety of the geological disposal concept for high-level radioactive wastes (HLW) in Japan and comprises seven chapters. Chapter I briefly describes the importance of HLW management in promoting nuclear energy utilization. According to the long-term program, the HLW separated from spent fuels at reprocessing plants is to be vitrified and stored for a period of 30 to 50 years to allow cooling, then be disposed of in a deep geological formation. Chapter II mainly explains the concepts of geological disposal in Japan. Chapters III to V are devoted to discussions on three important technical elements (the geological environment of Japan, engineering technology and safety assessment of the geological disposal system) which are necessary for reliable realization of the geological disposal concept. Chapter VI demonstrates the technical ground for site selection and for setup of safety standards of the disposal. Chapter VII summarizes together with plans for future research and development. (Ohno, S.)

  7. SPACE-R Thermionic Space Nuclear Power System: Design and Technology Demonstration Program. Semiannual technical progress report for period ending March 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-05-01

    This Semiannual Technical Progress Report summarizes the technical progress and accomplishments for the Thermionic Space Nuclear Power System (TI-SNPS) Design and Technology Demonstration Program of the Prime Contractor, Space Power Incorporated (SPI), its subcontractors and supporting National Laboratories during the first half of the Government Fiscal Year (GFY) 1993. SPI`s subcontractors and supporting National Laboratories include: Babcock & Wilcox for the reactor core and externals; Space Systems/Loral for the spacecraft integration; Thermocore for the radiator heat pipes and the heat exchanger; INERTEK of CIS for the TFE, core elements and nuclear tests; Argonne National Laboratories for nuclear safety, physics and control verification; and Oak Ridge National laboratories for materials testing. Parametric trade studies are near completion. However, technical input from INERTEK has yet to be provided to determine some of the baseline design configurations. The INERTEK subcontract is expected to be initiated soon. The Point Design task has been initiated. The thermionic fuel element (TFE) is undergoing several design iterations. The reactor core vessel analysis and design has also been started.

  8. Technical reliability of geological disposal for high-level radioactive wastes in Japan. The second progress report. Introductory part and summaries

    International Nuclear Information System (INIS)

    Based on the Advisory Committee Report on Nuclear Fuel Cycle Backend Policy submitted to the Japanese Government in 1997, JNC documents the progress of research and development program in the form of the second progress report (the first one published in 1992). It summarizes an evaluation of the technical reliability and safety of the geological disposal concept for high-level radioactive wastes (HLW) in Japan and comprises seven chapters. Chapter I briefly describes the importance of HLW management in promoting nuclear energy utilization. According to the long-term program, the HLW separated from spent fuels at reprocessing plants is to be vitrified and stored for a period of 30 to 50 years to allow cooling, then be disposed of in a deep geological formation. Chapter II mainly explains the concepts of geological disposal in Japan. Chapters III to V are devoted to discussions on three important technical elements (the geological environment of Japan, engineering technology and safety assessment of the geological disposal system) which are necessary for reliable realization of the geological disposal concept. Chapter VI demonstrates the technical ground for site selection and for setup of safety standards of the disposal. Chapter VII summarizes together with plans for future research and development. (Ohno, S.)

  9. Homogeneous catalysts

    CERN Document Server

    Chadwick, John C; Freixa, Zoraida; van Leeuwen, Piet W N M

    2011-01-01

    This first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste.The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics.

  10. Research progress in heterogeneous chromium oxide catalyst for PE%非均相氧化铬PE催化剂的研究进展

    Institute of Scientific and Technical Information of China (English)

    冉印; 崔楠楠; 徐国强; 刘东兵; 王洪涛

    2011-01-01

    非均相氧化铬催化剂的聚合机理包括Cr6+还原为Cr2+形成活性中心的过程、链引发的单活性中心机理、链增长的Cossee机理、通过B-H消除的链终止机理.硅胶、磷酸铝等载体的改性影响催化剂活性和聚合物性质:氧化铬催化剂的负载和活化过程,氟、钛、磷、卤代烃等改性剂对氧化铬催化剂性能有重要的影响,铬系催化剂与其他催化剂复配使用也能缩短诱导期,提高聚合活性,并制备出宽相对分子质量分布的聚乙烯.%The polymerization mechanisms in the presence of heterogeneous chromium oxide catalysts involve the reduction and activation from Cr6+ to Cr2+, the single active center mechanism of chain initiation, the Cossee mechanism of chain propagation and the termination mechanism based on |J-hydrogen elimination. The modification of carriers like silicon and aluminophosphates exerts influence on the catalysts' activity and the resultant polymers' properties. The loading and activation process of the catalysts and the addition of modifiers like fluorine, titanium, phosphorus and halohydrocarbon have impact on the properties of chromium oxide catalysts. The application of composite catalysts consisting of the chromium-based catalysts and other catalysts can shorten the induction time, improve the polymerization activity and produce polyethylene with broad relative molecular mass distribution.

  11. Engineering-support services for the DOE/GRI coal-gasification research program. Quarterly technical progress report, October-December 1980

    Energy Technology Data Exchange (ETDEWEB)

    Bostwick, L.E.; Brancheau, R.J.; Chen, R.G.

    1980-01-01

    Kellogg activities included continued monitoring of test operations at BI-GAS, Westinghouse, Exxon and IGT (for peak gasification). Pilot plant/PDU test runs which were monitored and reported included: BI-GAS tests G-14, G-14A, G-15 and G-15A; Westinghouse PDU tests TP-027-5 and TP-031-1 and CFSF tests TP-M001-1, 2, 3 and 4; Exxon run periods No. 23 and No. 24; and IGT single-stage peat gasification tests BF-1 through BF-6. Draft reports were submitted regarding Hygas data base evaluation, gasifier vessel design and scaleup risks of the Westinghouse oxygen-blown gasifier. Evaluation of the Hygas data base continued, and a similar study of the Peatgas PDU data base was initiated. Work was begun on preparation of a descriptive brochure for the DOE/GRI joint program. Kellogg personnel participated in investigations of welding materials with the MPC. Significant progress was made in the technical/economic assessments of Westinghouse, Exxon and Peatgas and in the technical/economic comparison of Westinghouse and U-gas, with technical definitions being essentially finished and cost estimation begun. Technical definition and preliminary capital cost estimates were completed for the peat harvesting/dewatering study. Work continued in the study of carbonyl formation. Following reviews by the developers, Kellogg began finalization of the report on screening evaluations of Westinghouse, Exxon and Rockwell. Work on the safety assurance study continued, with the commencement of safety audit visits.

  12. 苯乙炔半加氢催化剂研究进展%Research Progress of Phenylacetylene Semi-hydrogenation Catalysts

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    对苯乙烯的生产现状进行了说明,并对从裂解汽油中获得苯乙烯的应用前景进行了分析;重点对国内外的最新苯乙炔加氢催化剂的前沿研究进行了报道,从贵金属催化剂、非贵金属催化剂的角度进行了分析,详细介绍了一些具有新颖性的催化剂的制备方法,并对催化剂的使用条件、性能及对苯乙烯的选择性进行了分析。%The production status of styrene was introduced, and application prospect of obtaining styrene from pyrolysis gasoline was analyzed; Researches on the domestic and foreign latest phenylacetylene hydrogenation catalyst were reported, precious metal catalysts and non-noble metal catalysts were introduced as well as preparation methods of some novel catalysts. At last, conditions of use, performance and styrene selectivity of the catalysts were analyzed.

  13. PILOT TESTING OF MERCURY OXIDATION CATALYSTS FOR UPSTREAM OF WET FGD SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    Gary M. Blythe

    2003-01-21

    This document summarizes progress on Cooperative Agreement DE-FC26-01NT41185, Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems, during the time period October 1, 2002 through December 31, 2002. The objective of this project is to demonstrate at pilot scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion. The project is being funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-01NT41185. EPRI, Great River Energy (GRE), and City Public Service (CPS) of San Antonio are project co-funders. URS Group is the prime contractor. The mercury catalytic oxidation process under development uses catalyst materials applied to honeycomb substrates to promote the oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone flue gas desulfurization (FGD) systems. Oxidized mercury is removed in the wet FGD absorbers and co-precipitates with the byproducts from the FGD system. The co-precipitated mercury does not appear to adversely affect the disposal or reuse properties of the FGD byproduct. The current project testing previously identified, effective catalyst materials at a larger, pilot scale and in a commercial form, to provide engineering data for future fullscale designs. The pilot-scale tests will continue for up to 14 months at each of two sites to provide longer-term catalyst life data. This is the fifth full reporting period for the subject Cooperative Agreement. During this period, project efforts included starting up the pilot unit with three catalysts at the first site, conducting catalyst activity measurements, completing comprehensive flue gas sampling and analyses, and procuring additional catalysts for the pilot unit. This technical progress report provides an update on these efforts.

  14. Isobutanol-methanol mixtures from synthesis gas. Quarterly technical progress report, October 1, 1996--December 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    A series of MgO-based Cu catalysts have been prepared by coprecipitating the corresponding metal nitrates with a mixed solution of potassium carbonate and potassium hydroxide. The bulk composition of the catalyst has been measured by atomic absorption (AA) analysis and the Cu dispersion has been determined by N{sub 2}O titration at 363 K. Kinetic studies of ethanol coupling reactions on Cu{sub 0.5}Mg{sub 5}CeO{sub x} and 1.0 wt % K-Cu{sub 0.5}Mg{sub 5}CeO{sub x} catalyst indicates that at similar steady-state acetaldehyde concentrations, the presence of K increases the rates of base-catalyzed aldol coupling reactions to acetone and butyraldehyde. Aldol coupling chain growth reaction rates on 1.2 wt % K-Cu{sub 7.5}Mg{sub 5}CeO{sub x} are higher than on 1.0 wt % K-Cu{sub 0.5}Mg{sub 5}CeO{sub x} even though basic site densities are similar on both samples, suggesting that Cu metal sites are also involved in rate-determining steps required for condensation reactions. Cu appears to enhance the desorption of H{sub 2} via the migration of H species from basic to Cu sites and makes the basic sites available for subsequent C-H bond activation steps. Addition of CO{sub 2} decreases the rate of base-catalyzed chain growth reaction to acetone, but does not affect the rate of ethanol dehydrogenation reaction on Cu metal sites

  15. Heterogeneous catalytic process for alcohol fuels from syngas. Fourteenth quarterly technical progress report, April--June 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-31

    The project objectives are: (1) To discover, study, and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas. In particular, novel heterogeneous catalysts will be studied and optimized for the production of: (a) C{sub 1}-C{sub 5} alcohols using conventional methanol synthesis conditions, and (b) methanol and isobutanol mixtures which may be used for the downstream synthesis of MTBE or related oxygenates. (2) To explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. (3) To develop on the bench scale the best combination of chemistry, catalyst, reactor, and total process configuration to achieve the minimum product cost for the conversion of syngas to liquid products. The authors have prepared a comparative Zn/Cr spinel oxide support that contains excess ZnO and have looked at the catalytic performance of (a) the bare support, (b) a potassium traverse on the bare support to determine the effect of alkali addition in the absence of Pd and (c) a potassium traverse on the support impregnated with 6 wt% Pd. The bare support is an inefficient methanol catalyst. Alkali addition results in an increase in selectivity to total alcohols vs. the bare support and a dramatic increase higher alcohol synthesis. Pd addition results in further improvements in performance. Selectivities increase with K loading. The 5 wt% K, 5.9 wt% Pd catalyst produces > 100 g/kg-hr of isobutanol at 440 C and 1,000 psi, with 85% selectivity to total alcohols and with a methanol/isobutanol mole ratio of <2. The authors intend to continue formulation screening using K/Pd formulations on ZnO and ZnCr{sub 2}O{sub 4} prepared conventionally and via controlled pH precipitation. They will also examine the effect of Cs in place of K as the alkali promoter and the use of Rh instead of Pd as a promoter.

  16. Bimetallic Catalysts.

    Science.gov (United States)

    Sinfelt, John H.

    1985-01-01

    Chemical reaction rates can be controlled by varying composition of miniscule clusters of metal atoms. These bimetallic catalysts have had major impact on petroleum refining, where work has involved heterogeneous catalysis (reacting molecules in a phase separate from catalyst.) Experimentation involving hydrocarbon reactions, catalytic…

  17. GPHS-RTGs in support of the Cassini mission. Semi annual technical progress report, 2 October 1995--31 March 1996

    International Nuclear Information System (INIS)

    The technical progress achieved during the period 2 October 1995 through 31 March 1996 on Contract No. DE-AC03-91SF18852, Radioisotope Generators and Ancillary Activities is described herein. This report is organized by the program task structure as follows: spacecraft integration and liaison; engineering support; safety; qualified unicouple fabrication; ETG fabrication, assembly, and test; ground support equipment (GSE); RTG shipping and launch support; designs, reviews, and mission applications; project management, quality assurance and reliability, contract changes, non-capital CAGO acquisition, and CAGO maintenance; contract acquired government-owned property (CAGO) acquisition; and program calendars

  18. Design, construction, operation, and evaluation of a prototype culm-combustion boiler/heater unit. Quarterly technical progress report, October 1-December 31, 1980

    Energy Technology Data Exchange (ETDEWEB)

    1981-02-01

    This report provides a summary of the work performed on the Prototype Culm Combustion Boiler/Heater Unit, Phase I - Engineering Design and Analysis and Phase II - Prototype Plant Construction during the period October 1, 1980 through December 31, 1980. The objectives of the program as well as the technical progress and problem areas encountered during the reporting period are presented. The final detail design effort was completed and the final design report submitted. Progress on procurement activity authorized by full Phase II release on March 20, 1980, is discussed. Following approval by DOE, a purchase order was placed with the Norflor Construction Corporation for the prototype plant construction which began in November. Construction of the access roadway installation of the electric power, sewer and water lines was completed during this reporting period. Boiler construction continued.

  19. Bench-scale testing of on-line control of column flotation using a novel analyzer. Second quarterly technical progress report, January 1, 1993--March 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-04-16

    This document contains the second quarterly technical progress report for PTI`s Bench-Scale Testing Project of a circuit integrating PTI`s KEN-FLOTE{trademark} Column Flotation Technology and PTI`s On-Line Quality Monitor and Control System. The twelve-month project involves installation and testing of a 200--300 lb/hr. bench-scale testing circuit at PETC`s Coal Preparation Process Research Facility (CPPRF) for two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). The project schedule timeline by task series for the twelve month project, as it was laid out in the initial Project Work Plan. At the present time, all tasks are progressing according to schedule with the exception of the Task 800 Circuit Testing and Sample Prep and Task 1000 Circuit Decommissioning, which have slipped approximately five weeks due to delays incurred within in the project.

  20. 燃煤电厂SCR催化剂研究进展%Research progress of SCR catalysts for coal-fired power plant

    Institute of Scientific and Technical Information of China (English)

    葛春亮

    2014-01-01

    本文介绍了SCR催化剂的国内外研究情况、特性和关键指标,分析了目前存在的问题和研究方向,最后对催化剂的发展进行了展望。%This paper introduces the research situation at home and abroad, characteristics and the critical index of SCR catalyst, analyzes the problems and research direction at present, and discusses the development of SCR catalyst finally.

  1. Research progress of SCR catalysts for coal-fired power plant%燃煤电厂SCR催化剂研究进展

    Institute of Scientific and Technical Information of China (English)

    葛春亮

    2014-01-01

    本文介绍了SCR催化剂的国内外研究情况、特性和关键指标,分析了目前存在的问题和研究方向,最后对催化剂的发展进行了展望。%This paper introduces the research situation at home and abroad, characteristics and the critical index of SCR catalyst, analyzes the problems and research direction at present, and discusses the development of SCR catalyst finally.

  2. Search for major genes with progeny test data to accelerate the development of genetically superior loblolly pine. Technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-02-15

    This report details the progress of the three tasks of this project. The tasks are: (1) develop genetic models and analytical methods; (2) molecular confirmation of major gene segregation; and (3) develop strategies for marker-assisted breeding.

  3. Plasma physics research on Tokapole II: Technical progress report for the period November 1, 1985-May 31, 1987

    International Nuclear Information System (INIS)

    This progress report covers research performed on the Tokapole II tokamak during FY 1986 and FY 1987 (May 1987). Experiments in the following areas are being investigated: turbulence studies, stability property studies of q/sub a/ < 1, disruption studies at 1 < q/sub a/ < 3, Alfven wave loading and resonance studies, gun refueling, and plasma recycling in a scoop limiter. Progress has been accomplished in upgrading of the machine and data acquisition system, along with modification of the divertor ring supports

  4. OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Constance Senior; Temi Linjewile

    2003-10-31

    This is the third Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-03NT41728. The objective of this program is to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel. The Electric Power Research Institute (EPRI) and Argillon GmbH are providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, the second set of mercury measurements was made after the catalysts had been exposed to flue gas for about 2,000 hours. There was good agreement between the Ontario Hydro measurements and the SCEM measurements. Carbon trap measurements of total mercury agreed fairly well with the SCEM. There did appear to be some loss of mercury in the sampling system toward the end of the sampling campaign. NO{sub x} reductions across the catalysts ranged from 60% to 88%. Loss of total mercury across the commercial catalysts was not observed, as it had been in the March/April test series. It is not clear whether this was due to aging of the catalyst or to changes in the sampling system made between March/April and August. In the presence of ammonia, the blank monolith showed no oxidation. Two of the commercial catalysts showed mercury oxidation that was comparable to that in the March/April series. The other three commercial catalysts showed a decrease in mercury oxidation relative to the March/April series. Oxidation of mercury increased without ammonia present. Transient experiments showed that when ammonia was turned on, mercury appeared to desorb from the catalyst, suggesting displacement of adsorbed mercury by the ammonia.

  5. Technical basis for the ITER-FEAT outline design. Progress in resolving open design issues from the outline design report

    International Nuclear Information System (INIS)

    In this publication the technical basis for the ITER-FEAT outline design is presented. It comprises the Plant Design Specifications, the Safety Principles and Environmental Criteria, the Site Requirements and Site Design Assumptions. The outline of the key features of the ITER-FEAT design includes main physical parameters and assessment, design overview and preliminary safety assessment, cost and schedule

  6. New York City School Survey 2008-2010: Assessing the Reliability and Validity of a Progress Report Measure. Technical Appendices

    Science.gov (United States)

    Nathanson, Lori; Cole, Rachel; Kemple, James J.; Lent, Jessica; McCormick, Meghan; Segeritz, Micha

    2013-01-01

    The Research Alliance for New York City Schools examined Department of Education (DOE) School Survey data from 2008-2010 to better understand the richness and complexities of the information elicited by the Survey from parents, students, and teachers. This document provides the appendices to the technical report "New York City School Survey…

  7. Research progress on the cathode catalysts for Li-air batteries%锂-空气电池正极催化剂研究进展

    Institute of Scientific and Technical Information of China (English)

    李月艳; 王莉; 何向明; 金云学; 李建军

    2014-01-01

    具有超高比能量的锂-空气电池是近年来的研究热点,电解质和空气电极催化剂是锂-空气电池的重要研究内容。介绍了有机体系锂-空气电池空气电极催化剂的研究进展,分析了碳、贵金属、氧化物三类催化剂材料的特征及性能,进而提出了新型、高效、兼具催化氧还原/氧析出功能的纳米催化剂的发展方向。%Lithium-air battery becomes a research hotspot in recent years due to its ultra-high ener-gy density.To develop lithium-air batteries of practical value,plenty of investigation on corre-sponding electrolytes and cathode catalysts have been explored.Air electrode catalysts in lithium-air batteries of aprotic electrolyte architecture are reviewed in this paper.In addition,the charac-teristics and electrochemical performances of carbon material,transition metal oxide catalysts,as well as noble metal based catalysts were introduced,along with a perspective of future research for efficient oxygen reduction/evolution bifunctional cathode nanocatalysts.

  8. Technical Progress in Home-made Low NOx Burners for Cracking Furnace%裂解炉用低NOx燃烧器国内技术进展

    Institute of Scientific and Technical Information of China (English)

    张建; 李金科

    2012-01-01

    综述了裂解炉用低NOx燃烧器的发展方向和技术开发的国内进展情况,介绍了低NOx燃烧器的CFD模拟结合理论研究和冷热态试验的研发手段,这些技术将满足裂解炉对火焰形状、热通量分布、NOx排放和操作稳定性的要求,提升具有自主知识产权低NOx燃烧器的市场竞争力.%Both development direction and technical progress in home-made low NO., burners for cracking furnace were summarized. The technical progress in it can meet cracking furnace ' s requirements for flame shape, heat flux, NO, emission and operational stability and can promote low-NO, burner's competitiveness in the market because of its proprietary intellectual property rights.

  9. A systematic assessment of the state of hazardous waste clean-up technologies. Quarterly technical progress report, April 1--June 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Berg, M.T.; Reed, B.E.; Gabr, M.

    1993-07-01

    West Virginia University (WVU) and the US DOE Morgantown Energy Technology Center (METC) entered into a Cooperative Agreement on August 29, 1992 entitled ``Decontamination Systems Information and Research Programs.`` Stipulated within the Agreement is the requirement that WVU submit to METC a series of Technical Progress Report for Year 1 of the Agreement. This report reflects the progress and/or efforts performed on the following nine technical projects encompassed by the Year 1 Agreement for the period of April 1 through June 30, 1993: Systematic assessment of the state of hazardous waste clean-up technologies; site remediation technologies -- drain-enhanced soil flushing (DESF) for organic contaminants removal; site remediation technologies -- in situ bioremediation of organic contaminants; excavation systems for hazardous waste sites; chemical destruction of polychlorinated biphenyls; development of organic sensors -- monolayer and multilayer self-assembled films for chemical sensors; Winfield lock and dam remediation; Assessments of Technologies for hazardous waste site remediation -- non-treatment technologies and pilot scale test facility implementation; and remediation of hazardous sites with stream reforming.

  10. Technical support services to assist the Office of Environmental Audit in conducting the DOE Environmental Survey and to provide technical assistance on Environmental Compliance issues. Technical progress report, February 16, 1990--August 13, 1990

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    NUS received authorization from DOE on August 14, 1987 to provide technical support services to assist the Office of Environmental Audit (OEV) in conducting the DOE Environmental Survey and to provide technical assistance on environmental compliance issues. The overall contract is to accomplish a one-time, no-fault baseline Survey of all DOE operating facilities, and to provide technical assistance and support for the resolution of environmental compliance issues. NUS has completed the Preliminary Reports and continues to support DOE on the Prioritization and Tiger Team Assessment efforts. The project requires a broad range of environmental protection expertise, necessitating senior-level personnel as the primary project staff. Many of the tasks assigned by DOE require quick startup and performance, and several tasks may be active at any one time.

  11. Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction. Technical progress report, July--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Song, C.; Saini, A.K.; Huang, L.; Schobert, H.H.; Hatcher, P.G.

    1994-01-01

    In this quarter, progress has been made in the following two aspects: (1) spectroscopic and chemical reaction studies on the effects of drying and mild oxidation of a Wyodak subbituminous coal on its structure and pretreatment/liquefaction at 350{degrees}C; and (2) effects of dispersed catalyst and solvent on conversion and structural changes of a North Dakota lignite. Drying and oxidation of Wyodak subbituminous coal at 100-150{degrees}C have been shown to have significant effects on its structure and on its catalytic and non-catalytic low-severity liquefaction at 350{degrees}C for 30 min under 6.9 MPa H{sub 2}. Spectroscopic analyses using solid-state {sup 13}C NMR, Pyrolysis-GC-MS, and FT-IR revealed that oxidative drying at 100-150{degrees}C causes the transformation of phenolics and catechol into other related structures (presumably via condensation) and high-severity air drying at 150{degrees}C for 20 h leads to disappearance of catechol-like structure. Increasing air drying time or temperature increases oxidation to form more oxygen functional groups at the expense of aliphatic carbons. Such a clearly negative impact of severe oxidation is considered to arise from significantly increased oxygen functionality which enhances the cross-link formation in the early stage of coal liquefaction. Physical, chemical, and surface physicochemical aspects of drying and oxidation and the role of water are also discussed. A North Dakota lignite (DECS-1) coal was studied for its behaviors in non-catalytic and catalytic liquefaction. Reactions were carried out at temperatures between 250 and 450{degrees}C. Regardless the reaction solvents and the catalyst being used, the optimum temperature was found to be 400{degrees}C. The donor solvent has a significant effect over the conversion especially at temperatures higher than 350{degrees}C.

  12. Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technical progress report, April 1, 1992--June 30, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Kubiak, C.P.

    1992-11-01

    Aryl carbon-oxygen bond cleavage is a chemical transformation of importance in coal liquefaction and the upgrading of coal liquids as well as in the synthesis of natural products. There have been numerous attempts to discover general methods for the cleavage of aryl carbon-oxygen bonds. All the stoichiometric organic methods for phenol deoxygenation have limited applications and involve expensive reagents. Catalytic method, for the hydrodeoxygenation (HDO) of phenols involve supported transition metal oxides, such as Mo/{gamma}-Al{sub 2}O{sub 3}, Ni-MO/{gamma}-Al{sub 2}O{sub 3}, Co-Mo/{gamma}-Al{sub 2}O{sub 3}, and Fe{sub 2}O{sub 3}/SiO{sub 2}. Typical phenol hydrodeoxygenation conditions involve hydrogen pressures in excess of 100 atm and temperatures in excess of 200{degrees}C. Under these conditions arene ring hydrogenation is generally found to compete with phenol deoxygenation; and the coproduct water is found to impair the activity of the catalysts. This proposed research offers the possibility of effecting the selective catalytic deoxygenation of phenolic functional groups using CO. The deoxygenation of phenols by carbon monoxide mediated by Ir(triphos)OAr has provided us with a catalytic Phenol deoxygenation pathway, through the elimination of CO{sub 2} and formation of a benzyne intermediate. Although the [Pt(triphos)(O-Ph-Me)]PF{sub 6} system is not expected to be as efficient a catalyst as some of the other transition metals systems we are currently exploring, it will provide more information about the deoxygenation mechanism in these triphos complexes. This is due to the presence of the structurally sensitive {sup 3l}P--{sup 195}Pt coupling constant and comparisons to the extensively studied Pt(dppe)(O-Ph){sub 2} systems.

  13. Technical progress, the concept of individualized cancer treatment and the innovation of computer-assisted radiotherapy planning

    International Nuclear Information System (INIS)

    After a first step of cancerogenesis, the further development of the tumor is an individual process. At the end of this process the tumor is formed as an individual in the individual. The individuality of cancer exists on the level of organs, tissues and cells and includes an individual tumor-host relationship. Today, optimized cancer treatment requires a most precise biological characterization possible of the tumor and of the tumor-host relationship, which will provide objective information about the individual character of every tumor. Routine analysis and strict therapeutic consideration of the clinical and biological individuality of human cancer can offer real chances for the improvement of cancer treatment. A routine acquisition of individual tumor characteristics will be possible only if methods and equipment are available for the registration of suitable parameters. In this context technical innovations have an essential influence on the realization of the concept of individualized cancer treatment. With the method of flow cytophotometry and other techniques examples are given in how far the ideas of individual cancer management can be realized by introduction of new technical solutions into medical research and clinical practice. Unfortunately there is still a lack of methodology in individualizing cancer treatment. The individualization of radiotherapy is connected to an extremely high degree of technical innovations. Particularly this refers to the topometrical description of the target volume in relation to the adjacent anatomical structures and the body contour as well as the fitting of isodoses to the shape and size of the target volume. As an example of innovation of a technical solution for individual radiotherapy planning the computer-assisted radiotherapy planning system DOPSY is described. (author)

  14. Silicon ribbon growth by a capillary action shaping technique. Annual report (Quarterly technical progress report No. 9)

    Energy Technology Data Exchange (ETDEWEB)

    Schwuttke, G.H.; Ciszek, T.F.; Kran, A.

    1977-10-01

    Progress on the technological and economical assessment of ribbon growth of silicon by a capillary action shaping technique is reported. Progress in scale-up of the process from 50 mm to 100 mm ribbon widths is presented, the use of vitreous carbon as a crucible material is analyzed, and preliminary tests of CVD Si/sub 3/N/sub 4/ as a potential die material are reported. Diffusion length measurements by SEM, equipment and procedure for defect display under MOS structure in silicon ribbon for lifetime interpretation, and an assessment of ribbon technology are discussed. (WHK)

  15. Photo-oxidation catalysts

    Science.gov (United States)

    Pitts, J. Roland; Liu, Ping; Smith, R. Davis

    2009-07-14

    Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

  16. FRIPP新型石蜡加氢精制催化剂研究进展%Research Progress in New Paraffin Wax Hydrofining Catalyst

    Institute of Scientific and Technical Information of China (English)

    王士新

    2012-01-01

    In Fushun research institute of petroleum and petrochemicals, status quo and development of paraffin wax hydrofining technology as well as study on new hydrofining catalyst were introduced. The process studies show that new spherical catalyst for paraffin wax hydrofining has good activity and stability. Carbonizable substances, polynuclear aromatics and stability of hydrofined products accord with food paraffin national standards.%介绍了FRIPP石蜡加氢技术概况以及新型石蜡加氢精制催化剂研制和工艺研究方面取得的新进展,工艺研究表明,新研制的球形石蜡加氢催化剂具有较好的活性和稳定性,加氢产品的易碳化物、稠环芳烃和安定性指标符合食品石蜡国家标准.

  17. Technical reliability of geological disposal for high-level radioactive wastes in Japan. The second progress report. Part 2. Engineering technology for geological disposal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    Based on the Advisory Committee Report on Nuclear Fuel Cycle Backend Policy submitted to the Japanese Government in 1997, JNC documents the progress of research and development program in the form of the second progress report (the first one published in 1992). It summarizes an evaluation of the technical reliability and safety of the deep geological disposal concept for high-level radioactive wastes (HLW) in Japan. The present document, part 2 of the progress report, concerns engineering aspect with reference to Japanese geological disposal plan, according to which the vitrified HLW will be disposed of into a deep, stable rock mass with thick containers and surrounding buffer materials at the depth of several hundred meters. It discusses on multi-barrier systems consisting of a series of engineered and natural barriers that will isolate radioactive nuclides effectively and retard their migrations to the biosphere environment. Performance of repository components, including specifications of containers for vitrified HLW and their overpacks under design as well as buffer material such as Japanese bentonite to be placed in between are described referring also to such possible problems as corrosion arising from the supposed system. It also presents plans and designs for underground disposal facilities, and the presumed management of the underground facilities. (Ohno, S.)

  18. Technical reliability of geological disposal for high-level radioactive wastes in Japan. The second progress report. Part 3. Safety assessment for geological disposal systems

    International Nuclear Information System (INIS)

    Based on the Advisory Committee Report on Nuclear Fuel Cycle Backend Policy submitted to the Japanese Government in 1997, JNC documents the progress of research and development program in the form of the second progress report (the first one published in 1992). It summarizes an evaluation of the technical reliability and safety of the geological disposal concept for high-level radioactive wastes (HLW) in Japan. The present document, the part 3 of the progress report, concerns safety assessment for geological disposal systems definitely introduced in part 1 and 2 of this series and consists of 9 chapters. Chapter I concerns the methodology for safety assessment while Chapter II deals with diversity and uncertainty about the scenario, the adequate model and the required data of the systems above. Chapter III summarizes the components of the geological disposal system. Chapter IV refers to the relationship between radioactive wastes and human life through groundwater, i.e. nuclide migration. In Chapter V is made a reference case which characterizes the geological environmental data using artificial barrier specifications. (Ohno. S.)

  19. Technical reliability of geological disposal for high-level radioactive wastes in Japan. The second progress report. Part 3. Safety assessment for geological disposal systems

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    Based on the Advisory Committee Report on Nuclear Fuel Cycle Backend Policy submitted to the Japanese Government in 1997, JNC documents the progress of research and development program in the form of the second progress report (the first one published in 1992). It summarizes an evaluation of the technical reliability and safety of the geological disposal concept for high-level radioactive wastes (HLW) in Japan. The present document, the part 3 of the progress report, concerns safety assessment for geological disposal systems definitely introduced in part 1 and 2 of this series and consists of 9 chapters. Chapter I concerns the methodology for safety assessment while Chapter II deals with diversity and uncertainty about the scenario, the adequate model and the required data of the systems above. Chapter III summarizes the components of the geological disposal system. Chapter IV refers to the relationship between radioactive wastes and human life through groundwater, i.e. nuclide migration. In Chapter V is made a reference case which characterizes the geological environmental data using artificial barrier specifications. (Ohno. S.)

  20. 纳米金属催化剂在推进剂中应用进展%Application progress of nanometer-sized metal catalyst in propellants

    Institute of Scientific and Technical Information of China (English)

    康永

    2012-01-01

    Solid propellant is an important research field of military affairs and spaceflight technology. Now solid propellant with high energy and high burning rate is one of the most popular research aspects. Among those methods of improving the burning rate of solid propellant, the nanometer-sized catalyst is considered as one kind of most prospective methods. Nanometer-sized catalyst with catalytic and energetic function can be achieved. The application solid propellant indicates that the decomposition of propellant is accelerated, and the combustion heat is increased distinctively. This paper gives a brief review of research and development in nanometer - sized catalyst, and some problems, synthesis and application of nanometer - sized catalyst are described.%固体推进剂是军事和航天技术的重要研究领域,一直为国内外研究者所重视.目前,高能和高燃速推进剂是最热门的研究方向.在提高固体推进剂燃速的众多方法中,采用纳米催化剂被认为是最有前途的方法之一.纳米催化剂既具有高效的催化作用,又具有很好的能量性能.将该新型催化剂应用到固体火箭推进剂中,发现使推进剂的能量性能和燃烧性能都得到较大提高.回顾纳米催化剂的研究和发展,介绍纳米催化剂若干问题、制备及应用.

  1. 轻质烃芳构化催化剂的研究进展%Research Progress on Catalysts of Light Paraffin Aromatization Technology

    Institute of Scientific and Technical Information of China (English)

    施捷; 平大为; 马晓婧; 史博颖

    2016-01-01

    Instead of petroleum resources, light paraffin aromatization is a mainstream research, and the key is the catalysts. By searching domestic and international patents, the development in catalysts of light paraffin aromatization technology was sorted out in two aspects of development and modification method of the catalyst carrier, choosing the type and SiO2/Al2 O3 molar ratio of molecular sieve, adding metal modification, adjusting the pore size and particle size of molecular sieve, other advanced modifying technologies were summarized.%轻质烃芳构化作为替代石油资源的一项重要研究课题,其中催化剂是该反应的关键技术。本文通过检索国内外的相关专利,从催化剂载体的发展和催化剂载体的改性方法两个方面,对轻质烃芳构化催化剂的研究进展进行了梳理,其中对分子筛型号、分子筛载体硅铝比的选择、负载金属元素改性、分子筛孔径和粒径调整、前沿改性技术等进行了总结。

  2. Association Euratom - Risø National Laboratory for Sustainable Energy, Technical University of Denmark - Annual Progress Report 2008

    DEFF Research Database (Denmark)

    Korsholm, Søren Bang; Michelsen, Poul; Juul Rasmussen, Jens;

    interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. New activities in technology related to development of high temperature superconductors have......The programme of the Research Unit of the Fusion Association Euratom - Risø National Laboratory for Sustainable Energy, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its...

  3. Association Euratom - Risø National Laboratory for Sustainable Energy, Technical University of Denmark - Annual Progress Report 2010

    DEFF Research Database (Denmark)

    Korsholm, Søren Bang; Michelsen, Poul; Juul Rasmussen, Jens;

    interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. Within fusion technology there are activities related to development of high temperature......The programme of the Research Unit of the Fusion Association Euratom - Risø National Laboratory for Sustainable Energy, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its...

  4. Association Euratom - Risø National Laboratory for Sustainable Energy, Technical University of Denmark - Annual Progress Report 2009

    DEFF Research Database (Denmark)

    Korsholm, Søren Bang; Michelsen, Poul; Juul Rasmussen, Jens;

    interaction with the plasma equilibrium and particles. The effort includes both first principles based modelling, and experimental observations of turbulence and of fast ion dynamics by collective Thomson scattering. Within fusion technology there are activities related to development of high temperature......The programme of the Research Unit of the Fusion Association Euratom - Risø National Laboratory for Sustainable Energy, Technical University of Denmark, covers work in fusion plasma physics and in fusion technology. The fusion plasma physics research focuses on turbulence and transport, and its...

  5. Diagnostic development and support of MHD test facilities: Technical progress report for the period January, February, March 1985

    International Nuclear Information System (INIS)

    Mississippi State University is developing diagnostic instruments for MHD power train data acquisition and for support of MHD component development test facilities. Microprocessor-controlled optical instruments, initially developed for HRSR support, are being refined, and new systems to measure temperatures and gas-seed-slag stream characteristics are being developed. To further data acquisition and analysis capabilities, the diagnostic systems are being interfaced with MHD Energy Center computers. Additionally, technical support of the diagnostic needs of the national MHD research effort is being provided

  6. Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technical progress report, April 1, 1991--June 30, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Kubiak, C.P.

    1991-12-31

    The deoxygenation of phenols is a conceptually simple, but unusually difficult chemical transformation to achieve. Aryl carbon-oxygen bond cleavage is a chemical transformation of importance in coal liquefaction and the upgrading of coal liquids as well as in the synthesis of natural products. This proposed research offers the possibility of effecting the selective catalytic deoxygenation of phenolic functional groups using CO. A program of research for the catalytic deoxygenation of phenols, via a low energy mechanistic pathway that is based on the use of the CO/CO{sub 2} couple to remove phenolic oxygen atoms, is underway. We are focusing on systems which have significant promise as catalysts: Ir(triphos)OPh, [Pt(triphos)OPh]{sup +} and Rh(triphos)OPh. Our studies of phenol deoxygenation focus on monitoring the reactions for the elementary processes upon which catalytic activity will depend: CO insertion into M-OPh bonds, CO{sub 2} elimination from aryloxy carbonyls {l_brace}M-C(O)-O-Ph{r_brace}, followed by formation of a coordinated benzyne intermediate.

  7. Technical progress report of biological research on the Volcanic Island Surtsey and its environs for the period 1965--1978

    Energy Technology Data Exchange (ETDEWEB)

    Fridriksson, S.

    1978-01-01

    Progress is reported on the following research projects: changes in shoreline and surface of the island due to volcanic activity; colonization of microorganisms, algae, lichens, and vascular plants; introduction of insects and other arthropods by wind, water, and man; transport of invertebrates to the island by flotsam of the sea; species and nesting habits of birds on the island; behavior of seals on beaches of the island; and future trends of Surtsey ecosystems. (HLW)

  8. Advanced alternate planar geometry solid oxide fuel cells. Interim quarterly technical progress report, November 1, 1988--January 31, 1989

    Energy Technology Data Exchange (ETDEWEB)

    Prouse, D.; Elangovan, S.; Khandkar, A. [Ceramatec, Inc., Salt Lake City, UT (United States); Donelson, R.; Marianowski, L. [Institute of Gas Technology, Chicago, IL (United States)

    1989-12-31

    During this quarter, progress was made at Ceramatec in seal development and conductivity measurements of YIG compositions. A creep test was completed on the porous/dense/porous triilayer. IGT provided a discussion on possible interconnect materials. The following tasks are reported on: cell design analysis, program liaison and test facility preparation, cell component fabrication/development, out-of-cell tests. 9 figs, 2 tabs.

  9. Mercuric iodide research and development in support of DOE Historically Black Colleges and University Program. Semiannual technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    George, M.A.; Zheng, Y.; Salary, L.; Chen, K.T.; Burger, A.

    1994-10-31

    This report describes the progress achieved during the first six months of the program. The different subjects studied were: zone refining experiments of mercuric iodide to establish optimum refining parameters and produce purified material; development of surface reflection spectroscopy as a method to measure crystal surface temperatures, with emphasis on investigation the potential of using optical multichannel analysis; optical methods for measuring iodine vapor during physical vapor transport of HgI{sub 2}; and atomic force microscopy studies.

  10. Research proposal and annual report No. 16. Part B. Technical progress, September 1, 1975--August 31, 1976

    International Nuclear Information System (INIS)

    Progress is reported on the following research projects: RNA synthesis in yeast; regulation of nitrogen metabolism; biological toxicity of intracellular radioisotope decay; the mechanism of energy conversion in chloroplasts; promoting vibrations in spin-orbital coupling in vibrationally deficient molecules; electronic excitation and hydrogen bonding; macromolecular biophysics; the synthesis and maturation of RNA; electronic response properties of biomolecular systems; chromosome structure and function and chromosome damage; DNA replication and chromosome structure; and influence of phospholipids on the dynamic properties of rhodopsin

  11. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

    1995-04-01

    Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

  12. Research progress of olefins asymmetric hydrogenation catalyzed by rhodium catalysts%铑催化剂催化烯烃不对称加氢反应研究进展

    Institute of Scientific and Technical Information of China (English)

    王红琴; 蒋丽红; 王亚明

    2016-01-01

    不对称催化氢化反应具有完美的原子经济性和清洁高效等特点,是最受青睐的不对称合成方法之一。C=C、C=O、C=N 的不对称加氢反应仍主要依赖过渡金属催化剂。过渡金属催化剂,尤其是铑催化剂,催化碳碳双键的不对称加氢反应仍是一个不断发展的领域。本文对近年来利用铑催化剂催化烯烃进行不对称氢化反应的研究进展进行了综述,着重介绍了铑-双膦配体催化体系催化烯烃不对称加氢反应的催化机理,以及铑催化剂在烯胺、不饱和羧酸及衍生物、烯醇酯和非官能团烯烃不对称氢化中的应用,并通过对现有文献的总结指出了今后铑催化剂催化烯烃氢化反应的研究重点,即:①铑-单膦配体催化烯烃不对称氢化反应的作用机理须待提出;②非官能化底物不对称催化氢化反应的手性配体亟待拓宽。%Asymmetric hydrogenation has the advantage of cleanliness,perfect atom economy,and is one of the hottest methods of asymmetric synthesis. The asymmetric hydrogenation in C=C,C=O, C=N are still primarily dependent on the use of transition metal catalysts. The study of transition metal catalysts,especially the asymmetric hydrogenation of carbon-carbon double bond catalyzed by rhodium catalysts is still an evolving field. In the present review,the progress on asymmetric hydrogenation of olefins catalyzed by rhodium catalysts are described,including the catalytic mechanism of rhodium-diphosphine ligand catalyst system,the application of asymmetric hydrogenation of enamines,unsaturated carboxylic acids and their derivatives,enol ester as well as unfunctionalized olefins catalyzed by rhodium catalysts. The development trend of rhodium catalysts for asymmetric hydrogenation of olefins was pointed out. For instance:① the catalytic mechanism of asymmetric hydrogenation of olefins by rhodium-monophosphine ligand needs to be understood;②more chiral ligands for

  13. 焦炉煤气的回收利用技术进展%Technical Progress of Coke Oven Gas Recovery and Utilization

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

      叙述了我国焦炉煤气开展综合利用的迫切性,介绍了其作用于发电、生产甲醇、制氢、生产直接还原铁等技术的进展,分析了焦炉煤气综合利用的广阔前景。%The urgency to comprehensively utilize coke oven gas in China is presented. The technical progress of the coke oven gas used in power generation, production of methanol, production of hydrogen, and production of direct reduced iron is introduced. The broad prospects of comprehensive utilization of coke oven gas are analyzed.

  14. FRIPP加氢裂化催化剂研发新进展%Research Progress in Hydrocracking Catalysts Developed by FRIPP

    Institute of Scientific and Technical Information of China (English)

    杜艳泽; 王凤来; 孙晓艳; 刘昶

    2011-01-01

    To meet the goal of the industrial clean fuels production and products quality upgrading, FRIPP (Fushun research institute of petroleum and petrochemicals, SINOPEC) , actively devoted itself to develop new generation of hydrocracking catalysts. Through the exploitation of new materials and the use of new technologies and methods, FRIPP enhanced the ability to master hydrogenation metal and cognize performance of acidic carrier, then prepared new generation of high performance hydrocracking catalysts with reasonable matching of hydrogenation activity sites and cracking activity sites, such as FC-32,FC-34,FC-46 and FC-50 catalysts.%为满足工业实现清洁生产和产品质量持续升级的要求为目标,FRIPP(中石化抚顺石油化工研究院)积极致力于加氢裂化催化剂的开发,催化剂更新换代速度和技术水平不断提高,针对特定用户,“量体裁衣”地开发加氢裂化催化剂.通过催化新材料开发、新技术和新方法的使用,提高了对加氢金属的掌控能力和对酸性载体性能的认知能力,制备出了加氢活性中心和裂化活性中心匹配更加合理的新一代高性能加氢裂化催化剂FC-32、FC-34、FC-46和FC-50等.

  15. High-temperature liquid-metal technology review. A Bimonthly Technical Progress Review, Volume 7, Number 2, April 1969

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    1969-04-01

    The purpose of the High-Temperature Liquid-Metal Technology Review is to provide up-to-date information on the various research and development programs in the United States in the field of high-temperature liquid-metal technology. The method is to publish reviews prepared by members of the Department of Applied Science of the Brookhaven National Laboratory on current topical and progress reports submitted by contracting organizations. When results and conclusions are reported, it is intended that the individual reviews become both summaries and critiques. Thirteen reviews are presented in this issue.

  16. Indiana University high energy physics group, Task E. Technical progress report, December 1, 1987-June 1, 1988

    International Nuclear Information System (INIS)

    Task E of the Indiana University High Energy Physics Group was established on December 1, 1987. This progress report covers the period December 1, 1987 to June 1, 1988. Work was concentrated on the development of the Large Volume Detector (LVD) at the Gran Sasso Laboratory in Italy. Most effort was devoted to design and experimental tests for the gas recirculating and purification system of the limited streamer tubes used in particle tracking. Some time was also devoted to the valuation of competing designs for the data acquisition system of the limited streamer tubes

  17. Catalyst composition

    Energy Technology Data Exchange (ETDEWEB)

    Onodera, T.; Sakai, T.; Sumitani, K.; Yamasaki, Y.

    1984-11-27

    A catalyst composition comprising a crystalline aluminosilicate selected from the group consisting of zeolite ZSM-5, zeolite ZSM-11, zeolite ZSM-12, zeolite ZSM-35 and zeolite ZSM-38 and having a silica/alumina mole ratio of 20 to 1,000; and at least two metals which are platinum and at least one other metal selected from the group consisting of titanium, chromium, zinc, gallium, germanium, strontium, yttrium, zirconium, molybdenum, palladium, tin, barium, cerium, tungsten, osmium, lead, cadmium, mercury, indium, lanthanum and beryllium. This catalyst composition is useful particularly for the isomerization of aromatic hydrocarbons and reforming of naphtha.

  18. Direct probing of chromatography columns by laser-induced fluorescence. Technical progress report, September 1, 1989--February 28, 1993

    Energy Technology Data Exchange (ETDEWEB)

    McGuffin, V.L.

    1992-12-07

    This report summarizes the progress and accomplishments of this research project from September 1, 1989 to February 28, 1993. During this period, we have accomplished all of the primary scientific objectives of the research proposal: (1) constructed and evaluated a laser-induced fluorescence detection system that allows direct examination of the chromatographic column, (2) examined nonequilibrium processes that occur upon solute injection and elution, (3) examined solute retention in liquid chromatography as a function of temperature and pressure, (4) examined solute zone dispersion in liquid chromatography as a function of temperature and pressure, and (5) developed appropriate theoretical models to describe these phenomena. In each of these studies, substantial knowledge has been gained of the fundamental processes that are responsible for chromatographic separations. In addition to these primary research objectives, we have made significant progress in three related areas: (1) examined pyrene as a fluorescent polarity probe insupercritical fluids and liquids as a function of temperature and pressure, (2) developed methods for the class-selective identification of polynuclear aromatic hydrocarbons in coal-derived fluids by microcolumn liquid chromatography with fluorescence quenching detection, and (3) developed methods for the determination of saturated and unsaturated (including omega-3) fatty acids in fish oil extracts by microcolumn liquid chromatography with laser-induced fluorescence detection. In these studies, the advanced separation and detection techniques developed in our laboratory are applied to practical problems of environmental and biomedical significance.

  19. Committee on Atomic, Molecular, and Optical Sciences (CAMOS). Technical progress report ampersand continuation proposal, February 1, 1993--January 31, 1994

    International Nuclear Information System (INIS)

    The Committee on Atomic, Molecular and Optical Sciences (CAMOS) of the National Research Council (NRC) is charged with monitoring the health of the field of atomic, molecular, and optical (AMO) science in the United States. Accordingly, the Committee identifies and examines both broad and specific issues affecting the field. Regular meetings, teleconferences, briefings from agencies and the scientific community, the formation of study panels to prepare reports, and special symposia are among the mechanisms used by the CAMOS to meet its charge. This progress report presents a review of CAMOS activities from February 1, 1993 to January 31, 1994. The details of prior activities are discussed in earlier progress reports. This report also includes the status of activities associated with the CAMOS study on the field that is being conducted by the Panel on the Future of Atomic, Molecular, and Optical Sciences (FAMOS). During the above period, CAMOS has continued to track and participate in, when requested, discussions on the health of the field. Much of the perspective of CAMOS has been presented in the recently-published report Research Briefing on Selected Opportunities in Atomic, Molecular, and Optical Sciences. That report has served as the basis for briefings to representatives of the federal government as well as the community-at-large. In keeping with its charge to monitor the health of the field, CAMOS launched a study designed to highlight future directions of the field

  20. 国内外加氢裂化预处理催化剂的研究进展%Research Progress in Hydrocracking Pretreatment Catalysts at Home and Abroad

    Institute of Scientific and Technical Information of China (English)

    张宝香; 关明华

    2012-01-01

    With crude oil increasingly becoming heavier and poor-quality as well as quickening step of upgrading cleanfuel, hydrocracking capability is constantly increasing, the hydrocracking pretreatment technology will gain fastdevelopment.In this paper, research progress in hydrocracking pretreatment catalysts at home and abroad wasintroduced.%随着原油的日益重质化和劣质化及清洁燃料升级换代步伐的加快,加氢裂化能力持续增长,加氢裂化预处理技术也将得到快速发展.本文重点介绍了Albemarle公司、CLG公司、Criterion Catalyst公司、Haldor Topsφe公司、Axens公司、FRIPP等国内外大石油公司和科研单位在加氢裂化预处理催化剂方面的研究进展.

  1. ITER technology R and D progress report. Report by the Director. ITER technical advisory committee meeting, 25-27 June 2000, St. Petersburg

    International Nuclear Information System (INIS)

    The overall philosophy for the ITER design has been to use established approaches through detailed analysis and to validate their application to ITER through technology R and D, including fabrication of full scale or scalable models of key components. All this R and D work has been done for ITER under collaboration among the Home Teams, with a total resource of about 660 KIUA. R and D issues for ITER-FEAT are almost the same as for the 1998 ITER design. Major developments and fabrication have been completed and tests have significantly progressed. The technical output from the R and D validates the technologies and confirms the manufacturing techniques and quality assurance incorporated in the ITER design, and supports the manufacturing cost estimates for important key cost drivers. The testing of models is continuing to demonstrate their performance margin and/or to optimize their operational use. Their realisation offers insights useful for a possible future collaborative construction activity. Valuable and relevant experience has already been gained in the management of industrial scale, cross-party ventures. The successful progress of these projects increases confidence in the possibility of jointly constructing ITER in an international project framework. The R and D present status is summarized in the following: details are given in Chapters 2 and 3. Significant efforts and resources have been devoted to the Seven Large R and D Projects which cover all the major key components of the basic machine of ITER and their maintenance tools

  2. Engineering support services for the DOE/GRI coal-gasification research program. Quarterly technical progress report, April-June 1980

    Energy Technology Data Exchange (ETDEWEB)

    Bostwick, L.E.; Brancheau, R.J.; Chen, R.G.

    1980-01-01

    Kellogg activities included continued monitoring of test operations at the Hygas, BI-GAS, Westinghouse, Exxon, Rockwell and Bell plant sites, and of peat gasification laboratory activities. Pilot plant/PDU test runs monitored and reported were: Hygas Tests 85 and 86; BI-GAS Tests G-11C, 11D, 11E, 11F, G-12 and G-12A; Westinghouse test runs TP-023-4, TP-027-1, TP-027-2 and TP-027-3; Exxon test periods 13 through 17; and Rockwell Tests 318-063 through 318-073. Kellogg made significant progress toward completion of the Operating Plan Requirements for the individual developers, and began an evaluation of the Hygas data base. The final report on Westinghouse Risk Analysis were issued. Progress was made in completing the reports of the screening evaluations of Exxon, Rockwell and Westinghouse. The safety assurance study continued, as did normal participation in MPC activities. New task orders for technical/economic studies were submitted for review and approval.

  3. Progress of non-precious metal oxide cathode catalysts microbial fuel cells%微生物燃料电池非贵金属氧化物阴极催化剂研究进展

    Institute of Scientific and Technical Information of China (English)

    邓丽芳; 袁浩然; 陈勇

    2012-01-01

    Microbial fue1 cell(MFC) is a device directly converting chemical energy in the organic matter into electricity with the microbial catalysts,which has been paid much attention because of its advantages of abundant resource,mild reaction condition and high theoretical efficiency.In order to clarify the research direction and development trend of non-precious metal oxide cathode catalysts,the research progress of two main non-precious metal oxide cathode catalysts(manganese dioxide and titanium dioxide) of MFC are summarized.The possible catalytic reaction mechanisms are analyzed also.Then,the application prospects of non-precious metal oxide cathode catalysts about MFC are discussed: 1) Cathode material modification,including replacement of metal oxides,doping,and morphological features change,etc.2) Cathode materials morphology modification: by hydrothermal synthesis,liquid phase deposition,sol gel method,etc.%微生物燃料电池(Microbial Fuel Cell,MFC)是一种利用微生物将底物中的化学能直接转化为电能的理想产电装置,具有产电与废弃物处置双重功效.为探究非贵金属氧化物作为微生物燃料电池阴极催化剂可能的研究方向和发展趋势,主要总结了近几年来两种主要非贵金属氧化物(二氧化锰、二氧化钛)作为微生物燃料电池阴极催化剂的最新研究进展,并分析了其可能的催化反应机制.随后,对其发展方向提出了自己的见解:1)阴极材料改性:包括金属氧化物替换、掺杂、形貌特征改变等;2)阴极材料结构形貌改性:水热合成、液相沉积、溶胶凝胶等方法.

  4. Technical progress report for the Magnetohydrodynamics Coal-Fired Flow Facility: October 1, 1992--December 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    1993-06-01

    Progress is reported on a multitask contract to develop technology for steam bottoming cycle of a Combined Cycle MHD Steam Power Plant. The report describes a 314 hour proof-of-concept (POC) test completed during the quarter. Results include secondary combustion and effect of potassium on the light-off temperature, fouling of heat transfer surfaces, particulate clean-up device performance and advanced diagnostic system performance. Test results on ceramic materials and tubes directed toward the development of a high temperature recuperative air heater are summarized. Results of data analysis of previous tests that are reported include the continuing analysis of tube materials that were exposed to 1500 and 2000 hours of eastern coal fired operation during the previously completed 2000 hour POC test series on eastern, high sulfur coal.

  5. High resolution, low cost solar cell contact development. Quarterly technical progress and schedule report, September 28, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Mardesich, N.

    1980-01-01

    The scope of the contract covers the development and evaluation of forming solar cell collector grid contacts by the MIDFILM process. This is a proprietary process developed by the Ferro Corporation which is a subcontractor for the program. The MIDFILM process attains line resolution characteristics of photoresist methods with processing related to screen printing. The surface to be processed is first coated with a thin layer of photoresist material. Upon exposure to ultraviolet light through a suitable mask, the resist in the non-pattern area cross-links and becomes hard. The unexposed pattern areas remain tacky. The conductor material is applied in the form of a dry mixture of metal and frit particles which adhere to the tacky pattern area. The assemblage is then fired to ash the photopolymer and sinter the fritted conductor powder. Effort was concentrated during this period on the establishment, optimization and identification of problem areas of the MIDFILM process. Progress is reported. (WHK)

  6. Low-rank coal research under the UND/DOE cooperative agreement. Quarterly technical progress report, April 1983-June 1983

    Energy Technology Data Exchange (ETDEWEB)

    Wiltsee, Jr., G. A.

    1983-01-01

    Progress reports are presented for the following tasks: (1) gasification wastewater treatment and reuse; (2) fine coal cleaning; (3) coal-water slurry preparation; (4) low-rank coal liquefaction; (5) combined flue gas cleanup/simultaneous SO/sub x/-NO/sub x/ control; (6) particulate control and hydrocarbons and trace element emissions from low-rank coals; (7) waste characterization; (8) combustion research and ash fowling; (9) fluidized-bed combustion of low-rank coals; (10) ash and slag characterization; (11) organic structure of coal; (12) distribution of inorganics in low-rank coals; (13) physical properties and moisture of low-rank coals; (14) supercritical solvent extraction; and (15) pyrolysis and devolatilization.

  7. Measurements of scattering processes in negative ion: Atom collisions. Technical progress report, 1 September 1991--31 December 1994

    Energy Technology Data Exchange (ETDEWEB)

    Kvale, T.J.

    1994-09-27

    This report describes the progress made on the research objectives during the past three years of the grant. This research project is designed to study various scattering processes which occur in H{sup {minus}} collisions with atomic (specifically, noble gas and atomic hydrogen) targets in the intermediate energy region. These processes include: elastic scattering, single- and double-electron detachment, and target excitation/ionization. For the elastic and target inelastic processes where H{sup {minus}} is scattered intact, the experimental technique of Ion Energy-Loss Spectroscopy (IELS) will be employed to identify the final target state(s). In most of the above processes, cross sections are unknown both experimentally and theoretically. The measurements will provide total cross sections (TCS) initially, and once the angular positioning apparatus is installed, will provide angular differential cross sections (ADCS).

  8. AFCT/TFCT/ISFS Program. Technical progress report for the period January 1, 1978--March 31, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Hill, O.F. (comp.)

    1978-04-01

    This is the ninth in a series of quarterly progress reports on Fuel Cycle Technologies/Thorium Fuel Cycle Technologies/International Spent Fuel Receipt and Storage (AFCT/TFCT/ISFS) program. This program provides information needed by industry to close the back end of the power reactor fuel cycle. Included in the program are activities supporting specific design studies, as well as activities for general fuel cycle technology. Studies were conducted in the following tasks: thorium resource price analyses; investigation of air cleaning processes for removing TBP from off-gas streams; study of iodine chemistry in process solutions; high-level waste treatment; electropolishing to decontaminate metallic waste from alternate and thorium converter fuel cycles; U.S. scale transport, dispersion and removal model comparison; safety criticality experiments; and criticality research in support of thorium fuel cycle technology program. (21 figs., 7 tables) (DLC)

  9. Technical progress and energy substitutions in transport sector; Progres techniques et substitutions energetiques dans le secteur des transports

    Energy Technology Data Exchange (ETDEWEB)

    Florane, Philippe

    2002-11-15

    Alternative motorization technologies have been proposed in order to achieve energy diversification and a reduction in pollutant emissions. Fuel cell vehicles are, among others, at the centre of research carried out by car manufacturers and oil companies. The use of fuel cell vehicles could contribute, first, to a less stringent long-term energy dependence of oil importing countries and, second, to pollutant reduction in the transport sector. First of all, we propose the definition of 'innovation' and its treatment in the frame of mainstream economic theories. Then we proceed to a retrospective analysis of diesel motorization of the car market. In the second part of our work, we conduct a survey among French households aiming to obtain up-to-date information about their degree of acceptance of fuel cell technology. We are concerned about highlighting the determining factors of fuel cell vehicle adoption by consumers. For this, we set up a discrete choice model linking the individual decision to the whole group of technical or socio-economical factors and characteristics. Finally, we develop patterns of fuel cell equipment of passenger cars which differ according to type of vehicle and possible purchase assistance. These patterns lead us to the analysis of long-term fuel cell vehicle development on the French car market. (author)

  10. Bench-scale testing of the micronized magnetite process. Third quarterly technical progress report, January 1995--March 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-04-29

    The major focus of the project, which is scheduled to occur through December 1995, will be to install and test a 500{number_sign}/hr. fine-coal cleaning circuit at DOE`s Process Research Facility (PRF), located at the Pittsburgh Energy Technology Center (PETC). The circuit will utilize an extremely fine, micron-sized magnetite media and small diameter cyclones to make efficient density separations on minus-28-Mesh coal. The overall objectives of the project are to: Determine the effects of operating time on the characteristics of the recirculating medium in a continuous integrated processing circuit, and subsequently, the sensitivity of cyclone separation performance to the quality of the recirculating medium; and determine the technical and economic feasibility of various unit operations and systems in optimizing the separation and recovery of the micronized magnetite from the coal products. This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  11. Coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1995--June 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. This includes new installations and those existing installations that were originally designed for oil or gas firing. The data generated by these projects must be sufficient for private-sector decisions on the feasibility of using coal as the fuel of choice. This work should also provide incentives for the private sector to continue and expand the development, demonstration, and application of these combustion systems. Vortec Corporation`s Coal-Fired Combustion System for Industrial Process Heating Applications is being developed under contract DE-AC22-91PC91161 as part of this DOE development program. The current contract represents the third phase of a three-phase development program. Phase I of the program addressed the technical and economic feasibility of the process, and was initiated in 1987 and completed 1989. Phase II was initiated in 1989 and completed in 1990. During Phase II of the development, design improvements were made to critical components and the test program addressed the performance of the process using several different feedstocks. Phase III of the program was initiated September 1991 and is scheduled for completion in 1994. The Phase III research effort is being focused on the development of a process heater system to be used for producing value-added vitrified glass products from boiler/incinerator ashes and selected industrial wastes.

  12. Molluscs and echinoderms aquaculture: biological aspects, current status, technical progress and future perspectives for the most promising species in Italy

    Directory of Open Access Journals (Sweden)

    Antonio Pais

    2012-10-01

    Full Text Available Shellfish aquaculture is a widespread activity in the Italian peninsula. However, only two bivalve species are mainly cultured along the coastline of that country: the Mediterranean mussel Mytilus galloprovincialis and the Manila clam Venerupis philippinarum (Ruditapes philippinarum. By contrast, just a few other mollusc species of commercial interest are scarcely reared at a small-scale level. After analysing the current status of Italian shellfish production, this paper reports and discusses the potential for culturing several different invertebrate species [i.e., the European flat oyster Ostrea edulis, the grooved carpet shell Venerupis decussata (Ruditapes decussatus, the razor clams Ensis minor and Solen marginatus, the cephalopod Octopus vulgaris, and the purple sea urchin Paracentrotus lividus] in this country. In addition, a detailed overview of the progress made in aquacultural techniques for these species in the Mediterranean basin is presented, highlighting the most relevant bottlenecks and the way forward to shift from the experimental to the aquaculture phase. Finally, an outlook of the main economic and environmental benefits arising from these shellfish culture practices is also given.

  13. Intermediate-energy nuclear physics. Task C. Technical progress report, October 1, 1982-October 1, 1983. Part I

    International Nuclear Information System (INIS)

    Progress is reported on the following experimental studies: (1) excitation of giant resonances in 118Sn in inelastic pion scattering at 130 MeV; (2) giant dipole excitations of 40Ca by inelastic pion scattering; (3) charge symmetry test using the π+ and π- elastic scattering from deuterium at 143 and 256 MeV; (4) binding energy effects on the isospin amplitudes in p-shell nuclei; (5) the energy dependence of the 14C (π+,π0)14N reaction to the IAS; (6) the (3He,t) reaction at 2 GeV; (7) analyzing power in the (polarized p,n) IAS transitions; (8) the excitation of the 1/2+ (2.36) MeV state in the 24Mg (polarized p,d) reaction from 27 to 150 MeV; (9) the energy dependence of the (polarized p,d) reaction for 54Fe and 140Ce; and (10) the energy dependence of the 7Li(p,d)6Li reaction. Publications are listed

  14. Establishment of an Institute for Fusion Studies. Technical progress report, 1 November 1993--31 October 1994

    Energy Technology Data Exchange (ETDEWEB)

    Hazeltine, R.D.

    1994-07-01

    The Institute for Fusion Studies is a national center for theoretical fusion plasma physics research. Its purposes are: (1) to conduct research on theoretical questions concerning the achievement of controlled fusion energy by means of magnetic confinement--including both fundamental problems of long-range significance, as well as shorter-term issues; (2) to serve as a national and international center for information exchange by hosting exchange visits, conferences, and workshops; (3) and to train students and postdoctoral research personnel for the fusion energy program and plasma physics research areas. The theoretical research results obtained by the Institute contribute to the progress of nuclear fusion research, whose goal is the development of fusion power as a basic energy source. Close collaborative relationships have been developed with other university and national laboratory fusion groups, both in the US and abroad. In addition to its primary focus on mainstream fusion physics, the Institute is also involved with research in fusion-sidestream fields, such as advanced computing techniques, nonlinear dynamics, space plasmas and astrophysics, statistical mechanics, fluid dynamics, and accelerator physics. Important research discoveries are briefly described.

  15. Advanced development of particle beam probe diagnostic systems. Technical progress report, June 1, 1982-October 31, 1983

    International Nuclear Information System (INIS)

    The primary objective of this program is the advanced development of sophisticated particle beam diagnostic techniques for making space and time resolved measurements on high temperature magnetically confined plasmas. The procedure is to develop and test new techniques on small-scale laboratory experiments and then transfer the technology to mainline confinement experiments. During the period covered by this progress report the major advances were: (1) demonstrated that beam probing can provide simultaneous measurements of n, phi and T/sub e/ on plasmas when T/sub e/ is less than approximately 500 eV; (2) demonstrated simultaneous measurements of n tilde and phi tilde on tokamak geometry for frequencies below 200 kHz; (3) developed the concept of multi-element energy analyzer to provide simultaneous measurements for more than one spatial location in the plasma; and (4) carried out preliminary analysis that showed that beam probes can be implemented on complex magnetic geometries such as ATF and that beam probe system could be extended into the MeV energy range

  16. Indiana University High Energy Physics Group: Task A: Technical progress report, December 1, 1986 to November 30, 1987

    International Nuclear Information System (INIS)

    Data collection on the production of the KKπ state in π-, K-, and p-bar induced reactions is reported, with partial wave analysis in progress. Work on the design of a target calorimeter and data taking for a muon scattering experiment at CERN is completed. Analysis of a fixed-target jet experiment is reported. A dimuon detector has been prepared for an experiment at Fermilab to study hadronic processes yielding high mass dimuons and associated particles. Participation in the coordination and writing of software for the DO collider detector at Fermilab is reported. Some results from the High Resolution Spectrometer (HRS) are reported, including direct observation of several decay modes of the charmed mesons, directly observed meson resonances, baryon resonances, and some discoveries concerning the tau lepton. Activity is reported in the building of hardware for the muon upgrade for the Mark2 detector at the SLC and the building of the beam position monitors for the SLC, and microprocessors for Mark2 data analysis. Involvement in the SLC polarization collaboration is also reported

  17. Technical Progress Report for PEPCO: Turbo-Z Battery Charging System. Calendar Quarter Ending March 31, 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-04-01

    The project is proceeding at a rapid pace now. The software is in development for the control board and the test stand. Portions of the writing and debugging of this software have been in conjunction with the hardware development. The software now interfaces with all the measurement instruments and displays the measurements on the screen, and it saves the measurements to a disc file. There is still cleanup work to do on the display items. Work must still be imparted to the code to control a charging sequence while taking measurements of the results. The test stand hardware has received a good development effort this quarter. The timer-counter board is working in the computer. This board paces the measurement cycle and times the discharge pulse (whine circuit). The thermocouple multiplexer is scanning at the same time the analog to digital converter is taking measurements. We have made a good number of hardware modifications to solve problems revealed while writing the software. The power factor correction for the charger power section is still in development. The engineers have found additional sources for the PFC chips, and they have obtained more technical data sheets and acquired samples. The control board schematics are complete, and the software is far along in the development phase. The functions of the control board have been detailed. The control board must next be integrated with the power supply unit. The next phase of development will concentrate on integrating the components together. At this time, the final debugging of the hardware and software will begin. Additionally, the capacitive coupler development is proceeding. The annual DARPA/DoT Advanced Transportation review will be held on May 16, 1999. We expect to learn the status of our project proposal during this conference. Should we more forward, UL has agreed to help us determine the design requirements of the complete charging system at their EV testing facility, prior to manufacturing. This

  18. Continuous Fiber Wound Ceramic Composite (CFCC) for Commercial Water Reactor Fuel. Technical progress report for period ending April 1, 2000

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-04-01

    Our program began on August 1, 1999. As of April 1, 2000, the progress has been in materials selection and test planning. Three subcontracts are in place (McDermott Technologies Inc. for continuous fiber reinforced ceramic tubing fabrication, Swales Aerospace for LOCA testing of tubes, and Massachusetts Institute of Technology for In Reactor testing of tubes). With regard to materials selection we visited McDermott Technologies Inc. a number of times, including on February 23, 2000 to discuss the Draft Material Selection and Fabrication Report. The changes discussed at this meeting were implemented and the final version of this report is attached (attachment 1). McDermott Technologies Inc. will produce one type of tubing: Alumina oxide (Nextel 610) fiber, a carbon coating (left in place), and alumina-yttria matrix. A potentially desirable CFCC material of silicon carbide fiber with spinel matrix was discussed. That material selection was not adopted primarily due to material availability and cost. Gamma Engineering is exploring the available tube coatings at Northwestern University as a mechanism for reducing the permeability of the tubes, and thus, will use coating as a differentiating factor in the testing of tubing in the LOCA test as well as the In-Reactor Test. The conclusion of the Material Selection and Fabrication Report lists the possible coatings under evaluation. With regard to Test Planning, the MIT and Swales Aerospace have submitted draft Test Plans. MIT is attempting to accommodate an increased number of test specimens by evaluating alternative test configurations. Swales Aerospace held a design review at their facilities on February 24, 2000 and various engineering alternatives and safety issues were addressed. The final Test Plans are not expected until just before testing begins to allow for incorporation of changes during ''dry runs.''

  19. 微乳液法制备纳米催化剂及其在加氢反应中应用的研究进展%Research Progress in Preparation of Nano-Catalysts by Microemulsion and Their Application to Hydrogenation

    Institute of Scientific and Technical Information of China (English)

    杨思源; 戴伟; 傅吉全; 卫国宾

    2012-01-01

    综述了微乳液法制备纳米粒子、纳米催化剂及其应用方面的研究进展.介绍了超临界微乳液法制备纳米催化剂的特点;重点介绍了微乳液法制备纳米催化剂在不饱和键加氢.芳烃加氢和碳氧化合物加氢反应中的应用,微乳液法制备的纳米催化剂在加氢反应中表现出了较高的催化性能;并提出微乳液法制备纳米催化剂发展的需要解决的问题.%The research progresses in the preparation processes of nanoparticles and nano-catalysts by a microemulsion method, and the application of the nano-catalysts to hydrogenation were reviewed. The preparation of the nano-catalysts by a supercritical microemulsion method was introduced. The applications of the nano-catalysts to the hydrogenations of unsaturated hydrocarbons, aromatics and carbon oxides were discussed in detail. The nano-catalysts showed high catalytic performance in the hydrogenation reactions. The subsistent problems concerning the synthesis of the nano-catalysts were presented.

  20. Catalyst Architecture

    DEFF Research Database (Denmark)

    Kiib, Hans; Marling, Gitte; Hansen, Peter Mandal

    2014-01-01

    How can architecture promote the enriching experiences of the tolerant, the democratic, and the learning city - a city worth living in, worth supporting and worth investing in? Catalyst Architecture comprises architectural projects, which, by virtue of their location, context and their combinatio...... meaningful for everyone. The exhibited works are designed by SANAA, Diller Scofidio + Renfro, James Corner Field Operation, JBMC Arquitetura e Urbanismo, Atelier Bow-Wow, Ateliers Jean Nouvel, COBE, Transform, BIG, Topotek1, Superflex, and by visual artist Jane Maria Petersen....

  1. Non-intrusive measurement of particle charge: Electrostatic dry coal cleaning. Technical progress report No. 8, April 1, 1993--June 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    As we reported in the Technical Progress Report No. 7, there are surges of electric current in the charging loop during triboelectrification of all particles. A high speed data acquisition and analysis system was developed to monitor and record the current pattern. There is no known report on such charge-discharge surges in the literature. The mechanism for it is yet to be understood. The on-line computerized electric current measurement also leads to an observation of charging effects as a function of particle feeding rate. It is shown that feed rate greatly alters particle charge. Such an effect is mostly overlooked by researchers and it could have a important role in process design where the feed rate would be maximized. The initial results for coal and mineral particles demonstrated that the average charge was lower when the feed rate was increased. Further investigation is scheduled to identify potential controlling factors, eg, the solid volume fraction and particle number density could be important process factors. The study of charging velocity and particle size was continued. It was found that particle charge was linearly dependent on the charging velocity for all samples investigated. However, the slope of this linear dependence varied for particles having different diameters. In addition, the charge-velocity relationships were dependent on feeding rates. Hence, the data discussed below include these interrelationships.

  2. Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report No. 2 for reporting period August 1, 1998--November 1, 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-10

    This report summarizes the technical progress achieved during the first quarter of the ERIP project entitled, ``Laser Ultrasonic Furnace Tube Coke Monitor.`` The focus of work during this reporting period was the testing of a novel device for introducing a broad bandwidth ultrasonic pulse at the surface of a simulated furnace tube. The device employs a sacrificial stand-off composed of a fusible alloy that conforms to hot furnace tube surface upon contact. Conventional high-temperature couplants have a maximum operating temperature of about 550{degrees}C, which limits their use for contact against ethylene cracker furnace tube surfaces that typically operate at about 1000{degrees}C. In the absence of a couplant, insufficient ultrasonic energy can be transmitted from the transducer to the tube surface. By using a fusible alloy, the device efficiently couples the transducer to the hot furnace tube surface, even for rough and convex tube surfaces operating at temperatures of 1800{degrees}F and above. Initial tests confirmed the ability to resolve pulse echoes in a simulated furnace tube using a 5 MHz piezoelectric transducer with a fusible stand-off.

  3. Increasing waterflood reserves in the Wilmington oil field through improved reservoir characterization and reservoir management. Quarterly technical progress report, March 21, 1995--June 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, D.; Clarke, D. [Long Beach City Dept. of Oil Properties, CA (United States); Walker, S.; Phillips, C.; Nguyen, J. [Tidelands Oil Production Co. (United States); Moos, D. [Stanford Univ. (United States); Tagbor, K. [MPI (United States)

    1995-07-26

    The main objective of this project is the transfer of technologies, methodologies, and findings developed and applied in this project to other operators of Slope and Basin Clastic Reservoirs. This project will study methods to identify sands with high remaining oil saturation and to recomplete existing wells using advanced completion technology. The identification of the sands with high remaining oil saturation will be accomplished by developing a deterministic 3-D geologic model and by using a state of the art reservoir management computer software. The wells identified by the geologic and reservoir engineering work as having the best potential will be logged with a pulsed acoustic cased-hole logging tool. The application of the logging tools will be optimized in the lab by developing a rock-log model. The wells that are shown to have the best oil production potential will be recompleted. The recompletions will be optimized by evaluating short radius and ultra-short radius lateral recompletions. Technical progress is reported for the following tasks: Reservoir characterization; reservoir engineering; 3-D geologic modeling; pulsed acoustic logging; and technology transfer.

  4. The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report No. 19, April 1, 1996--June 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    The objective of Task I is to prepare and evaluate catalysts and to develop efficient reactor systems for the selective conversion of hydrogen-lean synthesis gas to alcohol fuel extenders and octane enhancers. In Task 1, during this reporting period, we encountered and solved a problem in the analysis of the reaction products containing a small amount of heavy components. Subsequently, we continued with the major thrusts of the program. We analyzed the results from our preliminary studies on the packed-bed membrane reactor using the BASF methanol synthesis catalyst. We developed a quantitative model to describe the performance of the reactor. The effect of varying permeances and the effect of catalyst aging are being incorporated into the model. Secondly, we resumed our more- detailed parametric studies on selected non-sulfide Mo-based catalysts. Finally, we continue with the analysis of data from the kinetic study of a sulfided carbon-supported potassium-doped molybdenum-cobalt catalyst in the Rotoberty reactor. We have completed catalyst screening at UCC. The complete characterization of selected catalysts has been started. In Task 2, the fuel blends of alcohol and unleaded test gas 96 (UTG 96) have been made and tests have been completed. The testing includes knock resistance tests and emissions tests. Emissions tests were conducted when the engine was optimized for the particular blend being tested (i.e. where the engine produced the most power when running on the blend in question). The data shows that the presence of alcohol in the fuel increases the fuel`s ability to resist knock. Because of this, when the engine was optimized for use with alcohol blends, the engine produced more power and lower emission rates.

  5. Progress for Cu-based Small Pore Molecular Sieves as Disel De-NOx Catalysts%铜基小孔分子筛柴油车尾气脱硝催化材料研究进展

    Institute of Scientific and Technical Information of China (English)

    翁端; 王蕾; 吴晓东; 冉锐; 司知蠢

    2013-01-01

    柴油车尾气排放是大气污染物氮氧化物(NOx)的主要来源之一.氨选择性催化还原技术(NH3-SCR)具有高效率、低成本等特征,已成为目前主要的移动源脱硝技术.传统铜基中孔分子筛高温水热稳定较差,而小孔分子筛负载催化材料具有优良的催化活性和水热稳定性,近年受到国内外研究者的广泛关注,成为一种新型NH3-SCR催化材料.综述了铜基小孔分子筛催化材料在柴油车尾气脱硝领域的研究进展.以Cu-SSZ-13和Cu-SAPO-34为例,论述了其突出的低温活性和水热稳定性,总结了Cu含量、Cu物种形态及表面酸性等因素对其催化活性、水热稳定性的影响,归纳其反应活性中心、反应路径等催化机理方面的研究进展.分析表明,该类催化材料是极具发展潜力的NH3-SCR催化材料.其新型催化材料设计、抗中毒机理等还有待进一步深入研究.%NOx is one of the main pollutants in diesel vehicle emissions.Selective catalytic reduction of NOx by ammonia (NH3-SCR) has been extensively studied for the lean NOx control due to its high performance and economic efficiency.Copper based zeolites have been widely used as the De-NOx catalysts and significant research efforts have concentrated on developing different types of zeolites to improve the activity and durability.Recently,SCR catalysts based on small-pore molecular sieves have been reported for NH3-SCR with much improved activities and high thermal durability and have received substantial attention.This review sums up the research progress related with Cu-based small pore molecular sieves,such as Cu-SSZ-13 and Cu-SAPO-34,as diesel De-NOx Catalysts with outstanding low temperature NH3-SCR activity and hydrothermal stability.The nature of the copper species and the surface acidity are the most important factors that affect the NH3-SCR performance.Important results on the active sites and catalytic mechanisms are especially discussed in details

  6. IRIS Final Technical Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    M. D. Carelli

    2003-11-03

    OAK-B135 This NERI project, originally started as the Secure Transportable Autonomous Light Water Reactor (STAR-LW) and currently known as the International Reactor Innovative and Secure (IRIS) project, had the objective of investigating a novel type of water-cooled reactor to satisfy the Generation IV goals: fuel cycle sustainability, enhanced reliability and safety, and improved economics. The research objectives over the three-year (1999-2002) program were as follows: First year: Assess various design alternatives and establish main characteristics of a point design; Second year: Perform feasibility and engineering assessment of the selected design solutions; Third year: Complete reactor design and performance evaluation, including cost assessment These objectives were fully attained and actually they served to launch IRIS as a full fledged project for eventual commercial deployment. The program did not terminate in 2002 at the end of the NERI program, and has just entered in its fifth year. This has been made possible by the IRIS project participants which have grown from the original four member, two-countries team to the current twenty members, nine countries consortium. All the consortium members work under their own funding and it is estimated that the value of their in-kind contributions over the life of the project has been of the order of $30M. Currently, approximately 100 people worldwide are involved in the project. A very important constituency of the IRIS project is the academia: 7 universities from four countries are members of the consortium and five more US universities are associated via parallel NERI programs. To date, 97 students have worked or are working on IRIS; 59 IRIS-related graduate theses have been prepared or are in preparation, and 41 of these students have already graduated with M.S. (33) or Ph.D. (8) degrees. This ''final'' report (final only as far as the NERI program is concerned) summarizes the work performed in the first four years of IRIS, from October 1999 to October 2003. It provides a panoramic of the project status and design effort, with emphasis on the current status, since two previous reports have very extensively documented the work performed, from inception to early 2002.

  7. 1986 PAEC Technical progress report

    International Nuclear Information System (INIS)

    Presented are on-going research and development projects of the Philippine Atomic Energy Commission in the fields of agriculture and natural resources, health and nutrition, supportive research, nuclear applications services, industry and energy, and other scientific and technological services and information system. (ELC)

  8. Progress in the domain of emissions tracking and environment radioactivity monitoring - Proceedings of the technical days organised by the SFRP Environment Section

    International Nuclear Information System (INIS)

    The Environment Section of the French Society of Radiation Protection (SFRP) organized a technical meeting on the progress made in the domain of emissions tracking and environment radioactivity monitoring. This document brings together the abstracts and the presentations (slides) of the different talks given at the meeting: 1 - Environment monitoring at the global, national and local scale: historical overview (Dominique CALMET, CEA); 2 - Evolution of radioactivity monitoring in the environment from 1960 to the present day (Guillaume MANIFICAT, IRSN); 3 - Euratom's legal framework (Zhana GENOVA, CTE); 4 - Main regulatory changes during the last decade (Nathalie REYNAL, ASN); 5 - Progress of standardization works on radioactive effluent emissions control and environment monitoring (Philippe BEGUINEL, BNEN); 6 - From operators' self-monitoring to ASN's inspections: a many components control system (Eric LE COZ, ASN); 7 - Control of effluents and emissions management at CEA Centres (Marianne CALVEZ, CEA); 8 - Liquid and gaseous effluents of ITER experimental facility: description and impacts (Pierre CORTES, IO); 9 - Effluents and emissions management strategy at AREVA NC La Hague facility (Stephane PUYDARRIEUX, AREVA); 10 - Radioactive effluents from nuclear facilities ongoing deconstruction: from dimensioning to real effluents (Benoit CLAVEL, EDF); 11 - Radionuclides decontamination process for liquid effluents using micro-algae at the laboratory scale (Corinne RIVASSEAU, CEA); 12 - Radioactive effluents from nuclear medicine services: management, monitoring and impact measurement methods (Nathalie TCHILIAN, ASN); 13 - Evolution history of effluents management and environment monitoring at the Solvay La Rochelle site (Thierry DELLOYE, SOLVAY); 14 - Different international approaches in effluents management and monitoring: example of French and German gaseous effluents - regulation, analyses, accounting rules (Jean-Jacques DIANA, ASN); 15 - Environment

  9. 资本深化、技术进步与雇佣规模调整%Capital Deepening, Technical Progress and Employment Size Adjustment

    Institute of Scientific and Technical Information of China (English)

    巫强

    2013-01-01

    本文试图解释工资增长趋势下中国上市公司的经营行为,在Cobb-Douglas生产函数的分析框架下,利用2000年至2011年沪深上市公司的数据对相关命题进行了检验,发现在工资增长的趋势下,资本深化总体上呈加尉态势,工资增长越快、劳动分配率越高则资本深化越剧烈,国有企业以资本替代劳动的倾向表现得越来越强烈.就企业的雇佣规模而言,技术进步和工资增长对其有显著的负向影响,营业收入则有显著的正向影响.民企的雇佣规模调整对技术进步越来越敏感,国企的雇佣规模调整对工资增长越来越敏感.本研究的启示包括:首先,未来一段时间的就业压力仍可能较大,但其表现形式由以往的劳动力市场供给带来的压力逐渐转向为劳动力市场需求方的压力.其次,国有企业在资本获取上的优势应该受到限制.再次,在提高劳动分配率的同时要关注资本深化的趋势.%This study aims to explain the employment practices of Chinese listed companies in the trend of wage growth.With the scheme of Cobb-Douglas production function and the data from Guotaian database,several hypotheses are induced and tested.The results show that capital deepening is aggravated in the wage growth trend,and the speed of capital deepening positively correlate to the wage growth rate and labor distribution rate.The state-owned enterprises are more tend to substitute labor with capital.For the employment size,technical progress and wage growth have significant negative effect,while firms' income has significant positive effect.The private enterprises' employment size adjustment are tend to get more sensitive to technical progresses,while the state-owned enterprises' get more sensitive to wage growth.There are several implications of this research:first of all,the employment pressure is still high in the immediate future,while the source of pressure gradually turns to the demand side

  10. The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report No. 5, October 1, 1992--December 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    1993-01-01

    Two base case flow sheets have now been prepared. In the first, which was originally presented in TPR4, a Texaco gasifier is used. Natural gas is also burned in sufficient quantity to increase the hydrogen to carbon monoxide ratio of the synthesis gas to the required value of 1. 1 for alcohol synthesis. Acid gas clean up and sulfur removal are accomplished using the Rectisol process followed by the Claus and Beavon processes. About 10% of the synthesis gas is sent to a power generation unit in order to produce electric power, with the remaining 90% used for alcohol synthesis. For this process, the estimated installed cost is $474.2 mm. The estimated annual operating costs are $64.5 MM. At a price of alcohol fuels in the vicinity of $1. 00/gal, the pay back period for construction of this plant is about four years. The details of this case, called Base Case 1, are presented in Appendix 1. The second base case, called Base Case 2, also has a detailed description and explanation in Appendix 1. In Base Case 2, a Lurgi Gasifier is used. The motivation for using a Lurgi Gasifier is that it runs at a lower temperature and pressure and, therefore, produces by-products such as coal liquids which can be sold. Based upon the economics of joint production, discussed in Technical Progress Report 4, this is a necessity. Since synthesis gas from natural gas is always less expensive to produce than from coal, then alcohol fuels will always be less expensive to produce from natural gas than from coal. Therefore, the only way to make coal- derived alcohol fuels economically competitive is to decrease the cost of production of coal-derived synthesis gas. one method for accomplishing this is to sell the by-products from the gasification step. The details of this strategy are discussed in Appendix 3.

  11. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, October--December 1996

    Energy Technology Data Exchange (ETDEWEB)

    Wehner, S.; Prieditis, J.

    1996-12-31

    The principal objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will be used to determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of energy`s (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate reservoirs. Texaco Exploration and Production Inc`s. (TEPI) mid-term plans are to implement a full-scale miscible CO{sub 2} project in the CVU. TEPI concluded all of the tasks associated with the First Budget Period by October, 1995. The DOE approved the TEPI continuation application. Budget Period No. 2 is in progress. Initial injection of CO{sub 2} began in November, and after a short shut-in period for the soak, the well was returned to production in late December, 1995. This report, covers TEPI`s efforts at history matching the results of the field demonstration. Costs and economics of the work are presented. The majority of effort during the fourth quarter has revolved around the selection of a new project site and refinement of the demonstration design and well selection.

  12. 技术进步对就业人力资本结构的影响%The Impact of Technical Progress on Human Capital Structure of Employment

    Institute of Scientific and Technical Information of China (English)

    黄犚

    2012-01-01

    利用2003-2010年省际面板数据,研究不同类型的技术进步对我国就业人力资本结构的影响.结果表明:总就业与就业结构的调整是矛盾的统一体;自主创新的技术进步对总就业的创造作用大于摧毁作用;外商直接投资和进出口贸易产生的引进技术进步有利于促进我国对外经济体转型升级,增加高人力资本需求;我国对外直接投资作为贸易的补充有利于增加我国总就业,但由于技术获取动力不足,吸收技术溢出的效果不明显,不具有高人力资本偏态效应.同时,该影响也表现出一定程度的区域差异.%Using the provincial panel data from 2003 to 2010, this paper studies the influence of different types of technical progress of the human capital structure of employment in China. The result shows that: total employment and employment structure adjustment are the unity of contradiction; independent innovation benefits job creation; FDI and foreign trade promote the transformation and upgrading of Chinas foreign economy, and thus increase the demand of high human capital; China's technology sourcing OFDI is underpowered; as a supplement to trade, it will be beneficial to increase total employment; but the technology spillover effect is not obvious. Meanwhile, the effect is different in areas.

  13. Thin films of gallium arsenide on low-cost substrates. Quarterly technical progress report No. 8 and topical report No. 3, April 2-July 1, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Ruth, R.P.; Dapkus, P.D.; Dupuis, R.D.; Johnson, R.E.; Manasevit, H.M.; Moudy, L.A.; Yang, J.J.; Yingling, R.D.

    1978-07-01

    The seventh quarter of work on the contract is summarized. The metalorganic chemical vapor deposition (MO-CVD) technique has been applied to the growth of thin films of GaAs and GaAlAs on inexpensive polycrystalline or amorphous substrate materials (primarily glasses and metals) for use in fabrication of large-area low-cost photovoltaic device structures. Trimethylgallium (TMG), arsine (AsH/sub 3/), and trimethylaluminum (TMAl) are mixed in appropriate concentrations at room temperature in the gaseous state and pyrolyzed at the substrate, which is heated in a vertical reactor chamber to temperatures of 725 to 750/sup 0/C, to produce the desired film composition and properties. The technical activities during the quarter were concentrated on (1) a continuing evaluation of various graphite materials as possible substrates for MO-CVD growith of the polycrystalline GaAs solar cells; (2) attempts to improve the quality (especially the grain size) of polycrystalline GaAs films on Mo sheet and Mo/glass substrates by using HCl vapor during the MO-CVD growith process; (3) further studies of the transport properties of polycrystalline GaAs films, wth emphasis on n-type films; (4) continuing investigations of the properties of p-n junctions in polycrystalline GaAs, with emphasis on the formation and properties of p/sup +//n/n/sup +/ deposited structures; and (5) assembling apparatus and establishing a suitable technique for producing TiO/sub 2/ layers for use as AR coatings on GaAs cells. Progress is reported. (WHK)

  14. Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report number 11, January 1--March 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-06-11

    During this quarter, the third draft of the Topical Report on Process Economics Studies was issued for review. A recommendation to continue with design verification testing on the coproduction of methanol and dimethyl ether (DME) was made. A liquid phase dimethyl ether (LPDME) catalyst system with reasonable long-term activity and stability is being developed, and a decision to proceed with a proof-of-concept test run at the LaPorte Alternative Fuels Development Unit (AFDU) is pending the release of a memo from Air Products on the catalyst targets and corresponding economics for a commercially successful LPDME catalyst. The off-site product-use test plan is to be updated in June of 1997. During this quarter, Air Products and Acurex Environmental Corporation continued developing the listing of product-use test participants who are involved in fuel cell, transportation, and stationary power plant applications. Start-up activities (Task 3.1) began during the reporting period, and coal-derived synthesis gas (syngas) was introduced to the demonstration unit. The recycle compressor was tested successfully on syngas at line pressure of 700 psig, and the reactor loop reached 220 C for carbonyl burnout. Iron carbonyl in the balanced gas feed remained below the 10 ppbv detection limit for all samples but one. Within the reactor loop, iron carbonyl levels peaked out near 200 ppbv after about 40 hours on-stream, before decreasing to between 10--20 ppbv at 160 hours on -stream. Nickel carbonyl measurements reached a peak of about 60 ppbv, and decreased at all sampling locations to below the 10 ppbv detection limit by 70 hours on-stream. Catalyst activation of the nine 2,250 lb batches required for the initial catalyst charge began and concluded. All batches met or slightly exceeded the theoretical maximum uptake of 2.82 SCF of reducing gas/lb catalyst.

  15. Research progress in H2O2/solid catalyst carrier for oxidative desulfurization%H2O2/固体催化剂氧化脱硫体系中载体的研究进展

    Institute of Scientific and Technical Information of China (English)

    王广建; 崔会杰; 冯庆吉; 韩亚飞; 王芳

    2015-01-01

    从研究应用角度出发,综述了近年来 H2O2/固体催化剂氧化脱硫体系中载体的研究进展和发展趋势,分别从单一氧化物载体、复合氧化物载体、活性炭载体、分子筛及复合分子筛载体4个方面论述了氧化脱硫催化剂载体各自的优缺点及应用成果。单一氧化物载体重点介绍了 Al2O3、TiO2、SiO2、ZrO2;复合氧化物载体主要对二元复合氧化物进行了综述;重点介绍了以 ZSM-5、SBA-15、MCM-41、HMS 为代表的分子筛及复合分子筛载体。最后将不同类型载体的结构特点、反应优缺点等进行了归纳总结,展望了氧化脱硫催化剂载体未来的研究方向,并提出分子筛及复合分子筛载体将是氧化脱硫催化剂载体研究的焦点。%The article summarizes the research progress and development of carriers in the system of oxidative desulfurization with solid catalyst H2O2. Advantages,disadvantages and application results are discussed from following four aspects:single oxide carrier,mixed oxide carrier,activated carbon carrier,molecular sieve and composite molecular sieve carrier. As single carriers,Al2O3,TiO2,SiO2 and ZrO2 are emphatically introduced; and binary compound oxides are specially introduced in mixed oxide carriers. The molecular sieve and composite molecular sieve carrier represented by ZSM-5, SBA-15,MCM-41 and HMS are also introduced emphatically. Finally,we give an induction and summarization on structural characteristics,advantages and disadvantages in the reaction of different carriers. The research tendency of oxidative desulfurization carrier is prospected,meanwhile,molecular sieve and composite molecular sieve carrier are proposed as the key research focuses of catalyst carriers for oxidative desulfurization in the future.

  16. Research progress of catalysts for copolymerization of CO2 and epoxides%二氧化碳与环氧化合物共聚反应催化剂的研究进展

    Institute of Scientific and Technical Information of China (English)

    秦刚; 范利丹; 曹少魁; 卜站伟; 陈涛; 易奎

    2013-01-01

    Chemical fixation of CO2 is a very attractive subject not only from carbon resource utilization, but also from increasing environmental concerns. In this paper, the significance and methods of CO2 participation in chemical reactions are introduced. Carbon dioxide-based polycarbonates is compared with bisphenol-A polycarbonates, and the emphasis is highly efficient catalyst in copolymerization of CO2 and epoxides to produce aliphatic polycarbonates. Recent progress of the catalysts for copolymerization of CO2 and epoxides is reviewed, and their advantages and disadvantages are discussed. The difficulties in future research are pointed out. The copolymerization product has wide application prospect due to its biodegradability and carbon oxide as raw material.%二氧化碳综合利用对于减轻温室效应和开发有机化工新碳源都具有重要价值.本文简要介绍了二氧化碳化学转化的研究意义,总结了其参与化学反应的主要途径,对比了二氧化碳基聚碳酸酯与双酚A型聚碳酸酯,指出开发催化二氧化碳与环氧化合物共聚反应的高效催化剂是该领域研究的重点.重点综述了二氧化碳与环氧化合物共聚各类催化剂的研究进展,并探讨了其优缺点.分析得出该研究领域进一步发展面临的主要问题是催化剂效率和共聚产物的性能与应用.产品由于具有生物降解性且其原料为储量丰富的二氧化碳,因而具有广阔的应用前景.

  17. Electrochemical catalyst recovery method

    Science.gov (United States)

    Silva, Laura J.; Bray, Lane A.

    1995-01-01

    A method of recovering catalyst material from latent catalyst material solids includes: a) combining latent catalyst material solids with a liquid acid anolyte solution and a redox material which is soluble in the acid anolyte solution to form a mixture; b) electrochemically oxidizing the redox material within the mixture into a dissolved oxidant, the oxidant having a potential for oxidation which is effectively higher than that of the latent catalyst material; c) reacting the oxidant with the latent catalyst material to oxidize the latent catalyst material into at least one oxidized catalyst species which is soluble within the mixture and to reduce the oxidant back into dissolved redox material; and d) recovering catalyst material from the oxidized catalyst species of the mixture. The invention is expected to be particularly useful in recovering spent catalyst material from petroleum hydroprocessing reaction waste products having adhered sulfides, carbon, hydrocarbons, and undesired metals, and as well as in other industrial applications.

  18. Research progress in mercury-free catalysts for the systhesis of vinyl chloride%氯乙烯合成用无汞催化剂研究进展

    Institute of Scientific and Technical Information of China (English)

    王小艳; 李国栋

    2012-01-01

    The research situations of mercury-free catalysts for the systhesis of vinyl chloride at home and abroad were described. The present situations and difficulties in research of non--precious metal mercu- ry-free catalyst, precious metal mercury-free catalyst and liquid mercury-free catalyst were introduced re- spectively. The further development concepts and prospects of mercury-free catalysts were looked forward.%概述了国内外氯乙烯合成用无汞催化剂的研究情况,分别介绍了非贵金属无汞催化剂、贵金属无汞催化剂和液相无汞催化剂的研究现状和难点,并展望了无汞催化剂的后续发展思路及前景。

  19. Humic substances in performance assessment of nuclear waste disposal: Actinide and iodine migration in the far-field. Third technical progress report

    International Nuclear Information System (INIS)

    The present report describes progress within the third and final year of the EC-project 'Humic Substances in Performance Assessment of Nuclear Waste Disposal: Actinide and Iodine Migration in the Far-Field'. The work conducted within the present project builds on a number of previous activities/project supported by the Commission. It finds its continuation within different EC FP 6 instruments and also provides for additional continued cooperation through network structures resulting from the broad cooperation within the project. Without being a formal requirement of the Commission or co-funding bodies, this report documents results in great technical detail and makes the results available to a broad scientific community. The report contains an executive summary written by the coordinator. More detailed results are given as individual contributions in the form of 12 annexes. Not all results are discussed or referred to in the executive summary report and thus readers with a deeper interest also need to consult the annexes. The overall objectives were to generate knowledge about the impact of humic substances on the migration of actinides and iodine in the far-field of a nuclear waste repository. In the beginning, focus was rather on the potential enhancement due to humic colloid mediated radionuclide transport. Thereby, sources, inventory, stability and mobility of dissolved humic substances in their colloidal form formed a key topic. Other key topics were the interaction with actinides and iodine, transport studies under near-natural conditions in the laboratory, rationalization of knowledge in models and application to three migration cases for visualization of the overall outcome. Changes relative to the original objectives were given by moving emphasis of natural chemical analogue studies from the question of kinetic exchange constants for different inventories in natural and laboratory systems to the study of anthropogenic actinide contaminants in the Irish Sea

  20. Research Progress on Catalysts for Copolymerization of CO2 and Epoxides%二氧化碳和环氧化合物共聚催化剂的研究进展

    Institute of Scientific and Technical Information of China (English)

    路学春; 林素静; 刘美蓉; 陈建新; 张治纯

    2016-01-01

    Carbon dioxide is one of the green house gases and is considered as a recyclable, abundant, and non-toxic C1 resource. Its scientific utilization has attracted extensive attention. The synthesis of aliphatic polycarbonate from carbon dioxide and epoxides is one of the most effective routes for chemical utilization of carbon dioxide. The research progress of the catalysts for copolymerization of CO2 and epoxides was reviewed and the catalytic efficiency the performance of copolymer was discussed. The polycarbonate has wide application prospect due to its biodegradability and the reduction of greenhouse gases.%二氧化碳是主要的温室气体之一,也是储量丰富、无毒且可循环利用的碳资源,它的科学利用一直受到人们的广泛关注。二氧化碳与环氧化合物通过环加成反应制备脂肪族聚碳酸酯是二氧化碳化学利用最为有效的途径之一。本文综述了二氧化碳与环氧化合物共聚各类催化剂的研究进展,并讨论了催化剂效率和共聚产物的性能。由于所得聚碳酸酯具有生物降解性且可以控制温室气体含量,因而具有广阔的应用前景。

  1. TECHNICAL COORDINATION

    CERN Multimedia

    A. Ball and W. Zeuner

    2011-01-01

    In this report we will review the main achievements of the Technical Stop and the progress of several centrally-managed projects to support CMS operation and maintenance and prepare the way for upgrades. Overview of the extended Technical Stop  The principal objectives of the extended Technical Stop affecting the detector itself were the installation of the TOTEM T1 telescopes on both ends, the readjustment of the alignment link-disk in YE-2, the replacement of the light-guide sleeves for all PMs of both HFs, and some repairs on TOTEM T2 and CASTOR. The most significant tasks were, however, concentrated on the supporting infrastructure. A detailed line-by-line leak search was performed in the C6F14 cooling system of the Tracker, followed by the installation of variable-frequency drives on the pump motors of the SS1 and SS2 tracker cooling plants to reduce pressure transients during start-up. In the electrical system, larger harmonic filters were installed in ...

  2. (Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending June 30, 1987. [Advanced Coal Research and Technology Development Programs

    Energy Technology Data Exchange (ETDEWEB)

    None

    1988-02-01

    Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)

  3. Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report number 5, July 1--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-31

    The project involves the construction of an 80,000 gallons per day (260 TPD) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} process is ideally suited for directly processing gases produced by modern-day coal gasifiers. Originally tested at a small, DOE-owned experimental unit in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates.

  4. Foundation Flash Catalyst

    CERN Document Server

    Goralski, Greg

    2010-01-01

    This book offers an introduction to Flash Catalyst for designers with intermediate to advanced skills. It discusses where Catalyst sits within the production process and how it communicates with other programs. It covers all of the features of the Flash Catalyst workspace, teaching you how to create designs from scratch, how to build application designs and add functionality, and how to master the Catalyst/Flex workflow. * Introduces Flash Catalyst * Focuses on production process * Covers the interrelation between Flash Catalyst and Photoshop/Illustrator/Flex/Flash What you'll learn Starting f

  5. THE ECONOMICAL PRODUCTION OF ALCOHOL FUELS FROM COAL-DERIVED SYNTHESIS GAS. Includes quarterly technical progress report No.25 from 10/01/1997-12/31/1997, and quarterly technical progress report No.26 from 01/01/1998-03/31/1998; FINAL

    International Nuclear Information System (INIS)

    This project was divided into two parts. One part evaluated possible catalysts for producing higher-alcohols (C(sub 2) to C(sub 5+)) as fuel additives. The other part provided guidance by looking both at the economics of mixed-alcohol production from coal-derived syngas and the effect of higher alcohol addition on gasoline octane and engine performance. The catalysts studied for higher-alcohol synthesis were molybdenum sulfides promoted with potassium. The best catalysts produced alcohols at a rate of 200 g/kg of catalyst/h. Higher-alcohol selectivity was over 40%. The hydrocarbon by-product was less than 20%. These catalysts met established success criteria. The economics for mixed alcohols produced from coal were poor compared to mixed alcohols produced from natural gas. Syngas from natural gas was always less expensive than syngas from coal. Engine tests showed that mixed alcohols added to gasoline significantly improved fuel quality. Mixed-alcohols as produced by our catalysts enhanced gasoline octane and decreased engine emissions. Mixed-alcohol addition gave better results than adding individual alcohols as had been done in the 1980's when some refiners added methanol or ethanol to gasoline

  6. THE ECONOMICAL PRODUCTION OF ALCOHOL FUELS FROM COAL-DERIVED SYNTHESIS GAS. Includes quarterly technical progress report No.25 from 10/01/1997-12/31/1997, and quarterly technical progress report No.26 from 01/01/1998-03/31/1998

    Energy Technology Data Exchange (ETDEWEB)

    None

    1999-03-01

    This project was divided into two parts. One part evaluated possible catalysts for producing higher-alcohols (C{sub 2} to C{sub 5+}) as fuel additives. The other part provided guidance by looking both at the economics of mixed-alcohol production from coal-derived syngas and the effect of higher alcohol addition on gasoline octane and engine performance. The catalysts studied for higher-alcohol synthesis were molybdenum sulfides promoted with potassium. The best catalysts produced alcohols at a rate of 200 g/kg of catalyst/h. Higher-alcohol selectivity was over 40%. The hydrocarbon by-product was less than 20%. These catalysts met established success criteria. The economics for mixed alcohols produced from coal were poor compared to mixed alcohols produced from natural gas. Syngas from natural gas was always less expensive than syngas from coal. Engine tests showed that mixed alcohols added to gasoline significantly improved fuel quality. Mixed-alcohols as produced by our catalysts enhanced gasoline octane and decreased engine emissions. Mixed-alcohol addition gave better results than adding individual alcohols as had been done in the 1980's when some refiners added methanol or ethanol to gasoline.

  7. PROGRESS IN CATALYST AND PROCESS DEVELOPMENT FOR LOW SULFUR AND LOW AROMATICS DIESEL PRODUCTION%低硫低芳烃柴油生产技术开发进展

    Institute of Scientific and Technical Information of China (English)

    周勇; 韩崇仁

    2003-01-01

    The article includes three parts: ①The development and performance of FH-DS catalyst for deep and ultra-deep distillate HDS; ②The single stage HDS/HDA hydrotreating process for the production of low sulfur and low aromatics diesels from straight run and coker AGO by using highly active base metal catalyst at moderate pressure; ③A two-stage aromatics saturation system utilizing noble metal catalyst in the second stage developed for production of low sulfur and low aromatics diesel from LCO. FDA catalyst developed by FRIPP has high activity for aromatics saturation together with high tolerance for sulfur and nitrogen in the feed. The process is effective in reducing density and increasing cetane number.

  8. OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Constance Senior; Temi Linjewile

    2003-07-25

    This is the first Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-03NT41728. The objective of this program is to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel. The Electric Power Research Institute (EPRI) and Ceramics GmbH are providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, analysis of the coal, ash and mercury speciation data from the first test series was completed. Good agreement was shown between different methods of measuring mercury in the flue gas: Ontario Hydro, semi-continuous emission monitor (SCEM) and coal composition. There was a loss of total mercury across the commercial catalysts, but not across the blank monolith. The blank monolith showed no oxidation. The data from the first test series show the same trend in mercury oxidation as a function of space velocity that has been seen elsewhere. At space velocities in the range of 6,000-7,000 hr{sup -1} the blank monolith did not show any mercury oxidation, with or without ammonia present. Two of the commercial catalysts clearly showed an effect of ammonia. Two other commercial catalysts showed an effect of ammonia, although the error bars for the no-ammonia case are large. A test plan was written for the second test series and is being reviewed.

  9. Pd Close Coupled Catalyst

    Institute of Scientific and Technical Information of China (English)

    Zhong Hua SHI; Mao Chu GONG; Yao Qiang CHEN

    2006-01-01

    A catalyst comprised novel high surface area alumina support was prepared to control emission of automobiles. The results showed that prepared catalyst could satisfy the requirements of a high performance close coupled catalyst for its good catalytic activity at low temperature and good stability at high temperature.

  10. Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report No. 1, October 1, 1993--June 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-31

    The Liquid Phase Methanol (LPMEOH{trademark}) Demonstration Project at Kingsport, Tennessee is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products and Chemicals, Inc. (Air Products). This document describes major accomplishments in project development for Fiscal Year 1993. The preliminary process hazards review, project safety plan, schedule, and cost management report are included as appendices. The demonstration is sited at the Eastman Chemical Company (Eastman) complex in Kingsport. Air Products and Eastman are working on a partnership agreement which will form the Air Products Liquid Phase Conversion Company, L.P. As a limited partner in the venture, Eastman will own and operate the demonstration unit. The project involves the construction of a 260 tons-per-day (TPD) or 80,000 gallon per day methanol demonstration unit utilizing an existing coal-derived synthesis gas from Eastman. The new equipment consists of synthesis gas feed preparation and compression, liquid phase reactor and auxiliaries, product distillation, and utilities. The technology to be demonstrated was developed by Air Products in a DOE sponsored program that started in 1981. Originally tested at a small, DOE-owned experimental facility in LaPorte, Texas, the LPMEOH{trademark} process offers several advantages over current methods of making methanol. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The liquid dissipates heat from the chemical reaction away from the catalyst surface, protecting the catalyst, and allowing the gas-to-methanol reaction to proceed at higher rates. The process is ideally suited to the type of gas produced by modem coal gasifiers. At the Eastman Chemical complex, the technology will be integrated with existing coal gasifiers to demonstrate the commercially important aspects of the operation of the LPMEOH{trademark} Process to produce methanol.

  11. Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report number 6, October 1--December 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    The project involves the construction of an 80,000 gallons per day (260 TPD) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} process is ideally suited for directly processing gases produced by modern-day coal gasifiers. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology will be integrated with existing coal-gasifiers. A carefully developed test plan will allow operations at Eastman to simulate electricity demand load-following in coal-based IGCC facilities. The operations will also demonstrate the enhanced stability and heat dissipation of the conversion process, its reliable on/off operation, and its ability to produce methanol as a clean liquid fuel without additional upgrading. An off-site product testing program will be conducted to demonstrate the suitability of the methanol product as a transportation fuel and as a fuel for stationary applications for small modular electric power generators for distributed power.

  12. Novel approaches to the production of higher alcohols from synthesis gas. Quarterly technical progress report No. 20, July 1, 1995--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, G.W.

    1996-09-05

    Standard thermal stability tests were carried out on four liquids: decahydroquinoline (DHQ); 1, 3-Di-4 piperidylpropane (134PPDP), Naphthenic Base 37 and tetrahydronaphthalene (tetralin). Tetralin was more stable than decahydronaphthalene (Decalin{reg_sign}), and THQ was slightly less stable. Both tetralin and THQ should be evaluated further as slurry liquids in the presence of catalyst and syngas. Naphthenic Base 37 and 134PPDP do not have satisfactory thermal stability. Vapor pressure osmometry (VPO) was shown to be an unreliable technique for measuring the average molecular weight of slurry liquids. Gas chromatography/mass spectroscopy (GUMS) is a more accurate technique for pure compounds.

  13. 甲乙酮生产工艺进展及国内外生产状况分析%Technical progress and production status of analysis on methyl ethyl ketone

    Institute of Scientific and Technical Information of China (English)

    徐沛; 米杰; 程可可; 张建安

    2012-01-01

    综述了目前国内外甲乙酮生产的合成方法及其工艺进展,分析了国内外甲乙酮市场的生产消费状况,提出了甲乙酮相关的应用展望及建议。%In this paper, the technical progress and synthesis methods of methyl ethyl ketone at home and abroad as well as their applications were introduced. The domestic and foreign production status of methyl ethyl ketone were analyzed. In addition, the prospects and reasonable suggestions on development of MEK in china were presented.

  14. The training process of rhythmic gymnastics elements (technics of throws and catching of a boll at PE lessons in secondary school, as one of the progress means of dexterity and flexibility at younger students.

    Directory of Open Access Journals (Sweden)

    Andreeva N.O.

    2011-04-01

    Full Text Available The existing systems of physical training of younger pupils at school requires the perfection of its forms and methods. One of such innovations maybe the use of procedures of sports training in educational process, in particular - rhythmic gymnastics. The article deals with the initial theoretical position of expedient usage of teaching methods of throws and catching technics of a boll in educational process of students as one of the basic means of progress of such motion qualities as dexterity and flexibility.

  15. Recent Technological Developments in Cobalt Catalysts for Fischer-Tropsch Synthesis

    Institute of Scientific and Technical Information of China (English)

    Junling Zhang; Jiangang Chen; Yongwang Li; Yuhan Sun

    2002-01-01

    Co-based catalysts are often utilized due to their high Fischer-Tropsch synthesis (FT) activity,C+5 hydrocarbon selectivity, low water-gas shift reaction (WGS) activity and relatively low cost. Selective control of C5+ hydrocarbons and the catalyst longevity are critical in the design of cobalt catalysts.Thus, various methods to improve the performance of Co catalysts have been suggested. The progress in cobalt catalysts reviewed in the last few decades, mainly involved the support, promoter, preparation and deactivation of Co-based catalysts.

  16. Research advances in the catalysts for the selective oxidation of ethane to aldehydes

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zhe; ZHAO Zhen; XU Chunming

    2005-01-01

    Selective oxidation of ethane to aldehydes is one of the most difficult processes in the catalysis researches of low alkanes. The development of selective oxidation of ethane to aldehydes (formaldehyde, acetaldehyde and acrolein) is discussed. The latest progress of the catalysts, including bulk or supported metal oxide catalysts, highly dispersed and isolated active sites catalysts, and the photo-catalytic ethane oxidation catalysts, partial oxidation of ethane in the gas phase, and the proposed reaction pathways from ethane to aldehydes are involved.

  17. The development of coal-based technologies for Department of Defense facilities. Volume 2, Appendices. Semiannual technical progress report, September 28, 1994--March 27, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Miller, B.G.; Bartley, D.A.; Hatcher, P. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center] [and others

    1996-10-15

    This semiannual progress report contains the following appendices: description of the 1,000 lb steam/h watertube research boiler; the Pennsylvania CGE model; Phase II, subtask 3.9 coal market analysis; the CGE model; and sector definition.

  18. The development of coal-based technologies for Department of Defense facilities. Volume 2, Appendices. Semiannual technical progress report, September 28, 1994--March 27, 1995

    International Nuclear Information System (INIS)

    This semiannual progress report contains the following appendices: description of the 1,000 lb steam/h watertube research boiler; the Pennsylvania CGE model; Phase II, subtask 3.9 coal market analysis; the CGE model; and sector definition

  19. Investigations of nuclear structure and nuclear reactions induced by complex projectiles. Technical progress report, November 1, 1978-October 31, 1979. [Summaries of research activities at Washington Univ

    Energy Technology Data Exchange (ETDEWEB)

    Sarantites, D.G.

    1979-01-01

    Experimental research on nuclear structure and reactions both published and in progress is summarized. Included are fusion reactions, strongly damped heavy ion collisions, and nuclear structure at high angular momentum. A list of publications is included. (JFP)

  20. SCIENCE AND TECHNOLOGY POLICIES, INDUSTRIAL REFORM AND TECHNICAL PROGRESS IN CHINA. CAN SOCIALIST PROPERTY RIGHTS BE COMPATIBLE WITH TECHNOLOGICAL CATCHING UP?

    OpenAIRE

    Gabriele, Alberto

    2001-01-01

    This paper analyses the quest for technological progress in China, a large, semi-industrialized, socialist developing country. In the introduction, it is argued that international income convergence is not an automatic product of market forces. Therefore, the path of technological progress in a less advanced country is dependent on its bsorptive capacity, which can be enhanced by the development of an effective national innovation system. The specific meaning attached to key terms such as tec...

  1. TECHNICAL COORDINATION

    CERN Multimedia

    Austin Ball

    Summary of progress since last CMS week. Ten years of construction work have been completed. CMS is closed, in very close to the ideal low luminosity configuration, and performed well in the first tests with LHC beam. Behind this encouraging news is the story of a summer of intense commitment by many teams (from the collaboration and 3 CERN departments) working together, against the clock and despite many minor setbacks, to ensure that the experiment was ready to play a leading role in the excitement of September 10. Following beampipe bakeout and refill with pure neon, a magnificent effort by the ECAL group and the pt 5 technical crew made it possible to install and commission all 4 ECAL endcap Dees before the end of August. In the shadow of this activity, the barrel and forward pixel trackers and part of the beam monitoring were installed within the vac tank. The pt 5 technical teams then succeeded in safely removing the 20t installation tables and their support blocks from beneath the already installed ...

  2. Federal Assistance Program Quarterly Project Progress Report. Geothermal Energy Program: Information Dissemination, Public Outreach, and Technical Analysis Activities. Reporting Period: January 1 - March 31, 2001 [Final report

    Energy Technology Data Exchange (ETDEWEB)

    Lund, John W.

    2002-03-22

    The final report of the accomplishments of the geothermal energy program: information dissemination, public outreach and technical analysis activities by the project team consisting of the Geo-Heat Center, Geothermal Resources Council, Geothermal Education Office, Geothermal Energy Association and the Washington State University Energy Program.

  3. Increased oil production and reserves utilizing secondary/tertiary recovery techniques on small reservoirs in the Paradox Basin, Utah. Technical progress report, January 1--March 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Allison, M.L.

    1996-04-30

    The primary objective of this project is to enhance domestic petroleum production by demonstration and technology transfer of an advanced oil recovery technology in the Paradox basin, southeastern Utah. If this project can demonstrate technical and economic feasibility, the technique can be applied to approximately 100 additional small fields in the Paradox basin alone, and result in increased recovery of 150 to 200 million barrels of oil. This project is designed to characterize five shallow-shelf carbonate reservoirs in the Pennsylvanian (Desmoinesian) Paradox Formation and choose the best candidate for a pilot demonstration project for either a waterflood or carbon dioxide-(CO{sub 2}-)flood project. The field demonstration, monitoring of field performance, and associated validation activities will take place in the Paradox basin within the Navajo Nation. The results of this project will be transferred to industry and other researchers through a petroleum extension service, creation of digital databases for distribution, technical workshops and seminars, field trips, technical presentations at national and regional professional meetings, and publication in newsletters and various technical or trade journals.

  4. Progress report for '89

    International Nuclear Information System (INIS)

    The 1989 Progress Report presents the most important scientific and technical achievements of the Nuclear Research Institute's research work. Some specialized products prepared at or fabricated by the NRI are mentioned as well. (author). 24 figs., 8 tabs., 101 refs

  5. Cooperative Research Program in coal liquefaction. Technical report, May 1, 1994--October 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-12-31

    Progress reports are presented for the following tasks: coliquefaction of coal with waste materials; catalysts for coal liquefaction to clean transportation fuels; fundamental research in coal liquefaction; and in situ analytical techniques for coal liquefaction and coal liquefaction catalysts.

  6. TECHNICAL COORDINATION

    CERN Multimedia

    Austin Ball

    2013-01-01

      Since the last report, much visible progress has been made, as the LS1 programme approaches the halfway point. From early October, technical and safety shift-crew have been present around the clock, allowing detectors to stay switched on overnight, ensuring that safety systems are operational and instructions for non-expert shift-crew are clear. LS1 progress Throughout the summer, whilst the solenoid vacuum tank and YB0 surfaces were accessible, an extensive installation programme took place to prepare for Tracker colder operation and the PLT installation, in 2014, the Phase 1 Pixel Tracker installation, in 2016–’17, and the HCAL Phase 1 upgrade completion, ending in LS2. This included pipework for N2 or dry air to flush the Tracker bulkhead region, many sensors to monitor temperature and dew point in the Tracker and its service channels, heating wires outside the Tracker cooling bundles, supports for the new vacuum-jacketed, concentric, CO2 Pixel cooling lines, the PLT cool...

  7. Computational Modeling and Experimental Studies on NO(x) Reduction Under Pulveerized Coal Combustion Conditions. Quarterly technical progress report, July 1 - September 30, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Kumpaty, S.K.; Subramanian, K.; Darboe, A.; Kumpati, S.K.

    1997-12-31

    Several experiments were conducted during this quarter to study the NO{sub x} reduction effectiveness of lignite coal, activated carbon and catalytic sites such as calcium sulfide and calcium carbide. While some of the coals/chemicals could be fed easily, some needed the mixing with silica gel to result in a uniform flow through the feeder. Several trial runs were performed to ensure proper feeding of the material before conducting the actual experiment to record NO{sub x} reduction. The experimental approach has been the same as presented in the past two quarterly reports with the coal reburning experiments. Partial reduction is achieved through methane addition for SR2=0.95 conditions and then coal or the catalyst is introduced to see if there is further reduction. Presented below are the results of the experiments conducted during this quarter.

  8. Mobile phase in coals: its nature and modes of release. Technical progress report, September-November 1985 and December 1985-February 1986

    Energy Technology Data Exchange (ETDEWEB)

    Derbyshire, F.J.

    1986-04-01

    Studies have been continued in probing the molecular phase-network concept of coal structure through the catalytic hydrogenation of coals in the absence of solvent. Experiments have now been conducted using a Spanish lignite and a sample of Illinois No. 6, in addition to three coals examined previously. Earlier findings, that low-rank coals are more reactive than bituminous coals at 350/sup 0/C, have been confirmed. In an attempt to minimize the loss of volatile liquids during product work-up, the temperature used for solvent stripping was lowered from 110/sup 0/C to 50/sup 0/C. This expedient has not proved to be satisfactory as it results in excessive retention of solvent in the products. Two series of coal samples have been prepared by the catalytic hydrogenation of a bituminous and a subbituminous coal, for different times at 400 C and will be examined by Dr. Lynch (CSIRO, Australia) using /sup 1/H NMR. The principal aim of the study is to investigate the change in coal molecular phase content, as determined by pulsed /sup 1/H free induction decay, which is brought about by partial liquefaction. To address the question of whether the molecular phase plays an important role in the early stages of dry catalytic hydrogenation, a number of experiments were performed on coals which had first been extracted in chloroform. The removal of the chloroform-soluble liquids appeared to have little effect upon the initial rate of liquefaction. It is suggested that the MoS/sub 2/ catalyst may be mobile within the coal structure at the reaction temperatures used, which could explain the effectiveness of this catalyst at short reaction times. A preparative scale, high performance liquid chromatography system has been assembled to allow the separation of liquefaction products into different compound classes. The separated fraction will be examined in detail by GC-MS. 7 refs., 2 figs., 16 tabs.

  9. 单中心催化剂聚烯烃材料的研究进展%Progress in the Research of Polyolefin Materials with Single-Site Catalysts

    Institute of Scientific and Technical Information of China (English)

    王伟

    2013-01-01

    The researches of single-site catalysts, namely metallocene catalysts, non-metallocene catalysts and late transition metal catalysts, for olefin polymerization were reviewed. The synthesis of some special polyolefins by non-coordination polymerization (e.g. ring-opening metathesis polymerization) was also involved. Some commercially available polyolefin materials based on these kinds of catalysts were focused on. The types, structures and applications of the polyolefin resins were summarized. And the uncommercialized functional polyolefins which had strong potential market value were also discussed. The development trends of polyolefins based on the single-site catalysts were proposed.%综述了茂金属催化剂、非茂金属催化剂和后过渡金属催化剂等单中心催化体系的研究进展,同时介绍了一些使用非配位聚合方法(如开环易位聚合)合成特殊结构聚烯烃的研究.着重介绍了基于这类催化剂的聚烯烃材料工业生产的情况,总结归纳了各公司生产的单中心催化剂聚烯烃产品并阐述了它们的结构和用途,对具有强大潜在市场而未工业化的产品(如功能化聚烯烃)进行了论述. 对我国单中心催化剂和聚烯烃材料未来的发展提出了展望.单中心催化剂的研究与开发将促进聚烯烃产品的差异化和升级换代.

  10. Research and development of methods/utilities and rules for managing cooperation for performance improvement in government offices. Second Technical progress report, September 1, 1992--January 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Kurstedt, H.A.

    1993-03-01

    Purpose is to help managers approach their responsibilities proactively, so that they can anticipate problems and take actions to alleviate or eliminate those problems. Continuous performance improvement, the philosophy behind total quality management, requires working cooperatively to do a little better each day. The most effective tools are working through a closed set of 9 methods: setting expectations, charting, defining indicators and standards, collecting and logging data, converting data to information, organizing and presenting information, reviewing status and progress, self-management, and appraising. In addition, there are 8 rules: focus on what you can do, supply physical evidence of progress, pay attention to detail, inspect (don`t expect), review progress routinely and frequently, face ``success/fail`` squarely, communicate crisply, and conduct honest, open appraisals. Scope and plans of the draft research plan (study areas) are described.

  11. Materials Compatibility and Lubricants Research of CFC-refrigerant substitutes. Quarterly technical progress report, 1 April 1993--30 June 1993

    Energy Technology Data Exchange (ETDEWEB)

    Godwin, D.S.; Hourahan, G.C.; Szymurski, S.R.

    1993-07-01

    The Materials Compatibility and Lubricants Research (MCLR) program supports critical research to accelerate the introduction of CFC and HCFC refrigerant substitutes. The DCLR program addresses refrigerant and lubricant properties and materials compatibility. The primary elements of the work include data collection and dissemination, materials compatibility testing, and methods development. The work is guided by an Advisory Committee consisting of technical experts from the refrigeration and air-conditioning industry and government agencies. Under the current MCLR program the Air-Conditioning and Refrigeration Technology Institute, Inc., (ARTI) is contracting and managing multiple research projects and a data collection and dissemination effort. Detailed results from these projects are reported in technical reports prepared by each researcher.

  12. 碳四馏分制低碳烯烃技术进展%Technical Progress of Olefins Production from C4 Fraction

    Institute of Scientific and Technical Information of China (English)

    张永军; 刘剑; 汲永钢; 孙淑坤; 万书宝; 明利鹏

    2011-01-01

    To present technical process of olefins production from C4 fraction, e.g. olefin disproportionation, olefin cracking, isobutene dehydrogenation, C4 hydrogenation feedstock for cracking, etc. which are effective ways to ease C4 excess. To discuss the technical economy of industrial application of new technologies. To predict that olefin cracking process in olefin plant will have good return on investment.%提出烯烃歧化、烯烃裂解、异丁烷脱氢和C4加氢作裂解原料等C4制取低碳烯烃技术,是解决C4资源过剩的有效手段。讨论了新技术工业应用的技术经济,预测烯烃裂解与烯烃厂结合将有很好的投资回报。

  13. Progress in resolving open design issues from the ODR. Report by the Director. ITER technical advisory committee meeting, 25-27 June 2000, St. Petersburg

    International Nuclear Information System (INIS)

    This report presents progress in resolving open design issues from the ITER-FEAT Outline Design Report and is not repeating the ODR information but concentrates on the specific issues and the progress towards their resolution. It includes some aspects of the Physics analysis (inductive operation scenario and sensitivity analysis, ion heating, possibility of high Q and ignition operation, divertor physics), Magnets (TF coil loads, inductive flux generation, conductor design issues), Vessel/in Vessel (manifolding of blanket coolant, vacuum vessel design development, design implications of divertor material choice), Buildings and Plant services, Operation and Safety

  14. Technical analysis of failure of catalyst support of reformer furnace tube of a hydrogen generation unit%制氢装置转化炉炉管催化剂支托失效分析

    Institute of Scientific and Technical Information of China (English)

    齐庆轩; 冯岩

    2012-01-01

    The damages of catalyst support of reformer furnace tubes of No. 1 hydrogen generation unit in SINOPEC Shijiazhuang Refining & Chemical Co. , Ltd. in two maintenances were introduced. The composition analysis of catalyst support, the study on the macroscopic photo, the analysis of damaged surface of catalyst support of Incoloy800H, the metallographic analysis, energy dispersion spectrum (EDS) analysis, and scanning electron microscope analysis of support' s section area as well as study on the anti-caburization performances of Cr25Ni20 and Incoloy800H materials have concluded the following: The damages of catalyst support was caused by surface carburization of catalyst support material under high temperature in the presence of hydrogen, which led to phase changes of material surface structure, material stratification, loosening and bulging of surface material structure, large amount of micro-crackings in grain boundary at surface area and eduction of large amount of carbides. All these will reduce the ductility and plasticity of material. Therefore, it is difficult for the catalyst support to restore its original state after thermal expansion, which explains why there are some bulges on the tube of failed support. The anti-carburization performance is greatly improved after application of Cr25Ni20 steel material.%对两次检修中所发现的中国石油化工股份有限公司石家庄炼化分公司l号制氢装置转化炉炉管催化剂支托出现损坏的情况做了介绍,并对两种批次的催化剂支托进行了成分分析,对使用Incoloy800H材料、损坏严重的催化剂支托表面宏观照片进行了分析,对损伤支托的横截面进行金相、电镜及能谱检验分析.通过对Cr25Ni20和lncoloy800H两种材料的抗渗碳能力的比较,得出了以下结论:催化剂支托损伤的原因是材料在含氢高温环境下发生了表面渗碳现象,直接导致材料表面组织相变、材料分层、表现材料组织疏松和隆起,

  15. Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction. Final technical report, Volume 1 - effects of solvents, catalysts and temperature conditions on conversion and structural changes of low-rank coals

    Energy Technology Data Exchange (ETDEWEB)

    Lili Huang; Schobert, H.H.; Chunshan Song

    1998-01-01

    The main objectives of this project were to study the effects of low-temperature pretreatments on coal structure and their impacts on subsequent liquefaction. The effects of pretreatment temperatures, catalyst type, coal rank, and influence of solvent were examined. Specific objectives were to identify the basic changes in coal structure induced by catalytic and thermal pretreatments, and to determine the reactivity of the catalytically and thermally treated coals for liquefaction. In the original project management plan it was indicated that six coals would be used for the study. These were to include two each of bituminous, subbituminous, and lignite rank. For convenience in executing the experimental work, two parallel efforts were conducted. The first involved the two lignites and one subbituminous coal; and the second, the two bituminous coals and the remaining subbituminous coal. This Volume presents the results of the first portion of the work, studies on two lignites and one subbituminous coal. The remaining work accomplished under this project will be described and discussed in Volume 2 of this report. The objective of this portion of the project was to determine and compare the effects of solvents, catalysts and reaction conditions on coal liquefaction. Specifically, the improvements of reaction conversion, product distribution, as well as the structural changes in the coals and coal-derived products were examined. This study targeted at promoting hydrogenation of the coal-derived radicals, generated during thermal cleavage of chemical bonds, by using a good hydrogen donor-solvent and an effective catalyst. Attempts were also made in efforts to match the formation and hydrogenation of the free radicals and thus to prevent retrogressive reaction.

  16. [Conduct theoretical and experimental research programs in high energy physics]: Technical progress, Appendix A-2, FTP/A, Item 20,f

    International Nuclear Information System (INIS)

    Progress is reported in these areas: neutrino physics; nucleon decay and the intrinsic properties of neutrinos; the D-zero experiment; QCD jet physics and ultrarelativistic nuclear physics; the Colliding Detector at Fermilab; rare kaon decay; the Anomalous Single Photon detector at SLAC; particle theory; neutrino astrophysics and cosmology; and operations and support services

  17. Geothermal resource assessment of Mt. Hood volcano, Oregon, Phase I study. Technical progress report No. 2, October 1, 1977--March 31, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Hull, D.A.

    1978-05-31

    Several phases of the Mt. Hood geothermal resource assessment project are nearing completion. Most of the field work has been completed for the geologic study, gravity survey, and water sampling portions of the project. Thermal modelling, water analyses, rock analyses and age dating, and preparation of a complete Bouguer gravity map are in progress.

  18. Materials testing and requirement for the ERDA nuclear-powered artificial heart. Technical progress report, July 15, 1975--May 30, 1976. [BIOMER and AVCOTHANE

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, J. D.; Hufferd, W. L.; Lyman, D. J.

    1976-01-01

    The two materials currently being used for the artificial heart fabrication are BIOMER and AVCOTHANE. BIOMER is a polyether urethane polymer. AVCOTHANE is a proprietary polyurethane/polydimethylsiloxane polymer blend. Research progress on the chemical degradation, mechanical strength, and blood compatibility is reported. (TFD)

  19. A "Fear" Studies Perspective and Critique: Analyzing English and Stengel's Progressive Study of Fear and Learning in "Education Theory." Technical Paper No. 37

    Science.gov (United States)

    Fisher, R. Michael

    2011-01-01

    The author critiques the progressive approach of two contemporary educational philosophers (English and Stengel) on the topic of fear and learning. Using a postmodern integral approach, this article examines the tendency of reductionism, individualism, and psychologism as part of a hegemonic liberalism and modernism in discourses on fear and…

  20. Design, engineering, and evaluation of refractory liners for slagging gasifiers. Second annual technical progress report, 1 October 1979-30 September 1980

    Energy Technology Data Exchange (ETDEWEB)

    Booth, G.; Firestone, R. F.; Greaves, M. J.; Hales, C.; Lamoureux, J. P.; Ledford, R. R.

    1980-10-01

    The program has been making steady progress to completion. The refractory liner test system is a much more complex design than originally proposed, but it is also safer and better able to simulate the actual coal gasification environment to which refractories will be exposed. Consequently, the data from the tests will be more reliable and the final handbook more useful for refractory liner design.

  1. GPHS-RTGs in support of the Cassini Mission. Semi-annual technical progress report, April 3, 1995--October 1, 1995

    International Nuclear Information System (INIS)

    This document is the April-October 1995 Progress Report on the Cassini RTG Program. Nine tasks are summarized; (1) Spacecraft integration and liason, (2) Engineering support, (3) Safety, (4) Unicouple fabrication, (5) ETG fabrication, assembly, and test, (6) Ground support equipment, (7) RTG shipping and launch support, (8) Design, reviews, and mission applications, and (9) Project management, QA, contract changes, and material acquisitions

  2. Alloy catalyst material

    DEFF Research Database (Denmark)

    2014-01-01

    The present invention relates to a novel alloy catalyst material for use in the synthesis of hydrogen peroxide from oxygen and hydrogen, or from oxygen and water. The present invention also relates to a cathode and an electrochemical cell comprising the novel catalyst material, and the process use...... of the novel catalyst material for synthesising hydrogen peroxide from oxygen and hydrogen, or from oxygen and water....

  3. Resin Catalyst Hybrids

    Institute of Scientific and Technical Information of China (English)

    S. Asaoka

    2005-01-01

    @@ 1Introduction: What are resin catalyst hybrids? There are typically two types of resin catalyst. One is acidic resin which representative is polystyrene sulfonic acid. The other is basic resin which is availed as metal complex support. The objective items of this study on resin catalyst are consisting of pellet hybrid, equilibrium hybrid and function hybrid of acid and base,as shown in Fig. 1[1-5].

  4. Progress on the appliction of mesoporous catalysts in the oxidation desulfurization of oil%油品氧化脱硫介孔催化剂研究进展

    Institute of Scientific and Technical Information of China (English)

    王天星; 杨丽娜; 娄井阳; 王义皓; 郭来德

    2012-01-01

    Applications of mesoporous catalysts including modified mesoporous SBA-15 catalyst,series of modified mesoporous MCM-n,modified HMS,mesoporous silicate,mesoporous transition metal oxides and mesoporous carbon as catalysts in the oxidation desulfurization were introduced. Loading tungsten, phosphorus,molybdenum, titanium and other elements on the mesoporous materials catalysts can efficiently improve the catalytic conversion of macromolecular organic sulfur in the oil, however, the stability of the catalytic active center need to be increased significantly.%综述了介孔催化剂包括改性SBA 15介孔催化剂、改性MCM-n系列介孔催化制、改性HMS介孔催化剂,介孔硅酸盐催化剂、介孔过渡金属氧化物催化剂及介孔碳催化剂在油品氧化脱硫中的应用.指出介孔催化剂能够高效催化转化油品中的大分子有机硫化物,通过负载钨、磷、钼、钛等元素使得油品氧化脱硫率大大增加,但是催化剂活性中心的稳定性和催化剂的寿命还需要进一步的提高.

  5. Progress in plasma treated catalysts used in pollution control%等离子体处理催化剂应用于大气污染控制研究进展

    Institute of Scientific and Technical Information of China (English)

    向瑛; 唐晓龙; 易红宏; 李凯; 王建根; 王川

    2011-01-01

    利用等离子体处理催化剂是目前比较有吸引力和发展前景的技术.介绍了等离子体处理催化剂应用于大气污染控制方面的研究进展,分别讨论了等离子体的处理对催化剂比表面积和孔径、分散性、稳定性、活性、其他结构等的影响,以及等离子体处理条件对催化剂性能的影响,探讨了等离子体技术在催化剂制备方面的应用前景和发展方向.%Plasma-treated catalysts are attractive and promising currently. The perspectives of plasma treated catalysts used in air pollution control are reviewed. The influences of catalyst's specific surface area and pore diameter, dispersion,stability,activity,other structure by plasma treated and the plasma treatment conditions are also discussed. In the end, the prospect on the preparation of catalysts by plasma technology is proposed.

  6. Research Progress on Catalyst of Catalytic Wet Air Oxidation for Phenol Wastewater%催化湿式氧化含酚废水催化剂的研究进展

    Institute of Scientific and Technical Information of China (English)

    李荣; 段大勇

    2015-01-01

    Catalytic wet air oxidation ( CWAO ) technology is an effective technology for phenol wastewater, developing and selecting suitable catalyst is a key factor of CWAO. Active components were briefly introduced and CWAO catalyst for phenol wastewater treatment was carried out. It was specified that selecting the best combination of suitable active component and carrier of CWAO catalyst can improve the efficiency of phenol degradation, developing the catalyst with high activity, stability and cheap characteristics was the development direction of CWAO for phenol wastewater treatment.%催化湿式氧化技术是处理含酚废水的有效技术,此技术的关键是合适催化剂的研制和选用。本文对催化湿式氧化含酚废水催化剂的活性组分、载体等情况进行了综述,并指出选用最佳活性组分和载体的组合能够提高催化剂对苯酚的降解效率,研发高活性、高稳定性及廉价的催化剂是催化湿式氧化含酚废水的发展方向。

  7. Study Progress of the Catalytic Hydrogenation of Chloronitrobenzene with Modified Palladium Catalysts%钯金属催化氯代硝基苯加氢的研究进展

    Institute of Scientific and Technical Information of China (English)

    徐文龙; 杨晓瑞; 梁金花; 陈安猛; 朱建良

    2015-01-01

    以钯金属催化剂催化氯代硝基苯加氢制备氯代苯胺的工艺具有催化活性高、催化剂可回收套用、绿色环保等优点,然而该类催化剂在催化过程中经常发生脱氯氢解生成副产物,影响产品品质,因此寻找合适的方法抑制脱氯副反应成为了目前该类反应研究的热点问题。本文阐述了钯金属催化剂的多种改性方法,重点介绍了钯金属纳米颗粒的制备,合适载体的选择,以及水溶性钯金属催化剂的制备等改性途径,通过钯金属催化剂的改性可以提高其催化氯代硝基苯加氢反应中反应物的转化率与目标产物的选择性。目前钯金属负载型催化剂已经成为工业抑制脱氯副反应的主要方法,其中高分子聚合-钯络合催化剂效果最优。%In the catalytic hydrogenation process of chloronitrobenzene to chloroaniline with the palladium catalyst, these advantages were showed that higher catalytic activity, catalyst recyclable and environmental friendly. However, this kind of catalyst could lead to a dechlorohydrogenation in the catalytic process and produce by-products which infect the quality of outcome. Searching for the method to restrain the side reaction has been the hot point problems. Several methods modifying palladium catalysts are investigated and compared in this review. It is focused on the introduction of the preparation of palladium nano-particles, the selection of suitable supports and the preparation of water-soluble palladium catalysts. The conversion of reactant and the selectivity of desired products in the catalytic hydrogenation of chloronitrobenzene would be increased by the modification of palladium catalysts. Presently, the preparation of supported palladium catalyst is the preferred method for restraining the side reactions in industry, in which the supported polymer-palladium complexes is the best.

  8. 合成甲醇铜基催化剂及制备工艺研究进展%Research progress in Cu-based catalysts for methanol synthesis and their preparation technology

    Institute of Scientific and Technical Information of China (English)

    程金燮; 胡志彪; 王科; 凌华招; 邹鑫; 徐晓峰; 李倩; 黄宏

    2015-01-01

    合成甲醇大型化装置主要使用铜基催化剂,并且铜基催化剂类型、助催化剂和制备工艺等对甲醇收率影响较大。合成甲醇铜基催化剂主要分为 CU - Zn、CU - Zn - Cr、CU - Zn - Al、CU - Zr以及其他类,CU - Zn - Al 催化剂性能优异,是当代甲醇生产技术主要采用的催化剂。碱金属、碱土金属、过渡金属、稀土金属和非金属元素对合成甲醇催化剂的活性、选择性和稳定性表现出不同作用。沉淀法、溶胶-凝胶法、燃烧法、机械混合法和骨架合成法等是制备铜基催化剂的有效方法,工业上制备合成甲醇催化剂主要采用沉淀法。针对合成甲醇大型化装置催化剂的开发,提升催化剂的选择性与稳定性是下一步的研究重点。%CU-based catalysts were commonly Used in large-scale methanol synthesis device,and the cat-alyst types,promoters and preparation process have significant inflUence on the yield of methanol. CU-based catalyst for methanol synthesis coUld be mainly divided into CU-Zn,CU-Zn-Cr,CU-Zn-Al,CU-Zr and so on. CU-Zn-Al catalysts possessed excellent performance,and were Used for the main catalyst in contemporary methanol prodUction technology. Alkali metal,alkaline earth metal,transition metal,rare earth metal and nonmetal elements showed different effects on the activity,selectivity and stability of the catalysts for methanol synthesis. The effective preparation methods of CU-based catalysts were precipitation method,sol-gel method,combUstion method,mechanical mixing method and skeleton synthesis method, and precipitation method was mainly Used for the preparation of methanol synthesis catalyst in indUstry. As for the development of the catalysts for large-scale methanol synthesis device,the improvement of selectivity and stability of the catalysts were the next research key.

  9. Reaserch progress in bifunctional catalysts for cellulose to polyols%双功能催化剂在纤维素制多元醇中的研究进展

    Institute of Scientific and Technical Information of China (English)

    肖竹钱; 欧阳洪生; 葛秋伟; 王珍珍; 张金建; 蒋成君; 计建炳; 毛建卫

    2015-01-01

    The research on heterogeneous bifunctional catalysts (BFC) is the hot theme in cellulose processing to obtain green chemicals. But in this process,the BFC still had some fatal problems needed to be solved,such as the mechanism of the catalytic process,and its low selectivity for aimed products and hydrothermal stability. The research progress in most concerned BFC containing active metal components,such as Ru,Ni,W,and Pt,and the interacts between metal components and carriers for the application in cellulose to hexabasic alcohols and low carbon polyols (C2-C3),were introduced, and the recent advances in mono-metallic,bi-metallic BFC and the BFC based on different carriers were simply summarized. The analysis results demonstrated the ratios of different metal components and the internal interacts between active metals and carriers had a great influence on catalytic results. The future study should be focused on the mechanism of interacts of catalytic constituents and carriers.%双功能催化剂的研究一直是纤维素降解制备高值化学品过程中催化剂研究的热点问题,但其在催化纤维素降解过程中还存在着催化机理不明确、目标产物选择性不高、水热稳定性不好等问题.本文简述了目前最受关注的含Ru、Ni、W、Pt等体系的双功能催化剂和不同载体影响下的双功能催化剂在纤维素制备C6多元醇、低碳多元醇(C2~C3)等化学品中的研究进展,初步总结了单金属、双金属体系和不同载体的双功能催化剂研究的前沿进展,分析表明不同活性金属之间配比以及活性金属与载体之间的相互作用均对催化效果产生重大影响;最后对其在纤维素制备多元醇中的应用前景进行了展望,指出继续研究活性金属之间及其与载体之间的相互作用将是今后研究的重点方向.

  10. Evaluation and capacity building to improve precollege science and mathematics achievement in the US: 10 CFR, Part 605. Technical progress report, June--December 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-31

    The National Center for Improving Science Education has undertaken activities to achieve evaluation goals for DOE`s Precollege programs: develop means to determine program quality; develop means for determining the contribution of DOE precollege programs to both teacher enhancement and student achievement; provide evaluation designs and instruments and reports of program quality and impact; and strengthen both DOE`s and the Labs` capacity to do both short- and long-term planning as well as deliver effective programs and evaluation. Appendices include evaluation/technical assistance report, profiling teacher research participation and teacher development programs, teacher surveys, impact assessment design, and teacher research participation programs anecdotes for 8 labs.

  11. Production and screening of carbon products precursors from coal. Quarterly technical progress report No. 5, January 1,1996--March 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-04-01

    Individual quarterly reports of four industrial participants of this project are included in this report. The technical emphasis continues to be the supply of coal-based feedstocks to the industrial participants. There have been several iterations of samples and feedback to meet feedstock characteristics for a wide variety of carbon products. Technology transfer and marketing of the Carbon Products Consortium (CPC) is a continual effort. Interest in the program and positive results from the research continue to grow. In several aspects, the program is ahead of schedule.

  12. Parameterization of GCM subgrid nonprecipitating cumulus and stratocumulus clouds using stochastic/phenomenological methods. Annual technical progress report, 1 December 1992--30 November 1993

    Energy Technology Data Exchange (ETDEWEB)

    Stull, R.B.

    1993-08-27

    This document is a progress report to the USDOE Atmospheric Radiation and Measurement Program (ARM). The overall project goal is to relate subgrid-cumulus-cloud formation, coverage, and population characteristics to statistical properties of surface-layer air, which in turn are modulated by heterogeneous land-usage within GCM-grid-box-size regions. The motivation is to improve the understanding and prediction of climate change by more accurately describing radiative and cloud processes.

  13. GPHS-RTGs in support of the Cassini Mission. Semi annual technical progress report, 28 March 1994--25 September 1994

    International Nuclear Information System (INIS)

    The progress on the radioisotope generators and ancillary activities is described. This report is organized by program task as follows: spacecraft integration and liaison; engineering support; safety; qualified unicouple fabrication; ETG fabrication, assembly, and test; ground support equipment; RTG shipping and launch support; design, reviews, and mission applications; project management, quality assurance and reliability, contract changes, non-capital CAGO acquisition, and CAGO maintenance; contractor acquired government owned property (CAGO) acquisition

  14. Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction. Technical progress report, October 1991--December 1991

    Energy Technology Data Exchange (ETDEWEB)

    Song, C.; Saini, A.; Huang, L.; Wenzel, K.; Hatcher, P.G.; Schobert, H.H.

    1992-01-01

    Low-temperature catalytic pretreatment is a promising approach to the development of an improved liquefaction process. This work is a fundamental study on effects of pretreatments on coal structure and reactivity in liquefaction. The main objectives of this project are to study the coal structural changes induced by low-temperature catalytic and thermal pretreatments by using spectroscopic techniques; and to clarify the pretreatment-induced changes in reactivity or convertibility of coals in the subsequent liquefaction. This report describes the progress of our work during the first quarterly period. Substantial progress has been made in the spectroscopic characterization of fresh and THF-extracted samples of two subbituminous coals and fresh samples of three bituminous coals using cross-polarization magic angle spinning (CPMAS) solid state {sup 13}C NMR and pyrolysis-GC-MS techniques. CPMAS {sup 13}C NMR and pyrolysis-GC-MS provided important information on carbon distribution/functionality and molecular components/structural units, respectively, for these coal samples. Pyrolysis-GC-MS revealed that there are remarkable structural differences in structural units between the subbituminous coals and the bituminous coals. Furthermore, significant progress has been made in the pretreatments and spectroscopic characterization of catalytically and thermally pretreated as well as physically treated Wyodak subbituminous coal, and temperature-staged and temperature-programmed thermal and catalytic liquefaction of a Montana subbituminous coal.

  15. Engineering-support services for the DOE/GRI coal-gasification research program. Quarterly technical progress report, April-June 1981

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, D.M.; Bostwick, L.E.; Ethridge, T.R.; Gilwood, W.C.; Hubbard, D.A.; Montgomery, R.L.; Senules, E.A.; Singer, D.L.; Smith, M.R.; Ward, W.E.

    1981-01-01

    Kellog activities during April to June 1981 included continued monitoring of activities at Bi-Gas, Westinghouse, Exxon and IGT (for peat gasification). Pilot plant/PDU tests which were monitored and reported include Bi-Gas tests G-16B, G-17, G-17A, G-17B, and G-17C; Westinghouse PDU test runs TP-029-1/030-1, TP-030-2 and TP-028-1 and CFSF tests TP-M002-1 and TP-M002-2; Exxon run period number 28; Peatgas pilot plant Test RF-1 and gasification Test number 1; and IGT single-stage peat gasification PDU Tests BF-13 through BF-20. Significant milestones were reached with the issue of draft reports for several tasks, including carbonyl formation, peat harvesting/dewatering, technical/economic assessments of Exxon, Westinghouse and PeatGas, technical/economic comparison of Westinghouse and U-Gas, gasifier design, safety audits, Hygas data base evaluation and the safety assurance study. In addition, final reports were issued for the Westinghouse oxygen blown gasifier risk analysis and for the PDU screening evaluations of Exxon, Westinghouse and Rockwell. Work on the Peatgas PDU data base evaluation continued, and a review of the Hygas final report was begun.

  16. Engineering-support services for the DOE/GRI coal-gasification research program. Quarterly technical progress report, July-September 1981

    Energy Technology Data Exchange (ETDEWEB)

    Bostwick, L.E.; Ethridge, T.R.; Gilwood, W.C.; Glasgow, P.E.; Hubbard, D.A.; Shah, K.V.; Singer, D.L.; Smith, M.R.; Ward, W.E.

    1981-01-01

    During July-September 1981 Kellogg continued to actively monitor operations at BI-GAS, Westinghouse and IGT (for peat gasification). Pilot plant/PDU tests which were monitored and reported included BI-GAS Tests G-17D, G-17E, and G-17F; Westinghouse PDU test runs TP-0282 and TP-028-3 and CFSF Tests TP-M002-2 and TP-M006-1; Peatgas pilot plant Tests number 2 and number 3; and single-stage peat gasification PDU Test BF-21. Work on several task orders was completed with the issue of final reports on technical/economic assessments of Exxon, Westinghouse and Peatgas, the technical/economic comparison of Westinghouse and U-Gas, safety audits, safety assurance, peat harvesting and dewatering, gasifier vessel design and carbonyl formation. Kellogg continued its efforts toward completion of the descriptive brochure for the DOE/GRI Joint program and of the reports on the Hygas and Peatgas data bases. A new subtask, to evaluate the data base for single-stage peat gasification, was undertaken, and Kellogg participated in reviews of the Hygas final report. Normal MPC activities continued.

  17. Engineering-support services for the DOE/GRI Coal-Gasification Research Program. Quarterly technical progress report, July-September 1980

    Energy Technology Data Exchange (ETDEWEB)

    Bostwick, L.E.; Brancheau, R.J.; Castiglioni, B.P.

    1982-01-01

    Kellogg activities included contained monitoring of test operations at the Hygas, BI-GAS, Westinghoue, Exxon and Bell plant sites. Peat gasification laboratory tests were also monitored; Rockwell testing ended during June. Pilot Plant/PDU test runs monitored and reported were: Hygas Test 87 (the last of the pilot plant series), BI-GAS Tests G-13 and G-14, Westinghouse test runs TP-027, TP-027-4 and TP-027-5, Exxon test periods 19 through 21 and Bell Tests 2174 through 3195. Kellogg continued its work on the Hygas data base evaluation and began an evaluation of the scaleup risks of the Westinghouse oxygen-blown gasifier. Work under new task orders was initiated. The topics included are: Technical/Economic Assessments of Westinghouse, Exxon and Peatgas, Gasifier Vessel Design, Technical/Economic Comparisons of Westinghouse and U-Gas, Peat Harvesting and Dewatering, and Carbonyl Formation in Coal Gasification processes. Economics are essentially complete for the Screening Evaluations of Westinghouse, Exxon and Rockwell and report preparation has begun. Work on the Pilot/Plant PDU Safety Evaluation Task continued.

  18. 对甲酚烷基化反应催化剂的研究进展%Research progress of catalysts used in the alkylation reaction ofp-cresol

    Institute of Scientific and Technical Information of China (English)

    张吕鸿; 王江涛; 肖晓明; 罗铭芳; 朱桃月; 张荣亚

    2016-01-01

    主要从酸性催化剂的发展历程全面综述了分子筛、固体超强酸、离子交换树脂、杂多酸、离子液体等多种酸性催化剂的优点和缺点,并总结出对甲酚在不同催化剂作用下反应产物区域选择性的结果。通过对多种催化剂的特性和反应结果对比着重介绍了离子液体催化剂,离子液体同时拥有液体酸高密度酸性和固体酸易分离不挥发的优点,在保持着浓硫酸酸性强度的同时,还具有低蒸气压、热稳定性高、对环境无污染、功能化设计的优良特性,这为今后对甲酚烷基化反应绿色催化剂的发展提供了重要的研究方向,避免了目前工业上常用液体酸催化剂存在的污染环境设备和安全隐患等重大问题。%Various novel acidic catalysts in the development history of catalysts,such as molecular sieves,super solid acids,heteropoly acids,ion exchange resins,ionic liquids,are introduced .The products’ regioselectivity ofp-cresol under the acidic catalysts are also summarized. Through comparing the characteristics of various catalysts and reaction results,ionic liquids are introduced as key points which show both high density acidity by liquid acids and easy separation by non-volatile solid acids. Apart from the acidity of similar to sulfuric acid,ionic liquids also have good features of low consumption,stability to water and air,no pollution and functional design which provide an important research direction for development of the catalysts ofp-cresol alkylation reaction. Also, problems of liquid acid catalysts used in industrial such as corrosion and safety can be avoided.

  19. Progress in portable direct methanol fuel cell

    Institute of Scientific and Technical Information of China (English)

    佘沛亮; 胡信国; 陈怀林

    2004-01-01

    The progresses in portable DMFC worldwide were reviewed, the current status of its components, catalysts, proton exchange membrane and flow field plate, the market development of portable electronic appliances, such as mobile phone, PDA and notebook were introduced.

  20. Magnetic catalyst bodies

    NARCIS (Netherlands)

    Teunissen, Wendy; Bol, A.A.; Geus, John W.

    2001-01-01

    After a discussion about the importance of the size of the catalyst bodies with reactions in the liquid-phase with a suspended catalyst, the possibilities of magnetic separation are dealt with. Deficiencies of the usual ferromagnetic particles are the reactivity and the clustering of the particles.

  1. Catalyst for Ammonia Oxidation

    DEFF Research Database (Denmark)

    2015-01-01

    The present invention relates to a bimetallic catalyst for ammonia oxidation, a method for producing a bimetallic catalyst for ammonia oxidation and a method for tuning the catalytic activity of a transition metal. By depositing an overlayer of less catalytic active metal onto a more catalytic...

  2. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, second quarter 1994, April 1994--June 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NOx combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NOx burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters. Results are described.

  3. Development of coal-based technologies for Department of Defense Facilities. Semiannual technical progress report, September 28, 1996--March 27, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Miller, B.G.; Miller, S.F.; Pisupati, S.V. [and others

    1997-07-22

    The U.S. Department of Defense (DOD), through an Interagency Agreement with the U.S. Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal-Water Slurry Fuel Technology, with the aim of developing technologies which can potentially decrease DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Work in Phase III focused on coal preparation studies, pilot-scale NO{sub x} reduction studies, economic analyses of coal use, and evaluation of deeply-cleaned coal as boiler fuel. Coal preparation studies were focused on continuing activities on particle size control, physical separations, surface-based separation processes, and dry processing. Preliminary pilot-scale NO{sub x} reduction catalyst tests were conducted when firing natural gas in Penn State`s down-fired combustor. This is the first step in the scale-up of bench-scale results obtained in Phase II to the demonstration boiler scale when firing coal. The economic study focused on community sensitivity to coal usage, regional/national economic impacts of new coal utilization technologies, and constructing a national energy portfolio. The evaluation of deeply-cleaned coal as boiler fuel included installing a ribbon mixer into Penn State`s micronized coal-water mixture circuit for reentraining filter cake. In addition, three cleaned coals were received from CQ Inc. and three cleaned coals were received from Cyprus-Amax.

  4. Continuing development of regenerable sorbents for fluidized-bed combustion. Semiannual technical progress report No. 2, April 1-September 30, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Kalfadelis, C D

    1980-01-01

    Our efforts were directed primarily to preparation for and/the initial operation of the laboratory-scale hot fluidized bed test system (LSHFB). The initial test sequence in the LSHFB system was performed with a fixed-bed of 100 grams of barium titanate synthetic sorbent. The sorbent bed was alternately sulfated and regenerated five times. Sulfation was accomplished at 900/sup 0/C, with a synthetic flue gas mixture comprising 10.1% CO/sub 2/, 4.95% O/sub 2/, 0.2435% SO/sub 2/ and 84.7% N/sub 2/. Regeneration was performed at 1025/sup 0/C with a gas containing 8.0% CO and 92.0% N/sub 2/. After an initial drop in sulfation performance after the first sulfation/regeneration cycle, performance held steady, or was shown to be improving, during the succeeding four cycles. Although the initial operation of this system proceeded relatively smoothly, the reactor was found to have been irreparably damaged by the end of the initial test sequence. A new reactor was subsequently designed, fabricated, and installed in the unit. Concurrently, sorbent pellet preparation by extrusion was investigated in the Catalyst Preparation Facility at the Baton Rouge Laboratory of Exxon Research and Engineering Company. Preparation of sorbent pellets for use in the LSHFB operation was continued on a laboratory-scale at Linden throughout the reporting period. Cost and time estimates were prepared for operation of the bench-scale fluidized bed coal combustion and regeneration facilities, including preparation of the requisite volumes of synthetic sorbent pellets needed for that program.

  5. A study on the catalyst for the removal of dissolved oxygen from NPP's system water

    International Nuclear Information System (INIS)

    The catalytic removal method of dissolved oxgen was selected as optimm process, which can produce water with less than 5 ppb dissolved oxgen, maximum permissible concentration. To develope the catalyst essential to the removal process, technical investigation, fundamental experiment, property test and analysis for various catalysts were carried out. The setup of methodology, column design for catalyst performance test also have been carried out. (Author)

  6. 介孔硅材料及其负载型催化剂去除挥发性有机物的最新进展%Recent Progress in the Removal of Volatile Organic Compounds by Mesoporous Silica Materials and Supported Catalysts

    Institute of Scientific and Technical Information of China (English)

    张晓东; 王吟; 杨一琼; 陈丹

    2015-01-01

    Mesoporous silica materials have attracted much attention because of their large surface area, uniform pore-size distribution, large pore size, and wide potential applications in the fields of separation, adsorption, and catalysis. The progress in the removal of volatile organic compounds (VOCs, mainly containing hydrocarbons, methanol, formaldehyde, acetone, benzene, toluene, naphthalene, and ethyl acetate) by mesoporous silica materials and supported catalysts in recent years is reviewed. The effect of the structure of mesoporous silica materials on the adsorption of VOCs is discussed. We also discuss the catalytic performance and reaction mechanism for catalytic VOC oxidation over supported catalysts. The recent developments in catalytic combustion of toluene are examined in detail. We found that the surface environment, pore structure, and morphology of mesoporous silica materials are the main factors influencing adsorption of VOC molecules. The application of noble metal catalyst focuses on improving poison resistance and reducing cost. The research on non-noble metal catalysts focuses on developing supported mixed-metal oxide catalysts with high activity. Future developments of mesoporous silica materials and supported catalysts are highlighted. The design of the catalyst can be carried out from two aspects: the silica support and the mesoporous channel. This review wil be helpful in choosing an appropriate catalyst for the removal of VOCs with high activity and stability.%介孔硅材料由于具有大的比表面积,均一的孔结构和大的孔径,常被用于分离、吸附和催化等领域。本文综述了近年来国内外介孔硅材料及其负载型催化剂去除各类挥发性有机物(VOCs)的研究进展,主要包括烃类、甲醇、甲醛、丙酮、苯、甲苯、萘、乙酸乙酯等。讨论了介孔硅材料的结构对VOCs吸附过程的影响;介绍了不同催化剂消除各类VOCs的催化性能及反

  7. Heterogeneous hydrogenation catalysts

    International Nuclear Information System (INIS)

    The main types of heterogeneous catalysts used for hydrogenation, the methods for their preparation, and the structure and chemistry of their surfaces are considered, as well as the catalytic activity and the mechanism of action in the hydrogenation of unsaturated and aromatic compounds, of CO, and of carbonyl compounds and in the hydrorefining of fuels. Chief attention is paid to supported Ni catalysts, to the methods for their preparation and physicochemical studies, and to the development of novel catalytic systems through modification. A novel type of catalyst for hydrogenation, viz. metal carbides, is described. Some aspects of the mechanochemical treatment of hydrogenation catalysts, including in situ methods, are discussed. Sulfide catalysts for hydrotreating are also discussed in detail. The bibliography includes 340 references.

  8. Design of heterogeneous catalysts

    DEFF Research Database (Denmark)

    Frey, Anne Mette

    . Previously it has been shown that calcination of cobalt catalyst in a NO/He mixture resulted in improved catalytic activity compared to standard air calcined samples, since more homogenous cobalt particles with a narrow particle size distribution were formed. Unfortunately the C5+ selectivity decreased....... Since Mn is known to improve C5+ selectivity the addition of this promoter, combined with NO calcination, was studied. The influence of parameters such as Co:Mn ratio, drying conditions, and reduction temperatures on the catalytic performance were investigated. The promotion strategy turned out to work...... well, and the best catalyst prepared had a C5+ yield almost a factor of two higher than a standard air calcined Co catalyst. In the NH3-SCR reaction it is desirable to develop an active and stable catalyst for NOx removal in automotive applications, since the traditionally used vanadium-based catalyst...

  9. Clean coal technology III (CCT III): 10 MW demonstration of gas suspension absorption. Technical progress report, October 1, 1990--December 31, 1990

    Energy Technology Data Exchange (ETDEWEB)

    1990-12-31

    This project will be the first North American demonstration of the Gas Suspension Absorption (GSA) System in its application for flue gas desulfurization. The purpose of this project is to demonstrate the high sulfur dioxide (SO{sub 2}) removal efficiency as well as the cost effectiveness of the GSA system. GSA is a novel concept for flue gas desulfurization developed by F.L. Smidth miljo (FLS miljo). The GSA system is distinguished in the European market by its low capital cost, high SO{sub 2} removal efficiency and low operating cost. The specific technical objectives of the GSA demonstration project are to: effectively demonstrate SO{sub 2} removal in excess of 90% using high sulfur US coal. Optimize recycle and design parameters to increase efficiencies of lime reagent utilization and SO{sub 2} removal. Compare removal efficiency and cost with existing Spray Dryer/Electrostatic Precipitator technology.

  10. Progress in design, research and development and testing of safety systems for advanced water cooled reactors. Proceedings of a technical committee meeting

    International Nuclear Information System (INIS)

    The meeting covered the following topics: Developments in design of safety-related heat removal components and systems for advanced water cooled reactors; status of test programmes on heat removal components and systems of new designs; range of validity and extrapolation of test results for the qualification of design/licensing computer models and codes for advanced water cooled reactors; future needs and trends in testing of safety systems for advanced water cooled reactors. Tests of heat removal safety systems have been conducted by various groups supporting the design, testing and certification of advanced water cooled reactors. The Technical Committee concluded that the reported test results generally confirm the predicted performance features of the advanced designs. Refs, figs, tabs

  11. Nuclear interactions of high energy heavy ions and applications in astrophysics: Technical progress report, 1 April 1988--31 March 1989

    International Nuclear Information System (INIS)

    During the past year of activity under DOE Grant DE-FG05-84ER40147 at Louisiana State University we have made significant progress in the data analysis, in hardware development for the Bevalac and in new experimental runs. We now have reliable longitudinal momentum distributions for 16O at three energies, 225, 170 and 360 MeV/nucleon. Combining these results with previous data shows an unexpected energy dependence of the momentum widths for A = 12--15 fragments. The widths peak at /approximately/100 MeV/nucleon projectile energy. We have also finished the analysis for 3 of the 4 energy points from the 6/87 28Si investigation of the total charge changing cross sections. These results also show an energy dependence. With the University of Siegen group, we have analyzed the test data from a new drift chamber system and used the system to provide trajectory measurements for the 28Si run in B40. The test data demonstrated position resolution of better than 100μm in some operating modes, and a study of the resolution dependence on timing mode, discriminator setting and wire voltage has been prepared for publication. The 28Si run provided 30-50% of the data we had hoped to obtain. There were significant beam and beamline tuning problems at our rigidity. Nevertheless, a relatively complete dataset for 245 MeV/n 28Si was obtained, processed and calibrations are in progress. In addition, we have participated in a HISS run at 2.1 GeV/n obtaining data on the fragmentation of 4He and 20Ne. All of the datasets, both B40 and HISS, are being analyzed and significant progress has been achieved. 20 figs

  12. Advanced development of fine coal desulfurization and recovery technology. Quarterly technical progress report, October 1, 1976--December 31, 1976. [53 references

    Energy Technology Data Exchange (ETDEWEB)

    Fisher, R.W.; Wheelock, T.D.

    1977-02-01

    The improvement and technical development of promising methods for desulfurizing and recovering fine coal underway includes froth flotation, selective oil agglomeration, pelletization, and a chemical desulfurization process which involves leaching fine coal with a hot dilute solution of sodium carbonate containing dissolved oxygen under pressure. A preliminary assessment of the state of the art and review of the technical literature has been made. Equipment and apparatus have been assembled for small-scale laboratory experiments in froth flotation, oil agglomeration and chemical desulfurization. Preliminary froth flotation tests have been carried out on an Iowa coal to establish baseline data. Quite unexpectedly these tests indicated that aluminum nitrate may be an activator for coal because it served to increase the recovery of coal. Several potential flotation depressants for pyrite have been screened by measurement at the zeta potential and floatability of pyrite or coal in aqueous suspensions containing the potential depressants. The following reagents show some promise as pyrite depressants: ferric chloride, sodium cyanide, ammonium thiocyanate, and the disodium salt of ethylenediaminetetraacetic acid. Preliminary plans have been prepared for a continuous flow bench-scale system to demonstrate the process. This system will include equipment for grinding and pretreating the coal as well as equipment for demonstrating froth flotation, selective oil agglomeration and pelletization. An investigation of coal microstructure as it relates to coal beneficiation methods has also been initiated. The distribution of various forms of pyrite by size and crystal structure has been determined for two cannel samples of coal through application of scanning electron microscope techniques.

  13. Characterization of open-cycle coal-fired MHD generators. 14th/15th quarterly technical progress report, February 1-July 31, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Wormhoudt, J.; Yousefian, V.; Weinberg, M.; Kolb, C.; Martinez-Sanchez, M.; Cheng, W.; Bien, F.; Dvore, D.; Unkel, W.; Stewart, G.

    1980-09-01

    The successful design of full-scale, open-cycle, coal-fired MHD generators for baseload electrical production requires a detailed understanding of the plasma chemical and plasma dynamic characteristics of anticipated combustor and channel fluids. Progress in efforts to model the efficiency of an open-cycle, coal-fired MHD channel based on the characterization of the channel flow as well as laboratory experiments to validate the modeling effort as detailed. In addition, studies related to understanding arcing phenomena in the vicinity of an anode are reported.

  14. Silicon germanium (SiGe) radioisotope thermoelectric generator (RTG) program for space missions. Nineteenth technical progress report, December 1980-January 1981

    International Nuclear Information System (INIS)

    Work accomplished during the reporting period on the DOE Silicon Germanium RTG Program, Contract DE-AC01-79ET-32043 is described. This program consists of the following three tasks: multi-hundred watt RTG for the Galileo probe mission; reestablishment of silicon germanium unicouple capability; and general purpose heat source RTG for the international solar polar and Galileo orbiter missions. Details of program progress for each task, including a milestone schedule and a discussion of current problem areas (if any) are presented

  15. 1993 Annual progress report for subsidiary agreement No. 2 (1991--1996) between AECL and US/DOE for a radioactive waste management technical co-operative program

    International Nuclear Information System (INIS)

    A coordinated research program on radioactive waste disposal is being carried out by the Atomic Energy of Canada Limited and the US Department of Energy. This annual report describes progress in the following eight studies: Fundamental materials investigations; In-situ stress determination; Development of a spent fuel dissolution model; Large block tracer test--Experimental testing of retardation models; Laboratory and field tests of in-situ hydrochemical tools; Cigar Lake--Analogue study, actinide and fission product geochemistry; Performance assessment technology exchange; and Development of multiple-well hydraulic test and field tracer test methods

  16. Research progress in the catalysts for vapor phase hydrogenation of dimethyl oxalate to ethylene glycol%草酸二甲酯气相法加氢制乙二醇催化剂研究进展

    Institute of Scientific and Technical Information of China (English)

    付金萍; 赵洋; 周强; 王树华; 吴周安; 谢冠群; 罗孟飞

    2014-01-01

    :the hydration of ethylene oxide depended on the petroleum resource and the hydrogenation of oxalate based on the syngas route from the coal or natural gas. The latter route is suitable for the situation of China, and is the focus of this review. During the indirect synthesis of EG from syngas,dimethyl oxalates( DMO) are firstly synthesized via the coupling of CO with nitrite esters,and then are catalytically hydrogenated to EG. The designment and preparation of highly active catalysts for DMO hydrogenation are the key to realize the industrialization of coal to EG. The catalysts for DMO hydrogenation to EG mainly include homogeneous ruthenium-based catalysts and homogeneous copper-based catalysts. Cu/SiO2 catalysts,non-chromium Cu-based catalysts,are nowadays research focus of DMO hydrogenation catalysts. Three key factors affecting the catalytic performance of Cu/SiO2 catalysts are supports,assistants and preparation methods. The types of supports can affect not only the interaction between the active species and supports,but also the dispersion of copper species. Supports with large surface areas and ordered mesoporous structure can improve the dispersion of copper species,and then greatly promote the activity and stability of Cu catalysts. The preparation methods of Cu/SiO2 catalysts include impregnation,deposition-precipitation,ammonia evapo-ration,and sol-gel method,etc. When Cu/SiO2 catalysts were prepared by ammonia evaporation method, copper-ammonia complex ions formed on the catalysts,which resulted in well dispersion of Cu species,and Cu+ contents on the surface of Cu/SiO2 catalysts after reduction were higher. The promoters,such as Mo, Co,Ni and B,etc,could modulate the valence and dispersion of Cu species greatly,and then improve the performance of the catalysts. The catalytic mechanism over Cu/SiO2 catalysts should be related to the cooperation of Cu0 and Cu+ in DMO hydronation to EG. Cu0 was as the active site for the activation of H2 ,and Cu+ was as Lewis

  17. Catalysts, methods of making catalysts, and methods of use

    KAUST Repository

    Renard, Laetitia

    2014-03-06

    Embodiments of the present disclosure provide for catalysts, methods of making catalysts, methods of using catalysts, and the like. In an embodiment, the method of making the catalysts can be performed in a single step with a metal nanoparticle precursor and a metal oxide precursor, where a separate stabilizing agent is not needed.

  18. Catalysts for CO2/epoxide ring-opening copolymerization

    OpenAIRE

    G. Trott; Saini, P. K.; Williams, C. K.

    2016-01-01

    This article summarizes and reviews recent progress in the development of catalysts for the ring-opening copolymerization of carbon dioxide and epoxides. The copolymerization is an interesting method to add value to carbon dioxide, including from waste sources, and to reduce pollution associated with commodity polymer manufacture. The selection of the catalyst is of critical importance to control the composition, properties and applications of the resultant polymers. This review highlights an...

  19. Technical Shibboleths.

    Science.gov (United States)

    Harris, John S.

    1998-01-01

    Focuses on technical sub-languages to reveal sociological functions of language that transcend mere transfer of substantive information. Finds one sociological feature, the shibboleth, acting widely throughout technical fields. (PA)

  20. Application of railgun principle to high-velocity hydrogen pellet injection for magnetic fusion reactor refueling. Technical progress report, [July 16, 1990--August 16, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Kim, K.

    1991-08-01

    This report contains three documents describing the progress made by the University of Illinois electromagnetic railgun program sponsored by the Office of Fusion Energy of the United States Department of Energy during the period from July 16, 1990 to August 16, 1991. The first document contains a brief summary of the tasks initiated, continued, or completed, the status of major tasks, and the research effort distribution, estimated and actual, during the period. The second document contains a description of the work performed on time resolved laser interferometric density measurement of the railgun plasma-arc armature. The third document is an account of research on the spectroscopic measurement of the electron density and temperature of the railgun plasma arc.

  1. Engineering support services for the DOE/GRI coal-gasification research program. Quarterly technical progress report, October-December 1981

    Energy Technology Data Exchange (ETDEWEB)

    Bostwick, L.E.; Ethridge, T.R.; Starr, D.W.; Shah, K.V.; Hubbard, D.A.; Koneru, P.B.; Smith, M.R.; Ward, W.E.; Wong, E.W.; Zeis, L.A.

    1982-02-01

    Kellogg continued to actively monitor operations at BI-GAS Westinghouse and IGT (for peat gasification). Pilot plant/PDU testing which was monitored and reported includes Westinghouse PDU tests TP-030-3 and TP-031-3 and CFSF test TP-M003-1; Peatgas Pilot Plant test No. 4; and single-stage peat gasification PDU tests BF-22 and BF-23. Kellogg personnel briefed the GRI Project Advisors on current tasks and a DOE representative on peat-related work. The report on the Hygas Data Base Evaluation was approved for issue. Progress was made toward finalizing the report on the Peatgas Data Base Evaluation and the Descriptive Brochure for the DOE/GRI Joint Program. Work on the evaluation of the data base for single-stage peat gasification continued. Review of the Hygas final report was completed.

  2. Identification and validation of heavy metal and radionuclide hyperaccumulating terrestrial plant species, Quarterly technical progress report, December 20, 1995--March 20, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Kochian, L.; Brady, D.; Last, M.; Ebbs, S.

    1995-12-01

    Although the period covered by this progress report began on December 20, 1994, which was the date that DOE approved the Interagency Agreement, the agreement was not approved by USDA until January 9, 1995 and the first scientists working on the project were not hired until February 1, 1995. The first goal of the research supported by the Interagency Agreement is to use hydroponic techniques to identify plant species and genotypes with potential for heavy metal hyperaccumulation for planting on a test site at Silverbow Creek and for radionuclide ({sup 90}Sr and {sup 137}Cs) accumulation on a test site at INEL, Idaho, later this year. The second goal of this research is to identify soil amendment procedures that will enhance the bioavailability of heavy metals and radionuclides in the soil without increasing the movement of the contaminants of concern (COC`s) into the groundwater. Our initial research covered in this report focuses on the first goal.

  3. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 11, April--June, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-07-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 tons of each of three project coals, by each process. During Quarter 11 (April--June, 1995), work continued on the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at the Lady Dunn Preparation Plant with the installation and calibration of a refurbished 30-inch diameter column. The evaluation of toxic trace element data for column flotation samples continued, with preliminary analysis indicating that reasonably good mass balances were achieved for most elements, and that significant reductions in the concentration of many elements were observed from raw coal, to flotation feed, to flotation product samples. Significant progress was made on Subtask 6.5 selective agglomeration bench-scale testing. Data from this work indicates that project ash specifications can be met for all coals evaluated, and that the bulk of the bridging liquid (heptane) can be removed from the product for recycle to the process. The detailed design of the 2 t/hr selective agglomeration module progressed this quarter with the completion of several revisions of both the process flow, and the process piping and instrument diagrams. Procurement of coal for PDU operation began with the purchase of 800 tons of Taggart coal. Construction of the 2 t/hr PDU continued through this reporting quarter and is currently approximately 60% complete.

  4. Catalyst in Basic Oleochemicals

    Directory of Open Access Journals (Sweden)

    Eva Suyenty

    2007-10-01

    Full Text Available Currently Indonesia is the world largest palm oil producer with production volume reaching 16 million tones per annum. The high crude oil and ethylene prices in the last 3 – 4 years contribute to the healthy demand growth for basic oleochemicals: fatty acids and fatty alcohols. Oleochemicals are starting to replace crude oil derived products in various applications. As widely practiced in petrochemical industry, catalyst plays a very important role in the production of basic oleochemicals. Catalytic reactions are abound in the production of oleochemicals: Nickel based catalysts are used in the hydrogenation of unsaturated fatty acids; sodium methylate catalyst in the transesterification of triglycerides; sulfonic based polystyrene resin catalyst in esterification of fatty acids; and copper chromite/copper zinc catalyst in the high pressure hydrogenation of methyl esters or fatty acids to produce fatty alcohols. To maintain long catalyst life, it is crucial to ensure the absence of catalyst poisons and inhibitors in the feed. The preparation methods of nickel and copper chromite catalysts are as follows: precipitation, filtration, drying, and calcinations. Sodium methylate is derived from direct reaction of sodium metal and methanol under inert gas. The sulfonic based polystyrene resin is derived from sulfonation of polystyrene crosslinked with di-vinyl-benzene. © 2007 BCREC UNDIP. All rights reserved.[Presented at Symposium and Congress of MKICS 2007, 18-19 April 2007, Semarang, Indonesia][How to Cite: E. Suyenty, H. Sentosa, M. Agustine, S. Anwar, A. Lie, E. Sutanto. (2007. Catalyst in Basic Oleochemicals. Bulletin of Chemical Reaction Engineering and Catalysis, 2 (2-3: 22-31.  doi:10.9767/bcrec.2.2-3.6.22-31][How to Link/DOI: http://dx.doi.org/10.9767/bcrec.2.2-3.6.22-31 || or local: http://ejournal.undip.ac.id/index.php/bcrec/article/view/6

  5. Implementing waste minimization at an active plutonium processing facility: Successes and progress at technical area (TA) -55 of the Los Alamos National Laboratory

    International Nuclear Information System (INIS)

    The Los Alamos National Laboratory has ongoing national security missions that necessitate increased plutonium processing. The bulk of this activity occurs at Technical Area -55 (TA-55), the nations only operable plutonium facility. TA-55 has developed and demonstrated a number of technologies that significantly minimize waste generation in plutonium processing (supercritical CO2, Mg(OH)2 precipitation, supercritical H2O oxidation, WAND), disposition of excess fissile materials (hydride-dehydride, electrolytic decontamination), disposition of historical waste inventories (salt distillation), and Decontamination ampersand Decommissioning (D ampersand D) of closed nuclear facilities (electrolytic decontamination). Furthermore, TA-55 is in the process of developing additional waste minimization technologies (molten salt oxidation, nitric acid recycle, americium extraction) that will significantly reduce ongoing waste generation rates and allow volume reduction of existing waste streams. Cost savings from reduction in waste volumes to be managed and disposed far exceed development and deployment costs in every case. Waste minimization is also important because it reduces occupational exposure to ionizing radiation, risks of transportation accidents, and transfer of burdens from current nuclear operations to future generations

  6. Simultaneous high-temperature removal of alkali and particulates in a pressurized gasification system. Final technical progress report, April 1981-July 1983

    Energy Technology Data Exchange (ETDEWEB)

    Mulik, P.R.; Alvin, M.A.; Bachovchin, D.M.

    1983-09-01

    This program is directed at performing experimental and analytical investigations, deriving system designs, and estimating costs to ascertain the feasibility of using aluminosilicate-based getters for controlling alkali in pressurized gasification systems. Its overall objective is to develop a plan for evaluating a scaled-up version of the gettering process as a unit operation or as an integral part of a particulate removal device. This report describes work completed on the four technical program tasks: Thermodynamic projections; Getter Selection and Qualification; System Performance Projections; and Program Definition for Concept Scale-up during the 27-month contract performance period. Work completed on the thermodynamic projections includes a data base update, development of alkali phase diagrams, and system performance projections. Getter selection and qualification efforts involved over 70 kinetic studies in which a leading candidate getter - emathlite - was selected and characterized. System performance projections identified a packed-bed configuration containing relatively large getter pellets as the preferred contacting device for a full-scale unit. For emathlite, we concluded that full-scale unit bed heights of 2 m or less would be required if we assume annual replacement on the basis of bed saturation capacity. Concept scale-up work involved defining the hardware and test program requirements for further development of the emathlite packed-bed system. 56 references, 80 figures, 74 tables.

  7. Undergraduate technical skills training guided by student tutors – Analysis of tutors' attitudes, tutees' acceptance and learning progress in an innovative teaching model

    Directory of Open Access Journals (Sweden)

    Jünger Jana

    2008-04-01

    Full Text Available Abstract Background Skills labs provide a sheltered learning environment. As close supervision and individual feedback were proven to be important in ensuring effective skills training, we implemented a cross-year peer tutor system in our skills lab of internal medicine that allowed intense training sessions with small learning groups (3–4 students taught by one student tutor. Methods The expectations, experiences and criticisms of peer tutors regarding the tutor system for undergraduate skills lab training were investigated in the context of a focus group. In addition, tutees' acceptance of this learning model and of their student tutors was evaluated by means of a pre/post web-based survey. Results 14 voluntary senior students were intensely prepared by consultants for their peer tutor activity. 127 students participated in the project, 66.9% of which responded to the web-based survey (23 topics with help of 6-point Likert scale + free comments. Acceptance was very high (5.69 ± 0.07, mean ± SEM, and self-confidence ratings increased significantly after the intervention for each of the trained skills (average 1.96 ± 0.08, all p Conclusion This study demonstrates that peer teaching in undergraduate technical clinical skills training is feasible and widely accepted among tutees, provided that the tutors receive sufficient training and supervision.

  8. ALKALI RESISTANT CATALYST

    DEFF Research Database (Denmark)

    2008-01-01

    The present invention concerns the selective removal of nitrogen oxides (NOx) from gasses. In particular, the invention concerns a process, a catalyst and the use of a catalyst for the selective removal of nitrogen oxides in the presence of ammonia from gases containing a significant amount...... of alkali metal and/or alkali-earth compounds which process comprises using a catalyst combined of (i) a formed porous superacidic support, said superacidic support having an Hammett acidity stronger than Ho=-12, and (ii) a metal oxide catalytic component deposited on said superacidic support selected from...

  9. Deactivation by carbon of iron catalysts for indirect liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Bartholomew, C.H.

    1990-10-29

    This report describes recent progress in a fundamental, three-year investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for synthesis, the objectives of which are: determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation over a range of CO concentrations, CO:H{sub 2} ratios, and temperatures; model the rates of deactivation of the same catalysts in fixed-bed reactors. During the fourteenth quarter design of software for a computer-automated reactor system to be used in the kinetic and deactivation studies was continued. Further progress was made toward the completion of the control language, control routines, and software for operating this system. Progress was also made towards testing of the system hardware and software. 47 refs.

  10. Development & testing of industrial scale, coal fired combustion system, phase 3. Eighth quarterly technical progress report, 1 October, 1993--31 December, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Zauderer, B.

    1994-01-31

    The primary objective of the present Phase 3 effort is to perform the final testing at a 20 MMBtu/hr commercial scale of an air cooled, slagging coal combustor for application to industrial steam boilers and power plants. The focus of the test effort will be on combustor durability, automatic control of the combustor`s operation, and optimum environmental control of emissions inside the combustor. In connection with the latter, the goal is to achieve 0.4 lb/MMBtu of SO{sub 2} emissions, 0.2 lb/MMBtu of NO{sub x} emissions, and 0.02 lb particulates/MMBtu. Meeting the particulate goal will require the use of a baghouse or electrostatic precipitator to augment the nominal slag retention in the combustor. The NO{sub x} emission goal will require a modest improvement over maximum reduction achieved to date in the combustor to a level of 0.26 lb/MMBtu. To reach the SO{sub 2} emissions goal may require a combination of sorbent injection inside the combustor and sorbent injection inside the boiler, especially in high (>3.5%) sulfur coals. Prior to the initiation of the project, SO{sub 2} levels as low as 0.6 lb/MMBtu, equal to 81% reduction in 2% sulfur coals, were measured with boiler injection of calcium hydrate. The final objective is to define suitable commercial power or steam generating systems to which the use of the air cooled combustor offers significant technical and economic benefits. In implementing this objective both simple steam generation and combined gas turbine-steam generation systems will be considered.

  11. Engineering development of advanced coal-fired low-emission boiler systems. Technical progress report No. 10, January 1995--March 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-17

    The project is on schedule and under budget. The current status is shown in the Milestone Schedule Report included as Appendix A. All Project Plans were updated based on the revised finding level authorized for FY95 and anticipated for FY96. Technology Transfer activities included {open_quotes}supplying{close_quotes} three executives and several team members to the LEBS Workshop, delivering a technical paper at a conference, and working on a Combustion 2000 Session for another conference. ABBES and CeraMem reached agreement concerning Task 7 work, including ownership and disposition of project-purchased equipment to be used during Task 7 and also during Task 11. A test plan was prepared. Task 7 activities for the Low-NO{sub x} Firing System included computational modeling of the firing arrangement. Reasonable comparisons to experimental data previously obtained in the Boiler Simulation Facility were achieved. A kinetic evaluation for both baseline and low NO{sub x} firing arrangements was also performed, with results indicating that the final reducing zone within the main windbox has a dominant effect on NO{sub x} reduction, with higher temperatures being more favorable for lower NO{sub x}. A week of combustion testing was completed in the Fundamental Scale Burner Facility to examine the impact of integrated fuel staging (NO{sub x} reduction via the reburn mechanism), and to explore preliminary vertical staging concepts within the main windbox region. Preliminary results from this testing demonstrated the potential of vertical air staging within the main windbox to augment overfire air. Testing was performed to quantify the coal size distribution and power requirements for one (1) conventional static and four (4) dynamic classifier designs. Results from this testing show the dynamic classifier capable of producing finer grinds of coal at lower relative power requirements.

  12. Research Progress on Denitrification Catalysts for Low Temperature Coal Tar Hydrogenation%中低温煤焦油加氢脱氮催化剂研究进展

    Institute of Scientific and Technical Information of China (English)

    陈繁荣; 杨军

    2015-01-01

    详细介绍了煤焦油加氢技术,将现有煤焦油加氢转化技术划分为轻组分加氢,脱酚加氢,加氢裂化-加氢改质和全馏分加氢四种,分别介绍了每种技术的工艺流程特点和发展状况。阐述了国内外加氢催化剂研究进展,分析了催化剂中活性金属、载体和助剂的种类及对催化剂性能的影响;结合煤焦油加氢催化特点,展望了加氢脱氮催化剂的研究方向,旨在为煤焦油加氢催化剂研究提供一定的理论依据。%The domestic hydro - conversion technologies of coal tar were inwestigated, all technologies were divided into 4 species, such as i. e. hydrofing of light fraction oil, hydrofing of phenol removal fraction oil, oil hydrogenation cracking-hydrogenation modification of oil and hydrofing of whole fraction oil. The process flow and actuality of each species were described separately. The research status of the sulfides of the metals as the active components of the catalysts were introduced and the influences of the type and the active mental, carrier and promoter were described. Combining with the characteristics of catalytic hydrogenation of coal tar, the research direction of denitrification catalysts was prospected. Some theoretical guidance for the research ( design) of coal tar hydro -refining catalyst was provided.

  13. Catalyst for microelectromechanical systems microreactors

    Energy Technology Data Exchange (ETDEWEB)

    Morse, Jeffrey D. (Martinez, CA); Sopchak, David A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA); Reynolds, John G. (San Ramon, CA); Satcher, Joseph H. (Patterson, CA); Gash, Alex E. (Brentwood, CA)

    2011-11-15

    A microreactor comprising a silicon wafer, a multiplicity of microchannels in the silicon wafer, and a catalyst coating the microchannels. In one embodiment the catalyst coating the microchannels comprises a nanostructured material. In another embodiment the catalyst coating the microchannels comprises an aerogel. In another embodiment the catalyst coating the microchannels comprises a solgel. In another embodiment the catalyst coating the microchannels comprises carbon nanotubes.

  14. Catalyst for microelectromechanical systems microreactors

    Science.gov (United States)

    Morse, Jeffrey D.; Sopchak, David A.; Upadhye, Ravindra S.; Reynolds, John G.; Satcher, Joseph H.; Gash, Alex E.

    2010-06-29

    A microreactor comprising a silicon wafer, a multiplicity of microchannels in the silicon wafer, and a catalyst coating the microchannels. In one embodiment the catalyst coating the microchannels comprises a nanostructured material. In another embodiment the catalyst coating the microchannels comprises an aerogel. In another embodiment the catalyst coating the microchannels comprises a solgel. In another embodiment the catalyst coating the microchannels comprises carbon nanotubes.

  15. 苯部分加氢制环己烯钌基催化剂研究进展%Progress in Ru-based catalysts for partial hydrogenation of benzene to cyclohexene

    Institute of Scientific and Technical Information of China (English)

    刘有鹏; 孙国方; 高鹏; 费亚南; 赵甲; 郑修新; 李孝国; 于海斌

    2015-01-01

    环己烯是重要的化工原料及中间体,广泛应用于合成纤维及其他工业领域。介绍了苯部分加氢制环己烯的技术路线,该技术路线具有安全环保和节能高效的特点,其中,催化反应体系是该技术的关键要素。重点概述了近年来对液相苯部分加氢催化体系中钌基催化剂的研究,包括催化剂前驱体、催化剂制备方法、载体、助催化剂以及添加剂对催化剂性能和产物选择性等的影响。介绍了已工业化的旭化成和神马集团的苯部分加氢工艺。环己烯的市场前景广阔,苯部分加氢工艺是一条经济效益高的工艺路线,实现催化体系的突破对于该工艺至关重要,但存在催化剂成本高、易失活和环己烯收率低的问题。%As an important chemical raw material and intermediate,cyclohexene is widely used in syn-thetic fiber industry and other industrial sectors. A route of partial hydrogenation of benzene to cyclohex-ene was introduced,which was safe,green,efficient and energy-saving. Catalyst system was the key factor in the route. The research on Ru-based catalysts for liquid-phase partial hydrogenation of benzene in recent years was reviewed,including the influence of precursors,preparation methods,supports,promoters and additives on catalyst activity and the selectivity to the products. The commercial technologies of partial hydrogenation of benzene of Asahi Kasei Corporation and Shenma Group were introduced. The market prospect of cyclohexene is prosperous. The partial hydrogenation process of benzene is a route of high eco-nomic benefit. It is crucial for the catalytic technology to make breakthroughs. But there exists the prob-lems of high cost and easy inactivation of catalyst,and low cyclohexene yield.

  16. Epoxidation catalyst and process

    Science.gov (United States)

    Linic, Suljo; Christopher, Phillip

    2010-10-26

    Disclosed herein is a catalytic method of converting alkenes to epoxides. This method generally includes reacting alkenes with oxygen in the presence of a specific silver catalyst under conditions suitable to produce a yield of the epoxides. The specific silver catalyst is a silver nanocrystal having a plurality of surface planes, a substantial portion of which is defined by Miller indices of (100). The reaction is performed by charging a suitable reactor with this silver catalyst and then feeding the reactants to the reactor under conditions to carry out the reaction. The reaction may be performed in batch, or as a continuous process that employs a recycle of any unreacted alkenes. The specific silver catalyst has unexpectedly high selectivity for epoxide products. Consequently, this general method (and its various embodiments) will result in extraordinarily high epoxide yields heretofore unattainable.

  17. Photovoltaic manufacturing technology monolithic amorphous silicon modules on continuous polymer substrates. Annual technical progress report, July 5, 1996--December 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Jeffrey, F. [Iowa Thin Film Technologies, Inc., Ames, IA (United States)

    1998-08-01

    Iowa Thin Film Technologies, Inc.`s (ITF) goal is to develop the most cost effective PV manufacturing process possible. To this end the authors have chosen a roll based manufacturing process with continuous deposition and monolithic integration. Work under this program is designed to meet this goal by improving manufacturing throughput and performance of the manufactured devices. Significant progress was made during Phase 2 of this program on a number of fronts. A new single pass tandem deposition machine was brought on line which allows greatly increased and improved throughput for rolls of tandem material. The TCO deposition process was improved resulting in an increase in throughput by 20%. A new alignment method was implemented on the printing process which improves throughput six fold while improving alignment from 100 {micro}m to 10 {micro}m. A roll based lamination procedure was developed and implemented on selected products which improves throughput from 20 sq. ft./hr. to 240 sq. ft./hr. A wide range of lower cost encapsulants were evaluated. A promising material was selected initially to be introduced in 5 year lifetime type products. The sum of these improvements bring the overall cost reduction resulting from this program to 49%.

  18. Chemical activation of molecules by metals: Experimental studies of electron distributions and bonding. Technical progress report, March 1, 1992--February 28, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Lichtenberger, D.L.

    1997-06-01

    During this period of the project we have (1) accomplished the high-resolution gas phase photoelectron spectra of C{sub 60} and C{sub 70}, (2) characterized the electronic features of imaging C{sub 60} on gold by STM, (3) evaluated the orbital distributions of C{sub 60} and the bonding interactions with metals, (4) revealed details of the bonding of phosphines to metals, including the subtleties of a geometrical twist in sterically crowded situations, (5) determined the formal electron distribution in the bonding of {eta}{sup 3} -cyclopropenyl with metals, (6) related gas-phase ionization energies to electron transfer kinetics and ion salvation thermochemistry of metallocenes, (7) correlated lone-pair ionization energies with proton affinities for a variety of amino acids and related compounds, (8) examined sigma-pi interactions in non-conjugated polyalkynes, (9) characterized extensive metal-ligand {pi} interactions in metal-acetylide compounds, and (10) continued to develop the experimental and theoretical methods for these studies. All of these studies have contributed significantly to expanding our understanding of the electronic structure and bonding of organic molecules and the ways this electronic structure is altered by interaction with metals. Further developments in the instrumentation and methods of gas phase and surface photoelectron spectroscopy are underway. Most notable is the progress on the new gas phase photoelectron spectrometer that combines improved capabilities for He I/He II UPS, XPS, and Auger investigations of organometallic molecules.

  19. Research and development of methods/utilities and rules for managing cooperation for performance improvement in government offices. First technical progress report, September 1, 1991--August 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-01

    On September 1, 1991, Defense Programs (DP) within the US Department of Energy entered into a research grant with Management Systems Laboratories (MSL) of Virginia Polytechnic Institute and State University (Virginia Tech), to study Tools, Methods, and Rules for Managing Cooperation for Performance Improvement. Continuous performance improvement is a gradual, systematic process. The idea is to do a little better each day by knowing where you are, where you want to be, what you have to do to get there, whether or not you have done it, and how to resolve problems doing it. And, although many management decisions are made along direct lines of authority, much of the work of an organization can be achieved only through cooperation (people sharing information and coordinating effort). Therefore, continuous performance improvement requires working cooperatively to do a little better each day. We are researching the most effective configuration of tools working through what we believe is a closed set of nine methods. These methods are: setting expectations, charting, defining indicators and standards, collecting and logging data, converting data to information, organizing and presenting information, reviewing status and progress, self-management, and appraising. We believe that these methods form a closed set because they reflect the management activities of formulation (planning),execution (doing), and verification (evaluating). If these activities are carried out effectively through the methods, the manager can achieve visibility and control.

  20. Development of innovative techniques and principles that may be used as models to improve plant performance. Technical progress report, February 1, 1990--January 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Hanna, W.W.; Burton, G.W.

    1992-06-01

    Methods and techniques for transferring germplasm from wild to cultivated species are being developed. The transferred germplasm is being shown to be valuable in plant breeding and in cultivar development. In the primary gene pool of the grassy Pennisetum glaucum subspecies monodii germplasm, some cytoplasms are being identified that appear to have significant effects on forage yields and morphological characteristics. One cytoplasm, A{sub 4}, is very stable for male sterility and fertility is not easily restored by other lines. It should be a valuable cytoplasm for producing commercial forage hybrids. Disease resistance and yield genes transferred from monodii to cultivated pearl millet lines are having a major impact on increasing production of animals grazing disease resistant Tifleaf 2 pearl millet. Genes controlling resistance to many of the world-wide diseases on pearl millet are being identified in the monodii germplasm. Valuable germplasm has been transferred from the secondary gene pool P. purpuroum) which is used as the pollinator of the first pearl millet grain hybrid in the US Production of 7-chromosome gametes in 42-chromosome interspecific hybrids appears to be genotype specific and makes possible transfer of germplasm from the secondary gene pool to cultivated diploid pearl millet. Significant progress has been made in transferring genes controlling apomixis from P. squamulatum (tertiary gene pool) to cultivated pearl millet. Highly apomictic BC{sub 4} plants have been recovered, one of which sets five times as much seed as the best BC{sub 3} plant.