WorldWideScience

Sample records for catalyst packing mode

  1. Packing mode and optimization of flotation column

    Energy Technology Data Exchange (ETDEWEB)

    Li Yan-feng; Zhang Min; Liu Jiong-tian [University of Mining and Technology, Xuzhou (China). School of Chemical Engineering and Technology

    2008-04-15

    The effects of the two usual packing types, namely filling material and sieve plates, on flotation environment were analyzed and it was pointed out that sieve plate filling could be integrated with the fluid regime and mineralization environment with the results of stabilizing bubbles and enhancing the efficiencies of flotation and mineralization. The tests show that the ash gradient of the flotation column increases from 1.62%/m to 6.80%/m as a result of sieve plate filling. Material filling can clean the froth, reduce the ash of clean coal and make the froth steady. To form the two non-linear-change separation environments suitable for mineral separation, the mixed filling mode of packing sieve plates in the middle and lower parts of the column and packing material in the foam area was proposed. By optimizing the packing mode, the mixed packing mode of the sieve plates and honeycomb tubes were introduced. The simulation results show that obligatory suppression of the honeycomb tubes make the radial distribution of the fluid at the second sieve plate completely disappear and the axial velocity stable. It makes the flow regime transfers from turbulent flow to plug flow in a short distance come true. 7 refs., 5 figs., 2 tabs.

  2. Catalyst design for the growth of highly packed nanotube forests

    Energy Technology Data Exchange (ETDEWEB)

    Esconjauregui, Santiago; Fouquet, Martin; Bayer, Bernhard C.; Robertson, John [Engineering Department, University of Cambridge, CB2 1PZ Cambridge (United Kingdom); Ducati, Caterina [Materials Science Department, University of Cambridge, CB2 3QZ Cambridge (United Kingdom)

    2011-11-15

    We report a technique for the design of high-density catalyst nanoparticles (NPs) which allow the growth of highly packed forests of carbon nanotubes (CNTs). The technique consists of cycles of deposition and annealing of thin metal films, followed by NP immobilisation. This allows a CNT areal density of at least 10{sup 13} cm{sup -2}. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  3. EFFECTS OF TEMPERATURE AND CATALYST ON OXIDATION OF AQUEOUS CYANIDES IN PACKED COLUMNS

    OpenAIRE

    Ahmet ALICILAR; MURATHAN, Atilla

    2000-01-01

    The oxidation of aqueous cyanides in packed columns has been studied. The experiment was performed in three different temperatures on inert packing at co- and counter-current conditions. In addition to this, experiments made on room temperature were repeated in the presence of catalyst. After reaching to steady state in each case, cyanide concentrations of liquid samples taken from the column outlet were titrimetrically determined. Oxidation yields were calculated by comparing these values to...

  4. Elastic moduli and vibrational modes in jammed particulate packings

    Science.gov (United States)

    Mizuno, Hideyuki; Saitoh, Kuniyasu; Silbert, Leonardo E.

    2016-06-01

    When we elastically impose a homogeneous, affine deformation on amorphous solids, they also undergo an inhomogeneous, nonaffine deformation, which can have a crucial impact on the overall elastic response. To correctly understand the elastic modulus M , it is therefore necessary to take into account not only the affine modulus MA, but also the nonaffine modulus MN that arises from the nonaffine deformation. In the present work, we study the bulk (M =K ) and shear (M =G ) moduli in static jammed particulate packings over a range of packing fractions φ . The affine MA is determined essentially by the static structural arrangement of particles, whereas the nonaffine MN is related to the vibrational eigenmodes. We elucidate the contribution of each vibrational mode to the nonaffine MN through a modal decomposition of the displacement and force fields. In the vicinity of the (un)jamming transition φc, the vibrational density of states g (ω ) shows a plateau in the intermediate-frequency regime above a characteristic frequency ω*. We illustrate that this unusual feature apparent in g (ω ) is reflected in the behavior of MN: As φ →φc , where ω*→0 , those modes for ω ω* approach a constant value which results in MN to approach a critical value MN c, as MN-MN c˜ω* . At φc itself, the bulk modulus attains a finite value Kc=KA c-KN c>0 , such that KN c has a value that remains below KA c. In contrast, for the critical shear modulus Gc, GN c and GA c approach the same value so that the total value becomes exactly zero, Gc=GA c-GN c=0 . We explore what features of the configurational and vibrational properties cause such a distinction between K and G , allowing us to validate analytical expressions for their critical values.

  5. New proposition on performance evaluation of hydrophobic Pt catalyst packed in trickle bed

    International Nuclear Information System (INIS)

    On the evaluation of the performance of the hydrophobic Pt catalyst packed in the trickle-bed test column, the conventionally defined (Ksub(y)a) and the newly defined (Ksub(f))sub (G) are compared with each other as a measure of the overall D-transfer coefficient. The value of (Ksub(y)a) varies in a wide range in accordance with the length of the test column. On the other hand (Ksub(f))sub (G sub (l = L)) has a finite value in the test column longer than about 0.5 m. By considering the values of ksub(g) and ksub(l) which are the constituents of (Ksub(f))sub (G), it is possible to improve the hydrophobic Pt catalyst trickle bed and to design the H2/H2O-isotopic exchange trickle-bed column packed with this catalyst. (author)

  6. Periodic Packing Mode for Trickle-Bed Reactors:Experiments and Modeling

    Institute of Scientific and Technical Information of China (English)

    刘国柱; 米镇涛

    2004-01-01

    A periodic packing mode of trickle-bed reactor (TBR) for the gas limited reaction was proposed. Hydrogenation of 2-ethylanthraquinone over Pd/A12Oa in a laboratory-scale TBR was taken as a test reaction for determining whether the periodic packing mode is advantageous. The effects of operating conditions and packing type on TBR performance were experimentally examined to demonstrate the cause-effect relationships. A mathematic model of TBR considering axial dispersion and fractional wetting was developed to quantitatively illuminate the reason of performance enhancement.

  7. Catalyst-Packed Non-Thermal Plasma Reactor for Removal of Nitrogen Oxides

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    A single-stage plasma-catalytic reactor in which catalytic materials were packedwas used to remove nitrogen oxides. The packing material was scoria being made of various metaloxides including A12O3, MgO, TiO2, etc. Scoria was able to act not only as dielectric pelletsbut also as a catalyst in the presence of reducing agent such as ethylene and ammonia. Withoutplasma discharge, scoria did not work well as a catalyst in the temperature range of 100 °Cto 200 °C, showing less than 10% of NOx removal efficiency. When plasma is produced inside thereactor, the NOx removal efficiency could be increased to 60% in this temperature range.

  8. Modeling of methanol decomposition on Pt/CeO2/ZrO2 catalyst in a packed bed microreactor

    Science.gov (United States)

    Pohar, Andrej; Belavič, Darko; Dolanc, Gregor; Hočevar, Stanko

    2014-06-01

    Methanol decomposition on Pt/CeO2/ZrO2 catalyst is studied inside a packed bed microreactor in the temperature range of 300-380 °C. The microreactor is fabricated using low-temperature co-fired ceramic (LTCC) technology, which is well suited for the production of relatively complex three-dimensional structures. It is packed with 2 wt% Pt-CeO2 catalyst, which is deposited onto ZrO2 spherical particles. A 1D mathematical model, which incorporates diffusion, convection and mass transfer through the boundary layer to the catalyst particles, as well as a 3D computational fluid dynamics model, are developed to describe the methanol decomposition process inside the packed bed. The microreactor exhibits reliable operation and no catalyst deactivation was observed during three months of experimentation. A comparison between the 1D mathematical model and the 3D model, considering the full 3D geometry of the microreactor is made and the differences between the models are identified and evaluated.

  9. Investigation of hydrodynamic behavior of a pilot-scale trickle bed reactor packed with hydrophobic catalyst using radiotracer technique

    International Nuclear Information System (INIS)

    Exchange of isotopes of hydrogen between aqueous phase and hydrogen gas is one of the most efficient methods for separation of hydrogen isotopes and is commonly used for production of heavy water or removal of tritium from tritiated water effluents. The isotope exchange reaction can be effectively executed in a counter-current trickle bed reactor (TBR) packed with a novel metal (Pt, Pd, Ni) based hydrophobic catalyst as the conventional novel metal based hydrophilic catalysts become ineffective after they come in contact with liquid effluents. The overall exchange reaction in the TBR mainly consists of a gas-liquid mass transfer process that transfers reactants from liquid to gaseous phase followed by an isotopic exchange reaction between the reactants in gaseous phase in presence of a solid hydrophobic catalyst. However, due to water repellent nature of the catalyst, poor liquid distribution in the reactor is normally observed that deteriorates the gas-liquid mass transfer. Therefore, it was thought that if a mixture of hydrophobic catalyst and a suitable hydrophilic mass transfer packing is used to fill the TBR column then, it can improve the distribution or mixing of the liquid and gas phase and thus improve the gas-liquid mass transfer and overall performance of the reactor and needs to be confirmed

  10. Super-radiant plasmon mode is more efficient for SERS than the sub-radiant mode in highly packed 2D gold nanocube arrays

    International Nuclear Information System (INIS)

    The field coupling in highly packed plasmonic nanoparticle arrays is not localized due to the energy transport via the sub-radiant plasmon modes, which is formed in addition to the regular super-radiant plasmon mode. Unlike the sub-radiant mode, the plasmon field of the super-radiant mode cannot extend over long distances since it decays radiatively with a shorter lifetime. The coupling of the plasmon fields of gold nanocubes (AuNCs) when organized into highly packed 2D arrays was examined experimentally. Multiple plasmon resonance optical peaks are observed for the AuNC arrays and are compared to those calculated using the discrete dipole approximation. The calculated electromagnetic plasmon fields of the arrays displayed high field intensity for the nanocubes located in the center of the arrays for the lower energy super-radiant mode, while the higher energy sub-radiant plasmon mode displayed high field intensity at the edges of the arrays. The Raman signal enhancement by the super-radiant plasmon mode was found to be one hundred fold greater than that by sub-radiant plasmon mode because the super-radiant mode has higher scattering and stronger plasmon field intensity relative to the sub-radiant mode

  11. Super-radiant plasmon mode is more efficient for SERS than the sub-radiant mode in highly packed 2D gold nanocube arrays

    Energy Technology Data Exchange (ETDEWEB)

    Mahmoud, Mahmoud A., E-mail: mmahmoud@gatech.edu [Laser Dynamics Laboratory, School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332-0400 (United States)

    2015-08-21

    The field coupling in highly packed plasmonic nanoparticle arrays is not localized due to the energy transport via the sub-radiant plasmon modes, which is formed in addition to the regular super-radiant plasmon mode. Unlike the sub-radiant mode, the plasmon field of the super-radiant mode cannot extend over long distances since it decays radiatively with a shorter lifetime. The coupling of the plasmon fields of gold nanocubes (AuNCs) when organized into highly packed 2D arrays was examined experimentally. Multiple plasmon resonance optical peaks are observed for the AuNC arrays and are compared to those calculated using the discrete dipole approximation. The calculated electromagnetic plasmon fields of the arrays displayed high field intensity for the nanocubes located in the center of the arrays for the lower energy super-radiant mode, while the higher energy sub-radiant plasmon mode displayed high field intensity at the edges of the arrays. The Raman signal enhancement by the super-radiant plasmon mode was found to be one hundred fold greater than that by sub-radiant plasmon mode because the super-radiant mode has higher scattering and stronger plasmon field intensity relative to the sub-radiant mode.

  12. Effect of Temperature Gradient Direction in the Catalyst Nanoparticle on CNTs Growth Mode

    Directory of Open Access Journals (Sweden)

    Liu Shang-Bin

    2010-01-01

    Full Text Available Abstract To improve the understanding on CNT growth modes, the various processes, including thermal CVD, MP-CVD and ECR-CVD, have been used to deposit CNTs on nanoporous SBA-15 and Si wafer substrates with C2H2 and H2 as reaction gases. The experiments to vary process parameter of ΔT, defined as the vector quantities of temperature at catalyst top minus it at catalyst bottom, were carried out to demonstrate its effect on the CNT growth mode. The TEM and TGA analyses were used to characterize their growth modes and carbon yields of the processes. The results show that ΔT can be used to monitor the temperature gradient direction across the catalyst nanoparticle during the growth stage of CNTs. The results also indicate that the tip-growth CNTs, base-growth CNTs and onion-like carbon are generally fabricated under conditions of ΔT > 0, <0 and ~0, respectively. Our proposed growth mechanisms can be successfully adopted to explain why the base- and tip-growth CNTs are common in thermal CVD and plasma-enhanced CVD processes, respectively. Furthermore, our experiments have also successfully demonstrated the possibility to vary ΔT to obtain the desired growth mode of CNTs by thermal or plasma-enhanced CVD systems for different applications.

  13. The unusual thermochromic NIR luminescence of Cu(I) clusters: tuned by Cu-Cu interactions and packing modes.

    Science.gov (United States)

    Shan, Xiao-Chen; Jiang, Fei-Long; Yuan, Da-Qiang; Wu, Ming-Yan; Zhang, Shu-Quan; Hong, Mao-Chun

    2012-08-21

    Two hexanuclear Cu(I) clusters [Cu(I)(3)(4-ptt)(3)](2)·3DMF·3H(2)O (1) and [Cu(I)(4-ptt)](6)·8DMF·7H(2)O (2) (4-Hptt = 5-(pyridin-4-yl)-1H-1,2,4-triazole-3-thiol, DMF = N,N-dimethylformamide), were synthesized and characterized. Compounds 1 and 2 with similar coordination environments are isomers, but their detailed structures are different due to the reaction temperature tuning effect. Both 1 and 2 extend from monomers to 3D supramolecules with the help of hydrogen bonding between the triazole and pyridine from the 4-ptt ligands. The Cu(6)S(6) units of 1 pack in a polydirectional array, while the Cu(6)S(6) units in 2 extend in one direction and link the planes of adjacent ligands to enhance the delocalization of π electrons. Their varied Cu-Cu interactions and individual packing modes cause differences in luminescent and thermostable behaviors. Compound 1 exhibits an unusually long wavelength at about 900 nm and a higher thermal stability; while the emission of 2 splits into two bands (high-energy and low-energy emission bands) as the temperature decreases. Therefore, the emissions of 1 originate from a (3)CC transition, and those of 2 are from a mixture of (3)CC and MLCT. PMID:22740116

  14. Periodic Packing Mode for Trickle-Bed Reactors:Experiments and Modeling%滴流反应器的周期性填充:实验与模拟

    Institute of Scientific and Technical Information of China (English)

    刘国柱; 米镇涛

    2004-01-01

    A periodic packing mode of trickle-bed reactor(TBR)for the gas limited reaction was proposed.Hydrogenation of 2-ethylanthraquinone over Pd/Al2O3 in a laboratory-scale TBR was taken as a test reaction for determining whether the periodic packing mode is advantageous.The effects of operating conditions and packing type on TBR performance were experimentally examined to demonstrate the cause-effect relationships.A mathematic model of TBR considering axial dispersion and fractional wetting was developed to quantitatively illuminate the reason of performance enhancement.

  15. Demand Planning of Electric Vehicle Battery Pack Under Battery Swapping Mode%换电模式下电动汽车电池组需求规划

    Institute of Scientific and Technical Information of China (English)

    高赐威; 吴茜; 薛飞; 刘红超

    2013-01-01

      针对“集中充电、统一配送”模式下的电池数量规划问题展开研究,根据原始可用信息和规划目标要求的不同,分为远期与近期2个规划阶段,并对该问题进行建模,形成涵盖多阶段的电池数量综合规划模型。首先进行远期规划,根据电动汽车运行的相关统计参数初步估算集中型充电站最多需要购买的电池组数量,从而为近期规划提供指导。然后,近期规划基于最大日换电需求预测曲线,根据一定的物流配送原则确定日配送次数及物流能力,最终获得集中型充电站的近期规划电池组数量。算例分析表明,换电曲线的方差越小,则电池配比率越低,充裕度越高。此外,物流配送方案对电池组数量规划的影响至关重要,是影响电池组数量的关键因素。%  The electric vehicles (EV) battery pack quantity planning under the mode of centralized charging and unified distribution is researched. According to the differences between original usable information and the demand of planning objectives, the planning is divided into plannings for two stages, namely the near-term planning and the long-term planning, and corresponding models are established to form a comprehensive EV battery pack quantity planning model covering multi stages. Firstly, the long-term planning is performed, which preliminary estimates the most battery pack quantity that the centralized charging station should purchase according to relevant statistical parameters of EV operation to provide guidance for the near-term planning; secondly, based on the forecasted curve of maximum daily charging demand the near-term planning decides daily distribution times and logistics capability according to a certain logistics distribution principle;finally the EV battery pack quantity of the centralized charging station in the near-term planning is attained. Case study results show that the smaller the

  16. New improved hydrophobic Pt-catalyst for hydrogen isotope separation

    International Nuclear Information System (INIS)

    This paper presents the studies on preparation methods and applications of the hydrophobic catalysts in deuterium and tritium separation. The objectives of the paper are: (1) to provide a database for selection of the most appropriate catalyst and catalytic packing for above mentioned processes; (2) to evaluate the potentiality of hydrophobic Pt-catalysts in the deuterium and tritium separation; (3) to assess and to find a new procedure for preparation of a new improved hydrophobic catalyst. Unlike the conventional hydrophilic catalysts, the hydrophobic catalysts maintain a high catalytic activity and stability even under the direct contact to liquid water or in the presence of saturated humidity. A large diversity of catalyst types (over 100 catalysts) was prepared and tested for hydrogen isotope separation. The impregnation modes, the type of precursor of active metal, conditions of reduction and waterproofing methods are in detail analysed. As result of this assessment, platinum appears to be the most active catalytic metal and TEFLON is the most hydrophobic agent. A method for preparation of new improved hydrophobic Pt-catalysed has been proposed. The main steps and experimental conditions are largely discussed. The advantages of the hydrophobic catalysts are shown in comparison to hydrophilic catalysts. Some suggestions concerning the deuterium and tritium enrichment by means of hydrophobic catalysts are also discussed.The extension of hydrophobic Pt-catalysts' applications in environmental field is proposed. (author)

  17. Optimal Switching Table-Based Sliding Mode Control of an Energy Recovery Li-Ion Power Accumulator Battery Pack Testing System

    Directory of Open Access Journals (Sweden)

    Kil To Chong

    2013-10-01

    Full Text Available The main objective of the present work is to apply a sliding mode controller (SMC to medium voltage and high power output energy recovery Li-ion power accumulator battery pack testing systems (ERLPABTSs, which are composed of a three-level neutral-point-clamped (NPC three-phase voltage source inverter (VSI and a two-level buck-boost converter without an isolating transformer. An inner current decoupled control scheme for the aforementioned system is proposed and two sliding mode planes for active and reactive current control are designed based on the control scheme. An optimized switching table for current convergence is used according to the error sign of the equivalent input voltage and feedback voltage. The proposed ERLPABTS could be used to integrate discharging energy into the power grid when performing high accuracy current testing. The active and reactive power references for the grid-connected inverter are determined based on the discharging energy from the DC-DC converter. Simulations and experiments on a laboratory hardware platform using a 175 kW insulated gate bipolar transistor (IGBT-based ERLPABTS have been implemented and verified, and the performance is found satisfactory and superior to conventional ERLPABPTS.

  18. Supported Tetrahedral Oxo-Sn Catalyst: Single Site, Two Modes of Catalysis

    Energy Technology Data Exchange (ETDEWEB)

    Beletskiy, Evgeny V.; Hou, Xianliang; Shen, Zhongliang; Gallagher, James R.; Miller, Jeffrey T.; Wu, Yuyang; Li, Tiehu; Kung, Mayfair C.; Kung, Harold H.

    2016-03-17

    Mild calcination in ozone of a (POSS)-Sn- (POSS) complex grafted on silica generated a heterogenized catalyst that mostly retained the tetrahedral coordination of its homogeneous precursor, as evidenced by spectroscopic characterizations using EXAFS, NMR, UV-vis, and DRIFT. The Sn centers are accessible and uniform and can be quantified by stoichiometric pyridine poisoning. This Sn-catalyst is active in hydride transfer reactions as a typical solid Lewis acid. However, the Sn centers can also create Brønsted acidity with alcohol by binding the alcohol strongly as alkoxide and transferring the hydroxyl H to the neighboring Sn-O-Si bond. The resulting acidic silanol is active in epoxide ring opening and acetalization reactions.

  19. Power Packing

    Centers for Disease Control (CDC) Podcasts

    2011-08-16

    In this podcast for kids, the Kidtastics talk about how to pack a lunch safely, to help keep you from getting sick.  Created: 8/16/2011 by National Center for Emerging and Zoonotic Infectious Diseases (NCEZID).   Date Released: 8/16/2011.

  20. Packing Smart

    Centers for Disease Control (CDC) Podcasts

    2011-08-22

    In this podcast for kids, the Kidtastics talk about packing a lunch that's not boring and is full of the power and energy kids need to make it through the day.  Created: 8/22/2011 by National Center for Emerging and Zoonotic Infectious Diseases (NCEZID).   Date Released: 8/22/2011.

  1. Supramolecular Packing Controls H₂ Photocatalysis in Chromophore Amphiphile Hydrogels.

    Science.gov (United States)

    Weingarten, Adam S; Kazantsev, Roman V; Palmer, Liam C; Fairfield, Daniel J; Koltonow, Andrew R; Stupp, Samuel I

    2015-12-01

    Light harvesting supramolecular assemblies are potentially useful structures as components of solar-to-fuel conversion materials. The development of these functional constructs requires an understanding of optimal packing modes for chromophores. We investigated here assembly in water and the photocatalytic function of perylene monoimide chromophore amphiphiles with different alkyl linker lengths separating their hydrophobic core and the hydrophilic carboxylate headgroup. We found that these chromophore amphiphiles (CAs) self-assemble into charged nanostructures of increasing aspect ratio as the linker length is increased. The addition of salt to screen the charged nanostructures induced the formation of hydrogels and led to internal crystallization within some of the nanostructures. For linker lengths up to seven methylenes, the CAs were found to pack into 2D crystalline unit cells within ribbon-shaped nanostructures, whereas the nine methylene CAs assembled into long nanofibers without crystalline molecular packing. At the same time, the different molecular packing arrangements after charge screening led to different absorbance spectra, despite the identical electronic properties of all PMI amphiphiles. While the crystalline CAs formed electronically coupled H-aggregates, only CAs with intermediate linker lengths showed evidence of high intermolecular orbital overlap. Photocatalytic hydrogen production using a nickel-based catalyst was observed in all hydrogels, with the highest turnovers observed for CA gels having intermediate linker lengths. We conclude that the improved photocatalytic performance of the hydrogels formed by supramolecular assemblies of the intermediate linker CA molecules likely arises from improved exciton splitting efficiencies due to their higher orbital overlap. PMID:26593389

  2. Agro-industrial waste: a low cost adsorbent for effective removal of 4-chloro-2-methylphenoxyacetic acid herbicide in batch and packed bed modes.

    Science.gov (United States)

    Deokar, Sunil K; Mandavgane, Sachin A; Kulkarni, Bhaskar D

    2016-08-01

    The present work describes the aqueous phase removal of 4-chloro-2-methylphenoxyacetic acid herbicide by rice husk ash (RHA) using batch and packed bed adsorption techniques. The effects of dosage, initial concentration, time, pH, temperature, and particle size of adsorbent in batch compared with effects of influent concentration, flow rate, and bed height in packed bed were studied. The particle size effect reveals that the removal is dependent on chemical composition (silica and carbon content) together with BET surface area of RHA. The aptness of Langmuir isotherm to batch data indicates the favorable adsorption whereas that of Temkin isotherm informs the heterogeneous nature of RHA. The kinetics of adsorption follows the pseudo-second order and Elovich models while thermodynamics of process indicates the exothermic adsorption. Among the models applied in packed bed study, the deactivation kinetic, Yoon-Nelson and bed depth service time (BDST) models are suitable to explain the packed bed adsorption. The adsorption capacity of RHA in packed bed study is found greater than that in batch. The adsorption capacity of RHA determined by the BDST model is 3019 mg/L for 90 % saturation of bed. The adsorption capacity of RHA based on weight is ∼2.3 times and that based on surface area is ∼55.55 times greater than that of granular activated carbon. PMID:27151241

  3. Wolf Pack Algorithm for Unconstrained Global Optimization

    OpenAIRE

    Hu-Sheng Wu; Feng-Ming Zhang

    2014-01-01

    The wolf pack unites and cooperates closely to hunt for the prey in the Tibetan Plateau, which shows wonderful skills and amazing strategies. Inspired by their prey hunting behaviors and distribution mode, we abstracted three intelligent behaviors, scouting, calling, and besieging, and two intelligent rules, winner-take-all generation rule of lead wolf and stronger-survive renewing rule of wolf pack. Then we proposed a new heuristic swarm intelligent method, named wolf pack algorithm (WPA). E...

  4. Effects of hydrophobic carrier and packing on the mass transfer capabilities in hydrogen-water liquid phase catalytic exchange bed

    International Nuclear Information System (INIS)

    Hydrogen-water liquid phase catalytic exchange bed was packed with 'sandwich' layers of the catalyst and the packing, and the effects of catalyst carrier, inert packing and their filled ratio on the overall mass transfer coefficient (Kya) were investigated experimentally. The results show that C-PTFE is suitable for hydrophobic catalyst. Kya of the bed with catalyst-stainless steel mini-spiral packing is better than that with stainless steel θ-packing, and the active Al2O3 is not suitable for the exchange bed. Moreover, if the stainless steel mini-spiral packing is etched in aqua regia, the operating flexibility and overall mass transfer capability of exchange bed are improved notably. The preferable packing ratio (catalyst/packing) is 1:4. (authors)

  5. Thermal modeling of microwave heated packed and fluidized bed catalytic reactors.

    Science.gov (United States)

    Thomas, J R; Faucher, F

    2000-01-01

    Thermal models of small-scale, microwave-heated, packed-bed and fluidized-bed catalytic chemical reactors were developed to investigate the possibility of selectively heating the catalyst sites or the catalyst pellets with microwaves. Results indicate catalyst sites may be selectively heated under special conditions in a packed or fluidized bed, and catalyst pellets may be heated above the temperature of the cooling(and reacting) gas under certain conditions in a fluidized bed. PMID:11098441

  6. Comparison of the activities of binder-added and binder-free Mo/HZSM-5 catalysts in methane dehydroaromatization at 1073 K in periodic CH4-H2 switch operation mode

    Institute of Scientific and Technical Information of China (English)

    Yuebing Xu; Hongtao Ma; Yo Yamamoto; Yoshizo Suzuki; Zhanguo Zhang

    2012-01-01

    Three industry-supplied,well-shaped Mo/HZSM-5 catalysts,two binder-added and one binder-free,were tested for the first time in methane dehydroaromatization to benzene at 1073 K and 10000 mL/(g.h) in periodic CH4-H2 switch operation mode,and their catalytic performances were compared with those of three self-prepared,binder-free powder Mo/HZSM-5 catalysts.XRD,27Al NMR,SEM,BET and NH3-TPD characterizations of all the catalysts show that the zeolites in the two binder-added catalysts are comparable to those in the three binder-free powder catalysts in crystallinity,crystal size,micropore volume and Br(¢)nsted acidity.The test results,on the other hand,show that the catalytic performances of the two binder-added catalysts are worse than those of the four binder-free catalysts on both catalyst mass and zeolite mass bases.Then,TPO and BET measurements of all spent samples were conducted to get a deep insight into the negative effects of binder addition,and the results suggest that the binder additives functioned mainly to enhance the polyaromatization of formed aromatics to coke on their external surfaces and consequently lower the benzene formation activity and selectivity of the catalyst.

  7. The Performance of Structured Packings in Trickle-Bed Reactors

    NARCIS (Netherlands)

    Frank, M.J.W.; Kuipers, J.A.M.; Versteeg, G.F.; Swaaij, W.P.M. van

    1999-01-01

    An experimental study was carried out to investigate whether the use of structured packings might improve the mass transfer characteristics and the catalyst effectiveness of a trickle-bed reactor. Therefore, the performances of a structured packing, consisting of KATAPAK elements, and a dumped packi

  8. The performance of structured packings in trickle-bed reactors.

    NARCIS (Netherlands)

    Frank, M.J.W.; Kuipers, J.A.M.; Versteeg, G.F.; Swaaij, van W.P.M.

    1999-01-01

    An experimental study was carried out to investigate whether the use of structured packings might improve the mass transfer characteristics and the catalyst effectiveness of a trickle-bed reactor. Therefore, the performances of a structured packing, consisting of KATAPAK elements, and a dumped packi

  9. Hydrodynamics of multi-phase packed bed micro-reactors

    NARCIS (Netherlands)

    Márquez Luzardo, N.M.

    2010-01-01

    Why to use packed bed micro-reactors for catalyst testing? Miniaturized packed bed reactors have a large surface-to-volume ratio at the reactor and particle level that favors the heat- and mass-transfer processes at all scales (intra-particle, inter-phase and inter-particle or reactor level). If the

  10. Tunable random packings

    International Nuclear Information System (INIS)

    We present an experimental protocol that allows one to tune the packing fraction η of a random pile of ferromagnetic spheres from a value close to the lower limit of random loose packing ηRLP≅0.56 to the upper limit of random close packing ηRCP≅0.64. This broad range of packing fraction values is obtained under normal gravity in air, by adjusting a magnetic cohesion between the grains during the formation of the pile. Attractive and repulsive magnetic interactions are found to affect stongly the internal structure and the stability of sphere packing. After the formation of the pile, the induced cohesion is decreased continuously along a linear decreasing ramp. The controlled collapse of the pile is found to generate various and reproducible values of the random packing fraction η

  11. Flat Pack Toy Design

    Science.gov (United States)

    Hutcheson, Brian

    2007-01-01

    In this article, the author introduces the concept of flat pack toys. Flat pack toys are designed using a template on a single sheet of letter-sized card stock paper. Before being cut out and built into a three-dimensional toy, they are scanned into the computer and uploaded to a website. With the template accessible from the website, anyone with…

  12. Oxidation catalyst

    Science.gov (United States)

    Ceyer, Sylvia T.; Lahr, David L.

    2010-11-09

    The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

  13. MECHANICAL STRENGTH AND RELIABILITY OF SOLID CATALYSTS

    Institute of Scientific and Technical Information of China (English)

    Yongdan Li; Dongfang Wu; Y.S. Lin

    2004-01-01

    The mechanical strength of solid catalysts is one of the key parameters for reliable and efficient performance of a fixed bed reactor. Some recent developments and their basic mechanics within this context are reviewed. The main concepts discussed are brittle fracture which leads to the mechanical failure of the catalyst pellets, measurement and statistical properties of the catalyst strength data, and mechanical reliability of the catalyst pellets and their packed bed. The scientific basis for the issues on the catalyst mechanical properties calls yet for further elucidation and advancement.

  14. Manufacture of Catalyst Systems for Ammonia Conversion

    Institute of Scientific and Technical Information of China (English)

    GAKH S.V.; SAVENKOV D.A.

    2012-01-01

    Platinum catalyst gauzes have been in use since the moment of development of the process of catalyst oxidation of ammonia for production of nitric acid or hydrocyanic acid.Catalyst gauzes are usually made of platinum or its alloys with rhodium and palladium.These precious metals have remarkable properties that make them ideal catalysts for acceleration of the ammonia/oxygen reaction.In 2008,OJSC "SIC ‘Supermetal’" and Umicore AG&Co.KG launched a production line for Pt-alloy-based catalyst systems to be used for ammonia oxidation in the production of weak nitric acid.Catalyst systems consist of a pack of catalyst gauzes and a pack of catchment gauzes,which are made using flat-bed knitting machines and wire-cloth looms.Today,up-to-date catalyst systems MKSpreciseTM are being manufactured,the basic advantages of which are an individual structure of gauzes and composition of the material,which allows to define precisely the position of each gauze in the catalyst pack,a high activity of the catalyst pack,direct catching of platinum and rhodium in the catalyst system,and a reasonable combination of single- and multilayer types of gauzes.This makes it possible to vary the configuration of the catalyst and select an optimum composition of the system to ensure the maximum efficiency of the ammonia oxidation process.We also produce the catchment systems that allow to find the best decision from the economic point view for each individual case.

  15. Optimal Packed String Matching

    DEFF Research Database (Denmark)

    Ben-Kiki, Oren; Bille, Philip; Breslauer, Dany;

    2011-01-01

    In the packed string matching problem, each machine word accommodates – characters, thus an n-character text occupies n/– memory words. We extend the Crochemore-Perrin constantspace O(n)-time string matching algorithm to run in optimal O(n/–) time and even in real-time, achieving a factor – speedup...... over traditional algorithms that examine each character individually. Our solution can be efficiently implemented, unlike prior theoretical packed string matching work. We adapt the standard RAM model and only use its AC0 instructions (i.e., no multiplication) plus two specialized AC0 packed string...

  16. Nasal packing and stenting

    Directory of Open Access Journals (Sweden)

    Weber, Rainer K.

    2009-01-01

    Full Text Available Nasal packs are indispensable in ENT practice. This study reviews current indications, effectiveness and risks of nasal packs and stents. In endoscopic surgery, nasal packs should always have smooth surfaces to minimize mucosal damage, improve wound healing and increase patient comfort. Functional endoscopic endonasal sinus surgery allows the use of modern nasal packs, since pressure is no longer required. So called hemostatic/resorbable materials are a first step in this direction. However, they may lead to adhesions and foreign body reactions in mucosal membranes. Simple occlusion is an effective method for creating a moist milieu for improved wound healing and avoiding dryness. Stenting of the frontal sinus is recommended if surgery fails to produce a wide, physiologically shaped drainage path that is sufficiently covered by intact tissue.

  17. Optimized packings with applications

    CERN Document Server

    Pintér, János

    2015-01-01

    This volume presents a selection of case studies that address a substantial range of optimized object packings (OOP) and their applications. The contributing authors are well-recognized researchers and practitioners. The mathematical modelling and numerical solution aspects of each application case study are presented in sufficient detail. A broad range of OOP problems are discussed: these include various specific and non-standard container loading and object packing problems, as well as the stowing of hazardous and other materials on container ships, data centre resource management, automotive engineering design, space station logistic support, cutting and packing problems with placement constraints, the optimal design of LED street lighting, robust sensor deployment strategies, spatial scheduling problems, and graph coloring models and metaheuristics for packing applications. Novel points of view related to model development and to computational nonlinear, global, mixed integer optimization and heuristic st...

  18. Layered circle packings

    Directory of Open Access Journals (Sweden)

    David Dennis

    2005-01-01

    Full Text Available Given a bounded sequence of integers {d0,d1,d2,…}, 6≤dn≤M, there is an associated abstract triangulation created by building up layers of vertices so that vertices on the nth layer have degree dn. This triangulation can be realized via a circle packing which fills either the Euclidean or the hyperbolic plane. We give necessary and sufficient conditions to determine the type of the packing given the defining sequence {dn}.

  19. Separation of deuterium by H2/H2O reaction with hydrophobic platinum catalyst

    International Nuclear Information System (INIS)

    The separation performance of a trickle bed exchange column packed with a hydrophobic or waterproof catalyst is related to operating conditions such as hydrogen surface velocity, water flow rate, and temperature. The optimum carrier type and catalyst platinum content were determined. The continuous injection of roughly 103 ppm O2 regenerates the catalyst effectively. The ratio of hydrophobic catalyst to hydrophilic packing is an important factor in increasing the exchange rate in deuterium extraction

  20. Hydrogen gettering packing material and process for making same

    Energy Technology Data Exchange (ETDEWEB)

    LeMay, James D.; Thompson, Lisa M.; Smith, Henry Michael; Schicker, James R.

    1999-09-09

    A hydrogen gettering system for a sealed container is disclosed comprising packing material for use within the sealed container, and a coating film containing hydrogen gettering material on at least a portion of the surface of such packing material. The coating film containing the hydrogen gettering material comprises a mixture of one or more organic materials capable of reacting with hydrogen and one or more catalysts capable of catalyzing the reaction of hydrogen with such one or more organic materials. The mixture of one or more organic materials capable of reacting with hydrogen and the one or more catalysts is dispersed in a suitable carrier which preferably is a curable film-forming material. In a preferred embodiment, the packing material comprises a foam material which is compatible with the coating film containing hydrogen gettering material thereon.

  1. Influence of packing material and method on the efficiency of liquid phase water-hydrogen isotope exchange

    International Nuclear Information System (INIS)

    The influence of packing material in the countercurrent catalytic column on the efficiency of liquid phase water-hydrogen isotope exchange is studied. Stainless steel triangle spring packing demonstrates best performance among the tested three hydrophilic packing materials. Pretreatment of the stainless steel packing lowers the height of a mass transfer unit (HTU) by about 50%. The effectiveness of a catalytic column for water-hydrogen isotope exchange is proved to be higher when the column is packed in layers with hydrophilic packing and hydrophobic catalyst in the volume ratio 1:4

  2. Packing fraction of particles with lognormal size distribution.

    Science.gov (United States)

    Brouwers, H J H

    2014-05-01

    This paper addresses the packing and void fraction of polydisperse particles with a lognormal size distribution. It is demonstrated that a binomial particle size distribution can be transformed into a continuous particle-size distribution of the lognormal type. Furthermore, an original and exact expression is derived that predicts the packing fraction of mixtures of particles with a lognormal distribution, which is governed by the standard deviation, mode of packing, and particle shape only. For a number of particle shapes and their packing modes (close, loose) the applicable values are given. This closed-form analytical expression governing the packing fraction is thoroughly compared with empirical and computational data reported in the literature, and good agreement is found.

  3. Simulation of abuse tolerance of lithium-ion battery packs

    Science.gov (United States)

    Spotnitz, Robert M.; Weaver, James; Yeduvaka, Gowri; Doughty, D. H.; Roth, E. P.

    A simple approach for using accelerating rate calorimetry data to simulate the thermal abuse resistance of battery packs is described. The thermal abuse tolerance of battery packs is estimated based on the exothermic behavior of a single cell and an energy balance than accounts for radiative, conductive, and convective heat transfer modes of the pack. For the specific example of a notebook computer pack containing eight 18650-size cells, the effects of cell position, heat of reaction, and heat-transfer coefficient are explored. Thermal runaway of the pack is more likely to be induced by thermal runaway of a single cell when that cell is in good contact with other cells and is close to the pack wall.

  4. Battery Pack Thermal Design

    Energy Technology Data Exchange (ETDEWEB)

    Pesaran, Ahmad

    2016-06-14

    This presentation describes the thermal design of battery packs at the National Renewable Energy Laboratory. A battery thermal management system essential for xEVs for both normal operation during daily driving (achieving life and performance) and off-normal operation during abuse conditions (achieving safety). The battery thermal management system needs to be optimized with the right tools for the lowest cost. Experimental tools such as NREL's isothermal battery calorimeter, thermal imaging, and heat transfer setups are needed. Thermal models and computer-aided engineering tools are useful for robust designs. During abuse conditions, designs should prevent cell-to-cell propagation in a module/pack (i.e., keep the fire small and manageable). NREL's battery ISC device can be used for evaluating the robustness of a module/pack to cell-to-cell propagation.

  5. DIY Fraction Pack.

    Science.gov (United States)

    Graham, Alan; Graham, Louise

    2003-01-01

    Describes a very successful attempt to teach fractions to year 5 pupils based on pupils making their own fraction pack. Children decided for themselves how to make the fractional slices used in the activity using colored cardboard sheets and templates of a paper circle consisting of 24 equal slices. (Author/NB)

  6. The Six Pack Model

    DEFF Research Database (Denmark)

    Andersen, Henrik; Ritter, Thomas

    Ever seen a growth strategies fail because it was not connect ed to the firm’s customer base? Or a customer relationship strategy falters just because it was the wrong thing to do with that given customer? This article presents the six pack model, a tool that makes growth profitable and predictable...

  7. Mass transfer characteristics in a rotating packed bed with split packing

    Institute of Scientific and Technical Information of China (English)

    Youzhi Liu; Deyin Gu; Chengcheng Xu; Guisheng Qi; Weizhou Jiao

    2015-01-01

    The rotating packed bed (RPB) with split packing is a novel gas–liquid contactor, which intensifies the mass transfer processes controlled by gas-side resistance. To assess its efficacy, the mass transfer characteristics with adjacent rings in counter-rotation and co-rotation modes in a split packing RPB were studied experimentally. The physical absorption system NH3–H2O was used for characterizing the gas volumetric mass transfer coeffi-cient (kyae) and the effective interfacial area (ae) was determined by chemical absorption in the CO2–NaOH sys-tem. The variation in kyae and ae with the operating conditions is also investigated. The experimental results indicated that kyae and ae for counter-rotation of the adjacent packing rings in the split packing RPB were higher than those for co-rotation, and both counter-rotation and co-rotation of the split packing RPB were superior over conventional RPBs under the similar operating conditions.

  8. Effect of packing method on the randomness of disc packings

    Science.gov (United States)

    Zhang, Z. P.; Yu, A. B.; Oakeshott, R. B. S.

    1996-06-01

    The randomness of disc packings, generated by random sequential adsorption (RSA), random packing under gravity (RPG) and Mason packing (MP) which gives a packing density close to that of the RSA packing, has been analysed, based on the Delaunay tessellation, and is evaluated at two levels, i.e. the randomness at individual subunit level which relates to the construction of a triangle from a given edge length distribution and the randomness at network level which relates to the connection between triangles from a given triangle frequency distribution. The Delaunay tessellation itself is also analysed and its almost perfect randomness at the two levels is demonstrated, which verifies the proposed approach and provides a random reference system for the present analysis. It is found that (i) the construction of a triangle subunit is not random for the RSA, MP and RPG packings, with the degree of randomness decreasing from the RSA to MP and then to RPG packing; (ii) the connection of triangular subunits in the network is almost perfectly random for the RSA packing, acceptable for the MP packing and not good for the RPG packing. Packing method is an important factor governing the randomness of disc packings.

  9. Method of making hydrophobic industrial catalyst for water-hydrogen isotope exchange

    International Nuclear Information System (INIS)

    The authors have performed the research centering around the development of platinum catalyst carried by styrene divinylbenzene copolymer as the hydrophobic catalyst for water-hydrogen isotope exchange for the purpose of heavy water concentration and especially tritium removal. In this paper, the method of industrial production of this catalyst, the results of catalytic performance test by trickle bed and the problems are reported. It was found that only chloroplatinic acid was suitable as the practical raw material of the catalyst. The ethanol solution of chloroplatinic acid is practically most desirable. Generally, the catalytic activity increases by the aging of SDB in pure hydrogen flow. For the impregnation of chloroplatinic acid into SDB, the column method is suitable. The impregnated carriers are dried with an air drier. Then the carriers carrying chloroplatinic acid are reduced in a reaction tube with highly pure hydrogen. The catalytic performance test was performed in a packed tower, and the effects of the shape of catalysts, flow mode, oxygen, scale-up, pressure and impurities are reported. (Kako, I.)

  10. Hydrodynamics of multi-phase packed bed micro-reactors

    OpenAIRE

    Márquez Luzardo, N.M.

    2010-01-01

    Why to use packed bed micro-reactors for catalyst testing? Miniaturized packed bed reactors have a large surface-to-volume ratio at the reactor and particle level that favors the heat- and mass-transfer processes at all scales (intra-particle, inter-phase and inter-particle or reactor level). If the mass-transfer processes are fast in respect to the reaction-rate, then the reaction-rate is under kinetic control over the entire range of conversion and it is possible to measure intrinsic kineti...

  11. Argo packing friction research update

    International Nuclear Information System (INIS)

    This paper focuses on the issue of valve packing friction and its affect on the operability of motor- and air-operated valves (MOVs and AOVs). At this time, most nuclear power plants are required to perform postmaintenance testing following a packing adjustment or replacement. In many cases, the friction generated by the packing does not impact the operability window of a valve. However, to date there has not been a concerted effort to substantiate this claim. To quantify the effects of packing friction, it has become necessary to develop a formula to predict the friction effects accurately. This formula provides a much more accurate method of predicting packing friction than previously used factors based strictly on stem diameter. Over the past 5 years, Argo Packing Company has been developing and testing improved graphite packing systems at research facilities, such as AECL Chalk River and Wyle Laboratories. Much of this testing has centered around reducing and predicting friction that is related to packing. In addition, diagnostic testing for Generic Letter 89-10 MOVs and AOVs has created a significant data base. In July 1992 Argo asked several utilities to provide running load data that could be used to quantify packing friction repeatability and predictability. This technical paper provides the basis to predict packing friction, which will improve calculations for thrust requirements for Generic Leter 89-10 and future AOV programs. In addition, having an accurate packing friction formula will improve packing performance when low running loads are identified that would indicate insufficient sealing force

  12. Separable subgroups have bounded packing

    CERN Document Server

    Yang, Wen-yuan

    2010-01-01

    In this note, we prove that separable subgroups have bounded packing in ambient groups. The notion bounded packing was introduced by Hruska-Wise \\cite{HrWi} and in particular, our result confirms a conjecture in \\cite{HrWi} which states each subgroup of a virtually polycyclic group has the bounded packing property.

  13. Ceramic cooling tower packings

    Energy Technology Data Exchange (ETDEWEB)

    Honekamp, H.; Katzmann, A.

    1986-05-01

    No material for cooling tower packings demonstrates all the characteristics desired by the designer. The choice of a specific material must therefore always be oriented towards the limiting conditions of a specific project. Resistance to frost, combustibility and resistance to ageing may, for example, be determining requirements. Ceramic stones will find further possibilities of application in the near future due to their almost unlimited durability.

  14. Bifunctional anode catalysts for direct methanol fuel cells

    DEFF Research Database (Denmark)

    Rossmeisl, Jan; Ferrin, Peter; Tritsaris, Georgios;

    2012-01-01

    Using the binding energy of OH* and CO* on close-packed surfaces as reactivity descriptors, we screen bulk and surface alloy catalysts for methanol electro-oxidation activity. Using these two descriptors, we illustrate that a good methanol electro-oxidation catalyst must have three key properties...

  15. Packing ellipsoids with overlap

    CERN Document Server

    Uhler, Caroline

    2012-01-01

    The problem of packing ellipsoids of different sizes and shapes into an ellipsoidal container so as to minimize a measure of overlap between ellipsoids is considered. A bilevel optimization formulation is given, together with an algorithm for the general case and a simpler algorithm for the special case in which all ellipsoids are in fact spheres. Convergence results are proved and computational experience is described and illustrated. The motivating application - chromosome organization in the human cell nucleus - is discussed briefly, and some illustrative results are presented.

  16. Homogeneous catalysts

    CERN Document Server

    Chadwick, John C; Freixa, Zoraida; van Leeuwen, Piet W N M

    2011-01-01

    This first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste.The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics.

  17. Cell packing structures

    KAUST Repository

    Pottmann, Helmut

    2015-03-03

    This paper is an overview of architectural structures which are either composed of polyhedral cells or closely related to them. We introduce the concept of a support structure of such a polyhedral cell packing. It is formed by planar quads and obtained by connecting corresponding vertices in two combinatorially equivalent meshes whose corresponding edges are coplanar and thus determine planar quads. Since corresponding triangle meshes only yield trivial structures, we focus on support structures associated with quad meshes or hex-dominant meshes. For the quadrilateral case, we provide a short survey of recent research which reveals beautiful relations to discrete differential geometry. Those are essential for successfully initializing numerical optimization schemes for the computation of quad-based support structures. Hex-dominant structures may be designed via Voronoi tessellations, power diagrams, sphere packings and various extensions of these concepts. Apart from the obvious application as load-bearing structures, we illustrate here a new application to shading and indirect lighting. On a higher level, our work emphasizes the interplay between geometry, optimization, statics, and manufacturing, with the overall aim of combining form, function and fabrication into novel integrated design tools.

  18. ExactPack Documentation

    Energy Technology Data Exchange (ETDEWEB)

    Singleton, Jr., Robert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Israel, Daniel M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Doebling, Scott William [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Woods, Charles Nathan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Kaul, Ann [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Walter, Jr., John William [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Rogers, Michael Lloyd [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-05-09

    For code verification, one compares the code output against known exact solutions. There are many standard test problems used in this capacity, such as the Noh and Sedov problems. ExactPack is a utility that integrates many of these exact solution codes into a common API (application program interface), and can be used as a stand-alone code or as a python package. ExactPack consists of python driver scripts that access a library of exact solutions written in Fortran or Python. The spatial profiles of the relevant physical quantities, such as the density, fluid velocity, sound speed, or internal energy, are returned at a time specified by the user. The solution profiles can be viewed and examined by a command line interface or a graphical user interface, and a number of analysis tools and unit tests are also provided. We have documented the physics of each problem in the solution library, and provided complete documentation on how to extend the library to include additional exact solutions. ExactPack’s code architecture makes it easy to extend the solution-code library to include additional exact solutions in a robust, reliable, and maintainable manner.

  19. Dense packing on uniform lattices

    CERN Document Server

    Eloranta, Kari

    2009-01-01

    We study the Hard Core Model on the graphs ${\\rm {\\bf \\scriptstyle G}}$ obtained from Archimedean tilings i.e. configurations in $\\scriptstyle \\{0,1\\}^{{\\rm {\\bf G}}}$ with the nearest neighbor 1's forbidden. Our particular aim in choosing these graphs is to obtain insight to the geometry of the densest packings in a uniform discrete set-up. We establish density bounds, optimal configurations reaching them in all cases, and introduce a probabilistic cellular automaton that generates the legal configurations. Its rule involves a parameter which can be naturally characterized as packing pressure. It can have a critical value but from packing point of view just as interesting are the noncritical cases. These phenomena are related to the exponential size of the set of densest packings and more specifically whether these packings are maximally symmetric, simple laminated or essentially random packings.

  20. Packing solutions for power plants

    International Nuclear Information System (INIS)

    Asbestos packings are being replaced in more and more countries with alternative products. This paper discusses modern packing solutions for valves and pumps in power plants. Die-moulded packing rings made of expanded graphite foil are described m detail, with recommendations for correct installation. Application examples for spring-loaded valves and cover lid seals are given. As an alternative for repair and service use, a braided expanded graphite packing reinforced with Inconel wire is described. Proposals for sealing various pump applications in power plants are also made. (Author)

  1. Bimetallic Catalysts.

    Science.gov (United States)

    Sinfelt, John H.

    1985-01-01

    Chemical reaction rates can be controlled by varying composition of miniscule clusters of metal atoms. These bimetallic catalysts have had major impact on petroleum refining, where work has involved heterogeneous catalysis (reacting molecules in a phase separate from catalyst.) Experimentation involving hydrocarbon reactions, catalytic…

  2. Random very loose packings.

    Science.gov (United States)

    Ciamarra, Massimo Pica; Coniglio, Antonio

    2008-09-19

    We measure the number Omega(phi) of mechanically stable states of volume fraction phi of a granular assembly under gravity. The granular entropy S(phi)=logOmega(phi) vanishes both at high density, at phi approximately equal to phi_rcp, and a low density, at phi approximately equal to phi_rvlp, where phi_rvlp is a new lower bound we call random very loose pack. phi_rlp is the volume fraction where the entropy is maximal. These findings allow for a clear explanation of compaction experiments and provide the first first-principle definition of the random loose volume fraction. In the context of the statistical mechanics approach to static granular materials, states with phi

  3. Polarizable protein packing

    KAUST Repository

    Ng, Albert H.

    2011-01-24

    To incorporate protein polarization effects within a protein combinatorial optimization framework, we decompose the polarizable force field AMOEBA into low order terms. Including terms up to the third-order provides a fair approximation to the full energy while maintaining tractability. We represent the polarizable packing problem for protein G as a hypergraph and solve for optimal rotamers with the FASTER combinatorial optimization algorithm. These approximate energy models can be improved to high accuracy [root mean square deviation (rmsd) < 1 kJ mol -1] via ridge regression. The resulting trained approximations are used to efficiently identify new, low-energy solutions. The approach is general and should allow combinatorial optimization of other many-body problems. © 2011 Wiley Periodicals, Inc. J Comput Chem, 2011 Copyright © 2011 Wiley Periodicals, Inc.

  4. Packing for food irradiation

    International Nuclear Information System (INIS)

    Joint FAO/IAEA/WHO Expert Committee approved the use of radiation treatment of foods. Nowadays food packaging are mostly made of plastics, natural or synthetic, therefore effect of irradiation on these materials is crucial for packing engineering for food irradiation technology. By selecting the right polymer materials for food packaging it can be ensured that the critical elements of material and product performance are not compromised. When packaging materials are in contact with food at the time of irradiation that regulatory approvals sometimes apply. The review of the R-and-D and technical papers regarding material selection, testing and approval is presented in the report. The most information come from the USA where this subject is well elaborated, the International Atomic Energy Agency (IAEA) reports are reviewed as well. The report can be useful for scientists and food irradiation plants operators. (author)

  5. A biphasic oxidation of alcohols to aldehydes and ketones using a simplified packed-bed microreactor

    OpenAIRE

    Andrew Bogdan; D. Tyler McQuade

    2009-01-01

    We demonstrate the preparation and characterization of a simplified packed-bed microreactor using an immobilized TEMPO catalyst shown to oxidize primary and secondary alcohols via the biphasic Anelli-Montanari protocol. Oxidations occurred in high yields with great stability over time. We observed that plugs of aqueous oxidant and organic alcohol entered the reactor as plugs but merged into an emulsion on the packed-bed. The emulsion coalesced into larger plugs upon exiting the reactor, leavi...

  6. Sugar exported: sugar packed in containers

    Directory of Open Access Journals (Sweden)

    José Alberto Yemal

    2010-04-01

    Full Text Available This paper presents a study in the port sector specialized in handling of bagged sugar. Sugar has always been exported in bags of 50 kg, placed directly in the holds of ships for general cargo. It appears that this form of transport has become obsolete now, the market for the direct form of transport of sugar packed in containers. Companies involved in this type of port handling need understand the reasons that are influencing this new mode of transportation as a way to fit and remain active and competitive in the industry.

  7. Random packing of digitized particles

    NARCIS (Netherlands)

    Korte, de A.C.J.; Brouwers, H.J.H.

    2012-01-01

    The random packing of regularly and irregularly shaped particles has been studied extensively. Within this paper, packing is studied from the perspective of digitized particles. These digitized particles are developed for and used in cellular automata systems, which are employed for the simple mathe

  8. Packing Products: Polystyrene vs. Cornstarch

    Science.gov (United States)

    Starr, Suzanne

    2009-01-01

    Packing materials such as polystyrene take thousands of years to decompose, whereas packing peanuts made from cornstarch, which some companies are now using, can serve the same purpose, but dissolve in water. The author illustrates this point to her class one rainy day using the sculptures students made from polystyrene and with the cornstarch…

  9. Photo-oxidation catalysts

    Science.gov (United States)

    Pitts, J. Roland; Liu, Ping; Smith, R. Davis

    2009-07-14

    Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

  10. On Packing Densities of Set Partitions

    OpenAIRE

    Goyt, Adam M.; Pudwell, Lara K.

    2013-01-01

    We study packing densities for set partitions, which is a generalization of packing words. We use results from the literature about packing densities for permutations and words to provide packing densities for set partitions. These results give us most of the packing densities for partitions of the set $\\{1,2,3\\}$. In the final section we determine the packing density of the set partition $\\{\\{1,3\\},\\{2\\}\\}$.

  11. The pursuit of perfect packing

    CERN Document Server

    Weaire, Denis

    2008-01-01

    Coauthored by one of the creators of the most efficient space packing solution, the Weaire-Phelan structure, The Pursuit of Perfect Packing, Second Edition explores a problem of importance in physics, mathematics, chemistry, biology, and engineering: the packing of structures. Maintaining its mathematical core, this edition continues and revises some of the stories from its predecessor while adding several new examples and applications. The book focuses on both scientific and everyday problems ranging from atoms to honeycombs. It describes packing models, such as the Kepler conjecture, Voronoï decomposition, and Delaunay decomposition, as well as actual structure models, such as the Kelvin cell and the Weaire-Phelan structure. The authors discuss numerous historical aspects and provide biographical details on influential contributors to the field, including emails from Thomas Hales and Ken Brakke. With examples from physics, crystallography, engineering, and biology, this accessible and whimsical bo...

  12. Automotive Catalyst State Diagnosis Using Microwaves

    Directory of Open Access Journals (Sweden)

    Moos Ralf

    2015-01-01

    Full Text Available The state of catalysts plays a key role in automotive exhaust gas aftertreatment. The soot or ash loading of Diesel particulate filters, the oxygen loading degree in three-way catalysts, the amount of stored ammonia in SCR catalysts, or the NOx loading degree in NOx storage catalysts are important parameters that are today determined indirectly and in a model-based manner with gas sensors installed upstream and/or downstream of the catalysts. This contribution gives an overview on a novel approach to determine the catalyst state directly by a microwave-based technique. The method exploits the fact that the catalyst housing acts as a microwave cavity resonator. As “sensing” elements, one or two simple antennas are mounted inside the catalyst canning. The electrical properties of the catalyst device (ceramic honeycomb plus coating and storage material can be measured. Preferably, the resonance characteristics, e.g., the resonance frequencies, of selected cavity modes are observed. The information on the catalyst interior obtained in such a contactless manner is very well correlated with the catalyst state as will be demonstrated for different exhaust gas aftertreatment systems.

  13. Catalytic Pyrolysis of Oak via Pyroprobe and Bench Scale, Packed Bed Pyrolysis Reactors

    Science.gov (United States)

    The pyrolytic conversion of oak sawdust at 500°C in flowing He over eight proprietary catalysts is described and compared to the control bed material, quartz sand. The reactions were conducted and compared in two reactors, an analytical, ug-scale pyroprobe reactor and a bench, g-scale packed bed re...

  14. Hydrodynamic behaviour of a gas—solid counter-current packed column at trickle flow

    NARCIS (Netherlands)

    Roes, A.W.M.; Swaaij, van W.P.M.

    1979-01-01

    Trickle flow of a more or less fluidized catalyst through a packed column is a promising new gas—solid counter-current operation. The hydrodynamic, behaviour of such a column, filled with dumped PALL rings, has been investigated, while some results have been obtained with RASCHIG rings and cylindric

  15. Catalyst composition

    Energy Technology Data Exchange (ETDEWEB)

    Onodera, T.; Sakai, T.; Sumitani, K.; Yamasaki, Y.

    1984-11-27

    A catalyst composition comprising a crystalline aluminosilicate selected from the group consisting of zeolite ZSM-5, zeolite ZSM-11, zeolite ZSM-12, zeolite ZSM-35 and zeolite ZSM-38 and having a silica/alumina mole ratio of 20 to 1,000; and at least two metals which are platinum and at least one other metal selected from the group consisting of titanium, chromium, zinc, gallium, germanium, strontium, yttrium, zirconium, molybdenum, palladium, tin, barium, cerium, tungsten, osmium, lead, cadmium, mercury, indium, lanthanum and beryllium. This catalyst composition is useful particularly for the isomerization of aromatic hydrocarbons and reforming of naphtha.

  16. Packing Optimization of Sorbent Bed Containing Dissimilar and Irregular Shaped Media

    Science.gov (United States)

    Holland, Nathan; Guttromson, Jayleen; Piowaty, Hailey

    2011-01-01

    The Fire Cartridge is a packed bed air filter with two different and separate layers of media designed to provide respiratory protection from combustion products after a fire event on the International Space Station (ISS). The first layer of media is a carbon monoxide catalyst and the second layer of media is universal carbon. During development of Fire Cartridge prototypes, the two media beds were noticed to have shifted inside the cartridge. The movement of media within the cartridge can cause mixing of the bed layers, air voids, and channeling, which could cause preferential air flow and allow contaminants to pass through without removal. An optimally packed bed mitigates these risks and ensures effective removal of contaminants from the air. In order to optimally pack each layer, vertical, horizontal, and orbital agitations were investigated and a packed bulk density was calculated for each method. Packed bulk density must be calculated for each media type to accommodate variations in particle size, shape, and density. Additionally, the optimal vibration parameters must be re-evaluated for each batch of media due to variations in particle size distribution between batches. For this application it was determined that orbital vibrations achieve an optimal pack density and the two media layers can be packed by the same method. Another finding was media with a larger size distribution of particles achieve an optimal bed pack easier than media with a smaller size distribution of particles.

  17. Nature of packs used in propellant modeling.

    Science.gov (United States)

    Maggi, F; Stafford, S; Jackson, T L; Buckmaster, J

    2008-04-01

    In recent years we have constructed closely packed spheres using the Lubachevsky-Stillinger algorithm to generate morphological models of heterogeneous solid propellants. Improvements to the algorithm now allow us to create large polydisperse packs on a laptop computer, and to create monodisperse packs with packing fractions greater than 70% which display significant crystal order. The use of these models in the physical context motivates efforts to examine in some detail the nature of the packs, including certain statistical properties. We compare packing fractions for binary packs with long-known experimental data. Also, we discuss the near-neighbor number and the radial distribution function (RDF) for monodisperse packs and make comparisons with experimental data. We also briefly discuss the RDF for bidisperse packs. We also consider bounded monodisperse packs, and pay particular attention to the near-wall structure where we identify significant order.

  18. Dosimetry effects of film packing

    International Nuclear Information System (INIS)

    Full text: Dosimetric artefacts in film based dosimetry have been addressed by a number of authors. We have investigated the influence on film dose results, of a number of materials that are commonly packed against the film including, solid water, paper, air and plastic. The results indicate that variations in optical density occur due to the character and relative quantity of the packing material as well as the film itself. Kodak X-omat V and GAFChromic film samples were placed in a solid water cassette with packing sheets of various materials placed in contact with the film. Photon and electron exposures were carried out with various film orientation and beam qualities. Results have been obtained for solid water, paper and air. An example of the relative change in film density as a function of depth due to four paper sheets packed adjacent to a film aligned with the central axis of a 6MV photon beam is shown. Other results indicate dose variation can be attributed to Cerenkov radiation. Packing materials in contact or in close proximity with dosimetric film, contribute to optical density variations of the order of several percent. Careful consideration of these effects is necessary when using film in high accuracy dosimetry. Copyright (2001) Australasian College of Physical Scientists and Engineers in Medicine

  19. Commercial Application of Novel FDFCC Grid Packing Type Stripper

    Institute of Scientific and Technical Information of China (English)

    Zhang Zhenqian; Tian Geng; Lei Shiyuan

    2007-01-01

    The novel FDFCC grid packing stripper is used to raise the stripping efficiency of the equipment.This technology aims to increase the gas-solid contact area and improve the gas-solid contact efficiency.This technology has been applied in the revamped 1.05 Mt/a No.1 FCC unit at the SINOPEC Changling Branch Company.The outcome on application of this equipment has revealed that the fluidization of the stripper was stable coupled with smooth operation.At a steam stripping load of less than 50%of the design value the spent catalyst had a lower H/C ratio,and the hydrogen content in the coke after revamp of the FCC unit decreased by 8.1%compared to the case before the equipment revamp.The spent catalyst had higher activity with the dry gasand coke yields reduced by over 0.5%.resulting in good economic benefits.

  20. Critical packing fraction in multicomponent, glass forming metallic liquids

    International Nuclear Information System (INIS)

    Glass forming Ni59.5Nb40.5 and Ni60Nb34.8Sn5.2 have been investigated in their equilibrium liquid by quasielastic neutron scattering. These liquids exhibit extraordinary high packing fraction. Structural relaxation shows stretching in time and extent of stretching depends on the temperature of the liquid. The self-diffusivity decreases about two orders of magnitude within 360 K. From the β-relaxation, τ-scaling analysis of self-diffusion and mean relaxation times of the α-process the critical packing fraction of these liquids have been derived. Our results provide, for the first time, an experimentally observed value for the critical packing fraction in the glass forming metallic liquids and is in good agreement with mode-coupling theory prediction

  1. Sleeping distance in wild wolf packs

    Science.gov (United States)

    Knick, S.T.; Mech, L.D.

    1980-01-01

    Sleeping distances were observed among members of 13 wild wolf (Canis lupus) packs and 11 pairs in northeastern Minnesota to determine if the distances correlated with pack size and composition. The study utilized aerial radio-tracking and observation during winter. Pack size and number of adults per pack were inversely related to pack average sleeping distance and variability. No correlation between sleeping distance and microclimate was observed. Possible relationships between social bonding and our results are discussed.

  2. The pursuit of perfect packing

    CERN Document Server

    Weaire, Denis

    2000-01-01

    In 1998 Thomas Hales dramatically announced the solution of a problem that has long teased eminent mathematicians: what is the densest possible arrangement of identical spheres? The Pursuit of Perfect Packing recounts the story of this problem and many others that have to do with packing things together. The examples are taken from mathematics, physics, biology, and engineering, including the arrangement of soap bubbles in foam, atoms in a crystal, the architecture of the bee''s honeycomb, and the structure of the Giant''s Causeway. Using an informal style and with key references, the book also includes brief accounts of the lives of many of the scientists who devoted themselves to problems of packing over many centuries, together with wry comments on their efforts. It is an entertaining introduction to the field for both specialists and the more general public.

  3. Cylinder valve packing nut studies

    Energy Technology Data Exchange (ETDEWEB)

    Blue, S.C. [Martin Marietta Energy Systems, Inc., Paducah, KY (United States)

    1991-12-31

    The design, manufacture, and use of cylinder valve packing nuts have been studied to improve their resistance to failure from stress corrosion cracking. Stress frozen photoelastic models have been analyzed to measure the stress concentrations at observed points of failure. The load effects induced by assembly torque and thermal expansion of stem packing were observed by strain gaging nuts. The effects of finishing operations and heat treatment were studied by the strain gage hole boring and X-ray methods. Modifications of manufacturing and operation practices are reducing the frequency of stress corrosion failures.

  4. Catalyst Architecture

    DEFF Research Database (Denmark)

    Kiib, Hans; Marling, Gitte; Hansen, Peter Mandal

    2014-01-01

    How can architecture promote the enriching experiences of the tolerant, the democratic, and the learning city - a city worth living in, worth supporting and worth investing in? Catalyst Architecture comprises architectural projects, which, by virtue of their location, context and their combinatio...... meaningful for everyone. The exhibited works are designed by SANAA, Diller Scofidio + Renfro, James Corner Field Operation, JBMC Arquitetura e Urbanismo, Atelier Bow-Wow, Ateliers Jean Nouvel, COBE, Transform, BIG, Topotek1, Superflex, and by visual artist Jane Maria Petersen....

  5. Packing Optimization of an Intentionally Stratified Sorbent Bed Containing Dissimilar Media Types

    Science.gov (United States)

    Kidd, Jessica; Guttromson, Jayleen; Holland, Nathan

    2010-01-01

    The Fire Cartridge is a packed bed air filter with two different and separate layers of media designed to provide respiratory protection from combustion products after a fire event on the International Space Station (ISS). The first layer of media is a carbon monoxide catalyst made from gold nanoparticles dispersed on iron oxide. The second layer of media is universal carbon, commonly used in commercial respirator filters. Each layer must be optimally packed to effectively remove contaminants from the air. Optimal packing is achieved by vibratory agitations. However, if post-packing movement of the media within the cartridge occurs, mixing of the bed layers, air voids, and channeling could cause preferential air flow and allow contaminants to pass. Several iterations of prototype fire cartridges were developed to reduce post-packing movement of the media within each layer (settling), and to prevent mixing of the two media types. Both types of movement of the media contribute to decreased fire cartridge performance. Each iteration of the fire cartridge design was tested to demonstrate mechanical loads required to cause detrimental movement within the bed, and resulting level of functionality of the media beds after movement was detected. In order to optimally pack each layer, vertical, horizontal, and orbital agitations were tested and a final packed bulk density was calculated for each method. Packed bulk density must be calculated for each lot of catalyst to accommodate variations in particle size, shape, and density. In addition, a physical divider sheet between each type of media was added within the fire cartridge design to further inhibit intermixing of the bed layers.

  6. Pack cementation coatings for alloys

    Energy Technology Data Exchange (ETDEWEB)

    He, Yi-Rong; Zheng, Minhui; Rapp, R.A. [Ohio State Univ., Columbus, OH (United States)

    1996-08-01

    The halide-activated pack cementation process was modified to produce a Ge-doped silicide diffusion coating on a Cr-Cr{sub 2}Nb alloy in a single processing step. The morphology and composition of the coating depended both on the composition of the pack and on the composition and microstructure of the substrate. Higher Ge content in the pack suppressed the formation of CrSi{sub 2} and reduced the growth kinetics of the coating. Ge was not homogeneously distributed in the coatings. In cyclic and isothermal oxidation in air at 700 and 1050{degrees}C, the Ge-doped silicide coating protected the Cr-Nb alloys from significant oxidation by the formation of a Ge-doped silica film. The codeposition and diffusion of aluminum and chromium into low alloy steel have been achieved using elemental Al and Cr powders and a two-step pack cementation process. Sequential process treatments at 925{degrees}C and 1150{degrees}C yield dense and uniform ferrite coatings, whose compositions are close to either Fe{sub 3}Al or else FeAl plus a lower Cr content, when processed under different conditions. The higher content of Al in the coatings was predicted by thermodynamic calculations of equilibrium in the gas phase. The effect of the particle size of the metal powders on the surface composition of the coating has been studied for various combinations of Al and Cr powders.

  7. The Maximum Resource Bin Packing Problem

    DEFF Research Database (Denmark)

    Boyar, J.; Epstein, L.; Favrholdt, L.M.;

    2006-01-01

    Usually, for bin packing problems, we try to minimize the number of bins used or in the case of the dual bin packing problem, maximize the number or total size of accepted items. This paper presents results for the opposite problems, where we would like to maximize the number of bins used or...... algorithms, First-Fit-Increasing and First-Fit-Decreasing for the maximum resource variant of classical bin packing. For the on-line variant, we define maximum resource variants of classical and dual bin packing. For dual bin packing, no on-line algorithm is competitive. For classical bin packing, we find...

  8. A Numerical Model for Thermal Effects in a Microwave Irradiated Catalyst Bed

    OpenAIRE

    Lanz, Jason E.

    1998-01-01

    Electromagnetic and heat transfer analysis is used to determine possibility of selective heating of nanometer-sized, metallic catalyst particles attached to a ceramic support through microwave irradiation. This analysis is incorporated into a macroscopic heat transfer model of a packed and fluidized catalyst bed heated by a microwave field to predict thermal effects associated with selective heating of the catalyst sites. The model shows a dependence on particle size and microwave frequency...

  9. Performance characteristics of a new structured packing

    OpenAIRE

    Bessou, Vincent; Rouzineau, David; Prevost, Michel; Abbé, François; Dumont, Charles; Maumus, Jean-Pierre; Meyer, Michel

    2010-01-01

    A new structured packing using carbon fibres, called Sepcarb® 4D, is presented. This packing has several attractive properties, such as high voidage (ε=94%) and high effective area (a=420 m2 m−3). These properties are advantageous for packing used as a gas–liquid contactor for separation units. To determine the internal characteristics of this packing, we performed several experiments using a 150-mm-internal-diameter column. Firstly, hydrodynamics experiments were conducted using an air–water...

  10. Heuristics for Multidimensional Packing Problems

    DEFF Research Database (Denmark)

    Egeblad, Jens

    In this thesis we consider solution methods for packing problems. Packing problems occur in many different situations both directly in the industry and as sub-problems of other problems. High-quality solutions for problems in the industrial sector may be able to reduce transportation and production......) and may be defined in any number of dimensions. Solution methods are based on theory from both computational geometry and operations research. The scientific contributions of this thesis are presented in the form of six papers and a section which introduces the many problem types and recent solution...... of items. The heuristic was developed in collaboration with an industrial partner and is now being used to solve hundreds of problems every day as part of their planning process. A simple heuristic for optimizing a placement of items with respect to balance and moment of inertia is presented in the fifth...

  11. Packing Superballs from Codes and Algebraic Curves

    Institute of Scientific and Technical Information of China (English)

    Li LIU; Chao Ping XING

    2008-01-01

    In the present paper, we make use of codes with good parameters and algebraic curves over finite fields with many rational points to construct dense packings of superballs. It turns out that our packing density is quite reasonable. In particular, we improve some values for the best-known lower bounds on packing density.

  12. 7 CFR 51.1527 - Standard pack.

    Science.gov (United States)

    2010-01-01

    ... package. The number of plums or prunes in California peach boxes or lug boxes shall not vary more than 4... Standards for Grades of Fresh Plums and Prunes Standard Pack § 51.1527 Standard pack. (a) Packing. (1) All... plums or prunes in the top layer of any package shall be reasonably representative in quality and...

  13. Random packing of colloids and granular matter

    NARCIS (Netherlands)

    Wouterse, A.

    2008-01-01

    This thesis deals with the random packing of colloids and granular matter. A random packing is a stable disordered collection of touching particles, without long-range positional and orientational order. Experimental random packings of particles with the same shape but made of different materials sh

  14. 7 CFR 51.310 - Packing requirements.

    Science.gov (United States)

    2010-01-01

    ... MARKETING ACT OF 1946 FRESH FRUITS, VEGETABLES AND OTHER PRODUCTS 1,2 (INSPECTION, CERTIFICATION, AND.... (a) Apples tray packed or cell packed in cartons shall be arranged according to approved and... that apples are of the proper size for molds or cell compartments in which they are packed, and...

  15. Towards optimal packed string matching

    DEFF Research Database (Denmark)

    Ben-Kiki, Oren; Bille, Philip; Breslauer, Dany;

    2014-01-01

    In the packed string matching problem, it is assumed that each machine word can accommodate up to α characters, thus an n-character string occupies n/α memory words.(a) We extend the Crochemore–Perrin constant-space O(n)-time string-matching algorithm to run in optimal O(n/α) time and even in real......-time, achieving a factor α speedup over traditional algorithms that examine each character individually. Our macro-level algorithm only uses the standard AC0 instructions of the word-RAM model (i.e. no integer multiplication) plus two specialized micro-level AC0 word-size packed-string instructions. The main word...... matching work.(b) We also consider the complexity of the packed string matching problem in the classical word-RAM model in the absence of the specialized micro-level instructions wssm and wslm. We propose micro-level algorithms for the theoretically efficient emulation using parallel algorithms techniques...

  16. Diffusion in Jammed Particle Packs.

    Science.gov (United States)

    Bolintineanu, Dan S; Grest, Gary S; Lechman, Jeremy B; Silbert, Leonardo E

    2015-08-21

    Using random walk simulations we explore diffusive transport through monodisperse sphere packings over a range of packing fractions ϕ in the vicinity of the jamming transition at ϕ(c). Various diffusion properties are computed over several orders of magnitude in both time and packing pressure. Two well-separated regimes of normal "Fickian" diffusion, where the mean squared displacement is linear in time, are observed. The first corresponds to diffusion inside individual spheres, while the latter is the long-time bulk diffusion. The intermediate anomalous diffusion regime and the long-time value of the diffusion coefficient are both shown to be controlled by particle contacts, which in turn depend on proximity to ϕ(c). The time required to recover normal diffusion t* scales as (ϕ-ϕ(c))(-0.5) and the long-time diffusivity D(∞)∼(ϕ-ϕ(c))0.5, or D(∞)∼1/t*. It is shown that the distribution of mean first passage times associated with the escape of random walkers between neighboring particles controls both t* and D(∞) in the limit ϕ→ϕ(c).

  17. Destabilization of confined granular packings due to fluid flow

    Science.gov (United States)

    Monloubou, Martin; Sandnes, Bjørnar

    2016-04-01

    Fluid flow through granular materials can cause fluidization when fluid drag exceeds the frictional stress within the packing. Fluid driven failure of granular packings is observed in both natural and engineered settings, e.g. soil liquefaction and flowback of proppants during hydraulic fracturing operations. We study experimentally the destabilization and flow of an unconsolidated granular packing subjected to a point source fluid withdrawal using a model system consisting of a vertical Hele-Shaw cell containing a water-grain mixture. The fluid is withdrawn from the cell at a constant rate, and the emerging flow patterns are imaged in time-lapse mode. Using Particle Image Velocimetry (PIV), we show that the granular flow gets localized in a narrow channel down the center of the cell, and adopts a Gaussian velocity profile similar to those observed in dry grain flows in silos. We investigate the effects of the experimental parameters (flow rate, grain size, grain shape, fluid viscosity) on the packing destabilization, and identify the physical mechanisms responsible for the observed complex flow behaviour.

  18. Adhesive loose packings of small dry particles

    Science.gov (United States)

    Liu, Wenwei; Li, Shuiqing; Baule, Adrian; Makse, Hernán A.

    We explore adhesive loose packings of dry small spherical particles of micrometer size using 3D discrete-element simulations with adhesive contact mechanics. A dimensionless adhesion parameter ($Ad$) successfully combines the effects of particle velocities, sizes and the work of adhesion, identifying a universal regime of adhesive packings for $Ad>1$. The structural properties of the packings in this regime are well described by an ensemble approach based on a coarse-grained volume function that includes correlations between bulk and contact spheres. Our theoretical and numerical results predict: (i) An equation of state for adhesive loose packings that appears as a continuation from the frictionless random close packing (RCP) point in the jamming phase diagram; (ii) The existence of a maximal loose packing point at the coordination number $Z=2$ and packing fraction $\\phi=1/2^{3}$. Our results highlight that adhesion leads to a universal packing regime at packing fractions much smaller than the random loose packing, which can be described within a statistical mechanical framework. We present a general phase diagram of jammed matter comprising frictionless, frictional, adhesive as well as non-spherical particles, providing a classification of packings in terms of their continuation from the spherical frictionless RCP.

  19. Recycling and Activity Recovery of Chloroaluminate Ionic Liquid as Catalyst for Alkylation of Benzene with 1-Dodecene

    Institute of Scientific and Technical Information of China (English)

    乔聪震; 李成岳

    2006-01-01

    Performances of 1-butyl-3-methylimidazolium aluminium chloride ([BMIM]Cl-AlCl3) ionic liquid as catalyst for the alkylation of benzene with long chain olefins were investigated in a continuous operation mode. A small pilot plant with continuous mixing-reacting-separating-recycling functions, equipped with a static mixer reactor, a tube packed with metal Al thread and a combined liquid-liquid settling phase separator, was introduced as an alternative. The results showed that the continuous fast mixing and separation of ionic liquid catalyst from reactant mixture could be synchronously accomplished within a wider flow rate ratio range of the recycling reaction mixture to the ionic liquid catalyst. The recycling of chloroaluminate ionic liquid was realized. ICP-AES detection results of Al content in the reactants proves that in-situ Al compensation to the reaction system may be an important choice to prolong the stable running time of moisture-sensitive ionic liquid [BMIM]Cl-AlCl3 when feedstock inevitably contains trace water. It suggests that the activity of chloroaluminate ionic liquid is recovered under the in-situ Al compensation operation.

  20. Electrochemical catalyst recovery method

    Science.gov (United States)

    Silva, Laura J.; Bray, Lane A.

    1995-01-01

    A method of recovering catalyst material from latent catalyst material solids includes: a) combining latent catalyst material solids with a liquid acid anolyte solution and a redox material which is soluble in the acid anolyte solution to form a mixture; b) electrochemically oxidizing the redox material within the mixture into a dissolved oxidant, the oxidant having a potential for oxidation which is effectively higher than that of the latent catalyst material; c) reacting the oxidant with the latent catalyst material to oxidize the latent catalyst material into at least one oxidized catalyst species which is soluble within the mixture and to reduce the oxidant back into dissolved redox material; and d) recovering catalyst material from the oxidized catalyst species of the mixture. The invention is expected to be particularly useful in recovering spent catalyst material from petroleum hydroprocessing reaction waste products having adhered sulfides, carbon, hydrocarbons, and undesired metals, and as well as in other industrial applications.

  1. Covering and packing pumpkin models

    OpenAIRE

    Chatzidimitriou, Dimitris; Raymond, Jean-Florent; Sau, Ignasi; Thilikos, Dimitrios M.

    2014-01-01

    International audience Let θr (the r-pumpkin) be the multi-graph containing two vertices and r parallel edges between them. We say that a graph is a a θr-model if it can be transformed into θr after a (possibly empty) sequence of contractions. We prove that there is a function g : N → N such that, for every two positive integers k and q, if G is a Kq-minor-free graph, then either G contains a set of k vertex-disjoint subgraphs (a θr-model-vertex-packing) each isomorphic to a θr-model or a ...

  2. Packing, tiling, orthogonality and completeness

    OpenAIRE

    Kolountzakis, Mihail N.

    1999-01-01

    Let $\\Omega \\subseteq {\\bf R}^d$ be an open set of measure 1. An open set $D \\subseteq {\\bf R}^d$ is called a ``tight orthogonal packing region'' for $\\Omega$ if $D-D$ does not intersect the zeros of the Fourier Transform of the indicator function of $\\Omega$ and $D$ has measure 1. Suppose that $\\Lambda$ is a discrete subset of ${\\bf R}^d$. The main contribution of this paper is a new way of proving the following result (proved by different methods by Lagarias, Reeds and Wang and, in the case...

  3. Hydrogenation of Aliphatic Alkenes in a High-Temperature High-Pressure Packed-Bed Microreactor

    OpenAIRE

    Stavárek, Petr

    2012-01-01

    This contribution presents results of the characterization of a new high-temperature high-pressure integrated packed-bed microreactor (MCTU 600 from Ehrfeld Mikrotechnik BTS GmbH) for lab-scale catalyst testing. As the model reaction we used the hydrogenation of C4-C5 aliphatic alkenes heterogeneously catalyzed by Pt/Al2O3 or Pd/Al2O3.

  4. PRESSURE DROP ACROSS A FIXED BED REACTOR WITH MECHANICAL FAILURE OF CATALYST PELLETS DESCRIBED BY SIMPLIFIED ERGUN'S EQUATION

    Institute of Scientific and Technical Information of China (English)

    Dong Zhang; Panfeng Fan; Dongfang Wu; Yongdan Li

    2005-01-01

    The pressure drop across a laboratory-scale catalyst packed bed with mechanical failure of catalyst pellets has been examined. It was found that the increased pressure drop can be described by a simplified model deduced from Ergun's equation. The pressure drop is determined mainly by the term of viscous energy loss.

  5. The “Theoreticals” Pack

    CERN Multimedia

    CERN Bulletin

    2011-01-01

    The Particle Zoo is a colourful set of hand-made soft toys representing the particles in the Standard Model and beyond. It includes a “theoreticals” pack where you can find yet undiscovered particles: the best-selling Higgs boson, the graviton, the tachyon, and dark matter. Supersymmetric particle soft toys are also available on demand. But what would happen to the zoo if Nature had prepared some unexpected surprises? Julie Peasley, the zookeeper, is ready to sew new smiling faces…   The "Theoreticals" pack in the Particle Zoo. There is only one place in the world where you can buy a smiling Higgs boson and it’s not at CERN, although this is where scientists hope to observe it. The blue star-shaped particle is the best seller of Julie Peasley’s Particle Zoo – a collection of tens of soft toys representing all sorts of particles, including composite and decaying particles.  Over the years Julie’s zoo ...

  6. Structured packing: an opportunity for energy savings

    International Nuclear Information System (INIS)

    This work emphasizes the advantages about the use of structured packing. This type of packings allows by its geometry to reduce the processing time giving energy savings and throw down the production costs in several industries such as heavy water production plants, petrochemical industry and all industries involved with separation processes. There is a comparative results of energy consumption utilizing the structured vs. Raschig packings. (Author)

  7. Three techniques for obtaining algebraic circle packings

    OpenAIRE

    Louder, Larsen; Mishchenko, Andrey M.; Souto, Juan

    2014-01-01

    The main purpose of this article is to demonstrate three techniques for proving algebraicity statements about circle packings. We give proofs of three related theorems: (1) that every finite simple planar graph is the contact graph of a circle packing on the Riemann sphere, equivalently in the complex plane, all of whose tangency points, centers, and radii are algebraic, (2) that every flat conformal torus which admits a circle packing whose contact graph triangulates the torus has algebraic ...

  8. L1-norm packings from function fields

    Institute of Scientific and Technical Information of China (English)

    LI; Hongli

    2005-01-01

    In this paper, we study some packings in a cube, namely, how to pack n points in a cube so as to maximize the minimal distance. The distance is induced by the L1-norm which is analogous to the Hamming distance in coding theory. Two constructions with reasonable parameters are obtained, by using some results from a function field including divisor class group, narrow ray class group, and so on. We also present some asymptotic results of the two packings.

  9. The advantages of hydraulic packing extraction

    International Nuclear Information System (INIS)

    Today's competitive environment, coupled with industry's desire to improve the efficiency of plant maintenance and operations, has management continually seeking ways to save time, money, and, at nuclear plants, radiation exposure. One area where a tremendous improvement in efficiency can be realized is valve packing removal. For example, industry experience indicates that up to 70% of the time it takes to repack a valve can be spent just removing the old packing. In some case, the bonnets of small valves are removed to facilitate packing removal and prevent stem and stuffing box damage that can occur when using packing removal picks. In other cases, small valves are simply removed and discarded because it costs less to replace the valves than to remove the packing using conventional methods. Hydraulic packing extraction greatly reduces packing removal time and will not damage the stem nor stuffing box, thus eliminating the need for bonnet removal or valve replacement. This paper will review some of the more common problems associated with manual packing extraction techniques. It will explain how hydraulic packing extraction eliminates or greatly reduces the impact of each of the problem areas. A discussion will be provided of some actual industry operating experiences related to success stories using hydraulic packing extraction. The paper will also briefly describe the operating parameters associated with hydraulic packing extraction tools. Throughout the paper, actual operating experiences from the nuclear power, fossil power, petrochemical, and refinery industries will be used to support the conclusion that hydraulic packing extraction is an alternative that can save time, money, and exposure

  10. SPECTRUM OF DIRECTED KIRKMAN PACKING DESIGNS

    Institute of Scientific and Technical Information of China (English)

    ZhangYan; DuBeiliang

    2003-01-01

    The problem studied in this article is the directed Kirkman packing, the resolvable directed packing which requires all blocks to be of size three except that ,each resolution class should contain either one block of size two(when v=2(mod 3)) or one block of size four (when v=l (mod 3)). A directed Kirkman packing design DKPD(v) is a resolvable directed packing of a v-set by the maximum possible number of resolution classes of this type. This article investigates the spectrum of DKPD(v) and it is found that it contains all positive integers v≥3 and v≠5,6.

  11. Foundation Flash Catalyst

    CERN Document Server

    Goralski, Greg

    2010-01-01

    This book offers an introduction to Flash Catalyst for designers with intermediate to advanced skills. It discusses where Catalyst sits within the production process and how it communicates with other programs. It covers all of the features of the Flash Catalyst workspace, teaching you how to create designs from scratch, how to build application designs and add functionality, and how to master the Catalyst/Flex workflow. * Introduces Flash Catalyst * Focuses on production process * Covers the interrelation between Flash Catalyst and Photoshop/Illustrator/Flex/Flash What you'll learn Starting f

  12. Minimally packed phases in holography

    CERN Document Server

    Donos, Aristomenis

    2015-01-01

    We numerically construct asymptotically AdS black brane solutions of $D=4$ Einstein-Maxwell theory coupled to a pseudoscalar. The solutions are holographically dual to $d=3$ CFTs held at constant chemical potential and magnetic field that spontaneously break translation invariance leading to the spontaneous formation of abelian and momentum magnetisation currents flowing around the plaquettes of a periodic Bravais lattice. We analyse the three-dimensional moduli space of lattice solutions, which are generically oblique, and show that the free energy is minimised by the triangular lattice, associated with minimal packing of circles in the plane. The triangular structure persists at low temperatures indicating the existence of novel crystalline ground states.

  13. Evaluation of a commercial packed bed flow hydrogenator for reaction screening, optimization, and synthesis

    Directory of Open Access Journals (Sweden)

    Marian C. Bryan

    2011-08-01

    Full Text Available The performance of the ThalesNano H-Cube®, a commercial packed bed flow hydrogenator, was evaluated in the context of small scale reaction screening and optimization. A model reaction, the reduction of styrene to ethylbenzene through a 10% Pd/C catalyst bed, was used to examine performance at various pressure settings, over sequential runs, and with commercial catalyst cartridges. In addition, the consistency of the hydrogen flow was indirectly measured by in-line UV spectroscopy. Finally, system contamination due to catalyst leaching, and the resolution of this issue, is described. The impact of these factors on the run-to-run reproducibility of the H-Cube® reactor for screening and reaction optimization is discussed.

  14. Confined disordered strictly jammed binary sphere packings

    Science.gov (United States)

    Chen, D.; Torquato, S.

    2015-12-01

    Disordered jammed packings under confinement have received considerably less attention than their bulk counterparts and yet arise in a variety of practical situations. In this work, we study binary sphere packings that are confined between two parallel hard planes and generalize the Torquato-Jiao (TJ) sequential linear programming algorithm [Phys. Rev. E 82, 061302 (2010), 10.1103/PhysRevE.82.061302] to obtain putative maximally random jammed (MRJ) packings that are exactly isostatic with high fidelity over a large range of plane separation distances H , small to large sphere radius ratio α , and small sphere relative concentration x . We find that packing characteristics can be substantially different from their bulk analogs, which is due to what we term "confinement frustration." Rattlers in confined packings are generally more prevalent than those in their bulk counterparts. We observe that packing fraction, rattler fraction, and degree of disorder of MRJ packings generally increase with H , though exceptions exist. Discontinuities in the packing characteristics as H varies in the vicinity of certain values of H are due to associated discontinuous transitions between different jammed states. When the plane separation distance is on the order of two large-sphere diameters or less, the packings exhibit salient two-dimensional features; when the plane separation distance exceeds about 30 large-sphere diameters, the packings approach three-dimensional bulk packings. As the size contrast increases (as α decreases), the rattler fraction dramatically increases due to what we call "size-disparity" frustration. We find that at intermediate α and when x is about 0.5 (50-50 mixture), the disorder of packings is maximized, as measured by an order metric ψ that is based on the number density fluctuations in the direction perpendicular to the hard walls. We also apply the local volume-fraction variance στ2(R ) to characterize confined packings and find that these

  15. Effect of Electric Discharge on Properties of Nano-Particulate Catalyst for Plasma-Catalysis.

    Science.gov (United States)

    Lee, Chung Jun; Kim, Jip; Kim, Taegyu

    2016-02-01

    Heterogeneous catalytic processes have been used to produce hydrogen from hydrocarbons. However, high reforming temperature caused serious catalyst deteriorations and low energy efficiency. Recently, a plasma-catalyst hybrid process was used to reduce the reforming temperature and to improve the stability and durability of reforming catalysts. Effect of electric discharges on properties of nanoparticulate catalysts for plasma-catalysis was investigated in the present study. Catalyst-bed porosity was varied by packing catalyst beads with the different size in a reactor. Discharge power and onset voltage of the plasma were measured as the catalyst-bed porosity was varied. The effect of discharge voltage, frequency and voltage waveforms such as the sine, pulse and square was investigated. We found that the optimal porosity of the catalyst-bed exists to maximize the electric discharge. At a low porosity, the electric discharge was unstable to be sustained because the space between catalysts got narrow nearly close to the sheath region. On the other hand, at a high porosity, the electric discharge became weak because the plasma was not sufficient to interact with the surface of catalysts. The discharge power increased as the discharge voltage and frequency increased. The square waveform was more efficient than the sine and pulse one. At a high porosity, however, the effect of the voltage waveform was not considerable because the space between catalysts was too large for plasma to interact with the surface of catalysts.

  16. Particle-size distribution and packing fraction of geometric random packings

    NARCIS (Netherlands)

    Brouwers, H.J.H.

    2006-01-01

    This paper addresses the geometric random packing and void fraction of polydisperse particles. It is demonstrated that the bimodal packing can be transformed into a continuous particle-size distribution of the power law type. It follows that a maximum packing fraction of particles is obtained when t

  17. Optimization of the packing design for manifold catalytic converter application

    Energy Technology Data Exchange (ETDEWEB)

    Kil, J.; Yeo, G.

    1996-09-01

    A preconverter is an essential component of the new vehicle exhaust system for the achievement of tightened emission standards. To meet those standards, the Manifold Catalytic Converter (MCC) system has been developed in the Hyundai Motor Company (HMC). Unfortunately, the conventional MCC is no longer a suitable design for the exhaust gas treatment of the newly developed high performance engine since it cannot withstand the engine`s exhaust temperature, vibration, pressure pulsation, and many other severe conditions. This paper is focused on a failure-mode analysis and new packing designs for the MCC application through a series of durability tests.

  18. BIPP (BISMUTH IODINE PARAFFINE PASTE PACK REVISITED

    Directory of Open Access Journals (Sweden)

    Balasubramanian Thiagarajan

    2011-09-01

    Full Text Available This review article takes a new look at the use of BIPP pack following nasal and ear surgeries. It lists the advantages and pitfalls of using this packing material. Pubmed search revealed very little material on this topic hence I compiled existing data to bring out an article.

  19. Call packing bound for overflow loss systems

    NARCIS (Netherlands)

    N.M. van Dijk; E. van der Sluis

    2009-01-01

    Finite loss queues with overflow naturally arise in a variety of communications structures. For these systems, there is no simple analytic expression for the loss probability. This paper proves and promotes easily computable bounds based on the so-called call packing principle. Under call packing, a

  20. Call packing bounds for overflow queues

    NARCIS (Netherlands)

    N.M. van Dijk; E. van der Sluis

    2004-01-01

    Finite queueing loss systems are studied with overflow. For these systems there is no simple analytic expression for the loss probability or throughput. This paper aims to prove and promote easily computable bounds as based upon the so-called call packing principle. Under call packing a standard pro

  1. Development of an effective valve packing program

    Energy Technology Data Exchange (ETDEWEB)

    Hart, K.A.

    1996-12-01

    Current data now shows that graphite valve packing installed within the guidance of a controlled program produces not only reliable stem sealing but predictable running loads. By utilizing recent technological developments in valve performance monitoring for both MOV`s and AOV`s, valve packing performance can be enhanced while reducing maintenance costs. Once known, values are established for acceptable valve packing loads, the measurement of actual valve running loads via the current MOV/AOV diagnostic techniques can provide indication of future valve stem sealing problems, improper valve packing installation or identify the opportunity for valve packing program improvements. At times the full benefit of these advances in material and predictive technology remain under utilized due to simple past misconceptions associated with valve packing. This paper will explore the basis for these misconceptions, provide general insight into the current understanding of valve packing and demonstrate how with this new understanding and current valve diagnostic equipment the key aspects required to develop an effective, quality valve packing program fit together. The cost and operational benefits provided by this approach can be significant impact by the: elimination of periodic valve repacking, reduction of maintenance costs, benefits of leak-free valve operation, justification for reduced Post Maintenance Test Requirements, reduced radiation exposure, improved plant appearance.

  2. Difference packing arrays and systematic authentication codes

    Institute of Scientific and Technical Information of China (English)

    YIN Jianxing

    2004-01-01

    In this paper, a type of combinatorial design (called difference packing array)is proposed and used to give a construction of systematic authentication codes. Taking advantage of this construction, some new series of systematic authentication codes are obtainable in terms of existing difference packing arrays.

  3. Monitoring three-dimensional packings in microgravity.

    NARCIS (Netherlands)

    Yu, Peidong; Frank-Richter, Stefan; Börngen, Alexander; Sperl, Matthias

    2014-01-01

    We present results from experiments with granular packings in three dimensions in microgravity as realized on parabolic flights. Two different techniques are employed to monitor the inside of the packings during compaction: (1) X-ray radiography is used to measure in transmission the integrated fluc

  4. Pack Density Limitations of Hybrid Parachutes

    Science.gov (United States)

    Zwicker, Matthew L.; Sinclair, Robert J.

    2013-01-01

    The development and testing of the Orion crew capsule parachute system has provided a unique opportunity to study dense parachute packing techniques and limits, in order to establish a new baseline for future programs. The density of parachute packs has a significant influence on vibration loads, retention system stresses, and parachute mortar performance. Material compositions and pack densities of existing designs for space capsule recovery were compared, using the pack density of the Apollo main parachutes as the current baseline. The composition of parachutes has changed since Apollo, incorporating new materials such as Kevlar , Vectran , Teflon and Spectra . These materials have different specific densities than Nylon, so the densities of hybrid parachute packs cannot be directly compared to Nylon parachutes for determination of feasibility or volume allocation. Six parachute packs were evaluated in terms of weighted average solid density in order to achieve a non-dimensional comparison of packing density. Means of mitigating damage due to packing pressure and mortar firing were examined in light of the Capsule Parachute Assembly System (CPAS) and Apollo experience. Parachute design improvements including incorporation of modern materials and manufacturing processes serves to make CPAS the new knowledge base on which future spacecraft parachute systems will be built.

  5. Does Post Septoplasty Nasal Packing Reduce Complications?

    Directory of Open Access Journals (Sweden)

    Bijan Naghibzadeh

    2011-01-01

    Full Text Available The main issues in nasal surgery are to stabilize the nose in the good position after surgery and preserve the cartilages and bones in the favorable situation and reduce the risk of deviation recurrence. Also it is necessary to avoid the synechia formation, nasal valve narrowing, hematoma and bleeding. Due to the above mentioned problems and in order to solve and minimize them nasal packing, nasal splint and nasal mold have been advised. Patients for whom the nasal packing used may faced to some problems like naso-pulmonary reflex, intractable pain, sleep disorder, post operation infection and very dangerous complication like toxic shock syndrome. We have two groups of patients and three surgeons (one of the surgeons used post operative nasal packing in his patients and the two others surgeons did not.Complications and morbidities were compared in these two groups. Comparing the two groups showed that the rate of complication and morbidities between these two groups were same and the differences were not valuable, except the pain and discomfort post operatively and at the time of its removal. Nasal packing has several risks for the patients while its effects are not studied. Septoplasty can be safely performed without postoperative nasal packing. Nasal packing had no main findings that compensated its usage. Septal suture is one of the procedures that can be used as alternative method to nasal packing. Therefore the nasal packing after septoplasty should be reserved for the patients with increased risk of bleeding.

  6. Cluster and constraint analysis in tetrahedron packings.

    Science.gov (United States)

    Jin, Weiwei; Lu, Peng; Liu, Lufeng; Li, Shuixiang

    2015-04-01

    The disordered packings of tetrahedra often show no obvious macroscopic orientational or positional order for a wide range of packing densities, and it has been found that the local order in particle clusters is the main order form of tetrahedron packings. Therefore, a cluster analysis is carried out to investigate the local structures and properties of tetrahedron packings in this work. We obtain a cluster distribution of differently sized clusters, and peaks are observed at two special clusters, i.e., dimer and wagon wheel. We then calculate the amounts of dimers and wagon wheels, which are observed to have linear or approximate linear correlations with packing density. Following our previous work, the amount of particles participating in dimers is used as an order metric to evaluate the order degree of the hierarchical packing structure of tetrahedra, and an order map is consequently depicted. Furthermore, a constraint analysis is performed to determine the isostatic or hyperstatic region in the order map. We employ a Monte Carlo algorithm to test jamming and then suggest a new maximally random jammed packing of hard tetrahedra from the order map with a packing density of 0.6337.

  7. 7 CFR 51.1217 - Standard pack.

    Science.gov (United States)

    2010-01-01

    ... be ring faced and tightly packed with sufficient bulge to prevent any appreciable movement of the... the box. (d) Peaches packed in other type boxes such as wire-bound boxes and fiber-board boxes may be... than 10 percent of the packages in any lot may not meet these requirements. (i) “Well filled”...

  8. Pd Close Coupled Catalyst

    Institute of Scientific and Technical Information of China (English)

    Zhong Hua SHI; Mao Chu GONG; Yao Qiang CHEN

    2006-01-01

    A catalyst comprised novel high surface area alumina support was prepared to control emission of automobiles. The results showed that prepared catalyst could satisfy the requirements of a high performance close coupled catalyst for its good catalytic activity at low temperature and good stability at high temperature.

  9. Condensation in Nanoporous Packed Beds.

    Science.gov (United States)

    Ally, Javed; Molla, Shahnawaz; Mostowfi, Farshid

    2016-05-10

    In materials with tiny, nanometer-scale pores, liquid condensation is shifted from the bulk saturation pressure observed at larger scales. This effect is called capillary condensation and can block pores, which has major consequences in hydrocarbon production, as well as in fuel cells, catalysis, and powder adhesion. In this study, high pressure nanofluidic condensation studies are performed using propane and carbon dioxide in a colloidal crystal packed bed. Direct visualization allows the extent of condensation to be observed, as well as inference of the pore geometry from Bragg diffraction. We show experimentally that capillary condensation depends on pore geometry and wettability because these factors determine the shape of the menisci that coalesce when pore filling occurs, contrary to the typical assumption that all pore structures can be modeled as cylindrical and perfectly wetting. We also observe capillary condensation at higher pressures than has been done previously, which is important because many applications involving this phenomenon occur well above atmospheric pressure, and there is little, if any, experimental validation of capillary condensation at such pressures, particularly with direct visualization. PMID:27115446

  10. Hawking Colloquium Packed CERN Auditoriums

    CERN Multimedia

    2006-01-01

    Stephen Hawking's week long visit to CERN included an 'exceptional CERN colloquium' which filled six auditoriums. Stephen Hawking during his visit to the ATLAS experiment. Stephen Hawking, Lucasian Professor of Cambridge University, visited the Theory Unit of the Physics Department from 24 September to 1 October 2006. As part of his visit, he gave two lectures in the main auditorium - a theoretical seminar on 'The Semi-Classical Birth of The Universe', attended by about 120 specialists; and a colloquium titled 'The Origin of The Universe'. As a key public figure in theoretical physics, his presence was eagerly awaited on both occasions. Those who wanted to attend the colloquium had to arrive early and be equipped with plenty of patience. An hour before it was due to begin, the 400 capacity of the main auditorium was already full. The lecture, simultaneously broadcast to five other fully packed CERN auditoriums, was attended by an estimated total of 850. Stephen Hawking attracted a large CERN crowd, filling ...

  11. Deactivation by carbon of iron catalysts for indirect liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Bartholomew, C.H.

    1991-01-10

    Although promoted cobalt and iron catalysts for Fischer-Tropsch (FT) synthesis of gasoline feedstock were first developed more than three decades ago, a major technical problem still limiting the commercial use of these catalysts today is carbon deactivation. This report describes recent progress in a fundamental, three-year investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for FT synthesis, the objectives of which are to: determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation over a range of CO concentrations, CO:H{sub 2} ratios, and temperatures; and model the rates of deactivation of the same catalysts in fixed-bed reactors. To accomplish the above objectives, the project is divided into the following tasks: (1) determine the kinetics of reaction and of carbon deactivation during CO hydrogenation on Fe and Fe/K catalysts coated on monolith bodies. (2) Determine the reactivities and types of carbon deposited during reaction on the same catalysts from temperature-programmed-surface-reaction spectroscopy (TPSR) and transmission electron microscopy (TEM). Determine the types of iron carbides formed at various temperatures and H{sub 2}/CO ratios using x-ray diffraction and Moessbauer spectroscopy. (3) Develop mathematical deactivation models which include heat and mass transport contributions for FT synthesis is packed-bed reactors. Progress to date is described. 48 refs., 3 figs., 1 tab.

  12. A New Hydrophobic Catalyst for Tritium Separation from Nuclear Effluents

    International Nuclear Information System (INIS)

    The hydrophobic catalysts were originally conceived in Canada for the deuterium enrichment and tritium separation by hydrogen-liquid water isotopic exchange in nuclear field. Unlike the conventional hydrophilic catalysts, which becomes inefficient to direct contact with liquid water, the hydrophobic catalysts kept a high catalytic activity and stability, even under the direct contact with liquid water or in presence of humid gas. Based on the long experience of the authors, in the preparation, testing and evaluation of the performances of hydrophobic catalysts, and based on the reviewed references, this paper presents up-to-date R and D activities on the preparation methods and applications of the hydrophobic catalysts, in tritium separation. The objectives of the paper are: (1) to provide a database for selection of the most appropriate catalyst and catalytic packing for above mentioned processes, (2) to asses and to find a new procedure for preparation of a new improved hydrophobic catalyst. From reviewed references we consider that platinum remains the most active and efficient catalytic metal and the TEFLON is the best wetproofing agent. A new improved hydrophobic Pt-catalyst has been proposed and is now underway. The main steps and experimental conditions of preparation are largely discussed. A new wet-proofing agent and a new binding agents (titanium oxide, cerium oxide, zirconium oxide) with catalytic role are proposed and tested. The physico-structural parameters of new improved catalyst have been determined and are discussed in details. The new proposal is a promising idea to improve the performances of conventional hydrophobic Pt-catalysts

  13. A New hydrophobic catalyst for tritium separation from nuclear effluents

    International Nuclear Information System (INIS)

    Full text: The hydrophobic catalysts were originally conceived in Canada for the deuterium enrichment and tritium separation by hydrogen-liquid water isotopic exchange in nuclear field. Unlike the conventional hydrophilic catalysts, which becomes inefficient to direct contact with liquid water, the hydrophobic catalysts kept a high catalytic activity and stability, even under the direct contact with liquid water or in presence of humid gas. Based on the long experience of the authors, in the preparation, testing and evaluation of the performances of hydrophobic catalysts, and based on the reviewed references, this paper presents current R and D activities on the preparation methods and applications of the hydrophobic catalysts, in tritium separation. The objectives of the paper are: (1) to provide a database for selection of the most appropriate catalyst and catalytic packing for above mentioned processes; (2) to find and to asses a new procedure for preparation of a new improved hydrophobic catalyst. Based on reviewed references we concluded that platinum appears to be the most active and efficient catalytic metal while the Teflon is the best wet-proofing agent. A new improved hydrophobic Pt-catalyst has been proposed and its study is now underway. The main steps and experimental conditions of preparation are largely discussed. A new wet-proofing agent and new binding agents (titanium oxide, cerium oxide, zirconium oxide) with catalytic role were proposed and now are tested. The physico-structural parameters of newly improved catalyst have been determined and are discussed in details. The new proposal is a promising idea to improve the performances of conventional hydrophobic Pt-catalysts. (authors)

  14. An assessment on preparation methods and applications of hydrophobic Pt-catalyst in nuclear and environmental field

    International Nuclear Information System (INIS)

    Based on the long experience of the authors in the preparation, testing and evaluation of the performances of hydrophobic catalysts and based on the reviewed references, this paper presents up-to-date R and D activities on the preparation and application of hydrophobic catalysts for use in nuclear and environmental fields. Unlike the conventional hydrophilic catalysts, the hydrophobic catalysts repel the liquid water and allow the transport of the gaseous reactants and reaction products to and from catalytic active centers. For deuterium and tritium separation, over one hundred hydrophobic catalyst types have been prepared in different experimental conditions and by a large diversity of wet proofing methods. The influence of about twenty parameters on catalytic activity have been also studied. The purpose of this paper is: (1) to provide a database for preparation and selection of he most appropriate method for preparing an active hydrophobic catalyst, (2) to show how to use the hydrophobic catalyst and how to operate efficiently the reactor packed with hydrophobic catalyst, (3) to evaluate the performances and potentiality of hydrophobic catalysts in nuclear and environmental field, (4) evaluation of applications of hydrophobic catalysts in nuclear and environmental fields. As result, the following categories are shown: (1) the hydrophobic catalysts based on platinum and Teflon as wet-proofing proved to have the highest activity and the longest stability, (2) the utilization of hydrophobic catalyst as ordered mixed catalytic packing in the trickle bed or separated bed reactors is more efficient and has been entirely proved on industrial scale for tritium separation process, (3) the extension of the applications of hydrophobic catalysts for other processes which take place in the presence of saturated humidity or liquid water in environmental protection field. The merits of hydrophobic Pt-catalysts for tritium separation are discussed in comparison to other

  15. [Review: pathophysiology and methodology of nasal packing].

    Science.gov (United States)

    Beule, A G; Weber, R K; Kaftan, H; Hosemann, W

    2004-08-01

    Nasal packing is a frequent procedure to control spontaneous nasal bleeding or postoperative oozing following different types of nasal surgery. It strives for internal stabilization of the nasal framework and for optimizing wound healing by prevention of stenosis or synechia. A lot of different materials is used and there is no accepted standard concerning the type and application. A review on pathophysiology of the packed nose is given together with a survey on customary packing materials focussing on the specific merits, demerits and side-effects including economical aspects. PMID:15316896

  16. Improved Taxation Rate for Bin Packing Games

    Science.gov (United States)

    Kern, Walter; Qiu, Xian

    A cooperative bin packing game is a N-person game, where the player set N consists of k bins of capacity 1 each and n items of sizes a 1, ⋯ ,a n . The value of a coalition of players is defined to be the maximum total size of items in the coalition that can be packed into the bins of the coalition. We present an alternative proof for the non-emptiness of the 1/3-core for all bin packing games and show how to improve this bound ɛ= 1/3 (slightly). We conjecture that the true best possible value is ɛ= 1/7.

  17. Co-Assembled Supported Catalysts: Synthesis of Nano-Structured Supported Catalysts with Hierarchic Pores through Combined Flow and Radiation Induced Co-Assembled Nano-Reactors

    Directory of Open Access Journals (Sweden)

    Galip Akay

    2016-05-01

    Full Text Available A novel generic method of silica supported catalyst system generation from a fluid state is presented. The technique is based on the combined flow and radiation (such as microwave, thermal or UV induced co-assembly of the support and catalyst precursors forming nano-reactors, followed by catalyst precursor decomposition. The transformation from the precursor to supported catalyst oxide state can be controlled from a few seconds to several minutes. The resulting nano-structured micro-porous silica supported catalyst system has a surface area approaching 300 m2/g and X-ray Diffraction (XRD-based catalyst size controlled in the range of 1–10 nm in which the catalyst structure appears as lamellar sheets sandwiched between the catalyst support. These catalyst characteristics are dependent primarily on the processing history as well as the catalyst (Fe, Co and Ni studied when the catalyst/support molar ratio is typically 0.1–2. In addition, Ca, Mn and Cu were used as co-catalysts with Fe and Co in the evaluation of the mechanism of catalyst generation. Based on extensive XRD, Scanning Electron Microscopy (SEM and Transmission Electron Microscopy (TEM studies, the micro- and nano-structure of the catalyst system were evaluated. It was found that the catalyst and silica support form extensive 0.6–2 nm thick lamellar sheets of 10–100 nm planar dimensions. In these lamellae, the alternate silica support and catalyst layer appear in the form of a bar-code structure. When these lamellae structures pack, they form the walls of a micro-porous catalyst system which typically has a density of 0.2 g/cm3. A tentative mechanism of catalyst nano-structure formation is provided based on the rheology and fluid mechanics of the catalyst/support precursor fluid as well as co-assembly nano-reactor formation during processing. In order to achieve these structures and characteristics, catalyst support must be in the form of silane coated silica nano

  18. Multistep continuous-flow synthesis of (R)- and (S)-rolipram using heterogeneous catalysts

    Science.gov (United States)

    Tsubogo, Tetsu; Oyamada, Hidekazu; Kobayashi, Shū

    2015-04-01

    Chemical manufacturing is conducted using either batch systems or continuous-flow systems. Flow systems have several advantages over batch systems, particularly in terms of productivity, heat and mixing efficiency, safety, and reproducibility. However, for over half a century, pharmaceutical manufacturing has used batch systems because the synthesis of complex molecules such as drugs has been difficult to achieve with continuous-flow systems. Here we describe the continuous-flow synthesis of drugs using only columns packed with heterogeneous catalysts. Commercially available starting materials were successively passed through four columns containing achiral and chiral heterogeneous catalysts to produce (R)-rolipram, an anti-inflammatory drug and one of the family of γ-aminobutyric acid (GABA) derivatives. In addition, simply by replacing a column packed with a chiral heterogeneous catalyst with another column packed with the opposing enantiomer, we obtained antipole (S)-rolipram. Similarly, we also synthesized (R)-phenibut, another drug belonging to the GABA family. These flow systems are simple and stable with no leaching of metal catalysts. Our results demonstrate that multistep (eight steps in this case) chemical transformations for drug synthesis can proceed smoothly under flow conditions using only heterogeneous catalysts, without the isolation of any intermediates and without the separation of any catalysts, co-products, by-products, and excess reagents. We anticipate that such syntheses will be useful in pharmaceutical manufacturing.

  19. Two-Dimensional Bipyramid Plasmonic Nanoparticle Liquid Crystalline Superstructure with Four Distinct Orientational Packing Orders.

    Science.gov (United States)

    Shi, Qianqian; Si, Kae Jye; Sikdar, Debabrata; Yap, Lim Wei; Premaratne, Malin; Cheng, Wenlong

    2016-01-26

    Anisotropic plasmonic nanoparticles have been successfully used as constituent elements for growing ordered nanoparticle arrays. However, orientational control over their spatial ordering remains challenging. Here, we report on a self-assembled two-dimensional (2D) nanoparticle liquid crystalline superstructure (NLCS) from bipyramid gold nanoparticles (BNPs), which showed four distinct orientational packing orders, corresponding to horizontal alignment (H-NLCS), circular arrangement (C-NLCS), slanted alignment (S-NLCS), and vertical alignment (V-NLCS) of constituent particle building elements. These packing orders are characteristic of the unique shape of BNPs because all four packing modes were observed for particles with various sizes. Nevertheless, only H-NLCS and V-NLCS packing orders were observed for the free-standing ordered array nanosheets formed from a drying-mediated self-assembly at the air/water interface of a sessile droplet. This is due to strong surface tension and the absence of particle-substrate interaction. In addition, we found the collective plasmonic coupling properties mainly depend on the packing type, and characteristic coupling peak locations depend on particle sizes. Interestingly, surface-enhanced Raman scattering (SERS) enhancements were heavily dependent on the orientational packing ordering. In particular, V-NLCS showed the highest Raman enhancement factor, which was about 77-fold greater than the H-NLCS and about 19-fold greater than C-NLCS. The results presented here reveal the nature and significance of orientational ordering in controlling plasmonic coupling and SERS enhancements of ordered plasmonic nanoparticle arrays.

  20. Statistical inference for disordered sphere packings

    Directory of Open Access Journals (Sweden)

    Jeffrey Picka

    2012-01-01

    Full Text Available This paper gives an overview of statistical inference for disordered sphere packing processes. These processes are used extensively in physics and engineering in order to represent the internal structure of composite materials, packed bed reactors, and powders at rest, and are used as initial arrangements of grains in the study of avalanches and other problems involving powders in motion. Packing processes are spatial processes which are neither stationary nor ergodic. Classical spatial statistical models and procedures cannot be applied to these processes, but alternative models and procedures can be developed based on ideas from statistical physics.Most of the development of models and statistics for sphere packings has been undertaken by scientists and engineers. This review summarizes their results from an inferential perspective.

  1. Electroosmotic Driving Liquid Using Nanosilica Packed Column

    Institute of Scientific and Technical Information of China (English)

    Ling Xin CHEN; Guo An LUO; Tao WEN

    2005-01-01

    The electroosmotic pump (EOP) using nanosilica particles packed-bed column was experimentally studied. The relationship between flowrate, pressure and applied voltage of the pump, and pressure-flowrate (P-Q) characteristic were investigated.

  2. Packing circles and spheres on surfaces

    KAUST Repository

    Schiftner, Alexander

    2009-01-01

    Inspired by freeform designs in architecture which involve circles and spheres, we introduce a new kind of triangle mesh whose faces\\' incircles form a packing. As it turns out, such meshes have a rich geometry and allow us to cover surfaces with circle patterns, sphere packings, approximate circle packings, hexagonal meshes which carry a torsion-free support structure, hybrid tri-hex meshes, and others. We show how triangle meshes can be optimized so as to have the incircle packing property. We explain their relation to conformal geometry and implications on solvability of optimization. The examples we give confirm that this kind of meshes is a rich source of geometric structures relevant to architectural geometry. © 2009 ACM.

  3. Think Safety When Picking, Packing School Backpacks

    Science.gov (United States)

    ... 160523.html Think Safety When Picking, Packing School Backpacks Heavy, unbalanced loads can cause injury that is ... Aug. 19, 2016 (HealthDay News) -- Many students use backpacks to carry their school books and supplies, but ...

  4. Packing circles and spheres on surfaces

    KAUST Repository

    Schiftner, Alexander

    2009-12-01

    Inspired by freeform designs in architecture which involve circles and spheres, we introduce a new kind of triangle mesh whose faces\\' incircles form a packing. As it turns out, such meshes have a rich geometry and allow us to cover surfaces with circle patterns, sphere packings, approximate circle packings, hexagonal meshes which carry a torsion-free support structure, hybrid tri-hex meshes, and others. We show how triangle meshes can be optimized so as to have the incircle packing property. We explain their relation to conformal geometry and implications on solvability of optimization. The examples we give confirm that this kind of meshes is a rich source of geometric structures relevant to architectural geometry.

  5. Preparation of Weak Cation Exchange Packings Based on Monodisperse Poly (chloromethylstyrene-co-divinylbenzene) Particles and Its Chromatographic Properties

    Institute of Scientific and Technical Information of China (English)

    卫引茂; 陈强; 耿信笃

    2001-01-01

    Monodisperse poly ( chloromethylstyrene-co-divinylbenzene )particles were firstly prepared by a two-step swelling method.Based on this media, one kind of weak cation ion exchange packings was prepared. It was demonstrated that the prepared packings have comparative advantages for biopolymer separation with high column efficiency, low interstitial volume and low column backpressure, and have good resolution to proteins. The effects of salt concentration and pH of mobile phase on protein retentions were investigated. The properties of the weak cation ion exchange packings were evaluated by the unified retention model for mixed-mode interaction mechanison in ion exchange and hydrophobic interaction chromatography.

  6. Protein Packing Quality Using Delaunay Complexes

    DEFF Research Database (Denmark)

    Fonseca, Rasmus; Winter, Pawel; Karplus, Kevin

    2011-01-01

    A new method for estimating the packing quality of protein structures is presented. Atoms in high quality protein crystal structures are very uniformly distributed which is difficult to reproduce using structure prediction methods. Packing quality measures can therefore be used to assess structur...... respectively. Our results show that the developed method is correlated to the well-established RosettaHoles2 but three times faster....

  7. Packing of elastic wires in flexible shells

    Science.gov (United States)

    Vetter, R.; Wittel, F. K.; Herrmann, H. J.

    2015-11-01

    The packing problem of long thin filaments that are injected into confined spaces is of fundamental interest for physicists and biologists alike. How linear threads pack and coil is well known only for the ideal case of rigid containers, though. Here, we force long elastic rods into flexible spatial confinement borne by an elastic shell to examine under which conditions recently acquired knowledge on wire packing in rigid spheres breaks down. We find that unlike in rigid cavities, friction plays a key role by giving rise to the emergence of two distinct packing patterns. At low friction, the wire densely coils into an ordered toroidal bundle with semi-ellipsoidal cross-section, while at high friction, it packs into a highly disordered, hierarchic structure. These two morphologies are shown to be separated by a continuous phase transition. Our findings demonstrate the dramatic impact of friction and confinement elasticity on filamentous packing and might drive future research on such systems in physics, biology and even medical technology toward including these mutually interacting effects.

  8. Patchy particle packing under electric fields.

    Science.gov (United States)

    Song, Pengcheng; Wang, Yufeng; Wang, Yu; Hollingsworth, Andrew D; Weck, Marcus; Pine, David J; Ward, Michael D

    2015-03-01

    Colloidal particles equipped with two, three, or four negatively charged patches, which endow the particles with 2-fold, 3-fold, or tetrahedral symmetries, form 1D chains, 2D layers, and 3D packings when polarized by an AC electric field. Two-patch particles, with two patches on opposite sides of the particle (2-fold symmetry) pack into the cmm plane group and 3D packings with I4mm space group symmetry, in contrast to uncharged spherical or ellipsoidal colloids that typically crystallize into a face-centered ABC layer packing. Three-patch particles (3-fold symmetry) form chains having a 21 screw axis symmetry, but these chains pair in a manner such that each individual chain has one-fold symmetry but the pair has 21 screw axis symmetry, in an arrangement that aligns the patches that would favor Coulombic interactions along the chain. Surprisingly, some chain pairs form unanticipated double-helix regions that result from mutual twisting of the chains about each other, illustrating a kind of polymorphism that may be associated with nucleation from short chain pairs. Larger 2D domains of the three-patch particles crystallize in the p6m plane group with alignment (with respect to the field) and packing densities that suggest random disorder in the domains, whereas four-patch particles form 2D domains in which close-packed rows are aligned with the field.

  9. iTreePack: Protein Complex Side-Chain Packing by Dual Decomposition

    OpenAIRE

    Peng, Jian; Hosur, Raghavendra; Berger, Bonnie; Xu, Jinbo

    2015-01-01

    Protein side-chain packing is a critical component in obtaining the 3D coordinates of a structure and drug discovery. Single-domain protein side-chain packing has been thoroughly studied. A major challenge in generalizing these methods to protein complexes is that they, unlike monomers, often have very large treewidth, and thus algorithms such as TreePack cannot be directly applied. To address this issue, SCWRL4 treats the complex effectively as a monomer, heuristically excluding weak interac...

  10. A combined in situ XAS-XRPD-Raman study of Fischer-Tropsch synthesis over a carbon supported Co catalyst

    DEFF Research Database (Denmark)

    Tsakoumis, Nikolaos E.; Dehghan, Roya; Johnsen, Rune;

    2013-01-01

    . Post-treatment at 400 degrees C under H-2 atmosphere leads to sintering of the cobalt particles, while a CO treatment followed by H-2 treatment creates a catalyst rich in hexagonal close packed cobalt through the formation of a Co2C intermediate. (C) 2012 Elsevier B.V. All rights reserved....... spectroscopy, while changes in the gas phase were observed by mass spectrometry (MS). Transmission electron microscopy (TEM) was also applied to characterise the catalyst. The catalyst has a bimodal particle size distribution and exhibits a high deactivation rate. During the in situ study the catalyst appears...

  11. Snow Pack and Lake Ice Pack Remote Sensing using Wideband Autocorrelation Radiometry

    Science.gov (United States)

    Mousavi, S.; De Roo, R. D.; Sarabandi, K.; England, A. W.

    2015-12-01

    A novel microwave radiometric technique, wideband autocorrelation radiometry (WiBAR), offers a deterministic method of remotely sensing the propagation time τdelay of microwaves through low loss layers at the bottom of the atmosphere. Terrestrial examples are the snow and lake ice packs. This technique is based on the Planck radiation from the surface beneath the pack which travels upwards through the pack towards the radiometer; such a signal we call a direct signal. On the other hand, part of this radiation reflects back from the pack's upper interface then from its lower interface, before traveling towards the radiometer's antenna. Thus, there are two signals received by the radiometer, the direct signal and a delayed copy of it. The microwave propagation time τdelay through the pack yields a measure of its vertical extent. We report a time series of measurements of the ice pack on Lake Superior from February to April 2014 to demonstrate this technique. The observations are done at frequencies from 7 to 10 GHz. At these frequencies, the volume and surface scattering are small in the ice pack. This technique is inherently low-power since there is no transmitter as opposed to active remote sensing techniques. The results of this paper is to present the WiBAR technique and show that the microwave travel time within a dry snow pack and lake ice pack can be deterministically measured for different thicknesses using this technique.

  12. Alloy catalyst material

    DEFF Research Database (Denmark)

    2014-01-01

    The present invention relates to a novel alloy catalyst material for use in the synthesis of hydrogen peroxide from oxygen and hydrogen, or from oxygen and water. The present invention also relates to a cathode and an electrochemical cell comprising the novel catalyst material, and the process use...... of the novel catalyst material for synthesising hydrogen peroxide from oxygen and hydrogen, or from oxygen and water....

  13. Resin Catalyst Hybrids

    Institute of Scientific and Technical Information of China (English)

    S. Asaoka

    2005-01-01

    @@ 1Introduction: What are resin catalyst hybrids? There are typically two types of resin catalyst. One is acidic resin which representative is polystyrene sulfonic acid. The other is basic resin which is availed as metal complex support. The objective items of this study on resin catalyst are consisting of pellet hybrid, equilibrium hybrid and function hybrid of acid and base,as shown in Fig. 1[1-5].

  14. Preparation of biodiesel from soybean oil by using heterogeneous catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Ferdous, Kaniz; Rakib Uddin, M.; Islam, M.A. [Department of Chemical Engineering and Polymer Science, Shah Jalal University of Science and Technology, Sylhet 3114 (Bangladesh); Khan, Maksudur R. [Department of Chemical Engineering and Polymer Science, Shah Jalal University of Science and Technology, Sylhet 3114 (Bangladesh); Faculty of Chemical and Natural Resources Engineering, University Malaysia Pahang, 26300 Gambang, Kuantan, Pahang (Malaysia)

    2013-07-01

    The predicted shortage of fossil fuels and related environmental concerns has recently attracted significant attention to search alternative fuel. Biodiesel is one of the alternatives to fossil fuel. Now-a-days, most biodiesel is produced by the transesterification of oils using methanol and a homogeneous base catalyst. The use of homogeneous catalysts is normally limited to batch mode processing followed by a catalyst separation step. The immiscible glycerol phase, which accumulates during the course of the reaction, solubilizes the homogeneous base catalyst and therefore, withdraws from the reaction medium. Moreover, other difficulties of using homogeneous base catalysts relate to their sensitivity to free fatty acid (FFA) and water and resulting saponification phenomenon. High energy consumption and costly separation of the catalyst from the reaction mixture have inspired the use of heterogeneous catalyst. The use of heterogeneous catalysts does not lead to the formation of soaps through neutralization of FFA and saponification of oil. In the present paper, biodiesel was prepared from crude (soybean) oil by transesterification reaction using heterogeneous base catalyst name calcium oxide (CaO). Various reaction parameters were optimized and the biodiesel properties were evaluated.

  15. Preparation of biodiesel from soybean oil by using heterogeneous catalyst

    Directory of Open Access Journals (Sweden)

    Kaniz Ferdous, M. Rakib Uddin, Maksudur R. Khan, M. A. Islam

    2013-01-01

    Full Text Available The predicted shortage of fossil fuels and related environmental concerns has recently attracted significant attention to search alternative fuel. Biodiesel is one of the alternatives to fossil fuel. Now-a-days, most biodiesel is produced by the transesterification of oils using methanol and a homogeneous base catalyst. The use of homogeneous catalysts is normally limited to batch mode processing followed by a catalyst separation step. The immiscible glycerol phase, which accumulates during the course of the reaction, solubilizes the homogeneous base catalyst and therefore, withdraws from the reaction medium. Moreover, other difficulties of using homogeneous base catalysts relate to their sensitivity to free fatty acid (FFA and water and resulting saponification phenomenon. High energy consumption and costly separation of the catalyst from the reaction mixture have inspired the use of heterogeneous catalyst. The use of heterogeneous catalysts does not lead to the formation of soaps through neutralization of FFA and saponification of oil. In the present paper, biodiesel was prepared from crude (soybean oil by transesterification reaction using heterogeneous base catalyst name calcium oxide (CaO. Various reaction parameters were optimized and the biodiesel properties were evaluated.

  16. Research on the hydrogen-water isotope exchange reaction by Pt-SDB hydrophobic catalyst

    International Nuclear Information System (INIS)

    The authors study the Pt-SDB hydrophobic catalyst used in the hydrogen-water exchange reaction. Platinum is as active metal and the polystyrene divinylbenzene (SDB) is as hydrophobic carrier in the Pt-SDB hydrophobic catalyst. The experimental results show that the efficiency of catalytic exchange reaction is higher in random bed with a packing ratio of 1:1 mixture of catalyst and hydrophilic or 1:4 in order bed. The volume transfer coefficient increases with increasing temperature, but the trend is slow down when the temperature is above 60 degree C

  17. A biphasic oxidation of alcohols to aldehydes and ketones using a simplified packed-bed microreactor

    Directory of Open Access Journals (Sweden)

    Andrew Bogdan

    2009-04-01

    Full Text Available We demonstrate the preparation and characterization of a simplified packed-bed microreactor using an immobilized TEMPO catalyst shown to oxidize primary and secondary alcohols via the biphasic Anelli-Montanari protocol. Oxidations occurred in high yields with great stability over time. We observed that plugs of aqueous oxidant and organic alcohol entered the reactor as plugs but merged into an emulsion on the packed-bed. The emulsion coalesced into larger plugs upon exiting the reactor, leaving the organic product separate from the aqueous by-products. Furthermore, the microreactor oxidized a wide range of alcohols and remained active in excess of 100 trials without showing any loss of catalytic activity.

  18. Continuous Production of Structured Phospholipids in a Packed Red Reactor with Lipase from Thermomyces lanuginosa

    DEFF Research Database (Denmark)

    Vikbjerg, Anders Falk; Peng, Lifeng; Mu, Huiling;

    2005-01-01

    immobilized lipase from Thermomyces lanuginosa (Lipozyme TL IM) as catalyst. In the packed bed reactors, different parameters for the lipase-catalyzed acidolysis were elucidated such as solvent ratio (solvent system), temperature, substrate ratio, residence time, water content, and operation stability...... was favored by high substrate ratio between acyl donor and phospholipids, longer residence time, and higher reaction temperature. Under certain conditions, an incorporation of around 30% caprylic acid can be obtained in continuous operation with hexane as the solvent.......The possibilities of producing structured phospholipids by lipase-catalyzed acidolysis between soybean phospholipids and caprylic acid were examined in continuous packed bed enzyme reactors. Acidolysis reactions were performed in both a solvent system and a solvent-free system with the commercially...

  19. Towards the Rational Design of Nanoparticle Catalysts

    Science.gov (United States)

    Dash, Priyabrat

    This research is focused on development of routes towards the rational design of nanoparticle catalysts. Primarily, it is focused on two main projects; (1) the use of imidazolium-based ionic liquids (ILs) as greener media for the design of quasi-homogeneous nanoparticle catalysts and (2) the rational design of heterogeneous-supported nanoparticle catalysts from structured nanoparticle precursors. Each project has different studies associated with the main objective of the design of nanoparticle catalysts. In the first project, imidazolium-based ionic liquids have been used for the synthesis of nanoparticle catalysts. In particular, studies on recyclability, reuse, mode-of-stability, and long-term stability of these ionic-liquid supported nanoparticle catalysts have been done; all of which are important factors in determining the overall "greenness" of such synthetic routes. Three papers have been published/submitted for this project. In the first publication, highly stable polymer-stabilized Au, Pd and bimetallic Au-Pd nanoparticle catalysts have been synthesized in imidazolium-based 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6) ionic liquid (Journal of Molecular Catalysis A: Chemical, 2008, 286, 114). The resulting nanoparticles were found to be effective and selective quasi-homogeneous catalysts towards a wide-range of hydrogenation reactions and the catalyst solution was reused for further catalytic reactions with minimal loss in activity. The synthesis of very pure and clean ILs has allowed a platform to study the effects of impurities in the imidazolium ILs on nanoparticle stability. In a later study, a new mode of stabilization was postulated where the presence of low amounts of 1-methylimidazole has substantial effects on the resulting stability of Au and Pd-Au nanoparticles in these ILs (Chemical Communications, 2009, 812). In further continuation of this study, a comparative study involving four stabilization protocols for nanoparticle

  20. 27 CFR 24.308 - Bottled or packed wine record.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Bottled or packed wine... BUREAU, DEPARTMENT OF THE TREASURY LIQUORS WINE Records and Reports § 24.308 Bottled or packed wine record. A proprietor who bottles, packs, or receives bottled or packed beverage wine in bond...

  1. Quasistatic packings of droplets in flat microfluidic channels

    Science.gov (United States)

    Kadivar, Erfan

    2016-02-01

    As observed in recent experiments, monodisperse droplets self-assemble spontaneously in different ordered packings. In this work, we present a numerical study of the droplet packings in the flat rectangular microfluidic channels. Employing the boundary element method, we numerically solve the Stokes equation in two-dimension and investigate the appearance of droplet packing and transition between one and two-row packings of monodisperse emulsion droplets. By calculating packing force applied on the droplet interface, we investigate the effect of flow rate, droplet size, and surface tension on the packing configurations of droplets and transition between different topological packings.

  2. A review on packed bed solar energy storage systems

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Harmeet; Saini, R.P. [Alternate Hydro Energy Centre, Indian Institute of Technology Roorkee, Roorkee 247667 (India); Saini, J.S. [Mechanical and Industrial Engineering Department, Indian Institute of Technology Roorkee, Roorkee 247667 (India)

    2010-04-15

    Because of intermittent nature of solar energy, storage is required for uninterrupted supply in order to match the needs. Packed beds are generally used for storage of thermal energy from solar air heaters. A packed bed is a volume of porus media obtained by packing particles of selected material into a container. A number of studies carried out on packed beds for their performance analysis were reported in the literature. These studies included the design of packed beds, materials used for storage, heat transfer enhancement, flow phenomenon and pressure drop through packed beds. This paper presents an extensive review on the research carried out on packed beds. Based on the literature review, it is concluded that most of the studies carried out are on rocks and pebbles as packing material. A very few studies were conducted on large sized packing materials. Further no study has been reported so far on medium sized storage elements in packed beds. (author)

  3. [Research progress on the management of no packing after septoplasty].

    Science.gov (United States)

    Lu, Sheng; Zhang, Longcheng; Li, Jieen

    2016-01-01

    Packing the nose after septoplasty is common practice. The use of postoperative packing has been proposed to reduce the dead space between the subperichondrial flaps and minimize postoperative complications such as hemorrhage, septal hematoma, and formation of synechiae. Additionally, postoperative packing is thought to stabilize the remaining cartilaginous septum and minimize persistence or recurrence of septal deviation. Despite these theoretic advantages, evidence to support the use of postoperative packing is lacking. Additionally, nasal packing is not an innocuous procedure. The use of nasal packing actually cause these complications such as postop- erative pain, mucosal injury, bleeding, worsening of breathing due to sleep disorders, and postoperative infections. Routine use of anterior nasal packing after septoplasty should be challenged for not presenting proven benefit. As alternatives to traditional packing, septal suturing, septal stapler and fibrin glue have been used recently. The purpose of this article is to summarize the progress of traditional packing to no packing after septoplasty. PMID:27197467

  4. Direct contact condensation in packed beds

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yi; Klausner, James F.; Mei, Renwei; Knight, Jessica [Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, FL 32611 (United States)

    2006-12-15

    A diffusion driven desalination process was recently described where a very effective direct contact condenser with a packed bed is used to condense water vapor out of an air/vapor mixture. A laboratory scale direct contact condenser has been fabricated as a twin tower structure with two stages, co-current and countercurrent. Experiments have been operated in each stage with respective saturated air inlet temperatures of 36, 40 and 43{sup o}C. The temperature and humidity data have been collected at the inlet and exit of the packed bed for different water to air mass flow ratios that vary between 0 and 2.5. A one-dimensional model based on conservation principles has been developed, which predicts the variation of temperature, humidity, and condensation rate through the condenser stages. Agreement between the model and experiments is very good. It is observed that the countercurrent flow stage condensation effectiveness is significantly higher than that for the co-current stage. The condensation heat and mass transfer rates were found to decrease when water blockages occur within the packed bed. Using high-speed digital cinematography, it was observed that this problem can occur at any operating condition, and is dependent on the packing surface wetting characteristics. This observation is used to explain the requirement for two different empirical constants, depending on packing diameter, suggested by Onda for the air side mass transfer coefficient correlation. (author)

  5. Coalescence preference in dense packing of bubbles

    Science.gov (United States)

    Kim, Yeseul; Gim, Bopil; Gim, Bopil; Weon, Byung Mook

    2015-11-01

    Coalescence preference is the tendency that a merged bubble from the contact of two original bubbles (parent) tends to be near to the bigger parent. Here, we show that the coalescence preference can be blocked by densely packing of neighbor bubbles. We use high-speed high-resolution X-ray microscopy to clearly visualize individual coalescence phenomenon which occurs in micro scale seconds and inside dense packing of microbubbles with a local packing fraction of ~40%. Previous theory and experimental evidence predict a power of -5 between the relative coalescence position and the parent size. However, our new observation for coalescence preference in densely packed microbubbles shows a different power of -2. We believe that this result may be important to understand coalescence dynamics in dense packing of soft matter. This work (NRF-2013R1A22A04008115) was supported by Mid-career Researcher Program through NRF grant funded by the MEST and also was supported by Ministry of Science, ICT and Future Planning (2009-0082580) and by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry and Education, Science and Technology (NRF-2012R1A6A3A04039257).

  6. Magnetic catalyst bodies

    NARCIS (Netherlands)

    Teunissen, Wendy; Bol, A.A.; Geus, John W.

    2001-01-01

    After a discussion about the importance of the size of the catalyst bodies with reactions in the liquid-phase with a suspended catalyst, the possibilities of magnetic separation are dealt with. Deficiencies of the usual ferromagnetic particles are the reactivity and the clustering of the particles.

  7. Catalyst for Ammonia Oxidation

    DEFF Research Database (Denmark)

    2015-01-01

    The present invention relates to a bimetallic catalyst for ammonia oxidation, a method for producing a bimetallic catalyst for ammonia oxidation and a method for tuning the catalytic activity of a transition metal. By depositing an overlayer of less catalytic active metal onto a more catalytic...

  8. Heterogeneous hydrogenation catalysts

    International Nuclear Information System (INIS)

    The main types of heterogeneous catalysts used for hydrogenation, the methods for their preparation, and the structure and chemistry of their surfaces are considered, as well as the catalytic activity and the mechanism of action in the hydrogenation of unsaturated and aromatic compounds, of CO, and of carbonyl compounds and in the hydrorefining of fuels. Chief attention is paid to supported Ni catalysts, to the methods for their preparation and physicochemical studies, and to the development of novel catalytic systems through modification. A novel type of catalyst for hydrogenation, viz. metal carbides, is described. Some aspects of the mechanochemical treatment of hydrogenation catalysts, including in situ methods, are discussed. Sulfide catalysts for hydrotreating are also discussed in detail. The bibliography includes 340 references.

  9. Design of heterogeneous catalysts

    DEFF Research Database (Denmark)

    Frey, Anne Mette

    . Previously it has been shown that calcination of cobalt catalyst in a NO/He mixture resulted in improved catalytic activity compared to standard air calcined samples, since more homogenous cobalt particles with a narrow particle size distribution were formed. Unfortunately the C5+ selectivity decreased....... Since Mn is known to improve C5+ selectivity the addition of this promoter, combined with NO calcination, was studied. The influence of parameters such as Co:Mn ratio, drying conditions, and reduction temperatures on the catalytic performance were investigated. The promotion strategy turned out to work...... well, and the best catalyst prepared had a C5+ yield almost a factor of two higher than a standard air calcined Co catalyst. In the NH3-SCR reaction it is desirable to develop an active and stable catalyst for NOx removal in automotive applications, since the traditionally used vanadium-based catalyst...

  10. Packing of ganglioside-phospholipid monolayers

    DEFF Research Database (Denmark)

    Majewski, J.; Kuhl, T.L.; Kjær, K.;

    2001-01-01

    Using synchrotron grazing-incidence x-ray diffraction (GIXD) and reflectivity, the in-plane and out-of-plane structure of mixed ganglioside-phospholipid monolayers was investigated at the air-water interface. Mixed monolayers of 0, 5, 10, 20, and 100 mol% ganglioside GM, and the phospholipid dipa...... polymer groups. Indeed, the lack of packing disruptions by the oligosaccharide groups indicates that protein-GM, interactions, including binding, insertion, chain fluidization, and domain formation (lipid rafts), can be studied in 2-D monolayers using scattering techniques....... monolayers did not affect hydrocarbon tail packing (fluidization or condensation of the hydrocarbon region). This is in contrast to previous investigations of lipopolymer-lipid mixtures, where the packing structure of phospholipid monolayers was greatly altered by the inclusion of lipids bearing hydrophilic...

  11. In-situ Quasi-Instantaneous e-beam Driven Catalyst-Free Formation Of Crystalline Aluminum Borate Nanowires

    OpenAIRE

    Ignacio G. Gonzalez-Martinez; Thomas Gemming; Rafael Mendes; Alicja Bachmatiuk; Viktor Bezugly; Jens Kunstmann; Jürgen Eckert; Gianaurelio Cuniberti; Rümmeli, Mark H

    2016-01-01

    The catalyst-assisted nucleation and growth mechanisms for many kinds of nanowires and nanotubes are pretty well understood. At times, though, 1D nanostructures form without a catalyst and the argued growth modes have inconsistencies. One such example is the catalyst-free growth of aluminium borate nanowires. Here we develop an in-situ catalyst-free room temperature growth route for aluminium nanowires using the electron beam in a transmission electron microscope. We provide strong experiment...

  12. On the Multiple Packing Densities of Triangles

    OpenAIRE

    Sriamorn, Kirati

    2014-01-01

    Given a convex disk $K$ and a positive integer $k$, let $\\delta_T^k(K)$ and $\\delta_L^k(K)$ denote the $k$-fold translative packing density and the $k$-fold lattice packing density of $K$, respectively. Let $T$ be a triangle. In a very recent paper, K. Sriamorn proved that $\\delta_L^k(T)=\\frac{2k^2}{2k+1}$. In this paper, I will show that $\\delta_T^k(T)=\\delta_L^k(T)$.

  13. Lattice approaches to packed column simulations

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    This work presents a review of the findings into the ability of a digitally based particle packing algorithm, called DigiPac, to predict bed structure in a variety of packed columns, for a range of generic pellet shapes frequently used in the chemical and process engineering industries.Resulting macroscopic properties are compared with experimental data derived from both invasive and non-destructive measurement techniques.Additionally, fluid velocity distributions, through samples of the resulting bed structures, are analysed using lattice Boltzmann method (LBM) simulations and are compared against experimental data from the literature.

  14. Correlation between Voronoi volumes in disc packings

    OpenAIRE

    Zhao, Song-Chuan; Sidle, Stacy; Swinney, Harry L.; Schröter, Matthias

    2011-01-01

    We measure the two-point correlation of free Voronoi volumes in binary disc packings, where the packing fraction $\\phi_{\\rm avg}$ ranges from 0.8175 to 0.8380. We observe short-ranged correlations over the whole range of $\\phi_{\\rm avg}$ and anti-correlations for $\\phi_{\\rm avg}>0.8277$. The spatial extent of the anti-correlation increases with $\\phi_{\\rm avg}$ while the position of the maximum of the anti-correlation and the extent of the positive correlation shrink with $\\phi_{\\rm avg}$. We...

  15. Packed column supercritical fluid chromatography using stainless steel particles and water as a stationary phase.

    Science.gov (United States)

    Murakami, Jillian N; Thurbide, Kevin B

    2015-09-15

    Stainless steel (SS) particles were demonstrated as a novel useful support for a water stationary phase in packed column supercritical fluid chromatography using a CO2 mobile phase. Separations employed flame ionization detection, and the system was operated over a range of temperatures and pressures. Retention times reproduced well with RSD values of 2.6% or less. Compared to analogous separations employing a water stationary phase coated onto a SS capillary column, the packed column method provided separations that were about 10× faster, with nearly 8-fold larger analyte retention factors, while maintaining good peak shape and comparable column efficiency. Under normal operating conditions, the packed column contains about 131 ± 4 μL/m of water phase (around a 5% m/m coating), which is over 25× greater than the capillary column and also affords it a 20-fold larger sample capacity. Several applications of the packed column system are examined, and the results indicate that it is a useful alternative to the capillary column mode, particularly where analyte loads or sample matrix interference is a concern. Given its high sample capacity, this packed column method may also be useful to explore on a more preparative scale in the future.

  16. Catalysts, methods of making catalysts, and methods of use

    KAUST Repository

    Renard, Laetitia

    2014-03-06

    Embodiments of the present disclosure provide for catalysts, methods of making catalysts, methods of using catalysts, and the like. In an embodiment, the method of making the catalysts can be performed in a single step with a metal nanoparticle precursor and a metal oxide precursor, where a separate stabilizing agent is not needed.

  17. Operation of FCC with mixtures of regenerated and deactivated catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Spretz, R.; Sedran, U. [INCAPE, FIQ, UNL - CONICET, Instituto de Investigaciones en Catalisis y Petroquimica, Santiago del Estero 2654, 3000 Santa Fe (Argentina)

    2001-07-13

    The operation of FCC with mixtures of coked and regenerated catalyst was studied with a riser simulator reactor on two equilibrium catalysts at 550C. The coked catalysts maintain an activity level that enables them to be used in the mixtures. The catalytic performances of the regenerated catalysts were used as references against which the behaviors of 25:75 and 50:50 (coked:regenerated) mixtures were compared. It was observed that overall catoil has to be increased to maintain conversion. While the yields of gases, gasoline and LCO showed to be independent of the operative mode, changes were observed in the selectivity to light olefins C4-C6 that are mainly due to changes in the yields of the isoparaffins in the groups. In turn, these changes could be the consequence of the resulting density of paired acid sites in the zeolite components on hydrogen transfer reactions, due to the contributions by the coked and regenerated portions of catalysts. Coke yields in mixtures of coked and regenerated catalysts are not higher, which would allow increasing catalyst circulation without impacting on heat balance. The particularities of this new operation of FCC are very dependent on catalyst properties.

  18. Characterization of deactivated bio-oil hydrotreating catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Huamin; Wang, Yong

    2016-01-18

    Deactivation of bio-oil hydrotreating catalysts remains a significant challenge because of the poor quality of pyrolysis bio-oil input for hydrotreating and understanding their deactivation mode is critical to developing improved catalysts and processes. In this research, we developed an understanding of the deactivation of two-step bio-oil hydrotreating catalysts (sulfided Ru/C and sulfided CoMo/C) through detailed characterization of the catalysts using various complimentary analytical techniques. Severe fouling of both catalysts by carbonaceous species was the major form of deactivation, which is consistent with the significant loss of surface area and pore volume of both deactivated catalysts and the significant increase of the bulk density. Further analysis of the carbonaceous species by thermogravimetric analysis and x-ray photoelectron spectroscopy indicated that the carbonaceous species was formed by condensation reaction of active species such as sugars and sugar derivatives (aldehydes and ketones) in bio-oil feedstock during bio-oil hydrotreating under the conditions and catalysts used. Microscopy results did not show metal sintering of the Ru/C catalyst. However, X-ray diffraction indicated a probable transformation of the highly-active CoMoS phase in the sulfided CoMo/C catalyst to Co8S9 and MoS2 phase with low activity. Loss of the active site by transport of inorganic elements from the bio-oil and the reactor construction material onto the catalyst surface also might be a cause of deactivation as indicated by elemental analysis of spent catalysts.

  19. Catalyst in Basic Oleochemicals

    Directory of Open Access Journals (Sweden)

    Eva Suyenty

    2007-10-01

    Full Text Available Currently Indonesia is the world largest palm oil producer with production volume reaching 16 million tones per annum. The high crude oil and ethylene prices in the last 3 – 4 years contribute to the healthy demand growth for basic oleochemicals: fatty acids and fatty alcohols. Oleochemicals are starting to replace crude oil derived products in various applications. As widely practiced in petrochemical industry, catalyst plays a very important role in the production of basic oleochemicals. Catalytic reactions are abound in the production of oleochemicals: Nickel based catalysts are used in the hydrogenation of unsaturated fatty acids; sodium methylate catalyst in the transesterification of triglycerides; sulfonic based polystyrene resin catalyst in esterification of fatty acids; and copper chromite/copper zinc catalyst in the high pressure hydrogenation of methyl esters or fatty acids to produce fatty alcohols. To maintain long catalyst life, it is crucial to ensure the absence of catalyst poisons and inhibitors in the feed. The preparation methods of nickel and copper chromite catalysts are as follows: precipitation, filtration, drying, and calcinations. Sodium methylate is derived from direct reaction of sodium metal and methanol under inert gas. The sulfonic based polystyrene resin is derived from sulfonation of polystyrene crosslinked with di-vinyl-benzene. © 2007 BCREC UNDIP. All rights reserved.[Presented at Symposium and Congress of MKICS 2007, 18-19 April 2007, Semarang, Indonesia][How to Cite: E. Suyenty, H. Sentosa, M. Agustine, S. Anwar, A. Lie, E. Sutanto. (2007. Catalyst in Basic Oleochemicals. Bulletin of Chemical Reaction Engineering and Catalysis, 2 (2-3: 22-31.  doi:10.9767/bcrec.2.2-3.6.22-31][How to Link/DOI: http://dx.doi.org/10.9767/bcrec.2.2-3.6.22-31 || or local: http://ejournal.undip.ac.id/index.php/bcrec/article/view/6

  20. ALKALI RESISTANT CATALYST

    DEFF Research Database (Denmark)

    2008-01-01

    The present invention concerns the selective removal of nitrogen oxides (NOx) from gasses. In particular, the invention concerns a process, a catalyst and the use of a catalyst for the selective removal of nitrogen oxides in the presence of ammonia from gases containing a significant amount...... of alkali metal and/or alkali-earth compounds which process comprises using a catalyst combined of (i) a formed porous superacidic support, said superacidic support having an Hammett acidity stronger than Ho=-12, and (ii) a metal oxide catalytic component deposited on said superacidic support selected from...

  1. Bin Packing via Discrepancy of Permutations

    CERN Document Server

    Eisenbrand, Friedrich; Rothvoß, Thomas

    2010-01-01

    A well studied special case of bin packing is the 3-partition problem, where n items of size >1/4 have to be packed in a minimum number of bins of capacity one. The famous Karmarkar-Karp algorithm transforms a fractional solution of a suitable LP relaxation for this problem into an integral solution that requires at most O(log n) additional bins. The three-permutations-conjecture of Beck is the following. Given any 3 permutations on n symbols, one can color the symbols red and blue, such that in any interval of any of those permutations, the number of red and blue symbols differs only by a constant. Beck's conjecture is well known in the field of discrepancy theory. We establish a surprising connection between bin packing and Beck's conjecture: If the latter holds true, then the additive integrality gap of the 3-partition linear programming relaxation is bounded by a constant. This result indicates that improving approximability results for bin packing requires a better understanding of discrepancy theory.

  2. Close packing of rods on spherical surfaces

    Science.gov (United States)

    Smallenburg, Frank; Löwen, Hartmut

    2016-04-01

    We study the optimal packing of short, hard spherocylinders confined to lie tangential to a spherical surface, using simulated annealing and molecular dynamics simulations. For clusters of up to twelve particles, we map out the changes in the geometry of the closest-packed configuration as a function of the aspect ratio L/D, where L is the cylinder length and D the diameter of the rods. We find a rich variety of cluster structures. For larger clusters, we find that the best-packed configurations up to around 100 particles are highly dependent on the exact number of particles and aspect ratio. For even larger clusters, we find largely disordered clusters for very short rods (L/D = 0.25), while slightly longer rods (L/D = 0.5 or 1) prefer a global baseball-like geometry of smectic-like domains, similar to the behavior of large-scale nematic shells. Intriguingly, we observe that when compared to their optimal flat-plane packing, short rods adapt to the spherical geometry more efficiently than both spheres and longer rods. Our results provide predictions for experimentally realizable systems of colloidal rods trapped at the interface of emulsion droplets.

  3. Improved lower bound for online strip packing

    NARCIS (Netherlands)

    Harren, Rolf; Kern, Walter

    2015-01-01

    We study the online strip packing problem and derive an improved lower bound of ρ ≥ 2.589... for the competitive ratio of this problem. The construction is based on modified “Brown-Baker-Katseff sequences” (Brown et al. in Acta Inform. 18:207–225, 1982) using only two types of rectangles. In additio

  4. Close packing of rods on spherical surfaces.

    Science.gov (United States)

    Smallenburg, Frank; Löwen, Hartmut

    2016-04-28

    We study the optimal packing of short, hard spherocylinders confined to lie tangential to a spherical surface, using simulated annealing and molecular dynamics simulations. For clusters of up to twelve particles, we map out the changes in the geometry of the closest-packed configuration as a function of the aspect ratio L/D, where L is the cylinder length and D the diameter of the rods. We find a rich variety of cluster structures. For larger clusters, we find that the best-packed configurations up to around 100 particles are highly dependent on the exact number of particles and aspect ratio. For even larger clusters, we find largely disordered clusters for very short rods (L/D = 0.25), while slightly longer rods (L/D = 0.5 or 1) prefer a global baseball-like geometry of smectic-like domains, similar to the behavior of large-scale nematic shells. Intriguingly, we observe that when compared to their optimal flat-plane packing, short rods adapt to the spherical geometry more efficiently than both spheres and longer rods. Our results provide predictions for experimentally realizable systems of colloidal rods trapped at the interface of emulsion droplets. PMID:27131565

  5. Bacteriological Survey of AFD (Meat Packing Plant

    Directory of Open Access Journals (Sweden)

    T. N. Rawal

    1974-04-01

    Full Text Available The paper describes the manufacturing process of freeze dried mutton from slaughtering to packing and makes an assessment of microbial build-up on equipment, hands of workers and environment in which the mutton comes in contact during processing.

  6. Optimal online bounded space multidimensional packing

    NARCIS (Netherlands)

    Epstein, L.; Stee, R. van

    2003-01-01

    We solve an open problem in the literature by providing an online algorithm for multidimensional bin packing that uses only bounded space. We show that it is optimal among bounded space algorithms for any dimension $d>1$. Its asymptotic performance ratio is $(Pi_{infty})^d$, where $Pi_{infty}approx1

  7. Simple Cloud Chambers Using Gel Ice Packs

    Science.gov (United States)

    Kamata, Masahiro; Kubota, Miki

    2012-01-01

    Although cloud chambers are highly regarded as teaching aids for radiation education, school teachers have difficulty in using cloud chambers because they have to prepare dry ice or liquid nitrogen before the experiment. We developed a very simple and inexpensive cloud chamber that uses the contents of gel ice packs which can substitute for dry…

  8. Computational Modelling of Particle Packing in Concrete

    NARCIS (Netherlands)

    He, H.

    2010-01-01

    Physical particle packing is becoming a hot topic in concrete technology as more and more types of granular materials are used in concrete either for ecological or for engineering purposes. Although various analytical methods have been developed for optimum mixture design, comprehensive information

  9. The benefits of using customized procedure packs.

    Science.gov (United States)

    Baines, R; Colquhoun, G; Jones, N; Bateman, R

    2001-01-01

    Discrete item purchasing is the traditional approach for hospitals to obtain consumable supplies for theatre procedures. Although most items are relatively low cost, the management and co-ordination of the supply chain, raising orders, controlling stock, picking and delivering to each operating theatre can be complex and costly. Customized procedure packs provide a solution. PMID:11892113

  10. Porous bead packings for gas chromatography

    Science.gov (United States)

    Pollock, G. E.; Woeller, F. H.

    1979-01-01

    Porous polyaromatic packing beads have low polarity, high efficiency, short retention time, and may be synthesized in size range of 50 to 150 micrometers (100 to 270 mesh). Mechanically strong beads may be produced using various materials depending on elements and compounds to be identified.

  11. Production of syngas by ethanol reforming on Ni catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Catapan, Rafael C.; Oliveira, Amir A.M.; Donadel, Karina; Oliveira, Antonio Pedro N.; Rambo, Carlos R. [Federal University of Santa Catarina (UFSC), Florianopolis, SC (Brazil). Dept. of Mechanical Engineering. Lab. of Combustion and Thermal Systems Engineering], Emails: catapan@labcet.ufsc.br, donadel@emc.ufsc.br, pedronovaes@emc.ufsc.br, rambo@enq.ufsc.br; Oliveira, Therezinha Maria N.; Wagner, Theodoro M. [Universidade da Regiao de Joinville, SC (Brazil). Campus Universitario Bom Retiro], E-mails: tnovais@univille.br, theowag@terra.com.br

    2010-07-01

    In the recent literature, attention has been directed to the development of noble metals based catalysts for the ethanol reforming. However, the high costs and low availability of noble metals, e.g. platinum, as a resource justify the development of alternatives technologically, economically and environmentally viable such as Ni-based catalysts. Here, the thermal decomposition, partial oxidation and steam reforming of ethanol over SiO{sub 2} supported Ni was studied in a packed bed reactor in the 673 - 973 K temperature range at 1 atm. The catalyst was produced from 10% NiO, 5% of bentonite and 85% (wt.) of natural amorphous silica fibers (NASF). Scanning Electron Microscopy (SEM) evaluation revealed that particles of Ni were homogeneously distributed over the NASF. The X-ray diffraction (XRD) patterns did not show peaks related to silicates in all spectra, which indicates that there is no, apparently, interaction between the nickel catalysts and SiO{sub 2} or devitrification The reactions of ethanol on this catalyst occurs mainly by the dehydrogenation reaction generating acetaldehyde. Further, CH{sub 3}CHO is decomposed to CH{sub 4} and CO. In parallel to this route, ethanol is dehydrated producing ethylene, which is successively dehydrogenated in Ni sites generating carbon on the surface. Also, carbon can be produced by consecutive dehydrogenation of CH{sub 4}. Both reactions contribute to increase the production of H{sub 2} to values higher than those predicted by the thermodynamic equilibrium. (author)

  12. Catalyst for microelectromechanical systems microreactors

    Energy Technology Data Exchange (ETDEWEB)

    Morse, Jeffrey D. (Martinez, CA); Sopchak, David A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA); Reynolds, John G. (San Ramon, CA); Satcher, Joseph H. (Patterson, CA); Gash, Alex E. (Brentwood, CA)

    2011-11-15

    A microreactor comprising a silicon wafer, a multiplicity of microchannels in the silicon wafer, and a catalyst coating the microchannels. In one embodiment the catalyst coating the microchannels comprises a nanostructured material. In another embodiment the catalyst coating the microchannels comprises an aerogel. In another embodiment the catalyst coating the microchannels comprises a solgel. In another embodiment the catalyst coating the microchannels comprises carbon nanotubes.

  13. Catalyst for microelectromechanical systems microreactors

    Science.gov (United States)

    Morse, Jeffrey D.; Sopchak, David A.; Upadhye, Ravindra S.; Reynolds, John G.; Satcher, Joseph H.; Gash, Alex E.

    2010-06-29

    A microreactor comprising a silicon wafer, a multiplicity of microchannels in the silicon wafer, and a catalyst coating the microchannels. In one embodiment the catalyst coating the microchannels comprises a nanostructured material. In another embodiment the catalyst coating the microchannels comprises an aerogel. In another embodiment the catalyst coating the microchannels comprises a solgel. In another embodiment the catalyst coating the microchannels comprises carbon nanotubes.

  14. Power generation by packed-bed air-cathode microbial fuel cells

    KAUST Repository

    Zhang, Xiaoyuan

    2013-08-01

    Catalysts and catalyst binders are significant portions of the cost of microbial fuel cell (MFC) cathodes. Many materials have been tested as aqueous cathodes, but air-cathodes are needed to avoid energy demands for water aeration. Packed-bed air-cathodes were constructed without expensive binders or diffusion layers using four inexpensive carbon-based materials. Cathodes made from activated carbon produced the largest maximum power density of 676±93mW/m2, followed by semi-coke (376±47mW/m2), graphite (122±14mW/m2) and carbon felt (60±43mW/m2). Increasing the mass of activated carbon and semi-coke from 5 to ≥15g significantly reduced power generation because of a reduction in oxygen transfer due to a thicker water layer in the cathode (~3 or ~6cm). These results indicate that a thin packed layer of activated carbon or semi-coke can be used to make inexpensive air-cathodes for MFCs. © 2013 Elsevier Ltd.

  15. Epoxidation catalyst and process

    Science.gov (United States)

    Linic, Suljo; Christopher, Phillip

    2010-10-26

    Disclosed herein is a catalytic method of converting alkenes to epoxides. This method generally includes reacting alkenes with oxygen in the presence of a specific silver catalyst under conditions suitable to produce a yield of the epoxides. The specific silver catalyst is a silver nanocrystal having a plurality of surface planes, a substantial portion of which is defined by Miller indices of (100). The reaction is performed by charging a suitable reactor with this silver catalyst and then feeding the reactants to the reactor under conditions to carry out the reaction. The reaction may be performed in batch, or as a continuous process that employs a recycle of any unreacted alkenes. The specific silver catalyst has unexpectedly high selectivity for epoxide products. Consequently, this general method (and its various embodiments) will result in extraordinarily high epoxide yields heretofore unattainable.

  16. STUDIES ON HYDROISOMERIZATION CATALYSTS

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    C5/C6 alkane hydroisomerization is one of the most economical technologies for octane enhancement and has potential application in China in the next decade. The work about choice of hydroisomerization catalyst systems and scale-up in catalyst preparation was presented. Performance and regeneration behaviors tested in different laboratory reactors and a 1000 t/a pilot plant were discussed, which offers the information for commercial use of this process. Mechanism for coke formation was also proposed.

  17. New Catalysts for ROMP

    Institute of Scientific and Technical Information of China (English)

    H. Berke; C. Frech; A. Lhamazares; O. Blacque; H.W. Schmalle; C. Adlhart; P. Chen

    2005-01-01

    @@ 1Introduction Ring Opening Metathesis Polymerization (ROMP) is based on the olefin metathesis reaction, which requires transition metal catalysts. Mainly molybdenum, tungsten and ruthenium based catalysts have up to now been used. The "in-between" metal rhenium was only rarely applied in olefin metathesis reactions, and not at all in ROMP processes.We have found that cationic phosphine substituted dinitrosyl rhenium complexes[1]1a and 1b effectively catalyze ROMP of norbonene, dicyclopentadiene and of cyclooctene. See Fig. 1.

  18. Fundamental Studies on Two-Phase Gas-Liquid Flows Through Packed Beds in Microgravity

    Science.gov (United States)

    Balakotaiah, Vemuri; McCready, Mark J.; Motil, Brian J.

    2002-01-01

    In the typical operation of a packed-bed reactor, gas and liquid flow simultaneously through a fixed bed of solid particles. Depending on the application, the particles can be of various shapes and sizes and provide for intimate contact and high rates of transport between the phases needed to sustain chemical or biological reactions. The packing may also serve as either a catalyst or as a support for growing biological material. NASA has flown two of these packed-bed systems in a microgravity environment with limited or no success. The goal of this research is to develop models (with scale-up capability) needed for the design of the physicochemical equipment to carry out these unit operations in microgravity. New insight will also lead to improvements in normal gravity operations. Our initial experiment was flown using an existing KC-135 two-phase flow rig with a modified test section. The test section is a clear polycarbonate rectangular column with a depth of 2.54 cm, a width of 5.08 cm, and 60 cm long. The column was randomly packed with spherical glass beads by slowly dropping the beads into the bed. Even though care was taken in handling the column after it was filled with packing, the alternating high and low gravity cycles with each parabola created a slightly tighter packed bed than is typically reported for this type. By the usual method of comparing the weight difference of a completely dry column versus a column filled with water, the void fraction was found to be .345 for both sizes of beads used. Five flush mounted differential pressure transducers are spaced at even intervals with the first location 4 cm from the inlet port and the subsequent pressure transducers spaced at 13 cm intervals along the column. Differential pressure data was acquired at 1000 Hz to adequately observe pulse formation and characteristics. Visual images of the flow were recorded using a high-speed SVHS system at 500 frames per second. Over 250 different test conditions were

  19. Influence of catalyst deactivation on N2O emissions from automobiles

    International Nuclear Information System (INIS)

    Though estimates of the total N2O emitted by automobiles differ widely, automobiles are believed to be a significant source of non-agricultural anthropogenic N2O emissions. At the Third Conference of the Parties (COP-3) UN Framework Convention on Climate Change, held in Kyoto in 1997, N2O was designated as a greenhouse gas whose release into the atmosphere must be reduced. This action increased the need for more accurate estimates of automotive N2O emissions. The wide variation in estimates may be attributed to differences in emission test modes, types of catalysts, and levels of catalyst deactivation involved in the tests. In this study, we examined the influence of automotive catalyst deactivation on N2O emissions from the perspective of catalyst temperature frequency distribution. Using a model gas and deactivated three-way catalysts (TWCs), we applied the exhaust emission test modes of various countries. The results indicate that the factor behind the increase of N2O emissions following catalyst deactivation is not growth in N2O generation, but a decline in the N2O decomposition capability of the catalyst. It was also found that the effect of catalyst deactivation differs according to the catalyst composition and the emission test mode.(author)

  20. The statistical character of packed-bed heat transport properties

    OpenAIRE

    Wijngaarden, R.J.; Westerterp, K. R.

    1992-01-01

    Packed beds are essentially heterogeneous on a pellet scale. For random packed beds this heterogeneity causes a statistical character both on a pellet and bed scale. We discuss experimental results which deal with bed-scale statistics.

  1. Self-similar space-filling packings in three dimensions

    OpenAIRE

    Baram, Reza Mahmoodi; Herrmann, Hans J.

    2003-01-01

    We develop an algorithm to construct new self-similar space-filling packings of spheres. Each topologically different configuration is characterized by its own fractal dimension. We also find the first bi-cromatic packing known up to now.

  2. A multiscale methodology for CFD simulation of catalytic distillation bale packings

    Directory of Open Access Journals (Sweden)

    Ding Huidian

    2016-03-01

    Full Text Available A multiscale model for simulating the hydrodynamic behavior of catalytic bale packings has been proposed. This model combines computational fluid dynamics (CFD and macroscopic calculation. At small scale calculation, the CFD model includes 3-D volume-of-fluid (VOF simulation within representative elementary unit (REU under unsteady-state conditions. The REU constitutes gauze and catalyst domain, and porous media model is applied. At large scale calculation, a new mechanistic model deduced from the unit network model is employed. Based on liquid split proportion from small scale calculation, liquid distribution of the entire bale packing can be predicted. To evaluate different packing design, three common bale arrangements, i.e. one-bale, nine-bales and seven-bales, are compared. The area-weighted Christiansen uniformity coefficient is introduced to assess the distribution performance. A comparison between simulation and experimental results is made to validate the multiscale model. The present methodology is proved to be effective to analysis and design of catalytic distillation columns.

  3. Oxygen supply for CHO cells immobilized on a packed-bed of Fibra-Cel disks.

    Science.gov (United States)

    Meuwly, F; Loviat, F; Ruffieux, P-A; Bernard, A R; Kadouri, A; von Stockar, U

    2006-03-01

    Packed-bed bioreactors (PBR) have proven to be efficient systems to culture mammalian cells at very high cell density in perfusion mode, thus leading to very high volumetric productivity. However, the immobilized cells must be continuously supplied with all nutrients in sufficient quantities to remain viable and productive over the full duration of the perfusion culture. Among all nutrients, oxygen is the most critical since it is present at very low concentration due to its low solubility in cell culture medium. This work presents the development of a model for oxygenation in a packed-bed bioreactor system. The experimental system used to develop the model was a packed-bed of Fibra-Cel disk carriers used to cultivate Chinese Hamster Ovary cells at high density ( approximately 6.1 x 10(7) cell/mL) in perfusion mode. With the help of this model, it was possible to identify if a PBR system is operated in optimal or sub-optimal conditions. Using the model, two options were proposed, which could improve the performance of the basal system by about twofold, that is, by increasing the density of immobilized cells per carrier volume from 6.1 x 10(7) to 1.2 x 10(8) cell/mL, or by increasing the packed-bed height from 0.2 to 0.4 m. Both strategies would be rather simple to test and implement in the packed-bed bioreactor system used for this study. As a result, it would be possible to achieve a substantial improvement of about twofold higher productivity as compared with the basal conditions. PMID:16358288

  4. Oxygen supply for CHO cells immobilized on a packed-bed of Fibra-Cel disks.

    Science.gov (United States)

    Meuwly, F; Loviat, F; Ruffieux, P-A; Bernard, A R; Kadouri, A; von Stockar, U

    2006-03-01

    Packed-bed bioreactors (PBR) have proven to be efficient systems to culture mammalian cells at very high cell density in perfusion mode, thus leading to very high volumetric productivity. However, the immobilized cells must be continuously supplied with all nutrients in sufficient quantities to remain viable and productive over the full duration of the perfusion culture. Among all nutrients, oxygen is the most critical since it is present at very low concentration due to its low solubility in cell culture medium. This work presents the development of a model for oxygenation in a packed-bed bioreactor system. The experimental system used to develop the model was a packed-bed of Fibra-Cel disk carriers used to cultivate Chinese Hamster Ovary cells at high density ( approximately 6.1 x 10(7) cell/mL) in perfusion mode. With the help of this model, it was possible to identify if a PBR system is operated in optimal or sub-optimal conditions. Using the model, two options were proposed, which could improve the performance of the basal system by about twofold, that is, by increasing the density of immobilized cells per carrier volume from 6.1 x 10(7) to 1.2 x 10(8) cell/mL, or by increasing the packed-bed height from 0.2 to 0.4 m. Both strategies would be rather simple to test and implement in the packed-bed bioreactor system used for this study. As a result, it would be possible to achieve a substantial improvement of about twofold higher productivity as compared with the basal conditions.

  5. Power Cycle Testing of Press-Pack IGBT Chips

    OpenAIRE

    Frank, Øyvind Bjerke

    2014-01-01

    In this thesis the power cycling capability of individual press-pack IGBT chips is investigated. Press-pack is a packaging technology used for power semiconductors. For press-packs, both thermal and electrical contact to the semiconductor chip is obtained by the application of force on the package. Press-pack IGBTs is claimed by the manufacturers to be especially suitable for high-power applications with large variations in power output. Power cycle testing is an accelerated lifetime stress t...

  6. Pattern Generation by Bubble Packing Method

    Directory of Open Access Journals (Sweden)

    Goel V.K.

    2013-06-01

    Full Text Available This paper presents a new computational method forornamental Pattern design. The work is a concerted effort ofevaluation of various methods and the comparatively betterprocess is used for designing keeping in mind the accuracyrequirement for such Indian traditional ethnic designs. The firststep in the process to apply the CAD tools to design the patterns.Small semantics (profile are made using the mathematicalmodelling to make different pattern. Geometric constraints suchas scaling, rotation, transformation etc. are applied to make andmodify the profiles. To create patterns, obtains node locationsthrough a physically based particle simulation, which we call'bubble packing. Bubbles are closely packed on the corners,edges and on the surface domain, and nodes are placed at thecenters of the bubbles. Experimental results show that ourmethod can create high quality ornamental patterns. Thefabrication of the ornaments is on rapid prototype machine.

  7. Is incest common in gray wolf packs?

    Science.gov (United States)

    Smith, D.; Meier, T.; Geffen, E.; Mech, L.D.; Burch, J.W.; Adams, L.G.; Wayne, R.K.

    1997-01-01

    Wolf packs generally consist of a breeding pair and their maturing offspring that help provision and protect pack young. Because the reproductive tenure in wolves often is short, reproductively mature offspring might replace their parents, resulting in sibling or parent-offspring matings. To determine the extent of incestuous pairings, we measure relatedness based on variability in 20 microsatellite loci of mated pairs, parent-offspring pairs and siblings in two populations of gray wolves. Our 16 sampled mated pairs had values of relatedness not overlapping those of known parent-offspring or sibling dyads, which is consistent with their being unrelated or distantly related. These results suggest that full siblings or a parent and their offspring rarely mate and that incest avoidance is an important constraint on gray wolf behavioral ecology.

  8. Helix-packing motifs in membrane proteins.

    Science.gov (United States)

    Walters, R F S; DeGrado, W F

    2006-09-12

    The fold of a helical membrane protein is largely determined by interactions between membrane-imbedded helices. To elucidate recurring helix-helix interaction motifs, we dissected the crystallographic structures of membrane proteins into a library of interacting helical pairs. The pairs were clustered according to their three-dimensional similarity (rmsd universe of common transmembrane helix-pairing motifs is relatively simple. The largest cluster, which comprises 29% of the library members, consists of an antiparallel motif with left-handed packing angles, and it is frequently stabilized by packing of small side chains occurring every seven residues in the sequence. Right-handed parallel and antiparallel structures show a similar tendency to segregate small residues to the helix-helix interface but spaced at four-residue intervals. Position-specific sequence propensities were derived for the most populated motifs. These structural and sequential motifs should be quite useful for the design and structural prediction of membrane proteins.

  9. TIBER-II TF winding pack design

    International Nuclear Information System (INIS)

    The superconducting, toroidal-field (TF) coils in the Tokamak Ignition/Burn Engineering Reactor (TIBER II) are designed with cable-in-conduit conductor (CICC) using NB3Sn composite strands. To design the CICC winding pack, the authors used an optimization technique that maximizes the conductor stability without violating the constraints imposed by the structure, electrical insulation, quench protection, and fabrication technique. Detailed helium-properties codes calculate the heat removal along a flow path, and detailed field calculations determine the temperature, current, and stability margins. The conductor sheath is designed as distributed structure to partially support the combined in-plane and out-of-plane loads generated within the winding pack. Pancakes of the coil are wound, reacted, and insulated before being potted in the case. This design is aggressive but fully consistent with good engineering practice

  10. Body Packing: From Seizures to Laparotomy

    Directory of Open Access Journals (Sweden)

    Joanna M. Janczak

    2015-01-01

    Full Text Available Body packing is a common method for illegal drug trafficking. Complications associated with body packing can be severe and even lead to rapid death. Thus, a timely diagnosis is warranted. As most body packers initially do not show any symptoms, making a correct diagnosis can be rather challenging. We describe a case of a 41-year-old male, who was admitted with an epileptic seizure and who turned out to be a cocaine intoxicated body packer. Due to neurological and cardiovascular deterioration an emergency surgery was performed. Four bags of cocaine could be removed. We discuss the current management regimen in symptomatic and asymptomatic body packers and highlight pearls and pitfalls with diagnosis and treatment.

  11. Packing and Disorder in Substituted Fullerenes

    KAUST Repository

    Tummala, Naga Rajesh

    2016-07-15

    Fullerenes are ubiquitous as electron-acceptor and electron-transport materials in organic solar cells. Recent synthetic strategies to improve the solubility and electronic characteristics of these molecules have translated into a tremendous increase in the variety of derivatives employed in these applications. Here, we use molecular dynamics (MD) simulations to examine the impact of going from mono-adducts to bis- and tris-adducts on the structural, cohesive, and packing characteristics of [6,6]-phenyl-C60-butyric acid methyl ester (PCBM) and indene-C60. The packing configurations obtained at the MD level then serve as input for density functional theory calculations that examine the solid-state energetic disorder (distribution of site energies) as a function of chemical substitution. The variations in structural and site-energy disorders reflect the fundamental materials differences among the derivatives and impact the performance of these materials in thin-film electronic devices.

  12. Meromorphic Vector Fields and Circle Packings

    DEFF Research Database (Denmark)

    Dias, Kealey

    of dynamical systems, continuous and discrete, correspond to the study of differential equations (vector fields) and iteration of mappings respectively. In holomorphic dynamics, the systems studied are restricted to those described by holomorphic (complex analytic) functions or meromorphic (allowing poles...... to the development of a theory of discrete analytic functions, which is a new tool in conformal geometry that can be used to implement many of the classical tools from complex analysis. Circle packing is a relatively new subject that has a great potential for technological applications, specifically for imaging......The objective of the Ph.D. project is to initiate a classification of bifurcations of meromorphic vector fields and to clarify their relation to circle packings. Technological applications are to image analysis and to effective grid generation using discrete conformal mappings. The two branches...

  13. Myosin molecule packing within the vertebrate skeletal muscle thick filaments. A complete bipolar model.

    Science.gov (United States)

    Skubiszak, Ludmila; Kowalczyk, Leszek

    2002-01-01

    Computer modelling related to the real dimensions of both the whole filament and the myosin molecule subfragments has revealed two alternative modes for myosin molecule packing which lead to the head disposition similar to that observed by EM on the surface of the cross-bridge zone of the relaxed vertebrate skeletal muscle thick filaments. One of the modes has been known for three decades and is usually incorporated into the so-called three-stranded model. The new mode differs from the former one in two aspects: (1) myosin heads are grouped into asymmetrical cross-bridge crowns instead of symmetrical ones; (2) not the whole myosin tail, but only a 43-nm C-terminus of each of them is straightened and near-parallel to the filament axis, the rest of the tail is twisted. Concurrent exploration of these alternative modes has revealed their influence on the filament features. The parameter values for the filament models as well as for the building units depicting the myosin molecule subfragments are verified by experimental data found in the literature. On the basis of the new mode for myosin molecule packing a complete bipolar structure of the thick filament is created. PMID:12545190

  14. 48 CFR 211.272 - Alternate preservation, packaging, and packing.

    Science.gov (United States)

    2010-10-01

    ..., packaging, and packing. 211.272 Section 211.272 Federal Acquisition Regulations System DEFENSE ACQUISITION... Requirements Documents 211.272 Alternate preservation, packaging, and packing. Use the provision at 252.211-7004, Alternate Preservation, Packaging, and Packing, in solicitations which include...

  15. 48 CFR 552.211-87 - Export packing.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 4 2010-10-01 2010-10-01 false Export packing. 552.211-87... FORMS SOLICITATION PROVISIONS AND CONTRACT CLAUSES Text of Provisions and Clauses 552.211-87 Export packing. As prescribed in 511.204(b)(7), insert the following clause: Export Packing (JAN 2010)...

  16. 21 CFR 133.124 - Cold-pack cheese food.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Cold-pack cheese food. 133.124 Section 133.124 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD... Cheese and Related Products § 133.124 Cold-pack cheese food. (a)(1) Cold-pack cheese food is the...

  17. CoolPack – Simulation tools for refrigeration systems

    DEFF Research Database (Denmark)

    Jakobsen, Arne; Rasmussen, Bjarne D.; Andersen, Simon Engedal

    1999-01-01

    CoolPack is a collection of programs used for energy analysis and optimisation of refrigeration systems. CoolPack is developed at the Department of Energy Engineering at the Technical University of Denmark. The Danish Energy Agency finances the project. CoolPack is freeware and can be downloaded ...

  18. 27 CFR 24.255 - Bottling or packing wine.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Bottling or packing wine..., DEPARTMENT OF THE TREASURY LIQUORS WINE Storage, Treatment and Finishing of Wine Bottling, Packing, and Labeling of Wine § 24.255 Bottling or packing wine. (a) General. Proprietors of a bonded wine premises...

  19. 36 CFR 1002.16 - Horses and pack animals.

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 3 2010-07-01 2010-07-01 false Horses and pack animals. 1002... AND RECREATION § 1002.16 Horses and pack animals. The following are prohibited: (a) The use of animals other than those designated as “pack animals” for purposes of transporting equipment. (b) The use...

  20. 36 CFR 2.16 - Horses and pack animals.

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Horses and pack animals. 2.16... RESOURCE PROTECTION, PUBLIC USE AND RECREATION § 2.16 Horses and pack animals. The following are prohibited: (a) The use of animals other than those designated as “pack animals” for purposes of...

  1. 36 CFR 34.10 - Saddle and pack animals.

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Saddle and pack animals. 34... INTERIOR EL PORTAL ADMINISTRATIVE SITE REGULATIONS § 34.10 Saddle and pack animals. The use of saddle and pack animals is prohibited without a permit from the Superintendent....

  2. Investigations on a new internally-heated tubular packed-bed methanol–steam reformer

    KAUST Repository

    Nehe, Prashant

    2015-05-01

    Small-scale reformers for hydrogen production through steam reforming of methanol can provide an alternative solution to the demand of continuous supply of hydrogen gas for the operation of Proton Exchange Membrane Fuel Cells (PEMFCs). A packed-bed type reformer is one of the potential designs for such purpose. An externally heated reformer has issues of adverse lower temperature in the core of the reformer and significant heat loss to the environment thus impacting its performance. Experimental and numerical studies on a new concept of internally heated tubular packed-bed methanol-steam reformer have been reported in this paper with improved performance in terms of higher methanol conversion and reduced heat losses to surroundings. CuO/ZnO/Al2O3 is used as the catalyst for the methanol-steam reforming reaction and a rod-type electric heater at the center of the reactor is used for supplying necessary heat for endothermic steam reforming reaction. The vaporizer and the reformer unit with a constant volume catalyst bed are integrated in the annular section of a tubular reformer unit. The performance of the reformer was investigated at various operating conditions like feed rate of water-methanol mixture, mass of the catalyst and reforming temperature. The experimental and numerical results show that the methanol conversion and CO concentration increase with internal heating for a wide range of operating conditions. The developed reformer unit generates 50-80W (based on lower heating value) of hydrogen gas for applications in PEMFCs. For optimized design and operating conditions, the reformer unit produced 298sccm reformed gas containing 70% H2, 27% CO2 and 3% CO at 200-240°C which can produce a power output of 25-32W assuming 60% fuel cell efficiency and 80% of hydrogen utilization in a PEMFC. © 2015 Hydrogen Energy Publications, LLC.

  3. Dimer packings with gaps and electrostatics

    OpenAIRE

    Ciucu, Mihai

    2008-01-01

    Fisher and Stephenson conjectured in 1963 that the correlation function (defined by dimer packings) of two unit holes on the square lattice is rotationally invariant in the limit of large separation between the holes. We consider the same problem on the hexagonal lattice, extend it to an arbitrary finite collection of holes, and present an explicit conjectural answer. In recent work we managed to prove this conjecture in two fairly general cases. The quantity giving the answer can be regarded...

  4. Breakup of Pack Ice, Antarctic Ice Shelf

    Science.gov (United States)

    1991-01-01

    Breakup of Pack Ice along the periphery of the Antarctic Ice Shelf (53.5S, 3.0E) produced this mosaic of ice floes off the Antarctic Ice Shelf. Strong offshore winds, probably associated with strong katabatic downdrafts from the interior of the continent, are seen peeling off the edges of the ice shelf into long filamets of sea ice, icebergs, bergy bits and growlers to flow northward into the South Atlantic Ocean. 53.5S, 3.0E

  5. Gaseous phase benzene decomposition by non-thermal plasma coupled with nano titania catalyst

    International Nuclear Information System (INIS)

    Synergistic effect of atmospheric non-thermal plasma generated by dielectric barrier discharge and nano titania photo catalyst for benzene decomposition was tested. The paper indicated the effect of photo catalyst on removal efficiency of benzene, the compare of photo catalyst characteristic in different high temperatures by heat treatment, analysis of by-products. The results showed that the effect of degradation was visible by added photo catalyst in the plasma reactor. When concentration of benzene was 600 mg/m3 and electric field strength was 10 kV/cm, the removal efficiency of benzene was increased up to 81 % without photo catalyst. At the same condition, the removal efficiency was increased to 15 % higher with photo catalyst. Nano titania crystal was anatase crystal in 450 degC heat treatment which is best for benzene removal. The plasma reactor packed with photo catalyst shows a better selectivity of carbon dioxide than that without photo catalyst. By-products are mostly carbon dioxide, water and a small quantity of carbon monoxide

  6. A Controlled New Process of Pack Aluminization

    Institute of Scientific and Technical Information of China (English)

    HUANG Zhi-rong; MA Liu-bao; LI Pei-ning; XU Hong

    2004-01-01

    Aluminum diffusion coatings are often prepared by a pack aluminization technique, which is a specific variety of chemical vapor deposition (CVD) method. The coating process takes place in a bed containing a mixed powder that serves as a source of the coatings forming element. The phase composition of the diffusion layer obtained depends on the activity of the Al during the pack aluminization processing. In this work, the proportion of Al to special additive powder in the pack and the treatment temperature are adjusted to achieve the desired surface composition of aluminized layer. The aluminized 20 plain carbon steel and HK40 austenitic steel were investigated by optical microscopy (OM) , X-ray diffraction (XRD)and microsclerometer. The results showed that the desired FeAl, Fe3Al and NiAl were respectively formed on the 20 plain carbon steel and HK40 austenitic steel, and the aluminides FeAl3, Fe2Al5 or Ni2Al3, NiAl3 could be inhibited.

  7. A Controlled New Process of Pack Aluminization

    Institute of Scientific and Technical Information of China (English)

    HUANGZhi-rong; MALiu-bao; LIPei-ning; XUHong

    2004-01-01

    Aluminum diffusion coatings are often prepared by a pack aluminization technique, which is a specific variety of chemical vapor deposition (CVD) method. The coating process takes place in a bed containing a mixed powder that serves as a source of the coatings forming element. The phase composition of the diffusion layer obtained depends on the activity of the Al during the pack aluminization processing. In this work, the proportion of Al to special additive powder in the pack and the treatment temperature are adjusted to achieve the desired surface composition of aluminized layer. The aluminized 20 plain carbon steel and HK40 austenitic steel were investigated by optical microscopy (OM) , X-ray diffraction (XRD) and microsclerometer. The results showed that the desired FeAl, Fe3Al and NiAl were respectively formed on the 20 plain carbon steel and HK40 austenitic steel, and the aluminides FeAl3, Fe2Al5 or Ni2Al3, NiAl3 could be inhibited.

  8. Multi-pack Disposal Concepts for Spent Fuel (Rev. 0)

    Energy Technology Data Exchange (ETDEWEB)

    Hadgu, Teklu [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Hardin, Ernest [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Matteo, Edward N. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-12-01

    At the initiation of the Used Fuel Disposition (UFD) R&D campaign, international geologic disposal programs and past work in the U.S. were surveyed to identify viable disposal concepts for crystalline, clay/shale, and salt host media (Hardin et al., 2012). Concepts for disposal of commercial spent nuclear fuel (SNF) and high-level waste (HLW) from reprocessing are relatively advanced in countries such as Finland, France, and Sweden. The UFD work quickly showed that these international concepts are all “enclosed,” whereby waste packages are emplaced in direct or close contact with natural or engineered materials . Alternative “open” modes (emplacement tunnels are kept open after emplacement for extended ventilation) have been limited to the Yucca Mountain License Application Design (CRWMS M&O, 1999). Thermal analysis showed that, if “enclosed” concepts are constrained by peak package/buffer temperature, waste package capacity is limited to 4 PWR assemblies (or 9-BWR) in all media except salt. This information motivated separate studies: 1) extend the peak temperature tolerance of backfill materials, which is ongoing; and 2) develop small canisters (up to 4-PWR size) that can be grouped in larger multi-pack units for convenience of storage, transportation, and possibly disposal (should the disposal concept permit larger packages). A recent result from the second line of investigation is the Task Order 18 report: Generic Design for Small Standardized Transportation, Aging and Disposal Canister Systems (EnergySolution, 2015). This report identifies disposal concepts for the small canisters (4-PWR size) drawing heavily on previous work, and for the multi-pack (16-PWR or 36-BWR).

  9. Multi-Pack Disposal Concepts for Spent Fuel (Revision 1)

    Energy Technology Data Exchange (ETDEWEB)

    Hardin, Ernest [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Matteo, Edward N. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Hadgu, Teklu [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-01-01

    At the initiation of the Used Fuel Disposition (UFD) R&D campaign, international geologic disposal programs and past work in the U.S. were surveyed to identify viable disposal concepts for crystalline, clay/shale, and salt host media. Concepts for disposal of commercial spent nuclear fuel (SNF) and high-level waste (HLW) from reprocessing are relatively advanced in countries such as Finland, France, and Sweden. The UFD work quickly showed that these international concepts are all “enclosed,” whereby waste packages are emplaced in direct or close contact with natural or engineered materials . Alternative “open” modes (emplacement tunnels are kept open after emplacement for extended ventilation) have been limited to the Yucca Mountain License Application Design. Thermal analysis showed that if “enclosed” concepts are constrained by peak package/buffer temperature, that waste package capacity is limited to 4 PWR assemblies (or 9 BWR) in all media except salt. This information motivated separate studies: 1) extend the peak temperature tolerance of backfill materials, which is ongoing; and 2) develop small canisters (up to 4-PWR size) that can be grouped in larger multi-pack units for convenience of storage, transportation, and possibly disposal (should the disposal concept permit larger packages). A recent result from the second line of investigation is the Task Order 18 report: Generic Design for Small Standardized Transportation, Aging and Disposal Canister Systems. This report identifies disposal concepts for the small canisters (4-PWR size) drawing heavily on previous work, and for the multi-pack (16-PWR or 36-BWR).

  10. Method of synthesizing bulk transition metal carbide, nitride and phosphide catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Jae Soon; Armstrong, Beth L; Schwartz, Viviane

    2015-04-21

    A method for synthesizing catalyst beads of bulk transmission metal carbides, nitrides and phosphides is provided. The method includes providing an aqueous suspension of transition metal oxide particles in a gel forming base, dropping the suspension into an aqueous solution to form a gel bead matrix, heating the bead to remove the binder, and carburizing, nitriding or phosphiding the bead to form a transition metal carbide, nitride, or phosphide catalyst bead. The method can be tuned for control of porosity, mechanical strength, and dopant content of the beads. The produced catalyst beads are catalytically active, mechanically robust, and suitable for packed-bed reactor applications. The produced catalyst beads are suitable for biomass conversion, petrochemistry, petroleum refining, electrocatalysis, and other applications.

  11. Crystallographic dependence of CO activation on cobalt catalysts: HCP versus FCC.

    Science.gov (United States)

    Liu, Jin-Xun; Su, Hai-Yan; Sun, Da-Peng; Zhang, Bing-Yan; Li, Wei-Xue

    2013-11-01

    Identifying the structure sensitivity of catalysts in reactions, such as Fischer-Tropsch synthesis from CO and H2 over cobalt catalysts, is an important yet challenging issue in heterogeneous catalysis. Based on a first-principles kinetic study, we find for the first time that CO activation on hexagonal close-packed (HCP) Co not only has much higher intrinsic activity than that of face centered-cubic (FCC) Co but also prefers a different reaction route, i.e., direct dissociation with HCP Co but H-assisted dissociation on the FCC Co. The origin is identified from the formation of various denser yet favorable active sites on HCP Co not available for FCC Co, due to their distinct crystallographic structure and morphology. The great dependence of the activity on the crystallographic structure and morphology of the catalysts revealed here may open a new avenue for better, stable catalysts with maximum mass-specific reactivity.

  12. Supported organoiridium catalysts for alkane dehydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Baker, R. Thomas; Sattelberger, Alfred P.; Li, Hongbo

    2013-09-03

    Solid supported organoiridium catalysts, a process for preparing such solid supported organoiridium catalysts, and the use of such solid supported organoiridium catalysts in dehydrogenation reactions of alkanes is provided. The catalysts can be easily recovered and recycled.

  13. Deactivation-resistant catalyst for selective catalyst reduction of NOx

    OpenAIRE

    Jensen, Anker Degn; Castellino, Francesco; Rams, Per Donskov; Pedersen, Jannik Blaabjerg; Putluru, Siva Sankar Reddy

    2011-01-01

    The present invention relates to a catalyst for selective catalytic reduction of NOx in alkali metal containing flue gas using ammonia as reductant, the catalyst comprising a surface with catalytically active sites, wherein the surface is at least partly coated with a coating comprising at least one metal oxide. In another aspect the present invention relates to the use of said catalyst and to a method of producing said catalyst. In addition, the present invention relates to a method of treat...

  14. Hydrophobic catalyst applications in the nuclear field and in environmental studies

    International Nuclear Information System (INIS)

    The paper presents methods of preparation and applications of hydrophobic platinum catalysts in nuclear field and environmental protection. These catalysts allow the transport of gaseous reactants and reaction products to and from catalytic active centers since the pore blocking by water is avoided. Hence the activity and stability of the catalysts increase and isotopic exchange columns with simpler internal structure can be achieved. The aim of the paper is: 1. to give a data base regarding the preparation methods of the optimal catalyst type; 2. to indicate the utilization and operation procedures of hydrophobic catalysts with mixed and simple packings; 3. to evaluate the performances and applications of hydrophobic catalysts. Over one hundred of hydrophobic catalysts of the active metal/support type were prepared in our laboratory. Hydrophobic features were obtained by different methods like these: - coating a hydrophilic conventional catalyst with a hydrophobic agent such as silicone or teflon; - supporting the active metal directly into the pores of a hydrophobic support; - mixing the teflon powder with a hydrophilic conventional catalyst; coating the support with teflon followed by the impregnation with the precursor of the active metal. The most important application of these catalysts is detritiation of the heavy water used as moderator and coolant in CANDU type reactors. Build-up of tritium in heavy water following the neutron capture by deuterium leads to a reduction in the moderating properties and at the same time leads to a contamination hazard for both operation personnel and environment. Tritium recovery leads this way to both improving the moderating qualities of the heavy water and obtaining valuable pure tritium of high importance in fusion research and other laboratory studies. One gram of tritium costs about USD 10,000. The physical chemical process is water-hydrogen catalyzed isotopic exchange. Also discussed in the paper is the separation of

  15. Highly efficient capillary columns packed with superficially porous particles via sequential column packing.

    Science.gov (United States)

    Treadway, James W; Wyndham, Kevin D; Jorgenson, James W

    2015-11-27

    Highly efficient capillary columns packed with superficially porous particles were created for use in ultrahigh pressure liquid chromatography. Superficially porous particles around 1.5μm in diameter were packed into fused silica capillary columns with 30, 50, and 75μm internal diameters. To create the columns, several capillary columns were serially packed from the same slurry, with packing progress plots being generated to follow the packing of each column. Characterization of these columns using hydroquinone yielded calculated minimum reduced plate heights as low as 1.24 for the most efficient 30μm internal diameter column, corresponding to over 500,000plates/m. At least one highly efficient column (minimum reduced plate height less than 2) was created for all three of the investigated column inner diameters, with the smallest diameter columns having the highest efficiency. This study proves that highly efficient capillary columns can be created using superficially porous particles and shows the efficiency potential of these particles.

  16. Eating less from bigger packs: Preventing the pack size effect with diet primes.

    Science.gov (United States)

    Versluis, Iris; Papies, Esther K

    2016-05-01

    An increase in the package size of food has been shown to lead to an increase in energy intake from this food, the so-called pack size effect. Previous research has shown that providing diet-concerned individuals with a reminder, or prime, of their dieting goal can help them control their consumption. Here, we investigated if providing such a prime is also effective for reducing the magnitude of the pack size effect. We conducted two experiments in which the cover of a dieting magazine (Experiment 1) and diet-related commercials (Experiment 2) served as diet goal primes. Both experiments had a 2 (pack size: small vs. large) × 2 (prime: diet vs. control) × 2 (dietary restraint: high vs. low) between participants design. We measured expected consumption of four snack foods in Experiment 1 (N = 477), and actual consumption of M&M's in Experiment 2 (N = 224). Results showed that the diet prime reduced the pack size effect for both restrained and unrestrained eaters in Experiment 1 and for restrained eaters only in Experiment 2. Although effect sizes were small, these findings suggest that a diet prime motivates restrained eaters to limit their consumption, and as a result the pack size has less influence on the amount consumed. We discuss limitations of this research as well as potential avenues for further research and theoretical and practical implications. PMID:26876911

  17. Numerical Simulation of Random Close Packing with Tetrahedra

    Institute of Scientific and Technical Information of China (English)

    LI Shui-Xiang; ZHAO Jian; ZHOU Xuan

    2008-01-01

    The densest packing of tetrahedra is still an unsolved problem.Numerical simulations of random close packing of tetrahedra are carried out with a sphere assembly model and improved relaxation algorithm. The packing density and average contact number obtained for random close packing of regular tetrahedra is 0.6817 and 7.21respectively,while the values of spheres are 0.6435 and 5.95.The simulation demonstrates that tetrahedra can be randomly packed denser than spheres.Random close packings of tetrahedra with a range of height are simulated as well.We find that the regular tetrahedron might be the optimal shape which gives the highest packing density of tetrahedra.

  18. A STUDY OF THE COMPLICATIONS OF RIBBON GAUZE IMPREGNATED WITH SOFRAMYCIN NASAL PACKING AND MEROCEL PACKING IN POST SEPTOPLASTY PATIENTS

    Directory of Open Access Journals (Sweden)

    Swaroop Dev

    2015-03-01

    Full Text Available OBJECTIVE: To compare the complications of Ribbon Gauze Impregnated with soframycin nasal packing and Merocel Packing in Post Septoplasty patients. MATERIALS AND METHODS : A randomized trial was conducted in the department of Otorhinolaryngology and Head and Neck Sur gery of Sri Siddhartha Medical College, Tumkur, Karnataka from July 2011 - September 2014. In our study 100 patients who underwent septoplasty were divided into two groups. Group A and Group B consisting of 50 patients each. The Patients were alternately ass igned into the two groups. In patients of Group A Merocel packing (size 8cm impregnated with soframycin ointement was done. In patients of Group B Ribbon Gauze Impregnated with Soframycin packing was done. Cottle’s maxillary - premaxillary septoplasty appr oach was employed in all the 100 patients under local anaesthesia. The complications of nasal packing like Bleeding during pack in situ, Bleeding during pack removal, Pain score during pack in - situ, Pain score during pack removal, Septal Hematoma, nasal sy nechia and Septal perforation were compared between the two groups. Both the groups were followed up for 8 weeks. RESULTS: In our study group A patients show statistically significant less pain score while pack was in situ and during pack removal compared with group B patients. Bleeding during pack removal and development of synechia in group A patients were statistically les s compared to group B patients. None of the patients developed septal hematoma and septal perforation in both the groups. CONCLUSION: The use of Merocel nasal packing in post septoplasty patients have better compliance with respect to pain compared with co nventional ribbon gauze. Although bleeding is well controlled with both Merocel and Ribbon gauze when the pack is in situ, Merocel cause less bleeding during pack removal and less nasal synechia compared to conventional ribbon gauze.

  19. Olefin metathesis catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Kukes, S.G.; Banks, R.L.

    1986-05-20

    A process is described for preparing a disproportionation catalyst comprising admixing a catalytically effective amount of a calcined and activated catalyst consisting essentially of at least one metal oxide selected from molybdenum oxide and tungsten oxide and a support containing a major proportion of silica or alumina with a promoting amount of a methylating agent selected from the group consisting of dimethyl sulfate, dimethylsulfoxide, trimethyloxonium tetrafluorborate, methyl iodide, and methyl bromide, and subjecting same to inert atmospheric conditions for the methylating agent to promote the activity of the calcined molybdenum and tungsten oxides for the disproportionation of olefins.

  20. Aerogel derived catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, J. G., LLNL

    1996-12-11

    Aerogels area class of colloidal materials which have high surface areas and abundant mesoporous structure. SiO{sub 2} aerogels show unique physical, optical and structural properties. When catalytic metals are incorporated in the aerogel framework, the potential exists for new and very effective catalysts for industrial processes. Three applications of these metal-containing SiO{sub 2} aerogels as catalysts are briefly reviewed in this paper--NO{sub x} reduction, volatile organic compound destruction, and partial oxidation of methane.

  1. Dynamics of Catalyst Nanoparticles

    DEFF Research Database (Denmark)

    Hansen, Thomas Willum; Cavalca, Filippo; Wagner, Jakob Birkedal

    under gas exposure, dynamic phenomena such as sintering and growth can be observed with sub-Ångstrøm resolution. Metal nanoparticles contain the active sites in heterogeneous catalysts, which are important for many industrial applications including the production of clean fuels, chemicals...... and pharmaceuticals, and the cleanup of exhaust from automobiles and stationary power plants. Sintering, or thermal deactivation, is an important mechanism for the loss of catalyst activity. In order to initiate a systematic study of the dynamics and sintering of nanoparticles, various catalytic systems have been...

  2. Effects of Airlfow Field on Droplets Diameter inside the Corrugated Packing of a Rotating Packed Bed

    Institute of Scientific and Technical Information of China (English)

    Xu Chengcheng; Jiao Weizhou; Liu Youzhi; Guo Liang; Yuan Zhiguo; Zhang Qiaoling

    2014-01-01

    Rotating packing bed (RPB) has a better mixing performance than traditional mixers and shows potential applica-tion in the petroleum industry. However, acquisition of information about the mixing process directly through experiments is dififcult because of the compact structure and complex multiphase lfow pattern in RPB. To study the mixing character-istic, Fluent, the computational lfuid dynamics (CFD) software, was used to explore the effect of airlfow ifeld on droplet diameter. For conducting calculations, the gas-liquid two-phase lfow inside the packing was simulated with the RNG k-εturbulence model and the Lagrange Discrete Phase Model (DPM), respectively. The numerical calculation results showed that coalescence and breakup of droplets can take place in the gas phase lfow inside the packing and can be strengthened with increased rotating speed, thereby leading to the enlargement of the average diameter.

  3. Deactivation-resistant catalyst for selective catalyst reduction of NOx

    DEFF Research Database (Denmark)

    2011-01-01

    The present invention relates to a catalyst for selective catalytic reduction of NOx in alkali metal containing flue gas using ammonia as reductant, the catalyst comprising a surface with catalytically active sites, wherein the surface is at least partly coated with a coating comprising at least...... one metal oxide. In another aspect the present invention relates to the use of said catalyst and to a method of producing said catalyst. In addition, the present invention relates to a method of treating an catalyst for conferring thereon an improved resistance to alkali poisoning....

  4. Bifunctional Anode Catalysts for Direct Methanol Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Rossmeisl, Jan; Ferrin, Peter A.; Tritsaris, Georgios A.; Nilekar, Anand U.; Koh, Shirlaine; Bae, Sang Eun; Brankovic, Stanko R.; Strasser, Peter; Mavrikakis, Manos

    2012-06-13

    Using the binding energy of OH* and CO* on close-packed surfaces as reactivity descriptors, we screen bulk and surface alloy catalysts for methanol electro-oxidation activity. Using these two descriptors, we illustrate that a good methanol electro-oxidation catalyst must have three key properties: (1) the ability to activate methanol, (2) the ability to activate water, and (3) the ability to react off surface intermediates (such as CO* and OH*). Based on this analysis, an alloy catalyst made up of Cu and Pt should have a synergistic effect facilitating the activity towards methanol electro-oxidation. Using these two reactivity descriptors, a surface PtCu3 alloy is proposed to have the best catalytic properties of the Pt–Cu model catalysts tested, similar to those of a Pt–Ru bulk alloy. To validate the model, experiments on a Pt(111) surface modified with different amounts of Cu adatoms are performed. Adding Cu to a Pt(111) surface increases the methanol oxidation current by more than a factor of three, supporting our theoretical predictions for improved electrocatalysts.

  5. Comparing Online Algorithms for Bin Packing Problems

    DEFF Research Database (Denmark)

    Epstein, Leah; Favrholdt, Lene Monrad; Kohrt, Jens Svalgaard

    2012-01-01

    The relative worst-order ratio is a measure of the quality of online algorithms. In contrast to the competitive ratio, this measure compares two online algorithms directly instead of using an intermediate comparison with an optimal offline algorithm. In this paper, we apply the relative worst......-order ratio to online algorithms for several common variants of the bin packing problem. We mainly consider pairs of algorithms that are not distinguished by the competitive ratio and show that the relative worst-order ratio prefers the intuitively better algorithm of each pair....

  6. Importance of packing in spiral defect chaos

    Indian Academy of Sciences (India)

    Kapilanjan Krishna

    2008-04-01

    We develop two measures to characterize the geometry of patterns exhibited by the state of spiral defect chaos, a weakly turbulent regime of Rayleigh-Bénard convection. These describe the packing of contiguous stripes within the pattern by quantifying their length and nearest-neighbor distributions. The distributions evolve towards unique distribution with increasing Rayleigh number that suggests power-law scaling for the dynamics in the limit of infinite system size. The techniques are generally applicable to patterns that are reducible to a binary representation.

  7. Ethylene Oligomerization and Polymerization: Alternative Iron Catalysts beyond 2,6-Bisiminopyridyl Iron Complexes

    Institute of Scientific and Technical Information of China (English)

    Suyun Jie; Shu Zhang; Wenjuan Zhang; Yingxia Song; Junxian Hou; Wen-Hua Sun

    2005-01-01

    @@ 1Introduction Polyolefin industry arrives the option to transfer from multiple-site systems of the classical Ziegler-Natta catalysts to more sophisticated single-site catalysts. The late-transition metal compounds were traditionally assumed with poor polymerization properties due to the highly competitive chain-termination step, and produced the short-chain oligomers up to 40 carbon atoms (SHOP catalysts). Recently the polyolefins employing latetransition metal complexes as catalysts became a hot research subject with the pioneering works by Brookhart and Gibson. It is promising for nickel catalysts to use solely ethylene as monomer for highly branched polyethylenes, and the designed nickel catalysts were not useful in industry. It is critical time to investigate the relationship of coordination modes of nickel complexes and its catalytic activities and the properties of resultant polyethylenes.

  8. Hydrogen evolution reaction catalyst

    Science.gov (United States)

    Subbaraman, Ram; Stamenkovic, Vojislav; Markovic, Nenad; Tripkovic, Dusan

    2016-02-09

    Systems and methods for a hydrogen evolution reaction catalyst are provided. Electrode material includes a plurality of clusters. The electrode exhibits bifunctionality with respect to the hydrogen evolution reaction. The electrode with clusters exhibits improved performance with respect to the intrinsic material of the electrode absent the clusters.

  9. Olefin metathesis and catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Kukes, S. G.; Banks, R. L.

    1985-05-14

    Olefins are converted into other olefins having different numbers of carbon atoms by contact with a catalyst comprising an inorganic refractory oxide support containing at least one of tungsten oxide and molybdenum oxide and a promoting amount of at least one methylating agent under conditions suitable for the methylating agent compounds to promote the activity of tungsten and molybdenum oxides for the disproportionation reaction.

  10. Tight bifunctional hierarchical catalyst.

    Science.gov (United States)

    Højholt, Karen T; Vennestrøm, Peter N R; Tiruvalam, Ramchandra; Beato, Pablo

    2011-12-28

    A new concept to prepare tight bifunctional catalysts has been developed, by anchoring CoMo(6) clusters on hierarchical ZSM-5 zeolites for simultaneous use in HDS and hydrocracking catalysis. The prepared material displays a significant improved activity in HDS catalysis compared to the impregnated counterpart. PMID:22048337

  11. Catalysts for Environmental Remediation

    DEFF Research Database (Denmark)

    Abrams, B. L.; Vesborg, Peter Christian Kjærgaard

    2013-01-01

    The properties of catalysts used in environmental remediation are described here through specific examples in heterogeneous catalysis and photocatalysis. In the area of heterogeneous catalysis, selective catalytic reduction (SCR) of NOx was used as an example reaction with vanadia and tungsta...

  12. Nanopore and nanoparticle catalysts.

    Science.gov (United States)

    Thomas, J M; Raja, R

    2001-01-01

    The design, atomic characterization, performance, and relevance to clean technology of two distinct categories of new nanocatalysts are described and interpreted. Exceptional molecular selectivity and high activity are exhibited by these catalysts. The first category consists of extended, crystallographically ordered inorganic solids possessing nanopores (apertures, cages, and channels), the diameters of which fall in the range of about 0.4 to about 1.5 nm, and the second of discrete bimetallic nanoparticles of diameter 1 to 2 nm, distributed more or less uniformly along the inner walls of mesoporous (ca. 3 to 10 nm diameter) silica supports. Using the principles and practices of solid-state and organometallic chemistry and advanced physico-chemical techniques for in situ and ex situ characterization, a variety of powerful new catalysts has been evolved. Apart from those that, inter alia, simulate the behavior of enzymes in their specificity, shape selectivity, regio-selectivity, and ability to function under ambient conditions, many of these new nanocatalysts are also viable as agents for effecting commercially significant processes in a clean, benign, solvent-free, single-step fashion. In particular, a bifunctional, molecular sieve nanopore catalyst is described that converts cyclohexanone in air and ammonia to its oxime and caprolactam, and a bimetallic nanoparticle catalyst that selectively converts cyclic polyenes into desirable intermediates. Nanocatalysts in the first category are especially effective in facilitating highly selective oxidations in air, and those in the second are well suited to effecting rapid and selective hydrogenations of a range of organic compounds.

  13. An efficient block-discriminant identification of packed malware

    Indian Academy of Sciences (India)

    Smita Naval; Vijay Laxmi; Manoj Singh Gaur; P Vinod

    2015-08-01

    Advanced persistent attacks, incorporated by sophisticated malware, are on the rise against hosts, user applications and utility software. Modern malware hide their malicious payload by applying packing mechanism. Packing tools instigate code encryption to protect the original malicious payload. Packing is employed in tandem with code obfuscation/encryption/compression to create malware variants. Despite being just a variant of known malware, the packed malware invalidates the traditional signature based malware detection as packing tools create an envelope of packer code around the original base malware. Therefore, unpacking becomes a mandatory phase prior to anti-virus scanning for identifying the known malware hidden behind packing layers. Existing techniques of unpacking solutions increase execution overhead of AV scanners in terms of time. This paper illustrates an easy to use approach which works in two phases to reduce this overhead. The first phase (ESCAPE) discriminates the packed code from the native code (non-packed) by using random block entropy. The second phase (PEAL) validates inferences of ESCAPE by employing bi-classification (packed vs native) model using relevant hex byte features extracted blockwise. The proposed approach is able to shrink the overall execution time of AV scanners by filtering out native samples and avoiding excessive unpacking overhead. Our method has been evaluated against a set consisting of real packed instances of malware and benign programs.

  14. Study of vibration packing characteristics with simulated fuel particles

    International Nuclear Information System (INIS)

    This report presents the results of vibration packing experiments and computational simulations of particle compaction behavior. Both sphere and shard particles were evaluated in these works. Experiments with simulated fuel particles were conducted to investigate the factors affecting packing behavior. The factors are classified into geometrical and dynamics factors. With regard to the geometrical factors for sphere packing, the experimental results proved that the achievable packing fraction can be predicted by the equation derived by Ayer, which is relationship of inner diameter of cladding and diameters of particles. As for the dynamics factors, less vibration displacement is preferable, because it produces faster packing with less segregation. Similar experiments were conducted for the shard particles. The results indicate the packing characteristics of the shard particles are different from those of the sphere particles. Optimum weight ratio between particle sizes is different from the ratio given by Ayer's equation. As for the dynamics factors, the sweeping frequencies while packing were sufficient to obtain high packing fraction. Computational simulations were performed to investigate the particle behavior during packing. The movement of infiltrating and bed particles during packing was well understood. (author)

  15. Partial Degree Bounded Edge Packing Problem

    CERN Document Server

    Zhang, Peng

    2012-01-01

    In [1], whether a target binary string s can be represented from a boolean formula with operands chosen from a set of binary strings W was studied. In this paper, we first examine selecting a maximum subset X from W, so that for any string t in X, t is not representable by X\\{t}. We rephrase this problem as graph, and surprisingly find it give rise to a broad model of edge packing problem, which itself falls into the model of forbidden subgraph problem. Specifically, given a graph G(V;E) and a constant c, the problem asks to choose as many as edges to form a subgraph G'. So that in G', for each edge, at least one of its endpoints has degree no more than c. We call such G' partial c degree bounded. When c = 1, it turns out to be the complement of dominating set. We present several results about hardness, approximation for the general graph and efficient exact algorithm on trees. This edge packing problem model also has a direct interpretation in resource allocation. There are n types of resources and m jobs. E...

  16. Effective Thermal Conductivity of Adsorbent Packed Beds

    Science.gov (United States)

    Mori, Hideo; Hamamoto, Yoshinori; Yoshida, Suguru

    The effective thermal conductivity of adsorbent packed beds of granular zeolite 13X and granular silica gel A in the presence of stagnant steam or air was measured under different conditions of the adsorbent bed temperature, particle size and filler-gas pressure. The measured effective thermal conductivity showed to become smaller with decreasing particle size or decreasing pressure, but it was nearly independent of the bed temperature. When steam was the filler-gas, the rise in the thermal conductivity of the adsorbent particles due to steam adsorption led to the increase in the effective thermal conductivity of the bed, and this effect was not negligible at high steam pressure for the bed of large particle size. It was found that both the predictions of the effective thermal conductivity by the Hayashi et al.'s model and the Bauer-Schlünder model generally agreed well with the measurements, by considering the particle thermal conductivity rise due to steam adsorption. The thermal conductivity of a consolidated bed of granular zeolite 13X was also measured, and it was found to be much larger than that of the packed bed especially at lower pressure. The above prediction models underestimated the effective thermal conductivity of the consolidated bed.

  17. A novel reactor configuration for packed bed chemical-looping combustion of syngas

    Energy Technology Data Exchange (ETDEWEB)

    Hamers, H.P.; Gallucci, F.; Van Sint Annaland, M. [Multiphase Reactor Group, Chemical Process Intensification, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Cobden, P.D. [Energy Research Centre of the Netherlands (ECN), P.O. Box 1, 1755 ZG Petten (Netherlands); Kimball, E. [TNO Gas Treatment, P.O. Box 6000, 2600 JA Delft (Netherlands)

    2013-08-15

    This study reports on the application of chemical looping combustion (CLC) in pressurized packed bed reactors using syngas as a fuel. High pressure operation of CLC in packed bed has a different set of challenges in terms of material properties, cycle and reactor design compared to fluidized bed operation. However, high pressure operation allows the use of inherently more efficient power cycles than low pressure fluidized bed solutions. This paper quantifies the challenges in high pressure operation and introduces a novel reactor concept with which those challenges can be addressed. Continuous cyclic operation of a packed bed CLC system is simulated in a 1D numerical reactor model. Importantly, it is demonstrated that the temperature profiles that can occur in a packed bed reactor as a result of the different process steps do not accumulate, and have a negligible effect on the overall performance of the system. Moreover, it has been shown that an even higher energy efficiency can be achieved by feeding the syngas from the opposite direction during the reduction step (i.e. countercurrent operation). Unfortunately, in this configuration mode, more severe temperature fluctuations occur in the reactor exhaust, which is disadvantageous for the operation of a downstream gas turbine. Finally, a novel reactor configuration is introduced in which the desired temperature rise for obtained hot pressured air suitable for a gas turbine is obtained by carrying out the process with two packed bed reactor in series (two-stage CLC). This is shown to be a good alternative to the single bed configuration, and has the added advantage of decreasing the demands on both the oxygen carrier and the reactor materials and design specification.

  18. Preparation of HZSM-5 membrane packed CuO–ZnO–Al{sub 2}O{sub 3} nanoparticles for catalysing carbon dioxide hydrogenation to dimethyl ether

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Rong; Tian, Haifeng; Yang, Aimei; Zha, Fei, E-mail: zhafei@nwnu.edu.cn; Ding, Jian; Chang, Yue

    2015-08-01

    Highlights: • CuO–ZnO–Al{sub 2}O{sub 3} composite nanoparticles were successfully prepared using carbon sphere as template. • HZSM-5@CuO–ZnO–Al{sub 2}O{sub 3} capsule catalyst was prepared hydrothermally. • Zeolite capsule catalysts exhibited an extremely good selectivity for DME compared with the conventional hybrid catalyst. - Abstract: Spherical carbons were prepared successfully from aqueous glucose using hydrothermal method. After covered with aqueous Cu{sup 2+}, Zn{sup 2+} and Al{sup 3+} ions during the co-precipitation treatment, carbons were removed via calcination to yield CuO–ZnO–Al{sub 2}O{sub 3} nanoparticles. HZSM-5 membrane, which was synthesized using tetrapropylammonium hydroxide as templating agent, was packed onto CuO–ZnO–Al{sub 2}O{sub 3} nanoparticles hydrothermally to form HZSM-5 packed CuO–ZnO–Al{sub 2}O{sub 3} nanoparticles. It was characterized by the method of X-ray powder diffraction (XRD), scanning electronic microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and nitrogen sorption measurement. HZSM-5 packed CuO–ZnO–Al{sub 2}O{sub 3} nanoparticles were used as catalysts for the CO{sub 2} hydrogenation to dimethyl ether. The catalyst activity was investigated in a fixed-bed reactor. Under the reaction conditions of pressure at 3.0 MPa, space velocity (SV) of 1800 mL g{sub cat}{sup −1} h{sup −1}, volume ratio of CO{sub 2}/H{sub 2} to 1:3 and temperature at 270 °C, the conversion of CO{sub 2} could reach to 48.3%, with a dimethyl ether yield and selectivity of 23.4% and 48.5%, respectively.

  19. A Comparative Study of Septoplasty With or Without Nasal Packing

    OpenAIRE

    Walikar, Basavaraj N.; Rashinkar, S. M.; Watwe, M. V.; Fathima, Anees; Kakkeri, Ashfak

    2011-01-01

    This study was conducted to compare the outcome of septoplasty with or without Nasal packing. The study subjects were randomly allocated into two groups. There was significant reduction in frequency of post operative pain, headache, discomfort and duration of hospital stay in patients who have undergone septoplasty without nasal packing. However there was no difference in post operative bleeding and septal perforation between two groups. Therefore after Septoplasty without nasal packing is pr...

  20. Low density gravel substitute gravel pack in Marlim

    Energy Technology Data Exchange (ETDEWEB)

    Albino, E.

    1996-12-31

    Successful gravel pack completion means optimization of production. This has been PETROBRAS` task regarding completion of the giant Marlim field. Significant improvement have been noticed recently with the introduction of techniques such as horizontal drilling, frac pack and low density gravel substitute gravel pack. This paper discusses the introduction and results of the system, its advantages and trends since this technique can become an excellent alternative when a more aggressive technique is no economical. (author). 5 refs., 4 figs.

  1. Human Error in Throat Pack Management: Report of Two Cases.

    Science.gov (United States)

    Baranger, Violaine; Bon Mardion, Nicolas; Dureuil, Bertrand; Compère, Vincent

    2016-06-15

    Throat packs are frequently used after tracheal intubation during ear, nose, and throat surgery. We report 2 cases of complications related to throat packs retained at the end of surgery. Miscommunication between anesthesiology and surgery teams on throat pack management led to an upper gastrointestinal endoscopy examination under general anesthesia in the first case and to severe respiratory distress requiring tracheal reintubation in the second case. Our 2 case reports highlight the importance of good communication between anesthesiology and surgery teams and of standardized procedures and checklists for the management of throat packs to ensure patient safety. PMID:27301056

  2. Multilayer DNA Origami Packed on Hexagonal and Hybrid Lattices

    DEFF Research Database (Denmark)

    Ke, Yonggang; Voigt, Niels Vinther; Shih, William M.;

    2012-01-01

    . Here we report successful folding of multilayer DNA origami with helices arranged on a close-packed hexagonal lattice. This arrangement yields a higher density of helical packing and therefore higher resolution of spatial addressing than has been shown previously. We also demonstrate hybrid multilayer...... DNA origami with honeycomb-lattice, square-lattice, and hexagonal-lattice packing of helices all in one design. The availability of hexagonal close-packing of helices extends our ability to build complex structures using DNA nanotechnology....

  3. Packed bed carburization of tantalum and tantalum alloy

    Science.gov (United States)

    Lopez, Peter C.; Rodriguez, Patrick J.; Pereyra, Ramiro A.

    1999-01-01

    Packed bed carburization of a tantalum or tantalum alloy object. A method for producing corrosion-resistant tantalum or tantalum alloy objects is described. The method includes the steps of placing the object in contact with a carburizing pack, heating the packed object in vacuum furnace to a temperature whereby carbon from the pack diffuses into the object forming grains with tantalum carbide along the grain boundaries, and etching the surface of the carburized object. This latter step removes tantalum carbides from the surface of the carburized tantalum object while leaving the tantalum carbide along the grain boundaries.

  4. Fluorination process using catalysts

    Science.gov (United States)

    Hochel, R.C.; Saturday, K.A.

    1983-08-25

    A process is given for converting an actinide compound selected from the group consisting of uranium oxides, plutonium oxides, uranium tetrafluorides, plutonium tetrafluorides and mixtures of said oxides and tetrafluorides, to the corresponding volatile actinide hexafluoride by fluorination with a stoichiometric excess of fluorine gas. The improvement involves conducting the fluorination of the plutonium compounds in the presence of a fluoride catalyst selected from the group consisting of CoF/sub 3/, AgF/sub 2/ and NiF/sub 2/, whereby the fluorination is significantly enhanced. The improvement also involves conducting the fluorination of one of the uranium compounds in the presence of a fluoride catalyst selected from the group consisting of CoF/sub 3/ and AgF/sub 2/, whereby the fluorination is significantly enhanced.

  5. Fluorination process using catalyst

    Science.gov (United States)

    Hochel, Robert C.; Saturday, Kathy A.

    1985-01-01

    A process for converting an actinide compound selected from the group consisting of uranium oxides, plutonium oxides, uranium tetrafluorides, plutonium tetrafluorides and mixtures of said oxides and tetrafluorides, to the corresponding volatile actinide hexafluoride by fluorination with a stoichiometric excess of fluorine gas. The improvement involves conducting the fluorination of the plutonium compounds in the presence of a fluoride catalyst selected from the group consisting of CoF.sub.3, AgF.sub.2 and NiF.sub.2, whereby the fluorination is significantly enhanced. The improvement also involves conducting the fluorination of one of the uranium compounds in the presence of a fluoride catalyst selected from the group consisting of CoF.sub.3 and AgF.sub.2, whereby the fluorination is significantly enhanced.

  6. Obesity prevention and personal responsibility: the case of front-of-pack food labelling in Australia

    Directory of Open Access Journals (Sweden)

    Magnusson Roger S

    2010-11-01

    Full Text Available Abstract Background In Australia, the food industry and public health groups are locked in serious struggle for regulatory influence over the terms of front-of-pack food labelling. Clear, unambiguous labelling of the nutritional content of pre-packaged foods and of standardized food items sold in chain restaurants is consistent with the prevailing philosophy of 'personal responsibility'. An interpretive, front-of-pack labelling scheme has the capacity to encourage healthier patterns of eating, and to be a catalyst for improvements in the nutritional quality of food products through re-formulation. On the other hand, the strength of opposition of the Australian Food and Grocery Council to 'Traffic Light Labelling', and its efforts to promote a non-interpretive, voluntary scheme, invite the interpretation that the food industry is resistant to any reforms that could destabilise current (unhealthy purchasing patterns and the revenues they represent. Discussion This article argues that although policies that aim to educate consumers about the nutritional content of food are welcome, they are only one part of a broader basket of policies that are needed to make progress on obesity prevention and public health nutrition. However, to the extent that food labelling has the capacity to inform and empower consumers to make healthier choices - and to be a catalyst for improving the nutritional quality of commercial recipes - it has an important role to play. Furthermore, given the dietary impact of meals eaten in fast food and franchise restaurants, interpretive labelling requirements should not be restricted to pre-packaged foods. Summary Food industry resistance to an interpretive food labelling scheme is an important test for government, and a case study of how self-interest prompts industry to promote weaker, voluntary schemes that pre-empt and undermine progressive public health regulation.

  7. Olefin metathesis and catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Kukes, S. G.; Banks, R. L.

    1985-03-12

    Olefins are converted into other olefins having different numbers of carbon atoms by contact with a catalyst comprising an inorganic refractory material containing at least one of tungsten oxide and molybdenum oxide and a promoting amount of at least one treating agent selected from chlorinated silicon compounds, thionyl chloride, and sulfuryl chloride under conditions suitable for the treating agent to promote the activity of tungsten and molybdenum oxides for the disporoportionation reaction.

  8. School meal sociality or lunch pack individualism?

    DEFF Research Database (Denmark)

    Andersen, Sidse Schoubye; Holm, Lotte; Baarts, Charlotte

    2015-01-01

    the social life of a school class, and how these arrangements involve strategies of both inclusion and exclusion. Two types of school meals are compared in the intervention study: a hot meal based on Nordic ingredients and the normal Danish school meal arrangement in which children bring lunch packs...... to school. The study discusses commensality by examining and comparing lunchtime interactions within the same group of children in the two contrasting meal situations. The results fail to confirm the conventional view that shared meals have greater social impacts and benefits than eating individualized......The present article specifies and broadens our understanding of the concept of commensality by investigating what it means to ‘share a meal’. The study utilizes a school meal intervention carried out in Denmark in 2011/2012. It shows how different types of school meal arrangement influence...

  9. Hyperstaticity and loops in frictional granular packings

    Science.gov (United States)

    Tordesillas, Antoinette; Lam, Edward; Metzger, Philip T.

    2009-06-01

    The hyperstatic nature of granular packings of perfectly rigid disks is analyzed algebraically and through numerical simulation. The elementary loops of grains emerge as a fundamental element in addressing hyperstaticity. Loops consisting of an odd number of grains behave differently than those with an even number. For odd loops, the latent stresses are exterior and are characterized by the sum of frictional forces around each loop. For even loops, the latent stresses are interior and are characterized by the alternating sum of frictional forces around each loop. The statistics of these two types of loop sums are found to be Gibbsian with a "temperature" that is linear with the friction coefficient μ when μ<1.

  10. Packing of charged chains on toroidal geometries

    Science.gov (United States)

    Yao, Zhenwei; de la Cruz, Monica Olvera

    2013-01-01

    We study a strongly adsorbed flexible polyelectrolyte chain on tori. In this generalized Thomson problem, the patterns of the adsorbed chain are analyzed in the space of the toroidal coordinates and in terms of the orientation of each chain segment. Various patterns are found, including double spirals, disclination-like structures, Janus tori, and uniform wrappings, arising from the long-range electrostatic interaction and the toroidal geometry. Their broken mirror symmetry is quantitatively characterized by introducing an order parameter, an integral of the torsion. The uniform packing, which breaks the mirror symmetry the least, has the lowest value of the order parameter. In addition, it is found that the electrostatic energy of confined chains on tori conforms to a power law regardless of the screening effect in some typical cases studied. Furthermore, we study random walks on tori that generate chain configurations in the large screening limit or at large thermal fluctuation; some features associated with the toroidal geometry are discussed.

  11. Regulation relative to the packing and packing wastes; Reglementation relative aux emballages et dechets d'emballages

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-08-01

    The objectives of the european directive 94/62/CE of the 20 december 1994, relative to the packing and the packing wastes, are the harmonization between the States members, the environment protection and a management of the internal market in agreement with the Treaty. This text recalls the regulations in the french domain. Industrial and municipal packings wastes are concerned. (A.L.B.)

  12. Tandem isomerization-decarboxylation of unsaturated fatty acids to olefins via ruthenium metal-as-ligand catalysts

    Science.gov (United States)

    A new facile Ru-catalyzed route to bio-olefins3 from unsaturated fatty acids via readily accessible metal-as-ligand type catalyst precursors, [Ru(CO)2RCO2]n and Ru3(CO)12, will be described. The catalyst apparently functions in a tandem mode by dynamically isomerizing the positions of double bonds i...

  13. Experimental and modeling study of sulfur dioxide oxidation in packed-bed tubular reactor

    Directory of Open Access Journals (Sweden)

    Hanen NOURI

    2013-08-01

    Full Text Available The conversion of sulfur dioxide into sulfur trioxide is a reaction which interests not only the industry of sulfuric acid production but also the processes of pollution control of certain gas effluents containing SO2. This exothermic reaction needs a very good control of temperature, that's why it is led in the industry in a multistage converter with intermediate heat exchangers. Microreactors represent a good alternative for such reaction due to their intensification of mass and heat transfer and enhancement of temperature control. In this study, this reaction was conducted in a stainless steel tubular (4mm ID packed bed reactor using particles of vanadium pentoxide as catalyst at atmospheric pressure. Experiments were performed with different inlet SO2 concentration in 3-9% range and reaction temperature between 685-833K. We noticed that the conversion decreases with the amount of SO2 and increases with the temperature until an optimum, above this value the conversion drop according to the shape of the equilibrium curve. Controlling rate mechanism is studied by varying temperature. Pseudohomogeneous perfect plug flow is used to describe this small tubular reactor. Numerical simulations with MATLAB were performed to validate the experimental results. Good agreement between the model predictions and the experimental results is achieved. Fluid flow description inside the packed bed reactor was performed by using the free fluid and porous media flow model. This model was solved by the commercial software COMSOL Multiphysics. Velocity profile inside the reactor is theoretically obtained.

  14. Optical anisotropy in packed isotropic spherical particles: indication of nanometer scale anisotropy in packing structure.

    Science.gov (United States)

    Yamaguchi, Kohei; Inasawa, Susumu; Yamaguchi, Yukio

    2013-02-28

    We investigated the origin of birefringence in colloidal films of spherical silica particles. Although each particle is optically isotropic in shape, colloidal films formed by drop drying demonstrated birefringence. While periodic particle structures were observed in silica colloidal films, no regular pattern was found in blended films of silica and latex particles. However, since both films showed birefringence, regular film structure patterns were not required to exhibit birefringence. Instead, we propose that nanometer-scale film structure anisotropy causes birefringence. Due to capillary flow from the center to the edge of a cast suspension, particles are more tightly packed in the radial direction. Directional packing results in nanometer-scale anisotropy. The difference in the interparticle distance between radial and circumferential axes was estimated to be 10 nm at most. Nanometer-scale anisotropy in colloidal films and the subsequent optical properties are discussed.

  15. Failure Modes

    DEFF Research Database (Denmark)

    Jakobsen, K. P.; Burcharth, H. F.; Ibsen, Lars Bo;

    1999-01-01

    The present appendix contains the derivation of ten different limit state equations divided on three different failure modes. Five of the limit state equations can be used independently of the characteristics of the subsoil, whereas the remaining five can be used for either drained or undrained...

  16. Oxygen-reducing catalyst layer

    Science.gov (United States)

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; Yang, Ruizhi; Easton, E. Bradley; Dahn, Jeffrey R.; O'Neill, David G.

    2011-03-22

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  17. Catalyst systems and uses thereof

    Science.gov (United States)

    Ozkan, Umit S.; Holmgreen, Erik M.; Yung, Matthew M.

    2012-07-24

    A method of carbon monoxide (CO) removal comprises providing an oxidation catalyst comprising cobalt supported on an inorganic oxide. The method further comprises feeding a gaseous stream comprising CO, and oxygen (O.sub.2) to the catalyst system, and removing CO from the gaseous stream by oxidizing the CO to carbon dioxide (CO.sub.2) in the presence of the oxidation catalyst at a temperature between about 20 to about 200.degree. C.

  18. Development of GREET Catalyst Module

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhichao [Argonne National Lab. (ANL), Argonne, IL (United States); Benavides, Pahola T. [Argonne National Lab. (ANL), Argonne, IL (United States); Dunn, Jennifer B. [Argonne National Lab. (ANL), Argonne, IL (United States); Cronauer, Donald C. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2015-09-01

    In this report, we develop energy and material flows for the production of five different catalysts (tar reforming, alcohol synthesis, Zeolite Socony Mobil-5 [ZSM-5], Mo/Co/ γ-Al2O3, and Pt/ γ-Al2O3) and two chemicals (olivine, dimethyl ether of polyethylene glycol [DEPG]). These compounds and catalysts are now included in the Greenhouse Gases, Regulated Emissions and Energy Use in Transportation (GREET™) catalyst module.

  19. Privileged chiral ligands and catalysts

    CERN Document Server

    Zhou, Qi-Lin

    2011-01-01

    This ultimate ""must have"" and long awaited reference for every chemist working in the field of asymmetric catalysis starts with the core structure of the catalysts, explaining why a certain ligand or catalyst is so successful. It describes in detail the history, the basic structural characteristics, and the applications of these ""privileged catalysts"". A novel concept that gives readers a much deeper insight into the topic.

  20. Measured black carbon deposition on the Sierra Nevada snow pack and implication for snow pack retreat

    Directory of Open Access Journals (Sweden)

    O. L. Hadley

    2010-08-01

    Full Text Available Modeling studies show that the darkening of snow and ice by black carbon deposition is a major factor for the rapid disappearance of arctic sea ice, mountain glaciers and snow packs. This study provides one of the first direct measurements for the efficient removal of black carbon from the atmosphere by snow and its subsequent deposition to the snow packs of California. The early melting of the snow packs in the Sierras is one of the contributing factors to the severe water problems in California. BC concentrations in falling snow were measured at two mountain locations and in rain at a coastal site. All three stations reveal large BC concentrations in precipitation, ranging from 1.7 ng/g to 12.9 ng/g. The BC concentrations in the air after the snow fall were negligible suggesting an extremely efficient removal of BC by snow. The data suggest that below cloud scavenging, rather than ice nuclei, was the dominant source of BC in the snow. A five-year comparison of BC, dust, and total fine aerosol mass concentrations at multiple sites reveals that the measurements made at the sampling sites were representative of large scale deposition in the Sierra Nevada. The relative concentration of iron and calcium in the mountain aerosol indicates that one-quarter to one-third of the BC may have been transported from Asia.

  1. Measured black carbon deposition on the Sierra Nevada snow pack and implication for snow pack retreat

    Directory of Open Access Journals (Sweden)

    O. L. Hadley

    2010-04-01

    Full Text Available Modeling studies show that the darkening of snow and ice by black carbon (BC deposition is a major factor for the rapid disappearance of arctic sea ice, mountain glaciers and snow packs. This study provides one of the first direct measurements for the efficient removal of black carbon from the atmosphere by snow and its subsequent deposition on the snow packs of California. The early melting of the snow packs in the Sierras is one of the contributing factors to the severe water problems in California. BC concentrations in falling snow were measured at two mountain locations and in rain at a coastal site. All three stations reveal large BC concentrations in precipitation, ranging from 1.7 ng/g to 12.9 ng/g. The BC concentrations in the air after the snow fall were negligible suggesting an extremely efficient removal of BC by snow. The data suggest that below cloud scavenging, rather than ice nuclei, was the dominant source of BC in the snow. A five-year comparison of BC, dust, and total fine aerosol mass concentrations at multiple sites reveals that the measurements made at the sampling sites were representative of large scale deposition in the Sierra Nevada. The relative concentration of iron and calcium in the mountain aerosol indicates that one-quarter to one-third of the BC may have been transported from Asia.

  2. Measured Black Carbon Deposition on the Sierra Nevada Snow Pack and Implication for Snow Pack Retreat

    Energy Technology Data Exchange (ETDEWEB)

    Hadley, O.L.; Corrigan, C.E.; Kirchstetter, T.W.; Cliff, S.S.; Ramanathan, V.

    2010-01-12

    Modeling studies show that the darkening of snow and ice by black carbon deposition is a major factor for the rapid disappearance of arctic sea ice, mountain glaciers and snow packs. This study provides one of the first direct measurements for the efficient removal of black carbon from the atmosphere by snow and its subsequent deposition to the snow packs of California. The early melting of the snow packs in the Sierras is one of the contributing factors to the severe water problems in California. BC concentrations in falling snow were measured at two mountain locations and in rain at a coastal site. All three stations reveal large BC concentrations in precipitation, ranging from 1.7 ng/g to 12.9 ng/g. The BC concentrations in the air after the snow fall were negligible suggesting an extremely efficient removal of BC by snow. The data suggest that below cloud scavenging, rather than ice nuclei, was the dominant source of BC in the snow. A five-year comparison of BC, dust, and total fine aerosol mass concentrations at multiple sites reveals that the measurements made at the sampling sites were representative of large scale deposition in the Sierra Nevada. The relative concentration of iron and calcium in the mountain aerosol indicates that one-quarter to one-third of the BC may have been transported from Asia.

  3. New series of paper pack vending machines; Paper pack jido hanbaiki no shin series

    Energy Technology Data Exchange (ETDEWEB)

    Ohashi, M. [Fuji Denki Reiki Co. Ltd., Tokyo (Japan); Umino, S. [Fuji Electric Co. Ltd., Tokyo (Japan)

    1996-07-10

    This paper presents series of paper pack vending machines. These machines may be broadly classified into those of cold drinks and of hot and cold drinks depending on the storage temperature of products. The former is the machine for cooling dairy products at 10{degree}C with a combined stacking by direct-stacked racks and chain-multiracks. The latter is provided with divided storing chambers with each chamber selectively cooled or heated. Products in the hot chamber are canned coffee and the like set at 55{degree}C. The temperature control is performed by a microcomputer. The chain-multiracks are provided with advantages such as capability of handling various kinds of container shapes, storing drinks and foods vertically, replacing products by the change of a shelf attachment with one operation, and storing one liter packs by setting pair columns. The direct-stacked racks are provided with advantages such as versatility of handling various kinds of containers and miniaturization of the mechanism other than the storage part. The installation space was reduced by devising the opening and closing of the door. The control part is capable of setting temperatures differently for cans and paper packs. 7 figs., 1 tab.

  4. Hydrodewaxing with mixed zeolite catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Chester, A.W.; McHale, W.D.; Yen, J.H.

    1986-03-11

    A process is described for catalytically dewaxing a hydrocarbon lubricating oil feedstock comprising contacting the feedstock with a dewaxing catalyst, the dewaxing catalyst comprising, in combination: (a) a zeolite catalyst having a Constraint Index not less than 1, (b) an acidic catalytic material selected from the group consisting of Mordenite, TEA Mordenite, Dealuminized Y, Ultrastable Y, Rare Earth Y, amorphous silica-alumina chlorinated alumina, ZSM-4 and ZSM-20, and (c) a hydrogenation component, and recovering a dewaxed product. A process is also described for catalytically dewaxing a hydrocarbon lubricating oil feedstock comprising contacting the feedstock with a dewaxing catalyst, the dewaxing catalyst comprising, in combinations: (a) a first zeolite catalyst selected from the group consisting of ZSM-5, ZMS-11, ZSM-12, ZSM-22, ZSM-23, ZSM-34, ZSM-35, ZSM-38, ZSM-48, TMA Offretite and Erionite, (b) a second catalyst selected from the group consisting of ZSM-12, ZSM-22, ZSM-38 and ZSM-48, the second zeolite catalyst being different from the first zeolite catalyst, and (c) a hydrogenation component, and recovering a dewaxed product.

  5. 48 CFR 552.211-75 - Preservation, Packaging and Packing.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 4 2010-10-01 2010-10-01 false Preservation, Packaging....211-75 Preservation, Packaging and Packing. As prescribed in 511.204(b)(2), insert the following clause: Preservation, Packaging, and Packing (FEB 1996) Unless otherwise specified, all items shall...

  6. Experimental validation of packed bed chemical-looping combustion

    NARCIS (Netherlands)

    Noorman, S.; Sint Annaland, van M.; Kuipers, J.A.M.

    2010-01-01

    Chemical-looping combustion has emerged as a promising alternative technology, intrinsically integrating CO2 capture in power production. A novel reactor concept based on dynamically operated packed beds has been proposed [Noorman, S., van Sint Annaland, M., Kuipers, J.A.M., 2007. Packed bed reactor

  7. Predicting the Liquid Phase Mass Transfer Resistance of Structured Packings

    NARCIS (Netherlands)

    Olujic, Z.; Seibert, A.F.

    2014-01-01

    Published correlations for estimating the liquid phase mass transfer coefficients of structured packings are compared using experimental evidence on the efficiency of Montz-Pak B1–250MN and B1–500MN structured packings as measured in total reflux distillation tests using the chlorobenzene/ethylbenze

  8. Dense Packings of Polyhedra: Platonic and Archimedean Solids

    CERN Document Server

    Torquato, S

    2009-01-01

    We formulate the problem of generating dense packings of nonoverlapping, non-tiling polyhedra within an adaptive fundamental cell subject to periodic boundary conditions as an optimization problem, which we call the Adaptive Shrinking Cell (ASC) scheme. This novel optimization problem is solved here (using a variety of multi-particle initial configurations) to find the dense packings of each of the Platonic solids in three-dimensional Euclidean space R3 , except for the cube, which is the only Platonic solid that tiles space. We find the densest known packings of tetrahedra, icosahedra, dodecahedra, and octahedra with densities 0:823:::, 0:836:::, 0:904:::, and 0:947:::, respectively. It is noteworthy that the densest tetrahedral packing possesses no long-range order. Unlike the densest tetrahedral packing, which must not be a Bravais lattice packing, the densest packings of the other non-tiling Platonic solids that we obtain are their previously known optimal (Bravais) lattice packings. We also derive a simp...

  9. 48 CFR 852.214-73 - Alternate packaging and packing.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false Alternate packaging and....214-73 Alternate packaging and packing. As prescribed in 814.201-6(b)(3), insert the following provision: Alternate Packaging and Packing (JAN 2008) The bidder's offer must clearly indicate the...

  10. Online Variable-Sized Bin Packing with Conflicts

    DEFF Research Database (Denmark)

    Epstein, Leah; Favrholdt, Lene Monrad; Levin, Asaf

    2011-01-01

    We study a new kind of on-line bin packing with conflicts, motivated by a problem arising when scheduling jobs on the Grid. In this bin packing problem, the set of items is given at the beginning, together with a set of conflicts on pairs of items. A conflict on a pair of items implies...

  11. A relationship between maximum packing of particles and particle size

    Science.gov (United States)

    Fedors, R. F.

    1979-01-01

    Experimental data indicate that the volume fraction of particles in a packed bed (i.e. maximum packing) depends on particle size. One explanation for this is based on the idea that particle adhesion is the primary factor. In this paper, however, it is shown that entrainment and immobilization of liquid by the particles can also account for the facts.

  12. A selection-quotient process for packed word Hopf algebra

    CERN Document Server

    Duchamp, G H E; Tanasa, A

    2013-01-01

    In this paper, we define a Hopf algebra structure on the vector space spanned by packed words using a selection-quotient coproduct. We show that this algebra is free on its irreducible packed words. Finally, we give some brief explanations on the Maple codes we have used.

  13. 76 FR 251 - Country of Origin Labeling of Packed Honey

    Science.gov (United States)

    2011-01-04

    ... final rule published in the Federal Register on July 8, 2009 (74 FR 32389) to include provisions for... Service 7 CFR Part 52 RIN 0581-AC89 Country of Origin Labeling of Packed Honey AGENCY: Agricultural..., establishing new regulations addressing country of origin labeling for packed honey bearing any official...

  14. Does the fluid elasticity influence the dispersion in packed beds?

    NARCIS (Netherlands)

    Westerterp, K. Roel; Wijngaarden, Ruud J.; Nijhuis, Niek B.G.

    1996-01-01

    Reasons are given why the axial dispersion in a gas flowing through a packed bed may be influenced by the elasticity - or compressibility - of the fluid. To support this hypothesis, experiments have been done in a packed column at pressures from 0.13 to 2.0 MPa. The elasticity E of a gas is proporti

  15. Growth of Vanadium Carbide by Halide-Activated Pack Diffusion

    DEFF Research Database (Denmark)

    Fernandes, Frederico Augusto Pires; Christiansen, Thomas Lundin; Dahl, Kristian Vinter;

    The present work investigates growth of vanadium carbide (VC) layers by the pack diffusion method on a Vanadis 6 tool steel. The VC layers were produced by pack diffusion at 1000°C for 1, 4 and 16 hours. The VC layers were characterized with optical and electron microscopy, Vickers hardness tests...

  16. Simulation and control of water-gas shift packed bed reactor with inter-stage cooling

    Science.gov (United States)

    Saw, S. Z.; Nandong, J.

    2016-03-01

    Water-Gas Shift Reaction (WGSR) has become one of the well-known pathways for H2 production in industries. The issue with WGSR is that it is kinetically favored at high temperatures but thermodynamically favored at low temperatures, thus requiring careful consideration in the control design in order to ensure that the temperature used does not deactivate the catalyst. This paper studies the effect of a reactor arrangement with an inter-stage cooling implemented in the packed bed reactor to look at its effect on outlet temperature. A mathematical model is developed based on one-dimensional heat and mass transfers which incorporate the intra-particle effects. It is shown that the placement of the inter-stage cooling and the outlet temperature exiting the inter-stage cooling have strong influence on the reaction conversion. Several control strategies are explored for the process. It is shown that a feedback- feedforward control strategy using Multi-scale Control (MSC) is effective to regulate the reactor temperature profile which is critical to maintaining the catalysts activity.

  17. The effect of nanoparticle packing on capacitive electrode performance

    Science.gov (United States)

    Lee, Younghee; Noh, Seonmyeong; Kim, Min-Sik; Kong, Hye Jeong; Im, Kyungun; Kwon, Oh Seok; Kim, Sungmin; Yoon, Hyeonseok

    2016-06-01

    Nanoparticles pack together to form macro-scale electrodes in various types of devices, and thus, optimization of the nanoparticle packing is a prerequisite for the realization of a desirable device performance. In this work, we provide in-depth insight into the effect of nanoparticle packing on the performance of nanoparticle-based electrodes by combining experimental and computational findings. As a model system, polypyrrole nanospheres of three different diameters were used to construct pseudocapacitive electrodes, and the performance of the electrodes was examined at various nanosphere diameter ratios and mixed weight fractions. Two numerical algorithms are proposed to simulate the random packing of the nanospheres on the electrode. The binary nanospheres exhibited diverse, complicated packing behaviors compared with the monophasic packing of each nanosphere species. The packing of the two nanosphere species with lower diameter ratios at an optimized composition could lead to more dense packing of the nanospheres, which in turn could contribute to better device performance. The dense packing of the nanospheres would provide more efficient transport pathways for ions because of the reduced inter-nanosphere pore size and enlarged surface area for charge storage. Ultimately, it is anticipated that our approach can be widely used to define the concept of ``the best nanoparticle packing'' for desirable device performance.Nanoparticles pack together to form macro-scale electrodes in various types of devices, and thus, optimization of the nanoparticle packing is a prerequisite for the realization of a desirable device performance. In this work, we provide in-depth insight into the effect of nanoparticle packing on the performance of nanoparticle-based electrodes by combining experimental and computational findings. As a model system, polypyrrole nanospheres of three different diameters were used to construct pseudocapacitive electrodes, and the performance of the

  18. Numerical optimization method for packing regular convex polygons

    Science.gov (United States)

    Galiev, Sh. I.; Lisafina, M. S.

    2016-08-01

    An algorithm is presented for the approximate solution of the problem of packing regular convex polygons in a given closed bounded domain G so as to maximize the total area of the packed figures. On G a grid is constructed whose nodes generate a finite set W on G, and the centers of the figures to be packed can be placed only at some points of W. The problem of packing these figures with centers in W is reduced to a 0-1 linear programming problem. A two-stage algorithm for solving the resulting problems is proposed. The algorithm finds packings of the indicated figures in an arbitrary closed bounded domain on the plane. Numerical results are presented that demonstrate the effectiveness of the method.

  19. DEHYDROGENATION CATALYST FOR PRODUCTION OF MTBE

    Science.gov (United States)

    The objectives of this project were to better understand the effect of different catalyst preparation parameters, the effect of different catalyst treatment parameters, and the mechanism of deactivation. Accordingly, catalysts were made using various preparation methods and with...

  20. REACTOR FILLED WITH CATALYST MATERIAL, AND CATALYST THEREFOR

    NARCIS (Netherlands)

    Sie, S.T.

    1995-01-01

    Abstract of WO 9521691 (A1) Described is a reactor (1) at least partially filled with catalyst granules (11), which is intended for catalytically reacting at least one gas and at least one liquid with each other. According to the invention the catalyst granules (11) are collected in agglomerates

  1. Catalyst regeneration by circulating catalyst in a hydrotreating oil process

    Energy Technology Data Exchange (ETDEWEB)

    Kanbier, D.; Goudriaan, F.

    1978-02-14

    A process is disclosed for catalytic hydrotreating of a heavy hydrocarbon oil and a light hydrocarbon oil in separate reactors, wherein the hydrotreating catalyst is circulated through both reactors. The process is particularly suited to obtaining long catalyst life when operating at low hydrogen pressures.

  2. Packing regularities in biological structures relate to their dynamics.

    Science.gov (United States)

    Jernigan, Robert L; Kloczkowski, Andrzej

    2007-01-01

    The high packing density inside proteins leads to certain geometric regularities and also is one of the most important contributors to the high extent of cooperativity manifested by proteins in their cohesive domain motions. The orientations between neighboring nonbonded residues in proteins substantially follow the similar geometric regularities, regardless of whether the residues are on the surface or buried, a direct result of hydrophobicity forces. These orientations are relatively fixed and correspond closely to small deformations from those of the face-centered cubic lattice, which is the way in which identical spheres pack at the highest density. Packing density also is related to the extent of conservation of residues, and we show this relationship for residue packing densities by averaging over a large sample or residue packings. There are three regimes: (1) over a broad range of packing densities the relationship between sequence entropy and inverse packing density is nearly linear, (2) over a limited range of low packing densities the sequence entropy is nearly constant, and (3) at extremely low packing densities the sequence entropy is highly variable. These packing results provide important justification for the simple elastic network models that have been shown for a large number of proteins to represent protein dynamics so successfully, even when the models are extremely coarse grained. Elastic network models for polymeric chains are simple and could be combined with these protein elastic networks to represent partially denatured parts of proteins. Finally, we show results of applications of the elastic network model to study the functional motions of the ribosome, based on its known structure. These results indicate expected correlations among its components for the step-wise processing steps in protein synthesis, and suggest ways to use these elastic network models to develop more detailed mechanisms, an important possibility because most

  3. SEPTOPLASTY WITH AND WITHOUT NASAL PACKING: A COMPARATIVE STUDY

    Directory of Open Access Journals (Sweden)

    Mitta

    2016-05-01

    Full Text Available Septoplasty is one of the most commonly performed surgeries in rhinology to relieve nasal obstruction of patients with distortion in the midline cartilage or septum of the nose to relieve nasal obstruction of patient and findings consistent with nasal endoscopy. The anterior nasal packing routinely done following septoplasty is usually conventional and not evidence based. The purpose of nasal packing is to obtain haemostasis, enhance opposition of septal flaps, avoid septal haematoma formation, close the dead space, avoid synechiae formation, provide support to septal cartilage and prevent its displacement. OBJECTIVE This study intends to evaluate the effects of nasal packing on surgical success and related complications in septoplasty. MATERIALS AND METHODS The present clinical prospective and randomised study was carried out on patients attending Otorhinolaryngology Department of Santhiram Medical College & General Hospital between March 2012 and March 2015. Patients undergoing septoplasty were randomised either to receive anterior nasal packing or to not receive nasal packing postoperatively. RESULTS Levels of pain experienced by patients with nasal packing postoperatively during the initial 24 hours postoperatively and during the removal of the pack were significantly more. Post-operative headache, epiphora, swallowing discomfort and sleep disturbance were more in patients with nasal packing and statistically (p.05. Septal haematoma, adhesions and local infections in both groups were statistically insignificant (p>.05. CONCLUSION Septoplasty enhances the standard of living of patients with septal deviation and nasal obstruction. Our study results suggest that nasal packing after septoplasty is not obligatory. Nasal packing causes considerably more pain and complications, and it should be reserved only for those who have bleeding predisposition.

  4. Too packed to change: side-chain packing and site-specific substitution rates in protein evolution

    Directory of Open Access Journals (Sweden)

    María Laura Marcos

    2015-04-01

    Full Text Available In protein evolution, due to functional and biophysical constraints, the rates of amino acid substitution differ from site to site. Among the best predictors of site-specific rates are solvent accessibility and packing density. The packing density measure that best correlates with rates is the weighted contact number (WCN, the sum of inverse square distances between a site’s Cα and the Cα of the other sites. According to a mechanistic stress model proposed recently, rates are determined by packing because mutating packed sites stresses and destabilizes the protein’s active conformation. While WCN is a measure of Cα packing, mutations replace side chains. Here, we consider whether a site’s evolutionary divergence is constrained by main-chain packing or side-chain packing. To address this issue, we extended the stress theory to model side chains explicitly. The theory predicts that rates should depend solely on side-chain contact density. We tested this prediction on a data set of structurally and functionally diverse monomeric enzymes. We compared side-chain contact density with main-chain contact density measures and with relative solvent accessibility (RSA. We found that side-chain contact density is the best predictor of rate variation among sites (it explains 39.2% of the variation. Moreover, the independent contribution of main-chain contact density measures and RSA are negligible. Thus, as predicted by the stress theory, site-specific evolutionary rates are determined by side-chain packing.

  5. Too packed to change: side-chain packing and site-specific substitution rates in protein evolution.

    Science.gov (United States)

    Marcos, María Laura; Echave, Julian

    2015-01-01

    In protein evolution, due to functional and biophysical constraints, the rates of amino acid substitution differ from site to site. Among the best predictors of site-specific rates are solvent accessibility and packing density. The packing density measure that best correlates with rates is the weighted contact number (WCN), the sum of inverse square distances between a site's C α and the C α of the other sites. According to a mechanistic stress model proposed recently, rates are determined by packing because mutating packed sites stresses and destabilizes the protein's active conformation. While WCN is a measure of C α packing, mutations replace side chains. Here, we consider whether a site's evolutionary divergence is constrained by main-chain packing or side-chain packing. To address this issue, we extended the stress theory to model side chains explicitly. The theory predicts that rates should depend solely on side-chain contact density. We tested this prediction on a data set of structurally and functionally diverse monomeric enzymes. We compared side-chain contact density with main-chain contact density measures and with relative solvent accessibility (RSA). We found that side-chain contact density is the best predictor of rate variation among sites (it explains 39.2% of the variation). Moreover, the independent contribution of main-chain contact density measures and RSA are negligible. Thus, as predicted by the stress theory, site-specific evolutionary rates are determined by side-chain packing.

  6. Novel Reforming Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Pfefferle, Lisa D; Haller, Gary L

    2012-10-16

    Aqueous phase reforming is useful for processing oxygenated hydrocarbons to hydrogen and other more useful products. Current processing is hampered by the fact that oxide based catalysts are not stable under high temperature hydrothermal conditions. Silica in the form of structured MCM-41 is thermally a more stable support for Co and Ni than conventional high surface area amorphous silica but hydrothermal stability is not demonstrated. Carbon nanotube supports, in contrast, are highly stable under hydrothermal reaction conditions. In this project we show that carbon nanotubes are stable high activity/selectivity supports for the conversion of ethylene glycol to hydrogen.

  7. Altering bio-oil composition by catalytic treatment of pinewood pyrolysis vapors over zeolites using an auger - packed bed integrated reactor system

    Directory of Open Access Journals (Sweden)

    Vamshi Krishna Guda

    2016-09-01

    Full Text Available Pine wood pyrolysis vapors were catalytically treated using Zeolite catalysts. An auger fed reactor was used for the pinewood pyrolysis while a packed bed reactor mounted on the top of the auger reactor housed the catalyst for the treatment of pinewood pyrolytic vapors. The pyrolytic vapors produced at 450 oC were passed through zeolite catalysts maintained at 425 oC at a weight hourly space velocity (WHSV of 12 h-1. Five zeolites, including ZSM-5, mordenite, ferrierite, Zeolite-Y, and Zeolite-beta (all in H form, were used to study the effect of catalyst properties such as acidity, pore size, and pore structure on catalytic cracking of pinewood pyrolysis vapors. Product bio-oils were analyzed for their chemical composition using GC-MS, water content, density, viscosity, acid value, pH, and elemental compositions. Thermogravimetric analysis (TGA was performed to analyze the extent of coking on zeolite catalysts. Application of catalysis to biomass pyrolysis increased gas product yields at the expense of bio-oil yields. While all the zeolites deoxygenated the pyrolysis vapors, ZSM-5 was found to be most effective. The ZSM-5 catalyzed bio-oil, rich in phenolics and aromatic hydrocarbons, was less viscous, had relatively lower acid number and high pH, and possessed oxygen content nearly half that of un-catalyzed bio-oil. Brønsted acidity, pore size, and shape-selective catalysis of ZSM-5 catalyst proved to be the determining factors for its activity. TGA results implied that the pore size of catalysts highly influenced coking reactions. Regeneration of the used catalysts was successfully completed at 700 oC.

  8. In-situ characterization of heterogeneous catalysts

    CERN Document Server

    Rodriguez, Jose A; Chupas, Peter J

    2013-01-01

    Helps researchers develop new catalysts for sustainable fuel and chemical production Reviewing the latest developments in the field, this book explores the in-situ characterization of heterogeneous catalysts, enabling readers to take full advantage of the sophisticated techniques used to study heterogeneous catalysts and reaction mechanisms. In using these techniques, readers can learn to improve the selectivity and the performance of catalysts and how to prepare catalysts as efficiently as possible, with minimum waste. In-situ Characterization of Heterogeneous Catalysts feat

  9. Localized breathing modes in granular crystals with defects

    OpenAIRE

    Theocharis, G.; Kavousanakis, M; Kevrekidis, P. G.; Daraio, Chiara; Porter, Mason A.; Kevrekidis, I. G.

    2009-01-01

    We study localized modes in uniform one-dimensional chains of tightly packed and uniaxially compressed elastic beads in the presence of one or two light-mass impurities. For chains composed of beads of the same type, the intrinsic nonlinearity, which is caused by the Hertzian interaction of the beads, appears not to support localized, breathing modes. Consequently, the inclusion of light-mass impurities is crucial for their appearance. By analyzing the problem’s linear limit, we identify the ...

  10. Packing schemes of cavities in selected clathrasils and zeolites and the analogous packings of atoms in crystal structures

    DEFF Research Database (Denmark)

    Hem, Caroline Piper; Makovicky, Emil; Balic Zunic, Tonci

    2010-01-01

    of kagome nets and its cavity packing is an analog to the packing scheme of atoms in the cubic Laves phase MgCu2. Dodecasil 1H has an arrangement of [512] cavities in an AA stacking of kagome nets and is analogous to the alloy structure type CaZn5. Edingtonite and natrolite are built from two types......, and interpreted by comparison with analogous packings of atoms in inorganic compounds and alloys. The topology is described qualitatively as “negative” structures formed by the cavities. Melanophlogite and dodecasils 3C and 1H are all clathrasils with isolated cavities. They all have pentagonal dodecahedral [512......] cages, associated with other cavity types. The packing of cavities in melanophlogite is analogous to the packing of atoms in the structure of Cr3Si, where the Cr atoms form icosahedra around the Si sites. Dodecasil 3C has a cubic arrangement of [512] cavities, which is described as ABC stacking...

  11. Modeling the elution of organic chemicals from a melting homogeneous snow pack.

    Science.gov (United States)

    Meyer, Torsten; Wania, Frank

    2011-06-01

    Organic chemicals are often released in peak concentrations from melting snow packs. A simple, mechanistic snowmelt model was developed to simulate and predict the elution of organic substances from melting, homogeneous snow, as influenced by chemical properties and snow pack characteristics. The model calculates stepwise the chemical transport along with the melt water flow in a multi-layered snow pack, based on chemical equilibrium partitioning between the individual bulk snow phases. The model succeeds in reproducing the elution behavior of several organic contaminants observed in previously conducted cold room experiments. The model aided in identifying four different types of enrichment of organic substances during snowmelt. Water soluble substances experience peak releases early during a melt period (type 1), whereas chemicals that strongly sorb to particulate matter (PM) or snow grain surfaces elute at the end of melting (type 2). Substances that are somewhat water soluble and at the same time have a high affinity for snow grain surfaces may exhibit increasing concentrations in the melt water (type 3). Finally, elution sequences involving peak loads both at the beginning and the end of melting are simulated for chemicals that are partially dissolved in the aqueous melt water phase and partially sorbed to PM (type 4). The extent of type 1 enrichment mainly depends on the snow depth, whereby deeper snow generates more pronounced concentration peaks. PM influences the elution behavior of organic chemicals strongly because of the very large natural variability in the type and amount of particles present in snow. Urban and road-side snow rich in PM can generate type 2 concentration peaks at the end of the melt period for even relatively water soluble substances. From a clean, melting snow pack typical for remote regions, even fairly hydrophobic chemicals can be released in type 1 mode while being almost completely dissolved in the aqueous melt water phase. The

  12. deNOx catalysts for biomass combustion

    DEFF Research Database (Denmark)

    Kristensen, Steffen Buus

    industrial reference catalyst. Furthermore long-term activity measurements at normal operating temperature revealed that the catalyst did not display any sign of deactivation. The catalyst showed very high resistance towards potassium poisoning maintaining a 16 times higher activity than the equally poisoned...... industrial reference catalyst, after impregnation of 225 mole potassium/g of catalyst. A catalyst plate was synthesised using 20 wt.% sepiolite mixed with nano catalyst, supported by a SiO2-fibre mesh. Realistic potassium poisoning was performed on the catalyst plate, by exposure in a potassium aerosol...

  13. Doped palladium containing oxidation catalysts

    Science.gov (United States)

    Mohajeri, Nahid

    2014-02-18

    A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

  14. Catalysts for low temperature oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Toops, Todd J.; Parks, III, James E.; Bauer, John C.

    2016-03-01

    The invention provides a composite catalyst containing a first component and a second component. The first component contains nanosized gold particles. The second component contains nanosized platinum group metals. The composite catalyst is useful for catalyzing the oxidation of carbon monoxide, hydrocarbons, oxides of nitrogen, and other pollutants at low temperatures.

  15. Optimization of operating parameters for gas-phase photocatalytic splitting of H2S by novel vermiculate packed tubular reactor.

    Science.gov (United States)

    Preethi, V; Kanmani, S

    2016-10-01

    Hydrogen production by gas-phase photocatalytic splitting of Hydrogen Sulphide (H2S) was investigated on four semiconductor photocatalysts including CuGa1.6Fe0.4O2, ZnFe2O3, (CdS + ZnS)/Fe2O3 and Ce/TiO2. The CdS and ZnS coated core shell particles (CdS + ZnS)/Fe2O3 shows the highest rate of hydrogen (H2) production under optimized conditions. Packed bed tubular reactor was used to study the performance of prepared photocatalysts. Selection of the best packing material is a key for maximum removal efficiency. Cheap, lightweight and easily adsorbing vermiculate materials were used as a novel packing material and were found to be effective in splitting H2S. Effect of various operating parameters like flow rate, sulphide concentration, catalyst dosage, light irradiation were tested and optimized for maximum H2 conversion of 92% from industrial waste H2S. PMID:27562700

  16. Localized lipid packing of transmembrane domains impedes integrin clustering.

    Directory of Open Access Journals (Sweden)

    Mehrdad Mehrbod

    Full Text Available Integrin clustering plays a pivotal role in a host of cell functions. Hetero-dimeric integrin adhesion receptors regulate cell migration, survival, and differentiation by communicating signals bidirectionally across the plasma membrane. Thus far, crystallographic structures of integrin components are solved only separately, and for some integrin types. Also, the sequence of interactions that leads to signal transduction remains ambiguous. Particularly, it remains controversial whether the homo-dimerization of integrin transmembrane domains occurs following the integrin activation (i.e. when integrin ectodomain is stretched out or if it regulates integrin clustering. This study employs molecular dynamics modeling approaches to address these questions in molecular details and sheds light on the crucial effect of the plasma membrane. Conducting a normal mode analysis of the intact αllbβ3 integrin, it is demonstrated that the ectodomain and transmembrane-cytoplasmic domains are connected via a membrane-proximal hinge region, thus merely transmembrane-cytoplasmic domains are modeled. By measuring the free energy change and force required to form integrin homo-oligomers, this study suggests that the β-subunit homo-oligomerization potentially regulates integrin clustering, as opposed to α-subunit, which appears to be a poor regulator for the clustering process. If α-subunits are to regulate the clustering they should overcome a high-energy barrier formed by a stable lipid pack around them. Finally, an outside-in activation-clustering scenario is speculated, explaining how further loading the already-active integrin affects its homo-oligomerization so that focal adhesions grow in size.

  17. Mechanochemical activation of iron ore-based catalysts for the hydrogenation of brown coal

    Energy Technology Data Exchange (ETDEWEB)

    Kuznetsov, P.N.; Kuznetsova, L.I.; Chumakov, V.G.; Moiseeva, G.A. [Rossijskaya Akademiya Nauk, Krasnoyarsk (Russian Federation). Inst. of Chemistry and Chemical Technology

    2000-10-01

    Genesis of pyrrhotite catalysts from different iron ore concentrates and pure iron oxides was investigated using the method of mechanochemical treatment in a planetary mill. The dispersion and fine crystalline structure of oxide and pyrrhotite particles were studied as the function of mechanical load, sulfiding temperature and mode of preparation. Methods for the preparation of high performance iron ore-based catalysts for brown coal hydrogenation have been developed. (orig.)

  18. Catalyst design for biorefining.

    Science.gov (United States)

    Wilson, Karen; Lee, Adam F

    2016-02-28

    The quest for sustainable resources to meet the demands of a rapidly rising global population while mitigating the risks of rising CO2 emissions and associated climate change, represents a grand challenge for humanity. Biomass offers the most readily implemented and low-cost solution for sustainable transportation fuels, and the only non-petroleum route to organic molecules for the manufacture of bulk, fine and speciality chemicals and polymers. To be considered truly sustainable, biomass must be derived from resources which do not compete with agricultural land use for food production, or compromise the environment (e.g. via deforestation). Potential feedstocks include waste lignocellulosic or oil-based materials derived from plant or aquatic sources, with the so-called biorefinery concept offering the co-production of biofuels, platform chemicals and energy; analogous to today's petroleum refineries which deliver both high-volume/low-value (e.g. fuels and commodity chemicals) and low-volume/high-value (e.g. fine/speciality chemicals) products, thereby maximizing biomass valorization. This article addresses the challenges to catalytic biomass processing and highlights recent successes in the rational design of heterogeneous catalysts facilitated by advances in nanotechnology and the synthesis of templated porous materials, as well as the use of tailored catalyst surfaces to generate bifunctional solid acid/base materials or tune hydrophobicity. PMID:26755755

  19. Effect of structured packing density on performance of air dehumidifier

    International Nuclear Information System (INIS)

    An experimental study has been conducted to investigate the performance of a liquid desiccant air dehumidifier equipped with a structured packing made of wood for three different densities using triethylene glycol (TEG) as the liquid desiccant. The structured packing densities used were 77, 100 and 200 m2/m3. The performance of the dehumidifier was expressed in terms of the moisture removal rate and the dehumidifier effectiveness under different air and desiccant parameters, i.e. the air and TEG flow rates, air and TEG inlet temperatures, inlet air humidity and inlet TEG concentration. In general, the trend in the dehumidifier performance was similar to that reported by other investigators using random packing. The effect of packing density on moisture removal rate and dehumidifier effectiveness is assessed. The differences in the effectiveness of different packing densities are attributed to the wetting condition. Lower effectiveness of the column is shown with the packing density of 200 m2/m3 compared to the other two packing densities when the air flow rate, inlet concentration and desiccant flow rate are increased. However, higher effectiveness is shown when either the inlet temperature of the air or desiccant is increased

  20. Effect of structured packing density on performance of air dehumidifier

    Energy Technology Data Exchange (ETDEWEB)

    Abdul-Wahab, S.A. E-mail: sabah1@squ.edu.om; Abu-Arabi, M.K.; Zurigat, Y.H

    2004-09-01

    An experimental study has been conducted to investigate the performance of a liquid desiccant air dehumidifier equipped with a structured packing made of wood for three different densities using triethylene glycol (TEG) as the liquid desiccant. The structured packing densities used were 77, 100 and 200 m{sup 2}/m{sup 3}. The performance of the dehumidifier was expressed in terms of the moisture removal rate and the dehumidifier effectiveness under different air and desiccant parameters, i.e. the air and TEG flow rates, air and TEG inlet temperatures, inlet air humidity and inlet TEG concentration. In general, the trend in the dehumidifier performance was similar to that reported by other investigators using random packing. The effect of packing density on moisture removal rate and dehumidifier effectiveness is assessed. The differences in the effectiveness of different packing densities are attributed to the wetting condition. Lower effectiveness of the column is shown with the packing density of 200 m{sup 2}/m{sup 3} compared to the other two packing densities when the air flow rate, inlet concentration and desiccant flow rate are increased. However, higher effectiveness is shown when either the inlet temperature of the air or desiccant is increased.

  1. Air dehumidification by triethylene glycol desiccant in a packed column

    International Nuclear Information System (INIS)

    The performance of an air dehumidifier using triethylene glycol (TEG) as desiccant under hot and humid conditions was investigated. The performance of the dehumidifier was evaluated and expressed in terms of the moisture removal rate and the dehumidifier effectiveness. A packed bed column (dehumidifier) was employed, with low packing density (77 m2/m3), to provide direct contact between the air and the TEG. Two different structured packings were used, wood and aluminum. The experiments covered a wide range of parameter space that included the air and TEG flow rates, air and TEG inlet temperatures, inlet air humidity and inlet TEG concentration. The liquid flow rate investigated is much less than that covered in previous studies (2 s). The trend of the dehumidifier performance was similar to that reported in the literature using high density and random packing. The results were compared to the Chung and Luo correlation, which over predicted the effectiveness. The Martin and Goswami correlation failed to predict the effectiveness under the conditions of this study. In the present study, it was found that the moisture removal rate increased with increasing inlet TEG concentration, TEG flow rate and air flow rate. This was seen for both the wood and the aluminum packings. In addition, the moisture removal rate is increased with increasing the inlet air temperature for the aluminum packing only. The effectiveness of the column was increased by increasing the TEG flow rate and inlet TEG temperature for the two packings

  2. Air dehumidification by triethylene glycol desiccant in a packed column

    Energy Technology Data Exchange (ETDEWEB)

    Zurigat, Y.H.; Abu-Arabi, M.K.; Abdul-Wahab, S.A. E-mail: sabah1@squ.edu.om

    2004-01-01

    The performance of an air dehumidifier using triethylene glycol (TEG) as desiccant under hot and humid conditions was investigated. The performance of the dehumidifier was evaluated and expressed in terms of the moisture removal rate and the dehumidifier effectiveness. A packed bed column (dehumidifier) was employed, with low packing density (77 m{sup 2}/m{sup 3}), to provide direct contact between the air and the TEG. Two different structured packings were used, wood and aluminum. The experiments covered a wide range of parameter space that included the air and TEG flow rates, air and TEG inlet temperatures, inlet air humidity and inlet TEG concentration. The liquid flow rate investigated is much less than that covered in previous studies (<1 kg/m{sup 2} s). The trend of the dehumidifier performance was similar to that reported in the literature using high density and random packing. The results were compared to the Chung and Luo correlation, which over predicted the effectiveness. The Martin and Goswami correlation failed to predict the effectiveness under the conditions of this study. In the present study, it was found that the moisture removal rate increased with increasing inlet TEG concentration, TEG flow rate and air flow rate. This was seen for both the wood and the aluminum packings. In addition, the moisture removal rate is increased with increasing the inlet air temperature for the aluminum packing only. The effectiveness of the column was increased by increasing the TEG flow rate and inlet TEG temperature for the two packings.

  3. Do gray wolves (Canis lupus) support pack mates during aggressive inter-pack interactions?

    Science.gov (United States)

    Cassidy, Kira A; McIntyre, Richard T

    2016-09-01

    For group-living mammals, social coordination increases success in everything from hunting and foraging (Crofoot and Wrangham in Mind the Gap, Springer, Berlin, 2010; Bailey et al. in Behav Ecol Sociobiol 67:1-17, 2013) to agonism (Mosser and Packer in Anim Behav 78:359-370, 2009; Wilson et al. in Anim Behav 83:277-291, 2012; Cassidy et al. in Behav Ecol 26:1352-1360, 2015). Cooperation is found in many species and, due to its low costs, likely is a determining factor in the evolution of living in social groups (Smith in Anim Behav 92:291-304, 2014). Beyond cooperation, many mammals perform costly behaviors for the benefit of group mates (e.g., parental care, food sharing, grooming). Altruism is considered the most extreme case of cooperation where the altruist increases the fitness of the recipient while decreasing its own fitness (Bell in Selection: the mechanism of evolution. Oxford University Press, Oxford 2008). Gray wolf life history requires intra-pack familiarity, communication, and cooperation in order to succeed in hunting (MacNulty et al. in Behav Ecol doi: 10.1093/beheco/arr159 2011) and protecting group resources (Stahler et al. in J Anim Ecol 82: 222-234, 2013; Cassidy et al. in Behav Ecol 26:1352-1360, 2015). Here, we report 121 territorial aggressive inter-pack interactions in Yellowstone National Park between 1 April 1995 and 1 April 2011 (>5300 days of observation) and examine each interaction where one wolf interferes when its pack mate is being attacked by a rival group. This behavior was recorded six times (17.6 % of interactions involving an attack) and often occurred between dyads of closely related individuals. We discuss this behavior as it relates to the evolution of cooperation, sociality, and altruism. PMID:27193460

  4. Enabling Microliquid Chromatography by Microbead Packing of Microchannels

    Science.gov (United States)

    Balvin, Manuel; Zheng, Yun

    2014-01-01

    The microbead packing is the critical element required in the success of on-chip microfabrication of critical microfluidic components for in-situ analysis and detection of chiral amino acids. In order for microliquid chromatography to occur, there must be a stationary phase medium within the microchannel that interacts with the analytes present within flowing fluid. The stationary phase media are the microbeads packed by the process discussed in this work. The purpose of the microliquid chromatography is to provide a lightweight, low-volume, and low-power element to separate amino acids and their chiral partners efficiently to understand better the origin of life. In order to densely pack microbeads into the microchannels, a liquid slurry of microbeads was created. Microbeads were extracted from a commercially available high-performance liquid chromatography column. The silica beads extracted were 5 microns in diameter, and had surface coating of phenyl-hexyl. These microbeads were mixed with a 200- proof ethanol solution to create a microbead slurry with the right viscosity for packing. A microfilter is placed at the outlet via of the microchannel and the slurry is injected, then withdrawn across a filter using modified syringes. After each injection, the channel is flushed with ethanol to enhance packing. This cycle is repeated numerous times to allow for a tightly packed channel of microbeads. Typical microbead packing occurs in the macroscale into tubes or channels by using highly pressurized systems. Moreover, these channels are typically long and straight without any turns or curves. On the other hand, this method of microbead packing is completed within a microchannel 75 micrometers in diameter. Moreover, the microbead packing is completed into a serpentine type microchannel, such that it maximizes microchannel length within a microchip. Doing so enhances the interactions of the analytes with the microbeads to separate efficiently amino acids and amino acid

  5. NO_x-assisted soot oxidation over K/CuCe catalyst

    Institute of Scientific and Technical Information of China (English)

    翁端; 李佳; 吴晓东; 司知蠢

    2010-01-01

    CeO2 and CuOx-CeO2 supported potassium catalysts were synthesized by wetness impregnation method. The catalysts were characterized by BET, NO-TPO, NOx-TPD and soot-TPO measurements. By the decoration of potassium and copper, the maximum soot combustion temperature of the ceria-based catalyst decreased to 338 and 379 °C in the presence and absence of NO under a loose contact mode, re- spectively. The pronouncedly enhanced NO oxidation ability by copper introduction and NOx storage capacity by potassium modif...

  6. Modethema Mode

    Directory of Open Access Journals (Sweden)

    Julia Bertschik

    2001-07-01

    Full Text Available Das Themenheft „Mode/Kunst – Fashion/Art“ der Zeitschrift figurationen versammelt heterogene Beiträge, die die Beziehung zwischen Kleidermode und Kunst von der Renaissance bis in die Gegenwart unter literaturwissenschaftlichem Schwerpunkt untersuchen. Reflexionen internationaler Künstler/-innen, Autorinnen und Autoren über die modischen Inszenierungsweisen des Körpers werden dabei auf ihre Darstellung der Geschlechter ebenso überprüft wie auf ihre ästhetische Stellung innerhalb des künstlerischen Gesamtwerks oder des zeitspezifischen Kanons.

  7. The Use of Inorganic Packing Materials during Methane Biofiltration

    OpenAIRE

    Josiane Nikiema; Michèle Heitz

    2010-01-01

    The objective behind this study is to select a suitable inorganic packing material for methane biofiltration. Three packing materials are to be compared: two rock materials (average particles' sizes: 2 and 5 mm) and one porous clay particles (average particle size of 7 mm). The main parameter used to assess the efficiency of the packing material is the methane elimination capacity. The study reveals that the rock material having an average particle size around 2 mm is to be preferred. This re...

  8. UNIFORM PACKING DIMENSION RESULTS FOR MULTIPARAMETER STABLE PROCESSES

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    In this article, authors discuss the problem of uniform packing dimension of the image set of multiparameter stochastic processes without random uniform H(o)lder condition, and obtain the uniform packing dimension of multiparameter stable processes.If Z is a stable (N, d, α)-process and αN ≤ d, then the following holds with probability 1 Dim Z(E) = α DimE for any Borel setE ∈ B(R+N),where Z(E) = {x: (E) t ∈ E, Z(t) = x}. Dim(E) denotes the packing dimension of E.

  9. Packing parameters effect on injection molding of polypropylene nanostructured surfaces

    DEFF Research Database (Denmark)

    Calaon, Matteo; Tosello, Guido; Hansen, Hans Nørgaard;

    2012-01-01

    In today´s industry, applications involving surface patterning of sub-μm to nanometer scale structures have shown a high growth potential. To investigate the injection molding capability of replicating sub-μm surface texture on a large scale area, a 30x80 mm2 tool insert with surface structures...... having a diameter of 500 nm was employed. The tool insert surface was produced using chemical-based-batch techniques such aluminum anodization and nickel electroplating. During the injection molding process, polypropylene (PP) was employed as material and packing phase parameters (packing time, packing...

  10. Multi-dimensional Bin Packing Problems with Guillotine Constraints

    DEFF Research Database (Denmark)

    Amossen, Rasmus Resen; Pisinger, David

    2010-01-01

    The problem addressed in this paper is the decision problem of determining if a set of multi-dimensional rectangular boxes can be orthogonally packed into a rectangular bin while satisfying the requirement that the packing should be guillotine cuttable. That is, there should exist a series of face...... parallel straight cuts that can recursively cut the bin into pieces so that each piece contains a box and no box has been intersected by a cut. The unrestricted problem is known to be NP-hard. In this paper we present a generalization of a constructive algorithm for the multi-dimensional bin packing...

  11. A Modeling Method for Small Packing Particles in Electromagnetic Simulation

    Directory of Open Access Journals (Sweden)

    Yi Cheng Zhong

    2016-01-01

    Full Text Available A modeling method for small packing particles is proposed in this paper, especially for the application of the electromagnetic simulation. This method is able to model random distributed and mutual-contacted packing particles efficiently and accurately. This modeling method is faster than a commonly used software, especially for large number of particles. The accuracy of this modeling method is validated by experiments of packing density and effective permittivity. The established model can be easily imported into commercial electromagnetic simulation software.

  12. Replacement of the cooling tower packing at the Goesgen-Daeniken AG nuclear power plant

    International Nuclear Information System (INIS)

    In 2005 the asbestos cement cooling tower packing was replaced by plastic material. Two years later, the packing showed strong deformations, deposits of solids and weight gain. At the end of 2007 parts of the packing collapsed into the cooling tower basin. Investigations were made, revealing that the thickness of the packing foil was too low and that packing geometry and biofilms on the surface of the packing favoured deposition of solids. Successful measures were taken to solve the problems. (orig.)

  13. Upper threshold for stability of multipole-mode solitons in nonlocal nonlinear media

    OpenAIRE

    Xu, Zhiyong; Kartashov, Yaroslav V.; Torner, Lluis

    2005-01-01

    We address the stability of multipole-mode solitons in nonlocal Kerr-type nonlinear media. Such solitons comprise several out-of-phase peaks packed together by the forces acting between them. We discover that dipole-, triple-, and quadrupole-mode solitons can be made stable, whereas all higher-order soliton bound states are unstable.

  14. Stereospecific olefin polymerization catalysts

    Science.gov (United States)

    Bercaw, John E.; Herzog, Timothy A.

    1998-01-01

    A metallocene catalyst system for the polymerization of .alpha.-olefins to yield stereospecific polymers including syndiotactic, and isotactic polymers. The catalyst system includes a metal and a ligand of the formula ##STR1## wherein: R.sup.1, R.sup.2, and R.sup.3 are independently selected from the group consisting of hydrogen, C.sub.1 to C.sub.10 alkyl, 5 to 7 membered cycloalkyl, which in turn may have from 1 to 3 C.sub.1 to C.sub.10 alkyls as a substituent, C.sub.6 to C.sub.15 aryl or arylalkyl in which two adjacent radicals may together stand for cyclic groups having 4 to 15 carbon atoms which in turn may be substituted, or Si(R.sup.8).sub.3 where R.sup.8 is selected from the group consisting of C.sub.1 to C.sub.10 alkyl, C.sub.6 to C.sub.15 aryl or C.sub.3 to C.sub.10 cycloalkyl; R.sup.4 and R.sup.6 are substituents both having van der Waals radii larger than the van der Waals radii of groups R.sup.1 and R.sup.3 ; R.sup.5 is a substituent having a van der Waals radius less than about the van der Waals radius of a methyl group; E.sup.1, E.sup.2 are independently selected from the group consisting of Si(R.sup.9).sub.2, Si(R.sup.9).sub.2 --Si(R.sup.9).sub.2, Ge(R.sup.9).sub.2, Sn(R.sup.9).sub.2, C(R.sup.9).sub.2, C(R.sup.9).sub.2 --C(R.sup.9).sub.2, where R.sup.9 is C.sub.1 to C.sub.10 alkyl, C.sub.6 to C.sub.15 aryl or C.sub.3 to C.sub.10 cycloalkyl; and the ligand may have C.sub.S or C.sub.1 -symmetry. Preferred metals are selected from the group consisting of group III, group IV, group V or lanthanide group elements. The catalysts are used to prepare stereoregular polymers including polypropylene from .alpha.-olefin monomers.

  15. Ceramic catalyst materials

    Energy Technology Data Exchange (ETDEWEB)

    Sault, A.G.; Gardner, T.J. [Sandia National Laboratories, Albuquerque, NM (United States); Hanprasopwattanna, A.; Reardon, J.; Datye, A.K. [Univ. of New Mexico, Albuquerque, NM (United States)

    1995-08-01

    Hydrous titanium oxide (HTO) ion-exchange materials show great potential as ceramic catalyst supports due to an inherently high ion-exchange capacity which allows facile loading of catalytically active transition metal ions, and an ability to be cast as thin films on virtually any substrate. By coating titania and HTO materials onto inexpensive, high surface area substrates such as silica and alumina, the economics of using these materials is greatly improved, particularly for the HTO materials, which are substantially more expensive in the bulk form than other oxide supports. In addition, the development of thin film forms of these materials allows the catalytic and mechanical properties of the final catalyst formulation to be separately engineered. In order to fully realize the potential of thin film forms of titania and HTO, improved methods for the deposition and characterization of titania and HTO films on high surface area substrates are being developed. By varying deposition procedures, titania film thickness and substrate coverage can be varied from the submonolayer range to multilayer thicknesses on both silica and alumina. HTO films can also be formed, but the quality and reproducibility of these films is not nearly as good as for pure titania films. The films are characterized using a combination of isopropanol dehydration rate measurements, point of zero charge (PZC) measurements, BET surface area, transmission electron microscopy (TEM), and elemental analysis. In order to assess the effects of changes in film morphology on catalytic activity, the films are being loaded with MoO{sub 3} using either incipient wetness impregnation or ion-exchange of heptamolybdate anions followed by calcining. The MoO{sub 3} is then sulfided to form MOS{sub 2}, and tested for catalytic activity using pyrene hydrogenation and dibenzothiophene (DBT) desulfurization, model reactions that simulate reactions occurring during coal liquefaction.

  16. An effective evolutionary algorithm for the multiple container packing problem

    Institute of Scientific and Technical Information of China (English)

    Sang-Moon Soak; Sang-Wook Lee; Gi-Tae Yeo; Moon-Gu Jeon

    2008-01-01

    This paper focuses on a new optimization problem, which is called "The Multiple Container Packing Problem (MCPP)" and proposes a new evolutionary approach for it. The proposed evolutionary approach uses "Adaptive Link Adjustment Evolutionary Algorithm (ALA-EA)" as a basic framework and it incorporates a heuristic local improvement approach into ALA-EA. The first step of the local search algorithm is to raise empty space through the exchange among the packed items and then to improve the fitness value through packing unpacked items into the raised empty space. The second step is to exchange the packed items and the unpacked items one another toward improving the fitness value. The proposed algorithm is compared to the previous evolutionary approaches at the benchmark instances (with the same container capacity) and the modified benchmark instances (with different container capacity) and that the algorithm is proved to be superior to the previous evolutionary approaches in the solution quality.

  17. Preparation and characterization of hexagonal close-packed Ni nanoparticles

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Hexagonal close-packed Ni nanoparticles were synthesized using a heat-treating technique with the precursors prepared by the sol-gel method.The synthesis condition,structure,and morphology of the samples were characterized and analysed by thermogravimetric analysis (TG),differential thermal analysis (DTA),X-ray diffraction (XRD) and transmission electron microscopy (TEM).Results indicate that the hexagonal close packed Ni nanoparticles were synthesized at a heat-treating temperature of 300℃.The cell constants are calculated at a=0.2652 nm and c=0.4334 nm.The average grain size of the hexagonal close-packed Ni particles evaluated by Scherrer equation is about 12 nm.The phase transformation from a hexagonal close-packed Ni to a face-centered cubic Ni structure occurred when the heat-treating temperature was increased.

  18. Excise Tax Rates On Packs Of Cigarettes PDF Slides

    Data.gov (United States)

    U.S. Department of Health & Human Services — Download the current excise tax rates on packs of cigarettes slides. These slides are available in PDF and PowerPoint formats. The PowerPoint version can be found...

  19. Estimation of maximum coated particle fuel compact packing fraction

    International Nuclear Information System (INIS)

    This work develops an analytic fuel fraction packing model for a high temperature gas cooled reactor fuel compact fabricated from overcoated particles of a single size. The model includes the effects of one dimensional compression and finite matrix grain size. One dimensional compression limits the maximum fuel packing fraction to about 48% for the pressed compact in this single sized particle system. This limit is due to two effects. The first is that the process of die loading limits the pre-compression packing configuration to one that is stable under gravity, which is not the most space efficient one. The second effect is due to the one dimensional compression which reduces only the axial dimension of the particle lattice rather than uniformly compressing the lattice. The die wall can also limit the maximum packing fraction by preventing the nearby particles from moving into a more space efficient configuration

  20. Evaluation of Hematological Parameters in Partial Exchange and Packed Cell Transfusion in Treatment of Severe Anemia in Pregnancy

    Directory of Open Access Journals (Sweden)

    Sudha Salhan

    2012-01-01

    Full Text Available Objectives. Anemia is a major public health problem throughout the world which assumes prominence in pregnant mothers. Patients with severe anemia continue to present themselves at term or in labor. This study was conducted to compare the improvements in hematological parameters of patients receiving partial exchange blood transfusion and transfusion of packed cells without exchange. Methods. One hundred and twenty-five severely anemic antenatal mothers were admitted from outpatient service. Partial exchange transfusion was given to sixty-six patients while fifty-nine received transfusion of packed cells with frusemide cover. Results. The two groups were comparable in terms of age, height, weight, religion, diet, education, occupation of self and husband, and income. Hemoglobin level in Group 1 was comparatively less than Group 2 at prelevel (5.2±1.5 versus 6.6±2.3, P=0.001 and postlevel (7.2±1.5 versus 8.6±1.8, P=0.001, respectively, but there was no significant difference between the two modes of transfusion (2.09±1.6 versus 2.01±1.5, P=0.78. Conclusion. The study produced an equally significant improvement in hematological parameters in partial exchange and packed cell transfusion. Platelet counts were significantly less in partial exchange as compared with packed cell transfusion.

  1. Magnetically Recoverable Ruthenium Catalysts in Organic Synthesis

    OpenAIRE

    Dong Wang; Didier Astruc

    2014-01-01

    Magnetically recyclable catalysts with magnetic nanoparticles (MNPs) are becoming a major trend towards sustainable catalysts. In this area, recyclable supported ruthenium complexes and ruthenium nanoparticles occupy a key place and present great advantages compared to classic catalysts. In this micro-review, attention is focused on the fabrication of MNP-supported ruthenium catalysts and their catalytic applications in various organic syntheses.

  2. Random close packing fractions of lognormal distributions of hard spheres

    OpenAIRE

    Farr, Robert S.

    2013-01-01

    We apply a recent one-dimensional algorithm for predicting random close packing fractions of polydisperse hard spheres [Farr and Groot, J. Chem. Phys. 133, 244104 (2009)] to the case of lognormal distributions of sphere sizes and mixtures of such populations. We show that the results compare well to two much slower algorithms for directly simulating spheres in three dimensions, and show that the algorithm is fast enough to tackle inverse problems in particle packing: designing size distributi...

  3. Integrating packing and distribution problems and optimization through mathematical programming

    OpenAIRE

    Fabio Miguel; Mariano Frutos; Fernando Tohmé; Máximo Méndez

    2016-01-01

    This paper analyzes the integration of two combinatorial problems that frequently arise in production and distribution systems. One is the Bin Packing Problem (BPP) problem, which involves finding an ordering of some objects of different volumes to be packed into the minimal number of containers of the same or different size. An optimal solution to this NP-Hard problem can be approximated by means of meta-heuristic methods. On the other hand, we consider the Capacitated Vehicle Routing Proble...

  4. [Promising technologies of packed red blood cells production and storage].

    Science.gov (United States)

    Maksimov, A G; Golota, A S; Krassiĭ, A B

    2013-10-01

    The current article is dedicated to promising technologies of packed red blood cells production and storage. The following new technical approaches are presented: (1) erythrocytes storage in strict anaerobic argon-hydrogen environment, (2) lyophilization of erythrocyte suspension by its atomization in nitrogen gas, (3) lyophilization of erythrocytes by directional freezing under the influence of radio frequency radiation, (4) automated pharming of antigen free packed red blood cells from progenitor cell directly at the battlefield. PMID:24611298

  5. Shock-Induced Flows through Packed Beds: Transient Regimes

    CERN Document Server

    Shtemler, Yuri M; Britan, Alex

    2006-01-01

    The early stage of the transient regimes in the shock-induced flows within solid-packed beds are investigated in the linear longwave and high-frequency approximation. The transient resistance law is refined as the Duhameltime integral that follows from the general concept of dynamic tortuosity and compressibility of the packed beds. A closed-form solution is expected to describe accurately the early stage of the transient regime flow and is in qualitative agreement with available experimental data.

  6. Computational Fluid Dynamics Simulation of Multiphase Flow in Structured Packings

    OpenAIRE

    Saeed Shojaee; Seyyed Hossein Hosseini; Behzad Saeedi Razavi

    2012-01-01

    A volume of fluid multiphase flow model was used to investigate the effective area and the created liquid film in the structured packings. The computational results revealed that the gas and liquid flow rates play significant roles in the effective interfacial area of the packing. In particular, the effective area increases as the flow rates of both phases increase. Numerical results were compared with the Brunazzi and SRP models, and a good agreement between them was found. Attention was gi...

  7. [Promising technologies of packed red blood cells production and storage].

    Science.gov (United States)

    Maksimov, A G; Golota, A S; Krassiĭ, A B

    2013-10-01

    The current article is dedicated to promising technologies of packed red blood cells production and storage. The following new technical approaches are presented: (1) erythrocytes storage in strict anaerobic argon-hydrogen environment, (2) lyophilization of erythrocyte suspension by its atomization in nitrogen gas, (3) lyophilization of erythrocytes by directional freezing under the influence of radio frequency radiation, (4) automated pharming of antigen free packed red blood cells from progenitor cell directly at the battlefield.

  8. Model for surface packing and aeolian transport on sand ripples

    Science.gov (United States)

    Louge, M. Y.; Valance, A.; el-Moctar, A. Ould; Ahmedou, D. Ould; Dupont, P.

    2009-06-01

    Measurements indicate that the solid volume fraction on a sand ripple varies from random jammed packing at troughs to the minimum stable packing at crests. By relating variations of the solid volume fraction to those of the surface turbulent shear stress, a collisional model of reptation suggests a qualitative origin for these observations. Although the model overestimates the critical shear velocity at which reptation arises, it predicts the rate of aeolian transport on Earth and Mars.

  9. Preparation of Zirconia Based Packing Material and Its Evaluation

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A new reversed-phase packing (C18-PBD-ZrO2) was prepared by depositing and cross-linking 1-octadecene (ODE or C18) and polybutadiene (PBD) onto the surface of porous zirconia microspheres (5~10 mm in diameter) which were synthesized by a sol-gel process. These novel column packings possess high mechanical and chemical stability,wider usable pH range and can be used to separate basic compounds with no observable peak tailing.

  10. Damped Arrow-Hurwicz algorithm for sphere packing

    OpenAIRE

    Degond, Pierre; Ferreira, Marina A.; Motsch, Sébastien

    2016-01-01

    We consider algorithms that, from an arbitrarily sampling of $N$ spheres (possibly overlapping), find a close packed configuration without overlapping. These problems can be formulated as minimization problems with non-convex constraints. For such packing problems, we observe that the classical iterative Arrow-Hurwicz algorithm does not converge. We derive a novel algorithm from a multi-step variant of the Arrow-Hurwicz scheme with damping. We compare this algorithm with classical algorithms ...

  11. A SAT Encoding for Multi-dimensional Packing Problems

    Science.gov (United States)

    Grandcolas, Stéphane; Pinto, Cédric

    The Orthogonal Packing Problem (OPP) consists in determining if a set of items can be packed into a given container. This decision problem is NP-complete. Fekete et al. modelled the problem in which the overlaps between the objects in each dimension are represented by interval graphs. In this paper we propose a SAT encoding of Fekete et al. characterization. Some results are presented, and the efficiency of this approach is compared with other SAT encodings.

  12. Impeded solid state reactions and transformations in ceramic catalysts supports and catalysts

    Directory of Open Access Journals (Sweden)

    Ernő E. Kiss

    2012-12-01

    Full Text Available Impeded chemical reactions and impeded polymorphous transformation in materials are discussed, as desired effects, for stabilization of ceramic catalyst supports and ceramic based catalysts. This paper gives a short overview about the possibilities of slowing down the aging processes in ceramic catalyst supports and catalysts. Special attention is given to alumina and titania based catalysts.

  13. Heuristic Placement Routines for Two-Dimensional Bin Packing Problem

    Directory of Open Access Journals (Sweden)

    L. Wong

    2009-01-01

    Full Text Available Problem statement: Cutting and packing (C and P problems are optimization problems that are concerned in finding a good arrangement of multiple small items into one or more larger objects. Bin packing problem is a type of C AND P problems. Bin packing problem is an important industrial problem where the general objective is to reduce the production costs by maximizing the utilization of the larger objects and minimizing the material used. Approach: In this study, we considered both oriented and non-oriented cases of Two-Dimensional Bin Packing Problem (2DBPP where a given set of small rectangles (items, was packed without overlaps into a minimum number of identical large rectangles (bins. We proposed heuristic placement routines called the Improved Lowest Gap Fill, LGFi and LGFiOF for solving non-oriented and oriented cases of 2DBPP respectively. Extensive computational experiments using benchmark data sets collected from the literature were conducted to assess the effectiveness of the proposed routines. Results: The computational results were compared with some well known heuristic placement routines. The results showed that the LGFi and LGFiOF are competitive when compared with other heuristic placement routines. Conclusion: Both LGFi and LGFiOF produced better packing quality compared to other heuristic placement routines.

  14. Novel equipment for testing catalytic cracking and catalyst regeneration with short contact times

    Energy Technology Data Exchange (ETDEWEB)

    Lipiaeinen, K.; Hagelberg, P.; Aittamaa, J.; Eilos, I.; Hiltunen, J.; Niemi, V.M. [Fortum Oil and Gas Oy, P. O. Box 310, FIN-06101 Porvoo (Finland); Krause, A.O.I. [Helsinki University of Technology, Department of Chemical Technology, P. O. Box 6100, FIN-02015 HUT (Finland)

    1999-07-19

    A new piece of equipment was developed for testing catalytic cracking and catalyst regeneration, particularly for short contact times. The gas oil to be cracked is injected into the upper section of the reactor, which can be operated in the temperature range 400-800C, catalyst-to-oil ratios from 0 to 300g{sub cat}/g{sub oil} and residence times between 0.01 and 2.3s. The product is led directly into the analysis section where hydrocarbons from C{sub 1} to C{sub 12} (in total 350 compounds) are separated by a capillary column. In catalyst regeneration studies oxygen/nitrogen pulses are fed into the reactor via a gas-loop. The carbon monoxide and carbon dioxide formed are first separated in a packed column after which they are converted to methane by hydrogen on a Ni/{gamma}-Al{sub 2}O{sub 3} catalyst ensuring the determination of even small amounts of coke. The reproducibility of the experiments has proved to be excellent. With this new reactor system, accurate information can be obtained on the initial activity of the catalyst and product distribution

  15. Tritium removal by hydrogen isotopic exchange between hydrogen gas and water on hydrophobic catalyst

    International Nuclear Information System (INIS)

    Many kinds of the hydrophobic catalysts for hydrogen isotopic exchange between hydrogen gas and water have been prepared. The carriers are the hydrophobic organic materials such as polytetrafluoroethylene(PTFE), monofluorocarbon-PTFE mixture(PTFE-FC), and styrene-divinylbenzene copolymer(SDB). 0.1 to 2 wt % Pt is deposited on the carriers. The Pt/SDB catalyst has much higher activity than the Pt/PTFE catalyst and the Pt/PTFE-FC catalyst shows the intermediate value of catalytic activity. The observation of electron microscope shows that the degrees of dispersion of Pt particles on the hydrophobic carriers result in the difference of catalytic activities. A gas-liquid separated type column containing ten stages is constructed. Each stage is composed of both the hydrophobic catalyst bed for the hydrogen gas/water vapor isotopic exchange and the packed column type bed for the water vapor/liquid water isotopic exchange. In the column hydrogen gas and water flow countercurrently and hydrogen isotopes are separated

  16. Computational Chemistry-Based Identification of Ultra-Low Temperature Water-Gas-Shift Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Manos Mavrikakis

    2008-08-31

    The current work seeks to identify novel, catalytically-active, stable, poison-resistant LWGS catalysts that retain the superior activity typical of conventional Cu catalysts but can be operated at similar or lower temperatures. A database for the Binding Energies (BEs) of the LWGS relevant species, namely CO, O and OH on the most-stable, close-packed facets of a set of 17 catalytically relevant transition metals was established. This BE data and a database of previously established segregation energies was utilized to predict the stability of bimetallic NSAs that could be synthesized by combinations of the 17 parent transition metals. NSAs that were potentially stable both in vacuo and under the influence of strong-binding WGS intermediates were then selected for adsorption studies. A set of 40 NSAs were identified that satisfied all three screener criteria and the binding energies of CO, O and OH were calculated on a set of 66, 43 and 79 NSA candidates respectively. Several NSAs were found that bound intermediates weaker than the monometallic catalysts and were thus potentially poison-resistant. Finally, kinetic studies were performed and resulted in the discovery of a specific NSA-based bimetallic catalyst Cu/Pt that is potentially a promising LWGS catalyst. This stable Cu/Pt subsurface alloy is expected to provide facile H{sub 2}O activation and remain relatively resistant from the poisoning by CO, S and formate intermediates.

  17. Alumina supported iridium catalysts - preparation

    International Nuclear Information System (INIS)

    This report describes the method employed in the preparation of alumina supported iridium catalysts, with metal contents between 30 and 40%, that will be used for hydrazine monopropellant decomposition. (author)

  18. Duplex steam reformer: alternate catalyst

    International Nuclear Information System (INIS)

    The manufacturing feasibility of a duplex steam reformer tube for potential use in a high temperature gas cooled reactor has been successfully demonstrated. This technique consists of explosively expanding the inner tube into the outer tube. To successfully achieve the desired 0 to 3 mil radial gap between the tubes it is necessary to perform the expansion in two steps with an intermediate anneal. A catalyst design that would have replaced the conventional Raschig rings with a metal supported catalyst has been evaluated and it has been concluded that further development and testing are needed before fabrication of a full scale prototype is warranted. Consequently, the immediate efforts are directed towards reevaluating the incentives for developing a catalyst and the probability of successfully developing a catalyst that could be used for steam reforming

  19. Generation of Random Particle Packings for Discrete Element Models

    Science.gov (United States)

    Abe, S.; Weatherley, D.; Ayton, T.

    2012-04-01

    An important step in the setup process of Discrete Element Model (DEM) simulations is the generation of a suitable particle packing. There are quite a number of properties such a granular material specimen should ideally have, such as high coordination number, isotropy, the ability to fill arbitrary bounding volumes and the absence of locked-in stresses. An algorithm which is able to produce specimens fulfilling these requirements is the insertion based sphere packing algorithm originally proposed by Place and Mora, 2001 [2] and extended in this work. The algorithm works in two stages. First a number of "seed" spheres are inserted into the bounding volume. In the second stage the gaps between the "seed" spheres are filled by inserting new spheres in a way so they have D+1 (i.e. 3 in 2D, 4 in 3D) touching contacts with either other spheres or the boundaries of the enclosing volume. Here we present an implementation of the algorithm and a systematic statistical analysis of the generated sphere packings. The analysis of the particle radius distribution shows that they follow a power-law with an exponent ≈ D (i.e. ≈3 for a 3D packing and ≈2 for 2D). Although the algorithm intrinsically guarantees coordination numbers of at least 4 in 3D and 3 in 2D, the coordination numbers realized in the generated packings can be significantly higher, reaching beyond 50 if the range of particle radii is sufficiently large. Even for relatively small ranges of particle sizes (e.g. Rmin = 0.5Rmax) the maximum coordination number may exceed 10. The degree of isotropy of the generated sphere packing is also analysed in both 2D and 3D, by measuring the distribution of orientations of vectors joining the centres of adjacent particles. If the range of particle sizes is small, the packing algorithm yields moderate anisotropy approaching that expected for a face-centred cubic packing of equal-sized particles. However, once Rmin < 0.3Rmax a very high degree of isotropy is demonstrated in

  20. Copper containing hydrocarbon cracking catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Lussier, R.J.; Magee, J.S. Jr.

    1975-12-30

    A copper-exchanged zeolite cracking catalyst capable of producing high octane gasoline of increased aromatic and olefinic content is described. Mixtures of copper and hydrogen ions are exchanged into a Y-type zeolite using a combination of exchange and calcination steps. The exchanged zeolite is advantageously combined with a major portion of inorganic oxide matrix to produce a catalyst suitable for use in standard commercial fluid and moving bed cat-cracking units. (auth)

  1. Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Topical report No. 14. Catalyst activity trends in two-stage coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    1984-02-01

    The Two Stage Coal Liquefaction process became operational at Wilsonville in May 1981, with the inclusion of an H-OIL ebullated-bed catalytic reactor. The two stage process was initially operated in a nonintegrated mode and has recently been reconfigurated to fully integrate the thermal and the catalytic stages. This report focuses on catalyst activity trends observed in both modes of operation. A literature review of relevant catalyst screening studies in bench-scale and PDU units is presented. Existing kinetic and deactivation models were used to analyze process data over an extensive data base. Based on the analysis, three separate, application studies have been conducted. The first study seeks to elucidate the dependence of catalyst deactivation rate on type of coal feedstock used. A second study focuses on the significance of catalyst type and integration mode on SRC hydrotreatment. The third study presents characteristic deactivation trends observed in integrated operation with different first-stage thermal severities. In-depth analytical work was conducted at different research laboratories on aged catalyst samples from Run 242. Model hydrogenation and denitrogenation activity trends are compared with process activity trends and with changes observed in catalyst porosimetric properties. The accumulation of metals and coke deposits with increasing catalyst age, as well as their distribution across a pellet cross-section, are discussed. The effect of catalyst age and reactor temperature on the chemical composition of flashed bottoms product is addressed. Results from regenerating spent catalysts are also presented. 35 references, 31 figures, 18 tables.

  2. Chemical transformations drive complex self-assembly of uracil on close-packed coinage metal surfaces.

    Science.gov (United States)

    Papageorgiou, Anthoula C; Fischer, Sybille; Reichert, Joachim; Diller, Katharina; Blobner, Florian; Klappenberger, Florian; Allegretti, Francesco; Seitsonen, Ari P; Barth, Johannes V

    2012-03-27

    We address the interplay of adsorption, chemical nature, and self-assembly of uracil on the Ag(111) and Cu(111) surfaces as a function of molecular coverage (0.3 to 1 monolayer) and temperature. We find that both metal surfaces act as templates and the Cu(111) surface acts additionally as a catalyst for the resulting self-assembled structures. With a combination of STM, synchrotron XPS, and NEXAFS studies, we unravel a distinct polymorphism on Cu(111), in stark contrast to what is observed for the case of uracil on the more inert Ag(111) surface. On Ag(111) uracil adsorbs flat and intact and forms close-packed two-dimensional islands. The self-assembly is driven by stable hydrogen-bonded dimers with poor two-dimensional order. On Cu(111) complex structures are observed exhibiting, in addition, a strong annealing temperature dependence. We determine the corresponding structural transformations to be driven by gradual deprotonation of the uracil molecules. Our XPS study reveals unambiguously the tautomeric signature of uracil in the contact layer and on Cu(111) the molecule's deprotonation sites. The metal-mediated deprotonation of uracil and the subsequent electron localization in the molecule determine important biological reactions. Our data show a dependence between molecular coverage and molecule-metal interaction on Cu(111), as the molecules tilt at higher coverages in order to accommodate a higher packing density. After deprotonation of both uracil N atoms, we observe an adsorption geometry that can be understood as coordinative anchoring with a significant charge redistribution in the molecule. DFT calculations are employed to analyze the surface bonding and accurately describe the pertaining electronic structure.

  3. The innovation catalysts.

    Science.gov (United States)

    Martin, Roger L

    2011-06-01

    A few years ago the software development company Intuit realized that it needed a new approach to galvanizing customers. The company's Net Promoter Score was faltering, and customer recommendations of new products were especially disappointing. Intuit decided to hold a two-day, off-site meeting for the company's top 300 managers with a focus on the role of design in innovation. One of the days was dedicated to a program called Design for Delight. The centerpiece of the day was a PowerPoint presentation by Intuit founder Scott Cook, who realized midway through that he was no Steve Jobs: The managers listened dutifully, but there was little energy in the room. By contrast, a subsequent exercise in which the participants worked through a design challenge by creating prototypes, getting feedback, iterating, and refining, had them mesmerized. The eventual result was the creation of a team of nine design-thinking coaches--"innovation catalysts"--from across Intuit who were made available to help any work group create prototypes, run experiments, and learn from customers. The process includes a "painstorm" (to determine the customer's greatest pain point), a "soljam" (to generate and then winnow possible solutions), and a "code-jam" (to write code "good enough" to take to customers within two weeks). Design for Delight has enabled employees throughout Intuit to move from satisfying customers to delighting them. PMID:21714388

  4. The innovation catalysts.

    Science.gov (United States)

    Martin, Roger L

    2011-06-01

    A few years ago the software development company Intuit realized that it needed a new approach to galvanizing customers. The company's Net Promoter Score was faltering, and customer recommendations of new products were especially disappointing. Intuit decided to hold a two-day, off-site meeting for the company's top 300 managers with a focus on the role of design in innovation. One of the days was dedicated to a program called Design for Delight. The centerpiece of the day was a PowerPoint presentation by Intuit founder Scott Cook, who realized midway through that he was no Steve Jobs: The managers listened dutifully, but there was little energy in the room. By contrast, a subsequent exercise in which the participants worked through a design challenge by creating prototypes, getting feedback, iterating, and refining, had them mesmerized. The eventual result was the creation of a team of nine design-thinking coaches--"innovation catalysts"--from across Intuit who were made available to help any work group create prototypes, run experiments, and learn from customers. The process includes a "painstorm" (to determine the customer's greatest pain point), a "soljam" (to generate and then winnow possible solutions), and a "code-jam" (to write code "good enough" to take to customers within two weeks). Design for Delight has enabled employees throughout Intuit to move from satisfying customers to delighting them.

  5. Synthesis and characterization of supported sugar catalyst by dip coating method

    Science.gov (United States)

    Janaun, J.; Siambun, N. J.; Safie, N. N.

    2016-06-01

    Sugar catalyst is a novel solid acid catalyst with reactivity comparable to that of sulphuric acid in biodiesel production. However, the fine powder form of sugar catalyst with the non-porous structure might cause large pressure drop in a packed bed reactor due to low bed porosity, affecting the reaction conversion especially in gas phase reaction. Furthermore, higher pressure drop requires higher electrical energy to drive the fluid through. Increasing the particle size is anticipated to be able to overcome the pressure drop matter. Hence, a deposition of sugar catalyst on larger particle materials was studied. Three types of materials were used for this investigation namely aluminum, silica and clay. The deposition was done via dip-coating method. The materials were characterized for their total acidity, thermal stability, functional groups, surface area, and element composition. The total acidity for SCDCAl, SCDCSi, and SCDCCl were 0.9 mmol/g, 0.2 mmol/g, and 0.4 mmol/g, respectively. The ratio of char deposited on SCDCAl, SCDCSi and SCDCCl were 0.9 g of support/g of carbon, 0.040 g of support/g of carbon, and 0.014 g of support/g of carbon respectively. FTIR and EDX analyses were carried out to determine the presence of active sites of the catalysis by identifying the functional groups such as -COOH, -OH, -SO3H. The results showed that -SO3H was detected on the surface of synthesized catalysts, except for SCDCC1.The pore size of SCDCAl, SCDCSi and SCDCCl were classified as macropores because the average diameter were greater than 50nm.. The catalysts were stable up to 400°C. The results showed that the dipcoating method could deposit sugar catalyst on aluminum, silica, and clay at low total acidity concentration.

  6. The exact packing measure for a random re-ordering of the Cantor set

    Institute of Scientific and Technical Information of China (English)

    胡晓予

    1996-01-01

    The packing measure for a random re-ordering of the Cantor set, the packing dimension for the random set belonging to a sequence satisfying the Hausdorff and packing measures and packing measures for random subsets of R belonging to a regular sequence have been obtained.

  7. Expanded and packed bed albumin adsorption on fluoride modified zirconia.

    Science.gov (United States)

    Mullick, A; Griffith, C M; Flickinger, M C

    1998-11-01

    The expanded bed characteristics of 75-103microm fluoride-modified zirconia (FmZr) particles synthesized by a fed batch oil emulsion process were investigated. These particles are distinguished from commercially available expanded-bed adsorbents by virtue of their high density (2.8 g/cc) and the mixed mode protein retention mechanism which allows for the retention of both cationic and anionic proteins. The linear velocity versus bed porosity data agree with the Richardson-Zaki relationship with the terminal velocity in infinite medium of 2858.4 cm/h and a bed expansion index of 5.1. Residence time distribution (RTD) studies and bovine serum albumin (BSA) adsorption studies were performed as a function of the height of the settled bed to the column diameter (H:D) ratio and degree of bed expansion with superficial velocities of 440 to 870 cm/h. The settled bed, a 2x expanded bed, and a 3x expanded bed were studied for the H:D ratios of 1:1, 2:1, and 3:1. The dynamic binding capacity (DBC) at 5% breakthrough was low (2-8 mg BSA/mL settled bed) and was independent of the H:D ratio or the degree of bed expansion. The saturation DBC was 32.3 +/- 7.0 mg BSA/mL settled bed. The adsorption-desorption kinetics and intraparticle diffusion for protein adsorption on FmZr (38-75 micrometer) were investigated by studying the packed bed RTD and BSA adsorption as a function of temperature and flow rate. The data show that the adsorption-desorption kinetics along with intraparticle diffusion significantly influence protein adsorption on FmZr. Low residence times ( approximately 0.8 min) of BSA result in a DBC at 5% breakthrough which is 3.5-fold lower compared to that at 6-fold higher protein residence time. At low linear velocity (45 cm/h) the breakthrough curve is nearly symmetrical and becomes asymmetrical and more dispersed at higher linear velocity (270 cm/h) due to the influence of slow adsorption-desorption kinetics and intraparticle diffusion. Bioeng 60: 333-340, 1998. PMID

  8. Effect of gravity on colloid transport through water-saturated columns packed with glass beads: modeling and experiments.

    Science.gov (United States)

    Chrysikopoulos, Constantinos V; Syngouna, Vasiliki I

    2014-06-17

    The role of gravitational force on colloid transport in water-saturated columns packed with glass beads was investigated. Transport experiments were performed with colloids (clays: kaolinite KGa-1b, montmorillonite STx-1b). The packed columns were placed in various orientations (horizontal, vertical, and diagonal) and a steady flow rate of Q = 1.5 mL/min was applied in both up-flow and down-flow modes. All experiments were conducted under electrostatically unfavorable conditions. The experimental data were fitted with a newly developed, analytical, one-dimensional, colloid transport model. The effect of gravity is incorporated in the mathematical model by combining the interstitial velocity (advection) with the settling velocity (gravity effect). The results revealed that flow direction influences colloid transport in porous media. The rate of particle deposition was shown to be greater for up-flow than for down-flow direction, suggesting that gravity was a significant driving force for colloid deposition.

  9. Performance of high-rate gravel-packed oil wells

    Energy Technology Data Exchange (ETDEWEB)

    Unneland, Trond

    2001-05-01

    Improved methods for the prediction, evaluation, and monitoring of performance in high-rate cased-hole gravel-packed oil wells are presented in this thesis. The ability to predict well performance prior to the gravel-pack operations, evaluate the results after the operation, and monitor well performance over time has been improved. This lifetime approach to performance analysis of gravel-packed oil wells contributes to increase oil production and field profitability. First, analytical models available for prediction of performance in gravel-packed oil wells are reviewed, with particular emphasis on high-velocity flow effects. From the analysis of field data from three North Sea oil fields, improved and calibrated cased-hole gravel-pack performance prediction models are presented. The recommended model is based on serial flow through formation sand and gravel in the perforation tunnels. In addition, new correlations for high-velocity flow in high-rate gravel-packed oil wells are introduced. Combined, this improves the performance prediction for gravel-packed oil wells, and specific areas can be targeted for optimized well design. Next, limitations in the current methods and alternative methods for evaluation and comparison of well performance are presented. The most widely used parameter, the skin factor, remains a convenient and important parameter. However, using the skin concept in direct comparisons between wells with different reservoir properties may result in misleading or even invalid conclusions. A discussion of the parameters affecting the skin value, with a clarification of limitations, is included. A methodology for evaluation and comparison of gravel-packed well performance is presented, and this includes the use of results from production logs and the use of effective perforation tunnel permeability as a parameter. This contributes to optimized operational procedures from well to well and from field to field. Finally, the data sources available for

  10. Important notice for Windows 2000 Service Pack 3 computers

    CERN Multimedia

    The NICE Team

    2005-01-01

    Microsoft is ending support for Windows 2000 Service Pack 3, which was introduced in 2002. As a consequence, computers running Windows 2000 Service Pack 3 (or older versions1) ) must be updated. It is recommended that Windows 2000 computers be re-installed with Windows XP Service Pack 2 (see http://cern.ch/Win/Services/Installation/Diane). If this is not possible for compatibility reasons, Windows 2000 Service Pack 4 must be installed to ensure the computers continue to receive security patches (see http://cern.ch/Win/Docs/2000SP4). In the next few days, NICE 2000 computers requiring an update will receive a pop-up window with instructions. Users requiring help with the update can contact Helpdesk@cern.ch or call 78888. If your computer needs to be updated you are recommended to read the additional information available at http://cern.ch/Win/Docs/2000SP3. The NICE Team 1) To determine your Windows service pack version, use the ‘Start' button and select ‘Run'. In the new window that opens, type ‘wi...

  11. The progress in the study of Arctic pack ice ecology

    Institute of Scientific and Technical Information of China (English)

    何剑锋; 王桂忠; 蔡明红; 李少菁

    2004-01-01

    The sea ice community plays an important role in the Arctic marine ecosystem. Because of the predicted environmental changes in the Arctic environment and specifically related to sea ice, the Arctic pack ice biota has received more attention in recent years using modern ice-breaking research vessels. Studies show that the Arctic pack ice contains a diverse biota and besides ice algae, the bacterial and protozoan biomasses can be high. Surprisingly high primary production values were observed in the pack ice of the central Arctic Ocean. Occasionally biomass maximum were discovered in the interior of the ice floes, a habitat that had been ignored in most Arctic studies. Many scientific questions, which deserve special attention, remained unsolved due to logistic limitations and the sea ice characteristics. Little is know about the pack ice community in the central Arctic Ocean. Almost no data exists from the pack ice zone for the winter season. Concerning the abundance of bacteria and protozoa, more studies are needed to understand the microbial network within the ice and its role in material and energy flows. The response of the sea ice biota to global change will impact the entire Arctic marine ecosystem and a long-term monitoring program is needed. The techniques, that are applied to study the sea ice biota and the sea ice ecology, should be improved.

  12. A Geometric-Structure Theory for Maximally Random Jammed Packings

    Science.gov (United States)

    Tian, Jianxiang; Xu, Yaopengxiao; Jiao, Yang; Torquato, Salvatore

    2015-11-01

    Maximally random jammed (MRJ) particle packings can be viewed as prototypical glasses in that they are maximally disordered while simultaneously being mechanically rigid. The prediction of the MRJ packing density ϕMRJ, among other packing properties of frictionless particles, still poses many theoretical challenges, even for congruent spheres or disks. Using the geometric-structure approach, we derive for the first time a highly accurate formula for MRJ densities for a very wide class of two-dimensional frictionless packings, namely, binary convex superdisks, with shapes that continuously interpolate between circles and squares. By incorporating specific attributes of MRJ states and a novel organizing principle, our formula yields predictions of ϕMRJ that are in excellent agreement with corresponding computer-simulation estimates in almost the entire α-x plane with semi-axis ratio α and small-particle relative number concentration x. Importantly, in the monodisperse circle limit, the predicted ϕMRJ = 0.834 agrees very well with the very recently numerically discovered MRJ density of 0.827, which distinguishes it from high-density “random-close packing” polycrystalline states and hence provides a stringent test on the theory. Similarly, for non-circular monodisperse superdisks, we predict MRJ states with densities that are appreciably smaller than is conventionally thought to be achievable by standard packing protocols.

  13. DEM simulation of particle percolation in a packed bed

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The phenomenon of spontaneous particle percolation under gravity is investigated by means of the discrete element method. Percolation behaviors such as percolation velocity,residence time distribution and radial dispersion are examined under various conditions. It is shown that the vertical velocity of a percolating particle moving down through a packing of larger particles decreases with increasing the restitution coefficient between particles and diameter ratio of the percolating to packing particles. With the increase of the restitution coefficient,the residence time and radial dispersion of the percolating particles increase. The packing height affects the residence time and radial dispersion. But,the effect can be eliminated in the analysis of the residence time and radial dispersion when they are normalized by the average residence time and the product of the packing height and packing particle diameter,respectively.In addition,the percolation velocity is shown to be related to the vertical acceleration of the percolating particle when an extra constant vertical force is applied. Increasing the feeding rate of percolating particles decreases the dispersion coefficient.

  14. Bernal's road to random packing and the structure of liquids

    Science.gov (United States)

    Finney, John L.

    2013-11-01

    Until the 1960s, liquids were generally regarded as either dense gases or disordered solids, and theoretical attempts at understanding their structures and properties were largely based on those concepts. Bernal, himself a crystallographer, was unhappy with either approach, preferring to regard simple liquids as 'homogeneous, coherent and essentially irregular assemblages of molecules containing no crystalline regions'. He set about realizing this conceptual model through a detailed examination of the structures and properties of random packings of spheres. In order to test the relevance of the model to real liquids, ways had to be found to realize and characterize random packings. This was at a time when computing was slow and in its infancy, so he and his collaborators set about building models in the laboratory, and examining aspects of their structures in order to characterize them in ways which would enable comparison with the properties of real liquids. Some of the imaginative - often time consuming and frustrating - routes followed are described, as well the comparisons made with the properties of simple liquids. With the increase of the power of computers in the 1960s, computational approaches became increasingly exploited in random packing studies. This enabled the use of packing concepts, and the tools developed to characterize them, in understanding systems as diverse as metallic glasses, crystal-liquid interfaces, protein structures, enzyme-substrate interactions and the distribution of galaxies, as well as their exploitation in, for example, oil extraction, understanding chromatographic separation columns, and packed beds in industrial processes.

  15. Acid monolayer functionalized iron oxide nanoparticle catalysts

    Science.gov (United States)

    Ikenberry, Myles

    Superparamagnetic iron oxide nanoparticle functionalization is an area of intensely active research, with applications across disciplines such as biomedical science and heterogeneous catalysis. This work demonstrates the functionalization of iron oxide nanoparticles with a quasi-monolayer of 11-sulfoundecanoic acid, 10-phosphono-1-decanesulfonic acid, and 11-aminoundecanoic acid. The carboxylic and phosphonic moieties form bonds to the iron oxide particle core, while the sulfonic acid groups face outward where they are available for catalysis. The particles were characterized by thermogravimetric analysis (TGA), transmission electron microscopy (TEM), potentiometric titration, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), inductively coupled plasma optical emission spectrometry (ICP-OES), X-ray photoelectron spectrometry (XPS), and dynamic light scattering (DLS). The sulfonic acid functionalized particles were used to catalyze the hydrolysis of sucrose at 80° and starch at 130°, showing a higher activity per acid site than the traditional solid acid catalyst Amberlyst-15, and comparing well against results reported in the literature for sulfonic acid functionalized mesoporous silicas. In sucrose catalysis reactions, the phosphonic-sulfonic nanoparticles (PSNPs) were seen to be incompletely recovered by an external magnetic field, while the carboxylic-sulfonic nanoparticles (CSNPs) showed a trend of increasing activity over the first four recycle runs. Between the two sulfonic ligands, the phosphonates produced a more tightly packed monolayer, which corresponded to a higher sulfonic acid loading, lower agglomeration, lower recoverability through application of an external magnetic field, and higher activity per acid site for the hydrolysis of starch. Functionalizations with 11-aminoundecanoic acid resulted in some amine groups binding to the surfaces of iron oxide nanoparticles. This amine binding is commonly ignored in iron oxide

  16. Measurement of HETP of SUS Dixon ring and porcelain packing in small-scale water distillation column for H2O-HTO isotope separation

    International Nuclear Information System (INIS)

    Series of water distillations in a total reflux mode have been performed in a 100 cm height column of 1.6 cm I.D. in order to measure values of HETP for various packings, that is, one brass or three SUS Dixon rings and three porcelain packings. The HETP were measured by changing the vapor flow rate within the column. The SUS Dixon ring of 1.5 mm diameter and the porcelain packing of 1.2 mm O.D. had a small HETP (∼5 cm), but could not meet a large vapor flow rate because of a large pressure drop. The SUS Dixon ring of 6.0 mm diameter had a small HETP (∼6 cm) in the vapor flow rate under 2 g/min, but the HETP value increased with increasing the vapor flow rate. The pressure drop for the ring, however, was almost constant in the range of these measurements. (author)

  17. Experiments on the resistance of a large transport vessel navigating in the Arctic region in pack ice conditions

    Science.gov (United States)

    Huang, Yan; Li, Wei; Wang, Yinghui; Wu, Baoshan

    2016-07-01

    In this study, we carried out model tests to investigate the ice failure process and the resistance experienced by a transport vessel navigating in the Arctic region in pack ice conditions. We tested different navigation velocities, ice plate sizes, and ice concentrations. During the tests, we closely observed several phenomena, including the modes of interaction of the ice ship and the moving and failure modes of ice. We also measured the vessel resistances under different conditions. The test results indicate that the navigation velocity is a significant determinant of the moving and failure modes of ice. Moreover, vessel resistance is remarkably dependent on the ice concentration and navigation velocity. The variances of the mean and maximum resistance are also compared and discussed in detail.

  18. Experiments on the Resistance of a Large Transport Vessel Navigating in the Arctic Region in Pack Ice Conditions

    Institute of Scientific and Technical Information of China (English)

    Yan Huang; Wei Li; Yinghui Wang; Baoshan Wu

    2016-01-01

    In this study, we carried out model tests to investigate the ice failure process and the resistance experienced by a transport vessel navigating in the Arctic region in pack ice conditions. We tested different navigation velocities, ice plate sizes, and ice concentrations. During the tests, we closely observed several phenomena, including the modes of interaction of the ice ship and the moving and failure modes of ice. We also measured the vessel resistances under different conditions. The test results indicate that the navigation velocity is a significant determinant of the moving and failure modes of ice. Moreover, vessel resistance is remarkably dependent on the ice concentration and navigation velocity. The variances of the mean and maximum resistance are also compared and discussed in detail.

  19. Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

    Energy Technology Data Exchange (ETDEWEB)

    Amitava Sarkar; James K. Neathery; Burtron H. Davis

    2006-12-31

    A fundamental filtration study was started to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. Slurry-phase FTS in slurry bubble column reactor systems is the preferred mode of operation since the reaction is highly exothermic. Consequently, heavy wax products in one approach may be separated from catalyst particles before being removed from the reactor system. Achieving an efficient wax product separation from iron-based catalysts is one of the most challenging technical problems associated with slurry-phase iron-based FTS and is a key factor for optimizing operating costs. The separation problem is further compounded by attrition of iron catalyst particles and the formation of ultra-fine particles.

  20. Natural manganese oxides as catalysts for oxidative coupling of methane: a structural and degradation study

    Energy Technology Data Exchange (ETDEWEB)

    Ioffe, L.M.; Bosch, P.; Viveros, T.; Sanchez, H.; Borodko, Y.G. [Universidad Autonoma Metropolitana-Iztapalapa, Mexico (Mexico). Dept. of Chem.

    1997-12-01

    Natural manganese oxides were evaluated as oxidative coupling catalysts to convert methane into C{sub 2}-hydrocarbons. Reactions were done in a cyclic redox mode in which the oxidized catalyst was reacted with methane at 850 C in the absence of oxygen. The bulk and surface analyses (XRD, XPS, FT-IR) indicate that the catalyst deactivation in the methane atmosphere is related to reduction of manganese ions, oxygen depletion of the catalyst surface and formation of manganese carbide species. It is proposed that the XPS line of O1s electrons, Eb=528.6 eV should be assigned to the surface oxygen bound to the reduced Mn{sup 2+} cation with close oxygen vacancies, and lines ofMn2p{sub 3/2} electrons, Eb=641 eV and C1s at 282.5 eV may be assigned to the surface manganese carbide. (orig.) 27 refs.

  1. CFD study of pressure drop and flow through corrugated structured packing to be used for tritium extraction in TBM

    International Nuclear Information System (INIS)

    In this paper we have presented the flow profiles of the gas in the packing and the dry pressure drop respectively using commercial Computational Fluid Dynamics (CFD) software. Due to the complexity of the geometry of the packing and intense requirement of the CPU time, calculations have been carried out for estimation of pressure drop and flow pattern for only gas flow though both gauze type and sheet type corrugated packing with different combinations of packing elements as: a) 2 sheet model for corrugated sheet packing, b) 2 sheet model for corrugated gauze packing, c) Packing element model for corrugated sheet packing, d) Packing element model for corrugated gauze packing

  2. Packing entropy of extended, hard, rigid objects on a lattice

    Science.gov (United States)

    Li, Wenshuo; Freed, Karl F.; Nemirovsky, Adolfo M.

    1993-06-01

    We present a systematic method of evaluating the packing entropy for a set of mutually avoiding extended, hard, rigid objects on a lattice. The method generalizes a simple algebraic representation of the lattice cluster theory developed by Freed and co-workers for systems composed of flexible objects. The theory provides a power series expansion in z-1 for the corrections to the zeroth order mean field approximation partition function, where z is the lattice coordination number. We illustrate the general theory by calculating the packing entropy of four-unit rigid ``square'' objects on a hypercubic lattice as a function of the volume fraction of the squares. As a particular limiting case, we also evaluate for the packing entropy of two, three, and four squares on a two-dimensional square lattice and find agreement with the cluster expansion.

  3. Formation and displacement of bubbles in a packed bed

    CERN Document Server

    Soto, Enrique; Zenit, Roberto

    2010-01-01

    The fluid dynamics video show a gas stream which is injected into a packed bed immersed in water and fluid dynamcis video present the dynamics involved. The refractive index of the water an the packed bed are quite similar and the edges of the spherical particles can be seen. Two distinctive regimens can be observed. The first one, for low air flow rates, which is characterized by the percolation of the air thought the interstitial space among particles. And the second one, for high air flow rates, which is characterized by the accumulation of air inside the packed bed without percolation, it can be observed that the bubble pull apart the particles apart. Furthermore, for the first case the position of the particles remains constant while for the second one a circulation of particles is induced by the bubbles flow.

  4. Emergence of Gamma distributions in granular materials and packing models

    Science.gov (United States)

    Aste, T.; di Matteo, T.

    2008-02-01

    We study the distribution of volume fluctuations in experiments and numerical simulations concerning equal-sized sphere packings prepared with different techniques. We show that the distribution of the local volumes (Voronoï cells) and also the distributions of the global volumes (whole samples) follow remarkably well a shifted and rescaled Gamma distribution that we name a k-Gamma distribution. Such agreement is robust over a broad range of packing fractions and it is observed for several distinct systems. This distribution is characterized by the average packing fraction and a shape parameter “ k ” which is very sensitive to changes in the structural organization. A statistical mechanics approach predicts such k-Gamma distribution at statistical equilibrium and it links the parameter k with the number of elementary cells which are exchanging volume during the system preparation. The thermodynamical equivalent of k and its relation with the “granular temperature” are also discussed.

  5. Bin Completion Algorithms for Multicontainer Packing, Knapsack, and Covering Problems

    CERN Document Server

    Fukunaga, A S; 10.1613/jair.2106

    2011-01-01

    Many combinatorial optimization problems such as the bin packing and multiple knapsack problems involve assigning a set of discrete objects to multiple containers. These problems can be used to model task and resource allocation problems in multi-agent systems and distributed systms, and can also be found as subproblems of scheduling problems. We propose bin completion, a branch-and-bound strategy for one-dimensional, multicontainer packing problems. Bin completion combines a bin-oriented search space with a powerful dominance criterion that enables us to prune much of the space. The performance of the basic bin completion framework can be enhanced by using a number of extensions, including nogood-based pruning techniques that allow further exploitation of the dominance criterion. Bin completion is applied to four problems: multiple knapsack, bin covering, min-cost covering, and bin packing. We show that our bin completion algorithms yield new, state-of-the-art results for the multiple knapsack, bin covering,...

  6. FY-87 packing fabrication techniques (commercial waste form) results

    International Nuclear Information System (INIS)

    This report covers the investigation of fabrication techniques associated with the development of suitable materials and methods to provide a prefabricated packing for waste packages for the Basalt Waste Isolation Project (BWIP). The principal functions of the packing are to minimize container corrosion during the 300 to 1000 years following repository closure and provide long-term control of the release of radionuclides from the waste package. The investigative work, discussed in this report, was specifically conceived to develop the design criteria for production of full-scale prototypical packing rings. The investigative work included the preparation of procedures, the preparation of fabrication materials, physical properties, and the determination of the engineering properties. The principal activities were the preparation of the materials and the determination of the physical properties. 21 refs., 20 figs., 14 tabs

  7. A Personified Annealing Algorithm for Circles Packing Problem

    Institute of Scientific and Technical Information of China (English)

    ZHANGDe-Fu; LIXin

    2005-01-01

    Circles packing problem is an NP-hard problem and is difficult to solve. In this paper, a hybrid search strategy for circles packing problem is discussed. A way of generating new configuration is presented by simulating the moving of elastic objects, which can avoid the blindness of simulated annealing search and make iteration process converge fast. Inspired by the life experiences of people,an effective personified strategy to jump out of local minima is given. Based on the simulated annealing idea and personification strategy, an effective personified annealing algorithm for circles packing problem is developed. Numerical experiments on benchmark problem instances show that the proposed algorithm outperforms the best algorithm in the literature.

  8. Lightweight, Flexible, Thin, Integrated Solar-Power Packs

    Science.gov (United States)

    Hanson, Robert R.

    2004-01-01

    Lightweight, flexible, thin, one-piece, solar-power packs are undergoing development. Each power pack of this type is a complete, modular, integrated power-supply system comprising three power subsystems that, in conventional practice, have been constructed as separate units and connected to each other by wires. These power packs are amenable to a variety of uses: For example, they could be laminated to the tops of tents and other shelters to provide or augment power for portable electronic equipment in the field, and they could be used as power sources for such small portable electronic systems as radio transceivers (including data relays and cellular telephones), laptop computers, video camcorders, and Global Positioning System receivers.

  9. A Heuristic Algorithm for Solving Triangle Packing Problem

    Directory of Open Access Journals (Sweden)

    Ruimin Wang

    2013-01-01

    Full Text Available The research on the triangle packing problem has important theoretic significance, which has broad application prospects in material processing, network resource optimization, and so forth. Generally speaking, the orientation of the triangle should be limited in advance, since the triangle packing problem is NP-hard and has continuous properties. For example, the polygon is not allowed to rotate; then, the approximate solution can be obtained by optimization method. This paper studies the triangle packing problem by a new kind of method. Such concepts as angle region, corner-occupying action, corner-occupying strategy, and edge-conjoining strategy are presented in this paper. In addition, an edge-conjoining and corner-occupying algorithm is designed, which is to obtain an approximate solution. It is demonstrated that the proposed algorithm is highly efficient, and by the time complexity analysis and the analogue experiment result is found.

  10. Laser-Induced Fluorescence Detection in High-Throughput Screening of Heterogeneous Catalysts and Single Cells Analysis

    International Nuclear Information System (INIS)

    Laser-induced fluorescence detection is one of the most sensitive detection techniques and it has found enormous applications in various areas. The purpose of this research was to develop detection approaches based on laser-induced fluorescence detection in two different areas, heterogeneous catalysts screening and single cell study. First, we introduced laser-induced imaging (LIFI) as a high-throughput screening technique for heterogeneous catalysts to explore the use of this high-throughput screening technique in discovery and study of various heterogeneous catalyst systems. This scheme is based on the fact that the creation or the destruction of chemical bonds alters the fluorescence properties of suitably designed molecules. By irradiating the region immediately above the catalytic surface with a laser, the fluorescence intensity of a selected product or reactant can be imaged by a charge-coupled device (CCD) camera to follow the catalytic activity as a function of time and space. By screening the catalytic activity of vanadium pentoxide catalysts in oxidation of naphthalene, we demonstrated LIFI has good detection performance and the spatial and temporal resolution needed for high-throughput screening of heterogeneous catalysts. The sample packing density can reach up to 250 x 250 subunits/cm(sub 2) for 40-(micro)m wells. This experimental set-up also can screen solid catalysts via near infrared thermography detection

  11. Laser-Induced Fluorescence Detection in High-Throughput Screening of Heterogeneous Catalysts and Single Cells Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Hui Su

    2001-05-01

    Laser-induced fluorescence detection is one of the most sensitive detection techniques and it has found enormous applications in various areas. The purpose of this research was to develop detection approaches based on laser-induced fluorescence detection in two different areas, heterogeneous catalysts screening and single cell study. First, we introduced laser-induced imaging (LIFI) as a high-throughput screening technique for heterogeneous catalysts to explore the use of this high-throughput screening technique in discovery and study of various heterogeneous catalyst systems. This scheme is based on the fact that the creation or the destruction of chemical bonds alters the fluorescence properties of suitably designed molecules. By irradiating the region immediately above the catalytic surface with a laser, the fluorescence intensity of a selected product or reactant can be imaged by a charge-coupled device (CCD) camera to follow the catalytic activity as a function of time and space. By screening the catalytic activity of vanadium pentoxide catalysts in oxidation of naphthalene, we demonstrated LIFI has good detection performance and the spatial and temporal resolution needed for high-throughput screening of heterogeneous catalysts. The sample packing density can reach up to 250 x 250 subunits/cm{sub 2} for 40-{micro}m wells. This experimental set-up also can screen solid catalysts via near infrared thermography detection.

  12. Influence of Catalyst Type and Regeneration on Upgrading of Crude Bio-oil through Catalytical Thermal Cracking

    Institute of Scientific and Technical Information of China (English)

    郭晓亚; 颜涌捷; 李庭琛

    2004-01-01

    Catalysts, such as HZSM-5(Si/Al=50), HZSM-5(25), zeolite 5A, CaHZSM-5(50), ZnHZSM-5(50), and Kaolin were used in upgrading of crude biomass oil from pyrolysis in a fixed-bed reactor under atmospheric pressure, in order to investigate the effects of catalyst type on the yield of desired product. A blank test was carried out in a bed of inert packings to determine the extent of non-catalytical thermal cracking. The gas produced in the reaction was analyzed by the chemical absorption method. Among those catalysts, HZSM-5(50) gave the highest yield of the desired organic distillate while Kaolin gave the least formation of coke. Regeneration of deactivated HZSM-5(50) was studied. In terms of yield of organic distillate and formation rate of coke, the catalytic activity did not change much during the first 3 times of regeneration.

  13. A Quantitative Study on Packing Density and Pozzolanic Activity of Cementitious Materials Based on the Compaction Packing Model

    Science.gov (United States)

    Gong, Jianqing; Chou, Kai; Huang, Zheng Yu; Zhao, Minghua

    2014-08-01

    A brief introduction to the theoretical basis of compaction packing model (CPM) and an over-view of the principle of the specific strength method provided the starting point of this study. Then, research on quantitative relations was carried out to find the correlation between the contribution rate of the pozzolanic activity and the contribution value of packing density when CPM was applied to fine powder mixture systems. The concept of the contribution value of the packing density being in direct correspondence with the contribution rate was proved by the compressive strength results and SEM images. The results indicated that the variation rule of the contribution rate of the pozzolanic activity is similar to that of the contribution value of packing density as calculated by CPM. This means the contribution value of the packing density could approximately simulate the change tendency of the contribution rate of the pozzolanic activity, which is of significant value for the future of mix designs for high and ultra-high performance concrete.

  14. A model for evaluating the ballistic resistance of stratified packs

    Science.gov (United States)

    Pirvu, C.; Georgescu, C.; Badea, S.; Deleanu, L.

    2016-08-01

    Models for evaluating the ballistic performance of stratified packs are useful in reducing the time for laboratory tests, understanding the failure process and identifying key factors to improve the architecture of the packs. The authors present the results of simulating the bullet impact on a packs made of 24 layers, taking into consideration the friction between layers (μ = 0.4) and the friction between bullet and layers (μ = 0.3). The aim of this study is to obtain a number of layers that allows for the bullet arrest in the packs and to have several layers undamaged in order to offer a high level of safety for this kind of packs that could be included in individual armors. The model takes into account the yield and fracture limits of the two materials the bullet is made of and those for one layer, here considered as an orthotropic material, having maximum equivalent plastic strain of 0.06. All materials are considered to have bilinear isotropic hardening behavior. After documentation, the model was designed as isothermal because thermal influence of the impact is considered low for these impact velocities. The model was developed with the help of Ansys 14.5. Each layer has 200 mm × 200 × 0.35 mm. The bullet velocity just before impact was 400 m/s, a velocity characterizing the average values obtained in close range with a ballistic barrel and the bullet model is following the shape and dimensions of the 9 mm FMJ (full metal jacket). The model and the results concerning the number of broken layers were validated by experiments, as the number of broken layers for the actual pack (made of 24 layers of LFT SB1) were also seven...eight. The models for ballistic impact are useful when they are particularly formulated for resembling to the actual system projectile - target.

  15. Preparation and study of IrO2/SiC–Si supported anode catalyst for high temperature PEM steam electrolysers

    DEFF Research Database (Denmark)

    Nikiforov, Aleksey; Tomás García, Antonio Luis; Petrushina, Irina;

    2011-01-01

    A novel catalyst material for oxygen evolution electrodes was prepared and characterised by different techniques. IrO2 supported on a SiC–Si composite was synthesised by the Adams fusion method. XRD and nitrogen adsorption experiments showed an influence of the support on the surface properties o....... Powder conductivity measurements were also performed, which showed the influence of the support particles in the packing of IrO2 particles, perhaps favouring the formation of channels and pores between particles, thus increasing the catalyst utilisation....... of the IrO2 particles, affecting the IrO2 particle size. The prepared catalysts were electrochemically characterised by cyclic voltammetry experiments at 25,80,120 and 150 °C. In accordance with the observed variation in particle size, a support loading of up to 20% improved the activity of the catalyst...

  16. [Removal of Mixed Waste Gases by a Biotrickling Filter Packed with a Novel Combined Packing Material].

    Science.gov (United States)

    Mei, Yu; Cheng, Zhuo-wei; Wang, Jia-de; Lu, Yin

    2015-12-01

    A pilot biotrickling filter (BTF) was set up for removal of a mixed waste gas containing toluene and ethanol. The packing material was composed of polyhedral sphere and polyhedral hollow column previously designed by our group. The results showed this BTF could successfully start up within only 8 d and the average eliminate capacities for toluene and ethanol were 97.14 and 113.10 g · (m³ · h)⁻¹, respectively. Empty bed residence time (EBRT) and the inlet concentration had effects on the removal of toluene. The maximum elimination capacity of toluene and ethanol was 123.34 and 206.36 g (m³ · h)⁻¹ under EBRT of 21.11 s, respectively. However, the effect of spray liquid density was not obvious, and the optimal value of solution and gas ratio was 6.82 L · m⁻³. The influence of unstable processing condition on its performance was also investigated. NaOH solution could effectively reduce the plugging of the filler layer, and the removal capability of pollutant could be recovered within 3 days. After the running was stopped for 10 d, the removal performance of this BTF could be quickly recovered. PMID:27011972

  17. Excluded volumes of clusters in tetrahedral particle packing

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Lufeng; Lu, Peng; Meng, Lingyi; Jin, Weiwei; Li, Shuixiang, E-mail: lsx@pku.edu.cn

    2014-02-01

    We investigate the excluded volumes of clusters in tetrahedral particle packing using an ideal tetrahedron model and Monte Carlo simulation. Both the influences of the size and topology of clusters on the excluded volume are studied. We find that the excluded volumes of the dimer composed of two tetrahedra and the wagon wheel composed of five tetrahedra are relatively lower than other cluster forms. For large clusters, the excluded volume decreases when the topology of a cluster approaches the wagon-wheel geometry. The results give an explanation to the cluster distribution which demonstrates that the dimer and wagon wheel are the dominative cluster forms in the packing structure of tetrahedra.

  18. Regeneration of Hydrotreating and FCC Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    CM Wai; JG Frye; JL Fulton; LE Bowman; LJ Silva; MA Gerber

    1999-09-30

    Hydrotreating, hydrocracking, and fluid catalytic cracking (FCC) catalysts are important components of petroleum refining processes. Hydrotreating and hydrocracking catalysts are used to improve the yield of high-quality light oil fractions from heavier crude oil and petroleum feedstocks containing high levels of impurities. FCC catalysts improve the yield of higher octane gasoline from crude oil. Residuum hydrotreating and cracking catalysts are susceptible to irreversible deactivation caused by adsorption of sulfur and by metals impurities, such as vanadium and nickel. The gradual buildup of these impurities in a hydrotreating catalyst eventually plugs the pores and deactivates it. Nickel and vanadium adversely affect the behavior of cracking catalysts, reducing product yield and quality. Replacing deactivated catalysts represents a significant cost in petroleum refining. Equally important are the costs and potential liabilities associated with treating and disposing spent catalysts. For example, recent US Environmental Protection Agency rulings have listed spent hydrotreating and hydrorefining catalysts as hazardous wastes. FCC catalysts, though more easily disposed of as road-base or as filler in asphalt and cement, are still an economic concern mainly because of the large volumes of spent catalysts generated. New processes are being considered to increase the useful life of catalysts or for meeting more stringent disposal requirements for spent catalysts containing metals. This report discusses a collaborative effort between Pacific Northwest National Laboratory (PNNL) and Phillips Petroleum, Inc., to identify promising chemical processes for removing metals adhered to spent hydrodesulfurization (HDS, a type of hydrotreating catalyst) and FCC catalysts. This study, conducted by PNNL, was funded by the US Department of Energy's Bartlesville Project Office. Fresh and spent catalysts were provided by Phillips Petroleum. The FCC catalyst was a rare

  19. Design of Engine-Generator Work Mode for Hybrid Electric Vehicle

    Institute of Scientific and Technical Information of China (English)

    何洪文; 余晓江; 孙逢春

    2004-01-01

    From electric circuit theory view, a system model of series hybrid electric vehicle was built which uses engine-generator and battery pack as its on-board energy source in this paper. Based on the analysis for the constant power work mode and constant bus voltage work mode of engine-generator, a third work mode was put forward which combined the advantages of constant power and constant bus voltage work modes. The new work mode is reasonable to keep the battery in good working conditions and to extend its life. Also the working conditions of engine can be bettered to get low pollution and high efficiency.

  20. Rolling-induced Face Centered Cubic Titanium in Hexagonal Close Packed Titanium at Room Temperature

    Science.gov (United States)

    Wu, H. C.; Kumar, A.; Wang, J.; Bi, X. F.; Tomé, C. N.; Zhang, Z.; Mao, S. X.

    2016-04-01

    Combining transmission electron microscopes and density functional theory calculations, we report the nucleation and growth mechanisms of room temperature rolling induced face-centered cubic titanium (fcc-Ti) in polycrystalline hexagonal close packed titanium (hcp-Ti). Fcc-Ti and hcp-Ti take the orientation relation: hcp||fcc and , different from the conventional one. The nucleation of fcc-Ti is accomplished via pure-shuffle mechanism with a minimum stable thickness of three atomic layers, and the growth via shear-shuffle mechanisms through gliding two-layer disconnections or pure-shuffle mechanisms through gliding four-layer disconnections. Such phase transformation offers an additional plastic deformation mode comparable to twinning.

  1. Catalyst containing oxygen transport membrane

    Science.gov (United States)

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  2. Catalytic flash pyrolysis of oil-impregnated-wood and jatropha cake using sodium based catalysts

    NARCIS (Netherlands)

    Ali Imran, A.; Bramer, E.A.; Seshan, K.; Brem, G.

    2016-01-01

    Catalytic pyrolysis of wood with impregnated vegetable oil was investigated and compared with catalytic pyrolysis of jatropha cake making use of sodium based catalysts to produce a high quality bio-oil. The catalytic pyrolysis was carried out in two modes: in-situ catalytic pyrolysis and post treatm

  3. Catalyst Degradation in High Temperature Proton Exchange Membrane Fuel Cells Based on Acid Doped Polybenzimidazole Membranes

    DEFF Research Database (Denmark)

    Cleemann, Lars Nilausen; Buazar, F.; Li, Qingfeng;

    2013-01-01

    Degradation of carbon supported platinum catalysts is a major failure mode for the long term durability of high temperature proton exchange membrane fuel cells based on phosphoric acid doped polybenzimidazole membranes. With Vulcan carbon black as a reference, thermally treated carbon black...

  4. Recovery of Dilute Acetic Acid by Catalytic Distillation Using NKC-9 as Catalyst

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zhigang; LI Xiaofeng; XU Shimin; LI Xingang

    2006-01-01

    The reaction kinetics of dilute acetic acid with methanol using NKC-9 as catalyst was studied at temperatures of 308 K, 318 K, 323 K, 328 K. The kinetic model based on Langmuir-Hinshelwood rate model was derived and the activation energy was 6.13 x 104 kJ/kmol. The experiment of recovery of dilute acetic acid was conducted in a packed bed catalytic distillation column. The optimal process parameters and operational conditions determined to make up to 85.9% conversion of acetic acid are as follows:the height of catalyst bed is 1 100 mm, reflux ratio is 4: 1, and the ratio of methanol to acetic acid is 2: 1. The method can be used as a guide in industrial scale recovery of 15%-30% dilute acetic acid.

  5. New Construction and Catalyst Support Materials for Water Electrolysis at Elevated Temperatures

    DEFF Research Database (Denmark)

    Nikiforov, Aleksey

    showed the in uence of the support on the packing of IrO2 particles. Investigation showed that even a support material with poor electrical conductivity contributes beneficially to the electrocatalyst active surface area, increasing its utilization. Results demonstrated potential perspectives of using...... in Chapter 5. The active iridium oxide was deposited on the SiC-Si in-situ by the Adams fusion synthesis and characterized by different techniques. XRD and nitrogen adsorption experiments showed an influence of the support on surface properties of the IrO2 particles, affecting IrO2 particle size....... The prepared catalysts were electrochemically characterized by cyclic voltammetry experiments at 25, 80, 120 and 150 °C. In accordance with the observed variation in particle size, a support loading of up to 80% improved the activity of the catalyst. Powder conductivity measurements were also performed, which...

  6. Production and optimization of biodiesel using mixed immobilized biocatalysts in packed bed reactor.

    Science.gov (United States)

    Bakkiyaraj, S; Syed, Mahin Basha; Devanesan, M G; Thangavelu, Viruthagiri

    2016-05-01

    Vegetable oils are used as raw materials for biodiesel production using transesterification reaction. Several methods for the production of biodiesel were developed using chemical (alkali and acidic compounds) and biological catalysts (lipases). Biodiesel production catalyzed by lipases is energy and cost-saving processes and is carried out at normal temperature and pressure. The need for an efficient method for screening larger number of variables has led to the adoption of statistical experimental design. In the present study, packed bed reactor was designed to study with mixed immobilized biocatalysts to have higher productivity under optimum conditions. Contrary to the single-step acyl migration mechanism, a two-step stepwise reaction mechanism involving immobilized Candida rugosa lipase and immobilized Rhizopus oryzae cells was employed for the present work. This method was chosen because enzymatic hydrolysis followed by esterification can tolerate high free fatty acid containing oils. The effects of flow rate and bed height on biodiesel yield were studied using two factors five-level central composite design (CCD) and response surface methodology (RSM). Maximum biodiesel yield of 85 and 81 % was obtained for jatropha oil and karanja oil with the optimum bed height and optimum flow rate of 32.6 cm and 1.35 L/h, and 32.6 cm and 1.36 L/h, respectively. PMID:25940482

  7. Novel Fischer-Tropsch catalysts. [DOE patent

    Science.gov (United States)

    Vollhardt, K.P.C.; Perkins, P.

    Novel compounds are described which are used as improved Fischer-Tropsch catalysts particularly for the conversion of CO + H/sub 2/ to gaseous and liquid hydrocarbons at milder conditions than with prior catalysts.

  8. Catalyst for Decomposition of Nitrogen Oxides

    Science.gov (United States)

    Schryer, David R. (Inventor); Jordan, Jeffrey D. (Inventor); Akyurtlu, Ates (Inventor); Akyurtlu, Jale (Inventor)

    2015-01-01

    This invention relates generally to a platinized tin oxide-based catalyst. It relates particularly to an improved platinized tin oxide-based catalyst able to decompose nitric oxide to nitrogen and oxygen without the necessity of a reducing gas.

  9. Rhenium Nanochemistry for Catalyst Preparation

    Directory of Open Access Journals (Sweden)

    Vadim G. Kessler

    2012-08-01

    Full Text Available The review presents synthetic approaches to modern rhenium-based catalysts. Creation of an active center is considered as a process of obtaining a nanoparticle or a molecule, immobilized within a matrix of the substrate. Selective chemical routes to preparation of particles of rhenium alloys, rhenium oxides and the molecules of alkyltrioxorhenium, and their insertion into porous structure of zeolites, ordered mesoporous MCM matrices, anodic mesoporous alumina, and porous transition metal oxides are considered. Structure-property relationships are traced for these catalysts in relation to such processes as alkylation and isomerization, olefin metathesis, selective oxidation of olefins, methanol to formaldehyde conversion, etc.

  10. Biomass processing over gold catalysts

    CERN Document Server

    Simakova, Olga A; Murzin, Dmitry Yu

    2013-01-01

    The book describes the valorization of biomass-derived compounds over gold catalysts. Since biomass is a rich renewable feedstock for diverse platform molecules, including those currently derived from petroleum, the interest in various transformation routes has become intense. Catalytic conversion of biomass is one of the main approaches to improving the economic viability of biorefineries.  In addition, Gold catalysts were found to have outstanding activity and selectivity in many key reactions. This book collects information about transformations of the most promising and important compounds

  11. Quick Guide to Flash Catalyst

    CERN Document Server

    Elmansy, Rafiq

    2011-01-01

    How do you transform user interface designs created in Photoshop or Illustrator into interactive web pages? It's easier than you think. This guide shows you how to use Adobe Flash Catalyst to create interactive UIs and website wireframes for Rich Internet Applications-without writing a single line of code. Ideal for web designers, this book introduces Flash Catalyst basics with detailed step-by-step instructions and screenshots that illustrate every part of the process. You'll learn hands-on how to turn your static design or artwork into working user interfaces that can be implemented in Fla

  12. Continuous Production of Lipase-Catalyzed Biodiesel in a Packed-Bed Reactor: Optimization and Enzyme Reuse Study

    Directory of Open Access Journals (Sweden)

    Hsiao-Ching Chen

    2011-01-01

    Full Text Available An optimal continuous production of biodiesel by methanolysis of soybean oil in a packed-bed reactor was developed using immobilized lipase (Novozym 435 as a catalyst in a tert-butanol solvent system. Response surface methodology (RSM and Box-Behnken design were employed to evaluate the effects of reaction temperature, flow rate, and substrate molar ratio on the molar conversion of biodiesel. The results showed that flow rate and temperature have significant effects on the percentage of molar conversion. On the basis of ridge max analysis, the optimum conditions were as follows: flow rate 0.1 mL/min, temperature 52.1∘C, and substrate molar ratio 1 : 4. The predicted and experimental values of molar conversion were 83.31±2.07% and 82.81±.98%, respectively. Furthermore, the continuous process over 30 days showed no appreciable decrease in the molar conversion. The paper demonstrates the applicability of using immobilized lipase and a packed-bed reactor for continuous biodiesel synthesis.

  13. Impact of conduit geometry on the performance of typical particulate microchip packings.

    Science.gov (United States)

    Jung, Stephanie; Höltzel, Alexandra; Ehlert, Steffen; Mora, Jose-Angel; Kraiczek, Karsten; Dittmann, Monika; Rozing, Gerard P; Tallarek, Ulrich

    2009-12-15

    This work investigates the impact of conduit geometry on the chromatographic performance of typical particulate microchip packings. For this purpose, high-performance liquid chromatography (HPLC)/UV-microchips with separation channels of quadratic, trapezoidal, or Gaussian cross section were fabricated by direct laser ablation and lamination of multiple polyimide layers and then slurry-packed with either 3 or 5 microm spherical porous C8-silica particles under optimized packing conditions. Experimentally determined plate height curves for the empty microchannels are compared with dispersion coefficients from theoretical calculations. Packing densities and plate height curves for the various microchip packings are presented and conclusively explained. The 3 microm packings display a high packing density irrespective of their conduit geometries, and their performance reflects the dispersion behavior of the empty channels. Dispersion in 5 microm packings correlates with the achieved packing densities, which are limited by the number and accessibility of corners in a given conduit shape. PMID:19916548

  14. EFFECTS OF CATALYST MORPHOLOGY ON HYDROTREATING REACTIONS

    OpenAIRE

    TYE CHING THIAN

    2008-01-01

    Due to the new environmental regulations for fuel quality, refineries need to process cleaner fuel. This requires an improvement in performance of hydrotreating catalysts. Improvements in catalyst activity require knowledge of the relationships between catalyst morphology and activity. Molybdenum sulfide, the generally agreed catalysts that give the best performance in hydrocracking and hydrotreating was investigated for its morphology effects on hydrotreating reactions. Three types of MoS2 c...

  15. Colloidal nanoparticles as catalysts and catalyst precursors for nitrite hydrogenation

    NARCIS (Netherlands)

    Zhao, Yingnan

    2015-01-01

    The most distinguished advantage to use colloidal methods for catalyst preparation is that the size and the shape of nanoparticles can be manipulated easily under good control, which is normally difficult to achieve by using traditional methods, such as impregnation and precipitation. This facilitat

  16. Berreman mode and epsilon near zero mode.

    Science.gov (United States)

    Vassant, Simon; Hugonin, Jean-Paul; Marquier, Francois; Greffet, Jean-Jacques

    2012-10-01

    In this paper, we discuss the existence of an electromagnetic mode propagating in a thin dielectric film deposited on a metallic film at the particular frequency such that the dielectric permittivity vanishes. We discuss the remarkable properties of this mode in terms of extreme subwavelength mode confinment and its potential applications. We also discuss the link between this mode, the IR absorption peak on a thin dielectric film known as Berreman effect and the surface phonon polariton mode at the air/dielectric interface. Finally, we establish a connection with the polarization shift occuring in quantum wells. PMID:23188363

  17. Packing of protein structures in clusters with magic numbers

    DEFF Research Database (Denmark)

    Lindgård, Per-Anker; Bohr, Henrik

    1997-01-01

    Recently we have proposed a model for folding proteins into packed `clusters'. We have constructed a local homology measure for protein fold classes by projecting consecutively secondary structures onto a lattice. Taking into account hydrophobic forces we have found a mechanism for formation of...... abundances. In this paper we demonstrate that the results are robust to variations in the coordination number of the model....

  18. Shelf-life extension of packed meat by irradiation

    International Nuclear Information System (INIS)

    The shelf-life extension of sliced pork under modified atmosphere (vacuum-, CO2-, CO2-N2-packaging), at different storage temperature (3-5 and 8-10 deg. C) and irradiation doses (1, 2, 4 kGy) was studied. Pork meat vacuum-packed and irradiated at 2 kGy had a shelf-life of between 28-35 days at 3-5 deg. C temperature, the actual extension depending on the initial contamination. The pathogenic microorganisms were eliminated by irradiation. The microbiological quality of gas-packed and irradiated (stored at 3-5 deg. C) meat was in the first two weeks better, than that of the vacuum-packed sampled, but on the 20th day the results were better for vacuum-packed meat. Therefore, from technological and economical point of view, gas-packaging-systems are not recommended. The colour changes (pink) in the irradiated pork did not influence its quality. (author). 16 refs, 9 figs

  19. Packed Bed Reactor Technology for Chemical-Looping Combustion

    NARCIS (Netherlands)

    Noorman, Sander; Sint Annaland, van Martin; Kuipers, Hans

    2007-01-01

    Chemical-looping combustion (CLC) has emerged as an alternative for conventional power production processes to intrinsically integrate power production and CO2 capture. In this work a new reactor concept for CLC is proposed, based on dynamically operated packed bed reactors. With analytical expressi

  20. A heuristic method for solving triangle packing problem

    Institute of Scientific and Technical Information of China (English)

    CHEN Chuan-bo; HE Da-hua

    2005-01-01

    Given a set of triangles and a rectangle container, the triangle packing problem is to determine ifthese triangles can be placed into the container without overlapping. Triangle packing problem is a special case of polygon packing problem and also NP-hard, so it is unlikely that an efficient and exact algorithm can be developed to solve this problem. In this paper, a new concept of rigid placement is proposed, based on which a discrete solution space called rigid solution space is constructed. Each solution in the rigid solution space can be built by continuously applying legal rigid placements one by one until all the triangles are placed into the rectangle container without overlapping. The proposed Least-Destruction-First (LDF) strategy determines which rigid placement has the privilege to go into the rectangle container. Based on this, a heuristic algorithm is proposed to solve the problem.Combining Least-Destruction-First strategy with backtracking, the corresponding backtracking algorithm is proposed. Computational results show that our proposed algorithms are efficient and robust. With slight modification, these techniques can be conveniently used for solving polygon packing problem.

  1. Packed bed heat storage: Continuum mechanics model and validation

    Science.gov (United States)

    Knödler, Philipp; Dreißigacker, Volker; Zunft, Stefan

    2016-05-01

    Thermal energy storage (TES) systems are key elements for various types of new power plant concepts. As possible cost-effective storage inventory option, packed beds of miscellaneous material come into consideration. However, high technical risks arise due to thermal expansion and shrinking of the packed bed's particles during cyclic thermal operation, possibly leading to material failure. Therefore, suitable tools for designing the heat storage system are mandatory. While particle discrete models offer detailed simulation results, the computing time for large scale applications is inefficient. In contrast, continuous models offer time-efficient simulation results but are in need of effective packed bed parameters. This work focuses on providing insight into some basic methods and tools on how to obtain such parameters and on how they are implemented into a continuum model. In this context, a particle discrete model as well as a test rig for carrying out uniaxial compression tests (UCT) is introduced. Performing of experimental validation tests indicate good agreement with simulated UCT results. In this process, effective parameters required for a continuous packed bed model were identified and used for continuum simulation. This approach is validated by comparing the simulated results with experimental data from another test rig. The presented method significantly simplifies subsequent design studies.

  2. Consumer preferences for front-of-pack calories labelling

    NARCIS (Netherlands)

    Kleef, van E.; Trijp, van J.C.M.; Paeps, F.; Fernández-Celemín, L.

    2008-01-01

    Objective In light of the emerging obesity pandemic, front-of-pack calories labels may be an important tool to assist consumers in making informed healthier food choices. However, there is little prior research to guide key decisions on whether caloric content should be expressed in absolute terms o

  3. Optimizing packing fraction in granular media composed of overlapping spheres.

    Science.gov (United States)

    Roth, Leah K; Jaeger, Heinrich M

    2016-01-28

    What particle shape will generate the highest packing fraction when randomly poured into a container? In order to explore and navigate the enormous search space efficiently, we pair molecular dynamics simulations with artificial evolution. Arbitrary particle shape is represented by a set of overlapping spheres of varying diameter, enabling us to approximate smooth surfaces with a resolution proportional to the number of spheres included. We discover a family of planar triangular particles, whose packing fraction of ϕ ∼ 0.73 is among the highest experimental results for disordered packings of frictionless particles. We investigate how ϕ depends on the arrangement of spheres comprising an individual particle and on the smoothness of the surface. We validate the simulations with experiments using 3D-printed copies of the simplest member of the family, a planar particle consisting of three overlapping spheres with identical radius. Direct experimental comparison with 3D-printed aspherical ellipsoids demonstrates that the triangular particles pack exceedingly well not only in the limit of large system size but also when confined to small containers. PMID:26592541

  4. Optimizing packing fraction in granular media composed of overlapping spheres.

    Science.gov (United States)

    Roth, Leah K; Jaeger, Heinrich M

    2016-01-28

    What particle shape will generate the highest packing fraction when randomly poured into a container? In order to explore and navigate the enormous search space efficiently, we pair molecular dynamics simulations with artificial evolution. Arbitrary particle shape is represented by a set of overlapping spheres of varying diameter, enabling us to approximate smooth surfaces with a resolution proportional to the number of spheres included. We discover a family of planar triangular particles, whose packing fraction of ϕ ∼ 0.73 is among the highest experimental results for disordered packings of frictionless particles. We investigate how ϕ depends on the arrangement of spheres comprising an individual particle and on the smoothness of the surface. We validate the simulations with experiments using 3D-printed copies of the simplest member of the family, a planar particle consisting of three overlapping spheres with identical radius. Direct experimental comparison with 3D-printed aspherical ellipsoids demonstrates that the triangular particles pack exceedingly well not only in the limit of large system size but also when confined to small containers.

  5. The use of particle packing models to design ecological concrete

    NARCIS (Netherlands)

    Fennis, S.A.A.M.; Walraven, J.C.; Den Uijl, J.A.

    2009-01-01

    Ecological concrete can be designed by replacing cement with fillers. With low amounts of cement it becomes increasingly important to control the water demand of concrete mixtures. In this paper a cyclic design method based on particle packing is presented and evaluated on the basis of experiments o

  6. Designing Drill-in Fluids by Using Ideal Packing Technique

    Institute of Scientific and Technical Information of China (English)

    Feng Wenqiang; Yan Jienian

    2007-01-01

    Selecting bridging agents properly is a critical factor in designing non-damaging or low-damaging drill-in fluids.Historically,Abrams' rule has been used for this purpose.However,Abrams' rule only addresses the size of particle required to initiate a bridge.The rule does not give an optimum size nor an ideal packing sequence for minimizing fluid invasion and optimizing sealing.This paper elaborates an ideal packing approach to solving the sealing problem by sealing pores with different sizes,especially those large pores which usually make dominant contribution to permeability and thereby effectively preventing the solids and filtrate of drill-in fluids from invading into formations,compared with the conventionally used techniques.Practical software has been developed to optimize the blending proportion of several bridging agents,so as to achieve ideal packing effectiveness.The method and its use in selecting the best blending proportion of several bridging agents are also discussed in this paper.A carefully designed drill-in fluid by using the ideal packing technique (named the IPT fluid) for offshore drilling operations at the Weizhou Oilfield,Nanhai West Company,CNOOC is presented.The near 100% return permeabilities from the dynamic damage tests using reservoir cores demonstrated the excellent bridging effect provided by this drill-in fluid.

  7. Particle shape effects on the stress response of granular packings.

    Science.gov (United States)

    Athanassiadis, Athanasios G; Miskin, Marc Z; Kaplan, Paul; Rodenberg, Nicholas; Lee, Seung Hwan; Merritt, Jason; Brown, Eric; Amend, John; Lipson, Hod; Jaeger, Heinrich M

    2014-01-01

    We present measurements of the stress response of packings formed from a wide range of particle shapes. Besides spheres these include convex shapes such as the Platonic solids, truncated tetrahedra, and triangular bipyramids, as well as more complex, non-convex geometries such as hexapods with various arm lengths, dolos, and tetrahedral frames. All particles were 3D-printed in hard resin. Well-defined initial packing states were established through preconditioning by cyclic loading under given confinement pressure. Starting from such initial states, stress-strain relationships for axial compression were obtained at four different confining pressures for each particle type. While confining pressure has the largest overall effect on the mechanical response, we find that particle shape controls the details of the stress-strain curves and can be used to tune packing stiffness and yielding. By correlating the experimentally measured values for the effective Young's modulus under compression, yield stress and energy loss during cyclic loading, we identify trends among the various shapes that allow for designing a packing's aggregate behavior.

  8. Packing states of multilamellar vesicles in a nonionic surfactant system

    DEFF Research Database (Denmark)

    Le, T.D.; Olsson, U.; Mortensen, K.

    2001-01-01

    under shear. Here, we focused only in the MLV region, L-alpha(*), of a temperature sensitive surfactant system (C12E4-water) to investigate the packing of multilamellar vesicles as a function of temperature under constant shear. Two sets of temperature scan experiments were performed in the L...

  9. Mass transfer models analysis for the structured packings

    International Nuclear Information System (INIS)

    The models that have been developing, to understand the mechanism of the mass transfer through the structured packings, present limitations for their application, existing then uncertainty in order to use them in the chemical industrial processes. In this study the main parameters used in the mass transfer are: the hydrodynamic of the bed of the column, the geometry of the bed, physical-chemical properties of the mixture and the flow regime of the operation between the flows liquid-gas. The sensibility of each one of these parameters generate an arduous work to develop right proposals and good interpretation of the phenomenon. With the purpose of showing the importance of these parameters mentioned in the mass transfer, this work is analyzed the process of absorption for the system water-air, using the models to the structured packings in packed columns. The models selected were developed by Bravo and collaborators in 1985 and 1992, in order to determine the parameters previous mentioned for the system water-air, using a structured packing built in the National Institute of Nuclear Research. In this work is showed the results of the models application and their discussion. (Author)

  10. Frac-and-pack stimulation: Application, design, and field experience

    Energy Technology Data Exchange (ETDEWEB)

    Roodhart, L.P.; Fokker, P.A.; Davies, D.R.; Shlyapobersky, J.; Wong, G.K.

    1994-03-01

    This paper discusses the criteria for selecting wells to be frac-and-packed. The authors show how systematic study of the inflow performance can be used to assess the potential of frac-and-packed wells, to identify the controlling factors, and to optimize design parameters. They also show that fracture conductivity is often the key to successful treatment. This conductivity depends largely on proppant size; formation permeability damage around the created fracture has less effect. Appropriate allowance needs to be made for flow restrictions caused by the presence of the perforations, partial penetration, and non-Darcy effects. They describe the application of the overpressure-calibrated hydraulic fracture model in frac-and-pack treatment design, and discuss some operational considerations with reference to field examples. The full potential of this promising new completion method can be achieved only if the design is tailored to the individual well. This demands high-quality input data, which can be obtained only from a calibration test. This paper presents their strategy for frac-and-pack design, drawing on examples from field experience. They also point out several areas that the industry needs to address, such as the sizing of proppant in soft formations and the interaction between fracturing fluids and resin in resin-coated proppant.

  11. 7 CFR 51.2840 - Export packing requirements.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 2 2010-01-01 2010-01-01 false Export packing requirements. 51.2840 Section 51.2840 Agriculture Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards, Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE REGULATIONS AND STANDARDS UNDER THE...

  12. A NOTE ON MULTIFRACTAL PACKING DIMENSION OF MEASURES

    Institute of Scientific and Technical Information of China (English)

    Jinjun Li

    2009-01-01

    The relations between the multifractal packing dimension of Borel probability measures and the asymptotic behavior of the function φ*(x)=lim sup/r→0 logv(V(x, r))-qlogμ(B(x, r))/logr are discussed and some applications are given.

  13. Efficient epoxidation of propene using molecular catalysts

    DEFF Research Database (Denmark)

    Markovits, Iulius I. E.; Anthofer, Michael H.; Kolding, Helene;

    2014-01-01

    The epoxidation of propene is performed in homogeneous phase using various molecular catalysts and H2O2 or tert-butyl hydroperoxide as oxidants. A comparison between some molybdenum catalysts and methyltrioxorhenium (MTO) shows that the well known Re catalyst is the best among the examined...

  14. Novel non-platinum metal catalyst material

    DEFF Research Database (Denmark)

    2014-01-01

    The present invention relates to a novel non-platinum metal catalyst material for use in low temperature fuel cells and electrolysers and to fuel cells and electrolysers comprising the novel non-platinum metal catalyst material. The present invention also relates to a novel method for synthesizing...... the novel non-platinum metal catalyst material....

  15. Silver doped catalysts for treatment of exhaust

    Energy Technology Data Exchange (ETDEWEB)

    Park, Paul Worn (Peoria, IL); Hester, Virgil Raymond (Edelstein, IL); Ragle, Christie Susan (Havana, IL); Boyer, Carrie L. (Shiloh, IL)

    2009-06-02

    A method of making an exhaust treatment element includes washcoating a substrate with a slurry that includes a catalyst support material. At least some of the catalyst support material from the slurry may be transferred to the substrate, and silver metal (Ag) is dispersed within the catalyst support material.

  16. Alternative alkali resistant deNOx catalysts

    DEFF Research Database (Denmark)

    Putluru, Siva Sankar Reddy; Kristensen, Steffen Buus; Due-Hansen, Johannes;

    2012-01-01

    Alternative alkali resistant deNOx catalysts were prepared using three different supports ZrO2, TiO2 and Mordenite zeolite. The majority of the catalysts were prepared by incipient wetness impregnation of a commercial support, with vanadium, copper or iron precursor, one catalyst was prepared...

  17. Intrinsic Selectivity and Structure Sensitivity of Rhodium Catalysts for C(2+) Oxygenate Production.

    Science.gov (United States)

    Yang, Nuoya; Medford, Andrew J; Liu, Xinyan; Studt, Felix; Bligaard, Thomas; Bent, Stacey F; Nørskov, Jens K

    2016-03-23

    Synthesis gas (CO + H2) conversion is a promising route to converting coal, natural gas, or biomass into synthetic liquid fuels. Rhodium has long been studied as it is the only elemental catalyst that has demonstrated selectivity to ethanol and other C2+ oxygenates. However, the fundamentals of syngas conversion over rhodium are still debated. In this work a microkinetic model is developed for conversion of CO and H2 into methane, ethanol, and acetaldehyde on the Rh (211) and (111) surfaces, chosen to describe steps and close-packed facets on catalyst particles. The model is based on DFT calculations using the BEEF-vdW functional. The mean-field kinetic model includes lateral adsorbate-adsorbate interactions, and the BEEF-vdW error estimation ensemble is used to propagate error from the DFT calculations to the predicted rates. The model shows the Rh(211) surface to be ∼6 orders of magnitude more active than the Rh(111) surface, but highly selective toward methane, while the Rh(111) surface is intrinsically selective toward acetaldehyde. A variety of Rh/SiO2 catalysts are synthesized, tested for catalytic oxygenate production, and characterized using TEM. The experimental results indicate that the Rh(111) surface is intrinsically selective toward acetaldehyde, and a strong inverse correlation between catalytic activity and oxygenate selectivity is observed. Furthermore, iron impurities are shown to play a key role in modulating the selectivity of Rh/SiO2 catalysts toward ethanol. The experimental observations are consistent with the structure-sensitivity predicted from theory. This work provides an improved atomic-scale understanding and new insight into the mechanism, active site, and intrinsic selectivity of syngas conversion over rhodium catalysts and may also guide rational design of alloy catalysts made from more abundant elements. PMID:26958997

  18. Potent inhibition of mandelate racemase by a fluorinated substrate-product analogue with a novel binding mode.

    Science.gov (United States)

    Nagar, Mitesh; Lietzan, Adam D; St Maurice, Martin; Bearne, Stephen L

    2014-02-25

    Mandelate racemase (MR) from Pseudomonas putida catalyzes the Mg(2+)-dependent 1,1-proton transfer that interconverts the enantiomers of mandelate. Because trifluorolactate is also a substrate of MR, we anticipated that replacing the phenyl rings of the competitive, substrate-product analogue inhibitor benzilate (Ki = 0.7 mM) with trifluoromethyl groups might furnish an inhibitor. Surprisingly, the substrate-product analogue 3,3,3-trifluoro-2-hydroxy-2-(trifluoromethyl)propanoate (TFHTP) was a potent competitive inhibitor [Ki = 27 ± 4 μM; cf. Km = 1.2 mM for both (R)-mandelate and (R)-trifluorolactate]. To understand the origins of this high binding affinity, we determined the X-ray crystal structure of the MR-TFHTP complex to 1.68 Å resolution. Rather than chelating the active site Mg(2+) with its glycolate moiety, like other ground state analogues, TFHTP exhibited a novel binding mode with the two trifluoromethyl groups closely packed against the 20s loop and the carboxylate bridging the two active site Brønsted acid-base catalysts Lys 166 and His 297. Recognizing that positioning a carboxylate between the Brønsted acid-base catalysts could yield an inhibitor, we showed that tartronate was a competitive inhibitor of MR (Ki = 1.8 ± 0.1 mM). The X-ray crystal structure of the MR-tartronate complex (1.80 Å resolution) revealed that the glycolate moiety of tartronate chelated the Mg(2+) and that the carboxylate bridged Lys 166 and His 297. Models of tartronate in monomers A and B of the crystal structure mimicked the binding orientations of (S)-mandelate and that anticipated for (R)-mandelate, respectively. For the latter monomer, the 20s loop appeared to be disordered, as it also did in the X-ray structure of the MR triple mutant (C92S/C264S/K166C) complexed with benzilate, which was determined to 1.89 Å resolution. These observations indicate that the 20s loop likely undergoes a significant conformational change upon binding (R)-mandelate. In general, our

  19. Biodiesel production using heterogenous catalyst

    Science.gov (United States)

    The current transesterification of triacylglycerides (TAG) to produce biodiesel is based on the homogenous catalyst method using strong base such as hydroxides or methoxides. However, this method results in a number of problems: (1) acid pre-treatment is required of feedstocks high in free fatty ac...

  20. Part I: A Comparative Thermal Aging Study on the Regenerability of Rh/Al2O3 and Rh/CexOy-ZrO2 as Model Catalysts for Automotive Three Way Catalysts

    Directory of Open Access Journals (Sweden)

    Qinghe Zheng

    2015-10-01

    Full Text Available The rhodium (Rh component in automotive three way catalysts (TWC experiences severe thermal deactivation during fuel shutoff, an engine mode (e.g., at downhill coasting used for enhancing fuel economy. In a subsequent switch to a slightly fuel rich condition, in situ catalyst regeneration is accomplished by reduction with H2 generated through steam reforming catalyzed by Rh0 sites. The present work reports the effects of the two processes on the activity and properties of 0.5% Rh/Al2O3 and 0.5% Rh/CexOy-ZrO2 (CZO as model catalysts for Rh-TWC. A very brief introduction of three way catalysts and system considerations is also given. During simulated fuel shutoff, catalyst deactivation is accelerated with increasing aging temperature from 800 °C to 1050 °C. Rh on a CZO support experiences less deactivation and faster regeneration than Rh on Al2O3. Catalyst characterization techniques including BET surface area, CO chemisorption, TPR, and XPS measurements were applied to examine the roles of metal-support interactions in each catalyst system. For Rh/Al2O3, strong metal-support interactions with the formation of stable rhodium aluminate (Rh(AlO2y complex dominates in fuel shutoff, leading to more difficult catalyst regeneration. For Rh/CZO, Rh sites were partially oxidized to Rh2O3 and were relatively easy to be reduced to active Rh0 during regeneration.

  1. High performance liquid chromatography column packings with deliberately broadened particle size distribution: relation between column performance and packing structure.

    Science.gov (United States)

    Liekens, Anuschka; Billen, Jeroen; Sherant, Ron; Ritchie, Harald; Denayer, Joeri; Desmet, Gert

    2011-09-23

    The effect of the addition of 25%, 50% and 75% (weight percent, wt%) of larger particles (resp. 3 and 5 μm) to a commercial batch of 1.9 μm particles has been investigated as an academic exercise to study the effects of particle size distribution on the kinetic performance of packed bed columns in a magnified way. Comparing the performance of the different mixtures in a kinetic plot, it could be irrefutably shown that the addition of larger particles to a commercial batch of small particles cannot be expected to lead to an improved kinetic performance. Whereas the addition of 25 wt% of larger particles still only has a minor negative effect, a significantly deteriorated performance is obtained when 50 or 75 wt% of larger particles are added. In this case, separation impedance number increases up to 200% were observed. Studying the packing structure through computational packing simulations, together with the experimental determination of the external porosity, helped in understanding the obtained results. This showed that small particles tend to settle in the flow-through pores surrounding the larger particles, leading to very high packing densities (external porosities as low as 32% were observed) and also negatively influencing the column permeability as well as the band broadening (because of the broadened flow-through pore size range).

  2. Highly stable precious metal-free cathode catalyst for fuel cell application

    Science.gov (United States)

    Serov, Alexey; Workman, Michael J.; Artyushkova, Kateryna; Atanassov, Plamen; McCool, Geoffrey; McKinney, Sam; Romero, Henry; Halevi, Barr; Stephenson, Thomas

    2016-09-01

    A platinum group metal-free (PGM-free) oxygen reduction reaction (ORR) catalyst engineered for stability has been synthesized using the sacrificial support method (SSM). This catalyst was comprehensively characterized by physiochemical analyses and tested for performance and durability in fuel cell membrane electrode assemblies (MEAs). This catalyst, belonging to the family of Fe-N-C materials, is easily scalable and can be manufactured in batches up to 200 g. The fuel cell durability tests were performed in a single cell configuration at realistic operating conditions of 0.65 V, 1.25 atmgauge air, and 90% RH for 100 h. In-depth characterization of surface chemistry and morphology of the catalyst layer before and after durability tests were performed. The failure modes of the PGM-free electrodes were derived from structure-to-property correlations. It is suggested that under constant voltage operation, the performance loss results from degradation of the electrode pore structure, while under carbon corrosion accelerated test protocols the failure mode is catalyst corrosion.

  3. Strategies for catalyst development: possibilities of the ``rational approach`` illustrated with partial oxidation reactions

    Energy Technology Data Exchange (ETDEWEB)

    Weiss, W.; Schedel-Niedrig, T.; Schloegl, R. [Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin (Germany). Abt. Oberflaechenphysik

    1998-12-31

    The paper discusses two petrochemical selective oxidation reactions namely the practised formation of styrene (STY) and the desired oxidative functionalisation of propane. The present knowledge about the mode of operation of oxide catalysts is critically considered. The dehydrogenation of ethylbenzene (EB) should be described by an oxidehydration with water acting as oxidant. The potential role of the coke formed during catalytic reaction as co-catalyst will be discussed. Selective oxidation is connected with the participation of lattice oxygen mechanism which transforms unselective gas phase oxygen into selective oxygen. The atomistic description of this process is still quite unclear as well as the electron structural properties of the activated oxygen atom. The Role of solid state acidity as compared to the role of lattice oxygen is much less well investigated modern multiphase-multielement oxide (MMO) catalysts. The rationale is that the significant efforts made to improve current MMO systems by chemical modifications can be very much more fruitful when in a first step the mode of action of a catalyst is clarified on the basis of suitable experiments. Such time-consuming experiments at the beginning of a campaign for catalyst improvement pay back their investment in later stages of the project when strategies of chemical development can be derived on grounds of understanding. (orig.)

  4. Importance of counterion reactivity on the deactivation of Co-salen catalysts in the hydrolytic kinetic resolution of epichlorohydrin.

    Science.gov (United States)

    Jain, Surbhi; Zheng, Xiaolai; Jones, Christopher W; Weck, Marcus; Davis, Robert J

    2007-10-15

    Possible modes of deactivation of Jacobsen's Co-salen catalyst during the hydrolytic kinetic resolution (HKR) of epichlorohydrin were explored by UV-vis spectroscopy, X-ray absorption spectroscopy, and electrospray ionization mass spectrometry, combined with recycling studies. Although an active Co(III)-salen catalyst deactivated substantially after multiple cycles without regeneration, the catalyst maintained its +3 oxidation state throughout the runs. Thus, deactivation of Co-salen during HKR was not the result of Co reduction. The mass spectrum of a deactivated material showed that catalyst dimerization does not account for the loss of activity. Results from various catalyst pretreatment tests, as well as from catalysts containing various counterions (acetate, tosylate, chloride, iodide) indicated that the rate of addition of the Co-salen counterions to epoxide forming Co-OH during the reaction correlated with deactivation. The extent of counterion addition to epoxide was influenced by the exposure time and the nucleophilicity of the counterion. An oligo(cyclooctene)-supported Co-OAc salen catalyst, which was 25 times more active than the standard Co-salen catalyst, was recycled multiple times with negligible deactivation. PMID:17850142

  5. Catalysis Science Initiative: Catalyst Design by Discovery Informatics

    Energy Technology Data Exchange (ETDEWEB)

    Delgass, William Nicholas [Purdue Univ., West Lafayette, IN (United States). Chemical Engineering; Abu-Omar, Mahdi [Purdue Univ., West Lafayette, IN (United States) Department of Chemistry; Caruthers, James [Purdue Univ., West Lafayette, IN (United States). Chemical Engineering; Ribeiro, Fabio [Purdue Univ., West Lafayette, IN (United States). Chemical Engineering; Thomson, Kendall [Purdue Univ., West Lafayette, IN (United States). Chemical Engineering; Schneider, William [Univ. of Notre Dame, IN (United States)

    2016-07-08

    Catalysts selectively enhance the rates of chemical reactions toward desired products. Such reactions provide great benefit to society in major commercial sectors such as energy production, protecting the environment, and polymer products and thereby contribute heavily to the country’s gross national product. Our premise is that the level of fundamental understanding of catalytic events at the atomic and molecular scale has reached the point that more predictive methods can be developed to shorten the cycle time to new processes. The field of catalysis can be divided into two regimes: heterogeneous and homogeneous. For the heterogeneous catalysis regime, we have used the water-gas shift (WGS) reaction (CO + H2O + CO2 + H2O) over supported metals as a test bed. Detailed analysis and strong coupling of theory with experiment have led to the following conclusions: • The sequence of elementary steps goes through a COOH intermediate • The CO binding energy is a strong function of coverage of CO adsorbed on the surface in many systems • In the case of Au catalysts, the CO adsorption is generally too weak on surface with close atomic packing, but the enhanced binding at corner atoms (which are missing bonding partners) of cubo-octahedral nanoparticles increases the energy to a near optimal value and produces very active catalysts. • Reaction on the metal alone cannot account for the experimental results. The reaction is dual functional with water activation occurring at the metal-support interface. It is clear from our work that the theory component is essential, not only for prediction of new systems, but also for reconciling data and testing hypotheses regarding potential descriptors. Particularly important is the finding that the interface between nano-sized metal particles and the oxides that are used to support them represent a new state of matter in the sense that the interfacial bonding perturbs the chemical state of both metals atoms and the support

  6. Autothermal reforming catalyst having perovskite structure

    Science.gov (United States)

    Krumpel, Michael; Liu, Di-Jia

    2009-03-24

    The invention addressed two critical issues in fuel processing for fuel cell application, i.e. catalyst cost and operating stability. The existing state-of-the-art fuel reforming catalyst uses Rh and platinum supported over refractory oxide which add significant cost to the fuel cell system. Supported metals agglomerate under elevated temperature during reforming and decrease the catalyst activity. The catalyst is a perovskite oxide or a Ruddlesden-Popper type oxide containing rare-earth elements, catalytically active firs row transition metal elements, and stabilizing elements, such that the catalyst is a single phase in high temperature oxidizing conditions and maintains a primarily perovskite or Ruddlesden-Popper structure under high temperature reducing conditions. The catalyst can also contain alkaline earth dopants, which enhance the catalytic activity of the catalyst, but do not compromise the stability of the perovskite structure.

  7. List mode multichannel analyzer

    Science.gov (United States)

    Archer, Daniel E.; Luke, S. John; Mauger, G. Joseph; Riot, Vincent J.; Knapp, David A.

    2007-08-07

    A digital list mode multichannel analyzer (MCA) built around a programmable FPGA device for onboard data analysis and on-the-fly modification of system detection/operating parameters, and capable of collecting and processing data in very small time bins (<1 millisecond) when used in histogramming mode, or in list mode as a list mode MCA.

  8. Fuel Cell Shaft Power Pack - Regulering af brændselsceller

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl

    2009-01-01

    Afsluttende formidling af forskningsresultater i forbindelse med projektet Fuel Cell Shaft Power Pack......Afsluttende formidling af forskningsresultater i forbindelse med projektet Fuel Cell Shaft Power Pack...

  9. Treatment of azo dye-containing wastewater by a Fenton-like process in a continuous packed-bed reactor filled with activated carbon

    International Nuclear Information System (INIS)

    Highlights: ► Oxidation with the Fenton's reagent was carried out in a packed-bed reactor. ► The packed-bed was filled with iron-impregnated activated carbon. ► The increment of temperature increases the Chicago Sky Blue removal and mineralization. ► The values of iron leaching were below 0.4 ppm in the outlet effluent. ► It was possible to reach a dye conversion of 88% in steady-state. - Abstract: In this work, oxidation with a Fenton-like process of a dye solution was carried out in a packed-bed reactor. Activated carbon Norit RX 3 Extra was impregnated with ferrous sulfate and used as catalyst (7 wt.% of iron). The effect of the main operating conditions in the Chicago Sky Blue (CSB) degradation was analyzed. It was found that the increase in temperature leads to a higher removal of the dye and an increased mineralization. However, it also increases the iron leaching, but the values observed were below 0.4 ppm (thus, far below European Union limits). It was possible to reach, at steady-state, a dye conversion of 88%, with a total organic carbon (TOC) removal of ca. 47%, being the reactor operated at 50 °C, pH 3, Wcat/Q = 4.1 g min mL−1 (Wcat is the mass of catalyst and Q the total feed flow rate) and a H2O2 feed concentration of 2.25 mM (for a CSB feed concentration of 0.012 mM). The same performance was reached in three consecutive cycles.

  10. Treatment of azo dye-containing wastewater by a Fenton-like process in a continuous packed-bed reactor filled with activated carbon

    Energy Technology Data Exchange (ETDEWEB)

    Mesquita, Isabel; Matos, Luis C. [Chemical Engineering Department, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); Duarte, Filipa [Chemical Engineering Department, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); LEPAE - Laboratory for Process, Environmental and Energy Engineering, Department of Chemical Engineering, Faculty of Engineering, University of Porto, Porto (Portugal); Maldonado-Hodar, F.J. [Department of Inorganic Chemistry, Faculty of Sciences, University of Granada, Av. Fuentenueva, 18071 Granada (Spain); Mendes, Adelio [Chemical Engineering Department, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); LEPAE - Laboratory for Process, Environmental and Energy Engineering, Department of Chemical Engineering, Faculty of Engineering, University of Porto, Porto (Portugal); Madeira, Luis M., E-mail: mmadeira@fe.up.pt [Chemical Engineering Department, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); LEPAE - Laboratory for Process, Environmental and Energy Engineering, Department of Chemical Engineering, Faculty of Engineering, University of Porto, Porto (Portugal)

    2012-10-30

    Highlights: Black-Right-Pointing-Pointer Oxidation with the Fenton's reagent was carried out in a packed-bed reactor. Black-Right-Pointing-Pointer The packed-bed was filled with iron-impregnated activated carbon. Black-Right-Pointing-Pointer The increment of temperature increases the Chicago Sky Blue removal and mineralization. Black-Right-Pointing-Pointer The values of iron leaching were below 0.4 ppm in the outlet effluent. Black-Right-Pointing-Pointer It was possible to reach a dye conversion of 88% in steady-state. - Abstract: In this work, oxidation with a Fenton-like process of a dye solution was carried out in a packed-bed reactor. Activated carbon Norit RX 3 Extra was impregnated with ferrous sulfate and used as catalyst (7 wt.% of iron). The effect of the main operating conditions in the Chicago Sky Blue (CSB) degradation was analyzed. It was found that the increase in temperature leads to a higher removal of the dye and an increased mineralization. However, it also increases the iron leaching, but the values observed were below 0.4 ppm (thus, far below European Union limits). It was possible to reach, at steady-state, a dye conversion of 88%, with a total organic carbon (TOC) removal of ca. 47%, being the reactor operated at 50 Degree-Sign C, pH 3, W{sub cat}/Q = 4.1 g min mL{sup -1} (W{sub cat} is the mass of catalyst and Q the total feed flow rate) and a H{sub 2}O{sub 2} feed concentration of 2.25 mM (for a CSB feed concentration of 0.012 mM). The same performance was reached in three consecutive cycles.

  11. MECHANISTIC KINETIC MODELS FOR STEAM REFORMING OF CONCENTRATED CRUDE ETHANOL ON NI/AL2O3 CATALYST

    Directory of Open Access Journals (Sweden)

    O. A. OLAFADEHAN

    2015-05-01

    Full Text Available Mechanistic kinetic models were postulated for the catalytic steam reforming of concentrated crude ethanol on a Ni-based commercial catalyst at atmosphere pressure in the temperature range of 673-863 K, and at different catalyst weight to the crude ethanol molar flow rate ratio (in the range 0.9645-9.6451 kg catalyst h/kg mole crude ethanol in a stainless steel packed bed tubular microreactor. The models were based on Langmuir-Hinshelwood-Hougen-Watson (LHHW and Eley-Rideal (ER mechanisms. The optimization routine of Nelder-Mead simplex algorithm was used to estimate the inherent kinetic parameters in the proposed models. The selection of the best kinetic model amongst the rival kinetic models was based on physicochemical, statistical and thermodynamic scrutinies. The rate determining step for the steam reforming of concentrated crude ethanol on Ni/Al2O3 catalyst was found to be surface reaction between chemisorbed CH3O and O when hydrogen and oxygen were adsorbed as monomolecular species on the catalyst surface. Excellent agreement was obtained between the experimental rate of reaction and conversion of crude ethanol, and the simulated results, with ADD% being ±0.46.

  12. Biological treatment of textile dyes by agar-agar immobilized consortium in a packed bed reactor.

    Science.gov (United States)

    Patel, Yogesh; Gupte, Akshaya

    2015-03-01

    The decolorization of Acid Maroon V was investigated using bacterial consortium EDPA containing Enterobacter dissolvens AGYP1 and Pseudomonas aeruginosa AGYP2 immobilized in different entrapment matrices. The consortium displayed 96% removal of dye (100 mg/l) within 6 h when immobilized in agar-agar. Under optimum concentrations of agar-agar (3.0% w/v) and cell biomass (0.9 g% w/v), the consortium displayed decolorization for 18 successive batches of Acid Maroon V and also decolorized 14 other different textile dyes. A packed bed reactor under batch mode showed 89% decolorization of dye after 56 repetitive cycles. Under continuous flow mode, maximum color removal was achieved with bed length of 36 cm, hydraulic retention time of 2.66 h, and dye concentration of 100 mg/l. Additionally, the reactor decolorized relatively higher concentrations (100-2000 mg/l) of dye. The synthetic dye wastewater containing five textile dyes was decolorized 92% with 62% COD reduction using an immobilized consortium.

  13. Liquid Axial Mixing in Packed Tower at Elevated Pressure

    Institute of Scientific and Technical Information of China (English)

    唐忠利; 张鹏; 等

    2003-01-01

    Liquid phase axial mixing was measured with the tracer technique in a packed column with inner diameter of 0.15m,in which the structured packing,Mellapak 350Y,was installed.Tap water as the liquid phase flowed down through the column and stagnant gas was at elevated pressure ranging from atmospheric to 2.0MPa.The model parameters of Bo andθwere estimated with the least square method in the time domain.As liquid flow rate was increased,the liquid axial mixing decreased.under our experimental conditions,the effect of pressure on Bo number on single liquid phase was negligible,and eddy diffusion was believed to be the primary cause of axial mixing in liquid phase.

  14. GravitinoPack and late decays involving gravitinos

    CERN Document Server

    Eberl, Helmut

    2015-01-01

    In this talk, we present the package GravitinoPack that calculates decays of unstable supersymmetric particles, involving gravitinos in the final or initial state. If the gravitino is the dark matter particle and therefore stable, the package calculates the decays of the lightest neutralino, and the lighter stau or stop NLSP into the gravitino LSP and one or two Standard Model particles. On the other hand, assuming that the gravitino is unstable, GravitinoPack calculates all its two-body and the three-body decay widths to the neutralino LSP and Standard Model particles. Since all these decays, involving the gravitino, are of gravitational nature, the lifetime of the decaying particle can be of the order of seconds are more, hence called "late decays". The precise knowledge of all these partial decay widths enables the user to apply accurately the relevant cosmological constraints.

  15. Integrating packing and distribution problems and optimization through mathematical programming

    Directory of Open Access Journals (Sweden)

    Fabio Miguel

    2016-06-01

    Full Text Available This paper analyzes the integration of two combinatorial problems that frequently arise in production and distribution systems. One is the Bin Packing Problem (BPP problem, which involves finding an ordering of some objects of different volumes to be packed into the minimal number of containers of the same or different size. An optimal solution to this NP-Hard problem can be approximated by means of meta-heuristic methods. On the other hand, we consider the Capacitated Vehicle Routing Problem with Time Windows (CVRPTW, which is a variant of the Travelling Salesman Problem (again a NP-Hard problem with extra constraints. Here we model those two problems in a single framework and use an evolutionary meta-heuristics to solve them jointly. Furthermore, we use data from a real world company as a test-bed for the method introduced here.

  16. Simulated Annealing Algorithm and Its Application in Irregular Polygons Packing

    Institute of Scientific and Technical Information of China (English)

    段国林; 王彩红; 张健楠

    2003-01-01

    Two-dimensional irregular polygons packing problem is very difficult to be solved in traditional optimal way.Simulated annealing(SA)algorithm is a stochastic optimization technique that can be used to solve packing problems.The whole process of SA is introduced firstly in this paper. An extended neighborhood searching method in SA is mainly analyzed. A general module of SA algorithm is given and used to lay out the irregular polygons. The judgment of intersection and other constrains of irregular polygons are analyzed. Then an example that was used in the paper of Stefan Jakobs is listed.Results show that this SA algorithm shortens the computation time and improves the solution.

  17. Molecular packing in bone collagen fibrils prior to mineralization

    Science.gov (United States)

    Hsiao, Benjamin; Zhou, Hong-Wen; Burger, Christian; Chu, Benjamin; Glimcher, Melvin J.

    2012-02-01

    The three-dimensional packing of collagen molecules in bone collagen fibrils has been largely unknown because even in moderately mineralized bone tissues, the organic matrix structure is severely perturbed by the deposition of mineral crystals. During the past decades, the structure of tendon collagen (e.g. rat tail) --- a tissue that cannot mineralize in vivo, has been assumed to be representative for bone collagen fibrils. Small-angle X-ray diffraction analysis of the native, uncalcified intramuscular fish bone has revealed a new molecular packing scheme, significantly different from the quasi-hexagonal arrangement often found in tendons. The deduced structure in bone collagen fibrils indicates the presence of spatially discrete microfibrils, and an arrangement of intrafibrillar space to form ``channels'', which could accommodate crystals with dimensions typically found in bone apatite.

  18. Construction of optimal supersaturated designs by the packing method

    Institute of Scientific and Technical Information of China (English)

    FANG Kaitai; GE Gennian; LIU Minqian

    2004-01-01

    A supersaturated design is essentially a factorial design with the equal occurrence of levels property and no fully aliased factors in which the number of main efits potential in factor screening experiments. A packing design is an important object in combinatorial design theory. In this paper, a strong link between the two apparently unrelated kinds of designs is shown. Several criteria for comparing supersaturated designs are proposed, their properties and connections with other existing criteria are discussed.A combinatorial approach, called the packing method, for constructing optimal supersaturated designs is presented, and properties of the resulting designs are also investigated.Comparisons between the new designs and other existing designs are given, which show that our construction method and the newly constructed designs have good properties.

  19. Packing tight Hamilton cycles in 3-uniform hypergraphs

    CERN Document Server

    Frieze, Alan; Loh, Po-Shen

    2010-01-01

    Let H be a 3-uniform hypergraph with N vertices. A tight Hamilton cycle C \\subset H is a collection of N edges for which there is an ordering of the vertices v_1, ..., v_N such that every triple of consecutive vertices {v_i, v_{i+1}, v_{i+2}} is an edge of C (indices are considered modulo N). We develop new techniques which enable us to prove that under certain natural pseudo-random conditions, almost all edges of H can be covered by edge-disjoint tight Hamilton cycles, for N divisible by 4. Consequently, we derive the corollary that random 3-uniform hypergraphs can be almost completely packed with tight Hamilton cycles w.h.p., for N divisible by 4 and P not too small. Along the way, we develop a similar result for packing Hamilton cycles in pseudo-random digraphs with even numbers of vertices.

  20. Packing of Helices: Is Chirality the Highest Crystallographic Symmetry?

    Directory of Open Access Journals (Sweden)

    Romain Gautier

    2016-08-01

    Full Text Available Chiral structures resulting from the packing of helices are common in biological and synthetic materials. Herein, we analyze the noncentrosymmetry (NCS in such systems using crystallographic considerations. A comparison of the chiral structures built from helices shows that the chirality can be expected for specific building units such as 31/32 or 61/65 helices which, in hexagonal arrangement, will more likely lead to a chiral resolution. In these two systems, we show that the highest crystallographic symmetry (i.e., the symmetry which can describe the crystal structure from the smallest assymetric unit is chiral. As an illustration, we present the synthesis of two materials ([Zn(2,2’-bpy3](NbF62 and [Zn(2,2’-bpy3](TaF62 in which the 3n helices pack into a chiral structure.

  1. Chromium Enrichment on P11 Ferritic Steel by Pack Cementation

    Directory of Open Access Journals (Sweden)

    Fauzi F. A.

    2016-01-01

    Full Text Available The future thermal power plant is expected to operate at higher temperature to improve its efficiency and to reduce greenhouse gas emission. This target requires better corrosion properties of ferritic steels, which commonly used as materials for superheater and reheater of boiler tubes. In this work, chromium enrichment on the surface of ferritic steel is studied. The deposited chromium is expected to become a reservoir for the formation of chromia protective layer. Chromium was deposited on the substrate of steel by pack cementation process for two hours at the temperature of 850ºC, 950ºC and 1050ºC, respectively. XRD analysis indicated that chromium was successfully deposited at all temperatures. Somehow, SEM cross sectional image showed that continuous layer of chromium was not continuously formed at 850oC. Therefore, this research clarify that chromium enrichment by pack cementation may be conducted at the temperature above 950°C.

  2. Packing Different Cuboids with Rotations and Spheres into a Cuboid

    Directory of Open Access Journals (Sweden)

    Y. G. Stoyan

    2014-01-01

    Full Text Available The paper considers a packing optimization problem of different spheres and cuboids into a cuboid of the minimal height. Translations and continuous rotations of cuboids are allowed. In the paper, we offer a way of construction of special functions (Φ-functions describing how rotations can be dealt with. These functions permit us to construct the mathematical model of the problem as a classical mathematical programming problem. Basic characteristics of the mathematical model are investigated. When solving the problem, the characteristics allow us to apply a number of original and state-of-the-art efficient methods of local and global optimization. Numerical examples of packing from 20 to 300 geometric objects are given.

  3. The fine triangle intersections for maximum kite packings

    OpenAIRE

    Zhang, Guizhi; Chang, Yanxun; Feng, Tao

    2012-01-01

    In this paper the fine triangle intersection problem for a pair of maximum kite packings is investigated. Let $Fin(v)={(s,t):$ $\\exists$ a pair of maximum kite packings of order $v$ intersecting in $s$ blocks and $s+t$ triangles$}$. Let $Adm(v)={(s,t): s+t\\leq b_v, s,t$ are non-negative integers$}$, where $b_v=\\lfloor v(v-1)/8\\rfloor$. It is established that $Fin(v)= Adm(v)\\setminus {(b_v-1,0),(b_v-1,1)}$ for any integer $v\\equiv 0,1 ({\\rm mod} 8)$ and $v\\geq 8$; $Fin(v)=Adm(v)$ for any integ...

  4. Mobility of icy sand packs, with application to Martian permafrost

    Science.gov (United States)

    Durham, W.B.; Pathare, A.V.; Stern, L.A.; Lenferink, H.J.

    2009-01-01

    [1] The physical state of water on Mars has fundamental ramifications for both climatology and astrobiology. The widespread presence of "softened" Martian landforms (such as impact craters) can be attributed to viscous creep of subsurface ground ice. We present laboratory experiments designed to determine the minimum amount of ice necessary to mobilize topography within Martian permafrost. Our results show that the jammed-to-mobile transition of icy sand packs neither occurs at fixed ice content nor is dependent on temperature or stress, but instead correlates strongly with the maximum dry packing density of the sand component. Viscosity also changes rapidly near the mobility transition. The results suggest a potentially lower minimum volatile inventory for the impact-pulverized megaregolith of Mars. Furthermore, the long-term preservation of partially relaxed craters implies that the ice content of Martian permafrost has remained close to that at the mobility transition throughout Martian history. Copyright 2009 by the American Geophysical Union.

  5. 48 CFR 252.211-7004 - Alternate preservation, packaging, and packing.

    Science.gov (United States)

    2010-10-01

    ..., packaging, and packing. 252.211-7004 Section 252.211-7004 Federal Acquisition Regulations System DEFENSE... CLAUSES Text of Provisions And Clauses 252.211-7004 Alternate preservation, packaging, and packing. As prescribed in 211.272, use the following provision: Alternate Preservation, Packaging, and Packing (DEC...

  6. A Recursive Formulation of Cholesky Factorization of a Matrix in Packed Storage Format

    DEFF Research Database (Denmark)

    Andersen, Bjarne Stig; Gustavson, Fred; Wasniewski, Jerzy

    2001-01-01

    A new compact way to store a symmetric or triangular matrix called RPF for Recursive Packed Format is fully described. Novel ways to transform RPF to and from standard packed format are included. A new algorithm, called RPC for Recursive Packed Cholesky that operates on the RPF format is presente...

  7. A study on the turbine efficiency through the shaft packing improvement of new fossil power plant

    International Nuclear Information System (INIS)

    The main reason for applying positive pressure variable clearance packing in fossil power plant is high efficiency and energy saving movement in the government. This study intends to analyze the turbine efficiency through the shaft packing improvement in thermal power plant and makes its comparison to that of the used packing

  8. Schwarz’s lemma for the circle packings with the general combinatorics

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Rodin (1987) proved the Schwarz’s lemma analog for the circle packings based on the hexagonal combinatorics. In this paper, we prove the Schwarz’s lemma for the circle packings with the general combinatorics and our proof is more simpler than Rodin’s proof. At the same time, we obtain a rigidity property for those packings with the general combinatorics.

  9. Effect of particle shape on the random packing density of amorphous solids

    NARCIS (Netherlands)

    Kyrylyuk, A.V.; Philipse, A.P.

    2011-01-01

    The packing density of a particulate solid strongly depends on the shape of the particles that are jammed at random close packing (RCP). To investigate the effect of particle shape on the RCP density of an amorphous solid, we studied jammed packings of binary mixtures of a-thermal or granular sphero

  10. Packing of Fruit Fly Parasitoids for Augmentative Releases

    OpenAIRE

    Pablo Montoya; Lía Ruiz; Jorge Cancino

    2012-01-01

    The successful application of Augmentative Biological Control (ABC) to control pest fruit flies (Diptera: Tephritidae) confronts two fundamental requirements: (1) the establishment of efficient mass rearing procedures for the species to be released, and (2) the development of methodologies for the packing and release of parasitoids that permit a uniform distribution and their optimal field performance under an area-wide approach. Parasitoid distributions have been performed by ground and by a...

  11. Packed multi-channels for parallel chromatographic separations in microchips.

    Science.gov (United States)

    Nagy, Andrea; Gaspar, Attila

    2013-08-23

    Here we report on a simple method to fabricate microfluidic chip incorporating multi-channel systems packed by conventional chromatographic particles without the use of frits. The retaining effectivities of different bottlenecks created in the channels were studied. For the parallel multi-channel chromatographic separations several channel patterns were designed. The obtained multipackings were applied for parallel separations of dyes. The implementation of several chromatographic separation units in microscopic size makes possible faster and high throughput separations.

  12. Generic Unpacking of Self-modifying, Aggressive, Packed Binary Programs

    OpenAIRE

    Bania, Piotr

    2009-01-01

    Nowadays most of the malware applications are either packed or protected. This techniques are applied especially to evade signature based detectors and also to complicate the job of reverse engineers or security analysts. The time one must spend on unpacking or decrypting malware layers is often very long and in fact remains the most complicated task in the overall process of malware analysis. In this report author proposes MmmBop as a relatively new concept of using dynamic binary instrument...

  13. Nearly-Linear Time Packing and Covering LP Solvers

    OpenAIRE

    Allen-Zhu, Zeyuan; Orecchia, Lorenzo

    2014-01-01

    Packing and covering linear programs (PC-LPs) form an important class of linear programs (LPs) across computer science, operations research, and optimization. In 1993, Luby and Nisan constructed an iterative first-order algorithm for approximately solving PC-LPs in $\\textit{nearly-linear time}$, independently of the program's $\\textit{width}$, i.e., the largest value in the program's description. Unfortunately, all existing nearly-linear-time algorithms for solving PC-LPs require time at leas...

  14. A genetic programming hyper-heuristic approach to automated packing

    OpenAIRE

    Hyde, Matthew

    2010-01-01

    This thesis presents a programme of research which investigated a genetic programming hyper-heuristic methodology to automate the heuristic design process for one, two and three dimensional packing problems. Traditionally, heuristic search methodologies operate on a space of potential solutions to a problem. In contrast, a hyper-heuristic is a heuristic which searches a space of heuristics, rather than a solution space directly. The majority of hyper-heuristic research papers, so far, hav...

  15. Packing Regularities in Biological Structures Relate to Their Dynamics

    OpenAIRE

    Jernigan, Robert L.; Kloczkowski, Andrzej

    2007-01-01

    The high packing density inside proteins leads to certain geometric regularities and also is one of the most important contributors to the high extent of cooperativity manifested by proteins in their cohesive domain motions. The orientations between neighboring non-bonded residues in proteins substantially follow the similar geometric regularities, regardless of whether the residues are on the surface or buried - a direct result of hydrophobicity forces. These orientations are relatively fixe...

  16. Pulp moulding machines for the production of packing paper elements

    OpenAIRE

    Lukić Ljubomir S.; Krgović Milorad V.; Jaraković Ilija M.

    2005-01-01

    Paper pulp molds are now commonly applied in the technology of modern packing for a wide range of products. The technological process of producing the paper molds has three basic phases: paper pulp preparation, in which water and waste paper are the basic raw materials, the formation of product in tool pulp moulding machines and process drying. The firm "SERVOTEH" from Belgrade has developed various pulp moulding machines for different operating conditions (manual, semiautomatic and automatic...

  17. QUALITY ASSESSMENT OF EGGS PACKED UNDER MODIFIED ATMOSPHERE

    OpenAIRE

    Aline Giampietro-Ganeco; Hirasilva Borba; Aline Mary Scatolini-Silva; Marcel Manente Boiago; Pedro Alves de Souza; Juliana Lolli Malagoli de Mello

    2015-01-01

    Eggs are perishable foods and lose quality quickly if not stored properly. From the moment of posture to the marketing of egg, quality loss occurs through gas exchange and water through the pores of the shell with the external environment and thus, studies involving modified atmosphere packaging are extremely important. The aim of the present study is to assess the internal quality of eggs packed under modified atmosphere and stored at room temperature. Six hundred and twelve fresh commercial...

  18. Controlling droplet incubation using close-packed plug flow

    OpenAIRE

    Mary, Pascaline; Abate, Adam R.; Agresti, Jeremy J.; Weitz, David A.

    2011-01-01

    Controlling droplet incubation is critical for droplet-based microfluidic applications; however, current techniques are either of limited precision or place strict limits on the incubation times that can be achieved. Here, we present a simple technique to control incubation time by exploiting close-packed plug flow. In contrast to other techniques, this technique is applicable to very short and very long incubation times.

  19. Catalysts for upgrading coal-derived oils; Sekitan ekikayu no upgrading shokubai

    Energy Technology Data Exchange (ETDEWEB)

    Yoshimura, Y.; Sato, T.; Shimada, H.; Matsubayashi, N.; Nishijima, A.; Kaneoka, T.; Yanase, H.; Watanabe, M.; Masuda, K.; Kanda, Y.; Osuka, K. [National Institute of Materials and Chemical Research, Tsukuba (Japan)

    1995-07-28

    Coal-derived oils were hydrotreated in two-stage catalytic processes or in single stage co-refining catalytic processes to produce high-quality oils. The former processes were much more flexible to control the quality of the final products such as gasoline and/or kerosene, depending on the reaction mode/severity of each stage. In hydrotreating neat and low sulfur coal-derived oils, we developed a new type of NiW/Al2O3 hydrotreating catalyst for the first stage use, which catalyst had higher hydrogenation and hydrodenitrogenation activities and better activity maintenance than the conventional NiMo/Al2O3 catalysts. A new type of NiW/Al2O3-USY-zeolite hydrocracking catalyst, which showed high activity to convert 180{degree}C+ fraction into gasoline fraction with minimal gas make, was also developed for the second stage usage. In the latter co-refining process, where coal-derived oils were mixed with the proper fraction of petroleum oils and hydroprocessed to get high-quality kerosene and/or diesel oils, RuNiMo/Al2O3 catalysts were superior to NiMo/Al2O3 and NiW/Al2O3 catalysts. Spent NiW and NiMo catalysts were successfully cured by the oxidative regeneration under the low partial pressure of oxygen (-1.5%) in the oxidizing gas and low oxidation temperature conditions. The thermodynamic analyses gave us a new criteria for designing/selecting the catalytic materials and for optimizing the catalyst calcination/sulfidation/hydrotreating reaction conditions. 21 refs., 21 figs., 5 tabs.

  20. PlanetPack: a radial-velocity time-series analysis tool facilitating exoplanets detection, characterization, and dynamical simulations

    CERN Document Server

    Baluev, Roman V

    2013-01-01

    We present PlanetPack, a new software tool that we developed to facilitate and standardize the advanced analysis of radial velocity (RV) data for the goal of exoplanets detection, characterization, and basic dynamical $N$-body simulations. PlanetPack is a command-line interpreter, that can run either in an interactive mode or in a batch mode of automatic script interpretation. Its major abilities include: (i) Advanced RV curve fitting with the proper maximum-likelihood treatment of unknown RV jitter; (ii) User-friendly multi-Keplerian as well as Newtonian $N$-body RV fits; (iii) Use of more efficient maximum-likelihood periodograms that involve the full multi-planet fitting (sometimes called as ``residual'' or ``recursive'' periodograms); (iv) Easily calculatable parametric 2D likelihood function level contours, reflecting the asymptotic confidence regions; (v) Fitting under some useful functional constraints is user-friendly; (vi) Basic tasks of short- and long-term planetary dynamical simulation using a fas...

  1. Biodegradation of low-ethoxylated nonylphenols in a bioreactor packed with a new ceramic support (Vukopor ® S10).

    Science.gov (United States)

    Sciubba, Luigi; Bertin, Lorenzo; Todaro, Daniela; Bettini, Cristina; Fava, Fabio; Di Gioia, Diana

    2014-03-01

    This work was aimed at studying the possibility of biodegrading 4-nonylphenol and low ethoxylated nonylphenol mixtures, which are particularly recalcitrant to microbial degradation, by employing a biofilm reactor packed with a ceramic support (Vukopor® S10). A selected microbial consortium (Consortium A) was used to colonize the support. 4-Nonylphenol and ethoxylated nonylphenol degradation and mineralization capabilities were studied both in batch and continuous mode. The results showed that Vukopor® S10 was able to be colonized by an active biofilm for the degradation of the target pollutants with the reactor operating both in batch and continuous mode. On the other hand, pollutant adsorption on the support was negligible. FISH showed equal proportion of Alphaproteobacteria and Gammaproteobacteria in the Igepal CO-520 degrading reactor. A shift towards high proportion of Gammaproteobacteria was observed by supplying Igepal CO-210. PCR-density gradient gel electrophoresis (DGGE) analyses also evidenced that the biofilm evolved with time by changing the mixture applied and that Proteobacteria were the most represented phylum in the biofilm. Taken together, the data obtained provide a strong indication that the biofilm reactor packed with Vukopor® S10 and inoculated with Consortium A could potentially be used to develop a technology for the decontamination of 4-nonylphenol and low ethoxylated nonylphenol polluted effluents.

  2. Discrimination between biological interfaces and crystal-packing contacts

    Directory of Open Access Journals (Sweden)

    Yuko Tsuchiya

    2008-11-01

    Full Text Available Yuko Tsuchiya1, Haruki Nakamura2, Kengo Kinoshita1,31Institute of Medical Science, The University of Tokyo, 4-6-1 Shirokanedai, Minatoku, Tokyo, 108-8639, Japan; 2Institute for Protein Research, Osaka University, 3-2 Yamadaoka, Suita, Osaka, 565-0871, Japan; 3Bioinformatics Research and Development, JST, 4-1-8 Honcho, Kawaguchi, Saitama, 332-0012, JapanAbstract: A discrimination method between biologically relevant interfaces and artificial crystal-packing contacts in crystal structures was constructed. The method evaluates protein-protein interfaces in terms of complementarities for hydrophobicity, electrostatic potential and shape on the protein surfaces, and chooses the most probable biological interfaces among all possible contacts in the crystal. The method uses a discriminator named as “COMP”, which is a linear combination of the complementarities for the above three surface features and does not correlate with the contact area. The discrimination of homo-dimer interfaces from symmetry-related crystal-packing contacts based on the COMP value achieved the modest success rate. Subsequent detailed review of the discrimination results raised the success rate to about 88.8%. In addition, our discrimination method yielded some clues for understanding the interaction patterns in several examples in the PDB. Thus, the COMP discriminator can also be used as an indicator of the “biological-ness” of protein-protein interfaces.Keywords: protein-protein interaction, complementarity analysis, homo-dimer interface, crystal-packing contact, biological interfaces

  3. Gradient packing bed bio-filter for landfill methane mitigation.

    Science.gov (United States)

    Obulisamy, Parthiba Karthikeyan; Sim Yan May, Jane; Rajasekar, Balasubramanian

    2016-10-01

    We assessed the suitability of various biogenic materials for development of a gradient packed bed bio-filter to mitigate the methane (CH4) emission from landfills. Five different biogenic materials (windrow compost-WC; vermicompost-VC; landfill top cover-LTC; landfill bottom soil-LBS; and river soil sediment-SS) were screened. Among these materials, the VC showed a better CH4 oxidation potential (MOP) of 12.6μg CH4 gdw(-1)h(-1). Subsequently, the VC was used as a packing material along with wood chips in proto-type bio-filters. Wood chips were mixed at 5-15% to form three distinct gradients in a test bio-filter. Under the three different CH4 loading rates of 33, 44 and 55 gCH4 m(-3)h(-1), the achieved MOPs were 31, 41, and 47gCH4 m(-3)h(-1), respectively. The gradient packed bed bio-filter is effective for landfill CH4 mitigation than the conventional bio-filter as the latter shows gas channeling effects with poor MOPs. PMID:26883060

  4. Gradient packing bed bio-filter for landfill methane mitigation.

    Science.gov (United States)

    Obulisamy, Parthiba Karthikeyan; Sim Yan May, Jane; Rajasekar, Balasubramanian

    2016-10-01

    We assessed the suitability of various biogenic materials for development of a gradient packed bed bio-filter to mitigate the methane (CH4) emission from landfills. Five different biogenic materials (windrow compost-WC; vermicompost-VC; landfill top cover-LTC; landfill bottom soil-LBS; and river soil sediment-SS) were screened. Among these materials, the VC showed a better CH4 oxidation potential (MOP) of 12.6μg CH4 gdw(-1)h(-1). Subsequently, the VC was used as a packing material along with wood chips in proto-type bio-filters. Wood chips were mixed at 5-15% to form three distinct gradients in a test bio-filter. Under the three different CH4 loading rates of 33, 44 and 55 gCH4 m(-3)h(-1), the achieved MOPs were 31, 41, and 47gCH4 m(-3)h(-1), respectively. The gradient packed bed bio-filter is effective for landfill CH4 mitigation than the conventional bio-filter as the latter shows gas channeling effects with poor MOPs.

  5. Pack hunting by a common soil amoeba on nematodes.

    Science.gov (United States)

    Geisen, Stefan; Rosengarten, Jamila; Koller, Robert; Mulder, Christian; Urich, Tim; Bonkowski, Michael

    2015-11-01

    Soils host the most complex communities on Earth, including the most diverse and abundant eukaryotes, i.e. heterotrophic protists. Protists are generally considered as bacterivores, but evidence for negative interactions with nematodes both from laboratory and field studies exist. However, direct impacts of protists on nematodes remain unknown. We isolated the soil-borne testate amoeba Cryptodifflugia operculata and found a highly specialized and effective pack-hunting strategy to prey on bacterivorous nematodes. Enhanced reproduction in presence of prey nematodes suggests a beneficial predatory life history of these omnivorous soil amoebae. Cryptodifflugia operculata appears to selectively impact the nematode community composition as reductions of nematode numbers were species specific. Furthermore, we investigated 12 soil metatranscriptomes from five distinct locations throughout Europe for 18S ribosomal RNA transcripts of C. operculata. The presence of C. operculata transcripts in all samples, representing up to 4% of the active protist community, indicates a potential ecological importance of nematophagy performed by C. operculata in soil food webs. The unique pack-hunting strategy on nematodes that was previously unknown from protists, together with molecular evidence that these pack hunters are likely to be abundant and widespread in soils, imply a considerable importance of the hitherto neglected trophic link 'nematophagous protists' in soil food webs.

  6. Pack cementation diffusion coatings for iron-base alloys

    Energy Technology Data Exchange (ETDEWEB)

    Rapp, R.A. [Ohio State Univ., Columbus, OH (United States). Dept. of Materials Science and Engineering

    1995-02-01

    With the aid of computer-assisted calculations of the equilibrium vapor pressures in halide-activated cementation packs, processing conditions have been identified and experimentally verified for the codeposition of two or more alloying elements in a diffusion coating on a variety of steels. The Cr-Si ferrite layers have proven to be very resistant to high temperature cyclic oxidation and to pitting in aqueous solutions. The process has been patented, and is being transferred for industrial application, e.g. for water walls of utility boilers, etc. In the proposed extension of this project, the use of mixed pure metal powders in the pack will be extended to achieve similar ferrite Fe-Cr-Al coatings with excellent oxidation resistance, with the eventual transfer of the technology to industry. In other recent studies, Ni-base alloy rods were aluminized by the halide-activated pack cementation process to bring their average composition to that for the ORNL-developed Ni{sub 3}Al, for use as a welding rod. A similar effort to develop a welding rod for the ORNL Fe{sub 3}Al alloy did not yield reproducible coating compositions or growth kinetics. The continued effort to produce Duriron-type (Fe-18Si-5Cr) coatings on steels was not successful. Literature for the intrinsic diffusion coefficients suggests that this task cannot be achieved.

  7. The structure of tropical forests and sphere packings.

    Science.gov (United States)

    Taubert, Franziska; Jahn, Markus Wilhelm; Dobner, Hans-Jürgen; Wiegand, Thorsten; Huth, Andreas

    2015-12-01

    The search for simple principles underlying the complex architecture of ecological communities such as forests still challenges ecological theorists. We use tree diameter distributions--fundamental for deriving other forest attributes--to describe the structure of tropical forests. Here we argue that tree diameter distributions of natural tropical forests can be explained by stochastic packing of tree crowns representing a forest crown packing system: a method usually used in physics or chemistry. We demonstrate that tree diameter distributions emerge accurately from a surprisingly simple set of principles that include site-specific tree allometries, random placement of trees, competition for space, and mortality. The simple static model also successfully predicted the canopy structure, revealing that most trees in our two studied forests grow up to 30-50 m in height and that the highest packing density of about 60% is reached between the 25- and 40-m height layer. Our approach is an important step toward identifying a minimal set of processes responsible for generating the spatial structure of tropical forests.

  8. Performance of Structured Packing in High Pressure Distillation

    Institute of Scientific and Technical Information of China (English)

    张鹏; 刘春江; 等

    2002-01-01

    Performance of Mellapak 250Y and 350Y corrugated structured packing in distillation applications at pressures ranging from 0.3 to 2.0MPa is analysed by using HTU-NTU method.These data are obtained in distillation column with 0.15m diameter operated with n-butane/n-pentane system at total reflux.In considering the axial backmixing effects.the height of an overall gas phase transfer unit,HTUOG,is divided into two parts.One part represents the height of an overall gas phase transfer unit,without backmixing, designated as HUTOG,and the other part,designated as the height of a backmixing unit(HBUO),accounts for the backmixing effects.The HTUOG is evaluated from the measured concentration profile of n-butane in liquid phase.The HBUO obtained experimentally is correlated in terms of the properties of the materials being separated and the equivalent diameter of the structured packing.Our result shows that HBUO varies from 0.12 to 0.34m as pressure increases from 1.0 to 1.9MPa.It indicates that the overall efficiency of the structured packing decreas gradually at high pressure,as a result of the vapor backmixing.

  9. A new look at gravel pack carrier fluid properties

    Energy Technology Data Exchange (ETDEWEB)

    Scheuerman, R.F.

    1984-02-01

    For gravel pack carrier fluids, less viscosity is needed downhole than for suspending and pumping high gravel loadings on the surface. To achieve this dual viscosity need, breakers are added to degrade the viscosifying polymers. Unfortunately, viscosity breakback criteria are not well defined. In addition to the type and concentration of breaker and temperature, the apparent viscosity breakback time of a polymer solution also depends on the shear rate at which the viscosity is measured. As a result, industry breakback data generally disagree because of the variety of instruments and shear rates used to measure viscosity. This paper discusses two new viscosity breakback criteria for gravel packing carrier fluids: The time for the apparent viscosity at 0.03 sec/sup -1/ to decrease to 1000 cp, and start of compaction of the settled gravel bed. These criteria correlate well with fluid performance and apply to slurries with different initial viscosities (including crosslinked gels), brine densities, and gravel sizes. Data useful for formulating gravel pack carrier fluids are also presented. Although this paper does not define optimum downhole carrier fluid properties, the new criteria reflect downhole conditions better than most previous criteria. They should give better correlation with model studies and field experience, and, in turn, lead to a better understanding of the requirements for optimum downhole performance.

  10. Packing fraction of particles with a Weibull size distribution

    Science.gov (United States)

    Brouwers, H. J. H.

    2016-07-01

    This paper addresses the void fraction of polydisperse particles with a Weibull (or Rosin-Rammler) size distribution. It is demonstrated that the governing parameters of this distribution can be uniquely related to those of the lognormal distribution. Hence, an existing closed-form expression that predicts the void fraction of particles with a lognormal size distribution can be transformed into an expression for Weibull distributions. Both expressions contain the contraction coefficient β. Likewise the monosized void fraction φ1, it is a physical parameter which depends on the particles' shape and their state of compaction only. Based on a consideration of the scaled binary void contraction, a linear relation for (1 - φ1)β as function of φ1 is proposed, with proportionality constant B, depending on the state of compaction only. This is validated using computational and experimental packing data concerning random close and random loose packing arrangements. Finally, using this β, the closed-form analytical expression governing the void fraction of Weibull distributions is thoroughly compared with empirical data reported in the literature, and good agreement is found. Furthermore, the present analysis yields an algebraic equation relating the void fraction of monosized particles at different compaction states. This expression appears to be in good agreement with a broad collection of random close and random loose packing data.

  11. Particle size and packing characterization by diffuse light transmission

    Institute of Scientific and Technical Information of China (English)

    Henrik Ehlers; Jyrki Hein(a)m(a)ki; Jouko Yliruusi

    2012-01-01

    Particle size,packing density and blend composition of glass ballotini,microcrystalline cellulose pellets and theophylline granules were studied by diffuse light transmission.Diffuse visible light was directed to the sample and the intensity of the light transmitted to the opposite side of the sample was measured through a diffusing lens using a phototransistor.Light transmission was found to decrease with decreasing particle size and with increasing packing density.There was a correlation,though somewhat irregular,between light transmission and particle size for glass ballotini and microcrystalline cellulose pellets,and a strong near-linear correlation between light transmission and particle size for theophylline granules.The effect of packing density on light transmission was significant.Differentiating the composition of binary blends of microcrystalline cellulose pellets and glass ballotini and blends of theophylline granules was found possible on the basis of light transmission.The method proposed showed potential as a rapid,simple and inexpensive analytical tool for basic process diagnostics.

  12. The Use of Inorganic Packing Materials during Methane Biofiltration

    Directory of Open Access Journals (Sweden)

    Josiane Nikiema

    2010-01-01

    Full Text Available The objective behind this study is to select a suitable inorganic packing material for methane biofiltration. Three packing materials are to be compared: two rock materials (average particles' sizes: 2 and 5 mm and one porous clay particles (average particle size of 7 mm. The main parameter used to assess the efficiency of the packing material is the methane elimination capacity. The study reveals that the rock material having an average particle size around 2 mm is to be preferred. This result is probably due to its high specific surface area and to its good surface properties as compared to the other 2 tested porous materials. The influence of the nonirrigation with the nutrient solution of the biofilter is also investigated. It has been found that nonirrigation of biofilter causes the biofilter performance to decrease significantly (e.g., 45% decrease in 1 week even with the humidification of the gas phase prior to its introduction into the biofilter.

  13. Phenomenological Anisotropic Study of Surface Finish in Pack Rolling

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    A phenomenological anisotropic model has been presented for the surface roughness modeling of pack rolling. The model is an assembly of grains in different orientations and sizes. The grain size is assumed to be in log-normal distribution. To model the macro anisotropic mechanical behavior of the grains induced by the slip deformation, the grains are assumed as isolated anisotropic units. The units have different mechanic behavior, and depend on the crystallographic orientations and the external loading as well as the interaction of the adjunctive grains. In the paper,the material properties of the grains are assumed as uniform distributions. The roughness of the contact surfaces depends on the distribution types and the scatters of the distributions. It is found that the initial roughness of the contact surfaces has a little influence on the surface roughness when the rolling deformation is large. The comparison between the phenomenological model and crystallographic model shows that the phenomenological model can also give out a reasonable result, while it only takes much less CPU time. The agreement between the single sheet model and the pack rolling model shows that in a certain degree the pack rolling model can be replaced by the single sheet model to decrease the CPU time.

  14. He II heat transfer through random packed spheres: Pressure drop

    Science.gov (United States)

    Vanderlaan, M. H.; Van Sciver, S. W.

    2014-09-01

    Heat flow induced pressure drop through superfluid helium (He II) contained in porous media is examined. In this experiment, heat was applied to one side of a He II column containing a random pack of uniform size polyethylene spheres. Measured results include steady state pressure drops across the random packs of spheres (nominally 35 μm, 49 μm, and 98 μm diameter) for different heat inputs. Laminar, turbulent, and transition fluid flow regimes are examined. The laminar permeability and equivalent channel shape factor are compared to our past studies of the temperature drop through He II in the same porous media of packed spheres. Results from the pressure drop experiments are more accurate than temperature drop experiments due to reduced measurement errors achieved with the pressure transducer. Turbulent results are fitted to models with empirically derived friction factors. A turbulent model considering only dynamic pressure losses in the normal fluid yields the most consistent friction factors. The addition of the laminar and turbulent heat flow equations into a unifying prediction fits all regimes to within 10%.

  15. Geometric aspects of shear jamming induced by deformation of frictionless sphere packings

    Science.gov (United States)

    Vinutha, H. A.; Sastry, Srikanth

    2016-09-01

    It has recently been demonstrated that shear deformation of frictionless sphere packings leads to structures that will undergo jamming in the presence of friction, at densities well below the isotropic jamming point {φj}≈ 0.64 , and at high enough strains. Here, we show that the geometric features induced by strain are robust with respect to finite size effects, and include the feature of hyperuniformity, previously studied in the context of jamming, and more recently in driven systems. We study the approach to jamming as strain is increased, by evolving frictionless sheared configurations through frictional dynamics, and thereby identify a critical, or jamming, strain for each density, for a chosen value of the coefficient of friction. In the presence of friction above a certain strain value the sheared frictionless packings begin to develop finite stresses, which marks the onset of shear jamming. At a higher strain value, the shear stress reaches a saturation value after rising rapidly above the onset of shear jamming, which permits identification of the shear jamming transition. The onset of shear jamming and shear jamming are found to occur when the coordination number Z reaches values of Z  =  3 and Z  =  4 respectively. By considering percolation probabilities for the contact network, clusters of four coordinated and six coordinated spheres, we show that the percolation of four coordinated spheres corresponds to the onset of shear jamming behaviour, whereas the percolation of six coordinated spheres corresponds to shear jamming, for the chosen friction coefficients. At the onset of shear jamming, the force distribution begins to develop a peak at finite value and the force network is anisotropic and heterogeneous. And at the shear jamming transition, the force distribution has a well defined peak close to and the force network is less anisotropic and homogeneous. We briefly discuss mechanical aspects of the jamming behaviour by performing

  16. Attachment-less rack mounted paper-pack automatic vending machine; Atacchimentoresu rakku tosai paper pack jido hanbaiki

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-01-10

    Under the circumstances that over 90% of automatic paper-pack vending machines are installed indoors, a new series was developed with an aim to enhance installation convenience and operation performance. Automatic paper-pack vending machines selling merchandises reaching as many as 30 models have required a number of attachments. The new series mounted with attachment-less directly loaded racks eliminating all of the attachments was put into mass production for the first time in the industry. Its major features are as follows: (1) the directly loaded racks requiring no attachments can be mounted by making the rack side plate movable when merchandises are changed; (2) improvement in the main box body construction reduced the box width by 7 cm; (3) 10% energy conservation was achieved as compared to conventional machines; and (4) merchandise moving noise was reduced by adopting plastic chains. (translated by NEDO)

  17. Highly Active Carbon Supported Pd-Ag Nanofacets Catalysts for Hydrogen Production from HCOOH.

    Science.gov (United States)

    Wang, Wenhui; He, Ting; Liu, Xuehua; He, Weina; Cong, Hengjiang; Shen, Yangbin; Yan, Liuming; Zhang, Xuetong; Zhang, Jinping; Zhou, Xiaochun

    2016-08-17

    Hydrogen is regarded as a future sustainable and clean energy carrier. Formic acid is a safe and sustainable hydrogen storage medium with many advantages, including high hydrogen content, nontoxicity, and low cost. In this work, a series of highly active catalysts for hydrogen production from formic acid are successfully synthesized by controllably depositing Pd onto Ag nanoplates with different Ag nanofacets, such as Ag{111}, Ag{100}, and the nanofacet on hexagonal close packing Ag crystal (Ag{hcp}). Then, the Pd-Ag nanoplate catalysts are supported on Vulcan XC-72 carbon black to prevent the aggregation of the catalysts. The research reveals that the high activity is attributed to the formation of Pd-Ag alloy nanofacets, such as Pd-Ag{111}, Pd-Ag{100}, and Pd-Ag{hcp}. The activity order of these Pd-decorated Ag nanofacets is Pd-Ag{hcp} > Pd-Ag{111} > Pd-Ag{100}. Particularly, the activity of Pd-Ag{hcp} is up to an extremely high value, i.e., TOF{hcp} = 19 000 ± 1630 h(-1) at 90 °C (lower limit value), which is more than 800 times higher than our previous quasi-spherical Pd-Ag alloy nanocatalyst. The initial activity of Pd-Ag{hcp} even reaches (3.13 ± 0.19) × 10(6) h(-1) at 90 °C. This research not only presents highly active catalysts for hydrogen generation but also shows that the facet on the hcp Ag crystal can act as a potentially highly active catalyst. PMID:27454194

  18. Investigation of heat transfer and friction characteristics of packed bed solar air heater using wire mesh as packing material

    Energy Technology Data Exchange (ETDEWEB)

    Prasad, S.B.; Saini, J.S.; Singh, Krishna M. [Department of Mechanical and Industrial Engineering, Indian Institute of Technology Roorkee, Roorkee 247667 (India)

    2009-05-15

    An experimental investigation has been carried out on a packed bed solar air heater using wire mesh as packing material. Data pertaining to heat transfer and friction characteristics were collected for air flow rates ranging from 0.0159 to 0.0347 kg/s-m{sup 2} for eight sets of matrices with varying geometrical parameters. The thermal efficiency of a packed bed solar air heater was compared with that of a conventional solar air heater to determine the enhancement which was found to be strong function of system and operating parameters of the bed. It was found that an enhancement of the order of 76.9-89.5% can be obtained. Experimental data were utilised to develop correlations for Colburn J{sub h} factor and friction factor as function of geometrical parameters of the bed and the flow Reynolds number. These correlations were found to predict the experimental results with reasonable accuracy. It has also been found that the present correlations show much better agreement as compared to the values predicted by earlier correlations for such systems. (author)

  19. Disordered strictly jammed binary sphere packings attain an anomalously large range of densities.

    Science.gov (United States)

    Hopkins, Adam B; Stillinger, Frank H; Torquato, Salvatore

    2013-08-01

    Previous attempts to simulate disordered binary sphere packings have been limited in producing mechanically stable, isostatic packings across a broad spectrum of packing fractions. Here we report that disordered strictly jammed binary packings (packings that remain mechanically stable under general shear deformations and compressions) can be produced with an anomalously large range of average packing fractions 0.634≤φ≤0.829 for small to large sphere radius ratios α restricted to α≥0.100. Surprisingly, this range of average packing fractions is obtained for packings containing a subset of spheres (called the backbone) that are exactly strictly jammed, exactly isostatic, and also generated from random initial conditions. Additionally, the average packing fractions of these packings at certain α and small sphere relative number concentrations x approach those of the corresponding densest known ordered packings. These findings suggest for entropic reasons that these high-density disordered packings should be good glass formers and that they may be easy to prepare experimentally. We also identify an unusual feature of the packing fraction of jammed backbones (packings with rattlers excluded). The backbone packing fraction is about 0.624 over the majority of the α-x plane, even when large numbers of small spheres are present in the backbone. Over the (relatively small) area of the α-x plane where the backbone is not roughly constant, we find that backbone packing fractions range from about 0.606 to 0.829, with the volume of rattler spheres comprising between 1.6% and 26.9% of total sphere volume. To generate isostatic strictly jammed packings, we use an implementation of the Torquato-Jiao sequential linear programming algorithm [Phys. Rev. E 82, 061302 (2010)], which is an efficient producer of inherent structures (mechanically stable configurations at the local maxima in the density landscape). The identification and explicit construction of binary packings

  20. A study on the Noise Radiation of a Power Pack for Construction Equipment

    Directory of Open Access Journals (Sweden)

    Chae-Sil Kim

    2016-09-01

    Full Text Available The Power Pack of these machines is composed of an engine, fuel tank and oil tank. Energy is transferred to the Casing Rotor through the engine inside the Power Pack. In this study, the generated noise of a Power Pack was predicted, to provide suggestions on how to improve the noise level. First, we constructed a 3D model of the Power Pack. A finite element analysis was performed using ANSYS. We then analysed the Power Pack through the generated acoustic analysis. Finally, we suggest a way to reduce the noise during the design stage using the analysis results