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Sample records for castor oil

  1. 21 CFR 172.876 - Castor oil.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Castor oil. 172.876 Section 172.876 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN... Multipurpose Additives § 172.876 Castor oil. The food additive castor oil may be safely used in accordance...

  2. Castor oil: Biosynthesis and Uses

    Science.gov (United States)

    Castor oil is unique among commodity oils in its fatty acid composition, which consists of 90% ricinoleate, (12-hydroxy-octadec-cis 9-enoate). The mid-chain hydroxyl group imparts physical and chemical properties that make it useful in many industrial applications. Among its uses are lithium grease,...

  3. Contact Allergy to Castor Oil, but Not to Castor Wax

    Directory of Open Access Journals (Sweden)

    Michel Verheyden

    2017-01-01

    Full Text Available Ricinus communis (castor seed oil (CAS 8001-79-4, a vegetable oil extracted from the seeds of Ricinus communis, is widely used in cosmetics and pharmaceuticals, and may be a cause of allergic contact dermatitis from these products. We present two patients with allergic contact dermatitis from cosmetics containing castor oil, in whom a correct diagnosis was achieved by patch testing castor oil ‘as is’. PEGylated and/or hydrogenated derivatives (the latter formerly also available from patch test allergen suppliers and/or cosmetics containing these specific derivatives did not result in contact allergy or allergic contact dermatitis. This observation might be relevant for the manufacturing of cosmetics and pharmaceuticals. In the future, further research into the allergenicity of castor oil and its numerous derivatives, and their optimal patch test concentrations, may be desirable.

  4. Castor Oil-Based Biodegradable Polyesters.

    Science.gov (United States)

    Kunduru, Konda Reddy; Basu, Arijit; Haim Zada, Moran; Domb, Abraham J

    2015-09-14

    This Review compiles the synthesis, physical properties, and biomedical applications for the polyesters based on castor oil and ricinoleic acid. Castor oil has been known for its medicinal value since ancient times. It contains ∼90% ricinoleic acid, which enables direct chemical transformation into polyesters without interference of other fatty acids. The presence of ricinoleic acid (hydroxyl containing fatty acid) enables synthesis of various polyester/anhydrides. In addition, castor oil contains a cis-double bond that can be hydrogenated, oxidized, halogenated, and polymerized. Castor oil is obtained pure in large quantities from natural sources; it is safe and biocompatible.

  5. Biodegradable foam plastics based on castor oil.

    Science.gov (United States)

    Wang, Hong Juan; Rong, Min Zhi; Zhang, Ming Qiu; Hu, Jing; Chen, Hui Wen; Czigány, Tibor

    2008-02-01

    In this work, a simple but effective approach was proposed for preparing biodegradable plastic foams with a high content of castor oil. First of all, castor oil reacted with maleic anhydride to produce maleated castor oil (MACO) without the aid of any catalyst. Then plastic foams were synthesized through free radical initiated copolymerization between MACO and diluent monomer styrene. With changes in MACO/St ratio and species of curing initiator, mechanical properties of MACO foams can be easily adjusted. In this way, biofoams with comparable compressive stress at 25% strain as commercial polyurethane (PU) foams were prepared, while the content of castor oil can be as high as 61 wt %. The soil burial tests further proved that the castor oil based foams kept the biodegradability of renewable resources despite the fact that some petrol-based components were introduced.

  6. Thermoanalytical characterization of castor oil biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Conceicao, Marta M.; Fernandes, Valter J. [Universidade Federal do Rio Grande do Norte, Departamento de Quimica, Laboratorio de Combustiveis, Natal, RN, Lagoa Nova, CEP 59072970 (Brazil); Candeia, Roberlucia A.; Bezerra, Aline F.; Souza, Antonio G. [Universidade Federal da Paraiba, Departamento Quimica, Joao Pessoa, PB (Brazil); Silva, Fernando C. [Universidade Federal do Maranhao, Sao Luis, Maranhao (Brazil)

    2007-06-15

    The castor oil seed has 47-49% of oil. Biodiesel obtained from castor oil has a lower cost compared to the ones obtained from other oils, as due its solvability in alcohol transesterification occurs without heating. The use of biodiesel will allow a reduction on the consumption of petroleum-derived fuels minimizing the harmful effects on the environment. This work wants to provide a thermoanalytical and physical-chemistry characterization of castor oil and biodiesel. Biodiesel was obtained with methyl alcohol and characterized through several techniques. Gas chromatography indicated methyl ester content of 97.7%. The volatilization of biodiesel starts and finishes under inferior temperatures than the beginning and final volatilization temperatures of castor oil. Biodiesel data are very close to the volatilization temperatures of conventional diesel. (author)

  7. Phenylpropanoid esters of lesquerella and castor oil

    Science.gov (United States)

    Lesquerella (LO) and castor oil (CO) were esterified at the secondary hydroxyl groups of their 14-hydroxyeicos-cis-11-enoic fatty acids and 12-hydroxyoctadec-cis-9-enoic fatty acids, respectively, with 4-acetoxy-3-methoxycinnamic acid (acetoxyferulic acid). The unconventional esterifications were co...

  8. Tough blends of polylactide and castor oil.

    Science.gov (United States)

    Robertson, Megan L; Paxton, Jessica M; Hillmyer, Marc A

    2011-09-01

    Poly(l-lactide) (PLLA) is a renewable resource polymer derived from plant sugars with several commercial applications. Broader implementation of the material is limited due to its inherent brittleness. We show that the addition of 5 wt % castor oil to PLLA significantly enhances the overall tensile toughness with minimal reductions in the modulus and no plasticization of the PLLA matrix. In addition, we used poly(ricinoleic acid)-PLLA diblock copolymers, synthesized entirely from renewable resources, as compatibilizers for the PLLA/castor oil blends. Ricinoleic acid, the majority fatty acid comprising castor oil, was polymerized through a lipase-catalyzed condensation reaction. The resulting polymers contained a hydroxyl end-group that was subsequently used to initiate the ring-opening polymerization of l-lactide. The binary PLLA/castor oil blend exhibited a tensile toughness seven times greater than neat PLLA. The addition of block copolymer allowed for control over the morphology of the blends, and even further improvement in the tensile toughness was realized-an order of magnitude larger than that of neat PLLA.

  9. Tough Blends of Polylactide and Castor Oil

    Energy Technology Data Exchange (ETDEWEB)

    Robertson, Megan L.; Paxton, Jessica M.; Hillmyer, Marc A. (UMM)

    2012-10-10

    Poly(l-lactide) (PLLA) is a renewable resource polymer derived from plant sugars with several commercial applications. Broader implementation of the material is limited due to its inherent brittleness. We show that the addition of 5 wt % castor oil to PLLA significantly enhances the overall tensile toughness with minimal reductions in the modulus and no plasticization of the PLLA matrix. In addition, we used poly(ricinoleic acid)-PLLA diblock copolymers, synthesized entirely from renewable resources, as compatibilizers for the PLLA/castor oil blends. Ricinoleic acid, the majority fatty acid comprising castor oil, was polymerized through a lipase-catalyzed condensation reaction. The resulting polymers contained a hydroxyl end-group that was subsequently used to initiate the ring-opening polymerization of L-lactide. The binary PLLA/castor oil blend exhibited a tensile toughness seven times greater than neat PLLA. The addition of block copolymer allowed for control over the morphology of the blends, and even further improvement in the tensile toughness was realized - an order of magnitude larger than that of neat PLLA.

  10. Synthesis of branched naphthoquinones from castor oil

    Directory of Open Access Journals (Sweden)

    Adriano Olímpio da Silva

    2012-06-01

    Full Text Available The naphthoquinones are cyclic aromatic α,β-dienonas with a basic framework derived from naphthalene. They are also found in many higher plants, algae, fungi and as the product of the  metabolism  of some  bacteria  having large biologica activity described in the literature such as antibacterial, anti-inflammatory, antitumor, anticancer and trypanocidal [1-3]. Castor oil is an abundant raw material in Brazil of great versatility and, it is present in biodiesel production, surfactants, cosmetics and others. Considering the importance of naphthoquinones and, the availability of the ricinoleic acid from castor oil, the aim of this study was the preparation of new branched naphthoquinones in order to test their trypanocidal activity. Castor oil was submitted to saponification with sodium hydroxide, ethanol and water under reflux for 6 h. We then carried out an acid hydrolysis with hydrochloric acid and the formed ricinoleic acid was extracted with ethyl acetate. Following, through Kochi-Anderson addition reaction it was performed the alkylation of a naphthoquinone 1 and 2, using ammonium persulfate, silver nitrate, acetonitrile and water, under heating at 70-80 ° C during 3 h, to give the branched naphthoquinones 4 and 5 (scheme 1. The naphthoquinone 3 will be similarly submitted to this procedure. The naphthoquinones 4 and 5 were purified by column chromatography on sílica gel using hexane as the eluent. The compounds were characterized by mass spectrometry and 1H and 13CNMR spectroscopy.

  11. Production of Detergent from Castor Oil

    Directory of Open Access Journals (Sweden)

    Abubakar Garba ISAH

    2006-07-01

    Full Text Available This research work was carried out with the objective of extraction of oil from castor seeds and its utilization to produce a synthetic detergent. Solvent extraction method was employed in extracting the oil and the total percent oil yield was found to be 23.8%. The experimentally determined saponification value of the oil was 183.7275mgKOH/g of oil. The detergent efficiency, determined as a measure of the foamability of the detergent was found to be 2.6cm. The pH tests revealed mildly basic properties. The color, scent and efficiency of the detergent were improved with the addition of bleaching agent, perfume and foaming agents respectively.

  12. 21 CFR 178.3280 - Castor oil, hydrogenated.

    Science.gov (United States)

    2010-04-01

    ... FOR HUMAN CONSUMPTION (CONTINUED) INDIRECT FOOD ADDITIVES: ADJUVANTS, PRODUCTION AIDS, AND SANITIZERS Certain Adjuvants and Production Aids § 178.3280 Castor oil, hydrogenated. Hydrogenated castor oil may be safely used in the manufacture of articles or components of articles intended for use in contact...

  13. Renewable polyethylene mimics derived from castor oil.

    Science.gov (United States)

    Türünç, Oĝuz; Montero de Espinosa, Lucas; Meier, Michael A R

    2011-09-01

    An increasing number of reports on the syntheses of carbohydrate- and plant oil-based polymers has been published in ongoing efforts to produce plastic materials from renewable resources. Although many of these polymers are biodegradable and this is a desirable property for certain applications, in some cases non-degradable polymers are needed for long-term use purposes. Polyolefins are one of the most important classes of materials that have already taken their places in our daily life. On the other hand, their production relies on fossil resources. Therefore, within this contribution, we discuss synthetic routes toward a number of polyethylene mimics derived from fatty acids via thiol-ene and ADMET polymerization reactions in order to establish more sustainable routes toward this important class of polymers. Two different diene monomers were thus prepared from castor oil derived platform chemicals, their polymerization via the two mentioned routes was optimized and compared to each other, and their thermal properties were investigated.

  14. Experimental Study of Castor Oil Based Lubricant for Automotive Applications

    Directory of Open Access Journals (Sweden)

    Amit Suhane,

    2014-01-01

    Full Text Available Vegetable oils due to their better natural propertiescan be used as an alternative to reduce the dependency on the conventional lubricants. With the depletion of conventional resources at faster pace, need of hour is to approach the safer alternatives for ensuring the availability of such resources for longer periods with lesser harm to the mankind and sorroundings.This workevaluates the prospects of Castor oil based lubricant for automotive applications in contrast to the available commercial servo gear oil. Experimentation has been performed on four ball tester set up.Material used is carbon steel balls. Refined castor and mahua oils are blended in fixed ratios and subjected to friction and wear tests. Experimentation reveals that castor mahua oil blend possess immense potential in contrast to servo gear oil due to good wear reducing traits apart from environmental benefits.

  15. Heterogeneous catalysis afford biodiesel of babassu, castor oil and blends

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Lee M.G. de; Abreu, Wiury C. de; Silva, Maria das Gracas de O. e; Matos, Jose Milton E. de; Moura, Carla V.R. de; Moura, Edmilson M. de, E-mail: mmoura@ufpi.edu.br [Universidade Federal do Piaui (UFPI), Teresina, PI (Brazil). Departamento de Quimica; Lima, Jose Renato de O.; Oliveira, Jose Eduardo de [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP/IQ/CEMPEQC), Araraquara, SP (Brazil). Instituto de Quimica. Centro de Monitoramento e Pesquisa da Qualidade de Combustiveis, Biocombustiveis, Petroleo e Derivados

    2013-04-15

    This work describes the preparation of babassu, castor oil biodiesel and mixtures in various proportions of these oils, using alkaline compounds of strontium (SrCO{sub 3} + SrO + Sr (OH){sub 2}) as heterogeneous catalysts. The mixture of oils of these oleaginous sources was used in the production of biodiesel with quality parameters that meet current legislation. The catalyst was characterized by X-ray diffractometry (XDR), physisorption of gas (BET method), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDX) and Fourier transform infrared spectroscopy (FTIR). The viscometric technique was used to monitor the optimization.The transesterification reactions performed using strontium compounds reached conversion rates of 97.2% babassu biodiesel (BB), 96.4% castor oil biodiesel (COB) and 95.3% Babassu/Castor Oil Biodiesel 4:1 (BBCO41). (author)

  16. 21 CFR 524.2620 - Liquid crystalline trypsin, Peru balsam, castor oil.

    Science.gov (United States)

    2010-04-01

    ... NEW ANIMAL DRUGS § 524.2620 Liquid crystalline trypsin, Peru balsam, castor oil. (a)(1) Specifications..., and 788.0 milligrams of castor oil. (2) Sponsor. See No. 051079 in § 510.600(c) of this chapter. (b)(1... balsam, and 800 milligrams of castor oil. (2) Sponsor. See No. 017135 in § 510.600(c) of this chapter....

  17. Extraction, Characterization and Modification of Castor Seed Oil

    Directory of Open Access Journals (Sweden)

    A. D. MOHAMMED

    2006-01-01

    Full Text Available This paper carried out experimental study, through extraction and characterization of both crude and refined castor oil. Normal hexane was used as solvent for the extraction process. The oil produced was refined through degumming, neutralization and bleaching process using local adsorbent (activated clay. The characterization analysis revealed that tested parameters, which include specific gravity, refractive index, acid value, saponification value and iodine value for both crude and refined castor oil produced, were within the ASTM standard specifications. In fact the iodine value obtained (84.8 for the refined oil indicates that the oil could certainly be used as lubricant, hydraulic break fluid and protecting coatings. The oil was modified via sulphation method to produce Turkey – red oil that was tested on wooden material, paper and cloth. The test revealed that the Turkey – red oil produced is suitable to be used as a good dying agent and polish.

  18. Castor Oil: Properties, Uses, and Optimization of Processing Parameters in Commercial Production

    Science.gov (United States)

    Patel, Vinay R.; Dumancas, Gerard G.; Kasi Viswanath, Lakshmi C.; Maples, Randall; Subong, Bryan John J.

    2016-01-01

    Castor oil, produced from castor beans, has long been considered to be of important commercial value primarily for the manufacturing of soaps, lubricants, and coatings, among others. Global castor oil production is concentrated primarily in a small geographic region of Gujarat in Western India. This region is favorable due to its labor-intensive cultivation method and subtropical climate conditions. Entrepreneurs and castor processors in the United States and South America also cultivate castor beans but are faced with the challenge of achieving high castor oil production efficiency, as well as obtaining the desired oil quality. In this manuscript, we provide a detailed analysis of novel processing methods involved in castor oil production. We discuss novel processing methods by explaining specific processing parameters involved in castor oil production. PMID:27656091

  19. Castor Oil: Properties, Uses, and Optimization of Processing Parameters in Commercial Production.

    Science.gov (United States)

    Patel, Vinay R; Dumancas, Gerard G; Kasi Viswanath, Lakshmi C; Maples, Randall; Subong, Bryan John J

    2016-01-01

    Castor oil, produced from castor beans, has long been considered to be of important commercial value primarily for the manufacturing of soaps, lubricants, and coatings, among others. Global castor oil production is concentrated primarily in a small geographic region of Gujarat in Western India. This region is favorable due to its labor-intensive cultivation method and subtropical climate conditions. Entrepreneurs and castor processors in the United States and South America also cultivate castor beans but are faced with the challenge of achieving high castor oil production efficiency, as well as obtaining the desired oil quality. In this manuscript, we provide a detailed analysis of novel processing methods involved in castor oil production. We discuss novel processing methods by explaining specific processing parameters involved in castor oil production.

  20. Multisystem organ failure after large volume injection of castor oil.

    Science.gov (United States)

    Smith, Silas W; Graber, Nathan M; Johnson, Rudolph C; Barr, John R; Hoffman, Robert S; Nelson, Lewis S

    2009-01-01

    We report a case of multisystem organ failure after large volume subcutaneous injection of castor oil for cosmetic enhancement. An unlicensed practitioner injected 500 mL of castor oil bilaterally to the hips and buttocks of a 28-year-old male to female transsexual. Immediate local pain and erythema were followed by abdominal and chest pain, emesis, headache, hematuria, jaundice, and tinnitus. She presented to an emergency department 12 hours postinjection. Persistently hemolyzed blood samples complicated preliminary laboratory analysis. She rapidly deteriorated despite treatment and developed fever, tachycardia, hemolysis, thrombocytopenia, hepatitis, respiratory distress, and anuric renal failure. An infectious diseases evaluation was negative. After intensive supportive care, including mechanical ventilation and hemodialysis, she was discharged 11 days later, requiring dialysis for an additional 1.5 months. Castor oil absorption was inferred from recovery of the Ricinus communis biomarker, ricinine, in the patient's urine (41 ng/mL). Clinicians should anticipate multiple complications after unapproved methods of cosmetic enhancement.

  1. Laser-fabricated castor oil-capped silver nanoparticles.

    Science.gov (United States)

    Zamiri, Reza; Zakaria, Azmi; Abbastabar, Hossein; Darroudi, Majid; Husin, Mohd Shahril; Mahdi, Mohd Adzir

    2011-01-01

    Silver nanoparticles were fabricated by ablation of a pure silver plate immersed in castor oil. A Nd:YAG-pulsed Q-switch laser with 1064-nm wavelength and 10-Hz frequency was used to ablate the plate for 10 minutes. The sample was characterized by ultraviolet-visible, atomic absorption, Fourier transform-infrared spectroscopies, and transmission electron microscopy. The results of the fabricated sample showed that the nanoparticles in castor oil were about 5-nm in diameter, well dispersed, and showed stability for a long period of time.

  2. Large nonlocal nonlinear optical response of castor oil

    Science.gov (United States)

    Souza, Rogério F.; Alencar, Márcio A. R. C.; Meneghetti, Mario R.; Hickmann, Jandir M.

    2009-09-01

    The nonlocal nonlinearity of castor oil was investigated using the Z-scan technique in the CW regime at 514 nm and in femtosecond regime at 810 nm. Large negative nonlinear refractive indexes of thermal origin, thermo-optical coefficients and degree of nonlocality were obtained for both laser excitation wavelengths. The results indicate that the electronic part of the nonlinear refractive index and nonlinear absorption were negligible. Our results suggest that castor oil is promising candidate as a nonlinear medium for several nonlocal optical applications, such as in spatial soliton propagation, as well as a dispersant agent in the measurement of absorptive properties of nanoparticles.

  3. Synthesis of carbon nanotubes using natural carbon precursor: Castor oil

    Science.gov (United States)

    Raziah, A. Z.; Junizah, A. R.; Saifuddin, N.

    2012-09-01

    Castor oil has long been an article of commerce due to its versatility as it is widely used as a starting material for many industrial chemical products because of its unique structure. In this study, carbon nanotubes has been synthesized by thermal decomposition of castor oil in nitrogen atmosphere at 300-400δC using custom-made microwave processing unit. The precursor material was catalyzed by iron clusters originating from the addition of ferrocene. The morphology and characterization of the CNTs were studied and discussed by transmission electron microscopy (TEM).

  4. Evaluation of castor oil samples for potential toxin contamination

    Science.gov (United States)

    Castor oil and its derivatives are widely used as a chemical feedstock for production of lubricants and greases, and for engineering plastics, plasticizers and surfactants. They also have wide application in consumer goods such as lipstick, deodorants and medicinal products. Due to concerns about th...

  5. Preparation and research on properties of castor oil as a diesel fuel additive

    OpenAIRE

    Nurbakhit Imankulov

    2012-01-01

    The research shows an opportunity of preparing biodiesel fuel on the basis of local diesel fuel and the bioadditive - castor oil. Limiting optimum concentration of introduction of the bioadditive equal was established as 5% mass ratio. The castor oil released from seeds of Palma Christi grown on experimental field. All physical and chemical characteristics of the oil including IR-spectra were determined. Operating conditions of castor oil introduction (temperature, solubility, concentra-tion,...

  6. Castor and jatropha oils: production strategies – A review

    Directory of Open Access Journals (Sweden)

    Lago Regina C.A.

    2009-07-01

    Full Text Available The Brazilian bioenergy matrix is based on four platforms: ethanol, energy forests, residues and co-products and biodiesel. The food-energy dichotomy in the use of edible oils is one factor which has stimulated the search for non-edible oleaginous energy crops, such as many native palms. By the year 2000 Brazil had an annual deficit of 80 thousand tons of castor oil, making necessary to import oil from China and India. After a strong debate the National Program on Biodiesel Production (NPBP was launched by December 2004. After an initial excessive enthusiasm, small producers being focused in the program, a more mature and realistic planning is undertaken. Production in semi arid lands is being stimulated, mainly castor (Ricinus communis and Jatropha (Jatropha curcas. Apart from belonging to the same botanical family (Euphorbiaceae, both plants are well resistant to poor soils. Castor plant is well adapted to practically the whole country, except for some extreme areas (too low water availability or too much rain. Castor keeps being an alternative for the semi arid region but much more technology is requested to make it largely exploited. Following the petroleum crisis of 1980’s an ambitious research program on Jatropha curcas was initiated, later on discontinued and presently retaken by Embrapa and some Universities. Progress is slower than in the case of Ricinus communis. The first agronomical observations confirmed low productivity, problems with pests and diseases, high harvesting costs etc. Some strategic factors should be considered for the production of castor and Jatropha oils: 1. Production of raw materials; 2. Production of oils; 3. Detoxification and value aggregation to the extraction cakes and residues. Regarding raw material production, it is necessary a strong, long term research program on genetic breeding (short cycle varieties, with high productivity and allowing a sole harvesting, soil fertility, pest control, domestication

  7. CASTOR SEED BIO -TRANSFORMER OIL AS AN ALTERNATIVE TO CONVENTIONAL TRANSFORMER OIL

    OpenAIRE

    Egbuna, S.O.*, Ude, O.C., Ude, C.N.

    2016-01-01

    In search of solution to the harmful ecological problems due to toxicity and non-biodegradability posed by conventional transformer insulation oil (mineral oil), the production of transformer oil from castor seed oil (vegetable oil) was carried out. The oil was extracted using N-hexane and was refined. The transformer oil was produced by trans-esterification and was characterized using American Society for Testing Material (ASTM) standard test. The solvent employed gave good yield of oil from...

  8. Measurement of quadratic electrogyration effect in castor oil

    Science.gov (United States)

    Izdebski, Marek; Ledzion, Rafał; Górski, Piotr

    2015-07-01

    This work presents a detailed analysis of electrogyration measurement in liquids with the usage of an optical polarimetric technique. Theoretical analysis of the optical response to an applied electric field is illustrated by experimental data for castor oil which exhibits natural optical activity, quadratic electro-optic effect and quadratic electrogyration effect. Moreover, the experimental data show that interaction of the oil with a pair of flat electrodes induces a significant dichroism and natural linear birefringence. The combination of these effects occurring at the same time complicates the procedure of measurements. It has been found that a single measurement is insufficient to separate the contribution of the electrogyration effect, but it is possible on the basis of several measurements performed with various orientations of the polarizer and the analyser. The obtained average values of the quadratic electrogyration coefficient β13 in castor oil at room temperature are from - 0.92 ×10-22 to - 1.44 ×10-22m2V-2 depending on the origin of the oil. Although this study is focused on measurements in castor oil, the presented analysis is much more general.

  9. Physicochemical and sensory characteristics of milk from goats supplemented with castor or licuri oil.

    Science.gov (United States)

    Pereira, R A G; Oliveira, C J B; Medeiros, A N; Costa, R G; Bomfim, M A D; Queiroga, R C R E

    2010-02-01

    The purpose of this study was to evaluate the influence of castor and licuri palm oils supplemented to milking goats on the physical, chemical, and sensory characteristics of milk. A double Latin square experimental design (5x5) using 10 confined crossbred Moxotó-Alpine goats was performed according to the following treatments: nonsupplemented (control), 3% castor oil, 5% castor oil, 3% licuri oil, and 5% licuri oil. Oils in each treatment were supplemented in the dry matter. Castor oil supplementation reduced the fat content and increased the lactose and density of milk. Considering the sensory analysis, a lower acceptability was observed for milk from goats supplemented with castor oil. On the other hand, licuri oil supplementation led to higher acceptability scores for flavor and odor of goat milk.

  10. Development of Castor-Oil-Resistant Polyurethane Sonar Encapsulants.

    Science.gov (United States)

    2014-09-26

    Z) 2-ethyl-i,3-hexanediol Union Carbide 14.70 N,N-(2- hydroxypropyl )-aniline Upjohn Co. 36.75 Diamine Component (See pages 4 & 5) 22.05 N,N,N’,N...Carbide 6.02 N,N-(2- hydroxypropyl )aniline Upjohn Co. 18.07 Diamine component (See pages 4 & 5) 21.68 Castor Oil Caschem 24.09 2000 PPG diol Olin Corp

  11. Oil content among the diverse castor genetic resources in the U.S. collection

    Science.gov (United States)

    Castor (Ricinus communis L.) contains oil used for medicine, as an ingredient in shampoo, soap, hand lotion, high-speed lubricants, and as a coating material. Due to its high oil content, oil derived from castor seeds is currently proposed to be used as a feedstock for biodiesel production. The USDA...

  12. Low-modulus PMMA bone cement modified with castor oil.

    Science.gov (United States)

    López, Alejandro; Hoess, Andreas; Thersleff, Thomas; Ott, Marjam; Engqvist, Håkan; Persson, Cecilia

    2011-01-01

    Some of the current clinical and biomechanical data suggest that vertebroplasty causes the development of adjacent vertebral fractures shortly after augmentation. These findings have been attributed to high injection volumes as well as high Young's moduli of PMMA bone cements compared to that of the osteoporotic cancellous bone. The aim of this study was to evaluate the use of castor oil as a plasticizer for PMMA bone cements. The Young's modulus, yield strength, maximum polymerization temperature, doughing time, setting time and the complex viscosity curves during curing, were determined. The cytotoxicity of the materials extracts was assessed on cells of an osteoblast-like cell line. The addition of up to 12 wt% castor oil decreased yield strength from 88 to 15 MPa, Young's modulus from 1500 to 446 MPa and maximum polymerization temperature from 41.3 to 25.6°C, without affecting the setting time. However, castor oil seemed to interfere with the polymerization reaction, giving a negative effect on cell viability in a worst-case scenario.

  13. Synthesis and characterization of castor oil-based polymeric surfactants

    Directory of Open Access Journals (Sweden)

    Xujuan HUANG,He LIU,Shibin SHANG,Zhaosheng CAI,Jie SONG,Zhanqian SONG

    2016-03-01

    Full Text Available Dehydrated castor oil was epoxidized using phosphoric acid as a catalyst and acetic acid peroxide as an oxidant to produce epoxidized castor oil (ECO. Ring-opening polymerization with stannic chloride was used to produce polymerized ECO (PECO, and sodium hydroxide used to give hydrolyzed PECO (HPECO. The HPECO was characterized by Fourier transform infrared, 1H and 13C nuclear magnetic resonance spectroscopies, gel permeation chromatography, and differential scanning calorimetry. The weight-average molecular weight of soluble PECO and HPECO were 5026 and 2274 g·mol-1, respectively. PECO and HPECO exhibited glass transition. Through neutralizing the carboxylic acid of HPECO with different counterions, castor oil-based polymeric surfactants (HPECO-M, where M= Na+, K+ or triethanolamine ion exhibited high efficiency to reduce the surface tension of water. The critical micelle concentration (CMC values of HPECO-M ranged from 0.042 to 0.098 g·L-1 and the minimum equilibrium surface tensions at CMC (gcmc of HPECO-M ranged from 25.6 to 30.0 mN·m-1. The water-hexadecane interfacial energy was calculated from measured surface tension using harmonic and geometric mean methods. Measured values of water-hexadecane interfacial tension agreed well with those calculated using the harmonic and geometric mean methods.

  14. Trial of an experimental castor oil solution for cleaning dentures.

    Science.gov (United States)

    Andrade, Ingrid Machado de; Andrade, Kelly Machado de; Pisani, Marina Xavier; Silva-Lovato, Cláudia Helena; de Souza, Raphael Freitas; Paranhos, Helena de Freitas Oliveira

    2014-01-01

    Denture hygiene is essential because denture biofilm is involved in oral infections and systemic diseases. Although there are chemical agents available on the market, none of them have ideal properties and research on such products is still necessary. The aim of this study was to evaluate the efficacy of a castor bean (Ricinus communis)-based solution for removing denture biofilm, compared to two traditional products (sodium hypochlorite and alkaline peroxide). Fifty maxillary complete denture wearers were instructed to brush their dentures after meals and to immerse their dentures once a day in the following solutions: Saline (20 min; control), Polident alkaline peroxide (3 min), NaOCl (20 min) and 2% castor oil solution (20 min). Participants used each solution for a period of 7 consecutive days, according to a random sequence. After each period, the internal surfaces of maxillary complete dentures were stained with a disclosing solution (1% neutral red), photographed and the disclosed biofilm was quantified with the aid of specific software. The influence of treatments on results was verified by the Friedman test (α=0.05). Tested solutions presented significant difference (Fr=51.67; poil presented intermediate results (median: 1.0% and 1.5%, respectively). It can be concluded that the castor oil solution tested in this study was comparable to alkaline peroxide in terms of efficiency in denture biofilm removal.

  15. Biodiesel production from castor oil in Brazil: A difficult reality

    Energy Technology Data Exchange (ETDEWEB)

    Silva Cesar, Aldara da, E-mail: aldara@dep.ufscar.b [Federal University of Sao Carlos, Gepai - Grupo de Estudos e Pesquisas Agroindustriais, Departamento de Engenharia de Producao - UFSCar, Rodovia Washington Luis, km 235 - CEP 13565-905 - Sao Carlos - SP (Brazil); Otavio Batalha, Mario [Federal University of Sao Carlos, Gepai - Grupo de Estudos e Pesquisas Agroindustriais, Departamento de Engenharia de Producao - UFSCar, Rodovia Washington Luis, km 235 - CEP 13565-905 - Sao Carlos - SP (Brazil)

    2010-08-15

    The Brazilian National Program for Production and Use of Biodiesel (PNPB in Portuguese) has created a huge demand for biodiesel in Brazil. The PNPB is strongly based on social development through the inclusion of family farmers in projects integrated with biodiesel power plants. Among the various oilseeds, castor bean (Ricinus communis L.) was identified as the ideal one to promote social development in the semi-arid region. However, although promising, the mechanisms of the federal program are still insufficient to promote the effective participation of family farmers. This research shows that companies are facing huge problems in implementing contracts with family farmers. It describes and analyzes the functioning dynamics of this agro-production chain. This paper addresses the identification and the discussion of these obstacles, in order to increase the competitiveness of the biodiesel agribusiness chain, based on castor oil social projects in Brazil.

  16. Biodiesel production from castor oil in Brazil. A difficult reality

    Energy Technology Data Exchange (ETDEWEB)

    Silva Cesar, Aldara da; Otavio Batalha, Mario [Federal University of Sao Carlos, Gepai - Grupo de Estudos e Pesquisas Agroindustriais, Departamento de Engenharia de Producao - UFSCar, Rodovia Washington Luis, km 235 - CEP 13565-905 - Sao Carlos (Brazil)

    2010-08-15

    The Brazilian National Program for Production and Use of Biodiesel (PNPB in Portuguese) has created a huge demand for biodiesel in Brazil. The PNPB is strongly based on social development through the inclusion of family farmers in projects integrated with biodiesel power plants. Among the various oilseeds, castor bean (Ricinus communis L.) was identified as the ideal one to promote social development in the semi-arid region. However, although promising, the mechanisms of the federal program are still insufficient to promote the effective participation of family farmers. This research shows that companies are facing huge problems in implementing contracts with family farmers. It describes and analyzes the functioning dynamics of this agro-production chain. This paper addresses the identification and the discussion of these obstacles, in order to increase the competitiveness of the biodiesel agribusiness chain, based on castor oil social projects in Brazil. (author)

  17. Mass spectrometry of the lithium adducts of diacylglycerols containing hydroxy FA in castor oil and two normal FA

    Science.gov (United States)

    Castor oil can be used in industry. The molecular species of triacylglycerols containing hydroxy fatty acids (FA) in castor oil have been identified. We report here the identification of twelve diacylglycerols (DAG) containing hydroxy FA in castor oil using positive ion electrospray ionization mass ...

  18. Castor oil induces laxation and uterus contraction via ricinoleic acid activating prostaglandin EP3 receptors.

    Science.gov (United States)

    Tunaru, Sorin; Althoff, Till F; Nüsing, Rolf M; Diener, Martin; Offermanns, Stefan

    2012-06-01

    Castor oil is one of the oldest drugs. When given orally, it has a laxative effect and induces labor in pregnant females. The effects of castor oil are mediated by ricinoleic acid, a hydroxylated fatty acid released from castor oil by intestinal lipases. Despite the wide-spread use of castor oil in conventional and folk medicine, the molecular mechanism by which ricinoleic acid acts remains unknown. Here we show that the EP(3) prostanoid receptor is specifically activated by ricinoleic acid and that it mediates the pharmacological effects of castor oil. In mice lacking EP(3) receptors, the laxative effect and the uterus contraction induced via ricinoleic acid are absent. Although a conditional deletion of the EP(3) receptor gene in intestinal epithelial cells did not affect castor oil-induced diarrhea, mice lacking EP(3) receptors only in smooth-muscle cells were unresponsive to this drug. Thus, the castor oil metabolite ricinoleic acid activates intestinal and uterine smooth-muscle cells via EP(3) prostanoid receptors. These findings identify the cellular and molecular mechanism underlying the pharmacological effects of castor oil and indicate a role of the EP(3) receptor as a target to induce laxative effects.

  19. Comparison of lubricant properties of castor oil and commercial engine oil

    Directory of Open Access Journals (Sweden)

    Binfa Bongfa

    2015-06-01

    Full Text Available The tribological performance of crude Nigeria-based castor oil has been investigated and compared with that of a foreign, 20W-50 high quality crankcase oil, to see its suitability as base oil for lubricating oils in indigenous vehicle and power plants engines. The experiment was conducted using a four ball tester. The results showed that unrefined castor oil has superior friction reduction and load bearing capability in an unformulated form than the commercial oil; can compete favourably with the commercial oil in wear protection when formulated with suitable antiwear agent, hence can be a good alternative base stock for crankcase oils suitable for Nigeria serviced vehicles, and plants engines from tribological, environmental, and non-food competitive points of view.

  20. Characterization and Digestibility of Detoxified Castor Oil Meal for Japanese Quails

    Directory of Open Access Journals (Sweden)

    PA dos Santos

    2015-12-01

    Full Text Available ABSTRACT These experiments were performed to determine the chemical composition, coefficients of nutrient and energy metabolizability, amino acid composition, and cytotoxicity of different castor oil meals subjected to different detoxification processes and added to the diet of Japanese quails. In the trial, 180 46-d-old female Japanese quails were distributed according to a completely randomized design into five treatments and with replicates of six bird each. The treatments consisted of following detoxification methods of castor oil meal: Castor oil meal A (CMA - recovery in alcohol at 80 °C for 20 minutes and drying at 80 °C; castor oil meal B (CMB and C (CMC - recovery in alcohol at 80 °C for 6 minutes, neutralization with 5% NaOH, and drying under direct sunlight sun for two days (CMB or pelleted (CMC; castor oil meal D (CMD - recovery in alcohol at 110 °C for 15 minutes and drying at 110 °C. Castor oil meal was added replacing 20% of the reference diet. There was slight chemical composition variation (1.21% in crude protein, 6% in dry matter, 2.2% in ether extract and 64 kcal/kg in gross energy among the castor oil meals submitted to the different treatments. The castor oil meal submitted to treatment C showed the highest amino acid values. In the cytotoxicity test, treatment D presented lower ricin activity. Castor oil meals A, C, and D may be included in Japanese quail diets; however, castor oil meal D is recommended due to the simplicity its industrial process, its low toxicity, and metabolizability coefficients obtained.

  1. LDPE/PHB blends filled with castor oil cake

    Science.gov (United States)

    Burlein, Gustavo A.; Rocha, Marisa C. G.

    2015-05-01

    The response surface methodology (RSM) is a collection of mathematical techniques useful for developing, improving and optimizing process. In this study, RSM technique was applied to evaluate the effect of the components proportion on the mechanical properties of low density polyethylene (LDPE)/ poly (3-hydroxy-butyrate) (PHB) blends filled with castor oil cake (CC). The blends were prepared by melt mixing in a twin screw extruder. Low density polyethylene, poly (3-hydroxy-butyrate) and castor oil pressed cake were represented by the input variables designated as LDPE, PHB and CC, respectively. As it was desirable to consider the largest LDPE content in the ternary system, the components of the mixture were subjected to the following constraints: 0.7 ≤ LDPE ≤ 1.0, 0≤ PHB≤0.3 e 0 ≤ CC ≤0.3. The mechanical properties of the different mixtures were determined by conventional ASTM tests and were evaluated through analysis of variance performed by the Minitab software. Some polynomial equations were tested in order to describe the mechanical behavior of the samples. The quadratic model in pseudo components was selected for describing the tensile behavior because it was the most efficient from a statistical point of view (p-value ≤ 0.05; coefficient of determination (r2) close to 1 and variation inflation factor (VIF) values castor oil cake to LDPE. The morphological study of the materials obtained showed that LDPE/PHB blends are immiscible and form morphological structures with well distinguished phase boundaries between dispersed phase and matrix. Biodegradation was evaluated burying the samples in simulated soil for different periods of time. The LDPE/PHB/CC mixtures with higher content of PHB showed more pronounced degradation. Under the experimental conditions studied the LDPE/CC compositions presented no degradation. However, the loss of mass of the LDPE/PHB/CC mixtures was higher than the loss of mass of the corresponding LDPE/PHB binary blend. This

  2. Characterization of Novel Castor Oil-Based Polyurethane Polymer Electrolytes

    Directory of Open Access Journals (Sweden)

    Salmiah Ibrahim

    2015-04-01

    Full Text Available Castor oil-based polyurethane as a renewable resource polymer has been synthesized for application as a host in polymer electrolyte for electrochemical devices. The polyurethane was added with LiI and NaI in different wt% to form a film of polymer electrolytes. The films were characterized by using attenuated total reflectance-Fourier transform infrared spectroscopy, dynamic mechanical analysis, electrochemical impedance spectroscopy, linear sweep voltammetry and transference number measurement. The highest conductivity of 1.42 × 10−6 S cm−1 was achieved with the addition of 30 wt% LiI and 4.28 × 10−7 S·cm−1 upon addition of 30 wt% NaI at room temperature. The temperature dependence conductivity plot indicated that both systems obeyed Arrhenius law. The activation energy for the PU-LiI and PU-NaI systems were 0.13 and 0.22 eV. Glass transition temperature of the synthesized polyurethane decreased from −15.8 °C to ~ −26 to −28 °C upon salts addition. These characterizations exhibited the castor oil-based polyurethane polymer electrolytes have potential to be used as alternative membrane for electrochemical devices.

  3. Identification of diacylglycerol and triacylglycerol containing 11,12,13-trihydroxy-9,14-octadecadienoic acid in castor oil.

    Science.gov (United States)

    Lin, Jiann-Tsyh; Chen, Grace Q

    2011-02-28

    Castor oil has many industrial uses. Molecular species of acylglycerols containing monohydroxy, dihydroxy and trihydroxy fatty acids in castor oil have been reported. We report here the identification of acylglycerols containing a triOH18:2 fatty acid in castor oil. The structure of this novel fatty acid was proposed as 11,12,13-trihydroxy-9,14-octadecadienoic acid by the mass spectrometry of the lithiated adducts of acylglycerols in the HPLC fractions of castor oil. The fragmentation pathways of the lithiated adduct of 11,12,13-trihydroxy-9,14-octadecadienoic acid were proposed. We also proposed the biosynthetic pathways of polyhydroxy fatty acids in castor.

  4. Comparative clinical trial of castor oil and diclofenac sodium in patients with osteoarthritis.

    Science.gov (United States)

    Medhi, B; Kishore, K; Singh, U; Seth, S D

    2009-10-01

    A randomized, double-blind, comparative clinical study was conducted to compare the safety and efficacy of castor oil with diclofenac sodium in patients with knee osteoarthritis. Subjects with symptoms of knee osteoarthritis were given a castor oil capsule 0.9 mL (n = 50) thrice daily for 4 weeks or a capsule of diclofenac sodium (n = 50), 50 mg thrice daily for 4 weeks. The subjects completed an overall evaluation of symptom relief at 2 weeks and 4 weeks of completed treatment. The subjects were evaluated by clinical, routine laboratory and radiographic investigations for improvement of disease conditions and also for adverse drug reaction. On completion of 4 weeks treatment it was observed that both drugs were significantly effective in the treatment of knee osteoarthritis (p castor oil there were no adverse effects reported. The present study indicates that castor oil can be used as an effective therapy in primary knee osteoarthritis.

  5. Immobilization of Yarrowia lipolytica for aroma production from castor oil.

    Science.gov (United States)

    Braga, Adelaide; Belo, Isabel

    2013-04-01

    The main aim of this study was to compare different materials for Y. lipolytica immobilization that could be used in the production of γ-decalactone (a peach-like aroma) in order to prevent the toxic effect both of the substrate and the aroma upon the cells. Therefore, cells adsorption onto pieces of methyl polymethacrylate and of DupUM(®) was studied and further used in the biotransformation of castor oil into γ-decalactone. The highest aroma concentration was obtained with immobilized cells in DupUM(®), where reconsumption of the aroma by the cells was prevented, contrarily to what happens with free cells. This is a very promising result for γ-decalactone production, with potential to be used at an industrial level since the use of immobilized cells system will facilitate the conversion of a batch process into a continuous mode keeping high cell density and allowing easier recovery of metabolic products.

  6. Effects of Process Parameters on the Yield of oil from Castor Seed

    Directory of Open Access Journals (Sweden)

    Mbah, G.O

    2016-08-01

    Full Text Available The physicochemical properties of castor seed oil were evaluated in this work using standard analytical technique. The results showed the percentage (% moisture, crude lipid, crude protein, ash and carbohydrate contents of the castor seed as 0.700, 48.800, 7.200, 10.600, 31.615 respectively. The oil from the castor seed was odourless and yellowish at room temperature (30℃. The treatment combinations used (leaching time, leaching temperature and solvent: solute ratio showed significant differences (p< 0.05 in yield of castor oil seed flour with % oil yield of 35.52 – 53.90%. Lipid indices of the castor seed oil indicated the acid value (AV as 1.100mg NaOH/g of oil, free fatty acid (FFA as 0.550%, saponification value (SV as 188.300mgkOH/g of oil, iodine value (IV as 74.700I2/g of oil, peroxide value as 1.500ml/g of oil, and viscosity as 0.008. A standard statistical package Minitab version 16.0 program was used in the regression analysis and analysis of variance (ANOVA. The statistical software mentioned above was also used to generate various plots such as single effect, interaction plot, contour plot and 3D surface plot. The response or yield of oil extracted from castor flour was used to develop a mathematical model that correlates the yield of oil. The optimum condition obtained to give the highest yield of castor oil extraction are leaching time of 2hrs, leaching temperature of 50℃ and solute: solvent ratio of 0.05g/ml.

  7. Sorption of oil in the polyurethane from oil or castor oil; Sorcao de oleo no poliuretano derivado do petroleo ou do oleo de mamona

    Energy Technology Data Exchange (ETDEWEB)

    Florentino, Wagner M.; Goulart, Shane A.S.; Mulinari, Daniella R. [Centro Universitario de Volta Redonda (UniFOA), Volta Redonda, RJ (Brazil)], e-mail: wagner-can@hotmail.com

    2011-07-01

    The oil outpouring has caused serious environmental problems. To minimize this damage polyurethane foams have been used. In this work, the use of polyurethane from oil and castor oil, in different polyol/diisocyanate mass ratios, to absorb oil was evaluated. Results revealed that the proportion of polyol and diisocyanate influenced in the sorption capacity and the polyurethane from castor oil presented greater sorption capacity. Of this way, can say that the polyurethane from oil can be replaced by castor oil, contributing to sustainable development. (author)

  8. Surface Coating Studies of Polyurethane Derived from [(Alkyd-(Epoxy Resin Treated Castor Oil] Using Isophorene Diisocynate - II

    Directory of Open Access Journals (Sweden)

    Dinesh. P. Patel

    2012-07-01

    Full Text Available Castor oil (C was reacted with profitable epoxy resin (E (diglycidylether of bisphenol-A, DGEBF at a range of mole ratios. The consequential products (Castor oil- Epoxy resin were nominated as CEs. Isocyanate terminated castor oil Polyurethane (ICOPU was prepared by reaction of castor oil and various proportion of Isophoren diisocyanate. A commercial alkyd resin was blended with various proportions of CEs and ICOPU. A unique solvent system, which shows a one – phase clear solution and a clear coat of binder system, was used. All the blends were applied on mild steel panels and characterized for drying time, adhesion, flexibility, hardness, impact resistance and chemical resistance properties.

  9. Preparation and research on properties of castor oil as a diesel fuel additive

    Directory of Open Access Journals (Sweden)

    Nurbakhit Imankulov

    2012-06-01

    Full Text Available The research shows an opportunity of preparing biodiesel fuel on the basis of local diesel fuel and the bioadditive - castor oil. Limiting optimum concentration of introduction of the bioadditive equal was established as 5% mass ratio. The castor oil released from seeds of Palma Christi grown on experimental field. All physical and chemical characteristics of the oil including IR-spectra were determined. Operating conditions of castor oil introduction (temperature, solubility, concentra-tion, etc. were determined. The received biofuel was tested at oil refinery and its bench tests with a positive effect were also carried out. Technical requirements and technological regulation (temporary on manufacture of this biodiesel fuel were prepared.

  10. Optimization of biodiesel production from castor oil using response surface methodology.

    Science.gov (United States)

    Jeong, Gwi-Taek; Park, Don-Hee

    2009-05-01

    The short supply of edible vegetable oils is the limiting factor in the progression of biodiesel technology; thus, in this study, we applied response surface methodology in order to optimize the reaction factors for biodiesel synthesis from inedible castor oil. Specifically, we evaluated the effects of multiple parameters and their reciprocal interactions using a five-level three-factor design. In a total of 20 individual experiments, we optimized the reaction temperature, oil-to-methanol molar ratio, and quantity of catalyst. Our model equation predicted that the following conditions would generate the maximum quantity of castor biodiesel (92 wt.%): a 40-min reaction at 35.5 degrees C, with an oil-to-methanol molar ratio of 1:8.24, and a catalyst concentration of 1.45% of KOH by weight of castor oil. Subsequent empirical analyses of the biodiesel generated under the predicted conditions showed that the model equation accurately predicted castor biodiesel yields within the tested ranges. The biodiesel produced from castor oil satisfied the relevant quality standards without regard to viscosity and cold filter plugging point.

  11. The castor oil production in Brazil and the biodiesel program (Probiodiesel); A producao de mamona no Brasil e o Probiodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Cezar Menezes; Almeida Neto, Jose Adolfo de; Pires, Monica de Moura [Universidade Estadual de Santa Cruz, Ilheus, BA (Brazil). Grupo Bioenergia e Meio Ambiente]. E-mails: biocomb@uesc.br; Rocha, Pauletti Karllien [Secretaria de Ciencia, Tecnologia e Inovacao do Estado da Bahia (SECTI), Salvador, BA (Brazil)]. E-mail: pauletti@secti.ba.gov.br

    2004-07-01

    The objective of this work is to present a prospective study of the national production of biodiesel and castor oil and to determine the level of the public investment necessary to attain the proposed production. For replacement of 2% of the diesel internal consumption, 786 millions of liters of biodiesel will be necessary, based on the consumption of 2003. From this amount 293 millions of liters (40%) will be derived from the castor oil. Considering the castor oil agricultural productivity of 1.8 t/ha and the 45% industrial income in oil, it will be necessary the planting of 360.000 ha and investment amount of R$ 370 million. An idleness of 71% of the castor oil crushing industry has been detected, but this sector works with profit as function of castor oil price. An deficit of 55% between the castor oil planting area and the necessary one for biodiesel production was identified, considering that all the castor oil will be exclusively used for this purpose. With the proposed goals and without the necessary allocation of public resources for castor oil production, probably it will not be possible to expect that 1/5 of the biodiesel national production can come from the domestic agricultural planting.

  12. Lipase applications in oil hydrolysis with a case study on castor oil: a review.

    Science.gov (United States)

    Goswami, Debajyoti; Basu, Jayanta Kumar; De, Sirshendu

    2013-03-01

    Lipase (triacylglycerol acylhydrolase) is a unique enzyme which can catalyze various types of reactions such as hydrolysis, esterification, alcoholysis etc. In particular, hydrolysis of vegetable oil with lipase as a catalyst is widely studied. Free lipase, lipase immobilized on suitable support, lipase encapsulated in a reverse micelle and lipase immobilized on a suitable membrane to be used in membrane reactor are the most common ways of employing lipase in oil hydrolysis. Castor oil is a unique vegetable oil as it contains high amounts (90%) of a hydroxy monounsaturated fatty acid named ricinoleic acid. This industrially important acid can be obtained by hydrolysis of castor oil. Different conventional hydrolysis processes have certain disadvantages which can be avoided by a lipase-catalyzed process. The degree of hydrolysis varies widely for different lipases depending on the operating range of process variables such as temperature, pH and enzyme loading. Immobilization of lipase on a suitable support can enhance hydrolysis by suppressing thermal inactivation and estolide formation. The presence of metal ions also affects lipase-catalyzed hydrolysis of castor oil. Even a particular ion has different effects on the activity of different lipases. Hydrophobic organic solvents perform better than hydrophilic solvents during the reaction. Sonication considerably increases hydrolysis in case of lipolase. The effects of additives on the same lipase vary with their types. Nonionic surfactants enhance hydrolysis whereas cationic and anionic surfactants decrease it. A single variable optimization method is used to obtain optimum conditions. In order to eliminate its disadvantages, a statistical optimization method is used in recent studies. Statistical optimization shows that interactions between any two of the following pH, enzyme concentration and buffer concentration become significant in presence of a nonionic surfactant named Span 80.

  13. Effectiveness of castor oil extract on Escherichia coli and its endotoxins in root canals.

    Science.gov (United States)

    Valera, Marcia Carneiro; Maekawa, Lilian Eiko; Chung, Adriana; de Oliveira, Luciane Dias; Carvalho, Claudio Antonio Talge; Koga-Ito, Cristiane Yumi; Jorge, Antonio Olavo Cardoso

    2012-01-01

    This in vitro study sought to evaluate the effectiveness of castor oil extract used as an irrigating solution on Escherichia coli and its endotoxins in root canals. Sixty single-rooted teeth were prepared (using castor oil extract as irrigating solution) and divided into five groups (n = 12): Group 1 samples were treated with calcium hydroxide (Ca(OH)2), Group 2 samples were treated with polymyxin B, Group 3 samples were treated with Ca(OH)2 and 2% chlorhexidine gel (CHX), and Group 4 samples were treated with castor oil extract. A control group used physiological saline solution as an irrigant. Canal content samples were collected at four different times: immediately after instrumentation, seven days after instrumentation, after 14 days of intracanal medication, and seven days after removal of intracanal medication. A plating method was used to assess antimicrobial activity and the quantification of endotoxins was evaluated by the chromogenic Limulus lysate assay. Data were submitted to ANOVA and a Dunn test (a = 5%). Irrigation with castor oil extract decreased E. coli counts but had no effect on the level of endotoxins. Samples taken seven days after removal of medication revealed a significant reduction in endotoxin levels in Groups 3 and 4. Compared to the saline solution irrigation, castor oil extract decreased microorganism counts in root canals immediately after canal preparation. None of the medications used completely eliminated endotoxins in the root canal.

  14. THE EFFECTS OF POSSIBLE CONTAMINATION ON THE RADIOCARBON DATING OF THE DEAD SEA SCROLLS II : EMPIRICAL METHODS TO REMOVE CASTOR OIL AND SUGGESTIONS FOR REDATING

    NARCIS (Netherlands)

    Rasmussen, Kaare Lund; van der Plicht, Johannes; Doudna, Gregory; Nielsen, Frederik; Hojrup, Peter; Stenby, Erling Halfdan; Pedersen, Carl Th; Højrup, Peter

    2009-01-01

    While kept at the Rockefeller Museum in East Jerusalem, many Dead Sea Scroll fragments were exposed to castor oil by the original team of editors in the course of cleaning the parchments. Castor oil must be regarded as a serious contaminant in relation to radiocarbon dating. If modern castor oil is

  15. Screening of the entire USDA castor germplasm collection for oil content and fatty acid composition for optimum biodiesel production.

    Science.gov (United States)

    Wang, Ming Li; Morris, J Bradley; Tonnis, Brandon; Pinnow, David; Davis, Jerry; Raymer, Paul; Pederson, Gary A

    2011-09-14

    Castor has tremendous potential as a feedstock for biodiesel production. The oil content and fatty acid composition in castor seed are important factors determining the price for production and affecting the key fuel properties of biodiesel. There are 1033 available castor accessions collected or donated from 48 countries worldwide in the USDA germplasm collection. The entire castor collection was screened for oil content and fatty acid composition by nuclear magnetic resonance (NMR) and gas chromatography (GC), respectively. Castor seeds on the average contain 48.2% oil with significant variability ranging from 37.2 to 60.6%. Methyl esters were prepared from castor seed by alkaline transmethylation. GC analysis of methyl esters confirmed that castor oil was composed primarily of eight fatty acids: 1.48% palmitic (C16:0), 1.58% stearic (C18:0), 4.41% oleic (C18:1), 6.42% linoleic (C18:2), 0.68% linolenic (C18:3), 0.45% gadoleic (C20:1), 84.51% ricinoleic (C18:1-1OH), and 0.47% dihydroxystearic (C18:0-2OH) acids. Significant variability in fatty acid composition was detected among castor accessions. Ricinoleic acid (RA) was positively correlated with dihydroxystearic acid (DHSA) but highly negatively correlated with the five other fatty acids except linolenic acid. The results for oil content and fatty acid composition obtained from this study will be useful for end-users to explore castor germplasm for biodiesel production.

  16. Castor oil biodiesel: an economic evaluation; Biodiesel de mamona: uma avaliacao economica

    Energy Technology Data Exchange (ETDEWEB)

    Pires, Monica de Moura; Alves, Jaenes Miranda; Almeida Neto, Jose Adolfo de; Almeida, Cezar Menezes; Sousa, Geovania Silva de; Cruz, Rosenira Serpa da; Monteiro, Renata; Lopes, Beatriz Sampaio; Robra, Sabine [Universidade Estadual de Santa Cruz, Ilheus, BA (Brazil). Grupo Bioenergia e Meio Ambiente]. E-mails: mpires@uesc.br; jaenes@uesc.br; jalmeida@uesc.br; roserpa@uesc.br

    2004-07-01

    The production cost of castor oil biodiesel by methyl way and its economic viability, using as reference the production cost data of castor oil and the implantation of the pilot plant at UESC - state university of Santa Cruz, Bahia State, Brazil was determined. From this information, it was seen that the estimated price of castor oil biodiesel is close to the diesel price in the Itabuna market, Bahia state, Brazil. The indicators show economic viability of the mini-power plant installation. Such information are preliminary estimative for the market and can be modified as function of changes in the main factors used to have the production costs, as well as the sectorial policies that drives the activity as much in levels of raw material production as in biodiesel.

  17. STUDY ON CASTOR OIL POLYURETHANE/POLY (METHYL METHACRYLATE) AB CROSSLINKED POLYMERS

    Institute of Scientific and Technical Information of China (English)

    DU Ying; HAN Xiaozu; LIU Wenzhong

    1991-01-01

    Castor oil polyurethane/poly(methyl methacrylate) AB crosslinked polymers (ABCP) were synthesized by free radical copolymerization of MMA and vinyl-terminated castor oil polyurethane which was obtained from isocyanate-terminated castor oil polyurethane and hydroxyethyl methacrylate.The mechanical properties, transition and relaxation, as well as compatibility and morphology of the ABCP were investigated by changing the component. The results show that the ABCP is a semicompatible system and the compatibility of the two components decreases with increasing content of the hard segment. The mechanical and damping properties of the ABCP are obviously superior to that of their homopolymers. The damping value is mainly controlled by crosslink density of the ABCP but the Tg value by component.

  18. Synthesis and characterization of castor oil based polyurethane–polyacrylonitrile interpenetrating polymer networks

    Indian Academy of Sciences (India)

    P Mallu; Siddaramaiah; R Somashekar

    2000-10-01

    A series of interpenetrating polymer networks (IPNs) of castor oil based polyurethane/polyacrylonitrile (PU/PAN: 80/20, 60/40, 50/50, 40/60 and 20/80) were synthesized by condensation reaction of castor oil with methylene diisocyanate and acrylonitrile, employing benzoyl peroxide (BPO) and ethylene glycol dimethylacrylate (EGDM) as initiator and crosslinkers respectively. The physical, chemical, optical and some of the mechanical properties of PU/PAN were studied. Phase stabilization in IPNs was investigated by wide angle X-ray (WAXS) profile analysis. Variation of crystal size distribution was studied in these polymer networks.

  19. Characterization and Utilization of castor bean seed oil extract for production of medicated soap.

    Directory of Open Access Journals (Sweden)

    Abdulrasheed A

    2015-12-01

    Full Text Available The research work is to investigate the potential utilization of castor bean seed oil extract in the production of medicated soap. The oil was extracted via soxhlet extractor using hexane as solvent. The characterization analysis reveals the acid value and saponification value of the oil which were between the ranges of values specified by ASTM. The soap produced gave a pH of (8.9, foam height (16cm, alcohol insoluble (3.45%, moisture content (4.2% and free acidity of (0.10. The antibacterial activity of soap produced from castor oil on bacteria isolate (Staphylococcus Aureus was promising with an inhibition zone of 15.5mm but at dilutions of 10-1 , 10-2 and 10-3 , were found to be 11.5mm, 9.5mm and 6mm respectively. This shows that as concentration decreases, the sensitivity of the soap to the bacteria isolate also decreases. The sensitivity of the medicated soap to the bacteria isolate is as a result of the presence of ricinoleic acid present in large proportion in the fatty acid composition of castor oil. It can be concluded that a highly effective soap can be produced from castor bean seed oil extract.

  20. Maximization of bioconversion of castor oil into ricinoleic acid by response surface methodology.

    Science.gov (United States)

    Goswami, Debajyoti; Sen, Ramkrishna; Basu, Jayanta Kumar; De, Sirshendu

    2009-09-01

    In this study, response surface methodology was applied to optimize process variables like temperature, pH, enzyme concentration (mg/g oil), and buffer concentration (g/g oil) for hydrolysis of castor oil using Candida rugosa lipase. A 2(4) full factorial central composite design was used to develop the quadratic model that was subsequently optimized and the optimal conditions were as follows: temperature 40 degrees C, pH 7.72, enzyme concentration 5.28 mg/g oil, buffer concentration 1g/g oil and there was 65.5% conversion in 6 h. These predicted optimal conditions agreed well with the experimental results. This is the first report on the application of response surface methodology in castor oil hydrolysis using C. rugosa lipase with higher percentage conversion in 6 h.

  1. Treatment of Sebacic Acid Industrial Wastewater by Extraction Process Using Castor Oil Acid as Extractant*

    Institute of Scientific and Technical Information of China (English)

    徐航; 周全; 王金福

    2013-01-01

    Wastewater containing high concentrations of phenol and sodium sulfate is generated in sebacic acid (SA) industry. Castor oil acid, a raw material for producing SA, can be used to extract phenol from wastewater in order to reduce the amount of phenol used in the process and discharge of phenol. The results show that the extrac-tion mechanism is that hydroxyl group of phenol is linked to carboxyl group of castor oil acid by hydrogen bond. The extraction process approaches equilibrium in 30 min. Extraction ratio increases with the increase of sodium sulfate and castor oil acid, and decreases as phenol increases. When the oil-water ratio is 1︰3, the optimal distribu-tion coefficient of 40 is obtained. Phenol saturation concentration in castor oil acid is 1.03 mol·L−1 after extraction for 4 times. The equilibrium constant (Kex) at 25 °C is 8.41 and the endothermic enthalpy (ΔH) is 1.513 kJ·mol−1. The Gibbs free energy (ΔG) is−5.277 kJ·mol−1 and the value ofΔS is calculated to be 22.3 J·mol−1·K−1.

  2. A Comparative Experimental Analysis of Tribological Properties Between Commercial Mineral Oil and Neat Castor Oil using Taguchi Method in Boundary Lubrication Regime

    Directory of Open Access Journals (Sweden)

    S. Bhaumik

    2016-03-01

    Full Text Available The present work aims to carry out a comparative experimental analysis of tribological properties of 372cSt mineral oil and 229cSt castor oil. The antiwear and extreme pressure properties of both the oils have been analysed according to ASTM G 99 and ASTM D-2783 standards. The surfaces of the balls and pins after tribo tests have been analysed using Scanning Electron Microscope (SEM images. The present test results predict that the antiwear and extreme pressure properties in case of the selected commercially available mineral oil are better than neat castor oil. Both coefficient of friction and frictional force increased by 16-42 % and 16-35 % respectively in case of neat castor oil as compared with that of the mineral oil. The load carrying capacity in case of mineral oil has been found to be 250 kg while in case of castor oil it has been found to be 126 kg. SEM images show a higher plastic deformation in case of castor oil as compared to the mineral oil. Both mineral oil and castor oil showed surface deteriorations and increase in roughness after 40 hrs of intermittent running during scuffing test. Thus, the present investigation indicates that the tribological properties of neat castor are inferior to that of mineral oil although close observation of the results shows that both AW and EP properties of neat castor oil are much closer to that of commercial mineral oil. Thus, the present work would help in formulating castor oil based new bio lubricants with better anti wear and extreme pressure properties

  3. Isotope labeling-based quantitative proteomics of developing seeds of castor oil seed (Ricinus communis L.)

    DEFF Research Database (Denmark)

    Nogueira, Fábio C S; Palmisano, Giuseppe; Schwämmle, Veit

    2013-01-01

    In this study, we used a mass spectrometry-based quantification approach employing isotopic (ICPL) and isobaric (iTRAQ) labeling to investigate the pattern of protein deposition during castor oil seed (Ricinus communis L.) development, including that of proteins involved in fatty acid metabolism...

  4. Synthesis and properties of radiation modified thermally cured castor oil based polyurethanes

    Science.gov (United States)

    Mortley, Aba; Bonin, H. W.; Bui, V. T.

    2007-12-01

    Thermally cured polyurethanes were prepared from castor oil and hexamethylene diisocyanate (HMDI). Due to the long aliphatic chain of the castor oil component of polyurethane, thermal curing of castor oil based polyurethane (COPU) is limited by increasing polymer viscosity. To enhance further crosslinking, COPUs were exposed to doses up to 3.0 MGy produced by the mixed ionizing radiation field of a SLOWPOKE-2 research nuclear reactor. The physico-mechanical properties of castor oil based polyurethanes (COPU), unirradiated and irradiated, were characterized by mechanical tensile tests. A four-fold increase in modulus and tensile strength values from 0.930 to 4.365 MPa and 0.149 to 0.747 MPa, respectively, suggests improved physico-mechanical properties resulting from radiation. The changing areas of the carbonyl and the NH absorbance peaks and the disappearance of the isocyanate peak in the FTIR spectra as radiation progressed, indicates increased hydrogen bonding and intermolecular crosslinking, which is in agreement with the mechanical tests. Unchanging 13C solid state NMR spectra imply limited sample degradation with increasing radiation.

  5. Antimicrobial action of sodium hypochlorite and castor oil solutions for denture cleaning - in vitro evaluation.

    Science.gov (United States)

    Salles, Marcela Moreira; Oliveira, Viviane de Cássia; Souza, Raphael Freitas; Silva, Cláudia Helena Lovato; Paranhos, Helena de Freitas Oliveira

    2015-01-01

    The objective of this in vitro study was to evaluate the antimicrobial action of sodium hypochlorite (0.25% and 0.50%) and 10% castor oil solutions against specific microorganisms, by counting Colony Forming Units (CFU) of clinically important bacteria and Candida species. Acrylic resin specimens (n = 320; Lucitone 550) were obtained from square metal matrices (10 x 10 x 2 mm), sterilized by microwave (650W, for 6 minutes) and contaminated by Staphylococcus aureus, Pseudomonas aeruginosa, Candida albicans, Bacillus subtilis, Escherichia coli, Streptococcus mutans, Enterococcus faecalis and Candida glabrata. The specimens were immersed for 20 minutes in one of the following hygiene solutions (n = 10/each): A - 0.25% Sodium hypochlorite; B - 0.5% Sodium hypochlorite; C - 10% Castor oil solution; and D (Control) - saline. Adhered cells were suspended and inoculated into a selective solid medium (37ºC for 24 h). The Student's t-test (α = 0.05) was performed to compare log10(CFU+1)/mL between Groups C and D. The results showed that sodium hypochlorite (0.25% and 0.5%) completely eliminated all detectable microorganisms. The castor oil solution eliminated B. subtilis and reduced counts for other strains. Differences between C and D were significant (p castor oil solution provided moderate efficacy and performed differently on the tested species, with the strongest effect on B. subtilis and with non-significant action on E. faecalis.

  6. Lipase catalyzed transesterification of castor oil by straight chain higher alcohols.

    Science.gov (United States)

    Malhotra, Deepika; Mukherjee, Joyeeta; Gupta, Munishwar N

    2015-03-01

    Biolubricants from Castor oil were produced enzymatically by transesterification with higher alcohols using a lipase mixture of immobilized Mucor miehei (RMIM) and immobilized Candida antarctica lipase B (Novozym 435) under low water conditions. The conversions were in the range of 80-95% under the optimized conditions.

  7. Allergic contact dermatitis from 12-hydroxystearic Acid and hydrogenated castor oil.

    Science.gov (United States)

    Shaw, Daniel W

    2009-01-01

    A 34-year-old male experienced severe allergic contact dermatitis from 12-hydroxystearic acid in a lip balm and from hydrogenated castor oil in an underarm deodorant. He also had a positive patch-test reaction to bis-diglyceryl polyacyladipate-2, which is present in the implicated lip balm and which itself contains 12-hydroxystearic acid. He was also incidentally found to have contact allergy to ricinoleic acid and castor oil. Ricinoleic acid is the principal fatty acid in castor oil, whereas 12-hydroxystearic acid is the principal fatty acid in hydrogenated castor oil. These two fatty acids are each 18-carbon 12-hydroxylated fatty acids, differing only in degree of saturation. The lack of patch-test reactivity to the analogous nonhydroxylated fatty acids, stearic acid (C18:0), and oleic acid (C18:1) indicates that 12-hydroxylation was required for allergenicity in this patient. In addition, serial dilution testing demonstrated that saturation of the hydroxylated C18 fatty acid enhanced its allergenicity.

  8. Experimental investigation on performance and exhaust emissions of castor oil biodiesel from a diesel engine.

    Science.gov (United States)

    Shojaeefard, M H; Etgahni, M M; Meisami, F; Barari, A

    2013-01-01

    Biodiesel, produced from plant and animal oils, is an important alternative to fossil fuels because, apart from dwindling supply, the latter are a major source of air pollution. In this investigation, effects of castor oil biodiesel blends have been examined on diesel engine performance and emissions. After producing castor methyl ester by the transesterification method and measuring its characteristics, the experiments were performed on a four cylinder, turbocharged, direct injection, diesel engine. Engine performance (power, torque, brake specific fuel consumption and thermal efficiency) and exhaust emissions were analysed at various engine speeds. All the tests were done under 75% full load. Furthermore, the volumetric blending ratios of biodiesel with conventional diesel fuel were set at 5, 10, 15, 20 and 30%. The results indicate that lower blends of biodiesel provide acceptable engine performance and even improve it. Meanwhile, exhaust emissions are much decreased. Finally, a 15% blend of castor oil-biodiesel was picked as the optimized blend of biodiesel-diesel. It was found that lower blends of castor biodiesel are an acceptable fuel alternative for the engine.

  9. Undecylenic acid: a valuable and physiologically active renewable building block from castor oil.

    Science.gov (United States)

    Van der Steen, Marijke; Stevens, Christian V

    2009-01-01

    A lot of attention is currently being paid to the transition to a biobased economy. In this movement, most efforts concentrate on the development of bioenergy applications including bioethanol, biodiesel, thermochemical conversion of biomass, and others. However, in the energy sector other nonbiomass alternatives are known, whereas no valuable alternatives are available when thinking about chemical building blocks. Therefore, it is also essential to develop new routes for the synthesis of bio-based chemicals and materials derived thereof. Such intermediates can originate either from plants or from animals. Castor oil is a non-edible oil extracted from the seeds of the castor bean plant Ricinus communis (Euphorbiaceae), which grows in tropical and subtropical areas. Globally, around one million tons of castor seeds are produced every year, the leading producing areas being India, PR China, and Brazil.2 10-Undecenoic acid or undecylenic acid is a fatty acid derived from castor oil that, owing to its bifunctional nature, has many possibilities to develop sustainable applications.

  10. Characteristics and Composition of a High Oil Yielding Castor Variety from Pakistan.

    Science.gov (United States)

    Panhwar, Tarique; Mahesar, Sarfaraz Ahmed; Mahesar, Abdul Waheed; Kandhro, Aftab Ahmed; Talpur, Farah Naz; Laghari, Zahid Hussain; Chang, Abdul Sattar; Hussain Sherazi, Syed Tufail

    2016-01-01

    Keeping in view the versatile applications of castor oil in cosmetic, pharmaceutical and recently as renewable source, the present work is a step towards the commercialization of castor on large scale in Pakistan. The current study introduces a castor variety with high oil content. Initially seeds were physically examined for some physical parameters. Seed moisture, ash content and linear dimensions such as length, width and thickness were found to be 4.53%, 6.44%, 12.24 mm, 8.31 mm and 5.67 mm, respectively. For oil extraction, Soxhlet method was used which resulted in the high oil content 54.0%. For quality assessment of oil, physicochemical parameters were checked according to official standard AOCS methods and compared with ASTM specifications. The determined parameters were as follows; specific gravity 0.953 g/cm(-3), refractive index 1.431, viscosity 672.0 mPas.s, moisture content 0.32%, FFA 0.14%, IV 83.61 gI2/100 g, PV 2.25 meq/Kg and SV 186.0 mgKOH/g. Furthermore, fatty acid analysis of oil showed that, most abundant fatty acid was ricinoleic acid 94.59%, followed by palmitic 0.31%, linoleic 1.84%, oleic (n-9) 2.05%, oleic (n-10) 0.22%, stearic 0.45% and eicosenoic acid 0.53%. The detected fatty acids were compared with registered variety and varieties of other regions.

  11. Isotope labeling-based quantitative proteomics of developing seeds of castor oil seed (Ricinus communis L.).

    Science.gov (United States)

    Nogueira, Fábio C S; Palmisano, Giuseppe; Schwämmle, Veit; Soares, Emanuela L; Soares, Arlete A; Roepstorff, Peter; Domont, Gilberto B; Campos, Francisco A P

    2013-11-01

    In this study, we used a mass spectrometry-based quantification approach employing isotopic (ICPL) and isobaric (iTRAQ) labeling to investigate the pattern of protein deposition during castor oil seed (Ricinus communis L.) development, including that of proteins involved in fatty acid metabolism, seed-storage proteins (SSPs), toxins, and allergens. Additionally, we have used off-line hydrophilic interaction chromatography (HILIC) as a step of peptide fractionation preceding the reverse-phase nanoLC coupled to a LTQ Orbitrap. We were able to identify a total of 1875 proteins, and from these 1748 could be mapped to extant castor gene models, considerably expanding the number of proteins so far identified from developing castor seeds. Cluster validation and statistical analysis resulted in 975 protein trend patterns and the relative abundance of 618 proteins. The results presented in this work give important insights into certain aspects of the biology of castor oil seed development such as carbon flow, anabolism, and catabolism of fatty acid and the pattern of deposition of SSPs, toxins, and allergens such as ricin and 2S albumins. We also found, for the first time, some genes of SSP that are differentially expressed during seed development.

  12. Optimum Operating Conditions for Epoxidation Reaction of Jojoba and Castor Oils

    Directory of Open Access Journals (Sweden)

    El-Adly R. A

    2014-03-01

    Full Text Available The goal of this paper is to determine the best set of parameters such as, glacial acetic acid to ethylenic unsaturation mole ratio (acid/ethylene, hydrogen peroxide to ethylenic unsaturation mole ratio (H2O2/ethylene and temperature on epoxidation conversion based on experimental results, with respect to time. The effect of these parameters has been studied in a separate set of experiments. Their ranges were as follows: 0.2-0.8Wt%, 0.75-3Wt%, and 40oC-80oC respectively. Six models have been introduced to indicate the effect of these three variables on conversion for both jojoba and castor oil, and the prediction abilities of the resultant models were tested. Regression analysis is used to extract the introduced non linear models. In addition, two new correlations have been introduced to incorporate all the studied variables and their effect on conversion simultaneously for both jojoba and castor oil. An optimization program has been introduced to determine the optimum operating conditions for maximum conversion for both jojoba and castor oil. The study shows that, the maximum conversion for epoxidized jojoba oil (66% could be achieved at acid/ethylene ratio: 0.4, H2O2/ethylene ratio: 1.44; temp: 66.5 and time is 8hr. While the maximum conversion for epoxidized castor oil (53.24% could be achieved at acid/ethylene ratio: 0.37; H2O2/ethylenes ratio: 1.32; temp: 61 and time is 8hr. the model results are strongly agreed with the experimental results.

  13. Identification of acylglycerols containing dihydroxy fatty acids in castor oil by mass spectrometry.

    Science.gov (United States)

    Lin, Jiann-Tsyh; Arcinas, Arthur; Harden, Leslie A

    2009-04-01

    Ricinoleate, a monohydroxy fatty acid, in castor oil has many industrial uses. Dihydroxy fatty acids can also be used in industry. The C(18) HPLC fractions of castor oil were analyzed by electrospray ionization mass spectrometry of lithium adducts to identify the acylglycerols containing dihydroxy fatty acids and the dihydroxy fatty acids. Four diacylglycerols identified were diOH18:1-diOH18:1, diOH18:2-OH18:1, diOH18:1-OH18:1 and diOH18:0-OH18:1. Eight triacylglycerols identified were diOH18:1-diOH18:1-diOH18:1, diOH18:1-diOH18:1-diOH18:0, diOH18:2-diOH18:1-OH18:1, diOH18:1-diOH18:1-OH18:1, diOH18:1-diOH18:0-OH18:1, diOH18:2-OH18:1-OH18:1, diOH18:1-OH18:1-OH18:1 and diOH18:0-OH18:1-OH18:1. The locations of fatty acids on the glycerol backbone were not determined. The structures of these three newly identified dihydroxy fatty acids were proposed as 11,12-dihydroxy-9-octadecenoic acid, 11,12-dihydroxy-9,13-octadecadienoic acid and 11,12-dihydroxyoctadecanoic acid. These individual acylglycerols were at the levels of about 0.5% or less in castor oil and can be isolated from castor oil or overproduced in a transgenic oil seed plant for future industrial uses.

  14. Cross-Linkable Epoxidized Maleinated Castor Oil: A Renewable Resin Alternative to Unsaturated Polyesters

    Directory of Open Access Journals (Sweden)

    Yeşim Müge Şahin

    2016-01-01

    Full Text Available As an alternative resin to conventional synthetic unsaturated polyesters (UPEs, epoxidized maleinated castor oil (EMACO was synthesized in two steps. For this purpose, castor oil was reacted with maleic anhydride at 70°C to obtain maleinated castor oil (MACO. Then, epoxidation of MACO was carried out by using a mixture of formic acid and hydrogen peroxide at 0–5°C. Then, the free carboxyl groups of the synthesized EMACO were further reacted with free epoxide groups of EMACO at 90°C. At the end of the reaction, an unsaturated polyester precursor-prepolymer was obtained (P-EMACO. FTIR and 1H NMR spectroscopic techniques were used to characterize the monomers synthesized. The P-EMACO was then mixed with styrene and cross-linked in the presence of AIBN at 50°C. Thermal and mechanical properties of the final cross-linked product were investigated by thermogravimetric analysis (TGA and dynamic mechanical analysis (DMA techniques. The degradation onset temperature of the material at which cross-linked X-EMACO loses 5% of its weight was found to be 209°C. Its dynamic Tg and storage modulus at 25°C were determined as 72°C and 1.08 GPa, respectively. These results are higher than some of the different oil based polymers reported in the literature.

  15. Prospective study for the production of oleochemicals derivates from castor oil in Colombia

    Directory of Open Access Journals (Sweden)

    Margarita Guerrero

    2010-04-01

    Full Text Available There are many ways get closet to the future, being the prospective the one that conceives the future, not like an unique reality but like a multiple one, obtained as a result of the identification of the human beign future actions. For all this, the human being takes knowledge, the yearings and the fears that he sees for the actions he will undertake. Using the prospective, this article outlines the dynamics that will have the oleochemical castor oil sector, because Colombia has resources to develop Ricinus comunnis cultivation and industrial uses of castor oil and its derivates. The study establishes the keys that define the current and future behaviour of the system, the position and the power of each one of the involved actors will have, and the determination of the scenarios (future representations with more probability to occur, as well as the definition of the scenario wanted and the strategies that will allow to reach it.

  16. Production and characterization of MDF using eucalyptus fibers and castor oil-based polyurethane resin

    Directory of Open Access Journals (Sweden)

    Campos Cristiane Inácio de

    2004-01-01

    Full Text Available The growing popularity of wooden panels renders this market segment increasingly competitive. MDF (Medium Density Fiberboard, in particular, is widely employed for a variety of applications, including civil construction, furniture, and packaging. This paper discusses a study of MDF produced from alternative raw materials, i.e., Eucalyptus fibers and castor-oil-based polyurethane resin. Physical and mechanical tests were performed to determine the MDF's modulus of elasticity and modulus of rupture in static bending tests, its swelling, water absorption, moisture and density. The results of the physical and mechanical characterization of this laboratory-produced MDF are discussed and compared with the Euro MDF Board standard. MDF produced with eucalyptus fiber and castor-oil-based polyurethane resin presents results very satisfactory.

  17. Production and Characterization of Biodiesel Using Nonedible Castor Oil by Immobilized Lipase from Bacillus aerius

    OpenAIRE

    Sunil Kumar Narwal; Nitin Kumar Saun; Priyanka Dogra; Ghanshyam Chauhan; Reena Gupta

    2015-01-01

    A novel thermotolerant lipase from Bacillus aerius was immobilized on inexpensive silica gel matrix. The immobilized lipase was used for the synthesis of biodiesel using castor oil as a substrate in a solvent free system at 55°C under shaking in a chemical reactor. Several crucial parameters affecting biodiesel yield such as incubation time, temperature, substrate molar ratio, and amount of lipase were optimized. Under the optimized conditions, the highest biodiesel yield was up to 78.13%. Th...

  18. Cadmium sulfide quantum dots stabilized by castor oil and ricinoleic acid

    Science.gov (United States)

    Kyobe, Joseph William; Mubofu, Egid Beatus; Makame, Yahya M. M.; Mlowe, Sixberth; Revaprasadu, Neerish

    2016-02-01

    Castor oil and ricinoleic acid (an isolate of castor oil) are environmentally friendly bio-based organic surfactants that have been used as capping agents to prepare nearly spherical cadmium sulfide quantum dots (QDs) at 230, 250 and 280 °C. The prepared quantum dots were characterized by Ultra violet-visible (UV-vis), Photoluminescence (PL), Transmission Electron Microscopy (TEM), High Resolution Transmission Electron Microscopy (HRTEM) and X-ray diffraction (XRD) giving an overall CdS QDs average size of 5.14±0.39 nm. The broad XRD pattern and crystal lattice fringes in the HRTEM images showed a hexagonal phase composition of the CdS QDs. The calculated/estimated average size of the prepared castor oil capped CdS QDs for various techniques were 4.64 nm (TEM), 4.65 nm (EMA), 5.35 nm (UV-vis) and 6.46 nm (XRD). For ricinoleic acid capped CdS QDs, the average sizes were 5.56 nm (TEM), 4.78 nm (EMA), 5.52 nm (UV-vis) and 8.21 nm (XRD). Optical properties of CdS QDs showed a change of band gap energy from its bulk band gap of 2.42-2.82 eV due to quantum size confinement effect for temperature range of 230-280 °C. Similarly, a blue shift was observed in the photoluminescence spectra. Scanning electron microscope (SEM) observations show that the as-synthesized CdS QDs structures are spherical in shape. Fourier transform infra-red (FTIR) studies confirms the formation of castor oil and ricinoleic acid capped CdS QDs.

  19. Glutathione Preservation during Storage of Rat Lenses in Optisol-GS and Castor Oil

    DEFF Research Database (Denmark)

    Holm, Thomas; Brøgger-Jensen, Martin Rocho; Johnson, Leif;

    2013-01-01

    Glutathione concentration in the lens decreases in aging and cataractous lenses, providing a marker for tissue condition. Experimental procedures requiring unfrozen lenses from donor banks rely on transportation in storage medium, affecting lens homeostasis and alterations in glutathione levels. ....... The aim of the study was to examine the effects of Optisol-GS and castor oil on lens condition, determined from their ability to maintain glutathione concentrations....

  20. Antimicrobial action of sodium hypochlorite and castor oil solutions for denture cleaning – in vitro evaluation

    Directory of Open Access Journals (Sweden)

    Marcela Moreira SALLES

    2015-01-01

    Full Text Available The objective of this in vitro study was to evaluate the antimicrobial action of sodium hypochlorite (0.25% and 0.50% and 10% castor oil solutions against specific microorganisms, by counting Colony Forming Units (CFU of clinically important bacteria and Candida species. Acrylic resin specimens (n = 320; Lucitone 550 were obtained from square metal matrices (10 x 10 x 2 mm, sterilized by microwave (650W, for 6 minutes and contaminated by Staphylococcus aureus, Pseudomonas aeruginosa, Candida albicans, Bacillus subtilis, Escherichia coli, Streptococcus mutans, Enterococcus faecalisand Candida glabrata. The specimens were immersed for 20 minutes in one of the following hygiene solutions (n = 10/each: A – 0.25% Sodium hypochlorite; B – 0.5% Sodium hypochlorite; C – 10% Castor oil solution; and D (Control – saline. Adhered cells were suspended and inoculated into a selective solid medium (37ºC for 24 h. The Student’s t-test (α = 0.05 was performed to compare log10(CFU+1/mL between Groups C and D. The results showed that sodium hypochlorite (0.25% and 0.5% completely eliminated all detectable microorganisms. The castor oil solution eliminatedB. subtilisand reduced counts for other strains. Differences between C and D were significant (p E. faecalis. Both sodium hypochlorite solutions (0.25% and 0.5% were effective in eliminating all microorganisms evaluated, and may be useful as cleaning solutions for complete dentures. The castor oil solution provided moderate efficacy and performed differently on the tested species, with the strongest effect on B. subtilis and with non-significant action on E. faecalis.

  1. UV and gamma irradiation effects on surface properties of polyurethane derivate from castor oil

    Directory of Open Access Journals (Sweden)

    Elaine C. Azevedo

    2013-01-01

    Full Text Available Gamma and ultraviolet radiation effects on hardness, elastic modulus and viscoelastic properties of polyurethane derived from castor oil (PU were investigated by nanoindentation tests. Modifications on surface morphology, induced by radiation, were observed by atomic force microscopy. The polyurethane derivate from castor oil shows good resistance to gamma radiation, with only small changes in hardness, elastic modulus, viscoelastic properties and contact angle. The hardness of PU increases at the near surface region due to UVA radiation and decreases after UVC radiation. The contact angle for water drop decreases after UVC radiation, but not after gamma radiation, despite a significant increase in roughness. Such results are attributed to different responses from polyurethane to radiation energy. Increase in hardness due to UVA is attributed to a higher crosslinking at shallow depths, while a decrease in mechanical properties may be attributed to chain scission. These results are consistent with the modifications on viscoelastic properties. Shore D hardness did not show the same trend as observed by nanoindentation results. Hardness, viscoelastic properties and contact angle of castor oil polyurethane are more severely influenced by UVC radiation, while gamma radiation does not have a significant effect.

  2. UV and gamma irradiation effects on surface properties of polyurethane derivative from castor oil

    Energy Technology Data Exchange (ETDEWEB)

    Azevedo, Elaine C.; Nascimento, Eduardo M., E-mail: helunica@yahoo.com.br [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil); Chierice, Gilberto O.; Claro Neto, Salvador [Universidade de Sao Paulo (IQSC/USP), Sao Carlos, SP (Brazil). Instituto de Quimica; Lepienski, Carlos M. [Universidade Federal do Parana (UFPR), Curitiba (Brazil)

    2013-07-01

    Gamma and ultraviolet radiation effects on hardness, elastic modulus and viscoelastic properties of polyurethane derived from castor oil (PU) were investigated by nanoindentation tests. Modifications on surface morphology, induce by radiation, were observed by atomic force microscopy. The polyurethane derivative from castor oil shows good resistance to gamma radiation, with only small changes in hardness, elastic modulus, viscoelastic properties and contact angle. The hardness of PY increases at the near surface region due to UVA radiation and decreases after UVC radiation. The contact angle for water drop decreases after UVC radiation, by not after gamma radiation, despite a significant increase in roughness. Such results are attributed to different responses from polyurethane to radiation energy. Increase in hardness due to UVA is attributed to a higher crosslinking at shallow depths, while a decrease in mechanical properties may be attributed to chain scission. These results are consistent with the modifications on viscoelastic properties. Shore D hardness did not show the same trend as observed by nanoindentation results. Hardness, viscoelastic properties and contact angle of castor oil polyurethane are more severely influenced by UVC radiation, while gamma radiation does not have a significant effect. (author)

  3. 环氧蓖麻油合成研究%Synthesis of Epoxidized Castor Oil

    Institute of Scientific and Technical Information of China (English)

    侯宾; 向开权; 黄东海; 杨艳

    2012-01-01

    The castor oil was prepared using the peroxyacetic acid by catalysis of phosphoric acid. Some factors which had effect on the epoxy value of product, such as reaction time, reaction temperature, the a- mounts of hydrogen peroxide etc were discussed. The result showed the effects of various parameters as follows:reaction time〉reaction temperature 〉 the amount of acid consumption〉 the amount of hydrogen peroxide 〉 catalyst concentration. FI-IPt was exploited to characterize the epoxidized castor oil, and then the differences of TG and DTG were compared to examine the thermal stability of epoxidized castor oil.%以磷酸为催化剂、采用过氧乙酸法对蓖麻油(CO)进行环氧化研究,探索了反应时间、反应温度和双氧水的用量等变量参数对蓖麻油环氧化的影响,得到各变量参数对反应的影响大小为:时间〉温度〉酸量〉双氧水的量〉催化剂的浓度.利用FI-IR对环氧蓖麻油(ECO)进行了表征,然后对比了CO和ECO的TG和DTG热稳定性.

  4. Performance evaluation of a diesel engine fueled with methyl ester of castor seed oil

    Directory of Open Access Journals (Sweden)

    G.DURGA DEVI

    2012-07-01

    Full Text Available Diesel engines are widely used as power sources in medium and heavy-duty applications because of their lower fuel consumption and lower emissions of carbon monoxide (CO and unburned hydrocarbons (HC compared with gasoline engines. Rudolf Diesel, the inventor ofthe diesel engine, ran an engine on groundnut oil at the Paris Exposition of 1900. Since then, vegetable oils have been used as fuels when petroleum supplies were expensive or difficult to obtain. With the increased availability of petroleum in the 1940s, research into vegetable oils decreased. Since the oil crisis of the 1970s research interest has expanded in the area of alternative fuels. The difficulties associated with using raw vegetable oils in diesel engines identified in the literature are injector coking, severe engine deposits, filter gumming problems, piston ring sticking, and injector coking and thickening of the lubricating oil. The highviscosity and low volatility of raw vegetable oils are generally considered to be the major drawbacks for their utilization as fuels in diesel engines. Castor methyl ester (CME blends showed performance characteristics close to diesel. Therefore castor methylester blends can be used in CI engines in rural area for meeting energy requirement in various agricultural operations such as irrigation, threshing, indistries etc.

  5. Energetic balance of castor oil methyl and ethyl esters; Balanco energetico de esteres metilicos e etilicos de oleo de mamona

    Energy Technology Data Exchange (ETDEWEB)

    Almeida Neto, Jose Adolfo de; Cruz, Rosenira Serpa da; Alves, Jaenes Miranda; Pires, Monica de Moura; Robra, Sabine [Universidade Estadual de Santa Cruz, Ilheus BA (Brazil). Grupo Bioenergia e Meio Ambiente]. E-mails: jalmeida@uesc.br; Parente Junior, Expedito [Tecnologias Bioenergeticas Ltda. (TECBIO), Fortaleza, CE (Brazil); Fundacao Nucleo de Tecnologia Industrial (NUTEC), Fortaleza, CE (Brazil)]. E-mail: expeditojr@tecbio.com.br

    2004-07-01

    Castor oil (Ricinus communis L.) is one of the cultures chosen by the biodiesel federal and state programs to supply raw material for biodiesel production - a biofuel indicated as renewable and less pollutant than its fossil competitor. An energetic balance was performed based on LCA - Life Cycle Analysis principles and Input-Output Analysis, comparing the castor oil energy performance with others traditional cultures: colza (Brassica napus) in Europe and soybean (Glycine max) in the United States. Energy balance (O-I) was positive in both production ways (methyl and ethyl) independent of coproduct use allocation alternative. The relation Output-Input (O-I) calculated for castor oil biodiesel [1.3-2.9] was higher than the colza (1.2-1.9) and lower than the soybean (3.2--3.4), independent of the way and allocation of the used byproduct. Both indicators suggest the energy and environmental viability of the castor oil biodiesel, provided that high agricultural productivity (higher than 1.500 kg/ha year) can be guaranteed. The potentialization of the positive energetic and environmental effects depends on the adequate utilization of the coproducts and process residues, the improvement of the energy efficiency in the the castor oil and biodiesel processing and the implementation of efficient management in the use of the chemical inputs (specially the N), responsible for up 5% of the total energy input.

  6. 蓖麻油的单官能团反应%Single Functional Group Reactions of Castor Oil

    Institute of Scientific and Technical Information of China (English)

    张海飞; 朱新宝

    2015-01-01

    Castor oil is a kind of plant oils with unique properties,its molecule contains functional groups such as hydroxyl, ester group,ethylenic bond. Among these functional groups,single group can react to form castor oil derivatives,two or three groups of them also have different reactions to get special application of castor oil derivatives. Chemical reaction is summarized and classified according to the single group reaction. This article systematically introduces the reaction of the castor oil,briefly describes a variety of purposes of different products,comprehensively recommends castor oils basis chemistry knowledge,facilitates the design of the new chemical reaction and the development of new products,improves the castor oil deep processing technology.%蓖麻油是具有独特性能的植物油类,分子中含有羟基、酯基、烯键等官能团,这些官能团可以单独进行反应得到蓖麻油衍生物,也可以其中两个或三个基团组合先后进行不同反应得到特殊用途的蓖麻油衍生物。主要对三种官能团单独进行化学反应综述归类,系统地介绍蓖麻油中各官能团所能发生的反应,简述不同反应产物的用途,较全面地介绍了蓖麻油基础化学反应知识,便于新反应和多官能团反应的设计和新产品的开发,提高蓖麻油深加工技术水平。

  7. Effect of castor oil enrichment layer produced by reaction on the properties of PLA/HDI-g-starch blends.

    Science.gov (United States)

    Xiong, Zhu; Zhang, Lisheng; Ma, Songqi; Yang, Yong; Zhang, Chuanzhi; Tang, Zhaobin; Zhu, Jin

    2013-04-15

    Blends of entirely bio-sourced polymers, namely polylactide (PLA) and starch, have been melt-compounded by lab-scale co-extruder with castor oil (CO) as a plasticizer. The enrichment of castor oil on starch had great effect on the properties of the blends. If the castor oil was mainly dispersed in PLA matrix, the properties of the blends were poor, but when the hexamethylenediisocyanate (HDI) was grafted on starch granules the ready reactions between the hydroxyl on CO and the isocyante on the HDI-grafted starch (HGSTs) brought CO molecules enriched on starch particles. DSC analysis shows that the CO layer on starch has a positive effect on the crystallization of PLA in the ternary blend. The accumulation of CO on starch greatly improves the toughness and impact strength of PLA/starch blends. The grafting content of HDI on the starch granules primarily determined the compatibility and properties of the resulted blends.

  8. Glutathione preservation during storage of rat lenses in optisol-GS and castor oil.

    Directory of Open Access Journals (Sweden)

    Thomas Holm

    Full Text Available BACKGROUND: Glutathione concentration in the lens decreases in aging and cataractous lenses, providing a marker for tissue condition. Experimental procedures requiring unfrozen lenses from donor banks rely on transportation in storage medium, affecting lens homeostasis and alterations in glutathione levels. The aim of the study was to examine the effects of Optisol-GS and castor oil on lens condition, determined from their ability to maintain glutathione concentrations. METHODOLOGY/PRINCIPAL FINDINGS: Rat lenses were stored in the two types of storage media at varying time intervals up to 3 days. Glutathione concentration was afterwards determined in an enzymatic detection assay, specific for both reduced and oxidized forms. Lenses removed immediately after death exhibited a glutathione concentration of 4.70±0.29 mM. In vitro stored lenses in Optisol-GS lost glutathione quickly, ending with a concentration of 0.60±0.34 mM after 3 days while castor oil stored lenses exhibited a slower decline and ended at 3 times the concentration. A group of lenses were additionally stored under post mortem conditions within the host for 6 hours before its removal. Total glutathione after 6 hours was similar to that of lenses removed immediately after death, but with altered GSH and GSSG concentrations. Subsequent storage of these lenses in media showed changes similar to those in the first series of experiments, albeit to a lesser degree. CONCLUSIONS/SIGNIFICANCE: It was determined that storage in Optisol-GS resulted in a higher loss of glutathione than lenses stored in castor oil. Storage for more than 12 hours reduced glutathione to half its original concentration, and was considered unusable after 24 hours.

  9. Kinetic and Thermodynamics studies for Castor Oil Extraction Using Subcritical Water Technology.

    Science.gov (United States)

    Abdelmoez, Wael; Ashour, Eman; Naguib, Shahenaz M; Hilal, Amr; Al Mahdy, Dalia A; Mahrous, Engy A; Abdel-Sattar, Essam

    2016-06-01

    In this work both kinetic and thermodynamics of castor oil extraction from its seeds using subcritical water technique were studied. It was found that the extraction process followed two consecutive steps. In these steps, the oil was firstly extracted from inside the powder by diffusion mechanism. Then the extracted oil, due to extending the extraction time under high temperature and pressure, was subjected to a decomposition reaction following first order mechanism. The experimental data correlated well with the irreversible consecutive unimolecular-type first order mechanism. The values of both oil extraction rate constants and decomposition rate constants were calculated through non-linear fitting using DataFit software. The extraction rate constants were found to be 0.0019, 0.024, 0.098, 0.1 and 0.117 min(-1), while the decomposition rate constants were 0.057, 0.059, 0.014, 0.019 and 0.17 min(-1) at extraction temperatures of 240, 250, 260, 270 and 280°C, respectively. The thermodynamic properties of the oil extraction process were investigated using Arrhenius equation. The values of the activation energy, Ea, and the frequency factor, A, were 73 kJ mol(-1) and 946, 002 min(-1), respectively. The physicochemical properties of the extracted castor oil including the specific gravity, viscosity, acid value, pH value and calorific value were found to be 0.947, 7.487, 1.094 mg KOH/g, 6.1, and 41.5 MJ/Kg, respectively. Gas chromatography analysis showed that ricinoleic acid (83.6%) appears as the predominant fatty acid in the extracted oil followed by oleic acid (5.5%) and linoleic acid (2.3%).

  10. Production and Characterization of Biodiesel Using Nonedible Castor Oil by Immobilized Lipase from Bacillus aerius

    Directory of Open Access Journals (Sweden)

    Sunil Kumar Narwal

    2015-01-01

    Full Text Available A novel thermotolerant lipase from Bacillus aerius was immobilized on inexpensive silica gel matrix. The immobilized lipase was used for the synthesis of biodiesel using castor oil as a substrate in a solvent free system at 55°C under shaking in a chemical reactor. Several crucial parameters affecting biodiesel yield such as incubation time, temperature, substrate molar ratio, and amount of lipase were optimized. Under the optimized conditions, the highest biodiesel yield was up to 78.13%. The characterization of synthesized biodiesel was done through FTIR spectroscopy, 1H NMR spectra, and gas chromatography.

  11. Production and characterization of biodiesel using nonedible castor oil by immobilized lipase from Bacillus aerius.

    Science.gov (United States)

    Narwal, Sunil Kumar; Saun, Nitin Kumar; Dogra, Priyanka; Chauhan, Ghanshyam; Gupta, Reena

    2015-01-01

    A novel thermotolerant lipase from Bacillus aerius was immobilized on inexpensive silica gel matrix. The immobilized lipase was used for the synthesis of biodiesel using castor oil as a substrate in a solvent free system at 55°C under shaking in a chemical reactor. Several crucial parameters affecting biodiesel yield such as incubation time, temperature, substrate molar ratio, and amount of lipase were optimized. Under the optimized conditions, the highest biodiesel yield was up to 78.13%. The characterization of synthesized biodiesel was done through FTIR spectroscopy, (1)H NMR spectra, and gas chromatography.

  12. Green superlubricity of Nitinol 60 alloy against steel in presence of castor oil

    Science.gov (United States)

    Zeng, Qunfeng; Dong, Guangneng; Martin, Jean Michel

    2016-07-01

    In the present work, first, we show that sliding Nitinol 60 alloy against steel under castor oil lubrication exhibits a new case of superlubricity (coefficient of friction CoF ≪ 0.01). So far, CoF below 0.01 have never been achieved under boundary lubrication at high contact pressure and in presence of vegetable oil as a green lubricant. Next, it is demonstrated that superlubricity is controlled by tribochemical reactions, involving chemical degradation of castor oil and the formation of metal oxy-hydroxides. Finally, to explain these findings, we propose a novel superlubricity mechanism consisting of hexanoic acid molecules intercalated between nickel and iron oxy-hydroxide lamellar layers, a structure very similar to the one found in Fe-Ni batteries. We propose that superlubricity is achieved due to repulsive electrostatic forces acting between the intercalated metal oxy-hydroxide lamellar compounds. This system would be suitable for practical engineering applications in many fields including biotechnologies.

  13. The catalytic microwave synthesis of biodegradable polyester polyols based on castor oil and l-lactide

    Science.gov (United States)

    Kojić, D.; Erceg, T.; Vukić, N.; Teofilović, V.; Ristić, I.; Budinski-Simendić, J.; Aleksić, V.

    2017-01-01

    Various strategies for achieving a functional poly(lactic acid) (PLA) have been developed such as ring-opening copolymerization with a functional monomer, the use of functional initiator and various post polymerization modifications. It is possible to obtain the star shaped polymer using natural oil with at least three OH groups as an initiator. It was estimated that despite of low-molecular mass of star-shaped PLA, the hydrophobic castor oil central core influenced the slow degradation rate in the case of injectable biomedical application. The star-shaped polymers with low-molecular-mass have a lower melt viscosity correlated with linear counterparts. In soft tissue reparation the polymer viscosity increases with fluid body contact and the solid implant can be formed. To ensure liquid state at injection temperature the low molar mass polymer is favorable. There is a particular size for each macromolecular chains at which chain entanglement occurs. In this work the influence of the l-lactide (LA) and the castor oil (CO) contents on the size of biodegradable branched polyester polyols was studied. The average molecular masses of synthesized polymers were estimated by GPC procedure. In sample formulations the [LA]/[CO] ratios were from to 113 to 533. Mn values for obtained polymers were from 5000 to 20000 Da. The molecular mass distribution for the resulting polymers was between 1.09 and 1.37.

  14. Fatty acid methyl esters (FAMEs) from castor oil: Production process assessment and synergistic effects in its properties

    Energy Technology Data Exchange (ETDEWEB)

    Canoira, Laureano; Garcia Galean, Juan; Alcantara, Ramon [Department of Chemical Engineering and Fuels, ETS Ingenieros de Minas, Universidad Politecnica de Madrid, Rios Rosas 21, 28003 Madrid (Spain); Lapuerta, Magin; Garcia-Contreras, Reyes [Maquinas y Motores Termicos, ETS Ingenieros Industriales, Universidad de Castilla La Mancha, Avda. Camilo Jose Cela s/n, 13071 Ciudad Real (Spain)

    2010-01-15

    Fatty acid methyl esters (FAMEs) from castor oil have been synthesized by methanolysis catalyzed by sodium methoxide and the optimal transesterification conditions have been found. However, some properties of the castor FAME render it unsuitable in pure state for its direct use as fuel in internal combustion engines. Thus, blends with reference diesel have been prepared and their properties have been evaluated. Among these properties, the oxidative stability of the blends shows a negative anti-synergistic effect, that is, all the blends have an induction period lower than the pure reference diesel and the pure castor FAME. On the contrary, the lubricity shows a positive synergistic effect, the wear scar of the blends being always lower than those of the pure components. The cold-filter plugging point of the blends shows also a singular effect, since the filterability remains identical to that of the reference diesel until around 50 vol% of castor FAME has been blended with it. The blends of castor FAME and reference diesel until approximately 40 vol% of castor FAME meet most of the specifications of the EN 590 standard. (author)

  15. Potential of castor bean (Ricinus communis L.) for phytoremediation of mine tailings and oil production.

    Science.gov (United States)

    Ruiz Olivares, Alejandro; Carrillo-González, Rogelio; González-Chávez, Ma del Carmen A; Soto Hernández, Ramón Marcos

    2013-01-15

    Bioenergy production combined with phytoremediation has been suggested to help in solving two critical world problems: the gradual reduction of fossil fuels and soil contamination. The aim of this research was to investigate the potential for the use of Ricinus communis L. (castor oil plant) as an energy crop and plant species to remediate metal-polluted sites. This study was performed in mine tailings containing high concentrations of Cu, Zn, Mn, Pb and Cd. Physico-chemical characterization, total, DTPA-extractable and water-soluble metals in rhizospheric tailings heap samples were carried. Metal concentrations in plant tissues and translocation factors (TFs) were also determined. The Ricinus seed-oil content was high between 41 and 64%, seeds from San Francisco site 6 had the highest oil content, while these from site 7 had the lowest. No trend between oil yield vs seed origin site was observed. Seed-oil content was negatively correlated with root concentration of Cu, Zn, Pb and Cd, but no correlation was observed with the extractable-metals. According to its shoot metal concentrations and TFs, castor bean is not a metal accumulator plant. This primary colonizing plant is well suited to cope with the local toxic conditions and can be useful for the stabilization of these residues, and for then decreasing metal bioavailability, dispersion and human health risks on these barren tailings heaps and in the surrounding area. Our work is the first report regarding combined oil production and a phytostabilization role for Ricinus plants in metal mine tailings and may give a new value to suitable metal-polluted areas.

  16. Castor (Ricinus communis L.)

    Science.gov (United States)

    The castor plant has been cultivated for thousands of years, providing a useful source of medicine, lamp fuel and lubricant long before petroleum came into wide use. The oil content of castor seed ranges from 45 to 60%, with most cultivars closer to 50% oil content. The presence of the hydroxy fatty...

  17. Toxicity of water-soluble fractions of biodiesel fuels derived from castor oil, palm oil, and waste cooking oil.

    Science.gov (United States)

    Leite, Maria Bernadete Neiva Lemos; de Araújo, Milena Maria Sampaio; Nascimento, Iracema Andrade; da Cruz, Andrea Cristina Santos; Pereira, Solange Andrade; do Nascimento, Núbia Costa

    2011-04-01

    Concerns over the sustained availability of fossil fuels and their impact on global warming and pollution have led to the search for fuels from renewable sources to address worldwide rising energy demands. Biodiesel is emerging as one of the possible solutions for the transport sector. It shows comparable engine performance to that of conventional diesel fuel, while reducing greenhouse gas emissions. However, the toxicity of products and effluents from the biodiesel industry has not yet been sufficiently investigated. Brazil has a very high potential as a biodiesel producer, in view of its climatic conditions and vast areas for cropland, with consequent environmental risks because of possible accidental biodiesel spillages into water bodies and runoff to coastal areas. This research determined the toxicity to two marine organisms of the water-soluble fractions (WSF) of three different biodiesel fuels obtained by methanol transesterification of castor oil (CO), palm oil (PO), and waste cooking oil (WCO). Microalgae and sea urchins were used as the test organisms, respectively, for culture-growth-inhibition and early-life-stage-toxicity tests. The toxicity levels of the analyzed biodiesel WSF showed the highest toxicity for the CO, followed by WCO and the PO. Methanol was the most prominent contaminant; concentrations increased over time in WSF samples stored up to 120 d.

  18. Analysis to foliate of mamoneira with emphasis in macronutrientes using organic garbage it is crooked of castor oil plant

    Directory of Open Access Journals (Sweden)

    Fabiana Xavier Costa

    2009-12-01

    Full Text Available Aimed with this work to evaluate the present macronutrientes in the leaves of the castor beans, in accomplished rehearsal being used the organic manuring front to three witness. The rehearsal was developed in the year of 2006, in house-of-vegetation of Embrapa Algodão, in Campina Grande PB. The treatments were constituted of the addition of the castor oil plant pie to the soil in the dosagens of 1, 2, 3, and 4 t. have-1 and I sand organic in the dosagens of 11,2; 22,4; 33,6 and 44,8 t. have-1 compared with three witness: the absolute (soil without addition of fertilizers; b he/she testifies relative 1 with the addition of NPK, in the dosagens of 180 kg N have-1, 64 kg P N have-1, 52 kg K have-1, he/she testifies relative 2, with addition of the micronutrients: boron (B, copper (Cu, iron (Fe, manganese (Mg and zinc (Zn , The used variable was her it analyzes to foliate to the 130 days after the emergency of the plântulas. An experimental design was used in blocks randomized with 11 treatments and four repetitions and the results of the macronutrientes were submitted to the variance analysis and of regression. The tenor of macronutrientes of the leaf of the castor beans had positive effect, when it was just used the castor oil plant pie in the variables. The composed of organic garbage didn't influence in the studied variables. Being, like this, the castor oil plant pie is constituted in a very interesting organic fertilizer for the growth, development, productivity and tenor of oil of the castor beans.

  19. Isocyanate-Functionalized Chitin and Chitosan as Gelling Agents of Castor Oil

    Directory of Open Access Journals (Sweden)

    José M. Franco

    2013-06-01

    Full Text Available The main objective of this work was the incorporation of reactive isocyanate groups into chitin and chitosan in order to effectively use the products as reactive thickening agents in castor oil. The resulting gel-like dispersions could be potentially used as biodegradable lubricating greases. Three different NCO–functionalized polymers were obtained: two of them by promoting the reaction of chitosan with 1,6-hexamethylene diisocyanate (HMDI, and the other by using chitin instead of chitosan. These polymers were characterized through 1H-NMR, FTIR and thermogravimetric analysis (TGA. Thermal and rheological behaviours of the oleogels prepared by dispersing these polymers in castor oil were studied by means of TGA and small-amplitude oscillatory shear (SAOS measurements. The evolution and values of the linear viscoelasticity functions with frequency for –NCO–functionalized chitosan- and chitin-based oleogels are quite similar to those found for standard lubricating greases. In relation to long-term stability of these oleogels, no phase separation was observed and the values of viscoelastic functions increase significantly during the first seven days of ageing, and then remain almost constant. TGA analysis showed that the degradation temperature of the resulting oleogels is higher than that found for traditional lubricating greases.

  20. The use of castor oil and ricinoleic acid in lead chalcogenide nanocrystal synthesis

    Science.gov (United States)

    Kyobe, Joseph W. M.; Mubofu, Egid B.; Makame, Yahya M. M.; Mlowe, Sixberth; Revaprasadu, Neerish

    2016-08-01

    A green solution-based thermolysis method for the synthesis of lead chalcogenide (PbE, E = S, Se, Te) nanocrystals in castor oil (CSTO) and its isolate ricinoleic acid (RA) is described. The blue shift observed from the optical spectra of CSTO and RA-capped PbE nanocrystals (NCs) confirmed the evidence of quantum confinement. The dimensions of PbE NCs obtained from NIR absorption spectra, transmission electron microscopy (TEM), and X-ray diffraction (XRD) studies were in good agreement. The particle sizes estimated were in the range of 20, 25, and 130 nm for castor oil-capped PbS, PbSe, and PbTe, respectively. Well-defined close to cubic-shaped particles were observed in the scanning electron microscopy (SEM) images of PbSe and PbTe nanocrystals. The high-resolution TEM and selective area electron diffraction (SAED) micrographs of the as-synthesized crystalline PbE NCs showed distinct lattice fringes with d-spacing distances corroborating with the standard values reported in literature.

  1. Hypersensitivity reaction studies of a polyethoxylated castor oil-free, liposome-based alternative paclitaxel formulation.

    Science.gov (United States)

    Wang, Hongbo; Cheng, Guang; Du, Yuan; Ye, Liang; Chen, Wenzhong; Zhang, Leiming; Wang, Tian; Tian, Jingwei; Fu, Fenghua

    2013-03-01

    The commercial drug paclitaxel (Taxol) may introduce hypersensitivity reactions associated with the polyethoxylated castor oil-ethanol solvent. To overcome these problems, we developed a polyethoxylated castor oil-free, liposome-based alternative paclitaxel formulation, known as Lipusu. In this study, we performed in vitro and in vivo experiments to compare the safety profiles of Lipusu and Taxol, with special regard to hypersensitivity reactions. First, Swiss mice were used to determine the lethal dosages, and then to evaluate hypersensitivity reactions, followed by histopathological examination and enzyme-linked immunosorbent assays (ELISAs) of serum SC5b-9 and lung histamine. Additionally, healthy human serum was used to analyze in vitro complement activation. Finally, an MTT assay was used to determine the in vitro anti-proliferation activity. Our data clearly showed that Lipusu displayed a much higher safety margin and did not induce hypersensitivity or hypersensitivity-related lung lesions, which may be associated with the fact that Lipusu did not activate complement or increase histamine release in vivo. Moreover, Lipusu did not promote complement activation in healthy human serum in vitro, and demonstrated anti-proliferative activity against human cancer cells, similar to that of Taxol. Therefore, the improved formulation of paclitaxel, which exhibited a much better safety profile and comparable cytotoxic activity to Taxol, may bring a number of benefits to cancer patients.

  2. Castor oil as secondary carbon source for production of sophorolipids using Starmerella bombicola NRRL Y-17069.

    Science.gov (United States)

    Bajaj, Vinit Kamalkishor; Annapure, Uday S

    2015-01-01

    Sophorolipids (SLs), a prominent member of the biosurfactants family are produced in acidic and/or lactonic form by yeast Starmerella bombicola NRRL Y-17069 when grown on hydrophilic or hydrophobic or both carbon sources. In current study, ricinoleic acid rich castor oil (10%) was used as hydrophobic and glycerol (10%) was used as hydrophilic carbon source. The yields of 24.5 ± 0.25 g/l sophorolipids were analyzed by anthrone and HPLC method which further increased upto 40.24 ± 0.76 g/l sophorolipids using fed batch process at 5L fermenter level. The structures of sophorolipids synthesized on castor oil were elucidated by liquid chromatography-mass spectrometer (LC-MS), (13)C and (1)H NMR. The results indicated that the ricinoleic acid (RA) gets hydroxylated at ω-1 position but incorporated into sophorolipids through already available hydroxyl group at 12(th) position. It resulted in the production of a novel sophorolipids with hydroxyl fatty acid as side chain and has applications as surfactant for novel drug delivery, anti microbial agent, cosmetic ingredient and emulsifier.

  3. [Analysis of Trace Inorganic Elements in Castor Oil by Inductively Coupled Plasma Mass Spectrometry].

    Science.gov (United States)

    Li, Tan-ping; Xie, Hua-lin; Nie, Xi-du

    2015-10-01

    A method for the determination of Na, Mg, Si, P, K, Ca, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Sr, Mo, Cd, Hg and Pb in castor oil after direct dilution with ethanol by inductively coupled plasma mass spectrometry (ICP-MS) was established. The sample was diluted by ethanol before ICP-MS determination. The condensation and deposition of high concentrations of carbon in mass cone interface and ion lens, which will decrease the sensitivity of element analysis, were avoided effectively by introducing O2 to plasma. The mass spectral interferences were eliminated by octopole reaction system (ORS). The matrix effects were calibrated to using Sc, Ge, Rh and Ir as internal standard elements. Au standard solution, which could form amalgam alloy with Hg, was dropped to eliminate the memory effect of Hg. The results show that the correlation coefficient for analyte is no less than 0.999 5, the detection limits is in the range of 0.06 - 20.1 ng x L(-1), the recovery is in the range of 990.4% - 110.2%, and the RSD is less than 4.8%. This method was very fast, simple and accurate to simultaneously analyze multi-elements in castor oil.

  4. Effect of hydroxypropyl methylcellulose and hydrogenated castor oil on naproxen release from sustained-release tablets.

    Science.gov (United States)

    Amaral, M H; Lobo, J M; Ferreira, D C

    2001-04-09

    The effect of the concentration of hydrophilic (hydroxypropyl methylcellulose [HPMC]) and hydrophobic (hydrogenated castor oil [HCO]) products, fillers (lactose and dibasic calcium phosphate), and buffers (sodium bicarbonate, calcium carbonate, and sodium citrate) on naproxen release rate was studied. Matrix tablets were prepared by double compression, and in vitro dissolution tests were performed. The dissolution results showed that an increased amount of HPMC or hydrogenated castor oil resulted in reduced drug release. The inclusion of buffers in the HPMC matrix tablets enhanced naproxen release. For HCO tablets, only sodium bicarbonate enhanced naproxen release. The presence of lactose on HPMC matrix tablets did not show a significantly different result from that obtained with the formulation containing dibasic calcium phosphate as a filler. However, for the tablets containing HCO, the presence of lactose significantly enhanced the naproxen release rate. The matrix-forming materials in this study were suitable for use in sustained-release tablets containing naproxen. The drug release can be modulated by adding suitable amounts of diluents and buffers.

  5. Polyurethane and polyurea nanoparticles based on polyoxyethylene castor oil derivative surfactant suitable for endovascular applications.

    Science.gov (United States)

    Morral-Ruíz, Genoveva; Melgar-Lesmes, Pedro; García, María Luísa; Solans, Conxita; García-Celma, María José

    2014-01-30

    The design of new, safe and effective nanotherapeutic systems is an important challenge for the researchers in the nanotechnology area. This study describes the formation of biocompatible polyurethane and polyurea nanoparticles based on polyoxyethylene castor oil derivative surfactant formed from O/W nano-emulsions by polymerization at the droplet interfaces in systems composed by aqueous solution/Kolliphor(®) ELP/medium chain triglyceride suitable for intravenous administration. Initial nano-emulsions incorporating highly hydrophilic materials were prepared by the phase inversion composition (PIC) method. After polymerization, nanoparticles with a small particle diameter (25-55 nm) and low polydispersity index were obtained. Parameters such as concentration of monomer, O/S weight ratio as well as the polymerization temperature were crucial to achieve a correct formation of these nanoparticles. Moreover, FT-IR studies showed the full conversion of the monomer to polyurethane and polyurea polymers. Likewise the involvement of the surfactant in the polymerization process through their nucleophilic groups to form the polymeric matrix was demonstrated. This could mean a first step in the development of biocompatible systems formulated with polyoxyethylene castor oil derivative surfactants. In addition, haemolysis and cell viability assays evidenced the good biocompatibility of KELP polyurethane and polyurea nanoparticles thus indicating the potential of these nanosystems as promising drug carriers.

  6. Sugarcane bagasse and castor oil polyurethane adhesive-based particulate composite

    Directory of Open Access Journals (Sweden)

    Juliano Fiorelli

    2013-04-01

    Full Text Available This paper discusses the potential use of sugarcane bagasse in two different fiber lengths (5 mm and 8 mm of the same density as a raw material for the production of particleboards, using castor oil-based two-component polyurethane adhesive. The quality of the product that can be manufactured industrially was evaluated based on density, thickness swell (TS, absorption (WA, modulus of elasticity (MOE, modulus of rupture (MOR in static bending and internal bond (IB, according to the Brazilian NBR 14.810:2006 standard. The results revealed a significant difference between the particleboards made with 5-mm-long fibers and those made with 8-mm-long fibers. An analysis by scanning electron microscopy (SEM indicates that the interparticle spaces are filled with castor oil-based two-component polyurethane adhesive, contributing to improve the physicomechanical properties of the particleboards. A durability assessment based on accelerated aging tests shows that waterproofed particleboards can be used in moist environments.

  7. Bio-based polyurethane prepared from Kraft lignin and modified castor oil

    Directory of Open Access Journals (Sweden)

    L. B. Tavares

    2016-11-01

    Full Text Available Current challenges highlight the need for polymer research using renewable natural sources as a substitute for petroleum-based polymers. The use of polyols obtained from renewable sources combined with the reuse of industrial residues such as lignin is an important agent in this process. Different compositions of polyurethane-type materials were prepared by combining technical Kraft lignin (TKL with castor oil (CO or modified castor oil (MCO1 and MCO2 to increase their reactivity towards diphenylmethane diisocyanate (MDI. The results indicate that lignin increases the glass transition temperature, the crosslinking density and improves the ultimate stress especially for those prepared from MCO2 and 30% lignin content from 8.2 MPa (lignin free to 23.5 MPa. Scanning electron microscopy (SEM micrographs of rupture surface after uniaxial tensile tests show ductile-to-brittle transition. The results show the possibility to develop polyurethane-type materials, varying technical grade Kraft lignin content, which cover a wide range of mechanical properties (from large elastic/low Young modulus to brittle/high Young modulus polyurethanes.

  8. Isocyanate-functionalized chitin and chitosan as gelling agents of castor oil.

    Science.gov (United States)

    Gallego, Rocío; Arteaga, Jesús F; Valencia, Concepción; Franco, José M

    2013-06-03

    The main objective of this work was the incorporation of reactive isocyanate groups into chitin and chitosan in order to effectively use the products as reactive thickening agents in castor oil. The resulting gel-like dispersions could be potentially used as biodegradable lubricating greases. Three different NCO-functionalized polymers were obtained: two of them by promoting the reaction of chitosan with 1,6-hexamethylene diisocyanate (HMDI), and the other by using chitin instead of chitosan. These polymers were characterized through 1H-NMR, FTIR and thermogravimetric analysis (TGA). Thermal and rheological behaviours of the oleogels prepared by dispersing these polymers in castor oil were studied by means of TGA and small-amplitude oscillatory shear (SAOS) measurements. The evolution and values of the linear viscoelasticity functions with frequency for -NCO-functionalized chitosan- and chitin-based oleogels are quite similar to those found for standard lubricating greases. In relation to long-term stability of these oleogels, no phase separation was observed and the values of viscoelastic functions increase significantly during the first seven days of ageing, and then remain almost constant. TGA analysis showed that the degradation temperature of the resulting oleogels is higher than that found for traditional lubricating greases.

  9. Castor oil transesterification reaction: A kinetic study and optimization of parameters

    Energy Technology Data Exchange (ETDEWEB)

    Ramezani, K. [Fuel Cell Research Laboratory, Green Research Center, Iran University of Science and Technology, Tehran (Iran); Rowshanzamir, S. [Fuel Cell Research Laboratory, Green Research Center, Iran University of Science and Technology, Tehran (Iran); School of Chemical Engineering, Iran University of Science and Technology, Tehran (Iran); Eikani, M.H. [Department of Chemical Industries, Iranian Research Organization for Science and Technology (IROST), Tehran (Iran)

    2010-10-15

    In this paper, parameters affecting castor oil transesterification reaction were investigated. Applying four basic catalysts including NaOCH{sub 3}, NaOH, KOCH{sub 3} and KOH the best one with maximum biodiesel yield was identified. Using Taguchi method consisting four parameters and three levels, the best experimental conditions were determined. Reaction temperature (25, 65 and 80 C), mixing intensity (250, 400 and 600 rpm), alcohol/oil ratio (4:1, 6:1 and 8:1) and catalyst concentration (0.25, 0.35 and 0.5%) were selected as experimental parameters. It was concluded that reaction temperature and mixing intensity can be optimized. Using the optimum results, we proposed a kinetic model which resulted in establishing an equation for the beginning rate of transesterification reaction. Furthermore, applying ASTM D 976 correlation, minimum cetane number of produced biodiesel was determined as 37.1. (author)

  10. Biodiesel Production from Castor Oil by Using Calcium Oxide Derived from Mud Clam Shell

    Directory of Open Access Journals (Sweden)

    S. Ismail

    2016-01-01

    Full Text Available The catalytic potential of calcium oxide synthesized from mud clam shell as a heterogeneous catalyst for biodiesel production was studied. The mud clam shell calcium oxide was characterized using particle size analyzer, Fourier transform infrared spectroscopy, scanning electron microscopy, and BET gas sorption analyzer. The catalyst performance of mud clam shell calcium oxide was studied in the transesterification of castor oil as biodiesel. Catalyst characterization and transesterification study results of synthesized catalyst proved the efficiency of the natural derived catalyst for biodiesel production. A highest biodiesel yield of 96.7% was obtained at optimal parameters such as 1 : 14 oil-to-methanol molar ratio, 3% w/w catalyst concentration, 60°C reaction temperature, and 2-hour reaction time. Catalyst reusability test shows that the synthesized calcium oxide from mud clam shell is reusable up to 5 times.

  11. 蓖麻油多官能团反应进展%Castor Oil Functional Reaction Review

    Institute of Scientific and Technical Information of China (English)

    张海飞; 朱新宝

    2015-01-01

    Castor oil molecules contain functional groups such as hydroxyl,ester group,ethylenic bond,two or three kinds of functional groups can perform a series of chemical reactions,which form many new castor oil deriva-tives,and develop many new application,now the series of chemical reactions were reviewed and classified,authors systematically introduced the reaction of castor oil and briefly described different a variety of purposes of product,to facilitate the design of the new reaction and the development of new products,to improve the castor oil deep process-ing technology.%蓖麻油分子中含有羟基、酯基、烯键等官能团,其中二种或三种官能团组合能进行一系列化学反应,已合成出许多新的蓖麻油衍生物,开发出很多新的用途,现对其系列化学反应进行综述归类,系统地介绍蓖麻油多官能团组合所能发生的反应,简述不同反应产物的多种用途,便于新反应的设计和新产品的开发,提高蓖麻油深加工技术。

  12. The effects of possible contamination on the radiocarbon dating of the Dead Sea Scrolls I : Castor oil

    NARCIS (Netherlands)

    Rasmussen, KL; van der Plicht, J; Cryer, FH; Doudna, G; Cross, FM; Strugnell, J; Rasmussen, Kaare L.; Cryer, Frederick H.; Cross, Frank M.

    2001-01-01

    Some fragments of the Dead Sea Scroll manuscripts were contaminated with castor oil in the late 1950s. We have conducted experiments in order to establish if the AAA pretreatment cleaning procedures conducted on Dead Sea Scroll manuscript samples in the last two dating series (Bonani et al. 1992; Ju

  13. Rhipicephalus sanguineus (Acari: Ixodidae) female ticks exposed to castor oil (Ricinus communis): an ultrastructural overview.

    Science.gov (United States)

    Sampieri, B R; Furquim, K C S; Nunes, P H; Camargo-Mathias, M I

    2013-02-01

    Tick control has been accomplished through the use of synthetic acaricides, which has created resistant individuals, as well as contaminating the environment and nontarget organisms. Substances of plant origin, such as oils and extracts of eucalyptus and neem leaves, have been researched as an alternative to replace the synthetic acaricides. Ricinoleic acid esters from castor oil have recently been shown as a promising alternative in eliminating bacterial contamination during ethanol fermentation, by acting as an effective biocide. The same positive results have been observed when these esters are added to the food given to tick-infested rabbits. This study tested the effect of these substance on the reproductive system of Rhipicephalus sanguineus females, added to rabbit food, more specifically on oogenesis. For this, four groups were established: four control groups (CG1, CG2, CG3, and CG4) and four treatment groups (TG1, TG2, TG3, and TG4) with one rabbit in each (New Zealand White), used as hosts. After full 4 days feeding (semi-engorgement), the females were collected and had their ovaries extracted. In this study, it was observed that R. sanguineus females exposed to esters had their ovaries modified, which was demonstrated through transmission electron microscopy techniques. The addition of ricinoleic esters to the diet of tick-infested rabbits revealed how toxic such substances are for the cytoplasmic organelles of oocytes and pedicel cells. These compounds can change the morphophysiology of germ and somatic cells, consequently influencing their viability and, therefore, confirming that the ricinoleic acid esters from castor oil are a promising substance in the control of R. sanguineus.

  14. Detailed molecular characterization of castor oil ethoxylates by liquid chromatography multistage mass spectrometry.

    Science.gov (United States)

    Nasioudis, Andreas; van Velde, Jan W; Heeren, Ron M A; van den Brink, Oscar F

    2011-10-07

    The molecular characterization of castor oil ethoxylates (CASEOs) was studied by reverse-phase liquid chromatography (RPLC) mass spectrometry (MS) and multistage mass spectrometry (MS(n)). The developed RPLC method allowed the separation of the various CASEO components, and especially, the baseline separation of multiple nominal isobars (same nominal mass) and isomers (same exact mass). MS and MS(n) were used for the determination and structure elucidation of various structures and for the discrimination of the isobars and isomers. Different ionization techniques and adduct ions were also tested for optimization of the MS detection and the MS(n) fragmentation. A unique fragmentation pathway of ricinoleic acid is proposed, which can be used as a marker of the polymerization process and the topology of ethoxylation in the CASEO. In addition, characteristic neutral losses of ricinoleic acid reveal its (terminal or internal) position in the molecule.

  15. An examination of the effect of castor oil packs on constipation in the elderly.

    Science.gov (United States)

    Arslan, Gülşah Gürol; Eşer, Ismet

    2011-02-01

    This research, conducted at two rest homes in Manisa, Turkey, was undertaken to examine the effect of castor oil pack (COP) administrations on constipation in the elderly. Study participants were monitored for 7 days before, 3 days during, and 4 days after COP administration utilizing the Recall Bias and Visual Scale Analog (RB-VSAQ) as well as the Standard Diary developed by Pamuk et al. Wilcoxon Signed Ranks, Repeated Measures, Bonferroni, and Mann-Whitney U tests were used for data analysis. Eighty percent of study subjects had been constipated for 10 years or longer. COP administration did not have an effect on the number of bowel movements or amount of feces, but decreased the feces consistency score, straining during defecation and feeling of complete evacuation after a bowel movement, thus decreasing symptoms of constipation. We conclude that COP may be used for controlling symptoms of constipation.

  16. High pressure changes of the castor oil viscosity by ultrasonic method

    Science.gov (United States)

    Rostocki, A. J.; Siegoczyński, R. M.; Kielczyński, P.; Szalewski, M.

    2008-07-01

    The pressure change of viscosity of castor oil have been measured by ultrasonic method within the range of pressure up to 0.9 GPa. For the measurement, the authors have applied a new ultrasonic method based on Bleustein-Gulyaev (B-G) waves. For the lower pressures (up to 0.3 GPa) the results have been compared with earlier results obtained by falling body method, whereas for the higher pressure range results were compared with those obtained by the flow type viscometer. The measurements have shown: 1. Exponential rise of viscosity with pressure up to 0.4 GPa according to the Barus formula. 2. Extraordinary increment of viscosity at constant pressure during phase transition. 3. The decomposition of the high pressure phase during the decompression process have shown very large hysteresis of viscosity on pressure. 4. After the decompression process the viscosity lasts higher then a initial value for several hours.

  17. Castor oil and commercial thermoplastic polyurethane membranes modified with polyaniline: a comparative study

    Energy Technology Data Exchange (ETDEWEB)

    Almeida Junior, Jose Humberto Santos; Meneguzzi, Alvaro; Ferreira, Carlos Arthur, E-mail: jhsajunior@globomail.com [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegtre, RS (Brazil). Dept. de Engenharia de Materiais; Bertuol, Daniel Assumpcao [Universidade Federal de Santa Maria (UFSM), RS (Brazil). Dept. de Engenharia Quimica; Amado, Franco Dani Rico [Universidade Estadual de Santa Cruz (UESC), Ilheus, BA (Brazil). Dept. de Ciencias Exatas e Tecnologia

    2013-11-01

    The study of conducting polymeric membranes is decisive in some areas, as in fuel cells and electrodialysis. This work aims the study of membranes using conventional and conductive polymers blends. Two types of polyurethane were used as conventional polymers, commercial thermoplastic polyurethane and polyurethane synthesized from castor oil and 4-4-dicyclohexylmethane isocyanate. Two kinds of conducting polymers were used, polyaniline doped with organic acid and a self doped polyaniline. The polymers and the membranes were characterized by electrical conductivity, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and scanning electron microscopy (SEM). The synthesis of the membranes produced was proper, featuring a complete reaction, analyzed by FTIR. The membranes also showed good mechanical properties and thermal stability ( Almost-Equal-To 220 Degree-Sign C). Among the membranes studied, the polyaniline doped with p-toluenesulphonic acid obtained higher thermal and viscoelastic properties. Thus they can be used in separation techniques using membranes. (author)

  18. Isolation and Characterization of Castor Seed Oil and Its Utilization Potential in the Production of Polyurethane Foam

    Directory of Open Access Journals (Sweden)

    Aishat IMASUEN

    2014-05-01

    Full Text Available Firm polyurethane (PU foams were prepared using Nigerian grown brown and white castor seed oil starting materials extracted at ambient temperature. Polyol with terminal primary hydroxyl groups synthesized from crude castor oil were reacted with aromatic diphenylmethane diisocyanate to prepare the foams. Castor seeds were decorticated and milled, after which they were weighed into filter bags for expression at ambient temperature, 50, 100 and 150 °C respectively at a constant pressure of 2 ton. Evaluation of the oil yield shows that the brown seeds with lower weight at a temperature of 150 °C gave a high yield of 54.79 %, compared to high weight at ambient temperature, which yielded 29.45 %. The white seeds with lower weight at a temperature of 150 °C gave high yields of 52.75 %, compared to higher weight at ambient temperature yielding 30.06 %. The oil was characterized in terms of moisture content, volatile content, acid value, free fatty acid and saponification value. The results are within the range reported in literature. In-situ polymerization was used in the production of polyurethane foam using the extracted oil as polyol. The results of the foam characterization in terms of compression set and density conform to standard foams.doi:10.14456/WJST.2014.20

  19. Evaluating the effect of temperature on biodiesel production from castor oil

    Directory of Open Access Journals (Sweden)

    Carlos Alberto Guerrero Fajardo

    2010-06-01

    Full Text Available Problems arising between biofuels and food as raw materials have led to investigating the use of inedible raw materials for their production. This work was aimed at studying the effect of temperature on converting castor oil in biodiesel production. Oil transesterification with methanol was carried out using an alkaline catalyst (0.5% NaOH - water solution for 1 hour using a 6:1 alcohol/oil molar ratio, at atmospheric pressure and taking temperature as a free variable. The temperature was evaluated at 68°F, 86°F, 104°F and 122ºF. The reaction products were analyzed by gas chromatography (CG-FID for quantifying the fatty acid methyl esters (FAME present. The results showed different dispersion depending on temperature, finding that 122°F resulted in less dispersion than the others. CG-FID analysis showed that most FAME content was reached at 122ºF, such temperature giving the highest ricinoleic acid conversion rate. Gas chromatography also revealed that reaction time was adequate, in process conditions, for obtaining ricinoleic acid-based 94.26% con- version.

  20. Síntesis y caracterización de espumas flexibles de poliuretano obtenidas a partir de aceite de castor maleinizado Flexible polyurethane foam synthesis and characterization obtained from maleinizated castor oil

    Directory of Open Access Journals (Sweden)

    Paula Mazo

    2009-06-01

    Full Text Available En este trabajo se realiza la síntesis de espumas flexibles de poliuretano empleando un diseño experimental Taguchi, utilizando aceite de castor con y sin maleinización, se estudia la cinética de la reacción de esterificación del aceite por cuantificación de los grupos ácido (ASTM D4662 - 03 y se evalúan las propiedades mecánicas de las espumas (densidad, resistencia tensil, % elongación, resiliencia y dureza. Norma NTC 2019 Icontec obtenidas en función de las variables de síntesis (cantidad y tipo de catalizador, relación molar aceite castor (CO - aceite maleinizado (MACO, cantidad de agua y surfactante empleado. Se realizan análisis de FTIR y SEM para las espumas. Los resultados mostraron una cinética de primer orden con respecto al anhídrido. El aceite maleinizado (MACO incrementa la resistencia mecánica de las espumas, debido al mayor entrecruzamiento por la incorporación de grupos ácido.In this work, the synthesis of polyurethane flexible foam is realized with the experimental design Taguchi, using castor oil with and without maleinization. The kinetic reaction of oil esterification was monitored by estimating the number of acid groups (ASTM D4662 - 03, and the mechanical properties of the foam were studied, including density, tensile resistance, % elongation, resilience and hardness (Norm NTC 2019 Icontec. The influence of various synthesis parameters was investigated, namely amount and type of catalyst, molar ratio of castor oil (CO - maleinizated castor oil (MACO, amount of water and surfactant used. The foams were analyzed using FTIR and scanning electron microscopy (SEM. The results showed first order kinetics with respect to the anhydride. The maleinizated castor oil (MACO increased the mechanical resistance of the foam due to the greater interweaving by the incorporation of acid groups.

  1. Solvent-free enzymatic synthesis of feruloylated structured lipids by the transesterification of ethyl ferulate with castor oil.

    Science.gov (United States)

    Sun, Shangde; Zhu, Sha; Bi, Yanlan

    2014-09-01

    A novel enzymatic route of feruloylated structured lipids synthesis by the transesterification of ethyl ferulate (EF) with castor oil, in solvent-free system, was investigated. The transesterification reactions were catalysed by Novozym 435, Lipozyme RMIM, and Lipozyme TLIM, among which Novozym 435 showed the best catalysis performance. Effects of feruloyl donors, reaction variables, and ethanol removal on the transesterification were also studied. High EF conversion (∼100%) was obtained under the following conditions: enzyme load 20% (w/w, relative to the weight of substrates), reaction temperature 90 °C, substrate molar ratio 1:1 (EF/castor oil), 72 h, vacuum pressure 10 mmHg, and 200 rpm. Under these conditions, the transesterification product consisted of 62.6% lipophilic feruloylated structured lipids and 37.3% hydrophilic feruloylated lipids.

  2. Fatty Acid Profile of Cheese from Dairy Goats Fed a Diet Enriched with Castor, Sesame and Faveleira Vegetable Oils

    Directory of Open Access Journals (Sweden)

    Ertha Medeiros

    2014-01-01

    Full Text Available The addition of vegetable oils to the diets of dairy goats is an alternative to supplemental feeding during the dry period and improves the lipid profile of milk and by-products. Cheeses were produced using milk from cross bred goats (Saanen × Alpina fed diets enriched with 4% vegetable oil (faveleira, sesame or castor, the fatty acid profile of cheeses was studied. Supplementation with vegetable oils did not increase the total fat percentage of the cheese (p ≥ 0.05 but did increase the percentage of CLA isomers, long-chain fatty acids (LCFA and polyunsaturated fatty acids (PUFA; in addition, the index of desirable fatty acids (DFA - expressed as the sum of unsaturated fatty acids plus stearic acid was increased for cheese made from milk from goats fed sesame or faveleira oil. Cheeses may have had increased percentages of cis-9,trans-11-CLA due to the supplementation of animal diets with vegetable oils rich in C18:2, such as faveleira and sesame oils. The fatty acid profile of goat cheese did not change significantly in response to the use of castor oil. Thus, the addition of sesame and faveleira oils to goat diets positively altered the fatty acid profile, which improved the nutritional characteristics of the fat present in goat cheese.

  3. Final report on the safety assessment of Ricinus Communis (Castor) Seed Oil, Hydrogenated Castor Oil, Glyceryl Ricinoleate, Glyceryl Ricinoleate SE, Ricinoleic Acid, Potassium Ricinoleate, Sodium Ricinoleate, Zinc Ricinoleate, Cetyl Ricinoleate, Ethyl Ricinoleate, Glycol Ricinoleate, Isopropyl Ricinoleate, Methyl Ricinoleate, and Octyldodecyl Ricinoleate.

    Science.gov (United States)

    2007-01-01

    The oil derived from the seed of the Ricinus communis plant and its primary constituent, Ricinoleic Acid, along with certain of its salts and esters function primarily as skin-conditioning agents, emulsion stabilizers, and surfactants in cosmetics, although other functions are described. Ricinus Communis (Castor) Seed Oil is the naming convention for castor oil used in cosmetics. It is produced by cold pressing the seeds and subsequent clarification of the oil by heat. Castor oil does not contain ricin because ricin does not partition into the oil. Castor oil and Glyceryl Ricinoleate absorb ultraviolet (UV) light, with a maximum absorbance at 270 nm. Castor oil and Hydrogenated Castor Oil reportedly were used in 769 and 202 cosmetic products, respectively, in 2002; fewer uses were reported for the other ingredients in this group. The highest reported use concentration (81%) for castor oil is associated with lipstick. Castor oil is classified by Food and Drug Administration (FDA) as generally recognized as safe and effective for use as a stimulant laxative. The Joint Food and Agriculture Organization (FAO)/World Health Organization (WHO) Expert Committee on Food Additives established an acceptable daily castor oil intake (for man) of 0 to 0.7 mg/kg body weight. Castor oil is hydrolyzed in the small intestine by pancreatic enzymes, leading to the release of glycerol and Ricinoleic Acid, although 3,6-epoxyoctanedioic acid, 3,6-epoxydecanedioic acid, and 3,6-epoxydodecanedioic acid also appear to be metabolites. Castor oil and Ricinoleic Acid can enhance the transdermal penetration of other chemicals. Although chemically similar to prostaglandin E(1), Ricinoleic Acid did not have the same physiological properties. These ingredients are not acute toxicants, and a National Toxicology Program (NTP) subchronic oral toxicity study using castor oil at concentrations up to 10% in the diet of rats was not toxic. Other subchronic studies of castor oil produced similar findings

  4. Morphology of autogenous bone graft and castor oil polyurethane in the infraorbital rim of rabbits: a comparative study

    Directory of Open Access Journals (Sweden)

    Mendonça José Carlos Garcia de

    2006-01-01

    Full Text Available PURPOSE: Morphological study comparing castor oil polyurethane and autogenous bone graft to repair bone defect in zygomatic bone of rabbits. METHODS: Twenty-four adult, male New Zealand rabbits were randomly distributed between two groups of twelve. Bone defects of 5mm in diameter were cut through the zygomatic bone and filled with polyurethane discs in the experimental group or autogenous bone harvested from the tibia in the control group. Animals were sacrificed after 30, 60 or 90 days, and the zygomatic bones were macro- and microscopically analyzed. Student's, Fisher's, chi-squared and McNemar's tests were used for statistical analysis. RESULTS: Both the castor oil polyurethane and the autograft adapted well to the defect, with no need for fixation. Fibrous connective tissue encapsulated the polyurethane, but no inflammation or giant cell reaction was observed. Acidophilic and basophilic areas were observed inside the micropores of the polyurethane, suggesting cell nuclei. After 90 days, bone repair with a lamellar pattern of organization was observed in the control group. CONCLUSION: The castor oil polyurethane was biocompatible and did not cause inflammation. It may be considered an alternative to fill bone defects.

  5. ROMP-based thermosetting polymers from modified castor oil with various cross-linking agents

    Science.gov (United States)

    Ding, Rui

    Polymers derived from bio-renewable resources are finding an increase in global demand. In addition, polymers with distinctive functionalities are required in certain advanced fields, such as aerospace and civil engineering. In an attempt to meet both these needs, the goal of this work aims to develop a range of bio-based thermosetting matrix polymers for potential applications in multifunctional composites. Ring-opening metathesis polymerization (ROMP), which recently has been explored as a powerful method in polymer chemistry, was employed as a unique pathway to polymerize agricultural oil-based reactants. Specifically, a novel norbornyl-functionalized castor oil alcohol (NCA) was investigated to polymerize different cross-linking agents using ROMP. The effects of incorporating dicyclopentadiene (DCPD) and a norbornene-based crosslinker (CL) were systematically evaluated with respect to curing behavior and thermal mechanical properties of the polymers. Isothermal differential scanning calorimetry (DSC) was used to investigate the conversion during cure. Dynamic DSC scans at multiple heating rates revealed conversion-dependent activation energy by Ozawa-Flynn-Wall analysis. The glass transition temperature, storage modulus, and loss modulus for NCA/DCPD and NCA/CL copolymers with different cross-linking agent loading were compared using dynamic mechanical analysis. Cross-link density was examined to explain the very different dynamic mechanical behavior. Mechanical stress-strain curves were developed through tensile test, and thermal stability of the cross-linked polymers was evaluated by thermogravimetric analysis to further investigate the structure-property relationships in these systems.

  6. Intake, nutrient apparent digestibility and ruminal constituents of sheep fed diets with canola, sunflower or castor oils

    Directory of Open Access Journals (Sweden)

    Michelle de Oliveira Maia

    2012-11-01

    Full Text Available The objective in this experiment was to determine the effects of feeding diets with canola, sunflower or castor oils on intake, nutrient apparent digestibility and ruminal constituents of crossbred Dorper × Santa Inês sheep. Four rumen-cannulated animals of 90.2±11.4 kg average body weight were assigned to a 4 × 4 latin square. Animals remained individually in cages for the metabolism assay and were fed diets containing roughage at 500 g/kg and concentrate based on ground corn and soybean meal also at 500 g/kg. No oil was added to the control diet, whereas the others had canola, sunflower or castor oils at 30 g/kg (DM basis. There was no difference for the intake of DM and nutrients, except for ether extract, which was greater when animals received oil. The digestibility coefficients of dry matter, organic matter, crude protein, non-fiber carbohydrates and neutral detergent fiber were not changed; however, the addition of oil increased the ether extract digestibility. The values of total digestible nutrients (TDN, g/kg of DM, digestible energy (DE, Mcal/kg of DM, TDN intake and DE intake also did not change with the addition of lipids. Concerning the ruminal constituents, the addition of vegetable oils reduced the concentrations of acetate, butyrate and total short-chain fatty acids. Adding canola, sunflower or castor oils at 30 g/kg in diets with 500 g roughage/kg and 500 g concentrate/kg does not impair the intake or digestibility of nutrients in sheep, although it reduces the concentration of short-chain fatty acids in the rumen.

  7. Effects of compression ratio on variation of stresses and residual oil of cake in pressing process of castor beans and its curve fitting

    Institute of Scientific and Technical Information of China (English)

    刘汝宽; 许方雷; 肖志红; 李昌珠; 李辉; 曾凡涛; 叶红齐

    2015-01-01

    The relationships among compression ratio and stress, compression ratio and residual oil of cake in pressing process of castor beans were studied using the test equipment under different states of oilseeds and ways of pressing manners. The results show that variation of stress increases nonlinearly and residual oil rate decreases with the increase of compression ratio. Lower residual oil of cake was obtained by pressing gently and frequently. Curve fitting on both relationships had been built and parameters for the model were obtained by least square procedure and deepening research on pressing process of the castor beans for castor oil. By assuming that the value of oil production is equivalent to the value of energy consumption, the critical compression ratio of intact seeds is 6.2 while that of crushed seeds is 3.6.

  8. Computational identification and phylogenetic analysis of the oil-body structural proteins, oleosin and caleosin, in castor bean and flax.

    Science.gov (United States)

    Hyun, Tae Kyung; Kumar, Dhinesh; Cho, Young-Yeol; Hyun, Hae-Nam; Kim, Ju-Sung

    2013-02-25

    Oil bodies (OBs) are the intracellular particles derived from oilseeds. These OBs store lipids as a carbon resource, and have been exploited for a variety of industrial applications including biofuels. Oleosin and caleosin are the common OB structural proteins which are enabling biotechnological enhancement of oil content and OB-based pharmaceutical formations via stabilizing OBs. Although the draft whole genome sequence information for Ricinus communis L. (castor bean) and Linum usitatissimum L. (flax), important oil seed plants, is available in public database, OB-structural proteins in these plants are poorly indentified. Therefore, in this study, we performed a comprehensive bioinformatic analysis including analysis of the genome sequence, conserved domains and phylogenetic relationships to identify OB structural proteins in castor bean and flax genomes. Using comprehensive analysis, we have identified 6 and 15 OB-structural proteins from castor bean and flax, respectively. A complete overview of this gene family in castor bean and flax is presented, including the gene structures, phylogeny and conserved motifs, resulting in the presence of central hydrophobic regions with proline knot motif, providing an evolutionary proof that this central hydrophobic region had evolved from duplications in the primitive eukaryotes. In addition, expression analysis of L-oleosin and caleosin genes using quantitative real-time PCR demonstrated that seed contained their maximum expression, except that RcCLO-1 expressed maximum in cotyledon. Thus, our comparative genomics analysis of oleosin and caleosin genes and their putatively encoded proteins in two non-model plant species provides insights into the prospective usage of gene resources for improving OB-stability.

  9. A comparison of the efficacy, adverse effects, and patient compliance of the sena-graph®syrup and castor oil regimens for bowel preparation.

    Science.gov (United States)

    Ghazikhanlou Sani, Karim; Jafari, Mahmood-Reza; Shams, Safar

    2010-01-01

    Sena-Graph syrup has recently been formulated by an Iranian pharmaceutical company for being used in bowel evacuation before radiography, colonoscopy and surgery. This study compares the efficacy, adverse effects and patient compliance of two bowel preparation regimens with castor oil and Sena-Graph syrup in of outpatients for Intravenous Urography (IVU). One hundred and fourteen consecutive outpatients were randomized to receive either the standard bowel preparation with 60 mL of castor oil or the test method with 60 mL of Sena-Graph syrup before IVU examination. Demographic data of patients and their prior bowel preparation experience were collected before the examination. Two radiologists, blinded to the method of bowel preparation, reviewed the radiographs and graded the bowel preparation. The compliance and acceptability of both regimens were assessed by using structured questionnaires filled by the patients. The Numbers, ages, weights and gender distribution of patients and their prior bowel preparation experience in the two groups did not differ significantly. The cleanliness scores for the castor oil and Sena-Graph group were 3.97 ± 0.971 and 4.87 ± 0.917, respectively. The results indicated that Sena-Graph syrup causes a better bowel cleansing compared castor oil. Adverse effects in Sena-Graph groups were significantly lower than the castor oil group. Acceptability of the regimen in patients who used Sena-Graph was higher than the other group. The Sena-Graph regimen is significantly more effective and better tolerated than of Castor oil regimen in bowel cleansing. The incidence and severity of the adverse effects from Castor oil was higher than Sena-Graph.

  10. A COMPARATIVE STUDY OF CASTOR AND JATROPHA OIL SOURCE AND ITS METHYL ESTER TEST ON THE DIESEL ENGINE

    Directory of Open Access Journals (Sweden)

    DEVENDRA VASHIST,

    2011-06-01

    Full Text Available Neat non-edible oils pose problems when subjected to use when used in the CI engines. These problems are attributed to high viscosity, low volatility and polyunsaturated character of these oils. Two non-edible sources of the oils were identified i.e jatropha and castor. The biodiesel was prepared from neat oils and blends preparedwith diesel. up till 20 percent of biodiesel. Produced blends were tested for their use as a substitute fuel for diesel in a single cylinder diesel engine at varying loads. The best engine operating condition based on lower brake specific fuel consumption and higher brake thermal efficiency were identified and compared. On the observed data for both the fuels, Chi square (2 statistical test was applied. The values calculated for 2 jatropha oil methyl ester (JOME = 0.0104 and 2 castor oil methyl ester (COME = 0.0524. The values concluded that there is no effect of fuel type on fuel consumption up till 20 percent biodiesel blended fuel.

  11. Effect of fermentation period on the organic acid and amino acid contents of Ogiri from castor oil bean seeds

    Directory of Open Access Journals (Sweden)

    Ojinnaka, M-T. C.

    2013-01-01

    Full Text Available Aims: To monitor the changes in the concentration of organic acid and amino acid contents during the fermentation of castor oil bean seed into ogiri.Methodology and results: In this study, ogiri, a Nigerian fermented food condiment was prepared from castor oil bean using Bacillus subtilis as a monoculture starter for the production of three different fermented castor oil bean condiment samples: B1 (0% NaCl/lime, B2 (2% NaCl, B3 (3% lime. Variations in the composition of the castor oil bean with fermentation over 96 h periods were evaluated for organic acid and amino acid contents using High Performance Liquid Chromatography. Organic acids were detected in the fermented castor oil bean samples as fermentation period increased to 96 h. Organic acids identified were oxalic, citric, tartaric, malic, succinic, lactic, formic, acetic, propionic and butyric acids. The lactic acid contents in sample B1 (0% NaCl/lime decreased initially and then increased as the fermentation period progressed. The value at 96 h fermentation was 1.336 µg/mL as against 0.775 µg/mL at 0 h fermentation. Sample B3 (3% lime had lactic acid content that increased as fermentation period increased with lactic acid content of 1.298 µg/mL at 96 h fermentation. The acetic acid content of sample B1 increased as fermentation progressed and at 96 h fermentation, its value was 1.204 µg/mL while those of B2 and B3 were 0.677 µg/mL and 1.401 µg/mL respectively. The three fermented castor oil bean samples also contained sufficient amount of amino acids. Sample B1 had the highest values in isoleucine glycine and histidine with values 1.382 µg/mL, 0.814 µg/mL and 1.022 µg/mL respectively while sample B2 had the highest value in leucine content with 0.915 µg/mL at 96 h fermentation, closely followed by sample B3 and B1 with 0.798 µg/mL and 0.205 µg/mL respectively. The results of amino acid analysis indicated a high concentration of all amino acids at 96 h of fermentation

  12. Preparation and characterization of activated carbon from castor de-oiled cake

    Directory of Open Access Journals (Sweden)

    Viviana M. Ospina-Guarín

    2014-01-01

    Full Text Available Biomass residues have been used to produce activated carbons. On this process, the activation method and the raw composition determine the properties as porosity and surface area of the charcoal. After the extraction of castor oil, there is a solid byproduct (cake of low added value, which was used in the production of activated carbon to add value to this waste. For this purpose two traditional methods were used, first, physical activation using as activating agents steam, CO2 and mixture of both, and additionally chemical activation using K2CO3 as the activating agent. Some activated carbons were characterized using N2 adsorption isotherms, BET surface areas varied between 255.98 (m2/g and 1218.43 (m2/g. By SEM and EDS analysis was possible to observe that materials obtained by the two types of activation are principally amorphous and morphological characteristics of the carbon obtained by physical activation are very different from those obtained by chemical activation. Finally, through impregnation of inorganic phases of Ni and Mo was revealed that the high dispersion characteristics, these carbonaceous materials will have potential to be used as catalyst support.

  13. CASTOR OIL-BASED BUILDING MATERIALS REINFORCED WITH FLY ASH, CLAY, EXPANDED PERLITE AND PUMICE POWDER

    Directory of Open Access Journals (Sweden)

    Figen Balo

    2011-09-01

    Full Text Available This paper reports the results of a study conducted to evaluate the influence of class C fly ash (FA, clay (C, expanded perlite (EP, pumice powder (PP and epoxidized castor oil (ECO on the density, thermal conductivity, compressive strength, tensile strength, abrasion loss and water absorption of building material. Density, thermal conductivity, compressive strength and tensile strength decreased with the increase of ECO and FA as replacement for building material. These properties also decreased with increasing process temperature. The addition of clay in the building material had an increasing effect on these properties. The addition of clay decreased abrasion loss and water absorption as a function of replacement percent. The minimum thermal conductivity and maximum water absorption observed for the sample made with minimum clay and maximum FA-ECO ratios processed at the highest process temperature. The maximum compression-tensile strengths and minimum abrasion loss observed for the sample with maximum clay and minimum FA-ECO ratios processed at the lowest process temperature.

  14. Water solubility enhancements of PAHs by sodium castor oil sulfonate microemulsions

    Institute of Scientific and Technical Information of China (English)

    ZHU Li-zhong; ZHAO Bao-wei; LI Zong-lai

    2003-01-01

    Water solubility enhancements of naphthalene(Naph), phenantherene(Phen) and pyrene(Py) in sodium castor oil sulfonate(SCOS) microemulsions were evaluated. The apparent solubilities of PAHs are linearly proportional to the concentrations of SCOS microemulsion, and the enhancement extent by SCOS solutions is greater than that by ordinary surfactants on the basis of weight solubilization ratio(WSR). The logKem values of Naph, Phen, and Py are 3.13, 4.44 and 5.01 respectively, which are about the same as the logKow values. At 5000 mg/L of SCOS conccentration, the apparent solubilities are 8.80, 121, and 674 times as the intrinsic solubilities for Naph, Phen, and Py. The effects of inorganic ions and temperature on the solubilization of solutes are also investigated. The solubilization is improved with a moderate addition of Ca2+, Na+, NH4+ and the mixture of Na+, K+, Ca2+, Mg2+ and NH4+. WSR values are enhanced by 22.0% for Naph, 23.4% for Phen, and 24.6% for Py with temperature increasing by 5℃. The results indicated that SCOS microemulsions improve the performance of the surfactant-enhanced remediation(SER) of soil, by increasing solubilities of organic pollutants and reducing the level of surfactant pollution and remediation expenses.

  15. Gamma radiation effects on mechanical properties and morphology of a polyurethane derivate from castor oil

    Science.gov (United States)

    Azevedo, Elaine Cristina; Orivaldo Chierice, Gilberto; Claro Neto, Salvador; Scheidegger Soboll, Daniel; Mauro Nascimento, Eduardo; Lepienski, Carlos Mauricio

    2011-03-01

    In this study, an adhesive of a polyurethane derivate from castor oil was irradiated with gamma radiation from a 60Co source, at doses from 0.2 to 25 kGy. This adhesive polyurethane is considered for use in hospital furniture because it does not liberate dangerous solvents. Hardness and elastic modulus were measured by instrumented indentation with a pyramidal Berkovich indenter, using loads from 0.08-40 mN with a nanoindenter XP. The instrumented indentation hardness was 110 MPa for an untreated sample, increasing to 124 MPa after irradiation with 25 kGy, at penetration depths of about 5 μm. The increases in elastic modulus induced by radiation were less pronounced. This polyurethane is naturally cross-linked and the relative modifications in the hardness are attributed to an additional cross-linking process induced by radiation. X-ray diffraction indicates a slight increase in crystallinity. The roughness measured by atomic force microscopy increases after gamma irradiation.

  16. The role of nanocrystalline cellulose on the microstructure of foamed castor-oil polyurethane nanocomposites.

    Science.gov (United States)

    Cordero, Andrés Ignacio; Amalvy, Javier Ignacio; Fortunati, Elena; Kenny, José María; Chiacchiarelli, Leonel Matías

    2015-12-10

    Nanocrystalline cellulose (CNC), obtained by sulphuric acid hydrolysis, was used to synthesize polyurethane foams (PUFs) based on a functionalized castor oil polyol and a Methylene diphenyl diisocyanate (MDI). Formulations with varying isocyanate index (FI) and NCO number were prepared. At 0.5 wt.%, SEM's of the fractured surface underlined that the CNC acted both as a nucleation agent and as a particulate surfactant with cell geometries and apparent density changing selectively. The chemical structure of the PUF (FTIR) changed after the incorporation of CNC by a relative change of the amount of urea, urethane and isocyanurate groups. A low NCO number and isocyanate index contributed to the migration of the CNC to the Hard Segment (HS), acting as reinforcement and improving substantially the compressive mechanical properties (Ec and σc improvements of 63 and 50%, respectively). For a high NCO number or isocyanate index, the CNC migrated to the Soft Segment (SS), without causing a reinforcement effect. The migration of the CNC was also detected with DSC, TGA and DMA, furtherly supporting the hypothesis that a low NCO number and index contributed both to the formation of a microstructure with a higher content of urethane groups.

  17. The emulsion crystallization of hydrogenated castor oil into long thin fibers

    Science.gov (United States)

    De Meirleir, Niels; Pellens, Linda; Broeckx, Walter; De Malsche, Wim

    2013-11-01

    The present study discusses the optimal crystal growth conditions required for the emulsion crystallization of hydrogenated castor oil (HCO) into several crystal morphologies. The best possible crystal shape is furthermore identified in case high rheology modifying performance is required. HCO was crystallized in a meso- and micro-continuous process which allowed for a controlled and fast screening of several crystal morphologies at different crystallization conditions. Applying high isothermal temperatures (above 55 °C) resulted in a combination of rosettes, thick fibers and thin fibers. At lower isothermal temperatures (below 55 °C) the shape gradually evolved to a combination of short needles, spherically shaped and/or irregularly shaped crystals. Crystals with the highest aspect ratio were obtained when crystals were grown between 30 °C and 45 °C and were subsequently reheated above 63 °C, forming high amounts of large thin fibrous crystals. When diluted to 0.25 wt% these fibrous crystals increased the low shear viscosity far better compared to the other crystal shapes.

  18. Castor oil polymer induces bone formation with high matrix metalloproteinase-2 expression.

    Science.gov (United States)

    Saran, Wallace Rocha; Chierice, Gilberto Orivaldo; da Silva, Raquel Assed Bezerra; de Queiroz, Alexandra Mussolino; Paula-Silva, Francisco Wanderley Garcia; da Silva, Léa Assed Bezerra

    2014-02-01

    The aim of this study was to evaluate the modulation of matrix metalloproteinase-2 (MMP-2) and -9 (MMP-9) expression in newly formed bone tissue at the interface between implants derived from castor oil (Ricinus communis) polymer and the tibia medullary canal. Forty-four rabbits were assigned to either Group 1 (n = 12; control) or Group 2 (n = 30), which had the tibial medullary canals reamed bilaterally and filled with polymer. CT scans showed no space between the material surface and the bone at the implant/bone marrow interface, and the density of the tissues at this interface was similar to the density measured of other regions of the bone. At 90 days postimplantation, the interface with the polymer presented a thick layer of newly formed bone tissue rich in osteocytes. This tissue exhibited ongoing maturation at 120 and 150 days postimplantation. Overall, bone remodeling process was accompanied by positive modulation of MMP-2 and low MMP-9 expression. Differently, in control group, the internal surface close to the medullary canal was lined by osteoblasts, followed by a bone tissue zone with few lacunae filled with osteocytes. Maturation of the tissue of the medullary internal surface occurred in the inner region, with the bone being nonlamellar.

  19. Evaluation of the properties of iron oxide-filled castor oil polyurethane

    Directory of Open Access Journals (Sweden)

    Eleonora Mussatti

    2013-02-01

    Full Text Available The aim of this study was to obtain and evaluate the electrical, thermal and mechanical properties of iron oxide-filled castor oil polyurethane (PU/Fe2O3. The iron oxide used in this study was a residue derived from the steel pickling process of a Brazilian steel rolling industry. Polymeric composites with different iron oxide volume fractions (2.5, 5.0, 7.5, 10.0 and 12.5% were prepared through the casting process followed by compression molding at room temperature. The composites were analyzed by FTIR, XRD and densities, tensile strength, Young's modulus, electrical and thermal conductivities measurements. By increasing the iron oxide content, the apparent density, tensile strength, Young's modulus and electrical conductivity values of the composites were also increased. The iron oxide additions did not change significantly the value of thermal conductivity (from 0.191 W.mK-1 for PU up to 0.340 W.mK-1 for PU enriched with 12.5% v/v of iron oxide. Thus, even at the higher iron oxide concentration, the compounds as well as the pure polyurethane can be classified as thermal insulators.

  20. Subcutaneous tissue reaction to castor oil bean and calcium hydroxide in rats

    Directory of Open Access Journals (Sweden)

    Samira Esteves Afonso Camargo

    2010-06-01

    Full Text Available Castor oil bean cement (COB is a new material that has been used as an endodontic sealer, and is a candidate material for direct pulp capping. OBJECTIVE: The purpose of this study was to evaluate the biocompatibility of a new formulation of COB compared to calcium hydroxide cement (CH and a control group without any material, in the subcutaneous tissue of rats. MATERIAL AND METHODS: The materials were prepared, packed into polyethylene tubes, and implanted in the rat dorsal subcutaneous tissue. Animals were sacrificed at the 7th and 50th days after implantation. A quantitative analysis of inflammatory cells was performed and data were subjected to ANOVA and Tukey's tests at 5% significance level. RESULTS: Comparing the mean number of inflammatory cells between the two experimental groups (COB and CH and the control group, statistically significant difference (p=0.0001 was observed at 7 and 50 days. There were no significant differences (p=0.111 between tissue reaction to CH (382 inflammatory cells and COB (330 inflammatory cells after 7 days. After 50 days, significantly more inflammatory cells (p=0.02 were observed in the CH group (404 inflammatory cells than in the COB group (177 inflammatory cells. CONCLUSIONS: These results demonstrate that the COB cement induces less inflammatory response within long periods.

  1. Flexural behavior of Sisal/Castor oil-Based Polyurethane and Sisal/Phenolic Composites

    Directory of Open Access Journals (Sweden)

    Andressa Cecília Milanese

    2012-04-01

    Full Text Available Natural fibers used as reinforcement of polymeric composites are interesting research subjects in polymer technology. Nowadays, these materials are being considered as a way to reinforce timber structures improvement. Fibers with larger structural applications are glass and carbon fibers, however, the use of natural fibers is an economic alternative and present many advantages such as biodegradability and having its origin from a renewable source. Castor oil, a triglyceride vegetable with hydroxyl groups, was reacted with 4,4' methylene diphenyl diisocyanate (MDI to produce the polyurethane matrix. The composites were prepared by compress molding at room temperature using woven sisal fiber as a reinforcement, with and without thermal treatment (at 60 ºC for 72 hours to the fabrics before the composites molding process. The present paper presents the preparation and a flexural caracterization of sisal/polyurethane and sisal/phenolic composites by using the three-point bending. The sisal fibers moisture content influence on the flexural behaviour was also analyzed. Experimental results showed a higher stiffness for the sisal/phenolic composite (11.2 MPa followed by the sisal/polyurethane (3.7 MPa, respectively.

  2. Preparation and characterization of novel antibacterial castor oil-based polyurethane membranes for wound dressing application.

    Science.gov (United States)

    Yari, Abbas; Yeganeh, Hamid; Bakhshi, Hadi; Gharibi, Reza

    2014-01-01

    Preparation of novel antibacterial and cytocompatible polyurethane membranes as occlusive dressing, which can provide moist and sterile environment over mild exudative wounds is considered in this work. In this regard, an epoxy-terminated polyurethane (EPU) prepolymer based on castor oil and glycidyltriethylammonium chloride (GTEAC) as a reactive bactericidal agent were synthesized. Polyurethane membranes were prepared through cocuring of EPU and different content of GTEAC with 1,4-butane diamine. The physical and mechanical properties, as well as cytocompatibility and antibacterial performance of prepared membranes were studied. Depending on their chemical formulations, the equilibrium water absorption and water vapor transmission rate values of the membranes were in ranges of 3-85% and 53-154g m(-2) day(-1), respectively. Therefore, these transparent membranes can maintain for a long period the moist environment over the wounds with low exudates. Detailed cytotoxicity analysis of samples against mouse L929 fibroblast and MCA-3D keratinocyte cells showed good level of cytocompatibility of membranes after purification via extraction of residual unreacted GTEAC moieties. The antibacterial activity of the membranes against Escherichia coli and Staphylococcus aureus bacteria was also studied. The membrane containing 50% GTEAC exhibited an effective antibacterial activity, while showed acceptable cytocompatibility and therefore, can be applied as an antibacterial occlusive wound dressing.

  3. WEIGHT LOSS AND COMPRESSIVE STRENGTH OF CASTOR OIL-TREATED Pinus caribaea (Morelet WOOD EXPOSED TO FUNGI

    Directory of Open Access Journals (Sweden)

    Adewunmi Omobolaji ADENAIYA

    2016-12-01

    Full Text Available The need for environmental sustainability calls for a radical change from the use of synthetic wood preservatives which persist in the environment even after wood has been taken out of service. There has therefore been a growing interest in the development of efficacious biocides from plants, prompting the exploration of castor seed oil as a potential wood antifungal in this study due to its reported antimicrobial properties. Thus, this study aimed at evaluating the resistance of castor oil treated P. caribaea wood against two strains of wood basidiomycetes. Five trees of Pinus caribaea were harvested at Shasha Forest Reserve, Osun State. Wood samples were obtained from the top, middle and base of the trees. The samples were conditioned and treated with four formulated fungicides prepared from mechanically extracted oil of castor seeds. The treated and control samples were inoculated with Sclerotium rolfsii (Brown rot and Ganoderma lucidum (White rot for 24 weeks. Parameters such as oil yield, preservative absorption, weight loss and compressive strength of the treated wood samples were determined. ANOVA was used in analyzing the data generated. Results show that the oil yield of the seed of the plant is 41.75%. The preservative absorption of the wood ranged between 114.85 - 277.12 (Kgm-3 , weight loss (1.36 - 15.85% and MCS// (33.05 - 48.35N/mm2 . Sampling height and preservative concentration significantly influenced weight loss of the wood (p<0.05. The 30% preservative concentration performed best, having the least weight loss (1.71% and 1.61% and highest MCS// (47.06N/mm2 and 44.65N/mm2 after exposure to S. rolfsii and G. lucidum, respectively. The brown rot (4.12% was more virulent than the white rot (3.66% on the basis of wood weight loss, however, the MCS// results indicated otherwise. It is concluded that castor seed oil is effective in protecting wood against white and brown rot fungi.

  4. A Comparative Experimental Analysis of Tribological Properties Between Commercial Mineral Oil and Neat Castor Oil using Taguchi Method in Boundary Lubrication Regime

    OpenAIRE

    Bhaumik, S; Pathak, S. D.

    2016-01-01

    The present work aims to carry out a comparative experimental analysis of tribological properties of 372cSt mineral oil and 229cSt castor oil. The antiwear and extreme pressure properties of both the oils have been analysed according to ASTM G 99 and ASTM D-2783 standards. The surfaces of the balls and pins after tribo tests have been analysed using Scanning Electron Microscope (SEM) images. The present test results predict that the antiwear and extreme pressure properties in case of the sele...

  5. Effects of sowing dates and different fertilizers on yield, yield components, and oil percentage of castor bean (Ricinus communis L.

    Directory of Open Access Journals (Sweden)

    parviz rezvani moghadam

    2009-06-01

    Full Text Available In order to study the effects of sowing dates and different fertilizers on yield, yield components, and oil percentage of castor bean, an experiment was conducted at Experimental station, College of Agriculture, Ferdowsi University of Mashhad, Iran in years 2004-2005. The experimental treatments comprised all combinations of four sowing dates (11 April, 25 April, 8 May and 22 May and three different fertilizers (cow manure (30 tons/ha, compost (30 tons/ha, chemical fertilizers (100 kg/ha N and 250 kg/ha of super phosphate and no fertilizer as control. Different characteristics such as plant height, main inflorescence height, number of inflorescence per plant, number of secondary stems per plant, number of capsules per plant, number of grain per plant, grain weight per plant, 100 seed weight, grain yield, oil percentage and oil yield were recorded. A factorial arrangement based on a randomized complete block design with three replications was used. The results showed by delaying sowing date grain yield, seed oil percentage and oil yield were decreased, but there was no significant differences between 25 April, 8 May and 22 May sowing dates. Harvest index and 100 seed weight did not affect by neither sowing dates nor fertilizer treatments. The highest number of branches per plant, number of fertile inflorescences per plant, number of fertile capsules per plant, number of grain per plant, grain weight per plant and biological yield were obtained at 8 May sowing date on chemical fertilizer. Percentage of seed oil, grain yield and oil yield was higher at the first sowing date (11 April in compost and chemical fertilizer treatments. Keywords: Castor bean, sowing date, fertilizer, grain yield, oil percentage.

  6. Blends of nitrile butadiene rubber/poly (vinyl chloride: The use of maleated anhydride castor oil based plasticizer

    Directory of Open Access Journals (Sweden)

    Indiah Ratna Dewi

    2016-06-01

    Full Text Available Recently, much attention has been focused on research to replace petroleum-based plasticizers, with biodegradable materials, such as biopolymer which offers competitive mechanical properties. In this study, castor oil was modified with maleic anhydride (MAH to produce bioplasticizer named maleated anhydride castor oil (MACO, and used in nitrile butadiene rubber (NBR/poly vinyl chloride (PVC blend. The effect of MACO on its cure characteristics and mechanical properties of NBR/PVC blend has been determined. The reactions were carried out at different castor oil (CO/xylene ratios, i.e. 1:0 and 1:1 by weight, and fixed CO/MAH ratio, 1:3 by mole. DOP, CO, and MACO were added into each NBR/PVC blend according to the formula. It was found that the viscosity and safe process level of NBR/PVC blend is similar from all plasticizer, however, MACO (1:0 showed the highest cure rate index (CRI. MACO-based plasticizer gave a higher value of the mechanical properties of the NBR/PVC blend as compared to DOP based plasticizer. MACO (1:1 based plasticizer showed a rather significance performance compared to another type of plasticizers both before and after aging. The value of hardness, elongation at break, tensile strength, and tear strength were 96 Shore A, 155.91 %, 19.15 MPa, and 74.47 MPa, respectively. From this result, NBR/PVC blends based on MACO plasticizer can potentially replace the DOP, and therefore, making the rubber blends eco-friendly.

  7. Interpenetrating polymer networks based on polyol modified castor oil polyurethane and poly(2-hydroxyethylmethacrylate): Synthesis, chemical, mechanical and thermal properties

    Indian Academy of Sciences (India)

    K Prashantha; K Vasanth Kumar Pai; B S Sherigara; S Prasannakumar

    2001-10-01

    Interpenetrating polymer networks (IPNs) of glycerol modified castor oil polyurethane (GC–PU) and poly[2-hydroxyethylmethacrylate] (PHEMA) were synthesized using benzoyl peroxide as initiator and N,N-methylene bis acrylamide as crosslinker. GC–PU/PHEMA interpenetrating polymer networks were obtained by transfer moulding. These were characterized with respect to their resistance to chemical reagents and mechanical properties such as tensile strength, per cent elongation and shore A hardness. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were undertaken for thermal characterization. The changes in NCO/OH ratio and GC–PU/PHEMA composition on the properties of the IPNs were studied.

  8. Bio-aviation fuel production from hydroprocessing castor oil promoted by the nickel-based bifunctional catalysts.

    Science.gov (United States)

    Liu, Siyang; Zhu, Qingqing; Guan, Qingxin; He, Liangnian; Li, Wei

    2015-05-01

    Bio-aviation fuel was firstly synthesized by hydroprocessing castor oil in a continuous-flow fixed-bed microreactor with the main objective to obtain the high yield of aviation fuel and determine the elemental compositions of the product phases as well as the reaction mechanism. Highest aviation range alkane yields (91.6 wt%) were achieved with high isomer/n-alkane ratio (i/n) 4.4-7.2 over Ni supported on acidic zeolites. In addition, different fuel range alkanes can be obtained by adjusting the degree of hydrodeoxygenation (HDO) and hydrocracking. And the observations are rationalized by a set of reaction pathways for the various product phases.

  9. Preparation and evaluation of tilmicosin-loaded hydrogenated castor oil nanoparticle suspensions of different particle sizes.

    Science.gov (United States)

    Chen, Xiaojin; Wang, Ting; Lu, Mengmeng; Zhu, Luyan; Wang, Yan; Zhou, WenZhong

    2014-01-01

    Three tilmicosin-loaded hydrogenated castor oil nanoparticle (TMS-HCO-NP) suspensions of different particle sizes were prepared with different polyvinyl alcohol surfactant concentrations using a hot homogenization and ultrasonic technique. The in vitro release, in vitro antibacterial activity, mammalian cytotoxicity, acute toxicity in mice, and stability study were conducted to evaluate the characteristics of the suspensions. The in vitro tilmicosin release rate, antibacterial activity, mammalian cytotoxicity, acute toxicity in mice, and stability of the suspensions were evaluated. When prepared with polyvinyl alcohol concentrations of 0.2%, 1%, and 5%, the mean diameters of the nanoparticles in the three suspensions were 920±35 nm, 452±10 nm, and 151±4 nm, respectively. The three suspensions displayed biphasic release profiles similar to that of freeze-dried TMS-HCO-NP powders, with the exception of having a faster initial release. Moreover, suspensions of smaller-sized particles showed faster initial release, and lower minimum inhibitory concentrations and minimum bactericidal concentrations. Time-kill curves showed that within 12 hours, the suspension with the 151 nm particles had the most potent bactericidal activity, but later, the suspensions with larger-sized particles showed increased antibacterial activity. None of the three suspensions were cytotoxic at clinical dosage levels. At higher drug concentrations, all three suspensions showed similar concentration-dependent cytotoxicity. The suspension with the smallest-sized particle showed significantly more acute toxicity in mice, perhaps due to faster drug release. All three suspensions exhibited good stability at 4°C and at room temperature for at least 6 months. These results demonstrate that TMS-HCO-NP suspensions can be a promising formulation for tilmicosin, and that nanoparticle size can be an important consideration for formulation development.

  10. Diametral tensile strength and film thickness of an experimental dental luting agent derived from castor oil

    Directory of Open Access Journals (Sweden)

    Juliana Cabrini Carmello

    2012-02-01

    Full Text Available The need to develop new dental luting agents in order to improve the success of treatments has greatly motivated research. OBJECTIVE: The aim of this study was to evaluate the diametral tensile strength (DTS and film thickness (FT of an experimental dental luting agent derived from castor oil (COP with or without addition of different quantities of filler (calcium carbonate - CaCO3. MATERIAL AND METHODS: Eighty specimens were manufactured (DTS N=40; FT N=40 and divided into 4 groups: Pure COP; COP 10%; COP 50% and zinc phosphate (control. The cements were mixed according to the manufacturers' recommendations and submitted to the tests. The DTS test was performed in the MTS 810 testing machine (10 KN, 0.5 mm/min. For FT test, the cements were sandwiched between two glass plates (2 cm² and a load of 15 kg was applied vertically on the top of the specimen for 10 min. The data were analyzed by means of one-way ANOVA and Tukey's test (α=0.05. RESULTS: The values of DTS (MPa were: Pure COP- 10.94±1.30; COP 10%- 30.06±0.64; COP 50%- 29.87±0.27; zinc phosphate- 4.88±0.96. The values of FT (µm were: Pure COP- 31.09±3.16; COP 10%- 17.05±4.83; COP 50%- 13.03±4.83; Zinc Phosphate- 20.00±0.12. One-way ANOVA showed statistically significant differences among the groups (DTS - p=1.01E-40; FT - p=2.4E-10. CONCLUSION: The experimental dental luting agent with 50% of filler showed the best diametral tensile strength and film thickness.

  11. Toxin content of commercial castor cultivars

    Science.gov (United States)

    The castor plant Ricinus communis L. is the source of castor oil which has numerous uses and is a key chemical feedstock for an array of products from polymers to cosmetics. Although castor was once widely grown throughout the world, the presence of the toxic protein ricin has deterred the re-introd...

  12. Synthesis and Physicochemical Behaviour of Polyurethane-Multiwalled Carbon Nanotubes Nanocomposites Based on Renewable Castor Oil Polyols

    Directory of Open Access Journals (Sweden)

    Alaa Ali

    2014-01-01

    Full Text Available Polyurethanes (PUs are high performance materials, with vast industrial and engineering applications. In this research, effects of Multiwalled Carbon Nanotubes (MWCNTs on physicochemical properties of Castor Oil based Polyurethanes (COPUs were studied. MWCNTs were added in different weight percentages (0% to 1% wt in a castor oil based polyurethane (COPUs-MWCNTs nanocomposites. The composition, structure, and morphology of polyurethanes were characterized by Fourier transform infrared spectroscopy (FTIR, X-ray diffraction (XRD, scanning electron microscopy (SEM, field emission scanning electron microscopy (FESEM, and element detection by energy dispersive spectroscopy (EDX analysis, respectively. Thermal stability was studied by thermogravimetric analysis (TGA. Barrier properties and surface area studies were investigated by nitrogen permeability machine and BET technique. Mechanical properties were calculated by tensile universal testing machine. Results showed well dispersed MWCNTs in polyurethane matrix at different weight percentages. The best results were obtained with 0.3 wt% of MWCNTs in the composite. Surface area studies revealed presence of very few pores which is in a good agreement with barrier permeability, reduced up to ~68% in 1 wt% and ~70% in 0.5 wt% of MWCNTs in polymer matrix, with respect to pure COPUs samples.

  13. Poly(DL:lactic acid-castor oil) 3:7-bupivacaine formulation: reducing burst effect prolongs efficacy in vivo.

    Science.gov (United States)

    Sokolsky-Papkov, Marina; Golovanevski, Ludmila; Domb, Abraham J; Weiniger, Carolyn F

    2010-06-01

    Prolonged analgesia may be achieved using a single injection of slow-release local anesthetic formulation. The study objective was to improve the efficacy of a previously reported formulation comprising 10% bupivacaine in poly(DL:lactic acid co castor oil) 3:7. The polymer was loaded with 15% bupivacaine and injected through a 22G needle close to the sciatic nerve of ICR mice. Sensory and motor nerve blockade were measured. The efficacy and toxicity of the polymer-drug combination were determined. Sixty percent of the incorporated bupivacaine was released during 1 week in vitro. During in vitro release no burst effect was seen, suggesting low toxicity of the formulation. Single injection of 0.1 mL of 15% polymer-bupivacaine formulation caused motor block that lasted 64 h and sensory block that lasted 96 h. The MTD of the polymer-drug formulation was established as 0.175 mL. Microscopic examination of the injection sites revealed reversible nerve inflammation and normal internal organs. The polymer poly(DL:lactic acid co castor oil) 3:7 is a safe carrier for prolonged activity of bupivacaine up to 96 h. The increase of drug load in the formulation reduces the drug release rates due to stronger polymer-drug interactions and higher overall hydrophobicity of the formulation.

  14. Synthesis of carboxylate complexes and evaluation of their catalytic activities for polyesterification of castor oil (Ricinum communis with terephthalic acid

    Directory of Open Access Journals (Sweden)

    Eduardo Ulisses Xavier Peres

    2015-07-01

    Full Text Available The use of castor oil (Ricinus communis has been pointed out as an interesting alternative to produce several polymers obtained from step-growth polymerization and are suitable to be used as resins and coatings. The ricinoleate metal complexes Ni[C17H34(OHCOO]2, Sn[C17H34(OHCOO]2, Co[C17H34(OHCOO]2 and Fe[C17H34(OHCOO]2 have been prepared and used as catalyst precursors for polyesterification of castor oil and terephthalic acid (TFA. The observed catalytic activity decreased in the order: Fe[C17H34(OHCOO]2 > Co[C17H34(OHCOO]2 > Sn[C17H34(OHCOO]2 > Ni[C17H34(OHCOO]2. The new polymeric materials did not show homogeneity in their chains, as indicated by their high polydispersity. Indeed, the polydispersity index value varied from 5.49 for the polymer produced in the presence of the nickel complex to 12.42 for these prepared with the cobalt compound. On the other hand, the final material presented high molecular weight, being the lower value (Mw = 13400 Da observed for the polymer prepared with the nickel complex and the highest (Mw = 36400 Da verified for the one obtained with the cobalt compound. It was observed only a glass transition temperature for all the materials, suggesting an amorphous structure of polymeric chains.

  15. Synthesis and characterization of castor oil-based polyurethane for potential application as host in polymer electrolytes

    Indian Academy of Sciences (India)

    S Ibrahim; A Ahmad; N S Mohamed

    2015-09-01

    Polyurethane (PU) based on polyol, derived from castor oil has been synthesized and characterized for potential use as a base material for electrolytes. Transesterification process of castor oil formed a polyol with hydroxyl value of 190 mg KOH g–1 and molecular weight of 2786 g mol–1. The polyols together with 4,4′-diphenylmethane diisocyanate were used to synthesize the desired bio-based PU. The molecular structure of PU was investigated by Fourier transform infrared (FTIR) spectroscopy. The disappearance of NCO peak in the FTIR spectrum at 2270–2250 cm–1 showed that diisocyanate has completely reacted to form PU. Morphological characteristic of the PU film was analysed using scanning electron microscopy, whereas thermal characteristics of the materials were characterized using dynamic mechanical analysis and thermal gravimetric analysis. The cross-sectional micrograph showed that the prepared film was highly amorphous and homogeneous. Thermal studies revealed that the film had low glass transition temperature, –15.8°C, and was thermally stable up to 259°C. These observations indicated the synthesized PU possessed favourable properties to act as a base material in polymer electrolytes.

  16. Traditional crop for biodiesel. Castor oil could be an alternative, but it is a problematic additive; Traditionspflanze fuer Biodiesel. Rizinusoel koennte eine Alternative sein - problematisch als Beimischung

    Energy Technology Data Exchange (ETDEWEB)

    Ristau, Oliver

    2012-11-01

    As the demand for energy crops like soy is increasing, so are prices. The castor-oil plant may soon become one of these crops. An Israeli-Brazilian cooperation project is to raise the yields of this old culture plant and make it profitable.

  17. Acute toxicity study of tilmicosin-loaded hydrogenated castor oil-solid lipid nanoparticles

    Directory of Open Access Journals (Sweden)

    Xie Shuyu

    2011-11-01

    Full Text Available Abstract Background Our previous studies demonstrated that tilmicosin-loaded hydrogenated castor oil solid lipid nanoparticles (Til-HCO-SLN are a promising formulation for enhanced pharmacological activity and therapeutic efficacy in veterinary use. The purpose of this work was to evaluate the acute toxicity of Til-HCO-SLN. Methods Two nanoparticle doses were used for the study in ICR mice. The low dose (766 mg/kg.bw with tilmicosin 7.5 times of the clinic dosage and below the median lethal dose (LD50 was subcutaneously administered twice on the first and 7th day. The single high dose (5 g/kg.bw was the practical upper limit in an acute toxicity study and was administered subcutaneously on the first day. Blank HCO-SLN, native tilmicosin, and saline solution were included as controls. After medication, animals were monitored over 14 days, and then necropsied. Signs of toxicity were evaluated via mortality, symptoms of treatment effect, gross and microscopic pathology, and hematologic and biochemical parameters. Results After administration of native tilmicosin, all mice died within 2 h in the high dose group, in the low dose group 3 died after the first and 2 died after the second injections. The surviving mice in the tilmicosin low dose group showed hypoactivity, accelerated breath, gloomy spirit and lethargy. In contrast, all mice in Til-HCO-SLN and blank HCO-SLN groups survived at both low and high doses. The high nanoparticle dose induced transient clinical symptoms of treatment effect such as transient reversible action retardation, anorexy and gloomy spirit, increased spleen and liver coefficients and decreased heart coefficients, microscopic pathological changes of liver, spleen and heart, and minor changes in hematologic and biochemical parameters, but no adverse effects were observed in the nanoparticle low dose group. Conclusions The results revealed that the LD50 of Til-HCO-SLN and blank HCO-SLN exceeded 5 g/kg.bw and thus the

  18. Preparation and Characterization of Castor Oil Based Polyester Polyol%蓖麻油基聚酯多元醇的制备及表征

    Institute of Scientific and Technical Information of China (English)

    张猛; 周永红; 潘青良; 曹振华

    2012-01-01

    Castor oil based polyester polyol was prepared by renewable resources castor oil, phthalic anhydride and small molecular alcohol respectively as raw materials via alcoholysis and polyesterification reaction, tetra-n-butyl titanate as catalyst. The influence of the reaction time on the acid value of polyester polyol and different degree of hy-droxy functionality on the hydroxy value and structure of alcoholysis of castor oil were investigated. Further, the quality and thermal stability of alcoholysis of castor oil and castor oil based polyester polyol were charactered by the FT-IR, GPC and TGA. The experimental results showed that, with the degree of hydroxy functionality of small molecular alcohol increasing, the conversion rate and the content of monoglycerol and diglycerol decreased. The alcoholysis of castor oil by glycerol and castor oil based polyester polyol had higher thermal stability than polyether polyol 635.%以可再生资源蓖麻油、苯酐和小分子醇为原料,钛酸正丁酯为催化剂,经酯化、缩聚合成蓖麻油基聚酯多元醇,考察了反应时间对聚酯多元醇酸值的影响以及不同官能度的小分子醇对醇解蓖麻油结构和羟值的影响.采用红外光谱仪(FT-IR)、凝胶色谱(GPC)、热失重仪(TGA)对醇解蓖麻油、蓖麻油基聚酯多元醇的相对分子质量、热稳定性进行了表征.结果表明,随着小分子醇官能度的增加,醇解体系中单酯和二酯含量明显减少,转化率也相应减小;甘油醇解蓖麻油和蓖麻油基聚酯多元醇较普通聚醚多元醇635具有更高的热稳定性.

  19. Reducing the toxicity of castor seed meal through processing treatments

    Science.gov (United States)

    The castor plant produces a seed that is high in oil content and composed of approximately 90% ricinoleate. Due to the numerous uses of castor oil and ricinoleate, the oil is in high demand. However, the presence of a protein toxin in the seed meal is a key concern about processing the castor seed t...

  20. NTP technical report on the toxicity studies of Castor Oil (CAS No. 8001-79-4) in F344/N Rats and B6C3F1 Mice (Dosed Feed Studies).

    Science.gov (United States)

    Irwin, R

    1992-03-01

    Castor oil is a natural oil derived from the seeds of the castor bean, Ricinus communis. It is comprised largely of triglycerides with a high ricinolin content. Toxicity studies with castor oil were performed by incorporating the material at concentrations as high as 10% in diets given to F344/N rats and B6C3F1 mice of both sexes for 13 weeks. Genetic toxicity studies also were performed and were negative for mutation induction in Salmonella typhimurium, for induction of sister chromatid exchanges or chromosomal aberrations in Chinese hamster ovary cells, and for induction of micronuclei in the peripheral blood erythrocytes of mice evaluated at the end of the 13-week studies. Exposure to castor oil at dietary concentrations as high as 10% in 13-week studies did not affect survival or body weight gains of rats or mice (10 per sex and dose). There were no biologically significant effects noted in hematologic analyses in rats. Mild increases in total bile acids and in serum alkaline phosphatase were noted at various times during the studies in rats receiving the higher dietary concentrations of castor oil. Liver weights were increased in male rats receiving the 10% dietary concentration and in male and female mice receiving diets containing 5% or 10% castor oil. However, there were no histopathologic lesions associated with these liver changes, nor were there any compound-related morphologic changes in any organ in rats or mice. No significant changes were noted in a screening for male reproductive endpoints, including sperm count and motility, and no changes were observed in the length of estrous cycles of rats or mice given diets containing castor oil. Thus, no significant adverse effects of castor oil administration were noted in these studies. Synonyms: Ricinus Oil, oil of Palma Christi, tangantangan oil, phorboyl, Neoloid.

  1. Response of broiler finishers to diets containing graded levels of processed castor oil bean (Ricinus communis L) meal.

    Science.gov (United States)

    Ani, A O; Okorie, A U

    2009-04-01

    A 4-week feeding experiment was conducted to determine the effects of graded levels of dehulled and cooked castor oil bean (Ricinus communis L) meal on the performance of broiler finishers. Castor oil bean seeds were dehulled and detoxified by cooking in two stages at 100 degrees C for 50 min per cooking. Sixty 6-week-old broiler birds (Anak strain) were randomly divided into four groups of 15 birds each. The groups were fed four isocaloric (2.90 Mcal of metabolizable energy/kg) and isonitrogenous (21% crude protein) diets containing 0%, 10%, 15% and 20% dehulled and cooked castor oil bean meal (CBM) for 4 weeks. Results showed that there were significant (p 0.05) different from the ADWG of birds on 10% CBM diet. Birds fed diets containing10% and 15% levels of CBM had similar and non-significant (p > 0.05) ADWG. Birds fed 20% CBM diet had the least (p 0.05) PCV values. Birds fed diets containing 0%, 10% and 15% levels of CBM had similar and significantly (p < 0.05) lower heamoglobin than birds fed 20% CBM diets. There were also significant (p < 0.05) differences among treatments in dry matter (DM), nitrogen, ether extract (EE) and nitrogen-free extract (NFE) retention. Birds fed 0% CBM diet had significantly (p < 0.05) higher retention of DM, nitrogen and NFE than birds on 10%, 15% and 20% CBM diets. Birds fed 10% CBM diet had significantly (p < 0.05) higher DM, nitrogen and NFE retention than birds on 15% and 20% CBM diets. The lowest retention of DM, nitrogen and NFE was recorded at the 20% CBM inclusion level. Birds fed 0% CBM diet had significantly (p < 0.05) higher EE retention than birds on 15% and 20% CBM diets. The lowest EE retention was observed at the 20% CBM inclusion level. The results of the study indicate that up to 10% dehulled and cooked CBM can be included in broiler finisher rations for optimum performance.

  2. A castor oil-containing dental luting agent: effects of cyclic loading and storage time on flexural strength.

    Science.gov (United States)

    Derceli, Juliana Dos Reis; Fais, Laiza Maria Grassi; Pinelli, Lígia Antunes Pereira

    2014-01-01

    Favorable results in the use of castor oil polyurethane (COP) as pulp capping, membrane material, sealer, mouthwash and in bone repair, associated with the fact that Ricinus communis is not derived from petroleum and it is abundant in Brazil, encourage researches in the development of luting agents. Objectives This study compared the flexural strength (FS) of a castor oil-containing dental luting agent with a weight percentage of 10% (wt%) of calcium carbonate (COP10) with RelyX ARC (RX) after mechanical cycling (MC) and distilled water storage. Material and Methods Sixty-four specimens (25x2x2 mm) were fabricated and divided into two groups, COP10 and RX (control). Each group was divided into 4 subgroups (n=8) according to the storage time, 24 hours (24 h) or 60 days (60 d), and the performance (MC+FS) or not (only FS) of the mechanical cycling test. The FS (10 kN; 0.5 mm/min) and MC tests (10,000 cycles, 5 Hz, 0.5 mm/min) were carried out using an MTS-810 machine. The data were analyzed using ANOVA (α=0.05). Results The obtained FS (MPa) values were: COP10 24h- 19.04±2.41; COP10 60d- 17.92±3.54; RX 24h- 75.19±3.43; RX 60d- 88.77±6.89. All the RX specimens submitted to MC fractured, while the values for COP10 after MC were as follows: COP10 24h- 17.90±1.87 and COP10 60d- 18.60±1.60. Conclusions A castor oil-containing dental luting agent with a weight percentage of 10% (wt%) of calcium carbonate is resistant to mechanical cycling without decreases in flexural strength. However, mean COP10 showed only about 25% of the RelyX ARC mean flexural strength.

  3. Nickel-carbon nanocomposites prepared using castor oil as precursor: A novel catalyst for ethanol steam reforming

    Science.gov (United States)

    Carreño, Neftalí L. V.; Garcia, Irene T. S.; Raubach, Cristiane W.; Krolow, Mateus; Santos, Cláudia C. G.; Probst, Luiz F. D.; Fajardo, Humberto V.

    A novel and simple method to prepare nickel-based catalysts for ethanol steam reforming is proposed. The present method was developed using castor oil as a precursor. The results clarify that the nickel-carbon (Ni/C) catalyst has a high activity for ethanol steam reforming. It was observed that the catalytic behavior could be modified according to the experimental conditions employed. Moreover, it is interesting to note that the increase in the catalytic activity of the Ni/C nanocomposite over time, at 500 and 600 °C of reaction temperature, may be associated with the formation of filamentous carbon. The preliminary results indicate that the novel methodology used, led to the obtainment of materials with important properties that can be extended to applications in different catalytic process.

  4. Preparation and properties of aqueous castor oil-based polyurethane-silica nanocomposite dispersions through a sol-gel process.

    Science.gov (United States)

    Xia, Ying; Larock, Richard C

    2011-09-01

    Waterborne castor oil-based polyurethane-silica nanocomposites with the polymer matrix and silica nanoparticles chemically bonded have been successfully prepared through a sol-gel process. The formation of silica nanoparticles in water not only reinforces the resulting coatings, but also increases the crosslink density of the nanocomposites. The (29)Si solid state NMR spectrum indicates the formation of silica and the TEM indicates that the nanoparticles are embedded in the polymers, resembling a core-shell structure. The silica nanoparticles in the polymer matrix play an important role in improving both the mechanical properties and the thermal stabilities of the resulting nanocomposites. This work provides an effective and promising way to prepare biorenewable, high performance nanocomposite coatings.

  5. Development of Castor Oil Based Poly(urethane-esteramide/TiO2 Nanocomposites as Anticorrosive and Antimicrobial Coatings

    Directory of Open Access Journals (Sweden)

    Mohammed Rafi Shaik

    2015-01-01

    Full Text Available Castor oil based polyesteramide (CPEA resin has been successfully synthesized by the condensation polymerization of N-N-bis (2-hydroxyethyl castor oil fatty amide (HECA with terephthalic acid and further modified with different percentages of 7, 9, 11, and 13 wt.% of toluene-2,4-diisocyanate (TDI to obtain poly(urethane-esteramide (UCPEA, via addition polymerization. TiO2 (0.1, 0.2, 0.3, 0.4, and 0.5 wt% nanoparticles were dispersed in UCPEA resin. The structural elucidation of HECA, CPEA, and UCPEA has been carried out using FT-IR, 1H-NMR, and 13C-NMR spectroscopic techniques while physicochemical and physicomechanical properties were investigated by standard methods. Thermal stability and molecular weight of UCPEA have been assessed by thermogravimetric analysis (TGA and gel permeation chromatography (GPC, respectively. Furthermore, the corrosion behavior of UCPEA coatings on mild steel has been investigated by potentiodynamic polarization measurements in different corrosive environments (3.5 wt% HCl, 5 wt% NaCl, 3.5 wt% NaOH, and tap water at room temperature and surface analysis by scanning electron microscope (SEM and energy dispersive X-ray (EDX. The antibacterial activities of the UCPEA were tested against bacteria and fungi by agar disc diffusion method. The results of this study have revealed that UCPEA nanocomposite coatings exhibit good physicomechanical, anticorrosion and antimicrobial properties, which can be safely used up to 200°C.

  6. Mechanical and thermal properties of castor oil polyurethane bone cement after gamma irradiation;Propriedades mecanicas e termicas de poliuretanas derivadas do oleo de mamona usadas como cimento osseo depois da irradiacao com radiacao gamma

    Energy Technology Data Exchange (ETDEWEB)

    Azevedo, E.C. [Universidade Tecnologica Federal do Parana (DF/UTFPR), Curitiba, PR (Brazil). Dept. de Fisica; Soboll, D.S. [Universidade Tecnologica Federal Parana (CPGEI/UTFPR), Curitiba, PR (Brazil); Chierice, G.O.; Claro Neto, S. [Universidade de Sao Paulo (IQSC/USP), Sao Carlos, SP (Brazil). Inst. de Quimica; Lepiesnki, C.M. [Universidade Federal do Parana (DF/UFPR), Curitiba, PR (Brazil). Dept. de Fisica; Nascimento, E.M. [Universidade Tecnologica Federal do Parana (DM/UTFPR), Curitiba (Brazil). Dept. de Mecanica

    2009-07-01

    Polyurethanes from castor oil are being employed as bone cement in medical applications. In this work the thermal and mechanical properties of gamma irradiated polyurethanes derivative from castor oil were investigated by instrumented indentation, thermogravimetry and scanning electron microscopy. A slightly increase in hardness is observed only for doses as high as 100 kGy. Thermal analysis indicates stability at human body temperature. The glass transition temperature has small changes after gamma irradiation. (author)

  7. Growth, testis size, spermatogenesis, semen parameters and seminal plasma and sperm membrane protein profile during the reproductive development of male goats supplemented with de-oiled castor cake.

    Science.gov (United States)

    Oliveira, C H A; Silva, A M; Silva, L M; van Tilburg, M F; Fernandes, C C L; Velho, A L M C; Moura, A A; Moreno, F B M B; Monteiro-Moreira, A C O; Moreira, R A; Lima, I M T; Rondina, D

    2015-06-01

    The present study was conducted to evaluate the effect of de-oiled castor cake on reproductive traits of crossbreed goats. Fourteen males were grouped into two lots (n = 7/group), as described: group without de-oiled castor cake (WCC) and group fed with de-oiled castor cake (CC). Goats received two diets containing a mixture of Bermudagrass hay and concentrates with the same energy (73% total digestive nutrients) and protein content (15% crude protein) during 150 days, corresponding to ages from 40 (puberty) to 60 weeks. Blood plasma concentrations of urea, albumin, lactate dehydrogenase, creatinine, alanine aminotransferase and testosterone were determined. We also evaluated scrotal circumference, sperm parameters, quantitative aspects of spermatogenesis and daily sperm production (DSP), as well as the proteome of seminal plasma and sperm membrane. Seminal fluid and sperm proteins were analyzed by 2D SDS-PAGE and mass spectrometry. After 150 days of castor cake feeding, animals had no changes in the biochemical composition of blood plasma, suggesting the absence of intoxication by ingestion of ricin. There were no alterations in dry mater intake, weight gain, testis size, peripheral concentrations of testosterone, sperm concentration, motility and morphology. Sertoli and germ cell populations in the testis and DSP were not affected either. However, there were significant variations in the expression of five seminal plasma proteins and four sperm membrane proteins. In conclusion, the replacement of soybean meal by castor cake (with ricin concentrations of 50mg/kg) did not interfere with the growth and core reproductive development of male goats. However, the diet with ricin altered the expression of certain seminal plasma and sperm membrane proteins, which play roles in sperm function and fertilization. Lower expression of these proteins may impair the ricin-fed animals to perform as high-fertility sires.

  8. Metabolism of 1-acyl-2-oleoyl-sn-glycero-3-phosphoethanolamine in castor oil biosynthesis.

    Science.gov (United States)

    Lin, J T; Lew, K M; Chen, J M; Iwasaki, Y; McKeon, T A

    2000-05-01

    We have examined the role of 2-oleoyl-PE (phosphatidylethanolamine) in the biosynthesis of triacylglycerols (TAG) by castor microsomes. In castor microsomal incubation, the label from 14C-oleate of 1-palmitoyl-2-[1-(14)C]oleoyl-sn-glycero-3-phosphoethanolamine is incorporated into TAG containing ricinoleate. The enzyme characteristics, such as optimal pH, and the effect of incubation components of the oleoyl-12-hydroxylase using 2-oleoyl-PE as incubation substrate are similar to those for 2-oleoyl-PC (phosphatidylcholine). However, compared to 2-oleoyl-PC, 2-oleoyl-PE is a less efficient incubation substrate of oleoyl-12-hydroxylase in castor microsomes. Unlike 2-oleoyl-PC, 2-oleoyl-PE is not hydroxylated to 2-ricinoleoyl-PE by oleoyl-12-hydroxylase and is not desaturated to 2-linoleoyl-PE by oleoyl-12-desaturase. We have demonstrated the conversion of 2-oleoyl-PE to 2-oleoyl-PC and vice versa. The incorporation of label from 2-[14C]oleoyl-PE into TAG occurs after its conversion to 2-oleoyl-PC, which can then be hydroxylated or desaturated. We detected neither PE-N-monomethyl nor PE-N,N-dimethyl, the intermediates from PE to PC by N-methylation. The conversion of 2-oleoyl-PE to 2-oleoyl-PC likely occurs via hydrolysis to 1,2-diacyl-sn-glycerol by phospholipase C and then by cholinephosphotransferase. This conversion does not appear to play a key role in driving ricinoleate into TAG.

  9. Growth, carcass characteristics, chemical composition and fatty acid profile of the longissimus dorsi muscle in goat kids fed diets with castor oil

    Directory of Open Access Journals (Sweden)

    Michelle de Oliveira Maia

    2012-11-01

    Full Text Available The objective in this study was to determine growth, carcass characteristics, chemical composition and fatty acid profile of the longissimus dorsi of crossbred Boer × Saanen kids fed castor oil. Twenty-four kids (12 males and 12 females were assigned in a randomized complete block design with two treatments and twelve replications. Blocks were defined according to weight, gender and initial age of animals for the evaluation of performance. The experimental treatments consisted of two diets containing 900 g concentrate/kg: a control diet (without addition of oil and another containing castor oil at 30 g/kg (on a dry matter basis. After they reached an average body weight of 25 kg, males were slaughtered for the evaluation of carcass characteristics, chemical composition and fatty acid profile of the longissimus dorsi muscle. The addition of castor oil in the diet did not affect the intake of dry matter, crude protein and neutral detergent fiber; the average daily gain; and feed conversion, but increased the ether extract intake. No difference was observed for the carcass characteristics, chemical composition of the meat, concentration of C18:2 cis-9, trans-11 (CLA and total concentration of saturated, monounsaturated and polyunsaturated fatty acids and their relations; however, there was increase in the concentrations of C18:2 trans-10, cis-12 (CLA and C20:4 ω-6. The addition of castor oil to the diet of crossbred Boer × Saanen kids containing a high content of concentrate did not promote benefit to the characteristics evaluated.

  10. Stability assessment of injectable castor oil-based nano-sized emulsion containing cationic droplets stabilized by poloxamer-chitosan emulsifier films.

    Science.gov (United States)

    Tamilvanan, S; Kumar, B Ajith; Senthilkumar, S R; Baskar, Raj; Sekharan, T Raja

    2010-06-01

    The objectives of the present work were to prepare castor oil-based nano-sized emulsion containing cationic droplets stabilized by poloxamer-chitosan emulgator film and to assess the kinetic stability of the prepared cationic emulsion after subjecting it to thermal processing and freeze-thaw cycling. Presence of cryoprotectants (5%, w/w, sucrose +5%, w/w, sorbitol) improved the stability of emulsions to droplet aggregation during freeze-thaw cycling. After storing the emulsion at 4 degrees C, 25 degrees C, and 37 degrees C over a period of up to 6 months, no significant change was noted in mean diameter of the dispersed oil droplets. However, the emulsion stored at the highest temperature did show a progressive decrease in the pH and zeta potential values, whereas the emulsion kept at the lowest temperatures did not. This indicates that at 37 degrees C, free fatty acids were formed from the castor oil, and consequently, the liberated free fatty acids were responsible for the reduction in the emulsion pH and zeta potential values. Thus, the injectable castor oil-based nano-sized emulsion could be useful for incorporating various active pharmaceutical ingredients that are in size from small molecular drugs to large macromolecules such as oligonucleotides.

  11. Castor Oil Derivatives Terminal--Nylon 10 and 810%蓖麻油的终端衍生产品--尼龙10与810

    Institute of Scientific and Technical Information of China (English)

    赵学敬

    2016-01-01

    A brief description of castor oil terminal derivative products, as well as nylon 10 and 810, the article on their principles of chemical generation method, molecular structure, major equipment, preparation conditions, the physical and chemical properties, processing, and other products, to expand the reader castor oil chemical utilization perspective.%蓖麻油的终端衍生产品中,还有尼龙10及810,文章对它们的化工原理、生成方式、分子结构、主要设备、制取条件、物化性能、制品加工等作了简要介绍,以扩大读者对蓖麻油化工利用的视野。

  12. 无溶剂法合成环氧蓖麻油的工艺研究%Technical Study on Non-solvent Synthesis of Epoxidized Castor Oil

    Institute of Scientific and Technical Information of China (English)

    赵栋; 卢倩倩; 李驰宇; 史以俊; 何明; 罗振扬

    2011-01-01

    以可再生的蓖麻油为主要原料,H3P04作为催化剂,30% H2O2作为氧源,在无溶剂条件下合成环氧蓖麻油.通过正交实验的方法对蓖麻油环氧化反应进行了研究和探讨,得出最佳反应条件为:n(H202):n(蓖麻油双键)=1.4:1,n(甲酸):n(蓖麻油双键)=0.5:1,催化剂H3POa质量分数为蓖麻油的0.3%,反应时间6h,所得产物环氧值为3.23%,并采用红外光谱、碘值分析和薄.层色谱对环氧化产品进行了分析表征.%Using renewable castor oil as the main raw material, H3PO4 as catalyst and H2O2 (30%, mass fraction) as oxidation agent, epoxidized castor oil was prepared without solvent.The synthesis conditions were studied using orthogonal experiment.The optimized reaction conditions were as follows: n( H2O2): n( double bonds of castor oil) = 1.4: 1, n ( formic acid): n ( double bonds of castor oil) = 0.5: 1, the amount of catalyst H3PO4 was 0.3% and reaction time was 6 h.Under these optimized conditons, the epoxy value of the final product was 3.23%.FT-IR, iodine value analysis and TLC were employed to characterize the product.

  13. 蓖麻油基下游产物及蓖麻油增塑剂的研究及其应用进展%Research and application progress of castor oil-based downstream products and its plasticizer

    Institute of Scientific and Technical Information of China (English)

    许伟; 葛小东; 金丽珠; 邵荣

    2015-01-01

    随着全球化石资源消耗量的不断剧增,能源危机问题引起了广泛的关注。在植物资源能源化的利用中,以蓖麻油为原料开发高附加值下游产品已成为研究热点。本文介绍了国内外蓖麻油基下游产品的制备方法、产品性能及应用领域等方面。回顾了脱水蓖麻油、酯交换蓖麻油、环氧化蓖麻油、蓖麻油基聚氨酯等下游产物的制备与应用性能研究。简述了蓖麻油基增塑剂的种类及应用领域,具体分析了环氧乙酰蓖麻油酸甲酯的制备方法及产品特性。提出了在我国蓖麻油基增塑剂的生产过程中反应温度、催化剂用量等因素影响环氧基团稳定性的问题,指出目前我国催化合成蓖麻油基增塑剂的趋势和发展方向。%With the rapid consumption of fossil resources,the global energy crisis has caused serious concern. In the utilization of plant resources,the exploitation of downstream products,during which castor oil used as raw materials,has become to be a hot research area. The preparation methods, performance as well as the application fields of castor oil-based downstream products were introduced in this work. The preparation and properties of some castor oil-based downstream products,such as dehydrated castor oil,transesterification of castor oil,exploitation of castor oil,polyurethane of castor oil and so on,were reviewed. The types and application areas of castor oil-based plasticizers were sketched and the preparation methods and the properties of epoxidized methyl acetorieinoleate were analyzed. The problems of the effects of the reaction temperature and the dosage of catalyst on the stability of epoxy group in the production process of the castor oil-based plasticizer were discussed,and the developing trends in the field of castor oil-based plasticizers were proposed.

  14. HDO of guaiacol over NiMo catalyst supported on activated carbon derived from castor de-oiled cake

    Directory of Open Access Journals (Sweden)

    Viviana Ospina

    2015-08-01

    Full Text Available Physical and chemical activation methods were used to prepare two different activated carbons (ACs from castor de-oiled cake. H2O/CO2 mixture was used as the physical activating agent, and for chemical activation potassium carbonate (K2CO3 was used. For both materials, textural and chemical properties were characterized by N2 adsorption–desorption isotherms, thermogravimetric analysis (TGA, Fourier Transform Infrared Spectroscopy (FTIR, thermal programmed reduction (TPR, X-ray fluorescence (XRF, and scanning electron microscopy (SEM. The ACs were used as supports for NiMo sulfide catalysts, which were prepared by wetness impregnation and in-situ sulfided for the hydrodeoxygenation (HDO of guaiacol (GUA as a model compound of bio-oil. The HDO reaction was carried out in a typical batch reactor at 5 MPa of H2 and 350 °C. Under the same test conditions, commercial catalysts were also tested in the reaction. Although the commercial catalysts displayed higher GUA conversion, the prepared catalysts showed higher activity and non-oxygenated and saturated products yield. 

  15. AGRIFIS - simulator prospecting scenarios and evaluation of projects for production of seeds, in nature oil and castor oil biodiesel; AGRIFIS - simulador de prospeccao de cenarios e avaliacao de projetos de producao de sementes, oleo in natura e biodiesel de mamona

    Energy Technology Data Exchange (ETDEWEB)

    Polizel, L.H.; Tahan, C.M.V.; Pelegrini, M. A.; Soares, B.F. [Universidade de Sao Paulo (ENERQ/USP), SP (Brazil). Centro de Estudos em Regulacao e Qualidade de Energia], Email: cmvtahan@pea.usp.br; Takeno, H.K. [Companhia Energetica de Petrolina (CEP), PE (Brazil); Silva, O.C. da; Monteiro, B.; Velazquez, S.M.S.G. [Universidade de Sao Paulo (CENBIO/USP), SP (Brazil). Centro Nacional de Referencia em Biomassa; Drumond, M.A.; Anjos, J.B. dos [EMBRAPA Semi-Arido - Empresa Brasileira de Pesquisa Agropecuaria (EMBRAPA), Petrolina, PE (Brazil)

    2006-07-01

    This paper presents a model conceived for scenario prospection and project evaluation of small scale castor bean farming, oil extraction and bio diesel production (transesterification) integrated chain. To evaluate the performance of each project the model adopts financial, social and environmental index such as NPV, IRR, SPB, DPB, production costs, family income, number of settled families and employment. The model was implemented in a computational environment, allowing its use as a decision support tool for investments on the castor bean production chain; it calculates the cash flow of the entire project and of each family, including earnings, debts, taxes, interest and amortization. (author)

  16. 蓖麻油缩水甘油醚合成工艺研究%Synthesis Process of Castor Oil Glycidyl Ether

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    Using castor oil and epoxy chloropropane( ECH) as the main raw materials under the alkali condition, a novel castor oil glycidyl ether ( COGE) was synthesized through two steps, namely open loop and closed loop reaction. The effects of process conditions on epoxy values were investigated. The results showed that the highest epoxy value the product achieved was 1. 56 mmol/g under the condition that the open loop reaction was set at 0. 4% catalyst dosage,3. 5 molar ratio of ECH and castor oil, and reaction temperature at 60 ℃ for 5 h, and as well as the close-loop reaction was set 0. 4% catalyst dosage, 1. 1 molar ratio of NaOH and ECH, and reaction temperature at 60 ℃ for 6 h. The chemical structure of the castor oil glycidyl ether was characterized by FT-IR and 1H NMR. TGA analysis showed that castor oil glycidyl ether had good thermal stability at high temperature. Viscosity test showed that the product could reduce the viscosity of epoxy resin.%以蓖麻油、环氧氯丙烷( ECH)和液碱为主要原料,经二步法开环闭环反应合成了蓖麻油缩水甘油醚( COGE),研究了开环、闭环工艺条件对产物环氧值的影响。结果表明,开环催化剂三氟化硼-二乙基醚用量0.4%,ECH与蓖麻油的物质的量比3.5∶1,反应温度60℃,反应时间5 h;闭环催化剂四甲基氯化铵用量0.4%,反应时间6 h,反应温度60℃,NaOH与ECH物质的量比1.1∶1时产物环氧值最高为1.56 mmol/g。采用红外光谱(FT-IR)、核磁共振氢谱(1H NMR)表征了合成产物的化学结构,热失重(TG)分析表明蓖麻油缩水甘油醚具有优良的高温热稳定性,黏度测试表明该产物可以降低环氧树脂的黏度,加入量15%时,黏度降低46%。

  17. Analysis of the gamma radiation effects in the composite of polyurethane derived from castor oil and natural fibers; Analise dos efeitos da radiacao gama no composito de poliuretano derivado de mamona com serragem

    Energy Technology Data Exchange (ETDEWEB)

    Kienen, Victor D.; Todt, Matheus L.; Capellari, Giovanni S.; Azevedo, Elaine C. [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil); Neto, Salvador C. [Universidade de Sao Paulo (IQSC/USP), Sao Carlos, SP (Brazil)

    2013-07-01

    Composite of Polyurethane derived from castor oil and natural fibers are obtained from renewable raw material, low cost, and for not assaulting nature. This paper analyzes the effects of gamma radiation on composite polyurethane derived from castor with sawdust irradiated with gamma radiation of 25 kGy . It was held from 3 tips bending tests and micrograph by scanning electron microscopy. The results indicate that gamma radiation decreases the breakdown voltage and the micrograph of the fracture indicates brittle fracture occurred. (author)

  18. 混合催化剂催化蓖麻油合成蓖麻油多元醇%Preparation of Castor Oil Polyol by Mixed Catalyst

    Institute of Scientific and Technical Information of China (English)

    张立强; 张猛; 周永红; 胡丽红; 杨晓慧

    2013-01-01

    The castor oil polyols were prepared by using renewable castor oil as the main raw material,using sodium methoxide and triethanolamine as mixed catalyst,through transesterification reaction with cheap glycerol in nitrogen atmosphere.The effects of catalyst dosage,mass ratio,reaction temperature and reaction time on the conversion rate of castor oil monoglycerides,castor oil Kennedy diester and all product were investigated,respectively.The chemical structures,molecular mass and yield of the products were characterized by means of FT-IR,GPC.The optimum process was optimized by single variable experiment.The highest yield(92.54%) of castor oil polyol was obtained when mixed catalyst dosage was 0.75% of the castor oil mass,reaction temperature was 180 ℃,the mass ratio of castor oil and glycerol was 50 ∶ 12.33 and reaction time was 2.5 hours.Compared with sodium methoxide and tetrabutyl titanate as catalyst,not only the convention rate but also the hydroxyl value of the product was improved using the mixed catalyst,and the color of the product was reduced.%以可再生的蓖麻油为主要原料,首次采用甲醇钠和三乙醇胺为混合催化剂,与甘油在N2环境中发生酯交换反应,生成蓖麻油单甘脂和蓖麻油甘二酯.考察了催化剂用量、甘油用量、反应温度、反应时间对蓖麻油单甘脂转化率、蓖麻油甘二酯转化率和总转化率的影响,并与传统的催化剂甲醇钠、钛酸四丁酯催化酯交换反应进行了比较.采用FT-IR、GPC对产物的结构、相对分子质量和转化率进行了表征.通过单一变量控制法对反应的条件进行优化.结果表明,催化剂用量为蓖麻油质量的0.75%、蓖麻油和甘油的质量比为50∶12.33、反应温度为180℃、反应时间为2.5h时,蓖麻油多元醇的转化率最高,可达92.54%,与传统催化剂相比较,混合催化剂不仅提高了产物的转化率和羟值,而且使产品的色泽降低.

  19. Performance and Emission Characteristics of a Compression Ignition Engine Operating on Blends of Castor Oil Biodiesel-Diesel

    Science.gov (United States)

    Kanwar, Roopesh; Sharma, Pushpendra Kumar; Singh, Aditya Narayan; Agrawal, Yadvendra Kumar

    2016-06-01

    Diesel vehicles are the nerves and veins of transportation, particularly in developing countries. With the rapid rate of modernization, increasing demand of fuel is inevitable. The exponential increase in fuel prices and the scarcity of its supply from the environment have promoted interest in the development of alternative sources of fuel. In this work, genus Ricinus communis L. was studied in order to delimit their potential as a raw material for biodiesel production. Further, castor oil, ethyl ester were prepared by transesterification using potassium hydroxide (KOH) as a catalyst and tested on a four-stroke, single-cylinder compression ignition engine. The test was carried out at a constant speed of 3000 rpm at different loads. The results represent a substantial decrease in carbon monoxide (CO) emission with an increasing biodiesel percentage. The reduction of CO in B05, B10, B15 and B20 averaged 11.75, 22.02, 24.23 and 28.79 %, respectively, compared to mineral diesel. The emission results of the comparative test indicated that CO, oxygen (O2) and smoke density emissions are found to be lower when the engine is filled with B05, B10, B15 and B20 as compared to mineral diesel, while carbon dioxide (CO2) and nitrogen oxide (NOx) with B05, B10, B15 and B20 are found to increase marginally. Brake thermal efficiency and brake specific fuel consumption decrease and increase respectively in biodiesel with different blends in comparison of mineral diesel.

  20. Production of a novel mannosylerythritol lipid containing a hydroxy fatty acid from castor oil by Pseudozyma tsukubaensis.

    Science.gov (United States)

    Yamamoto, Shuhei; Fukuoka, Tokuma; Imura, Tomohiro; Morita, Tomotake; Yanagidani, Shusaku; Kitamoto, Dai; Kitagawa, Masaru

    2013-01-01

    Mannosylerythritol lipids (MELs) are glycolipid biosurfactants produced by various yeasts belonging to the genus Pseudozyma, which exhibit excellent surface activities as well as versatile biochemical activities. A study on P. tsukubaensis NBRC1940 as a mono-acetylated MEL (MEL-B) producer revealed that the yeast accumulated a novel glycolipid from castor oil at a yield of 22 g/L. Its main chemical structure was identified as 1-O-β-(2'-O-alka(e)noyl-3'-O-hydroxyalka(e)noyl-6'-O-acetyl-D-mannopyranosyl)-D-erythritol designated as "new MEL-B." The new MEL-B, comprising a hydroxy fatty acid had a reduced surface tension of 28.5 mN/m at a critical micelle concentration (CMC) of 2.2×10⁻⁵ M in water. The observed CMC was 5-fold higher than that of conventional MEL-B. When conventional MEL-B was dispersed in water, it self-assembled to form the lamellar (L(α)) phase at a wide range of concentrations. In contrast, new MEL-B formed spherical oily droplets similar to the sponge (L₃) phase, which is observed in aqueous solutions of di-acetylated MEL (MEL-A). The data suggest that the newly identified MEL-B is likely to have a different structure and interfacial properties compared to the conventional MELs, and could facilitate an increase in the application of glycolipid biosurfactants.

  1. Structure and mechanical properties of new biomass-based nanocomposite: castor oil-based polyurethane reinforced with acetylated cellulose nanocrystal.

    Science.gov (United States)

    Lin, Song; Huang, Jin; Chang, Peter R; Wei, Siwen; Xu, Yixiang; Zhang, Qiaoxin

    2013-06-01

    New nanocomposites consisting of a castor oil-based polyurethane matrix filled with acetylated cellulose nanocrystals (ACNs) were developed. The ACN exhibited improved dispersion in tetrahydrofuran as a blending medium, and reduced polarity as compared with unmodified cellulose nanocrystals, resulting in a high loading level of 25 wt% in the nanocomposite. As the ACN loading-level increased from 0% to 25%, the tensile strength and Young's modulus of the nanocomposites increased from 2.79 MPa to 10.41 MPa and from 0.98 MPa to 42.61 MPa, respectively. When the ACN loading-level was 10 wt%, the breaking elongation of the nanocomposites reached the maximum value of more than twice that of the polyurethane. The enhanced mechanical performance was primarily attributed to the formation of a three-dimensional ACN network and strong interfacial interactions between filler and matrix. This work produced new polyurethane-based nanocomposites containing modified cellulose nanocrystal with a high biomass content. Its high performance could contribute to potential applications.

  2. Synthesis and characterization of gold nanotube/nanowire-polyurethane composite based on castor oil and polyethylene glycol.

    Science.gov (United States)

    Ganji, Yasaman; Kasra, Mehran; Salahshour Kordestani, Soheila; Bagheri Hariri, Mohiedin

    2014-09-01

    Gold nanotubes/nanowires (GNT/NW) were synthesized by using the template-assisted electrodeposition technique and mixed with castor oil-polyethylene glycol based polyurethane (PU) to fabricate porous composite scaffolds for biomedical application. 100 and 50 ppm of GNT/NW were used to synthesize composites. The composite scaffolds were characterized by Fourier transform infrared spectroscopy, dynamic mechanical thermal analysis, differential scanning calorimetry, and scanning electron microscopy. Cell attachment on polyurethane-GNT/NW composites was investigated using fat-derived mesenchymal stem cells. Addition of 50 or 100 ppm GNT/NW had significant effects on thermal, mechanical, and cell attachment of polyurethane. Higher crosslink density and better cell attachment and proliferation were observed in polyurethane containing 50 ppm GNT/NW. The results revealed that GNT/NW formed hydrogen bonding with the polyurethane matrix and improved the thermomechanical properties of nanocomposites. Compared with pure PU, better cellular attachment on polyurethane-GNT/NW composites was observed resulting from the improved surface properties of composites.

  3. Wound Healing Bionanocomposites Based on Castor Oil Polymeric Films Reinforced with Chitosan-Modified ZnO Nanoparticles.

    Science.gov (United States)

    Díez-Pascual, Ana M; Díez-Vicente, Angel L

    2015-09-14

    Castor oil (CO), which is a readily available, relatively inexpensive, and environmentally benign nonedible oil, has been successfully used as matrix material to prepare biocompatible and biodegradable nanocomposite films filled with chitosan (CS)-modified ZnO nanoparticles. The biocomposites were synthesized via a simple and versatile solution mixing and casting method. The morphology, structure, thermal stability, water absorption, biodegradability, cytocompatibility, barrier, mechanical, viscoelastic, antibacterial, and wound healing properties of the films have been analyzed. FT-IR spectra were used to obtain information about the nanoparticle-matrix interactions. The thermal stability, hydrophilicity, degree of porosity, water absorption, water vapor transmission rate (WVTR), oxygen permeability (Dk), and biodegradability of the films increased with the CS-ZnO loading. The WVTR and Dk data obtained are within the range of values reported for commercial wound dressings. Tensile tests demonstrated that the nanocomposites displayed a good balance between elasticity, strength, and flexibility under both dry and simulated body fluid (SBF) environments. The flexibility increased in a moist atmosphere due to the plasticization effect of absorbed water. The nanocomposites also exhibited significantly enhanced dynamic mechanical performance (storage modulus and glass transition temperature) than neat CO under different humidity conditions. The antibacterial activity of the films against Escherichia coli, Staphylococcus aureus, and Micrococcus luteus bacteria was investigated in the presence and the absence of UV light. The biocide effect increased progressively with the CS-ZnO content and was systematically stronger against Gram-positive cells. Composites with nanoparticle loading ≤5.0 wt % exhibited very good in vitro cytocompatibility and enabled a faster wound healing than neat CO and control gauze, hence showing great potential to be applied as antibacterial

  4. Synthesis and characterisation of simultaneous interpenetrating polymer networks (SIN formed by polystyrene and polyurethane obtained from castor oil and cassava starch polyol-suspensions

    Directory of Open Access Journals (Sweden)

    Juan Manuel Cabrera Anaya

    2011-01-01

    Full Text Available Castor oil was modified by transesterification with pentaerythritol and cassava starch was subsequently incorporated into this oil (oil modified by incorporating starch is called a polyol-suspension. Polyurethane/polystyrene SINs (simulta- neously produced IPNs were synthesised from them and styrene. Reactants used in the synthesis were MDI (methylene diphenyl diisocyanate as diisocyanate, DVB (divinylbenzene as crosslinking agent for polystyrene, dibutylamine as redox primer and benzoyl peroxide as styrene polymerisation primer. The variables considered in SIN synthesis were percentage weight ratio used in the modification (1.32%; 2.64% and 5.28% to increase polyol hydroxyl functionality, starch species incorporated into polyol (Brazilian, Venezuelan and commercial to vary the amount of amylopectin within the polyol-suspension, diisocyanate/hydroxyl NCO/OH (0.85 and 1 functional groups’ molar ratio and polyurethane/ polystyrene PU/PS weight ratio (70/30 and 80/20. A wide range of materials was obtained and characterised by tensile strength, hardness, chemical attack and Soxhlet extraction. The physical-mechanical properties of the materials produced with polyols (transesterified castor oil were improved when starch was incorporated into the polyol. Several tests indicated that 24 hours as curing time were not enough, because the SINs showed lower physical-mechanical properties than the homologous polyurethane elastomers did; thus, the curing time had to be increased to 48 hours.

  5. Acyl-ACP thioesterases from castor (Ricinus communis L.): an enzymatic system appropriate for high rates of oil synthesis and accumulation.

    Science.gov (United States)

    Sánchez-García, Alicia; Moreno-Pérez, Antonio J; Muro-Pastor, Alicia M; Salas, Joaquín J; Garcés, Rafael; Martínez-Force, Enrique

    2010-06-01

    Acyl-acyl carrier protein (ACP) thioesterases are enzymes that terminate the intraplastidial fatty acid synthesis in plants by hydrolyzing the acyl-ACP intermediates and releasing free fatty acids to be incorporated into glycerolipids. These enzymes are classified in two families, FatA and FatB, which differ in amino acid sequence and substrate specificity. In the present work, both FatA and FatB thioesterases were cloned, sequenced and characterized from castor (Ricinus communis) seeds, a crop of high interest in oleochemistry. Single copies of FatA and FatB were found in castor resulting to be closely related with those of Jatropha curcas. The corresponding mature proteins were heterologously expressed in Escherichia coli for biochemical characterization after purification, resulting in high catalytic efficiency of RcFatA on oleoyl-ACP and palmitoleoyl-ACP and high efficiencies of RcFatB for oleoyl-ACP and palmitoyl-ACP. The expression profile of these genes displayed the highest levels in expanding tissues that typically are very active in lipid biosynthesis such as developing seed endosperm and young expanding leaves. The contribution of these two enzymes to the synthesis of castor oil is discussed.

  6. 蓖麻油缓释微囊的研制%Study on the Preparation of Sustained-release Castor Oil Microcapsule

    Institute of Scientific and Technical Information of China (English)

    常明; 岳红坤; 牟微; 李慧; 郭敬敬

    2011-01-01

    [目的]对蓖麻油进行微胶囊化,制成蓖麻油缓释微胶囊.[方法]运用复凝聚法,以明胶和阿拉伯胶为囊材,蓖麻油为囊心物制备微囊.借助显微镜观察微囊形态;通过紫外分光光度计进行蓖麻油含量测定;以水为溶出介质考察该制剂的体外溶出情况;以包封率作为质量判定指标,采用单因素考察和正交试验优化处方工艺.[结果]蓖麻油缓释微囊的最佳制备工艺条件为:明胶和阿拉伯胶浓度皆为7.5%,甲醛用量为1.0 ml,pH值为3.80,材药比为6:1.按该处方制得的微囊囊型圆整光滑,载药量较高,并具有一定的缓释效果.[结论]复凝聚法可成功制备出包封率较高的蓖麻油缓释微囊,且产品稳定性良好.该法可操作性强,重复性好,有一定的实用价值.%[ Objective ] Microencapsulation was carried out for castor oil, thus, sustained-release castor oil microcapsule was prepared. [ Method ]Complex coacervation method was used, and taking gelatin and Arabic gum as capsule materials, in addition, castor oil was viewed as core materials to prepare micro-capsule. The shapes of microcapsules were observed with the help of microscope, the content of castor oil was determined based on ultraviolet spectrophotometer; and dissolution rate in vitro with water were investigated. With encapsulation efficiency as quahty evaluation index, furthermore, the prescription was optimized by single phoneme and orthogonal experiment. [ Result ] The best preparation technological conditions of sustained-release castor oil microcapsule were:the gelatin and the Arabic gum density was 7.5%, the formaldehyde amount was the 1.0 ml, pH value was 3.80, the proportion of raw material to medicine was 6∶1. According to this prescription, the shape of micro-capsule was rounding and smooth, and showed larger loading capacity, moreover, had certain sustained-release effect. [ Conclusion ] The duplicate condensation law may successfully prepared

  7. Study on Property of Castor Oil Based Polyurethane Modified Asphalt%蓖麻油基聚氨酯改性沥青的性能研究

    Institute of Scientific and Technical Information of China (English)

    夏磊; 张海燕; 曹东伟; 郭燕生

    2016-01-01

    To develop a new type of modified asphalt and its preparation process, the castor oil contained asphalt is obtained with green renewable castor oil instead of petroleum based polyols at first, then the second monomer liquefied MDI is slowly dropped into pitch system with shearing and the castor oil based polyurethane ( PU) modified asphalt is prepared. The dosage of castor oil and the second monomer MDI are calculated by isocyanate index R( -NCO/ -OH) =1. 8, and the modified asphalt with 10% -30% content of castor oil based PU are synthesized. The performance of modified asphalt are characterized by conventional experiment. The experiment result shows that the modifier in asphalt dispersed evenly and both the high and low temperature performance of the castor oil based PU modified asphalt are improved, especially the high temperature performance. The high temperature grade of asphalt is determined by the original grade test and thin film oven tests ( TFOT) grade test on the samples. On the basis of high temperature grade, the high temperature performances of different asphalts after aging are analysed and evaluated by multiple stress creep recovery ( MSCR) test. The result shows that the creep compliance of the modified asphalt declined greatly and recovery rate raised obviously compared with base asphalt, which effectively achieved the effect of increasing elasticity and stiffening. With the increase of the modifier dosage, creep compliance declined and recovery rate raised in the same time, the modification effect is better.%为开发一种新型改性沥青及其制备工艺,以绿色可再生的蓖麻油代替石油基多元醇,先制成含油沥青,在沥青体系中再缓慢滴加第二单体液化二苯基甲烷二异氰酸酯(MDI),边剪切边制成蓖麻油基聚氨酯改性沥青.通过异氰酸酯指数R(-NCO/-OH)=1.8,按10%~30%总体改性剂掺量,计算出蓖麻油及第二单体MDI的用量,分别制备10%~30%的蓖麻油基聚氨酯改性沥青.通

  8. 蓖麻油脂肪酸镁生产技术研究与应用%Production Technology Research and Application of Magnesium Castor Oil Fatty Acid

    Institute of Scientific and Technical Information of China (English)

    王恩; 许广秀

    2011-01-01

    In this thesis,the production technology of Magnesium castor oil fatty acid was studied,saponification reaction,double decomposition reaction,spin-drying,drying processes,etc were studied specially to determine the appropriate technology specification.%研究了蓖麻油脂肪酸镁的生产技术,对生产过程中的皂化反应、复分解反应、甩干、烘干工序等进行了专题研究,确定了相应的工艺技术指标.

  9. Effects of ricinoleic acid esters from castor oil of Ricinus communis on the vitellogenesis of Rhipicephalus sanguineus (Latreille, 1806) (Acari: Ixodidae) ticks.

    Science.gov (United States)

    Arnosti, André; Brienza, Paula Desjardins; Furquim, Karim Christina Scopinho; Chierice, Gilberto Orivaldo; Bechara, Gervásio Henrique; Calligaris, Izabela Braggião; Camargo-Mathias, Maria Izabel

    2011-02-01

    This study examines the effects of ricinoleic acid esters from Ricinus communis castor oil on the vitellogenesis of Rhipicephalus sanguineus ticks attached to hosts that were fed with commercial rabbit food containing these esters. The oocytes of ticks from the treatment group (TG) showed cytoplasmic changes that inhibited the development of oocytes I and II to the advanced stages (IV and V) in addition to preventing the maturation of oocytes V, resulting in small ones. In addition, sperm was not observed in ampoules. Our findings confirm the acaricide potential of ricinoleic acid esters.

  10. Experimental evaluation of the performance and emissions of diesel engines using blends of crude castor oil and diesel; Avaliacao experimental do desempenho e emissoes de motores diesel usando misturas de oleo de mamona e oleo diesel

    Energy Technology Data Exchange (ETDEWEB)

    Pimentel, Valeria Said de Barros; Pereira, Pedro Paulo [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Dept. de Engenharia Mecanica; Belchior, Carlos Rodrigues Pereira [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Dept. de Engenharia Oceanica

    2004-07-01

    This work refers to the experimental evaluation of diesel generators operating with blend of crude castor oil and diesel. Performance and emissions tests were accomplished in a diesel engine of direct injection. Because of the high viscosity of the blend a device was installed on the engine in order to lower the blend viscosity. A comprehensive analysis of the results obtained in these tests indicates the possibility of use of the blend of castor oil and diesel as fuel for diesel-generators, with modifications introduced in the engines. (author)

  11. 蓖麻油合成尼龙-11树脂可行性研究%STUDY ON THE SYNTHESIS OF OYLON-11 RESIN FEASIBILITY OF CASTOR OIL

    Institute of Scientific and Technical Information of China (English)

    王枝光; 孙天鹤; 王宏波

    2014-01-01

    论述了蓖麻油的发展和应用开发。阐述了尼龙11的国内外研究现况,最后介绍了以蓖麻油为原料合成尼龙11的生产工艺和可行性研究。%The development and application of castor oil are elucidated. Describes the research status of nylon 11 at home and abroad, finally introduced the research process and the feasibility of synthetic nylon11 with castor oil as raw material.

  12. 蓖麻油酸甲酯乙氧基化物洗涤性能的研究%Washing performance of ethoxylated castor oil acid methyl esters

    Institute of Scientific and Technical Information of China (English)

    张谦; 孙永强; 王万绪; 智丽飞; 张勇; 孙晋源; 武华萍

    2015-01-01

    The washing properties of different average ethylene oxide (EO) adduct number of ethoxylated castor oil acid methyl esters (ECAME) was tested and the hydrolysis resistant ability of ECAME was investigat-ed under different pH. The results showed that ethoxylated castor oil acid methyl esters with 14 of EO adduct number (ECAME- 14) had the best washing property. The hydrolysis rate of ECAME- 14 was low under pH=4~9 for 4 weeks. Under alkaline condition, the surface activity of ECAME- 14 was weakened while its surface ac-tivity was enhanced under acidic condition.%对不同平均环氧乙烷(EO)加合数的蓖麻油酸甲酯乙氧基化物(ECAME)的洗涤性能进行了测定,并考察了其在不同pH条件下的抗水解能力.结果表明,平均EO加合数为14的蓖麻油酸甲酯乙氧基化物(ECAME-14)的洗涤能力最好.在pH为4~9的溶液中放置4周,ECAME-14水解率很低.在碱性条件下,其表面活性被削弱,但在酸性条件下,其表面活性增强.

  13. Research on Castor Oil Modified Epoxy Primer for Polyurea%蓖麻油改性环氧基聚脲底漆的研究

    Institute of Scientific and Technical Information of China (English)

    张虎; 张伶俐; 陈博远; 李国荣; 廖昔虬; 纪凤龙

    2013-01-01

    Aproprietary epoxy primer for polyurea was prepared with castor oil, silane coupling agent, etc. In the film -forming process, castor oil's hydroxyl was bonded on substrate via hydrogen bond, which also reacted with the residual isocyanate group (-NCO) in polyurea layer, forming a bridge, reducing the internal stress of the paint film and improving the film flexibility, impact resistance, bonding strength and peel resistance.%采用蓖麻油、硅烷偶联剂等制备了聚脲专用环氧树脂底漆.在底漆的成膜过程中,蓖麻油能与基材形成氢键,同时与聚脲层中残留的异氰酸根(-NCO)反应,起到桥接作用,降低了漆膜的内应力,改善了漆膜柔韧性、耐冲击性,提高了粘结强度及耐剥离性能.

  14. Studies on interfacial tension and contact angle of synthesized surfactant and polymeric from castor oil for enhanced oil recovery

    Science.gov (United States)

    Babu, Keshak; Pal, Nilanjan; Bera, Achinta; Saxena, V. K.; Mandal, Ajay

    2015-10-01

    New synthesized polymeric surfactants have immensely attracted the researchers for further development of chemical enhanced oil recovery method particularly in surfactant flooding. Contact angle and interfacial tension measurement tests are the effective ways to identify proper chemicals/surfactants for enhanced oil recovery by chemical/surfactant flooding. In the present study a new polymeric surfactant was synthesized from pre-synthesized sodium methyl ester sulfonate (surfactant) and acrylamide for application in chemical enhanced oil recovery. The synthesized surfactant and polymeric surfactant were used to measure interfacial tension between their aqueous phase and crude oil phase to investigate the efficiency of the surfactants in reduction of interfacial tension. The synthesized polymeric surfactant has also ability to control the mobility because of its viscous nature in aqueous solution. Contact angles of solid-crude oil-surfactant interface were also measured to study the effect of the synthesized surfactant and polymeric surfactant on wettability alteration mechanism. Synergistic effect was studied by using NaCl and synthesized surfactants on interfacial tension. Dynamic interfacial tensions of the surfactant and polymeric surfactant solutions with crude oil were measured at different NaCl concentrations. Interfacial tension was found to be lowered up to 10-2 to 10-3 mN/m which is effective for oil recovery. Measurement of contact angle indicates the wettability change of the quartz surface. Comparative studies on efficiencies of synthesized sodium methyl ester sulfonate surfactant and polymeric surfactant were also carried out with respect to interfacial tension reduction and contact angle change.

  15. Proposition to use 'in natura' vegetable oil and biodiesel from castor oil in thermal power plants; Proposicao de uso de oleo vegetal in natura e biodiesel de mamona em termeletricas

    Energy Technology Data Exchange (ETDEWEB)

    Soares, B.F.; Tahan, C.M.V.; Pelegrini, M.A.; Polizel, L.H. [Universidade de Sao Paulo (ENERQ/USP), SP (Brazil). Centro de Estudo em Regulacao e Qualidade de Energia; Vandelli, M.V.M. [Termocabo Ltda., Recife, PE (Brazil); Takeno, H.K. [Companhia Energetica de Petrolina (CEP), PE (Brazil)

    2006-07-01

    This paper proposes the adoption of renewable fuels on thermal power plants using diesel or high sulfur fuel oil generator sets. The renewable fuels proposed to partially or fully replace the fossil fuels are castor oil in natura or transesterified (biodiesel). Physical and chemical analyses were carried out on laboratory, establishing the energetic performance of each sample. The results showed that mixtures of bio diesel-fossil fuel offers similar performance when compared to the conventional fuels, allowing its use on thermal power plants in a satisfactory basis. (author)

  16. 蓖麻油及其衍生物的制备与应用研究进展%Research advance in preparation and application of castor seed oil and its derivatives

    Institute of Scientific and Technical Information of China (English)

    黄晓义; 路遥

    2011-01-01

    As a kind of cheap and essential reproducible bio - resource, castor seed oil is used widely in the chemical field, medicine and national defense. The research progresses of castor seed oil and its derivatives in polyurethane materials, biodiesel, coating, lubricants, nylon and medicine were introduced.Castor seed oil could be used as raw stuff to prepare many materials which could solve the problem of absent petroleum and extend its application fields, and promote the development of castor seed oil deep -processing industrial.%蓖麻油作为一种价格低廉的可再生资源,在化工、医药、国防等领域有着广泛应用.介绍了蓖麻油及其衍生物在聚氨醋材料、生物柴油、涂料、润滑油、尼龙材料、药物等方面的应用研究进展,指出以蓖麻油为原料改性和制备各种产品不仅可缓解对日趋紧缺的石油资源的依赖,而且拓宽了蓖麻油的应用领域,对于推动我国蓖麻油深加工的发展有着重要意义.

  17. Tissue-specific expression and post-translational modifications of plant- and bacterial-type phosphoenolpyruvate carboxylase isozymes of the castor oil plant, Ricinus communis L.

    Science.gov (United States)

    O'Leary, Brendan; Fedosejevs, Eric T; Hill, Allyson T; Bettridge, James; Park, Joonho; Rao, Srinath K; Leach, Craig A; Plaxton, William C

    2011-11-01

    This study employs transcript profiling together with immunoblotting and co-immunopurification to assess the tissue-specific expression, protein:protein interactions, and post-translational modifications (PTMs) of plant- and bacterial-type phosphoenolpyruvate carboxylase (PEPC) isozymes (PTPC and BTPC, respectively) in the castor plant, Ricinus communis. Previous studies established that the Class-1 PEPC (PTPC homotetramer) of castor oil seeds (COS) is activated by phosphorylation at Ser-11 and inhibited by monoubiquitination at Lys-628 during endosperm development and germination, respectively. Elimination of photosynthate supply to developing COS by depodding caused the PTPC of the endosperm and cotyledon to be dephosphorylated, and then subsequently monoubiquitinated in vivo. PTPC monoubiquitination rather than phosphorylation is widespread throughout the castor plant and appears to be the predominant PTM of Class-1 PEPC that occurs in planta. The distinctive developmental patterns of PTPC phosphorylation versus monoubiquitination indicates that these two PTMs are mutually exclusive. By contrast, the BTPC: (i) is abundant in the inner integument, cotyledon, and endosperm of developing COS, but occurs at low levels in roots and cotyledons of germinated COS, (ii) shows a unique developmental pattern in leaves such that it is present in leaf buds and young expanding leaves, but undetectable in fully expanded leaves, and (iii) tightly interacts with co-expressed PTPC to form the novel and allosterically-desensitized Class-2 PEPC heteromeric complex. BTPC and thus Class-2 PEPC up-regulation appears to be a distinctive feature of rapidly growing and/or biosynthetically active tissues that require a large anaplerotic flux from phosphoenolpyruvate to replenish tricarboxylic acid cycle C-skeletons being withdrawn for anabolism.

  18. Weed management strategies for castor bean crops

    Directory of Open Access Journals (Sweden)

    Augusto Guerreiro Fontoura Costa

    2014-04-01

    Full Text Available Castor bean crops are agriculturally relevant due to the quality and versatility of their oil, both for the chemical industry and for biodiesel production. Proper weed management is important for both the cultivation and the yield of castor bean crops; therefore, the intention of the present work is to review pertinent information regarding weed management, including the studies regarding weed interference periods, chemical controls for use in different crop production systems and herbicide selectivity, for castor bean crops. Weed science research for castor bean crops is scarce. One of the main weed management challenges for castor bean crops is the absence of herbicides registered with the Ministry of Agriculture, Livestock and Food Supply (MALFS. Research for viable herbicides for weed control in castor bean crops should be directed by research and/or rural extension institutions, associations and farmers cooperatives, as well as by manufactures, for the registration of these selective herbicides, which would be primarily used to control eudicotyledons in castor bean crops. New studies involving the integration of weed control methods in castor bean also may increase the efficiency of weed management, for both small farmers using traditional crop methods in the Brazilian Northeast region, as well as for areas with the potential for large scale production, using conservation tillage systems, such as the no-tillage crop production system.

  19. Síntesis y caracterización de adhesivos reposicionables de poliuretano dispersos en agua, obtenidos a partir de aceite de castor maleinizado Synthesis and characterization of pressure-sensitive adhesives of waterborne polyurethane from maleinizated castor oil

    Directory of Open Access Journals (Sweden)

    Paula Mazo

    2010-06-01

    Full Text Available El presente trabajo se centró en la producción de dispersiones acuosas de poliuretano empleando el método de emulsificación por inversión de fases. Para la síntesis fueron empleados dos polioles: uno comercial tipo poliéster y el otro es aceite de castor maleinizado (MACO; dos diisocianatos, uno aromático Toluen diisocianato (TDI y otro alifático Hexametilen diisocianato (HDI, siendo poco comunes para esta aplicación. Como emulsificante interno se empleó ácido cítrico el cual es muy económico y de fácil adquisición. Como factores se evaluaron la cantidad de ácido cítrico y la relación molar de grupos isocianato a hidroxilos (NCO/OH, generando un diseño de experimentos factorial 3² y minimizando el contenido de sólidos sedimentados. Mediante la metodología de superficie de respuesta, se obtuvo una ecuación polinomial cuadrática por un análisis de regresión múltiple. Los poliuretanos formados fueron evaluados en cuanto a sus propiedades adhesivas y mecánicas (pegajosidad tack, pegajosidad en cinta loop tack, cohesión hold, pelado peel, lo que permitió clasificar el adhesivo como reposicionable, para emplearlo en etiquetas.This work focused on the production of aqueous dispersions of polyurethane using the emulsification method by phase inversion. For the synthesis two polyols were employed, viz. a commercial polyester and Maleinizated Castor Oil (MACO, with two diisocyanates: one aromatic, toluene diisocyanate (TDI and another aliphatic, hexamethylene diisocyanate (HDI, which are not common for this application. Citric acid was used as internal emulsifier which is inexpensive and readily available. The parameters were the amount of citric acid and the mole ratio of isocyanate groups to hydroxyl (NCO/OH, generating a 3² factorial design, with minimization of the sedimented solids. The surface methodology was used to obtain a quadratic polynomial equation by multiple regression analysis. Polyurethanes synthesized were

  20. 蓖麻油用作喷气燃料润滑剂的润滑性及润滑机制%Lubricity and Lubricating Mechanism of Castor Oil as Lubricity Improver of Jet Fuel

    Institute of Scientific and Technical Information of China (English)

    李进; 陈国需; 胡泽祥; 赵立涛; 杜鹏飞

    2015-01-01

    The castor oil was characterized using Infrared spectrometer and its tribological properties as anti⁃wear addi⁃tive in jet fuel were evaluated using the High Frequency reciprocating rig (HFRR).The morphologies and elemental distri⁃butions of the worn steel surface lubricated by castor oil were analyzed by means of scanning electron microscopy and EDS for discussing its lubricating mechanism.The results show that the jet fuel shows a good sensitivity to castor oil, and castor acid contributes to improve the lubricity of jet fuel.The anti⁃wear mechanism of castor oil can be concluded that castor acid is adsorbed on the metal surface physically at first, while a chemical⁃adsorbing film of containing oxygen is formed at a mass addition of castor oil, resulting in a good lubricating effect.%利用红外光谱仪分析蓖麻油结构特征,采用高频往复试验机HFRR考察蓖麻油在喷气燃料中的摩擦学性能,利用SEM及EDS能谱仪对蓖麻油润滑下的钢球磨斑形貌和表面组成进行分析,并探讨其润滑机制。结果表明,喷气燃料对蓖麻油具有较好的感受性,蓖麻油在喷气燃料中具有一定润滑作用,其作用机制可能是蓖麻酸先物理吸附在金属表面上,形成一层物理吸附膜,随着蓖麻油添加量的增加,蓖麻油开始化学吸附在金属表面上,形成了一层含氧的化学保护膜,起到了抗磨效果。

  1. The bacterial-type phosphoenolpyruvate carboxylase isozyme from developing castor oil seeds is subject to in vivo regulatory phosphorylation at serine-451.

    Science.gov (United States)

    Dalziel, Katie J; O'Leary, Brendan; Brikis, Carolyne; Rao, Srinath K; She, Yi-Min; Cyr, Terry; Plaxton, William C

    2012-04-01

    Phosphoenolpyruvate carboxylase (PEPC) is a tightly controlled anaplerotic enzyme situated at a pivotal branch point of plant carbohydrate-metabolism. In developing castor oil seeds (COS) a novel allosterically-densensitized 910-kDa Class-2 PEPC hetero-octameric complex arises from a tight interaction between 107-kDa plant-type PEPC and 118-kDa bacterial-type PEPC (BTPC) subunits. Mass spectrometry and immunoblotting with anti-phosphoSer451 specific antibodies established that COS BTPC is in vivo phosphorylated at Ser451, a highly conserved target residue that occurs within an intrinsically disordered region. This phosphorylation was enhanced during COS development or in response to depodding. Kinetic characterization of a phosphomimetic (S451D) mutant indicated that Ser451 phosphorylation inhibits the catalytic activity of BTPC subunits within the Class-2 PEPC complex.

  2. Study of castor oil polyurethane - poly(methyl methacrylate semi-interpenetrating polymer network (SIPN reaction parameters using a 2³ factorial experimental design

    Directory of Open Access Journals (Sweden)

    Fernanda Oliveira Vieira da Cunha

    2004-12-01

    Full Text Available In this work was employed a 2³ factorial experiment design to evaluate the castor oil polyurethane-poly(methyl methacrylate semi-IPN synthesis. The reaction parameters used as independent variables were NCO/OH molar ratio, polyurethane polymerization time and methyl methacrylate (MMA content. The semi-IPNs were cured over 28 h using two thermal treatments. The polymers were characterized by infrared and Raman spectroscopy, thermal analysis and swelling profiles in n-hexane. The glass transition temperature (Tg and the swelling were more affect by the NCO/OH molar ratio variation. The semi-IPNs showed Tg from - 27 to - 6 °C and the swelling range was from 3 to 22%, according to the crosslink density. The IPN mechanical properties were dependent on the cure temperature and MMA content in it. Lower elastic modulus values were observed in IPNs cured at room temperature.

  3. Thermal stability and fracture toughness of epoxy resins modified with epoxidized castor oil and Al{sub 2}O{sub 3} nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Lin; Jin, Fanlong [Jilin Institute of Chemical Technology, Jilin (China); Park, Soojin [Inha Univ., Incheon (Korea, Republic of)

    2012-04-15

    This study examined the effects of the epoxidized castor oil (ECO) and Al{sub 2}O{sub 3} content on the thermal stability and fracture toughness of the diglycidylether of bisphenol-A (DGEBA)/ECO/Al{sub 2}O{sub 3} ternary composites using a range of techniques. The thermal stability of the composites was decreased by the addition of ECO and Al{sub 2}O{sub 3} nanoparticles. The fracture toughness of the composites was improved significantly by the addition of ECO and Al{sub 2}O{sub 3} nanoparticles. The composite containing 3 wt % Al{sub 2}O{sub 3} nanoparticles showed the maximum flexural strength. Scanning electron microscopy (SEM) revealed tortuous cracks in the DGEBA/ECO/Al{sub 2}O{sub 3} composites, which prevented deformation and crack propagation.

  4. Evaluation of Castor Oil Cake Starch and Recovered Glycerol and Development of “Green” Composites Based on Those with Plant Fibers

    Directory of Open Access Journals (Sweden)

    José Luis Guimarães

    2016-01-01

    Full Text Available Continuous efforts are being made in some countries for the recovery of crude glycerin (RG/CG and castor oil cake (COC, the two byproducts of biodiesel production. These are expected to help, not only in addressing environmental safety, but also in adding value to those byproducts, which otherwise may go to waste. Finding ways to utilize those byproducts underlines the main objective of this study. This paper presents the evaluation of (i COC, glycerin and banana and sugarcane fibers for moisture content; (ii COC for structural and thermal properties; and (iii CG for its chemical characteristics. The possibility of using COC and CG with the selected fibers as reinforcement in the development of bio-composites is attempted through thermo-molding. Results revealed enhanced mechanical properties for these composites. The obtained results are discussed in terms of the observed morphology.

  5. Synthesis and Properties of Cationic Waterborne Polyurethane Dispersions Modified by Castor Oil%蓖麻油改性阳离子型水性聚氨酯的合成及性能

    Institute of Scientific and Technical Information of China (English)

    饶舟; 张威; 王焕; 许戈文; 黄毅萍

    2012-01-01

    采用蓖麻油、异佛尔酮二异氰酸酯、聚己二酸乙二醇酯、聚丙二醇、一缩二乙二醇、N-甲基二乙醇胺、三羟甲基丙烷,合成了一系列蓖麻油改性阳离子型水性聚氨酯分散液.用红外光谱分析、粒径测试、智能电子拉力试验、摆杆硬度测试、热分析等对所合成的聚氨酯的结构、乳液的粒径和膜性能进行测试.结果表明:随着蓖麻油用量的增加,阳离子型水性聚氨酯乳液的粒径逐渐增加,膜的摆杆硬度及耐水性能逐渐增强:蓖麻油在树脂中质量分数达8.4%时,膜的摆杆硬度达到0.86;而蓖麻油在树脂中质量分数达6.4%时,阳离子型水性聚氨酯胶膜浸泡24 h的吸水率几近为零;且蓖麻油的引入,使胶膜的耐热性也有所提高.%Castor oil modified cationic waterborne polyurethane ( WPU) dispersions are prepared from castor oil,isophorone diisocyanate ( IPDI) ,polyethyleneglycol adipate ( PEGA ) ,polypropylene glycol (PPG),diethylene glycol (DEG) ,N - methyldiethanolamine ( MDEA) and trimethylolpropane(TMP) . The structure,emulsion particle distribution and film properties of the resulted WPU are characterized by Fourier transform infrared( FT - IR) ,particle size analyzer,intelligent tensile machine,pendulum tester and thermal gravimetric analysis ( TGA ) . The result indicates that the increase of castor oil leads to increase of emulsion particle size,and improvement of pendulum hardness and water resistance of the cured film. Specifically when the content of castor oil is 8. 4% ,the pendulum hardness of film is 0. 86. And when the content of castor oil is wt. 6. 4% ,the film shows its water absorption nearly zero after immersed for 24 hrs. Additionally ,the incorporation of castor oil causes improvement of heat resistance.

  6. Sintesis de poliuretanos a partir de polioles obtenidos a partir del aceite de higuerilla modificado por transesterificación con pentaeritritol Polyurethanes sintetized of polyols obtained from castor oil modified by transesterification with pentaerythritol

    Directory of Open Access Journals (Sweden)

    Manuel F. Valero

    2008-01-01

    Full Text Available Castor oil was reacted by transesterification with various percentages in mass of pentaerythritol to obtain different esters of pentaerythritol. Alternatively, glycerol was also used instead of pentaerythritol for the same reaction in order to establish comparative reference products. The products of the reactions were characterized by matrix-assisted laser desorption/ionization time-of-flight mass spectroscopy in order to detect and quantify (in terms of the molecular mass and structural information the components of the products obtained. Analysis for hydroxyl value, acid value, viscosity and specific gravity were used to complete the characterization of the polyols obtained and also of the original castor oil. The polymer characterization was accomplished by tensile stress-strain tests, Shore A hardness, thermogravimetric analysis and chemical resistance to solvents.

  7. Clinical analysis of castor oiled egg combined with diazepam in hastening parturition and inducing labor in 400 cases%蓖麻油联合地西泮用于催引产400例临床分析

    Institute of Scientific and Technical Information of China (English)

    贺同强; 米阳; 赵三纯

    2012-01-01

    Objective To investigate the effect and security of applying castor oiled egg and diazepam in hastening parturition and inducing labor for late pregnancy. Methods The clinical data of 400 cases of applying castor oiled egg and diazepam to hasten parturition and induce labor and taking vaginal delivery and that of 200 cases of natural childbirth without human intervention at the same period was retrospectively analyzed. Results The success rate of hastening with castor oiled egg and diazepam to hasten parturition for late pregnancy was 96. 5% , and that of inducing labor was 86.0% (X2 = 13. 81 ,P <0.01 ). Gestational weeks, indications of pregnancy termination and cervical maturity were related with the success rate. Conclusion The success rate is high and it is safe and convenient by applying castor oiled egg and diazepam to hasten parturition and induce labor.%目的 探讨蓖麻油蛋餐联合地西泮用于晚期妊娠催引产的效果及安全性.方法 对400例应用蓖麻油蛋餐联合地西泮催引产并经阴道分娩者与200例同期自然分娩无人为干预者的临床资料进行回顾性分析.结果 蓖麻油蛋餐联合地西泮用于晚期妊娠催产成功率为96.5%,引产成功率为86.0%,χ2=13.81,P<0.01.孕周、终止妊娠指征及宫颈成熟度与催引产成功率有关.结论 蓖麻油蛋餐联合地西泮催引产成功率高,用药安全方便.

  8. Development of Castor oil Modified Epoxy Polyurethane Anti-corrosion Coatings%蓖麻油改性环氧聚氨酯防腐蚀涂料的研制

    Institute of Scientific and Technical Information of China (English)

    李阳

    2012-01-01

    A kind of castor oil-modified epoxy polyurethane anti-corrosion coating was introduced. Castor oil modified isocyanate prepolymer and epoxy resin were used as basic materials,cheap talc, titanium dioxide, precipitated barium sulfate were used as pigment and filler , a kind of low cost and excellent performance anti-corrosion coating was developed. The performance of the coating developed under optimized conditions was detected. Castor oil modified epoxy polyurethane anti-corrosion coating and epoxy polyurethane anti-corrosion coating were compared. The results show that castor oil modified epoxy polyurethane anti-corrosion coating is better than epoxy polyurethane anti-corrosion coating in the aspects of acid - resistant, alkali - resistant and seawater - resistant.%介绍了一种蓖麻油改性的环氧聚氨酯防腐蚀涂料、以蓖麻油改性异氰酸酯预聚物和环氧树脂为基料,以价格较为低廉的滑石粉、钛白粉、沉淀硫酸钡为颜填料制备了成本较低,件能较为优异的防腐蚀涂料.检测了优化条件下制备的涂料的性能.以蓖麻油改性环氧聚氨酯防腐蚀涂料和未经蓖麻油改件的环氧聚氨酯防腐蚀涂料进行防腐蚀性能对比,蓖麻油改性环氧聚氨酯防腐蚀涂料的耐酸、碱、盐水等防腐蚀性能更好.

  9. Synthesis and Antitumor Activity of Novel Castor Oil-based Quaternary Ammonium%新型蓖麻油基季铵盐的合成及其抑菌性能

    Institute of Scientific and Technical Information of China (English)

    谢友利; 张猛; 周永红; 杨晓慧

    2012-01-01

    Two kinds of novel castor oil-based quaternary ammonium were synthesized from the starting material of methyl ricinoleate by amidation reaction and quaternization reaction. Their structures were characterized by means of FTIR,1HNMR, 13CNMR and ESI( MS). The bactericidal activity of the novel castor oil-based quaternary ammonium salts was evaluated by inhibitory zone diameters against E. coli and S. aureus. It is found that they have antibacterial activity. The antibacterial activity of N, N-dimethyl-N-ethyl-castor oil acid amide propyl bromide is stronger than that of N-benzyl-N,N-dimethyl-castor oil acid amide propyl bromide.%以蓖麻油酸甲酯为起始原料,与N,N-二甲基-1,3-丙二胺和溴化苄、溴乙烷通过酰胺化反应和季铵化反应生成了新型蓖麻油基季铵盐,其结构经FTIR、1HNMR、13CNMR及ESI-MS进行了确证.采用抑菌圈直径法对目标产物的抑菌性能进行了测试,结果表明,两种季铵盐均有一定的抑菌活性,N,N-二甲基-N-乙基-蓖麻油酸酰胺丙基溴化铵的抑菌活性略强于N,N-二甲基-N-苄基-蓖麻油酸酰胺丙基溴化铵.

  10. Characterization of adhesive of polyurethane from castor oil by FTIR, TGA and XRD;Caracterizacao de adesivo de poliuretano derivado do oleo de mamona por FTIR, TGA e XRD

    Energy Technology Data Exchange (ETDEWEB)

    Azevedo, Elaine C.; Santana, Simone S. de M.; Nascimento, Eduardo M. do, E-mail: elainazeve@utfpr.edu.b [Universidade Tecnologia Federal do Parana (UTFPR), Curitiba, PR (Brazil); Claro Neto, Salvador [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil); Lepienski, Carlos M. [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil)

    2009-07-01

    Castor oil polyurethanes are an alternative to adhesives that emanate volatile compounds. This adhesive come from a renewable source and has very low toxicity. In this work the microstructural and thermal characterization is presented. This material is partially crystalline. The mass loss start at 240 deg C and the glass transition temperature is 60 deg C. Then the adhesive is adequate to be employed at temperatures lower than 60 deg C. (author)

  11. Effect of cutting speed and feed in turning hardened stainless steel using coated carbide cutting tool under minimum quantity lubrication using castor oil

    Directory of Open Access Journals (Sweden)

    Mohamed Handawi Saad Elmunafi

    2015-08-01

    Full Text Available Minimum quantity lubrication is a technique to have the advantages that cutting fluids bring yet keeping their use at minimum. For the cutting fluids, inedible vegetable oils are potential for minimum quantity lubrication machining. Castor oil was selected in this study as the cutting fluid for turning of hardened stainless steel (hardness of 47–48 HRC. The hard turning was with minimum quantity lubrication (50 mL/h flow rate and 5 bar air pressure at various cutting speeds (100, 135, and 170 m/min and feeds (0.16, 0.20, and 0.24 mm/rev. The machining responses were tool life, surface roughness, and cutting forces. Design of experiments was applied to quantify the effects of cutting parameters to the machining responses. Empirical models for tool life, surface roughness, and cutting forces were developed within the range of cutting parameters selected. All machining responses are significantly influenced by the cutting speed and feed. Tool life is inversely proportional to cutting speed and feed. Surface roughness is inversely proportional to cutting speed yet is proportional to feed. Cutting forces are more influenced by feed than by cutting speed. A combination of low cutting speed and feed was the optimum cutting parameters to achieve long tool life, low surface roughness, and low cutting forces.

  12. 固体酸催化蓖麻油制备生物柴油%Preparation of biodiesel from castor seed oil using solid acid as a catalyst

    Institute of Scientific and Technical Information of China (English)

    靳福全; 牛宇岚; 李晓红

    2011-01-01

    以一水硫酸氢钠固体酸为催化剂,对蓖麻油酯交换制备生物柴油进行了研究.在反应温度为75℃条件下,考察了醇油摩尔比、催化剂用量(占油质量)及反应时间对酯交换反应的影响.在反应温度为75℃、醇油摩尔比为9:1、催化剂用量为4%、反应时间为8 h的优化工艺条件下,平均甘油收率达93%,产物中甲酯总含量为95.20%.甲酯和甘油静置分层快,后处理简单,对环境无污染.%The transesterification of castor seed oil to produce biodiesel catalyzed by solid acid sodium bisulfate monohydrate was studied. At the temperature of 75 ℃, effects of molar ratio of methanol to oil, catalyst dosage ( mass ratio of catalyst to oil) and reaction time on the transesterification were investigated. Under the optimal conditions of reaction temperature 75 ℃, molar ratio of methanol to oil 9: 1, catalyst dosage 4% and reaction time 8 h, the average yield of glycerine arrived 93% . The products were analyzed by GC - MS and the mass fraction of methyl ester was 95.20%. The methyl ester and the glycerine were easily separated, and the method had no pollution to the environment.

  13. Synthesis Process of Epoxidized Dehydrated Castor Oil%环氧脱水蓖麻油的制备工艺研究

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    Dehydrated castor oil( DCO) was firstly prepared by using castor oil( CTO) as raw material via dehydration reaction, and epoxidized dehydrated castor oil( EDCO) was synthesized using phosphoric acid as catalyst and acetic acid peroxide as the oxidant by epoxidation reaction afterwards. The influences of different parameters on the epoxy value of EDCO were investigated through single factor and orthogonal experiments. The results indicated that the optimal preparation conditions of EDCO were 3. 5 h reaction time, 30℃ reaction temperature, 5. 5∶1 molar ratio of peracetic acid to DCO and 0. 5% phosphoric acid dosage. The epoxy value of EDCO could be up to 4. 82% under these conditions. In addition, the chemical structures of CTO, DCO, and EDCO were characterized by FT-IR and 1H NMR . It was confirmed that the C—C double bonds in EDCO almost disappeared and the epoxy bonds were formed during the epoxidation. The properties of the products were also studied by viscosity measurement and thermogravimetric analysis( TG) . Viscosity measurement showed that the viscosities of CTO, DCO, and EDCO were 1 100. 0, 299. 5 and 1 896. 0 mPa·s, respectively. TG analysis demonstrated that the descending order of thermal stability of the products was EDCO>DCO>CTO.%以蓖麻油( CTO)为原料,先制备脱水蓖麻油( DCO),再以磷酸为催化剂,过氧乙酸为氧化剂,进行环氧化反应制备环氧脱水蓖麻油( EDCO),通过单因素和正交试验优化不同条件对产品环氧值的影响。结果表明,制备EDCO较佳工艺条件为反应温度30℃、反应时间3.5 h、DCO与过氧乙酸物质的量之比5.5∶1、磷酸用量0.5%,此条件下所得EDCO的环氧值达到4.82%。采用FT-IR和1H NMR表征了蓖麻油、脱水蓖麻油以及环氧脱水蓖麻油的化学结构,结果证实EDCO中C—C被环氧化后基本消失,生成了环氧键。通过黏度测定、热重分析(TG)等方法对产品的性能进行了分析,得到CTO黏度为1100.0 m

  14. Ectopic overexpression of castor bean LEAFY COTYLEDON2 (LEC2) in Arabidopsis triggers the expression of genes that encode regulators of seed maturation and oil body proteins in vegetative tissues.

    Science.gov (United States)

    Kim, Hyun Uk; Jung, Su-Jin; Lee, Kyeong-Ryeol; Kim, Eun Ha; Lee, Sang-Min; Roh, Kyung Hee; Kim, Jong-Bum

    2013-01-01

    The LEAFY COTYLEDON2 (LEC2) gene plays critically important regulatory roles during both early and late embryonic development. Here, we report the identification of the LEC2 gene from the castor bean plant (Ricinus communis), and characterize the effects of its overexpression on gene regulation and lipid metabolism in transgenic Arabidopsis plants. LEC2 exists as a single-copy gene in castor bean, is expressed predominantly in embryos, and encodes a protein with a conserved B3 domain, but different N- and C-terminal domains to those found in LEC2 from Arabidopsis. Ectopic overexpression of LEC2 from castor bean under the control of the cauliflower mosaic virus (CaMV) 35S promoter in Arabidopsis plants induces the accumulation of transcripts that encodes five major transcription factors (the LEAFY COTYLEDON1 (LEC1), LEAFY COTYLEDON1-LIKE (L1L), FUSCA3 (FUS3), and ABSCISIC ACID INSENSITIVE 3 (ABI3) transcripts for seed maturation, and WRINKELED1 (WRI1) transcripts for fatty acid biosynthesis), as well as OLEOSIN transcripts for the formation of oil bodies in vegetative tissues. Transgenic Arabidopsis plants that express the LEC2 gene from castor bean show a range of dose-dependent morphological phenotypes and effects on the expression of LEC2-regulated genes during seedling establishment and vegetative growth. Expression of castor bean LEC2 in Arabidopsis increased the expression of fatty acid elongase 1 (FAE1) and induced the accumulation of triacylglycerols, especially those containing the seed-specific fatty acid, eicosenoic acid (20:1(Δ11)), in vegetative tissues.

  15. 离子液体[Emim]Br中蓖麻油裂解制备仲辛醇的工艺%Preparation of 2-octanol through Castor Oil Pyrolysis in Ionic Liquid [Emim]Br

    Institute of Scientific and Technical Information of China (English)

    张东明; 张月娥; 黄凤岐

    2014-01-01

    通过单因素实验和正交实验研究溴化3-甲基-1-乙基咪唑([Emim]Br)离子液体中蓖麻油裂解制备仲辛醇的工艺条件,分别考察蓖麻油酸与离子液体的质量比、裂解反应时间、裂解温度以及蓖麻油酸与 NaOH 溶液质量比对仲辛醇产率的影响,得出优化工艺条件:裂解温度300,℃、裂解时间90,min、蓖麻油酸和离子液体的质量比1∶1、蓖麻油酸与NaOH溶液(6,mol/L)的质量比1∶1.5,最优条件下仲辛醇的产率为28.2%.此方法用离子液体[Emim]Br替代传统有机溶剂甲酚,减少了污染,属清洁生产,而且离子液体可以回收再利用.%The technological conditions for producing 2-octanol from castor oil in ionic liquid,[Emim]Br,was studied through single factor experiments and orthogonal experiments. The mass ratio of castor oil acid to ionic liquid,pyrolysis reaction time,temperature,and the ratio of castor oil acid to NaOH were investigated in detail. The optimal technological conditions obtained are as follows:the temperature was 300,℃,pyrolysis time was 90,min,the mass ratio of castor oil to ionic liquid was 1∶1,and the ratio of castor oil to alkali(6,mol/L)was 1∶1.5. The yield of 2-octanol was about 28.2%under the optimal technological conditions. In addition,the traditional solvent cresol was replaced by ionic liquid [Emim]Br,and pollution was reduced with this clean production method. The ionic liquid can be recycled and used again.

  16. Research on a clean preparation process of sebacic acid by catalytic cracking of castor oil%蓖麻油催化裂解制备癸二酸的清洁工艺研究

    Institute of Scientific and Technical Information of China (English)

    王彦雄; 张小里; 李红亚; 豆坤坤; 张甜甜; 姚娜

    2012-01-01

    The traditional preparation process of sebacic acid by cracking castor oil could cause serious environment pollution because of using o-cresol as the diluent and lead oxide as the catalyst. Using liquid paraffin as the diluent, an environmental friendly catalyst for preparation of sebacic acid was screened and the clean preparation process of sebacic acid was investigated. The results showed that iron oxide as the catalyst exhibited good cracking effect;sebacic acid yield of 67.2% and the purity of 99.0% after separation were attained under the optimum condition as follows:catalyst dosage 1.00% of castor oil mass, V( diluent) : V( castor oil) =4-1, V( sodium hydroxide): V( castor oil) =1:1,reaction temperature 280?, and reaction time 4 h. Using iron oxide as the catalyst and liquid paraffin as the diluent,a clean preparation process of sebacic acid by cracking castor oil will be expected to be developed.%传统的蓖麻油裂解制备癸二酸工艺因使用稀释剂邻甲酚和催化剂铅氧化物而导致严重的环境污染.以对环境温和的液体石蜡作稀释剂,筛选环境友好型催化剂制备癸二酸,开发清洁生产工艺,研究发现,采用氧化铁作催化剂可取得良好的裂解反应效果.最佳工艺条件为:催化剂用量为蓖麻油质量的1.00%,V(稀释剂)∶V(蓖麻油)=4∶1,V(碱液)∶V(蓖麻油)=1∶1,反应温度280℃,反应时间4h.在此条件下,癸二酸收率达67.2%,分离后纯度达到99.0%.表明氧化铁作为催化剂配合液体石蜡作稀释剂可望开发一条蓖麻油裂解制备癸二酸的清洁生产工艺.

  17. Synthesis and characterization of gold nanotube/nanowire–polyurethane composite based on castor oil and polyethylene glycol

    Energy Technology Data Exchange (ETDEWEB)

    Ganji, Yasaman, E-mail: y.ganji@aut.ac.ir [Faculty of Biomedical Engineering, Amirkabir University of Technology, 424 Hafez Ave., Tehran (Iran, Islamic Republic of); Kasra, Mehran, E-mail: mkasra@aut.ac.ir [Faculty of Biomedical Engineering, Amirkabir University of Technology, 424 Hafez Ave., Tehran (Iran, Islamic Republic of); Salahshour Kordestani, Soheila, E-mail: s.kordestani@aut.ac.ir [Faculty of Biomedical Engineering, Amirkabir University of Technology, 424 Hafez Ave., Tehran (Iran, Islamic Republic of); Bagheri Hariri, Mohiedin, E-mail: mohibagheri@gmail.com [Materials Science and Engineering Department, Sharif University of Technology, Azadi Ave., Tehran (Iran, Islamic Republic of)

    2014-09-01

    Gold nanotubes/nanowires (GNT/NW) were synthesized by using the template-assisted electrodeposition technique and mixed with castor oil–polyethylene glycol based polyurethane (PU) to fabricate porous composite scaffolds for biomedical application. 100 and 50 ppm of GNT/NW were used to synthesize composites. The composite scaffolds were characterized by Fourier transform infrared spectroscopy, dynamic mechanical thermal analysis, differential scanning calorimetry, and scanning electron microscopy. Cell attachment on polyurethane–GNT/NW composites was investigated using fat-derived mesenchymal stem cells. Addition of 50 or 100 ppm GNT/NW had significant effects on thermal, mechanical, and cell attachment of polyurethane. Higher crosslink density and better cell attachment and proliferation were observed in polyurethane containing 50 ppm GNT/NW. The results revealed that GNT/NW formed hydrogen bonding with the polyurethane matrix and improved the thermomechanical properties of nanocomposites. Compared with pure PU, better cellular attachment on polyurethane–GNT/NW composites was observed resulting from the improved surface properties of composites. - Highlights: • Polyurethane–gold nanotubes/nanowires (GNT/NWs) composites were synthesized. • Tan δ, E′ and E″ were increased upon addition of 50 ppm of GNT/NW. • Better cell attachment was observed in composites containing 50 ppm of GNT/NW. • GNT/NWs can make a bridge between the pores of the porous polymeric scaffolds. • GNT/NWs increased the crosslink density of the polymeric matrix.

  18. Biochar prepared from castor oil cake at different temperatures: A voltammetric study applied for Pb(2+), Cd(2+) and Cu(2+) ions preconcentration.

    Science.gov (United States)

    Kalinke, Cristiane; Mangrich, Antonio Sálvio; Marcolino-Junior, Luiz H; Bergamini, Márcio F

    2016-11-15

    Biochar is a carbonaceous material similar produced by pyrolysis of biomass under oxygen-limited conditions. Pyrolysis temperature is an important parameter that can alters biochar characteristics (e.g. surface area, pore size distribution and surface functional groups) and affects it efficacy for adsorption of several probes. In this work, biochar samples have been prepared from castor oil cake using different temperatures of pyrolysis (200-600°C). For the first time, a voltammetric procedure based on carbon paste modified electrode (CPME) was used to investigate the effect of temperature of pyrolysis on the adsorptive characteristics of biochar for Pb(II), Cd(II) and Cu(II) ions. Besides the electrochemical techniques, several characterizations have been performed to evaluate the physicochemical properties of biochar in function of the increase of the pyrolysis temperature. Results suggest that biochar pyrolized at 400°C (BC400) showed a better potential for ions adsorption. The CPME modified with BC400 showed better relative current signal with adsorption affinity: Pb(II)>Cd(II)>Cu(II). Kinetic studies revealed that the pseudo-second order model describes more accurately the adsorption process suggesting that the surface reactions control the adsorption rate. Values found for amount adsorbed were 15.94±0.09; 4.29±0.13 and 2.38±0.39μgg(-1) for Pb(II), Cd(II) and Cu(II) ions, respectively.

  19. Effect of ricinoleic acid esters from castor oil (Ricinus communis) on the oocyte yolk components of the tick Rhipicephalus sanguineus (Latreille, 1806) (Acari: Ixodidae).

    Science.gov (United States)

    Sampieri, Bruno Rodrigues; Arnosti, André; Furquim, Karim Christina Scopinho; Chierice, Gilberto Orivaldo; Bechara, Gervásio Henrique; de Carvalho, Pedro Luiz Pucci Figueiredo; Nunes, Pablo Henrique; Camargo-Mathias, Maria Izabel

    2013-01-31

    Rhipicephalus sanguineus are bloodsucking ectoparasites, whose main host is the domestic dog, thus being present in urban areas and closely located to people. Eventually, this tick species parasitize humans and can become a potential vector of infectious diseases. Methods to control this type of pest have been the focus of many research groups worldwide. The use of natural products is increasingly considered nowadays, due to the low toxicity levels to the host and low waste generation to the environment. This study tested the effect of ricinoleic acid esters from castor oil (as an potential acaricide) on the reproductive system of R. sanguineus females, more specifically on the vitellogenesis process. For this, two groups were established: the control group (CG) and the treatment group (TG) with five rabbits in each (New Zealand White), used as hosts. NaCl and ester were added to rabbits' food and offered to the hosts. After full engorgement, the females were collected and had their ovaries extracted. The ticks ovaries were submitted to histochemical techniques so the effects of esters could be observed over polysaccharides, proteins and lipids yolk. Changes in the deposition of yolk components were observed. This caused modifications on elements of polysaccharide origin and on glycoprotein compounds, interfering in the final yolk synthesis and compromising the development of the future embryo.

  20. Electroactive polyurethane/siloxane derived from castor oil as a versatile cardiac patch, part I: Synthesis, characterization, and myoblast proliferation and differentiation.

    Science.gov (United States)

    Baheiraei, Nafiseh; Gharibi, Reza; Yeganeh, Hamid; Miragoli, Michele; Salvarani, Nicolò; Di Pasquale, Elisa; Condorelli, Gianluigi

    2015-11-05

    Tissue-engineered cardiac patch aims at regenerating an infarcted heart by improving cardiac function and providing mechanical support to the diseased myocardium. In order to take advantages of electroactivity, a new synthetic method was developed for the introduction of an electroactive oligoaniline into the backbone of prepared patches. For this purpose, a series of electroactive polyurethane/siloxane films containing aniline tetramer (AT) was prepared through sol-gel reaction of trimethoxysilane functional intermediate polyurethane prepolymers made from castor oil and poly(ethylene glycol). Physicochemical, mechanical, and electrical conductivity of samples were evaluated and the recorded results were correlated to their structural characteristics. The optimized films were proved to be biodegradable and have tensile properties suitable for cardiac patch application. The embedded AT moieties in the backbone of the prepared samples preserved their electroactivity with the electrical conductivity in the range of 10(-4) S/cm. The prepared films were compatible with proliferation of C2C12 and had potential for enhancing myotube formation even without external electrical stimulation. © 2015 Wiley Periodicals, Inc. J Biomed Mater Res Part A, 2015.

  1. Study on Pyrolyzing Castor Oil Catalytically in Preparing Undecenoic Acid%蓖麻油催化裂解-制十一烯酸研究

    Institute of Scientific and Technical Information of China (English)

    靳福泉

    2001-01-01

    采用减压催化的方式,对蓖麻油直接裂解制备十一烯酸的方法进行了研究。结果表明:使用N型催化剂,在温度400℃,压力23.3 kPa,物料流量700g/h的条件下,十一烯酸收率达24.6%,庚醛18.3%。该法降低了解裂温度,简化了工艺,节省了原料,且催化剂可反复再生使用。%Castor oil was catalytically pyrolyzed for preparing undecenoic acid under reduced pressure. Results showed that the yield of undecenoic acid was up to 24. 6% and that of heptaldehyde to 18.3% in pres ence of N catalyst and at 400℃ and 23.3 kPa pressure, 700 g/h flow rate. In the process, pyrolytic temperature was reduced, the process simplified and the material economized. Moreover, the catalyst can be regenerated.

  2. Effect of emulsion method and co- emulsifier on performance of castor oil emulsion%乳化方式及助乳化剂对蓖麻油乳化液性能的影响

    Institute of Scientific and Technical Information of China (English)

    鲍艳; 吴成兰; 马建中

    2012-01-01

    A blended emulsifier consisting of nonionic surfactant sorbitan mono - fatty acid ester ( Span) and polyoxyethylene sorbitan mono -fatty acid ester (Tween) was applied to emulsify castor oil by three different emulsion methods,constant speed mixing,high shearing and ultrasonic,respectively. The influences of different co - emulsifiers with different chain length such as octanol, ethyl hexanol and dodecanol on stability of the caster oil emulsion were investigated. Results indicated that the stability of castor oil emulsion is improved with the increase of carbon number of the fatty alcohol. The castor oil emulsion prepared via ultrasonic method,both the original emulsion and diluted emulsion, shows good stability.%分别采用恒速搅拌乳化、高剪切乳化及超声波乳化3种方式,以非离子型表面活性剂失水山梨醇单脂肪酸酯(Span)与聚氧乙烯失水山梨醇单脂肪酸酯(Tween)为复合乳化剂对蓖麻油进行乳化,考察了助乳化剂正辛醇、异辛醇、十二醇对乳化体系稳定性的影响.结果表明,随助乳化剂脂肪醇碳链长度的增加,蓖麻油的乳化稳定性提高;采用超声波乳化方式可制得稳定的蓖麻油乳化液,且稀释稳定性良好.

  3. Catalytic Conversion of Castor Oil to Biodiesel Using Ionic Liquid as Catalyst%碱性离子液体在制备生物柴油中的应用

    Institute of Scientific and Technical Information of China (English)

    马洁; 顾俊; 夏晓莉; 倪邦庆; 王海军

    2012-01-01

    Efficient catalytic conversion of castor oil to biodiesel,is achieved using 1-buthyl-3-methylimidazolium hydroxide(OH) as the catalyst.The influence factors,such as alcohol-oil ratio,catalyst dosage,reaction temperature,reaction time are investigated in detail.The results showed that OH was an efficient catalyst for catalytic conversion of castor oil to biodiesel,and 82.3 % yield of HMF was obtained for 90 min at 50 ℃ in the presence of the load of catalyst was 8 % and the CH3OH: oil ratio was 9∶1.%文章研究了碱性离子液体1-丁基-3-甲基咪唑氢氧盐([Bmim]OH)催化蓖麻油酯交换制备生物柴油的工艺。考察了醇油比、催化剂用量、反应温度、反应时间等因素对脂肪酸甲酯的得率的影响。研究表明以[Bmim]OH为催化剂,脂肪酸甲酯得率达到82.3%。最佳反应条件为:醇油摩尔比9∶1,催化剂用量8%,反应温度50℃,反应时间90 min。

  4. Isolation and Identification of Waste Castor-based Oil-highly Efficient Degrading Strains%废弃蓖麻基润滑油高效降解菌的分离与鉴定

    Institute of Scientific and Technical Information of China (English)

    刘亚琼; 王昌禄; 李风娟; 叶峰

    2012-01-01

    M-4 strain which was screened out of the sewage and sludge in a castor oil refinery (Inner Mongolia, China) belongs to Alternaria altemata sp., and was identified by 18S rDNA gene sequence analysis. Degradation test of castor based lubricant base oil showed that after 7 days' work, the degradation rate of M-4 strain analysed with GC was 71.3%. Studies of the growth characteristics of M-4 have shown that, in the case of the same inoculum, M-4 strains grew well in the concentration of 120 g/L waste castor oil-based mineral medium and the caster oil was degraded into the form of sludge. The results showed that M-4 strain can grow well in high content of oil and has remarkable restoration effect on the environment polluted by the castor based lubricants, which indicaties that it will have good prospect in application.%从内蒙古某蓖麻榨油车间排污口取样,经分离,筛选出菌株M-4,通过对该菌株菌落形态及18S rDNA基因扩增序列分析,鉴定为链格孢属.菌株M-4降解废弃蓖麻基润滑油基础油结果表明,降解7d后,采用气相色谱法(GC)进行定量分析,降解率达71.3%.对菌株生长特性研究表明,在相同接种量下,菌株M-4在含废弃蓖麻基润滑油12%的培养基中仍能较好地生长,并将其降解成污泥状,表明菌株M-4能在含油量较高的环境中良好生长,具有研发应用前景.

  5. Optimization of transesterification reaction conditions for the production of biodiesel from oil blend of castor bean and soybean; Otimizacao das condicoes reacionais de transesterizacao para producao de biodiesel a partir de mistura de oleos de mamona e soja

    Energy Technology Data Exchange (ETDEWEB)

    Lobato, Ana Katerine de Carvalho Lima; Lima, Milena Gouveia Oliveira de; Pontes, Luiz Antonio M.; Teixeira, Leonardo S.G. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil); Almeida, Daniel Freire; Costa, Tales Santana Martins; Menezes; Mateus Della Cella; Santos, Iran Talis Viana; Almeida, Selmo Q. [Universidade Salvador (UNIFACS), BA (Brazil)

    2012-07-01

    Biodiesel is an alternative fuel to diesel oil, and industrially obtained by the transesterification of triglycerides of fatty acids from vegetable oils and/or animal fats. Currently, the main raw material used to produce biodiesel in Brazil is soybean oil. The inclusion of other raw materials from different cultures in this sector is important and aims to reduce dependence on a single oilseed, assign specific characteristics to the product and encourage the development of family farming. The use of blends of soybean oil and castor for biodiesel may prove an important strategy to minimize the negative effects and maximize the positives of each oilseed. In this work, we carried out an experimental study using full factorial design 2{sup 4}, to increase the conversion of esters, by conventional transesterification, using as feedstock a blend of oils containing 20% castor and 80% soybean. The aim of this study was to evaluate the influence of mixing ratio of oil: methanol, KOH concentration, temperature and reaction time in biodiesel production. It was found that the variation of these parameters affected the conversion of esters and quality of biodiesel produced. Conversions above 95% were obtained, and the best conversion was 99.05% at 25 deg C in a reaction time of 20 minutes using 2% KOH as a catalyst and a molar ratio methanol/oil 12:1. In order to reduce the costs of the process with respect to amount of methanol used without affecting the conversion of esters, we identified a second set of process conditions, which used the same conditions of temperature, reaction time and catalyst concentration and a different molar ratio methanol/oil (6:1) which gave a conversion of esters of 98.59%. (author)

  6. Draft genome sequence of the ricin-producing oilseed castor bean

    Science.gov (United States)

    Chan, Agnes P.; Crabtree, Jonathan; Zhao, Qi; Lorenzi, Hernan; Orvis, Joshua; Puiu, Daniela; Melake-Berhan, Admasu; Jones, Kristine M.; Redman, Julia; Chen, Grace; Cahoon, Edgar B.; Gedil, Melaku; Stanke, Mario; Haas, Brian J.; Wortman, Jennifer R.; Fraser-Liggett, Claire M.; Ravel, Jacques; Rabinowicz, Pablo D.

    2010-01-01

    Castor bean (Ricinus communis) is an oil crop that belongs to the spurge (Euphorbiaceae) family. Its seeds are the source of castor oil, used for the production of high-quality lubricants due to its high proportion of the unusual fatty acid ricinoleic acid. Castor bean seeds also produce ricin, a highly toxic ribosome inactivating protein, making castor bean relevant for biosafety. We report here the 4.6X draft genome sequence of castor bean, representing the first reported Euphorbiaceae genome sequence. Our analysis shows that most key castor oil metabolism genes are single-copy while the ricin gene family is larger than previously thought. Comparative genomics analysis suggests the presence of an ancient hexaploidization event that is conserved across the dicotyledonous lineage. PMID:20729833

  7. 蓖麻油硅氧烷双重交联改善水性聚氨酯的耐水性%Improving Water Resistance of Waterborne Polyurethane by Double Crosslinking Using Castor Oil and 3-Aminopropyltriethoxysilane as Crosslink Agents

    Institute of Scientific and Technical Information of China (English)

    吕建平; 李彬; 张磊; 梁亚平; 冯志媚

    2011-01-01

    Polyester waterborne polyurethane dispersion (WPU) was synthesized with benzoic acid anhydride polyester polyol, dimethylolpropionic acid (DMPA) and 2, 4-diisocyanatotoluene (TDI) as raw materials, respectively. Water resistance of WPU was improved evidently by double crosslink method, which using castor oil and 3-aminopropyltriethoxysilane (KH-550) as crosslink agents. The effects of the amount of castor oil and KH-550 on the properties of the emulsion and cast film were discussed. The results showed that in the process of synthesizing polyester WPU, the suitable amount of castor oil and KH-550 were 1O% and 1% , respectively. After double crosslinking modification, WPU film with good water resistance was obtained, and water absorption of cast film could be decreased from 34.3% to 5.7% . The WPU film could be used as paving materials in sport field.%以苯酐聚酯多元醇、二羟甲基丙酸和甲苯二异氰酸酯为主要原料,选用蓖麻油及3-氨基丙基三乙氧基硅烷(KH-550)为交联剂,通过预聚物的合成和水相扩链两步反应,制备了水性聚氨酯,研究了蓖麻油和KH-550用量对水性聚氨酯力学性能、附着力和吸水率等的影响.结果表明,当蓖麻油质量分数为10%、KH-550质量分数为1%,经过双重交联改性,水性聚氨酯成膜物具有较好耐水性,其吸水率从34.3%下降到5.7%,可以用于体育场地铺装材料.

  8. Síntesis y caracterización de espumas flexibles de poliuretano obtenidas a partir de aceite de castor maleinizado Flexible polyurethane foam synthesis and characterization obtained from maleinizated castor oil

    OpenAIRE

    Paula Mazo; Luis A. Rios; Diana Estenoz

    2009-01-01

    En este trabajo se realiza la síntesis de espumas flexibles de poliuretano empleando un diseño experimental Taguchi, utilizando aceite de castor con y sin maleinización, se estudia la cinética de la reacción de esterificación del aceite por cuantificación de los grupos ácido (ASTM D4662 - 03) y se evalúan las propiedades mecánicas de las espumas (densidad, resistencia tensil, % elongación, resiliencia y dureza. Norma NTC 2019 Icontec) obtenidas en función de las variables de síntesis (cantida...

  9. Determinación de la densidad de entrecruzamiento de poliuretanos obtenidos a partir de aceite de ricino modificado por transesterificación Determination of crosslink density of polyurethanes obtained from castor oil modified by transesterification

    Directory of Open Access Journals (Sweden)

    Manuel F. Valero

    2009-01-01

    Full Text Available Se obtuvo una gama de polioles a partir del aceite de ricino modificado por transesterificación con pentaeritriol y glicerina. Los productos resultantes fueron caracterizados físico-químicamente. Se sintetizaron elastómeros de poliuretano a partir de los polioles derivados del aceite de ricino modificado. La densidad de entrecruzamiento se determinó por ensayos de hinchamiento a partir de la ecuación de Flory-Rehner apoyada en la espectroscopia MALDI TOF MS para determinar la estructura química de la unidad repetitiva promedio del poliuretano. Se estudió la variación de la densidad de entrecruzamiento de los poliuretanos con base en el índice de hidroxilo del poliol utilizado en la síntesis. Los resultados muestran que los PU obtenidos a través de la modificación del aceite con pentaeritriol tienen una mayor densidad de entrecruzamiento que los PU obtenidos a partir del aceite original y de los polioles derivados de la reacción de transesterificación del aceite con glicerina, debido a que estos polioles poseen una mayor funcionalidad hidroxílica.Two series of polyols were obtained from castor oil modified by transesterification with various amounts of pentaerythritol and glycerol. The resultant polyol properties were characterized as a function of the hydroxyl functionality. Polyurethane elastomers (PU were synthesized from the two series of polyols obtained. The crosslink density of those polyurethanes was determined by swelling tests data adjusted to the Flory-Rehner's equation and according to the elasticity theory. The variation of the crosslink density of polyurethanes was studied by following the hydroxyl value of the modified polyol utilized in the synthesis and based on the average structure of each polyurethane repeating unit, as determined by the method of matrix-assisted laser desorption/ionization time-of-flight mass spectroscopy (MALDI TOF MS. The results show that the PU obtained through castor oil modified with

  10. 磺化蓖麻油应用于无煮茧自动缫丝工艺的研究%Research on Application of Sulfonated Castor Oil in Non-cocoon Cooking Automatic Silk Reeling Technology

    Institute of Scientific and Technical Information of China (English)

    肖海波; 李军生; 阎柳娟; 黄国霞; 邓塔; 韦德科; 徐立勤

    2013-01-01

    This paper conducts a practical reeling test using raw materials with different cocoon qualities based on non-cocoon cooking automatic silk reeling technology and discusses the influence of sulfonated castor oil additive on the performance of silk reeling. The test result shows that sulfonated castor oil additive can improve the reelability percentage of non-cocoon cooking automatic silk reeling technology, reduce the frequency rushing upon cocoons per 10 km averages, decrease the maximum deviation and mean square deviation, improve machine-hour output and cleanness and neatness, thus increasing the overall grade of raw silk by 0. 64 A on average. Sulfonated castor oil non-cocoon cooking automatic silk reeling technology inherits all advantages of non-cocoon cooking automatic silk reeling technology and overcomes the deficiency that non-cocoon cooking technology is inappropriate for raw material cocoon with a poor reelability performance. It is highly feasible to use sulfonated castor oil additive to improve the silk reeling performance of non-cocoon cooking automatic silk reeling technology.%在无煮茧自动缫丝工艺的基础上,采用不同茧质的原料进行实缫试验,探讨了磺化蓖麻油助剂对缫丝成绩的影响.试验结果表明:磺化蓖麻油助剂可提高无煮茧自动缫丝工艺的解舒率,降低万米吊糙次数、减小最大偏差和均方差、增加台时产量、提高清洁和洁净,使生丝的综合等级平均提高了0.64 A.磺化蓖麻油无煮茧自动缫丝工艺继承了无煮茧自动缫丝工艺的全部优点,并克服了无煮茧工艺对解舒成绩较差的原料茧不宜使用的不足,利用磺化蓖麻油助剂来改善无煮茧自动缫丝工艺的缫丝性能具有很大的可行性.

  11. Producing Process of Sebaconitrile from Sebacic Acid in Castor Oil%蓖麻油制取工程之癸二酸制取癸二腈工艺设计研究

    Institute of Scientific and Technical Information of China (English)

    赵云发; 赵学敬; 苗泽凯

    2015-01-01

    本文针对蓖麻油制取工艺中癸二酸制取癸二腈的制取机理及工艺设计做了理论与实践的研究。通过实践优化了工艺操作的反应温度及相关的操作条件。%Preparation mechanism and technology of sebaconitrile from sebacic acid in castor oil were studied in theory and practice. Operating temperature and conditions were optimized through practice.

  12. Selective production of ricinoleic acid by hydrolysis of castor oil using lipase immobilized in N-polyisopropylacrylamide gel; Ripaze koteika N-poriisopuropiruakuriruamidogeru wo mochiita himashiyu no kasuibunaki ni yoru rishinorusan no sentakuteki seisei

    Energy Technology Data Exchange (ETDEWEB)

    Goto, M.; Hatanaka, C.; Haraguchi, T. [Kitakyushu National College of Technology, Fukuoka (Japan)

    2000-05-10

    Lipase from Candida cylindracea or Rhizopus was immobilized in gel beads prepared by copolymerization of N-isopropylacrylamide, N-N'-methylenebisacrylamide, and acrylamide. The hydrolysis reaction of castor oil was carried out at 37 degree C by using immobilized lipase or free lipase. The optimal condition of immobilization of lipase and the productivity of ricinoleic acid is investigated. It is found that thermal inactivation of enzyme was suppressed and the formation of by-products such as estolide decreases by immobilization into the gel compared with free lipase. (author)

  13. Evaluation gamma radiation in composite sisal fiber- polyurethane derived of castor oil by bending test; Avaliacao da influencia da radiacao gama em compositos de fibra de sisal - poliuretano derivado de oleo de mamona atraves de ensaios de flexao

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Felipe H. de; Geraldo, Ricardo R.; Vasco, Marina C.; Azevedo, Elaine, E-mail: helunica@yahoo.com.br [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil); Claro Neto, Salvador [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil). Instituto de Quimica

    2013-07-01

    Materials used for making furniture and accessories or positioning in X -ray examination rooms should not exhale volatile organic compounds and are resistant to ionizing radiation. One solution is the use of vegetable fiber and polyurethane composites of vegetable origin, since they are biodegradable, derived from renewable raw materials and have no volatile organic compounds. The main difficulty in developing this material is fiber adhesion with the polymer. The objective of this study is to evaluate the mechanical properties of composite sisal fiber composite, without further treatment, and polyurethane derived from castor oil, with a dose of 25 kGy gamma radiation, subjected to 3 points bending tests. (author)

  14. Biochemical and molecular characterization of RcSUS1, a cytosolic sucrose synthase phosphorylated in vivo at serine 11 in developing castor oil seeds.

    Science.gov (United States)

    Fedosejevs, Eric T; Ying, Sheng; Park, Joonho; Anderson, Erin M; Mullen, Robert T; She, Yi-Min; Plaxton, William C

    2014-11-28

    Sucrose synthase (SUS) catalyzes the UDP-dependent cleavage of sucrose into UDP-glucose and fructose and has become an important target for improving seed crops via metabolic engineering. A UDP-specific SUS homotetramer composed of 93-kDa subunits was purified to homogeneity from the triacylglyceride-rich endosperm of developing castor oil seeds (COS) and identified as RcSUS1 by mass spectrometry. RcSUS1 transcripts peaked during early development, whereas levels of SUS activity and immunoreactive 93-kDa SUS polypeptides maximized during mid-development, becoming undetectable in fully mature COS. The cytosolic location of the enzyme was established following transient expression of RcSUS1-enhanced YFP in tobacco suspension cells and fluorescence microscopy. Immunological studies using anti-phosphosite-specific antibodies revealed dynamic and high stoichiometric in vivo phosphorylation of RcSUS1 at its conserved Ser-11 residue during COS development. Incorporation of (32)P(i) from [γ-(32)P]ATP into a RcSUS1 peptide substrate, alongside a phosphosite-specific ELISA assay, established the presence of calcium-dependent RcSUS1 (Ser-11) kinase activity. Approximately 10% of RcSUS1 was associated with COS microsomal membranes and was hypophosphorylated relative to the remainder of RcSUS1 that partitioned into the soluble, cytosolic fraction. Elimination of sucrose supply caused by excision of intact pods of developing COS abolished RcSUS1 transcription while triggering the progressive dephosphorylation of RcSUS1 in planta. This did not influence the proportion of RcSUS1 associated with microsomal membranes but instead correlated with a subsequent marked decline in SUS activity and immunoreactive RcSUS1 polypeptides. Phosphorylation at Ser-11 appears to protect RcSUS1 from proteolysis, rather than influence its kinetic properties or partitioning between the soluble cytosol and microsomal membranes.

  15. Bacterial- and plant-type phosphoenolpyruvate carboxylase isozymes from developing castor oil seeds interact in vivo and associate with the surface of mitochondria.

    Science.gov (United States)

    Park, Joonho; Khuu, Nicholas; Howard, Alexander S M; Mullen, Robert T; Plaxton, William C

    2012-07-01

    Phosphoenolpyruvate carboxylase (PEPC) from developing castor oil seeds (COS) exists as two distinct oligomeric isoforms. The typical class-1 PEPC homotetramer consists of 107-kDa plant-type PEPC (PTPC) subunits, whereas the allosterically desensitized 910-kDa class-2 PEPC hetero-octamer arises from the association of class-1 PEPC with 118-kDa bacterial-type PEPC (BTPC) subunits. The in vivo interaction and subcellular location of COS BTPC and PTPC were assessed by imaging fluorescent protein (FP)-tagged PEPCs in tobacco suspension-cultured cells. The BTPC-FP mainly localized to cytoplasmic punctate/globular structures, identified as mitochondria by co-immunostaining of endogenous cytochrome oxidase. Inhibition of respiration with KCN resulted in proportional decreases and increases in mitochondrial versus cytosolic BTPC-FP, respectively. The FP-PTPC and NLS-FP-PTPC (containing an appended nuclear localization signal, NLS) localized to the cytosol and nucleus, respectively, but both co-localized with mitochondrial-associated BTPC when co-expressed with BTPC-FP. Transmission electron microscopy of immunogold-labeled developing COS revealed that BTPC and PTPC are localized at the mitochondrial (outer) envelope, as well as the cytosol. Moreover, thermolysin-sensitive BTPC and PTPC polypeptides were detected on immunoblots of purified COS mitochondria. Overall, our results demonstrate that: (i) COS BTPC and PTPC interact in vivo as a class-2 PEPC complex that associates with the surface of mitochondria, (ii) BTPC's unique and divergent intrinsically disordered region mediates its interaction with PTPC, whereas (iii) the PTPC-containing class-1 PEPC is entirely cytosolic. We hypothesize that mitochondrial-associated class-2 PEPC facilitates rapid refixation of respiratory CO(2) while sustaining a large anaplerotic flux to replenish tricarboxylic acid cycle C-skeletons withdrawn for biosynthesis.

  16. Corneal-protective effects of an artificial tear containing sodium hyaluronate and castor oil on a porcine short-term dry eye model.

    Science.gov (United States)

    Hasegawa, Takashi; Amako, Hideki; Yamamoto, Takeshi; Tazawa, Mariko; Sakamoto, Yuji

    2014-09-01

    The corneal-protective effects of an artificial tear containing sodium hyaluronate (SH) and castor oil (CO) were evaluated on a porcine short-term dry eye model. Fresh porcine eyes with an intact cornea were treated with an artificial tear of saline, SH solution (0.1%, 0.5% or 1%), CO solution (0.5%, 1% or 5%) or a mixture solution containing 0.5% SH and 1% CO and then desiccated for 60, 90 or 180 min. To assess corneal damage, the eyes were stained with methylene blue (MB) or lissamine green (LG). The staining score of MB, absorbance of MB extracted from the cornea and staining density of LG increased significantly with increasing desiccation time in untreated and all artificial tear-treated eyes, although there were no significant differences in staining scores and absorbance of MB between eyes treated continuously with saline and 1% SH-treated ones at 60 and 90 min of desiccation or the mixture-treated eyes at 60 min of desiccation. No significant differences in the staining density of LG were also found between continuous saline-treated eyes and ones desiccated for 60 min and treated with 1% SH and the mixture. Mild cytoplasmic vacuolations were histopathologically observed in the basal and wing cells in eyes desiccated for 60 min and treated with 1% SH and the mixture. The mixture solution containing 0.5% SH and 1% CO has protective effects against corneal desiccation similar to those of 1% SH and would be helpful as an artificial tear.

  17. Cytoxicity, dynamic and thermal properties of bio-based rosin-epoxy resin/ castor oil polyurethane/ carbon nanotubes bio-nanocomposites.

    Science.gov (United States)

    Huo, Li; Wang, Dan; Liu, Hongmei; Jia, Pan; Gao, Jungang

    2016-08-01

    In order to prepare bio-nanocomposites with no-cytotoxicity, the rosin-based epoxy resin (MPAER) and castor oil-based polyurethane (COPU) were synthesized and carbon nanotubes (CNTs) was used to enhance the properties of curing MPAER/COPU materials. The curing reaction, dynamic mechanical and thermal properties of this system were characterized by FTIR, NMR, DMA, TG et al. The cytotoxicity of materials is evaluated for HeLa cells using a MTT cell-viability assay. The results showed that COPU can cure MPAER and CNTs can increase effectively the properties of MPAER/COPU nanocomposites. The Tg of MPAER/COPU/CNTs has the highest value when CNTs content is 0.4 wt%, which is 52.4 °C higher than the pure MPAER/COPU. Thermal stability of the nanocomposites is enhanced by the addition of CNTs, the initial decomposition temperature Td5 of the sample No. 0.4 has increased from 284.5 to 305.2 °C, which is 20.7 °C higher than No. 0. The impact strength of the No. 0.4 film is 15 kg cm higher than the pure resin system. The survival rate of HeLa cells to the products is greater than 90% within 48 and 72 h, which demonstrate that this material has excellent biocompatibility and no obvious cytotoxicity for HeLa cells, which may be used in the medical treatment.

  18. Ultrastructural changes in the ovary cells of engorged Rhipicephalus sanguineus female ticks treated with esters of ricinoleic acid from castor oil (Ricinus communis).

    Science.gov (United States)

    Sampieri, Bruno Rodrigues; Arnosti, André; Nunes, Pablo Henrique; Furquim, Karim Christina Scopinho; Chierice, Gilberto Orivaldo; Mathias, Maria Izabel Camargo

    2012-05-01

    Rhipicephalus sanguineus is a widely distributed tick species that has adapted to the urban environment, and the dog is its main host. This species is also known as a vector and reservoir of diseases caused by bacteria, protozoa, and viruses. Currently, acaricides of synthetic chemical origin have been widely and indiscriminately used, leading to the development of resistance to these products by ticks and causing damage to the environment. Thus, these issues have made it necessary to seek other forms of controlling these ectoparasites. R. sanguineus was artificially infested in host New Zealand White rabbits, which were divided into four treatment groups: control (CG1 and CG2) and treatment (TG1 and TG2) groups. TG1 and TG2 hosts were provided with feed supplemented with esters of ricinoleic acid from castor oil at a concentration of 5 g/kg of feed for 7 and 15 days. Afterward, the ovaries of the female ticks were removed for analysis by transmission electron microscopy. The results showed ultrastructural changes in the somatic and germ cells of ovaries from TG1 and TG2 females, particularly with respect to chorion deposition, a protective membrane of the oocyte, as well as in the transport process of vitellogenic materials via the hemolymph and pedicel cells. Moreover, the mitochondria were less electron-dense and had cristae that were more disorganized than the mitochondria from CG1 and CG2 individuals. Thus, this study demonstrated the action of esters on the ovaries of R. sanguineus, signaling the prospect of a way to control this ectoparasite without affecting nontarget organisms or the environment.

  19. Shock Hugoniot and equations of states of water, castor oil, and aqueous solutions of sodium chloride, sucrose and gelatin

    Science.gov (United States)

    Gojani, A. B.; Ohtani, K.; Takayama, K.; Hosseini, S. H. R.

    2016-01-01

    This paper reports a result of experiments for the determination of reliable shock Hugoniot curves of liquids, in particular, at relatively low pressure region, which are needed to perform precise numerical simulations of shock wave/tissue interaction prior to the development of shock wave related therapeutic devices. Underwater shock waves were generated by explosions of laser ignited 10 mg silver azide pellets, which were temporally and spatially well controlled. Measuring temporal variation of shock velocities and over-pressures in caster oil, aqueous solutions of sodium chloride, sucrose and gelatin with various concentrations, we succeeded to determine shock Hugoniot curves of these liquids and hence parameters describing Tait type equations of state.

  20. Production of Ricinoleic Acid from Castor Oil by Free Lipase-mediated Hydrolysis%游离脂肪酶催化蓖麻油制备蓖麻油酸

    Institute of Scientific and Technical Information of China (English)

    杨威; 杜伟; 刘德华

    2014-01-01

    游离脂肪酶与固定化脂肪酶相比具有成本低、反应速率快等优势,是油脂化工中新的研究方向。前期研究表明,游离脂肪酶NS81006能高效催化多种油脂水解,进一步研究其对含独特羟基的绿色石油材料蓖麻油的水解过程,对于促进游离脂肪酶在新能源领域的应用具有重要意义。本文对影响游离脂肪酶NS81006催化蓖麻油水解过程的主要因素,温度、酶用量、水用量和搅拌速率进行了研究和优化,在优化后的条件下48 h水解率可达94.8%,且发现通过离心分离可有效实现NS81006的重复使用,连续回用5个批次,游离脂肪酶仍能有效催化水解反应。而对比高温高压法水解蓖麻油,发现游离脂肪酶NS81006具有明显优势。%Compared to immobilized lipase, free lipase has the merits of lower cost and faster reaction rate, which is a rising research orientation in oil chemical industry. The previous study showed that free lipase NS81006 is capable of efficiently hydrolyzing oil to fatty acids. Further study on its unique hydrolysis process of castor oil, an environmentally friendly hydroxyl oil, is of great importance for its application in new energy. By means of optimizing the main influence factors of the castor oil hydrolysis catalyzed by NS81006 involving temperature, enzyme dosage, water usage, and stirring speed, 98. 4% degree of hydrolysis was achieved under the optimum conditions at 48 h. The free lipase could be reused after centrifugation and maintained high catalytic efficiency in 5 consecutive recovery batches. It was also found that enzyme catalysis has obvious advantage in castor oil hydrolyzation compared with HTHP .

  1. Castor oil polyurethane containing silica nanoparticles as filling material of bone defect in rats Poliuretana de mamona contendo nanopartículas de sílica como material de preenchimento de defeito ósseo em ratos

    Directory of Open Access Journals (Sweden)

    Renato Silva Nacer

    2012-01-01

    Full Text Available PURPOSE: To evaluate the biologic behavior of the castor polymer containing silica nanoparticles as a bone substitute in diafisary defect. METHODS: Twenty seven male rattus norvegicus albinus wistar lineage were submitted to bone defect filled with castor oil polymer. Three experimental groups had been formed with nine animals each: (1 castor oil polymer containing only calcium carbonate; (2 castor oil polymer with calcium carbonate and doped with 5% of silica nanoparticles; (3 castor polymer with calcium carbonate doped with 10% of silica nanoparticles; 3 animals of each group were submitted to euthanasia 15, 30 and 60 days after experimental procedure, and their femurs were removed to histological evaluation. RESULTS: there was bone growth in all the studied groups, with a greater tendency of growth in the group 1. After 30 days all the groups presented similar results. After 60 days a greater amount of fibroblasts, osteoblasts, osteocytes and osteoclasts in group 3 was observed, with integrated activity of 3 kinds of cells involved in the bone activation-reabsorption-formation. CONCLUSIONS: The castor polymer associated to the silica nanoparticles is biocompatible and allows osteoconduction. The presence of osteoprogenitors cells suggests silica osteoinduction capacity.OBJETIVO: Avaliar o comportamento biológico do polímero de mamona contendo nanopartículas de sílica como substituto ósseo. MÉTODOS: Vinte e sete rattus norvergicus albinus, Wistar foram submetidos a defeito ósseo preenchido com polímero de mamona. Foram formados três grupos experimentais, com nove ratos cada: (1 Polímero com carbonato de cálcio; (2 Polímero com carbonato de cálcio dopado com 5% de nanopartículas de sílica; (3 Polímero com carbonato de cálcio dopado com 10% de nanopartículas de sílica; três animais de cada grupo foram submetidos à eutanásia 15, 30 e 60 dias após o procedimento experimental e os fêmures removidos e submetidos à avalia

  2. Research on the recovery of phenol and alkali in the products of castor oil cracking%蓖麻油碱裂解液中酚及碱的回收方法研究

    Institute of Scientific and Technical Information of China (English)

    王文举; 赵晓波; 张哲宇

    2011-01-01

    采用气相色谱-质谱联用仪分析了蓖麻油碱裂解料液的化学组成,研究了溶剂种类、用量对碱裂解料中苯酚和NaOH浸出性能的影响.结果表明:甲醇-叔丁醇混合溶剂(体积比为1∶1)对苯酚和NaOH的浸出具有高选择性;当溶剂用量为6 mL/g时,苯酚回收率可达80%,NaOH回收率可达72%.%The chemical compositions of the products of castor oil cracking were analyzed by gas chromatography-mass spectrometry and then the effect of solvents and its volume on the leaching performance of phenol and sodium hydroxide in the products of castor oil cracking were studied. The results show that methanol-tert-butanol(V(methanol) : V(butanol)= 1: 1) mixed solvents exhibit high leaching selectivity towards phenol and sodium hydroxide. When the solvent dosage is 6 mL/g, the recovery of phenol and sodium hydroxide can be up to 80% and 72% ,respectively.

  3. Fitting Time Functions of Castor Oil Viscous Coefficient by Origin%Origin软件在拟合蓖麻油黏滞系数随温度变化关系曲线中的应用

    Institute of Scientific and Technical Information of China (English)

    金叶; 彭川黔; 梁霄; 张锋; 冯文林; 蒲利春

    2012-01-01

    蓖麻油在不同温度下的黏度系数差别很大,国际公认的标准值只有几个特定温度下的数值,这给实际应用及实验测量结果的比较带来了较大的困难。根据不同温度获得的实验数据,借助于Origin软件,利用曲线拟合方法得出了蓖麻油的黏滞系数随温度变化的函数曲线及相应的经验方程,计算值与实验值符合较好。%The viscosity coefficient of Castor oil is various under different temperature.Under internationally recognized standard,there are only a few values,which is not propitious for application.This paper shows a new method to fit viscosity coefficient of Castor oil with various temperature by Origin.

  4. Preparation of triglyceride polybasic carboxylic acid by ozonolysis of castor oil%臭氧氧化蓖麻油制备甘油三酸酯多元酸的研究

    Institute of Scientific and Technical Information of China (English)

    艾买提江·萨伍提; 吾满江·艾力; 司马义·努尔拉

    2009-01-01

    以蓖麻油为原料,经臭氧氧化法制备甘油三酸酯多元酸.考察了溶剂、臭氧化反应温度及时间,氧化裂解温度及时间对反应的影响.实验结果表明,合成甘油三酸酯多元酸的最佳条件为:m(蓖麻油):m(乙酸) 为1:4,臭氧化反应温度10~15 ℃,时间2 h;氧化裂解温度90~95 ℃,时间2.5 h.在此条件下收率达83%以上.%The preparation of triglyceride polybasic carboxylic acid by ozonolysis reaction from castor oil was studied.The effects of reaction factors such as solvent,reaction time and temperature of ozonolysis,reaction time and temperature of oxygenolysis were discussed.The results showed that the optimum conditions of synthesizing polybasic carboxylic acid were as follows:mass ratio of castor oil to 10-15 ℃,oxygenolysis time 2.5 h and oxygenolysis temperature 90-95 ℃.The yield was over 83% under the optimum conditions.

  5. Synthesis & Property of Siloxane-endcapped Castor Oil-modified Polyurethane%硅烷封端蓖麻油改性聚氨酯预聚物合成及性能研究

    Institute of Scientific and Technical Information of China (English)

    游胜勇; 陈衍华; 邹怀华; 詹媖

    2013-01-01

    The isocyanate endcapped castor oil-modified polyurethane prepolymer was synthesized with renewable castor oil,polyether polyols,and toluene diisocyanate (TDI) as the starting material.The obtained isocyanate capped polyurethane prepolymer was reacted with 3-aminopropyltriethoxysilane to produce siloxaneendcapped castor oil modified polyurethane prepolymer.IR was used for the analysis of the structure of materials,and TGA was used for the thermal property.The mechanical properties of the film were also tested.Results indicated that the proper temperature of siloxane-endcapped castor oil-modified polyurethane and KH 550 was 70℃,the reaction time was 4 h; as the curing temperature was increased,the tack-free time of the polyurethane film was decreased.When the curing temperature exceeded 30℃,the downtrend tends to be smooth.The film kept stable before 230℃,its tensile strength reached to 11.6 MPa with an elongation of 460%.Compared with castor oil-modified prepolymer,its elongation improved by 37.8% and 22.1%,respectively.%以可再生的蓖麻油、聚酯多元醇、甲苯二异氰酸酯为原料,合成出异氰酸酯基封端蓖麻油改性聚氨酯预聚体;再与γ-氨丙基三乙氧基硅烷(KH 550)反应,制备出硅烷封端蓖麻油改性聚氨酯预聚物.采用红外光谱对预聚体结构进行了定性分析,采用热失重对成膜物进行热性能分析,并测试了成膜物的力学性能.结果表明,异氰酸酯基封端蓖麻油改性聚氨酯与KH 550的较佳反应温度为70℃,反应时间为4h;随固化温度的增加,硅烷封端蓖麻油改性聚氨酯胶膜的表干时间缩短,固化温度大于30℃后下降趋势趋于平坦;固化膜能在230℃前保持稳定,其拉伸强度达到11.6 MPa、拉断伸长率为460%,与蓖麻油改性聚氨酯相比分别提高37.8%、22.1%.

  6. Biologia comparada de Spodoptera cosmioides (Walk. (Lepidoptera: Noctuidae em cebola, mamona, soja e feijão Compared biology of Spodoptera cosmioides (Walk. (Lepidoptera: Noctuidae in onion, castor oil plant, soybean and bean

    Directory of Open Access Journals (Sweden)

    Alvimar Bavaresco

    2003-12-01

    Full Text Available Estudou-se a biologia de Spodoptera cosmioides (Walk. sobre quatro hospedeiros naturais (folhas de cebola, mamona, soja cv. Embrapa 48 e feijão cv. Carioca. Foram avaliados a duração e viabilidade das fases imaturas e do ciclo total, número de ínstares, peso de pupas, razão sexual, porcentagem de deformação de adultos e de adultos não liberados dos invólucros pupais, longevidade de adultos, fecundidade e viabilidade de ovos. Observou-se menor duração e maior viabilidade do período ovo-adulto para mamona e cebola (39,7 dias e 21,7% e 40,5 dias e 21,8%, respectivamente, do que para soja (46,0 dias e 3,9%. O peso pupal foi de 444,6 mg em cebola, 420,0 em feijão, 396,6 em mamona e 298,7 em soja. Constatou-se um predomínio de seis ínstares larvais em folhas de cebola e mamona, ocorrendo também sete para alguns indivíduos, enquanto que em soja predominou a ocorrência de sete, também verificando oito ínstares, indicando uma menor adequação nutricional deste hospedeiro. As fêmeas apresentaram duração da fase pupal significativamente menor do que os machos em todos hospedeiros, fazendo com que a emergência do adulto ocorresse antes dos machos. Em cebola, a longevidade de adultos foi significativamente superior aos demais hospedeiros. A fecundidade foi maior em cebola e mamona (3224 e 3206 ovos/fêmea, respectivamente, enquanto que para soja observou-se 1353 ovos/fêmea. Em folhas de feijão, o desenvolvimento do inseto foi prejudicado por caracteres morfológicos - pilosidade, que promoveram elevada mortalidade na fase larval.The biology of Spodoptera cosmioides (Walk. was studied on four natural hosts (onion leaves, castor oil plant, soy cv. Embrapa 48 and bean cv. Carioca. The duration and viability of immature phases and total cycle, instar number, pupals weight, sexual ratio, percentage of deformed adults and adults not released of pupal beg, adults' longevity, fecundity and eggs viability were evaluated. It was observed in

  7. Waterborne polyurethane adhesive modified by castor oil and silane%蓖麻油/硅烷双重改性水性聚氨酯黏合剂

    Institute of Scientific and Technical Information of China (English)

    段启勇; 潘飞; 曾县明; 朱守玉; 吕建平

    2011-01-01

    With polyether diol (N220 and N240) and isophorone diisocyanate (IPDI) as main raw materials,dimethylolpropionic acid (DMPA) as hydrophilic chain extender, trihydroxylmethylpropane (TMP), castor oil (CO)and organic silane(KH-550) as cross linkers, a waterborne polyurethane (WPU) adhesive modified by CO/KH-550 was synthesized.The influences of some factors such as the mass ratio of m(N220)∶m(N240),CO and KH-550 contents on the properties of WPU adhesive and its pigment printing fabric were discussed.The results showed that the WPU adhesive modified by CO/KH-550 had better water resistance,the rubbing fastness and soaping fastness of fabric with CO/KH-550 modified WPU as adhesive of pigment printing were obviously higher than those with unmodified WPU as adhesive of pigment printing,and the former fabric was more soft when R value(namely molar ratio of-NCO to -OH) was l.4,the mass fractions of CO and KH-550 were 5% and 4% respectively,the mass ratio of m(N220)∶m(N240) was 2∶1.%以聚醚二元醇(N220和N240)和异佛尔酮二异氰酸酯(IPDI)为主要原料,二羟甲基丙酸(DMPA)为亲水扩链剂,三羟甲基丙烷(TMP)、蓖麻油(CO)和有机硅烷(KH-550)为交联剂,合成了CO/KH-550双重改性WPU(水性聚氨酯)黏合剂.探讨了m(N220)∶m(N240)比例、CO和KH-550用量对WPU黏合剂及其涂料印花织物性能的影响.结果表明:当R=n(-NCO)/n(-OH)=1.4、w(CO)=5%、m(N220):m(N240)=2∶1和w(KH-550)=4%时,CO/KH-550双重改性WPU黏合剂的耐水性较好,其涂料印花织物的摩擦牢度及皂洗牢度均明显高于未改性WPU,并且织物手感较柔软.

  8. Castor bean response to zinc fertilization

    Energy Technology Data Exchange (ETDEWEB)

    Chaves, Lucia Helena Garofalo; Cunha, Tassio Henrique Cavalcanti da Silva; Lima, Vinicius Mota; Cabral, Paulo Cesar Pinto; Barros Junior, Genival; Lacerda, Rogerio Dantas de [Universidade Federal de Campina Grande (UAEAg/UFCG), PB (Brazil). Unidade Academica de Engenharia Agricola

    2008-07-01

    Zinc is a trace element and it is absolutely essential for the normal healthy growth of plants. This element plays a part of several enzyme systems and other metabolic functions in the plants. Castor beans (Ricinus communis L.) crop is raising attention as an alternative crop for oil and biodiesel production. Despite the mineral fertilization is an important factor for increasing castor beans yield, few researches has been made on this issue, mainly on the use of zinc. In order to evaluate the effects of zinc on growth of this plant an experiment was carried out in a greenhouse, in Campina Grande, Paraiba State, Brazil, from July to December 2007. The substrate for the pot plants was a 6 mm-sieved surface soil (Neossolo Quartzarenico). The experimental design was a completely randomized with three replications. The treatments were composed of five levels of Zn (0; 2; 4; 6 and 8 mg dm{sup -3}), which were applied at the time of planting. One plant of castor bean, cultivar BRS 188 - Paraguacu, was grown per pot after thinning and was irrigated whenever necessary. Data on plant height, number and length of leaves and stem diameter were measured at 21, 34, 77 and 103 days after planting. Under conditions that the experiment was carried out the results showed that the Zn levels used, did not affect the castor bean plants growth. (author)

  9. A review on the challenges for increassed production of castor

    Science.gov (United States)

    The oil produced by castor (Ricinus communis) is an important raw material for chemical industry for its unique properties such as the only commercial source of a hydroxilated fatty acid that composes around 90% of the oil. This crop has a remarkable potential for increasing importance as a raw mate...

  10. Castor bean organelle genome sequencing and worldwide genetic diversity analysis.

    Directory of Open Access Journals (Sweden)

    Maximo Rivarola

    Full Text Available Castor bean is an important oil-producing plant in the Euphorbiaceae family. Its high-quality oil contains up to 90% of the unusual fatty acid ricinoleate, which has many industrial and medical applications. Castor bean seeds also contain ricin, a highly toxic Type 2 ribosome-inactivating protein, which has gained relevance in recent years due to biosafety concerns. In order to gain knowledge on global genetic diversity in castor bean and to ultimately help the development of breeding and forensic tools, we carried out an extensive chloroplast sequence diversity analysis. Taking advantage of the recently published genome sequence of castor bean, we assembled the chloroplast and mitochondrion genomes extracting selected reads from the available whole genome shotgun reads. Using the chloroplast reference genome we used the methylation filtration technique to readily obtain draft genome sequences of 7 geographically and genetically diverse castor bean accessions. These sequence data were used to identify single nucleotide polymorphism markers and phylogenetic analysis resulted in the identification of two major clades that were not apparent in previous population genetic studies using genetic markers derived from nuclear DNA. Two distinct sub-clades could be defined within each major clade and large-scale genotyping of castor bean populations worldwide confirmed previously observed low levels of genetic diversity and showed a broad geographic distribution of each sub-clade.

  11. Castor bean organelle genome sequencing and worldwide genetic diversity analysis.

    Science.gov (United States)

    Rivarola, Maximo; Foster, Jeffrey T; Chan, Agnes P; Williams, Amber L; Rice, Danny W; Liu, Xinyue; Melake-Berhan, Admasu; Huot Creasy, Heather; Puiu, Daniela; Rosovitz, M J; Khouri, Hoda M; Beckstrom-Sternberg, Stephen M; Allan, Gerard J; Keim, Paul; Ravel, Jacques; Rabinowicz, Pablo D

    2011-01-01

    Castor bean is an important oil-producing plant in the Euphorbiaceae family. Its high-quality oil contains up to 90% of the unusual fatty acid ricinoleate, which has many industrial and medical applications. Castor bean seeds also contain ricin, a highly toxic Type 2 ribosome-inactivating protein, which has gained relevance in recent years due to biosafety concerns. In order to gain knowledge on global genetic diversity in castor bean and to ultimately help the development of breeding and forensic tools, we carried out an extensive chloroplast sequence diversity analysis. Taking advantage of the recently published genome sequence of castor bean, we assembled the chloroplast and mitochondrion genomes extracting selected reads from the available whole genome shotgun reads. Using the chloroplast reference genome we used the methylation filtration technique to readily obtain draft genome sequences of 7 geographically and genetically diverse castor bean accessions. These sequence data were used to identify single nucleotide polymorphism markers and phylogenetic analysis resulted in the identification of two major clades that were not apparent in previous population genetic studies using genetic markers derived from nuclear DNA. Two distinct sub-clades could be defined within each major clade and large-scale genotyping of castor bean populations worldwide confirmed previously observed low levels of genetic diversity and showed a broad geographic distribution of each sub-clade.

  12. Castor Bean Organelle Genome Sequencing and Worldwide Genetic Diversity Analysis

    Science.gov (United States)

    Chan, Agnes P.; Williams, Amber L.; Rice, Danny W.; Liu, Xinyue; Melake-Berhan, Admasu; Huot Creasy, Heather; Puiu, Daniela; Rosovitz, M. J.; Khouri, Hoda M.; Beckstrom-Sternberg, Stephen M.; Allan, Gerard J.; Keim, Paul; Ravel, Jacques; Rabinowicz, Pablo D.

    2011-01-01

    Castor bean is an important oil-producing plant in the Euphorbiaceae family. Its high-quality oil contains up to 90% of the unusual fatty acid ricinoleate, which has many industrial and medical applications. Castor bean seeds also contain ricin, a highly toxic Type 2 ribosome-inactivating protein, which has gained relevance in recent years due to biosafety concerns. In order to gain knowledge on global genetic diversity in castor bean and to ultimately help the development of breeding and forensic tools, we carried out an extensive chloroplast sequence diversity analysis. Taking advantage of the recently published genome sequence of castor bean, we assembled the chloroplast and mitochondrion genomes extracting selected reads from the available whole genome shotgun reads. Using the chloroplast reference genome we used the methylation filtration technique to readily obtain draft genome sequences of 7 geographically and genetically diverse castor bean accessions. These sequence data were used to identify single nucleotide polymorphism markers and phylogenetic analysis resulted in the identification of two major clades that were not apparent in previous population genetic studies using genetic markers derived from nuclear DNA. Two distinct sub-clades could be defined within each major clade and large-scale genotyping of castor bean populations worldwide confirmed previously observed low levels of genetic diversity and showed a broad geographic distribution of each sub-clade. PMID:21750729

  13. Estratégias de irrigação com água salina na mamoneira Irrigation strategies with saline water in castor oil plant

    Directory of Open Access Journals (Sweden)

    Maria Eugênia da Costa

    2013-03-01

    Full Text Available Este experimento foi realizado em campo para avaliar estratégias de irrigação com água salina no crescimento e na produção da mamoneira (BRS Energia, além de identificar eventuais estádios de maior tolerância à salinidade e monitorar alguns atributos químicos do solo. Os tratamentos consistiram da irrigação com águas de CE 0,53; 2,09; 3,66 dS m-1 de acordo com a fase de desenvolvimento da cultura, totalizando cinco estratégias de irrigação com água salina e uma testemunha. As avaliações de crescimento foram realizadas aos 20; 40; 60; 80; 100 dias após a semeadura (DAS. As coletas de solo foram realizadas concomitantemente às avaliações de crescimento, nas camadas 0-0,10; 0,10-0,30; 0,30-0,50 m. A irrigação contínua com água de CE 3,66 dS m-1 reduziu a altura de planta, o comprimento de racemo terciário, o número de frutos por área útil e a produtividade de frutos. Essa estratégia aumentou acentuadamente os teores de Na+ e a CE do solo no final do ciclo. Por outro lado, a irrigação com água salina começando aos 45 DAS não prejudicou as variáveis de crescimento e os componentes de produção. Essa estratégia minimizou os impactos negativos sobre a salinidade/sodicidade do solo no final do ciclo. Comportamento similar foi observado para a irrigação contínua com água de CE 2,09 dS m-1 (mistura de águas com CE de 0,53 e 3,66 dS m-1. A mamoneira não apresentou tolerância diferenciada à salinidade em função da fase de desenvolvimento, embora tenha sido prejudicada quando aumentaram a intensidade e a duração do estresse salino.This experiment was conducted under field conditions to evaluate irrigation strategies with saline water on growth and production of castor oil plant (cv. BRS Energia, identify eventual stages with higher tolerance to salinity and monitor some soil chemical attributes. The treatments consisted of irrigations with water of EC 0.53; 2.09; 3.66 dS m-1 according to the development

  14. 蓖麻油聚氧乙烯醚水基润滑液摩擦学特性研究%Lubricating Properties of the Aqueous Solution of Castor Oil Polyoxyethylene Ether

    Institute of Scientific and Technical Information of China (English)

    刘俊铭; 张晨辉; 张朝辉; 王岩; 刘思思

    2011-01-01

    本文以蓖麻油聚氧乙烯醚水基润滑液为研究对象,分别使用润滑膜厚度测量仪、微摩擦试验机和四球摩擦试验机对其成膜特性、摩擦磨损特性和抗磨极压特性进行了系统的研究,并用扫描电子显微镜和能量色散光谱仪对摩擦磨损机制进行了分析.结果表明:蓖麻油聚氧乙烯醚提高了纯水的成膜能力,能够在钢-铝摩擦副形成有效的润滑膜,起到良好的减摩抗磨效果.随着浓度的增大,对钢-铝摩擦副的减摩抗磨性能和四球摩擦试验的抗磨极压性能都得到了提高.%The soluble polyether has attracted more attention due to its excellent lubricating performance and environment -friendly properties. The lubricating characteristics of castor oil polyoxyethylene ether solution, e. G. Film forming ability, friction-reducing, ami -wear and extreme pressure properties, were systematically investigated on the lubricating film measuring instrument, universal micro - tribotester and four - ball friction tester, respectively. The friction and wear mechanisms were analyzed by scanning electron microscopy and energy dispersive spectroscopy. The results show that the film forming ability of water was improved by mixing in castor oil polyoxyethylene ether. The effective lubricating film can be formed at the tribo - interface of steel/aluminum tribo - pair to reduce friction coefficient and improve anti - wear properties. The performance of the castor oil polyoxyethylene ether solution in friction reduction, anti -wear and extreme pressure was improved with the increasing solution concentration.

  15. Castor oil modified two-components PU laminating adhesive without solvent%蓖麻油改性无溶剂型双组分聚氨酯复膜胶

    Institute of Scientific and Technical Information of China (English)

    杨俊香; 季永新

    2013-01-01

    With castor oil,phthalic anhydride and diethylene glycol as raw materials,a polyester polyol modified by castor oil,which could be used as curing agent of laminating adhesive,was synthesized by esterification and polycondensation.With MDI-50 (diphenyl methane diisocyanate) and PPG-2000/PPG400 (polyether diols) as raw materials,a-NCO-end polyurethane(PU) prepolymer,which could be used as main agent of laminating adhesive,was synthesized.Finally,a two-components PU laminating adhesive without solvent was prepared by mixing between main agent and curing agent according to certain proportion.The research results showed that the main agent had the relatively optimal viscosity and liquidity when reaction temperature was 45℃,reaction time was 3h and mass fraction of-NCO was 18%.The laminating adhesive had the relatively best bonding property,and bonding properties between laminating adhesive and like import product were adjacent when molar ratio of n(-NCO)∶n(-OH) was 1.9∶1 in two-components,curing temperature and time were 50℃ and 24h respectively,and mass fraction of castor oil was 28.3%.%以蓖麻油、苯酐和二甘醇等为原料,经酯化、缩聚后,合成了蓖麻油改性聚酯多元醇,并以此作为复膜胶的固化剂;以MDI-50(二苯基甲烷二异氰酸酯)、PPG-2000/PPG400(聚醚二元醇)为原料,合成了端-NCO基聚氨酯(PU)预聚体,并以此作为复膜胶的主剂;将主剂和固化剂按一定比例混合后,制得无溶剂型双组分PU复膜胶.研究结果表明:当反应温度为45℃、反应时间为3h和w(-NCO)=18%时,主剂的黏度、流动性相对最好;当双组分中n(-NCO)∶n(-OH)=1.9∶1、固化温度为50℃、固化时间为24h和w(蓖麻油)=28.3%时,复膜胶的粘接性能相对最好,并且接近于进口同类产品.

  16. Clinical efficacy of oral or nasal feeding of castor oil for simple intestinal obstruction%蓖麻油辅助治疗单纯性肠梗阻疗效观察

    Institute of Scientific and Technical Information of China (English)

    李正才

    2011-01-01

    Objective To study the clinical efficacy of oral or nasal feeding of castor oil for simple intestinal obstruction. Methods 120 patients with intestinal obstruction were randomly divided into treatment group(n =60)and control group(n = 60). The patients in treatment group were given both o-ral or nasal feeding castor oil and conventional therapy for 5 days, and those in control group administered with conventional therapy alone. The clinical outcome was compared between two groups. Results The total curative rate wassignificantly higher in treatment group than in control group(P<0. 05). The mean time of gastrointestinal function recovery, passage of flatus or stool and hospital stay in treatment group were significantly shorter than in control group(P<0. 05). Conclusion Oral or nasal feeding castor oil is effective,quick and safe for treatment of simple intestinal obstruction.%目的 观察口服或鼻饲蓖麻油辅助治疗单纯性肠梗阻的临床疗效.方法 将120例肠梗阻病人随机分为治疗组(60例)和对照组(60例).治疗组在常规基础治疗上加口服或鼻饲蓖麻油,对照组仅予常规基础治疗.观察治疗5d,比较两组疗效.结果 治疗组治愈率及总有效率明显高于对照组,且临床症状改善时间、肛门排气排便时间及住院时间也均显著早于对照组,差异具有统计学意义(P<0.05).结论 口服或鼻饲蓖麻油治疗肠梗阻疗效肯定,见效快,使用安全,可以推广应用.

  17. 粗蓖麻油合成生物柴油反应热力学分析%Thermodynamic Analysis of Biodiesel Synthesis from Rude Castor Oil

    Institute of Scientific and Technical Information of China (English)

    袁红

    2012-01-01

    [Objective]The thermodynamics characters of biodiesel synthesis from rude castor oil (with water and free fatty acid) and methanol were studied. [Method] Yoneda group contribution method and other empirical formulas were applied to calculate the enthalpy,entropy and heat capacity of triglycerides (TG),diacylglycerol (DG) , monoglyceride ( MG) , methyl ( ME) and free fatty acids (FFA) of five fatty acids in the system. The thermodynamic analysis of biodiesel synthesis system which involves transesterification,esterification and hydrolysis reaction was carried out. [Result]The calculated results showed,Gibbs free energy change ( ΔrG0) in the first and the third steps of transesterification were all less than zero, ΔrG0 of the second step of transesterification was greater than zero. ΔrG0 of the esterification ( FFA and methanol) was less than zero ΔrG0 of the three steps of hydrolysis were greater than zero. [ Conclusion] The presence of FFA had more influence on the transesterification than the presence of water.%[目的]研究粗蓖麻油(含水、游离脂肪酸)与甲醇为原料的生物柴油合成体系的反应热力学特性.[方法]采用Yoneda基团贡献法和其他经验公式计算了组成蓖麻油的5种脂肪酸甘油三酸酯(TG)、甘油二酸酯(DG)、甘油单酸酯(MG)、脂肪酸甲酯(ME)及游离脂肪酸(FFA)的焓、熵及热容等基础热力学数据;对生物柴油合成体系,反应涉及酯交换、酯化及水解共3类7个反应进行了热力学分析.[结果]蓖麻油与甲醇的第1步和第3步酯交换反应的吉布斯自由能变化(△rG0)均小于0,第二步酯交换反应的△rG0大于0,游离脂肪酸与甲醇的酯化反应的△rG0小于0,蓖麻油与水的3步水解反应的△rG0均大于0.[结论]蓖麻油中游离脂肪酸的存在比水的存在对蓖麻油的酯交换反应影响更大.

  18. 异氰酸酯指数对蓖麻油聚氨酯胶粘剂性能的影响%Influence of Isocyanate Index on the Properties of Castor Oil Based Polyurethane Adhesive

    Institute of Scientific and Technical Information of China (English)

    贾金荣; 黄志雄; 秦岩; 王富忠; 张慧

    2012-01-01

    A solventless castor oil based polyurethane adhesive was prepared by TDI and castor oil.The structure, damping property and morphology were investigated by FT-IR, DMA and SEM.The influence of isocyanate index (nNCO/nOH) on the damping and adhesion mechanical property and morphology were also examined.The results showed that the adhesive exhibited excellent damping property, the glass transition temperature, damping temperature range and maximum loss factor were - 18.4 ℃,48.3 ℃ and 1.262 when nNCO/nOH was 1.4 in prepolymer. The adhesive with nNCO/nOH 1.6 showed the optimal mechanical property.%以甲苯-2,4-二异氰酸酯(TDI)及蓖麻油为原料制备了一种无溶剂蓖麻油聚氨酯胶粘剂,用FT-IR、DMA及SEM分析了胶粘剂结构、阻尼性能及断口形貌,考察了异氰酸酯指数(nNco/noH)对胶粘剂阻尼、粘接的力学性能及断面形貌的影响.结果表明,当预聚体中nNCO/nOH为1.4时,该胶粘剂阻尼性能优异,玻璃化转变温度Tg为-18.4℃,阻尼温域为48.3℃,(tanδ)max为1.262;胶粘剂的力学性能在nNCO/noH为1.6时达到最佳.

  19. 蓖麻油多元醇在聚氨酯阻燃硬泡中的应用研究%Application of Castor Oil Polyol in the Flame-Retardant Rigid Polyurethane Foam

    Institute of Scientific and Technical Information of China (English)

    冯月兰; 李其峰; 王军威; 亢茂青; 曹月领; 王心葵

    2013-01-01

    Castor oil polyol (COP) was prepared by the transesterification of castor oil with glycerin, and applied for the manufacture of inflaming retarding rigid polyurethane foam ( RPUF). The effect of flame-retardants type and content, COP dosage on the overall performance of RPUF was investigated. The results showed that COP affected the limiting oxygen index of RPUF slightly, except that the RPUF could shrink when the COP content exceeded 50%. Among the introduced flame-retardants, dimethyl methylphosphonate ( DMMP) exhibited highest flame resistance for RPUF. The further investigation confirmed that adding DMMP of about 20% ~ 30% of totel polyols weight should be more favorable for keeping overall performance of RPUF.%通过蓖麻油与甘油进行酯交换反应制备蓖麻油多元醇,并应用于聚氨酯阻燃硬泡的制备,研究了阻燃剂类型、添加量及蓖麻油多元醇的添加量对聚氨酯硬质泡沫(RPUF)综合性能的影响.结果表明,蓖麻油多元醇的添加量对阻燃RPUF氧指数影响不大,只是添加量大于50%时会导致泡沫收缩;添加不同阻燃剂后发现甲基磷酸二甲酯(DMMP)的阻燃效果好,DMMP合适用量为多元醇组分的20% ~ 30%.

  20. Mid-low Castor Agronomic Traits under Different Density Level and the Oil Content of the Correlation and Path Analysis%不同密度水平下矮秆蓖麻各农艺性状与含油量的相关及通径分析

    Institute of Scientific and Technical Information of China (English)

    贾娟霞; 朱国立; 衣海会; 何智彪; 莫德乐吐; 张智勇; 乔文杰

    2013-01-01

    对5个不同种植密度处理下2个矮秆蓖麻品种含油量与个农艺性状态进行相关及通径分析。总结出不同密度水平下,影响矮秆蓖麻含油量的主要农艺性状,并提出提高密植矮秆蓖麻的含油量,一定要主攻容重,在增加容重的基础上增加株穗数,并选择适中的株高、茎粗及主穗与一级分枝夹角。%through the analysis of 5 different planting densities of 2 dwarf castor varieties of oil content and agronomic state correlation and path ,it could be summarized that the main agronomic traits of dwarf castor oil content in different density level, and be put forward improving oil content close planting dwarf castor-oil plant,and the bulk density must be the main part, increasing on the number of spike per plant based on increased bulk density, and choose the moderate plant height, stem diameter and main spike and a branch angle.

  1. Modulating the properties of sunflower oil based novel emulgels using castor oil fatty acid ester: prospects for topical antimicrobial drug delivery.

    Science.gov (United States)

    Behera, B; Biswal, D; Uvanesh, K; Srivastava, A K; Bhattacharya, Mrinal K; Paramanik, K; Pal, K

    2015-04-01

    The current study describes the effect of polyglycerol polyricinoleate (PGPR) on the properties of sunflower oil and span-40 based emulgels. The prepared emulgels contained PGPR in varied concentrations. The microstructure of the emulgels was characterized by bright-field microscopy. The molecular interactions amongst the components of the emulgels were studied using FTIR spectroscopy. The flow and mechanical behaviors of the emulgels were studied using cone-and-plate viscometer and static mechanical tester, respectively. The efficiency of the metronidazole-loaded emulgels as antimicrobial formulations was tested in vitro. E. coli was used as the model microorganism for the antimicrobial study. The emulgels were also explored for iontophoretic delivery applications. The biocompatibility of the emulgels was tested using human keratinocytes (HaCaT). The microscopic evaluation of the emulgels indicated formation of biphasic formulations. FTIR studies suggested a decrease in the hydrogen bonding amongst the components of the emulgels as the concentration of the PGPR was increased. Viscosity studies indicated shear-thinning property of the emulgels. An increase in the PGPR concentration resulted in the reduction in the mechanical properties of the emulgels. Incorporation of PGPR resulted in the decrease in the drug released (both passive and iontophoresis) from the emulgels. The emulgels were found to be cytocompatible in the presence of keratinocytes. The drug loaded emulgels showed good antimicrobial activity against E. coli. In gist, the developed emulgels can be tried for controlled delivery of antimicrobial drugs. The physical and the release properties of the emulgels can be modulated by incorporating PGPR in varied proportions.

  2. 溴化蓖麻油多元醇合成及其制备的阻燃聚氨酯硬泡性能%The Synthesis of Bromine-containing Castor Oil Polyol and the Flame-retardant Polyurethane Foam Prooerties

    Institute of Scientific and Technical Information of China (English)

    何明; 罗振扬; 史以俊; 顾晓利; 张银萍

    2011-01-01

    A novel bromine-containing castor oil based polyol was prepared via the reaction of glycerin-exchanged castor oil and bromine.Structure of bromation product was analyzed by FT-IR.The basic characters of the polyol, such as viscosity, hydroxyl value and acid value were investigated.The effects of bromine-containing castor oil based polyols on properties of the rigid polyurethane foams, especially on their resistance to combustion, were studied by foam experiment, oxygen index, smoke density and horizontal burning experiments.It was compared with the foam prepared by RB-79 of Albemarle Corporation.It was found that the bromine-containing castor oil based polyols were effective for improving the resistance to combustion of rigid polyurethane foams, having the same effects with the commercial flame retardant RB-79 of Albemarle Corporation.%采用可再生的醇解蓖麻油多元醇为原料,与液溴进行加成反应制备溴化蓖麻油多元醇,通过红外光谱证实发生了溴化反应,并测定了产物粘度、羟值、酸值.通过发泡实验和氧指数、烟密度、水平燃烧等测试手段,考察了溴化蓖麻油基聚氨酯硬泡发泡参数和阻燃性质,并与工业级阻燃荆雅保RB-79制备的聚氨酯硬泡进行比较.结果表明,由溴化蓖麻油多元醇制备的泡沫体现出较好阻燃性能,与RB-79的阻燃效果相当.

  3. Análise macroscópica e histológica do emprego da poliuretana derivada do óleo de mamona (Ricinus communis aplicada na tíbia de cães em fase de crescimento Macroscopic and histopathologic evaluations of the use of polyurethane resins derived from castor oil (Ricinus communis applied in the tibia of the puppies

    Directory of Open Access Journals (Sweden)

    Patricia Popak Maria

    2003-08-01

    Full Text Available OBJETIVO: Estudar o efeito da poliuretana de mamona aplicada ao osso de cães em crescimento. MÉTODOS: Foram utilizados 12 cães subdivididos aleatoriamente em 3 grupos, os quais receberam o implante de mamona na face medial proximal da tíbia, com análise macroscópica e histopatológica aos 30 (GIII, 60 (GII e 90 (GI dias. RESULTADOS: A poliuretana foi recoberta por uma cápsula conjuntiva fibrosa, não ocorrendo proliferação óssea ao seu redor. CONCLUSÃO: A poliuretana é biocompatível, comportando-se como espaçador biológico em cães. Nesta espécie não ocorre a osteointegração.PURPOSE: To analyze the effects of castor oil derived poliurethane, when applied to bones of puppies. METHODS: Twelve dogs, randomly divided in 3 groups, received a castor oil derived poliurethane at the medial side of the proximal tibia. Gross and histopathologic evaluations were performed at 30 (GIII, 60 (GII and 90 (GI days. RESULTS: The poliurethane was enclosed in a connective fibrous tissue capsule and there was no new bone formation around it. CONCLUSION: The castor oil derived poliurethane is biocompatible and behaves as a biological "stand off" in dogs. Osteointegration does not occur in this species.

  4. EVALUATION OF PHYSIOLOGY AND BIOCHEMISTRY THE CASTOR BEAN FUNCTION OF DOSES AND FERTILIZER IN SOIL

    Directory of Open Access Journals (Sweden)

    Fabiana Xavier Costa

    2011-04-01

    Full Text Available Aimed at with this work to investigate the physiology and biochemistry of the castor bean, after use of compost and organic castor bean. The trial began on October 3, 2005 ending on March 20, 2006, in green-house, controlled environment of the National Center of Cotton Research (CNPA / EMBRAPA, in Campina Grande , State of Paraiba. Was used to cultivate castor BRS Paraguaçu. We used a randomized block design with four replications, totaling 11 treatments, since they are derived from doses of castor-oil and organic compost (four doses of each and three witnesses, with further study of orthogonal contrasts . The castor bean showed effective results in the variables chlorophyll content (ppm in leaves and number of days to flowering of the first cluster (DIAFI. Compost organic waste not produced any significant result for both variables.

  5. Session 4: Bio-diesel fuel (BDF) production by the trans-esterification of soybean and castor oils and the esterification of fatty acid using fixed bed reactor with solid super-acid and amorphous zirconia catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Satoshi, Furuta; Kyoji, Yano [Petroleum Refining Research and Technology Center, Japan Energy Corporation Niizo-minami, Toda, Saitama (Japan); Hiromi, Matsuhashi; Kazushi, Arata [Hokkaido University of Education, Dept. of Science, Hakodate (Japan)

    2004-07-01

    -esterification. For castor oil as a feedstock at 523 K, WZA showed higher activity than that of Al/ZrO{sub 2}, and in the case with ethanol, the activity of WZA showed little change It seems that the OH groups in ricinoleic acid, main element of castor oil, have an effect on their catalytic action. The catalysts were also evaluated in the esterification of n-octanoic acid with methanol. All of the catalysts also showed high activities. STO showed especially high performance even at low temperature, 40% at 333 K below the boiling temperature of methanol. This is due to its strong acidity of STO. The adsorption heats of Ar were measured to be 20.7, 31.0, and 24.3 kJ/mol for WZA, STO, and SZA, respectively. It is important for the BDF production that catalysts should be also enough active for the esterification of free fatty acid, a source of soap. In conclusion, solid super-acids and amorphous zirconia are promising catalysts for the production of bio-diesel fuels because of their trans-esterification and esterification activities. (authors)

  6. SUBACUTE AND MULTIGENERATIONAL TOXICITY EVALUATION OF CASTOR OIL POLYMER INGESTION IN RATS AVALIAÇÃO DA TOXICIDADE SUBAGUDA E MULTIGERACIONAL DA INGESTÃO DE DERIVADO DO POLÍMERO DE MAMONA EM RATOS

    Directory of Open Access Journals (Sweden)

    Gilberto Chierice

    2009-04-01

    Full Text Available Castor oil polymer is a biomaterial that can be used to fill bone defects. Biomaterials should present some characteristics such as: biocompatibility, inert, absence of toxin radical and vapour discharge and permit the organism to recognize them as a part of their structure. The aim of this study was to investigate changes in water ingestion, feed intake, weight gain and toxic effects in rats (Rattus norvegicus after ingestion of 0, 10, 25 and 50% of castor oil polymer (COP, Ricinus communis. In groups that received 10 and 25% of COP the weight gain was smaller than the control group. Feed intake in control group was greater than in groups 10 and 50% COP. The intake of castor oil polymer reduced feed intake and water ingest probably because of the palatability of the product. In the second part of this study (multigenerational there were no toxic effects in the offspring, as external birth defects or alterations incompatible with life, in spite of the fact that lower weight were observed in males and females of the second generation.

    KEY WORDS: Biomaterials, bone defects, polymer, Ricinus communis. Os biomateriais são polímeros artificiais desenvolvidos para substituir tecidos orgânicos danificados e preencherem falhas ósseas. Eles devem apresentar características como a biocompatibilidade, serem inertes, não liberarem vapores e radicais tóxicos e permitirem ao organismo reconhecê-los como parte de sua estrutura. Procurou-se determinar a ingestão de água, o consumo de ração, ganho de peso e possível efeito tóxico decorrentes da ingestão de três doses (10%, 25% e 50% do derivado do polímero de mamona (PM, Ricinus communis, adicionado à água de bebida, em ratos (Rattus norvegicus. Nos grupos que receberam 10% e 25% do PM, o ganho de peso foi menor (P?0,05, quando comparado ao grupo-controle. O consumo de ração nos grupos que receberam 10% e 50% de PM foi menor em relação ao grupo-controle. A ingestão do pol

  7. Phytotoxicity of three plant-based biodiesels, unmodified castor oil, and Diesel fuel to alfalfa (Medicago sativa L.), lettuce (Lactuca sativa L.), radish (Raphanus sativus), and wheatgrass (Triticum aestivum).

    Science.gov (United States)

    Bamgbose, Ifeoluwa; Anderson, Todd A

    2015-12-01

    The wide use of plant-based oils and their derivatives, in particular biodiesel, have increased extensively over the past decade to help alleviate demand for petroleum products and improve the greenhouse gas emissions profile of the transportation sector. Biodiesel is regarded as a clean burning alternative fuel produced from livestock feeds and various vegetable oils. Although in theory these animal and/or plant derived fuels should have less environmental impact in soil based on their simplified composition relative to Diesel, they pose an environmental risk like Diesel at high concentrations when disposed. The aim of the present study was to ascertain the phytotoxicity of three different plant-derived biodiesels relative to conventional Diesel. For phytotoxicological analysis, we used seeds of four crop plants, Medicago sativa, Lactuca sativa, Raphanus sativus, and Triticum aestivum to analyze the germination of seeds in contaminated soil samples. The toxicological experiment was conducted with two different soil textures: sandy loam soil and silt loam soil. The studied plant-based biodiesels were safflower methyl-ester, castor methyl ester, and castor ethyl-ester. Biodiesel toxicity was more evident at high concentrations, affecting the germination and survival of small-seeded plants to a greater extent. Tolerance of plants to the biodiesels varied between plant species and soil textures. With the exception of R. sativus, all plant species were affected and exhibited some sensitivity to the fuels, such as delayed seedling emergence and slow germination (average=10 days) at high soil concentrations (0.85% for Diesel and 1.76% for the biodiesels). Tolerance of plants to soil contamination had a species-specific nature, and on average, decreased in the following order: Raphanus sativus (0-20%)>Triticum aestivum (10-40%) ≥ Medicago sativa> Lactuca sativa (80-100%). Thus, we conclude that there is some phytotoxicity associated with plant-based biodiesels. Further

  8. Preparation of Castor Oil Modified Thiol-Ene UV-Curable Waterborne Polyurethane Dispersions%蓖麻油改性巯基-烯UV固化水性聚氨酯分散体的制备

    Institute of Scientific and Technical Information of China (English)

    付长清; 陈樟; 乔永洛; 陈义旺; 申亮

    2012-01-01

    采用自乳化聚氨酯水分散体的制备方法,分别制备了含蓖麻油基和巯基的聚氨酯水分散体.将两者按一定比例复合,加入水性光引发剂,在紫外光照射下,通过水性光引发剂引发涂层中的双键及巯基进行巯基-烯点击反应,制得交联聚氨酯涂膜.采用核磁共振氢谱、红外光谱、差示扫描量热仪、热重分析等手段对水分散体及光固化涂膜的结构和性能进行了分析表征.结果表明:巯基和蓖麻油结构中的碳碳双键成功地引入到了水性聚氨酯链段中;在紫外光辐照下,巯基和不饱和双键间进行了加成反应;UV固化膜具有良好的机械性能和热稳定性:凝胶量为96.67%、胶膜吸水率为13.0%、耐冲击性大于50 cm、硬度为5H、耐溶剂(甲乙酮)拭擦次数为734次、失质量50%时的温度为375 ℃.%Waterborne polyurethane containing castor oil ( CAPU ) and waterborne polyurethane containing multifunctional thiol ( SHPU ) were prepared via self - emulsification process of WPU,respectively,which were - blended with addition of aqueous photo - initiator in certain proportions,ihen crosslinked to form polyurethane coatings through thiol - ene couple reaction between the double bond and thiol under UV irradiation. The structure and properties of the title coatings were characterized by 1H - NMR,FT - IR,DSC and TG. The results indicated that thiol and the double bond in castor oil were integrated into polyurethane main chain and thiol - ene addition reaction was proceeded. The UV - cured films showed good mechanical properties and thermal stability with gel content 96. 67% ,solvent - resistance (methyl ethyl ketone) 734 times,pencil hardness 5H,water absorption 13.0% ,impact strength 50 cm and 50% mass loss at 375℃ ,respectively.

  9. 蓖麻饼粕的脱毒及综合开发利用%The Detoxification and Comprehensive Development and Utilization of Castor Bean Meal

    Institute of Scientific and Technical Information of China (English)

    张树军; 狄建军; 白靓; 黄凤兰; 穆莎茉莉; 魏永春; 张国文

    2011-01-01

    Castor bean meal is a by-product after oil extraction,it contains rich protein and amino acids castor bean hulls and a spot of castor toxins,has a high utilization value.This paper reviewes the detoxification of castor bean meal,the development and utilization of proteins in detoxificated castor bean meal,castor toxins and castor bean hull.%蓖麻饼粕是蓖麻籽榨油后的副产品,含有丰富的蛋白和氨基酸、蓖麻壳及少量的蓖麻毒素,具有较高的综合利用价值.本文综述了蓖麻饼的脱毒,脱毒蓖麻饼蛋白质、蓖麻饼中毒素及蓖麻壳的开发利用.

  10. Produção e composição química do leite de cabras mestiças Moxotó sob suplementação com óleo de licuri ou de mamona Production and chemical composition of the milk from crossbred Moxotó goats supplemented with licuri or castor oil

    Directory of Open Access Journals (Sweden)

    Rita de Cássia Ramos do Egypto Queiroga

    2010-01-01

    Full Text Available Avaliou-se o efeito da inclusão de óleos de licuri ou de mamona na dieta sobre a produção, a composição química do leite de cabras leiteiras e a viabilidade econômica dessas dietas. No delineamento experimental foram utilizadas cabras Mestiças Moxotó distribuídas em quadrado latino 5 × 5 com duas repetições, composto de cinco dietas: uma controle, sem lipídio suplementar, e as demais com 3% ou 5% de óleo de licuri ou de mamona. A suplementação com 5% de óleo de licuri reduziu a produção de leite, mas não influenciou a produção de leite corrigida para 4% de gordura. A adição de 3% de óleo de mamona reduziu o teor de gordura e de sólidos totais em comparação ao óleo de licuri, aumentando o teor de lactose. O teor de proteína do leite, no entanto, não foi alterado pela adição de óleo na dieta. Os indicadores econômicos apontaram a dieta controle como a mais rentável, no entanto, a suplementação com 3% de óleo de licuri, em comparação ao de mamona, pode ser interessante quando o leite se destina ao processamento, em virtude do maior teor de gordura.The effect was assessed of including licuri and castor oils in the diet on the production and chemical composition of milk from goats and the economic viability of the diets. Crossbred Moxotó goats in a 5 × 5 Latin square design were used with two replications consisting of five diets: a control treatment without supplementary oil (control, and the others with 3% or 5% licuri or castor oil. Milk production decreased with the inclusion of 5% licuri oil, but it did not influence the production of milk corrected to 4% fat. The addition of 3% castor oil reduced the fat content and total solids production compared to licuri oil, but it increased the lactose content. There was no significant difference in the protein content among treatments. The simple financial analyses showed that the control diet was more profitable, but supplementation with 3% licuri oil when

  11. Morphology and viability of castor bean genotypes pollen grains

    OpenAIRE

    Maria Selma Alves Silva Diamantino; Maria Angélica Pereira de Carvalho Costa; Taliane Leila Soares; Daniel Vieira Morais; Simone Alves Silva; Everton Hilo Souza

    2016-01-01

    The objective of this work was to characterize the morphology and viability of the pollen of 15 genotypes of castor bean (Ricinus communis L.) and to generate information that can assist in the selection of highly promising male parents for future use in genetic improvement programs aimed at producing seeds for oil extraction. Acetolysis and scanning electron microscopy was used to characterize the morphology of the pollen. The viability of the pollen grains was estimated by in vitro germinat...

  12. Morphology and viability of castor bean genotypes pollen grains

    OpenAIRE

    Diamantino,Maria Selma Alves Silva; Costa,Maria Angélica Pereira de Carvalho; Soares,Taliane Leila; Morais,Daniel Vieira; Silva,Simone Alves; Souza,Everton Hilo de

    2016-01-01

    ABSTRACT. The objective of this work was to characterize the morphology and viability of the pollen of 15 genotypes of castor bean (Ricinus communis L.) and to generate information that can assist in the selection of highly promising male parents for future use in genetic improvement programs aimed at producing seeds for oil extraction. Acetolysis and scanning electron microscopy was used to characterize the morphology of the pollen. The viability of the pollen grains was estimated by in vitr...

  13. Physical and Mechanical Characterization of Fiber Cell Wall in Castor (Ricinus communis L. Stalk

    Directory of Open Access Journals (Sweden)

    Xiaoping Li

    2014-02-01

    Full Text Available Castor (Ricinus communis L. stalk is a byproduct of the production of castor oil. As a natural material, castor stalk has great potential in the production of bio-composites as reinforcement materials. To provide more information about the castor stalk for using it better, the structure, microfibril angle (MFA, relative degree of crystallinity (%, and mechanical properties of castor fiber cell walls were investigated using X-ray diffraction (XRD and nanoindentation. The influence of chemical composition and MFA on the mechanical properties of fiber cell wall was studied as well. The cortex of castor stalks primarily contains long fibers, while the xylem of castor stalk, an excellent wood-type material, comprises most of the castor stalk (83.95% by weight; the pith of the stalk is composed of parenchyma cells. The average elastic modulus of fiber cell wall in lower, upper, and branch parts are 16.0 GPa, 18.6 GPa, and 13.2 GPa, respectively. The average hardness of fiber cell wall in lower, upper, and branch parts are 0.50 GPa, 0.54 GPa, and 0.43 GPa, respectively. As lignin content increases from 15.57% to 17.41% and MFA decreases from 21.3˚ to 15.4˚, the elastic modulus increases from 13.2 GPa to 18.6 GPa and the hardness increases from 0.43 GPa to 0.54 GPa. The mechanical properties, including the elastic modulus and the hardness of the fiber cell wall in the upper region of the castor stalk, are higher than those in the lower region, while the mechanical properties of the fiber cell wall in the branches are lower than those in either the upper or lower regions.

  14. Phosphorylation of bacterial-type phosphoenolpyruvate carboxylase by a Ca2+-dependent protein kinase suggests a link between Ca2+ signalling and anaplerotic pathway control in developing castor oil seeds.

    Science.gov (United States)

    Hill, Allyson T; Ying, Sheng; Plaxton, William C

    2014-02-15

    The aim of the present study was to characterize the native protein kinase [BTPC (bacterial-type phosphoenolpyruvate carboxylase)-K (BTPC Ser451 kinase)] that in vivo phosphorylates Ser451 of the BTPC subunits of an unusual Class-2 PEP (phosphoenolpyruvate) carboxylase hetero-octameric complex of developing COS (castor oil seeds). COS BTPC-K was highly purified by PEG fractionation and hydrophobic size-exclusion anion-exchange and affinity chromatographies. BTPC-K phosphorylated BTPC strictly at Ser451 (Km=1.0 μM; pH optimum=7.3), a conserved target residue occurring within an intrinsically disordered region, as well as the protein histone III-S (Km=1.7 μM), but not a COS plant-type PEP carboxylase or sucrose synthase or α-casein. Its activity was Ca2+- (K0.5=2.7 μM) and ATP- (Km=6.6 μM) dependent, and markedly inhibited by trifluoperazine, 3-phosphoglycerate and PEP, but insensitive to calmodulin or 14-3-3 proteins. BTPC-K exhibited a native molecular mass of ~63 kDa and was soluble rather than membrane-bound. Inactivation and reactivation occurred upon BTPC-K's incubation with GSSG and then DTT respectively. Ser451 phosphorylation by BTPC-K inhibited BTPC activity by ~50% when assayed under suboptimal conditions (pH 7.3, 1 mM PEP and 10 mM L-malate). Our collective results indicate a possible link between cytosolic Ca2+ signalling and anaplerotic flux control in developing COS.

  15. Synthesis of alpha-hydroxyphosphonic acids from Lesquerella oil

    Science.gov (United States)

    Lesquerella oil has been a substance of growing chemical interest, due to the ease with which it is produced and its similarity in structure to castor oil. The primary fatty acid in Lesquerella oil, lesquerolic acid, is very similar to the principal component of castor oil, ricinoleic acid, and may ...

  16. Poliuretanos elastoméricos obtenidos a partir de aceite de ricino y almidón de yuca original y modificado con anhídrido propiónico: síntesis, propiedades fisicoquímicas y fisicomecánicas Polyurethane elastomers from castor oil and chemically modified yucca starch: synthesis and physical-chemical, physical-mechanical and thermical properties

    Directory of Open Access Journals (Sweden)

    Manuel F. Valero

    2010-01-01

    Full Text Available Chemical modification of cassava starch was conducted through an acylation reaction by using pyridine and propionic anhydride to replace the functional groups of starch. Polyurethane elastomers were prepared using suspensions of the mixture obtained from castor oil and yucca starch that was modified by a propionic anhydride reaction. The suspensions were characterized by means of tests based on The Fourier Transform Infrared Spectroscopy and the Hydroxyl Index. The castor oil-AMP suspensions were used for the PU synthesis. The PUs were characterized by their physical-mechanical properties like tension- deformation and Shore A. hardness, thermal gravimetric analysis and swelling test. The density cross-linking of from swelling tests was determined by applying the Flory-Rehner equation.

  17. Effect of glyphosate on the castor plant Ricinus communis L

    Science.gov (United States)

    The presence of a toxin in the castor seed has been a major impediment to the reintroduction of castor as a domestic crop in the US. Because dehiscent forms of castor are invasive and castor seed remains viable for years under the right conditions, there is concern that if castor were widely cultiva...

  18. Influência das variáveis de processo na alcoólise enzimática de óleo de mamona Evaluation of the influence of process variables on enzimatic alcoholysis of castor oil

    Directory of Open Access Journals (Sweden)

    D. Oliveira

    2004-06-01

    intermediates to produce a number of oleochemicals and fuel alternatives (biodiesel. In this work, enzymatic alcoholysis of castor bean oil with an immobilized lipase (Lipozyme IM was accomplished using n-hexane as solvent. In order to maximize the esters production a Taguchi design was adopted varying temperature, water and enzyme concentrations in the reaction media and the oil:ethanol molar ratio. The reactions were monitorated by determining the glycerol production. An empirical model was built to evaluate the influence of the process variables on the conversion and afterwards the operating conditions that maximize esters production were established.

  19. CASTOR Calorimeter Installation Review at CMS

    CERN Multimedia

    CERN Video Productions

    2011-01-01

    This test is a part of CASTOR EDR process. The CASTOR phys-tech review held on 14 Jan 2011 and the subsequent EDR held on 17 Jun 2011, the CMS Management Board has endorsed a strategy in which CASTOR is removed during the 2011 Year-End Technical Stop, but is then refurbished, replacing a substantial fraction of the phototubes, so that it is ready for re-installation in the Technical Stop just before 2012 heavy-ion operation.

  20. CASTOR GSF packaging design criteria

    Energy Technology Data Exchange (ETDEWEB)

    Burnside, M.E.

    1996-08-06

    Encapsulated vitrified materials (Isotopic Heat Sources) are currently stored in the Pacific Northwest National Laboratories (PNNL) 324 Building located in the 300 Area. As part of the 324 Building transition program, the vitrified material, encapsulated in stainless steel canisters, must be removed. These canisters were originally intended to be used by the German government, but are no longer desired. As part of an agreement with the German government, the Germans are providing the U.S. Department of Energy (DOE) with six (6) CASTOR GSF and four (4) GNS-12 casks.The canisters will be transported onsite in CASTOR GSF and GNS-12 casks for interim storage until final disposition of the material is determined.

  1. Effect of copper on castor bean (Ricinus communis L.) growth

    Energy Technology Data Exchange (ETDEWEB)

    Chaves, Lucia Helena Garofalo; Cunha, Tassio Cavalcanti da Silva; Lima, Vinicius Mota; Cabral, Paulo Cesar Pinto; Barros Junior, Genival; Lacerda, Rogerio Dantas de [Universidade Federal de Campina Grande (UAEAg/UFCG), PB (Brazil). Unidade Academica de Engenharia Agricola

    2008-07-01

    Castor beans crop (Ricinus communis L.) is raising attention as an alternative crop for oil and biodiesel production. Despite the mineral fertilization is an important factor for increasing castor yield, few research has been made on this issue, mainly on the use de copper. In order to evaluate the effects of copper on growth of this plant an experiment was carried out in a greenhouse, in Campina Grande, Paraiba State, Brazil, from July to December 2007. The substrate for the pot plants was a 6 mm-sieved surface soil (Neossolo Quartzarenico). The experimental design was a completely randomized with three replications. The treatments were composed of five levels of Cu (0; 1; 2; 3 and 4 mg dm{sup -3}), which were applied at the time of planting. One plant of castor bean, cultivar BRS 188 - Paraguacu, was grown per pot after thinning and was irrigated whenever necessary. Data on plant height, number and length of leaves and stem diameter were measured at 21, 34, 77 and 103 days after planting. Copper levels used, in general, did not affect the plant height, stem diameter and leaf area, however they influenced the leaves and shoot biomass dry mass and the quadratic trend was the best to show the behavior of these. (author)

  2. An analysis of expressed sequence tags of developing castor endosperm using a full-length cDNA library

    Directory of Open Access Journals (Sweden)

    Wallis James G

    2007-07-01

    Full Text Available Abstract Background Castor seeds are a major source for ricinoleate, an important industrial raw material. Genomics studies of castor plant will provide critical information for understanding seed metabolism, for effectively engineering ricinoleate production in transgenic oilseeds, or for genetically improving castor plants by eliminating toxic and allergic proteins in seeds. Results Full-length cDNAs are useful resources in annotating genes and in providing functional analysis of genes and their products. We constructed a full-length cDNA library from developing castor endosperm, and obtained 4,720 ESTs from 5'-ends of the cDNA clones representing 1,908 unique sequences. The most abundant transcripts are genes encoding storage proteins, ricin, agglutinin and oleosins. Several other sequences are also very numerous, including two acidic triacylglycerol lipases, and the oleate hydroxylase (FAH12 gene that is responsible for ricinoleate biosynthesis. The role(s of the lipases in developing castor seeds are not clear, and co-expressing of a lipase and the FAH12 did not result in significant changes in hydroxy fatty acid accumulation in transgenic Arabidopsis seeds. Only one oleate desaturase (FAD2 gene was identified in our cDNA sequences. Sequence and functional analyses of the castor FAD2 were carried out since it had not been characterized previously. Overexpression of castor FAD2 in a FAH12-expressing Arabidopsis line resulted in decreased accumulation of hydroxy fatty acids in transgenic seeds. Conclusion Our results suggest that transcriptional regulation of FAD2 and FAH12 genes maybe one of the mechanisms that contribute to a high level of ricinoleate accumulation in castor endosperm. The full-length cDNA library will be used to search for additional genes that affect ricinoleate accumulation in seed oils. Our EST sequences will also be useful to annotate the castor genome, which whole sequence is being generated by shotgun sequencing at

  3. Sustainable and economic feasibility of castor bean oil production: a methodology to support investments decision taking; Viabilidade economica e sustentabilidade da producao de oleo de mamona: uma metodologia de suporte a decisao de investimentos

    Energy Technology Data Exchange (ETDEWEB)

    Maia, Glawther Lima [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Mestrado em Logistica e Pesquisa Operacional; Arruda, Joao Bosco Furtado [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil)

    2008-07-01

    The castor bean agribusiness is supported by a complex supply chain that involves several inputs, main products and other derived products. So, the control of production costs is a basic and extremely important activity for the optimization of management processes. Using literature research, case study and assessment of scenarios, the present work was developed with the objective of conceiving a methodology, based on theoretical and economical aspects, the formation of costs and the revenue forecasting, which is applied with the aid of a computational program for supporting decision taking in the castor bean small producers agribusiness. The results obtained in the case study show, for example, that about 40% of the projects are considered accepted under the criterion of recovering the invested capital in less than 2 years. Also, it reveals that 75% of the projects contribute for the increase of the producer income and about 63% of the projects provide enough profit to add value to the producer's properties. Finally, it is clear that the proposed methodology makes easier a better agricultural planning, allowing a better utilization of the raw material and it facilitates the analysis of diversifying other derived products and revenue sources in the castor bean chain. (author)

  4. Components of complex lipid biosynthetic pathways in developing castor (Ricinus communis) seeds identified by MudPIT analysis of enriched endoplasmic reticulum.

    Science.gov (United States)

    Brown, Adrian P; Kroon, Johan T M; Topping, Jennifer F; Robson, Joanne L; Simon, William J; Slabas, Antoni R

    2011-08-05

    Ricinoleic acid is a feedstock for nylon-11 (N11) synthesis which is currently obtained from castor (Ricinus communis) oil. Production of this fatty acid in a temperate oilseed crop is of great commercial interest, but the highest reported level in transgenic plant oils is 30%, below the 90% observed in castor and insufficient for commercial exploitation. To identify castor oil-biosynthetic enzymes and inform strategies to improve ricinoleic acid yields, we performed MudPIT analysis on endoplasmic reticulum (ER) purified from developing castor bean endosperm. Candidate enzymes for all steps of triacylglycerol synthesis were identified among 72 proteins in the data set related to complex-lipid metabolism. Previous reported proteomic data from oilseeds had not included any membrane-bound enzyme that might incorporate ricinoleic acid into oil. Analysis of enriched ER enabled determination of which protein isoforms for these enzymes were in developing castor seed. To complement this data, quantitative RT-PCR experiments with castor seed and leaf RNA were performed for orthologues of Arabidopsis oil-synthetic enzymes, determining which were highly expressed in the seed. These data provide important information for further manipulation of ricinoleic acid content in oilseeds and peptide data for future quantification strategies.

  5. Endoplasmic reticulum-located PDAT1-2 from castor bean enhances hydroxy fatty acid accumulation in transgenic plants.

    Science.gov (United States)

    Kim, Hyun Uk; Lee, Kyeong-Ryeol; Go, Young Sam; Jung, Jin Hee; Suh, Mi-Chung; Kim, Jong Bum

    2011-06-01

    Ricinoleic acid (12-hydroxy-octadeca-9-enoic acid) is a major unusual fatty acid in castor oil. This hydroxy fatty acid is useful in industrial materials. This unusual fatty acid accumulates in triacylglycerol (TAG) in the seeds of the castor bean (Ricinus communis L.), even though it is synthesized in phospholipids, which indicates that the castor plant has an editing enzyme, which functions as a phospholipid:diacylglycerol acyltransferase (PDAT) that is specific to ricinoleic acid. Transgenic plants containing fatty acid Δ12-hydroxylase encoded by the castor bean FAH12 gene produce a limited amount of hydroxy fatty acid, a maximum of around 17% of TAGs present in Arabidopsis seeds, and this unusual fatty acid remains in phospholipids of cell membranes in seeds. Identification of ricinoleate-specific PDAT from castor bean and manipulation of the phospholipid editing system in transgenic plants will enhance accumulation of the hydroxy fatty acid in transgenic seeds. The castor plant has three PDAT genes; PDAT1-1 and PDAT2 are homologs of PDAT, which are commonly found in plants; however, PDAT1-2 is newly grouped as a castor bean-specific gene. PDAT1-2 is expressed in developing seeds and localized in the endoplasmic reticulum, similar to FAH12, indicating its involvement in conversion of ricinoleic acid into TAG. PDAT1-2 significantly enhances accumulation of total hydroxy fatty acid up to 25%, with a significant increase in castor-like oil, 2-OH TAG, in seeds of transgenic Arabidopsis, which is an identification of the key gene for oilseed engineering in production of unusual fatty acids.

  6. Study on Emission and Performance of Diesel Engine Using Castor Biodiesel

    Directory of Open Access Journals (Sweden)

    Md. Saiful Islam

    2014-01-01

    performance of diesel engine using the castor biodiesel and its blend with diesel from 0% to 40% by volume. The acid-based catalyzed transesterification system was used to produce castor biodiesel and the highest yield of 82.5% was obtained under the optimized condition. The FTIR spectrum of castor biodiesel indicates the presence of C=O and C–O functional groups, which is due to the ester compound in biodiesel. The smoke emission test revealed that B40 (biodiesel blend with 40% biodiesel and 60% diesel had the least black smoke compared to the conventional diesel. Diesel engine performance test indicated that the specific fuel consumption of biodiesel blend was increased sufficiently when the blending ratio was optimized. Thus, the reduction in exhaust emissions and reduction in brake-specific fuel consumption made the blends of caster seed oil (B20 a suitable alternative fuel for diesel and could help in controlling air pollution.

  7. Exogenous glutamine increases lipid accumulation in developing seeds of castor bean (Ricinus communis L. cultured in vitro

    Directory of Open Access Journals (Sweden)

    Zhang Yang

    2015-01-01

    Full Text Available This report describes biomass production and compositional changes of developing castor seeds in response to change in the nitrogen resource (glutamine of the medium. During the early developmental period (24-36 days after pollination, oil was found to initially accumulate in the developing seeds. Carbohydrates and oil were inversely related after glutamine provision (35 mM, in the culture medium. [U-14C] sucrose labeling was used to investigate the effect of metabolic fluxes among different storage materials. Addition of glutamine led to a 7% increase of labeling in lipids and an inverse decrease of labeling in carbohydrates. It was postulated that changes in the glutamine concentration in the medium are likely to influence the partitioning of resources between the various storage products, especially carbohydrates and oil. These observations will contribute to a better understanding of assimilate partitioning in developing castor seeds and the development of molecular strategies to improve castor bean seed quality and plant breeding studies.

  8. Non-destructive determination of photosynthetic pigments in the leaves of castor oil plants=Determinação não destrutiva de pigmentos da fotossíntese em folhas de mamoneira

    Directory of Open Access Journals (Sweden)

    Fabíola Vanessa de França

    2012-07-01

    Full Text Available The aim of the present work was to determine the relationship between photosynthetic pigments extracted in dimethyl sulfoxide (DMSO and readings obtained by the portable chlorophyll meter, ClorofiLOG® 1030, to generate mathematical models that are able to report the contents of chlorophyll and carotenoids in the leaves of the castor oil plant. This work was conducted at Embrapa Cotton, located in the city of Campina Grande, state of Paraíba, Brazil, in October 2010. For the indirect analysis, portable equipment was used to read leaf discs of different shades of green. The chlorophyll in these discs was then determined using a classical method: 5 mL of DMSO was added, the samples were incubated in a water bath at 70ºC for 30 minutes, and a 3 mL aliquot was removed for spectrophotometric measurements at 470, 646 and 663 nm. The data were subjected to analysis of variance and regression analyses in which the readings obtained using the portable chlorophyll meter were the dependent variable and the photosynthetic pigments that were determined by the classical method were the independent variable. The results indicated that, with the exception of chlorophyll b, the ClorofiLOG® 1030 portable chlorophyll meter estimated the concentration of photosynthetic pigments with high precision, thus saving time and the chemical reagents that are typically used in conventional procedures.Objetivou-se com o presente trabalho, estabelecer a relação entre os pigmentos fotossintéticos extraídos em DMSO e as leituras obtidas no clorofilômetro portátil ClorofiLOG® 1030, gerando modelos matemáticos capazes de predizer os teores de clorofila e de carotenóides em folhas de mamoneira. O trabalho foi conduzido na Embrapa Algodão, situada em Campina Grande, Estado da Paraíba, em outubro de 2010. Para a análise indireta, foi utilizado um equipamento portátil, sendo realizada a leitura em discos foliares com diferentes tonalidades de verde, sendo feita, nesses

  9. Resposta tecidual a implantes de discos de poliuretana de mamona nas formas pré-moldada ou biomassa moldada Tissue reaction to premolded or molded biomass disks of polyurethanes containing castor oil

    Directory of Open Access Journals (Sweden)

    Samanta Aires Celeste

    2010-12-01

    Full Text Available O trabalho teve por objetivo avaliar a resposta tecidual à implantação de discos de poliuretana derivada do óleo de mamona confeccionados de duas formas distintas, na forma pré-moldada fornecida pela indústria e em biomassa moldada no momento da aplicação, de forma a observar se haveria algum tipo de reação local tardia associada à possível continuidade do processo de endurecimento final do biomaterial. Foram utilizados 20 ratos, linhagem Wistar, fêmeas, com peso de 300-350g, nos quais foi inserido o disco pré-moldado no tecido subcutâneo do flanco direito e o de biomassa moldada no flanco esquerdo. Ambos os discos tinham 0,8cm de diâmetro por 0,5cm de espessura. Para o procedimento histológico, cinco ratos foram submetidos à eutanásia aos 3, 7, 15 e 30 dias de pós-cirúrgico. Os implantes e tecidos circundantes foram colhidos, processados e corados pela técnica de hematoxilina-eosina. Foi observada inicialmente uma reação inflamatória moderada, composta especialmente por células polimorfonucleares e macrófagos. Os linfócitos variaram de ausentes a discretos. A reação inflamatória diminui de intensidade à medida que se intensificou a formação de tecido conjuntivo fibroso ao redor dos implantes, porém sem modificação dos números de macrófagos. Sendo assim, conclui-se que ambos os discos de poliuretana induzem uma reação inflamatória similar, que varia de moderada a discreta na dependência do momento de avaliação.The aim of this study was to histologically evaluate the tissue reaction to implantation of polyurethane disks containing castor oil produced in premolded form, supplied commercially, and biomass molded at the moment of application; since a late tissue reaction may occur during the total hardening process of the biomaterial. Twenty female Wistar rats, about 3 months of age, weighing 300-350g, and polyurethane disks 0.8cm in diameter and 0.5cm in thickness were used. The premolded disk was

  10. Poliuretana de mamona (Ricinus communis para desvio da crista tibial no cão Polyurethane resins derived from castor oil (Ricinus communis for tibial crest deviation in dogs

    Directory of Open Access Journals (Sweden)

    Patricia Popak Maria

    2004-06-01

    Full Text Available A luxação medial de patela é uma das principais afecções ortopédicas que afetam cães de raças de pequeno porte. Tendo como princípio que o desvio da crista tibial é uma das alterações anatômicas encontradas, este estudo objetivou avaliar o efeito da poliuretana de mamona (Ricinus communis aplicada em defeitos produzidos experimentalmente na porção proximal medial da tíbia de cães normais em fase de crescimento. Para isto, foram utilizados 12 cães subdivididos aleatoriamente em 3 grupos de igual número, com mesmo tratamento, mas com análise histopatológica aos 30 (GI, 60 (GII e 90 (GIII dias. O estudo constou de avaliações clínica, radiográfica, macroscópica, histopatológica, tomográfica e análise estatística. Avaliação clínica demonstrou não haver rejeição do implante. A análise radiográfica revelou intensa reação periosteal e neoformações ósseas no local da implantação. Macroscopicamente observou-se espessamento da crista tibial, neoformações ósseas e desvio lateral da crista. Os achados à microscopia óptica revelaram presença de tecido conjuntivo fibroso ao redor da poliuretana, ausência de proliferação óssea em direção ao implante e proliferação de periósteo na face medial das tíbias. A tomografia computadorizada revelou desvio lateral da crista em 11 animais e estes desvios foram estatisticamente significantes em nível de 5% por meio do teste t pareado.Medial patellar luxation is one of the most common orthopedic problems in small breeds of dogs and tibial crest deviation is a frequent accompaining anatomical abnormality. For that reason, the purpose of this study was to evaluate the behavior of castor oil derived polyurethane implants when apllied to experimental defects created on the medial side of the proximal tibia of normal puppies. Twelve dogs were randomly divided in 3 groups of 4 animals and were submitted to the same treatment. Histopathological study was performed

  11. 蓖麻油基聚氨酯灌封胶的固化行为研究(Ⅰ)固化过程中的流变行为和凝胶时间%Studies on Curing Behavior of Castor oil-based Polyurethane(Ⅰ)Rheological Behavior and Gelation Time during Curing

    Institute of Scientific and Technical Information of China (English)

    关键; 罗祥林; 乐以伦

    2001-01-01

    The castor oil-based polyurethane potting materials were synthesized from castor oil,4,4-diphenylmethane diisocyanate (MDI),trimethylolpropane (TMP) and 1,2-propanediol.Rheological behavior and gelation time of the potting materials during curing were studied.The experimental results showed that the prepaved potting material had low initial viscosity,being no more than 1600 mPa*s at 20℃,and its operation time at 20℃、40℃ and 60℃ was 38,20 and 10min respectively;the increase of 1,2-propanediol content could decrease the curing rate of the material,which was only 5min at 120℃.%以蓖麻油,4,4’-二苯基甲烷二异氰酸酯(MDI)、三羟甲基丙烷(TMP)与1,2-丙二醇为原料合成了蓖麻油基聚氨酯灌封胶,研究了灌封胶的固化流变行为和凝胶化时间。结果表明,该灌封胶初始粘度低,在20℃时不超过1600mPa*s;在20℃、40℃和60℃下的可操作时间分别为38、20和10min;增加1,2-丙二醇用量可降低胶液的固化速度,120℃固化时的凝胶时间仅为5min。

  12. Identification and expression analysis of castor bean (Ricinus communis) genes encoding enzymes from the triacylglycerol biosynthesis pathway.

    Science.gov (United States)

    Cagliari, Alexandro; Margis-Pinheiro, Márcia; Loss, Guilherme; Mastroberti, Alexandra Antunes; de Araujo Mariath, Jorge Ernesto; Margis, Rogério

    2010-11-01

    Castor bean (Ricinus communis) oil contains ricinoleic acid-rich triacylglycerols (TAGs). As a result of its physical and chemical properties, castor oil and its derivatives are used for numerous bio-based products. In this study, we survey the Castor Bean Genome Database to report the identification of TAG biosynthesis genes. A set of 26 genes encoding six distinct classes of enzymes involved in TAGs biosynthesis were identified. In silico characterization and sequence analysis allowed the identification of plastidic isoforms of glycerol-3-phosphate acyltransferase and lysophosphatidate acyltransferase enzyme families, involved in the prokaryotic lipid biosynthesis pathway, that form a cluster apart from the cytoplasmic isoforms, involved in the eukaryotic pathway. In addition, two distinct membrane bound diacylglycerol acyltransferase enzymes were identified. Quantitative expression pattern analyses demonstrated variations in gene expressions during castor seed development. A tendency of maximum expression level at the middle of seed development was observed. Our results represent snapshots of global transcriptional activities of genes encompassing six enzyme families involved in castor bean TAG biosynthesis that are present during seed development. These genes represent potential targets for biotechnological approaches to produce nutritionally and industrially desirable oils.

  13. CASTOR end-to-end monitoring

    CERN Document Server

    Rekatsinas, T; Pokorski, W; Ponce, S; Rabaçal, B; Waldron, D; Wojcieszuk, J

    2010-01-01

    With the start of Large Hadron Collider approaching, storage and management of raw event data, as well as reconstruction and analysis data, is of crucial importance for the researchers. The CERN Advanced STORage system (CASTOR) is a hierarchical system developed at CERN, used to store physics production files and user files. CASTOR, as one of the essential software tools used by the LHC experiments, has to provide reliable services for storing and managing data. Monitoring of this complicated system is mandatory in order to assure its stable operation and improve its future performance. This paper presents the new monitoring system of CASTOR which provides operation and user request specific metrics. This system is build around a dedicated, optimized database schema. The schema is populated by PL/SQL procedures, which process a stream of incoming raw metadata from different CASTOR components, initially collected by the Distributed Logging Facility (DLF). A web interface has been developed for the visualizatio...

  14. Exploiting EST databases for the development and characterization of EST-SSR markers in castor bean (Ricinus communis L.

    Directory of Open Access Journals (Sweden)

    Yang Jun-Bo

    2010-12-01

    Full Text Available Abstract Background The castor bean (Ricinus communis L., a monotypic species in the spurge family (Euphorbiaceae, 2n = 20, is an important non-edible oilseed crop widely cultivated in tropical, sub-tropical and temperate countries for its high economic value. Because of the high level of ricinoleic acid (over 85% in its seed oil, the castor bean seed derivatives are often used in aviation oil, lubricants, nylon, dyes, inks, soaps, adhesive and biodiesel. Due to lack of efficient molecular markers, little is known about the population genetic diversity and the genetic relationships among castor bean germplasm. Efficient and robust molecular markers are increasingly needed for breeding and improving varieties in castor bean. The advent of modern genomics has produced large amounts of publicly available DNA sequence data. In particular, expressed sequence tags (ESTs provide valuable resources to develop gene-associated SSR markers. Results In total, 18,928 publicly available non-redundant castor bean EST sequences, representing approximately 17.03 Mb, were evaluated and 7732 SSR sites in 5,122 ESTs were identified by data mining. Castor bean exhibited considerably high frequency of EST-SSRs. We developed and characterized 118 polymorphic EST-SSR markers from 379 primer pairs flanking repeats by screening 24 castor bean samples collected from different countries. A total of 350 alleles were identified from 118 polymorphic SSR loci, ranging from 2-6 per locus (A with an average of 2.97. The EST-SSR markers developed displayed moderate gene diversity (He with an average of 0.41. Genetic relationships among 24 germplasms were investigated using the genotypes of 350 alleles, showing geographic pattern of genotypes across genetic diversity centers of castor bean. Conclusion Castor bean EST sequences exhibited considerably high frequency of SSR sites, and were rich resources for developing EST-SSR markers. These EST-SSR markers would be particularly

  15. Transcriptome-wide identification and characterization of microRNAs from castor bean (Ricinus communis L..

    Directory of Open Access Journals (Sweden)

    Wei Xu

    Full Text Available BACKGROUND: MicroRNAs (miRNAs are endogenously encoded small RNAs that post-transcriptionally regulate gene expression and play essential roles in numerous developmental and physiological processes. Currently, little information on the transcriptome and tissue-specific expression of miRNAs is available in the model non-edible oilseed crop castor bean (Ricinus communis L., one of the most important non-edible oilseed crops cultivated worldwide. Recent advances in sequencing technologies have allowed the identification of conserved and novel miRNAs in many plant species. Here, we used high-throughput sequencing technologies to identify and characterize the miRNAs in castor bean. RESULTS: Five small RNA libraries were constructed for deep sequencing from root tips, leaves, developing seeds (at the initial stage, seed1; and at the fast oil accumulation stage, seed2 and endosperms in castor bean. High-throughput sequencing generated a large number of sequence reads of small RNAs in this study. In total, 86 conserved miRNAs were identified, including 63 known and 23 newly identified. Sixteen miRNA isoform variants in length were found from the conserved miRNAs of castor bean. MiRNAs displayed diverse organ-specific expression levels among five libraries. Combined with criteria for miRNA annotation and a RT-PCR approach, 72 novel miRNAs and their potential precursors were annotated and 20 miRNAs newly identified were validated. In addition, new target candidates for miRNAs newly identified in this study were proposed. CONCLUSIONS: The current study presents the first high-throughput small RNA sequencing study performed in castor bean to identify its miRNA population. It characterizes and increases the number of miRNAs and their isoforms identified in castor bean. The miRNA expression analysis provides a foundation for understanding castor bean miRNA organ-specific expression patterns. The present study offers an expanded picture of miRNAs for castor

  16. Castor industry development:from cultivation to product exploitation%蓖麻产业发展:从种植到利用

    Institute of Scientific and Technical Information of China (English)

    孙振钧; 吕丽媛; 伍玉鹏

    2012-01-01

    蓖麻作为世界十大油料作物之一,具有很高的开发利用价值。本文从产业发展的角度,综述了蓖麻种植的历史和高产栽培技术现状,分析了蓖麻利用特别是蓖麻基生物燃油及蓖麻深加工产品的研发现状及发展趋势。论述了蓖麻的耐盐性及蓖麻栽培对盐碱地的修复作用,并结合我国边际土地的情况,分析了我国种植蓖麻的潜力。据此提出我国蓖麻研究及产业发展的重点为:蓖麻适宜种植区调查与区划、种质资源调查与创新、低质非耕土壤蓖麻高产栽培技术研究、蓖麻基生物燃油制备工艺研究、蓖麻综合利用研究和蓖麻产业可持续发展及保障系统研究。%As one of the world's ten largest oil crops,castor has broad utilization prospects based on its high economic value.This paper analyzes the current situation of high-yielding castor cultivation technology,summarizes the comprehensive utilization of castor and describes the development of castor biodiesel fuel.Castor salt resistance and the remediation of saline-alkali soil by castor cultivationis are also discussed,as well as the potential of China's cultivation of castor.In this paper,recommendation for castor research and industrial development were also proposed,including the castor surrey and zoning in suitable planting area,the investigation and innovation of germplasm resources,high-yielding cultivation technology of castor in low quality and non-farming soil,preparation process of castor biodiesel fuel,comprehensive utilization research of castor,sustainable development and security system of castor industry.

  17. Morphology of autogenous bone graft and castor oil polyurethane in the infraorbital rim of rabbits: a comparative study Estudo morfológico comparativo do enxerto ósseo autógeno e polímero de mamona em rebordo infra-orbitário de coelhos

    Directory of Open Access Journals (Sweden)

    José Carlos Garcia de Mendonça

    2006-10-01

    Full Text Available PURPOSE: Morphological study comparing castor oil polyurethane and autogenous bone graft to repair bone defect in zygomatic bone of rabbits. METHODS: Twenty-four adult, male New Zealand rabbits were randomly distributed between two groups of twelve. Bone defects of 5mm in diameter were cut through the zygomatic bone and filled with polyurethane discs in the experimental group or autogenous bone harvested from the tibia in the control group. Animals were sacrificed after 30, 60 or 90 days, and the zygomatic bones were macro- and microscopically analyzed. Student's, Fisher's, chi-squared and McNemar's tests were used for statistical analysis. RESULTS: Both the castor oil polyurethane and the autograft adapted well to the defect, with no need for fixation. Fibrous connective tissue encapsulated the polyurethane, but no inflammation or giant cell reaction was observed. Acidophilic and basophilic areas were observed inside the micropores of the polyurethane, suggesting cell nuclei. After 90 days, bone repair with a lamellar pattern of organization was observed in the control group. CONCLUSION: The castor oil polyurethane was biocompatible and did not cause inflammation. It may be considered an alternative to fill bone defects.OBJETIVO: Estudo morfológico comparativo do implante de poliuretana de mamona e enxerto ósseo autógeno em defeito ósseo padrão em osso zigomático de coelhos. MÉTODOS: Vinte e quatro coelhos Nova Zelândia, machos, adultos, foram distribuídos aleatoriamente em dois grupos de 12. Defeitos de 5mm de diâmetro, perenes, foram confeccionados em osso zigomático e preenchidos com discos pré-fabricados de poliuretana no grupo experimento ou osso autógeno extraído da tíbia no grupo controle. Os animais foram sacrificados após 30, 60 e 90 dias e as peças anatômicas foram avaliadas macro e microscopicamente. Foram utilizados os testes de Student, Fisher,qui-quadrado e McNemar para a análise estatística dos resultados

  18. Use of castor oil polyurethane in an alternative technique for medial patella surgical correction in dogs Utilização do poliuretano de mamona em técnica alternativa de correção cirúrgica da luxação medial de patela em cães

    Directory of Open Access Journals (Sweden)

    Fabrício de Oliveira Frazilio

    2006-01-01

    Full Text Available PURPOSE: Comparative morphologic study of utilization of castor oil polymer in dogs joints, as an alternative technique to autogenous graft, in surgical correction of medial patella luxation. METHODS:Twelve adult dogs, of both sexes, were randomly allocated to two different groups of six animals each. Group I (biopolymer consisted of the deepening of the right femoral troclea, with the implantation of the biopolymer prothesis, and compared to group II (control which consisted of the conventional trocleoplastia technique with wedged cut of the left femoral troclea. The dogs were sacrified after 30 or 90 days and the anathomic peaces were analyzed macro and microscopically. Qui square and Wilcoxon tests were used for the statistic analyses of the results, considering probability of 5%. RESULTS: It was not observed bony integration on the castor oil polymer group. There was resorption of the graft along experimental period and absence of inflammatory cells in the studied periods. CONCLUSION: Castor oil polymer assisted cicatrisation process, was biocompatible without inflammation, and it can be used in joints as an alternative for bony filling.OBJETIVO: Estudo morfológico do implante da prótese de polímero de mamona em articulações de cães, como técnica alternativa ao enxerto ósseo autógeno na correção cirúrgica da luxação medial de patela. MÉTODOS: Doze cães adultos, de ambos os sexos, foram distribuídos aleatoriamente em dois grupos de 6 animais. No grupo I (poliuretano foi feito o aprofundamento da tróclea femoral direita com prótese de polímero de mamona, que foi comparado com o grupo II (controle sendo feita a trocleoplastia por ressecção em cunha da tróclea femoral esquerda. Os animais foram sacrificados após 30 e 90 dias e as peças anatômicas foram avaliadas macro e microscopicamente. O teste do quiquadrado e o teste não-paramétrico de Wilcoxon foram utilizados para a análise estatística dos resultados. Fixou

  19. Differential Contribution of Malic Enzymes during Soybean and Castor Seeds Maturation.

    Directory of Open Access Journals (Sweden)

    Mariel Claudia Gerrard Wheeler

    Full Text Available Malic enzymes (ME catalyze the decarboxylation of malate generating pyruvate, CO2 and NADH or NADPH. In some organisms it has been established that ME is involved in lipids biosynthesis supplying carbon skeletons and reducing power. In this work we studied the MEs of soybean and castor, metabolically different oilseeds. The comparison of enzymatic activities, transcript profiles and organic acid contents suggest different metabolic strategies operating in soybean embryo and castor endosperm in order to generate precursors for lipid biosynthesis. In castor, the malate accumulation pattern agrees with a central role of this metabolite in the provision of carbon to plastids, where the biosynthesis of fatty acids occurs. In this regard, the genome of castor possesses a single gene encoding a putative plastidic NADP-ME, whose expression level is high when lipid deposition is active. On the other hand, NAD-ME showed an important contribution to the maturation of soybean embryos, perhaps driving the carbon relocation from mitochondria to plastids to support the fatty acids synthesis in the last stages of seed filling. These findings provide new insights into intermediary metabolism in oilseeds and provide new biotechnological targets to improve oil yields.

  20. Organic matter and soil water content influence on BRS 188 castor bean growth

    Energy Technology Data Exchange (ETDEWEB)

    Lacerda, Rogerio Dantas de; Araujo, Ester Luiz de; Nascimento, Elka Costa Santos; Barros Junior, Genival [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Guerra, Hugo O. Carvallo; Chaves, Lucia Helena G. [Universidade Federal de Campina Grande (UAEAg/UFCG), PB (Brazil). Unidade Academica de Engenharia Agricola

    2008-07-01

    The castor bean culture has been highlighted due to the several applications of its oil, which constitutes one of the best row materials for biodiesel manufacturing, and the base for several other industrial products. The objective of the present work was to study the effect of different soil water and soil organic matter on the castor bean growth. The experiment was conducted from April to August 2006 under greenhouse conditions using a randomized block 2x4 factorial design with two soil organic mater content (5.0 g.kg{sup -1} e 25.0 g.kg{sup -1}), four levels of available water (100, 90, 80 e 70% ) and three replicates. For this, 24 plastic containers, 75 kg capacity, were used on which was grown one plant 120 days after the seedling. At regular intervals the plant height was measured and the results analyzed statistically. For the qualitative treatments (with and without organic matter) the treatment means were compared through the Tukey test. For the quantitative ones (water levels) were used regressions. The castor bean cultivar height was significantly influenced by the organic matter content only after 80 days. Castor bean height increased significantly with the soil water content after 40 days of growing. (author)

  1. Apis mellifera pollination improves agronomic productivity of anemophilous castor bean (Ricinus communis).

    Science.gov (United States)

    Rizzardo, Rômulo A G; Milfont, Marcelo O; Silva, Eva M S da; Freitas, Breno M

    2012-12-01

    Castor bean (Ricinus communis L.) is cultivated mainly for biodiesel production because of its oil-rich seeds; it is assumed to be an anemophylous species. But pollination deficit can lead to low productivity often attributed to other reasons. In this paper, we investigated pollination requirements, pollination mechanism, occurrence of pollination deficit, and the role of biotic pollinators in a large commercial plantation of castor bean. Our results show that R. communis bears a mixed breeding system favoring selfing by geitonogamy, although the wind promotes mostly outcrossing. We also found that the honey bee (Apis mellifera L.) foraging on castor bean can both transfer pollen from male to female flowers within the same raceme and boost the release of airborne pollen by male flowers. Both situations increase geitonogamy rates, raising significantly fruit set and seed yield. This is the first report of an animal foraging activity increasing seed yield in an anemophilous and geitonogamous crop and elucidates the role of biotic pollinators in castor bean reproduction.

  2. Differential Contribution of Malic Enzymes during Soybean and Castor Seeds Maturation

    Science.gov (United States)

    Righini, Silvana; Badia, Mariana Beatriz; Andreo, Carlos Santiago; Drincovich, María Fabiana; Saigo, Mariana

    2016-01-01

    Malic enzymes (ME) catalyze the decarboxylation of malate generating pyruvate, CO2 and NADH or NADPH. In some organisms it has been established that ME is involved in lipids biosynthesis supplying carbon skeletons and reducing power. In this work we studied the MEs of soybean and castor, metabolically different oilseeds. The comparison of enzymatic activities, transcript profiles and organic acid contents suggest different metabolic strategies operating in soybean embryo and castor endosperm in order to generate precursors for lipid biosynthesis. In castor, the malate accumulation pattern agrees with a central role of this metabolite in the provision of carbon to plastids, where the biosynthesis of fatty acids occurs. In this regard, the genome of castor possesses a single gene encoding a putative plastidic NADP-ME, whose expression level is high when lipid deposition is active. On the other hand, NAD-ME showed an important contribution to the maturation of soybean embryos, perhaps driving the carbon relocation from mitochondria to plastids to support the fatty acids synthesis in the last stages of seed filling. These findings provide new insights into intermediary metabolism in oilseeds and provide new biotechnological targets to improve oil yields. PMID:27347875

  3. Sources of nitrogenous fertilizers and their effects in the growth of the castor bean plant

    Directory of Open Access Journals (Sweden)

    Joelma Sales dos Santos

    2008-12-01

    Full Text Available The main goal of this research was to verify and quantify the effects of doses (equivalent to nitrogen of fertilizers, manure from corral, residential sewage sludge, castor oil cake and urea, in the early growth of castor beans, BRS Nordestina in a greenhouse. The experiment was conducted in the Embrapa, at county of Campina Grande, state of Paraiba, Brazil, and it was used an experimental design of randomized with three replicates and 13 treatments, with a factorial 4 x 3 + 1, which factors were: types of organic fertilizers (manure from corral and manure, biosolids and castor bean cake and urea at rates of (85,170 and 255 kg N ha-¹, plus an additional treatment, which was the absolute witness without the fertilization. All the treatments witness received a mineral supplement P and K, at doses of 80 kg of P2O2 and K2O, applied in the foundation, with triple superphosphate and potassium chloride. Among the fertilizers, which further promoted the initial growth of castor beans was the pie of Euphorbia that, in addition to nutrients, especially of nitrogen, have much fiber, more than 35%, constituting themselves, thus a factor in improving soil physical environment.

  4. Painéis de partículas à base de bagaço de cana e resina de mamona – produção e propriedades - doi: 10.4025/actascitechnol.v33i4.9615 Particleboards of sugar cane bagasse and castor oil resin – production and properties

    Directory of Open Access Journals (Sweden)

    Holmer Savastano Junior

    2011-09-01

    Full Text Available Este trabalho apresenta um estudo do potencial de utilização do bagaço de cana-de-açúcar para fabricação de painéis de partículas aglomeradas utilizando resina poliuretana à base de óleo de mamona. A qualidade dos produtos foi avaliada com base nas prescrições do documento normativo NBR 14810 (ABNT, 2006b, com a determinação da densidade, do inchamento, da absorção, do Módulo de Elasticidade (MOE e Módulo de Ruptura (MOR na flexão estática. Após análise dos resultados, os painéis avaliados apresentaram densidade média de 0,93 g cm-3, MOR e MOE médios 24,4 e 2432 MPa, sendo classificados, segundo os indicativos da norma ANSI A208.1 (1993, como material de alta densidade, recomendado para uso industrial. A resina à base de óleo de mamona mostrou-se eficiente como matriz polimérica para fabricação de compósito à base de bagaço de cana-de-açúcar.Here we present a study of the potential use of agro-industry residues (sugar cane bagasse in order to add value to these materials through the manufacture of particle boards and evaluation of the physical and mechanical performance. For this, we used polyurethane monocomponent and bicomponent resin based on castor oil. The quality of the products was evaluated based on the requirements of normative documents NBR 14810 (ABNT, 2006b, with determination of the density, swelling, absorption, elasticity modulus (MOE and strength in static bending (MOR. After analyzing the results, the panels presented average density 0.93 g cm-3, average MOR and MOE 24.4 and 2432 MPa, respectively, being classified according to the indicative of the ANSI A208.1 (1993, as material of high density, recommended for industrial use. The resin based on castor oil was efficient as a matrix polymer for making composites based on sugar cane bagasse.

  5. Genome-Wide Identification, Evolutionary Analysis, and Stress Responses of the GRAS Gene Family in Castor Beans

    Directory of Open Access Journals (Sweden)

    Wei Xu

    2016-06-01

    Full Text Available Plant-specific GRAS transcription factors play important roles in regulating growth, development, and stress responses. Castor beans (Ricinus communis are important non-edible oilseed plants, cultivated worldwide for its seed oils and its adaptability to growth conditions. In this study, we identified and characterized a total of 48 GRAS genes based on the castor bean genome. Combined with phylogenetic analysis, the castor bean GRAS members were divided into 13 distinct groups. Functional divergence analysis revealed the presence of mostly Type-I functional divergence. The gene structures and conserved motifs, both within and outside the GRAS domain, were characterized. Gene expression analysis, performed in various tissues and under a range of abiotic stress conditions, uncovered the potential functions of GRAS members in regulating plant growth development and stress responses. The results obtained from this study provide valuable information toward understanding the potential molecular mechanisms of GRAS proteins in castor beans. These findings also serve as a resource for identifying the genes that allow castor beans to grow in stressful conditions and to enable further breeding and genetic improvements in agriculture.

  6. Repertoire of SSRs in the Castor Bean Genome and Their Utilization in Genetic Diversity Analysis in Jatropha curcas

    Directory of Open Access Journals (Sweden)

    Arti Sharma

    2011-01-01

    Full Text Available Castor bean and Jatropha contain seed oil of industrial importance, share taxonomical and biochemical similarities, which can be explored for identifying SSRs in the whole genome sequence of castor bean and utilized in Jatropha curcas. Whole genome analysis of castor bean identified 5,80,986 SSRs with a frequency of 1 per 680 bp. Genomic distribution of SSRs revealed that 27% were present in the non-genic region whereas 73% were also present in the putative genic regions with 26% in 5′UTRs, 25% in introns, 16% in 3′UTRs and 6% in the exons. Dinucleotide repeats were more frequent in introns, 5′UTRs and 3′UTRs whereas trinucleotide repeats were predominant in the exons. The transferability of randomly selected 302 SSRs, from castor bean to 49 J. curcas genotypes and 8 Jatropha species other than J. curcas, showed that 211 (~70% amplified on Jatropha out of which 7.58% showed polymorphisms in J. curcas genotypes and 12.32% in Jatropha species. The higher rate of transferability of SSR markers from castor bean to Jatropha coupled with a good level of PIC (polymorphic information content value (0.2 in J. curcas genotypes and 0.6 in Jatropha species suggested that SSRs would be useful in germplasm analysis, linkage mapping, diversity studies and phylogenetic relationships, and so forth, in J. curcas as well as other Jatropha species.

  7. Repertoire of SSRs in the Castor Bean Genome and Their Utilization in Genetic Diversity Analysis in Jatropha curcas.

    Science.gov (United States)

    Sharma, Arti; Chauhan, Rajinder Singh

    2011-01-01

    Castor bean and Jatropha contain seed oil of industrial importance, share taxonomical and biochemical similarities, which can be explored for identifying SSRs in the whole genome sequence of castor bean and utilized in Jatropha curcas. Whole genome analysis of castor bean identified 5,80,986 SSRs with a frequency of 1 per 680 bp. Genomic distribution of SSRs revealed that 27% were present in the non-genic region whereas 73% were also present in the putative genic regions with 26% in 5'UTRs, 25% in introns, 16% in 3'UTRs and 6% in the exons. Dinucleotide repeats were more frequent in introns, 5'UTRs and 3'UTRs whereas trinucleotide repeats were predominant in the exons. The transferability of randomly selected 302 SSRs, from castor bean to 49 J. curcas genotypes and 8 Jatropha species other than J. curcas, showed that 211 (∼70%) amplified on Jatropha out of which 7.58% showed polymorphisms in J. curcas genotypes and 12.32% in Jatropha species. The higher rate of transferability of SSR markers from castor bean to Jatropha coupled with a good level of PIC (polymorphic information content) value (0.2 in J. curcas genotypes and 0.6 in Jatropha species) suggested that SSRs would be useful in germplasm analysis, linkage mapping, diversity studies and phylogenetic relationships, and so forth, in J. curcas as well as other Jatropha species.

  8. Accumulation of arsenic and nutrients by castor bean plants grown on an As-enriched nutrient solution.

    Science.gov (United States)

    Melo, E E C; Costa, E T S; Guilherme, L R G; Faquin, V; Nascimento, C W A

    2009-08-30

    Phytoextraction is a remediation technique that consists in using plants to remove contaminants from soils and water. This study evaluated arsenic (As) accumulation in Castor bean (Ricinus communis cv. Guarany) grown in nutrient solution in order to assess its phytoextraction ability. Castor bean plants were grown under greenhouse conditions in pots containing a nutrient solution amended with increasing doses of As (0, 10, 50, 100, 250, 500 and 5000 microg L(-1)) in a completely randomized design with four replications. Shoot and roots dry matter production as well as arsenic and nutrient tissue concentrations were measured at the end of the experiment. The results showed that increasing As concentration in nutrient solution caused a decrease in shoot and root biomass but did not result in severe toxicity symptoms in castor bean growing under a range of As concentration from 0 to 5000 microg L(-1). The As doses tested did not affect the accumulation of nutrients by castor bean. Although castor bean did not pose characteristics of a plant suitable for commercial phytoextraction, it could be useful for revegetation of As-contaminated areas while providing an additional income by oil production.

  9. Genome-Wide Identification, Evolutionary Analysis, and Stress Responses of the GRAS Gene Family in Castor Beans

    Science.gov (United States)

    Xu, Wei; Chen, Zexi; Ahmed, Naeem; Han, Bing; Cui, Qinghua; Liu, Aizhong

    2016-01-01

    Plant-specific GRAS transcription factors play important roles in regulating growth, development, and stress responses. Castor beans (Ricinus communis) are important non-edible oilseed plants, cultivated worldwide for its seed oils and its adaptability to growth conditions. In this study, we identified and characterized a total of 48 GRAS genes based on the castor bean genome. Combined with phylogenetic analysis, the castor bean GRAS members were divided into 13 distinct groups. Functional divergence analysis revealed the presence of mostly Type-I functional divergence. The gene structures and conserved motifs, both within and outside the GRAS domain, were characterized. Gene expression analysis, performed in various tissues and under a range of abiotic stress conditions, uncovered the potential functions of GRAS members in regulating plant growth development and stress responses. The results obtained from this study provide valuable information toward understanding the potential molecular mechanisms of GRAS proteins in castor beans. These findings also serve as a resource for identifying the genes that allow castor beans to grow in stressful conditions and to enable further breeding and genetic improvements in agriculture. PMID:27347937

  10. Tape write-efficiency improvements in CASTOR

    CERN Document Server

    Murray, S; Cancio, G; Cano, E; Kotlyar, V; Lo Presti, G; Lo Re, G; Ponce, S

    2012-01-01

    The CERN Advanced STORage manager (CASTOR) is used to archive to tape the physics data of past and present physics experiments. For reasons of physical storage space, all of the tape resident data in CASTOR are repacked onto higher density tapes approximately every two years. Improving the performance of writing files smaller than 2GB to tape is essential in order to keep the time needed to repack all of the tape resident data within a period of no more than 1 year. This paper reports on the solution to writing efficiently to tape that is currently in its early deployment phases at CERN.

  11. Simultaneous allergen inactivation and detoxification of castor bean cake by treatment with calcium compounds

    Directory of Open Access Journals (Sweden)

    K.V. Fernandes

    2012-11-01

    Full Text Available Ricinus communis L. is of great economic importance due to the oil extracted from its seeds. Castor oil has been used for pharmaceutical and industrial applications, as a lubricant or coating agent, as a component of plastic products, as a fungicide or in the synthesis of biodiesel fuels. After oil extraction, a castor cake with a large amount of protein is obtained. However, this by-product cannot be used as animal feed due to the presence of toxic (ricin and allergenic (2S albumin proteins. Here, we propose two processes for detoxification and allergen inactivation of the castor cake. In addition, we establish a biological test to detect ricin and validate these detoxification processes. In this test, Vero cells were treated with ricin, and cell death was assessed by cell counting and measurement of lactate dehydrogenase activity. The limit of detection of the Vero cell assay was 10 ng/mL using a concentration of 1.6 x 10(5 cells/well. Solid-state fermentation (SSF and treatment with calcium compounds were used as cake detoxification processes. For SSF, Aspergillus niger was grown using a castor cake as a substrate, and this cake was analyzed after 24, 48, 72, and 96 h of SSF. Ricin was eliminated after 24 h of SSF treatment. The cake was treated with 4 or 8% Ca(OH2 or CaO, and both the toxicity and the allergenic properties were entirely abolished. A by-product free of toxicity and allergens was obtained.

  12. Simultaneous allergen inactivation and detoxification of castor bean cake by treatment with calcium compounds

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, K.V.; Deus-de-Oliveira, N. [Laboratório de Química e Função de Proteínas e Peptídeos, Centro de Biociências e Biotecnologia, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Rio de Janeiro, RJ (Brazil); Godoy, M.G. [Laboratório de Biotecnologia Microbiana, Instituto de Química, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ (Brazil); Guimarães, Z.A.S. [Laboratório de Biologia Celular e Tecidual, Centro de Biociências e Biotecnologia, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Rio de Janeiro, RJ (Brazil); Nascimento, V.V. [Laboratório de Química e Função de Proteínas e Peptídeos, Centro de Biociências e Biotecnologia, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Rio de Janeiro, RJ (Brazil); Melo, E.J.T. de [Laboratório de Biologia Celular e Tecidual, Centro de Biociências e Biotecnologia, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Rio de Janeiro, RJ (Brazil); Freire, D.M.G. [Laboratório de Biotecnologia Microbiana, Instituto de Química, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ (Brazil); Dansa-Petretski, M.; Machado, O.L.T. [Laboratório de Química e Função de Proteínas e Peptídeos, Centro de Biociências e Biotecnologia, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Rio de Janeiro, RJ (Brazil)

    2012-08-24

    Ricinus communis L. is of great economic importance due to the oil extracted from its seeds. Castor oil has been used for pharmaceutical and industrial applications, as a lubricant or coating agent, as a component of plastic products, as a fungicide or in the synthesis of biodiesel fuels. After oil extraction, a castor cake with a large amount of protein is obtained. However, this by-product cannot be used as animal feed due to the presence of toxic (ricin) and allergenic (2S albumin) proteins. Here, we propose two processes for detoxification and allergen inactivation of the castor cake. In addition, we establish a biological test to detect ricin and validate these detoxification processes. In this test, Vero cells were treated with ricin, and cell death was assessed by cell counting and measurement of lactate dehydrogenase activity. The limit of detection of the Vero cell assay was 10 ng/mL using a concentration of 1.6 × 10{sup 5} cells/well. Solid-state fermentation (SSF) and treatment with calcium compounds were used as cake detoxification processes. For SSF, Aspergillus niger was grown using a castor cake as a substrate, and this cake was analyzed after 24, 48, 72, and 96 h of SSF. Ricin was eliminated after 24 h of SSF treatment. The cake was treated with 4 or 8% Ca(OH){sub 2} or CaO, and both the toxicity and the allergenic properties were entirely abolished. A by-product free of toxicity and allergens was obtained.

  13. Metodología basada en el Modelo de Referencia para Cadenas de Suministro para Analizar el Proceso de producción de Biodiesel a partir de Higuerilla Methodology based on the Supply Chain Operations Reference Model to Analyze the Production Process of Biodiesel from Castor Oil Plant

    Directory of Open Access Journals (Sweden)

    Fernando Salazar

    2012-01-01

    Full Text Available Se presenta un análisis para la producción de Biodiesel a partir de Higuerilla usando el Modelo de Referencia para Cadenas de Suministro (SCOR. Se identificaron los niveles del proceso, indicadores clave de desempeño, atributos y operaciones logísticas que se llevan a cabo en toda la cadena de la producción de biodiesel de higuerilla. La utilidad de la aplicación del modelo SCOR se determina por la identificación que logra de los componentes de la cadena, evidenciando fortalezas y debilidades que presenta en las relaciones externas e internas de la logística. Desde esta perspectiva se observó que la aplicación del modelo SCOR hace más eficiente las operaciones logísticas a lo largo de la cadena.The production process of Biodiesel from castor oil plants is analyzed using the Supply Chain Operations Reference Model (SCOR. The different levels of the process, the key performance indicators, the attributes and the logistic operations carried out throughout the chain were analyzed. The usefulness of applying the SCOR model is determined by the identification of the components of the chain, highlighting strengths and weaknesses of external and internal relations of the logistics. From this perspective it was observed that the implementation of the SCOR model makes more efficient the logistics operations through the whole chain.

  14. Metabolizable energy and nutrient digestibility of detoxified castor meal and castor cake for poultry

    Directory of Open Access Journals (Sweden)

    João Batista Matos Júnior

    2011-11-01

    Full Text Available This experiment aimed to determine the metabolizable energy and the digestibility of detoxified castor meal and castor cake nutrients for broilers. A total of 180 Cobb-500TM broilers from 21 to 32 days of age was randomly distributed in three treatments with six replicates of 10 broilers - 5 males and 5 females. The experimental treatments were a reference-diet and two test-diets composed of 80% of reference-diet and 20% of detoxified castor cake or castor meal. The adaptation period ranged from 21 to 27 days of age and the total excreta collection period ranged from 28 to 32 days of age. The detoxified castor meal presented apparent metabolizable energy of 2,032 kcal/kg of natural matter, apparent metabolizable energy corrected for nitrogen balance of 1,829 kcal/kg of natural matter and the digestibility coefficients of 57.8% dry matter, 68.4% crude protein, 10.5% crude fiber, 35.9% nitrogen free extract, 80.0% ether extract and 26.6% ash. In the detoxified castor cake, the apparent metabolizable energy content was 2,550 kcal/kg of natural matter, the nitrogen corrected apparent metabolizable energy balance was of 2,320 kcal/kg of natural matter and the digestibility coefficients of 60.6% for dry matter, 77.2% for crude protein, 14.0% for crude fiber, 45.7% for nitrogen free extract, 85.4% for ether extract and 28.2% for ash. The metabolizable energy and digestibility of nutrients in detoxified castor cake are higher than in the detoxified castor meal.

  15. Sur la biologie du Castor du Rhône (Castor fiber L.)

    NARCIS (Netherlands)

    Urbain, Achille

    1949-01-01

    Le Castor du Rhône ( Castor fiber L.) a été particulièrement bien étudié par de nombreux auteurs. VICTOR PIRAUD ¹) a donné d’intéressants renseignements sur ses moeurs; M. P. CORDIER ²) et A. HUGUES ³) ont fait aussi une étude appronfondie de cet animal et L. GERMAND 4) a fourni une description déta

  16. Simulation of the Centauro events at CASTOR

    CERN Document Server

    Kharlov, Yu V; CERN. Geneva; Sadovsky, S A; Gladysz-Dzadius, E

    1997-01-01

    We present the first Monte Carlo simulation of Centauro events, based on the phenomenological model of Panagiotou et al. and discuss the quantitative predictions for kinematics, baryon number, mass and decay properties of the Centauro fireball. The identification of Centauro events by the CASTOR detector is simulated. The signatures of these events are discussed in details.

  17. Polymercaptanized soybean oil – properties and tribological characterization

    Science.gov (United States)

    Polymercaptanized vegetable oils are produced in industrial scale by the addition of hydrogen sulfide across double bonds or epoxides of vegetable oils, in the presence of UV-light. To date, soybean oil, epoxidized soybean oil, and castor oil has been mercaptanized using such a procedure. Depending ...

  18. Ingestive behavior of finishing sheep fed detoxified castor bean meal

    Directory of Open Access Journals (Sweden)

    Daniel Cézar da Silva

    2016-06-01

    Full Text Available ABSTRACT Castor bean crops stand out in the Northeastern Brazil for oil production, producing coproducts with potential for animal diets. Thus, this work evaluated the effect on ingestive behavior when 0, 33, 67 and 100% of detoxified castor bean meal (DCBM were included to substitute soy bean meal in diets for sheep. The randomized blocks design was used with five sheep in each treatment. Dry matter intake and neutral detergent fiber intake were not affected (P > .05 by the inclusion of DCBM in the diet, with means of 1362.6 and 582.98 g/animal/day, respectively. Substitution of soybean meal by DCBM did not affect (P > .05 times of rumination, idle and total chewing, with averages of 181.33, 347.04 and 366.24 minute/12 h, respectively. A quadratic effect (P < .05 was found for feeding time, with minimum of 164.56 min/12 h, when 60% of DCBM was included in the diet. A quadratic effect (P < .05 was verified for eating efficiency with maximum of 4.43 g DM/minute and 2.08 g NDF/minute. Rumination efficiency in g DM and NDF/minute were not affected (P < .05, with means of 4.31 and 1.84, respectively. The substitution of soybean meal by DCBM decreases feeding time when 60% of it was used but does not influence the intake of DM and NDF, time spent in ruminating and idle, and total chewing time. The use of 60% of DCBM increases feeding efficiency of DM and NDF, and does not compromise the efficiency of rumination.

  19. Elastohydrodynamic Traction Properties of Seed Oils

    Science.gov (United States)

    The elastohydrodynamic traction coefficient (tc) properties of nine seed oils of varying chemical structures, PAO and hexadecane, were investigated using a ball-on disk traction apparatus. The seed oils were: castor oil, a triglyceride with hydroxyl functional group; jojoba, a monoglyceride; and s...

  20. Elastohydrodynamic (EHD) traction properties of seed oils

    Science.gov (United States)

    The elastohydrodynamic traction coefficient (tc) properties of nine seed oils of varying chemical structures, PAO and hexadecane, were investigated using a ball-on disk traction apparatus. The seed oils were: castor oil, a triglyceride with hydroxyl functional group; jojoba, a monoglyceride; and sev...

  1. Fractional characterisation of jatropha, neem, moringa, trisperma, castor and candlenut seeds as potential feedstocks for biodiesel production in Cuba

    Energy Technology Data Exchange (ETDEWEB)

    Martin, Carlos [Bioresource Technology group, Department of Chemistry and Chemical Engineering, University of Matanzas, Autopista a Varadero, km 3, Matanzas 44740 (Cuba); Department of Chemical Engineering, University of Vigo (Campus Ourense), Polytechnical Building, As Lagoas, 32004 Ourense (Spain); Moure, Andres; Dominguez, Herminia; Parajo, Juan C. [Department of Chemical Engineering, University of Vigo (Campus Ourense), Polytechnical Building, As Lagoas, 32004 Ourense (Spain); Martin, Giraldo [Experimental Station of Pastures and Forages ' ' Indio Hatuey' ' , Central Espana Republicana, CP 44280, Matanzas (Cuba); Carrillo, Eugenio [Biomass Energy Department, National Renewable Energy Centre (CENER), Ciudad de la Innovacion 4, Sarriguren, 31621 Pamplona (Spain)

    2010-04-15

    A preliminary investigation on the suitability of various non-edible oil seeds for the integral utilisation of their fractions for production of biodiesel and other products was carried out. The oil seeds considered were jatropha (Jatropha curcas), neem (Azadirachta indica), moringa (Moringa oleifera), trisperma (Aleurites trisperma), castor beans (Ricinus communis) and candlenut (Aleurites moluccana). The highest oil content (62.0% (w/w)) was found in trisperma seeds, but the use of that oil for biodiesel production is restricted by its high content of polyunsaturated fatty acids. The oils of castor beans and moringa contained 86.0% of ricinoleic acid and 70.6% of oleic acid, respectively, while in the oils from the other seeds no predominance of any acid was observed. According to the oil yield and to the fatty acid composition of the oil, jatropha was identified as the most promising oil seed for biodiesel production in Cuba. All the press cakes were rich in protein, the highest content (68.6%) being detected in moringa cake. The investigation revealed that the husks of neem and moringa can be considered potential substrates for ethanol production due to their high cellulose content (approximately 30%). A high concentration (4.3%) of acetyl groups was found in neem husks, what is favourable for the hydrolytic conversion of polysaccharides to simple sugars. A high protein content (15.2%) was detected in moringa husks, which is a positive feature for lowering the cost of nutrient supplementation in ethanolic fermentation. (author)

  2. Caracterização física e térmica de compósito de poliuretano derivado de óleo de mamona associado com partículas de bambu Physical and thermal characterization of polyurethane based on castor oil composite with bamboo particles

    Directory of Open Access Journals (Sweden)

    P. Marinho Nelson

    2013-01-01

    Full Text Available Compósitos de resina Poliuretana (PU derivada de óleo de mamona e partículas de bambu (Dendrocalamus giganteus foram preparados com 10, 15 e 20% em peso de PU pelo processo de prensagem. O objetivo do presente estudo foi criar uma solução para aproveitar resíduos da manufatura do bambu, minimizando impactos negativos ao meio ambiente, adicionando-lhe uma resina que não contém compostos orgânicos voláteis (COV. A sua caracterização foi feita através de análises físicas e termogravimetria. A associação de PU com partículas de bambu produziu efeitos esperados como a diminuição no teor de umidade, inchamento e absorção de água com o aumento do percentual de PU. Nos ensaios de dureza Shore D obteve-se um aumento gradual da rigidez superficial com o acréscimo em percentual de resina PU.Composites of Polyurethane (PU resin derived from castor oil and bamboo particles (Dendrocalamus giganteus were prepared by pressing with 10, 15 and 20% weight of PU. The aim of this study was to develop a new application of wastes from bamboo manufacture, minimizing the negative impact to the environment, adding a resin free of volatile organic compounds (COV. The composite characterization was performed with physical and thermogravimetric analysis. The association of PU and bamboo particles produced the expected effects, including a decrease in moisture content, swelling and water absorption as PU percentage increased. The Shore D hardness increased with the percentage of resin PU in the composite.

  3. LHCb: CASTORFS - A Filesystem to Access CASTOR

    CERN Multimedia

    Mazurov, A

    2009-01-01

    CASTOR provides a powerful and rich interface for managing files and pools of files backed by tape-storage. The API is modelled very closely on that of a POSIX filesystem, where part of the actual I/O part is handled by the rfio library. While the API is very close to POSIX it is still separated, which unfortunately makes it impossible to use standard tools and scripts straight away. This is particularly inconvenient when applications are written in languages other than C/C++ such as is frequently the case in web-apps. Here up to now the only the recourse was to use command-line utilities and parse their output, which is clearly a kludge. We have implemented a complete POSIX filesystem to access CASTOR using FUSE (Filesystem in Userspace) and have successfully tested and used this on SLC4 and SLC5 (both in 32 and 64 bit). We call it CastorFS. In this paper we will present its architecture and implementation, with emphasis on performance and caching aspects.

  4. Effects of autoclaving on the proximate composition of stored castor (Ricinus communis seeds

    Directory of Open Access Journals (Sweden)

    ANTHONY NEGEDU

    2013-11-01

    Full Text Available Negedu A, Ameh JB, Umoh VJ, Atawodi SE, Rai MK. 2013. Effects of autoclaving on the proximate composition of stored castor (Ricinus communis seeds. Nusantara Bioscience 5: 51-56. The effect of autoclaving on the proximate composition, free fatty acids and peroxide value of castor (Ricinus communis L. seeds in storage were studied. Seeds of castor were surface sterilized, dried and divided into two equal sets of 300g each. One set was autoclaved at 15 1b pressure for 30 minutes at 121oC and the other set served as control. Each set was prepared in triplicates and both sets were stored under same room temperature conditions for a period of 180 days and agitated intermittently. Analysis of the proximate composition showed that autoclaving treatment caused an increased total fat content, reduced moisture, protein, nitrogen free extract (soluble sugar and ash contents of the seeds in storage, as well as a non-significant increase in crude fiber (non-soluble sugar content. It increased the free fatty acid content and decreased the peroxide value of seed oil.

  5. Photosynthetic pigments and gas exchange in castor bean under conditions of above the optimal temperature and high CO2

    Directory of Open Access Journals (Sweden)

    Fabiola França Silva

    2015-08-01

    Full Text Available The castor bean plant, a Euphorbiaceae oil seed C3-metabolism rustic and drought-resistant plant, is cultivated in a wide range of environments due to its good adaptive capacity. However, given the current environmental changes, many biochemical and physiological impacts may affect the productivity of important crops, such as castor bean. This work aimed to evaluate the impacts of the castor bean gas exchange in response to high temperature and increased CO2concentration.Our experiment was conducted in a phytotron located at Embrapa Algodão in 2010. We adopted a completely randomized design, with four treatments in a factorial combination of two temperatures (30/20 and 37/30°C and two CO2 levels (400 and 800 mmol L-1; four replications were performed, obtained in five surveys over the growth cycle, for a total of 80 sample units. An infrared gas analyzer (IRGA - Infra Red Gas Analyzer was used for the quantification of the photosynthetic rate, stomatal conductance and transpiration. An increase in the atmospheric CO2 concentration and temperature negatively affected the physiology of the castor bean plants, decreasing the net rate of photosynthesis, transpiration and stomatal conductance.

  6. Genomic surveys and expression analysis of bZIP gene family in castor bean (Ricinus communis L.).

    Science.gov (United States)

    Jin, Zhengwei; Xu, Wei; Liu, Aizhong

    2014-02-01

    The basic leucine zipper (bZIP) transcription factors comprise a family of transcriptional regulators present extensively in plants, involved in regulating diverse biological processes such as flower and vascular development, seed maturation, stress signaling and pathogen defense. Castor bean (Ricinus communis L. Euphorbiaceae) is one of the most important non-edible oilseed crops and its seed oil is broadly used for industrial applications. We performed a comprehensive genome-wide identification and analysis of the bZIP transcription factors that exist in the castor bean genome in this study. In total, 49 RcbZIP transcription factors were identified, characterized and categorized into 11 groups (I-XI) based on their gene structure, DNA-binding sites, conserved motifs, and phylogenetic relationships. The dimerization properties of 49 RcbZIP proteins were predicted on the basis of the characteristic features in the leucine zipper. Global expression profiles of 49 RcbZIP genes among different tissues were examined using high-throughput sequencing of digital gene expression profiles, and resulted in diverse expression patterns that may provide basic information to further reveal the function of the 49 RcbZIP genes in castor bean. The results obtained from this study would provide valuable information in understanding the molecular basis of the RcbZIP transcription factor family and their potential function in regulating the growth and development, particularly in seed filling of castor bean.

  7. Evaluation of Genetic Diversity of Castor Bean for Biodiesel Utilization

    Science.gov (United States)

    Castor bean (Ricinus communis L., 2n=20) is a cross-pollinated diploid species belonging to the family Euphorbiaceae instead of the Leguminosae. It is a native of Africa but may have originated in India. Castor bean plants grow as annual or perennial, depending on geographical locations, climate a...

  8. Performance and Calibration of CASTOR Calorimeter at CMS

    CERN Document Server

    Kuznetsova, Ekaterina

    2012-01-01

    CASTOR trigger was developed and activated during beam injections and ramp-ups. The triggered events correspond to an isolated particle penetrating the calorimeter parallel to the beam axis. Analysis of the obtained spectra provides relative response to a muon per individual read-out channel. An absolute CASTOR calibration is not discussed here.

  9. 蓖麻及其衍生制品在食品工业中应用的研究进展%Research progress in application of castor and its derivative products in the food field

    Institute of Scientific and Technical Information of China (English)

    张智勇; 倪娜; 李国瑞; 黄凤兰

    2012-01-01

    Being rich in ricinoleic acid,proteins and some functional factors,castor and its derivatives products are widely used in the food industry.Developments in the study of application of castor products in food industry were reviewed from the utilization of castor oil,castor bean meal,etc.%蓖麻中含有丰富的蓖麻油酸、蛋白质及一些功能成分,因此其衍生制品在食品工业中具有广泛的应用。文章从蓖麻油、蓖麻饼粕蛋白及其他成分的利用等几个方面,对蓖麻产品在食品工业中应用的研究进展情况进行了综述。

  10. CASTOR detector Model, objectives and simulated performance

    CERN Document Server

    Angelis, Aris L S; Bartke, Jerzy; Bogolyubsky, M Yu; Chileev, K; Erine, S; Gladysz-Dziadus, E; Kharlov, Yu V; Kurepin, A B; Lobanov, M O; Maevskaya, A I; Mavromanolakis, G; Nicolis, N G; Panagiotou, A D; Sadovsky, S A; Wlodarczyk, Z

    2001-01-01

    We present a phenomenological model describing the formation and evolution of a Centauro fireball in the baryon-rich region in nucleus-nucleus interactions in the upper atmosphere and at the LHC. The small particle multiplicity and imbalance of electromagnetic and hadronic content characterizing a Centauro event and also the strongly penetrating particles (assumed to be strangelets) frequently accompanying them can be naturally explained. We describe the CASTOR calorimeter, a subdetector of the ALICE experiment dedicated to the search for Centauro in the very forward, baryon-rich region of central Pb+Pb collisions at the LHC. The basic characteristics and simulated performance of the calorimeter are presented. (22 refs).

  11. CASTOR detector. Model, objectives and simulated performance

    Energy Technology Data Exchange (ETDEWEB)

    Angelis, A. L. S.; Mavromanolakis, G.; Panagiotou, A. D. [University of Athens, Nuclear and Particle Physics Division, Athens (Greece); Aslanoglou, X.; Nicolis, N. [Ioannina Univ., Ioannina (Greece). Dept. of Physics; Bartke, J.; Gladysz-Dziadus, E. [Institute of Nuclear Physics, Cracow (Poland); Lobanov, M.; Erine, S.; Kharlov, Y.V.; Bogolyubsky, M.Y. [Institute for High Energy Physics, Protvino (Russian Federation); Kurepin, A.B.; Chileev, K. [Institute for Nuclear Research, Moscow (Russian Federation); Wlodarczyk, Z. [Pedagogical University, Institute of Physics, Kielce (Poland)

    2001-10-01

    It is presented a phenomenological model describing the formation and evolution of a Centauro fireball in the baryon-rich region in nucleus-nucleus interactions in the upper atmosphere and at the LHC. The small particle multiplicity and imbalance of electromagnetic and hadronic content characterizing a Centauro event and also the strongly penetrating particles (assumed to be strangelets) frequently accompanying them can be naturally explained. It is described the CASTOR calorimeter, a sub detector of the ALICE experiment dedicated to the search for Centauro in the very forward, baryon-rich region of central Pb+Pb collisions at the LHC. The basic characteristics and simulated performance of the calorimeter are presented.

  12. Morphology and viability of castor bean genotypes pollen grains

    Directory of Open Access Journals (Sweden)

    Maria Selma Alves Silva Diamantino

    2016-01-01

    Full Text Available The objective of this work was to characterize the morphology and viability of the pollen of 15 genotypes of castor bean (Ricinus communis L. and to generate information that can assist in the selection of highly promising male parents for future use in genetic improvement programs aimed at producing seeds for oil extraction. Acetolysis and scanning electron microscopy was used to characterize the morphology of the pollen. The viability of the pollen grains was estimated by in vitro germination and colorimetric analysis (acetocarmine 2% and 2, 3, 5-triphenyltetrazolium chloride 1%. For the in vitro germination, pollen grains were grown in 10 types of solidified culture medium consisting of different concentrations of sucrose, boric acid, calcium nitrate, magnesium sulfate and potassium nitrate. The pollen grains had the following characteristics: medium size, isopolar and subspheroidal shape, radial symmetry, circular ambit, 3-colporate, elongated endoapertures, tectate exine and granulated sexine. The acetocarmine dye overestimated pollen viability. The media M5 and M8 were the most efficient at promoting the germination of pollen grains. The studied genotypes had high levels of viability and can therefore be used as male parents in genetic improvement programs.

  13. Effect of calcium and magnesium silicate on the growth of the castor oil plant subjected to salinity levels Efeito de silicato de cálcio e magnésio sobre o crescimento de plantas de mamoneira submetidas a níveis de salinidade

    Directory of Open Access Journals (Sweden)

    José Félix Brito Neto

    2012-12-01

    Full Text Available Salt stress decreases the osmotic potential of soil solution causing water stress, causing toxic effects in the plants resulting in injuries on the metabolism and nutritional disorders, thus compromising the plant growth, resulting in lower production. The calcium silicate and magnesium can perform the same function as limestone, besides providing silicon to plants, may also contribute to the resistance of plants to salt stress. Thus, the objective of this study was to evaluate the effect of calcium and magnesium silicate on the growth of the castor oil plant BRS Energia cultivated under saline conditions. This study evaluated plant height, stem diameter, number of leaves, leaf area, dry weight of shoot and root, and soil chemical characteristics. There was no interaction between factors of salinity level and of silicate level regarding the evaluated variables. There was a direct relationship between salinity levels and plant growth in height and stem diameter. The K concentration in soil were affected by salinity levels. O estresse salino diminui o potencial osmótico da solução do solo causando estresse hídrico, provocando efeitos tóxicos nas plantas que resultam em injúrias no metabolismo e desordens nutricionais, comprometendo assim o crescimento das plantas, resultando em menor produção. O silicato de cálcio e magnésio pode desempenhar a mesma função do calcário, além de fornecer silício para as plantas, podendo ainda, contribuir para a resistência de plantas ao estresse salino. Nesse sentido, objetivou-se com esse trabalho avaliar o efeito do silicato de cálcio e magnésio no crescimento da mamoneira BRS Energia cultivada sob condições salinas. Avaliou-se a altura da planta, diâmetro do caule, número de folhas, área foliar, massa seca da parte aérea e da raiz e as características químicas do solo. Não houve interação entre os fatores níveis de salinidade e silicato sobre as variáveis analisadas. Houve rela

  14. Potential of various fungi for biomass production of castor.

    Science.gov (United States)

    Sawant, V S; Bansode, K G; Bavachkar, S N; Bhale, U N

    2013-11-01

    An experiment was conducted to evaluate biomass production of castor (Ricinus communis) with inoculation of native Arbuscular Mycorrhizal Fungi (AMF), Trichoderma harzianum and Aspergillus niger. In castor, dual treatment of mycorrhiza and T. harzianum was better for shoot length (29.5 cm), root length (40.3 cm), fresh shoot weight (4.90 g), fresh root weight (1.13 g), number of leaves (10) and leaf area (75.5 cm2) than dual treatment of mycorrhiza and A. niger or mycorrhiza alone. These findings established the potential of the fungi for increase in biomass of castor.

  15. Lubrication properties of new crop oils

    Science.gov (United States)

    Oils from new crops such as lesquerella (Lesquerella fendleri), field pennycress (Thlaspi arvense L.), meadowfoam (Limnanthes alba L.), and cuphea PSR-23 (Cuphea viscosissima × Cuphea lanceolata) were investigated and compared with vegetable oils from commodity crops such as castor, corn, and soybea...

  16. Control of papaya fruits anthracnose by essential oil of Ricinus communis

    Directory of Open Access Journals (Sweden)

    César Luis Siqueira Júnior

    2012-02-01

    Full Text Available The aim of this work was to investigate the potential of castor oil for the control of papaya diseases caused by the fungus Colletotrichum gloeosporioides and the bacterium Pseudomonas caricapapayae. The treatment with 1% castor oil did not significantly affect the fungal growth. The effectiveness of castor oil for the control of anthracnose was shown when 5% and 10% (v/v were used in the assays resulting in reduced mycelial growth. Fungal sporulation was strongly inhibited at 10% (v/v concentration of essential oil. The studies with the fresh fruits treated with 5% (v/v castor oil in aqueous emulsions resulted in effective reduction of pathogen spread in these fruits. No lesion was found in the fruits treated with oil, when compared to the control fruits. Castor oil showed no effect against the P. caricapapayae when tested in vitro. These results suggested the potential use of the castor bean essential oil and its fatty acids constituents for the control of anthracnose in papaya fruits.

  17. Influence of the organic matter and soil water deficit on the castor bean absolute growth rate

    Energy Technology Data Exchange (ETDEWEB)

    Lacerda, Rogerio Dantas de; Guerra, Hugo O. Carvallo; Chaves, Lucia Helena G. [Universidade Federal de Campina Grande (UAEAg/UFCG), PB (Brazil). Unidade Academica de Engenharia Agricola; Araujo, Ester Luiz de; Nascimento, Elka Costa Santos; Barros Junior, Genival [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2008-07-01

    Even when under low precipitations conditions, the castor bean production decrease, it constitutes a very good alternative. It has an elevated economical importance, because from the plant it is used their leaves, stem and seeds. From the stem it is obtained cellulose for the paper industry, from the leaves textile products and from the seeds oil and tort. The oil is the only glycerin soluble in alcohol and the base for several industrial products such as the biodiesel. The objective of the present work was to study the effect of different soil water and soil organic matter on the castor bean, BRS 188 cultivar rate growth. The experiment was conducted from April to August 2006 under greenhouse conditions using a randomized block 2x4 factorial design with two soil organic mater content (5.0 g.kg{sup -1} e 25.0 g.kg{sup -1}), four levels of available water (100, 90, 80 e 70% ) and three replicates. For this, 24 plastic containers, 75 kg capacity, were used on which was grown one plant 120 days after the seedling. At regular intervals the plant height was measured and the results analyzed statistically. For the qualitative treatments (with and without organic matter) the treatment means were compared through the Tukey test. For the quantitative ones (water levels) regressions were used. It was observed that both, organic matter and available water for plants proportionated benefit effects to the growth rate of the plant. (author)

  18. Antidiarrhoeic effect of Eugenia dysenterica DC (Myrtaceae) leaf essential oil.

    Science.gov (United States)

    Galheigo, Maria Raquel Unterkircher; Prado, Ligia Carolina da Silva; Mundin, Angélica Martins Moreira; Gomes, Dayane Olímpia; Chang, Roberto; Lima, Anna Monteiro Correia; Canabrava, Hudson Armando Nunes; Bispo-da-Silva, Luiz Borges

    2016-01-01

    Essential oil from Eugenia dysenterica leaves was able to inhibit both the diarrhoea and enteropooling induced by castor oil; however, the distance travelled by charcoal meal in the intestine was not change. These data suggest that the antidiarrhoeic effect of the essential oil from E. dysenterica leaves is related to its ability to inhibit intestinal secretion and/or to increase intestinal absorption.

  19. 改性氢化蓖麻油/KH550-TiO 2复合材料的制备及性能%The preparation and properties of modified hydrogenated castor oil/KH550-TiO2 nanocomposites

    Institute of Scientific and Technical Information of China (English)

    吕斌; 段徐宾; 高党鸽; 马建中; 段力民

    2015-01-01

    以硅烷偶联剂 KH550为改性剂对纳米TiO 2进行改性,制得 KH550改性纳米 TiO 2(KH550-TiO 2),然后以其与氢化蓖麻油为原料,通过原位法制得了改性氢化蓖麻油/KH550改性 TiO 2纳米复合材料(SSF/KH550-TiO 2),再将其应用于山羊皮服装革的加脂工序中。采用 X 射线衍射(XRD)、红外(FT-IR)及热重(TGA)对 KH550-TiO 2进行表征,采用 FT-IR、动态激光散射(DLS)、透射电镜(TEM)和紫外分光光度计(UV)对 SSF/KH550-TiO 2进行表征,并且对应用后革样的耐黄变性能、机械性能、增厚率及柔软度进行检测,同时也通过扫描电子显微镜(SEM)对胶原纤维进行观察。XRD、FT-IR 和 TGA 检测结果表明,硅烷偶联剂能够成功地对纳米 TiO 2进行改性,并且不改变 TiO 2晶型结构,其包覆率在2.27%~2.72%。DLS、UV 和 TEM 检测结果表明,KH550-TiO 2的引入,不仅能够明显降低 SSF/KH550-TiO 2的粒径,也能提高 SSF/KH550-TiO 2的紫外吸收性能,并且 KH550-TiO 2均匀地分散在 SSF/KH550-TiO 2中。革样性能表明,KH550-TiO 2的引入对革样的机械性能影响不明显,但耐黄变、增后率及柔软度明显增加,并随着 KH550-TiO 2引入量的增加而增加。SEM 检测结果表明,KH550-TiO 2能够渗透到胶原纤维之间。%Modified TiO 2 (KH550-TiO 2 )was prepared by γ-ammonia propyl triethoxysilane and TiO 2 .Hydro-genated castor oil and modified titanium synthesizedhydrogenated castor oil/γ-ammonia propyl triethoxysilane modifiedtitanium nanocomposites (SSF/KH550-TiO 2 )by in-situ method.Finally SSF/KH550-TiO 2 was applied in fatliquoring of goatskin garment and properties of the fatliquored leather were tested.KH550-TiO 2 was char-acterized by X-ray diffraction (XRD),fourier transform infrared spectroscopy (FT-IR)and thermogravimetric analysis(TGA).dynamic SSF/KH550-TiO 2 was characterized by FT-IR,dynamic laser scattering(DLS),UV spectrophotometer (UV)and transmission electron microscope (TEM

  20. High light exposure on seed coat increases lipid accumulation in seeds of castor bean (Ricinus communis L.), a nongreen oilseed crop.

    Science.gov (United States)

    Zhang, Yang; Mulpuri, Sujatha; Liu, Aizhong

    2016-05-01

    Little was known on how sunlight affects the seed metabolism in nongreen seeds. Castor bean (Ricinus communis L.) is a typical nongreen oilseed crop and its seed oil is an important feedstock in industry. In this study, photosynthetic activity of seed coat tissues of castor bean in natural conditions was evaluated in comparison to shaded conditions. Our results indicate that exposure to high light enhances photosynthetic activity in seed coats and consequently increases oil accumulation. Consistent results were also reached using cultured seeds. High-throughput RNA-Seq analyses further revealed that genes involved in photosynthesis and carbon conversion in both the Calvin-Benson cycle and malate transport were differentially expressed between seeds cultured under light and dark conditions, implying several venues potentially contributing to light-enhanced lipid accumulation such as increased reducing power and CO2 refixation which underlie the overall lipid biosynthesis. This study demonstrated the effects of light exposure on oil accumulation in nongreen oilseeds and greatly expands our understanding of the physiological roles that light may play during seed development in nongreen oilseeds. Essentially, our studies suggest that potential exists to enhance castor oil yield through increasing exposure of the inflorescences to sunlight either by genetically changing the plant architecture (smart canopy) or its growing environment.

  1. Production of bran castor biochar through slow pyrolysis

    Science.gov (United States)

    Pissinati de Rezende, E. I.; Mangrich, A. S.; Batista, M. G. F.; Toledo, J. M. S.; Novotny, E. H.

    2012-04-01

    Pyrolysis is a thermal process of great importance in the present context, since it constitutes a significant alternative to adequate use of organic waste. The principal products obtained in the pyrolysis of discarded biomass are bio-oil, biogas and biochar. Biochar, in turn, may play a relevant role when applied to the soil to sequester carbon and as a soil conditioner, a material comparable to organic matter of Indians Black Earths from the Amazon Region [1]. Seeking to determine the best methods of preparation of biochar, we studied the pyrolysis of bran castor residue of the Brazilian biodiesel industry. Eight samples, from FM1 to FM8, were prepared in a factorial design 23 using two temperature (300 and 350 °C), two heating velocity (5 and 10 °C min-1) and two period of heating (30 and 60 min). The eight samples were studied using the spectroscopy: EPR, FTIR, RMN, XPS, and elemental analysis. By elemental analysis, the samples that keep for lower temperature of pyrolysis, 300 °C, showed H/C and N/C ratios greater than the samples of 350 °C. That higher value can be attributed to chemical structure more aliphatic than aromatic mainly in the FM7 sample (V = 10 °C min-1, T = 300 °C, P = 30 min). The greater N/C ratio correlated with a superior amount of nitrogenous functions, presenting by both FM7 and FM4 samples, as determined by 13C NMR spectroscopy with absorptions in 175 ppm (amide) and 55 ppm (N-alkyl).

  2. Apis mellifera pollination improves agronomic productivity of anemophilous castor bean (Ricinus communis

    Directory of Open Access Journals (Sweden)

    Rômulo A.G. Rizzardo

    2012-12-01

    Full Text Available Castor bean (Ricinus communis L. is cultivated mainly for biodiesel production because of its oil-rich seeds; it is assumed to be an anemophylous species. But pollination deficit can lead to low productivity often attributed to other reasons. In this paper, we investigated pollination requirements, pollination mechanism, occurrence of pollination deficit, and the role of biotic pollinators in a large commercial plantation of castor bean. Our results show that R. communis bears a mixed breeding system favoring selfing by geitonogamy, although the wind promotes mostly outcrossing. We also found that the honey bee (Apis mellifera L. foraging on castor bean can both transfer pollen from male to female flowers within the same raceme and boost the release of airborne pollen by male flowers. Both situations increase geitonogamy rates, raising significantly fruit set and seed yield. This is the first report of an animal foraging activity increasing seed yield in an anemophilous and geitonogamous crop and elucidates the role of biotic pollinators in castor bean reproduction.A mamoneira (Ricinus communis L. é cultivada principalmente para produção de biodiesel devido ao alto teor de óleo de suas sementes e considerada como sendo de polinização anemófila. Mas déficits de polinização podem levar a baixos índices de produtividade geralmente atribuídos a outros fatores. Neste trabalho foram investigados os requerimentos, mecanismos e déficit de polinização e o papel dos polinizadores bióticos em um monocultivo comercial de mamona. Os resultados mostram que R. communis possui um sistema de polinização misto, favorecendo a autopolinização por geitonogamia, embora o vento normalmente promova polinização cruzada. Observou-se também que a abelha melífera (Apis mellifera L. forrageando na mamoneira pode tanto transferir pólen das flores estaminadas para as pistiladas do mesmo racemo, quanto aumentar consideravelmente a liberação de p

  3. Effect of the organic matter and soil water deficit on the castor bean inflorescences emission

    Energy Technology Data Exchange (ETDEWEB)

    Lacerda, Rogerio Dantas de; Araujo, Ester Luiz de; Nascimento, Elka Costa Santos; Barros Junior, Genival [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Guerra, Hugo O. Carvallo; Chaves, Lucia Helena G. [Universidade Federal de Campina Grande (UAEAg/UFCG), PB (Brazil). Unidade Academica de Engenharia Agricola

    2008-07-01

    The castor bean culture has become important due to the several applications of its oil, which constitutes one of the best row materials for biodiesel manufacturing, and the base for several other industrial products. The objective of the present work was to study the effect of different soil water and soil organic matter on the castor bean inflorescence emission. The experiment was conducted from April to August 2006 under Greenhouse conditions using a randomized block 2x4 factorial design with two soil organic mater content (5.0 g.kg{sup -1} e 25.0 g.kg{sup -1}), four levels of available water (100, 90, 80 e 70% ) and three replicates. For this, 24 plastic containers, 75 kg capacity, were used on which was grown one plant 120 days after the seedling. When flowering occurred it was measured the number, the time required for the emission and the height of the emissions. The results were analyzed statistically; for the qualitative factor (with and without organic matter) the treatment means were compared through the Tukey test. For the quantitative ones (water levels) regressions were used. The time for the emission of the inflorescences was affected significantly by the organic matter and the available soil water content for plants. The number of inflorescences was affected positively by both treatments. (author)

  4. Early Stage Design of a Bio refinery from Castor Oil

    DEFF Research Database (Denmark)

    de Faria, Daniela; Quaglia, Alberto; Pessoa, Fernando

    2014-01-01

    This paper presents a systematic method fo r synthesis and analysis of bio mass based biorefinery pathways (process networks) in terms of current and future market conditions. The systematic method has been implemented into a computer aided tool that is able to quickly evaluate alternatives...

  5. 75 FR 40751 - Castor Oil, Ethoxylated, Oleate; Tolerance Exemption

    Science.gov (United States)

    2010-07-14

    ... of its composition the atomic elements carbon, hydrogen, and oxygen. 3. The polymer does not contain as an integral part of its composition, except as impurities, any element other than those listed in... recordkeeping requirements. Dated: July 7, 2010. Lois Rossi, Director, Registration Division, Office...

  6. 75 FR 44917 - Castor Oil, Ethoxylated, Dioleate; Tolerance Exemption

    Science.gov (United States)

    2010-07-30

    ... of its composition the atomic elements carbon, hydrogen, and oxygen. 3. The polymer does not contain as an integral part of its composition, except as impurities, any element other than those listed in..., Reporting and recordkeeping requirements. Dated: July 22, 2010. Lois Rossi, Director, Registration...

  7. Estudio comparativo del uso de la matriz ósea desmineralizada de origen humana y de la poliuretana derivada del aceite de mamona sobre el proceso de regeneración ósea: Estudio histométrico en calota de conejos A comparative study on the use of demineralized bone matrix of human origin and polyurethane derived from castor oil in bone regeneration processes: A histometric study on rabbit calvaria

    Directory of Open Access Journals (Sweden)

    J. Rodrigues Laureano Filho

    2007-08-01

    Full Text Available Objetivo. Analizar histométricamente el efecto de la matriz ósea desmineralizada de origen humana y de la resina poliuretana derivada del aceite de mamona, sobre el proceso de regeneración ósea. Diseño del estudio: fueron utilizados 24 conejos y en cada calota craniana fueron preparadas dos cavidades quirúrgicas, siendo una a cada lado de la sutura parietal. Los animales fueron divididos en dos grupos. En el grupo I la cavidad experimental (lado derecho fue rellenada con la poliuretana derivada del aceite de mamona, mientras que en el grupo II la cavidad experimental fue rellenada con la matriz ósea desmineralizada de origen humano. Las cavidades de control fueron rellenadas solo con la sangre del animal. Los animales fueron sacrificados en los períodos postoperatorios de 04, 07 y 15 semanas. Resultados. El análisis estadístico, realizado en base de los datos de la histometría, mostró una mayor neoformación ósea de los grupos I y II en relación al grupo control, no existiendo diferencia estadística cuando los grupos experimentales fueron comparados. Conclusiones. El uso de poliuretana derivada del aceite de mamona y matriz ósea desmineralizada de origen humano mejoran el proceso de regeneración cuando lo comparamos a la regeneración ósea normal resultando que entre ambos materiales tuvieron un comportamiento similar sin diferencias estadísticas significantes entre sí.Objective. The present study was aimed at carrying out a histological and histometric analysis on the effect of human demineralized bone matrix and a polyurethane resin, derived of the castor bean oil, on the bone regeneration process. Design: For this, 24 rabbits were used and in each calvarium two surgical bone defect were prepared, one on the right side and another on the left side of the parietal suture. The animals were divided into two groups. In group I the experimental defect (right side was filled with polyurethane derived from oil of the castor oil

  8. Detoxified Castor Seed Cake for Broilers

    Directory of Open Access Journals (Sweden)

    DE Faria Filho

    2016-03-01

    Full Text Available Abstract The objective of the present study was to evaluate the effect of the dietary detoxified castor seed cake (DCC inclusion on broiler performance and carcass traits. Two hundred and fifty Cobb-500(r broilers were distributed according to a completely randomized experimental design consisting of five treatments (dietary inclusion of 0.0, 2.5, 5.0, 7.5, and 10.0% DCC with five replicates of 10 birds each (five males and five females. Feed intake (FI, body weight gain (WG, and feed conversion ratio (FCR were evaluated from one to 40 days of age. Carcass yield and the yields of the breast, leg (drumstick+thighs, and wings were determined when broilers were 40 days old. Live performance parameters were influenced by DCC dietary inclusion, and levels 2.00, 1.38, and 1.25% DCC impaired FI, WG, and FCR, respectively. Carcass and parts yields were not affected by dietary DCC inclusion. It was concluded that the addition of DCC levels up to 1.25% to broiler diets does not impair live performance or carcass traits.

  9. Castor Seed from Melkasa Agricultural Research Centre, East Showa, Ethiopia and it’s biodiesel performance in Four Stroke Diesel Engine

    Directory of Open Access Journals (Sweden)

    Tesfahun Tegegne Akanawa

    2014-05-01

    Full Text Available This study focused in investigating the fuel properties of Castor oil Methyl Ester (CME and its blend with diesel fuel in running a diesel engine. Engine tests have been carried out with the aim of obtaining comparative measures of torque, power, and specific fuel consumption. Castor oil was extracted by using a mechanical pressing machine and trans-esterification was made by methyl alcohol and potassium hydroxide as a catalyst.  So that its viscosity and density were reduced and by increasing its volatility.  By following the procedures given in American Society for Testing and Materials (ASTM book the fuel characteristics were identified whether it fulfil the requirements needed to be used as a fuel in internal combustion engines or not. From the characterization result, it was proved that trans-esterified castor oil was found to be a promising alternative fuel for compression ignition (diesel engines. But the viscosity of CME was still higher and the energy content was a little bit less as compared to petro diesel. To solve these problems CME was blended with petro diesel in some proportion (B5, B10, B20, B40, B80. The torque, power and brake specific fuel consumption performances of CME and its blends with petro diesel were tested in a four stroke diesel engine. The analyzed results were compared with that of petro diesel and found to be very nearly similar, making CME a suiTable alternative fuel for petro diesel.

  10. Ricinus communis and Jatropha curcas (Euphorbiaceae) seed oil toxicity against Atta sexdens rubropilosa (Hymenoptera: Formicidae).

    Science.gov (United States)

    Alonso, E C; Santos, D Y A C

    2013-04-01

    Leaf-cutting ants are the main herbivores in the New World tropics. Although the toxicity of seed oils against these ants has been poorly investigated, previous results revealed that seed oils exert considerable toxic activity against these insects. This paper analyzes the toxic action and deterrent properties of castor oil, Ricinus communis L., and physic nut oil, Jatropha curcas L., against workers of the leaf-cutting ant Atta sexdens rubropilosa reared in laboratory. Toxic effect was analyzed by feeding insects artificial diets supplemented with different oil concentrations and direct contact with the two oils. Deterrent activity was assessed by measuring the frequency of attendance to diets during the first 48 h of the ingestion bioassay. Castor oil at 10 and 30 mg/ml and physic nut oil at 5, 10, and 30 mg/ml were toxic by ingestion. In the direct contact bioassay, toxicity was observed for physic nut oil at 0.1 and 0.2 mg/ml, whereas castor oil exerted toxic effects only when the highest concentration was applied. Also, castor oil had a more pronounced deterrent effect against the leaf-cutting ant, compared with physic nut oil. Methods to apply these oils to control these insects are discussed.

  11. A Novel Methodology for the Synthesis of Acyloxy Castor Polyol Esters: Low Pour Point Lubricant Base Stocks.

    Science.gov (United States)

    Kamalakar, Kotte; Mahesh, Goli; Prasad, Rachapudi B N; Karuna, Mallampalli S L

    2015-01-01

    Castor oil, a non-edible oil containing hydroxyl fatty acid, ricinoleic acid (89.3 %) was chemically modified employing a two step procedure. The first step involved acylation (C(2)-C(6) alkanoic anhydrides) of -OH functionality employing a green catalyst, Kieselguhr-G and solvent free medium. The catalyst after reaction was filtered and reused several times without loss in activity. The second step is esterification of acylated castor fatty acids with branched mono alcohol, 2-ethylhexanol and polyols namely neopentyl glycol (NPG), trimethylolpropane (TMP) and pentaerythritol (PE) to obtain 16 novel base stocks. The base stocks when evaluated for different lubricant properties have shown very low pour points (-30 to -45°C) and broad viscosity ranges 20.27 cSt to 370.73 cSt, higher viscosity indices (144-171), good thermal and oxidative stabilities, and high weld load capacities suitable for multi-range industrial applications such as hydraulic fluids, metal working fluids, gear oil, forging and aviation applications. The study revealed that acylated branched mono- and polyol esters rich in monounsaturation is desirable for developing low pour point base stocks.

  12. Cosmic ray teststand for the CASTOR calorimeter of CMS

    Energy Technology Data Exchange (ETDEWEB)

    Jesus Damiao, Dilson de; Santoro, Alberto [Universidade do Estado do Rio de Janeiro (UERJ) (Brazil); Grothe, Monika [University of Wisconsin, Madison (United States)

    2008-07-01

    The very forward region of the CMS experiment at the LHC will house a quartz-tungsten sampling calorimeter CASTOR (''Centauro And STrange Object Research) with rapidity coverage 5.1CASTOR will add considerably to the forward physics reach of CMS in both proton-proton and heavy-ion collisions. We report on the setup and operation of a teststand for calibrating the calorimeter response with the help of mip signals originating from muons in cosmic-ray-initiated particle showers.

  13. Effect of abscisic and gibberellic acids on malate synthase transcripts in germinating castor bean seeds.

    Science.gov (United States)

    Rodriguez, D; Dommes, J; Northcote, D H

    1987-05-01

    Several clones complementary to malate synthase mRNA have been identified in a complementary-DNA library to mRNA from castor bean endosperm. One of these clones has been used as a probe to measure levels of transcripts during seed germination and the effects of gibberellic acid and abscisic acid on these levels have been examined.Malate synthase transcripts increased during germination and GA3 advanced their appearance in the endosperm. Exogenously applied ABA inhibited the accumulation of transcripts over a time course of germination but the addition of GA3 counteracted its inhibitory effects. The data confirmed previous reports which indicated that the action of both growth regulators was on transcript accumulation and that there is a coordinated induction of the enzymes involved in the lipid metabolism in oil seeds.

  14. Análise clínica, radiológica, macroscópica e histológica do úmero de codornas domésticas (Coturnix japonica, submetido ao implante da poliuretana derivada do polímero de mamona (Ricinnus communis Clinical, radiological, macroscopical and histological analysis of domestic quail (Coturnix japonica humerus submitted to implant of polyurethane from castor oil polymer (Ricinnus communis

    Directory of Open Access Journals (Sweden)

    Juliano Bolson

    2005-10-01

    ça de trabéculas e medula óssea no interior do implante. Concluiu-se que a poliuretana derivada do polímero de mamona é biocompatível em aves, podendo ser utilizada na cirurgia ortopédica, ocorrendo osteointegração.In orthopedic surgery there are frequently situations in which the surgeon faces severe bone losses caused by high-energy trauma, tumors or infections. Repairing these losses require knowledge about filling materials. Those materials can be biological, synthetic or metallic, with emphasis in bony grafts and biomaterial implants. The increase of the use of birds as pets is leading to an increasing number of clinical and surgical cases related to this taxon, where fractures are the most commonly observed surgical problems. The objective of this study was to evaluate clinical, radiological, macroscopic and microscopic effects of the polyurethane derived from castor oil (Ricinus communis polymer, when implanted in the humerus of domestic quails (Coturnix japonica. Twenty male and female quails, were used randomly distributed in four groups of five individuals. The birds received the implants in the left humerus, being submitted to daily physical examination during the postoperative period, immediate and biweekly radiological examination, and macroscopic and microscopic evaluation at the 15th, 30th, 60th and 90th days. Clinically, there were not observed local, regional or systemic changes. Radiologically, increase in local density was observed with no signs of changes in bone or adjacent tissue, as well as in the air sacs. Macroscopic analysis revealed that the polyurethane derived from castor oil polymer was not absorbed in none of the four groups, remaining implanted within the pneumatic bone. Its resistance, however, has changed. Microscopic examination evidenced minimum inflammatory reaction, slight fibrosis around the implants, and osteo-integration with presence of trabeculi and bone marrow inside the implants. Concluding, implants of polyurethane

  15. Comparative Bio-activity Guided Characterization of Biocide from Jatropha curcas and Ricinus communius L Seeds Oil

    Directory of Open Access Journals (Sweden)

    Asnake G. Ede

    2013-09-01

    Full Text Available This study reports the characterization of biocide from Jatropha (Jatropha curca and castor (Ricinus communius L seeds oil. The biocide potential of the seeds oil was evaluated against termite (Odontotermes obesus and cockroach (Blattela germanica. The bioassay study showed that Jatropha 10% oil caused 100% mortality in 48 hrs and 72 hrs against termite and cockroach, respectively. Castor 10% oil caused 100% mortality in 60hrs and 72 hrs against termite and cockroach, respectively. The LD50 was determined to be 0.64% and 1.24% for termite and cockroach, respectively for jatropha oil after 72hrs exposure. It was determined to be 1.43% and 1.08% for termite and cockroach respectively for castor oil. The biocidal potential of the oil is statistically significant (p<0.05 when compared with blank and solvent controls at all concentration tested. Various physicochemical parameters were also evaluated in accordance with American standard testing method specifications.

  16. Quantification of TAG and DAG in lesquerella (Physaria fendleri) oil by HPLC and MS

    Science.gov (United States)

    Castor oil has many industrial uses because of its high content (90%) of the hydroxy fatty acid, ricinoleic acid (OH1218:19). Lesquerella oil containing lesquerolic acid (Ls, OH1420:111, 56.5%) is potentially useful in industry. Ten diacylglycerols (DAG) and 74 triacylglycerols (TAG) in the seed oil...

  17. Evaluation of the safety and efficacy of Lesquerella fendleri seed and oils as poultry feed additives

    Science.gov (United States)

    Lesquerella (Lesquerella fendleri (Gray) Wats) is an oil seed plant capable of growth over a large geographic area of the southwestern U.S. The seed oil contains hydroxyfatty acids, useful in a variety of industrial products, and can replace imported castor bean oil (Ricinus communis L.). Lesquere...

  18. Identification of Drying Oils in Paints by Gas-Liquid Chromatography.

    Science.gov (United States)

    1982-06-01

    Stearic 4. Oleic 5. Linoleic 6. Impurity 7. Ricinoleic Figure 2. Chromatogram of castor oil methyl ester. 7 DISTRIBUTION FOR MERADCOM REPORT 2360 No...as methyl esters shown on the chromatogram. D D W 103 ENtTIo* OF 0 NOV 4s IS o06IErTE UNCLASSIFIED SECURITY CLASSIFICATION OF TfIS PAGE tfta Date...ILLUSTRATIONS Figure Title Page I Chromatogram of Soybean Oil Methyl Ester 6 2 Chromatogram of Castor Oil Methyl Ester 7 TABLES Table Title Page I Drying Oils

  19. IN VITRO REGENERATION CASTOR (RICINUS COMMUNIS L.) USING COTYLEDON EXPLANTS

    Science.gov (United States)

    A novel plant regeneration protocol was established for castor (Ricinus communis L.), an important oilseed crop. Mature seed-derived cotyledon explants produced adventitious shoots when placed on Murashige and Skoog (MS) medium containing thidiazuron (TDZ). The rate of shoot regeneration was maximal...

  20. Exotic Physics at the LHC with CASTOR in CMS

    CERN Document Server

    Norbeck, Edwin; Gladysz-Dziadus, Ewa; Panagiotou, Apostolos; Katsas, Panagiotis

    2007-01-01

    If CASTOR does not find events that can be identified with the anomalous cosmic-ray events, this assumption may need to be reconsidered. Pb-Pb collisions with the LHC will have an energy 28 times that of Au-Au collisions studied at RHIC. With this huge increase in energy a wealth of new phenomena is almost assured. Be...

  1. GNS Castor V/21 Headspace Gas Sampling 2014

    Energy Technology Data Exchange (ETDEWEB)

    Winston, Philip Lon [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-01-01

    Prior to performing an internal visual inspection, samples of the headspace gas of the GNS Castor V/21 cask were taken on June 12, 2014. These samples were taken in support of the CREIPI/Japanese nuclear industry effort to validate fuel integrity without visual inspection by measuring the 85Kr content of the cask headspace

  2. The influence of the type of oil phase on the self-assembly process of ¿-oryzanol + ß-sitosterol tubules in organogel systems

    NARCIS (Netherlands)

    Sawalha, H.I.M.; Margry, G.; Adel, den R.; Venema, P.; Bot, A.; Flöter, E.; Linden, van der E.

    2013-01-01

    Mixtures of ¿-oryzanol and ß-sitosterol were used to structure different oils (decane, limonene, sunflower oil, castor oil and eugenol). The ¿-oryzanol and ß-sitosterol mixtures self-assemble into double-walled hollow tubules (~10 nm in diameter) in the oil phase, which aggregate to form a network r

  3. 蓖麻种质资源创新及育种方向研究%Germplasm Resource Innovation and Breeding Direction of Castor

    Institute of Scientific and Technical Information of China (English)

    张宝贤; 王光明; 刘红光; 谭德云; 刘婷婷; 孙慧博

    2013-01-01

    Castor is dicotyledonous annual or perennial herb,which is originally produced in eastern Affica,and successively introduced to Asia,America and Europe.Because of wide adaptability and high survival rate,it is widely grown in various countries,being one of the world's ten most important oil crops.Castor has very wide application range,which is recognized as the most promising plant oil in deep processing instead of oil.It has very high development and utilization value,and has been paid attention by a large number of researches.However,the current international castor seed breach is serious,so the development and utilization of castor industry is restricted.Castro breeding research in China began in early 1950s.Currently,castor breeding technology and variety yield level in China have reached international advanced level.Although great improvement has been made,there still have space in many ways.Based on long-term castor breeding practice,the paper discusses the feasibility and importance of using wild resources,native variety and imported varieties to improve and innovate germplasm resources of castor,and breed disease-resistant inbred lines and hybrids.According to regional characteristics of castor cultivation in China,the main breeding objectives including high yield and high oil,suitable for mechanized cultivation,high resistance and strong stress tolerance are put forward in the paper.%蓖麻为双子叶一年生或多年生草本植物,原产于非洲东部,先后传入亚洲、美洲和欧洲.因其适应性广、存活率高,故广泛存在于各国家,是世界十大重要油料作物之一.蓖麻油应用范围十分广泛,在替代石油的深加工方面是公认的最有前景的植物油,其综合开发利用的经济价值极高,已被众多研究者所瞩目.但是,目前国际上蓖麻籽缺口严重,使得蓖麻产业的开发利用受到较大限制.我国蓖麻育种研究工作始于上世纪50年代初,目前,我国蓖麻育种技术及品

  4. Polímero derivado de mamona acrescido de cálcio, associado ou não à medula óssea autógena na reparação de falhas ósseas Castor oil plant polymer and calcium associated or not to autogenous bone marrow in bone gaps repair

    Directory of Open Access Journals (Sweden)

    Ricardo Junqueira Del Carlo

    2003-12-01

    ítio heterotópico, o implante foi incapaz de osteoindução e histologicamente, em ambos os sítios de implantação foram identificadas células gigantes e tecido fibroso envolvente.In order to evaluate tissue repair after the use of castor oil polymer implant additioned with 40% sodium carbonate, isolated or associated to autogenous bone marrow in heterotopic site and in experimental bone gaps in radii of rabbits, 30 White New Zealand rabbits were submitted to bilateral radial ostectomy. In 15 rabbits the bone gap of the right side was filled with polymer cylinders (group P of similar size of the gaps; the remaining rabbits received autogenous bone marrow with the implant (group M. The bone defects of the left limb did not receive any treatment and served as control. Six rabbits received 6 implants in the Rectus abdominus muscle (heterotopic site and in three of these rabbits the implants was associated with bone marrow. In the radiographic study both groups presented increased radiopacity at the implant site without bone axis deviation or resorption of the receptor bone ends. Group P presented irregular calcification areas at the peripheral region and over the polymer. Group M presented a more intense, regular and precocious radiopacity pattern in relation to group P. In microscopical evaluation there was evidence of immature bone tissue formation tending to organize itself, isolated sprouts of neoformed bone over the polymer and its superficial pores. It was concluded that implant allows osteogenenesis and osteoconduction in bone gaps, and bone formation was progressive, especially when additioned bone marrow aspirate; there was capillary, perivascular tissue and osteoprogenitor cells migrating into the pores; with fibrovascular tissue permeating implant surface; implants incorporation was slowly and was found incomplete until 9 weeks; the implant was able to induce foreign body reaction without toxic or secondary reactions to its presence. In heterotopic and orthotopic

  5. Comparison between jojoba oil and other vegetable oils as a substitute to petroleum

    Energy Technology Data Exchange (ETDEWEB)

    El Kinawy, O. [National Research centre, Dokki, Cairo (Egypt)

    2004-06-15

    Jojoba oil and other vegetable oils, such as soybean, sunflower and castor oils, were evaluated to be used as lubricants. Three standard mineral lubricating oils were considered in this study as reference. The essential parameters tested for comparison were the oil viscosity, viscosity index, and viscosity--temperature and shear rate--shear stress relationships. The effect of excessive heating on the vegetable oils' stability was studied and the corresponding parameters were also measured. Jojoba oil was found to be the best among all tested oils, whereas it gave the minimum change in viscosity gradient and hence the highest viscosity index. There was a linear relation between shear rate and shear stress of all oils before and after heat deterioration. Therefore, these oils were considered as Newtonion liquids. However, the oil viscosity, as well as the rate of viscosity variation with temperature, ({delta}{sup '}{eta}/{delta}{tau}) were affected by heat deterioration being lowered in value, in case of jojoba oil, and higher value, in case of castor oil. Jojoba oil was examined for other important properties for its use as a lubricant, such as refractive index, acid value, peroxide value, saponification value, iodine value, flash, fire and pour points. (author)

  6. Detection of olive oil adulteration by low-field NMR relaxometry and UV-Vis spectroscopy upon mixing olive oil with various edible oils

    Directory of Open Access Journals (Sweden)

    S. Ok

    2017-03-01

    Full Text Available Adulteration of olive oil using unhealthy substitutes is considered a threat for public health. Low-field (LF proton (1H nuclear magnetic resonance (NMR relaxometry and ultra-violet (UV visible spectroscopy are used to detect adulteration of olive oil. Three different olive oil with different oleoyl acyl contents were mixed with almond, castor, corn, and sesame oils with three volumetric ratios, respectively. In addition, Arbequina olive oil was mixed with canola, flax, grape seed, peanut, soybean, and sunflower seed oils with three volumetric ratios. Transverse magnetization relaxation time (T2 curves were fitted with bi-exponential decaying functions. T2 times of each mixture of olive oils and castor oils, and olive oils and corn oils changed systematically as a function of volumetric ratio. To detect the adulteration in the mixtures with almond and sesame oils, both LF 1H NMR relaxometry and UV-Vis spectroscopy were needed, where UV-Vis-spectroscopy detected the adulteration qualitatively. In the mixtures of Arbequina olive oil and flax, peanut, soybean, and sunflower seed oils, both T21 and T22 values became longer systematically as the content of the olive oil was decreased. The unique UV-Vis maximum absorbance of flax oil at 320.0 nm shows the adulteration of olive oil qualitatively.

  7. MIT Orbital Transfer Vehicle (MOTV): CASTOR Satellite: Design Document

    Science.gov (United States)

    2010-11-18

    mitsat_analysis). November 18, 2010 16.83 CASTOR Design Document Page 222 As such, the software allows the user to import solids from Solidworks...lunar phenomenon: Outgassing is the venting of elements and molecules such as radon , nitrogen, carbon monoxide, and carbon oxide from the moon‘s...of spectroscopy measurements are be done by alpha particle spectrometers, mass spectrometers; also, radon and muon emissions could be measured as

  8. Results on CASTOR Performance during LHC Run 2

    CERN Document Server

    CMS Collaboration

    2016-01-01

    The intercalibration of the gains of the fine mesh PMT's using beam-halo muons is discussed, this in combination with results of a study on the noise and baseline. Two methods on obtaining gain correction factors for reweighing the gains between different high voltage settings are compared. Results on the efficiency of a CASTOR jet trigger are compared for LHC Run 2 collision data and Monte Carlo event generator predictions.

  9. Castor bean (Ricinus communis L.) as a potential environmental bioindicator.

    Science.gov (United States)

    Mendes, M G; Santos Junior, C D; Dias, A C C; Bonetti, A M

    2015-10-21

    Biomonitoring of air quality using living organisms is a very interesting approach to environmental impact assessment. Organisms with a vast distribution, such as plants, are widely used for these purposes. The castor bean (Ricinus communis L.) is an oleaginous plant that can potentially be used as a bioindicator plant owing to its rapid growth and large leaves, which have a wide surface area of contact with the air and the pollutants therein. This study investigated the the bioindicator potential of the castor bean by performing several tests. We observed statistically significant differences in the concentrations of chlorophyll a and b in the leaves of plants in polluted areas compared to that in the control group plants, which were located in a pollution-free area. Leaves of plants in the former group had higher peroxidase activity and showed a greater buffering ability than those of plants in the control group. The pKa values obtained via buffering capacity tests, revealed the presence of aminoazobenzene (an industrial dye) in leaves of R. communis. Genotoxicity was evaluated through the comet assay technique and revealed that other than some differences in DNA fragmentation, there is no statistically significant difference in this parameter between places analyzed. Our data indicate that R. communis can be a highly useful biological indicator. Further, we hypothesized that the castor bean can be a potential candidate for phytoremediation owing its physiological buffering capacity when exposed to substantial pollution.

  10. Mining whole genomes and transcriptomes of Jatropha (Jatropha curcas) and Castor bean (Ricinus communis) for NBS-LRR genes and defense response associated transcription factors.

    Science.gov (United States)

    Sood, Archit; Jaiswal, Varun; Chanumolu, Sree Krishna; Malhotra, Nikhil; Pal, Tarun; Chauhan, Rajinder Singh

    2014-11-01

    Jatropha (Jatropha curcas L.) and Castor bean (Ricinus communis) are oilseed crops of family Euphorbiaceae with the potential of producing high quality biodiesel and having industrial value. Both the bioenergy plants are becoming susceptible to various biotic stresses directly affecting the oil quality and content. No report exists as of today on analysis of Nucleotide Binding Site-Leucine Rich Repeat (NBS-LRR) gene repertoire and defense response transcription factors in both the plant species. In silico analysis of whole genomes and transcriptomes identified 47 new NBS-LRR genes in both the species and 122 and 318 defense response related transcription factors in Jatropha and Castor bean, respectively. The identified NBS-LRR genes and defense response transcription factors were mapped onto the respective genomes. Common and unique NBS-LRR genes and defense related transcription factors were identified in both the plant species. All NBS-LRR genes in both the species were characterized into Toll/interleukin-1 receptor NBS-LRRs (TNLs) and coiled-coil NBS-LRRs (CNLs), position on contigs, gene clusters and motifs and domains distribution. Transcript abundance or expression values were measured for all NBS-LRR genes and defense response transcription factors, suggesting their functional role. The current study provides a repertoire of NBS-LRR genes and transcription factors which can be used in not only dissecting the molecular basis of disease resistance phenotype but also in developing disease resistant genotypes in Jatropha and Castor bean through transgenic or molecular breeding approaches.

  11. Demodex castoris sp. nov. (Acari: Demodecidae) parasitizing Castor fiber (Rodentia), and other parasitic arthropods associated with Castor spp.

    Science.gov (United States)

    Izdebska, Joanna N; Fryderyk, Sławomira; Rolbiecki, Leszek

    2016-02-11

    A new species of demodecid mite, Demodex castoris sp. nov. (Acari: Prostigmata: Demodecidae), is described based on adult stages from the skin of the nasal region of the Eurasian beaver Castor fiber Linnaeus, 1758, collected in Poland. This is the first detection of a representative demodecid mite in rodents of the suborder Castorimorpha and also represents the first detection of a skin mite in Eurasian beavers. The new species is a small skin mite (average 173 µm in length) characterized by sexual dimorphism related to body proportions. D. castoris sp. nov. was observed in 4 out of 6 beavers examined (66.6%), with a mean intensity of 10.8 and an intensity range of 2-23 ind. host(-1). This paper also contains a checklist of parasitic arthropods known from Castor spp.

  12. Effects of dietary supplementation of fish and vegetable oils on the growth performance and muscle compositions of the freshwater prawn Macrobrachium rosenbergii

    Directory of Open Access Journals (Sweden)

    T. Muralisankar

    2014-03-01

    Full Text Available The present investigation was conducted to assess the suitability of three vegetable oils (sunflower oil, coconut oil and castor oil as an alternative dietary lipid source for cod liver oil to culture Macrobrachium rosenbergii post larvae (PLs. The experimental feeds contained 40% protein with separately incorporated three vegetable oils and cod liver oil. The feeding trial was conducted on M. rosenbergii PL for 60 days. In the final day of the experimental period, the survival rate, weight gain, length gain, specific growth rate and protein efficiency ratio of prawns showed no significance (P > 0.05 between sunflower oil and cod liver oil incorporated feed fed groups. The coconut oil and castor oil showed lower performance when compared with cod liver oil. The present result showed biochemical accumulation of total protein, amino acids, carbohydrate and lipid in experimental groups. Also there is no significant difference in ash and mineral (Na+ and K+ contents. Among the tested diets, the recorded growth rate and biochemical constituents of sunflower oil and cod liver oil incorporated feed fed groups were similar. The present results revealed that the sunflower oil was on par with cod liver oil. Hence, the sunflower oil can be incorporated in feed formulation for M. rosenbergii PL culture. It can be concluded that the coconut oil and castor oil are not ideal vegetable lipid source with these concentrations which produced lower performance in survival, growth and biochemical compositions of M. rosenbergii PL.

  13. Efficacy and insecticidal properties of some essential oils against Caryedon serratus (Oliver)-a storage pest of groundnut.

    Science.gov (United States)

    Harish, G; Nataraja, M V; Holajjer, Prasanna; Thirumalaisamy, P P; Jadon, K S; Savaliya, S D; Padavi, R D; Koradia, V G; Gedia, M V

    2014-11-01

    During storage groundnut is attacked by number of stored grain pest and management of these insect pests particularly bruchid beetle, Caryedon serratus (Oliver) is of prime importance as they directly damage the pod and kernels. Hence, some essential oils were tested for their insecticidal and fungicidal properties. Highest total bruchid mortality was recorded with the application of neem oil and pongamia oil at 10% (v/w) concentration and lowest in eucalyptus oil at 5% (v/w). Number of eggs laid was recorded 2.3 in neem oil 10% (v/w) which was lowest and significantly superior over untreated control and was at par with castor oil 10% (v/w) which recorded 2.5 eggs per 100 g of groundnut pods. There was no adult emergence in the groundnut pods treated with castor oil, eucalyptus oil, neem oil and pongamia oil at 10% (v/w) concentration. Groundnut pods treated with castor oil, eucalyptus oil, neem oil and pongamia oil at 10% (v/w) and neem oil at 5% (v/w) concentrations recorded no damage to pods and kernels and also zero per cent weight loss. These oils effectively influenced groundnut bruchid establishment and reduce damage besides reduction in aflatoxin contamination.

  14. Identification and functional expression of a type 2 acyl-CoA:diacylglycerol acyltransferase (DGAT2) in developing castor bean seeds which has high homology to the major triglyceride biosynthetic enzyme of fungi and animals.

    Science.gov (United States)

    Kroon, Johan T M; Wei, Wenxue; Simon, William J; Slabas, Antoni R

    2006-12-01

    Seed oil from castor bean (Ricinus communis) contains high amounts of hydroxy fatty acid rich triacylglycerols (TAGs) that can serve as raw material for production of bio-based products such as nylon, cosmetics, lubricants, foams, and surfactants. Diacylglycerol acyltransferase (DGAT) catalyses the terminal reaction in the acyl-CoA dependent Kennedy pathway of triglyceride biosynthesis. There is still some debate whether there are three or four enzymes in yeast that have DGAT activity and catalyse the synthesis of TAG but of these the DGAT2 homologue Dga1 contributes in a major way to TAG biosynthesis. Here we report on the cloning of a cDNA for DGAT2 from castor bean and prove its biological activity following expression in yeast and enzymatic assays using diricinolein as the acceptor and ricinoleoyl-CoA as the donor. Previous reports of DGAT in castor have focussed on DGAT1 which has little amino acid sequence homology to DGAT2. Expressional studies demonstrate that DGAT2 is 18-fold more highly expressed in seeds than in leaves and shows temporal specific expression during seed development. In contrast, DGAT1 shows little difference in expression in seeds versus leaves. We conclude that in castor bean DGAT2 is more likely to play a major role in seed TAG biosynthesis than DGAT1.

  15. An innovative European integrated project: Castor-CO2 from capture to storage

    NARCIS (Netherlands)

    Thiez, P.L.; Mosditchian, G.; Torp, T.; Feron, P.; Ritsema, I.; Zweigel, P.; Lindeberg, E.

    2005-01-01

    This chapter gives an overview of the CASTOR (CO2, from Capture to Storage) R and D project, funded by the European Union (EU) under the 6th Framework Program. With a partnership involving Industry and Research organizations, CASTOR aims at developing new technologies for post-combustion capture and

  16. Novo cultivar de mamona: IAC-226(Tarabay New castor bean cultivar IAC-226 (Tarabay

    Directory of Open Access Journals (Sweden)

    Angelo Savy Filho

    1990-01-01

    Full Text Available Este trabalho descreve um novo cultivar de mamona (Ricinus communis 1., IAC-226 (Tarabay originado de linhagem pura, obtida do cruzamento controlado entre o 'Pindorama' e o 'Campinas': trata-se de germoplasma adaptado às condições climáticas normais de cultura no Estado de São Paulo, material de porte alto (250-350cm, diâmetro de copa de 215cm e ciclo vegetativo médio (180 dias, a partir da emergência. A produção econômica é dada pelos racemos primários, secundários, terciários e quaternários, com 19, 30, 23 e 28% da produção total respectivamente, elevado potencial produtivo (2.681kg/ha de sementes e 1.233kg/ha de óleo, e frutos indeiscentes.The characteristics of a new castor bean (Ricinus communis L. cultivar, named IAC-226 (Tarabay, obtained by hybridization between 'Pindorama' and 'Campinas', and selected by the pedigree method, are reported. The origin, characteristics of the plant and fruits such as seed weight and yield are described. Remarkable traits are: tall height indehiscent fruits, adaptation and outstanding yield ability with mean value of 2,681kg of seeds/ha and 1,233kg of oil/ha.

  17. Supply chain management of the castor biodiesel in the Bahia state, Brazil; Gestao da cadeia de suprimentos do biodiesel de mamona no estado da Bahia

    Energy Technology Data Exchange (ETDEWEB)

    Freires, Francisco G.M.; Goncalo, Thomas E.E.; Oliveira, Danillo R.S.B. [Universidade Federal do Vale do Sao Francisco (UNIVASF), Juazeiro, BA (Brazil)], E-mail: francisco.gaudencio@univasf.edu.br

    2009-07-01

    In front of the global trend for developing new ways of energy that pollute less and are renewable, Brazil emerges as a major actor in the development and use of technology for the production of biofuels. In the context of the potential of semi-arid to produce some oil used in production, the Brazilian government is enabling the production of Northeastern region. The State of Bahia is the largest producer of castor oil from Brazil, with an estimated production of 102.8 thousand tonnes of grain in the season 2008/2009 (CONAB, 2009). The development of the sector depends on appropriate government actions to support their competitive sustainability, and encouraging the improvement of management techniques in all involved. In that scenario, the logistics contributes to the development of this sector through the supply chain management. One conclusion is that the competitiveness and sustainability of the supply chain of castor in the Semi-arid of Bahia practices depends on the adoption of integrated logistics, without which the current failures prevent the consolidation of governmental objectives defined. (author)

  18. Castor Bean Cereal Based Bio-Organic-Inorganic Compound Fertilizers and Use%蓖麻粕基生物有机无机复混肥及其应用

    Institute of Scientific and Technical Information of China (English)

    陈绍荣; 邵建华; 赵立新; 刘园园

    2014-01-01

    A brief account is given of the properties and features of castor bean cereal based bio-organic-inorganic compound fertilizers.By field experiment of fertilizer efficiency with corn, rice and peanut , it is proved that castor bean cereal based bio-organic-inorganic compound fertilizers have better effects on increasing production and improving the properities of soil, and can be widely applied to grain and oil crops.%简要介绍了蓖麻粕基生物有机无机复混肥的性能及特点。通过玉米、水稻、花生大田肥效试验,结果证明蓖麻粕基生物有机无机复混肥具有较好的增产改土效果,可在粮油作物上推广应用。

  19. Synthetic technology of castor oleic acid Trimethylolpropane ester%蓖麻油酸三羟甲基丙烷酯的合成工艺条件及性能

    Institute of Scientific and Technical Information of China (English)

    焦体; 胡文云; 唐志辉; 周诗磊; 邹晨

    2012-01-01

    以蓖麻油和三羟甲基丙烷为原料,通过皂化,酯化合成蓖麻油酸三羟酯,研究了原料配比,催化剂用量,反应温度,反应时间等对酯化反应的影响,最佳条件为:蓖麻油与三羟甲基丙烷的摩尔比为5∶4,,催化剂用量为蓖麻油酸质量的0.5%,反应温度180 ~ 200℃,反应时间4h.生成的蓖麻油酸三羟甲基丙烷酯为黄色透明液体,产率为86.48%,用红外光谱进行了定性分析,证明了目标产物的存在,采用了热重/差热综合热分析仪研究了其热稳定性,采用了运动粘度测定仪研究了其粘温性能.结果表明:其润滑性能、热稳定性、粘温性能满足工艺润滑油基础油的要求.%With castor oil and Trimethylolpropane as raw material, castor oleic acid ester was synthesized by the saponification and esterification. The ratio of raw material, catalyst dosage, reaction temperature and reaction time on the esterification of influence was studied. And the best conditions were as follows; castor oil and Trimethylolpropane mole ratio of 5: 4, catalyst dosage of the mass of oleic acid castor for 0. 5 % , reaction temperature 180-200 °C , reaction time 4 h. The Castor oleic acid Trimethylolpropane ester is a kind of yellow transparent liquid, production rate is 86.48%. It is proved the existence of the target product with infrared spectra of qualitative analysis. The results show that; the lubrication properties, thermal stability, glue temperature performance meet the technological requirements of base oil lubricating oil.

  20. Performance of the CASTOR calorimeter at CMS during Run II of LHC

    CERN Document Server

    Van De Klundert, Merijn H F

    2016-01-01

    The detector has pseudorapidity borders at -5.2 and -6.6. An overview is presented on the various aspects of CASTOR's performance and their relations during LHC Run 2. The equalisation of CASTOR's channels is performed using beam-halo muons. Thereafter, CASTOR's pedestal spectrum is studied. It is shown that noise estimates which are extracted using a fit, give on average a 10\\% lower threshold than statistical estimates. Gain correction factors, which are needed for the intercalibration, are obtained using a statistical, in-situ applicable method. The results of this method are shown to be reasonably consistent with laboratory measurements. Penultimately the absolute calibration is discussed, with emphasis on the relation between the scale uncertainty and CASTOR's alignment. It is shown that the alignment's contribution to the systematic uncerta...

  1. Moisture sorption isotherms of castor beans. Part 2: Thermodynamic properties

    Directory of Open Access Journals (Sweden)

    André L. D. Goneli

    Full Text Available ABSTRACT Knowledge on the water sorption within agricultural products is extremely important for decision making during post-harvest procedures. In order to improve this knowledge, thermodynamic properties regarding water sorption provide useful data. Thermodynamic properties of castor beans, related to sorption, were determined. Static gravimetric technique under different conditions of temperature (25, 35, 45 and 55 ± 1 °C was used. Saturated salt solutions in the range of 37-87% ± 2% were utilized to create the required controlled humidity environment. After the sorption procedure, differential enthalpy, differential entropy and Gibbs free energy of this process were calculated and decreased with increased values of equilibrium moisture content.

  2. ARTICLE - Inbreeding depression in castor bean (Ricinus communis L. progenies

    Directory of Open Access Journals (Sweden)

    Milton Krieger

    2012-12-01

    Full Text Available The purpose of this study was to investigate inbreeding depression (DE in castor bean. From a population derived from the Guarani cultivar, 60 mother plants were sampled. Three types of progenies were obtained from each one: from self-pollination (AU, from crosses (CR and from open pollination (PL. Grain yield of the progenies was evaluated in two locations. There was a strong interaction of progenies x locations, which led to obtaining estimates within each location. Broad variation was observed in inbreeding depression, with mean values of 6.7% and 13.4%, comparing AU progenies with PL progenies. It was observed that the population has high potential for selecting promising inbred lines. The frequency of mother plants generating progenies with simultaneous high general combination capacity and low inbreeding depression was low. Recurrent selection will increase the occurrence of parent plants associating these two properties, which is necessary for obtaining superior synthetic varieties.

  3. CASTOR3D: linear stability studies for 2D and 3D tokamak equilibria

    Science.gov (United States)

    Strumberger, E.; Günter, S.

    2017-01-01

    The CASTOR3D code, which is currently under development, is able to perform linear stability studies for 2D and 3D, ideal and resistive tokamak equilibria in the presence of ideal and resistive wall structures and coils. For these computations ideal equilibria represented by concentric nested flux surfaces serve as input (e.g. computed with the NEMEC code). Solving an extended eigenvalue problem, the CASTOR3D code takes simultaneously plasma inertia and wall resistivity into account. The code is a hybrid of the CASTOR_3DW stability code and the STARWALL code. The former is an extended version of the CASTOR and CASTOR_FLOW code, respectively. The latter is a linear 3D code computing the growth rates of resistive wall modes in the presence of multiply-connected wall structures. The CASTOR_3DW code, and some parts of the STARWALL code have been reformulated in a general 3D flux coordinate representation that allows to choose between various types of flux coordinates. Furthermore, the implemented many-valued current potentials in the STARWALL part allow a correct treatment of the m  =  0, n  =  0 perturbation. In this paper, we outline the theoretical concept, and present some numerical results which illustrate the present status of the code and demonstrate its numerous application possibilities.

  4. Development of nine new microsatellite loci for the American beaver, Castor canadensis (Rodentia: Castoridae), and cross-species amplification in the European beaver, Castor fiber

    Science.gov (United States)

    Pelz-Serrano, K.; Munguia-Vega, A.; Piaggio, A.J.; Neubaum, M.; Munclinger, P.; PArtl, A.; van Riper, Charles; Culver, M.

    2009-01-01

    We developed nine new nuclear dinucleotide microsatellite loci for Castor canadensis. All loci were polymorphic, except for one. The number of alleles ranged from two to four and from five to 12 in populations from Arizona and Wisconsin, respectively. Average heterozygosity ranged from 0.13 to 0.86 per locus. Since cross-species amplification in Castor fiber was successful only in four loci, we tested also nine recently published C. canadensis loci in the Eurasian species. Eight of the published loci amplified; however, three were monomorphic. The number of alleles was lower in C. fiber than in C. canadensis at all loci tested. ?? 2009 Blackwell Publishing Ltd.

  5. Produtividade da mamona irrigada com esgoto doméstico tratado Productivity of castor bean irrigated with treated domestic sewage

    Directory of Open Access Journals (Sweden)

    Neyliane C. de Souza

    2010-05-01

    Full Text Available A mamoneira (Ricinus communis L., oleaginosa de relevante importância econômica e social no Nordeste, apresenta-se como alternativa para a produção do biodiesel. O experimento objetivou avaliar, em escala real, os aspectos produtivos da cultura da mamona irrigada com esgoto doméstico tratado. Empregou-se o sistema de microaspersão; a delimitação experimental foi de quatro repetições e quatro tratamentos: T1: água do poço e adubação recomendada; T2: esgoto doméstico tratado e adubação recomendada; T3: somente esgoto doméstico tratado e T4: esgoto doméstico tratado e metade da adubação recomendada. Verificou-se que as unidades irrigadas com esgoto tratado superaram as irrigadas com água, em quase todas as variáveis analisadas. A produtividade foi maior nos tratamentos irrigados com esgoto e adubação (T2 e (T4, alcançando produtividade de 1.986 e 1.412 kg ha-1, respectivamente. O teor de óleo contido nas sementes foi analisado e não apresentou nenhuma diferença significativa entre os tratamentos com adubação (T1, T2 e T4, sendo que o tratamento com esgoto tratado (T3 forneceu baixíssimos teores de óleo na semente.The castor bean (Ricinus communis L., an oil crop of economic and social importance for the Northeast region of Brazil, can be used for biodiesel production. The experiment aimed to evaluate, at a realistic scale, the productive aspects of the castor bean irrigated with treated sewage. Microsprinkler irrigation method was selected, and the experimental set-up consisted of four repetitions and four different treatments: well water and recommended fertilization (T1; treated wastewater and recommended fertilization (T2; treated wastewater without external recommended fertilization (T3; and treated wastewater and half of recommended fertilization (T4. It was found that units irrigated with treated sewage exceeded the ones irrigated with well water in almost all variables. The highest productivities were in the

  6. The role of CASTOR calorimeter in the forward physics program with CMS detector

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Wagner de Paula [Universidade do Estado do Rio de Janeiro (UERJ), RJ (Brazil)

    2009-07-01

    Full text. The CMS Collaboration at LHC/CERN envisages to carry out a broad program in Forward Physics at the TeV scale. To reach this goal, two forward subsystems, CASTOR and ZDC, have been built and installed and a project of a proton tagger, the FP420, is under development. CASTOR (Centauro And STrange Object Research) is a longitudinally and azimuthally segmented calorimeter, placed 14.3 m away from the CMS interaction point and covering the pseudo rapidity region 5:2 < |{eta}| < 6:6. Made up of alternating layers of tungsten and quartz plates, it comprises an electromagnetic and a hadronic section, which overall amount to 10.5 {lambda}. CASTOR will provide fast and good resolution measurements of energy and position of the jets, as well as measurements of the energy flux in the forward region. Originally conceived for the heavy ions program of LHC, it has latter on been incorporated into the pp program, of special interest to the Brazilian group in the Collaboration, which has contributed in many aspects to the CASTOR project. In this presentation we intend to show how CASTOR will play a central role in the Forward Physics analyzes. Especially in the LHC early days, when no proton tagging will be available at CMS to characterize diffractive and exclusive signatures.(author)

  7. Further implementation of the user space file system based on CastorFS and Xrootd

    CERN Document Server

    Jiao, Manjun

    The LHC (Large Hadron Collider) experiments use a mass storage system for recording petabytes of experimental data. This system is called CASTOR[1] (CERN Advanced STORage manager) and it is powerful and convenient for many use cases. However, it is impossible to use standard tools and scripts straight away for dealing with the files in the system since the users can access the data just in the way of using command-line utilities and parsing their output. Thus a complete POSIX filesystem – CastorFS[2] is developed based on the FUSE[3] (File System in Userspace) and two CASTOR I/O libraries-RFIO (Remote File I/O) library and NS (Name Server) library. Although it is applied successfully, it has serious limitation of wide application because the I/O protocols it relies on are very old. Each time the CASTOR side receives the calling for accessing data files from the user side, the load of the CASTOR side system will increase quickly even out of its upper bound and the system would crash. Besides that, those two ...

  8. Naturally occurring and experimentally induced castor bean (Ricinus communis) poisoning in ducks

    Science.gov (United States)

    Jensen, W.I.; Allen, J.P.

    1981-01-01

    Castor bean (Ricinus communis) poisoning accounted for the death of several thousand ducks in the Texas panhandle in the fall and winter months of 1969-1971. Signs of intoxication resembled those of botulism, except for mucoid, blood-tinged excreta. The most common lesions were severe fatty change in the liver, widely distributed internal petechial hemorrhages or ecchymoses, and catarrhal enteritis. Nearly intact castor beans were found in the stomach of one duck during field necropsy. Fragments of seed coat resembling castor bean were found in the stomachs of 10 of 14 ducks examined in the laboratory. Clinical signs and postmortem lesions observed in wild ducks were induced experimentally in mallards (Anas platyrhynchos) by force-feeding intact castor beans. Toxicity titrations were erratic, but the LD50 appeared to be between three and four seeds. The mouse toxicity test, used to detect Clostridium botulinum toxin in the blood serum of intoxicated ducks, was negative in every case. Hemagglutination and precipitin tests generally failed to detect castor bean in extracts of excreta or intestinal contents of experimentally intoxicated ducks.

  9. Adição de torta de mamona em substratos na aclimatação de mudas micropropagadas de bananeira Effect of addition of castor bean pie in substrates in acclimatization of micropropagated banana plantlets

    Directory of Open Access Journals (Sweden)

    Adriana Novais Martins

    2011-03-01

    Full Text Available A utilização de mudas micropropagadas de bananeira que oferecem qualidade genética e fitossanitária, favorecendo o desenvolvimento, instalação e uniformidade do pomar, é importante para a exploração comercial da bananicultura. O objetivo deste trabalho foi avaliar a influência da adição da torta de mamona nos substratos na aclimatação de mudas micropropagadas de bananeira da cv. Willians. O delineamento estatístico utilizado foi o inteiramente casualizado, com 10 tratamentos, sendo 2 substratos e 5 dosagens de torta de mamona (0; 6; 12; 18 e 24 g vaso-1. O substrato Vivatto Slim Plus® possibilitou o melhor desenvolvimento das plantas na aclimatação. Não são recomendadas doses superiores a 12 g planta-1 de torta de mamona misturadas ao substrato na aclimatação de mudas de bananeira.The use of micropropagated banana tree seedlings offer genetic and phytosanitary qualities, favoring the development, installation and uniformity of the yield and it is very important for the commercial exploration of banana fruits. The objective of this study was to evaluate the influence of castor oil plant pie added to the substrate in the acclimatization of micropropagated banana plantlets cv. 'Willians'. It was use the completely randomized, with 10 treatments, being 2 substrates and 5 dosages of castor oil plant pie (0; 6; 12; 18 and 24 g for each recipient. The substrate Vivatto Slim Plus® showed the best development of the plants in acclimatization processes. Dosages above 12 g of castor oil plant pie for each plant are not recommended mixed to the substrate in the acclimatization of banana tree seedlings

  10. Castor oil decoloration and No. 1 Castor oil%蓖麻油脱色与国产一号蓖麻油

    Institute of Scientific and Technical Information of China (English)

    赵学敏; 缪晓涓

    2001-01-01

    系统论述了蓖麻油脱色的有关问题,包括油中色素来源、脱色原理和最佳脱色参数(温度、时间、真空度、脱色剂及剂量),并介绍了国产一号蓖麻油的生产工艺和质量标准.

  11. Castor oil Decolorizing Technology and No1 Castor Oil in China%蓖麻油脱色与国产一号蓖麻油

    Institute of Scientific and Technical Information of China (English)

    赵学敬; 缪晓涓

    2001-01-01

    本文论述蓖麻油脱色的有关问题,包括油中色素来源、脱色原理和最佳脱色参数(温度、时间、真空度、脱色剂及剂量等)。鉴于国产一号蓖麻油产品是在蓖麻油脱色基础上研制出来的,于1989年荣获山西省优质产品奖和科技进步一等奖;但是,技术详情10余年来尚未公开介绍,现特在本文与脱色一并报道。

  12. Particles from Centauro Decay in the CASTOR Detecting System

    CERN Document Server

    Panagiotou, A D; CERN. Geneva

    1997-01-01

    Please note this ps file is TEXT ONLY, for the complete note please contact the ALICE Secretariat. To estimate the numbers of particles from the Centauro fireball, detected in the "Castor" system we should know the average multiplicities and spectra of all kinds of particles produced at the LHC Centauro. From extrapolation of features of cosmic-ray Centauros we expect at the LHC only a residual electromagnetic component: : zero or only a few g-rays or electrons in our photon detectors and much more numerous nuclear component in the hadronic part of our detectors. The nuclear component is expected to be composed mainly of non strange baryons coming from the last stage of the Centauro evolution and K+, K0 mesons, firstly emitted particles from the Centauro fireball. In contrary, in cosmic ray Centauros we have not observed kaons. Kaons, as firstly emitted particles, were lost in nuclear-electromagnetic cascade process in the atmosphere and thus the nuclear active component registered by emulsion chambers have ...

  13. Streamlining CASTOR to manage the LHC data torrent

    Science.gov (United States)

    Lo Presti, G.; Espinal Curull, X.; Cano, E.; Fiorini, B.; Ieri, A.; Murray, S.; Ponce, S.; Sindrilaru, E.

    2014-06-01

    This contribution describes the evolution of the main CERN storage system, CASTOR, as it manages the bulk data stream of the LHC and other CERN experiments, achieving over 90 PB of stored data by the end of LHC Run 1. This evolution was marked by the introduction of policies to optimize the tape sub-system throughput, going towards a cold storage system where data placement is managed by the experiments' production managers. More efficient tape migrations and recalls have been implemented and deployed where bulk meta-data operations greatly reduce the overhead due to small files. A repack facility is now integrated in the system and it has been enhanced in order to automate the repacking of several tens of petabytes, required in 2014 in order to prepare for the next LHC run. Finally the scheduling system has been evolved to integrate the internal monitoring. To efficiently manage the service a solid monitoring infrastructure is required, able to analyze the logs produced by the different components (about 1 kHz of log messages). A new system has been developed and deployed, which uses a transport messaging layer provided by the CERN-IT Agile Infrastructure and exploits technologies including Hadoop and HBase. This enables efficient data mining by making use of MapReduce techniques, and real-time data aggregation and visualization. The outlook for the future is also presented. Directions and possible evolution will be discussed in view of the restart of data taking activities.

  14. Lipid composition of organelles from germinating castor bean endosperm

    Energy Technology Data Exchange (ETDEWEB)

    Donaldson, R.P.; Beevers, H.

    1977-02-01

    Glyoxysome, endoplasmic reticulum, mitochondria, and proplastid fractions were isolated from endosperm of castor beans (Ricinus communis) germinated for 5 days at 30 C. Samples from sucrose density gradients were diluted with 0.15 M KCl and the membranes pelleted. Lipid extracts of these membranes were analyzed for phosphoglyceride, acyl lipid, and sterol content. The endoplasmic reticulum contains 1.24 ..mu..mol of phosphoglyceride per mg of protein; the mitochondria, 0.65 ..mu..mol/mg; and the glyoxysome membranes, 0.55 ..mu..mol/mg. Phosphatidyl choline and phosphatidyl ethanolamine are the most abundant lipids in all membranes studied, accounting for 70% or more of the lipid phosphorus and 50% or more of the fatty acid. Glyoxysome membranes and endoplasmic reticulum also contain phosphatidyl inositol (respectively, 9 and 17% of the lipid phosphorus) and free fatty acids (13% of the total fatty acid in each). Compared with other organelles, mitochondrial membranes have more phosphatidyl ethanolamine relative to phosphatidyl choline and are characterized by the presence of cardiolipin, in which 80% of the fatty acid is linoleate. The relative amounts of linoleate, palmitate, oleate, stearate, and linolenate in each of the phosphotoglycerides are constant regardless of the membrane source. Stimasgasterol and ..beta..-sitosterol are present in the membranes (1 to 9 nmol each/mg protein). The data provide further evidence that glyoxysome membranes are derived from the endoplasmic reticulum but at the same time indicate some differentiation.

  15. CASTOR: Centauro and strange object research in nucleus-nucleus collisions at the LHC

    Energy Technology Data Exchange (ETDEWEB)

    Angelis, A.L.S.; Bartke, J.; Bogolyubsky, M.Yu.; Gadysz-Dziadus, E.; Kharlov, Yu.V.; Kurepin, A.B.; Maevskaya, A.I.; Mavromanolakis, G.; Panagiotou, A.D.; Sadovsky, S.A.; Stefanski, P.; Wodarczyk, Z

    2001-04-01

    We present a phenomenological model which describes the formation of a Centauro fireball in the baryon-rich projectile fragmentation region in nucleus-nucleus interactions in the upper atmosphere and at the LHC, and its decay to non-strange baryons and Strangelets. Strangelets are assimilated to the 'strongly penetrating component' frequently observed accompanying hadron-rich cosmic ray events. We describe the CASTOR subdetector for the ALICE experiment at the LHC. CASTOR will probe, in an event-by-event mode, the very forward, baryon-rich phase space 5.6 {<=} {eta} {<=} 7.2 in 5.5 x A TeV central Pb + Pb collisions. It will look for events with pronounced imbalance between hadronic and photonic content and for deeply penetrating objects. We present results of simulations for the response of the CASTOR calorimeter to the passage of Strangelets.

  16. CASTOR Centauro And STrange Object Research in nucleus-nucleus collisions at the LHC

    CERN Document Server

    Angelis, Aris L S; Bogolyubsky, M Yu; Gladysz-Dziadus, E; Kharlov, Yu V; Kurepin, A B; Maevskaya, A I; Mavromanolakis, G; Panagiotou, A D; Sadovsky, S A; Stefanski, P; Wiodarczyk, Z

    2001-01-01

    We present a phenomenological model which describes the formation of a Centauro fireball in the baryon-rich projectile fragmentation region in nucleus-nucleus interactions in the upper atmosphere and at the LHC, and its decay to non-strange baryons and Strangelets. Strangelets are assimilated to the "strongly penetrating component" frequently observed accompanying hadron-rich cosmic ray events. We describe the CASTOR subdetector for the ALICE experiment at the LHC. CASTOR will probe, in an event-by-event mode, the very forward, baryon-rich phase space 5.6< eta <7.2 in 5.5*A TeV central Pb+Pb collisions. It will look for events with pronounced imbalance between hadronic and photonic content and for deeply penetrating objects. We present results of simulations for the response of the CASTOR calorimeter to the passage of Strangelets. (15 refs).

  17. Characterization of the 11S globulin gene family in the castor plant Ricinus communis L.

    Science.gov (United States)

    Chileh, Tarik; Esteban-García, Belén; Alonso, Diego López; García-Maroto, Federico

    2010-01-13

    The 11S globulin (legumin) gene family has been characterized in the castor plant Ricinus communis L. Phylogenetic analysis reveals the presence of two diverged subfamilies (RcLEG1 and RcLEG2) comprising a total of nine genes and two putative pseudogenes. The expression of castor legumin genes has been studied, indicating that it is seed specific and developmentally regulated, with a maximum at the stage when cellular endosperm reaches its full expansion (around 40-45 DAP). However, conspicuous differences are appreciated in the expression timing of individual genes. A characterization of the 5'-proximal regulatory regions for two genes, RcLEG1-1 and RcLEG2-1, representative of the two legumin subfamilies, has also been performed by fusion to the GUS reporter gene. The results obtained from heterologous expression in tobacco and transient expression in castor, indicating seed-specific regulation, support the possible utility of these promoters for biotechnological purposes.

  18. Antidiarrheal activity and acute oral toxicity of Mentha longifolia L. essential oil

    OpenAIRE

    Ghader Jalilzadeh-Amin; Massoud Maham

    2015-01-01

    Objectives: Mentha longifolia L. (Lamiaceae) is an annual herb that is used in the Iranian traditional medicine for treating stomach and intestinal disorders. The purpose of this study was to determine the protective effect of M. longifolia on experimental diarrhea in a rat model. Materials and Methods: The antidiarrheal activity of essential oil of M. longifolia (20-80 mg/kg) was investigated against castor oil-induced diarrhea in rats using loperamide as the standard reference drug. In acut...

  19. CASTOR: A dedicated detector for the detection of centauros and strangelets at the LHC

    Energy Technology Data Exchange (ETDEWEB)

    Angelis, Aris L.S.; Panagiotou, Apostolos D. [Nuclear and Particle Physics Division, Department of Physics, University of Athens (Greece)

    1997-12-01

    We present a specialized detector system, CASTOR, which, as an integral part of the ALICE experiment, will search for centauros and strangelets in central Pb+Pb collisions at the LHC. CASTOR will cover the very forward, baryon-rich pseudorapidity region 4.5{<=}{eta}{<=}6.2 and will consist of a charged particle multiplicity detector, a photon multiplicity detector and a calorimeter with electromagnetic and hadronic sections. The physics motivation is presented, along with simulation results and the detector design. The influence of the background on the identification of centauro-type events is discussed. (author)

  20. 蓖麻油的终端衍生产品-尼龙1010%Terminal Derivative Product of Castor Oil:Nylon1010

    Institute of Scientific and Technical Information of China (English)

    赵学敬

    2016-01-01

    Nylon 1010 is a material developed in China, and has important industrial applications. As the terminal product of castor oil derivatives, this paper discussed the production theory, properties, industrial application, and preparation method of products made of nylon 1010.%尼龙1010是我国研制成功的材料品种,工业用途重要。文章把它视作蓖麻油衍生产品的终端,对其产出的化工原理、各种性能、工业用途、以它为原料的制品加工方法,一一作了论述。

  1. Thermal properties measurements in biodiesel oils using photothermal techniques

    Science.gov (United States)

    Castro, M. P. P.; Andrade, A. A.; Franco, R. W. A.; Miranda, P. C. M. L.; Sthel, M.; Vargas, H.; Constantino, R.; Baesso, M. L.

    2005-08-01

    In this Letter, thermal lens and open cell photoacoustic techniques are used to measure the thermal properties of biodiesel oils. The absolute values of the thermal effusivity, thermal diffusivity, thermal conductivity and the temperature coefficient of the refractive index were determined for samples obtained from soy, castor bean, sunflower and turnip. The results suggest that the employed techniques may be useful as complementary methods for biodiesel certification.

  2. Grinding temperature and energy ratio coe cient in MQL grinding of high-temperature nickel-base alloy by using di erent vegetable oils as base oil

    Institute of Scientific and Technical Information of China (English)

    Li Benkai; Li Changhe; Zhang Yanbin; Wang Yaogang; Jia Dongzhou; Yang Min

    2016-01-01

    Vegetable oil can be used as a base oil in minimal quantity of lubrication (MQL). This study compared the performances of MQL grinding by using castor oil, soybean oil, rapeseed oil, corn oil, sunflower oil, peanut oil, and palm oil as base oils. A K-P36 numerical-control precision surface grinder was used to perform plain grinding on a workpiece material with a high-temperature nickel base alloy. A YDM–III 99 three-dimensional dynamometer was used to measure grinding force, and a clip-type thermocouple was used to determine grinding temperature. The grinding force, grind-ing temperature, and energy ratio coefficient of MQL grinding were compared among the seven veg-etable oil types. Results revealed that (1) castor oil-based MQL grinding yields the lowest grinding force but exhibits the highest grinding temperature and energy ratio coefficient;(2) palm oil-based MQL grinding generates the second lowest grinding force but shows the lowest grinding temperature and energy ratio coefficient;(3) MQL grinding based on the five other vegetable oils produces similar grinding forces, grinding temperatures, and energy ratio coefficients, with values ranging between those of castor oil and palm oil;(4) viscosity significantly influences grinding force and grinding tem-perature to a greater extent than fatty acid varieties and contents in vegetable oils;(5) although more viscous vegetable oil exhibits greater lubrication and significantly lower grinding force than less vis-cous vegetable oil, high viscosity reduces the heat exchange capability of vegetable oil and thus yields a high grinding temperature;(6) saturated fatty acid is a more efficient lubricant than unsaturated fatty acid;and (7) a short carbon chain transfers heat more effectively than a long carbon chain. Palm oil is the optimum base oil of MQL grinding, and this base oil yields 26.98 N tangential grinding force, 87.10 N normal grinding force, 119.6 °C grinding temperature, and 42.7%energy ratio coefficient

  3. Differential oxidative stress responses in castor semilooper, Achaea janata.

    Science.gov (United States)

    Pavani, Ayinampudi; Chaitanya, R K; Chauhan, Vinod K; Dasgupta, Anwesha; Dutta-Gupta, Aparna

    2015-11-01

    Balance between reactive oxygen species (ROS) and the antioxidant (AO) defense mechanisms is vital for organism survival. Insects serve as an ideal model to elucidate oxidative stress responses as they are prone to different kinds of stress during their life cycle. The present study demonstrates the modulation of AO enzyme gene expression in the insect pest, Achaea janata (castor semilooper), when subjected to different oxidative stress stimuli. Antioxidant enzymes' (catalase (Cat), superoxide dismutase (Sod), glutathione-S-transferase (GST) and glutathione peroxidase (Gpx)) partial coding sequences were cloned and characterized from larval whole body. Tissue expression studies reveal a unique pattern of AO genes in the larval tissues with maximum expression in the gut and fat body. Ontogeny profile depicts differential expression pattern through the larval developmental stages for each AO gene studied. Using quantitative RT-PCR, the expression pattern of these genes was monitored during sugar-induced (d-galactose feeding), infection-induced (Gram positive, Gram negative and non-pathogenic bacteria) and pesticide-induced oxidative stress (Bt Cry toxin). d-Galactose feeding differentially modulates the expression of AO genes in the larval gut and fat body. Immune challenge with Escherichia coli induces robust upregulation of AO genes when compared to Bacillus coagulans and Bacillus cereus in the larval fat body and gut. Cry toxin feeding predominantly induced GST upregulation in the gut. The current study suggests that though there are multiple ways of generation of oxidative stress in the insect, the organism tailors its response by insult- and tissue-specific recruitment of the antioxidant players and their differential regulation for each inducer.

  4. Virulence factors genes in enterococci isolated from beavers (Castor fiber).

    Science.gov (United States)

    Lauková, Andrea; Strompfová, Viola; Kandričáková, Anna; Ščerbová, Jana; Semedo-Lemsaddek, Teresa; Miltko, Renata; Belzecki, Grzegorz

    2015-03-01

    Only limited information exists concerning the microbiota in beaver (Castor fiber). This study has been focused on the virulence factors genes detection in enterococci from beavers. In general, animals are not affected by enterococcal infections, but they can be a reservoir of, e.g. pathogenic strains. Moreover, detection of virulence factors genes in enterococci from beavers was never tested before. Free-living beavers (12), male and female (age 4-5 years) were caught in the north-east part of Poland. Sampling of lower gut and faeces was provided according to all ethical rules for animal handling. Samples were treated using a standard microbiological method. Pure bacterial colonies were identified by matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) identification system. Virulence factors genes-gelE (gelatinase), agg (aggregation), cylA (cytolysin A), efaAfs (adhesin Enterococcus faecalis), efaAfm (adhesin Enterococcus faecium) and esp (surface protein) were tested by PCR. Moreover, gelatinase and antibiotic phenotypes were tested. Species detected were Enterococcus thailandicus, E. faecium, E. faecalis and Enterococcus durans. In literature, enterococcal species distribution was never reported yet up to now. Strains were mostly sensitive to antibiotics. Vancomycin-resistant E. faecalis EE9Tr1 possess cylA, efaAfs, esp and gelE genes. Strains were aggregation substance genes absent. Adhesin E. faecium (efaAfm) gene was detected in two of three E. faecium strains, but it was present also in E. thailandicus. Esp gene was present in EE9Tr1 and E. durans EDTr92. The most detected were gelE, efaAfm genes; in EF 4Hc1 also gelatinase phenotype was found. Strains with virulence factors genes will be tested for their sensitivity to antimicrobial enterocins.

  5. Impact of castor meal on root-knot and free-living nematodes

    Directory of Open Access Journals (Sweden)

    Cecilia Helena Silvino Prata Ritzinger

    2014-08-01

    Full Text Available Soil amendment may enhance soil quality as well as reduce plant-parasitic nematode. Despite the many applications already undertaken using castor meal, its efficiency in controlling root-knot nematodes (RKN, Meloidogyne incognita when applied to melon (Cucumis melo is still not clear. Three different amounts of castor meal (Ricinus communis applied were evaluated in microplots planted with melon either with or without RKN. The impact of castor meal on soil free-living nematode communities was also determined. Total nematode genera richness was estimated as 37 for the entire set of microplots sampled across both sampling dates. Rarefaction analysis resulted in 12 collector's curves out of the total of 30 that reached the horizontal asymptote. Univariate ANOVA with two factors yielded differences (p < 0.05 only with regard to the time factor. Simpson, Shannon, Evenness and Equitability indices showed a trend toward moderate increases by the end of the experiment, while the other indices were higher for tomato in pre-transplant sampling compared to harvest. Nematode community and diversity changed during the course of the experiment, although there was substantial confounding heterogeneity within and between the factorial combinations from the beginning. Root knot population was not reduced by the castor meal but increased throughout the period, regardless of treatment. RKN reduced melon yield, number and weight of melon.

  6. Analysis of castor by ELISAs that distinguish Ricin and Ricinus communis agglutinin (RCA)

    Science.gov (United States)

    To facilitate the analysis of castor (Ricinus communis L.) seed fractions and germplasm for ricin content, we investigated the use of enzyme-linked immunosorbent assay (ELISA) methods to differentiate between ricin toxin and the related Ricinus communis agglutinin (RCA). Both proteins are based on ...

  7. Factors affecting scent-marking behaviour in Eurasion beaver (Castor fiber)

    NARCIS (Netherlands)

    Rosell, F.; Nolet, B.A.

    1997-01-01

    We tested the hypothesis that a main function of territory marking in Eurasian beaver (Castor fiber) is defense of the territory. The results showed that: (1) beaver colonies with close neighbors scent-mark more often than isolated ones; (2) the number of scent markings increased significantly with

  8. Development and viability of a translocated beaver Castor fiber population in the Netherlands

    NARCIS (Netherlands)

    Nolet, B.A.; Baveco, J.M.

    1996-01-01

    We monitored survival, reproduction and emigration of a translocated beaver Castor fiber population in the Netherlands for five years and used a stochastic model to assess its viability. Between 1988 and 1991, 42 beavers were released in the Biesbosch National Park. The mortality was initially high

  9. Comeback of the beaver Castor fiber: An overview of old and new conservation problems

    NARCIS (Netherlands)

    Nolet, B.A.; Rosell, F.

    1998-01-01

    Due to over-hunting c. 1200 Eurasian beavers Castor fiber survived in eight relict populations in Europe and Asia at the beginning of the 20th century. Following hunting restrictions and translocation programmes in IS countries, the Eurasian beaver became re-established over much of its former range

  10. Deficiency symptoms and uptake of micronutrients by castor bean grown in nutrient solution

    Directory of Open Access Journals (Sweden)

    José Lavres Junior

    2012-02-01

    Full Text Available Castor bean is a nutrient-demanding species, but there is still little information on its micronutrient requirements. The objectives of this study were to evaluate the effects of levels of B (2.5, 12.5 and 25.0 µmol L-1, Cu (0.05, 0.25 and 0.50 µmol L-1, Mn (0.2, 1.0 and 2.0 µmol L-1 and Zn (0.2, 1.0 and 2.0 µmol L-1 in a nutrient solution on plant B, Cu, Mn and Zn concentrations and uptake, vegetative growth and fruit yield of castor bean "Iris", grown in greenhouse. The experiment was arranged in a completely randomized block design with three replicates. The first deficiency symptoms were observed for B, followed by Zn, Cu and Mn. The main changes in the cell ultrastructure due to lack of B were thickening of the cell walls and middle lamellae, distorted chloroplasts and tightly stacked thylakoids, besides the absence of starch grains. The Mn, Zn and Cu deficiencies led to disruption of chloroplasts, disintegration of thylakoids and absence of amyloplasts. The concentration and uptake of B, Cu, Mn, and Zn in castor bean plants increased with micronutrient supply in the solution. Fruit yield was drastically reduced by B and Mn deficiencies. On the other hand, the dry matter yield of the shoot and root of castor bean plants was not. In the treatment with full nutrient solution, the leaves accumulated 56 and 48 % of the total B and Mn taken up by the plants, respectively, and the seeds and roots 85 and 61 % of the total Cu and Zn taken up, respectively. This shows the high demand of castor bean Iris for B and Mn for fruit yield.

  11. Outbreaks of Chrysodeixis includens (Walker (Lepidoptera: Noctuidae in common bean and castor bean in São Paulo State, Brazil

    Directory of Open Access Journals (Sweden)

    Edson Luiz Lopes Baldin

    2014-12-01

    Full Text Available Since 2009, increasing populations of Chrysodeixis includens (Walker (Lepidoptera: Noctuidae have been observed in cultivated common bean (Phaseolus vulgaris L. and castor bean (Ricinus communis L. at the Lageado Experimental Farm, belonging to the FCA/UNESP, Botucatu, São Paulo State, Brazil. Defoliations around 80% and 50% were observed in the common bean cv. Pérola and castor bean cv. IAC-2028, respectively. Samples of individuals (caterpillars and pupae were collected in the field, and kept in laboratory until adult emergence aiming to confirm the species. These are new observations for common bean in São Paulo State and, in the case of castor bean, unpublished in Brazil. It suggests that C. includens has adapted to attack other agricultural crops, demanding attention of common bean and castor bean producers.

  12. Nitrogen balance and ruminal assessment in male and female sheeps fed rations containing castor cake under different treatments

    Directory of Open Access Journals (Sweden)

    Rafael Nogueira Furtado

    2014-12-01

    Full Text Available Was evaluated the influence of alternative methods of detoxification of castor cake on nitrogen balance and ruminal evaluation in sheep fed isocaloric and isonitrogenous experimental diets. Twenty sheep (ten males and ten females were used in five treatments (castor cake untreated, treated with limestone, treated with urea, treated with phosphate monodicalcium and autoclaved and four repetitions. For nitrogen balance we used a randomized block design, with the blocks according to the sex and the variables pH and ammonia nitrogen (NH3-N in the experimental design was split plot, with plots in the diets subplots and the collection times (0, 2, 5 and 8 hours postprandial.The treatments did not influence N intake, N urinary, urea and N-urea concentration in plasma. The Urinary N was higher in diet containing castor cake treated with phosphate monodicalcium (FOS when compared with those containing castor cake treated by autoclave (ACL. Already the nitrogen balance (BN was higher in diet ACL when compared to FOS diet. The pH and N-NH3 were within the normal range of sheep, being little affected by diet. Diets with methods of detoxification of castor cake promoted moderate changes in nitrogen balance with emphasis on the castor cake autoclaved and treated with limestone. The males sheep showed higher nitrogen balance than females.

  13. Deep-processing Technique of Castor Oil%蓖麻油深加工技术

    Institute of Scientific and Technical Information of China (English)

    李天铎; 张庆思; 刘耘

    2001-01-01

    从蓖麻油分子中羟基、酯基、烯键等官能团的化学反应出发,对种类繁多的蓖麻油化学品加工技术进行综述归类.认为加强蓖麻油化学化工基础的研究,是提升我国蓖麻油深加工技术的根本途径.

  14. Study on construction of degradable microorganisms for lubricant-castor and its bioremediation to soil%蓖麻基润滑油降解菌群的构建及对土壤的修复作用

    Institute of Scientific and Technical Information of China (English)

    王昌禄; 赵璇; 王玉荣; 孟祥云

    2011-01-01

    以添加蓖麻基润滑油的土壤为模拟实验对象,从大港油田油井附近受污染的土壤和污水中筛选出优势降解菌株,构建高效降解菌群,确定了BM-1+BM-2+BM-4+BM-5菌株为最佳组合.将菌群投加到模拟被润滑油污染的土壤中进行生物修复,以土壤生物活性及土壤呼吸强度作为考核指标,40 d后土壤含油量从89 g·kg-1下降到24 g·kg-1,降解率达73.03%,比自然条件下降解率提高34.83%.结果表明,投加该菌群的污染土壤生物修复能力强于未投加菌群的污染土壤;蓖麻基润滑油为可生物降解型油品.%Through the experiments of lubricant-castor degradation, a series of microorganisms were screened to construct a high-effective microbial consortium, and confirmed the optimal combination was BM-I+BM-2+BM-4+BM-5.Adding it to the soil polluted by lubricant-castor for biological repairing, with soil respiration intensity and biological activity of change as indicators ofbioremediation, the results showed that during the process of40-day bioremediation, the degradation rate was improved by 34.83% compared with that in nature condition, plus bacteria bioremediation of soil strength significantly larger than that without bacteria with soil samples, lubricant-castor was biodegradable oil.

  15. Natural oils and waxes: studies on stick bases.

    Science.gov (United States)

    Budai, Lívia; Antal, István; Klebovich, Imre; Budai, Marianna

    2012-01-01

    The objective of the present article was to examine the role of origin and quantity of selected natural oils and waxes in the determination of the thermal properties and hardness of stick bases. The natural oils and waxes selected for the study were sunflower, castor, jojoba, and coconut oils. The selected waxes were yellow beeswax, candelilla wax, and carnauba wax. The hardness of the formulations is a critical parameter from the aspect of their application. Hardness was characterized by the measurement of compression strength along with the softening point, the drop point, and differential scanning calorimetry (DSC). It can be concluded that coconut oil, jojoba oil, and carnauba wax have the greatest influence on the thermal parameters of stick bases.

  16. Energy-calibration of the forward calorimeter CASTOR with particle decays in the CMS experiment

    Energy Technology Data Exchange (ETDEWEB)

    Woehrmann, Hauke [Karlsruher Institut fuer Technologie (KIT), Karlsruhe (Germany)

    2012-07-01

    The CMS(Compact Muon Solenoid) experiment is a detector system to analyse hadronic collisions at the LHC(Large Hadron Collider). For studying high energy physics CMS covers a large rapidity range at LHC. One subdetector of CMS to measure in this high rapidity region around 6 is the CASTOR(Centauro And STrange Object Research) calorimeter. CASTOR has an electromagnetic(20 X{sub 0}) and hadronic(10{lambda}{sub I}) section where each is build of alternative layers of tungsten- and quartz-plates. The charged particles produce cherenkov-photons in this quartz-plates. Because of a residual magnetic field at the detector location an energy calibration is difficult. For this purpose we investigate the approach to use the electromagnetic two-body-decay of well known particles like Z or {pi}{sup 0}. Therefore we run over 50 pb{sup -1} of data and determine clean electromagnetic signals in the detector.

  17. CASTOR A Dedicated Detector for the Detection of Centauros and Strangelets at the LHC

    CERN Document Server

    Angelis, Aris L S

    1997-01-01

    Under publication in J. Phys. G: Nucl. Part. Phys. 23 (1997) 2069-2080 We present a specialised detector system, CASTOR, which, as an integral part of the ALICE experiment, will cover the search for centauros and strangelets in central Pb+Pb collisions at the LHC. CASTOR will cover the very forward, baryon-rich pseudorapidity region 4.5≤eta≤6.2 and will consist of a charged particle multiplicity detector, a photon multiplicity detector and a calorimeter with electromagnetic and hadronic sections. The physics motivation is presented, along with simulation results and the detector design. The influence of the background on the identification of centauro-type events is discussed.

  18. Growth of castor bean BRS-149 nordestina fertilized with nitrogen, phosphorus and potassium

    Directory of Open Access Journals (Sweden)

    Diva Lima de Araujo

    2009-12-01

    Full Text Available A trial was carried out in a greenhouse located at the Federal University of Campina Grande, in Campina Grande, Paraiba State, Brazil, with castor bean plants (Ricinus communis L., cv BRS Nordestina, in order to evaluate the effects of nitrogen, phosphorus and potassium on the growth. A completely randomized design with three replications and 15 treatments originated from a baconian matrix was adopted. Reference doses were 40:90:60 kg ha-1 of N:P2O5:K2O, respectively. Plant height, stem diameter, number and length of leaves were measured at 20, 40, 60, 80, 100, 120 and 140 days after planting (DAP. The unbalanced fertilization affected the development and seed production of castor bean, and the best response of the plants was observed at levels of 200 kg ha-1 de N; 150 kg ha-1 de P2O5 and 150 kg ha-1 de K2O.

  19. « Lewis Henry Morgan, Le castor américain et ses ouvrages »,

    OpenAIRE

    2011-01-01

    Compte - rendu Lewis Henry Morgan, Le castor américain et ses ouvrages », Gradhiva, 13 | 2011, 231-233.; Le présent ouvrage est la première traduction française du livre initialement publié en 1868 par Lewis Henry Morgan : The American Beaver and His Works. Cette première monographie digne de ce nom dédiée au castor a participé à la fondation de l’éthologie américaine. Mise en contexte du point de vue de l’histoire des idées par Lucienne Strivay, la traduction que nous proposent les éditions ...

  20. Biosynthesis of medium chain length poly(3-hydroxyalkanoates) (mcl-PHAs) by Comamonas testosteroni during cultivation on vegetable oils.

    Science.gov (United States)

    Thakor, Nehal; Trivedi, Ujjval; Patel, K C

    2005-11-01

    Comamonas testosteroni has been studied for its ability to synthesize and accumulate medium chain length poly(3-hydroxyalkanoates) (mcl-PHAs) during cultivation on vegetable oils available in the local market. Castor seed oil, coconut oil, mustard oil, cotton seed oil, groundnut oil, olive oil and sesame oil were supplemented in the mineral medium as a sole source of carbon for growth and PHAs accumulation. The composition of PHAs was analysed by a coupled gas chromatography/mass spectroscopy (GC/MS). PHAs contained C6 to C14 3-hydroxy acids, with a strong presence of 3-hydroxyoctanoate when coconut oil, mustard oil, cotton seed oil and groundnut oil were supplied. 3-hydroxydecanoate was incorporated at higher concentrations when castor seed oil, olive oil and sesame oil were the substrates. Purified PHAs samples were characterized by Fourier Transform Infrared (FTIR) and 13C NMR analysis. During cultivation on various vegetable oils, C. testosteroni accumulated PHAs up to 78.5-87.5% of the cellular dry material (CDM). The efficiency of the culture to convert oil to PHAs ranged from 53.1% to 58.3% for different vegetable oils. Further more, the composition of the PHAs formed was not found to be substrate dependent as PHAs obtained from C. testosteroni during growth on variety of vegetable oils showed similar compositions; 3-hydroxyoctanoic acid and/or 3-hydroxydecanoic acid being always predominant. The polymerizing system of C. testosteroni showed higher preference for C8 and C10 monomers as longer and smaller monomers were incorporated less efficiently.

  1. Role of biotechnological interventions in the improvement of castor (Ricinus communis L.) and Jatropha curcas L.

    Science.gov (United States)

    Sujatha, M; Reddy, T P; Mahasi, M J

    2008-01-01

    Castor and Jatropha belong to the Euphorbiaceae family. This review highlights the role of biotechnological tools in the genetic improvement of castor and jatropha. Castor is monotypic and breeding programmes have mostly relied on the variability available in the primary gene pool. The major constraints limiting profitable cultivation are: vulnerability to insect pests and diseases, and the press cake is toxic which restrict its use as cattle feed. Conventional breeding techniques have limited scope in improvement of resistance to biotic stresses and in quality improvement owing to low genetic variability for these traits. Genetic diversity was assessed using protein based markers while use of molecular markers is at infancy. In vitro studies in castor have been successful in shoot proliferation from meristematic explants, but not callus-mediated regeneration. Genetic transformation experiments have been initiated for development of insect resistant and ricin-free transgenics with very low transformation frequency. In tropical and subtropical countries jatropha is viewed as a potential biofuel crop. The limitations in available germplasm include; lack of knowledge of the genetic base, poor yields, low genetic diversity and vulnerability to a wide array of insects and diseases. Great scope exists for genetic improvement through conventional methods, induced mutations, interspecific hybridization and genetic transformation. Reliable and highly efficient tissue culture protocols for direct and callus-mediated shoot regeneration and somatic embryogenesis are established for jatropha which indicates potential for widening the genetic base through biotechnological tools. Assessment of genetic diversity using molecular markers disclosed low interaccessional variability in local Jatropha curcas germplasm. The current status and future prospects of in vitro regeneration, genetic transformation and the role of molecular tools in the genetic enhancement of the two

  2. Performance Studies of the Full Length Prototype for the CASTOR Forward Calorimeter of the CMS Experiment

    CERN Document Server

    Basegmez, S; Gouskos, L; Katsas, P; Katkov, I; Khein, L

    2008-01-01

    CASTOR is a project of a forward \\v{C}erenkov sampling calorimeter for the CMS experiment at the LHC collider, with quartz plates as active medium and tungsten as absorber. Several prototypes of the calorimeter have been constructed and tested at CERN. Results of the beam test performed with a full length prototype in summer of 2007 at CERN SPS machine are reported here.

  3. The Mechanical Properties of Castor Seed Shell-polyester Matrix Composites

    OpenAIRE

    S.C. Nwigbo; T.C. Okafor; C.U. Atuanya

    2013-01-01

    A composite with a polyester matrix reinforced with chemically modified shells of castor seed (Ricinus communis) was produced. The effect of the shell (filler) on the mechanical properties of the composite was experimentally quantified. A preliminary study was earlier carried out the shell in terms of their chemical constituents, functional group and mechanical strength. The shell was ground and chemically treated to enhance good bonding and adhesion to the matrix. Composites were fabricated ...

  4. Yield of castor bean fertilized with sewage sludge and potassium and magnesium sulphate

    Directory of Open Access Journals (Sweden)

    Thâmara F. M. Cavalcanti

    2015-08-01

    Full Text Available ABSTRACTThe aim of this study was to evaluate the yield and nutrition of castor bean in response to fertilization with sewage sludge and potassium (K and magnesium (Mg sulphate. The experiment was carried out from January to July 2011. The treatments, in a randomized block design with three replicates, in a Nitosol, corresponded to a factorial scheme (2 x 4 +1: two doses of K and Mg sulphate combined with four doses of sewage sludge (0, 2.60, 5.20 and 10.40 t ha-1, dry basis, applied based on its nitrogen (N content and the N requirement for the crop and an additional treatment with NPK. The castor bean grain yield fertilized with sewage sludge did not differ from conventional fertilization, with the maximum value achieved at a dose of 7.5 t ha-1 of sewage sludge. The fertilization with sewage sludge increased zinc and copper levels in the soil to values close to or higher than those in conventional fertilization, without any influence on the concentrations in the leaf. Fertilization with K and Mg sulphate increased the levels of these cations in the soil without affecting the concentrations in the leaves. The fertilization with sewage sludge increased the contents of organic matter, sulfur, zinc, iron, copper and boron in the soil, and manganese and boron in castor bean leaves.

  5. Molecular cytogenetic analysis and genomic organization of major DNA repeats in castor bean (Ricinus communis L.).

    Science.gov (United States)

    Alexandrov, O S; Karlov, G I

    2016-04-01

    This article addresses the bioinformatic, molecular genetic, and cytogenetic study of castor bean (Ricinus communis, 2n = 20), which belongs to the monotypic Ricinus genus within the Euphorbiaceae family. Because castor bean chromosomes are small, karyotypic studies are difficult. However, the use of DNA repeats has yielded new prospects for karyotypic research and genome characterization. In the present study, major DNA repeat sequences were identified, characterized and localized on mitotic metaphase and meiotic pachytene chromosomes. Analyses of the nucleotide composition, curvature models, and FISH localization of the rcsat39 repeat suggest that this repeat plays a key role in building heterochromatic arrays in castor bean. Additionally, the rcsat390 sequences were determined to be chromosome-specific repeats located in the pericentromeric region of mitotic chromosome A (pachytene chromosome 1). The localization of rcsat39, rcsat390, 45S and 5S rDNA genes allowed for the development of cytogenetic landmarks for chromosome identification. General questions linked to heterochromatin formation, DNA repeat distribution, and the evolutionary emergence of the genome are discussed. The article may be of interest to biologists studying small genome organization and short monomer DNA repeats.

  6. Chemical composition and fermentation characteristics of sugar cane silage enriched with detoxified castor bean meal

    Directory of Open Access Journals (Sweden)

    A.C. Oliveira

    2015-02-01

    Full Text Available This experiment was designed to evaluate the effects of the inclusion of detoxified castor bean meal (CM content on the chemical-bromatological composition, as well as the fermentation characteristics and dry matter losses of sugarcane silage. The treatments consisted of four levels (0, 7, 14 and 21% natural matter of addition of castor bean meal. The design was completely randomized, with five replicates. The material was ensiled in PVC silos of 50-cm in height and 10-cm in diameter, which were opened after 60 days. The density of fodder maintained in the silos was equal to 750kg of natural matter/m3. In order to quantify the gas and effluent losses, the silos were weighed at the beginning and at the end of the experiment. The addition of castor bean meal has increased the levels of DM and crude protein and reduced the levels of neutral detergent fiber, N-NH3, ethanol, and gas and effluent losses from silages, but did not affect pH values. During ensiling, alcoholic fermentation was controlled with the inclusion of the additive.

  7. Magnetic measurements using array of integrated Hall sensors on the CASTOR tokamaka)

    Science.gov (United States)

    Duran, Ivan; Hronová, Olena; Stöckel, Jan; Sentkerestiová, Jana; Havlicek, Josef

    2008-10-01

    We have performed the first tests of "integrated" Hall sensors (IHSs) in a tokamak in-vessel environment. IHS combines the sensing element together with the complex electronic circuitry on a single small chip. The on-chip integrated circuits provide stabilization of the supply voltage, output amplification, noise suppression, and elimination of temperature dependencies. Eight IHSs of A1322LUA type produced by Allegro MicroSystems, Inc. were mounted on a stainless steel ring symmetrically encircling the CASTOR plasmas in poloidal direction 10 mm outside the limiter radius. IHSs were oriented such that they measure the horizontal and vertical magnetic fields. We found out that these sensors qualify for in-vessel use of small to middle sized fusion devices where the radiation is not an issue and the temperature below 150 °C can be guaranteed. The main advantages over the traditional pickup coils are the smaller size and more straightforward interpretation of output without the need of rather cumbersome integration and drift removal procedure associated with the use of inductive loops. We successfully exploited the sensors for determination of vertical plasma displacement on CASTOR. This new diagnostic helped us to shed more light into long term observed discrepancy on CASTOR between vertical plasma displacement as deduced by standard magnetic and by nonmagnetic diagnostics (Langmuir probes, bolometers).

  8. Magnetic measurements using array of integrated Hall sensors on the CASTOR tokamak

    Science.gov (United States)

    Ďuran, Ivan; Hronová, Olena; Stöckel, Jan; Sentkerestiová, Jana; Havlicek, Josef

    2008-10-01

    We have performed the first tests of ``integrated'' Hall sensors (IHSs) in a tokamak in-vessel environment. IHS combines the sensing element together with the complex electronic circuitry on a single small chip. The on-chip integrated circuits provide stabilization of the supply voltage, output amplification, noise suppression, and elimination of temperature dependencies. Eight IHSs of A1322LUA type produced by Allegro MicroSystems, Inc. were mounted on a stainless steel ring symmetrically encircling the CASTOR plasmas in poloidal direction 10 mm outside the limiter radius. IHSs were oriented such that they measure the horizontal and vertical magnetic fields. We found out that these sensors qualify for in-vessel use of small to middle sized fusion devices where the radiation is not an issue and the temperature below 150 °C can be guaranteed. The main advantages over the traditional pickup coils are the smaller size and more straightforward interpretation of output without the need of rather cumbersome integration and drift removal procedure associated with the use of inductive loops. We successfully exploited the sensors for determination of vertical plasma displacement on CASTOR. This new diagnostic helped us to shed more light into long term observed discrepancy on CASTOR between vertical plasma displacement as deduced by standard magnetic and by nonmagnetic diagnostics (Langmuir probes, bolometers).

  9. Potential of sunflower, castor bean, common buckwheat and vetiver as lead phytoaccumulators

    Directory of Open Access Journals (Sweden)

    Jailson do C. Alves

    2016-03-01

    Full Text Available ABSTRACT Studies concerning the tolerance, absorption and distribution of heavy metals in plants are essential for the success of phytoremediation programs. The present study was carried out in order to evaluate the potential of the sunflower, castor bean, common buckwheat and vetiver as lead phytoaccumulators. The species were grown in nutrient solution containing increasing doses of Pb (0, 50, 100, 200 and 400 mg L-1 during a 30-day exposure period. A completely randomized split-plot design was used, with a 4 x 5 factorial and three replicates. Significant reductions of dry matter of the root, shoot and whole plant were found in the all species under study as a function of the increased Pb doses. Vetiver showed higher tolerance to Pb contamination; sunflower and castor bean had intermediate tolerance and the common buckwheat proved to be the most sensitive species. The concentration and total content of Pb in plant compartments were significantly affected by the increased Pb doses in solution, and higher accumulation of this element was observed, in general, in the roots of the studied species. Common buckwheat proved to be not much promising for Pb-phytoremediation programs; sunflower showed potential for Pb phytoextraction and castor bean and vetiver were the most appropriate for Pb phytostabilization.

  10. Superlubricity behaviors of Nitinol 60 alloy under oil lubrication%TiNi60合金在油润滑下的超滑行为

    Institute of Scientific and Technical Information of China (English)

    曾群锋; 董光能

    2014-01-01

    The tribological tests were performed using Nitinol 60 alloy pin sliding over GCr15 steel disc in the tribometer system. Four kinds of oils were experimentally investigated as lubrication oils for lubricating Nitinol 60 alloy in the boundary lubrication regime. The experimental results were compared with a reference dry friction. It was found that Nitinol 60 alloy can be lubricated significantly and has shown remarkable lubrication performance. A superlubricity behavior of Nitinol 60 alloy was observed under castor oil lubrication. An ultra-low coefficient of friction of Nitinol 60 alloy about 0.008 between Nitinol 60 alloy and GCr15 steel was obtained under castor oil lubrication condition after a running-in period. Accordingly, the present study is focused on the lubrication behaviors of castor oil as potential lubrication oil for Nitinol 60 alloy. In the presence of castor oil, coefficient of friction is kept at 0.008 at steady state, corresponding to so-called superlubricity regime (when sliding is then approaching pure rolling). The mechanism of superlubricity is attributed to the triboformed OH-terminated surfaces from friction-induced dissociation of castor oil and the boundary lubrication films formed on the contact surface due to high polarity and long chain of castor oil allowing strong interactions with the lubricated surfaces.%研究了4种润滑油(蓖麻油、菜籽油、透平油、石蜡油)对TiNi60合金润滑性能的影响。研究发现,TiNi60合金在可再生蓖麻油润滑下呈现出摩擦因数为0.008的超滑现象。TiNi60合金在干摩擦及4种润滑油下的销-盘摩擦磨损实验研究表明:TiNi60合金在油润滑下具有优异的摩擦学性能,蓖麻油的润滑性能最优,摩擦因数最小,长时间摩擦后摩擦副表面无可测磨损。超滑机理归纳为极性高、碳链长的蓖麻油在 TiNi60合金表面形成了边界润滑膜以及摩擦诱发的解离-OH基团形成屏蔽表面有关。

  11. Effect of the available soil water and organic matter on the castor bean foliar area growth; Influencia da agua disponivel e materia organica no crescimento da area foliar da mamoneira

    Energy Technology Data Exchange (ETDEWEB)

    Lacerda, Rogerio D. de; Almeida, Larissa C.; Guerra, Hugo O. Carvalho; Souza, Cristiana M. de; Batista, Faed R. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)], Emails: rogerio_dl@yahoo.com.br, laris_almeida@yahoo.com.br, hugo_carvallo@hotmail.com, crismsouza@hotmail.com, faedrideiro@hotmail.com

    2010-07-01

    The Brazilian potential for bio fuel production through the cultivation of oil seeds is immeasurable. On the Northeast is possible to cultivate the castor bean, peanuts, sesame, babassu and other species. Just for the castor bean there exist 3.0 millions of hectares able for cultivation. The experiment had as objective to study the effect of available soil water for plants and organic matter on the foliar area production. It was conducted on the field during the period of October 2008 to March 2009 using an experimental design 2 x 4 factorial on a randomized-complete block design, constituted of two soil organic matter contents (5.0 g.kg{sup -1} and 25.0 g.kg{sup -1}) and four soil water contents (100, 90, 80 and 70% of the soil available water for the plants) with 3 replicates. On each 100 m{sup 2} parcel 50 plants were cultivated until 180 days after the sowing, DAS. The analyses of variance allowed to observe that the addition of organic matter increased the foliar areas in 20,7% and the available water produced an increment of 51,5% when were elevated from 70 to 100%. (author)

  12. Ratios of regioisomers of minor acylglycerols less polar than triricinolein in castor oil estimated by mass spectrometry and the biosynthesis of tetraacylglycerols in castor

    Science.gov (United States)

    We have recently reported the identification of forty new minor molecular species of acylglycerols containing hydroxy fatty acids less polar than triricinolein by electrospray ionization mass spectrometry of the lithium adducts. The ratios of regioisomers of triacylglycerols (ABC and AAB types) and ...

  13. Phase-transfer catalysis and ultrasonic waves II: saponification of vegetable oil.

    Science.gov (United States)

    Entezari, M H; Keshavarzi, A

    2001-07-01

    Saponification of oils which is a commercially important heterogeneous reaction, can be speeded up by the application of ultrasound in the presence of phase-transfer catalyst (PTC). This paper focuses on the ability of ultrasound to cause efficient mixing of this liquid-liquid heterogeneous reaction. Castor oil was taken as a model oil and the kinetic of the reaction was followed by the extent of saponification. The hydrolysis of castor oil was carried out with different PTC such as cetyl trimethyl ammonium bromide (CTAB), benzyl triethyl ammonium chloride (BTAC) and tetrabutyl ammonium bromide (TBAB) in aqueous alkaline solution. As hydroxyl anion moves very slowly from aqueous to oil phase, the presence of a PTC is of prime importance. For this purpose, cationic surfactants are selected. The sonication of biphasic system were performed by 20 kHz (simple horn and cup horn) and 900 kHz. It was found that CTAB was better than the two others and this could be related to the molecular structure of the PTCs. The effect of temperature was also studied on the saponification process. By increasing the temperature, the yield was also increased and this could be explained by intermolecular forces, interfacial tension and mass transfer. Saponification of three different vegetable oils shows that the almond oil is saponified easier than the two others and this could be related to their properties such as surface tension, viscosity and density.

  14. Incorporating different vegetable oils into an aqueous dispersion of hybrid organic nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Samyn, Pieter, E-mail: Pieter.Samyn@fobawi.uni-freiburg.de [Albert-Luedwigs-University Freiburg, Institute for Forest Utilization (Germany); Schoukens, Gustaaf [Ghent University, Department of Textiles (Belgium); Stanssens, Dirk; Vonck, Leo; Van den Abbeele, Henk [Topchim N.V. (Belgium)

    2012-08-15

    Different vegetable oils including soy oil, high-oleic sunflower oil, corn oil, castor oil (CO), rapeseed oil, and hydrogenated CO were added to the imidization reaction of poly(styrene-maleic anhydride) or SMA, with ammonium hydroxide in aqueous medium. The oils favorably reduce viscosity during ammonolysis of the anhydride moieties and increase the maximum solid content of the dispersed imidized SMA to at least 50 wt%, compared to a maximum of 35 wt% for pure imidized SMA. The viscosity of imidized SMA with polyunsaturated oils was generally larger than for monosaturated oils, but it was highest for COs due to high contents of hydroxyl groups. Depending on the oil reactivity, homogeneous or core-shell nanoparticles with 20-60 nm diameters formed. The interactions of oil and organic phase were studied by Fourier-transform infrared spectroscopy, indicating qualitative variances between different oils, the fraction imidized SMA and remaining fraction of ammonolyzed SMA without leakage of oil upon diluting the dispersion and precipitation at low pH. A quantitative analysis with calculation of imide contents, amounts of reacted oil and chemical interactions was made by Fourier-transform-Raman spectroscopy suggesting that most interactions take place around the unsaturated oil moieties and ammonolyzed anhydride.

  15. Energy flow in castor bean (Ricinus communis L. production systems Fluxos de energia em sistemas de produção de mamona (Ricinus communis L.

    Directory of Open Access Journals (Sweden)

    Adilson Nunes da Silva

    2010-12-01

    Full Text Available Although energy analysis is a way to evaluate the sustainability of production systems, this practice is not often used in the agribusiness. In this context, the castor bean (Ricinus communis L is an agricultural crop not yet well studied despite its great potential in the Brazilian energetic scenario. This article aimed to evaluate the productive potential of the castor bean oil, using an energetic view applied to two management systems: low (System 1 and medium (System 2 technologies. The quantification of the used material fluxes was made converting these factors in energy units. The input energy fluxes were 3,170.6 MJ ha¹ and 10,366.0 MJ ha¹ for Systems 1 and 2, respectively. The energy balance of System 1 was 11,938.2 MJ ha¹ and that of System 2 16,296.5 MJ ha¹. The net energetic gain or the energy gain over the invested energy (EROI of System 1 was 3.8 and of System 2, 2.6. Although presenting a greater energy demand and a lower EROI, System 2 had a greater energy balance, demonstrating a better viability of this cultivation system for the production of castor bean oil.A análise energética é uma forma de se avaliar a sustentabilidade de um sistema produtivo, apesar de ainda pouco utilizada no setor agropecuário. Inserida neste setor encontra-se a produção da mamoneira (Ricinus communis L., cultura ainda pouco estudada e que apresenta grande importância para o agronegócio brasileiro. Avaliou-se sob a ótica energética a produção potencial de óleo de mamona em dois sistemas de cultivo: com baixa (Sistema 1 e média (Sistema 2 tecnologias. Foi realizada a quantificação dos fluxos de materiais empregados nos dois sistemas de produção e conversão destes fatores em unidades de energia. Os fluxos de energia de entrada foram de 3.170,6 MJ ha¹ e 10.366 MJ ha¹ para os sistemas 1 e 2, respectivamente. O balanço de energia foi de 11.938,2 MJ ha¹ no sistema 1 e 16.296,5 MJ ha¹ no sistema 2. A lucratividade energética, retorno

  16. Calculative activation analysis of the transport rack for CASTOR {sup registered} casks; Berechnung der Aktivierung eines Transportgestells fuer CASTOR {sup registered} -Behaelter

    Energy Technology Data Exchange (ETDEWEB)

    Tittelbach, S. [Wissenschaftlich-Technische Ingenieurberatung GmbH (WTI), Juelich (Germany); Biedermann, R. [GNS Gesellschaft fuer Nuklear-Service mbH, Essen (Germany); Schmidt-Wohlfarth, Y.; Louia, A. [EnBW Kernkraft GmbH, Philippsburg (Germany)

    2011-07-01

    The transport rack for the internal transport of loaded CASTOR {sup registered} casks before the storage in the intermediate storage facility at the site of the NPP Philippsburg is exposed to neutron irradiation from the cask inventory. Using the Monte Carlo code MCNP the activation rates of the transport rack materials are calculated for typical storage times of the casks in the rack. The long-term activation was also calculated for the continuous use of the transport rack over 10 years. Further topics were the dose rate in the near surrounding of the transport rack after long-term activation and finally the disposability of rack components according to the legal regulations. The maximum contact dose rate was calculated to be below 1 micro Sv/h after 10 years of application. The transport rack can be disposed with large safety margins to the radiation protection limits.

  17. Reproductive responses and productive characteristics in ewes supplemented with detoxified castor meal for a long period

    Directory of Open Access Journals (Sweden)

    Liliane Moreira Silva

    2014-08-01

    Full Text Available The objective of the present study was to evaluate the effects of supplementation with detoxified castor meal (DCM in the diet of ewes during pregnancy, partum, and post-partum on the weight development of their offspring and at slaughter. The study included 56 ewes with synchronized estrus that were naturally mated. At the beginning of pregnancy and in post-partum, hepatic and renal function-related parameters and progesterone levels were measured. At slaughter, the proximate composition and fatty acid profile were determined in the loin of ewes. There was no effect of diet on reproductive response after estrus synchronization. At the beginning of pregnancy, albumin and creatinine levels were lower in the DCM group. Supplementation with DCM did not alter the weight or body condition of ewes at partum. However, at weaning, the DCM group showed a higher loin-eye area (LEA in relation to the group fed diets without detoxified castor meal (WDCM. At partum, as well as at weaning, the offspring of the ewes supplemented with DCM had a larger LEA than the WDCM group. In post-partum, levels of glucose, urea, protein, and cholesterol were lower in the DCM group. The return to cyclicity was similar in both groups, with an average of 47 days after partum. At slaughter, neither anatomical and carcass components nor the results of the proximate analysis were affected by the type of diet, except for an increase in heptadecanoic acid in the DCM group. Supplementation with detoxified castor meal in the diet of ewes does not affect lambing, pregnancy, prolificacy, return to cyclicity, milk production, blood biochemical parameters, or carcass characteristics.

  18. Single nucleotide polymorphisms for assessing genetic diversity in castor bean (Ricinus communis

    Directory of Open Access Journals (Sweden)

    Rabinowicz Pablo D

    2010-01-01

    Full Text Available Abstract Background Castor bean (Ricinus communis is an agricultural crop and garden ornamental that is widely cultivated and has been introduced worldwide. Understanding population structure and the distribution of castor bean cultivars has been challenging because of limited genetic variability. We analyzed the population genetics of R. communis in a worldwide collection of plants from germplasm and from naturalized populations in Florida, U.S. To assess genetic diversity we conducted survey sequencing of the genomes of seven diverse cultivars and compared the data to a reference genome assembly of a widespread cultivar (Hale. We determined the population genetic structure of 676 samples using single nucleotide polymorphisms (SNPs at 48 loci. Results Bayesian clustering indicated five main groups worldwide and a repeated pattern of mixed genotypes in most countries. High levels of population differentiation occurred between most populations but this structure was not geographically based. Most molecular variance occurred within populations (74% followed by 22% among populations, and 4% among continents. Samples from naturalized populations in Florida indicated significant population structuring consistent with local demes. There was significant population differentiation for 56 of 78 comparisons in Florida (pairwise population ϕPT values, p Conclusion Low levels of genetic diversity and mixing of genotypes have led to minimal geographic structuring of castor bean populations worldwide. Relatively few lineages occur and these are widely distributed. Our approach of determining population genetic structure using SNPs from genome-wide comparisons constitutes a framework for high-throughput analyses of genetic diversity in plants, particularly in species with limited genetic diversity.

  19. CASTOR BEAN PRODUCTION AND CHEMICAL ATTRIBUTES OF SOIL IRRIGATED WITH WATER WITH VARIOUS CATIONIC COMPOSITIONS

    Directory of Open Access Journals (Sweden)

    GEOVANI SOARES DE LIMA

    2016-01-01

    Full Text Available This study aimed to evaluate the production of castor beans, cv. „BRS Energia‟, in terms of soil chemical composition as a function of the cationic nature, and salinity levels, of the irrigation water. The experiment was carried out using lysimeters in a controlled environment at the Center of Technology and Natural Resources of the Federal University of Campina Grande, from November 2013 to February 2014. The treatments consisted of six types of salinity (S 1 - Control; S 2 - Na + ; S 3 - Ca 2+ ; S 4 - Na + + Ca 2+ ; S 5 - K + , and S 6 - Na + + Ca 2+ + Mg 2+ , distributed in randomized blocks with four replicates; each plot consisted of five plants for evaluation, totaling 120 experimental plots. Plants in the control treatment (S 1 were irrigated with water with an electrical conductivity (ECw of 0.6 dS m - 1 , and the other treatments (S 2 ; S 3 ; S 4 ; S 5 and S 6 with ECw of 4.5 dS m - 1 , but with (a different cation(s. Water salinity of 4.5 dS m - 1 hampers castor bean production, regardless of the cationic nature of the water; castor bean „BRS Energia‟ was more sensitive to salinity caused by the presence of potassium salts in the irrigation water; the mass of seeds in the primary raceme is the most sensitive variable to salinity and the cationic nature of the irrigation water; the adopted leaching fraction (0.10 was not sufficient to avoid salt accumulation in the soil; irrigation with low ECw promoted the lowest value of exchangeable sodium percentage.

  20. Growth of castor bean plant under different types of wastewaters and soil water levels

    Directory of Open Access Journals (Sweden)

    Vera Lúcia Antunes de Lima

    2009-12-01

    Full Text Available This work evaluated the effect of different levels of water into the soil and types of treated wastewaters from industries of Campina Grande city, Paraíba state, on the growth of castor bean plant, variety BRS Nordestina. The experiment was conducted in greenhouse of the National Center of Research of Cotton. The experimental design was in entirely randomized blocks with 15 treatments in scheme of additional factorial analysis [(4 x 3 + 3] with three replications, having the following factors: three types of treated wastewaters and water of provisioning (A1 = IPELSA - Industry of Cellulose and Paper of Paraíba S/A; A2 = COTEMINAS - Industry of improvement of cotton fiber S/A; A3 = ILCASA - Industry of dairy products of Grande S/A (LEBOM; A4 = Water of the network of public provisioning of Campina Grande city, three levels of available soil water (AW (N1 = 100%, N2 = 80% and N3 = 70% and three controls, one for each AW with water of provisioning and with inorganic fertilizer in the foundation (A4C. In order to evaluate the growth of the castor bean plant during a period of 135 days, biweekly measures of the plant height, diameter of the stem and total foliar area variables were accomplished. For all growth variables there were significant interactions among the studied factors, denoting the interdependence among them, what was reflected on the growth of the plants. The castor bean plant, variety BRS Nordestina, responded well to irrigation with treated wastewater, especially from COTEMINAS industry mainly when associated to the level of 100% of the available soil water.

  1. Dry Cask Storage Characterization Project - Phase 1: CASTOR V/21 Cask Opening and Examination

    Energy Technology Data Exchange (ETDEWEB)

    Bare, Walter Claude; Ebner, Matthias Anthony; Torgerson, Laurence Dale

    2001-08-01

    This report documents visual examination and testing conducted in 1999 and early 2000 at the Idaho National Engineering and Environmental Laboratory (INEEL) on a Gesellschaft für Nuklear Service (GNS) CASTOR V/21 pressurized water reactor (PWR) spent fuel dry storage cask. The purpose of the examination and testing is to develop a technical basis for renewal of licenses and Certificates of Compliance for dry storage systems for spent nuclear fuel and high-level waste at independent spent fuel storage installation sites. The examination and testing was conducted to assess the condition of the cask internal and external surfaces, cask contents consisting of 21 Westinghouse PWR spent fuel assemblies from Dominion’s (formerly named Virginia Power) Surry Power Station and cask concrete storage pad. The assemblies have been continuously stored in the CASTOR cask since 1985. Cask exterior surface and selected fuel assembly temperatures, and cask surface gamma and neutron dose rates were measured. Cask external/internal surfaces, fuel basket components including accessible weldments, fuel assembly exteriors, and primary lid seals were visually examined. Selected fuel rods were removed from one fuel assembly, visually examined, and then shipped to Argonne National Laboratory for nondestructive, destructive, and mechanical examination. Cask interior crud samples and helium cover gas samples were collected and analyzed. The results of the examination and testing indicate the concrete storage pad, CASTOR V/21 cask, and cask contents exhibited sound structural and seal integrity and that long-term storage has not caused detectable degradation of the spent fuel cladding or the release of gaseous fission products between 1985 and 1999.

  2. Structure and function of a benthic invertebrate stream community as influenced by beaver (Castor canadensis).

    Science.gov (United States)

    McDowell, Donald M; Naiman, Robert J

    1986-03-01

    Beaver (Castor canadensis) affect the benthic invertebrate community of small woodland streams in Quebec through habitat modifications. Their activities influence community structure through the replacement of lotic taxa by lentic forms and community function by increasing the absolute importance of collectors and predators while decreasing the relative importance of shredders and scrapers in impounded sites. At our study site during the 1983 ice-free season, standing stocks of coarse particulate organic matter (>1 mm) were 2-5 times greater (Podonates, Tubificidae, and filtering pelycopods. Our results suggest that current paradigms applied to lotic ecosystems need to be reevaluated to incorporate the influence of beaver upon invertebrate communities.

  3. Performance studies of the final prototype for the CASTOR forward calorimeter at the CMS experiment

    CERN Document Server

    Aslanoglou, Xenofon; Bakirci, Mustafa Numan; Basegmez, Suzan; Beaumont, Willem; Blocki, Jacek; Borras, Kerstin; Campbell, Alan; Çerçi, Salim; d'Enterria, David; de Silva, M; Dumanoglu, Isa; Erturk, Sefa; Eskut, Eda; Erchov, Y; Göttlicher, P; Gouskos, Loukas; Onengüt, G; Gusev, Yuri; Jung, Hannes; Katkov, Igor; Katsas, Panagiotis; Khein, Lev; Kisoglu, F; Knutsson, Albert; Kuleshov, Sergey; Kuznetsov, Andrey; Lebeau, Michel; McCauley, Thomas; Muhl, Carsten; Musienko, Yuri; Ochesanu, Silvia; Oroku, M; Ozdemir, Kadri; Ozturk, Sertac; Panagiotou, Apostolos; Shileev, K; Sogut, Kenan; Swain, John; Reucroft, Steve; Ripert, Marion; Tiflov, V; Kayis-Topaksu, A; Van Haevermaet, Hans; Van Mechelen, Pierre

    2008-01-01

    We present performance results of the final prototype for the CASTOR quartz-tungsten sampling calorimeter, to be installed in the very forward region of the CMS experiment at the LHC. The energy linearity and resolution, the uniformity, as well as the spatial resolution of the prototype to electromagnetic and hadronic showers are studied with $E=$ 10--200 GeV electrons, $E=$ 20--350 GeV pions, and $E=$ 50, 150 GeV muons in beam tests carried out at CERN/SPS in 2007.

  4. Performance Studies of Prototype II for the CASTOR forward Calorimeter at the CMS Experiment

    CERN Document Server

    Aslanoglou, Xenofon; Cerci, Salim; Cyz, Antoni; D'Enterria, David; Gladysz-Dziadus, Ewa; Gouskos, Loukas; Ivashkin, Alesandr; Kalfas, Costas; Katsas, Panagiotis; Kuznetsov, Andrey; Musienko, Yuri; Panagiotou, Apostolos; Vlassov, E

    2007-01-01

    We present results of the performance of the second prototype of the CASTOR quartz-tungsten sampling calorimeter, to be installed in the very forward region of the CMS experiment at the LHC. The energy linearity and resolution, as well as the spatial resolution of the prototype to electromagnetic and hadronic showers are studied with E=20-200 GeV electrons, E=20-350 GeV pions, and E=50,150 GeV muons from beam tests carried out at CERN/SPS in 2004. The responses of the calorimeter using two different types of photodetectors (avalanche photodiodes APDs, and photomultiplier tubes PMTs) are compared.

  5. Kinematics Modeling of an Omnidirectional Autonomous Mobile Robot with Castor Wheels

    Institute of Scientific and Technical Information of China (English)

    Peng Yiqiang

    2006-01-01

    The kinematics model of an omnidirectional wheeled mobile robot (WMR) platform with 3 castor wheels was built, which includes the actuated inverse solution and the sensed forward solution. Motion simulations verify the consistency between the actuated inverse solution and the sensed forward solution. Analysis results show that the WMR possesses 3 degrees of freedom, and its motion trajectory is a straight line. The "pushing" and "pulling" motion patterns of the WMR can be generated by using different wheel orientations. It can be used in the places where the space is limited.

  6. [Cutaneous candidiosis in an European beaver, Castor fiber. Epidimiological aspect and parasitic form of Candida albicans].

    Science.gov (United States)

    Saëz, H

    1976-12-01

    On the thigh of an Europa Beaver, Castor fiber L., dead after 8 years of captivity, a candidiasis has been found due to Candida albicans. Were reported successively: the frequence of C. albicans in the Europa Beaver and the Canada Beaver, the diagnosis, an epidemiologic aspect and the morphologic parasitic form of that yeast. In the epiderma parasited of the Beaver, C. albicans has developed in a yeast-form in the superficial strates of the skin and in the filamentous-form in the deeper.

  7. Componentes do rendimento de mamona segundo a ordem floral e época de semeadura no Rio Grande do Sul Castor yield components according to floral order and sowing season in the Rio Grande do Sul State

    Directory of Open Access Journals (Sweden)

    Jacson Zuchi

    2010-09-01

    Full Text Available Diversos fatores, como a época de semeadura, afetam a produtividade e a qualidade das sementes. O objetivo deste trabalho foi avaliar quatro componentes do rendimento de mamona em função da época de semeadura e da ordem floral na Embrapa Clima Temperado em Pelotas, Rio Grande do Sul em solo tipo Argissolo Amarelo na latitude de 31º40'53,6" S, longitude de 52º26'23,5" W e altitude de 67,10 metros. O número de cachos emitidos, produtividade de sementes, percentagem de casca e peso de mil sementes foram avaliados para as cultivares Al Guarany 2002, IAC 80, IAC 226 e BRS 188 Paraguaçu. A maior emissão de cachos de mamona não implica, necessariamente, em maior produtividade de sementes, a qual variou entre época de semeadura e ordem floral.Several factors, including sowing time, can affect the productivity and the quality of seeds. The objective of this work was to evaluate four components of the castor oil plant production as function of the sowing time and of the floral order in the "Embrapa Clima Temperado" in Pelotas, Rio Grande do Sul, Brazil in yellow clay soil type at the latitude of 31º40'53.6" S, longitude of 52º26'23.5" W and altitude of 67.10 meters. The number of bunches emitted, productivity of seeds, peel percentage and weight of a thousand seeds were evaluated for the cultivars Al Guarany 2002, IAC 80, IAC 226 and BRS 188 Paraguaçu. The largest emission of bunches on castor oil plant does not lead, necessarily, to higher productivity of seeds, which varied between sowing time and floral order.

  8. Castor Plant and Culture%陕西关中地区蓖麻新品种高产栽培技术

    Institute of Scientific and Technical Information of China (English)

    庞宁; 姚学慧; 杨世琦; 孙兆敏

    2005-01-01

    1关中地区蓖麻生产概况 蓖麻(Castor-oil plant)属大戟科经济作物,掌状裂叶,盾状着生,圆锥花序顶生,雌花位于上部,雄花位于下部,雄蕊很多,蒴果具有软刺,种子有种阜,胚乳丰富。蓖麻原产于非洲东部,其栽培历史悠久,为世界十大油料作物之一。世界蓖麻年种植面积在330万hm2,蓖麻籽年产量120万t左右,主要生产国有印度、中国和巴西。我国常年种植面积约27万hm2,

  9. Fermentation characteristics, chemical composition and fractionation of carbohydrates and crude protein of silage of elephant grass wilted or with addition of castor bean meal

    Directory of Open Access Journals (Sweden)

    Leandro Sampaio Oliveira Ribeiro

    2014-06-01

    Full Text Available The experiment was conducted to evaluate the concentrations of ammonia nitrogen, hydrogen potential, the losses of deriving the fermentative process, nutritional value, the fractioning of carbohydrates and protein the elephant grass silage wilted or not containing castor bean meal. The experimental design was completely randomized, with five treatments and with four replications: elephant grass wilted; elephant not wilted; elephant grass more castor bean meal (6%; elephant grass more castor bean meal (12% and elephant grass more castor bean meal (18%, the coproduct was added with base on natural matter. We adopted a specific mass of 600 kg/m3. The silage containing 18% castor bean meal showed higher (P0.05 among the silages with additives for fractions A+B1, B2 and C. For the protein fractioning, the fractions A and C decreased (P<0.05 with increase of the inclusion of castor bean meal, differently, of the fraction B1+B2 which increased. The castor bean stands out as a good additive in silage of elephant grass to reduce moisture and improve the fermentation characteristics of silages also was effective in increasing the protein value of silages, especially when using the dose 18%.

  10. Energetic characterization of the husk of the castor bean fruits of the variety Guarani

    Energy Technology Data Exchange (ETDEWEB)

    Teramoto, Erico Tadao; Sousa, Frederico Faula; Castro Neto, Pedro [Universidade Federal de Lavras (DEG/UFLA), MG (Brazil). Dept. de Engenharia; Trugilho, Paulo Fernando [Universidade Federal de Lavras (DCF/UFLA), MG (Brazil). Dept. de Ciencias Florestais; Fraga, Antonio Carlos [Universidade Federal de Lavras (DAG/UFLA), MG (Brazil). Dept. de Agricultura; Nunes, Ramon Rachide [Universidade Federal de Lavras (DAG/UFLA), MG (Brazil). Dept. de Quimica

    2008-07-01

    The knowledge of the physical properties and of the calorific power and of the immediate chemical analysis certain products are interesting for the development of new technologies and equipment for your processing or use as fuel. This way, due to the scarce readiness of referring works for the husk of the castor bean fruits, the present study seeks complemental the available data in the literature. For such were certain the following properties of the husk of the castor bean fruits of variety Guarani: angle of repose, hectolitre weigh, moisture, ash content, volatile material content, fixed carbon content and superior calorific power and inferior calorific power. The following values were found: 42 deg for the angle of repose, 13.92 kg for the hectolitre weight, 4223.19 kcal/kg for the superior calorific power, 3829.92 kcal/kg for the inferior calorific power, 8.21% for the moisture, 9.86% for the ash content, 73.67% for the volatile material content and 8.26% for the fixed carbon content. (author)

  11. SOIL EXCHANGEABLE ALUMINUM INFLUENCING THE GROWTH AND LEAF TISSUE MACRONUTRIENTS CONTENT OF CASTOR PLANTS

    Directory of Open Access Journals (Sweden)

    ROSIANE DE LOURDES SILVA DE LIMA

    2014-01-01

    Full Text Available Three castor ( Ricinus communis genotypes were studied regarding tolerance to high exchange factorial distribution of five doses of exchangeable aluminum added to the soil (0, 0.15, 0.30, 0.60, and 1.20 cmol c dm - 3 and three castor genotypes (BRS Nordestina, BRS Paraguaçu, and Lyra. The plants were raised in pots in a greenhouse. At 53 days after emergence, data were taken on plant height, leaf area, dry mass of shoot and root, and leaf tissue content of macronutrients. The most sensitive genotype was the cv. BRS Nordestina, in which the shoot and root dry weight in the highest aluminum content were reduced to 12.9% and 16.2% of the control treatment, respectively. The most tolerant genotype was the hybrid Lyra, in which the shoot and root dry weight in the maximum content of aluminum were reduced to 43.5% and 42.7% of the control treatment, respectively.The increased exchangeable aluminum affected the leaf nutrient content, and the intensity of the response was different among cultivars. The aluminum toxicity increased N, Ca, and Mg contents and reduced on P, K, and S contents. The cv. BRS Nordestina had a drastic shoot dry weight reduction associated with an intense increment in the N leaf content. Thus, the N increment was caused by a concentration effect caused by the limited growth.

  12. Genetic variability and homozygosity in a F4 castor bean population by microsatellite markers

    Directory of Open Access Journals (Sweden)

    Edna Lobo Machado

    2016-01-01

    Full Text Available ABSTRACT The objectives of this study were to identify the genetic variability and estimate the level of homozygosity in a castor bean F4 population using microsatellite markers (SSR. To this end, it was performed the genotyping of the population through 53 pairs of SSR primers. Allele frequencies were estimated by number of alleles per locus, expected heterozygosity (He, observed heterozygosity (Ho and polymorphic information content (PIC. An array of genetic dissimilarity was generated by Nei and Li index, and hierarchical cluster analysis was performed using the Unweighted Pair-Group Method Averages (UPGMA method. Polymorphism was detected in a total of eight loci (15.09% of the 53 evaluated, with the presence of two alleles per locus. Allele frequencies varied between 0.71 and 0.53, and the PIC, between 0.32 and 0.37. The average observed heterozygosity Ho (0.30 was lower than the expected heterozygosity He (0.47. Five dissimilar groups were formed, showing that there is genetic variability among the evaluated genotypes. The highest genetic dissimilarity was 0.708 and the lowest, 0.00. The percentages of homozygous genotypes varied from 25 to 75%. These results show that controlled selfing in castor bean raises the level of homozygosity, important for the breeding program.

  13. NUV performance of e2v large BICMOS array for CASTOR

    Science.gov (United States)

    Scott, Alan; Beaton, Alexander; Roy, Niladri; Côté, Patrick; Hutchings, John

    2016-07-01

    We have characterized the e2v CIS113 16 μm pitch 4608 x 1920 back-illuminated CMOS (BICMOS) array with near Ultraviolet (NUV) sensitization surface processing and measured its quantum efficiency over the wavelength range from 150 to 350 nm. The Cosmological Advanced Survey Telescope for Optical and UV Research (CASTOR), one of the top priorities in the Canadian astronomical community's decadal plan, is a space-based survey mission that would provide panoramic, high-resolution imaging of 1/8th of the sky in the UV/optical (150-550 nm) spectral region. This small-satellite class mission would provide high angular resolution ultra-deep imaging in three broad filters to supplement data from planned international dark energy missions (Euclid, WFIRST) as well as from the Large Synoptic Survey Telescope (LSST). One of the leading technical risks on this mission is the UV sensitivity required to approach 26th magnitude in the near UV band. In this paper we briefly describe the architecture of this new high speed, high sensitivity CMOS detector and report on the results of our characterization and the implications for the proposed CASTOR survey mission.

  14. Enhanced accumulation of Cd in castor (Ricinus communis L) by soil-applied chelators.

    Science.gov (United States)

    Chhajro, Muhammad Afzal; Rizwan, Muhammad Shahid; Guoyong, Huang; Jun, Zhu; Kubar, Kashif Ali; Hongqing, Hu

    2016-01-01

    Phytoextraction has been identified as one of the most propitious methods of phytoremediation. This pot experiment were treated with varying amounts of (ethylenediamine triacetic acid) EDTA 3-15, (Nitriloacetic acid) NTA 3-10, (Ammonium citrate) NH4 citrate 10 - 25 mmol and one mg kg(-1)Cd, filled with 5 kg soil. The addition of chelators significantly increased Cd concentration in soil and plant. The results showed that maximum Cd uptake was noted under root, shoot and leaf of castor plant tissue (2.26, 1.54, and 0.72 mg kg(-1)) under EDTA 15, NTA 10, and NH4 citrate 25 mmol treatments respectively, and in soil 1.08, 1.06 and 0.52 mg kg(-1) pot(-1) under NH4 citrate 25, NTA 10 and EDTA 15 mmol treatments respectively, as against to control (p < 0.05). Additions of chelators reduction biomass under the EDTA 15 mmol as compared to other treatments, However, Bioconcentration factor (BCF), translocation factor (TF) and remediation factor (RF) were significantly increased under EDTA 15 and NH4 citrate 25 mmol as against control. Our results demonstrated that castor plant proved satisfactory for phytoextraction on contaminated soil, and EDTA 15 and NH4 citrate 25 mmol had the affirmative effect on the Cd uptake in the artificial Cd-contaminated soil.

  15. Population genetic structure in natural and reintroduced beaver (Castor fiber populations in Central Europe

    Directory of Open Access Journals (Sweden)

    Kautenburger, R.

    2008-12-01

    Full Text Available Castor fiber Linnaeus, 1758 is the only indigenous species of the genus Castor in Europe and Asia. Due to extensive hunting until the beginning of the 20th century, the distribution of the formerly widespread Eurasian beaver was dramatically reduced. Only a few populations remained and these were in isolated locations, such as the region of the German Elbe River. The loss of genetic diversity in small or captive populations throughgenetic drift and inbreeding is a severe conservation problem. However, the reintroduction of beaver populations from several regions in Europe has shown high viability and populations today are growing fast. In the present study we analysed the population genetic structure of a natural and two reintroduced beaver populations in Germany and Austria. Furthermore, we studied the genetic differentiation between two beaver species, C. fiber and the American beaver (C. canadensis, using RAPD (Random Amplified Polymorphic DNA as a genetic marker. The reintroduced beaver populations of different origins and the autochthonous population of the Elbe River showed a similar low genetic heterogeneity. There was an overall high genetic similarity in the species C. fiber, and no evidence was found for a clear subspecific structure in the populations studied.

  16. The Correlation Between Soluble Carbohydrate Metabolism and Lipid Accumulation in Castor Seeds%蓖麻种子油脂累积与可溶性糖变化的关系

    Institute of Scientific and Technical Information of China (English)

    张洋; 刘爱忠

    2016-01-01

    The relationship between soluble carbohydrates metabolism and lipid accumulation in the development of castor seeds was studied by HPLC,RNA-seq sequencing and radioactive carbon isotope tracing method. Soluble carbohydrates in developing castor seeds were mainly composed of glucose,fructose and sucrose,and decreased obviously with seed development and oil accumulation. The significant negative correlation between sucrose content and lipid accumulation(r=0.980)was observed. Hexose-to-sucrose ratio was much higher and the genes related to carbohydrates metabolism were highly expressed in the early stage of seed development. Especially,sucrose synthase played the key role in carbohydrates metabolism. Hexose-to-sucrose ratio was decreased and the genes involved in carbohydrates metabolism were down regulated with the rapid accumulation of seed oil during the middle and late developmental stages,while the expressions of genes related to fatty acid synthesis and lipid accumulation increased significantly. Confirmed by 14C-sucrose isotope tracing experiments,the conversion of carbohydrates to oil was significantly inhibited by reducing the sucrose intake;consequently lipid accumulation was limited in developing castor seeds. Therefore,soluble carbohydrates metabolism(mainly sucrose)may play an important role in the process of lipid accumulation in castor seeds.%通过高效液相色谱、RNA-seq测序和放射性碳同位素示踪等技术研究了蓖麻种子发育过程中可溶性糖代谢与油脂累积过程的关系。结果表明,蓖麻种子可溶性糖主要由葡萄糖、果糖和蔗糖构成。随着种子发育和油脂累积,可溶性糖含量呈现明显的下降趋势。其中蔗糖含量变化与油脂累积存在极显著的负相关性(r=0.980)。在种子发育早期,己糖/蔗糖比值较高,糖代谢相关基因大量表达,其中蔗糖合成酶在蔗糖代谢过程中起关键性作用;而在发育中后期,随着种子油脂快速

  17. Antidiarrheal activity and acute oral toxicity of Mentha longifolia L. essential oil

    Directory of Open Access Journals (Sweden)

    Ghader Jalilzadeh-Amin

    2015-02-01

    Full Text Available Objectives: Mentha longifolia L. (Lamiaceae is an annual herb that is used in the Iranian traditional medicine for treating stomach and intestinal disorders. The purpose of this study was to determine the protective effect of M. longifolia on experimental diarrhea in a rat model. Materials and Methods: The antidiarrheal activity of essential oil of M. longifolia (20-80 mg/kg was investigated against castor oil-induced diarrhea in rats using loperamide as the standard reference drug. In acute toxicity evaluation, rats were orally administrated with single dose of EOML at doses ranging from 10 to 1000 mg/kg. Results: EOML caused a significant (p

  18. Results of the CMS-CASTOR very-forward calorimeter in pp collisions at 13 TeV

    CERN Document Server

    Van Haevermaet, Hans

    2016-01-01

    A brief summary of physics results from proton-proton collisions at 13 TeV at the LHC achieved with data from the forward CMS-CASTOR calorimeter is presented. This includes measurements of the inelastic cross section, forward energy flow spectra, and inclusive jet cross sections.

  19. The effect of herbivory on temporal and spatial dynamics of foliar nectar production in cotton and castor

    NARCIS (Netherlands)

    Wäckers, F.L.; Zuber, D.; Wunderlin, R.; Keller, F.

    2001-01-01

    The effects of feeding Spodoptera a littoralis (Boisd.) (Lepidoptera: Noctuidae) larvae on the quantity and distribution of extrafloral nectar production by leaves of castor ((Ricinus communis) and cotton (Gossypium herbaceum) were investigated. Following larval feeding, the total volume of nectar s

  20. The effect of herbivory on temporal and spatial dynamics of foliar nectar production in cotton and castor

    NARCIS (Netherlands)

    Wäckers, F.L.; Zuber, D.; Wunderlin, R.; Keller, F.

    2001-01-01

    The effects of feeding Spodoptera littoralis(Boisd.) (Lepidoptera: Noctuidae) larvae on the quantity and distribution of extrafloral nectar production by leaves of castor (Ricinus communis) and cotton (Gossypium herbaceum) were investigated. Following larval feeding, the total volume of nectar secre

  1. EARLY DEVELOPMENT OF CASTOR BEANS GROWN UNDER SALINITY CONDITIONS (VARIETIES BRS ENERGIA, MPA 34 AND MPB 01

    Directory of Open Access Journals (Sweden)

    RAFAEL ANTÔNIO PRESOTTO

    2016-01-01

    Full Text Available Studies have shown that some plant species exhibit satisfactory production levels when grown under high salinity levels, whereas others exhibit decreased production due to sodium sensitivity even at low sodium concentrations. The castor bean is moderately sensitive to salinity. The aim of the present study was to evaluate the early growth of three castor bean varieties (BRS Energia, MPA 34 and MPB 01 grown in nutrient solution with increasing sodium concentrations (control, 25, 50, 75 and 100 mmol L - 1 . A completely randomized split - plot experimental design was used, with a 5x3 factorial scheme and three replicates per treatment. Salinity resulted in decreased dry weight of all castor bean varieties grown for 31 days under hydroponic conditions. The dry weight accumulation was less affected at the root than at the shoot level. Nevertheless, the shoot dry weight decreased with the increasing salinity. MPA 34 exhibited higher early growth than the remaining tested varieties. Salinity affected the early development of the tested castor bean varieties, and this effect was more pronounced at the shoot than at the root. Variety MPA 34 is promising for cultivation under moderate salinity levels.

  2. A review of nutritional and toxicological implications of castor bean (Ricinus communis L.) meal in animal feeding systems.

    Science.gov (United States)

    Akande, T O; Odunsi, A A; Akinfala, E O

    2016-04-01

    The nutrient-rich defatted castor meal has been tested as a potential source of protein in diets of many livestock species but has limitation due to challenges of toxins. This review was conducted to compile the relevant research information on advances in the use of raw and differently processed castor seed meal in animal feed. In this article, distribution and uses of castor and its products were identified. Research findings on the nutrients profile, principal toxins, various detoxification strategies, nutritional value and toxicity on common livestock species were compiled and reviewed. The defatted seed meal had crude protein range of 32-48%, gross energy of about 3200 kcal/kg. Ricin content was 9.3 mg/g seed, and the average RCA content was 9.9 mg/g. The meal had high activity of lectin, which produced agglutination at about 4.70 mg/ml minimum assays. Reports of detoxification strategies showed varying degrees of success but high pH, moist heating and microbial techniques appeared to exert greater effect on deactivating ricin. Detoxification strategy for the allergen component is inconclusive. Tannins and the phenolic contents were present at trace level and did not constitute notable threat. It was concluded that castor seed holds great potential as feedstuff when upgraded but such upgrading must be safe, cost-effective and labour efficient for commercial acceptability.

  3. Feeding Strategies of Castor fiber brirula%蒙新河狸采食对策初步研究

    Institute of Scientific and Technical Information of China (English)

    卢山; 黄艳; 兰文旭; 葛炎

    2011-01-01

    蒙新河狸为国家一级保护动物,数量稀少,属濒危物种。通过对该物种采食对策的初步观察研究,结果表明:在食物选择上,蒙新河狸对径级为1~3 cm的树木呈正选择。蒙新河狸家域最主要的采食区域为巢穴上下游100 m范围内,主河道两岸10 m范围内。蒙新河狸采食主要选择2年生的树木和多年生的大树(7 cm以上)。%Castor fiber brirula,whose number is rare,is first class national protected animals,being endangered species.Feeding strategies of this species were preliminarily observed studied.Result shows that: in the choice of food,Castor fiber brirula appears positive selection on the diameter class of the 1-3 cm.The main feeding range of Castor fiber brirula home range is 100 m upstream and downstream within the nest,10 m range in both sides of main channel.Castor fiber brirula mainly choose 2-year-old trees perennial trees(above 7 cm) for feed.

  4. Expression of castor LPAT2 enhances ricinoleic acid content at the sn-2 position of triacylglycerols in lesquerella seed

    Science.gov (United States)

    Lesquerella (Physaria fendelri) is a potential crop for hydroxy fatty acid (HFA) production. Its seed triacylglcerols (TAGs) contain 55–60% lesquerolic acid (20:1OH), mostly at the sn-1 and the sn-3 positions of TAG. Castor (Ricinus communis) TAGs contain 90% of ricinoleic acid (18:1OH) which is est...

  5. Local Perceptions about the Effects of Jatropha (Jatropha curcas and Castor (Ricinus communis Plantations on Households in Ghana and Ethiopia

    Directory of Open Access Journals (Sweden)

    Joleen A. Timko

    2014-10-01

    Full Text Available Biofuel plantations have been hyped as a means to reinvigorate Africa’s rural areas. Yet there is still apprehension about the negative environmental and social impacts of large-scale commercial biofuel production around rising food prices, land grabbing, ecological damage, and disruption of rural livelihoods. Given the extent of Jatropha curcas production in Ghana and Ethiopia and Castor bean (Ricinus communis in Ethiopia, this paper presents the results of a study that assessed the socio-economic implications of industrial Jatropha plantations on local livelihoods in Ghana, and of industrial Jatropha and Castor plantations on local livelihoods in Ethiopia. This study used primary data collected from 234 households in Ghana and 165 in Ethiopia. The cultivation of Jatropha and Castor has had several important effects on local livelihoods in the study sites, most notably decreases in household landholdings due to the arrival of industrial Jatropha or Castor plantations; and the resulting changes these plantations have caused in household socio-economic status, food security, fallow periods, and fodder availability. We consider how a lack of meaningful consultation between local people, their traditional authorities and the biofuel company managers, along with shortcomings in each country’s broader land acquisition process and poor land use information, may have contributed to these overall negative effects on local livelihoods. We conclude by suggesting several ways that emerging biofuel industries could be improved from the perspective of local people and their livelihoods.

  6. Biopolymers from vegetable oils via catalyst- and solvent-free "click" chemistry: effects of cross-linking density.

    Science.gov (United States)

    Hong, Jian; Luo, Qiang; Wan, Xianmei; Petrović, Zoran S; Shah, Bipin K

    2012-01-09

    New monomers were prepared by introducing the azide groups in castor, canola, corn, soybean, and linseed oils. Polymerization of the azidated oils with alkynated soybean oil under thermal "click" chemistry conditions (without using a solvent or a catalyst) yielded fully cross-linked elastomers (1-5) of almost the same density (1.05 × 10(-3) kg/m(3)). The degree of cross-linking gradually increased from the castor-derived polymer (220 mol/m(3)) to the linseed-derived polymer (683 mol/m(3)). A systematic correlation between the degree of cross-linking and the thermal and mechanical properties was observed in these biopolymers. Tensile strength (0.62-3.39 MPa) and glass transition temperature (-5 to 16 °C) increased and the linear thermal expansion coefficient decreased in the series from the canola-derived polymer (2) to the linseed-derived polymer (5). The castor-derived polymer (1) that possesses an additional hydroxyl group per fatty acid chain behaved differently.

  7. Diesel oil

    Science.gov (United States)

    Oil ... Diesel oil ... Diesel oil poisoning can cause symptoms in many parts of the body. EYES, EARS, NOSE, AND THROAT Loss of ... most dangerous effects of hydrocarbon (such as diesel oil) poisoning are due to inhaling the fumes. NERVOUS ...

  8. Palm Oil

    Science.gov (United States)

    Palm oil is obtained from the fruit of the oil palm tree. Palm oil is used for preventing vitamin A deficiency, cancer, ... blood pressure, high cholesterol, and cyanide poisoning. Palm oil is used for weight loss and increasing the ...

  9. Rheology of oleo gels based on sorbitan and glyceryl mono stearates and vegetable oils for lubricating applications

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez, R.; Franco, J. M.; Delgado, M. A.; Valencia, C.; Gallegos, C.

    2011-07-01

    Oleo gels based on sorbitan and glyceryl mono stearates and different types of vegetable oils, potentially applicable as biodegradable alternatives to traditional lubricating greases, have been studied. In particular, the rheological behavior, by means of small-amplitude oscillatory shear (SAOS) measurements, and some lubrication performance-related properties (mechanical stability and tribological response) have been evaluated in this work. SAOS response and mechanical stability of these oleo gels are significantly influenced by the type and concentration of the organogelator and the vegetable oil used in the formulations. Glyceryl monostearate (GMS) generally produces stronger gels than sorbitan monostearate (SMS). The use of low-viscosity oils, such as rapeseed and soybean oils, yields gels with significantly higher values of the linear viscoelastic functions than oleo gels prepared with high-viscosity oils, i.e. castor oil. The rheological behavior of SMS-based oleo gels also depends on the cooling rate applied during the gelification process. On the other hand, the oleo gels studied present low values of the friction coefficient obtained in a tribological contact, although only some GMS/castor oil-based oleo gels exhibit a suitable mechanical stability. (Author) 28 refs.

  10. SYNTHESIS AND CHARACTERIZATION O F SODIUM METHYL ESTER SULFONATE FOR CHEMICALLY-ENHANCED OIL RECOVERY

    Directory of Open Access Journals (Sweden)

    K. Babu

    2015-09-01

    Full Text Available AbstractAttention has been given to reduce the cost of surfactant by using castor oil as an alternative natural source of feedstock. A new surfactant, sodium methyl ester sulfonate (SMES was synthesised using ricinoleic acid methyl ester, which is obtained from castor oil, for enhanced oil recovery in petroleum industries. The performance of SMES was studied by measuring the surface tension with and without sodium chloride and its thermal stability at reservoir temperature. SMES exhibited good surface activity, reducing the surface tension of surfactant solution up to 38.4 mN/m and 27.6 mN/m without and with NaCl, respectively. During the thermal analysis of SMES, a 31.2% mass loss was observed from 70 ˚C to 500 ˚C. The phase behavior of the cosurfactant/SMES-oil-water system plays a key role in interpreting the performance of enhanced oil recovery by microemulsion techniques. Flooding experiments were performed using a 0.5 pore volume of synthesized SMES solutions at three different concentrations. In each case chase water was used to maintain the pressure gradient. The additional recoveries in surfactant flooding were found to be 24.53%, 26.04% and 27.31% for 0.5, 0.6 and 0.7 mass% of surfactant solutions, respectively.

  11. Behaviour of neutron moderator materials at high temperatures in CASTOR {sup registered} -casks: qualification and assessment

    Energy Technology Data Exchange (ETDEWEB)

    Krietsch, T.; Wolff, D. [Federal Inst. for Materials Research and Testing (BAM), Berlin (Germany); Knopp, U. [Gesellschaft fuer Nuklear-Behaelter mbH (GNB), Essen (Germany); Brocke, H.D. [TUeV Rheinland Group, Berlin (Germany)

    2004-07-01

    The Federal Institute for Materials Research and Testing (BAM) is the responsible German authority for the assessment of mechanical and thermal designs of transport and storage casks for radioactive materials. BAM checks up the proofs of the applicants in their safety reports and assesses the conformity to the Regulations for the Safe Transport of Radioactive Material. One applicant is the Gesellschaft fuer Nuklear-Behaelter mbH (GNB) with a new generation of transport and storage casks of CASTOR {sup registered} -design. GNB typically uses ultra high molecular weight Polyethylene (UHMW-PE) for the moderation of free neutrons. Rods made of UHMW-PE are positioned in axial bore holes in the wall of the cask and plates of UHMW-PE are in free spaces between primary and secondary lid and between the bottom of the cask and an outer plate (Figure 1). Because of the heat generated by the radioactive inventory and because of a strained spring at the bottom of every bore hole, UHMW-PE is subjected to permanent thermal and mechanical loads as well as loads from gamma and neutron radiation. UHMW-PE has been used under routine- and normal conditions of transport for maximum temperatures up to 130 C. For new generations of CASTOR registered -design maximum temperatures will be increased up to 160 C. That means a permanent use of UHMW-PE at temperatures within and above the melting region of the crystallites. In this paper, some results of special investigations for the proofs of usability of UHMW-PE at temperatures up to 160 C under real conditions of transport and storage in CASTOR registered -casks are given. For that, investigations on temperature dependent expansion behaviour under laboratory conditions as well as in large scale experiments, especially in the case of multiple heating and cooling, were done. Besides, geometrical creep strength for long-term loading by temperatures and pressures with regard to the chemical and physical stability properties of UHMW-PE above the

  12. Oil-in-water emulsions characterization by laser granulometry and impact on γ-decalactone production in Yarrowia lipolytica.

    Science.gov (United States)

    Gomes, Nelma; Waché, Yves; Teixeira, José A; Belo, Isabel

    2011-08-01

    Oil-in-water emulsions composed of methyl ricinoleate (MR) or castor oil (CO) as the organic phase, stabilized by Tween 80, are in the basis of the biotechnological production of γ-decalactone. Yarrowia lipolytica was used due to its ability to grow on hydrophobic substrates and to carry out the biotransformation. The characterization of oil droplets size distribution by laser granulometry was performed under different oil concentrations. The impact of the presence of cells on droplets size was also analyzed as well as the relevance of washing inoculum cells. Furthermore, the granulometric characterization of the emulsions was related with γ-decalactone production and it was observed that, in the presence of non-washed cells, the smaller droplets disappeared, using both oils, which increased γ-decalactone concentration. This suggests that the access of cells to the substrate occurs by their adhesion around larger oil droplets.

  13. Late Holocene Drought Record From Castor Lake, North-Central Washington State

    Science.gov (United States)

    Nelson, D. B.; Abbott, M. B.; Polissar, P. J.; Finney, B.

    2006-12-01

    The effects of recent and historic drought in the North American west provide motivation for understanding the natural variability and underlying causes of these events. We present a 6,000-year lake sediment record of water balance from Washington State in an effort to address these questions. A series of overlapping sediment cores were collected and chronological control was established through a combination of radiocarbon, tephrochronology, and cesium isotope activity. Modern basin morphometry and lake water oxygen and hydrogen isotope data indicate closed-basin hydrology and the strong influence of evaporative enrichment on lake water composition, and therefore sensitivity of the system to changes in regional water balance and drought. Samples of endogenic aragonite precipitates were isolated from sediment cores at an average sampling interval of 3.7mm, corresponding to a temporal resolution of approximately 7 years. Grayscale data were generated from digital images of the cores collected under controlled light conditions and are shown to track changes in oxygen isotope values, with darker layers corresponding to periods of increased isotopic composition. In addition to supporting the notion that oxygen isotope data are primarily recording changes in water balance as opposed to changes in water source or temperature, the increased resolution of the grayscale record improves the resolution of the climate signal to the sub-millimeter scale of the laminations. There is a significant correlation between the most recent portion of the Castor Lake grayscale record and a 1,500-yr Palmer Drought Severity Index (PDSI) reconstruction from central Washington (1). The strong association between changes in the Castor Lake record and changes in the PDSI reconstruction provides convincing method validation and strengthens the interpretation of both as drought signals. Spectral analyses of the grayscale record using singular spectrum analysis (SSA), maximum entropy method (MEM

  14. CASTOR Centauro and Strange Object Research in nucleus-nucleus collisions at LHC

    CERN Document Server

    Angelis, Aris L S; Bartke, Jerzy; Chileev, K; Gladysz-Dziadus, E; Golubeva, M B; Guber, F F; Karavitcheva, T L; Kharlov, Yu V; Kurepin, A B; Mavromanolakis, G; Panagiotou, A D; Sadovsky, S A; Tiflov, V V; Wlodarczyk, Z

    2002-01-01

    We describe the CASTOR detector designed to probe the very forward, baryon-rich rapidity region in nucleus-nucleus collisions at the LHC. We present a phenomenological model describing the formation of a QGP fireball in a high baryochemical potential environment, and its subsequent decay into baryons and strangelets. The model explains Centauros and the long-penetrating component and makes predictions for the LHC. Simulations of Centauro-type events were done. To study the response of the apparatus to new effects different exotic species (DCC, Centauros, strangelets etc.) were passed through the deep calorimeter. The energy deposition pattern in the calorimeter appears to be a new clear signature of the QGP.

  15. The Mechanical Properties of Castor Seed Shell-polyester Matrix Composites

    Directory of Open Access Journals (Sweden)

    S.C. Nwigbo

    2013-05-01

    Full Text Available A composite with a polyester matrix reinforced with chemically modified shells of castor seed (Ricinus communis was produced. The effect of the shell (filler on the mechanical properties of the composite was experimentally quantified. A preliminary study was earlier carried out the shell in terms of their chemical constituents, functional group and mechanical strength. The shell was ground and chemically treated to enhance good bonding and adhesion to the matrix. Composites were fabricated using a hand lay-up or contact mould method for different percentage compositions of the filler. Tests, with respect to the mechanical properties (i.e., tensile, flexural and creep response were carried out. The result obtained was compared with the unreinforced polyester plate. It was observed that the inclusion of the filler (shell added strength to the composite. Scanning Electron Microscopy (SEM was taken on the composite samples to study the morphology of the composites.

  16. Bayesian Integration of Isotope Ratios for Geographic Sourcing of Castor Beans

    Energy Technology Data Exchange (ETDEWEB)

    Webb-Robertson, Bobbie-Jo M.; Kreuzer, Helen W.; Hart, Garret L.; Ehleringer, James; West, Jason B.; Gill, Gary A.; Duckworth, Douglas C.

    2012-08-15

    Recent years have seen an increase in the forensic interest associated with the poison ricin, which is extracted from the seeds of the Ricinus communis plant. Both light element (C, N, O, and H) and strontium (Sr) isotope ratios have previously been used to associate organic material with geographic regions of origin. We present a Bayesian integration methodology that can more accurately predict the region of origin for a castor bean than individual models developed independently for light element stable isotopes or Sr isotope ratios. Our results demonstrate a clear improvement in the ability to correctly classify regions based on the integrated model with a class accuracy of 6 0 . 9 {+-} 2 . 1 % versus 5 5 . 9 {+-} 2 . 1 % and 4 0 . 2 {+-} 1 . 8 % for the light element and strontium (Sr) isotope ratios, respectively. In addition, we show graphically the strengths and weaknesses of each dataset in respect to class prediction and how the integration of these datasets strengthens the overall model.

  17. Surveillance of Space Concept Demonstrator. Presentation of One Sensor: CASTOR-V

    Science.gov (United States)

    2007-04-01

    capteurs optiques , situés au sol et géographiquement dispersés pour l’observation de satellites. Ces trois détecteurs seront télécommandés par le Centre...d’opération du système de détecteurs (COSD). Avant que cette opération soit entreprise, CASTOR-V, le capteur situé à Valcartier, a été caractérisé et...temps, les diverses composantes d’équipement et de logiciel du capteur , il présente ensuite les résultats de sa caractérisation incluant le temps

  18. First performance studies of a prototype for the CASTOR forward calorimeter at the CMS experiment

    CERN Document Server

    Aslanoglou, Xenofon; Davis, N; D'Enterria, David; Gladysz-Dziadus, Ewa; Kalfas, Costas; Musienko, Yuri; Kuznetsov, Andrey; Panagiotou, Apostolos

    2008-01-01

    We present results of the performance of the first prototype of the CASTOR quartz-tungsten sampling calorimeter, to be installed in the very forward region of the CMS experiment at the LHC. This study includes GEANT Monte Carlo simulations of the Cerenkov light transmission efficiency of different types of air-core light guides, as well as analysis of the calorimeter linearity and resolution as a function of energy and impact-point, obtained with 20-200 GeV electron beams from CERN/SPS tests in 2003. Several configurations of the calorimeter have been tested and compared, including different combinations of (i) structures for the active material of the calorimeter (quartz plates and fibres), (ii) various light-guide reflecting material (glass and foil reflectors) and (iii) light-sensing devices (photomultipliers and avalanche photodiodes).

  19. Phytoextraction of metals and rhizoremediation of PAHs in co-contaminated soil by co-planting of Sedum alfredii with ryegrass (Lolium perenne) or castor (Ricinus communis).

    Science.gov (United States)

    Wang, Kai; Huang, Huagang; Zhu, Zhiqiang; Li, Tingqiang; He, Zhenli; Yang, Xiaoe; Alva, Ashok

    2013-01-01

    A pot experiment was conducted to investigate the potential for phytoextraction of heavy metals and rhizoremediation of polycyclic aromatic hydrocarbons (PAHs) in co-contaminated soil by co-planting a cadmium/zinc (Cd/Zn) hyperaccumulator and lead (Pb) accumulator Sedum alfredii with ryegrass (Lolium perenne) or castor (Ricinus communis). Co-planting with castor decreased the shoot biomass of S. alfredii as compared to that in monoculture. Cadmium concentration in S. alfredii shoot significantly decreased when grown with ryegrass or castor as compared to that in monoculture. However, no reduction of Zn or Pb concentration in S. alfredii shoot was detected in co-planting treatments. Total removal of either Cd, Zn, or Pb by plants was similar across S. alfredii monoculture or co-planting with ryegrass or castor, except enhanced Pb removal in S. alfredii and ryegrass co-planting treatment. Co-planting of S. alfredii with ryegrass or castor significantly enhanced the pyrene and anthracene dissipation as compared to that in the bare soil or S. alfredii monoculture. This appears to be due to the increased soil microbial population and activities in both co-planting treatments. Co-planting of S. alfredii with ryegrass or castor provides a promising strategy to mitigate both metal and PAH contaminants from co-contaminated soils.

  20. Effects of pH on protein components of extracted oil bodies from diverse plant seeds and endogenous protease-induced oleosin hydrolysis.

    Science.gov (United States)

    Zhao, Luping; Chen, Yeming; Chen, Yajing; Kong, Xiangzhen; Hua, Yufei

    2016-06-01

    Plant seeds are used to extract oil bodies for diverse applications, but oil bodies extracted at different pH values exhibit different properties. Jicama, sunflower, peanut, castor bean, rapeseed, and sesame were selected to examine the effects of pH (6.5-11.0) on the protein components of oil bodies and the oleosin hydrolysis in pH 6.5-extracted oil bodies. In addition to oleosins, many extrinsic proteins (globulins, 2S albumin, and enzymes) were present in pH 6.5-extracted oil bodies. Globulins were mostly removed at pH 8.0, whereas 2S albumins were removed at pH 11.0. At pH 11.0, highly purified oil bodies were obtained from jicama, sunflower, peanut, and sesame, whereas lipase remained in the castor bean oil bodies and many enzymes in the rapeseed oil bodies. Endogenous protease-induced hydrolysis of oleosins occurred in all selected plant seeds. Oleosins with larger sizes were hydrolysed more quickly than oleosins with smaller sizes in each plant seed.

  1. Anatomic and tissue characteristics in goats fed for extended periods with residue of castor biodiesel production

    Directory of Open Access Journals (Sweden)

    Cláudio Henrique de Almeida Oliveira

    2013-12-01

    Full Text Available Twenty-five adult crossbred goats, divided in two groups, were fed over a period of 16 months with diets based on Tifton hay and concentrate feed with (DCO or without (WDCO detoxified castor bean meal as a substitute for soybean meal. Throughout 480 days, blood samples were taken to measure lactate dehydrogenase, aspartate aminotransferase, alanine aminotransferase, urea, albumin and creatinine. The animals were euthanized, and the anatomical components (lungs, heart, spleen, liver, kidneys, tongue, empty stomach, empty intestines, omentum, cardiac and renal adipose tissue, carcass and commercial cuts (shoulder, ham, loin, ribs and neck were weighed. Thereafter, an anatomic dissection of the loin was performed, separating the muscle, adipose and bone tissues. On the muscular part of the loin, longissimus dorsi, the proximate composition, fatty acid profile and the expression of SEW-1, IGF-I and IGF-II were analyzed. A higher incidence of bone tissue was observed in the anatomical dissections of the loin and a lower incidence of fat in the proximate composition of the longissimus dorsi of the DCO group compared to the WDCO group (p<0.05. The expression of the IGF-II and SEW-1 genes was higher (p<0.001 for each in the muscle tissue of the DCO animals. Thus, using detoxified castor bean meal for long periods does not produce significant changes in the anatomical composition of the loin or the proximate composition of the longissimus dorsi. However, the differences in gene expression suggest the need for new investigations and care when using this product for animal feeding.

  2. Balanço energético para a produção de biodiesel pela cultura da mamona (Ricinus communis L. Energy balance for biodiesel production by the castor bean crop (Ricinus communis L.

    Directory of Open Access Journals (Sweden)

    Rodolfo Glauber Chechetto

    2010-12-01

    Full Text Available A cultura da mamona (Ricinus communis L. adquiriu prestígio ao interesse da indústria pela qualidade de seu óleo e, recentemente, pela busca de novas fontes de energias. O experimento que serviu como base para os dados utilizados nesse trabalho foi realizado na Fazenda Experimental Lageado, FCA - UNESP, no município de Botucatu - SP, no ano de 2008. O objetivo deste trabalho foi avaliar a viabilidade energética da cultura através do balanço e da eficiência energética, desde a implantação até a produção de biodiesel, utilizando parâmetros de consumo operacional no manejo para instalação e manutenção da cultura, colheita e processamento de óleo. As operações de manejo de solo, semeadura e colheita consumiramo total de 266,20 MJ ha-1, que juntamente com fertilizantes, agrotóxicos, combustíveis e lubrificantes, mão-de-obra, sementes e processamento industrial totalizaram uma entrada de energia de 56.808,10 MJ ha-1. A produção de energia foi de 72.814,00 MJ ha-1. O setor ainda carece de estudos que contribuiriam para o levantamento de dados e coeficientes energéticos mais específicos. A cultura da mamona foi considerada eficiente, permitindo ganho de 15.983,44 MJ ha-1, equivalente a aproximadamente 415 L de óleo diesel.The castor bean crop (Ricinus communis L. has acquired prestige due to industries interest in the oil quality and recently for new sources of energy demand. The experiment that served as basis for the data used in this study was conducted at the Lageado Experimental Farm, in Botucatu - SP, 2008. This study aimed to avaluate the crop viability through energy balance and energy efficiency since the implantation until biodiesel production using parameters of consumption in operational management for installation and maintenance of culture harvest and oil production. The soil management operations, sow and harvest consumed the total of 266.20 MJ ha-1, gathering with the fertilizers, pesticides, fuels

  3. Peanut Oil

    Science.gov (United States)

    ... and baby care products. Sometimes the less expensive soya oil is added to peanut oil. ... are pregnant or breast-feeding. Allergy to peanuts, soybeans, and related plants: Peanut oil can cause serious ...

  4. Oil Spills

    Science.gov (United States)

    Oil spills often happen because of accidents, when people make mistakes or equipment breaks down. Other causes include natural disasters or deliberate acts. Oil spills have major environmental and economic effects. Oil ...

  5. Short communication. Evaluation of castor (Ricinus communis L.) induced mutants for possible selection in the improvement of seed yield

    Energy Technology Data Exchange (ETDEWEB)

    Sarwar, G.; Boota Chaudhry, M.

    2008-07-01

    The aim of the present work was to determine selection criteria suitable for developing castor ideotypes with high yield potentials. Nineteen M4 generation castor mutants were obtained by gamma irradiation (100 to 1000 Gy) of DS30 castor seeds, and evaluated alongside this reference variety over 2006-07 for their possible use in the improvement of castor seed yield. Days to ripening, plant height, number of spikes/plant, length of main spike, number of main spike capsules, capsule weight, 100-seed weight and seed yield per plant were recorded for each mutant. Correlation coefficients were calculated, path analyses performed, and the genetic features of the different traits were determined. A significant, positive correlation was seen between capsule weight and seed yield. The 100-seed weight showed a positive but non-significant phenotypic relationship plus a significant genotypic relationship with seed yield. Capsule weight also showed a strong direct effect on seed yield, plus a strong positive and significant genotypic correlation with this variable. More than 50% heritability was observed for all the traits studied except the 100-seed weight and capsule weight. The number of main spike capsules showed the greatest genetic advance, followed by spike length and number of spikes. Traits such as the number of capsules, spike length and number of spikes showed strong heritability and good genetic advance. These traits are therefore governed by additive genes, and for the improvement of seed yield selection may be based directly on these attributes. In conclusion, for the improvement of seed yield the main emphasis should be placed on the number of spikes and capsule weight, via the selection of the highest yielding mutants among those tested. However, spike length and 100-seed weight should also be taken into account. (Author) 18 refs.

  6. Sexual and Asexual Reproduction of Salix sitchensis and the Influence of Beaver (Castor canadensis) Herbivory on Reproductive Success

    OpenAIRE

    Travis G. Gerwing; Alyssa M. Allen Gerwing; Rapaport, Eric; Alström-Rapaport, Cecilia

    2012-01-01

    The influence of beaver (Castor canadensis Kuhl) herbivory on Salix reproduction, specifically the stimulation of asexual reproduction via browsed stem fragments, is relatively unknown. This study aimed to determine if beaver herbivory stimulates asexual reproduction of riparian willows and results in mature populations dominated by clones. The survival of seedlings and asexual propagules produced by beaver browse in populations of the riparian willow Salix sitchensis (Sanson in Bongard) were...

  7. Local Perceptions about the Effects of Jatropha (Jatropha curcas) and Castor (Ricinus communis) Plantations on Households in Ghana and Ethiopia

    OpenAIRE

    2014-01-01

    Biofuel plantations have been hyped as a means to reinvigorate Africa’s rural areas. Yet there is still apprehension about the negative environmental and social impacts of large-scale commercial biofuel production around rising food prices, land grabbing, ecological damage, and disruption of rural livelihoods. Given the extent of Jatropha curcas production in Ghana and Ethiopia and Castor bean ( Ricinus communis ) in Ethiopia, this paper presents the results of a study that assessed the socio...

  8. Gene Structures, Evolution, Classification and Expression Profiles of the Aquaporin Gene Family in Castor Bean (Ricinus communis L..

    Directory of Open Access Journals (Sweden)

    Zhi Zou

    Full Text Available Aquaporins (AQPs are a class of integral membrane proteins that facilitate the passive transport of water and other small solutes across biological membranes. Castor bean (Ricinus communis L., Euphobiaceae, an important non-edible oilseed crop, is widely cultivated for industrial, medicinal and cosmetic purposes. Its recently available genome provides an opportunity to analyze specific gene families. In this study, a total of 37 full-length AQP genes were identified from the castor bean genome, which were assigned to five subfamilies, including 10 plasma membrane intrinsic proteins (PIPs, 9 tonoplast intrinsic proteins (TIPs, 8 NOD26-like intrinsic proteins (NIPs, 6 X intrinsic proteins (XIPs and 4 small basic intrinsic proteins (SIPs on the basis of sequence similarities. Functional prediction based on the analysis of the aromatic/arginine (ar/R selectivity filter, Froger's positions and specificity-determining positions (SDPs showed a remarkable difference in substrate specificity among subfamilies. Homology analysis supported the expression of all 37 RcAQP genes in at least one of examined tissues, e.g., root, leaf, flower, seed and endosperm. Furthermore, global expression profiles with deep transcriptome sequencing data revealed diverse expression patterns among various tissues. The current study presents the first genome-wide analysis of the AQP gene family in castor bean. Results obtained from this study provide valuable information for future functional analysis and utilization.

  9. Photosynthetic pigments, cell extrusion and relative leaf water content of the castor bean under silicon and salinity

    Directory of Open Access Journals (Sweden)

    Rener L. de S. Ferraz

    2015-09-01

    Full Text Available ABSTRACTThe castor bean crop plays an important social, environmental and economic role, especially due to possibility of its use as feedstock for the generation of clean energy. Thus, this study aimed to evaluate the contents of photosynthetic pigments, cell membrane extrusion and the relative water content in the leaves of the castor bean cultivar ‘BRS Energia’ under silicon and salinity levels. The experiment was carried out at Embrapa Cotton, in a completely randomized design, in a 4 x 4 factorial scheme, and the treatments consisted of four silicon levels (0, 100, 200 and 300 mg L-1 and four water salinity levels of (ECw 0, 2, 4 and 6 dS m-1, with three replicates. The gradual increase in salinity levels reduced the concentration of photosynthetic pigments, relative water content in the leaves and increased cell membrane extrusion. The increase in the concentration of silicon reduced the harmful effects of salts on the analysed variables in the castor bean ‘BRS Energia’.

  10. Gene Structures, Evolution and Transcriptional Profiling of the WRKY Gene Family in Castor Bean (Ricinus communis L..

    Directory of Open Access Journals (Sweden)

    Zhi Zou

    Full Text Available WRKY proteins comprise one of the largest transcription factor families in plants and form key regulators of many plant processes. This study presents the characterization of 58 WRKY genes from the castor bean (Ricinus communis L., Euphorbiaceae genome. Compared with the automatic genome annotation, one more WRKY-encoding locus was identified and 20 out of the 57 predicted gene models were manually corrected. All RcWRKY genes were shown to contain at least one intron in their coding sequences. According to the structural features of the present WRKY domains, the identified RcWRKY genes were assigned to three previously defined groups (I-III. Although castor bean underwent no recent whole-genome duplication event like physic nut (Jatropha curcas L., Euphorbiaceae, comparative genomics analysis indicated that one gene loss, one intron loss and one recent proximal duplication occurred in the RcWRKY gene family. The expression of all 58 RcWRKY genes was supported by ESTs and/or RNA sequencing reads derived from roots, leaves, flowers, seeds and endosperms. Further global expression profiles with RNA sequencing data revealed diverse expression patterns among various tissues. Results obtained from this study not only provide valuable information for future functional analysis and utilization of the castor bean WRKY genes, but also provide a useful reference to investigate the gene family expansion and evolution in Euphorbiaceus plants.

  11. Expression of Castor LPAT2 Enhances Ricinoleic Acid Content at the sn-2 Position of Triacylglycerols in Lesquerella Seed

    Directory of Open Access Journals (Sweden)

    Grace Q. Chen

    2016-04-01

    Full Text Available Lesquerella is a potential industrial oilseed crop that makes hydroxy fatty acid (HFA. Unlike castor its seeds are not poisonous but accumulate lesquerolic acid mostly at the sn-1 and sn-3 positions of triacylglycerol (TAG, whereas castor contains ricinoleic acid (18:1OH at all three positions. To investigate whether lesquerella can be engineered to accumulate HFAs in the sn-2 position, multiple transgenic lines were made that express castor lysophosphatidic acid acyltransferase 2 (RcLPAT2 in the seed. RcLPAT2 increased 18:1OH at the sn-2 position of TAGs from 2% to 14%–17%, which resulted in an increase of tri-HFA-TAGs from 5% to 13%–14%. Our result is the first example of using a LPAT to increase ricinoleic acid at the sn-2 position of seed TAG. This work provides insights to the mechanism of HFA-containing TAG assembly in lesquerella and directs future research to optimize this plant for HFA production.

  12. [CASTOR-Radiology: software of management in a Unit of Medical Imaging: use in the CHU of Tours].

    Science.gov (United States)

    Bertrand, P; Rouleau, P; Alison, D; Bristeau, M; Minard, P; Saad, B

    1993-01-01

    Despite the large volume of information circulating in radiology departments, very few of them are currently computerised, although computer processing is developing rapidly in hospitals, encouraged by the installation of PMSI. This article illustrates the example of an imaging department management software: CASTOR-Radiologie, Computerisation of part of the Hospital Information System (HIS) must allow an improvement in the efficacy of the service rendered, must reliably reflect the department's activity and must be able to monitor the running costs. CASTOR-Radiologie was developed in conformity with standard national specifications defined by the Public Hospitals Department of the French Ministry of Health. The functions of this software are: unique patient identification, HIS base, management of examination requests, allowing a rapid reply to clinician's requests, "real-time" follow-up of patients in the department, saving time for secretaries and technicians, medical files and file analysis, allowing analysis of diagnostic strategies and quality control, edition of analytical tables of the department's activity compatible with the PMSI procedures catalogue, allowing optimisation of the use of limited resources, aid to the management of human, equipment and consumable resources. Links with other hospital computers raise organisational rather than technical problems, but have been planned for in the CASTOR-Radiologie software. This new tool was very well accepted by the personnel.

  13. Gene Structures, Evolution, Classification and Expression Profiles of the Aquaporin Gene Family in Castor Bean (Ricinus communis L.).

    Science.gov (United States)

    Zou, Zhi; Gong, Jun; Huang, Qixing; Mo, Yeyong; Yang, Lifu; Xie, Guishui

    2015-01-01

    Aquaporins (AQPs) are a class of integral membrane proteins that facilitate the passive transport of water and other small solutes across biological membranes. Castor bean (Ricinus communis L., Euphobiaceae), an important non-edible oilseed crop, is widely cultivated for industrial, medicinal and cosmetic purposes. Its recently available genome provides an opportunity to analyze specific gene families. In this study, a total of 37 full-length AQP genes were identified from the castor bean genome, which were assigned to five subfamilies, including 10 plasma membrane intrinsic proteins (PIPs), 9 tonoplast intrinsic proteins (TIPs), 8 NOD26-like intrinsic proteins (NIPs), 6 X intrinsic proteins (XIPs) and 4 small basic intrinsic proteins (SIPs) on the basis of sequence similarities. Functional prediction based on the analysis of the aromatic/arginine (ar/R) selectivity filter, Froger's positions and specificity-determining positions (SDPs) showed a remarkable difference in substrate specificity among subfamilies. Homology analysis supported the expression of all 37 RcAQP genes in at least one of examined tissues, e.g., root, leaf, flower, seed and endosperm. Furthermore, global expression profiles with deep transcriptome sequencing data revealed diverse expression patterns among various tissues. The current study presents the first genome-wide analysis of the AQP gene family in castor bean. Results obtained from this study provide valuable information for future functional analysis and utilization.

  14. Gene Structures, Evolution and Transcriptional Profiling of the WRKY Gene Family in Castor Bean (Ricinus communis L.).

    Science.gov (United States)

    Zou, Zhi; Yang, Lifu; Wang, Danhua; Huang, Qixing; Mo, Yeyong; Xie, Guishui

    2016-01-01

    WRKY proteins comprise one of the largest transcription factor families in plants and form key regulators of many plant processes. This study presents the characterization of 58 WRKY genes from the castor bean (Ricinus communis L., Euphorbiaceae) genome. Compared with the automatic genome annotation, one more WRKY-encoding locus was identified and 20 out of the 57 predicted gene models were manually corrected. All RcWRKY genes were shown to contain at least one intron in their coding sequences. According to the structural features of the present WRKY domains, the identified RcWRKY genes were assigned to three previously defined groups (I-III). Although castor bean underwent no recent whole-genome duplication event like physic nut (Jatropha curcas L., Euphorbiaceae), comparative genomics analysis indicated that one gene loss, one intron loss and one recent proximal duplication occurred in the RcWRKY gene family. The expression of all 58 RcWRKY genes was supported by ESTs and/or RNA sequencing reads derived from roots, leaves, flowers, seeds and endosperms. Further global expression profiles with RNA sequencing data revealed diverse expression patterns among various tissues. Results obtained from this study not only provide valuable information for future functional analysis and utilization of the castor bean WRKY genes, but also provide a useful reference to investigate the gene family expansion and evolution in Euphorbiaceus plants.

  15. Deacidification of high free fatty acid-containing rice bran oil by non-conventional reesterification process.

    Science.gov (United States)

    Singh, Sibban; Singh, R P

    2009-01-01

    Rice bran (Oryza sativa) oil is known for containing higher amount of free fatty acid (FFA) generated by hydrolytic enzyme. This FFA causes heavy neutral oil losses due to saponification and emulsification since it produces large amount of soap in the conventional alkali refining process. In the present study the FFA of degummed rice bran oil (RBO) was significantly reduced by reesterifying it with glycerol. The reesterification process was carried out by varying the temperature and amount of excess glycerol using 0.2% catalyst (SnCl(2)). The maximum efficiency of the process could be attained at 200 degrees C using 70% excess glycerol and the maximum reduction in acid value (from 24.3 to 3.0) of RBO was observed within 4 h. The reesterified RBO was used to prepare stand oil