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Sample records for castor oil production

  1. Production of Detergent from Castor Oil

    Directory of Open Access Journals (Sweden)

    Abubakar Garba ISAH

    2006-07-01

    Full Text Available This research work was carried out with the objective of extraction of oil from castor seeds and its utilization to produce a synthetic detergent. Solvent extraction method was employed in extracting the oil and the total percent oil yield was found to be 23.8%. The experimentally determined saponification value of the oil was 183.7275mgKOH/g of oil. The detergent efficiency, determined as a measure of the foamability of the detergent was found to be 2.6cm. The pH tests revealed mildly basic properties. The color, scent and efficiency of the detergent were improved with the addition of bleaching agent, perfume and foaming agents respectively.

  2. Optimization of biodiesel production from castor oil by response ...

    African Journals Online (AJOL)

    This work investigated the possibility of using response surface methodology based on a four factor five level central composite design to optimize biodiesel production from castor oil. The reaction variables were oil: ethanol ratio, lipozyme concentration, time and temperature. The properties of the biodiesel produced were ...

  3. Castor Oil: Properties, Uses, and Optimization of Processing Parameters in Commercial Production

    Science.gov (United States)

    Patel, Vinay R.; Dumancas, Gerard G.; Kasi Viswanath, Lakshmi C.; Maples, Randall; Subong, Bryan John J.

    2016-01-01

    Castor oil, produced from castor beans, has long been considered to be of important commercial value primarily for the manufacturing of soaps, lubricants, and coatings, among others. Global castor oil production is concentrated primarily in a small geographic region of Gujarat in Western India. This region is favorable due to its labor-intensive cultivation method and subtropical climate conditions. Entrepreneurs and castor processors in the United States and South America also cultivate castor beans but are faced with the challenge of achieving high castor oil production efficiency, as well as obtaining the desired oil quality. In this manuscript, we provide a detailed analysis of novel processing methods involved in castor oil production. We discuss novel processing methods by explaining specific processing parameters involved in castor oil production. PMID:27656091

  4. Castor and jatropha oils: production strategies – A review

    Directory of Open Access Journals (Sweden)

    Lago Regina C.A.

    2009-07-01

    Full Text Available The Brazilian bioenergy matrix is based on four platforms: ethanol, energy forests, residues and co-products and biodiesel. The food-energy dichotomy in the use of edible oils is one factor which has stimulated the search for non-edible oleaginous energy crops, such as many native palms. By the year 2000 Brazil had an annual deficit of 80 thousand tons of castor oil, making necessary to import oil from China and India. After a strong debate the National Program on Biodiesel Production (NPBP was launched by December 2004. After an initial excessive enthusiasm, small producers being focused in the program, a more mature and realistic planning is undertaken. Production in semi arid lands is being stimulated, mainly castor (Ricinus communis and Jatropha (Jatropha curcas. Apart from belonging to the same botanical family (Euphorbiaceae, both plants are well resistant to poor soils. Castor plant is well adapted to practically the whole country, except for some extreme areas (too low water availability or too much rain. Castor keeps being an alternative for the semi arid region but much more technology is requested to make it largely exploited. Following the petroleum crisis of 1980’s an ambitious research program on Jatropha curcas was initiated, later on discontinued and presently retaken by Embrapa and some Universities. Progress is slower than in the case of Ricinus communis. The first agronomical observations confirmed low productivity, problems with pests and diseases, high harvesting costs etc. Some strategic factors should be considered for the production of castor and Jatropha oils: 1. Production of raw materials; 2. Production of oils; 3. Detoxification and value aggregation to the extraction cakes and residues. Regarding raw material production, it is necessary a strong, long term research program on genetic breeding (short cycle varieties, with high productivity and allowing a sole harvesting, soil fertility, pest control, domestication

  5. Contact Allergy to Castor Oil, but Not to Castor Wax

    Directory of Open Access Journals (Sweden)

    Michel Verheyden

    2017-01-01

    Full Text Available Ricinus communis (castor seed oil (CAS 8001-79-4, a vegetable oil extracted from the seeds of Ricinus communis, is widely used in cosmetics and pharmaceuticals, and may be a cause of allergic contact dermatitis from these products. We present two patients with allergic contact dermatitis from cosmetics containing castor oil, in whom a correct diagnosis was achieved by patch testing castor oil ‘as is’. PEGylated and/or hydrogenated derivatives (the latter formerly also available from patch test allergen suppliers and/or cosmetics containing these specific derivatives did not result in contact allergy or allergic contact dermatitis. This observation might be relevant for the manufacturing of cosmetics and pharmaceuticals. In the future, further research into the allergenicity of castor oil and its numerous derivatives, and their optimal patch test concentrations, may be desirable.

  6. Physicochemical characteristics of castor oil from local wild castor ...

    African Journals Online (AJOL)

    Physicochemical characteristics of castor oil from seeds of the local wild castor plant (Ricinus communis) found in Ghana were determined to evaluate its suitability for exploitation for industrial purposes. The castor seeds were found to be rich in oil, containing 57 per cent castor oil of which 37 per cent was easily expressed ...

  7. Prospective study for the production of oleochemicals derivates from castor oil in Colombia

    National Research Council Canada - National Science Library

    Margarita Guerrero; Paulo César Narváez Rincón

    2010-01-01

    .... Using the prospective, this article outlines the dynamics that will have the oleochemical castor oil sector, because Colombia has resources to develop Ricinus comunnis cultivation and industrial uses...

  8. Integral process of obtaining glycerol as a by-product of biodiesel production from castor oil

    Directory of Open Access Journals (Sweden)

    Leonel Romero

    2012-12-01

    Full Text Available The biodiesel is obtained from about 10 years ago in Europe, and now that it has taken hold as fuel for diesel engines, it is expected a clear increase in the production of this class of fuels in a the near future. The biodiesel is derived from the transesterification reaction of castor oil with methanol, which is the main by-product the glycerol with an approximate content of 10%. Besides catalyst residuals, soaps, methanol traces, mono and diglycerides in small percentages are presented. This study proposes the separation, purification and characterization of the glycerol obtained from the transesterificación reaction of the castor oil, in order to be able to market it in the national or international market, so that it fulfills the standards of quality, which means getting a pure glycerol and the appropriate physico-chemical characteristics and techniques. The glycerin-methyl esters separation is carried out by decantation being obtained a percentage of around 70% glycerol. This percentage is subsequently increased through the purification process, using hydrochloric acid. Glycerol characterization was carried out by physicochemical and organoleptic tests. The purification process allowed us to obtain a glycerol with a percentage of purity close to 98%. It was also tested by comparison with theoretical data that remnants influenced in the physiochemical properties

  9. Biodiesel Production from Castor Oil by Using Calcium Oxide Derived from Mud Clam Shell

    OpenAIRE

    Ismail, S.; Ahmed, A.S.; Reddy Anr; Hamdan, S

    2016-01-01

    The catalytic potential of calcium oxide synthesized from mud clam shell as a heterogeneous catalyst for biodiesel production was studied. The mud clam shell calcium oxide was characterized using particle size analyzer, Fourier transform infrared spectroscopy, scanning electron microscopy, and BET gas sorption analyzer. The catalyst performance of mud clam shell calcium oxide was studied in the transesterification of castor oil as biodiesel. Catalyst characterization and transesterification s...

  10. Alternative castor oil-based polyurethane adhesive used in the production of plywood

    Directory of Open Access Journals (Sweden)

    Fabricio Moura Dias

    2004-09-01

    Full Text Available Plywood is normally produced with urea-formaldehyde and/or phenol-formaldehyde adhesives. However, the former is considerably toxic and environmentally damaging, while the latter is expensive, thus motivating the search for alternative raw materials in plywood production. The castor oil-based polyurethane adhesive developed at the São Carlos Institute of Chemistry, University of São Paulo, is an environmentally friendly vegetal oil-based polymer that is harmless to humans. The wood species Eucalyptus grandis offers favorable properties for plywood the manufacture. The study reported on here involved the use of castor oil-based polyurethane adhesive to produce plywood with Eucalyptus grandis layers. The plywood's performance was evaluated based on the results of physical and mechanical tests recommended by the Brazilian code, ABNT. Tests results showed higher values than those reported in the literature and recommended by the ABNT, indicating that the castor oil-based polyurethane adhesive is a promising glue for the manufacture of plywood.

  11. Evaluating the effect of temperature on biodiesel production from castor oil

    Directory of Open Access Journals (Sweden)

    Carlos Alberto Guerrero Fajardo

    2010-06-01

    Full Text Available Problems arising between biofuels and food as raw materials have led to investigating the use of inedible raw materials for their production. This work was aimed at studying the effect of temperature on converting castor oil in biodiesel production. Oil transesterification with methanol was carried out using an alkaline catalyst (0.5% NaOH - water solution for 1 hour using a 6:1 alcohol/oil molar ratio, at atmospheric pressure and taking temperature as a free variable. The temperature was evaluated at 68°F, 86°F, 104°F and 122ºF. The reaction products were analyzed by gas chromatography (CG-FID for quantifying the fatty acid methyl esters (FAME present. The results showed different dispersion depending on temperature, finding that 122°F resulted in less dispersion than the others. CG-FID analysis showed that most FAME content was reached at 122ºF, such temperature giving the highest ricinoleic acid conversion rate. Gas chromatography also revealed that reaction time was adequate, in process conditions, for obtaining ricinoleic acid-based 94.26% con- version.

  12. Prospective study for the production of oleochemicals derivates from castor oil in Colombia

    Directory of Open Access Journals (Sweden)

    Margarita Guerrero

    2010-04-01

    Full Text Available There are many ways get closet to the future, being the prospective the one that conceives the future, not like an unique reality but like a multiple one, obtained as a result of the identification of the human beign future actions. For all this, the human being takes knowledge, the yearings and the fears that he sees for the actions he will undertake. Using the prospective, this article outlines the dynamics that will have the oleochemical castor oil sector, because Colombia has resources to develop Ricinus comunnis cultivation and industrial uses of castor oil and its derivates. The study establishes the keys that define the current and future behaviour of the system, the position and the power of each one of the involved actors will have, and the determination of the scenarios (future representations with more probability to occur, as well as the definition of the scenario wanted and the strategies that will allow to reach it.

  13. Production and characterization of MDF using eucalyptus fibers and castor oil-based polyurethane resin

    Directory of Open Access Journals (Sweden)

    Campos Cristiane Inácio de

    2004-01-01

    Full Text Available The growing popularity of wooden panels renders this market segment increasingly competitive. MDF (Medium Density Fiberboard, in particular, is widely employed for a variety of applications, including civil construction, furniture, and packaging. This paper discusses a study of MDF produced from alternative raw materials, i.e., Eucalyptus fibers and castor-oil-based polyurethane resin. Physical and mechanical tests were performed to determine the MDF's modulus of elasticity and modulus of rupture in static bending tests, its swelling, water absorption, moisture and density. The results of the physical and mechanical characterization of this laboratory-produced MDF are discussed and compared with the Euro MDF Board standard. MDF produced with eucalyptus fiber and castor-oil-based polyurethane resin presents results very satisfactory.

  14. Production and Characterization of Biodiesel Using Nonedible Castor Oil by Immobilized Lipase from Bacillus aerius

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    Sunil Kumar Narwal

    2015-01-01

    Full Text Available A novel thermotolerant lipase from Bacillus aerius was immobilized on inexpensive silica gel matrix. The immobilized lipase was used for the synthesis of biodiesel using castor oil as a substrate in a solvent free system at 55°C under shaking in a chemical reactor. Several crucial parameters affecting biodiesel yield such as incubation time, temperature, substrate molar ratio, and amount of lipase were optimized. Under the optimized conditions, the highest biodiesel yield was up to 78.13%. The characterization of synthesized biodiesel was done through FTIR spectroscopy, 1H NMR spectra, and gas chromatography.

  15. Synthesis of branched naphthoquinones from castor oil

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    Adriano Olímpio da Silva

    2012-06-01

    Full Text Available The naphthoquinones are cyclic aromatic α,β-dienonas with a basic framework derived from naphthalene. They are also found in many higher plants, algae, fungi and as the product of the  metabolism  of some  bacteria  having large biologica activity described in the literature such as antibacterial, anti-inflammatory, antitumor, anticancer and trypanocidal [1-3]. Castor oil is an abundant raw material in Brazil of great versatility and, it is present in biodiesel production, surfactants, cosmetics and others. Considering the importance of naphthoquinones and, the availability of the ricinoleic acid from castor oil, the aim of this study was the preparation of new branched naphthoquinones in order to test their trypanocidal activity. Castor oil was submitted to saponification with sodium hydroxide, ethanol and water under reflux for 6 h. We then carried out an acid hydrolysis with hydrochloric acid and the formed ricinoleic acid was extracted with ethyl acetate. Following, through Kochi-Anderson addition reaction it was performed the alkylation of a naphthoquinone 1 and 2, using ammonium persulfate, silver nitrate, acetonitrile and water, under heating at 70-80 ° C during 3 h, to give the branched naphthoquinones 4 and 5 (scheme 1. The naphthoquinone 3 will be similarly submitted to this procedure. The naphthoquinones 4 and 5 were purified by column chromatography on sílica gel using hexane as the eluent. The compounds were characterized by mass spectrometry and 1H and 13CNMR spectroscopy.

  16. Modified Castor Oil as an Epoxy Resin Curing Agent

    Directory of Open Access Journals (Sweden)

    B. P. Patel

    2004-01-01

    Full Text Available A castor oil, an agricultural product, is an unsaturated material. Hence the castor oil is brominated by bromine liquid. The brominated castor oil (BCO was then reacted with excess of aliphatic diamines viz; ethylene diamine, 1,3-propane diamine and 1,6-hexane diamine. The resultant amino functionalized castor oil (ACO samples were then characterized by elemental analysis, IR spectral study and number of amino groups. All the three ACO samples were then employed for the curing of commercial Brominated epoxy resin. The curing of epoxy resin by ACO was monitored on differential scanning calorimeter (DSC and based on the DSC study their glass fibre reinforced composites (GRC were fabricated. The cured samples (i.e. unreinforced were also subjected to thermo gravimetric analysis (TGA. The chemical, mechanical and electrical properties of the glass fibre reinforced composites (GRC were also evaluated.

  17. One-pot conjugated linoleic acid production from castor oil by Rhizopus oryzae lipase and resting cells of Lactobacillus plantarum.

    Science.gov (United States)

    Khaskheli, Abid Ali; Talpur, Farah Naz; Cebeci Aydin, Aysun; Jawaid, Sana; Surhio, Muhammad Ali; Afridi, Hassan Imran

    2017-10-01

    Conjugated linoleic acid (CLA) has attracted as novel type of fatty acids having unusual health-promoting properties such as anticarcinogenic and antiobesitic effects. The present work employed castor oil as substrate for one-pot production of CLA using washed cells of Lactobacillus plantarum (L. plantarum) and lipases as catalysts. Among the screened lipases, the lipase Rhizopus oryzae (ROL) greatly assisted resting cells to produce CLA. Mass spectral analysis of the product showed that two major isomers of CLA were produced in the reaction mixture i.e. cis-9, trans-11 56.55% and trans-10, cis-12 43.45%. Optimum factors for CLA synthesis were found as substrate concentration (8 mg/mL), pH (6.5), washed cell concentration (12% w/v), and incubation time of 20 h. Hence, the combination of ROL with L. plantarum offers one pot production of CLA selectively using castor oil as a cost-effective substrate.

  18. Heterogeneous catalysis afford biodiesel of babassu, castor oil and blends

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Lee M.G. de; Abreu, Wiury C. de; Silva, Maria das Gracas de O. e; Matos, Jose Milton E. de; Moura, Carla V.R. de; Moura, Edmilson M. de, E-mail: mmoura@ufpi.edu.br [Universidade Federal do Piaui (UFPI), Teresina, PI (Brazil). Departamento de Quimica; Lima, Jose Renato de O.; Oliveira, Jose Eduardo de [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP/IQ/CEMPEQC), Araraquara, SP (Brazil). Instituto de Quimica. Centro de Monitoramento e Pesquisa da Qualidade de Combustiveis, Biocombustiveis, Petroleo e Derivados

    2013-04-15

    This work describes the preparation of babassu, castor oil biodiesel and mixtures in various proportions of these oils, using alkaline compounds of strontium (SrCO{sub 3} + SrO + Sr (OH){sub 2}) as heterogeneous catalysts. The mixture of oils of these oleaginous sources was used in the production of biodiesel with quality parameters that meet current legislation. The catalyst was characterized by X-ray diffractometry (XDR), physisorption of gas (BET method), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDX) and Fourier transform infrared spectroscopy (FTIR). The viscometric technique was used to monitor the optimization.The transesterification reactions performed using strontium compounds reached conversion rates of 97.2% babassu biodiesel (BB), 96.4% castor oil biodiesel (COB) and 95.3% Babassu/Castor Oil Biodiesel 4:1 (BBCO41). (author)

  19. Castor Oil Transesterification Catalysed by Liquid Enzymes

    DEFF Research Database (Denmark)

    Andrade, Thalles; Errico, Massimiliano; Christensen, Knud Villy

    2017-01-01

    In the present work, biodiesel production by reaction of non-edible castor oil with methanol under enzymatic catalysis is investigated. Two liquid enzymes were tested: Eversa Transform and Resinase HT. Reactions were performed at 35 °C and with a molar ratio of methanol to oil of 6:1. The reaction...... time was 8 hours. Stepwise addition of methanol was necessary to avoid enzyme inhibition by methanol. In order to minimize the enzyme costs, the influence of enzyme activity loss during reuse of both enzymes was evaluated under two distinct conditions. In the former, the enzymes were recovered...... and fully reused; in the latter, a mixture of 50 % reused and 50 % fresh enzymes was tested. In the case of total reuse after three cycles, both enzymes achieved only low conversions. The biodiesel content in the oil-phase using Eversa Transform was 94.21 % for the first cycle, 68.39 % in the second, and 33...

  20. Bio-aviation fuel production from hydroprocessing castor oil promoted by the nickel-based bifunctional catalysts.

    Science.gov (United States)

    Liu, Siyang; Zhu, Qingqing; Guan, Qingxin; He, Liangnian; Li, Wei

    2015-05-01

    Bio-aviation fuel was firstly synthesized by hydroprocessing castor oil in a continuous-flow fixed-bed microreactor with the main objective to obtain the high yield of aviation fuel and determine the elemental compositions of the product phases as well as the reaction mechanism. Highest aviation range alkane yields (91.6 wt%) were achieved with high isomer/n-alkane ratio (i/n) 4.4-7.2 over Ni supported on acidic zeolites. In addition, different fuel range alkanes can be obtained by adjusting the degree of hydrodeoxygenation (HDO) and hydrocracking. And the observations are rationalized by a set of reaction pathways for the various product phases. Copyright © 2015 Elsevier Ltd. All rights reserved.

  1. 75 FR 44917 - Castor Oil, Ethoxylated, Dioleate; Tolerance Exemption

    Science.gov (United States)

    2010-07-30

    ... polymer does not contain any reactive functional groups. Thus, castor oil, ethoxylated, dioleate meets the...-0232; FRL-8835-3] Castor Oil, Ethoxylated, Dioleate; Tolerance Exemption AGENCY: Environmental... requirement of a tolerance for residues of castor oil, ethoxylated, dioleate; when used as an inert ingredient...

  2. CASTOR SEED BIO -TRANSFORMER OIL AS AN ALTERNATIVE TO CONVENTIONAL TRANSFORMER OIL

    OpenAIRE

    Egbuna, S.O.*, Ude, O.C., Ude, C.N.

    2016-01-01

    In search of solution to the harmful ecological problems due to toxicity and non-biodegradability posed by conventional transformer insulation oil (mineral oil), the production of transformer oil from castor seed oil (vegetable oil) was carried out. The oil was extracted using N-hexane and was refined. The transformer oil was produced by trans-esterification and was characterized using American Society for Testing Material (ASTM) standard test. The solvent employed gave good yield of oil from...

  3. AGRIFIS - simulator prospecting scenarios and evaluation of projects for production of seeds, in nature oil and castor oil biodiesel; AGRIFIS - simulador de prospeccao de cenarios e avaliacao de projetos de producao de sementes, oleo in natura e biodiesel de mamona

    Energy Technology Data Exchange (ETDEWEB)

    Polizel, L.H.; Tahan, C.M.V.; Pelegrini, M. A.; Soares, B.F. [Universidade de Sao Paulo (ENERQ/USP), SP (Brazil). Centro de Estudos em Regulacao e Qualidade de Energia], Email: cmvtahan@pea.usp.br; Takeno, H.K. [Companhia Energetica de Petrolina (CEP), PE (Brazil); Silva, O.C. da; Monteiro, B.; Velazquez, S.M.S.G. [Universidade de Sao Paulo (CENBIO/USP), SP (Brazil). Centro Nacional de Referencia em Biomassa; Drumond, M.A.; Anjos, J.B. dos [EMBRAPA Semi-Arido - Empresa Brasileira de Pesquisa Agropecuaria (EMBRAPA), Petrolina, PE (Brazil)

    2006-07-01

    This paper presents a model conceived for scenario prospection and project evaluation of small scale castor bean farming, oil extraction and bio diesel production (transesterification) integrated chain. To evaluate the performance of each project the model adopts financial, social and environmental index such as NPV, IRR, SPB, DPB, production costs, family income, number of settled families and employment. The model was implemented in a computational environment, allowing its use as a decision support tool for investments on the castor bean production chain; it calculates the cash flow of the entire project and of each family, including earnings, debts, taxes, interest and amortization. (author)

  4. Synthesis and characterization of castor oil based polyurethane ...

    Indian Academy of Sciences (India)

    A series of interpenetrating polymer networks (IPNs) of castor oil based polyurethane/polyacrylonitrile (PU/PAN: 80/20, 60/40, 50/50, 40/60 and 20/80) were synthesized by condensation reaction of castor oil with methylene diisocyanate and acrylonitrile, employing benzoyl peroxide (BPO) and ethylene glycol ...

  5. Influence of the reaction conditions on the enzyme catalyzed transesterification of castor oil: A possible step in biodiesel production.

    Science.gov (United States)

    Andrade, Thalles A; Errico, Massimiliano; Christensen, Knud V

    2017-11-01

    The identification of the influence of the reaction parameters is of paramount importance when defining a process design. In this work, non-edible castor oil was reacted with methanol to produce a possible component for biodiesel blends, using liquid enzymes as the catalyst. Temperature, alcohol-to-oil molar ratio, enzyme and added water contents were the reaction parameters evaluated in the transesterification reactions. The optimal conditions, giving the optimal final FAME yield and FFA content in the methyl ester-phase was identified. At 35°C, 6.0 methanol-to-oil molar ratio, 5wt% of enzyme and 5wt% of water contents, 94% of FAME yield and 6.1% of FFA in the final composition were obtained. The investigation was completed with the analysis of the component profiles, showing that at least 8h are necessary to reach a satisfactory FAME yield together with a minor FFA content. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Castor Oil Based Polyurethanes: Synthesis and Characterization

    Science.gov (United States)

    Macalino, AD; Salen, VA; Reyes, LQ

    2017-09-01

    In this study, polyurethanes based on castor oil and 1,6-hexamethylene diisocyanate (HMDI) were synthesized with varying weight ratio of the castor oil and HMDI. The formation of urethane linkages was verified through the use of a fourier transform infrared spectroscopy (FTIR). The hydrophilicity of the films was evaluated through the use of a contact angle meter and it was found that the contact angle of all the films were below 90 degrees which confirms their hydrophilicity. The thermal stability of the PU films were studies through the use of a thermal gravimetric analyzer and found that all of the polyurethane films exhibited two weight loss events at elevated temperatures wherein the first weight loss event was observed to occur at 285°C to 384°C while the second weight loss event was observed at around 521°C to 551°C. The hardness, elastic modulus, and tensile elongation of the PU films were determined by using a universal testing machine (UTM) where it was found out that the hardness and the elastic modulus of the film is directly proportional with HMDI loading while the tensile elongation is inversely proportional to it. Lastly, it was known through the swelling studies of the PU films that it does not swell, this is due to the presence of unreacted triglycerides in the material, which prevents water from permeating to the films.

  7. Transesterification of Castor Oil Catalyzed by Liquid Enzymes

    DEFF Research Database (Denmark)

    Andrade, Thalles; Errico, Massimiliano; Christensen, Knud Villy

    2017-01-01

    was used to determine the optimal reaction conditions to get a high biodiesel yield and a low free fatty acids concentration. The results obtained showed that at 35 °C, 5 wt% of enzymes, 5 wt% of water, and a 6.0 alcohol-to-oil molar ratio, the yield in biodiesel was about 94% with a content of free fatty...... acids of about 6%. This condition was used to develop a reaction equilibrium model using Aspen Plus V8.8. For the main components the difference between the simulated and the experimental data was less than 6%....... economy. Based on this, and considering its low influence with food production, castor oil was investigated as a potential feedstock. Compared to other vegetable oils, it has a higher polarity resulting in better system homogeneity during reaction. The enzyme tested as catalyst was Eversa Transform. Four...

  8. Castor oil biodiesel: an economic evaluation; Biodiesel de mamona: uma avaliacao economica

    Energy Technology Data Exchange (ETDEWEB)

    Pires, Monica de Moura; Alves, Jaenes Miranda; Almeida Neto, Jose Adolfo de; Almeida, Cezar Menezes; Sousa, Geovania Silva de; Cruz, Rosenira Serpa da; Monteiro, Renata; Lopes, Beatriz Sampaio; Robra, Sabine [Universidade Estadual de Santa Cruz, Ilheus, BA (Brazil). Grupo Bioenergia e Meio Ambiente]. E-mails: mpires@uesc.br; jaenes@uesc.br; jalmeida@uesc.br; roserpa@uesc.br

    2004-07-01

    The production cost of castor oil biodiesel by methyl way and its economic viability, using as reference the production cost data of castor oil and the implantation of the pilot plant at UESC - state university of Santa Cruz, Bahia State, Brazil was determined. From this information, it was seen that the estimated price of castor oil biodiesel is close to the diesel price in the Itabuna market, Bahia state, Brazil. The indicators show economic viability of the mini-power plant installation. Such information are preliminary estimative for the market and can be modified as function of changes in the main factors used to have the production costs, as well as the sectorial policies that drives the activity as much in levels of raw material production as in biodiesel.

  9. TRANSFORMATION OF RICINOLEIC OF CASTOR OIL INTO LINOLEIC (OMEGA-6 AND CONJUGATED LINOLEIC ACID BY DEHYDRATION

    Directory of Open Access Journals (Sweden)

    Marham Sitorus

    2010-06-01

    Full Text Available The ricinoleic of Castor Oil was dehydrated by various dehydrator agent (P2O5, K2CO3, H3PO4, NaHSO4, Al2O3, molecular sieve and activated bentonite at 450 °C - HCl on the same condition (150 °C, mol ratio 1:1 and 2 hours . The compositions of Refined Ricinus Castor Oil as starting material were : 0.92% palmitic , 5.56% linoleic , 4.07% octadecanoic , 1.22% stearic and 85.06% ricinoleic. The spesific wave number of IR was bandwith 3411 cm-1 caused of hydroxyl (-OH group of ricinoleic at C-12 as main component. The product was Dehydrated Castor Oil (DCO mixed of linoleic (omega 6 [C18 : 2 (9,12] and Conjugated Linoleic Acid (CLA [C18: 2 (9,11]. The best dehydrator was P2O5 based on three parameters were : Free Fatty Acid (FFA nearly the same (1.855% of Castor oil and 2.139% of DCO, the most increased of Iodium value (49.860 mg/g of Castor oil in to 63.090 mg/g of DCO, and the most decresed of hydroxyl number (28.27 mg of Castor oil in to 17.75 mg/g of DCO. To optimized the dehydration was done by various number of P2O5 (3g, 5g and 7g, tempereture (room, 100 °C and 150 °C and time (2h, 2.5h, 3h, and 3.5h. The optimal conditon of dehydration was not found yet. Some of sugestted or idea for dehydration were: dehydration must be done by base or netral, non oxydator dehydrator, mol ratio 1:1, temperature (100-150 °C and 2-3.5 h. Based on GC-MS the best DCO (7g P2O5, 150 °C and 3.5 h were showed that the decrease of ricinoleic 14.13% (85.08% of Castor Oil in to 70.93% of DCO, increased linoleic 2.09% (5.56 of Castor oil in to 7.65% of DCO and conducted of 9.09% CLA. Some new peaks between linoleic and ricinoleic are maybe isomer's of linoleic and CLA. The wave number of cunjugated alkene (C=C (1666.3 cm-1 of IR spectra of DCO together with GC-MS chromatogram's to indicated that linoleic and CLA were conducted.   Keywords: castor oil, risinoleic, dehydration, omega 6 dan CLA

  10. Extraction, Characterization and Modification of Castor Seed Oil

    Directory of Open Access Journals (Sweden)

    A. D. MOHAMMED

    2006-01-01

    Full Text Available This paper carried out experimental study, through extraction and characterization of both crude and refined castor oil. Normal hexane was used as solvent for the extraction process. The oil produced was refined through degumming, neutralization and bleaching process using local adsorbent (activated clay. The characterization analysis revealed that tested parameters, which include specific gravity, refractive index, acid value, saponification value and iodine value for both crude and refined castor oil produced, were within the ASTM standard specifications. In fact the iodine value obtained (84.8 for the refined oil indicates that the oil could certainly be used as lubricant, hydraulic break fluid and protecting coatings. The oil was modified via sulphation method to produce Turkey – red oil that was tested on wooden material, paper and cloth. The test revealed that the Turkey – red oil produced is suitable to be used as a good dying agent and polish.

  11. LDPE/PHB blends filled with castor oil pressed cake

    OpenAIRE

    Burlein,Gustavo A. D.; Rocha,Marisa C. G.

    2014-01-01

    Blends of PHB and LDPE were prepared by melt mixing in a twin screw extruder. Castor oil pressed cake (CC) was used as filler for the blends. The mixture design technique was used to evaluate the effect of the components proportion on the materials flexural properties. The results show that superior LDPE flexural properties may be obtained by the addition of PHB or castor oil cake to LDPE. Biodegradation was evaluated burying the samples in simulated soil for different periods of time. The te...

  12. Comparative Analysis of Flame Characteristics of Castor Oil and ...

    African Journals Online (AJOL)

    The flame characteristics of castor oil based foam and that of polyether foam impregnated with inorganic flame retardants (FR) were investigated. The polyether foams were impregnated with measured concentration of Antimony trioxide and Sodium bromide, Ammonium dihydrogen orthophosphate, Diammonium hydrogen ...

  13. Comparative Analysis of Flame Characteristics of Castor Oil and ...

    African Journals Online (AJOL)

    ABSTRACT: The flame characteristics of castor oil based foam and that of polyether foam impregnated with inorganic flame retardants (FR) were investigated. The polyether foams were impregnated with measured concentration of Antimony trioxide and Sodium bromide, Ammonium dihydrogen orthophosphate ...

  14. Selective production of ricinoleic acid by hydrolysis of castor oil using lipase immobilized in N-polyisopropylacrylamide gel; Ripaze koteika N-poriisopuropiruakuriruamidogeru wo mochiita himashiyu no kasuibunaki ni yoru rishinorusan no sentakuteki seisei

    Energy Technology Data Exchange (ETDEWEB)

    Goto, M.; Hatanaka, C.; Haraguchi, T. [Kitakyushu National College of Technology, Fukuoka (Japan)

    2000-05-10

    Lipase from Candida cylindracea or Rhizopus was immobilized in gel beads prepared by copolymerization of N-isopropylacrylamide, N-N'-methylenebisacrylamide, and acrylamide. The hydrolysis reaction of castor oil was carried out at 37 degree C by using immobilized lipase or free lipase. The optimal condition of immobilization of lipase and the productivity of ricinoleic acid is investigated. It is found that thermal inactivation of enzyme was suppressed and the formation of by-products such as estolide decreases by immobilization into the gel compared with free lipase. (author)

  15. A survey of the castor oil content, seed weight and seed-coat colour on the United States Department of Agriculture germplasm collection.

    Science.gov (United States)

    Castor bean is an important non-edible oilseed crop that can potentially be used as feedstock for biodiesel production. Cultivars with a high percentage of oil content in seeds are preferred for biodiesel production. There are 1033 accessions in the USDA castor bean germplasm collection. The range o...

  16. Optimization of transesterification reaction conditions for the production of biodiesel from oil blend of castor bean and soybean; Otimizacao das condicoes reacionais de transesterizacao para producao de biodiesel a partir de mistura de oleos de mamona e soja

    Energy Technology Data Exchange (ETDEWEB)

    Lobato, Ana Katerine de Carvalho Lima; Lima, Milena Gouveia Oliveira de; Pontes, Luiz Antonio M.; Teixeira, Leonardo S.G. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil); Almeida, Daniel Freire; Costa, Tales Santana Martins; Menezes; Mateus Della Cella; Santos, Iran Talis Viana; Almeida, Selmo Q. [Universidade Salvador (UNIFACS), BA (Brazil)

    2012-07-01

    Biodiesel is an alternative fuel to diesel oil, and industrially obtained by the transesterification of triglycerides of fatty acids from vegetable oils and/or animal fats. Currently, the main raw material used to produce biodiesel in Brazil is soybean oil. The inclusion of other raw materials from different cultures in this sector is important and aims to reduce dependence on a single oilseed, assign specific characteristics to the product and encourage the development of family farming. The use of blends of soybean oil and castor for biodiesel may prove an important strategy to minimize the negative effects and maximize the positives of each oilseed. In this work, we carried out an experimental study using full factorial design 2{sup 4}, to increase the conversion of esters, by conventional transesterification, using as feedstock a blend of oils containing 20% castor and 80% soybean. The aim of this study was to evaluate the influence of mixing ratio of oil: methanol, KOH concentration, temperature and reaction time in biodiesel production. It was found that the variation of these parameters affected the conversion of esters and quality of biodiesel produced. Conversions above 95% were obtained, and the best conversion was 99.05% at 25 deg C in a reaction time of 20 minutes using 2% KOH as a catalyst and a molar ratio methanol/oil 12:1. In order to reduce the costs of the process with respect to amount of methanol used without affecting the conversion of esters, we identified a second set of process conditions, which used the same conditions of temperature, reaction time and catalyst concentration and a different molar ratio methanol/oil (6:1) which gave a conversion of esters of 98.59%. (author)

  17. Energetic balance of castor oil methyl and ethyl esters; Balanco energetico de esteres metilicos e etilicos de oleo de mamona

    Energy Technology Data Exchange (ETDEWEB)

    Almeida Neto, Jose Adolfo de; Cruz, Rosenira Serpa da; Alves, Jaenes Miranda; Pires, Monica de Moura; Robra, Sabine [Universidade Estadual de Santa Cruz, Ilheus BA (Brazil). Grupo Bioenergia e Meio Ambiente]. E-mails: jalmeida@uesc.br; Parente Junior, Expedito [Tecnologias Bioenergeticas Ltda. (TECBIO), Fortaleza, CE (Brazil); Fundacao Nucleo de Tecnologia Industrial (NUTEC), Fortaleza, CE (Brazil)]. E-mail: expeditojr@tecbio.com.br

    2004-07-01

    Castor oil (Ricinus communis L.) is one of the cultures chosen by the biodiesel federal and state programs to supply raw material for biodiesel production - a biofuel indicated as renewable and less pollutant than its fossil competitor. An energetic balance was performed based on LCA - Life Cycle Analysis principles and Input-Output Analysis, comparing the castor oil energy performance with others traditional cultures: colza (Brassica napus) in Europe and soybean (Glycine max) in the United States. Energy balance (O-I) was positive in both production ways (methyl and ethyl) independent of coproduct use allocation alternative. The relation Output-Input (O-I) calculated for castor oil biodiesel [1.3-2.9] was higher than the colza (1.2-1.9) and lower than the soybean (3.2--3.4), independent of the way and allocation of the used byproduct. Both indicators suggest the energy and environmental viability of the castor oil biodiesel, provided that high agricultural productivity (higher than 1.500 kg/ha year) can be guaranteed. The potentialization of the positive energetic and environmental effects depends on the adequate utilization of the coproducts and process residues, the improvement of the energy efficiency in the the castor oil and biodiesel processing and the implementation of efficient management in the use of the chemical inputs (specially the N), responsible for up 5% of the total energy input.

  18. Evaluation of Castor Oil Cake Starch and Recovered Glycerol and Development of “Green” Composites Based on Those with Plant Fibers

    National Research Council Canada - National Science Library

    Guimarães, José; Trindade Cursino, Ana; Ketzer Saul, Cyro; Sierrakowski, Maria; Ramos, Luiz; Satyanarayana, Kestur

    2016-01-01

    ...) and castor oil cake (COC), the two byproducts of biodiesel production. These are expected to help, not only in addressing environmental safety, but also in adding value to those byproducts, which otherwise may go to waste...

  19. Synthesis and characterization of dialkanolamides from castor oil (Ricinus communis) as nonionic surfactant

    Science.gov (United States)

    Anwar, M.; Wahyuningsih, T. D.

    2017-12-01

    Nonionic surfactant of dialkanolamide derivates was synthesized and characterized from castor oil (Ricinus comunnis). Ricinoleic acid was isolated from castor oil by hydrolysis in alkaline (KOH) condition at 65 °C. Oxidation of ricinoleic acid by dilute potassium permanganate (KMnO4) in alkaline condition at 75-90 °C gave dicarboxylic acid which was then reacted with ethanolamine at 140-160 °C for 6 hours. The product was recrystallized with isopropanol, and the structure elucidation was performed by FTIR, 1HNMR spectrometer, and GC-MS with silylation method. Characterization of surfactants was carried out by surface tension measurement (capillary rise method), Critical Micelle Concentration (CMC) based on turbidity method and calculation of Hydrophilic-Lipophilic Balance (HLB) value with Griffin method and Bancroft rule. The result showed that ricinoleic acid in castor oil is 86.19 % and it is oxidation give an azelaic acid and octanedioic acid in 53.25 %. Amidation of a dicarboxylic acid and ethanolamine at 140-160 °C for 6 hours yielded of N1,N9-bis(2-hydroxyethyl)nona diamide in 49.35 %. Surfactant characterization indicates that dialkanolamide derivates can be used as a surfactant due to its ability to reduce the surface tension of ethanol with CMC at 1.2 g/L, HLB value is 5.58 and can be used as emulsifier water in oil (W/O).

  20. the use of castor oil as a flame retardant in polyurethane foam

    African Journals Online (AJOL)

    Dr Abdusalam

    ABSTRACT. Thirteen polyurethane foam samples were prepared with varying quantity of castor oil as a reactant with polyisocyanate and their flammability test was carried out using various flame test procedures. Physical properties of the foam samples were found to increase with the increasing in the quantity of castor oil.

  1. Synthesis and membrane performance characterization of self-emulsified waterborne nitrocellulose dispersion modified with castor oil

    Energy Technology Data Exchange (ETDEWEB)

    Su, Xiuxia; Zhao, Qingxiao, E-mail: 934481965@qq.com; Zhang, Dan; Dong, Wei

    2015-11-30

    Graphical abstract: - Highlights: • Waterborne nitrocellulose dispersion modified with castor oil (CWNC) was synthesized successfully. • It is a kind of environment-friendly coatings, in which volatile organic content (VOC) is near zero. • Castor oil used as an internal crosslinking agent for WNC improved the properties of the coating. • When the mass fraction of castor oil to total reactants is 7%, emulsion and the coating are of the best comprehensive performance. - Abstract: Waterborne nitrocellulose dispersion modified with castor oil (CWNC) was designed and successfully synthesized by self emulsification and reaction among isophorone diisocyanate (IPDI) trimer, dimethylol propionic acid (DMPA), nitrocellulose (NC) and castor oil (C.O.). The CWNC was characterized by transmission electron microscope (TEM), Fourier transform infrared (FTIR) spectroscopy and thermal gravimetric analysis (TGA), etc. The particle size of CWNC increased with the increase of mass fraction of castor oil to total reactants, ω (C.O.). The morphology of particles is an approximate core–shell structure indicated by TEM. FTIR confirmed that the reactions (i.e. IPDI trimer and castor oil, IPDI trimer and NC) occurred, the NCO groups of IPDI trimer were consumed totally and the backbone of NC was retained. The water contact angle measurements confirmed that introduced castor oil increased hydrophobicity of the film, thereby increasing the contact angle. TGA revealed that the CWNC film had better thermal resistance.

  2. Effect of powdered castor oil seed ( Ricinus communis L.) on some ...

    African Journals Online (AJOL)

    The rats were in five groups, which were replicated three (3) times. The castor oil seed was turned to powdery form using pestle and mortal. Four feed formulations were used; powdered castor oil seed and commercial rat feed mixed in ratio 1:1, 1:2, 1:5, 1:10 and ordinary commercial rat feed, which serves as the control.

  3. Synthesis and membrane performance characterization of self-emulsified waterborne nitrocellulose dispersion modified with castor oil

    Science.gov (United States)

    Su, Xiuxia; Zhao, Qingxiao; Zhang, Dan; Dong, Wei

    2015-11-01

    Waterborne nitrocellulose dispersion modified with castor oil (CWNC) was designed and successfully synthesized by self emulsification and reaction among isophorone diisocyanate (IPDI) trimer, dimethylol propionic acid (DMPA), nitrocellulose (NC) and castor oil (C.O.). The CWNC was characterized by transmission electron microscope (TEM), Fourier transform infrared (FTIR) spectroscopy and thermal gravimetric analysis (TGA), etc. The particle size of CWNC increased with the increase of mass fraction of castor oil to total reactants, ω (C.O.). The morphology of particles is an approximate core-shell structure indicated by TEM. FTIR confirmed that the reactions (i.e. IPDI trimer and castor oil, IPDI trimer and NC) occurred, the NCO groups of IPDI trimer were consumed totally and the backbone of NC was retained. The water contact angle measurements confirmed that introduced castor oil increased hydrophobicity of the film, thereby increasing the contact angle. TGA revealed that the CWNC film had better thermal resistance.

  4. Characterization and Digestibility of Detoxified Castor Oil Meal for Japanese Quails

    Directory of Open Access Journals (Sweden)

    PA dos Santos

    2015-12-01

    Full Text Available ABSTRACT These experiments were performed to determine the chemical composition, coefficients of nutrient and energy metabolizability, amino acid composition, and cytotoxicity of different castor oil meals subjected to different detoxification processes and added to the diet of Japanese quails. In the trial, 180 46-d-old female Japanese quails were distributed according to a completely randomized design into five treatments and with replicates of six bird each. The treatments consisted of following detoxification methods of castor oil meal: Castor oil meal A (CMA - recovery in alcohol at 80 °C for 20 minutes and drying at 80 °C; castor oil meal B (CMB and C (CMC - recovery in alcohol at 80 °C for 6 minutes, neutralization with 5% NaOH, and drying under direct sunlight sun for two days (CMB or pelleted (CMC; castor oil meal D (CMD - recovery in alcohol at 110 °C for 15 minutes and drying at 110 °C. Castor oil meal was added replacing 20% of the reference diet. There was slight chemical composition variation (1.21% in crude protein, 6% in dry matter, 2.2% in ether extract and 64 kcal/kg in gross energy among the castor oil meals submitted to the different treatments. The castor oil meal submitted to treatment C showed the highest amino acid values. In the cytotoxicity test, treatment D presented lower ricin activity. Castor oil meals A, C, and D may be included in Japanese quail diets; however, castor oil meal D is recommended due to the simplicity its industrial process, its low toxicity, and metabolizability coefficients obtained.

  5. Characterization of Novel Castor Oil-Based Polyurethane Polymer Electrolytes

    Directory of Open Access Journals (Sweden)

    Salmiah Ibrahim

    2015-04-01

    Full Text Available Castor oil-based polyurethane as a renewable resource polymer has been synthesized for application as a host in polymer electrolyte for electrochemical devices. The polyurethane was added with LiI and NaI in different wt% to form a film of polymer electrolytes. The films were characterized by using attenuated total reflectance-Fourier transform infrared spectroscopy, dynamic mechanical analysis, electrochemical impedance spectroscopy, linear sweep voltammetry and transference number measurement. The highest conductivity of 1.42 × 10−6 S cm−1 was achieved with the addition of 30 wt% LiI and 4.28 × 10−7 S·cm−1 upon addition of 30 wt% NaI at room temperature. The temperature dependence conductivity plot indicated that both systems obeyed Arrhenius law. The activation energy for the PU-LiI and PU-NaI systems were 0.13 and 0.22 eV. Glass transition temperature of the synthesized polyurethane decreased from −15.8 °C to ~ −26 to −28 °C upon salts addition. These characterizations exhibited the castor oil-based polyurethane polymer electrolytes have potential to be used as alternative membrane for electrochemical devices.

  6. LDPE/PHB blends filled with castor oil cake

    Science.gov (United States)

    Burlein, Gustavo A.; Rocha, Marisa C. G.

    2015-05-01

    The response surface methodology (RSM) is a collection of mathematical techniques useful for developing, improving and optimizing process. In this study, RSM technique was applied to evaluate the effect of the components proportion on the mechanical properties of low density polyethylene (LDPE)/ poly (3-hydroxy-butyrate) (PHB) blends filled with castor oil cake (CC). The blends were prepared by melt mixing in a twin screw extruder. Low density polyethylene, poly (3-hydroxy-butyrate) and castor oil pressed cake were represented by the input variables designated as LDPE, PHB and CC, respectively. As it was desirable to consider the largest LDPE content in the ternary system, the components of the mixture were subjected to the following constraints: 0.7 ≤ LDPE ≤ 1.0, 0≤ PHB≤0.3 e 0 ≤ CC ≤0.3. The mechanical properties of the different mixtures were determined by conventional ASTM tests and were evaluated through analysis of variance performed by the Minitab software. Some polynomial equations were tested in order to describe the mechanical behavior of the samples. The quadratic model in pseudo components was selected for describing the tensile behavior because it was the most efficient from a statistical point of view (p-value ≤ 0.05; coefficient of determination (r2) close to 1 and variation inflation factor (VIF) values oil cake to LDPE. The morphological study of the materials obtained showed that LDPE/PHB blends are immiscible and form morphological structures with well distinguished phase boundaries between dispersed phase and matrix. Biodegradation was evaluated burying the samples in simulated soil for different periods of time. The LDPE/PHB/CC mixtures with higher content of PHB showed more pronounced degradation. Under the experimental conditions studied the LDPE/CC compositions presented no degradation. However, the loss of mass of the LDPE/PHB/CC mixtures was higher than the loss of mass of the corresponding LDPE/PHB binary blend. This result

  7. Collection of castor-oil plant germoplasm (Ricinus communis L. in two municipalities of Arauca, Colombia

    Directory of Open Access Journals (Sweden)

    Carlos Iván Cardozo Conde

    2013-05-01

    Full Text Available Ricinus communis L., commonly known as the castor-oil plant, is important for its use in biofuels production. With the objective of learning about its current status, in 40 villages influential to the oil complex of Caricare (municipality of Arauquita and Caño Limón (municipality of Arauca in Arauca, Colombia (where five years earlier the crop had been established, a collection of sexual seed was carried out between December 2011 and January 2012. The variables studied include passport data as a collection resource, local name, relief, and soil type among others. A Garmin map76CSx was used in order to identify the transects and record data such as geographic location and elevation. Simple descriptive statistics were used to identify the variables of greatest variation. Using the qualitative variables of greatest importance, a contingency table analysis with a significance level of 5%, a multiple correspondence analysis (MCA and principal component analysis (PCA were performed for quantitative and qualitative variables, in addition to a classification analysis through a similarity matrix. The castor-oil plant was found in 25% of the villages visited. 12 introductions were collected, four from Caricare and eight from Caño Limón. Although the environmental conditions were favo­rable for its cultivation, there are no castor-oil plant crops in the locations visited. The absence of grain commercialization and oil extraction equipment is the main limiting factor. A garden was established using collected materials for the purpose of research, breeding and propagation.

  8. Final report on the safety assessment of Ricinus Communis (Castor) Seed Oil, Hydrogenated Castor Oil, Glyceryl Ricinoleate, Glyceryl Ricinoleate SE, Ricinoleic Acid, Potassium Ricinoleate, Sodium Ricinoleate, Zinc Ricinoleate, Cetyl Ricinoleate, Ethyl Ricinoleate, Glycol Ricinoleate, Isopropyl Ricinoleate, Methyl Ricinoleate, and Octyldodecyl Ricinoleate.

    Science.gov (United States)

    2007-01-01

    The oil derived from the seed of the Ricinus communis plant and its primary constituent, Ricinoleic Acid, along with certain of its salts and esters function primarily as skin-conditioning agents, emulsion stabilizers, and surfactants in cosmetics, although other functions are described. Ricinus Communis (Castor) Seed Oil is the naming convention for castor oil used in cosmetics. It is produced by cold pressing the seeds and subsequent clarification of the oil by heat. Castor oil does not contain ricin because ricin does not partition into the oil. Castor oil and Glyceryl Ricinoleate absorb ultraviolet (UV) light, with a maximum absorbance at 270 nm. Castor oil and Hydrogenated Castor Oil reportedly were used in 769 and 202 cosmetic products, respectively, in 2002; fewer uses were reported for the other ingredients in this group. The highest reported use concentration (81%) for castor oil is associated with lipstick. Castor oil is classified by Food and Drug Administration (FDA) as generally recognized as safe and effective for use as a stimulant laxative. The Joint Food and Agriculture Organization (FAO)/World Health Organization (WHO) Expert Committee on Food Additives established an acceptable daily castor oil intake (for man) of 0 to 0.7 mg/kg body weight. Castor oil is hydrolyzed in the small intestine by pancreatic enzymes, leading to the release of glycerol and Ricinoleic Acid, although 3,6-epoxyoctanedioic acid, 3,6-epoxydecanedioic acid, and 3,6-epoxydodecanedioic acid also appear to be metabolites. Castor oil and Ricinoleic Acid can enhance the transdermal penetration of other chemicals. Although chemically similar to prostaglandin E(1), Ricinoleic Acid did not have the same physiological properties. These ingredients are not acute toxicants, and a National Toxicology Program (NTP) subchronic oral toxicity study using castor oil at concentrations up to 10% in the diet of rats was not toxic. Other subchronic studies of castor oil produced similar findings

  9. Application of Taguchi design to produce polyols based on castor oil derivatives with diethylene glycol

    Directory of Open Access Journals (Sweden)

    Thiago Alessandre da Silva

    2015-04-01

    Full Text Available Castor oil (CO is one of the most valuable oils, because of its characteristics and potential use in synthesis.  A simple way to modify the castor oil structure is the transesterification reaction with an alcohol. Through this reaction, a renewable polyol could be produced and applied in the polyurethane industry.  In this study, the transesterification was done by KOH catalysis following a Taguchi experimental design.  The chosen alcohol was diethylene glycol (DEG and the product components were estimated by GPC.  This chromatographic technique allowed establishment of the most favorable conditions to produce monosubstituted DEG or disubstituted DEG.  In the conditions suggested by the Taguchi design, the condition that favors monosubstituted DEG is 9:1 DEG:CO molar ratios, 200°C for 4 h and 0.5% KOH.  This condition leads to approximately 75% monosubstituted DEG and 11% disubstituted DEG in a mixture with the remaining acylglycerols.  The hydroxyl value of this product is 407, a high value for a product with a relatively low molecular weight.  These characteristics suggest that it can be used as a polyol for polyurethanes.

  10. Apis mellifera pollination improves agronomic productivity of anemophilous castor bean (Ricinus communis).

    Science.gov (United States)

    Rizzardo, Rômulo A G; Milfont, Marcelo O; Silva, Eva M S da; Freitas, Breno M

    2012-12-01

    Castor bean (Ricinus communis L.) is cultivated mainly for biodiesel production because of its oil-rich seeds; it is assumed to be an anemophylous species. But pollination deficit can lead to low productivity often attributed to other reasons. In this paper, we investigated pollination requirements, pollination mechanism, occurrence of pollination deficit, and the role of biotic pollinators in a large commercial plantation of castor bean. Our results show that R. communis bears a mixed breeding system favoring selfing by geitonogamy, although the wind promotes mostly outcrossing. We also found that the honey bee (Apis mellifera L.) foraging on castor bean can both transfer pollen from male to female flowers within the same raceme and boost the release of airborne pollen by male flowers. Both situations increase geitonogamy rates, raising significantly fruit set and seed yield. This is the first report of an animal foraging activity increasing seed yield in an anemophilous and geitonogamous crop and elucidates the role of biotic pollinators in castor bean reproduction.

  11. Sorption of oil in the polyurethane from oil or castor oil; Sorcao de oleo no poliuretano derivado do petroleo ou do oleo de mamona

    Energy Technology Data Exchange (ETDEWEB)

    Florentino, Wagner M.; Goulart, Shane A.S.; Mulinari, Daniella R. [Centro Universitario de Volta Redonda (UniFOA), Volta Redonda, RJ (Brazil)], e-mail: wagner-can@hotmail.com

    2011-07-01

    The oil outpouring has caused serious environmental problems. To minimize this damage polyurethane foams have been used. In this work, the use of polyurethane from oil and castor oil, in different polyol/diisocyanate mass ratios, to absorb oil was evaluated. Results revealed that the proportion of polyol and diisocyanate influenced in the sorption capacity and the polyurethane from castor oil presented greater sorption capacity. Of this way, can say that the polyurethane from oil can be replaced by castor oil, contributing to sustainable development. (author)

  12. The investigation reaction kinetic for polyurethanes based on different types of diisocyanate and castor oil

    Directory of Open Access Journals (Sweden)

    Ristić Ivan S.

    2012-01-01

    Full Text Available The formation of polyurethanes based on vegetable oils is very complex and thus for industrial production of this materials it is important to determine the optimal temperature for polymerisation and finally to obtain materials with the proper mechanical properties. The goal of this work was to assess the kinetic of catalysed and noncatalysed reactions for polyurethanes based on castor oil as the polyol component and different types of diisocyanates. Due to the presences of hydroxyl groups on ricinoleic acid, castor oil is suitable for polyurethane preparation. The differential scanning calorimetry has been employed to study the polyurethane formation reaction using Ozawa isoconversion method. It was estimated that the catalyst addition decreases the activation energy. The highest reduction of activation energy was observed for the reactive systems with hexamethylene diisocyanate. Validity of obtained kinetic model was examined by FTIR spectroscopy following the apsorption of reactive groups. Obtained results of mechanical characteristics of the polyuretahane networks (with different NCO/OH ratio confirmed that applied method could be used for prediction of optimal reaction condition in polyurethane networks synthesis.

  13. Sugarcane bagasse and castor oil polyurethane adhesive-based particulate composite

    Directory of Open Access Journals (Sweden)

    Juliano Fiorelli

    2013-04-01

    Full Text Available This paper discusses the potential use of sugarcane bagasse in two different fiber lengths (5 mm and 8 mm of the same density as a raw material for the production of particleboards, using castor oil-based two-component polyurethane adhesive. The quality of the product that can be manufactured industrially was evaluated based on density, thickness swell (TS, absorption (WA, modulus of elasticity (MOE, modulus of rupture (MOR in static bending and internal bond (IB, according to the Brazilian NBR 14.810:2006 standard. The results revealed a significant difference between the particleboards made with 5-mm-long fibers and those made with 8-mm-long fibers. An analysis by scanning electron microscopy (SEM indicates that the interparticle spaces are filled with castor oil-based two-component polyurethane adhesive, contributing to improve the physicomechanical properties of the particleboards. A durability assessment based on accelerated aging tests shows that waterproofed particleboards can be used in moist environments.

  14. Isocyanate-Functionalized Chitin and Chitosan as Gelling Agents of Castor Oil

    Directory of Open Access Journals (Sweden)

    José M. Franco

    2013-06-01

    Full Text Available The main objective of this work was the incorporation of reactive isocyanate groups into chitin and chitosan in order to effectively use the products as reactive thickening agents in castor oil. The resulting gel-like dispersions could be potentially used as biodegradable lubricating greases. Three different NCO–functionalized polymers were obtained: two of them by promoting the reaction of chitosan with 1,6-hexamethylene diisocyanate (HMDI, and the other by using chitin instead of chitosan. These polymers were characterized through 1H-NMR, FTIR and thermogravimetric analysis (TGA. Thermal and rheological behaviours of the oleogels prepared by dispersing these polymers in castor oil were studied by means of TGA and small-amplitude oscillatory shear (SAOS measurements. The evolution and values of the linear viscoelasticity functions with frequency for –NCO–functionalized chitosan- and chitin-based oleogels are quite similar to those found for standard lubricating greases. In relation to long-term stability of these oleogels, no phase separation was observed and the values of viscoelastic functions increase significantly during the first seven days of ageing, and then remain almost constant. TGA analysis showed that the degradation temperature of the resulting oleogels is higher than that found for traditional lubricating greases.

  15. Rheological behavior of castor oil mixed with different pyromellitic esters

    Directory of Open Access Journals (Sweden)

    Boran Sorina

    2014-01-01

    Full Text Available The paper presents the rheological behavior study of castor oil mixed with different pyromellitic esters. The pyromellitic tetraesters used were obtained through the esterification of pyromellitic anhydride with a special alcohol of a complex alkyl-aryl structure (2-phenoxy-ethanol in conjunction with a linear aliphatic alcohol with variable length (n-butanol, n-decanol. The influence of pyromellitic esters’ structure and concentration was determined, as well as that of temperature, on the rheological behavior, by setting the dependence between the shear stress τ and the shear rate γ. The analysis of dependence between τ and γ demonstrates that the studied solutions have Newtonian behavior. The evolution of samples' viscosity with temperature was characterized by Arrhenius type equations, being established the values of viscous flow activation energy, Ea. This constant can be correlated with the effect of reducing friction in the presence of additives. It was also realized a characterization of annulus fluids flow under the effect of rotational motion, calculating the values of Taylor-Reynolds number (TaRe.

  16. Bowel Preparation of Outpatients for Intravenous Urography: Efficacy of Castor Oil Versus Bisacodyl

    Directory of Open Access Journals (Sweden)

    Huei-Chen Yang

    2005-04-01

    Full Text Available The purpose of this study was to compare the efficacy of two laxatives, castor oil and bisacodyl, in the routine bowel preparation of outpatients for intravenous urography (IVU. We used castor oil in patients undergoing IVU for 1 month, and then used bisacodyl in patients undergoing IVU for another month. Two uroradiologists, unaware of the method of bowel preparation, reviewed the standard radiographs and graded the residue in the large bowel and the clearness of the opacified urinary collecting system. In total, 71 consecutive outpatients received castor oil, and 84 received bisacodyl. For the castor oil group, grades from the two uroradiologists did not differ in terms of fecal residue on plain abdominal images (p = 0.54, and visualization of the urinary system on the left (p = 0.36 and right sides (p = 0.63. Findings were similar for bisacodyl recipients (p = 0.11, 0.59, and 0.32, respectively. When the laxative effect of the two agents was compared, we found no difference in the grading of fecal residue on plain abdominal images (p = 0.14, or in visualization of the urinary system on the left (p = 0.31 and right sides (p = 0.98. In conclusion, we observed no difference in laxative efficacy between castor oil and bisacodyl; thus, bisacodyl may be a useful alternative for bowel preparation before IVU.

  17. Effectiveness of castor oil extract on Escherichia coli and its endotoxins in root canals.

    Science.gov (United States)

    Valera, Marcia Carneiro; Maekawa, Lilian Eiko; Chung, Adriana; de Oliveira, Luciane Dias; Carvalho, Claudio Antonio Talge; Koga-Ito, Cristiane Yumi; Jorge, Antonio Olavo Cardoso

    2012-01-01

    This in vitro study sought to evaluate the effectiveness of castor oil extract used as an irrigating solution on Escherichia coli and its endotoxins in root canals. Sixty single-rooted teeth were prepared (using castor oil extract as irrigating solution) and divided into five groups (n = 12): Group 1 samples were treated with calcium hydroxide (Ca(OH)2), Group 2 samples were treated with polymyxin B, Group 3 samples were treated with Ca(OH)2 and 2% chlorhexidine gel (CHX), and Group 4 samples were treated with castor oil extract. A control group used physiological saline solution as an irrigant. Canal content samples were collected at four different times: immediately after instrumentation, seven days after instrumentation, after 14 days of intracanal medication, and seven days after removal of intracanal medication. A plating method was used to assess antimicrobial activity and the quantification of endotoxins was evaluated by the chromogenic Limulus lysate assay. Data were submitted to ANOVA and a Dunn test (a = 5%). Irrigation with castor oil extract decreased E. coli counts but had no effect on the level of endotoxins. Samples taken seven days after removal of medication revealed a significant reduction in endotoxin levels in Groups 3 and 4. Compared to the saline solution irrigation, castor oil extract decreased microorganism counts in root canals immediately after canal preparation. None of the medications used completely eliminated endotoxins in the root canal.

  18. Fabrication of modified hydrogenated castor oil/GPTMS-ZnO composites and effect on UV resistance of leather.

    Science.gov (United States)

    Ma, Jianzhong; Duan, Limin; Lu, Juan; Lyu, Bin; Gao, Dangge; Wu, Xionghu

    2017-06-16

    Leather products are made from the natural skin collagen fibers. It is vulnerable to the environmental factor such as solar ultraviolet irradiation in the using process. Therefore anti-UV performance is a very important quality, particularly for chrome-free leather. ZnO is a well-known UV absorber commonly used in the cosmetic industry. We have investigated its potential to increase the anti-UV performance of chrome-free leather. Modified hydrogenated castor oil/GPTMS-ZnO (MHCO/ GPTMS-ZnO) composites were prepared using spherical ZnO nanoparticles, hydrogenated castor oil, maleic anhydride and sodium bisulfite. MHCO/GPTMS-ZnO composites have better anti-UV ability and stability. MHCO/GPTMS-ZnO composites were applied to the leather processing. The treated samples were exposed to artificial sunlight. Anti-yellowing tests showed that MHCO/GPTMS-ZnO composites significantly improved anti-UV performance of leather.

  19. THE EFFECTS OF POSSIBLE CONTAMINATION ON THE RADIOCARBON DATING OF THE DEAD SEA SCROLLS II : EMPIRICAL METHODS TO REMOVE CASTOR OIL AND SUGGESTIONS FOR REDATING

    NARCIS (Netherlands)

    Rasmussen, Kaare Lund; van der Plicht, Johannes; Doudna, Gregory; Nielsen, Frederik; Hojrup, Peter; Stenby, Erling Halfdan; Pedersen, Carl Th; Højrup, Peter

    2009-01-01

    While kept at the Rockefeller Museum in East Jerusalem, many Dead Sea Scroll fragments were exposed to castor oil by the original team of editors in the course of cleaning the parchments. Castor oil must be regarded as a serious contaminant in relation to radiocarbon dating. If modern castor oil is

  20. Antibacterial effects of castor oil on foodborne pathogens: comparative evaluation of the components

    Directory of Open Access Journals (Sweden)

    samaneh hatami

    2016-01-01

    Full Text Available For centuries, antimicrobial compounds derived from plants, have been used for medicinal treatment. The aim of this study was to evaluate the antibacterial activity of castor seed oil extracted from Mashhad and Isfahan varieties on Staphylococcus aureus, Escherichia coli and Listeria inocula. The sensitivity of the indicator bacteria was evaluated using disc diffusion technique and minimum inhibitory concentration (MIC and minimum bactericidal concentration (MBC were tested by broth micro-dilution assays. Oil from castor seeds was extract by Soxhlet method and the extracted oils were analyzed by a gas chromatograph connected to a mass spectrometer (GC/MS. According to the results of various dilutions of the extracts, MIC for castor oils ranged 12.5-25%, except for the Isfahan variety that was estimated at 6.25-12.5% for E. coli. The two varieties of castor oils showed the MBC activity on the indicator organisms at the original (100% concentration. Based on GC/MS data, ricinoleic acid (1.307%, genetistic acid (0.597% and palmitic acid (1.947% were detected in oil extracted from Isfahan variety; meanwhile these compounds did not found in Mashhad variety. According to the results, the two castor varieties had antibacterial impact on E. coli. In addition, the overall antimicrobial activity of Isfahan variety was higher than Mashhad type. It seems that the presence of phenolic compounds as well as camphoric and unsaturated fatty acids is the major reason for the higher antibacterial effect of Isfahan variety on E. coli. Considering the inhibitory impact of castor oil, it can be used as a natural preservative in food industry.

  1. Thermoplastic Polyurethanes Stemming from Castor Oil: Green Synthesis and Their Application in Wood Bonding

    Directory of Open Access Journals (Sweden)

    Shaolong Li

    2017-09-01

    Full Text Available We report an efficient and green approach to synthesize a linear castor oil-based polyurethane (CPU without using any solvent or catalyst. Diol monomers were first synthesized by the aminolysis reaction between castor oil and diamines; this was accomplished within 6 h at 130 °C. Polymerization of the diols and isocyanate was further confirmed by Fourier transform infrared (FTIR, 1H-nuclear magnetic resonance (1H-NMR, and gel permeation chromatography analyses. The resultant CPUs showed a good thermal stability with an initial degradation temperature higher than 300 °C, and their mechanical and wood bonding property can be modulated by the structures of diamine. In addition, the CPUs possessed a satisfying water resistance property with the water absorption amount lower than 2%. The green conversion of castor oil to thermoplastic polyurethane affords new opportunities in bio-based industries.

  2. Fatty Acid Profile of Cheese from Dairy Goats Fed a Diet Enriched with Castor, Sesame and Faveleira Vegetable Oils

    Directory of Open Access Journals (Sweden)

    Ertha Medeiros

    2014-01-01

    Full Text Available The addition of vegetable oils to the diets of dairy goats is an alternative to supplemental feeding during the dry period and improves the lipid profile of milk and by-products. Cheeses were produced using milk from cross bred goats (Saanen × Alpina fed diets enriched with 4% vegetable oil (faveleira, sesame or castor, the fatty acid profile of cheeses was studied. Supplementation with vegetable oils did not increase the total fat percentage of the cheese (p ≥ 0.05 but did increase the percentage of CLA isomers, long-chain fatty acids (LCFA and polyunsaturated fatty acids (PUFA; in addition, the index of desirable fatty acids (DFA - expressed as the sum of unsaturated fatty acids plus stearic acid was increased for cheese made from milk from goats fed sesame or faveleira oil. Cheeses may have had increased percentages of cis-9,trans-11-CLA due to the supplementation of animal diets with vegetable oils rich in C18:2, such as faveleira and sesame oils. The fatty acid profile of goat cheese did not change significantly in response to the use of castor oil. Thus, the addition of sesame and faveleira oils to goat diets positively altered the fatty acid profile, which improved the nutritional characteristics of the fat present in goat cheese.

  3. Toxicity of water-soluble fractions of biodiesel fuels derived from castor oil, palm oil, and waste cooking oil.

    Science.gov (United States)

    Leite, Maria Bernadete Neiva Lemos; de Araújo, Milena Maria Sampaio; Nascimento, Iracema Andrade; da Cruz, Andrea Cristina Santos; Pereira, Solange Andrade; do Nascimento, Núbia Costa

    2011-04-01

    Concerns over the sustained availability of fossil fuels and their impact on global warming and pollution have led to the search for fuels from renewable sources to address worldwide rising energy demands. Biodiesel is emerging as one of the possible solutions for the transport sector. It shows comparable engine performance to that of conventional diesel fuel, while reducing greenhouse gas emissions. However, the toxicity of products and effluents from the biodiesel industry has not yet been sufficiently investigated. Brazil has a very high potential as a biodiesel producer, in view of its climatic conditions and vast areas for cropland, with consequent environmental risks because of possible accidental biodiesel spillages into water bodies and runoff to coastal areas. This research determined the toxicity to two marine organisms of the water-soluble fractions (WSF) of three different biodiesel fuels obtained by methanol transesterification of castor oil (CO), palm oil (PO), and waste cooking oil (WCO). Microalgae and sea urchins were used as the test organisms, respectively, for culture-growth-inhibition and early-life-stage-toxicity tests. The toxicity levels of the analyzed biodiesel WSF showed the highest toxicity for the CO, followed by WCO and the PO. Methanol was the most prominent contaminant; concentrations increased over time in WSF samples stored up to 120 d. Copyright © 2010 SETAC.

  4. Castor oil as a natural alternative to labor induction: A retrospective descriptive study.

    Science.gov (United States)

    DeMaria, Andrea L; Sundstrom, Beth; Moxley, Grace E; Banks, Kendall; Bishop, Ashlan; Rathbun, Lesley

    2017-08-21

    To describe birthing outcomes among women who consumed castor oil cocktail as part of a freestanding birth center labor induction protocol. De-identified data from birth logs and electronic medical records were entered into SPSS Statistics 22.0 for analysis for all women who received the castor oil cocktail (n=323) to induce labor between January 2008 and May 2015 at a birth center in the United States. Descriptive statistics were analyzed for trends in safety and birthing outcomes. Of the women who utilized the castor oil cocktail to stimulate labor, 293 (90.7%) birthed vaginally at the birth center or hospital. The incidence of maternal adverse effects (e.g., nausea, vomiting, extreme diarrhea) was less than 7%, and adverse effects of any kind were reported in less than 15% of births. An independent sample t-test revealed that parous women were more likely to birth vaginally at the birth center after using the castor oil cocktail than their nulliparous counterparts (p<.010), while gestational age (p=.26), woman's age (p=.23), and body mass index (p=.28) were not significantly associated. Nearly 91% of women in the study who consumed the castor oil cocktail to induce labor were able to give birth vaginally with little to no maternal or fetal complications. Findings indicate further research is needed to compare the safety and effectiveness of natural labor induction methodologies, including castor oil, to commonly used labor induction techniques in a prospective study or clinical trial. Copyright © 2017 Australian College of Midwives. Published by Elsevier Ltd. All rights reserved.

  5. Produção e composição química do leite de cabras mestiças Moxotó sob suplementação com óleo de licuri ou de mamona Production and chemical composition of the milk from crossbred Moxotó goats supplemented with licuri or castor oil

    Directory of Open Access Journals (Sweden)

    Rita de Cássia Ramos do Egypto Queiroga

    2010-01-01

    Full Text Available Avaliou-se o efeito da inclusão de óleos de licuri ou de mamona na dieta sobre a produção, a composição química do leite de cabras leiteiras e a viabilidade econômica dessas dietas. No delineamento experimental foram utilizadas cabras Mestiças Moxotó distribuídas em quadrado latino 5 × 5 com duas repetições, composto de cinco dietas: uma controle, sem lipídio suplementar, e as demais com 3% ou 5% de óleo de licuri ou de mamona. A suplementação com 5% de óleo de licuri reduziu a produção de leite, mas não influenciou a produção de leite corrigida para 4% de gordura. A adição de 3% de óleo de mamona reduziu o teor de gordura e de sólidos totais em comparação ao óleo de licuri, aumentando o teor de lactose. O teor de proteína do leite, no entanto, não foi alterado pela adição de óleo na dieta. Os indicadores econômicos apontaram a dieta controle como a mais rentável, no entanto, a suplementação com 3% de óleo de licuri, em comparação ao de mamona, pode ser interessante quando o leite se destina ao processamento, em virtude do maior teor de gordura.The effect was assessed of including licuri and castor oils in the diet on the production and chemical composition of milk from goats and the economic viability of the diets. Crossbred Moxotó goats in a 5 × 5 Latin square design were used with two replications consisting of five diets: a control treatment without supplementary oil (control, and the others with 3% or 5% licuri or castor oil. Milk production decreased with the inclusion of 5% licuri oil, but it did not influence the production of milk corrected to 4% fat. The addition of 3% castor oil reduced the fat content and total solids production compared to licuri oil, but it increased the lactose content. There was no significant difference in the protein content among treatments. The simple financial analyses showed that the control diet was more profitable, but supplementation with 3% licuri oil when

  6. Nanoparticle Structures with (Un-)Hydrogenated Castor Oil as Hydrophobic Paper Coating.

    Science.gov (United States)

    Samyn, Pieter; Vonck, Leo; Stanssens, Dirk; Abbeele, Henk Van den

    2018-05-01

    The encapsulation of vegetable oils within an aqueous dispersion of polymer nanoparticles provides an alternative route to create functional paper coatings from renewable resources, by combining the presentation of hydrophobic moieties together with variations in roughness at the paper surface. The effects of two selected vegetable oil types, i.e., castor oil and hydrogenated castor oil (wax), are compared in terms of nanoparticle synthesis, coating hydrophobicity and surface gloss. The nanoparticles were synthesized by adding 50 wt.-% oil during imidization of poly(styrene-co-maleic anhydride) with ammonium hydroxide. From evaluation of the thermal properties, the nanoparticles have a high glass transition temperature that is suppressed in presence of oil. The nanoparticles with hydrogenated castor oil have higher imide content and better thermal stability compared to castor oil, in parallel with lower chemical reactivity of the hydrogenated oil and less interference with the imidization reaction. After deposition as a coating on paper, the physical coating properties are discussed in parallel with the coating chemistry and morphology or roughness at different scale lengths. The nanoparticle coatings with hydrogenated oil provides a multi-scale roughness with an open, porous nanoparticles structures and presentation of some amount free oil augmenting hydrophobicity towards a water contact angle of 128° (static contact angle) or 138° (advancing contact angle). The differences in surface coverage of coated papers in terms of imide and oil contents are confirmed by chemical Raman mapping. The differences in surface roughness are confirmed by non-contact profilometry, laser interferometry and atomic force microscopy.

  7. Sustainable and economic feasibility of castor bean oil production: a methodology to support investments decision taking; Viabilidade economica e sustentabilidade da producao de oleo de mamona: uma metodologia de suporte a decisao de investimentos

    Energy Technology Data Exchange (ETDEWEB)

    Maia, Glawther Lima [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Mestrado em Logistica e Pesquisa Operacional; Arruda, Joao Bosco Furtado [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil)

    2008-07-01

    The castor bean agribusiness is supported by a complex supply chain that involves several inputs, main products and other derived products. So, the control of production costs is a basic and extremely important activity for the optimization of management processes. Using literature research, case study and assessment of scenarios, the present work was developed with the objective of conceiving a methodology, based on theoretical and economical aspects, the formation of costs and the revenue forecasting, which is applied with the aid of a computational program for supporting decision taking in the castor bean small producers agribusiness. The results obtained in the case study show, for example, that about 40% of the projects are considered accepted under the criterion of recovering the invested capital in less than 2 years. Also, it reveals that 75% of the projects contribute for the increase of the producer income and about 63% of the projects provide enough profit to add value to the producer's properties. Finally, it is clear that the proposed methodology makes easier a better agricultural planning, allowing a better utilization of the raw material and it facilitates the analysis of diversifying other derived products and revenue sources in the castor bean chain. (author)

  8. Effect of fermentation period on the organic acid and amino acid contents of Ogiri from castor oil bean seeds

    Directory of Open Access Journals (Sweden)

    Ojinnaka, M-T. C.

    2013-01-01

    Full Text Available Aims: To monitor the changes in the concentration of organic acid and amino acid contents during the fermentation of castor oil bean seed into ogiri.Methodology and results: In this study, ogiri, a Nigerian fermented food condiment was prepared from castor oil bean using Bacillus subtilis as a monoculture starter for the production of three different fermented castor oil bean condiment samples: B1 (0% NaCl/lime, B2 (2% NaCl, B3 (3% lime. Variations in the composition of the castor oil bean with fermentation over 96 h periods were evaluated for organic acid and amino acid contents using High Performance Liquid Chromatography. Organic acids were detected in the fermented castor oil bean samples as fermentation period increased to 96 h. Organic acids identified were oxalic, citric, tartaric, malic, succinic, lactic, formic, acetic, propionic and butyric acids. The lactic acid contents in sample B1 (0% NaCl/lime decreased initially and then increased as the fermentation period progressed. The value at 96 h fermentation was 1.336 µg/mL as against 0.775 µg/mL at 0 h fermentation. Sample B3 (3% lime had lactic acid content that increased as fermentation period increased with lactic acid content of 1.298 µg/mL at 96 h fermentation. The acetic acid content of sample B1 increased as fermentation progressed and at 96 h fermentation, its value was 1.204 µg/mL while those of B2 and B3 were 0.677 µg/mL and 1.401 µg/mL respectively. The three fermented castor oil bean samples also contained sufficient amount of amino acids. Sample B1 had the highest values in isoleucine glycine and histidine with values 1.382 µg/mL, 0.814 µg/mL and 1.022 µg/mL respectively while sample B2 had the highest value in leucine content with 0.915 µg/mL at 96 h fermentation, closely followed by sample B3 and B1 with 0.798 µg/mL and 0.205 µg/mL respectively. The results of amino acid analysis indicated a high concentration of all amino acids at 96 h of fermentation

  9. Fractional characterisation of jatropha, neem, moringa, trisperma, castor and candlenut seeds as potential feedstocks for biodiesel production in Cuba

    Energy Technology Data Exchange (ETDEWEB)

    Martin, Carlos [Bioresource Technology group, Department of Chemistry and Chemical Engineering, University of Matanzas, Autopista a Varadero, km 3, Matanzas 44740 (Cuba); Department of Chemical Engineering, University of Vigo (Campus Ourense), Polytechnical Building, As Lagoas, 32004 Ourense (Spain); Moure, Andres; Dominguez, Herminia; Parajo, Juan C. [Department of Chemical Engineering, University of Vigo (Campus Ourense), Polytechnical Building, As Lagoas, 32004 Ourense (Spain); Martin, Giraldo [Experimental Station of Pastures and Forages ' ' Indio Hatuey' ' , Central Espana Republicana, CP 44280, Matanzas (Cuba); Carrillo, Eugenio [Biomass Energy Department, National Renewable Energy Centre (CENER), Ciudad de la Innovacion 4, Sarriguren, 31621 Pamplona (Spain)

    2010-04-15

    A preliminary investigation on the suitability of various non-edible oil seeds for the integral utilisation of their fractions for production of biodiesel and other products was carried out. The oil seeds considered were jatropha (Jatropha curcas), neem (Azadirachta indica), moringa (Moringa oleifera), trisperma (Aleurites trisperma), castor beans (Ricinus communis) and candlenut (Aleurites moluccana). The highest oil content (62.0% (w/w)) was found in trisperma seeds, but the use of that oil for biodiesel production is restricted by its high content of polyunsaturated fatty acids. The oils of castor beans and moringa contained 86.0% of ricinoleic acid and 70.6% of oleic acid, respectively, while in the oils from the other seeds no predominance of any acid was observed. According to the oil yield and to the fatty acid composition of the oil, jatropha was identified as the most promising oil seed for biodiesel production in Cuba. All the press cakes were rich in protein, the highest content (68.6%) being detected in moringa cake. The investigation revealed that the husks of neem and moringa can be considered potential substrates for ethanol production due to their high cellulose content (approximately 30%). A high concentration (4.3%) of acetyl groups was found in neem husks, what is favourable for the hydrolytic conversion of polysaccharides to simple sugars. A high protein content (15.2%) was detected in moringa husks, which is a positive feature for lowering the cost of nutrient supplementation in ethanolic fermentation. (author)

  10. A Comparative Experimental Analysis of Tribological Properties Between Commercial Mineral Oil and Neat Castor Oil using Taguchi Method in Boundary Lubrication Regime

    Directory of Open Access Journals (Sweden)

    S. Bhaumik

    2016-03-01

    Full Text Available The present work aims to carry out a comparative experimental analysis of tribological properties of 372cSt mineral oil and 229cSt castor oil. The antiwear and extreme pressure properties of both the oils have been analysed according to ASTM G 99 and ASTM D-2783 standards. The surfaces of the balls and pins after tribo tests have been analysed using Scanning Electron Microscope (SEM images. The present test results predict that the antiwear and extreme pressure properties in case of the selected commercially available mineral oil are better than neat castor oil. Both coefficient of friction and frictional force increased by 16-42 % and 16-35 % respectively in case of neat castor oil as compared with that of the mineral oil. The load carrying capacity in case of mineral oil has been found to be 250 kg while in case of castor oil it has been found to be 126 kg. SEM images show a higher plastic deformation in case of castor oil as compared to the mineral oil. Both mineral oil and castor oil showed surface deteriorations and increase in roughness after 40 hrs of intermittent running during scuffing test. Thus, the present investigation indicates that the tribological properties of neat castor are inferior to that of mineral oil although close observation of the results shows that both AW and EP properties of neat castor oil are much closer to that of commercial mineral oil. Thus, the present work would help in formulating castor oil based new bio lubricants with better anti wear and extreme pressure properties

  11. Lipase catalyzed transesterification of castor oil by straight chain higher alcohols.

    Science.gov (United States)

    Malhotra, Deepika; Mukherjee, Joyeeta; Gupta, Munishwar N

    2015-03-01

    Biolubricants from Castor oil were produced enzymatically by transesterification with higher alcohols using a lipase mixture of immobilized Mucor miehei (RMIM) and immobilized Candida antarctica lipase B (Novozym 435) under low water conditions. The conversions were in the range of 80-95% under the optimized conditions. Copyright © 2014 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

  12. Optimum Operating Conditions for Epoxidation Reaction of Jojoba and Castor Oils

    National Research Council Canada - National Science Library

    El-Adly R. A; Shoaib A. M

    2014-01-01

    ...%, and 40oC-80oC respectively. Six models have been introduced to indicate the effect of these three variables on conversion for both jojoba and castor oil, and the prediction abilities of the resultant models were tested...

  13. Recycling of waste poly(ethylene terephthalate) with castor oil using microwave heating

    Czech Academy of Sciences Publication Activity Database

    Beneš, Hynek; Slabá, J.; Walterová, Zuzana; Rais, David

    2013-01-01

    Roč. 98, č. 11 (2013), s. 2232-2243 ISSN 0141-3910 R&D Projects: GA MPO 2A-2TP1/135 Institutional support: RVO:61389013 Keywords : poly(ethylene terephthalate) * castor oil * chemical recycling Subject RIV: CD - Macromolecular Chemistry Impact factor: 2.633, year: 2013

  14. Amelioration of Anti-Nutritive Effects of Castor Oil Seed ( Ricinus ...

    African Journals Online (AJOL)

    Amelioration of Anti-Nutritive Effects of Castor Oil Seed ( Ricinus communis ) Meal in Broilers' Ration Using Natural Fermentation and Dl-Methionine ... Growth performance, coefficient of total tract apparent digestibility, serum metabolites, dressing percentage, and retail cuts were determined at the end of the study, which ...

  15. Evaluation of the performance of a castor-oil based formulation in limiting pesticide residues in strawberry crops

    Directory of Open Access Journals (Sweden)

    Mário Sérgio Galhiane

    2012-01-01

    Full Text Available A study was made to evaluate the effect of a castor oil-based detergent on strawberry crops treated with different classes of pesticides, namely deltamethrin, folpet, tebuconazole, abamectin and mancozeb, in a controlled environment. Experimental crops of greenhouse strawberries were cultivated in five different ways with control groups using pesticides and castor oil-based detergent. The results showed that the group 2, which was treated with castor oil-based detergent, presented the lowest amount of pesticide residues and the highest quality of fruit produced.

  16. Synthesis and characterization of castor oil-based polyurethane for ...

    Indian Academy of Sciences (India)

    Administrator

    as soybean oil, canola oil, palm oil, sunflower oil, corn oil, linseed oil and nahar seed oil7–9 have been exten- sively studied as bases for various polyols used for the manufacture of PUs for different applications. The preparation of polymers from vegetable oils is currently receiving increasing attention because of the.

  17. Isotope labeling-based quantitative proteomics of developing seeds of castor oil seed (Ricinus communis L.)

    DEFF Research Database (Denmark)

    Nogueira, Fábio C S; Palmisano, Giuseppe; Schwämmle, Veit

    2013-01-01

    could be mapped to extant castor gene models, considerably expanding the number of proteins so far identified from developing castor seeds. Cluster validation and statistical analysis resulted in 975 protein trend patterns and the relative abundance of 618 proteins. The results presented in this work......In this study, we used a mass spectrometry-based quantification approach employing isotopic (ICPL) and isobaric (iTRAQ) labeling to investigate the pattern of protein deposition during castor oil seed (Ricinus communis L.) development, including that of proteins involved in fatty acid metabolism......, seed-storage proteins (SSPs), toxins, and allergens. Additionally, we have used off-line hydrophilic interaction chromatography (HILIC) as a step of peptide fractionation preceding the reverse-phase nanoLC coupled to a LTQ Orbitrap. We were able to identify a total of 1875 proteins, and from these 1748...

  18. Experimental investigation on performance and exhaust emissions of castor oil biodiesel from a diesel engine.

    Science.gov (United States)

    Shojaeefard, M H; Etgahni, M M; Meisami, F; Barari, A

    2013-01-01

    Biodiesel, produced from plant and animal oils, is an important alternative to fossil fuels because, apart from dwindling supply, the latter are a major source of air pollution. In this investigation, effects of castor oil biodiesel blends have been examined on diesel engine performance and emissions. After producing castor methyl ester by the transesterification method and measuring its characteristics, the experiments were performed on a four cylinder, turbocharged, direct injection, diesel engine. Engine performance (power, torque, brake specific fuel consumption and thermal efficiency) and exhaust emissions were analysed at various engine speeds. All the tests were done under 75% full load. Furthermore, the volumetric blending ratios of biodiesel with conventional diesel fuel were set at 5, 10, 15, 20 and 30%. The results indicate that lower blends of biodiesel provide acceptable engine performance and even improve it. Meanwhile, exhaust emissions are much decreased. Finally, a 15% blend of castor oil-biodiesel was picked as the optimized blend of biodiesel-diesel. It was found that lower blends of castor biodiesel are an acceptable fuel alternative for the engine.

  19. Transesterification of triacetin and castor oil with methanol catalyzed by supported polyaniline-sulfate. A role of polymer morphology

    Czech Academy of Sciences Publication Activity Database

    Drelinkiewicz, A.; Kalemba-Jaje, Z.; Lalik, E.; Zieba, A.; Mucha, D.; Konyushenko, Elena; Stejskal, Jaroslav

    2013-01-01

    Roč. 455, 30 March (2013), s. 92-106 ISSN 0926-860X Institutional support: RVO:61389013 Keywords : transesterification * triacetin * castor oil Subject RIV: CD - Macromolecular Chemistry Impact factor: 3.674, year: 2013

  20. Propolis or cashew and castor oils effects on composition of Longissimus muscle of crossbred bulls finished in feedlot

    Directory of Open Access Journals (Sweden)

    Maribel Velandia Valero

    2014-12-01

    Full Text Available The natural additive products (propolis or essential oils, in replacing antibiotics, could be used as an alternative for feed strategies to improve animal production. This work was performed to evaluate the effect of natural additives as propolis or essential oils on meat quality of crossbred (Aberdeen Angus vs. Nellore bulls. Thirty bulls were kept in feedlot (individual pen for 55 d and randomly assigned to one of three diets (n = 10: control (CON, propolis (PRO, or essential oils (OIL. CON diet consists of corn silage (45% DM and concentrate (cracked corn, soybean meal, glycerin, limestone, and mineral salt, 55% DM. The PRO group received same CON diet plus 3 g animal-1 d-1 of propolis premix added to the concentrate. The OIL group received same CON diet and 3 g animal-1 d-1 of a premix (cashew Anacardium occidentale L. and castor Ricinus communis L. oils added to the concentrate. Fat thickness (5.0 mm, pH (5.9, Longissimus muscle area 58.0 cm², marbling, texture, color (L* = 36.6, a* = 17.3, and b* = 5.9, lipid oxidation (0.08 malonaldehyde kg-1 meat, and Warner-Bratzler shear force (3.3 kg were unaffected by the diet. PRO and OIL diets had no effect neither on moisture (73.7%, ashes (1.1%, protein (23.8%, and lipids (1.7%, fatty acid composition or polyunsaturated/saturated fatty acid (PUFA/ SFA, 0.13, and n-6/n-3 ratio (6.9 on Longissimus muscle. Addition of natural additives as propolis extract or cashew and castor oils in the diet of bulls when they are finished in a feedlot did not change meat qualities.

  1. Influence of the reaction conditions on the enzyme catalyzed transesterification of castor oil

    DEFF Research Database (Denmark)

    Andrade, Thalles Allan; Errico, Massimiliano; Christensen, Knud Villy

    2017-01-01

    The identification of the influence of the reaction parameters is of paramount importance when defining a process design. In this work, non-edible castor oil was reacted with methanol to produce a possible component for biodiesel blends, using liquid enzymes as the catalyst. Temperature, alcohol......-to-oil molar ratio, enzyme and added water contents were the reaction parameters evaluated in the transesterification reactions. The optimal conditions, giving the optimal final FAME yield and FFA content in the methyl ester-phase was identified. At 35 °C, 6.0 methanol-to-oil molar ratio, 5 wt% of enzyme and 5...

  2. Glutathione Preservation during Storage of Rat Lenses in Optisol-GS and Castor Oil

    DEFF Research Database (Denmark)

    Holm, Thomas; Brøgger-Jensen, Martin Rocho; Johnson, Leif

    2013-01-01

    Glutathione concentration in the lens decreases in aging and cataractous lenses, providing a marker for tissue condition. Experimental procedures requiring unfrozen lenses from donor banks rely on transportation in storage medium, affecting lens homeostasis and alterations in glutathione levels....... The aim of the study was to examine the effects of Optisol-GS and castor oil on lens condition, determined from their ability to maintain glutathione concentrations....

  3. Antimicrobial action of sodium hypochlorite and castor oil solutions for denture cleaning – in vitro evaluation

    Directory of Open Access Journals (Sweden)

    Marcela Moreira SALLES

    2015-01-01

    Full Text Available The objective of this in vitro study was to evaluate the antimicrobial action of sodium hypochlorite (0.25% and 0.50% and 10% castor oil solutions against specific microorganisms, by counting Colony Forming Units (CFU of clinically important bacteria and Candida species. Acrylic resin specimens (n = 320; Lucitone 550 were obtained from square metal matrices (10 x 10 x 2 mm, sterilized by microwave (650W, for 6 minutes and contaminated by Staphylococcus aureus, Pseudomonas aeruginosa, Candida albicans, Bacillus subtilis, Escherichia coli, Streptococcus mutans, Enterococcus faecalisand Candida glabrata. The specimens were immersed for 20 minutes in one of the following hygiene solutions (n = 10/each: A – 0.25% Sodium hypochlorite; B – 0.5% Sodium hypochlorite; C – 10% Castor oil solution; and D (Control – saline. Adhered cells were suspended and inoculated into a selective solid medium (37ºC for 24 h. The Student’s t-test (α = 0.05 was performed to compare log10(CFU+1/mL between Groups C and D. The results showed that sodium hypochlorite (0.25% and 0.5% completely eliminated all detectable microorganisms. The castor oil solution eliminatedB. subtilisand reduced counts for other strains. Differences between C and D were significant (p E. faecalis. Both sodium hypochlorite solutions (0.25% and 0.5% were effective in eliminating all microorganisms evaluated, and may be useful as cleaning solutions for complete dentures. The castor oil solution provided moderate efficacy and performed differently on the tested species, with the strongest effect on B. subtilis and with non-significant action on E. faecalis.

  4. Síntesis de espumas rígidas de poliuretano obtenidas a partir de aceite de castor y poliglicerol empleando calentamiento por microondas Synthesis of rigid polyurethane foams obtained from castor oil and polyglycerol using microwave heating

    Directory of Open Access Journals (Sweden)

    Paula Mazo

    2011-01-01

    Full Text Available En este trabajo se realizó la síntesis de espumas rígidas de poliuretano utilizando un macropoliol sintetizado a partir de aceite de castor y poliglicerol, se optimizó mediante un análisis de superficie de respuesta, empleando un diseño factorial 32, los factores evaluados fueron: cantidad de agua y de ácido tartárico, el cual actúa como agente entrecruzante y catalizador; se evalúaron las propiedades mecánicas de las espumas como: densidad aparente (ASTM D1622-08, resistencia a la compresión (ASTM D1621, conductividad térmica (ASTM C177-04 y friabilidad (ASTM C421-8; se realizó Microscopia Electrónica de Barrido (SEM y Análisis de Calorimetría Diferencial de Barrido (DSC. El macropoliol fue obtenido desde fuentes renovables, mediante la transesterificación de Aceite de Castor (CO ó Aceite de Castor Maleinizado (MACO con Poliglicerol (PG. Se evalúo el efecto de las microondas en las reacciones, donde se encuentra una disminución del tiempo; el seguimiento y la caracterización de los productos intermedios se realiza mediante la cuantificación de valor ácido por titulación (ASTM D4662-03 y número de hidroxilos (ASTM D4274-05.In this work we showed the polyurethane rigid foams synthesis using a macropolyol synthesized from castor oil and polyglycerol. This process is optimized employing a response surface analysis and using a 3² factorial design. The factors evaluated were: amount of water and tartaric acid, where tartaric acid acts as crosslinking agent and catalyst; mechanical properties of foams were evaluated as bulk density (ASTM D1622-08, compressive strength (ASTM D1621, thermal conductivity (ASTM C177-04, and friability (ASTM C421-8; scanning electronic microscopic (SEM and differential scanning calorimetry (DSC. The macropolyol was obtained from renewable sources by the transesterification of castor oil (CO or maleinized castor oil (MACO and polyglycerol (PG. The effect of microwaves on the reactions was

  5. UV and gamma irradiation effects on surface properties of polyurethane derivative from castor oil

    Energy Technology Data Exchange (ETDEWEB)

    Azevedo, Elaine C.; Nascimento, Eduardo M., E-mail: helunica@yahoo.com.br [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil); Chierice, Gilberto O.; Claro Neto, Salvador [Universidade de Sao Paulo (IQSC/USP), Sao Carlos, SP (Brazil). Instituto de Quimica; Lepienski, Carlos M. [Universidade Federal do Parana (UFPR), Curitiba (Brazil)

    2013-07-01

    Gamma and ultraviolet radiation effects on hardness, elastic modulus and viscoelastic properties of polyurethane derived from castor oil (PU) were investigated by nanoindentation tests. Modifications on surface morphology, induce by radiation, were observed by atomic force microscopy. The polyurethane derivative from castor oil shows good resistance to gamma radiation, with only small changes in hardness, elastic modulus, viscoelastic properties and contact angle. The hardness of PY increases at the near surface region due to UVA radiation and decreases after UVC radiation. The contact angle for water drop decreases after UVC radiation, by not after gamma radiation, despite a significant increase in roughness. Such results are attributed to different responses from polyurethane to radiation energy. Increase in hardness due to UVA is attributed to a higher crosslinking at shallow depths, while a decrease in mechanical properties may be attributed to chain scission. These results are consistent with the modifications on viscoelastic properties. Shore D hardness did not show the same trend as observed by nanoindentation results. Hardness, viscoelastic properties and contact angle of castor oil polyurethane are more severely influenced by UVC radiation, while gamma radiation does not have a significant effect. (author)

  6. Apis mellifera pollination improves agronomic productivity of anemophilous castor bean (Ricinus communis

    Directory of Open Access Journals (Sweden)

    Rômulo A.G. Rizzardo

    2012-12-01

    Full Text Available Castor bean (Ricinus communis L. is cultivated mainly for biodiesel production because of its oil-rich seeds; it is assumed to be an anemophylous species. But pollination deficit can lead to low productivity often attributed to other reasons. In this paper, we investigated pollination requirements, pollination mechanism, occurrence of pollination deficit, and the role of biotic pollinators in a large commercial plantation of castor bean. Our results show that R. communis bears a mixed breeding system favoring selfing by geitonogamy, although the wind promotes mostly outcrossing. We also found that the honey bee (Apis mellifera L. foraging on castor bean can both transfer pollen from male to female flowers within the same raceme and boost the release of airborne pollen by male flowers. Both situations increase geitonogamy rates, raising significantly fruit set and seed yield. This is the first report of an animal foraging activity increasing seed yield in an anemophilous and geitonogamous crop and elucidates the role of biotic pollinators in castor bean reproduction.A mamoneira (Ricinus communis L. é cultivada principalmente para produção de biodiesel devido ao alto teor de óleo de suas sementes e considerada como sendo de polinização anemófila. Mas déficits de polinização podem levar a baixos índices de produtividade geralmente atribuídos a outros fatores. Neste trabalho foram investigados os requerimentos, mecanismos e déficit de polinização e o papel dos polinizadores bióticos em um monocultivo comercial de mamona. Os resultados mostram que R. communis possui um sistema de polinização misto, favorecendo a autopolinização por geitonogamia, embora o vento normalmente promova polinização cruzada. Observou-se também que a abelha melífera (Apis mellifera L. forrageando na mamoneira pode tanto transferir pólen das flores estaminadas para as pistiladas do mesmo racemo, quanto aumentar consideravelmente a liberação de p

  7. Mechanical evaluation of bone gap filled with rigid formulations castor oil polyurethane and chitosan in horses

    Directory of Open Access Journals (Sweden)

    Rodrigo Crispim Moreira

    Full Text Available ABSTRACT: Often fractures of long bones in horses are comminuted and form bone gaps, which represent a major challenge for the fixation of these fractures by loss of contact between the fragments. Bone grafts help in treating this kind of fracture and synthetic materials have been gaining ground because of the limitations of autologous and heterologous grafts. In this study were performed compressive non destructive test in 10 bones with complete cross-bone gap in mid-diaphyseal of the third metacarpal bone of horses. Using a mechanism of "crossing" the 10 bones were used in the three groups (control, castor oil poliuretane and chitosan according to the filling material. After the test with maximum load of 1000N bone had a gap filled by another material and the test was repeated. Deformations caused on the whole bone, plate and bone tissue near and distant of gap were evaluated, using strain gauges adhered to the surface at these locations. There was a reduction in bone deformation from 14% (control to 3,5% and 4,8% by filling the gap with Chitosan and castor oil respectively, and a reduction of strain on the plate of 96% and 85% by filling gap with chitosan and castor respectively. An increase in intensity and direction of deformations occurred in bone near to gap after its filling; however, there was no difference in bone deformations occurring far the gap.

  8. Preparation and characterization of activated carbon from castor de-oiled cake

    Directory of Open Access Journals (Sweden)

    Viviana M. Ospina-Guarín

    2014-01-01

    Full Text Available Biomass residues have been used to produce activated carbons. On this process, the activation method and the raw composition determine the properties as porosity and surface area of the charcoal. After the extraction of castor oil, there is a solid byproduct (cake of low added value, which was used in the production of activated carbon to add value to this waste. For this purpose two traditional methods were used, first, physical activation using as activating agents steam, CO2 and mixture of both, and additionally chemical activation using K2CO3 as the activating agent. Some activated carbons were characterized using N2 adsorption isotherms, BET surface areas varied between 255.98 (m2/g and 1218.43 (m2/g. By SEM and EDS analysis was possible to observe that materials obtained by the two types of activation are principally amorphous and morphological characteristics of the carbon obtained by physical activation are very different from those obtained by chemical activation. Finally, through impregnation of inorganic phases of Ni and Mo was revealed that the high dispersion characteristics, these carbonaceous materials will have potential to be used as catalyst support.

  9. Polyurethane Foams for Thermal Insulation Uses Produced from Castor Oil and Crude Glycerol Biopolyols.

    Science.gov (United States)

    Carriço, Camila S; Fraga, Thaís; Carvalho, Vagner E; Pasa, Vânya M D

    2017-07-02

    Rigid polyurethane foams were synthesized using a renewable polyol from the simple physical mixture of castor oil and crude glycerol. The effect of the catalyst (DBTDL) content and blowing agents in the foams' properties were evaluated. The use of physical blowing agents (cyclopentane and n-pentane) allowed foams with smaller cells to be obtained in comparison with the foams produced with a chemical blowing agent (water). The increase of the water content caused a decrease in density, thermal conductivity, compressive strength, and Young's modulus, which indicates that the increment of CO₂ production contributes to the formation of larger cells. Higher amounts of catalyst in the foam formulations caused a slight density decrease and a small increase of thermal conductivity, compressive strength, and Young's modulus values. These green foams presented properties that indicate a great potential to be used as thermal insulation: density (23-41 kg·m-3), thermal conductivity (0.0128-0.0207 W·m-1·K-1), compressive strength (45-188 kPa), and Young's modulus (3-28 kPa). These biofoams are also environmentally friendly polymers and can aggregate revenue to the biodiesel industry, contributing to a reduction in fuel prices.

  10. Polyurethane Foams for Thermal Insulation Uses Produced from Castor Oil and Crude Glycerol Biopolyols

    Directory of Open Access Journals (Sweden)

    Camila S. Carriço

    2017-07-01

    Full Text Available Rigid polyurethane foams were synthesized using a renewable polyol from the simple physical mixture of castor oil and crude glycerol. The effect of the catalyst (DBTDL content and blowing agents in the foams’ properties were evaluated. The use of physical blowing agents (cyclopentane and n-pentane allowed foams with smaller cells to be obtained in comparison with the foams produced with a chemical blowing agent (water. The increase of the water content caused a decrease in density, thermal conductivity, compressive strength, and Young’s modulus, which indicates that the increment of CO2 production contributes to the formation of larger cells. Higher amounts of catalyst in the foam formulations caused a slight density decrease and a small increase of thermal conductivity, compressive strength, and Young’s modulus values. These green foams presented properties that indicate a great potential to be used as thermal insulation: density (23–41 kg·m−3, thermal conductivity (0.0128–0.0207 W·m−1·K−1, compressive strength (45–188 kPa, and Young’s modulus (3–28 kPa. These biofoams are also environmentally friendly polymers and can aggregate revenue to the biodiesel industry, contributing to a reduction in fuel prices.

  11. Preparation, Characterization and Mechanical Properties of Bio-Based Polyurethane Adhesives from Isocyanate-Functionalized Cellulose Acetate and Castor Oil for Bonding Wood

    Directory of Open Access Journals (Sweden)

    Adrián Tenorio-Alfonso

    2017-04-01

    Full Text Available Nowadays, different types of natural carbohydrates such as sugars, starch, cellulose and their derivatives are widely used as renewable raw materials. Vegetable oils are also considered as promising raw materials to be used in the synthesis of high quality products in different applications, including in the adhesive field. According to this, several bio-based formulations with adhesion properties were synthesized first by inducing the functionalization of cellulose acetate with 1,6-hexamethylene diisocyanate and then mixing the resulting biopolymer with a variable amount of castor oil, from 20% to 70% (wt. These bio-based adhesives were mechanically characterized by means of small-amplitude oscillatory torsion measurements, at different temperatures, and standardized tests to evaluate tension loading (ASTM-D906 and peel strength (ASTM-D903. In addition, thermal properties and stability of the synthesized bio-polyurethane formulations were also analyzed through differential scanning calorimetry and thermal gravimetric analysis. As a result, the performance of these bio-polyurethane products as wood adhesives were compared and analyzed. Bio-polyurethane formulations exhibited a simple thermo-rheological behavior below a critical temperature of around 80–100 °C depending on the castor oil/cellulose acetate weight ratio. Formulation with medium castor oil/biopolymer weight ratio (50:50 % wt showed the most suitable mechanical properties and adhesion performance for bonding wood.

  12. Allelopathic effect of aqueous extract of fresh leaf castor beans ...

    African Journals Online (AJOL)

    Allelopathy defines the production of specific biomolecules (allelochemical) by a plant that can induce positive or negative impacts on another culture. The crop of castor beans (Ricinus communis L.) is being economically valued and receiving attention, mainly by the biodiesel production, castor oil and animal feeding.

  13. Weed management strategies for castor bean crops

    Directory of Open Access Journals (Sweden)

    Augusto Guerreiro Fontoura Costa

    2014-04-01

    Full Text Available Castor bean crops are agriculturally relevant due to the quality and versatility of their oil, both for the chemical industry and for biodiesel production. Proper weed management is important for both the cultivation and the yield of castor bean crops; therefore, the intention of the present work is to review pertinent information regarding weed management, including the studies regarding weed interference periods, chemical controls for use in different crop production systems and herbicide selectivity, for castor bean crops. Weed science research for castor bean crops is scarce. One of the main weed management challenges for castor bean crops is the absence of herbicides registered with the Ministry of Agriculture, Livestock and Food Supply (MALFS. Research for viable herbicides for weed control in castor bean crops should be directed by research and/or rural extension institutions, associations and farmers cooperatives, as well as by manufactures, for the registration of these selective herbicides, which would be primarily used to control eudicotyledons in castor bean crops. New studies involving the integration of weed control methods in castor bean also may increase the efficiency of weed management, for both small farmers using traditional crop methods in the Brazilian Northeast region, as well as for areas with the potential for large scale production, using conservation tillage systems, such as the no-tillage crop production system.

  14. Glutathione Preservation during Storage of Rat Lenses in Optisol-GS and Castor Oil

    Science.gov (United States)

    Holm, Thomas; Brøgger-Jensen, Martin Rocho; Johnson, Leif; Kessel, Line

    2013-01-01

    Background Glutathione concentration in the lens decreases in aging and cataractous lenses, providing a marker for tissue condition. Experimental procedures requiring unfrozen lenses from donor banks rely on transportation in storage medium, affecting lens homeostasis and alterations in glutathione levels. The aim of the study was to examine the effects of Optisol-GS and castor oil on lens condition, determined from their ability to maintain glutathione concentrations. Methodology/Principal Findings Rat lenses were stored in the two types of storage media at varying time intervals up to 3 days. Glutathione concentration was afterwards determined in an enzymatic detection assay, specific for both reduced and oxidized forms. Lenses removed immediately after death exhibited a glutathione concentration of 4.70±0.29 mM. In vitro stored lenses in Optisol-GS lost glutathione quickly, ending with a concentration of 0.60±0.34 mM after 3 days while castor oil stored lenses exhibited a slower decline and ended at 3 times the concentration. A group of lenses were additionally stored under post mortem conditions within the host for 6 hours before its removal. Total glutathione after 6 hours was similar to that of lenses removed immediately after death, but with altered GSH and GSSG concentrations. Subsequent storage of these lenses in media showed changes similar to those in the first series of experiments, albeit to a lesser degree. Conclusions/Significance It was determined that storage in Optisol-GS resulted in a higher loss of glutathione than lenses stored in castor oil. Storage for more than 12 hours reduced glutathione to half its original concentration, and was considered unusable after 24 hours. PMID:24260265

  15. Meat quality assessment from young goats fed for long periods with castor de-oiled cake.

    Science.gov (United States)

    Oliveira, C H A; Silva, A M; Silva, L M; van Tilburg, M F; Fernandes, C C L; Moura, A A; Moreno, F B M B; Monteiro-Moreira, A C O; Moreira, R A; Bezerra, F J; Rondina, D

    2015-08-01

    Diet can influence both the qualitative and quantitative traits of ruminant meat. This study evaluated the effects of castor de-oiled cake on the meat of mixed-breed male goat kids. After 165days of diet treatment, no alterations (p>0.05) were observed in the in vivo performance, anatomic components, dissection and proximate composition of the Longissimus dorsi muscle, as well as in the color and pH of the carcasses. However, diet had an effect (pled to alterations in meat quality, without compromising its consumption qualities. Copyright © 2015 Elsevier Ltd. All rights reserved.

  16. Kinetic and Thermodynamics studies for Castor Oil Extraction Using Subcritical Water Technology.

    Science.gov (United States)

    Abdelmoez, Wael; Ashour, Eman; Naguib, Shahenaz M; Hilal, Amr; Al Mahdy, Dalia A; Mahrous, Engy A; Abdel-Sattar, Essam

    2016-06-01

    In this work both kinetic and thermodynamics of castor oil extraction from its seeds using subcritical water technique were studied. It was found that the extraction process followed two consecutive steps. In these steps, the oil was firstly extracted from inside the powder by diffusion mechanism. Then the extracted oil, due to extending the extraction time under high temperature and pressure, was subjected to a decomposition reaction following first order mechanism. The experimental data correlated well with the irreversible consecutive unimolecular-type first order mechanism. The values of both oil extraction rate constants and decomposition rate constants were calculated through non-linear fitting using DataFit software. The extraction rate constants were found to be 0.0019, 0.024, 0.098, 0.1 and 0.117 min(-1), while the decomposition rate constants were 0.057, 0.059, 0.014, 0.019 and 0.17 min(-1) at extraction temperatures of 240, 250, 260, 270 and 280°C, respectively. The thermodynamic properties of the oil extraction process were investigated using Arrhenius equation. The values of the activation energy, Ea, and the frequency factor, A, were 73 kJ mol(-1) and 946, 002 min(-1), respectively. The physicochemical properties of the extracted castor oil including the specific gravity, viscosity, acid value, pH value and calorific value were found to be 0.947, 7.487, 1.094 mg KOH/g, 6.1, and 41.5 MJ/Kg, respectively. Gas chromatography analysis showed that ricinoleic acid (83.6%) appears as the predominant fatty acid in the extracted oil followed by oleic acid (5.5%) and linoleic acid (2.3%).

  17. Green superlubricity of Nitinol 60 alloy against steel in presence of castor oil

    Science.gov (United States)

    Zeng, Qunfeng; Dong, Guangneng; Martin, Jean Michel

    2016-07-01

    In the present work, first, we show that sliding Nitinol 60 alloy against steel under castor oil lubrication exhibits a new case of superlubricity (coefficient of friction CoF ≪ 0.01). So far, CoF below 0.01 have never been achieved under boundary lubrication at high contact pressure and in presence of vegetable oil as a green lubricant. Next, it is demonstrated that superlubricity is controlled by tribochemical reactions, involving chemical degradation of castor oil and the formation of metal oxy-hydroxides. Finally, to explain these findings, we propose a novel superlubricity mechanism consisting of hexanoic acid molecules intercalated between nickel and iron oxy-hydroxide lamellar layers, a structure very similar to the one found in Fe-Ni batteries. We propose that superlubricity is achieved due to repulsive electrostatic forces acting between the intercalated metal oxy-hydroxide lamellar compounds. This system would be suitable for practical engineering applications in many fields including biotechnologies.

  18. Evaluation of Castor Oil Cake Starch and Recovered Glycerol and Development of "Green" Composites Based on Those with Plant Fibers.

    Science.gov (United States)

    Guimarães, José Luis; Trindade Cursino, Ana Cristina; Ketzer Saul, Cyro; Sierrakowski, Maria Rita; Ramos, Luiz Pereira; Satyanarayana, Kestur Gundappa

    2016-01-27

    Continuous efforts are being made in some countries for the recovery of crude glycerin (RG/CG) and castor oil cake (COC), the two byproducts of biodiesel production. These are expected to help, not only in addressing environmental safety, but also in adding value to those byproducts, which otherwise may go to waste. Finding ways to utilize those byproducts underlines the main objective of this study. This paper presents the evaluation of (i) COC, glycerin and banana and sugarcane fibers for moisture content; (ii) COC for structural and thermal properties; and (iii) CG for its chemical characteristics. The possibility of using COC and CG with the selected fibers as reinforcement in the development of bio-composites is attempted through thermo-molding. Results revealed enhanced mechanical properties for these composites. The obtained results are discussed in terms of the observed morphology.

  19. The effects of possible contamination on the radiocarbon dating of the Dead Sea Scrolls I: Castor oil

    OpenAIRE

    Rasmussen, KL; van der Plicht, J; Cryer, FH; Doudna, G; Cross, FM; Strugnell, J; Rasmussen, Kaare L.; Cryer, Frederick H.; Cross, Frank M.

    2001-01-01

    Some fragments of the Dead Sea Scroll manuscripts were contaminated with castor oil in the late 1950s. We have conducted experiments in order to establish if the AAA pretreatment cleaning procedures conducted on Dead Sea Scroll manuscript samples in the last two dating series (Bonani et al. 1992; Jull et al. 1995) were effective in removing oil contamination. Our experiments show that not all oil contamination can be expected to have been removed by the acid-alkaline-acid (AAA) pretreatment, ...

  20. Polyurethane and polyurea nanoparticles based on polyoxyethylene castor oil derivative surfactant suitable for endovascular applications.

    Science.gov (United States)

    Morral-Ruíz, Genoveva; Melgar-Lesmes, Pedro; García, María Luísa; Solans, Conxita; García-Celma, María José

    2014-01-30

    The design of new, safe and effective nanotherapeutic systems is an important challenge for the researchers in the nanotechnology area. This study describes the formation of biocompatible polyurethane and polyurea nanoparticles based on polyoxyethylene castor oil derivative surfactant formed from O/W nano-emulsions by polymerization at the droplet interfaces in systems composed by aqueous solution/Kolliphor(®) ELP/medium chain triglyceride suitable for intravenous administration. Initial nano-emulsions incorporating highly hydrophilic materials were prepared by the phase inversion composition (PIC) method. After polymerization, nanoparticles with a small particle diameter (25-55 nm) and low polydispersity index were obtained. Parameters such as concentration of monomer, O/S weight ratio as well as the polymerization temperature were crucial to achieve a correct formation of these nanoparticles. Moreover, FT-IR studies showed the full conversion of the monomer to polyurethane and polyurea polymers. Likewise the involvement of the surfactant in the polymerization process through their nucleophilic groups to form the polymeric matrix was demonstrated. This could mean a first step in the development of biocompatible systems formulated with polyoxyethylene castor oil derivative surfactants. In addition, haemolysis and cell viability assays evidenced the good biocompatibility of KELP polyurethane and polyurea nanoparticles thus indicating the potential of these nanosystems as promising drug carriers. Copyright © 2013 Elsevier B.V. All rights reserved.

  1. Bio-based polyurethane prepared from Kraft lignin and modified castor oil

    Directory of Open Access Journals (Sweden)

    L. B. Tavares

    2016-11-01

    Full Text Available Current challenges highlight the need for polymer research using renewable natural sources as a substitute for petroleum-based polymers. The use of polyols obtained from renewable sources combined with the reuse of industrial residues such as lignin is an important agent in this process. Different compositions of polyurethane-type materials were prepared by combining technical Kraft lignin (TKL with castor oil (CO or modified castor oil (MCO1 and MCO2 to increase their reactivity towards diphenylmethane diisocyanate (MDI. The results indicate that lignin increases the glass transition temperature, the crosslinking density and improves the ultimate stress especially for those prepared from MCO2 and 30% lignin content from 8.2 MPa (lignin free to 23.5 MPa. Scanning electron microscopy (SEM micrographs of rupture surface after uniaxial tensile tests show ductile-to-brittle transition. The results show the possibility to develop polyurethane-type materials, varying technical grade Kraft lignin content, which cover a wide range of mechanical properties (from large elastic/low Young modulus to brittle/high Young modulus polyurethanes.

  2. Production of quartz plates for CMS-CASTOR Experiment

    CERN Document Server

    Adiguzel, Aytul; Ayhan, Aydin; Bakirci, Mustafa Numan; Basegmez, Suzan; Beaumont, Willem; Borras, Kerstin; Campbell, Alan; De Paula Carvalho, W; Çerçi, Salim; De Jesus Damiao, Dilson; Dogangün, O; Dumanoglu, Isa; d'Enterria, David; Erchov, Y; Eskut, Eda; Figueiredo, D; Girgis, Semiray; Göttlicher, P; Gouskos, Loukas; Gurpinar, Emine; Hos, Ilknur; Katkov, Igor; Katsas, Panagiotis; Khein, Lev; Knutsson, Albert; Kuznetsov, Andrey; Lebeau, Michel; Van Mechelen, Pierre; Muhl, Carsten; Musienko, Yuri; Ochesanu, Silvia; Onengüt, G; Onengut, G Jr; Ozdemir, Kadri; Panagiotou, Apostolos; Polatoz, A; Ripert, Marion; Shileev, K; Sogut, Kenan; Tiflov, B TaliV; Kayis-Topaksu, A; Uzun, Dilber

    2008-01-01

    Light transmission rate performance of $102$ irradiated quartz samples was measured to select the best quartz plates for CMS-CASTOR calorimeter. All the produced quartz plates were originally used in a previous CERN experiment, DELPHI. Three different doses of $^{60}$Co source were used with the collaboration of PSI (Paul Scherrer Institute, Villigen PSI, Switzerland.) to study the transmission rate performance of the quartz samples after irradiation for different incident light, ranging from $250$ to $700$ nm in $5$ nm increasing steps. All samples show different decrease in the rate with wavelength for different doses. Three different steps were followed before irradiation to find out the best way of cleaning the original DELPHI Cu/Cr tracks on the samples. Results of these measurements presented here correspond to the quartz plates that will be used in one hadronic sector of CASTOR calorimeter until end of 2008. For the full calorimeter new quartz plates will be installed. We also present the light transmi...

  3. EFFECT OF CASTOR BEAN (Ricinus communis L.) AQUEOUS ...

    African Journals Online (AJOL)

    User

    potted plant studies, crude castor bean aqueous extracts and its lower concentrations of 20, 40 ... -knot nematodes in vitro and in potted-tomato plants, but this was not demonstrated in field stud- ies. Further ..... tain medicinal plant oil products.

  4. Optimization of castor seed oil extraction process using response surface methodology

    Directory of Open Access Journals (Sweden)

    J. D. Mosquera-Artamonov

    2016-09-01

    Full Text Available This work focuses on the study of the oil extraction yield from castor seed using three different seed conditions: whole, minced and bare endosperm. Taguchi design was used to determine the contribution of the following parameters: seed condition, seed load in the extractor, temperature, and pressure. It was proved that it is necessary to introduce the whole seed and that the presence of the pericarp increases the extraction yield. The contribution of the control factors has an extraction yield limit. After determining which factors contributed to the process, these were left at their optimum levels aiming to reduce the control factors to only two. The complete analysis was done using a surface response methodology giving the best parameter for temperature and pressure that allows a better yielding mechanical extraction. The oil extraction yield can be kept up to 35% of the seed.

  5. The effects of possible contamination on the radiocarbon dating of the Dead Sea Scrolls I : Castor oil

    NARCIS (Netherlands)

    Rasmussen, KL; van der Plicht, J; Cryer, FH; Doudna, G; Cross, FM; Strugnell, J; Rasmussen, Kaare L.; Cryer, Frederick H.; Cross, Frank M.

    2001-01-01

    Some fragments of the Dead Sea Scroll manuscripts were contaminated with castor oil in the late 1950s. We have conducted experiments in order to establish if the AAA pretreatment cleaning procedures conducted on Dead Sea Scroll manuscript samples in the last two dating series (Bonani et al. 1992;

  6. THE EFFECTS OF POSSIBLE CONTAMINATION ON THE RADIOCARBON DATING OF THE DEAD SEA SCROLLS II: EMPIRICAL METHODS TO REMOVE CASTOR OIL AND SUGGESTIONS FOR REDATING

    OpenAIRE

    Rasmussen, Kaare Lund; van der Plicht, Johannes; Doudna, Gregory; Nielsen, Frederik; Hojrup, Peter; Stenby, Erling Halfdan; Pedersen, Carl Th; Højrup, Peter

    2009-01-01

    While kept at the Rockefeller Museum in East Jerusalem, many Dead Sea Scroll fragments were exposed to castor oil by the original team of editors in the course of cleaning the parchments. Castor oil must be regarded as a serious contaminant in relation to radiocarbon dating. If modern castor oil is present and is not removed prior to dating, the (14)C dates will be skewed artificially towards modern values. In Rasmussen et al. (2001), it was shown that the standard AAA pretreatment procedure ...

  7. Mechanical Behavior of Castor-Oil-Based Advanced Polyurethane Functionalized with Glycidol and Siloxanes

    Science.gov (United States)

    Mathew, Aiswarea; Kurmvanshi, Surendra; Mohanty, Smita; Nayak, Sanjay K.

    2017-09-01

    Castor-oil-based polyurethane (PU), epoxy (glycidol) terminated polyurethane (EPU), and hydroxy terminated poly (dimethyl siloxane) (HTPDMS) modified EPU (EPDMS) were synthesized. The PU and EPU were synthesized with polyol:diisocyanate and polyol:diisocyanate:glycidol ratio of 1:1.2 and 1:3:3, respectively, whereas EPDMS was prepared by the incorporation of 5 wt.%, 10 wt.%, 20 wt.%, and 30 wt.% of HTPDMS into the EPU. The structural modification of EPDMS was confirmed by solid-state CP/MAS 13C and 29Si NMR spectroscopy. The results of a tensile test revealed that the EPDMS with 10 wt.% loading of HTPDMS (EPDMS10) exhibited considerable enhancement in the tensile strength and modulus. The scanning electron microscope analysis was performed to understand the increased phase heterogeneity of the samples.

  8. Castor oil and commercial thermoplastic polyurethane membranes modified with polyaniline: a comparative study

    Energy Technology Data Exchange (ETDEWEB)

    Almeida Junior, Jose Humberto Santos; Meneguzzi, Alvaro; Ferreira, Carlos Arthur, E-mail: jhsajunior@globomail.com [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegtre, RS (Brazil). Dept. de Engenharia de Materiais; Bertuol, Daniel Assumpcao [Universidade Federal de Santa Maria (UFSM), RS (Brazil). Dept. de Engenharia Quimica; Amado, Franco Dani Rico [Universidade Estadual de Santa Cruz (UESC), Ilheus, BA (Brazil). Dept. de Ciencias Exatas e Tecnologia

    2013-11-01

    The study of conducting polymeric membranes is decisive in some areas, as in fuel cells and electrodialysis. This work aims the study of membranes using conventional and conductive polymers blends. Two types of polyurethane were used as conventional polymers, commercial thermoplastic polyurethane and polyurethane synthesized from castor oil and 4-4-dicyclohexylmethane isocyanate. Two kinds of conducting polymers were used, polyaniline doped with organic acid and a self doped polyaniline. The polymers and the membranes were characterized by electrical conductivity, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and scanning electron microscopy (SEM). The synthesis of the membranes produced was proper, featuring a complete reaction, analyzed by FTIR. The membranes also showed good mechanical properties and thermal stability ( Almost-Equal-To 220 Degree-Sign C). Among the membranes studied, the polyaniline doped with p-toluenesulphonic acid obtained higher thermal and viscoelastic properties. Thus they can be used in separation techniques using membranes. (author)

  9. Castor oil and commercial thermoplastic polyurethane membranes modified with polyaniline: a comparative study

    Directory of Open Access Journals (Sweden)

    José Humberto Santos Almeida Júnior

    2013-01-01

    Full Text Available The study of conducting polymeric membranes is decisive in some areas, as in fuel cells and electrodialysis. This work aims the study of membranes using conventional and conductive polymers blends. Two types of polyurethane were used as conventional polymers, commercial thermoplastic polyurethane and polyurethane synthesized from castor oil and 4-4-dicyclohexylmethane isocyanate. Two kinds of conducting polymers were used, polyaniline doped with organic acid and a self doped polyaniline. The polymers and the membranes were characterized by electrical conductivity, Fourier transform infrared spectroscopy (FTIR, thermogravimetric analysis (TGA, dynamic mechanical analysis (DMA and scanning electron microscopy (SEM. The synthesis of the membranes produced was proper, featuring a complete reaction, analyzed by FTIR. The membranes also showed good mechanical properties and thermal stability (≈ 220 °C. Among the membranes studied, the polyaniline doped with p-toluenesulphonic acid obtained higher thermal and viscoelastic properties. Thus they can be used in separation techniques using membranes.

  10. HDO of guaiacol over NiMo catalyst supported on activated carbon derived from castor de-oiled cake

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    Viviana Ospina

    2015-08-01

    Full Text Available Physical and chemical activation methods were used to prepare two different activated carbons (ACs from castor de-oiled cake. H2O/CO2 mixture was used as the physical activating agent, and for chemical activation potassium carbonate (K2CO3 was used. For both materials, textural and chemical properties were characterized by N2 adsorption–desorption isotherms, thermogravimetric analysis (TGA, Fourier Transform Infrared Spectroscopy (FTIR, thermal programmed reduction (TPR, X-ray fluorescence (XRF, and scanning electron microscopy (SEM. The ACs were used as supports for NiMo sulfide catalysts, which were prepared by wetness impregnation and in-situ sulfided for the hydrodeoxygenation (HDO of guaiacol (GUA as a model compound of bio-oil. The HDO reaction was carried out in a typical batch reactor at 5 MPa of H2 and 350 °C. Under the same test conditions, commercial catalysts were also tested in the reaction. Although the commercial catalysts displayed higher GUA conversion, the prepared catalysts showed higher activity and non-oxygenated and saturated products yield. 

  11. Síntesis y caracterización de espumas flexibles de poliuretano obtenidas a partir de aceite de castor maleinizado Flexible polyurethane foam synthesis and characterization obtained from maleinizated castor oil

    Directory of Open Access Journals (Sweden)

    Paula Mazo

    2009-06-01

    Full Text Available En este trabajo se realiza la síntesis de espumas flexibles de poliuretano empleando un diseño experimental Taguchi, utilizando aceite de castor con y sin maleinización, se estudia la cinética de la reacción de esterificación del aceite por cuantificación de los grupos ácido (ASTM D4662 - 03 y se evalúan las propiedades mecánicas de las espumas (densidad, resistencia tensil, % elongación, resiliencia y dureza. Norma NTC 2019 Icontec obtenidas en función de las variables de síntesis (cantidad y tipo de catalizador, relación molar aceite castor (CO - aceite maleinizado (MACO, cantidad de agua y surfactante empleado. Se realizan análisis de FTIR y SEM para las espumas. Los resultados mostraron una cinética de primer orden con respecto al anhídrido. El aceite maleinizado (MACO incrementa la resistencia mecánica de las espumas, debido al mayor entrecruzamiento por la incorporación de grupos ácido.In this work, the synthesis of polyurethane flexible foam is realized with the experimental design Taguchi, using castor oil with and without maleinization. The kinetic reaction of oil esterification was monitored by estimating the number of acid groups (ASTM D4662 - 03, and the mechanical properties of the foam were studied, including density, tensile resistance, % elongation, resilience and hardness (Norm NTC 2019 Icontec. The influence of various synthesis parameters was investigated, namely amount and type of catalyst, molar ratio of castor oil (CO - maleinizated castor oil (MACO, amount of water and surfactant used. The foams were analyzed using FTIR and scanning electron microscopy (SEM. The results showed first order kinetics with respect to the anhydride. The maleinizated castor oil (MACO increased the mechanical resistance of the foam due to the greater interweaving by the incorporation of acid groups.

  12. The effect of herbivory on temporal and spatial dynamics of foliar nectar production in cotton and castor

    NARCIS (Netherlands)

    Wäckers, F.L.; Zuber, D.; Wunderlin, R.; Keller, F.

    2001-01-01

    The effects of feeding Spodoptera littoralis(Boisd.) (Lepidoptera: Noctuidae) larvae on the quantity and distribution of extrafloral nectar production by leaves of castor (Ricinus communis) and cotton (Gossypium herbaceum) were investigated. Following larval feeding, the total volume of nectar

  13. The effect of herbivory on temporal and spatial dynamics of foliar nectar production in cotton and castor

    NARCIS (Netherlands)

    Wäckers, F.L.; Zuber, D.; Wunderlin, R.; Keller, F.

    2001-01-01

    The effects of feeding Spodoptera a littoralis (Boisd.) (Lepidoptera: Noctuidae) larvae on the quantity and distribution of extrafloral nectar production by leaves of castor ((Ricinus communis) and cotton (Gossypium herbaceum) were investigated. Following larval feeding, the total volume of nectar

  14. Synthesis and characterization of polyanhydride derived from castor oil; Sintese e caracterizacao de polianidrido derivado do oleo de mamona

    Energy Technology Data Exchange (ETDEWEB)

    Borges, Fernando de M.; Reis, Roberta Yonara Nascimento; Nobre, Francisco X.; Matos, Jose M.E., E-mail: robertayonara@gmail.com [Universidade Federal do Piaui (UFPI), Teresina, PI (Brazil)

    2015-07-01

    Polyanhydrides are biopolymers already used as drug carriers, that allow the controlled release of the drug in vivo. Currently, these polymers are produced from a polyol, such as ethyleneglycol. In this work we synthesized a polyanhydride from castor oil, from the derivatization of oil via alcoholysis reaction. The oil was then converted to a monoglyceride (MG) by alcoholysis reaction at 140 °C. The MG reacted with phthalic anhydride (PA) at 100 °C, forming the polymer P1. The polymer was characterized by FT-IR, {sup 1}H and {sup 13}C NMR. These techniques allowed confirmation of the polymer formation. (author)

  15. Morphology of autogenous bone graft and castor oil polyurethane in the infraorbital rim of rabbits: a comparative study

    Directory of Open Access Journals (Sweden)

    Mendonça José Carlos Garcia de

    2006-01-01

    Full Text Available PURPOSE: Morphological study comparing castor oil polyurethane and autogenous bone graft to repair bone defect in zygomatic bone of rabbits. METHODS: Twenty-four adult, male New Zealand rabbits were randomly distributed between two groups of twelve. Bone defects of 5mm in diameter were cut through the zygomatic bone and filled with polyurethane discs in the experimental group or autogenous bone harvested from the tibia in the control group. Animals were sacrificed after 30, 60 or 90 days, and the zygomatic bones were macro- and microscopically analyzed. Student's, Fisher's, chi-squared and McNemar's tests were used for statistical analysis. RESULTS: Both the castor oil polyurethane and the autograft adapted well to the defect, with no need for fixation. Fibrous connective tissue encapsulated the polyurethane, but no inflammation or giant cell reaction was observed. Acidophilic and basophilic areas were observed inside the micropores of the polyurethane, suggesting cell nuclei. After 90 days, bone repair with a lamellar pattern of organization was observed in the control group. CONCLUSION: The castor oil polyurethane was biocompatible and did not cause inflammation. It may be considered an alternative to fill bone defects.

  16. Intake, nutrient apparent digestibility and ruminal constituents of sheep fed diets with canola, sunflower or castor oils

    Directory of Open Access Journals (Sweden)

    Michelle de Oliveira Maia

    2012-11-01

    Full Text Available The objective in this experiment was to determine the effects of feeding diets with canola, sunflower or castor oils on intake, nutrient apparent digestibility and ruminal constituents of crossbred Dorper × Santa Inês sheep. Four rumen-cannulated animals of 90.2±11.4 kg average body weight were assigned to a 4 × 4 latin square. Animals remained individually in cages for the metabolism assay and were fed diets containing roughage at 500 g/kg and concentrate based on ground corn and soybean meal also at 500 g/kg. No oil was added to the control diet, whereas the others had canola, sunflower or castor oils at 30 g/kg (DM basis. There was no difference for the intake of DM and nutrients, except for ether extract, which was greater when animals received oil. The digestibility coefficients of dry matter, organic matter, crude protein, non-fiber carbohydrates and neutral detergent fiber were not changed; however, the addition of oil increased the ether extract digestibility. The values of total digestible nutrients (TDN, g/kg of DM, digestible energy (DE, Mcal/kg of DM, TDN intake and DE intake also did not change with the addition of lipids. Concerning the ruminal constituents, the addition of vegetable oils reduced the concentrations of acetate, butyrate and total short-chain fatty acids. Adding canola, sunflower or castor oils at 30 g/kg in diets with 500 g roughage/kg and 500 g concentrate/kg does not impair the intake or digestibility of nutrients in sheep, although it reduces the concentration of short-chain fatty acids in the rumen.

  17. Effect of plant and row spacing on the yield and oil contents of castor ...

    African Journals Online (AJOL)

    Castor (Ricinus communis L.) is an industrial non edible oilseed adapted to drier areas. An experiment was conducted in the Central Rift Valley of Ethiopia to determine optimum plant population of castor variety Hiruy. Four plant (50, 60, 70 and 80 cm) and four row spacing (60,80,100 and 120 cm) were arranged in factorial ...

  18. Computational identification and phylogenetic analysis of the oil-body structural proteins, oleosin and caleosin, in castor bean and flax.

    Science.gov (United States)

    Hyun, Tae Kyung; Kumar, Dhinesh; Cho, Young-Yeol; Hyun, Hae-Nam; Kim, Ju-Sung

    2013-02-25

    Oil bodies (OBs) are the intracellular particles derived from oilseeds. These OBs store lipids as a carbon resource, and have been exploited for a variety of industrial applications including biofuels. Oleosin and caleosin are the common OB structural proteins which are enabling biotechnological enhancement of oil content and OB-based pharmaceutical formations via stabilizing OBs. Although the draft whole genome sequence information for Ricinus communis L. (castor bean) and Linum usitatissimum L. (flax), important oil seed plants, is available in public database, OB-structural proteins in these plants are poorly indentified. Therefore, in this study, we performed a comprehensive bioinformatic analysis including analysis of the genome sequence, conserved domains and phylogenetic relationships to identify OB structural proteins in castor bean and flax genomes. Using comprehensive analysis, we have identified 6 and 15 OB-structural proteins from castor bean and flax, respectively. A complete overview of this gene family in castor bean and flax is presented, including the gene structures, phylogeny and conserved motifs, resulting in the presence of central hydrophobic regions with proline knot motif, providing an evolutionary proof that this central hydrophobic region had evolved from duplications in the primitive eukaryotes. In addition, expression analysis of L-oleosin and caleosin genes using quantitative real-time PCR demonstrated that seed contained their maximum expression, except that RcCLO-1 expressed maximum in cotyledon. Thus, our comparative genomics analysis of oleosin and caleosin genes and their putatively encoded proteins in two non-model plant species provides insights into the prospective usage of gene resources for improving OB-stability. Copyright © 2012 Elsevier B.V. All rights reserved.

  19. Performance and Emission Characteristics of a Compression Ignition Engine Operating on Blends of Castor Oil Biodiesel-Diesel

    Science.gov (United States)

    Kanwar, Roopesh; Sharma, Pushpendra Kumar; Singh, Aditya Narayan; Agrawal, Yadvendra Kumar

    2017-04-01

    Diesel vehicles are the nerves and veins of transportation, particularly in developing countries. With the rapid rate of modernization, increasing demand of fuel is inevitable. The exponential increase in fuel prices and the scarcity of its supply from the environment have promoted interest in the development of alternative sources of fuel. In this work, genus Ricinus communis L. was studied in order to delimit their potential as a raw material for biodiesel production. Further, castor oil, ethyl ester were prepared by transesterification using potassium hydroxide (KOH) as a catalyst and tested on a four-stroke, single-cylinder compression ignition engine. The test was carried out at a constant speed of 3000 rpm at different loads. The results represent a substantial decrease in carbon monoxide (CO) emission with an increasing biodiesel percentage. The reduction of CO in B05, B10, B15 and B20 averaged 11.75, 22.02, 24.23 and 28.79 %, respectively, compared to mineral diesel. The emission results of the comparative test indicated that CO, oxygen (O2) and smoke density emissions are found to be lower when the engine is filled with B05, B10, B15 and B20 as compared to mineral diesel, while carbon dioxide (CO2) and nitrogen oxide (NOx) with B05, B10, B15 and B20 are found to increase marginally. Brake thermal efficiency and brake specific fuel consumption decrease and increase respectively in biodiesel with different blends in comparison of mineral diesel.

  20. Flexural behavior of Sisal/Castor oil-Based Polyurethane and Sisal/Phenolic Composites

    Directory of Open Access Journals (Sweden)

    Andressa Cecília Milanese

    2012-04-01

    Full Text Available Natural fibers used as reinforcement of polymeric composites are interesting research subjects in polymer technology. Nowadays, these materials are being considered as a way to reinforce timber structures improvement. Fibers with larger structural applications are glass and carbon fibers, however, the use of natural fibers is an economic alternative and present many advantages such as biodegradability and having its origin from a renewable source. Castor oil, a triglyceride vegetable with hydroxyl groups, was reacted with 4,4' methylene diphenyl diisocyanate (MDI to produce the polyurethane matrix. The composites were prepared by compress molding at room temperature using woven sisal fiber as a reinforcement, with and without thermal treatment (at 60 ºC for 72 hours to the fabrics before the composites molding process. The present paper presents the preparation and a flexural caracterization of sisal/polyurethane and sisal/phenolic composites by using the three-point bending. The sisal fibers moisture content influence on the flexural behaviour was also analyzed. Experimental results showed a higher stiffness for the sisal/phenolic composite (11.2 MPa followed by the sisal/polyurethane (3.7 MPa, respectively.

  1. Evaluation of the properties of iron oxide-filled castor oil polyurethane

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    Eleonora Mussatti

    2013-02-01

    Full Text Available The aim of this study was to obtain and evaluate the electrical, thermal and mechanical properties of iron oxide-filled castor oil polyurethane (PU/Fe2O3. The iron oxide used in this study was a residue derived from the steel pickling process of a Brazilian steel rolling industry. Polymeric composites with different iron oxide volume fractions (2.5, 5.0, 7.5, 10.0 and 12.5% were prepared through the casting process followed by compression molding at room temperature. The composites were analyzed by FTIR, XRD and densities, tensile strength, Young's modulus, electrical and thermal conductivities measurements. By increasing the iron oxide content, the apparent density, tensile strength, Young's modulus and electrical conductivity values of the composites were also increased. The iron oxide additions did not change significantly the value of thermal conductivity (from 0.191 W.mK-1 for PU up to 0.340 W.mK-1 for PU enriched with 12.5% v/v of iron oxide. Thus, even at the higher iron oxide concentration, the compounds as well as the pure polyurethane can be classified as thermal insulators.

  2. Accelerated artificial aging of particleboards from residues of CCB treated Pinus sp. and castor oil resin

    Directory of Open Access Journals (Sweden)

    Marília da Silva Bertolini

    2013-04-01

    Full Text Available Tests simulating exposure to severe weather conditions have been relevant in seeking new applications for particleboard. This study aimed to produce particleboards with residues of CCB (chromium-copper-boron oxides impregnated Pinus sp. and castor oil-based polyurethane resin, and to evaluate their performance before and after artificial accelerated aging. Panels were produced with different particle mass, resin content and pressing time, resulting eight treatments. Particles moisture and size distribution were determined, beyond panel physical and mechanical properties, according to NBR14810-3: 2006. After characterization, treatments B and G (small adhesive consumption and better mechanical performance, respectively were chosen to artificial aging tests. Statistical results analysis showed best performances were achieved for waterproof aged samples, of both B and G treatments. As example, in treatment B, MOR and MOE values were 23 MPa and 2,297 MPa, samples before exposure; 26 MPa and 3,185 MPa, 32 MPa and 3,982 MPa for samples after exposure (non-sealed and sealed, respectively.

  3. Effects of sowing dates and different fertilizers on yield, yield components, and oil percentage of castor bean (Ricinus communis L.

    Directory of Open Access Journals (Sweden)

    parviz rezvani moghadam

    2009-06-01

    Full Text Available In order to study the effects of sowing dates and different fertilizers on yield, yield components, and oil percentage of castor bean, an experiment was conducted at Experimental station, College of Agriculture, Ferdowsi University of Mashhad, Iran in years 2004-2005. The experimental treatments comprised all combinations of four sowing dates (11 April, 25 April, 8 May and 22 May and three different fertilizers (cow manure (30 tons/ha, compost (30 tons/ha, chemical fertilizers (100 kg/ha N and 250 kg/ha of super phosphate and no fertilizer as control. Different characteristics such as plant height, main inflorescence height, number of inflorescence per plant, number of secondary stems per plant, number of capsules per plant, number of grain per plant, grain weight per plant, 100 seed weight, grain yield, oil percentage and oil yield were recorded. A factorial arrangement based on a randomized complete block design with three replications was used. The results showed by delaying sowing date grain yield, seed oil percentage and oil yield were decreased, but there was no significant differences between 25 April, 8 May and 22 May sowing dates. Harvest index and 100 seed weight did not affect by neither sowing dates nor fertilizer treatments. The highest number of branches per plant, number of fertile inflorescences per plant, number of fertile capsules per plant, number of grain per plant, grain weight per plant and biological yield were obtained at 8 May sowing date on chemical fertilizer. Percentage of seed oil, grain yield and oil yield was higher at the first sowing date (11 April in compost and chemical fertilizer treatments. Keywords: Castor bean, sowing date, fertilizer, grain yield, oil percentage.

  4. Influence of MgO on Performance and Emissions of DI Engine using blends of Castor oil

    Science.gov (United States)

    Ganesan, S.; Padmanabhan, s.; Senthil kumar, J.; Polina, Navakanth; Krishna kumar, Sanivada

    2017-05-01

    With the technological development, the research over alternate fuels is increasing day by day in order to help the upcoming generation with a bright and greener future. In order to preserve the existing petroleum resources for future generation, it is necessary to soon switch to any alternate source which is easily available, renewable as well as environment friendly. In this paper I would like to highlight upon the usage of Diesel, Castor Oil and Nano Particles for a compression ignition engine and study the emission characteristics of this fuel at different mixing ratios and analyze the different levels of residue particles.

  5. Rosemary, Castor Oils, and Propolis Extract: Activity Against Candida Albicans and Alterations on Properties of Dental Acrylic Resins.

    Science.gov (United States)

    Heidrich, Daiane; Fortes, Carmen Beatriz Borges; Mallmann, Aline Taís; Vargas, Clarissa Machado; Arndt, Paula Borges; Scroferneker, Maria Lúcia

    2018-01-11

    To evaluate the in vitro activity of 8% rosemary, 2% castor oils, and 12% propolis glycolic extract against Candida albicans, as well as the physical changes of properties in colorless and pink acrylic resins after immersion in these liquids. Colorimetric, roughness, and Knoop microhardness assays were evaluated in 25 specimens distributed into five groups (3 test groups and 2 control groups - distilled water and hypochlorite 1%), totaling five specimens per group for each acrylic resin (colorless and pink). The specimens were individually immersed for 30 minutes in 10 mL of these liquids, washed, and dried once a week. They were maintained in distilled water at 37°C between processes during all experiments. The analyses were performed before immersion and in the 4th and/or 12th month. In vitro, 18 acrylic resins were exposed to C. albicans and, after a process of 30 minutes in immersion in the five groups cited and oil vehicle control of vesicle (liquid Vaseline), the specimens were washed and incubated for 24 hours in 37°C. The growth was determined by colony counting. For comparisons between the groups in each trial and the disinfection test, paired Student's t-tests and ANOVA with post hoc Tukey were performed by the SPSS program, considering α = 0.05. None of the liquids altered the microhardness, but all the natural compounds and 1% sodium hypochlorite (control) altered color and roughness after the 12th month of immersion in these agents. In the colorless specimens, 8% rosemary oil caused a color change similar to water, and less color and roughness alterations when compared to 2% castor oil and 1% sodium hypochlorite, respectively. There was no growth of yeast colonies after immersion in rosemary oil, propolis glycolic extract, and 1% sodium hypochlorite. Eight percent rosemary oil has the potential to be used as an acrylic resin disinfectant. © 2018 by the American College of Prosthodontists.

  6. Reproductive responses and productive characteristics in ewes supplemented with detoxified castor meal for a long period

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    Liliane Moreira Silva

    2014-08-01

    Full Text Available The objective of the present study was to evaluate the effects of supplementation with detoxified castor meal (DCM in the diet of ewes during pregnancy, partum, and post-partum on the weight development of their offspring and at slaughter. The study included 56 ewes with synchronized estrus that were naturally mated. At the beginning of pregnancy and in post-partum, hepatic and renal function-related parameters and progesterone levels were measured. At slaughter, the proximate composition and fatty acid profile were determined in the loin of ewes. There was no effect of diet on reproductive response after estrus synchronization. At the beginning of pregnancy, albumin and creatinine levels were lower in the DCM group. Supplementation with DCM did not alter the weight or body condition of ewes at partum. However, at weaning, the DCM group showed a higher loin-eye area (LEA in relation to the group fed diets without detoxified castor meal (WDCM. At partum, as well as at weaning, the offspring of the ewes supplemented with DCM had a larger LEA than the WDCM group. In post-partum, levels of glucose, urea, protein, and cholesterol were lower in the DCM group. The return to cyclicity was similar in both groups, with an average of 47 days after partum. At slaughter, neither anatomical and carcass components nor the results of the proximate analysis were affected by the type of diet, except for an increase in heptadecanoic acid in the DCM group. Supplementation with detoxified castor meal in the diet of ewes does not affect lambing, pregnancy, prolificacy, return to cyclicity, milk production, blood biochemical parameters, or carcass characteristics.

  7. Evaluation of Castor Oil Cake Starch and Recovered Glycerol and Development of “Green” Composites Based on Those with Plant Fibers

    Directory of Open Access Journals (Sweden)

    José Luis Guimarães

    2016-01-01

    Full Text Available Continuous efforts are being made in some countries for the recovery of crude glycerin (RG/CG and castor oil cake (COC, the two byproducts of biodiesel production. These are expected to help, not only in addressing environmental safety, but also in adding value to those byproducts, which otherwise may go to waste. Finding ways to utilize those byproducts underlines the main objective of this study. This paper presents the evaluation of (i COC, glycerin and banana and sugarcane fibers for moisture content; (ii COC for structural and thermal properties; and (iii CG for its chemical characteristics. The possibility of using COC and CG with the selected fibers as reinforcement in the development of bio-composites is attempted through thermo-molding. Results revealed enhanced mechanical properties for these composites. The obtained results are discussed in terms of the observed morphology.

  8. Evaluation of Castor Oil Cake Starch and Recovered Glycerol and Development of “Green” Composites Based on Those with Plant Fibers

    Science.gov (United States)

    Guimarães, José Luis; Trindade Cursino, Ana Cristina; Ketzer Saul, Cyro; Sierrakowski, Maria Rita; Ramos, Luiz Pereira; Satyanarayana, Kestur Gundappa

    2016-01-01

    Continuous efforts are being made in some countries for the recovery of crude glycerin (RG/CG) and castor oil cake (COC), the two byproducts of biodiesel production. These are expected to help, not only in addressing environmental safety, but also in adding value to those byproducts, which otherwise may go to waste. Finding ways to utilize those byproducts underlines the main objective of this study. This paper presents the evaluation of (i) COC, glycerin and banana and sugarcane fibers for moisture content; (ii) COC for structural and thermal properties; and (iii) CG for its chemical characteristics. The possibility of using COC and CG with the selected fibers as reinforcement in the development of bio-composites is attempted through thermo-molding. Results revealed enhanced mechanical properties for these composites. The obtained results are discussed in terms of the observed morphology. PMID:28787878

  9. Synthesis and Physicochemical Behaviour of Polyurethane-Multiwalled Carbon Nanotubes Nanocomposites Based on Renewable Castor Oil Polyols

    Directory of Open Access Journals (Sweden)

    Alaa Ali

    2014-01-01

    Full Text Available Polyurethanes (PUs are high performance materials, with vast industrial and engineering applications. In this research, effects of Multiwalled Carbon Nanotubes (MWCNTs on physicochemical properties of Castor Oil based Polyurethanes (COPUs were studied. MWCNTs were added in different weight percentages (0% to 1% wt in a castor oil based polyurethane (COPUs-MWCNTs nanocomposites. The composition, structure, and morphology of polyurethanes were characterized by Fourier transform infrared spectroscopy (FTIR, X-ray diffraction (XRD, scanning electron microscopy (SEM, field emission scanning electron microscopy (FESEM, and element detection by energy dispersive spectroscopy (EDX analysis, respectively. Thermal stability was studied by thermogravimetric analysis (TGA. Barrier properties and surface area studies were investigated by nitrogen permeability machine and BET technique. Mechanical properties were calculated by tensile universal testing machine. Results showed well dispersed MWCNTs in polyurethane matrix at different weight percentages. The best results were obtained with 0.3 wt% of MWCNTs in the composite. Surface area studies revealed presence of very few pores which is in a good agreement with barrier permeability, reduced up to ~68% in 1 wt% and ~70% in 0.5 wt% of MWCNTs in polymer matrix, with respect to pure COPUs samples.

  10. Produtividade da mamona irrigada com esgoto doméstico tratado Productivity of castor bean irrigated with treated domestic sewage

    Directory of Open Access Journals (Sweden)

    Neyliane C. de Souza

    2010-05-01

    Full Text Available A mamoneira (Ricinus communis L., oleaginosa de relevante importância econômica e social no Nordeste, apresenta-se como alternativa para a produção do biodiesel. O experimento objetivou avaliar, em escala real, os aspectos produtivos da cultura da mamona irrigada com esgoto doméstico tratado. Empregou-se o sistema de microaspersão; a delimitação experimental foi de quatro repetições e quatro tratamentos: T1: água do poço e adubação recomendada; T2: esgoto doméstico tratado e adubação recomendada; T3: somente esgoto doméstico tratado e T4: esgoto doméstico tratado e metade da adubação recomendada. Verificou-se que as unidades irrigadas com esgoto tratado superaram as irrigadas com água, em quase todas as variáveis analisadas. A produtividade foi maior nos tratamentos irrigados com esgoto e adubação (T2 e (T4, alcançando produtividade de 1.986 e 1.412 kg ha-1, respectivamente. O teor de óleo contido nas sementes foi analisado e não apresentou nenhuma diferença significativa entre os tratamentos com adubação (T1, T2 e T4, sendo que o tratamento com esgoto tratado (T3 forneceu baixíssimos teores de óleo na semente.The castor bean (Ricinus communis L., an oil crop of economic and social importance for the Northeast region of Brazil, can be used for biodiesel production. The experiment aimed to evaluate, at a realistic scale, the productive aspects of the castor bean irrigated with treated sewage. Microsprinkler irrigation method was selected, and the experimental set-up consisted of four repetitions and four different treatments: well water and recommended fertilization (T1; treated wastewater and recommended fertilization (T2; treated wastewater without external recommended fertilization (T3; and treated wastewater and half of recommended fertilization (T4. It was found that units irrigated with treated sewage exceeded the ones irrigated with well water in almost all variables. The highest productivities were in the

  11. Acute toxicity study of tilmicosin-loaded hydrogenated castor oil-solid lipid nanoparticles

    Directory of Open Access Journals (Sweden)

    Xie Shuyu

    2011-11-01

    Full Text Available Abstract Background Our previous studies demonstrated that tilmicosin-loaded hydrogenated castor oil solid lipid nanoparticles (Til-HCO-SLN are a promising formulation for enhanced pharmacological activity and therapeutic efficacy in veterinary use. The purpose of this work was to evaluate the acute toxicity of Til-HCO-SLN. Methods Two nanoparticle doses were used for the study in ICR mice. The low dose (766 mg/kg.bw with tilmicosin 7.5 times of the clinic dosage and below the median lethal dose (LD50 was subcutaneously administered twice on the first and 7th day. The single high dose (5 g/kg.bw was the practical upper limit in an acute toxicity study and was administered subcutaneously on the first day. Blank HCO-SLN, native tilmicosin, and saline solution were included as controls. After medication, animals were monitored over 14 days, and then necropsied. Signs of toxicity were evaluated via mortality, symptoms of treatment effect, gross and microscopic pathology, and hematologic and biochemical parameters. Results After administration of native tilmicosin, all mice died within 2 h in the high dose group, in the low dose group 3 died after the first and 2 died after the second injections. The surviving mice in the tilmicosin low dose group showed hypoactivity, accelerated breath, gloomy spirit and lethargy. In contrast, all mice in Til-HCO-SLN and blank HCO-SLN groups survived at both low and high doses. The high nanoparticle dose induced transient clinical symptoms of treatment effect such as transient reversible action retardation, anorexy and gloomy spirit, increased spleen and liver coefficients and decreased heart coefficients, microscopic pathological changes of liver, spleen and heart, and minor changes in hematologic and biochemical parameters, but no adverse effects were observed in the nanoparticle low dose group. Conclusions The results revealed that the LD50 of Til-HCO-SLN and blank HCO-SLN exceeded 5 g/kg.bw and thus the

  12. Síntesis y caracterización de adhesivos reposicionables de poliuretano dispersos en agua, obtenidos a partir de aceite de castor maleinizado Synthesis and characterization of pressure-sensitive adhesives of waterborne polyurethane from maleinizated castor oil

    Directory of Open Access Journals (Sweden)

    Paula Mazo

    2010-06-01

    Full Text Available El presente trabajo se centró en la producción de dispersiones acuosas de poliuretano empleando el método de emulsificación por inversión de fases. Para la síntesis fueron empleados dos polioles: uno comercial tipo poliéster y el otro es aceite de castor maleinizado (MACO; dos diisocianatos, uno aromático Toluen diisocianato (TDI y otro alifático Hexametilen diisocianato (HDI, siendo poco comunes para esta aplicación. Como emulsificante interno se empleó ácido cítrico el cual es muy económico y de fácil adquisición. Como factores se evaluaron la cantidad de ácido cítrico y la relación molar de grupos isocianato a hidroxilos (NCO/OH, generando un diseño de experimentos factorial 3² y minimizando el contenido de sólidos sedimentados. Mediante la metodología de superficie de respuesta, se obtuvo una ecuación polinomial cuadrática por un análisis de regresión múltiple. Los poliuretanos formados fueron evaluados en cuanto a sus propiedades adhesivas y mecánicas (pegajosidad tack, pegajosidad en cinta loop tack, cohesión hold, pelado peel, lo que permitió clasificar el adhesivo como reposicionable, para emplearlo en etiquetas.This work focused on the production of aqueous dispersions of polyurethane using the emulsification method by phase inversion. For the synthesis two polyols were employed, viz. a commercial polyester and Maleinizated Castor Oil (MACO, with two diisocyanates: one aromatic, toluene diisocyanate (TDI and another aliphatic, hexamethylene diisocyanate (HDI, which are not common for this application. Citric acid was used as internal emulsifier which is inexpensive and readily available. The parameters were the amount of citric acid and the mole ratio of isocyanate groups to hydroxyl (NCO/OH, generating a 3² factorial design, with minimization of the sedimented solids. The surface methodology was used to obtain a quadratic polynomial equation by multiple regression analysis. Polyurethanes synthesized were

  13. Development of Castor Oil Based Poly(urethane-esteramide/TiO2 Nanocomposites as Anticorrosive and Antimicrobial Coatings

    Directory of Open Access Journals (Sweden)

    Mohammed Rafi Shaik

    2015-01-01

    Full Text Available Castor oil based polyesteramide (CPEA resin has been successfully synthesized by the condensation polymerization of N-N-bis (2-hydroxyethyl castor oil fatty amide (HECA with terephthalic acid and further modified with different percentages of 7, 9, 11, and 13 wt.% of toluene-2,4-diisocyanate (TDI to obtain poly(urethane-esteramide (UCPEA, via addition polymerization. TiO2 (0.1, 0.2, 0.3, 0.4, and 0.5 wt% nanoparticles were dispersed in UCPEA resin. The structural elucidation of HECA, CPEA, and UCPEA has been carried out using FT-IR, 1H-NMR, and 13C-NMR spectroscopic techniques while physicochemical and physicomechanical properties were investigated by standard methods. Thermal stability and molecular weight of UCPEA have been assessed by thermogravimetric analysis (TGA and gel permeation chromatography (GPC, respectively. Furthermore, the corrosion behavior of UCPEA coatings on mild steel has been investigated by potentiodynamic polarization measurements in different corrosive environments (3.5 wt% HCl, 5 wt% NaCl, 3.5 wt% NaOH, and tap water at room temperature and surface analysis by scanning electron microscope (SEM and energy dispersive X-ray (EDX. The antibacterial activities of the UCPEA were tested against bacteria and fungi by agar disc diffusion method. The results of this study have revealed that UCPEA nanocomposite coatings exhibit good physicomechanical, anticorrosion and antimicrobial properties, which can be safely used up to 200°C.

  14. Anatomic and tissue characteristics in goats fed for extended periods with residue of castor biodiesel production

    Directory of Open Access Journals (Sweden)

    Cláudio Henrique de Almeida Oliveira

    2013-12-01

    Full Text Available Twenty-five adult crossbred goats, divided in two groups, were fed over a period of 16 months with diets based on Tifton hay and concentrate feed with (DCO or without (WDCO detoxified castor bean meal as a substitute for soybean meal. Throughout 480 days, blood samples were taken to measure lactate dehydrogenase, aspartate aminotransferase, alanine aminotransferase, urea, albumin and creatinine. The animals were euthanized, and the anatomical components (lungs, heart, spleen, liver, kidneys, tongue, empty stomach, empty intestines, omentum, cardiac and renal adipose tissue, carcass and commercial cuts (shoulder, ham, loin, ribs and neck were weighed. Thereafter, an anatomic dissection of the loin was performed, separating the muscle, adipose and bone tissues. On the muscular part of the loin, longissimus dorsi, the proximate composition, fatty acid profile and the expression of SEW-1, IGF-I and IGF-II were analyzed. A higher incidence of bone tissue was observed in the anatomical dissections of the loin and a lower incidence of fat in the proximate composition of the longissimus dorsi of the DCO group compared to the WDCO group (p<0.05. The expression of the IGF-II and SEW-1 genes was higher (p<0.001 for each in the muscle tissue of the DCO animals. Thus, using detoxified castor bean meal for long periods does not produce significant changes in the anatomical composition of the loin or the proximate composition of the longissimus dorsi. However, the differences in gene expression suggest the need for new investigations and care when using this product for animal feeding.

  15. (11) EFFECT OF POWDERED CASTOR BEAN

    African Journals Online (AJOL)

    Adeyinka Odunsi

    Ladoke Akintola University of Technology Ogbomoso, to determine the effects of powdered castor oil seed. (Ricinus communis L.Euphorbiaceae) on kidney, liver, spleen of albino rats. The rats were in five groups, which were replicated three (3) times. The castor oil seed was turned to powdery form using pestle and mortal.

  16. Growth, carcass characteristics, chemical composition and fatty acid profile of the longissimus dorsi muscle in goat kids fed diets with castor oil

    Directory of Open Access Journals (Sweden)

    Michelle de Oliveira Maia

    2012-11-01

    Full Text Available The objective in this study was to determine growth, carcass characteristics, chemical composition and fatty acid profile of the longissimus dorsi of crossbred Boer × Saanen kids fed castor oil. Twenty-four kids (12 males and 12 females were assigned in a randomized complete block design with two treatments and twelve replications. Blocks were defined according to weight, gender and initial age of animals for the evaluation of performance. The experimental treatments consisted of two diets containing 900 g concentrate/kg: a control diet (without addition of oil and another containing castor oil at 30 g/kg (on a dry matter basis. After they reached an average body weight of 25 kg, males were slaughtered for the evaluation of carcass characteristics, chemical composition and fatty acid profile of the longissimus dorsi muscle. The addition of castor oil in the diet did not affect the intake of dry matter, crude protein and neutral detergent fiber; the average daily gain; and feed conversion, but increased the ether extract intake. No difference was observed for the carcass characteristics, chemical composition of the meat, concentration of C18:2 cis-9, trans-11 (CLA and total concentration of saturated, monounsaturated and polyunsaturated fatty acids and their relations; however, there was increase in the concentrations of C18:2 trans-10, cis-12 (CLA and C20:4 ω-6. The addition of castor oil to the diet of crossbred Boer × Saanen kids containing a high content of concentrate did not promote benefit to the characteristics evaluated.

  17. The In Vitro–In Vivo Safety Confirmation of PEG-40 Hydrogenated Castor Oil as a Surfactant for Oral Nanoemulsion Formulation

    Science.gov (United States)

    Rachmawati, Heni; Novel, Miranti Anggraeni; Ayu, Sri; Berlian, Guntur; Tandrasasmita, Olivia Mayasari; Tjandrawinata, Raymond Rubianto; Anggadiredja, Kusnandar

    2017-01-01

    Evaluation on the safety use of high concentration of polyoxyl 40 (PEG-40) hydrogenated castor oil as a surfactant for oral nanoemulsion was performed in Webster mice. As previously reported, nearly 20% of PEG-40 hydrogenated castor oil was used to emulsify the glyceryl monooleate (GMO) as an oil to the aqueous phase. Thermodynamically stable and spontaneous nanoemulsion was formed by the presence of co-surfactant polyethylene glycol 400 (PEG-400). Standard parameters were analyzed for nanoemulsion including particle size and particle size distribution, the surface charge of nanoemulsion, and morphology. To ensure the safety of this nanoemulsion, several cell lines were used for cytotoxicity study. In addition, 5000 mg/kg body weight (BW) of the blank nanoemulsion was given orally to Webster mice once a day for 14 days. Several parameters such as gross anatomy, body weight, and main organs histopathology were observed. In particular, by considering the in vivo data, it is suggested that nanoemulsion composed with a high amount of PEG-40 hydrogenated castor oil is acceptable for oral delivery of active compounds. PMID:28362322

  18. The In Vitro-In Vivo Safety Confirmation of PEG-40 Hydrogenated Castor Oil as a Surfactant for Oral Nanoemulsion Formulation.

    Science.gov (United States)

    Rachmawati, Heni; Novel, Miranti Anggraeni; Ayu, Sri; Berlian, Guntur; Tandrasasmita, Olivia Mayasari; Tjandrawinata, Raymond Rubianto; Anggadiredja, Kusnandar

    2017-03-31

    Evaluation on the safety use of high concentration of polyoxyl 40 (PEG-40) hydrogenated castor oil as a surfactant for oral nanoemulsion was performed in Webster mice. As previously reported, nearly 20% of PEG-40 hydrogenated castor oil was used to emulsify the glyceryl monooleate (GMO) as an oil to the aqueous phase. Thermodynamically stable and spontaneous nanoemulsion was formed by the presence of co-surfactant polyethylene glycol 400 (PEG-400). Standard parameters were analyzed for nanoemulsion including particle size and particle size distribution, the surface charge of nanoemulsion, and morphology. To ensure the safety of this nanoemulsion, several cell lines were used for cytotoxicity study. In addition, 5000 mg/kg body weight (BW) of the blank nanoemulsion was given orally to Webster mice once a day for 14 days. Several parameters such as gross anatomy, body weight, and main organs histopathology were observed. In particular, by considering the in vivo data, it is suggested that nanoemulsion composed with a high amount of PEG-40 hydrogenated castor oil is acceptable for oral delivery of active compounds.

  19. Castor bean response to zinc fertilization

    Energy Technology Data Exchange (ETDEWEB)

    Chaves, Lucia Helena Garofalo; Cunha, Tassio Henrique Cavalcanti da Silva; Lima, Vinicius Mota; Cabral, Paulo Cesar Pinto; Barros Junior, Genival; Lacerda, Rogerio Dantas de [Universidade Federal de Campina Grande (UAEAg/UFCG), PB (Brazil). Unidade Academica de Engenharia Agricola

    2008-07-01

    Zinc is a trace element and it is absolutely essential for the normal healthy growth of plants. This element plays a part of several enzyme systems and other metabolic functions in the plants. Castor beans (Ricinus communis L.) crop is raising attention as an alternative crop for oil and biodiesel production. Despite the mineral fertilization is an important factor for increasing castor beans yield, few researches has been made on this issue, mainly on the use of zinc. In order to evaluate the effects of zinc on growth of this plant an experiment was carried out in a greenhouse, in Campina Grande, Paraiba State, Brazil, from July to December 2007. The substrate for the pot plants was a 6 mm-sieved surface soil (Neossolo Quartzarenico). The experimental design was a completely randomized with three replications. The treatments were composed of five levels of Zn (0; 2; 4; 6 and 8 mg dm{sup -3}), which were applied at the time of planting. One plant of castor bean, cultivar BRS 188 - Paraguacu, was grown per pot after thinning and was irrigated whenever necessary. Data on plant height, number and length of leaves and stem diameter were measured at 21, 34, 77 and 103 days after planting. Under conditions that the experiment was carried out the results showed that the Zn levels used, did not affect the castor bean plants growth. (author)

  20. Study of castor oil polyurethane - poly(methyl methacrylate) semi-interpenetrating polymer network (SIPN) reaction parameters using a 2³ factorial experimental design

    OpenAIRE

    Fernanda Oliveira Vieira da Cunha; Diogo Henrique Roesler Melo; Vinicius Bassanesi Veronese; Maria Madalena de Camargo Forte

    2004-01-01

    In this work was employed a 2³ factorial experiment design to evaluate the castor oil polyurethane-poly(methyl methacrylate) semi-IPN synthesis. The reaction parameters used as independent variables were NCO/OH molar ratio, polyurethane polymerization time and methyl methacrylate (MMA) content. The semi-IPNs were cured over 28 h using two thermal treatments. The polymers were characterized by infrared and Raman spectroscopy, thermal analysis and swelling profiles in n-hexane. The glass transi...

  1. Current progress towards the metabolic engineering of plant seed oil for hydroxy fatty acids production.

    Science.gov (United States)

    Lee, Kyeong-Ryeol; Chen, Grace Q; Kim, Hyun Uk

    2015-04-01

    Hydroxy fatty acids produced in plant seed oil are important industrial material. This review focuses on the use of metabolic engineering approaches for the production of hydroxy fatty acids in transgenic plants. Vegetable oil is not only edible but can also be used for industrial purposes. The industrial demand for vegetable oil will increase with the continued depletion of fossil fuels and ensuing environmental issues such as climate change, caused by increased carbon dioxide in the air. Some plants accumulate high levels of unusual fatty acids in their seeds, and these fatty acids (FAs) have properties that make them suitable for industrial applications. Hydroxy fatty acids (HFAs) are some of the most important of these industrial FAs. Castor oil is the conventional source of HFA. However, due to the presence of toxin ricin in its seeds, castor is not cultivated on a large scale. Lesquerella is another HFA accumulator and is currently being developed as a new crop for a safe source of HFAs. The mechanisms of HFA synthesis and accumulation have been extensively studied using castor genes and the model plant Arabidopsis. HFAs accumulated to 17% in the seed oil of Arabidopsis expressing a FA hydroxylase gene from castor (RcFAH12), but its seed oil content and plant growth decreased. When RcFAH12 gene was coexpressed with additional castor gene(s) in Arabidopsis, ~30% HFAs were accumulated and the seed oil content and plant growth was almost restored to the wild-type level. Further advancement of our understanding of pathways, genes and regulatory mechanisms underlying synthesis and accumulation of HFAs is essential to developing and implementing effective genetic approaches for enhancing HFA production in oilseeds.

  2. Metal concentration in plant tissues of Ricinus communis L. (Castor oil)

    African Journals Online (AJOL)

    SLO) contaminated soil at concentrations of 1-6% (w/w, oil/soil). Plant height and stem girth were depressed by spent lubricating oil at concentrations of 2% (w/w) and above. One percent (1%) spent lubricating oil in soil promoted growth of ...

  3. Analysis of the gamma radiation effects in the composite of polyurethane derived from castor oil and natural fibers; Analise dos efeitos da radiacao gama no composito de poliuretano derivado de mamona com serragem

    Energy Technology Data Exchange (ETDEWEB)

    Kienen, Victor D.; Todt, Matheus L.; Capellari, Giovanni S.; Azevedo, Elaine C. [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil); Neto, Salvador C. [Universidade de Sao Paulo (IQSC/USP), Sao Carlos, SP (Brazil)

    2015-07-01

    Composite of Polyurethane derived from castor oil and natural fibers are obtained from renewable raw material, low cost, and for not assaulting nature. This paper analyzes the effects of gamma radiation on composite polyurethane derived from castor with sawdust irradiated with gamma radiation of 25 kGy . It was held from 3 tips bending tests and micrograph by scanning electron microscopy. The results indicate that gamma radiation decreases the breakdown voltage and the micrograph of the fracture indicates brittle fracture occurred. (author)

  4. Numerical and experimental study of the slug-flow regime in a mixture of castor and paraffin oils in a T-type microchannel

    Science.gov (United States)

    Minakov, A. V.; Shebeleva, A. A.; Yagodnitsyna, A. A.; Kovalev, A. V.; Bilsky, A. V.

    2017-09-01

    The slow-flug regime in a mixture of castor and paraffin oils in a T-type microchannel with crosssectional dimensions of 200 × 400 μm has been studied by numerical and experimental methods. The domain of existence of the slow-flug regime in this system has been determined. Dependence of the paraffin-oil slug length on the ratio of flow rates of the mixture components is established. Comparison of the calculated and experimental data shows their good agreement.

  5. Synthesis and characterisation of simultaneous interpenetrating polymer networks (SIN formed by polystyrene and polyurethane obtained from castor oil and cassava starch polyol-suspensions

    Directory of Open Access Journals (Sweden)

    Juan Manuel Cabrera Anaya

    2011-01-01

    Full Text Available Castor oil was modified by transesterification with pentaerythritol and cassava starch was subsequently incorporated into this oil (oil modified by incorporating starch is called a polyol-suspension. Polyurethane/polystyrene SINs (simulta- neously produced IPNs were synthesised from them and styrene. Reactants used in the synthesis were MDI (methylene diphenyl diisocyanate as diisocyanate, DVB (divinylbenzene as crosslinking agent for polystyrene, dibutylamine as redox primer and benzoyl peroxide as styrene polymerisation primer. The variables considered in SIN synthesis were percentage weight ratio used in the modification (1.32%; 2.64% and 5.28% to increase polyol hydroxyl functionality, starch species incorporated into polyol (Brazilian, Venezuelan and commercial to vary the amount of amylopectin within the polyol-suspension, diisocyanate/hydroxyl NCO/OH (0.85 and 1 functional groups’ molar ratio and polyurethane/ polystyrene PU/PS weight ratio (70/30 and 80/20. A wide range of materials was obtained and characterised by tensile strength, hardness, chemical attack and Soxhlet extraction. The physical-mechanical properties of the materials produced with polyols (transesterified castor oil were improved when starch was incorporated into the polyol. Several tests indicated that 24 hours as curing time were not enough, because the SINs showed lower physical-mechanical properties than the homologous polyurethane elastomers did; thus, the curing time had to be increased to 48 hours.

  6. Experimental evaluation of the performance and emissions of diesel engines using blends of crude castor oil and diesel; Avaliacao experimental do desempenho e emissoes de motores diesel usando misturas de oleo de mamona e oleo diesel

    Energy Technology Data Exchange (ETDEWEB)

    Pimentel, Valeria Said de Barros; Pereira, Pedro Paulo [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Dept. de Engenharia Mecanica; Belchior, Carlos Rodrigues Pereira [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Dept. de Engenharia Oceanica

    2004-07-01

    This work refers to the experimental evaluation of diesel generators operating with blend of crude castor oil and diesel. Performance and emissions tests were accomplished in a diesel engine of direct injection. Because of the high viscosity of the blend a device was installed on the engine in order to lower the blend viscosity. A comprehensive analysis of the results obtained in these tests indicates the possibility of use of the blend of castor oil and diesel as fuel for diesel-generators, with modifications introduced in the engines. (author)

  7. Growth and production of tomato fertilized with ash and castor cake and under varying water depths, cultivated in organic potponics

    Directory of Open Access Journals (Sweden)

    Daniela Pinto Gomes

    2017-04-01

    Full Text Available Two experiments were performed to evaluate the effect of ash (40, 80, and 120 g per plant, castor cake (140 and 280 g per plant and water depth (135, 165, 191, and 213 mm on the growth and production of organic tomato cultivated in pots in a greenhouse. The experimental design was randomized blocks, and the irrigation was managed using an automatic irrigation device. The following variables were evaluated: plant heights, numbers of leaves, bunches, flowers and fruits, total mass of fruits, mass of marketable fruits, mass of fruits with blossom-end rot, total diameter of fruits, and diameter of marketable fruits. Most of the growth variables showed gains with the application of 140 g of ash and 280 g of cake. The dose of 280 g of castor cake was responsible for the greatest mass of marketable fruits (1.78 kg per plant, regardless of the ash dose. The water deficit reduced values of most of the variables of growth and production. The irrigation depth of 213 mm was responsible for the greatest mass of marketable fruits (4.04 kg per plant. The highest water use efficiencies, 37.00 and 37.93 kg m-3, were observed at irrigation depths of 191 and 213 mm, respectively.

  8. Propriedades mecânicas do cimento ósseo e da poliuretana de mamona com e sem catalisador Mechanical properties of bone cement and castor oil-based polyurethane with and without a catalyst

    Directory of Open Access Journals (Sweden)

    A.F.M. Lima

    2008-10-01

    Full Text Available Avaliou-se o comportamento mecânico do polímero de mamona, tendo por variáveis o tempo de produção e a presença de catalisador, e utilizando como padrão comparativo o cimento ósseo (polimetilmetacrilato. Foram estabelecidos três grupos experimentais, de acordo com o tipo de corpo de prova (cilindro ou barra e polímero utilizado, que foram posteriormente subdivididos em subgrupos conforme o tempo após produção, ou seja, 24, 48 e 72 horas. O ensaio de compressão analisou a carga máxima e a tensão e o ensaio de dobramento estudou o módulo de dobramento e a resistência. Estatisticamente não houve diferenças nos valores de resistência à compressão ou ao dobramento às 24, 48 e 72 horas após a produção do polimetilmetacrilato e da poliuretana, com ou sem catalisador. A poliuretana com catalisador foi a mais resistente nos ensaios de compressão, apresentando módulo de dobramento semelhante ao do polimetilmetacrilato e resistência ao dobramento superior à da poliuretana sem catalisador. Conclui-se que: o tempo não alterou as propriedades mecânicas dos compósitos avaliados; o catalisador melhorou o desempenho mecânico da poliuretana de mamona; na resistência mecânica à compressão, a poliuretana com catalisador suportou mais carga que o polimetilmetacrilato.The mechanical properties of castor oil-based polyurethane was evaluated considering post-production time and the presence of a catalyst as variables and using bone cement (polymethylmetacrylate as a comparative pattern. According to proof body type (cylinders or bars and the used polymer, three experimental groups were established. Such groups were later subdivided according to post-production time, namely, 24, 48, and 72 hours. A compression assay analyzed maximum load and tension, and a folding assay evaluated the folding module and resistance. There were no statistical differences in the values for resistance to compression or folding at 24, 48, and 72 hours

  9. Energy flow in castor bean (Ricinus communis L. production systems Fluxos de energia em sistemas de produção de mamona (Ricinus communis L.

    Directory of Open Access Journals (Sweden)

    Adilson Nunes da Silva

    2010-12-01

    Full Text Available Although energy analysis is a way to evaluate the sustainability of production systems, this practice is not often used in the agribusiness. In this context, the castor bean (Ricinus communis L is an agricultural crop not yet well studied despite its great potential in the Brazilian energetic scenario. This article aimed to evaluate the productive potential of the castor bean oil, using an energetic view applied to two management systems: low (System 1 and medium (System 2 technologies. The quantification of the used material fluxes was made converting these factors in energy units. The input energy fluxes were 3,170.6 MJ ha¹ and 10,366.0 MJ ha¹ for Systems 1 and 2, respectively. The energy balance of System 1 was 11,938.2 MJ ha¹ and that of System 2 16,296.5 MJ ha¹. The net energetic gain or the energy gain over the invested energy (EROI of System 1 was 3.8 and of System 2, 2.6. Although presenting a greater energy demand and a lower EROI, System 2 had a greater energy balance, demonstrating a better viability of this cultivation system for the production of castor bean oil.A análise energética é uma forma de se avaliar a sustentabilidade de um sistema produtivo, apesar de ainda pouco utilizada no setor agropecuário. Inserida neste setor encontra-se a produção da mamoneira (Ricinus communis L., cultura ainda pouco estudada e que apresenta grande importância para o agronegócio brasileiro. Avaliou-se sob a ótica energética a produção potencial de óleo de mamona em dois sistemas de cultivo: com baixa (Sistema 1 e média (Sistema 2 tecnologias. Foi realizada a quantificação dos fluxos de materiais empregados nos dois sistemas de produção e conversão destes fatores em unidades de energia. Os fluxos de energia de entrada foram de 3.170,6 MJ ha¹ e 10.366 MJ ha¹ para os sistemas 1 e 2, respectivamente. O balanço de energia foi de 11.938,2 MJ ha¹ no sistema 1 e 16.296,5 MJ ha¹ no sistema 2. A lucratividade energética, retorno

  10. Proposition to use 'in natura' vegetable oil and biodiesel from castor oil in thermal power plants; Proposicao de uso de oleo vegetal in natura e biodiesel de mamona em termeletricas

    Energy Technology Data Exchange (ETDEWEB)

    Soares, B.F.; Tahan, C.M.V.; Pelegrini, M.A.; Polizel, L.H. [Universidade de Sao Paulo (ENERQ/USP), SP (Brazil). Centro de Estudo em Regulacao e Qualidade de Energia; Vandelli, M.V.M. [Termocabo Ltda., Recife, PE (Brazil); Takeno, H.K. [Companhia Energetica de Petrolina (CEP), PE (Brazil)

    2006-07-01

    This paper proposes the adoption of renewable fuels on thermal power plants using diesel or high sulfur fuel oil generator sets. The renewable fuels proposed to partially or fully replace the fossil fuels are castor oil in natura or transesterified (biodiesel). Physical and chemical analyses were carried out on laboratory, establishing the energetic performance of each sample. The results showed that mixtures of bio diesel-fossil fuel offers similar performance when compared to the conventional fuels, allowing its use on thermal power plants in a satisfactory basis. (author)

  11. Exogenous glutamine increases lipid accumulation in developing seeds of castor bean (Ricinus communis L. cultured in vitro

    Directory of Open Access Journals (Sweden)

    Zhang Yang

    2015-01-01

    Full Text Available This report describes biomass production and compositional changes of developing castor seeds in response to change in the nitrogen resource (glutamine of the medium. During the early developmental period (24-36 days after pollination, oil was found to initially accumulate in the developing seeds. Carbohydrates and oil were inversely related after glutamine provision (35 mM, in the culture medium. [U-14C] sucrose labeling was used to investigate the effect of metabolic fluxes among different storage materials. Addition of glutamine led to a 7% increase of labeling in lipids and an inverse decrease of labeling in carbohydrates. It was postulated that changes in the glutamine concentration in the medium are likely to influence the partitioning of resources between the various storage products, especially carbohydrates and oil. These observations will contribute to a better understanding of assimilate partitioning in developing castor seeds and the development of molecular strategies to improve castor bean seed quality and plant breeding studies.

  12. An analysis of expressed sequence tags of developing castor endosperm using a full-length cDNA library

    Directory of Open Access Journals (Sweden)

    Wallis James G

    2007-07-01

    Full Text Available Abstract Background Castor seeds are a major source for ricinoleate, an important industrial raw material. Genomics studies of castor plant will provide critical information for understanding seed metabolism, for effectively engineering ricinoleate production in transgenic oilseeds, or for genetically improving castor plants by eliminating toxic and allergic proteins in seeds. Results Full-length cDNAs are useful resources in annotating genes and in providing functional analysis of genes and their products. We constructed a full-length cDNA library from developing castor endosperm, and obtained 4,720 ESTs from 5'-ends of the cDNA clones representing 1,908 unique sequences. The most abundant transcripts are genes encoding storage proteins, ricin, agglutinin and oleosins. Several other sequences are also very numerous, including two acidic triacylglycerol lipases, and the oleate hydroxylase (FAH12 gene that is responsible for ricinoleate biosynthesis. The role(s of the lipases in developing castor seeds are not clear, and co-expressing of a lipase and the FAH12 did not result in significant changes in hydroxy fatty acid accumulation in transgenic Arabidopsis seeds. Only one oleate desaturase (FAD2 gene was identified in our cDNA sequences. Sequence and functional analyses of the castor FAD2 were carried out since it had not been characterized previously. Overexpression of castor FAD2 in a FAH12-expressing Arabidopsis line resulted in decreased accumulation of hydroxy fatty acids in transgenic seeds. Conclusion Our results suggest that transcriptional regulation of FAD2 and FAH12 genes maybe one of the mechanisms that contribute to a high level of ricinoleate accumulation in castor endosperm. The full-length cDNA library will be used to search for additional genes that affect ricinoleate accumulation in seed oils. Our EST sequences will also be useful to annotate the castor genome, which whole sequence is being generated by shotgun sequencing at

  13. Productive performance and efficiency of utilization of the diet components in dairy cows fed castor meal treated with calcium oxide

    Directory of Open Access Journals (Sweden)

    Juliana Variz Cobianchi

    2012-10-01

    Full Text Available The effect of replacing of 0; 0.33; 0.67 and 1.0 (kg/kg of soybean meal (SBM by undecorticated castor seed meal treated with calcium oxide (CMT - 60 g/kg was evaluated on performance and efficiency of nutrient utilization in dairy cows. Sixteen Holstein and crossbred cows were distributed in four 4 × 4 latin squares. Animals received concentrated feed at a ratio of 1 kg for 3 kg of milk produced, in the natural matter. The diets had the same amount of nitrogen (150.4 g crude protein/kg DM, containing 325.6 g of concentrated feed/kg DM. There was no effect on the serum concentration of transaminase and the animals showed no clinical symptoms of intoxication by ricin. The intake of DM, crude protein (CP and non-fibrous carbohydrates (NFC reduced from 0.67 replacement of SBM by CMT. The intake of neutral detergent fibers corrected for ash and protein (NDFap increased from 0.33 replacement of SBM with CMT. Although the digestibility of dietary components decreased from 0.33 replacement, the intake of digestible components only reduced from 0.67 replacement. Because of the reduction of digestible energy, the synthesis of microbial CP and the utilization efficiency of rumen-degradable protein for the synthesis of microbial CP reduced with full replacement of SBM by CMT. Milk yield, milk composition, daily variation of body weight and the efficiency of utilization of the nutrients for the synthesis of N in milk reduced from 0.67 replacement of SBM by CMT. Castor seed meal treated with calcium oxide can replace up to 0.33 of SBM (50 g/kg DM diet DM in the diet of dairy cows with an average milk production of 20 kg/day.

  14. Study of castor oil polyurethane - poly(methyl methacrylate semi-interpenetrating polymer network (SIPN reaction parameters using a 2³ factorial experimental design

    Directory of Open Access Journals (Sweden)

    Fernanda Oliveira Vieira da Cunha

    2004-12-01

    Full Text Available In this work was employed a 2³ factorial experiment design to evaluate the castor oil polyurethane-poly(methyl methacrylate semi-IPN synthesis. The reaction parameters used as independent variables were NCO/OH molar ratio, polyurethane polymerization time and methyl methacrylate (MMA content. The semi-IPNs were cured over 28 h using two thermal treatments. The polymers were characterized by infrared and Raman spectroscopy, thermal analysis and swelling profiles in n-hexane. The glass transition temperature (Tg and the swelling were more affect by the NCO/OH molar ratio variation. The semi-IPNs showed Tg from - 27 to - 6 °C and the swelling range was from 3 to 22%, according to the crosslink density. The IPN mechanical properties were dependent on the cure temperature and MMA content in it. Lower elastic modulus values were observed in IPNs cured at room temperature.

  15. Dirt-binding particles consisting of hydrogenated castor oil beads constitute a nonirritating alternative for abrasive cleaning of recalcitrant oily skin contamination in a three-step programme of occupational skin protection.

    Science.gov (United States)

    Mahler, V; Erfurt-Berge, C; Schiemann, S; Michael, S; Egloffstein, A; Kuss, O

    2010-04-01

    In occupational fields with exposure to grease, oil, metal particles, coal, black lead or soot, cleansing formulations containing abrasive bodies (e.g. refined walnut shell, corn, wood, plastic or pumice) are used. These may constitute an irritant per se. As an alternative, hydrogenated castor oil (also known as castor wax) beads have been developed as dirt-binding particles. A polar surface contributes to their mechanical cleaning effects in removal of oily grime. Standardized examination of the in vivo effects upon the skin barrier of castor wax beads in comparison with abrasive bodies and pure detergent. Three cleansing preparations - (i) detergent, (ii) detergent containing castor wax beads, (iii) detergent containing walnut shell powder - were each repetitively applied in vivo (four times daily for 3 weeks), mimicking workplace conditions, in 30 healthy volunteers (15 with and 15 without an atopic skin diathesis) and compared vs. (iv) no treatment. The treatment effects upon the skin barrier were monitored by repeated measurements of functional parameters [transepidermal water loss (TEWL), redness] and surface topography. After a 3-week treatment, a significant global treatment effect (P oily skin contamination appropriate for individuals with an atopic skin diathesis in a three-step programme of occupational skin protection. As the skin barrier may additionally be influenced by the composition of dirt and use of skin protection and skin care measures under real workplace conditions, this component may now be used and examined further in different occupations.

  16. Industrial uses of vegetable oils

    National Research Council Canada - National Science Library

    Erhan, Sevim Z

    2005-01-01

    ..., cotton, sunflower, flax, and rape. Although a major part of these oils are used for food products such as shortenings, salad and cooking oils and margarines, large quantities serve feed and industrial applications. Other vegetable oils widely used industrially include palm, palm kernel, coconut, castor, and tung. However, these are not of domestic or...

  17. Feeding behavior of finishing goats fed diets containing detoxified castor meal, co-product of the biodiesel industry.

    Science.gov (United States)

    Palmieri, Adriana Dantas; de Carvalho, Gleidson Giordano Pinto; Tosto, Manuela Silva Libânio; Leite, Vagner Maximino; Santos, Stefanie Alvarenga; Borja, Máikal Souza; Azevêdo, José Augusto Gomes; Júnior, José Esler Freitas; Leite, Laudi Cunha; de Almeida Rufino, Luana Marta

    2017-02-01

    An investigation was made into the feeding behavior of goats to evaluate the effects of a detoxified castor bean meal in the diet of goats. Thirty-six ½ crossbred Boer goats were used, with an average weight of 20 ± 3.2 kg. A completely randomized design was used with four treatments (diets with of 0, 100, 200, and 300 g detoxified castor bean meals/kg dry matter) and nine replicates. Castor bean meal was detoxified using calcium oxide. Diets were formulated to be isonitrogenous, and the forage:concentrate ratio was 50:50. The feeding behavior was observed on the 17th, 45th, and 70th days of the experiment. For the evaluation of feeding behavior (feeding, idle, and rumination times), the animals were observed in 5-min intervals for 24 h. The addition of detoxified castor bean meal did not change (P > 0.05) the evaluated behavioral variables. Linear reduction was observed (P goats did not change (P > 0.05) with the inclusion of detoxified castor bean meal. The inclusion of detoxified castor bean meal in growing goats' diets does not change the feeding, rumination, and idle times, however, decreases intake, feeding, and rumination efficiencies of dry matter.

  18. Analysing oil-production subsidies

    Science.gov (United States)

    Steenblik, Ronald

    2017-11-01

    Understanding how subsidies affect fossil-fuel investment returns and production is crucial to commencing new reforms. New analysis on the impact of subsidies on US crude-oil producers finds that, at recent oil prices of around US50 per barrel, tax preferences and other subsidies push nearly half of new oil investments into profitability.

  19. Estratégias de irrigação com água salina na mamoneira Irrigation strategies with saline water in castor oil plant

    Directory of Open Access Journals (Sweden)

    Maria Eugênia da Costa

    2013-03-01

    Full Text Available Este experimento foi realizado em campo para avaliar estratégias de irrigação com água salina no crescimento e na produção da mamoneira (BRS Energia, além de identificar eventuais estádios de maior tolerância à salinidade e monitorar alguns atributos químicos do solo. Os tratamentos consistiram da irrigação com águas de CE 0,53; 2,09; 3,66 dS m-1 de acordo com a fase de desenvolvimento da cultura, totalizando cinco estratégias de irrigação com água salina e uma testemunha. As avaliações de crescimento foram realizadas aos 20; 40; 60; 80; 100 dias após a semeadura (DAS. As coletas de solo foram realizadas concomitantemente às avaliações de crescimento, nas camadas 0-0,10; 0,10-0,30; 0,30-0,50 m. A irrigação contínua com água de CE 3,66 dS m-1 reduziu a altura de planta, o comprimento de racemo terciário, o número de frutos por área útil e a produtividade de frutos. Essa estratégia aumentou acentuadamente os teores de Na+ e a CE do solo no final do ciclo. Por outro lado, a irrigação com água salina começando aos 45 DAS não prejudicou as variáveis de crescimento e os componentes de produção. Essa estratégia minimizou os impactos negativos sobre a salinidade/sodicidade do solo no final do ciclo. Comportamento similar foi observado para a irrigação contínua com água de CE 2,09 dS m-1 (mistura de águas com CE de 0,53 e 3,66 dS m-1. A mamoneira não apresentou tolerância diferenciada à salinidade em função da fase de desenvolvimento, embora tenha sido prejudicada quando aumentaram a intensidade e a duração do estresse salino.This experiment was conducted under field conditions to evaluate irrigation strategies with saline water on growth and production of castor oil plant (cv. BRS Energia, identify eventual stages with higher tolerance to salinity and monitor some soil chemical attributes. The treatments consisted of irrigations with water of EC 0.53; 2.09; 3.66 dS m-1 according to the development

  20. Registration of Crop Varieties A Unique Purple Castor (Racinnus ...

    African Journals Online (AJOL)

    The genetic variability of castor in terms of plant height, branching, leaf color, leaf size, leaf waxiness, leaf indentation, stem thickness, branching, inflorescence height, femaleness, stem color, seed color, seed size and oil content is tremendous. Castor is also cross pollinating species suited to hybrid variety development.

  1. Low density polyethylene (LDPE) / poli (3-hydroxy-butyrate) (PHB) blends filled with castor oil cake; Misturas de polietileno de baixa densidade (PEBD) e poli(3-hidroxibutirato) (PHB) carregados com torta de mamona (TM)

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, M.C.G.; Oliveira, C.I.R. de; Sanches, M.C.; Coelho, N.N., E-mail: mrocha@iprj.uerj.br [Universidade do Estado do Rio de Janeiro (IP/UERJ), Rio de Janeiro, RJ (Brazil). Instituto Politecnico

    2014-07-01

    Blends of PHB and LDPE were prepared by melt mixing in a Haake internal mixer. Castor oil pressed cake was used as filler for the blends. In order to improve the interfacial adhesion between the filler and the polymers, a mercerization process with 5% NaOH solution was employed. This process was evaluated by several techniques such as: X-Ray diffraction, infrared spectroscopy and scanning electron microscopy (SEM). The mechanical properties were evaluated by traditional tensile stress-strain tests (ASTM D- 638). The obtained results showed that the mercerization process leads to better adhesion properties. The Young Modulus of the blends presented a tendency to increase with the addition of the castor oil cake.(author)

  2. CASTOR BEAN AND SUNFLOWER INTERCROPPING SYSTEMS IN ROW ARRANGEMENT: BIOLOGICAL EFFICIENCY

    Directory of Open Access Journals (Sweden)

    Ciro de Miranda Pinto

    2012-07-01

    Full Text Available An experiment field was carried in the agricultural seasons 2008, 2009 and 2010, with aim of studying the response of castorbean (Ricinus communis L. intercropping with sunflower (Helianthus annus L. in row arrangement in the dryland farming conditions. In addition, it was evaluated the biological efficiency of plants in intercropping systems.The design used in the experiment was randomized block with seven treatement and four replications. The treatments were represented by rows of castor oil (Ma and sunflower (Gi listed below: 1Ma:1Gi; 1Ma:2Gi; 1Ma:3Gi; 2Ma:2Gi; 2Ma:3Gi; castor and sunflower in the monoculture. The efficiency of intercropping was measured by LER, ATER, LEC, average between LER and ATER, SPI and CoR. The grain yield of castor bean and sunflower were reduced in intercropped row arrangements. The row arrangement 1Ma:2Gi showed the smallest reduction of average productivity of castor beans and sunflower in the evaluation period of the experiment. The castor bean was the dominant crop in relation to sunflower.

  3. Characterization of adhesive of polyurethane from castor oil by FTIR, TGA and XRD;Caracterizacao de adesivo de poliuretano derivado do oleo de mamona por FTIR, TGA e XRD

    Energy Technology Data Exchange (ETDEWEB)

    Azevedo, Elaine C.; Santana, Simone S. de M.; Nascimento, Eduardo M. do, E-mail: elainazeve@utfpr.edu.b [Universidade Tecnologia Federal do Parana (UTFPR), Curitiba, PR (Brazil); Claro Neto, Salvador [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil); Lepienski, Carlos M. [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil)

    2009-07-01

    Castor oil polyurethanes are an alternative to adhesives that emanate volatile compounds. This adhesive come from a renewable source and has very low toxicity. In this work the microstructural and thermal characterization is presented. This material is partially crystalline. The mass loss start at 240 deg C and the glass transition temperature is 60 deg C. Then the adhesive is adequate to be employed at temperatures lower than 60 deg C. (author)

  4. SUBACUTE AND MULTIGENERATIONAL TOXICITY EVALUATION OF CASTOR OIL POLYMER INGESTION IN RATS AVALIAÇÃO DA TOXICIDADE SUBAGUDA E MULTIGERACIONAL DA INGESTÃO DE DERIVADO DO POLÍMERO DE MAMONA EM RATOS

    Directory of Open Access Journals (Sweden)

    Gilberto Chierice

    2009-04-01

    Full Text Available Castor oil polymer is a biomaterial that can be used to fill bone defects. Biomaterials should present some characteristics such as: biocompatibility, inert, absence of toxin radical and vapour discharge and permit the organism to recognize them as a part of their structure. The aim of this study was to investigate changes in water ingestion, feed intake, weight gain and toxic effects in rats (Rattus norvegicus after ingestion of 0, 10, 25 and 50% of castor oil polymer (COP, Ricinus communis. In groups that received 10 and 25% of COP the weight gain was smaller than the control group. Feed intake in control group was greater than in groups 10 and 50% COP. The intake of castor oil polymer reduced feed intake and water ingest probably because of the palatability of the product. In the second part of this study (multigenerational there were no toxic effects in the offspring, as external birth defects or alterations incompatible with life, in spite of the fact that lower weight were observed in males and females of the second generation.

    KEY WORDS: Biomaterials, bone defects, polymer, Ricinus communis. Os biomateriais são polímeros artificiais desenvolvidos para substituir tecidos orgânicos danificados e preencherem falhas ósseas. Eles devem apresentar características como a biocompatibilidade, serem inertes, não liberarem vapores e radicais tóxicos e permitirem ao organismo reconhecê-los como parte de sua estrutura. Procurou-se determinar a ingestão de água, o consumo de ração, ganho de peso e possível efeito tóxico decorrentes da ingestão de três doses (10%, 25% e 50% do derivado do polímero de mamona (PM, Ricinus communis, adicionado à água de bebida, em ratos (Rattus norvegicus. Nos grupos que receberam 10% e 25% do PM, o ganho de peso foi menor (P?0,05, quando comparado ao grupo-controle. O consumo de ração nos grupos que receberam 10% e 50% de PM foi menor em relação ao grupo-controle. A ingestão do pol

  5. Phytotoxicity of three plant-based biodiesels, unmodified castor oil, and Diesel fuel to alfalfa (Medicago sativa L.), lettuce (Lactuca sativa L.), radish (Raphanus sativus), and wheatgrass (Triticum aestivum).

    Science.gov (United States)

    Bamgbose, Ifeoluwa; Anderson, Todd A

    2015-12-01

    The wide use of plant-based oils and their derivatives, in particular biodiesel, have increased extensively over the past decade to help alleviate demand for petroleum products and improve the greenhouse gas emissions profile of the transportation sector. Biodiesel is regarded as a clean burning alternative fuel produced from livestock feeds and various vegetable oils. Although in theory these animal and/or plant derived fuels should have less environmental impact in soil based on their simplified composition relative to Diesel, they pose an environmental risk like Diesel at high concentrations when disposed. The aim of the present study was to ascertain the phytotoxicity of three different plant-derived biodiesels relative to conventional Diesel. For phytotoxicological analysis, we used seeds of four crop plants, Medicago sativa, Lactuca sativa, Raphanus sativus, and Triticum aestivum to analyze the germination of seeds in contaminated soil samples. The toxicological experiment was conducted with two different soil textures: sandy loam soil and silt loam soil. The studied plant-based biodiesels were safflower methyl-ester, castor methyl ester, and castor ethyl-ester. Biodiesel toxicity was more evident at high concentrations, affecting the germination and survival of small-seeded plants to a greater extent. Tolerance of plants to the biodiesels varied between plant species and soil textures. With the exception of R. sativus, all plant species were affected and exhibited some sensitivity to the fuels, such as delayed seedling emergence and slow germination (average=10 days) at high soil concentrations (0.85% for Diesel and 1.76% for the biodiesels). Tolerance of plants to soil contamination had a species-specific nature, and on average, decreased in the following order: Raphanus sativus (0-20%)>Triticum aestivum (10-40%) ≥ Medicago sativa> Lactuca sativa (80-100%). Thus, we conclude that there is some phytotoxicity associated with plant-based biodiesels. Further

  6. Environmental emergency in the oil production and oil products transport

    Directory of Open Access Journals (Sweden)

    Jozef Čopan

    2006-10-01

    Full Text Available The paper refers to the experience of the environmental emergency response in the case of accidental leakages of oil or oil products into the environment. The gained experience is demonstrated on four different sites where the remediation of contaminated soil / groundwater and emergency response were carried out by the Czech environmental company DEKONTA a.s.

  7. Biotechnology for improved hHydroxy fatty acid production in oilseed lesquerella

    Science.gov (United States)

    The conventional source of hydroxy fatty acid (HFA) is from castor (Ricinus communis), 90% of castor oil is ricinoleic acid (18:1OH). Ricinoleic acid and its derivatives are used as raw materials for numerous industrial products, such as lubricants, plasticizers and surfactants. The production of ca...

  8. Effect of copper on castor bean (Ricinus communis L.) growth

    Energy Technology Data Exchange (ETDEWEB)

    Chaves, Lucia Helena Garofalo; Cunha, Tassio Cavalcanti da Silva; Lima, Vinicius Mota; Cabral, Paulo Cesar Pinto; Barros Junior, Genival; Lacerda, Rogerio Dantas de [Universidade Federal de Campina Grande (UAEAg/UFCG), PB (Brazil). Unidade Academica de Engenharia Agricola

    2008-07-01

    Castor beans crop (Ricinus communis L.) is raising attention as an alternative crop for oil and biodiesel production. Despite the mineral fertilization is an important factor for increasing castor yield, few research has been made on this issue, mainly on the use de copper. In order to evaluate the effects of copper on growth of this plant an experiment was carried out in a greenhouse, in Campina Grande, Paraiba State, Brazil, from July to December 2007. The substrate for the pot plants was a 6 mm-sieved surface soil (Neossolo Quartzarenico). The experimental design was a completely randomized with three replications. The treatments were composed of five levels of Cu (0; 1; 2; 3 and 4 mg dm{sup -3}), which were applied at the time of planting. One plant of castor bean, cultivar BRS 188 - Paraguacu, was grown per pot after thinning and was irrigated whenever necessary. Data on plant height, number and length of leaves and stem diameter were measured at 21, 34, 77 and 103 days after planting. Copper levels used, in general, did not affect the plant height, stem diameter and leaf area, however they influenced the leaves and shoot biomass dry mass and the quadratic trend was the best to show the behavior of these. (author)

  9. Biodiesel production from palm oil

    Directory of Open Access Journals (Sweden)

    Kiatsimkul, P.

    2001-11-01

    Full Text Available Methyl ester was produced from many sources of oil palm products, namely used frying oil, RBD palm oil, degummed and deacidified palm oil, palm stearin and superhard palm stearin. Production process was a conventional transesterification batch process using methanol as reactant and sodium hydroxide as catalyst. Production procedure consisted of oil preparation, solvent preparation, reaction step, glycerol separation, washing step and finishing step. Thin layer chromatograph was used to determine the composition of product and nearly 100% methyl ester was obtained at a suitable condition. Molar ratio of oil: methanol was about 1:6, which equal to 20% by weight of methanol. Sodium hydroxide was 0.5-1 %wt. of oil. The production temperature was 60-80ºC, mixing time was only 15-30 minutes and reaction time was 3-4 hours. Many fuel properties of methyl ester were very close to high-speed diesel such as viscosity, density, heating value and boiling point range. Pour point of methyl ester was higher than diesel owing to the high composition of saturated methyl ester that has a high melting point.

  10. Balanço energético para a produção de biodiesel pela cultura da mamona (Ricinus communis L. Energy balance for biodiesel production by the castor bean crop (Ricinus communis L.

    Directory of Open Access Journals (Sweden)

    Rodolfo Glauber Chechetto

    2010-12-01

    Full Text Available A cultura da mamona (Ricinus communis L. adquiriu prestígio ao interesse da indústria pela qualidade de seu óleo e, recentemente, pela busca de novas fontes de energias. O experimento que serviu como base para os dados utilizados nesse trabalho foi realizado na Fazenda Experimental Lageado, FCA - UNESP, no município de Botucatu - SP, no ano de 2008. O objetivo deste trabalho foi avaliar a viabilidade energética da cultura através do balanço e da eficiência energética, desde a implantação até a produção de biodiesel, utilizando parâmetros de consumo operacional no manejo para instalação e manutenção da cultura, colheita e processamento de óleo. As operações de manejo de solo, semeadura e colheita consumiramo total de 266,20 MJ ha-1, que juntamente com fertilizantes, agrotóxicos, combustíveis e lubrificantes, mão-de-obra, sementes e processamento industrial totalizaram uma entrada de energia de 56.808,10 MJ ha-1. A produção de energia foi de 72.814,00 MJ ha-1. O setor ainda carece de estudos que contribuiriam para o levantamento de dados e coeficientes energéticos mais específicos. A cultura da mamona foi considerada eficiente, permitindo ganho de 15.983,44 MJ ha-1, equivalente a aproximadamente 415 L de óleo diesel.The castor bean crop (Ricinus communis L. has acquired prestige due to industries interest in the oil quality and recently for new sources of energy demand. The experiment that served as basis for the data used in this study was conducted at the Lageado Experimental Farm, in Botucatu - SP, 2008. This study aimed to avaluate the crop viability through energy balance and energy efficiency since the implantation until biodiesel production using parameters of consumption in operational management for installation and maintenance of culture harvest and oil production. The soil management operations, sow and harvest consumed the total of 266.20 MJ ha-1, gathering with the fertilizers, pesticides, fuels

  11. Optimization of walnut oil production

    Directory of Open Access Journals (Sweden)

    Stela Jokić

    2014-01-01

    Full Text Available Walnut is recognized worldwide as a functional health food. In the walnut oil production it is very important to find an appropriate method to recover the oil from seeds. Walnut oil in this study was obtained by pressing the seeds followed by extraction with supercritical CO2. The effects of pressing temperature (70, 85, 100 °C, frequency (20, 30, 40 Hz and nozzle size (8, 10, 12 mm in pressing experiments on oil recovery and oil temperature were monitored. The optimal calculated pressing condition within the experimental range of the variables studied was determined. In obtained walnut oil the following parameters were analyzed: peroxide value, free fatty acids, insoluble impurities, moisture content, iodine value, saponification value, p-anisidine value and Totox value. The residual oil from pressed cake obtained at optimal conditions was extracted with CO2 with a goal to extract tocopherols residue from walnut after applied screw press process. Content of tocopherols in walnut oil obtained by pressing and oil extracted by supercritical CO2 were compared.

  12. Castor (Ricinus communis L. and Pigweed (Amaranthus retroflexus L. Growth Indices in Terms of Interference

    Directory of Open Access Journals (Sweden)

    naser jafarzadeh

    2016-11-01

    Full Text Available Introduction Growth analysis has been widely used in breeding programs to identify the important plant developmental phases and components related to higher yield under a particular set of environmental conditions. Castor bean (Ricinus communis L. is an important commercial crop. Castor oil based by products is used in manufacturing of several commercially important commodities like surfactants, coatings, greases, pharmaceuticals, cosmetics, polyesters, polymers, etc. Interference (Interactive effects among species on inter-species populations is one of the main issues on the eco-physiology of plant populations where weeds impose negative effects by approaching the plant to compete in light, water and nutrient elements availability and results in reduced growth and yield (Shinggu et al., 2011. Growth indices are useful for interpreting plant reactions to the crop and weed density. Various reasons have been attributed for the low productivity among the most important is weed competition (Radosevich, 1987. The aim of the present experiment was evaluating the interference effects of redroot pigweed on growth indices of castor bean in northwest of Iran. Materials and methods This experiment was conducted in Urmia, Iran (Agricultural Research of West Azarbayjan, Saatlo Station (37°44´18״ N Latitude and 45° 10´ 53״ E Longitude, at 1338 m above sea level in 2012. The soil of the experimental field was sandy - loam, with pH of 7.2. Competitive pattern of experiment was in two-factor based on a randomized complete block design (RCBD with three replications arranged in four castor plant densities (3, 4, 5 and 6 plants.m-2 and four redroot pigweed densities (0, 5, 10 and 15 plants.m-2. Redroot pigweed and castor seeds were simultaneously directly planted on the 22th May in 2012. Redroot pigweed plants were weeded at the times related to the treatments level. Irrigation and intercultural operations were performed whenever necessary. Plots were 3m×5m

  13. Natural cold pressed oils as cosmetic products

    Directory of Open Access Journals (Sweden)

    Małgorzata Ligęza

    2016-12-01

    Full Text Available Background. It seems that patients may ask general practitioners about natural cosmetics applied on the skin regarding their safety and suitability. Objectives. The aim of the study was to analyze natural cold pressed oils as potential cosmetic products. Material and methods. Cold pressed oils obtained from selected seeds and fruit stones were analyzed, including: chokeberry seed oil, blackcurrant seed oil, elderberry seed oil, raspberry seed oil, apricot seed oil, tomato seed oil, strawberry seed oil, broccoli seed oil, Nigella sativa seed oil, hemp oil, safflower seed oil, Silybum marianum seed oil and coconut oil. 80 adult volunteers assessed the cosmetic properties of the analyzed oils. Each of the volunteers tested 2 to 4 different oils, by applying them on the skin. In addition, patch tests with all analyzed oils were performed on 23 individuals. Results. The majority of tested oils were positively evaluated by the participants: in the opinion of the participants, oil extracted from safflower had the best appearance (100% positive opinions, coconut oil had the best smell (70% positive opinions, while black currant seed oil showed the best absorbency (85% positive opinions. No irritation was observed within the analyzed product group, albeit one allergic reaction to apricot seed oil was observed with patch testing. Conclusions . Based on the achieved results, it could be suggested that natural cold pressed oils can be applied to the skin as cosmetics. Our observations may be helpful for general practitioners when choosing natural cosmetics.

  14. Efeito do óleo de mamona em composições de borracha natural contendo sílica Effects from the castor oil on silica-filled natural rubber compounds

    Directory of Open Access Journals (Sweden)

    Helson M. da Costa

    2004-03-01

    Full Text Available O potencial do óleo de mamona como um ativador para a vulcanização de composições de borracha natural (NR contendo sílica foi investigado. Utilizando-se um planejamento de experimentos adequado, manteve-se a concentração de sílica e outros aditivos constantes enquanto as quantidades de ácido esteárico, óleo de mamona e poli(etileno-glicol foram variadas. A cura foi conduzida em um reômetro de disco oscilatório TI-100 e a variável de controle escolhida foi a resistência à tração. Os resultados demonstraram que o óleo de mamona sozinho não exerce influência considerável sobre o desempenho mecânico da borracha natural em presença de sílica.The possible use of castor oil fatty acid as an activator for the vulcanization reaction in silica-filled natural rubber (NR compounds was investigated. The design and analysis of the experiments were carried out by keeping constant the concentration of silica and the other ingredients while the amounts of stearic acid, castor oil and poly(ethylene glycol were varied. Cure was carried out on a TI-100 oscillating disk rheometer, and the tensile strength was chosen as the control variable. The results show that the addition of castor oil does not significantly change the mechanical performance of silica-filled natural rubber compounds.

  15. Biochar prepared from castor oil cake at different temperatures: A voltammetric study applied for Pb(2+), Cd(2+) and Cu(2+) ions preconcentration.

    Science.gov (United States)

    Kalinke, Cristiane; Mangrich, Antonio Sálvio; Marcolino-Junior, Luiz H; Bergamini, Márcio F

    2016-11-15

    Biochar is a carbonaceous material similar produced by pyrolysis of biomass under oxygen-limited conditions. Pyrolysis temperature is an important parameter that can alters biochar characteristics (e.g. surface area, pore size distribution and surface functional groups) and affects it efficacy for adsorption of several probes. In this work, biochar samples have been prepared from castor oil cake using different temperatures of pyrolysis (200-600°C). For the first time, a voltammetric procedure based on carbon paste modified electrode (CPME) was used to investigate the effect of temperature of pyrolysis on the adsorptive characteristics of biochar for Pb(II), Cd(II) and Cu(II) ions. Besides the electrochemical techniques, several characterizations have been performed to evaluate the physicochemical properties of biochar in function of the increase of the pyrolysis temperature. Results suggest that biochar pyrolized at 400°C (BC400) showed a better potential for ions adsorption. The CPME modified with BC400 showed better relative current signal with adsorption affinity: Pb(II)>Cd(II)>Cu(II). Kinetic studies revealed that the pseudo-second order model describes more accurately the adsorption process suggesting that the surface reactions control the adsorption rate. Values found for amount adsorbed were 15.94±0.09; 4.29±0.13 and 2.38±0.39μgg(-1) for Pb(II), Cd(II) and Cu(II) ions, respectively. Copyright © 2016 Elsevier B.V. All rights reserved.

  16. Determinación de la densidad de entrecruzamiento de poliuretanos obtenidos a partir de aceite de ricino modificado por transesterificación Determination of crosslink density of polyurethanes obtained from castor oil modified by transesterification

    Directory of Open Access Journals (Sweden)

    Manuel F. Valero

    2009-01-01

    Full Text Available Se obtuvo una gama de polioles a partir del aceite de ricino modificado por transesterificación con pentaeritriol y glicerina. Los productos resultantes fueron caracterizados físico-químicamente. Se sintetizaron elastómeros de poliuretano a partir de los polioles derivados del aceite de ricino modificado. La densidad de entrecruzamiento se determinó por ensayos de hinchamiento a partir de la ecuación de Flory-Rehner apoyada en la espectroscopia MALDI TOF MS para determinar la estructura química de la unidad repetitiva promedio del poliuretano. Se estudió la variación de la densidad de entrecruzamiento de los poliuretanos con base en el índice de hidroxilo del poliol utilizado en la síntesis. Los resultados muestran que los PU obtenidos a través de la modificación del aceite con pentaeritriol tienen una mayor densidad de entrecruzamiento que los PU obtenidos a partir del aceite original y de los polioles derivados de la reacción de transesterificación del aceite con glicerina, debido a que estos polioles poseen una mayor funcionalidad hidroxílica.Two series of polyols were obtained from castor oil modified by transesterification with various amounts of pentaerythritol and glycerol. The resultant polyol properties were characterized as a function of the hydroxyl functionality. Polyurethane elastomers (PU were synthesized from the two series of polyols obtained. The crosslink density of those polyurethanes was determined by swelling tests data adjusted to the Flory-Rehner's equation and according to the elasticity theory. The variation of the crosslink density of polyurethanes was studied by following the hydroxyl value of the modified polyol utilized in the synthesis and based on the average structure of each polyurethane repeating unit, as determined by the method of matrix-assisted laser desorption/ionization time-of-flight mass spectroscopy (MALDI TOF MS. The results show that the PU obtained through castor oil modified with

  17. Evaluation gamma radiation in composite sisal fiber- polyurethane derived of castor oil by bending test; Avaliacao da influencia da radiacao gama em compositos de fibra de sisal - poliuretano derivado de oleo de mamona atraves de ensaios de flexao

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Felipe H. de; Geraldo, Ricardo R.; Vasco, Marina C.; Azevedo, Elaine, E-mail: helunica@yahoo.com.br [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil); Claro Neto, Salvador [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil). Instituto de Quimica

    2015-07-01

    Materials used for making furniture and accessories or positioning in X -ray examination rooms should not exhale volatile organic compounds and are resistant to ionizing radiation. One solution is the use of vegetable fiber and polyurethane composites of vegetable origin, since they are biodegradable, derived from renewable raw materials and have no volatile organic compounds. The main difficulty in developing this material is fiber adhesion with the polymer. The objective of this study is to evaluate the mechanical properties of composite sisal fiber composite, without further treatment, and polyurethane derived from castor oil, with a dose of 25 kGy gamma radiation, subjected to 3 points bending tests. (author)

  18. Formulation of soy oil products

    Directory of Open Access Journals (Sweden)

    Woerfel, John B.

    1995-12-01

    Full Text Available The paper comments different formulations of soy oil products such as salad and cooking oils, margarine, shortenings, commercial shortenings, frying shortenings, and fluid shortenings. Hydrogenation and its influence on final products is also included.

    El trabajo presenta diferentes formulaciones a base de aceite de soja tales como aceites para ensalada y cocinado, margarina, grasas sólidas (shortenings, grasas sólidas comerciales, grasas sólidas para frituras y grasas fluidas. Hace también referencia al proceso de hidrogenación y a sus efectos en los productos finales.

  19. Organic matter and soil water content influence on BRS 188 castor bean growth

    Energy Technology Data Exchange (ETDEWEB)

    Lacerda, Rogerio Dantas de; Araujo, Ester Luiz de; Nascimento, Elka Costa Santos; Barros Junior, Genival [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Guerra, Hugo O. Carvallo; Chaves, Lucia Helena G. [Universidade Federal de Campina Grande (UAEAg/UFCG), PB (Brazil). Unidade Academica de Engenharia Agricola

    2008-07-01

    The castor bean culture has been highlighted due to the several applications of its oil, which constitutes one of the best row materials for biodiesel manufacturing, and the base for several other industrial products. The objective of the present work was to study the effect of different soil water and soil organic matter on the castor bean growth. The experiment was conducted from April to August 2006 under greenhouse conditions using a randomized block 2x4 factorial design with two soil organic mater content (5.0 g.kg{sup -1} e 25.0 g.kg{sup -1}), four levels of available water (100, 90, 80 e 70% ) and three replicates. For this, 24 plastic containers, 75 kg capacity, were used on which was grown one plant 120 days after the seedling. At regular intervals the plant height was measured and the results analyzed statistically. For the qualitative treatments (with and without organic matter) the treatment means were compared through the Tukey test. For the quantitative ones (water levels) were used regressions. The castor bean cultivar height was significantly influenced by the organic matter content only after 80 days. Castor bean height increased significantly with the soil water content after 40 days of growing. (author)

  20. Intensification of Tatar oil production

    Energy Technology Data Exchange (ETDEWEB)

    Mannanov, A.

    1984-11-13

    The industrial workers of the Tatneft Order of Lenin Production Association have extracted 250 million tons of oil from the depths of the earth since the beginning of the 11th Five-Year Plan. Especially gratifying is the fact the 2 million tons above the plan have been produced. The Tatar oilmen reached high boundaries by intensifying production, constant research of ways to increase the oil production of fields, capable organization of prospecting-exploration tasks, and accelerated drilling of wells. In less than 4 years, more than 37,000 single technical innovations have been adopted in enterprises of the association. All of this has made it possible to significantly boost labor productivity and lower the prime cost of production.

  1. Simultaneous allergen inactivation and detoxification of castor bean cake by treatment with calcium compounds

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, K.V.; Deus-de-Oliveira, N. [Laboratório de Química e Função de Proteínas e Peptídeos, Centro de Biociências e Biotecnologia, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Rio de Janeiro, RJ (Brazil); Godoy, M.G. [Laboratório de Biotecnologia Microbiana, Instituto de Química, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ (Brazil); Guimarães, Z.A.S. [Laboratório de Biologia Celular e Tecidual, Centro de Biociências e Biotecnologia, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Rio de Janeiro, RJ (Brazil); Nascimento, V.V. [Laboratório de Química e Função de Proteínas e Peptídeos, Centro de Biociências e Biotecnologia, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Rio de Janeiro, RJ (Brazil); Melo, E.J.T. de [Laboratório de Biologia Celular e Tecidual, Centro de Biociências e Biotecnologia, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Rio de Janeiro, RJ (Brazil); Freire, D.M.G. [Laboratório de Biotecnologia Microbiana, Instituto de Química, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ (Brazil); Dansa-Petretski, M.; Machado, O.L.T. [Laboratório de Química e Função de Proteínas e Peptídeos, Centro de Biociências e Biotecnologia, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Rio de Janeiro, RJ (Brazil)

    2012-08-24

    Ricinus communis L. is of great economic importance due to the oil extracted from its seeds. Castor oil has been used for pharmaceutical and industrial applications, as a lubricant or coating agent, as a component of plastic products, as a fungicide or in the synthesis of biodiesel fuels. After oil extraction, a castor cake with a large amount of protein is obtained. However, this by-product cannot be used as animal feed due to the presence of toxic (ricin) and allergenic (2S albumin) proteins. Here, we propose two processes for detoxification and allergen inactivation of the castor cake. In addition, we establish a biological test to detect ricin and validate these detoxification processes. In this test, Vero cells were treated with ricin, and cell death was assessed by cell counting and measurement of lactate dehydrogenase activity. The limit of detection of the Vero cell assay was 10 ng/mL using a concentration of 1.6 × 10{sup 5} cells/well. Solid-state fermentation (SSF) and treatment with calcium compounds were used as cake detoxification processes. For SSF, Aspergillus niger was grown using a castor cake as a substrate, and this cake was analyzed after 24, 48, 72, and 96 h of SSF. Ricin was eliminated after 24 h of SSF treatment. The cake was treated with 4 or 8% Ca(OH){sub 2} or CaO, and both the toxicity and the allergenic properties were entirely abolished. A by-product free of toxicity and allergens was obtained.

  2. Simultaneous allergen inactivation and detoxification of castor bean cake by treatment with calcium compounds

    Directory of Open Access Journals (Sweden)

    K.V. Fernandes

    2012-11-01

    Full Text Available Ricinus communis L. is of great economic importance due to the oil extracted from its seeds. Castor oil has been used for pharmaceutical and industrial applications, as a lubricant or coating agent, as a component of plastic products, as a fungicide or in the synthesis of biodiesel fuels. After oil extraction, a castor cake with a large amount of protein is obtained. However, this by-product cannot be used as animal feed due to the presence of toxic (ricin and allergenic (2S albumin proteins. Here, we propose two processes for detoxification and allergen inactivation of the castor cake. In addition, we establish a biological test to detect ricin and validate these detoxification processes. In this test, Vero cells were treated with ricin, and cell death was assessed by cell counting and measurement of lactate dehydrogenase activity. The limit of detection of the Vero cell assay was 10 ng/mL using a concentration of 1.6 x 10(5 cells/well. Solid-state fermentation (SSF and treatment with calcium compounds were used as cake detoxification processes. For SSF, Aspergillus niger was grown using a castor cake as a substrate, and this cake was analyzed after 24, 48, 72, and 96 h of SSF. Ricin was eliminated after 24 h of SSF treatment. The cake was treated with 4 or 8% Ca(OH2 or CaO, and both the toxicity and the allergenic properties were entirely abolished. A by-product free of toxicity and allergens was obtained.

  3. Simultaneous allergen inactivation and detoxification of castor bean cake by treatment with calcium compounds.

    Science.gov (United States)

    Fernandes, K V; Deus-de-Oliveira, N; Godoy, M G; Guimarães, Z A S; Nascimento, V V; Melo, E J T de; Freire, D M G; Dansa-Petretski, M; Machado, O L T

    2012-11-01

    Ricinus communis L. is of great economic importance due to the oil extracted from its seeds. Castor oil has been used for pharmaceutical and industrial applications, as a lubricant or coating agent, as a component of plastic products, as a fungicide or in the synthesis of biodiesel fuels. After oil extraction, a castor cake with a large amount of protein is obtained. However, this by-product cannot be used as animal feed due to the presence of toxic (ricin) and allergenic (2S albumin) proteins. Here, we propose two processes for detoxification and allergen inactivation of the castor cake. In addition, we establish a biological test to detect ricin and validate these detoxification processes. In this test, Vero cells were treated with ricin, and cell death was assessed by cell counting and measurement of lactate dehydrogenase activity. The limit of detection of the Vero cell assay was 10 ng/mL using a concentration of 1.6 x 10(5) cells/well. Solid-state fermentation (SSF) and treatment with calcium compounds were used as cake detoxification processes. For SSF, Aspergillus niger was grown using a castor cake as a substrate, and this cake was analyzed after 24, 48, 72, and 96 h of SSF. Ricin was eliminated after 24 h of SSF treatment. The cake was treated with 4 or 8% Ca(OH)2 or CaO, and both the toxicity and the allergenic properties were entirely abolished. A by-product free of toxicity and allergens was obtained.

  4. Production of biodiesel from Jatropha oil (Curcas Oil) | Oladeji ...

    African Journals Online (AJOL)

    This work deals with the production of Biodiesel from Jatropha oil also known as Curcas oil. Material used for the production was sourced for locally. Basic test for the suitability of the Jatropha oil was carried out in the lab. The test carried out to determine if the produced Biodiesel met standards set was carried out at the ...

  5. Production of pyrolysis oil

    OpenAIRE

    2011-01-01

    Methods for fractional catalytic pyrolysis which allow for conversion of biomass into a slate of desired products without the need for post-pyrolysis separation are described. The methods involve use of a fluid catalytic bed which is maintained at a suitable pyrolysis temperature. Biomass is added to the catalytic bed, preferably while entrained in a non-reactive gas such as nitrogen, causing the biomass to become pyrolyzed and forming the desired products in vapor and gas forms, allowing the...

  6. Experimental and empirical study of diesel and castor biodiesel blending effect, on kinematic viscosity, density and calorific value

    Directory of Open Access Journals (Sweden)

    A. Amin

    2016-12-01

    Full Text Available This study aimed to investigate the fuel properties like density, viscosity and calorific value of trans-esterified methyl ester using castor biodiesel and their blends with No. 2 diesel. Empirical correlations are proposed to predict the kinematic viscosity, density, and calorific value for a mixture of castor oil and No. 2 diesel. Kay mixing rule shows a good prediction for the fuel properties under study. Several polynomials are fitted using least square method, and the fitted equations show a good agreement with the experimental data from our study. The developed equations could be used as universal formulas to predict the kinematic viscosity, density, and calorific value for castor oil and No. 2 diesel blend. The equations can be used to optimize the mixing ratio of the castor oil/No. 2 diesel for different applications. Blending of castor oil with No. 2 diesel- in the range of 20% castor oil, will not violate the required specification of diesel engines.

  7. Water issues associated with heavy oil production.

    Energy Technology Data Exchange (ETDEWEB)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  8. Castor oil polyurethane containing silica nanoparticles as filling material of bone defect in rats Poliuretana de mamona contendo nanopartículas de sílica como material de preenchimento de defeito ósseo em ratos

    Directory of Open Access Journals (Sweden)

    Renato Silva Nacer

    2012-01-01

    Full Text Available PURPOSE: To evaluate the biologic behavior of the castor polymer containing silica nanoparticles as a bone substitute in diafisary defect. METHODS: Twenty seven male rattus norvegicus albinus wistar lineage were submitted to bone defect filled with castor oil polymer. Three experimental groups had been formed with nine animals each: (1 castor oil polymer containing only calcium carbonate; (2 castor oil polymer with calcium carbonate and doped with 5% of silica nanoparticles; (3 castor polymer with calcium carbonate doped with 10% of silica nanoparticles; 3 animals of each group were submitted to euthanasia 15, 30 and 60 days after experimental procedure, and their femurs were removed to histological evaluation. RESULTS: there was bone growth in all the studied groups, with a greater tendency of growth in the group 1. After 30 days all the groups presented similar results. After 60 days a greater amount of fibroblasts, osteoblasts, osteocytes and osteoclasts in group 3 was observed, with integrated activity of 3 kinds of cells involved in the bone activation-reabsorption-formation. CONCLUSIONS: The castor polymer associated to the silica nanoparticles is biocompatible and allows osteoconduction. The presence of osteoprogenitors cells suggests silica osteoinduction capacity.OBJETIVO: Avaliar o comportamento biológico do polímero de mamona contendo nanopartículas de sílica como substituto ósseo. MÉTODOS: Vinte e sete rattus norvergicus albinus, Wistar foram submetidos a defeito ósseo preenchido com polímero de mamona. Foram formados três grupos experimentais, com nove ratos cada: (1 Polímero com carbonato de cálcio; (2 Polímero com carbonato de cálcio dopado com 5% de nanopartículas de sílica; (3 Polímero com carbonato de cálcio dopado com 10% de nanopartículas de sílica; três animais de cada grupo foram submetidos à eutanásia 15, 30 e 60 dias após o procedimento experimental e os fêmures removidos e submetidos à avalia

  9. Biologia comparada de Spodoptera cosmioides (Walk. (Lepidoptera: Noctuidae em cebola, mamona, soja e feijão Compared biology of Spodoptera cosmioides (Walk. (Lepidoptera: Noctuidae in onion, castor oil plant, soybean and bean

    Directory of Open Access Journals (Sweden)

    Alvimar Bavaresco

    2003-12-01

    Full Text Available Estudou-se a biologia de Spodoptera cosmioides (Walk. sobre quatro hospedeiros naturais (folhas de cebola, mamona, soja cv. Embrapa 48 e feijão cv. Carioca. Foram avaliados a duração e viabilidade das fases imaturas e do ciclo total, número de ínstares, peso de pupas, razão sexual, porcentagem de deformação de adultos e de adultos não liberados dos invólucros pupais, longevidade de adultos, fecundidade e viabilidade de ovos. Observou-se menor duração e maior viabilidade do período ovo-adulto para mamona e cebola (39,7 dias e 21,7% e 40,5 dias e 21,8%, respectivamente, do que para soja (46,0 dias e 3,9%. O peso pupal foi de 444,6 mg em cebola, 420,0 em feijão, 396,6 em mamona e 298,7 em soja. Constatou-se um predomínio de seis ínstares larvais em folhas de cebola e mamona, ocorrendo também sete para alguns indivíduos, enquanto que em soja predominou a ocorrência de sete, também verificando oito ínstares, indicando uma menor adequação nutricional deste hospedeiro. As fêmeas apresentaram duração da fase pupal significativamente menor do que os machos em todos hospedeiros, fazendo com que a emergência do adulto ocorresse antes dos machos. Em cebola, a longevidade de adultos foi significativamente superior aos demais hospedeiros. A fecundidade foi maior em cebola e mamona (3224 e 3206 ovos/fêmea, respectivamente, enquanto que para soja observou-se 1353 ovos/fêmea. Em folhas de feijão, o desenvolvimento do inseto foi prejudicado por caracteres morfológicos - pilosidade, que promoveram elevada mortalidade na fase larval.The biology of Spodoptera cosmioides (Walk. was studied on four natural hosts (onion leaves, castor oil plant, soy cv. Embrapa 48 and bean cv. Carioca. The duration and viability of immature phases and total cycle, instar number, pupals weight, sexual ratio, percentage of deformed adults and adults not released of pupal beg, adults' longevity, fecundity and eggs viability were evaluated. It was observed in

  10. Environmental consequences of oil production from oil sands

    Science.gov (United States)

    Rosa, Lorenzo; Davis, Kyle F.; Rulli, Maria C.; D'Odorico, Paolo

    2017-02-01

    Crude oil from oil sands will constitute a substantial share of future global oil demand. Oil sands deposits account for a third of globally proven oil reserves, underlie large natural forested areas, and have extraction methods requiring large volumes of freshwater. Yet little work has been done to quantify some of the main environmental impacts of oil sands operations. Here we examine forest loss and water use for the world's major oil sands deposits. We calculate actual and potential rates of water use and forest loss both in Canadian deposits, where oil sands extraction is already taking place, and in other major deposits worldwide. We estimated that their exploitation, given projected production trends, could result in 1.31 km3 yr-1 of freshwater demand and 8700 km2 of forest loss. The expected escalation in oil sands extraction thus portends extensive environmental impacts.

  11. Castor bean organelle genome sequencing and worldwide genetic diversity analysis.

    Directory of Open Access Journals (Sweden)

    Maximo Rivarola

    Full Text Available Castor bean is an important oil-producing plant in the Euphorbiaceae family. Its high-quality oil contains up to 90% of the unusual fatty acid ricinoleate, which has many industrial and medical applications. Castor bean seeds also contain ricin, a highly toxic Type 2 ribosome-inactivating protein, which has gained relevance in recent years due to biosafety concerns. In order to gain knowledge on global genetic diversity in castor bean and to ultimately help the development of breeding and forensic tools, we carried out an extensive chloroplast sequence diversity analysis. Taking advantage of the recently published genome sequence of castor bean, we assembled the chloroplast and mitochondrion genomes extracting selected reads from the available whole genome shotgun reads. Using the chloroplast reference genome we used the methylation filtration technique to readily obtain draft genome sequences of 7 geographically and genetically diverse castor bean accessions. These sequence data were used to identify single nucleotide polymorphism markers and phylogenetic analysis resulted in the identification of two major clades that were not apparent in previous population genetic studies using genetic markers derived from nuclear DNA. Two distinct sub-clades could be defined within each major clade and large-scale genotyping of castor bean populations worldwide confirmed previously observed low levels of genetic diversity and showed a broad geographic distribution of each sub-clade.

  12. Effect of calcium and magnesium silicate on the growth of the castor oil plant subjected to salinity levels

    OpenAIRE

    de Brito Neto, Jose Felix [UNESP; Macedo Beltrao, Napoleao de Esberard; Gonsiorkiewicz Rigon, Joao Paulo [UNESP; Capuani, Silvia [UNESP

    2012-01-01

    Salt stress decreases the osmotic potential of soil solution causing water stress, causing toxic effects in the plants resulting in injuries on the metabolism and nutritional disorders, thus compromising the plant growth, resulting in lower production. The calcium silicate and magnesium can perform the same function as limestone, besides providing silicon to plants, may also contribute to the resistance of plants to salt stress. Thus, the objective of this study was to evaluate the effect of ...

  13. Evaluation of reaction mechanisms and the kinetic parameters for the transesterification of castor oil by liquid enzymes

    DEFF Research Database (Denmark)

    Andrade, Thalles Allan; Errico, Massimiliano; Christensen, Knud Villy

    2017-01-01

    methanolysis rates of glycerides obtained, indicated that transesterification dominates over hydrolysis. The mechanism among the four models proposed that gave the best fit could be simplified, eliminating the kinetic parameters with negligible effects on the reaction rates. This model was able to fit......The use of liquid enzymes for the production of biodiesel as an alternative to chemical catalysts requires significant investigation due to the lack of experimental data for the various feedstock and catalyst combinations. In this paper, reaction rates and kinetic modeling...... the concentration data, four different reaction mechanistic models were compared to determine the mechanism that best fitted the experimental data. Mechanisms where the methanolysis and hydrolysis reactions occurred simultaneously in the system were best at describing the concentration profiles. The high...

  14. Caspian Oil and Gas: Production and Prospects

    National Research Council Canada - National Science Library

    Gelb, Bernard A

    2005-01-01

    .... The Caspian Sea region historically has been an oil and natural gas producer, but many believe that the region contains large reserves of oil and gas capable of much greater production than at present...

  15. Inibição do desenvolvimento de fungos fitopatogênicos por detergente derivado de óleo da mamona (Ricinus communis The castor oil plant detergent (Ricinus communis inhibits the asexual development of phytopathogenic fungi

    Directory of Open Access Journals (Sweden)

    Eunice Hitomi Takano

    2007-10-01

    Full Text Available No presente estudo avaliou-se o efeito fungitóxico do detergente derivado do óleo da mamona (Ricinus communis sobre o desenvolvimento dos fitopatógenos: Pyricularia grisea, Fusarium graminearum e Colletotrichum lindemuthianum. Seis concentrações do detergente (12,5mL L-1 a 300mL L-1 foram, individualmente, incorporadas ao Meio Basal; a seguir, após inoculação fúngica, o crescimento radial dos micélios foi avaliado. A inibição total do desenvolvimento de C. lindemuthianum e P. grisea foi observada entre as concentrações de 50mL L-1 e 200mL L-1, respectivamente. Com base no crescimento miceliano das colônias de F. graminearum, a atividade antifúngica do detergente do óleo da mamona (DOM determinou inibição variável entre 79,4 e 91% para a raça F2 e entre 80,7 e 90,7% para a raça F4. O detergente, nas concentrações de 100 a 300mL L-1, inibiu em 100% a germinação de conídios de F. graminearum (raças F-4 e F-2. Os resultados demonstram nítida atividade antifúngica do detergente derivado do óleo da mamona sobre fitopatógenos.In the present study the fungitoxic effect of the castor oil plant detergent (Ricinus communis on the development of the phytopathogens Pyricularia grisea, Fusarium graminearum and Colletotrichum lindemuthianum was evaluated. Six concentrations of the detergent (12.5mL L-1 to 300mL L-1 had been, individually, incorporated to the Basal Medium. After fungi inoculations, the radial growth of mycelia were evaluated. Detergent at 50mL L-1 and 200mL L-1 inhibited completely the development of P. grisea and C. lindemuthianum, respectively. On the basis of the mycelial growth of F. graminearum, the fungitoxic activity of the castor oil plant detergent (DOM determined inhibition in the range of 79.4 and 91% for the F2 race and 80.7 and 90.7% for the F4 race. Detergent at the concentrations of 100mL L-1 to 300mL L-1 inhibited in 100% the F. graminearum germination conidia (races F-4 and F-2. Results

  16. Influência das variáveis de processo na alcoólise enzimática de óleo de mamona Evaluation of the influence of process variables on enzimatic alcoholysis of castor oil

    Directory of Open Access Journals (Sweden)

    D. Oliveira

    2004-06-01

    intermediates to produce a number of oleochemicals and fuel alternatives (biodiesel. In this work, enzymatic alcoholysis of castor bean oil with an immobilized lipase (Lipozyme IM was accomplished using n-hexane as solvent. In order to maximize the esters production a Taguchi design was adopted varying temperature, water and enzyme concentrations in the reaction media and the oil:ethanol molar ratio. The reactions were monitorated by determining the glycerol production. An empirical model was built to evaluate the influence of the process variables on the conversion and afterwards the operating conditions that maximize esters production were established.

  17. Large scale fuel oil production experiments

    Energy Technology Data Exchange (ETDEWEB)

    1943-08-04

    The effect of the coal throughput and the composition of the pasting oil, in particular the effect of different middle oil contents in the pasting oil, was previously tested in small scale experiments of hydrogenation of coal. Possibilities of increasing the throughput through the converter when producing heavy oil together with middle oil is shown in this work. The proper industrial detail for the production of heavy oil had to be developed first on a semi-commercial plant. The Upper Silesian coal was used to study the production of gasoline, middle oil, and heavy oil at 700 atm in a 1.6 m/sup 3/ converter and to relate the results with the small scale experiments (10-liter converter). Paste heat exchange was carried out successfully. The following experiments, among others, were carried out: mixed coals were hydrogenated to 100% gasoline plus middle oil, to 65% gasoline and middle oil and 35% heavy oil, as well as 50% gasoline and middle oil plus 50% heavy oil, in part with the usual iron catalyst combination and in part with the sulfurated Bayer mass together with the iron sulfate and sulfigran. The Heinity coal had been hydrogenated with the usual iron catalyst to 65% gasoline and middle oil plus 35% heavy oil. The important results were summarized in a table. Details of the experiments and processes used were given in 3 graphs and 42 tables.

  18. Production of pomace olive oil

    Directory of Open Access Journals (Sweden)

    Ruiz Méndez, Mª Victoria

    2006-03-01

    Full Text Available Pomace oil is the principal by-product in olive oil processing and is currently developing considerably due to the technological advances which the mills have undergone in recent years. This investigation aims at presenting an overview of the complexity of this sector which, with around 100 years of existence, is searching for a role in the new integral strategy of the olive oil industry after the crisis suffered in 2001. Physical extraction, drying and solvent extraction are discussed, along with the influence of the technological treatments on the chemical composition of pomace oil.El aceite de orujo es el principal subproducto en el procesado de aceite de oliva y su obtención se ha transformado considerablemente en los últimos tiempos debido a los avances tecnológicos que han experimentado las almazaras. Este trabajo tiene la finalidad de presentar una panorámica de la complejidad de este sector, de casi 100 años de existencia, que se afana en encontrar su función dentro de la nueva estrategia integral de la industria oleícola después de la crisis sufrida en el año 2001. En el mismo se comentan la extracción física, el secado, así como la extracción con disolvente, y la influencia que tienen los tratamientos tecnológicos sobre la composición química del aceite de orujo.

  19. Recovery of different waste vegetable oils for biodiesel production: a pilot experience in Bahia State, Brazil.

    Science.gov (United States)

    Torres, Ednildo Andrade; Cerqueira, Gilberto S; Tiago, M Ferrer; Quintella, Cristina M; Raboni, Massimo; Torretta, Vincenzo; Urbini, Giordano

    2013-12-01

    In Brazil, and mainly in the State of Bahia, crude vegetable oils are widely used in the preparation of food. Street stalls, restaurants and canteens make a great use of palm oil and soybean oil. There is also some use of castor oil, which is widely cultivated in the Sertão Region (within the State of Bahia), and widely applied in industry. This massive use in food preparation leads to a huge amount of waste oil of different types, which needs either to be properly disposed of, or recovered. At the Laboratorio Energia e Gas-LEN (Energy & Gas lab.) of the Universidade Federal da Bahia, a cycle of experiments were carried out to evaluate the recovery of waste oils for biodiesel production. The experiences were carried out on a laboratory scale and, in a semi-industrial pilot plant using waste oils of different qualities. In the transesterification process, applied waste vegetable oils were reacted with methanol with the support of a basic catalyst, such as NaOH or KOH. The conversion rate settled at between 81% and 85% (in weight). The most suitable molar ratio of waste oils to alcohol was 1:6, and the amount of catalyst required was 0.5% (of the weight of the incoming oil), in the case of NaOH, and 1%, in case of KOH. The quality of the biodiesel produced was tested to determine the final product quality. The parameters analyzed were the acid value, kinematic viscosity, monoglycerides, diglycerides, triglycerides, free glycerine, total glycerine, clearness; the conversion yield of the process was also evaluated. Copyright © 2013 Elsevier Ltd. All rights reserved.

  20. Photosynthetic pigments and gas exchange in castor bean under conditions of above the optimal temperature and high CO2

    Directory of Open Access Journals (Sweden)

    Fabiola França Silva

    2015-08-01

    Full Text Available The castor bean plant, a Euphorbiaceae oil seed C3-metabolism rustic and drought-resistant plant, is cultivated in a wide range of environments due to its good adaptive capacity. However, given the current environmental changes, many biochemical and physiological impacts may affect the productivity of important crops, such as castor bean. This work aimed to evaluate the impacts of the castor bean gas exchange in response to high temperature and increased CO2concentration.Our experiment was conducted in a phytotron located at Embrapa Algodão in 2010. We adopted a completely randomized design, with four treatments in a factorial combination of two temperatures (30/20 and 37/30°C and two CO2 levels (400 and 800 mmol L-1; four replications were performed, obtained in five surveys over the growth cycle, for a total of 80 sample units. An infrared gas analyzer (IRGA - Infra Red Gas Analyzer was used for the quantification of the photosynthetic rate, stomatal conductance and transpiration. An increase in the atmospheric CO2 concentration and temperature negatively affected the physiology of the castor bean plants, decreasing the net rate of photosynthesis, transpiration and stomatal conductance.

  1. The CASTOR initiative

    Energy Technology Data Exchange (ETDEWEB)

    Le Thiez, Pierre [GEOGREEN (France)

    2008-07-15

    In this paper it is spoken over the CASTOR project, which has 31 partners of 12 European countries. Also it is spoken on the strategy for the CO{sub 2} reduction in Europe; what on the capture and post-combustion has been done, and what as far as geologic CO{sub 2} storage has been accomplished. [Spanish] En esta ponencia se habla sobre el proyecto Castor, el cual cuenta con 31 socios de 12 paises europeos. Tambien se habla sobre la estrategia para la reduccion de CO{sub 2} en Europa; lo que se ha hecho en cuanto a captura post-combustion y lo que se ha hecho para el almacenamiento geologico de CO{sub 2}.

  2. Asphaltene precipitates in oil production wells

    DEFF Research Database (Denmark)

    Kleinitz, W,; Andersen, Simon Ivar

    1998-01-01

    At the beginning of production in a southern German oil field, flow blockage was observed during file initial stage of production from the oil wells. The hindrance was caused by the precipitation of asphaltenes in the proximity of the borehole and in the tubings. The precipitates were of solid...

  3. Survey of the castor bean production (Ricinus communis L. in a collection of producers from five counties of Bahia State. = Levantamento da produção de mamona (Ricinus communis L. em uma amostra de produtores em cinco municípios do Estado da Bahia.

    Directory of Open Access Journals (Sweden)

    Vicente de Paula Queiroga

    2011-08-01

    Full Text Available The objective of this study was to verify the situation of the culture of castor bean from a collection of producers located in five counties of Bahia state, highlighting the technical conditions of production and commercialization of the product, beyond its social aspects. Twenty-five castor bean producers were interviewed during the 2005 agricultural year by a team of researchers from the Embrapa Cotton. A present questionnaire with 15 variable questions pertaining to agro-economic and social-economic was applied to producers with the objective to diagnose the agricultural social-economic profiles of theproducers of castor bean that are used for the production of berries to be used within the energy market of the Program of Biodiesel and Ricin chemistry. Data analysis concluded that the family farmers of Bahia have the culture of castor oil as, a major source of income, but the cultivation techniques, promising cultivars, and oil content are underutilized. It was shown that a technology gap can be solved by a adopting a differential pricing policy that is based on a feasibility comprehensive recovery program that increases the ricin culture productivity throughout the production chain, reduce costs, and increase the oil content of cultivars.ResumoObjetivou-se com este estudo verificar a situação da cultura da mamona em uma amostra de produtores levantados em cinco municípios localizados no noroeste do estado da Bahia (São Gabriel, Irecê, Lapão, Ibititá e Cafarnaum, destacando-se as condições técnicas de produção e de comercialização do produto, além dos seus aspectos sociais. Um total de 25 produtores de mamona foi entrevistado no ano agrícola de 2005, por uma equipe de pesquisadores da Embrapa Algodão. Um questionário preestabelecido com 15 variáveis agronômicas e socioecononômicas foi aplicado junto aos produtores, visando o diagnóstico do perfil agrossocioeconômico dos produtores de mamona que estão destinando sua

  4. Interpenetrating polymer networks based on polyol modified castor ...

    Indian Academy of Sciences (India)

    Interpenetrating polymer networks (IPNs) of glycerol modified castor oil polyurethane (GC–PU) and poly[2-hydroxyethylmethacrylate] (PHEMA) were synthesized using benzoyl peroxide as initiator and N,N-methylene bis acrylamide as crosslinker. GC–PU/PHEMA interpenetrating polymer networks were obtained by ...

  5. Modulating the properties of sunflower oil based novel emulgels using castor oil fatty acid ester: prospects for topical antimicrobial drug delivery.

    Science.gov (United States)

    Behera, B; Biswal, D; Uvanesh, K; Srivastava, A K; Bhattacharya, Mrinal K; Paramanik, K; Pal, K

    2015-04-01

    The current study describes the effect of polyglycerol polyricinoleate (PGPR) on the properties of sunflower oil and span-40 based emulgels. The prepared emulgels contained PGPR in varied concentrations. The microstructure of the emulgels was characterized by bright-field microscopy. The molecular interactions amongst the components of the emulgels were studied using FTIR spectroscopy. The flow and mechanical behaviors of the emulgels were studied using cone-and-plate viscometer and static mechanical tester, respectively. The efficiency of the metronidazole-loaded emulgels as antimicrobial formulations was tested in vitro. E. coli was used as the model microorganism for the antimicrobial study. The emulgels were also explored for iontophoretic delivery applications. The biocompatibility of the emulgels was tested using human keratinocytes (HaCaT). The microscopic evaluation of the emulgels indicated formation of biphasic formulations. FTIR studies suggested a decrease in the hydrogen bonding amongst the components of the emulgels as the concentration of the PGPR was increased. Viscosity studies indicated shear-thinning property of the emulgels. An increase in the PGPR concentration resulted in the reduction in the mechanical properties of the emulgels. Incorporation of PGPR resulted in the decrease in the drug released (both passive and iontophoresis) from the emulgels. The emulgels were found to be cytocompatible in the presence of keratinocytes. The drug loaded emulgels showed good antimicrobial activity against E. coli. In gist, the developed emulgels can be tried for controlled delivery of antimicrobial drugs. The physical and the release properties of the emulgels can be modulated by incorporating PGPR in varied proportions. Copyright © 2015 Elsevier B.V. All rights reserved.

  6. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    Energy Technology Data Exchange (ETDEWEB)

    Anthony R. Kovscek

    2002-07-01

    This technical progress report describes work performed from April 1 through June 30, 2002, for the project ''Heavy and Thermal Oil Recovery Production Mechanisms.'' We investigate a broad spectrum of topics related to thermal and heavy-oil recovery. Significant results were obtained in the areas of multiphase flow and rock properties, hot-fluid injection, improved primary heavy oil recovery, and reservoir definition. The research tools and techniques used are varied and span from pore-level imaging of multiphase fluid flow to definition of reservoir-scale features through streamline-based history-matching techniques. Briefly, experiments were conducted to image at the pore level matrix-to-fracture production of oil from a fractured porous medium. This project is ongoing. A simulation studied was completed in the area of recovery processes during steam injection into fractured porous media. We continued to study experimentally heavy-oil production mechanisms from relatively low permeability rocks under conditions of high pressure and high temperature. High temperature significantly increased oil recovery rate and decreased residual oil saturation. Also in the area of imaging production processes in laboratory-scale cores, we use CT to study the process of gas-phase formation during solution gas drive in viscous oils. Results from recent experiments are reported here. Finally, a project was completed that uses the producing water-oil ratio to define reservoir heterogeneity and integrate production history into a reservoir model using streamline properties.

  7. New production techniques for alberta oil sands.

    Science.gov (United States)

    Carrigy, M A

    1986-12-19

    Low world oil prices represent a serious threat to expanded commercial development of the Canadian oil sands in the near term, as they do to all of the higher cost alternatives to crude oil such as oil shales and coal liquefaction. Nonetheless, research and field testing of new technology for production of oil from oil sands are being pursued by industry and government in Alberta. New production technology is being developed in Canada to produce synthetic oil from the vast resources of bitumen trapped in the oil sands and bituminous carbonates of northern Alberta. This technology includes improved methods of mining, extraction, and upgrading of bitumen from near-surface deposits as well as new drilling and production techniques for thermal production of bitumen from the more deeply buried reservoirs. Of particular interest are the cluster drilling methods designed to reduce surface disturbance and the techniques for horizontal drilling of wells from underground tunnels to increase the contact of injection fluids with the reservoir.

  8. Influence of the organic matter and soil water deficit on the castor bean absolute growth rate

    Energy Technology Data Exchange (ETDEWEB)

    Lacerda, Rogerio Dantas de; Guerra, Hugo O. Carvallo; Chaves, Lucia Helena G. [Universidade Federal de Campina Grande (UAEAg/UFCG), PB (Brazil). Unidade Academica de Engenharia Agricola; Araujo, Ester Luiz de; Nascimento, Elka Costa Santos; Barros Junior, Genival [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2008-07-01

    Even when under low precipitations conditions, the castor bean production decrease, it constitutes a very good alternative. It has an elevated economical importance, because from the plant it is used their leaves, stem and seeds. From the stem it is obtained cellulose for the paper industry, from the leaves textile products and from the seeds oil and tort. The oil is the only glycerin soluble in alcohol and the base for several industrial products such as the biodiesel. The objective of the present work was to study the effect of different soil water and soil organic matter on the castor bean, BRS 188 cultivar rate growth. The experiment was conducted from April to August 2006 under greenhouse conditions using a randomized block 2x4 factorial design with two soil organic mater content (5.0 g.kg{sup -1} e 25.0 g.kg{sup -1}), four levels of available water (100, 90, 80 e 70% ) and three replicates. For this, 24 plastic containers, 75 kg capacity, were used on which was grown one plant 120 days after the seedling. At regular intervals the plant height was measured and the results analyzed statistically. For the qualitative treatments (with and without organic matter) the treatment means were compared through the Tukey test. For the quantitative ones (water levels) regressions were used. It was observed that both, organic matter and available water for plants proportionated benefit effects to the growth rate of the plant. (author)

  9. White oil production from western Siberian petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Vlasenkov, L.A.; Potanina, V.A.; Popova, L.V.; Marcheva, Y.N.; Radchenko, K.A.

    1981-08-01

    The technology of producing white oils was investigated in multistage sulfonization of the initial raw material by oleum or gaseous sulphuranhydride (SO/sub 3/) with subsequent neutralization and contact prepurification. The use of gaseous sulphuranhydride instead of oleum has the advantage of lower consumption of the sulfonating agent, lower volume of acid tar formed and an increase of the yield of sulfonic acids which are used as a raw material to produce sulfonate additives. White oils are used to produce medical vaseline, perfume bases, a solvent of the ethylene polymerization reaction initiator, lubricating oil for high-pressure compressors and as cable lubricant. The technology of producing a variety of white oils based on neutral oil from a mixture of low-sulphur Fergana and Turkemen oils from sulfonate additive production was developed to expand the raw material resources produced from other oil fields. The yield of low-soluble sulfonic acids increases as SO/sub 3/ consumption increases in sulphurization of the fourth oil fraction of Western Siberian oils; yield decreases as SO/sub 3/ consumption increases during sulphurization of neutral oil of first degree of sulphurization, while the yield of acid tar increases. (JMT)

  10. 17 CFR 229.1204 - (Item 1204) Oil and gas production, production prices and production costs.

    Science.gov (United States)

    2010-04-01

    ... price (including transfers) per unit of oil, gas and other products produced; and (2) The average... conversion to synthetic oil or gas, the product's production, transfer prices, and production costs should be disclosed separately from all other products. Instruction 4 to Item 1204: The transfer price of oil and gas...

  11. Ingestive behavior of finishing sheep fed detoxified castor bean meal

    Directory of Open Access Journals (Sweden)

    Daniel Cézar da Silva

    2016-06-01

    Full Text Available ABSTRACT Castor bean crops stand out in the Northeastern Brazil for oil production, producing coproducts with potential for animal diets. Thus, this work evaluated the effect on ingestive behavior when 0, 33, 67 and 100% of detoxified castor bean meal (DCBM were included to substitute soy bean meal in diets for sheep. The randomized blocks design was used with five sheep in each treatment. Dry matter intake and neutral detergent fiber intake were not affected (P > .05 by the inclusion of DCBM in the diet, with means of 1362.6 and 582.98 g/animal/day, respectively. Substitution of soybean meal by DCBM did not affect (P > .05 times of rumination, idle and total chewing, with averages of 181.33, 347.04 and 366.24 minute/12 h, respectively. A quadratic effect (P < .05 was found for feeding time, with minimum of 164.56 min/12 h, when 60% of DCBM was included in the diet. A quadratic effect (P < .05 was verified for eating efficiency with maximum of 4.43 g DM/minute and 2.08 g NDF/minute. Rumination efficiency in g DM and NDF/minute were not affected (P < .05, with means of 4.31 and 1.84, respectively. The substitution of soybean meal by DCBM decreases feeding time when 60% of it was used but does not influence the intake of DM and NDF, time spent in ruminating and idle, and total chewing time. The use of 60% of DCBM increases feeding efficiency of DM and NDF, and does not compromise the efficiency of rumination.

  12. Factors Affecting Oil Palm Production in Ondo State of Nigeria ...

    African Journals Online (AJOL)

    The discovery of crude oil and the civil war adversely affected oil palm production in Nigeria. This has resulted in scarcity and high cost of palm products and palm oil. The study therefore investigated the factors influencing oil palm production in Ondo State, Nigeria. One hundred and fifty respondents were selected from ...

  13. Production development for a mature oil field

    Energy Technology Data Exchange (ETDEWEB)

    Demiral, B.; Gumrah, F.; Okandan, E. [Middle East Technical Univ., Ankara (Turkey)

    2001-06-01

    Petroleum reservoir engineers often analyze production data and forecast reserves through the decline curve analysis method which is a useful tool for extrapolating oil production in the future. The recovery of oil can be defined in terms of the oil relative permeability, the drainage volume and the pressure gradient. Problems occur in using decline curve analysis when there are changes to the relative permeability relationship or drainage occurs. This paper presented development strategies for the Mishovdag oil field in Azerbaijan. This sandstone reservoir provides 40 per cent of the total oil produced from the Sirvan oilfield region. A total of 516 wells have been drilled in the area since 1956, of which 198 are still in production. The reservoir properties were evaluated using core and well log data as well as the decline curve analysis. Two development scenarios were considered. The one which showed a production rate increase of 50 per cent within four years involved the stopping of water injection from the anticline and continuing it from other injection wells into the sands. 20 refs., 3 tabs., 9 figs.

  14. Production, optimization and quality assessment of biodiesel from Ricinus communis L. oil

    Directory of Open Access Journals (Sweden)

    Maryam Ijaz

    2016-04-01

    Full Text Available At present, biodiesel is gaining tremendous attention due to its eco-friendly nature and is possible substitute for diesel fuel. Biodiesel as renewable energy source can be produced from edible and non-edible feedstock. Non-edible resources are preferred to circumvent for food competition. In the present study FAME was produced from Ricinus communis L. oil by transesterification with methanol and ethanol in the presence of potassium hydroxide. The practical optimal condition for the production of biodiesel from castor bean was found to be: methanol/oil molar ratio, 6:1; temperature, 60 °C; time, 45 min; catalyst concentration 0.32 g. Quality assessment of biodiesel showed comparable results with ASTM standards. The values of specific gravity (SG were 0.5, kinematic viscosity 2.45 cSt, acid values 0.13 mg KOH/g, carbon residue 0.03%, flash point 119 °C, fire point 125 °C, cloud point −10 °C and pour point −20 °C of Ricinus FAME, respectively. Based on our data, it is suggested that to overcome prevailing energy crisis this non-edible plant is useful for production of biodiesel, which is an alternate to fossil fuel and may be used alone or in blend with HSD in engine combustion.

  15. Production, properties and utilisation of pyrolysis oil

    Energy Technology Data Exchange (ETDEWEB)

    Sipilae, K.; Oasmaa, A.; Arpiainen, V.; Solantausta, Y.; Leppaemaeki, E.; Kuoppala, E.; Levander, J.; Kleemola, J.; Saarimaeki, P. [VTT Energy, Jyvaeskylae (Finland). Energy Production Technologies

    1997-12-01

    In this project VTT Energy co-ordinates the EU JOULE Project `Biofuel oil for power plants and boilers` supporting the development projects of Finnish enterprises, and participates in the Pyrolysis Project of IEA Bioenergy Agreement. Presently two pyrolysis devices with capacities of 150 g/h and 1 kg/h are used for the project. Hot gas filtering tests by using one ceramic candle equipment have been carried out with the 1 kg/h device for pyrolysis oil. The solids and alkali contents of the product oil were reduced clearly. Suitable conditions are being defined for continuous hot gas filtering. A PDU device of 20 kg/h is being commissioned. The main aim of the chemical characterisation of pyrolysis oil was to develop as simple a method as possible for differentiating pyrolysis oils and for finding correlations between the characteristics and behaviour of pyrolysis oils. Pyrolysis oils produced from various raw materials (hardwood, pine, straw) were analysed and compared with each other. VTT Energy participates in the pyrolysis network (EU/PYNE) of EU, the aim of which is to collect and disseminate research results of pyrolysis studies, i.e., through a journal with a wide circulation. VTT also participates in the pyrolysis activity of IEA (PYRA), the other partners being Great Britain, EU, Canada and the United States. I.e., quality criteria and improvement, occupational safety and pyrolysis kinetics are discussed in IEA/PYRA

  16. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    Energy Technology Data Exchange (ETDEWEB)

    Anthony R. Kovscek

    2003-01-01

    This technical progress report describes work performed from October 1 through December 31, 2002 , for the project ''Heavy and Thermal Oil Recovery Production Mechanisms.'' In this project, a broad spectrum of research is undertaken related to thermal and heavy-oil recovery. The research tools and techniques used are varied and span from pore-level imaging of multiphase fluid flow to definition of reservoir-scale features through streamline-based history-matching techniques. During this period, experimental data regarding multidimensional imbibition was analyzed to obtain shape factors appropriate for dual-porosity simulation. It is shown that the usual assumption of constant, time-independent shape factors is incorrect. In other work, we continued to study the mechanisms by which oil is produced from fractured media at high pressure and high temperature. High temperature significantly increased the apparent wettability and affected water relative permeability of cores used in previous experiments. A phenomenological and mechanistic cause for this behavior is sought. Our work in the area of primary production of heavy oil continues with field cores and crude oil. On the topic of reservoir definition, work continued on developing techniques that integrate production history into reservoir models using streamline-based properties.

  17. Production Optimization of Oil Reservoirs

    DEFF Research Database (Denmark)

    Völcker, Carsten

    with emphasis on optimal control of water ooding with the use of smartwell technology. We have implemented immiscible ow of water and oil in isothermal reservoirs with isotropic heterogenous permeability elds. We use the method of lines for solution of the partial differential equation (PDE) system that governs...... the uid ow. We discretize the the two-phase ow model spatially using the nite volume method (FVM), and we use the two point ux approximation (TPFA) and the single-point upstream (SPU) scheme for computing the uxes. We propose a new formulation of the differential equation system that arise...... as a consequence of the spatial discretization of the two-phase ow model. Upon discretization in time, the proposed equation system ensures the mass conserving property of the two-phase ow model. For the solution of the spatially discretized two-phase ow model, we develop mass conserving explicit singly diagonally...

  18. Biodiesel production from Jatropha curcas oil

    Energy Technology Data Exchange (ETDEWEB)

    Jain, Siddharth; Sharma, M.P. [Alternate Hydro Energy Centre, Indian Institute of Technology Roorkee, Roorkee, Uttarakhand 247667 (India)

    2010-12-15

    In view of the fast depletion of fossil fuel, the search for alternative fuels has become inevitable, looking at huge demand of diesel for transportation sector, captive power generation and agricultural sector, the biodiesel is being viewed a substitute of diesel. The vegetable oils, fats, grease are the source of feedstocks for the production of biodiesel. Significant work has been reported on the kinetics of transesterification of edible vegetable oils but little work is reported on non-edible oils. Out of various non-edible oil resources, Jatropha curcas oil (JCO) is considered as future feedstocks for biodiesel production in India and limited work is reported on the kinetics of transesterification of high FFA containing oil. The present study reports a review of kinetics of biodiesel production. The paper also reveals the results of kinetics study of two-step acid-base catalyzed transesterification process carried out at pre-determined optimum temperature of 65 and 50 C for esterification and transesterification process, respectively, under the optimum condition of methanol to oil ratio of 3:7 (v/v), catalyst concentration 1% (w/w) for H{sub 2}SO{sub 4} and NaOH and 400 rpm of stirring. The yield of methyl ester (ME) has been used to study the effect of different parameters. The maximum yield of 21.2% of ME during esterification and 90.1% from transesterification of pretreated JCO has been obtained. This is the first study of its kind dealing with simplified kinetics of two-step acid-base catalyzed transesterification process carried at optimum temperature of both the steps which took about 6 h for complete conversion of TG to ME. (author)

  19. Energy balance of the lavender oil production

    Directory of Open Access Journals (Sweden)

    Osman GÖKDOĞAN

    2016-06-01

    Full Text Available This research was carried out to determine the energy input-output analysis of lavender oil production. Data from agricultural farms in Isparta province was used. Energy input was calculated as 1993.89 MJ and energy output was calculated as 2925.51 MJ. Wood energy, fresh stalked lavender flower energy, equipment energy, human labour energy, electricity energy, and water energy inputs were 54.22 %, 41.86 %, 3.40 %, 0.23 %, 0.18 %, and 0.10 % of energy inputs, respectively. In this production, it is noteworthy that wood was used as fuel in the lavender oil production distillation process as the highest input. In the energy outputs, an average of 3.10 kg lavender oil and 130 kg lavender water were extracted by processing 234 kg fresh stalked lavender flower. Energy use efficiency, specific energy, energy productivity, and net energy for lavender oil production were calculated as 1.47, 643.19 MJ kg-1, 0.002 kg MJ-1 and 931.62 MJ, respectively.

  20. Variations in seed traits of castor ( Ricinus communis ) accessions ...

    African Journals Online (AJOL)

    The physicochemical analysis showed that castor seed and oil had saponification value of 182.9 mg/g, moisture content of 4.4%, acid value of 3.085 mg/g, viscosity of 110.41 cP, pH of 6.11, iodine value of 8.46 mg/g, specific gravity of 0.962 and refractive index of 1.477˚C. The proximate analysis showed that moisture ...

  1. Pollutant in palm oil production process.

    Science.gov (United States)

    Hosseini, Seyed Ehsan; Abdul Wahid, Mazlan

    2015-07-01

    Palm oil mill effluent (POME) is a by-product of the palm industry and it releases large amounts of greenhouse gases (GHGs). Water systems are also contaminated by POME if it is released into nonstandard ponds or rivers where it endangers the lives of fish and water fowl. In this paper, the environmental bottlenecks faced by palm oil production were investigated by analyzing the data collected from wet extraction palm oil mills (POMs) located in Malaysia. Strategies for reducing pollution and technologies for GHG reduction from the wet extraction POMs were also proposed. Average GHG emissions produced from processing 1 ton of crude palm oil (CPO) was 1100 kg CO2eq. This amount can be reduced to 200 kg CO2eq by capturing biogases. The amount of GHG emissions from open ponds could be decreased from 225 to 25 kg CO2eq/MT CPO by covering the ponds. Installation of biogas capturing system can decrease the average of chemical oxygen demand (COD) to about 17,100 mg/L and stabilizing ponds in the final step could decrease COD to 5220 mg/L. Using a biogas capturing system allows for the reduction of COD by 80% and simultaneously using a biogas capturing system and by stabilizing ponds can mitigate COD by 96%. Other ways to reduce the pollution caused by POME, including the installation of wet scrubber vessels and increasing the performance of biogas recovery and biogas upgrading systems, are studied in this paper. Around 0.87 m3 POME is produced per 1 ton palm fruit milled. POME consists of around 2% oil, 2-4% suspended solid, 94-96% water. In palm oil mills, more than 90% of GHGs were emitted from POME. From 1 ton crude palm oil, 1100 kg CO2eq GHGs are generated, which can be reduced to 200 kg CO2eq by installation of biogas capturing equipment.

  2. Sustainability aspects of biobased products : comparison of different crops and products from the vegetable oil platform

    NARCIS (Netherlands)

    Meesters, K.P.H.; Corré, W.J.; Conijn, J.G.; Patel, M.K.; Bos, H.L.

    2012-01-01

    This study focusses on the production of vegetable oil based products. A limited number of aspacts of the sustainability of the full chain (from agriculture to product at the factory gate) was evaluated. Three different vegetable oils were taken into account: palm oil, soy oil and rapeseed oil. Also

  3. Production of fats and oils by microorganisms

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Osamu

    1987-10-20

    This paper describes the production of fats and oils by microorganisms. Various fat-productive bacteria have been found to produce the fats and oils by microorganisms which are roughly classified into enzyme and filiform fungus. The cells do not proliferate under the conditions adequate for producing the cells with the high content of lipid. A cell with high content of fat belonging to Mortierella filamentas fungi has been recently obtained at high density in the high concentration culture medium. The productivity of the fat similar to cocoa butter seems to be also high. A lot of microorganisms producing various functional fatty acids have been found. The microorganismic production methods of esters of longer-chain dicarboxylic acids and alcohols than C/sub 11/ hardly produced in nature form n-alkane also have been recently developed. Squalene has been able to produce by a cell from the other raw materials than the shark oil. Various sterols exist in microorganisms. The high-productivity manufacturing method of the fats containing gamma-linoleic acid by Mortierella filiform fungi has been developed and commercialized as the first production process of the fat by the microorganism. (5 figs, 7 tabs, 128 refs

  4. Exploiting EST databases for the development and characterization of EST-SSR markers in castor bean (Ricinus communis L.).

    Science.gov (United States)

    Qiu, Lijun; Yang, Chun; Tian, Bo; Yang, Jun-Bo; Liu, Aizhong

    2010-12-16

    The castor bean (Ricinus communis L.), a monotypic species in the spurge family (Euphorbiaceae, 2n = 20), is an important non-edible oilseed crop widely cultivated in tropical, sub-tropical and temperate countries for its high economic value. Because of the high level of ricinoleic acid (over 85%) in its seed oil, the castor bean seed derivatives are often used in aviation oil, lubricants, nylon, dyes, inks, soaps, adhesive and biodiesel. Due to lack of efficient molecular markers, little is known about the population genetic diversity and the genetic relationships among castor bean germplasm. Efficient and robust molecular markers are increasingly needed for breeding and improving varieties in castor bean. The advent of modern genomics has produced large amounts of publicly available DNA sequence data. In particular, expressed sequence tags (ESTs) provide valuable resources to develop gene-associated SSR markers. In total, 18,928 publicly available non-redundant castor bean EST sequences, representing approximately 17.03 Mb, were evaluated and 7732 SSR sites in 5,122 ESTs were identified by data mining. Castor bean exhibited considerably high frequency of EST-SSRs. We developed and characterized 118 polymorphic EST-SSR markers from 379 primer pairs flanking repeats by screening 24 castor bean samples collected from different countries. A total of 350 alleles were identified from 118 polymorphic SSR loci, ranging from 2-6 per locus (A) with an average of 2.97. The EST-SSR markers developed displayed moderate gene diversity (He) with an average of 0.41. Genetic relationships among 24 germplasms were investigated using the genotypes of 350 alleles, showing geographic pattern of genotypes across genetic diversity centers of castor bean. Castor bean EST sequences exhibited considerably high frequency of SSR sites, and were rich resources for developing EST-SSR markers. These EST-SSR markers would be particularly useful for both genetic mapping and population structure

  5. Solubility and Permeability Studies of Aceclofenac in Different Oils ...

    African Journals Online (AJOL)

    Methods: UV spectrophotometeric method was used at the wavelength of 276 nm to measure the dissolved quantity of aceclofenac in each of the oils (almond oil, oleic acid, castor oil, paraffin oil, cinnamon oil, clove oil, canola oil, sesame oil, isopropyl myristate (ipm), sunflower oil, corn oil, coconuts oil and eucalyptus oil) at ...

  6. Identification and functional expression of a type 2 acyl-CoA:diacylglycerol acyltransferase (DGAT2) in developing castor bean seeds which has high homology to the major triglyceride biosynthetic enzyme of fungi and animals.

    Science.gov (United States)

    Kroon, Johan T M; Wei, Wenxue; Simon, William J; Slabas, Antoni R

    2006-12-01

    Seed oil from castor bean (Ricinus communis) contains high amounts of hydroxy fatty acid rich triacylglycerols (TAGs) that can serve as raw material for production of bio-based products such as nylon, cosmetics, lubricants, foams, and surfactants. Diacylglycerol acyltransferase (DGAT) catalyses the terminal reaction in the acyl-CoA dependent Kennedy pathway of triglyceride biosynthesis. There is still some debate whether there are three or four enzymes in yeast that have DGAT activity and catalyse the synthesis of TAG but of these the DGAT2 homologue Dga1 contributes in a major way to TAG biosynthesis. Here we report on the cloning of a cDNA for DGAT2 from castor bean and prove its biological activity following expression in yeast and enzymatic assays using diricinolein as the acceptor and ricinoleoyl-CoA as the donor. Previous reports of DGAT in castor have focussed on DGAT1 which has little amino acid sequence homology to DGAT2. Expressional studies demonstrate that DGAT2 is 18-fold more highly expressed in seeds than in leaves and shows temporal specific expression during seed development. In contrast, DGAT1 shows little difference in expression in seeds versus leaves. We conclude that in castor bean DGAT2 is more likely to play a major role in seed TAG biosynthesis than DGAT1.

  7. Castor (Ricinus communis L. Tolerance to Postemergence Herbicides and Weed Control Efficacy

    Directory of Open Access Journals (Sweden)

    W. James Grichar

    2012-01-01

    Full Text Available Potential US castor production is limited due to only one labeled herbicide (trifluralin. Field studies were conducted at two Texas locations during 2008 and 2009 to evaluate postemergence herbicides for castor tolerance and weed control efficacy. Clethodim and fluazifop-P-butyl caused no castor stunting while acifluorfen, bentazon, imazethapyr, and lactofen caused stunting which ranged from 5 to 46%. Imazapic and 2,4-DB caused the greatest stunting (44 to 99% and resulted in castor yields of 0 to 45% of the untreated check. Acifluorfen, imazapic, imazethapyr, lactofen, and 2,4-DB controlled at least 80% smellmelon (Cucumis melo L. var. Dudaim Naud. while clethodim and fluazifop-P-butyl controlled at least 98% Texas millet [Urochloa texana (Buckl. R.Webster]. Imazapic and imazethapyr provided 57 to 75% Texas millet control. Results suggest that castor tolerance to the graminicides, clethodim, and fluazifop-P-butyl is high; however, castor injury and yield reductions with the postemergence applications of broadleaf herbicides suggest that these herbicides should not be used in castor production.

  8. seed oil

    African Journals Online (AJOL)

    Wara

    The foam height of the soap was found to be 2.0 cm which is lower than that of Jatropha oil soap(5.4cm), Sesame oil soap(4.8cm), Cotton seed oil soap(4.5cm) and shea nut soap(4.2cm),t higher than that of Castor oil soap(1.6cm) and Castor glycerine soap(1.4cm). The soap was milk in colour and slightly soluble in distilled ...

  9. Production of polyhydroxyalkanoates from waste frying oil by Cupriavidus necator.

    Science.gov (United States)

    Verlinden, Rob Aj; Hill, David J; Kenward, Melvin A; Williams, Craig D; Piotrowska-Seget, Zofia; Radecka, Iza K

    2011-06-10

    Polyhydroxyalkanoates (PHAs) are biopolymers, which can replace petrochemical plastics in many applications. However, these bioplastics are currently far more expensive than petrochemical plastics. Many researchers are investigating the use of inexpensive substrates derived from waste streams. Waste frying oil is abundant and can be used in PHA production without filtration.Cupriavidus necator (formerly known as Ralstonia eutropha) is a versatile organism for the production of PHAs. Small-scale batch fermentation studies have been set up, using different concentrations of pure vegetable oil, heated vegetable oil and waste frying oil. These oils are all rapeseed oils.It has been shown that Cupriavidus necator produced the homopolymer polyhydroxybutyrate (PHB) from the rapeseed oils. The achieved PHB concentration from waste frying oil was 1.2 g/l, which is similar to a concentration that can be obtained from glucose. The PHB harvest from pure oil and heated oil was 0.62 g/l and 0.9 g/l respectively. A feed of waste frying oil could thus achieve more biopolymer than pure vegetable oil. While the use of a waste product is beneficial from a life-cycle perspective, PHB is not the only product that can be made from waste oil. The collection of waste frying oil is becoming more widespread, making waste oil a good alternative to purified oil or glucose for PHB production.

  10. Bioemulsan Production by Iranian Oil Reservoirs Microorganisms

    Directory of Open Access Journals (Sweden)

    A Amiriyan, M Mazaheri Assadi, VA Saggadian, A Noohi

    2004-10-01

    Full Text Available The biosurfactants are believed to be surface active components that are shed into the surrounding medium during the growth of the microorganisms. The oil degrading microorganism Acinetobacter calcoaceticus RAG-1 produces a poly-anionic biosurfactant, hetero-polysaccharide bioemulsifier termed as emulsan which forms and stabilizes oil-water emulsions with a variety of hydrophobic substrates. In the present paper results of the possibility of biosurfactant (Emulsan production by microorganisms isolated from Iranian oil reservoirs is presented. Fourthy three gram negative and gram positive, non fermentative, rod bacilli and coccobacilli shaped baceria were isolated from the oil wells of Bibi Hakimeh, Siri, Maroon, Ilam , East Paydar and West Paydar. Out of the isolated strains, 39 bacterial strains showed beta haemolytic activity, further screening revealed the emulsifying activity and surface tension. 11 out of 43 tested emulsifiers were identified as possible biosurfactant producers and two isolates produced large surface tension reduction, indicating the high probability of biosurfactant production. Further investigation revealed that, two gram negative, oxidase negative, aerobic and coccoid rods isolates were the best producers and hence designated as IL-1, PAY-4. Whole culture broth of isolates reduced surface tension from 68 mN /m to 30 and 29.1mN/m, respectively, and were stable during exposure to high salinity (10%NaCl and elevated temperatures(120C for 15 min .

  11. A novel xyloglucan film-based biosensor for toxicity assessment of ricin in castor seed meal.

    Science.gov (United States)

    Furtado, R F; Alves, C R; Moreira, A C O; Azevedo, R M; Dutra, R F

    2012-06-20

    Oil from the seed of the castor plant (Ricinus communis L.) is an important commodity for a number of industries, ranging from pharmaceuticals to renewable energy resources. However, the seed and subsequent seed meal contain ricin (RCA60), a potent cytotoxin, making it an unusable product for animal feed. In order to investigate the efficiency of reducing the toxicity of the seed meal, a biosensor is proposed by exploring the lectin-carbohydrate binding. A gold electrode was assembled with a film of Xyloglucan (XG) extracted from Hymenaea courbaril L. The analytical response to RCA60 was obtained using a polyclonal antibody against RCA60 conjugated to peroxidase. The current responses were generated by reaction with H2O2 and amplified with hydroquinone as chemical mediator. Voltammetric studies showed that the XG film was tightly bound to the gold electrode. This biosensor allows discriminate lectins in native and denatured forms. The limit of detection of native RCA60 was 2.1 μg mL(-1). This proposed biosensor showed to be a potential and accurate method for toxicity assessment of the ricin in castor seed meal by simple polysaccharide film-electrode strategy. Copyright © 2012. Published by Elsevier Ltd.

  12. Effect of the organic matter and soil water deficit on the castor bean inflorescences emission

    Energy Technology Data Exchange (ETDEWEB)

    Lacerda, Rogerio Dantas de; Araujo, Ester Luiz de; Nascimento, Elka Costa Santos; Barros Junior, Genival [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Guerra, Hugo O. Carvallo; Chaves, Lucia Helena G. [Universidade Federal de Campina Grande (UAEAg/UFCG), PB (Brazil). Unidade Academica de Engenharia Agricola

    2008-07-01

    The castor bean culture has become important due to the several applications of its oil, which constitutes one of the best row materials for biodiesel manufacturing, and the base for several other industrial products. The objective of the present work was to study the effect of different soil water and soil organic matter on the castor bean inflorescence emission. The experiment was conducted from April to August 2006 under Greenhouse conditions using a randomized block 2x4 factorial design with two soil organic mater content (5.0 g.kg{sup -1} e 25.0 g.kg{sup -1}), four levels of available water (100, 90, 80 e 70% ) and three replicates. For this, 24 plastic containers, 75 kg capacity, were used on which was grown one plant 120 days after the seedling. When flowering occurred it was measured the number, the time required for the emission and the height of the emissions. The results were analyzed statistically; for the qualitative factor (with and without organic matter) the treatment means were compared through the Tukey test. For the quantitative ones (water levels) regressions were used. The time for the emission of the inflorescences was affected significantly by the organic matter and the available soil water content for plants. The number of inflorescences was affected positively by both treatments. (author)

  13. Poliuretanos elastoméricos obtenidos a partir de aceite de ricino y almidón de yuca original y modificado con anhídrido propiónico: síntesis, propiedades fisicoquímicas y fisicomecánicas Polyurethane elastomers from castor oil and chemically modified yucca starch: synthesis and physical-chemical, physical-mechanical and thermical properties

    Directory of Open Access Journals (Sweden)

    Manuel F. Valero

    2010-01-01

    Full Text Available Chemical modification of cassava starch was conducted through an acylation reaction by using pyridine and propionic anhydride to replace the functional groups of starch. Polyurethane elastomers were prepared using suspensions of the mixture obtained from castor oil and yucca starch that was modified by a propionic anhydride reaction. The suspensions were characterized by means of tests based on The Fourier Transform Infrared Spectroscopy and the Hydroxyl Index. The castor oil-AMP suspensions were used for the PU synthesis. The PUs were characterized by their physical-mechanical properties like tension- deformation and Shore A. hardness, thermal gravimetric analysis and swelling test. The density cross-linking of from swelling tests was determined by applying the Flory-Rehner equation.

  14. Biodegradable multifunctional oil production chemicals: Thermal polyaspartates

    Energy Technology Data Exchange (ETDEWEB)

    Ross, R.J. [Donlar Corporation (United States); Ravenscroft, P.D. [BP Exploration Operating Company, (United Kingdom)

    1996-12-31

    The paper deals with biodegradable oil production chemicals. Control of both mineral scale and corrosion with a single, environmentally acceptable material is an ambitious goal. Polyaspartate polymers represent a significant milestone in the attainment of this goal. Thermal polyaspartates (TPA) are polycarboxylate polymers derived via thermal condensation of the naturally occurring amino acid aspartic acid. These protein-like polymers are highly biodegradable and non-toxic, and are produced by an environmentally benign manufacturing process. TPAs exhibit excellent mineral scale inhibition activity and CO{sub 2} corrosion control. Laboratory data on scale inhibition and corrosion control in the North Sea oil field production applications is presented. 8 refs., 2 figs., 6 tabs.

  15. Optimization of Jatropha curcas pure plant oil production

    NARCIS (Netherlands)

    Subroto, Erna

    2015-01-01

    The use of pure plant oils as fuel, either directly or after conversion of the oil to bio-diesel, is considered to be one of the potential contributions to the transformation of the current fossil oil based economy to a sustainable bio-based one. The production of oil producing seeds using plants

  16. Opportunities in oil sands production bi-products

    Energy Technology Data Exchange (ETDEWEB)

    Gunardson, H. [Air Products Canada Ltd., Calgary, AB (Canada)

    2006-07-01

    This presentation investigated potential by-products from oil sands production and upgrading facilities, and examined the extent to which carbon dioxide (CO{sub 2}) enhanced oil recovery (EOR) projects can absorb greenhouse gas (GHG) emissions from oil sands developments. Oil sands production by-products included bitumen and petroleum coke; heat; hydrocarbon off-gases; hydrogen; syngas; sulfur; metals; and CO{sub 2} sources from combustion processes and hydrogen production. CO{sub 2} concentrations from flue gases are typically less than 17 per cent, and contain contaminants such as nitrogen, particulates, nitrogen oxide (NO{sub x}) and sulphur dioxide (SO{sub x}). CO{sub 2} concentrations derived from hydrogen production have a high purity and contain water vapour, unreacted hydrocarbons, hydrogen sulphide (H{sub 2}S) and volatile metals. Existing carbon capture technologies are currently not capable of processing large volumes of CO{sub 2}. However, small volumes of CO{sub 2} are used in the manufacturing of carbonated beverages. Larger volumes of CO{sub 2} are used in EOR and coalbed methane (CBM) recovery as well as in CO{sub 2} sequestration. Carbon capture technologies include amine scrubbers, selexol and rectisol gasification processes, and Benfield Catacarb processes. The market price for CO{sub 2} in EOR and gas recovery is approximately $35 per tonne. However, combustion processes typically cost $103 per tonne. CO{sub 2} sources and sinks were also identified. It is estimated that total CO{sub 2} sequestration using EOR will equal 200 mega tonnes by 2030. Apart from gasification processes, all CO{sub 2} sources are uneconomic using current technology. The oil sands industry is in need of a policy framework and support for infrastructure investments for CO{sub 2} pipelines and sequestration facilities. tabs., figs.

  17. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    Energy Technology Data Exchange (ETDEWEB)

    Anthony R. Kovscek; Louis M. Castanier

    2002-09-30

    The Stanford University Petroleum Research Institute (SUPRI-A) conducts a broad spectrum of research intended to help improve the recovery efficiency from difficult to produce reservoirs including heavy oil and fractured low permeability systems. Our scope of work is relevant across near-, mid-, and long-term time frames. The primary functions of the group are to conduct direction-setting research, transfer research results to industry, and educate and train students for careers in industry. Presently, research in SUPRI-A is divided into 5 main project areas. These projects and their goals include: (1) Multiphase flow and rock properties--to develop better understanding of the physics of displacement in porous media through experiment and theory. This category includes work on imbibition, flow in fractured media, and the effect of temperature on relative permeability and capillary pressure. (2) Hot fluid injection--to improve the application of nonconventional wells for enhanced oil recovery and elucidate the mechanisms of steamdrive in low permeability, fractured porous media. (3) Mechanisms of primary heavy oil recovery--to develop a mechanistic understanding of so-called ''foamy oil'' and its associated physical chemistry. (4) In-situ combustion--to evaluate the effect of different reservoir parameters on the insitu combustion process. (5) Reservoir definition--to develop and improve techniques for evaluating formation properties from production information. What follows is a report on activities for the past year. Significant progress was made in all areas.

  18. Biodiesel production and optimization from Calophyllum inophyllum linn oil (honne oil)--a three stage method.

    Science.gov (United States)

    Venkanna, B K; Venkataramana Reddy, C

    2009-11-01

    The present work examines the production of a biodiesel from a non-edible oil namely honne oil (Calophyllum inophyllum linn). A three stage process viz., pre-treatment, alkali catalyzed transesterification and post treatment adopted for the production is discussed. The reaction parameters such as methanol to oil molar ratio, catalyst concentration, temperature and time have been optimized for the production of biodiesel. The yield of biodiesel from the honne oil under the optimized conditions is found to be 89%.

  19. Marine Lipids (Omega-3 Oil) - Stability of Oil and Enriched Products During Production and Storage

    DEFF Research Database (Denmark)

    Nielsen, Nina Skall

    2015-01-01

    off-flavours and gives rise to unhealthy compounds such as free radicals and reactive aldehydes. Necessary prerequisites for successful development of omega-3 enriched products are that the oil used for enrichment is of a high quality and low in oxidation products and that oxidation of the lipids...... oxidation. As processing will often cause extra oxidative stress to the omega-3 oil, extrinsic factors are especially important to consider during processing. Due to the complexity of multiphase foods, it is very difficult to predict the oxidative stability and therefore the behaviour and efficacy...... of antioxidants in omega-3 oil enriched products and optimal composition and processing conditions must be evaluated for each product....

  20. CASTOR Calorimeter Installation Review at CMS

    CERN Multimedia

    CERN Video Productions

    2011-01-01

    This test is a part of CASTOR EDR process. The CASTOR phys-tech review held on 14 Jan 2011 and the subsequent EDR held on 17 Jun 2011, the CMS Management Board has endorsed a strategy in which CASTOR is removed during the 2011 Year-End Technical Stop, but is then refurbished, replacing a substantial fraction of the phototubes, so that it is ready for re-installation in the Technical Stop just before 2012 heavy-ion operation.

  1. Potential Development Essential Oil Production of Central Java, Indonesia

    Science.gov (United States)

    Alighiri, D.; Eden, W. T.; Supardi, K. I.; Masturi; Purwinarko, A.

    2017-04-01

    Indonesia is the source of raw essential oil in the world. Essential oils are used in various types of industries such as food and beverage, flavour, fragrance, perfumery, pharmaceuticals, and cosmetics. However, the development of Indonesian essential oil industry has not been encouraging for the production of essential oils, further it is unable to meet global demand. Besides that, the quality of volatile oil resulted cannot meet the international market standards. Based on the facts, the potential of Indonesian essential oils needs to be developed to provide added value, through increased production, improved quality and product diversification. One part of Indonesia having abundant of raw essential oil source is Central Java. Central Java has the quite large potential production of essential oils. Some essential oils produced from refining industry owned by the government, private and community sectors include cananga oils (Boyolali district), clove oils (Semarang district), patchouli oils (Brebes district, Pemalang district, and Klaten district). The main problem in the development of plants industries that producing essential oil in Central Java is low crops production, farming properties, quality of essential oils are diverse, providing poor-quality products and volatile oil price fluctuations. Marketing constraints of Central Java essential oils are quite complex supply chain. In general, marketing constraints of essential oils due to three factors, namely the low quality due to type of essential oil business that generally shaped small businesses with different capital and technology, domestic marketing is still a buyer-market (price determined by the buyer) because of weak bargaining position processors businessman, and prices fluctuate (domestic and foreign) due to uncontrolled domestic production and inter-country competition among manufacturers.

  2. Characterization of CRUDE OILS and petroleum products: (i) elution ...

    African Journals Online (AJOL)

    Some physical and chemical properties of samples of light, medium and heavy Nigerian crude oils and petroleum products including gasoline, kerosene and engine oil have been measured and are reported in this paper. The crude oils and petroleum products have also been characterized by fractional distillation and ...

  3. Substratos para produção de mudas de mamoneira compostos por misturas de cinco fontes de matéria orgânica Substrates for castor seedlings production composed by blends of five organic materials

    Directory of Open Access Journals (Sweden)

    Rosiane de Lourdes Silva de Lima

    2006-06-01

    Full Text Available O plantio de mamona (Ricinus communis L. através de mudas pode ser uma alternativa para um melhor aproveitamento da curta estação chuvosa do semi-árido brasileiro, porém ainda não se dispõe de informações básicas para o emprego desta técnica. Na formulação de substratos para produção de mudas de mamona, as características físicas, principalmente a aeração, são fatores de grande importância. O presente estudo objetivou avaliar a composição de substratos utilizando misturas de solo, esterco bovino, casca de amendoim, mucilagem de sisal, bagaço de cana e cama de frango. Utilizou-se delineamento em blocos casualizados com 12 tratamentos e quatro repetições. Sementes da cultivar BRS Nordestina foram semeadas em sacos plásticos de 17 x 28cm, contendo misturas dos materiais a serem testados. Valores de altura, área foliar, número de folhas e diâmetro caulinar foram registrados semanalmente entre 15 e 43 dias após a emergência. Na última coleta também se registraram a massa seca da parte aérea e das raízes. O substrato composto por solo + casca de amendoim + cama de frango + mucilagem de sisal propiciou o melhor crescimento das mudas. A cama de frango contribuiu para o enriquecimento químico do substrato, enquanto a casca de amendoim e a mucilagem de sisal contribuíram para adequar as características físicas de aeração e retenção de água.Planting castor (Ricinus communis L. by seedlings can be an alternative for a better use of the short rainy season at brazilian semi-arid region, however there has been a lack of information necessary for this technique adoption. Physics characteristics, mainly aeration, are very important in a substrate for castor seedlings production. A trial was run in a randomized block design with 12 treatments and 4 replications in order to evaluate substrates for castor seedlings production. Treatments were blends of sand, bovine manure, peanut hulls, agave mucilage, sugarcane bagasse

  4. CASTOR GSF packaging design criteria

    Energy Technology Data Exchange (ETDEWEB)

    Burnside, M.E.

    1996-08-06

    Encapsulated vitrified materials (Isotopic Heat Sources) are currently stored in the Pacific Northwest National Laboratories (PNNL) 324 Building located in the 300 Area. As part of the 324 Building transition program, the vitrified material, encapsulated in stainless steel canisters, must be removed. These canisters were originally intended to be used by the German government, but are no longer desired. As part of an agreement with the German government, the Germans are providing the U.S. Department of Energy (DOE) with six (6) CASTOR GSF and four (4) GNS-12 casks.The canisters will be transported onsite in CASTOR GSF and GNS-12 casks for interim storage until final disposition of the material is determined.

  5. Production of polyol oils from soybean oil by Pseudomonas aeruginosa E03-12.

    Science.gov (United States)

    Soy-polyols are important starting materials for the manufacture of polymers such as polyurethane. We have been trying to develop a bioprocess for the production of polyol oils directly from soybean oil. We reported earlier the polyol products produced from soybean oil by Acinetobacter haemolyticus ...

  6. Production of polyol oils from soybean oil by bioprocess and Philippines edible medicinal wild mushrooms

    Science.gov (United States)

    We have been trying to develop a bioprocess for the production of polyol oils directly from soybean oil. We reported earlier the polyol products produced from soybean oil by Acinetobacter haemolyticus A01-35 (NRRL B-59985) (Hou and Lin, 2013). The objective of this study is to identify the chemical ...

  7. Assessing the Comparative Advantage of Albanian Olive Oil Production

    OpenAIRE

    Mane-Kapaj, Ana; Kapaj, Ilir; Chan-Halbrendt, Catherine; Totojani, Orkida

    2010-01-01

    The main objective of this study is to evaluate the comparative advantage of olive oil production in Albania using Policy Analysis Matrix (PAM) method. The result indicates that olive oil production in Albania is profitable for the producers. Whereas the DRC ratio equals to 2.2, meaning that olive oil production in Albania does not have a comparative advantage for the given situation of production, prices and technology. This means that while it is profitable for private producers to manufact...

  8. Bio gas oil production from waste lard.

    Science.gov (United States)

    Hancsók, Jeno; Baladincz, Péter; Kasza, Tamás; Kovács, Sándor; Tóth, Csaba; Varga, Zoltán

    2011-01-01

    Besides the second generations bio fuels, one of the most promising products is the bio gas oil, which is a high iso-paraffin containing fuel, which could be produced by the catalytic hydrogenation of different triglycerides. To broaden the feedstock of the bio gas oil the catalytic hydrogenation of waste lard over sulphided NiMo/Al(2)O(3) catalyst, and as the second step, the isomerization of the produced normal paraffin rich mixture (intermediate product) over Pt/SAPO-11 catalyst was investigated. It was found that both the hydrogenation and the decarboxylation/decarbonylation oxygen removing reactions took place but their ratio depended on the process parameters (T = 280-380°C, P = 20-80 bar, LHSV = 0.75-3.0  h(-1) and H(2)/lard ratio: 600  Nm(3)/m(3)). In case of the isomerization at the favourable process parameters (T = 360-370°C, P = 40-50 bar, LHSV = 1.0  h(-1) and H(2)/hydrocarbon ratio: 400  Nm(3)/m(3)) mainly mono-branching isoparaffins were obtained. The obtained products are excellent Diesel fuel blending components, which are practically free of heteroatoms.

  9. Production of top quality soybean oil

    Directory of Open Access Journals (Sweden)

    Moustafa, Dr. Ahmad

    1995-12-01

    Full Text Available The paper comments the most adequate conditions required to produce to quality soybean oil. It is essential to avoid contaminations (water, metallic, oxidation products, overheating, undue exposition to air, as well as an appropriate control of the different steps of the refining process.

    El trabajo presenta las condiciones recomendadas para obtener aceite de soja de la mejor calidad. Es importante evitar las contaminaciones (agua, metales y compuestos oxidados, los sobrecalentamientos, la exposición al aire, así como el adecuado control de los diferentes pasos del proceso de refinación.

  10. By-products of palm oil extraction and refining

    Directory of Open Access Journals (Sweden)

    Tan Yew-Ai

    2006-01-01

    Full Text Available This paper outlines the utilisation of by-products resulting from the extraction and refining of palm oil. It summarises research by the Malaysian Palm Oil Board (MPOB directed at producing zero waste from the palm oil industry. MPOB regards by-products of the palm oil industry not as waste but resources. It will be evident that by-products from the palm oil industry can be and have been used extensively and that the research carried out is relevant to both the milling and refining sectors.

  11. Effects of Oganic and Biofertilizers on Growth Indices of Castor Bean (Ricinus communis L.

    Directory of Open Access Journals (Sweden)

    A Amin Ghafori

    2016-07-01

    Full Text Available Introduction Castor plant, Ricinus communis L. is a species of flowering plant in the spurge family; Euphorbiaceae, which contains a vast number of plants mostly native to the tropics. It belongs to a monotypic genus Ricinus. The name Ricinus is a latin word for tick. The plant is probably named because its seed has markings and a dump at the end that resemble certain ticks (NCRI, 2014. Castorbean is an industrial oil seed crop containing about 45-58 percent oil, which has tremendous application in petrochemicals, pharmaceuticals, cosmetics, textiles, chemicals, soap, leather, paints, varnishes, ink, nylon and plastic. Castor oil is traditionally associated with medicine and veterinary use in the fields of obstetrics, dermatology. It is also used as laxative. Presently, its utilization as bio-diesel has magnified its importance. Its oil does not freeze even at high altitudes and it is one the best lubricants for jet engines. This 100% castor-based product, has numerous applications in industry such as rotating glass car-wipers, ski boots fixatives, and for use in air-brake systems on trucks. Many new uses, based on the biodegradability of castor oil derived products, are expected in the future (Labalette et al., 1996. The shell of the castor bean is used as an organic termite control agent and its seed cake as manure in the soil. Medicinal plants are valuable resources in a wide range of natural resources that scientific identification, cultivation, development and proper utilization of them can have an important role in community health, employment and non-petrol exports. Quality of medicinal plants is more important than other crops. One of the most important factors determining the yield of castor bean is fertility. Integrated supply of nutrient to plants through combinations of organic and inorganic sources is becoming an increasingly important aspect of environmentally sound agriculture. Reports showed that the application of manure on bean

  12. Genome-wide survey and expression profiles of the AP2/ERF family in castor bean (Ricinus communis L.).

    Science.gov (United States)

    Xu, Wei; Li, Fei; Ling, Lizhen; Liu, Aizhong

    2013-11-13

    The AP2/ERF transcription factor, one of the largest gene families in plants, plays a crucial role in the regulation of growth and development, metabolism, and responses to biotic and abiotic stresses. Castor bean (Ricinus communis L., Euphobiaceae) is one of most important non-edible oilseed crops and its seed oil is broadly used for industrial applications. The available genome provides a great chance to identify and characterize the global information on AP2/ERF transcription factors in castor bean, which might provide insights in understanding the molecular basis of the AP2/ERF family in castor bean. A total of 114 AP2/ERF transcription factors were identified based on the genome in castor bean. According to the number of the AP2/ERF domain, the conserved amino acid residues within AP2/ERF domain, the conserved motifs and gene organization in structure, and phylogenetical analysis, the identified 114 AP2/ERF transcription factors were characterized. Global expression profiles among different tissues using high-throughput sequencing of digital gene expression profiles (DGEs) displayed diverse expression patterns that may provide basic information in understanding the function of the AP2/ERF gene family in castor bean. The current study is the first report on identification and characterization of the AP2/ERF transcription factors based on the genome of castor bean in the family Euphobiaceae. Results obtained from this study provide valuable information in understanding the molecular basis of the AP2/ERF family in castor bean.

  13. Polymers in crude oil and products

    Energy Technology Data Exchange (ETDEWEB)

    Lonstrup, T.F.; Taillardat, J.; Turner, D.W.

    1980-01-01

    The work describes applications of polymers classified by petroleum end uses. Approximately 1200 literature references have been reviewed, 60% of which deal with applications in lubricants. Polymers are being used as additives for many phases of crude production, transportation, and processing. This includes improved drilling, flow behavior, recovery, desalting, and dehydration. For engine lubricants, the major use of polymers is still as viscosity modifiers. New types of viscosity index polymers are described. Most of the past 4 yr research effort in the lubricants area has dealt with the rheology of multigrade oils, particularly the temporary loss of viscosity under high shear rates and its effects on engine performance. In industrial lubricants, polymers increase load-carrying capacity; control wear, rust and foam; improve cold properties; reduce energy requirements and mist emissions; and modify surface active properties. Polymers are used in fuel products mainly to improve handling and stability debits. 253 references.

  14. Phytomass production of the castor bean under different soil water reposition levels and organic matter content; Producao de fitomassa da mamoneira Paraguacu sob diferentes niveis de reposicao de agua e materia organica do solo

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Larissa C.; Lacerda, Rogerio D. de; Guerra, Hugo Orlando C.; Almeida, Flavio R. dos S. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)], Emails: laris_almeida@yahoo.com.br, rogerio_dl@yahoo.com.br, hugo_carvallo@hotmail.com, flavio_rangel@yahoo.com.br; Barros Junior, Genival [Universidade Federal Rural de Pernambuco (UFRPE), Serra Talhada, PE (Brazil)], E-mail: barrosjnior@yahoo.com.br

    2010-07-01

    The Castor bean crop has obtained notoriety in Brazil due to its insertion on the biodiesel production. Exigent in fertility, shows growth reduction under negative conditions, obtaining, otherwise, increase of production with the use of organic fertilization. Besides the increase on soil water retention, the organic matter improves the physical properties of the soil increasing its aeration allowing thus a better penetration and distribution of the roots. The experiment had as objective to study the effect of available soil water for plants and organic matter on the phytomass production. It was conducted on the field during the period of October 2008 to March 2009 using an experimental design 2 x 4 factorial on a randomized-complete block design, constituted of two soil organic matter contents (5.0 g.kg{sup -1} and 25.0 g.kg{sup -1}) and four soil water contents (100, 90, 80 and 70% of the soil available water for the plants) with 3 replicates. On each 100 m{sup 2} parcel 50 plants were cultivated until 180 days after the sowing, DAS. The analyses of variance allowed to observe that the addition of organic matter increased the phytomass production on a 14,51% and that the available water produced an increment of 50% when the water levels were elevated from 70 to 100%. (author)

  15. Challenges and Prospects of Smallholder Oil Palm Production in ...

    African Journals Online (AJOL)

    The study examined the challenges and prospects of smallholder oil palm production in Awka Agricultural Zone of Anambra State. Seventy two smallholder oil palm farmers were interviewed for the purpose of eliciting information. Smallholder oil palm farmers in Awka Agricultural Zone were educated (79.2% - Senior ...

  16. RISK ANALYSIS APPLIED IN OIL EXPLORATION AND PRODUCTION

    African Journals Online (AJOL)

    ES Obe

    projects. Although the use of risk management techniques does not reduce the uncertainty in Oil field projects; it reduces the impact of the losses should an unfavourable event occur. Keywords: risk analysis, oil field, risk management, projects, investment opportunity. 1. Introduction. The Oil Exploration and Production is a.

  17. Effect Of Weed On Oil Palm Inflorenscence Production: Implication ...

    African Journals Online (AJOL)

    Weed consistently depressed the performance of oil palm and this depressive effect was attributed to aggressive growth resources, smothering of the oil palm and preventing the palm from proper ventilation and solar radiation. Weed interference on inflorescence production of oil palm was assessed with the view of ...

  18. Market analysis of shale oil co-products. Appendices

    Energy Technology Data Exchange (ETDEWEB)

    1980-12-01

    Data are presented in these appendices on the marketing and economic potential for soda ash, aluminia, and nahcolite as by-products of shale oil production. Appendices 1 and 2 contain data on the estimated capital and operating cost of an oil shales/mineral co-products recovery facility. Appendix 3 contains the marketing research data.

  19. Crescimento e produção de bagas da mamoneira irrigada com água residuária doméstica Growth and production of seeds of castor bean crop irrigated with domestic wastewater

    Directory of Open Access Journals (Sweden)

    Luis N. Rodrigues

    2009-12-01

    Full Text Available Objetivou-se avaliar os efeitos da irrigação com água de esgoto doméstico sobre o crescimento e a produção de bagas da mamoneira (Ricinus communis L, em ambiente protegido. A pesquisa foi desenvolvida entre novembro/2005 e maio/2006, no Centro de Tecnologia e Recursos Naturais (CTRN da UFCG-PB. Foram estudados 5 níveis de reposição da evapotranspiração da cultura - ETc, (0,60, 0,75, 0,90, 1,05 e 1,20 em duas cultivares de mamoneira (BRS Nordestina e BRS Paraguaçu, constituindo um fatorial 5 x 2, com três repetições, no delineamento estatístico de blocos ao acaso. Avaliaram-se altura de planta, diâmetro caulinar, número de folhas e área foliar aos 48, 90, 132 e 174 dias após a semeadura (DAS. A produção de sementes foi avaliada na última data. A mamoneira irrigada com 0,60 ETc, em relação a 1,05 da ETc, aos 174 DAS, teve a altura de planta, o diâmetro caulinar, o número de folhas, a área foliar e produção de sementes reduzidos em 23,45, 16,14, 26,23, 44,06 e 50,59%, respectivamente. O crescimento em altura da cultivar BRS Paraguaçu foi significativamente maior, ao longo do ensaio, enquanto a BRS Nordestina se destacou em área foliar, no início do ciclo. A produção de bagas foi semelhante nas duas cultivares Não houve interação significativa entre os fatores estudados.The objective of this study was to evaluate the impacts of irrigation with domestic wastewater on growth and production of seeds of castor bean (Ricinus communis L in greenhouse. The research was carried out between November, 2005 and May, 2006, at Centro de Tecnologia e Recursos Naturais (CTRN of UFCG - PB. A randomized block design was used, with 5 x 2 scheme of factorial analysis with three replications, testing 5 levels of replacement of crop evapotranspiration - ETc (0.60, 0.75, 0.90, 1.05 and 1.20 ETc and 2 cultivars of castor bean (BRS Nordestina and BRS Paraguaçu. Plant height, stem diameter, number of leaves and leaf area were evaluated

  20. State and trends of oil crops production in China

    Directory of Open Access Journals (Sweden)

    Yang Tiankui

    2016-11-01

    Full Text Available This paper attempts to present a full picture of current situation and future trends of Chinese oil crop production. The total oil crop production remained broadly constant during 2011–2014. The top three oil crops are soybean, peanut and rapeseed, together accounting for more than 70% of total oil crop production. The area under cultivation and the production of peanuts will keep steadily increasing because most Chinese like its pleasant roasted flavor. Because of their high content in polyunsaturated fatty acids and the natural minor functional components in their oils, more attention is being paid to sunflower seed and rice bran. The diminishing availability of arable land and concern over the security of edible oil supplies is driving both a change in cultivation structure of crops and improvements in the efficiency of oilseed production in China.

  1. A comparative economic evaluation of annual castor, sorghum and ...

    African Journals Online (AJOL)

    Conséquement le dernier pourrait être acceptable comme une culture de sécurité alimentaire plutôt qu' une culture de rente, même dans les conditions semi-arides, bien que les rendements et le prix du marché informel payé au fermier restent très faibles. Les résultats ont montré aussi que la production du castor était plus ...

  2. Life Cycle Assessment for the Production of Oil Palm Seeds.

    Science.gov (United States)

    Muhamad, Halimah; Ai, Tan Yew; Khairuddin, Nik Sasha Khatrina; Amiruddin, Mohd Din; May, Choo Yuen

    2014-12-01

    The oil palm seed production unit that generates germinated oil palm seeds is the first link in the palm oil supply chain, followed by the nursery to produce seedling, the plantation to produce fresh fruit bunches (FFB), the mill to produce crude palm oil (CPO) and palm kernel, the kernel crushers to produce crude palm kernel oil (CPKO), the refinery to produce refined palm oil (RPO) and finally the palm biodiesel plant to produce palm biodiesel. This assessment aims to investigate the life cycle assessment (LCA) of germinated oil palm seeds and the use of LCA to identify the stage/s in the production of germinated oil palm seeds that could contribute to the environmental load. The method for the life cycle impact assessment (LCIA) is modelled using SimaPro version 7, (System for Integrated environMental Assessment of PROducts), an internationally established tool used by LCA practitioners. This software contains European and US databases on a number of materials in addition to a variety of European- and US-developed impact assessment methodologies. LCA was successfully conducted for five seed production units and it was found that the environmental impact for the production of germinated oil palm was not significant. The characterised results of the LCIA for the production of 1000 germinated oil palm seeds showed that fossil fuel was the major impact category followed by respiratory inorganics and climate change.

  3. Supply chain management of the castor biodiesel in the Bahia state, Brazil; Gestao da cadeia de suprimentos do biodiesel de mamona no estado da Bahia

    Energy Technology Data Exchange (ETDEWEB)

    Freires, Francisco G.M.; Goncalo, Thomas E.E.; Oliveira, Danillo R.S.B. [Universidade Federal do Vale do Sao Francisco (UNIVASF), Juazeiro, BA (Brazil)], E-mail: francisco.gaudencio@univasf.edu.br

    2009-07-01

    In front of the global trend for developing new ways of energy that pollute less and are renewable, Brazil emerges as a major actor in the development and use of technology for the production of biofuels. In the context of the potential of semi-arid to produce some oil used in production, the Brazilian government is enabling the production of Northeastern region. The State of Bahia is the largest producer of castor oil from Brazil, with an estimated production of 102.8 thousand tonnes of grain in the season 2008/2009 (CONAB, 2009). The development of the sector depends on appropriate government actions to support their competitive sustainability, and encouraging the improvement of management techniques in all involved. In that scenario, the logistics contributes to the development of this sector through the supply chain management. One conclusion is that the competitiveness and sustainability of the supply chain of castor in the Semi-arid of Bahia practices depends on the adoption of integrated logistics, without which the current failures prevent the consolidation of governmental objectives defined. (author)

  4. Ethyl ester production from (RBD palm oil

    Directory of Open Access Journals (Sweden)

    Oscar Mauricio Martínez Ávila

    2010-07-01

    Full Text Available This work develops a methodology for obtaining ethyl esters from RBD (refined, bleached and deodorised palm oil by evaluating the oil’s transesterification and separation. Two catalysts were first tested (KOH and NaOH by studying the effect of water presence on the reaction. The separation process was then evaluated by using water and water-salt and water-acid mixtures, establishing the agent offering the best results and carrying out the purification stage. Raw materials and products were characterised for comparing the latter with those obtained by traditional means and verifying the quality of the esters so produced; minimum differences were found bet-ween both. The proposed methodology thus allows esters to be used as raw material in petrochemical industry applications. A more profitable process can be obtained compared to those used today, given the amounts of separation agent so established (1% H3PO4 solution, in water. The overall process achieved 74.4% yield, based on the oil being used.

  5. Alternatif Pembuatan Biodiesel Melalui Transesterifikasi Minyak Castor (Ricinus communis Menggunakan Katalis Campuran Cangkang Telur Ayam dan Kaolin

    Directory of Open Access Journals (Sweden)

    Soni - Setiadji

    2017-05-01

    Full Text Available Biodiesel was produced by transesterification of castor oil (Ricinus communis using a catalyst of CaO and kaolin (CaO / kaolin had been performed. CaO was obtained from the calcination of eggshell. Castor oil is selected as biodiesel feedstock because it belongs to non-food oil and easy to cultivate. In general, the research method aims to comprise the CaO / Kaolin catalysts with a ratio of 15 mmol CaO per 1 gram of kaolin activated using impregnation method and biodiesel produced through transesterification of castor oil using the catalyst at 65 ºC for 8 hours with ratio of castor oil: methanol: catalyst (1: 15: 5% w / w. The reaction is carried out on the reflux system. The XRD analysis show the presence of silica and potassium aluminum silicate hydroxide in the catalyst. The EDS results show the catalyst-forming components CaO and silica. The FTIR analysis results show the absorption peak in the functional group forming the methyl ester compound. Based on the characterization of GC-MS, the largest methyl ester components contained in biodiesel are methyl risinoleate, methyl elaidat, methyl stearate, methyl linoleate, and methyl palmitate. The overall conversion of castor oil to methyl ester using CaO / kaolin catalyst is 97.36%. The largest component in castor oil is risinoleic acid, has been successfully converted to methyl risinoleate by 74.75%.DOI: http://dx.doi.org/10.15408/jkv.v0i0.4778

  6. Study on Emission and Performance of Diesel Engine Using Castor Biodiesel

    Directory of Open Access Journals (Sweden)

    Md. Saiful Islam

    2014-01-01

    performance of diesel engine using the castor biodiesel and its blend with diesel from 0% to 40% by volume. The acid-based catalyzed transesterification system was used to produce castor biodiesel and the highest yield of 82.5% was obtained under the optimized condition. The FTIR spectrum of castor biodiesel indicates the presence of C=O and C–O functional groups, which is due to the ester compound in biodiesel. The smoke emission test revealed that B40 (biodiesel blend with 40% biodiesel and 60% diesel had the least black smoke compared to the conventional diesel. Diesel engine performance test indicated that the specific fuel consumption of biodiesel blend was increased sufficiently when the blending ratio was optimized. Thus, the reduction in exhaust emissions and reduction in brake-specific fuel consumption made the blends of caster seed oil (B20 a suitable alternative fuel for diesel and could help in controlling air pollution.

  7. Crescimento e produtividade da mamoneira irrigada com diferentes diluições de esgoto doméstico tratado Growth and production of castor bean irrigated with different dilutions of domestic wastewater

    Directory of Open Access Journals (Sweden)

    Mário C. de F. Ribeiro

    2012-06-01

    Full Text Available Objetivou-se avaliar, neste trabalho, os efeitos da irrigação com água de esgoto doméstico sobre as variáveis de crescimento e produtividade da mamoneira, genótipo EBDA MPB 01, em condições de campo. A pesquisa foi realizada no período de dezembro de 2009 a junho 2010, na Universidade Federal do Recôncavo da Bahia, Campus de Cruz das Almas. Foram estudadas quatro diferentes proporções de diluição de esgoto doméstico tratado em comparação com o tratamento testemunha (adubação e irrigação convencional, da seguinte forma: T1 - 100% do efluente tratado; T2 - 75% do efluente tratado mais 25% de água de poço artesiano; T3 - 50% do efluente tratado mais 50% de água de poço artesiano; T4 - 25% do efluente tratado mais 75% de água de poço artesiano e T5 - manejo convencional (adubação química e irrigação suplementar com água de poço artesiano. O delineamento experimental foi em blocos casualizados (DBC com quatro blocos cada tratamento, constituindo de 20 parcelas experimentais. A produtividade da mamoneira não apresentou diferença estatística entre os tratamentos. O uso de água residuária de esgoto doméstico na cultura da mamoneira, não afetou as variáveis de crescimento analisadas.The effects of the irrigation with domestic wastewater effluent on the growth variables and the productivity of castor bean, genotyps EBDA MPB 01, were evaluated under field conditions. The research was carried out from December 2009 to June 2010, at UFRB experimental area, in Cruz das Almas, BA. Four different proportions of dilution of domestic wastewater effluent in comparison with the conventional treatment were studied, in the following way: T1 - 100% of the treated effluent; T2 - 75% of the effluent +25% of artesian well water; T3 - 50% of the efluent +50% of artesian well water; T4 - 25% of the effluent +75% of artesian well water; T5 - conventional treatment (chemical fertilization and supplementary irrigation with water of

  8. Hydrogenated Castor Oil-Gum Tragacanth

    African Journals Online (AJOL)

    equation, at pH 2.5, propranolol hydrochloride is almost ilOO% ionized while at pH 7.6 it is. 98.76% ionized. The pH of distilled water is approximately 6.5 hence intermediate releases as shown in Figure 1. This difference in percentage ionization with pH might explain the difference in the release profiles. However, previous.

  9. Palm oil based surfactant products for petroleum industry

    Science.gov (United States)

    Permadi, P.; Fitria, R.; Hambali, E.

    2017-05-01

    In petroleum production process, many problems causing reduced production are found. These include limited oil recovery, wax deposit, asphaltene deposit, sludge deposit, and emulsion problem. Petroleum-based surfactant has been used to overcome these problems. Therefore, innovation to solve these problems using surfactant containing natural materials deserves to be developed. Palm oil-based surfactant is one of the potential alternatives for this. Various types of derivative products of palm oil-based surfactant have been developed by SBRC IPB to be used in handling problems including surfactant flooding, well stimulation, asphaltene dissolver, well cleaning, and wax removal found in oil and gas industry.

  10. Biosurfactant production by Mucor circinelloides on waste frying oil and possible uses in crude oil remediation.

    Science.gov (United States)

    Hasanizadeh, Parvin; Moghimi, Hamid; Hamedi, Javad

    2017-10-01

    Biosurfactants are biocompatible surface active agents which many microorganisms produce. This study investigated the production of biosurfactants by Mucor circinelloides. The effects of different factors on biosurfactant production, including carbon sources and concentrations, nitrogen sources, and iron (II) concentration, were studied and the optimum condition determined. Finally, the strain's ability to remove the crude oil and its relationship with biosurfactant production was evaluated. The results showed that M. circinelloides could reduce the surface tension of the culture medium to 26.6 mN/m and create a clear zone of 12.9 cm diameter in an oil-spreading test. The maximum surface tension reduction was recorded 3 days after incubation. The optimum condition for biosurfactant production was achieved in the presence of 8% waste frying oil as a carbon source, 2 g/L yeast extract as a nitrogen source, and 0.01 mM FeSO4. M. circinelloides could consume 8% waste frying oil in 5 days of incubation, and 87.6% crude oil in 12 days of incubation. A direct correlation was observed between oil degradation and surface tension reduction in the first 3 days of fungal growth. The results showed that the waste frying oil could be recommended as an inexpensive oily waste substance for biosurfactant production, and M. circinelloides could have the potential to treat waste frying oil. According to the results, the produced crude biosurfactant or fungal strain could be directly used for the mycoremediation of crude oil contamination in oil fields.

  11. Non-destructive determination of photosynthetic pigments in the leaves of castor oil plants=Determinação não destrutiva de pigmentos da fotossíntese em folhas de mamoneira

    Directory of Open Access Journals (Sweden)

    Fabíola Vanessa de França

    2012-07-01

    Full Text Available The aim of the present work was to determine the relationship between photosynthetic pigments extracted in dimethyl sulfoxide (DMSO and readings obtained by the portable chlorophyll meter, ClorofiLOG® 1030, to generate mathematical models that are able to report the contents of chlorophyll and carotenoids in the leaves of the castor oil plant. This work was conducted at Embrapa Cotton, located in the city of Campina Grande, state of Paraíba, Brazil, in October 2010. For the indirect analysis, portable equipment was used to read leaf discs of different shades of green. The chlorophyll in these discs was then determined using a classical method: 5 mL of DMSO was added, the samples were incubated in a water bath at 70ºC for 30 minutes, and a 3 mL aliquot was removed for spectrophotometric measurements at 470, 646 and 663 nm. The data were subjected to analysis of variance and regression analyses in which the readings obtained using the portable chlorophyll meter were the dependent variable and the photosynthetic pigments that were determined by the classical method were the independent variable. The results indicated that, with the exception of chlorophyll b, the ClorofiLOG® 1030 portable chlorophyll meter estimated the concentration of photosynthetic pigments with high precision, thus saving time and the chemical reagents that are typically used in conventional procedures.Objetivou-se com o presente trabalho, estabelecer a relação entre os pigmentos fotossintéticos extraídos em DMSO e as leituras obtidas no clorofilômetro portátil ClorofiLOG® 1030, gerando modelos matemáticos capazes de predizer os teores de clorofila e de carotenóides em folhas de mamoneira. O trabalho foi conduzido na Embrapa Algodão, situada em Campina Grande, Estado da Paraíba, em outubro de 2010. Para a análise indireta, foi utilizado um equipamento portátil, sendo realizada a leitura em discos foliares com diferentes tonalidades de verde, sendo feita, nesses

  12. Resposta tecidual a implantes de discos de poliuretana de mamona nas formas pré-moldada ou biomassa moldada Tissue reaction to premolded or molded biomass disks of polyurethanes containing castor oil

    Directory of Open Access Journals (Sweden)

    Samanta Aires Celeste

    2010-12-01

    Full Text Available O trabalho teve por objetivo avaliar a resposta tecidual à implantação de discos de poliuretana derivada do óleo de mamona confeccionados de duas formas distintas, na forma pré-moldada fornecida pela indústria e em biomassa moldada no momento da aplicação, de forma a observar se haveria algum tipo de reação local tardia associada à possível continuidade do processo de endurecimento final do biomaterial. Foram utilizados 20 ratos, linhagem Wistar, fêmeas, com peso de 300-350g, nos quais foi inserido o disco pré-moldado no tecido subcutâneo do flanco direito e o de biomassa moldada no flanco esquerdo. Ambos os discos tinham 0,8cm de diâmetro por 0,5cm de espessura. Para o procedimento histológico, cinco ratos foram submetidos à eutanásia aos 3, 7, 15 e 30 dias de pós-cirúrgico. Os implantes e tecidos circundantes foram colhidos, processados e corados pela técnica de hematoxilina-eosina. Foi observada inicialmente uma reação inflamatória moderada, composta especialmente por células polimorfonucleares e macrófagos. Os linfócitos variaram de ausentes a discretos. A reação inflamatória diminui de intensidade à medida que se intensificou a formação de tecido conjuntivo fibroso ao redor dos implantes, porém sem modificação dos números de macrófagos. Sendo assim, conclui-se que ambos os discos de poliuretana induzem uma reação inflamatória similar, que varia de moderada a discreta na dependência do momento de avaliação.The aim of this study was to histologically evaluate the tissue reaction to implantation of polyurethane disks containing castor oil produced in premolded form, supplied commercially, and biomass molded at the moment of application; since a late tissue reaction may occur during the total hardening process of the biomaterial. Twenty female Wistar rats, about 3 months of age, weighing 300-350g, and polyurethane disks 0.8cm in diameter and 0.5cm in thickness were used. The premolded disk was

  13. Poliuretana de mamona (Ricinus communis para desvio da crista tibial no cão Polyurethane resins derived from castor oil (Ricinus communis for tibial crest deviation in dogs

    Directory of Open Access Journals (Sweden)

    Patricia Popak Maria

    2004-06-01

    Full Text Available A luxação medial de patela é uma das principais afecções ortopédicas que afetam cães de raças de pequeno porte. Tendo como princípio que o desvio da crista tibial é uma das alterações anatômicas encontradas, este estudo objetivou avaliar o efeito da poliuretana de mamona (Ricinus communis aplicada em defeitos produzidos experimentalmente na porção proximal medial da tíbia de cães normais em fase de crescimento. Para isto, foram utilizados 12 cães subdivididos aleatoriamente em 3 grupos de igual número, com mesmo tratamento, mas com análise histopatológica aos 30 (GI, 60 (GII e 90 (GIII dias. O estudo constou de avaliações clínica, radiográfica, macroscópica, histopatológica, tomográfica e análise estatística. Avaliação clínica demonstrou não haver rejeição do implante. A análise radiográfica revelou intensa reação periosteal e neoformações ósseas no local da implantação. Macroscopicamente observou-se espessamento da crista tibial, neoformações ósseas e desvio lateral da crista. Os achados à microscopia óptica revelaram presença de tecido conjuntivo fibroso ao redor da poliuretana, ausência de proliferação óssea em direção ao implante e proliferação de periósteo na face medial das tíbias. A tomografia computadorizada revelou desvio lateral da crista em 11 animais e estes desvios foram estatisticamente significantes em nível de 5% por meio do teste t pareado.Medial patellar luxation is one of the most common orthopedic problems in small breeds of dogs and tibial crest deviation is a frequent accompaining anatomical abnormality. For that reason, the purpose of this study was to evaluate the behavior of castor oil derived polyurethane implants when apllied to experimental defects created on the medial side of the proximal tibia of normal puppies. Twelve dogs were randomly divided in 3 groups of 4 animals and were submitted to the same treatment. Histopathological study was performed

  14. HEAVY-OIL PRODUCTION USING EMULSION FLOODING

    African Journals Online (AJOL)

    user

    Several researchers have found it difficult to achieve oil in-water (O/W) emulsion stability status. In an effort to minimize the viscosity, heavy crude needs modification. The morphology and stability of oil-in-water emulsions were studied as a function of aqueous phase salinity. In reducing the viscosity of the heavy-oil, brine.

  15. Oil extraction from plant seeds for biodiesel production

    Directory of Open Access Journals (Sweden)

    Yadessa Gonfa Keneni

    2017-04-01

    Full Text Available Energy is basic for development and its demand increases due to rapid population growth, urbanization and improved living standards. Fossil fuels will continue to dominate other sources of energy although it is non-renewable and harm global climate. Problems associated with fossil fuels have driven the search for alternative energy sources of which biodiesel is one option. Biodiesel is renewable, non-toxic, environmental-friendly and an economically feasible options to tackle the depleting fossil fuels and its negative environmental impact. It can be produced from vegetable oils, animal fats, waste oils and algae. However, nowadays, the major feedstocks of biodiesel are edible oils and this has created food vs fuel debate. Therefore, the future prospect is to use non-edible oils, animal fats, waste oils and algae as feedstock for biodiesel. Selection of non-expensive feedstock and the extraction and preparation of oil for biodiesel production is a crucial step due to its relevance on the overall technology. There are three main conventional oil extraction methods: mechanical, chemical/solvent and enzymatic extraction methods. There are also some newly developed oil extraction methods that can be used separately or in combination with the conventional ones, to overcome some disadvantages of the conventional oil extraction methods. This review paper presents, compare and discusses different potential biofuel feedstocks, various oil extraction methods, advantages and disadvantages of different oil extraction methods, and propose future prospective for the improvement of oil extraction methods and sustainability of biodiesel production and utilization.

  16. Evaluation of castor oil-based polyurethane membranes in rat bone-marrow cell culture Avaliação de membranas à base de óleo de polímero de mamona em culturas de células de medula óssea de ratos

    Directory of Open Access Journals (Sweden)

    Sofia de Amorim Cerejo

    2011-10-01

    Full Text Available PURPOSE: To evaluate three methods to isolate rats MSCs and to analyze the potential of a castor oil polyurethane base membrane as a scaffold for MSCs. METHODS: Four male Wistar rats, aged 20-30 days were used. Bone marrow aspirates from femur and tibia were harvested using DMEM high glucose and heparin. The cell culture was performed in three different ways: direct culture and two types of density gradients. After 15 days, was made the 1st passage and analyzed cell viability with markers Hoerscht 33342 and propidium iodide. The MSCs were characterized by surface markers with the aid of flow cytometry. After this, three types of castor oil polyurethane membranes associated with the MSCs were kept on the 6-well plate for 5 days and were analyzed by optical microscopy to confirm cell aggregation and growth. RESULTS: Separation procedures 1 and 2 allowed adequate isolation of MSCs and favored cell growth with the passage being carried out at 70% confluence after 15 days in culture. The cells could not be isolated using procedure 3. When the 3 castor oil polyurethane membrane types were compared it was possible to observe that the growth of MSCs was around 80% in membrane type 3, 20% in type 2, and 10% in type 1. CONCLUSION: Both Ficoll-Hypaque densities allow isolation of rat MSCs, and especially castor oil-based membrane type 3 may be used as a scaffold for MSCs.OBJETIVO: Avaliar três formas de cultivo de células-tronco mesenquimais de ratos; e analisar o potencial do polímero de mamona na forma de membrana como arcabouço para CTMs. MÉTODOS: Foram utilizados quatro ratos machos Wistar, de 20 a 30 dias de idade. Aspirados da medula óssea do fêmur e da tíbia foram colhidos com DMEM alta glicose e heparina. As células foram isoladas de três formas diferentes: cultivo direto e com dois tipos de gradientes de densidade. Após 15 dias, foi feita a 1ª passagem e analisada a viabilidade celular com os marcadores Hoerscht 33342 e Iodeto de Prop

  17. Improving environmental sustainability of Thai palm oil production in 2050

    NARCIS (Netherlands)

    Saswattecha, Kanokwan; Kroeze, Carolien; Jawjit, Warit; Hein, Lars

    2017-01-01

    Palm oil production has increased in Thailand with considerable environmental impacts. The aim of this study is to analyse possibilities to examine how the environmental sustainability of Thai palm oil production can be improved in the coming decades. To this end, we integrated a sectoral and a

  18. Biodiesel production from Jatropha curcas oil catalyzed by whole ...

    African Journals Online (AJOL)

    ... optimal biodiesel production were found to be 1:3 oil:methanol molar ratio at 30°C with constant stirring at 250 rpm. Under these conditions a maximum fatty acid methyl ester (biodiesel) production level of 71.8% was obtained after 72 h. Keywords: Lipase, Aureobasidium pullulans, physic nut oil, biodiesel, green energy

  19. Impact of heavy metals on the oil products biodegradation process.

    Science.gov (United States)

    Zukauskaite, Audrone; Jakubauskaite, Viktorija; Belous, Olga; Ambrazaitiene, Dalia; Stasiskiene, Zaneta

    2008-12-01

    Oil products continue to be used as a principal source of energy. Wide-scale production, transport, global use and disposal of petroleum have made them major contaminants in prevalence and quantity in the environment. In accidental spills, actions are taken to remove or remediate or recover the contaminants immediately, especially if they occur in environmentally sensitive areas, for example, in coastal zones. Traditional methods to cope with oil spills are confined to physical containment. Biological methods can have an advantage over the physical-chemical treatment regimes in removing spills in situ as they offer biodegradation of oil fractions by the micro-organisms. Recently, biological methods have been known to play a significant role in bioremediation of oil-polluted coastal areas. Such systems are likely to be of significance in the effective management of sensitive coastal ecosystems chronically subjected to oil spillage. For this reason the aim of this paper is to present an impact of Mn, Cu, Co and Mo quantities on oil biodegradation effectiveness in coastal soil and to determine the relationship between metal concentrations and degradation of two oil products (black oil and diesel fuel). Soil was collected in the Baltic Sea coastal zone oil products degradation area (Klaipeda, Lithuania). The experiment consisted of two parts: study on the influence of micro-elements on the oil product biodegradation process; and analysis of the influence of metal concentration on the number of HDMs. The analysis performed and results obtained address the following areas: impact of metal on a population of hydrocarbon degrading micro-organisms, impact of metals on residual concentrations of oil products, influence of metals on the growth of micro-organisms, inter-relation of metal concentrations with degradation rates. Statistical analysis was made using ;Statgraphics plus' software. The influence of metals on the growth of micro-organisms, the biodegradation process

  20. Effect of calcium and magnesium silicate on the growth of the castor oil plant subjected to salinity levels Efeito de silicato de cálcio e magnésio sobre o crescimento de plantas de mamoneira submetidas a níveis de salinidade

    Directory of Open Access Journals (Sweden)

    José Félix Brito Neto

    2012-12-01

    Full Text Available Salt stress decreases the osmotic potential of soil solution causing water stress, causing toxic effects in the plants resulting in injuries on the metabolism and nutritional disorders, thus compromising the plant growth, resulting in lower production. The calcium silicate and magnesium can perform the same function as limestone, besides providing silicon to plants, may also contribute to the resistance of plants to salt stress. Thus, the objective of this study was to evaluate the effect of calcium and magnesium silicate on the growth of the castor oil plant BRS Energia cultivated under saline conditions. This study evaluated plant height, stem diameter, number of leaves, leaf area, dry weight of shoot and root, and soil chemical characteristics. There was no interaction between factors of salinity level and of silicate level regarding the evaluated variables. There was a direct relationship between salinity levels and plant growth in height and stem diameter. The K concentration in soil were affected by salinity levels. O estresse salino diminui o potencial osmótico da solução do solo causando estresse hídrico, provocando efeitos tóxicos nas plantas que resultam em injúrias no metabolismo e desordens nutricionais, comprometendo assim o crescimento das plantas, resultando em menor produção. O silicato de cálcio e magnésio pode desempenhar a mesma função do calcário, além de fornecer silício para as plantas, podendo ainda, contribuir para a resistência de plantas ao estresse salino. Nesse sentido, objetivou-se com esse trabalho avaliar o efeito do silicato de cálcio e magnésio no crescimento da mamoneira BRS Energia cultivada sob condições salinas. Avaliou-se a altura da planta, diâmetro do caule, número de folhas, área foliar, massa seca da parte aérea e da raiz e as características químicas do solo. Não houve interação entre os fatores níveis de salinidade e silicato sobre as variáveis analisadas. Houve rela

  1. Improvements and simplifications of staged gasification unit for CHP production. Report for the project: Simplification, system and operation optimization of staged gasification unit for CHP production (the Castor unit in Graested); Forbedringer og forenklinger af trinopdelt forgasningsanlaeg til kraftvarmeproduktion. En Delrapport til projektet: Forenkling, system- og driftsoptimering af trinopdelt forgasningsanlaeg til kraftvarmeproduktion (Castor anlaegget i Graested)

    Energy Technology Data Exchange (ETDEWEB)

    Houmann Jakobsen, H.

    2010-08-15

    In 2003/04 BioSynergi Proces ApS built a complete approx. 450 kWth Open Core staged gasification unit as a development / demonstration plant. The plant uses wet wood chips as fuel for generating electricity and heat. The facility, known as the Castor plant, is connected to the heat supply network in Graested District Heating. The daily operation is handled by BioSynergi Process. The cogeneration system, that the Castor plant represents, is the basis for this completed project. In this subproject the Castor plant has been used to develop and test improvements to the cogeneration system at the following points: 1) Optimization of process design of the gas generator within the existing framework; 2) Establishment of a heating system to start up the gas generator; 3) Automation of switching the gas engine to operate on produced gas; 4) Simplification of the gas generator's fuel feeding system; 5) Improving the control options for the supply of gasification air. The introduced changes have led to the operation of the total gasification-cogeneration system becoming more convenient and easier to operate for non specialists. Operational testing of the plant during the project has covered approx. 2,300 hours of operation of cogeneration. It has identified the periodic maintenance tasks on the demonstration plant. Through further development of plant components that may happen in the subsequent development versions, it will be possible to eliminate some of the regular maintenance tasks and reduce the frequency of others. The optimization of the process design was completed with an experiment with the addition of extra air in the middle of the lower coke zone. Observations during the experiment gave the impression that both the amount and size of charcoal pieces are reduced. Because of the gas generator's section-wise construction, it will be relatively easy to construct and install a new subsection to it and thereby install the system permanently. It is estimated

  2. Produced water management - clean and safe oil and gas production

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The conference contains 22 presentations on topics within pollution sources and abatement, discharge reductions, water analysis and monitoring, water production, treatment and injection, enhanced recovery, condensate water, produced water markets, separation technologies for oil/gas/condensate and water, oil removal from solids, environmental risks of oil and gas production and environmental impacts on ecosystems and fisheries. Some oil field case histories are presented. The main focus is on the northern areas such as the North Sea, the north Atlantic Ocean and the Barents Sea, and technological aspects (tk)

  3. Modeling peak oil and the geological constraints on oil production

    NARCIS (Netherlands)

    Okullo, S.J.; Reynès, F.; Hofkes, M.W.

    2015-01-01

    We propose a model to reconcile the theory of inter-temporal non-renewable resource depletion with well-known stylized facts concerning the exploitation of exhaustible resources such as oil. Our approach introduces geological constraints into a Hotelling type extraction-exploration model. We show

  4. Production of polyol oils from soybean oil through bioprocess

    Science.gov (United States)

    Soy-polyol oils (oxygenated acylglycerols) are important starting materials for the manufacture of polymers such as polyurethane. Currently, they are produced by a two-step chemical process involving epoxidation and then the subsequent opening of the oxirane ring. The objective of this study is to d...

  5. Technical preparation of a 300 kWel biomass gasification plant. Report for the project: Simplification, system and operation optimization of staged gasification unit for CHP production (the Castor unit in Graested); Teknisk forberedelse af 300 kWel bioforgasningsanlaeg. En Delrapport til projektet: Forenkling, system- og driftsoptimering af trinopdelt forgasningsanlaeg til kraftvarmeproduktion (Castor anlaegget i Graested)

    Energy Technology Data Exchange (ETDEWEB)

    Houmann Jakobsen, H.

    2009-09-15

    In 2003/04 BioSynergi Proces ApS built a complete approx. 450 kWth Open Core staged gasification unit as a development / demonstration plant. The plant uses wet wood chips as fuel for generating electricity and heat. The facility, known as the Castor plant, is connected to the heat supply network in Graested District Heating. The daily operation is handled by BioSynergi Process. The cogeneration system, that the Castor plant represents, is the basis for this completed project. For technical preparation of the planned future up scaling of the cogeneration system, a test of the function of the gas generator core (reactor core) was performed in this sub-project. It is the central component of the total cogeneration system, and it is also the one who has the greatest influence on the overall gasification process. The experiments have demonstrated that the stage gasification principle, which is in operation at the Castor plant, is also possible to have in operation with the desired process steps in the tested reactor core with four times more capacity. Finalization of the total gas generator in the range of 300 kWel is now being developed in a new project. The simplified experiments, that were possible to perform with the outdoor setup of the reactor core, were, however, not suited to qualitative assessments of the gasification process. (ln)

  6. The CASTOR calorimeter at the CMS experiment

    CERN Document Server

    Gunnellini, Paolo

    2013-01-01

    The CASTOR Calorimeter at the CMS experiment is an electromagnetic/hadronic calorimeter which covers the very forward region of the detector (-6.6 < eta < -5.2). CASTOR is a Cherenkov sampling calorimeter, consisting of quartz and tungsten plates, with an overall depth of 10 interaction lengths, able to detect penetrating cascade particles. It is segmented in 16 transversal and 14 longitudinal sections. Surrounding the beam pipe, its design is determined by space constraints and restricted to materials which tolerate a high radiation level. In this presentation we report on the operational experience and measurements with the CASTOR calorimeter during the 2010 data taking at the LHC, with proton-proton and heavy ion collisions. An overview of the broad physics program which can be accessed with CASTOR, as well as the status of published and ongoing physics analyses and detector studies are presented.

  7. The CASTOR calorimeter at the CMS experiment

    CERN Document Server

    Gunnellini, Paolo

    2013-01-01

    The CASTOR Calorimeter at the CMS experiment is an electromagnetic/hadronic calorimeter which covers the very forward region of the detector (-6.6 lt eta lt -5.2). CASTOR is a Cherenkov sampling calorimeter, consisting of quartz and tungsten plates, with an overall depth of 10 interaction lengths, able to detect penetrating cascade particles. It is segmented in 16 transversal and 14 longitudinal sections. Surrounding the beam pipe, its design is determined by space constraints and restricted to materials which tolerate a high radiation level. In this presentation we report on the operational experience and measurements with the CASTOR calorimeter during the 2010 data taking at the LHC, with proton-proton and heavy ion collisions. An overview of the broad physics program which can be accessed with CASTOR, as well as the status of published and ongoing physics analyses and detector studies are presented.

  8. Growth and production of castor bean under different levels of irrigation water salinity and nitrogen dosesCrescimento e produção da mamoneira cultivada sob diferentes níveis de salinidade da água de irrigação e doses de nitrogênio

    Directory of Open Access Journals (Sweden)

    Reginaldo Gomes Nobre

    2013-06-01

    Full Text Available The castor bean (Ricinus communis L. is a plant belonging to the family Euphorbiaceae, and stands for the rusticity and adaptation to adverse conditions of climate and soil, for the fast growth, high production and considerable oil content in its seeds. In this context, this study we conducted to evaluate the effect of different levels of irrigation water of salinity and nitrogen on the growth and yield of castor bean cv. BRS Energia. The experiment was conducted in lysimeters under field conditions, at the Centro de Ciências e Tecnologia Agroalimentar, of Universidade Federal de Campina Grande. A complete randomized block design in a 5 x 5 factorial design with three replications. Treatments included a combination of five levels of electrical conductivity of irrigation water (0.4, 1.4, 2.4, 3.4 and 4.4 dS m-1 and five doses of nitrogen (50, 75; 100, 125 and 150% of the recommended dose. The number of leaves, stem diameter, plant height, dry mass of stems and leaves, and fruit number in primary raceme of castor bean cv. BRS Energia were linearly and negatively affected by irrigation water salinity from 0.4 dS m-1, the dry mass of leaves and production of primary cluster are variables more sensitive to salt stress, increasing doses of nitrogen fertilization promoted at harvest, increase in dry weight of stem and leaves and number of fruit in primary cluster; applying increasing doses of nitrogen reduced the effect of salinity on stem diameter of castor bean cv. BRS Energia.A mamoneira (Ricinus communis L. é uma planta pertencente à família Euphorbiaceae que se destaca pela rusticidade e boa adaptação a condições adversas de clima e solo, apresentando rápido crescimento, elevada produção e considerável teor de óleo em suas sementes. Neste contexto, conduziuse esta pesquisa objetivando avaliar a influência da irrigação com água de diferentes concentrações salinas e doses de nitrogênio sobre o crescimento e a produção de

  9. Response to Oil Sands Products Assessment

    Science.gov (United States)

    2015-09-01

    indoors or leave the area to limit their exposure to toxic fumes. Specific information about the diluent added to an oil sands mixture of concern would...known as upgraders. These refineries essentially strip much of the carbon from the bitumen and produce a light synthetic crude oil (known as Syncrude...Minnesota’s new law, states: (Douglass, 2014) “ Essentially , there’s no meaningful regulation or requirements or standards for oil spill response for

  10. Medicinal and cosmetics soap production from Jatropha oil.

    Science.gov (United States)

    Shahinuzzaman, M; Yaakob, Zahira; Moniruzzaman, M

    2016-06-01

    Soap is the most useful things which we use our everyday life in various cleansing and cosmetics purposes. Jatropha oil is nonedible oil which has more benefits to soap making. It has also cosmetics and medicinal properties. But the presence of toxic Phorbol esters in Jatropha oil is the main constrains to use it. So it is necessary to search a more suitable method for detoxifying the Jatropha oil before the use as the main ingredient of soap production. This review implies a more suitable method for removing phorbol esters from Jatropha oil. Several parameters such as the % yield of pure Jatropha oil soap, TFM value of soap, total alkali content, free caustic alkalinity content, pH, the antimicrobial activity, and CMC value of general soap should be taken into consideration for soap from detoxified Jatropha oil. © 2016 Wiley Periodicals, Inc.

  11. Genetic discovery for oil production and quality in sesame

    Science.gov (United States)

    Wei, Xin; Liu, Kunyan; Zhang, Yanxin; Feng, Qi; Wang, Linhai; Zhao, Yan; Li, Donghua; Zhao, Qiang; Zhu, Xiaodong; Zhu, Xiaofeng; Li, Wenjun; Fan, Danlin; Gao, Yuan; Lu, Yiqi; Zhang, Xianmei; Tang, Xiumei; Zhou, Congcong; Zhu, Chuanrang; Liu, Lifeng; Zhong, Ruichun; Tian, Qilin; Wen, Ziruo; Weng, Qijun; Han, Bin; Huang, Xuehui; Zhang, Xiurong

    2015-01-01

    Oilseed crops are used to produce vegetable oil. Sesame (Sesamum indicum), an oilseed crop grown worldwide, has high oil content and a small diploid genome, but the genetic basis of oil production and quality is unclear. Here we sequence 705 diverse sesame varieties to construct a haplotype map of the sesame genome and de novo assemble two representative varieties to identify sequence variations. We investigate 56 agronomic traits in four environments and identify 549 associated loci. Examination of the major loci identifies 46 candidate causative genes, including genes related to oil content, fatty acid biosynthesis and yield. Several of the candidate genes for oil content encode enzymes involved in oil metabolism. Two major genes associated with lignification and black pigmentation in the seed coat are also associated with large variation in oil content. These findings may inform breeding and improvement strategies for a broad range of oilseed crops. PMID:26477832

  12. Coffee oil as a potential feedstock for biodiesel production.

    Science.gov (United States)

    Oliveira, Leandro S; Franca, Adriana S; Camargos, Rodrigo R S; Ferraz, Vany P

    2008-05-01

    A preliminary evaluation of the feasibility of producing biodiesel using oil extracted from defective coffee beans was conducted as an alternative means of utilizing these beans instead of roasting for consumption of beverage with depreciated quality. Direct transesterifications of triglycerides from refined soybean oil (reference) and from oils extracted from healthy and defective coffee beans were performed. Type of alcohol employed and time were the reaction parameters studied. Sodium methoxide was used as alkaline catalyst. There was optimal phase separation after reactions using both soybean and healthy coffee beans oils when methanol was used. This was not observed when using the oil from defective beans which required further processing to obtain purified alkyl esters. Nevertheless, coffee oil was demonstrated to be a potential feedstock for biodiesel production, both from healthy and defective beans, since the corresponding oils were successfully converted to fatty acid methyl and ethyl esters.

  13. Genetic discovery for oil production and quality in sesame.

    Science.gov (United States)

    Wei, Xin; Liu, Kunyan; Zhang, Yanxin; Feng, Qi; Wang, Linhai; Zhao, Yan; Li, Donghua; Zhao, Qiang; Zhu, Xiaodong; Zhu, Xiaofeng; Li, Wenjun; Fan, Danlin; Gao, Yuan; Lu, Yiqi; Zhang, Xianmei; Tang, Xiumei; Zhou, Congcong; Zhu, Chuanrang; Liu, Lifeng; Zhong, Ruichun; Tian, Qilin; Wen, Ziruo; Weng, Qijun; Han, Bin; Huang, Xuehui; Zhang, Xiurong

    2015-10-19

    Oilseed crops are used to produce vegetable oil. Sesame (Sesamum indicum), an oilseed crop grown worldwide, has high oil content and a small diploid genome, but the genetic basis of oil production and quality is unclear. Here we sequence 705 diverse sesame varieties to construct a haplotype map of the sesame genome and de novo assemble two representative varieties to identify sequence variations. We investigate 56 agronomic traits in four environments and identify 549 associated loci. Examination of the major loci identifies 46 candidate causative genes, including genes related to oil content, fatty acid biosynthesis and yield. Several of the candidate genes for oil content encode enzymes involved in oil metabolism. Two major genes associated with lignification and black pigmentation in the seed coat are also associated with large variation in oil content. These findings may inform breeding and improvement strategies for a broad range of oilseed crops.

  14. Biodiesel production in crude oil contaminated environment using Chlorella vulgaris.

    Science.gov (United States)

    Xaaldi Kalhor, Aadel; Mohammadi Nassab, Adel Dabbagh; Abedi, Ehsan; Bahrami, Ahmad; Movafeghi, Ali

    2016-12-01

    Biodiesel is a valuable alternative to fossil fuels and many countries choose biodiesel as an unconventional energy source. A large number of investigations have been done on microalgae as a source of oil production. In recent years, wastewater pollutions have caused many ecological problems, and therefore, wastewater phycoremediation has attracted the international attention. This paper studied the cultivation of Chlorella vulgaris in a crude oil polluted environment for biodiesel production. Intended concentrations were 10 and 20gperliter (crude oil/water) at two times. The results showed that the growth of C. vulgaris was improved in wastewater and the maximum amount of dry mass and oil was produced at the highest concentration of crude oil (0.41g and 0.15g/l, respectively). In addition, dry mass and oil yield of the microalga were significantly enhanced by increasing the experiment duration. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Vegetable oil based liquid nanocomposite dielectric

    OpenAIRE

    Leon Chetty; Isaac W. Serukenya; Nelson M. Ijumba

    2013-01-01

    Physically smaller dielectric materials would improve the optimisation of space for power systems. Development of nanotechnology provides an effective way to improve the performances of insulating oils used in power system applications. In this research study, we focused on the development of nanomodified vegetable oils to be used in power transformers. Higher conduction currents were observed in virgin linseed oil than in virgin castor oil. However, for both virgin linseed and virgin castor ...

  16. Features of electric drive sucker rod pumps for oil production

    Science.gov (United States)

    Gizatullin, F. A.; Khakimyanov, M. I.; Khusainov, F. F.

    2018-01-01

    This article is about modes of operation of electric drives of downhole sucker rod pumps. Downhole oil production processes are very energy intensive. Oil fields contain many oil wells; many of them operate in inefficient modes with significant additional losses. Authors propose technical solutions to improve energy performance of a pump unit drives: counterweight balancing, reducing of electric motor power, replacing induction motors with permanent magnet motors, replacing balancer drives with chain drives, using of variable frequency drives.

  17. Solubility and Permeability Studies of Aceclofenac in Different Oils

    African Journals Online (AJOL)

    microemulsion-based gel for improved bioavailability. Methods: UV spectrophotometeric method was used at the wavelength of 276 nm to measure the dissolved quantity of aceclofenac in each of the oils (almond oil, oleic acid, castor oil, paraffin oil, cinnamon oil, clove oil, canola oil, sesame oil, isopropyl myristate (ipm), ...

  18. Biosurfactant production by Corynebacterium kutscheri from waste motor lubricant oil and peanut oil cake.

    Science.gov (United States)

    Thavasi, R; Jayalakshmi, S; Balasubramanian, T; Banat, Ibrahim M

    2007-12-01

    Production and characterization of biosurfactant from renewable sources. Biosurfactant production was carried out in 3-l fermentor using waste motor lubricant oil and peanut oil cake. Maximum biomass (9.8 mg ml(-l)) and biosurfactant production (6.4 mg ml(-l)) occurred with peanut oil cake at 120 and 132 h, respectively. Chemical characterization of the biosurfactant revealed that it is a glycolipopeptide with chemical composition of carbohydrate (40%), lipid (27%) and protein (29%). The biosurfactant is able to emulsify waste motor lubricant oil, crude oil, peanut oil, kerosene, diesel, xylene, naphthalene and anthracene; the emulsification activity was comparatively higher than the activity found with Triton X-100. This study indicates the possibility of biosurfactant production using renewable, relatively inexpensive and easily available resources like waste motor lubricant oil and peanut oil cake. Emulsification activity found with the biosurfactant against different hydrocarbons showed the possibility of the application of biosurfactants against diverse hydrocarbon pollution. The data obtained from the study could be useful for large-scale biosurfactant production using economically cheaper substrates. Information obtained in emulsification activity and laboratory-scale experiment on bioremediation inferred that bioremediation of hydrocarbon-polluted sites may be treated with biosurfactants or the bacteria that produces it.

  19. Waxy crude oil production in the South China Sea

    Energy Technology Data Exchange (ETDEWEB)

    Low, W.R.; Gerber, E.J.; Simek, L.A.

    1996-12-31

    The Phillips Petroleum International Corporation Asia (PPICA) Xijiang Field Development Project is a unique project resulting in the production of a waxy crude oil. The crude oil is produced on two platforms feeding a final production unit located on an FPSO (Floating Production, Storage and Off-loading) vessel located between the platforms. The crude from these two fields contains a high concentration of wax and has a relatively high pour point temperature. The crude composition and oil properties are listed in two tables. Special consideration was needed with respect to operating temperatures, start-up and shutdown procedures.

  20. Comparative Effect Of Crude Oil Products On Nitrogen Content Of ...

    African Journals Online (AJOL)

    The comparative effect of crude oil products was investigated using Clarias gariepinus uveniles. The fsh (average weight 100.20 ± 0.08g) was introduced inograded concentratons (2.00, 4.00, 6.00 and 8.00 ml -1) of Bonny light crude oil (BLCO), premium motor spirit (PMS) Dua purpose Kerosene (DPK) in toxic phase that ...

  1. Production of biodiesel from crude neem oil feedstock and its ...

    African Journals Online (AJOL)

    Due to its high acid value, the neem oil was processed via two step acid – base transesterification process. ... The results reveal the optimum conditions for biodiesel production to be ratio 1:6 of oil to methanol and 1.5 h reaction time. ... Key words: Neem, biodiesel, internal combustion, transesterification, free fatty acid.

  2. Production of high-quality fish oil from herring byproducts

    NARCIS (Netherlands)

    Aidos, I.M.F.

    2002-01-01

    In this work, the feasibility of producing high-quality fish oil from herring byproducts was evaluated in various ways. With this, a contribution has been made to a more efficient usage of natural resources while yielding a high-quality product. Crude oil extracted from herring byproducts

  3. Production of biodiesel by transesterification of refined soybean oil ...

    African Journals Online (AJOL)

    This study focused on the production of biodiesel via transesterification of refined soybean oil obtained locally. Sodium hydroxide was used as the alkali catalyst and methanol (as alcohol) was used in the transesterification process due to its low cost. The methanol-to-oil molar ratio was maintained at 6:1. The effect of ...

  4. Vegetable fats and oils as functional ingredients in meat products

    OpenAIRE

    Alfonso Totosaus

    2011-01-01

    Sausages are a widely consumed food in México, and due to their low fat content (ca. 10%) they can be employed to enrich diet by including functional or nutraceutic ingredients as vegetable fats and oils. The replace or incorporation of vegetable fats or oils in cooked sausages is a way to improve their nutritional profile to offer functional meat products.

  5. Oil and Gas Production, Environmental Health and Livelihood ...

    African Journals Online (AJOL)

    The paper has examined the level of communities' knowledge about associated environmental health and livelihood risks of oil exploration and development along ... The study has found very low levels of awareness with regards to the impacts of oil production on environmental health and livelihoods in the communities.

  6. Adoption of improved oil palm production and processing ...

    African Journals Online (AJOL)

    The study determined the extent of adoption of improved oil palm production and processing technologies in Arochukwu Local Government Area of Abia State, Nigeria. Fifty oil palm farmers randomly selected from five communities were sampled. A structured interview schedule was used for data collection, while ...

  7. Toxicity of crude oil products and detergent on serum alkaline ...

    African Journals Online (AJOL)

    The comparative effect of exposing Clarias gariepinus juveniles (100.20 + 0.8g) to diferent concentrations of crude oil products and detergent were studied. Bonny Light Crude oil (BLCO), Premium motor spirit (PMS), Dual purpose kerosene (DPK) and Ariel Enzymax Detergent (AED) were respectively applied at three ...

  8. Current status of the production of chemicals from oil shale

    Energy Technology Data Exchange (ETDEWEB)

    Yesavage, V.F.; Griswold, C.F.; Dickson, P.F.

    1980-08-01

    An alternate use of shale oil is as a feedstock for chemical intermediates (ethylene, propylene, benzene, toluene, and xylene (BTX)) production. The most extensively used method for production of petrochemical intermediates is by steam pyrolysis of a hydrocarbon feed. Steam pyrolysis is generally directed towards maximizing ethylene production while producing other olefins and aromatics as salable by-products. Crude shale oil has a high content of organic nitrogen (2% by weight), which acts as a catalyst poison, contains a large residuum fraction (20 to 50% by weight) and has a high pour point (generally > 40/sup 0/). Thus, it has generally been considered necessary to prerefine crude shale oil to produce a synthetic crude compatible with typical refineries. The prerefinery steps generally consist either of a delayed coking step on the crude shale oil or residuum fraction, followed by one or several hydrogenation steps, or of direct hydrogenation of crude shale oil at more severe conditions. These hydrogenation steps must generally be accomplished under severe operating conditions (750/sup 0/F, 2000 psia hydrogen partial pressure and up to 2000 Scf/bbl hydrogen uptake). Since such severe prerefining of crude shale oil may not be required for the utilization of shale oil as a steam pyrolysis feedstock, use of shale oil as a petrochemical feedstock offers a potential advantage over usage for a refinery feedstock. Studies made by the US Bureau of Mines, the Institute of Gas Technology, and the Colorado School of Mines on the conversion of shale oil to petrochemicals are summarized. A comparison is made between shale oil and petroleum oil pyrolysis. (DMC)

  9. Exploiting EST databases for the development and characterization of EST-SSR markers in castor bean (Ricinus communis L.

    Directory of Open Access Journals (Sweden)

    Yang Jun-Bo

    2010-12-01

    Full Text Available Abstract Background The castor bean (Ricinus communis L., a monotypic species in the spurge family (Euphorbiaceae, 2n = 20, is an important non-edible oilseed crop widely cultivated in tropical, sub-tropical and temperate countries for its high economic value. Because of the high level of ricinoleic acid (over 85% in its seed oil, the castor bean seed derivatives are often used in aviation oil, lubricants, nylon, dyes, inks, soaps, adhesive and biodiesel. Due to lack of efficient molecular markers, little is known about the population genetic diversity and the genetic relationships among castor bean germplasm. Efficient and robust molecular markers are increasingly needed for breeding and improving varieties in castor bean. The advent of modern genomics has produced large amounts of publicly available DNA sequence data. In particular, expressed sequence tags (ESTs provide valuable resources to develop gene-associated SSR markers. Results In total, 18,928 publicly available non-redundant castor bean EST sequences, representing approximately 17.03 Mb, were evaluated and 7732 SSR sites in 5,122 ESTs were identified by data mining. Castor bean exhibited considerably high frequency of EST-SSRs. We developed and characterized 118 polymorphic EST-SSR markers from 379 primer pairs flanking repeats by screening 24 castor bean samples collected from different countries. A total of 350 alleles were identified from 118 polymorphic SSR loci, ranging from 2-6 per locus (A with an average of 2.97. The EST-SSR markers developed displayed moderate gene diversity (He with an average of 0.41. Genetic relationships among 24 germplasms were investigated using the genotypes of 350 alleles, showing geographic pattern of genotypes across genetic diversity centers of castor bean. Conclusion Castor bean EST sequences exhibited considerably high frequency of SSR sites, and were rich resources for developing EST-SSR markers. These EST-SSR markers would be particularly

  10. Advances in biofuel production from oil palm and palm oil processing wastes: A review

    OpenAIRE

    Jundika C. Kurnia; Sachin V. Jangam; Saad Akhtar; Sasmito, Agus P.; Mujumdar, Arun S.

    2016-01-01

    Over the last decades, the palm oil industry has been growing rapidly due to increasing demands for food, cosmetic, and hygienic products. Aside from producing palm oil, the industry generates a huge quantity of residues (dry and wet) which can be processed to produce biofuel. Driven by the necessity to find an alternative and renewable energy/fuel resources, numerous technologies have been developed and more are being developed to process oil-palm and palm-oil wastes into biofuel. To further...

  11. Methanolysis of Carica papaya Seed Oil for Production of Biodiesel

    Directory of Open Access Journals (Sweden)

    Foluso O. Agunbiade

    2014-01-01

    Full Text Available The future of fossil fuel sources of energy has necessitated the need to search for renewable alternatives. Thus, Carica papaya seed oil (CPSO was employed as feedstock for the production of biodiesel by methanolysis. The seed was obtained locally, dried, and extracted with n-hexane. The CPSO was analyzed for specific gravity, viscosity, iodine value, and saponification value, among others using standard methods. The oil was transesterified by two-stage catalysis with oil to methanol mole ratio of 1 : 9. The biodiesel produced was subjected to standard fuel tests. The seed has an oil yield of 31.2% which is commercially viable. The kinematic viscosity of the oil at 313 K was 27.4 mm2s−1 while that of Carica papaya oil methylester (CPOME was reduced to 3.57 mm2s−1 and the specific gravity was 0.84 comparable with other seed-oil biodiesels and number 2 diesel. Other oil properties were compared favourably with seed oils already documented for biodiesel synthesis. CPOME’s cloud and pour points were 275 K and 274 K, respectively, and relatively higher than other biodiesels and number 2 diesel. CPOME exhibits moderate corrosion of copper strip. The methanolysis improved the fuel properties of the CPOME similar to other biodiesels. CPSO therefore exhibits a potential for biodiesel production.

  12. Biodiesel production from residual oils recovered from spent bleaching earth

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Yi-Pin; Chang, James I. [Department of Safety, Health and Environmental Engineering, National Kaohsiung First University of Science and Technology, 1, University Blvd., Yenchao, Kaohsiung (China)

    2010-01-15

    This work was to study technical and economic feasibilities of converting residual oils recovered from spent bleaching earth generated at soybean oil refineries into useable biodiesel. Experimental results showed that fatty acids in the SBE residual oil were hexadecenoic acid (58.19%), stearic acid (21.49%) and oleic acid (20.32%), which were similar to those of vegetable oils. The methyl ester conversion via a transesterification process gave a yield between 85 and 90%. The biodiesel qualities were in reasonable agreement with both EN 14214 and ASTM D6751 standards. A preliminary financial analysis showed that the production cost of biodiesel from SBE oils was significantly lower than the pre-tax price of fossil diesel or those made of vegetable oils or waste cooking oils. The effects of the crude oil price and the investment on the production cost and the investment return period were also conducted. The result showed that the investment would return faster at higher crude oil price. (author)

  13. Application of Neuro-Fuzzy to palm oil production process | Odior ...

    African Journals Online (AJOL)

    Palm oil is an important nutritional food requirement and in order to facilitate the production of palm oil for consumption, the production process of palm oil has been investigated. The basic operations involved in the production of edible palm oil include; purchase, transportation and reception of oil palm bunches; bunch ...

  14. Advances in biofuel production from oil palm and palm oil processing wastes: A review

    Directory of Open Access Journals (Sweden)

    Jundika C. Kurnia

    2016-03-01

    Full Text Available Over the last decades, the palm oil industry has been growing rapidly due to increasing demands for food, cosmetic, and hygienic products. Aside from producing palm oil, the industry generates a huge quantity of residues (dry and wet which can be processed to produce biofuel. Driven by the necessity to find an alternative and renewable energy/fuel resources, numerous technologies have been developed and more are being developed to process oil-palm and palm-oil wastes into biofuel. To further develop these technologies, it is essential to understand the current stage of the industry and technology developments. The objective of this paper is to provide an overview of the palm oil industry, review technologies available to process oil palm and palm oil residues into biofuel, and to summarise the challenges that should be overcome for further development. The paper also discusses the research and development needs, technoeconomics, and life cycle analysis of biofuel production from oil-palm and palm-oil wastes.

  15. Development of ethanol production from cooking oil glycerol waste ...

    African Journals Online (AJOL)

    Tuoyo Aghomotsegin

    2016-10-12

    Oct 12, 2016 ... Full Length Research Paper. Development of ethanol production from cooking oil glycerol waste by mutant Enterobacter aerogenes. Thalisa Yuwa-amornpitak* and Kannika Chookietwatana. Department of Biotechnology, Faculty of Technology, Mahasarakham University, Khamriang, Kantarawichai, Maha.

  16. Field study of heavy oil viscosity reduction for production transport

    Energy Technology Data Exchange (ETDEWEB)

    Pinto, J.; Annichiariccom, G.; Montanez, M. [Ecopetrol S.A. (Venezuela); Faust, M.; Weathers, T. [Nalco Energy Services (Colombia); Parra, R. [Nalco de Colombia Ltda. (Colombia)

    2011-07-01

    In the heavy oil industry, production and transportation are expensive processes requiring complex equipment and procedures. The main issue with heavy crude oil is its high viscosity. A method using naphtha injection was developed to dilute the fluids and aid in water separation, but this method is expensive and raises safety issues. To reduce naphtha consumption, Ecopetrol and Nalco Energy Services developed a new dispersion technology. This paper presents this technology and the results of its field trial in the Chichimene oil field. Key production indicators were monitored to determine how effective the emulsion method was in enhancing production. Results showed no negative effect on the separation facility or oil and water quality while reducing by 75% the injection of diluent. This paper presents a dispersion technology which successfully reduced the need for naphtha and thus reduced production costs.

  17. Map service: United States Oil and Gas Production 2008

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This map service displays present and past oil and gas production in the United States, as well as the location and intensity of exploratory drilling outside...

  18. Heavy and Thermal Oil Recovery Production Mechanisms, SUPRI TR-127

    Energy Technology Data Exchange (ETDEWEB)

    Kovscek, Anthony R.; Brigham, William E.; Castanier, Louis M.

    2001-09-07

    The program spans a spectrum of topics and is divided into five categories: (i) multiphase flow and rock properties, (ii) hot fluid injection, (iii) primary heavy-oil production, (iv) reservoir definition, and (v) in-situ combustion.

  19. Oil production by vacuum pyrolysis of Canadian oil shales and fate of the biological markers

    Energy Technology Data Exchange (ETDEWEB)

    Pakdel, H.; Roy, C.; Kalkreuth, W. [Institut Pyrovac Inc., Quebec, PQ (Canada)

    1999-02-01

    A bench-scale experiment study was undertaken to investigate the potential of vacuum pyrolysis for the production of oil from Carboniferous-age oil shales from New Brunswick and Nova Scotia. Vacuum pyrolysis limits the secondary decomposition reactions, which as a result provides a high yield of pyrolysis oil and a low yield of gas. The objectives of this study were: (1) to determine the optimum pyrolysis conditions for the production of pyrolysis oil; (2) to study the influence of reaction conditions on the nature of the oil; (3) to correlate the oil composition with the organic source material; and (4) to gain some insight into the kerogen decomposition. Batches of 120 g oil shale samples sieved to 1-5 mm particle size were heated to 600{degree}C and 1 kPa total pressure. The oil yield varied in the range of 10-20 wt% depending on the type of oil shale pyrolyzed. These oil yields are significantly higher than yields obtained by other industrial processes. The major pyrolysis gases generated during pyrolysis were CO{sub 2} (the most abundant), CO, H{sub 2}, CH{sub 4} and C{sub 2}-C{sub 4} hydrocarbons. The pyrolysis shale oils were deasphalted and yielded about 60-80 wt% maltene. n-Alkanes with biomodal distribution in the range of C{sub 8}-C{sub 34} were found in maltene fractions. The maltene fraction of a lamosite pyrolysis shale oil from New Brunswick was analyzed in detail. The analytical results were interpreted in terms of biological markers including n-alkanes, 2-alkylthiophenes, 2-alkylketones and triterpenoid hopanes. The soluble organic matter in the samples analyzed was found to be from a mixture of terrestrial and aquatic origins deposited in a lacustrine environment. 36 refs., 7 figs., 4 tabs.

  20. Oil Reservoir Production Optimization using Optimal Control

    DEFF Research Database (Denmark)

    Völcker, Carsten; Jørgensen, John Bagterp; Stenby, Erling Halfdan

    2011-01-01

    Practical oil reservoir management involves solution of large-scale constrained optimal control problems. In this paper we present a numerical method for solution of large-scale constrained optimal control problems. The method is a single-shooting method that computes the gradients using the adjo...... reservoir using water ooding and smart well technology. Compared to the uncontrolled case, the optimal operation increases the Net Present Value of the oil field by 10%.......Practical oil reservoir management involves solution of large-scale constrained optimal control problems. In this paper we present a numerical method for solution of large-scale constrained optimal control problems. The method is a single-shooting method that computes the gradients using...

  1. Characterization of products from the pyrolysis of rapeseed oil cake.

    Science.gov (United States)

    Ucar, Suat; Ozkan, Ahmet R

    2008-12-01

    The main aim of this study was to investigate the composition of products from the pyrolysis of rapeseed oil cake in a fixed bed reactor at 400, 450, 500, 700 and 900 degrees C. The gas products mainly consisted of CO(2), CO, CH(4) and H(2)S at 500 degrees C. Empirical formula of bio-oil from the pyrolysis of rapeseed oil cake was CH(1.59)O(0.16)N(0.116)S(0.003) for 500 degrees C. Bio-oils mainly contained oleic acid, 1H-indole, 2,3,5-trimethoxy toluene, toluene, (Z)-9-octadecanamide, psoralene, phenol and phenol derivatives at all pyrolysis temperatures. Both non-aromatic and aromatic hydrocarbon compounds were determined in water phase of liquid product by Headspace-GC analysis. The heating values of bio-chars were found to be similar (24MJkg(-1)) at all pyrolysis temperatures.

  2. Volume de recipientes e composição de substratos para produção de mudas de mamoneira Recipients volume and substrate composition for castor seedlings production

    Directory of Open Access Journals (Sweden)

    Rosiane de Lourdes Silva de Lima

    2006-06-01

    have to be set in order to succeed, such as recipient volume, substrate composition and period of seedling at nursery. A trial was run in greenhouse at Embrapa Algodão, Campina Grande, Paraíba State, Brazil, in a randomized block design with four replications and 25 treatments in 5² factorial distribution of five recipient volumes and five substrate compositions. Between 15 and 43 days after emergence, five destructive measurements were weekly performed for obtaining data on plant height, stem diameter, leaf area, number of leaves and dry weight of shoot and roots. Significant effects of treatments were detected on all variables analyzed. Seedlings growth stabilized about 36 days after emergence regardless recipient volume. Substrates composed by soil mixed to peanut hulls or bovine manure propitiated the best seedlings growth, while those ones containing sugarcane bagasse or agave mucilage were the worst. Recipients with 2 L of volume were the most appropriated to castor seedlings production.

  3. Differential Contribution of Malic Enzymes during Soybean and Castor Seeds Maturation.

    Directory of Open Access Journals (Sweden)

    Mariel Claudia Gerrard Wheeler

    Full Text Available Malic enzymes (ME catalyze the decarboxylation of malate generating pyruvate, CO2 and NADH or NADPH. In some organisms it has been established that ME is involved in lipids biosynthesis supplying carbon skeletons and reducing power. In this work we studied the MEs of soybean and castor, metabolically different oilseeds. The comparison of enzymatic activities, transcript profiles and organic acid contents suggest different metabolic strategies operating in soybean embryo and castor endosperm in order to generate precursors for lipid biosynthesis. In castor, the malate accumulation pattern agrees with a central role of this metabolite in the provision of carbon to plastids, where the biosynthesis of fatty acids occurs. In this regard, the genome of castor possesses a single gene encoding a putative plastidic NADP-ME, whose expression level is high when lipid deposition is active. On the other hand, NAD-ME showed an important contribution to the maturation of soybean embryos, perhaps driving the carbon relocation from mitochondria to plastids to support the fatty acids synthesis in the last stages of seed filling. These findings provide new insights into intermediary metabolism in oilseeds and provide new biotechnological targets to improve oil yields.

  4. Utilisation of vegetable oils in the production of lovastatin by Aspergillus terreus ATCC 20542 in submerged cultivation

    OpenAIRE

    Pattana Sripalakit

    2011-01-01

    The effect of vegetable oils as a supplementary carbon source during the production of lovastatin by Aspergillus terreus ATCC 20542 in submerged culture was investigated. The six vegetable oils tested were sesame oil, sunflower oil, soya bean oil, corn oil, palm oil and olive oil. Lovastatin concentration and biomass were measured. Lovastatin production was higher in several oil-containing media compared to control medium. In particular, palm oil and soya bean oil significantly improved lovas...

  5. Borehole radar for oil production monitoring

    NARCIS (Netherlands)

    Miorali, M.

    2012-01-01

    The area of smart well technology, or closed-loop reservoir management, aims at enhancing oil recovery through a combination of monitoring and control. Monitoring is performed with a wide range of sensors deployed downhole or at the surface. These sensors allow for capturing changes in the reservoir

  6. Use of castor oil polyurethane in an alternative technique for medial patella surgical correction in dogs Utilização do poliuretano de mamona em técnica alternativa de correção cirúrgica da luxação medial de patela em cães

    Directory of Open Access Journals (Sweden)

    Fabrício de Oliveira Frazilio

    2006-01-01

    Full Text Available PURPOSE: Comparative morphologic study of utilization of castor oil polymer in dogs joints, as an alternative technique to autogenous graft, in surgical correction of medial patella luxation. METHODS:Twelve adult dogs, of both sexes, were randomly allocated to two different groups of six animals each. Group I (biopolymer consisted of the deepening of the right femoral troclea, with the implantation of the biopolymer prothesis, and compared to group II (control which consisted of the conventional trocleoplastia technique with wedged cut of the left femoral troclea. The dogs were sacrified after 30 or 90 days and the anathomic peaces were analyzed macro and microscopically. Qui square and Wilcoxon tests were used for the statistic analyses of the results, considering probability of 5%. RESULTS: It was not observed bony integration on the castor oil polymer group. There was resorption of the graft along experimental period and absence of inflammatory cells in the studied periods. CONCLUSION: Castor oil polymer assisted cicatrisation process, was biocompatible without inflammation, and it can be used in joints as an alternative for bony filling.OBJETIVO: Estudo morfológico do implante da prótese de polímero de mamona em articulações de cães, como técnica alternativa ao enxerto ósseo autógeno na correção cirúrgica da luxação medial de patela. MÉTODOS: Doze cães adultos, de ambos os sexos, foram distribuídos aleatoriamente em dois grupos de 6 animais. No grupo I (poliuretano foi feito o aprofundamento da tróclea femoral direita com prótese de polímero de mamona, que foi comparado com o grupo II (controle sendo feita a trocleoplastia por ressecção em cunha da tróclea femoral esquerda. Os animais foram sacrificados após 30 e 90 dias e as peças anatômicas foram avaliadas macro e microscopicamente. O teste do quiquadrado e o teste não-paramétrico de Wilcoxon foram utilizados para a análise estatística dos resultados. Fixou

  7. Morphology of autogenous bone graft and castor oil polyurethane in the infraorbital rim of rabbits: a comparative study Estudo morfológico comparativo do enxerto ósseo autógeno e polímero de mamona em rebordo infra-orbitário de coelhos

    Directory of Open Access Journals (Sweden)

    José Carlos Garcia de Mendonça

    2006-10-01

    Full Text Available PURPOSE: Morphological study comparing castor oil polyurethane and autogenous bone graft to repair bone defect in zygomatic bone of rabbits. METHODS: Twenty-four adult, male New Zealand rabbits were randomly distributed between two groups of twelve. Bone defects of 5mm in diameter were cut through the zygomatic bone and filled with polyurethane discs in the experimental group or autogenous bone harvested from the tibia in the control group. Animals were sacrificed after 30, 60 or 90 days, and the zygomatic bones were macro- and microscopically analyzed. Student's, Fisher's, chi-squared and McNemar's tests were used for statistical analysis. RESULTS: Both the castor oil polyurethane and the autograft adapted well to the defect, with no need for fixation. Fibrous connective tissue encapsulated the polyurethane, but no inflammation or giant cell reaction was observed. Acidophilic and basophilic areas were observed inside the micropores of the polyurethane, suggesting cell nuclei. After 90 days, bone repair with a lamellar pattern of organization was observed in the control group. CONCLUSION: The castor oil polyurethane was biocompatible and did not cause inflammation. It may be considered an alternative to fill bone defects.OBJETIVO: Estudo morfológico comparativo do implante de poliuretana de mamona e enxerto ósseo autógeno em defeito ósseo padrão em osso zigomático de coelhos. MÉTODOS: Vinte e quatro coelhos Nova Zelândia, machos, adultos, foram distribuídos aleatoriamente em dois grupos de 12. Defeitos de 5mm de diâmetro, perenes, foram confeccionados em osso zigomático e preenchidos com discos pré-fabricados de poliuretana no grupo experimento ou osso autógeno extraído da tíbia no grupo controle. Os animais foram sacrificados após 30, 60 e 90 dias e as peças anatômicas foram avaliadas macro e microscopicamente. Foram utilizados os testes de Student, Fisher,qui-quadrado e McNemar para a análise estatística dos resultados

  8. Technological products to support the Venezuelan heavy oil development

    Energy Technology Data Exchange (ETDEWEB)

    Lopez, J.; Negrin, Z.; Duran, M.; Vilera, M.; Santamaria, F. [PDVSA INTEVEP (Venezuela)

    2011-07-01

    In Venezuela, important reserves of heavy oil crude are located at the Orinoco oil belt and the challenge is to develop these fields in a safe and environmentally friendly way. To address this challenge, PDVSA Intevep has been developing cutting edge technologies for more than 30 years. The aim of this paper is to present the principal inventions of PDVSA Intevep and their application in the Venezuelan traditional areas. PDVSA Intevep is the technological development and research center of the Venezuelan national oil industry; they own 773 patents, 103 trademarks, 48 copyrights, 13 trade secrets and 35 products used in different technological areas. The technologies presented will be used in the Orinoco oil belt in support of Venezuelan technological sovereignty. PDVSA Intevep has developed and adapted many technologies aimed at putting oil resources at the service of the whole population and ending social inequalities.

  9. Formulation and evaluation of oil entrapped gastroretentive floating gel beads of loratadine

    National Research Council Canada - National Science Library

    Mishra, Shashi Kiran; Pathak, Kamla

    2008-01-01

    ... (pectin/sodium alginate) by mass, 15% (m/V) of oil (mineral oil or castor oil) and 0.45 mol L-1 calcium chloride solution as the optimized processing conditions for the desired buoyancy and physical stability...

  10. Avocado oil extraction processes: method for cold-pressed high-quality edible oil production versus traditional production

    Directory of Open Access Journals (Sweden)

    Giacomo Costagli

    2015-10-01

    Full Text Available Nowadays the avocado fruit (Persea americana Mill. is widely regarded as an important fruit for its nutritional values, as it is rich in vital human nutrients. The avocado fruit is mainly sold fresh on the market, which however trades also a relevant quantity of second-grade fruits with a relatively high oil content. Traditionally, this oil is extracted from dried fruits by means of organic solvents, but a mechanical method is also used in general in locations where drying systems and/or solvent extraction units cannot be installed. These traditional processes yield a grade of oil that needs subsequent refining and is mainly used in the cosmetic industry. In the late 1990s, in New Zeland, a processing company with the collaboration of Alfa Laval began producing cold-pressed avocado oil (CPAO to be sold as edible oil for salads and cooking. Over the last fifteen years, CPAO production has increased in many other countries and has led to an expansion of the market which is set to continue, given the growing interest in highquality and healthy food. Avocado oil like olive oil is extracted from the fruit pulp and in particular shares many principles of the extraction process with extra-vergin olive oil. We conducted a review of traditional and modern extraction methods with particular focus on extraction processes and technology for CPAO production.

  11. The production and evaluation of bio-oils from the pyrolysis of sunflower-oil cake

    Energy Technology Data Exchange (ETDEWEB)

    Gercel, Hasan Ferdi [Anadolu Univ., Dept. of Chemical Engineering, Eskisehir (Turkey)

    2002-10-01

    Sunflower (Helianthus annus L.)-oil cake pyrolysis experiments were achieved in a fixed-bed tubular reactor. The effects of nitrogen flow rate and final pyrolysis temperature on the pyrolysis product yields and chemical compositions have been investigated. The maximum bio-oil yield of 48.69 wt% was obtained in nitrogen atmosphere with nitrogen flow rate of 100 cm{sup 3} min{sup -1} and at a pyrolysis temperature of 550 deg C with a heating rate of 5 deg Cs{sup -1}. Chromatographic and spectroscopic studies on the pyrolytic oil showed that the oil obtained from sunflower-oil cake can be used as a renewable fuel and chemical feedstocks. (Author)

  12. Peaking of world oil production: Impacts, mitigation, & risk management

    Energy Technology Data Exchange (ETDEWEB)

    Hirsch, R.L. (SAIC); Bezdek, Roger (MISI); Wendling, Robert (MISI)

    2005-02-01

    The peaking of world oil production presents the U.S. and the world with an unprecedented risk management problem. As peaking is approached, liquid fuel prices and price volatility will increase dramatically, and, without timely mitigation, the economic, social, and political costs will be unprecedented. Viable mitigation options exist on both the supply and demand sides, but to have substantial impact, they must be initiated more than a decade in advance of peaking.... The purpose of this analysis was to identify the critical issues surrounding the occurrence and mitigation of world oil production peaking. We simplified many of the complexities in an effort to provide a transparent analysis. Nevertheless, our study is neither simple nor brief. We recognize that when oil prices escalate dramatically, there will be demand and economic impacts that will alter our simplified assumptions. Consideration of those feedbacks will be a daunting task but one that should be undertaken. Our aim in this study is to-- • Summarize the difficulties of oil production forecasting; • Identify the fundamentals that show why world oil production peaking is such a unique challenge; • Show why mitigation will take a decade or more of intense effort; • Examine the potential economic effects of oil peaking; • Describe what might be accomplished under three example mitigation scenarios. • Stimulate serious discussion of the problem, suggest more definitive studies, and engender interest in timely action to mitigate its impacts.

  13. Biodiesel production from seed oil of Cleome viscosa L.

    Science.gov (United States)

    Kumari, Rashmi; Jain, Vinod Kumar; Kumar, Sushil

    2012-07-01

    Edible oil seed crops, such as rapeseed, sunflower, soyabean and safflower and non-edible seed oil plantation crops Jatropha and Pongamia have proved to be internationally viable commercial sources of vegetable oils for biodiesel production. Considering the paucity of edible oils and unsustainability of arable land under perennial plantation of Jatropha and Pongamia in countries such as India, the prospects of seed oil producing Cleome viscosa, an annual wild short duration plant species of the Indogangetic plains, were evaluated for it to serve as a resource for biodiesel. The seeds of C. viscosa resourced from its natural populations growing in Rajasthan, Haryana and Delhi areas of Aravali range were solvent extracted to obtain the seed oil. The oil was observed to be similar in fatty acid composition to the non-edible oils of rubber, Jatropha and Pongamia plantation crops and soybean, sunflower, safflower, linseed and rapeseed edible oil plants in richness of unsaturated fatty acids. The Cleome oil shared the properties of viscosity, density, saponification and calorific values with the Jatropha and Pongamia oils, except that it was comparatively acidic. The C. viscosa biodiesel had the properties of standard biodiesel specified by ASTM and Indian Standard Bureau, except that it had low oxidation stability. It proved to be similar to Jatropha biodiesel except in cloud point, pour point, cold filter plugging point and oxidation stability. In view of the annual habit of species and biodiesel quality, it can be concluded that C. viscosa has prospects to be developed into a short-duration biodiesel crop.

  14. Oil industry waste: a potential feedstock for biodiesel production.

    Science.gov (United States)

    Abbas, Javeria; Hussain, Sabir; Iqbal, Muhammad Javid; Nadeem, Habibullah; Qasim, Muhammad; Hina, Saadia; Hafeez, Farhan

    2016-08-01

    The worldwide rising energy demands and the concerns about the sustainability of fossil fuels have led to the search for some low-cost renewable fuels. In this scenario, the production of biodiesel from various vegetable and animal sources has attracted worldwide attention. The present study was conducted to evaluate the production of biodiesel from the oil industry waste following base-catalysed transesterification. The transesterification reaction gave a yield of 83.7% by 6:1 methanol/oil molar ratio, at 60°C over 80 min of reaction time in the presence of NaOH. The gas chromatographic analysis of the product showed the presence of 16 fatty acid methyl esters with linoleic and oleic acid as principal components representing about 31% and 20.7% of the total methyl esters, respectively. The fourier transform infrared spectroscopy spectrum of oil industry waste and transesterified product further confirmed the formation of methyl esters. Furthermore, the fuel properties of oil industry waste methyl esters, such as kinematic viscosity, cetane number, cloud point, pour point, flash point, acid value, sulphur content, cold filter plugging point, copper strip corrosion, density, oxidative stability, higher heating values, ash content, water content, methanol content and total glycerol content, were determined and discussed in the light of ASTM D6751 and EN 14214 biodiesel standards. Overall, this study presents the production of biodiesel from the oil industry waste as an approach of recycling this waste into value-added products.

  15. Biotechnological processes for biodiesel production using alternative oils

    Energy Technology Data Exchange (ETDEWEB)

    Azocar, Laura; Ciudad, Gustavo [La Frontera Univ., Temuco (Chile). Nucleo Cietifico Tecnologico en Biorrecursos; Heipieper, Hermann J. [Helmholtz Centre for Environmental Research-UFZ, Leipzig (Germany). Dept. of Environmental Biotechnology; Navia, Rodrigo [La Frontera Univ., Temuco (Chile). Nucleo Cietifico Tecnologico en Biorrecursos; La Frontera Univ., Temuco (Chile). Dept. de Ingenieria Quimica

    2010-10-15

    As biodiesel (fatty acid methyl ester (FAME)) is mainly produced from edible vegetable oils, crop soils are used for its production, increasing deforestation and producing a fuel more expensive than diesel. The use of waste lipids such as waste frying oils, waste fats, and soapstock has been proposed as low-cost alternative feedstocks. Non-edible oils such as jatropha, pongamia, and rubber seed oil are also economically attractive. In addition, microalgae, bacteria, yeast, and fungi with 20% or higher lipid content are oleaginous microorganisms known as single cell oil and have been proposed as feedstocks for FAME production. Alternative feedstocks are characterized by their elevated acid value due to the high level of free fatty acid (FFA) content, causing undesirable saponification reactions when an alkaline catalyst is used in the transesterification reaction. The production of soap consumes the conventional catalyst, diminishing FAME production yield and simultaneously preventing the effective separation of the produced FAME from the glycerin phase. These problems could be solved using biological catalysts, such as lipases or whole-cell catalysts, avoiding soap production as the FFAs are esterified to FAME. In addition, by-product glycerol can be easily recovered, and the purification of FAME is simplified using biological catalysts. (orig.)

  16. Biotechnological processes for biodiesel production using alternative oils.

    Science.gov (United States)

    Azócar, Laura; Ciudad, Gustavo; Heipieper, Hermann J; Navia, Rodrigo

    2010-10-01

    As biodiesel (fatty acid methyl ester (FAME)) is mainly produced from edible vegetable oils, crop soils are used for its production, increasing deforestation and producing a fuel more expensive than diesel. The use of waste lipids such as waste frying oils, waste fats, and soapstock has been proposed as low-cost alternative feedstocks. Non-edible oils such as jatropha, pongamia, and rubber seed oil are also economically attractive. In addition, microalgae, bacteria, yeast, and fungi with 20% or higher lipid content are oleaginous microorganisms known as single cell oil and have been proposed as feedstocks for FAME production. Alternative feedstocks are characterized by their elevated acid value due to the high level of free fatty acid (FFA) content, causing undesirable saponification reactions when an alkaline catalyst is used in the transesterification reaction. The production of soap consumes the conventional catalyst, diminishing FAME production yield and simultaneously preventing the effective separation of the produced FAME from the glycerin phase. These problems could be solved using biological catalysts, such as lipases or whole-cell catalysts, avoiding soap production as the FFAs are esterified to FAME. In addition, by-product glycerol can be easily recovered, and the purification of FAME is simplified using biological catalysts.

  17. Transformation of soil and vegetable conditions at oil production territories

    Science.gov (United States)

    Gatina, Evgeniia

    2017-04-01

    On the territory of modern oil production soil, vegetation, ecosystem conditions of the environment are significantly transformed. Researches have been conducted on the oil production territories located in a boreal coniferous forest natural zone from 2005 to 2015. Standard geobotanical and soil methods are used. Mechanical destruction of a plant cover, change of the water conditions, intake of oil products and salty waters in ecosystems, pollution of the atmosphere are considered as the major technology-related factors defining transformation of land ecosystems at operation of the oil field. Under the mechanical destruction of a plant cover the pioneer plant communities are formed. These communities are characterized by most reduced specific wealth with prevalence of types of meadow groups of plants and presence of types of wetland groups of plants. The biodiversity of biocenosis which are affected linear infrastructure facilities of oil production territories and change of the water conditions, decreases. It is observed decrease in species wealth, simplification of structure of communities. Under the salting of soils in ecosystems there is a decrease species diversity of communities to prevalence nitrophilous and meadow plant species. At the increased content of organic substances in the soils that is a consequence of intake of oil products, is characteristic increase in specific richness of communities, introduction of types of wetland and oligotrophic groups of plants in forest communities. Influence depends on distance to an influence source. In process of removal from a source of atmospheric pollution in forest communities there is a decrease in species diversity and complication of structure of community. It is caused by introduction of types of meadow groups of plants in ecotone sites of the forest communities located near a source of influence and restoration of structural features of forest communities in process of removal from an influence source

  18. Biodiesel Production from Rubber Seed Oil via Esterification Process

    Directory of Open Access Journals (Sweden)

    W Widayat

    2012-07-01

    Full Text Available One promise source of alternative energy is biodiesel from rubber seed oil, because the raw materials available in plentiful quantities and can be renewed. In addition, the rubber seed is still lack of utilization, and Indonesia is one of the largest rubbers producing country in the world. The objective of this research is to studied on biodiesel production by esterification process. Parameters used in this study are the ratio of catalyst and temperature and its influence on the characteristics of the resulting biodiesel product. Characterization of rubber seed include acid content number analysis, saponification numbers, density, viscosity, iodine number, type of free fatty acids and triglyceride oils. The results of analysis showed that rubber seed oil content obtained is 50.5%. The results of the GCMS analysis showed that a free fatty acid level in rubber seed is very high. Conversion into bio-diesel oil is obtained by at most 59.91% and lowest 48.24%.

  19. Opportunities to improve oil productivity in unstructured deltaic reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    1991-01-01

    This report contains presentations presented at a technical symposium on oil production. Chapter 1 contains summaries of the presentations given at the Department of Energy (DOE)-sponsored symposium and key points of the discussions that followed. Chapter 2 characterizes the light oil resource from fluvial-dominated deltaic reservoirs in the Tertiary Oil Recovery Information System (TORIS). An analysis of enhanced oil recovery (EOR) and advanced secondary recovery (ASR) potential for fluvial-dominated deltaic reservoirs based on recovery performance and economic modeling as well as the potential resource loss due to well abandonments is presented. Chapter 3 provides a summary of the general reservoir characteristics and properties within deltaic deposits. It is not exhaustive treatise, rather it is intended to provide some basic information about geologic, reservoir, and production characteristics of deltaic reservoirs, and the resulting recovery problems.

  20. Use of calcium oxide in palm oil methyl ester production

    Directory of Open Access Journals (Sweden)

    Kulchanat Prasertsit

    2014-04-01

    Full Text Available Introducing an untreated calcium oxide (CaO as a solid heterogeneous catalyst for biodiesel production from palm oil by transesterification was studied in this work. The four studied parameters were methanol to oil molar ratio, CaO catalyst concentration, reaction time, and water content. The results for palm oil show that when the water content is higher than 3%wt and the amount of CaO greater than 7%wt soap formation from saponification occurs. A higher methanol to oil molar ratio requires a higher amount of CaO catalyst to provide the higher product purity. The appropriate methanol to CaO catalyst ratio is about 1.56. Commercial grade CaO gives almost the same results as AR grade CaO. In addition, reusing commercial grade CaO for about 5 to 10 repetitions without catalyst regeneration drops the percentage of methyl ester purity approximately 5 to 10%, respectively.

  1. Method for creating high carbon content products from biomass oil

    Science.gov (United States)

    Parker, Reginald; Seames, Wayne

    2012-12-18

    In a method for producing high carbon content products from biomass, a biomass oil is added to a cracking reactor vessel. The biomass oil is heated to a temperature ranging from about 100.degree. C. to about 800.degree. C. at a pressure ranging from about vacuum conditions to about 20,700 kPa for a time sufficient to crack the biomass oil. Tar is separated from the cracked biomass oil. The tar is heated to a temperature ranging from about 200.degree. C. to about 1500.degree. C. at a pressure ranging from about vacuum conditions to about 20,700 kPa for a time sufficient to reduce the tar to a high carbon content product containing at least about 50% carbon by weight.

  2. Enzymatic interesterification of vegetable oil/ fish oil blend for margarine production

    DEFF Research Database (Denmark)

    Ibrahim, Nuzul Amri Bin; Xu, Xuebing

    In margarine formulation, oils of different melting points are blended to make a product that is spreadable at room temperature. Usually, the blend would be subjected to modification process, either by interesterification (chemical or enzymatic) or partial hydrogenation in order to achieve...... the desired properties. In this study, palm stearin (PS), palm kernel oil (PKO) and fish oil (FO) are blended and modified by enzymatic interesterification. PS functioned as the hard stock, PKO as the soft oil and FO as a source for eicosapentaenoic acid (EPA)/ docosahexaenoic acid (DHA). The purpose...... they are consumed as a quick source of energy. The remaining 2-monoacyl- glycerol becomes a source of essential fatty acid, after being absorbed through the intestinal wall. This would enhance the nutritional value of the enzymatically interesterified product. However, the incorporation of FO into the blend would...

  3. HEAVY-OIL PRODUCTION USING EMULSION FLOODING

    African Journals Online (AJOL)

    user

    The United State of America heavy oil resources is .... viscometer, puppets and weight balance machine. The viscosity values were calculated as follows: (. ) 1 is the absolute viscosity of water, t1 is the time of flow of water ρ1 is the Density of water 2 is the absolute viscosity of liquid, t2 is the time of flow of liquid and ρ2 is the ...

  4. Regional Oil Extraction and Consumption: A simple production model for the next 35 years Part I

    CERN Document Server

    Dittmar, Michael

    2016-01-01

    The growing conflicts in and about oil exporting regions and speculations about volatile oil prices during the last decade have renewed the public interest in predictions for the near future oil production and consumption. Unfortunately, studies from only 10 years ago, which tried to forecast the oil production during the next 20-30 years, failed to make accurate predictions for today's global oil production and consumption. Forecasts using economic growth scenarios, overestimated the actual oil production, while models which tried to estimate the maximum future oil production/year, using the official country oil reserve data, predicted a too low production. In this paper, a new approach to model the maximal future regional and thus global oil production (part I) and consumption (part II) during the next decades is proposed. Our analysis of the regional oil production data during past decades shows that, in contrast to periods when production was growing and growth rates varied greatly from one country to ano...

  5. Enzymatic biodiesel production from sludge palm oil (SPO) using ...

    African Journals Online (AJOL)

    Biodiesel is a non-toxic, renewable and environmental friendly fuel. This study involved the production of biodiesel from sludge palm oil ... The results in solvent system for biodiesel production showed that ethanol gave higher yield of biodiesel as compared to methanol. One-factor-at-a time (OFAT) method was applied to ...

  6. Utilization of papaya waste and oil production by Chlorella protothecoides

    Science.gov (United States)

    Algae derived oils have outstanding potential for use in biodiesel production. Chlorella protothecoides has been shown to accumulate lipid up to 60% of its cellular dry weight with glucose supplementation under heterotrophic growth conditions. To reduce production costs, alternative carbon feedstock...

  7. Electric power supply in an offshore oil production platform | Ibe ...

    African Journals Online (AJOL)

    A study of the provision of electric power using associated natural gas as primary source of energy, in an offshore oil production platform has been carried out. Some of the problems to be contended with include: the effects of impurities contained in the fuel gas supply;variations in the production process characteristics; ...

  8. Economic potentials of oil palm products and weed control on ...

    African Journals Online (AJOL)

    A study was carried out at the Research Farm of National Root Crops Research Institute Umudike, southeastern Nigeria (05o, 29'N, 07o 33'E and 122 m above sea level), in 2015 and 2016 cropping seasons to study the economic potentials of oil palm products and weed control on sustainable turmeric production and some ...

  9. 75 FR 20271 - Oil and Gas and Sulphur Operations in the Outer Continental Shelf-Oil and Gas Production...

    Science.gov (United States)

    2010-04-19

    ... Minerals Management Service 30 CFR Part 250 RIN 1010-AD12 Oil and Gas and Sulphur Operations in the Outer Continental Shelf--Oil and Gas Production Requirements AGENCY: Minerals Management Service (MMS), Interior. ACTION: Final rule. SUMMARY: The MMS is amending the regulations regarding oil and natural gas production...

  10. 78 FR 59632 - Oil and Gas and Sulphur Operations on the Outer Continental Shelf-Oil and Gas Production Safety...

    Science.gov (United States)

    2013-09-27

    ... Bureau of Safety and Environmental Enforcement 30 CFR Part 250 RIN 1014-AA10 Oil and Gas and Sulphur Operations on the Outer Continental Shelf--Oil and Gas Production Safety Systems AGENCY: Bureau of Safety and... amend and update the regulations regarding oil and natural gas production by addressing issues such as...

  11. Cleaning oil refining drainage waters out of emulsified oil products with thermic treated cedar nut shell

    Science.gov (United States)

    Pyatanova, P. A.; Adeeva, L. N.

    2017-08-01

    It was elaborated the ability of the sorbent produced by thermic treatment of cedar nut shell to destruct model and real first kind (direct) emulsions in static and dynamic conditions. In static conditions optimal ratio sorbent-emulsion with the original concentration of oil products 800 mg/l was in the range of 2.0 g per 100 ml of emulsion which corresponds to the level of treatment 94.9%. The time of emulsion destruction was 40 minutes. This sorbent is highly active in dynamic processes of oil-contaminated water treatment, the level of treatment 96.0% is being achieved. Full dynamic sorptive capacity of the sorbent is 0.85 g/g. Sorbent based on the thermic treated cedar nut shell can be elaborated as sorptive filter element of local treatment facilities of oil refining and petrochemical processes. After the treatment with this sorbent of drainage waters of oil refinery in dynamic conditions the concentration of oil products became less than mpc on oil products for waste waters coming to biological treatment.

  12. Metabolizable energy and nutrient digestibility of detoxified castor meal and castor cake for poultry

    Directory of Open Access Journals (Sweden)

    João Batista Matos Júnior

    2011-11-01

    Full Text Available This experiment aimed to determine the metabolizable energy and the digestibility of detoxified castor meal and castor cake nutrients for broilers. A total of 180 Cobb-500TM broilers from 21 to 32 days of age was randomly distributed in three treatments with six replicates of 10 broilers - 5 males and 5 females. The experimental treatments were a reference-diet and two test-diets composed of 80% of reference-diet and 20% of detoxified castor cake or castor meal. The adaptation period ranged from 21 to 27 days of age and the total excreta collection period ranged from 28 to 32 days of age. The detoxified castor meal presented apparent metabolizable energy of 2,032 kcal/kg of natural matter, apparent metabolizable energy corrected for nitrogen balance of 1,829 kcal/kg of natural matter and the digestibility coefficients of 57.8% dry matter, 68.4% crude protein, 10.5% crude fiber, 35.9% nitrogen free extract, 80.0% ether extract and 26.6% ash. In the detoxified castor cake, the apparent metabolizable energy content was 2,550 kcal/kg of natural matter, the nitrogen corrected apparent metabolizable energy balance was of 2,320 kcal/kg of natural matter and the digestibility coefficients of 60.6% for dry matter, 77.2% for crude protein, 14.0% for crude fiber, 45.7% for nitrogen free extract, 85.4% for ether extract and 28.2% for ash. The metabolizable energy and digestibility of nutrients in detoxified castor cake are higher than in the detoxified castor meal.

  13. Sur la biologie du Castor du Rhône (Castor fiber L.)

    NARCIS (Netherlands)

    Urbain, Achille

    1949-01-01

    Le Castor du Rhône ( Castor fiber L.) a été particulièrement bien étudié par de nombreux auteurs. VICTOR PIRAUD ¹) a donné d’intéressants renseignements sur ses moeurs; M. P. CORDIER ²) et A. HUGUES ³) ont fait aussi une étude appronfondie de cet animal et L. GERMAND 4) a fourni une description

  14. Past, Present, and Future Production of Bio-oil

    Energy Technology Data Exchange (ETDEWEB)

    Steele, Philip; Yu, Fei; Gajjela, Sanjeev

    2009-04-01

    Bio-oil is a liquid product produced by fast pyrol-ysis of biomass. The fast pyrolysis is performed by heating the biomass rapidly (2 sec) at temperatures ranging from 350 to 650 oC. The vapors produced by this rapid heating are then condensed to produce a dark brown water-based emulsion composed of frag-ments of the original hemicellulose, cellulose and lignin molecules contained in the biomass. Yields range from 60 to 75% based on the feedstock type and the pyrolysis reactor employed. The bio-oil pro-duced by this process has a number of negative prop-erties that are produced mainly by the high oxygen content (40 to 50%) contributed by that contained in water (25 to 30% of total mass) and oxygenated compounds. Each bio-oil contains hundreds of chemi-cal compounds. The chemical composition of bio-oil renders it a very recalcitrant chemical compound. To date, the difficulties in utilizing bio-oil have limited its commercial development to the production of liq-uid smoke as food flavoring. Practitioners have at-tempted to utilize raw bio-oil as a fuel; they have also applied many techniques to upgrade bio-oil to a fuel. Attempts to utilize raw bio-oil as a combustion engine fuel have resulted in engine or turbine dam-age; however, Stirling engines have been shown to successfully combust raw bio-oil without damage. Utilization of raw bio-oil as a boiler fuel has met with more success and an ASTM standard has recently been released describing bio-oil characteristics in relation to assigned fuel grades. However, commercialization has been slow to follow and no reports of distribution of these bio-oil boiler fuels have been reported. Co-feeding raw bio-oil with coal has been successfully performed but no current power generation facilities are following this practice. Upgrading of bio-oils to hydrocarbons via hydroprocessing is being performed by several organizations. Currently, limited catalyst life is the obstacle to commercialization of this tech-nology. Researchers

  15. Repertoire of SSRs in the Castor Bean Genome and Their Utilization in Genetic Diversity Analysis in Jatropha curcas

    Directory of Open Access Journals (Sweden)

    Arti Sharma

    2011-01-01

    Full Text Available Castor bean and Jatropha contain seed oil of industrial importance, share taxonomical and biochemical similarities, which can be explored for identifying SSRs in the whole genome sequence of castor bean and utilized in Jatropha curcas. Whole genome analysis of castor bean identified 5,80,986 SSRs with a frequency of 1 per 680 bp. Genomic distribution of SSRs revealed that 27% were present in the non-genic region whereas 73% were also present in the putative genic regions with 26% in 5′UTRs, 25% in introns, 16% in 3′UTRs and 6% in the exons. Dinucleotide repeats were more frequent in introns, 5′UTRs and 3′UTRs whereas trinucleotide repeats were predominant in the exons. The transferability of randomly selected 302 SSRs, from castor bean to 49 J. curcas genotypes and 8 Jatropha species other than J. curcas, showed that 211 (~70% amplified on Jatropha out of which 7.58% showed polymorphisms in J. curcas genotypes and 12.32% in Jatropha species. The higher rate of transferability of SSR markers from castor bean to Jatropha coupled with a good level of PIC (polymorphic information content value (0.2 in J. curcas genotypes and 0.6 in Jatropha species suggested that SSRs would be useful in germplasm analysis, linkage mapping, diversity studies and phylogenetic relationships, and so forth, in J. curcas as well as other Jatropha species.

  16. Genome-Wide Identification, Evolutionary Analysis, and Stress Responses of the GRAS Gene Family in Castor Beans

    Directory of Open Access Journals (Sweden)

    Wei Xu

    2016-06-01

    Full Text Available Plant-specific GRAS transcription factors play important roles in regulating growth, development, and stress responses. Castor beans (Ricinus communis are important non-edible oilseed plants, cultivated worldwide for its seed oils and its adaptability to growth conditions. In this study, we identified and characterized a total of 48 GRAS genes based on the castor bean genome. Combined with phylogenetic analysis, the castor bean GRAS members were divided into 13 distinct groups. Functional divergence analysis revealed the presence of mostly Type-I functional divergence. The gene structures and conserved motifs, both within and outside the GRAS domain, were characterized. Gene expression analysis, performed in various tissues and under a range of abiotic stress conditions, uncovered the potential functions of GRAS members in regulating plant growth development and stress responses. The results obtained from this study provide valuable information toward understanding the potential molecular mechanisms of GRAS proteins in castor beans. These findings also serve as a resource for identifying the genes that allow castor beans to grow in stressful conditions and to enable further breeding and genetic improvements in agriculture.

  17. Repertoire of SSRs in the Castor Bean Genome and Their Utilization in Genetic Diversity Analysis in Jatropha curcas

    Science.gov (United States)

    Sharma, Arti; Chauhan, Rajinder Singh

    2011-01-01

    Castor bean and Jatropha contain seed oil of industrial importance, share taxonomical and biochemical similarities, which can be explored for identifying SSRs in the whole genome sequence of castor bean and utilized in Jatropha curcas. Whole genome analysis of castor bean identified 5,80,986 SSRs with a frequency of 1 per 680 bp. Genomic distribution of SSRs revealed that 27% were present in the non-genic region whereas 73% were also present in the putative genic regions with 26% in 5′UTRs, 25% in introns, 16% in 3′UTRs and 6% in the exons. Dinucleotide repeats were more frequent in introns, 5′UTRs and 3′UTRs whereas trinucleotide repeats were predominant in the exons. The transferability of randomly selected 302 SSRs, from castor bean to 49 J. curcas genotypes and 8 Jatropha species other than J. curcas, showed that 211 (∼70%) amplified on Jatropha out of which 7.58% showed polymorphisms in J. curcas genotypes and 12.32% in Jatropha species. The higher rate of transferability of SSR markers from castor bean to Jatropha coupled with a good level of PIC (polymorphic information content) value (0.2 in J. curcas genotypes and 0.6 in Jatropha species) suggested that SSRs would be useful in germplasm analysis, linkage mapping, diversity studies and phylogenetic relationships, and so forth, in J. curcas as well as other Jatropha species. PMID:21687555

  18. Oil migration in chocolate and almond product confectionery systems.

    Science.gov (United States)

    Altan, Aylin; Lavenson, David M; McCarthy, Michael J; McCarthy, Kathryn L

    2011-08-01

    Oil migration from high oil content almond confections into adjacent chocolate causes changes in product quality. The objective of this study was to quantify the oil migration from almond products to dark chocolate. Magnetic resonance imaging (MRI) was used to monitor spatial and temporal changes of liquid lipid content. A multislice spin echo pulse (MSSE) sequence was used to acquire images with a 7.8-ms echo time and a 1000-ms repetition time using a 1.03T Aspect AI MRI spectrometer. Samples were prepared as a 2-layer model system of chocolate and almond confection. Six different almond products and 1 type of dark chocolate were used. Samples were stored at 20, 25, and 30°C for a time frame of several months. Rate and extent of migration were quantified by a kinetic expression based on the linear dependence of oil uptake by chocolate and the square root of the time. Samples showed distinctly different rate and extent of oil migration, as evidenced by quantitative differences in the kinetic rate constants and equilibrium uptake for the different sample types. This work will be helpful to design formulations for almond and almond-based products in confections. This work will be helpful to design formulations for almond use in confections. © 2011 Institute of Food Technologists®

  19. BIOSURFACTANTS PRODUCTION BY Pseudomonas aeruginosa USING SOYBEAN OIL AS SUBSTRATE

    Directory of Open Access Journals (Sweden)

    Venty Suryanti

    2010-06-01

    Full Text Available Optimization condition of the biosurfactants production by P. aeruginosa using soybean oil as substrate has been examined. The media containing 10% v/v of the soybean oil and 6 days of the fermentation time was the optimum condition for the biosurfactants production. The extraction technique using different solvent polarity (n-hexane, chloroform, ethyl acetate and buthanol, respectively was applied for the isolation of the biosurfactants. The biosurfactant was found in the extract chloroform of the crude biospasoy (biosurfactants obtained from soybean oil as substrate which then is called chlo-biospasoy. The chlo-biospasoy was identified as rhamnolipids which had oil in water (o/w emulsion type, had the CMC of 860 mg/L and could reduced the surface tension of the water from 72 mN/m to 52 mN/m. The chlo-biospasoy could be used as an emulsifier to form emulsion between water and hydrocarbon such as palm oil, benzene, premium or toluene with various stability. The results indicated that chlo-biospasoy could be used as an emulsifying and emulsion-stabilizing agent.     Keywords: Biosurfactants, P. aeruginosa, Soybean Oil, Emulsifier

  20. Carbon nanotubes (CNT) for enhanced oil production from shales

    OpenAIRE

    Hussain, Aqeel

    2014-01-01

    The shale gas production has brought a revolution in US energy market and the global prospect of shale gas production is on continuous increase. The advancements in hydraulic fracturing made it possible to extract very low permeability shale gas through fracturing the shale rock. The once fractured shale rock is kept open with the induction of spherical particles known as proppants. The performance of proppants is crucial for oil & gas production. Therefore, the prospect of applic...

  1. Biodiesel Production from Acidified Oils via Supercritical Methanol

    Directory of Open Access Journals (Sweden)

    Jianxin Li

    2011-12-01

    Full Text Available In biodiesel production, the vegetable oil used as raw material for transesterification should be free of water and free fatty acids (FFAs, which may consume catalyst and reduce catalyst efficiency. In this work biodiesel was prepared from acidified oils (AO through a supercritical methanol route, in which the esterification of FFAs and transesterification of glyceride with methanol occurred simultaneously. The effects of the mass ratio of methanol to AO, the operation temperature as well as the water content on the FFAs conversion and glycerol yield were investigated. The results indicated that the FFAs conversion for esterification under the condition of 1:1 methanol/oil ratio, 310 °C and 15 min reaction time reached 98.7%, and the glycerol yield for transesterification under 0.25:1 methanol/oil ratio, 290 °C and 20 min reaction time reached 63.5% respectively.

  2. Impact of Expanded North Slope of Alaska Crude Oil Production on Crude Oil Flows in the Contiguous United States

    Energy Technology Data Exchange (ETDEWEB)

    DeRosa, Sean E. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Flanagan, Tatiana Paz [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-05-01

    The National Transportation Fuels Model was used to simulate a hypothetical increase in North Slope of Alaska crude oil production. The results show that the magnitude of production utilized depends in part on the ability of crude oil and refined products infrastructure in the contiguous United States to absorb and adjust to the additional supply. Decisions about expanding North Slope production can use the National Transportation Fuels Model take into account the effects on crude oil flows in the contiguous United States.

  3. Life Cycle Assessment (LCA) of the biofuel production process from sunflower oil, rapeseed oil and soybean oil

    Energy Technology Data Exchange (ETDEWEB)

    Sanz Requena, J.F.; Guimaraes, A.C.; Quiros Alpera, S.; Relea Gangas, E.; Hernandez-Navarro, S.; Navas Gracia, L.M.; Martin-Gil, J.; Fresneda Cuesta, H. [Universidad Europea Miguel de Cervantes, Valladolid (Spain). Dept. of Natural Resources; Valladolid Univ., Palencia (Spain). Dept. of Forest and Agricultural Engineering

    2011-02-15

    Once ratified the Kyoto protocol, Spain arises the great challenge of reducing the emissions of greenhouse gases. Among the measures proposed is the introduction of biofuels in the market, both for the transport sector and for the production of heat. This paper compares the environmental impact from the production of biofuels whose origin is the oil obtained from sunflower, rapeseed and soybeans. The environmental impact of each production is performed by applying the methodology of life cycle analysis (LCA). The categories where you get a greater impact are land use, fossil fuels, carcinogens, inorganic respiratory and climate change. The cause is mainly due to the processes of seed production. We have also found a significant impact on the drying and preparation processes of the seed as well as the crude soybean oil extracting process. Moreover as the LCA shows production of rapeseed and sunflower has a positive contribution to climate change. (author)

  4. Side-stream products of edible oil refining as feedstocks in biodiesel production

    Directory of Open Access Journals (Sweden)

    Cvetković Bojan S.

    2016-01-01

    Full Text Available Biodiesel, a diesel fuel alternative, is produced from vegetable oils and animal fats by the transesterification reaction of triacylglycerols and lower aliphatic alcohols. Beside number advantages related to fossil fuels, the main barrier to biodiesel wider commercial use is the high price of edible oils. Recently, the special attention was given to side-stream products of edible oil refining as low-cost triacylglycerol sources for biodiesel production because of their positive economic and ecological effects. In this paper, the different procedures for biodiesel production from side-stream refining products such as soapstock, spent bleaching earth and deodorizer distillate were analyzed. The main goal of this paper is to analyze the possibilities for reusing the by-products of edible oil refinement in the biodiesel production.

  5. Learning from the Past - Evaluating Forecasts for Canadian Oil Sands Production with Data

    OpenAIRE

    Hehl, Friedrich

    2013-01-01

    Crude oil plays an important role for the global energy system. As there is ample evidence that conventional oil production will have peaked by 2020, unconventional oil has attained a stronger focus. In particular, oil derived from bitumen from Canadian oilsands has been proposed as a possible remedy to global oil depletion. This study aims to test the hypothesis that forecasts on the Canadian oil sands published between about 2000 and 2010 have been overestimating production significantly. A ...

  6. Indonesia palm oil production without deforestation and peat conversion by 2050

    NARCIS (Netherlands)

    Afriyanti, Dian; Kroeze, Carolien; Saad, Asmadi

    2016-01-01

    Palm oil is a promising source of cooking oil and biodiesel. The demand for palm oil has been increasing worldwide. However, concerns exist surrounding the environmental and socio-economic sustainability of palm oil production. Indonesia is a major palm oil producing country. We explored

  7. Natural Occurrence of Aldol Condensation Products in Valencia Orange Oil.

    Science.gov (United States)

    Abreu, Ingo; Da Costa, Neil C; van Es, Alfred; Kim, Jung-A; Parasar, Uma; Poulsen, Mauricio L

    2017-12-01

    Cold pressed orange oils contain predominantly d-limonene (approximately 95%) and various other lower concentration monoterpenes, sesquiterpenes, sinensals plus 3 key aliphatic aldehydes: hexanal, octanal. and decanal. The aldol self-condensation products or "dimers" for each aldehyde have been postulated as being present at low concentrations in the oil. However, to date only the hexanal dimer has been previously reported. In this paper, cold pressed Valencia orange oil was fractionally distilled/folded and analyzed by GC and high resolution GC-MS to detect these compounds on 2 different capillary column phases. Subsequently the hexanal, octanal, and decanal self-aldol condensation products, 2-butyl-2-octenal, 2-hexyl-2-decenal, and 2-octyl-2-dodecenal, respectively, were detected in the folded oil. These predominantly trans configuration isomeric compounds were synthesized, to confirm them as being present in nature and evaluated organoleptically by a panel of evaluators. To further confirm the mechanism of their formation, the enriched oil was made into a simple beverage to show the effect on the formation of these aldol compounds under acidic conditions. Finally aliphatic aldehydes from hexanal to undecanal were reacted together in various combinatorial pairs to give an additional 33 self and mixed aldol condensation products, some of which were also detected in the folded oil. This paper discloses the structural elucidation and synthesis of 8 novel aldol condensation products found at trace concentrations in citrus and leading to a further 31 mass spectrally determined aldol products. Sensory evaluations and application of some of these components were demonstrated in a model citrus beverage. © 2017 Institute of Food Technologists®.

  8. Production of biodiesel from vegetable oils

    Directory of Open Access Journals (Sweden)

    Luque, Susana

    2008-03-01

    Full Text Available Biodiesel is produced by transesterification of triglycerides present in animal fat or vegetable oils, by displacing glycerine with a low molar mass alcohol. This resulting ester mixture has physico-chemical properties similar to those of petroleum diesel. This paper reviews the synthetic paths that lead to biodiesel by means of the catalytic transesterification of vegetable oils. Although methyl esters are at present the only ones produced at industrial scale, the use of ethanol, which can also be obtained from renewable resources, has been considered, since it would generate a cleaner and more biocompatible fuel.El biodiésel se produce mediante la transesterificación de triglicéridos, presentes en grasas animales o aceites vegetales, en un proceso en el que un alcohol de bajo peso molecular desplaza a la glicerina. La mezcla de esteres así resultante posee unas propiedades físico-químicas similares a las del diésel procedente de petróleo. En este artículo se revisan las vías de síntesis de biodiésel mediante la transesterificación catalítica de aceites vegetales. Aunque actualmente a escala industrial solo se producen ésteres metílicos, también se ha considerado el uso de etanol, ya que éste se obtiene también de fuentes renovables, generando así un combustible más limpio y biocompatible.

  9. Characterization of residual oils for biodiesel production

    Directory of Open Access Journals (Sweden)

    Edmilson Antonio Canesin

    2014-01-01

    Conclusions: The obtained results suggesting that it is possible to take advantage of these residues for biodiesel production as the obtained products were approved according to the rules established by the National Association of Petroleum (ANP; the bovine samples were the exception regarding moisture and acidity.

  10. VAT: ways of improving administration and calculation during transshipment and transfer of oil and oil products

    Directory of Open Access Journals (Sweden)

    Vasiliy F. Stoykov

    2017-12-01

    Full Text Available Objective to eliminate legal uncertainty in interpretation and implementation of a legal norm para. 4 subclause 2.2. clause 1 Art. 164 of the Taxation Code of the Russian Federation to elaborate proposals for improving the Russian legislation on taxes and duties which is essential for elimination of the said problems. Methods the research is based on a set of general scientific and specific methods of cognition used in the science of Financial Law dialectic method formaldogmatic method methods of analysis analogy induction and synthesis historical retrospective formalization and logical method. Results the article presents theoreticallegal analysis of the consequences of ambiguous interpretation of a legal norm para. 4 subclause 2.2. clause 1 Art. 164 of the Taxation Code of the Russian Federation in relation to organizations rendering services in the sphere of oil and oil products transportation and transshipment. It is stated that one of the essential problems in the practice of value added tax implementation is the use of zero tax rate. When the norms of the above Article are interpreted it causes problems in organizations engaged in oil and oil products transportation and transshipment due to the differences in positions of the Russian Ministry of Finance and the taxation authorities about the location of works to be referred to transshipment. Another problem is narrow comprehension of organizations engaged in oil transportation as well as uncertainty of norms related to the terminology of oil transportation transshipment and reloading. All the above inaccuracies and ambiguities in legislation lead to problems in organizations engaged in oil transportation as is shown by the example of ldquoMarine Port Servicerdquo Close Corporation. The author also presents the results of analysis of judicial practice in the sphere of interpreting para. 4 subclause 2.2. clause 1 Art. 164 of the Taxation Code of the Russian Federation. The possible

  11. The research and practice of boosting oil production by duplicated horizontal wells in thick super heavy oil reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Peiwu, Li; Yang Jing, Wangping; Ping, Yuan [Exploration and Development Research Institute of Liaohe Oilfield Company, PetroChina, P.R.China , 124010 (China)

    2011-07-01

    In the oil industry, the extraction of heavy oil and super heavy oil from reservoirs is difficult and production decline and sand production are some of the numerous challenges it faces. The aim of this paper is to show how secondary development can address these issues. A preliminary study was conducted and then a plan of secondary development was applied to M6 Block which is a massive extra-ultra heavy oil reservoir. The plan included 154 wells with 30 new horizontal wells. Results proved SAGD to be a good technique for high oil recovery results with improved production from M6 Block. After the implementation of the secondary development, oil recovery improved by 36.3%. This technique also solved the sand production problem. This study showed that secondary development can be a solution to obtain a better performance from heavy oil reservoirs and provides guidance to other similar reservoir.

  12. Transesterification of coconut oil for FAME production using ultrasound

    Science.gov (United States)

    Supriadi, Eko; Marlinda, Lenny; Prajitno, Danawati Hari; Mahfud, Mahfud

    2017-05-01

    To overcome energy crisis, the vegetable oils-derived biofuel can be chosen as an alternative to petroleum-based diesel. The transesterification of coconut oil in methanol with K/γ-Al2O3 catalyst using ultrasound-assisted to produce fatty acid methyl ester (FAME) as one of type biofuel was studied. The reaction occurred in batch reactor at a 9 : 1 molar ratio of methanol to coconut oil. The following reaction conditions were used in the catalytic test : concentration of catalyst to oil of 0.5, 1.0, 1.5, 2.0, and 2.5%, the reaction time of 10, 20, 30, 60, 90, 120, and 150 s, and the frequency ultrasonication of 20 and 40 KHz. At first, the preparation of K/γ-Al2O3 catalyst was done and followed by transesterification process. After reaction, the phase separation and purification from impurities were done. Finally, FAME was analized based on this parameters, i.e., yield, density, viscosity, and flash point. FAME yield of 93.76% was obtained at the frequency ultrasonication of 40 kHz with K/γ-Al2O3 catalyst concentration to oil of 2.5 wt.% for 150 s. It's the best conditions for FAME production by transesterification of coconut oil using ultrasound-assisted.

  13. OIL SLUGS FOR PRODUCTION OF PISTON RING

    Directory of Open Access Journals (Sweden)

    V. F. Bevza

    2008-01-01

    Full Text Available The developed technological process of continuously cyclic casting by frosting allows to receive high-quality hollow cylindrical slugs of cast iron for production of critical parts. 

  14. Ultrasound Assisted Esterification of Rubber Seed Oil for Biodiesel Production

    Directory of Open Access Journals (Sweden)

    W Widayat

    2012-04-01

    Full Text Available Production of biodiesel is currently shifting from the first to the second generation inwhich the raw materials are mostly from non-edible type oils and fats. Biodiesel production iscommonly conducted under batch operation using mechanical agitation to accelerate masstransfers. The main drawback of oil esterification is the high content of free fatty acids (FFA whichmay reduce the yield of biodiesel and prolong the production time (2-5 hours. Ultrasonificationhas been used in many applications such as component extraction due to its ability to producecavitation under certain frequency. This research is aimed to facilitate ultrasound system forimproving biodiesel production process particularly rubber seed oil. An ultrasound unit was usedunder constant temperature (40oC and frequency of 40 Hz. The result showed that ultrasound canreduces the processing time and increases the biodiesel yield significantly. A model to describecorrelation of yield and its independent variables is yield (Y = 43,4894 – 0,6926 X1 + 1,1807 X2 –7,1042 X3 + 2,6451 X1X2 – 1,6557 X1X3 + 5,7586 X2X3 - 10,5145 X1X2X3, where X1 is mesh sizes, X2ratio oil: methanol and X3 type of catalyst.

  15. Moringa oleifera oil: Studies of characterization and biodiesel production

    Energy Technology Data Exchange (ETDEWEB)

    da Silva, Jhosianna P.V.; Serra, Tatiana M.; Meneghetti, Simoni M.P. [Universidade Federal de Alagoas, Instituto de Quimica e Biotecnologia, Laboratorio de Oleoquimica, Maceio, Alagoas, CEP 57072-970 (Brazil); Gossmann, Marcelo; Wolf, Carlos R.; Meneghetti, Mario R. [Universidade Luterana do Brasil, Instituto de Quimica, Canoas, Rio Grande do Sul, CEP 92420-280 (Brazil)

    2010-10-15

    This work describes studies with the seeds of Moringa oleifera (MO), obtained in the northeast of Brazil, evaluating some properties and chemical composition of the oil, as well any potential application in biodiesel production. The studied physicochemical properties of the MO biodiesel, suggest that this material may be used as fuel in diesel engines, mainly as a mixture to petrodiesel. (author)

  16. First One Hundred Days of Oil Production in Ghana

    African Journals Online (AJOL)

    User

    2011-04-19

    Apr 19, 2011 ... Abstract. This paper discusses the events and happenings in Ghana within the first one hundred days of oil production. Using elite interviews and media reports, the paper chronicles several challenges and problems including lack of transparency, secrecy, consensus building, discontentment, etc that have.

  17. Development of ethanol production from cooking oil glycerol waste ...

    African Journals Online (AJOL)

    Bacterial strains, capable of producing ethanol by using cooking oil glycerol waste (derived from biodiesel production) as sole C-source were screened from soil samples. Based on 16S rRNA sequence, the selected strain was identified as Enterobacter aerogenes G2WG. The sequence was submitted to GenBank and the ...

  18. Optimization of biodiesel production from rice bran oil via ...

    African Journals Online (AJOL)

    DR. NJ TONUKARI

    2011-11-16

    Nov 16, 2011 ... The lipase-catalyzed transesterification of rice bran oil and methanol for biodiesel production in hexane was investigated. The effects of different hexane weight ratio, methanol molar ratio, reaction temperature and immobilized lipase dosage on the total conversion were systematically analyzed by response ...

  19. Gender Role in Sustainable Palm Oil Production in Imo State ...

    African Journals Online (AJOL)

    E M IGBOKWE

    Department of Agricultural Economics and Extension, Anambra State University, Igbariam. Campus. E-mail: nwalieji73@yahoo.com Phone: 07033994751 ..... Lack of finance and modern processing equipment are twin problems that militate against sustainable production of palm oil. In fact, these constraints operate like ...

  20. Production of biodiesel using Colocynthis citrullus L. oil over green ...

    African Journals Online (AJOL)

    The production and characterization of biodiesel fuel obtained by means of transesterification over green solid heterogeneous catalyst with Colocynthis citrullus ... The biodiesel was synthesized homogeneously using a three-necked round bottom flask at 333 K and the feedstock ratio of catalyst to methanol to oil is 3:10:10.

  1. Biodiesel production from Jatropha curcas oil catalyzed by whole ...

    African Journals Online (AJOL)

    my mord

    2013-07-03

    Jul 3, 2013 ... friendly and renewable fuel that can be used directly in diesel engines without any engine modification. Biodiesel, principally produced as fatty acid methyl esters (FAME), is a product from the transesterification reaction between triglycerides (vegetable oils or animal fat) and short chain alcohols (methanol ...

  2. Dietary manipulation of oil production in commercial emu

    African Journals Online (AJOL)

    client

    The aim of this research was to optimize emu oil production by manipulation of the dietary protein and energy ratios for ... The long-chain fatty acid composition of the fat did not differ between treatment groups and consisted of ... For example, the feeds have been adapted from the poultry (ostrich & chicken) industry in.

  3. The analysis of bunch production in the oil palm

    NARCIS (Netherlands)

    Sparnaaij, L.D.

    1959-01-01

    Bunch yield of oil palms can be expressed as the product of number of bunches and average bunch weight. Number of bunches is itself composite, being determined by number of leaves, percentage floral abortion, sex ratio and percentage bunch failure. Of these elements sex ratio proved to be most

  4. Optimization of biodiesel production from rice bran oil via ...

    African Journals Online (AJOL)

    The lipase-catalyzed transesterification of rice bran oil and methanol for biodiesel production in hexane was investigated. The effects of different hexane weight ratio, methanol molar ratio, reaction temperature and immobilized lipase dosage on the total conversion were systematically analyzed by response surface ...

  5. English-Igbo glossary creation of palm oil production and ...

    African Journals Online (AJOL)

    To achieve this objective, this paper comes to fill the gap of lack of an Igbo glossary for the technical terms involved in palm oil production and processing. The study is anchored on such translation techniques as Adaptation, Calque, Naturalisation, Transposition, Modulation and Loaning. It is a rendition from English to Igbo.

  6. Production of polyol oils from soybean oil by bioprocess: results of microbial screening and identification of positive cultures

    Science.gov (United States)

    Recently we reported methods for microbial screening and production of polyol oils from soybean oil through bioprocessing (Hou and Lin, 2013). Soy-polyol oils (oxygenated acylglycerols) are important starting materials for the manufacture of polymers such as polyurethane. Currently, they are produce...

  7. Biodiesel production from microalgae oil catalyzed by a recombinant lipase.

    Science.gov (United States)

    Huang, Jinjin; Xia, Ji; Jiang, Wei; Li, Ying; Li, Jilun

    2015-03-01

    A recombinant Rhizomucor miehei lipase was constructed and expressed in Pichia pastoris. The target enzyme was termed Lipase GH2 and it can be used as a free enzyme for catalytic conversion of microalgae oil mixed with methanol or ethanol for biodiesel production in an n-hexane solvent system. Conversion rates of two major types of biodiesel, fatty acid methyl ester (FAME) and fatty acid ethyl ester (FAEE), reached maximal values (>90%) after 24h. The process of FAME production is generally more simple and economical than that of FAEE production, even though the two processes show similar conversion rates. In spite of the damaging effect of ethanol on enzyme activity, we successfully obtained ethyl ester by the enzymatic method. Our findings indicate that Lipase GH2 is a useful catalyst for conversion of microalgae oil to FAME or FAEE, and this system provides efficiency and reduced costs in biodiesel production. Copyright © 2014 Elsevier Ltd. All rights reserved.

  8. Biosurfactant production by Corynebacterium kutscheri from waste motor lubricant oil and peanut oil cake

    National Research Council Canada - National Science Library

    Thavasi, R; Jayalakshmi, S; Balasubramanian, T; Banat, Ibrahim M

    2007-01-01

    ... ) and biosurfactant production (6·4 mg ml –l ) occurred with peanut oil cake at 120 and 132 h, respectively. Chemical characterization of the biosurfactant revealed that it is a glycolipopeptide with chemical composition of carbohydrate...

  9. Biodiesel production by chemical or enzymatic esterification of sunflower oil

    Energy Technology Data Exchange (ETDEWEB)

    Passarinho, Paula C.; Rosa, M. Fernanda; Oliveira, A.C.; Pingarilho, M.S.; Beirao, S.G.; Vieira, Ana Maria Soares

    1998-07-01

    In this work, two processes of sunflower oil transesterification, with methanol or ethanol, were studied for biodiesel production: chemical (catalyst- NaOH) and enzymatic (catalyst - rhizomucor miehei lipase). The chemical catalysis proved to be more efficient, having been obtained higher conversion yields and a better quality biodiesel, mainly in the case where methanol was used. The transesterification product had, in all cases, to be purified in order to be used as a diesel substitute.

  10. [Products of the interaction of ethazole with mustard oils].

    Science.gov (United States)

    Vurbanova, S; Ivanov, I

    1976-01-01

    Synthesized were nonsymmetrical N1N1--replaced products of thiocarbamide containing residual alkyl- and arylsinapic oils and the sulfonamide ethasole, in order to study their pharmacologic activity. The synthesis was performed through heating the components up to the point of weak boiling in an ethanol medium. The obtained nine new N1N1--thiocarbamide products were identified in terms of their melting point and sulfur analysis. Tentative microbiologic testing showed that the newly obtained compounds produce bacteriostatic and bactericidal effects.

  11. Some modern notions on oil and gas reservoir production regulation

    Energy Technology Data Exchange (ETDEWEB)

    Lohrenz, J.; Monash, E.A.

    1980-05-21

    The historic rhetoric of oil and gas reservoir production regulations has been burdened with misconceptions. One was that most reservoirs are rate insensitive. Another was that a reservoir's decline is primarily a function of reservoir mechaism rather than a choice unconstrained by the laws of physics. Relieved of old notions like these, we introduce some modern notions, the most basic being that production regulation should have the purpose of obtaining the highest value from production per irreversible diminution of thermodynamically available energy. The laws of thermodynamics determine the available energy. What then is value. Value may include contributions other than production per se and purely monetary economic outcomes.

  12. production of glycerol from palm kernel oil

    African Journals Online (AJOL)

    industry, ranging from textile, petroleum, paper, leather and cosmetics to pharmaceuticals. They are also used in making surface active agents, protective and decorative coatings, etc. In purified commercial form, glycerol is usually called glycerine. Glycerine can be applied in various products such as lubricants, tobacco,.

  13. Production of high-quality fish oil from herring byproducts

    OpenAIRE

    Aidos, I.M.F.

    2002-01-01

    In this work, the feasibility of producing high-quality fish oil from herring byproducts was evaluated in various ways. With this, a contribution has been made to a more efficient usage of natural resources while yielding a high-quality product. Crude oil extracted from herring byproducts is relatively rich in essentialw-3 PUFAs such as EPA and DHA, and is relatively stable during storage. The main conclusions of this study were: herring byprodu...

  14. Ultrasound Assisted Esterification of Rubber Seed Oil for Biodiesel Production

    Directory of Open Access Journals (Sweden)

    Berkah Fajar Tamtomo Kiono

    2012-02-01

    Full Text Available roduction of biodiesel is currently shifting from the first to the second generation in which the raw materials are mostly from non-edible type oils and fats. Biodiesel production is commonly conducted under batch operation using mechanical agitation to accelerate mass transfers. The main drawback of oil esterification is the high content of free fatty acids (FFA which may reduce the yield of biodiesel and prolong the production time (2-5 hours. Ultrasonification has been used in many applications such as component extraction due to its ability to produce cavitation under certain frequency. This research is aimed to facilitate ultrasound system for improving biodiesel production process particularly rubber seed oil. An ultrasound unit was used under constant temperature (40oC and frequency of 40 Hz. The result showed that ultrasound can reduces the processing time and increases the biodiesel yield significantly. A model to describe correlation of yield and its independent variables is yield (Y = 43,4894 – 0,6926 X1 + 1,1807 X2 – 7,1042 X3 + 2,6451 X1X2 – 1,6557 X1X3 + 5,7586 X2X3 - 10,5145 X1X2X3, where X1 is mesh sizes, X2 ratio oil: methanol and X3 type of catalyst.

  15. Olive Oil Based Emulsions in Frozen Puff Pastry Production

    Science.gov (United States)

    Gabriele, D.; Migliori, M.; Lupi, F. R.; de Cindio, B.

    2008-07-01

    Puff pastry is an interesting food product having different industrial applications. It is obtained by laminating layers of dough and fats, mainly shortenings or margarine, having specific properties which provides required spreading characteristic and able to retain moisture into dough. To obtain these characteristics, pastry shortenings are usually saturated fats, however the current trend in food industry is mainly oriented towards unsatured fats such as olive oil, which are thought to be safer for human health. In the present work, a new product, based on olive oil, was studied as shortening replacer in puff pastry production. To ensure the desired consistency, for the rheological matching between fat and dough, a water-in-oil emulsion was produced based on olive oil, emulsifier and a hydrophilic thickener agent able to increase material structure. Obtained materials were characterized by rheological dynamic tests in linear viscoelastic conditions, aiming to setup process and material consistency, and rheological data were analyzed by using the weak gel model. Results obtained for tested emulsions were compared to theological properties of a commercial margarine, adopted as reference value for texture and stability. Obtained emulsions are characterized by interesting rheological properties strongly dependent on emulsifier characteristics and water phase composition. However a change in process temperature during fat extrusion and dough lamination seems to be necessary to match properly typical dough rheological properties.

  16. Pyrolysis of poppy capsule pulp for bio-oil production.

    Science.gov (United States)

    Hopa, Derya Yeşim; Yılmaz, Nazan; Alagöz, Oğuzhan; Dilek, Meltem; Helvacı, Ahmet; Durupınar, Ümit

    2016-12-01

    The feasibility of biofuel production via the pyrolysis of poppy capsule pulp, the main waste product of Afyon Alkoloid Factory, was investigated. The poppy capsule pulp was shown to have a high volatile matter content (ca. 76%). Pyrolysis experiments were carried out in the temperature range 400-550°C (heating rate 18°C min(-1) and holding time 20 min) under a nitrogen atmosphere. The chemical components of the bio-oil were characterized by Fourier transform infrared spectrometry and gas chromatography-mass spectrometry. The effects of pyrolysis temperature on the production efficiency and the calorific value of the bio-oil were investigated. The maximum bio-oil yield and its calorific value at 500°C were 23.6% and 31.6 MJ kg(-1), respectively. The latter value is close to that of many petroleum fractions. This high-energy bio-oil is therefore a clean fuel precursor and can be upgraded into higher quality fuels. © The Author(s) 2016.

  17. Recycling of waste engine oil for diesel production.

    Science.gov (United States)

    Maceiras, R; Alfonsín, V; Morales, F J

    2017-02-01

    The aim of this work was to recycle waste engine oil until converting it into reusable product, diesel fuel. The waste oil was treated using pyrolytic distillation. The effect of two additives (sodium hydroxide and sodium carbonate) in the purification of the obtained fuel was also studied. Moreover, the influence of the number of distillations were analysed. Some thermal and physicochemical properties (density, viscosity, colour, turbidity, acidity value, distillation curves, cetane number, corrosiveness to Cu, water content, flash point and hydrocarbons) were determined to analyse the quality of the obtained fuel. The best results were obtained with 2% of sodium carbonate and two successive distillations. The obtained results showed that pyrolytic distillation of waste engine oil is an excellent way to produce diesel fuel to be used in engines. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Water footprints of products of oil palm plantations and palm oil mills in Thailand.

    Science.gov (United States)

    Suttayakul, Phetrada; H-Kittikun, Aran; Suksaroj, Chaisri; Mungkalasiri, Jitti; Wisansuwannakorn, Ruthairat; Musikavong, Charongpun

    2016-01-15

    The water footprint (WF) of fresh fruit bunches (FFBs) from oil palm plantations and crude palm oil (CPO) from palm oil mills in southern and eastern Thailand were determined over 25 years. Climatic conditions, soil characteristics, and the characteristics of oil palm growth were considered. The WF of FFBs was 1063 m(3)/ton (t) on average. Green, blue, and grey waters comprised of 68, 18, and 14% of total WF, respectively. The oil palm plantations in Thailand required smaller amounts of indirect blue water. The average WF for producing a ton of CPO of seven mills was 5083 m(3). Most of the waters used in the mills originated from indirect green, blue and grey waters from the plantations. The direct blue water used in the mills had less impact on the total WF, lower than 1% of the total WF. Average percentages of green, blue, and grey waters of 69, 16, and 15% of total WF were determined for the mills, respectively. The water deprivation of the FFBs and CPO ranged from 0.73-12.9 and 3.44-58.3 m(3)H2Oeq/t, respectively. In 2013, the CPO production in Thailand including green, blue, and grey waters from plantation and blue water from mills required 11,343 million m(3) water. If the oil palm variety Suratthani 7 is used in the plantation, it would increase the yield from 15.2 to 22.8 t FFBs/ha-year and decrease the WF to 888 m(3)/t FFBs. The average value of the oil extraction rate (OER) of mills was 18.1%. With an increase in the OER of 1%, a reduction of the WF of 250 m(3)/t CPO or 5.1% of total WF could be obtained. Copyright © 2015 Elsevier B.V. All rights reserved.

  19. Okra (Hibiscus esculentus) seed oil for biodiesel production

    Energy Technology Data Exchange (ETDEWEB)

    Anwar, Farooq; Nadeem, Muhammad [Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad 38040 (Pakistan); Rashid, Umer [Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad 38040 (Pakistan); Department of Industrial Chemistry, Government College University, Faisalabad 38000 (Pakistan); Ashraf, Muhammad [Department of Botany, University of Agriculture, Faisalabad 38040 (Pakistan)

    2010-03-15

    Biodiesel was derived from okra (Hibiscus esculentus) seed oil by methanol-induced transesterification using an alkali catalyst. Transesterification of the tested okra seed oil under optimum conditions: 7:1 methanol to oil molar ratio, 1.00% (w/w) NaOCH{sub 3} catalyst, temperature 65 C and 600 rpm agitation intensity exhibited 96.8% of okra oil methyl esters (OOMEs) yield. The OOMEs/biodiesel produced was analyzed by GC/MS, which showed that it mainly consisted of four fatty acids: linoleic (30.31%), palmitic (30.23%), oleic (29.09%) and stearic (4.93%). A small amount of 2-octyl cyclopropaneoctanoic acid with contribution 1.92% was also established. Fuel properties of OOMEs such as density, kinematic viscosity, cetane number, oxidative stability, lubricity, flash point, cold flow properties, sulfur contents and acid value were comparable with those of ASTM D 6751 and EN 14214, where applicable. It was concluded that okra seed oil is an acceptable feedstock for biodiesel production. (author)

  20. Green polyurethane synthesis by emulsion technique: a magnetic composite for oil spill removal

    Directory of Open Access Journals (Sweden)

    Raphael Maria Dias da Costa

    Full Text Available Abstract After the consolidation of the Brazilian biodiesel industry, issues related to the final destination of the glycerin, the by-product from the biodiesel industrial process, drawing the attention of several researchers. There are several uses to this byproduct. Among them, the obtaining of polymers, such as polyurethane (PU, are very encouraged since the glycerin ca be used, as well as the castor oil, in the replacement of petrochemical polyols. The aim of this work was to propose a new route for the obtainment of a petroleum sorbent based on polyurethane resin from glycerin and castor oil, through the emulsion technique. In addition, maghemite (γ-Fe2O3 was mixed to the polymer matrix, producing a magnetic composite, able to make easier the oil cleanup process. The products synthesized were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, simultaneous Thermogravimetry (TGA and Differential scanning calorimetry (DSC, Optical microscopy, Scanning electron microscopy (SEM. In addition, magnetic force and oil removal capability tests were also performed. The magnetic material was used to remove oil from water, exhibited a good oil removal capability. In a typical test, 1g of the composite containing 5wt% of maghemite was able to remove 10g of oil from water.

  1. LHCb: CASTORFS - A Filesystem to Access CASTOR

    CERN Multimedia

    Mazurov, A

    2009-01-01

    CASTOR provides a powerful and rich interface for managing files and pools of files backed by tape-storage. The API is modelled very closely on that of a POSIX filesystem, where part of the actual I/O part is handled by the rfio library. While the API is very close to POSIX it is still separated, which unfortunately makes it impossible to use standard tools and scripts straight away. This is particularly inconvenient when applications are written in languages other than C/C++ such as is frequently the case in web-apps. Here up to now the only the recourse was to use command-line utilities and parse their output, which is clearly a kludge. We have implemented a complete POSIX filesystem to access CASTOR using FUSE (Filesystem in Userspace) and have successfully tested and used this on SLC4 and SLC5 (both in 32 and 64 bit). We call it CastorFS. In this paper we will present its architecture and implementation, with emphasis on performance and caching aspects.

  2. Production of rapeseed oil fuel in decentralized oil extraction plants. Handbook. 2. new rev. and enl. ed.; Herstellung von Rapsoelkraftstoff in dezentralen Oelgewinnungsanlagen. Handbuch

    Energy Technology Data Exchange (ETDEWEB)

    Remmele, Edgar [Technologie- und Foerderzentrum (TFZ) im Kompetenzzentrum fuer Nachwachsende Rohstoffe, Straubing (Germany)

    2009-11-15

    Increasing oil prices, the dependence on petroleum imports and the desire to reduce the CO{sub 2} emissions, are arguments to accelerate the production and utilization of biofuels. In 2007, 3.3 million tons of biodiesel and 772,000 tons of vegetable oil were used as fuel. The technically and economically successful production of rapeseed oil fuel in decentralized oil mills requires a quality assurance. Specifically, the brochure under consideration reports on the following: (1) Oilseed processing; (2) Centralized oil production in Germany; (3) Design of a decentralized oil mill; (4) Production of rapeseed oil fuel in decentralized systems; (5) Quality assurance for rapeseed oil fuel in decentralized oil mills; (6) Properties of rapeseed oil fuel; (7) Quality of rapeseed oil fuel from decentralized oil mills; (8) Economic aspects of decentralized oil extraction; (9) Legal framework conditions.

  3. Produção de etanol a partir de torta de mamona (Ricinus communis L. e avaliação da letalidade da torta hidrolisada para camundongos Ethanol production from castor bean cake (Ricinus communis L. and evaluation of the lethality of the cake for mice

    Directory of Open Access Journals (Sweden)

    Walber Carvalho Melo

    2008-01-01

    Full Text Available The castor bean cake is rich in starch (48 ± 0.53% and bears a problem linked to the occurrence of a toxic protein (ricin. The chemical hydrolysis (ratio solid:liquid = 1:6; H2SO4= 0.1 mol L-1; 120 °C; 40 min generated a medium with 27 g L-1 of reducing sugars (hydrolysis efficiency= 32%. The hydrolyzed product was fermented and produced 11 g L-1 of ethanol (volumetric productivity=1.38 g L-1 h-1 and ethanol yield on substrate consumed=0.45 g g-1. In vivo experiments (DL50 revealed a reduction of roughly 240 times in the CBC toxicity (2.11 µg g-1.

  4. Indigenous production of biosurfactant and degradation of crude oil

    Directory of Open Access Journals (Sweden)

    Hamid Rashedi

    2015-04-01

    Full Text Available The present study investigated the isolation and identification of biosurfactant producing bacteria from Iranian oil wells. The biosurfactant production of bacteria isolates was evaluated and confirmed using hemolysis and emulsification tests. The biodegradation of crude oil was studied using GC and HPLC analysis. A total of 45 strains have been isolated. These strains showed less than a 40 mN m-1 reduction in surface tension. The effects of different pH (4.2-9.2, salinity concentrations (1%-15%, and temperatures (25-50 in biosurfactant production of isolated strains were evaluated. One of the strains (Bacillus sp. NO.4 showed a high salt tolerance and a successful production of biosurfactant in a vast pH range. Its maximum biomass production (about 3.1 g L-1 dry weight was achieved after 60 hours of growth. The surface tension of the culture broth dropped rapidly after inoculation and reached its lowest value (36 mN m-1 during the exponential phase after about 36-48 hours of growth. The study of the GC graphs showed that higher aliphatic reduction occurred in fractions with C14 to C24 hydrocarbons. The depicted results of the HPLC graphs indicated a 100% degradation of chrysene and fluorine. In this study, we demonstrated the useful capacities of the isolates in removing oil pollutants and their application in MEOR in vitro.

  5. Characterizing risk factors for pediatric lamp oil product exposures.

    Science.gov (United States)

    Sheikh, S; Chang, A; Kieszak, S; Law, R; Bennett, H K W; Ernst, E; Bond, G R; Spiller, H A; Schurz-Rogers, H; Chu, A; Bronstein, A C; Schier, J G

    2013-11-01

    Poisonings from lamp oil ingestion continue to occur worldwide among the pediatric population despite preventive measures such as restricted sale of colored and scented lamp oils. This suggests that optimal prevention practices for unintentional pediatric exposures to lamp oil have yet to be identified and/or properly implemented. To characterize demographic, health data, and potential risk factors associated with reported exposures to lamp oil by callers to poison centers (PCs) in the US and discuss their public health implications. This was a two part study in which the first part included characterizing all exposures to a lamp oil product reported to the National Poison Data System (NPDS) with regard to demographics, exposure, health, and outcome data from 1/1/2000 to 12/31/2010. Regional penetrance was calculated using NPDS data by grouping states into four regions and dividing the number of exposure calls by pediatric population per region (from the 2000 US census). Temporal analyses were performed on NPDS data by comparing number of exposures by season and around the July 4th holiday. Poisson regression was used to model the count of exposures for these analyses. In the second part of this project, in order to identify risk factors we conducted a telephone-based survey to the parents of children from five PCs in five different states. The 10 most recent lamp oil product exposure calls for each poison center were systematically selected for inclusion. Calls in which a parent or guardian witnessed a pediatric lamp oil product ingestion were eligible for inclusion. Data on demographics, exposure information, behavioral traits, and health were collected. A descriptive analysis was performed and Fisher's exact test was used to evaluate associations between variables. All analyses were conducted using SAS v9.3. Among NPDS data, 2 years was the most common patient age reported and states in the Midwestern region had the highest numbers of exposure calls compared to

  6. Biosurfactant production and use in oil tank clean-up.

    Science.gov (United States)

    Banat, I M; Samarah, N; Murad, M; Horne, R; Banerjee, S

    1991-01-01

    A proprietary bacterial strain (Pet 1006) produced biosurfactants when grown on both glucose and an immiscible hydrocarbon as carbon sources. Pilot-plant-scale (1500 I) production gave, on repeated batch runs, 2 tonnes of culture broth containing active biosurfactant. The product was used as a substitute for chemical surfactants in a clean-up demonstration test carried out by Cargo Fleet Chemical Company Ltd. (UK) on an oil storage tank belonging to Kuwait Oil Company, Kuwait. The clean-up was successful in removing the sludge from the tank bottom, and it also allowed the recovery of more than 90% of the hydrocarbon trapped in the sludge. The recovered hydrocarbon had excellent properties and could be sold after being blended with fresh crude.

  7. Possibility of direct electricity production from waste canola oil

    Directory of Open Access Journals (Sweden)

    Włodarczyk Paweł P.

    2017-01-01

    Full Text Available Powering high-efficiency devices, such as fuel cells, with waste products will allow for a broader development of renewable energy sources and utilisation of by- products. This publication presents the possibility of electrooxidation of the emulsion of waste rapeseed oil, prepared on the basis of the detergent Syntanol DS-10. The process of electrooxidation was carried out on platinum electrode in alkaline (KOH and acidic (H2SO4 electrolyte, in the temperature range of 293-333 K. In each analysed case the process of electrooxidation took place. The maximum current density obtained was 7 mA cm-2. Thus, it has been shown that it is possible to generate electricity directly from the emulsion of the waste rapeseed oil.

  8. Possibility of direct electricity production from waste canola oil

    Science.gov (United States)

    Włodarczyk, Paweł P.; Włodarczyk, Barbara; Kalinichenko, Antonina

    2017-10-01

    Powering high-efficiency devices, such as fuel cells, with waste products will allow for a broader development of renewable energy sources and utilisation of by- products. This publication presents the possibility of electrooxidation of the emulsion of waste rapeseed oil, prepared on the basis of the detergent Syntanol DS-10. The process of electrooxidation was carried out on platinum electrode in alkaline (KOH) and acidic (H2SO4) electrolyte, in the temperature range of 293-333 K. In each analysed case the process of electrooxidation took place. The maximum current density obtained was 7 mA cm-2. Thus, it has been shown that it is possible to generate electricity directly from the emulsion of the waste rapeseed oil.

  9. Estudo experimental do poliuretano de óleo de mamona (Ricinus communis como substituto parcial do tendão calcâneo comum em coelhos (Oryctolagus cuniculus An experimental study of polyurethane of castor-oil plant (Ricinus communis as a partial substitute of the common calcaneous tendon in rabbits (Oryctogalus cuniculus

    Directory of Open Access Journals (Sweden)

    C.M.F. Rezende

    2001-12-01

    Full Text Available Com o objetivo de avaliar a eficiência da prótese de poliuretano de mamona como substituto parcial do tendão calcâneo comum, foram utilizadas 30 coelhas da raça Nova Zelândia, entre dois e três meses de idade e peso médio de 2kg. Após anestesia geral, o procedimento cirúrgico em ambos os membros constou de incisão caudo-lateral no sentido longitudinal do terço médio ao distal da tíbia e exposição do tendão calcâneo comum. Após a tenectomia do tendão do músculo gastrocnêmio, a prótese de poliuretano de cerca de 0,5cm de extensão por 0,5cm de diâmetro foi fixada aos cotos proximal e distal do tendão, empregando-se o fio de polipropileno monofilamentar 4-0, conforme técnica modificada de Kessler. A prótese de poliuretano na forma elastomérica revelou propriedades como textura e flexibilidade semelhantes à do tecido tendinoso, pode ser confeccionada na forma e no tamanho almejados e permite ser moldada, cortada e esterilizada por calor úmido. Todos os animais apoiaram os membros operados imediatamente após o retorno anestésico. Não se observaram sinais clínicos de infecção e não ocorreu deiscência de ferida. Percebeu-se aumento de volume local devido ao edema, evidente na primeira semana pós-cirúrgica, que gradualmente desapareceu . À palpação foi possível delimitar com facilidade a prótese que se conservou fixa no local e intacta. Clinicamente o poliuretano de mamona não induziu reação desfavorável que comprometesse a cicatrização tendínea, podendo ser indicado como substituto temporário de tendão.With the goal of evaluating the efficiency of a prosthesis of castor-oil plant (Ricinus communis polyurethane as a partial substitute for common calcaneous tendon, 30 New Zealand female rabbits, aging between two to three months, weighting about 2kg were used. After general anesthesia, the surgical procedure in both members consisted of rear lateral longitudinal incision, in the medium third of the

  10. Effects of autoclaving on the proximate composition of stored castor (Ricinus communis seeds

    Directory of Open Access Journals (Sweden)

    ANTHONY NEGEDU

    2013-11-01

    Full Text Available Negedu A, Ameh JB, Umoh VJ, Atawodi SE, Rai MK. 2013. Effects of autoclaving on the proximate composition of stored castor (Ricinus communis seeds. Nusantara Bioscience 5: 51-56. The effect of autoclaving on the proximate composition, free fatty acids and peroxide value of castor (Ricinus communis L. seeds in storage were studied. Seeds of castor were surface sterilized, dried and divided into two equal sets of 300g each. One set was autoclaved at 15 1b pressure for 30 minutes at 121oC and the other set served as control. Each set was prepared in triplicates and both sets were stored under same room temperature conditions for a period of 180 days and agitated intermittently. Analysis of the proximate composition showed that autoclaving treatment caused an increased total fat content, reduced moisture, protein, nitrogen free extract (soluble sugar and ash contents of the seeds in storage, as well as a non-significant increase in crude fiber (non-soluble sugar content. It increased the free fatty acid content and decreased the peroxide value of seed oil.

  11. Recent developments in microbial oils production: a possible alternative to vegetable oils for biodiesel without competition with human food?

    Directory of Open Access Journals (Sweden)

    Gwendoline Christophe

    2012-02-01

    Full Text Available Since centuries vegetable oils are consumed as human food but it also finds applications in biodiesel production which is attracting more attention. But due to being in competition with food it could not be sustainable and leads the need to search for alternative. Nowdays microbes-derived oils (single cell oils seem to be alternatives for biodiesel production due to their similar composition to that of vegetable oils. However, the cold flow properties of the biodiesel produced from microbial oils are unacceptable and have to be modified by an efficient transesterification. Glycerol which is by product of transesterification can be valorised into some more useful products so that it can also be utilised along with biodiesel to simplify the downstream processing. The review paper discusses about various potent microorganisms for biodiesel production, enzymes involved in the lipid accumulation, lipid quantification methods, catalysts used in transesterification (including enzymatic catalyst and valorisation of glycerol.

  12. Valorization of By-Products from Palm Oil Mills for the Production of Generic Fermentation Media for Microbial Oil Synthesis.

    Science.gov (United States)

    Tsouko, Erminda; Kachrimanidou, Vasiliki; Dos Santos, Anderson Fragoso; do Nascimento Vitorino Lima, Maria Eduarda; Papanikolaou, Seraphim; de Castro, Aline Machado; Freire, Denise Maria Guimarães; Koutinas, Apostolis A

    2017-04-01

    This study demonstrates the production of a generic nutrient-rich feedstock using by-product streams from palm oil production that could be used as a substitute for commercial fermentation supplements. Solid-state fermentations of palm kernel cake (PKC) and palm-pressed fiber (PPF) were conducted in tray bioreactors and a rotating drum bioreactor by the fungal strain Aspergillus oryzae for the production of crude enzymes. The production of protease was optimized (319.3 U/g) at an initial moisture content of 55 %, when PKC was used as the sole substrate. The highest free amino nitrogen (FAN) production (5.6 mg/g) obtained via PKC hydrolysis using the crude enzymes produced via solid-state fermentation was achieved at 50 °C. Three initial PKC concentrations (48.7, 73.7, and 98.7 g/L) were tested in hydrolysis experiments, leading to total Kjeldahl nitrogen to FAN conversion yields up to 27.9 %. Sequential solid-state fermentation followed by hydrolysis was carried out in the same rotating drum bioreactor, leading to the production of 136.7 U/g of protease activity during fermentation and 196.5 mg/L of FAN during hydrolysis. Microbial oil production was successfully achieved with the oleaginous yeast strain Lipomyces starkeyi DSM 70296 cultivated on the produced PKC hydrolysate mixed with commercial carbon sources, including glucose, xylose, mannose, galactose, and arabinose.

  13. Profit and Risk Measures in Oil Production Optimization

    DEFF Research Database (Denmark)

    Capolei, Andrea; Foss, Bjarne; Jørgensen, John Bagterp

    2015-01-01

    In oil production optimization, we usually aim to maximize a deterministic scalar performance index such as the profit over the expected reservoir lifespan. However, when uncertainty in the parameters is considered, the profit results in a random variable that can assume a range of values dependi...... pro and cons for each of them. Finally, among the presented risk measures, we identify two of them as appropriate risk measures when minimizing the risk....

  14. Diesel-like fuel obtained by pyrolysis of vegetable oils

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Daniela G.; Soares, Valerio C.D.; Ribeiro, Eric B.; Cardoso, Erika C.V.; Rassi, Flavia C.; Mundim, Kleber C.; Rubim, Joel C.; Suarez, Paulo A.Z. [Instituto de Quimica, Universidade de Brasilia, CP 4478, 70919-970 Brasilia-DF (Brazil); Carvalho, Daniel A. [CEPAT-ANP, Brasilia-DF (Brazil)

    2004-06-01

    The pyrolysis reactions of soybean, palm tree, and castor oils were studied. The pyrolytic products were analyzed by CG-FID, CG-MS, and FTIR, showing the formation of olefins, paraffins, carboxylic acids, and aldehydes. The adequate choice of distillation temperature (DT) ranges made it possible to isolate fuels with physical-chemical properties comparable to those specified for petroleum based fuels. The catalytic upgrading of the soybean pyrolytic fuel over HZSM-5 zeolite at 400C was also studied and has shown a partial deoxygenation of the pyrolytic products.

  15. Waste Cooking Oil as an Alternate Feedstock for Biodiesel Production

    Directory of Open Access Journals (Sweden)

    M. Rafiqul Islam

    2008-04-01

    Full Text Available As crude oil price reach a new high, the need for developing alternate fuels has become acute. Alternate fuels should be economically attractive in order to compete with currently used fossil fuels. In this work, biodiesel (ethyl ester was prepared from waste cooking oil collected from a local restaurant in Halifax, Nova Scotia, Canada. Ethyl alcohol with sodium hydroxide as a catalyst was used for the transesterification process. The fatty acid composition of the final biodiesel esters was determined by gas chromatography. The biodiesel was characterized by its physical and fuel properties including density, viscosity, acid value, flash point, cloud point, pour point, cetane index, water and sediment content, total and free glycerin content, diglycerides and monoglycerides, phosphorus content and sulfur content according to ASTM standards. The viscosity of the biodiesel ethyl ester was found to be 5.03 mm2/sec at 40oC. The viscosity of waste cooking oil measured in room temperature (at 21° C was 72 mm2/sec. From the tests, the flash point was found to be 164oC, the phosphorous content was 2 ppm, those of calcium and magnesium were 1 ppm combined, water and sediment was 0 %, sulfur content was 2 ppm, total acid number was 0.29 mgKOH/g, cetane index was 61, cloud point was -1oC and pour point was -16oC. Production of biodiesel from waste cooking oils for diesel substitute is particularly important because of the decreasing trend of economical oil reserves, environmental problems caused due to fossil fuel use and the high price of petroleum products in the international market.

  16. [Job satisfaction and its influential factors in oil production workers].

    Science.gov (United States)

    He, Ya-hui; Meng, Xian-hai; Yu, Shan-fa; Qi, Xiu-ying

    2008-03-01

    To investigate the job satisfaction and its influential factors in oil production workers. 423 oil production workers were investigated using the Occupational Stress Instrument. The job satisfaction, job organization satisfaction, job itself satisfaction in the workers aged aged > or = 30 years old (49.34 +/- 10.12, 24.60 +/- 5.40, 24.74 +/- 5.36 respectively) (P job satisfaction in the groups of different service length was significantly different. The job satisfaction in the workers of service length 5-10 years was the lowest compared with those of service length 10 years (P job satisfaction. The relationship between psychological health, work locus of control, coping strategies, affective balance and social support showed a statistical significance difference (P job satisfaction as strain and personal characters, occupational stress factors, coping as independent variables. Five variables entered regression equation. They were work locus of control, affective balance, social support, psychological health and coping strategies. The job satisfaction of oil production workers is affected by multiple factors such as the age, work length and social support.

  17. Organic Substances from Unconventional Oil and Gas Production in Shale

    Science.gov (United States)

    Orem, W. H.; Varonka, M.; Crosby, L.; Schell, T.; Bates, A.; Engle, M.

    2014-12-01

    Unconventional oil and gas (UOG) production has emerged as an important element in the US and world energy mix. Technological innovations in the oil and gas industry, especially horizontal drilling and hydraulic fracturing, allow for the enhanced release of oil and natural gas from shale compared to conventional oil and gas production. This has made commercial exploitation possible on a large scale. Although UOG is enormously successful, there is surprisingly little known about the effects of this technology on the targeted shale formation and on environmental impacts of oil and gas production at the surface. We examined water samples from both conventional and UOG shale wells to determine the composition, source and fate of organic substances present. Extraction of hydrocarbon from shale plays involves the creation and expansion of fractures through the hydraulic fracturing process. This process involves the injection of large volumes of a water-sand mix treated with organic and inorganic chemicals to assist the process and prop open the fractures created. Formation water from a well in the New Albany Shale that was not hydraulically fractured (no injected chemicals) had total organic carbon (TOC) levels that averaged 8 mg/L, and organic substances that included: long-chain fatty acids, alkanes, polycyclic aromatic hydrocarbons, heterocyclic compounds, alkyl benzenes, and alkyl phenols. In contrast, water from UOG production in the Marcellus Shale had TOC levels as high as 5,500 mg/L, and contained a range of organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at thousands of μg/L for individual compounds. These chemicals and TOC decreased rapidly over the first 20 days of water recovery as injected fluids were recovered, but residual organic compounds (some naturally-occurring) remained up to 250 days after the start of water recovery (TOC 10-30 mg/L). Results show how hydraulic fracturing changes the organic

  18. Potential of eleven Eucalyptus species for the production of essential oils

    OpenAIRE

    Silva,Paulo Henrique Müller da; Brito,José Otávio; Silva Junior,Francides Gomes da

    2006-01-01

    Most Eucalyptus plantations in Brazil aim the production of paper and charcoal, but the use of the species for lumbering, construction and extraction of essential oil has increased. Eleven species of Eucalyptus were assessed in regard to their essential oil production potential, nine never used before for commercial, essential oil extraction. Assessements were compared with Eucalyptus citriodora and Eucalyptus globulus, already explored in oil production for perfume and medical purposes, aimi...

  19. Inheritance of plant height in two Ethiopian castor varieties | Alemaw ...

    African Journals Online (AJOL)

    Castor varieties are tall in plant height which makes them difficult for harvesting. A study was carried out to investigate the inheritance of plant height among two tall Castor varieties Hiruy and Abaro and one dwarf experimental line MD-1 during 2012 to 2014 at Melkassa. The F1 from reciprocal crosses of Abaro and Hiruy ...

  20. Life cycle inventory for the production of germinated oil palm seeds at a selected seed production unit in Malaysia

    Science.gov (United States)

    Khairuddin, Nik Sasha Khatrina; Ismail, B. S.; Muhamad, Halimah; May, Choo Yuen

    2013-11-01

    The increasing global demand for edible oil has encouraged Malaysia to increase the areas under oil palm cultivation. The total demand for germinated oil palm seeds in the years 2009, 2010, 2011 and 2012 were 86.4, 76.5, 72.6 and 75.2 million, respectively. Production of germinated oil palm seeds is the first link in the palm oil supply chain. Therefore, good management practices at seed production stage is required to ensure only high quality germinated oil palm seeds are produced before sale to customers. Life cycle assessment (LCA) has been used as a tool to assess environmental impact of the processes throughout a product's lifespan and this approach is an important tool for assessing green house gas (GHG) emission. For this study, a gate-to-gate life cycle inventory (LCI) of a single germinated oil palm seed production unit was carried out. The functional unit used for this LCI was one germinated oil palm seed. To determine the environmental impact for the production of germinated oil palm seeds, information on the inputs were obtained. The inputs for the production of germinated oil palm seeds involved materials such as polyethylene bags, electricity, water, chemicals and fungicides. For this study, the system boundary involved seed germination process and management of germinated oil palm seeds. It was found that the amount of input such as materials and energy used in the production of germinated oil palm seeds was very minimal.

  1. Microbiological Production of Citric and Isocitric Acids from Sunflower Oil

    Directory of Open Access Journals (Sweden)

    Svetlana V. Kamzolova

    2008-01-01

    Full Text Available The growth of wild type strain Yarrowia lipolytica VKM Y-2373 and its mutant Yarrowia lipolytica N 15 as well the biosynthesis of citric and isocitric acids on sunflower oil were studied. It was indicated that cell growth was associated with the simultaneous utilization of glycerol and free fatty acids produced during oil hydrolysis. The activities of enzymes of glycerol metabolism (glycerol kinase, fatty acid assimilation enzymes of glyoxylate cycle (isocitrate lyase and malate synthase and citric acid cycle were comparatively assayed in Y. lipolytica grown on sunflower oil, glycerol and oleic acid. Glycerol kinase and enzymes of glyoxylate cycle were active during the whole period of cell cultivation on sunflower oil. Citric acid production and a ratio between citric and isocitric acids depended on both the strain used and the medium composition. It was revealed that wild type strain Y. lipolytica VKM Y-2373 produced almost equal amounts of citric and isocitric acids at pH=4.5 and predominantly accumulated isocitric acid at pH=6.0. The mutant Y. lipolytica N 15 produced only citric acid (150 g/L with mass yield (YCA of 1.32 g/g. Biochemical characteristics of mutant strain Y. lipolytica N 15 were discussed.

  2. Enzymatic production of biodiesel from canola oil using immobilized lipase

    Energy Technology Data Exchange (ETDEWEB)

    Dizge, Nadir; Keskinler, Buelent [Department of Environmental Engineering, Gebze Institute of Technology, Gebze 41400 (Turkey)

    2008-12-15

    In the present work, a novel method for immobilization of lipase within hydrophilic polyurethane foams using polyglutaraldehyde was developed for the immobilization of Thermomyces lanuginosus lipase to produce biodiesel with canola oil and methanol. The enzyme optimum conditions were not affected by immobilization and the optimum pH for free and immobilized enzyme were 6, resulting in 80% immobilization yield. Using the immobilized lipase T. lanuginosus, the effects of enzyme loading, oil/alcohol molar ratio, water concentration, and temperature in the transesterification reaction were investigated. The optimal conditions for processing 20 g of refined canola oil were: 430 {mu}g lipase, 1:6 oil/methanol molar ratio, 0.1 g water and 40 C for the reactions with methanol. Maximum methyl esters yield was 90% of which enzymatic activity remained after 10 batches, when tert-butanol was adopted to remove by-product glycerol during repeated use of the lipase. The immobilized lipase proved to be stable and lost little activity when was subjected to repeated uses. (author)

  3. Castor halls. A problem for the century; Castor-Hallen. Ein Jahrhundertproblem

    Energy Technology Data Exchange (ETDEWEB)

    Stay, Jochen

    2017-01-15

    The interim storage of high-level radioactive waste will last longer than asserted. The existing halls for the castor casks are not appropriate for this task with respect to safety. The casks themselves are not designed for long-term storage. Politics obviously do not consider the problems seriously.

  4. Technology transfer to US oil producers: A policy tool to sustain or increase oil production

    Energy Technology Data Exchange (ETDEWEB)

    Dowd, W. T.

    1990-03-01

    The Department of Energy provided the Interstate Oil Compact Commission with a grant to identify and evaluate existing technology transfer channels to operators, to devise and test improvements or new technology transfer channels and to make recommendations as to how the Department of Energy's oil and gas technology transfer methods could be improved. The IOCC conducted this effort in a series of four tasks: a structural analysis to characterize the oil producing industry according to operator production size class, geographic location, awareness and use of reservoir management technologies, and strategies for adding reserves and replacing produced reserves; targeted interviews conducted with some 300 oil and gas industry participants to identify current technology transfer channels and their relative usefulness for various classes of industry participants; a design and testing phase, in which the IOCC critiqued the current technology transfer structure, based on results of the structural analysis and targeted interviews, and identified several strategies for improvement; and an evaluation of existing state outreach programs to determine whether they might provide a model for development of additional outreach programs in other producing states.

  5. Engineered microbes and methods for microbial oil production

    Energy Technology Data Exchange (ETDEWEB)

    Stephanopoulos, Gregory; Tai, Mitchell; Chakraborty, Sagar

    2015-02-10

    Some aspects of this invention provide engineered microbes for oil production. Methods for microbe engineering and for use of engineered microbes are also provided herein. In some embodiments, microbes are provided that are engineered to modulate a combination of rate-controlling steps of lipid synthesis, for example, a combination of a step generating metabolites, acetyl-CoA, ATP or NADPH for lipid synthesis (a push step), and a step sequestering a product or an intermediate of a lipid synthesis pathway that mediates feedback inhibition of lipid synthesis (a pull step). Such push-and-pull engineered microbes exhibit greatly enhanced conversion yields and TAG synthesis and storage properties.

  6. Engineered microbes and methods for microbial oil production

    Energy Technology Data Exchange (ETDEWEB)

    Stephanopoulos, Gregory; Tai, Mitchell; Chakraborty, Sagar

    2018-01-09

    Some aspects of this invention provide engineered microbes for oil production. Methods for microbe engineering and for use of engineered microbes are also provided herein. In some embodiments, microbes are provided that are engineered to modulate a combination of rate-controlling steps of lipid synthesis, for example, a combination of a step generating metabolites, acetyl-CoA, ATP or NADPH for lipid synthesis (a push step), and a step sequestering a product or an intermediate of a lipid synthesis pathway that mediates feedback inhibition of lipid synthesis (a pull step). Such push-and-pull engineered microbes exhibit greatly enhanced conversion yields and TAG synthesis and storage properties.

  7. Hazards from handling mineral oil products. Gefahren beim Umgang mit Mineraloelprodukten

    Energy Technology Data Exchange (ETDEWEB)

    Zimmer, A.

    1991-01-01

    In forestry, mineral oil products are ubiquintous as operating materials. Their uses are manifold. Products used are fuel mixtures for motor saws, carburettor and diesel fuels for working machinery, engine, hydraulic, and gear lubricant oil as well as lubricating greases. So, almost anybody working in forestry has day-to-day contact with mineral oil products. This brochure wants to point out possible hazards to health from contact with mineral oil products. Furthermore, such measures are pointed out as are necessary to minimize risks for those concerned. Possible cancerogeneous effects of mineral oil products are mentioned. The measures indicated aim is in the first place to reduce exposure to mineral oil products to a minimum. In addition, general hints regarding the handling of mineral oil products are given. (orig./BBR).

  8. Indonesia palm oil production without deforestation and peat conversion by 2050.

    Science.gov (United States)

    Afriyanti, Dian; Kroeze, Carolien; Saad, Asmadi

    2016-07-01

    Palm oil is a promising source of cooking oil and biodiesel. The demand for palm oil has been increasing worldwide. However, concerns exist surrounding the environmental and socio-economic sustainability of palm oil production. Indonesia is a major palm oil producing country. We explored scenarios for palm oil production in Indonesia until 2050, focusing on Sumatra, Kalimantan and Papua. Our scenarios describe possible trends in crude palm oil production in Indonesia, while considering the demand for cooking oil and biodiesel, the available land for plantations, production capacity (for crude palm oil and fresh fruit bunches) and environmentally restricting conditions. We first assessed past developments in palm oil production. Next, we analysed scenarios for the future. In the past 20years, 95% of the Indonesian oil palm production area was in Sumatra and Kalimantan and was increasingly cultivated in peatlands. Our scenarios for the future indicate that Indonesia can meet a considerable part of the global and Asian demand for palm oil, while avoiding further cultivation of peatlands and forest. By 2050, 264-447Mt crude palm oil may be needed for cooking oil and biodiesel worldwide. In Indonesia, the area that is potentially suitable for oil palm is 17 to 26Mha with a potential production rate of 27-38t fresh fruit bunches/ha, yielding 130-176Mt crude palm oil. Thus Indonesia can meet 39-60% of the international demand. In our scenarios this would be produced in Sumatra (21-26%), Kalimantan (12-16%), and Papua (2%). The potential areas include the current oil palm plantation in mineral lands, but exclude the current oil palm plantations in peatlands. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. Mineral oil and synthetic hydrocarbons in cosmetic lip products.

    Science.gov (United States)

    Niederer, M; Stebler, T; Grob, K

    2016-04-01

    Lipsticks and lip care products may contain saturated hydrocarbons which either stem from mineral oil saturated hydrocarbons (MOSH) or are synthetic, that is polyolefin oligomeric saturated hydrocarbons (POSH). Some of these hydrocarbons are strongly accumulated and form granulomas in human tissues, which prompted Cosmetics Europe (former Colipa) to issue a recommendation for their use in lip care and oral products. From 2012 to 2014, MOSH+POSH were determined in 175 cosmetic lip products taken from the Swiss market in order to estimate their contribution to human exposure. Mineral oil saturated hydrocarbons and POSH were extracted and analysed by GC with FID. Areas were integrated as a total as well as by mass ranges with cuts at n-C25 and n-C34 to characterize the molecular mass distribution. About 68% of the products contained at least 5% MOSH+POSH (total concentration). For regular users, these products would be major contributors to their MOSH+POSH exposure. About 31% of the products contained more than 32% MOSH+POSH. Their regular usage would amount in an estimated MOSH+POSH exposure exceeding the highest estimated dietary exposure. The majority of the products contained hydrocarbons with a molecular mass range which was not in line with the recommendations of Cosmetics Europe. Taking into account that material applied to the lips largely ends up being ingested, MOSH and POSH levels should be reduced in the majority of cosmetic lip products. As the extensive evaluation of the data available on MOSH (EFSA J., 10, 2012, 2704) did not enable the specification of limits considered as safe, the present level of dietary exposure and its evaluation as 'of potential concern' provide the relevant bench mark, which means that lip products should contain clearly less than 5% MOSH+POSH. © 2015 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

  10. Production Strategies and Applications of Microbial Single Cell Oils

    Science.gov (United States)

    Ochsenreither, Katrin; Glück, Claudia; Stressler, Timo; Fischer, Lutz; Syldatk, Christoph

    2016-01-01

    Polyunsaturated fatty acids (PUFAs) of the ω-3 and ω-6 class (e.g., α-linolenic acid, linoleic acid) are essential for maintaining biofunctions in mammalians like humans. Due to the fact that humans cannot synthesize these essential fatty acids, they must be taken up from different food sources. Classical sources for these fatty acids are porcine liver and fish oil. However, microbial lipids or single cell oils, produced by oleaginous microorganisms such as algae, fungi and bacteria, are a promising source as well. These single cell oils can be used for many valuable chemicals with applications not only for nutrition but also for fuels and are therefore an ideal basis for a bio-based economy. A crucial point for the establishment of microbial lipids utilization is the cost-effective production and purification of fuels or products of higher value. The fermentative production can be realized by submerged (SmF) or solid state fermentation (SSF). The yield and the composition of the obtained microbial lipids depend on the type of fermentation and the particular conditions (e.g., medium, pH-value, temperature, aeration, nitrogen source). From an economical point of view, waste or by-product streams can be used as cheap and renewable carbon and nitrogen sources. In general, downstream processing costs are one of the major obstacles to be solved for full economic efficiency of microbial lipids. For the extraction of lipids from microbial biomass cell disruption is most important, because efficiency of cell disruption directly influences subsequent downstream operations and overall extraction efficiencies. A multitude of cell disruption and lipid extraction methods are available, conventional as well as newly emerging methods, which will be described and discussed in terms of large scale applicability, their potential in a modern biorefinery and their influence on product quality. Furthermore, an overview is given about applications of microbial lipids or derived fatty

  11. Production Strategies and Applications of Microbial Single Cell Oils.

    Science.gov (United States)

    Ochsenreither, Katrin; Glück, Claudia; Stressler, Timo; Fischer, Lutz; Syldatk, Christoph

    2016-01-01

    Polyunsaturated fatty acids (PUFAs) of the ω-3 and ω-6 class (e.g., α-linolenic acid, linoleic acid) are essential for maintaining biofunctions in mammalians like humans. Due to the fact that humans cannot synthesize these essential fatty acids, they must be taken up from different food sources. Classical sources for these fatty acids are porcine liver and fish oil. However, microbial lipids or single cell oils, produced by oleaginous microorganisms such as algae, fungi and bacteria, are a promising source as well. These single cell oils can be used for many valuable chemicals with applications not only for nutrition but also for fuels and are therefore an ideal basis for a bio-based economy. A crucial point for the establishment of microbial lipids utilization is the cost-effective production and purification of fuels or products of higher value. The fermentative production can be realized by submerged (SmF) or solid state fermentation (SSF). The yield and the composition of the obtained microbial lipids depend on the type of fermentation and the particular conditions (e.g., medium, pH-value, temperature, aeration, nitrogen source). From an economical point of view, waste or by-product streams can be used as cheap and renewable carbon and nitrogen sources. In general, downstream processing costs are one of the major obstacles to be solved for full economic efficiency of microbial lipids. For the extraction of lipids from microbial biomass cell disruption is most important, because efficiency of cell disruption directly influences subsequent downstream operations and overall extraction efficiencies. A multitude of cell disruption and lipid extraction methods are available, conventional as well as newly emerging methods, which will be described and discussed in terms of large scale applicability, their potential in a modern biorefinery and their influence on product quality. Furthermore, an overview is given about applications of microbial lipids or derived fatty

  12. Production strategies and applications of microbial single cell oils

    Directory of Open Access Journals (Sweden)

    Katrin Ochsenreither

    2016-10-01

    Full Text Available Polyunsaturated fatty acids (PUFAs of the -3 and -6 class (e.g. -linolenic acid, linoleic acid are essential for maintaining biofunctions in mammalians like humans. Due to the fact that humans cannot synthesize these essential fatty acids, they must be taken up from different food sources. Classical sources for these fatty acids are porcine liver and fish oil. However, microbial lipids or single cell oils, produced by oleaginous microorganisms such as algae, fungi and bacteria, are a promising source as well. These single cell oils can be used for many valuable chemicals with applications not only for nutrition but also for fuels and are therefore an ideal basis for a bio-based economy. A crucial point for the establishment of microbial lipids utilization is the cost-effective production and purification of fuels or products of higher value. The fermentative production can be realized by submerged (SmF or solid state fermentation (SSF. The yield and the composition of the obtained microbial lipids depend on the type of fermentation and the particular conditions (e.g. medium, pH-value, temperature, aeration, nitrogen source. From an economical point of view, waste or by-product streams can be used as cheap and renewable carbon and nitrogen sources. In general, downstream processing costs are one of the major obstacles to be solved for full economic efficiency of microbial lipids. For the extraction of lipids from microbial biomass cell disruption is most important, because efficiency of cell disruption directly influences subsequent downstream operations and overall extraction efficiencies. A multitude of cell disruption and lipid extraction methods are available, conventional as well as newly emerging methods, which will be described and discussed in terms of large scale applicability, their potential in a modern biorefinery and their influence on product quality. Furthermore, an overview is given about applications of microbial lipids

  13. Biodiesel production from vegetable oil: Process design, evaluation and optimization

    Directory of Open Access Journals (Sweden)

    Kianimanesh Hamid Reza

    2017-09-01

    Full Text Available To investigate the effect of reactor performance/configuration of biodiesel production on process parameters (mass & energy consumption, required facilities etc., two diverse production processes (from vegetable oil were implemented/designed using Aspen HYSYS V7.2. Two series reactors were taken into account where overall conversion was set to be 97.7% and 70% in first and second processes respectively. Comparative analysis showed that an increase in conversion yield caused to consumption reduction of oil, methanol, cold energy and hot energy up to 9.1%, 22%, 67.16% and 60.28% respectively; further, a number of facilities (e.g. boiler, heat exchanger, distillation tower were reduced. To reduce mass & energy consumption, mass/heat integration method was employed. Applying integration method showed that in the first design, methanol, cold and hot energy were decreased by 49.81%, 17.46% and 36.17% respectively; while in the second design, oil, methanol, cold and hot energy were decreased by 9%, 60.57% 19.62% and 36.58% respectively.

  14. Approaches to cold heavy oil production workover practices and strategies

    Energy Technology Data Exchange (ETDEWEB)

    Walin, C.; Dusseault, M.B. [Waterloo Univ., ON (Canada); Haves, K. [Kirby Hayes Inc., Calgary, AB (Canada); Kremer, M. [Husky Oil Operations Ltd., Calgary, AB (Canada)

    2000-06-01

    Cold heavy oil production (CHOP) has been used successfully in several Canadian heavy oil fields. It is a method of producing heavy oil from unconsolidated sandstones by encouraging sand influx. This study was undertaken to make an attempt at assessing the efficiency of various workover techniques in different circumstances. The workover methods that use large physical disruptions to the wellbore region and the surrounding reservoir seem to be the most successful in re-establishing production, but this takes up a significant part of operating costs. The best plan is to use a staged approach using cost-benefit estimates based on behavioural history of each well. This requires comprehensive well reviews and data. It was concluded that each unique case requires different cost analysis and options. It was suggested that a rational risk-and-return-based approach should be used. Flow charts were included to outline some of the decision-making paths and activities that should be considered in any CHOP well working program. 18 refs., 5 tabs., 3 figs.

  15. Diesel-soluble lignin oils and methods of their production

    DEFF Research Database (Denmark)

    2016-01-01

    Solvent consumption in supercritical ethanol, propanol or butanol treatment of either refined pre-extracted lignin or comparatively impure lignin-rich solid residual from hydrothermally pretreated lignocellulosic biomass can be minimized by conducting the reaction at very high loading of lignin...... to solvent. Comparatively impure, crude lignin- rich solid residual can be directly converted by supercritical alcohol treatment to significantly diesel-soluble lignin oil without requirement for pre-extraction or pre- solubilisation of lignin or for added reaction promoters such as catalysts, hydrogen donor...... co-solvents, acids, based or H2 gas. O:C ratio of product oil can readily be obtained using crude lignin residual in such a process at levels 0.20 or lower....

  16. Production of Biodiesel from Shea Butter Oil using Homogeneous Catalysts

    Directory of Open Access Journals (Sweden)

    Jude EJEH

    2014-02-01

    Full Text Available An investigation into the production of biodiesel from shea butter oil using homogenous catalyst was carried out. The properties of the oil obtained were first determined, having an FFA value of 2.279 amongst other properties. Thus, the direct base-catalysis method was used, with potassium hydroxide as the catalyst. In a 1 hour batch run, biodiesel was produced with a conversion of 92%, FAME content of 97.1%, cetane number of 46.84 and kinematic viscosity of 4.30mm2/s, conforming to ASTM D6751 and EN 14214 international standards. As such, it was established that shea butter biodiesel could be produced by the direct base catalysis, over a shorter time with low cost chemicals.

  17. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    Energy Technology Data Exchange (ETDEWEB)

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. It was hoped that the successful application of these technologies would result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs.

  18. Halogens in oil and gas production-associated wastewater.

    Science.gov (United States)

    Harkness, J.; Warner, N. R.; Dwyer, G. S.; Mitch, W.; Vengosh, A.

    2014-12-01

    Elevated chloride and bromide in oil and gas wastewaters that are released to the environment are one of the major environmental risks in areas impacted by shale gas development [Olmstead et al.,2013]. In addition to direct contamination of streams, the potential for formation of highly toxic disinfection by-products (DBPs) in drinking water in utilities located downstream from disposal sites poses a serious risk to human health. Here we report on the occurrence of iodide in oil and gas wastewater. We conducted systematic measurements of chloride, bromide, and iodide in (1) produced waters from conventional oil and gas wells from the Appalachian Basin; (2) hydraulic fracturing flowback fluids from unconventional Marcellus and Fayetteville shale gas, (3) effluents from a shale gas spill site in West Virginia; (4) effluents of oil and gas wastewater disposed to surface water from three brine treatment facilities in western Pennsylvania; and (5) surface waters downstream from the brine treatment facilities. Iodide concentration was measured by isotope dilution-inductively coupled plasma-mass spectrometry, which allowed for a more accurate measurement of iodide in a salt-rich matrix. Iodide in both conventional and unconventional oil and gas produced and flowback waters varied from 1 mg/L to 55 mg/L, with no systematic enrichment in hydraulic fracturing fluids. The similarity in iodide content between the unconventional Marcellus flowback waters and the conventional Appalachian produced waters clearly indicate that the hydraulic fracturing process does not induce additional iodide and the iodide content is related to natural variations in the host formations. Our data show that effluents from the brine treatment facilities have elevated iodide (mean = 20.9±1 mg/L) compared to local surface waters (0.03± 0.1 mg/L). These results indicate that iodide, in addition to chloride and bromide in wastewater from oil and gas production, poses an additional risk to downstream

  19. Review of Well Operator Files for Hydraulically Fractured Oil and Gas Production Wells: Hydraulic Fracturing Operations

    Science.gov (United States)

    EPA conducted a survey of oil and gas production wells hydraulically fractured by nine oil and gas service companies in the United States during 2009 and 2010. This is the second well file review report.

  20. Contaminants, toxicity and wildlife mortality at oil production sites in western South Dakota

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Chemicals at oil production sites can be hazardous to migratory birds and other wildlife. Oil, grease, and other chemical wastes related to well drilling are...

  1. Effect of the available soil water and organic matter on the castor bean foliar area growth; Influencia da agua disponivel e materia organica no crescimento da area foliar da mamoneira

    Energy Technology Data Exchange (ETDEWEB)

    Lacerda, Rogerio D. de; Almeida, Larissa C.; Guerra, Hugo O. Carvalho; Souza, Cristiana M. de; Batista, Faed R. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)], Emails: rogerio_dl@yahoo.com.br, laris_almeida@yahoo.com.br, hugo_carvallo@hotmail.com, crismsouza@hotmail.com, faedrideiro@hotmail.com

    2010-07-01

    The Brazilian potential for bio fuel production through the cultivation of oil seeds is immeasurable. On the Northeast is possible to cultivate the castor bean, peanuts, sesame, babassu and other species. Just for the castor bean there exist 3.0 millions of hectares able for cultivation. The experiment had as objective to study the effect of available soil water for plants and organic matter on the foliar area production. It was conducted on the field during the period of October 2008 to March 2009 using an experimental design 2 x 4 factorial on a randomized-complete block design, constituted of two soil organic matter contents (5.0 g.kg{sup -1} and 25.0 g.kg{sup -1}) and four soil water contents (100, 90, 80 and 70% of the soil available water for the plants) with 3 replicates. On each 100 m{sup 2} parcel 50 plants were cultivated until 180 days after the sowing, DAS. The analyses of variance allowed to observe that the addition of organic matter increased the foliar areas in 20,7% and the available water produced an increment of 51,5% when were elevated from 70 to 100%. (author)

  2. Distillation Parameters for Pilot Plant Production of Laurus nobilis Essential oil

    OpenAIRE

    Temel Özek

    2012-01-01

    Essential oils have increasing importance in flavour and fragrance industries. They are obtained by distillation techniques. In order to produce an oil with market potential its optimum production parameters have to be well known prior to its commercial production. Determination of the steam distillation parameters of commercially available Laurel leaves oil in pilot plant scale is described. The effect of steam rate and processing time play a major role in distillation of essential oils. Dis...

  3. Collective action in a smallholder oil palm production system in Indonesia: The key to sustainable and inclusive smallholder palm oil?

    NARCIS (Netherlands)

    Jelsma, Idsert; Slingerland, Maja; Giller, Ken E.; Bijman, Jos

    2017-01-01

    Indonesian smallholder oil palm generally yield much less than corporate plantations. We analysed a smallholder oil palm production system in West Sumatra which outperformed its nucleus estate plantation, consistently producing yields far above the national average for over 25 years. Its

  4. Thermal Oxidation of Tail Gases from the Production of Oil-furnace Carbon Black

    OpenAIRE

    Bosak, Z.; Barta, D.; Zečević, N.; S. Šiklušić

    2009-01-01

    This paper describes the production technology of oil-furnace carbon black, as well as the selected solution for preventing the emissions of this process from contaminating the environment.The products of industrial oil-furnace carbon black production are different grades of carbon black and process tail gases. The qualitative composition of these tail gases during the production of oil-furnace carbon black are: carbon(IV) oxide, carbon(II) oxide, hydrogen, methane, hydrogen sulfide, nitrogen...

  5. Raceways-based production of algal crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Chisti, Yusuf [Massey Univ., Palmerston North (New Zealand). School of Engineering

    2013-11-01

    Raceway ponds, or 'high-rate algal ponds', of various configurations have been used to treat wastewater since the 1950s. They are also known as Oswald ponds after their inventor W. J. Oswald. Large-scale outdoor culture of microalgae and cyanobacteria in raceways is well established (Terry and Raymond 1985; Oswald 1988; Borowitzka and Borowitzka 1989; Becker 1994; Lee 1997; Molina Grima 1999; Pulz 2001; Borowitzka 2005; Spolaore et al. 2006). Raceway culture is used commercially in the United States, Thailand, China, Israel and elsewhere, mostly to produce algae for relatively high-value applications. This chapter is focused on raceways typically used in the production of algal biomass and not in the treatment of wastewater. The engineering design, operation and performance characteristics of raceways are discussed. The biomass productivity of the raceways is assessed in relation to limits imposed by algal biology. The economics of algal oil production in raceways are discussed. (orig.)

  6. SENSITIVITY OF MOLDS ISOLATED FROM WAREHOUSES OF FOOD PRODUCTION FACILITY ON SELECTED ESSENTIAL OILS

    Directory of Open Access Journals (Sweden)

    Łukasz Kręcidło

    2015-07-01

    Full Text Available Storage of raw materials is one of steps in food production chain. The aim of this study was to estimate the influence of selected essential oils on the growth of four fungal strains: Trichoderma viride, Rhizomucor miehei, Penicillium chrysogenum, Penicillium janthinellum. Strains were isolated from warehouses of the food production facility. Selected essential oils: thyme oil, rosewood oil and rosemary oil were used to assess antifungal activity. Chemical composition of essential oils was determined by Gas Chromatography-Mass Spectroscopy (GC-MS. Antifungal activity of essential oils was estimated in relative to peracetic acid (PAA and sterile water with Tween 80 (0,5%. The influence of essential oils on fungal growth was carried by medium poisoning method. Increment of fungal mycelium was measured every day by 10 days. The thyme essential oils totally inhibited fungal growth in the lowest concentration of 1 mm3·cm-3. The most resistant strain was Penicillium janthinellum.

  7. Noncatalytic biodiesel fuel production from croton megalocarpus oil

    Energy Technology Data Exchange (ETDEWEB)

    Kafuku, G.; Mbarawa, M. [Department of Mechanical Engineering, Tshwane University of Technology, Pretoria (South Africa); Tan, K.T.; Lee, K.T. [School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, Seri Ampangan, Nibong Tebal, Pulau Pinang (Malaysia)

    2011-11-15

    Biodiesel is currently considered as the most promising substitute for diesel fuel because of its similar properties to diesel. This study presents the use of the supercritical methanol method in the production of biodiesel from Croton megalocarpus oil. The reaction parameters such as methanol-to-oil ratio, reaction temperature and reaction time were varied to obtain the optimal reaction conditions by design of experiment, specifically, response surface methodology based on three-variable central composite design with {alpha}=2. It has been shown that it is possible to achieve methyl ester yields as high as 74.91 % with reaction conditions such as 50:1 methanol-to-oil molar ratio, 330 C reaction temperature and a reaction period of 20 min. However, Croton-based biodiesel did not sustain higher temperatures due to decomposition of polyunsaturated methyl linoleate, which is dominant in biodiesel. Lower yields were observed when higher temperatures were used during the optimization process. The supercritical methanol method showed competitive biodiesel yields when compared with catalytic methods. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. Morphology and viability of castor bean genotypes pollen grains

    Directory of Open Access Journals (Sweden)

    Maria Selma Alves Silva Diamantino

    2016-01-01

    Full Text Available The objective of this work was to characterize the morphology and viability of the pollen of 15 genotypes of castor bean (Ricinus communis L. and to generate information that can assist in the selection of highly promising male parents for future use in genetic improvement programs aimed at producing seeds for oil extraction. Acetolysis and scanning electron microscopy was used to characterize the morphology of the pollen. The viability of the pollen grains was estimated by in vitro germination and colorimetric analysis (acetocarmine 2% and 2, 3, 5-triphenyltetrazolium chloride 1%. For the in vitro germination, pollen grains were grown in 10 types of solidified culture medium consisting of different concentrations of sucrose, boric acid, calcium nitrate, magnesium sulfate and potassium nitrate. The pollen grains had the following characteristics: medium size, isopolar and subspheroidal shape, radial symmetry, circular ambit, 3-colporate, elongated endoapertures, tectate exine and granulated sexine. The acetocarmine dye overestimated pollen viability. The media M5 and M8 were the most efficient at promoting the germination of pollen grains. The studied genotypes had high levels of viability and can therefore be used as male parents in genetic improvement programs.

  9. Natural Oil Production from Microorganisms: Bioprocess and Microbe Engineering for Total Carbon Utilization in Biofuel Production

    Energy Technology Data Exchange (ETDEWEB)

    None

    2010-07-15

    Electrofuels Project: MIT is using carbon dioxide (CO2) and hydrogen generated from electricity to produce natural oils that can be upgraded to hydrocarbon fuels. MIT has designed a 2-stage biofuel production system. In the first stage, hydrogen and CO2 are fed to a microorganism capable of converting these feedstocks to a 2-carbon compound called acetate. In the second stage, acetate is delivered to a different microorganism that can use the acetate to grow and produce oil. The oil can be removed from the reactor tank and chemically converted to various hydrocarbons. The electricity for the process could be supplied from novel means currently in development, or more proven methods such as the combustion of municipal waste, which would also generate the required CO2 and enhance the overall efficiency of MIT’s biofuel-production system.

  10. Vegetable oil based liquid nanocomposite dielectric

    Directory of Open Access Journals (Sweden)

    Leon Chetty

    2013-01-01

    Full Text Available Physically smaller dielectric materials would improve the optimisation of space for power systems. Development of nanotechnology provides an effective way to improve the performances of insulating oils used in power system applications. In this research study, we focused on the development of nanomodified vegetable oils to be used in power transformers. Higher conduction currents were observed in virgin linseed oil than in virgin castor oil. However, for both virgin linseed and virgin castor oil, the DC conduction current increased approximately linearly with the applied DC voltage. In nanomodified linseed oil, the characteristic curve showed two distinct regions: a linear region (at lower applied voltage and a saturation region (at slightly higher voltage. Conversely, in nanomodified castor oil, the characteristic curve showed three distinct regions: a linear region (at lower applied voltage, a saturation region (at intermediate applied voltage and an exponential growth region (at higher applied voltage. The nanomodified linseed oil exhibited a better dielectric performance than the nanomodified castor oil. Overall, the addition of nanodielectrics to vegetable oils decreased the dielectric performance of the vegetable oils. The results of this study contribute to the understanding of the pre-breakdown phenomenon in liquid nanocomposite dielectrics.

  11. 1985 oil production of 21 oil producing non-OPEC countries

    Energy Technology Data Exchange (ETDEWEB)

    Warner, A.J.

    1979-03-01

    This report assesses the possibility of increased oil production from 21 less developed non-OPEC countries (excluding the Middle East and Mexico) by 1985. The forecast is compared with those prepared by the World Bank, the International Energy Agency, and others. The 21 Latin American, African, and Far East (including Asia) countries produce 2.5 million barrels of oil per day (BD) or 4.2% of world production, and they have 21 billion barrels of proved reserves, or 3.2% of the world total. In recent years these countries have consumed 3.1 million BD, some 0.9 million barrels in excess of their production. By 1985, the 21 countries may produce 3.9 million BD, an average annual increase of 5.0%; however, demand is expected to increase at an annual rate of 3.5% to 4.4 million BD. The net effect is that the 1985 aggregated supply-demand balance will be in deficit, by nearly 560 thousand BD, compared to slightly more than 930 thousand BD in 1976.

  12. World oil production. [Demand to overshadow supplies before year 2000

    Energy Technology Data Exchange (ETDEWEB)

    Flower, A.R.

    1978-03-01

    The supply of oil will fail to meet increasing demand before the year 2000. As oil production inevitably levels off and then falls, alternative fuels will have to meet the demand for energy, which will continue to grow in the face of even vigorous attempts at conservation. The oil-importing countries have perhaps as few as five years or perhaps as many as 20 in which to accomplish a transition from dependence on oil to greater reliance on other fossil fuels, on nuclear energy and eventually on renewable energy sources. Because large investments and long lead times are required for developing new energy resources the effort must begin immediately. These are among the major conclusions of a two-year international study, the Workshop on Alternative Energy Strategies. The workshop participants came from the U.S., Canada, Mexico, Venezuela, the United Kingdom, France, West Germany, the Netherlands, Denmark, Sweden, Norway, Finland, Italy, Iran, and Japan. The workshop developed projections of energy supply and demand under various assumptions, notably concerning economic growth and the price of energy. Two basic scenarios were formulated, one assuming a high economic growth rate and high energy prices and the other a low growth rate and constant prices. The high-growth, high-price scenario assumed that economic growth in the non-Communist world would average 5.2% per year between 1976 and 1985 and 4% between 1985 and 2000, and that energy prices would remain constant (in real terms) until 1985 and increase 50% by 2000. The low-growth, constant-price scenario assumed that economic growth would average 3.4% per year until 1985 and then 2.8% until 2000, and that real energy prices would remain constant during the entire period. Within that framework energy-demand forecasts were prepared for the various regions for each fuel and were aggregated to project the total energy demand in 1985 and 2000.

  13. Production of higher quality bio-oils by in-line esterification of pyrolysis vapor

    Science.gov (United States)

    Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

    2014-12-02

    The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

  14. State-of-the-art on ultrasonic oil production technique for EOR in China.

    Science.gov (United States)

    Wang, Zhenjun; Yin, Congbo

    2017-09-01

    Ultrasonic oil production technique for enhanced oil recovery (EOR) attracts more attention due to its high adaptability, simple operation, low cost and zero pollution to the oil reservoir. In this paper, recent new downhole tools used for enhanced oil recovery developed in China are summarized. Furthermore, research advance on some key problems that affect the widespread application of ultrasonic oil production technique in China are also summarized in view of what are the primary factors that influence crude oil paraffin inhibition and viscosity reduction, whether ultrasonic excitation is better than chemical agent for any plugs removal and whether ultrasound-chemical combination plug removal technology has the best plugs removal effect. The purpose of this paper is to provide reference for the broad application of ultrasonic oil production for enhance oil recovery. Copyright © 2017 Elsevier B.V. All rights reserved.

  15. Reprint of: State-of-the-art on ultrasonic oil production technique for EOR in China.

    Science.gov (United States)

    Wang, Zhenjun; Yin, Congbo

    2018-01-01

    Ultrasonic oil production technique for enhanced oil recovery (EOR) attracts more attention due to its high adaptability, simple operation, low cost and zero pollution to the oil reservoir. In this paper, recent new downhole tools used for enhanced oil recovery developed in China are summarized. Furthermore, research advance on some key problems that affect the widespread application of ultrasonic oil production technique in China are also summarized in view of what are the primary factors that influence crude oil paraffin inhibition and viscosity reduction, whether ultrasonic excitation is better than chemical agent for any plugs removal and whether ultrasound-chemical combination plug removal technology has the best plugs removal effect. The purpose of this paper is to provide reference for the broad application of ultrasonic oil production for enhance oil recovery. Copyright © 2017. Published by Elsevier B.V.

  16. Productions of sunflower oil biodiesel and used cooking oil through heterogeneous catalysts compared to conventional homogeneous catalysts

    Science.gov (United States)

    Gutiérrez-Zapata, C. A.; Blanco Martínez, D.; Collazos, C. A.; Castellanos Acuña, H. E.; Cuervo, J. A.; Fernandez, C. P.

    2017-01-01

    This document compares homogeneous and heterogeneous catalysts used by production of biodiesel of sunflower oil and cooking oil used in frying. For this, NaOH was used as a catalyst homogeneous, and K2CO3 and Na2CO3 supported in gamma-alumina (K2CO3/γ Al2O3 y Na2CO3 /γ-Al2O3) were synthesized as heterogeneous catalysts, which were characterized by X-ray diffraction. The transesterification tests were carried out for the sunflower oil and used cooking oil, in a reflux system, to different molar relations methanol/oil, depending on the type of oil and characterization of the same. The reflux system is performed at a temperature of 55-60°C for one hour. Finally, biofuel was characterized and the yield of the reaction was calculated.

  17. PRODUCTION OF PALM OIL WITH METHANE AVOIDANCE AT PALM OIL MILL: A CASE STUDY OF CRADLE-TO-GATE LIFE CYCLE ASSESSMENT

    OpenAIRE

    Chiew Wei Puah; Yuen May Choo; Soon Hock Ong

    2013-01-01

    The study discusses a case study of cradle to gate life cycle assessment for the production of Crude Palm Oil (CPO) with methane avoidance at palm oil mill. The improved milling process enables total utilization of the oil palm fruit to produce alow oil palm based food source. The minimal modification in the mill includes cleaning of Fresh Fruit Bunches (FFB) and obtaining the low oil food source from the aqueous stream. The oil palm fruit processing plant enables the significant reduction of...

  18. Life cycle assessment of a palm oil system with simultaneous production of biodiesel and cooking oil in Cameroon.

    Science.gov (United States)

    Achten, Wouter M J; Vandenbempt, Pieter; Almeida, Joana; Mathijs, Erik; Muys, Bart

    2010-06-15

    The use of palm oil as a biofuel has been heavily debated for its land-use conflict with nature and its competition with food production, being the number one cooking oil worldwide. In that context, we present a life cycle assessment of a palm oil production process yielding both biodiesel and cooking oil, incorporating the land-use impact and evaluating the effect of treating the palm oil mill effluent (POME) prior to disposal. The results show that the nonrenewable energy requirement, global warming potential (GWP; exclusive land-use change), and acidification potential are lower than those of the fossil alternative. However, the system triggers an increase in eutrophication potential (EP) compared to the fossil fuel reference. This system shows less energy requirement, global warming and acidification reduction, and less eutrophication increase compared to the reference than the same system converting all palm oil into biodiesel (no cooking oil production). The land occupation of palm oil triggers ecosystem quality (EQ) loss of 30-45% compared to the potential natural vegetation. Furthermore, such land-use change triggers a carbon debt neutralizing the GWP reduction for 45-53 years. The POME treatment scenarios reveal a trade-off between GWP and EP.

  19. Gamma-linolenic acid egg production enriched with hemp seed oil and evening primrose oil in diet of laying hens.

    Science.gov (United States)

    Park, Sang-Oh; Hwangbo, Jong; Yuh, In-Suh; Park, Byung-Sung

    2014-07-01

    This study was carried out to find out the effect of supplying gamma linolenic acid (GLA) on laying performance and egg quality. A hundred twenty of 30 weeks old hyline brown laying hens with 98% of egg production were completely randomized to 4 different treatment groups by 30 hens (the control group fed with the diet containing beef tallow, 3 treatment groups fed with the diet containing corn oil, the diet containing hemp seed oil and the diet containing evening primrose oil, respectively), and their laying performance and egg production were investigated for 5 weeks. Intake of hemp seed oil or evening primrose helped to increase the retention rate of GLA, which was transmigrated into eggs from blood. GLA was not detected in the blood samples of control group and treatment group fed diet containing corn oil, while it was significantly increased in the blood samples of the treatment groups fed with diet containing hemp seed oil and diet containing evening primrose oil, respectively. GLA retention was not observed in the eggs produced respectively by control group and treatment group fed with diet containing corn oil, whereas it was significantly increased in the eggs produced by the treatment group fed with diet containing hemp seed oil by 1.09% and the treatment group fed with diet containing evening primrose oil by 4.87%. This result suggests that GLA-reinforced functional eggs can be produced by adding hemp seed oil and evening primrose oil to the feed for laying hens and feeding them with it. It is thought that further researches and clinical trials on biochemical mechanism related to atopic dermatitis should be conducted in future.

  20. Gradient-based methods for production optimization of oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Suwartadi, Eka

    2012-07-01

    Production optimization for water flooding in the secondary phase of oil recovery is the main topic in this thesis. The emphasis has been on numerical optimization algorithms, tested on case examples using simple hypothetical oil reservoirs. Gradientbased optimization, which utilizes adjoint-based gradient computation, is used to solve the optimization problems. The first contribution of this thesis is to address output constraint problems. These kinds of constraints are natural in production optimization. Limiting total water production and water cut at producer wells are examples of such constraints. To maintain the feasibility of an optimization solution, a Lagrangian barrier method is proposed to handle the output constraints. This method incorporates the output constraints into the objective function, thus avoiding additional computations for the constraints gradient (Jacobian) which may be detrimental to the efficiency of the adjoint method. The second contribution is the study of the use of second-order adjoint-gradient information for production optimization. In order to speedup convergence rate in the optimization, one usually uses quasi-Newton approaches such as BFGS and SR1 methods. These methods compute an approximation of the inverse of the Hessian matrix given the first-order gradient from the adjoint method. The methods may not give significant speedup if the Hessian is ill-conditioned. We have developed and implemented the Hessian matrix computation using the adjoint method. Due to high computational cost of the Newton method itself, we instead compute the Hessian-timesvector product which is used in a conjugate gradient algorithm. Finally, the last contribution of this thesis is on surrogate optimization for water flooding in the presence of the output constraints. Two kinds of model order reduction techniques are applied to build surrogate models. These are proper orthogonal decomposition (POD) and the discrete empirical interpolation method (DEIM

  1. Effect of orange peel oil on ethanol production by Zymomonas mobilis

    Energy Technology Data Exchange (ETDEWEB)

    Wilkins, Mark R. [Department of Biosystems and Agricultural Engineering, 111 Agricultural Hall, Oklahoma State University, Stillwater, OK 74078 (United States)

    2009-03-15

    The effect of orange peel oil on ethanol production by the ethanologenic bacterium Zymomonas mobilis was investigated. Orange peel oil was added in various amounts to determine its effects on ethanol production. Fermentation of model sugar solutions was conducted at 30 and 37 C. The minimum orange peel oil concentration that inhibited ethanol production by Z. mobilis was determined after 24, 48, 72 and 96 h for both temperatures. Minimum inhibitory orange peel oil concentrations for ethanol production at 30 C were 0.05% after 24 h, 0.10% after 48 h, 0.15% after 72 h, and 0.20% after 96 h. Minimum inhibitory orange peel oil concentrations for ethanol production at 37 C were 0.05% after 24 h, 0.10% after 48 h, and 0.20% after 72 h. Orange peel oil did not inhibit ethanol production after 96 h at a temperature of 37 C. (author)

  2. Transport and transcriptional regulation of oil production in plants.

    Science.gov (United States)

    Manan, Sehrish; Chen, Beibei; She, Guangbiao; Wan, Xiaochun; Zhao, Jian

    2017-08-01

    Triacylglycerol (TAG) serves as an energy reservoir and phospholipids as build blocks of biomembrane to support plant life. They also provide human with foods and nutrients. Multi-compartmentalized biosynthesis, trafficking or cross-membrane transport of lipid intermediates or precursors and their regulatory mechanisms are not fully understood. Recent progress has aided our understanding of how fatty acids (FAs) and phospholipids are transported between the chloroplast, the cytoplasm, and the endoplasmic reticulum (ER), and how the ins and outs of lipids take place in the peroxisome and other organelles for lipid metabolism and function. In addition, information regarding the transcriptional regulation network associated with FA and TAG biosynthesis has been further enriched. Recent breakthroughs made in lipid transport and transcriptional regulation has provided significant insights into our comprehensive understanding of plant lipid biology. This review attempts to highlight the recent progress made on lipid synthesis, transport, degradation, and their regulatory mechanisms. Metabolic engineering, based on these knowledge-powered technologies for production of edible oils or biofuels, is reviewed. The biotechnological application of metabolic enzymes, transcription factors and transporters, for oil production and composition improvement, are discussed in a broad context in order to provide a fresh scenario for researchers and to guide future research and applications.

  3. Local Perceptions about the Effects of Jatropha (Jatropha curcas and Castor (Ricinus communis Plantations on Households in Ghana and Ethiopia

    Directory of Open Access Journals (Sweden)

    Joleen A. Timko

    2014-10-01

    Full Text Available Biofuel plantations have been hyped as a means to reinvigorate Africa’s rural areas. Yet there is still apprehension about the negative environmental and social impacts of large-scale commercial biofuel production around rising food prices, land grabbing, ecological damage, and disruption of rural livelihoods. Given the extent of Jatropha curcas production in Ghana and Ethiopia and Castor bean (Ricinus communis in Ethiopia, this paper presents the results of a study that assessed the socio-economic implications of industrial Jatropha plantations on local livelihoods in Ghana, and of industrial Jatropha and Castor plantations on local livelihoods in Ethiopia. This study used primary data collected from 234 households in Ghana and 165 in Ethiopia. The cultivation of Jatropha and Castor has had several important effects on local livelihoods in the study sites, most notably decreases in household landholdings due to the arrival of industrial Jatropha or Castor plantations; and the resulting changes these plantations have caused in household socio-economic status, food security, fallow periods, and fodder availability. We consider how a lack of meaningful consultation between local people, their traditional authorities and the biofuel company managers, along with shortcomings in each country’s broader land acquisition process and poor land use information, may have contributed to these overall negative effects on local livelihoods. We conclude by suggesting several ways that emerging biofuel industries could be improved from the perspective of local people and their livelihoods.

  4. EARLY DEVELOPMENT OF CASTOR BEANS GROWN UNDER SALINITY CONDITIONS (VARIETIES BRS ENERGIA, MPA 34 AND MPB 01

    Directory of Open Access Journals (Sweden)

    RAFAEL ANTÔNIO PRESOTTO

    2016-01-01

    Full Text Available Studies have shown that some plant species exhibit satisfactory production levels when grown under high salinity levels, whereas others exhibit decreased production due to sodium sensitivity even at low sodium concentrations. The castor bean is moderately sensitive to salinity. The aim of the present study was to evaluate the early growth of three castor bean varieties (BRS Energia, MPA 34 and MPB 01 grown in nutrient solution with increasing sodium concentrations (control, 25, 50, 75 and 100 mmol L - 1 . A completely randomized split - plot experimental design was used, with a 5x3 factorial scheme and three replicates per treatment. Salinity resulted in decreased dry weight of all castor bean varieties grown for 31 days under hydroponic conditions. The dry weight accumulation was less affected at the root than at the shoot level. Nevertheless, the shoot dry weight decreased with the increasing salinity. MPA 34 exhibited higher early growth than the remaining tested varieties. Salinity affected the early development of the tested castor bean varieties, and this effect was more pronounced at the shoot than at the root. Variety MPA 34 is promising for cultivation under moderate salinity levels.

  5. Effects of Crude Oil and Oil Products on Growth of Some Edible ...

    African Journals Online (AJOL)

    The vegetative growth response of three local edible mushrooms: Pleurotus pulmonarius (Pp), Pleurotus tuber-regium (Pt) and Lentinus squarrosulus (Ls) on different concentrations of Crude oil (COIL), Automotive Gasoline Oil (AGO), Fresh Engine Oil (ENGOIL) and Spent Engine Oil (SENGOIL) was investigated. The result ...

  6. The Response of Industrial Production to the Price of Oil: New Evidence for Thailand

    OpenAIRE

    Jiranyakul, Komain

    2017-01-01

    Abstract. This paper examines the oil price-industrial production nexus in Thailand by using multivariate cointegration test. In addition, Granger causality is also used to examine the impact of oil price uncertainty on industrial production growth. The main focus of this paper is on one sector of the economy, i.e., manufacturing sector. Monthly data from 1993 to 2015 are utilized. Empirical results reveal that there is a long-run relationship between industrial production and real oil price ...

  7. Non-Edible Plant Oils as New Sources for Biodiesel Production

    Directory of Open Access Journals (Sweden)

    M. Rafiqul Islam

    2008-02-01

    Full Text Available Due to the concern on the availability of recoverable fossil fuel reserves and the environmental problems caused by the use those fossil fuels, considerable attention has been given to biodiesel production as an alternative to petrodiesel. However, as the biodiesel is produced from vegetable oils and animal fats, there are concerns that biodiesel feedstock may compete with food supply in the long-term. Hence, the recent focus is to find oil bearing plants that produce non-edible oils as the feedstock for biodiesel production. In this paper, two plant species, soapnut (Sapindus mukorossi and jatropha (jatropha curcas, L. are discussed as newer sources of oil for biodiesel production. Experimental analysis showed that both oils have great potential to be used as feedstock for biodiesel production. Fatty acid methyl ester (FAME from cold pressed soapnut seed oil was envisaged as biodiesel source for the first time. Soapnut oil was found to have average of 9.1% free FA, 84.43% triglycerides, 4.88% sterol and 1.59% others. Jatropha oil contains approximately 14% free FA, approximately 5% higher than soapnut oil. Soapnut oil biodiesel contains approximately 85% unsaturated FA while jatropha oil biodiesel was found to have approximately 80% unsaturated FA. Oleic acid was found to be the dominant FA in both soapnut and jatropha biodiesel. Over 97% conversion to FAME was achieved for both soapnut and jatropha oil.

  8. Non-Edible Plant Oils as New Sources for Biodiesel Production

    Science.gov (United States)

    Chhetri, Arjun B.; Tango, Martin S.; Budge, Suzanne M.; Watts, K. Chris; Islam, M. Rafiqul

    2008-01-01

    Due to the concern on the availability of recoverable fossil fuel reserves and the environmental problems caused by the use those fossil fuels, considerable attention has been given to biodiesel production as an alternative to petrodiesel. However, as the biodiesel is produced from vegetable oils and animal fats, there are concerns that biodiesel feedstock may compete with food supply in the long-term. Hence, the recent focus is to find oil bearing plants that produce non-edible oils as the feedstock for biodiesel production. In this paper, two plant species, soapnut (Sapindus mukorossi) and jatropha (jatropha curcas, L.) are discussed as newer sources of oil for biodiesel production. Experimental analysis showed that both oils have great potential to be used as feedstock for biodiesel production. Fatty acid methyl ester (FAME) from cold pressed soapnut seed oil was envisaged as biodiesel source for the first time. Soapnut oil was found to have average of 9.1% free FA, 84.43% triglycerides, 4.88% sterol and 1.59% others. Jatropha oil contains approximately 14% free FA, approximately 5% higher than soapnut oil. Soapnut oil biodiesel contains approximately 85% unsaturated FA while jatropha oil biodiesel was found to have approximately 80% unsaturated FA. Oleic acid was found to be the dominant FA in both soapnut and jatropha biodiesel. Over 97% conversion to FAME was achieved for both soapnut and jatropha oil. PMID:19325741

  9. Options to reduce environmental impacts of palm oil production in Thailand

    NARCIS (Netherlands)

    Saswattecha, Kanokwan; Kroeze, Carolien; Jawjit, Warit; Hein, Lars

    2016-01-01

    There is an increasing demand for palm oil worldwide. In Thailand, oil palm is being promoted by the government but this expansion is associated with several environmental impacts. We identified 26 options for reducing the environmental impact of palm oil production in Thailand, and assessed their

  10. Suitability of conophor oil for the production of aklyd resins, and ...

    African Journals Online (AJOL)

    Oil was extracted from Tetracaripidum conophorum nut (conophor plant) using solvent extraction method, with hexane as solvent. The oil obtained was used to synthesize an alkyd resin, which in turn was utilized in the production of white gloss paints and vanishes. The IR and UV analysis of the oil showed the presence of ...

  11. Biodiesel Production from Chlorella protothecoides Oil by Microwave-Assisted Transesterification.

    Science.gov (United States)

    Gülyurt, Mustafa Ömer; Özçimen, Didem; İnan, Benan

    2016-04-22

    In this study, biodiesel production from microalgal oil by microwave-assisted transesterification was carried out to investigate its efficiency. Transesterification reactions were performed by using Chlorella protothecoides oil as feedstock, methanol, and potassium hydroxide as the catalyst. Methanol:oil ratio, reaction time and catalyst:oil ratio were investigated as process parameters affected methyl ester yield. 9:1 methanol/oil molar ratio, 1.5% KOH catalyst/oil ratio and 10 min were optimum values for the highest fatty acid methyl ester yield.

  12. Biodiesel Production from Chlorella protothecoides Oil by Microwave-Assisted Transesterification

    Directory of Open Access Journals (Sweden)

    Mustafa Ömer Gülyurt

    2016-04-01

    Full Text Available In this study, biodiesel production from microalgal oil by microwave-assisted transesterification was carried out to investigate its efficiency. Transesterification reactions were performed by using Chlorella protothecoides oil as feedstock, methanol, and potassium hydroxide as the catalyst. Methanol:oil ratio, reaction time and catalyst:oil ratio were investigated as process parameters affected methyl ester yield. 9:1 methanol/oil molar ratio, 1.5% KOH catalyst/oil ratio and 10 min were optimum values for the highest fatty acid methyl ester yield.

  13. Oxidative Stability and Sensory Attributes of Fermented Milk Product Fortified with Fish Oil and Marine Phospholipids

    DEFF Research Database (Denmark)

    Lu, Henna Fung Sieng; Thomsen, Birgitte Raagaard; Hyldig, Grethe

    2013-01-01

    product fortified with fish oil alone. Fortification of a fermented milk product with marine PL was performed by incorporating 1 % w/w lipids, either in the form of neat oil or in the form of a pre-emulsion. Lipid oxidation was investigated in the neat emulsions and fortified products by the measurements...

  14. 76 FR 67201 - Information Collection Activities: Oil and Gas Production Safety Systems; Submitted for Office of...

    Science.gov (United States)

    2011-10-31

    ... Production Safety Systems; Submitted for Office of Management and Budget (OMB) Review; Comment Request ACTION... the paperwork requirements in the regulations under Subpart H, ``Oil and Gas Production Safety Systems... H, Oil and Gas Production Safety Systems. Abstract: The Outer Continental Shelf (OCS) Lands Act, as...

  15. Multi-Agents in the North Sea – The Case of Oil and Gas Production

    DEFF Research Database (Denmark)

    Mikkelsen, Lars Lindegaard; Demazeau, Yves; Jørgensen, Bo Nørregaard

    2011-01-01

    Developing control systems for offshore oil and gas production is a challenging task, due to the complex inherent issues of the domain, i.e. changing properties of the oil and gas reservoirs, and variations in production configuration, due to new wells and production technologies. In this paper, we...

  16. Production of free fatty acids from waste oil by application of ultrasound

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Larissa P.; Santos, Francisco F.P.; Costa, Enio; Fernandes, Fabiano A.N. [Universidade Federal do Ceara, Departamento de Engenharia Quimica, Fortaleza, CE (Brazil)

    2012-12-15

    This paper evaluates the production of free fatty acids (FFAs) from waste oil by means of low-frequency high-intensity ultrasound application under atmospheric pressure. To evaluate the potential of this technology, the reaction between waste palm oil and ethanol was carried out. Response surface methodology (RSM) was used to evaluate the influence of alcohol-to-oil weight ratio, potassium hydroxide-to-oil weight ratio, and temperature on the yield of waste oil into FFA. Analysis of the operating conditions by RSM showed that the most important operating conditions affecting the reaction were ethanol-to-oil weight ratio and potassium hydroxide-to-oil weight ratio. The highest yield observed was of 97.3 % after 45 min of reaction. The best operating condition was obtained by applying an ethanol-to-oil weight ratio of 2.4, a potassium hydroxide-to-oil weight ratio of 0.3, and temperature of 60 C. (orig.)

  17. Results of the International Energy Agency Round Robin on Fast Pyrolysis Bio-oil Production

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.; Meier, Dietrich; Oasmaa, Anja; van de Beld, Bert; Bridgwater, Anthony V.; Marklund, Magnus

    2017-04-06

    An international round robin study of the production of fast pyrolysis bio-oil was undertaken. Fifteen institutions in six countries contributed. Three biomass samples were distributed to the laboratories for processing in fast pyrolysis reactors. Samples of the bio-oil produced were transported to a central analytical laboratory for analysis. The round robin was focused on validating the pyrolysis community understanding of production of fast pyrolysis bio-oil by providing a common feedstock for bio-oil preparation. The round robin included: •distribution of 3 feedstock samples from a common source to each participating laboratory; •preparation of fast pyrolysis bio-oil in each laboratory with the 3 feedstocks provided; •return of the 3 bio-oil products (minimum 500 ml) with operational description to a central analytical laboratory for bio-oil property determination. The analyses of interest were: density, viscosity, dissolved water, filterable solids, CHN, S, trace element analysis, ash, total acid number, pyrolytic lignin, and accelerated aging of bio-oil. In addition, an effort was made to compare the bio-oil components to the products of analytical pyrolysis through GC/MS analysis. The results showed that clear differences can occur in fast pyrolysis bio-oil properties by applying different reactor technologies or configurations. The comparison to analytical pyrolysis method suggested that Py-GC/MS could serve as a rapid screening method for bio-oil composition when produced in fluid-bed reactors. Furthermore, hot vapor filtration generally resulted in the most favorable bio-oil product, with respect to water, solids, viscosity, and total acid number. These results can be helpful in understanding the variation in bio-oil production methods and their effects on bio-oil product composition.

  18. Short-chain chlorinated paraffins in cooking oil and related products from China.

    Science.gov (United States)

    Cao, Yang; Harada, Kouji H; Liu, Wanyang; Yan, Junxia; Zhao, Can; Niisoe, Tamon; Adachi, Ayumu; Fujii, Yukiko; Nouda, Chihiro; Takasuga, Takumi; Koizumi, Akio

    2015-11-01

    Short-chain chlorinated paraffins (SCCPs) are emerging persistent organic pollutants. It has been found that dietary intakes of SCCPs in China have recently increased and are now higher than in Japan and Korea. The contribution of cooking oil to dietary exposure to SCCPs in China was evaluated by analyzing SCCPs in cooking oil, raw seeds used to produce cooking oil, and fried confectionery products collected in China in 2010 and 2012. Detectable amounts of SCCP homologs were found in 48 out of the 49 cooking oil samples analyzed, and the SCCP concentrations varied widely, from production and processing of the oil. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. Peppermint Oil Decreases the Production of Virulence-Associated Exoproteins by Staphylococcus aureus

    Directory of Open Access Journals (Sweden)

    Xu-Ming Deng

    2011-02-01

    Full Text Available The present study aimed to evaluate the antimicrobial activity of peppermint oil against Staphylococcus aureus, and further investigate the influence of peppermint oil on S. aureus virulence-related exoprotein production. The data show that peppermint oil, which contained high contents of menthone, isomenthone, neomenthol, menthol, and menthyl acetate, was active against S. aureus with minimal inhibitory concentrations (MICs ranging from 64-256 µg/mL, and the production of S. aureus exotoxins was decreased by subinhibitory concentrations of peppermint oil in a dose-dependent manner. The findings suggest that peppermint oil may potentially be used to aid in the treatment of S. aureus infections.

  20. THE DEVELOPMENT OF OIL AND GAS PRODUCTION GATHERING AND TRANSPORTATION TECHNOLOGY

    Directory of Open Access Journals (Sweden)

    Mirko Zelić

    1990-12-01

    Full Text Available The oil production was started in 1945 to cover several small capacity oil fields and to expand in the forthcoming forty-five years to the wider area of the Northern Croatia. Significant exploration efforts and enthusiasm revealed perspective hydrocarbon layers on which a complex technological infrastructure was constructed (wells, technological systems, transportation systems for the purpose of oil and gas production, its processing and transportation to refineries and consumers. In line with development of other technoligies in the world, the oil and gas production and gathering technologies in INA - Naftaplin were also up—graded, monitoring and adopting the most advanced world achievements in the field of oil and gas production. Presently applied technology ranks INA - Naftaplin among modernly organized (from the technical and technologica point of view companies, engaged in the field of oil and gas production and processing (the paper is published in Croatian.

  1. In Situ Biodiesel Production from Residual Oil Recovered from Spent Bleaching Earth

    OpenAIRE

    Ramli Mat; Ow Shin Ling; Anwar Johari; Mahadhir Mohammed

    2011-01-01

    Currently, semi-refined and refined vegetable oils are used as a feedstock in biodiesel production. However, due to competition with conventional fossil fuel, economic reasons, shortage supply of food and its social impact on the global scale has somewhat slowed the development of biodiesel industry. Studies have been conducted to recover oil from mill palm oil operation especially from the spent bleaching earth. Hence, the study was to investigate the potential recovery of oil from spent ble...

  2. Bio-oil production via subcritical hydrothermal liquefaction of biomass

    Science.gov (United States)

    Durak, Halil

    2017-04-01

    Biomass based raw materials can be converted into the more valued energy forms using biochemical methods such as ethanol fermentation, methane fermentation and the thermochemical methods such as direct combustion, pyrolysis, gasification, liquefaction. The bio-oil obtained from the biomass has many advantages than traditional use. Firstly, it has features such as high energy density, easy storage and easy transportation. Bio-oil can be used as a fuel in engines, turbines and burning units directly. Besides, it can be converted into products in higher quality and volume via catalytic cracking, hydrodexygenation, emulsification, and steam reforming [1,2]. Many organic solvents such as acetone, ethanol, methanol, isopropanol are used in the supercritical liquefaction processes. When we think about the cost and effects of the organic solvent on nature, it will be understood better that it is necessary to find solvent that are more sensitive against nature. Here, water must have an important place because of its features. Most important solvent of the world water is named as "universal solvent" because none of the liquids can dissolve the materials as much as done by water. Water is found much at the nature and cost of it is very few when compared with the other solvent. Hydrothermal liquefaction, a thermochemical conversion process is an effective method used for converting biomass into the liquid products. General reaction conditions for hydrothermal liquefaction process are the 250-374 °C temperature range and 4 - 22 Mpa pressure values range, besides, the temperature values can be higher according to the product that is expected to be obtained [3,4]. In this study, xanthium strumarium plant stems have been used as biomass source. The experiments have been carried out using a cylindrical reactor (75 mL) at the temperatures of 300 °C. The produced liquids at characterized by elemental analysis, GC-MS and FT-IR. According to the analysis, different types of compounds

  3. The implications of the declining energy return on investment of oil production.

    Science.gov (United States)

    Murphy, David J

    2014-01-13

    Declining production from conventional oil resources has initiated a global transition to unconventional oil, such as tar sands. Unconventional oil is generally harder to extract than conventional oil and is expected to have a (much) lower energy return on (energy) investment (EROI). Recently, there has been a surge in publications estimating the EROI of a number of different sources of oil, and others relating EROI to long-term economic growth, profitability and oil prices. The following points seem clear from a review of the literature: (i) the EROI of global oil production is roughly 17 and declining, while that for the USA is 11 and declining; (ii) the EROI of ultra-deep-water oil and oil sands is below 10; (iii) the relation between the EROI and the price of oil is inverse and exponential; (iv) as EROI declines below 10, a point is reached when the relation between EROI and price becomes highly nonlinear; and (v) the minimum oil price needed to increase the oil supply in the near term is at levels consistent with levels that have induced past economic recessions. From these points, I conclude that, as the EROI of the average barrel of oil declines, long-term economic growth will become harder to achieve and come at an increasingly higher financial, energetic and environmental cost.

  4. Thermoeconomic Analysis of Biodiesel Production from Used Cooking Oils

    Directory of Open Access Journals (Sweden)

    Emilio Font de Mora

    2015-05-01

    Full Text Available Biodiesel from used cooking oil (UCO is one of the most sustainable solutions to replace conventional fossil fuels in the transport sector. It can achieve greenhouse gas savings up to 88% and at the same time reducing the disposal of a polluting waste. In addition, it does not provoke potential negative impacts that conventional biofuels may eventually cause linked to the use of arable land. For this reason, most policy frameworks favor its consumption. This is the case of the EU policy that double-counters the use of residue and waste use to achieve the renewable energy target in the transport sector. According to different sources, biodiesel produced from UCO could replace around 1.5%–1.8% of the EU-27 diesel consumption. This paper presents an in-depth thermoeconomic analysis of the UCO biodiesel life cycle to understand its cost formation process. It calculates the ExROI value (exergy return on investment and renewability factor, and it demonstrates that thermoeconomics is a useful tool to assess life cycles of renewable energy systems. It also shows that UCO life cycle biodiesel production is more sustainable than biodiesel produced from vegetable oils.

  5. Basement rift control on oil production in eastern Kansas

    Energy Technology Data Exchange (ETDEWEB)

    Gustavson, J.B.

    1983-08-01

    Improved understanding of the central North American rift system (CNARS) offers a new interpretation of the basement structure in certain parts of the Mid-Continent. In eastern Kansas, basement structure can be shown to control oil production from some producing fields. Structural control includes rotated blocks along faults created by horst and graben tectonics typically associated with rift zones. A distinctive gravity signature, the Mid-Continent geophysical anomaly (MGA) is related directly to the CNARS and provides good data for interpretation of the basement structure. Some oil fields can be correlated directly with gravity-interpreted basement structure. Aeromagnetic and Landsat information, combined with the gravity data, further define exploration targets along the general trend of basement features. Migration of thermally matured hydrocarbons into pre-Pennsylvanian, rift generated traps in the ancestral north Kansas basin is postulated. The Nemaha ridge subsequently divided that basin into two smaller basins, the present Salina and Forest City basins. Several exploration targets could exist in this area, with the Arbuckle, Simpson, and Viola units being primary targets. The source of hydrocarbons also may lie in the deep but distant Anadorko basin. An additional totally untested hydrocarbons potential exists in the deep Precambrian/Cambrian sedimentary subbasins created along the flanks of the CNARS. Recent data points to sedimentary columns with depths of approximately 15,000 ft (4500 m) which might be hosts to gas reserves similar to the Rome trough potential of the Appalachian region.

  6. A review of nutritional and toxicological implications of castor bean (Ricinus communis L.) meal in animal feeding systems.

    Science.gov (United States)

    Akande, T O; Odunsi, A A; Akinfala, E O

    2016-04-01

    The nutrient-rich defatted castor meal has been tested as a potential source of protein in diets of many livestock species but has limitation due to challenges of toxins. This review was conducted to compile the relevant research information on advances in the use of raw and differently processed castor seed meal in animal feed. In this article, distribution and uses of castor and its products were identified. Research findings on the nutrients profile, principal toxins, various detoxification strategies, nutritional value and toxicity on common livestock species were compiled and reviewed. The defatted seed meal had crude protein range of 32-48%, gross energy of about 3200 kcal/kg. Ricin content was 9.3 mg/g seed, and the average RCA content was 9.9 mg/g. The meal had high activity of lectin, which produced agglutination at about 4.70 mg/ml minimum assays. Reports of detoxification strategies showed varying degrees of success but high pH, moist heating and microbial techniques appeared to exert greater effect on deactivating ricin. Detoxification strategy for the allergen component is inconclusive. Tannins and the phenolic contents were present at trace level and did not constitute notable threat. It was concluded that castor seed holds great potential as feedstuff when upgraded but such upgrading must be safe, cost-effective and labour efficient for commercial acceptability. Journal of Animal Physiology and Animal Nutrition © 2015 Blackwell Verlag GmbH.

  7. Modelling future oil production, population and the economy

    Energy Technology Data Exchange (ETDEWEB)

    Laherrere, Jean

    2003-07-01

    Most published data on energy, population and the economy are unreliable. In many cases, authors have political motives, selectively choosing data from a wide range of uncertainty to give a desired image. In addition to the uncertainty of the measurements themselves, as in the case of population or the confidentiality of the oil reserves, they often indulge in manipulation. A so-called hedonistic factor distorts the calculation of GDP in the United States; and the definition of the Proved Reserves by the Securities and Exchange Commission gives rise to 'reserve growth'. OPEC misreports its oil reserves because its quotas depend upon the reported reserves, and the reserves were overestimated in the Soviet Union because economic and technical constraints were ignored. Our present culture of eternal growth makes the word 'decline' politically incorrect, but constant growth is unsustainable in a finite world. Growth is the Santa Claus of the modern age who is supposed to provide welfare and retirement for our children and us. All natural events, when measured over their full life, can be modelled under one or more cycles, as in the Fourier analysis. This cyclical nature corresponds with the finite nature of the Universe; everything that is born will die, whether we speak of the solar system, the Earth, or human species. What goes up must come down. The Russian population is already declining and Europe's will soon do so too. This basic understanding was recognised by the celebrated King Hubbert when he made his famous prediction in 1956 that US oil production would peak in 1970. But, in fact, he oversimplified by showing a single peak. In reality, US oil production had a secondary peak (93% of the first one) in 1985, reflecting the entry of Alaskan production, which itself peaked in 1988. A symmetrical oil cycle reflects a large number of independent producers, acting randomly, but in many cases economic and political factors disturb the

  8. Stability evaluation of quality parameters for palm oil products at low temperature storage.

    Science.gov (United States)

    Ramli, Nur Aainaa Syahirah; Mohd Noor, Mohd Azmil; Musa, Hajar; Ghazali, Razmah

    2017-12-18

    Palm oil is one of the major oils and fats produced and traded worldwide. The value of palm oil products is mainly influenced by their quality. According to ISO 17025:2005, accredited laboratories shall have quality control procedure for monitoring the validity of tests for determination of quality parameters. This includes regular use of internal quality control using secondary reference materials. Unfortunately, palm oil reference materials are not currently available. In order to establish internal quality control samples, the stability of quality parameters need to be evaluated. In this study, the stability of quality parameters for palm oil products were examined over a period of ten months at low temperature storage (6 ± 2 °C). The palm oil products tested herein include crude palm oil (CPO), refined, bleached and deodorized (RBD) palm oil (RBDPO), RBD palm olein (RBDPOo), and RBD palm stearin (RBDPS). The quality parameters of the oils, i.e. moisture content, free fatty acid content (FFA), iodine value (IV), fatty acids composition (FAC) and slip melting point (SMP), were determined prior to and throughout the storage period. The moisture, FFA, IV, FAC and SMP for palm oil products changed significantly (P0.05). The stability study indicated that the quality of the palm oil products was stable within the specified limits throughout the storage period at low temperature. The storage condition has preserved the quality of palm oil products throughout the storage period. These findings qualify the use of the palm oil products; CPO, RBDPO, RBDPOo and RBDPS as control samples for validation of test results. This article is protected by copyright. All rights reserved.

  9. Study of the co-deoxy-liquefaction of biomass and vegetable oil for hydrocarbon oil production.

    Science.gov (United States)

    Chen, Yigang; Wang, Chao; Lu, Weipeng; Yang, Zhengyu

    2010-06-01

    Hydrocarbon oil was obtained by co-deoxy-liquefaction of biomass and vegetable oil in the work. Results showed the weight ratio of biomass to vegetable oil exerted a great effect on the quality of obtained hydrocarbon oil. The optimum weight ratio of biomass to vegetable oil was 4.4:1, when alkanes with the content of 50.43% were detected in obtained hydrocarbon oil, with lower oxygen content of 2.52%, which resulted in higher calorific value-up to 43.36 MJ kg(-1). At the same time, removal rate of carbonyl group of vegetable oil in the mixture reached at least 75.11%. The overall efficiency of the deoxy-liquefaction of biomass and the decarboxylation of vegetable oil were both enhanced by adding vegetable oil into biomass. Compared with the oils obtained from vegetable oil and biomass, respectively, distribution of hydrocarbon oil obtained from the mixture was much more similar to that of diesel oil. (c) 2010 Elsevier Ltd. All rights reserved.

  10. Bio-oil production from palm fronds by fast pyrolysis process in fluidized bed reactor

    Science.gov (United States)

    Rinaldi, Nino; Simanungkalit, Sabar P.; Kiky Corneliasari, S.

    2017-01-01

    Fast pyrolysis process of palm fronds has been conducted in the fluidized bed reactor to yield bio-oil product (pyrolysis oil). The process employed sea sand as the heat transfer medium. The objective of this study is to design of the fluidized bed rector, to conduct fast pyrolysis process to product bio-oil from palm fronds, and to characterize the feed and bio-oil product. The fast pyrolysis process was conducted continuously with the feeding rate around 500 g/hr. It was found that the biomass conversion is about 35.5% to yield bio-oil, however this conversion is still minor. It is suggested due to the heating system inside the reactor was not enough to decompose the palm fronds as a feedstock. Moreover, the acids compounds ware mostly observed on the bio-oil product.

  11. Ultrasound-assisted biodiesel production from Camelina sativa oil.

    Science.gov (United States)

    Sáez-Bastante, J; Ortega-Román, C; Pinzi, S; Lara-Raya, F R; Leiva-Candia, D E; Dorado, M P

    2015-06-01

    The main drawbacks of biodiesel production are high reaction temperatures, stirring and time. These could be alleviated by aiding transesterification with alternative energy sources, i.e. ultrasound (US). In this study, biodiesel was obtained from Camelina sativa oil, aided with an ultrasonic probe (20kHz, 70% duty cycle, 50% amplitude). Design of experiments included the combination of sonication and agitation cycles, w/wo heating (50°C). To gain knowledge about the implications of the proposed methodology, conventional transesterification was optimized, resulting in higher needs on catalyst concentration and reaction time, compared to the proposed reaction. Although FAME content met EN 14103 standard, FAME yields were lower than those provided by US-assisted transesterification. Energy consumption measurements showed that ultrasound assisted transesterification required lower energy, temperature, catalyst and reaction time. Copyright © 2015 Elsevier Ltd. All rights reserved.

  12. Cross-correlation between crude oil and refined product prices

    Science.gov (United States)

    Liu, Li; Ma, Guofeng

    2014-11-01

    In this paper, we investigate cross-correlations between crude oil and refined product prices based on the well-known detrended cross-correlation analysis (DCCA). Our findings indicate that the cross-correlations are significant and strong. Furthermore, the multifractality in cross-correlations is also revealed. The cross-correlation coefficients are as high as 0.9 for larger time scales and are greater than those for smaller time scales. Two popular models, vector error correction model and bivariate BEKK volatility model, are found to have very limited power in capturing long-range cross-correlations, suggesting the drawbacks of these conventional models in actual applications. Long-term cross-correlations are stronger in recent ten years than those in the past decades.

  13. Food and biomass production in small oil expression facilities

    Energy Technology Data Exchange (ETDEWEB)

    Kato, H.; Kanai, G.; Yakushido, K. [National Agricultural Research Center, Tsukuba (Japan). Biomass Production and Processing Research Team

    2010-07-01

    This paper reported on a study in which rapeseeds were separated into high quality seed for food oil and low quality seed for biofuels. A laboratory-scale oilseed screw press was then used to examine the effects of choke opening and seed preheating on the rapeseed pressing performance and the quality of food oil and biofuels oil. Oil recovery and chlorophyll content was found to increase as maximum pressure increased. In terms of pressing performance, the rapeseed heated by microwaves yielded more oil and chlorophyll than without heating. The NEB ratio of microwave heating press with an 8.0 mm choke opening was advantageous. Rapeseed oil extracted from low quality seeds was found to have a high acid value. The quality of oil extracted by oilseed screw press was found to be good and met the requirements of the Codex Alimentarius for edible oils.

  14. Measurement of the water content in oil and oil products using IR light-emitting diode-photodiode optrons

    Science.gov (United States)

    Bogdanovich, M. V.; Kabanau, D. M.; Lebiadok, Y. V.; Shpak, P. V.; Ryabtsev, A. G.; Ryabtsev, G. I.; Shchemelev, M. A.; Andreev, I. A.; Kunitsyna, E. V.; Ivanov, E. V.; Yakovlev, Yu. P.

    2017-02-01

    The feasibility of using light-emitting devices, the radiation spectrum of which has maxima at wavelengths of 1.7, 1.9, and 2.2 μm for determining the water concentration in oil and oil products (gasoline, kerosene, diesel fuel) has been demonstrated. It has been found that the measurement error can be lowered if (i) the temperature of the light-emitting diode is maintained accurate to 0.5-1.0°C, (ii) by using a cell through which a permanently stirred analyte is pumped, and (iii) by selecting the repetition rate of radiation pulses from the light-emitting diodes according to the averaging time. A meter of water content in oil and oil products has been developed that is built around IR light-emitting device-photodiode optrons. This device provides water content on-line monitoring accurate to 1.5%.

  15. Utilization of shale oil as a feedstock for steam pyrolysis and petrochemical intermediate production. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Dickson, P.F.; Yesavage, V.F.

    1979-09-01

    The major objectives of this study were to determine the effects of prerefining on product yields for steam pyrolysis of a shale oil feed and to determine the suitability of shale oil as a petrochemical feedstock. The results of this research program have in general been highly successful. A bench scale pyrolysis reactor was designed and constructed which was used to obtain yield data for variable operating conditions in the range typically employed commercially. Two crude shale oils were used in this study, a Tosco II shale oil as an example of above ground retorting and simulated in-situ shale oil as an example of in-situ processing. Each crude oil was processed to four different levels of prerefining: vacuum distillation and hydrogenation of the vacuum distillate at three levels of severity. A total of 112 experimental runs have been performed on the 10 shale oil samples. An initial comparison of shale oil with petroleum feedstocks indicates that yields of all major gaseous components for shale oil feedstocks are comparable with yields for petroleum fractions with the exception of ethylene. Yields of ethylene are in general considerably higher for the shale oil feedstocks than for typical petroleum feedstocks. A tendency for severely hydrogenated samples to gasify is at present the major qualification to the potential advantages of using shale oil as a petrochemical feedstock. To more fully define the sutiability of shale oil and prerefined shale oil as petrochemical feedstocks more thorough investigation of the liquid products is essential. A preliminary kinetics model was developed which consists of a reaction of feed shale oil to primary products, with subsequent reaction of these products to secondary products.

  16. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    Energy Technology Data Exchange (ETDEWEB)

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies would result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs.

  17. Processing use, and characterization of shale oil products

    Science.gov (United States)

    Decora, Andrew W.; Kerr, Robert D.

    1979-01-01

    Oil shale is a potential source of oil that will supplement conventional sources for oil as our needs for fossil fuels begin to exceed our supplies. The resource may be mined and processed on the surface or it may be processed in situ. An overview of the potential technologies and environmental issues is presented. PMID:446454

  18. Frankfurter Type Sausage Production with Sunflower Oil Substitution

    OpenAIRE

    Ertaş, A. Hamdi; KARABAŞ, Gülay

    1998-01-01

    Some quality characteristics of frankfurter type sausages (with 30% total fat) produced by adding sunflower oil at different levels (10%, 20% and 30%) were determined and compared to control with 30% animal fat. Increasing of sunflower oil content resulted in lower process yield. Cholesterol content and water holding capacity of frankfurters also decreased at the levels of sunflower oil from 10 to 30% (P

  19. Utilization possibilites of waste products from fishing and hunting to biogas and bio-oil production in Uummannaq County

    DEFF Research Database (Denmark)

    Gunnarsdottir, Ragnhildur; Jørgensen, Marianne Willemoes

    2008-01-01

    the specific conditions that apply in Uummannaq County. The best alternatives were evaluated to be biogas production and utilization of fat from the fish waste to produce bio-oil. The results showed that with the price of energy in Greenland in 2009 of 3,71 DKR per kWh, the waste in Uummannaq County would...... amount to approximately 6 million DKR when using biogas production and 5,7 million DKR when using bio-oil. Compared with the energy used in Uummannaq County today, the biogas production would be able to supply 17 percent of the energy and bio-oil production would cover approximately 16 percent....

  20. A Qualitative Approach of Identifying Major Cost Influencing Factors in Palm Oil Mills and the Relations towards Production Cost of Crude Palm Oil

    OpenAIRE

    Elaine L.Y. Man; Adam Baharum

    2011-01-01

    Problem statement: The oil palm industry, which heavily depends on the world market, is an export oriented industry. Worlds palm oil consumption was growing over the years. In addition, Indonesia and Malaysia dominated the oil palm industry. The oil palm industry in Malaysia is very competitive and become one of the major economic sectors contributing to the total revenue of the country. In year 2009, there was a total of 22.40 million tons of oil palm products including p...