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Sample records for cast duplex stainless

  1. Phase Transformations in Cast Duplex Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Yoon-Jun Kim

    2004-12-19

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as {sigma} and {chi} can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase ({sigma} + {chi}) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, {sigma} was stabilized with increasing Cr addition and {chi} by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in

  2. Phase Transformations in Cast Duplex Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Yoon-Jun [Iowa State Univ., Ames, IA (United States)

    2004-01-01

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as σ and χ can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase (σ + χ) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, σ was stabilized with increasing Cr addition and χ by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in DSS can be affected by

  3. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Byun, T. S.; Yang, Y.; Overman, N. R.; Busby, J. T.

    2016-02-28

    Cast stainless steels (CASSs) have been extensively used for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr–rich α'-phase by Spinodal decomposition of δ-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. An approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program and the results are used to describe the precipitation behaviors in duplex stainless steels. These results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  4. Final Report, Volume 1, Metallurgical Evaluation of Cast Duplex Stainless Steels and their Weldments

    Energy Technology Data Exchange (ETDEWEB)

    Wen, Songqing; Lundin, Carl, W.; Batten, Greg, W.

    2005-09-30

    Duplex stainless steels (DSS) are being specified for chloride containing environments due to their enhanced pitting and stress corrosion cracking resistance. They exhibit improved corrosion performance over the austenitic stainless steels. Duplex stainless steels also offer improved strength properties and are available in various wrought and cast forms. Selected grades of duplex stainless steel castings and their welds, in comparison with their wrought counterparts, were evaluated, regarding corrosion performance and mechanical properties and weldability. Multiple heats of cast duplex stainless steel were evaluated in the as-cast, solution annealed (SA) static cast and SA centrifugal cast conditions, while their wrought counterparts were characterized in the SA condition and in the form of as-rolled plate. Welding, including extensive assessment of autogenous welds and a preliminary study of composite welds (shielded metal arc weld (SMAW)), was performed. The evaluations included critical pitting temperature (CPT) testing, intergranular corrosion (IGC) testing, ASTM A923 (Methods A, B and C), Charpy impact testing, weldability testing (ASTM A494), ferrite measurement and microstructural evaluations. In the study, the corrosion performances of DSS castings were characterized and assessed, including the wrought counterparts for comparison. The evaluation filled the pore of lack of data for cast duplex stainless steels compared to wrought materials. A database of the pitting corrosion and IGC behavior of cast and wrought materials was generated for a greater depth of understanding for the behavior of cast duplex stainless steel. In addition, improved evaluation methods for DSS castings were developed according to ASTM A923, A262, G48 and A494. The study revealed that when properly heat treated according to the specification, (1) DSS castings have equal or better pitting and intergranular corrosion resistance than their wrought counterparts; (2) Welding reduces the

  5. Final Report, Volume 1, Metallurgical Evaluation of Cast Duplex Stainless Steels and their Weldments

    Energy Technology Data Exchange (ETDEWEB)

    Wen, Songqing; Lundin, Carl, W.; Batten, Greg, W.

    2005-09-30

    Duplex stainless steels (DSS) are being specified for chloride containing environments due to their enhanced pitting and stress corrosion cracking resistance. They exhibit improved corrosion performance over the austenitic stainless steels. Duplex stainless steels also offer improved strength properties and are available in various wrought and cast forms. Selected grades of duplex stainless steel castings and their welds, in comparison with their wrought counterparts, were evaluated, regarding corrosion performance and mechanical properties and weldability. Multiple heats of cast duplex stainless steel were evaluated in the as-cast, solution annealed (SA) static cast and SA centrifugal cast conditions, while their wrought counterparts were characterized in the SA condition and in the form of as-rolled plate. Welding, including extensive assessment of autogenous welds and a preliminary study of composite welds (shielded metal arc weld (SMAW)), was performed. The evaluations included critical pitting temperature (CPT) testing, intergranular corrosion (IGC) testing, ASTM A923 (Methods A, B and C), Charpy impact testing, weldability testing (ASTM A494), ferrite measurement and microstructural evaluations. In the study, the corrosion performances of DSS castings were characterized and assessed, including the wrought counterparts for comparison. The evaluation filled the pore of lack of data for cast duplex stainless steels compared to wrought materials. A database of the pitting corrosion and IGC behavior of cast and wrought materials was generated for a greater depth of understanding for the behavior of cast duplex stainless steel. In addition, improved evaluation methods for DSS castings were developed according to ASTM A923, A262, G48 and A494. The study revealed that when properly heat treated according to the specification, (1) DSS castings have equal or better pitting and intergranular corrosion resistance than their wrought counterparts; (2) Welding reduces the

  6. Ferrite Measurement in Austenitic and Duplex Stainless Steel Castings - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Lundin, C.D.; Zhou, G.; Ruprecht, W.

    1999-08-01

    The ability to determine ferrite rapidly, accurately and directly on a finished casting, in the solution annealed condition, can enhance the acceptance, save on manufacturing costs and ultimately improve service performance of duplex stainless steel cast products. If the suitability of a non-destructive ferrite determination methodology can be demonstrated for standard industrial measurement instruments, the production of cast secondary standards for calibration of these instruments is a necessity. With these concepts in mind, a series of experiments were carried out to demonstrate, in a non-destructive manner, the proper methodology for determining ferrite content. The literature was reviewed, with regard to measurement techniques and vagaries, an industrial ferrite measurement round-robin was conducted, the effects of casting surface finish, preparation of the casting surface for accurate measurement and the evaluation of suitable means for the production of cast secondary standards for calibration were systematically investigated. The data obtained from this research program provide recommendations to ensure accurate, repeatable, and reproducible ferrite measurement and qualifies the Feritscope for field use on production castings.

  7. Ferrite Measurement in Austenitic and Duplex Stainless Steel Castings - Literature Review

    Energy Technology Data Exchange (ETDEWEB)

    Lundin, C.D.; Zhou, G.; Ruprecht, W.

    1999-08-01

    The ability to determine ferrite rapidly, accurately and directly on a finished casting, in the solution annealed condition, can enhance the acceptance, save on manufacturing costs and ultimately improve service performance of duplex stainless steel cast products. If the suitability of a non-destructive ferrite determination methodology can be demonstrated for standard industrial measurement instruments, the production of cast secondary standards for calibration of these instruments is a necessity. With these concepts in mind, a series of experiments were carried out to demonstrate, in a non-destructive manner, the proper methodology for determining ferrite content. The literature was reviewed, with regard to measurement techniques and vagaries, an industrial ferrite measurement round-robin was conducted, the effects of casting surface finish, preparation of the casting surface for accurate measurement and the evaluation of suitable means for the production of cast secondary standards for calibration were systematically investigated. The data obtained from this research program provides recommendations to insure accurate, repeatable and reproducible ferrite measurement and qualifies the Feritscope for field use on production castings.

  8. Clean cast steel technology. Determination of transformation diagrams for duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Chumbley, S. L. [Iowa State Univ., Ames, IA (United States)

    2005-09-01

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as sigma ( can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling- transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe 22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase ( formation were analyzed using the Johnson-Mehl-Avrami (JMA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations, The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities, a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, was stabilized with increasing Cr addition and by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in DSS can be affected by local

  9. Investigation of thermal aging damage mechanism of the Cast Duplex Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Wang Zhaoxi, E-mail: wangzx03@mails.tsinghua.edu.c [Applied Mechanics Laboratory, Tsinghua University, Beijing 100084 (China); Suzhou Nuclear Power Research Institute, Suzhou 215004 (China); Xue Fei; Guo Wenhai [Suzhou Nuclear Power Research Institute, Suzhou 215004 (China); Shi Huiji [Applied Mechanics Laboratory, Tsinghua University, Beijing 100084 (China); Zhang Guodong [Suzhou Nuclear Power Research Institute, Suzhou 215004 (China); School of Mechanical and Power Engineering, Nanjing University of Technology, Nanjing 210009 (China); Shu Guogang [Suzhou Nuclear Power Research Institute, Suzhou 215004 (China)

    2010-10-15

    Besides the macro-mechanical properties for thermal aging effect published in 'Thermal aging effect on Z3CN20.09M Cast Duplex Stainless Steel' (Nuclear Engineering and Design 239(2009) 2217-2223), the thermal aging damage mechanism is investigated in this paper through nano-indentation tests and micro-structures evolution examination. Numerical simulations were carried out with GTN continuum damage model to investigate the different crack propagation process for aging. The nano-indentation hardness values increase with aging time for both phases while the hardness values of the ferrite phase are much higher and increase much more. The nano-indentation energy indicating the toughness decreases for both phases with aging time. TEM results show that the Cr-enriched {alpha}' phase precipitates in the ferrite phase which is considered as the critical reason making the dislocation slip difficult and causing the increase of the strength and reduction of the toughness. The crack initiates from the ferrite phase instead of the austenite phase from the SEM observation and FEA simulation results, which reflects the change of the fracture mechanism for thermal aging.

  10. Final Report, Volume 2, The Development of Qualification Standards for Cast Duplex Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Russell, Steven, W.; Lundin, Carl, D.

    2005-09-30

    The scope of testing cast Duplex Stainless Steel (DSS) required testing to several ASTM specifications, while formulating and conducting industry round robin tests to verify and study the reproducibility of the results. ASTM E562 (Standard Test Method for Determining Volume Fraction by Systematic manual Point Count) and ASTM A923 (Standard Test Methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic/Ferritic Stainless Steels) were the specifications utilized in conducting this work. An ASTM E562 industry round robin, ASTM A923 applicability study, ASTM A923 industry round robin, and an ASTM A923 study of the effectiveness of existing foundry solution annealing procedures for producing cast DSS without intermetallic phases were implemented. In the ASTM E562 study, 5 samples were extracted from various cast austenitic and DSS in order to have varying amounts of ferrite. Each sample was metallographically prepared by UT and sent to each of 8 participants for volume fraction of ferrite measurements. Volume fraction of ferrite was measured using manual point count per ASTM E562. FN was measured from the Feritescope{reg_sign} and converted to volume fraction of ferrite. Results indicate that ASTM E562 is applicable to DSS and the results have excellent lab-to-lab reproducibility. Also, volume fraction of ferrite conversions from the FN measured by the Feritescope{reg_sign} were similar to volume fraction of ferrite measured per ASTM E562. In the ASTM A923 applicability to cast DSS study, 8 different heat treatments were performed on 3 lots of ASTM A890-4A (CD3MN) castings and 1 lot of 2205 wrought DSS. The heat treatments were selected to produce a wide range of cooling rates and hold times in order to study the suitability of ASTM A923 to the response of varying amounts on intermetallic phases [117]. The test parameters were identical to those used to develop ASTM A923 for wrought DSS. Charpy V-notch impact samples were extracted from the

  11. Final Report, Volume 2, The Development of Qualification Standards for Cast Duplex Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Russell, Steven, W.; Lundin, Carl, W.

    2005-09-30

    The scope of testing cast Duplex Stainless Steel (DSS) required testing to several ASTM specifications, while formulating and conducting industry round robin tests to verify and study the reproducibility of the results. ASTM E562 (Standard Test Method for Determining Volume Fraction by Systematic manual Point Count) and ASTM A923 (Standard Test Methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic/Ferritic Stainless Steels) were the specifications utilized in conducting this work. An ASTM E562 industry round robin, ASTM A923 applicability study, ASTM A923 industry round robin, and an ASTM A923 study of the effectiveness of existing foundry solution annealing procedures for producing cast DSS without intermetallic phases were implemented. In the ASTM E562 study, 5 samples were extracted from various cast austenitic and DSS in order to have varying amounts of ferrite. Each sample was metallographically prepared by UT and sent to each of 8 participants for volume fraction of ferrite measurements. Volume fraction of ferrite was measured using manual point count per ASTM E562. FN was measured from the Feritescope® and converted to volume fraction of ferrite. Results indicate that ASTM E562 is applicable to DSS and the results have excellent lab-to-lab reproducibility. Also, volume fraction of ferrite conversions from the FN measured by the Feritescope® were similar to volume fraction of ferrite measured per ASTM E562. In the ASTM A923 applicability to cast DSS study, 8 different heat treatments were performed on 3 lots of ASTM A890-4A (CD3MN) castings and 1 lot of 2205 wrought DSS. The heat treatments were selected to produce a wide range of cooling rates and hold times in order to study the suitability of ASTM A923 to the response of varying amounts on intermetallic phases [117]. The test parameters were identical to those used to develop ASTM A923 for wrought DSS. Charpy V-notch impact samples were extracted from the castings and wrought

  12. Development of TRIP-Aided Lean Duplex Stainless Steel by Twin-Roll Strip Casting and Its Deformation Mechanism

    Science.gov (United States)

    Zhao, Yan; Zhang, Weina; Liu, Xin; Liu, Zhenyu; Wang, Guodong

    2016-12-01

    In the present work, twin-roll strip casting was carried out to fabricate thin strip of a Mn-N alloyed lean duplex stainless steel with the composition of Fe-19Cr-6Mn-0.4N, in which internal pore defects had been effectively avoided as compared to conventional cast ingots. The solidification structure observed by optical microscope indicated that fine Widmannstatten structure and coarse-equiaxed crystals had been formed in the surface and center, respectively, with no columnar crystal structures through the surface to center of the cast strip. By applying hot rolling and cold rolling, thin sheets with the thickness of 0.5 mm were fabricated from the cast strips, and no edge cracks were formed during the rolling processes. With an annealing treatment at 1323 K (1050 °C) for 5 minutes after cold rolling, the volume fractions of ferrite and austenite were measured to be approximately equal, and the distribution of alloying elements in the strip was further homogenized. The cold-rolled and annealed sheet exhibited an excellent combination of strength and ductility, with the ultimate tensile strength and elongation having been measured to be 1000 MPa and 65 pct, respectively. The microstructural evolution during deformation was investigated by XRD, EBSD, and TEM, indicating that ferrite and austenite had different deformation mechanisms. The deformation of ferrite phase was dominated by dislocation slipping, and the deformation of austenite phase was mainly controlled by martensitic transformation in the sequence of γ→ ɛ-martensite→ α'-martensite, leading to the improvement of strength and plasticity by the so-called transformation-induced plasticity (TRIP) effect. By contrast, lean duplex stainless steels of Fe-21Cr-6Mn-0.5N and Fe-23Cr-7Mn-0.6N fabricated by twin-roll strip casting did not show TRIP effects and exhibited lower strength and elongation as compared to Fe-19Cr-6Mn-0.4N.

  13. Sigma-phase formation in weldments of cast super duplex stainless steel; Formacion de fase sigma en uniones soldadas de acero inoxidable super duplex fundido

    Energy Technology Data Exchange (ETDEWEB)

    Garin, J. L.; Mannheim, R. L.; Camus, M. A.

    2011-07-01

    This paper describes the microstructural characteristics of weldments of cast super duplex stainless steel (J93404), being subjected to annealing processes to induce formation of sigma-phase at high temperatures. The influence of heating time at 1073 K, 1123 K and 1173 K upon precipitation of sigma in the heat affected zone, base metal and fusion zone of the weldments was analyzed. The experimental results revealed the formation of this intermetallic compound throughout decomposition of the ferritic phase into austenite and sigma. At earlier stages of the transformation the phase rapidly nucleates and growth along the ferrite-austenite grain boundaries, and then massively advances towards the bulk of the ferritic zone with greater effectiveness as temperature increases. The formation of sigma-phase in all weldments resembles the Johnson-Mehl-Avramis mechanism stated for nucleation and growth. (Author) 27 refs.

  14. Effect of rolling deformation and solution treatment on microstructure and mechanical properties of a cast duplex stainless steel

    Indian Academy of Sciences (India)

    S K Ghosh; D Mahata; R Roychaudhuri; R Mondal

    2012-10-01

    The present study deals with the effect of rolling deformation and solution treatment on the microstructure and mechanical properties of a cast duplex stainless steel. Cast steel reveals acicular/Widmanstätten morphology as well as island of austenite within the -ferrite matrix. Hot rolled samples exhibit the presence of lower volume percent of elongated band of -ferrite (∼40%) and austenite phase which convert into finer and fragmented microstructural constituents after 30% cold deformation. By the solution treatment, the elongated and broken crystalline grains recrystallize which leads to the formation of finer grains (<10 m) of austenite. X-ray diffraction analysis has corroborated well with the above-mentioned microstructural investigation. Enhancement in hardness, yield strength and tensile strength values as well as drop in percent elongation with cold deformation increases its suitability for use in thinner sections. 30% cold rolled and solution treated sample reveals attractive combination of strength and ductility (25.22 GPa%). The examination of fracture surface also substantiates the tensile results. The sub-surface micrographs provide the potential sites for initiation of microvoids.

  15. Final Report, Volume 4, The Develpoment of Qualification Standards forCast Super Duplex Stainless Steel (2507 Wrought Equivalent)

    Energy Technology Data Exchange (ETDEWEB)

    Hariharan, Vasudevan; Lundin, Carl, D.

    2005-09-30

    The objective of the program is to determine the suitability of ASTM A923 Standard Test methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic-Ferritic Stainless Steels for 25 Cr Cast Super Duplex Stainless Steels (ASTM A890-5A). Different tests were carried out on the materials procured from various steel foundries as stated in the ASTM A923. The foundries were designated as Foundry A, B, C and D. All the materials were foundry solution annealed. Materials from Foundry D were solution heat treated at The University of Tennessee also and then they were subjected to heat treatment schedule which was derived from the testing of wrought DSS to establish the A923 specification. This was possible because the material from the same heat was sufficient for conducting the full scope of heat treatment. This was done prior to carrying out various other tests. Charpy samples were machined. The Ferrite content was measured in all the Charpy samples using Feritscope{reg_sign} and ASTM E562 Manual Point Count Method. After the ferrite content was measured the samples were sent to AMC-Vulcan, Inc. in Alabama to conduct the Charpy impact test based on ASTM A923 Test Method B. This was followed by etch testing and corrosion analysis based on ASTM A923 Test Methods A and C respectively at University of Tennessee. Hardness testing using Rockwell B and C was also carried out on these samples. A correlation was derived between all the three test methods and the best method for evaluating the presence of intermetallic in the material was determined. The ferrite content was correlated with the toughness values. Microstructural analysis was carried out on the etch test samples using Scanning Electron Microscopy in order to determine if intermetallic phases were present. The fracture surfaces from Charpy test specimens were also observed under SEM in order to determine the presence of any cracks and whether it was a brittle or a ductile fracture. A correlation

  16. Final Report, Volume 4, The Development of Qualification Standards for Cast Super Duplex Stainless Steel (2507 Wrought Equivalent)

    Energy Technology Data Exchange (ETDEWEB)

    Hariharan, Vasudevan; Lundin, Carl, W.

    2005-09-30

    The objective of the program is to determine the suitability of ASTM A923 Standard Test methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic-Ferritic Stainless Steels for 25 Cr Cast Super Duplex Stainless Steels (ASTM A890-5A). Different tests were carried out on the materials procured from various steel foundries as stated in the ASTM A923. The foundries were designated as Foundry A, B, C and D. All the materials were foundry solution annealed. Materials from Foundry D were solution heat treated at The University of Tennessee also and then they were subjected to heat treatment schedule which was derived from the testing of wrought DSS to establish the A923 specification. This was possible because the material from the same heat was sufficient for conducting the full scope of heat treatment. This was done prior to carrying out various other tests. Charpy samples were machined. The Ferrite content was measured in all the Charpy samples using Feritscope® and ASTM E562 Manual Point Count Method. After the ferrite content was measured the samples were sent to AMC-Vulcan, Inc. in Alabama to conduct the Charpy impact test based on ASTM A923 Test Method B. This was followed by etch testing and corrosion analysis based on ASTM A923 Test Methods A and C respectively at University of Tennessee. Hardness testing using Rockwell B and C was also carried out on these samples. A correlation was derived between all the three test methods and the best method for evaluating the presence of intermetallic in the material was determined. The ferrite content was correlated with the toughness values. Microstructural analysis was carried out on the etch test samples using Scanning Electron Microscopy in order to determine if intermetallic phases were present. The fracture surfaces from Charpy test specimens were also observed under SEM in order to determine the presence of any cracks and whether it was a brittle or a ductile fracture. A correlation was

  17. Long-term embrittlement of cast duplex stainless steels in LWR systems. Semiannual report, October 1991--March 1992: Volume 7, No.1

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, O.K. [Argonne National Lab., IL (United States)

    1993-05-01

    This progress report summarizes work performed by Argonne National Laboratory on long-term thermal embrittlement of cast duplex stainless steels in LWR systems during the six months from October 1991 to March 1992. Charpy-impact, tensile, and fracture toughness J-R curve data are presented for several heats of cast stainless steel that were aged 10,000-58,000 h at 290, 320, and 350{degree}C. The results indicate that thermal aging decreases the fracture toughness of cast stainless steels. In general, CF-3 steels are the least sensitive to thermal aging and CF-8M steels are the most sensitive. The values of fracture toughness J{sub IC} and tearing modulus for CF-8M steels can be as low as {approx}90 kJ/m{sup 2} and {approx}60, respectively. The fracture toughness data are consistent with the Charpy-impact results, i.e. unaged and aged steels that show low impact energy also exhibit lower fracture toughness. All steels reach a minimum saturation fracture toughness after thermal aging; the time to reach saturation depends on the aging temperature. The results also indicate that low-strength cast stainless steels are generally insensitive to thermal aging.

  18. Final Report, Volume 4, The Development of Qualification Standards for Cast Super Duplex Stainless Steel (2507 Wrought Equivalent)

    Energy Technology Data Exchange (ETDEWEB)

    Hariharan, Vasudevan; Lundin, Carl, W.

    2005-09-30

    The objective of the program is to determine the suitability of ASTM A923 Standard Test methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic-Ferritic Stainless Steels for 25 Cr Cast Super Duplex Stainless Steels (ASTM A890-5A). Different tests were carried out on the materials procured from various steel foundries as stated in the ASTM A923. The foundries were designated as Foundry A, B, C and D. All the materials were foundry solution annealed. Materials from Foundry D were solution heat treated at The University of Tennessee also and then they were subjected to heat treatment schedule which was derived from the testing of wrought DSS to establish the A923 specification. This was possible because the material from the same heat was sufficient for conducting the full scope of heat treatment. This was done prior to carrying out various other tests. Charpy samples were machined. The Ferrite content was measured in all the Charpy samples using Feritscope® and ASTM E562 Manual Point Count Method. After the ferrite content was measured the samples were sent to AMC-Vulcan, Inc. in Alabama to conduct the Charpy impact test based on ASTM A923 Test Method B. This was followed by etch testing and corrosion analysis based on ASTM A923 Test Methods A and C respectively at University of Tennessee. Hardness testing using Rockwell B and C was also carried out on these samples. A correlation was derived between all the three test methods and the best method for evaluating the presence of intermetallic in the material was determined. The ferrite content was correlated with the toughness values. Microstructural analysis was carried out on the etch test samples using Scanning Electron Microscopy in order to determine if intermetallic phases were present. The fracture surfaces from Charpy test specimens were also observed under SEM in order to determine the presence of any cracks and whether it was a brittle or a ductile fracture. A correlation was

  19. Final Report, Volume 4, The Develpoment of Qualification Standards forCast Super Duplex Stainless Steel (2507 Wrought Equivalent)

    Energy Technology Data Exchange (ETDEWEB)

    Hariharan, Vasudevan; Lundin, Carl, D.

    2005-09-30

    The objective of the program is to determine the suitability of ASTM A923 Standard Test methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic-Ferritic Stainless Steels for 25 Cr Cast Super Duplex Stainless Steels (ASTM A890-5A). Different tests were carried out on the materials procured from various steel foundries as stated in the ASTM A923. The foundries were designated as Foundry A, B, C and D. All the materials were foundry solution annealed. Materials from Foundry D were solution heat treated at The University of Tennessee also and then they were subjected to heat treatment schedule which was derived from the testing of wrought DSS to establish the A923 specification. This was possible because the material from the same heat was sufficient for conducting the full scope of heat treatment. This was done prior to carrying out various other tests. Charpy samples were machined. The Ferrite content was measured in all the Charpy samples using Feritscope{reg_sign} and ASTM E562 Manual Point Count Method. After the ferrite content was measured the samples were sent to AMC-Vulcan, Inc. in Alabama to conduct the Charpy impact test based on ASTM A923 Test Method B. This was followed by etch testing and corrosion analysis based on ASTM A923 Test Methods A and C respectively at University of Tennessee. Hardness testing using Rockwell B and C was also carried out on these samples. A correlation was derived between all the three test methods and the best method for evaluating the presence of intermetallic in the material was determined. The ferrite content was correlated with the toughness values. Microstructural analysis was carried out on the etch test samples using Scanning Electron Microscopy in order to determine if intermetallic phases were present. The fracture surfaces from Charpy test specimens were also observed under SEM in order to determine the presence of any cracks and whether it was a brittle or a ductile fracture. A correlation

  20. Tem study of thermal ageing of ferrite in cast duplex stainless steel; Etude par microscopie electronique en transmission du vieillissement thermique de la ferrite d'aciers inoxydables austenoferritiques moules

    Energy Technology Data Exchange (ETDEWEB)

    Nenonen, P. [VTT Industrial Systems (Finland); Massoud, J.P. [Electricite de France (EDF), 75 - Paris (France); Timofeev, B.T. [ZNIIKM, Moscow (Russian Federation)

    2002-07-01

    The changes in the microstructure and composition of ferrite in two types of cast duplex stainless steels and in an austenitic-ferritic weld metal after long term thermal ageing has been studied using analytical transmission electron microscope (FEGTEM). A cast test steel containing Mo was investigated first as a reference material in three different conditions: as solution annealed, aged at 300 C and aged at 400 C. This investigation was carried out to gain experience of how EDS (X-ray analyser) analyser and TEM (transmission electron microscope) can be used to study elemental inhomogeneity, which is usually investigated with an atom probe (APFIM). The two other materials, an austenitic-ferritic weld metal and a cast duplex Ti-stabilised stainless steel used for long time at NPP operation temperature were investigated using the experience obtained with the test steel. The results showed that analytical TEM can be used to investigate elemental inhomogeneity of ferrite, but there are several important things to be taken into account when the spectra for this purpose are collected. These things are, such as the thickness of the specimen, probe size, contamination rate, 'elemental background' of the spectrum and possible enrichment of certain alloying elements in the surface oxide layer of the TEM-specimens. If minor elements are also analysed, it may increase the scattering of the results. (authors)

  1. MICROSCOPIC CORROSION STUDIES OF DUPLEX STAINLESS STEELS

    Institute of Scientific and Technical Information of China (English)

    C.Leygraf; J.Pan; M.Femenia

    2004-01-01

    Electrochemical scanning tunneling microscopy and scanning electrochemical microscopy have been used for in situ monitoring of localized corrosion processes of different Duplex stainless steels (DSS) in acidic chloride solutions. The techniques allow imaging of local dissolution events with micrometer resolution, as opposed to conventional electrochemical techniques, which only give an overall view of the corrosion behavior. In addition, combined scanning Kelvin probe force microscopy and magnetic force microscopy were used for mapping the Volta potential variation over the surface of DSSs. A significant difference in Volta potential between the austenite and ferrite phases suggests galvanic interaction between the phases. A compositional gradient appears within 2 micrometers across the phase boundary, as seen with scanning Auger microscopy (SAM). In all, the studies suggest that higher alloyed DSS exhibit a more homogeneous dissolution behavior than lower alloyed DSS, due to higher and more similar corrosion resistance of the two phases, and enhanced resistance of the ferrite/austenite phase boundary regions.

  2. Investigation of the Hot Plasticity of Duplex Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    LIN Gang; ZHANG Zhi-xia; SONG Hong-wei; TONG Jun; ZHOU Can-dong

    2008-01-01

    Hot plasticity of a nitrogen alloyed 25Cr-7Ni-4 Mo duplex stainless steel was investigated.The results indicate that thc main factors affecting the hot plasticity of duplex stainless steel are listed as follows:coalescent force of phase interface,microstructure,and the phase ratio and difference between the mechanicsl propertms of ferrite and austenite.The heat treatment and sulphur contents have a notable effect on the hot plasticity.The reasonable heat treatrnents and the irlcreased interfacial coalescent force will effectively enhance the hot plasticity of duplex stainless steel.

  3. Hot Deformation Behavior of As-Cast 2101 Grade Lean Duplex Stainless Steel and the Associated Changes in Microstructure and Crystallographic Texture

    Science.gov (United States)

    Patra, Sudipta; Ghosh, Abhijit; Singhal, Lokesh Kumar; Podder, Arijit Saha; Sood, Jagmohan; Kumar, Vinod; Chakrabarti, Debalay

    2017-01-01

    The hot deformation behavior of 2101 grade lean duplex stainless steel (DSS, containing 5 wt pct Mn, 0.2 wt pct N, and 1.4 wt pct Ni) and associated microstructural changes within δ-ferrite and austenite ( γ) phases were investigated by hot-compression testing in a GLEEBLE 3500 simulator over a range of deformation temperatures, T def [1073 K to 1373 K (800 °C to 1100 °C)], and applied strains, ɛ (0.25 to 0.80), at a constant true strain rate of 1/s. The microstructural softening inside γ was dictated by discontinuous dynamic recrystallization (DDRX) at a higher T def [1273 K to 1373 K (1000 °C to 1100 °C)], while the same was dictated by continuous dynamic recrystallization (CDRX) at a lower T def (1173 K (900 °C)]. Dynamic recovery (DRV) and CDRX dominated the softening inside δ-ferrite at T def ≥ 1173 K (900 °C). The dynamic recrystallization (DRX) inside δ and γ could not take place upon deformation at 1073 K (800 °C). The average flow stress level increased 2 to 3 times as the T def dropped from 1273 to 1173 K (1000 °C to 900 °C) and finally to 1073 K (800 °C). The average microhardness values taken from δ-ferrite and γ regions of the deformed samples showed a different trend. At T def of 1373 K (1100 °C), microhardness decreased with the increase in strain, while at T def of 1173 K (900 °C), microhardness increased with the increase in strain. The microstructural changes and hardness variation within individual phases of hot-deformed samples are explained in view of the chemical composition of the steel and deformation parameters ( T def and ɛ).

  4. Hot Deformation Behavior of As-Cast 2101 Grade Lean Duplex Stainless Steel and the Associated Changes in Microstructure and Crystallographic Texture

    Science.gov (United States)

    Patra, Sudipta; Ghosh, Abhijit; Singhal, Lokesh Kumar; Podder, Arijit Saha; Sood, Jagmohan; Kumar, Vinod; Chakrabarti, Debalay

    2016-11-01

    The hot deformation behavior of 2101 grade lean duplex stainless steel (DSS, containing 5 wt pct Mn, 0.2 wt pct N, and 1.4 wt pct Ni) and associated microstructural changes within δ-ferrite and austenite (γ) phases were investigated by hot-compression testing in a GLEEBLE 3500 simulator over a range of deformation temperatures, T def [1073 K to 1373 K (800 °C to 1100 °C)], and applied strains, ɛ (0.25 to 0.80), at a constant true strain rate of 1/s. The microstructural softening inside γ was dictated by discontinuous dynamic recrystallization (DDRX) at a higher T def [1273 K to 1373 K (1000 °C to 1100 °C)], while the same was dictated by continuous dynamic recrystallization (CDRX) at a lower T def (1173 K (900 °C)]. Dynamic recovery (DRV) and CDRX dominated the softening inside δ-ferrite at T def ≥ 1173 K (900 °C). The dynamic recrystallization (DRX) inside δ and γ could not take place upon deformation at 1073 K (800 °C). The average flow stress level increased 2 to 3 times as the T def dropped from 1273 to 1173 K (1000 °C to 900 °C) and finally to 1073 K (800 °C). The average microhardness values taken from δ-ferrite and γ regions of the deformed samples showed a different trend. At T def of 1373 K (1100 °C), microhardness decreased with the increase in strain, while at T def of 1173 K (900 °C), microhardness increased with the increase in strain. The microstructural changes and hardness variation within individual phases of hot-deformed samples are explained in view of the chemical composition of the steel and deformation parameters (T def and ɛ).

  5. Properties of duplex stainless steels made by powder metallurgy

    OpenAIRE

    Rosso, M.; M. Actis Grande; Z. Brytan; L.A. Dobrzański

    2007-01-01

    Purpose: of this paper was to examine the mechanical properties of duplex stainless steels.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the studies behind the preparation of mixes, Schaeffler’s diagram was taken into consideration. Prepared mixes have been sintered in a vacuu...

  6. Corrosion behaviour of sintered duplex stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Utrilla, M. Victoria; Urena, Alejandro; Otero, Enrique; Munez, Claudio Jose [Escuela Superior de Ciencias Experimentales y Tecnologia, Universidad Rey Juan Carlos, C/ Tulipan s/n, 28933 Mostoles, Madrid (Spain)

    2004-07-01

    Duplex austenite-ferrite stainless steels were prepared by mixing austenitic (316L) and ferritic (434L) atomized powders. Although different 316L/434L ratios were prepared, present work centred its study on 50% ferrite - 50% austenite sintered steel. The powders were mixed and pressed at 700 MPa and sintered at 1250 deg. C for 30 min in vacuum. The cooling rate was 5 deg. C/min. Solution treatment was carried out to homogenize the microstructure at 1100 deg. C during 20 min. A microstructural study of the material in solution was performed, evaluating the microstructure, proportion and shape of porosity, and ferrite percentage. This last was measured by two methods, quantitative metallography and Fischer ferrito-metry. The materials were heat treated in the range of 700 to 1000 deg. C, for 10, 30 and 60 min and water quenched, to study the microstructural changes and the influence on the intergranular corrosion resistance. The method used to evaluate the sensitization to the intergranular corrosion was the electrochemical potentio-kinetic reactivation procedure (EPR). The test solution was 0.5 M H{sub 2}SO{sub 4} + 0,01 M KSCN at 30 deg. C. The criterion used to evaluate the sensitization was the ratio between the maximum reactivation density (Ir) and the maximum activation density (Ia). The results of the electrochemical tests were discussed in relation with the microstructures observed at the different heat treatments. (authors)

  7. Ferrite Quantification Methodologies for Duplex Stainless Steel

    Directory of Open Access Journals (Sweden)

    Arnaldo Forgas Júnior

    2016-07-01

    Full Text Available In order to quantify ferrite content, three techniques, XRD, ferritoscope and optical metallography, were applied to a duplex stainless steel UNS S31803 solution-treated for 30 min at 1,000, 1,100 and 1,200 °C, and then compared to equilibrium of phases predicted by ThermoCalc® simulation. As expected, the microstructure is composed only by austenite and ferrite phases, and ferrite content increases as the solution treatment temperature increases. The microstructure presents preferred grains orientation along the rolling directions even for a sample solution treated for 30 min at 1,200 °C. For all solution treatment temperatures, the ferrite volume fractions obtained by XRD measurements were higher than those achieved by the other two techniques and ThermoCalc® simulation, probably due to texturing effect of previous rolling process. Values obtained by quantitative metallography look more assertive as it is a direct measurement method but the ferritoscope technique should be considered mainly for in loco measurement.

  8. XPS Analysis of Corrosion Product Scale on Surface of 29Cr Super Duplex Stainless Cast Steel%29Cr超级双相不锈铸钢表面腐蚀XPS分析

    Institute of Scientific and Technical Information of China (English)

    向红亮; 黄伟林; 刘东; 何福善

    2011-01-01

    用x射线光电子能谱(XPS)技术研究29Cr超级双相不锈铸钢在人工海水中经电化学极化后表面腐蚀产物.结果表明,材料的腐蚀是以点蚀为主的局部腐蚀;MoO4^2-,NH+和少量Noi吸附在钝化膜表面,从而提升钝化膜的保护作用.材料在人工海水中极化后的钝化膜表层主要由氢氧化物Cr(OH)3,FeOOH等和氧化物Cr2O3,Fe3O4,FeO,Fe2O3,MOo2,MoO3,NiO等组成;在膜的里层有大量的金属单质Fe,Cr,Ni,Mo等和氧化物Cr2O3,Fe3O4,FeO,MoO2,NiO等及金属氮化物Cr2%The chemical constituent of corrosion product scale on 29Cr super duplex stainless cast steel after electrochemical polarization in artificial seawater was studied by X-ray photoelectron spectroscopy in this paper. The results indicate that the corrosion is mainly pitting corrosion; MoO42-, NH+ and a small amount of NO3 absorbed on the surface of the passive film so that to enhance the protectiveness of the layer. The outer portion of passive film of 29Cr super duplex stainless steel is mainly composed of hydroxide type compounds such as Cr(OH)3, FeOOH and oxides such as Cr2O3, Fe3O4, FeO, Fe2O3, MOO2, MoO3 and NiO, but its inner portion is mainly composed of abundant metallic elements of Fe, Cr, Ni, Mo and oxides including Cr2O3, Fe3O4, FeO, MOO2, NiO and some nitride such as Cr2N. During the passivation process, Cr2N tends to enrich at the passive film surface, thereby its pitting corrosion resistance may be enhanced.

  9. Microstructure of reaction zone in WCp/duplex stainless steels matrix composites processing by laser melt injection

    NARCIS (Netherlands)

    Do Nascimento, A. M.; Ocelik, V.; Ierardi, M. C. F.; De Hosson, J. Th. M.

    2008-01-01

    The laser melt injection (LMI) process has been used to create a metal matrix composite consisting of 80gm sized multi-grain WC particles embedded in three cast duplex stainless steels. The microstruture was investigated by scanning electron microscopy with integrated EDS and electron back-scatter d

  10. Effect of ultrafine grain on tensile behaviour and corrosion resistance of the duplex stainless steel.

    Science.gov (United States)

    Jinlong, Lv; Tongxiang, Liang; Chen, Wang; Limin, Dong

    2016-05-01

    The ultrafine grained 2205 duplex stainless steel was obtained by cold rolling and annealing. The tensile properties were investigated at room temperature. Comparing with coarse grained stainless steel, ultrafine grained sample showed higher strength and plasticity. In addition, grain size changed deformation orientation. The strain induced α'-martensite was observed in coarse grained 2205 duplex stainless steel with large strain. However, the grain refinement inhibited the transformation of α'-martensite;nevertheless, more deformation twins improved the strength and plasticity of ultrafine grained 2205 duplex stainless steel. In addition, the grain refinement improved corrosion resistance of the 2205 duplex stainless steel in sodium chloride solution.

  11. Residual stresses and fatigue in a duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Johansson, Johan

    1999-05-01

    Duplex stainless steels, consisting of approximately equal amounts of austenite and ferrite, often combine the best features of austenitic and ferritic stainless steels. They generally have good mechanical properties, including high strength and ductility, and the corrosion resistance is often better than conventional austenitic grades. This has lead to a growing use of duplex stainless steels as a material in mechanically loaded constructions. However, detailed knowledge regarding its mechanical properties and deformation mechanisms are still lacking. In this thesis special emphasis has been placed on the residual stresses and their influence on mechanical behaviour of duplex stainless steels. Due to the difference in coefficient of thermal expansion between the two phases, tensile microstresses are found in the austenitic phase and balancing compressive microstresses in the ferritic phase. The first part of this thesis is a literature survey, which will give an introduction to duplex stainless steels and review the fatigue properties of duplex stainless steels and the influence of residual stresses in two-phase material. The second part concerns the evolution of the residual stress state during uniaxial loading. Initial residual stresses were found to be almost two times higher in the transverse direction compared to the rolling direction. During loading the absolute value of the microstresses increased in the macroscopic elastic regime but started to decrease with increasing load in the macroscopic plastic regime. A significant increase of the microstresses was also found to occur during unloading. Finite element simulations also show stress variation within one phase and a strong influence of both the elastic and plastic anisotropy of the individual phases on the simulated stress state. In the third part, the load sharing between the phases during cyclic loading is studied. X-ray diffraction stress analysis and transmission electron microscopy show that even if

  12. EFFECT OF INTERMETALLIC PHASES ON CORROSION BEHAVIOR AND MECHANICAL PROPERTIES OF DUPLEX STAINLESS STEEL AND SUPER-DUPLEX STAINLESS STEEL

    Directory of Open Access Journals (Sweden)

    Prabhu Paulraj

    2015-08-01

    Full Text Available Duplex Stainless Steels (DSS and Super Duplex Stainless Steel (SDSS have excellent integration of mechanical and corrosion properties. However, the formation of intermetallic phases is a major problem in their usage. The mechanical and corrosion properties are deteriorated due to the presence of intermetallic phases. These phases are induced during welding, prolonged exposure to high temperatures, and improper heat treatments. The main emphasis of this review article is on intermetallic phases and their effects on corrosion and mechanical properties. First the effect of various alloying elements on DSS and SDSS has been discussed followed by formation of various intermetallic phases. The intermetallic phases affect impact toughness and corrosion resistance significantly. Their deleterious effect on weldments has also been reviewed.

  13. FABRICATION OF GD CONTAINING DUPLEX STAINLESS STEEL SHEET FOR NEUTRON ABSORBING STRUCTURAL MATERIALS

    Directory of Open Access Journals (Sweden)

    YONG CHOI

    2013-10-01

    Full Text Available A duplex stainless steel sheet with 1 wt.% gadolinium was fabricated for a neutron absorbing material with high strength, excellent corrosion resistance, and low cost as well as high neutron absorption capability. The microstructure of the as-cast specimen has typical duplex phases including 31% ferrite and 69% austenite. Main alloy elements like chromium (Cr, nickel (Ni, and gadolinium (Gd are relatively uniformly distributed in the matrix. Gadolinium rich precipitates were present in the grains and at the grain boundaries. The solution treatment at 1070 °C for 50 minutes followed by the hot-rolling above 950 °C after keeping the sheet at 1200 °C for 1.5 hours are important points of the optimum condition to produce a 6 mm-thick plate without cracking.

  14. Corrosion resistance properties of sintered duplex stainless steel

    Directory of Open Access Journals (Sweden)

    L.A. Dobrzański

    2006-09-01

    Full Text Available Purpose: of this paper was to examine the corrosion resistance of duplex stainless steels using electrochemical methods in 1M NaCl solution. The influence of powder mixes preparation and cooling cycle after sintering on corrosion properties was evaluated.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the studies behind the preparation of mixes, Schaeffler’s diagram was taken into consideration. Prepared mixes have been compacted at 800 MPa and sintered in a vacuum furnace with argon backfilling at 1260°C for 1 h. After sintering two different cooling cycles were applied: rapid cooling with an average cooling rate of 245 °C/min and slow cooling of 5 °C/min in argon atmosphere. Produced duplex stainless steels have been studied by scanning and optical microscopy and EDS chemical analysis of microstructure components. Corrosion properties have been studied through electrochemical methods in 1M NaCl water solutionFindings: According to achieved results, it was affirmed that applied sintering method as well as powder mixes preparation allows for manufacturing the sintered duplex steels with good corrosion properties which depends on austenite/ferrite ratio in the microstructure and elements partitioning between phases. Corrosion resistance of sintered stainless steels is strictly connected with the density and the pore morphology present in the microstructure too. The highest resistance to pitting corrosion in 1M NaCl solution was achieved for composition with approximate balance of ferrite and austenite in the microstructure.Research limitations/implications: According to the powders characteristic, the applied fast cooling rate seems to be a good compromise for corrosion properties and microstructures, nevertheless further tests should be carried out in

  15. Stress corrosion cracking of duplex stainless steels in caustic solutions

    Science.gov (United States)

    Bhattacharya, Ananya

    Duplex stainless steels (DSS) with roughly equal amount of austenite and ferrite phases are being used in industries such as petrochemical, nuclear, pulp and paper mills, de-salination plants, marine environments, and others. However, many DSS grades have been reported to undergo corrosion and stress corrosion cracking in some aggressive environments such as chlorides and sulfide-containing caustic solutions. Although stress corrosion cracking of duplex stainless steels in chloride solution has been investigated and well documented in the literature but the SCC mechanisms for DSS in caustic solutions were not known. Microstructural changes during fabrication processes affect the overall SCC susceptibility of these steels in caustic solutions. Other environmental factors, like pH of the solution, temperature, and resulting electrochemical potential also influence the SCC susceptibility of duplex stainless steels. In this study, the role of material and environmental parameters on corrosion and stress corrosion cracking of duplex stainless steels in caustic solutions were investigated. Changes in the DSS microstructure by different annealing and aging treatments were characterized in terms of changes in the ratio of austenite and ferrite phases, phase morphology and intermetallic precipitation using optical micrography, SEM, EDS, XRD, nano-indentation and microhardness methods. These samples were then tested for general and localized corrosion susceptibility and SCC to understand the underlying mechanisms of crack initiation and propagation in DSS in the above-mentioned environments. Results showed that the austenite phase in the DSS is more susceptible to crack initiation and propagation in caustic solutions, which is different from that in the low pH chloride environment where the ferrite phase is the more susceptible phase. This study also showed that microstructural changes in duplex stainless steels due to different heat treatments could affect their SCC

  16. Numerical modeling and optimization of machining duplex stainless steels

    Directory of Open Access Journals (Sweden)

    Rastee D. Koyee

    2015-01-01

    Full Text Available The shortcomings of the machining analytical and empirical models in combination with the industry demands have to be fulfilled. A three-dimensional finite element modeling (FEM introduces an attractive alternative to bridge the gap between pure empirical and fundamental scientific quantities, and fulfill the industry needs. However, the challenging aspects which hinder the successful adoption of FEM in the machining sector of manufacturing industry have to be solved first. One of the greatest challenges is the identification of the correct set of machining simulation input parameters. This study presents a new methodology to inversely calculate the input parameters when simulating the machining of standard duplex EN 1.4462 and super duplex EN 1.4410 stainless steels. JMatPro software is first used to model elastic–viscoplastic and physical work material behavior. In order to effectively obtain an optimum set of inversely identified friction coefficients, thermal contact conductance, Cockcroft–Latham critical damage value, percentage reduction in flow stress, and Taylor–Quinney coefficient, Taguchi-VIKOR coupled with Firefly Algorithm Neural Network System is applied. The optimization procedure effectively minimizes the overall differences between the experimentally measured performances such as cutting forces, tool nose temperature and chip thickness, and the numerically obtained ones at any specified cutting condition. The optimum set of input parameter is verified and used for the next step of 3D-FEM application. In the next stage of the study, design of experiments, numerical simulations, and fuzzy rule modeling approaches are employed to optimize types of chip breaker, insert shapes, process conditions, cutting parameters, and tool orientation angles based on many important performances. Through this study, not only a new methodology in defining the optimal set of controllable parameters for turning simulations is introduced, but also

  17. Crack propagation during fatigue in cast duplex stainless steels: influence of the microstructure, of the aging and of the test temperature; Propagation de fissure par fatigue dans les aciers austeno-ferritiques moules: influence de la microstructure, du vieillissement et de la temperature d'essai

    Energy Technology Data Exchange (ETDEWEB)

    Calonne, V

    2001-07-15

    Duplex stainless steels are used as cast components in nuclear power plants. At the service temperature of about 320 C, the ferrite phase is thermally aged and embrittled. This induces a significant decrease in fracture properties of these materials. The aim of this work consists in studying Fatigue Crack Growth Rates (FCGR) and Fatigue Crack Growth Mechanisms (FCGM) as a function of thermal ageing and test temperature (20 C/320 C). Two cast duplex stainless steels (30% ferrite) are tested. In order to better understand the influence of the crystallographic orientation of the phases on the FCGM, the solidification structure of the material is studied by Electron Back-Scatter Diffraction (EBSD) and by Unidirectional Solidification Quenching. Fatigue crack growth tests are also performed in equiaxed and basaltic structures. Microstructure, fatigue crack growth mechanical properties and mechanisms are thus studied in relation to each other. In the studied range of delta K, the crack propagates without any preferential path by successive ruptures of phase laths. The macroscopic crack propagation plane, as determined by EBSD, depends on the crystallographic orientation of the ferrite grain. So, according to the solidification structure, secondary cracks can appear, which in turn influences the FCGR. Fatigue crack closure, which has to be determined to estimate the intrinsic FCGR, decreases with increasing ageing. This can be explained by a decrease in the kinematic cyclic hardening. The Paris exponent as determined from intrinsic FCGR increases with ageing. Intrinsic FCGR can then be separated in two ranges: one with lower FCGR in aged materials than in un-aged and one with the reversed tendency. (author)

  18. The influence of sintering time on the properties of PM duplex stainless steel

    OpenAIRE

    Z. Brytan; L.A. Dobrzański; M. Actis Grande; Rosso, M.

    2009-01-01

    Purpose: The purpose of this paper is to analyse the effect of sintering time on the pore morphology, microstructural changes, tensile properties and corrosion resistance of vacuum sintered duplex stainless steel.Design/methodology/approach: In presented study PM duplex stainless steels were obtained through mixing base ferritic stainless steel powder with controlled addition of elemental alloying powders and then sintered in a vacuum furnace with argon backfilling at 1250°C for different tim...

  19. Cast Stainless Steel Ferrite and Grain Structure

    Energy Technology Data Exchange (ETDEWEB)

    Ruud, Clayton O.; Ramuhalli, Pradeep; Meyer, Ryan M.; Mathews, Royce; Diaz, Aaron A.; Anderson, Michael T.

    2012-09-01

    In-service inspection requirements dictate that piping welds in the primary pressure boundary of light-water reactors be subject to a volumetric examination based on the rules contained within the American Society of Mechanical Engineers Boiler and Pressure Vessel Code, Section XI. The purpose of the inspection is the reliable detection and accurate sizing of service-induced degradation and/or material flaws introduced during fabrication. The volumetric inspection is usually carried out using ultrasonic testing (UT) methods. However, the varied metallurgical macrostructures and microstructures of cast austenitic stainless steel piping and fittings, including statically cast stainless steel and centrifugally cast stainless steel (CCSS), introduce significant variations in the propagation and attenuation of ultrasonic energy. These variations complicate interpretation of the UT responses and may compromise the reliability of UT inspection. A review of the literature indicated that a correlation may exist between the microstructure and the delta ferrite content of the casting alloy. This paper discusses the results of a recent study where the goal was to determine if a correlation existed between measured and/or calculated ferrite content and grain structure in CCSS pipe.

  20. Phase transformations evaluation on a UNS S31803 duplex stainless steel based on nondestructive testing

    Energy Technology Data Exchange (ETDEWEB)

    Macedo Silva, Edgard de, E-mail: edgard@cefetpb.edu.br [Centro federal de Educacao Tecnologica da Paraiba (CEFET PB), Area da Industria, Avenida 1o de Maio, 720 - 58015-430 - Joao Pessoa/PB (Brazil); Costa de Albuquerque, Victor Hugo, E-mail: victor.albuquerque@fe.up.pt [Universidade Federal da Paraiba (UFPB), Departamento de Engenharia Mecanica (DEM), Cidade Universitaria, S/N - 58059-900 - Joao Pessoa/PB (Brazil); Pereira Leite, Josinaldo, E-mail: josinaldo@ct.ufpb.br [Universidade Federal da Paraiba (UFPB), Departamento de Engenharia Mecanica (DEM), Cidade Universitaria, S/N - 58059-900 - Joao Pessoa/PB (Brazil); Gomes Varela, Antonio Carlos, E-mail: varela@cefetpb.edu.br [Universidade Federal da Paraiba (UFPB), Departamento de Engenharia Mecanica (DEM), Cidade Universitaria, S/N - 58059-900 - Joao Pessoa/PB (Brazil); Pinho de Moura, Elineudo, E-mail: elineudo@pq.cnpq.br [Universidade Federal do Ceara (UFC), Departamento de Engenharia Metalurgica e de Materiais, Campus do Pici, Bloco 715, 60455-760 - Fortaleza/CE (Brazil); Tavares, Joao Manuel R.S., E-mail: tavares@fe.up.pt [Faculdade de Engenharia da Universidade do Porto (FEUP), Departamento de Engenharia Mecanica e Gestao Industrial (DEMEGI)/Instituto de Engenharia Mecanica e Gestao Industrial - INEGI, Rua Dr. Roberto Frias, s/n, 4200-465 Porto (Portugal)

    2009-08-15

    Duplex stainless steel presents special mechanical properties such as, for example, mechanical and corrosion strength, becoming competitive in relation to the other types of stainless steel. One of the great problems of duplex stainless steel microstructural changes study is related to embrittlement above 300 deg. C, with the precipitation of the {alpha}' phase occurring over the ferritic microstructure. Aiming to characterise embrittlement of duplex stainless steel, hardening kinetics, from 425 to 475 deg. C, was analysed through the speed of sound, Charpy impact energy, X-ray diffraction, hardness and microscopy parameters. The presence of two hardening stages, detected through the speed of sound, was observed, one being of brittle characteristic and the other ductile. Moreover, the speed of sound showed a direct correlation with the material's hardness. Thus, it is concluded that the speed of sound is a promising nondestructive parameter to follow-up embrittlement in duplex stainless steel.

  1. Phase Transformation in Cast Superaustenitic Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Lee Phillips, Nathaniel Steven [Iowa State Univ., Ames, IA (United States)

    2006-01-01

    Superaustenitic stainless steels constitute a group of Fe-based alloys that are compositionally balanced to have a purely austenitic matrix and exhibit favorable pitting and crevice corrosion resistant properties and mechanical strength. However, intermetallic precipitates such as sigma and Laves can form during casting or exposure to high-temperature processing, which degrade the corrosion and mechanical properties of the material. The goal of this study was to accurately characterize the solid-solid phase transformations seen in cast superaustenitic stainless steels. Heat treatments were performed to understand the time and temperature ranges for intermetallic phase formations in alloys CN3MN and CK3MCuN. Microstructures were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy and wavelength dispersive spectroscopy (EDS, WDS). The equilibrium microstructures, composed primarily of sigma and Laves within purely austenitic matrices, showed slow transformation kinetics. Factors that determine the extent of transformation, including diffusion, nucleation, and growth, are discussed.

  2. Electromagnetic non-destructive technique for duplex stainless steel characterization

    Science.gov (United States)

    Rocha, João Vicente; Camerini, Cesar; Pereira, Gabriela

    2016-02-01

    Duplex stainless steel (DSS) is a two-phase (ferrite and austenite) material, which exhibits an attractive combination of mechanical properties and high corrosion resistance, being commonly employed for equipment of petrochemical plants, refining units and oil & gas platforms. The best properties of DSS are achieved when the phases are in equal proportions. However, exposition to high temperatures (e.g. welding process) may entail undesired consequences, such as deleterious phases precipitation (e.g. sigma, chi) and different proportion of the original phases, impairing dramatically the mechanical and corrosion properties of the material. A detailed study of the magnetic behavior of DSS microstructure with different ferrite austenite ratios and deleterious phases content was accomplished. The non destructive method evaluates the electromagnetic properties changes in the material and is capable to identify the presence of deleterious phases into DSS microstructure.

  3. Corrosion and Wear Properties of Cold Rolled 0.087% Gd Lean Duplex Stainless Steels for Neutron Absorbing Material

    Directory of Open Access Journals (Sweden)

    Yong Choi

    2016-02-01

    Full Text Available Lean duplex stainless steels with 0.087 wt.% gadolinium (Gd were inert arc-melted and cast in molds of size 10 mm × 10 mm × 20 mm. The micro-hardnesses of the rolling direction (RD, transverse direction (TD and short transverse (ST direction were 258.5 HV, 292.3 HV, and 314.7 HV, respectively. A 33% cold rolled specimen had the crystallographic texture that (100 pole was mainly concentrated to the normal direction (ND and (110 pole was concentrated in the center of ND and RD. The corrosion potential and corrosion rate in artificial seawater and 0.1M H2SO4 solution were in the range of 105.6–221.6 mVSHE, 0.59–1.06 mA/cm2, and 4.75–8.25 mVSHE, 0.69–1.68 mA/cm2, respectively. The friction coefficient and wear loss of the 0.087 w/o Gd-lean duplex stainless steels in artificial seawater were about 67% and 65% lower than in air, whereas the wear efficiency was 22% higher. The corrosion and wear behaviors of the 0.087 w/o Gd-lean duplex stainless steels significantly depended on the Gd phases.

  4. Hot Forging of Nitrogen Alloyed Duplex Stainless Steels

    Institute of Scientific and Technical Information of China (English)

    P.Chandramohan; S.S. Mohamed Nazirudeen; S.S. Ramakrishnan

    2007-01-01

    Duplex stainless steels are gaining global importance because of the need for a high strength corrosion resistant material. Three compositions of this group were selected with three different nitrogen contents viz, 0.15 wt pct (alloy 1), 0.23 wt pct (alloy 2) and 0.32 wt pct (alloy 3). The steels were melted in a high frequency induction furnace and hot forged to various reductions from 16% to 62%. In this work, the effect of hot forging on the ferrite content, hardness, yield strength, impact strength and grain orientation (texture) were studied. Fracture analysis on all the forged specimens using SEM reveals that a size reduction of 48% results in maximum ductility and impact strength as well as minimal ferrite content and grain size. Thus the mechanical properties are found to have a direct correlation to ferrite content and grain size. The highest impact strength was observed in specimens with the smallest grain size, which was observed in specimens forged to 48% reduction in size.

  5. Carburizing of Duplex Stainless Steel (DSS) Under Compression Superplastic Deformation

    Science.gov (United States)

    Ahamad, Nor Wahida; Jauhari, Iswadi

    2012-12-01

    A new surface carburizing technique which combines superplastic deformation with superplastic carburizing (SPC) is introduced. SPC was conducted on duplex stainless steel under compression mode at a fixed 0.5 height reduction strain rates ranging from 6.25 × 10-5 to 1 × 10-3 s-1 and temperature ranging from 1173 K to 1248 K (900 °C to 975 °C). The results are compared with those from conventional and non-superplastic carburizing. The results show that thick hard carburized layers are formed at a much faster rate compared with the other two processes. A more gradual hardness transition from the surface to the substrate is also obtained. The highest carburized layer thickness and surface hardness are attained under SPC process at 1248 K (975 °C) and 6.25 × 10-5 s-1 with a value of (218.3 ± 0.5) μm and (1581.0 ± 5.0) HV respectively. Other than that, SPC also has the highest scratch resistance.

  6. Tooling solutions for sheet metal forming and punching of lean duplex stainless steel

    DEFF Research Database (Denmark)

    Wadman, Boel; Madsen, Erik; Bay, Niels

    2012-01-01

    .4509 and lean duplex EN1.4162 in a production designed for austenitic stainless steels, such as EN1.4301 and 1.4401. The result is a guideline that summarizes how stainless material properties may affect tool degradation, and suggests tool solutions for reduced production disturbances and tool maintenance cost.......For producers of advanced stainless components the choice of stainless material influences not only the product properties, but also the tooling solution for sheet metal stamping. This work describes how forming and punching tools will be affected when introducing the stainless alloys ferritic EN1...

  7. Characterization of microstructure and texture across dissimilar super duplex/austenitic stainless steel weldment joint by super duplex filler metal

    Energy Technology Data Exchange (ETDEWEB)

    Eghlimi, Abbas, E-mail: a.eghlimi@ma.iut.ac.ir [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Shamanian, Morteza [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Eskandarian, Masoomeh [Department of Materials Engineering, Shiraz University, Shiraz 71348-51154 (Iran, Islamic Republic of); Zabolian, Azam [Department of Natural Resources, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Szpunar, Jerzy A. [Department of Mechanical Engineering, University of Saskatchewan, Saskatoon SK S7N 5A9 (Canada)

    2015-08-15

    In the present paper, microstructural changes across an as-welded dissimilar austenitic/duplex stainless steel couple welded by a super duplex stainless steel filler metal using gas tungsten arc welding process is characterized with optical microscopy and electron back-scattered diffraction techniques. Accordingly, variations of microstructure, texture, and grain boundary character distribution of base metals, heat affected zones, and weld metal were investigated. The results showed that the weld metal, which was composed of Widmanstätten austenite side-plates and allotriomorphic grain boundary austenite morphologies, had the weakest texture and was dominated by low angle boundaries. The welding process increased the ferrite content but decreased the texture intensity at the heat affected zone of the super duplex stainless steel base metal. In addition, through partial ferritization, it changed the morphology of elongated grains of the rolled microstructure to twinned partially transformed austenite plateaus scattered between ferrite textured colonies. However, the texture of the austenitic stainless steel heat affected zone was strengthened via encouraging recrystallization and formation of annealing twins. At both interfaces, an increase in the special character coincident site lattice boundaries of the primary phase as well as a strong texture with <100> orientation, mainly of Goss component, was observed. - Graphical abstract: Display Omitted - Highlights: • Weld metal showed local orientation at microscale but random texture at macroscale. • Intensification of <100> orientated grains was observed adjacent to the fusion lines. • The austenite texture was weaker than that of the ferrite in all duplex regions. • Welding caused twinned partially transformed austenites to form at SDSS HAZ. • At both interfaces, the ratio of special CSL boundaries of the primary phase increased.

  8. Effect of Temperature and Cl-Concentration on Pitting of 2205 Duplex Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    DONG Chaofang; LUO Hong; XIAO Kui; SUN Ting; LIU Qian; LI Xiaogang

    2011-01-01

    The electrochemical behaviors of 2205 duplex stainless steel in NaCl solution with different temperatures and concentrations were studied by gravimetric tests,potentiodynamic polarization,electrochemical impedance spectroscopy and scanning electron microscopy.The experimental results show that temperature and chloride concentration have a great influence on the pitting resistance of 2205 duplex stainless steels.They not only effect the corrosion rate of pitting,but also change the shape of the pits.When NaCl solution was in low concentration and temperature below the critical pitting temperature,pits were very small and scattered with hemisphere-like shape.On the contrary,the pits of 2205 duplex stainless steel were large and sometimes had a lacy cover when the NaCl concentration was higher and the temperature was 70℃.

  9. SIMULATION OF THE TWIN ROLL STAINLESS STRIP CASTING PROCESS

    Institute of Scientific and Technical Information of China (English)

    Y.C. Miao; X.M. Zhang; G.D. Wang; H.S. Di; X.H. Liu

    2001-01-01

    The position of the solidification completed temperature of twin roll stainless strip casting process is very important to the quality of the casting strip. In order to control this position, the solidification completed temperature should be known at first.The present paper first simulated dendritic microsegregation under conditions of twin roll stainless strip casting, and got the relationship between the temperature and solid fraction of the mush zone. The temperatures such as ZDT (equal to the solidification completed temperature) and LIT (liquid impenetrable temperature), et al., also were obtained. Then by using the turbulent model, the flow and thermal fields of the pool of the twin roll stainless strip casting, and the speed and temperature fields of different casting speeds were given and also explained. The results are coincident with the experimental result. Combined with the results of these two simulations. the appropriated casting speed was found.

  10. Influence Of Heat Treatment On Duplex Stainless Steel To Study The Material Properties

    Directory of Open Access Journals (Sweden)

    Jithin M

    2015-02-01

    Full Text Available Abstract The various heat treatment processes are annealing normalizing hardening tempering spheroidising surface hardening flame and induction hardening nitriding cyaniding carbonitriding carburizing etc Heat treatment on duplex stainless steel is to improve ductility toughness strength hardness and to relieve internal stress developed in the material. Here basically the experiment of hardness test impact test wear test and compression is done to get idea about heat treated duplex stainless steel which has extensive uses in all industries and scientific research and development fields.

  11. Characterization of duplex stainless steel weld metals obtained by hybrid plasma-gas metal arc welding

    Directory of Open Access Journals (Sweden)

    Koray Yurtisik

    2013-09-01

    Full Text Available Despite its high efficiency, autogenous keyhole welding is not well-accepted for duplex stainless steels because it causes excessive ferrite in as-welded duplex microstructure, which leads to a degradation in toughness and corrosion properties of the material. Combining the deep penetration characteristics of plasma arc welding in keyhole mode and metal deposition capability of gas metal arc welding, hybrid plasma - gas metal arc welding process has considered for providing a proper duplex microstructure without compromising the welding efficiency. 11.1 mm-thick standard duplex stainless steel plates were joined in a single-pass using this novel technique. Same plates were also subjected to conventional gas metal arc and plasma arc welding processes, providing benchmarks for the investigation of the weldability of the material. In the first place, the hybrid welding process enabled us to achieve less heat input compared to gas metal arc welding. Consequently, the precipitation of secondary phases, which are known to be detrimental to the toughness and corrosion resistance of duplex stainless steels, was significantly suppressed in both fusion and heat affected zones. Secondly, contrary to other keyhole techniques, proper cooling time and weld metal chemistry were achieved during the process, facilitating sufficient reconstructive transformation of austenite in the ferrite phase.

  12. Yield stress of duplex stainless steel specimens estimated using a compound Hall–Petch equation

    Directory of Open Access Journals (Sweden)

    Noriaki Hirota, Fuxing Yin, Tsukasa Azuma and Tadanobu Inoue

    2010-01-01

    Full Text Available In this study, the 0.2% yield stress of duplex stainless steel was evaluated using a compound Hall–Petch equation. The compound Hall–Petch equation was derived from four types of duplex stainless steel, which contained 0.2–64.4 wt% δ-ferrite phase, had different chemical compositions and were annealed at different temperatures. Intragranular yield stress was measured with an ultra-microhardness tester and evaluated with the yield stress model proposed by Dao et al. Grain size, volume fraction and texture were monitored by electron backscattering diffraction measurement. The kγ constant in the compound equation for duplex stainless steel agrees well with that for γ-phase SUS316L steel in the temperature range of 1323–1473 K. The derived compound Hall–Petch equation predicts that the yield stress will be in good agreement with the experimental results for the Cr, Mn, Si, Ni and N solid-solution states. We find that the intragranular yield stress of the δ-phase of duplex stainless steel is rather sensitive to the chemical composition and annealing conditions, which is attributed to the size misfit parameter.

  13. Low-Temperature Mechanical Behavior of Super Duplex Stainless Steel with Sigma Precipitation

    Directory of Open Access Journals (Sweden)

    Seul-Kee Kim

    2015-09-01

    Full Text Available Experimental studies in various aspects have to be conducted to maintain stable applications of super duplex stainless steels (SDSS because the occurrence rate of sigma phase, variable temperature and growth direction of sigma phase can influence mechanical performances of SDSS. Tensile tests of precipitated SDSS were performed under various temperatures to analyze mechanical and morphological behavior.

  14. Effect of Deleterious Phases on Corrosion Resistance of Duplex Stainless Steel (2205

    Directory of Open Access Journals (Sweden)

    AbdulKadar M. Godil

    2013-07-01

    Full Text Available Duplex stainless steel is a Ferritic(BCC-Austenitic(FCC steel, covers the advantages of both Austenitic and Ferritic Stainless steels. They having good mechanical and corrosion resistance properties are widely used in many industries like chemical plants, refineries for critical equipments such as pressure vessels, heatexchangers, water heaters. Major problem occurs with duplex steels when they are worked or heated above about temperature of 280°C. Detrimental phases like Sigma, Chi, Laves and Alpha prime form when the Duplex steels are treated above this temperature and they retard the properties of Duplex stainless steels. They also cause embrittlement above temperature of 475°C called “475°C embrittlement”. During welding of duplex steels, Secondary austenite also forms, which is also one of the harmful phases in duplex steels. Among all of these phases, Sigma (σ is extremely harmful to the corrosion resistance of steel. Due to these limitations duplexgrades are not used above certain temperature ranges. In this experimental work a plate of duplex grade 2205 in hot worked condition was procured from TCR Advanced Engineering Pvt. Ltd., GIDC, Vadodara. Initially chemical composition of the plate was checked with emission spectrometer, tensile test and hardness tests werecarried out for comparing with the standard data. As there was no Sigma phase detected when tested with ASTM 930 in the received sample, Sigma phase was intentionally produced by giving heat treatment in the range of 700-850°C. Sigma phases were quantified with ASTM 930 practice A, by electrolytic etching with 40% NaOH. The effect of Sigma phase on corrosion resistance was measured by ASTM G48. The pitting corrosion resistance was evaluated in terms of average pit depth and overall corrosion rate.

  15. Experimental Study of the Thermal Diffusivity and Heat Capacity Concerning Some Duplex Stainless Steel

    Directory of Open Access Journals (Sweden)

    Riad Harwill Abdul Abas

    2015-06-01

    Full Text Available In the present work, thermal diffusivity and heat capacity measurements have been investigated in temperature range between RT and 1473 K for different duplex stainless steel supplied by Outokumpu Stainless AB, Sweden. The purpose of this study is to get a reliable thermophysical data of these alloys and to study the effect of microstructure on the thermal diffusivity and heat capacity value. Results show the ferrite content in the duplex stainless steel increased with temperature at equilibrium state. On the other hand, ferrite content increased with increasing Cr/Ni ratio and there is no significant effect of ferrite content on the thermal diffusivity value at room temperature. Furthermore, the heat capacity of all samples increases with temperature from room temperature to 473 K, while it decreases with increasing temperature until 1073 K. Then it increases with temperature at higher temperature. Curie temperature and sigma phase formation temperature can be detected by heat capacity-temperature curves.

  16. Towards economic design of a pressure vessel made of duplex stainless steel

    OpenAIRE

    Veljkovic, Milan, ed. lit.; Gozzi, Jonas

    2005-01-01

    The feasibility of manufacturing pressure vessels from duplex stainless steel (grade EN 1.4462, duplex 2205: 0.02%C, 22%Cr, 5.7%Ni, 3.1%Mo, 0.17%N) was evaluated by measurements of the mechanical properties of the parent metal and welds, and by finite element modelling. The tensile stress-strain properties of 4 mm sheet, and of the weld metal and the HAZ were measured in the transverse and rolling directions. Behaviour under biaxial stress was studied by pressurising circular sheet specimens ...

  17. Characterization of Solidification and Solid State Transformation in Duplex Cast Steel: Thermo-Calc Investigation

    OpenAIRE

    2007-01-01

    The paper presents a characteristic of solidification process and changes occurring in the solid state in a duplex cast steel. Theoretical chemical composition of individual phases, its changes during solidification and cooling after solidification and also changes in volume fractions of phases versus temperature have been determined. Theoretical results of Thermo-Calc analysis have been correlated with the microstructure of as-cast cast steel as well as with analysis of chemical composition ...

  18. Paraequilibrium Carburization of Duplex and Ferritic Stainless Steels

    Science.gov (United States)

    Michal, G. M.; Gu, X.; Jennings, W. D.; Kahn, H.; Ernst, F.; Heuer, A. H.

    2009-08-01

    AISI 301 and E-BRITE stainless steels were subjected to low-temperature (743 K) carburization experiments using a commercial technology developed for carburization of 316 austenitic stainless steels. The AISI 301 steel contained ~40 vol pct ferrite before carburization but had a fully austenitic hardened case, ~20- μm thick, and a surface carbon concentration of ~8 at. pct after treatment; this “colossal” paraequilibrium carbon supersaturation caused an increase in lattice parameter of ~3 pct. The E-BRITE also developed a hardened case, 12- to 18- μm thick, but underwent a more modest (~0.3 pct) increase in lattice parameter; the surface carbon concentration was ~10 at. pct. While the hardened case on the AISI 301 stainless steel appeared to be single-phase austenite, evidence for carbide formation was apparent in X-ray diffractometer (XRD) scans of the E-BRITE. Paraequilibrium phase diagrams were calculated for both AISI 301 and E-BRITE stainless steels using a CALPHAD compound energy-based interstitial solid solution model. In the low-temperature regime of interest, and based upon measured paraequilibrium carbon solubilities, more negative Cr-carbon interaction parameters for austenite than those in the current CALPHAD data base may be appropriate. A sensitivity analysis involving Cr-carbon interaction parameters for ferrite found a strong dependence of carbon solubility on relatively small changes in the magnitude of these parameters.

  19. Influence of surface texture on the galling characteristics of lean duplex and austenitic stainless steels

    DEFF Research Database (Denmark)

    Wadman, Boel; Eriksen, J.; Olsson, M.;

    2010-01-01

    of sheet materials and lubricants. The strip reduction test, a severe sheet forming tribology test was used to simulate the conditions during ironing. This investigation shows that the risk of galling is highly dependent on the surface texture of the duplex steel. Trials were also performed......Two simulative test methods were used to study galling in sheet forming of two types of stainless steel sheet: austenitic (EN 1.4301) and lean duplex LDX 2101 (EN 1.4162) in different surface conditions. The pin-on-disc test was used to analyse the galling resistance of different combinations...... in an industrial tool used for high volume production of pump components, to compare forming of LDX 2101 and austenitic stainless steel with equal thickness. The forming forces, the geometry and the strains in the sheet material were compared for the same component. It was found that LDX steels can be formed...

  20. Eddy Current Transducer Dedicated for Sigma Phase Evaluation in Duplex Stainless Steel

    Directory of Open Access Journals (Sweden)

    Grzegorz Psuj

    2012-01-01

    Full Text Available The paper describes a new transducer dedicated for evaluation of a duplex stainless steel (DSS. Different phases which exist in DSS have influence on mechanical as well as on electrical properties. Therefore, an eddy current transducer was utilized. In order to achieve high sensitivity, a differential type of the transducer was selected. The performance of the transducer was verified by utilizing the samples which had a different amount of sigma phase.

  1. Relationship between microstructure and fracture types in a UNS S32205 duplex stainless steel

    Directory of Open Access Journals (Sweden)

    Maria Victoria Biezma

    2013-01-01

    Full Text Available Duplex stainless steels are susceptible to the formation of sigma phase at high temperature which could potentially be responsible for catastrophic service failure of components. Thermal treatments were applied to duplex stainless steels in order to promote the precipitation of different fractions of sigma phase into a ferrite-austenite microstructure. Quantitative image analysis was employed to characterize the microstructure and Charpy impact tests were used in order to evaluate the mechanical degradation caused by sigma phase presence. The fracture morphology of the Charpy test specimens were thoroughly observed in SEM, looking for a correlation between the microstructure and the fracture types in UNS S32205 duplex stainless steel. The main conclusion is the strong embrittlement effect of sigma phase since it is possible to observe a transition from transgranular fracture to intergranular fracture as increases the percentage of sigma phase. Thus, the mixed modes of fracture are predominant in the present study with high dependence on sigma phase percentages obtained by different thermal treatments.

  2. Ultrasonic Characterization And Micro-Structural Studies On 2205 Duplex Stainless Steel In Thermal Variations

    Directory of Open Access Journals (Sweden)

    Bernice Victoria

    2015-08-01

    Full Text Available Abstract Due to increasing concern on potential impact of materials on human health and environment the materials used in hygienic applications should be durable corrosion resistant clean surface etc. Type 2205 duplex stainless steel is a preferred material for use in biomedical pharmaceutical nuclear pressure vessels chemical tankers etc. it exhibits good mechanical strength and high resistance to corrosion. The strength toughness hardness of such materials are usually determined by destructive tests. However continuous destructive measurements are generally difficult to perform during the productive process which creates a need for a fast and easy nondestructive method of material characterization. Microstructural changes in duplex stainless steel due to changes in annealing temperature are characterized by ultrasonic pulse echo technique and optical microscopy. Type 2205 duplex stainless steel are heat treated at 1000 deg C 1050 deg C 1100 deg C 1150 deg C and 1200 deg C for 15 min and water quenched. There is an appreciable change in the morphology of all the heat treated samples and the ultrasonic velocity is dependent on both ferrite and austenite ratio and the grain size.

  3. Microstructure analysis of AISI 304 stainless steel produced by twin-roll thin strip casting process

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The microstructure of AISI 304 austenite stainless steel fabricated by the thin strip casting process were investigated using optical microscope, scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD).The microstructures of the casting strips show a duplex structure consisting of delta ferrite and austenite. The volume fraction of the delta ferrite is about 9.74vol% at the center and 6.77vol% at the surface of the casting thin strip, in vermicular and band shapes. On account of rapid cooling and solidification in the continuous casting process, many kinds of inclusions and precipitates have been found. Most of the inclusions and precipitates are spherical complex compounds consisting of oxides, such as, SiO2, MnO, Al2O3,Cr2O3,and FeO or their multiplicity oxides of MnO·Al2O3,2FeO·SiO2, and 2MnO·SiO2. Many defects including dislocations and stacking faults have also formed during the rapid cooling and solidification process, which is helpful to improve the mechanical properties of the casting strips.

  4. Duplex stainless steel surface bay laser cladding; Modificacion de las propiedades superficiales de aceros inoxidables Duplex mediante recubrimientos por laser

    Energy Technology Data Exchange (ETDEWEB)

    Amigo, V.; Pineda, Y.; Segovia, F.; Vicente, A.

    2004-07-01

    Laser cladding is one of the most promising techniques to restore damaged surfaces and achieve properties similar to those of the base metal. In this work, duplex stainless steels have been cladded by a nickel alloy under different processing conditions. The influence of the beam speed and defocusing variables ha been evaluated in the microstructure both of the cladding and heat affected zone, HAZ. These results have been correlated to mechanical properties by means of microhardness measurements from cladding area to base metal through the interface. This technique has shown to be very appropriate to obtain controlled mechanical properties as they are determined by the solidification microstructure, originated by the transfer of mass and heat in the system. (Author) 21 refs.

  5. Passivation of duplex stainless steel in solutions simulating chloride-contaminated concrete

    Directory of Open Access Journals (Sweden)

    Takenouti, H.

    2007-12-01

    Full Text Available Most studies published to date on the corrosion behaviour of stainless reinforcing steel are based on austenitic steel. The market presence of corrugated duplex steel is growing, however. The present study compared passivity in 2205 type duplex and 304 type austenitic stainless steel. Polarization tests in chloride-containing Ca(OH2 solutions confirmed the exceptional performance of duplex steels. X-ray photoelectronic spectroscopy (XPS showed that the passive layer generated on duplex stainless steel in media simulating concrete pore solutions had a higher Cr content than the layer formed on steel in contact with the air. The XPS results also revealed that in duplex steel the form adopted by the passive layer Fe oxides was Fe3O4 in the solutions simulating concrete, rather than Fe2O3, as in duplex steel exposed to air. Electrochemical impedance spectroscopy (EIS can be used to monitor the transformations taking place in the passive layer and analyze the factors involved.La mayoría de los estudios publicados hasta el momento sobre el comportamiento frente a la corrosión de armaduras de acero inoxidable se basan en aceros austeníticos. Sin embargo, la presencia en el mercado de aceros corrugados dúplex es cada vez más importante. En este trabajo se analiza la pasividad de un acero inoxidable dúplex tipo 2205 en comparación con la de un inoxidable austenítico tipo 304. Los ensayos de polarización en disoluciones de Ca(OH2 con cloruros confirman el excepcional comportamiento de los aceros dúplex. La espectroscopía fotoelectrónica de rayos X (XPS informa de que la capa pasiva generada en aceros inoxidables dúplex en medios que simulan la disolución de los poros del hormigón posee mayor contenido en óxidos de Cr que la formada en aire. También se puede deducir de los resultados de XPS que los óxidos de Fe de la capa pasiva de los aceros dúplex se encuentran en forma de Fe3O4 en las disoluciones que simulan el hormigón en vez de en

  6. Significance of the  phase for the erosive wear process of the duplex cast steel

    Directory of Open Access Journals (Sweden)

    Z. Stradomski

    2008-10-01

    Full Text Available The work presents a possibility of increasing the tribological properties of the ferritic-austenitic cast steel (the so called duplex cast steel of GX2CrNiMoCu25-6-3-3 grade by taking an advantage of the mechanism of precipitation strengthening with the σ phase arisen due to the eutectoidal ferrite decomposition. The examinations have been held using specimens cut out of both a massive casting (an impeller of about one-ton mass and a thin-walled casting (of the wall thickness about 2 mm. The huge impeller has been made of cast steel containing 0.09% of carbon (i.e. exceeding the demands of the current standard, while the thin-walled casting has been of cast steel withextremely low carbon content (0.024% due to applying the input material of a great purity. Employing the moulding material withalkaline phenolic binder hardened with CO2 and using the zirconia coating has allowed for achieving about 20% fraction of σ phase in the as-cast state of the casting. An increase in σ phase fraction in the structure of duplex cast steel results in improving the abrasive wear resistance of the material. It should be stressed that despite the high fraction of the σ phase in the material, the crack-free castings have been obtained. An addition of copper has made possible producing the high-quality thin-walled (as for cast steel castings of smoothsurfaces. No defects (including shrinkage porosity have been found.

  7. Development of Cast Alumina-Forming Austenitic Stainless Steels

    Science.gov (United States)

    Muralidharan, G.; Yamamoto, Y.; Brady, M. P.; Walker, L. R.; Meyer, H. M., III; Leonard, D. N.

    2016-09-01

    Cast Fe-Ni-Cr chromia-forming austenitic stainless steels with Ni levels up to 45 wt.% are used at high temperatures in a wide range of industrial applications that demand microstructural stability, corrosion resistance, and creep strength. Although alumina scales offer better corrosion protection at these temperatures, designing cast austenitic alloys that form a stable alumina scale and achieve creep strength comparable to existing cast chromia-forming alloys is challenging. This work outlines the development of cast Fe-Ni-Cr-Al austenitic stainless steels containing about 25 wt.% Ni with good creep strength and the ability to form a protective alumina scale for use at temperatures up to 800-850°C in H2O-, S-, and C-containing environments. Creep properties of the best alloy were comparable to that of HK-type cast chromia-forming alloys along with improved oxidation resistance typical of alumina-forming alloys. Challenges in the design of cast alloys and a potential path to increasing the temperature capability are discussed.

  8. Development of Cast Alumina-Forming Austenitic Stainless Steels

    Science.gov (United States)

    Muralidharan, G.; Yamamoto, Y.; Brady, M. P.; Walker, L. R.; Meyer, H. M., III; Leonard, D. N.

    2016-11-01

    Cast Fe-Ni-Cr chromia-forming austenitic stainless steels with Ni levels up to 45 wt.% are used at high temperatures in a wide range of industrial applications that demand microstructural stability, corrosion resistance, and creep strength. Although alumina scales offer better corrosion protection at these temperatures, designing cast austenitic alloys that form a stable alumina scale and achieve creep strength comparable to existing cast chromia-forming alloys is challenging. This work outlines the development of cast Fe-Ni-Cr-Al austenitic stainless steels containing about 25 wt.% Ni with good creep strength and the ability to form a protective alumina scale for use at temperatures up to 800-850°C in H2O-, S-, and C-containing environments. Creep properties of the best alloy were comparable to that of HK-type cast chromia-forming alloys along with improved oxidation resistance typical of alumina-forming alloys. Challenges in the design of cast alloys and a potential path to increasing the temperature capability are discussed.

  9. Microstructure and mechanical properties of duplex stainless steel subjected to hydrostatic extrusion

    Energy Technology Data Exchange (ETDEWEB)

    Maj, P., E-mail: Piotr.maj@inmat.pw.edu.pl [Faculty of Materials Science and Engineering, Warsaw University of Technology, Wołoska 141, 02-507 Warsaw (Poland); Adamczyk-Cieślak, B.; Mizera, J. [Faculty of Materials Science and Engineering, Warsaw University of Technology, Wołoska 141, 02-507 Warsaw (Poland); Pachla, W. [High Pressure Research Center, Polish Academy of Sciences, Sokołowska 29, 01-142 Warsaw (Poland); Kurzydłowski, K.J. [Faculty of Materials Science and Engineering, Warsaw University of Technology, Wołoska 141, 02-507 Warsaw (Poland)

    2014-07-01

    The nanostructure and mechanical properties of ferritic-austenitic duplex stainless steel subjected to hydrostatic extrusion were examined. The refinement of the structure in the initial state and in the two deformation states (ε = 1.4 and ε = 3.8) was observed in an optical microscope (OM) and a transmission electron microscope (TEM). The results indicate that the structure evolved from microcrystalline with a grain size of about 4 μm to nanocrystalline with a grain size of about 150 nm in ferrite and 70 nm in austenite. The material was characterized mechanically by tensile tests performed in the two deformation states. The ultimate strength appeared to increase significantly compared to that in the initial deformation stages, which can be attributed to the grain refinement and plastic deformation. The heterogeneity observed in microregions results from the dual-phase structure of the steel. The results indicate that hydrostatic extrusion is a highly potential technology suitable for improving the properties of duplex steels. - Highlights: • Duplex stainless steel was hydro extruded to a total strain of 3.8 • After the last stage of deformation heterogeneous structure was obtained in the material • As a result of stresses non-diffusive transformation γ→α’ occurred in the material • Nanometric (sub)grains were obtained in the austenite regions.

  10. Some pitfalls in welding of duplex stainless steels Algumas armadilhas na soldagem de aços inoxidáveis duplex

    Directory of Open Access Journals (Sweden)

    Demian J. Kotecki

    2010-12-01

    Full Text Available Duplex stainless steels (DSS, including super duplex stainless steels {SDSS} have proven to be very useful engineering materials, albeit with somewhat different welding requirements than those of the more familiar austenitic stainless steels. Despite a generally good track record in welding of duplex stainless steels, certain pitfalls have been encountered with enough frequency that they deserve review. Inappropriate base metal specification often leads to unsuitable heat affected zone (HAZ properties. Autogenous fusion zones are also of concern. This issue centers around nitrogen limits. The most frequently encountered is applying the UNS S31803 composition for 2205 DSS, instead of the S32205 composition. Inappropriate welding heat input arises most frequently with SDSS. While 0.5 to 1.5 kJ/mm is a normal heat input recommendation for SDSS, either a root pass or many small beads towards the low end of this heat input range tends to result in precipitation and/or secondary austenite formation in weld metal subjected to repeated thermal cycles from multiple weld passes. Inappropriate PWHT occurs when the enhanced nickel filler metals (typically 9% Ni are used. DSS are not normally given PWHT, but extensive forming of heads, for example, or repair welding of castings, may require a postweld anneal. Specifications such as ASTM A790 and A890 call for annealing at 1040ºC minimum, and the fabricator tends to use temperatures close to that minimum. However, the enhanced nickel filler metals require higher temperatures to dissolve sigma phase that forms during heating to the annealing temperature.Aços inoxidáveis duplex (AID, incluindo os aços super duplex, AISD provaram ser materiais de engenharia muito úteis, embora com requerimentos de soldagem em alguma medida diferentes daqueles dos aços inoxidáveis austeníticos mais usuais. Apesar do histórico geralmente bom dos aços inoxidáveis duplex quanto a soldagem, algumas dificuldades têm sido

  11. Use of a gray level co-occurrence matrix to characterize duplex stainless steel phases microstructure

    Directory of Open Access Journals (Sweden)

    L. Zortea

    2011-04-01

    Full Text Available Duplex stainless steels are widely used in industry. This is due to their higher strength compared to austenitic steels and to their higher toughness than ferritic steels. They also have good weldability and high resistance to stress corrosion cracking.These steels are characterized by two-phase microstructures composed by almost the same level of ferrite and austenite.Duplex steel 2205 samples evaluated are: as received, cold rolled (33% and heat-treated at 800°C for 10 hours.A metallographic etching with 10% oxalic acid has been carried out to highlight the phases morphology. Some photos have been taken by SEM microscope and submitted to image analysis. The analysis carried out is based on the determination of co-occurrence matrix and on the following interpretation of appropriate indicators. Through these indicators is possible to estimate the features of images objectively.

  12. Effect of laser shock processing on fatigue crack growth of duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Rubio-Gonzalez, C., E-mail: crubio@cidesi.mx [Centro de Ingenieria y Desarrollo Industrial, Pie de la Cuesta, 702, Desarrollo San Pablo, Queretaro, Qro., 76130 (Mexico); Felix-Martinez, C. [Centro de Ingenieria y Desarrollo Industrial, Pie de la Cuesta, 702, Desarrollo San Pablo, Queretaro, Qro., 76130 (Mexico); Gomez-Rosas, G. [Universidad de Guadalajara, Guadalajara, Jal (Mexico); Ocana, J.L.; Morales, M.; Porro, J.A. [Departamento de Fisica Aplicada a la Ingenieria Industrial, E.T.S.I.I., Universidad Politecnica de Madrid (Spain)

    2011-01-25

    Research highlights: {yields} LSP is an effective surface treatment to improve fatigue properties of duplex stainless steel. {yields} Increasing pulse density, fatigue crack growth rate is reduced. {yields} Microstructure is not affected by LSP. {yields} Compressive residual stresses increases increasing pulse density. - Abstract: Duplex stainless steels have wide application in different fields like the ship, petrochemical and chemical industries that is due to their high strength and excellent toughness properties as well as their high corrosion resistance. In this work an investigation is performed to evaluate the effect of laser shock processing on some mechanical properties of 2205 duplex stainless steel. Laser shock processing (LSP) or laser shock peening is a new technique for strengthening metals. This process induces a compressive residual stress field which increases fatigue crack initiation life and reduces fatigue crack growth rate. A convergent lens is used to deliver 2.5 J, 8 ns laser pulses by a Q-switched Nd:YAG laser, operating at 10 Hz with infrared (1064 nm) radiation. The pulses are focused to a diameter of 1.5 mm. Effect of pulse density in the residual stress field is evaluated. Residual stress distribution as a function of depth is determined by the contour method. It is observed that the higher the pulse density the greater the compressive residual stress. Pulse densities of 900, 1600 and 2500 pul/cm{sup 2} are used. Pre-cracked compact tension specimens were subjected to LSP process and then tested under cyclic loading with R = 0.1. Fatigue crack growth rate is determined and the effect of LSP process parameters is evaluated. In addition fracture toughness is determined in specimens with and without LSP treatment. It is observed that LSP reduces fatigue crack growth and increases fracture toughness if this steel.

  13. On the High Temperature Deformation Behaviour of 2507 Super Duplex Stainless Steel

    Science.gov (United States)

    Mishra, M. K.; Balasundar, I.; Rao, A. G.; Kashyap, B. P.; Prabhu, N.

    2017-02-01

    High temperature deformation behaviour of 2507 super duplex stainless steel was investigated by conducting isothermal hot compression tests. The dominant restoration processes in ferrite and austenite phases present in the material were found to be distinct. The possible causes for these differences are discussed. Based on the dynamic materials model, processing map was developed to identify the optimum processing parameters. The microstructural mechanisms operating in the material were identified. A unified strain-compensated constitutive equation was established to describe the high temperature deformation behaviour of the material under the identified processing conditions. Standard statistical parameter such as correlation coefficient has been used to validate the established equation.

  14. Microhardness changes gradient of the duplex stainless steel (DSS surface layer after dry turning

    Directory of Open Access Journals (Sweden)

    G. Krolczyk

    2014-10-01

    Full Text Available The article presents the gradient of microhardness changes as a function of the distance from the material surface after turning with a wedge provided with a coating with a ceramic intermediate layer. The investigation comprised the influence of cutting speed on surface integrity microhardness in dry machining. The tested material was duplex stainless steel (DSS with two-phase, ferritic-austenitic structure. The tests have been performed under production conditions during machining of parts for electric motors and deep-well pumps.

  15. Tribological study in roll forming of lean duplex stainless steel sheets

    DEFF Research Database (Denmark)

    Nielsen, Peter Søe; Nielsen, Morten Strogaard; Bay, Niels

    2012-01-01

    focus on tribological issues are galling and pick-up formation as well as tool life in roll forming of stainless duplex steel sheets. The roll forming process is exemplified by production of an s-shaped profile used in interlock carcass production for flexible pipes used in off-shore oil extraction...... are relatively low and surface expansion is more or less non-existent, long roll forming production runs imply large sliding/contact lengths due to relative movement between steel strip and rolls. This requires an efficient tribological system to prevent pick-up formation on the forming tools. The present work...

  16. Effects of prior solution treatment on thermal aging behavior of duplex stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Li, Shilei; Wang, Yanli; Zhang, Hailong; Li, Shuxiao [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China); Wang, Genqi [Yantai Taihai Marnoir Nuclear Equipment Co. Ltd., Yantai 264003 (China); Wang, Xitao, E-mail: xtwang@ustb.edu.cn [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China)

    2013-10-15

    The influence of solution temperature on thermal aging behavior was studied in duplex stainless steels. With increasing solution temperature, the ferrite contents remarkably increase, Cr and Ni elements redistribute. During thermal aging, the impact properties of higher solution temperature treated materials suffer a serious degradation, which is not only related with ferrite content but also the alloy compositions in ferrite. Enrichment of Ni in ferrite can accelerate the spinodal decomposition kinetics. Thermal aging-inducing strain fields in ferrite cause the embrittlement of DSS.

  17. On the High Temperature Deformation Behaviour of 2507 Super Duplex Stainless Steel

    Science.gov (United States)

    Mishra, M. K.; Balasundar, I.; Rao, A. G.; Kashyap, B. P.; Prabhu, N.

    2017-01-01

    High temperature deformation behaviour of 2507 super duplex stainless steel was investigated by conducting isothermal hot compression tests. The dominant restoration processes in ferrite and austenite phases present in the material were found to be distinct. The possible causes for these differences are discussed. Based on the dynamic materials model, processing map was developed to identify the optimum processing parameters. The microstructural mechanisms operating in the material were identified. A unified strain-compensated constitutive equation was established to describe the high temperature deformation behaviour of the material under the identified processing conditions. Standard statistical parameter such as correlation coefficient has been used to validate the established equation.

  18. Relationship between hydrogen-induced phase transformations and pitting nucleation sites in duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Liqiu; Yang, Binjie; Qin, Sixiao [University of Science and Technology Beijing (China). Corrosion and Protection Center

    2016-02-15

    This paper demonstrates the hydrogen-induced phase transformation and the associated pitting nucleation sites of 2507 duplex stainless steel using scanning Kelvin probe force microscopy and magnetic force microscopy. The low potential sites in Volta potential images, which are considered as the pitting nucleation sites, are strongly dependent on the hydrogen-induced phase transformation. They firstly initiate on the magnetic martensite laths in the austenite phase or at the ferrite/austenite boundaries, and then appear near the needle-shaped microtwins in the ferrite phase, because of the difference in physicochemical properties of hydrogen-induced phase transformation microstructures.

  19. Accelerated corrosion of 2205 duplex stainless steel caused by marine aerobic Pseudomonas aeruginosa biofilm.

    Science.gov (United States)

    Xu, Dake; Xia, Jin; Zhou, Enze; Zhang, Dawei; Li, Huabing; Yang, Chunguang; Li, Qi; Lin, Hai; Li, Xiaogang; Yang, Ke

    2017-02-01

    Microbiologically influenced corrosion (MIC) of 2205 duplex stainless steel (DSS) in the presence of Pseudomonas aeruginosa was investigated through electrochemical and surface analyses. The electrochemical results showed that P. aeruginosa significantly reduced the corrosion resistance of 2205 DSS. Confocal laser scanning microscopy (CLSM) images showed that the depths of the largest pits on 2205 DSS with and without P. aeruginosa were 14.0 and 4.9μm, respectively, indicating that the pitting corrosion was accelerated by P. aeruginosa. X-ray photoelectron spectroscopy (XPS) results revealed that CrO3 and CrN formed on the 2205 DSS surface in the presence of P. aeruginosa.

  20. Process for stabilizing dimensions of duplex stainless steels for service at elevated temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Hull, Frederick C. (Pittsburgh, PA); Tobin, John C. (Richland, WA)

    1981-01-01

    Duplex stainless steel materials containing austenite plus delta ferrite, are dimensionally stabilized by heating the material to a reaction temperature between about 1050.degree.-1450.degree. F. (566.degree.-788.degree. C.), holding it at this temperature during transformation of delta ferrite to austenite plus sigma phase, and subsequently heating to a reversion temperature between about 1625.degree.-1750.degree. F. (885.degree.-954.degree. C.), whereby the sigma phase transforms back to ferrite, but the austenite remains dispersed in the ferrite phase. Final controlled cooling permits transformation of ferrite to austenite plus sigma and, later, precipitation of carbides.

  1. The Prediction of Long-Term Thermal Aging in Cast Austenitic Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Byun, Thak Sang; Yang, Ying; Lach, Timothy G.

    2017-02-15

    Cast austenitic stainless steel (CASS) materials are extensively used for many massive primary coolant system components of light water reactors (LWRs) including coolant piping, valve bodies, pump casings, and piping elbows. Many of these components are operated in complex and persistently damaging environments of elevated temperature, high pressure, corrosive environment, and sometimes radiation for long periods of time. Since a large number of CASS components are installed in every nuclear power plant and replacing such massive components is prohibitively expensive, any significant degradation in mechanical properties that affects structural integrity, cracking resistance in particular, of CASS components will raise a serious concern on the performance of entire power plant. The CASS materials for nuclear components are highly corrosion-resistant Fe-Cr-Ni alloys with 300 series stainless steel compositions and mostly austenite (γ)–ferrite (δ) duplex structures, which result from the casting processes consisting of alloy melting and pouring or injecting liquid metal into a static or spinning mold. Although the commonly used static and centrifugal casting processes enable the fabrication of massive components with proper resistance to environmental attacks, the alloying and microstructural conditions are not highly controllable in actual fabrication, especially in the casting processes of massive components. In the corrosion-resistant Fe-Cr-Ni alloy system, the minor phase (i.e., the δ-ferrite phase) is inevitably formed during the casting process, and is in a non-equilibrium state subject to detrimental changes during exposure to elevated temperature and/or radiation. In general, relatively few critical degradation modes are expected within the current design lifetime of 40 years, given that the CASS components have been processed properly. It has been well known, however, that both the thermal aging and the neutron irradiation can cause degradation of static

  2. Application of martensitic, modified martensitic and duplex stainless steel bar stock for completion equipment

    Energy Technology Data Exchange (ETDEWEB)

    Bhavsar, R.B. [CAMCO Products and Services, Houston, TX (United States); Montani, R. [Foroni, S.p.A., Colombo (Italy)

    1998-12-31

    Martensitic and duplex stainless steel tubing are commonly used for oil and gas applications containing CO{sub 2}. Completion equipment manufacturing requires use of solid round bar or heavy wall hollows. Material properties for this stock are not identical in all cases. Material properties as well as corrosion characteristics are discussed for 13Cr, 13Cr-5Ni-2Mo and 25Cr alloys. Corrosion testing of modified or Enhanced 13Cr solid bar stock, UNS S41425 and other compositions in H{sub 2}S-Cl{sup {minus}} and pH is reported in coupled and uncoupled condition. Corrosion testing of various super duplex bar stock at various H{sub 2}S-chlorides and temperature in CO{sub 2} environment is reported. Impact value requirements, welding issues and special consideration required for these alloys for completion equipment is discussed. Modified 13Cr and Super Duplex Oil Country Tubular Goods (OCTG) are readily available, however, availability of completion equipment raw material compatible with these OCTG is limited.

  3. Machining Duplex Stainless Steel: Comparative Study Regarding End Mill Coated Tools

    Directory of Open Access Journals (Sweden)

    Ronny M. Gouveia

    2016-10-01

    Full Text Available The difficulties in the machining of duplex stainless steel are well known. However, research on this matter is rather limited. Suppliers offer quite different cutting tools for the same raw material, with end mills of two, three or even four knives and a huge number of distinct coatings, some of them under commercial brands, making it difficult to assess the advantages they offer. Furthermore, there is a remarkable difference among the several types of duplex stainless steel available nowadays on the market. The present work intends to assess the machining performance of different tools, analyzing the behavior and wear mechanisms with two different cutting lengths, keeping constant the machining trajectory. Some other parameters were also kept constant, such as cutting speed, depth of cut and cutting width, as well as feed per tooth. The machining process was carried out under lubricated conditions, using an emulsion of 5% oil in water. Tools provided with a different number of teeth and surface coatings were tested, analyzing the wear behavior of each cutting length using scanning electron microscopy, trying to identify wear performance and how each coating contributes to increased tool life. The surfaces produced were also analyzed by means of profilometry measurements, correlating tool wear and part surface roughness. This comparative study allows determining the advantages of different tools relative to others, based on coatings and tool geometry.

  4. Stainless steel porous substrates produced by tape casting

    Science.gov (United States)

    Mercadelli, Elisa; Gondolini, Angela; Pinasco, Paola; Sanson, Alessandra

    2017-01-01

    In this work the technological issues related to the production of tape cast large-area porous stainless steel supports for Solid Oxide Fuel Cells (SOFC) applications were carefully investigated. The slurry formulation was optimized in terms of amount and nature of the organic components needed: rice starch and polymethyl metacrylate were found to be, respectively, the most suitable pore former and binder because easily eliminated during the thermal treatment in reducing atmosphere. The compatibility of the binder system chosen with the most widely used solvents for screen printing inks was also evaluated. Finally the influence of the sintering temperature and of the refractory supports to be used during the thermal treatments onto the production of porous stainless steel supports was discussed. The whole process optimization allows to produce flat, crack-free metallic substrate 900-1000 μm thick, dimensions up to 5×5 cm and with a tailored porosity of 40% suitable for SOFCs application.

  5. X-Ray diffraction technique applied to study of residual stresses after welding of duplex stainless steel plates

    Energy Technology Data Exchange (ETDEWEB)

    Monin, Vladimir Ivanovitch; Assis, Joaquim Teixeira de [Instituto Politecnico do Rio e Janeiro (IPRJ), Nova Friburgo, RJ (Brazil); Lopes, Ricardo Tadeu; Turibus, Sergio Noleto; Payao Filho, Joao C., E-mail: sturibus@nuclear.ufrj.br [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil)

    2014-08-15

    Duplex stainless steel is an example of composite material with approximately equal amounts of austenite and ferrite phases. Difference of physical and mechanical properties of component is additional factor that contributes appearance of residual stresses after welding of duplex steel plates. Measurements of stress distributions in weld region were made by X-ray diffraction method both in ferrite and austenite phases. Duplex Steel plates were joined by GTAW (Gas Tungsten Arc Welding) technology. There were studied longitudinal and transverse stress components in welded butt joint, in heat affected zone (HAZ) and in points of base metal 10 mm from the weld. Residual stresses measured in duplex steel plates jointed by welding are caused by temperature gradients between weld zone and base metal and by difference of thermal expansion coefficients of ferrite and austenite phases. Proposed analytical model allows evaluating of residual stress distribution over the cross section in the weld region. (author)

  6. Mechanical properties of duple stainless steels laser joints; Propiedades mecanicas de las uniones por laser de aceros inoxidables duplex

    Energy Technology Data Exchange (ETDEWEB)

    Amigo, V.; Bonache, V.; Teruel, L.; Vicente, A.

    2005-07-01

    The welded joints of stainless steels always present problems for the microstructural modifications that occur in the heat affected zone. Particularly, duplex stainless steels present very important changes when the weld pool solidifies forming fundamentally ferritic structures with some austenite in grain boundaries. These microstructural modifications, and those which occur in the HAZ, justify the mechanical properties of the joint and mainly those of plasticity, being all of them influenced by the processing conditions. In this work the influence of the laser welding speed on the tensile behaviour od duplex stainless steel welded joints is presented. The microstructure of the obtained seams and of the heat affected zone will be evaluated by means of optic and scanning electron microscopy. Also, different microhardness profiles have been obtained to evaluate the modifications in the mechanical properties both in the seam and the zone of thermal affection. (Author) 23 refs.

  7. Short fatigue cracks nucleation and growth in lean duplex stainless steel LDX 2101

    Energy Technology Data Exchange (ETDEWEB)

    Strubbia, R., E-mail: strubbia@ifir-conicet.gov.ar [Instituto de Física Rosario – CONICET, Universidad Nacional de Rosario (Argentina); Hereñú, S.; Alvarez-Armas, I. [Instituto de Física Rosario – CONICET, Universidad Nacional de Rosario (Argentina); Krupp, U. [Faculty of Engineering and Computer Science, University of Applied Sciences Osnabrück (Germany)

    2014-10-06

    This work is focused on the fatigue damage of lean duplex stainless steels (LDSSs) LDX 2101. Special interest is placed on analyzing short fatigue crack behavior. In this sense, short crack initiation and growth during low cycle fatigue (LCF) and short crack nucleation during high cycle fatigue (HCF) of this LDSS have been studied. The active slip systems and their associated Schmid factors (SF) are determined using electron backscattered diffraction (EBSD). Additionally, the dislocation structure developed during cycling is observed by transmission electron microscopy (TEM). Regardless of the fatigue regime, LCF and HCF, short cracks nucleate along intrusion/extrusions in ferritic grains. Moreover, during the LCF phase boundaries decelerate short crack propagation. These results are rationalized by the hardness of the constitutive phases and the dependence of screw dislocation mobility in the ferrite phase on strain rate and stress amplitude.

  8. 475 °C Embrittlement in a duplex stainless steel UNS S31803

    Directory of Open Access Journals (Sweden)

    Tavares S.S.M.

    2001-01-01

    Full Text Available The susceptibility of a duplex stainless steel UNS S31803 to thermal embrittlement at 475 °C was evaluated by means of mechanical tests (impact energy and hardness, magnetic measurements (hysteresis and thermomagnetic analysis and scanning electron microscopy. The results show that the material undergoes severe embrittlement and hardening in the first 100 h. The corrosion resistance of the ferrite phase in a 10%HNO3 + 0.05%HF solution deteriorated after 500 h of ageing. The Curie temperature (Tc was the most sensitive magnetic property to the microstructural changes that promote embrittlement. Tc increases with ageing time due to the progressive reduction of chromium in the Fe-rich matrix during spinodal decomposition.

  9. Finite element modelling and characterization of friction welding on UNS S31803 duplex stainless steel joints

    Directory of Open Access Journals (Sweden)

    Mohammed Asif. M

    2015-12-01

    Full Text Available Solid state joining techniques are increasingly employed in joining duplex stainless steel materials due to their high integrity. Continuous drive friction welding is a solid state welding technique which is used to join similar and dissimilar materials. This joining technique is characterized by short cycle time, low heat input and narrow heat affected zones. The simulation becomes an important tool in friction welding because of short welding cycle. In the present work, a three dimensional non-linear finite element model was developed. The thermal history and axial shortening profiles were predicted using ANSYS, a software tool. This numerical model was validated using experimental results. The results show that the frictional heating stage of the process has more influence on temperature and upsetting stage has more impact on axial shortening. The knowledge of these parameters would lead to optimization of input parameters and improvement of design and machine tools.

  10. Magnetic Characterization of Selective Laser-Melted Saf 2507 Duplex Stainless Steel

    Science.gov (United States)

    Davidson, Karl P.; Singamneni, Sarat

    2017-03-01

    Selective laser melting (SLM) is disruptive in terms of the sensitive balance between constituent phases of the biphasic duplex stainless steel material options. While adversely affecting the mechanical and corrosion properties, the predominantly ferritic structures resulting from the high thermal gradients were also noted to impart significant magnetic responses. Scientific attention is essential for ascertaining the material-process-magnetic response relationships to establish the underlying principles and critical responses. This is attempted here through magnetic characterization based on results from saturation hysteresis loops and evaluation of austenite-ferrite ratios allowing for identification of the structure-magnetic property relationships. Overall, the experimental results indicated strong process-property relationships, whereas the magnetic saturation levels of SLM samples are much higher compared with the wrought counterparts.

  11. Effect of Secondary Phase Precipitation on the Corrosion Behavior of Duplex Stainless Steels

    Directory of Open Access Journals (Sweden)

    Kai Wang Chan

    2014-07-01

    Full Text Available Duplex stainless steels (DSSs with austenitic and ferritic phases have been increasingly used for many industrial applications due to their good mechanical properties and corrosion resistance in acidic, caustic and marine environments. However, DSSs are susceptible to intergranular, pitting and stress corrosion in corrosive environments due to the formation of secondary phases. Such phases are induced in DSSs during the fabrication, improper heat treatment, welding process and prolonged exposure to high temperatures during their service lives. These include the precipitation of sigma and chi phases at 700–900 °C and spinodal decomposition of ferritic grains into Cr-rich and Cr-poor phases at 350–550 °C, respectively. This article gives the state-of the-art review on the microstructural evolution of secondary phase formation and their effects on the corrosion behavior of DSSs.

  12. Relative merits of duplex and austenitic stainless steels for applications in the oil and gas industry

    Energy Technology Data Exchange (ETDEWEB)

    Johansson, Elisabeth; Wegrelius, Lena; Pettersson, Rachel [Outokumpu Stainless AB, Avesta (Sweden)

    2012-07-01

    The broad range of available stainless steel grades means that these materials can fulfil a wide variety of requirements within the oil and gas industry. The duplex grades have the advantage of higher strength than standard austenitic grades, while the superaustenitic grades provide a cost-effective alternative to nickel-base alloys in a number of cases. The paper presents the results of various types of laboratory testing to rank the grades in terms of resistance to pitting, crevice corrosion and stress corrosion cracking. Results from field testing in actual or simulated service conditions are discussed and a number of application examples, including process piping flexible, heat exchangers and topside equipment are presented. (author)

  13. Development of Weld Metal Microstructures in Pulsed Laser Welding of Duplex Stainless Steel

    Science.gov (United States)

    Mirakhorli, F.; Malek Ghaini, F.; Torkamany, M. J.

    2012-10-01

    The microstructure of the weld metal of a duplex stainless steel made with Nd:YAG pulsed laser is investigated at different travel speeds and pulse frequencies. In terms of the solidification pattern, the weld microstructure is shown to be composed of two distinct zones. The presence of two competing heat transfer channels to the relatively cooler base metal and the relatively hotter previous weld spot is proposed to develop two zones. At high overlapping factors, an array of continuous axial grains at the weld centerline is formed. At low overlapping factors, in the zone of higher cooling rate, a higher percentage of ferrite is transformed to austenite. This is shown to be because with extreme cooling rates involved in pulsed laser welding with low overlapping, the ferrite-to-austenite transformation can be limited only to the grain boundaries.

  14. Effect of QPQ nitriding time on microstructure and wear resistance of SAF2906 duplex stainless steel

    Science.gov (United States)

    Liu, D.; Wu, G. X.; Shen, L. X.

    2017-01-01

    QPQ salt bath treatment of SAF2906 duplex stainless steel was conducted at 570 °C for 60 min, 90 min,120 min,150 min and 180 min, followed by post-oxidation process with heating temperature of 400°C and holding duration of 30 min. The effect of QPQ nitriding time on microstructure and wear resistance of SAF2906 duplex stainless steel was investigated by means of OM, SEM, XRD, microhardness test, adhesion strength test and wear resistance test. Microstructure observation showed outer layer was composed of Fe3O4. The main phase of the intermediate layer was CrN, αN and Fe2-3N. The main phase of the inner layer was CrN and S. The adhesion strength test of the surface layer-substrate showed the QPQ treated samples have favorable adhesion strength of HF-1 level. With the increase of nitriding time, the growth rate of the compound layer gradually slowed down and the surface hardness first increased and then decreased, and the maximum hardness was 1283 HV0.2 at 150 min. The dry siliding results showed that the wear resistance of the QPQ treated samples was at least 20 times than that of the substrate, and the optimum nitriding time to obtain the best wear resistance is 150 min. The worn surface morphology observation showed the main wear mechanism of the substrate was plough wear, while micro-cutting is the main wear mechanism that causes the damage of the QPQ treated samples.

  15. Formation of NiAl intermetallic coatings on stainless steel by a conventional duplex process

    Energy Technology Data Exchange (ETDEWEB)

    Ashrafizadeh, F.; Hajdaie, A.H.; Miraghaie, S. [Isfahan Univ. of Technology, Dept. of Materials Engineering, Isfahan (Iran, Islamic Republic of)

    2003-07-01

    Nickel-aluminide coatings were formed on 403 stainless steel samples by a duplex process incorporating electro-deposition and diffusion coating. Nickel was deposited by conventional electroplating on some specimens to appropriate thickness. The uncoated and nickel-coated samples were then aluminized by a powder pack method. Process parameters including pack composition, temperature, coating and annealing cycles were optimized in terms of the intermetallic phases produced in the near surface layers. The coatings and interface regions were characterized by optical and scanning electron microscopy, x-ray diffraction, glow discharge spectroscopy, micro-hardness measurements and pin-on-disc wear testing. Experimental results indicate that deposition of nickel on 403 steel before aluminizing produced two distinct layers of NiAl and FeAl on the surface and below that, respectively. The formation of these phases depends on the coating and annealing temperatures. The intermetallic phase NiAl on steel substrate acts as an alumina forming material to increase the life of aluminized layer. The intermetallic coatings produced by this duplex process had dense structure and excellent adhesion to the substrate; these are suitable candidates for high temperature applications of steel components under oxidation and hot corrosion conditions. (author)

  16. Mechanism of hot-rolling crack formation in lean duplex stainless steel 2101

    Institute of Scientific and Technical Information of China (English)

    Zhi-hui Feng; Jing-yuan Li; Yi-de Wang

    2016-01-01

    The thermoplasticity of duplex stainless steel 2205 (DSS2205) is better than that of lean duplex steel 2101 (LDX2101), which un-dergoes severe cracking during hot rolling. The microstructure, microhardness, phase ratio, and recrystallization dependence of the deforma-tion compatibility of LDX2101 and DSS2205 were investigated using optical microscopy (OM), electron backscatter diffraction (EBSD), Thermo-Calc software, and transmission electron microscopy (TEM). The results showed that the phase-ratio transformations of LDX2101 and DSS2205 were almost equal under the condition of increasing solution temperature. Thus, the phase transformation was not the main cause for the hot plasticity difference of these two steels. The grain size of LDX2101 was substantially greater than that of DSS2205, and the microhardness difference of LDX2101 was larger than that of DSS2205. This difference hinders the transfer of strain from ferrite to austenite. In the rolling process, the ferrite grains of LDX2101 underwent continuous softening and were substantially refined. However, although little recrystallization occurred at the boundaries of austenite, serious deformation accumulated in the interior of austenite, leading to a substantial increase in hardness. The main cause of crack formation is the microhardness difference between ferrite and austenite.

  17. Characterization of microstructure and texture across dissimilar super duplex/austenitic stainless steel weldment joint by austenitic filler metal

    Energy Technology Data Exchange (ETDEWEB)

    Eghlimi, Abbas, E-mail: a.eghlimi@ma.iut.ac.ir [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Shamanian, Morteza [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Eskandarian, Masoomeh [Department of Materials Engineering, Shiraz University, Shiraz 71348-51154 (Iran, Islamic Republic of); Zabolian, Azam [Department of Natural Resources, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Szpunar, Jerzy A. [Department of Mechanical Engineering, University of Saskatchewan, Saskatoon, SK S7N 5A9 (Canada)

    2015-08-15

    The evolution of microstructure and texture across an as-welded dissimilar UNS S32750 super duplex/UNS S30403 austenitic stainless steel joint welded by UNS S30986 (AWS A5.9 ER309LMo) austenitic stainless steel filler metal using gas tungsten arc welding process was evaluated by optical micrography and EBSD techniques. Due to their fabrication through rolling process, both parent metals had texture components resulted from deformation and recrystallization. The weld metal showed the highest amount of residual strain and had large austenite grain colonies of similar orientations with little amounts of skeletal ferrite, both oriented preferentially in the < 001 > direction with cub-on-cube orientation relationship. While the super duplex stainless steel's heat affected zone contained higher ferrite than its parent metal, an excessive grain growth was observed at the austenitic stainless steel's counterpart. At both heat affected zones, austenite underwent some recrystallization and formed twin boundaries which led to an increase in the fraction of high angle boundaries as compared with the respective base metals. These regions showed the least amount of residual strain and highest amount of recrystallized austenite grains. Due to the static recrystallization, the fraction of low degree of fit (Σ) coincident site lattice boundaries, especially Σ3 boundaries, was increased in the austenitic stainless steel heat affected zone, while the formation of subgrains in the ferrite phase increased the content of < 5° low angle boundaries at that of the super duplex stainless steel. - Graphical abstract: Display Omitted - Highlights: • Extensive grain growth in the HAZ of austenitic stainless steel was observed. • Intensification of < 100 > orientated grains was observed adjacent to both fusion lines. • Annealing twins with Σ3 CSL boundaries were formed in the austenite of both HAZ. • Cub-on-cube OR was observed between austenite and ferrite in the weld

  18. Magnetic detection of sigma phase in duplex stainless steel UNS S31803

    Energy Technology Data Exchange (ETDEWEB)

    Tavares, S.S.M., E-mail: ssmtavares@terra.com.b [Universidade Federal Fluminense, Departamento de Engenharia Mecanica, PGMEC, Rua Passo da Patria, 156, CEP 24210-240, Niteroi (Brazil); Pardal, J.M.; Guerreiro, J.L. [Universidade Federal Fluminense, Departamento de Engenharia Mecanica, PGMEC, Rua Passo da Patria, 156, CEP 24210-240, Niteroi (Brazil); Gomes, A.M. [Universidade Federal do Rio de Janeiro, Instituto de Fisica (Brazil); Silva, M.R. da [Universidade Federal de Itajuba, Instituto de Ciencias (Brazil)

    2010-09-15

    Duplex stainless steels are high strength and corrosion resistant steels extensively used in the chemical and petrochemical industry. The best mechanical properties and corrosion resistance are obtained with a microstructure composed by equal parts of ferrite and austenite and free from tertiary phases. Sigma phase is one of these deleterious tertiary phases. In the present work different amounts of sigma phase were precipitated by heat treatments in a UNS S31803 stainless steel. Some specimens were cold rolled before sigma phase precipitation in order to evaluate the effect of deformation on the magnetic measurements. The amount of sigma phase was precisely determined by microscopy and image analysis for each heat treatment condition. The effects of sigma phase on the steel properties were investigated, confirming the detrimental effects of very small percentages on corrosion resistance and toughness. Two magnetic methods were used to detect sigma phase: magnetization saturation measurements in a Vibrating Sample Magnetometer and ferritoscope testing. Both methods were found to be sensitive to small percentages of sigma phase in the microstructure.

  19. Tribocorrosion Failure Mechanism of TiN/SiOx Duplex Coating Deposited on AISI304 Stainless Steel

    Directory of Open Access Journals (Sweden)

    Qiang Chen

    2016-11-01

    Full Text Available TiN/SiOx duplex coatings were synthesized on AISI304 stainless steel by plasma immersion ion implantation and deposition (PIIID followed by radio frequency magnetron sputtering (RFMS. The microstructure and tribocorrosion failure behaviors of the duplex coatings were investigated by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, atomic force microscopy, reciprocating-sliding tribometer, and electrochemical tests. The as-deposited duplex coating had a two-layered columnar growth structure consisting of face-centered cubic TiN and amorphous SiOx. Sliding tests showed that the TiN interlayer had good adhesion with the substrate, but the SiOx layer suffered from severe delamination failure. Friction force induced a number of micro-cracks in the coating, which provided channels for the diffusion of NaCl solution. The tribocorrosion test showed that the duplex coating exhibited a lower wear-performance in NaCl solution than in ambient atmosphere. Multi-scale chloride ion corrosion occurred simultaneously and substantially degraded the bonding strength of the columnar crystals or neighboring layers. Force-corrosion synergy damage eventually led to multi-degradation failure of the duplex coating. The presented results provide a comprehensive understanding of the tribocorrosion failure mechanism in coatings with duplex architecture.

  20. Study of corrosive effect of oil in super duplex stainless steels; Estudo do efeito corrosivo do petroleo em acos super duplex

    Energy Technology Data Exchange (ETDEWEB)

    Gusmao, E.F.; Azambuja, V.M. [IFES, Coordenadoria de Metalurgia, Vitoria, ES (Brazil); Santos, D.S. [Universidade Federal do Rio de Janeiro (PEMM/COPPE/UFRJ), RJ (Brazil). Pos-Graduacao em Engenharia Metalurgica e de Materiais

    2010-07-01

    The super duplex stainless steel was exposed in an environment at 75 degree C with oil for days, weeks and month to observe the change in mass. The corrosion leads to loss of weight of material which could harm the economy of a company, as this will have to stop production to replace the corroded part. Hence the great importance of studies on ways to mitigate the corrosion. There was a chemical attack by the reagent Behara and testing to study the quality of the protective coating after the tests with oil by electrochemical impedance. (author)

  1. Influence of the heat treatment on the cold deformation od duplex stainless steels; Influencia de los tratamientos termicos en la deformacion en frio de los aceros inoxidables duplex

    Energy Technology Data Exchange (ETDEWEB)

    Fargas, G.; Manero, J. M.; Anglada, M.; Mateo, A.

    2004-07-01

    The purpose of this paper is to study the compression behavior of a duplex stainless steel after several annealing conditions, in order to simulate the response during cold rolling in the industrial process. For each studied condition, stress-strain curves present serrations in the flow zone due to austenite and ferrite twinning and the austenite phase transformation to martensite. At the same time, it is shown that sigma phase increases the strength and diminish the cold deformation capacity of the steel. (Author) 15 refs.

  2. Effect of Multipass Friction Stir Processing on Mechanical and Corrosion Behavior of 2507 Super Duplex Stainless Steel

    Science.gov (United States)

    Mishra, M. K.; Gunasekaran, G.; Rao, A. G.; Kashyap, B. P.; Prabhu, N.

    2016-12-01

    The microstructure, mechanical properties, and corrosion behavior of 2507 super duplex stainless steel after multipass friction stir processing (FSP) were examined. A significant refinement in grain size of both ferrite and austenite was observed in stir zone resulting in improved yield and tensile strength. Electrochemical impedance spectroscopy and anodic polarization studies in 3.5 wt.% NaCl solution showed nobler corrosion characteristics with increasing number of FSP passes. This was evident from the decrease in corrosion current density, decrease in passive current density, and increase in polarization resistance. Also, the decrease in density of defects, based on Mott-Schottky analysis, further confirms the improvement in corrosion resistance of 2507 super duplex stainless steel after multipass FSP.

  3. Surface Texturing-Plasma Nitriding Duplex Treatment for Improving Tribological Performance of AISI 316 Stainless Steel

    Directory of Open Access Journals (Sweden)

    Naiming Lin

    2016-10-01

    Full Text Available Surface texturing-plasma nitriding duplex treatment was conducted on AISI 316 stainless steel to improve its tribological performance. Tribological behaviors of ground 316 substrates, plasma-nitrided 316 (PN-316, surface-textured 316 (ST-316, and duplex-treated 316 (DT-316 in air and under grease lubrication were investigated using a pin-on-disc rotary tribometer against counterparts of high carbon chromium bearing steel GCr15 and silicon nitride Si3N4 balls. The variations in friction coefficient, mass loss, and worn trace morphology of the tested samples were systemically investigated and analyzed. The results showed that a textured surface was formed on 316 after electrochemical processing in a 15 wt % NaCl solution. Grooves and dimples were found on the textured surface. As plasma nitriding was conducted on a 316 substrate and ST-316, continuous and uniform nitriding layers were successfully fabricated on the surfaces of the 316 substrate and ST-316. Both of the obtained nitriding layers presented thickness values of more than 30 μm. The nitriding layers were composed of iron nitrides and chromium nitride. The 316 substrate and ST-316 received improved surface hardness after plasma nitriding. When the tribological tests were carried out under dry sliding and grease lubrication conditions, the tested samples showed different tribological behaviors. As expected, the DT-316 samples revealed the most promising tribological properties, reflected by the lowest mass loss and worn morphologies. The DT-316 received the slightest damage, and its excellent tribological performance was attributed to the following aspects: firstly, the nitriding layer had high surface hardness; secondly, the surface texture was able to capture wear debris, store up grease, and then provide continuous lubrication.

  4. Investigation of corrosion of welded joints of austenitic and duplex stainless steels

    Science.gov (United States)

    Topolska, S.

    2016-08-01

    Investigation of corrosion resistance of materials is one of the most important tests that allow determining their functional properties. Among these tests the special group consist electrochemical investigations, which let to accelerate the course of the process. These investigations allow rapidly estimating corrosion processes occurring in metal elements under the influence of the analysed environment. In the paper are presented results of investigations of the resistance to pitting corrosion of the steel of next grades: austenitic 316L and duplex 2205. It was also analysed the corrosion resistance of welded joints of these grades of steel. The investigations were conducted in two different corrosion environments: in the neutral one (3.5 % sodium chloride) and in the aggressive one (0.1 M sulphuric acid VI). The obtained results indicate different resistance of analysed grades of steel and their welded joints in relation to the corrosion environment. The austenitic 316L steel characterizes by the higher resistance to the pitting corrosion in the aggressive environment then the duplex 2205 steel. In the paper are presented results of potentiodynamic tests. They showed that all the specimens are less resistant to pitting corrosion in the environment of sulphuric acid (VI) than in the sodium chloride one. The 2205 steel has higher corrosion resistance than the 316L stainless steel in 3.5% NaCl. On the other hand, in 0.1 M H2SO4, the 316L steel has a higher corrosion resistance than the 2205 one. The weld has a similar, very good resistance to pitting corrosion like both steels.

  5. Hardness analysis of welded joints of austenitic and duplex stainless steels

    Science.gov (United States)

    Topolska, S.

    2016-08-01

    Stainless steels are widely used in the modern world. The continuous increase in the use of stainless steels is caused by getting greater requirements relating the corrosion resistance of all types of devices. The main property of these steels is the ability to overlap a passive layer of an oxide on their surface. This layer causes that they become resistant to oxidation. One of types of corrosion-resistant steels is ferritic-austenitic steel of the duplex type, which has good strength properties. It is easily formable and weldable as well as resistant to erosion and abrasive wear. It has a low susceptibility to stress-corrosion cracking, to stress corrosion, to intercrystalline one, to pitting one and to crevice one. For these reasons they are used, among others, in the construction of devices and facilities designed for chemicals transportation and for petroleum and natural gas extraction. The paper presents the results which shows that the particular specimens of the ][joint representing both heat affected zones (from the side of the 2205 steel and the 316L one) and the weld are characterized by higher hardness values than in the case of the same specimens for the 2Y joint. Probably this is caused by machining of edges of the sections of metal sheets before the welding process, which came to better mixing of native materials and the filler metal. After submerged arc welding the 2205 steel still retains the diphase, austenitic-ferritic structure and the 316L steel retains the austenitic structure with sparse bands of ferrite σ.

  6. Study of the fatigue behaviour and damage of a aged duplex stainless steel; Etude du comportement et de l'endommagement en fatigue d'un acier inoxydable austeno-ferritique moule vieilli

    Energy Technology Data Exchange (ETDEWEB)

    Le Roux, J.Ch

    2000-07-01

    Cast duplex stainless steels are commonly used in components of pressurized water reactors primary circuit. When submitted to in-service temperatures embrittlement occurs because of the nucleation and growth of a harder phase in the ferrite by spinodal composition. Macrostructure of this steel (ferritic primary grain size is about 4-5 mm) and embrittlement of ferrite due to aging lead to a very high scattering of mechanical properties for monotonous loadings. We showed that, in spite of this macrostructure, the cyclic behaviour of aged duplex stainless steels fits usual Manson-Coffin law while initial hardening is followed by softening, in part because of the demodulation of the composition. The fatigue crack propagation rate of material follows a Paris law. While crack initiation mainly appears next to the millimetric cast defects, fatigue crack propagation remains a continuous mechanism. Ferritic and austenitic elements break successively (ferrite first breaks by cleavage, then austenite breaks by ductile fatigue). In spite of the fact that the aged ferrite is embrittled, cleavage microcracks, for load levels examined, seldom appear in ferrite at the crack tip and on both sides of the main crack. Effects of cast defects and crystallographic ferrite orientation were also studied. Propagation fatigue crack behaviour was modeled assuming that the crack tip material behaves as if it was submitted to low cycle fatigue loadings. If we consider a homogeneous material, results are in good agreement with experiments. (authors)

  7. Influence of dislocation glide on the spinodal decomposition of fatigued duplex stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Herenu, S., E-mail: herenu@ifir-conicet.gov.ar [Instituto de Fisica Rosario, Bv. 27 de Febrero 210 bis, (2000) Rosario, Santa Fe (Argentina); Sennour, M. [MINES ParisTech, Centre des Materiaux - UMR CNRS 7633 - 91003, Evry Cedex (France); Balbi, M.; Alvarez-Armas, I. [Instituto de Fisica Rosario, Bv. 27 de Febrero 210 bis, (2000) Rosario, Santa Fe (Argentina); Thorel, A. [MINES ParisTech, Centre des Materiaux - UMR CNRS 7633 - 91003, Evry Cedex (France); Armas, A.F. [Instituto de Fisica Rosario, Bv. 27 de Febrero 210 bis, (2000) Rosario, Santa Fe (Argentina)

    2011-09-25

    Highlights: {center_dot} Dislocations bands and microbands are developed in {alpha} phase of fatigued aged DSS. {center_dot} Inside these structures, demodulation of spinodal decomposition (SD) were found. {center_dot} This fact could take part in the cyclic softening displayed by DSS S32750. {center_dot} Cyclic tests at 475 deg. C show a saturation stage at the end of fatigue life. {center_dot} This could be explained by the effect of demodulation and creation of SD. - Abstract: The present work is focused on assessing the influence of dislocation movement on spinodal decomposition through scanning transmission electron microscopy (STEM) in combination with energy dispersive X-ray spectroscopy (EDS) analysis in aged duplex stainless steel (DSS) S32750. Dislocation bands and microbands are the prominent dislocation arrangements observed in fatigue tested aged samples. By EDS measurements it was found that the spinodal decomposition was dissolved inside these dislocations structures. Therefore, the mechanism of microband formation developed in the ferritic phase during cycling seems to be responsible for the demodulation of the spinodal decomposition and cyclic softening of the aged DSS.

  8. Investigation of Hot Deformation Behavior of Duplex Stainless Steel Grade 2507

    Science.gov (United States)

    Kingklang, Saranya; Uthaisangsuk, Vitoon

    2017-01-01

    Recently, duplex stainless steels (DSSs) are being increasingly employed in chemical, petro-chemical, nuclear, and energy industries due to the excellent combination of high strength and corrosion resistance. Better understanding of deformation behavior and microstructure evolution of the material under hot working process is significant for achieving desired mechanical properties. In this work, plastic flow curves and microstructure development of the DSS grade 2507 were investigated. Cylindrical specimens were subjected to hot compression tests for different elevated temperatures and strain rates by a deformation dilatometer. It was found that stress-strain responses of the examined steel strongly depended on the forming rate and temperature. The flow stresses increased with higher strain rates and lower temperatures. Subsequently, predictions of the obtained stress-strain curves were done according to the Zener-Hollomon equation. Determination of material parameters for the constitutive model was presented. It was shown that the calculated flow curves agreed well with the experimental results. Additionally, metallographic examinations of hot compressed samples were performed by optical microscope using color tint etching. Area based phase fractions of the existing phases were determined for each forming condition. Hardness of the specimens was measured and discussed with the resulted microstructures. The proposed flow stress model can be used to design and optimize manufacturing process at elevated temperatures for the DSS.

  9. Investigation of Hot Deformation Behavior of Duplex Stainless Steel Grade 2507

    Science.gov (United States)

    Kingklang, Saranya; Uthaisangsuk, Vitoon

    2016-10-01

    Recently, duplex stainless steels (DSSs) are being increasingly employed in chemical, petro-chemical, nuclear, and energy industries due to the excellent combination of high strength and corrosion resistance. Better understanding of deformation behavior and microstructure evolution of the material under hot working process is significant for achieving desired mechanical properties. In this work, plastic flow curves and microstructure development of the DSS grade 2507 were investigated. Cylindrical specimens were subjected to hot compression tests for different elevated temperatures and strain rates by a deformation dilatometer. It was found that stress-strain responses of the examined steel strongly depended on the forming rate and temperature. The flow stresses increased with higher strain rates and lower temperatures. Subsequently, predictions of the obtained stress-strain curves were done according to the Zener-Hollomon equation. Determination of material parameters for the constitutive model was presented. It was shown that the calculated flow curves agreed well with the experimental results. Additionally, metallographic examinations of hot compressed samples were performed by optical microscope using color tint etching. Area based phase fractions of the existing phases were determined for each forming condition. Hardness of the specimens was measured and discussed with the resulted microstructures. The proposed flow stress model can be used to design and optimize manufacturing process at elevated temperatures for the DSS.

  10. Multiobjective optimization of friction welding of UNS S32205 duplex stainless steel

    Directory of Open Access Journals (Sweden)

    P.M. Ajith

    2015-06-01

    Full Text Available The present study is to optimize the process parameters for friction welding of duplex stainless steel (DSS UNS S32205. Experiments were conducted according to central composite design. Process variables, as inputs of the neural network, included friction pressure, upsetting pressure, speed and burn-off length. Tensile strength and microhardness were selected as the outputs of the neural networks. The weld metals had higher hardness and tensile strength than the base material due to grain refinement which caused failures away from the joint interface during tensile testing. Due to shorter heating time, no secondary phase intermetallic precipitation was observed in the weld joint. A multi-layer perceptron neural network was established for modeling purpose. Five various training algorithms, belonging to three classes, namely gradient descent, genetic algorithm and Levenberg–Marquardt, were used to train artificial neural network. The optimization was carried out by using particle swarm optimization method. Confirmation test was carried out by setting the optimized parameters. In conformation test, maximum tensile strength and maximum hardness obtained are 822 MPa and 322 Hv, respectively. The metallurgical investigations revealed that base metal, partially deformed zone and weld zone maintain austenite/ferrite proportion of 50:50.

  11. Surface properties and activation energy of superplastically carburized duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Ahamad, Nor Wahida, E-mail: wahida_um@yahoo.com [Department of Mechanical and Materials Engineering, Faculty of Engineering, University Malaya, Lembah Pantai, 50603 Kuala Lumpur (Malaysia); Jauhari, Iswadi, E-mail: iswadi@um.edu.my [Department of Mechanical and Materials Engineering, Faculty of Engineering, University Malaya, Lembah Pantai, 50603 Kuala Lumpur (Malaysia); Azis, Sharidah Azuar Abdul, E-mail: sharidah_azuar@yahoo.com [Department of Mechanical and Materials Engineering, Faculty of Engineering, University Malaya, Lembah Pantai, 50603 Kuala Lumpur (Malaysia); Aziz, Nur Hafizah Abd, E-mail: phiza_aziz@yahoo.com [Department of Mechanical and Materials Engineering, Faculty of Engineering, University Malaya, Lembah Pantai, 50603 Kuala Lumpur (Malaysia)

    2010-08-01

    A new surface carburizing technique which combines superplastic phenomenon and carburizing process called superplastic carburizing (SPC) was introduced and compared with conventional carburizing (CC) process. Thermomechanically treated duplex stainless steel (DSS) with a fine grain microstructure that exhibits superplasticity was used as the superplastic material. SPC was carried out at temperatures of 1198-1248 K and a compression rate of 1 x 10{sup -4} s{sup -1} for various durations. Metallographic studies revealed that a carbon layer with a uniform, dense and smooth morphology formed on all carburized specimens. The case depth of the carbon layer was between 50.8 and 159.1 {mu}m. A remarkable increase in surface hardness was observed in the range 389.9-1129.0 HV. Activation energy for SPC was determined as 183.4 kJ mol{sup -1}, which is lower compare to CC process. The results indicate that SPC accelerates the diffusion of carbon atoms into the surface of DSS, thus increasing the thickness of the carburized layer and the surface hardness, at lower activation energy.

  12. Effect of silver on microstructure and antibacterial property of 2205 duplex stainless steel.

    Science.gov (United States)

    Yang, Sheng-Min; Chen, Yi-Chun; Pan, Yeong-Tsuen; Lin, Dong-Yih

    2016-06-01

    In this study, 2205 duplex stainless steel (DSS) was employed to enhance the antibacterial properties of material through silver doping. The results demonstrated that silver-doped 2205 DSS produces an excellent bacteria-inhibiting effect against Escherichia coli and Staphylococcus aureus. The antibacterial rates were 100% and 99.5%, respectively. Because the mutual solubility of silver and iron is very low in both the solid and liquid states, a silver-rich compound solidified and dispersed at the ferrite/austenite interface and the ferrite, austenite, and secondary austenite phases in silver-doped 2205 DSS. Doping 2205 DSS with silver caused the Creq/Nieq ratio of ferrite to decrease; however, the lower Creq/Nieq ratio promoted the rapid nucleation of γ2-austenite from primary α-ferrite. After 12h of homogenisation treatment at 1200 °C, the solubility of silver in the γ-austenite and α-ferrite phases can be increased by 0.10% and 0.09%, respectively. Moreover, silver doping was found to accelerate the dissolution of secondary austenite in a ferrite matrix during homogenisation.

  13. Development of Cutting Tool Through Superplastic Boronizing of Duplex Stainless Steel

    Science.gov (United States)

    Jauhari, Iswadi; Harun, Sunita; Jamlus, Siti Aida; Sabri, Mohd Faizul Mohd

    2017-01-01

    In this study, a cutting tool is developed from duplex stainless steel (DSS) using the superplastic boronizing technique. The feasibility of the development process is studied, and the cutting performances of the cutting tool are evaluated and compared with commercially available carbide and high-speed steel (HSS) tools. The superplastically boronized (SPB) cutting tool yielded a dense boronized layer of 50.5 µm with a surface hardness of 3956 HV. A coefficient of friction value of 0.62 is obtained, which is lower than 1.02 and 0.8 of the carbide and HSS tools. When tested on an aluminum 6061 surface under dry condition, the SPB cutting tool is also able to produce turning finishing below 0.4 µm, beyond the travel distance of 3000 m, which is comparable to the carbide tool, but produces much better results than HSS tool. Through superplastic boronizing of DSS, it is possible to produce a high-quality metal-based cutting tool that is comparable to the conventional carbide tool.

  14. Evolutions of Microstructure and Properties During Cold Rolling of 19Cr Duplex Stainless Steel

    Science.gov (United States)

    Ran, Qingxuan; Xu, Wanjian; Wu, Zhaoyu; Li, Jun; Xu, Yulai; Xiao, Xueshan; Hu, Jincheng; Jiang, Laizhu

    2016-10-01

    Evolutions of microstructure, mechanical, and corrosion properties of 19Cr (Fe-18.9Cr-10.1Mn-0.3Ni-0.261N-0.030C-0.5Si) duplex stainless steel have been investigated during cold rolling at room temperature. Dislocation slip dominated deformation mode of ferrite phase. However, deformation mechanism of austenite phase was different with the increasing cold-rolling reductions. Dislocation slip and strengthening effect of twin boundaries caused pile-up phenomenon at the initial deformation stage. When the amount of cold-rolling reduction attained greater than 50 pct, induced α'-martensite appeared in deformed austenite phase. Hardness of austenite phase was higher than that of the deformed ferrite because of its higher strengthening effect during cold-rolling process. Cold-rolling deformation caused deterioration of the pitting corrosion resistance in 3.5 wt pct NaCl aqueous solution. Pitting corrosion always initiated in the ferrite phase and the phase boundary in the solution-treated alloy. Additional pitting holes appeared in deformed austenite phase because of the decrease in corrosion resistance caused by dislocation accumulation and induced α'-martensite.

  15. Characterization of a cold-rolled 2101 lean duplex stainless steel.

    Science.gov (United States)

    Bassani, Paola; Breda, Marco; Brunelli, Katya; Mészáros, Istvan; Passaretti, Francesca; Zanellato, Michela; Calliari, Irene

    2013-08-01

    Duplex stainless steels (DSS) may be defined as a category of steels with a two-phase ferritic-austenitic microstructure, which combines good mechanical and corrosion properties. However, these steels can undergo significant microstructural modification as a consequence of either thermo-mechanical treatments (ferrite decomposition, which causes σ- and χ-phase formation and nitride precipitation) or plastic deformation at room temperature [austenite transformation into strain-induced martensite (SIM)]. These secondary phases noticeably affect the properties of DSS, and therefore are of huge industrial interest. In the present work, SIM formation was investigated in a 2101 lean DSS. The material was subjected to cold rolling at various degrees of deformation (from 10 to 80% thickness reduction) and the microstructure developed after plastic deformation was investigated by electron backscattered diffraction, X-ray diffraction measurements, and hardness and magnetic tests. It was observed that SIM formed as a consequence of deformations higher than ~20% and residual austenite was still observed at 80% of thickness reduction. Furthermore, a direct relationship was found between microstructure and magnetic properties.

  16. Development of Cutting Tool Through Superplastic Boronizing of Duplex Stainless Steel

    Science.gov (United States)

    Jauhari, Iswadi; Harun, Sunita; Jamlus, Siti Aida; Sabri, Mohd Faizul Mohd

    2017-03-01

    In this study, a cutting tool is developed from duplex stainless steel (DSS) using the superplastic boronizing technique. The feasibility of the development process is studied, and the cutting performances of the cutting tool are evaluated and compared with commercially available carbide and high-speed steel (HSS) tools. The superplastically boronized (SPB) cutting tool yielded a dense boronized layer of 50.5 µm with a surface hardness of 3956 HV. A coefficient of friction value of 0.62 is obtained, which is lower than 1.02 and 0.8 of the carbide and HSS tools. When tested on an aluminum 6061 surface under dry condition, the SPB cutting tool is also able to produce turning finishing below 0.4 µm, beyond the travel distance of 3000 m, which is comparable to the carbide tool, but produces much better results than HSS tool. Through superplastic boronizing of DSS, it is possible to produce a high-quality metal-based cutting tool that is comparable to the conventional carbide tool.

  17. The characteristic of 2205 duplex stainless steel and application in natural gas pipeline

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    2205 duplex stainless steel (DSS) possesses favorable mechanical property and good corrosion resistance at the same time, and has been a new material and applied widely in petroleum,natural gas, ocean and chemistry industry etc from 1980's in some advanced countries and from 1990's in China. One natural gas headstream project possesses abundant natural gas and provides 80% of total quantity gas for West-East Pipeline Project. The project includes a 13 km length pipeline and a gas treatment plant that purify gas about 12 × 109 m3 every year. The Cl- concentration in the water separated from gas is about 10%, and so the corrosion of medium is very violent to the pipeline. 2205 DSS material has been applied successfully to the project in 2004. This is the first time of such a mass of DSS material application in a project in China. The characteristic of 2205 DSS and application in natural gas pipeline project has been introduced in this paper.

  18. SnO2:F Coated Duplex Stainless Steel for PEM Fuel Cell Bipolar Plates

    Energy Technology Data Exchange (ETDEWEB)

    Wang, H.; Turner, J. A.

    2008-01-01

    Duplex 2205 stainless steel was deposited with 0.6 {micro}m thick SnO2:F coating; coated steel was characterized for PEMFC bipolar plate application. Compared with bare alloy, interfacial contact resistance (ICR) values of the coated 2205 steel are higher. SnO2:F coating adds its own resistance to the air-formed film on the steel. In a PEMFC anode environment, a current peak of ca. 25 {micro}A/cm2 registered at ca. 30 min for coated 2205 steel. It stabilized at ca. 2.0 {approx} -1.0 {micro}A/cm2. This peak is related to the complicated process of coating dissolution and oxide-layer formation. Anodic-cathodic current transfer occurred at ca. 200 min polarization. In a PEMFC cathode environment, current was stable immediately after polarization. The stable current was ca. 0.5 {approx} 2.0 {micro}A/cm2 during the entire polarization period. AES depth profiles with tested samples and ICP analysis with the tested solutions confirmed the excellent corrosion resistance of the SnO2:F coated 2205 alloy in simulated PEMFC environments.

  19. Investigations on structure–property relationships of activated flux TIG weldments of super-duplex/austenitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Devendranath Ramkumar, K., E-mail: ramdevendranath@gmail.com; Bajpai, Ankur; Raghuvanshi, Shubham; Singh, Anshuman; Chandrasekhar, Aditya; Arivarasu, M.; Arivazhagan, N.

    2015-06-25

    This research work articulated the effect of SiO{sub 2} flux assisted tungsten inert gas (TIG) welding on the microstructure and mechanical properties of marine grade stainless steel weldments, such as super-duplex stainless steel (UNS S32750) and austenitic stainless steel (AISI 316L). The studies showed that the use of flux decreased the heat input required to obtain complete penetration. Microstructure studies revealed the presence of ferrite at the heat affected zone of AISI 316L and the fusion zone which obviated the hot cracking tendency. Tensile studies corroborated that the joint strength was sufficiently greater than that of the parent metals. Impact toughness slightly impoverished owing to the presence of large platelets of Widmanstätten austenite in the fusion zone. The study also explored the structure–property relationships of the flux assisted weldments using the combined techniques of optical and scanning electron microscopy analysis. Owing to the better metallurgical and mechanical properties, this study recommends the use of SiO{sub 2} flux for joining the dissimilar metals involving austenitic and super-duplex stainless steels.

  20. Characterization of Solidification and Solid State Transformation in Duplex Cast Steel: Thermo-Calc Investigation

    Directory of Open Access Journals (Sweden)

    Z. Stradomski

    2007-07-01

    Full Text Available The paper presents a characteristic of solidification process and changes occurring in the solid state in a duplex cast steel. Theoretical chemical composition of individual phases, its changes during solidification and cooling after solidification and also changes in volume fractions of phases versus temperature have been determined. Theoretical results of Thermo-Calc analysis have been correlated with the microstructure of as-cast cast steel as well as with analysis of chemical composition of individual phases, carried out on a scanning microscope equipped with an EDS attachment. It has been shown that at the carbon content of 0.1% the enrichment of residual liquid phase with carbon results in a peritectic reaction, changing the ferritic solidification model typical for cast steels with low carbon content. In the case of solidification grain boundary areas enrichment with carbon, chromium and molybdenum there is a possibility of carbides precipitation already in the liquid state, what increases propensity for hot cracking and reduces the quality of castings produced. A correlation between theoretical composition of ferrite, austenite and M23C6 carbides, determined based on Thermo-Calc software, and their actual composition determined based on local analyses of chemical composition carried out on a scanning microscope has been shown. The volume fractions of ferrite, austenite and carbides determined using Thermo-Calc software show a strong correlation with actual fractions of those phases in the examined alloy’s structure. The chemical composition of ferrite, austenite and carbides determined using Thermo-Calc software does not show any more such strong correlation with the actual chemical composition of those phases determined based on local analyses of chemical composition carried out using a scanning microscope.

  1. Optimization of Heat Treatment in Aspect of Production’s Costs Reducing and Improving of Casting Quality from Duplex Cast Steel

    Directory of Open Access Journals (Sweden)

    D. Dyja

    2007-07-01

    Full Text Available The paper determines possibilities of cost optimisation in the production of GX2CrNiMoCu25-6-3-3 type duplex cast steel castings through selection of appropriate solution heat treatment temperature, which value depends on the content of alloying elements. Metallographic analysis was carried out for as-cast and heat treated cast steel. Hardness and impact strength of the cast steel were determined, which were correlated with the volume fraction of phases determined by means of ImagePro computer image analyser. It has been shown that increased carbon content creates a need to use higher treatment temperatures, thereby increasing the production cost. With increasing carbon content the cast steel hardness after solution heat treatment increases, however, crack resistance decreases

  2. Influence of microstructure and elemental partitioning on pitting corrosion resistance of duplex stainless steel welding joints

    Science.gov (United States)

    Zhang, Zhiqiang; Jing, Hongyang; Xu, Lianyong; Han, Yongdian; Zhao, Lei; Zhang, Jianli

    2017-02-01

    The influences of microstructure and elemental partitioning on pitting corrosion resistance of duplex stainless steel joints welded by gas tungsten arc welding (GTAW) and flux-cored arc welding (FCAW) with different shielding gas compositions were studied by optical microscopy, electron backscatter diffraction, scanning electron microscopy, transmission electron microscopy, energy dispersive spectroscopy, electron probe microanalysis, and potentiostatic and potentiodynamic polarization methods The adding 2% N2 in shielding gas facilitated primary austenite formation in GTAW weld metal (WM) and suppressed Cr2N precipitation in GTAW weld root. In the HAZ, the banded microstructure disappeared while the coarse ferrite grains maintained same orientation as the banded ferrite in the BM. In the WM, the ferrite had one single orientation throughout a grain, whereas several families of austenite appeared. The austenite both in BM and WM enriched in Ni and nitro`gen, while Cr and Mo were concentrated in the ferrite and thus no element showed clear dendritic distribution in the WM (ER2209 and E2209T1). In addition, the secondary austenite had higher Ni content but lower Cr and Mo content than the primary austenite. The N2-supplemented shielding gas promoted nitrogen solid-solution in the primary and secondary austenite. Furthermore, the secondary austenite had relatively lower pitting resistance equivalent number (PREN) than the ferrite and primary austenite, thereby resulting in its preferential corrosion. The Cr2N precipitation led to relatively poor resistance to pitting corrosion in three HAZs and pure Ar shielding GTAW weld root. The N2-supplemented shielding gas improved pitting corrosion resistance of GTAW joint by increasing PREN of secondary austenite and suppressing Cr2N precipitation. In addition, the FCAW WM had much poorer resistance to pitting corrosion than the GTAW WM due to many O-Ti-Si-Mn inclusions. In the BM, since the austenite with lower PREN compared

  3. Electrochemical Corrosion Behavior ofthe Laser Continuous Heat Treatment Welded Joints of 2205 Duplex Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    LIU Heping; JIN Xuejun

    2011-01-01

    The electrochemical corrosion behaviors of the welded joints of 2205 duplex stainless steel with the laser continuous heat treatment were investigated.The secondary austenite formation is the outcome of thermodynamic equilibrium breach of the alloy during heat treatment and the result of the continuous heat treatment which has the most important effect on the weld material.The partitioning behaviors of chromium and molybdenum as well as the volume fraction of ferrite and austenite have a remarkable influence on the composition of the individual phase.Mechanical examination of the laser trated weld demonstrates that the tensile strength and yield strength increase with increasing the amount of the secondary austenite.It is shown that the ultimate tensile strength of the 6 kW laser-treated weld is higher about 20 MPa than no heat treatment weld and the ductility can be further improved without compromising strength.The results indicate that the welding alters the corrosion behavior because of different post heat treatment power and the broad active peak is not identified which is attributed to the dissolution of the secondary austenitic in the ferrite phase.It is indicated that pitting resistance equivalent (PRE) values of base metal and 6 kW weld are higher than that of other welds; base metal is 33.7,6 kW weld 33.3,no treatment 32.4,4 kW weld 32.8,8 kW weld 32.5.The extent of corrosion resistance improvement after reheating treatment is mainly caused by the removal of nitrogen from ferritic regions,which occurred as a consequence of secondary austenite growth.

  4. The Effect of Constant and Pulsed Current Gas Tungsten Arc Welding on Joint Properties of 2205 Duplex Stainless Steel to 316L Austenitic Stainless Steel

    Science.gov (United States)

    Neissi, R.; Shamanian, M.; Hajihashemi, M.

    2016-05-01

    In this study, dissimilar 316L austenitic stainless steel/2205 duplex stainless steel (DSS) joints were fabricated by constant and pulsed current gas tungsten arc welding process using ER2209 DSS as a filler metal. Microstructures and joint properties were characterized using optical and electron scanning microscopy, tensile, Charpy V-notch impact and micro-hardness tests, and cyclic polarization measurements. Microstructural observations confirmed the presence of chromium nitride and delta ferrite in the heat-affected zone of DSS and 316L, respectively. In addition, there was some deviation in the austenite/ferrite ratio of the surface welding pass in comparison to the root welding pass. Besides having lower pitting potential, welded joints produced by constant current gas tungsten arc welding process, consisted of some brittle sigma phase precipitates, which resulted in some impact energy reduction. The tensile tests showed high tensile strength for the weld joints in which all the specimens were broken in 316L base metal.

  5. Effect of microstructure on mechanical properties of a thin-walled cast duplex steel

    Energy Technology Data Exchange (ETDEWEB)

    Petzold, L.; Kreschel, T.; Peisker, D. [TU Bergakademie Freiberg, Institut fuer Eisen- und Stahltechnologie, Freiberg (Germany); Minnich, D. [Evosteel GmbH, Leipzig (Germany)

    2010-06-15

    The paper investigates the microstructure and the resulting mechanical properties of a duplex steel cast in sand dead-moulds. The chemical composition and the cooling rate are the main parameters affecting the properties. The chemical composition influences the thermodynamics of the phase transformation, the cooling rate determines the kinetics of formation of the microstructure. The latter varies with changes in wall thickness (investigated from 2 to 7 mm) and the position of the material within the casting. Through heat treatment, the composition of the microstructural components can be changed selectively afterwards, thereby the properties are improved. The correlation between microstructure and mechanical properties is explained quantitatively. Additionally to the austenite-ferrite ratio, the dispersion of microstructure has a large influence on the mechanical properties. Ranges of chemical composition and heat treatment parameters are identified where third phases, such as carbides and {sigma}-phase tend to occur. These influence the properties very sensitively even in small amounts. Finally, structural parameters are recognized that will lead to optimal combinations of properties. With an appropriate heat treatment technique, in particular the ductility properties are further increased. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  6. Weldability and Welding Technique of 2101 Duplex Stainless Steel%2101双相不锈钢的焊接性能和焊接技术

    Institute of Scientific and Technical Information of China (English)

    刘长文; 邓钢; 曾广庭

    2012-01-01

    对2101双相不锈钢的焊接性能进行了分析,并提出了几个关键的焊接技术,最后以12.7mm厚2101双相不锈钢板为例,进行了该材料的焊接工艺评定。结果表明:在合理的焊接方法和焊接参数下,2101双相不锈钢具有良好的焊接性能。%Weldability of 2101 duplex stainless steel was analyzed, several key welding techniques were put forward, and finally welding procedure qualification was done taken 12. 7 mm 2101 duplex stainless steel plate as an example. The results show that 2101 duplex stainless steel has good welding performance under the condition of reasonable welding method and welding parameters.

  7. Monte Carlo simulation of spinodal decomposition in a ternary alloy within a three-phases field: comparison to phase transformation of ferrite in duplex stainless steels

    Science.gov (United States)

    Emo, Jonathan; Pareige, Cristelle; Saillet, Sébastien; Domain, Christophe; Pareige, Philippe

    2014-06-01

    This work proposes to model phase transformations occurring in duplex stainless steels using atomistic kinetic Monte Carlo in a ternary model alloy. Kinetics are simulated in the three-phase field of a ternary system. Influence of the precipitation of the third phase on the kinetic of spinodal decomposition between the two other phases is studied in order to understand the synergy between spinodal decomposition and G-phase precipitation which exists in duplex stainless steels. Simulation results are compared to experimental data obtained with atom probe tomography.

  8. Effect of electromagnetic interaction during fusion welding of AISI 2205 duplex stainless steel on the corrosion resistance

    Science.gov (United States)

    García-Rentería, M. A.; López-Morelos, V. H.; González-Sánchez, J.; García-Hernández, R.; Dzib-Pérez, L.; Curiel-López, F. F.

    2017-02-01

    The effect of electromagnetic interaction of low intensity (EMILI) applied during fusion welding of AISI 2205 duplex stainless steel on the resistance to localised corrosion in natural seawater was investigated. The heat affected zone (HAZ) of samples welded under EMILI showed a higher temperature for pitting initiation and lower dissolution under anodic polarisation in chloride containing solutions than samples welded without EMILI. The EMILI assisted welding process developed in the present work enhanced the resistance to localised corrosion due to a modification on the microstructural evolution in the HAZ and the fusion zone during the thermal cycle involved in fusion welding. The application of EMILI reduced the size of the HAZ, limited coarsening of the ferrite grains and promoted regeneration of austenite in this zone, inducing a homogeneous passive condition of the surface. EMILI can be applied during fusion welding of structural or functional components of diverse size manufactured with duplex stainless steel designed to withstand aggressive environments such as natural seawater or marine atmospheres.

  9. Effects of Cold Rolling and Strain-Induced Martensite Formation in a SAF 2205 Duplex Stainless Steel

    Science.gov (United States)

    Breda, Marco; Brunelli, Katya; Grazzi, Francesco; Scherillo, Antonella; Calliari, Irene

    2015-02-01

    Duplex stainless steels (DSSs) are biphasic steels having a ferritic-austenitic microstructure that allows them to combine good mechanical and corrosion-resistance properties. However, these steels are sensitive to microstructural modifications, such as ferrite decomposition at high temperatures and the possibility of strain-induced martensite (SIM) formation from cold-worked austenite, which can significantly alter their interesting features. In the present work, the effects of cold rolling on the developed microstructural features in a cold-rolled SAF 2205 DSS and the onset of martensitic transformation are discussed. The material was deformed at room temperature from 3 to 85 pct thickness reduction, and several characterization techniques (scanning and transmission electron microscopy, X-ray diffraction, hardness measurements, and time-of-flight-neutron diffraction) were employed in order to fully describe the microstructural behavior of the steel. Despite the low stacking fault energy of DSS austenite, which contributed to SIM formation, the steel was found to be more stable than other stainless steel grades, such as AISI 304L. Rolling textures were similar to those pertaining to single-phase materials, but the presence of the biphasic (Duplex) microstructure imposed deformation constraints that affected the developed microstructural features, owing to phases interactions. Moreover, even if an intensification of the strain field in austenite was revealed, retarded SIM transformation kinetics and lower martensite amounts with respect to AISI 304L were observed.

  10. High-Temperature Phase Equilibria of Duplex Stainless Steels Assessed with a Novel In-Situ Neutron Scattering Approach

    Science.gov (United States)

    Pettersson, Niklas; Wessman, Sten; Hertzman, Staffan; Studer, Andrew

    2017-01-01

    Duplex stainless steels are designed to solidify with ferrite as the parent phase, with subsequent austenite formation occurring in the solid state, implying that, thermodynamically, a fully ferritic range should exist at high temperatures. However, computational thermodynamic tools appear currently to overestimate the austenite stability of these systems, and contradictory data exist in the literature. In the present work, the high-temperature phase equilibria of four commercial duplex stainless steel grades, denoted 2304, 2101, 2507, and 3207, with varying alloying levels were assessed by measurements of the austenite-to-ferrite transformation at temperatures approaching 1673 K (1400 °C) using a novel in-situ neutron scattering approach. All grades became fully ferritic at some point during progressive heating. Higher austenite dissolution temperatures were measured for the higher alloyed grades, and for 3207, the temperature range for a single-phase ferritic structure approached zero. The influence of temperatures in the region of austenite dissolution was further evaluated by microstructural characterization using electron backscattered diffraction of isothermally heat-treated and quenched samples. The new experimental data are compared to thermodynamic calculations, and the precision of databases is discussed.

  11. Influence of the filler material on the pitting corrosion in welded duplex stainless; Influencia del material de aporte en la resistencia a corrosion por picadura en uniones soldadas de un acero inoxidable duplex

    Energy Technology Data Exchange (ETDEWEB)

    Munez, C. J.; Utrilla, M. V.; Urena, A.; Otero, E.

    2007-07-01

    In this work, it has been studied the pitting corrosion resistance of welding duplex stainless steel 2205. Unions were made by GMAW process with different fillers: duplex ER 2209 and two austenitic (ER 316LSi and ER 308LSi). the microstructure obtained with the duplex ER 2209 filler is similar to the duplex 2205 base material, but the unions produced with the austenitic fillers cause a decrease of the phases relation{alpha}/{gamma}. To evaluate the influence of the filler on the weld, the pitting corrosion resistance was determined by electrochemical critical pitting temperature test (TCP) and the mechanical properties by the hardness. The phases imbalance produced for the dissimilar fillers bring out a variation of the pitting corrosion resistance and the mechanical properties. (Author)

  12. Advanced manufacturing technologies of large martensitic stainless steel castings with ultra low carbon and high cleanliness

    Directory of Open Access Journals (Sweden)

    Lou Yanchun

    2010-11-01

    Full Text Available The key manufacturing technologies associated with composition, microstructure, mechanical properties, casting quality and key process control for large martensitic stainless steel castings are involved in this paper. The achievements fully satisfied the technical requirements of the large 700 MW stainless steel hydraulic turbine runner for the Three Gorges Hydropower Station, and become the major technical support for the design and manufacture of the largest 700 MW hydraulic turbine generator unit in the world developed through our own efforts. The characteristics of a new high yield to tensile strength (Rp0.2/Rm ratio and high obdurability martensitic stainless steel with ultra low carbon and high cleanliness are also described. Over the next ten years, the large martensitic stainless steel castings and advanced manufacturing technologies will see a huge demand in clean energy industry such as nuclear power, hydraulic power at home and abroad. Therefore, the new high yield o tensile strength (Rp0.2/Rm ratio and high obdurability martensitic stainless steel materials, the fast and flexible manufacturing technologies of large size castings, and new environment friendly sustainable process will face new challenges and opportunities.

  13. Influence of Trace Alloying Elements on Corrosive Resistance of Cast Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    DUAN Han-qiao; YAN Xiang; WEI Bo-kang; LIN Han-tong

    2005-01-01

    The influences of trace alloying elements niobium, vanadium and zirconium on the corrosive resistance of 18-8 type cast stainless steel have been studied in deta() orthogonal design experiments. The results show that zirconium is mainly in the form of compound inclusions, which is unfavorable to promote the corrosive resistance of the cast stainless steel. It can alleviate the disadvantageous influence of carbon addition on corrosive resistance when some elements such as vanadium and niobium exist in the steel, and niobium has a remarkable influence on the intergranular corrosive resistance but unobvious on the pitting corrosion, and vanadium has a slightly favorable influence on the corrosive resistance of the steel.

  14. Detailed Microstructural Characterization and Restoration Mechanisms of Duplex and Superduplex Stainless Steel Friction-Stir-Welded Joints

    Science.gov (United States)

    Santos, T. F. A.; Torres, E. A.; Lippold, J. C.; Ramirez, A. J.

    2016-12-01

    Duplex stainless steels are successfully used in a wide variety of applications in areas such as the food industry, petrochemical installations, and sea water desalination plants, where high corrosion resistance and high mechanical strength are required. However, during fusion welding operations, there can be changes to the favorable microstructure of these materials that compromise their performance. Friction stir welding with a non-consumable pin enables welded joints to be obtained in the solid state, which avoids typical problems associated with solidification of the molten pool, such as segregation of alloying elements and the formation of solidification and liquefaction cracks. In the case of superduplex stainless steels, use of the technique can avoid unbalanced proportions of ferrite and austenite, formation of deleterious second phases, or growth of ferritic grains in the heat-affected zone. Consolidated joints with full penetration were obtained for 6-mm-thick plates of UNS S32101 and S32205 duplex stainless steels, and S32750 and S32760 superduplex steels. The welding heat cycles employed avoided the conditions required for formation of deleterious phases, except in the case of the welded joint of the S32760 steel, where SEM images indicated the formation of secondary phases, as corroborated by decreased mechanical performance. Analysis using EBSD and transmission electron microscopy revealed continuous dynamic recrystallization by the formation of cellular arrays of dislocations in the ferrite and discontinuous dynamic recrystallization in the austenite. Microtexture evaluation indicated the presence of fibers typical of shear in the thermomechanically affected zone. These fibers were not obviously present in the stir zone, probably due to the intensity of microstructural reformulation to which this region was subjected.

  15. Influence of the post-weld surface treatment on the corrosion resistance of the duplex stainless steel 1.4062

    Science.gov (United States)

    Rosemann, P.; Müller, C.; Baumann, O.; Modersohn, W.; Halle, T.

    2017-03-01

    The duplex stainless steel 1.4062 (X2CrNiN22-2) is used as alternative material to austenitic stainless steels in the construction industry. The corrosion resistance of welded seams is influenced by the base material, the weld filler material, the welding process and also by the final surface treatment. The scale layer next to the weld seam can be removed by grinding, pickling, electro-polished or blasting depending on the application and the requested corrosion resistance. Blasted surfaces are often used in industrial practice due to the easier and cheaper manufacturing process compared to pickled or electro-polished surfaces. Furthermore blasting with corundum-grain is more effective than blasting with glass-beads which also lower the process costs. In recent years, stainless steel surfaces showed an unusually high susceptibility to pitting corrosion after grinding with corundum. For this reason, it is now also questioned critically whether the corrosion resistance is influenced by the applied blasting agent. This question was specifically investigated by comparing grinded, pickled, corundum-grain- and glass-bead-blasted welding seams. Results of the SEM analyses of the blasting agents and the blasted surfaces will be presented and correlated with the different performed corrosion tests (potential measurement, KorroPad-test and pitting potential) on welding seams with different surface treatments.

  16. Influence of Vanadium and Cast Temperature on Nitrogen Solubility of Stainless Steel

    Directory of Open Access Journals (Sweden)

    Saeed Ghali

    2014-01-01

    Full Text Available Three stainless steel grades with different vanadium content were produced in open induction furnace. The base chemical composition of investigated stainless steel has contained 18.48–18.75% Cr, 5.17–5.62% Mn, 2.47–2.58% Mo, and 6.39–6.64% Ni. The vanadium contents of the three stainless steel grades were 0.009%, 0.112%, and 0.189%. The proposed stainless steels were casted at temperatures 1753 K and 1833 K. The nitrogen contents were determined for the produced steel grades at every cast temperature. The determined nitrogen contents were compared with those calculated from the developed equation of Grigorenko and Pomarin. The influence of cast temperature and vanadium content on nitrogen solubility was investigated. Interpretation between experimental and calculated nitrogen content was carried out. Increasing vanadium content and decreasing cast temperature were found to have positive significant effect on the nitrogen solubility. There were great deviations between experimental results and those calculated by Grigorenko and Pomarin equation.

  17. Sigma Phase Precipitation and Properties of Super-duplex Stainless Steel UNS S32750 Aged at the Nose Temperature

    Institute of Scientific and Technical Information of China (English)

    ZOU Dening; HAN Ying; ZHANG Wei; YU Junhui

    2011-01-01

    The nose temperature for σ-phase precipitation in super-duplex stainless steel (SDSS) UNS S32750 was evaluated by hardness method. Color-optical microscopy, scanning electron microscopy, energy spectrum analysis, impact and corrosion testing were carried out to investigate characteristics of microstructure and properties of the SDSS aged at the nose temperature. The experimental results indicate that the nose temperature of precipitation is 920 ℃ and aging at this temperature tiny σ phases can precipitate at phase interfaces or ferrite grain boundaries within 2 min.Prolonging aging duration the amount of σ-phase increases and a dual structure with σ and γ is obtained when aging for 120 min. The precipitation of σ-phase leads to severe deterioration in impact toughness (longitudinal/transverse direction) and corrosion resistance of SDSS.

  18. Investigations on the microstructure and mechanical properties of multi-pass PCGTA welding of super-duplex stainless steel

    Indian Academy of Sciences (India)

    K Devendranath Ramkumar; Debidutta Mishra; G Thiruvengatam; S P Sudharsan; Tadikonda Harsha Mohan; Vimal Saxena; Rachit Pandey; N Arivazhagan

    2015-08-01

    This paper addresses the weldability, microstructure and mechanical properties of the multi-pass welding of super-duplex stainless steel (SDSS). Pulsed current gas tungsten arc welding (PCGTAW) was carried out employing ER2553 and ERNiCrMo-4 fillers. Microstructure examination showed the presence of austenite in different forms at the weld zone of ER2553 whereas multi-directional grain growth was observed for ERNiCrMo-4 welds. Tensile and impact studies corroborated that the weldments employing ER2553 exhibited better results compared with ERNiCrMo-4 weldments. Detailed structure–property relationships of the weldments have been reported in the present study. The results corroborated that the enhanced properties could be achieved with the matching filler wire compared with the over-alloyed filler.

  19. Cavitation Erosion Behavior of CrMnN Duplex Stainless Steel in Distilled Water and 3% NaCl Solution

    Institute of Scientific and Technical Information of China (English)

    Suzhen LUO; Yugui ZHENG; Wei LIU; Heming JING; Zhiming YAO; Wei KE

    2003-01-01

    The cavitation erosion (CE) behavior of CrMnN ferrite-austenite duplex stainless steel in distilled water and 3% NaCl solution was investigated by using a magnetostrictive-induced CE facility. The damaged surfaces were observed by scanning electron microscope (SEM). It was found that the CE resistance of CrMnN steel was higher than that of 0Cr13Ni5Mo steel. The mass loss rate of CrMnN steel in distilled water was similar to that in 3% NaCl except at the early stage of CE. The failure mode of ferrite phase was brittle fracture, which had adverse effect on the resistance to CE, while the failure of austenite phase was a ductile failure in CrMnN steel. The excellent resistance to CE was related to the good mechanical properties of austenitic phase and the consumption of CE energy by plastic deformation involving slip and twinning.

  20. Thermally Sprayed Aluminum (TSA) Coatings for Extended Design Life of 22%Cr Duplex Stainless Steel in Marine Environments

    Science.gov (United States)

    Paul, S.; Shrestha, S.; Lee, C. M.; Harvey, M. D. F.

    2013-03-01

    In this article, evaluation of sealed and unsealed thermally sprayed aluminum (TSA) for the protection of 22%Cr duplex stainless steel (DSS) from corrosion in aerated, elevated temperature synthetic seawater is presented. The assessments involved general and pitting corrosion tests, external chloride stress corrosion cracking (SCC), and hydrogen-induced stress cracking (HISC). These tests indicated that DSS samples, which would otherwise fail on their own in a few days, did not show pitting or fail under chloride SCC and HISC conditions when coated with TSA (with or without a sealant). TSA-coated specimens failed only at very high stresses (>120% proof stress). In general, TSA offered protection to the underlying or exposed steel by cathodically polarizing it and forming a calcareous deposit in synthetic seawater. The morphology of the calcareous deposit was found to be temperature dependent and in general was of duplex nature. The free corrosion rate of TSA in synthetic seawater was measured to be ~5-8 μm/year at ~18 °C and ~6-7 μm/year at 80 °C.

  1. Superplastic deformation of commercial 00Cr22Ni5Mo3N0.17 duplex stainless steel

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The superplastic behavior of a commercial duplex stainless steel has been studied by means of isothermal hot tensile testat temperatures of 850-1050℃ for the initial strain rates ranging from 3×l0-4 s-1 to 5X10-2 s-1. At 960℃, the best superplastic de-formation that caused the maximum elongation greater than 840% was obtained for an initial strain rate of 1.2×10-3 s-1. At 850℃, thebest elongation 500% was achieved for an initial strain rate of 2.5×10-3 s-1. During the deformation in higher temperature region,coarse γ grains formed during the prior treatments were broken into spherical particles, resulting in a homogeneous dispersion of γparticles within the δ-ferrite matrix. However, at lower temperatures between 800 and 950℃, the σ phase was formed through theeutectoid decomposition of δ→γ+σ, resulting finally in the stable equiaxed micro-duplex structures with δ/γ and γ/σ, respectively.The precipitation of the σ phase played an important role in improving the superplasticity at 850℃. The strain-rate sensitivity coeffi-cient, m-values, were also determined by the strain rate change tests. The microstructure studies show that the superplastic processoccurs mainly by the local work hardening and the subsequent dynamic recrystallization and a grain boundary sliding and grain switching mechanism.

  2. The corrosion behaviour of austenitic and duplex stainless steels in artificial saliva with the addition of fluoride

    Energy Technology Data Exchange (ETDEWEB)

    Kocijan, Aleksandra, E-mail: Aleksandra.Kocijan@imt.s [Institute of Metals and Technology, Lepi pot 11, 1000 Ljubljana (Slovenia); Merl, Darja Kek [Jozef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia); Jenko, Monika [Institute of Metals and Technology, Lepi pot 11, 1000 Ljubljana (Slovenia)

    2011-02-15

    Research highlights: The corrosion behaviour of AISI 316L and 2205 DSS in orthodontics. The increased passive range for DSS 2205 compared to AISI 316L in artificial saliva. Higher R{sub p} values of DSS compared to AISI 316L in artificial saliva. The main constituent of the passive layers on DSS at the OCP in saliva was Cr-oxide. DSS 2205 is suitable for orthodontic applications in artificial saliva. - Abstract: The evolution of the passive films on 2205 duplex stainless steel (2205 DSS) and AISI 316L stainless steel in artificial saliva, and with the addition of fluoride, was studied using electrochemical impedance spectroscopy (EIS) and potentiodynamic measurements. The extent of the passive range increased for the 2205 DSS compared to the AISI 316L in both solutions. The formation of the passive film was studied by EIS at the open-circuit potential (OCP). The passive layers were studied at the OCP by X-ray photoelectron spectroscopy (XPS). The passive films on both materials predominantly contained Cr-oxides, whereas the Fe species were markedly depleted.

  3. Cracking susceptibility of duplex stainless steel in the presence of H{sub 2}S-containing environments at an intermediate temperature

    Energy Technology Data Exchange (ETDEWEB)

    Maldonado, Julio G.; Kane, Russell D. [InterCorr International, Inc., 14503 Bammel N. Houston, Suite 300, Houston, Texas 77014 (United States); Skogsberg, James W. [ChevronTexaco, 4800 Fournace Pl, Bellaire, Texas 77401 (United States)

    2004-07-01

    The use of duplex stainless steels in the oil and gas industry has received special consideration due to their good corrosion resistance, mechanical properties and weldability. Specifically, duplex stainless steels possess excellent chloride pitting resistance and stress corrosion cracking resistance. In this study, the cracking susceptibility of duplex stainless steel at 80 deg. C in the presence of H{sub 2}S containing environments was investigated. Specifically, environments containing 1,000 ppm and 100,000 ppm Cl- brines with a pH of 3 and 4.5, respectively, and with H{sub 2}S partial pressures of 1.5, 5 and 10 psia (10, 34 and 69 kPa abs) were employed for the evaluation. The cracking susceptibility of the duplex stainless steel material was only evaluated with respect to the solution-annealed condition. For the experimental work, sub-size tensile specimens of annealed 2205 duplex (UNS S31803/S32205) stainless steel under a sustained load, with the use of proving rings, were tested in triplicate with exposure durations of up to 90 days. Cyclic polarization scans were also conducted for each of the environments selected for the cracking susceptibility study. The electrochemical work was conducted to ascertain the differences in the breakdown potential, hence, pitting potential and resulting cracking susceptibility of the material under the environmental conditions evaluated. The results of this work indicated that duplex stainless steel in the solution-annealed condition was resistant to sulfide stress cracking up to a partial pressure of H{sub 2}S of 5 psia (34 kPa abs). Only one specimen in each of the two Cl-/pH combined conditions with an applied H{sub 2}S partial pressure of 10 psia (69 kPa abs) failed during the 90-day exposure. These results suggest a possible extension on the applicability of the material in terms of the maximum allowed H{sub 2}S partial pressure in the NACE MR0175 document. (authors)

  4. Structure and mechanical properties of improved cast stainless steels for nuclear applications

    Science.gov (United States)

    Kenik, E. A.; Busby, J. T.; Gussev, M. N.; Maziasz, P. J.; Hoelzer, D. T.; Rowcliffe, A. F.; Vitek, J. M.

    2017-01-01

    Casting of stainless steels is a promising and cost saving way of directly producing large and complex structures, such a shield modules or divertors for the ITER. In the present work, a series of modified high-nitrogen cast stainless steels has been developed and characterized. The steels, based on the cast equivalent of the composition of 316 stainless steel, have increased N (0.14-0.36%) and Mn (2-5.1%) content; copper was added to one of the heats. Mechanical tests were conducted with non-irradiated and 0.7 dpa neutron irradiated specimens. It was established that alloying by nitrogen significantly improves the yield stress of non-irradiated steels and the deformation hardening rate. Manganese tended to decrease yield stress but increased radiation hardening. The role of copper on mechanical properties was negligibly small. Analysis of structure was conducted using SEM-EDS and the nature and compositions of the second phases and inclusions were analyzed in detail. No ferrite formation or significant precipitation were observed in the modified steels. It was shown that the modified steels, compared to reference material (commercial cast 316L steel), had better strength level, exhibit significantly reduced elemental inhomogeneity and only minor second phase formation.

  5. Corrosion Resistance and Mechanical Properties of TIG and A-TIG Welded Joints of Lean Duplex Stainless Steel S82441 / 1.4662

    Directory of Open Access Journals (Sweden)

    Brytan Z.

    2016-06-01

    Full Text Available This paper presents results of pitting corrosion resistance of TIG (autogenous and with filler metal and A-TIG welded lean duplex stainless steel S82441/1.4662 evaluated according to ASTM G48 method, where autogenous TIG welding process was applied using different amounts of heat input and shielding gases like pure Ar and Ar+N2 and Ar+He mixtures. The results of pitting corrosion resistance of the welded joints of lean duplex stainless steel S82441 were studied in as weld conditions and after different mechanical surface finish treatments. The results of the critical pitting temperature (CPT determined according to ASTM G48 at temperatures of 15, 25 and 35°C were presented. Three different surface treatment after welding were applied: etching, milling, brushing + etching. The influence of post weld surface treatment was studied in respect to the pitting corrosion resistance, basing on CPT temperature.

  6. Electron work functions of ferrite and austenite phases in a duplex stainless steel and their adhesive forces with AFM silicon probe.

    Science.gov (United States)

    Guo, Liqiu; Hua, Guomin; Yang, Binjie; Lu, Hao; Qiao, Lijie; Yan, Xianguo; Li, Dongyang

    2016-02-12

    Local electron work function, adhesive force, modulus and deformation of ferrite and austenite phases in a duplex stainless steel were analyzed by scanning force microscopy. It is demonstrated that the austenite has a higher electron work function than the ferrite, corresponding to higher modulus, smaller deformation and larger adhesive force. Relevant first-principles calculations were conducted to elucidate the mechanism behind. It is demonstrated that the difference in the properties between austenite and ferrite is intrinsically related to their electron work functions.

  7. Superficial integrity analysis in a super duplex stainless steel after turning

    OpenAIRE

    E.C. Bordinassi; M.F . Stipkovic; G.F. Batalha; S. Delijaicov; LIMA, N.B.

    2006-01-01

    Purpose: Purpose of this paper was to study the main effects of the turning in the superficial integrity of theduplex stainless steel ASTM A890-Gr6A.Design/methodology/approach: The focus of the work was the finishing operations and a complete factorialplanning was used, with 2 levels and 5 factors. The tests were conducted on a turning center with carbidetools and the main entrances variables were: tool material class, feed rate, cutting depth, cutting speed andcutting fluid utilization. The...

  8. The effect of chloride ions on the corroded surface layer of 00Cr22Ni5Mo3N duplex stainless steel under cavitation.

    Science.gov (United States)

    Wan, Tong; Xiao, Ning; Shen, Hanjie; Yong, Xingyue

    2016-11-01

    The effects of Cl(-) on the corroded surface layer of 00Cr22Ni5Mo3N duplex stainless steel under cavitation in chloride solutions were investigated using nanoindentation in conjunction with XRD and XPS. The results demonstrate that Cl(-) had a strong effect on the nano-mechanical properties of the corroded surface layer under cavitation, and there was a threshold Cl(-) concentration. Furthermore, a close relationship between the nano-mechanical properties and the cavitation corrosion resistance of 00Cr22Ni5Mo3N duplex stainless steel was observed. The degradation of the nano-mechanical properties of the corroded surface layer was accelerated by the synergistic effect between cavitation erosion and corrosion. A key factor was the adsorption of Cl(-), which caused a preferential dissolution of the ferrous oxides in the passive film layer on the corroded surface layer. Cavitation further promoted the preferential dissolution of the ferrous oxides in the passive film layer. Simultaneously, cavitation accelerated the erosion of the ferrite in the corroded surface layer, resulting in the degradation of the nano-mechanical properties of the corroded surface layer on 00Cr22Ni5Mo3N duplex stainless steel under cavitation.

  9. Surface analysis of localized corrosion of austenitic 316L and duplex 2205 stainless steels in simulated body solutions

    Energy Technology Data Exchange (ETDEWEB)

    Conradi, Marjetka, E-mail: marjetka.conradi@imt.si [Institute of Metals and Technology, Lepi pot 11, 1000 Ljubljana (Slovenia); Schoen, Peter M. [Materials Science and Technology of Polymers and MESA Institute for Nanotechnology, University of Twente, Enschede 7500 AE (Netherlands); Kocijan, Aleksandra; Jenko, M. [Institute of Metals and Technology, Lepi pot 11, 1000 Ljubljana (Slovenia); Vancso, G. Julius [Materials Science and Technology of Polymers and MESA Institute for Nanotechnology, University of Twente, Enschede 7500 AE (Netherlands)

    2011-10-17

    Highlights: {yields} In situ steel surface morphology observations in simulated body solutions. {yields} Pitting, square-like and elliptic-like corrosion products. {yields} Corrosion products' shapes related to the growth of Cr and Fe oxides. {yields} Direct relation of the size of the deposition products to surface roughness. - Abstract: We report on cyclic voltammetry and in situ electrochemical atomic force microscopy (EC-AFM) studies of localized corrosion of duplex 2205 stainless steel (DSS 2205) and austenitic stainless steel of the type AISI 316L in two model solutions, including artificial saliva (AS) and a simulated physiological solution known as - Hank's solution (PS). The AFM topography analysis illustrated the higher corrosion resistance of DSS 2205 steel for the chosen range of electrochemical potentials that were applied to the steel surface in both solutions. In contrast, pitting corrosion was observed at the surface of AISI 316L steel, with the pits becoming more evident, larger and deeper, when the sample was electrochemically treated in the PS. On both surfaces the growth of corrosion products formed during the oxidation process was observed. As a result, depending on the sample's metallurgical structure, different types of oxides covered the surface close to the breakdown potential. We distinguished between the square-like type of oxides on the surface of the DSS 2205, and the AISI 316L with its ellipse-like oxide deposits. The X-ray photoelectron spectroscopy (XPS) revealed the chemical composition of the deposition products, which consisted of two main elements, Fe and Cr. However, the oxides of the alloying elements Ni and Mo were negligible compared to the bulk.

  10. Effect of Annealing Temperature on the Mechanical and Corrosion Behavior of a Newly Developed Novel Lean Duplex Stainless Steel

    Directory of Open Access Journals (Sweden)

    Yanjun Guo

    2014-09-01

    Full Text Available The effect of annealing temperature (1000–1150 °C on the microstructure evolution, mechanical properties, and pitting corrosion behavior of a newly developed novel lean duplex stainless steel with 20.53Cr-3.45Mn-2.08Ni-0.17N-0.31Mo was studied by means of optical metallographic microscopy (OMM, scanning electron microscopy (SEM, magnetic force microscopy (MFM, scanning Kelvin probe force microscopy (SKPFM, energy dispersive X-ray spectroscopy (EDS, uniaxial tensile tests (UTT, and potentiostatic critical pitting temperature (CPT. The results showed that tensile and yield strength, as well as the pitting corrosion resistance, could be degraded with annealing temperature increasing from 1000 up to 1150 °C. Meanwhile, the elongation at break reached the maximum of 52.7% after annealing at 1050 °C due to the effect of martensite transformation induced plasticity (TRIP. The localized pitting attack preferentially occurred at ferrite phase, indicating that the ferrite phase had inferior pitting corrosion resistance as compared to the austenite phase. With increasing annealing temperature, the pitting resistance equivalent number (PREN of ferrite phase dropped, while that of the austenite phase rose. Additionally, it was found that ferrite possessed a lower Volta potential than austenite phase. Moreover, the Volta potential difference between ferrite and austenite increased with the annealing temperature, which was well consistent with the difference of PREN.

  11. Real Time Imaging of Deuterium in a Duplex Stainless Steel Microstructure by Time-of-Flight SIMS

    Science.gov (United States)

    Sobol, O.; Straub, F.; Wirth, Th.; Holzlechner, G.; Boellinghaus, Th.; Unger, W. E. S.

    2016-02-01

    For more than one century, hydrogen assisted degradation of metallic microstructures has been identified as origin for severe technical component failures but the mechanisms behind have not yet been completely understood so far. Any in-situ observation of hydrogen transport phenomena in microstructures will provide more details for further elucidation of these degradation mechanisms. A novel experiment is presented which is designed to elucidate the permeation behaviour of deuterium in a microstructure of duplex stainless steel (DSS). A hydrogen permeation cell within a TOF-SIMS instrument enables electrochemical charging with deuterium through the inner surface of the cell made from DSS. The outer surface of the DSS permeation cell exposed to the vacuum has been imaged by TOF-SIMS vs. increasing time of charging with subsequent chemometric treatment of image data. This in-situ experiment showed evidently that deuterium is permeating much faster through the ferrite phase than through the austenite phase. Moreover, a direct proof for deuterium enrichment at the austenite-ferrite interface has been found.

  12. Direct Observations of Sigma Phase Formation in Duplex Stainless Steels using In Situ Synchrotron X-Ray Diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Elmer, J W; Palmer, T A; Specht, E D

    2006-07-03

    The formation and growth of sigma phase in 2205 duplex stainless steel was observed and measured in real time using synchrotron radiation during 10 hr isothermal heat treatments at temperatures between 700 C and 850 C. Sigma formed in near-equilibrium quantities during the isothermal holds, starting from a microstructure which contained a balanced mixture of metastable ferrite and austenite. In situ synchrotron diffraction continuously monitored the transformation, and these results were compared to those predicted by thermodynamic calculations. Differences between the calculated and measured amounts of sigma, ferrite and austenite suggest that the thermodynamic calculations underpredict the sigma dissolution temperature by approximately 50 C. The data were further analyzed using a modified Johnson-Mehl-Avrami (JMA) approach to determine kinetic parameters for sigma formation over this temperature range. The initial JMA exponent, n, at low fractions of sigma was found to be approximately 7.0, however, towards the end of the transformation, n decreased to values of approximately 0.75. The change in the JMA exponent was attributed to a change in the transformation mechanism from discontinuous precipitation with increasing nucleation rate, to growth of the existing sigma phase after nucleation site saturation occurred. Because of this change in mechanism, it was not possible to determine reliable values for the activation energy and pre-exponential terms for the JMA equation. While cooling back to room temperature, the partial transformation of austenite resulted in a substantial increase in the ferrite content, but sigma retained its high temperature value to room temperature.

  13. Characterization of Low Temperature Ferrite/Austenite Transformations in the Heat Affected Zone of 2205 Duplex Stainless Steel Arc Welds

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, T A; Elmer, J W; Babu, S S; Vitek, J M

    2003-08-20

    Spatially Resolved X-Ray Diffraction (SRXRD) has been used to identify a previously unobserved low temperature ferrite ({delta})/austenite({gamma}) phase transformation in the heat affected zone (HAZ) of 2205 Duplex Stainless Steel (DSS) welds. In this ''ferrite dip'' transformation, the ferrite transforms to austenite during heating to peak temperatures on the order of 750 C, and re-transforms to ferrite during cooling, resulting in a ferrite volume fraction equivalent to that in the base metal. Time Resolved X-Ray Diffraction (TRXRD) and laser dilatometry measurements during Gleeble{reg_sign} thermal simulations are performed in order to verify the existence of this low temperature phase transformation. Thermodynamic and kinetic models for phase transformations, including both local-equilibrium and para-equilibrium diffusion controlled growth, show that diffusion of substitutional alloying elements does not provide a reasonable explanation for the experimental observations. On the other hand, the diffusion of interstitial alloying elements may be rapid enough to explain this behavior. Based on both the experimental and modeling results, two mechanisms for the ''ferrite dip'' transformation, including the formation and decomposition of secondary austenite and an athermal martensitic-type transformation of ferrite to austenite, are considered.

  14. Physical Simulation of a Duplex Stainless Steel Friction Stir Welding by the Numerical and Experimental Analysis of Hot Torsion Tests

    Science.gov (United States)

    da Fonseca, Eduardo Bertoni; Santos, Tiago Felipe Abreu; Button, Sergio Tonini; Ramirez, Antonio Jose

    2016-09-01

    Physical simulation of friction stir welding (FSW) by means of hot torsion tests was performed on UNS S32205 duplex stainless steel. A thermomechanical simulator Gleeble 3800® with a custom-built liquid nitrogen cooling system was employed to reproduce the thermal cycle measured during FSW and carry out the torsion tests. Microstructures were compared by means of light optical microscopy and electron backscatter diffraction. True strain and strain rate were calculated by numerical simulation of the torsion tests. Thermomechanically affected zone (TMAZ) was reproduced at peak temperature of 1303 K (1030 °C), rotational speeds of 52.4 rad s-1 (500 rpm) and 74.5 rad s-1 (750 rpm), and 0.5 to 0.75 revolutions, which represent strain rate between 10 and 16 s-1 and true strain between 0.5 and 0.8. Strong grain refinement, similar to the one observed in the stir zone (SZ), was attained at peak temperature of 1403 K (1130 °C), rotational speed of 74.5 rad s-1 (750 rpm), and 1.2 revolution, which represent strain rate of 19 s-1 and true strain of 1.3. Continuous dynamic recrystallization in ferrite and dynamic recrystallization in austenite were observed in the TMAZ simulation. At higher temperature, dynamic recovery of austenite was also observed.

  15. Corrosion studies using potentiodynamic and EIS electrochemical techniques of welded lean duplex stainless steel UNS S82441

    Science.gov (United States)

    Brytan, Z.; Niagaj, J.; Reiman, Ł.

    2016-12-01

    The corrosion characterisation of lean duplex stainless steel (1.4662) UNS S82441 welded joints using the potentiodynamic test and electrochemical impedance spectroscopy in 1 M NaCl solution are discussed. The influence of autogenous TIG welding parameters (amount of heat input and composition of shielding gases like Ar and Ar-N2 and an Ar-He mixture), as well as A-TIG welding was studied. The influence of welding parameters on phase balance, microstructural changes and the protective properties of passive oxide films formed at the open circuit potential or during the anodic polarisation were studied. From the results of the potentiodynamic test and electrochemical impedance spectroscopy of TIG and A-TiG, welded joints show a lower corrosion resistance compared to non-welded parent metal, but introducing heat input properly during welding and applying shielding gases rich in nitrogen or helium can increase austenitic phase content, which is beneficial for corrosion resistance, and improves surface oxide layer resistance in 1 M NaCl solution.

  16. Finite Element Analysis of Modeling Residual Stress Distribution in All-position Duplex Stainless Steel Welded Pipe

    Institute of Scientific and Technical Information of China (English)

    Xiaojun JIN; Lixing HUO; Yufeng ZHANG; Bingren BAI; Xiaowei LI; Jun CAO

    2004-01-01

    On the basis of the thermal-elastic-plastic theory, a three-dimensional finite element numerical simulation is performed on the girth welded residual stresses of the duplex stainless steel pipe with ANSYS nonlinear finite element program for the first time. Three-dimensional FEM using mobile heat source for analysis transient temperature field and welding stress field in circumferential joint of pipes is founded. Distributions of axial and hoop residual stresses of the joint are investigated. The axial and the hoop residual stresses at the weld and weld vicinity on inner surface of pipes are tensile, and they are gradually transferred into compressive with the increase of the departure from the weld. The axial residual stresses at the weld and weld vicinity on outer surface of pipes is compressive while the hoop one is tensile. The distributions of residual stresses compared positive-circle with negative-circle show distinct symmetry. These results provide theoretical knowledge for the optimization of process and the control of welding residual stresses.

  17. Effect of Austenitic and Austeno-Ferritic Electrodes on 2205 Duplex and 316L Austenitic Stainless Steel Dissimilar Welds

    Science.gov (United States)

    Verma, Jagesvar; Taiwade, Ravindra V.

    2016-09-01

    This study addresses the effect of different types of austenitic and austeno-ferritic electrodes (E309L, E309LMo and E2209) on the relationship between weldability, microstructure, mechanical properties and corrosion resistance of shielded metal arc welded duplex/austenitic (2205/316L) stainless steel dissimilar joints using the combined techniques of optical, scanning electron microscope, energy-dispersive spectrometer and electrochemical. The results indicated that the change in electrode composition led to microstructural variations in the welds with the development of different complex phases such as vermicular ferrite, lathy ferrite, widmanstatten and intragranular austenite. Mechanical properties of welded joints were diverged based on compositions and solidification modes; it was observed that ferritic mode solidified weld dominated property wise. However, the pitting corrosion resistance of all welds showed different behavior in chloride solution; moreover, weld with E2209 was superior, whereas E309L exhibited lower resistance. Higher degree of sensitization was observed in E2209 weld, while lesser in E309L weld. Optimum ferrite content was achieved in all welds.

  18. Effect of Austenitic and Austeno-Ferritic Electrodes on 2205 Duplex and 316L Austenitic Stainless Steel Dissimilar Welds

    Science.gov (United States)

    Verma, Jagesvar; Taiwade, Ravindra V.

    2016-11-01

    This study addresses the effect of different types of austenitic and austeno-ferritic electrodes (E309L, E309LMo and E2209) on the relationship between weldability, microstructure, mechanical properties and corrosion resistance of shielded metal arc welded duplex/austenitic (2205/316L) stainless steel dissimilar joints using the combined techniques of optical, scanning electron microscope, energy-dispersive spectrometer and electrochemical. The results indicated that the change in electrode composition led to microstructural variations in the welds with the development of different complex phases such as vermicular ferrite, lathy ferrite, widmanstatten and intragranular austenite. Mechanical properties of welded joints were diverged based on compositions and solidification modes; it was observed that ferritic mode solidified weld dominated property wise. However, the pitting corrosion resistance of all welds showed different behavior in chloride solution; moreover, weld with E2209 was superior, whereas E309L exhibited lower resistance. Higher degree of sensitization was observed in E2209 weld, while lesser in E309L weld. Optimum ferrite content was achieved in all welds.

  19. Solid Solution Nitriding Technology of 15Cr-7.5Mn-2.6Mo Duplex Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    FU Rui-dong; ZHAO Pin; WANG Chun-Yu; QIU Liang; ZHENG Yang-zeng

    2004-01-01

    Solid solution nitriding technologies of 15Cr-7.5Mn-2.6Mo duplex stainless steel were investigated by using of orthogonal tests. The results show that the best technology would be the processes of 1050℃× 2h + 1150℃× 3h +1050℃× 2h + 1150℃× 4h under pure N2 with PN2=0.15MPa. The high nitrogen austenitic case with the depth of1.62mm can be obtained. Orthogonal tests show that the type of atmosphere has the most notable effect on solid solution nitriding process; the pressure in the furnace and the nitriding processes has a notable effect. X-ray diffraction analyses results indicate that the main phases in the cases of the solution-nitrided samples cooled in the furnace are high nitrogen austenite, CrN, Fe3O4 and nitrogen containing ferrite. In the other samples experienced solid solution nitriding and solution treatment the obtained phase in the cases is high nitrogen austenite only. The results show that solid solution nitriding is a process that nitrogen absolutely diffuses in the austenite. The diffusing activation energy in the conditions of PN2 = 0.15MPa and 1050℃~ 1200℃ is 186.6K J/mol.

  20. Simulation of Fluid Flow, Heat Transfer and Micro-Segregation in Twin-roll Strip Casting of Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    Xiaoming ZHANG; Zhengyi JIANG; Xianghua LIU; Guodong WANG

    2006-01-01

    In twin-roll strip casting process, metal flow and temperature distribution in the molten pool directly affect the stability of the process and the quality of products. In this paper, a 3D coupled thermal-flow fenite element modeling (FEM) simulation for twin-roll strip casting of stainless steel was performed. Influences of the pouring temperature and casting speed on the temperature fields were obtained from the numerical simulation. The micro-segregation of the solutes during the strip casting process of stainless steel was also simulated. A developed micro-segregation model was used to calculate the micro-segregation of solutes in twin-roll casting of stainless steel. The relationship between the solidus fraction in solidification and temperature was given,which was used to determine the LIT (liquid impermeable temperature), ZST (zero strength temperature) and ZDT (zero ductility temperature) in the period of non-equilibrium solidification. The effect of temperature on the micro-segregation was discussed. According to the computational results, the solidification completion temperature in the twin-roll strip casting of stainless steel was then determined, which can provide a basis for controlling the location of solidification completion temperature and analysing the crack of the casting strip.

  1. Thermal treatments effect on the austenite-ferrite equilibrium in a duplex stainless steel weld beads; Effet des traitements thermiques sur l equilibre austenite - ferrite dans un cordon de soudure en acier inoxydable duplex

    Energy Technology Data Exchange (ETDEWEB)

    Belkessa, Brahim; Badji, Riad; Bettahar, Kheireddine; Maza, Halim [Division de la Metallurgie et Mecanique. Centre de Recherche Scientifique et Technique en Soudage et Controle. B.P 64, Route de Dely Ibrahim, Cheraga, Alger (Algeria)

    2006-07-01

    Heat treatments in the temperature range between 800 to 1200 C, with a keeping at high temperature of 60 min, followed by a water quenching at 20 C, have been carried out on austeno-ferritic stainless steel welds (of type SAF 2205-UNS S31803). The heat treatments carried out at temperatures below 1000 C have modified the structure of the duplex stainless steel 2205 in inducing the formation of precipitates, identified by X-ray diffraction as being the intermetallic compound {sigma} and the chromium carbides M{sub 23}C{sub 6}. The treatments applied to temperatures superior to 1000 C shift the {delta}-{gamma} equilibrium towards the {delta} phase. Indeed, the increase of the ferrite rate with the treatment temperature is approximately linear. The ferrite rates are higher in the heat-affected zone, which has been submitted to a ferritizing due to the welding thermal effects. (O.M.)

  2. Utilization of aluminum to obtaining a duplex type stainless steel using high energy ball milling; Obtencao de um aco inoxidavel de estrutura duplex do sistema FeMnAl processado por moagem de alta energia

    Energy Technology Data Exchange (ETDEWEB)

    Pavlak, I.E.; Cintho, O.M., E-mail: eng.igorpavlak@yahoo.com.b [Universidade Estadual de Ponta Grossa (UEPG), PR (Brazil); Capocchi, J.D.T. [Universidade de Sao Paulo (USP), SP (Brazil)

    2010-07-01

    The obtaining of stainless steel using aluminum in its composition - FeMnAl system, has been researches subject since the sixties, by good mechanical properties and resistance to oxidation presented, when compared with conventional FeNiCr stainless steel system. In another point, the aluminum and manganese are low cost then traditional elements. This work, metallic powders of iron, manganese and pure aluminum, were processed in a Spex type high-energy ball mill in nitrogen atmosphere. The milling products were compressed into pastille form and sintered under inert atmosphere. The final products were characterized by optical and electronic microscopy and microhardness test. The metallographic analysis shows a typical austenite and ferrite duplex type microstructure. The presence of these phases was confirmed according X ray diffraction analysis. (author)

  3. Wearing Quality of Austenitic, Duplex Cast Steel, Gray and Spheroidal Graphite Iron

    Directory of Open Access Journals (Sweden)

    S. Pietrowski

    2012-04-01

    Full Text Available The current work presents the research results of abrasion wear and adhesive wear at rubbing and liquid friction of new austenitic, austenitic-ferritic (“duplex” cast steel and gray cast iron EN-GJL-250, spheroidal graphite iron EN-GJS-600-3, pearlitic with ledeburitic carbides and spheroidal graphite iron with ledeburitic carbides with a microstructure of the metal matrix: pearlitic, upper bainite, mixture of upper and lower bainite, martensitic with austenite, pearlitic-martensitic-bainitic-ausferritic obtained in the raw state. The wearing quality test was carried out on a specially designed and made bench. Resistance to abrasion wear was tested using sand paper P40. Resistance to adhesive wear was tested in interaction with steel C55 normalized, hardened and sulfonitrided. The liquid friction was obtained using CASTROL oil. It was stated that austenitic cast steel and “duplex” are characterized by a similar value of abrasion wear and adhesive wear at rubbing friction. The smallest decrease in mass was shown by the cast steel in interaction with the sulfonitrided steel C55. Austenitic cast steel and “duplex��� in different combinations of friction pairs have a higher wear quality than gray cast iron EN-GJL- 250 and spheroidal graphite iron EN-GJS-600-3. Austenitic cast steel and “duplex” are characterized by a lower wearing quality than the spheroidal graphite iron with bainitic-martensitic microstructure. In the adhesive wear test using CASTROL oil the tested cast steels and cast irons showed a small mass decrease within the range of 1÷2 mg.

  4. Effect of electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    An investigation on the influence of low frequency rotary electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting was experimentally conducted and carried out on an industrial trial basis. The results show that application of appropriate electromagnetic stirring parameters can obviously improve the macrostructure of austenitic stainless steel, in which both columnar and equiaxed grains can be greatly refined and shrinkage porosity or cavity zone along centerline can be remarkably decreased due to eliminating intracrystalline and enlarging equiaxed grains zone. The industrial trials verify that the electromagnetic stirring intensity of austenitic stainless steel should be higher than that of plain carbon steel. Electromagnetic stirring has somewhat affected the macrostructure of austenitic stainless steel even if the magnetic flux density of the electromagnetic stirring reaches 90 mT (amplitude reaches 141 mT ) in average at frequency f=3-4Hz, which provides a reference for the optimization of design and process parameters when applying the rotary electromagnetic stirrer

  5. Effect of electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting

    Directory of Open Access Journals (Sweden)

    ZHOU Shu-cai

    2007-08-01

    Full Text Available An investigation on the influence of low frequency rotary electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting was experimentally conducted and carried out on an industrial trial basis. The results show that application of appropriate electromagnetic stirring parameters can obviously improve the macrostructure of austenitic stainless steel, in which both columnar and equiaxed grains can be greatly refined and shrinkage porosity or cavity zone along centerline can be remarkably decreased due to eliminating intracrystalline and enlarging equiaxed grains zone. The industrial trials verify that the electromagnetic stirring intensity of austenitic stainless steel should be higher than that of plain carbon steel. Electromagnetic stirring has somewhat affected the macrostructure of austenitic stainless steel even if the magnetic flux density of the electromagnetic stirring reaches 90 mT (amplitude reaches 141 mT in average at frequency f=3-4Hz, which provides a reference for the optimization of design and process parameters when applying the rotary electromagnetic stirrer.

  6. Assessment of Crack Detection in Heavy-Walled Cast Stainless Steel Piping Welds Using Advanced Low-Frequency Ultrasonic Methods

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Michael T.; Crawford, Susan L.; Cumblidge, Stephen E.; Denslow, Kayte M.; Diaz, Aaron A.; Doctor, Steven R.

    2007-03-01

    Studies conducted at the Pacific Northwest National Laboratory in Richland, Washington, have focused on assessing the effectiveness and reliability of novel approaches to nondestructive examination (NDE) for inspecting coarse-grained, cast stainless steel reactor components. The primary objective of this work is to provide information to the U.S. Nuclear Regulatory Commission on the effectiveness and reliability of advanced NDE methods as related to the inservice inspection of safety-related components in pressurized water reactors (PWRs). This report provides progress, recent developments, and results from an assessment of low frequency ultrasonic testing (UT) for detection of inside surface-breaking cracks in cast stainless steel reactor piping weldments as applied from the outside surface of the components. Vintage centrifugally cast stainless steel piping segments were examined to assess the capability of low-frequency UT to adequately penetrate challenging microstructures and determine acoustic propagation limitations or conditions that may interfere with reliable flaw detection. In addition, welded specimens containing mechanical and thermal fatigue cracks were examined. The specimens were fabricated using vintage centrifugally cast and statically cast stainless steel materials, which are typical of configurations installed in PWR primary coolant circuits. Ultrasonic studies on the vintage centrifugally cast stainless steel piping segments were conducted with a 400-kHz synthetic aperture focusing technique and phased array technology applied at 500 kHz, 750 kHz, and 1.0 MHz. Flaw detection and characterization on the welded specimens was performed with the phased array method operating at the frequencies stated above. This report documents the methodologies used and provides results from laboratory studies to assess baseline material noise, crack detection, and length-sizing capability for low-frequency UT in cast stainless steel piping.

  7. Evaluation of hydrogen trapping mechanisms during performance of different hydrogen fugacity in a lean duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Silverstein, R., E-mail: barrav@post.bgu.ac.il [Department of Material Science and Engineering, Ben-Gurion University of the Negev, Beer-Sheva (Israel); Eliezer, D. [Department of Material Science and Engineering, Ben-Gurion University of the Negev, Beer-Sheva (Israel); Glam, B.; Eliezer, S.; Moreno, D. [Soreq Nuclear Research Center, Yavne, 81800 (Israel)

    2015-11-05

    Hydrogen trapping behavior in a lean duplex stainless steel (LDS) is studied by means of thermal desorption spectrometry (TDS). The susceptibility of a metal to hydrogen embrittlement is directly related to the trap characteristics: source or sink (reversible or irreversible, respectively). Since trapping affects the metal's diffusivity, it has a major influence on the hydrogen assisted cracking (HAC) phenomenon. It is known from previously published works that the susceptibility will depend on the competition between reversible and irreversible traps; meaning a direct relation to the hydrogen's initial state in the steel. In this research the trapping mechanism of LDS, exposed to different hydrogen charging environments, is analyzed by means of TDS. The TDS analysis was supported and confirmed by means of X-ray diffraction (XRD), hydrogen quantitative measurements and microstructural observations. It was found that gaseous charging (which produces lower hydrogen fugacity) creates ∼22% higher activation energy for hydrogen trapping compared with cathodic charging (which produces higher hydrogen fugacity). These results are due to the different effects on the hydrogen behavior in LDS which causes a major difference in the hydrogen contents and different hydrogen assisted phase transitions. The highest activation energy value in the cathodic charged sample was ascribed to the dominant phase transformation of γ → γ{sup ∗}, whereas in the gaseous charged sample it was ascribed to the dominant formation of intermetallic compound, sigma (σ). The relation between hydrogen distribution in LDS and hydrogen trapping mechanism is discussed in details. - Highlights: • The relation between hydrogen distribution and trapping in LDS is discussed. • Hydrogen's initial state in LDS causes different microstructural changes. • Gaseous charged LDS creates higher trapping energy compared to cathodic charged LDS. • The dominant phase transformation in

  8. Influence of volumic heat treatments upon cavitation erosion resistance of duplex X2CrNiMoN 22-5-3 stainless steels

    Science.gov (United States)

    Micu, L. M.; Bordeasu, I.; Popoviciu, M. O.; Popescu, M.; Bordeaşu, D.; Salcianu, L. C.

    2015-06-01

    The stainless steels Duplex 2205 with austenite and ferrite structure have mechanical characteristics close to those of martensite stainless steels but a better corrosion resistance; these steels are very sensitive on the heat treatments. Present work studies the cavitation erosion for those steels for three different heat treatments: simply quenched, annealed at 475°C post quenching and annealed at 875°C. The researches were undertaken at Timisoara “Politehnica” University in the Laboratory of Material Science and the Laboratory of Cavitation, using the T2 facility which integrally respects the recommendation of ASTM G32- 10 Standard. The best results were obtained with the specimens annealed at 875°C. In comparison with the stainless steel 41Cr4, with very good cavitation erosion qualities, all tested steels presented also good erosion resistance. So, Duplex 2205 steels can be used for details subjected to cavitation. The best results are obtained by increasing both the hardness and the quantity of the structure constituent with better cavitation erosion resistance, in our case the alloyed austenite.

  9. Methodology for calculating the thickness free of sigma phase in duplex stainless steels large section parts during hiperquenching; Metodologia para el calculo de espesores limite libres de fase sigma durante el hipertemple en piezas de aceros duplex de gran seccion

    Energy Technology Data Exchange (ETDEWEB)

    Jimbert, P.; Guraya, T.; Torregary, A.; Bravo, P.

    2013-06-01

    To achieve the mechanical properties and corrosion resistance desired by duplex stainless steels used by the petrochemical and nuclear industry, parts are subjected to a hiperquenching heat treatment from about 1050 degree centigrade. This avoids the risk of intermetallic precipitation which drastically reduces the properties of these materials. However with increasing depth to which the deposits are present, the thicknesses for such pipes have been increased, resulting in higher levels of demand on all its manufacturing process, including the heat treatment. To avoid the precipitation of intermetallic phases such as sigma phase it is necessary to know the cooling profile in the center of the work piece and for this purpose to know the value of the Surface Heat Transfer Coefficient (h) is essential. This coefficient changes during the hiperquenching and its value is determined experimentally as it depends on several process parameters. Studies reveal that its value is stabilized within a few seconds. We can then assume that to know the cooling profile in the center of large sections it is only necessary to know the stabilized value of h. However, all the studies found in the literature are referred to diameters smaller than 100 mm. This paper has developed a methodology to predict the precipitation of intermetallic phases in duplex stainless steel parts with large thicknesses in industrial facilities from the calculation of h. This methodology allows us to calculate the cooling profiles without wasting any work piece using one or more sensorized patterns with thermocouples and a subsequent simulation with ANSYS. (Author)

  10. Ultrasonic Sound Field Mapping Through Coarse Grained Cast Austenitic Stainless Steel Components

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, Susan L.; Prowant, Matthew S.; Cinson, Anthony D.; Larche, Michael R.; Diaz, Aaron A.

    2014-08-01

    The Pacific Northwest National Laboratory (PNNL) has been involved with nondestructive examination (NDE) of coarse-grained cast austenitic stainless steel (CASS) components for over 30 years. More recent work has focused on mapping the ultrasonic sound fields generated by low-frequency phased array probes that are typically used for the evaluation of CASS materials for flaw detection and characterization. The casting process results in the formation of large grained material microstructures that are nonhomogeneous and anisotropic. The propagation of ultrasonic energy for examination of these materials results in scattering, partitioning and redirection of these sound fields. The work reported here provides an assessment of sound field formation in these materials and provides recommendations on ultrasonic inspection parameters for flaw detection in CASS components.

  11. Influence of the nitrogen gas addition in the Ar shielding gas on the erosion-corrosion of tube-to-tube sheet welds of hyper duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hye-Jin; Jeon, Soon-Hyeok; Kim, Soon-Tae; Lee, In-Sung; Park, Yong-Soo [Yonsei University, Seoul (Korea, Republic of)

    2014-03-15

    Duplex stainless steels with nearly equal fraction of the ferrite(α) phase and austenite(γ) phase have been increasingly used for various applications such as power plants, desalination facilities due to their high resistance to corrosion, good weldability, and excellent mechanical properties. Hyper duplex stainless steel (HDSS) is defined as the future duplex stainless steel with a pitting resistance equivalent (PRE= wt.%Cr+3.3(wt.%Mo+0.5wt.%W)+30wt.%N) of above 50. However, when HDSS is welded with gas tungsten arc (GTA), incorporation of nitrogen in the Ar shielding gas are very important because the volume fraction of α-phase and γ-phase is changed and harmful secondary phases can be formed in the welded zone. In other words, the balance of corrosion resistance between two phases and reduction of Cr{sub 2}N are the key points of this study. The primary results of this study are as follows. The addition of N{sub 2} to the Ar shielding gas provides phase balance under weld-cooling conditions and increases the transformation temperature of the α-phase to γ-phase, increasing the fraction of γ-phase as well as decreasing the precipitation of Cr2N. In the anodic polarization test, the addition of nitrogen gas in the Ar shielding gas improved values of the electrochemical parameters, compared to the Pure Ar. Also, in the erosion-corrosion test, the HDSS welded with shielding gas containing N{sub 2} decreased the weight loss, compared to HDSS welded with the Ar pure gas. This result showed the resistance of erosion-corrosion was increased due to increasing the fraction of γ-phase and the stability of passive film according to the addition N{sub 2} gas to the Ar shielding gas. As a result, the addition of nitrogen gas to the shielding gas improved the resistance of erosion-corrosion.

  12. A study on the mechanism of stress corrosion cracking of duplex stainless steels in hot alkaline-sulfide solution

    Science.gov (United States)

    Chasse, Kevin Robert

    Duplex stainless steels (DSS) generally have superior strength and corrosion resistance as compared to most standard austenitic and ferritic stainless grades owing to a balanced microstructure of austenite and ferrite. As a result of having favorable properties, DSS have been selected for the construction of equipment in pulp and paper, chemical processing, nuclear, oil and gas as well as other industries. The use of DSS has been restricted in some cases because of stress corrosion cracking (SCC), which can initiate and grow in either the ferrite or austenite phase depending on the environment. Thorough understanding of SCC mechanisms of DSS in chloride- and hydrogen sulfide-containing solutions has been useful for material selection in many environments. However, understanding of SCC mechanisms of DSS in sulfide-containing caustic solutions is limited, which has restricted the capacity to optimize process and equipment design in pulp and paper environments. Process environments may contain different concentrations of hydroxide, sulfide, and chloride, altering corrosion and SCC susceptibility of each phase. Crack initiation and growth behavior will also change depending on the relative phase distribution and properties of austenite and ferrite. The role of microstructure and environment on the SCC of standard grade UNS S32205 and lean grade UNS S32101 in hot alkaline-sulfide solution were evaluated in this work using electrochemical, film characterization, mechanical testing, X-ray diffraction, and microscopy techniques. Microstructural aspects, which included residual stress state, phase distribution, phase ratio, and microhardness, were related to the propensity for SCC crack initiation in different simulated alkaline pulping liquors at 170 °C. Other grades of DSS and reference austenitic and superferritic grades of stainless steel were studied using exposure coupons for comparison to understand compositional effects and individual phase susceptibility

  13. Elastic-plastic characterization of a cast stainless steep pipe elbow material

    Energy Technology Data Exchange (ETDEWEB)

    Joyce, J.A. [Naval Academy, Annapolis, MD (United States); Hackett, E.M.; Roe, C. [David W. Taylor Naval Ship Research and Development Center, Annapolis, MD (United States)

    1992-01-01

    Tests conducted in Japan as part of the High Level Vibration Test (HLVT) program for reactor piping systems revealed fatigue crack growth in a cast stainless steel pipe elbow. The material tested was equivalent to ASME SA-351CF8M. The David Taylor Research Center (DTRC) was tasked to developed the appropriate material property data to characterize cyclic deformation, cyclic elastic-plastic crack growth and ductile tearing resistance in the pipe elbow material. It was found that the cast stainless steel was very resistant to ductile crack extension. J-R curves essentially followed a blunting behavior to very high J levels. Low cycle fatigue crack growth rate data obtained on this material using a cyclic J integral approach was consistent with the high cycle fatigue crack growth rate and with a standard textbook correlation equation typical for this type of material. Evaluation of crack closure effects was essential to accurately determine the crack driving force for cyclic elastic- plastic crack growth in this material. SEM examination of several of the cyclic J test fracture surfaces indicated that fatigue was the primary mode of fracture with ductile crack extension intervening only during the last few cycles of loading.

  14. Fatigue and corrosion fatigue behavior of 13Cr and duplex stainless steel and a welded nickel alloy employed in oil and gas production

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, R.M. [Department of Metallurgy Engineering, Federal University of Rio Grande do Sul, Porto Alegre (Brazil); Juca Batista, Ipanema, Porto Alegre, Rio Grande do Sul CEP (Brazil); Mueller, I.L. [Department of Metallurgy Engineering, Federal University of Rio Grande do Sul, Porto Alegre (Brazil); Aneron Correia de Oliveira, Porto Alegre, Rio Grande do Sul (Brazil)

    2009-05-15

    The materials used in off-shore oil and gas production, e.g. in risers, are often exposed to cyclic loads from the water movement because of their contact with seawater. These factors acting together can develop a corrosion fatigue (CF) process. A duplex and a 13% chromium (13Cr) wrought stainless steel (SS) and a welded nickel base alloy Inconel 625 were tested at different cyclic load magnitudes in an eccentric fatigue machine type. The specimens were tested in the presence of a corrosive environment at low loading frequencies (0.3 Hz). The medium used was an aqueous solution with 115.000 ppm of chloride, pH adjusted to 4, and CO{sub 2} bubbling inside the solution during the test. The end of the test was determined in maximum 500.000 cycles (23 days for frequency of 0.3 Hz) if no fracture occurred before. In the 13Cr steel the fissure seems to propagate in a uniform unique path, while in the duplex steel the crack changes the direction when passing from the ferritic to austenitic grains. The propagation speed seems to be different in the ferrite and in the austenitic structures. Among the materials tested the Inconel 625 alloy, even being in the welded condition, showed higher CF strength than the SSs; 13Cr shows better results when compared with the duplex steel, even though the last one would be more corrosion resistant. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  15. Microstructural evolution during aging at 800 °C and its effect on the magnetic behavior of UNS S32304 lean duplex stainless steel

    Science.gov (United States)

    Dille, J.; Areiza, M. C. L.; Tavares, S. S. M.; Pereira, G. R.; De Almeida, L. H.; Rebello, J. M. A.

    2017-03-01

    Duplex stainless steels are high strength and corrosion resistant alloys extensively used in chemical and petrochemical industries. However, exposition to temperatures in the range 300-1000 °C leads to precipitation of different phases having a detrimental effect on the mechanical properties and on the corrosion resistance of the alloy. In this work, the microstructural evolution during aging of a UNS S32304 lean duplex stainless steel was investigated by scanning electron microscopy, transmission electron microscopy and magnetic force microscopy. Formation of secondary austenite as well as Cr2N and Cr23C6 precipitation and, consequently, a decrease of ferrite volume fraction were observed. EDX analysis indicated that secondary austenite is depleted in chromium which is detrimental to the corrosion resistance of the alloy. A variation of magnetic properties and Eddy current measurement parameters during aging was simultaneously detected and can be explained by the decrease of ferrite volume content. Therefore, Eddy current non-destructive testing can be successfully applied to detect the formation of deleterious phases during aging.

  16. Corrosion behavior of heat-treated low grade duplex stainless steel (type Fe-15Cr-5Ni-1.9Cu) in sweet environments

    Energy Technology Data Exchange (ETDEWEB)

    Ezuber, H. M. [Faculty of Engineering University of Bahrain P.O. Box 32038 Bahrain (Bahrain)

    2004-07-01

    Sweet and/or sour service environments require the use of corrosion resistant materials since conventional steels usually exhibit general corrosion, pitting attack and Stress Corrosion Cracking (SCC) under these conditions. Long term performance and cost effectiveness must be considered when evaluating material selection. Low grade duplex stainless steel may be considered as a useful material under corrosive conditions. These materials are immune to general corrosion and low nickel content is an advantage from a SCC stand point. In this study, the pitting corrosion behavior of low grade duplex stainless steel (type Fe-15Cr-5Ni-1.9Cu) alloys were evaluated in 01 M NaCl solutions saturated with CO{sub 2} (sweet environment) and containing no or little thiosulfate species at 50 deg. C. The effect of inappropriate heat treatment is also studied under such conditions. The results revealed that this alloy is susceptible to chloride pitting corrosion. The intensity of the chloride attack is remarkably increased with the application of inappropriate heat treatment, addition of CO{sub 2} and presence of thiosulfate species. Although chloride solutions containing saturated dissolved CO{sub 2} are more corrosive than those containing thiosulfate species, the presence of both species (CO{sub 2} and S{sub 2}O{sub 3}{sup 2}) has a more negative effect on the chloride pitting resistance than would occur for either component by it self. (authors)

  17. Transformation and Precipitation Reactions by Metal Active Gas Pulsed Welded Joints from X2CrNiMoN22-5-3 Duplex Stainless Steels

    Directory of Open Access Journals (Sweden)

    Ion-Dragos Utu

    2016-07-01

    Full Text Available The high alloying degree of Duplex stainless steels makes them susceptible to the formation of intermetallic phases during their exposure to high temperatures. Precipitation of these phases can lead to a decreasing of the corrosion resistance and sometimes of the toughness. Starting from the advantages of the synergic Metal Active Gas (MAG pulsed welding process, this paper analyses the structure formation particularities of homogeneous welded joints from Duplex stainless steel. The effect of linear welding energy on the structure morphology of the welded joints was revealed by macro- and micrographic examinations, X-ray energy dispersion analyses, measurements of ferrite proportion and X-ray diffraction analysis. The results obtained showed that the transformation of ferrite into austenite is associated with the chromium, nickel, molybdenum and nitrogen distribution between these two phases and their redistribution degree is closely linked to the overall heat cycle of the welding process. The adequate control of the energy inserted in the welded components provides an optimal balance between the two microstructural constituents (Austenite and Ferrite and avoids the formation of undesirable intermetallic phases.

  18. Flexural Strength and Toughness of Austenitic Stainless Steel Reinforced High-Cr White Cast Iron Composite

    Science.gov (United States)

    Sallam, H. E. M.; Abd El-Aziz, Kh.; Abd El-Raouf, H.; Elbanna, E. M.

    2013-12-01

    Flexural behavior of high-Cr white cast iron (WCI) reinforced with different shapes, i.e., I- and T-sections, and volume fractions of austenitic stainless steel (310 SS) were examined under three-point bending test. The dimensions of casted beams used for bending test were (50 × 100 × 500 mm3). Carbon and alloying elements diffusion enhanced the metallurgical bond across the interface of casted beams. Carbon diffusion from high-Cr WCI into 310 SS resulted in the formation of Cr-carbides in 310 SS near the interface and Ni diffusion from 310 SS into high-Cr WCI led to the formation of austenite within a network of M7C3 eutectic carbides in high-Cr WCI near the interface. Inserting 310 SS plates into high-Cr WCI beams resulted in a significant improvement in their toughness. All specimens of this metal matrix composite failed in a ductile mode with higher plastic deformation prior to failure. The high-Cr WCI specimen reinforced with I-section of 310 SS revealed higher toughness compared to that with T-section at the same volume fraction. The presence of the upper flange increased the reinforcement efficiency for delaying the crack growth.

  19. Effect of shot peening treatment in the behavior of residual stress in duplex stainless steel during medium cycle fatigue; Efeito do tratamento de shot peening no comportamento das tensoes residuais em aco inoxidavel duplex durante fadiga de medio ciclo

    Energy Technology Data Exchange (ETDEWEB)

    Pedrosa, Peter D.S.; Rebello, Joao Marcos A. [Coordenacao dos Programas de Pos-Graduacao de Engenharia (PEMM/COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Metalurgica e de Materiais; Fonseca, Maria P. Cindra, E-mail: mcindra@vm.uff.b [Universidade Federal Fluminense (PGMEC/UFF), Niteroi, RJ (Brazil). Escola de Engenharia. Programa de Pos-Graduacao em Engenharia Mecanica

    2010-07-01

    The lifetime of duplex stainless steel parts experiencing cyclic fatigue is directly influenced by the residual stresses present in the ferrite and austenite phases. The motivation for this work was to analyze the behaviour of the residual stresses fields introduced by shot peening treatment in both phases, in the sample surface as in the subsurface layers, in low fatigue cycles, using the X-rays diffraction technique. The results shows that the compressive residual stresses introduced by the shot peening treatment in both phases improved fatigue life of the material. However, the cyclical loads produce partial or total relief in these residual stresses fields. It was verified that the shot peening process induced the formation of microcracks only in the ferrite phase. The largest variations in the total compressive residual stresses fields also occurred in this phase. The samples surfaces were analyzed by scanning electron microscopy. (author)

  20. Automated Flaw Detection Scheme For Cast Austenitic Stainless Steel Weld Specimens Using Hilbert Huang Transform Of Ultrasonic Phased Array Data

    Energy Technology Data Exchange (ETDEWEB)

    Khan, T.; Majumdar, Shantanu; Udpa, L.; Ramuhalli, Pradeep; Crawford, Susan L.; Diaz, Aaron A.; Anderson, Michael T.

    2012-01-01

    The objective of this work is to develop processing algorithms to detect and localize the flaws using NDE ultrasonic data. Data was collected using cast austenitic stainless steel (CASS) weld specimens on-loan from the U.S. nuclear power industry’s Pressurized Water Reactor Owners Group (PWROG) specimen set. Each specimen consists of a centrifugally cast stainless steel (CCSS) pipe section welded to a statically cast (SCSS) or wrought (WRSS) section. The paper presents a novel automated flaw detection and localization scheme using low frequency ultrasonic phased array inspection signals in the weld and heat affected zone of the base materials. The major steps of the overall scheme are preprocessing and region of interest (ROI) detection followed by the Hilbert Huang transform (HHT) of A-scans in the detected ROIs. HHT offers time-frequency-energy distribution for each ROI. The accumulation of energy in a particular frequency band is used as a classification feature for the particular ROI.

  1. Effect of Sintering Atmosphere and Solution Treatment on Density, Microstructure and Tensile Properties of Duplex Stainless Steels Developed from Pre-alloyed Powders

    Science.gov (United States)

    Murali, Arun Prasad; Mahendran, Sudhahar; Ramajayam, Mariappan; Ganesan, Dharmalingam; Chinnaraj, Raj Kumar

    2017-01-01

    In this research, Powder Metallurgy (P/M) of Duplex Stainless Steels (DSS) of different compositions were prepared through pre-alloyed powders and elemental powders with and without addition of copper. The powder mix was developed by pot mill for 12 h to obtain the homogeneous mixture of pre-alloyed powder with elemental compositions. Cylindrical green compacts with the dimensions of 30 mm diameter and 12 mm height were compacted through universal testing machine at a pressure level of 560 ± 10 MPa. These green compacts were sintered at 1350 °C for 2 h in hydrogen and argon atmospheres. Some of the sintered stainless steel preforms were solution treated at 1050 °C followed by water quenching. The sintered as well as solution treated samples were analysed by metallography examination, Scanning Electron Microscopy and evaluation of mechanical properties. Ferrite content of sintered and solution treated DSS were measured by Fischer Ferritoscope. It is inferred that the hydrogen sintered DSS depicted better density (94% theoretical density) and tensile strength (695 MPa) than the argon sintered steels. Similarly the microstructure of solution treated DSS revealed existence of more volume of ferrite grains than its sintered condition. Solution treated hydrogen sintered DSS A (50 wt% 316L + 50 wt% 430L) exhibited higher tensile strength of 716 MPa and elongation of 17%, which are 10-13% increment than the sintered stainless steels.

  2. In situ Colonization of Marine Biofilms on UNS S32760 Duplex Stainless Steel Coupons in Areas with Different Water Qualities:Implications for Corrosion Potential Behavior

    Institute of Scientific and Technical Information of China (English)

    Luciana VR de Messano; Barbara LIgnacio; Maria HCB Neves; Ricardo Coutinho

    2014-01-01

    In the presence of biofilms, stainless steels (SS) exhibits an increase in corrosion potential, called ennoblement. In the present study, the corrosion potential (Ecor ) behavior of the duplex SS UNS S32760 was recorded simultaneously with the in situ marine biofilm formation in two areas at Arraial do Cabo, Southeastern Brazil. The biofilm at Forno Harbor (an anthropogenically disturbed area) was characterized by higher relative abundances of Bacteria at day 2, followed by diatoms (especially Navicula sp.) on day 10 and dinoflagellates on day 18, whereas no clear trend was recorded at Cabo Frio Island (an undisturbed area). The ennoblement of Ecor values was site-dependent. In a complementary laboratory assay, biofilms were removed and the Ecor values registered in sterile conditions for the subsequent 10 days and corroborated in situ results. Understanding biofilms and SS interactions has important implications for materials science and engineering decisions as well as helping to fill in important gaps in this knowledge.

  3. Improvement of localised corrosion resistance of AISI 2205 Duplex Stainless Steel joints made by gas metal arc welding under electromagnetic interaction of low intensity

    Science.gov (United States)

    García-Rentería, M. A.; López-Morelos, V. H.; García-Hernández, R.; Dzib-Pérez, L.; García-Ochoa, E. M.; González-Sánchez, J.

    2014-12-01

    The resistance to localised corrosion of AISI 2205 duplex stainless steel plates joined by Gas Metal Arc Welding (GMAW) under the effect of electromagnetic interaction of low intensity (EMILI) was evaluated with sensitive electrochemical methods. Welds were made using two shielding gas mixtures: 98% Ar + 2% O2 (M1) and 97% Ar + 3% N2 (M2). Plates were welded under EMILI using the M1 gas with constant welding parameters. The modified microstructural evolution in the high temperature heat affected zone and at the fusion zone induced by application of EMILI during welding is associated with the increase of resistance to localised corrosion of the welded joints. Joints made by GMAW using the shielding gas M2 without the application of magnetic field presented high resistance to general corrosion but high susceptibility to undergo localised attack.

  4. Improvement of localised corrosion resistance of AISI 2205 Duplex Stainless Steel joints made by gas metal arc welding under electromagnetic interaction of low intensity

    Energy Technology Data Exchange (ETDEWEB)

    García-Rentería, M.A., E-mail: crazyfim@gmail.com [Instituto de Investigación en Metalurgia y Materiales, Universidad Michoacana de San Nicolás de Hidalgo, A.P. 888, CP 58000, Morelia, Michoacán (Mexico); López-Morelos, V.H., E-mail: vhlopez@umich.mx [Instituto de Investigación en Metalurgia y Materiales, Universidad Michoacana de San Nicolás de Hidalgo, A.P. 888, CP 58000, Morelia, Michoacán (Mexico); García-Hernández, R., E-mail: rgarcia@umich.mx [Instituto de Investigación en Metalurgia y Materiales, Universidad Michoacana de San Nicolás de Hidalgo, A.P. 888, CP 58000, Morelia, Michoacán (Mexico); Dzib-Pérez, L., E-mail: luirdzib@uacam.mx [Centre for Corrosion Research, Autonomous University of Campeche, Av. Agustín Melgar s/n, Col. Buenavista, CP 24039, Campeche, Cam (Mexico); García-Ochoa, E.M., E-mail: emgarcia@uacam.mx [Centre for Corrosion Research, Autonomous University of Campeche, Av. Agustín Melgar s/n, Col. Buenavista, CP 24039, Campeche, Cam (Mexico); González-Sánchez, J., E-mail: jagonzal@uacam.mx [Centre for Corrosion Research, Autonomous University of Campeche, Av. Agustín Melgar s/n, Col. Buenavista, CP 24039, Campeche, Cam (Mexico)

    2014-12-01

    Highlights: • Electromagnetic interaction in welding improved localised corrosion resistance. • Electromagnetic interaction in welding enhanced γ/δ phase balance of DuplexSS. • Welding under Electromagnetic interaction repress formation and growth of detrimental phases. • Welds made with gas protection (2% O{sub 2} + 98% Ar) have better microstructural evolution during welding. - Abstract: The resistance to localised corrosion of AISI 2205 duplex stainless steel plates joined by Gas Metal Arc Welding (GMAW) under the effect of electromagnetic interaction of low intensity (EMILI) was evaluated with sensitive electrochemical methods. Welds were made using two shielding gas mixtures: 98% Ar + 2% O{sub 2} (M1) and 97% Ar + 3% N{sub 2} (M2). Plates were welded under EMILI using the M1 gas with constant welding parameters. The modified microstructural evolution in the high temperature heat affected zone and at the fusion zone induced by application of EMILI during welding is associated with the increase of resistance to localised corrosion of the welded joints. Joints made by GMAW using the shielding gas M2 without the application of magnetic field presented high resistance to general corrosion but high susceptibility to undergo localised attack.

  5. Development of Stronger and More Reliable Cast Austenitic Stainless Steels (H-Series) Based on Scientific and Design Methodology

    Energy Technology Data Exchange (ETDEWEB)

    Pankiw, Roman I; Muralidharan, G. (Murali); Sikka, Vinod K.

    2006-06-30

    The goal of this project was to increase the high-temperature strength of the H-Series of cast austenitic stainless steels by 50% and the upper use temperature by 86 to 140 degrees fahrenheit (30 to 60 degrees celsius). Meeting this goal is expected to result in energy savings of 35 trillion Btu/year by 2020 and energy cost savings of approximately $230 million/year. The higher-strength H-Series cast stainless steels (HK and HP type) have applications for the production of ethylene in the chemical industry, for radiant burner tubes and transfer rolls for secondary processing of steel in the steel industry, and for many applications in the heat treating industry, including radiant burner tubes. The project was led by Duraloy Technologies, Inc., with research participation by Oak Ridge National Laboratory (ORNL) and industrial participation by a diverse group of companies.

  6. Effect of Ni Contents on the Microstructure and Mechanical Properties of Martensitic Stainless Steel Guide Roll by Centrifugal Casting

    Institute of Scientific and Technical Information of China (English)

    Villando Thursdiyanto; Eun-Jae Bae; Eung-Ryul Baek

    2008-01-01

    A novel process based on centrifugal casting was developed to produce martensitic stainless steel for guideroll materials. Centrifugal casting provides a lower production cost and less of the thermal cracking defects which normally occur in the overlaid welding process. In this study, the effects of Ni on the microstructure and mechanical properties of martensitic stainless steel were investigated. The results show that the addition of Ni resulted in a decrease in the volume fraction of delta ferrite and an increase in the volume fraction of the retained austenite, respectively. Moreover, a tensile strength of 1600 MPa with an elongation of 4% were obtained after tempering at 500℃ for 2 h. These values were higher than those obtained by using the conventional overlaid process.

  7. Prevention of burn-on defect on surface of hydroturbine blade casting of ultra-low-carbon refining stainless steel

    Directory of Open Access Journals (Sweden)

    Li Ling

    2008-08-01

    Full Text Available The burn-on sand is common surface defect encountered in CO2-cured silicate-bonded sand casting of hydroturbine blade of ultra-low-carbon martensitic stainless steel, its feature, causes and prevention measures are presented in this paper. Experiments showed that the burn-on defect is caused by oxidization of chromium in the molten steel at high temperature and can be effectively eliminated by using chromium-corundum coating.

  8. Prevention of burn-on defect on surface of hydroturbine blade casting of ultra-low-carbon refining stainless steel

    Institute of Scientific and Technical Information of China (English)

    Li Ling; Xie Huasheng; Huang Danzhong; Li Hankun; Tan Rui; Zhou Jingyi

    2008-01-01

    The burn-on sand is common surface defect encountered in CO2-cured silicate-bonded sand casting of hydroturbine blade of ultra-low-carbon martensitic stainless steel, its feature, causes and prevention measures are presented in this paper. Experiments showed that the bum-on defect is caused by oxidization of chromium in the molten steel at high temperature and can be effectively eliminated by using chromium-corundum coating.

  9. Methods for the In-Situ Characterization of Cast Austenitic Stainless Steel Microstructures

    Science.gov (United States)

    Ramuhalli, P.; Good, M. S.; Harris, R. J.; Bond, L. J.; Ruud, C. O.; Diaz, A. A.; Anderson, M. T.

    2011-06-01

    Cast austenitic stainless steel (CASS) that was commonly used in U.S. nuclear power plants is a coarse-grained, elastically anisotropic material. Its engineering properties made it a material of choice for selected designs of nuclear power reactor systems. However, the material manufacturing and fabrication processes result in a variety of coarse-grain microstructures that make current ultrasonic in-service inspection of components quite challenging. To address inspection needs, new ultrasonic inspection approaches are being sought. However, overcoming the deleterious and variable effects of the microstructure on the interrogating ultrasonic beam may require knowledge of the microstructure, for potential optimization of inspection parameters to enhance the probability of detection (POD). The ability to classify microstructure type (e.g. polycrystalline or columnar) has the potential to guide selection of optimal NDE approaches. This paper discusses the application of ultrasonic and electromagnetic methods for classifying CASS microstructures, when making measurements from the outside surface of the component. Results to date demonstrate the potential of these measurements to discriminate between two consistent microstructures—equiaxed-grain material versus columnar-grain material. The potential for fusion of ultrasonic and electromagnetic measurements for in-situ microstructure characterization in CASS materials will be explored.

  10. Methods for the In-Situ Characterization of Cast Austenitic Stainless Steel Microstructures

    Energy Technology Data Exchange (ETDEWEB)

    Ramuhalli, Pradeep; Good, Morris S.; Harris, Robert V.; Bond, Leonard J.; Ruud, Clayton O.; Diaz, Aaron A.; Anderson, Michael T.

    2011-06-29

    Cast austenitic stainless steel (CASS) that was commonly used in U.S. nuclear power plants is a coarse-grained, elastically anisotropic material. Its engineering properties made it a material of choice for selected designs of nuclear power reactor systems. However, the fabrication processes result in a variety of coarse-grain microstructures that make current ultrasonic in-service inspection of components quite challenging. To address inspection needs, new ultrasonic inspection approaches are being sought. However, overcoming the deleterious and variable effects of the microstructure on the interrogating ultrasonic beam may require knowledge of the microstructure, for potential optimization of inspection parameters to enhance the probability of detection (POD). The ability to classify microstructure type (e.g. polycrystalline or columnar) has the potential to guide selection of optimal NDE approaches. This paper discusses the application of ultrasonic and electromagnetic methods for classifying CASS microstructures, when making measurements from the outside surface of the component. Results to date demonstrate the potential of these measurements to discriminate between two consistent microstructures - equiaxed-grain material versus columnar-grain material. The potential for fusion of ultrasonic and electromagnetic measurements for in-situ microstructure characterization in CASS materials will be explored.

  11. Fabrication of low-cost, cementless femoral stem 316L stainless steel using investment casting technique.

    Science.gov (United States)

    Baharuddin, Mohd Yusof; Salleh, Sh-Hussain; Suhasril, Andril Arafat; Zulkifly, Ahmad Hafiz; Lee, Muhammad Hisyam; Omar, Mohd Afian; Abd Kader, Ab Saman; Mohd Noor, Alias; A Harris, Arief Ruhullah; Abdul Majid, Norazman

    2014-07-01

    Total hip arthroplasty is a flourishing orthopedic surgery, generating billions of dollars of revenue. The cost associated with the fabrication of implants has been increasing year by year, and this phenomenon has burdened the patient with extra charges. Consequently, this study will focus on designing an accurate implant via implementing the reverse engineering of three-dimensional morphological study based on a particular population. By using finite element analysis, this study will assist to predict the outcome and could become a useful tool for preclinical testing of newly designed implants. A prototype is then fabricated using 316L stainless steel by applying investment casting techniques that reduce manufacturing cost without jeopardizing implant quality. The finite element analysis showed that the maximum von Mises stress was 66.88 MPa proximally with a safety factor of 2.39 against endosteal fracture, and micromotion was 4.73 μm, which promotes osseointegration. This method offers a fabrication process of cementless femoral stems with lower cost, subsequently helping patients, particularly those from nondeveloped countries.

  12. Technical Letter Report on the Cracking of Irradiated Cast Stainless Steels with Low Ferrite Content

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Y. [Argonne National Lab. (ANL), Argonne, IL (United States); Alexandreanu, B. [Argonne National Lab. (ANL), Argonne, IL (United States); Natesan, K. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2014-11-01

    Crack growth rate and fracture toughness J-R curve tests were performed on CF-3 and CF-8 cast austenite stainless steels (CASS) with 13-14% of ferrite. The tests were conducted at ~320°C in either high-purity water with low dissolved oxygen or in simulated PWR water. The cyclic crack growth rates of CF-8 were higher than that of CF-3, and the differences between the aged and unaged specimens were small. No elevated SCC susceptibility was observed among these samples, and the SCC CGRs of these materials were comparable to those of CASS alloys with >23% ferrite. The fracture toughness values of unirradiated CF-3 were similar between unaged and aged specimens, and neutron irradiation decreased the fracture toughness significantly. The fracture toughness of CF-8 was reduced after thermal aging, and declined further after irradiation. It appears that while lowering ferrite content may help reduce the tendency of thermal aging embrittlement, it is not very effective to mitigate irradiation-induced embrittlement. Under a combined condition of thermal aging and irradiation, neutron irradiation plays a dominant role in causing embrittlement in CASS alloys.

  13. Response of duplex Cr(N)/S and Cr(C)/S coatings on 316L stainless steel to tribocorrosion in 0.89% NaCl solution under plastic contact conditions.

    Science.gov (United States)

    Sun, Y; Dearnley, P A; Mallia, Bertram

    2016-04-27

    Two duplex coatings, Cr(N)/S and Cr(C)/S, were deposited on 316 L stainless steel by magnetron sputtering. The effectiveness of these duplex coatings in improving the tribocorrosion behavior of medical alloys under elastic contact conditions has been demonstrated in a recent publication. The present work focused on the response of these duplex coatings to tribocorrosion under plastic contact conditions. Tribocorrosion tests were conducted in 0.89% NaCl solution at 37°C at an initial contact pressure of 740 MPa and under unidirectional sliding conditions for sliding duration up to 24 h. The results showed that during sliding in the corrosive solution, the duplex coatings were plastically deformed into the substrate to a depth about 1 μm. The Cr(C)/S duplex coating had sufficient ductility to accommodate the deformation without cracking, such that it was worn through gradually, leading to the gradual increase in open circuit potential (OCP) and coefficient of friction (COF). On the other hand, the Cr(N)/S duplex coating suffered from cracking at all tested potentials, leading to coating blistering after prolonged sliding at OCP and stable pit formation in the substrate beneath the coating at applied anodic potentials. © 2016 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 2016.

  14. Effect of Welding Processes on Tensile and Impact Properties, Hardness and Microstructure of AISI 409M Ferritic Stainless Joints Fabricated by Duplex Stainless Steel Filler Metal

    Institute of Scientific and Technical Information of China (English)

    A K Lakshminarayanan; K Shanmugam; V Balasubramanian

    2009-01-01

    The effect of welding processes such as shielded metal arc welding, gas metal arc welding and gas tungsten arc welding on tensile and impact properties of the ferritic stainless steel conforming to AISI 409M grade is studied. Rolled plates of 4 mm thickness were used as the base material for preparing single pass butt welded joints. Tensile and impact properties, microhardness, microstructure and fracture surface morphology of the welded joints have been evaluated and the results are compared. From this investigatio.n, it is found that gas tungsten arc welded joints of ferritic stainless steel have superior tensile and impact properties compared with shielded metal are and gas metal arc welded joints and this is mainly due to the presence of finer grains in fusion zone and heat affected zone.

  15. Evaluation of structural behaviour and corrosion resistant of austenitic AISI 304 and duplex AISI 2304 stainless steel reinforcements embedded in ordinary Portland cement mortars; Evaluacion del comportamiento estructural y de resistencia a la corrosion de armaduras de acero inoxidable austenitico AISI 304 y duplex AISI 2304 embebidas en morteros de cemento Portland

    Energy Technology Data Exchange (ETDEWEB)

    Medina, E.; Cobo, A.; Bastidas, D. M.

    2012-07-01

    The mechanical and structural behaviour of two stainless steels reinforcements, with grades austenitic EN 1.4301 (AISI 304) and duplex EN 1.4362 (AISI 2304) have been studied, and compared with the conventional carbon steel B500SD rebar. The study was conducted at three levels: at rebar level, at section level and at structural element level. The different mechanical properties of stainless steel directly influence the behaviour at section level and structural element level. The study of the corrosion behaviour of the two stainless steels has been performed by electrochemical measurements, monitoring the corrosion potential and the lineal polarization resistance (LPR), of reinforcements embedded in ordinary Portland cement (OPC) mortar specimens contaminated with different amount of chloride over one year time exposure. Both stainless steels specimens embedded in OPC mortar remain in the passive state for all the chloride concentration range studied after one year exposure. (Author) 26 refs.

  16. Environmental fatigue behaviors of wrought and cast stainless steels in 310 .deg. C Deoxygenated Water

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Pyung Yeon

    2011-02-15

    Environmental fatigue behaviors of wrought type 316LN stainless steel and cast CF8M stainless steel were investigated. LCF tests were performed at fixed strain rate of 0.04%/s with 0.4%, 0.6%, 0.8%, 1.0% strain amplitudes in 310 .deg. C deoxygenated water environment. In addition, to analyze microstructure effect on fatigue behavior, low cycle fatigue tests in air environment were performed at fixed strain rate of 0.4%/s, 0.04%/s with 0.4%, 0.8% strain amplitudes. It was shown that the low cycle fatigue life of CF8M in a 310 .deg. C deoxygenated water environment was slightly longer than that of 316LN. On the other hand, the low cycle fatigue life of CF8M in a 310 .deg. C air environment was slightly shorter than that of 316LN or was similar with that of 316LN. Through OM observation and phase image analysis, it was confirmed that the ferrite content of CF8M tested in a 310 .deg. C deoxygenated water environment was larger than that of CF8M tested in a 310 .deg. C air environment. It was shown that the ferrite phase fraction of CF8M tested in 310 .deg. C deoxygenated water environment was approximately 26∼28% and that of CF8M tested in air environment was approximately 10∼12%. The difference of ferrite content in CF8M results in superior tensile properties as higher ferrite content. Furthermore, the difference of ferrite content in CF8M might be the cause of different result of fatigue life between CF8M and 316LN depending on environment. In this study, focused on CF8M having 26∼28% ferrite content, to understand the causes of these differences in a 310 .deg. C deoxygenated water environment, fracture surface and crack morphology were observed. And material factors like microstructure, mechanical properties factors like stress behavior during fatigue life, factors by environmentally assisted cracking (EAC) like hydrogen induced cracking (HIC) and chemical compositions of both materials were analyzed. Mainly in a 310 .deg. C deoxygenated water environment, the

  17. Analysis of cracking phenomena in continuous casting of 1Cr13 stainless steel billets with final electromagnetic stirring

    Institute of Scientific and Technical Information of China (English)

    Yu Xu; Rong-jun Xu; Zheng-jie Fan; Cheng-bin Li; An-yuan Deng; En-gang Wang

    2016-01-01

    Solidification cracking that occurs during continuous casting of 1Cr13 stainless steel was investigated with and without final elec-tromagnetic stirring (F-EMS). The results show that cracks initiates and propagates along the grain boundaries where the elements of carbon and sulfur are enriched. The final stirrer should be appropriately placed at a location that is 7.5 m away from the meniscus, and the appropri-ate thickness of the liquid core in the stirring zone is 50 mm. As a stirring current of 250 A is imposed, it can promote columnar-equiaxed transition, decrease the secondary dendrite arm spacing, and reduce the segregation of both carbon and sulfur. F-EMS can effectively de-crease the amount of cracks in 1Cr13 stainless steel.

  18. Effects of cooling time and alloying elements on the microstructure of the gleeble-simulated heat-affected zone of 22% Cr duplex stainless steels

    Science.gov (United States)

    Hsieh, Rong-Iuan; Liou, Horng-Yih; Pan, Yeong-Tsuen

    2001-10-01

    The effects of austenite stabilizers, such as nitrogen, nickel, and manganese, and cooling time on the microstructure of the Gleeble simulated heat-affected zone (HAZ) of 22% Cr duplex stainless steels were investigated. The submerged are welding was performed for comparison purposes. Optical microscopy (OM) and transmission electron microscopy (TEM) were used for microscopic studies. The amount of Cr2N precipitates in the simulated HAZ was determined using the potentiostatic electrolysis method. The experimental results indicate that an increase in the nitrogen and nickel contents raised the δ to transformation temperature and also markedly increased the amount of austenite in the HAZ. The lengthened cooling time promotes the reformation of austenite. An increase in the austenite content reduces the supersaturation of nitrogen in ferrite matrix as well as the precipitation tendency of Cr2N. The optimum cooling time from 800 to 500 °C (Δ t 8/5) obtained from the Gleeble simulation is between 30 and 60 s, which ensures the austenite content in HAZ not falling below 25% and superior pitting and stress corrosion cracking resistance for the steels. The effect of manganese on the formation of austenite can be negligible.

  19. 2205双相不锈钢固溶处理工艺研究%The Technical Study of 2205 Duplex Stainless Steel Solid Solution Treatment

    Institute of Scientific and Technical Information of China (English)

    伍曦耘

    2009-01-01

    2205 duplex stainless steel was solid solution treated at different temperature between 910~1 300℃ heating for 40 min, then by water cooling or air cooling. The microstructure was observed by a metallographic microscope and α phase content and the hardness were tested, as well as the corrosion resistance was analyzed. The results showed that α phase rising in content gradually with the solid solution temperature increasing. We suggested that the optimized technology was heated at 1 070℃ for 40 min by water cooling.%2205双相不锈钢在910~1 300℃不同的温度保温40 min后,分别进行空冷或水冷固溶处理.用金相显微镜观察了2205双相不锈钢的显微组织,测定了组织α相的含量和显微硬度.结果表明:随着固溶处理温度的升高,α相含量逐渐升高.建议2205双相不锈钢的固溶处理工艺为固溶温度1 070℃,保温40 min,水冷.

  20. Atmospheric-Induced Stress Corrosion Cracking of Grade 2205 Duplex Stainless Steel—Effects of 475 °C Embrittlement and Process Orientation

    Directory of Open Access Journals (Sweden)

    Cem Örnek

    2016-07-01

    Full Text Available The effect of 475 °C embrittlement and microstructure process orientation on atmospheric-induced stress corrosion cracking (AISCC of grade 2205 duplex stainless steel has been investigated. AISCC tests were carried out under salt-laden, chloride-containing deposits, on U-bend samples manufactured in rolling (RD and transverse directions (TD. The occurrence of selective corrosion and stress corrosion cracking was observed, with samples in TD displaying higher propensity towards AISCC. Strains and tensile stresses were observed in both ferrite and austenite, with similar magnitudes in TD, whereas, larger strains and stresses in austenite in RD. The occurrence of 475 °C embrittlement was related to microstructural changes in the ferrite. Exposure to 475 °C heat treatment for 5 to 10 h resulted in better AISCC resistance, with spinodal decomposition believed to enhance the corrosion properties of the ferrite. The austenite was more susceptible to ageing treatments up to 50 h, with the ferrite becoming more susceptible with ageing in excess of 50 h. Increased susceptibility of the ferrite may be related to the formation of additional precipitates, such as R-phase. The implications of heat treatment at 475 °C and the effect of process orientation are discussed in light of microstructure development and propensity to AISCC.

  1. A New Resource-Saving, High Chromium and Manganese Super Duplex Stainless Steels 29Cr-12Mn-2Ni-1Mo-xN

    Institute of Scientific and Technical Information of China (English)

    MA Zheng-huan; ZHAO Xiang-juan; GE Chang-sheng; DING Tie-suo; LI Jun; XIAO Xue-shan

    2011-01-01

    A new family of resource saving, high chromium and manganese super duplex stainless steels (DSSs), with a composition in mass percent, % of Cr 0.29, Mn 0.12, Ni 2.0, Mo i. 0, and N 0. 51-0. 68, has been developed by examining the effect of N on the microstructure, mechanical properties and corrosion properties. The results show that these alloys have a balanced ferrite-austenite relation. The austenite volume fraction decreases with the solution treatment temperature, but it increases with an increase in N content. The increases in nitrogen enhance the ultimate tensile strength (UTS) and reduce the ductility of the material slightly. The pitting corrosion potential increases first and then decreases with an increase in nitrogen content when the amount of N arrives to 0.68%. The yield stress and ultimate tensile strength of solution treated samples were more than 680 and 900 MPa, the elongation of experimental alloys are higher than 30%, respectively, what is more, the pitting potentials were beyond 1 100 mV.

  2. Surface modification of 2205 duplex stainless steel by low temperature salt bath nitrocarburizing at 430 °C

    Science.gov (United States)

    Huang, Runbo; Wang, Jun; Zhong, Si; Li, Mingxing; Xiong, Ji; Fan, Hongyuan

    2013-04-01

    2205 stainless steel was modified by salt bath nitrocarburizing at 430 °C in this study. The microstructure, surface hardness and erosion-corrosion resistance were systematically evaluated. Salt bath nitrocarburizing at 430 °C can form a nitrocarburized layer, and with the treated time prolong, the thickness of the layer increased. By nitrocarburizing within 8 h, only expanded austenite (S phase) formed. With treated time increased, CrN gradually diffused from the places where there were ferrite grains in the layer before nitrocarburizing. Besides, the depth increased with the nitrocarburized time and the layer grew approximately conforms to the parabolic rate law. Salt bath nitrocarburizing can effectively improve the surface hardness of 2205 DSS. The erosion-corrosion resistance was improved by salt bath nitrocarburizing and the 16 h treated sample had the best erosion-corrosion behavior.

  3. Observations of Ferrite/Austenite Transformations in the Heat Affected Zone of 2205 Duplex Stainless Steel Spot Welds Using Time Resolved X-Ray Diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, T; Elmer, J; Babu, S

    2003-10-29

    Time Resolved X-Ray Diffraction (TRXRD) measurements are made in the Heat Affected Zone (HAZ) of 2205 Duplex Stainless Steel (DSS) spot welds. Both the {gamma} {yields} {delta} and {delta} {yields} {gamma} transformations are monitored as a function of time during the rapid spot weld heating and cooling cycles. These observations are then correlated with calculated thermal cycles. Where the peak temperatures are highest ({approx}1342 C), the {gamma} {yields} {delta} transformation proceeds to completion, leaving a ferritic microstructure at the end of heating. With lower peak temperatures, the {gamma} {yields} {delta} transformation proceeds to only partial completion, resulting in a microstructure containing both transformed and untransformed austenite. Further analyses of the individual diffraction patterns show shifts in the peak positions and peak widths as a function of both time and temperature. In addition, these changes in the peak characteristics are correlated with measured changes in the ferrite volume fraction. Such changes in the peak positions and widths during the {gamma} {yields} {delta} transformation provide an indication of changes occurring in each phase. These changes in peak properties can be correlated with the diffusion of nitrogen and other substitutional alloying elements, which are recognized as the primary mechanisms for this transformation. Upon cooling, the {delta} {yields} {gamma} transformation is observed to proceed from both the completely and partially transformed microstructural regions in the TRXRD data. An examination of the resulting microstructures confirms the TRXRD observation as the evidence shows that austenite both nucleates and grows from the ferritic microstructure at locations closest to the fusion zone boundary and grows from untransformed austenite grains at locations further from this boundary.

  4. Effect of oxygen on weld shape and crystallographic orientation of duplex stainless steel weld using advanced A-TIG (AA-TIG) welding method

    Energy Technology Data Exchange (ETDEWEB)

    Zou, Ying, E-mail: yingzou@jwri.osaka-u.ac.jp; Ueji, Rintaro; Fujii, Hidetoshi

    2014-05-01

    The double-shielded advanced A-TIG (AA-TIG) welding method was adopted in this study for the welding of the SUS329J4L duplex stainless steel with the shielding gases of different oxygen content levels. The oxygen content in the shielding gas was controlled by altering the oxygen content in the outer layer gas, while the inner layer remained pure argon to suppress oxidation on the tungsten electrode. As a result, a deep weld penetration was obtained due to the dissolution of oxygen into the weld metals. Additionally, the microstructure of the weld metal was changed by the dissolution of oxygen. The austenite phase at the ferrite grain boundary followed a Kurdjumov–Sachs (K–S) orientation relationship with the ferrite matrix phase at any oxide content. On the other hand, the orientation relationship between the intragranular austenite phase and the ferrite matrix phase exhibited different patterns under different oxygen content levels. When there was little oxide in the fusion zone, only a limited part of the intragranular austenite phase and the ferrite matrix phase followed the K–S orientation relationship. With the increase of the oxide, the correspondence of the K–S relationship increased and fit very well in the 2.5% O{sub 2} shielded sample. The investigation of this phenomenon was carried out along with the nucleation mechanisms of the intragranular austenite phases. - Highlights: • Weld penetration increased with the increase of the oxygen content. • Average diameter and number density of oxide were changed by the oxygen content. • K-S relationship of Widmanstätten austenite/ferrite wasn’t varied by oxide. • Orientation relationship of intragranular austenite/ferrite was varied by oxide.

  5. Influence of the working electrode area on the cavitation-corrosion behaviour of a duplex stainless steel in aqueous LiBr solution

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Garcia, D.M.; Blasco-Tamarit, E.; Igual-Munoz, A.; Garcia-Anton, J. [Valencia Univ. Politecnica, Dept. de Ingenieria Quimica y Nuclear. ETSI Industriales, Valencia (Spain)

    2009-07-01

    Cavitation erosion can occur in almost all hydrodynamic systems and turbo machines, e.g. pumps, valves, marine propeller and hydraulic turbines. It causes serious material damage. Corrosion problems associated with cavitation can appear on different points in LiBr absorption machines. Many efforts have been made to solve this problem, such as optimizing the design of the flow-handling component and selecting better materials and coatings to resist the cavitation erosion-corrosion. A better understanding of cavitation erosion-corrosion mechanisms is very important for the selection materials and coatings. The objective of the present work was to study the influence of the exposed area of the working electrode on the corrosion behaviour of a duplex stainless steel (EN 1.4462) in a 992 g/l LiBr solution under static conditions (without cavitation) and dynamic conditions (with cavitation) at 25 C. Potentiodynamic cyclic curves were obtained under static and dynamic conditions exposing different areas of the working electrode: 1.6 mm diameter (0.02 cm{sup 2} area ), 4 mm diameter (0.12 cm{sup 2} area), 6 mm diameter (0.28 cm{sup 2} area) and 8 mm diameter (0.5 cm{sup 2} area). The dynamic conditions were generated using an ultrasonic cavitation facility in a three-electrode electrochemical cell. The Potentiodynamic Cyclic curves obtained with and without cavitation have been compared and different tendencies were observed. Cavitation increased the cathodic current density when the exposed area to the solution is large (6 mm and 8 mm diameters). This behaviour was not observed during the tests with smaller electrode areas (1.6 mm and 4 mm diameters). In all cases, cavitation increased the anodic current densities independently of the exposed area to the solution. Besides, cavitation favoured the pitting corrosion, since lower pitting potentials were obtained under cavitation conditions than under static conditions. (authors)

  6. Characterization by X ray diffraction of deleterious phases precipitated in a super duplex stainless steel; Caracterizacao por difracao de raios X de fases deleterias precipitadas em aco inoxidavel superduplex

    Energy Technology Data Exchange (ETDEWEB)

    Pardal, Juan M.; Tavares, Sergio S. Maior; Fonseca, Maria P. Cindra; Montenegro, Talles Ribeiro, E-mail: juanpardal@vm.uff.b [Universidade Federal Fluminense (PGEMEC/UFF), Niteroi, RJ (Brazil). Programa de Pos-graduacao em Engenharia Mecanica; Dias, Antonio Jose N.; Almeida, Sergio L. de [Instituto Nacional de Tecnologia (INT), Rio de Janeiro, RJ (Brazil). Div. de Materiais Ceramicos e Metalicos. Lab. de Tecnologia de Materiais

    2010-07-01

    In this work the identification and quantification of deleterious phases in two super duplex stainless steels grade UNS S32750, with quite different grain sizes, was performed by X-ray diffraction. The materials were isothermally aged in the 800 . 950 deg C range. Direct comparison method was used to quantify the ferrite phase in each sample. The amount of deleterious phases ({sigma}, {chi} and {gamma}2) formed was calculated by the difference of the amount of ferrite phase measured in each specimen to the amount of ferrite initially measured in the un-aged steel. The results obtained give an useful contribution to the understanding of kinetics of deleterious phases precipitation in super duplex steels. (author)

  7. Study on wear resistant cast B-containing 1Cr18Ni9Ti stainless steel

    Institute of Scientific and Technical Information of China (English)

    Kuang Jiacai; Jiang Zhiqiang; Zhang Shiyin; Ye Chang; Liu Qicheng

    2009-01-01

    The developed 1Cr18Ni9Ti austenitic stainless steel containing 1.63 wt.%B have been characterized by X-ray diffraction (XRD), electron probe microanalyzer (EPMA), optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and Vickers microhardness measurement. The microstructural evolution and property of high boron stainless steel after solution treatment at the temperature of 1050℃ are also investigated. The results show that the main compositions of borides are Fe, Cr and B, and with small amount of Ni, Mn and C elements. Silicon is insoluble in the borides. The hardness of borides is over 1,500 HV. It has been found that borides do not decompose during solution treatment, but part of borides dissolves into the matrix. The effect of increasing the solubility of boron element in the austenitic matrix favours the hardness enhancement by 8.54%. High boron stainless steel has excellent wear resistance in corrosive environment. Lifetime of transfer pipe made of high boron-containing stainless steel is 1.5-1.8 times longer than that of boron-free 1Cr18Ni9Ti stainless steel.

  8. Thermal Response of Mould in High Speed Casting of Stainless Steel Billet

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    An industrial trial was conducted on a billet-casting machine at Atlas Steel, Canada, during which a mould was instrumented with 52 thermocouples. The measured data of ten heats were collected to determine mould wall temperature profiles for different steel grades at different casting speeds. Based on these data, heat fluxes were calculated with inverse heat conduction model. Heat fluxes for different operating parameters were compared and analyzed.

  9. Energy Saving Melting and Revert Reduction (E-SMARRT): Optimization of Heat Treatments on Stainless Steel Castings for Improved Corrosion Resistance and Mechanical Properties

    Energy Technology Data Exchange (ETDEWEB)

    John N. DuPont; Jeffrey D. Farren; Andrew W. Stockdale; Brett M. Leister

    2012-06-30

    It is commonly believed that high alloy steel castings have inferior corrosion resistance to their wrought counterparts as a result of the increased amount of microsegregation remaining in the as-cast structure. Homogenization and dissolution heat treatments are often utilized to reduce or eliminate the residual microsegregation and dissolve the secondary phases. Detailed electron probe microanalysis (EPMA) and light optical microscopy (LOM) were utilized to correlate the amount of homogenization and dissolution present after various thermal treatments with calculated values and with the resultant corrosion resistance of the alloys.The influence of heat treatment time and temperature on the homogenization and dissolution kinetics were investigated using stainless steel alloys CN3MN and CK3MCuN. The influence of heat treatment time and temperature on the impact toughness and corrosion reistance of cast stainless steel alloys CF-3, CF-3M, CF-8, and CF-8M was also investigated.

  10. Field Evaluations of Low-Frequency SAFT-UT on Cast Stainless Steel and Dissimilar Metal Weld Components

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, Aaron A.; Harris, R. V.; Doctor, Steven R.

    2008-11-01

    This report documents work performed at the Pacific Northwest National Laboratory (PNNL) in Richland, Washington, and at the Electric Power Research Institute's (EPRI) Nondestructive Examination (NDE) Center in Charlotte, North Carolina, on evalutating a low frequency ultrasonic inspection technique used for examination of cast stainless steel (CSS) and dissimilar metal (DMW) reactor piping components. The technique uses a zone-focused, multi-incident angle, low frequency (250-450 kHz) inspection protocol coupled with the synthetic aperture focusing technique (SAFT). The primary focus of this work is to provide information to the United States Nuclear Regulatory Commission on the utility, effectiveness and reliability of ultrasonic testing (UT) inspection techniques as related to the inservice ultrasonic inspection of coarse grained primary piping components in pressurized water reactors (PWRs).

  11. Effects of Thermocapillary Forces during Welding of 316L-Type Wrought, Cast and Powder Metallurgy Austenitic Stainless Steels

    CERN Document Server

    Sgobba, Stefano

    2003-01-01

    The Large Hadron Collider (LHC) is now under construction at the European Organization for Nuclear Research (CERN). This 27 km long accelerator requires 1248 superconducting dipole magnets operating at 1.9 K. The cold mass of the dipole magnets is closed by a shrinking cylinder with two longitudinal welds and two end covers at both extremities of the cylinder. The end covers, for which fabrication by welding, casting or Powder Metallurgy (PM) was considered, are dished-heads equipped with a number of protruding nozzles for the passage of the different cryogenic lines. Structural materials and welds must retain high strength and toughness at cryogenic temperature. AISI 316L-type austenitic stainless steel grades have been selected because of their mechanical properties, ductility, weldability and stability of the austenitic phase against low-temperature spontaneous martensitic transformation. 316LN is chosen for the fabrication of the end covers, while the interconnection components to be welded on the protrud...

  12. Electrochemical noise transient analysis for 316 and Duplex 2205 stainless steels in NaCl and FeCl; Analisis de los transitorios de ruido electroquimico para aceros inoxidables 316 Y - DUPLEX 2205 en NaCl Y FeCl

    Energy Technology Data Exchange (ETDEWEB)

    Almeraya-Calderaon, F.; Estupinan, F.; Zambrano, P.; Martinez-Villafane, A.; Borunda, A.; Colas, R.; Gaona-Tiburcio, C.

    2012-11-01

    This work shows the results obtained from electrochemical noise measurements for different materials exhibiting pitting corrosion. The transients presented in the potential and current time, correlates with the scanning electron microscopy (SEM) surface analysis. Electrochemical measurements were made at different exposure times to obtain the correlation. The materials used were stainless steel austenitic 316 and duplex 2205, immersed in ferric chloride (FeCl3) and sodium chloride (NaCl) electrolytes. SEM analysis shows that the transients observed in the time series, really correspond to the activity of pit nucleation developed over the surface of the electrodes. (Author) 31 refs.

  13. Estudo da soldagem de tubos de aço inoxidável duplex e superduplex na posição 5G Study of the welding of duplex and superduplex stainless steel pipes in the 5G position

    Directory of Open Access Journals (Sweden)

    Pedro Ivo Guimarães de Vasconcellos

    2010-09-01

    Full Text Available Os aços inoxidáveis duplex e superduplex possuem uma microestrutura austeno-ferrítica com fração média de cada fase de cerca 50%. A microestrutura duplex é responsável pelas excelentes propriedades mecânicas, especialmente o limite de escoamento e a tenacidade, e pela elevada resistência a corrosão por pites e sob tensão em meios contendo cloretos. A soldagem destes aços é frequentemente uma operação crítica. Neste trabalho, um tubo de superduplex SAF 2207 foi soldado pelo processo TIG (GTAW no passe de raiz e eletrodo revestido (SMAW nos passes de enchimento, e um tubo de duplex SAF 2205 foi todo soldado pelo processo GTAW. A microestrutura do metal base, zona afetada termicamente (ZTA e metal de solda foi caracterizada e quantificada. As propriedades de tenacidade, resistência a corrosão e composição química foram avaliadas e correlacionadas. Os valores de tenacidade ao impacto Charpy-V foram considerados adequados. Não foi observada a precipitação de intermetálicos, carbonetos e nitretos. O melhor resultado no teste de corrosão da junta soldada de aço inox superduplex, comparado ao duplex, foi atribuído ao baixo teor de ferrita delta na solda e ZTA, e composição química da solda enriquecida em Cr, Mo, W e N.The duplex and superduplex stainless steels have an austenitic-ferritic microstructure with an average fraction of each phase of approximately 50%. This duplex microstructure is responsible for the excellent mechanical properties, specially the yield strength and toughness, and for the improved pitting and stress corrosion cracking resistance in chloride environments. Welding of these steels is often a critical operation. In this work, a superduplex stainless steel SAF 2507 pipe was welded by the GTAW process in the root pass and by SMAW process on filler passes, and one pipe of duplex SAF 2205 was entirely welded by the GTAW process. The microstructure of the base metal, heat affected zone (HAZ and weld

  14. Evaluation of stress corrosion of duplex stainless steel overlay%双相不锈钢堆焊层应力腐蚀性能评价

    Institute of Scientific and Technical Information of China (English)

    王晶; 张亦良; 仇飞; 吴道文

    2013-01-01

    为防止换热器等设备发生应力腐蚀,工程上试采用在与腐蚀介质接触的表面堆焊2205双相不锈钢.为探索方案的应用范畴与可行性,对两种焊接工艺(自动焊及焊条电弧焊)、3种工程上常见腐蚀环境(饱和硫化氢、氯化镁、氯化钙),通过恒负荷拉伸试验方法及断口微观分析手段,综合评价其应力腐蚀性能,并根据试验结果建立应力-寿命数学模型.结果表明,饱和H2S环境中恒负荷拉伸门槛值σth自动焊为0.45ReL、焊条电弧焊为0.4ReL,二者相差17%.氯化钙环境中0.9ReL应力下96 h试验后所有试样完好,显示出优良的抗氯化钙应力腐蚀能力.而该材料则不适于在沸腾氯化镁环境下工作.%In order to prevent stress corrosion in petrochemical facilities, 2205 duplex stainless steel was deposited on the surface contacted with the corrosive media in projects. In order to explore the application scope and feasibility of the solution, two welding processes ( automatic welding and manual welding) , three kinds of common corrosion environment ( saturated hydrogen sulfide, magnesium chloride, calcium chloride) were used to evaluate its stress corrosion comprehensively at the constant tensile load based on the microanalysis of fracture, and the mathematical model of stress-life was established based on the experimental results. The results indicate that the constant tensile load threshold is 0.45 ReL for automatic welding and 0.4 ReL for manual welding in saturated H2S environment, and there is an error of 17% between them. All the samples are good after 96 hours in 0. 9 ReL stress test with the calcium chloride environment , which shows the excellent resistance to chloride stress corrosion. But the coating cannot be used in boiling magnesium chloride environment.

  15. Temperature effects on the static and dynamic fracture behaviors of low-silicon CA-15 tempered stainless steel castings

    Science.gov (United States)

    Hsu, Cheng-Hsun; Teng, Hwei-Yuan

    2005-04-01

    In this research we studied the effect of testing temperature on both static and dynamic fracturing behaviors of low-silicon CA-15 martensitic stainless steel (MSS) castings after austenitizing and tempering treatments. The results showed that the material's microstructure was influenced by heat treatment and various testing temperatures would cause different fracturing mechanisms. In static tensile tests, the 573-673 K tempered specimens occurred secondary strengthening at 423 K and 298 K testing temperatures. However, there is a contrast of weakening occurred at 123 K for the same type of tempered samples. The phenomenon was mainly triggered by local cracking at the ferrite/martensitic interface and incoherent precipitate site in the materials because of the existence of shrinkage stress under subzero temperature. In the dynamic strain-rate tests, impact embrittlement occurred in the 573-673 K tempered samples as a result of the tempered martensite embrittlement (TME) phenomenon. The ductile-to-brittle transition temperature (DBTT) of the tempered material was obviously lower than that of the as-cast material. Also, optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were performed to correlate the properties attained to the microstructural observation.

  16. Duplex ultrasound

    Science.gov (United States)

    Vascular ultrasound; Peripheral vascular ultrasound ... A duplex ultrasound combines: Traditional ultrasound: This uses sound waves that bounce off blood vessels to create pictures. Doppler ultrasound: This ...

  17. Ultrasonic Characterization of Cast Austenitic Stainless Steel Microstructure: Discrimination between Equiaxed- and Columnar-Grain Material – An Interim Study

    Energy Technology Data Exchange (ETDEWEB)

    Ramuhalli, Pradeep; Good, Morris S.; Diaz, Aaron A.; Anderson, Michael T.; Watson, Bruce E.; Peters, Timothy J.; Dixit, Mukul; Bond, Leonard J.

    2009-10-27

    Ultrasonic nondestructive evaluation (NDE) and inspection of cast austenitic stainless steel (CASS) components used in the nuclear power industry is neither as effective nor reliable as is needed due to detrimental effects upon the interrogating ultrasonic beam and interference from ultrasonic backscatter. The root cause is the coarse-grain microstructure inherent to this class of materials. Some ultrasonic techniques perform better for particular microstructural classifications and this has led to the hypothesis that an ultrasonic inspection can be optimized for a particular microstructural class, if a technique exists to reliably classify the microstructure for feedback to the inspection. This document summarizes scoping experiments of in-situ ultrasonic methods for classification and/or characterization of the material microstructures in CASS components from the outside surface of a pipe. The focus of this study was to evaluate ultrasonic methods and provide an interim report that documents results and technical progress. An initial set of experiments were performed to test the hypothesis that in-service characterization of cast austenitic stainless steel (CASS) is feasible, and that, if reliably performed, such data would provide real-time feedback to optimize in-service inspections in the field. With this objective in mind, measurements for the experiment were restricted to techniques that should be robust if carried forward to eventual field implementation. Two parameters were investigated for their ability to discriminate between different microstructures in CASS components. The first parameter was a time-of-flight ratio of a normal incidence shear wave to that of a normal incidence longitudinal wave (TOFRSL). The ratio removed dependency on component thickness which may not be accurately reported in the field. The second parameter was longitudinal wave attenuation. The selected CASS specimens provided five equiaxed-grain material samples and five columnar

  18. Heat treatment of investment cast PH 13-8 Mo stainless steel: Part II. Isothermal aging kinetics

    Science.gov (United States)

    Robino, C. V.; Cieslak, M. J.; Hochanadel, P. W.; Edwards, G. R.

    1994-04-01

    The hardening response of investment cast PH 13-8 Mo stainless steel has been evaluated by hardness measurements following aging in the temperature range normally specified for this alloy (510 °C to 593 °C). A new relationship between fraction transformed and hardness was developed, and analysis of the data in terms of the kinetics of precipitation, in a manner similar to that frequently applied to other precipitation-hardenable martensitic steels, yielded low time exponents and a low value for the apparent activation energy. The values of the time exponents were 0.49, 0.37, 0.56, and 0.53 at 510 °C, 538 °C, 566 °C, and 593 °C, respectively, and that for the apparent activation energy was 139 kJ/mole. As has been proposed for other maraging type steels, these estimates suggest that Β-NiAl precipitates along or near dislocations and that growth of the precipitates is dominated by dislocation pipe diffusion. However, these predictions were neither supported nor refuted by transmission electron microscopy (TEM) because of difficulties in imaging the Β-NiAl precipitates at the aging times and temperatures used. Further, analysis of the data using the formalism of Wert and Zener for the growth of precipitates with interfering diffusion fields indicated that the estimates of fraction transformed from hardness data are not fully appropriate for maraging type steels. Consideration of the nature of the Avrami analysis and the electron microscopy results suggests that other phenomena, including dislocation recovery and reversion of martensite to austenite, occur at rates sufficient to convolute the Avrami analysis. It is further suggested that these results cast doubt on the fundamental implications of previous analyses of precipitation kinetics in age-hardening martensitic steels. Although the Avrami analysis was found not to provide a tenable description of the precipitation kinetics, it does provide a reasonable methodology for portrayal of the hardening response

  19. Optimization of the pulsed current gas tungsten arc welding (PCGTAW) parameters for corrosion resistance of super duplex stainless steel (UNS S32760) welds using the Taguchi method

    Energy Technology Data Exchange (ETDEWEB)

    Yousefieh, M., E-mail: m.yousefieh@ma.iut.ac.ir [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Shamanian, M., E-mail: shamanian@cc.iut.ac.ir [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Saatchi, A. [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of)

    2011-01-21

    Research highlights: > Among the four factors and three levels tested, it was concluded that the pulse current had the most significant effect on the pitting potential and the background current had the next most significant effect. The effects of pulse frequency and % on time are less important when compared to the other factors. > The percentage contributions of the pulse current, the background current, % on time, and pulse frequency to the corrosion resistance are 66.28%, 25.97%, 2.71% and 5.04%, respectively. > The optimum conditions within the selected parameter values were found as the second level of pulse current (120 A), second level of background current (60 A), third level of % on time (80%) and third level of pulse frequency (5 Hz). > The confirmation test was carried out at optimum working conditions. Pitting potential was increased to 1.06 V{sub SCE} by setting the control factors. Predicted (1.04 V{sub SCE}) and observed (1.06 V{sub SCE}) pitting potential values are close to each other, which are the highest values obtained in the present study. - Abstract: In the present work, a design of experiment (DOE) technique, the Taguchi method, has been used to optimize the pulsed current gas tungsten arc welding (PCGTAW) parameters for the corrosion resistance of super duplex stainless steel (UNS S32760) welds. A L{sub 9} (3{sup 4}) orthogonal array (OA) of Taguchi design which involves nine experiments for four parameters (pulse current, background current, % on time, pulse frequency) with three levels was used. Corrosion resistance in 3.5%NaCl solution was evaluated by anodic polarization tests at room temperature. Analysis of variance (ANOVA) is performed on the measured data and S/N (signal to noise) ratios. The higher the better response category was selected to obtain optimum conditions. The optimum conditions providing the highest pitting potential were estimated. The optimum conditions were found as the second level of pulse current (120 A

  20. Avaliação da soldagem multipasse de chapas espessas de aços inoxidáveis lean duplex UNS S32304 soldadas pelos processos SMAW, GMAW e FCAW: parte 1: propriedades mecânicas Evaluation of multipass welding of thick lean duplex stainless steel UNS S32304 plates welded by SMAW, GMAW and FCAW: part 1: Mechanical Properties

    Directory of Open Access Journals (Sweden)

    Ronaldo Cardoso Junior

    2012-12-01

    Full Text Available Os aços inoxidáveis duplex (AID vêm se apresentando como uma excelente alternativa para aplicações em que alta resistência à corrosão e alta resistência mecânica são requeridas. Contudo, os AID, incluindo os aços inoxidáveis lean duplex, apresentam soldabilidade inferior em relação aos aços inoxidáveis austeníticos. Nesse sentido, esse trabalho tem como objetivo a avaliação da soldagem multipasse de chapas 22 mm de espessura da liga inoxidável lean duplex UNS S32304, utilizando-se os processo SMAW, GMAW e FCAW e consumíveis com dois tipos de composição química, 22%Cr9%Ni3%Mo e 23%Cr7%Ni, totalizando seis experimentos. Foram empregados chanfros em V com 60º e suporte cerâmico para soldagem do passe de raiz, sendo que o aporte térmico foi mantido praticamente constante em 1,6 kJ.mm-1. Determinou-se os tempos de soldagem e a seqüência de passes, objetivando uma análise de produtividade, em seguida as juntas soldadas foram submetidas à END por raios x. Foram extraídos corpos de prova para ensaios de tração, dobramento, Charpy a -30 ºC e microdureza. A produtividade dos processos semi-automáticos se mostrou pelo menos 63 % maior que a do processo SMAW, enquanto o processo FCAW se mostrou de 6 a 18% mais rápido que o GMAW. Foram encontradas descontinuidades (porosidade consideradas aceitáveis segundo ASME B31.3 em alguns dos experimentos, que não influenciaram negativamente os resultados mecânicos, os quais se apresentaram acima requerimento do metal de base e especificado por normas de fabricação.The duplex stainless steels (DSS's have been placed as an excellent alternative for applications where high corrosion resistance and high mechanical strength are required. However, DSS's, including the lean duplex, present lower weldability than the austenitic stainless steels. Thus, this study aims to evaluate the multipass welding of 22 mm plates of lean duplex stainless steel alloy UNS S32304, using the process

  1. In situ TEM study of G-phase precipitates under heavy ion irradiation in CF8 cast austenitic stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Wei-Ying [Argonne National Laboratory, Argonne, IL 60439 (United States); University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Li, Meimei; Zhang, Xuan; Kirk, Marquis A.; Baldo, Peter M. [Argonne National Laboratory, Argonne, IL 60439 (United States); Lian, Tiangan [Electric Power Research Institute, Palo Alto, CA 94304 (United States)

    2015-09-15

    Thermally-aged cast austenitic stainless steels (CASS) CF8 was irradiated with 1 MeV Kr ions at 300, 350 and 400 °C to 1.88 × 10{sup 19} ions/m{sup 2} (∼3 dpa) at the IVEM-Tandem Facility at the Argonne National Laboratory. Before irradiation, the distribution of G-phase precipitates in the ferrite showed spatial variations, and both their size and density were affected by the ferrite–austenite phase boundary and presence of M{sub 23}C{sub 6} carbides. Under 300 °C irradiation, in situ TEM observation showed G-phase precipitates were relatively unchanged in the vicinity of the phase boundary M{sub 23}C{sub 6} carbides, while the density of G-phase precipitates increased with increasing dose within the ferrite matrix. Coarsening of G-phase precipitates was observed in the vicinity of phase boundary M{sub 23}C{sub 6} carbides at 350 °C and 400 °C.

  2. Development of Stronger and More Reliable Cast Austenitic Stainless Steels (H-Series) Based on Scientific Design Methodology

    Energy Technology Data Exchange (ETDEWEB)

    Muralidharan, G.; Sikka, V.K.; Pankiw, R.I.

    2006-04-15

    The goal of this program was to increase the high-temperature strength of the H-Series of cast austenitic stainless steels by 50% and upper use temperature by 86 to 140 F (30 to 60 C). Meeting this goal is expected to result in energy savings of 38 trillion Btu/year by 2020 and energy cost savings of $185 million/year. The higher strength H-Series of cast stainless steels (HK and HP type) have applications for the production of ethylene in the chemical industry, for radiant burner tubes and transfer rolls for secondary processing of steel in the steel industry, and for many applications in the heat-treating industry. The project was led by Duraloy Technologies, Inc. with research participation by the Oak Ridge National Laboratory (ORNL) and industrial participation by a diverse group of companies. Energy Industries of Ohio (EIO) was also a partner in this project. Each team partner had well-defined roles. Duraloy Technologies led the team by identifying the base alloys that were to be improved from this research. Duraloy Technologies also provided an extensive creep data base on current alloys, provided creep-tested specimens of certain commercial alloys, and carried out centrifugal casting and component fabrication of newly designed alloys. Nucor Steel was the first partner company that installed the radiant burner tube assembly in their heat-treating furnace. Other steel companies participated in project review meetings and are currently working with Duraloy Technologies to obtain components of the new alloys. EIO is promoting the enhanced performance of the newly designed alloys to Ohio-based companies. The Timken Company is one of the Ohio companies being promoted by EIO. The project management and coordination plan is shown in Fig. 1.1. A related project at University of Texas-Arlington (UT-A) is described in Development of Semi-Stochastic Algorithm for Optimizing Alloy Composition of High-Temperature Austenitic Stainless Steels (H-Series) for Desired

  3. Phased Array Ultrasonic Sound Field Mapping through Large-Bore Coarse Grained Cast Austenitic Stainless Steel (CASS) Components

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, Susan L.; Cinson, Anthony D.; Prowant, Matthew S.; Coble, Jamie B.; Diaz, Aaron A.; Anderson, Michael T.

    2012-09-01

    A sound field beam mapping exercise was conducted to assist in understanding the effects of coarse-grained microstructures found in cast austenitic stainless steel (CASS) materials on acoustic longitudinal wave propagation. Ultrasonic laboratory measurements were made on three specimens representing four different grain structures. Phased array (PA) probes were fixed on each specimen surface and excited in the longitudinal mode at specific angles while a point receiver was scanned in a raster pattern over the end of the specimen, generating a transmitted sound field image. Three probes operating at nominal frequencies of 0.5, 0.8, and 1.0 MHz were used. A 6.4 mm (0.25-in.) thick slice was removed from the specimen end and beam mapping was repeated three times, yielding four full sets of beam images. Data were collected both with a constant part path for each configuration (probe, specimen and slice, angle, etc.) and with a variable part path (fixed position on the surface). The base specimens and slices were then polished and etched to reveal measureable grain microstructures that were compared to the sound field interactions and scattering effects seen in the collected data.

  4. Heat treatment of investment cast PH 13-8 Mo stainless steel: Part I. Mechanical properties and microstructure

    Science.gov (United States)

    Hochanadel, P. W.; Edwards, G. R.; Robino, C. V.; Cieslak, M. J.

    1994-04-01

    The microstructure of investment cast PH 13-8 Mo stainless steel heat-treated to various conditions was studied using light and electron microscopy, electron probe microanalysis, and Mössbauer spectroscopy. The mechanical properties were investigated by using uniaxial tensile testing, hardness testing, and Charpy impact testing. The Β-NiAl strengthening precipitates, though detectable by electron diffraction, were difficult to resolve by transmission electron microscopy (TEM) in specimens aged at low temperatures (566 °C and below). A high dislocation density was observed in the lath martensitic structure. The higher strength and lower ductility observed at low aging temperatures was attributed to both the high dislocation density and the precipitation of Β-NiAl. When samples were aged at high temperatures (> 566 °C), a lower dislocation density and a reverted austenite fraction on the order of 15 pct were observed. Spherical Β-NiAl precipitates were observed in the overaged condition. The decrease in strength and corresponding increase in ductility observed in samples aged at temperatures above 566 °C were attributed to the reverted austenite and recovery. Mechanical properties were improved when the homogenizing temperature and time were increased. Electron probe microanalysis quantified the increased homogeneity realized by increasing homogenizing temperature and time. Elimination of the refrigeration step, which normally follows the solution treatment, did not degrade the mechanical properties. Mössbauer spectroscopy showed only minor decreases in the fraction of retained austenite when refrigeration followed the solution treatment.

  5. Characteristics of vacuum sintered stainless steels

    OpenAIRE

    Z. Brytan; L.A. Dobrzański; M. Actis Grande; Rosso, M.

    2009-01-01

    Purpose: In the present study duplex stainless steels were sintered in vacuum. using rapid cooling form the mixture of prealloyed and alloying element powders The purpose of this paper was to describe the obtained microstructures after sintering as well as the main mechanical properties of sintered stainless steels.Design/methodology/approach: In presented work duplex stainless steels were obtained through powder metallurgy starting from austenitic 316L or ferritic 410L prealloyed stainless s...

  6. Cast, heat-resistant austenitic stainless steels having reduced alloying element content

    Energy Technology Data Exchange (ETDEWEB)

    Muralidharan, Govindarajan [Knoxville, TN; Sikka, Vinod Kumar [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Pankiw, Roman I [Greensburg, PA

    2010-07-06

    A cast, austenitic steel composed essentially of, expressed in weight percent of the total composition, about 0.4 to about 0.7 C, about 20 to about 30 Cr, about 20 to about 30 Ni, about 0.5 to about 1 Mn, about 0.6 to about 2 Si, about 0.05 to about 1 Nb, about 0.05 to about 1 W, about 0.05 to about 1.0 Mo, balance Fe, the steel being essentially free of Ti and Co, the steel characterized by at least one microstructural component selected from the group consisting of MC, M.sub.23C.sub.6, and M(C, N).

  7. Cast, heat-resistant austenitic stainless steels having reduced alloying element content

    Energy Technology Data Exchange (ETDEWEB)

    Muralidharan, Govindarajan [Knoxville, TN; Sikka, Vinod Kumar [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Pankiw, Roman I [Greensburg, PA

    2011-08-23

    A cast, austenitic steel composed essentially of, expressed in weight percent of the total composition, about 0.4 to about 0.7 C, about 20 to about 30 Cr, about 20 to about 30 Ni, about 0.5 to about 1 Mn, about 0.6 to about 2 Si, about 0.05 to about 1 Nb, about 0.05 to about 1 W, about 0.05 to about 1.0 Mo, balance Fe, the steel being essentially free of Ti and Co, the steel characterized by at least one microstructural component selected from the group consisting of MC, M.sub.23C.sub.6, and M(C, N).

  8. Tensile and Impact Properties of Shielded Metal Arc Welded AISI 409M Ferritic Stainless Steel Joints

    Institute of Scientific and Technical Information of China (English)

    K.Shanmugam; A.K.Lakshminarayanan; V.Balasubramanian

    2009-01-01

    The present study is concerned with the effect of filler metals such as austenitic stainless steel, ferritic stainless steel and duplex stainless steel on tensile and impact properties of the ferritic stainless steel conforming to AISI 409M grade. Rolled plates of 4 mm thickness were used as the base material for preparing single pass butt welded joints. Tensile and impact properties, microhardness, microstructure and fracture surface morphology of the joints fabricated by austenitic stainless steel, ferritic stainless steel and duplex stainless steel filler metals were evaluated and the results were reported. From this investigation, it is found that the joints fabricated by duplex stainless steel filler metal showed higher tensile strength and hardness compared to the joints fabricated by austenitic and ferritic stainless steel filler metals. Joints fabricated by austenitic stainless steel filler metal exhibited higher ductility and impact toughness compared with the joints fabricated by ferritic stainless steel and duplex stainless steel filler metals.

  9. Microstructure evaluation of UNS S32205 duplex stainless steel friction stir welds Avaliação microestrutural de juntas soldadas por atrito com pino não-consumível do aço inoxidável duplex UNS S32205

    Directory of Open Access Journals (Sweden)

    Tiago F. A. Santos

    2013-06-01

    Full Text Available UNS S32205 duplex stainless steel welds were performed by friction stir welding (FSW. Advancing and retreating sides showed distinct characteristics in the welded joint. The advancing side shows the strongest grain refinement which is corroborated by microhardness measurements. The microstructure characterization was carried out by optical, scanning and transmission electron microscopy. The thermomechanically affected zone displays austenite islands deformed in a ferrite matrix. The stir zone (SZ showed a fine recrystallized microstructure providing an outstanding increase of hardness associated with better corrosion performance. Transmission electron microscopy and corrosion tests have corroborated the absence of intermetallic phases on welded joints.Juntas soldadas por atrito com pino foram obtidas para o aço inoxidável duplex UNS S32205. Os lados de avanço e retrocesso da junta soldada evidenciaram diferentes características microestruturais, o lado de avanço apresentou um maior grau de refinamento de grãos, principal mecanismo de aumento de dureza. A caracterização microestrutural foi realizada através de microscopia ótica, eletrônica de varredura e de transmissão. A zona termomecanicamente afetada apresentou ilhas de austenita deformadas em matriz ferrítica. A zona misturada apresentou uma microestrutura fina completamente recristalizada, permitindo um impressionante aumento de dureza, na junta soldada associado a uma melhoria na resistência à corrosão. Avaliações por microscopia eletrônica de transmissão e ensaios de corrosão corroboraram para a ausência de fases secundárias deletérias na junta soldada.

  10. Analysis of Brittleness for Ferritic Stainless Steel 430 As-cast%430铁素体不锈钢铸件脆性分析

    Institute of Scientific and Technical Information of China (English)

    周灿旭; 师红旗; 陈育贵; 丁毅

    2009-01-01

    对430铸造铁素体不锈钢的脆性进行了分析,采用金相显微组织分析、力学性能测试、冲击断口宏观和SEM等技术手段探讨了430不锈钢发生脆化的原因.结果表明:430铸造铁素体不锈钢的脆性主要是由铸造过程中马氏体的生成引起的,通过700℃热处理水冷可以显著提高430铸造铁索体不锈钢的韧性,并同时改善其抗拉强度和塑性.%The brittleness of ferritic stainless steel 430 as-east was analyzed by metaUographic microscope, mechanical properties test, macroscope ffactography and SEM. The results show that the brittleness of ferritic stainless steel 430 as-cast is caused by martensite. The toughness of 430 ferritic stainless steel increases obviously through 700 ℃ heat treatment, while the tensile strength and ductility properties also improves.

  11. Estudo dos efeitos da restrição na microestrutura, microdureza e tenacidade em juntas soldadas em aço inoxidável duplex Study of restriction effects on mMicrostructure, microhardness and toughness in welded joints of duplex stainless steel

    Directory of Open Access Journals (Sweden)

    Everton Barbosa Nunes

    2011-06-01

    Full Text Available Os aços inoxidáveis duplex (AID apresentam em sua microestrutura ferrita e austenita, de modo a aliar boas propriedades mecânicas e resistência à corrosão. Estes materiais possuem grande aplicação na indústria petroquímica, sendo o UNS S31803 um dos mais conhecidos. Existem poucos trabalhos referentes ao estudo da influência da restrição na soldagem da junta na formação de Widmanstätten. Logo, este trabalho tem como objetivo analisar a influência da restrição no balanceamento de fases, na morfologia da austenita, na microdureza e na tenacidade da Zona Afetada pelo Calor (ZAC e da Zona Fundida (ZF. Foram realizadas soldagens em juntas tipo V utilizando eletrodo revestido AWS E2209-17com dois níveis de energia: 15 kJ/cm e 20 kJ/cm, com e sem restrição. De maneira geral, houve maior quantidade de ferrita nos passes de acabamento em relação aos passes de enchimento e de raiz. Foram observadas maiores quantidades de Widmanstätten nas condições soldadas com restrição. A ZAC apresentou uma microestrutura mais grosseira nos passes de acabamento. No entanto, não foram observadas diferenças significativas nas microestruturas quando comparadas as condições com e sem restrição. As condições que apresentaram maior quantidade de Widmanstätten obtiveram menores níveis de microdureza. Não foram observadas diferenças na energia absorvida na ZAC e ZF.Duplex stainless steels present ferrite and austenite in their microstructure in order to join good mechanical properties and corrosion resistance. These materials are very used in petrochemical industry, being the DSS UNS S31803 one of the most commercially known. There were not much published literature to study the influence of the precipitation of Widmanstätten austenite in joins with some restriction. This work has as objective to analyze the influence of the restriction in the phase balance of austenite and ferrite, in the morphology of the austenite, in the

  12. Evaluation of the corrosion resistance of plasma nitrided austenitic stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Mareci, Daniel; Bolat, Georgiana [Technical Univ. Iasi (Romania). Faculty of Chemical Engineering and Environmental Protection; Strugaru, Sorin Iacob; Munteanu, Corneliu [Technical Univ. Iasi (Romania). Faculty of Mechanical Engineering; Souto, Ricardo M. [Univ. of La Laguna, Tenerife (Spain). Dept. of Chemistry

    2015-03-15

    Plasma nitriding at 500 C for 14 h was applied to austenitic 304 stainless steel for surface hardening. The effect of surface treatment on the corrosion resistance of the material was investigated in naturally-aerated 0.5 M NaCl solution for 30 days using linear potentiodynamic polarization and electrochemical impedance spectroscopy methods. Both as-cast and plasma nitrided stainless steel samples underwent spontaneous passivation, though the nitrided sample exhibited more positive zero current potential, higher breakdown potential, and lower anodic current densities than the as-cast material. Impedance spectra were interpreted in terms of a duplex passive film, corrosion resistance mainly arising from a thin inner compact layer, whereas the outer layer was more porous and less sealing. Capacitive behaviour and high corrosion resistance were observed in the low and medium frequency ranges for the nitrided samples.

  13. Development of Cast Alumina-forming Austenitic Stainless Steel Alloys for use in High Temperature Process Environments

    Energy Technology Data Exchange (ETDEWEB)

    Muralidharan, Govindarajan [ORNL; Yamamoto, Yukinori [ORNL; Brady, Michael P [ORNL; Pint, Bruce A [ORNL; Pankiw, Roman [Duraloy Technologies Inc; Voke, Don [Duraloy Technologies Inc

    2015-01-01

    There is significant interest in the development of alumina-forming, creep resistant alloys for use in various industrial process environments. It is expected that these alloys can be fabricated into components for use in these environments through centrifugal casting and welding. Based on the successful earlier studies on the development of wrought versions of Alumina-Forming Austenitic (AFA) alloys, new alloy compositions have been developed for cast products. These alloys achieve good high-temperature oxidation resistance due to the formation of protective Al2O3 scales while multiple second-phase precipitation strengthening contributes to excellent creep resistance. This work will summarize the results on the development and properties of a centrifugally cast AFA alloy. This paper highlights the strength, oxidation resistance in air and water vapor containing environments, and creep properties in the as-cast condition over the temperature range of 750°C to 900°C in a centrifugally cast heat. Preliminary results for a laboratory cast AFA composition with good oxidation resistance at 1100°C are also presented.

  14. Effect of the Solution Annealing and Chemical Passivation Followed by Aging on the Corrosion of Shell Mold Cast CF8 Stainless Steel

    Science.gov (United States)

    Kim, Kuk-Jin; Ju, Heongkyu; Moon, Young-Dae; Hong, Jun Ho; Pak, Sung Joon

    2016-10-01

    The effects of solution annealing and passivation of shell mold cast CF8 stainless steels on Elbow pipe fittings with 2-month room temperature aging have been studied using a corrosion technique. The resistance of corrosion increased with 2-month room temperature aging combined with solid solution annealing and chemical passivation. The mode of corrosion was deeply related to the δ-ferrite content, permeability, and passivation. The corrosion probability decreased as both the δ-ferrite content and the permeability decreased. Therefore, it is considered that δ-ferrite content and passive film of Cr2O3 play an important role in corrosion resistance of CF8 Elbow pipe fittings due to the long-term aging with solid solution annealing and chemical passivation. This result shows that the corrosion resistance of CF8 fittings can be enhanced by the solid solution annealing and chemical passivation. Decreased ferrite phases and permeability improve IGC resistance in CF8 steel.

  15. Technical Letter Report Assessment of Ultrasonic Phased Array Testing for Cast Austenitic Stainless Steel Pressurizer Surge Line Piping Welds and Thick Section Primary System Cast Piping Welds JCN N6398, Task 2A

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, Aaron A.; Denslow, Kayte M.; Cinson, Anthony D.; Morra, Marino; Crawford, Susan L.; Prowant, Matthew S.; Cumblidge, Stephen E.; Anderson, Michael T.

    2008-07-21

    Research is being conducted for the NRC at PNNL to assess the effectiveness and reliability of advanced NDE methods for the inspection of LWR components. The scope of this research encompasses primary system pressure boundary materials including cast austenitic stainless steels (CASS), dissimilar metal welds (DMWs), piping with corrosion-resistant cladding, weld overlays, and far-side examinations of austenitic piping welds. A primary objective of this work is to evaluate various NDE methods to assess their ability to detect, localize, and size cracks in coarse-grained steel components. This interim technical letter report (TLR) provides a synopsis of recent investigations at PNNL aimed at evaluating the capabilities of phased-array (PA) ultrasonic testing (UT) methods as applied to the inspection of CASS welds in nuclear reactor piping. A description of progress, recent developments and interim results are provided.

  16. Characterization of the hot cracking resistance using the Essential Work of Fracture (EWF: application to duplex stainless steels Caracterização da resistência ao trincamento a quente com base nos trabalhos esssenciais de mecânica da fratura: aplicação aos aços inoxidáveis duplex

    Directory of Open Access Journals (Sweden)

    Guilhem Martin

    2013-06-01

    Full Text Available Duplex stainless steels (DSS involve two ductile phases, i.e. ferrite and austenite, with a proportion of each phase around 50%. The main advantage in comparison with other austenitic and ferritic stainless steels is the excellent combination of high strength and corrosion resistance together with good formability and weldability. Unfortunately, DSS present in general a poor hot workability. Standard hot ductility tests like hot tensile or hot torsion tests are always helpful to compare the fracture resistance of two very ductile materials. A new method based on the essential work of fracture (EWF concept has been used in order to determine the hot cracking resistance. The EWF concept was introduced to address ductile fracture based on the entire load-displacement response up to the complete fracture of a specimen and not from the initiation measurements such as in classical fracture mechanics concepts. The aim of the method consists in separating, based on dimensional considerations, the work performed within the plastic zone from the total work of fracture in order to provide an estimate of the work spent per unit area within the fracture process zone to break the material. This method proved to be very well adapted to high temperature cracking. Two different duplex stainless steels have been characterized by the essential work of fracture method. Examination of the fracture micrographs and profiles match the EWF results. This method turns out to be a discriminating tool for quantifying hot cracking and to generate a physically relevant fracture index to guide the optimization of microstructures towards successful forming operations.Aços inoxidáveis duplex (AID envolvem duas fases dúcteis, isto é, ferrita e austenita, com uma proporção de cada fase de cerca de 50%. A principal vantagem, em comparação com outros austeníticos e aços inoxidáveis ferríticos, é a excelente combinação de alta resistência mecânica e resistência

  17. Microstructural study of thermally aged duplex stainless steel deformation and fracture modes; Etude microstructurale des modes de deformation et de rupture d`un acier austenoferritique vieilli thermiquement

    Energy Technology Data Exchange (ETDEWEB)

    Verhaeghe, B. [Institut national polytechnique, 38 - Grenoble (France)

    1996-12-31

    The aim of this work is to study the micro mechanisms of deformation and rupture of an austeno ferritic stainless steel (Z 3 CND 22-10 M) with 33 % of ferrite. It is studied after ageing 1 000 h at 400 deg. C and 8 000 h at 350 deg. C and compared to the `as received` state. During ageing the ferritic phase undergoes microstructural evolutions which affects its properties. The two ageing treatments lead to roughly the same level of embrittlement. Microstructural characterisation shows that both phases percolate and exhibit orientation relationships close to Kurdjumov-Sachs ones. Mechanical properties of the steel were characterised for different ageing treatments at room temperature and at 320 deg. C. The interface is particularly strong and ensures the load transfer to ferrite even if this phase contains cleavage cracks. Moreover the interface does not oppose slip transmission which is instead controlled by localised glide in the ferritic phase. If activated slip systems of austenite are common with ferrite, slip transmission from austenite to ferrite indeed occurs through the=e interface. If they are not common, dislocations cross-slip back into the austenite. At 320 deg. C cross-slip occurs even far from the interface. Damage starts by nucleation in ferrite of cleavage cracks which propagate between austenite islands. Crack propagation is controlled by stretching of austenite ligaments. The material breaks by ductile tearing of austenite islands when the crack eventually percolates in the ferritic phase. The ductility of the material can be correctly describer using a simple model that takes into account the tearing-off the ductile-phase. (author). 153 refs.

  18. Status for cast stainless steel in older Swedish nuclear power plants, March 1996; Status foer gjutet rostfritt staal i aeldre svenska kaernkraftverk, mars 1996

    Energy Technology Data Exchange (ETDEWEB)

    Trolle, M.

    1996-04-01

    The purpose of this study is to compile what is known about larger cast components primarly in older BWR nuclear power plants with external circulation pumps. The work includes metallurgical data and a compilation on the material that the owner of Oskarshamn 1, OKG AB, has delivered to The Swedish Nuclear Power Inspectorate as a result of the investigation of these components. An overview of the investigations performed on the other Swedish plants of similar design during the annual outage 1995 is also described in this report. International experinece is also reported. The results from OKG AB show that there has been extensive cracking in both valves and pump casings and that they are probably resulting defects from the manufacturing process, but an environmental factor cannot be excluded. In order to get a complete picture of the situation in Swedish nuclear power plants a more extensive survey needs to be performed. Internationally the phenomenon of hot cracking in cast stainless steel is well known, but not as severe as in Oskarshamn 1. One question however that is discussed is the recommended amount of ferrite in these steels in order to avoid hot cracking without risking embrittlement of the ferrite phase. The Swedish utilities specify 3%, some European countries recommend 8%. Japan suggests ferrite contents up to 30%. 25 refs.

  19. Effect of Bonding Temperature on Phase Transformation of Diffusion-Bonded Joints of Duplex Stainless Steel and Ti-6Al-4V Using Nickel and Copper as Composite Intermediate Metals

    Science.gov (United States)

    Kundu, Sukumar; Thirunavukarasu, Gopinath; Chatterjee, Subrata; Mishra, Brajendra

    2015-12-01

    In the present study, the effect of bonding temperature on phase transformation of diffusion-bonded joints of duplex stainless steel (DSS) and Ti-6Al-4V (Ti64) using simultaneously both nickel (Ni) and copper (Cu) interlayers was investigated in the temperature range of 1148 K to 1223 K (875 °C to 950 °C) insteps of 25 K (25 °C) for 60 minutes under 4 MPa uniaxial pressure in vacuum. Interfaces were characterized by scanning electron microscopy and interdiffusion of the chemical species across the diffusion interfaces were witnessed by electron probe microanalysis. At 1148 K (875 °C), layer-wise Cu4Ti, Cu2Ti, Cu4Ti3, CuTi, and CuTi2 phases were observed at the Cu-Ti64 interface; however, DSS-Ni and Ni-Cu interfaces were free from any intermetallic. At 1173 K and 1198 K (900 °C and 925 °C), Cu interlayer could not restrict the diffusion of atoms from Ti64 to Ni, and vice versa; and Ni-Ti-based intermetallics were formed at the Ni-Cu interface and throughout the Cu zone as well; however, at 1223 K (950 °C), both Ni and Cu interlayers could not inhibit the diffusion of atoms from Ti64 to DSS, and vice versa. The maximum shear strength of ~377 MPa was obtained for the diffusion couple processed at 1148 K (875 °C) and strength of the bonded joints gradually decreased with the increasing bonding temperature due to the widening of brittle intermetallics at the diffusion zone. Fracture path indicated that failure took place through the Cu4Ti intermetallic at the Cu-Ti64 interface when bonding was processed at 1148 K (875 °C). When bonding was processed at 1173 K and 1198 K (900 °C and 925 °C), fracture took place through the Ni3Ti intermetallic at the Ni-(Ni + Cu + Ti64 diffusion reaction) interface; however, at 1223 K (950 °C), fracture morphology indicated the brittle nature and the fracture took place apparently through the σ phase at the DSS-(DSS + Ni + Cu + Ti64 diffusion reaction) interface.

  20. Orientation Characteristics of Hot Deformed Duplex Stainless Steel Under Different Strain Rate%不同应变速率热变形双相不锈钢的取向特征

    Institute of Scientific and Technical Information of China (English)

    王佳夫; 花福安; 李建平; 王国栋

    2011-01-01

    在MMS-200热模拟实验机上,对S32750超级双相不锈钢在1 000℃,应变速率为0.01~10 s-1的条件下进行了高温压缩实验,利用电子背散射衍射(EBSD)技术对其晶体取向和晶界特征进行了分析.研究结果表明:在低应变速率时,铁素体晶粒出现〈111〉∥压缩轴织构;在高应变速率时,〈001〉织构又明显增加.铁素体晶粒随着应变速率的增加变得细小,而小角度晶界数量增加;在应变速率为10 s-1时,形变后奥氏体晶粒得到了〈110〉织构.应变速率的增加使奥氏体晶粒变大,小角度晶界数量增加.奥氏体相在小应变速率条件下变形可以获得更多的Σ3孪晶界.%Under 1 000 ℃ and strain rate range of 0.01~10 s-1,the hot compression test of super duplex stainless steels S32750 was carried out with MMS-200 thermal-mechanical simulator.EBSD(electron backscattering diffraction) technique was applied to analyze grain orientation and grain boundary characters.The results showed that the 〈111〉 texture appears in ferrite under lower strain rate,and the additional 〈001〉 texture appears under higher strain rate.The ferrite grains become finer and the number of small angle grain boundaries increases with the increasing of strain rate.The 〈110〉 texture appears in the deformed austenite under the strain rate of 10 s-1.The austenite grain size and the number of small angle grain boundaries increase with the increasing of strain rate.A lot of Σ3 twin boundaries appear in the deformed austenite under lower strain rate.

  1. 2205不锈钢焊接接头疲劳裂纹扩展试验及分析%2205 Duplex Stainless Steel Welded Joint Fatigue Crack Growth Test and Analysis

    Institute of Scientific and Technical Information of China (English)

    张帅谋; 张雪峰; 陈彪

    2015-01-01

    2205 duplex stainless steel was welded using IGTB inverter type CO 2 gas shielded welding .Ac-cording to the standard GB6398-2000, the fatigue crack growth test of welded joint was carried out .Through testing the fatigue crack growth rate , and using Matlab software and Paris equation of linear regression analysis of data, the fatigue crack growth rate lg ( da /dN ) -lgΔK curve of different regions of the butt joint was gotten . The results show that the difference between butt joint's fatigue crack growth rates is remarkable at the same stress ratio.The heat affected zone's fatigue crack growth rate is the fastest while the welding zone is the lowest .The fa-tigue fracture was observed using SEM method , and the reason why the difference between butt joint's fatigue crack growth rates is remarkable was interpreted .%采用IGTB逆变式CO2气体保护焊对2205双相不锈钢进行焊接,形成焊接接头;并根据标准GB6398-2000对接头进行疲劳裂纹扩展试验。通过疲劳裂纹扩展速率测试,利用Matlab软件和Paris线性回归方程分析数据,得到对接接头上焊缝区、热影响区和母材区的疲劳裂纹扩展速率lg( da /dN )-lgΔK曲线。结果显示,给定的应力比工作条件下,疲劳裂纹在对接接头各区域的扩展速率差别较大,热影响区的扩展速率较快,母材次之,焊缝金属最慢。并利用SEM方法观察了疲劳断口,分析了产生疲劳裂纹扩展速率不同的原因。

  2. Influência da energia de soldagem na microestrutura e na microdureza de revestimentos de aço inoxidável duplex Influence of the heat input on the microstructure and microhardness of weld overlay of duplex stainless steel

    Directory of Open Access Journals (Sweden)

    Everton Barbosa Nunes

    2012-06-01

    Full Text Available Aços inoxidáveis duplex (AID são caracterizados por apresentar interessante boas propriedades mecânicas e resistência à corrosão, possuindo um vasto campo de aplicação na indústria química e petroquímica. Geralmente, os reparos dos equipamentos ou estruturas são realizados por soldagem, sendo importante a seleção de parâmetros. É de suma importância a obtenção do teor adequado de ferrita no metal de solda, sendo que a variação da energia de soldagem pode influenciar de forma direta no percentual de ferrita. Logo, o objetivo deste trabalho é avaliar a influência da variação da energia de soldagem na microestrutura e na microdureza do metal de solda do AID. Foram realizadas soldagens de revestimento com sobreposição de duas camadas sobre o aço estrutural ASTM A516 Gr.60, utilizando eletrodo revestido AWS E2209-17. Três níveis de energia (15, 20 e 24 kJ/cm foram empregados, variando-se a corrente e a velocidade de soldagem. Foi verificado que para os níveis de energia empregados não houve diferença significativa no percentual de ferrita, porém o primeiro cordão depositado apresentou maior teor de austenita em relação aos demais cordões. De forma geral, foi verificado que o primeiro cordão depositado obteve níveis maiores de microdureza. Todas as condições apresentaram microdurezas abaixo do valor crítico.Duplex stainless steels (DSS are characterized by the presentation of an interesting combination of good mechanical properties and corrosion resistance, having a wide application in chemical and petrochemical industry. Generally, the manufacture and repair of any industrial equipment involve welding operations, even though it is very important to evaluate the influence of welding parameters. It is very important to obtain appropriate ferrite content in the weld metal, so that the variation of heat input can influence on the ferrite content directly. Therefore, the aim this work is to evaluate the

  3. Hybrid Laser-Arc Welding of 10-mm-Thick Cast Martensitic Stainless Steel CA6NM: As-Welded Microstructure and Mechanical Properties

    Science.gov (United States)

    Mirakhorli, Fatemeh; Cao, Xinjin; Pham, Xuan-Tan; Wanjara, Priti; Fihey, Jean-Luc

    2016-07-01

    Cast CA6NM martensitic stainless steel plates, 10 mm in thickness, were welded using hybrid laser-arc welding. The effect of different welding speeds on the as-welded joint integrity was characterized in terms of the weld bead geometry, defects, microstructure, hardness, ultimate tensile strength, and impact energy. Significant defects such as porosity, root humping, underfill, and excessive penetration were observed at a low welding speed (0.5 m/min). However, the underfill depth and excessive penetration in the joints manufactured at welding speeds above 0.75 m/min met the specifications of ISO 12932. Characterization of the as-welded microstructure revealed untempered martensite and residual delta ferrite dispersed at prior-austenite grain boundaries in the fusion zone. In addition, four different heat-affected zones in the weldments were differentiated through hardness mapping and inference from the Fe-Cr-Ni ternary phase diagram. The tensile fracture occurred in the base metal for all the samples and fractographic analysis showed that the crack path is within the martensite matrix, along primary delta ferrite-martensite interfaces and within the primary delta ferrite. Additionally, Charpy impact testing demonstrated slightly higher fracture energy values and deeper dimples on the fracture surface of the welds manufactured at higher welding speeds due to grain refinement and/or lower porosity.

  4. Molecular characterization of natural biofilms from household taps with different materials: PVC, stainless steel, and cast iron in drinking water distribution system.

    Science.gov (United States)

    Lin, Wenfang; Yu, Zhisheng; Chen, Xi; Liu, Ruyin; Zhang, Hongxun

    2013-09-01

    Microorganism in drinking water distribution system may colonize in biofilms. Bacterial 16S rRNA gene diversities were analyzed in both water and biofilms grown on taps with three different materials (polyvinyl chloride (PVC), stainless steel, and cast iron) from a local drinking water distribution system. In total, five clone libraries (440 sequences) were obtained. The taxonomic composition of the microbial communities was found to be dominated by members of Proteobacteria (65.9-98.9 %), broadly distributed among the classes Alphaproteobacteria, Betaproteobacteria, and Gammaproteobacteria. Other bacterial groups included Firmicutes, Acidobacteria, Bacteroidetes, Cyanobacteria, and Deinococcus-Thermus. Moreover, a small proportion of unclassified bacteria (3.5-10.6 %) were also found. This investigation revealed that the bacterial communities in biofilms appeared much more diversified than expected and more care should be taken to the taps with high bacterial diversity. Also, regular monitor of outflow water would be useful as potentially pathogenic bacteria were detected. In addition, microbial richness and diversity in taps ranked in the order as: PVC steel iron. All the results interpreted that PVC would be a potentially suitable material for use as tap component in drinking water distribution system.

  5. Cast microstructure and tribological properties of particulate TiC-reinforced Ni-base or stainless steel matrix composites

    Energy Technology Data Exchange (ETDEWEB)

    Skolianos, S. (Department of Mechanical Engineering, Aristoteles University of Thessaloniki, Thessaloniki (Greece)); Kattamis, T.Z. (Department of Metallurgy, Institute of Materials Science, University of Connecticut, Storrs, CT 06269-3136 (United States)); Chen, M. (Department of Metallurgy, Institute of Materials Science, University of Connecticut, Storrs, CT 06269-3136 (United States)); Chambers, B.V. (Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States))

    1994-06-15

    Particulate TiC-reinforced nickel, 304 stainless steel and IN-100 nickel-base superalloy matrix composites were processed by precipitating the carbide during solidification of a melt of appropriate composition at various cooling rates. The microstructure and tribological properties of prepared specimens were evaluated. The microstructures of these composites can be controlled by controlling melt composition and homogeneity, as well as cooling rate. The specific wear rate decreased with increasing volume fraction of carbide and decreasing carbide particle size and spacing. For given volume fraction of carbide and carbide particle size composites with a softer matrix exhibited a higher wear rate and vice versa. The difference in wear rate among the three types of composites slightly decreased with increasing volume fraction carbide. Microhardness increased with increasing volume fraction of carbide. The friction coefficient between a diamond stylus and the polished specimen surface decreased with increasing volume fraction of carbide and decreasing particle size and spacing. For given volume fraction of carbide and carbide particle size the friction coefficient decreased with increasing matrix microhardness. For all composites a lower friction coefficient corresponded to a higher wear resistance. ((orig.))

  6. Microstructural Evolution and Mechanical Properties of Simulated Heat-Affected Zones in Cast Precipitation-Hardened Stainless Steels 17-4 and 13-8+Mo

    Science.gov (United States)

    Hamlin, Robert J.; DuPont, John N.

    2016-11-01

    Cast precipitation-hardened (PH) stainless steels 17-4 and 13-8+Mo are used in applications that require a combination of high strength and moderate corrosion resistance. Many such applications require fabrication and/or casting repair by fusion welding. The purpose of this work is to develop an understanding of microstructural evolution and resultant mechanical properties of these materials when subjected to weld thermal cycles. Samples of each material were subjected to heat-affected zone (HAZ) thermal cycles in the solution-treated and aged condition (S-A-W condition) and solution-treated condition with a postweld thermal cycle age (S-W-A condition). Dilatometry was used to establish the onset of various phase transformation temperatures. Light optical microscopy (LOM), scanning electron microscopy (SEM), and energy dispersive spectrometry (EDS) were used to characterize the microstructures, and comparisons were made to gas metal arc welds that were heat treated in the same conditions. Tensile testing was also performed. MatCalc thermodynamic and kinetic modeling software was used to predict the evolution of copper (Cu)-rich body center cubic precipitates in 17-4 and β-NiAl precipitates in 13-8+Mo. The yield strength was lower in the simulated HAZ samples of both materials prepared in the S-A-W condition when compared to their respective base metals. Samples prepared in the S-W-A condition had higher and more uniform yield strengths for both materials. Significant changes were observed in the matrix microstructure of various HAZ regions depending on the peak temperature, and these microstructural changes were interpreted with the aid of dilatometry results, LOM, SEM, and EDS. Despite these significant changes to the matrix microstructure, the changes in mechanical properties appear to be governed primarily by the precipitation behavior. The decrease in strength in the HAZ samples prepared in the S-A-W condition was attributed to the dissolution of precipitates

  7. Effects of phosphate addition on biofilm bacterial communities and water quality in annular reactors equipped with stainless steel and ductile cast iron pipes.

    Science.gov (United States)

    Jang, Hyun-Jung; Choi, Young-June; Ro, Hee-Myong; Ka, Jong-Ok

    2012-02-01

    The impact of orthophosphate addition on biofilm formation and water quality was studied in corrosion-resistant stainless steel (STS) pipe and corrosion-susceptible ductile cast iron (DCI) pipe using cultivation and culture-independent approaches. Sample coupons of DCI pipe and STS pipe were installed in annular reactors, which were operated for 9 months under hydraulic conditions similar to a domestic plumbing system. Addition of 5 mg/L of phosphate to the plumbing systems, under low residual chlorine conditions, promoted a more significant growth of biofilm and led to a greater rate reduction of disinfection by-products in DCI pipe than in STS pipe. While the level of THMs (trihalomethanes) increased under conditions of low biofilm concentration, the levels of HAAs (halo acetic acids) and CH (chloral hydrate) decreased in all cases in proportion to the amount of biofilm. It was also observed that chloroform, the main species of THM, was not readily decomposed biologically and decomposition was not proportional to the biofilm concentration; however, it was easily biodegraded after the addition of phosphate. Analysis of the 16S rDNA sequences of 102 biofilm isolates revealed that Proteobacteria (50%) was the most frequently detected phylum, followed by Firmicutes (10%) and Actinobacteria (2%), with 37% of the bacteria unclassified. Bradyrhizobium was the dominant genus on corroded DCI pipe, while Sphingomonas was predominant on non-corroded STS pipe. Methylobacterium and Afipia were detected only in the reactor without added phosphate. PCR-DGGE analysis showed that the diversity of species in biofilm tended to increase when phosphate was added regardless of the pipe material, indicating that phosphate addition upset the biological stability in the plumbing systems.

  8. 马氏体不锈钢水轮机叶片铸造缺陷修补工艺的研究%Study on Repairing Process of Casting Defects for Martensitic Stainless Steel Turbine Blade

    Institute of Scientific and Technical Information of China (English)

    李红霞; 柏长友; 杨保

    2015-01-01

    In view of the characteristics of ASTM A743 CA6NM martensitic stainless steel turbine blade casting, speciifc research and analysis have been carried out on welding repair technology for casting defects. E410NiMo-15 martensitic stainless steel was selected as welding material. welding process in strict accordance with the requirements was operated, and the heat treatment temperature was controlled reasonably. The results show that the welding repair process of the casting can meet the technical requirements, and the qualiifed rate of welding repair is more than 95%.%针对ASTM A743 CA6NM马氏体不锈钢水轮机叶片的铸件特点,对铸造缺陷的焊接修补工艺进行具体研究和分析。选用牌号为E410NiMo-15马氏体不锈钢作为焊接材料,严格按照焊接工艺要求进行操作并合理控制焊后热处理温度。结果表明,该铸件的焊接修补工艺达到技术要求,焊补合格率达到95%以上。

  9. Tensile deformation behavior of duplex stainless steel before and after thermal aging by EBSD%双相不锈钢热老化前后拉伸变形行为的电子背散射衍射表征

    Institute of Scientific and Technical Information of China (English)

    刘刚; 李时磊; 王艳丽; 王西涛

    2015-01-01

    The effects of deformation degree and thermal aging on the tensile properties, phase boundaries, local strain distribu-tion, coincidence site lattice ( CSL) boundaries and orientation distribution of duplex stainless steels were investigated by electron backscattered diffraction ( EBSD) . It is found that after thermal aging, the strength of duplex stainless steels enhances and the ductili-ty decreases. The number and density of small-angle boundaries in ferrite grains increase slightly under large deformation conditions. The plastic deformation ability and local strain in ferrite phases of the thermal aged materials decline. Large deformation destroys the original distribution of austenite and ferrite grains, as well as ∑3 twinning boundaries.%通过电子背散射衍射实验分析方法,研究变形量和热老化因素对双相不锈钢的拉伸性能、相边界、局部应变分布、重位点阵特殊晶界和取向分布的影响。研究结果表明:热老化后,双相不锈钢的强度提高,韧性降低;在大变形条件下铁素体晶粒内小角度晶界的数量和密度略有增加;热老化材料的铁素体的塑性变形和局部应变能力下降,大变形破坏初始奥氏体和铁素体以及∑3孪晶边界的分布。

  10. Characteristics of vacuum sintered stainless steels

    Directory of Open Access Journals (Sweden)

    Z. Brytan

    2009-04-01

    Full Text Available Purpose: In the present study duplex stainless steels were sintered in vacuum. using rapid cooling form the mixture of prealloyed and alloying element powders The purpose of this paper was to describe the obtained microstructures after sintering as well as the main mechanical properties of sintered stainless steels.Design/methodology/approach: In presented work duplex stainless steels were obtained through powder metallurgy starting from austenitic 316L or ferritic 410L prealloyed stainless steels powders by controlled addition of alloying elements powder. Prepared mixes were sintered in a vacuum furnace in 1250°C for 1h. After sintering rapid cooling (6°C/s using nitrogen under pressure was applied. Sintered compositions were subjected to structural examinations by scanning and optical microscopy and EDS analysis as well as X-ray analysis. Mechanical properties were studied through tensile tests and Charpy impact test.Findings: It was demonstrated that austenitic-ferritic microstructures with regular arrangement of both phases and absence of precipitates can be obtained with properly designed powder mix composition as well as sintering cycle with rapid cooling rate. Obtained sintered duplex stainless steels shows good mechanical properties which depends on phases ratio in the microstructure and elements partitioning (Cr/Ni between phases.Research limitations/implications: Basing on alloys characteristics applied cooling rate and powder mix composition seems to be a good compromise to obtain balanced sintered duplex stainless steel microstructures.Practical implications: Mechanical properties of obtained sintered duplex stainless steels structures are rather promising, especially with the aim of extending their field of possible applications.Originality/value: The utilization of vacuum sintering process with rapid cooling after sintering combined with use of elemental powders added to a stainless steel base powder shows its advantages in terms

  11. 铸造奥氏体不锈钢的疲劳裂纹扩展%Fatigue crack growth of cast austenitic stainless steels

    Institute of Scientific and Technical Information of China (English)

    吕绪明; 李时磊; 王西涛; 王艳丽

    2015-01-01

    用紧凑拉伸试样研究了载荷比、单峰过载和两步高-低幅加载对Z3CN20-09M铸造奥氏体不锈钢疲劳裂纹扩展速率的影响。当应力强度因子范围相同时,疲劳裂纹扩展速率随载荷比的增大而增大。单峰过载使裂纹扩展速率先有短暂的增加后长距离的减速扩展,出现裂纹扩展迟滞现象。两步高-低幅加载时,若两步的最大载荷不同,第二步裂纹扩展也会出现迟滞现象。用两参数模型和Wheeler模型能够预测恒幅载荷和变幅载荷下的疲劳裂纹扩展行为。%The influences of stress ratio, single overload and high-low loading sequence on the fatigue crack growth of Z3CN20-09M cast austenitic stainless steels were studied with compact tension specimens. When the stress intensity factor range is identical, the fatigue crack growth rate increases with the increase of stress ratio. During single overload, the fatigue crack growth rate shows a short period of acceleration followed by a significant decrease, leading to subsequent crack growth retardation. Similarly, high-low loading sequence with the maximum load in the second step lower than that in the first loading step results in significant crack growth retardation in the second loading step. A two-parameter model and Wheeler’ s model are found to predict well the crack growth behav-ior under constant-amplitude loading and variable-amplitude loading, respectively.

  12. Tensile behavior of CF8-CPF8-304H and CF8M-CPF8M-316H stainless steel static and centrifugal castings

    Energy Technology Data Exchange (ETDEWEB)

    McEnerney, J.W.; Sikka, V.K.; Booker, M.K.

    1981-10-01

    We have analyzed the tensile behavior of 11 heats of grades CF8-CPF8-304H and 13 heats of grades CF8M-CPF8M-316H static and centrifugal castings from room temperature to 650/sup 0/C. Except for anomalous conditions, the centrifugal castings exhibited uniform composition. All CPF8-304H centrifugal castings contained only radial columnar grains, but some CPF8M-316H castings had columnar, banded, or equiaxed structures. Ultimate tensile strength and total elongation were the properties in which castings showed the most inferiority to wrought material. With increasing ferrite content, 0.2% yield strength and ultimate tensile strength increased while uniform elongation, total elongation, and reduction of area decreased. Although centrifugal castings did not exhibit significant end-to-end variation in tensile behavior, the 0.2% yield strength displayed anisotropy, with axial and circumferential values being greater than radial.

  13. Caracterização e avaliação da resistência à corrosão na soldagem de tubulação de aço inoxidável duplex UNS S31803 pelo processo a arco submerso Characterization and evaluation of corrosion resistance of welded joint of duplex stainless steel pipe UNS S31803 by submerged arc process

    Directory of Open Access Journals (Sweden)

    Juan Manuel Pardal

    2011-12-01

    Full Text Available O presente trabalho apresenta os resultados da caracterização e avaliação da resistência à corrosão de uma junta soldada correspondente a uma tubulação de aço inoxidável duplex (AID UNS S31803 de 35 mm de espessura de parede soldada pelos processos de soldagem TIG (GTAW na raiz e arco submerso (SAW no enchimento e acabamento. Foram empregados como consumíveis de soldagem metais de adição de liga 25Cr-9Ni-4Mo (% em peso. Os resultados da caracterização das propriedades mecânicas, composição química e resistência à corrosão em diversas regiões da junta soldada foram comparados com os obtidos para o metal de base da tubulação, assim como com os valores mínimos exigidos pelas normas de projeto. Os resultados obtidos demonstram claramente a possibilidade da implementação do processo SAW na pré fabricação de tubulações de paredes espessas de AID, tendo em vista os resultados das propriedades analisadas e a grande demanda na construção e montagem de tubulações desta família de aço inoxidáveis na indústria offshore.This work presents the mechanical properties, microstructural and corrosion resistance evaluation of a welded joint of duplex stainless steel (DSS pipe with 35 mm wall thickness. The joint was welded by gas tungsten arc welding (GTAW process in the root passes and submerged arc welding (SAW in the filling and cap passes using filler metals with composition 25Cr-9Ni-4Mo (%wt.. The results of mechanical properties, chemical composition and corrosion resistance characterization in different regions of the welded joint were compared to the base metal and to the specifications required by the standards applied in the project. The main focus of this work was to show the successful utilization of SAW process in the welding of thick wall pipes of DSS. The application of high productivity process such as SAW has a crescent demand in offshore industry.

  14. Tensile properties of duplex UNS S32205 and lean duplex UNS S32304 steels and the influence of short duration 475 ºC aging

    Directory of Open Access Journals (Sweden)

    Sérgio Souto Maior Tavares

    2012-12-01

    Full Text Available Duplex stainless steels are high strength and corrosion resistant steels extensively used in the petrochemical and chemical industries. The aging at 475 ºC for long periods of time provokes embrittlement and deterioration of corrosion resistance. However, short duration aging at 475 ºC may be used as heat treatment to improve mechanical resistance with small decrease in the other properties. In this work the flow stress curves of lean duplex UNS S32304 and duplex UNS S32205 steels were modeled with Hollomon's equation and work hardening exponents (n were determined. The analyses were conducted in specimens annealed and heat treated at 475 ºC for short periods of time. The aging at 475 ºC for 4 hours, 8 hours and 12 hours promoted significant hardening with small decrease of ductility. The work hardening exponents of both steels were compared, being higher in the duplex steel than in the lean duplex grade.

  15. A galvanic corrosion study of brass/stainless steel and brass/cast iron couples; Estudio de corrosion galvanica en pares laton/acero inoxidable y laton/fundicion de hierro

    Energy Technology Data Exchange (ETDEWEB)

    Ohanian, M.; Diaz, V.; Corengia, M.; Zinola, C. F.

    2011-07-01

    Corrosion attack in heat exchanger systems is a topic of main interest for the maintenance in each industrial plant. These are multi galvanic systems with particular geometric and fluidodynamic complexity. Corrosive damages include zinc selective dealeation in copper alloys. In order to explain zinc dealeation attack, this paper deals with laboratory scale testing, characterization and interactions between two copper and zinc alloys (Yellow brass UNS C268 and Admiralty brass UNS C443) compared to AISI 316 stainless steel and cast iron. The tests were performed at 20 degree centigrade in 1.5 % NaCl and 1.5 % Na{sub 2}SO{sub 4} solutions, pH 8 and each material was characterized by potentiodynamic sweeps. The couples are analyzed by studying transient galvanic currents. We conclude about the cause of the analyzed pathology, brass protection potential ranges and its coupling compatibility with other metals. (Author) 33 refs.

  16. Post-weld Tempered Microstructure and Mechanical Properties of Hybrid Laser-Arc Welded Cast Martensitic Stainless Steel CA6NM

    Science.gov (United States)

    Mirakhorli, Fatemeh; Cao, Xinjin; Pham, Xuan-Tan; Wanjara, Priti; Fihey, Jean-Luc

    2016-12-01

    Manufacturing of hydroelectric turbine components involves the assembly of thick-walled stainless steels using conventional multi-pass arc welding processes. By contrast, hybrid laser-arc welding may be an attractive process for assembly of such materials to realize deeper penetration depths, higher production rates, narrower fusion, and heat-affected zones, and lower distortion. In the present work, single-pass hybrid laser-arc welding of 10-mm thick CA6NM, a low carbon martensitic stainless steel, was carried out in the butt joint configuration using a continuous wave fiber laser at its maximum power of 5.2 kW over welding speeds ranging from 0.75 to 1.2 m/minute. The microstructures across the weldment were characterized after post-weld tempering at 873 K (600 °C) for 1 hour. From microscopic examinations, the fusion zone was observed to mainly consist of tempered lath martensite and some residual delta-ferrite. The mechanical properties were evaluated in the post-weld tempered condition and correlated to the microstructures and defects. The ultimate tensile strength and Charpy impact energy values of the fully penetrated welds in the tempered condition were acceptable according to ASTM, ASME, and industrial specifications, which bodes well for the introduction of hybrid laser-arc welding technology for the manufacturing of next generation hydroelectric turbine components.

  17. Q345R与SAF2507超级双相钢焊接及质量控制%Welding of Q345R and SAF2507 Duplex Stainless Steel and Quality Control

    Institute of Scientific and Technical Information of China (English)

    杨平平

    2015-01-01

    对国内应用较少、耐蚀性强的SAF2507超级双相钢的特点进行分析,对比Q345R与SAF2507焊接性,参考异种钢焊接,利用舍弗勒图选取合适焊材。针对Q345R与SAF2507超级双相钢焊接进行试验分析并归纳其焊接工艺,提出了防止缺陷产生的焊接方法和保证焊接质量的措施。%In this article, the features of deluxe stainless steel SAF2507, which is seldom used in China and is well anticorrosive, were analyzed. With the comparison of the weldabilities of Q345R and SAF2507 and the reference for welding of heterogeneous steels, the appropriate welding consumers were selected by using Schaeffler diagram. Welding tests for Q345R and SAF2507 were carried out. After the analysis and summarization of their welding procedures, the welding method which can protect the occurrence of welding defects and measures for controlling quality were proposed.

  18. 固溶处理对马氏体/铁素体双相不锈钢组织和性能影响%Effects of solid solution treatment on microstructure and mechanical properties of martensite/ferrite duplex stainless steel

    Institute of Scientific and Technical Information of China (English)

    孙国强; 易健宏; 梁剑雄; 刘振宝; 杨志勇; 甘国友

    2014-01-01

    利用金相显微镜、扫描电镜等试验手段,研究了固溶温度及固溶时间对马氏体/铁素体双相不锈钢微观组织和力学性能的影响。试验结果显示,随着固溶温度的升高,第二相逐渐溶解于基体中,马氏体含量逐渐增加,在力学性能方面表现为强度逐渐增大,塑韧性降低。通过相分析可知,基体中第二相为M23 C6,且固溶温度越高,第二相( M23 C6)在基体中的残留越少,当固溶温度高于1100℃时,第二相完全溶解到基体中。%Effects of solution temperature and time on microstructure and mechanical properties of martensite /ferrite duplex stainless steel were studied by means of optical microscope , scanning electron microscope and tensile testing machine .The results show that with the increase of solution temperature , the second phase gradually dissolves in the matrix , martensite content increases , the strength increases gradually and the toughness decreases .Phase analysis result shows that the second phase in the matrix is M 23 C6 , and the higher the solution temperature is, the less the second phase (M23C6) is, when the solution temperature is higher than 1100 ℃, the second phase completely dissolves into the matrix .

  19. Effect of thermal aging on SCC and mechanical properties of stainless steel weld metals

    Energy Technology Data Exchange (ETDEWEB)

    Hixon, J.R. [U.S. Nuclear Regulatory Commission (United States); Kim, J.H.; Ballinger, R.G. [Massachusetts Inst. of Technology (United States)

    2007-07-01

    The thermal aging and consequent embrittlement of materials are ongoing issues in cast stainless steels and duplex stainless steel. Spinodal decomposition is largely responsible for the well known '475{sup o}C embrittlement that results in drastic reductions in ductility and toughness in these materials, and this process is operative in welds in either cast or wrought stainless steels where delta ferrite is present. While the embrittlement can occur after several hundred hours of aging at 475{sup o}C, the process is also operative at lower temperatures, including the 300{sup o}C operating temperature of a boiling water reactor (BWR), where ductility reductions have been observed after several tens of thousands of hours. An experimental program is under way in to understand how the spinodal decomposition may affect material properties changes in BWR pipe weld metals. Testing includes nano and micro-structural analysis as well as fatigue and SCC crack growth. In this study we report on the initial results of this program, including tensile, Charpy impact, fracture toughness and SCC crack growth rates of SS weld metals under simulated BWR conditions. The measurement of tensile, microhardness and Charpy-impact energy show an increase in strength, a decrease in ductility, and a decrease in impact energy after aging for 1000 hours at 430 and 400 {sup o}C. Crack growth rates for material in the as welded and aged for 5000 hours at 400{sup o}C have been measured and are generally within the scatter band for wrought material although the aged material data fall at the high end. Unusual insitu unstable fracture behavior has been experienced at toughness values significantly below (<50%) the room temperature fracture toughness. This behavior, termed 'environmental fracture' requires further investigation. (author)

  20. Optimization of MRR in EDM Process with Different Job Material i.e Stainless Steel and Cast Iron by Taguchi Method.

    Directory of Open Access Journals (Sweden)

    Dr. D.C. Roy

    2015-05-01

    Full Text Available Electro discharge machining (EDM has been recognized as an efficient method of producing dies and machining of hard material such as ceramics and high strength metal matrix composites for the modern metal industry (1. In this process the metal are remove through melting or vaporization of job metal by high frequency spark discharge. Although in this process the metal removal rate is lower than the other nonconventional machining process. But the dimensional accuracy is higher than the other process and more complex shape can be produce generally composite material are fascinated as thy exhibit exceptional mechanical and physical properties such as high strength, high hardness, and high density at elevated temperature. For this extra ordinary behavior it has wide range of application on the metal industries like aerospace, dies or mould making industries, automobiles industries etc. The metal removal rate (M.R.R. and surface smoothness not only depend on the selection of tool material also depend on the number of input parameter (such-input current, voltage, spindle speed, duty factor, dielectric medium, job metal property (conductivity ,hardness, strength, density etc.,machine condition and machining condition(machine performances, temperature, depth of cut or area of cut etc.. It is most difficult to select machining condition for optimal performances due to large number of parameters and inherent complexity of material removal mechanism taking place in EDM process. In the present work, the experiments were conducted using Taguchi L9 orthogonal approach, to ascertain the effect of EDM process parameters on material removal rate (MRR of stain less steel and cast iron by using tool material such copper and graphite.

  1. Application of an energy efficient casting ladle heating system used in the manufacture of stainless steel; Einsatz einer energieeffizienten Pfannenaufheizstation bei der Herstellung von Edelstahl

    Energy Technology Data Exchange (ETDEWEB)

    Poeschl, Markus [Edelstahlwerke Schmees GmbH, Langenfeld (Germany); Lodde, Marcus [Effizienz-Agentur NRW, Duisburg (Germany). prisma Consult GmbH

    2011-06-15

    In the melting area, the company has been using four conventional burners to heat the ladles. The existing flame burners heat the upside down ladles from below and consume massive amount of energy. Heat radiation and all of the waste gas are released into the facility. The material around the ladles is therefore heavily affected. The company has now installed a new energy efficient casting ladle heating system with a new kind of porous burner which heats the transport ladles without exposing them to an open flame. The combustion heat is channeled to specially adapted steel pipes via infrared radiation and convection flow. By doing this, the heat is directly transferred to the ladles and can be controlled in a more balanced manner. The company now saves around 61,400 m{sup 3}/a of natural gas, approx. 60 % of the energy required for the ladle heating and, as a result, 113.8 tonnes of CO{sub 2}-equivalent. The life span of the ladles can be increased by a factor of 2 due to the reduced exposure of the fire resistant materials. The resulting waste gas is collected and the waste heat will be reused in the facility in the future (facility heating 2011). Due to reduction in cleaning and carrying time of the ladles, Fr. Schmees expects an increase in productivity of the complete process. The heat radiation from the ladles has been reduced by 75 % which has led to a reduction of breakdowns. In addition, the noise level has sunk from 78.7 dB to 67.4 db. (orig.)

  2. Low temperature gaseous nitriding and carburising of stainless steel

    DEFF Research Database (Denmark)

    Christiansen, Thomas; Somers, Marcel A.J.

    2005-01-01

    The response of various austenitic and duplex stainless steel grades to low temperature gaseous nitriding and carburising was investigated. Gaseous nitriding was performed in ammonia/hydrogen mixtures at temperatures ,723 K; gaseous carburising was carried out in carbon monoxide/hydrogen mixtures...

  3. Advances in the research of nitrogen containing stainless steels

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    The current status of nitrogen containing stainless steels at home and aboard has been introduced. The function and existing forms of nitrogen in the stainless steels, influence of nitrogen on mechanical properties and anti-corrosion properties as well as the application of nitrogen containing cast stainless steels were discussed in this paper. It is clear that nitrogen will be a potential and important alloying element in stainless steels. And Argon Oxygen Decarbonization (AOD) refining can provide an advanced manufacture process for nitrogen containing stainless steels with ultra-low- carbon and high cleanliness.

  4. Thermodynamic calculation of phase equilibria in stainless steels

    Directory of Open Access Journals (Sweden)

    Klančnik G.

    2012-01-01

    Full Text Available In this paper two examples of thermodynamic investigation of stainless steels using both, experimental and modeling approach are described. The ferritic-austenitic duplex stainless steel and austenitic stainless steel were investigated using thermal analysis. The complex melting behavior was evident for both alloy systems. Experimentally obtained data were compared with the results of the thermodynamic calculations using the CALPHAD method. The equilibrium thermal events were also described by the calculated heat capacity. In spite of the complexity of both selected real alloy systems a relative good agreement was obtained between the thermodynamic calculations and experimental results.

  5. [Carotid duplex ultrasonography for neurosurgeons].

    Science.gov (United States)

    Sadahiro, Hirokazu; Ishihara, Hideyuki; Oka, Fumiaki; Suzuki, Michiyasu

    2011-12-01

    Carotid duplex ultrasonography (CDU) is one of the most well-known imaging methods for arteriosclerosis and ischemic stroke. For neurosurgeons, it is very important for the details of carotid plaque to be thoroughly investigated by CDU. Symptomatic carotid plaque is very fragile and easily changes morphologically, and so requires frequent CDU examination. Furthermore, after carotid endarterectomy (CEA) and carotid artery stenting (CAS), restenosis is evaluated with CDU. CDU facilitates not only morphological imaging in the B mode, but also allows a flow study with color Doppler and duplex imaging. So, CDU can help assess the presence of proximal and intracranial artery lesions in spite of only having a cervical view, and the patency of the extracranial artery to intracranial artery bypass is revealed with CDU, which shows a rich velocity and low pulsatility index (PI) in duplex imaging. For the examiner, it is necessary to ponder on what duplex imaging means in examinations, and to summarize all imaging finding.

  6. Sigma phase formation kinetics in stainless steel laminate composites

    Energy Technology Data Exchange (ETDEWEB)

    Wenmen, D.W.; Olson, D.L.; Matlock, D.K. [Colorado School of Mines, Golden, CO (United States)] [and others

    1994-12-31

    Stainless steel laminate composites were made to simulate weld microstructures. The use of laminates with variations in chemical composition allows for one dimensional analysis of phase transformation associated with the more complex three-dimensional solidification experience of weld metal. Alternate layers of austenitic (304L and 316L) and ferritic (Ebrite) stainless steels allowed for the study of sigma phase formation at the austenite-ferrite interface in duplex stainless steel. Two austenitic stainless steels, 304L (18.5Cr-9.2Ni-0.3Mo) and 316L (16.2Cr-10.1Ni-2.6Mo), and one ferritic stainless steel, Ebrite (26.3Cr-0Ni-1.0Mo) were received in the form of sheet which was laboratory cold rolled to a final thickness of 0.25 mm (0.030 in.). Laminate composites were prepared by laboratory hot rolling a vacuum encapsulated compact of alternating layers of the ferrite steel with either 304L or 316L stainless steel sheets. Laminate composite specimens, which simulate duplex austenite-ferrite weld metal structure, were used to establish the kinetics of nucleation and growth of sigma phase. The factors affecting sigma phase formation were identified. The effects of time, temperature, and transport of chromium and nickel were evaluated and used to establish a model for sigma phase formation in the austenite-ferrite interfacial region. Information useful for designing stainless steel welding consumables to be used for high temperature service was determined.

  7. Local Approach to Fracture of an Aged Duplex Stainless Steel

    Directory of Open Access Journals (Sweden)

    Alfredo Hazarabedian

    2002-06-01

    Full Text Available The local approach to fracture (LAF is a methodology aimed to calculate macroscopic fracture properties of a body, from the knowledge of the local stress - strain field at the fracture site, and the modeling of the acting fracture mechanisms. In the present work, this method was applied to a CF8M steel, aged 30000h at 325 °C, in order to elucidate if LAF could be able to describe the measured fracture toughness data. We have simulated the elastoplastic behavior using the Gurson model and the general methodology of Joly. The required parameters were obtained from the stress strain curve and from the damage progression study by quantitative metallography. We extended the validity of that methodology for a material aged in a more realistic condition, i.e. at a relatively lower temperature and for a longer time. The model was found satisfactory because it was able to describe the experimental distribution of the fracture probability vs. fracture strain of notched axisymmetric specimens, without any parameter fitting. The model also predicted the lower bound of the experimental distribution of the crack resistance at 0.2 mm of crack extension (J02.

  8. Ferritic-austenitic cast steel - selected problems

    Directory of Open Access Journals (Sweden)

    Z. Stradomski

    2011-07-01

    Full Text Available The author has been involved in the problems occurring in the manufacture of ferritic-austenitic cast steel castings for many years. The author’s remarks and investigation results reported in this article will enable potential manufacturers to determine their own technical capabilities and structural determinants related to the chemical composition of material, which are crucial to the good quality of a casting. Particular emphasis should be laid on the role of enhanced carbon content, the presence of copper, the precipitates of the ζ phase, and the nature of solidification structure in the tendency of duplex-type cast steel to cracking. It seems that in view of the pro-ecological activities undertaken, including flue gas desulphurization in coal-fired power plants, efforts should be made in steel foundries to introduce selected grades of ferritic-austenitic cast steel to production.

  9. Achieving single channel, full duplex wireless communication

    KAUST Repository

    Choi, Jung Il

    2010-01-01

    This paper discusses the design of a single channel full-duplex wireless transceiver. The design uses a combination of RF and baseband techniques to achieve full-duplexing with minimal effect on link reliability. Experiments on real nodes show the full-duplex prototype achieves median performance that is within 8% of an ideal full-duplexing system. This paper presents Antenna Cancellation, a novel technique for self-interference cancellation. In conjunction with existing RF interference cancellation and digital baseband interference cancellation, antenna cancellation achieves the amount of self-interference cancellation required for full-duplex operation. The paper also discusses potential MAC and network gains with full-duplexing. It suggests ways in which a full-duplex system can solve some important problems with existing wireless systems including hidden terminals, loss of throughput due to congestion, and large end-to-end delays. Copyright 2010 ACM.

  10. Numerical simulation of hydrogen-assisted crack initiation in austenitic-ferritic duplex steels; Numerische Simulation der wasserstoffunterstuetzten Rissbildung in austentisch-ferritischen Duplexstaehlen

    Energy Technology Data Exchange (ETDEWEB)

    Mente, Tobias

    2015-07-01

    Duplex stainless steels have been used for a long time in the offshore industry, since they have higher strength than conventional austenitic stainless steels and they exhibit a better ductility as well as an improved corrosion resistance in harsh environments compared to ferritic stainless steels. However, despite these good properties the literature shows some failure cases of duplex stainless steels in which hydrogen plays a crucial role for the cause of the damage. Numerical simulations can give a significant contribution in clarifying the damage mechanisms. Because they help to interpret experimental results as well as help to transfer results from laboratory tests to component tests and vice versa. So far, most numerical simulations of hydrogen-assisted material damage in duplex stainless steels were performed at the macroscopic scale. However, duplex stainless steels consist of approximately equal portions of austenite and δ-ferrite. Both phases have different mechanical properties as well as hydrogen transport properties. Thus, the sensitivity for hydrogen-assisted damage is different in both phases, too. Therefore, the objective of this research was to develop a numerical model of a duplex stainless steel microstructure enabling simulation of hydrogen transport, mechanical stresses and strains as well as crack initiation and propagation in both phases. Additionally, modern X-ray diffraction experiments were used in order to evaluate the influence of hydrogen on the phase specific mechanical properties. For the numerical simulation of the hydrogen transport it was shown, that hydrogen diffusion strongly depends on the alignment of austenite and δ-ferrite in the duplex stainless steel microstructure. Also, it was proven that the hydrogen transport is mainly realized by the ferritic phase and hydrogen is trapped in the austenitic phase. The numerical analysis of phase specific mechanical stresses and strains revealed that if the duplex stainless steel is

  11. Boronization and Carburization of Superplastic Stainless Steel and Titanium-Based Alloys

    Directory of Open Access Journals (Sweden)

    Masafumi Matsushita

    2011-07-01

    Full Text Available Bronization and carburization of fine-grain superplastic stainless steel is reviewed, and new experimental results for fine grain Ti88.5Al4.5V3Fe2Mo2 are reported. In superplastic duplex stainless steel, the diffusion of carbon and boron is faster than in non-superplastic duplex stainless steel. Further, diffusion is activated by uniaxial compressive stress. Moreover, non-superplastic duplex stainless steel shows typical grain boundary diffusion; however, inner grain diffusion is confirmed in superplastic stainless steel. The presence of Fe and Cr carbides or borides is confirmed by X-ray diffraction, which indicates that the diffused carbon and boron react with the Fe and Cr in superplastic stainless steel. The Vickers hardness of the carburized and boronized layers is similar to that achieved with other surface treatments such as electro-deposition. Diffusion of boron into the superplastic Ti88.5Al4.5V3Fe2Mo2 alloy was investigated. The hardness of the surface exposed to boron powder can be increased by annealing above the superplastic temperature. However, the Vickers hardness is lower than that of Ti boride.

  12. Corrosion behavior of duplex coatings

    Directory of Open Access Journals (Sweden)

    K. Raghu Ram Mohan Reddy

    2016-07-01

    Full Text Available The titanium alloys are used in defense, aerospace, automobile, chemical plants and biomedical applications due to their very high strength and lightweight properties. However, corrosion is a life-limiting factor when Ti alloys are exposed to different chemical environments at high temperatures. In the present paper, duplex NiCrAlY/WC–Co coating is coated onto Ti6Al4V substrate to investigate the corrosion behavior of both coated samples and the substrate. The duplex coating was performed with NiCrAlY as the intermediate coat of 200 μm thickness deposited by HVOF process and WC–Co ceramic top coat with varying thicknesses of 250 μm, 350 μm and 450 μm deposited by DS process. Potentiodynamic polarization tests were employed to investigate the corrosion performance of duplex coated samples and substrate in Ringer’s solution at 37 °C and pH value was set to 5.7. Finally the results reveal that 350 μm thick coated samples showed highest corrosion resistance compared to 250 μm thick samples as well as bare substrate. However, the 450 μm thick coated sample showed poor corrosion resistance compared to the substrate. The scale formed on the samples upon corrosion was characterized by using SEM analysis to understand the degree of corrosion behavior.

  13. 厚壁铸造奥氏体不锈钢管道焊缝超声相控阵检测技术概述%Review of Phased Array Ultrasonic Testing for Thick Wall Cast Austenitic Stainless Steel Pipeline Welds

    Institute of Scientific and Technical Information of China (English)

    林莉; 杨平华; 张东辉; 赵天伟; 杨会敏; 李喜孟

    2012-01-01

    The welding quality of cast austenitic stainless steel (CASS) pipeline welds is critical to nuclear reactors. The mandatory requirements of NDT have been raised in inspection code of nuclear power plant, which is about the welding quality and service condition of CASS welds. However, the complex structure of welds makes the ultrasonic testing of CASS welds challenging. Phased array ultrasonic testing (PAUT) technique is promising to solve this problem. The difficulties of PAUT for thick wall CASS pipeline welds are analyzed, the corresponding key issues and solving strategies are summarized. Furthermore, the research progress and latest research results at home and abroad are described, which provides reference for the PAUT of thick wall CASS pipeline welds.%铸造奥氏体不锈钢(Cast austenitic stainless steel,CASS)管道的焊接质量直接关系到核反应堆的安全,在核动力装置的检验规范中,对此类焊缝加工质量及服役期间状况提出无损检测的强制性要求,但CASS焊缝组织状态的复杂性给超声检测工作带来困难,研究采用相控阵超声检测(Phased array ultrasonic testing,PAUT)技术解决这一难题已成为国内外无损检测工作者关注的热点.概述厚壁CASS管道焊缝PAUT技术的难点,归纳相应的关键技术及解决策略,并简述近期国内外相关研究工作的进展和成果,以期为厚壁CASS管道焊缝的PAUT技术提供借鉴和参考.

  14. Pitting corrosion resistant austenite stainless steel

    Science.gov (United States)

    van Rooyen, D.; Bandy, R.

    A pitting corrosion resistant austenite stainless steel comprises 17 to 28 wt. % chromium, 15 to 26 wt. % nickel, 5 to 8 wt. % molybdenum, and 0.3 to 0.5 wt. % nitrogen, the balance being iron, unavoidable impurities, minor additions made in the normal course of melting and casting alloys of this type, and may optionally include up to 10 wt. % of manganese, up to 5 wt. % of silicon, and up to 0.08 wt. % of carbon.

  15. 不锈钢管镶嵌件在压铸中的应用研究%Research and Application of Inserts of Stainless Steel Tube in Die Casting

    Institute of Scientific and Technical Information of China (English)

    李振生

    2013-01-01

    阐述了汽车发动机电控冷却器压铸件不锈钢油管内镶嵌件的结构、定位及工艺过程控制.其要点是,在油管接头上预先按图纸尺寸要求钻攻底孔、攻牙及铣面,同时做出与之配合的镀锌螺栓接头,装配后(将螺栓接头旋入油管接头内,成为油管总成,再放到压铸模上)通过与模具上的限位镶块精确定位,从而实现铸件压铸后油管接头位置度及接头端面的距离尺寸不变的目的.压铸结束后拆除可循环利用的螺栓接头,镀锌接头涂层防止了高温下因油污引起的生锈,满足了产品的清洁度要求.%According to the product assembly requirements, first pre-drilling thread bottom hole, tapping and milling surface in the tube union required by the drawing, and make the galvanized thread plug at the same time, the thread plug is screwed into the tube union as a tube assembly, and then put it into the casting mold . The tube dimensions of the casting would be achieved directly by the die casting process through die-casting mould precision limit insert . When the die casting is complete, remove the recyclable thread plug . The galvanized thread plug can prevent effectively metal from rust caused by the high temperature and oil of the fitting surface between the tube union and the thread plug to ensure the cleanliness requirement, and protect the tube surface against damage . The internal thread of the tube u-nion ensure the tooth shape in the thread plug force in the die casting process, so as to achieve the purpose of directly by the die-casting process. Reduce the cost under the precondition to satisfy the production requirements.

  16. Caste System

    OpenAIRE

    Hoff, Karla

    2016-01-01

    In standard economics, individuals are rational actors and economic forces undermine institutions that impose large inefficiencies. The persistence of the caste system is evidence of the need for psychologically more realistic models of decision-making in economics. The caste system divides South Asian society into hereditary groups whose lowest ranks are represented as innately polluted. ...

  17. Effect of Continuous Casting Process Parameters on Equiaxial Crystal Ratio of 430 Ferritic Stainless Steel%连铸工艺参数对430铁素体不锈钢等轴晶率的影响

    Institute of Scientific and Technical Information of China (English)

    冯兵; 陈兴润; 王建泽

    2013-01-01

    在工业试验条件下分析了电磁搅拌电流强度、中包过热度和二冷水强度对430不锈钢连铸坯等轴晶率的影响规律.结果表明:430不锈钢连铸坯低倍组织由柱状晶和等轴晶组成;等轴晶率随电流强度的增大而依次增大,随过热度的减小而依次增大;采用较小的二冷水强度,430不锈钢低倍组织中的等轴晶率高.在电流强度为1 700A、中包过热度为20℃、二冷水比水量为0.95 L/kg时,430连铸坯生产的制品表面无起皱现象发生.%The effects of stirring current intensity,superheat in tundish and second cooling intensity on equiaxial crystal ratio of 430 stainless steel slab were analyzed under the conditions of industry test.The results show that macrostructure of 430 ferritic stainless steel slab consisted of columnar grains and equiaxial crystal grains.With the stirring current intensity increasing or superheat in tundish decreasing,the equiaxial crystal ratio of 430 stainless steel slab increases significantly.Weak cooling process is advantageous to obtaining high equiaxial crystal ratio.With current intensity of 1 700 A,superheat in tundish of 20 ℃ and second cooling intensity of 0.95 L/kg,the surface wrinkling of 430 cold-rolled plates do not happen.

  18. Screening of Modified RNA duplexes

    DEFF Research Database (Denmark)

    Schyth, Brian Dall; Bramsen, Jesper Bertram; Kjems, Jørgen

    Because of sequence specific gene targeting activity siRNAs are regarded as promising active compounds in gene medicine. But one serious problem with delivering siRNAs as treatment is the now well-established non-specific activities of some RNA duplexes. Cellular reactions towards double stranded...... RNAs include the 2´-5´ oligoadenylate synthetase system, the protein kinase R, RIG-I and Toll-like receptor activated pathways all resulting in antiviral defence mechanism. We have previously shown that antiviral innate immune reactions against double stranded RNAs could be detected in vivo as partial...... protection against a fish pathogenic virus. This protection corresponded with an interferon response in the fish. Here we use this fish model to screen siRNAs containing various chemical modifications of the RNA backbone for their antiviral activity, the overall aim being identification of an siRNA form...

  19. Migração de minerais de panelas brasileiras de aço inoxidável, ferro fundido e pedra-sabão (esteatito para simulantes de alimentos Mineral migration from stainless steel, cast iron and soapstone pans (steatite onto a food simulants

    Directory of Open Access Journals (Sweden)

    Késia Diego Quintaes

    2004-09-01

    Full Text Available Os utensílios culinários podem liberar alguns componentes inorgânicos durante a cocção de alimentos. A migração destes pode ser interessante desde que ocorra em quantidades adequadas às necessidades nutricionais do usuário ou não existam implicações toxicológicas. Foi avaliada a migração de metais (Fe, Mg, Mn, Cr, Ni, Ca, Zn, Pb, Cd e Hg por espectrometria de emissão óptica, utilizando ácidos láctico e acético como simulantes do alimento em panelas de aço inoxidável (304, ferro fundido (GG-10 e pedra-sabão (esteatito, durante 15 cocções seqüenciais. O comportamento da migração durante cinco ciclos de estocagem a 22ºC também foi estudado. Análise de regressão dos dados revelou que, em função do uso, as panelas de inox apresentam redução da migração de metais de forma rápida, enquanto as de pedra-sabão mostram um declínio suave na migração, contrastando com as de ferro, que apresentam aumento na migração de Fe e Mn com o uso contínuo. Em nenhum utensílio foi observada a liberação de metais pesados, como Pb, Cd ou Hg.Cookware may release some inorganic components into foods during cooking. Migration of ions could be of nutritional interest provided they do not pose a toxic hazard or are released in excess of the recommended amounts. In the present study the migration of Fe, Mg, Mn, Cr, Ni, Ca, Zn, Pb, Cd and Hg from stainless steel (304, cast iron (GG-10 and soapstone (steatite commercial cooking pans was evaluated in 15 sequential operations using lactic and acetic acids as food simulants. The migration patterns were also studied along five cycles of storage at 22ºC. Regression analysis of the data showed that while ions migrated out of the stainless steel pans in a rapidly decreasing fashion, the rate of migration from the stone utensils exhibited a slow and gradual decrease, in contrast with the increasing tendency observed for Fe and Mn in the cast iron pans. In no case was the release of heavy

  20. Microstructure and Abrasive Wear Resistance of 18Cr-4Ni-2.5Mo Cast Steel

    Directory of Open Access Journals (Sweden)

    B. Kalandyk

    2012-12-01

    Full Text Available An influence of a decreased Cr content on the microstructure of the highly alloyed Cr-Ni cast steel, duplex type, melted under laboratoryconditions, was characterized in the paper. The microstructure investigations were performed in the initial state and after the heat treatment (solution annealing at 1060C as well as the phase transformation kinetics at continuous cooling was measured. The wear resistance of the investigated cast steel was tested and compared with the 24%Cr-5%Ni-2.5%Mo cast steel.The Cr content decrease, in ferritic-austenitic cast steels (duplex, from 24-26%Cr to 18% leads to the changes of the castingsmicrostructure and eliminating of a brittle  phase. In dependence of the casting cooling rate, apart from ferrite and austenite, also fine martensite precipitates occur in the casting structure. It was shown that the investigated cast steel is characterised by a slightly lower wear resistance than the typical cast steel duplex grades.

  1. Block compressed sensing for feedback reduction in relay-aided multiuser full duplex networks

    KAUST Repository

    Elkhalil, Khalil

    2016-08-11

    Opportunistic user selection is a simple technique that exploits the spatial diversity in multiuser relay-aided networks. Nonetheless, channel state information (CSI) from all users (and cooperating relays) is generally required at a central node in order to make selection decisions. Practically, CSI acquisition generates a great deal of feedback overhead that could result in significant transmission delays. In addition to this, the presence of a full-duplex cooperating relay corrupts the fed back CSI by additive noise and the relay\\'s loop (or self) interference. This could lead to transmission outages if user selection is based on inaccurate feedback information. In this paper, we propose an opportunistic full-duplex feedback algorithm that tackles the above challenges. We cast the problem of joint user signal-to-noise ratio (SNR) and the relay loop interference estimation at the base-station as a block sparse signal recovery problem in compressive sensing (CS). Using existing CS block recovery algorithms, the identity of the strong users is obtained and their corresponding SNRs are estimated. Numerical results show that the proposed technique drastically reduces the feedback overhead and achieves a rate close to that obtained by techniques that require dedicated error-free feedback from all users. Numerical results also show that there is a trade-off between the feedback interference and load, and for short coherence intervals, full-duplex feedback achieves higher throughput when compared to interference-free (half-duplex) feedback. © 2016 IEEE.

  2. Solidification and casting

    CERN Document Server

    Cantor, Brian

    2002-01-01

    INDUSTRIAL PERSPECTIVEDirect chillcasting of aluminium alloysContinuous casting of aluminium alloysContinuous casting of steelsCastings in the automotive industryCast aluminium-silicon piston alloysMODELLING AND SIMULATIONModelling direct chill castingMold filling simulation of die castingThe ten casting rulesGrain selection in single crystal superalloy castingsDefects in aluminium shape castingPattern formation during solidificationPeritectic solidificationSTRUCTURE AND DEFECTSHetergeneous nucleation in aluminium alloysCo

  3. Nitrogen-Bearing Stainless Steels for Pressure Vessel%压力容器用含氮不锈钢

    Institute of Scientific and Technical Information of China (English)

    黄嘉琥

    2013-01-01

    压力容器用不锈钢几乎全为奥氏体不锈钢和奥氏体/铁素体双相不锈钢。在ASME -2011a, EN 13445:2009及GB 150-2011压力容器标准中所采用的奥氏体与双相不锈钢的所有牌号中,含氮钢牌号所占百分比分别为63.4%,76.4%和60%。在不锈钢材料标准中所有的双相不锈钢(指1971年后研制的牌号)、超级奥氏体不锈钢以及超级或特超级双相不锈钢中的氮含量基本均为0.1%~0.6%(称其为中氮型不锈钢)。EN 13445:2009规定可用于-273℃的奥氏体不锈钢10个牌号均为含氮钢。本文讨论了氮在不锈钢中的溶解度与含量、含氮不锈钢的类型、氮对不锈钢性能与组织的影响以及含氮不锈钢在压力容器中的应用。国外压力容器标准中N=0.1%~0.6%的中氮型奥氏体不锈钢已成为最重要的高性能不锈钢。这些钢在中国压力容器标准中尚未采用。而ASME-2011a中已用12个牌号,EN 13445:2009中已用14个牌号。中国仅在GB/T 20878-2007中已有23个牌号,GB/T 4237-2007(或GB/T 3280-2007)中已有13个牌号。本文建议在此基础上可进行更多的压力容器的应用工作。%Types of stainless steel for pressure vessel almost are all austenitic stainless steel and duplex austenitic/ferritic stainless steel.The percentages of designations of nitrogen-bearing steel grade individ-ually are 63 .4%,76 .4% and 60% among all designations of austenitic and duplex stainless steel types used in ASME-2011a,EN 13445:2009 and GB 150-2011 pressure vessel standards.Nitrogen contents of all duplex stainless steels(research after 1971),all super austenitic stainless steels and all super or hy-per duplex stainless steels in stainless steel standards basically are 0.1%~0.6%(call them middle ni-trogen-bearing stainless steel).10 designations of austenitic stainless steel can used for -273 ℃speci-fied in EN 13445:2009 are all nitrogen-bearing steel grade

  4. Practical, real-time, full duplex wireless

    KAUST Repository

    Jain, Mayank

    2011-01-01

    This paper presents a full duplex radio design using signal inversion and adaptive cancellation. Signal inversion uses a simple design based on a balanced/unbalanced (Balun) transformer. This new design, unlike prior work, supports wideband and high power systems. In theory, this new design has no limitation on bandwidth or power. In practice, we find that the signal inversion technique alone can cancel at least 45dB across a 40MHz bandwidth. Further, combining signal inversion cancellation with cancellation in the digital domain can reduce self-interference by up to 73dB for a 10MHz OFDM signal. This paper also presents a full duplex medium access control (MAC) design and evaluates it using a testbed of 5 prototype full duplex nodes. Full duplex reduces packet losses due to hidden terminals by up to 88%. Full duplex also mitigates unfair channel allocation in AP-based networks, increasing fairness from 0.85 to 0.98 while improving downlink throughput by 110% and uplink throughput by 15%. These experimental results show that a re- design of the wireless network stack to exploit full duplex capability can result in significant improvements in network performance. © 2011 ACM.

  5. Development and investigation of electroslag continuous casting

    Institute of Scientific and Technical Information of China (English)

    Ximin Zang; Zhouhua Jiang; Tieyi Pan

    2007-01-01

    The principle and technological design of electroslag continuous casting (ESCC), including bifilar mode, T-shaped mould,and metal level detecting system, are detailed. Remelting was carried out for 1Cr18Ni9Ti stainless steel with ESCC. The surface finish, chemical composition, macro- and microstructures, and inclusions of the remelted billets were characterized. ESCC reduces the cost and increases the productivity in comparison to traditional ESR, while achieves comparably excellent products.

  6. Microstructure and wear resistance of spray-formed supermartensitic stainless steel

    Directory of Open Access Journals (Sweden)

    Guilherme Zepon

    2013-06-01

    Full Text Available Since the early 90's the oil industry has been encouraging the development of corrosion and wear resistant alloys for onshore and offshore pipeline applications. In this context supermartensitic stainless steel was introduced to replace the more expensive duplex stainless steel for tubing applications. Despite the outstanding corrosion resistance of stainless steels, their wear resistance is of concern. Some authors reported obtaining material processed by spray forming, such as ferritic stainless steel, superduplex stainless steel modified with boron, and iron-based amorphous alloys, which presented high wear resistance while maintaining the corrosion performance1,2. The addition of boron to iron-based alloys promotes the formation of hard boride particles (M2B type which improve their wear resistances3-9. This work aimed to study the microstructure and wear resistance of supermartensitic stainless steel modified with 0.3 wt. (% and 0.7 wt. (% processed by spray forming (SF-SMSS 0.3%B and SF-SMSS 0.7%B, respectively. These boron contents were selected in order to improve the wear resistance of supermartensitic stainless steel through the formation of uniformly distributed borides maintaining the characteristics of the corrosion resistant matrix. SF-SMSS 0.7%B presents an abrasive wear resistance considerably higher than spray-formed supermartensitic stainless steel without boron addition (SF-SMSS.

  7. Martensitic stainless steel seamless linepipe with superior weldability and CO{sub 2} corrosion resistance

    Energy Technology Data Exchange (ETDEWEB)

    Miyata, Y.; Kimura, M.; Koseki, T.; Toyooka, T.; Murase, F. [Kawasaki Steel Corp., Handa, Aichi (Japan)

    1997-08-01

    Two types of new martensitic stainless steel with good weldability and superior corrosion resistance have been developed for line pipe application. Both steels are suitable for welding without preheating owing to lowering C and N contents, and they show good low temperature toughness in welds without PWHT. One is applied to sweet environments. It gives better resistance to CO{sub 2} corrosion than the 13Cr martensitic stainless steel for OCTG. Lowering C and addition of Ni contribute to reduction of general corrosion rate in the CO{sub 2} environment. The addition of Cu improves the pitting resistance. The other is applied to light sour environments. It gives good SSC resistance in welds owing to the improvement of the pitting resistance due to Mo addition. The seamless pipes of these martensitic stainless steels are applicable as substitutes for a part of duplex stainless steel flow lines.

  8. Nodular cast iron and casting monitoring

    Directory of Open Access Journals (Sweden)

    S. Pietrowski

    2008-10-01

    Full Text Available In this paper quality monitoring of nodular cast iron and casting made of it is presented. A control system of initial liquid cast iron to spheroidization, after spheroidization and inoculation with using of TDA method was shown. An application of an ultrasonic method to assessment of the graphite form and the metal matrix microstructure of castings was investigated.

  9. Nodular cast iron and casting monitoring

    OpenAIRE

    2008-01-01

    In this paper quality monitoring of nodular cast iron and casting made of it is presented. A control system of initial liquid cast iron to spheroidization, after spheroidization and inoculation with using of TDA method was shown. An application of an ultrasonic method to assessment of the graphite form and the metal matrix microstructure of castings was investigated.

  10. Metallic Reinforcement of Direct Squeeze Die Casting Aluminum Alloys for Improved Strength and Fracture Resistance

    Energy Technology Data Exchange (ETDEWEB)

    D. Schwam: J.F. Wallace: Y. Zhu: J.W. Ki

    2004-10-01

    The utilization of aluminum die casting as enclosures where internal equipment is rotating inside of the casting and could fracture requires a strong housing to restrain the fractured parts. A typical example would be a supercharger. In case of a failure, unless adequately contained, fractured parts could injure people operating the equipment. A number of potential reinforcement materials were investigated. The initial work was conducted in sand molds to create experimental conditions that promote prolonged contact of the reinforcing material with molten aluminum. Bonding of Aluminum bronze, Cast iron, and Ni-resist inserts with various electroplated coatings and surface treatments were analyzed. Also toughening of A354 aluminum cast alloy by steel and stainless steel wire mesh with various conditions was analyzed. A practical approach to reinforcement of die cast aluminum components is to use a reinforcing steel preform. Such performs can be fabricated from steel wire mesh or perforated metal sheet by stamping or deep drawing. A hemispherical, dome shaped casting was selected in this investigation. A deep drawing die was used to fabricate the reinforcing performs. The tendency of aluminum cast enclosures to fracture could be significantly reduced by installing a wire mesh of austenitic stainless steel or a punched austenitic stainless steel sheet within the casting. The use of reinforcements made of austenitic stainless steel wire mesh or punched austenitic stainless steel sheet provided marked improvement in reducing the fragmentation of the casting. The best strengthening was obtained with austenitic stainless steel wire and with a punched stainless steel sheet without annealing this material. Somewhat lower results were obtained with the annealed punched stainless steel sheet. When the annealed 1020 steel wire mesh was used, the results were only slightly improved because of the lower mechanical properties of this unalloyed steel. The lowest results were

  11. Full Duplex Emulation via Spatial Separation of Half Duplex Nodes in a Planar Cellular Network

    DEFF Research Database (Denmark)

    Thomsen, Henning; Kim, Dong Min; Popovski, Petar;

    2016-01-01

    A Full Duplex Base Station (FD-BS) can be used to serve simultaneously two Half-Duplex (HD) Mobile Stations (MSs), one working in the uplink and one in the downlink, respectively. The same functionality can be realized by having two interconnected and spatially separated Half Duplex Base Stations...... (HD-BSs), which is a scheme termed CoMPflex (CoMP for In-Band Wireless Full Duplex). A FD-BS can be seen as a special case of CoMPflex with separation distance zero. In this paper we study the performance of CoMPflex in a two-dimensional cellular scenario using stochastic geometry and compare...... of communication reliability. Following the trend of wireless network densification, CoMPflex can be regarded as a method with a great potential to effectively use the dense HD deployments....

  12. Ultra-short silicon MMI duplexer

    Science.gov (United States)

    Yi, Huaxiang; Huang, Yawen; Wang, Xingjun; Zhou, Zhiping

    2012-11-01

    The fiber-to-the-home (FTTH) systems are growing fast these days, where two different wavelengths are used for upstream and downstream traffic, typically 1310nm and 1490nm. The duplexers are the key elements to separate these wavelengths into different path in central offices (CO) and optical network unit (ONU) in passive optical network (PON). Multimode interference (MMI) has some benefits to be a duplexer including large fabrication tolerance, low-temperature dependence, and low-polarization dependence, but its size is too large to integrate in conventional case. Based on the silicon photonics platform, ultra-short silicon MMI duplexer was demonstrated to separate the 1310nm and 1490nm lights. By studying the theory of self-image phenomena in MMI, the first order images are adopted in order to keep the device short. A cascaded MMI structure was investigated to implement the wavelength splitting, where both the light of 1310nm and 1490nm was input from the same port, and the 1490nm light was coupling cross the first MMI and output at the cross-port in the device while the 1310nm light was coupling through the first and second MMI and output at the bar-port in the device. The experiment was carried on with the SOI wafer of 340nm top silicon. The cascaded MMI was investigated to fold the length of the duplexer as short as 117μm with the extinct ratio over 10dB.

  13. On the Secrecy Degrees of Freedom with Full Duplex Communication

    DEFF Research Database (Denmark)

    Mahmood, Nurul Huda; Mogensen, Preben Elgaard

    2017-01-01

    and the delay reduction of full duplex communication are somewhat limited in realistic network settings, leading researchers to study other possible applications of full duplex communication which can provide significantly higher gains over half duplex communication. Physical layer security is an example...... of such an application. The potential of full duplex nodes in improving the physical layer security of a communication link is investigated in this contribution. We specifically derive the information theoretic secrecy degrees of freedom measure for a pair of nodes communicating in full duplex mode. Moreover, closed...

  14. On the Ergodic Secrecy Capacity with Full Duplex Communication

    DEFF Research Database (Denmark)

    Mahmood, Nurul Huda; Shafique Ansari, Imran; Mogensen, Preben Elgaard

    2017-01-01

    of full duplex communication providing significantly higher gains over half duplex communication. The potential of full duplex nodes in improving the physical layer security of a communication link is investigated in this contribution. Specifically, we present a thorough analysis of the ergodic secrecy......Full duplex communication promises performance gains in terms of the throughput and the delay. Generally, it has been shown that the throughput and delay gains of full duplex communication are somewhat limited in realistic network settings, leading researchers to study other possible applications...

  15. Moldless casting by laser

    Science.gov (United States)

    McLean, Marc A.; Shannon, G. J.; Steen, William M.

    1997-09-01

    The principle of laser cladding involves the use of high power carbon-dioxide lasers and powder deposition technology to provide wear and corrosion resistant surface coatings to engineering components. By injecting metal powder into a laser generated melt pool on a moving substrate a solidified metal track can be produced. Deposition of successive tracks produces a multi-layer build. Laser direct casting (LDC) utilizes a coaxial nozzle enabling consistent omnidirectional deposition to produce 3D components from a selection of metal powders. The influence of the principal process parameters over the process features namely, powder catchment efficiency, beam shape and build rates are presented with several successfully generated 3D components. Nickel, stainless steel and satellite powders were deposited at laser powders of 0.4 to 1.4 kW and speeds of 500 to 1000 mm/min achieving build rates of 3 to 9 mm3/s. Fully dense metallurgical structures have been produced with no cracking or porosity and powder catchment efficiencies up to 85% have been achieved.

  16. Casting materials

    Energy Technology Data Exchange (ETDEWEB)

    Chaudhry, Anil R. (Xenia, OH); Dzugan, Robert (Cincinnati, OH); Harrington, Richard M. (Cincinnati, OH); Neece, Faurice D. (Lyndurst, OH); Singh, Nipendra P. (Pepper Pike, OH)

    2011-06-14

    A foam material comprises a liquid polymer and a liquid isocyanate which is mixed to make a solution that is poured, injected or otherwise deposited into a corresponding mold. A reaction from the mixture of the liquid polymer and liquid isocyanate inside the mold forms a thermally collapsible foam structure having a shape that corresponds to the inside surface configuration of the mold and a skin that is continuous and unbroken. Once the reaction is complete, the foam pattern is removed from the mold and may be used as a pattern in any number of conventional casting processes.

  17. THE EFFECT OF W ON THE REPASSIVATION BEHAVIOR OF Ni-ADDED STAINLESS STEELS

    Institute of Scientific and Technical Information of China (English)

    J.X. Pan; K. Y. Kim

    2005-01-01

    The effect of W on the repassivation behavior of Ni-added stainless steels was investigated with respect to the repassivation rate and the SCC susceptibility. It was found that more stable passive film was formed on the W-modified stainless steels than that of steels without W-modification, and the repassivation rate was faster for W-modified stainless steels in acidic chloride solution (0.5M H2SO4+3.5% Cl-). In neutral chloride solution (1M MgCl2), there were no significant differences on both passivation properties and the repassivation rates for duplex stainless steels,while W-modified austenite stainless steel showed faster repassivation rate. The SCC tests verified that W-modified Ni-added stainless steels exhibited better SCC resistance than steels without W in chloride solution. Moreover, W-modification in higher Ni-added stainless steels exhibited more remarkable SCC resistance than steels with lower Ni content in chloride solution.

  18. The UK Casting Industry

    Institute of Scientific and Technical Information of China (English)

    Jincheng Liu

    2006-01-01

    The casting production in the UK in 2004 is presented and analysed. The UK casting industry has played an important role in world casting and manufacturing production. However recent years the rapid development of some developing countries has been shifting the casting production from the western industrialized countries including the UK. The UK casting industry and associated research and technology organizations, universities have been working together very hard to face the serious competition to make the UK casting industry have a sustainable future. The UK casting industry remains strong and plays an important role in world casting and manufacturing production.

  19. CA Investment Casting Process of Complex Castings

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    CA (Computer aided) investment casting technique used in superalloy castings of aerospace engine parts was presented. CA investment casting integrated computer application, RP (Rapid Prototyping) process, solidification simulation and investment casting process. It broke the bottle neck of making metal die. Solid model of complex parts were produced by UGII or other software, then translated into STL(Stereolithography) file, after RP process of SLS(Selective Laser Sintering), wax pattern used in investment ...

  20. Cast irons

    CERN Document Server

    1996-01-01

    Cast iron offers the design engineer a low-cost, high-strength material that can be easily melted and poured into a wide variety of useful, and sometimes complex, shapes. This latest handbook from ASM covers the entire spectrum of one of the most widely used and versatile of all engineered materials. The reader will find the basic, but vital, information on metallurgy, solidification characteristics, and properties. Extensive reviews are presented on the low-alloy gray, ductile, compacted graphite, and malleable irons. New and expanded material has been added covering high-alloy white irons used for abrasion resistance and high-alloy graphitic irons for heat and corrosion resistance. Also discussed are melting furnaces and foundry practices such as melting, inoculation, alloying, pouring, gating and rising, and molding. Heat treating practices including stress relieving, annealing, normalizing, hardening and tempering, autempering (of ductile irons), and surface-hardening treatments are covered, too. ASM Spec...

  1. The ancient Chinese casting techniques

    OpenAIRE

    2011-01-01

    In the course of Chinese civilization, which lasted more than 5,000 years, casting production has made a huge contribution. In this paper, some representative metal castings were presented. According to their forming techniques, they can be grouped into stone mould casting, clay mould casting, ablation casting, lost wax casting, stack casting, permanent mould casting, sand casting, etc. According to their materials, they can be categorized into tin bronze, bimetallic bronze, malleable cast ir...

  2. Protection of aluminium by duplex coatings

    Energy Technology Data Exchange (ETDEWEB)

    Musil, J. [Ceska Akademie Ved, Prague (Czech Republic). Fyzikalni Ustav; Vlcek, J. [West Bohemia Univ., Plzen (Czech Republic). Dept. of Phys.; Jezek, V. [West Bohemia Univ., Plzen (Czech Republic). Dept. of Phys.; Benda, M. [West Bohemia Univ., Plzen (Czech Republic). Dept. of Phys.

    1995-11-01

    The paper reports on a new way of producing duplex coatings consisting of two steps. First, the substrate is coated by a physically vapour-deposited coating. Then, this precoated substrate is plasma nitrided or vacuum heat treated. This method was tested in the protection of substrates made of aluminium with a sputtered Ti coating about 5 {mu}m thick. The as-deposited and then plasma-nitrided or vacuum-heat-treated (Ti coating)/(Al substrate) couple was characterized by elemental depth profiles measured by glow discharge optical spectroscopy. It was shown that both the plasma nitriding and vacuum heat treatment process can stimulate a strong interdiffusion between Ti and the substrate elements. It results not only in the formation of a very broad interfacial region with a dramatic redistribution of the substrate elements in the Ti film but also in a formation of intermetallic Ti-Al compounds. This new duplex coating technique is described in detail. (orig.)

  3. Renal duplex Doppler ultrasound findings in diabetics

    Energy Technology Data Exchange (ETDEWEB)

    Shim, Hyang Yee; Kim, Young Geun; Kook, Cheol Keu; Yoon, Chong Hyun; Lee, Shin Hyung; Lee, Chang Joon [National Medical Center, Seoul (Korea, Republic of)

    1993-12-15

    The correlation between clinical-laboratory findings and renal duplex Doppler ultrasound findings was studied in 45 patients with diabetes mellitus to see the role of duplex Doppler ultrasound in the detection of diabetic nephropathy. The resistive indices in patients with elevated serum creatinine, BUN, proteinuria, and systolic blood pressure levels were statistically significantly higher than those in patients with normal levels (p<0.05). Also resistive indics in patients with retinopathy were higher than that in patients without retinopathy (p<0.05). But the ultrasound morphologic changes of kidney such as renal length, cortical eye-catching, and corticomedullarycontrast were not well correlated with clinical-laboratory data and resistive index. The resistive index of the kidney in conjunction with clinical-laboratory data in diabetics may be helpful in the evaluation of diabetic nephropathy

  4. Thin Wall Iron Castings

    Energy Technology Data Exchange (ETDEWEB)

    J.F. Cuttino; D.M. Stefanescu; T.S. Piwonka

    2001-10-31

    Results of an investigation made to develop methods of making iron castings having wall thicknesses as small as 2.5 mm in green sand molds are presented. It was found that thin wall ductile and compacted graphite iron castings can be made and have properties consistent with heavier castings. Green sand molding variables that affect casting dimensions were also identified.

  5. Full duplex communication using visible light

    CERN Document Server

    Yang, Yongchao; Li, Yuanhang; Gao, Xumin; Yuan, Jialei; Zhu, Hongbo; Wang, Yongjin

    2016-01-01

    In this work, we propose, fabricate and characterize a full duplex communication system using visible light on a single chip. Both the suspended p-n junction InGaN/GaN multiple quantum well (MQW) devices and the suspended waveguides are obtained on a GaN-on-silicon platform by wafer-level processing. Two suspended p-n junction InGaN/GaN MQW devices that can both emit and detect light simultaneously are connected using suspended waveguides to form an in-plane visible light communication (VLC) system. The light that is emitted from one suspended p-n junction InGaN/GaN MQW device can induce a current in the device located at the other end of the waveguide via in-plane light coupling, thus leading to full duplex communication using visible light. This proof-of-concept in-plane VLC system paves the way towards the implementation of a full duplex communications system operating at the same frequency using visible light on a single chip.

  6. Articles comprising ferritic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Rakowski, James M.

    2016-06-28

    An article of manufacture comprises a ferritic stainless steel that includes a near-surface region depleted of silicon relative to a remainder of the ferritic stainless steel. The article has a reduced tendency to form an electrically resistive silica layer including silicon derived from the steel when the article is subjected to high temperature oxidizing conditions. The ferritic stainless steel is selected from the group comprising AISI Type 430 stainless steel, AISI Type 439 stainless steel, AISI Type 441 stainless steel, AISI Type 444 stainless steel, and E-BRITE.RTM. alloy, also known as UNS 44627 stainless steel. In certain embodiments, the article of manufacture is a fuel cell interconnect for a solid oxide fuel cell.

  7. Joint duplex mode selection, channel allocation, and power control for full-duplex cognitive femtocell networks

    Directory of Open Access Journals (Sweden)

    Mingjie Feng

    2015-02-01

    Full Text Available In this paper, we aim to maximize the sum rate of a full-duplex cognitive femtocell network (FDCFN as well as guaranteeing the quality of service (QoS of users in the form of a required signal to interference plus noise ratios (SINR. We first consider the case of a pair of channels, and develop optimum-achieving power control solutions. Then, for the case of multiple channels, we formulate joint duplex model selection, power control, and channel allocation as a mixed integer nonlinear problem (MINLP, and propose an iterative framework to solve it. The proposed iterative framework consists of a duplex mode selection scheme, a near-optimal distributed power control algorithm, and a greedy channel allocation algorithm. We prove the convergence of the proposed iterative framework as well as a lower bound for the greedy channel allocation algorithm. Numerical results show that the proposed schemes effectively improve the sum rate of FDCFNs.

  8. Corrosive-wear resistance of stainless steels for the impeller of slurry pump used in zinc hydrometallurgy process

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    This paper presents corrosive-wear (C-W) behaviors of three kinds of steels under the simulating condition of traditional zinc hydrometallurgy process by using a self-made rotating disk apparatus. Result shows that pure wear loss rate is significantly larger than pure corrosion loss rate. Under this C-W condition, the ranking of C-W resistance is S2 > S3 > S1 (S1: austenite stainless steel; S2: CD-4MCu duplex stainless steel; S3:17-4PH stainless steel). S2 has excellent C-W resistance due to strong surface deformation strengthening effect of high-density dislocations of the γphase. S3 also has excellent C-W resistance owing to high hardness and strength. However, S1 does not show good C-W resistance under strong erosion of liquid-solid slurry because of its single-phase austenitic structure and very low hardness. As a result, duplex stainless steels as well as 17-4 PH stainless steel can be used as impeller candidate materials in the zinc hydrometallurgy process due to their excellent C-W resistance and lower cost.

  9. Corrosive-wear resistance of stainless steels for the impeller of slurry pump used in zinc hydrometallurgy process

    Directory of Open Access Journals (Sweden)

    Ping LI

    2005-08-01

    Full Text Available This paper presents corrosive-wear (C-W behaviors of three kinds of steels under the simulating condition of traditional zinc hydrometallurgy process by using a self-made rotating disk apparatus. Result shows that pure wear loss rate is significantly larger than pure corrosion loss rate. Under this C-W condition, the ranking of C-W resistance is S2 > S3 > S1 (S1: austenite stainless steel; S2: CD-4MCu duplex stainless steel; S3 :17-4PH stainless steel. S2 has excellent C-W resistance due to strong surface deformation strengthening effect of high-density dislocations of the γ phase. S3 also has excellent C-W resistance owing to high hardness and strength. However, S1 does not show good C-W resistance under strong erosion of liquid-solid slurry because of its single-phase austenitic structure and very low hardness. As a result, duplex stainless steels as well as 17-4 PH stainless steel can be used as impeller candidate materials in the zinc hydrometallurgy process due to their excellent C-W resistance and lower cost.

  10. Interplay of microbiological corrosion and alloy microstructure in stress corrosion cracking of weldments of advanced stainless steels

    Indian Academy of Sciences (India)

    R K Singh Raman

    2003-06-01

    This paper presents an overview of the phenomenon of stress corrosion cracking (SCC) of duplex stainless steels and their weldments in marine environments and the potential role of microbial activity in inducing SCC susceptibility. As a precursor to the topic the paper also reviews the performance of the traditional corrosion-resistant alloys and their weldments and the necessity of using duplex stainless steels (DSS), in order to alleviate corrosion problems in marine environments. Given that the performance of weldments of such steels is often unsatisfactory, this review also assesses the research needs in this area. In this context the paper also discusses the recent reports on the role of microorganisms in inducing hydrogen embrittlements and corrosion fatigue.

  11. q-Ising model on a duplex and a partially duplex clique

    CERN Document Server

    Chmiel, Anna; Sznajd-Weron, Katarzyna

    2016-01-01

    We analyze a modified kinetic Ising model, so called $q$- neighbor Ising model, with Metropolis dynamics,[Phys. Rev. E {\\bf92} 052105] on a duplex clique and a partially duplex clique. In the $q$-Ising model each spin interacts only with $q$ spins randomly chosen from the whole neighborhood. In the case of a duplex clique the change of a spin is allowed only if both levels simultaneously induce this change. Due to the mean-field like nature of the model we are able to derive the analytic form of transition probabilities and solve the corresponding master equation. The existence of the second level changes dramatically the character of the phase transition. In the case of the monoplex clique, the $q$-neighbor Ising model exhibits continuous phase transition for $q=3$, discontinuous phase transition for $q \\ge 4$ and for $q=1$ and $q=2$ the phase transition is not observed. On the other hand, in the case of the duplex clique continuous phase transitions are observed for all values of $q$, even for $q=1$ and $q=...

  12. Dimensional accuracy of stone casts made from silicone-based impression materials and three impression techniques.

    Science.gov (United States)

    Vitti, Rafael Pino; da Silva, Marcos Aurélio Bomfim; Consani, Rafael Leonardo Xediek; Sinhoreti, Mário Alexandre Coelho

    2013-01-01

    The aim of this study was to measure and compare the dimensional accuracy of stone casts of a partially edentulous mandibular arch made by two condensation silicones, two addition silicones and three impression techniques (1-step putty/light-body, 2-step putty/light-body and monophase technique). A partially edentulous standard stainless steel mandibular arch cast was obtained with reference points on the permanent mandibular right and left canines, and permanent mandibular right and left second molars. The anteroposterior distances (between the mandibular left canine and second molar and between the mandibular right canine and second molar) and transverse distances (between the mandibular left and right canines and between the mandibular left and right second molars) of stainless steel cast were measured by a microscope at 30× magnification and 0.5 µm accuracy. All impressions were made with condensation or addition silicones. The 1- and 2-step putty/light-body impressions were accomplished with putty and light-body materials and the monophase impressions with light-body material only. After the impression procedures, accuracy of each material and technique was assessed measuring the stone casts poured (n=5) from the impressions, by the same microscope. The differences between the values of stone cast and stainless steel cast were calculated, presented as percentages and analyzed statistically by two-way ANOVA and the means compared by Tukey's test (α=0.05). All distances measured on stone casts showed altered dimensions with significantly negative linear changes (shrinkage) as compared to those of the stainless steel cast. The stone casts made from the addition silicones were dimensionally more accurate. No differences were found among the impression techniques.

  13. Solidification control in continuous casting of steel

    Indian Academy of Sciences (India)

    S Mazumdar; S K Ray

    2001-02-01

    An integrated understanding of heat transfer during solidification, friction/lubrication at solid-liquid interface, high temperature properties of the solidifying shell etc. is necessary to control the continuous casting process. The present paper elaborates upon the knowledge developed in the areas of initial shell formation, mode of mould oscillation, and lubrication mechanism. The effect of these issues on the caster productivity and the quality of the product has been discussed. The influence of steel chemistry on solidification dynamics, particularly with respect to mode of solidification and its consequence on strength and ductility of the solidifying shell, has been dealt with in detail. The application of these basic principles for casting of stainless steel slabs and processing to obtain good quality products have been covered.

  14. Duplex tube steam reformer development program

    Energy Technology Data Exchange (ETDEWEB)

    Lewe, C K; Nieto, J M; Papadopoulos, A

    1978-09-01

    Work done in partial fulfillment of Task 7 of the Duplex Steam Reformer Development Program is described. The DSR concept acts as a double barrier between a process heat high temperature reactor plant (PNP) and a closed loop chemical heat pipe (CHP) for the long distance transport of chemical energy to a remote industrial user. The current state of the DSR design is described as well as related systems and equipment. The PNP concept presented is based upon work currently underway in the Federal Republic of Germany.

  15. Scintigraphic features of duplex kidneys on DMSA renal cortical scans.

    Science.gov (United States)

    Kwatra, Neha; Shalaby-Rana, Eglal; Majd, Massoud

    2013-09-01

    The spectrum of manifestations of duplex kidneys on (99m)Tc-dimercaptosuccinic acid (DMSA) renal cortical scans and correlating findings on other imaging modalities are presented. Relevant embryology of the duplex systems and technical aspects of DMSA scintigraphy are reviewed.

  16. On the Ergodic Secrecy Capacity with Full Duplex Communication

    DEFF Research Database (Denmark)

    Mahmood, Nurul Huda; Shafique Ansari, Imran; Mogensen, Preben Elgaard;

    2017-01-01

    Full duplex communication promises performance gains in terms of the throughput and the delay. Generally, it has been shown that the throughput and delay gains of full duplex communication are somewhat limited in realistic network settings, leading researchers to study other possible applications...

  17. Structural Properties of G,T-Parallel Duplexes

    Directory of Open Access Journals (Sweden)

    Anna Aviñó

    2010-01-01

    Full Text Available The structure of G,T-parallel-stranded duplexes of DNA carrying similar amounts of adenine and guanine residues is studied by means of molecular dynamics (MD simulations and UV- and CD spectroscopies. In addition the impact of the substitution of adenine by 8-aminoadenine and guanine by 8-aminoguanine is analyzed. The presence of 8-aminoadenine and 8-aminoguanine stabilizes the parallel duplex structure. Binding of these oligonucleotides to their target polypyrimidine sequences to form the corresponding G,T-parallel triplex was not observed. Instead, when unmodified parallel-stranded duplexes were mixed with their polypyrimidine target, an interstrand Watson-Crick duplex was formed. As predicted by theoretical calculations parallel-stranded duplexes carrying 8-aminopurines did not bind to their target. The preference for the parallel-duplex over the Watson-Crick antiparallel duplex is attributed to the strong stabilization of the parallel duplex produced by the 8-aminopurines. Theoretical studies show that the isomorphism of the triads is crucial for the stability of the parallel triplex.

  18. Predicting Pattern Tooling and Casting Dimensions for Investment Casting, Phase III

    Energy Technology Data Exchange (ETDEWEB)

    Sabau, Adrian S [ORNL

    2008-04-01

    Efforts during Phase III focused mainly on the shell-alloy systems. A high melting point alloy, 17-4PH stainless steel, was considered. The experimental part of the program was conducted at ORNL and commercial foundries, where wax patterns were injected, molds were invested, and alloys were poured. Shell molds made of fused-silica and alumino-silicates were considered. A literature review was conducted on thermophysical and thermomechanical properties alumino-silicates. Material property data, which were not available from material suppliers, was obtained. For all the properties of 17-4PH stainless steel, the experimental data available in the literature did not cover the entire temperature range necessary for process simulation. Thus, some material properties were evaluated using ProCAST, based on CompuTherm database. A comparison between the predicted material property data and measured property data was made. It was found that most material properties were accurately predicted only over several temperature ranges. No experimental data for plastic modulus were found. Thus, several assumptions were made and ProCAST recommendations were followed in order to obtain a complete set of mechanical property data at high temperatures. Thermal expansion measurements for the 17-4PH alloy were conducted during heating and cooling. As a function of temperature, the thermal expansion for both the alloy and shell mold materials showed different evolution on heating and cooling. Numerical simulations were performed using ProCAST for the investment casting of 17-4PH stainless steel parts in fused silica molds using the thermal expansion obtained on heating and another one with thermal expansion obtained on cooling. Since the fused silica shells had the lowest thermal expansion properties in the industry, the dewaxing phase, including the coupling between wax-shell systems, was neglected. The shell mold was considered to be a pure elastic material. The alloy dimensions were

  19. LLNL casting technology

    Science.gov (United States)

    Shapiro, A. B.; Comfort, W. J., III

    1994-01-01

    Competition to produce cast parts of higher quality, lower rejection rate, and lower cost is a fundamental factor in the global economy. To gain an edge on foreign competitors, the US casting industry must cut manufacturing costs and reduce the time from design to market. Casting research and development (R&D) are the key to increasing US competiveness in the casting arena. Lawrence Livermore National Laboratory (LLNL) is the home of a wide range of R&D projects that push the boundaries of state-of-the art casting. LLNL casting expertise and technology include: casting modeling research and development, including numerical simulation of fluid flow, heat transfer, reaction/solidification kinetics, and part distortion with residual stresses; special facilities to cast toxic material; extensive experience casting metals and nonmetals; advanced measurement and instrumentation systems. Department of Energy (DOE) funding provides the leverage for LLNL to collaborate with industrial partners to share this advanced casting expertise and technology. At the same time, collaboration with industrial partners provides LLNL technologists with broader insights into casting industry issues, casting process data, and the collective experience of industry experts. Casting R&D is also an excellent example of dual-use technology; it is the cornerstone for increasing US industrial competitiveness and minimizing waste nuclear material in weapon component production. Annual funding for casting projects at LLNL is $10M, which represents 1% of the total LLNL budget. Metal casting accounts for about 80% of the funding. Funding is nearly equally divided between development directed toward US industrial competitiveness and weapon component casting.

  20. Spermine Condenses DNA, but Not RNA Duplexes

    Energy Technology Data Exchange (ETDEWEB)

    Katz, Andrea M.; Tolokh, Igor S.; Pabit, Suzette A.; Baker, Nathan; Onufriev, Alexey V.; Pollack, Lois

    2017-01-01

    Interactions between the polyamine spermine and nucleic acids drive important cellular processes. Spermine condenses DNA, and some RNAs such as poly(rA):poly(rU). A large fraction of the spermine present in cells is bound to RNA, but apparently does not condense it. Here, we study the effect of spermine binding to short duplex RNA and DNA and compare our findings with predictions of molecular dynamics simulations. When small numbers of spermine are introduced, RNA with a designed sequence, containing a mixture of 14 GC pairs and 11 AU pairs, resists condensation relative to DNA of an equivalent sequence or to 25 base pair poly(rA):poly(rU) RNA. Comparison of wide-angle x-ray scattering profiles with simulation suggests that spermine is sequestered deep within the major groove of mixed sequence RNA, preventing condensation by limiting opportunities to bridge to other molecules as well as stabilizing the RNA by locking it into a particular conformation. In contrast, for DNA, simulations suggest that spermine binds external to the duplex, offering opportunities for intermolecular interaction. The goal of this study is to explain how RNA can remain soluble, and available for interaction with other molecules in the cell, despite the presence of spermine at concentrations high enough to precipitate DNA.

  1. Duplex scanning using sparse data sequences

    DEFF Research Database (Denmark)

    Møllenbach, S. K.; Jensen, Jørgen Arendt

    2008-01-01

    The velocity distribution in vessels can be displayed using duplex scanning where B-mode acquisitions are interspaced with the velocity data. This gives an image for orientation, but lowers the maximum detectable velocity by a factor of two. Other pulse sequences either omits the B-mode image...... or leaves gaps in the velocity data, which makes it difficult to output audio data. The near full velocity range can be maintained and B-mode images shown by using a sparse data sequence with velocity and B-mode samples intermixed. The B-mode samples are placed in a (sparse) periodical pattern, which makes...... is scaled by the factor A/T. The approach has been investigated using in vivo RF data from the Hepatic vein, Carotid artery and Aorta from a 33 year old healthy male. A B-K Medical 3535 ultrasound scanner has been used in Duplex mode with a BK 8556, 3.2 MHz linear array probe. The sampling frequency...

  2. DNA Duplex Engineering for Enantioselective Fluorescent Sensor.

    Science.gov (United States)

    Hu, Yuehua; Lin, Fan; Wu, Tao; Zhou, Yufeng; Li, Qiusha; Shao, Yong; Xu, Zhiai

    2017-02-21

    The rapid identification of biomacromolecule structure that has a specific association with chiral enantiomers especially from natural sources will be helpful in developing enantioselective sensor and in speeding up drug exploitation. Herein, owing to its existence also in living cells, apurinic/apyrimidinic site (AP site) was first engineered into ds-DNA duplex to explore its competence in enantiomer selectivity. An AP site-specific fluorophore was utilized as an enantioselective discrimination probe to develop a straightforward chiral sensor using natural tetrahydropalmatine (L- and D-THP) as enantiomer representatives. We found that only L-THP can efficiently replace the prebound fluorophore to cause a significant fluorescence increase due to its specific binding with the AP site (two orders magnitude higher in affinity than binding with D-THP). The AP site binding specificity of L-THP over D-THP was assessed via intrinsic fluorescence, isothermal titration calorimetry, and DNA stability. The enantioselective performance can be easily tuned by the sequences near the AP site and the number of AP sites. A single AP site provides a perfect binding pocket to differentiate the chiral atom-induced structure discrepancy. We expect that our work will inspire interest in engineering local structures into a ds-DNA duplex for developing novel enantioselective sensors.

  3. Investigations on aged Ti-stabilised stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Ehrnsten, U.; Karjalainen-Roikonen, P.; Nenonen, P. [VTT Industrial Systems, Espoo (Finland); Korhonen, R. [Fortum Nuclear Services, Vantaa (Finland); Timofeev, B.T.; Bloomin, A.A. [ZNIIKM, St. Petersburg (Russian Federation)

    2003-03-01

    Mechanical and microstructural properties of cast material of type O8X8H10TL and wrought and welded stainless steel pipe material of type O8X8H10T have been determined, aged at NPP operation temperature for about 100 000 h and 200 000 h, respectively. The mechanical properties were determined using tensile testing, impact energy determination and fracture resistance testing. The microstructures were studied using optical, scanning and transmission electron microscopy. The mechanical properties of the cast Ti-stabilised stainless steel material are evaluated to be only slightly affected by long term ({approx} 100 000 hours) operation at NPP operation temperature. Also the effect of even longer ({approx} 200 000 hours) operation on wrought Ti-stabilised pipe material is very small, as the properties of the aged material are within the normal range of as-manufactured material. The mechanical properties of the Mo-alloyed stainless steel weld metal after {approx} 200 000 hours of operation are still good, although indications of changes due to thermal ageing were observed. (orig.)

  4. An atom probe perspective on phase separation and precipitation in duplex stainless steels

    Science.gov (United States)

    Guo, Wei; Garfinkel, David A.; Tucker, Julie D.; Haley, Daniel; Young, George A.; Poplawsky, Jonathan D.

    2016-06-01

    Three-dimensional chemical imaging of Fe-Cr alloys showing Fe-rich (α)/Cr-rich (α‧) phase separation is reported using atom probe tomography techniques. The extent of phase separation, i.e., amplitude and wavelength, has been quantitatively assessed using the Langer-Bar-on-Miller, proximity histogram, and autocorrelation function methods for two separate Fe-Cr alloys, designated 2101 and 2205. Although the 2101 alloy possesses a larger wavelength and amplitude after annealing at 427 °C for 100-10 000 h, it exhibits a lower hardness than the 2205 alloy. In addition to this phase separation, ultra-fine Ni-Mn-Si-Cu-rich G-phase precipitates form at the α/α‧ interfaces in both alloys. For the 2101 alloy, Cu clusters act to form a nucleus, around which a Ni-Mn-Si shell develops during the precipitation process. For the 2205 alloy, the Ni and Cu atoms enrich simultaneously and no core-shell chemical distribution was found. This segregation phenomenon may arise from the exact Ni/Cu ratio inside the ferrite. After annealing for 10 000 h, the number density of the G-phase within the 2205 alloy was found to be roughly one order of magnitude higher than in the 2101 alloy. The G-phase precipitates have an additional deleterious effect on the thermal embrittlement, as evaluated by the Ashby-Orowan equation, which explains the discrepancy between the hardness and the rate of phase separation with respect to annealing time (Gladman T 1999 Mater. Sci. Tech. Ser. 15 30-36). ).

  5. Corrosion sensitization behavior and mechanical properties of liquid-nitrogen-deformed austenitic 304 stainless steel

    Science.gov (United States)

    Maldonado, Julio Gerardo

    Plastic deformation of 304 stainless steel at liquid nitrogen temperature ({-}196sp°C) produces an almost complete transformation to strain-induced alphasp'/-martensite which provides the necessary conditions for a pseudo-recrystallization of the microstructure. This "so-called" pseudo-recrystallization results directly from the martensitic reversion (i.e. martensite to austenite reverse transformation) upon the application of heat treatment within the sensitization temperature range. The very fine duplex (alpha/gamma) microstructure which results (after heat treatment-0.1h-670sp°C) is also accompanied by a very extensive and homogeneous precipitation of chromium-rich carbides. The concomitant pseudo-recrystallization and precipitation processes not only have a profound positive effect on the sensitization behavior, but also affect the mechanical properties of the material. This suggests that 304 stainless steel could be thermo-mechanically treated, to in essence, heal itself and simultaneously produce an extremely fine (≈0.1mum) duplex grain structure with intermixed carbides to form a very high strength product. This might have important practical implications since 304 stainless steel is the material of choice in many engineering applications. Electrochemical testing, transmission electron microscopy, scanning electron microscopy, optical microscopy, neutron diffraction, X-ray diffraction, and mechanical testing were some of the techniques employed in this work.

  6. Ultrasound treatment of centrifugally atomized 316 stainless steel powders

    Science.gov (United States)

    Rawers, James C.; McCune, Robert A.; Dunning, John S.

    1991-12-01

    The Bureau of Mines is studying the surface characteristics of rapidly solidified powders and the potential for surface modification of fine powders prior to consolidation. The surface modification and work hardening of fine powders were accomplished by applying high-energy ultrasound to centrifugally atomized austenitic 316 stainless steel powders suspended in liquid media. Cavitation implosion changed the surface morphology, hammering the surface and occasionally fretting off microchips of work-hardened metal. Ultrasound-cavitation work-hardened metal powder surfaces producing a strained, duplex austenite face-centered cubic (fcc)-martensite body-centered tetragonal (bct) phase structure. The amount of work hardening depended upon the quantity of ultrasound energy used, considering both power level and experimental time. Work hardening was relatively independent of the liquid media used.

  7. Wear resistance and corrosion resistance of VCp particle reinforced stainless steel composites

    Institute of Scientific and Technical Information of China (English)

    YAO Xiu-rong; HAN Jie-cai; ZUO Hong-bo; LIU Zhao-jing; LI Feng-zhen; REN Shan-zhi

    2005-01-01

    The VCp reinforced stainless steel composite was produced by in-situ reaction casting. The composite was tested for its wear resistance under the wet abrasive condition and corrosion resistance, compared with the wear-resistant white iron and stainless steel. The results show that the wear resistance of the composite is slightly inferior to that of the white iron, but much better than that of the stainless steel under the wet grinding abrasive condition. The corrosion resistance of the composite is much better than that of the white iron in the acid medium,and a little worse than that of the stainless steel. Thus the composite exhibits superior properties of wear resistance and corrosion resistance.

  8. Properties, weldability and corrosion behavior of supermartensitic stainless steels for on- and offshore applications

    Energy Technology Data Exchange (ETDEWEB)

    Taban, Emel; Kaluc, Erdinc; Ojo, Olatunji Oladimeji [Kocaeli Univ. (Turkey). Welding Research, Education and Training Center

    2016-08-01

    Stimulated material-environment interactions inside and around flowlines of deep or ultra deep wells during oil and gas exploration, and fabrication economy of pipelines have been the major challenges facing the oil and gas industries. Presumably, an extensive focus on high integrity, performance and material economy of flowlines have realistically made supermartensitic stainless steels (SMSS) efficient and effective material choices for fabricating onshore and offshore pipelines. Supermartensitic stainless steels exhibit high strength, good low temperature toughness, sufficient corrosion resistance in sweet and mildly sour environments, and good quality weldability with both conventional welding processes and modern welding methods such as laser beam welding, electron beam welding and hybrid welding approaches. In terms of economy, supermartensitic stainless steels are cheaper and they are major replacements for more expensive duplex stainless steels required for tubing applications in the oil and gas industry. However, weld areas of SMSS pipes are exposed to sulphide stress cracking (SSC), so intergranular stress corrosion cracking (IGSCC) or stress corrosion cracking can occur. In order to circumvent this risk of cracking, a post-weld heat treatment (PWHT) for 5 minutes at about 650 C is recommended. This paper provides detailed literature perusal on supermartensitic stainless steels, their weldability and corrosion behaviors. It also highlights a major research area that has not been thoroughly expounded in literature; fatigue loading behaviors of welded SMSS under different corrosive environments have not been thoroughly detailed in literature.

  9. Buffer management in wireless full-duplex systems

    KAUST Repository

    Bouacida, Nader

    2015-10-19

    Wireless full-duplex radios can simultaneously transmit and receive using the same frequency. In theory, this can double the throughput. In fact, there is only little work addressing aspects other than throughput gains in full-duplex systems. Over-buffering in today\\'s networks or the so-called “bufferbloat” phenomenon creates excessive end-to-end delays resulting in network performance degradation. Our analysis shows that full-duplex systems may suffer from high latency caused by bloated buffers. In this paper, we address the problem of buffer management in full-duplex networks by using Wireless Queue Management (WQM), which is an active queue management technique for wireless networks. Our solution is based on Relay Full-Duplex MAC (RFD-MAC), an asynchronous media access control protocol designed for relay full-duplexing. We compare the performance of WQM in full-duplex environment to Drop Tail mechanism over various scenarios. Our solution reduces the end-to-end delay by two orders of magnitude while achieving similar throughput in most of the cases.

  10. Kinetics and thermodynamics of DNA, RNA, and hybrid duplex formation.

    Science.gov (United States)

    Rauzan, Brittany; McMichael, Elizabeth; Cave, Rachel; Sevcik, Lesley R; Ostrosky, Kara; Whitman, Elisabeth; Stegemann, Rachel; Sinclair, Audra L; Serra, Martin J; Deckert, Alice A

    2013-02-05

    The rates of duplex formation for two octamers of DNA (5' d-CACGGCTC/5' d-GAGCCGTG and 5' d-CACAGCAC/5' d-GTGCTGTG), the homologous RNA, and both sets of hybrids in 1 M NaCl buffer have been measured using stopped-flow spectroscopy. In addition, the thermodynamic parameters, ΔH° and ΔS°, have been determined for the same sequences under the same buffer conditions using optical melting techniques. These data reveal a linear free energy relationship between the free energy of activation for denaturation and the change in free energy for formation of the duplexes. This relationship indicates that these duplex formation reactions occur through a common unstructured transition state that is more similar to the single strands in solution than to the ensuing duplex. In addition, these data confirm that the greater stability of RNA duplexes relative to that of homologous DNA and hybrid duplexes is controlled by the denaturation rate and not the duplex formation rate.

  11. Duplex ultrasound for identifying renal artery stenosis

    DEFF Research Database (Denmark)

    Zachrisson, Karin; Herlitz, Hans; Lönn, Lars

    2017-01-01

    Background Renal artery duplex ultrasound (RADUS) is an established method for diagnosis of renal artery stenosis (RAS), but there is no consensus regarding optimal RADUS criteria. Purpose To define optimal cutoff values for RADUS parameters when screening for RAS using intra-arterial trans...... as PGM ≥15 mmHg and was found in 43 of the 76 arteries. RADUS parameters included renal artery peak systolic velocity (PSV) and the renal-aortic ratio (RAR) of flow velocities. Receiver operating characteristic curves (ROCs) and Youden's index were used to calculate optimal RADUS criteria for RAS...... The RAR ≥2.6 is a more sensitive criterion than traditional RADUS criteria when screening patients with clinical suspicion of RAS....

  12. Analysing Self Interference Cancellation in Full Duplex Radios

    DEFF Research Database (Denmark)

    Mahmood, Nurul Huda; Shafique Ansari, Imran; Berardinelli, Gilberto;

    2016-01-01

    Full duplex communication promises a theoretical $100\\%$ throughput gain by doubling the number of simultaneous transmissions. Such compelling gains are conditioned on perfect cancellation of the self interference power resulting from simultaneous transmission and reception. Generally, self...... cancellation. In this study, we derive an analytical model for the residual self interference power, and demonstrate various applications of the derived model in analysing the performance of a Full Duplex radio. In general, full duplex communication is found to provide only modest throughput gains over half...

  13. Glovebox Advanced Casting System Casting Optimization

    Energy Technology Data Exchange (ETDEWEB)

    Fielding, Randall Sidney [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-03-01

    Casting optimization in the GACS included three broad areas; casting of U-10Zr pins, incorporation of an integral FCCI barrier, and development of a permanent crucible coating. U-10Zr casting was improved over last year’s results by modifying the crucible design to minimize contact with the colder mold. Through these modifications casting of a three pin batch was successful. Incorporation of an integral FCCI barrier also was optimized through furnace chamber pressure changes during the casting cycle to reduce gas pressures in the mold cavities which led to three full length pins being cast which incorporated FCCI barriers of three different thicknesses. Permanent crucible coatings were tested against a base case; 1500°C for 10 minutes in a U-20Pu-10Zr molten alloy. None of the candidate coating materials showed evidence of failure upon initial visual examination. In all areas of work a large amount of characterization will be needed to fully determine the effects of the optimization activities. The characterization activities and future work will occur next year.

  14. High integrity automotive castings

    Energy Technology Data Exchange (ETDEWEB)

    Weiss, D. [Eck Industries Inc., St. Manitowoc, WI (United States)

    2007-07-01

    This paper described the High Integrity Magnesium Automotive Casting (HI-MAC) program, which was developed to ensure the widespread adoption of magnesium in structural castings. The program will encourage the use of low pressure permanent molds, squeeze casting, and electromagnetic pumping of magnesium into dies. The HI-MAC program is currently investigating new heat treatment methods, and is in the process of creating improved fluid flow and solidification modelling to produce high volume automotive components. In order to address key technology barriers, the program has been divided into 8 tasks: (1) squeeze casting process development; (2) low pressure casting technology; (3) thermal treatment; (4) microstructure control; (5) computer modelling and properties; (6) controlled molten metal transfer and filling; (7) emerging casting technologies; and (8) technology transfer throughout the automotive value chain. Technical challenges were outlined for each of the tasks. 1 ref., 3 tabs., 5 figs.

  15. Structure change of 430 stainless steel in the heating process

    Institute of Scientific and Technical Information of China (English)

    Xinzhong Liu; Jingtao Han; Wanhua Yu; Shifeng Dai

    2008-01-01

    The microstructure analysis was employed for the ferritic stainless steel (SUS430) with the carbon content from 0.029wt% to 0.100wt% under the simulated heating process condition. The higher carbon sample (430H) contains the duplex phase micro-structure at the temperature of 1150℃; on the other hand, the lower carbon content sample (430L) does not touch two phase area even at the temperature of 1450℃ and has the single phase ferritic microstrucmre. The carbon content need be well controlled for the 430 ferritic stainless steel since it can significandy affect the heating process curve, and the heating process may not be done in the two phase area due to the uncontrolled carbon content. With the low carbon content and the proper soaking time, the grain size is not sensitive to the heating process temperature and the soaking time. In the present heat treatment experiments, the soaking time is about 10 rain, and the processing parameters can be chosen according to the requ'trernent of the gross energy, the efficiency and the continual forming.

  16. Salt spray corrosion behaviour of austenitic stainless steel matrix composites

    Energy Technology Data Exchange (ETDEWEB)

    Velasco, F.; Abenojar, J.; Torralba, J.M. [Dept. de Ciencia de Materiales e Ing. Metalurgica, Univ. Carlos III de Madrid, Leganes (Spain); Lima, W.M. [Univ. Estadual de Maringa, Maringa PR (Brazil); Marce, R.; Bas, J.A. [AMES S.A., Sant Vicenc dels Horts Barcelona (Spain)

    2001-07-01

    This work deals with the possibility of using intermetallics as addition to P/M stainless steel in order to try to sinter these steels in nitrogen-base atmospheres. 316L was chosen as stainless steel matrix, and two intermetallics (from Ti-Al and Cr-Al binary systems), with a sieve size of less than 80 {mu}m, were added in the amount of 3% vol. to obtain MMCs. Powders were mixed, compacted at 700 MPa by uniaxial compacting, and then sintered at two temperatures (1120 and 1230 C) in five different atmospheres (95N{sub 2}/5H{sub 2}, 80N{sub 2}/20H{sub 2}, 25N{sub 2}/75H{sub 2}, hydrogen and vacuum). A complete microstructural study was carried out both by optical and scanning electron microscopy (SEM). Corrosion tests by salt spray fog were done in order to measure the possible improvements of intermetallic addition on the corrosion behaviour of these steels. SEM studies were also carried out on as corroded samples in order to understand the mechanisms of corrosion. Intermetallics absorb nitrogen from the nitrogen based atmospheres, and they develop a duplex (ferrite / austenite) microstructure when composite materials are sintered in hydrogen and vacuum. These microstructural features explain the results obtained in salt spray fog test. (orig.)

  17. Evolution of halictine castes

    Science.gov (United States)

    Knerer, Gerd

    1980-03-01

    Social halictine bees have female castes that range from species with no size differences to those with a discrete bimodality. Female caste differences are inversely correlated with the number of males produced in the first brood. It is proposed that the sexual dimorphism of solitary forms is being usurped by the female caste system of species in the process of turning social. Thus, caste differences and summer male suppression are greatest in the social species originating from solitary precursors with distinct sexual dimorphism, and are least in species evolving from solitary ancestors with a continuous sexual polymorphism.

  18. Caste in Itself, Caste and Class, or Caste in Class

    OpenAIRE

    Ramkrishna Mukherjee

    2015-01-01

    After the British conquered Bengal and eventually the whole of India,they set out to administer the colony. In this context they encountered two phenomena with which they were not familiar: (1) the relation of people to land for production (and not for revenue receiving, household living, etc.), and (2) the caste system of India, viz. the jati strati?cation of society.

  19. Effect of Contact Time Between Silicone Impression Materials and Stone on Dimensional Stability of Resultant Cast

    Directory of Open Access Journals (Sweden)

    Heidari

    2013-06-01

    Full Text Available Background Numerous factors have an effect on the accuracy of an impression and resultant cast, and these include: impression material, impression technique, tray selection, impression disinfection, storage time of impression before pouring, stone type used for fabrication of cast. Up to now, there has been little research conducted on the effect of contact time of a cast with an impression, on the dimensional stability of a cast. Objectives The purpose of this study was to evaluate the effect of the contact time of silicone impression materials with stone casts, on the dimensional stability of resultant casts. Materials and Methods A total of 44 impressions were made from a stainless steel master model, with each one of two silicone impression materials (Elite HD+ and Speedex, and poured with Elite Master Type IV. The thickness of the light-body material (1 mm was provided by using four copings. The resulting casts from each material were placed in four groups(n = 11 after each contact time with the impression (1 hour, 24 hours, 48 hours, 1 week. Distance between anterior and posterior abutments was measured for the casts and master model. Data were analyzed by two-way analysis of variance and a Tukey test. Results The relationship between the dimensional stability of the casts and the simultaneous effect of the impression material and contact time of the cast with the impression was not statistically significant (P = 0.099. Type of impression material on the dimensional stability of the cast had no significant effect (P = 0.163. Increased contact time of the cast with the impression resulted in increased dimensional change (P < 0.001. Conclusions Dimensional stability of the casts after different contact time with the impression was acceptable. The best time to separate the cast from the impression was one hour after pouring the impression.

  20. A cast orientation index.

    Science.gov (United States)

    Ivanhoe, J R; Mahanna, G K

    1994-12-01

    This article describes a technique that allows multiple master casts to be precisely oriented to the same path of insertion and withdrawal. This technique is useful in situations where multiple fixed prosthodontic preparations require surveyed restorations and a single master cast is not available.

  1. Higher Education's Caste System

    Science.gov (United States)

    Iannone, Ron

    2004-01-01

    In this article, the author discusses the history of the present caste system in higher education. He shows how the public's perception of this caste system is based on image and not usually on the quality of teaching and curriculum in colleges and universities. Finally, he discusses a model for accessibility to higher education and how higher…

  2. Caste and power

    DEFF Research Database (Denmark)

    Roy, Dayabati

    2011-01-01

    This paper explores the institution of caste and its operation in a micro-level village setting of West Bengal, an Indian state, where state politics at grass roots level is vibrant with functioning local self-government and entrenched political parties. This ethnographic study reveals that caste...

  3. Multi-layers castings

    Directory of Open Access Journals (Sweden)

    J. Szajnar

    2010-01-01

    Full Text Available In paper is presented the possibility of making of multi-layers cast steel castings in result of connection of casting and welding coating technologies. First layer was composite surface layer on the basis of Fe-Cr-C alloy, which was put directly in founding process of cast carbon steel 200–450 with use of preparation of mould cavity method. Second layer were padding welds, which were put with use of TIG – Tungsten Inert Gas surfacing by welding technology with filler on Ni matrix, Ni and Co matrix with wolfram carbides WC and on the basis on Fe-Cr-C alloy, which has the same chemical composition with alloy, which was used for making of composite surface layer. Usability for industrial applications of surface layers of castings were estimated by criterion of hardness and abrasive wear resistance of type metal-mineral.

  4. Dissolution of alpha-prime precipitates in thermally embrittled S2205-duplex steels during reversion-heat treatment

    Directory of Open Access Journals (Sweden)

    V. Shamanth

    2015-01-01

    Full Text Available Duplex stainless steels offer an attractive combination of strength, corrosion resistance and cost. In annealed condition duplex steels will be in thermodynamically metastable condition but when they are subjected to intermediate homologous temperature of ∼475 °C and below significant embrittlement occurs, which is one of the key material degradation properties that limits its upper service temperature in many applications. Hence the present study is aimed to study the effect of reversion heat treatment and its time on mechanical properties of the thermally embrittled steel. The results showed that 60 min reversion heat treated samples were able to recover the mechanical properties which were very close to annealed properties because when the embrittled samples were reversion heat treated at an elevated temperature of 550 °C which is above the (α + α′ miscibility gap, the ferritic phase was homogenized again. In other words, Fe-rich α and Cr-rich α′ prime precipitates which were formed during ageing become thermodynamically unstable and dissolve inside the ferritic phase.

  5. Weld bonding of stainless steel

    DEFF Research Database (Denmark)

    Santos, I. O.; Zhang, Wenqi; Goncalves, V.M.

    2004-01-01

    This paper presents a comprehensive theoretical and experimental investigation of the weld bonding process with the purpose of evaluating its relative performance in case of joining stainless steel parts, against alternative solutions based on structural adhesives or conventional spot...

  6. The ancient Chinese casting techniques

    Directory of Open Access Journals (Sweden)

    Tan Derui

    2011-02-01

    Full Text Available In the course of Chinese civilization, which lasted more than 5,000 years, casting production has made a huge contribution. In this paper, some representative metal castings were presented. According to their forming techniques, they can be grouped into stone mould casting, clay mould casting, ablation casting, lost wax casting, stack casting, permanent mould casting, sand casting, etc. According to their materials, they can be categorized into tin bronze, bimetallic bronze, malleable cast iron, ductile cast iron, brass, cupronickel alloy (Packtong, etc. According to their surface decorative techniques they can be devided into gem inlay, gilding, gold and silver inlay, copper inlay, engraved decoration, surface tin-enrichment, mother-of-pearl inlay, burnished works with gold or silver inlay, surface coloring and cloisonné enamel, etc.

  7. Caste in Itself, Caste and Class, or Caste in Class

    Directory of Open Access Journals (Sweden)

    Ramkrishna Mukherjee

    2015-08-01

    Full Text Available After the British conquered Bengal and eventually the whole of India,they set out to administer the colony. In this context they encountered two phenomena with which they were not familiar: (1 the relation of people to land for production (and not for revenue receiving, household living, etc., and (2 the caste system of India, viz. the jati strati?cation of society.

  8. Clean Metal Casting

    Energy Technology Data Exchange (ETDEWEB)

    Makhlouf M. Makhlouf; Diran Apelian

    2002-02-05

    The objective of this project is to develop a technology for clean metal processing that is capable of consistently providing a metal cleanliness level that is fit for a given application. The program has five tasks: Development of melt cleanliness assessment technology, development of melt contamination avoidance technology, development of high temperature phase separation technology, establishment of a correlation between the level of melt cleanliness and as cast mechanical properties, and transfer of technology to the industrial sector. Within the context of the first task, WPI has developed a standardized Reduced Pressure Test that has been endorsed by AFS as a recommended practice. In addition, within the context of task1, WPI has developed a melt cleanliness sensor based on the principles of electromagnetic separation. An industrial partner is commercializing the sensor. Within the context of the second task, WPI has developed environmentally friendly fluxes that do not contain fluorine. Within the context of the third task, WPI modeled the process of rotary degassing and verified the model predictions with experimental data. This model may be used to optimize the performance of industrial rotary degassers. Within the context of the fourth task, WPI has correlated the level of melt cleanliness at various foundries, including a sand casting foundry, a permanent mold casting foundry, and a die casting foundry, to the casting process and the resultant mechanical properties. This is useful in tailoring the melt cleansing operations at foundries to the particular casting process and the desired properties of cast components.

  9. Through process numerical simulation of a heavy hydro turbine blade casting

    Science.gov (United States)

    Kang, J. W.; Wang, T. J.; Y Huang, T.; Liu, B. C.

    2012-07-01

    Heavy Hydro turbine castings, made of martensitic stainless steel, of spatially twisted shape, are susceptible to deformation during both casting and heat treatment processes. During production, uneven heating and cooling, phase transformation, stress and stain are responsible for the deformation of castings. However, the current research most focus on casting process or heat treatment process or both but separately, martensitic phase transformation is usually neglected in casting process. In this paper, a coupled thermo-martensitic phase transformation-stress model is established. And it is implemented by secondary development of ABAQUS, which deals the finite element model change and incorporates multi thermal and mechanical boundaries during casting and heat treatment processes as well, such as the contact pair between casting and mold during casting process. The stress analysis of a heavy hydro blade casting was performed by this system. The stress, displacement and phase are obtained. The effect of martensitic phase transformation on the stress and deformation is discussed. The simulated deformation is compared with measured results, and their agreement is improved by the through process simulation.

  10. Symptomatic stent cast.

    LENUS (Irish Health Repository)

    Keohane, John

    2012-02-03

    Biliary stent occlusion is a major complication of endoscopic stent insertion and results in repeat procedures. Various theories as to the etiology have been proposed, the most frequently studied is the attachment of gram negative bacteria within the stent. Several studies have shown prolongation of stent patency with antibiotic prophylaxis. We report the case of stent occlusion from a cast of a previously inserted straight biliary stent; a "stent cast" in an 86-year-old woman with obstructive jaundice. This was retrieved with the lithotrypter and she made an uneventful recovery. This is the first reported case of a biliary stent cast.

  11. Symptomatic stent cast.

    Science.gov (United States)

    Keohane, John; Moore, Michael; O'Mahony, Seamus; Crosbie, Orla

    2008-02-01

    Biliary stent occlusion is a major complication of endoscopic stent insertion and results in repeat procedures. Various theories as to the etiology have been proposed, the most frequently studied is the attachment of gram negative bacteria within the stent. Several studies have shown prolongation of stent patency with antibiotic prophylaxis. We report the case of stent occlusion from a cast of a previously inserted straight biliary stent; a "stent cast" in an 86-year-old woman with obstructive jaundice. This was retrieved with the lithotrypter and she made an uneventful recovery. This is the first reported case of a biliary stent cast.

  12. CENTRIFUGAL CASTING MACHINE

    Science.gov (United States)

    Shuck, A.B.

    1958-04-01

    A device is described that is specifically designed to cast uraniumn fuel rods in a vacuunn, in order to obtain flawless, nonoxidized castings which subsequently require a maximum of machining or wastage of the expensive processed material. A chamber surrounded with heating elements is connected to the molds, and the entire apparatus is housed in an airtight container. A charge of uranium is placed in the chamber, heated, then is allowed to flow into the molds While being rotated. Water circulating through passages in the molds chills the casting to form a fine grained fuel rod in nearly finished form.

  13. Bainite obtaining in cast iron with carbides castings

    Directory of Open Access Journals (Sweden)

    S. Pietrowski

    2010-01-01

    Full Text Available In these paper the possibility of upper and lower bainite obtaining in cast iron with carbides castings are presented. Conditions, when in cast iron with carbides castings during continuous free air cooling austenite transformation to upper bainite or its mixture with lower bainte proceeds, have been given. A mechanism of this transformation has been given, Si, Ni, Mn and Mo distribution in the eutectic cell has been tested and hardness of tested castings has been determined.

  14. Defined presentation of carbohydrates on a duplex DNA scaffold.

    Science.gov (United States)

    Schlegel, Mark K; Hütter, Julia; Eriksson, Magdalena; Lepenies, Bernd; Seeberger, Peter H

    2011-12-16

    A new method for the spatially defined alignment of carbohydrates on a duplex DNA scaffold is presented. The use of an N-hydroxysuccinimide (NHS)-ester phosphoramidite along with carbohydrates containing an alkylamine linker allows for on-column labeling during solid-phase oligonucleotide synthesis. This modification method during solid-phase synthesis only requires the use of minimal amounts of complex carbohydrates. The covalently attached carbohydrates are presented in the major groove of the B-form duplex DNA as potential substrates for murine type II C-type lectin receptors mMGL1 and mMGL2. CD spectroscopy and thermal melting revealed only minimal disturbance of the overall helical structure. Surface plasmon resonance and cellular uptake studies with bone-marrow-derived dendritic cells were used to assess the capability of these carbohydrate-modified duplexes to bind to mMGL receptors.

  15. Sarcomatoid carcinoma of the renal pelvis in duplex kidney

    Institute of Scientific and Technical Information of China (English)

    CHEN Ge-ming; CHEN Shan-wen; XIA Dan; LI Jun; YAN Sheng; JIN Bai-ye

    2011-01-01

    Sarcomatoid transitional cell carcinoma of the renal pelvis is a rare neoplasm with only 14 well-illustrated examples reported previously. Duplex kidney is the most common congenital abnormality of the urinary tract, with an incidence of around 2%. Neoplasia of the renal pelvis in duplex kidney is rare. We reported a case whose sarcomatoid carcinoma originated from the upper portion of the duplicated renal pelvis with hydronephrosis, and total nephroureterectomy with bladder cuff excision surgery of both renal units was carried out. Because of the rare nature of renal pelvic sarcomatoid carcinoma and its apparent lack of response to adjuvant therapy, it is essential to do early diagnosis and early radical surgery to improve survival. It is important to stress the need for frequent and diligent monitoring or treating complex duplex kidney with hydronephrosis of either moiety in case of a risk of having neoplasias.

  16. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2011-01-01

    White Cast Iron (Ⅰ) White cast iron or ‘white iron' refers to the type of cast iron in which all of the carbon exists as carbide;there is no graphite in the as-cast structure and the fractured surface shows a white colour.White cast iron can be divided in three classes:· Normal white cast iron — this iron contains only C,Si,Mn,P and S,with no other alloying elements.· Low-alloy white cast iron — the total mass fraction of alloying elements is less than 5%.

  17. Brazing of stainless steel; Stainless ko no rozuke

    Energy Technology Data Exchange (ETDEWEB)

    Matsu, T.

    1996-04-01

    This paper explains brazing of stainless steel as to its processing materials, brazing materials, brazing methods, and brazing works. When performing brazing at higher than 800{degree}C on a martensite-based stainless steel represented by the 13Cr steel, attention is required on cracking caused by quenching. When a ferrite-based stainless steel represented by the 18Cr steel is heated above 900{degree}C, crystalline particles grow coarser, causing their tenacity and corrosion resistance to decline. High-temperature long-time heating in brazing in a furnace demands cautions. Austenite-based stainless steel represented by the 18Cr-8Ni steel has the best brazing performance. However, since the steel has large thermal expansion coefficient and low thermal conductivity, attention is required on strain and deformation due to heating, and on localized overheating. Deposition hardened stainless steel made of the Cr-Ni alloy steel added with aluminum and titanium has poor wettability in a brazing work, hence pretreatment is required for the purpose of activation. 9 figs., 7 tabs.

  18. Highly porous, low elastic modulus 316L stainless steel scaffold prepared by selective laser melting.

    Science.gov (United States)

    Čapek, Jaroslav; Machová, Markéta; Fousová, Michaela; Kubásek, Jiří; Vojtěch, Dalibor; Fojt, Jaroslav; Jablonská, Eva; Lipov, Jan; Ruml, Tomáš

    2016-12-01

    Recently, porous metallic materials have been extensively studied as candidates for use in the fabrication of scaffolds and augmentations to repair trabecular bone defects, e.g. in surroundings of joint replacements. Fabricating these complex structures by using common approaches (e.g., casting and machining) is very challenging. Therefore, rapid prototyping techniques, such as selective laser melting (SLM), have been investigated for these applications. In this study, we characterized a highly porous (87 vol.%) 316L stainless steel scaffold prepared by SLM. 316L steel was chosen because it presents a biomaterial still widely used for fabrication of joint replacements and, from the practical point of view, use of the same material for fabrication of an augmentation and a joint replacement is beneficial for corrosion prevention. The results are compared to the reported properties of two representative nonporous 316L stainless steels prepared either by SLM or casting and subsequent hot forging. The microstructural and mechanical properties and the surface chemical composition and interaction with the cells were investigated. The studied material exhibited mechanical properties that were similar to those of trabecular bone (compressive modulus of elasticity ~0.15GPa, compressive yield strength ~3MPa) and cytocompatibility after one day that was similar to that of wrought 316L stainless steel, which is a commonly used biomaterial. Based on the obtained results, SLM is a suitable method for the fabrication of porous 316L stainless steel scaffolds with highly porous structures.

  19. Comparison of simulated and measured quantities of a duplex reactor

    Energy Technology Data Exchange (ETDEWEB)

    Koskela, M.; Kajava, M. [ABB Marine, Helsinki (Finland)

    1997-12-31

    The purpose of this article is to illustrate the use of an analog simulator as a design tool when designing new power electric equipment. The purpose of simulation is to predict the functionality of electrical equipment to be constructed. Duplex reactor is an electromagnetic device designed to reduce voltage harmonics and short circuit currents in the ship electrical network. In this report a comparison between simulated and measured electrical quantities of a duplex reactor has been made. The purpose of the measurements was to show the correct functioning of the reactor. The simulation results and the measured waveforms corresponds well to each other. (orig.) 4 refs.

  20. 锻件

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Effect of Sc Alloying Additions on Structure and Mechanical Properties of PM and Cast High-Strength Al dAlloys of same composition ; Effects of copper on precipitation of secondary phases in duplex stainless steels; Effects of thermocapillary forces during welding of 316L-type wrought, cast and powder metallurgy austenitic stainless steels; ELECTROSPARK DEPOSITED COATING TECHNOLOGY FOR NAVAL APPLICATIONS

  1. On the Potential of Full Duplex Performance in 5G Ultra-Dense Small Cell Networks

    DEFF Research Database (Denmark)

    Gatnau, Marta; Fleischer, Marko; Berardinelli, Gilberto;

    2016-01-01

    Full duplex allows a device to transmit and receive simultaneously in the same frequency band, theoretically doubling the throughput compared to traditional half duplex systems. However, several limitations restrict the promised full duplex gain: non-ideal self-interference cancellation, increase...

  2. Breaking the Transmitter-Receiver Isolation Barrier in Mobile Handsets with Spatial Duplexing

    DEFF Research Database (Denmark)

    Alrabadi, Osama; Tatomirescu, Alexandru; Knudsen, Mikael;

    2013-01-01

    In full-duplex radio communication systems like eUTRAN, CDMA-2000, the radio transmitter (Tx) is active at the same time as the radio receiver (Rx). The Tx and the Rx will be using separate dedicated frequency bands and the Tx-Rx isolation is ensured by duplex filters. However, agile duplexers req...

  3. Analysis of full-duplex relay networks with opportunistic scheduling

    Directory of Open Access Journals (Sweden)

    Lei Shao

    2015-05-01

    Full Text Available This Letter addresses a two-hop decode-and-forward relay system with full-duplex relaying and opportunistic scheduling. Exact expressions for outage probability, average capacity and symbol error rate are presented in an independent identically distributed Rayleigh fading environment. Numerical and simulated results show the validity of the analytical results.

  4. Increased Y-chromosome detection by SRY duplexing

    DEFF Research Database (Denmark)

    Hansen, Morten Høgh; Clausen, Frederik Banch; Dziegiel, Morten Hanefeld

    2012-01-01

    Determining fetal sex noninvasively is dependent of a robust assay. We designed a novel SRY assay and combined it with a SRY assay from literature forming a duplex assay with the same fluorescent dye to increase detection of Y-chromosome at low cell-free fetal DNA or chimeric DNA concentrations....

  5. Full-duplex MIMO system based on antenna cancellation technique

    DEFF Research Database (Denmark)

    Foroozanfard, Ehsan; Franek, Ondrej; Tatomirescu, Alexandru

    2014-01-01

    The performance of an antenna cancellation technique for a multiple-input– multiple-output (MIMO) full-duplex system that is based on null-steering beamforming and antenna polarization diversity is investigated. A practical implementation of a symmetric antenna topology comprising three dual-pola...

  6. Capacity of the Degraded Half-Duplex Relay Channel

    CERN Document Server

    Vijayakumaran, Saravanan; Lok, Tat M

    2007-01-01

    A discrete memoryless half-duplex relay channel is constructed from a broadcast channel from the source to the relay and destination and a multiple access channel from the source and relay to the destination. When the relay listens, the channel operates in the broadcast mode. The channel switches to the multiple access mode when the relay transmits. If the broadcast component channel is physically degraded, the half-duplex relay channel will also be referred to as physically degraded. The capacity of this degraded half-duplex relay channel is examined. It is shown that the block Markov coding suggested in the seminal paper by Cover and El Gamal can be modified to achieve capacity for the degraded half-duplex relay channel. In the code construction, the listen-transmit schedule of the relay is made to depend on the message to be sent and hence the schedule carries information itself. If the schedule is restricted to be deterministic, it is shown that the capacity can be achieved by a simple management of infor...

  7. Effect of Radiofrequency Radiation on DNA Duplex Stability and Replication.

    Science.gov (United States)

    1983-08-01

    R.W., J.B. Dodgson, I.F. Nes, and R.D. Wells. Duplex regions in single-stranded OX174 DNA are cleaved by a restriction endonuclease from Haemophilus ... aegyptius . J Biol Chem 252:7300-7306 (1977). *i Brown, R.F., S.V. Marshall, and C.W. Hughes. Effect of radiofrequency radi- ation (RFR) on excision

  8. Surface modification of investment cast-316L implants: microstructure effects.

    Science.gov (United States)

    El-Hadad, Shimaa; Khalifa, Waleed; Nofal, Adel

    2015-03-01

    Artificial femur stem of 316L stainless steel was fabricated by investment casting using vacuum induction melting. Different surface treatments: mechanical polishing, thermal oxidation and immersion in alkaline solution were applied. Thicker hydroxyapatite (HAP) layer was formed in the furnace-oxidized samples as compared to the mechanically polished ones. The alkaline treatment enhanced the precipitation of HAP on the samples. It was also observed that the HAP precipitation responded differently to the different phases of the microstructure. The austenite phase was observed to have more homogeneous and smoother layer of HAP. In addition, the growth of HAP was sometimes favored on the austenite phase rather than on ferrite phase.

  9. Effect of acidizing solutions on K{sub IEAC} of 13 Cr and 22 Cr stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    McCoy, T.H.; Mackey, S.T.; Walker, M.L. [Halliburton Energy Services, Duncan, OK (United States)

    1994-12-31

    Fracture mechanics environment-assisted cracking tests, using precracked TM0177-90 double cantilever beam (DCB) specimens, were performed on 13 Cr (UNS S42000) martensitic stainless steel and 22 Cr (UNS S31803) duplex stainless steel in stimulation acidizing solutions to simulate downhole conditions. The acidizing solutions used were 15% HCl and 12% HCl-3% HF with proprietary inhibitors. The 13 Cr material was quenched and double tempered to meet the mechanical property requirements of API Spec 5CT Grade L-80. The 22 Cr material was grade 130 (130 ksi minimum yield strength) cold reduced tubing. This paper shows that the low strength 13 Cr material is not very susceptible to crack propagation in acidizing solutions. The high strength 22 Cr material, however, did show susceptibility to crack propagation in the same acidizing solutions while no cracking occurred in NACE TM0177-90 sour brine solution.

  10. Surface-protein interactions on different stainless steel grades: effects of protein adsorption, surface changes and metal release.

    Science.gov (United States)

    Hedberg, Y; Wang, X; Hedberg, J; Lundin, M; Blomberg, E; Wallinder, I Odnevall

    2013-04-01

    Implantation using stainless steels (SS) is an example where an understanding of protein-induced metal release from SS is important when assessing potential toxicological risks. Here, the protein-induced metal release was investigated for austenitic (AISI 304, 310, and 316L), ferritic (AISI 430), and duplex (AISI 2205) grades in a phosphate buffered saline (PBS, pH 7.4) solution containing either bovine serum albumin (BSA) or lysozyme (LSZ). The results show that both BSA and LSZ induce a significant enrichment of chromium in the surface oxide of all stainless steel grades. Both proteins induced an enhanced extent of released iron, chromium, nickel and manganese, very significant in the case of BSA (up to 40-fold increase), whereas both proteins reduced the corrosion resistance of SS, with the reverse situation for iron metal (reduced corrosion rates and reduced metal release in the presence of proteins). A full monolayer coverage is necessary to induce the effects observed.

  11. DMT of Multi-hop Cooperative Networks - Part II: Half-Duplex Networks with Full-Duplex Performance

    CERN Document Server

    Sreeram, K; Kumar, P Vijay

    2008-01-01

    We consider single-source single-sink (ss-ss) multi-hop relay networks, with slow-fading links and single-antenna half-duplex relay nodes. In a companion paper, we established some basic results which laid the foundation for the results presented here. In the present paper, we consider two families of networks of half-duplex networks. KPP networks may be viewed as the union of K node-disjoint parallel relaying paths. Generalizations of these networks include KPP(I) networks, which permit interference between paths and KPP(D) networks, which possess a direct link between source and sink. We characterize the DMT of these families of networks completely and show that they can achieve the cut-set bound, thus proving that full-duplex performance can be obtained even in the presence of the half-duplex constraint. We then consider layered networks, and prove that a linear DMT between maximum diversity and maximum multiplexing gain is achievable. All protocols in this paper are explicit and use only amplify-and-forwa...

  12. Improving by postoxidation of corrosion resistance of plasma nitrocarburized AISI 316 stainless steels

    Science.gov (United States)

    Yenilmez, A.; Karakan, M.; Çelik, İ.

    2017-01-01

    Austenitic stainless steels are widely used in several industries such as chemistry, food, health and space due to their perfect corrosion resistance. However, in addition to corrosion resistance, the mechanic and tribological features such as wear resistance and friction are required to be good in the production and engineering of this type of machines, equipment and mechanic parts. In this study, ferritic (FNC) and austenitic (ANC) nitrocarburizing were applied on AISI 316 stainless steel specimens with perfect corrosion resistance in the plasma environment at the definite time (4 h) and constant gas mixture atmosphere. In order to recover corrosion resistance which was deteriorated after nitrocarburizing again, plasma postoxidation process (45 min) was applied. After the duplex treatment, the specimens' structural analyses with XRD and SEM methods, corrosion analysis with polarization method and surface hardness with microhardness method were examined. At the end of the studies, AISI 316 surface hardness of stainless steel increased with nitrocarburizing process, but the corrosion resistance was deteriorated with FNC (570 °C) and ANC (670 °C) nitrocarburizing. With the following of the postoxidation treatment, it was detected that the corrosion resistance became better and it approached its value before the process.

  13. Cracking kinetics of two-phase stainless steel alloys in hydrogen gas

    Science.gov (United States)

    Perng, T.-P.; Altstetter, C. J.

    1988-01-01

    The kinetics of hydrogen-induced slow crack growth (SCG) under constant load was studied in two stainless steel alloys containing mixtures of bcc and fcc phases. FERRALIUM 255, a duplex stainless steel, consisting of ˜50 pct austenite in a ferrite matrix, was tested in hydrogen gas at 0 to 100 °C with the loading axis both perpendicular and parallel to the rolling direction. In addition, specimens of AISI 301 were deformed in air in different ways to produce various amounts of bcc phase in an austenite matrix prior to testing in H2 gas at room temperature. The kinetics of subcritical slow crack growth (SCG) in these alloys was compared with that for austenitic and for ferritic stainless steels. The SCG rates were rationalized in terms of differences in hydrogen permeation in the two phases. The results confirm that a higher rate of supply and accumulation of hydrogen in the region ahead of the crack tip allows a higher cracking velocity.

  14. 纳米SiC粉体对铸造超低碳马氏体不锈钢耐磨蚀性能的影响%Effect of Nano-SiC Powders on Abrasion Properties of Ultra-Low Carbon Martensitic Stainless Cast Steel

    Institute of Scientific and Technical Information of China (English)

    杨军; 王鑫; 陈美玲; 高宏; 杨莉

    2011-01-01

    水轮机用铸造超低碳马氏体不锈钢遭受着泥砂冲刷和腐蚀的双重作用.在生产条件下将经过表面改性处理的纳米SiC粉体加入到铸造超低碳马氏体不锈钢中,分别在加与不加NaCl的两种水砂粒介质中进行磨蚀试验,研究纳米SiC粉体加入量对其耐磨蚀性能的影响.结果表明:纳米SiC粉体强化处理后马氏体不锈钢表现出优越的耐磨蚀性能,其材料失重形式主要为韧性断裂,当SiC加入量为0.1%时,在水砂粒和3.5%NaCl水砂粒中磨蚀率分别降低了90%和86%.%The turbine steel has to suffer the dual effects of sediment erosion and corrosion. The nano-SiC powders were poured into the melt for ultra-low carbon martensitic stainless steel, and the abrasion test was carried out in sand-water mixture with and without NaCI to study the effect of nano-SiC powder addition on corrosion resistant properties of the steel. The results show that the martensitic stainless steel strengthened by nano-SiC powders shows superior abrasion performance. When the addition of SiC powders is 0.1%, the erosion rates in the sand-water mixture with 3.5% NaCI and sand-water mixture without NaCI, decrease by 86% and 90%, respectively.

  15. Preformed posterior stainless steel crowns: an update.

    Science.gov (United States)

    Croll, T P

    1999-02-01

    For almost 50 years, dentists have used stainless steel crowns for primary and permanent posterior teeth. No other type of restoration offers the convenience, low cost, durability, and reliability of such crowns when interim full-coronal coverage is required. Preformed stainless steel crowns have improved over the years. Better luting cements have been developed and different methods of crown manipulation have evolved. This article reviews stainless steel crown procedures for primary and permanent posterior teeth. Step-by-step placement of a primary molar stainless steel crown is documented and permanent molar stainless steel crown restoration is described. A method for repairing a worn-through crown also is reviewed.

  16. Casting Characteristics of Aluminum Die Casting Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Makhlouf M. Makhlouf; Diran Apelian

    2002-02-05

    The research program investigates the casting characteristics of selected aluminum die casting alloys. Specifically, the alloys' tendencies towards die soldering and sludge formation, and the alloys' fluidity and machinability are evaluated. It was found that: When the Fe and Mn contents of the alloy are low; caution has to be taken against possible die soldering. When the alloy has a high sludge factor, particularly a high level of Fe, measures must be taken to prevent the formation of large hardspots. For this kind of alloy, the Fe content should be kept at its lowest allowable level and the Mn content should be at its highest possible level. If there are problems in die filling, measures other than changing the alloy chemistry need to be considered first. In terms of alloy chemistry, the elements that form high temperature compounds must be kept at their lowest allowable levels. The alloys should not have machining problems when appropriate machining techniques and machining parameters are used.

  17. Accuracy of Multiple Pour Cast from Various Elastomer Impression Methods.

    Science.gov (United States)

    Haralur, Satheesh B; Saad Toman, Majed; Ali Al-Shahrani, Abdullah; Ali Al-Qarni, Abdullah

    2016-01-01

    The accurate duplicate cast obtained from a single impression reduces the profession clinical time, patient inconvenience, and extra material cost. The stainless steel working cast model assembly consisting of two abutments and one pontic area was fabricated. Two sets of six each custom aluminum trays were fabricated, with five mm spacer and two mm spacer. The impression methods evaluated during the study were additional silicone putty reline (two steps), heavy-light body (one step), monophase (one step), and polyether (one step). Type IV gypsum casts were poured at the interval of one hour, 12 hours, 24 hours, and 48 hours. The resultant cast was measured with traveling microscope for the comparative dimensional accuracy. The data obtained were subjected to Analysis of Variance test at significance level impression techniques had the percentage of variation for the height -0.36 to -0.97%, while diameter was increased by 0.40-0.90%. The values for one-step heavy-light body impression dies, additional silicone monophase impressions, and polyether were -0.73 to -1.21%, -1.34%, and -1.46% for the height and 0.50-0.80%, 1.20%, and -1.30% for the width, respectively.

  18. Accuracy of Multiple Pour Cast from Various Elastomer Impression Methods

    Directory of Open Access Journals (Sweden)

    Satheesh B. Haralur

    2016-01-01

    Full Text Available The accurate duplicate cast obtained from a single impression reduces the profession clinical time, patient inconvenience, and extra material cost. The stainless steel working cast model assembly consisting of two abutments and one pontic area was fabricated. Two sets of six each custom aluminum trays were fabricated, with five mm spacer and two mm spacer. The impression methods evaluated during the study were additional silicone putty reline (two steps, heavy-light body (one step, monophase (one step, and polyether (one step. Type IV gypsum casts were poured at the interval of one hour, 12 hours, 24 hours, and 48 hours. The resultant cast was measured with traveling microscope for the comparative dimensional accuracy. The data obtained were subjected to Analysis of Variance test at significance level <0.05. The die obtained from two-step putty reline impression techniques had the percentage of variation for the height −0.36 to −0.97%, while diameter was increased by 0.40–0.90%. The values for one-step heavy-light body impression dies, additional silicone monophase impressions, and polyether were −0.73 to −1.21%, −1.34%, and −1.46% for the height and 0.50–0.80%, 1.20%, and −1.30% for the width, respectively.

  19. Preparation and Characterization of Plasma Cu Surface Modified Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    ZHANG Xiangyu; TANG Bin; FAN Ailan; MA Yong; TIAN Linhai

    2012-01-01

    Cu modified layer was prepared on the surface of AISI304 stainless steel by plasma surface alloying technique.The effects of processing parameters on the thickness,surface topography,microstructure and chemical composition of Cu modified layer were characterized using glow discharge optical emission spectroscopy (GDOES),scanning electron microscopy (SEM) and X-ray diffraction (XRD).The experimental results show that the surface modified layer is a duplex layer (deposited + diffused layer) with thickness of about 26 μm under the optimum process parameters.The modified layer is mainly composed of a mixture of Cu and expanded austenite phase.The ball-on-disk results show that the modified layer possesses low friction coefficients (0.25) and excellent wear resistance (wear volume 0.005× 109 μm3).The Cu modified layer is very effective in killing the bacteria S.aureus.Meanwhile,no viable S.aureus is found after 3 h (100% killed) by contact with the Cu alloyed surface.

  20. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Ph.D Liu Jincheng

    2010-01-01

    @@ Note: This book consists of five sections: Chapter 1 Introduction, Chapter 2 Grey Iron, Chapter 3 Spheroidal Graphite Cast Iron, Chapter 4 Vermicular Cast Iron, and Chapter 5 White Cast Iron. CHINA FOUNDRY publishes this book in several parts serially, starting from the first issue of 2009.

  1. Full-Duplex Communications in Large-Scale Cellular Networks

    KAUST Repository

    AlAmmouri, Ahmad

    2016-04-01

    In-band full-duplex (FD) communications have been optimistically promoted to improve the spectrum utilization and efficiency. However, the penetration of FD communications to the cellular networks domain is challenging due to the imposed uplink/downlink interference. This thesis presents a tractable framework, based on stochastic geometry, to study FD communications in multi-tier cellular networks. Particularly, we assess the FD communications effect on the network performance and quantify the associated gains. The study proves the vulnerability of the uplink to the downlink interference and shows that the improved FD rate gains harvested in the downlink (up to 97%) comes at the expense of a significant degradation in the uplink rate (up to 94%). Therefore, we propose a novel fine-grained duplexing scheme, denoted as α-duplex scheme, which allows a partial overlap between the uplink and the downlink frequency bands. We derive the required conditions to harvest rate gains from the α-duplex scheme and show its superiority to both the FD and half-duplex (HD) schemes. In particular, we show that the α-duplex scheme provides a simultaneous improvement of 28% for the downlink rate and 56% for the uplink rate. We also show that the amount of the overlap can be optimized based on the network design objective. Moreover, backward compatibility is an essential ingredient for the success of new technologies. In the context of in-band FD communication, FD base stations (BSs) should support HD users\\' equipment (UEs) without sacrificing the foreseen FD gains. The results show that FD-UEs are not necessarily required to harvest rate gains from FD-BSs. In particular, the results show that adding FD-UEs to FD-BSs offers a maximum of 5% rate gain over FD-BSs and HD-UEs case, which is a marginal gain compared to the burden required to implement FD transceivers at the UEs\\' side. To this end, we shed light on practical scenarios where HD-UEs operation with FD-BSs outperforms the

  2. Evaluation of an improved centrifugal casting machine.

    Science.gov (United States)

    Donovan, T E; White, L E

    1985-05-01

    A Type III gold alloy, a silver-palladium alloy, and a base metal alloy were cast in two different centrifugal casting machines. With the number of complete cast mesh squares as an indicator of castability, the Airspin casting machine produced superior castings with all three alloys. The base metal alloy produced the greatest number of complete squares with both casting machines.

  3. Thermal deformation behavior and microstructure of nuclear austenitic stainless steel

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Gleeble-1500D thermal simulation tester was employed in the hot-compression investigation of as-cast nuclear 304 austenitic stainless steel under conditions: deformation temperature 950―1200℃; deformations 30% and 50%; deformation rates 0.01 and 0.1 s?1. The results show that the flow stress decreases with temperature rise under the same strain rate and deformation, that the flow stress increases with deformation under the same temperature and strain rate, and that the flow stress increases with strain rate under the same temperature condition, i.e., work hardening becomes distinct. Materials exhibit better strength-toughness when the strain rate is 0.01 s-1, the deformation is 50%, and the temperature is 1050℃.

  4. Machine casting of ferrous alloys. Final report, 30 June 1976--30 June 1977

    Energy Technology Data Exchange (ETDEWEB)

    Flemings, M.C.; Young, K.P.; Boylan, J.F.; Bye, R.L.; Santor, M.L.

    1977-06-01

    During this year the basic Rheocasting system, which was fully operational at the beginning of the year, was improved in various ways to increase reliability and productivity. Specific improvements were the addition of a reducing gas in the melting chamber, a shield gas extension nozzle and graphite inserts at the bottom of the Rheocaster to eliminate 'hot spots'. Large quantities of 304 and 440C stainless steel alloys were cast during this period (approximately 800 pounds of 304 and 2000 pounds of 440C) and smaller quantities of other materials were also Rheocast including M2 tool steel, and HS 31 Cobalt base superalloy. Improvements in details and automation of the Thixocasting process were also made during this period. Work subsequently concentrated on casting large quantities of stainless steel into various die materials in order to determine die life and to optimize that die life.

  5. The casting of western sculpture during the XIXth century: sand casting versus lost wax casting

    NARCIS (Netherlands)

    Beentjes, T.P.C.

    2014-01-01

    This paper will discuss research into bronze casting techniques as practiced during the XIXth and early XXth century. Both natural sand casting (fonte au sable naturel) and lost wax casting (fonte à la cire perdue) were employed during this period and sometimes rivalled for commissions. Before the X

  6. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2010-01-01

    @@ Chapter 3 Spheroidal Graphite Cast Iron(I) Spheroidal Graphite Cast Iron, SG iron in short, refers to the cast iron in which graphite precipitates as spheroidal shape during solidification of liquid iron. The graphite in common commercial cast iron can only be changed from flake to spheroidal shape by spheroidising treatment. Since spheroidal graphite reduces the cutting effect of stress concentration, the metal matrix strength of SG iron can be applied around 70%-90%, thus the mechanical property of SG iron is significantly superior to other cast irons;even the tensile strength of SG iron is higher than that carbon steel.

  7. Smectic phase in suspensions of gapped DNA duplexes

    Science.gov (United States)

    Salamonczyk, Miroslaw; Zhang, Jing; Portale, Giuseppe; Zhu, Chenhui; Kentzinger, Emmanuel; Gleeson, James T.; Jakli, Antal; de Michele, Cristiano; Dhont, Jan K. G.; Sprunt, Samuel; Stiakakis, Emmanuel

    2016-11-01

    Smectic ordering in aqueous solutions of monodisperse stiff double-stranded DNA fragments is known not to occur, despite the fact that these systems exhibit both chiral nematic and columnar mesophases. Here, we show, unambiguously, that a smectic-A type of phase is formed by increasing the DNA's flexibility through the introduction of an unpaired single-stranded DNA spacer in the middle of each duplex. This is unusual for a lyotropic system, where flexibility typically destabilizes the smectic phase. We also report on simulations suggesting that the gapped duplexes (resembling chain-sticks) attain a folded conformation in the smectic layers, and argue that this layer structure, which we designate as smectic-fA phase, is thermodynamically stabilized by both entropic and energetic contributions to the system's free energy. Our results demonstrate that DNA as a building block offers an exquisitely tunable means to engineer a potentially rich assortment of lyotropic liquid crystals.

  8. Listen and talk full-duplex cognitive radio networks

    CERN Document Server

    Liao, Yun; Han, Zhu

    2016-01-01

    This brief focuses on the use of full-duplex radio in cognitive radio networks, presenting a novel spectrum sharing protocol that allows the secondary users to simultaneously sense and access the vacant spectrum. This protocol, called “Listen-and-talk” (LAT), is evaluated by both mathematical analysis and computer simulations in comparison with other existing protocols, including the listen-before-talk protocol. In addition to LAT-based signal processing and resource allocation, the brief discusses techniques such as spectrum sensing and dynamic spectrum access. The brief proposes LAT as a suitable access scheme for cognitive radio networks, which can support the quality-of-service requirements of these high priority applications. Fundamental theories and key techniques of cognitive radio networks are also covered. Listen and Talk: Full-duplex Cognitive Radio Networks is designed for researchers, developers, and professionals involved in cognitive radio networks. Advanced-level students studying signal pr...

  9. Herpes Zoster Duplex Unilateralis: Two Cases and Brief Literature Review

    Science.gov (United States)

    Son, Jee Hee; Chung, Bo Young; Kim, Hye One; Cho, Hee Jin

    2016-01-01

    Cases involving dermatomal herpes zoster in two or more locations are rare, especially in immunocompetent patients. When two noncontiguous dermatomes are involved, if affected unilaterally, it is called herpes zoster duplex unilateralis; if bilaterally, bilateralis. Here, we report two cases of herpes zoster duplex unilateralis. A 66-year-old man presented with painful erythematous grouped vesicles on his left scalp, forehead, trunk, and back (left [Lt.] V1, Lt. T8). Histologic findings were consistent with herpetic infection. A 33-year-old woman presented with painful erythematous grouped vesicles and crust on her left forehead and neck (Lt. V1, Lt. C5). Both patients were treated with oral administration of famcyclovir 750 mg/day for seven days. PMID:27904277

  10. Comments on process of duplex coatings on aluminum alloys

    Institute of Scientific and Technical Information of China (English)

    Samir H.A.; QIAN Han-cheng(钱翰城); XIA Bo-cai(夏伯才); WU Shi-ming(吴仕明)

    2004-01-01

    Despite the great achievements made in improvement of wear resistance properties of aluminum alloys,their applications in heavy surface load-bearing are limited. Single coating is insufficient to produce the desired combination of surface properties. These problems can be solved through the duplex coatings. The aim of the present study is to overview the research advances on processes of duplex coatings on aluminum alloys combined with micro plasma oxidation process and with other modern processes such as physical vapour deposition and plasma assisted chemical vapour deposition and also to evaluate the performance of micro plasma oxidation coatings in improving the load-bearing, friction and wear resistance properties of aluminum alloys in comparison with other coatings. Wherein, a more detailed presentation of the processes and their performances and disadvantages are given as well.

  11. A 2-order MIMO Full-Duplex Antenna System

    DEFF Research Database (Denmark)

    Tsakalaki, Elpiniki; Foroozanfard, Ehsan; De Carvalho, Elisabeth

    2014-01-01

    The paper presents an antenna system with combined full-duplex and 2-order multiple-input-multiple-output (MIMO) functionalities, i.e., a system capable of spatially multiplexing and spatially demultiplexing 2 datastreams in the same frequency and in the same time. By exploiting symmetries....... On the other hand, the 2 MIMO ports (either at the Tx or at the Rx) are sufficiently decoupled thanks to polarization diversity. The proposed antenna system exhibits a remarkable level of fullduplex isolation over a wide bandwidth while maintaining low coupling between its MIMO ports and can serve...... as a concrete implementation of an antenna system equipped with both MIMO as well as full-duplex capabilities....

  12. Internal adaptation of cast titanium crowns

    Directory of Open Access Journals (Sweden)

    Sicknan Soares da Rocha

    2007-08-01

    Full Text Available As the adaptation of titanium crowns obtained by Rematitan Plus investment, specific for titanium, is not recognized to be suitable, this study evaluated the effect of the concentration of the specific liquid and the temperature of the mold of investments on the internal misfit of crowns cast on commercially pure titanium. Individual dies of epoxy resin were obtained, representing teeth prepared for full-crown restoration with a 6-degree axial surface convergence angle and shoulder (1.0 mm. For the waxing of each crown, a ring-shaped stainless steel matrix (8.0mm internal diameter; 7.5 mm height was adapted above the individual dies of epoxy resin. The Rematian Plus investment was mixed according to the manufacturer's instructions using two different concentrations of the specific liquid: 100%, 75%. Casting was performed in a Discovery Plasma Ar-arc vacuum-pressure casting machine with molds at temperatures of 430ºC, 515ºC and 600ºC. The crowns were cleaned individually in a solution (1% HF + 13% HNO3 for 10 min using a ultrasonic cleaner, with no internal adaptations, and luted with zinc phosphate cement under a 5 kg static load. The crown and die assemblies were embedded in resin and sectioned longitudinally. The area occupied by cement was observed using stereoscopic lens (10X and measured by the Leica Qwin image analysis system (mm². The data for each experimental condition (n=8 were analyzed by Kruskal-Wallis non-parametric test (á=0.05. The results showed that liquid dilution and the increase in mold temperature did not significantly influence the levels of internal fit of the cast titanium crowns. The lowest means (±SD of internal misfit were obtained for the 430ºC/100%: (7.25 mm² ±1.59 and 600ºC/100% (8.8 mm² ±2.25 groups, which presented statistically similar levels of internal misfit.

  13. Cold Spray Repair of Martensitic Stainless Steel Components

    Science.gov (United States)

    Faccoli, M.; Cornacchia, G.; Maestrini, D.; Marconi, G. P.; Roberti, R.

    2014-12-01

    The possibility of using cold spray as repair technique of martensitic stainless steel components was evaluated through laboratory investigations. An austenitic stainless steel feedstock powder was chosen, instead of soft metals powders like nickel, copper, or aluminum, used for repairing components made in light alloy or cast iron. The present study directly compares the microstructure, the residual stresses, and the micro-hardness of repairs obtained by cold spray and by TIG welding, that is commonly used as repair technique in large steel components. XRD and optical metallographic analysis of the repairs showed that cold spray offers some advantages, inducing compressive residual stresses in the repair and avoiding alterations of the interface between repair and base material. For these reasons, a heat treatment after the cold spray repair is not required to restore the base material properties, whereas a post-weld heat treatment is needed after the welding repair. Cold spray repair also exhibits a higher micro-hardness than the welding repair. In addition, the cavitation erosion resistance of a cold spray coating was investigated through ultrasonic cavitation tests, and the samples worn surfaces were observed by scanning electron microscopy.

  14. Implementation of real-time duplex synthetic aperture ultrasonography

    DEFF Research Database (Denmark)

    Hemmsen, Martin Christian; Larsen, Lee; Kjeldsen, Thomas;

    2015-01-01

    This paper presents a real-time duplex synthetic aperture imaging system, implemented on a commercially available tablet. This includes real-time wireless reception of ultrasound signals and GPU processing for B-mode and Color Flow Imaging (CFM). The objective of the work is to investigate the im...... and that the required bandwidth between the probe and processing unit is within the current Wi-Fi standards....

  15. Evolution of microstresses in plastically deformed duplex steel

    Energy Technology Data Exchange (ETDEWEB)

    Baczmanski, A.; Wierzbanowski, K. [Akademia Gorniczo-Hutnicza, Krakow (Poland). WFTJ; Braham, C. [LMMM, URA-CNRS 1219, Ecole Nationale Superieure d' Arts et Metiers, Paris (France); Lodini, A. [IFTS, Univ. de Reims Charleville-Mezieres (France)

    2000-07-01

    The X-ray diffraction method has been applied to determine the internal stresses in two phases austeno-ferritic steel during uniaxial tensile test. The elasto-plastic deformation model was used to predict internal stresses and critical resolved shear stress for the both phases. The model calculations were successfully compared with the information obtained from the shift and broadening of diffraction peak. Finally, the parameters characterising elasto-plastic deformation for duplex steel were determined. (orig.)

  16. Effect of heat treatment on corrosion behavior of duplex coatings

    Directory of Open Access Journals (Sweden)

    K. Raghu Ram Mohan Reddy

    2017-01-01

    Full Text Available In the present paper, duplex WC-Co/NiCrAlY coating is coated onto Ti6Al4V substrate and vacuum heat treatment is employed to investigate the corrosion behavior of heat treated samples as well as Ti6Al4V substrate for comparison. In this duplex coating system, High Velocity Oxy Fuel (HVOF process is used to deposit NiCrAlY interlayer with a constant thickness of 200 μm and WC-Co ceramic top layer with varying thickness of 250 μm, 350 μm and 450 μm deposited by Detonation Spray (DS process. Different heat treatment temperatures (600–1150 °C were employed for the coated samples to study the microstructure and the effect on corrosion resistance of the duplex coatings. Potentiodynamic polarization tests were carried to investigate the corrosion performance of duplex coated heat treated samples and the substrate in Ringer’s solution at 37 °C and prepared the pH to 5.7. The microstructure upon corrosion after heat treatment was characterized by SEM analysis to understand the corrosion behavior. The results disclosed that at all heat treatment temperatures, all the coated samples exhibited better corrosion resistance than the base substrate. However, during 950 °C and 1150 °C heat treatment temperatures, it was observed highest corrosion potential than 600 °C and 800 °C. The 350 μm thickness, coated sample exhibited highest corrosion resistance compared to other two coated samples and the substrate at all heat treatment temperatures.

  17. Cast iron - a predictable material

    Directory of Open Access Journals (Sweden)

    Jorg C. Sturm

    2011-02-01

    Full Text Available High strength compacted graphite iron (CGI or alloyed cast iron components are substituting previously used non-ferrous castings in automotive power train applications. The mechanical engineering industry has recognized the value in substituting forged or welded structures with stiff and light-weight cast iron castings. New products such as wind turbines have opened new markets for an entire suite of highly reliable ductile iron cast components. During the last 20 years, casting process simulation has developed from predicting hot spots and solidification to an integral assessment tool for foundries for the entire manufacturing route of castings. The support of the feeding related layout of the casting is still one of the most important duties for casting process simulation. Depending on the alloy poured, different feeding behaviors and self-feeding capabilities need to be considered to provide a defect free casting. Therefore, it is not enough to base the prediction of shrinkage defects solely on hot spots derived from temperature fields. To be able to quantitatively predict these defects, solidification simulation had to be combined with density and mass transport calculations, in order to evaluate the impact of the solidification morphology on the feeding behavior as well as to consider alloy dependent feeding ranges. For cast iron foundries, the use of casting process simulation has become an important instrument to predict the robustness and reliability of their processes, especially since the influence of alloying elements, melting practice and metallurgy need to be considered to quantify the special shrinkage and solidification behavior of cast iron. This allows the prediction of local structures, phases and ultimately the local mechanical properties of cast irons, to asses casting quality in the foundry but also to make use of this quantitative information during design of the casting. Casting quality issues related to thermally driven

  18. On full duplex Gaussian relay channels with self-interference

    KAUST Repository

    Behboodi, Arash

    2016-08-15

    Self interference (SI) in full duplex (FD) systems is the interference caused by the transmission stream on the reception stream. Being one of the main restrictive factors for performance of practical full duplex systems, however, not too much is known about its effect on the fundamental limits of relaying systems. In this work, we consider the full duplex three-node relay channel with SI where SI is modeled as an additive Gaussian noise whose variance is dependent on instantaneous input power. The classical achievable rates and upper bounds for the single three-node relay channel no longer apply due to the structure of SI. Achievable rates for Decode-and-Forward (DF) and Compress-and-Forward (CF) and upper bounds on the capacity are derived assuming Gaussian inputs and SI. The deterministic model is also introduced and its capacity is characterized. The optimal joint source-relay distributions is discussed. Numerical results are provided comparing the achievable rates and upper bound. © 2016 IEEE.

  19. Duplex Schemes in Multiple Antenna Two-Hop Relaying

    Directory of Open Access Journals (Sweden)

    Anja Klein

    2008-04-01

    Full Text Available A novel scheme for two-hop relaying defined as space division duplex (SDD relaying is proposed. In SDD relaying, multiple antenna beamforming techniques are applied at the intermediate relay station (RS in order to separate downlink and uplink signals of a bi-directional two-hop communication between two nodes, namely, S1 and S2. For conventional amplify-and-forward two-hop relaying, there appears a loss in spectral efficiency due to the fact that the RS cannot receive and transmit simultaneously on the same channel resource. In SDD relaying, this loss in spectral efficiency is circumvented by giving up the strict separation of downlink and uplink signals by either time division duplex or frequency division duplex. Two novel concepts for the derivation of the linear beamforming filters at the RS are proposed; they can be designed either by a three-step or a one-step concept. In SDD relaying, receive signals at S1 are interfered by transmit signals of S1, and receive signals at S2 are interfered by transmit signals of S2. An efficient method in order to combat this kind of interference is proposed in this paper. Furthermore, it is shown how the overall spectral efficiency of SDD relaying can be improved if the channels from S1 and S2 to the RS have different qualities.

  20. New Application of Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    YANG Jia-long; LI Ying; WANG Fu; ZANG Zheng-gui; LI Si-jun

    2006-01-01

    Several rigid substrates such as stainless steel, titanium alloy, aluminum alloy, nickel foil, silicon, and sodium lime glass have been employed for manufacturing high quality TiO2 films by metal organic chemical vapor deposition (MOCVD). The as-deposited TiO2 films have been characterized with SEM/EDX and XRD. The photocatalytic properties were investigated by decomposition of aqueous orangeⅡ. UV-VIS photospectrometer was employed to check the absorption characteristics and photocatalytic degradation activity. The results show that films synthesized on metal substrates display higher photoactivities than that on absolute substrates such as silicon and glass. It is found that solar light is an alternative to UV-light used for illumination during photodegradation of orange Ⅱ. TiO2 film on stainless steel substrate was regarded as the best one for photocatalysis.

  1. Study on Pot Forming of Induction Heater Type Rice Cookers by Forging Cast Process

    Science.gov (United States)

    Ohnishi, Masayuki; Yamaguchi, Mitsugi; Ohashi, Osamu

    This paper describes a study result on pot fabrication by the forging cast process of stainless steel with aluminum. Rice cooked with the new bowl-shaped pot for the induction heater type rice cookers is better tasting than rice cooked with the conventional cylindrical one, due to the achievement of better heat conduction and convection. The conventional pot is made of the clad sheet, consisting of stainless steel and aluminum. However, it is rather difficult to form a bowl shape from the clad sheet, primarily due to the problem of a material spring back. The fabrication of a new type of a pot was made possible by means of the adoption of a forging cast process instead of the clad sheet. In this process, iron powder is inserted between stainless steel and aluminum in order to alleviate the large difference on the coefficient of expansion between each material. It was made clear that the application of two kinds of iron particle, namely 10 μm size powder on the stainless steel side and 44 μm on the aluminum side, enables the joints to become strong enough. The joint strength of the new pot by this fabrication process was confirmed by the tests of the shear strength and the fatigue tests together with the stress analysis.

  2. Melting and casting of FeAl-based cast alloy

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K. [Oak Ridge National Lab., TN (United States); Wilkening, D. [Columbia Falls Aluminum Co., Columbia Falls, MT (United States); Liebetrau, J.; Mackey, B. [AFFCO, L.L.C., Anaconda, MT (United States)

    1998-11-01

    The FeAl-based intermetallic alloys are of great interest because of their low density, low raw material cost, and excellent resistance to high-temperature oxidation, sulfidation, carburization, and molten salts. The applications based on these unique properties of FeAl require methods to melt and cast these alloys into complex-shaped castings and centrifugal cast tubes. This paper addresses the melting-related issues and the effect of chemistry on the microstructure and hardness of castings. It is concluded that the use of the Exo-Melt{trademark} process for melting and the proper selection of the aluminum melt stock can result in porosity-free castings. The FeAl alloys can be melted and cast from the virgin and revert stock. A large variation in carbon content of the alloys is possible before the precipitation of graphite flakes occurs. Titanium is a very potent addition to refine the grain size of castings. A range of complex sand castings and two different sizes of centrifugal cast tubes of the alloy have already been cast.

  3. Melting and casting of FeAl-based cast alloy

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.; Wilkening, D. [Columbia Falls Aluminum Co., 2000 Aluminum Dr., Columbia Falls, MT 59912 (United States); Liebetrau, J.; Mackey, B. [AFFCO, L.L.C., P.O. Box 1071, Anaconda, MT 59711 (United States)

    1998-12-31

    The FeAl-based intermetallic alloys are of great interest because of their low density, low raw material cost, and excellent resistance to high-temperature oxidation, sulfidation, carburization, and molten salts. The applications based on these unique properties of FeAl require methods to melt and cast these alloys into complex-shaped castings and centrifugal cast tubes. This paper addresses the melting-related issues and the effect of chemistry on the microstructure and hardness of castings. It is concluded that the use of the Exo-Melt{sup TM} process for melting and the proper selection of the aluminum melt stock can result in porosity-free castings. The FeAl alloys can be melted and cast from the virgin and revert stock. A large variation in carbon content of the alloys is possible before the precipitation of graphite flakes occurs. Titanium is a very potent addition to refine the grain size of castings. A range of complex sand castings and two different sizes of centrifugal cast tubes of the alloy have already been cast. (orig.) 18 refs.

  4. Adsorption and protein-induced metal release from chromium metal and stainless steel.

    Science.gov (United States)

    Lundin, M; Hedberg, Y; Jiang, T; Herting, G; Wang, X; Thormann, E; Blomberg, E; Wallinder, I Odnevall

    2012-01-15

    A research effort is undertaken to understand the mechanism of metal release from, e.g., inhaled metal particles or metal implants in the presence of proteins. The effect of protein adsorption on the metal release process from oxidized chromium metal surfaces and stainless steel surfaces was therefore examined by quartz crystal microbalance with energy dissipation monitoring (QCM-D) and graphite furnace atomic absorption spectroscopy (GFAAS). Differently charged and sized proteins, relevant for the inhalation and dermal exposure route were chosen including human and bovine serum albumin (HSA, BSA), mucin (BSM), and lysozyme (LYS). The results show that all proteins have high affinities for chromium and stainless steel (AISI 316) when deposited from solutions at pH 4 and at pH 7.4 where the protein adsorbed amount was very similar. Adsorption of albumin and mucin was substantially higher at pH 4 compared to pH 7.4 with approximately monolayer coverage at pH 7.4, whereas lysozyme adsorbed in multilayers at both investigated pH. The protein-surface interaction was strong since proteins were irreversibly adsorbed with respect to rinsing. Due to the passive nature of chromium and stainless steel (AISI 316) surfaces, very low metal release concentrations from the QCM metal surfaces in the presence of proteins were obtained on the time scale of the adsorption experiment. Therefore, metal release studies from massive metal sheets in contact with protein solutions were carried out in parallel. The presence of proteins increased the extent of metals released for chromium metal and stainless steel grades of different microstructure and alloy content, all with passive chromium(III)-rich surface oxides, such as QCM (AISI 316), ferritic (AISI 430), austentic (AISI 304, 316L), and duplex (LDX 2205).

  5. Nickel: makes stainless steel strong

    Science.gov (United States)

    Boland, Maeve A.

    2012-01-01

    Nickel is a silvery-white metal that is used mainly to make stainless steel and other alloys stronger and better able to withstand extreme temperatures and corrosive environments. Nickel was first identified as a unique element in 1751 by Baron Axel Fredrik Cronstedt, a Swedish mineralogist and chemist. He originally called the element kupfernickel because it was found in rock that looked like copper (kupfer) ore and because miners thought that "bad spirits" (nickel) in the rock were making it difficult for them to extract copper from it. Approximately 80 percent of the primary (not recycled) nickel consumed in the United States in 2011 was used in alloys, such as stainless steel and superalloys. Because nickel increases an alloy's resistance to corrosion and its ability to withstand extreme temperatures, equipment and parts made of nickel-bearing alloys are often used in harsh environments, such as those in chemical plants, petroleum refineries, jet engines, power generation facilities, and offshore installations. Medical equipment, cookware, and cutlery are often made of stainless steel because it is easy to clean and sterilize. All U.S. circulating coins except the penny are made of alloys that contain nickel. Nickel alloys are increasingly being used in making rechargeable batteries for portable computers, power tools, and hybrid and electric vehicles. Nickel is also plated onto such items as bathroom fixtures to reduce corrosion and provide an attractive finish.

  6. Effect of Electrode Types on the Solidification Cracking Susceptibility of Austenitic Stainless Steel Weld Metal

    Directory of Open Access Journals (Sweden)

    J. U. Anaele

    2015-01-01

    Full Text Available The effect of electrode types on the solidification cracking susceptibility of austenitic stainless steel weld metal was studied. Manual metal arc welding method was used to produce the joints with the tungsten inert gas welding serving as the control. Metallographic and chemical analyses of the fusion zones of the joints were conducted. Results indicate that weldments produced from E 308-16 (rutile coated, E 308-16(lime-titania coated electrodes, and TIG welded joints fall within the range of 1.5≤Creq./Nieq.≤1.9 and solidified with a duplex mode and were found to be resistant to solidification cracking. The E 308-16 weld metal had the greatest resistance to solidification cracking. Joints produced from E 310-16 had Creq./Nieq. ratio 1.9 and solidified with ferrite mode. It had a low resistance to solidification cracking.

  7. Corrosivity of paper mill effluent and corrosion performance of stainless steel.

    Science.gov (United States)

    Ram, Chhotu; Sharma, Chhaya; Singh, A K

    2015-01-01

    Present study relates to the corrosivity of paper mill effluent and corrosion performance of stainless steel (SS) as a construction material for the effluent treatment plant (ETP). Accordingly, immersion test and electrochemical polarization tests were performed on SS 304 L, 316 L and duplex 2205 in paper mill effluent and synthetic effluent. This paper presents electrochemical polarization measurements, performed for the first time to the best of the authors' information, to see the influence of chlorophenols on the corrosivity of effluents. The corrosivity of the effluent was observed to increase with the decrease in pH and increase in Cl- content while the addition of SO4- tends to inhibit corrosion. Mill effluent was found to be more corrosive as compared to synthetic effluent and has been attributed to the presence of various chlorophenols. Corrosion performance of SS was observed to govern by the presence of Cr, Mo and N contents.

  8. Microstructure Evolution and Cracking Control of 316L Stainless Steel Manufactured by Multi-layer Laser Cladding

    Institute of Scientific and Technical Information of China (English)

    SONGJian-li; DENGQi-lin; HUDe-jin; SUNKang-kai; ZHOUGuang-cai

    2004-01-01

    Multi-layer laser cladding manufacturing is a newly developed rapid manufacturing technology. It is a powerful tool for direct fabrication of three-dimensional fully dense metal components and part repairing. In this paper, the microstructure evolution and properties of 316L stainless steel deposited with this technology was investigated, compact components with properties similar to the as-cast and wrought annealed material was obtained. Cracking was eliminated by introducing of supersonic vibration and application of parameter adjustment technologies.

  9. An investigation into crystalline phases and nano structural and mechanical properties of HH heat resistant stainless steels

    Directory of Open Access Journals (Sweden)

    M Hosseini

    2015-12-01

    Full Text Available In the present work, the effects of different casting parameters including pouring temperature and cooling rate on stainless steel structures and mechanical properties of heat resistant alloy (HH were studied. Mo nanoparticles were synthesized through sol-gel method and were coated on the stainless steel device using spin-coating method. The effect of coating layer on the device was studied by using XRD (X-Ray Diffraction and FT-IR (Fourier Transform Infra red and SEM (Scanning Electron Microscopy techniques. The obtained results indicated an enhancement of corrosion, surface abrasion protection without changing metal surface structure, and a reduction of leakage current through the stainless steel device. Furthermore, pouring temperature and cooling rate increase caused a fine grain structure to be acquired with less carbides and better distribution in the austenitic matrix.

  10. [Casting faults and structural studies on bonded alloys comparing centrifugal castings and vacuum pressure castings].

    Science.gov (United States)

    Fuchs, P; Küfmann, W

    1978-07-01

    The casting processes in use today such as centrifugal casting and vacuum pressure casting were compared with one another. An effort was made to answer the question whether the occurrence of shrink cavities and the mean diameter of the grain of the alloy is dependent on the method of casting. 80 crowns were made by both processes from the baked alloys Degudent Universal, Degudent N and the trial alloy 4437 of the firm Degusa. Slice sections were examined for macro and micro-porosity and the structural appearance was evaluated by linear analysis. Statistical analysis showed that casting faults and casting structure is independent of the method used and their causes must be found in the conditions of casting and the composition of the alloy.

  11. Light metal compound casting

    Institute of Scientific and Technical Information of China (English)

    Konrad J.M.PAPIS; Joerg F.LOEFFLER; Peter J.UGGOWITZER

    2009-01-01

    'Compound casting'simplifies joining processes by directly casting a metallic melt onto a solid metal substrate. A continuously metallurgic transition is very important for industrial applications, such as joint structures of spaceframe constructions in transport industry. In this project, 'compound casting' of light metals is investigated, aiming at weight-saving. The substrate used is a wrought aluminium alloy of type AA5xxx, containing magnesium as main alloying element. The melts are aluminium alloys, containing various alloying elements (Cu, Si, Zn), and magnesium. By replacing the natural oxygen layer with a zinc layer, the inherent wetting difficulties were avoided, and compounds with flawless interfaces were successfully produced (no contraction defects, cracks or oxides). Electron microscopy and EDX investigations as well as optical micrographs of the interfacial areas revealed their continu-ously metallic constitution. Diffusion of alloying elements leads to heat-treatable microstructures in the vicinity of the joining interfaces in Al-Al couples. This permits significant variability of mechanical properties. Without significantly cutting down on wettability, the formation of low-melting intermetallic phases (Al3Mg2 and AI12Mg17 IMPs) at the interface of Al-Mg couples was avoided by applying a protec-tive coating to the substrate.

  12. Bimetallic layered castings alloy steel – carbon cast steel

    Directory of Open Access Journals (Sweden)

    T. Wróbel

    2011-01-01

    Full Text Available In paper is presented technology of bimetallic layered castings based on founding method of layer coating directly in cast processso-called method of mould cavity preparation. Prepared castings consist two fundamental parts i.e. bearing part and working part (layer. The bearing part of bimetallic layered casting is typical foundry material i.e. ferritic-pearlitic carbon cast steel, whereas working part (layer is plate of austenitic alloy steel sort X10CrNi 18-8. The ratio of thickness between bearing and working part is 8:1. The quality of the bimetallic layered castings was evaluated on the basis of ultrasonic NDT (non-destructive testing, structure and macro- and microhardness researches.

  13. Casting larger polycrystalline silicon ingots

    Energy Technology Data Exchange (ETDEWEB)

    Wohlgemuth, J.; Tomlinson, T.; Cliber, J.; Shea, S.; Narayanan, M.

    1995-08-01

    Solarex has developed and patented a directional solidification casting process specifically designed for photovoltaics. In this process, silicon feedstock is melted in a ceramic crucible and solidified into a large grained semicrystalline silicon ingot. In-house manufacture of low cost, high purity ceramics is a key to the low cost fabrication of Solarex polycrystalline wafers. The casting process is performed in Solarex designed casting stations. The casting operation is computer controlled. There are no moving parts (except for the loading and unloading) so the growth process proceeds with virtually no operator intervention Today Solarex casting stations are used to produce ingots from which 4 bricks, each 11.4 cm by 11.4 cm in cross section, are cut. The stations themselves are physically capable of holding larger ingots, that would yield either: 4 bricks, 15 cm by 15 an; or 9 bricks, 11.4 cm by 11.4 an in cross-section. One of the tasks in the Solarex Cast Polycrystalline Silicon PVMaT Program is to design and modify one of the castings stations to cast these larger ingots. If successful, this effort will increase the production capacity of Solarex`s casting stations by 73% and reduce the labor content for casting by an equivalent percentage.

  14. Analyzing the Potential of Full Duplex in 5G Ultra-Dense Small Cell Networks

    DEFF Research Database (Denmark)

    Gatnau, Marta; Berardinelli, Gilberto; Mahmood, Nurul Huda;

    2016-01-01

    Full duplex technology has become an attractive solution for future 5th Generation (5G) systems for accommodating the exponentially growing mobile traffic demand. Full duplex allows a node to transmit and receive simultaneously in the same frequency band, thus, theoretically, doubling the system......-interference cancellation are demonstrated using our own developed test bed. Secondly, a detailed evaluation of full duplex communication in 5G ultra-dense small cell networks via system level simulations is provided. The results are presented in terms of throughput and delay. Two types of full duplex are studied: when...

  15. High-Power Diode Laser-Treated 13Cr4Ni Stainless Steel for Hydro Turbines

    Science.gov (United States)

    Mann, B. S.

    2014-06-01

    The cast martensitic chromium nickel stainless steels such as 13Cr4Ni, 16Cr5Ni, and 17Cr4Ni PH have found wide application in hydro turbines. These steels have adequate corrosion resistance with good mechanical properties because of chromium content of more than 12%. The 13Cr4Ni stainless steel is most widely used among these steels; however, lacks silt, cavitation, and water impingement erosion resistances (SER, CER, and WIER). This article deals with characterizing 13Cr4Ni stainless steel for silt, cavitation, and water impingement erosion; and studying its improved SER, CER, and WIER behavior after high-power diode laser (HPDL) surface treatment. The WIER and CER have improved significantly after laser treatment, whereas there is a marginal improvement in SER. The main reason for improved WIER and CER is due to its increased surface hardness and formation of fine-grained microstructure after HPDL surface treatment. CER and WIER of HPDL-treated 13Cr4Ni stainless steel samples have been evaluated as per ASTM G32-2003 and ASTM G73-1978, respectively; and these were correlated with microstructure and mechanical properties such as ultimate tensile strength, modified ultimate resilience, and microhardness. The erosion damage mechanism, compared on the basis of scanning electron micrographs and mechanical properties, is discussed and reported in this article.

  16. Microstructures of Austenitic Stainless Steel Produced by Twin-Roll Strip Caster

    Institute of Scientific and Technical Information of China (English)

    HUANG Fu-xiang; WANG Xin-hua; WANG Wan-jun

    2012-01-01

    The microstructures of austenitic stainless steel strip were studied using color metallographic method and electron probe micro analysis (EPMA). In the cast strips, there are three kinds of solidification structures: fine cel- lular dendrite in the surface layer, equiaxed grains in the center and fine dendrite between them. The solidification mode in the surface layer is the primary austenite AF mode because of extremely high cooling rate, with the retained ferrite located around the primary cellular austenite. In the fine dendrite zone, the solidification mode of molten stainless steel changes to FA mode and the residual ferrite with fish-bone morphology is located at the core of the dendrite. The retained ferrite of equiaxed grains in the center is located in the center of broken primary ferrite dendrite with vermicular morphology.

  17. Fracture Mechanisms in Steel Castings

    Directory of Open Access Journals (Sweden)

    Z. Stradomski

    2013-07-01

    Full Text Available The investigations were inspired with the problem of cracking of steel castings during the production process. A single mechanism of decohesion - the intergranular one - occurs in the case of hot cracking, while a variety of structural factors is decisive for hot cracking initiation, depending on chemical composition of the cast steel. The low-carbon and low-alloyed steel castings crack due to the presence of the type II sulphides, the cause of cracking of the high-carbon tool cast steels is the net of secondary cementite and/or ledeburite precipitated along the boundaries of solidified grains. Also the brittle phosphor and carbide eutectics precipitated in the final stage solidification are responsible for cracking of castings made of Hadfield steel. The examination of mechanical properties at 1050°C revealed low or very low strength of high-carbon cast steels.

  18. Influence of cerium on hot workability of 00Cr25Ni7Mo4N super duplex stainless steel

    Institute of Scientific and Technical Information of China (English)

    王晓峰; 陈伟庆

    2010-01-01

    The effect of Ce on hot workability of 00Cr25Ni7Mo4N steel melted in vacuum induction furnace was studied by Gleeble thermal simulation machine and scanning electron microscopy(SEM).The results showed that ductility of the steel with Ce addition was increased significantly because of increasing content of austenite,segregation of Ce at grain boundaries and modification of inclusion.The optimum range of Ce content in the steel was 0.030 wt.%-0.047 wt.%,and the optimum value was about 0.047 wt.%.The effect of...

  19. Low Temperature Surface Carburization of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Collins, Sunniva R; Heuer, Arthur H; Sikka, Vinod K

    2007-12-07

    Low-temperature colossal supersaturation (LTCSS) is a novel surface hardening method for carburization of austenitic stainless steels (SS) without the precipitation of carbides. The formation of carbides is kinetically suppressed, enabling extremely high or colossal carbon supersaturation. As a result, surface carbon concentrations in excess of 12 at. % are routinely achieved. This treatment increases the surface hardness by a factor of four to five, improving resistance to wear, corrosion, and fatigue, with significant retained ductility. LTCSS is a diffusional surface hardening process that provides a uniform and conformal hardened gradient surface with no risk of delamination or peeling. The treatment retains the austenitic phase and is completely non-magnetic. In addition, because parts are treated at low temperature, they do not distort or change dimensions. During this treatment, carbon diffusion proceeds into the metal at temperatures that constrain substitutional diffusion or mobility between the metal alloy elements. Though immobilized and unable to assemble to form carbides, chromium and similar alloying elements nonetheless draw enormous amounts of carbon into their interstitial spaces. The carbon in the interstitial spaces of the alloy crystals makes the surface harder than ever achieved before by more conventional heat treating or diffusion process. The carbon solid solution manifests a Vickers hardness often exceeding 1000 HV (equivalent to 70 HRC). This project objective was to extend the LTCSS treatment to other austenitic alloys, and to quantify improvements in fatigue, corrosion, and wear resistance. Highlights from the research include the following: • Extension of the applicability of the LTCSS process to a broad range of austenitic and duplex grades of steels • Demonstration of LTCSS ability for a variety of different component shapes and sizes • Detailed microstructural characterization of LTCSS-treated samples of 316L and other alloys

  20. A comparison of the accuracy of two removable die systems with intact working casts.

    Science.gov (United States)

    Aramouni, P; Millstein, P

    1993-01-01

    This study evaluated the reproducibility of die position using two removable die systems and two die stones. Poly(vinyl siloxane) impressions were made of a stainless steel, U-shaped arch with four evenly spaced abutments. Six groups were evaluated: Zeiser system/Fuji Rock; Zeiser system/Die Keen; solid cast/Fuji Rock; solid cast/Die Keen; Fuji Rock/Pindex; and Die Keen/Pindex. An optical comparator was used to measure the height of each abutment, the distance between the anterior abutments, and the distance between the posterior abutments. The Zeiser system with either Fuji Rock or Die Keen yielded the greatest accuracy. Die Keen exhibited more linear expansion than Fuji Rock, and solid casts had less distortion than the Pindex system.

  1. Force-Induced Rupture of a DNA Duplex: From Fundamentals to Force Sensors.

    Science.gov (United States)

    Mosayebi, Majid; Louis, Ard A; Doye, Jonathan P K; Ouldridge, Thomas E

    2015-12-22

    The rupture of double-stranded DNA under stress is a key process in biophysics and nanotechnology. In this article, we consider the shear-induced rupture of short DNA duplexes, a system that has been given new importance by recently designed force sensors and nanotechnological devices. We argue that rupture must be understood as an activated process, where the duplex state is metastable and the strands will separate in a finite time that depends on the duplex length and the force applied. Thus, the critical shearing force required to rupture a duplex depends strongly on the time scale of observation. We use simple models of DNA to show that this approach naturally captures the observed dependence of the force required to rupture a duplex within a given time on duplex length. In particular, this critical force is zero for the shortest duplexes, before rising sharply and then plateauing in the long length limit. The prevailing approach, based on identifying when the presence of each additional base pair within the duplex is thermodynamically unfavorable rather than allowing for metastability, does not predict a time-scale-dependent critical force and does not naturally incorporate a critical force of zero for the shortest duplexes. We demonstrate that our findings have important consequences for the behavior of a new force-sensing nanodevice, which operates in a mixed mode that interpolates between shearing and unzipping. At a fixed time scale and duplex length, the critical force exhibits a sigmoidal dependence on the fraction of the duplex that is subject to shearing.

  2. Dynamics characterization of microstructural changes in bars of duplex steels SAF 2205 using the information dimension; Caracterizacion dinamica de los cambios microestructurales en barras de aceros duplex SAF 2205 utilizando la dimension de informacion

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, E.; Suarez, K.; Amorer, L.; Silva, J.

    2014-04-01

    This study evaluates the ultrasonic signals behavior of a duplex stainless steel SAF 2205 (UNS S31803) after aging treatments at 875 and 950 degree centigrade. The first treatment promotes the precipitation of the sigma phase and the second, its dissolution. The microstructural evaluation was carried out by optical microscopy. The results showed an increase of the sigma phase fraction and the secondary austenite with the time of aging treatment at 875 degree centigrade. On the other hand, increasing the time of treatment at 950 degree centigrade promotes a reduction of the sigma phase and the corresponding increase of the ferrite phase fraction. The study proposed to evaluate in the dynamical system field the influence of microstructural phases in the signals behavior and their dependence on the energy losses occurring in system during heat treatment, by deterministic chaos theory. To accomplish characterization, algorithm employs the representation of dynamic phase space and the information dimension estimate. The results show a higher correlation between the information dimension and the attenuation coefficient in comparison with the phase fractions. However, the efficiency of this type of study will depend on the frequency selected for the evaluation of the material. (Author)

  3. Protocols For Half-Duplex Multiple Relay Networks

    CERN Document Server

    Rost, P

    2007-01-01

    In this paper we present several strategies for multiple relay networks which are constrained by a half-duplex operation, i. e., each node either transmits or receives on a particular resource. Using the discrete memoryless multiple relay channel we present achievable rates for a multilevel partial decode-and-forward approach which generalizes previous results presented by Kramer and Khojastepour et al.. Furthermore, we derive a compress-and-forward approach using a regular encoding scheme which simplifies the encoding and decoding scheme and improves the achievable rates in general. Finally, we give achievable rates for a mixed strategy used in a four-terminal network with alternately transmitting relay nodes.

  4. Technology of Welding Joints Mixed with Duplex Steel

    OpenAIRE

    Słania J.; Krawczyk R.; Masłoń D.

    2016-01-01

    Results of the examinations of sample plates of mixed joints with the duplex steel were discussed. Examinations were taken on the sample plates of mixed joints of sheet plates type P355NL1 and X2CrNiMoN22-5-3 welded by the flux-cored wire DW-329A by the Kobelco company of the following category T 22 9 3 NL RC/M3 in the gas shroud M21 (Ar+18%CO2) (plate no.1), and nickel covered electrodes E Ni 6082 by the Böhler company (plate no. 2). Results of the side bend test of welded joint, transverse ...

  5. Reliability Capacity of Half-Duplex Channels with Strict Deadlines

    DEFF Research Database (Denmark)

    Costa, Rui; Roetter, Daniel Enrique Lucani; Vinhoza, Tiago;

    2015-01-01

    A fundamental characterization of a half-duplex wireless system with packet losses under traffic with hard deadlines is instrumental to understanding and developing efficient, coding aware policies for real-time applications. We set forth the concept of reliability capacity with a limited number...... and in terms of its advantages towards the mean number of packets that can be transmitted reliably. Optimal schemes for leveraging feedback are presented and the results show that a judicious use of even a single feedback packet can have a significant impact on the mean performance....

  6. The Terahertz Controlled Duplex Isolator: Physical Grounds and Numerical Experiment

    Directory of Open Access Journals (Sweden)

    Konstantin Vytovtov

    2016-01-01

    Full Text Available Electromagnetic properties of an anisotropic stratified slab with an arbitrary orientation of the anisotropy axis under an oblique incidence of a plane harmonic wave are studied. The dependence of the eigenwave wavenumbers and the reflection coefficient on an anisotropy axis orientation and frequency is investigated. For the first time, the expression for the translation matrix is obtained in the compact analytical form. The controlled two-way dual-frequency (duplex isolator based on the above described slab is presented for the first time. It is based on the properties of the anisotropic structure described here but not on the Faraday effect.

  7. Interaction between stainless steel and plutonium metal

    Energy Technology Data Exchange (ETDEWEB)

    Dunwoody, John T [Los Alamos National Laboratory; Mason, Richard E [Los Alamos National Laboratory; Freibert, Franz J [Los Alamos National Laboratory; Willson, Stephen P [Los Alamos National Laboratory; Veirs, Douglas K [Los Alamos National Laboratory; Worl, Laura A [Los Alamos National Laboratory; Archuleta, Alonso [Los Alamos National Laboratory; Conger, Donald J [Los Alamos National Laboratory

    2010-01-01

    Long-term storage of excess plutonium is of great concern in the U.S. as well as abroad. The current accepted configuration involves intimate contact between the stored material and an iron-bearing container such as stainless steel. While many safety scenario studies have been conducted and used in the acceptance of stainless steel containers, little information is available on the physical interaction at elevated temperatures between certain forms of stored material and the container itself. The bulk of the safety studies has focused on the ability of a package to keep the primary stainless steel containment below the plutonium-iron eutectic temperature of approximately 410 C. However, the interactions of plutonium metal with stainless steel have been of continuing interest. This paper reports on a scoping study investigating the interaction between stainless steel and plutonium metal in a pseudo diffusion couple at temperatures above the eutectic melt-point.

  8. Development of Refractories for Continuous Casting

    Institute of Scientific and Technical Information of China (English)

    TIAN Shouxin; JIN Congjin; YAO Jinfu; LI Zeya

    2004-01-01

    The paper introduces refractories for continuous casting, especially, refractories for continuous casting for clean steel in baosteel. Developing direction of refractories for continuous casting has been pointed out to satisfy the new metallurgical operating practice.

  9. Deformation in thrust-ramp anticlines and duplexes: implications for geometry and porosity

    Energy Technology Data Exchange (ETDEWEB)

    Groshong, R.H. Jr.; Usdansky, S.I.

    1986-05-01

    A computerized kinematic model of thrust-ramp anticline geometry allows workers to predict the zones of greatest deformation in ramp anticlines and fault duplexes. The model assumes a constant cross-section area, symmetrical fold hinges, and slip in the hanging wall parallel to the ramp and forelimb. Assuming that the collapse of original porosity or the generation of secondary fracture porosity is proportional to deformation, the model can be used to predict porosity changes. Deformation in a single ramp anticline is greatest in the forelimb and backlimb, and may be absent in the crest. A duplex structure results from comparatively closely spaced thrusts that have a common upper detachment horizon. Relatively wide spacing between the duplex faults yields a bumpy roofed duplex as in the central Appalachians. Forelimbs may be deformed twice and should show greater porosity modification. Relatively close spacing between ramp-and-flat thrusts can produce a listric-fault, snakehead anticline geometry because younger faults deform the preexisting thrust slices. The resulting geometry is here called a snakehead duplex and appears to be fairly common, as in the Jumpingpound field in the Canadian Rockies. Each thrust slice within the duplex is deformed six times or more, providing the maximum opportunity for deformation-related porosity changes. Maximum fracture porosity should occur in thrusts having listric-fan or snakehead duplex geometry. Structures involving duplexes generally should be better than isolated ramp anticlines.

  10. Importance of diastolic velocities in the detection of celiac and mesenteric artery disease by duplex ultrasound

    DEFF Research Database (Denmark)

    Perko, M J; Just, S; Schroeder, T V

    1997-01-01

    To assess the predictive value of ultrasound duplex scanning in the detection of superior mesenteric artery (SMA) and celiac artery (CA) occlusive disease.......To assess the predictive value of ultrasound duplex scanning in the detection of superior mesenteric artery (SMA) and celiac artery (CA) occlusive disease....

  11. Pushing the limits of Full-duplex: Design and Real-time Implementation

    CERN Document Server

    Sahai, Achaleshwar; Sabharwal, Ashutosh

    2011-01-01

    Recent work has shown the feasibility of single-channel full-duplex wireless physical layer, allowing nodes to send and receive in the same frequency band at the same time. In this report, we first design and implement a real-time 64-subcarrier 10 MHz full-duplex OFDM physical layer, FD-PHY. The proposed FD-PHY not only allows synchronous full-duplex transmissions but also selective asynchronous full-duplex modes. Further, we show that in over-the-air experiments using optimal antenna placement on actual devices, the self-interference can be suppressed upto 80dB, which is 10dB more than prior reported results. Then we propose a full-duplex MAC protocol, FD-MAC, which builds on IEEE 802.11 with three new mechanisms -- shared random backoff, header snooping and virtual backoffs. The new mechanisms allow FD-MAC to discover and exploit full-duplex opportunities in a distributed manner. Our over-the-air tests show over 70% throughput gains from using full-duplex over half-duplex in realistically used cases.

  12. Segregation in cast products

    Indian Academy of Sciences (India)

    A Ghosh

    2001-02-01

    Microsegregation gets eliminated significantly if subsequent hot working and/or annealing are done on cast products. Macrosegregation however persists, causing problems in quality, and hence, has to be attended to. Microsegregation is a consequence of rejection of solutes by the solid into the interdendritic liquid. Scheil’s equation is mostly employed. However, other equations have been proposed, which take into account diffusion in solid phase and/or incomplete mixing in liquid. Macrosegregation results from movements of microsegregated regions over macroscopic distances due to motion of liquid and free crystals. Motion of impure interdendritic liquid causes regions of positive macrosegregation, whereas purer solid crystals yield negative macrosegregation. Flow of interdendritic liquid is primarily natural convection due to thermal and solutal buoyancy, and partly forced convection due to suction by shrinkage cavity formation etc. The present paper briefly deals with fundamentals of the above and contains some recent studies as well. Experimental investigations in molten alloys do not allow visualization of the complex flow pattern as well as other phenomena, such as dendrite-tip detachment. Experiments with room temperature analogues, and mathematical modelling have supplemented these efforts. However, the complexity of the phenomena demands simplifying assumptions. The agreement with experimental data is mostly qualitative. The paper also briefly discusses centreline macrosegregation during continuous casting of steel, methods to avoid it, and the, importance of early columnar-to-equiaxed transition (CET) as well as the fundamentals of CET.

  13. Biomaterials by freeze casting.

    Science.gov (United States)

    Wegst, Ulrike G K; Schecter, Matthew; Donius, Amalie E; Hunger, Philipp M

    2010-04-28

    The functional requirements for synthetic tissue substitutes appear deceptively simple: they should provide a porous matrix with interconnecting porosity and surface properties that promote rapid tissue ingrowth; at the same time, they should possess sufficient stiffness, strength and toughness to prevent crushing under physiological loads until full integration and healing are reached. Despite extensive efforts and first encouraging results, current biomaterials for tissue regeneration tend to suffer common limitations: insufficient tissue-material interaction and an inherent lack of strength and toughness associated with porosity. The challenge persists to synthesize materials that mimic both structure and mechanical performance of the natural tissue and permit strong tissue-implant interfaces to be formed. In the case of bone substitute materials, for example, the goal is to engineer high-performance composites with effective properties that, similar to natural mineralized tissue, exceed by orders of magnitude the properties of its constituents. It is still difficult with current technology to emulate in synthetic biomaterials multi-level hierarchical composite structures that are thought to be the origin of the observed mechanical property amplification in biological materials. Freeze casting permits to manufacture such complex, hybrid materials through excellent control of structural and mechanical properties. As a processing technique for the manufacture of biomaterials, freeze casting therefore has great promise.

  14. Erosion and corrosion of ceramic-metallic coatings and stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Bjordal, M.

    1995-04-01

    Simultaneous corrosion and erosion is a well-known problem in many environments, for instance in hydroelectric power plants and in oil production systems. This thesis presents a study of the combined effect of corrosion and erosion for some thermal spray ceramic-metallic coatings (cemented carbides) and a duplex stainless steel. By measuring the two effects separately and comparing them to the total material loss obtained when they occur simultaneously, it has been possible to reveal the relative contribution from the two deterioration mechanisms and how they interact. The materials were exposed to flowing aerated synthetic sea water containing silica particles. Specimens of various shapes were moved in the slurry. It is generally found that the corrosion percentage decreases when the erosivity of the environment is increased, for instance by increased flow velocity, and at the same time erosion plays a more important role. For all the materials tested the corrosion rate is increased by addition of particles to the flow. Differences are found between the thermal spray coatings. Small additions of Cr to the actively corroding Co matrix of the 83WC 17Co sample improve the corrosion resistance. Even if the amount of corrosion relative to the total weight loss rate is small, the corrosion can lead to a synergism of up to 90 %. Stainless steel does not exhibit a clear synergism. The computer code FLUENT was used for modelling the flow conditions. 79 refs., 67 figs., 29 tabs.

  15. Effect of laser surface melting in tensile properties of type 304L stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Akgun, O.V.; Inal, O.T. (New Mexico Inst. of Mining and Technology, Materials and Metallurgical Engineering Dept., Socorro, NM (US)); Lovato, M.L.; Jervist, T.R. (Los Alamos National Lab., Los Alamos, NM (US))

    1992-07-15

    In previous study the authors showed laser surface melting (LSM) to increase yield strength of 304 austenitic stainless steels. A consistent increase approximately 10% was also observed in the hardness of the melted layer compared to that of the substrate. Austentic stainless steels do not transform to martensite during laser processing. The microstructure is observed to contain only austenite and some retained {delta}-ferrite due to rapid cooling. Therefore, the hardness increase observed was interpreted to be due to microstructural modifications, namely in the formation of austenite {delta}-ferrite duplex structure as well as a refinement in the subgrain structure. The alloy used in this study, type 304L, is a lower carbon modification of type 304 for welding applications. Lower carbon content minimizes carbide precipitation in the heat affected zone of welds. In an annealed condition type 304L has lower mechanical properties than type 304. This paper reports on this present study which was undertaken to verify if a material that possesses an initially high yield strength, type 304L, would exhibit a similar increase in its yield strength and the magnitude of this enhancement at different test temperatures (22, 100, 200 and 300{degrees}C).

  16. Education and Caste in India

    Science.gov (United States)

    Chauhan, Chandra Pal Singh

    2008-01-01

    This paper analyses the policy of reservation for lower castes in India. This policy is similar to that of affirmative action in the United States. The paper provides a brief overview of the caste system and discusses the types of groups that are eligible for reservation, based on data from government reports. The stance of this paper is that…

  17. Theory of batchwise centrifugal casting

    NARCIS (Netherlands)

    Biesheuvel, P. Maarten; Nijmeijer, Arian; Verweij, Henk

    1998-01-01

    In batchwise centrifugal casting a cylindrical mold is filled with suspension and rotated rapidly around its axis. This results in the movement of the particulate phase toward the cylinder wall and the formation of a tubular cast. Theory is presented for particle transport in the suspension phase an

  18. Lost Foam Casting in China

    Institute of Scientific and Technical Information of China (English)

    YE Sheng-ping; WU Zhi-chao

    2006-01-01

    @@ 1. Lost Foam Casting Committee of Foundry Institution of Chinese Mechanical Engineering Society (FICMES) From the beginning of the 1990s, China entered a research and expansion climax in lost foam casting technology realm after the United States, Germany, and Japan etc.

  19. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2009-01-01

    @@ This book consists of five sections:Chapter 1 Introduction,Chapter 2 Grey Iron,Chapter 3 Ductile Iron,Chapter 4Vermicular Cast Iron,and Chapter 5 White Cast Iron. CHINA FOUNDRY publishs this book in several parts serially,starting from the first issue of 2009.

  20. Hole Transport in A-form DNA/RNA Hybrid Duplexes

    Science.gov (United States)

    Wong, Jiun Ru; Shao, Fangwei

    2017-01-01

    DNA/RNA hybrid duplexes are prevalent in many cellular functions and are an attractive target form for electrochemical biosensing and electric nanodevice. However the electronic conductivities of DNA/RNA hybrid duplex remain relatively unexplored and limited further technological applications. Here cyclopropyl-modified deoxyribose- and ribose-adenosines were developed to explore hole transport (HT) in both DNA duplex and DNA/RNA hybrids by probing the transient hole occupancies on adenine tracts. HT yields through both B-form and A-form double helixes displayed similar shallow distance dependence, although the HT yields of DNA/RNA hybrid duplexes were lower than those of DNA duplexes. The lack of oscillatory periods and direction dependence in HT through both helixes implied efficient hole propagation can be achieved via the hole delocalization and coherent HT over adenine tracts, regardless of the structural variations.

  1. Physical-Layer Security of a Buffer-Aided Full-Duplex Relaying System

    KAUST Repository

    El Shafie, Ahmed

    2016-07-07

    This letter proposes a novel hybrid half-/full-duplex relaying scheme to enhance the relay channel security. A source node (Alice) communicates with her destination node (Bob) in the presence of a buffer-aided full-duplex relay node (Rooney) and a potential eavesdropper (Eve). Rooney adopts two different relaying, namely randomize-and-forward and decode-andforward relaying strategies, to improve the security of the legitimate system. In the first relaying strategy, Rooney uses a codebook different from that used at Alice. In the second relaying strategy, Rooney and Alice use the same codebooks. In addition, Rooney switches between half-duplex and full-duplex modes to further enhance the security of the legitimate system. The numerical results demonstrate that our proposed scheme achieves a significant average secrecy end-to-end throughput improvement relative to the conventional bufferless full-duplex relaying scheme.

  2. Throughput Analysis of Full Duplex Communication with Asymmetric Traffic in Small Cell Systems

    DEFF Research Database (Denmark)

    Mahmood, Nurul Huda; Berardinelli, Gilberto; Mogensen, Preben Elgaard;

    2015-01-01

    in this contribution using network analysis tools from stochastic geometry. The analytical findings are further confirmed through computer-based Monte-Carlo simulations. Asymmetric downlink/uplink traffic pattern and the increased network interference stemming from full duplex transmissions are found to limit its......Full duplex communication promises a 100% throughput gain by enabling simultaneous transmission and reception. However, such simultaneous communication leads to a corresponding increase in the network interference. In addition, full duplex communication can only be exploited when traffic...... is available in both uplink and downlink directions; while, cellular network traffic tend to be downlink heavy in practice. The potential throughput gains of full duplex communication over conventional half duplex transmission in a small cell network with asymmetric traffic conditions are investigated...

  3. Sequence-selective targeting of duplex DNA by peptide nucleic acids

    DEFF Research Database (Denmark)

    Nielsen, Peter E

    2010-01-01

    Sequence-selective gene targeting constitutes an attractive drug-discovery approach for genetic therapy, with the aim of reducing or enhancing the activity of specific genes at the transcriptional level, or as part of a methodology for targeted gene repair. The pseudopeptide DNA mimic peptide...... nucleic acid (PNA) can recognize duplex DNA with high sequence specificity and affinity in triplex, duplex and double-duplex invasive modes or non-invasive triplex modes. Novel PNA modification has improved the affinity for DNA recognition via duplex invasion, double-duplex invasion and triplex...... recognition considerably. Such modifications have also resulted in new approaches to targeted gene repair and sequence-selective double-strand cleavage of genomic DNA....

  4. Duplex Identification of Staphylococcus aureus by Aptamer and Gold Nanoparticles.

    Science.gov (United States)

    Chang, Tianjun; Wang, Libo; Zhao, Kexu; Ge, Yu; He, Meng; Li, Gang

    2016-06-01

    Staphylococcus aureus is the top common pathogen causing infections and food poisoning. Identification of S. aureus is crucial for the disease diagnosis and regulation of food hygiene. Herein, we report an aptamer-AuNPs based method for duplex identification of S. aureus. Using AuNPs as an indicator, SA23, an aptamer against S. aureus, can well identify its target from Escherichia coli, Listeria monocytogenes and Pseudomonas aeruginosa. Furthermore, we find citrate-coated AuNPs can strongly bind to S. aureus, but not bind to Salmonella enterica and Proteus mirabilis, which leads to different color changes in salt solution. This colorimetric response is capable of distinguishing S. aureus from S. enteritidis and P. mirabilis. Thus, using the aptasensor and AuNPs together, S. aureus can be accurately identified from the common pathogens. This duplex identification system is a promising platform for simple visual identification of S. aureus. Additionally, in the aptasensing process, bacteria are incubated with aptamers and then be removed before the aptamers adding to AuNPs, which may avoid the interactions between bacteria and AuNPs. This strategy can be potentially applied in principle to detect other cells by AuNPs-based aptasensors.

  5. Fabrication of Duplex Coated U-Mo-Ti Atomized Powder

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Ji Min; Kim, Woo Jeong; Lee, Kyu Hong [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Ryu, Ho Jin [Korea Advanced Institue of Science and Technology, Daejeon (Korea, Republic of)

    2013-10-15

    The results of an annealing test showed that the coating layers inhibit the formation of interaction layers. The results of duplex coating showed that nitride coating layers inhibit the formation of other coating layers. High-density U-Mo alloys are regarded as promising candidates for advanced research reactor fuel as they have shown stable irradiation performance when compared to other uranium alloys and compounds. However, interaction layer formation between the U-Mo alloys and Al matrix degrades the irradiation performance of U-Mo dispersion fuel. Therefore, the addition of Ti in U-Mo alloys, the addition of Si in a Al matrix, and silicide or nitride coating on the surface of U-Mo particles have been proposed to inhibit the interaction layer growth. In this study, U-Mo-Ti alloy powder was produced using a centrifugal atomization method. In addition, nitride and silicide duplex coating layers were fabricated on the surface of the U-Mo-Ti particles. The coated powders were characterized by using X-ray diffraction, SEM, and EDX. Silicide and nitride single coating layers were fabricated on the surface of U-7wt%Mo-1wt%Ti alloys with a thickness of about 10.20 micrometers.

  6. Sex determination in 6 bovid species by duplex PCR.

    Science.gov (United States)

    Prashant; Gour, Digpal S; Dubey, Prem P; Jain, Anubhav; Gupta, Subhash C; Joshi, Balwinder K; Kumar, Dinesh

    2008-01-01

    Sex determination in domestic animals is of potential value to livestock breeding programs. The aim of this study was to develop a simple and accurate PCR-based sex determination protocol, which can be applicable to 6 major domesticated species of the family Bovidae, viz. Bos frontalis, B. grunniens, B. indicus, Bubalus bubalis, Capra hircus, and Ovis aries. In silico analysis was done to identify conserved DNA sequence in the HMG box region of the sex-determining region of the Y-chromosome (SRY gene) across the bovids. Duplex PCR assay, including the SRY gene and the GAPDH housekeeping gene, was optimized by using genomic DNA extracted from blood samples of known sex. It was possible to identify the sex of animals by amplifying both gender-specific (SRY) and autosomal (GAPDH) genes simultaneously in the duplex reaction, with the male yielding two bands and the female one band. The protocol was subjected to a blind test that showed a 100 percent specificity and accuracy, thus it can be used in sex determination in livestock breeding programs.

  7. Enhanced H-bonding and pi-stacking in DNA: a potent duplex-stabilizing and mismatch sensing nucleobase analogue

    DEFF Research Database (Denmark)

    Lou, Chenguang; Dallmann, Andre; Marafini, Pietro;

    2014-01-01

    X-pyrene is a new nucleic acid duplex stabilizing cytosine analogue that combines enhanced pi-stacking, hydrogen bonding and electrostatic interactions to greatly increase the stability of bulged DNA duplexes and DNA/RNA hybrids. X-pyrene is highly selective for guanine as a partner and duplex...... analogue for use in a variety of biological applications....

  8. New creep resistant cast alloys with improved oxidation resistance in water vapor at 650-800ºC

    OpenAIRE

    Sebastien eDryepondt; Pint, Bruce A.; Maziasz, Philip J.

    2015-01-01

    Cast stainless steel CF8C-Plus (19wt.%Cr/12%Ni) has excellent creep properties, but limited oxidation resistance above 700ºC in environments containing H2O. One strategy to improve the alloy oxidation performance is to increase the Cr and Ni concentration. Two new alloys, with respectively 21wt%Cr-15wt%Ni and 22wt%Cr-17.5wt%Ni were therefore developed and their long-term oxidation behavior in humid air were compared with the oxidation behavior of five other cast alloys. At 650 and 700ºC, all ...

  9. New Creep-Resistant Cast Alloys with Improved Oxidation Resistance in Water Vapor at 650–800°C

    OpenAIRE

    Dryepondt, Sebastien; Pint, Bruce A.; Maziasz, Philip J.

    2015-01-01

    Cast stainless steel CF8C-Plus (19wt%Cr/12%Ni) has excellent creep properties, but limited oxidation resistance above 700°C in environments containing H2O. One strategy to improve the alloy oxidation performance is to increase the Cr and Ni concentration. Two new alloys, with, respectively, 21wt%Cr–15wt%Ni and 22wt%Cr–17.5wt%Ni were therefore developed and their long-term oxidation behaviors in humid air were compared with the oxidation behavior of five other cast alloys. At 650°C and 700°C, ...

  10. Water-evaporation reduction by duplex films: application to the human tear film.

    Science.gov (United States)

    Cerretani, Colin F; Ho, Nghia H; Radke, C J

    2013-09-01

    Water-evaporation reduction by duplex-oil films is especially important to understand the physiology of the human tear film. Secreted lipids, called meibum, form a duplex film that coats the aqueous tear film and purportedly reduces tear evaporation. Lipid-layer deficiency is correlated with the occurrence of dry-eye disease; however, in-vitro experiments fail to show water-evaporation reduction by tear-lipid duplex films. We review the available literature on water-evaporation reduction by duplex-oil films and outline the theoretical underpinnings of spreading and evaporation kinetics that govern behavior of these systems. A dissolution-diffusion model unifies the data reported in the literature and identifies dewetting of duplex films into lenses as a key challenge to obtaining significant evaporation reduction. We develop an improved apparatus for measuring evaporation reduction by duplex-oil films including simultaneous assessment of film coverage, stability, and temperature, all under controlled external mass transfer. New data reported in this study fit into the larger body of work conducted on water-evaporation reduction by duplex-oil films. Duplex-oil films of oxidized mineral oil/mucin (MOx/BSM), human meibum (HM), and bovine meibum (BM) reduce water evaporation by a dissolution-diffusion mechanism, as confirmed by agreement between measurement and theory. The water permeability of oxidized-mineral-oil duplex films agrees with those reported in the literature, after correction for the presence of mucin. We find that duplex-oil films of bovine and human meibum at physiologic temperature reduce water evaporation only 6-8% for a 100-nm film thickness pertinent to the human tear film. Comparison to in-vivo human tear-evaporation measurements is inconclusive because evaporation from a clean-water surface is not measured and because the mass-transfer resistance is not characterized.

  11. Preparation of precursor for stainless steel foam

    Institute of Scientific and Technical Information of China (English)

    ZHOU Xiang-yang; LI Shan-ni; LI Jie; LIU Ye-xiang

    2008-01-01

    The effects of polyurethane sponge pretreatment and slurry compositions on the slurry loading in precursor were discussed, and the,performances of stainless steel foams prepared from precursors with different slurry loadings and different particle sizes of the stainless steel powder were also investigated. The experimental results show that the pretreatment of sponge with alkaline solution is effective to reduce the jam of cells in precursor and ensure the slurry to uniformly distribute in sponge, and it is also an effective method for increasing the slurry loading in precursor; the mass fraction of additive A and solid content in slurry greatly affect the slurry loading in precursor, when they are kept in 9%-13% and 52%-75%, respectively, the stainless steel foam may hold excellent 3D open-cell network structure and uniform muscles; the particle size of the stainless steel powder and the slurry loading in precursor have great effects on the bending strength, apparent density and open porosity of stainless steel foam; when the stainless steel powder with particle size of 44 tan and slurry loading of 0.5 g/cm3 in precursor are used, a stainless steel foam can be obtained, which has open porosity of 81.2%, bending strength of about 51.76 MPa and apparent density of about 1.0 g/cm3.

  12. EVOLUTION OF AS—CAST MICROSTRUCTURES OF 356 ALUMINIUM ALLOY CAST BY LIQUIDUS CASTING

    Institute of Scientific and Technical Information of China (English)

    J.Dong; G.M.Lu; 等

    2003-01-01

    A new method (liquidus casting)was used for 356 Al alloy semi-solid slurry mak-ing.The structures of 356 Al alloy cast by a fe mould and semi-continuous casting machine at different temperatures were inves tigated.How the globular grains form was qlso discussed.The results show that either being cast by single Fe mould or semi-continuous machine,the microstructures are not conventional dendrites but fine and net-globular grains.The average grain size is smaller than 30μm and suitable enough for thixoforming,meanwhile it can improve the mechanical properties of fol-lowing products.Under the suitable casting velocity and cooling intensity,most of global grains prolong their global browth and collide with each other before dendritic growth because of the large amount of the nucleation sites.

  13. Biocompatibility of MIM 316L stainless steel

    Institute of Scientific and Technical Information of China (English)

    ZHU Shai-hong; WANG Guo-hui; ZHAO Yan-zhong; LI Yi-ming; ZHOU Ke-chao; HUANG Bai-yun

    2005-01-01

    To evaluate the bioeompatibility of MIM 316L stainless steel, the percentage of S-period cells were detected by flow cytometry after L929 incubated with extraction of MIM 316L stainless steel, using titanium implant materials of clinical application as the contrast. Both materials were implanted in animal and the histopathological evaluations were carried out. The statistical analyses show that there are no significant differences between two groups (P>0.05), which demonstrates that MIM 316L stainless steel has a good biocompatibility.

  14. Comparison of marginal accuracy of castings fabricated by conventional casting technique and accelerated casting technique: An in vitro study

    Directory of Open Access Journals (Sweden)

    S Srikanth Reddy

    2013-01-01

    Full Text Available Background: Conventional casting technique is time consuming when compared to accelerated casting technique. In this study, marginal accuracy of castings fabricated using accelerated and conventional casting technique was compared. Materials and Methods: 20 wax patterns were fabricated and the marginal discrepancy between the die and patterns were measured using Optical stereomicroscope. Ten wax patterns were used for Conventional casting and the rest for Accelerated casting. A Nickel-Chromium alloy was used for the casting. The castings were measured for marginal discrepancies and compared. Results: Castings fabricated using Conventional casting technique showed less vertical marginal discrepancy than the castings fabricated by Accelerated casting technique. The values were statistically highly significant. Conclusion: Conventional casting technique produced better marginal accuracy when compared to Accelerated casting. The vertical marginal discrepancy produced by the Accelerated casting technique was well within the maximum clinical tolerance limits. Clinical Implication: Accelerated casting technique can be used to save lab time to fabricate clinical crowns with acceptable vertical marginal discrepancy.

  15. Standard test method for evaluating stress-corrosion cracking of stainless alloys with different nickel content in boiling acidified sodium chloride solution

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2000-01-01

    1.1 This test method describes a procedure for conducting stress-corrosion cracking tests in an acidified boiling sodium chloride solution. This test method is performed in 25% (by mass ) sodium chloride acidified to pH 1.5 with phosphoric acid. This test method is concerned primarily with the test solution and glassware, although a specific style of U-bend test specimen is suggested. 1.2 This test method is designed to provide better correlation with chemical process industry experience for stainless steels than the more severe boiling magnesium chloride test of Practice G36. Some stainless steels which have provided satisfactory service in many environments readily crack in Practice G36, but have not cracked during interlaboratory testing using this sodium chloride test method. 1.3 This boiling sodium chloride test method was used in an interlaboratory test program to evaluate wrought stainless steels, including duplex (ferrite-austenite) stainless and an alloy with up to about 33% nickel. It may also b...

  16. Analysis of Structural Flexibility of Damaged DNA Using Thiol-Tethered Oligonucleotide Duplexes.

    Directory of Open Access Journals (Sweden)

    Masashi Fujita

    Full Text Available Bent structures are formed in DNA by the binding of small molecules or proteins. We developed a chemical method to detect bent DNA structures. Oligonucleotide duplexes in which two mercaptoalkyl groups were attached to the positions facing each other across the major groove were prepared. When the duplex contained the cisplatin adduct, which was proved to induce static helix bending, interstrand disulfide bond formation under an oxygen atmosphere was detected by HPLC analyses, but not in the non-adducted duplex, when the two thiol-tethered nucleosides were separated by six base pairs. When the insert was five and seven base pairs, the disulfide bond was formed and was not formed, respectively, regardless of the cisplatin adduct formation. The same reaction was observed in the duplexes containing an abasic site analog and the (6–4 photoproduct. Compared with the cisplatin case, the disulfide bond formation was slower in these duplexes, but the reaction rate was nearly independent of the linker length. These results indicate that dynamic structural changes of the abasic site- and (6–4 photoproduct-containing duplexes could be detected by our method. It is strongly suggested that the UV-damaged DNA-binding protein, which specifically binds these duplexes and functions at the first step of global-genome nucleotide excision repair, recognizes the easily bendable nature of damaged DNA.

  17. Preparation and property of duplex Ni-B-TiO2/Ni nano-composite coatings

    Science.gov (United States)

    Wang, Shu-Jen; Wang, Yuxin; Shu, Xin; Tay, Seeleng; Gao, Wei; Shakoor, R. A.; Kahraman, Ramazan

    2015-03-01

    The duplex Nickel-Boron-Titania/Nickel (Ni-B-TiO2/Ni) coatings were deposited on mild steel by using two baths with Ni as the inner layer. TiO2 nanoparticles were incorporated into the Ni-B coatings as the outer layer by using solid particle mixing method. The microstructure, morphology and corrosion resistance of the duplex Ni-B-TiO2/Ni nanocomposite coatings were systemically investigated. The results show that the duplex interface was uniform and the adhesion between two layers was very good. The microhardness of duplex Ni-B-TiO2/Ni coating was much higher than the Ni coating due to the outer layer of Ni-B-TiO2 coating. The corrosion resistance of the duplex Ni-B-TiO2/Ni coating was also significantly improved comparing with single Ni-B coating. The Ni-B-10 g/L TiO2/Ni coating was found to have the best corrosion resistance among these duplex coatings. This type of duplex Ni-B-TiO2/Ni coating, with high hardness and good corrosion resistance properties, should be able to find broad applications under adverse environmental conditions.

  18. NUMERICAL MODELING OF HARDENING OF UNINTERRUPTEDLY-CASTED BRONZE CASTING

    Directory of Open Access Journals (Sweden)

    E. I. Marukovich

    2009-01-01

    Full Text Available The three-dimensional numerical model for calculation of thermal fields during solidification of continuously casted bronze casting is developed. Coefficients of heat transfer on borders of calculation areas on the basis of the solution of inverse heat transfer conduction problem are determined. The analysis of thermal fields, depending on loop variables of drawing and the sizes of not cooled zone of crystallizer is curried out.

  19. Modelling of flow phenomena during DC casting

    NARCIS (Netherlands)

    Zuidema, J.

    2005-01-01

    Modelling of Flow Phenomena during DC Casting Jan Zuidema The production of aluminium ingots, by semi-continuous casting, is a complex process. DC Casting stands for direct chill casting. During this process liquid aluminium transforms to solid aluminium while cooling down. This is not an instanta

  20. Hybridization accompanying FRET event in labeled natural nucleoside-unnatural nucleoside containing chimeric DNA duplexes.

    Science.gov (United States)

    Bag, Subhendu Sekhar; Das, Suman K; Pradhan, Manoj Kumar; Jana, Subhashis

    2016-09-01

    Förster resonance energy transfer (FRET) is a highly efficient strategy in illuminating the structures, structural changes and dynamics of DNA, proteins and other biomolecules and thus is being widely utilized in studying such phenomena, in designing molecular/biomolecular probes for monitoring the hybridization event of two single stranded DNA to form duplex, in gene detection and in many other sensory applications in chemistry, biology and material sciences. Moreover, FRET can give information about the positional status of chromophores within the associated biomolecules with much more accuracy than other methods can yield. Toward this end, we want to report here the ability of fluorescent unnatural nucleoside, triazolylphenanthrene ((TPhen)BDo) to show FRET interaction upon hybridization with fluorescently labeled natural nucleosides, (Per)U or (OxoPy)U or (Per)U, forming two stable chimeric DNA duplexes. The pairing selectivity and the thermal duplex stability of the chimeric duplexes are higher than any of the duplexes with natural nucleoside formed. The hybridization results in a Förster resonance energy transfer (FRET) from donor triazolylphenanthrene of (TPhen)BDo to acceptor oxopyrene of (OxoPy)U and/or to perylene chromophore of (Per)U, respectively, in two chimeric DNA duplexes. Therefore, we have established the FRET process in two chimeric DNA duplexes wherein a fluorescently labeled natural nucleoside ((OxoPy)U or (Per)U) paired against an unnatural nucleoside ((TPhen)BDo) without sacrificing the duplex stability and B-DNA conformation. The hybridization accompanying FRET event in these classes of interacting fluorophores is new. Moreover, there is no report of such designed system of chimeric DNA duplex. Our observed phenomenon and the design can potentially be exploited in designing more of such efficient FRET pairs for useful application in the detection and analysis of biomolecular interactions and in material science application.

  1. Interfacial Phenomena in Fe/Stainless Steel-TiC Systems and the Effect of Mo

    Science.gov (United States)

    Kiviö, Miia; Holappa, Lauri; Yoshikawa, Takeshi; Tanaka, Toshihiro

    2014-12-01

    Titanium carbide is used as reinforcement particles in composites due to its hardness, wear resistance and stability. This work is a part of the study in which titanium carbides are formed in stainless steel castings in the mold to improve the wear resistance of a certain surface of the casting. Such local reinforcement is a very potential method but it is a quite demanding task requiring profound knowledge of interfacial phenomena in the system, wettability, stability, dissolution and precipitation of new phases in production of these materials. Good wetting between different constituents in the material is a key factor to attain maximal positive effects. Mo is used with TiC or Ti(C,N) reinforcement in composites to improve wettability. In this work the effect of Mo on the phenomena in Fe/stainless steel-TiC systems was examined by wetting experiments between the substrate and the alloy. Wetting was not significantly improved by adding Mo to the systems. Core-rim type carbides as well as more homogenous carbide particles were observed. Overall the carbide particles are very complex regarding to their chemistry, size and shape which aspects have to be taken into account in the development of these materials and manufacturing processes.

  2. Stainless Steel to Titanium Bimetallic Transitions

    Energy Technology Data Exchange (ETDEWEB)

    Kaluzny, J. A. [Fermilab; Grimm, C. [Fermilab; Passarelli, D. [Fermilab

    2015-01-01

    In order to use stainless steel piping in an LCLS-II (Linac Coherent Light Source Upgrade) cryomodule, stainless steel to titanium bimetallic transitions are needed to connect the stainless steel piping to the titanium cavity helium vessel. Explosion bonded stainless steel to titanium transition pieces and bimetallic transition material samples have been tested. A sample transition tube was subjected to tests and x-ray examinations between tests. Samples of the bonded joint material were impact and tensile tested at room temperature as well as liquid helium temperature. The joint has been used successfully in horizontal tests of LCLS-II cavity helium vessels and is planned to be used in LCLS-II cryomodules. Results of material sample and transition tube tests will be presented.

  3. Duplex Stirling gas fired heating only heat pump

    Science.gov (United States)

    Beale, W.

    1982-03-01

    In phase I the Duplex Stirling Gas fired Heat Pump was analyzed with the aid of the Sunpower third order simulation and optimization code and found to show heating COP of 1.7 at the rating point of 8 C (17 F) with a heat delivery of 10 kW. Also it was found that a direct heat exchange between working fluid and source and sink air was consistent with high COP in the heat pump, thus eliminating the need for an intermediate heat transfer fluid and its associated pumps and controls. Further, it was demonstrated in the simulation that the heat engine power output could be matched to the heat pump load over the range of source temperatures without need of complex control systems. Cost estimates, along with COP figures from the analysis indicated a payback time of 2 to 4 years in completion with existing combustion heating systems in northern climates.

  4. Current status of duplex surface engineered Ti-based materials

    Institute of Scientific and Technical Information of China (English)

    T.Bell

    2004-01-01

    Industrial exploitation of the high specific strength and corrosion resistance of titanium were dominated historically by the technological advances which have been made in gas-turbine engine and aircraft components. Realization of the possible benefits in general engineering has been limited by the absence of any proven and reliable means of overcoming the poor wear resistance and galling tendency suffered by titanium alloys when in contact with other materials. This problem can only be addressed by optimizing and demonstrating industrially viable surface engineering processes for titanium in general engineering. The status of single and duplex surface engineering systems are reviewed. In addition, in order to fully realize the potential of advanced surface engineering of titanium components contact mechanics models are developed to enable the automotive engineers to design dynamically the loaded automotive engine and transmission components.

  5. Technology of Welding Joints Mixed with Duplex Steel

    Directory of Open Access Journals (Sweden)

    Słania J.

    2016-03-01

    Full Text Available Results of the examinations of sample plates of mixed joints with the duplex steel were discussed. Examinations were taken on the sample plates of mixed joints of sheet plates type P355NL1 and X2CrNiMoN22-5-3 welded by the flux-cored wire DW-329A by the Kobelco company of the following category T 22 9 3 NL RC/M3 in the gas shroud M21 (Ar+18%CO2 (plate no.1, and nickel covered electrodes E Ni 6082 by the Böhler company (plate no. 2. Results of the side bend test of welded joint, transverse tensile test, stretching of the weld metal, impact strength, micro and macroscopic metallographic examinations, and measurements of the delta ferrite content were presented.

  6. The Modern Applications of Surface Duplex Treatment Technology

    Institute of Scientific and Technical Information of China (English)

    JerzySmolik; JanWalkowicz; AdamMazurkiewicz; JerzyTomaszewski

    2004-01-01

    The paper presents results of the research carried out by the authors in different fields of plasma surface technologies applications. Three groups of different surface engineering technologies are shown in the paper. The first one concerns the possibility of using the duplex treatment technology for creation of biocompatible diamond-like a-C:H films. The paper presents research results concerning influence of the process parameters of the a-C:H coatings creation by means of the RFPACVD method in the pure methane amlosphere on their phase structure and mechanical properties. In the second case authors present the concept of a new special multilayer thermal barrier coatings with the PAPVD diffusion barrier layers based on aluminium oxide. As the last one the special application of plasma techniques for creation of composite materials characterized by the muffling of mechanical vibration was presented.

  7. The Modern Applications of Surface Duplex Treatment Technology

    Institute of Scientific and Technical Information of China (English)

    Jerzy Smolik; Jan Walkowicz; Adam Mazurkiewicz; Jerzy Tomaszewski

    2004-01-01

    The paper presents results of the research carried out by the authors in different fields of plasma surface technologies applications. Three groups of different surface engineering technologies are shown in the paper. The first one concerns the possibility of using the duplex treatment technology for creation of biocompatible diamond-like a-C:H films.The paper presents research results concerning influence of the process parameters of the a-C:H coatings creation by means of the RF PACVD method in the pure methane atmosphere on their phase structure and mechanical properties. In the second case authors present the concept of a new special multilayer thermal barrier coatings with the PAPVD diffusion barrier layers based on aluminium oxide. As the last one the special application of plasma techniques for creation of composite materials characterized by the muffling of mechanical vibration was presented.

  8. Full Duplex Wireless Communications for Cognitive Radio Networks

    CERN Document Server

    Cheng, Wenchi; Zhang, Hailin

    2011-01-01

    As a key in cognitive radio networks (CRNs), dynamic spectrum access needs to be carefully designed to minimize the interference and delay to the \\emph{primary} (licensed) users. One of the main challenges in dynamic spectrum access is to determine when the \\emph{secondary} (unlicensed) users can use the spectrum. In particular, when the secondary user is using the spectrum, if the primary user becomes active to use the spectrum, it is usually hard for the secondary user to detect the primary user instantaneously, thus causing unexpected interference and delay to primary users. The secondary user cannot detect the presence of primary users instantaneously because the secondary user is unable to detect the spectrum at the same time while it is transmitting. To solve this problem, we propose the full duplex wireless communications scheme for CRNs. In particular, we employ the Antennas Cancellation (AC), the RF Interference Cancellation (RIC), and the Digital Interference Cancellation (DIC) techniques for second...

  9. High Density Die Casting (HDDC): new frontiers in the manufacturing of heat sinks

    Science.gov (United States)

    Sce, Andrea; Caporale, Lorenzo

    2014-07-01

    Finding a good solution for thermal management problems is every day more complex. due to the power density and the required performances. When a solution suitable for high volumes is needed. die-casting and extrusion are the most convenient technologies. However designers have to face the well-known limitations for those processes. High Density Die Casting (HDDC) is a process under advanced development. in order to overcome the extrusion and traditional die casting limits by working with alloys having much better thermal performances than the traditional die-casting process. while keeping the advantages of a flexible 3D design and a low cost for high volumes. HDDC offers the opportunity to design combining different materials (aluminium and copper. aluminium and stainless steel) obtaining a structure with zero porosity and overcoming some of die-casting limits. as shown in this paper. A dedicated process involving embedded heat pipes is currently under development in order to offer the possibility to dramatically improve the heat spreading.

  10. Duplex Doppler ultrasound study of the temporomandibular joint.

    Science.gov (United States)

    Stagnitti, A; Marini, A; Impara, L; Drudi, F M; Lo Mele, L; Lillo Odoardi, G

    2012-06-01

    Sommario INTRODUZIONE: La fisiologia articolare dell’articolazione temporo-mandibolare (ATM) può essere esaminata sia dal punto di vista clinico che strumentale. La diagnostica per immagini ha da tempo contribuito con la risonanza magnetica (RM) e anche con la radiografia (Rx) e la tomografia computerizzata (TC) all’analisi della morfologia dei capi articolari e della cinetica condilare. L’esame duplex-ecodoppler è una metodica di largo impiego nello studio delle strutture in movimento in particolar modo a livello delle strutture del sistema vascolare. MATERIALI E METODI: È stata utilizzata un’apparecchiatura Toshiba APLIO SSA-770A, con l’uso di tecnica duplex-ecodoppler multi display, che consente la visualizzazione contemporanea dell’immagine ecografica e dei segnali Doppler utilizzando una sonda lineare del tipo phased array con cristalli trasduttori funzionanti ad una frequenza fondamentale di 6 MHz per gli spettri Doppler pulsati e 7.5 MHz per l’imaging ecografico. Sono stati esaminati nel Dipartimento di Scienze Radiologiche, Oncologiche e Anatomo-patologiche dell’Università “Sapienza” di Roma, 30 pazienti del reparto di Ortognatodonzia dell’Istituto di Odontoiatria della stessa Università. RISULTATI: Nei pazienti normali si è ottenuta un’alternanza regolare degli spettri Doppler, mentre nei soggetti con disfunzioni del complesso condilo-meniscale, si è persa la regolarità della sommatoria degli spettri di Fourier, con altezze incostanti in relazione a spostamenti irregolari del complesso condilo-meniscale. CONCLUSIONI: L’esame ecodoppler si è dimostrato, in tutti i pazienti, capace di discriminare quelli normali dai patologici e tra questi ultimi ha permesso di identificare gli aspetti più significativi delle patologie disfunzionali.

  11. Detection of Hepatitis B Virus DNA by Duplex Scorpion Primer-based PCR Assay

    Institute of Scientific and Technical Information of China (English)

    KONG De-Ming孔德明; SHEN Han-Xi沈含熙; MI Huai-Feng宓怀风

    2004-01-01

    The application of a new fiuorogenic probe-based PCR assay (PCR duplex scorpion primer assay) to the detection of Hepatitis B virus (HBV) DNA in human sera was described. Duplex scorpion primer is a modified variant of duplex Amplifluor, and the incorporation of a PCR stopper between probe and primer sequences improve the detection specificity and sensitivity. Combined with PCR amplification, this probe can give unambiguous positive results for the reactions initiated with more than 20 HBV molecules. In addition, the particular unimolecular probing mechanism of this probe makes the use of short target-specific probe sequence possible, which will render this probe applicable in some specific systems.

  12. Casting Using A Polystyrene Pattern

    Science.gov (United States)

    Vasquez, Peter; Guenther, Bengamin; Vranas, Thomas; Veneris, Peter; Joyner, Michael

    1993-01-01

    New technique for making metal aircraft models saves significant amount of time and effort in comparison with conventional lost-wax method. Produces inexpensive, effective wind-tunnel models. Metal wind-tunnel model cast by use of polystyrene pattern.

  13. The CAST Time Projection Chamber

    CERN Document Server

    Autiero, D; Cébrian, S; Carmona, J M; Chesi, Enrico Guido; Davenport, M; Delattre, M; Di Lella, L; Formenti, F; Gomez, H; Hasinoff, M; Irastorza, I G; Lakic, B; Luzón, G; Morales, J; Musa, L; Ortiz, A; Placci, A; Rodríguez, A; Ruz, J; Villar, J A; Zioutas, K

    2007-01-01

    One of the three X-ray detectors of the CAST experiment searching for solar axions is a Time Projection Chamber (TPC) with a multi-wire proportional counter (MWPC) as a readout structure. Its design has been optimized to provide high sensitivity to the detection of the low intensity X-ray signal expected in the CAST experiment. A low hardware threshold of 0.8 keV is safely set during normal data taking periods, and the overall efficiency for the detection of photons coming from conversion of solar axions is 62 %. Shielding has been installed around the detector, lowering the background level to 4.10 x 10^-5 counts/cm^2/s/keV between 1 and 10 keV. During phase I of the CAST experiment the TPC has provided robust and stable operation, thus contributing with a competitive result to the overall CAST limit on axion-photon coupling and mass.

  14. Some Theoretical Considerations on Caste

    Directory of Open Access Journals (Sweden)

    Madhusudan Subedi

    2014-05-01

    Full Text Available Caste as a system of social stratification was an encompassing system in the past. There was reciprocal system of exchange goods and services. With time, occupation and mode of generation of livelihood of various caste groups changed, and the traditional form of jajmani system fizzled out. This paper provides an account of changing perspectives of caste relations in social science writing and political discourse. The discourse of caste has been shifted from ritual hierarchy and social discrimination to an instrument to mobilize people for economic and political gain. DOI: http://dx.doi.org/10.3126/dsaj.v7i0.10437 Dhaulagiri Journal of Sociology and Anthropology Vol. 7, 2013; 51-86

  15. Natural clinoptilolite composite membranes on tubular stainless steel supports for water softening.

    Science.gov (United States)

    Adamaref, Solmaz; An, Weizhu; Jarligo, Maria Ophelia; Kuznicki, Tetyana; Kuznicki, Steven M

    2014-01-01

    Disk membranes generated from high-purity natural clinoptilolite mineral rock have shown promising water desalination and de-oiling performance. In order to scale up production of these types of membranes for industrial wastewater treatment applications, a coating strategy was devised. A composite mixture of natural clinoptilolite from St. Cloud (Winston, NM, USA) and aluminum phosphate was deposited on the inner surface of porous stainless steel tubes by the slip casting technique. The commercial porous stainless steel tubes were pre-coated with a TiO2 layer of about 10 μm. Phase composition and morphology of the coating materials were investigated using X-ray diffraction and scanning electron microscopy. Water softening performance of the fabricated membranes was evaluated using Edmonton (Alberta, Canada) municipal tap water as feed source. Preliminary experimental results show a high water flux of 7.7 kg/(m(2) h) and 75% reduction of hardness and conductivity in a once-through membrane process at 95 °C and feed pressure of 780 kPa. These results show that natural zeolite coated, stainless steel tubular membranes have high potential for large-scale purification of oil sands steam-assisted gravity drainage water at high temperature and pressure requirements.

  16. Microstructures and properties of welded joint of TiNi shape memory alloy and stainless steel

    Institute of Scientific and Technical Information of China (English)

    邱小明; 孙大谦; 李明高; 刘卫红

    2004-01-01

    The fracture characteristics of the joint were analyzed by means of scanning electron microscope(SEM).Microstructures of the joint were examined by means of optical microscope, SEM and an image analyzer. The results show that the tensile strength of the inhomogeneous joint of TiNi shape memory alloy and stainless steel is lower than that of the homogeneous joint and a plastic field appears in the heat affected zone on the side of TiNi shape memory alloy. Because TiNi shape memory alloy and stainless steel melted, a brittle as-cast structure was formed in the weld. The tensile strength and the shape memory effect of the inhomogeneous joint are strongly influenced by the changes of composition and structure of the joint. Measures should be taken to reduce the base metal melting and prevent the weld metal from the invasion by O for improving the properties of the TiNi shape memory alloy and stainless steel inhomogeneous joint.

  17. Stainless steel grafting of hyperbranched polymer brushes with an antibacterial activity: synthesis, characterization, and properties.

    Science.gov (United States)

    Ignatova, Milena; Voccia, Samule; Gabriel, Sabine; Gilbert, Bernard; Cossement, Damien; Jerome, Robert; Jerome, Christine

    2009-01-20

    Two strategies were used for the preparation of hyperbranched polymer brushes with a high density of functional groups: (a) the cathodic electrografting of stainless steel by poly[2-(2-chloropropionate)ethyl acrylate] [poly(cPEA)], which was used as a macroinitiator for the atom transfer radical polymerization of an inimer, 2-(2-bromopropionate)ethyl acrylate in the presence or absence of heptadecafluorodecyl acrylate, (b) the grafting of preformed hyperbranched poly(ethyleneimine) onto poly(N-succinimidyl acrylate) previously electrografted onto stainless steel. The hyperbranched polymer, which contained either bromides or amines, was quaternized because the accordingly formed quaternary ammonium or pyridinium groups are known for antibacterial properties. The structure, chemical composition, and morphology of the quaternized and nonquaternized hyperbranched polymer brushes were characterized by ATR-FTIR reflectance, Raman spectroscopy, X-ray photoelectron spectroscopy, and atomic force microscopy. The peeling test confirmed that the grafted hyperbranched polymer films adhered much more strongly to stainless steel than the nongrafted solvent-cast films. The quaternized hyperbranched polymer brushes were more effective in preventing both protein adsorption and bacterial adhesion than quaternary ammonium containing poly(cPEA) primary films, more likely because of the higher hydrophilicity and density of cationic groups.

  18. Inoculation of chromium white cast iron

    Directory of Open Access Journals (Sweden)

    D. Kopyciński

    2009-01-01

    Full Text Available It has been proved that an addition of boron carbide introduced as an inoculant to the chromium white cast iron changes the structureof castings. Castings after inoculation revealed a different structure with numerous grains. Primary precipitates of chromium carbide also appeared, reducing the mechanical properties of as-cast parts. Properly established heat treatment regime makes chromium iron castings regain their, originally high, mechanical properties.

  19. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2011-01-01

    @@ Vermicular graphite cast iron(VG iron for short in the following sections)is a type of cast iron in which the graphite is intermediate in shape between flake and spheroidal.Compared with the normal flake graphite in grey iron, the graphite in VG iron is shorter and thicker and shows a curved, more rounded shape.Because its outer contour is exactly like a worm, hence it is called vermicular graphite.

  20. Agile Manufacturing Development of Castings

    Science.gov (United States)

    2007-11-02

    responsible for con- verting the available 2D CATIA casting design into a 3D Pro/Engineering geometric model of the casting, for use by Clinkenbeard...changes to the draw- ings. MWM. As the part designer, MWM reviewed and evalu- ated proposed changes to the design. MWM also updated the CATIA ...creation of solid models of the cores and molds, using IGES translations of the CATIA files secured from MWM through GE Transportation Sys- tems. Due

  1. Mechanical Performances of Carbonitriding Films on Cast Iron by Plasma Electrolytic Carbonitriding

    Institute of Scientific and Technical Information of China (English)

    PANG Hua; ZHANG Gu-Ling; WANG Xing-Quan; LV Guo-Hua; CHEN Huan; YANG Si-Ze

    2011-01-01

    The plasma electrolytic carbonitriding (PEC/N) process is applied to cast iron using an aqueous solution of acetamide and glycerin as the electrolyte. Mechanical properties of the carbonitriding layers on cast iron are investigated. After the PEC/N treatment, the microhardness and wear resistance of cast iron are improved significantly compared to the untreated substrate. When the substrate is processed at 350 V for 60s, the coating presents the highest microhardness and it is about 554.14HK0.02, and the coating with the highest hardness has the best wear resistance.%The plasma electrolytic carbonitriding (PEC/N) process is applied to cast iron using an aqueous solution of acetamide and glycerin as the electrolyte.Mechanical properties of the carbonitriding layers on cast iron are investigated.After the PEC/N treatment,the microhardness and wear resistance of cast iron are improved significantly compared to the untreated substrate.When the substrate is processed at 350 V for 60s,the coating presents the highest microhardness and it is about 554.14HK0.02,and the coating with the highest hardness has the best wear resistance.Plasma electrolytic saturation (PES) is a relatively novel surface engineering technique,which operates at room temperature and atmospheric pressure.[1-3]It includes plasma electrolytic carburizing (PEC),[4,5]plasma electrolytic nitriding (PEN)[6] and plasma electrolytic carbonitriding (PEC/N).[7-10] The relatively unrestrained size and shape,and shorter treatment time compared to vacuum-plasma processes make the PES a desirable and flexible technique for industrial use.The PES treatments on low carbon steel,[11] stainless steel[3,12] and pure iron[13] have been investigated.Researchers studied the microstructure,phase composition,corrosion resistance,microhardness and wear performance of the PES-treated samples.It was found that the diffusion of N into stainless steels can improve the corrosion resistance of stainless steels,[14] while the

  2. Energy Saving Melting and Revert Reduction Technology (Energy-SMARRT): Clean Steel Casting Production

    Energy Technology Data Exchange (ETDEWEB)

    Kuyucak, Selcuk [CanmetMATERIALS; Li, Delin [CanmetMATERIALS

    2013-12-31

    Inclusions in steel castings can cause rework, scrap, poor machining, and reduced casting performance, which can obviously result in excess energy consumption. Significant progress in understanding inclusion source, formation and control has been made. Inclusions can be defined as non-metallic materials such as refractory, sand, slag, or coatings, embedded in a metallic matrix. This research project has focused on the mold filling aspects to examine the effects of pouring methods and gating designs on the steel casting cleanliness through water modeling, computer modeling, and melting/casting experiments. Early in the research project, comprehensive studies of bottom-pouring water modeling and low-alloy steel casting experiments were completed. The extent of air entrainment in bottom-poured large castings was demonstrated by water modeling. Current gating systems are designed to prevent air aspiration. However, air entrainment is equally harmful and no prevention measures are in current practice. In this study, new basin designs included a basin dam, submerged nozzle, and nozzle extension. The entrained air and inclusions from the gating system were significantly reduced using the new basin method. Near the end of the project, there has been close collaboration with Wescast Industries Inc., a company manufacturing automotive exhaust components. Both computer modeling using Magma software and melting/casting experiments on thin wall turbo-housing stainless steel castings were completed in this short period of time. Six gating designs were created, including the current gating on the pattern, non-pressurized, partially pressurized, naturally pressurized, naturally pressurized without filter, and radial choke gating without filter, for Magma modeling. The melt filling velocity and temperature were determined from the modeling. Based on the simulation results, three gating designs were chosen for further melting and casting experiments on the same casting pattern using

  3. Transcranial duplex doppler ultrasonography in dogs with hydrocephalus Ultrassonografia duplex Doppler transcraniana em cães com hidrocefalia

    Directory of Open Access Journals (Sweden)

    C.F. Carvalho

    2010-02-01

    Full Text Available Transcranial duplex Doppler ultrasound was performed in 32 conscious dogs presenting ventriculomegaly detected in B-mode, obtaining measures of lateral ventricles and resistance parameters of main cerebral arteries before and after 30 days of clinical treatment. The animals were distributed divided in two groups: group 1, dogs that presented remission or decrease of the neurological signs of the disease after clinical therapy; and group 2, dogs that displayed worsening of the neurological signs or clinical stability. The data were all presented in tables and were submitted to paired t test and to logistic regression models to evaluate the influence of the RI reduction on both groups. There was no significant influence of the variables in the B-mode. After the treatment, the mean resistive index (RI was significantly lower for the group that presented clinical improvement. There was no significant difference of the mean RI reduction for the same artery when the right and left sides were compared. It could be concluded that transcranial duplex Doppler ultrasound is a method of cerebral hemodynamic assessment able to monitor more precisely the treatment of hydrocephalus in dogs and verify the responses.Foi realizada a ultrassonografia duplex Doppler transcraniana em 32 cães, conscientes, que apresentavam ventriculomegalia previamente detectada ao exame modo-B, para obter as medidas dos ventrículos laterais e os parâmetros de resistência das artérias cerebrais antes e depois de 30 dias de tratamento clínico. Os animais foram distribuídos em dois grupos: 1 - formado por cães que apresentaram remissão ou diminuição dos sinais clínicos após tratamento; 2 - por cães que apresentaram piora dos sinais neurológicos ou estabilidade do quadro clínico. Todos os dados foram dispostos em tabelas e submetidos ao teste t pareado e a modelos de regressão logística para avaliar a influência da redução do índice de resistividade (IR. Não foi

  4. Light metal compound casting

    Institute of Scientific and Technical Information of China (English)

    Konrad; J.; M.; PAPIS; Joerg; F.; LOEFFLER; Peter; J.; UGGOWITZER

    2009-01-01

    ‘Compound casting’simplifies joining processes by directly casting a metallic melt onto a solid metal substrate. A continuously metallurgic transition is very important for industrial applications, such as joint structures of spaceframe constructions in transport industry. In this project, ‘compound casting’ of light metals is investigated, aiming at weight-saving. The substrate used is a wrought aluminium alloy of type AA5xxx, containing magnesium as main alloying element. The melts are aluminium alloys, containing various alloying elements (Cu, Si, Zn), and magnesium. By replacing the natural oxygen layer with a zinc layer, the inherent wetting difficulties were avoided, and compounds with flawless interfaces were successfully produced (no contraction defects, cracks or oxides). Electron microscopy and EDX investigations as well as optical micrographs of the interfacial areas revealed their continu- ously metallic constitution. Diffusion of alloying elements leads to heat-treatable microstructures in the vicinity of the joining interfaces in Al-Al couples. This permits significant variability of mechanical properties. Without significantly cutting down on wettability, the formation of low-melting intermetallic phases (Al3Mg2 and Al12Mg17 IMPs) at the interface of Al-Mg couples was avoided by applying a protective coating to the substrate.

  5. EVOLUTION OF AS-CAST MICROSTRUCTURES OF 356 ALUMINIUM ALLOY CAST BY LIQUIDUS CASTING

    Institute of Scientific and Technical Information of China (English)

    J. Dong; G.M. Lu; J.Z. Cui; Z.H. Zhao

    2003-01-01

    A new method (liquidus casting) was used for 356 Al alloy semi-solid slurry mak-ing. The structures of 356 Al alloy cast by a Fe mould and semi-continuous castingmachine at different temperatures were investigated. How the globular grains formwas also discussed. The results show that either being cast by single Fe mould orsemi-continuous machine, the microstructures are not conventional dendrites but fineand net-globular grains. The average grain size is smaller than 30μm and suitableenough for thixoforming, meanwhile it can improve the mechanical properties of fol-lowing products. Under the suitable casting velocity and cooling intensity, most ofglobal grains prolong their global growth and collide with each other before dendriticgrowth because of the large amount of the nucleation sites.

  6. High Mn austenitic stainless steel

    Science.gov (United States)

    Yamamoto, Yukinori [Oak Ridge, TN; Santella, Michael L [Knoxville, TN; Brady, Michael P [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Liu, Chain-tsuan [Knoxville, TN

    2010-07-13

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  7. Electrochemical Investigation of Interaction between a Bifunctional Probe and GG Mismatch Duplex.

    Science.gov (United States)

    Li, Jiao; He, Hanping; Peng, Xiaoqian; Huang, Min; Zhang, Xiuhua; Wang, Shengfu

    2015-01-01

    A bifunctional probe (FecNC), containing a recognition part and an electrochemical active center, was applied to electrochemical detection of GG mismatch duplexes. The preparation of gold electrodes modified by mismatch and complementatry duplexes was characterized by electrochemical impedance spectroscopy (EIS) and optimized for better detection in terms of self-assembly time, hybridization time, and incubation time. The interaction between FecNC and DNA duplexes modified on the surface of a gold electrode was explored by square wave voltammetry (SWV) and EIS. The results showed that the DNA duplexes with GG mismatch on the surface of a gold electrode was easily detected by the largest electrochemical signal of the bifunctional probe because of its selective binding to GG mismatches. The bifunctional probe could offer a simple, effective electrochemical detection of GG mismatches, and theoretical bases for development of electrochemical biosensors. Further, the method would be favorable for diagnosis of genetic diseases.

  8. Rapid method to detect duplex formation in sequencing by hybridization methods

    Science.gov (United States)

    Mirzabekov, A.D.; Timofeev, E.N.; Florentiev, V.L.; Kirillov, E.V.

    1999-01-19

    A method for determining the existence of duplexes of oligonucleotide complementary molecules is provided. A plurality of immobilized oligonucleotide molecules, each of a specific length and each having a specific base sequence, is contacted with complementary, single stranded oligonucleotide molecules to form a duplex. Each duplex facilitates intercalation of a fluorescent dye between the base planes of the duplex. The invention also provides for a method for constructing oligonucleotide matrices comprising confining light sensitive fluid to a surface and exposing the light-sensitive fluid to a light pattern. This causes the fluid exposed to the light to coalesce into discrete units and adhere to the surface. This places each of the units in contact with a set of different oligonucleotide molecules so as to allow the molecules to disperse into the units. 13 figs.

  9. Two-flux transfer matrix model for predicting the reflectance and transmittance of duplex halftone prints.

    Science.gov (United States)

    Mazauric, Serge; Hébert, Mathieu; Simonot, Lionel; Fournel, Thierry

    2014-12-01

    We introduce a model allowing convenient calculation of the spectral reflectance and transmittance of duplex prints. It is based on flux transfer matrices and enables retrieving classical Kubelka-Munk formulas, as well as extended formulas for nonsymmetric layers. By making different assumptions on the flux transfers, we obtain two predictive models for the duplex halftone prints: the "duplex Clapper-Yule model," which is an extension of the classical Clapper-Yule model, and the "duplex primary reflectance-transmittance model." The two models can be calibrated from either reflectance or transmittance measurements; only the second model can be calibrated from both measurements, thus giving optimal accuracy for both reflectance and transmittance predictions. The conceptual differences between the two models are deeply analyzed, as well as their advantages and drawbacks in terms of calibration. According to the test carried out in this study with paper printed in inkjet, their predictive performances are good provided appropriate calibration options are selected.

  10. Structural basis for duplex RNA recognition and cleavage by Archaeoglobus fulgidus C3PO

    Science.gov (United States)

    Parizotto, Eneida A; Lowe, Edward D; Parker, James S

    2013-01-01

    Oligomeric complexes of Trax and Translin proteins, known as C3POs, participate in a variety of eukaryotic nucleic acid metabolism pathways including RNAi and tRNA processing. In RNAi in humans and Drosophila, C3PO activates pre-RISC by removing the passenger strand of the siRNA precursor duplex using nuclease activity present in Trax. It is not known how C3POs engage with nucleic acid substrates. Here we identify a single protein from Archaeoglobus fulgidus that assembles into an octamer with striking similarity to human C3PO. The structure in complex with duplex RNA reveals that the octamer entirely encapsulates a single thirteen base-pair RNA duplex inside a large inner cavity. Trax-like subunit catalytic sites target opposite strands of the duplex for cleavage, separated by seven base pairs. The structure provides insight into the mechanism of RNA recognition and cleavage by an archaeal C3PO-like complex. PMID:23353787

  11. Can Full Duplex reduce the discovery time in D2D Communication?

    DEFF Research Database (Denmark)

    Gatnau, Marta; Berardinelli, Gilberto; Mahmood, Nurul Huda;

    2016-01-01

    Device-to-device (D2D) communication is considered as one of the key technologies to support new types of services, such as public safety and proximity-based applications. D2D communication requires a discovery phase, i.e., the node awareness procedure prior to the communication phase. Conventional...... half duplex transmission may not be sufficient to provide fast discovery and cope with the strict latency targets of future 5G services. On the other hand, in-band full duplex, by allowing simultaneous transmission and reception, may complete the discovery phase faster. In this paper, the potential...... of full duplex in providing fast discovery for the next 5th generation (5G) system supporting D2D communication is investigated. A design for such system is presented and evaluated via simulations, showing that full duplex can accelerate the discovery phase by supporting a higher transmission probability...

  12. Microstructure and Properties of SAE 2205 Stainless Steel After Salt Bath Nitrocarburizing at 450 °C

    Science.gov (United States)

    Yan, Jing; Wang, Jun; Lin, Yuanhua; Gu, Tan; Zeng, Dezhi; Huang, Runbo; Ji, Xiong; Fan, Hongyuan

    2014-04-01

    Nitrocarburizing of the type SAE 2205 duplex stainless steel was conducted at 450 °C, using a type of salt bath chemical surface treatment, and the microstructure and properties of the nitrided surface were systematically researched. Experimental results revealed that a modified layer transformed on the surface of samples with the thickness ranging from 3 to 28 μm changed with the treatment time. After 2205 duplex stainless steel was subjected to salt bath nitriding at 450 °C for time less than 8 h, the preexisting ferrite zone in the surface transformed into austenite by active nitrogen diffusion. The main phase of the nitrided layer was the expanded austenite. When the treatment time was extended to 16 h, the preexisting ferrite zone in the expanded austenite was decomposed and transformed partially into ɛ-nitride precipitate. When the treatment time extended to 40 h, the preexisting ferrite zone in the expanded austenite was transformed into ɛ-nitride and CrN precipitate. Further, a large amount of nitride precipitated from preexisting austenite zone. The nitrided layer depth thickness changed intensively with the increasing nitriding time. The growth of the nitride layer takes place mainly by nitrogen diffusion according to the expected parabolic rate law. The salt bath nitriding can effectively improve the surface hardness. The maximum values measured from the treated surface are observed to be approximately 1400 HV0.1 after 8 h, which is about 3.5 times as hard as the untreated material (396 HV0.1). Low-temperature nitriding can improve the erosion/corrosion resistance. After nitriding for 4 h, the sample has the best corrosion resistance.

  13. Effect of reversion treatment on strength and ductility of low C, Cr-Ni martensitic stainless steel with high resistance to weld softening. Yosetsu nanka teiko no takai teitanso Cr-Ni maruten saito kei stainless ko no kyodo, ensei ni oyobosu gyaku hentai shori no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Igawa, T.; Takemoto, T.; Uematsu, Y. (Nisshin Steel Co. Ltd., Tokyo (Japan). Steel R and D Lab.); Hoshino, K. (Nisshin Steel Co. Ltd., Tokyo (Japan))

    1993-08-01

    Like the stainless steel and the stainless steel belt used in the rolling stock, materials treated by process and weld has a high strength and a good ductility, moreover, was expected that weld softening would not occurred. In this study, formation of the ultra-fine crystal grains based on the M to [gamma] reversion transformation of low C, Cr-Ni martensitic stainless steel and effect of Si on change of mechanical properties were investigated. A high-strength stainless steel with a good ductility and without weld softening was developed. Main results obtained are as follows: After a steel was cold-rolled, the reversion treatment at the region between As and Af temperatures (600 to 640[degree]C) was carried out, a duplex structure with diameter of the ultra-fine grains of about 0.5 micron meter that is composed of [gamma] phase concentrated Ni and sintered M phase was formatted, and excellent mechanical properties with a high strength and a good ductility could be obtained, diameter of reversion [gamma] grains was dependent on reversion temperature. Diameter of [gamma] grains became large, and more homogeneous and uniform at higher reversion temperature. 20 refs., 11 figs., 2 tabs.

  14. The fabrication of a vanadium-stainless steel test section for MHD testing of insulator coatings in flowing lithium

    Energy Technology Data Exchange (ETDEWEB)

    Reed, C.B.; Mattas, R.F.; Smith, D.L.; Chung, H.; Tsai, H.-C. [Argonne National Lab., IL (United States); Morgan, G.D.; Wille, G.W. [McDonnell Douglas Aerospace, St. Louis, MO (United States). High Energy Systems; Johnson, W.R. [General Atomics, San Diego, CA (United States); Young, C. [Century Tubes, Inc., San Diego, CA (United States)

    1996-12-31

    To test the magnetohydrodynamic (MHD) pressure drop reduction performance of candidate insulator coatings for the ITER Vanadium/Lithium Breeding Blanket, a test section comprised of a V- 4Cr-4Ti liner inside a stainless steel pipe was designed and fabricated. Theoretically, the MHD pressure drop reduction benefit resulting, from an electrically insulating coating on a vanadium- lined pipe is identical to the benefit derived from an insulated pipe fabricated of vanadium alone. A duplex test section design consisting of a V alloy liner encased in a SS pressure boundary provided protection for vanadium from atmospheric contamination during operation at high temperature and obviated any potential problems with vanadium welding while also minimizing the amount of V alloy material required. From the MHD and insulator coating- point of view, the test section outer SS wall and inner V alloy liner can be modeled simply as a wall having a sandwich construction. Two 52.3 mm OD x 2.9 m long V-alloy tubes were fabricated by Century Tubes from 64 mm x 200 mm x 1245 mm extrusions produced by Teledyne Wah Chang. The test section`s duplex structure was subsequently fabricated at Century Tubes by drawing down a SS pipe (2 inch schedule 10) over one of the 53.2 mm diameter V tubes.

  15. Low Temperature Surface Carburization of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Collins, Sunniva R; Heuer, Arthur H; Sikka, Vinod K

    2007-12-07

    Low-temperature colossal supersaturation (LTCSS) is a novel surface hardening method for carburization of austenitic stainless steels (SS) without the precipitation of carbides. The formation of carbides is kinetically suppressed, enabling extremely high or colossal carbon supersaturation. As a result, surface carbon concentrations in excess of 12 at. % are routinely achieved. This treatment increases the surface hardness by a factor of four to five, improving resistance to wear, corrosion, and fatigue, with significant retained ductility. LTCSS is a diffusional surface hardening process that provides a uniform and conformal hardened gradient surface with no risk of delamination or peeling. The treatment retains the austenitic phase and is completely non-magnetic. In addition, because parts are treated at low temperature, they do not distort or change dimensions. During this treatment, carbon diffusion proceeds into the metal at temperatures that constrain substitutional diffusion or mobility between the metal alloy elements. Though immobilized and unable to assemble to form carbides, chromium and similar alloying elements nonetheless draw enormous amounts of carbon into their interstitial spaces. The carbon in the interstitial spaces of the alloy crystals makes the surface harder than ever achieved before by more conventional heat treating or diffusion process. The carbon solid solution manifests a Vickers hardness often exceeding 1000 HV (equivalent to 70 HRC). This project objective was to extend the LTCSS treatment to other austenitic alloys, and to quantify improvements in fatigue, corrosion, and wear resistance. Highlights from the research include the following: • Extension of the applicability of the LTCSS process to a broad range of austenitic and duplex grades of steels • Demonstration of LTCSS ability for a variety of different component shapes and sizes • Detailed microstructural characterization of LTCSS-treated samples of 316L and other alloys

  16. Minor Groove Binding between Norfloxacin and DNA Duplexes in Solution: A Molecular Dynamics Study

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Molecular dynamics were used to investigate the interaction between norfloxacin and DNA duplex. The results showed that norfloxacin was situated in the minor groove of DNA,binding to the TCGA region of d [ATATCGATAT] 2. Specific hydrogen bonds were formed between norfloxacin and guanine base of DNA during the 2 ns MD, which may be the reason for the preferentiality of quinolone antibacterial towards the guanine base of DNA duplex.

  17. Management of multiple type Ⅱ endoleaks detected by duplex ultrasound after endovascular abdominal aneurysm repair

    Institute of Scientific and Technical Information of China (English)

    GUO Da-qiao; LI Wei-miao; JIANG Jun-hao; SHI Zhen-yu; WANG Yu-qi; FU Wei-guo

    2012-01-01

    We reported a case of multiple type Ⅱ endoleaks detected by duplex ultrasound after endovascular abdominal aneurysm repair.The patient was undergoing warfarin therapy.Duplex ultrasound was applied as the sole surveillance method during follow-up and provided the concerned information for reintervention.The endoleaks were successfully repaired by coil embolization of the collaterals from the internal iliac artery feeding the fourth lumbar artery.

  18. RCFD: A Frequency Based Channel Access Scheme for Full Duplex Wireless Networks

    OpenAIRE

    Luvisotto, Michele; Sadeghi, Alireza; Lahouti, Farshad; Vitturi, Stefano; Zorzi, Michele

    2016-01-01

    Recently, several working implementations of in--band full--duplex wireless systems have been presented, where the same node can transmit and receive simultaneously in the same frequency band. The introduction of such a possibility at the physical layer could lead to improved performance but also poses several challenges at the MAC layer. In this paper, an innovative mechanism of channel contention in full--duplex OFDM wireless networks is proposed. This strategy is able to ensure efficient t...

  19. Untouchable castes of Uttar Pradesh

    Directory of Open Access Journals (Sweden)

    Kharinin Artem Igorevich

    2015-04-01

    Full Text Available The Untouchable Castes of Uttar Pradesh are examined in this article. This region is one of the most populated in India. Also it is one of the most social mixed-composed in whole State. That’s why main conclusions which were made on this material can be extrapolated to all social space of country. The authors choose four ethno-caste groups, which represent the majority in untouchables and the three smallest in jaties. Their positions in regional hierarchy and economic specialization are analyzed in detail. There are a lot of information about their number, social structure, literacy rating, endogamy, day-to-day practices, customs and other features. Special accents were pointed on mind orientation of their elites toward integration in modern society or, conversely, toward the conservation of traditional forms of existence. The issues of origin and social evolution of untouchable castes of Uttar Pradesh are examined. There is assessment of castes’ sanskritization or other forms of social selfdevelopment. The quality of “scheduled” castes social environment is analyzed. As a marks of its positiveness the data about discrimination untouchables from other social groups and degree of political representativeness of “scheduled” castes, accessibility of education and labour were chosen. The conclusions were made about development degree of some castes. The factors that play role in positive changes in contemporary conditions were determined. The authors put forward their own hypothesis of future development of untouchable castes in Uttar Pradesh. Empiric base of this article was established on sources that have Indian origin and historical and social research of outstanding western indologies.

  20. Development of vacuum die-casting process

    Institute of Scientific and Technical Information of China (English)

    Masashi Uchida

    2009-01-01

    The vacuum die-casting process, started 25 years ago in Japan, has been widely applied. This technology contributes very much to improvement of castings quality. The main factor causing the defects of die castings is the trapped air in the mold cavity, while the key technology of vacuum die-casting process is to avoid the trapped air effectively by evacuating the cavity before casting. At the same time, due to the shot speed and the casting pressure reduced in half, the service life of the die is prolonged and the productivity is enhanced, as well. Vacuum die-casting process is of great significance in improving the die castings quality and making up the shortcomings of super-high-speed shot casting.