WorldWideScience

Sample records for carburization

  1. Quality of carburizers and its influence on carburization process

    Directory of Open Access Journals (Sweden)

    K. Janerka

    2009-07-01

    Full Text Available In the papers issue of production the synthetic cast iron obtaining on the basis of only steel scrap and carburizing materials are presented. Natural graphite, synthetic graphite, anthracite, petroleum coke, foundry coke and charcoal were used to carburization. Examinations covered evaluation of used carburizers taking into account chemical composition; carbon, sulphur and nitrogen content have been analyzed. Obtained effectiveness of carburization with method of inserting carburizing material into charge in solid, were especially taken into considerations. The comparison between mechanical properties (tensile strength and hardness of produced synthetic cast iron and cast iron obtained on the basis of pig iron have been carried out.

  2. The rate and effectiveness of carburization to the sort of carburizer

    Directory of Open Access Journals (Sweden)

    K. Janerka

    2007-12-01

    Full Text Available The obtaining of demanded carbon contents during melting the cast iron with bounded pig iron’s portion is important problem for many foundries. There are searched the effective methods and carburizers, which would ensure obtaining of big carbon increases with great repeatability as quick as possible. The aim of presented researches was definition of influence of essential factors characterized the carburization and the sort of carburizer on the rate and effectiveness of process. The cast iron melts are presented only on the basis of steel scrap with the portion of graphitoidal, coke and anthracite carburizers. Two methods of carburization are taken into consideration during the experiments were carried out: the addition of carburizer to charge in solid in the initial period of melting and addition of carburizer on surface of liquid metal . The obtained researches results and their analyze allow to choose the corresponding method and the sort of carburizer. One can state, that the best carburizer is synthetic graphite, if the rate and effectiveness of process is considerate and the best method of carburization in the electric inductive furnace is addition of carburizer to charge in solid. In the subsequent part of researches the analyze of influence of carburizer on the structure of grey cast iron and ductile cast iron. The initial researches has showed the differences in obtained structures of synthetic cast iron melted only on the basis of steel scrap and defined kind of carburizer.

  3. Work function of carburized rhenium

    International Nuclear Information System (INIS)

    Pallmer, P.G. Jr.; Gordon, R.L.; Dresser, M.J.

    1980-01-01

    Variations of the electronic work function of carburized rhenium foils containing approximately 5 at.% carbon have been observed using the contact potential difference technique. Surface work function was observed to vary between 5.25 and 4.1 eV, with the work function of pure rhenium taken as 5.0 eV. Decrease in work function has been ascribed to the formation of graphitic layers on the surface at temperatures below the temperature of saturated solubility. The high work function surface was observed with all carbon in solution and has been ascribed to the presence of amorphous carbon near the surface

  4. Plasma carburizing with surface micro-melting

    Science.gov (United States)

    Balanovsky, A. E.; Grechneva, M. V.; Van Huy, Vu; Ponomarev, B. B.

    2018-03-01

    This paper presents carburizing the surface of 20 low carbon steel using electric arc and graphite prior. A carbon black solution was prepared with graphite powder and sodium silicate in water. A detailed analysis of the phase structure and the distribution profile of the sample hardness after plasma treatment were given. The hardened layer consists of three different zones: 1 – the cemented layer (thin white zone) on the surface, 2 – heat-affected zone (darkly etching structure), 3 – the base metal. The experimental result shows that the various microstructures and micro-hardness profiles were produced depending on the type of graphite coating (percentage of liquid glass) and processing parameters. The experiment proved that the optimum content of liquid glass in graphite coating is 50–87.5%. If the amount of liquid glass is less than 50%, adhesion to metal is insufficient. If liquid glass content is more than 87.5%, carburization of a metal surface does not occur. A mixture of the eutectic lamellar structure, martensite and austenite was obtained by using graphite prior with 67% sodium silicate and the levels of the hardness layer increased to around 1000 HV. The thickness of the cemented layer formed on the surface was around 200 μm. It is hoped that this plasma surface carburizing treatment could improve the tribological resistance properties.

  5. Carburization in fluidized bed of carbon-graphite materials

    Energy Technology Data Exchange (ETDEWEB)

    Murav' ev, V I

    1977-01-01

    A study has been made of the diffusion saturation with carbon of the surface of titanium alloy VT1-1, molybdenum and 08KP steel with respect to the type of carbographitic materials, methods of pseudoliquefaction and heating in the temperature interval 800 to 1100/sup 0/ deg C. Used as the carburizing materials have been charcoal, acetylene black, charcoal carburizer, graphitized particles, pyrobenzene. The maximum carburizing effect is shown to be possessed by charcoal, the minimum effect - by acetylene black. Carburization in the pseudoliquid layer is 5 to 7 times as intensive as in the case of gas cementation and in a solid carburizer. No oxidation of the materials and hydrogenation of titanium has been observed in the temperature interval under study.

  6. Final Scientific Report - "Novel Steels for High Temperature Carburizing"

    Energy Technology Data Exchange (ETDEWEB)

    McKimpson, Marvin G.; Liu, Tianjun; Maniruzzaman, Md

    2012-07-27

    This program was undertaken to develop a microalloy-modified grade of standard carburizing steel that can successfully exploit the high temperature carburizing capabilities of current commercial low pressure (i.e. 'vacuum') carburizing systems. Such steels can lower the amount of energy required for commercial carburizing operations by reducing the time required for deep-case carburizing operations. The specific technical objective of the work was to demonstrate a carburizing steel composition capable of maintaining a prior austenite grain size no larger than ASTM grain size number 5 after exposure to simulated carburizing conditions of 1050 C for 8 hr. Such thermal exposure should be adequate for producing carburized case depths up to about 2 mm. Such carburizing steels are expected to be attractive for use across a wide range of industries, including the petroleum, chemical, forest products, automotive, mining and industrial equipment industries. They have potential for reducing energy usage during low pressure carburizing by more than 25%, as well as reducing cycle times and process costs substantially. They also have potential for reducing greenhouse gas emissions from existing low pressure carburizing furnaces by more than 25%. High temperature carburizing can be done in most modern low pressure carburizing systems with no additional capital investment. Accordingly, implementing this technology on carburizing furnaces will provide a return on investment significantly greater than 10%. If disseminated throughout the domestic carburizing community, the technology has potential for saving on the order of 23 to 34 trillion BTU/year in industrial energy usage. Under the program, two compositions of microalloyed, coarsening-resistant low alloy carburizing steels were developed, produced and evaluated. After vacuum annealing at 1050oC for 8 hrs and high pressure gas quenching, both steels exhibited a prior austenite ASTM grain size number of 5.0 or finer

  7. Materials and Process Design for High-Temperature Carburizing: Integrating Processing and Performance

    Energy Technology Data Exchange (ETDEWEB)

    D. Apelian

    2007-07-23

    The objective of the project is to develop an integrated process for fast, high-temperature carburizing. The new process results in an order of magnitude reduction in cycle time compared to conventional carburizing and represents significant energy savings in addition to a corresponding reduction of scrap associated with distortion free carburizing steels.

  8. Characteristic of Low Temperature Carburized Austenitic Stainless Steel

    Science.gov (United States)

    Istiroyah; Pamungkas, M. A.; Saroja, G.; Ghufron, M.; Juwono, A. M.

    2018-01-01

    Low temperature carburizing process has been carried out on austenitic stainless steel (ASS) type AISI 316L, that contain chromium in above 12 at%. Therefore, conventional heat treatment processes that are usually carried out at high temperatures are not applicable. The sensitization process due to chromium migration from the grain boundary will lead to stress corrosion crack and decrease the corrosion resistance of the steel. In this study, the carburizing process was carried out at low temperatures below 500 °C. Surface morphology and mechanical properties of carburized specimens were investigated using optical microscopy, non destructive profilometer, and Vicker microhardness. The surface roughness analysis show the carburising process improves the roughness of ASS surface. This improvement is due to the adsorption of carbon atoms on the surface of the specimen. Likewise, the hardness test results indicate the carburising process increases the hardness of ASS.

  9. Creep properties of Hastelloy X in a carburizing helium environment

    International Nuclear Information System (INIS)

    Nakanishi, T.; Kawakami, H.

    1982-01-01

    In this work, we investigate the environmental effect on the creep behavior of Hastelloy X at 900 0 C in helium and air. Since helium coolant in HTGR is expected to be carburizing and very weakly oxidizing for most metals, testings were focused on the effect of carburizing and slight oxidation. Carburization decreases secondary creep strain rate and delays tertiary creep initiation. On the other hand, the crack growth rate on the specimen surface is enhanced due to very weak oxidation in helium, therefore the tertiary creep strain rate becomes larger than that in air. The rupture time of Hastelloy X was shorter in helium when compared with in air. Stress versus rupture time curves for both environments do not deviate with each other during up to 5000 hours test, and a ratio of rupture stress in helium to that in air was about 0.9

  10. Surface composition of carburized tungsten trioxide and its catalytic activity

    International Nuclear Information System (INIS)

    Nakazawa, M.; Okamoto, H.

    1985-01-01

    The surface composition and electronic structure of carburized tungsten trioxide are investigated using x-ray photoelectron spectroscopy (XPS). The relationship between the surface composition and the catalytic activity for methanol electro-oxidation is clarified. The tungsten carbide concentration in the surface layer increases with the carburization time. The formation of tungsten carbide enhances the catalytic activity. On the other hand, the presence of free carbon or tungsten trioxide in the surface layer reduces the activity remarkably. It is also shown that, the higher the electronic density of states near the Fermi level, the higher the catalytic activity

  11. Contribution to the study of gaseous Carburization of Uranium

    International Nuclear Information System (INIS)

    Esteban Hernandez, J. A.; Jimenez Moreno, J. M.; Villota Ruiz, P. de

    1966-01-01

    Thermal decomposition of uranium hydride powder obtained by hydrogenation of uranium turnings is studied on the first part of this paper. Carburization of the uranium hydride or metallic uranium powder with methane is studied in the second part. A method of uranium monocarbide fabrication under static atmosphere is described. On this method hydrogen is removed by means of an uranium getter. (Author) 6 refs

  12. Zircon Carburation Studies as Intermediate Stage in the Zirconium Fabrication

    International Nuclear Information System (INIS)

    Almagro Huertas, V.; Saenz de Tejada Gonzalez, L.; Lopez Rodriguez, M.

    1963-01-01

    Zirconium carbide and carbonitride mixtures were obtained by Kroll's method.Reaction products have been identified by micrography and X-ray diffraction analysis. The optimum graphite content in the initial charge for the carburation reaction has been studied. zirconium, silicon and carbon content in the final product has been controlled as a function of current in the furnace and reaction time.Further chlorination of the final product was performed successfully. (Author) 16 refs

  13. Paraequilibrium Carburization of Duplex and Ferritic Stainless Steels

    Science.gov (United States)

    Michal, G. M.; Gu, X.; Jennings, W. D.; Kahn, H.; Ernst, F.; Heuer, A. H.

    2009-08-01

    AISI 301 and E-BRITE stainless steels were subjected to low-temperature (743 K) carburization experiments using a commercial technology developed for carburization of 316 austenitic stainless steels. The AISI 301 steel contained ~40 vol pct ferrite before carburization but had a fully austenitic hardened case, ~20- μm thick, and a surface carbon concentration of ~8 at. pct after treatment; this “colossal” paraequilibrium carbon supersaturation caused an increase in lattice parameter of ~3 pct. The E-BRITE also developed a hardened case, 12- to 18- μm thick, but underwent a more modest (~0.3 pct) increase in lattice parameter; the surface carbon concentration was ~10 at. pct. While the hardened case on the AISI 301 stainless steel appeared to be single-phase austenite, evidence for carbide formation was apparent in X-ray diffractometer (XRD) scans of the E-BRITE. Paraequilibrium phase diagrams were calculated for both AISI 301 and E-BRITE stainless steels using a CALPHAD compound energy-based interstitial solid solution model. In the low-temperature regime of interest, and based upon measured paraequilibrium carbon solubilities, more negative Cr-carbon interaction parameters for austenite than those in the current CALPHAD data base may be appropriate. A sensitivity analysis involving Cr-carbon interaction parameters for ferrite found a strong dependence of carbon solubility on relatively small changes in the magnitude of these parameters.

  14. Carburizing treatment of low alloy steels: Effect of technological parameters

    Science.gov (United States)

    Benarioua, Younes

    2018-05-01

    The surface areas of the parts subjected to mechanical loads influence to a great extent the resistance to wear and fatigue. In majority of cases, producing of a hard superficial layer on a tough substrate is conducive to an increased resistance to mechanical wear and fatigue. Cementation treatment of low alloy steels which bonds superficial martensitic layer of high hardness and lateral compressive to a core of lower hardness and greater toughness is an example of a good solution of the problem. The high hardness of the martensitic layer is due to an increased concentration of interstitial carbon atoms in the austenite before quenching. The lower hardness of the core after quenching is due to the presence of ferrite and pearlite components which appear if the cooling rate after austenitization becomes lower than the critical on. The objective of the present study was to obtain a cemented surface layer on low alloy steel by means of pack carburizing treatment. Different steel grades, austenitization temperatures as well as different soaking times were used as parameters of the pack carburizing treatment. During this treatment, carbon atoms from the pack powder diffuse toward the steels surface and form compounds of iron carbides. The effect of carburizing parameters on the transformation rate of low carbon surface layer of the low alloy steel to the cemented one was investigated by several analytical techniques.

  15. Cluster carburizing. Final report, June 1, 1973-May 31, 1979

    International Nuclear Information System (INIS)

    Morral, J.E.

    1979-05-01

    Three major accomplishments of the cluster carburizing program were showing that the hardness of aged and carburized materials could be controlled via the aged structure; developing a new and analytical theory of subscale formation; and characterizing the properties of Ta-Hf alloys with respect to precipitation kinetics and morphology, diffusion kinetics, age hardening, and subscale formation. The first of these verified the cluster carburizing concept, which has potential use in the development of high strength materials. The second has applications in the fields of hot corrosion, oxidation, and high temperature coatings. The third provided necessary background for this study and provided a further understanding of the behavior of refractory metals. Details about the above are contained in this final report as well as comments on the Ta-Hf, TaC-HfC and NbC-HfC phase diagrams, a comparison of hardening in the Nb-Hf and Ta-Hf system, and a discussion of possible future work

  16. Low Temperature Surface Carburization of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Collins, Sunniva R; Heuer, Arthur H; Sikka, Vinod K

    2007-12-07

    Low-temperature colossal supersaturation (LTCSS) is a novel surface hardening method for carburization of austenitic stainless steels (SS) without the precipitation of carbides. The formation of carbides is kinetically suppressed, enabling extremely high or colossal carbon supersaturation. As a result, surface carbon concentrations in excess of 12 at. % are routinely achieved. This treatment increases the surface hardness by a factor of four to five, improving resistance to wear, corrosion, and fatigue, with significant retained ductility. LTCSS is a diffusional surface hardening process that provides a uniform and conformal hardened gradient surface with no risk of delamination or peeling. The treatment retains the austenitic phase and is completely non-magnetic. In addition, because parts are treated at low temperature, they do not distort or change dimensions. During this treatment, carbon diffusion proceeds into the metal at temperatures that constrain substitutional diffusion or mobility between the metal alloy elements. Though immobilized and unable to assemble to form carbides, chromium and similar alloying elements nonetheless draw enormous amounts of carbon into their interstitial spaces. The carbon in the interstitial spaces of the alloy crystals makes the surface harder than ever achieved before by more conventional heat treating or diffusion process. The carbon solid solution manifests a Vickers hardness often exceeding 1000 HV (equivalent to 70 HRC). This project objective was to extend the LTCSS treatment to other austenitic alloys, and to quantify improvements in fatigue, corrosion, and wear resistance. Highlights from the research include the following: • Extension of the applicability of the LTCSS process to a broad range of austenitic and duplex grades of steels • Demonstration of LTCSS ability for a variety of different component shapes and sizes • Detailed microstructural characterization of LTCSS-treated samples of 316L and other alloys

  17. Carburization of austenitic alloys by gaseous impurities in helium

    International Nuclear Information System (INIS)

    Lai, G.Y.; Johnson, W.R.

    1980-03-01

    The carburization behavior of Alloy 800H, Inconel Alloy 617 and Hastelloy Alloy X in helium containing various amounts of H 2 , CO, CH 4 , H 2 O and CO 2 was studied. Corrosion tests were conducted in a temperature range from 649 to 1000 0 C (1200 to 1832 0 F) for exposure time up to 10,000 h. Four different helium environments, identified as A, B, C, and D, were investigated. Concentrations of gaseous impurities were 1500 μatm H 2 , 450 μatm CO, 50 μatm CH 4 and 50 μatm H 2 O for Environment A; 200 μatm H 2 , 100 μatm CO, 20 μatm CH 4 , 50 μatm H 2 O and 5 μatm CO 2 for Environment B; 500 μatm H 2 , 50 μatm CO, 50 μatm CH 4 and 2 O for Environment C; and 500 μatm H 2 , 50 μatm CO, 50 μatm CH 4 and 1.5 μatm H 2 O for Environment D. Environments A and B were characteristic of high-oxygen potential, while C and D were characteristic of low-oxygen potential. The results showed that the carburization kinetics in low-oxygen potential environments (C and D) were significantly higher, approximately an order of magnitude higher at high temperatures, than those in high-oxygen potential environments (A and B) for all three alloys. Thermodynamic analyses indicated no significant differences in the thermodynamic carburization potential between low- and high-oxygen potential environments. It is thus believed that the enhanced carburization kinetics observed in the low-oxygen potential environments were related to kinetic effects. A qualitatively mechanistic model was proposed to explain the enhanced kinetics. The present results further suggest that controlling the oxygen potential of the service environment can be an effective means of reducing carburization of alloys

  18. Acetylene Flow Rate as a Crucial Parameter of Vacuum Carburizing Process of Modern Tool Steels

    Directory of Open Access Journals (Sweden)

    Rokicki P.

    2016-12-01

    Full Text Available Carburizing is one of the most popular and wide used thermo-chemical treatment methods of surface modification of tool steels. It is a process based on carbon diffusive enrichment of the surface material and is applied for elements that are supposed to present higher hardness and wear resistance sustaining core ductility. Typical elements submitted to carburizing process are gears, shafts, pins and bearing elements. In the last years, more and more popular, especially in highly advanced treatment procedures used in the aerospace industry is vacuum carburizing. It is a process based on chemical treatment of the surface in lower pressure, providing much higher uniformity of carburized layer, lower process cost and much lesser negative impact on environment to compare with conventional carburizing methods, as for example gas carburizing in Endo atmosphere. Unfortunately, aerospace industry requires much more detailed description of the phenomena linked to this process method and the literature background shows lack of tests that could confirm fulfilment of all needed requirements and to understand the process itself in much deeper meaning. In the presented paper, authors focused their research on acetylene flow impact on carburized layer characteristic. This is one of the most crucial parameters concerning homogeneity and uniformity of carburized layer properties. That is why, specific process methodology have been planned based on different acetylene flow values, and the surface layer of the steel gears have been investigated in meaning to impact on any possible change in potential properties of the final product.

  19. The formation of structures and properties of carburized elements and hardened in different quenching medium

    International Nuclear Information System (INIS)

    Przylecka, M.; Gestwa, W.

    2003-01-01

    In work structure and selected properties of hardened carburized layers were introduced produced on chromium-manganese steel (16HG - 16CrMn5), after processes of gas carburizing (850 o C/1-10 h) and vacuum carburizing (950 o C/2 h) as well as direct hardening (center cooling: distillated water, Water polymer solution - polyglycol oxyalkylen, oil and gas-nitrogen) and tempering. Results of investigations permitted to affirm, that layer with structure martensite - retained austenite, as carbides - martensite - retained austenite produced in process of hardening applying cooling centre water polymer solution, the impact strength of element (at define thickness of carburized layer) give profitable, suitable hardness and microhardness as well as changes of microhardness on section in comparison to produced layers during cooling in water or oil and gas. (author)

  20. The effect of variations in carbon activity on the carburization of austenitic steels in sodium

    International Nuclear Information System (INIS)

    Gwyther, J.R.; Hobdell, M.R.; Hooper, A.J.

    1978-07-01

    Experience has shown that the liquid sodium coolant of fast breeder reactors is an effective carbon-transport medium; the resulting carburization of thin austenitic stainless steel components (eg IHX and fuel cladding) could adversely affect their mechanical integrity. The degree and nature of steel carburization depend, inter alia, on the carbon activity of the sodium environment. Exploratory tests are described in which specimens of austenitic stainless steel were carburized in sodium, the carbon activity of which was continuously monitored by a BNL electrochemical carbon meter. The sodium carbon activity was initially high, but decreased with time, simulating conditions equivalent to plant start-up or coolant clean-up following accidental oil ingress. The extent and nature of steel carburization was identified by metallography, electron microscopy, X-ray crystallography and chemical analysis. (author)

  1. Rolling Contact Fatigue Performances of Carburized and High-C Nanostructured Bainitic Steels

    OpenAIRE

    Wang, Yanhui; Zhang, Fucheng; Yang, Zhinan; Lv, Bo; Zheng, Chunlei

    2016-01-01

    In the present work, the nanostructured bainitic microstructures were obtained at the surfaces of a carburized steel and a high-C steel. The rolling contact fatigue (RCF) performances of the two alloy steels with the same volume fraction of undissolved carbide were studied under lubrication. Results show that the RCF life of the carburized nanostructured bainitic steel is superior to that of the high-C nanostructured bainitic steel in spite of the chemical composition, phase constituent, plat...

  2. Response of cast austenitic stainless steel to low temperature plasma carburizing.

    OpenAIRE

    Sun, Yong

    2008-01-01

    The response of a cast 316 type austenitic stainless steel to the novel low temperature plasma carburizing process has been investigated in this work. The cast steel has a dendritic structure with a mix of austenite, ferrite and carbide phases. The results show that such a complex structure responds well to the carburizing process, and the inter-dendrite regions containing ferrite and carbides can be transformed to expanded austenite to form a continuous and uniform layer supersat...

  3. A model for fracture toughness evaluation of the carburized layer for SAE 5115 steel

    OpenAIRE

    Sandor, Leonardo Taborda; Ferreira, Itamar

    2006-01-01

    The purpose of this work is to propose a model for evaluating the fracture toughness along the SAE 5115 steel carburized layer. Due to the small thickness of those layers, it is impossible to machine specimens from those layer in accordance with standards. For simulating the microstructures of the carburized layer in order to get samples for tensile and the fracture toughness testing, specimens of SAE 5115, 5140, 5160, and 52100 steels have been machined, assuming the local influence just the...

  4. Sustainable Steel Carburization by Using Snack Packaging Plastic Waste as Carbon Resources

    Directory of Open Access Journals (Sweden)

    Songyan Yin

    2018-01-01

    Full Text Available In recent years, the research regarding waste conversion to resources technology has attracted growing attention with the continued increase of waste accumulation issues and rapid depletion of natural resources. However, the study, with respect to utilizing plastics waste as carbon resources in the metals industry, is still limited. In this work, an environmentally friendly approach to utilize snack packaging plastic waste as a valuable carbon resources for steel carburization is investigated. At high temperature, plastic waste could be subject to pyrolytic gasification and decompose into small molecular hydrocarbon gaseous products which have the potential to be used as carburization agents for steel. When heating some snack packaging plastic waste and a steel sample together at the carburization temperature, a considerable amount of carbon-rich reducing gases, like methane, could be liberated from the plastic waste and absorbed by the steel sample as a carbon precursor for carburization. The resulting carburization effect on steel was investigated by optical microscopy, scanning electron microscopy, electron probe microanalyzer, and X-ray photoelectron spectrometer techniques. These investigation results all showed that snack packaging plastic waste could work effectively as a valuable carbon resource for steel carburization leading to a significant increase of surface carbon content and the corresponding microstructure evolution in steel.

  5. Examination of Electrical Resistance of Carburizers Used for Cast Iron Production

    Directory of Open Access Journals (Sweden)

    Książek D.

    2016-12-01

    Full Text Available The publication presents the results of examination of selected carburizers used for cast iron production with respect to their electric resistance. Both the synthetic graphite carburizers and petroleum coke (petcoke carburizers of various chemical composition were compared. The relationships between electrical resistance of tested carburizers and their quality were found. The graphite carburizers exhibited much better conductivity than the petcoke ones. Resistance characteristics were different for the different types of carburizers. The measurements were performed according to the authors’ own method based on recording the electric current flow through the compressed samples. The samples of the specified diameter were put under pressure of the gradually increased value (10, 20, 50, 60, and finally 70 bar, each time the corresponding value of electric resistance being measured with a gauge of high accuracy, equal to 0.1μΩ. The higher pressure values resulted in the lower values of resistance. The relation between both the thermal conductance and the electrical conductance (or the resistance is well known and mentioned in the professional literature. The results were analysed and presented both in tabular and, additionally, in graphic form.

  6. Pulsed ion beam-assisted carburizing of titanium in methane discharge

    International Nuclear Information System (INIS)

    Shafiq, M.; Shahzad, K.; Zakaullah, M.; Hassan, M.; Qayyum, A.; Ahmad, S.; Rawat, R. S.

    2010-01-01

    The carburizing of titanium (Ti) is accomplished by utilizing energetic ion pulses of a 1.5 kJ Mather type dense plasma focus (DPF) device operated in methane discharge. X-ray diffraction (XRD) analysis confirms the deposition of polycrystalline titanium carbide (TiC). The samples carburized at lower axial and angular positions show an improved texture for a typical (200)TiC plane. The Williamson–Hall method is employed to estimate average crystallite size and microstrains in the carburized Ti surface. Crystallite size is found to vary from ∼ 50 to 100 nm, depending on the deposition parameters. Microstrains vary with the sample position and hence ion flux, and are converted from tensile to compressive by increasing the flux. The carburizing of Ti is confirmed by two major doublets extending from 300 to 390 cm −1 and from 560 to 620 cm −1 corresponding to acoustic and optical active modes in Raman spectra, respectively. Analyses by scanning electron microscopy/energy dispersive x-ray spectroscopy (SEM/EDS) have provided qualitative and quantitative profiles of the carburized surface. The Vickers microhardness of Ti is significantly improved after carburizing. (nuclear physics)

  7. Internal residual strain mapping in carburized chrome molybdenum steel after quenching by neutron strain scanning

    International Nuclear Information System (INIS)

    Sakaida, Yoshihisa; Serizawa, Takanobu; Manzanka, Michiya

    2011-01-01

    A hollow circular cylinder specimen with an annular U-notch of chrome molybdenum steel with 0.20 mass% C (SCM420) was carburized in carrier gas and quenched in oil bath. In order to determine the case depth, the specimen was cut off and carbon content and Vickers hardness gradients were measured experimentally near the carburized surface. The residual strain mapping in the interior of carburized cylinder was conducted nondestructively by neutron strain scanning. In this study, the neutron diffraction from Fe-211 plane was used for strain scanning. The neutron wavelength was tuned to 0.1654nm so that diffraction angle became about 90deg. Radial, hoop and axial residual strains were measured by scanning diffracting volume along the axial direction of cylinder specimen. Each residual strain was calculated from lattice spacing change. Unstressed lattice spacing was determined experimentally using reference coupon specimens that were cut from the interior of same carburized cylinder. As a result, the diffraction peak width at half height, FWHM, near the carburized surface was about 3.7 times wider than that of coupon specimens. On the other hand, the most peak widths in the interior equaled to that of coupon specimens. Peak width broadened slightly as the diffracting volume approached the carburized case layer. From the center to the quarter of cylinder specimen, the hoop and axial strains were tensile, and the radial one was compressive in the interior. From the quarter to the edge of the cylinder specimen, the hoop tensile strain increased, radial and axial strains changed to tensile and compressive, respectively. Therefore, the interior of the cylinder specimen was found to be deformed elastically to balance the existence of compressive residual stresses in the carburized case layer. (author)

  8. The sort of carburization and the quality of obtained cast iron

    Directory of Open Access Journals (Sweden)

    K. Janerka

    2008-12-01

    Full Text Available In the production of cast iron, the pig iron’s amount in charge material is more and more often limited, and replaced by steel scrap. That extorts the necessity of know-how the carburization and one is looking for carburizers, which ensure obtaining big carbon increment as quickly as possible with the high repeatability and the ones which ensure getting the adequate quality of cast iron. The object of presented research was definition of the influence of charge materials’ sort on the structure, course of solidification, and the effectiveness of process. The cast iron melts, which are presented below, are made only on the basis of steel scrap with portion of graphitoidal, coke and anthracite carburizers, which were added to the charge in solid. In the article one compared the carburizers in respect of their structure, chemical constitution and the effectiveness obtained during the carburization of liquid metal. The melting of cast iron, based on the special pig iron, was carried out as well. The course of melts, chemical constitution of obtained cast iron and its structure were presented. The comparison between quality distribution and the volume fraction of graphite in classes of size for the individual melts were achieved and the TDA curves were inserted.

  9. The effect of chromium diffusion redistribution on wear resistance of carburized 3Kh13 steel

    International Nuclear Information System (INIS)

    Shcherbedinskij, G.V.; Shumakov, A.I.; Zemskij, S.V.; Pereverzev, V.M.

    1977-01-01

    The redistribution of chromium in steel 3Kh13 on carburization in a high-activity carburizer and the wear-resistance of the steel have been investigated. Surface layers with an increased chromium concentration show the highest wear-resistance. The chromium content in the surface layer increases due to its diffusion from the interior. The distribution of carbon and chromium in the carburized layers has been studied with the aid of the radioactive isotope 14 C by the method of layer-by-layer spectral analysis on a vacuum quantometer, layer-by-layer chemical and X-ray structure analysis. The composition of the carbides has been determined by physicochemical analysis. It has been established that the carburized layer can be divided into four zones with respect to its phase composition: first zone - hematite and spinal with 0.5-2.0% C; second zone - solid carbides (Fe,Cr) 7 C 3 ; up to 5% C; third zone - globular carbides in a troostite matrix (Cr,Fe) 7 C 3 and Cr 23 C 6 ; up to 3.5% C; fourth, transitional, zone - troostite carbide mixture Cr 23 C 6 ; up to 1% C. The chromium diffusion in the carburized layer is faster than in the initial austenite. The chromium counterdiffusion is due to the development of a zone of solid carbides M 7 C 3

  10. Evaluation of Bending Strength of Carburized Gears Based on Inferential Identification of Principal Surface Layer Defects

    Science.gov (United States)

    Masuyama, Tomoya; Inoue, Katsumi; Yamanaka, Masashi; Kitamura, Kenichi; Saito, Tomoyuki

    High load capacity of carburized gears originates mainly from the hardened layer and induced residual stress. On the other hand, surface decarburization, which causes a nonmartensitic layer, and inclusions such as oxides and segregation act as latent defects which considerably reduce fatigue strength. In this connection, the authors have proposed a formula of strength evaluation by separately quantifying defect influence. However, the principal defect which limits strength of gears with several different defects remains unclarified. This study presents a method of inferential identification of principal defects based on test results of carburized gears made of SCM420 clean steel, gears with both an artificial notch and nonmartensitic layer at the tooth fillet, and so forth. It clarifies practical uses of presented methods, and strength of carburized gears can be evaluated by focusing on principal defect size.

  11. Pyrolysis of propane under vacuum carburizing conditions. An experimental and modeling study

    Energy Technology Data Exchange (ETDEWEB)

    Khan, R.U.; Bajohr, S.; Buchholz, D.; Reimert, R. [Engler-Bunte-Institut, Bereich Gas, Erdoel und Kohle, Engler Bunte Ring 1, Universitaet Karlsruhe, 76131 Karlsruhe (Germany); Minh, H.D.; Norinaga, K.; Janardhanan, V.M.; Tischer, S.; Deutschmann, O. [Institute of Chemical Technology, University of Karlsruhe, 76128 Karlsruhe (Germany)

    2008-03-15

    Propane has been pyrolyzed in a flow reactor system at different temperatures ranging from 640 C to 1010 C and at 8 mbar of partial pressure which are typical vacuum carburizing conditions for steel. Nitrogen was used as a carrier gas. The products of pyrolysis were collected and analyzed by gas chromatography. The reactor was numerically simulated by 1D and 2D flow models coupled to a detailed gas phase reaction mechanism. The gas atmosphere composition has been predicted under the conditions of vacuum carburizing of steel. (author)

  12. Surface modification of superaustenitic and maraging stainless steels by low-temperature gas-phase carburization

    Science.gov (United States)

    Gentil, Johannes

    Low-temperature gas-phase carburization of 316L austenitic stainless steel was developed in recent years by the Swagelok company. This process generates great mechanical and electrochemical surface properties. Hardness, wear resistance, fatigue behavior, and corrosion resistance are dramatically improved, while the formation of carbides is effectively suppressed. This new technique is of technical, economical, but especially of scientific interest because the surface properties of common stainless steel can be enhanced to a level of more sophisticated and more expensive superalloys. The consequential continuation of previous research is the application of the carburization process to other steel grades. Differences in chemical composition, microstructure, and passivity between the various alloys may cause technical problems and it is expected that the initial process needs to be optimized for every specific material. This study presents results of low-temperature carburization of AL-6XN (superaustenitic stainless steel) and PH13-8Mo (precipitation-hardened martensitic stainless steel). Both alloys have been treated successfully in terms of creating a hardened surface by introducing high amounts of interstitially dissolved carbon. The surface hardness of AL-6XN was increased to 12GPa and is correlated with a colossal carbon supersaturation at the surface of up to 20 at.%. The hardened case develops a carburization time-dependent thickness between 10mum after one carburization cycle and up to 35mum after four treatments and remains highly ductile. Substantial broadening of X-ray diffraction peaks in low-temperature carburized superaustenitic stainless steels are attributed to the generation of very large compressive biaxial residual stresses. Those large stresses presumably cause relaxations of the surface, so-called undulations. Heavily expanded regions of carburized AL-6XN turn ferromagnetic. Non-carburized AL-6XN is known for its outstanding corrosion resistance

  13. Rolling Contact Fatigue Performances of Carburized and High-C Nanostructured Bainitic Steels

    Directory of Open Access Journals (Sweden)

    Yanhui Wang

    2016-11-01

    Full Text Available In the present work, the nanostructured bainitic microstructures were obtained at the surfaces of a carburized steel and a high-C steel. The rolling contact fatigue (RCF performances of the two alloy steels with the same volume fraction of undissolved carbide were studied under lubrication. Results show that the RCF life of the carburized nanostructured bainitic steel is superior to that of the high-C nanostructured bainitic steel in spite of the chemical composition, phase constituent, plate thickness of bainitic ferrite, hardness, and residual compressive stress value of the contact surfaces of the two steels under roughly similar conditions. The excellent RCF performance of the carburized nanostructured bainitic steel is mainly attributed to the following reasons: finer carbide dispersion distribution in the top surface, the higher residual compressive stress values in the carburized layer, the deeper residual compressive stress layer, the higher work hardening ability, the larger amount of retained austenite transforming into martensite at the surface and the more stable untransformed retained austenite left in the top surface of the steel.

  14. Rolling Contact Fatigue Performances of Carburized and High-C Nanostructured Bainitic Steels.

    Science.gov (United States)

    Wang, Yanhui; Zhang, Fucheng; Yang, Zhinan; Lv, Bo; Zheng, Chunlei

    2016-11-25

    In the present work, the nanostructured bainitic microstructures were obtained at the surfaces of a carburized steel and a high-C steel. The rolling contact fatigue (RCF) performances of the two alloy steels with the same volume fraction of undissolved carbide were studied under lubrication. Results show that the RCF life of the carburized nanostructured bainitic steel is superior to that of the high-C nanostructured bainitic steel in spite of the chemical composition, phase constituent, plate thickness of bainitic ferrite, hardness, and residual compressive stress value of the contact surfaces of the two steels under roughly similar conditions. The excellent RCF performance of the carburized nanostructured bainitic steel is mainly attributed to the following reasons: finer carbide dispersion distribution in the top surface, the higher residual compressive stress values in the carburized layer, the deeper residual compressive stress layer, the higher work hardening ability, the larger amount of retained austenite transforming into martensite at the surface and the more stable untransformed retained austenite left in the top surface of the steel.

  15. Carburization behavior of AISI 316LN austenitic stainless steel - Experimental studies and modeling

    Energy Technology Data Exchange (ETDEWEB)

    Sudha, C. [Physical Metallurgy Division, Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamilnadu (India); Sivai Bharasi, N. [Corrosion Science and Technology Division, Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamilnadu (India); Anand, R. [Physical Metallurgy Division, Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamilnadu (India); Shaikh, H., E-mail: hasan@igcar.gov.i [Corrosion Science and Technology Division, Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamilnadu (India); Dayal, R.K. [Corrosion Science and Technology Division, Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamilnadu (India); Vijayalakshmi, M. [Physical Metallurgy Division, Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamilnadu (India)

    2010-07-31

    AISI type 316LN austenitic stainless steel was exposed to flowing sodium at 798 K for 16,000 h in the bi-metallic (BIM) sodium loop. A modified surface layer of 10 {mu}m width having a ferrite structure was detected from X-ray diffraction and electron micro probe based analysis. Beneath the modified surface layer a carburized zone of 60 {mu}m width was identified which was found to consist of M{sub 23}C{sub 6} carbides. A mathematical model based on finite difference technique was developed to predict the carburization profiles in sodium exposed austenitic stainless steel. In the computation, effect of only chromium on carbon diffusion was considered. Amount of carbon remaining in solution was determined from the solubility parameter. The predicted profile showed a reasonably good match with the experimental profile. Calculations were extended to simulate the thickness of the carburized layer after exposure to sodium for a period of 40 years. Attempt was also made to predict the carburization profiles based on equilibrium calculations using Dictra and Thermocalc which contain both thermodynamic and kinetic databases for the system under consideration.

  16. Low temperature plasma carburizing of AISI 316L austenitic stainless steel and AISI F51 duplex stainless steel

    OpenAIRE

    Pinedo,Carlos Eduardo; Tschiptschin,André Paulo

    2013-01-01

    In this work an austenitic AISI 316L and a duplex AISI F51 (EN 1.4462) stainless steel were DC-Plasma carburized at 480ºC, using CH4 as carbon carrier gas. For the austenitic AISI 316L stainless steel, low temperature plasma carburizing induced a strong carbon supersaturation in the austenitic lattice and the formation of carbon expanded austenite (γC) without any precipitation of carbides. The hardness of the carburized AISI 316L steel reached a maximum of 1000 HV due to ∼13 at% c...

  17. Low temperature plasma carburizing of AISI 316L austenitic stainless steel and AISI F51 duplex stainless steel

    OpenAIRE

    Pinedo, Carlos Eduardo; Tschiptschin, André Paulo

    2013-01-01

    In this work an austenitic AISI 316L and a duplex AISI F51 (EN 1.4462) stainless steel were DC-Plasma carburized at 480ºC, using CH4 as carbon carrier gas. For the austenitic AISI 316L stainless steel, low temperature plasma carburizing induced a strong carbon supersaturation in the austenitic lattice and the formation of carbon expanded austenite (γC) without any precipitation of carbides. The hardness of the carburized AISI 316L steel reached a maximum of 1000 HV due to ∼13 at% carbon super...

  18. Nanostructural Evolution of Hard Turning Layers in Carburized Steel

    Science.gov (United States)

    Bedekar, Vikram

    The mechanisms of failure for components subjected to contact fatigue are sensitive to the structure and properties of the material surface. Although, the bulk material properties are determined by the steel making, forming and the heat treatment; the near surface material properties are altered during final material removal processes such as hard turning or grinding. Therefore, the ability to optimize, modulate and predict the near surface properties during final metal removal operations would be extremely useful in the enhancement of service life of a component. Hard machining is known to induce severely deformed layers causing dramatic microstructural transformations. These transformations occur via grain refinement or thermal phenomena depending upon cutting conditions. The aim of this work is to engineer the near surface nanoscale structure and properties during hard turning by altering strain, strain rate, temperature and incoming microstructure. The near surface material transformations due to hard turning were studied on carburized SAE 8620 bearing steel. Variations in parent material microstructures were introduced by altering the retained austenite content. The strain, strain rate and temperature achieved during final metal cutting were altered by varying insert geometry, insert wear and cutting speed. The subsurface evolution was quantified by a series of advanced characterization techniques such as transmission electron microscopy (TEM), glancing angle X-ray diffraction (GAXRD), X-ray stress evaluation and nanoindentation which were coupled with numerical modeling. Results showed that the grain size of the nanocrystalline near surface microstructure can be effectively controlled by altering the insert geometry, insert wear, cutting speed and the incoming microstructure. It was also evident that the near surface retained austenite decreased at lower cutting speed indicating transformation due to plastic deformation, while it increased at higher cutting

  19. A study of internal oxidation in carburized steels by glow discharge optical emission spectroscopy and scanning electron microscopy

    CERN Document Server

    An, X; Rainforth, W M; Chen, L

    2003-01-01

    The internal oxidation of Cr-Mn carburizing steel was studied. Internal oxidation was induced using a commercial carburizing process. Sputter erosion coupled with glow discharge optical emission spectroscopy (GDOES) was used to determine the depth profile elemental distribution within the internal oxidation layer (<10 mu m). In addition, scanning electron microscopy (SEM) equipped with energy dispersive spectrometer (EDS) studies were carried out on selected sputter eroded surfaces. Oxide type was identified primarily by transmission electron microscopy (TEM). The carburized surface was found to consist of a continuous oxide layer, followed by a complex internal oxidation layer, where Cr and Mn oxides were found to populate grain boundaries in a globular form in the near surface region. At greater depths (5-10 mu m), Si oxides formed as a grain boundary network. The internal oxides (mainly complex oxides) grew quickly during the initial stages of the carburizing process (2 h, 800 deg. C+3 h, 930 deg. C). G...

  20. EFFECTS OF CARBURIZING AND NITRIDING PROCESSES ON THE COST AND QUALITY OF GEARS PRODUCED WITH AISI 4140 AND 8620 STEELS

    Directory of Open Access Journals (Sweden)

    Claudio José Leitão

    2012-09-01

    Full Text Available This study compares the effects of nitriding and carburizing processes applied to gears subjected to contact stresses below 1300 MPa. The manufacturing cost, as well the depth of hardened layer and the distortion produced by two processes are analyzed. AISI 4140 gears quenched, tempered, liquid and gas nitriding and AISI 8620 gears after liquid carburizing, quenching and tempering are analyzed. The dimensional control of the gears was carried out before and after heat and thermochemical treatments. It is concluded that liquid or gas nitriding processes are about 30% more economical than liquid carburizing an also they reduce the dimensional changes. By the other hand liquid carburizing achieves greater case depth. Liquid nitriding process presents the lowest cost, dimensional changes and case depth.

  1. LOW PRESSURE CARBURIZING IN A LARGE-CHAMBER DEVICE FOR HIGH-PERFORMANCE AND PRECISION THERMAL TREATMENT OF PARTS OF MECHANICAL GEAR

    Directory of Open Access Journals (Sweden)

    Emilia Wołowiec-Korecka

    2017-03-01

    Full Text Available This paper presents the findings of research of a short-pulse low pressure carburizing technology developed for a new large-chamber furnace for high-performance and precision thermal treatment of parts of mechanical gear. Sections of the article discuss the novel constructions of the device in which parts being carburized flow in a stream, as well as the low-pressure carburizing experiment. The method has been found to yield uniform, even and repeatable carburized layers on typical gear used in automotive industry.

  2. Study of the potential use of carburized niobium in plutonium processing

    International Nuclear Information System (INIS)

    Johnson, M.J.

    1998-01-01

    Carburized refractory metals, especially tantalum, have been shown to possess properties useful for application as hardware in the plutonium-processing environment. These applications are driven in part by a desire to minimize the production of radioactively contaminated waste. The current use of ceramics as containment materials for Pu processing are not ideal due to the short service life of the hardware, placing an additional burden on the contaminated waste stream. Carburized niobium has been examined for use as an improved hardware material. The Nb-C system is analogous to the previously studied Ta-C system. The low density of niobium relative to tantalum will improve the ergonomics of the glovebox environment. The choice of the Nb-C system will be supported by a thermodynamic and kinetic analysis. Preliminary results of the processing investigation also will be presented

  3. Creep behavior of plasma carburized Ti-6Al-4V alloy

    International Nuclear Information System (INIS)

    Oliveira, Veronica Mara Cortez Alves de; Barboza, Miguel Justino Ribeiro; Silva, Mariane Capellari Leite da; Pinto, Catia Gisele; Suzuki, Paulo Atsushi; Machado, Joao Paulo B.

    2010-01-01

    This paper aims to evaluate the effect of plasma carburizing on the Ti-6Al-4V alloy submitted to creep tests. The results showed that the alloy Ti-6Al-4V had a hardness of 334 ± 18 HV. After treatment thermochemical by plasma, was observed the formation of a layer of average thickness of 1,5 μm and hardness of 809 ± 79 HV due to the presence of TiC phase identified by X-ray diffraction. The treatment increased the values of average roughness of 1,28 to 2,02 μm. The creep properties of carburized specimens were improved in comparison with those of the uncarburized Ti-6Al-4V alloy. (author)

  4. The carbide M7C3 in low-temperature-carburized austenitic stainless steel

    International Nuclear Information System (INIS)

    Ernst, Frank; Li, Dingqiang; Kahn, Harold; Michal, Gary M.; Heuer, Arthur H.

    2011-01-01

    Prolonged low-temperature gas-phase carburization of AISI 316L-type austenitic stainless steel can cause intragranular precipitation of the carbide M 7 C 3 (M: randomly dispersed Fe, Cr, Ni). Transmission electron microscopy revealed that the carbide particles have the shape of needles. They grow by a ledge-migration mechanism and in a crystallographic orientation relationship to the austenite matrix that enables highly coherent interphase interfaces. A small solubility limit of Ni in the carbide and restricted Ni diffusivity at the processing temperature leads to Ni pileup around the particles and may explain the extreme aspect ratio of the particle shape. These characteristics closely resemble what has been observed earlier for precipitates of M 5 C 2 under slightly different processing conditions and can be rationalized by considering the particular constraints imposed by carburization at low temperature.

  5. Evaluation of carburization depth in service exposed ferritic steel using magnetic Barkhausen noise analysis

    International Nuclear Information System (INIS)

    Vaidyanathan, S.; Moorthy, V.; Jayakumar, T.; Baldev Raj

    1996-01-01

    The feasibility of using magnetic Barkhausen (MBN) measurement for the evaluation of carburization depth in ferritic steels has been reported in this paper. MBN measurements were carried out on samples from service exposed 0.5Cr-0.5Mo ferritic steel tube at different depths (cross section) from carburised ID surface to simulate the variation in carbon concentration gradient within the skin depth of MBN with increasing time of exposure to carburization. It has been observed that the MBN level increases with increasing depth of measurement. An inverse relation between MBN level and carbon content/hardness value has been observed. This study suggests that, the MBN measurements on the carburised surface can be correlated with the concentration gradient within the skin depth of the MBN which would help in predicting the approximate depth of the carburised layer with proper prior calibration. (author)

  6. Estimation of fatigue strength enhancement for carburized and shot-peened gears

    Science.gov (United States)

    Inoue, Katsumi; Kato, Masana

    1994-05-01

    An experimental formula has been proposed to estimate the bending fatigue strength of carburized gears from the hardness and the residual stress. The derivation of the formula is briefly reviewed, and the effectiveness of the formula is demonstrated in this article. The comparison with many test results for carburized and shot-peened gears verifies that the formula is effective for the approximate estimation of the fatigue strength. The formula quantitatively shows a way of enhancing fatigue strength, i.e., the increase of hardness and residual stress at the fillet. The strength is enhanced about 300 MPa by an appropriate shot peening, and it can be improved still more by the surface removal by electropolishing.

  7. Wear resistance of AISI 304 stainless steel submitted to low temperature plasma carburizing

    Directory of Open Access Journals (Sweden)

    Marcos Antônio Barcelos

    Full Text Available Abstract Despite the AISI 304 stainless steel has high corrosion/oxidation resistance, its tribological properties are poor, being one of the barriers for use in severe wear applications. Thus, there is a wide field for studying technologies that aim to increase the surface hardness and wear resistance of this material. In this work, hardness and wear resistance for AISI 304 stainless steel submitted to the thermochemical treatment by low temperature plasma carburizing (LTPC in a fixed gas mixture composition of 93% H2 and 7% CH4 are presented. Through the evaluation of the carburizing layers, it was possible to observe a substantial improvement in tribological properties after all temperature and time of treatment. This improvement is directly related to the increase of the process variables; among them temperature has a stronger influence on the wear resistance obtained using LTPC process.

  8. The effects of retained austenite on dry sliding wear behavior of carburized steels

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hyung-Jun [Research Inst. of Industrial Science and Technology, Steel Products Dept., Pohang (Korea, Republic of); Kweon, Young-Gak [Research Inst. of Industrial Science and Technology, Steel Products Dept., Pohang (Korea, Republic of)

    1996-04-01

    Ring-on-square tests on two kinds of low-alloy carburized steel which were AISI 8620 and 4140 were carried out to study the dry sliding wear behavior. The influence of different retained austenite level of 6% to 40% was evaluated while trying to eliminate other factors. Test results show that the effects of grain size and carburized steel species are negligible in dry sliding wear behavior. While the influence of retained austenite is negligible at 20 kg load condition, wear resistance is decreased at 40 kg load condition as the retained austenite level is increased from 6% to 30%. However, wear resistance is again increased above about 30% of retained austenite level at 40 kg load condition. (orig.)

  9. Anti-carburizing Coating for Resin Sand Casting of Low Carbon Steel Based on Composite Silicate Powder Containing Zirconium

    Directory of Open Access Journals (Sweden)

    Zhan Chunyi

    2018-01-01

    Full Text Available This paper studied the structure and properties of anticarburizing coating based on composite silicate powder containing zirconium by X-ray diffraction analyzer, thermal expansion tester, digital microscope and other equipment. It is introduced that the application example of the coating in the resin-sand casting of ZG1Cr18Ni9Ti stainless steel impeller. The anti-carburizing effect of the coating on the surface layer of the cast is studied by using direct reading spectrometer and spectrum analyzer. The change of the micro-structure of the coating after casting and cooling is observed by scanning electron microscope. The analysis of anti-carburizing mechanism of the coating is presented. The results indicate that the coating possesses excellent suspension property, brush ability, permeability, levelling property and crackresistance. The coating exhibits high strength and low gas evolution. Most of the coating could be automatically stripped off flakily when the casting was shaken out. The casting possesses excellent surface finish and antimetal penetration effect. The carburizing layer thickness of the stainless steel impeller casting with respect to allowable upper limit of carbon content is about 1mm and maximum carburizing rate is 23.6%. The anticarburizing effect of casting surface is greatly improved than that of zircon powder coating whose maximum carburizing rate is 67.9% and the carburizing layer thickness with respect to allowable upper limit of carbon content is greater than 2mm. The composite silicate powder containing zirconium coating substantially reduces the zircon powder which is expensive and radioactive and mainly dependent on imports. The coating can be used instead of pure zircon powder coating to effectively prevent metal-penetration and carburizing of resin-sand-casting surface of low carbon steel, significantly improve the foundry production environment and reduce the production costs.

  10. PENGARUH KOMPOSISI ARANG AKTIF DAN KALSIUM KARBONAT PADA PACK CARBURIZING TERHADAP MICROSTRUCTURE

    Directory of Open Access Journals (Sweden)

    Hafni, Syafrul Hadi

    2016-05-01

    Full Text Available Penelitian ini bertujuan untuk mendapatkan metode pengerasan  permukaan pada baja lunak, dengan proses pack carburizing. Baja lunak banyak digunakan sebagai bahan dalam pembuatan suatu produk.  Untuk mendapatkan sifat yang keras pada permukaan dan tetap lunak pada intinya maka  dilakukan proses pengerasan permukaan, sehingga produk tersebut dapat difungsikan sesuai dengan  tujuan desainnya. Proses carburizing ini, diperlukan sebuah tungku pembakar yang dirancang tahan panas serta mudah dioperasikan. aman dengan bahan bakar batu bara . untuk penguji tungku yang telah dirancang dilakukan pengujian pada baja rabon rendah dengan mengunakan media karburisasi 1000 gr arang aktif dengan variasi :  200 gram, 100 grm, 66.7 gram Kalsium  karbonat ( CaCo3 pada temperatur   pemanasan 950 0C dan  waktu tahan 4 jam   Kemudian dilanjukan dengan proses quenching. Dari hasil pengujian menunjukan bahan uji dengan komposisi 1000 gr arang aktif dengan 200 gram calcium carbonat lebih baik penambahan unsur karbon sehingga waktu dilakukan quenching terbentuk struktur mikro martensite Kata kunci : Komposisi Arang aktif dan CaCo3, Temperatur, Waktu tahan The goal of the research to obtain surface hardening method on mild steel, with a pack carburizing process. Mild steel is widely used as an ingredient in the manufacture of a product. To get hard on the nature of the surface and remains soft at the core surface hardening process is carried out, so that the product can be used in accordance with the purpose of design.To do this carburizing process, required a stove burner designed heat resistant and easy to operate. safe with fuel coal. for testers furnace that has been designed to do testing on steel Rabon low by using media carburizing 1000 grams of activated charcoal with variations: 200 grams, 100 grm, 66.7 grams of calcium carbonate (CaCO3 at the heating temperature of 950 0C and holding time 4 hours Then dilanjukan with process quenching. Test results

  11. Effect on stress-strain relations brought by surface carburization of 316 stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Matsumoto, K [Ishikawajima-Harima Heavy Industries, Tokyo (Japan)

    1977-07-01

    The effect of sodium. environment on austenitic stainless steels used as structural materials in Liquid Metal Cooled Fast Breeder Reactors (LMFBRs) has long been the subject of extensive studies in many countries. Recent developments tending toward stricter control of the oxygen content permitted to be present in the circulating sodium have come to allay the apprehensions formerly held on the possibility of general corrosion affecting the mechanical properties of structural materials expected to be used In LMFBR plants. Grain boundary corrosion and depletion of elements from the structure surface also have come to be considered to provide little cause of fear in this regard, though some uncertainty is still left concerning the influence that these phenomena might exert toward the end of plant life. What still remains essentially to be clarified relates to carbon mass transfer. Decarburization and/or carburization are phenomena that cannot be disregarded even in the primary heat transfer system of LMFBRs, on account of the temperature dependence of carbon activity in steels, which could cause the carbon to leak out from structural material into the circulating sodium in the higher temperature zones of a circuit, to deposit itself on the channel walls in the lower temperature parts. Recent reports on loop experiments point toward the possibility of carboneous matter leaching into flowing sodium and into the cover gas to produce significant carburization phenomena. Carburization, in particular, can bring about loss of ductility and deterioration of fatigue properties, and hence serious consideration of this aspect is called for in the design of components incorporating thin stainless steel plates. To represent the stress-strain behavior at 550 deg. C of 316 stainless steel affected by surface carburization, an empirical formula was adopted. It was proposed by Voce for relating true stress to true plastic strain: {sigma} = Aexp(C {epsilon}{sub p} ) + B, where {sigma

  12. Effect on stress-strain relations brought by surface carburization of 316 stainless steel

    International Nuclear Information System (INIS)

    Matsumoto, K.

    1977-01-01

    The effect of sodium. environment on austenitic stainless steels used as structural materials in Liquid Metal Cooled Fast Breeder Reactors (LMFBRs) has long been the subject of extensive studies in many countries. Recent developments tending toward stricter control of the oxygen content permitted to be present in the circulating sodium have come to allay the apprehensions formerly held on the possibility of general corrosion affecting the mechanical properties of structural materials expected to be used In LMFBR plants. Grain boundary corrosion and depletion of elements from the structure surface also have come to be considered to provide little cause of fear in this regard, though some uncertainty is still left concerning the influence that these phenomena might exert toward the end of plant life. What still remains essentially to be clarified relates to carbon mass transfer. Decarburization and/or carburization are phenomena that cannot be disregarded even in the primary heat transfer system of LMFBRs, on account of the temperature dependence of carbon activity in steels, which could cause the carbon to leak out from structural material into the circulating sodium in the higher temperature zones of a circuit, to deposit itself on the channel walls in the lower temperature parts. Recent reports on loop experiments point toward the possibility of carboneous matter leaching into flowing sodium and into the cover gas to produce significant carburization phenomena. Carburization, in particular, can bring about loss of ductility and deterioration of fatigue properties, and hence serious consideration of this aspect is called for in the design of components incorporating thin stainless steel plates. To represent the stress-strain behavior at 550 deg. C of 316 stainless steel affected by surface carburization, an empirical formula was adopted. It was proposed by Voce for relating true stress to true plastic strain: σ = Aexp(C ε p ) + B, where σ is the true stress, and

  13. Electronic specific heat of transition metal carbides; Chaleur specifique electronique de carbures de metaux de transition

    Energy Technology Data Exchange (ETDEWEB)

    Conte, R [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-07-15

    The experimental results that make it possible to define the band structure of transition metal carbides having an NaCI structure are still very few. We have measured the electronic specific heat of some of these carbides of varying electronic concentration (TiC, either stoichiometric or non-stoichiometric, TaC and mixed (Ti, Ta) - C). We give the main characteristics (metallography, resistivity, X-rays) of our samples and we describe the low temperature specific heat apparatus which has been built. In one of these we use helium as the exchange gas. The other is set up with a mechanical contact. The two use a germanium probe for thermometer. The measurement of the temperature using this probe is described, as well as the various measurement devices. The results are presented in the form of a rigid band model and show that the density of the states at the Fermi level has a minimum in the neighbourhood of the group IV carbides. (author) [French] Les donnees experimentales permettant de preciser la structure de bandes des carbures de metaux de transition de structure NaCI sont encore peu.nombreuses. Nous avons mesure la chaleur specifique electronique de certains de ces carbures, de differentes concentrations electroniques (TiC stoechiometrique ou non, TaC et mixtes (Ti, Ta) - C). Nous donnons les principales caracteristiques (metallographie, resistivite, rayon X), de nos echantillons, et nous decrivons l'appareillage de chaleur specifique a basse temperature realise. Dans l'un nous utilisons l'helium comme gaz d'echange. L'autre est monte avec un contact mecanique. Les deux utilisent une sonde au germanium comme thermometre. La mesure de la resistance de cette sonde est decrite, ainsi que les differents montages de mesure. Les resultats, presentes dans un modele de bande rigide, font apparaitre que la densite des etats au niveau de Fermi presente un minimum au voisinage des carbures du groupe IV. (auteur)

  14. Molybdenum acetate like precursor of molybdenum carburized supported on alumina: a catalyst for hydrogenation reactions

    International Nuclear Information System (INIS)

    Petkovic, Lucia M; Parra, Ruben D; Marquez Manuel; Larsen, Gustavo

    1994-01-01

    The stability of the Al203 supported dimers under relatively high temperatures and hydrocarbon/H2 (carburizing) atmospheres is reported also, it has been developed a new method for Mo2 loading of the support based on the wet impregnation of the latter. Since carbided Mo is active for hydrogenations, the isobutene/H2 has been chosen as the probe reaction. Al203 supported Mo2(Ac)4 results in a catalyst active for isobutene hydrogenation after treatment with a H2/C2H6 2:1 mixture at 753 k

  15. Analysis of carburizing steel with lath bainite in matrix by magnetic method

    Directory of Open Access Journals (Sweden)

    Weiwu ZOU

    2017-12-01

    Full Text Available The cryogenic treatment is used to reduce the large amount of retained austenite in the steel infiltration layer which affects the hardness. The vibrating sample magnetometer (VSM and direct reading spectroscopy are combined to compare and analyze the organization structure status of the test carburizing steel after air-cooling and low temperature tempering (T at 453 K × 1 h, or after cryogenic treatment at 113 K × 30 min and low temperature tempering (T at 453 K × 1 h. The cryopreservation effect of the 1 203 K × 9 h carburizing air-cooled bainitic steel is carried out. The results show that both the effective hardening layer depths are about 1.35 mm. The retained austenite mass fractions of T and CT in the effective hardened layer are approximately 29.8% and 12.6%, respectively, and the highest hardnesses of the effective hardened layer of T and CT are 679 HV and 821 HV, respectively. The matrix structure is lath bainite, and the retained austenite mass fractions in the matrix are approximately 7.4% for T and 6.9% for CT, respectively, and both the hardnesses of the matrixes are approximately 430 HV. After the cryogenic treatment, the austenite content in the infiltration layer is effectively reduced, so that the maximum hardness of the hardened layer increases by 20% or more. It can be widely used because of the decreased material cost and remarkable economical benefit.

  16. Sliding wear characteristics of carburized steels and thermally refined steels implanted with nitrogen ions

    International Nuclear Information System (INIS)

    Terashima, Keiichi; Koda, Hiroyuki; Takeuchi, Eiichi.

    1995-01-01

    In order to concretely examine the application of surface reforming by ion implantation, nitrogen ion implantation was applied to the thermally refined steels S45C and SCM440 and the carburized steel SCM415, which are high versatile steels for mechanical structures, and their friction and wear characteristics were examined. The results are summarized as follows. In the surface-reformed material, in which nitrogen was implanted for the purpose of improving the seizure durability of the carburized steel, the load-frictional coefficient curve in lubricated sliding friction was similar to that of the material without implantation, but it was recognized that the load at which seizure occurred reached 2000 kgf or more, and as the amount of implantation was more, the material withstood higher load. In the lubricated sliding friction using a pin-ring type wear testing machine of the thermally refined steels and those to which implantation was applied, it was recognized that the specific wear amount was less in the implanted steels than in those without implantation. The results of the analysis of the implanted surface layers and the friction surfaces are reported. (K.I.)

  17. Identification of a process window for tailored carburization of sheet metals in hot stamping

    Science.gov (United States)

    Horn, Alexander; Merklein, Marion

    2018-05-01

    Due to governmental regulations concerning the reduction of CO2 emissions and increasing safety standards, hot stamping of high strength boron manganese steel sheets has evolved into a state of the art process for manufacturing structural car body parts. The combined forming and in-die quenching process enables the formation of a fully martensitic microstructure. Therefore, press hardened steels offer high strength, but low ductility. In order to further improve passenger safety, a tailored configuration of mechanical properties is desired. Besides state of the art methods, like the application of locally different heat treatment temperatures or varying quenching rates, the adjustment of mechanical properties of sheet metals by a tailored carburization is a novel approach. For the carburization process, the specimens are first coated with graphite and subsequently heat treated. Within this contribution, different coating strategies as well as heat treatment temperatures and dwell times are investigated. For the determination of a process window, mechanical properties such as tensile strength and microhardness will be analyzed and correlated with the resulting microstructure.

  18. Analyses of quenching process during turn-off of plasma electrolytic carburizing on carbon steel

    International Nuclear Information System (INIS)

    Wu, Jie; Liu, Run; Xue, Wenbin; Wang, Bin; Jin, Xiaoyue; Du, Jiancheng

    2014-01-01

    Highlights: • Cooling rate of carburized steel at the end of PEC treatment is measured. • The quench hardening in the fast or slow turn-off mode hardly takes place. • Decrease of the surface roughness during slow turn-off process is found. • A slow turn-off mode is recommended to replace the conventional turn-off mode. - Abstract: Plasma electrolytic carburizing (PEC) under different turn-off modes was employed to fabricate a hardening layer on carbon steel in glycerol solution without stirring at 380 V for 3 min. The quenching process in fast turn-off mode or slow turn-off mode of power supply was discussed. The temperature in the interior of steel and electron temperature in plasma discharge envelope during the quenching process were evaluated. It was found that the cooling rates of PEC samples in both turn-off modes were below 20 °C/s, because the vapor film boiling around the steel sample reduced the cooling rate greatly in terms of Leidenfrost effect. Thus the quench hardening hardly took place, though the slow turn-off mode slightly decreased the surface roughness of PEC steel. At the end of PEC treatment, the fast turn-off mode used widely at present cannot enhance the surface hardness by quench hardening, and the slow turn-off mode was recommended in order to protect the electronic devices against a large current surge

  19. Effect of nanograin-boundary networks generation on corrosion of carburized martensitic stainless steel.

    Science.gov (United States)

    Boonruang, Chatdanai; Thong-On, Atcharawadi; Kidkhunthod, Pinit

    2018-02-02

    Martensitic stainless steel parts used in carbonaceous atmosphere at high temperature are subject to corrosion which results in a large amount of lost energy and high repair and maintenance costs. This work therefore proposes a model for surface development and corrosion mechanism as a solution to reduce corrosion costs. The morphology, phase, and corrosion behavior of steel are investigated using GIXRD, XANES, and EIS. The results show formation of nanograin-boundary networks in the protective layer of martensitic stainless steel. This Cr 2 O 3 -Cr 7 C 3 nanograin mixture on the FeCr 2 O 4 layer causes ion transport which is the main reason for the corrosion reaction during carburizing of the steel. The results reveal the rate determining steps in the corrosion mechanism during carburizing of steel. These steps are the diffusion of uncharged active gases in the stagnant-gas layer over the steel surface followed by the conversion of C into C 4- and O into O 2- at the gas-oxide interface simultaneously with the migration of Cr 3+ from the metal-oxide interface to the gas-oxide interface. It is proposed that previous research on Al 2 O 3 coatings may be the solution to producing effective coatings that overcome the corrosion challenges discussed in this work.

  20. Boronization and Carburization of Superplastic Stainless Steel and Titanium-Based Alloys

    Directory of Open Access Journals (Sweden)

    Masafumi Matsushita

    2011-07-01

    Full Text Available Bronization and carburization of fine-grain superplastic stainless steel is reviewed, and new experimental results for fine grain Ti88.5Al4.5V3Fe2Mo2 are reported. In superplastic duplex stainless steel, the diffusion of carbon and boron is faster than in non-superplastic duplex stainless steel. Further, diffusion is activated by uniaxial compressive stress. Moreover, non-superplastic duplex stainless steel shows typical grain boundary diffusion; however, inner grain diffusion is confirmed in superplastic stainless steel. The presence of Fe and Cr carbides or borides is confirmed by X-ray diffraction, which indicates that the diffused carbon and boron react with the Fe and Cr in superplastic stainless steel. The Vickers hardness of the carburized and boronized layers is similar to that achieved with other surface treatments such as electro-deposition. Diffusion of boron into the superplastic Ti88.5Al4.5V3Fe2Mo2 alloy was investigated. The hardness of the surface exposed to boron powder can be increased by annealing above the superplastic temperature. However, the Vickers hardness is lower than that of Ti boride.

  1. Green fuels, growth engines after petroleum; Les carburants verts, moteurs de la croissance apres le petrole

    Energy Technology Data Exchange (ETDEWEB)

    Mili, Dino

    2010-09-15

    The contribution of the new fuels to a greener environment is important and immediate. Thanks to clean novel technologies and to commercial plant projects in development, companies like Enerkem contribute to satisfy increasing global demand for clean energy. They stimulate local economies by creating jobs in an industry that offers real growth potential. Green fuels will gradually allow us to let go of non sustainable energy sources like oil to adopt a way of life based on sustainable development. They will also allow a shift towards a green economy. [French] La contribution des nouveaux carburants a un environnement plus vert est importante et immediate. Grace a des technologies propres novatrices et a des projets d'sines commerciales en developpement, des entreprises comme Enerkem contribuent a satisfaire a la demande mondiale croissante en energie propre. Elles stimulent les economies locales par la creation d'emplois dans une industrie qui offre un veritable potentiel de croissance. Les carburants verts permettront graduellement de nous affranchir des sources d'energie non renouvelables comme le petrole pour adopter un mode de vie base sur le developpement durable. Ils permettront aussi un virage vers une economie verte.

  2. A study of internal oxidation in carburized steels by glow discharge optical emission spectroscopy and scanning electron microscopy

    International Nuclear Information System (INIS)

    An, X; Cawley, J.; Rainforth, W.M.; Chen, L.

    2003-01-01

    The internal oxidation of Cr-Mn carburizing steel was studied. Internal oxidation was induced using a commercial carburizing process. Sputter erosion coupled with glow discharge optical emission spectroscopy (GDOES) was used to determine the depth profile elemental distribution within the internal oxidation layer (<10 μm). In addition, scanning electron microscopy (SEM) equipped with energy dispersive spectrometer (EDS) studies were carried out on selected sputter eroded surfaces. Oxide type was identified primarily by transmission electron microscopy (TEM). The carburized surface was found to consist of a continuous oxide layer, followed by a complex internal oxidation layer, where Cr and Mn oxides were found to populate grain boundaries in a globular form in the near surface region. At greater depths (5-10 μm), Si oxides formed as a grain boundary network. The internal oxides (mainly complex oxides) grew quickly during the initial stages of the carburizing process (2 h, 800 deg. C+3 h, 930 deg. C). GDOES proved to be an excellent tool for the quantification of oxidation and element distribution as a function of depth, particularly when combined with SEM and TEM to identify oxide type and morphology

  3. Contribution to the study of gaseous Carburization of Uranium; Contribucion al estudio de la Carburacion gaesosa del uranio

    Energy Technology Data Exchange (ETDEWEB)

    Esteban Hernandez, J A; Jimenez Moreno, J M; Villota Ruiz, P de

    1966-07-01

    Thermal decomposition of uranium hydride powder obtained by hydrogenation of uranium turnings is studied on the first part of this paper. Carburization of the uranium hydride or metallic uranium powder with methane is studied in the second part. A method of uranium monocarbide fabrication under static atmosphere is described. On this method hydrogen is removed by means of an uranium getter. (Author) 6 refs.

  4. EBSD analysis of tungsten-filament carburization during the hot-wire CVD of multi-walled carbon nanotubes

    CSIR Research Space (South Africa)

    Oliphant, CJ

    2014-02-01

    Full Text Available the carburization of tungsten filaments. During the synthesis, the W-filaments transform to W(sub2)C and WC.W-carbide growth followed a parabolic behavior corresponding to the diffusion of C as the rate-determining step. The grain size of W, W(sub2)C, and WC...

  5. Les nouveaux carburants pour l'automobile. Carburants oxygénés : emploi et émissions New Automotive Fuels. Oxygenated Fuels: Their Use and Emissions

    Directory of Open Access Journals (Sweden)

    Guibet J. C.

    2006-11-01

    Full Text Available A la lumière de résultats nouveaux obtenus à l'IFP et de publications récentes sur le sujet, on étudie les principales répercussions de l'emploi de carburants oxygénés sur les émissions de polluants à l'échapement et sur les risques possibles associés à la manipulation des produits. Les polluants examinés sont les alkyles de plomb, l'oxyde de carbone, les oxydes d'azote, les produits imbrûlés, les aldéhydes et les hydrocarbures aromatiques polynucléaires. Les émissions de fumées et de particules solides par les moteurs diesel font aussi l'objet de quelques commentaires. On aborde également les problèmes de pertes par évaporation et on fournit quelques informations sur la toxicité des alcools et des aldéhydes. L'étude fait apparaître un besoin réel de nouvelles recherches dans le domaine, mais elle indique déjà que l'emploi de produits organiques oxygénés comme carburants ne devrait pas changer l'ordre de grandeur des niveaux de polluants. In the light of new results from IFP and recent publications on the subject, this article examines the main repercussions of the use of oxygenated fuelss on pollutant exhauts emissions and on possible risks associated with the handling of products. The pollutants examined are lead alkyls, carbon monoxide, nitrogen oxides, unburned products, aldehydes and polynuclear aromatic hydrocarbons. Emissions of smoke and solid particles by diesel engines are also the subject of various comments. Likewise, the article takes up the problem of losses by evaporation, and some information is provided on the toxicity of alcohols and aldehydes. This study reveals the real need for further research in the field, but it already shows that the use of oxygenated organic products as fuels should not bring about much change in the order of magnitude of pollutant levels.

  6. Isotope ratio measurements of pg-size plutonium samples using TIMS in combination with the 'Multiple Ion Counting' and filament carburization

    Energy Technology Data Exchange (ETDEWEB)

    Jakopic, Rozle; Richter, Stephan; Kuehn, Heinz; Aregbe, Yetunde [European Commission, Directorate General Joint Research Centre Institute for Reference Materials and Measurements, IRMM Retieseweg 111, B-2440 Geel (Belgium)

    2008-07-01

    A new sample preparation procedure for isotopic measurements using the Triton TIMS (Thermal Ionization Mass Spectrometer) was developed which employed the technique of carburization of rhenium filaments. Carburized filaments were prepared in a special vacuum chamber in which the filaments were heated and exposed to benzene vapor. Ionization efficiency was improved by an order of magnitude. Additionally, a new 'multi-dynamic' measurement technique was developed for Pu isotope ratio measurements using the 'multiple ion counting' (MIC) system. This technique was further combined with the filament carburization technique and applied to the NBL-137 isotopic standard and samples of the NUSIMEP 5 inter-laboratory comparison campaign. The results clearly show an improved precision and accuracy for the 'multi-dynamic' measurement procedure, compared to measurements carried out either in peak-jumping or in static mode using the MIC system with non-carburized filaments. (authors)

  7. Carburizing plasma in a low temperature austenitic stainless steel AISI 304

    International Nuclear Information System (INIS)

    Mota, W.T.; Ramos, F.D.; Rocha, R.C.; Barcelos, M.V.; Barcelos, M.A.

    2014-01-01

    The industrial use of thermochemical treatment assisted by the cold plasma has been widely employed in recent years, mainly oriented to the excellent results obtained in the surface modification of engineering materials, when compared to more traditional methods. In this work, we studied the plasma carburizing low temperature steel AISI 304 mechanical parts used in construction. The thermochemical treatment was performed at a fixed gas atmosphere 7% CH 4 (g) and 93 % H 2 (g), 350 ° C and times of 1, 3 and 5 hours. Samples being tested for Vickers hardness, abrasive microwear, microstructure evaluation by optical microscopy and SEM and X-ray diffraction. The results show significant improvement in surface hardness, wear resistance and good formation of expanded austenite layer and no identifiers peaks of carbides. The results achieved are due to diffusion/adsorption of carbon present in the gaseous atmosphere to the evaluated samples. (author)

  8. Application of experiment planning during investigation of cementation process in solid carburizers

    International Nuclear Information System (INIS)

    Lisenkov, A.N.; Denisov, V.M.; Prigozhina, E.L.

    1981-01-01

    A mathematical model of cementation process in solid carburizirs is obtained, the most effective contents of carburizers are chosen. Specimens are produced out of St20, 12KhN3A, 40Kh13, KhVG steels. It is shown that specimens of St20 and 12KhN3A steels have the higher depth of cementated layer, specimens made of 40Kh13 and KhVG steels-the lower depth. It is shown that the quality of cementated layer structure at recommended regimes improved, cementated layer depth for low-carbon steels changed a little and for tool steels increased infficiently: for KhVG steel in 2-3 times for 40Kh13 steel in 1.5-2.5 times

  9. Possibility of surface carburization of refractory metals of electric spark alloying

    International Nuclear Information System (INIS)

    Verkhoturov, A.D.; Isaeva, L.P.; Timofeeva, I.I.; Tsyban', V.A.

    1981-01-01

    The paper is concerned with a study in the alloying layer formation under electric spark alloying of refractory (Ti, Zr, Nb, Mo, W, Co, Fe) metals with graphite in argon and in air using the EhFI-46A installation. It is shown that in electric spark alloying with graphite there appear certain specific conditions for the alloying layer formation manifested in the cathode mass decrease during treatment. In this case an alloying layer consisting of carbides, oxides of the corresponding metals and material of the base is formed on the metal surface. The best carburization conditions in the process of electric spark alloying are realized for group 4 metals when treating them in ''soft'' regime, specific time of alloying being 1-3 min/sm 2 and for group 5 and 6 metals - in ''rigid'' regime of treatment and specific time of alloying 3-5 min/cm 2 [ru

  10. Carburization of austenitic and ferritic alloys in hydrocarbon environments at high temperature

    Directory of Open Access Journals (Sweden)

    Serna, A.

    2003-12-01

    Full Text Available The technical and industrial aspects of high temperature corrosion of materials exposed to a variety of aggressive environments have significant importance. These environments include combustion product gases and hydrocarbon gases with low oxygen potentials and high carbon potentials. In the refinery and petrochemical industries, austenitic and ferritic alloys are usually used for tubes in fired furnaces. The temperature range for exposure of austenitic alloys is 800-1100 °C, and for ferritic alloys 500-700 °C, with carbon activities ac > 1 in many cases. In both applications, the carburization process involves carbon (coke deposition on the inner diameter, carbon absorption at the metal surface, diffusion of carbon inside the alloy, and precipitation and transformation of carbides to a depth increasing with service. The overall kinetics of the internal carburization are approximately parabolic, controlled by carbon diffusion and carbide precipitation. Ferritic alloys exhibit gross but uniform carburization while non-uniform intragranular and grain-boundary carburization is observed in austenitic alloys.

    La corrosión a alta temperatura, tal como la carburación de materiales expuestos a una amplia variedad de ambientes agresivos, tiene especial importancia desde el punto de vista técnico e industrial. Estos ambientes incluyen productos de combustión, gases e hidrocarburos con bajo potencial de oxígeno y alto potencial de carbono. En las industrias de refinación y petroquímica, las aleaciones austeníticas y ferríticas se utilizan en tuberías de hornos. El rango de temperatura de exposición para aleaciones austeníticas está entre 800-1.100°C y para aleaciones ferríticas está entre 500-700°C, con actividades de carbono ac>1 en algunos casos. En tuberías con ambas aleaciones, el proceso de carburación incluye deposición de carbón (coque en el diámetro interno, absorción de carbono en la superficie

  11. Metallographical procedure for detecting carburized layer in the 12Kh18N10T steel tubes

    International Nuclear Information System (INIS)

    Najmark, S.I.; Shmalenyuk, R.P.

    1977-01-01

    The various causes of the tendency to intercrystalline corrosion of stainless steel tubing were studied. 12Kh18N10T steel tube specimens were metallographically investigated to reveal the presence and depth of the carburized layer. Unlubricated specimens and specimens with the graphite-saltpeter lubrication applied on them were austenized in the temperature range from 950 to 1250 deg C and then exposed to a provoking anneal at 650 deg C for 24 h. All the lubricated specimens showed a carbide network along grain boundaries and intercrystalline cracks. The specimens treated without lubrication had no cracks. The method offered can differentiate poor tube cleaning and the undesirable effect of other processing steps on the tubes

  12. The efficiency of different types of wood charcoal on increasing carbon content on surfaces of low carbon steel in the pack carburizing process

    Directory of Open Access Journals (Sweden)

    Narongsak Thammachot

    2014-09-01

    Full Text Available The purpose of this research is to compare the efficiency of five types of wood charcoal, eucalyptus, coconut shell, tamarind, bamboo and cassava root in increasing carbon content on surfaces of low carbon steel by the pack carburizing process. The experiment for pack carburized low carbon steel (grade AISI 1020 was conducted by using the different wood charcoals as carburizers, mixed with 10% limestone (by weight as the energizer. The carburizing temperature of 950°C, and carburizing times of 2, 4 and 6 hours were used in the experiment. After grinding, the specimens in each case were checked for carbon content by optical emission spectroscopy. Micro-Vickers hardness testing and microstructure inspections were carried out. The results of the experiment showed that the efficiency of eucalyptus charcoal as the carburizer (for increasing carbon content on surfaces of low carbon steel was higher than that of tamarind, cassava root, coconut shell and bamboo charcoals. The averages for carbon content were: 1.16, 1.06, 0.97, 0.83 and 0.77% respectively.

  13. The carbide M{sub 7}C{sub 3} in low-temperature-carburized austenitic stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Ernst, Frank, E-mail: frank.ernst@cwru.edu [Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, OH 44106-7204 (United States); Li, Dingqiang; Kahn, Harold; Michal, Gary M.; Heuer, Arthur H. [Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, OH 44106-7204 (United States)

    2011-04-15

    Prolonged low-temperature gas-phase carburization of AISI 316L-type austenitic stainless steel can cause intragranular precipitation of the carbide M{sub 7}C{sub 3} (M: randomly dispersed Fe, Cr, Ni). Transmission electron microscopy revealed that the carbide particles have the shape of needles. They grow by a ledge-migration mechanism and in a crystallographic orientation relationship to the austenite matrix that enables highly coherent interphase interfaces. A small solubility limit of Ni in the carbide and restricted Ni diffusivity at the processing temperature leads to Ni pileup around the particles and may explain the extreme aspect ratio of the particle shape. These characteristics closely resemble what has been observed earlier for precipitates of M{sub 5}C{sub 2} under slightly different processing conditions and can be rationalized by considering the particular constraints imposed by carburization at low temperature.

  14. Study of the 1.25Cr-1Mo-0.25V steel microstructure after a carburization phenomenon

    Energy Technology Data Exchange (ETDEWEB)

    Simonetti, S., E-mail: ssimonet@uns.edu.ar [Departamento de Fisica, Universidad Nacional del Sur, Av. Alem 1253, 8000 Bahia Blanca (Argentina); Departamentos de Ciencias Basicas e Ingenieria Mecanica, Universidad Tecnologica Nacional, 11 de Abril 461, 8000 Bahia Blanca (Argentina); Lanz, C. [Departamento de Ingenieria, Universidad Nacional del Sur, Av. Alem 1253, 8000 Bahia Blanca (Argentina); Brizuela, G.; Juan, A. [Departamento de Fisica, Universidad Nacional del Sur, Av. Alem 1253, 8000 Bahia Blanca (Argentina)

    2010-08-20

    We studied the changes in the structure and carbide particle size in 1.25Cr-1Mo-0.25V steel under 600 deg. C and 168 MPa, after 4000 h service. We used microscopy and microanalysis techniques to analyze the carbide particles. We performed a complementary theoretical study on the chemical bonding and electronic structure of the carbide-Fe matrix interaction. The results contribute to the understanding of the changes in the alloy microstructure caused by the carburization phenomenon.

  15. Relationship between carburization and zero-applied-stress creep dilation in Alloy 800H and Hastelloy X

    International Nuclear Information System (INIS)

    Inouye, H.; Rittenhouse, P.L.

    1981-01-01

    Typical HTGR candidate alloys can carburize when exposed to simulated service environments. The carbon concentration gradients so formed give rise to internal stresses which could cause dilation. Studies performed with Hastelloy X and Alloy 800H showed that dilations of up to almost 1% can occur at 1000 0 C when carbon pickup is high. Dilation was normally observed only when the carbon increase was >1000 μg/cm 2 and ceased when diffusing carbon reached the center of the specimen. (Auth.)

  16. The Effects of CO{sub 2} Pressure on Corrosion and Carburization Behaviors of Chromia-forming Austenitic Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Ho Jung; Kim, Sung Hwan; Jang, Changheui [KAIST, Daejeon (Korea, Republic of)

    2015-05-15

    By applying S-CO{sub 2} cycle to SFR, the inherent safety could be improved by alleviating the concern of explosive reaction between high temperature steam and liquid sodium as well as increased thermal efficiency at 500-550 .deg. C compared to helium Brayton cycle. Meanwhile, from the material point of view, a compatibility such as corrosion and carburization of candidate materials in S-CO{sub 2} environment should be evaluated to assure the long-term integrity of IHX. It has been previously reported that Ni-base alloys and high-Cr Fe-base austenitic alloys showed a good corrosion resistance by the formation of thin chromia layer while carburization behaviors of those materials were not properly investigated. Corrosion and carburization behaviors of three chromia-forming austenitic alloys (Ni-base alloys and Alloy 800HT) were evaluated in S-CO{sub 2} (200 bar) and CO{sub 2} (1 bar) environment at 550.650 .deg. C for 1000 h. For all test materials, a good corrosion resistance was exhibited by the formation of thin chromia (Cr{sub 2}O{sub 3}) with small amount of minor oxides such as Mn1.5Cr1.5O{sub 4}, Al{sub 2}O{sub 3}, and TiO{sub 2}.

  17. Laws of alloyed cementite particles nucleation during heat-resistant steels carburizing

    Directory of Open Access Journals (Sweden)

    M. Yu. Semenov

    2014-01-01

    Full Text Available The article considers a problem analyzing a nucleation of cementite type carbides in carburized heat-resistant steels for the turbofan engines gear wheels.The verification of previously hypothesized mechanism of dislocation nucleation particles chromium-alloyed cementite during process of carburizing was accepted as an objective of the work.As a methodological basis of this paper were accepted the numerical experiments based on the kinetic theory of nucleation, as well as on the known results of experimental studies.According to the kinetic theory of nucleation, a new phase in the solid solutions take place in the defects of the crystal structure of the metal such as inter-grain boundaries and dislocations clusters. A principle feature of the inter-grain boundary mechanism of nucleation is formation of carbide lattice. It is of great practical interest because the cementite lattice drops mechanical properties of hardened parts.According to the experimental studies, the average chromium concentration in the alloyed cementite twice exceeds its Cr content in the heat-resistant steels. Furthermore, the areas of abnormally high (more than ten times in comparison with the average content chromium concentration in cementite have been experimentally revealed.Numerical experiments have revealed that the nucleation of cementite particles alloyed with chromium (chromium concentration of 3% or more occurs, mainly, by the dislocation mechanism on the concentration fluctuations of the alloying element. According to calculations, an obligatory prerequisite to start an active nucleation process of new phase in the solid solution is a local increase of the chromium concentration up to 40%.Despite the lack of physical prerequisites for the formation of chromium precipitates, this phenomenon is explained by a strong chemical affinity of chromium and carbon, causing diffusion of chromium atoms in the region of the carbon atoms clusters. The formation of carbon

  18. Carburization behavior under the pits induced by metal dusting in 304L and 347 stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Chia-Hao [Department of Materials Engineering and Science, National Cheng Kung University, Tainan 701, Taiwan (China); Tsai, Wen-Ta, E-mail: wttsai@mail.ncku.edu.tw [Department of Materials Engineering and Science, National Cheng Kung University, Tainan 701, Taiwan (China)

    2009-08-15

    The metal dusting behavior of Type 304L and 347 stainless steels (SSs) in a flowing mixed CO/H{sub 2}/H{sub 2}O gas stream at 600 deg. C was investigated. After exposure in a 35% CO + 60% H{sub 2} + 5% H{sub 2}O gas for 500 h, large pits were formed on both steel surfaces. The aspect ratio of the pits formed in 304L SS was higher than that of the pits formed in 347 SS. The microstructures and chemical compositions of the reaction products and those of the substrate under the pits were examined by using a scanning electron microscope (SEM) combined with an energy dispersive spectrometer (EDS). A Cr-depleted zone containing voids was formed on the outer surface just beneath the pit. Massive matrix carburization and intergranular carbide precipitation were seen for both steels. The experimental results showed that niobium (Nb) could delay the ingress of carbon and retard the metal dusting reaction.

  19. Effect of cryogenic treatment on tensile behavior of case carburized steel-815M17

    International Nuclear Information System (INIS)

    Bensely, A.; Senthilkumar, D.; Mohan Lal, D.; Nagarajan, G.; Rajadurai, A.

    2007-01-01

    The crown wheel and pinion represent the most highly stressed parts of a heavy vehicle; these are typically made of 815M17 steel. The reasons for the frequent failure of these components are due to tooth bending impact, wear and fatigue. The modern processes employed to produce these as high, durable components include cryogenic treatment as well as conventional heat treatment. It helps to convert retained austenite into martensite as well as promote carbide precipitation. This paper deals with the influence of cryogenic treatment on the tensile behavior of case carburized steel 815M17. The impetus for studying the tensile properties of gear steels is to ensure that steels used in gears have sufficient tensile strength to prevent failure when gears are subjected to tensile or fatigue loads, and to provide basic design information on the strength of 815M17 steel. A comparative study on the effects of deep cryogenic treatment (DCT), shallow cryogenic treatment (SCT) and conventional heat treatment (CHT) was made by means of tension testing. This test was conducted as per ASTM standard designation E 8M. The present results confirm that the tensile behavior is marginally reduced after cryogenic treatment (i.e. both shallow and deep cryogenic treatment) for 815M17 when compared with conventional heat treatment. Scanning electron microscopic (SEM) analysis of the fracture surface indicates the presence of dimples and flat fracture regions are more common in SCT specimens than for CHT and DCT-processed material

  20. Effect of cryogenic treatment on distribution of residual stress in case carburized En 353 steel

    International Nuclear Information System (INIS)

    Bensely, A.; Venkatesh, S.; Mohan Lal, D.; Nagarajan, G.; Rajadurai, A.; Junik, Krzysztof

    2008-01-01

    The effect of cryogenic treatment on the distribution of residual stress in the case carburized steel (En 353) was studied using X-ray diffraction technique. Two types of cryogenic treatment: shallow cryogenic treatment (193 K) and deep cryogenic treatment (77 K) were adopted, as a supplement to conventional heat treatment. The amount of retained austenite in conventionally heat-treated, shallow cryogenically treated and deep cryogenically treated samples was found to be 28%, 22% and 14%, respectively. The conventionally heat-treated, shallow cryogenically treated and deep cryogenically treated samples in untempered condition had a surface residual stress of -125 MPa, -115 MPa and -235 MPa, respectively. After tempering the conventionally heat-treated, shallow cryogenically treated and deep cryogenically treated samples had a surface residual stress of -150 MPa, -80 MPa and -80 MPa, respectively. A comparative study of the three treatments revealed that there was an increase in the compressive residual stress in steel that was subjected to cryogenic treatment prior to tempering. The experimental investigation revealed that deep cryogenically treated steel when subjected to tempering has undergone a reduction in compressive residual stress. Such stress relieving behaviour was mainly due to the increased precipitation of fine carbides in specimens subjected to DCT with tempering

  1. X-ray photoelectron spectroscopy investigation of the carburization of 310 stainless steel

    International Nuclear Information System (INIS)

    Tabet, N.; Allam, I.; Yin, R.C.

    2003-01-01

    The surface of 310 stainless steel (310SS) samples was investigated by X-ray photoelectron spectroscopy (XPS) after 500 h cyclic exposure to two carburizing atmospheres: CH 4 (2%)-H 2 (98%) at 800 deg. C, and CH 4 (10%)-H 2 (90%) at 1100 deg. C. The depth distribution of various elements in the surface region was obtained by XPS after successive cycles of argon etching. The microstructure of the alloy was observed by scanning electron microscopy (SEM) and the phases formed during the exposure were analyzed by X-ray diffraction (XRD). The results showed that the major phases that were formed within few micrometer depth during exposure at 800 deg. C include both iron and chromium carbides. (Mn, Cr) oxide was also formed as a result of the reaction with the residual oxygen of the atmosphere. A region of few microns width that was relatively depleted of chromium was formed under the surface as a result of the outwards diffusion of chromium. The exposure to the reducing atmosphere at 1100 deg. C led to the formation of various iron and chromium carbides. No oxide was formed during exposure. In all exposed samples, the surface was Cr enriched while nickel remained buried under the surface region that reacted with the atmosphere

  2. Wear of tin coating and Al-Si alloy substrate against carburized steel under mixed lubrication

    Science.gov (United States)

    Wang, Q.; Cheng, H. S.; Fine, M. E.

    1994-04-01

    Tin coatings on Al-Si alloys are widely used in the automotive industries. The soft tin coating and the harder substrate alloy form a tribological system with the advantages of low friction and reasonably high load-bearing capacity. Wear tests of tin coated Al-Si Z332 alloy in conformal contact against carburized 1016 steel have been carried out under mixed lubrications with SAE 10W30 oil to study the wear mechanisms. Two major wear mechanisms, uniform wear of the tin coating due to micro-plowing and spall pitting related to the substrate are found to contribute to the bearing material loss when the fluid lubrication film is relatively thick (Lambda about 1.6). Under conditions of thinner films (Lambda approximately = 0.8), some local coating debonding occurs. The pitting and local coating debounding are closely related to fracture in the substrate. The bonding between silicon and tin seems to be weaker than between aluminum and tin. During wear, oxidation occurs.

  3. Carburants de substitution : orientations et recherches françaises Synthetic Fuels: French Orientation and Research

    Directory of Open Access Journals (Sweden)

    Guibet J. C.

    2006-11-01

    Full Text Available Le programme d'études et de recherches entrepris en France, depuis 1981, dans le domaine des carburants de substitution, porte à la fois sur l'examen des techniques d'obtention et sur les modalités d'utilisation de ces produits. Les travaux concernent essentiellement le méthanol, le système acétono-butylique et, pour les moteurs Diesel, les dérivés d'huiles végétales. On prévoit, dans une première phase, l'incorporation de faibles proportions - moins de 10 % - de produits organiques oxygénés dans le supercarburant sans modifier les spécifications du produit ni les conditions de réglage des véhicules. D'autres études sont effectuées sur des mélanges à teneur moyenne ou élevée en méthanol (30, 50 ou 90 % afin d'examiner les meilleures voies possibles pour une substitution plus importante. The research undertaken in France since 1981 in the field of alternative fuels includes both the ways of producing and the ways of using such products. These research projects mainly concern methanol, butanol-acetone system and, for diesel engines, vegetable-oil derivatives. In the first phase, plans are being made to incorporate small proportions (less then 10% of oxygenated organic products in premium gasoline without modifying either the specifications of the product or vehicle tuning conditions. Other research is being done on mixtures with a moderate or high methanol content (30, 50 or 90% so as to examine the best possible methods for substituting larger amounts.

  4. Study of Effect of Quenching Deformation Influenced by 17CrNiMo6 Gear Shaft of Carburization

    Science.gov (United States)

    Pang, Zirui; Yu, Shenjun; Xu, Jinwu

    The 17CrNiMo6 steel is mainly used for the gear shaft of large modulus in many fields of heavy industry such as mining, transit, hoist, forging and so on[1]. The size of addendum circle and common normal line is changed a lot beyond the tolerance because of the long time of carburizing process and the out-of-step structural stress and thermal stress during the quenching process. And thus the posterior grinding efficiency and quality are influenced. In the paper comparison and analysis of the deformation affected by solid and hollow gear shafts were done and the methods of simulation and practice were both used. The results are as follows: the deformation of gear shaft was small before and after carburizing while that of gear shaft was large before and after quenching because of different cooling velocity, structure and hardness of each position. And the deformation of hollow was much smaller than that of solid. Therefore, if the hollow gear shaft is used, the waste of material will be decreased, and finishing cost will be reduced, and thus the technology of heat treatment will be optimized.

  5. Development of CSS-42L{trademark}, a high performance carburizing stainless steel for high temperature aerospace applications

    Energy Technology Data Exchange (ETDEWEB)

    Burrier, H.I.; Milam, L. [Timken Co., Canton, OH (United States); Tomasello, C.M.; Balliett, S.A.; Maloney, J.L. [Latrobe Steel Co., Latrobe, PA (United States); Ogden, W.P. [MPB Corp., Lebanon, NH (United States)

    1998-12-31

    Today`s aerospace engineering challenges demand materials which can operate under conditions of temperature extremes, high loads and harsh, corrosive environments. This paper presents a technical overview of the on-going development of CSS-42L (US Patent No. 5,424,028). This alloy is a case-carburizable, stainless steel alloy suitable for use in applications up to 427 C, particularly suited to high performance rolling element bearings, gears, shafts and fasteners. The nominal chemistry of CSS-42L includes: (by weight) 0.12% carbon, 14.0% chromium, 0.60% vanadium, 2.0% nickel, 4.75% molybdenum and 12.5% cobalt. Careful balancing of these components combined with VIM-VAR melting produces an alloy that can be carburized and heat treated to achieve a high surface hardness (>58 HRC at 1mm (0.040 in) depth) with excellent corrosion resistance. The hot hardness of the carburized case is equal to or better than all competitive grades, exceeding 60 HRC at 427 C. The fracture toughness and impact resistance of the heat treated core material have likewise been evaluated in detail and found to be better than M50-NiL steel. The corrosion resistance has been shown to be equivalent to that of 440C steel in tests performed to date.

  6. Study of the carburization of an austenitic steel through optical and scanning electron microscopy, microhardness and X ray microanalysis of C

    International Nuclear Information System (INIS)

    Champigny, Michel; Gauvain, Danielle; Meny, Lucienne

    1977-01-01

    Carburization tests of 316 L stainless steel have been performed in liquid sodium at 550, 600 and 650 0 C; the depth of penetration of carbon is of the order of 300 μm. The structure of the carburized layer has been studied through optical and scanning electron microscopy: the carbides precipitate first within the grain boundaries, making a nearly continuous superficial carbide layer. The Vickers and Knoop (under 50 g load) microhardness measurements determine the depth of carburization with an error of +-50μm. Though the tensile strength does not vary much with the carburization, the striction, and then the deformation capability, is highly decreased. The variation of the concentration in carbon versus distance has been measured by quantitative X ray microanalysis, using diamond as a standard; the best experimental conditions, regarding the overlapping of the Cr 2 Lα and Ni 3 Lα lines with CK line have been chosen, and the minimum contamination during the measurements has been performed. The results have been confirmed by the analysis of carbon in Fe Ni standards containing less than 1 w/o carbon. The results are discussed with the published data. This work shows that: the increase of microhardness is not related in a simple way with the carbon content of the stainless steel; the carbon concentration can be measured quickly with an error of +-5% when 0,2 [fr

  7. Effect of carburizing helium environment on creep behavior of Ni-base heat-resistant alloys for high-temperature gas-cooled reactors

    International Nuclear Information System (INIS)

    Kurata, Yuji; Ogawa, Yutaka; Nakajima, Hajime

    1988-01-01

    Creep tests were conducted on Ni-base heat-resistant alloys Hastelloy XR and XR-II, i.e. versions of Hastelloy X modified for nuclear applications, at 950degC using four types of helium environment with different impurity compositions, and mainly the effect of carburization was examined. For all the materials tested, the values of creep rupture time obtained under the carburizing conditions were similar to or longer than those in the commonly used, standard test environment (JAERI Type B helium). The difference among the results was interpreted by the counterbalancing effects of the strengthening due to carburization and possible weakening caused under very low oxidizing potential. In the corrosion monitoring specimens pronounced carbon pick-up was observed in the environment with high carbon activity and very low oxidizing potential. Based on the results obtained in the present and the previous works, it is suggested that a moderate control of the impurity chemistry is important rather than simple purification of the coolant in protecting the material from the environment-enhanced degradation. Either condition with high or low extremes in the oxidizing and carburizing potentials may cause enhanced degradation and thus are desirable to be avoided at the elevated temperatures. (author)

  8. Some observations on the carburization of type 316 stainless steel foil in a low carbon activity sodium environment

    International Nuclear Information System (INIS)

    Thorley, A.W.; Jeffcoat, P.J.

    1982-01-01

    Work currently being undertaken to establish the equilibrium composition of carbides which form in stainless steel foils during their exposure to low carbon activity sodium environment is described. The time it takes the carbon to reach equilibrium during exposure to sodium of different carbon activity is discussed. The lowest carbon activity measureable in test loops where the sodium is just above carburizing to stainless steel is reported. Analytical techniques are used to determine the composition of the carbide and the austenite matrix and hence estimate the carbon activity of the equilibrium structure. This provides a comparison with carbon activity values determined by alternative methods such as the Harwell Carbon Meter and nickel tab techniques

  9. Excellent durability of DLC film on carburized steel (JIS-SCr420) under a stress of 3.0 GPa

    International Nuclear Information System (INIS)

    Yakabe, F; Kumagai, M; Kuwahara, H; Ochiai, S; Jinbo, Y; Horiuchi, T

    2008-01-01

    To improve durability of transmission gears, Diamond Like Carbon (DLC) film coated on roller was estimated as well as TiN film. These films were coated on JIS-SCr420 steel, which was carburized, quenched, and tempered. DLC and TiN films were deposited by PCVD and PVD process, respectively. These surface modified rollers were estimated by usual metallurgical methods (observation of microstructure by optical microscope, SEM, and TEM, measurement of hardness by Vickers hardness tester and nano-indentator), measurement of friction coefficient by ball-on-disk in dry atmosphere, analysis of carbon by Raman spectroscopy and hydrogen by EDRA, and lifetime of pitting by the roller-pitting test. The hardness values were 21 GPa and 26 GPa, the elasticity coefficients were 192 GPa and 336 GPa, the friction coefficients were 0.1∼0.15 and 0.5∼0.6 for DLC and TiN films, respectively. The present DLC was a typical DLC called as hydrogenated amorphous carbon (a-C: H). The hydrogen content was about 20%. The surface fatigue resistance of DLC-coated specimen had 100 times longer life than that the carburized and quenched one even under Hertzian contact stress of 3.0 GPa. TiN coated specimen was failed at 3.0 GPa by 5.17·10 5 cycles despite that the strength of the surface of the substrate was reduced due to the exposure at higher temperature in the coating process than the temperature for tempering

  10. Gas carburizing end-discharge pusher furnaces for the automatic hardening of single gear components. Gasaufkohlungs-Durchstossanlagen mit automatischer Einzelhaertung von Getriebeteilen

    Energy Technology Data Exchange (ETDEWEB)

    Grassl, D; Washausen, R

    1989-09-01

    Apart from rotary hearth furnaces, end-discharge pusher furnaces are increasingly used for carburizing and hardening single components. These furnaces offer the following advantages: There is no limitation to the depth of case. The furnace zones can be controlled separately permitting carburizing to be optimized. The furnace can be designed to permit hardening of single components or quenching in batches. Process data relating to the components can be stored and called automatically (reproducibility of product quality). Heat treatment can be integrated in production control by process computer even if the furnace is installed separately. Regardless of what type of furnace is used, specific requirements have to be met to ensure reliable automatic discharge of single components. (orig./BWI).

  11. Pulverization of boron element and proportions of boron carbide in boron; Broyage de bore element et dosage de carbure de bore dans le bore

    Energy Technology Data Exchange (ETDEWEB)

    Lang, F M; Finck, C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1956-07-01

    It is possible to reduce boron element into fine powder by means of a mortar and pestle made of sintered boron carbide, the ratio of boron carbide introduced being less than one per cent. Boron element at our disposal is made of sharp edged, dark brown, little grains of average size greater than 5 {mu}. Grain sizes smaller than 1{mu} are required for applying thin layers of such boron. (author) [French] Il est possible de pulveriser finement du bore element au moyen de mortier et pilon en carbure de bore fritte, le taux de carbure de bore introduit etant inferieur a 1 pour cent. Le bore element dont nous disposons est constitue de petits grains brun fonce, a aretes vives, de dimension moyenne superieure a 5 {mu}. L'application de ce bore en couches minces demande des grains de dimensions inferieures a 1 {mu}. (aute0008.

  12. Effects of niobium additions on the structure, depth, and austenite grain size of the case of carburized 0.07% C steels

    Science.gov (United States)

    Islam, M. A.; Bepari, M. M. A.

    1996-10-01

    Carbon (0.07%) steel samples containing about 0.04% Nb singly and in combination with nitrogen were carburized in a natural Titas gas atmosphere at a temperature of 1223 K (950 °C) and a pressure of about 0.10 MPa for 1/2 to 4 h, followed by slow cooling in the furnace. Their microstructures were studied by optical microscopy. The austenite grain size of the case and the case depths were determined on baseline samples of low-carbon steels and also on niobium and (Nb + N) microalloyed steel samples. It was found that, when compared to the baseline steel, niobium alone or in combination with nitrogen decreased the thickness of cementite network near the surface of the carburized case of the steels. However, niobium in combination with nitrogen was more effective than niobium in reducing the thickness of cementite network. Niobium with or without nitrogen inhibited the formation of Widmanstätten cementite plates at grain boundaries and within the grains near the surface in the hypereutectoid zone of the case. It was also revealed that, when compared to the baseline steel, niobium decreased the case depth of the carburized steels, but that niobium with nitrogen is more effective than niobium alone in reducing the case depth. Niobium as niobium carbide (NbC) and niobium in the presence of nitrogen as niobium carbonitride, [Nb(C,N)] particles refined the austenite grain size of the carburized case, but Nb(C,N) was more effective than NbC in inhibiting austenite grain growth.

  13. Zircon Carburation Studies as Intermediate Stage in the Zirconium Fabrication; Estudios encaminados a la carburacion del circon como etapa intermedia en la obtencion de circonio

    Energy Technology Data Exchange (ETDEWEB)

    Almagro Huertas, V; Saenz de Tejada Gonzalez, L.; Lopez Rodriguez, M

    1963-07-01

    Zirconium carbide and carbonitride mixtures were obtained by Kroll's method.Reaction products have been identified by micrography and X-ray diffraction analysis. The optimum graphite content in the initial charge for the carburation reaction has been studied. zirconium, silicon and carbon content in the final product has been controlled as a function of current in the furnace and reaction time.Further chlorination of the final product was performed successfully. (Author) 16 refs.

  14. Zircon Carburation Studies as Intermediate Stage in the Zirconium Fabrication; Estudios encaminados a la carburacion del circon como etapa intermedia en la obtencion de circonio

    Energy Technology Data Exchange (ETDEWEB)

    Almagro Huertas, V.; Saenz de Tejada Gonzalez, L.; Lopez Rodriguez, M.

    1963-07-01

    Zirconium carbide and carbonitride mixtures were obtained by Kroll's method.Reaction products have been identified by micrography and X-ray diffraction analysis. The optimum graphite content in the initial charge for the carburation reaction has been studied. zirconium, silicon and carbon content in the final product has been controlled as a function of current in the furnace and reaction time.Further chlorination of the final product was performed successfully. (Author) 16 refs.

  15. THE INFLUENCE OF GRINDING CONDITIONS ON THE DISTRIBUTION OF RESIDUAL STRESS IN THE SURFACE LAYER OF 17crni6-6 STEEL AFTER CARBURIZING

    Directory of Open Access Journals (Sweden)

    Jacek Sawicki

    2017-06-01

    Full Text Available This paper presents the results of a study aimed at determining the residual stress which results from developing the surface layer by low-pressure and conventional carburizing and grinding of 17CrNi6-6 steel. A synergistic effect of thermochemical and abrasive treatment was examined on ring samples used to study residual stress by Davidenkov’s method. Samples were subjected to vacuum carburizing and conventional carburizing, which was followed by grinding with a 38A60K8V aloxite grinding wheel and a CBN grinding wheel - RNB80/63B75V. The following cutting fluids were used during the grinding process: oil emulsion 5%, supply rate ca. 20 l/min, Micro5000 oil supplied at the minimum quantity lubrication (MQL of ca. 25 ml/h, dry machining. The study determined the effect of the type of grinding wheel and the cooling and lubricating agent on the distribution of residual stress in the sur-face layer. The best effects of grinding with respect to the residual stress were achieved with flood cooling with oil emulsion and grinding with a CBN grinding wheel.

  16. Corrosion and carburization behavior of Al-rich surface layer on Ni-base alloy in supercritical-carbon dioxide environment

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Ho Jung, E-mail: leehojung@kaist.ac.kr; Kim, Sung Hwan, E-mail: sciencetom@kaist.ac.kr; Kim, Hyunmyung, E-mail: h46kim@kaist.ac.kr; Jang, Changheui, E-mail: chjang@kaist.ac.kr

    2016-12-01

    Highlights: • Al-rich layer was developed on Alloy 600 by Al deposition and EB remelting. • When exposed to S-CO{sub 2} at 600 °C, mostly Cr{sub 2}O{sub 3} with transition Al{sub 2}O{sub 3} was formed. • Carburized region of amorphous C layer was observed at the oxide/matrix interface. • α-Al{sub 2}O{sub 3} was formed after pre-oxidation which resulted in superior resistance. - Abstract: In order to improve the corrosion and carburization resistance in a high-temperature supercritical-carbon dioxide (S-CO{sub 2}) environment, an Al-rich surface layer was developed on Alloy 600 by Al deposition and a subsequent high energy electron beam (EB) remelting. As a result of the EB surface treatment, an Al enriched (5–7 wt.%) micro-alloying zone (40 μm) was produced. When the EB surface-treated Alloy 600 was corroded in S-CO{sub 2} at 600 °C (20 MPa) for 500 h, the surface oxide layer mostly consisted of chromia (Cr{sub 2}O{sub 3}) with small amount of transition alumina (Al{sub 2}O{sub 3}). In addition, a carburized region of an amorphous C layer inter-mixed with the alumina was observed at the oxide/matrix interface. Meanwhile, when the EB surface-treated specimen was pre-oxidized in helium at 900 °C, α-alumina layer was formed on the surface, which showed superior corrosion and carburization resistance in S-CO{sub 2} environment. Therefore, it could be said that the presence of Al-rich surface layer alone is not enough to provide sufficient corrosion and carburization resistance in S-CO{sub 2} environment at 600 °C, unless pre-oxidation at higher temperature is applied to form a more protective α-alumina on the surface.

  17. Synthetic Or Reformulated Fuels: a Challenge for Catalysis Carburants de synthèse ou reformulés : un défi pour la catalyse

    Directory of Open Access Journals (Sweden)

    Courty P.

    2006-12-01

    Full Text Available Despite comparative figures for wordwide crude oil and natural gas proven reserves, present time contribution of syngas chemistry to motorfuels remains marginal when the refining industry is faced to main constraints: market demand evolution, stringent specifications and environmental issues. Actually natural gas upgrading via syngas chemistry yields key products (e. g. methanol among which clean motorfuels (ethers, FT products should develop despite the huge investments required, mostly for syngas production. Main challenges and corresponding issues for catalysts and related technologies are identified for Fischer-Tropsch synthesis and motorfuels long-term reformulation. Among other, mastering the chain-growth (FT synthesis improving the FCC products: gasoline, and LCO for Diesel pool. All these issues need significant progresses in catalyst and technology to be solved. Lastly, our economical study, focused on Diesel-fuel production, shows up that clean diesel (from SR-LCO mixtures and FT Diesel reach similar production costs when cheap NG is available. In the future, FT middle distillates should amount to a few percent (5-150 Mt of the 1700-2000 Mt of transport middle distillates expected from oil refining. However they should more and more be a compulsory part of diesel pool if the level of investment for an FT process continues to decrease significantly. Malgré des réserves prouvées en pétrole et en gaz du même ordre de grandeur, la contribution de la chimie du gaz de synthèse à la production de carburants reste marginale, alors que l'industrie du raffinage est confrontée à des contraintes majeures : évolution de la demande, durcissement des spécifications des produits et contraintes environnementales. Cependant, la conversion chimique du gaz, via la chimie du gaz de synthèse, fournit des produits stratégiques (e. g. méthanol parmi lesquels les carburants propres (éthers, produits Fischer-Tropsch devraient se développer, bien

  18. An Investigation into the Effects of Process Conditions on the Tribological Performance of Pack Carburized Titanium with Limited Oxygen Diffusion

    Science.gov (United States)

    Bailey, R.; Sun, Y.

    2018-04-01

    In the present study, a new pack carburization technique for titanium has been investigated. The aim of this treatment is to produce a titanium carbide/oxycarbide layer atop of an extended oxygen diffusion zone [α-Ti(O)]. The effects of treatment temperature and pack composition have been investigated in order to determine the optimal conditions required to grant the best tribological response. The resulting structural features were investigated with particular interest in the carbon and oxygen concentrations across the samples cross section. The optimization showed that a temperature of 925 °C with a pack composition of 1 part carbon to 1 part energizer produced surface capable of withstanding a contact pressure of ≈ 1.5 GPa for 1 h. The process resulted in TiC surface structure which offers enhanced hardness (2100 HV) and generates a low friction coefficient (μ ≈ 0.2) when in dry sliding contact with an alumina (Al2O3) ball. The process also produced an extended oxygen diffusion zone that helps to improve the load bearing capacity of the substrate.

  19. The Influence of Calcium Carbonate Composition and Activated Carbon in Pack Carburizing Low Carbon Steel Process in The Review of Hardness and Micro Structure

    Science.gov (United States)

    Hafni; Hadi, Syafrul; Edison

    2017-12-01

    Carburizing is a way of hardening the surface by heating the metal (steel) above the critical temperature in an environment containing carbon. Steel at a temperature of the critical temperature of affinity to carbon. Carbon is absorbed into the metal form a solid solution of carbon-iron and the outer layer has high carbon content. When the composition of the activator and the activated charcoal is right, it will perfect the carbon atoms to diffuse into the test material to low carbon steels. Thick layer of carbon Depending on the time and temperature are used. Pack carburizing process in this study, using 1 kg of solid carbon derived from coconut shell charcoal with a variation of 20%, 10% and 5% calcium carbonate activator, burner temperature of 950 0C, holding time 4 hours. The test material is low carbon steel has 9 pieces. Each composition has three specimens. Furnace used in this study is a pack carburizing furnace which has a designed burner box with a volume of 1000 x 600 x 400 (mm3) of coal-fired. Equipped with a circulation of oxygen from the blower 2 inches and has a wall of refractory bricks. From the variation of composition CaCO3, microstructure formed on the specimen with 20% CaCO3, better diffusion of carbon into the carbon steel, it is seen by the form marten site structure after quenching, and this indicates that there has been an increase of or adding carbon to in the specimen. This led to the formation of marten site specimen into hard surfaces, where the average value of hardness at one point side (side edge) 31.7 HRC

  20. Low temperature plasma carburizing of AISI 316L austenitic stainless steel and AISI F51 duplex stainless steel Cementação sob plasma à baixa temperatura do aço inoxidável austenítico AISI 316L e do aço inoxidável duplex AISI F51

    OpenAIRE

    Carlos Eduardo Pinedo; André Paulo Tschiptschin

    2013-01-01

    In this work an austenitic AISI 316L and a duplex AISI F51 (EN 1.4462) stainless steel were DC-Plasma carburized at 480ºC, using CH4 as carbon carrier gas. For the austenitic AISI 316L stainless steel, low temperature plasma carburizing induced a strong carbon supersaturation in the austenitic lattice and the formation of carbon expanded austenite (γC) without any precipitation of carbides. The hardness of the carburized AISI 316L steel reached a maximum of 1000 HV due to ∼13 at% c...

  1. Reaction of uranium and plutonium carbides with austenitic steels; Reaction des carbures d'uranium et de plutonium avec des aciers austenitiques

    Energy Technology Data Exchange (ETDEWEB)

    Mouchnino, M [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1967-07-01

    The reaction of uranium and plutonium carbides with austenitic steels has been studied between 650 and 1050 deg. C using UC, steel and (UPu)C, steel diffusion couples. The steels are of the type CN 18.10 with or without addition of molybdenum. The carbides used are hyper-stoichiometric. Tests were also carried out with UCTi, UCMo, UPuCTi and UPuCMo. Up to 800 deg. C no marked diffusion of carbon into stainless steel is observed. Between 800 and 900 deg. C the carbon produced by the decomposition of the higher carbides diffuses into the steel. Above 900 deg. C, decomposition of the monocarbide occurs according to a reaction which can be written schematically as: (U,PuC) + (Fe,Ni,Cr) {yields} (U,Pu) Fe{sub 2} + Cr{sub 23}C{sub 6}. Above 950 deg. C the behaviour of UPuCMo and that of the titanium (CN 18.12) and nickel (NC 38. 18) steels is observed to be very satisfactory. (author) [French] La reaction des carbures d'uranium et de plutonium avec des aciers austenitiques a ete etudiee entre 650 deg. C et 1050 deg. C a partir de couples de diffusion UC, acier et (UPu)C, acier. Les aciers sont du type CN 18.10 avec ou sans addition de molybdene. Les carbures utilises sont hyper-stoechiometriques. En outre on a fait des essais avec UCTi, UCMo, UPuCTi, UPuCMo. Jusqu'a 800 deg. C on ne detecte pas de diffusion sensible du carbone dans l'acier inoxydable. Entre 800 et 900 deg. C il y a diffusion dans l'acier du carbone provenant de la decomposition des carbures superieurs. A partir de 900 deg. C il y a decomposition du monocarbure selon une reaction que l'on ecrit schematiquement: (U,PuC) + (Fe, Ni, Cr) {yields} (U,Pu)Fe{sub 2} + Cr{sub 23}C{sub 6}. Nous notons a 950 deg. C le bon comportement de UPuCMo ainsi que celui des aciers au titane (CN 18. 12) et au nickel (NC 38.18). (auteur)

  2. Improved microstructure and properties of 12Cr2Ni4A alloy steel by vacuum carburization and Ti + N co-implantation

    Science.gov (United States)

    Dong, Meiling; Cui, Xiufang; Jin, Guo; Wang, Haidou; Cai, Zhaobing; Song, Shengqiang

    2018-05-01

    The carburized 12Cr2Ni4A alloy steel was implanted by Ti + N double elements implantation. The microstructure, nano-hardness and corrosion properties were investigated by EPMA, TEM, XPS, nano-hardness and electrochemistry tests in detail. The results showed that the Ti + N co-implanted layer is composed of FCC TiN and TiC phases with BCC martensite. Compared with the un-implanted layer, the Ti + N implanted layer has higher nano-hardness and better corrosion resistance. In addition, the higher nano-hardness was presented below the surface of 1800 nm compared with un-implanted layer, which is far beyond the thickness of the implanted layer. The results also indicated that the generation of nanoscale ceramic phase and structures are not the only factor to impose the influence on the nano-hardness and corrosion resistance, but the radiation damage and lattice distortion will play an important role.

  3. Bimetallic NiFe2O4 synthesized via confined carburization in NiFe-MOFs for efficient oxygen evolution reaction

    Science.gov (United States)

    Fang, Zhiqiang; Hao, Zhaomin; Dong, Qingsong; Cui, Yong

    2018-04-01

    Transition metal oxides that derived from metal-organic framework (MOF) precursor have intensively received attention because of their numerous electrochemical applications. Bimetallic Ni-Fe oxides have been rarely reported on the basis of MOF-related strategy. Herein, a bimetallic NiFe2O4 was successfully synthesized via confined carburization in NiFe-MOF precursors and characterized by XRD, XPS, SEM, and TEM. After conducting an investigation of oxygen evolution reaction (OER), the as-synthesized NiFe2O4 material exhibited good catalytic efficiency and high stability and durability in alkaline media. The as-synthesized NiFe2O4 material would promote the development of MOFs in non-noble-metal OER catalyst.

  4. Evaluation of crack growth behavior and probabilistic S–N characteristics of carburized Cr–Mn–Si steel with multiple failure modes

    International Nuclear Information System (INIS)

    Li, Wei; Sun, Zhenduo; Zhang, Zhenyu; Deng, Hailong; Sakai, Tatsuo

    2014-01-01

    Highlights: • The stepwise S–N characteristics only for interior induced failure was observed. • The interior crack growth behavior with threshold conditions in different stages was clarified. • The distribution characteristics of test data in transition failure region was evaluated. • A model for evaluating the probabilistic S–N curve with multiple failure modes was developed. - Abstract: The unexpected failures of case-hardened steels in long life regime have been a critical issue in modern engineering design. In this study, the failure behavior of a carburized Cr–Mn–Si steel under very high cycle fatigue (VHCF) was investigated, and a model for evaluating the probabilistic S–N curve associated with multiple failure modes was developed. Results show that the carburized Cr–Mn–Si steel exhibits three failure modes including the surface flaw-induced failure, the interior inclusion-induced failure without the fine granular area (FGA) and the interior inclusion-induced failure with the FGA. As the predominant failure mode in the VHCF regime, the interior failure process can be divided into four stages: (i) the small crack growth around the inclusion, (ii) the stable macroscopic crack growth outside the FGA, (iii) the unstable crack growth outside the fish-eye and (iv) the momentary fracture outside the final crack growth zone. The threshold values are successively evaluated to be 2.33 MPa m 1/2 , 4.13 MPa m 1/2 , 18.51 MPa m 1/2 and 29.26 MPa m 1/2 . The distribution characteristics of the test data in transition failure region can be well characterized by the mixed two-parameter Weibull distribution function. The developed probabilistic S–N curve model is in good agreement with the test data with multiple failure modes. Although the result is somewhat conservative in the VHCF regime, it is acceptable for safety considerations

  5. Comportement des pots catalytiques en présence de carburants oxygénés Behavior of Catalytic Mufflers in the Presence of Oxygenated Fuels

    Directory of Open Access Journals (Sweden)

    Degobert P.

    2006-11-01

    Full Text Available A partir d'un examen critique de la bibliographie disponible, et après un rappel des répercussions sur les émissions de la présence d'alcools dans les carburants, sont successivement examinées les performances d'épurateurs catalytiques multifonctionnels ou d'oxydation appliqués à des véhicules alimentés avec des carburants dont les teneurs en produits oxygénés varient entre 10 et 100 %. Les performances des catalyseurs s'écartent peu de celles constatées dans le cas de l'essence. Elles restent très bonnes vis-à-vis des polluants non réglementés. Par ailleurs, le pot catalytique n'engendre pas, dans ses conditions normales de fonctionnement, de polluants supplémentaires caractéristiques des combustibles oxygènes utilisés. Based on a critical examination of the literature available and after a review of the effects of the presence of alcools in fuels on emissions, this article successively examines the performances of multifunctional or oxidation catalytic scrubbers applied to vehicles fed with fuels containing between 10 and 100% oxygenated products. The performances of catalysts are not very different from those found with gasoline. They remain very good with regard to pollutants not covered by regulations. Furthermore, under normal operating conditions, a catalytic muffler does not produce any supplementary pollutants characteristic of the oxygenated fuels used.

  6. Reaction of uranium and plutonium carbides with nitrogen; Reaction avec l'azote des carbures d'uranium et de plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Lorenzelli, R; Martin, A; Schickel, R [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-03-01

    Uranium and plutonium carbides react with nitrogen during the grinding process preceding the final sintering. The reaction occurs even in argon atmospheres containing a few percent of residual nitrogen. The resulting contamination is responsible for the appearance of an equivalent quantity of higher carbide in the sintered products; nitrogen remains quantitatively in the monocarbide phase. UC can be transformed completely into nitride under a nitrogen pressure, at a temperature as low as 400 C. The reaction is more sluggish with PuC. The following reactions take places: UC + 0,8 N{sub 2} {yields}> UN{sub 1.60} + C and PuC + 0,5 N{sub 2} {yields} PuN + C. (authors) [French] Les carbures d'uranium et de plutonium reagissent avec l'azote au cours du broyage qui precede le frittage final. Cette reaction est sensible meme sous des atmospheres d'argon ne contenant que quelques pour cent d'azote. Cette contamination se traduit sur les produits frittes par l'apparition d'une quantite equivalente de carbure superieur, l'azote restant fixe quantitativement dans la phase monocarbure. On peut transformer entierement UC en nitrure par action de l'azote sous pression des 400 C. La reaction est plus difficile avec PuC. Les reactions sont les suivantes: UC + 0,8 N{sub 2} {yields} UN{sub 1.60} + C et PuC + 0,5 N{sub 2} {yields} PuN + C.

  7. Hydrogenation-disproportionation-desorption-recombination in Sm2Fe16M (M=Al, Ga and Si) and magnetic properties of their carburized powders

    International Nuclear Information System (INIS)

    Kubis, M.; Rave, W.; Cao, L.; Gebel, B.; Mueller, K.-H.; Schultz, L.

    1998-01-01

    The application of the hydrogenation-disproportionation-desorption-recombination (HDDR) process in Sm 2 Fe 16 M (M=Al,Ga and Si) was investigated. The hydrogen absorption behaviour was studied by temperature-pressure analysis (TPA). In the temperature range between 500 and 800 C, Sm 2 Fe 16 M samples with M=Ga and Si show a weaker hydrogen absorption than Sm 2 Fe 16 Al. This was confirmed by X-ray diffraction which showed a complete disproportionation of Sm 2 Fe 16 Al into SmH z (1.9 2 Fe 16 Ga and Sm 2 Fe 16 Si exhibit a fraction of undecomposed material with the Th 2 Zn 17 -type structure after the disproportionation procedure. These results point to a stabilization of Sm 2 Fe 16 M against disproportionation by hydrogen for M=Ga and Si. The magnetization processes of carburized HDDR powders were studied by VSM measurements and Kerr microscopy. The demagnetization curve of our HDDR processed Sm 2 Fe 16 AlC y is well shaped, whereas those of Sm 2 Fe 16 GaC y and Sm 2 Fe 16 SiC y show a large decrease of the polarization at low fields. The favourable behaviour of Sm 2 Fe 16 AlC y is due to a homogeneous submicron grain structure. In Sm 2 Fe 16 GaC y and Sm 2 Fe 16 SiC y samples, an additional, magnetically soft phase with larger domains was observed which causes the low coercivity. As a consequence, HDDR was only favourable for the preparation of Sm 2 Fe 16 MC y hard magnets with M=Al but not for M=Ga and Si. Optimization of the HDDR process in Sm 2 Fe 16 Al and subsequent nitrogenation or carburization led to coercivities of μ 0j H c =2.9 and 2.5 T, respectively. (orig.)

  8. In-service testing of Ni{sub 3}Al coupons and trays in carburizing furnaces at Delphi Saginaw. CRADA final report

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Santella, M.L.; Viswanathan, S.; Swindeman, R.W. [Oak Ridge National Lab., TN (United States); Chatterjee, M. [General Motors Corporaion, Saginaw Division (United States)

    1998-08-01

    This Cooperative Research and Development Agreement (CRADA) report deals with the development of nickel aluminide alloy for improved longer life heat-resistant fixture assemblies for batch and continuous pusher carburizing furnaces. The nickel aluminide development was compared in both coupon and component testing with the currently used Fe-Ni-Cr heat-resisting alloy known as HU. The specific goals of the CRADA were: (1) casting process development, (2) characterization and possible modification of the alloy composition to optimize its manufacturing ability and performance under typical furnace operating conditions, and (3) testing and evaluation of specimens and prototype fixtures. In support of the CRADA objectives, coupons of nickel aluminide and the HU alloy were installed in both batch and pusher furnaces. The coupons were taken from two silicon levels and contained welds made with two different filler compositions (IC-221LA and IC-221W). Both nickel-aluminide and HU coupons were removed from the batch and pusher carburizing furnace at time intervals ranging from one month to one year. The exposed coupons were cut and mounted for metallographic, hardness, and microprobe analysis. The results of the microstructural analysis have been transmitted to General Motors Corporation, Saginaw Division (Delphi Saginaw) through reports that were presented at periodic CRADA review meetings. Based on coupon testing and verification of the coupon results with the testing of trays, Delphi Saginaw moved forward with the use of six additional trays in a batch furnace and two assemblies in a pusher furnace. Fifty percent of the trays and fixtures are in the as-cast condition and the remaining trays and fixtures are in the preoxidized condition. The successful operating experience of two assemblies in the pusher furnace for nearly a year formed the basis for a production run of 63 more assemblies. The production run required melting of 94 heats weighing 500 lb. each. Twenty

  9. Hydrogenation-disproportionation-desorption-recombination in Sm{sub 2}Fe{sub 16}M (M=Al, Ga and Si) and magnetic properties of their carburized powders

    Energy Technology Data Exchange (ETDEWEB)

    Kubis, M.; Rave, W.; Cao, L.; Gebel, B.; Mueller, K.-H.; Schultz, L. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany)

    1998-11-20

    The application of the hydrogenation-disproportionation-desorption-recombination (HDDR) process in Sm{sub 2}Fe{sub 16}M (M=Al,Ga and Si) was investigated. The hydrogen absorption behaviour was studied by temperature-pressure analysis (TPA). In the temperature range between 500 and 800 C, Sm{sub 2}Fe{sub 16}M samples with M=Ga and Si show a weaker hydrogen absorption than Sm{sub 2}Fe{sub 16}Al. This was confirmed by X-ray diffraction which showed a complete disproportionation of Sm{sub 2}Fe{sub 16}Al into SmH{sub z} (1.9carburized HDDR powders were studied by VSM measurements and Kerr microscopy. The demagnetization curve of our HDDR processed Sm{sub 2}Fe{sub 16}AlC{sub y} is well shaped, whereas those of Sm{sub 2}Fe{sub 16}GaC{sub y} and Sm{sub 2}Fe{sub 16}SiC{sub y} show a large decrease of the polarization at low fields. The favourable behaviour of Sm{sub 2}Fe{sub 16}AlC{sub y} is due to a homogeneous submicron grain structure. In Sm{sub 2}Fe{sub 16}GaC{sub y} and Sm{sub 2}Fe{sub 16}SiC{sub y} samples, an additional, magnetically soft phase with larger domains was observed which causes the low coercivity. As a consequence, HDDR was only favourable for the preparation of Sm{sub 2}Fe{sub 16}MC{sub y} hard magnets with M=Al but not for M=Ga and Si. Optimization of the HDDR process in Sm{sub 2}Fe{sub 16}Al and subsequent nitrogenation or carburization led to coercivities of {mu}{sub 0j}H{sub c}=2.9 and 2.5 T, respectively. (orig.) 11 refs.

  10. Stabilization of mixed carbides of uranium-plutonium by zirconium. Part 1.: uranium carbide with small additions of zirconium; Etude de la stabilisation des carbures mixtes d'uranium et de plutonium par addition de zirconium. 1. partie: etude des carbures d'uranium avec de faibles additions de zirconium

    Energy Technology Data Exchange (ETDEWEB)

    Bocker, S [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    Cast carbide samples, being of a high density and purity, are preferable for research purposes, to samples produced by powder metallurgy methods. Samples of uranium carbide with small additions of zirconium (1 to 5 per cent) were cast, as rods, in an arc furnace. A single phase carbide with interesting qualities was produced. As cast, a dendrite structure is observed, which does not disappear, after a treatment at 1900 deg. C during 110 hours. In comparison with uranium monocarbide the compatibility with stainless steel is much improved. The specific heat (between room temperature and 2500 deg. C) is similar to the specific heat of uranium monocarbide. A study of these mixed carbides, but having a part of the uranium replaced by plutonium is under way. (author) [French] Les echantillons de monocarbures obtenus par coulee sont tres interessants pour les recherches experimentales a cause de leur grande purete, de leur densite tres elevee et de la facilite d'obtention des lingots de forme et dimensions variees. On a prepare et coule dans un four a arc des echantillons de carbures d'uranium avec de faibles additions de zirconium (1 a 5 at. pour cent). On obtient ainsi des carbures monophases presentant de meilleures proprietes que le monocarbure d'uranium. A l'etat brut de coulee on observe une structure dendritique qui n'est pas detruite par un traitement thermique de 110 heures a 1900 deg. C. La compatibilite avec l'acier inoxydable 316 (a 925 deg. C pendant 500 heures) est nettement amelioree par rapport a UC. La chaleur specifique (entre la temperature ordinaire et 2500 deg. C) et la densite sont tres peu differentes de celles du monocarbure d'uranium. Une etude concernant les composes U-Pu-Zr-C est actuellement en cours. (auteur)

  11. Rational Formulation of Alternative Fuels using QSPR Methods: Application to Jet Fuels Développement d’un outil d’aide à la formulation des carburants alternatifs utilisant des méthodes QSPR (Quantitative Structure Property Relationship: application aux carburéacteurs

    Directory of Open Access Journals (Sweden)

    Saldana D.A.

    2013-06-01

    from the literature, from experimental measurements and from molecular simulations for complex molecules. The interest of such models in the selection of molecules can be shown for example by the trade-off between cold flow properties and density of paraffinic compounds. If the carbon chain length is too high, the cold flow properties are compromised. One solution can be to increase branching or incorporate fuel base with good cold flow properties such as naphthenic or aromatic compounds. However, this leads to a decrease in density below the jet fuel specification. Again, using naphthenic of alkyl-aromatic compounds produced from biomass can help. Le développement des carburants alternatifs est en plein essor, notamment dans le domaine aéronautique. Cela se concrétise par la possibilité d’incorporer jusqu’à 50 % de carburants de synthèse de type Fischer- Tropsch (FT ou hydroprocessed esters and fatty acids (HEFA dans du carburéacteur. De même, ces carburants paraffiniques se développent pour le transport terrestre en parallèle des biocarburants à base d’esters ou d’alcool actuellement disponibles. La formulation de ces carburants alternatifs est actuellement basée sur une sélection des produits via des critères physiques. L’atteinte de ces critères se fait souvent par des formulations empiriques et ce type de fonctionnement ne s’avère pas très efficace et montre ses limites. En effet, les carburants alternatifs présentent des propriétés chimiques qui peuvent être différentes en fonction du procédé (répartition n-paraffines/iso-paraffines, longueur de chaîne, ramification, etc. et donc modulable. Ainsi, une nouvelle voie pourrait être envisagée visant à déterminer par le calcul, la molécule (ou le mélange de molécules la plus à même de répondre au cahier des charges du carburant, puis à étudier ou à optimiser les voies de synthèse permettant d’accéder à ces produits. Le travail présenté a pour objectif le d

  12. Hardness and stability of a carburized surface layer on AISI 316L stainless steel after irradiation in a spallation neutron environment

    International Nuclear Information System (INIS)

    McClintock, David A.; Hyres, James W.; Vevera, Bradley J.

    2014-01-01

    The inner surfaces of mercury target vessels at the Spallation Neutron Source (SNS) experience material erosion caused by proton-beam induced cavitation of the liquid mercury. One approach developed and deployed to inhibit erosion of the target vessel material was surface hardening via a proprietary low-temperature carburization treatment, called Kolsterising®, to the target surfaces most susceptible to cavitation-induced erosion. Previous testing has shown that the hardened surface produced by the Kolsterising® treatment can delay the onset of erosion and inhibit erosion once initiated. But the stability of the carbon atmosphere in the treated surface layer after radiation to doses prototypic to the SNS target was unknown. Therefore, as part of the target Post Irradiation Examination program at the SNS, optical microscopy and microhardness testing were performed on material sampled from the first and second operational SNS target vessels. Optical micrographs contained no noticeable precipitation in the super-saturated carbon layer extending into the base material and several micrographs contained evidence of a proposed mechanism for mass wastage from the vessel surface. The hardened layer was characterized using Vickers microhardness testing and results show that the shape of hardness profile of the treated layer corresponded well with known pre-irradiation hardness values, though the microhardness results show some hardening occurred during irradiation. The results suggest that the hardened surface layer produced by the Kolsterising® treatment is stable at the operational temperatures and dose levels experienced by the first and second operational SNS target modules

  13. Thermochemical Conversion of Lignin for Fuels and Chemicals: A Review Conversion thermochimique de la lignine en carburants et produits chimiques : une revue

    Directory of Open Access Journals (Sweden)

    Joffres B.

    2013-10-01

    Full Text Available Lignin is one of the biomass components potentially usable as renewable resource to produce fuels or chemicals. After separation from the lignocellulosic matrix, this macromolecule is nowadays essentially valorized by combustion in paper mills. If second generation ethanol is produced in the future from lignocellulosic biomass, some increasing reserves of lignin will be available in addition to the ones coming from the paper industry. The main thermochemical ways such as pyrolysis, solvolysis, hydrothermal conversion and hydroconversion considered for the valorization of the lignin are reviewed in this article. La lignine est une des composantes de la biomasse lignocellulosique potentiellement valorisable comme ressource renouvelable pour la production de carburants ou de produits chimiques. Après séparation de la matrice lignocellulosique, cette macromolécule est de nos jours essentiellement utilisée comme combustible dans l’industrie papetière. Outre cette filière papetière, la production d’éthanol de seconde génération à partir de la cellulose aura comme conséquence la mise à disponibilité d’encore plus grandes quantités de lignine. De nouvelles applications pourront donc être proposées pour l’utilisation de cette bio-ressource. Les différentes voies thermochimiques : pyrolyse, solvolyse, conversion hydrothermale et hydroconversion envisagées pour la valorisation de la lignine sont décrites dans cet article.

  14. L'auto adaptation à des mélanges essence/alcool utilisés comme carburant automobile: le moteur souple The Self-Adapting of Gasoline/Alcohol Mixtures Used As Automotive Fuel: the Flexible Engine

    Directory of Open Access Journals (Sweden)

    Dorbon M.

    2006-11-01

    Full Text Available Le moteur souple est un moteur susceptible d'être alimenté par des carburants constitués de mélanges d'une essence classique et d'un alcool léger (méthanol ou éthanol; si la concentration de chacun des composants de ces mélanges varie, les réglages nécessaires au bon fonctionnement du véhicule se font automatiquement. Dans cet article, sont tout d'abord exposées les propriétés caractéristiques en tant que carburant automobile de l'un de ces alcools légers, le méthanol. Puis viennent les descriptions des dispositifs qui font le moteur souple c'est-à-dire d'une part les systèmes de reconnaissance du carburant et d'autre part les appareillages susceptibles de modifier les réglages du moteur (alimentation et allumage en fonction de la qualité du mélange consommé. A flexible engine is one capable of running on fuels consisting of mixtures of conventional gasoline and a light alcohol (methanol or ethanol. If the concentration of each of these components of such mixtures varies, the tuning required for the proper running of the vehicle takes place automatically. This article begins by describing the characteristic properties of one of these light alcohols (methanol as an automotive fuel. Then the equipment is described that makes an engine flexible, i. e. both the fuel recognition systems and the equipment capable of changing engine tuning (feed and ignition as a function of the quality of the mixture burned.

  15. Comportement des matériaux organiques vis-à-vis des carburants oxygénés The Behavior of Organic Materials with Regard to Oxygenated Fuels

    Directory of Open Access Journals (Sweden)

    Puisais M.

    2006-11-01

    Full Text Available Les incidences d'emploi des produits oxygénés dans les carburants ont été déterminées sur la tenue des principaux matériaux polymères utilisés dans les véhicules et les équipements de distribution. Des carburants renferment diverses teneurs en éthanol ou en méthanol, éventuellement en conjonction avec des co-solvants tels que le tertiobutanol ou un mélange acétonobutylique ont été examinés. Les méthodes d'essais appliquées ont permis de déterminer le comportement à long terme des matériaux au niveau de leur perméabilité, gonflement, vieillissement, fissuration sous contraintes, extraction et résistance à l'ozone. The effects of using oxygenated products in gasolines have been determined concerning the resistance of the leading polymer materials used in vehicles and distribution equipment. Fuels containing varying amounts of ethanol or methanol, possibly in conjunction with cosolvents such as tertiobutanol or a butanol-acetone mixture, have been examined. The test methods applied have determined the long-term behavior of materials with regard to their permeability, swelling, aging, stress cracking, extraction and ozone resistance.

  16. Irradiation behaviour of mixed uranium-plutonium carbides, nitrides and carbonitrides; Comportement a l'irradiation de carbures, nitrures et carbonitrures mixtes d'uranium et de plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Mikailoff, H; Mustelier, J P; Bloch, J; Leclere, J; Hayet, L [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1967-07-01

    In the framework of the research program of fast reactor fuels two irradiation experiments have been carried out on mixed uranium-plutonium carbides, nitrides and carbo-nitrides. In the first experiment carried out with thermal neutrons, the fuel consisted of sintered pellets sheathed in a stainless steel can with a small gap filled with helium. There were three mixed mono-carbide samples and the maximum linear power was 715 W/cm. After a burn-up slightly lower than 20000 MW day/tonne, a swelling of the fuel which had ruptured the cans was observed. In the second experiment carried out in the BR2 reactor with epithermal neutrons, the samples consisted of sintered pellets sodium bonded in a stainless steel tube. There were three samples containing different fuels and the linear power varies between 1130 and 1820 W/cm. Post-irradiation examination after a maximal burn-up of 1550 MW day/tonne showed that the behaviour of the three fuel elements was satisfactory. (authors) [French] Dans le cadre du programme d'etude des conibustiles pour reacteurs rapides, on a realise deux experiences d'irradiation de carbures, nitrures et carbonitrures mixtes d'uranium et de plutonium. Dans la premiere experience, faite en neutrons thermiques, le combustible etait constitue de,pastilles frittees gainees dans un tube d'acier inoxydable avec un faible jeu rempli d'helium. Il y avait trois echantillons de monocarbures mixtes, et la puissance lineaire maximale etait de 715 W/cm. Apres un taux de combustion legerement inferieur a 20 000 MWj/t, on a observe un gonflement des combustible qui a provoque, la rupture des gaines. Pans la seconde experience, realisee dans le reacteur BR2 en neutrons epithermiques, les echantillons etaient constitues de pastilles frittees gainees dans un tube d'acier avec un joint sodium. Il y avait trois echantillons contenant des combustibles differents, et la puissance lineaire variait de 1130 a 1820 W/cm. Les examens apres irradiation a un taux maximal de

  17. Fuel Penalty Comparison for (Electrically Heated Catalyst Technology Comparaison de l’augmentation de consommation de carburant pour la technologie de catalyseurs chauffés à l’électricité

    Directory of Open Access Journals (Sweden)

    Kessels J. T.B.A.

    2010-03-01

    Full Text Available The conversion efficiency of three way catalytic converters is mainly defined by the temperature range wherein they are operating. Traditionally, ignition retard has been used to reduce the light-off time of the catalyst. This is however associated with a fuel penalty. With increasing vehicle electrification, electrically heating facilities present an alternative, especially for hybrid vehicles. Nevertheless, system complexity of hybrid vehicles prevents engineers to evaluate possible heating technologies and their corresponding fuel penalty with respect to traditional solutions. This paper evaluates the application of an electrically heated catalyst on a hybrid vehicle equipped with a Natural Gas (NG engine. The effect of heating power on light-off time and fuel penalty is determined, using analysis techniques emerging from integrated powertrain control. By means of a case study, the importance of an integral approach is explained by comparing the fuel penalty and conversion efficiency improvement of electric heating with that of ignition retard. In this process, a mix of simulation and test data were combined, forming the foundations for future control developments of a suitable light-off strategy. L’efficacité de conversion des catalyseurs est principalement définie par la gamme de température dans laquelle ils fonctionnent. Un retard du point d’allumage a traditionnellement été utilisé pour réduire le temps d’amorçage du catalyseur. Ceci est cependant associé à une augmentation de la consommation de carburant. Avec l’électrification des véhicules, la possibilité de chauffage électrique représente véritablement une alternative, tout particulièrement pour les véhicules hybrides. Cependant, la complexité des véhicules hybrides rend difficile l’évaluation des technologies de chauffage éventuelles ainsi que l’augmentation de la consommation de carburant associée ; il est aussi difficile de comparer ces r

  18. The influence of surface microstructure and chemical composition on corrosion behaviour in fuel-grade bio-ethanol of low-alloy steel modified by plasma nitro-carburizing and post-oxidizing

    Science.gov (United States)

    Boniatti, Rosiana; Bandeira, Aline L.; Crespi, Ângela E.; Aguzzoli, Cesar; Baumvol, Israel J. R.; Figueroa, Carlos A.

    2013-09-01

    The interaction of bio-ethanol on steel surfaces modified by plasma-assisted diffusion technologies is studied for the first time. The influence of surface microstructure and chemical composition on corrosion behaviour of AISI 4140 low-alloy steel in fuel-grade bio-ethanol was investigated. The steel surfaces were modified by plasma nitro-carburizing followed plasma oxidizing. X-ray diffraction, scanning electron microscopy, optical microscopy, X-ray dispersive spectroscopy, and glow-discharge optical emission spectroscopy were used to characterize the modified surface before and after immersion tests in bio-ethanol up to 77 days. The main corrosion mechanism is pit formation. The pit density and pit size were measured in order to quantify the corrosion resistance which was found to depend more strongly on microstructure and morphology of the oxide layer than on its thickness. The best corrosion protection was observed for samples post-oxidized at 480 °C and 90 min.

  19. The influence of surface microstructure and chemical composition on corrosion behaviour in fuel-grade bio-ethanol of low-alloy steel modified by plasma nitro-carburizing and post-oxidizing

    International Nuclear Information System (INIS)

    Boniatti, Rosiana; Bandeira, Aline L.; Crespi, Ângela E.; Aguzzoli, Cesar; Baumvol, Israel J.R.; Figueroa, Carlos A.

    2013-01-01

    The interaction of bio-ethanol on steel surfaces modified by plasma-assisted diffusion technologies is studied for the first time. The influence of surface microstructure and chemical composition on corrosion behaviour of AISI 4140 low-alloy steel in fuel-grade bio-ethanol was investigated. The steel surfaces were modified by plasma nitro-carburizing followed plasma oxidizing. X-ray diffraction, scanning electron microscopy, optical microscopy, X-ray dispersive spectroscopy, and glow-discharge optical emission spectroscopy were used to characterize the modified surface before and after immersion tests in bio-ethanol up to 77 days. The main corrosion mechanism is pit formation. The pit density and pit size were measured in order to quantify the corrosion resistance which was found to depend more strongly on microstructure and morphology of the oxide layer than on its thickness. The best corrosion protection was observed for samples post-oxidized at 480 °C and 90 min.

  20. Fuels distribution; Distribution des carburants

    Energy Technology Data Exchange (ETDEWEB)

    Le Brun, S.

    2004-12-01

    Although they have never stop to increase for thirty years, the shares of market of the large stores in the sales of fuels make nowadays a stop. Have the strict reorganizing the structure of the petroleum networks and their marketing strategy at last borne fruit? During the Petroleum Days have been discussed the evolvements of the service stations and of the consumer behaviour. (O.M.)

  1. Contribution to the study of U-Ti and U-Pu-Ti carbides; Contribution a l'etude des carbures U-C-Ti et (U, Pu) - C-Ti

    Energy Technology Data Exchange (ETDEWEB)

    Milet, C A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    After having discussed the reasons to use (U,Pu) carbides as fast reactor fuel, we examine the influence of the addition of titanium to these carbides. A preliminary study has been done on the system of U-C-Ti and some properties have been measured such as: density, thermal expansion, electrical resistivity, atmospheric corrosion and compatibility with stainless steel. The systems U-Pu-C-Ti (Pu/U + Pu equal to 15 per cent) and U-C-Ti have been found to be very similar. There exists a two phases region (U,Pu)C + TiC, an eutectic between (U,Pu)C and TiC for approximately 15 at %. The solubilities of U + Pu in TiC and of Ti in (U,Pu)C is less than 1 % at. The addition of titanium does not markedly change thermal expansion coefficients of (U,Pu)C. However the resistance to atmospheric corrosion and compatibility with stainless steel is improved. Thermal conductivity, calculated from electrical resistivity, has increased. On the other side, the density of fissile material is lowered. The combination of (U,Pu)C + TiC seems to be the most promising alloy for application as nuclear fuel. (author) [French] Apres avoir rappele les problemes poses par un combustible pour les reacteurs a neutrons rapides et l'interet des carbures U-Pu-C comme combustible, on examine l'influence de l'addition de titane dans ces carbures. Une etude preliminaire sur le systeme U-C-Ti a ete effectuee et quelques proprietes sont indiquees: densite, coefficients de dilatation, resistivite electrique, tenue a la corrosion atmospherique, compatibilite avec l'acier inoxydable. Le systeme U-Pu-C-Ti (Pu/U + Pu egal a 15 pour cent) presente de grandes analogies avec le systeme U-C-Ti. Il existe un domaine biphase (U,Pu)C + TiC, un eutectique entre (U,Pu)C et TiC pour environ 15 at % Ti; les solubilites de U + Pu clans TiC et de Ti dans (U,Pu)C sont inferieures a 1 at %. Par rapport a la phase (U,Pu)C, l'addition de titane est sans effets importants sur les coefficients de dilatation. Par contre la tenue a

  2. Etude numérique et expérimentale de l'evaporation d'une ou plusieurs gouttes de mélange de carburants dans un écoulement chauffé

    Science.gov (United States)

    Daïf, A.; Ali Chérif, A.; Bresson, J.; Sarh, B.

    1995-10-01

    The vaporization of one or two multi-component fuel droplets in hot air-stream is presented. A thermal wind tunnel with experimental channel has been designed to develop an experimental process. Firstly, the comparison between experimental results and numerical data is presented for the case of an isolated multi-component droplet. The numerical method is based on the resolution of heat and mass transfer equations between the droplet and the gas stream. This model includes the effect of Stephan flow, the effect of variable thermophysical properties of the components, and the non-unitary Lewis number in the gas film. The experimental results show the micro-explosion phenomenon observed in the liquid phase of multi-component droplet at low temperature. The experimental case of two pure or multi-component droplets in interaction is also presented. On présente un article de synthèse sur l'évaporation d'une ou deux gouttes de carburants à plusieurs composants dans un écoulement d'air chaud. Un dispositif expérimental constitué d'une soufflerie thermique, avec veine d'expérimentation, est réalisé pour permettre cette étude. Pour le cas d'une goutte isolée, une comparaison expérience-calcul est entreprise. Le principe de la méthode numerique consiste en la résolution des équations de transfert de masse et de chaleur entre la goutte et l'écoulement. Ce modèle prend en compte les effets de l'écoulement de Stephan, les variations des propriétés thermophysiques des composants dans les deux phases et la valeur du nombre de Lewis différente de l'unité dans le film de vapeur. Outre l'analyse plus approfondie qu'apporte la confrontation entre le calcul et l'expérience, les résultats expérimentaux montrent le phénomène de micro-explosion observé à l'intérieur de la goutte liquide. Le cas expérimental de deux gouttes en interaction est abordé qu'il s'agisse de gouttes de carburant pur ou de mélange.

  3. ETUDE EXPERIMENTALE DE L’INFLUENCE DE LA RIGIDITE STATIQUE DES TOURS SUR LE COMPORTEMENT A L’USURE DES PLAQUETTES EN CARBURE METALLIQUE «NUANCE P25 »

    Directory of Open Access Journals (Sweden)

    L BOULANOUAR

    2002-12-01

    Full Text Available Ce travail consiste à étudier expérimentalement l’influence de quelques machines-outils sur le comportement à l’usure des plaquettes en carbure métalliques. Les essais ont été réalisés dans des conditions opératoires proches de celles industrielles. Les machines-outils utilisées sont caractérisées par leurs rigidités. Le suivi de l’évolution de l’usure des plaquettes en fonction du temps (τ et des éléments du régime de coupe (v, f et d sur chaque machine a été établi conformément à la méthode de planification des expériences. Les résultats obtenus ont été traités, analysés et interprétés physiquement.

  4. Electron bombardment fusion and continuous casting of uranium carbide. Fundamental study of the metallurgical and thermal processes; Fusion sous bombardement d'electrons et coulee continue de carbure d'uranium. Etude fondamentale des processus metallurgiques et thermiques

    Energy Technology Data Exchange (ETDEWEB)

    Trouve, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-02-01

    During a pilot production run, about 1.200 kg of uranium carbide cylindrical rods were prepared by electron bombardment fusion and continuous casting in an apparatus making it possible to operate in a constant vacuum automatically. In order to make the most of the fusion technique used, it was necessary to resolve a certain number of problems involved in this production. It was found that the energy yield for the electron bombardment heating using accelerating voltages of about 10 kV was 100 per cent; about 40 per cent of the electrons are re-emitted by back-scattering. These electrons leave the surface with practically zero energy. The fusion technique leads to the elimination of the majority of the metallic impurities. In order to explain the variations in the non-metallic impurity contents the different reactions occurring in the molten uranium monocarbide have been determined. A micrographic study of the rods obtained has shown various types of crystallization depending on the rate of casting and, despite the uniaxial symmetry of the cooling, no texture has been observed, whatever the rate of fusion employed. The aspects of the fracture surfaces observed on certain rods can be explained by theory in the domain where the material is elastic. Furthermore it has been shown that a decrease in the brittleness occurs as a result of the formation of fine precipitates of the Wiedmanstatten structure type. (authors) [French] Au cours d'une fabrication pilote, environ 1 200 kg de barreaux cylindriques de carbure d'uranium ont ete prepares par fusion sous bombardement d'electrons et coulee continue dans un appareillage permettant d'operer d'une maniere automatique sous vide constant. Afin de tirer le meilleur parti possible de la technique de fusion utilisee, il importait de repondre a un certain nombre de questions soulevees par cette fabrication. Le rendement energetique du chauffage par bombardement d'electrons pour des tensions acceleratrices de l'ordre de 10 kV a ete

  5. Study of the machining of uranium carbide rods obtained by continuous casting under electronic bombardment; Etude de l'usinage de barreaux de carbure d'uranium obtenus par coulee continue sous bombardement electronique

    Energy Technology Data Exchange (ETDEWEB)

    Rousset, P; Accary, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The authors consider the various methods of machining uranium mono-carbide and compare them critically in the case of their application to uranium carbide obtained by fusion under an electronic bombardment and continuous casting. This study leads them to propose two mechanical machining methods: cylindrical rectification and center-less rectification, preceded by a preliminary roughing out of a cylinder, the latter appearing more suitable. A study of the machining yields as a function of the diameter of the rough bars and of the diameter of the finished rods has shown that an optimum value of the rough bar diameter exists for each value of the finished rod diameter. It is found that the yield increases as the diameter itself increases, this yield rising from 45 per cent to around 70 per cent as the diameter of the rough bars increases from 25-26 mm to 37-38 mm. (authors) [French] Les auteurs envisagent les differentes methodes d'usinage du monocarbure d'uranium et se livrent a une etude critique de celles-ci, dans le cas de leur application a l'usinage de barreaux de carbure d'uranium obtenus par fusion sous bombardement electronique et coulee continue. Cette etude les conduit a proposer deux methodes d'usinage mecanique: la rectification cylindrique et la rectification 'centerless', precedee d'un ebauchage par carottage, la seconde paraissant la plus appropriee. L'etude des rendements d'usinage en fonction du diametre des barreaux bruts et du diametre des barreaux finis, a mis en evidence une valeur optimale du diametre des barreaux bruts pour chaque valeur du diametre des barreaux usines. Elle a montre que le rendement croit lorsque le diametre croit lui-meme, ce rendement passant d'environ 45 pour cent a environ 70 pour cent, lorsque le diametre des barreaux bruts passe de 25-26 mm a 37-38 mm.

  6. A Comprehensive Numerical Study on Effects of Natural Gas Composition on the Operation of an HCCI Engine Une étude numérique complète sur les effets de la composition du gaz naturel carburant sur le réglage d’un moteur HCCI

    Directory of Open Access Journals (Sweden)

    Jahanian O.

    2011-11-01

    Full Text Available Homogeneous Charge Compression Ignition (HCCI engine is a promising idea to reduce fuel consumption and engine emissions. Natural Gas (NG, usually referred as clean fuel, is an appropriate choice for HCCI engines due to its suitable capability of making homogenous mixture with air. However, varying composition of Natural Gas strongly affects the auto-ignition characteristics of in-cylinder mixture and the performance of the HCCI engine. This paper has focused on the influence of Natural Gas composition on engine operation in HCCI mode. Six different compositions of Natural Gas (including pure methane have been considered to study the engine performance via a thermo-kinetic zero-dimensional model. The simulation code covers the detailed chemical kinetics of Natural Gas combustion, which includes Zeldovich extended mechanism to evaluate NOx emission. Validations have been made using experimental data from other works to ensure the accuracy needed for comparison study. The equivalence ratio and the compression ratio are held constant but the engine speed and mixture initial temperature are changed for comparison study. Results show that the peak value of pressure/temperature of in-cylinder mixture is dependent of fuel Wobbe number. Furthermore, engine gross indicated power is linearly related to fuel Wobbe number. Gross indicated work, gross mean effective pressure, and NOx are the other parameters utilized to compare the performance of engine using different fuel compositions. Le moteur HCCI (Homogeneous Charge Compression Ignition, ou à allumage par compression d’une charge homogène est une idée prometteuse pour réduire la consommation de carburant et les émissions polluantes. Le gaz naturel, considéré généralement comme un carburant propre, est un choix approprié pour les moteurs HCCI en raison de sa capacité à former avec l’air un mélange homogène. Cependant, la composition du gaz naturel influe fortement sur les caract

  7. Study of the machining of uranium carbide rods obtained by continuous casting under electronic bombardment; Etude de l'usinage de barreaux de carbure d'uranium obtenus par coulee continue sous bombardement electronique

    Energy Technology Data Exchange (ETDEWEB)

    Rousset, P.; Accary, A. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    The authors consider the various methods of machining uranium mono-carbide and compare them critically in the case of their application to uranium carbide obtained by fusion under an electronic bombardment and continuous casting. This study leads them to propose two mechanical machining methods: cylindrical rectification and center-less rectification, preceded by a preliminary roughing out of a cylinder, the latter appearing more suitable. A study of the machining yields as a function of the diameter of the rough bars and of the diameter of the finished rods has shown that an optimum value of the rough bar diameter exists for each value of the finished rod diameter. It is found that the yield increases as the diameter itself increases, this yield rising from 45 per cent to around 70 per cent as the diameter of the rough bars increases from 25-26 mm to 37-38 mm. (authors) [French] Les auteurs envisagent les differentes methodes d'usinage du monocarbure d'uranium et se livrent a une etude critique de celles-ci, dans le cas de leur application a l'usinage de barreaux de carbure d'uranium obtenus par fusion sous bombardement electronique et coulee continue. Cette etude les conduit a proposer deux methodes d'usinage mecanique: la rectification cylindrique et la rectification 'centerless', precedee d'un ebauchage par carottage, la seconde paraissant la plus appropriee. L'etude des rendements d'usinage en fonction du diametre des barreaux bruts et du diametre des barreaux finis, a mis en evidence une valeur optimale du diametre des barreaux bruts pour chaque valeur du diametre des barreaux usines. Elle a montre que le rendement croit lorsque le diametre croit lui-meme, ce rendement passant d'environ 45 pour cent a environ 70 pour cent, lorsque le diametre des barreaux bruts passe de 25-26 mm a 37-38 mm.

  8. 3d Simulation of Di Diesel Combustion and Pollutant Formation Using a Two-Component Reference Fuel Simulation 3D de la combustion et de la formation des polluants dans un moteur Diesel à injection directe en utilisant un carburant de référence à deux composants

    Directory of Open Access Journals (Sweden)

    Barths H.

    2006-12-01

    reference fuels. The contributions of the different reaction paths (thermal, prompt, nitrous, and reburn to the NO formation are shown. Finally, the importance of the mixing process for the prediction of soot emissions is discussed. En séparant calculs aérodynamiques et calculs chimiques, le modèle instationnaire de flamelet permet d'introduire des mécanismes chimiques complets qui comprennent plusieurs centaines de réactions. Ceci est indispensable pour décrire les différents processus qui ont lieu dans un moteur Diesel à injection directe (ID tels que l'auto-inflammation, la fin de la phase de prémélange partiel, la transition vers une combustion diffusive et la formation de polluants tels que les NOx et les suies. Il n'est pas nécessaire de simplifier les taux de réactions hautement non linéaires, d'autre part, la structure complète du processus de combustion est conservée. En utilisant le modèle de type Representative Interaction Flamelet (RIF, l'ensemble monodimensionnel instationnaire d'équations différentielles aux dérivées partielles est résolu en interaction avec le code CFD 3D. La solution ainsi obtenue est couplée avec les flux gazeux et le champ de mélange par l'intermédiaire de plusieurs paramètres dépendant du temps (l'enthalpie, la pression, le taux scalaire de dissipation. En retour, le modèle de flamelet fournit les concentrations moyennes des espèces chimiques, qui sont ensuite exploitées par le code CFD 3D pour calculer les champs de températures et les densités. La densité est nécessaire au code CFD 3D pour déterminer les flux turbulents et le champ de mélange. La formation des polluants est déterminée expérimentalement dans un moteur Diesel Volkswagen DI 1900. Le moteur est alimenté avec du gazole et deux carburants de référence. Un des carburants de référence est du n-décane pur. Le second est un carburant bicomposant formé de 70 % (du volume liquide de n-décane et de 30 % d'alpha-méthylnaphtalène (Idea

  9. Utilisation des huiles végétales et de leurs produits de transestérification comme carburants Diesel Use of Vegetable Oils and Their Transesterification Products As Diesel Fuels

    Directory of Open Access Journals (Sweden)

    Gateau P.

    2006-11-01

    Full Text Available L'utilisation d'huiles végétales et de leurs dérivés comme carburants Diesel a fait l'objet, depuis 1981, de plusieurs études financées par l'Agence Française pour la Maîtrise de l'Energie (AFME et réalisées par l'institut Français du Pétrole (lFP en collaboration avec Elf Renault, le Centre d'Etudes et d'Expérimentation du Machinisme Agricole Tropical (CEEMAT et l'institut de Recherches pour les Huiles et Oléagineux (IRHO. Ce document rassemble les résultats obtenus au banc d'essai sur plusieurs types de moteurs représentant un assez large éventail d'applications, depuis le motoculteur utilisé en agriculture africaine jusqu'au moteur classique de tracteur ou de camion. Deux types de produits ont été examinés : les huiles végétales elles-mêmes employées pures ou en mélange au gazole, et les esters méthyliques de ces huiles utilisés tels quels. Lors d'un fonctionnement de courte durée les huiles aussi bien que les esters conduisent globalement à un fonctionnement satisfaisant du moteur; les pertes de performances par rapport au gazole restent modérées voire imperceptibles. Les seuls problèmes dans ce cas concernent la mise en oeuvre, difficile avec les huiles en raison de leur très forte viscosité, beaucoup plus aisée avec les esters. En endurance, l'inconvénient majeur des huiles végétales et de leurs dérivés concerne la formation de dépôts au nez des injecteurs. Sur les moteurs rustiques à préchambre (type Hatz ce phénomène reste limité puisqu'il a été possible de conduire, sans incident, un ensemble d'essais d'endurance de 1100 h avec différents types d'huiles pures (arachide, coton, palme. Sur les moteurs à Injection directe la formation de dépôts constitue une très sérieuse contrainte puisqu'elle conduit pratiquement à proscrire l'utilisation d'huiles même en mélange (25 ou 50 % dans le gazole. Les esters peuvent alors être proposés à condition qu'un certain nombre de pr

  10. D’une problématique locale-frontalière à un enjeu binational : le cas de la contrebande transfrontalière de carburants entre la Colombie et le Venezuela

    Directory of Open Access Journals (Sweden)

    Amanda Andrade Benitez

    2011-10-01

    Full Text Available Cet article propose d’appréhender le processus d’inscription de la question de la contrebande transfrontalière de carburants dans l’agenda d’intégration binational entre la Colombie et le Venezuela. Peu de travaux s’intéressent à ce sujet qui est habituellement abordé dans une perspective de politique intérieure et non pas extérieure. Notre étude s’inscrit dans le cadre théorique de la « mise en agenda » traitée par Cobb et Elders (1983 et des travaux de Jones et Baumgartner (2005 sur l’évolution de l’agenda politique après l’introduction de nouveaux enjeux. Elle vise à comprendre la manière dont la contrebande de carburants trouve une place dans l’agenda d’intégration énergétique bilatéral et devient un enjeu de coopération entre les deux pays. Les effets économiques de la contrebande ainsi que ses conséquences sur la sécurité de la frontière ont été des facteurs déterminants dans la signature d’un accord entre les deux pays. Les agences énergétiques de Colombie et du Venezuela ont été les acteurs privilégiés du processus d’inscription du problème dans l’agenda d’intégration entre les deux pays.This article analyzes the gradual inclusion of the illegal oil trade in the binational integration agenda between Venezuela and Colombia. Few scholars have focused on this question, which is generally examined through the prism of domestic –not foreign– policy. This study borrows from Cobb and Elders’ (1983 agenda setting theory and its development by Jones and Baumgartner (2005 on the evolution of political agendas following the incorporation of new issues. The purpose is to understand the ways in which illegal oil trade found its place in the bilateral energy integration agenda and became the subject of cooperation between Venezuela and Colombia. The economic effects of this illegal traffic along with its consequences on border security were crucial factors in the signing of a

  11. Visualisation of Gasoline and Exhaust Gases Distribution in a 4-Valve Si Engine; Effects of Stratification on Combustion and Pollutants Visualisation de la répartition du carburant et des gaz brûlés dans un moteur à 4 soupapes à allumage commandé ; effet de la stratification sur la combustion et les polluants

    Directory of Open Access Journals (Sweden)

    Deschamps B.

    2006-12-01

    Full Text Available sAn indirect method to map the burned gases in SI engine has been developed. It is based on visualisation by Laser Induced Fluorescence of the unburned mixture seeded with biacetyl. Both internally and externally recirculated burned gases are monitored. This diagnostic is complementary to the LIF technique applied to measure the gasoline distribution. These LIF gasoline and burned gases measurements are applied in a 4-valve optical access SI engine for a large range of operating conditions. These include variations of both fuel injection and burned gas recirculation modes causing different types of stratification leading to very distinct heat release and exhaust emissions characteristics. Tumble level and spark location are also modified. The observation of the actual stratification in the engine forms a sound basis explanation of the engine performance. Parameters allowing an optimisation of NOx and HC levels can be inferred, and in particular the effectiveness of recirculation and fuel injection strategies. The conclusions are confirmed by measurements in a single engine cylinder conventional head with the same geometry. Une méthode indirecte pour cartographier les gaz brûlés dans un moteur à allumage commandé a été développée. Elle est fondée sur une visualisation à partir de la fluorescence induite par laser (LIF du mélange air-carburant non brûlé et ensemencé avec du biacétyl. Les gaz brûlés provenant à la fois des recirculations internes et externes sont observés. Ce type de diagnostic est complémentaire des techniques de LIF utilisées pour observer la distribution du carburant. Ces mesures de concentration sont réalisées dans un moteur à 4 soupapes avec accès optiques, pour une gamme étendue de conditions opératoires. Celles-ci comprennent des variations des modes d'injection du carburant et des modes de recirculation des gaz brûlés, provoquant ainsi différents types de stratifications qui correspondent

  12. Carburation automobile. Contribution à l' étude d'un dispositif d'injection de GPL en phase gazeuse Automotive Fuel: Research on a New Gas-Phase Lpg Injection System

    Directory of Open Access Journals (Sweden)

    Dubois J. P.

    2006-11-01

    Full Text Available Les systèmes de carburation traditionnels aux GPL (induction donnent lieu à un certain nombre d'insatisfactions dues, en particulier, aux difficultés de réglages et à une adéquation imparfaite entre matériels et véhicules. Le système d'injection gazeuse mis au point comporte : - un débitmètre à volet mesurant le débit d'air admis au moteur; - un doseur, lié mécaniquement au volet, et fournissant le mélange air-gaz prédéterminé. Un dispositif d'ouverture forcée du volet permet, lorsqu'on fonctionne à l'essence, de ne pas perturber les performances du carburateur; - un vaporiseur détendeur à deux étages dont les fonctions essentielles sont : - la prédétente à 1,5 bar; - la détente finale à 250 mbar; - l'enrichissement à haut régime; - la sécurité intégrée en cas d'arrêt moteur; - un module de démarrage à froid évitant l'envahissement liquide du vaporiseur jusqu'à 10°C Les avantages de ce dispositif sont : - l'universalité : le même modèle est utilisé sur tous véhicules de 60 à 130 ch; - l'absence de réglage : seul le ralenti est à ajuster; - la maîtrise du rapport air/gaz à la valeur choisie; - le bon compromis performances/consommations; - la prise en compte des paramètres réels de fonctionnement. Conventional LPG induction systems used for transportation purposes do not usually work satisfactory, in particular due to adjustment difficulties and to unsuitable equipment/vehicle matching. The LPG injection system that has been developed comprises:(aa flap flowmeter measuring the air flow into the- engine;(b a proportioning device mechanically connected to the flap and supplying the predetermined air/gas mixture (a device forcing the flap open keeps carburettor performances the same when running on gasoline;(c a two-stage pressure regulator having the following main functions:- initial expansion down to 1. 5 bar;- final expansion down to 250 mbar;- high-speed enrichment;- built-in safety in case

  13. Silicon carbide technology; Technologie carbure de silicium

    Energy Technology Data Exchange (ETDEWEB)

    Billon, Th. [CEA Grenoble, LETI, 38 - Grenoble (France)

    2001-07-01

    SiC is a semiconductor material with better performances than Si in the domain of high power, high frequency and high temperature electronic applications. The markets concerned by the SiC technology are those of electric appliances, electronic equipments, telecommunication and power distribution systems, electrical vehicles etc.. This article summarizes the R and D works carried out since 1989 by the CEA-LETI in the domain of SiC technology and its experience in crystal growth methods for the elaboration of monocrystal SiC substrates with a low density of defects. (J.S.)

  14. Use of Ethanol/Diesel Blend and Advanced Calibration Methods to Satisfy Euro 5 Emission Standards without DPF Utilisation d’un carburant Diesel éthanolé à l’aide de méthodes de calibration avancées afin de satisfaire les normes Euro 5 sans filtre à particules

    Directory of Open Access Journals (Sweden)

    Magand S.

    2011-11-01

    innovative calibration methods, based on the simultaneous optimisation of engine basic settings and cold correction maps, are introduced in order to better suit to the new formulation impact on combustion and catalyst light-off and to drop off engine-out unburned hydrocarbons and carbon monoxide emissions. This stage allows pushing forward the work on test bed facilities in order to reduce the amount of vehicle tests. Tests on a chassis dynamometer are only used to validate the engine test bed results and to perform final tuning of cold correction maps. This alternative blend shows potential to achieve Euro 5 standard with Euro 4 Diesel vehicle configuration, without any hardware modification and without a Diesel particulate filter in the exhaust line. Such an innovative fuel formulation seems to be an interesting answer to the trade-off in the forthcoming years between cost and emissions reduction to achieve sustainable mobility. The presented calibration methods and tools allow to fully take advantage of this alternative fuel in a reduced time scale. L’utilisation des biocarburants s’est développée durant ces dernières années de façon importante afin de diversifier les sources d’énergies et de limiter la hausse des émissions de gaz à effet de serre du secteur des transports. L’un des carburants renouvelables les plus adaptés à une production de masse est l’éthanol. Celui-ci est aujourd’hui principalement utilisé dans les moteurs à allumage commandé, alors que la part des véhicules Diesel sur le marché européen est de l’ordre de 60 %. Ce constat nous a incité à proposer une formulation innovante utilisant de l’éthanol pour les applications Diesel. Les principaux verrous technologiques pour cette utilisation sont la miscibilité, la température d’éclair, la lubrification ou encore l’indice de cétane. Des travaux ont été réalisés pour optimiser la formulation contenant de l’éthanol, des biodiesels de première et seconde g

  15. Design, Fabrication and Performance of Boron-Carbide Control Elements; Conception, Fabrication et Comportement de Lames de Commande en Carbure de Bore; Raschety, izgotovlenie i kharakteristiki reguliruyushchikh sterzhnej. Iz karbida Bora; Proyecto, Elaboracion y Rendimiento de Elementos de Control de Carburo de Boro

    Energy Technology Data Exchange (ETDEWEB)

    Brammer, H. A.; Jacobson, J. [General Electric Company, San Jose, CA (United States)

    1964-06-15

    A control blade design, incorporating boron-carbide (B{sub 4}C) in stainless-steel tubes, was introduced into service in boiling water reactors in April 1961. Since that time this blade has become the standard reference control element in General Electric boiling-water reactors, replacing the 2% boron-stainless-steel blades previously used. The blades consist of a sheathed, cruciform array of small vertical stainless-steel tubes filled with compacted boron-carbide powder. The boron-carbide powder is confined longitudinally into several independent compartments by swaging over ball bearings located inside the tubes. The development and use of boron-carbide control rods is discussed in five phases: 1. Summary of experience with boron-steel blades and reasons for transition to boron-carbide control; 2. Design of the boron-carbide blade, beginning with developmental experiments, including early measurements performed in the AEC ''Control Rod Material and Development Program'' at the Vallecitos Atomic Laboratory, through a description of the final control blade configuration; 3. Fabrication of the blades and quality control procedures; 4. Results of confirmatory pre-operational mechanical and reactivity testing; and 5. Post-operational experience with the blades, including information on the results of mechanical inspection and reactivity testing after two years of reactor service. (author) [French] Un modele de lame de commande en carbure de bore (B{sub 4}C) a ete mis en place dans des reacteurs a eau bouillante en avril 1961. Depuis lors, cette lame est devenue l 'element de commande temoin classique dans les reacteurs a eau bouillante de la General Electric et a remplace les lames en acier inoxydable a 2% de bore utilisees auparavant. Ces lames consistent en un assemblage gaine cruciforme comprenant de petits tubes d'acier inoxydable verticaux remplis de poudre de carbure de bore agglomeree. Dans le sens de la longueur, cette poudre est enfermee dans plusieurs

  16. Utilisation de produits organiques oxygénés comme carburants et combustibles dans les moteurs. Deuxième partie : Les différentes filières d'obtention des carburols. Analyse technico-économique Using Oxygenated Organic Products As Fuels in Engines. Part Two: Different Systems for Producing Alcohol Fuels. Technico-Economic Analysis

    Directory of Open Access Journals (Sweden)

    Chauvel A.

    2006-11-01

    Full Text Available Parmi les produits à même d'être substitués aux hydrocarbures pour la constitution des carburants, les composés organiques oxygénés occupent une place prépondérante à cause de leurs caractéristiques favorables à la combustion dans les moteurs, qu'ils soient employés purs ou mélangés (seuls ou à plusieurs aux hydrocarbures, constituants des carburants classiques. Dans cet article, ces composés oxygénés sont désignés sous le nom de carburols. Alors que l'objet de la première partie de l'étude a été d'examiner les conséquences techniques de l'emploi de ces produits sur les circuits de distribution et le fonctionnement des véhicules, il s'agit dans la présente partie d'analyser les caractéristiques technico-économiques de leur fabrication. En particulier, on y aborde successivement les points suivants : - disponibilités en matières premières : ressources fossiles et végétales ; - analyse technique des divers modes d'obtention - analyse économique ; - programmes nationaux. Among products that can be substituted for hydrocarbons for producing fuels, oxygenated organic compounds occupy a preponderant position because of their favorable characteristics for combustion in engines whether they are used in a pure form or in mixtures (alone or severally with hydrocarbons which are used to make up conventional fuels. In this article these oxygenated compounds are given the name carburols (alcohol fuels. Whereas the aim of Part 1 was to examine the technical consequences of using such products in distribution circuits and for vehicle operating, Part 2 is an analysis of the technico-economic aspects of manufacturing them. In particular, the following points are taken up successively: (a availabilities of raw materials. fossil and vegetebal resources; (b technical analysis of various production methods; (c economic analysis; (d national programs. Depending on the amounts involved, a distinction is made among alternative

  17. Etude d'un procédé d'hydroliquéfaction du charbon pour la production simultanée de gaz et de carburant . . . . . Studies of a Coal Hydrogenation Process to Produce CO-Currently Gas and Gasoline

    Directory of Open Access Journals (Sweden)

    Franckowiak S.

    2006-11-01

    Full Text Available Un des principaux moyens de réintroduire le charbon dans le marché énergétique français est de le transformer en produits utiles comme le gaz de réseau ou les carburants. Les procédés d'oxyvapogazéification permettent d'obtenir un gaz de synthèse qui peut être ensuite converti en gaz riche ou en produits liquides. L'hydrogénation en phase liquide (ou hydroliquéfaction se présente pour le long terme comme une seconde voie qui offre des avantages spécifiques - taux de conversion du charbon et rendement élevés, - production directe de gaz de substitution (GNS et de carburant, - possibilité d'utilisation d'hydrogène provenant de l'électricité nucléaire. Un programme d'étude a été lancé avec la participation du Gaz de France (GDF, du Centre d'études et de recherches des Charbonnages de France (Cerchar, de l'institut Français du Pétrole (lFP et du Centre National de la Recherche Scientifique (CNRS dans le cadre du Groupe d'Étude de la Conversion du Charbon par Hydrogénation (GECH. Un banc d'essai d'hydroliquéfaction situé au Cerchar, d'un débit de 10 kg/h de mélange charbon-solvant, permet d'obtenir des hydrogénats dans des conditions variées et en présence de divers catalyseurs. L'étude de la valorisation de ces hydrogénats est effectuée dans les laboratoires de l'lFP. Les essais et les études effectués permettent d'envisager la production à volonté du GNS, de carburants ou des deux ensemble. Un modèle d'optimisation a été réalisé au GDF pour étudier et comparer les différentes filières en prenant en compte l'utilisation d'hydrogène d'électrolyse ou d'hydrogène produit sur place à partir du résidu de liquéfaction. One of the main ways to bring coal in the future french energy market is to transform it into valuable products. The oxygen steam gasification processes give a synthesis gas which can be converted into SNG or gasoline in a catalytic stage. The liquid phase hydrogenation process is a

  18. Kinetic study of uranium carburization by different carbonated gases

    International Nuclear Information System (INIS)

    Feron, Guy

    1963-01-01

    The kinetic study of the reaction U + CO 2 and U + CO has been performed by a thermogravimetric method on a spherical uranium powder, in temperature ranges respectively from 460 to 690 deg. C and from 570 to 850 deg. C. The reaction with carbon dioxide leads to uranium dioxide. A carbon deposition takes place at the same time. The global reactions is the result of two reactions: U + 2 CO 2 → UO 2 + 2 CO U + CO 2 → UO 2 + C The reaction with carbon monoxide leads to a mixture of dioxide UO 2 , dicarbide UC 2 and free carbon. The main reaction can be written. U + CO → 1/2 UO 2 + 1/2 UC 2 The free carbon results of the disproportionation of the carbon monoxide. A remarkable separation of the two phases UO 2 and UC 2 can be observed. A mechanism accounting for the phenomenon has been proposed. The two reactions U + CO 2 and U + CO begin with a long germination period, after which, the reaction velocity seems to be limited in both cases by the ionic diffusion of oxygen through the uranium dioxide. (author) [fr

  19. Effect of preliminary oxidation on process of steel carburization

    Energy Technology Data Exchange (ETDEWEB)

    Devochkin, O V; Vorontsov, E S; Filonov, V N [Voronezhskij Politekhnicheskij Inst. (USSR)

    1975-01-01

    Effects of preliminary oxidation of the metal surface and its subsequent reduction steel cementation were studied. The samples with interferentionally coloured oxide film on the surface had deeper carbonated layer than those without film. The kinetics of carbonation process and the mechanism proposed for this phenomenon are given.

  20. Hydraulic Hybrid Propulsion for Heavy Vehicles: Combining the Simulation and Engine-In-the-Loop Techniques to Maximize the Fuel Economy and Emission Benefits Propulsion hybride hydraulique des poids lourds : une approche alliant les techniques de simulation et d’« Engine-In-the-loop » (EIL afin de maximiser les économies de carburant et les avantages en termes d’émissions

    Directory of Open Access Journals (Sweden)

    Filipi Z.

    2009-09-01

    échauffement climatique fournissent une forte motivation pour le développement de moyens de propulsion véhiculaires économes. Pour les camions, cette tâche est particulièrement difficile à accomplir du fait d’importantes contraintes de taille et de poids. L’hybridation est la seule approche qui puisse déboucher sur des progrès importants à court et moyen termes. En particulier, la configuration “hybride série” découple le moteur thermique des roues et permet une flexibilité complète dans le contrôle des points de fonctionnement moteur. De plus, la conversion et le stockage de l’énergie hydraulique fournissent une densité de puissance et un rendement excellents. Le défi technologique tient à la faible densité d’énergie de l’accumulateur hydraulique, et met en avant l’importance particulière du développement du gestionnaire de l’énergie. Il est communément admis qu’il faut maintenir le moteur au point de rendement maximum mais, si l’objectif ultime en terme énergétique consiste à optimiser drastiquement le rendement du moteur, ceci induit des phases transitoires fréquentes causant pour des moteurs diesels des effets opposés tant sur l’émission de particules que sur l’agrément de conduite. Par conséquent, nous proposons une méthodologie pour le superviseur d’énergie d’un système hybride, qui prend en compte 2 objectifs : la réduction de consommation et la réduction des émissions polluantes. Les économies de carburant sont prises en compte par une approche fondée sur la simulation, alors que l’étude de l’impact des phases transitoires du moteur sur les émissions de particules, est fondée sur un dispositif expérimental combinant modèles temps réel et moteur réel – l’EIL (Engine-In-the-Loop. Le dispositif EIL confirme que le contrôle de la répartition énergétique thermique/hydraulique de l’état de charge des batteries (SOC présente des avantages certains sur celui basé sur l’approche de contr

  1. Irradiation Behaviour of Uranium Carbide Fuels; Comportement des carbures d'uranium sous l’effet de l'irradiation; ПОВЕДЕНИЕ УРАНО-КАРБИДНОГО ТОПЛИВА ПРИ ОБЛУЧЕНИИ; Comportamiento de los combustibles de carburo de uranio frente a la irradiación

    Energy Technology Data Exchange (ETDEWEB)

    Sinizer, D. I.; Webb, B. A.; Berger, S. [Atomics International, Canoga Park, CA (United States)

    1963-08-15

    is a void-free, single-phase microstructure in the decarburized region of the originally hyperstoichiometric fuel. No carbon transfer is observed with hypo- stoichiometric U-C. Carbon removed from hyperstoichiometric (J-C fuel is readily transferred across the Na bond to carburize stainless-steel cladding in both in-pile and out-of-pile experiments. This transfer represents a possible limitation of choice of fuel composition for Na-bonded stainless-steel-clad elements. Nevertheless, available data lead to the present conclusions that stoichiometric or hyperstoichiometric U-C Na-bonded to stainless steel can be effectively used in Na-cooled power reactors. Fission-gas release or fuel swelling do not represent limitations under presently conceived Na-cooled reactor conditions. Alternative cladding materials such as Cb alloys or gas-bonded fuel elements may be required for ultra-high-temperature applications. (author) [French] Des combustibles UC ayant uùe composition quasi stoechiométrique, obtenus par fusion à l’arc électrique et enfermés dans des gaines en acier inoxydable avec lien de sodium ou de NaK, ont été irradiés à des températures au centre allant jusqu'à 1950°F (1065°C) [température moyenne: 1750°F (950°C)] et des taux de combustion allant jusqu'à 25 000 MWj/t d'U, Les combustibles stoechiométriques et légèrement tiyperstoechiométriques accusent une augmentation à peu près linéaire du diamètre pour des taux de combustion allam jusqu'à 25 000 MWj/t d'U. Pour une température au centre moyenne de 1500°F (815°C), l'augmentation de diamètre est inférieure à 3% au-dessus de 25 000 MWj/t d’U; elle est proportionnellement moindre losque la température du combustible s'abaisse. A la température moyenne de 1000°F (540°C), on observe une dilatation qui est à peu près égal à celle que l'on peut prévoir du fait de l'accumulation des produits de fission. La libération des gaz de fission est estimée à moins de 1% au-dessus de

  2. Changing in Fatigue Life of 300 M Bainitic Steel After Laser Carburizing and Plasma Nitriding

    Directory of Open Access Journals (Sweden)

    Abdalla Antonio J.

    2018-01-01

    Full Text Available In this work 300M steel samples is used. This high-strength steel is used in aeronautic and aerospace industry and other structural applications. Initially the 300 M steel sample was submitted to a heat treatment to obtain a bainític structure. It was heated at 850 °C for 30 minutes and after that, cooled at 300 °C for 60 minutes. Afterwards two types of surface treatments have been employed: (a using low-power laser CO2 (125 W for introducing carbon into the surface and (b plasma nitriding at a temperature of 500° C for 3 hours. After surface treatment, the metallographic preparation was carried out and the observations with optical and electronic microscopy have been made. The analysis of the coating showed an increase in the hardness of layer formed on the surface, mainly, among the nitriding layers. The mechanical properties were analyzed using tensile and fatigue tests. The results showed that the mechanical properties in tensile tests were strongly affected by the bainitic microstructure. The steel that received the nitriding surface by plasma treatment showed better fatigue behavior. The results are very promising because the layer formed on steel surface, in addition to improving the fatigue life, still improves protection against corrosion and wear.

  3. Specific dissipated friction power distributions of machined carburized martensitic steel surfaces during running-in

    NARCIS (Netherlands)

    Stickel, D.; Fischer, A.; Bosman, Rob

    2015-01-01

    Due to new design specifications, current tribological systems are subjected to numerous modifications of their operating conditions such as lubrication regime, higher contact pressures, and longer operating times at lower maintenance costs. Thus the mixed lubrication regime might become most

  4. Biodegradability of fuel-ethers in environment; Biodegradabilite des ethers-carburants dans l'environnement

    Energy Technology Data Exchange (ETDEWEB)

    Fayolle-Guichard, F

    2005-04-01

    Fuel ethers (methyl tert-butyl ether or MTBE, ethyl tert-butyl ether or ETBE and tert-amyl methyl ether or TAME have been used as gasoline additives since about twenty years in order to meet the requirements for the octane index and to limit the polluting emission in exhaust pipe gas (unburnt hydrocarbons and carbon monoxide). The high water solubility and the poor biodegradability of these compounds make them pollutants frequently encountered in aquifers. The present manuscript summarizes the knowledge concerning the biodegradability of fuel ethers obtained both at IFP and during collaborations with the Pasteur Institute (Paris), the Biotechnology Research Institute (Montreal, Canada) and the Center for Environmental Biotechnology (University of Tennessee, USA). Rhodococcus ruber IFP 2001 and Mycobacterium austroafricanum IFP 2012, two microorganisms isolated at IFP for their ability to grow, respectively, on ETBE and MTBE, were studied in order to determine the intermediates produced during MTBE and ETBE biodegradation and the enzymes required for each biodegradation step, thus allowing us to propose MTBE and ETBE catabolic pathways. A proteomic approach, from the protein induced during the degradation of ETBE or MTBE to the genes encoding these different enzymes, was carried out. The isolation of such genes is required:1) to use them for help in determining the bio-remediation capacities in polluted aquifers (DNA micro-arrays), 2) to monitor the microorganisms isolated for their degradative capacities during bio-remediation processes (fluorescent in situ hybridization or FISH) and 3) to create new tools for the detection and the quantification of ETBE or MTBE in contaminated aquifers (bio-sensor). The manuscript also describes the different ways for the adaptation of microorganisms to the presence of a xenobiotic compound. (author)

  5. Doping of silicon carbide by ion implantation; Dopage du carbure de silicium par implantation ionique

    Energy Technology Data Exchange (ETDEWEB)

    Gimbert, J

    1999-03-04

    It appeared that in some fields, as the hostile environments (high temperature or irradiation), the silicon compounds showed limitations resulting from the electrical and mechanical properties. Doping of 4H and 6H silicon carbide by ion implantation is studied from a physicochemical and electrical point of view. It is necessary to obtain n-type and p-type material to realize high power and/or high frequency devices, such as MESFETs and Schottky diodes. First, physical and electrical properties of silicon carbide are presented and the interest of developing a process technology on this material is emphasised. Then, physical characteristics of ion implantation and particularly classical dopant implantation, such as nitrogen, for n-type doping, and aluminium and boron, for p-type doping are described. Results with these dopants are presented and analysed. Optimal conditions are extracted from these experiences so as to obtain a good crystal quality and a surface state allowing device fabrication. Electrical conduction is then described in the 4H and 6H-SiC polytypes. Freezing of free carriers and scattering processes are described. Electrical measurements are carried out using Hall effect on Van der Panw test patterns, and 4 point probe method are used to draw the type of the material, free carrier concentrations, resistivity and mobility of the implanted doped layers. These results are commented and compared to the theoretical analysis. The influence of the technological process on electrical conduction is studied in view of fabricating implanted silicon carbide devices. (author)

  6. Poitiers and automotive LPG; Poitiers: la municipalite et le district croient au GPL carburant

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    1999-04-01

    Looking for a reduction in its fuel expenses and a reduction in urban air pollution, Poitiers' local authorities ordered 15 LPG fuelled vehicles some 20 years ago. They ran solely with LPG. Today, some 115 vehicles, including two machines for floor cleaning, one for preparation of skating rings and a forklift, run on LPG. These last machines expected, all vehicles can run on LPG or gasoline. (authors)

  7. Environmental Transmission Electron Microscopy (ETEM) Studies of Single Iron Nanoparticle Carburization in Synthesis Gas

    DEFF Research Database (Denmark)

    Liu, Xi; Zhang, Chenghua; Li, Yongwang

    2017-01-01

    Structuralevolution of iron nanoparticles involving the formationand growth of iron carbide nuclei in the iron nanoparticle was directlyvisualized at the atomic level, using environmental transmission electronmicroscopy (TEM) under reactive conditions mimicking Fischer–Tropschsynthesis. Formation...... and electronenergy-loss spectra provides a detailed picture from initial activationto final degradation of iron under synthesis gas....

  8. Fuels and alternative propulsion in Germany; Les carburants et propulsion alternatifs en Allemagne

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-04-15

    The transportation sector is one of the first responsible of the air pollution in Germany. The kyoto protocol and the european directive led the german Government to set about some measures. To encourage the petroleum industry to develop classical fuels/biofuels mixing, the government exempted from taxes until 2020 the biofuels part. The Government decided also financial incentives for diesel vehicles equipped with particles filters. Among the different fuels, the document presents the advantages and disadvantages of the hydrogen fuels and the hybrid motors. (A.L.B.)

  9. The technologies for heavy vehicles motors and their fuels; Les technologies des moteurs de vehicules lourds et leurs carburants

    Energy Technology Data Exchange (ETDEWEB)

    Plassat, G

    2005-07-01

    The heavy vehicles are those the total weight (charged) is more than 3,5 tons. This document provides a comparative and parametric analysis of the main technologies developed for the future buses. A detailed presentation is done for each technique, as the operating principles and the advantages and disadvantages facing the today solution. More particularly the author presents the evolution of the diesel-fuel motor, the motor optimization for specific fuel as the natural gas and the liquefied petroleum gas, the hybrid thermal-electric motor, the hydrogen fuel cells, the biofuels and the de-pollution systems to eliminate the NO{sub X} and the particles. (A.L.B.)

  10. Fuels production by the thermochemical transformation of the biomass; La production de carburants par transformation thermochimique de la biomasse

    Energy Technology Data Exchange (ETDEWEB)

    Claudet, G. [CEA, 75 - Paris (France)

    2005-07-01

    The biomass is a local and renewable energy source, presenting many advantages. This paper proposes to examine the biomass potential in France, the energy valorization channels (thermochemical chains of thermolysis and gasification) with a special interest for the hydrogen production and the research programs oriented towards the agriculture and the forest. (A.L.B.)

  11. The sustainable development of transports: the motors and the fuels; Le developpement durable des transports: quels moteurs, quels carburants?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This panorama 2005 between politicians, industrialists and scientists discussed the following topics: exploration-production activities and markets, refining and petrochemistry, the future world gas market, the petroleum supply and demand, the new petroleum and gas reserves, the today and tomorrow alternative fuels, the biofuels in the world, the hybrid vehicles future, the energy consumption in the transport sector, the road fuels in europe and the increase of diesel fuel, the de-pollution techniques of industrial vehicles. The slides of the interventions are provided. The sheets ''le point sur'' of the year 2005 are also provided. (A.L.B.)

  12. Kinetics of niobium carbide precipitation in ferrite; Cinetiques de precipitation du carbure de niobium dans la ferrite

    Energy Technology Data Exchange (ETDEWEB)

    Gendt, D

    2001-07-01

    The aim of this study is to develop a NbC precipitation modelling in ferrite. This theoretical study is motivated by the fact it considers a ternary system and focus on the concurrence of two different diffusion mechanisms. An experimental study with TEP, SANS and Vickers micro-hardening measurements allows a description of the NbC precipitation kinetics. The mean radius of the precipitates is characterized by TEM observations. To focus on the nucleation stage, we use the Tomographic Atom Probe that analyses, at an atomistic scale, the position of the solute atoms in the matrix. A first model based on the classical nucleation theory and the diffusion-limited growth describes the precipitation of spherical precipitates. To solve the set of equations, we use a numerical algorithm that furnishes an evaluation of the precipitated fraction, the mean radius and the whole size distribution of the particles. The parameters that are the interface energy, the solubility product and the diffusion coefficients are fitted with the data available in the literature and our experimental results. It allows a satisfactory agreement as regards to the simplicity of the model. Monte Carlo simulations are used to describe the evolution of a ternary alloy Fe-Nb-C on a cubic centred rigid lattice with vacancy and interstitial mechanisms. This is realized with an atomistic description of the atoms jumps and their related frequencies. The model parameters are fitted with phase diagrams and diffusion coefficients. For the sake of simplicity, we consider that the precipitation of NbC is totally coherent and we neglect any elastic strain effect. We can observe different kinetic paths: for low supersaturations, we find an expected precipitation of NbC but for higher supersaturations, the very fast diffusivity of carbon atoms conducts to the nucleation of iron carbide particles. We establish that the occurrence of this second phenomenon depends on the vacancy arrival kinetics and can be related to the microstructure of the steel. (author)

  13. Biodegradability of fuel-ethers in environment; Biodegradabilite des ethers-carburants dans l'environnement

    Energy Technology Data Exchange (ETDEWEB)

    Fayolle-Guichard, F.

    2005-04-01

    Fuel ethers (methyl tert-butyl ether or MTBE, ethyl tert-butyl ether or ETBE and tert-amyl methyl ether or TAME have been used as gasoline additives since about twenty years in order to meet the requirements for the octane index and to limit the polluting emission in exhaust pipe gas (unburnt hydrocarbons and carbon monoxide). The high water solubility and the poor biodegradability of these compounds make them pollutants frequently encountered in aquifers. The present manuscript summarizes the knowledge concerning the biodegradability of fuel ethers obtained both at IFP and during collaborations with the Pasteur Institute (Paris), the Biotechnology Research Institute (Montreal, Canada) and the Center for Environmental Biotechnology (University of Tennessee, USA). Rhodococcus ruber IFP 2001 and Mycobacterium austroafricanum IFP 2012, two microorganisms isolated at IFP for their ability to grow, respectively, on ETBE and MTBE, were studied in order to determine the intermediates produced during MTBE and ETBE biodegradation and the enzymes required for each biodegradation step, thus allowing us to propose MTBE and ETBE catabolic pathways. A proteomic approach, from the protein induced during the degradation of ETBE or MTBE to the genes encoding these different enzymes, was carried out. The isolation of such genes is required:1) to use them for help in determining the bio-remediation capacities in polluted aquifers (DNA micro-arrays), 2) to monitor the microorganisms isolated for their degradative capacities during bio-remediation processes (fluorescent in situ hybridization or FISH) and 3) to create new tools for the detection and the quantification of ETBE or MTBE in contaminated aquifers (bio-sensor). The manuscript also describes the different ways for the adaptation of microorganisms to the presence of a xenobiotic compound. (author)

  14. Lattice dynamics of {alpha} boron and of boron carbide; Proprietes vibrationnelles du bore {alpha} et du carbure de bore

    Energy Technology Data Exchange (ETDEWEB)

    Vast, N

    1999-07-01

    The atomic structure and the lattice dynamics of {alpha} boron and of B{sub 4}C boron carbide have been studied by Density Functional Theory (D.F.T.) and Density Functional Perturbation Theory (D.F.P.T.). The bulk moduli of the unit-cell and of the icosahedron have been investigated, and the equation of state at zero temperature has been determined. In {alpha} boron, Raman diffusion and infrared absorption have been studied under pressure, and the theoretical and experimental Grueneisen coefficients have been compared. In boron carbide, inspection of the theoretical and experimental vibrational spectra has led to the determination of the atomic structure of B{sub 4}C. Finally, the effects of isotopic disorder have been modeled by an exact method beyond the mean-field approximation, and the effects onto the Raman lines has been investigated. The method has been applied to isotopic alloys of diamond and germanium. (author)

  15. Automotive fuels distribution on highways: 2007 statistical inquiry; La distribution de carburants sur autoroutes: enquete statistique 2007

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    The general direction of energy and raw materials (DGEMP) is in charge of the follow up of the French market of petroleum products distribution. Each year, a statistical inquiry is carried out with the suppliers and published in the annual report of the petroleum industry. A particular emphasis is laid on fuel sales at highway service stations which give some additional information. The 2007 sales remain stable with respect to 2006 but they show a significant progress of diesel with respect to gasoline. The super-ethanol (E85) sales remain modest but show an import rise all along the year. And finally, 70% of the market is in the hands of 3 suppliers only. (J.S.)

  16. Irradiation Effects in Fissile Oxides and Carbides at Low and High Burn-Up Levels; Effets de l'irradiation sur les oxydes et carbures fissiles a des taux de combustion faibles et élevés; ВЛИЯНИЕ ОБЛУЧЕНИЯ НА РАСЩЕПЛЯЩИЕСЯ ОКСИДЫ И КАРБИДЫ ПРИ НИЗКИХ И ВЫСОКИХ УРОВНЯХ ВЫГОРАНИЯ; Efectos de la irradiación sobre los óxidos y carburos fisionables para grados de combustion bajos y elevados

    Energy Technology Data Exchange (ETDEWEB)

    Frost, B. R.T.; Bradbury, B. T.; Griffiths, L. B. [Metallurgy Division, Atomic Energy Research Establishment, Harwell, Berks. (United Kingdom)

    1963-08-15

    des taux de combustion de l'ordre de 15 000 à 54 000 MWj/t, les températures centrales étant de l'ordre de 900 à 1600°C pour l'oxyde et d'environ 800°C pour le carbure. Après l'irradiation on a analysé le gaz produit par la fission, mesuré les modifications dimensionnelles et étudié les modifications structurelles au microscope optique et au microscope électronique. (author) [Spanish] Aplicando técnicas de microscopía óptica y electrónica, loe autores estudiaion las alteraciones estructurales que la irradiation provoca en el UO{sub 2} y el UC, en correspondencia con grados de combustion comprendidos entre 100 y 10 000 MWd/t(e). En particular, observaron cómo cambia el modo de fractura de transgranular a intergranular y cómo disminuye la resistencia a la flexión al aumentar la dosis de radiación. También estudiaron los daflos causados por la radiación en el UC, midiendo la variación de la resistividad eléctrica en función de la dosis, en el material frío irradiado y aplicaron ulteriormente la misma técnica para estudiar las temperaturas de recocido y el mecanismo y la cinética del recocido. Irradiaron una serie de bolillas de UO{sub 2}, una solución sólida de UO{sub 2}-PuO{sub 2} y una solución sólida de UC y de PuC-UC, en recipientes de acero inoxidable, hasta alcanzar grados de combustión del orden de 15 000 a 54 000 MWd/t(e), manteniendo las temperaturas centrales del óxido entre los 900 y 1600°C y las del carburo en los 800°C, aproximadamente. Los exámenes posteriores a la irradiación comprendieron el análisis de los gases de fisión, la medición de los cambios dimensionales y el estudio de las alteraciones estructurales por microscopía óptica y electrónica. (author) [Russian] Структурные изменения, возникающие в U02 и UC в течение облучения при выгораниях между 100 и 10 ООО мгвт-дней/т были изучены с применением

  17. Un carburant spécifique pour les engins agricoles : étude de quatre filières de production de biocarburants agricoles

    OpenAIRE

    Vaitilingom , G.; Agier , Y.; Lacour , S.

    2012-01-01

    The fuel has become essential to agriculture: it represents 30% of the hourly cost of a tractor and raises the problem of modern agriculture, entirely dependent on oil supplies and too sensitive to fuel market price. With the planned reduction of oil resources, this paper gives technical, economical and environmental issues for the choice of a specific agricultural fuel for tractors. Four options are presented dealing with 2 liquid fuels, pure vegetable oil and ethanol, 2 gaseous fuels: synga...

  18. Fuel and Electrical Systems Mechanic. Apprenticeship Training Standards = Mecanicien de systemes d'alimentation en carburant et electriques. Normes de formation en apprentissage.

    Science.gov (United States)

    Ontario Ministry of Skills Development, Toronto.

    These training standards for fuel and electrical systems mechanics are intended to be used by apprentice/trainees, instructors, and companies in Ontario, Canada, as a blueprint for training or as a prerequisite for prerequisite for accreditation/certification. The training standards identify skills required for this occupation and its related…

  19. Motor fuel demand analysis - applied modelling in the European union; Modelisation de la demande de carburant appliquee a l`europe

    Energy Technology Data Exchange (ETDEWEB)

    Chorazewiez, S

    1998-01-19

    Motor fuel demand in Europe amounts to almost half of petroleum products consumption and to thirty percent of total final energy consumption. This study considers, Firstly, the energy policies of different European countries and the ways in which the consumption of motor gasoline and automotive gas oil has developed. Secondly it provides an abstract of demand models in the energy sector, illustrating their specific characteristics. Then it proposes an economic model of automotive fuel consumption, showing motor gasoline and automotive gas oil separately over a period of thirty years (1960-1993) for five main countries in the European Union. Finally, forecasts of consumption of gasoline and diesel up to the year 2020 are given for different scenarios. (author) 330 refs.

  20. Fuel consumption and CO{sub 2} emissions (Car Labelling); Consommations de carburant et emissions de CO{sub 2} (Car Labelling)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-03-01

    CO{sub 2} is the most important greenhouse gas produced by internal combustion engines. In the framework of the Kyoto protocol, actions have been implemented in the transportation sector for the abatement of vehicles fuel consumption and pollutant emissions. This study presents the 'honors list' established by the French agency of environment and energy mastery (Ademe) of the fuel consumption and CO{sub 2} emissions of gasoline, diesel, LPG, NGV, and hybrid electric-powered vehicles. Results are presented in tables per company and model. These data are compiled and summarized in a last part which presents the key data about the evolution of the French automotive market, the emissions and consumptions of vehicles and the technological evolution of the vehicles and its influence on the fuel consumption. (J.S.)

  1. Contribution to the study of the hydrolysis of uranium carbides (1963); Contribution a l'etude de l'hydrolyse des carbures d'uranium (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Spitz, J [Commisariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1963-06-15

    The hydrolysis of uranium monocarbide in neutral or acid medium leads to the formation of a complex mixture of hydrogen and hydrocarbons mostly saturated. When UC-U alloys are dissolved in hydrochloric-phosphoric medium, the free uranium contents can be determined with good accuracy from the composition of the gaseous phase. The hydrolysis of mixtures of uranium mono - and dicarbide in neutral or acid medium, leads to the formation of a complex mixture of hydrogen and gaseous and condensed hydrocarbons, the composition of which is principally dependent upon the UC{sub 2} content. The reaction mechanisms which are presented in this paper for the hydrolysis of UC and UC{sub 2} provide account for all experimental observations. (author) [French] L'hydrolyse en milieu neutre ou acide du monocarbure d'uranium conduit a la formation d'un melange complexe d'hydrogene et d'hydrocarbures, satures en grande majorite. L'attaque en milieu chlorhydrique-phosphorique des alliages UC-U permet la determination avec une bonne precision, des teneurs en uranium libre a partir de la composition des gaz degages. L'hydrolyse en milieu neutre ou acide des melanges de mono - et dicarbure d'uranium conduit a la formation d'un melange complexe d'hydrogene et d'hydrocarbures gazeux et condenses, dont la composition est essentiellement fonction de la teneur en UC{sub 2}. Les mecanismes reactionnels proposes pour l'hydrolyse de UC et UC{sub 2} rendent compte de tous les faits experimentaux observes. (auteur)

  2. The automobile of the future: engine technologies and automotive fuels developed by IFP; l'automobile du futur: les technologies moteurs et carburants developpes par l'IFP

    Energy Technology Data Exchange (ETDEWEB)

    Appert, O; Pinchon, Ph

    2004-07-01

    In front of the challenges of climate change and depletion of petroleum reserves, in front of the continuous strengthening of pollution regulations applied to automobile (Euro IV and V) and the advances of R and D, several ways of research can be explored to answer the mobility needs of the coming decades. The IFP takes stock of these topics in this press kit which comprises 11 documents: the synthesis of O. Appert and P. Pinchon's talk about 'the cleaner and multi-energies automobile of the future', the slides of this presentation, the future evolutions of automobiles motorizations, the long-term evolutions of engines/fuels (brief for the Panorama 2004 colloquium), diesel fuel in the USA (brief for the Panorama 2004 colloquium), bio-fuels in Europe (brief for the Panorama 2004 colloquium), diesel pollution abatement: efficient results from the IFP's diesel combustion process 'NADI'(TM), the presentation of the IFP scientific meeting of September 22-23, 2004 'which fuels for low CO{sub 2} engines?', the strategic positioning of IFP in the world energy and environmental context, the brochures 'IFP engines and fuels: a competitive advantage' and 'innovating for a sustainable development in the domain of energy'. (J.S.)

  3. Heterogeneous precipitation of niobium carbide in the ferrite by Monte Carlo simulations; Cinetique de precipitation heterogene du carbure de niobium dans la ferrite

    Energy Technology Data Exchange (ETDEWEB)

    Hin, C

    2005-12-15

    The precipitation of niobium carbides in industrial steels is commonly used to control the recrystallization process or the amount of interstitial atoms in solid solution. It is then important to understand the precipitation kinetics and especially the competition between homogeneous and heterogeneous precipitation, since both of them have been observed experimentally, depending on they alloy composition, microstructure and thermal treatments. We propose Monte Carlo simulations of NbC precipitation in {open_square}-iron, based on a simple atomic description of the main parameters which control the kinetic pathway: - Realistic diffusion properties, with a rapid diffusion of C atoms by interstitial jumps and a slower diffusion of Fe and Nb atoms by vacancy jumps; - A model of grain boundaries which reproduces the segregation properties of Nb and C; - A model of dislocation which interacts with solute atoms through local segregation energies and long range elastic field; - A point defect source which drives the vacancy concentration towards its equilibrium value. Depending on the precipitation conditions, Monte Carlo simulations predict different kinetic behaviors, including a transient precipitation of metastable carbides, an early segregation stage of C, wetting phenomena at grain boundaries and on dislocations and a competition between homogeneous and heterogeneous NbC precipitation. Concerning the last point, we highlight that long range elastic field due to dislocation favors clearly the heterogeneous precipitation on dislocations. To understand this effect, we have developed a heterogeneous nucleation model including the calculation of the local concentration of solute atoms around the dislocation, the change of the solubility limit relative to the solubility limit in bulk and the energy of precipitates in an elastic field. We have concluded that elastic field favors the heterogeneous precipitation through the fall in nucleation barrier. (author)

  4. Fuel consumption: short term and long term price impacts per population type; Consommation de carburant: effets des prix a court et a long termes par type de population

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    This report presents assessments of the price sensitivity of household fuel consumption. After a literature review on price-elasticity assessments and the use of pseudo-panels, the investigation analyses the deciding factors of the household fuel expense and its evolution between 1985 and 2006. It proposes a short term price-elasticity assessment based on the most recent survey, and also proposes price-elasticity assessments for sub-populations, notably in terms of income level or location (rural or urban areas)

  5. Fuel consumption of private cars in France 1988-2006; Consommations de carburants des voitures particulieres en France 1988-2006

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-12-15

    The results of this study come from the exploitation of the 'TNSworldpanel Petrol' inquiry launched in April 1987. This panel follows the consumption of 3300 cars belonging to individuals living in France (company vehicles are excluded). This is the only operation of this scale ever carried out in France. The main results indicate: the continuation of the average consumption decay of individual cars (all kind of fuel considered); a new and significant progress of diesel-fueled vehicles: 57% of the cars purchased by households (50% in 2003, 33% in 1995); a new decay of the total distance covered by households: -1.1% in parallel to the rise of fuel prices. (J.S.)

  6. Study of boron carbide evolution under neutron irradiation; Contribution a l'etude de l'evolution du carbure de bore sous irradiation neutronique

    Energy Technology Data Exchange (ETDEWEB)

    Simeone, D. [CEA/Saclay, Dept. de Mecanique et de Technologie (DMT), 91 - Gif-sur-Yvette (France)]|[Universite Blaise Pascal, Clermont-Ferrand II, (CNRS), 63 - Aubiere (France)

    1999-07-01

    Owing to its high neutron efficiency, boron carbide (B{sub 4}C) is used as a neutron absorber in control rods of nuclear plants. Its behaviour under irradiation has been extensively studied for many years. It now seems clear that brittleness of the material induced by the {sup 10}B(n,{alpha}){sup 7}Li capture reaction is due to penny shaped helium bubbles associated to a high strain field around them. However, no model explains the behaviour of the material under neutron irradiation. In order to build such a model, this work uses different techniques: nuclear microprobe X-ray diffraction profile analysis and Raman and Nuclear Magnetic Resonance Spectroscopy to present an evolution model of B{sub 4}C under neutron irradiation. The use of nuclear reactions produced by a nuclear microprobe such as the {sup 7}Li(p,p'{gamma}){sup 7}Li reaction, allows to measure lithium profile in B{sub 4}C pellets irradiated either in Pressurised Water Reactors or in Fast Breeder Reactors. Examining such profiles enables us to describe the migration of lithium atoms out of B{sub 4}C materials under neutron irradiation. The analysis of X-ray diffraction profiles of irradiated B{sub 4}C samples allows us to quantify the concentrations of helium bubbles as well as the strain fields around such bubbles.Furthermore Raman spectroscopy studies of different B{sub 4}C samples lead us to propose that under neutron irradiation. the CBC linear chain disappears. Such a vanishing of this CBC chain. validated by NMR analysis, may explain the penny shaped of helium bubbles inside irradiated B{sub 4}C. (author)

  7. Resolution 49/013. Is adequate the quality control of liquid fuels Regulation, approved by Resolution of the URSEA 150/2008

    International Nuclear Information System (INIS)

    2013-01-01

    This Resolution is about the need to adapt the quality control regulation of liquid carburant approved by Resolution of the URSEA N. 150/2008. ANCAP has informed to URSEA the incorporation and reformularization of alcohol carburant in the gasoline

  8. Opening talk given by M. Dominique Maillard at the professional colloquium of the French federation of fuels; Discours d'ouverture prononce par M. Dominique Maillard au colloque professionnel de la Federation francaise des combustibles et des carburants

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This talk, given by D. Maillard, general director of energy and raw materials, presents first the 2004 world situation of petroleum products in terms of prices and production capacity and the role played by investment funds in this situation. Then, he proposes some short-term actions to be implemented: encouraging investment efforts in exploration-production, preservation of strategic stocks, influencing the consumers behaviour in order to reduce the demand, assigning exceptional financial helps to professionals whose activity is threatened by the rise of petroleum products price. In the last part of his talk, D. Maillard wants to reassure the petroleum products retailers about the evolutions of their profession in this context of prices inflation. The government will harmonize the tax discrepancies between natural gas and gas oil and will ensure the equilibrium between the different forms of trade in the petroleum products sector in order to maintain a sound competition between the small and big retailers. (J.S.)

  9. Elaboration par différents procédés de pulvérisation et caractérisation de mono et multi-couches minces de carbure de bore et de carbonitrure de bore

    OpenAIRE

    Tavsanoglu , Tolga

    2009-01-01

    Thèse en cotutelle avec L'Institute of Science and Technology, Istanbul Teknik Universitesi (Turquie); Over the last 30 years there has been a great deal of interest in the research of hard and wear resistant coatings. There exist ceramic thin films for industrial applications such as cutting tools, automobile and machine part including TiN, TiAlN, TiC, SiC, WC as examples. However, increasing technological and industrial demands request thin films with more advanced properties. For this purp...

  10. Theoretical study of silicon carbide under irradiation at the nano scale: classical and ab initio modelling; Etude theorique a l'echelle nanometrique du carbure de silicium sous irradiation: modelisation classique et ab initio

    Energy Technology Data Exchange (ETDEWEB)

    Lucas, G

    2006-10-15

    The behaviour of silicon carbide under irradiation has been studied using classical and ab initio simulations, focusing on the nano scale elementary processes. First, we have been interested in the calculation of threshold displacement energies, which are difficult to determine both experimentally and theoretically, and also the associated Frenkel pairs. In the framework of this thesis, we have carried out simulations in classical and ab initio molecular dynamics. For the classical approach, two types of potentials have been used: the Tersoff potential, which led to non satisfactory results, and a new one which has been developed during this thesis. This potential allows a better modelling of SiC under irradiation than most of the empirical potentials available for SiC. It is based on the EDIP potential, initially developed to describe defects in silicon, that we have generalized to SiC. For the ab initio approach, the feasibility of the calculations has been validated and average energies of 19 eV for the C and 38 eV for the Si sublattices have been determined, close to the values empirically used in the fusion community. The results obtained with the new potential EDIP are globally in agreement with those values. Finally, the elementary processes involved in the crystal recovery have been studied by calculating the stability of the created Frenkel pairs and determining possible recombination mechanisms with the nudged elastic band method. (author)

  11. Development of nano-structured silicon carbide ceramics: from synthesis of the powder to sintered ceramics; Elaboration de ceramiques nanostructurees en carbure de silicium: de la synthese de la poudre a la ceramique frittee

    Energy Technology Data Exchange (ETDEWEB)

    Reau, A.

    2008-12-15

    The materials used inside future nuclear reactors will be subjected to very high temperature and neutrons flux. Silicon carbide, in the form of SiC{sub f}/SiC nano-structured composite is potentially interesting for this type of application. It is again necessary to verify the contribution of nano-structure on the behaviour of this material under irradiation. To verify the feasibility and determine the properties of the matrix, it was envisaged to produce it by powder metallurgy from SiC nanoparticles. The objective is to obtain a fully dense nano-structured SiC ceramic without additives. For that, a parametric study of the phases of synthesis and agglomeration was carried out, the objective of which is to determine the active mechanisms and the influence of the key parameters. Thus, studying the nano-powder synthesis by laser pyrolysis allowed to produce, with high production rates, homogeneous batches of SiC nanoparticles whose size can be adjusted between 15 and 90 nm. These powders have been densified by an innovating method: Spark Plasma Sintering (SPS). The study and the optimization of the key parameters allowed the densification of silicon carbide ceramic without sintering aids while preserving the nano-structure of material. The thermal and mechanical properties of final materials were studied in order to determine the influence of the microstructure on their properties. (author)

  12. To break away from fossil fuels : a contribution to solve climatic change and energy security for Quebec; S'affranchir des carburants fossiles : une contribution a la lutte aux changements climatiques et a la securite energetique du Quebec

    Energy Technology Data Exchange (ETDEWEB)

    Bonin, P.; Seguin, H.; Waridel, L.

    2006-06-15

    In response to growing energy demands, Quebec has proposed the construction of 3 deep water terminals to accommodate methane tankers which transport liquefied natural gas (LNG). This paper focused on the proposed Gros Cacouna Port project in the St. Lawrence Seaway which is currently under study and subject to approval. Equiterre, questioned the energy security aspect of the proposal and argued that increasing Quebec's reliance on increasingly expensive energy would decrease energy security. In addition, importation of LNG would bring a clear exit of capital outside the province. Equiterre also argued that reliance on fossil fuels should be decreased in order to mitigate greenhouse gas emissions which contribute to climate change. The organization questioned whether the economic and social need for the proposed project justifies a greater dependency on fossil fuels and the associated impact on the environment and fragile ecosystems of the St. Lawrence. It was suggested that alternative solutions such as renewable energy sources and energy efficiency should be explored in order to promote sustainable development, increase energy security and reduce greenhouse gases. Equiterre argued that Quebec can and must decrease, and even eliminate, its dependence on fossil fuels, including natural gas, for Quebec's economic, social and environmental well-being. For these reasons, Equiterre recommended that the proposed project be rejected, particularly since the project proponents failed to show the real impact that the project would have on Quebec markets. 72 refs., 10 tabs., 21 figs.

  13. Elaboration of silicon carbides nano particles (SiC): from the powder synthesis to the sintered ceramic; Elaboration de ceramiques nanostructurees en carbure de silicium (SiC): de la synthese de poudre a la ceramique frittee

    Energy Technology Data Exchange (ETDEWEB)

    Reau, A. [CEA Saclay, Dept. des Materiaux pour le Nucleaire (DEN/DANS/DMN/SRMA), 91 - Gif-sur-Yvette (France)

    2008-07-01

    Materials for the reactor cores of the fourth generation will need materials supporting high temperatures with fast neutrons flux. SiC{sub f}/SiC ceramics are proposed. One of the possible elaboration process is to fill SiC fiber piece with nano particles SiC powder and to strengthen by sintering. The aim of this thesis is to obtain a nano structured SiC ceramic as a reference for the SiC{sub f}/SiC composite development and to study the influence of the fabrication parameters. (A.L.B.)

  14. Irradiation effects and diffusion of fission products (cesium and iodine) in silicon carbide; Effets d'irradiation et diffusion des produits de fission (cesium et iode) dans le carbure de silicium

    Energy Technology Data Exchange (ETDEWEB)

    Audren, A

    2007-03-15

    Silicon carbide is envisaged as a cladding material for the nuclear fuel in the fourth generation reactors. The aim of this work is to study the capacity to retain fission products and the structure evolution of this material under the combined effects of temperature and irradiation. The low energy ion implantations and the incorporation of stable analogues of fission products (Cs and I) in single crystalline 6H-SiC samples were performed by using the ion implanter or the accelerator of the CSNSM. The high energy heavy ion irradiations were made at GANIL. The evolution of the implanted ion profiles and the crystal structure were studied by RBS and Channeling. Complementary information were obtained by using the UV-visible absorption spectroscopy. The low energy ion implantations at room temperature induce a fast structural damage in the crystal. On the other hand, it is possible to attain a small disorder rate in the crystal during implantation by increasing the implantation temperature (600 C). The high energy heavy ion irradiations do not damage the SiC crystals. On the contrary, they cause an annealing of the disorder created by the low energy implantations. The implanted ions (I) do not diffuse during low or high energy ion irradiations at room temperature and at 600 C. However, a diffusion of Cs ions was observed during a post-implantation annealing at 1300 C. At this temperature, the crystal which had an extended amorphous layer starts to recover a single-crystal structure. (author)

  15. Development of lean burn gas engines using pilot fuel for ignition source; Developpement d'un moteur a gaz avec pre-injection de carburant pour la source d'allumage

    Energy Technology Data Exchange (ETDEWEB)

    Sakonji, T.; Saito, H.; Sakurai, T. [Tokyo Gas Co., Ltd. (Japan); Hirashima, T.; Kanno, K. [Nissan Diesel Motor Co., Ltd. (Japan)

    2000-07-01

    A development was conducted to investigate the performance of an open chamber gas engine with pilot fuel for ignition source. Experiments were conducted by using a gas engine equipped with a common-rail injection system. Main gas fuel is supplied to the engine cylinder, and then a small quantity of diesel fuel (approximately 1 % of total fuel energy input) was injected into the main chamber for ignition. The single cylinder prototype gas engine has demonstrated superior performance, such as, a shaft-end thermal efficiency of 36.7% with NO{sub x} level of 0.4 g/kW-h, which equals those of conventional spark ignited pre-chamber lean burn gas engines. For the next step, the multi-cylinder gas engine has been developed. That has 138 mm bore, 142 mm stroke, V8 configuration and 229 kW engine output 1500 rpm. This engine can also run with only diesel fuel for Standby-Power-Concurrent Co-generation. (authors)

  16. Dispersants in an organic medium: synthesis and physicochemical study of dispersants for fuels and lubricants; Dispersants en milieu organique: synthese et etude physicochimique de dispersants pour carburants et lubrifiants

    Energy Technology Data Exchange (ETDEWEB)

    Dubois-Clochard, M.C.

    1998-11-19

    Carbonaceous deposits coming from the fuel and the lubricant are known to form over time at critical locations in an engine. In general, the deposits have an adverse effect on four functional areas which are the fuel metering system, the intake system, the lubrication system and the combustion chambers. These deposits can degrade vehicle performance and drive-ability, reduce fuel economy, increase fuel consumption and pollutant emissions and may lead to the destruction of the engine. In order to remedy these problems, detergent-dispersant additives are used in fuels and lubricants to avoid or decrease deposit adhesion on metallic surfaces and prevent from deposit aggregation. These products are mainly polymer surfactants and in this work, poly-iso-butenyl-succinimide of different structures have been studied. Firstly, 'comb like' polymers have been synthesized. Then they have been compared to classical di-bloc additives in terms of performance and action mechanism. These additives are adsorbed from their hydrophilic polyamine part on the acidic functions of the carbon black surface chosen as an engine deposit model and on the aluminium oxide function of an aluminium powder chosen as an engine wall model. The adsorption increases with temperature on the two solids. Their affinity with the solid surface increases with the length of the hydrophilic part. In the same way, changing the di-bloc structure for a comb like one lead to a better adsorption. At low concentration, it has been shown that the adsorption phenomenon was irreversible, due to the polymer structure of the polar part. Depending on the space required by the hydrophilic part on the solid surface, a more of less dense monolayer is formed. At higher concentrations, an important increase of the adsorbed amount appears. This phenomenon is totally reversible showing that the interactions additive / additive are weak. The dispersing efficiency of a comb like structure is better than a di-bloc one as the hydrophilic parts are forced to huddle together, decreasing the solid surface required and enhancing the stretching of hydrophobic parts. (author) 136 refs.

  17. Densification of silicon and zirconium carbides by a new process: spark plasma sintering; Densification des carbures de silicium et de zirconium par un procede innovant: le spark plasma sintering

    Energy Technology Data Exchange (ETDEWEB)

    Guillard, F

    2006-12-15

    Materials research for suitable utilization in 4. generation nuclear plants needs new ways to densify testing components. Two carbides, silicon and zirconium carbide seems to be the most suitable choice due to their mechanical, thermal and neutron-transparency properties against next nuclear plant specifications. Nevertheless one main difficulty remains, which is densifying them even at high temperature. Spark Plasma Sintering a new metal-, ceramic- and composite-sintering process has been used to densify both SiC and ZrC. Understanding bases of mass transport mechanisms in SPS have been studied. Composites and interfaces have been processed and analyzed. This manuscript reports original results on SiC and ZrC ceramics sintered with commercial powder started, without additives. (author)

  18. The automobile of the future: engine technologies and automotive fuels developed by IFP; l'automobile du futur: les technologies moteurs et carburants developpes par l'IFP

    Energy Technology Data Exchange (ETDEWEB)

    Appert, O.; Pinchon, Ph.

    2004-07-01

    In front of the challenges of climate change and depletion of petroleum reserves, in front of the continuous strengthening of pollution regulations applied to automobile (Euro IV and V) and the advances of R and D, several ways of research can be explored to answer the mobility needs of the coming decades. The IFP takes stock of these topics in this press kit which comprises 11 documents: the synthesis of O. Appert and P. Pinchon's talk about 'the cleaner and multi-energies automobile of the future', the slides of this presentation, the future evolutions of automobiles motorizations, the long-term evolutions of engines/fuels (brief for the Panorama 2004 colloquium), diesel fuel in the USA (brief for the Panorama 2004 colloquium), bio-fuels in Europe (brief for the Panorama 2004 colloquium), diesel pollution abatement: efficient results from the IFP's diesel combustion process 'NADI'(TM), the presentation of the IFP scientific meeting of September 22-23, 2004 'which fuels for low CO{sub 2} engines?', the strategic positioning of IFP in the world energy and environmental context, the brochures 'IFP engines and fuels: a competitive advantage' and 'innovating for a sustainable development in the domain of energy'. (J.S.)

  19. Investigations of carbon diffusion and carbide formation in nickel-based alloys

    International Nuclear Information System (INIS)

    Schulten, R.; Bongartz, K.; Quadakkers, W.J.; Schuster, H.; Nickel, H.

    1989-11-01

    The present thesis describes the carburization behaviour of nickel based alloys in heavily carburizing environments. The mechanisms of carbon diffusion and carbide precipitation in NiCr alloys with and without ternary additions of iron, cobalt or molybdenum have been investigated. Using the results of carburization experiments, a mathematical model which describes carbon diffusion and carbide formation, was developed. The simulation of the carburization process was carried out by an iterative calculation of the local thermodynamic equilibrium in the alloy. An accurate description of the carbon profiles as a function of time became possible by using a finite-difference calculation. (orig.) [de

  20. HIGH-TEMPERATURE VACUUM CEMENTATION – THE RESERVE TO REDUCE THE ENERGY INTENSITY OF MANUFACTURE AND IMPROVE THE QUALITY OF TRANSMISSIONS GEARWHEELS OF HIGH-ENERGY MACHINES

    OpenAIRE

    A. A. Shipko; S. P. Rudenko; A. L. Valko; A. N. Chichin

    2016-01-01

    Results of research of influence of high-temperature vacuum chemical heat treatment on the amount of grain structural steels are presented. The efficiency of hereditary fine-grained steel for high temperature vacuum carburizing are shown.

  1. HIGH-TEMPERATURE VACUUM CEMENTATION – THE RESERVE TO REDUCE THE ENERGY INTENSITY OF MANUFACTURE AND IMPROVE THE QUALITY OF TRANSMISSIONS GEARWHEELS OF HIGH-ENERGY MACHINES

    Directory of Open Access Journals (Sweden)

    A. A. Shipko

    2016-01-01

    Full Text Available Results of research of influence of high-temperature vacuum chemical heat treatment on the amount of grain structural steels are presented. The efficiency of hereditary fine-grained steel for high temperature vacuum carburizing are shown.

  2. Chemical compatibility between cladding alloys and advanced fuels

    International Nuclear Information System (INIS)

    Fee, D.C.; Johnson, C.E.

    1975-05-01

    The National Advanced Fuels Program requires chemical, mechanical, and thermophysical properties data for cladding alloys. The compatibility behavior of cladding alloys with advanced fuels is critically reviewed. in carbide fuel pins, the principal compatibility problem is cladding carburization, diffusion of carbon into the cladding matrix accompanied by carbide precipitation. Carburization changes the mechanical properties of the cladding alloy. The extent of carburization increases in sodium (versus gas) bonded fuels. The depth of carburization increases with increasing sesquicarbide (M 2 C 3 ) content of the fuel. In nitride fuel pins, the principal compatibility problem is cladding nitriding, diffusion of nitrogen into the cladding matrix accompanied by nitride precipitation. Nitriding changes the mechanical properties of the cladding alloy. In both carbide and nitride fuel pins, fission products do not migrate appreciably to the cladding and do not appear to contribute to cladding attack. 77 references. (U.S.)

  3. Effects of WC Particle Size and Co Content on the Graded Structure in Functionally Gradient WC-Co Composites

    Directory of Open Access Journals (Sweden)

    Yuan Yigao

    2016-01-01

    Full Text Available Functionally gradient WC-Co composites having a Co depleted surface zone and not comprising the h phase can be manufactured via carburizing process. During carburizing, besides carburizing process parameters, the microstructural parameters of WC-Co materials, such as WC grain size and Co content, also have significant influences on the formation of Co gradient structure. In this study, the effects of WC particle size and Co content on the gradient structure within gradient hardmetals have been studied, based on a series of carburizing experiments of WC-Co materials with different WC particle sizes and cobalt contents. The results show that both the thickness and the amplitude of the gradients within gradient WC-Co materials increase with increasing initial WC particle size and Co content of WC-Co alloys. The reason for this finding is discussed.

  4. Influence of Heat Treatment on Mercury Cavitation Resistance of Surface Hardened 316LN Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Pawel, Steven J [ORNL; Hsu, Julia [Massachusetts Institute of Technology (MIT)

    2010-11-01

    The cavitation-erosion resistance of carburized 316LN stainless steel was significantly degraded but not destroyed by heat treatment in the temperature range 500-800 C. The heat treatments caused rejection of some carbon from the carburized layer into an amorphous film that formed on each specimen surface. Further, the heat treatments encouraged carbide precipitation and reduced hardness within the carburized layer, but the overall change did not reduce surface hardness fully to the level of untreated material. Heat treatments as short as 10 min at 650 C substantially reduced cavitation-erosion resistance in mercury, while heat treatments at 500 and 800 C were found to be somewhat less detrimental. Overall, the results suggest that modest thermal excursions perhaps the result of a weld made at some distance to the carburized material or a brief stress relief treatment will not render the hardened layer completely ineffective but should be avoided to the greatest extent possible.

  5. Nickel-silver composition shows promise as catalyst for hydrogen-oxygen fuel cells

    Science.gov (United States)

    Magerl, J. A.; Murray, J. N.

    1970-01-01

    Carburized 3-1 nickel-silver preparation exhibits considerable catalytic activity, although not as high as platinum black. Cost and availability factors warrant further evaluation of nickel-silver materials.

  6. Determination of Concentration Dependent Diffusion Coefficients of Carbon in Expanded Austenite

    DEFF Research Database (Denmark)

    Hummelshøj, Thomas Strabo; Christiansen, Thomas; Somers, Marcel A. J.

    2008-01-01

    Abstract. In the present paper various experimental procedures to experimentally determine the concentration dependent diffusion coefficient of carbon in expanded austenite are evaluated. To this end thermogravimetric carburization was simulated for various experimental conditions and the evaluated...... composition dependent diffusivity of carbon derived from the simulated experiments was compared with the input data. The most promising procedure for an accurate determination is shown to be stepwise gaseous carburizing of thin foils in a gaseous atmosphere; the finer the stepsize, the more accurate...

  7. Strengthening of oxidation resistant materials for gas turbine applications. [treatment of silicon ceramics for increased flexural strength and impact resistance

    Science.gov (United States)

    Kirchner, H. P.

    1974-01-01

    Silicon nitride and silicon carbide ceramics were treated to form compressive surface layers. On the silicon carbide, quenching and thermal exposure treatments were used, and on the silicon nitride, quenching, carburizing, and a combination of quenching and carburizing were used. In some cases substantial improvements in impact resistance and/or flexural strength were observed. The presence of compressive surface stresses was demonstrated by slotted rod tests.

  8. Contribution to the densification study of silicon and zirconium carbides by an innovating process: the Spark Plasma Sintering; Contribution a l'etude de la densification des carbures de silicium et de zirconium par un procede innovant: le spark plasma sintering

    Energy Technology Data Exchange (ETDEWEB)

    Allemand, A. [CEA Saclay, Dept. des Materiaux pour le Nucleaire (DEN/DMN/SRMA/LTMEx), 91 - Gif-sur-Yvette (France); Guillard, F.; Galy, J. [Centre d' Elaboration de Materiaux et d' Etudes Structurales (CEMES-CNRS), 31 - Toulouse (France)

    2007-07-01

    In the framework of the CPR ISMIR, the works presented here take up the results of the thesis of F. Guillard defended on december 2006. This thesis has dealt with the Spark Plasma Sintering (SPS) technique and more particularly have been studied: 1)the {beta}SiC and ZrC sintering 2)the modelling of ZrC sintering by the SPS technique and 3)the studies of the carbides/oxides interfaces carried out by SPS. Concerning the {beta}SiC and ZrC sintering: the two carbides have been sintered between 1450 and 1950 C with times periods of 10 minutes and pressures between 50 and 150 MPa. These experiments have shown that the way to apply the pressure is of major importance. Moreover, 92% of densification can be reached after 5 minutes in 1850 C for SiC. For ZrC, 95% of densification is reached as soon as 5 minutes in 1750 C. Different correlations between grains size, density and the way to apply pressure are presented. For the SPS modelling of ZrC, two existing models, taking into account the diffusion laws, are used to try to model the SPS. The results are presented and discussed. At last, the SPS allows to make interfaces starting from powders or materials previously sintered. The SiC/ZrC and ZrO{sub 2}/SiC interfaces have been studied. A microstructural study is presented as well as a technique which allows the assembling with no cracks of SiC and ZrC. (O.M.)

  9. Behaviour analysis of the fuel injected in the intake manifold of port-injected spark ignition engines: modeling and experimental validation; Analyse du comportement du carburant injecte dans les conduits d`admission des moteurs a allumage commande a injection multipoint: modelisation et validation experimentale

    Energy Technology Data Exchange (ETDEWEB)

    Sches, C

    1999-01-27

    In order to limit pollutant emissions resulting from transient engine operation, the mastering of mixture formation is essential. In this context, an interactive work was undertaken between a modeling job and an experimental study, to get better understanding of the mechanisms of fuel dynamic behavior in the intake manifold of port-injected spark-ignition engines. The experimental study, elaborated thanks to experimental designs, showed out two essential factors: injection timing and coolant liquid temperature, which act on the fuel dynamic behavior through a second order filter. Then, a phenomenological modeling was established and validated, to analyze the various phenomena influencing mixture formation and to calculate the air/fuel ratio evolutions during transient operation. This program uses the results of a 3D model describing the fuel spray transportation, evaporation and impact on the port walls. The calculation does not need any boundary conditions and the running times are vary satisfactory. We showed that a correct description of the liquid fuel film was necessary to get good prediction of the mixture fuel/air ratio. The spray modeling, which is necessary, can however be kept simple. Future work may develop either in the engine control filed (injection strategies development, optimization of the injection system configuration, ...), or in the theoretical field (better modeling of fuel film displacement or of secondary atomization of the fuel on the intake valve). (author) 79 refs.

  10. Development and validation of an Eulerian model towards the simulation of fuel injection in internal combustion engines; Developpement et validation d'un modele eulerien en vue de la simulation des jets de carburants dans les moteurs a combustion interne

    Energy Technology Data Exchange (ETDEWEB)

    Truchot, B.

    2005-12-15

    The objective of this work is to develop an Eulerian two phase model to improve the prediction of fuel injection in internal combustion engines, particularly the dense liquid zone close to the nozzle. Lagrangian models, usually used in engine simulations, are based on the assumption of dispersed two phase flows with low liquid volume fraction, which is not fulfilled in the case of direct injection engine technology. Different Eulerian approaches are available in the literature. Physical phenomena that occur near the nozzle and characteristics of each model lead to the choice of a two fluids two pressures model. Several open terms appear in the equations of the model: exchange between the two phases and turbulent correlations. Closures of exchange terms are based on the spherical droplets hypothesis while a RANS approach is adopted to close turbulent correlations. This model has been integrated in the IFP CFD code, IFP-C3D. Several numerical tests and analytical validations (for single and two phase flows) have been then carried out in order to check the correct implementation of equations and the predictivity of the model and closures. Modifications in the turbulent model of the gas have required validations in both the gas phase (flow behind a sudden enlargement) and the liquid phase (pure liquid injection). A two phase mixing layer has been then used to validate the whole model. Finally, injection tests have been achieved under realistic conditions (similar to those encountered in automotive engines) in order to check the feasibility of engine computations using the developed Eulerian approach. These tests have also allowed to check the compatibility of this approach with the specificities of engine simulations (especially mesh movement). (author)

  11. Low temperature oxidation, co-oxidation and auto-ignition of olefinic and aromatic blending compounds: Experimental study of interactions during the oxidation of a surrogate fuel; Oxydation, co-oxydation et auto-inflammation a basses temperatures d'alcenes et aromatiques types: etude experimentale des interactions au sein d'un carburant-modele

    Energy Technology Data Exchange (ETDEWEB)

    Vanhove, G.

    2004-12-15

    The low-temperature (600-900 K) and high-pressure (5-25 bar) oxidation and auto-ignition of the three position isomers of hexene, of binary mixtures of 1-hexene, toluene and iso-octane, and of a surrogate fuel composed of these three compounds were studied in motor conditions using a rapid compression machine. Auto-ignition delay times were measured as long as intermediate products concentrations during the delay. The results show that the oxidation chemistry of the hexenes is very dependent on the position of the double bond inside the molecule, and that strong interactions between the oxidation mechanisms of hydrocarbons in mixtures can occur. The data obtained concerning the surrogate fuel give a good insight into the behaviour of a practical gasoline after an homogeneous charge compression. (author)

  12. Économie d'un procédé d'hydrolyse enzymatique et fermentation de la paille de blé pour la production d'alcool carburant Economics of a Process for Producing Alcohol Fuels by Enzymatic Hydrolysis and Fermentation of Wheat Straw

    Directory of Open Access Journals (Sweden)

    Arlie J. P.

    2006-11-01

    Full Text Available Après définition des grandes lignes d'un procédé de base d'hydrolyse-fermentation de la paille de blé, l'analyse de sensibilité montre que le rendement de l'hydrolyse a une grande importance sur les bilans énergétique et économique. Des rendements de l'ordre de 85 % permettent d'obtenir des valeurs d'investissement par tonne de pétrole économisée tout à fait comparables à celles obtenues par d'autres techniques de valorisation de la biomasse en alcool, telle la synthèse du méthanol obtenu après gazéification du bois à l'oxygène. The basic features of a process for production from cereal straw of an acetone-butanol mixture for use as a gasoline substitute are described. They include pretreatment and enzymatic hydrolysis of the substrate followed by fermentation of the sugars produced. A cost evaluation based on the performances of a reference process is presented. Then, an analysis of the sensitivity of the cost price of the process to the variation of the important parameters such as production capacity, enzyme productivity, hydrolysis yield is carried out. The energy balance of the process is presented.

  13. Properties of point defects either native or induced by irradiation in the 3C and 6H polytypes of silicon carbide determined by positron annihilation and EPR; Proprietes des defauts ponctuels natifs et induits par irradiation dans les polytypes 3C et 6H du carbure de silicium determinees par annihilation de positons et RPE

    Energy Technology Data Exchange (ETDEWEB)

    Kerbiriou, X

    2006-02-15

    Potential applications of silicon carbide (SiC) in micro-electronics have justified many studies on point defects, which play an important role in the electrical compensation. Moreover, this material has many assets to take part in the fissile materials confining in the gas cooled reactors of the future (4. generation). In this thesis, we have used Electronic Paramagnetic Resonance and Positron Annihilation Spectroscopy to study the properties of point defects (nature, size, charge state, migration and agglomeration during annealing), either native or induced by irradiation with various particles (H{sup +}, e{sup -}, carbon ions), in the 3C and 6H polytypes of SiC. The positron annihilation study of native defects in 6H-SiC has shown the presence of a strong concentration of non-vacancy traps of acceptor type, which are not present in the 3C-SiC crystals. The nature of the defects detected after irradiation with low energy electrons (190 keV) depends on the polytype. Indeed, while silicon Frenkel pairs and carbon mono-vacancies are detected in the 6H crystals, only carbon mono-vacancies are detected in the 3C crystals. We propose that these differences concerning the populations of detected point defects result from different values of the silicon displacement threshold energy for the two polytypes (approximately 20 eV for 6H and 25 V for 3C). In addition, the irradiations with 12 MeV protons and 132 MeV carbon ions have created silicon mono-vacancies as well as VSi-VC di-vacancies. Neither the particle (protons or ions carbon), nor the polytype (3C or 6H) influence the nature of the generated defects. Finally the study of the annealing of 6H-SiC monocrystals irradiated with 12 MeV protons have revealed several successive processes. The most original result is the agglomeration of the silicon mono-vacancies with the VSi-VC di-vacancies which leads to the formation of VSi-VC-VSi tri-vacancies. (author)

  14. Study of irradiation effects in the silicon carbide cubic polytype by photoluminescence and electron spin resonance spectroscopies; Etude des effets d'irradiation dans le polytype cubique du carbure de silicium par les techniques spectroscopiques de photoluminescence et de resonance paramagnetique electronique

    Energy Technology Data Exchange (ETDEWEB)

    Lefevre, J

    2008-01-15

    This experimental work has consisted in the study of point defects induced by an electronic irradiation in the cubic crystallographic structure of silicon carbide with low temperature photoluminescence and electron spin resonance spectroscopies. The first one of these measurement tools has allowed to estimate the displacement threshold energy in the silicon sub-lattice and then to analyze the thermal stability of the irradiation defects in the low temperature range: (10-300 K) and then in the high temperature range: (300-1400 K). Besides, on the base of a recent theoretical model, this thesis has confirmed the proposition of the isolated silicon antisite for the D1 center whose running beyond the nominal running temperature of fission nuclear reactors (generation IV), for which SiC is in part intended, seems to be particularly problematic. Measurements carried out by ESR under lighting have at last allowed to detect a new defect in its metastable spin state S=1, possibly associated to a silicon interstitial configuration. (O.M.)

  15. Report of the results of the fiscal 1997 regional consortium R and D project. Regional consortium energy field / Development of the plasma use surface treatment process by in-situ control (first fiscal year); 1997 nendo chiiki consortium kenkyu kaihatsu jigyo. Chiiki consortium energy bun`ya / in-situ seigyo ni yoru plasma riyo hyohi shori process no kaihatsu (daiichi nendo) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper described the fiscal 1997 result of the development. To know of in-plasma phenomena such as carburization and nitriding, a basic plasma experimental device was fabricated for quantitative measurement of reaction activity species. For the study of reaction control between plasma and substrate, a rotary analyzer type ellipsometer was fabricated as a method to detect composition and thickness of the deposit on the substrate surface. For He gas cooling after carburization and hardening, basic specifications for He gas refining/circulating system were confirmed. For perfect non-hazardous processing of exhaust gas from plasma carburization furnace, conducted was the thermodynamic computation of the process. Priority in order of the functions to be possessed as specifications for basic design of mini plant is plasma carburization, He gas cooling, and in-situ measurement. To make the most of the plasma use surface treatment as substitutes for expensive alloy elements, sliding parts/die-cast mold raw materials were carburized to measure the hardness. The Cr carbide coating technology by plasma CVD is also under study as an application example except carburization. 47 refs., 59 figs., 31 tabs.

  16. The effect of prior tempering on cryogenic treatment to reduce retained austenite

    International Nuclear Information System (INIS)

    Stratton, Paul

    2010-01-01

    The consensus view is that a high carbon case gives gears the best overall properties provided that there is no carbide network and that the retained austenite has been reduced below 20% by cryogenic treatment. This view is effectively enshrined in the SAE AMS 2759/7 standard. The cryogenic treatment usually takes place immediately after the quench to avoid austenite stabilisation. However, for some parts with complex geometries that might crack during the treatment, a short low temperature temper is carried out first. Little is known on how this temper affects the subsequent cryogenic treatment. Three carburizing steels used extensively in the aerospace industry were carburized to produce high retained austenite levels in the case using two different, but typical carburizing cycles. The retained austenite was determined by XRD before and after cryogenic treatment carried out in accordance with the standard and compared with that obtained when an intermediate temper was used. This study shows that for three typical carburizing steels, carburized using typical cycles, the efficacy of the cryogenic treatment is reduced only slightly after the temper, and not enough to be industrially significant. (author)

  17. Corrosion behaviour of high temperature alloys in impure helium environments

    International Nuclear Information System (INIS)

    Shindo, Masami; Quadakkers, W.J.; Schuster, H.

    1986-01-01

    Corrosion tests with Ni-base high temperature alloys were carried out at 900 and 950 0 C in simulated high temperature reactor helium environments. It is shown that the carburization and decarburization behaviour is strongly affected by the Cr and Ti(Al) contents of the alloys. In carburizing environments, additions of Ti, alone or in combination with Al, significantly improve the carburization resistance. In oxidizing environment, the alloys with high Cr and Al(Ti) contents are the most resistant against decarburization. In this environment alloys with additions of Ti and Al show poor oxidation resistance. The experimental results obtained are compared with a recently developed theory describing corrosion of high temperature alloys in high temperature reactor helium environments. (orig.)

  18. Evaluation of light LPG-fueled vehicles and comparison with their diesel-fueled and gasoline-fueled versions. Measurements of regulated and non-regulated pollutant emissions. Measurement of CO{sub 2} emissions and fuel consumption; Evaluation de vehicules legers fonctionnant au GPL et comparatif avec leurs versions essence et diesel. Mesures des emissions polluantes reglementees et non reglementees. Mesure des emissions de CO{sub 2} et de la consommation de carburant

    Energy Technology Data Exchange (ETDEWEB)

    Gagnepain, L.

    2004-04-01

    During the end of the 1990's the number of light LPG-fueled vehicles has increased thanks to the environmental advantages of this automotive fuel and to its tax depreciation advantage. A European emission test program (EETP) has been initiated by LPG companies (BP LPG, French committee of butane propane, liquefied petroleum gas association, Shell global autogas, SHV gas, Totalgas, Vereniging Vloeibaar Gas) and by environment agencies (Ademe, energy saving trust) in order to compare the environmental performances of LPG-fueled vehicles with their equivalent diesel-fueled and gasoline-fueled models. Four laboratories have participated to this evaluation: TUV (Germany), IFP (France), TNO (Netherlands) and Millbrook (UK). The comparative results are presented in tables and graphs (CO, HC, NO{sub x} and CO{sub 2} emissions, fuel consumption, CH{sub 4}, N{sub 2}O, benzene, 1,3-butadiene, formaldehyde, acetaldehyde, polycyclic aromatic hydrocarbons (PAH) emissions, 'well to wheel' greenhouse impact, ozone formation potential, carcinogen risk). The results show important differences among the different models and differences in the environmental performances depending on the vehicle utilization (highway, urban area use). In general the new generation (Euro 3) of LPG-fueled vehicles is significantly better in terms of environmental impact than the previous generation (Euro 2) of vehicles. (J.S.)

  19. Natural gas use in treatment of steel surfaces; Utilizacao de gas natural em tratamento de superficies de aco

    Energy Technology Data Exchange (ETDEWEB)

    Ferraz, Andre Dias; Machado, Antonio Rogerio; Rocha, Ivan; Azevedo, Jorge; Oshiro, Hugo K.; Konishi, Ricardo; Lehmkuhl, Willian [Companhia de Gas de Santa Catarina (SCGAS), Florianopolis, SC (Brazil); Piazza, Walter [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2011-12-21

    The surface treatments of metals, such as carburizing, rely on processing under high temperature in carbon rich atmospheres. The atmosphere is industrially generated using the partial oxidation of a carbon rich fuel, such as propane, butane or methanol. This article reports a study of the production of a carburizing atmosphere for surface treatment of steel from the partial oxidation of natural gas in a catalytic reactor. The reactor studied was a production size reactor with 300 mm of diameter and 1500 mm of length, packed with alumina supported nickel catalyst. The quality of the carburizing gas was evaluated from its carbon potential of the carburizing gas that was calculated from the concentrations of carbon monoxide (CO), carbon dioxide (CO{sub 2}), oxygen (O{sub 2}) and methane (CH{sub 4}) measured at the reactor's exit. The results indicate that CO concentration is very close to equilibrium, while CO{sub 2} is higher and CH{sub 4} is lower. Examining the reactor, the conclusion was that there was an axial temperature gradient, resulting in lower residence time under the required processing temperature. This resulted in smaller decomposition of CH{sub 4} and smaller production of CO{sub 2}. An equilibrium calculation of carbon potential, expressed as weight percent of carbon in iron, was developed to predict the possible optimizations of mixture composition and reactor temperature for a given required carbon potential. Conclusion: it is possible to generate a carburizing atmosphere under well controlled and repeatable conditions for the carbon potentials required for surface carburizing of steels in industrial processing using natural gas and air mixtures. (author)

  20. Method and alloys for fabricating wrought components for high-temperature gas-cooled reactors

    International Nuclear Information System (INIS)

    Thompson, L.D.; Johnson, W.R.

    1983-01-01

    Wrought, nickel-based alloys, suitable for components of a high-temperature gas-cooled reactor exhibit strength and excellent resistance to carburization at elevated temperatures and include aluminum and titanium in amounts and ratios to promote the growth of carburization resistant films while preserving the wrought character of the alloys. These alloys also include substantial amounts of molybdenum and/or tungsten as solid-solution strengtheners. Chromium may be included in concentrations less than 10% to assist in fabrication. Minor amounts of carbon and one or more carbide-forming metals also contribute to high-temperature strength. The range of compositions of these alloys is given. (author)

  1. Survey of post-irradiation examinations made of mixed carbide fuels

    International Nuclear Information System (INIS)

    Coquerelle, M.

    1997-01-01

    Post-irradiation examinations on mixed carbide, nitride and carbonitride fuels irradiated in fast flux reactors Rapsodie and DFR were carried out during the seventies and early eighties. In this report, emphasis was put on the fission gas release, cladding carburization and head-end gaseous oxidation process of these fuels, in particular, of mixed carbides. (author). 8 refs, 16 figs, 3 tabs

  2. 2665-IJBCS-Article-Issa Chaibou

    African Journals Online (AJOL)

    hp

    Saverys et al., 2007). En plus de ces aspects environnementaux, les agro carburants présentent des avantages socio-économiques certains pour les pays en développement. Le Niger veut s'engager dans le développement de la filière des ...

  3. Study of the water-gas shift reaction on Mo2C/Mo catalytic coatings for application in microstructured fuel processors

    NARCIS (Netherlands)

    Rebrov, E.V.; Kuznetsov, S.A.; Croon, de M.H.J.M.; Schouten, J.C.

    2007-01-01

    The activity and stability of two types of molybdenum carbide coatings deposited on molybdenum substrates (Mo2C/Mo) were compared in the water-gas shift reaction at 513–631 K. The activity of the Mo2C/Mo coatings obtained by carburization of preoxidized molybdenum substrates in a CH4/H2 mixture at

  4. Apparatus with moderating material for microwave heat treatment of manufactured components

    Science.gov (United States)

    Ripley, Edward B [Knoxville, TN

    2011-05-10

    An apparatus for heat treating manufactured components using microwave energy and microwave susceptor material. Heat treating medium such as eutectic salts may be employed. A fluidized bed introduces process gases which may include carburizing or nitriding gases The process may be operated in a batch mode or continuous process mode. A microwave heating probe may be used to restart a frozen eutectic salt bath.

  5. OF PLAIN CARBON AND LOW ALLOY STEELS

    African Journals Online (AJOL)

    Two steels En 3 and En 39 were given a TiC-TiN. CVD coating in the carburized and uncarburized conditions. The continuity of the coatings and their adherance to the substrate were examined. The thickness of the deposited coatings were also measured, their adherence to the substrate and their thickness was off ected by ...

  6. The effect of percentage carbonon the CVD coating of plain carbon ...

    African Journals Online (AJOL)

    Two steels En 3 and En 39 were given a TiC-TiN CVD coating in the carburized and uncarburized conditions. The continuity of the coatings and their adherance to the substrate were examined. The thickness of the deposited coatings were also measured, their adherence to the substrate and their thickness was off ected by ...

  7. Lattice expansion of carbon-stabilized expanded austenite

    DEFF Research Database (Denmark)

    Hummelshøj, Thomas Strabo; Christiansen, Thomas; Somers, Marcel A. J.

    2010-01-01

    The lattice parameter of expanded austenite was determined as a function of the content of interstitially dissolved carbon in homogeneous, carburized thin stainless steel foils. For the first time this expansion of the face-centered cubic lattice is determined on unstrained austenite. It is found...

  8. Impact of heat treatment on HSS cutting tool (ASTM A600) and its behaviour during machining of mild steel (ASTM A36)

    Science.gov (United States)

    Afolalu, S. A.; Abioye, O. P.; Salawu, E. Y.; Okokpujie, I. P.; Abioye, A. A.; Omotosho, O. A.; Ajayi., O. O.

    2018-04-01

    Carburization is one the best heat treatment that responded well to hardening with Palm Kernel Shell giving the best hardness value. This work studied the influence of carburization on HSStool(ASTM A600) and its behaviour during machining of mild steel (ASTM A36). Composition of the samples (12 pieces of 180 × 12 × 12 mm) HSS tools were checked using UV-VIS spectrometer and the tools were carburized with PKS at holding temperatures and time of 800, 850, 900, 950 °C and 60,90 120 minutes using muffle furnance. The micro structural analysis, surface and core hardnessof the treated samples gave better results than the untreated samples when checked withsoft driven and optical microscope. It wasalso observed that increase in the feed rate and depth for length of cut of 50 mm significantly reduces the wear progression and thereby gave best machining time at maximum carburizing temperature and time(950 °C / 120 minutes) when it was used to cut mild steelon the lathe machine.

  9. Melting of Grey Cast Iron Based on Steel Scrap Using Silicon Carbide

    Directory of Open Access Journals (Sweden)

    Stojczew A.

    2014-08-01

    Full Text Available The paper presents the issue of synthetic cast iron production in the electric induction furnace exclusively on the steel scrap base. Silicon carbide and synthetic graphite were used as carburizers. The carburizers were introduced with solid charge or added on the liquid metal surface. The chemical analysis of the produced cast iron, the carburization efficiency and microstructure features were presented in the paper. It was stated that ferrosilicon can be replaced by silicon carbide during the synthetic cast iron melting process. However, due to its chemical composition (30% C and 70% Si which causes significant silicon content in iron increase, the carbon deficit can be partly compensated by the carburizer introduction. Moreover it was shown that the best carbon and silicon assimilation rate is obtained where the silicon carbide is being introduced together with solid charge. When it is thrown onto liquid alloy surface the efficiency of the process is almost two times less and the melting process lasts dozen minutes long. The microstructure of the cast iron produced with the silicon carbide shows more bulky graphite flakes than inside the microstructure of cast iron produced on the pig iron base.

  10. Methods for microwave heat treatment of manufactured components

    Science.gov (United States)

    Ripley, Edward B.

    2010-08-03

    An apparatus for heat treating manufactured components using microwave energy and microwave susceptor material. Heat treating medium such as eutectic salts may be employed. A fluidized bed introduces process gases which may include carburizing or nitriding gases. The process may be operated in a batch mode or continuous process mode. A microwave heating probe may be used to restart a frozen eutectic salt bath.

  11. Interstitial Hardening of Stainless Steel for Enhanced Corrosion Resistance for Naval Applications

    Science.gov (United States)

    2017-03-01

    smoothness of the final polish. All of the specimens were treated with the same acetylene-based carburizing recipe : 16 hat 450 oc in 0.05 liters/minute...novel low temperature (< 500 Celsius) interstitial hardening process for stainless steels for impellers, fasteners and other marine items. Although

  12. Research on Nondestructive Testing.

    Science.gov (United States)

    1981-11-01

    acoustic waves in specimens of AISI 4140 steel austenitized at temperatures ranging from 900C to 1200°C and either slow cooled or oil quenched. The...However, little relevant experimental effort has been reported. We have been experimenting with samples of AISI 4615 steel, a low carbon, carburizing

  13. Expanded austenite; crystallography and residual stress

    DEFF Research Database (Denmark)

    Christiansen, Thomas; Hummelshøj, Thomas Strabo; Somers, Marcel A. J.

    2009-01-01

    The identity of expanded austenite as developing during low temperature nitriding and/or carburizing of austenitic stainless steel has been under debate since the very first observation of this phase. In the present article recent results obtained with i) homogeneous samples of various uniform co...

  14. The ternary Fe-C-N system: Homogeneous distributions of nitrogen and carbon

    DEFF Research Database (Denmark)

    Brink, Bastian; Ståhl, Kenny; Christiansen, Thomas Lundin

    2017-01-01

    of the nitriding and carburizing potentials, tailored nitrogen and carbon contents can be achieved, which allows assessment of a phase stability diagram for the Fe-N-C system, for which available experimental data is limited. Thermal decomposition sequences were established for the various iron carbides and (carbo...

  15. Hydrogen-oxygen powered internal combustion engine

    Science.gov (United States)

    Cameron, H.; Morgan, N.

    1970-01-01

    Hydrogen at 300 psi and oxygen at 800 psi are injected sequentially into the combustion chamber to form hydrogen-rich mixture. This mode of injection eliminates difficulties of preignition, detonation, etc., encountered with carburated, spark-ignited, hydrogen-air mixtures. Ignition at startup is by means of a palladium catalyst.

  16. Influence of heating rate on corrosion behavior of Ni-base heat resistant alloys in simulated VHTR helium environment

    International Nuclear Information System (INIS)

    Kurata, Yuji; Kondo, Tatsuo

    1985-04-01

    The influence of heating rate on corrosion and carbon transfer was studied for Ni-base heat resistant alloys exposed to simulated VHTR(very high temperature reactor) coolant environment. Special attention was focused to relationship between oxidation and carburization at early stage of exposure. Tests were conducted on two heats of Hastelloy XR with different boron(B) content and the developmental alloys, 113MA and KSN. Two kinds of heating rates, i.e. 80 0 C/min and 2 0 C/min, were employed. Corrosion tests were carried out at 900 0 C up to 500 h in JAERI Type B helium, one of the simulated VHTR primary coolant specifications. Under higher heating rate, oxidation resistance of both heats of Hastelloy XR(2.8 ppmB and 40 ppmB) were equivalent and among the best, then KSN and 113MA followed in the order. Under lower heating rate only alloy, i.e. Hastelloy XR with 2.8 ppmB, showed some deteriorated oxidation resistance while all others being unaffected by the heating rate. On the other hand the carbon transfer behavior showed strong dependence on the heating rate. In case of higher heating rate, significant carburization occured at early stage of exposure and thereafter the progress of carburization was slow in all the alloys. On the other hand only slow carburization was the case throughout the exposure in case of lower heating rate. The carburization in VHTR helium environment was interpreted as to be affected by oxide film formation in the early stage of exposure. The carbon pick-up was largest in Hastelloy XR with 40 ppmB and it was followed by Hastelloy XR with 2.8 ppmB. 113MA and KSN were carburized only slightly. The observed difference of carbon pick-up among the alloys tested was interpreted to be attributed mainly to the difference of the carbon activity, the carbide precipitation characteristics among the alloys tested. (author)

  17. Physical mechanisms of thermal-diffusivity depth-profile generation in a hardened low-alloy Mn, Si, Cr, Mo steel reconstructed by photothermal radiometry

    International Nuclear Information System (INIS)

    Nicolaides, Lena; Mandelis, Andreas; Beingessner, Clare J.

    2001-01-01

    It is well established that in hardened steels thermal-diffusivity broadly anticorrelates with microhardness, allowing thermal-wave depth profilometry to be used as a tool to measure microhardness profiles. Nevertheless, the physical mechanisms for this anticorrelation have not been well understood. In this work, the thermal-diffusivity profiles of rough, hardened industrial steels were reconstructed after the elimination of roughness effects from the experimental data. Carburizing and quenching are widely used for the heat treatment of steel components, and it is important to understand their effects on thermal-diffusivity profiles. A thorough examination of the actual mechanism by which thermal-diffusivity depth profiles are affected by first carburizing and then quenching AISI-8620 steels was performed. It was concluded that the variation of thermal diffusivity with depth is dominated by the carbon concentration profile, whereas the absolute value of the thermal diffusivity is a function of microstructure. [copyright] 2001 American Institute of Physics

  18. Use of a glow discharge lamp as an excitation source in emission spectrometry. Application to concentration gradients

    International Nuclear Information System (INIS)

    Delarue, G.; Pichat, R.

    1978-01-01

    The principle of the method is to take the material studied as a cathode of a discharge tube of very small volume: it is etched without fusion by bombardment with the rare gas ions participating in the discharge. The atoms of the sputtered metal are excited in the plasma existing between the electrodes and by measurement of the intensity of spectral lines one can determine the concentration of the elements in the sample. The principal advantage of the glow discharge lamp is to obtain the profile of concentration gradients: indeed by means of ionic bombardment, there is a gradual erosion of the sample with a constant speed. At every moment the composition of the plasma corresponds to the composition of the level which is etched. This technique is used to study diffusion gradients of carbon in carburized and not carburized steels [fr

  19. Synthesis and characterization of binder-free Cr3C2 coatings on nickel-based alloys for molten fluoride salt corrosion resistance

    International Nuclear Information System (INIS)

    Brupbacher, Michael C.; Zhang, Dajie; Buchta, William M.; Graybeal, Mark L.; Rhim, Yo-Rhin; Nagle, Dennis C.; Spicer, James B.

    2015-01-01

    Under various conditions, chromium carbides appear to be relatively stable in the presence of molten fluoride salts and this suggests that their use in corrosion resistant coatings for fluoride salt environments could be beneficial. One method for producing these coatings is the carburization of sprayed Cr coatings using methane-containing gaseous precursors. This process has been investigated for the synthesis of binder-free chromium carbide coatings on nickel-based alloy substrates for molten fluoride salt corrosion resistance. The effects of the carburization process on coating microstructure have been characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM) in conjunction with energy dispersive spectroscopy (EDS). Both plasma-sprayed and cold-sprayed Cr coatings have been successfully converted to Cr 3 C 2 , with the mechanism of conversion being strongly influenced by the initial porosity in the as-deposited coatings

  20. Effect of flowing sodium on corrosion and tensile properties of AISI type 316LN stainless steel at 823 K

    Science.gov (United States)

    Sivai Bharasi, N.; Thyagarajan, K.; Shaikh, H.; Balamurugan, A. K.; Bera, Santanu; Kalavathy, S.; Gurumurthy, K.; Tyagi, A. K.; Dayal, R. K.; Rajan, K. K.; Khatak, H. S.

    2008-07-01

    AISI type 316LN stainless steel was exposed to flowing sodium in mass transfer loop (MTL) at 823 K for 16 000 h and then examined for changes in the tensile properties due to the mass transfer and corrosion effects. Comparisons in microstructural and mechanical properties were made between annealed, thermally aged and sodium exposed materials. Microstructural examination of thermally aged and sodium exposed materials revealed precipitation of carbides at the grain boundaries. The sodium exposed samples contained a degraded layer at the surface up to a depth of around 10 μm and a surface carburized layer of about 30 μm. There was about 15% increase in yield strength and a decrease of about 20% in ductility for the sodium exposed material vis-a-vis thermally aged material and this was attributed to carburization effects and microstructural changes.

  1. Preparation of nanocrystalline iron-carbon materials as fillers for polymers

    International Nuclear Information System (INIS)

    Narkiewicz, U; Pelech, I; Roslaniec, Z; Kwiatkowska, M; Arabczyk, W

    2007-01-01

    This paper presents a method of preparing nanocrystalline iron-carbon materials which can be applied as fillers for polymers. Nanocrystalline iron samples were carburized either under ethylene/hydrogen mixture or under pure ethylene. Three kinds of samples were prepared: cementite/carbon (Fe 3 C/C), iron/cementite (Fe/Fe 3 C) and iron/carbon (Fe/C) ones. After carburization the samples were characterized using XRD and SEM methods. The obtained samples of iron-carbon nanoparticles were applied as fillers to polymer nanocomposites prepared in a polycondensation reaction (in situ) in a poly(ether-ester) matrix. The nanofillers were dispersed in monomers (diols) using a sonificator and a high-speed rotary stirrer. The obtained nanocomposites were characterized as regards their structure (SEM method) and mechanical behaviour

  2. Effect of flowing sodium on corrosion and tensile properties of AISI type 316LN stainless steel at 823 K

    International Nuclear Information System (INIS)

    Sivai Bharasi, N.; Thyagarajan, K.; Shaikh, H.; Balamurugan, A.K.; Bera, Santanu; Kalavathy, S.; Gurumurthy, K.; Tyagi, A.K.; Dayal, R.K.; Rajan, K.K.; Khatak, H.S.

    2008-01-01

    AISI type 316LN stainless steel was exposed to flowing sodium in mass transfer loop (MTL) at 823 K for 16 000 h and then examined for changes in the tensile properties due to the mass transfer and corrosion effects. Comparisons in microstructural and mechanical properties were made between annealed, thermally aged and sodium exposed materials. Microstructural examination of thermally aged and sodium exposed materials revealed precipitation of carbides at the grain boundaries. The sodium exposed samples contained a degraded layer at the surface up to a depth of around 10 μm and a surface carburized layer of about 30 μm. There was about 15% increase in yield strength and a decrease of about 20% in ductility for the sodium exposed material vis-a-vis thermally aged material and this was attributed to carburization effects and microstructural changes

  3. XPS, XRD and laser Raman analysis of surface modified of 6150 steel substrates for the deposition of thick and adherent diamond-like carbon coatings

    Energy Technology Data Exchange (ETDEWEB)

    Silva, William de Melo; Carneiro, Jose Rubens Goncalves, E-mail: williammelosilva@gmail.com [Pontificia Universidade Catolica de Minas Gerais (PUC-MG), Belo Horizonte (Brazil). Dept. de Engenharia Mecanica; Trava-Airoldi, Vladimir Jesus [Associate Laboratory of Sensors and Materials, National Institute for Space Research, Sao Jose dos Campos, SP (Brazil)

    2013-11-01

    Although the 6150 steel has an excellent fatigue and impact resistance, it is unsuitable to operate it when the corrosion is a limited factor. We propose here a sequence of steel pre-treatment by carburizing, carbonitriding and nitriding in order to improve the poor adhesion between Diamond Like-Carbon coatings on steel. This sequence is our attempt to reduce the difference between the coefficients of thermal expansion of steel and DLC through the graded interface. This work demonstrates the quantitative analysis of the molecules present at surface using X-ray photoelectron spectroscopy. The crystallographic structures are investigated by X-ray diffraction which shows the formation of carbides and nitride phases. Raman spectroscopy reveals the carburizing surface characteristics where DLC coating is nucleated and grown at the substrate. At the end of the analysis it is possible to verify which molecules and phases are formed on the steel surface interface after each step of pre-treatment. (author)

  4. Intrinsic magnetic properties of Sm2Fe17-xMxNy/Cy (M=Al, Ga or Si)

    International Nuclear Information System (INIS)

    Kubis, M.; Eckert, D.; Gebel, B.; Mueller, K.-H.; Schultz, L.

    2000-01-01

    Curie temperature T c , saturation polarization J s and anisotropy field H a of Sm 2 Fe 17-x M x N y /C y with M=Al, Ga or Si (x≤3, y∼3) were determined by thermomagnetic measurements and a numerical fitting procedure of demagnetization curves. An increasing amount of the substitutional element M leads to an increase of T c of the Sm 2 Fe 17-x M x parent compounds and generally to a decrease of T c , J s and H a for the interstitial nitrides and carbides. However, for small M contents, x≤1, an increased H a was observed compared to the substitution-free interstitial compounds. Gas-carburized and melt-carburized Sm 2 Fe 15 Ga 2 C y samples showed large differences in J s and H a but identical T c values

  5. Effects of ion-implanted C on the microstructure and surface mechanical properties of Fe alloys implanted with Ti

    International Nuclear Information System (INIS)

    Follstaedt, D.M.; Knapp, J.A.; Pope, L.E.; Yost, F.G.; Picraux, S.T.

    1984-01-01

    The microstructural and tribological effects of ion implanting C into Ti-implanted, Fe-based alloys are examined and compared to the influence of C introduced by vacuum carburization during Ti implantation alone. The amorphous surface alloy formed by Ti implantation of pure Fe increases in thickness when additional C is implanted at depths containing Ti but beyond the range of carburization. Pin-on-disc tests of 15-5 PH stainless steel show that implantation of both Ti and C reduces friction significantly under conditions where no reduction is obtained by Ti implantation alone; wear depths are also less when C is implanted. All available experimental results can be accounted for by consideration of the thickness and Ti concentration of the amorphous Fe-Ti-C alloy. The thicker amorphous layer on samples implanted with additional C extends tribological benefits to more severe wear regimes

  6. XPS, XRD and laser Raman analysis of surface modified of 6150 steel substrates for the deposition of thick and adherent diamond-like carbon coatings

    International Nuclear Information System (INIS)

    Silva, William de Melo; Carneiro, Jose Rubens Goncalves

    2013-01-01

    Although the 6150 steel has an excellent fatigue and impact resistance, it is unsuitable to operate it when the corrosion is a limited factor. We propose here a sequence of steel pre-treatment by carburizing, carbonitriding and nitriding in order to improve the poor adhesion between Diamond Like-Carbon coatings on steel. This sequence is our attempt to reduce the difference between the coefficients of thermal expansion of steel and DLC through the graded interface. This work demonstrates the quantitative analysis of the molecules present at surface using X-ray photoelectron spectroscopy. The crystallographic structures are investigated by X-ray diffraction which shows the formation of carbides and nitride phases. Raman spectroscopy reveals the carburizing surface characteristics where DLC coating is nucleated and grown at the substrate. At the end of the analysis it is possible to verify which molecules and phases are formed on the steel surface interface after each step of pre-treatment. (author)

  7. Sandblasting induced stress release and enhanced adhesion strength of diamond films deposited on austenite stainless steel

    Science.gov (United States)

    Li, Xiao; Ye, Jiansong; Zhang, Hangcheng; Feng, Tao; Chen, Jianqing; Hu, Xiaojun

    2017-08-01

    We firstly used sandblasting to treat austenite stainless steel and then deposited a Cr/CrN interlayer by close field unbalanced magnetron sputtering on it. After that, diamond films were prepared on the interlayer. It is found that the sandblasting process induces phase transition from austenite to martensite in the surface region of the stainless steel, which decreases thermal stress in diamond films due to lower thermal expansion coefficient of martensite phase compared with that of austenite phase. The sandblasting also makes stainless steel's surface rough and the Cr/CrN interlayer film inherits the rough surface. This decreases the carburization extent of the interlayer, increases nucleation density and modifies the stress distribution. Due to lower residual stress and small extent of the interlayer's carburization, the diamond film on sandblast treated austenite stainless steel shows enhanced adhesion strength.

  8. XPS, XRD and laser raman analysis of surface modified of 6150 steel substrates for the deposition of thick and adherent diamond-like carbon coatings

    Directory of Open Access Journals (Sweden)

    William de Melo Silva

    2013-06-01

    Full Text Available Although the 6150 steel has an excellent fatigue and impact resistance, it is unsuitable to operate it when the corrosion is a limited factor. We propose here a sequence of steel pre-treatment by carburizing, carbonitriding and nitriding in order to improve the poor adhesion between Diamond Like-Carbon coatings on steel. This sequence is our attempt to reduce the difference between the coefficients of thermal expansion of steel and DLC through the graded interface. This work demonstrates the quantitative analysis of the molecules present at surface using X-ray photoelectron spectroscopy. The crystallographic structures are investigated by X-ray diffraction which shows the formation of carbides and nitride phases. Raman spectroscopy reveals the carburizing surface characteristics where DLC coating is nucleated and grown at the substrate. At the end of the analysis it is possible to verify which molecules and phases are formed on the steel surface interface after each step of pre-treatment.

  9. Stress and Composition of Carbon Stabilized Expanded Austenite on Stainless Steel

    DEFF Research Database (Denmark)

    Christiansen, Thomas; Somers, Marcel A. J.

    2009-01-01

    Low-temperature gaseous carburizing of stainless steel is associated with a colossal supersaturation of the fcc lattice with carbon, without the development of carbides. This article addresses the simultaneous determination of stress and composition profiles in layers of carbon xpanded austenite...... obtained by low-temperature gaseous carburizing of AISI 316. X-ray diffraction was applied for the determination of lattice spacing depth profiles by destructive depth profiling and reconstruction of the original lattice spacing profiles from the measured, diffracted intensity weighted, values....... The compressive stress depth distributions correlate with the depth distribution of the strain-free lattice parameter, the latter being a measure for the depth distribution of carbon in expanded austenite. Elastically accommodated compressive stress values as high as -2.7 GPa were obtained, which exceeds...

  10. Low leaded motor gasoline of high knock rating having few pollution effects

    Energy Technology Data Exchange (ETDEWEB)

    Droste, W; Obenaus, F; Schoefer, W

    1975-11-13

    A carburator gasoline has been developed that has a high knock rating and few enviromental pollution effects. The gasoline contains 0.1 to 0.4 g of lead per liter, and up to 20 percent by volume of a mixture made up of 80 to 90 percent by weight methyl-tert.-butyl ether and 20 to 10 percent by weight methanol. Through tests it has been determined that the characteristics (particularly the octane number) of a gasoline having a lead content of 0.15 g/liter and one of the above mentioned additives are better than those of a gasoline with a lead content of 0.4 g/liter, but not containing an additive. The harmful emissions were also lower. In addition, the danger of carburator icing is decreased.

  11. Development of Barrier Layers for the Protection of Candidate Alloys in the VHTR

    Energy Technology Data Exchange (ETDEWEB)

    Levi, Carlos G. [Battelle Energy Alliance, LLC, Idaho Falls, ID (United States); Jones, J. Wayne [Battelle Energy Alliance, LLC, Idaho Falls, ID (United States); Pollock, Tresa M. [Battelle Energy Alliance, LLC, Idaho Falls, ID (United States); Was, Gary S. [Battelle Energy Alliance, LLC, Idaho Falls, ID (United States)

    2015-01-22

    The objective of this project was to develop concepts for barrier layers that enable leading candi- date Ni alloys to meet the longer term operating temperature and durability requirements of the VHTR. The concepts were based on alpha alumina as a primary surface barrier, underlay by one or more chemically distinct alloy layers that would promote and sustain the formation of the pro- tective scale. The surface layers must possess stable microstructures that provide resistance to oxidation, de-carburization and/or carburization, as well as durability against relevant forms of thermo-mechanical cycling. The system must also have a self-healing ability to allow endurance for long exposure times at temperatures up to 1000°C.

  12. Aluminide protective coatings on high–temperature creep resistant cast steel

    OpenAIRE

    J. Kubicki; A. Kochmańska

    2009-01-01

    This paper presents the results of research on aluminide protective coatings manufactured on high–temperature creep resistant cast steel. The main purpose of these coatings is protection against the high temperature corrosion, especially at high carburizing potential atmosphere. Coatings were obtained on cast steel type G–XNiCrSi36–18 with the following methods: pack cementation, paste method, cast method and slurry cementation. The phase composition, thickness and morphology of coatings were...

  13. A contribution to the study of the mixed uranium-plutonium mono-carbides containing small quantities of zirconium; Contribution a l'etude du monocarbure d'uranium et de plutonium avec de faibles additions de zirconium

    Energy Technology Data Exchange (ETDEWEB)

    Bocker, S. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1970-03-01

    We have studied a mixed monocarbide, type (U,Pu)C, containing small additions of zirconium for the application as a fast neutron reactor fuel. A preliminary study was conducted on the (U,Zr)C monocarbide (Report CEA-R-3765(1). It was found that small additions of zirconium to the uranium-plutonium monocarbide improve a number of properties such as atmospheric corrosion, the hardness, and particularly the compatibility with 316 stainless steel. However, properties such as the coefficient of expansion and the melting point are only slightly changed. The relative percentage of Pu/U+Pu in the monocarbide was fixed at 20 per cent. Two processes of fabrication were employed: casting in an arc furnace, sintering, carried out after having the hydrides of the metals carburized. The metallurgical results indicate, that the above mentioned fuel might be of interest for fast neutron reactor application. (author) [French] On a etudie un combustible de type carbure (U,Pu)C pour les reacteurs a neutrons rapides. Les recherches preliminaires ont porte sur le carbure (UZr)C (rapport CEA-R-3765(1)). L'addition de faibles quantites de zirconium (3 at. pour cent) au monocarbure (U,Pu)C, ameliore certaines proprietes, commee la tenue a la corrosion atmospherique, la durete et surtout la compatibilite avec l'acier inoxydable X-18 M, Par contre le coefficient de dilatation et la densite sont peu changes. Le rapport Pu/Pu+U etait fixe a 20 pour cent. Deux procedes de fabrication ont ete etudies: l'un par fusion a l'arc, l'autre par frittage a partir de metaux hydrures. Au vu des resultats metallurgiques obtenus le carbure (U,Pu,Zr)C semble presenter un interet certain. (auteur)

  14. About the elaboration of pure uranium dicarbide

    International Nuclear Information System (INIS)

    Besson, J.; Blum, P.; Guinet, Ph.; Spitz, J.

    1963-01-01

    In order to develop methods for the elaboration of as pure as possible uranium dicarbide, the authors report the study of different elaboration processes based on the reaction between uranium and carbon, or between uranium and hydrocarbon, or between uranium oxide and carbon. They finally choose a method which comprises an arc-induced fusion of a mixture of uranium dioxide and carbon. The fusion process is described. The influence of thermal treatments is discussed as well as the graphite electrode carburization

  15. Initiatives de reddition de comptes ascendante et acquisitions ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Corey Piccioni

    mentation, au carburant, à l'énergie et aux finances se sont récemment multipliées et une conséquence des plus immédi- ates et importantes est la réévaluation des terres à ... de cas et la recherche-action participative. Le projet devrait permette la production de données probantes sur la façon dont les résidents peuvent ...

  16. Incendiary Devices for the in-situ Combustion of Crude Oil Slicks

    Science.gov (United States)

    1983-01-01

    contiennent. Celles-cl se composent principalement d’un oxydant , le perchlorate d’ammonium, d’un carburant, une poudre m~tallique, et d’un liant...20.8 I- R T: 78% vt. R-45HT/22% wt. DDI-1410. 2- Epoxy: 85% vt. Epon 815/15% wt. Hysol 3543. 3- Solvent: ethyl alcohol . 4- F-ND: boron-potassium nitrate

  17. Mechanism and Influencing Factors of Iron Nuggets Forming in Rotary Hearth Furnace Process at Lower Temperature

    Science.gov (United States)

    Han, Hongliang; Duan, Dongping; Chen, Siming; Yuan, Peng

    2015-10-01

    In order to improve the efficiency of slag and iron separation, a new idea of "the separation of slag (solid state) and iron (molten state) in rotary hearth furnace process at lower temperature" is put forward. In this paper, the forming process of iron nuggets has been investigated. Based on those results, the forming mechanisms and influencing factors of iron nugget at low temperature are discussed experimentally using an electric resistance furnace simulating a rotary hearth furnace process. Results show that the reduction of iron ore, carburization of reduced iron, and the composition and quantity of slag are very important for producing iron nuggets at lower temperature. Reduction reaction of carbon-containing pellets is mainly at 1273 K and 1473 K (1000 °C and 1200 °C). When the temperature is above 1473 K (1200 °C), the metallization rate of carbon-containing pellets exceeds 93 pct, and the reduction reaction is substantially complete. Direct carburization is the main method for carburization of reduced iron. This reaction occurs above 1273 K (1000 °C), with carburization degree increasing greatly at 1473 K and 1573 K (1200 °C and 1300 °C) after particular holding times. Besides, to achieve the "slag (solid state) and iron (molten state) separation," the melting point of the slag phase should be increased. Slag (solid state) and iron (molten state) separation can be achieved below 1573 K (1300 °C), and when the holding time is 20 minutes, C/O is 0.7, basicity is less than 0.5 and a Na2CO3 level of 3 pct, the recovery rate of iron can reach 90 pct, with a proportion of iron nuggets more than 3.15 mm of nearly 90 pct. This study can provide theoretical and technical basis for iron nugget production.

  18. Effect of oxide film of heat resistant alloy on coke formation during naphtha pyrolysis

    International Nuclear Information System (INIS)

    Shiratori, Nobuo; Hosoya, Keizo

    2002-01-01

    The coking of cracking furnace tubes has been an important subject of ethylene plants. The coke formations rate on the heat resistant alloys of 20Cr-4.5Al-0.5Y 2 O 3 covered with Al 2 O 3 oxide film and 25Cr-35Ni covered with Cr 2 O 3 oxide film during the thermal cracking of naphtha was quantitatively evaluated at temperatures ranging from 810 to 930 .deg. C. The experimental results showed that the coke formation rate on 20Cr-4.5Al-0.5Y 2 O 3 was lower than that on 25Cr-35Ni because of the difference of a catalytic activity to coke formation, especially in the case of a pre-carburized condition. Namely, the Al 2 O 3 formed on 20Cr-4.5Al-0.5Y 2 O 3 was stable even after carburization treatment and inert for catalytic coke formation, while coke formation on 25Cr-35Ni was under the control of catalytic coke formation, and carburization of 25Cr-35Ni accelerated catalytic coke formation. The stability of Al 2 O 3 and Cr 2 O 3 in a hydrocarbon with steam environment was thermodynamically calculated in 0.1mol of steam, 0.2mol of ethylene and 0.1mol of methane at 1,100 .deg. C. The simulation result shows that Al 2 O 3 is exceedingly stable while Cr 2 O 3 could be decomposed partially into chromium carbide. Therefore, it is concluded that Al 2 O 3 on 20Cr-4.5Al-0.5Y 2 O 3 is more stable than Cr 2 O 3 on 25Cr-35Ni, and 20Cr-4.5Al-0.5Y 2 O 3 is more resistant to coke formation and carburization than 25Cr-35Ni in a hydrocarbon with steam environment at high temperature

  19. Direct Digital Manufacturing (DDM) for the Defense Industrial Base

    Science.gov (United States)

    2014-07-25

    excellent quality. Martensitic stainless steel alloy with 20% (wt.) TiC deposit provides hardness similar to a carburized surface. The deposit also...431 AISI stainless steel alloy 431 (SS 431) is a case hardenable steel that exhibits excellent corrosion resistance. Martensitic stainless steels ...with a chromium electroplated surface. Deposition materials that were evaluated during these work included Inconel 718 ® , AISI stainless steel 431

  20. Atténuation des risques pour la santé dans le secteur de la poterie ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    En effet, les potiers utilisent un carburant de piètre qualité (de la poussière de coton et du coton mazouté) pour faire fonctionner leurs fours en briques, ce qui engendre une importante pollution atmosphérique, contribuant ainsi aux problèmes de santé majeurs dans les secteurs environnants. Le présent projet vise à ...

  1. Accounting sodium effect in calculation of strength of nuclear reactor components

    International Nuclear Information System (INIS)

    Nikitin, V.I.

    1981-01-01

    Accounting methods of liquid sodium effect on long-term strength and creep of structural materials of nuclear reactors are considered. The decrease of pearlite steel strength at the decarburization expense and the decrease of plasticity of austenitic steels at the expense of carburization are noted. The necessity to account thermal transfer of mass is shown. Values of safety factors are presented, they are recommended for the design of reactor component parts with the thickness not less than 1 mm [ru

  2. Carbon transport in sodium systems

    International Nuclear Information System (INIS)

    Martin Espigares, M.; Lapena, J.; La Torre, M. de

    1983-01-01

    Carbon activities in dynamic non isothermal sodium system are determined using an equilibratium method. Foils of Fe-18 w% Cr-8 W% Ni alloy with low carbon content (in the as received condition) are exposed to dynamic liquid sodium in the temperature range between 450 0 C and 700 0 C. The analysis was used to evaluate the carburization-decarburization behaviour of type 304 stainless steel exposed to sodium. (author)

  3. Simulation of creep test on 316FR stainless steel in sodium environment at 550degC

    International Nuclear Information System (INIS)

    Satmoko, A.; Asayama, Tai

    1999-04-01

    In sodium environment, material 316FR stainless steel risks to suffer from carburization. In this study, an analysis using a Fortran program is conducted to evaluate the carbon influence on the creep behavior of 316FR based on experimental results from uni-axial creep test that had been performed at temperature 550degC in sodium environment simulating Fast Breeder Reactor condition. As performed in experiments, two parts are distinguished. At first, elastic-plastic behavior is used to simulate the fact that just before the beginning of creep test, specimen suffers from load or stress much higher than initial yield stress. In second part, creep condition occurs in which the applied load is kept constant. The plastic component should be included, since stresses increase due to section area reduction. For this reason, elastic-plastic-creep behavior is considered. Through time carbon penetration occurs and its concentration is evaluated empirically. This carburization phenomena are assumed to affect in increasing yield stress, decreasing creep strain rate, and increasing creep rupture strength of material. The model is capable of simulating creep test in sodium environment. Material near from surface risks to be carburized. Its material properties change leading to non-uniform distribution of stresses. Those layers of material suffer from stress concentration, and are subject to damage. By introducing a damage criteria, crack initialization can thus be predicted. And even, crack growth can be evaluated. For high stress levels, tensile strength criterion is more important than creep damage criterion. But in low stress levels, the latter gives more influence in fracture. Under high stress, time to rupture of a specimen in sodium environment is shorter than in air. But for stresses lower than 26 kgf/mm 2 , the time to rupture of creep in sodium environment is the same or little longer than in air. Quantitatively, the carburization effect at 550degC is not important. This

  4. Thermodynamics of the hydrogen-carbon-oxygen-tungsten system, as applied to the manufacture of tungsten and tungsten carbide

    International Nuclear Information System (INIS)

    Schwenke, G.K.

    2001-01-01

    The thermodynamics of the quaternary hydrogen-carbon oxygen-tungsten system and its binary and ternary sub-systems are reviewed. Published thermodynamic data are evaluated, and expression for free energies of formation are chosen. These expressions are integrated with and equilibrium-calculating algorithm, producing a powerful tool for understanding and improving the manufacture of tungsten and tungsten carbide. Three examples are presented: reduction/carburization of tungstic oxide with hydrogen, carbon, and methane. (author)

  5. À la suite de la parution d'un rapport sur les subventions aux ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    7 juin 2016 ... A Senegalese boy standing behind a car tire. Scott Wallace / The World Bank. John Cockburn. La protection sociale par le truchement de transferts en espèces peut-elle aider le Ghana à réduire l'écart grandissant que ses subventions aux carburants ont contribué à créer entre les riches et les pauvres ?

  6. A contribution to the study of the mixed uranium-plutonium mono-carbides containing small quantities of zirconium; Contribution a l'etude du monocarbure d'uranium et de plutonium avec de faibles additions de zirconium

    Energy Technology Data Exchange (ETDEWEB)

    Bocker, S [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1970-03-01

    We have studied a mixed monocarbide, type (U,Pu)C, containing small additions of zirconium for the application as a fast neutron reactor fuel. A preliminary study was conducted on the (U,Zr)C monocarbide (Report CEA-R-3765(1). It was found that small additions of zirconium to the uranium-plutonium monocarbide improve a number of properties such as atmospheric corrosion, the hardness, and particularly the compatibility with 316 stainless steel. However, properties such as the coefficient of expansion and the melting point are only slightly changed. The relative percentage of Pu/U+Pu in the monocarbide was fixed at 20 per cent. Two processes of fabrication were employed: casting in an arc furnace, sintering, carried out after having the hydrides of the metals carburized. The metallurgical results indicate, that the above mentioned fuel might be of interest for fast neutron reactor application. (author) [French] On a etudie un combustible de type carbure (U,Pu)C pour les reacteurs a neutrons rapides. Les recherches preliminaires ont porte sur le carbure (UZr)C (rapport CEA-R-3765(1)). L'addition de faibles quantites de zirconium (3 at. pour cent) au monocarbure (U,Pu)C, ameliore certaines proprietes, commee la tenue a la corrosion atmospherique, la durete et surtout la compatibilite avec l'acier inoxydable X-18 M, Par contre le coefficient de dilatation et la densite sont peu changes. Le rapport Pu/Pu+U etait fixe a 20 pour cent. Deux procedes de fabrication ont ete etudies: l'un par fusion a l'arc, l'autre par frittage a partir de metaux hydrures. Au vu des resultats metallurgiques obtenus le carbure (U,Pu,Zr)C semble presenter un interet certain. (auteur)

  7. Synthesis of Fine Mo2C Powder from Prereduced Mo in Undiluted CH4 Flow

    Science.gov (United States)

    Cetinkaya, S.; Eroglu, S.

    2017-10-01

    The carburization behavior of prereduced Mo was investigated in undiluted CH4 flow at 900-1000 K. Prior to the experiments, equilibrium thermodynamic analysis was carried out in the Mo-C-H system. The products were characterized by mass measurement, x-ray diffraction and scanning electron microscopy techniques. A single Mo2C phase was obtained within 45 min, 5 min, and 2.5 min at 900 K, 950 K, and 1000 K, respectively, at CH4 contents higher than the predicted ones. The reasons for this behavior were discussed in terms of CH4 stability, open tube flow, and self-created atmosphere in the powder bed. The fractional conversion-time curves indicated that the carburization kinetics followed a linear rate law. The Mo2C crystallite size (26-37 nm) and platelet thickness (50-100 nm) were found to be smaller than those of the parent Mo phase. These findings were attributable to the defects formed as a result of stresses associated with the reduction and the carburization.

  8. The Study of Heat Treatment Effects on Chromium Carbide Precipitation of 35Cr-45Ni-Nb Alloy for Repairing Furnace Tubes

    Directory of Open Access Journals (Sweden)

    Nakarin Srisuwan

    2016-01-01

    Full Text Available This paper presents a specific kind of failure in ethylene pyrolysis furnace tubes. It considers the case in which the tubes made of 35Cr-45Ni-Nb high temperature alloy failed to carburization, causing creep damage. The investigation found that used tubes became difficult to weld repair due to internal carburized layers of the tube. The microstructure and geochemical component of crystallized carbide at grain boundary of tube specimens were characterized by X-ray diffractometer (XRD, scanning electron microscopy (SEM with back-scattered electrons mode (BSE, and energy dispersive X-ray spectroscopy (EDS. Micro-hardness tests was performed to determine the hardness of the matrix and the compounds of new and used tube material. The testing result indicated that used tubes exhibited a higher hardness and higher degree of carburization compared to those of new tubes. The microstructure of used tubes also revealed coarse chromium carbide precipitation and a continuous carbide lattice at austenite grain boundaries. However, thermal heat treatment applied for developing tube weld repair could result in dissolving or breaking up chromium carbide with a decrease in hardness value. This procedure is recommended to improve the weldability of the 35Cr-45Ni-Nb used tubes alloy.

  9. Measurement of N and C diffusion in Sm{sub 2}Fe{sub 17} by magnetic relaxation

    Energy Technology Data Exchange (ETDEWEB)

    Mommer, N.; Hirscher, M.; Gerlach, M.; Van Lier, J.; Kronmueller, H. [Max-Planck-Institut fuer Metallforschung, Stuttgart (Germany); Kubis, M.; Mueller, K.-H. [Institut fuer Festkoerper und Werkstofforschung, Institut fuer Metallische Werkstoffe, D-01171 Dresden (Germany)

    1998-10-02

    Magnetic after-effect (MAE) measurements of nitrided and carburized Sm{sub 2}Fe{sub 17} compounds were performed in the temperature range of 140 K to 480 K. Both nitrided and carburized compounds show relaxation maxima at 285 and 300 K, respectively, which are absent in pure Sm{sub 2}Fe{sub 17} compounds. Therefore, these relaxation maxima are attributed to jumps of interstitially dissolved nitrogen or carbon atoms. Numerical evaluation yielded an activation enthalpy Q{sup N} (0.84{+-}0.05) eV and a pre-exponential factor {tau}{sub 0}{sup N}=3.10{sup -15{+-}1} s for the short-range diffusion of N atoms. The corresponding values for the carbon diffusion are Q{sup C}=(0.91{+-}0.05) eV and {tau}{sub 0}{sup C}=1.10{sup -15{+-}1} s. The carbon and nitrogen content of the samples was determined from the increase in mass during nitrogenation or carburization to Sm{sub 2}Fe{sub 17}N{sub 1.2} and Sm{sub 2}Fe{sub 17}C{sub 2.6}. (orig.) 18 refs.

  10. Measurement of N and C diffusion in Sm2Fe17 by magnetic relaxation

    International Nuclear Information System (INIS)

    Mommer, N.; Hirscher, M.; Gerlach, M.; Van Lier, J.; Kronmueller, H.; Kubis, M.; Mueller, K.-H.

    1998-01-01

    Magnetic after-effect (MAE) measurements of nitrided and carburized Sm 2 Fe 17 compounds were performed in the temperature range of 140 K to 480 K. Both nitrided and carburized compounds show relaxation maxima at 285 and 300 K, respectively, which are absent in pure Sm 2 Fe 17 compounds. Therefore, these relaxation maxima are attributed to jumps of interstitially dissolved nitrogen or carbon atoms. Numerical evaluation yielded an activation enthalpy Q N (0.84±0.05) eV and a pre-exponential factor τ 0 N =3.10 -15±1 s for the short-range diffusion of N atoms. The corresponding values for the carbon diffusion are Q C =(0.91±0.05) eV and τ 0 C =1.10 -15±1 s. The carbon and nitrogen content of the samples was determined from the increase in mass during nitrogenation or carburization to Sm 2 Fe 17 N 1.2 and Sm 2 Fe 17 C 2.6 . (orig.)

  11. Heterogeneities in local plastic flow behavior in a dissimilar weld between low-alloy steel and stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Mas, Fanny [Université Grenoble Alpes, SIMAP, 38000 Grenoble (France); CNRS, SIMAP, 38000 Grenoble (France); Martin, Guilhem, E-mail: guilhem.martin@simap.grenoble-inp.fr [Université Grenoble Alpes, SIMAP, 38000 Grenoble (France); CNRS, SIMAP, 38000 Grenoble (France); Lhuissier, Pierre; Bréchet, Yves; Tassin, Catherine [Université Grenoble Alpes, SIMAP, 38000 Grenoble (France); CNRS, SIMAP, 38000 Grenoble (France); Roch, François [Areva NP, Tour Areva, 92084 Paris La Défense (France); Todeschini, Patrick [EDF R& D, Avenue des Renardières, 77250 Moret-sur-Loing (France); Simar, Aude [Institute of Mechanics, Materials and Civil Engineering (iMMC), Université catholique de Louvain, 1348 Louvain-la-Neuve (Belgium)

    2016-06-14

    In dissimilar welds between low-alloy steel and stainless steel, the post-weld heat-treatment results in a high variety of microstructures coexisting around the fusion line, due to carbon diffusion and carbides dissolution/precipitation. The local constitutive laws in the vicinity of the fusion zone were identified by micro tensile specimens for the sub-millimeter sized zones, equivalent bulk materials representing the decarburized layer using both wet H{sub 2} atmosphere and diffusion couple, and nano-indentation for the carburized regions (i.e. the martensitic band and the austenitic region). The decarburized zone presents only 50% of the yield strength of the low-alloy steel heat affected zone and a ductility doubled. The carburized zones have a yield strength 3–5 times higher than that of the low-alloy steel heat affected zone and have almost no strain hardening capacity. These properties result in heterogeneous plastic deformation happening over only millimeters when the weld is loaded perpendicularly to the weld line, affecting its overall behavior. The constitutive laws experimentally identified were introduced as inputs into a finite elements model of the transverse tensile test performed on the whole dissimilar weld. A good agreement between experiments and simulations was achieved on the global stress-strain curve. The model also well predicts the local strain field measured by microscale DIC. A large out-of-plane deformation due to the hard carburized regions has also been identified.

  12. Characterization and performances of cobalt-tungsten and molybdenum-tungsten carbides as anode catalyst for PEFC

    International Nuclear Information System (INIS)

    Izhar, Shamsul; Yoshida, Michiko; Nagai, Masatoshi

    2009-01-01

    The preparation of carbon-supported cobalt-tungsten and molybdenum-tungsten carbides and their activity as an anode catalyst for a polymer electrolyte fuel cell were investigated. The electrocatalytic activity for the hydrogen oxidation reaction over the catalysts was evaluated using a single-stack fuel cell and a rotating disk electrode. The characterization of the catalysts was performed by XRD, temperature-programmed carburization, temperature-programmed reduction and X-ray photoelectron spectroscopy. The maximum power densities of the 30 wt% 873 K-carburized cobalt-tungsten and molybdenum-tungsten mixed with Ketjen carbon (cobalt-tungsten carbide (CoWC)/Ketjen black (KB) and molybdenum-tungsten carbide (MoWC)/KB) were 15.7 and 12.0 mW cm -2 , respectively, which were 14 and 11%, compared to the in-house membrane electrode assembly (MEA) prepared from a 20 wt% Pt/C catalyst. The CoWC/KB catalyst exhibited the highest maximum power density compared to the MoWC/KB and WC/KB catalysts. The 873 K-carburized CoW/KB catalyst formed the oxycarbided and/or carbided CoW that are responsible for the excellent hydrogen oxygen reaction

  13. Fabrication of Hadfield-Cored Multi-layer Steel Sheet by Roll-Bonding with 1.8-GPa-Strength-Grade Hot-Press-Forming Steel

    Science.gov (United States)

    Chin, Kwang-Geun; Kang, Chung-Yun; Park, Jaeyeong; Lee, Sunghak

    2018-05-01

    An austenitic Hadfield steel was roll-bonded with a 1.8-GPa-strength-grade martensitic hot-press-forming (HPF) steel to fabricate a multi-layer steel (MLS) sheet. Near the Hadfield/HPF interface, the carburized and decarburized layers were formed by the carbon diffusion from the Hadfield (1.2%C) to HPF (0.35%C) layers, and could be regarded as kinds of very thin multi-layers of 35 μm in thickness. The tensile test and fractographic data indicated that the MLS sheet was fractured abruptly within the elastic range by the intergranular fracture occurred in the carburized layer. This was because C was mainly segregated at prior austenite grain boundaries in the carburized layer, which weakened grain boundaries to induce the intergranular fracture. In order to solve the intergranular facture problem, the MLS sheet was tempered at 200 °C. The stress-strain curve of the tempered MLS sheet lay between those of the HPF and Hadfield sheets, and a rule of mixtures was roughly satisfied. Tensile properties of the MLS sheet were dramatically improved after the tempering, and the intergranular fracture was erased completely. In particular, the yield strength up to 1073 MPa along with the high strain hardening and excellent ductility of 32.4% were outstanding because the yield strength over 1 GPa was hardly achieved in conventional austenitic steels.

  14. BioTfueL Project: Targeting the Development of Second-Generation Biodiesel and Biojet Fuels Le projet BioTfueL : un projet de développement de biogazole et biokérosène de 2 génération

    Directory of Open Access Journals (Sweden)

    Viguié J.-C.

    2013-10-01

    Full Text Available 2nd generation biofuels will have an important part to take in the energy transition as far as fuels are concerned. Using non edible biomass, they will avoid any direct competition with food usage. Within 2nd generation biofuels, the BTL route consists in the production of middle distillates (Diesel and jet fuel via gasification and Fischer-Tropsch (FT synthesis. These fuels are called “drop in” fuels; this means that to be used they technically do not request any modification in the vehicle whatever the blending rate with conventional fuels. This route is currently at the pre-industrial phase where demonstration is required. This article presents the BioTfueL project which has been created by Axens, CEA, IFP Energies nouvelles, Sofiprotéol, ThyssenKrupp Uhde and Total. This project is focused on the original concept of co-processing (biomass can be gasified together with fossil feedstock and proposes to develop and demonstrate a full process chain to be commercialized worldwide via licensing. Les biocarburants de 2e génération ont un rôle important à jouer en ce qui concerne le pool carburant dans le cadre de la transition énergétique. Utilisant comme matière première de la biomasse non comestible, ces carburants éviteront toute compétition directe avec un usage alimentaire de cette ressource. Parmi les biocarburants de 2e génération, la voie BTL consiste en la production de distillats moyens (gazole moteur et carburéacteur via gazéification et synthèse Fischer-Tropsch (FT. Ces carburants sont communément appelés des « drop in fuels », ce qui signifie que techniquement ils ne nécessitent aucune modification du véhicule quelque soit leur taux d’incorporation dans les carburants traditionnels. Cette voie entre actuellement en phase préindustrielle pour laquelle une démonstration est nécessaire. Cet article présente le projet BioTfueL qui est porté par Axens, le CEA, IFP Energies nouvelles, Sofiprotéol, Thyssen

  15. The foil equilibration method for carbon in sodium

    Energy Technology Data Exchange (ETDEWEB)

    Borgstedt, H; Frees, G; Peric, Z [Karlsruhe Nuclear Research Center, Institute of Materials and Solid State Research, Karlsruhe (Germany)

    1980-05-01

    Among the non-metallic impurities in sodium, carbon plays an important role since at high temperatures the structural materials exposed to sodium are subject to carburization and decarburization depending on the carbon activity of the sodium. Carburization of austenitic stainless steels leads to reduction in ductility and fatigue properties whereas decarburization results in a decrease in the high temperature creep strength. A knowledge of the carbon activities in sodium will help understanding of the carbon transfer phenomena in operating sodium systems of the fast reactors, and also carbon diffusion, microstructural stability and mechanical behaviour of materials under different service conditions. An understanding of the carbon behaviour in sodium becomes difficult in view of the complexities of the different species present as elemental carbon, carbide, acetylide, carbonate, and cyanide. Carbon estimation techniques for sodium presently in use are: chemical analytical methods, on-line carbon monitors, and oil equilibration method. Various chemical methods have been developed for the estimation of different species like acetylide, cyanide, carbonate, elemental carbon, and total carbon in sodium. All these methods are time consuming and subject to various errors. The on-line monitors developed for carbon in sodium are able to give continuous indication of carbon activities and have higher sensitivity than the chemical methods. A still more simple method for the determination of carbon activities is by the foil equilibration first published by Natesan et al. Because of its simplicity like the vanadium wire equilibration for oxygen it is being used widely for the estimation of carbon activities in sodium systems. Carbon concentrations in operating sodium systems estimated by this procedure by applying solubility relation to carbon activities have yielded very low values of carbon, lower than the sensitivity limits of the chemical estimation methods. Foil

  16. Medium temperature reaction between lanthanide and actinide carbides and hydrogen; Reaction a temperature moyenne entre les monocarbures de lanthanides et d'actinides et l'hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    Dean, G; Lorenzelli, R; Pascard, R [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-07-01

    Hydrogen is fixed reversibly by the lanthanide and actinide mono carbides in the range 25 - 400 C, as for pure corresponding metals. Hydrogen goes into the carbides lattice through carbon vacancies and the total fixed amount is approximately equal to two hydrogen atoms per initial vacancy. Final products c.n thus be considered as carbo-hydrides of general formula M(C{sub 1-x}, H{sub 2x}). The primitive CFC, NaCl type, structure remains unchanged but expands strongly in the case of actinide carbides. With lanthanide carbides, hydrogenation induces a phase transformation with reappearance of the metal structure (HCP). Hydrogen decomposition pressures of all the studied carbo-hydrides are greater than those of the corresponding di-hydrides. (authors) [French] Les monocarbures d'actinides et de lanthanides fixent reversiblement de l'hydrogene a temperature peu elevee, a peu pres dans les memes conditions que les metaux purs correspondants. L'hydrogene penetre dans le reseau des carbures par l'intermediaire des lacunes de carbone, et la quantite totale fixee est approximativement egale a deux atomes d'hydrogene par lacune initiale. Les produits obtenus peuvent donc etre consideres comme des carbohydrures de formule generale M(C{sub 1-x}, H{sub 2x}). La structure d'origine CFC, type NaCl est conservee, mais avec une forte expansion, dans le cas des carbures d'actinides. En revanche, l'hydrogenation entraine un changement de phase cristalline avec retour a la structure du metal (HC) pour les carbures de lanthanides. Tous les carbohydrures etudies ont des tensions de decomposition en hydrogene superieures a celles des dihydrures correspondants. (auteurs)

  17. Existence and structure of rare-earth mono-carbides: study of their low-temperature magnetic properties; Existence et structure des monocarbures de terres rares. Etude de leurs proprietes magnetiques a basses temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Lallement, R [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Fontenay-aux-Roses, 92 (France)

    1966-07-01

    There are two types of rare earth carbides, the first one is face-centered cubic, stable at high temperature, and very hypo-stoichiometric (formula MC{sub x} with 0.35 < x < 0.65); the other is rhombohedric, stable at lower temperature, with a formula M{sub 2}C. These two carbides are magnetically ordered at low temperatures (ferro or ferri-magnetism). They are highly anisotropic. A great part of the electric and magnetic properties can be explained from the following ideas: the M{sup 3+} ions are coupled via the conduction electrons, there are more conduction electrons in the carbides than in the metals, and there is some local order around the transition temperatures. (author) [French] Nous avons mis en evidence l'existence de deux carbures de terres rares, l'un de formule MC{sub x} (0,35 < x < 0,65) de structure cubique a faces centrees, stable a haute temperature, l'autre de formule M{sub 2}C, de structure rhomhoedrique, stable a temperature moyenne. Ces deux types de carbures presentent des phenomenes d'ordre magnetique a basses temperatures (ferro ou ferrimagnetisme). Ils sont caracterises par une forte anisotropie magnetique. Une grande partie des proprietes electriques et magnetiques s'explique a partir des hypotheses suivantes: a) Les ions M{sup 3+} sont couples entre eux par l'intermediaire des electrons de conduction; b) Le nombre d'electrons de conduction dans les carbures est plus grand que dans les metaux; c) Autour des temperatures de transition se manifestent des phenomenes d'ordre local. (auteur)

  18. The foil equilibration method for carbon in sodium

    International Nuclear Information System (INIS)

    Borgstedt, H.; Frees, G.; Peric, Z.

    1980-01-01

    Among the non-metallic impurities in sodium, carbon plays an important role since at high temperatures the structural materials exposed to sodium are subject to carburization and decarburization depending on the carbon activity of the sodium. Carburization of austenitic stainless steels leads to reduction in ductility and fatigue properties whereas decarburization results in a decrease in the high temperature creep strength. A knowledge of the carbon activities in sodium will help understanding of the carbon transfer phenomena in operating sodium systems of the fast reactors, and also carbon diffusion, microstructural stability and mechanical behaviour of materials under different service conditions. An understanding of the carbon behaviour in sodium becomes difficult in view of the complexities of the different species present as elemental carbon, carbide, acetylide, carbonate, and cyanide. Carbon estimation techniques for sodium presently in use are: chemical analytical methods, on-line carbon monitors, and oil equilibration method. Various chemical methods have been developed for the estimation of different species like acetylide, cyanide, carbonate, elemental carbon, and total carbon in sodium. All these methods are time consuming and subject to various errors. The on-line monitors developed for carbon in sodium are able to give continuous indication of carbon activities and have higher sensitivity than the chemical methods. A still more simple method for the determination of carbon activities is by the foil equilibration first published by Natesan et al. Because of its simplicity like the vanadium wire equilibration for oxygen it is being used widely for the estimation of carbon activities in sodium systems. Carbon concentrations in operating sodium systems estimated by this procedure by applying solubility relation to carbon activities have yielded very low values of carbon, lower than the sensitivity limits of the chemical estimation methods. Foil

  19. Interactions of reactor helium and simulating gas mixtures with high-temperature metals with particular regard to simultaneous deformation

    International Nuclear Information System (INIS)

    Berchtold, L.

    1983-01-01

    For the observation of multicomponent alloys (Inconel 617 and 713LC, chroman (Ni20Cr), vacromium (Ni20Cr+Si), TZM) in multicomponent HTR atmospheres (HHT search gas), interaction between gases and metals was studied, both in theoretical descriptions and experimentally. From the experimental viewpoint, gradual simplification employs, on the one hand, tests effected in undiluted atmospheres with exclusively oxidizing or carburizing properties; on the other hand, more simple alloys and pure metals are applied specifically in the helium atmosphere. For an evaluation of the materials, it is maintained that in a strongly oxidizing (H 2 O-rich) atmosphere, e.g. in HHT search gas, materials with sufficient chrome content (e.g. 20% Cr in Ni alloys such as IN 617) offer favourable conditions for an almost complete interruption of carburizing reactions. In that case, the maintenance of the shielding effect of coating during rapid deformation and a tendency to planar delamination during deformation, which becomes stronger as the layer thickness increases, appear to be critical. Concentrations of oxide-forming agents stronger than chromium offer disadvantages rather than advantages. Owing to its tendency to flake off as the covering oxide SiO 2 or as part of a cover layer, silicon may more than destroy the light advantage of a slowed down process of carbon diffusion. The cast alloy IN 713LC shows a deep-reaching carburation in HHT search gas, both with and without deformation. No deep-reaching corrosive damage is noticeable on the molybdenum alloy TZM. (orig./MM) [de

  20. Oxidation Behavior of Surface-modified Stainless Steel 316LN in Supercritical-CO{sub 2} Environment

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sung Hwan; Heo, Jin Woo; Kim, Hyunm Yung; Jang, Chang Heui [KAIST, Daejeon (Korea, Republic of)

    2016-05-15

    Compared to other working fluids such as helium or nitrogen, S-CO{sub 2} offers a higher efficiency at operating temperatures of advanced reactors above 550 .deg. C. Moreover, the S-CO{sub 2} cycle is expected to have a significantly smaller footprint compared to other power conversion cycles, resulting in a broader range of applications with lower capital costs. Currently, stainless steel 316 is considered as the candidate structural material for the SFR. In comparison, it is well known that alumina (Al{sub 2}O{sub 3}) have superior oxidation and carburization resistance specifically at higher temperatures where α-Al{sub 2}O{sub 3} may form. Thus, various surface modification techniques have been applied to mostly Ni-base alloys so that a protective and continuous Al-rich oxide layer forms on the surface, conferring superior oxidation and carburization resistance. In this study, SS 316LN was deposited with Al via physical vapor deposition (PVD) method followed by heat treatment processes to develop an Al-rich layer at the surface. The specimens are to be exposed to high temperature S-CO{sub 2} environment to evaluate the oxidation and carburization resistance. Stainless steel 316LN was surface-modified to develop an Al-rich layer for improvement of oxidation behavior in S-CO{sub 2} environment. As the test temperature of 600 .deg. C is not sufficiently high for the formation of protective α-Al{sub 2}O{sub 3} formation, pre-oxidation of surface modified SS 316LN was conducted.

  1. Study of the sulfur mechanism on the formation of coke deposition on iron surfaces; Etude des mecanismes d'action du soufre sur le cokage catalytique du fer

    Energy Technology Data Exchange (ETDEWEB)

    Bonnet, F.

    2001-12-01

    The formation of coke deposition which occurs in a range of temperature 500 deg C-650 deg C is a major problem in many chemical and petrochemical processes where hydrocarbons or other strongly carburizing atmospheres are involved. To reduce the rate of coke deposition, sulfur can be added in the gas phase. The topic of this work is to study the sulfur mechanism on the formation of coke deposition on iron surfaces. Firstly, we study the mechanism of graphitic filament formation on reduced and oxidised iron surfaces. A new mechanism of catalytic particle formation is proposed when the surface is initially oxidised. This mechanism is based on thermodynamic, kinetic and structural considerations. The results show that oxide/carbide transitions are involved in the transformation of the oxide layer in catalytic particles. Although the different iron oxides are precursors for the formation of catalytic particles, wustite (FeO) has a better reactivity than magnetite (Fe{sub 3}O{sub 4}) and hematite (Fe{sub 2}O{sub 3}). Sulfur acts on different steps of the coke formation, preventing phase transformations (carburation, graphitization) which occur during the formation of catalytic particles. Sulfur activity required to prevent these transformations changes with the temperature, the chemical state of iron (reduced or oxidised) and the carbon activity in the gas phase. Sulfur/ethylene co-adsorption studies were performed on mono-crystal of iron (110). The results show that sulfur can prevent adsorption and decomposition of this hydrocarbon on metallic surface (Fe) and on magnetite (Fe{sub 3}O{sub 4}). Then, sulfur prevents the reaction leading to the carburation and graphitization of the surface. (author)

  2. Biocarburants : la Commission propose d’encourager leur utilisation

    Directory of Open Access Journals (Sweden)

    Vermeersch Georges

    2002-01-01

    Full Text Available Depuis longtemps, la Commission, le Parlement et le Conseil encouragent le développement des sources d’énergie renouvelables, et plus particulièrement des biocarburants. Cela s’est traduit, entre autres, par la publication en novembre 2000 d’un livre vert intitulé « Vers une stratégie européenne de sécurité d’approvisionnement énergétique », qui fixe comme objectif, d’ici 2020, le remplacement de 20% des carburants classiques par des carburants de substitution pour le transport routier. Plus récemment, en juin 2001, au sommet de Göteborg, a été souligné le rôle important des biocarburants dans la lutte contre le changement climatique et le développement des énergies propres. Ces encouragements restaient au niveau de la déclaration d’intention faute de moyens administratifs et fiscaux pour bâtir une véritable stratégie. Depuis le 7 novembre 2001, les choses semblent évoluer : en effet, à cette date, le collège des Commissaires a adopté une communication sur les carburants de substitution pour les transports routiers et une série de mesures visant à promouvoir l’utilisation des biocarburants. De plus - et c’est ce qui est fondamental - cette communication était assortie de deux propositions de directives, l’une visant à promouvoir l’utilisation des biocarburants dans les transports, l’autre concernant la possibilité d’appliquer un taux d’accises réduit sur certaines huiles minérales qui contiennent des biocarburants et sur les biocarburants.

  3. Corrosion behaviour of high temperature alloys in the cooling gas of high temperature reactors

    International Nuclear Information System (INIS)

    Quadakkers, W.J.; Schuster, H.

    1989-01-01

    The reactive impurities in the primary cooling helium of advanced high temperature gas cooled reactors (HTGR) can cause oxidation, carburization or decarburization of the heat exchanging metallic components. By studies of the fundamental aspects of the corrosion mechanisms it became possible to define operating conditions under which the metallic construction materials show, from the viewpoint of technical application, acceptable corrosion behaviour. By extensive test programmes with exposure times of up to 30,000 hours, a data base has been obtained which allows a reliable extrapolation of the corrosion effects up to the envisaged service lives of the heat exchanging components. (author). 6 refs, 7 figs

  4. Metal-dusting resistance of uncoated and coated iron and nickel base materials against metal-dusting in heat treatment furnaces with carbonaceous atmospheres

    International Nuclear Information System (INIS)

    Kleingries, Mirko; Ackermann, Helen; Lucka, Klaus; Hoja, Timo; Mehner, Andeas; Zoch, Hans-Werner; Altena, Herwig

    2010-01-01

    Metal-Dusting is a well-known corrosion problem that occurs in carburizing atmospheres in industrial thermal processing plants. In literature almost no quantitative data on the metal dusting resistance of typical alloys employed in industrial furnaces are available. Therefore, a series of experiments with uncoated and sol gel ZrO 2 coated high temperature materials was conducted in order to quantify their metal dusting behaviour under conditions close to those in case hardening furnaces. The experimental results show a strong influence of the surface conditions on the alloys resistance and a noticeable enhancement of the resistance by sol gel coatings. (orig.)

  5. Estudio de la reoxidación y carburización de pelets reducidos de mineral de hierro

    Directory of Open Access Journals (Sweden)

    Lemus R., J.

    1998-12-01

    Full Text Available The influence of carburization on the reoxidation of commercial iron ore pellets was studied. The pellets were H2-reduced up to 88 % and then carburized in H2/CO/CO2 gas mixture, for 0, 12, 18, 25 and 32 min, at 700, 800, 900 and 1000°C. After the reduction-carburization process, the pellets were reoxidized at 250, 300, 350 and 400°C. It was found out that the higher reduction temperature, the lower was the reoxidation degree. This effect was stronger at the reoxidation temperatures of 250 and 300°C. The presence of iron carbide (Fe3C was more notorious when the reduction was carried out at 700 and 800°C, and the carburization time was increased. Finally, it was observed that the higher the reoxidation temperature, the higher was the reoxidation degree.

    Se estudió la influencia de la carburización en la reoxidación de pelets de mineral de hierro de grado comercial. Los pelets fueron reducidos en hidrógeno hasta un 88 % y carburizados en una mezcla de gas H2-CO-CO2, por 0, 12, 18, 25 y 32 min a 700, 800, 900 y 1000°C. Después del proceso de reducción-carburización, los pelets se reoxidaron a 250, 300, 350 y 400°C. Se encontró que el grado de reoxidación disminuye con el incremento de la temperatura de reducción. Este efecto es más marcado a las temperaturas de reoxidación de 250°C y 300°C. La presencia de carburo de hierro (Fe3C fue más clara al incrementarse el tiempo de carburización cuando la reducción se llevó a cabo a 700 y 800°C. Finalmente, se observó que el grado de reoxidación es mayor a medida que se incrementa la temperatura de reoxidación .

  6. Biodiesel : la réglementation européenne et le débat sur son évolution

    Directory of Open Access Journals (Sweden)

    Dusser Philippe

    2013-09-01

    Full Text Available La réglementation communautaire sur les biocarburants a été mise en place à partir de 2003 pour répondre à un triple objectif : réduction des émissions de gaz à effet de serre, réduction de la dépendance énergétique, et soutien à la production agricole dans un contexte où 10 % des terres étaient obligatoirement gelées. Cette réglementation a été renforcée en 2009 dans le cadre du « paquet énergie » par l’introduction par la directive energie renouvelable d’un objectif obligatoire d’incorporation de 10 % d’énergie renouvelable dans les carburants à l’horizon 2020. Cette législation est complétée par une directive qualité des carburants qui impose une réduction de 6 % d’ici 2020 de l’empreinte carbone des carburants. La forte diésélisation du parc de véhicule en Europe a conduit à une rapide progression de la consommation de biodiesel (11 millions de tonnes dont 9 produites dans l’UE. L’huile de colza est la principale matière première du biodiesel. L’augmentation de la production de colza a permis de répondre à cette demande, tout en fournissant un coproduit protéique permettant de réduire significativement le déficit en protéines européen. Le débat sur l’impact du CASI (changement indirect d’affectation des sols des biocarburants, ainsi que celui sur l’équilibre alimentaire, a conduit la Commission européenne, 3 ans après avoir défini sa politique, à proposer de plafonner les carburants issus des cultures (1ere génération à 5 % et à introduire des « facteurs CASI » dans l’évaluation des effets de réduction des gaz à effets de serre. Cette proposition qui pourrait fortement remettre en cause le développement du biodiesel...et de la culture de colza fait à la date de rédaction de cet article (juillet 2013 l’objet de difficiles négociations à Bruxelles, dont l’issue est difficile à prédire.

  7. Preliminary study on high temperature heat exchanger for nuclear steel making

    Energy Technology Data Exchange (ETDEWEB)

    Mori, Y [Tokyo Inst. of Tech. (Japan); Ikegami, H

    1975-03-01

    In the high temperature heat exchanger as well as the steam reformer, several technical problems should be solved before realizing a nuclear plant complex for iron and steel making. Research has been carried out on heat exchanger between helium and steam, hydrogen permeation through super alloys, hydrogen removal using a titanium sponge, and creep and carburization performance of super alloys. The primary coolant used is helium having a pressure of approximately 12 kg/cm/sup 2/G and a temperature of approximately 1100/sup 0/C measured at the inlet of the high temperature heat exchanger, i.e., the test section. Steam, hydrogen and carbon monoxide are used as secondary coolants.

  8. Kinetics of Hydrocarbon formation in a- C:H Film deposition plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Cal, E de la; Tabares, F L

    1993-07-01

    The formation of C2 and Cp hydrocarbons during the PACVD of a-C:H films from admixtures of methane with H2 and He has been investigated by mass spectrometry under several deposition condition. The time evolution of the observed species indicates that the formation mechanisms of ethylene and acetylene are sensitive to the conditions of the wall during the growing of the film. Acetylene are sensitive to the conditions of the wall during the growing of the film. Acetylene formation was found to be directly related to the formation of the film on top of the carburized metal. (Author) 12 refs.

  9. Electrical conductivity and magnetic permeability measurement of case hardened steels

    Science.gov (United States)

    Tian, Yong

    2015-03-01

    For case carburized steels, electrical conductivity and magnetic permeability profiles are needed to develop model-based case depth characterization techniques for the purpose of nondestructive quality control. To obtain fast and accurate measurement of these material properties, four-point potential drop approaches are applied on circular-shaped discs cut from steel rings with different case depths. First, a direct current potential drop (DCPD) approach is applied to measure electrical conductivity. Subsequently, an alternating current potential drop (ACPD) approach is used to measure magnetic permeability. Practical issues in measurement design and implementation are discussed. Depth profiles of electrical conductivity and magnetic permeability are reported.

  10. Effect of carbon on the oxidation of zirconium; Influence du carbone sur l'oxygenation du zirconium a haute temperature

    Energy Technology Data Exchange (ETDEWEB)

    Chauvin, G; Boudouresques, B; Coriou, H; Hure, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    The study of specimens contaminated by different amounts of carbon shows a deleterious effect of this element in the resistance of zirconium to high temperature oxidation (700 to 900 deg. C). We drew the following results: a) the white spots or 'pimples' observed by numerous authors seem to be caused by the oxidation of precipitated carbides. We suggest a mechanism of formation and growth of these pimples; b) for a certain carbon content, the resistance to oxidation is increased by an uniform dispersion of the carbide phase and decreased, for instance, by extrusion textures. In this case, for the more marked textures, the more oriented corrosion was observed; c) by burning of the carbide phase it can result a second reaction increasing the corrosion rate; d) thin zirconium foils undergoes dimensional changes when scaling in oxygen. This unusual feature is also subordinated to carbon content and specially to the carbide phase dispersion. (author) [French] L'etude d'echantillons differemment contamines par le carbone nous a permis de mettre en evidence l'action particulierement nocive de cet element sur la resistance du zirconium a la corrosion par l'oxygene a haute temperature (700 a 900 deg. C). Nous avons pu degager les resultats essentiels suivants: a) l'origine des pustules d'oxyde blanc signalees par de nombreux auteurs doit etre recherchee dans l'oxydation des carbures precipites. Nous suggerons un mecanisme de formation et de croissance de ces pustules, b) la tenue du metal est d'autant meilleure que, pour une meme teneur en carbone, la phase 'carbure' est plus uniformement dispersee. En consequence, si la dispersion est mauvaise, on observe selon l'axe des textures de filage, par exemple, une corrosion preferentielle d'autant plus accentuee que les textures sont plus marquees, c) la combustion de la phase 'carbure' peut engendrer une reaction secondaire susceptible d'accroitre la cinetique de corrosion, d) l'expansion des grandes faces d

  11. A computational model for the carbon transfer in stainless steel sodium systems

    International Nuclear Information System (INIS)

    Casadio, S.; Scibona, G.

    1980-01-01

    A method is proposed of computing the carbon transfer in the type 316, 304 and 321 stainless steels in sodium environment as a function of temperature, exposure time and carbon concentration in the sodium. The method is based on the criteria developed at ANL by introducing some simplifications and takes also into account the correlations obtained at WARD. Calculated carbon profiles are compared both with experimental data and with the results available by the other computer methods. The limits for quantitative predictions of the stainless steel carburization or decarburization exposed in a specific environment are discussed. (author)

  12. Mezclas etanol-gasolina como combustible de motores de encendido por chispa

    OpenAIRE

    Rodríguez, Luis Arnoby; Ray Long, Bill

    2010-01-01

    In the Agricultural Mechanics Shop at Texas A&I University in Kingsville (TX), six ethanolgasoline blends (0, 20, 40, 60, 80 and 100% ethanol) were used to operated a six-cylinder engine at different operating conditions of air-fuel ratio, timing, load and speed. A main jet the carburator was used for each fuel to obtaining its stoichiometric air-fuel ratio. The main jet diameter was enlarged 1262 times from gasoline to ethanol. To select the optimun timing, timing was varied from Oto 26°...

  13. Corrosion and material transfer in a sodium loop

    International Nuclear Information System (INIS)

    Garcia, A.M.; Espigares, M.M.; Arroyo, J.; Borgstedt, H.U.; Kernforschungszentrum Karlsruhe G.m.b.H.

    1984-01-01

    The corrosion and material transfer behaviour of the martensitic steel X18 CrMoVNb 12 1 as a function of the temperature and the position is studied in the ML-1 sodium loop. Up to 600 C the material has the same good compatibility with liquid sodium as austenitic stainless steels, as well in the corrosion region of the loop as in the deposition zone in the cooled leg. The steel is not sensitive to carburization or decarburization under the conditions in the sodium rig. (author)

  14. Physical and Numerical Analysis of Extrusion Process for Production of Bimetallic Tubes

    Energy Technology Data Exchange (ETDEWEB)

    Misiolek, W.Z.; Sikka, V.K.

    2006-08-10

    Bimetallic tubes are used for very specific applications where one of the two metals provides strength and the other provides specific properties such as aqueous corrosion and carburization, coking resistance, and special electrical and thermal properties. Bimetallic tubes have application in pulp and paper industry for heat-recovery boilers, in the chemical industry for ethylene production, and in the petrochemical industry for deep oil well explorations. Although bimetallic tubes have major applications in energy-intensive industry, they often are not used because of their cost and manufacturing sources in the United States. This project was intended to address both of these issues.

  15. Kinetics of Hydrocarbon formation in a-C:H film deposition plasmas

    International Nuclear Information System (INIS)

    De la Cal, E.; Tabares, F.L.

    1993-01-01

    The formation of C 2 and C 3 hydrocarbons during the PACVD of a-C-H films from admixtures of methane with H 2 and He has been investigated by mass spectrometry under several deposition condition. The time evolution of the observed species indicates that the formation mechanism of ethylene and acetylene are sensitive to the conditions of the wall during the growing of the film. Acetylene are sensitive to the conditions of the wall during the growing of the carburized metal. (Author)

  16. Kinetics of Hydrocarbon formation in a-C:H Film deposition plasmas

    International Nuclear Information System (INIS)

    Cal, E. de la; Tabares, F. L.

    1993-01-01

    The formation of C2 and Cp hydrocarbons during the PACVD of a-C:H films from admixtures of methane with H2 and He has been investigated by mass spectrometry under several deposition condition. The time evolution of the observed species indicates that the formation mechanisms of ethylene and acetylene are sensitive to the conditions of the wall during the growing of the film. Acetylene are sensitive to the conditions of the wall during the growing of the film. Acetylene formation was found to be directly related to the formation of the film on top of the carburized metal. (Author) 12 refs

  17. Etude de la propagation sous critique dans les fibres de verre par relaxation de la charge

    OpenAIRE

    R'Mili , M.; Godin , N.; Lamon , J.

    2011-01-01

    International audience; Plusieurs fibres inorganiques de type verre ou céramique (à base de carbure de silicium) sont très sensibles à la propagation sous critique de fissures, activée chimiquement ou thermiquement. Dans ce cas la rupture survient d'une façon prématurée à un niveau de contrainte relativement bas comparé à la contrainte de rupture. Cet article propose une approche statistique de la rupture en fatigue statique fondée sur l'analyse de la rupture des fibres dans une mèche sollici...

  18. Raising the Corrosion Resistance of Low-Carbon Steels by Electrolytic-Plasma Saturation with Nitrogen and Carbon

    Science.gov (United States)

    Kusmanov, S. A.; Grishina, E. P.; Belkin, P. N.; Kusmanova, Yu. V.; Kudryakova, N. O.

    2017-05-01

    Structural features of the external oxide layer and internal nitrided, carbonitrided and carburized layers in steels 10, 20 and St3 produced by the method of electrolytic plasma treatment are studied. Specimens of the steels are tested for corrosion in a naturally aerated 1-N solution of sodium chloride. The condition of the metal/sodium chloride solution interface is studied by the method of electrochemical impedance spectroscopy. It is shown that the corrosion resistance of low-carbon steels can be raised by anode electrolytic-plasma saturation with nitrogen and carbon. Recommendations are given on the choice of carbonitriding modes for structural steels.

  19. Surface Treatment to Improve Corrosion Resistance in Lead-Alloy Coolants

    International Nuclear Information System (INIS)

    Was, Gary S.; Jones, J.W.; Pollock, T.

    2009-01-01

    The objective of the proposed research is to define strategies for the improvement of alloys for structural components, such as the intermediate heat exchanger and primary-to-secondary piping, for service at 1000 degree C in the He environment of the NGNP. Specifically, we will investigate the oxidation/carburization behavior and microstructure stability and how these processes affect creep. While generating this data, the project will also develop a fundamental understanding of how impurities in the He environment affect these degradation processes and how this understanding can be used to develop more useful life prediction methodologies

  20. Subsystem Testing and Flight Test Instrumentation.

    Science.gov (United States)

    1981-04-01

    du isoteur avec loa autres systemes do Ilavion. L’anticipation et la r~solution do con probl~mom doivent absolument Atro r~alis~es do faqon...carburant avian. Des esosis, par temps chaud et froid , sont g~n~ralement inclus dens tout programme de d6veloppemont (Kiruna (Finlande) ot Marrakech...trim froide , ainsi quaosur des terrains on altitude pormottont ensuite de contr8ler la vaLidit6 den conaignee do d~marrage propos6es. 7 -ALINENTATION

  1. An introduction to surface alloying of metals

    CERN Document Server

    Hosmani, Santosh S; Goyal, Rajendra Kumar

    2014-01-01

    An Introduction to Surface Alloying of Metals aims to serve as a primer to the basic aspects of surface alloying of metals. The book serves to elucidate fundamentals of surface modification and their engineering applications. The book starts with basics of surface alloying and goes on to cover key surface alloying methods, such as carburizing, nitriding, chromizing, duplex treatment, and the characterization of surface layers. The book will prove useful to students at both the undergraduate and graduate levels, as also to researchers and practitioners looking for a quick introduction to surface alloying.

  2. Carbon Formation and Metal Dusting in Hot-Gas Cleanup Systems of Coal Gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    Tortorelli, Peter F.; Judkins, Roddie R.; DeVan, Jackson H.; Wright, Ian G.

    1995-12-31

    There are several possible materials/systems degradation modes that result from gasification environments with appreciable carbon activities. These processes, which are not necessarily mutually exclusive, include carbon deposition, carburization, metal dusting, and CO disintegration of refractories. Carbon formation on solid surfaces occurs by deposition from gases in which the carbon activity (a sub C) exceeds unity. The presence of a carbon layer CO can directly affect gasifier performance by restricting gas flow, particularly in the hot gas filter, creating debris (that may be deposited elsewhere in the system or that may cause erosive damage of downstream components), and/or changing the catalytic activity of surfaces.

  3. Dosage direct des alcools dans les carburols par chromatographie en phase gazeuse Direct Gas Chromatographie Determination of Alcohols in Gasolines Blended by Oxygenated Compounds

    Directory of Open Access Journals (Sweden)

    Petroff N.

    2006-11-01

    Full Text Available Dans cette étude, on décrit une méthode de chromatographie en phase gazeuse utilisant une colonne remplie ; elle permet de doser, sans préfractionnement, les alcools jusqu'aux butanols dans les carburols (carburants additionnés de composés oxygénés. La phase stationnaire sélectionnée est le glycérol. This report describes a gas chromatographie method using a packed column. It allows the direct determination of alcohols up to butanols in gasolines blended with oxygenated compounds without prefractionation. Glycerol has been selected as stationary phase.

  4. Planar Edge Terminations and Related Manufacturing Process Technology for High Power 4H-SiC Diodes

    OpenAIRE

    Pérez Rodríguez, Raúl

    2005-01-01

    Consultable des del TDX Títol obtingut de la portada digitalitzada Els dispositius semiconductors de potència es requereixen per transmetre o rebre gairebé qualsevol tipus de senyal elèctrica i energia electromagnètica. En temps de constant augment del consum energètic i de la sensibilitat medi-ambiental, aquests petits dispositius poden dura a terme un gran paper. Un aspecte molt important és la elecció del material semiconductor. El carbur de silici (SiC) es un semiconductor de ample ...

  5. Wear properties of metal ion implanted 4140 steel

    International Nuclear Information System (INIS)

    Evans, P.J.; Paoloni, F.J.

    1994-01-01

    AISI type 4140 (high tensile) steel has been implanted with tungsten and titanium using a metal vapour vacuum arc ion source. Doses in the range (1-5)x10 16 ionscm -2 were implanted to a depth of approximately 30nm. The relative wear resistance between non-implanted and implanted specimens has been estimated using pin-on-disc and abrasive wear tests. Implantation of titanium decreased the area of wear tracks by a factor of 5 over unimplanted steel. In some cases the steel was also hardened by a liquid carburization treatment before implantation. Abrasion tests revealed a further improvement in wear resistance on this material following ion irradiation. ((orig.))

  6. Boron Steel: An Alternative for Costlier Nickel and Molybdenum Alloyed Steel for Transmission Gears

    Directory of Open Access Journals (Sweden)

    A. Verma

    2010-06-01

    Full Text Available Case Carburized (CC low carbon steels containing Ni, Cr and Mo alloying elements are widely used for transmission gears in automobile, as it possesses desired mechanical properties. In order to cut cost and save scarce materials like Ni and Mo for strategic applications, steel alloyed with Boron has been developed, which gives properties comparable to Ni-Cr-Mo alloyed steel. In the process of steel development, care was taken to ensure precipitation of boron which results in precipitation hardening. The characterization of the developed boron steel had exhibited properties comparable to Ni-Cr-Mo alloyed steel and superior to conventional boron steel.

  7. Alloys for 1000 degree C service in the Next Generation Nuclear Plant NERI 05-0191

    Energy Technology Data Exchange (ETDEWEB)

    Gary S. Was; J.W. Jones; T. Pollock

    2009-01-15

    The objective of the proposed research is to define strategies for the improvement of alloys for structural components, such as the intermediate heat exchanger and primary-to-secondary piping, for service at 1000 degree C in the He environment of the NGNP. Specifically, we will investigate the oxidation/carburization behavior and microstructure stability and how these processes affect creep. While generating this data, the project will also develop a fundamental understanding of how impurities in the He environment affect these degradation processes and how this understanding can be used to develop more useful life prediction methodologies.

  8. Etude des mécanismes d'interaction, au cours du procédé d'emboutissage à chaud, entre les surces atmosphériques d'hydrogène et les aciers à haute résistance revêtus d'Al-Si

    OpenAIRE

    Mandy, Mélodie; Jacques, Pascal; Georges, Cédric; Journée Jeunes Chercheurs 2015 - Commission "Corrosion sous contrainte / Fatigue-Corrosion"

    2015-01-01

    Dans l’industrie automobile, le défi permanent d’allègement en vue de diminuer la consommation de carburant est profitable tant au niveau économique qu’écologique. Pour permettre cette diminution de masse sans compromettre pour autant la sécurité des passagers, il est donc essentiel de développer des nuances d’aciers toujours plus résistantes. Néanmoins, ces aciers doivent également garder une certaine ductilité nécessaire à leur mise en forme, mais aussi fondamentale pour la sécurité des pas...

  9. Electromagnetic Detection of Stress Gradients at the Surfaces of Metals

    International Nuclear Information System (INIS)

    Schmidt, William F.; Zinke, Otto H.

    2004-01-01

    A general, integral expression is developed which relates measurements of the variations of the imaginary component of complex- reluctance with frequency to stress profiles near the surfaces of metals. The technique should yield either applied or residual stress profiles produced, for example, by heat-treating, metal-working, fatigue, or peening. It may even be applicable to carburizing. The technique of measurement cancels out the effects of any pre-treatment residual-stress profile (subject to the assumption of superposition). The general, integral expression is induced from the results of measurements on a steel bar which is subjected to both tensile tests and bending tests

  10. Optimisation of trawl energy efficiency under fishing effort constraint

    OpenAIRE

    Priour, Daniel; Khaled, Ramez

    2009-01-01

    Trawls energy efficiency is greatly affected by the drag, as well as by the swept area. The drag results in an increase of the energy consumption and the sweeping influences the catch. Methods of optimisation of the trawl design have been developed in order to reduce the volume of carburant per kg of caught fish and consequently the drag per swept area of the trawl. Based on a finite element method model for flexible netting structures, the tool modifies step by step a reference design. For e...

  11. Post irradiation examination and analysis of 13(U,Pu) C-fuel pins irradiated in the thermal flux of FR 2

    International Nuclear Information System (INIS)

    Weimar, P.; Steiner, H.

    1979-01-01

    The post-irradiation examination of the pins at Karlsruhe Hot Cells revealed the following results: Nearly all specimens showed noteworthy clad deformations (up to 3%). Defects in the form of cracks in the clad were found at three pins. The observed clad deformations resulted from mechanical interaction between fuel and cladding in consequence of an inexorable fuel swelling. A linear relationship between burnup and clad deformation was found. Defects were observed for burnups greater than 50 MWd/kgM and can be explained by the small fabrications clearances between clad and fuel pellets (50-90 μm) and high smear densities. Fission gas measurements were performed in a three fold way, gas release, gas trapped in pores and gas in solid solution in the lattice of the mixed carbide were determined. The gas release fraction showed values between 10 and 15%. Whereas the fission gas content trapped in large pores (> 1 μm) was linearly dependent on burnup, fission gas in small pores and in solid solution reached a saturation value at about 20 MWd/kgM. Measurements of micro-hardness revealed carburization depths of the clad of up to 40% at temperatures of about 650 0 C. Furtermore, it could be confirmed that the carburization depth followed an Arrhenius law. (orig.)

  12. Microstructure analysis and wear behavior of titanium cermet femoral head with hard TiC layer.

    Science.gov (United States)

    Luo, Yong; Ge, Shirong; Liu, Hongtao; Jin, Zhongmin

    2009-12-11

    Titanium cermet was successfully synthesized and formed a thin gradient titanium carbide coating on the surface of Ti6Al4V alloy by using a novel sequential carburization under high temperature, while the titanium cermet femoral head was produced. The titanium cermet phase and surface topography were characterized with X-ray diffraction (XRD) and backscattered electron imaging (BSE). And then the wear behavior of titanium cermet femoral head was investigated by using CUMT II artificial joint hip simulator. The surface characterization indicates that carbon effectively diffused into the titanium alloys and formed a hard TiC layer on the Ti6Al4V alloys surface with a micro-porous structure. The artificial hip joint experimental results show that titanium cermet femoral head could not only improve the wear resistance of artificial femoral head, but also decrease the wear of UHMWPE joint cup. In addition, the carburized titanium alloy femoral head could effectively control the UHMWPE debris distribution, and increase the size of UHMWPE debris. All of the results suggest that titanium cermet is a prospective femoral head material in artificial joint.

  13. Modeling and Analysis of Deformation for Spiral Bevel Gear in Die Quenching Based on the Hardenability Variation

    Science.gov (United States)

    Zhang, Yingtao; Wang, Gang; Shi, Wankai; Yang, Lin; Li, Zhichao

    2017-07-01

    Spiral bevel gears are widely used to transmit energy between intersecting axes. The strength and fatigue life of the gears are improved by carburizing and quenching. A die quenching process is used to control the deformation of the gear. The deformation is determined by the variations in the hardenability for a certain die quenching process. The relationship between hardenability, phase transformation and deformation needs to be studied to minimize deformation during the adjustment of the die quenching process parameters. In this paper, material properties for 22CrMoH steel are determined by the results of Jominy tests, dilatometry experiments and static mechanical property tests. The material models were built based on testing results under the consideration of hardenability variation. An finite element analysis model was developed to couple the phase transformation and deformation history of the complete carburizing and die quenching process for the spiral bevel gears. The final microstructures in the gear were bainite for low hardenability steel and a mixture of bainite and ferrite for high hardenability steel. The largest buckling deformation at the gear bottom surface is 0.375 mm at the outer circle for the low hardenability gear and 0.091 mm at the inner circle for the high hardenability gear.

  14. Prevention of crack initiation in valve bodies under thermal shock

    Energy Technology Data Exchange (ETDEWEB)

    Delmas, J.; Coppolani, P.

    1996-12-01

    On site and testing experience has shown that cracking in valves affects mainly the stellite hardfacing on seats and discs but may also be a concern for valve bodies. Metallurgical investigations conducted by EDF laboratories on many damaged valves have shown that most of the damage had either a chemical, manufacturing, or operating origin with a strong correlation between the origins and the type of damage. The chemical defects were either excess ferritic dilution of stellite or excess carburizing. Excess carburizing leads to a too brittle hardfacing which cracks under excessive stresses induced on the seating surfaces, via the stem, by too high operating thrusts. The same conditions can also induce cracks of the seats in the presence, in the hardfacing, of hidden defects generated during the welding process. Reduction of the number of defects results first from controls during manufacturing, mainly in the thickness of stellite. On the other hand, maintenance must be fitted to the type of defect. In-situ lapping may lead to release of cobalt, resulting in contamination of the circuit. Furthermore, it is ineffectual in the case of a crack through the seating surface, as is often found on globe valves. The use of new technologies of valves with removable seats and cobalt-free alloys solves permanently this kind of problem.

  15. Surface strengthening using a self-protective diffusion paste and its application for ballistic protection of steel plates

    International Nuclear Information System (INIS)

    Lou, D.C.; Solberg, J.K.; Borvik, T.

    2009-01-01

    This paper deals with surface strengthening of steel plates using a self-protective diffusion paste. During the surface strengthening process, a paste containing carbon, boron or similar is applied on the steel surface. In addition to serving as a source for the various diffusion ingredients, the paste protects the steel against contact with the environment, so no packing or gas protection is necessary. Thus, the handling is in general very simple, and the surface strengthening process can be performed in a conventional air furnace. The method provides the same type of surface strengthening that is obtained by more conventional methods. In this work, the main focus will be surface strengthening by carburizing, but also boronizing and boronizing followed by carburizing have been tested out. The methods have been applied to increase the ballistic resistance of the low-strength carbon steel NVE36 (with nominal yield stress of 355 MPa) against impacts from small-arms bullets. An empirical model combining diffusion depth, heat-treatment temperature and soaking time was established on the basis of a series of experimental data. By means of this equation, the various heat-treatment parameters can be predicted when others are chosen. Ballistic perforation tests using 7.62 mm APM2 bullets showed that the low-strength carbon steel after surface strengthening obtained a ballistic limit higher than that of Hardox 400, which is a wear steel with a yield stress of about 1200 MPa.

  16. The surface fatigue life of contour induction hardened AISI 1552 gears

    Science.gov (United States)

    Townsend, Dennis P.; Turza, Alan; Chaplin, Mike

    1995-07-01

    Two groups of spur gears manufactured from two different materials and heat treatments were endurance tested for surface fatigue life. One group was manufactured from AISI 1552 and was finished ground to a 0.4 micron (16 micro-in.) rms surface finish and then dual frequency contour induction hardened. The second group was manufactured from CEVM AISI 9310 and was carburized, hardened, and ground to a 0.4 micron (16 micro-in.) rms surface finish. The gear pitch diameter was 8.89 cm (3.5 in.). Test conditions were a maximum Hertz stress of 1.71 GPa (248 ksi), a bulk gear temperature of approximately 350 K (170 F) and a speed of 10,000 rpm. The lubricant used for the tests was a synthetic paraffinic oil with an additive package. The test results showed that the 10 percent surface fatigue (pitting) life of the contour hardened AISI 1552 test gears was 1.7 times that of the carburized and hardened AISI 9310 test gears. Also there were two early failures of the AISI 1552 gears by bending fatigue.

  17. The tensile properties of alloys 800H and 617 in the range 20 to 950deg C

    International Nuclear Information System (INIS)

    Abd El-Azim, M.E.; Ennis, P.J.; Schuster, H.; Nickel, H.

    1990-01-01

    The tensile properties of Alloy 800H and Alloy 617 in the solution treated condition and after ageing or carburization have been determined for the temperature range 20 to 950deg C. It was found that ageing at 900deg C prior to testing led to an increase in strength and a decrease in ductility at test temperatures up to 700deg C. Above 700deg C, there was no significant difference between the tensile properties of solution treated and aged material. Carburization caused a severe loss of ductility in both alloys at temperatures of 20 to around 800deg C, but the ductility increased sharply at test temperatures above 800deg C, accompanied by a change in the fracture mode from fracture of the carbide particles themselves to void formation and separation at the carbide/matrix interface. The correlation between tensile properties and creep data was investigated in tests carried out at different strain rates. Reasonable agreement was found at 800 to 950deg C for Alloy 617 and at 800 to 900deg C for Alloy 800H. Strain ageing effects were observed in both alloys at some temperatures and strain rates; these effects were serrated flow, negative strain rate sensitivity, peaks in the normalized UTS-temperature curves and plateaus in the elongation-temperature curves. The experimental results were interpreted in the light of two current models for strain ageing, the dislocation-dislocation interaction model and the dislocation-solute interaction model. (orig.) [de

  18. Novel technologies for the lost foam casting process

    Science.gov (United States)

    Jiang, Wenming; Fan, Zitian

    2018-03-01

    Lost foam casting (LFC) is a green precision casting process categorized as a near net forming technology. Yet, despite its popularity, it still suffers from some technological problems, such as poor filling ability of the castings, coarse and non-dense microstructure, low mechanical properties for the Al and Mg LFC processes, and defective carburization for the low carbon steel LFC process. These drawbacks restrict the development and widespread application of the LFC process. To solve these problems, the present study developed several novel LFC technologies, namely, LFC technologies under vacuum and low pressure, vibration solidification, and pressure solidification conditions; expendable shell casting technology; and preparation technology of bimetallic castings based on the LFC process. The results showed that the LFC under vacuum and low pressure evidently improved the filling ability and solved the oxidization problem of the alloys, which is suitable for producing complex and thinwall castings. The vibration and pressure solidifications increased the compactness of the castings and refined the microstructure, significantly improving the mechanical properties of the castings. The expendable shell casting technology could solve the pore, carburization, and inclusion defects of the traditional LFC method, obtaining castings with acceptable surface quality. Moreover, the Al/Mg and Al/Al bimetallic castings with acceptable metallurgical bonding were successfully fabricated using the LFC process. These proposed novel LFC technologies can solve the current technological issues and promote the technological progress of the LFC process.

  19. Carbon transfer between 2 1/4 Cr 1 Mo alloy and austenitic steels (experiments in anisothermal loops)

    International Nuclear Information System (INIS)

    Baque, P.; Besson, M.; Champeix, L.; Donati, J.R.; Oberlin, C.; Saint-Paul, P.

    1976-01-01

    Studies on carbon transfer between the ferritic steel 2 1/4 Cr 1 Mo and the austenitic steels 316L and 321H have shown that there is not any measurable carbon transfer in the operating conditions of the secondary circuit of PHENIX (475 deg C was the maximal temperature of the 2 1/4 Cr 1 Mo steel). A significant carbon transfer has been observed between the ferritic steel and the 316L steel when the 321H was replaced by the 2 1/4 Cr 1 Mo steel in the same thermohydraulic conditions (the ferritic steel was then used up to 545 deg C). This experiment has demonstrated the importance of the temperature and the initial carbon content of the ferritic steel as parameters in the decarburization process. It appears that decarburization may not be sensitive to the thermohydraulic conditions at least in the range investigated in those experiments. In the other hand the 316L steel is observed to have been carburized, the degree of carburization remaining appreciably constant and independent on the temperature between 400 deg C and 550 deg C [fr

  20. Intrinsic magnetic properties of Sm{sub 2}Fe{sub 17-x}M{sub x}N{sub y}/C{sub y} (M=Al, Ga or Si)

    Energy Technology Data Exchange (ETDEWEB)

    Kubis, M.; Eckert, D.; Gebel, B.; Mueller, K.-H. E-mail: khm@ifw-dresden.de; Schultz, L

    2000-07-01

    Curie temperature T{sub c}, saturation polarization J{sub s} and anisotropy field H{sub a} of Sm{sub 2}Fe{sub 17-x}M{sub x}N{sub y}/C{sub y} with M=Al, Ga or Si (x{<=}3, y{approx}3) were determined by thermomagnetic measurements and a numerical fitting procedure of demagnetization curves. An increasing amount of the substitutional element M leads to an increase of T{sub c} of the Sm{sub 2}Fe{sub 17-x}M{sub x} parent compounds and generally to a decrease of T{sub c}, J{sub s} and H{sub a} for the interstitial nitrides and carbides. However, for small M contents, x{<=}1, an increased H{sub a} was observed compared to the substitution-free interstitial compounds. Gas-carburized and melt-carburized Sm{sub 2}Fe{sub 15}Ga{sub 2}C{sub y} samples showed large differences in J{sub s} and H{sub a} but identical T{sub c} values.

  1. Study on single step solid state synthesis of WC@C nanocomposite and electrochemical stability of synthesized WC@C & Pt/WC@C for alcohol oxidation (methanol/ethanol)

    Energy Technology Data Exchange (ETDEWEB)

    Singla, Gourav, E-mail: gsinghla@gmail.com; Singh, K., E-mail: kusingh@thapar.edu; Pandey, O.P., E-mail: oppandey@thapar.edu

    2016-04-25

    WC@C nano composite was prepared by a single step solid–state reaction through in situ reduction and carburization of WO{sub 3} in the presence of Mg and activated charcoal. The XRD results and thermodynamics analysis showed that the optimization of reaction temperature facilitates the reduction as well as carburization of tungsten oxide(s) at different reaction temperature. Thermogravimetric analysis of the product was done to assess the thermal stability in air. The Raman spectroscopy was used to find out the nature (amorphous/graphitic) of carbon in the obtained phase. The N{sub 2} adsorption–desorption measurement showed a narrow pore size distribution from 3 to 4 nm with BET surface area of up to 522.5 m{sup 2}/g. TEM/HRTEM images confirmed formation of the WC nano particles with spherical morphology. Electrochemical stability of pure and platinized carbide sample (Pt/WC) has been investigated using cyclic voltammetry in acidic media for alcohol (methanol and ethanol) oxidation. - Highlights: • Tungsten carbide nano powder was synthesized using charcoal as carbon source. • Formation of WC occurs through the formation of lower tungsten oxide. • CO{sub 2}/CO ratio effect the formation of WC. • Mesoporous tungsten carbide with surface areas 522.5 m{sup 2}/g obtained by using charcoal. • Pt modified WC powder showed higher electrochemical stability.

  2. Creep properties of superalloys for the HTGR in impure helium environments

    International Nuclear Information System (INIS)

    Kawakami, H.; Nakanishi, T.

    1981-01-01

    This paper describes creep behaviors of two heat resistant alloys, Hastelloy X and Incoloy 800, in helium environments of the HTGR. In impure helium environments, these alloys are susceptible to carburization and oxidization. We have investigated these effects separately, and related them to the creep behaviors of the alloys. Experiments were carried out at 900 0 C both in helium and in air. Carburization results in decrease of secondary creep strain rate and delay of tertiary creep initiation. Oxidization caused decrease in tertiary creep strain rate of Hastelloy X, but did not that of Incoloy 800. Enhancement in tertiary creep strain rate of Hastelloy X in a very weakly oxidizing environment was confirmed in creep crack growth experiment using notched plate specimens. The rupture time of Hastelloy X in helium was short when compared with in air. Stress versus rupture time curves for both environments were parallel up to 5000 hours test, and a ratio of rupture stress in helium to that in air was about 0.9. In case of Incoloy 800, rupture time in helium was markedly prolonged as compared with that in air. (orig.)

  3. Study of the first stages of oxidation of a ferritic-martensitic steel Fe-12Cr in CO2

    International Nuclear Information System (INIS)

    Bouhieda, S.

    2012-01-01

    In the framework of the development of Sodium Fast Reactors in France, supercritical carbon dioxide integrated in the Brayton cycle is proposed as new cycle energy conversion system to replace current steam generators. Ferritic-Martensitic steels with 9-12 wt% Cr are good candidates for heat exchanger application because they have good mechanical properties up to a temperature of 600 C, a high thermal conductivity, a low coefficient of thermal expansion and a lower cost than that of austenitic steels. However, it has been found that these steels present a high parabolic oxide growth rate and a strong carburization in the temperature and pressure conditions of the SC-CO 2 cycle (550 C, 250 bar). This study aims to investigate the influence of different parameters (impurities present in CO 2 , thermal ramp rate and surface state) on the oxidation mechanism of a Fe-12 Cr steel in CO 2 at 550 C. It has been shown that depending on these parameters, a thin protective oxide scale without any strong carburization can be obtained. A model is proposed to explain the experimental results. (author) [fr

  4. Application of a commercial diffusion type carbon meter in a sodium circuit

    International Nuclear Information System (INIS)

    Bhat, N.P.; Borgstedt, H.U.; Peric, Z.; Witting, G.

    1980-01-01

    The exchange of carbon between structural materials and liquid sodium influences the mechanical properties of components of the cooling circuits. Therefore, the estimation of the carbon content of the alkali metal and the knowledge of its carburizing potential is of importance. Since some years the measurement of the carburizing potential of sodium is easy to perform by the application of the foil equilibration method which leads to good results in spite of the very low carbon concentrations in the liquid metal. Thin foils (0.025 to 0.125 mm) of Fe-18Cr-8Ni-C alloy (corresponding to stainless steel type AISI 304) are immersed in sodium at 550 to 700 deg. C for 200 to 400 hours. The equilibrium of the carbon distribution must be reached. Chemical analyses of the steel tabs and relation of concentration to activity of carbon lead to information on the carbon concentration in the sodium, if the saturation concentration of carbon in sodium is known. The method gives arbitrary values over a longer period of time. The time needed for equilibration and analysis causes a delay for the getting of results. Therefore, there is a need for instruments which are capable to measure carbon directly in the circuits and give continuously information on the actual carbon activities in the fluid. Until 1975 only one carbon meter was commercially available. One unit in was tested a chemical analytical sodium circuit

  5. Fiscal 1999 achievement report on regional consortium research and development project. Regional consortium on energy research in its 3rd year (Development of metal forming technology using new energy-efficient process); 1999 nendo sho energy gata shingata process ni yoru kinzoku seikei gijutsu no kaihatsu seika hokokusho. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    An energy-efficient forming technology is developed for heat-resistant hard materials which are difficult to cut and demand much energy for their precision forming. It is hoped that a material Hv1000 in hardness if obtained will enable the manufacture of cutting tools for use under severe conditions. Under the circumstances, a material based on Fe-4.5%Mo-1.5%V-3%Cr is produced with high reproducibility, where a carbide dispersion carburization (CDC) method (vacuum carburization at 1,040 degrees C, second quenching at 800-850 degrees C, and tempering at 160 degrees C) is employed for realizing a very fine structure. This as the tip is combined with the tool, which is then tested for abrasion. As compared with the control material, it is found that the abrasion of the new material is but 33% of that of the control material. Studies are under way for a commercially acceptable constitution which will exhibit Hv1000 after heat treatment and for conditions of CDC treatment. An intermetallic compound TiAlCr, to be obtained by a process of mechanical alloying and pulse discharge sintering, is found to be superplastic. An automobile engine valve is manufactured by an extrusion process and by near-net shape forming, cutting, and grinding. In the manufacture of tungsten bonded ion gun parts by the pulse discharge sintering method, sufficiently high strength is obtained. (NEDO)

  6. FY 1998 annual report on the development of plasma-aided surface treatment processes by in-situ controlling (second year); 1997 nendo in-situ seigyo ni yoru plasma riyo hyohi shori process no kaihatsu seika hokokusho (dai 2 nendo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This R and D project is aimed at stable production of high-quality, important machine members, which are difficult to sufficiently achieve the required properties by a single material, by carburization while minimizing use of expensive alloy metals, where high-temperature carburizing time is reduced by a plasma-aided system to save energy, and, at the same time, the conventional oil-hardening system is replaced by a He gas cooling/recycling system to solve the environmental problems involved in the former. The exhaust gases released from the plasma-aided system are adequately treated to prevent the problems caused thereby. The conditions of the plasma itself and treated surfaces are sensed in-situ, and the data are fed back to the process controlling system, to keep the treated object stable and high in quality, while minimizing energy consumption. The FY 1998 efforts were directed to studies on methods for sensing the plasma and treated surfaces, and specifications of a mini-plant for the demonstration tests, and to collection of characteristic data for development of some new products to be produced. (NEDO)

  7. Le Gaz Naturel Véhicule Natural Gas for Vehicles

    Directory of Open Access Journals (Sweden)

    De Chauveron S.

    2006-11-01

    Full Text Available Cet article présente le GNV (Gaz Naturel Véhicule. Le GNV a en effet de sérieux atouts, à la fois comme carburant de substitution et comme carburant propre. Ces atouts sont aussi bien économiques que techniques. La première partie est consacrée aux enjeux du développement du GNV. Les premiers pays utilisateurs ont été ceux qui disposent sur leur sol de ressources de gaz naturel. Aujourd'hui, alors que de nombreux pays doivent faire face à l'inquiétude croissante relative à l'augmentation de la pollution urbaine, le gaz naturel apparaît également comme un carburant propre, permettant de réduire rapidement les émissions de polluants des véhicules. Dans une deuxième partie, nous donnons une description technique sommaire des stations GNV et des véhicules GNV. Il s'agit de familiariser le lecteur avec les quelques spécificités techniques du GNV, par rapport à l'essence et au gazole. On constatera d'ailleurs que les technologies GNV sont très proches des technologies classiques. Enfin, la dernière partie est consacrée aux actions en cours, qui permettront le développement du GNV en France et en Europe : programmes de recherche, réduction des coûts de la filière, actions réglementaires, communication, etc. This article presents compressed natural gas for vehicles (CNG, which can provide considerable advantages both as an alternative fuel and as a clean fuel. These assets are not only economic but also technical. The first part deals with what is at stake in developing natural gas as a motor fuel. The first countries to use CNG were those with natural gas resources in their subsoil. Today, with a large number of countries having to cope with growing concern about increasing urban pollution, natural gas is also seen as a clean fuel that can help cut vehicle pollutant emissions dramatically. In the second part a brief technical description is given of CNG stations and vehicles, with the aim of acquainting the reader with

  8. Alimentation des moteurs en mélange homogène pauvre Feeding Homogeneous Lean Mixtures to Engines

    Directory of Open Access Journals (Sweden)

    Rayna B.

    2006-11-01

    Full Text Available Les études effectuées dans le cadre de plusieurs conventions de recherche entre l'Institut de Recherche des Transports (IRT et l'Institut Français du Pétrole (IFP associé à d'autres organismes industriels (Régie Nationale des Usines Renault (RNUR, Solex... ont permis a de caractériser l'influence de la préparation physique du mélange air-carburant sur le fonctionnement de moteurs monocylindre et multicylindre. L'effet sur le rendement d'inégalités de richesse entre les cylindres a été estimé à l'aide d'un modèle mathématique de simulation du moteur à allumage commandé ; b d'analyser les défauts inhérents à certains systèmes d'alimentation actuels et d'expérimenter des techniques différentes de formation du mélange carburé (car-burateur à dépression constante, pulvérisation pneumatique du carburant. Les résultats obtenus ont montré notamment que des améliorations ne peuvent résulter que d'un aménagement d'ensemble de tous les éléments du circuit d'admission Investigations carried out under thé terms of several research agreements involving Institut de Recherche des Transports (IRT and Institut Français du Pétrole (IFP associated with other industrial organizations (Régie Nationale des Usines Renault (RNUR, Solex served ta a Characterize thé influence of thé physical preparation of thé air/fuel mixture on thé operating of single-cylinder and multicylinder engines. The effect on thé efficiency of unequal air/fuel ratios among thé cylindres was evaluated by a mathematical model used ta simulate a spark-ignition engine. b Analyze thé inhérent defects of some fuel-supply systems now used and ta experiment with différent techniques of mixture preparation (constant depression car-burettor, pneumatic fuel spraying. The results obtained show, in particulor, that improvements con be produced only by redesigning all thé parts of thé fuel-supply circuit.

  9. Etude expérimentale du cliquetis à haut régime Experimental Study of Hight-Speed Knocking

    Directory of Open Access Journals (Sweden)

    Guibet J. C.

    2006-11-01

    Full Text Available La première partie de cette étude a consisté à observer et à tenter d'interpréter l'action des conditions de fonctionnement et des paramètres de réglage du moteur sur la tendance au cliquetis à haut régime. On a montré ensuite que les différentes familles chimiques d'hydrocarbures qui constituent les carburants classiques présentent chacune un comportement bien distinct en fonction de la richesse, de la pression et de la température d'admission. On a également étudié l'influence de la teneur en plomb du carburant et du type d'alkyle de plomb employé. Quelques expériences ont été effectuées afin de déterminer l'incidence d'une réduction de un point de taux de compression sur l'exigence en octane à haut régime et sur l'action des caractéristiques de composition du carburant. Enfin, en déterminant le pourcentage de cycles soumis au cliquetis pour différentes avances à l'allumage, il a été possible de fournir quelques indications permettant de mieux caractériser l'intensité du phénomène. The first part of this study consists in observing and trying to interpret the effect of operating conditions and engine tuning parameters on the tendency for high-speed knocking to appear. The different chemical families of the hydrocarbons making up conventional fuels are shown to each have a quite different behavior depending on the fuel-air equivalency ratio and the admission pressure and temperature. The influence of the lead content in the fuel and of the type of lead alkyl used is also studied. Some experiments were performed to determine the influence of a one-point reduction in the compression ratio on the high-speed octane requirement and on the effect of fuel composition properties. Lastly, by determing the percentage of cycles accompanied by knocking at different spark advances, some indications were found for better characterizing the intensity of the phenomenon.

  10. Researches on vanadium and its compounds; Recherches sur le Vanadium et ses composes

    Energy Technology Data Exchange (ETDEWEB)

    Morette, Andre

    1937-06-03

    In this research thesis, the author proposes a new study of the action of some reduction agents on two groups of vanadium compounds, oxides and chlorides. Thus, he reports the study of the circumstances of reduction of vanadium oxides by carbon and of vanadium carburization from these compounds. He also reports the determination of the composition of vanadium melts obtained at high temperatures (either in a vacuum furnace or with an electric arc furnace). In order to determine in which conditions the processing of vanadium oxides could produce the pure metal, the author studied the action of calcium and magnesium on the vanadium pentoxide and trioxide. The second part of the thesis addresses the preparation of pure vanadium from vanadium anhydride chlorides. Then, the author reports the development of processes which could easily produce powdered vanadium [French] Nous nous sommes propose de reprendre l'etude de l'action de quelques reducteurs sur les deux groupes de composes du vanadium, oxydes et chlorures. Nous avons ete ainsi amene a preciser les circonstances de la reduction des oxydes de vanadium par le carbone et de la carburation du vanadium a partir de ceux-ci, puis a determiner la constitution des fontes de vanadium obtenues a haute temperature, soit au four a vide, soit au four a arc. D'autre part, en vue de determiner dans quelles conditions le traitement des oxydes de vanadium pourrait conduire au metal pur, nous avons repris et complete des travaux anterieurs concernant l'action du calcium et du magnesium sur le pentoxyde ou eventuellement le trioxyde de vanadium. Une seconde partie de notre these a ete consacree a la preparation du vanadium pur a partir des chlorures anhydres de vanadium. Nous nous sommes attache a trouver le mode operatoire le plus favorable pour l'obtention de chacun d'eux. Il nous a ete donne ainsi l'occasion de preciser certaines de leurs proprietes physiques et chimiques. Puis, a la suite d'essais systematiques, nous avons

  11. Mechanisms of oxidation of alloy 617 in helium-carbon monoxide-carbon dioxide environment with varying carbon and oxygen potentials

    Science.gov (United States)

    Kumar, Deepak

    The objective of this research was to determine the mechanism of decarburization and carburization of the alloy 617 by determining the gas-metal reactions. Binary gas mixtures containing only CO and CO2 as impurities were chosen to circumvent the complications caused by impurities H2, H2O, and CH4, normally, present in helium in addition to CO and CO2; and oxidation tests were conducted between 850°C-1000°C in six environments with CO/CO2 ratio varying between 9 and 1272. A critical temperature corresponding to the equilibrium of the reaction 2Cr+3CO↔Cr2O3+3Csolut ion was identified. Below the critical temperature the alloy reacted with CO resulting in formation of a stable chromia film and carburization, whereas, above the critical temperature the decarburization of the alloy occurred via reaction between the chromia film and carbon in the alloy producing CO and Cr. In environment with CO/CO2 of 9 the critical temperature was between 900°C and 950°C, whereas, in environment with CO/CO 2 ratio higher than 150, it was greater than 1000°C. The decarburization of the alloy occurred via two reactions occurring simultaneously on the surface: 2Cr+3/2O2→Cr2 O3, Cr2O3+3Csolution→ 2Cr+3CO. At 1000°C, the rate liming step was the formation of chromia which prevented the growth of chromia film until the carbon in the sample was depleted. The time taken for this to occur was 300h. The carburization of the alloy resulted in the formation of mixed Cr 2O3 and Cr7C3 surface scale. The Cr 7C3 was a metastable phase which nucleated due to preferential adsorption of carbon on the chromia surface. The Cr7C3 precipitates coarsened at the gas/scale interface via outward diffusion of Cr cations through the chromia scale until the activity of Cr at the reaction site fell below a critical value. Decrease in activity of Cr at the carbide/chromia interface triggered a reaction between chromia and carbide: Cr2O3+Cr7C3 →9Cr+3CO. The CO so produced was transported through the

  12. Aluminide protective coatings on high–temperature creep resistant cast steel

    Directory of Open Access Journals (Sweden)

    J. Kubicki

    2009-10-01

    Full Text Available This paper presents the results of research on aluminide protective coatings manufactured on high–temperature creep resistant cast steel. The main purpose of these coatings is protection against the high temperature corrosion, especially at high carburizing potential atmosphere. Coatings were obtained on cast steel type G–XNiCrSi36–18 with the following methods: pack cementation, paste method, cast method and slurry cementation. The phase composition, thickness and morphology of coatings were determined. Coatings capacity of carbon diffusion inhibition and thermal shocks resistance of coatings were determined with different methods. It was found, that all of the coatings reduce carbon diffusion in different degree and all coatings liable to degradation in consequence cracking and oxidation. Coating life time is mainly dependent on morphology, phase composition and service condition (thermal shocks first of all.

  13. Effect of various lanthanum sol-gel coatings on the 330Cb (Fe-35Ni-18Cr-1Nb-2Si) oxidation at 900 deg. C

    Energy Technology Data Exchange (ETDEWEB)

    Buscail, H., E-mail: buscail@iut.u-clermont1.fr [Clermont Universite- LVEEM, 8 rue J.B. Fabre, BP 219, 43006 Le Puy en Velay (France); Issartel, C.; Riffard, F.; Rolland, R.; Perrier, S. [Clermont Universite- LVEEM, 8 rue J.B. Fabre, BP 219, 43006 Le Puy en Velay (France); Fleurentin, A. [CETIM, 52 av Felix Louat, BP 80067, 60304 Senlis (France); Josse, C. [L' ICB UMR5209 CNRS, BP 47870, 21078 Dijon (France)

    2011-11-01

    The influence of a lanthanum sol-gel coating on the oxide scale adherence has been studied during the 330Cb (Fe-35Ni-18Cr-1Nb-2Si) oxidation at 900 deg. C, in air. The alloy oxidation is performed in order to generate a protective chromia scale acting as a good barrier against carburization. Argon annealing of lanthanum sol-gel coatings have been performed at various temperatures in order to find the best conditions to insure the scale adherence. Kinetic results show that lanthanum sol-gel coatings lead to a lower oxidation rate compared to blank specimens. Thermal cycling tests on lanthanum the sol-gel coated specimen show that the oxide scale formed at 900 deg. C, in air, is adherent.

  14. Environmental transmission electron microscopy investigations of Pt-Fe2O3 nanoparticles for nucleating carbon nanotubes

    DEFF Research Database (Denmark)

    He, Maoshuai; Jin, Hua; Zhang, Lili

    2016-01-01

    electron microscopy, restructuring of the acorn-like Pt-Fe2O3 nanoparticles at reaction conditions is investigated. Upon heating to reaction temperature, ε-Fe2O3 is converted to β-Fe2O3, which can be subsequently reduced to metallic Fe once introducing CO. As Pt promotes the carburization of Fe, part...... of the metallic Fe reacts with active carbon atoms to form Fe2.5C instead of Fe3C, catalyzing the nucleation of carbon nanotubes. Nanobeam electron diffraction characterizations on SWCNTs grown under ambient pressure at 800 °C demonstrate that their chiral angle and diameter distributions are similar to those...

  15. High burnup, high power irradiation behavior of helium-bonded mixed carbide fuel pins

    International Nuclear Information System (INIS)

    Levine, P.J.; Nayak, U.P.; Boltax, A.

    1983-01-01

    Large diameter (9.4 mm) helium-bonded mixed carbide fuel pins were successfully irradiated in EBR-II to high burnup (12%) at high power levels (100 kW/m) with peak cladding midwall temperatures of 550 0 C. The wire-wrapped pins were clad with 0.51-mm-thick, 20% cold-worked Type 316 stainless steel and contained hyperstoichiometric (Usub(0.8)Pusub(0.2))C fuel covering the smeared density range from 75-82% TD. Post-irradiation examinations revealed: extensive fuel-cladding mechanical interaction over the entire length of the fuel column, 35% fission gas release at 12% burnup, cladding carburization and fuel restructuring. (orig.)

  16. Measurement of carbon activity in sodium and steel and the behaviour of carbon-bearing species

    International Nuclear Information System (INIS)

    Rajendran Pillai, S.; Ranganathan, R.; Mathews, C.K.

    1988-01-01

    Carburization or decarburization of structural materials in a sodium system depends on the local differences in carbon activity. The behaviour of carbon-bearing species in sodium influences its carbon activity. In order to understand the behaviour of carbon in these systems, an electrochemical carbon meter was fabricated in our laboratory. The original version of this meter was capable of operating in the temperature range of 850-980 K. Studies are carried out to extend this lower limit of temperature. Employing the carbon meter, experiments were carried out to understand the behaviour of carbon-bearing species. Gas equilibration experiments were also carried out with the same view. A new method for measuring the carbon activity in steels are described which employs the carbon meter. A review on these investigations and the conclusions reached on the behaviour of carbon in fast reactor loops are described

  17. Effect of HTGR helium on fatigue and creep properties of 2 1/4Cr-1Mo steel

    International Nuclear Information System (INIS)

    Kurumaji, T.; Yamazaki, H.; Kudo, A.

    1982-01-01

    Low cycle fatigue and creep tests have been carried out on 2 1/4Cr-1Mo steel (candidate steel for VHTR reactor pressure vessel) in helium environment containing 200 approx. 300 μatm of H 2 , 100 approx. 150 μatm CO, 7 approx. 10 μatm CH 4 , 7 approx. 10 μatm CO 2 and 1 μatm H 2 O (JAERI B Helium). Fatigue life in helium environment was longer than that in air at 450 0 C. This results can be explained by supposing that oxidation at the crack tip causes the wedge effect to promote crack propagation in air. On the otherhand, creep rupture strength showed no significant difference in both helium and air. Equivalent creep rupture strength in both helium and air may be due to the fact that detrimental internal oxidation and carburization or decarburization hardly occur at 400 approx. 450 0 C

  18. Measurement of the activity coefficient of carbon in steels in liquid sodium

    International Nuclear Information System (INIS)

    Surville, G.

    1983-06-01

    In sodium cooled fast reactors carbon is both a carbon impurity and element of structural materials. Carbon transfert through liquid sodium can produce carburization or decarburization of structural materials. Carbon content in sodium is determined with thin foils of austenitic alloys, when equilibrium is reached thermodynamic activity of carbon in sodium is deduced from carbon activity in alloys. Studied alloys are FeMn 20%, FeNi 30%, Z2CN 18-10 and Z3CND17-13. Carbon activity of alloys in sodium was between 5.10 -3 and 10 -1 at 600 and 650 0 C. Calibration was obtained with the alloys FeNi 30% in gaseous mixtures He-CO-CO 2 of known activity [fr

  19. STUDY ON REDUCING AND MELTING BEHAVIOR OF MILL SCALE/PETROLEUM COKE BLEND

    Directory of Open Access Journals (Sweden)

    Bruno Deves Flores

    2015-07-01

    Full Text Available Self-reducing tests were carried out under isothermal and non-isothermal condition in a muffle furnace, aiming to assess the reduction and melting of a self-reducing blend of mill scale and petroleum coke (85-15% in weight. The products obtained were analyzed by mass loss and wet analysis. Further investigations for the products from the non-isothermal condition were done by X-ray diffraction, nude eye inspection and carbon analyzer. It was observed that mass loss fraction and metallization degree are directly related and both increase with time and temperature. In the non-isothermal maximum mass loss was achieved in 8 minutes, reaching metallization degrees above 90%. It was observed that the reduction of iron oxide occurs mainly in solid state and the smelting of the samples is directly related to the iron carburization process. Thus, the use of self-reducing mixtures shows a possible way to recycle mill scale.

  20. Fiscal 2000 collection of manuscripts for technology development committee on hydrogen energy and the like; 2000 nendo suiso energy nado kanren gijutsu kaihatsu iinkai yokoshu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-07

    The subjects listed in the collection are (1) the research and development of international clean energy system technology utilizing hydrogen (WE-NET - World Energy Network), including the outline of the project as a whole; research on system evaluation; research and development of safety measures; development of technologies for liquid hydrogen transportation and storage; research on low-temperature materials; development of hydrogen supply station and hydrogen-driven automobile system; development of supply station for hydrogen produced by electrolysis of water; development of hydrogen fuel system; development of hydrogen production technology; development of hydrogen absorbing alloys for dispersed hydrogen transportation and storage; development of polymer electrolyte fuel cell fed with pure hydrogen; and the development of power generation technology, (2) the development of closed type high-efficiency turbine technology capable of carbon dioxide recovery, and (3) the development of frontier technology of carburation using sensible heat in coke oven gas. (NEDO)

  1. A contribution to the study of the mixed uranium-plutonium mono-carbides containing small quantities of zirconium

    International Nuclear Information System (INIS)

    Bocker, S.

    1970-03-01

    We have studied a mixed monocarbide, type (U,Pu)C, containing small additions of zirconium for the application as a fast neutron reactor fuel. A preliminary study was conducted on the (U,Zr)C monocarbide (Report CEA-R-3765(1). It was found that small additions of zirconium to the uranium-plutonium monocarbide improve a number of properties such as atmospheric corrosion, the hardness, and particularly the compatibility with 316 stainless steel. However, properties such as the coefficient of expansion and the melting point are only slightly changed. The relative percentage of Pu/U+Pu in the monocarbide was fixed at 20 per cent. Two processes of fabrication were employed: casting in an arc furnace, sintering, carried out after having the hydrides of the metals carburized. The metallurgical results indicate, that the above mentioned fuel might be of interest for fast neutron reactor application. (author) [fr

  2. Principes et application de la digestion anaérobie pour la production d'énergie

    OpenAIRE

    Bernet, Nicolas

    2015-01-01

    La digestion anaérobie est un processus naturel par lequel la matière organique est transformée en un biogaz qui contient environ 2/3 de méthane et 1/3 de dioxyde de carbone. Elle résulte de l’activité d’un écosystème microbien anaérobie complexe. Le biogaz est une source d’énergie qui peut être utilisée directement en remplacement du gaz naturel, pour produire de la chaleur et de l’électricité par cogénération ou encore comme carburant pour véhicules. Ainsi, la domestication par l’homme de c...

  3. Modernization and efficiency of heat treatment and heating up plants; Modernisierung und Effizienz von Thermoprozessanlagen

    Energy Technology Data Exchange (ETDEWEB)

    Wendt, Peter [LOI Thermprocess GmbH, Essen (Germany); Kuehn, Friedhelm [Ingenieurbuero fuer Waermebehandlung, Industrieoefen und Energieberatung, Muelheim (Germany)

    2010-10-15

    A goal of this contribution is to show, using examples of the thermal heat treatment industry and the thermal processing units used there (Beltype plants, routary hearth, walking hearth, walking beam, pusher type furnaces and gas carburizing plants as well as case hardening plants), which increases in efficiency within and outside of the actual thermal treatment process and the necessary thermal processing units for the order are available today. From the possibilities of the reduction of energy employment resulting from that, a high potential for the discharge of the environment can be derived. The economic effect concerning energy employment and saving possibilities will also be considered. Concluding, examples of case-hardening show which variants of a change of process present themselves partially in the future, in order to achieve substantial production increases and thus energy cost reductions. (orig.)

  4. Generador oxihidrógeno para motor de combustión interna

    OpenAIRE

    Cebrián López, Héctor

    2014-01-01

    La pujada de preus dels carburants per la crisi econòmica actual motiva a investigar fonts d'energia alternatives. Les fonts d'energia convencionals com els combustibles fòssils són contaminants i costoses, i l'hidrogen generat a través de l'electròlisi de l'aigua és una solució ecològica i econòmica. En aquest projecte es dissenya un generador d'oxihidrógeno i s'estudien els efectes de l'addició d'aquest gas en 2 motors de combustió interna de 2 temps i 50 cc. Els resultats indiquen que, ...

  5. High temperature corrosion in the service environments of a nuclear process heat plant

    International Nuclear Information System (INIS)

    Quadakkers, W.J.

    1987-01-01

    In a nuclear process heat plant the heat-exchanging components fabricated from nickel- and Fe-Ni-based alloys are subjected to corrosive service environments at temperatures up to 950 0 C for service lives of up to 140 000 h. In this paper the corrosion behaviour of the high temperature alloys in the different service environments will be described. It is shown that the degree of protection provided by Cr 2 O 3 -based surface oxide scales against carburization and decarburization of the alloys is primarily determined not by the oxidation potential of the atmospheres but by a dynamic process involving, on the one hand, the oxidizing gas species and the metal and, on the other hand, the carbon in the alloy and the oxide scale. (orig.)

  6. Determination of constant of chemical reaction rate in the process of steel treatment in the endothermal atmosphere

    International Nuclear Information System (INIS)

    Gyulikhandanov, E.L.; Kislenkov, V.V.

    1978-01-01

    The high-temperature method was applied to measuring a relative variation in the electrical resistance of a thin steel foil prepared from the 12KhN3A, 18Kh2N4VA, 20KhGNR, and 20Kh3MVF steels during its carburization and decarburization, and determined was the temperature dependence of the reaction rate of the interaction of the endothermal atmosphere of different compositions with the analloyed γ-Fe. A connection has been established between the reaction rate constant and the thermodynamic activity of carbon in the alloyed austenite at the temperature of about 925 deg C, corresponding to the cementation temperature. This provides the quantitative estimation of the above value for any alloyed steels and with the presence of numerical values of diffusion coefficients; this also enables one to carry out an accurate calculation of the distribution of carbon throughout the depth of a layer when effecting the cementation in the endothermal atmosphere

  7. Finishing aeronautical planetary herringbone gear wheels in container vibrating smoothing machine

    Directory of Open Access Journals (Sweden)

    Jacek MICHALSKI

    2015-12-01

    Full Text Available The paper presents the technological process of abrasive-chemical machining wheel bearing surface of the cylindrical herringbone gears planetary gear in vibrating container smoothing machine according to Isotropic Finishing ISF® technology of the REM Chemicals Inc. company. Gear wheels are made of stainless Pyrowear 53 and subjected to carburizing, hardening, cold working and low tempering. The change in value of deviation indicators for the kinematic accuracy, smoothness and geometric structure of the machined surfaces of the gear teeth after smoothing compared with the contoured grinding were analyzed. The findings are different a characteristic performance on the surface of the tooth side along the outline, especially with a higher value at the head of the tooths. This creates a need for appropriate modification of the lateral surface of the teeth in the process of contoured grinding. The results of the mechanical strength of the samples gear wheel after the smoothing process and evaluating the hydrogen embrittlement are presented.

  8. Measurement of carbon activity of sodium using nickel tabs and the Harwell Carbon Meter - Preliminary experience

    International Nuclear Information System (INIS)

    Blundell, A.; Thorley, A.W.

    1980-01-01

    Carbon can have an important effect on the mechanical properties of certain constructional materials likely to be used in the LMFBRs. Transfer of carbon will occur between the metal and the sodium at any particular location to bring the chemical potential of carbon in both components to the sam: value. Thus, in a mixed system containing austenitic stainless steel and unstabilized ferritic steel, carbon could be transferred by the sodium from the high carbon activity ferritic to the lower activity austenitic steel. Loss of carbon from the unstabilized ferritic steel leads to a weaker, more ductile material, while carburization of the stainless steel could lead to its embrittlement. Similarly carbon entering the coolant in the form of oil from leaking mechanical pumps could have similar effects on the mechanical property of stainless steels. In the light of these possibilities it is essential to measure the carbon activity of the sodium so that its effect on materials properties can be predicted

  9. On the kinetics of high-temperature interaction of tungsten with light hydrocarbons

    International Nuclear Information System (INIS)

    Kharatyan, S.L.; Chatilyan, A.A.; Merzhanov, A.G.

    1989-01-01

    Comparative investigation of tungsten carbidizing treatment in ethylene, acetylene and methane media at T=1750-2500 deg C and p=2-10 Torr is carried out by the electrothermographical method. In all cases interaction is shown to proceed in stages due to step-by-step formation of carbide phases of tungsten W 2 C and WC as well as pyrocarbon. It is established that efficiency of carbidizing treatment is turned out to be maximum in methane medium in spite of great absolute values of ethylene and acetylene pyrolysis velocities on the surface of tungsten carbides in comparison with methane. Criterion of carburizing capability of hydrocarbous relatively to a metal is given on the basis of the results obtained

  10. Measurement of carbon activity of sodium using nickel tabs and the Harwell Carbon Meter - Preliminary experience

    Energy Technology Data Exchange (ETDEWEB)

    Blundell, A; Thorley, A W [UKAEA, Risley, Warrington, Cheshire (United Kingdom)

    1980-05-01

    Carbon can have an important effect on the mechanical properties of certain constructional materials likely to be used in the LMFBRs. Transfer of carbon will occur between the metal and the sodium at any particular location to bring the chemical potential of carbon in both components to the sam: value. Thus, in a mixed system containing austenitic stainless steel and unstabilized ferritic steel, carbon could be transferred by the sodium from the high carbon activity ferritic to the lower activity austenitic steel. Loss of carbon from the unstabilized ferritic steel leads to a weaker, more ductile material, while carburization of the stainless steel could lead to its embrittlement. Similarly carbon entering the coolant in the form of oil from leaking mechanical pumps could have similar effects on the mechanical property of stainless steels. In the light of these possibilities it is essential to measure the carbon activity of the sodium so that its effect on materials properties can be predicted.

  11. High temperature crevice corrosion of heat-resistant Ni-base alloy in the simulated HTR helium

    International Nuclear Information System (INIS)

    Kiuchi, Kiyoshi; Kondo, Tatsuo

    1980-03-01

    Interaction between a Ni-base heat-resistant alloy and the simulated HTR primary coolant environment was examined with emphasis on the reactions inside narrow crevice gaps. A new method using Mo crevice cells was developed to obtain reproducible quantitative results. The test environment was characterized by the low oxidizing species as trace gaseous impurities. Series of sequential phenomena were observed: i.e. the preferential consumptions of oxidizing species in the outer part of the crevice, followed by the lack of oxide film and the resultant extensive carburization further inside the crevice. A model on the possible phenomena occurring at tips of the cracks formed during creep or fatigue tests and low flow rate portions in the reactor primary circuit as well. The feasibility of the interpretation was checked referring to the existing numerical formula and using the experimental results obtained parameters. Calculations reproduced penetration curves of the Cr- oxidation with reasonable accuracy. (author)

  12. End Uses Mechanical Properties Settled By The Modified Sintering Conditions Of The Metal Injection Molding Process

    International Nuclear Information System (INIS)

    Marray, Tarek; Jaccquet, Philippe; Moinard-Checot, Delphine; Fabre, Agnes; Barrallier, Laurent

    2011-01-01

    Most common mechanical applications require parts with specific properties as hard faced features. It is well known that treating parts under suitable atmospheres may improve hardness and strength yield of steels. Heat treatment process and more particularly thermo-chemical diffusion processes (such as carburizing or its variation: carbonitriding) can be performed to reach the industrial hardness profile requirements. In this work, a low-alloyed steel feedstock based on water soluble binder system is submitted to the MIM process steps (including injection molding, debinding and sintering). As-sintered parts are then treated under a low pressure carbonitriding treatment. This contribution focuses on preliminary results such as microstructural analyses and mechanical properties which are established at each stage of the process to determine and monitor changes.

  13. Measurement of carbon activity in sodium by Fe-Mn 20% alloy, and by strainless austenitic steel 304L and 316L

    International Nuclear Information System (INIS)

    Oberlin, C.; Saint Paul, P.; Baque, P.; Champeix, L.

    1980-01-01

    Precise knowledge of carbon activity in sodium used as coolant in fast breeder reactors, is essential for continuous survey of carburization-decarburization processes. Carbon activity can be periodically surveyed by measuring the carbon concentration or by hot trap like metal alloy strip placed in sodium loop. In fact, in equilibrium, activity of carbon in sodium is equal to the activity in metal alloy. Thus if the relation between concentration of carbon and it activity in the alloy is known, it is possible to estimate the activity of carbon in sodium. Materials to be used should have high solubility in carbon at the needed temperature. They should quickly attain equilibrium with sodium and they should not contain impurities that can affect the results. Materials chosen according to these criteria were Fe-Mn 20%, stainless austenitic steel AISI 304L and 316L

  14. High temperature oxidation and corrosion behavior of Ni-base superalloy in He environment

    International Nuclear Information System (INIS)

    Lee, Gyoeng Geun; Park, Ji Yeon; Jung, Su jin

    2010-11-01

    Ni-base superalloy is considered as a IHX (Intermediate Heat Exchanger) material for VHTR (Very High Temperature Gas-Cooled Reactor). The helium environment in VHTR contains small amounts of impure gases, which cause oxidation, carburization, and decarburization. In this report, we conducted the literature survey about the high temperature behavior of Ni-base superalloys in air and He environments. The basic information of Ni-base superalloy and the basic metal-oxidation theory were briefly stated. The He effect on the corrosion of Ni-base superalloy was also summarized. This works would provide a brief suggestion for the next research topic for the application of Ni-base superalloy to VHTR

  15. Mitigation technologies for damage induced by pressure waves in high-power mercury spallation neutron sources (1). Material surface improvement

    International Nuclear Information System (INIS)

    Naoe, Takashi; Futakawa, Masatoshi; Wakui, Takashi; Kogawa, Hiroyuki; Shoubu, Takahisa; Takeuchi, Hirotsugu; Kawai, Masayoshi

    2008-01-01

    Liquid-mercury target systems for MW-class spallation neutron sources are being developed in the world. Proton beams will be used to induce the spallation reaction. At the moment the proton beam hits the target, pressure waves are generated in the mercury because of the abrupt heat deposition. The pressure waves interact with the target vessel leading to negative pressure that may cause cavitation along the vessel wall. Localized impacts by microjets and/or shock waves that are caused by cavitation bubble collapse impose pitting damage on the vessel wall. Bubble collapse behavior was observed by using a high-speed video camera, as well as simulated numerically. Localized impact due to cavitation bubble collapse was quantitatively estimated through comparison between numerical simulation and experiment. A novel surface treatment technique that consists of carburizing and nitriding processes was developed and the treatment condition was optimized to mitigate the pitting damage due to localized impacts. (author)

  16. Pollution provoquée par le moteur Diesel. Niveaux d'émission. Comparaison avec le moteur à allumage commandé Pollution Caused by Diesel Engines. Emission Levels. Comparison with Spark-Ignition Engines

    Directory of Open Access Journals (Sweden)

    Degobert P.

    2006-11-01

    Full Text Available A partir de l'analyse des différences de modes de combustion allumage commandé et Diesel , cet article compare et explique la nature et les niveaux des différents polluants émis en fonction de leurs mécanismes de formation. Les facteurs d'action au niveau moteur sont examinés, ainsi que l'influence du carburant utilisé. Based on an analysis of the difference between spark-ignition and diesel combustion modes, this article compares and explains the nature and levels of different pollutants emitted as a function of their formation mechanisms. The action factors at the engine> level are examined together with the influence of the fuel used.

  17. PROCEDE DE GESTION DENERGIE DUN VEHICULE ELECTRIQUE

    OpenAIRE

    Granato , Giovanni; Zidani , Hasnaa

    2013-01-01

    L'invention se rapporte à un procédé de gestion d'énergie pour un véhicule électrique, comprenant un calculateur, un moteur électrique, une batterie électrique et un moteur thermique d'appoint utilisant un carburant et conçu pour aider la batterie à faire fonctionner ledit moteur électrique. La principale caractéristique d'un procédé selon l'invention est qu'il comprend les étapes suivantes : - une étape de sélection d'un trajet compris entre un point de départ et un point de destination, - u...

  18. Influence of sodium evnironment on the uniaxial tensile behavior of titanium modified type 316 stainless steel

    International Nuclear Information System (INIS)

    Natesan, K.; Chopra, O.K.; Kassner, T.F.

    1978-01-01

    True stress-true strain tensile data have been obtained for titanium modified type 316 stainless steel in the solution annealed condition and after exposure to a flowing sodium environment at temperature of 700, 650, 600 and 550 0 C. The specimens were exposed to sodium for times between 120 and 5012 h to produce carbon penetration depths in the range 0.05-0.30 mm. The Voce equation was used to describe tensile flow curves for plastic strains above 0.005. The results showed that, when compared with solution annealed specimens, the tensile flow behavior of the sodium exposed specimens is characterized by a higher strain hardening rate, which decreases rapidly as the flow stress increases. The loss in tensile ductility of the material due to carburization in sodium environment was found to be minimal. (Auth.)

  19. OPTIMIZATION OF HEATING OF GEAR WHEEL USING NUMERICAL MODELING

    Directory of Open Access Journals (Sweden)

    Soňa Benešová

    2013-09-01

    Full Text Available Successful heat treating and carburizing of gear wheels for wind turbine gear boxes requires that plastic deformation in the wheel is minimized. Numerical modeling using the DEFORM software was aimed at exploring the effects of the base, on which the gear wheel rests during heating, on the heating process. Homogeneous heating was assumed. It was found that the base heats up more quickly than the workpiece. It is the consequence of the base's shape and volume. As a result, the base expands and slides against the wheel, predominantly at the first heating stage. Later on, it prevents the gear wheel from expanding, causing plastic deformation in the wheel. The findings were used for designing new heating schedules to minimize these undesirable interactions and to reduce the plastic deformation to a negligible magnitude. In addition, this paper presents an example of a practical use of numerical modeling in the DEFORM software.

  20. OPTIMIZATION OF HEATING OF GEAR WHEEL USING NUMERICAL MODELING

    Directory of Open Access Journals (Sweden)

    Sona Benesova

    2013-05-01

    Full Text Available Successful heat treating and carburizing of gear wheels for wind turbine gear boxes requires that plastic deformation in the wheel is minimized. Numerical modeling using the DEFORM software was aimed at exploring the effects of the base, on which the gear wheel rests during heating, on the heating process. Homogeneous heating was assumed. It was found that the base heats up more quickly than the workpiece. It is the consequence of the base's shape and volume. As a result, the base expands and slides against the wheel, predominantly at the first heating stage. Later on, it prevents the gear wheel from expanding, causing plastic deformation in the wheel. The findings were used for designing new heating schedules to minimize these undesirable interactions and to reduce the plastic deformation to a negligible magnitude. In addition, this paper presents an example of a practical use of numerical modeling in the DEFORM software.

  1. Study on niobium carbide dispersed superconducting tapes

    Energy Technology Data Exchange (ETDEWEB)

    Wada, H; Tachikawa, K [National Research Inst. for Metals, Tokyo (Japan); Oh' asa, M [Science Univ. of Tokyo (Japan)

    1977-11-01

    Niobium carbide (NbC) dispersed superconducting tapes have been fabricated by two metallurgical processes. In the first process, Ni-Nb-C alloys are directly arc melted and hot worked in air and the NbC phase is distributed in the form of fine discrete particles. In the second process, Ni-Nb and Ni-Nb-Cu alloys are arc melted, hot worked and subjected to solid-state carburization. NbC then precipitates along the grain boundaries, forming a network. The highest superconducting transition temperature attained is about 11 K. Taken together with the lattice parameter measurement, this indicates that NbC with a nearly perfect NaCl structure is formed in both processes. Measured values of the upper critical field, the critical current density and the volume fraction of the NbC phase are also discussed.

  2. Plasma assisted surface coating/modification processes: An emerging technology

    Science.gov (United States)

    Spalvins, T.

    1986-01-01

    A broad understanding of the numerous ion or plasma assisted surface coating/modification processes is sought. An awareness of the principles of these processes is needed before discussing in detail the ion nitriding technology. On the basis of surface modifications arising from ion or plasma energizing and interactions, it can be broadly classified as deposition of distinct overlay coatings (sputtering-dc, radio frequency, magnetron, reactive; ion plating-diode, triode) and surface property modification without forming a discrete coating (ion implantation, ion beam mixing, laser beam irradiation, ion nitriding, ion carburizing, plasma oxidation). These techniques offer a great flexibility and are capable in tailoring desirable chemical and structural surface properties independent of the bulk properties.

  3. Plasma assisted surface coating/modification processes - An emerging technology

    Science.gov (United States)

    Spalvins, T.

    1987-01-01

    A broad understanding of the numerous ion or plasma assisted surface coating/modification processes is sought. An awareness of the principles of these processes is needed before discussing in detail the ion nitriding technology. On the basis of surface modifications arising from ion or plasma energizing and interactions, it can be broadly classified as deposition of distinct overlay coatings (sputtering-dc, radio frequency, magnetron, reactive; ion plating-diode, triode) and surface property modification without forming a discrete coating (ion implantation, ion beam mixing, laser beam irradiation, ion nitriding, ion carburizing, plasma oxidation. These techniques offer a great flexibility and are capable in tailoring desirable chemical and structural surface properties independent of the bulk properties.

  4. Study on Damage Mechanism of Ductile Cast Iron Cooling Stave

    Science.gov (United States)

    Wang, Cui; Zhang, Jianliang; Zuo, Haibin; Dai, Bing

    The damage mechanism of ductile cast iron cooling stave applied to No.4 blast furnace of Guofeng steel was analyzed through damage investigation in details, the damage causes: high-temperature gas flow erosion, wear of burden, high-temperature ablation, carburizing damage, improper operation on blast furnace, etc. were given out both in macroscopic and microscopic views. It can be obtained from metallographic diagrams that the diameter of graphite nodules increases, the number per unit area reduces, and roundness declines, successively, from cold to hot surface, which are not conducive to stave longevity. In summary, the material for staves manufacture should be better in comprehensive mechanical properties to prolong the service life, thus making blast furnace long campaign.

  5. ASSET, An Information System for Alloy Corrosion in High Temperature Gases

    International Nuclear Information System (INIS)

    R. C. John; A. D. Pelton; A. L. Young; W. T. Thompson; I. G. Wright

    2001-01-01

    A large database for corrosion data and a corrosion prediction information system for metals and alloys corroding in high-temperature gases have been created. Corrosion data for about 75 commercial alloys, 4600 corrosion data measurements, and six million exposure hours have been compiled into an information system, ASSET. ASSET allows prediction of sound metal thickness losses for metals and alloys corroding by several common corrosion mechanisms at high-temperatures as functions of gas composition, temperature, time, and alloy. This paper presents examples of predicted metal losses of alloys corroding in standard conditions for several corrosion mechanisms expected in high-temperature gases. ASSET also provides a comprehensive capability to analyze the thermochemical interactions between alloys, corrosion products and exposure conditions. Some of the uses of the data compilation and the corrosion prediction feature are illustrated for oxidizing, sulfidizing, sulfidizing/oxidizing , and carburizing conditions

  6. High temperature materials for radioactive waste incineration and vitrification. Revision 1

    International Nuclear Information System (INIS)

    Bickford, D.F.; Ondrejcin, R.S.; Salley, L.

    1986-01-01

    Incineration or vitrification of radioactive waste subjects equipment to alkaline or acidic fluxing, oxidation, sulfidation, carburization, and thermal shock. It is necessary to select appropriate materials of construction and control operating conditions to avoid rapid equipment failure. Nickel- and cobalt-based alloys with high chromium or aluminum content and aluminum oxide/chromium oxide refractories with high chromium oxide content have provided the best service in pilot-scale melter tests. Inconel 690 and Monofrax K-3 are being used for waste vitrification. Haynes 188 and high alumina refractory are undergoing pilot scale tests for incineration equipment. Laboratory tests indicate that alloys and refractories containing still higher concentrations of chromium or chromium oxide, such as Inconel 671 and Monofrax E, may provide superior resistance to attack in glass melter environments

  7. Internal chlorination of Ni-Cr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Berztiss, D.; Hennesen, K.; Grabke, H.J. [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    1998-12-31

    In contrast to internal oxidation, sulfidation and carburization, very little information is available regarding internal chlorination, especially diffusion of chlorine in metallic alloys. This paper describes results of experiments on Ni-Cr alloys (<10 wt% Cr) exposed in an atmosphere containing radioactive HCl. The diffusion of chlorine in the alloy can be determined by measurement of residual {beta}-activity from the sample surface. Successively thin layers (0.5-10 {mu}m) of the alloy were removed by lapping and the surface activity was measured to obtain a depth profile. Both single and polycrystalline materials were tested. Through this work it should be determined if there is in fact solubility and diffusion of chlorine in Ni-based alloys as some authors have proposed or if the ingress of chlorine is mainly a grain boundary phenomenon. (orig.)

  8. Effect of Plastic Pre-straining on Residual Stress and Composition Profiles in Low-Temperature Surface-Hardened Austenitic Stainless Steel

    DEFF Research Database (Denmark)

    Bottoli, Federico; Christiansen, Thomas Lundin; Winther, Grethe

    2016-01-01

    The present work deals with the evaluation of the residual stress profiles in expanded austenite by applying grazing incidence X-ray diffraction (GI-XRD) combined with successive sublayer removal. Annealed and deformed (εeq=0.5) samples of stable stainless steel EN 1.4369 were nitrided...... or nitrocarburized. The residual stress profiles resulting from the thermochemical low-temperature surface treatment were measured. The results indicate high-residual compressive stresses of several GPa’s in the nitrided region, while lower-compressive stresses are produced in the carburized case. Plastic...... deformation in the steel prior to thermochemical treatment has a hardly measurable influence on the nitrogen-rich zone, while it has a measurable effect on the stresses and depth of the carbon-rich zone....

  9. Wear properties of metal ion implanted 4140 steel

    Energy Technology Data Exchange (ETDEWEB)

    Evans, P.J. (Applications of Nuclear Physics, Ansto, Private Mail Bag 1, Menai, NSW 2234 (Australia)); Paoloni, F.J. (Department of Electrical and Computer Engineering, University of Wollongong, GPO Box 1144, Wollongong, NSW 2500 (Australia))

    1994-07-01

    AISI type 4140 (high tensile) steel has been implanted with tungsten and titanium using a metal vapour vacuum arc ion source. Doses in the range (1-5)x10[sup 16]ionscm[sup -2] were implanted to a depth of approximately 30nm. The relative wear resistance between non-implanted and implanted specimens has been estimated using pin-on-disc and abrasive wear tests. Implantation of titanium decreased the area of wear tracks by a factor of 5 over unimplanted steel. In some cases the steel was also hardened by a liquid carburization treatment before implantation. Abrasion tests revealed a further improvement in wear resistance on this material following ion irradiation. ((orig.))

  10. Evaluation of carbon diffusion in heat treatment of H13 tool steel under different atmospheric conditions

    Directory of Open Access Journals (Sweden)

    Maziar Ramezani

    2015-04-01

    Full Text Available Although the cost of the heat treatment process is only a minor portion of the total production cost, it is arguably the most important and crucial stage on the determination of material quality. In the study of the carbon diffusion in H13 steel during austenitization, a series of heat treatment experiments had been conducted under different atmospheric conditions and length of treatment. Four austenitization atmospheric conditions were studied, i.e., heat treatment without atmospheric control, heat treatment with stainless steel foil wrapping, pack carburization heat treatment and vacuum heat treatment. The results showed that stainless steel foil wrapping could restrict decarburization process, resulting in a constant hardness profile as vacuum heat treatment does. However, the tempering characteristic between these two heat treatment methods is different. Results from the gas nitrided samples showed that the thickness and the hardness of the nitrided layer is independent of the carbon content in H13 steel.

  11. Characterization of catalysts by Moessbauer spectroscopy: An application to the study of Fischer-Tropsch, hydrotreating and super Claus catalysts

    International Nuclear Information System (INIS)

    Kraan, A.M. van der; Boellaard, E.; Craje, M.W.J.

    1993-01-01

    Moessbauer spectroscopy is an excellent in-situ technique for the identification of phases present in catalysts. Applied to metallic iron catalysts used in the Fischer-Tropsch reaction it reveals a detailed picture of the carburization process and provides insight into the relation between the properties of the catalytic material and its activity. The influence of a support and the effect of alloying iron with an (in)active metal on the catalytic performance is discussed for Fe, Cu-Fe and Ni-Fe systems. In addition, Moessbauer spectroscopy is used for the identification of 'Co-sulfide' species present in sulfided Co and CoMo catalysts applied in one of the largest chemical processes in the world, the hydrotreatment of crude oil. A structural model is proposed. Finally, the contribution of Moessbauer spectroscopic studies to the development of a new catalyst for cleaning of Claus tail gas via selective oxidation of hydrogen sulfide to elemental sulfur is discussed. (orig.)

  12. Metallurgical and environmental factors influencing creep behaviour of hastelloy-X

    International Nuclear Information System (INIS)

    Kiuchi, Kiyoshi; Kondo, Tatsuo

    1979-03-01

    Creep and rupture behaviours of Hastelloy-X and its modified version were examined with special reference to the effect of different test environments; i.e. air, high vacuum and the simulated HTR helium coolant. The respective environments showed different effects. The vacuum environment of about 10 -8 torr. gave best reproducible behaviour with essentially no surface-to-volume ratio effect. Such size effect was significant in the other two environments. The simulated HTR environment was characterized in its potentiality of both oxidizing selected alloy constituents and carburization. The observed behaviour was attributed to the depletion of strengthning solute elements caused by the surface reactions and the associated solid state reactions. (author)

  13. Development of a Composite Technique for Preconditioning of 41Cr4 Steel Used as Gear Material: Examination of Its Microstructural Characteristics and Properties

    Directory of Open Access Journals (Sweden)

    Jianjun Hu

    2016-01-01

    Full Text Available Commercial 41Cr4 (ISO standard steel was treated by a composite technique. An intermediate layer was introduced firstly at the 41Cr4 steel surface by traditional carburizing and nitriding. Then a hard Cr coating was brush-plated on the intermediate layer. Finally, the coating layer was modified by high current pulsed electron beam (HCPEB, followed by quenching and subsequent tempering treatment. The microstructure, mechanical properties, and fracture behavior were characterized. The results show that a nanocrystalline Cr coating is formed at the 41Cr4 steel surface by the treatment of the new composite technique. Such nanocrystalline Cr coating has acceptable hardness and high corrosion resistance performance, which satisfies the demands of the gears working under high speed and corrosive environment. The composite process proposed in this study is considered as a new prospect method due to the multifunction layer design on the gear surface.

  14. Mechanisms of metal dusting corrosion

    DEFF Research Database (Denmark)

    Hummelshøj, Thomas Strabo

    In this thesis the early stages of metal dusting corrosion is addressed; the development of carbon expanded austenite, C, and the decomposition hereof into carbides. Later stages of metal dusting corrosion are explored by a systematic study of stainless steel foils exposed to metal dusting...... deformed stainless steel flakes is transformed to expanded martensite/austenite during low-temperature carburization. Various experimental procedures to experimentally determine the concentration dependent diffusion coefficient of carbon in expanded austenite are evaluated. The most promising procedure...... powders and flakes. The nature of the decomposition products, carbides of the form M23C6 and M7C3, were evaluated by X-ray diffraction, light optical microscopy, scanning electron microscopy and thermodynamic modelling. The decomposition was found to be dependent on several parameters such as thermal...

  15. Studies on development of new functional natural materials from agricultural products - Technology developments for ceramic powders and materials from rice phytoliths

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Dae Kap; Kim, Yong Ik [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of); Yoon, Nang Kyu; Seong, Seo Yong [Myongseong Ceramics Com., Taejon (Korea, Republic of); Ryu, Sang Eun [Bae Jae Univ., Taejon (Korea, Republic of); Lee, Jae Chun [Myungji Univ., Seoul (Korea, Republic of)

    1995-08-01

    Based on an estimation of annual rice production of 5.2 million tons, rice husks by-production reaches to 1.17 million tons per year in Korea. Distinguished to other corns, rice contains a lot of Si; 10-20% by weight in rice husks calculated as silica. The aim of this research project is to develop technologies for ceramic powders and materials utilizing the silica in rice husks called phytoliths. In this first year research, researches of the following subjects were performed; material properties of rice husks, milling of rice husks, acid treatments, oxidations at low and high temperatures, sintering and crystalization of amorphous silica, low temperature carburization, formation of silicon carbide whiskers, and brick lightening method using milled rice husks. 11 tabs., 49 figs., 75 refs. (Author).

  16. Problematic of atmospheric pollution in Lebanon: the better stake is apprehended, the best acts are taken

    International Nuclear Information System (INIS)

    Chehab, Said

    1999-01-01

    Lebanon has imported in 1996 5000 Kt of carburants causing about 80 Kt of SO x ; 40 Kt of NO x ; 3 Kt of dusts and 3.5 million tons of CO 2 . The atmospheric pollution in Lebanon is due to three main sources: - Thermal central of electric production - Industries (cement) - Transportation sector The document describes in tables: the inventory of pollutants and pollutant emissions in 1993 and 2010; industrial and heating gas oil; liquified petroleum gas commercial propane; fuel oil for EDL; consumption of energy in 1996; sectorial distribution of pollutants PPM; emissions of CO 2 per tons per habitant in 1993; consumption in 1993 broken down by use and application. Finally, three projects concerning public transportation were presented

  17. Metal corrosion in a supercritical carbon dioxide - liquid sodium power cycle.

    Energy Technology Data Exchange (ETDEWEB)

    Moore, Robert Charles; Conboy, Thomas M.

    2012-02-01

    A liquid sodium cooled fast reactor coupled to a supercritical carbon dioxide Brayton power cycle is a promising combination for the next generation nuclear power production process. For optimum efficiency, a microchannel heat exchanger, constructed by diffusion bonding, can be used for heat transfer from the liquid sodium reactor coolant to the supercritical carbon dioxide. In this work, we have reviewed the literature on corrosion of metals in liquid sodium and carbon dioxide. The main conclusions are (1) pure, dry CO{sub 2} is virtually inert but can be highly corrosive in the presence of even ppm concentrations of water, (2) carburization and decarburization are very significant mechanism for corrosion in liquid sodium especially at high temperature and the mechanism is not well understood, and (3) very little information could be located on corrosion of diffusion bonded metals. Significantly more research is needed in all of these areas.

  18. Extended x-ray absorption fine structure investigation of annealed carbon expanded austenite

    DEFF Research Database (Denmark)

    Oddershede, Jette; Christiansen, Thomas L.; Somers, Marcel A. J.

    2012-01-01

    -carburized in a temperature regime around 470°C. The surface zone is converted into carbon expanded austenite; the high interstitial content of carbon dissolved in the surface results in highly favorable materials properties. In the present article the local atomic environment of (annealed) carbon expanded austenite...... austenite and Hägg carbide, Ξ-M5C2. EXAFS showed that the Cr atoms were mainly present in environments similar to the carbides Hägg Ξ-M5C2 and M23C6. The environments of the Fe and Ni atoms were concluded to be largely metallic austenite. Light optical micrograph of stainless steel AISI 316 gas...

  19. Nanocrystalline, superhard, ductile ceramic coatings for roller-cone bit bearings

    Energy Technology Data Exchange (ETDEWEB)

    Namavar, F.; Colter, P.; Karimy, H. [Spire Corp., Bedford, MA (United States)] [and others

    1997-12-31

    The established method for construction of roller bits utilizes carburized steel, frequently with inserted metal bearing surfaces. This construction provides the necessary surface hardness while maintaining other desirable properties in the core. Protective coatings are a logical development where enhanced hardness, wear resistance, corrosion resistance, and surface properties are required. The wear properties of geothermal roller-cone bit bearings could be further improved by application of protective ceramic hard coatings consisting of nanometer-sized crystallites. Nanocrystalline protective coatings provide the required combination of hardness and toughness which has not been available thus far using traditional ceramics having larger grains. Increased durability of roller-cone bit bearings will ultimately reduce the cost of drilling geothermal wells through increased durability.

  20. Endurance and failure characteristics of modified Vasco X-2, CBS 600 and AISI 9310 spur gears. [aircraft construction materials

    Science.gov (United States)

    Townsend, D. P.; Zaretsky, E. V.

    1980-01-01

    Gear endurance tests and rolling-element fatigue tests were conducted to compare the performance of spur gears made from AISI 9310, CBS 600 and modified Vasco X-2 and to compare the pitting fatigue lives of these three materials. Gears manufactured from CBS 600 exhibited lives longer than those manufactured from AISI 9310. However, rolling-element fatigue tests resulted in statistically equivalent lives. Modified Vasco X-2 exhibited statistically equivalent lives to AISI 9310. CBS 600 and modified Vasco X-2 gears exhibited the potential of tooth fracture occurring at a tooth surface fatigue pit. Case carburization of all gear surfaces for the modified Vasco X-2 gears results in fracture at the tips of the gears.

  1. Changes in mechanical properties and structure of electrolytic plasma treated X 12 CrNi 18 10 Ti stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Kurbanbekov, Sherzod; Baklanov, Viktor; Karakozov, Batyrzhan [Republican State Enterprise National Nuclear Center of Kazakhstan, Kurchatov (Kazakhstan). Inst. of Atomic Energy Branch; Skakov, Mazhyn [Republican State Enterprise National Nuclear Center of Kazakhstan, Kurchatov (Kazakhstan)

    2017-05-01

    The paper addresses findings regarding the influence of electrolytic plasma treatment on the mechanical properties as well as structural and phase states of X 12 CrNi 18 10 Ti steel. Electrolytic plasma treatment is based on carburizing of stainless steel heated in electrolytes. Treatment of steel samples has been performed as follows: the samples were heated up to a temperature between 850 and 950 C and then they were cured for 7 minutes in an electrolyte of an aqueous solution containing 10 % glycerol (C{sub 3}H{sub 8}O{sub 3}) and 15 % sodium carbonate (Na{sub 2}CO{sub 3}). It is found that, after plasma electrolytic treatment, the surface of X 12 CrNi 18 10 Ti steel had a modified structure and high hardness. Increasing wear resistance of X 12 CrNi 18 10 Ti steel has been observed after carburizing and the coefficient of friction has been reduced. X-ray analysis showed that retained austenite γ-Fe is a main phase, and there are some diffraction lines of orthorhombic Fe{sub 3}C phase as well as Fe{sub 3}O{sub 4} cubic phase. It has been determined, that, after plasma electrolytic treatment, a carbide phase in the modified surface layer, irrespective of the location in the steel structure has the chemical composition Fe{sub 3}C. High concentration of carbon atoms in a solid solution based on γ- and α-iron, a large dislocation density, presence of particles of carbide phase and retained austenite layers have been found.

  2. Ambient aging of rhenium filaments used in thermal ionization mass spectrometry: Growth of oxo-rhenium crystallites and anti-aging strategies

    Directory of Open Access Journals (Sweden)

    Joseph M. Mannion

    2017-01-01

    Full Text Available Degassing is a common preparation technique for rhenium filaments used for thermal ionization mass spectrometric analysis of actinides, including plutonium. Although optimization studies regarding degassing conditions have been reported, little work has been done to characterize filament aging after degassing. In this study, the effects of filament aging after degassing were explored to determine a “shelf-life” for degassed rhenium filaments, and methods to limit filament aging were investigated. Zone-refined rhenium filaments were degassed by resistance heating under high vacuum before exposure to ambient atmosphere for up to 2 months. After degassing the nucleation and preferential growth of oxo-rhenium crystallites on the surface of polycrystalline rhenium filaments was observed by atomic force microscopy and scanning electron microscopy (SEM. Compositional analysis of the crystallites was conducted using SEM-Raman spectroscopy and SEM energy dispersive X-ray spectroscopy, and grain orientation at the metal surface was investigated by electron back-scatter diffraction mapping. Spectra collected by SEM-Raman suggest crystallites are composed primarily of perrhenic acid. The relative extent of growth and crystallite morphology were found to be grain dependent and affected by the dissolution of carbon into filaments during annealing (often referred to as carbonization or carburization. Crystallites were observed to nucleate in region specific modes and grow over time through transfer of material from the surface. Factors most likely to affect the rates of crystallite growth include rhenium substrate properties such as grain size, orientation, levels of dissolved carbon, and relative abundance of defect sites; as well as environmental factors such as length of exposure to oxygen and relative humidity. Thin (∼180 nm hydrophobic films of poly(vinylbenzyl chloride were found to slow the growth of oxo-rhenium crystallites on the filament

  3. Thermodynamic analysis of the conditions of deoxidation and secondary treatment of low-silicon steel grade

    Directory of Open Access Journals (Sweden)

    Євген Анатолійович Чичкарьов

    2015-10-01

    Full Text Available This article is concerned with analysis and production testing of technological solutions aimed at reducing the consumption of aluminium for steel deoxidation and reducing level of metal contamination by oxide non-metal inclusions, as well as preventing silicon reduction during out-of-furnace treatment. The conditions of low-silicon steel deoxidation and out-of-furnace treatment have been analysed. It has been found that the scope of oxygen activity variation in the converter before tapping increases while the mass fraction of carbon in the metal decreases. For the converter meltings with a mass fraction of carbon over the range 0,05-0,07 % [C] before tapping the real range of variation was 150-300 ppm. The effect of meltings carburizing on aluminium consumption and the degree of aluminium assimilation have been analysed. It has been shown that in fact the same specific consumption of ferromanganese and comparable changes within the metal oxidation change range before tapping (400-1100 ppm the addition of the carburizer decreases the consumption of aluminium by 0,15 kg/t (in amounts of pure aluminium. The variation interval of assimilation degree of aluminium, consumed for binding the dissolved oxygen in metal and for dissolution in metal has been found. It has been shown that in the melting of low-silicon steel with out- of-furnace treatment but without the use of furnace-ladle unit the rational limit of variation of mass fraction of magnesium oxide variation in the ladle slag is equal to- 6-8 % by weight

  4. Thermal stability and environmental compatibility of Inconel 617

    International Nuclear Information System (INIS)

    Kimball, O.F.

    1989-01-01

    The thermal stability and environmental compatibility of Inconel 617, a prime nuclear process heat steam reformer candidate alloy, are described in this paper. This commercially available wrought nickel-base alloy has excellent high-temperature strength but is subject to loss of toughness and ductility due to thermal instability. Work done to improve the thermal stability of this alloy is discussed. Room-temperature tensile and toughness data and microstructural information for Inconel 617 specimens exposed at elevated temperatures are presented. Preliminary data indicate that controlling the chemistry of Inconel 617 can provide a substantial improvement in thermal stability. Preliminary work to define the range of high-temperature gas-cooled reactor (HTGR) primary coolant compositions within which minimal deleterious gas/metal reactions occur with Inconel 617 is described. Within this gas chemistry range a stable surface oxide forms and only slight carburization occurs. In other gas chemistry ranges, rapid carburization or decarburization can occur. The gas corrosion experiments discussed are part of a series of relatively short-term exposures to HTGR helium in which the effects of different H 2 O concentrations (0.01 to 1.0 Pa) were determined as a function of the systematic variation of a second constituent (CO and CH 4 for this work) in the test gas. The composition of the basic HTGR helium was 40 Pa H 2 , 4 Pa CO, 0.02 Pa CO 2 , 2 Pa CH 4 in helium at 0.2 MPa. Two other CO levels (1 and 12 Pa) and one additional CH 4 level (0.63 Pa) were used in these experiments. Experimental exposure methods are discussed and the results of gas-metal interaction studies are presented. These results include carbon analyses and optical and scanning electron microscopy to determine the morphology and type of surface and subsurface microstructures. (author). 15 refs, 6 figs, 5 tabs

  5. Damage characterization of an ASTM A 213 grade 91 tube after 116.000 h of service in a reforming plant

    International Nuclear Information System (INIS)

    Tonti, Andrea; Lega, Daniela; Antonini, Alessandra; Romitelli, Manuela; Alvino, Antonello

    2015-01-01

    ASTM A213 T91 steel is used in power plants and petrochemical industry, for long-term service components. The improved mechanical properties of grade 91 are strictly related to its specific microstructure: a tempered martensite matrix with fine precipitates embedded in. Despite low alloy heat resistant ferritic steels, that have a well known operational experience, T91 service performances are still faintly consolidated, because this material has serviced only in a limited number of plants, since the eighties. Most of the available data were obtained by laboratory tests on relatively short term creep strength and corrosion properties. The investigations reported in this paper represent an important opportunity to describe and better evaluate the damage evolution of the grade T91 steel after more than 100000 h of exposure in severe conditions (580 °C, 18–26 bar, combustion environment). Our results suggest that the steel suffered by different damage forms, which appear on definite portions of the tube cross section. The main degradation forms observed, in fact, into the tube bulk are both the martensite recovery and the microstructural evolution. This latter promoted mostly Laves phase precipitation and coarsening. On the other hand, both the outer and the inner wall side, suffered mainly by severe oxidation/carburization. Especially on the outer surface, the massive carbide precipitation has caused an evident loss of ductility so that the mechanical properties of the tube appear appreciably reduced. - Highlights: • ASTM A213 T91 steel is used in petrochemical industry, for long-term service components. • The investigations reported an evaluation of the damage evolution of the grade T91 steel. • Our results suggest that the steel suffered both the martensite recovery and the microstructural evolution. • The outer and the inner wall side, suffered mainly by severe oxidation/carburization. • Carbide precipitation caused loss of ductility so that the

  6. Structural instabilities of high temperature alloys and their use in advanced high temperature gas cooled reactors

    International Nuclear Information System (INIS)

    Schuster, H.; Ennis, P.J.; Nickel, H.; Czyrska-Filemonowicz, A.

    1989-01-01

    High-temperature, iron-nickel and nickel based alloys are the candidate heat exchanger materials for advanced high temperature gas-cooled reactors supplying process heat for coal gasification, where operation temperatures can reach 850-950 deg. C and service lives of more than 100,000 h are necessary. In the present paper, typical examples of structural changes which occur in two representative alloys (Alloy 800 H, Fe-32Ni-20Cr and Alloy 617, Ni-22Cr-12Co-9Mo-1Al) during high temperature exposure will be given and the effects on the creep rupture properties discussed. At service temperatures, precipitation of carbides occurs which has a significant effect on the creep behaviour, especially in the early stages of creep when the precipitate particles are very fine. During coarsening of the carbides, carbides at grain boundaries restrict grain boundary sliding which retards the development of creep damage. In the service environments, enhanced carbide precipitation may occur due to the ingress of carbon from the environment (carburization). Although the creep rate is not adversely affected, the ductility of the carburized material at low and intermediate temperatures is very low. During simulated service exposures, the formation of surface corrosion scales, the precipitation of carbides and the formation of internal oxides below the surface leads to depletion of the matrix in the alloying elements involved in the corrosion processes. In thin-walled tubes the depletion of Cr due to Cr 2 O 3 formation on the surface can lead to a loss of creep strength. An additional depletion effect resulting from environmental-metal reactions is the loss of carbon (decarburization) which may occur in specific environments. The compositions of the cooling gases which decarburize the material have been determined; they are to be avoided during reactor operation

  7. Cooperation in the field of materials and metallurgical technologies

    International Nuclear Information System (INIS)

    Pilous, V.; Kletecka, Z.; Matejovic, K.

    1989-01-01

    The SKODA Works cooperate extensively with the Mechanical and Electrical Engineering College in Plzen and with other organizations in many branches of science and technology, among others in the field of materials science and metallurgical technologies. For instance, the technology was mastered of welding low-pressure rotors from a medium-alloy high-strength steel with reduced carbon content of the CrNiMoV type, with yield points of 600 MPa in the basic material and 550 MPa in the welded joint. The welded rotor is used in three low-pressure parts of a 1000 MW steam turbine for a nuclear power plant, which is also produced at SKODA. Problems of protection against corrosion and erosion in saturated steam turbines, caused by wet steam at pressures of 0.5 to 5 MPa and humidity as high as 11%, were also solved. A complex of problems was tackled in the production of reactor pressure vessels. It was found that heat treatment of 25Cr/13Ni overlays of the CrMoV reactor steel at 665 degC results in the formation of a carburized zone between the overlay and the CrMoV steel. This zone constituted a good barrier against the diffusion of hydrogen from the austenitic overlay to the steel. The width of the zone where the diffusion had taken place did not increase in the working conditions, i.e. under the effect of a temperature of 320 degC, while the hardness of this zone increased considerably due to the redistribution of carbon within the 1.6 μm width. The occurrence of the carburized high-hardness zone had a favourable effect on the stabilization of the rate of crack propagation and on its diversion. Recovery annealing at 480 degC is suitable for reducing the hydrogen content of the austenitic overlays. (P.A.). 5 figs., 14 refs

  8. Fatigue and Creep Crack Propagation behaviour of Alloy 617 in the Annealed and Aged Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Julian K. Benz; Richard N. Wright

    2013-10-01

    The crack propagation behaviour of Alloy 617 was studied under various conditions. Elevated temperature fatigue and creep-fatigue crack growth experiments were conducted at 650 and 800 degrees C under constant stress intensity (triangle K) conditions and triangular or trapezoidal waveforms at various frequencies on as-received, aged, and carburized material. Environmental conditions included both laboratory air and characteristic VHTR impure helium. As-received Alloy 617 displayed an increase in the crack growth rate (da/dN) as the frequency was decreased in air which indicated a time-dependent contribution component in fatigue crack propagation. Material aged at 650°C did not display any influence on the fatigue crack growth rates nor the increasing trend of crack growth rate with decreasing frequency even though significant microstructural evolution, including y’ (Ni3Al) after short times, occurred during aging. In contrast, carburized Alloy 617 showed an increase in crack growth rates at all frequencies tested compared to the material in the standard annealed condition. Crack growth studies under quasi-constant K (i.e. creep) conditions were also completed at 650 degrees C and a stress intensity of K = 40 MPa9 (square root)m. The results indicate that crack growth is primarily intergranular and increased creep crack growth rates exist in the impure helium environment when compared to the results in laboratory air. Furthermore, the propagation rates (da/dt) continually increased for the duration of the creep crack growth either due to material aging or evolution of a crack tip creep zone. Finally, fatigue crack propagation tests at 800 degrees C on annealed Alloy 617 indicated that crack propagation rates were higher in air than impure helium at the largest frequencies and lowest stress intensities. The rates in helium, however, eventually surpass the rates in air as the frequency is reduced and the stress intensity is decreased which was not observed at 650

  9. Application of the laser pyrolysis to the synthesis of SiC, TiC and ZrC pre-ceramics nano-powders

    International Nuclear Information System (INIS)

    Leconte, Y.; Maskrot, H.; Combemale, L.; Herlin-Boime, N.; Reynaud, C.

    2007-01-01

    Refractory carbide nano-structured ceramics appear to be promising materials for high temperature applications requiring hard materials such as nuclear energy industry. Such carbide materials are usually obtained with micrometric sizes from the high temperature carbo-reduction of an oxide phase in a raw mixture of C black and titania or zirconia. TiC and ZrC nano-powders were produced from an intimate mixture of oxide nano-grains with free C synthesized by laser pyrolysis from the decomposition of a liquid precursor. The temperature and the duration of the thermal treatment leading to the carburization were decreased, allowing the preservation of the nano-scaled size of the starting grains. A solution of titanium iso-prop-oxide was laser-pyrolyzed with ethylene as sensitizer in order to synthesize Ti/C/O powders. These powders were composed of crystalline TiO 2 nano-grains mixed with C. Annealing under argon enabled the formation of TiC through the carburization of TiO 2 by free C. The final TiC mean grain size was about 80 nm. Zr/O/C powders were prepared from a solution of zirconium butoxide and were composed of ZrO 2 crystalline nano-grains and free C. The same thermal treatment as for TiC, but at higher temperature, showed the formation of crystalline ZrC with a final mean grain size of about 40 nm. These two liquid routes of nano-particles synthesis are also compared to the very efficient gaseous route of SiC nano-powders synthesis from a mixture of silane and acetylene. (authors)

  10. Les possibilités de limitation des émissions de plomb par les véhicules automobiles Possibilities of Limiting Leaded Exhaust from Automotive Vehicles

    Directory of Open Access Journals (Sweden)

    Roth J.

    2006-11-01

    Full Text Available Les additifs plombés permettent de satisfaire les besoins en octane des moteurs automobiles actuels. Dans le cadre de la lutte contre la pollution automobile, il est envisagé de réduire ou de supprimer le plomb présent dans les carburants. La suppression brutale, tout en présentant certains avantages, entraîne de nombreux inconvénients, d'ordre purement technique mais également d'ordre financier. La mise au point d'un dispositif de captation, par les sociétés Texaco et Octel, semble permettre d'envisager de maintenir la présence de plomb dans les carburants, tout en réduisant les émissions à l'échappement. Les travaux effectués à l'UTAC ont permis de tester ces dispositifs sur une endurance de 31 000 km. Les résultats obtenus ont permis de dégager un gain d'efficacité d'environ 60 %, les paramètres, bruit et pollution (CO et HC restant par ailleurs inchangés. Leaded additives enable the octane requirements of existing automotive engines to be satisfied. However, as part of the fight against automotive pollution, plans are being drawn up to reduce or eliminate the lead present in fuels. A sudden elimination, although having some advantages, would create a great many disadvantages of a purely technical as well as financiel nature. Texaco and Octet have developed a trapping device that appears to enable lead to be retained in fuels at the same time as reducing exhaust emissions. This device has undergone a 31,000-kilometer endurance test at UTAC. The results reveal an efficiency gain of 60 %, while the noise and pollution (CO and HC parameters remain the same.

  11. Carbonitriding of low alloy steels: Mechanical and metallurgical responses

    Energy Technology Data Exchange (ETDEWEB)

    Dal' Maz Silva, W., E-mail: waltermateriais@me.com [Institut Jean Lamour – UMR CNRS–Université de Lorraine, 7198, Parc de Saurupt, Nancy 54011 (France); Institut de Recherche Technologique M2P, Metz 57070 (France); Dulcy, J., E-mail: jacky.dulcy@univ-lorraine.fr [Institut Jean Lamour – UMR CNRS–Université de Lorraine, 7198, Parc de Saurupt, Nancy 54011 (France); Ghanbaja, J., E-mail: jaafar.ghanbaja@univ-lorraine.fr [Institut Jean Lamour – UMR CNRS–Université de Lorraine, 7198, Parc de Saurupt, Nancy 54011 (France); Redjaïmia, A., E-mail: abdelkrim.redjaimia@univ-lorraine.fr [Institut Jean Lamour – UMR CNRS–Université de Lorraine, 7198, Parc de Saurupt, Nancy 54011 (France); Michel, G., E-mail: gregory.michel@irt-m2p.fr [Institut de Recherche Technologique M2P, Metz 57070 (France); Thibault, S., E-mail: simon.thibault@safran.fr [Safran Tech, Magny les Hameaux (France); Belmonte, T., E-mail: thierry.belmonte@univ-lorraine.fr [Institut Jean Lamour – UMR CNRS–Université de Lorraine, 7198, Parc de Saurupt, Nancy 54011 (France)

    2017-05-02

    Metallurgical and mechanical responses of alloys 16NiCrMo13 and 23MnCrMo5 to the addition of carbon and/or nitrogen were investigated. Diffusion profiles of these interstitial elements were established by atmospheric pressure carburizing, austenitic nitriding, and a sequence of carburizing and nitriding – the carbonitriding. All treatments were performed at 1173 K under CO-H{sub 2} and/or NH{sub 3} based atmospheres. After enrichment, each sample was (i) room-temperature oil-quenched and (ii) immersed in boiling nitrogen prior to (iii) the stress relief treatment. Cross-section hardness profiles were evaluated after each of these steps. Electron probe microanalysis (EPMA) allowed for the determination of both carbon and nitrogen diffusion profiles after quenching. In order to estimate the fraction of nitrides formed during the enrichment of the alloys, these measured profiles were employed in the simulation of local equilibrium at each evaluated position. This allowed for the computation of total solid solution interstitial content, which was expressed in atomic fraction. Plots of as-quenched hardness against the square root of the computed interstitial content, i.e. the sum of solution carbon and the remaining nitrogen, show the complementary character of these elements in determining the mechanical properties of the materials prior to stress relief treatment. Tempering of carbon-nitrogen martensite resulted in hardness drop to a lesser degree than the one measured on carbon martensite with equivalent interstitial content. In order to investigate this behavior, transmission electron microscopy (TEM) analyses were performed. Results showed the precipitation of two morphologies of Fe{sub 16}N{sub 2} in the nitrogen-rich case and image analysis confirmed the simulated fraction of nitrides.

  12. Carbon in sodium - A status review of the U.S.A. R and D work

    International Nuclear Information System (INIS)

    McCown, J.J.; Bagnall, C.

    1980-01-01

    Liquid Metal Fast Breeder Reactors contain several types of steel in primary and secondary sodium systems. Austenitic stainless steels are used for in-core components, valves, heat exchangers, tanks and fuel cladding in primary systems. In power generating plants, the secondary or intermediate heat transport system may contain both austenitic and ferritic steel such as 2-1/4 Cr-l Mo type. Sodium circulating throughout the plant contains a number of impurities, metallic and non-metallic, with the steel interstitial elements carbon, hydrogen and oxygen being of prime importance. These elements can affect corrosion rates and mechanical behavior of materials. In the case of carbon, the sodium provides a transport medium with carburization and decarburization occurring in several parts of a system at rates depending upon temperature and types of steel. The US Sodium Technology R and D programs have investigated the behavior, transport, measurement and control of carbon in sodium. Measurement and control methods for carbon-containing materials which might contaminate the plant systems during reactor operation have also been studied. During the early 1970's, several US laboratories were active in studying carbon solubility, activity in sodium and interstitial transfer using both theoretical and experimental approaches. Modelling studies were done and models were used to predict FFTF and CRBRP materials requirements, component design and plant operating conditions. Over the past several years, carbon work has not been heavily emphasized. Most of the R and D studies have centered on improving chemical analysis methods for measuring active carbon, both by on-line monitors and by metal foil equilibration procedures; and on studies of pump oil-sodium reactions, reaction products, temperature effects and oil leak detection methods. One program at General Electric is investigating carburization-decarburization in a ferritic-austenitic system simulating conditions expected in

  13. Internal carbonitriding behavior of Ni-V, Ni-Cr, and Ni-3Nb alloys

    International Nuclear Information System (INIS)

    Allen, A.T.; Douglass, D.L.

    1999-01-01

    Ni-2V, Ni-5V, Ni-12V, Ni-10Cr, Ni-20Cr, and Ni-3Nb alloys were carbonitrided in C 3 H 6 and NH 3 gas mixtures (bal H 2 ) over the range 700--1,000 C. Carbonitridation of Ni-12V and Ni-20Cr in C 3 H 6 /NH 3 /H 2 (1.5/1.5/97 v/o) and (1.5/10/88.5 v/o) produced duplex subscales consisting of near-surface nitrides with underlying carbides. Growth of each zone obeyed the parabolic rate law under most conditions. The presence of carbon generally did not effect the depth of the nitride zones compared to nitriding the alloys in NH 3 /H 2 (10/90 v/o). However, at 700 C, the nitride zones were deeper in the carbonitrided Ni-V alloys and Ni-20Cr. The presence of nitrogen generally increased the depth of the carbide zones in Ni-12V and Ni-20Cr compared to carburizing these alloys in C 3 H 6 /H 2 (1.5/98.5 v/o). VN, CrN, and NbN formed in Ni-V, Ni-Cr, and Ni-Nb alloys, respectively, whereas the underlying carbide layers contained V 4 C 3 in Ni-12V, Cr 3 C 2 above a zone of Cr 7 C 3 in Ni-20Cr, and NbC in Ni-3Nb. The solubilities and diffusivities of nitrogen and carbon in nickel were determined. Nitrogen and carbon each exhibited retrograde solubility with temperature in pure Ni in both carbonitriding environments. Nitrogen diffusion in nickel was generally lower in each carbonitriding mixture compared to nitrogen diffusion in a nitriding environment, except at 700 C when nitrogen diffusion was higher. Carbon diffusion in nickel was generally higher in the carbonitriding environments compared to carbon diffusion in a carburizing environment

  14. Application of in situ x-ray diffraction techniques in heterogenous catalytic systems

    International Nuclear Information System (INIS)

    Sharifah Bee Abd Hamid

    2002-01-01

    A broad range of techniques is available today for the characterisation of catalysts and the investigation of catalyst reaction mechanisms. However, only a limited number of those are suitable for in situ studies, i.e experiments performed in conditions mimicking or close as possible to real operating conditions. Various commercially and in-house developed in situ X-Ray diffraction (XRD) cells have been used to obtain information on the phase and structure of materials at the initial formation stage, activation methodology, calcination, reduction and carburization. A major advantage of the in situ X-ray cells is that it allows direct observations on the decomposition of precursors leading to various phases in a controlled environment, i.e. controlled temperature and pressure under specified gases. The cells can be operated both at high temperatures and high pressures, equipped with Position Sensitive Detector (PSD), feature which was used to study phase transformation occurring during the activation of various solids. In MoO 3 , XRD results provide detailed information on the hydrogen insertion into its lattice, followed by carburization providing good understanding on the mechanism in the solid transformation leading to the metastable MoC 1 -x phase. For the Bi-SnO x systems, the environmental cell coupled with XRD and PSD allow the design of activation procedure to obtain the active Bi 2 Sn 2 O 7 . The in situ XRD technique reveals crucial information on the initial stage of oxides formations prior to condensation reaction shown in MCM-41 and titania systems. In this presentation, discussions on general achievements and problems relating to the use of in situ XRD techniques as well as of specific examples selected to illustrate the use and potential of in situ XRD are made. It is not intended to be a review of the art but a highlight of the challenges which the catalytic and material scientists face when entering the avenue. (Author)

  15. Gas-Solid Reaction Route toward the Production of Intermetallics from Their Corresponding Oxide Mixtures

    Directory of Open Access Journals (Sweden)

    Hesham Ahmed

    2016-08-01

    Full Text Available Near-net shape forming of metallic components from metallic powders produced in situ from reduction of corresponding pure metal oxides has not been explored to a large extent. Such a process can be probably termed in short as the “Reduction-Sintering” process. This methodology can be especially effective in producing components containing refractory metals. Additionally, in situ production of metallic powder from complex oxides containing more than one metallic element may result in in situ alloying during reduction, possibly at lower temperatures. With this motivation, in situ reduction of complex oxides mixtures containing more than one metallic element has been investigated intensively over a period of years in the department of materials science, KTH, Sweden. This review highlights the most important features of that investigation. The investigation includes not only synthesis of intermetallics and refractory metals using the gas solid reaction route but also study the reaction kinetics and mechanism. Environmentally friendly gases like H2, CH4 and N2 were used for simultaneous reduction, carburization and nitridation, respectively. Different techniques have been utilized. A thermogravimetric analyzer was used to accurately control the process conditions and obtain reaction kinetics. The fluidized bed technique has been utilized to study the possibility of bulk production of intermetallics compared to milligrams in TGA. Carburization and nitridation of nascent formed intermetallics were successfully carried out. A novel method based on material thermal property was explored to track the reaction progress and estimate the reaction kinetics. This method implies the dynamic measure of thermal diffusivity using laser flash method. These efforts end up with a successful preparation of nanograined intermetallics like Fe-Mo and Ni-W. In addition, it ends up with simultaneous reduction and synthesis of Ni-WN and Ni-WC from their oxide mixtures

  16. Carbon in sodium - A status review of the U.S.A. R and D work

    Energy Technology Data Exchange (ETDEWEB)

    McCown, J J; Bagnall, C [HEDL, Richland, WA (United States)

    1980-05-01

    Liquid Metal Fast Breeder Reactors contain several types of steel in primary and secondary sodium systems. Austenitic stainless steels are used for in-core components, valves, heat exchangers, tanks and fuel cladding in primary systems. In power generating plants, the secondary or intermediate heat transport system may contain both austenitic and ferritic steel such as 2-1/4 Cr-l Mo type. Sodium circulating throughout the plant contains a number of impurities, metallic and non-metallic, with the steel interstitial elements carbon, hydrogen and oxygen being of prime importance. These elements can affect corrosion rates and mechanical behavior of materials. In the case of carbon, the sodium provides a transport medium with carburization and decarburization occurring in several parts of a system at rates depending upon temperature and types of steel. The US Sodium Technology R and D programs have investigated the behavior, transport, measurement and control of carbon in sodium. Measurement and control methods for carbon-containing materials which might contaminate the plant systems during reactor operation have also been studied. During the early 1970's, several US laboratories were active in studying carbon solubility, activity in sodium and interstitial transfer using both theoretical and experimental approaches. Modelling studies were done and models were used to predict FFTF and CRBRP materials requirements, component design and plant operating conditions. Over the past several years, carbon work has not been heavily emphasized. Most of the R and D studies have centered on improving chemical analysis methods for measuring active carbon, both by on-line monitors and by metal foil equilibration procedures; and on studies of pump oil-sodium reactions, reaction products, temperature effects and oil leak detection methods. One program at General Electric is investigating carburization-decarburization in a ferritic-austenitic system simulating conditions expected in

  17. Catalytic synthesis of alcoholic fuels for transportation from syngas

    Energy Technology Data Exchange (ETDEWEB)

    Qiongxiao Wu

    2012-12-15

    carbon and reaches a maximum over bulk Mo2C, while the selectivity to methanol follows the opposite trend. The effect of Mo2C loading on the alcohol selectivity at a fixed K/Mo molar ratio of 0.14 could be related to the amount of K2CO3 actually on the active Mo2C phase and the size, structure, and composition of the supported carbide clusters. Unpromoted, active carbon supported Mo2C exhibits a high activity in CO hydrogenation with hydrocarbons as the dominant products. The K2CO3 promoter plays an essential role in directing the selectivity to alcohols rather than to hydrocarbons. The optimum selectivity towards higher alcohols and alcohols in general is obtained at a K/Mo molar ratio of 0.21 over the active carbon supported Mo2C (20 wt %). Combined in situ XAS and XRD have been used to follow directly the carburization process and formation of bulk and supported molybdenum carbides (20 wt % and 40 wt % Mo2C on active carbon). The bulk Mo2C prepared by temperature programmed carburization in flow of 20 mol % CH4 in H2 most likely adopts an orthorhombic structure (a-Mo2C). A two-step mechanism is discovered during the in situ carburization process, composed of the initial reduction of Mo(VI) oxide to Mo(IV) oxide followed by a succeeding conversion to carbide. The necessary carburization temperature is to a significant extent determined by the crystal sizes. A decrease on particle size can initiate the onset of carburization at a lower temperature. (LN)

  18. Analyse de la sensibilité aux paramètres gazoles d'un moteur diesel d'automobile à injection directe Small Direct Injection Diesel Engine Sensitivity to the Diesel Fuel Characteristics

    Directory of Open Access Journals (Sweden)

    Montagne X.

    2006-12-01

    Full Text Available L'étude présentée a été réalisée dans le cadre du GMCL (Groupement Moteur Carburant Lubrifiant, organisme qui réunit des constructeurs d'automobiles, des raffineurs et des additiveurs, avec l'objectif d'examiner la sensibilité d'un moteur Diesel à injection directe d'automobile aux paramètres du gazole. Les partenaires de cette étude sont Elf, IFP, Octel, PSA, Renault et Total. Parmi les solutions technologiques permettant de disposer de convertisseurs d'énergie assurant de faibles niveaux d'émissions de polluants et de consommation, le moteur Diesel se place naturellement en bonne position. Dans ce contexte, on enregistre aujourd'hui l'émergence du moteur Diesel à injection directe pour les véhicules légers en raison de ses performances, notamment en regard de la consommation. Toutefois, cette technologie nécessite une technique d'injection performante, associée à la gestion électronique, demande de l'EGR et un catalyseur d'oxydation afin de régler les problèmes d'émissions polluantes et sonores. Il est donc de première importance de cerner avec précision la sensibilité du moteur Diesel à injection directe aux paramètres carburants afin de tirer le meilleur profit de cette technologie. À partir d'un ensemble de gazoles formulés pour faire varier la composition chimique, l'indice de cétane et la densité, un moteur Audi à injection directe de type 1Z a été testé au banc, dans des conditions standard de réglage (avance à l'injection et taux de gaz recyclés. Cet ensemble de résultats a ainsi permis de démontrer que l'accroissement de l'indice de cétane, la réduction de la densité et de la teneur en polyaromatiques ont une influence positive sensible sur les émissions de CO, d'hydrocarbures imbrûlés, des VOF. En ce qui concerne les émissions de particules, l'indice de cétane semble avoir une influence négative sur la fraction sèche dans certaines conditions. De plus, il apparaît que les

  19. Potentiel des moteurs à mélange pauvre face aux moteurs actuels à réglage stoechiométrique : consommation, émissions, exigence en octane The Challenge to Modern Stoichiometric Engines by the Potential Lean-Burn Engine: Consumption, Emissions, Fuel Requirements

    Directory of Open Access Journals (Sweden)

    Douaud A. M.

    2006-11-01

    Full Text Available Le moteur à allumage commandé pour application automobile aux États-Unis est généralement dépollué par catalyse trifonctionnelle qui impose un contrôle stoechiométrique du mélange air-carburant. Le contexte européen de 1990 pour la qualité de l'air stimule l'industrie automobile dans ses recherches de solutions techniques performantes. Le moteur à mélange pauvre, performant en consommation, est une solution potentielle si l'émission de NOx peut être maîtrisée par la combustion. Cet objectif nécessite une conception du moteur contrôlant la turbulence et l'hétérogénéité du mélange air + carburant + résiduels pendant la combustion. La longévité de l'adaptation optimale moteur-carburant nécessitera un contrôle électronique de l'allumage et l'utilisation d'additifs détergents. Pour satisfaire les réglementations les plus sévères, les émissions de CO et HC pourront être contrôlées par un simple pot catalytique d'oxydation. Des oxydes de métaux non précieux introduits dans la formule catalytique en addition aux métaux précieux maintiennent la fonction oxydante pendant les transitoires en mélange riche tout en réduisant partiellement les NOx. Une vue d'ensemble de ce concept basé sur des simulations numériques et des résultats expérimentaux de consommation, d'émission, d'exigence en octane, etc. est présentée. Spark-ignition engines for automotive applications in the United States are currently depolluted by a 3-way catalyst that requires air-fuel control at stoichiometry. The 1990 European context for air pollution control is stimulating the automotive industry to search for improved technical solutions. The lean-burn engine is a potential fuel-efficient answer if its combustion can be optimized for low NOx emissions. Achieving this challenging approach requires engine design to control the turbulence and heterogeneity of the air + fuel + residual mixture during combustion. Electronic ignition

  20. Contribution to the study of the (U,Pu)C,N system; Contribution a l'etude du systeme (U,Pu)C,N

    Energy Technology Data Exchange (ETDEWEB)

    Lorenzelli, R [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    The reactions of UC, PuC, (U,Pu)C, UC{sub 2} and U(C{sub 1-x}O{sub x}) with nitrogen at moderate temperatures (room temperature to 400 C) are described. The influence of the uptake of nitrogen by the powders necessary to sinter the carbides upon the nature of the final product has been investigated; it has been shown that the sintered carbides are hyper-stoichiometric. The reactions of carbon with UN, PuN and (U,Pu)N has also been studied. Under vacuum, carbon reacts on the nitrides at temperatures as low as 1100 C; nitrogen is replaced by carbon and the final product is a carbonitride. The reaction is: MN + x C {yields} MN{sub 1-x}C{sub x} + x/2N{sub 2}. The reaction is limited and the carbonitrides have a fixed composition in presence of M{sub 2}C{sub 3} or MC{sub 2}; hence it is impossible to produce pure MC using the reaction. The ternary diagram U-C-N, Pu-C-N and (U,Pu)C-N have been drawn. They show clearly that it is possible to obtain single phase carbonitrides in a wide domain of compositions. (author) [French] On decrit les reactions avec l'azote de UC, PuC,(U,Pu)C,UC{sub 2} et U(C{sub 1-x}O{sub x}), par action directe de l'azote a temperature moderee (de l'ambiante a 450 C). On a etudie l'influence de la contamination par l'azote des poudres de carbures necessaires au frittage sur la nature des produits frittes; on a montre que les carbures frittes obtenus sont hyperstoechiometriques. On a etudie parallelement les reactions du carbone avec UN, PuN et (U,Pu)N. Sous vide le carbone reagit sur les nitrures des 1100 C: le carbone se substitue a l'azote; l'azote libere est elimine et le produit final est un carbonitrure. La reaction s'ecrit: MN + x C {yields} MN{sub 1-x}C{sub x} + x/2N{sub 2}. La reaction est limitee et les carbonitrures obtenus ont une composition limite fixe en presence des carbures superieurs M{sub 2}C{sub 3} et MC{sub 2}; il est donc impossible d'obtenir MC pur par cette reaction. Les diagrammes d'equilibre U-C-N, Pu-C-N et (U,Pu) C-N, ont

  1. Optimisation des trajectoires verticales par la methode de la recherche de l'harmonie =

    Science.gov (United States)

    Ruby, Margaux

    Face au rechauffement climatique, les besoins de trouver des solutions pour reduire les emissions de CO2 sont urgentes. L'optimisation des trajectoires est un des moyens pour reduire la consommation de carburant lors d'un vol. Afin de determiner la trajectoire optimale de l'avion, differents algorithmes ont ete developpes. Le but de ces algorithmes est de reduire au maximum le cout total d'un vol d'un avion qui est directement lie a la consommation de carburant et au temps de vol. Un autre parametre, nomme l'indice de cout est considere dans la definition du cout de vol. La consommation de carburant est fournie via des donnees de performances pour chaque phase de vol. Dans le cas de ce memoire, les phases d'un vol complet, soit, une phase de montee, une phase de croisiere et une phase de descente, sont etudies. Des " marches de montee " etaient definies comme des montees de 2 000ft lors de la phase de croisiere sont egalement etudiees. L'algorithme developpe lors de ce memoire est un metaheuristique, nomme la recherche de l'harmonie, qui, concilie deux types de recherches : la recherche locale et la recherche basee sur une population. Cet algorithme se base sur l'observation des musiciens lors d'un concert, ou plus exactement sur la capacite de la musique a trouver sa meilleure harmonie, soit, en termes d'optimisation, le plus bas cout. Differentes donnees d'entrees comme le poids de l'avion, la destination, la vitesse de l'avion initiale et le nombre d'iterations doivent etre, entre autre, fournies a l'algorithme pour qu'il soit capable de determiner la solution optimale qui est definie comme : [Vitesse de montee, Altitude, Vitesse de croisiere, Vitesse de descente]. L'algorithme a ete developpe a l'aide du logiciel MATLAB et teste pour plusieurs destinations et plusieurs poids pour un seul type d'avion. Pour la validation, les resultats obtenus par cet algorithme ont ete compares dans un premier temps aux resultats obtenus suite a une recherche exhaustive qui a

  2. Contribution to the study of the (U,Pu)C,N system; Contribution a l'etude du systeme (U,Pu)C,N

    Energy Technology Data Exchange (ETDEWEB)

    Lorenzelli, R. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    The reactions of UC, PuC, (U,Pu)C, UC{sub 2} and U(C{sub 1-x}O{sub x}) with nitrogen at moderate temperatures (room temperature to 400 C) are described. The influence of the uptake of nitrogen by the powders necessary to sinter the carbides upon the nature of the final product has been investigated; it has been shown that the sintered carbides are hyper-stoichiometric. The reactions of carbon with UN, PuN and (U,Pu)N has also been studied. Under vacuum, carbon reacts on the nitrides at temperatures as low as 1100 C; nitrogen is replaced by carbon and the final product is a carbonitride. The reaction is: MN + x C {yields} MN{sub 1-x}C{sub x} + x/2N{sub 2}. The reaction is limited and the carbonitrides have a fixed composition in presence of M{sub 2}C{sub 3} or MC{sub 2}; hence it is impossible to produce pure MC using the reaction. The ternary diagram U-C-N, Pu-C-N and (U,Pu)C-N have been drawn. They show clearly that it is possible to obtain single phase carbonitrides in a wide domain of compositions. (author) [French] On decrit les reactions avec l'azote de UC, PuC,(U,Pu)C,UC{sub 2} et U(C{sub 1-x}O{sub x}), par action directe de l'azote a temperature moderee (de l'ambiante a 450 C). On a etudie l'influence de la contamination par l'azote des poudres de carbures necessaires au frittage sur la nature des produits frittes; on a montre que les carbures frittes obtenus sont hyperstoechiometriques. On a etudie parallelement les reactions du carbone avec UN, PuN et (U,Pu)N. Sous vide le carbone reagit sur les nitrures des 1100 C: le carbone se substitue a l'azote; l'azote libere est elimine et le produit final est un carbonitrure. La reaction s'ecrit: MN + x C {yields} MN{sub 1-x}C{sub x} + x/2N{sub 2}. La reaction est limitee et les carbonitrures obtenus ont une composition limite fixe en presence des carbures superieurs M{sub 2}C{sub 3} et MC{sub 2}; il est donc impossible d'obtenir MC pur par cette reaction. Les diagrammes

  3. The Modification of Sodium Polyacrylate Water Solution Cooling Properties by AL2O3

    Directory of Open Access Journals (Sweden)

    Wojciech Gęstwa

    2010-01-01

    Based on cooling curves, it can be concluded that for the water solution of sodium polyacrylate with AL2O3 nanoparticles in comparison to water and 10% polymer water solution lower cooling speed is obtained. The cooling medium containing nanoparticles provides lower cooling speed in the smallest surface austenite occurance (500–600 C in the charts of the CTP for most nonalloy structural steels and low-alloy steels. However lower cooling temperature at the beginning of martensitic transformation causes the formation of smaller internal stresses, leading to smaller dimensional changes and hardening deformation. For the quenching media the wetting angle was appointed by the drop-shape method. These studies showed the best wettability of polymer water solution (sodium polyacrylate with the addition of AL2O3 nanoparticles, whose wetting angle was about 65 degrees. Obtaining the smallest wetting angle for the medium containing nanoparticles suggests that the heat transfer to the cooling medium is larger. This allows slower cooling at the same time ensuring its homogeneity. The obtained values of wetting angle confirm the conclusions drawn on the basis of cooling curves and allowus to conclude that in the case of the heat transfer rate it will have a lower value than for water and 10% polymer water solution. In the research on hardened carburized steel samples C10 and 16MnCr5 surface hardness, impact strength and changes in the size of cracks in Navy C-ring sample are examined. On this basis of the obtained results it can be concluded that polymer water solution with nanoparticles allows to obtain a better impact strength at comparable hardness on the surface. Research on the dimensional changes on the basis of the sample of Navy C-ring also shows small dimensional changes for samples carburized and hardened in 10% polymer water solution with the addition of nanoparticles AL2O3. Smaller dimensional changes were obtained for samples of steel 16MnCr5 thanfar C10. The

  4. Development and kinetic analysis of cobalt gradient formation in WC-Co composites

    Science.gov (United States)

    Guo, Jun

    2011-12-01

    Functionally graded cemented tungsten carbide (FG WC-Co) is one of the main research directions in the field of WC-Co over decades. Although it has long been recognized that FG WC-Co could outperform conventional homogeneous WC-Co owing to its potentially superior combinations of mechanical properties, until recently there has been a lack of effective and economical methods to make such materials. The lack of the technology has prevented the manufacturing and industrial applications of FG WC-Co from becoming a reality. This dissertation is a comprehensive study of an innovative atmosphere heat treatment process for producing FG WC-Co with a surface cobalt compositional gradient. The process exploited a triple phase field in W-C-Co phase diagram among three phases (solid WC, solid Co, and liquid Co) and the dependence of the migration of liquid Co on temperature and carbon content. WC-Co with a graded surface cobalt composition can be achieved by controlling the diffusion of carbon transported from atmosphere during sintering or during postsintering heat treatment. The feasibility of the process was validated by the successful preparations of FG WC-Co via both carburization and decarburization process following conventional liquid phase sintering. A study of the carburization process was undertaken to further understand and quantitatively modeled this process. The effects of key processing parameters (including heat treating temperature, atmosphere, and time) and key materials variables (involving Co content, WC grain size, and addition of grain growth inhibitors) on the formation of Co gradients were examined. Moreover, a carbon-diffusion controlled kinetic model was developed for simulating the formation of the gradient during the process. The parameters involved in this model were determined by thermodynamic calculations and regression-fit of simulation results with experimental data. In summary, this research first demonstrated the principle of the approach

  5. Manufacture of sintered bricks of high density from beryllium oxide; Fabrication de frittes de forte densite a base d'oxyde de beryllium

    Energy Technology Data Exchange (ETDEWEB)

    Pointud, R; Rispal, Ch; Le Garec, M [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    Beryllium oxide bricks of nuclear purity 100 x 100 x 50 and 100 x 100 x 100 mm of very high density (between 2.85 and 3.00) are manufactured by sintering under pressure in graphite moulds at temperatures between 1,750 and 1,850 deg. C, and under a pressure of 150 kg/cm{sup 2}. The physico-chemical state of the saw material is of considerable importance with regard to the success of the sintering operation. In addition, a study of the sintering of a BeO mixture with 3 to 5 per cent of boron introduced in the form of boric acid, boron carbide or elementary boron shows that high densities can only be obtained by sintering under pressure. For technical reasons of manufacture, only the mixture based on boron carbide is used. The sintering is carried out in graphite moulds at 1500 deg. C under 150 kg/cm{sup 2} pressure, and bricks can be obtained with density between 2,85 and 2,90. Laboratory studies and the industrial manufacture of various sinters are described in detail. (author) [French] La fabrication de briques d'oxyde de beryllium de purete nucleaire de 100 x 100 x 50 et de 100 x 100 x 100 mm de densite tres elevee (comprise entre 2.85 et 3.00) est realisee par frittage sous charge dans des moules en graphite entre 1750 et 1850 deg. C, sous 150 kg/cm{sup 2} de pression. L'etat physico-chimique de la matiere premiere a une importance considerable quant au succes de l'operation de frittage. Par ailleurs, l'etude du frittage du mixte BeO a 3 et 5 pour cent de bore element introduit sous forme d'anhydride borique, soit de carbure de bore ou de bore element, montre que seul le frittage sous charge permet d'obtenir des densites elevees. Pour des raisons techniques de fabrication seul le mixte a base de carbure de bore est retenu. Le frittage s'opere dans des moules de graphite a 1500 deg. C sous 150 kg/cm{sup 2} de pression et permet d'obtenir des briques de densite comprise entre 2.85 et 2.90. Les etudes de laboratoire et la fabrication industrielle des differents

  6. Fonctionnement transitoire et controle de la richesse des moteurs à allumage commandé à injection multipoint Transient Operation and Air-Fuel Ratio Control of Spark-Ignition Port-Injected Engines

    Directory of Open Access Journals (Sweden)

    Le Moyne L.

    2006-12-01

    Full Text Available Sur les moteurs à allumage commandé à injection multipoint on observe des désadaptations de richesse lors de fonctionnement transitoire. Ces désadaptations sont dues au dépôt, sous forme de film liquide, du carburant injecté dans le collecteur. Elles peuvent être compensées par une gestion adéquate de la masse injectée. Ainsi, afin d'obtenir la masse de carburant qui maintient la richesse constante, nous avons développé un modèle bidimensionnel des écoulements dans le collecteur au cours du cycle moteur. Ce modèle décrit l'écoulement des gaz frais, des gouttes injectées, des gaz brûlés refoulés vers l'admission et du film sur les parois, sur le principe de la séparation des phases. Nous montrons que le modèle reproduit correctement le signal de richesse et comment il permet de supprimer les désadaptations. La mesure de richesse est faite à l'échappement avec une sonde à oxygène dont nous validons le fonctionnement en transitoire avec une corrélation à la pression maximale du cycle dans le cylindre. Air-fuel ratio excursions are observed on port-injected spark ignition engines during transients. This excursions result from the liquid fuel film deposited on intake port. They can be compensated by controlling the injected fuel mass. In order to have the amount of fuel that keeps air-fuel ratio constant, we have developed a 2D model of flows in the intake port during engine cycle. This separate phases model describes the flow of fresh gases, injected droplets, hot burned gases and film on port walls. We show that the model effectively predicts the equivalence ratio and how it allows to eliminate excursions. Equivalence ratio measures are made with an oxygen sensor which functioning is validated during transients by correlating it to maximal pressure during engine cycle.

  7. Synthesis, structural characterization, and catalytic properties of tungsten-exchanged H-ZSM5

    International Nuclear Information System (INIS)

    Ding, Weiping; Meitzner, George D.; Marler, David O.; Iglesia, Enrique

    2001-01-01

    W-exchanged H-ZSM5 was prepared by sublimation of WCl6 at 673 K followed by hydrolysis of exchanged WClx species at 523 K. D2 exchange with residual OH groups showed that each W initially replaced about two zeolitic protons for W/Al ratios of 0.29 and 0.44, consistent with the formation of (WO2)2+ containing W6+ species bridging two cation exchange sites. As temperatures reached973 K during D2-OH exchange, these species reduced to (WO2)+ with the concurrent formation of one OD group. CH4 conversion turnover rates (per W) and C2-C1 2 selectivities are very similar to those observed on a Mo/H-ZSM5 sample with similar cation exchange level. As in the case of Mo/H-ZSM5, WOx/H-ZSM5 precursors are initially inactive in CH4 reactions, but they activate during induction with the concurrent evolution of CO, H2O, and an excess amount of H2. The reduction and carburization processes occurring during CH4 reactions and the structure of the exchanged WOx precursors was probed using in situ X-ray absorption spectroscopy (XAS). XAS studies confirmed the isolated initial nature of the exchanged WOx precursors after hydrolysis and dehydration and the formation of WCx clusters 0.6 nm in diameter during CH4 reactions at 973 K. The structural and catalytic resemblance between W- and Mo-exchanged H-ZSM5 is not unexpected, in view of chemical similarities between oxides or carbides of Mo and W. The synthesis of exchanged WOx precursors and their subsequent carburization during CH4 reactions, however, are more difficult than the corresponding processes for the MoOx counterparts. This may account for previous reports of lower CH4 reaction rates and aromatics selectivities on W/H-ZSM5 compared with those observed on Mo/H-ZSM5 and with those reported here for rigorously exchanged W/H-ZSM5

  8. Performansi mesin berbahan bakar etanol hasil destilasi arak Bali

    Directory of Open Access Journals (Sweden)

    I Gusti Ketut Sukadana

    2016-12-01

    Full Text Available Abstrak: Perkembangan penelitian tentang proses pengolahan arak sampai saat ini sudah banyak mengalami kemajuan, terlihatdari hasil penelitian tentang energi alternatif berbahan dasar arak. Kemajuan yang dicapai sampai saat ini adalahkualitas arak sebesar 95%. Sudah memenuhi persyaratan sebagai bahan bakar alternativ. Metode yang dipakai dalamusaha mencapai tujuan dari penelitian ini adalah: pertama metode perancangan yaitu merancang alat kondensasipaksa tipe aliran melintang. Kedua, metode eksperimental dengan melaksanakan pengujian pada berbagai variableoperasional seperti variabel laju aliran fluida pendingin yang berpengaruh terhadap laju produksi. Ketiga dilakukanpengujian terhadap unjuk kerja mesin dengan menggunakan arak bali sebagai bahan bakar. Semakin besar bilanganReynolds aliran fluida pendingin mengakibatkan laju pendinginan semakin besar, berpengaruh terhadap lajukondensasi semakin besar sehingga laju produksi semakin besar. Berbanding terbalik dengan kualitas produksi.Pengujian arak bali sebagai bahan bakar pada mesin tipe carburator menghasilkan peningkatan konsentrasi arak baliberpengaruh terhadap semakin besarnya tingkat konsumsi bahan bakar spesifik mesin, torsi mesin mengalamipenurunan dan daya mesin juga mengalami penurunan.Kata kunci: Konveksi paksa, arak, kapasitas, kualitas, bahan bakar, unjuk kerja Abstract: The development of research on the processing of wine it's been a lot of progress, seen from the results of research onalternative energy from the basic ingredients of beer. The progress made today is the quality of the wine production hasabove 95%. So qualify as a fuel. The methods used in order to achieve the objectives of this study are: The first methodof designing is designing and making scientific instruments forced condensation transverse flow type. Second theexperimental method to carry out testing on a variety of operational variables such as the cooling fluid flow ratevariables that affect the rate of

  9. Oxidation of iron and steels by carbon dioxide under pressure (1962); Oxydation du fer et des aciers par l'anhydride carbonique sous pression (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Colombie, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-07-01

    After having developed one of the first thermo-balances to operate under pressure, we have studied the influence of the pressure on the corrosion of iron and steels by carbon dioxide. The corrosion was followed by three different methods simultaneously: by the oxidation kinetics, by micrographs, and by radiocrystallography. We have been able to show that the influence of the pressure is not negligible and we have provided much experimental evidence: oxidation kinetics, micrographic aspects, surface precipitation of carbon, metal carburization, the texture of the magnetite layer. All these phenomena are certainly modified by changes in the carbon dioxide pressure. In order to interpret most of our results we have been led to believe that the phenomenon of corrosion by CO{sub 2} depends on secondary reactions localised at the oxide-gas interface. This would constitute a major difference between the oxidation by CO{sub 2} and that by oxygen. (author) [French] Apres avoir etudie et mis au point une des premieres thermobalances fonctionnant sous pression, nous avons etudie l'influence de la pression sur la corrosion du fer et des aciers par l'anhydride carbonique. Notre etude a ete conduite simultanement sur trois plans differents: etude des cinetiques d'oxydation, etude micrographique et etude radiocristallographique. Nous avons pu montrer que l'influence de la pression n'etait pas negligeable et nous en avons fourni un faisceau de preuves experimentales important: cinetiques d'oxydation, aspect micrographique, precipitation superficielle de carbone, carburation du metal, texture de la couche de magnetite. Tous ces phenomenes sont sans aucun doute modifies par une variation de pression du gaz carbonique. Pour interpreter la plupart de nos resultats, nous avons ete conduits a penser que le phenomene de corrosion par CO{sub 2} etait tributaire de reactions secondaires localisees a l'interface oxyde-gaz. Ce serait la une des differences fondamentales entre l'oxydation par

  10. Influencia de diferentes tratamientos termoquímicos en aceros sinterizados base molibdeno

    Directory of Open Access Journals (Sweden)

    Candela, N.

    2001-04-01

    Full Text Available Prealloyed steel powders with different amount of Mo-Cu-Ni-C were compacted at 700 MPa and sintered at 1120 °C in 95 % N2-5 % H2. After sinterizing, these materials were treated by carburizing. For materials characterization radial crushing strength were preformed, density was calculated and a complete study of fracture surfaces was carried out using scanning electron microscopy. The results of radial crushing strength show that resistance after carburizing is higher than in sintered materials. The fracture surfaces give an idea of materials briteless and the treatment depth. In sintered materials, a dúctil surface was observed, with the characteristic dimples. The fracture surfaces after different treatments show britelessnes in the outer zone, while inside appears a mix of dúctil and briteles fracture.

    Polvos prealeados de aceros con diferentes contenidos de Mo-Cu-Ni -C se compactaron a 700 MPa y se sinterizaron a 1.120 °C en atmósfera de 95 % N2-5 % H2. Después de la sinterización, los materiales se trataron termoquímicamente para su cementación (proceso endogas. Para la caracterización de todos los materiales se realizaron ensayos de compresión del tipo radial crushing strength, se calculó la densidad y se hizo un completo estudio de las superficies de fracturas a través de microscopía electrónica de barrido. Los resultados de resistencia a compresión muestran, después de la cementación, valores superiores a los encontrados en el estado sintetizado. La superficie de fractura da idea de la fragilidad del material y de la profundidad del tratamiento. En estado sintetizado, se observa una superficie de fractura totalmente dúctil, donde aparecen las características cavidades. Las superficies de fractura, tras distintos tipos de cementación, reflejan un comportamiento frágil en el exterior, mientras que el interior aparece una mezcla de fractura dúctil con frágil.

  11. On the Optimal Thermal Management of Hybrid-Electric Vehicles with Heat Recovery Systems Sur le thermo-management optimal d’un véhicule électrique hybride avec un système de récupération de chaleur

    Directory of Open Access Journals (Sweden)

    Merz F.

    2012-09-01

    Full Text Available A general framework to combine optimal energy management (powertrain supervisory control and thermal management in Hybrid Electric Vehicles (HEV is presented. A HEV system with engine exhaust aftertreatment and exhaust heat recovery system is simulated under various scenarios, including warm and cold start. Optimal strategies are derived from Pontryagin Minimum Principle (PMP. The concept of fuel equivalent of thermal energy variations – similar to the equivalence factors for battery energy of standard Equivalent Consumption Minimization Strategy (ECMS – is introduced. The PMP-based strategies are compared with a heuristic, rule-based strategy. The benefits in fuel economy and reduction of pollutant emissions that are obtained for several scenarios are very promising. Une approche généralisée pour combiner la gestion de l’énergie (supervision du groupe motopropulseur et le thermo-management dans les véhicules hybrides électriques est proposée. Un système hybride incluant le post-traitement des polluants et un système de récupération de la chaleur à l’échappement du moteur thermique est simulé pour plusieurs scénarii, y compris le cas de départ à froid. Des stratégies de gestion de l’énergie optimales sont dérivées à partir du Principe de Minimum de Pontriaguine (PMP. Inspirée par les facteurs d’équivalence pour la consommation électrique que l’on retrouve dans la stratégie ECMS, la notion d’équivalent en carburant des flux d’énergie thermique est introduite. Les stratégies dérivées du PMP sont comparées avec une stratégie heuristique basée sur des règles. Les bénéfices en termes d’économies de carburant et réduction des émissions polluantes que l’on trouve pour différents scénarii sont encourageantes.

  12. Improved reaction sintered silicon nitride. [protective coatings to improve oxidation resistance

    Science.gov (United States)

    Baumgartner, H. R.

    1978-01-01

    Processing treatments were applied to as-nitrided reaction sintered silicon nitride (RSSN) with the purposes of improving strength after processing to above 350 MN/m2 and improving strength after oxidation exposure. The experimental approaches are divided into three broad classifications: sintering of surface-applied powders; impregnation of solution followed by further thermal processing; and infiltration of molten silicon and subsequent carburization or nitridation of the silicon. The impregnation of RSSN with solutions of aluminum nitrate and zirconyl chloride, followed by heating at 1400-1500 C in a nitrogen atmosphere containing silicon monoxide, improved RSSN strength and oxidation resistance. The room temperature bend strength of RSSN was increased nearly fifty percent above the untreated strength with mean absolute strengths up to 420 MN/m2. Strengths of treated samples that were measured after a 12 hour oxidation exposure in air were up to 90 percent of the original as-nitrided strength, as compared to retained strengths in the range of 35 to 60 percent for untreated RSSN after the same oxidation exposure.

  13. An electrochemical engineering technique to improve the corrosion resistance of some structural materials in lead-alloy coolants

    International Nuclear Information System (INIS)

    Tacica, M.; Andrei, V.; Rusu, O.; Coaca, E.; Minca, M.; Florea, S.; Oncioiu, G.

    2013-01-01

    The goal of this paper is to present some conclusions resulted from the literature studies referring to the materials potential to be used in Lead Fast Reactors (LFR), and the results obtained in the surface engineering field which can be used in our institute in order to obtain materials with appropriate properties for their use in LFR. In this context, the paper presents some preliminary results obtained in Surface Analysis Laboratory of INR Pitesti and research works in progress referring to: controlled modification of AISI 316 L surface by electrochemical plasma treatment (carburization, nitrocarburizings); electrodeposition of some protective thin-films based on Ni and Al obtained from ionic liquids; development of some procedures related to the activities involved in the behaviour evaluation, in LFR specific conditions, for material samples subjected to treatments by surface engineering techniques using the LEad COrrosion TEsting LOop (LECOTELO) test bench. The superficial structures obtained have been characterized by metallographic microscopy, X-Ray Photoemission Spectroscopy (XPS), Electrochemical Impedance Spectroscopy (EIS); the electrochemical techniques were used to evaluate the corrosion behaviour. The preliminary results have shown that the used electrochemical surface engineering techniques are appropriate in order to improve the mechanical properties and corrosion behaviour of AISI 316 L steel. (authors)

  14. Various categories of defects after surface alloying induced by high current pulsed electron beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Dian [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Tang, Guangze, E-mail: oaktang@hit.edu.cn [School of Material Science & Engineering, Harbin Institute of Technology, Harbin 150001 (China); Ma, Xinxin [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Gu, Le [School of Mechatronics Engineering, Harbin Institute of Technology, Harbin 150001 (China); Sun, Mingren [School of Material Science & Engineering, Harbin Institute of Technology, Harbin 150001 (China); Wang, Liqin [School of Mechatronics Engineering, Harbin Institute of Technology, Harbin 150001 (China)

    2015-10-01

    Highlights: • Four kinds of defects are found during surface alloying by high current electron beam. • Exploring the mechanism how these defects appear after irradiation. • Increasing pulsing cycles will help to get good surface quality. • Choosing proper energy density will increase surface quality. - Abstract: High current pulsed electron beam (HCPEB) is an attractive advanced materials processing method which could highly increase the mechanical properties and corrosion resistance. However, how to eliminate different kinds of defects during irradiation by HCPEB especially in condition of adding new elements is a challenging task. In the present research, the titanium and TaNb-TiW composite films was deposited on the carburizing steel (SAE9310 steel) by DC magnetron sputtering before irradiation. The process of surface alloying was induced by HCPEB with pulse duration of 2.5 μs and energy density ranging from 3 to 9 J/cm{sup 2}. Investigation of the microstructure indicated that there were several forms of defects after irradiation, such as surface unwetting, surface eruption, micro-cracks and layering. How the defects formed was explained by the results of electron microscopy and energy dispersive spectroscopy. The results also revealed that proper energy density (∼6 J/cm{sup 2}) and multi-number of irradiation (≥50 times) contributed to high quality of alloyed layers after irradiation.

  15. DURABILITY AND TRIBOLOGICAL PROPERTIES OF THERMALLY SPRAYED WC CERMET COATING IN LUBRICATED ROLLING WITH SLIDING CONTACT

    Directory of Open Access Journals (Sweden)

    Mohammad Ali

    2010-09-01

    Full Text Available Durability and tribological properties of thermally sprayed WC-Cr-Ni cermet coating were investigated experimentally in lubricated rolling with sliding contact conditions. By means of the high energy type flame spraying (Hi-HVOF method, the coating was formed onto the axially ground and circumferentially ground roller specimens made of a thermally refined carbon steel. In the experiments, the WC cermet coated steel roller was mated with the carburized hardened steel roller without coating in line contact condition. The coated roller was mated with the smooth non-coated roller under a contact pressure of 1.0 or 1.2 GPa, and it was mated with the rough non-coated roller under a contact pressure of 0.6 or 0.8 GPa. As a result, it was found that in general, the coating on the circumferentially ground substrate shows a lower durability compared with that on the axially ground substrate and this difference appears more distinctly for the higher contact pressure for both smooth mating surface and rough mating surface. It was also found that there are significant differences in the tribological properties of WC cermet coating depending on the contact pressure. In addition, depending on the smooth or rough mating surface, remarkable differences in the tribological properties were found.

  16. Effect of Alloying Type and Lean Sintering Atmosphere on the Performance of PM Components

    Science.gov (United States)

    Sundaram, M. Vattur; Shvab, R.; Millot, S.; Hryha, E.; Nyborg, L.

    2017-12-01

    In order to be cost effective and to meet increasing performance demands, powder metallurgy steel components require continuous improvement in terms of materials and process development. This study demonstrates the feasibility of manufacturing structural components using two different alloys systems, i.e. lean Cr-prealloyed and diffusion bonded water atomised powders with different processing conditions. The components were sintered at two different temperatures, i.e. 1120 and 1250 °C for 30 minutes in three different atmospheres: vacuum, N2- 10%H2 atmosphere as well as lean N2-5%H2-0.5%CO-(0.1-0.4)%CH4 sintering atmosphere. Components after sintering were further processed by either low pressure carburizing, sinterhardening or case hardening. All trials were performed in the industrial furnaces to simulate the actual production of the components. Microstructure, fractography, apparent and micro hardness analyses were performed close to the surface and in the middle of the sample to characterize the degree of sintering (temperature and atmosphere) and the effect of heat treatment. In all cases, components possess mostly martensitic microstructure with a few bainitic regions. The fracture surface shows well developed sinter necks. Inter- and trans-granular ductile and cleavage fracture modes are dominant and their fraction is determined by the alloy and processing route.

  17. Study of the structural and mechanical properties of the alloy U-0.2V (weight percent) forged in the α phase

    International Nuclear Information System (INIS)

    Couterne, A.; Guillaume, C.

    1980-01-01

    The effects of forging carried out in the 2 phase on the structural properties of the alloy U-0.2V (evtl.%) carburized or not have been studied. A carbon content of the order of 300 x 10 6 , contrary to the one used for the cast alloy, is neither detrimental to the micrographic structure nor to the mechanical properties of the alloy. The forged plates have a semicrystalline structure with alternative, formed bands, on the one hand by small recrystallization grains, on the other by quite deformed coarse grains. The preferential orientations developed resume to a fibrous structure. The fiber axis, practically the [002] axis, is parallell to the normal to the surface of the forged disc. This result implies a good isotropy of the dilatometric and mechanical properities in the whole plane parallel to the disc faces. A correlation has been made between the found structure and the thermal expansion of the material. Furthermore, the mechanical characteristics reach an excellent level (Rsup(M) approx. 900 MPa, A approx. 38%). (orig.)

  18. Preliminary study on high temperature heat exchanger for nuclear steel making

    Energy Technology Data Exchange (ETDEWEB)

    Nakada, T; Ohtomo, A; Yamada, R; Suzuki, K; Narita, Y [Ishikawajima-Harima Heavy Industries Co. Ltd., Tokyo (Japan)

    1975-05-01

    Both in the high temperature heat exchanger and in the steam reformer, there remain several technical problems to be solved before nuclear steel making is actualized. The loop for use with basic studies of those problems was planned by the Iron and Steel Institute of Japan (ISIJ), and its actual design, construction and co-ordination of tests were undertaken by IHI on behalf of ISIJ. The primary coolant used in the loop was helium having a pressure of approx. 12 kg/cm/sup 2/g and a temperature of approx. 1100/sup 0/C at the inlet of the high temperature heat exchanger, i.e., the test section. Steam, hydrogen, and carbon monoxide were used as secondary coolants. Of the technical problems regarding the high temperature heat exchanger for nuclear steel making, which were selected and studied using the loop, the following items are discussed: (1) heat exchange performance using helium and steam; (2) hydrogen permeation of heat resisting alloys; (3) creep and carburization of heat resisting alloys; amd (4) hydrogen absorption performance of the titanium sponge.

  19. ECOLOGICAL CONTROL EQUIPMENT AND TECHNOLOGY OF UNDERWATER VEGETATION DEVELOPMENT

    Directory of Open Access Journals (Sweden)

    V. TITINSCHNEIDER

    2008-10-01

    Full Text Available The excess of aquatic submerse vegetation development carries to the reduction of the real rearing area for the piscicultural material from the production farms and allow nestling of the ichthyophages bird species that decrease the fish production. Aquatic submerse vegetation stumble the utilization of aquatic zones for recreation and also wright function of basins utilized for the electric energy production, of micro electricity works through obstruction of the dams grid. The control of the aquatic submerse vegetation development, for Myriophyllum verticillatum, Ceratophyllum submersum, Urticularia vulgaris, Potamogeton natans, Nimphoides peltata species it is accomplish through the removing of some parts of these, preferably with all the stump system. Usually, these its accomplish with the floating equipments fit up with the thermic engines and the propulsion and governating elements who have harm over the fish and some others aquatic organisms through the noise, the displacing a large quality of water caused of propulsion systems and through the noxes elimination (flue, carburant trails, etc.. These technologies reside from the evacuation of the aquatic submerse vegetation and the stump systems of these with the help of an adjustable rake, hang up from the coast by a rope, wrapped to a drummer, who is trained by a motto-propeller group with a small installed power.

  20. Contribution to the study of thermal diffusivity of solids; Contribution a l'etude de la diffusivite thermique des solides

    Energy Technology Data Exchange (ETDEWEB)

    Zankel, K. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-07-01

    Angstroem method has been reviewed for its application to measurements of thermal diffusivity and conductivity on short specimens. An apparatus and a technique have been developed for rapid and precise measurements of a large variety of materials, which might also contain heat sources. This technique allows measurements at both high and low temperatures. Stainless steel, nickel and uranium monocarbide specimens were tested and the results of the thermal diffusivity measurements between 50 deg. C and 700 deg. C are presented. (author) [French] L'application de la methode d'Angstroem pour la mesure de la diffusivite et de la conductivite thermique sur des echantillons courts est examinee. Un appareillage est decrit, qui permet non seulement des mesures sur une grande variete de materiaux, mais qui est aussi concu pour des mesures rapides, precises et ou des sources thermiques peuvent etre introduites au sein de l'echantillon. La methode s'adapte egalement aux mesures a basses et hautes temperatures. Des resultats de mesure sur un echantillon en acier inoxydable, en nickel et en carbure d'uranium pour des temperatures comprises entre 50 et 700 deg. C sont reportes. (auteur)

  1. Study of the obtainment of Mo{sub 2}C by gas-solid reaction in a fixed and rotary bed reactor; Estudo da obtencao de Mo{sub 2}C por reacao gas-solido em reator de leito fixo e rotativo

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, C.P.B. de; Souza, C.P. de; Souto, M.V.M.; Barbosa, C.M.; Frota, A.V.V.M., E-mail: cpbaraujo@gmail.com [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2016-07-01

    Carbides' synthesis via gas-solid reaction overcomes many of the difficulties found in other processes, requiring lower temperatures and reaction times than traditional metallurgic routes, for example. In carbides' synthesis in fixed bed reactors (FB) the solid precursor is permeated by the reducing/carburizing gas stream forming a packed bed without mobility. The use of a rotary kiln reactor (RK) adds a mixing character to this process, changing its fluid-particle dynamics. In this work ammonium molybdate was subjected to carbo-reduction reaction (CH4 / H2) in both reactors under the same gas flow (15L / h) and temperature (660 ° C) for 180 minutes. Complete conversion was observed Mo2C (dp = 18.9nm modal particles sizes' distribution) in the fixed bed reactor. In the RK reactor this conversion was only partial (∼ 40%) and Mo2C and MoO3 (34nm dp = bimodal) could be observed on the produced XRD pattern. Partial conversion was attributed to the need to use higher solids loading in the reactor CR (50% higher) to avoid solids to centrifuge. (author)

  2. Formation of carbon nanosheets via simultaneous activation and catalytic carbonization of macroporous anion-exchange resin for supercapacitors application.

    Science.gov (United States)

    Peng, Hui; Ma, Guofu; Sun, Kanjun; Mu, Jingjing; Zhang, Zhe; Lei, Ziqiang

    2014-12-10

    Two-dimensional mesoporous carbon nanosheets (CNSs) have been prepared via simultaneous activation and catalytic carbonization route using macroporous anion-exchange resin (AER) as carbon precursor and ZnCl2 and FeCl3 as activating agent and catalyst, respectively. The iron catalyst in the skeleton of the AER may lead to carburization to form a sheetlike structure during the carbonization process. The obtained CNSs have a large number of mesopores, a maximum specific surface area of 1764.9 m(2) g(-1), and large pore volume of 1.38 cm(3) g(-1). As an electrode material for supercapacitors application, the CNSs electrode possesses a large specific capacitance of 283 F g(-1) at 0.5 A g(-1) and excellent rate capability (64% retention ratio even at 50 A g(-1)) in 6 mol L(-1) KOH. Furthermore, CNSs symmetric supercapacitor exhibits specific energies of 17.2 W h kg(-1) at a power density of 224 W kg(-1) operated in the voltage range of 0-1.8 V in 0.5 mol L(-1) Na2SO4 aqueous electrolyte, and outstanding cyclability (retains about 96% initial capacitance after 5000 cycles).

  3. Material development for gas-cooled high temperature reactors for the production of nuclear process heat

    International Nuclear Information System (INIS)

    Nickel, H.

    1977-04-01

    In the framework of the material development for gas-cooled high temperature reactors, considerable investigations of the materials for the reactor core and the primary cicuit are being conducted. Concerning the core components, the current state-of-the-art and the objectives of the development work on the spherical fuel elements, coated particles and structural graphite are discussed. As an example of the structural graphite, the non-replaceable reflector of the process heat reactor is discussed. The primary circuit will be constructed mainly from metallic materials, although some ceramics are also being considered. Components of interest are hot gas ducts, liners, methane reformer tubes and helium-helium intermediate heat exchangers. The gaseous impurities present in the helium coolant may cause oxidation and carburization of the nickel-base and iron-base alloys envisaged for use in these components, with a possible associated adverse effect on the mechanical properties such as creep and fatigue. Test capacity has therefore been installed to investigate materials behaviour in simulated reactor helium under both constant and alternating stress conditions. The first results on the creep behaviour of several alloys in impure helium are presented and discussed. (orig./GSC) [de

  4. Improvement in surface fatigue life of hardened gears by high-intensity shot peening

    Science.gov (United States)

    Townsend, Dennis P.

    1992-04-01

    Two groups of carburized, hardened, and ground spur gears that were manufactured from the same heat vacuum induction melted vacuum arc melted (VIM VAR) AISI 9310 steel were endurance tested for surface fatigue. Both groups were manufactured with a standard ground 16 rms surface finish. One group was subjected to a shot peening (SP) intensity of 7 to 9A, and the second group was subjected to a SP intensity of 15 to 17A. All gears were honed after SP to a surface finish of 16 rms. The gear pitch diameter was 8.89 cm. Test conditions were a maximum Hertz stress of 1.71 GPa, a gear temperature of 350 K, and a speed of 10000 rpm. The lubricant used for the tests was a synthetic paraffinic oil with an additive package. The following results were obtained: The 10 pct. surface fatigue (pitting) life of the high intensity (15 to 17A) SPed gears was 2.15 times that of the medium intensity (7 to 9A) SPed gears, the same as that calculated from measured residual stress at a depth of 127 microns. The measured residual stress for the high intensity SPed gears was 57 pct. higher than that for the medium intensity SPed gears at a depth of 127 microns and 540 pct. higher at a depth of 51 microns.

  5. Long term performance degradation analysis and optimization of anode supported solid oxide fuel cell stacks

    International Nuclear Information System (INIS)

    Parhizkar, Tarannom; Roshandel, Ramin

    2017-01-01

    Highlights: • A degradation based optimization framework is developed. • The cost of electricity based on degradation of solid oxide fuel cells is minimized. • The effects of operating conditions on degradation mechanisms are investigated. • Results show 7.12% lower cost of electricity in comparison with base case. • Degradation based optimization is a beneficial concept for long term analysis. - Abstract: The main objective of this work is minimizing the cost of electricity of solid oxide fuel cell stacks by decelerating degradation mechanisms rate in long term operation for stationary power generation applications. The degradation mechanisms in solid oxide fuel cells are caused by microstructural changes, reactions between lanthanum strontium manganite and electrolyte, poisoning by chromium, carburization on nickel particles, formation of nickel sulfide, nickel coarsening, nickel oxidation, loss of conductivity and crack formation in the electrolyte. The rate of degradation mechanisms depends on the cell operating conditions (cell voltage and fuel utilization). In this study, the degradation based optimization framework is developed which determines optimum operating conditions to achieve a minimum cost of electricity. To show the effectiveness of the developed framework, optimization results are compared with the case that system operates at its design point. Results illustrate optimum operating conditions decrease the cost of electricity by 7.12%. The performed study indicates that degradation based optimization is a beneficial concept for long term performance degradation analysis of energy conversion systems.

  6. Computational Modeling Develops Ultra-Hard Steel

    Science.gov (United States)

    2007-01-01

    Glenn Research Center's Mechanical Components Branch developed a spiral bevel or face gear test rig for testing thermal behavior, surface fatigue, strain, vibration, and noise; a full-scale, 500-horsepower helicopter main-rotor transmission testing stand; a gear rig that allows fundamental studies of the dynamic behavior of gear systems and gear noise; and a high-speed helical gear test for analyzing thermal behavior for rotorcraft. The test rig provides accelerated fatigue life testing for standard spur gears at speeds of up to 10,000 rotations per minute. The test rig enables engineers to investigate the effects of materials, heat treat, shot peen, lubricants, and other factors on the gear's performance. QuesTek Innovations LLC, based in Evanston, Illinois, recently developed a carburized, martensitic gear steel with an ultra-hard case using its computational design methodology, but needed to verify surface fatigue, lifecycle performance, and overall reliability. The Battelle Memorial Institute introduced the company to researchers at Glenn's Mechanical Components Branch and facilitated a partnership allowing researchers at the NASA Center to conduct spur gear fatigue testing for the company. Testing revealed that QuesTek's gear steel outperforms the current state-of-the-art alloys used for aviation gears in contact fatigue by almost 300 percent. With the confidence and credibility provided by the NASA testing, QuesTek is commercializing two new steel alloys. Uses for this new class of steel are limitless in areas that demand exceptional strength for high throughput applications.

  7. Postirradiation results and evaluation of helium-bonded uranium--plutonium carbide fuel elements irradiated in EBR-II. Interim report

    International Nuclear Information System (INIS)

    Latimer, T.W.; Barner, J.O.; Kerrisk, J.F.; Green, J.L.

    1976-02-01

    An evaluation was made of the performance of 74 helium-bonded uranium-plutonium carbide fuel elements that were irradiated in EBR-II at 38-96 kW/m to 2-12 at. percent burnup. Only 38 of these elements have completed postirradiation examination. The higher failure rate found in fuel elements which contained high-density (greater than 95 percent theoretical density) fuel than those which contained low-density (77-91 percent theoretical density) fuel was attributed to the limited ability of the high-density fuel to swell into the void space provided in the fuel element. Increasing cladding thickness and original fuel-cladding gap size were both found to influence the failure rates for elements containing low-density fuel. Lower cladding strain and higher fission-gas release were found in high-burnup fuel elements having smear densities of less than 81 percent. Fission-gas release was usually less than 5 percent for high-density fuel, but increased with burnup to a maximum of 37 percent in low-density fuel. Maximum carburization in elements attaining 5-10 at. percent burnup and clad in Types 304 or 316 stainless steel and Incoloy 800 ranged from 36-80 μm and 38-52 μm, respectively. Strontium and barium were the fission products most frequently found in contact with the cladding but no penetration of the cladding by uranium, plutonium, or fission products was observed

  8. Compatibility Behavior of the Ferritic-Martensitic Steel Cladding under the Liquid Sodium Environment

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jun Hwan; Baek, Jong Hyuk; Kim, Sung Ho; Lee, Chan Bock [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2012-05-15

    Fuel cladding is a component which confines uranium fuel to transport energy into the coolant as well as protect radioactive species from releasing outside. Sodium-cooled Fast Reactor (SFR) has been considered as one of the most probable next generation reactors in Korea because it can maximize uranium resource as well as reduce the amount of PWR spent fuel in conjunction with pyroprocessing. Sodium has been selected as the coolant of the SFR because of its superior fast neutron efficiency as well as thermal conductivity, which enables high power core design. However, it is reported that the fuel cladding materials like austenitic and ferritic stainless steel react sodium coolant so that the loss of the thickness, intergranular attack, and carburization or decarburization process may happen to induce the change of the mechanical property of the cladding. This study aimed to evaluate material property of the cladding material under the liquid sodium environment. Ferritic-martensitic steel (FMS) coupon and cladding tube were exposed at the flowing sodium then the microstructural and mechanical property were evaluated. mechanical property of the cladding was evaluated using the ring tension test

  9. Sodium effects on mechanical performance and consideration in high temperature structural design for advanced reactors

    Science.gov (United States)

    Natesan, K.; Li, Meimei; Chopra, O. K.; Majumdar, S.

    2009-07-01

    Sodium environmental effects are key limiting factors in the high temperature structural design of advanced sodium-cooled reactors. A guideline is needed to incorporate environmental effects in the ASME design rules to improve the performance reliability over long operating times. This paper summarizes the influence of sodium exposure on mechanical performance of selected austenitic stainless and ferritic/martensitic steels. Focus is on Type 316SS and mod.9Cr-1Mo. The sodium effects were evaluated by comparing the mechanical properties data in air and sodium. Carburization and decarburization were found to be the key factors that determine the tensile and creep properties of the steels. A beneficial effect of sodium exposure on fatigue life was observed under fully reversed cyclic loading in both austenitic stainless steels and ferritic/martensitic steels. However, when hold time was applied during cyclic loading, the fatigue life was significantly reduced. Based on the mechanical performance of the steels in sodium, consideration of sodium effects in high temperature structural design of advanced fast reactors is discussed.

  10. Characterization of a Messer – The late-Medieval single-edged sword of Central Europe

    International Nuclear Information System (INIS)

    Fajfar, Peter; Medved, Jožef; Klančnik, Grega; Lazar, Tomaž; Nečemer, Marijan; Mrvar, Primož

    2013-01-01

    Metallurgical characterization of a sword blade fragments dating from the second half of the 15th century found in central Slovenia was performed in order to determine its chemical composition, microstructure, microhardness, and to obtain insight into the methods of manufacture of a late-medieval Messer sword. As the artefact was broken, examinations were limited to six very small fragments that were allowed to be removed from the cutting edge, core and the back of the blade. Light optical microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, energy dispersive X-ray fluorescence spectrometry, differential scanning calorimetry, thermodynamics approach and Vickers micro-hardness tests were employed to analyze the microstructure and mechanical properties. The results show that the sword was manufactured from a single wrought iron billet. The surface of the sword was carburized. No evidence of quenching was found. The ferritic microstructure is concentrated in the core, and the pearlitic in the outer layer of the blade. All metal fragments contained non-metallic inclusions that were derived mostly from slag and some from hammer scale. - Highlights: • A metallurgical characterization of a medieval sword blade has been performed. • The carbon content decreased from the surface to the core of the blade. • The dominant microstructure in the outer layer is pearlite and in the core is ferrite. • The presence of lump shaped and elongated non-metallic inclusions was observed. • The sword was manufactured from a single wrought iron billet

  11. Influence of hard particle addition and chemical interdiffusion on the properties of hot extruded tool steel compounds

    International Nuclear Information System (INIS)

    Silva, P.A.; Weber, S.; Inden, G.; Pyzalla, A.R.

    2009-01-01

    Low alloyed steel bars were co-extruded with pre-sintered tool steel powders with the addition of tungsten carbides (W 2 C/WC) as hard particles. During the hot extrusion process of these massive and powdery materials, an extrudate is formed consisting of a completely densified wear resistant coating layer and a bulk steel bar as the tough substrate core. This work combines experimental measurements (EPMA) and diffusion calculations (DICTRA TM ) to investigate the effect of hard particle addition and its dissolution, as well as the formation of M 6 C carbides on the properties of two different PM tool steel coatings hot extruded with a 1.2714 steel bar. A carburization effect resulting from the W 2 C hard particles is responsible for an increase of the 1.2344 steel matrix hardness. The mechanical properties of the interface region between coating matrix and substrate are influenced by chemical interdiffusion of carbon and other alloying elements occurring during heat treatment.

  12. Relation Between Residual and Hoop Stresses and Rolling Bearing Fatigue Life

    Science.gov (United States)

    Oswald, Fred B.; Zaretsky, Erwin V.; Poplawski, Joseph V.

    2015-01-01

    Rolling-element bearings operated at high speed or high vibration may require a tight interference fit between the bore of the bearing and shaft to prevent rotation of the bearing bore around the shaft and fretting damage at the interfaces. Previous work showed that the hoop stresses resulting from tight interference fits can reduce bearing lives by as much as 65 percent. Where tight interference fits are required, case-carburized steel such as AISI 9310 or M50 NiL is often used because the compressive residual stresses inhibit subsurface crack formation and the ductile core inhibits inner-ring fracture. The presence of compressive residual stress and its combination with hoop stress also modifies the Hertz stress-life relation. This paper analyzes the beneficial effect of residual stresses on rolling-element bearing fatigue life in the presence of high hoop stresses for three bearing steels. These additional stresses were superimposed on Hertzian principal stresses to calculate the inner-race maximum shearing stress and the resulting fatigue life of the bearing. The load-life exponent p and Hertz stress-life exponent n increase in the presence of compressive residual stress, which yields increased life, particularly at lower stress levels. The Zaretsky life equation is described and is shown to predict longer bearing lives and greater load- and stress-life exponents, which better predicts observed life of bearings made from vacuum-processed steel.

  13. Characterization of a Messer – The late-Medieval single-edged sword of Central Europe

    Energy Technology Data Exchange (ETDEWEB)

    Fajfar, Peter; Medved, Jožef; Klančnik, Grega [Department of Materials and Metallurgy, Faculty of Natural Sciences and Engineering, University of Ljubljana, Aškerčeva cesta 12, SI-1000 Ljubljana (Slovenia); Lazar, Tomaž [National Museum of Slovenia, Prešernova cesta 20, SI-1000 Ljubljana (Slovenia); Nečemer, Marijan [Jožef Stefan Institut, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Mrvar, Primož, E-mail: primoz.mrvar@omm.ntf.uni-lj.si [Department of Materials and Metallurgy, Faculty of Natural Sciences and Engineering, University of Ljubljana, Aškerčeva cesta 12, SI-1000 Ljubljana (Slovenia)

    2013-12-15

    Metallurgical characterization of a sword blade fragments dating from the second half of the 15th century found in central Slovenia was performed in order to determine its chemical composition, microstructure, microhardness, and to obtain insight into the methods of manufacture of a late-medieval Messer sword. As the artefact was broken, examinations were limited to six very small fragments that were allowed to be removed from the cutting edge, core and the back of the blade. Light optical microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, energy dispersive X-ray fluorescence spectrometry, differential scanning calorimetry, thermodynamics approach and Vickers micro-hardness tests were employed to analyze the microstructure and mechanical properties. The results show that the sword was manufactured from a single wrought iron billet. The surface of the sword was carburized. No evidence of quenching was found. The ferritic microstructure is concentrated in the core, and the pearlitic in the outer layer of the blade. All metal fragments contained non-metallic inclusions that were derived mostly from slag and some from hammer scale. - Highlights: • A metallurgical characterization of a medieval sword blade has been performed. • The carbon content decreased from the surface to the core of the blade. • The dominant microstructure in the outer layer is pearlite and in the core is ferrite. • The presence of lump shaped and elongated non-metallic inclusions was observed. • The sword was manufactured from a single wrought iron billet.

  14. Preparation and Fatigue Properties of Functionally Graded Cemented Carbides

    International Nuclear Information System (INIS)

    Liu Yong; Liu Fengxiao; Liaw, Peter K.; He Yuehui

    2008-01-01

    Cemented carbides with a functionally graded structure have significantly improved mechanical properties and lifetimes in cutting, drilling and molding. In this work, WC-6 wt.% Co cemented carbides with three-layer graded structure (surface layer rich in WC, mid layer rich in Co and the inner part of the average composition) were prepared by carburizing pre-sintered η-phase-containing cemented carbides. The three-point bending fatigue tests based on the total-life approach were conducted on both WC-6wt%Co functionally graded cemented carbides (FGCC) and conventional WC-6wt%Co cemented carbides. The functionally graded cemented carbide shows a slightly higher fatigue limit (∼100 MPa) than the conventional ones under the present testing conditions. However, the fatigue crack nucleation behavior of FGCC is different from that of the conventional ones. The crack nucleates preferentially along the Co-gradient and perpendicular to the tension surface in FGCC, while parallel to the tension surface in conventional cemented carbides

  15. Study of the obtainment of Mo_2C by gas-solid reaction in a fixed and rotary bed reactor

    International Nuclear Information System (INIS)

    Araujo, C.P.B. de; Souza, C.P. de; Souto, M.V.M.; Barbosa, C.M.; Frota, A.V.V.M.

    2016-01-01

    Carbides' synthesis via gas-solid reaction overcomes many of the difficulties found in other processes, requiring lower temperatures and reaction times than traditional metallurgic routes, for example. In carbides' synthesis in fixed bed reactors (FB) the solid precursor is permeated by the reducing/carburizing gas stream forming a packed bed without mobility. The use of a rotary kiln reactor (RK) adds a mixing character to this process, changing its fluid-particle dynamics. In this work ammonium molybdate was subjected to carbo-reduction reaction (CH4 / H2) in both reactors under the same gas flow (15L / h) and temperature (660 ° C) for 180 minutes. Complete conversion was observed Mo2C (dp = 18.9nm modal particles sizes' distribution) in the fixed bed reactor. In the RK reactor this conversion was only partial (∼ 40%) and Mo2C and MoO3 (34nm dp = bimodal) could be observed on the produced XRD pattern. Partial conversion was attributed to the need to use higher solids loading in the reactor CR (50% higher) to avoid solids to centrifuge. (author)

  16. Lityum iyon piller için kalay (II oksit kompozit anot elektrotlarının üretimi ve karakterizasyonu

    Directory of Open Access Journals (Sweden)

    Mehmet Oğuz Güler

    2017-04-01

    Full Text Available In this study, the core component of the composite, tin (II oxide powders synthesized through a facile chemical reduction methods for Li-ion batteries. As the shell structure, surfaces of the as-synthesized tin (II oxide particles were coated with carbon through microwave assisted carburization process. The surface morphologies and phase components of the as-synthesized tin (II oxide/carbon composites were investigated via scanning electron microscopy and X-ray diffraction methods, respectively. CR2016 type coin cells were prepared by using tin (II oxide/carbon composite powders and electrochemical tests were performed at room temperature via 8-channel MTI BST8‒MA electrochemical test station between 10 mV and 2.5 V potential range by applying fixed 1 C state of charge conditions. The results have shown that tin (II oxide/carbon composite structure have significantly improved the specific capacities to 396 mAh g-1 after 100 cycles.

  17. In vacuo substrate pretreatments for enhancing nanodiamond formation in electron cyclotron resonance plasma

    International Nuclear Information System (INIS)

    Teii, Kungen; Kouzuma, Yutaka; Uchino, Kiichiro

    2006-01-01

    Substrate pretreatment conditions at low pressures have been examined for enhancing nanocrystalline diamond formation on silicon in electron cyclotron resonance (ECR) plasma. Three kinds of pretreatments (I) exposure to an ECR H 2 plasma with application of a substrate bias from -100 to +30 V (II) hot-filament heating in H 2 gas, and (III) hot-filament heating in vacuum, were used alone or followed by carburization prior to a two-step process of ion-enhanced nucleation in an ECR plasma and subsequent growth in a hot-filament system. The number density of diamond particles after the final growth step was greatly increased up to the order of 10 7 -10 8 cm -2 when applying pretreatment (I) at the bias of 0 V corresponding to the ion-bombardment energy of around 10 eV. In this treatment, a clean and smooth surface with minimal damage was made by the dominance of anisotropic etching by hydrogen ions over isotropic etching by hydrogen atoms. The number density of diamond particles was still more increased when applying pretreatment (II), but the treated surface was unfavorably contaminated and roughened

  18. Sintering of beryllium oxide with 3-4 per cent elemental boron; Frittage de l'oxyde de beryllium a 3 et 5 pour cent de bore element

    Energy Technology Data Exchange (ETDEWEB)

    Pointud, R; Rispal, Ch; Le Garec, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    In order to manufacture a baffle absorbing neutrons of various energies, there was developed or mixture of a slower and an absorber. It is made by hot pressing impure beryllium containing boron carbide. The dense briquette has 100 x 100 x 50 mm and is machined on all her faces. She is of 2,85 density and about 3 to 4 per cent porosity, according to 5 per cent of boron. Difference of boron amount is lower than ten per cent between any two points of the briquette. (author) [French] Pour fabriquer un ecran absorbeur des neutrons d'energies diverses, on a realise l'association d'un element ralentisseur, Ie beryllium, et d'un element absorbant, le bore, par frittage sous charge d'une poudre mixte contenant de l'oxyde de beryllium technique et du carbure de bore technique. Le comprime obtenu est une brique de 100 x 100 x 50 mm, usinee sur toutes sur toutes surfaces, d'une densite de 2,85, porosite d'environ 3 a 4 pour cent pour une teneur en bore de 5 pour cent. L'heterogeneite en bore entre les differents points de cette brique est inferieure a 10 pour cent. (auteur)

  19. Chemical behavior of lanthanides-tungsten composite materials used in thermo-emissive cathodes

    International Nuclear Information System (INIS)

    Cadoret, K.; Cachard, J. de; Martinez, L.; Millot, F.; Hennet, L.; Douy, A.; Licheron, M.

    2001-01-01

    This work presents the crystallography and chemistry of new lanthanides-tungsten composite materials developed to manufacture thermionic cathodes for power grid tubes, based on the same principle than thorium-free cathodes. By mean of x-Ray diffraction at high temperature and under vacuum with synchrotron radiation facilities, we followed in real time the different phases and phase transitions that can occur during the heating process and the carburization at 1550 o C of such tungstates deposits on thin tungsten ribbons. Melting points for composition between 9 La 2 O 3 - 1 WO 3 and 2 La 2 O 3 - 9 WO 3 were specified under the pressure of 1x10 -6 mbar. After interpretation of x-ray diffraction results, phase diagram of n La 2 O 3 - m WO 3 system under vacuum in equilibrium with metallic tungsten have been deduced. Moreover we underline by these works the fact that using a lanthanum-rich tungstate involves better stability and chemical homogeneity of the cathodes surfaces with temperature. (author)

  20. High-temperature resistant, thermally sprayed diffusion barrier coatings on CFC lightweight materials; Hochtemperaturbestaendige, thermisch gespritzte Diffusionsbarriereschichten auf CFC-Leichtbauchargiergestellen

    Energy Technology Data Exchange (ETDEWEB)

    Drehmann, Rico; Rupprecht, Christian; Wielage, Bernhard; Lampke, Thomas [Technische Univ. Chemnitz (Germany). Inst. fuer Werkstoffwissenschaft und Werkstofftechnik (IWW); Gilbert, Maria; Uhlig, Volker; Trimis, Dimosthenis [Technische Univ. Bergakademie Freiberg (Germany). Inst. fuer Waermetechnik und Thermodynamik (IWTT); Heuer, Volker [ALD Vacuum Technologies GmbH, Hanau (Germany)

    2013-03-15

    In heat treating processes as well as in high temperature brazing processes, charge carriers enable the positioning and transport of work pieces. Recently, charge carriers consisting of graphite or carbon fibre reinforced carbon (CFC) are used. The main disadvantage of charge carriers based on CFC is the undesirable carburization of the overlying components due to diffusion processes. Under this aspect, thermally sprayed coatings are applied on CFC and tested with respect to their suitability as a high-temperature diffusion barrier. The ceramic powders aluminium oxide, aluminium oxide/chromium oxide, aluminium oxide/titanium oxide and zirconium oxide/yttrium oxide are used as a coating material which is processed by means of the powder flame spraying as well as atmospheric plasma spraying. Molybdenum and silicon carbide are used as an adhesive layer. The coating materials aluminium oxide and aluminium oxide/chromium oxide on siliconized CFC presented excellent results. This supplies a large potential of application for thermally sprayed ceramic coatings on carbon-based lightweight materials.

  1. La fermentation acétonobutylique. Synthèse bibliographique et orientations actuelles Butanol-Acetone Fermentation. Bibliographie Synthesis and Current Trends

    Directory of Open Access Journals (Sweden)

    Marchal R.

    2006-11-01

    Full Text Available Cet article présente une synthèse des connaissances sur la fermentation acétonobutylique tant d'un point de vue microbiologique que technologique. Divers aspects du métabolisme et de la régulation du microorganisme mis en oeuvre sont abordés. Les performances de la fermentation sur ses substrats traditionnels (farine de maïs ou mélasses sont comparées avec celles qui ont été récemment obtenues à partir du topinambour à l'Institut Français du Pétrole, dans le cadre d'un nouveau développement de cette fermentation pour la production de carburants. This article gives a synthesis of what is known about butylacetone fermentation from both the microbiological and technological standpoints. Different aspects of the metabolism of the microorganism used and of how it is regulated are considered. The performances of fermentation on traditional substrates (cornmeal or molasses are compared with those recently obtained using Jerusalem artichokes at Institut Français du Pétrole as part of a new project on this fermentation for the purpose of producing substitute fuel.

  2. Real time monitoring of filament-assisted chemically vapor deposited diamond by spectroscopic ellipsometry

    International Nuclear Information System (INIS)

    Yue Cong; An, I.; Vedam, K.; Collins, R.W.; Nguyen, H.V.; Messier, R.

    1991-01-01

    Spectroscopic ellipsometry over the range 1.5-4.5 eV was applied as a real time probe of the processes occurring in the initial nucleation of thin film diamond by heated-filament assisted chemical vapor deposition. Using both untreated and diamond-polished c-Si substrates, as well as both carburized and uncarburized tungsten filaments, it was possible to separate and characterize competing phenomena, including the increase in surface temperature induced by filament ignition, the formation of carbide layers, contamination of the substrate by tungsten from the filament, annealing of diamond polishing damage, and, finally, diamond nucleation. An accurate measurement of the true temperature of the substrate surface averaged over the top 500 A can be obtained from the energy position of critical points in the c-Si band structure. For diamond deposition, we operated with an initial excess flow of CH 4 to stimulate nucleation. We applied real time feedback and manual control to reduce the CH 4 flow in the first monolayers of deposition. The thickness of diamond and an estimate of its nucleation density can be obtained from real time spectra, and the latter was in good agreement with that obtained from scanning electron microscopy. (orig.)

  3. Corrosion tests in Baltic sea water on heat exchanger tubes of various metallic materials

    International Nuclear Information System (INIS)

    Henrikson, S.; Knutsson, L.

    1975-05-01

    Seventeen different tube materials have been exposed to continuous and intermittent flow in Baltic Sea water (0.4 % Cl - ) at 50 deg C for a maximum of 15 000 hours. During testing the specimens have been examined at certain intervals. After testing the specimens have been examined visually and metallographically. The following materials were completely resistant: titanium, CuNi30Mn1Fe, Alloy 825 and the austenitic steels Cr18Ni24Mo4.5, Cr20Ni25Mo4.5Cu and Cr24Ni24Mo2Ti. The ferritic-austenitic steels Cr18Ni5Mo2Si and Cr25Ni5Mo1.5 on the other hand, seem to be attacked by local intercrystalline corrosion in the vicinity of the welds. The same type of attack occurs, against expectations, even in the entirely ferritic steels, especially in Cr21Mo3Ti; this attack was however shown to be caused by surface carburization. Admiralty brass (2.5 m/s), aluminium brass (3.0 m/s) and CuNi10Fe1Mn (3.5 m/s) have been attacked by erosion corrosion. The same type of attack, although to a considerably smaller extent, has also been observed for the three aluminium materials (2.5 m/s). (author)

  4. Sintering of beryllium oxide with 3-4 per cent elemental boron; Frittage de l'oxyde de beryllium a 3 et 5 pour cent de bore element

    Energy Technology Data Exchange (ETDEWEB)

    Pointud, R.; Rispal, Ch.; Le Garec, M. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    In order to manufacture a baffle absorbing neutrons of various energies, there was developed or mixture of a slower and an absorber. It is made by hot pressing impure beryllium containing boron carbide. The dense briquette has 100 x 100 x 50 mm and is machined on all her faces. She is of 2,85 density and about 3 to 4 per cent porosity, according to 5 per cent of boron. Difference of boron amount is lower than ten per cent between any two points of the briquette. (author) [French] Pour fabriquer un ecran absorbeur des neutrons d'energies diverses, on a realise l'association d'un element ralentisseur, Ie beryllium, et d'un element absorbant, le bore, par frittage sous charge d'une poudre mixte contenant de l'oxyde de beryllium technique et du carbure de bore technique. Le comprime obtenu est une brique de 100 x 100 x 50 mm, usinee sur toutes sur toutes surfaces, d'une densite de 2,85, porosite d'environ 3 a 4 pour cent pour une teneur en bore de 5 pour cent. L'heterogeneite en bore entre les differents points de cette brique est inferieure a 10 pour cent. (auteur)

  5. Contribution to the study of thermal diffusivity of solids; Contribution a l'etude de la diffusivite thermique des solides

    Energy Technology Data Exchange (ETDEWEB)

    Zankel, K [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1967-07-01

    Angstroem method has been reviewed for its application to measurements of thermal diffusivity and conductivity on short specimens. An apparatus and a technique have been developed for rapid and precise measurements of a large variety of materials, which might also contain heat sources. This technique allows measurements at both high and low temperatures. Stainless steel, nickel and uranium monocarbide specimens were tested and the results of the thermal diffusivity measurements between 50 deg. C and 700 deg. C are presented. (author) [French] L'application de la methode d'Angstroem pour la mesure de la diffusivite et de la conductivite thermique sur des echantillons courts est examinee. Un appareillage est decrit, qui permet non seulement des mesures sur une grande variete de materiaux, mais qui est aussi concu pour des mesures rapides, precises et ou des sources thermiques peuvent etre introduites au sein de l'echantillon. La methode s'adapte egalement aux mesures a basses et hautes temperatures. Des resultats de mesure sur un echantillon en acier inoxydable, en nickel et en carbure d'uranium pour des temperatures comprises entre 50 et 700 deg. C sont reportes. (auteur)

  6. Thermoanalytical investigation of the hydrogen absorption behaviour of Sm2Fe17-xGax at high hydrogen pressures

    International Nuclear Information System (INIS)

    Handstein, A.; Kubis, M.; Gebel, B.; Mueller, K.-H.; Schultz, L.; Gutfleisch, O.; Harris, I.R.; Birmingham Univ.

    1998-01-01

    The complete disproportionation of Sm 2 Fe 17-x Ga x during annealing in hydrogen is hindered due to an increased stability of the compounds with a higher Ga content (x ≥ 1). Therefore the HD process as the first step of HDDR (hydrogenation-disproportionation-desorption-recombination) has to be carried out at a high hydrogen pressure for x ≥ 1. The hydrogen absorption behaviour of Sm 2 Fe 17-x Ga x (x = 0, 0.5, 1 and 2) was investigated by means of hydrogen differential thermal analysis (HDTA) and high pressure differential scanning calorimetry (HPDSC) at hydrogen pressures up to 70 bar. A dependency of hydrogenation and disproportionation temperatures on hydrogen pressure and Ga content was found. The comparison with other substituents (M = Al and Si) instead of M = Ga showed an increased stability of Sm 2 Fe 17-x M x compounds against disproportionation by hydrogen in the sequence Al, Ga and Si. The Curie temperatures of the interstitially hydrogenated Th 2 Zn 17 -type materials increase with the hydrogen pressure. In order to produce coercive and thermally stable Sm 2 Fe 15 Ga 2 C y powder by means of the HDDR process, we recombined material disproportionated at different hydrogen pressures. Preliminary results of magnetic properties of this HDDR treated and gas-carburized Sm 2 Fe 15 Ga 2 C y are discussed. (orig.)

  7. Preparation of Sm2Fe17-xGaxNy/Cy magnets by a hydrogenation-disproportionation-desorption-recombination process

    International Nuclear Information System (INIS)

    Kubis, M.; Cao, L.; Handstein, A.; Gebel, B.; Mueller, K.; Schultz, L.

    1997-01-01

    A hydrogenation-disproportionation-desorption-recombination process (HDDR) was applied to Sm 2 Fe 17-x Ga x (x=0.5, 1, and 2). The process was studied by means of temperature-pressure analysis, x-ray diffraction and scanning electron microscopy. It was shown that Ga not only stabilizes the interstitially modified compounds Sm 2 Fe 17-x Ga x C y (0 2 Fe 17-x Ga x against the disproportionation by hydrogen. Therefore, only for x=0.5 can a nearly complete HDDR be performed. The HDDR-treated and subsequently nitrogenated or carburized samples show coercivities μ 0J H C up to 3.1 T and 2.5 T, respectively. Hot compaction increases the density of the Sm 2 Fe 16.5 Ga 0.5 C y powder; however, it leads to a loss of coercivity due to decomposition into α-iron and samarium carbides. copyright 1997 American Institute of Physics

  8. Nd:YOV4 laser surface texturing on DLC coating: Effect on morphology, adhesion, and dry wear behavior

    Science.gov (United States)

    Surfaro, Maria; Giorleo, Luca; Montesano, Lorenzo; Allegri, Gabriele; Ceretti, Elisabetta; La Vecchia, Giovina Marina

    2018-05-01

    The surface of structural components is usually subjected to higher stresses, greater wear or fatigue damage, and more direct environmental exposure than the inner parts. For this reason, the interest to improve superficial properties of items is constantly increasing in different fields as automotive, electronic, biomedical, etc. Different approaches can be used to achieve this goal: case hardening by means of superficial heat treatments like carburizing or nitriding, deposition of thin or thick coatings, roughness modification, etc. Between the available technologies to modify components surface, Laser Surface Texturing (LST) has already been recognized in the last decade as a process, which improves the tribological properties of various parts. Based on these considerations the aim of the present research work was to realize a controlled laser texture on a Diamond-like Carbon (DLC) thin coating (about 3 µm thick) without damaging both the coating itself and the substrate. In particular, the effect of laser process parameters as marking speed and loop cycle were investigated in terms of texture features modifications. Both qualitative and quantitative analyses of the texture were executed by using a scanning electron microscope and a laser probe system to select the proper laser parameters. Moreover, the effect of the selected texture on the DLC nanohardness, adhesion and wear behavior was pointed out.

  9. Carbon potential measurement on some actinide carbides

    International Nuclear Information System (INIS)

    Anthonysamy, S.; Ananthasivan, K.; Kaliappan, I.; Chandramouli, V.; Vasudeva Rao, P.R.; Mathews, C.K.; Jacob, K.T.

    1994-01-01

    Uranium-Plutonium mixed carbides with a Pu/(U+Pu) ratio of 0.55 are to be used as the fuel in the Fast Breeder Test Reactor (FBTR) at Kalpakkam, India. Carburization of the stainless steel clad by this fuel is determined by its carbon potential. Because the carbon potential of this fuel composition is not available in the literature, it was measured by the methane-hydrogen gas equilibration technique. The sample was equilibrated with purified hydrogen and the equilibrium methane-to-hydrogen ratio in the gas phase was measured with a flame ionization detector. The carbon potential of the ThC-ThC 2 as well as Mo-Mo 2 C system, which is an important binary in the actinide-fission product-carbon systems, were also measured by this technique in the temperature range 973 to 1,173 K. The data for the Mo-Mo 2 C system are in agreement with values reported in the literature. The results for the ThC-ThC 2 system are different from estimated values with large uncertainty limits given in the literature. The data on (U, Pu) mixed carbides indicates the possibility of stainless steel clad attack under isothermal equilibrium conditions

  10. How much life is left in your olefin unit

    International Nuclear Information System (INIS)

    Baas, J.; Warner, R.

    1992-01-01

    Highly attractive economics in the olefin industry has justified increasing capacity via plant expansion and using aging olefin units beyond expected limitations. If these existing units are to operate well beyond their design life, what type of analysis and information is necessary to make this decision? What technologies or methods should be used for continued safe and controlled operation of these not so new units. This paper reports that the plant's mechanical integrity is the focal point of this analysis and decision-making method. Plant life expectancy study (PLES) looks at an operating plant's mechanical integrity from several vantage points. Four basic principles, such as plant history, process upsets and operating records, assessment of plant fires, and how to conduct records, assessment of plant fires, and how to conduct inspection and testing, provide the basis of how well a plant has been operated and maintained. Furthermore, the analysis includes a critical component inventory. These items address additional potential-failure causes, such as creep, fatigue, toughness, corrosion, erosion and carburization/oxidation

  11. UKAEA mechanical test work in sodium

    International Nuclear Information System (INIS)

    Wood, D.S.

    1977-01-01

    The main aim of the UKAEA work is to perform mechanical tests in high quality sodium, and on the basis of relatively long term tests to establish whether factors need to be applied to the air data for the design and assessment of components which will have to operate in sodium for up to 30 years. Most of the tests will be performed in sodium containing 5-10 ppm O 2 and ∼ 1 ppm C with a flow rate over the specimen surface of 3m/sec. Some work is also planned to establish the effect of changes in oxygen level up to 30 ppm on the properties and carburization studies will also be performed. Thin work has been in progress on a limited scale for 2-3 years but is now increasing in magnitude to meet the programme requirements. The materials under test include Type 316 steel and 9% Cr steel with most emphasis being placed on the austenitic steel. From the very limited fatigue and stress rupture tests so far performed on Type 316 steel there is no evidence to suggest that high purity sodium may be detrimental. Longer term tests are necessary however to confirm this finding which is based on results from relatively short term tests. Tests are also necessary in less pure sodium

  12. Content of nitrogen in waste petroleum carbon for steel industries

    International Nuclear Information System (INIS)

    Rios, R.O; Jimenez, A.F; Szieber, C.W; Banchik, A.D

    2004-01-01

    Steel industries use refined carbon as an alloy for steel production. This alloy is produced from waste carbon from the distillation of the petroleum. The refined carbon, called recarburizer, is obtained by calcination at high temperature. Under these thermal conditions the organic molecules decompose and a fraction of the N 2 , S and H 2 , volatile material and moisture are released; while the carbon tends to develop a crystalline structure similar to graphite's. The right combination of calcinations temperature and time in the furnace can optimize the quality of the resulting product. The content of S and N 2 has to be minimized for the use of calcined carbon in the steel industry. Nitrogen content should be reduced by two orders of magnitude, from 1% - 2% down to hundreds of ppm by weight. This work describes the activities undertaken to obtain calcined coke from petroleum from crude oil carbon that satisfies the requirements of the Mercosur standard 02:00-169 (Pending) for use as a carborizer in steels industries. To satisfy the requirements of the Mercosur standards NM 236:00 IRAM-IAS-NM so that graphite is used as a carburizer a content of 300 ppm maximum weight of nitrogen has to be obtained. So the first stage in this development is to define a production process for supplying calcined coke in the range of nitrogen concentrations required by the Mercosur standards (CW)

  13. Assessing corrosion in oil refining and petrochemical processing

    Directory of Open Access Journals (Sweden)

    Randy C. John

    2004-03-01

    Full Text Available This paper summarizes the development of an information system used to manage corrosion of metals and alloys by high temperature gases found in many different oil refining, petrochemical, power generation, and chemical processes. The database currently represents about 7.9 million h of exposure time for about 5,500 tests with 89 commercial alloys for a temperature range of 200 - 1,200°C. The system manages corrosion data from well-defined exposures and determines corrosion product stabilities. New models used in the analysis of thermochemical data for the Fe-Ni-Cr-Co-C-O-S-N-H system are being compiled. All known phases based upon combinations of the elements have been analyzed to allow complete assessments of corrosion product stabilities. Use of these data allows prediction of stable corrosion products and hence identification of the possible dominant corrosion mechanisms. The system has the potential to be used in corrosion research, alloy development, failure analysis, lifetime prediction, and process operations evaluations. The corrosion mechanisms emphasized are oxidation, sulfidation, sulfidation/oxidation, and carburization.

  14. The metallurgy of superalloys part 2

    International Nuclear Information System (INIS)

    Abdelazim, M.E.; Hammad, F.H.

    1990-01-01

    This is part II of the report titled 'the metallurgy of superalloys'. It deals with the effect of heat treatment and operating conditions (thermal exposure and environment) on the mechanical properties of superalloys. The heat treatment is important in the development of superalloys through that it controls type, amount, size shape and distribution of the precipitate and the grain size of the matrix. The thermal exposure leads to reduction in the amount of the primary carbides and to precipitation of secondary carbides. Also it leads to the agglomeration and coarsening of gamma or the transformation of gamma phase to phase. The environment may lead to the internal oxidation, carburization, decarburization or sulphidization of the superalloys which may result in the degradation of their mechanical properties. This part gives also an example of applications of superalloys in the field of nuclear reactors especially high temperature-gas cooled reactors. Joined with this part a table which contains the major superalloys including its chemical analysis, creep rupture strength and some of its applications. 1 tab

  15. X-ray photoelectron spectroscopy studies of hard coatings formed by titanium on 304 stainless steel

    International Nuclear Information System (INIS)

    Nair, M.R.; Kothari, D.C.; Rangwala, A.A.; Lal, K.B.; Prabhawalkar, P.D.; Raole, P.M.

    1986-01-01

    Titanium ions are implanted (at 30 keV) in 304 stainless steel to a dose of 1.8x10 17 ions cm -2 using 15 μA cm -2 and 5 μA cm -2 beam current densities for specimens 2 and 3 respectively. X-ray photoelectron spectroscopy (XPS) measurements are performed at different temperatures. The microhardness of implanted and unimplanted specimens is also measured. In specimen 2 the microhardness does not increase significantly and XPS measurements give evidence of carburized surface alloy formation. At 250 0 C TiO 2 is detected on the surface and it migrates into the bulk phase above 350 0 C. In specimen 3 the XPS measurements exhibit an absence of iron owing to the radiation-induced segregation of titanium on the surface. This specimen shows an increase in microhardness. The XPS measurements reveal a layer of (TiC x -C) on the surface which is suggested to be responsible for the increase in microhardness. Upon heating, TiC x is seen to move into the bulk phase and the carbon concentration is increased. These changes occurring at higher temperatures are suggested as having an effect on the wear-resistant properties of titanium-implanted 304 stainless steel. (orig.)

  16. Silicon effects on formation of EPO oxide coatings on aluminum alloys

    International Nuclear Information System (INIS)

    Wang, L.; Nie, X.

    2006-01-01

    Electrolytic plasma processes (EPP) can be used for cleaning, metal-coating, carburizing, nitriding, and oxidizing. Electrolytic plasma oxidizing (EPO) is an advanced technique to deposit thick and hard ceramic coatings on a number of aluminum alloys. However, the EPO treatment on Al-Si alloys with a high Si content has rarely been reported. In this research, an investigation was conducted to clarify the effects of silicon contents on the EPO coating formation, morphology, and composition. Cast hypereutectic 390 alloys (∼ 17% Si) and hypoeutectic 319 alloys (∼ 7% Si) were chosen as substrates. The coating morphology, composition, and microstructure of the EPO coatings on those substrates were investigated using scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis and X-ray diffraction (XRD). A stylus roughness tester was used for surface roughness measurement. It was found that the EPO process had four stages where each stage was corresponding to various coating surface morphology, composition, and phase structures, characterised by different coating growth mechanisms

  17. Low-cycle fatigue of heat-resistant alloys in high-temperature gas-cooled reactor helium

    International Nuclear Information System (INIS)

    Tsuji, H.; Kondo, T.

    1984-01-01

    Strain controlled low-cycle fatigue tests were conducted on four nickel-base heat-resistant alloys at 900 0 C in simulated high-temperature gas-cooled reactor (HTGR) environments and high vacuums of about 10 -6 Pa. The observed behaviors of the materials were different and divided into two groups when tests were made in simulated HTGR helium, while all materials behaved similarly in vacuums. The materials that have relatively high ductility and compatibility with impure helium at test temperature showed considerable resistance to the fatigue damage in impure helium. On the other hand, the alloys qualified with their high creep strength were seen to suffer from the adverse effects of impure helium and the trend of intergranular cracking as well. The results were analyzed in terms of their susceptibility to the environmentenhanced fatigue damage by examining the ratios of the performance in impure helium to in vacuum. The materials that showed rather unsatisfactory resistance were considered to be characterized by their limited ductility partly due to their coarse grain structure and susceptibility to intergranular oxidation. Moderate carburization was commonly noted in all materials, particularly at the cracked portions, indicating that carbon intrusion had occurred during the crack growth stage

  18. Scalable production of Cu@C composites for cross-coupling catalysis

    Energy Technology Data Exchange (ETDEWEB)

    Bu, Lijuan [Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081 (China); Ming, Hai, E-mail: lunaticmh@163.com [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China)

    2015-10-15

    Highlights: • Cu@C core–shell composite was prepared by reduction of [Cu(NH{sub 3}){sub 4}]{sup 2+} with glucose. • The carbon shell in Cu@C can be tuned to the different degree of carbonization. • The Cu@C composites were utilized to catalyze the C−N cross coupling reaction. • The catalytic ability of Cu@C depends on the degree of shell-carbonization. - Abstract: A novel Cu@C core–shell microstructure was prepared by reduction of [Cu(NH{sub 3}){sub 4}]{sup 2+} with glucose using a mild hydrothermal process. The carbon shell of such Cu@C composite can be tuned to different carbonization degrees just through varying the calcination conditions. The structural properties of as-prepared Cu@C were investigated in detail by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron micrographs (TEM) and Raman spectra. In addition, these Cu@C composites were firstly used to catalyze the C−N cross coupling of amines with iodobenzene. Among them, the catalytic ability of Cu@C composites increased as their surface carbon’s carburization degree improved.

  19. Reactions between sodium and various carbon bearing compounds

    Energy Technology Data Exchange (ETDEWEB)

    Raine, A C; Thorley, A W [UKAEA, Risley, Warrington, Cheshire (United Kingdom)

    1980-05-01

    The presence of carbon bearing materials in liquid sodium is undesirable because of their ability to carburise stainless steel components. It has been demonstrated for example that carbon taken up by stainless steels can affect their mechanical properties and that thinner sectioned material such as fuel cladding and the tubing of intermediate heat exchanger may be more sensitive to such effects. Generally speaking, there are a number of potential carbon sources in reactor systems. Some of the sources such as the graphite in neutron shield rods, boron carbide in control rods and carbide fuels are part of the reactor designs while others such as oil in mechanical pumps arid 'coupling-fluids' used to inspect plant components are associated with the respective operation arid inspection of the plant. In this paper it is intended to discuss in general terms the way these various compounds behave in liquid sodium and to assess what effect their presence will have on the materials of construction in fast reactor systems. The paper also reviews the chemistry of the environment in relation to the types of carburizing species which may exist in sodium systems.

  20. Effects of Mars Atmosphere on Arc Welds: Phase 2

    Science.gov (United States)

    Courtright, Z. S.

    2018-01-01

    Gas tungsten arc welding (GTAW) is a vital fusion welding process widely used throughout the aerospace industry. Its use may be critical for the repair or manufacture of systems, rockets, or facilities on the Martian surface. Aluminum alloy AA2219-T87 and titanium alloy Ti-6Al-4V butt welds have been investigated for weldability and weld properties in a simulated Martian gas environment. The resulting simulated Martian welds were compared to welds made in a terrestrial atmosphere, all of which used argon shielding gas. It was found that GTAW is a process that may be used in a Martian gas environment, not accounting for pressure and gravitational effects, as long as adequate argon shielding gas is used to protect the weld metal. Simulated Martian welds exhibited higher hardness in all cases and higher tensile strength in the case of AA2219-T87. This has been attributed to the absorption of carbon into the fusion zone, causing carbide precipitates to form. These precipitates may act to pin dislocations upon tensile testing of AA2219-T87. Dissolved carbon may have also led to carburization, which may have caused the increase in hardness within the fusion zone of the welds. Based on the results of this experiment and other similar experiments, GTAW appears to be a promising process for welding in a Martian gas environment. Additional funding and experimentation is necessary to determine the effects of the low pressure and low gravity environment found on Mars on GTAW.

  1. Effect of Shot Peening on Tribological Behaviors of Molybdenum-Thermal Spray Coating using HVOF Method

    Directory of Open Access Journals (Sweden)

    H. Mohassel

    2017-03-01

    Full Text Available We have investigated the influence of post-shot peening on Mo-coating as compared to substrate steel 16MnCr5 (according to ZFN-413 A. Shot peening of carburized steel discs with and without Mo-coating was performed by using Shot size S230, Almen intensity 0.42 mm ’A’ and exposure time 96 sec. Tribological properties were analyzed, using pin-on-disc tribometer apparatus, under dry sliding conditions at different specific applied loads, sliding velocities and distance. Typical standardized methods were used for studying of surface integrity parameters (micro-hardness, topography and surface roughness. Surface morphology of the Mo-coating specimens with and without Shot Peening before and after wear was evaluated by Scanning Electron Microscopy. The results showed that shot peening after Mo-coating has considerable effect on improving wear resistance and because of having low friction coefficient has showed better wear behavior and tribologi cal properties over that of the un-peened Mo-coating.

  2. Creep-rupture behavior of 2-1/4 Cr-1 Mo steel, Alloy 800H and Hastelloy Alloy X in a simulated HTGR helium environment

    International Nuclear Information System (INIS)

    Lai, G.Y.; Wolwowicz, R.J.

    1979-12-01

    Creep-rupture testing was conducted on 1 1/4 Cr-1 Mo steel, Alloy 800H and Hastelloy Alloy X in flowing helium containing nominal concentration of following gases: 1500 μatm H 2 , 450 μatm CO, 50 μatm CH 4 , 50 μatm H 2 O and 5 μatm CO 2 . This environment is believed to represent maximum permissible levels of impurities in the primary coolant for the steam-cycle system of a high-temperature gas-cooled reactor (HTGR) when it is operating continuously with a water and/or steam leak at technical specification limits. Two or three heats of material for each alloy were investigated. Tests were conducted at 482 0 C and 760 0 C (1200 0 F and 1400 0 F) for Alloy 800H, and at 760 0 C and 871 0 C (1400 0 F and 1600 0 F) for Hastelloy Alloy X for times up to 10,000 h. Selected tests were performed on same heat of material in both air and helium environments to make a direct comparison of creep-rupture behaviors between two environments. Metallurgical evaluation was performed on selected post test specimens with respect to gas-metal interactions which included oxidation, carburization and/or decarburization. Correlation between gaseous corrosion and creep-rupture behavior was attempted. Limited tests were also performed to investigate the specimen size effects on creep-rupture behavior in the helium environment

  3. Effects of Impurity on the Corrosion Behavior of Alloy 617 in the Helium Environment

    International Nuclear Information System (INIS)

    Jung, Sujin; Kim, Dong Jin; Lee, Gyeong Geun

    2013-01-01

    The helium coolant in the primary circuit inevitably includes minor impurities such as H 2 , CO, CH 4 , and H 2 O under operating condition. Material degradation is aggravated through oxidation, carburization, and decarburization under the impure helium environment. In this study, high-temperature corrosion tests were carried out at 850-950 .deg. C in the impure helium environment. The mass changes of the specimens were measured and the microstructures were analyzed quantitatively. In addition, all corrosion tests were conducted in the pure helium environment and the results were compared to the results under the impure helium. Alloy 617 specimens showed a parabolic oxidation behavior at all temperatures under the impure helium environment. All specimens had similar microstructure in the outer Cr-oxide layers, internal Al-oxides, and carbide-depleted zone. The weight increase of the corroded specimens in the pure helium was relatively reduced. Microstructure result, oxide layer and carbide depleted zone were hardly ever observed. The impurity in helium affected the corrosion behavior of Alloy 617 and may cause a decrease in the mechanical properties. Therefore, the control of minor impurities in VHTR helium is necessary for the application of Alloy 617 to the IHX material of a VHTR

  4. Manufacturing technology development of plasma/ion nitriding for improvement of hardness of machine components and tools

    International Nuclear Information System (INIS)

    Suprapto; Tjipto Sujitno; Saminto

    2015-01-01

    The manufacturing technology development of plasma/ion nitriding to improve of hardness of machine components and tools has been done. The development of this technology aims to improve device performance plasma nitriding double chamber and conducted with the addition of thermal radiation shield. Testing was done by testing for preheating operation (start-up), test operation for conditions nitriding and test for nitriding process. The results show that: the plasma nitriding device can be operated for nitriding process at the temperature of about 500 °C for 6 hours, using the thermal radiation shield obtained outside wall temperature of about 65 °C and shorten start-up time to about 60 minutes. The use of thermal radiation shield can also improve the efficiency of the electric power supply and increase the operating temperature for nitriding process. Test for nitriding obtained increase of hardness 1.33 times for the original camshaft (genuine parts) and 1.8 times for the imitation camshaft (imitation parts), the results are compared with after the tempering process at a temperature of 600 °C. For sample SS 304 was 2.45 times compared with before nitrided These results indicate that the development of manufacturing technology of plasma/ion nitriding to increase hardness of machine components and tools have been successfully able to increase the hardness, although still need to be optimized. Besides that, these devices can be developed to use for the process of carburizing and carbonitriding. (author)

  5. Impact of H2/CO ratios on phase and performance of Mn-modified Fe-based Fischer Tropsch synthesis catalyst

    International Nuclear Information System (INIS)

    Ding, Mingyue; Yang, Yong; Li, Yongwang; Wang, Tiejun; Ma, Longlong; Wu, Chuangzhi

    2013-01-01

    Highlights: ► Decreasing H 2 /CO ratio facilitated the conversion of Fe 3 O 4 to iron carbides on the surface layers. ► The formation of surface carbonaceous species was promoted in higher CO partial pressure. ► The formation of iron carbides on the surface of Fe 3 O 4 provided the FTS active sites. ► Decreasing H 2 /CO ratio promoted the product shifting towards heavy hydrocarbons. - Abstract: Impacts of H 2 /CO ratios on both the bulky and surface compositions of an iron–manganese based catalyst were investigated by XRD, MES, N 2 -physisorption, XPS and LRS. Fischer–Tropsch (F–T) synthesis performances were studied in a slurry-phase continuously stirred tank reactor. The characterization results showed that the fresh catalyst was comprised of the hematite, which was converted firstly to Fe 3 O 4 , and then carburized to iron carbides in both the bulk and surface regions under different H 2 /CO ratios atmosphere. Pretreatment in lower H 2 /CO ratio facilitated the formation of iron carbides on the surface of magnetite and surface carbonaceous species. During the F–T synthesis reaction, the catalyst reduced in lower H 2 /CO ratio presented higher catalytic activity, which is assigned probably to the formation of more iron carbides (especially for χ-Fe 5 C 2 ) on the surface of magnetite. The increase of CO partial pressure promoted the product distribution shifting towards heavy hydrocarbons

  6. In-situ fabrication of MoSi{sub 2}/SiC–Mo{sub 2}C gradient anti-oxidation coating on Mo substrate and the crucial effect of Mo{sub 2}C barrier layer at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Jun [School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Key Laboratory for Advanced Materials Processing Technology, Ministry of Education, Beijing 100084 (China); State Key Laboratory of New Ceramics and Fine Processing, Beijing 100084 (China); Gong, Qianming, E-mail: gongqianming@mail.tsinghua.edu.cn [School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Key Laboratory for Advanced Materials Processing Technology, Ministry of Education, Beijing 100084 (China); State Key Laboratory of New Ceramics and Fine Processing, Beijing 100084 (China); Shao, Yang; Zhuang, Daming [School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Key Laboratory for Advanced Materials Processing Technology, Ministry of Education, Beijing 100084 (China); State Key Laboratory of New Ceramics and Fine Processing, Beijing 100084 (China); Liang, Ji [Key Laboratory for Advanced Materials Processing Technology, Ministry of Education, Beijing 100084 (China); Department of Mechanical Engineering, Tsinghua University, Beijing 100084 (China)

    2014-07-01

    MoSi{sub 2}/SiC–Mo{sub 2}C gradient coating on molybdenum was in situ prepared with pack cementation process by two steps: (1) carburizing with graphite powder to obtain a Mo{sub 2}C layer on Mo substrate, and (2) siliconizing with Si powder to get a composite MoSi{sub 2}/SiC layer on the upper part of Mo{sub 2}C layer. The microstructure and elemental distribution in the coating were investigated with scanning electron microscopy (SEM), backscattered electron (BSE), energy dispersive spectroscopy (EDS), electron probe microanalysis (EPMA) and X-ray diffraction (XRD). Cyclic oxidation tests (at 500 °C, 1200 °C, 1400 °C and 1600 °C) demonstrated excellent oxidation resistance for the gradient composite coating and the mass loss was only 0.23% in 60 min at 1600 °C. XRD, EPMA, thermal dynamic and phase diagram analyses indicated that the Mo{sub 2}C barrier layer played the key role in slowing down the diffusion of C and Si toward inner Mo substrate at high temperature and principally this contributed to the excellent anti-oxidation for Mo besides the outer MoSi{sub 2}/SiC composite layer.

  7. In-situ fabrication of MoSi2/SiC–Mo2C gradient anti-oxidation coating on Mo substrate and the crucial effect of Mo2C barrier layer at high temperature

    International Nuclear Information System (INIS)

    Liu, Jun; Gong, Qianming; Shao, Yang; Zhuang, Daming; Liang, Ji

    2014-01-01

    MoSi 2 /SiC–Mo 2 C gradient coating on molybdenum was in situ prepared with pack cementation process by two steps: (1) carburizing with graphite powder to obtain a Mo 2 C layer on Mo substrate, and (2) siliconizing with Si powder to get a composite MoSi 2 /SiC layer on the upper part of Mo 2 C layer. The microstructure and elemental distribution in the coating were investigated with scanning electron microscopy (SEM), backscattered electron (BSE), energy dispersive spectroscopy (EDS), electron probe microanalysis (EPMA) and X-ray diffraction (XRD). Cyclic oxidation tests (at 500 °C, 1200 °C, 1400 °C and 1600 °C) demonstrated excellent oxidation resistance for the gradient composite coating and the mass loss was only 0.23% in 60 min at 1600 °C. XRD, EPMA, thermal dynamic and phase diagram analyses indicated that the Mo 2 C barrier layer played the key role in slowing down the diffusion of C and Si toward inner Mo substrate at high temperature and principally this contributed to the excellent anti-oxidation for Mo besides the outer MoSi 2 /SiC composite layer.

  8. Mass transfer of steels for FBR in sodium loop

    International Nuclear Information System (INIS)

    Susukida, Hiroshi; Yonezawa, Toshio; Ueda, Mitsuo; Imazu, Takayuki; Kiyokawa, Teruyuki.

    1976-06-01

    In order to grasp quantitatively the corrosion and mass transfer of steels for FBR in sodium loop and to establish their allowable stress value and corrosion rate, a special sodium loop for material testing was designed and fabricated and the steels were given 3010 hours exposing test in the sodium loop. This paper gives the outline of the sodium loop and the results of the test. (1) Carburization and a slight increase in weight were observed in the specimens of type 304 stainless steel exposed in the sodium loop for 3010 hours, while decarburization was observed in the specimens of 2 1/4 Cr-1 Mo steel. It is considered that these phenomena were caused by the downstream factor of the sodium loop. (2) A remarkable decrease of Charpy absorbed energy was observed in the specimens of type 304 stainless steel exposed in the sodium loop. It is considered that this resulted from the weakening of the grain boundary due to heat history and mass transfer. (3) The specimens exposed in the sodium loop must be washed by ultrasonic waves in a water bath after washing in alcohol. (auth.)

  9. Selection of steam generator materials for sodium cooled fast breeders

    International Nuclear Information System (INIS)

    Berge, P.

    1977-01-01

    The sodium water heat exchangers are now considered as the stumbling block in the development of liquid metal cooled fast breeders, due to the risk of sodium-water reactions. The selection of the materials for these tube-bundles has been very broad, for the different existing, or in-project, reactors in the world: low alloy 2 1/4 Cr - 1 Mo steels (unstabilized or stabilized); 9 Cr - 1 Mo ferritic steel; 18 Cr - 10 Ni austenitic stainless steels; alloy 800. On can also add other ferritic steels, as 9 Cr - 2 Mo stabilized, which are studied for this application. In the framework of the E.D.F.-C.E.A. working group a major effort was undertaken to study the characteristics of these various materials with respect to the main criteria governing construction of the tube bundles and their performance in service: mechanical characteristics at high temperature; fabrication and welding; behavior with respect to mass transfer in sodium; carburization and decarburization; corrosion resistance. The main lines and results of this program are described [fr

  10. Helium-cooled nuclear reactor

    International Nuclear Information System (INIS)

    Longton, P.B.; Cowen, H.C.

    1975-01-01

    In helium cooled HTR's there is a by-pass circuit for cleaning purposes in addition to the main cooling circuit. This is to remove such impurities as hydrogen, methane, carbon monoxide and water from the coolant. In this system, part of the coolant successively flows first through an oxidation bed of copper oxide and an absorption bed of silica gel, then through activated charcoal or a molecular sieve. The hydrogen and carbon monoxide impurities are absorbed and the dry gas is returned to the main cooling circuit. To lower the hydrogen/water ratio without increasing the hydrogen fraction in the main cooling circuit, some of the hydrogen fraction converted into water is added to the cooling circuit. This is done, inter alia, by bypassing the water produced in the oxidation bed before it enters the absorption bed. The rest of the by-pass circuit, however, also includes an absorption bed with a molecular sieve. This absorbs the oxidized carbon monoxide fraction. In this way, such side effects as the formation of additional methane, carburization of the materials of the by-pass circuit or loss of graphite are avoided. (DG/RF) [de

  11. Tribaloy intermetallic alloy compositions: new materials or additives for wear resistant applications

    International Nuclear Information System (INIS)

    Cameron, C.B.; Hoffman, R.A.; Poskitt, R.W.

    1975-01-01

    Properties and uses of TRIBALOY alloys in powder metallurgy fabrication are discussed. Powders of TRIBALOY can be blended with essentially any powder processed by powder metallurgy. Green strength of the blended powder parts is reduced as the amount of TRIBALOY is increased. The concentration of TRIBALOY, however, is usually 15 to 20 volume percent, a compromise between green strength and effectiveness as a wear resistant part. Blended powders are sintered at the temperature normally used for the base metal with special consideration given to a low dew point in the atmosphere. The sintered parts can be coined, carburized, machined, or impregnated in any of the well-known ways. TRIBALOY as a powder blending agent has extended the useful life of P/M parts by factors of 5 and more. A variety of industries are presently using P/M parts at higher temperatures, heavier loads, in poorer or non-lubricated conditions or at higher speeds because of the addition of TRIBALOY. More important, however, is that TRIBALOY can be incorporated in parts to be made by powder metallurgy which until now had not been feasible. The overall effect has been considerable savings for the customer by switching to the powder metal method of manufacturing and increased activity for the fabricator

  12. Plasma processing techniques for deposition of carbonic thin protective coatings on structural nuclear materials

    International Nuclear Information System (INIS)

    Andrei, V.; Oncioiu, G.; Coaca, E.; Rusu, O.; Lungu, C.

    2009-01-01

    Full text of publication follows: The production of nano-structured surface films with controlled properties is crucial for the development of materials necessary for the Advanced Systems for Nuclear Energy. Since the surface of materials is the zone through which materials interact with the environment, the surface science and surface engineering techniques plays an essential role in the understanding and control of the processes involved. Complex surface structures were developed on stainless steels used as structural nuclear materials: austenitic stainless steels based on Fe, austenitic steels with high content of Cr, ferrites resistant to corrosion, by various Plasma Processing methods which include: - Plasma Electrolytic (PE) treatments: the steel substrates were modified by nitriding and nitro-carburizing plasma diffusion treatments; - carbonic films deposition in Thermionic Vacuum Arc Plasma. The results of the characterization of surface structures obtained in various experimental conditions for improvement of the properties (corrosion resistance, hardness, wear properties) are reported: the processes and structures were characterized by correlation of the results of the complementary techniques: XPS, 'depth profiling', SEM, XRD, EIS. An overall description of the processes involved in the surface properties improvement, and some consideration about the new materials development for energy technologies are presented

  13. Melting and casting of FeAl-based cast alloy

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K. [Oak Ridge National Lab., TN (United States); Wilkening, D. [Columbia Falls Aluminum Co., Columbia Falls, MT (United States); Liebetrau, J.; Mackey, B. [AFFCO, L.L.C., Anaconda, MT (United States)

    1998-11-01

    The FeAl-based intermetallic alloys are of great interest because of their low density, low raw material cost, and excellent resistance to high-temperature oxidation, sulfidation, carburization, and molten salts. The applications based on these unique properties of FeAl require methods to melt and cast these alloys into complex-shaped castings and centrifugal cast tubes. This paper addresses the melting-related issues and the effect of chemistry on the microstructure and hardness of castings. It is concluded that the use of the Exo-Melt{trademark} process for melting and the proper selection of the aluminum melt stock can result in porosity-free castings. The FeAl alloys can be melted and cast from the virgin and revert stock. A large variation in carbon content of the alloys is possible before the precipitation of graphite flakes occurs. Titanium is a very potent addition to refine the grain size of castings. A range of complex sand castings and two different sizes of centrifugal cast tubes of the alloy have already been cast.

  14. Development of Combinatorial Methods for Alloy Design and Optimization

    International Nuclear Information System (INIS)

    Pharr, George M.; George, Easo P.; Santella, Michael L

    2005-01-01

    rapid structural and chemical characterization of alloy libraries was developed based on high intensity x-radiation available at synchrotron sources such as the Advanced Photon Source (APS) at Argonne National Laboratory (ANL). With the technique, structural and chemical characterization of up to 2500 discrete positions on a library can made in a period of less than 4 hours. Among the parameters that can be measured are the chemical composition, crystal structure, lattice parameters, texture, and grain size. From these, one can also deduce isothermal sections of ternary phase diagrams. The equipment and techniques needed to do this are now in place for use in future combinatorial studies at the ORNL beam line at the APS. In conjunction with the chemical and structural investigations, nanoindentation techniques were developed to investigate the mechanical properties of the combinatorial libraries. The two primary mechanical properties of interest were the elastic modulus, E, and hardness, H, both of which were measured on alloy library surfaces with spatial resolutions of better than 1 m. A nanoindentation testing system at ORNL was programmed to make a series of indentations at specified locations on the library surface and automatically collect and store all the data needed to obtain hardness and modulus as a function of position. Approximately 200 indentations can be made during an overnight run, which allows for mechanical property measurement over a wide range of chemical composition in a relatively short time. Since the materials based on the Fe-Ni-Cr system often find application in highly carburizing and harsh chemical environments, simple techniques were developed to assess the resistance of Fe-Ni-Cr alloy libraries to carburization and corrosion. Alloy libraries were carburized by standard techniques, and the effectiveness of the carburization at various points along the sample surface was assessed by nanoindentation hardness measurement. Corrosion tests were

  15. Zirconium carbide coating for corium experiments related to water-cooled and sodium-cooled reactors

    Energy Technology Data Exchange (ETDEWEB)

    Plevacova, K. [CEA, DEN, STRI, LMA, Cadarache, 3108 St. Paul lez Durance (France); Journeau, C., E-mail: christophe.journeau@cea.fr [CEA, DEN, STRI, LMA, Cadarache, 3108 St. Paul lez Durance (France); Piluso, P. [CEA, DEN, STRI, LMA, Cadarache, 3108 St. Paul lez Durance (France); Zhdanov, V.; Baklanov, V. [IAE, National Nuclear Centre, Material Structure Investigation Dept., Krasnoarmeiskaya, 10, Kurchatov City (Kazakhstan); Poirier, J. [CEMHTI, 1D, av. de la Recherche Scientifique, 45071 Orleans Cedex 2 (France)

    2011-07-01

    Since the TMI and Chernobyl accidents the risk of nuclear severe accident is intensively studied for existing and future reactors. In case of a core melt-down accident in a nuclear reactor, a complex melt, called corium, forms. To be able to perform experiments with prototypic corium materials at high temperature, a coating which resists to different corium melts related to Generation I and II Water Reactors and Generation IV sodium fast reactor was researched in our experimental platforms both in IAE NNC in Kazakhstan and in CEA in France. Zirconium carbide was selected as protective coating for graphite crucibles used in our induction furnaces: VCG-135 and VITI. The method of coating application, called reactive wetting, was developed. Zirconium carbide revealed to resist well to the (U{sub x}, Zr{sub y})O{sub 2-z} water reactor corium. It has also the advantage not to bring new elements to this chemical system. The coating was then tested with sodium fast reactor corium melts containing steel or absorbers. Undesirable interactions were observed between the coating and these materials, leading to the carburization of the corium ingots. Concerning the resistance of the coating to oxide melts without ZrO{sub 2}, the zirconium carbide coating keeps its role of protective barrier with UO{sub 2}-Al{sub 2}O{sub 3} below 2000 deg. C but does not resist to a UO{sub 2}-Eu{sub 2}O{sub 3} mixture.

  16. Irradiation performance of helium-bonded uranium--plutonium carbide fuel elements

    International Nuclear Information System (INIS)

    Latimer, T.W.; Petty, R.L.; Kerrisk, J.F.; DeMuth, N.S.; Levine, P.J.; Boltax, A.

    1979-01-01

    The current irradiation program of helium-bonded uranium--plutonium carbide elements is achieving its original goals. By August 1978, 15 of the original 171 helium-bonded elements had reached their goal burnups including one that had reached the highest burnup of any uranium--plutonium carbide element in the U.S.--12.4 at.%. A total of 66 elements had attained burnups over 8 at.%. Only one cladding breach had been identified at that time. In addition, the systematic and coordinated approach to the current steady-state irradiation tests is yielding much needed information on the behavior of helium-bonded carbide fuel elements that was not available from the screening tests (1965 to 1974). The use of hyperstoichiometric (U,Pu)C containing approx. 10 vol% (U,Pu) 2 C 3 appears to combine lower swelling with only a slightly greater tendency to carburize the cladding than single-phase (U,Pu)C. The selected designs are providing data on the relationship between the experimental parameters of fuel density, fuel-cladding gap size, and cladding type and various fuel-cladding mechanical interaction mechanisms

  17. Life prediction of l6 steel using strain-life curve and cyclic stress-strain curve by means of low cycle fatigue testing

    Science.gov (United States)

    Inamdar, Sanket; Ukhande, Manoj; Date, Prashant; Lomate, Dattaprasad; Takale, Shyam; Singh, RKP

    2017-05-01

    L6 Steel is used as die material in closed die hot forging process. This material is having some unique properties. These properties are due to its composition. Strain softening is the noticeable property of this material. Due to this in spite of cracking at high stress this material gets plastically deformed and encounters loss in time as well as money. Studies of these properties are necessary to nurture this material at fullest extent. In this paper, numerous experiments have been carried on L6 material to evaluate cyclic Stress - strain behavior as swell as strain-life behavior of the material. Low cycle fatigue test is carried out on MTS fatigue test machine at fully reverse loading condition R=-1. Also strain softening effect on forging metal forming process is explained in detail. The failed samples during low cycle fatigue test further investigated metallurgically on scanning electron microscopy. Based on this study, life estimation of hot forging die is carried out and it’s correlation with actual shop floor data is found out. This work also concludes about effect of pre-treatments like nitro-carburizing and surface coating on L6 steel material, to enhance its fatigue life to certain extent.

  18. Corrosion resistance of Ni-50Cr HVOF coatings on 310S alloy substrates in a metal dusting atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Saaedi, J. [Centre for Advanced Coating Technologies, Department of Materials Science and Engineering, University of Toronto, 184 College Street, Toronto, Ontario M5S 3E4 (Canada); Department of Materials and Metallurgical Engineering, Iran University of Science and Technology, Tehran (Iran, Islamic Republic of); Arabi, H.; Mirdamadi, S.; Ghorbani, H. [Department of Materials and Metallurgical Engineering, Iran University of Science and Technology, Tehran (Iran, Islamic Republic of); Coyle, T.W. [Centre for Advanced Coating Technologies, Department of Materials Science and Engineering, University of Toronto, 184 College Street, Toronto, Ontario M5S 3E4 (Canada)

    2011-09-15

    Metal dusting attack has been examined after three 168 h cycles on two Ni-50Cr coatings with different microstructures deposited on 310S alloy substrates by the high velocity oxy-fuel (HVOF) thermal-spray process. Metal dusting in uncoated 310S alloy specimens was found to be still in the initiation stage after 504 h of exposure in the 50H{sub 2}:50CO gas environment at 620 C. Dense Ni-50Cr coatings offered suitable resistance to metal dusting. Metal dusting was observed in the 310S substrates adjacent to pores at the interface between the substrate and a porous Ni-50Cr coating. The porosity present in the as-deposited coatings was shown to introduce a large variability into coating performance. Carbon formed by decomposition of the gaseous species accumulated in the surface pores and resulted in the dislodgement of surface splats due to stresses generated by the volume changes. When the corrosive gas atmosphere was able to penetrate through the interconnected pores and reach the coating-substrate interface, the 310S substrate was carburized, metal dusting attack occurred, and the resulting formation of coke in the pores led to local failure of the coating. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  19. Étude de la restauration des caractéristiques de tubes de four de vapocraquage en Manaurite 36 XS Study of the Restoration of the Characteristics of Steam-Cracker Tubes Made of Manaurite 36 Xs

    Directory of Open Access Journals (Sweden)

    Ropital F.

    2006-11-01

    Full Text Available Le vieillissement de tubes de four en Manaurite 36XS d'une unité de vapocraquage se traduit par une précipitation et une coalescence de carbures aux joints de grains, une évolution locale de la composition chimique et une forte diminution de la ductilité. Des traitements thermiques appropriés, dont l'efficacité est suivie par microanalyse et par l'évolution des propriétés mécaniques, permettent de restaurer en quasi totalité les caractéristiques de l'acier. Après détermination des conditions en laboratoire, un essai très positif a été réalisé sur tube de four avec des moyens utilisables sur chantier. The aging of Manaurite 36 XS tubes in a steam-cracking unit results in the precipitation and coalescence of carbides at grain boundaries, a local variation in the chemical composition and a strong decrease in ductility. Appropriate thermal treatments, whose efficiency is monitored by microanalysis and by the variation of mechanical properties, enable almost all the characteristics of the steel to be restored. After laboratory conditions were determined, a very positive test was performed on a cracker tube with means that can be used in the field.

  20. Production of Methanol-Higher Alcohol Mixtures from Natural Gas via Syngas Chemistry Production de mélanges méthanol-alcools supérieurs à partir du gaz, via (CO + H2

    Directory of Open Access Journals (Sweden)

    Courty P.

    2006-11-01

    Full Text Available Despite the prevailing position of ethers (MTBE, TAME as octane boosters, and the low oil prices at present, alcohol synthesis remains one of the near future means of natural gas upgrading via syngas chemistry. After a review of the available process development data in the field, this paper focuses on the IFP process studies, based on the CuCo and CuNi catalysts developed by Institut Français du Pétrole (IFR, France and Idemitsu Kosan (Japan. The adequacy between the product specifications, and the optimization of the performances is then discussed in a technico-economic context, together with a presentation of lab scale, pilot scale and demonstration scale test results. As a conclusion, a prospective overall view brings together todays economics and some improvement guidelines dealing with investments, operating cost and catalyst performances. Cette publication présente les travaux de R & D (Recherche et Développement menés par l'Institut Français du Pétrole (IFP, France et Idemitsu Kosan (Japon en synthèse d'alcools. Elle situe les résultats dans le contexte technique et économique actuel. L'accroissement constant des ressources prouvées en gaz et, chronologiquement, les deux crises pétrolières, la suppression du plomb dans les essences, ont conduit le monde industriel à intensifier les recherches concernant la synthèse d'alcools. Très récemment, les effets bénéfiques de l'addition d'alcools sur les émissions de polluants ont été mis en évidence. Toutefois, l'additivation de carburants par les alcools est en voie de disparition au profit des éthers, alors que, indépendamment, les procédés de production d'ammoniac, de méthanol, d'acide acétique, également fondés sur le gaz, se sont seuls développés. La synthèse d'alcools a fait l'objet de nombreux travaux, résumés dans les tableaux 1 et 2. L'étude des différents aspects réactionnels amène à prendre en compte l'exothermicité importante des r

  1. A Physics and Tabulated Chemistry Based Compression Ignition Combustion Model: from Chemistry Limited to Mixing Limited Combustion Modes Un modèle de combustion à allumage par compression basé sur la physique et la chimie tabulée : des modes de combustion contrôlés par la chimie jusqu’aux modes contrôlés par le mélange

    Directory of Open Access Journals (Sweden)

    Bordet N.

    2011-11-01

    experimental measurements carried out on a 2 liter Renault Diesel engine and good agreements are found. Ce papier présente une nouvelle approche 0D phénoménologique pour prédire le déroulement de la combustion dans les moteurs Diesel à injection directe pour toutes les conditions d’utilisation usuelles. Le but de ce travail est de développer une approche physique en vue d’améliorer la prédiction de la pression cylindre et du dégagement d’énergie, avec un nombre minimum d’essais nécessaires à la calibration. Les contributions principales de cette étude sont la modélisation de la phase de pré-mélange de la combustion et une extension du modèle pour les stratégies d’injections multiples. Dans ce modèle, le taux de dégagement d’énergie dû à la combustion pour la phase pré-mélangée est relié à un taux de réaction moyen du carburant. Ce taux de réaction moyen de carburant est évalué à l’aide d’une approche basée sur un taux de réaction local de carburant tabulé et la détermination d’une fonction de densité de probabilité (PDF de la fraction de mélange (Z. Cette PDF permet de prendre en compte la distribution de richesse existante dans la zone pré-mélangée. L’allure de cette PDF présumée est une β-fonction standardisée. Les fluctuations de la fraction de mélange sont décrites avec une équation de transport pour la variance de Z. La définition standard de la fraction de mélange, établie dans le cas de flammes de diffusion, est ici adaptée à une combustion pré-mélangée de type Diesel pour décrire l’inhomogénéité de la richesse dans le volume de contrôle. La chimie détaillée est décrite au travers de la tabulation du taux de réaction relatif à la flamme principale et du délai d’auto-inflammation relatif à la flamme froide, ces tabulations sont fonction de la variable d’avancement c, du taux de gaz brûlé ainsi que des grandeurs thermodynamiques telles que la température et la pression. Le

  2. De la mobilisation collective de décembre  2008 en  Guyane francaise  au référendum de janvier 2010, une année de crise Since the collective mobilization of December 2008 until Referendum of January 2010: One year of Crisis in French Guiana

    Directory of Open Access Journals (Sweden)

    Anne Catherine Ho Yick Cheong

    2012-01-01

    Full Text Available À la suite à d’une envolée des prix du carburant en Guyane, alors même que le cours du baril de pétrole mondial est en chute, les Guyanais s’emploient à mobiliser toute la société. En date du 24 novembre 2008, débute une manifestation contre la hausse du prix du carburant,  et plus globalement contre la vie chère. La Guyane, paralysée pendant plus de dix jours au départ, connaîtra une crise qui durera près d’un an. Elle a su transformer admirablement une contestation isolée en une mobilisation collective non conventionnelle et l’inscrire dans une logique décrite au plan théorique par A. Touraine : elle a transformé une particularité en « Totalité » (revendication globale, donné au mouvement une « Identité » en propulsant à sa tête un puissant acteur de classe et entrepreneur du mouvement, désigné un « Adversaire » de classe, en l’occurrence la puissance publique avec laquelle elle partage les mêmes objectifs (peser sur l’historicité de la collectivité mais en dispute les moyens. Deux consultations populaires ont marqué par la voie référendaire un attachement de la Guyane à la métropole (1ère consultation du 10 janvier 2010 et la volonté d’une simplification administrative des décisions (2nde consultation du 24 janvier 2010.In 2008, fuel prices increased in French Guyana, whilst at the same time world fuel prices fell.  In reaction to this the Guyanese began a protest on November 24th, 2008 against the rise of fuel prices and the high cost of living in general. Paralyzed for more than ten days during the protest, the country suffered a year long a crisis. This small isolated protest was transformed into an unconventional collective movement. The situation in Guyana can be applied to the A. Touraine’s theory of how a movement can give a country and its people an identity, which allows them to fight against the adversary. The public power with whom they share the same objectives

  3. The direct conversion of heat into electricity in reactors; Conversion directe de la chaleur en electricite dans les piles

    Energy Technology Data Exchange (ETDEWEB)

    Devin, B; Bliaux, J; Lesueur, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    pile atomique a ete etudiee dans la triple perspective de son utilisation soit comme source d'energie de servitude dans un engin spatial, soit en tete d'un systeme conventionnel de conversion dans les installations de puissance, soit enfin associee a la conversion thermoelectrique dans des installations de tres faible puissance. Les etudes en laboratoire ont porte principalement sur les travaux d'extraction electronique des metaux et composes et leur evolution a haute temperature. Des convertisseurs fournissant jusqu'a 50 amperes sous 0,4 volt avec un rendement voisin de 10 p. 100 ont ete realises en laboratoire; les emetteurs chauffes par bombardement electronique etaient constitues de tungstene recouvert d'un depot de carbure d'uranium ou de molybdene recouvert de cesium. Les principaux aspects du couplage entre le convertisseur et la pile atomique ont ete examines du point de vue electronique: influence de la desadaptation de la charge sur la temperature de l'emetteur et influence du flux thermique unitaire sur la temperature de l'emetteur et la stabilite du convertisseur. Des convertisseurs utilisant le carbure d'uranium comme emetteur electronique ont ete experimentes en pile. Des essais ont ete effectues en regime transitoire en vue de determiner les parametres dynamiques. Les reseaux d'adaptation a la charge ont pu etre construits et on en a deduit les performances globales de plusieurs cellules couplees de maniere a former un barreau de reacteur. Ces donnees sont indispensables pour la conception d'un systeme de controle d'une pile a conversion thermoionique, On a examine theoriquement les problemes de fiabilite des convertisseurs thermoioniques associes en serie dans un meme barreau de combustible. Enfin, on a trace les isothermes d'absorption a la temperature ambiante du krypton et du xenon sur un charbon active en vue d'etudier le degagement des produits de fission dans un convertisseur. (auteurs)

  4. Preliminary studies of vanadium-base alloys intended for use in fabrication of cans for fast reactors; Etudes preliminaires sur les alliages a base de vanadium envisages pour la fabrication de gaines de reacteurs rapides

    Energy Technology Data Exchange (ETDEWEB)

    Conte, M [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1967-03-15

    1050 deg. C sous vide montrent que d'une facon generale, les elements d'additions ameliorent les proprietes mecaniques du vanadium. Apres des traitements de corrosion dans une boucle a sodium liquide purifie par piege froid, les alliages sont fragilises a la temperature ambiante. Seule la nuance V-20 pour cent Ti conserve des proprietes plastiques. Ces alliages sont recouverts d'une couche superficielle de carbure de vanadium VC. Apres des traitements dans une boucle a sodium liquide purifie par piege chaud, tous les alliages conservent de bonnes caracteristiques mecaniques. La couche superficielle qui les recouvre est constituee de deux carbures de vanadium VC et {sub {gamma}}VC et d'un sous-oxyde de vanadium VO{sub 0,9}. (auteur)

  5. Impact environnemental d'une désulfuration poussée des gazoles Environmental Impact of Gaz Oil Desulfurization

    Directory of Open Access Journals (Sweden)

    Armengol C.

    2006-11-01

    Full Text Available En une dizaine d'années, le diesel a connu un développement spectaculaire sur les marchés automobile français et européen et pourrait atteindre, en 1995, la moitié des immatriculations de véhicules particuliers en France et le quart en Europe de l'Ouest. Cette situation n'est évidemment pas sans poser de problèmes. Problèmes environnementaux puisque le moteur diesel est une source plus importante d'émissions d'oxydes d'azote et de particules que le convertisseur essence, mais également au niveau de l'industrie du raffinage qui, en France, n'est plus en mesure de satisfaire la demande en gazole. De plus, à compter du 1er octobre 1996, la teneur en soufre du gazole routier ne devra pas excéder 0,05 %, conformément aux nouvelles spécifications européennes. Cette perspective de production de carburants fortement désulfurés va affecter directement l'équilibre en hydrogène de la raffinerie et donc les autoconsommations et les émissions de CO2. L'objectif de cette étude est de mesurer l'impact sur l'environnement d'une réduction de la teneur en soufre des gazoles de 0,3 à 0,05 %. Le bilan est réalisé sur l'ensemble de la filière énergétique, depuis l'extraction du pétrole jusqu'à la combustion du carburant dans le moteur. Les gains et les pertes en termes de pollution locale ou globale sont évalués suivant la nature de l'hydrogène utilisé (oxydation partielle de résidus sous vide ou de charbon, reformage à la vapeur de gaz naturel ou de naphta électrolyse et la nature de la charge à traiter (gazole straight run ou light cycle oil lors de l'hydrodésulfuration. Over the past decade, diesel had made large advances in the French and European automobile markets. In 1995, diesel could account for half of all private vehicle registrations in France, and a quarter in Western Europe. This situation inevitably raises a number of problems : environmental problems, because the diesel engine emits more nitrogen oxides and

  6. Preparation and study of the nitrides and mixed carbide-nitrides of uranium and of plutonium; Preparation et etude des nitrures et carbonitrures d'uranium et de plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Anselin, F [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-06-01

    frittage. On a observe un effet benefique, mais non reproductible, de traces d'oxyde. Les meilleurs resultats ont ete obtenus pour UN pur, a 1600 C (96 pour cent de la densite theorique) a condition d'utiliser une poudre bien caracterisee. Le critere utilise est la largeur integrale des raies de diffraction X. Les composes UN et PuN sont entierement miscibles avec les carbures correspondants. Ceci permet de preparer par diffusion en phase solide, vers 1400 C, des carbonitrures de formule generale (U,Pu) (C,N). Le frittage de ces carbonitrures s'apparente a celui des carbures, si la teneur en azote est faible; en particulier le nickel est un additif de frittage efficace. Pour les teneurs elevees, le frittage est comparable a celui des nitrures purs.

  7. Microstructure-property relationships and constitutive response of plastically graded case hardened steels

    Science.gov (United States)

    Klecka, Michael A.

    Case hardened materials, popularly used in many demanding engineering applications such as bearings, gears, and wear/impact surfaces, have high surface hardness and a gradient in material properties (hardness, yield strength, etc.) as a function of depth; therefore, they behave as plastically graded materials. In the current study, two different commercially available case carburized steels along with two through hardened steels are characterized to obtain relationships among the volume fraction of subsurface carbides, indentation hardness, elastic modulus, and yield strength as a function of depth. A variety of methods including microindentation, nanoindentation, ultrasonic measurements, compression testing, rule of mixtures, and upper and lower bound models are used to determine the relationships for elastic modulus and compare the experimental results with model predictions. In addition, the morphology, composition, and properties of the carbide particles are also determined. The gradient in hardness with depth in graded materials is commonly determined using microindentation on the cross-section of the material which contains the gradation in microstructure or composition. In the current study, a novel method is proposed to predict the hardness gradient profile using solely surface indentations at a range of loads. The method does not require the graded material to be sectioned, and has practical utility in the surface heat-treatment industry. For a material with a decreasing gradient in hardness, higher indent loads result in a lower measured hardness due to the influence of the softer subsurface layers. A power-law model is presented which relates the measured surface indentation hardness under increasing load to the subsurface gradient in hardness. A coordinated experimental and numerical study is presented to extract the constitutive response of graded materials, utilizing relationships between hardness, plastic deformation, and strain hardening response

  8. Corrosion of Structural Materials for Advanced Supercritical Carbon- Dioxide Brayton Cycle

    Energy Technology Data Exchange (ETDEWEB)

    Sridharan, Kumar [Univ. of Wisconsin, Madison, WI (United States)

    2017-05-13

    for simultaneous occurrence of carburization during oxidation of the material. Carburization can potentially lead to embrittlement of structural alloys in SC-CO2 Brayton cycle. An important consideration in regards to corrosion is that the temperatures can vary widely across the various sections of the SC-CO2 Brayton cycle, from room temperature to 750°C, with even higher temperatures being desirable for higher efficiencies. Thus the extent of corrosion and corrosion mechanisms in various components and SC-CO2 Brayton cycle will be different, requiring a judicious selection of materials for different sections of the cycle. The goal of this project was to address materials corrosion-related challenges, identify appropriate materials, and advance the body of scientific knowledge in the area of high temperature SC-CO2 corrosion. The focus was on corrosion of materials in SC-CO2 environment in the temperature range of 450°C to 750°C at a pressure of 2900 psi for exposure duration for up to 1000 hours. The Table below lists the materials tested in the project. The materials were selected based on their high temperature strength, their code certification status, commercial availabilities, and their prior or current usage in the nuclear reactor industry. Additionally, pure Fe, Fe-12%Cr, and Ni-22%Cr were investigated as simple model materials to more clearly understand corrosion mechanisms. This first phase of the project involved testing in research grade SC-CO2 (99.999% purity). Specially designed autoclaves with high fidelity temperature, pressure, and flow control capabilities were built or modified for this project.

  9. Uso de etanol carburado en motores Diesel

    Directory of Open Access Journals (Sweden)

    Rodríguez Luis Arnoby

    1990-06-01

    Full Text Available Este trabajo se ejecutó en el Taller de Maquinaria Agrícola de la Facultad de Ciencias Agropecuarias de la Universidad Nacional de Colombia, Seccional Palmira. Un motor diesel de 2 cilindros, 1260 cm3 y relación de comprensión 23:1, fue alimentado mediante un sistema dual formado por el sistema de inyección para ACPM y un sistema de carburación para etanol y mezclas etanol-agua. En primer término se varió el avance de la inyección entre 18 y 26° APMS(Antes de Punto Muerto Superior con el fin de determinar el avance óptimo de inyección en el motor original y el motor alimentado con el sistema dual. Con base en el punto de máxima potencia, se seleccionaron 20 y 22" como avances óptimos. En la segunda prueba, al operar el motor con carga y velocidad variables y alimentarlo con cuatro combustibles (ACPM, etanol y mezclas etanol- agua con 20 y 40 % agua, se incrementaron la velocidad en 10% la potencia máxima en 6.5% ; y el torque máximo en 3.73%, desde el motor original al sistema dual alimentado con la mezcla carburada de 40% agua. La mayor sustitución de combustible se presentó a alta velocidad donde se reemplazó hasta el 32 % de ACPM por etanol. Solo a alta velocidad se justifica la sobrealimentación con etanol carburado. En este rango se presentaron aumentos de potencia, velocidad, par torsor y sustitución de combustible.This work was performed in the Agricultural Mechanics Shop of the Universidad Nacional of Colombia in Palmira. A two-cylinder, 1260 cm3 diesel engine with a compression ratio of 23:1 was fueled by a dual system formed by its injection system for diesel oil and a carburation system for ethanol and ethanol-water blends. In a first test, m e injection advance was varied between 18 and 26 o BTDC (Before Top Dead Center to determine the optimum injection advance in the original engine and the engine fueled with the dual system. According to the maximum power point, 20 and 22° BTDC were selected as the optimum

  10. Optical Engines as Representative Tools in the Development of New Combustion Engine Concepts Moteurs transparents comme outils représentatifs dans le développement de nouveaux concepts des moteurs à combustion interne

    Directory of Open Access Journals (Sweden)

    Kashdan J.

    2011-11-01

    de s’assurer que le fonctionnement des moteurs transparents est tout à fait comparable et représentatif de celui des moteurs standards (opaques. Une comparaison du comportement de la combustion et des émissions des moteurs transparents et opaques a été réalisée. L’objectif était d’étudier les différences principales entre le moteur transparent et le moteur opaque et de comprendre comment ces différences peuvent influencer les phases de préparation du mélange, la combustion et la formation de polluants. Les résultats expérimentaux révèlent l’influence significative des différences liées à la température des parois de la chambre de combustion. Des mesures de la température des parois ont été effectuées par la technique de phosphorescence induite par laser. Ces mesures ont permis de définir des stratégies de fonctionnement moteur permettant de compenser les différences de température de paroi entre les deux moteurs. En outre, l’impact des différences géométriques des chambres a été investiguée. La réhausse piston peut subir soit un chargement mécanique dynamique (effets de compression ou de traction soit une expansion thermique. Ces effets peuvent faire varier le taux de compression effectif. La charge admise dans les moteurs transparents est souvent diluée par de l’EGR simulé au lieu d’utiliser l’EGR réel. Dans les conditions de Diesel LTC, une comparaison a été effectuée entre l’utilisation d’EGR réel et d’EGR simulé par un gaz diluant pur. Enfin, les carburants mono-composants (carburants purs sont souvent utilisés dans les moteurs Diesel transparents en raison des contraintes imposées par l’utilisation de techniques de diagnostics optiques. Cependant, les carburants purs diffèrent quelque peu des carburants Diesel réels, en particulier au travers de leur indice de cétane et de leur volatilité. Ces différences peuvent influencer fortement le comportement de la combustion et des

  11. Joint dissolution and oxidation behaviour of 316LN steel at 550 C. in liquid sodium containing low concentration of oxygen - 15417

    International Nuclear Information System (INIS)

    Courouau, J.L.; Rivollier, M.; Lorentz, V.; Tabarant, M.

    2015-01-01

    The sodium cooled fast reactor is selected in France as the 4. generation of nuclear power plant. 4. generation's reactor vessel, primary loop structures and heat exchangers will be made of austenitic stainless steels (316LN). To assess reactor service life time, corrosion of austenitic stainless steel by liquid sodium is studied in normal operating conditions as well as in transient conditions either expected or not. Oxygen, one of the main impurities, but present in trace amounts (1 to 10 μg/g or ppm weight), plays a major role on corrosion phenomena of the steel, although not totally understood yet. Literature reports an increased dissolution rate of steel or even of pure iron with increasing oxygen content although no thermodynamically stable iron oxide exists at low oxygen content. Oxygen is only known to form sodium chromite scale (NaCrO 2 ), those behaviour is, however, little documented. Based on corrosion tests performed in the static sodium test device (CorroNa) at 550 C. degrees for an oxygen content initially of about 1 ppm in weight or lower, and about 5-10 ppm after 4600 h of test, either a really small dissolution rate or small sodium chromite scale formation (NaCrO 2 ) are observed. Dissolution and carburation are observed for specimen immersed since the beginning of the test, while oxidation is the main feature observed for the specimen immersed during the last periods of the test. Some aspects of the morphologies of this oxide scale obtained by scanning electron microscopy (SEM) or transmission electron microscopy (TEM) as well as by Glow Discharge Optical Emission Spectroscopy (GD-OES) are presented. Discussions and explanations of these apparently opposing results are given based on thermodynamic analysis, as well as their possible consequences for reactor operation. (authors)

  12. Novel catalysts for upgrading coal-derived liquids. Final technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, L.T.; Savage, P.E.; Briggs, D.E.

    1995-03-31

    Research described in this report was aimed at synthesizing and evaluating supported Mo oxynitrides and oxycarbides for the selective removal of nitrogen, sulfur and oxygen from model and authentic coal-derived liquids. The Al{sub 2}O{sub 3}-supported oxynitrides and oxycarbides were synthesized via the temperature programmed reaction of supported molybdenum oxides or hydrogen bronzes with NH{sub 3} or an equimolar mixture of CH{sub 4} and H{sub 2}. Phase constituents and composition were determined by X-ray diffraction, CHN analysis, and neutron activation analysis. Oxygen chemisorption was used to probe the surface structure of the catalysts. The reaction rate data was collected using specially designed micro-batch reactors. The Al{sub 2}O{sub 3}-supported Mo oxynitrides and oxycarbides were competitively active for quinoline hydrodenitrogenation (HDN), benzothiophene hydrodesulfurization (HDS) and benzofuran hydrodeoxygenation (HDO). In fact, the HDN and HDO specific reaction rates for several of the oxynitrides and oxycarbides were higher than those of a commercial Ni-Mo/Al{sub 2}O{sub 3} hydrotreatment catalyst. Furthermore, the product distributions indicated that the oxynitrides and oxycarbides were more hydrogen efficient than the sulfide catalysts. For HDN and HDS the catalytic activity was a strong inverse function of the Mo loading. In contrast, the benzofuran hydrodeoxygenation (HDO) activities did not appear to be affected by the Mo loading but were affected by the heating rate employed during nitridation or carburization. This observation suggested that HDN and HDS occurred on the same active sites while HDO was catalyzed by a different type of site.

  13. TRANSFORMATION ISOTHERME D'UN ACIER A HAUTE RESISTANCE 40 CDV 13

    Directory of Open Access Journals (Sweden)

    A BOUTEFNOUCHET

    2001-06-01

    Full Text Available L'étude dilatométrique du comportement de l'austénite en condition isotherme d'un acier ternaire, à haute résistance mécanique de nuance 40 CDV 13, nous a permis de tracer son diagramme TTT. L'austénitisation a été réalisée pendant 10 minutes à  qg = 950°C (utilisée dans  l'industrie. Les températures de maintien sont comprises entre Ac1 = 810°C et Ms  = 310°C. Dans ce diagramme TTT, on distingue deux domaines de transformation isotherme de l'austénite. Le domaine I (625°C £  qiso < Ac1 = 810°C dans lequel l'austénite se transforme en ferrite et en perlite, et le domaine II (325°C  £  qiso £ 475°C où l'austénite se transforme en bainite ou en ferrite probainitique. Ces transformations sont précédées pour toutes les températures de maintien isotherme d'une précipitation de carbures. En outre, ces deux domaines de transformation de l'austénite sont séparés par une large zone de stabilité de l'austénite comprise entre 500°C et 600°C. L'analyse approfondie des courbes dilatométriques enregistrées durant le maintien isotherme et le refroidissement final jusqu'à l'ambiante, nous a permis de déterminer qualitativement et quantitativement les phase mises en jeu par ces transformations isothermes de l'austénite.

  14. EFFET DES TRAITEMENTS THERMIQUES SUR LA REACTION ENTRE DES COUCHES MINCES DE TITANE ET DES SUBSTRATS EN ACIER

    Directory of Open Access Journals (Sweden)

    D Slimani

    2015-06-01

    Full Text Available Des couches minces du titane pur ont été déposées avec la méthode de pulvérisation cathodique sur des substrats en acier, type FF80 K-1 contenants ~1% mass. en carbone. La réaction entre les deux parties du système substrat-couche mince est activée avec des traitements thermiques sous vide dans l’intervalle de températures de 400 à900°Cpendant 30 minutes. Les Spectres de diffraction de rayons x confirment l’inter- diffusion des éléments  chimiques du système résultants la formation et la croissance des nouvelles phases en particulier le carbure binaire TiC ayant des caractéristiques thermomécaniques importantes. L’analyse morphologique des échantillons traités  avec le microscope électronique à balayage (MEB montre l’augmentation du flux de diffusion atomique avec la température de recuit, notamment la diffusion du manganèse et du fer vers la surface libre des échantillons aux températures élevées provoquant la dégradation des propriétés mécaniques des revêtements contrairement au premiers stades d’interaction où on a obtenu des bonnes valeurs de la microdureté.

  15. Insights on finite size effects in ab initio study of CO adsorption and dissociation on Fe 110 surface

    International Nuclear Information System (INIS)

    Chakrabarty, Aurab; Bouhali, Othmane; Mousseau, Normand; Becquart, Charlotte S.; El-Mellouhi, Fedwa

    2016-01-01

    Adsorption and dissociation of hydrocarbons on metallic surfaces represent crucial steps on the path to carburization, eventually leading to dusting corrosion. While adsorption of CO molecules on Fe surface is a barrier-less exothermic process, this is not the case for the dissociation of CO into C and O adatoms and the diffusion of C beneath the surface that are found to be associated with large energy barriers. In practice, these barriers can be affected by numerous factors that combine to favour the CO-Fe reaction such as the abundance of CO and other hydrocarbons as well as the presence of structural defects. From a numerical point of view, studying these factors is challenging and a step-by-step approach is necessary to assess, in particular, the influence of the finite box size on the reaction parameters for adsorption and dissociation of CO on metal surfaces. Here, we use density functional theory (DFT) total energy calculations with the climbing-image nudged elastic band method to estimate the adsorption energies and dissociation barriers for different CO coverages with surface supercells of different sizes. We further compute the effect of periodic boundary condition for DFT calculations and find that the contribution from van der Waals interaction in the computation of adsorption parameters is important as they contribute to correcting the finite-size error in small systems. The dissociation process involves carbon insertion into the Fe surface causing a lattice deformation that requires a larger surface system for unrestricted relaxation. We show that, in the larger surface systems associated with dilute CO-coverages, C-insertion is energetically more favourable, leading to a significant decrease in the dissociation barrier. This observation suggests that a large surface system with dilute coverage is necessary for all similar metal-hydrocarbon reactions in order to study their fundamental electronic mechanisms, as an isolated phenomenon, free from

  16. Coating Properties of WC-Ni Cold Spray Coating for the Application in Secondary Piping System of Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Kim, JeongWon; Kim, Seunghyun; Kim, Ji Hyun [UNIST, Ulsan (Korea, Republic of)

    2015-10-15

    As a result of FAC(flow accelerated corrosion), severe accidents, failure of carbon steel like a Mihama Unit-3 occurred. Chemical composition change of carbon steel or coating to inner surface is one of methods to improve corrosion properties. Among them, thermal spray coating is convenient solution to apply at industry. Powder is melted at blast furnace and ejected to substrate. After adhesion, substrate and coating layer is cooled down and coated layer protects steel from corrosion finally. However high thermal energy is transferred to substrate and coating layer so it leads high thermal residual stress in coating procedure. Besides, high temperature for melting powder makes unexpected chemical reaction of powder like an oxidation or carburization. Whereas, cold spray uses low temperature comparing with other thermal spray. Thermal energy is used for not melting powder but high kinetic energy of powder and plastic deformation during collision. Therefore, fuel such as oxygen-acetylene gas is not needed. It needs carrier gas, compressed air, nitrogen or helium, to increase kinetic energy of powder and move powder to substrate. Comparing cold spray with high velocity oxy fuel (HVOF), one of thermal spray, cold spray coating layer contains only WC and Co. One of other problem about WC is brittleness during coating. To improve deformability of WC, binder metal is added. For example, Co, Cr, Ni, Cu, Al, Fe or etc. Additionally, binder metal lowering melting temperature of composite powder increases coating properties. Among them, Co which is widely used as binder metal maintains mechanical properties like a hardness and improves corrosion properties. Therefore Co is not suitable for binder metal of WC coating. In contrast, Ni has better corrosion resistance to alkaline environment and makes lower melting temperature. Moreover, in a view of cold spray, FCC structure has better deformability than BCC or HCP, and BCC has lowest deformability. WC is BCC structure so it

  17. Successive carbon- and boron saturation of KhVG steel in powder mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Alimov, Yu A; Gordienko, S I

    1975-01-01

    Method of successive saturation of KhVG steel with carbon and boron in powder mixtures is described. After carbonization of steel in a charcoal carburator at 930 deg C during 3 hrs a domain of equiaxial large grains is formed there the latter representing carbides of Fe/sub 3/C and (Fe, M)/sub 3/C. The increase of duration of carbonization up to 5 hrs and above results in formation of a cement grid greatly impairing the mechanical properties of the metal. Carbonization is followed by borating in powdered technical boron carbide at 900 deg C for 4 hrs which ensures formation on the sample surface of a borated layer with depth up to 65 mkm covering the carbonized zone. As followed from metallographic and x-ray structural analysis, the borated layer consists of boride needles with complex composition (Fe, Cr, Mn)B. Oil hardening of carbonized KhVG steel from 850 deg C and low-temperature tempering at 180 deg C for 1 hr results in formation in the main metal of martensite-carbide structure and, respectively, in the decrease of the microhardness gradient between the diffusion layers, as compared with borated KhVG steel. Operation tests of strengthened matrices of preforming machines under the conditions of application of dynamic pressing forces up to 1500 kg Fce/cm/sup 2/ demonstrated that the cyclical strength of carboborated coverings is 2.0-3.0 times higher than that of borated ones. The method of carboborating is recommended for strengthening the details of stamp and press tools.

  18. Knowledge Assisted Integrated Design of a Component and Its Manufacturing Process

    Science.gov (United States)

    Gautham, B. P.; Kulkarni, Nagesh; Khan, Danish; Zagade, Pramod; Reddy, Sreedhar; Uppaluri, Rohith

    Integrated design of a product and its manufacturing processes would significantly reduce the total cost of the products as well as the cost of its development. However this would only be possible if we have a platform that allows us to link together simulations tools used for product design, performance evaluation and its manufacturing processes in a closed loop. In addition to that having a comprehensive knowledgebase that provides systematic knowledge guided assistance to product or process designers who may not possess in-depth design knowledge or in-depth knowledge of the simulation tools, would significantly speed up the end-to-end design process. In this paper, we propose a process and illustrate a case for achieving an integrated product and manufacturing process design assisted by knowledge support for the user to make decisions at various stages. We take transmission component design as an example. The example illustrates the design of a gear for its geometry, material selection and its manufacturing processes, particularly, carburizing-quenching and tempering, and feeding the material properties predicted during heat treatment into performance estimation in a closed loop. It also identifies and illustrates various decision stages in the integrated life cycle and discusses the use of knowledge engineering tools such as rule-based guidance, to assist the designer make informed decisions. Simulation tools developed on various commercial, open-source platforms as well as in-house tools along with knowledge engineering tools are linked to build a framework with appropriate navigation through user-friendly interfaces. This is illustrated through examples in this paper.

  19. Corrosion of high temperature alloys in the primary circuit helium of high temperature gas cooled reactors. Pt. 2

    International Nuclear Information System (INIS)

    Quadakkers, W.J.

    1985-01-01

    The reactive impurities H 2 O, CO, H 2 and CH 4 which are present in the primary coolant helium of high temperature gas-cooled reactors can cause scale formation, internal oxidation and carburization or decarburization of the high temperature structural alloys. In Part 1 of this contribution a theoretical model was presented, which allows the explanation and prediction of the observed corrosion effects. The model is based on a classical stability diagram for chromium, modified to account for deviations from equilibrium conditions caused by kinetic factors. In this paper it is shown how a stability diagram for a commercial alloy can be constructed and how this can be used to correlate the corrosion results with the main experimental parameters, temperature, gas and alloy composition. Using the theoretical model and the presented experimental results, conditions are derived under which a protective chromia based surface scale will be formed which prevents a rapid transfer of carbon between alloy and gas atmosphere. It is shown that this protective surface oxide can only be formed if the carbon monoxide pressure in the gas exceeds a critical value. Psub(CO), which depends on temperature and alloy composition. Additions of methane only have a limited effect provided that the methane/water ratio is not near to, or greater than, a critical value of around 100/1. The influence of minor alloying additions of strong oxide forming elements, commonly present in high temperature alloys, on the protective properties of the chromia surface scales and the kinetics of carbon transfer is illustrated. (orig.) [de

  20. Diffusion-bonded 16MND5-Inconel 690-316LN junction: elaboration and process residual stresses modeling

    International Nuclear Information System (INIS)

    Martinez, Michael

    1999-01-01

    The objective of this research thesis is, on the one hand, to elaborate and to characterise a bonded junction of 16MND5 and 316LN steels, and, on the other hand, to develop a simulation tool for the prediction of microstructures after bonding, as well as residual stresses related to this process. The author first reports the study of the use of diffusion bonding by hot isostatic pressing (HIP diffusion bonding) for the bonding of 16MND5 (steel used in French PWR vessel) and 316LN (austenitic stainless steel used in piping), in order to obtain junctions adapted to a use within PWRs. In this case, the use of an Inconel insert material appeared to be necessary to avoid stainless steel carburization. Thus, inserts in Inconel 600 and 690 have been tested. The objective has then been to develop a realistic calculation of residual stresses in this assembly. These stresses are stimulated by quenching. The author notably studied the simulation of temperature dependent phase transformations, and stress induced phase transformations. An existing model is validated and applied to HIP and quenching cycles. The last part reports the calculation of residual stresses by simulation of the mechanical response of the three-component material cooled from 900 C to room temperature and thus submitted to a loading of thermal origin (dilatation) and metallurgical origin (phase transformations in the 16MND5). The effect of carbon diffusion on mechanical properties has also been taken into account. The author discusses problems faced by existing models, and explains the choice of conventional macro-mechanical models. The three materials are supposed to have a plastic-viscoplastic behaviour with isotropic and kinematic strain hardening, and this behaviour is identified between 20 and 900 C [fr

  1. Controlled formation of iron carbides and their performance in Fischer-Tropsch synthesis

    KAUST Repository

    Wezendonk, Tim A.

    2018-04-19

    Iron carbides are unmistakably associated with the active phase for Fischer-Tropsch synthesis (FTS). The formation of these carbides is highly dependent on the catalyst formulation, the activation method and the operational conditions. Because of this highly dynamic behavior, studies on active phase performance often lack the direct correlation between catalyst performance and iron carbide phase. For the above reasons, an extensive in situ Mössbauer spectroscopy study on highly dispersed Fe on carbon catalysts (Fe@C) produced through pyrolysis of a Metal Organic Framework was coupled to their FTS performance testing. The preparation of Fe@C catalysts via this MOF mediated synthesis allows control over the active phase formation and therefore provides an ideal model system to study the performance of different iron carbides. Reduction of fresh Fe@C followed by low-temperature Fischer-Tropsch (LTFT) conditions resulted in the formation of the ε′-Fe2.2C, whereas carburization of the fresh catalysts under high-temperature Fischer-Tropsch (HTFT) resulted in the formation of χ-Fe5C2. Furthermore, the different activation methods did not alter other important catalyst properties, as pre- and post-reaction transmission electron microscopy (TEM) characterization confirmed that the iron nanoparticle dispersion was preserved. The weight normalized activities (FTY) of χ-Fe5C2 and ε′-Fe2.2C are virtually identical, whilst it is found that ε′-Fe2.2C is a better hydrogenation catalyst than χ-Fe5C2. The absence of differences under subsequent HTFT experiments, where χ-Fe5C2 is the dominating phase, is a strong indication that the iron carbide phase is responsible for the differences in selectivity.

  2. A simplified method for preparing micro-samples for the simultaneous isotopic analysis of uranium and plutonium

    International Nuclear Information System (INIS)

    Carter, J.A.; Walker, R.L.; Eby, R.E.; Pritchard, C.A.

    1976-01-01

    In this simplified technique a basic anion resin is employed to selectively adsorb plutonium and uranium from 8M HNO 3 solutions containing dissolved spent reactor fuels. After a few beads of the resin are equilibrated with solution, a single bead is used for establishing the isotopic composition of plutonium and uranium. The resin-bead separation essentially removes all possible isobaric interference from such elements as americium and curium and at the same time eliminates most fission-product contamination in the mass spectrometer. Small aliquots of dissolver solution that contain 10 -6 g U and 10 -8 g Pu are adequate for preparing about ten resin beads. By employing a single focusing tandem magnet-type mass spectrometer, equipped with pulse counting for ion detection, simultaneous plutonium and uranium assays are obtained. The quantity of each element per bead may be as low as 10 -9 to 10 -10 g. The carburized bead, which forms as the filament is heated, acts as a reducing point source and emits a predominance of metallic ions as compared with oxide ion emission from direct solution loadings. In addition to isotopic abundance, the technique of isotope dilution can ve coupled with the ion-exchange bead separation and used effectively for measuring the total quantity of U and Pu. The technique possesses many advantages such as reduced radiation hazards from the infinitely smaller samples, thus less shielding and transport cost for sample handling; greatly simplified chemical preparations that eliminate fission products and actinide isobaric interferences; and the minor isotopes are more precisely established. (author)

  3. The influence of welding and post heat treatment parameters on the diffusion and precipitation processes in dissimilar metal joints of a 1% and a 12% Cr-steel

    International Nuclear Information System (INIS)

    Kullik, M.; Katerbau, K.H.

    1989-05-01

    The influences of different weld metals, welding processes and post weld heat treatments (PWHT) on mechanical properties, carbon diffusion and precipitation processes were investigated by studying dissimilar metal welds between the cast steel GS-17 CrMoV 5 11 (1% Cr) and the steel X 20 CrMoV 12 1 (12% Cr). By means of tensile and impact tests, metallographic investigation, hardness measurements, electron beam X-ray microanalysis and transmission electron microscope examination changes in the welded joints were shown after different PWHT's as well as after creep tests. It was found that the joint with a 5% CrMoV-weld metal shows higher yield and rupture strength than the joint with a 12% CrMoV-weld metal. With increasing heat input during PWHT the strength decreases for both welds, but always remains higher than the values of the base materials. During PWTH as well as during service at elevated temperatures carbon diffuses from the lower chromium material to the higher chromium material. Width and carbon concentration of the carburized and decarburized zones depend on the heat input. A simple diffusion model was developed to describe the carbon profile for any annealing time and temperature. The consequence of the decarburization is a microstructural change in the heat effected zone of the cast steel. During longer annealing the fine M 2 C-carbides dissolve and coarse M 6 C-crbides form, resulting in a lower creep ductility of this zone. (orig.) With 19 refs., 15 tabs., 104 figs [de

  4. Effect of Deep Cryogenic Treatment on Hardness and Wear Behavior of 5120 AISI Steel

    Directory of Open Access Journals (Sweden)

    S. Torkian

    2016-12-01

    Full Text Available In this paper the effect of deep cryogenic treatment time on microstructure and tribological behavior of AISI 5120 case hardennig steel is studied. The disk shape samples were carburized at 920 ◦C for 6 hours and air cooled; after austenitizing, the samples were quenched in oil.Then immediately after quenching and sanding, the sample were kept in liquid nitrogen for 1, 24, 30 and 48 h and then tempered at 200 ◦C for 2 hours. The wear test was done by ball on disk method using of WC ball at 80 and 110 N load. For characterization of carbides, the etchant solution of CuCl2 (5 gr+HCl (100 mL + ethanol (100 mL was used. The hardness of samples before and after of tempering was measured by vicers method at 300 N load.. The amount of retained austenite was measured by X Ray Diffraction method. For 1DCT and 24DCT samples it was about 8% and 4%; in the other samples, the retained austenite peal was so decreased that it was not visible. The result showed that the hardness increases by deep cryogenic treatment in all speciments. While wear resistance increases in 1DCT and 24DCT samples, it decreases for 30DCT and 48DCT samples in compare with Conventional heat treatment (CHT sample in both applied loads, such that , 48DCT sample has the least wear resistance. The cause of increament of hardness is due to reduction in amount of retained austenite as a result of deep cryogenic treatment and decreasing in wear resistance after 24 hour, is due to carbide growth and nonhemogenuse distribution in microstructure and then weakening of matrix. So the 24 hour deep cryogenic treatment was the best optimal for AISI 5120 steel.

  5. Improvement of mechanical strength of sintered Mo alloyed steel by optimization of sintering and cold-forging processes with densification

    Science.gov (United States)

    Kamakoshi, Y.; Shohji, I.; Inoue, Y.; Fukuda, S.

    2017-10-01

    Powder metallurgy (P/M) materials have been expected to be spread in automotive industry. Generally, since sintered materials using P/M ones contain many pores and voids, mechanical properties of them are inferior to those of conventional wrought materials. To improve mechanical properties of the sintered materials, densification is effective. The aim of this study is to improve mechanical strength of sintered Mo-alloyed steel by optimizing conditions in sintering and cold-forging processes. Mo-alloyed steel powder was compacted. Then, pre-sintering (PS) using a vacuum sintering furnace was conducted. Subsequently, coldforging (CF) by a backward extrusion method was conducted to the pre-sintered specimen. Moreover, the cold-forged specimen was heat treated by carburizing, tempering and quenching (CQT). Afterwards, mechanical properties were investigated. As a result, it was found that the density of the PS specimen is required to be more than 7.4 Mg/m3 to strengthen the specimen by heat treatment after CF. Furthermore, density and the microstructure of the PS specimen are most important factors to make the high density and strength material by CF. At the CF load of 1200 kN, the maximum density ratio reached approximately 99% by the use of the PS specimen with proper density and microstructure. At the CF load of 900 kN, although density ratio was high like more than 97.8%, transverse rupture strength decreased sharply. Since densification caused high shear stress and stress concentration in the surface layer, microcracks occurred by the damages of inter-particle sintered connection of the surface layer. On the contrary, in case of the CF load of 1200 kN, ultra-densification of the surface layer occurred by a sufficient plastic flow. Such sufficient compressed specimens regenerated the sintered connections by high temperature heat treatment and thus the high strength densified material was obtained. These processes can be applicable to near net shape manufacturing

  6. Thermoanalytical investigation of the hydrogen absorption behaviour of Sm{sub 2}Fe{sub 17-x}Ga{sub x} at high hydrogen pressures

    Energy Technology Data Exchange (ETDEWEB)

    Handstein, A.; Kubis, M.; Gebel, B.; Mueller, K.-H.; Schultz, L. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany). Inst. fuer Metallische Werkstoffe; Gutfleisch, O.; Harris, I.R. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany). Inst. fuer Metallische Werkstoffe]|[Birmingham Univ. (United Kingdom). School of Metallurgy and Materials

    1998-07-01

    The complete disproportionation of Sm{sub 2}Fe{sub 17-x}Ga{sub x} during annealing in hydrogen is hindered due to an increased stability of the compounds with a higher Ga content (x {>=} 1). Therefore the HD process as the first step of HDDR (hydrogenation-disproportionation-desorption-recombination) has to be carried out at a high hydrogen pressure for x {>=} 1. The hydrogen absorption behaviour of Sm{sub 2}Fe{sub 17-x}Ga{sub x} (x = 0, 0.5, 1 and 2) was investigated by means of hydrogen differential thermal analysis (HDTA) and high pressure differential scanning calorimetry (HPDSC) at hydrogen pressures up to 70 bar. A dependency of hydrogenation and disproportionation temperatures on hydrogen pressure and Ga content was found. The comparison with other substituents (M = Al and Si) instead of M = Ga showed an increased stability of Sm{sub 2}Fe{sub 17-x}M{sub x} compounds against disproportionation by hydrogen in the sequence Al, Ga and Si. The Curie temperatures of the interstitially hydrogenated Th{sub 2}Zn{sub 17}-type materials increase with the hydrogen pressure. In order to produce coercive and thermally stable Sm{sub 2}Fe{sub 15}Ga{sub 2}C{sub y} powder by means of the HDDR process, we recombined material disproportionated at different hydrogen pressures. Preliminary results of magnetic properties of this HDDR treated and gas-carburized Sm{sub 2}Fe{sub 15}Ga{sub 2}C{sub y} are discussed. (orig.)

  7. Production de méthanol et d'alcools supérieurs à partir de gaz via (CO + H2 Production of Methanol and Higher Alcohols from Gas via (Co + H2

    Directory of Open Access Journals (Sweden)

    Kawata N.

    2006-11-01

    Full Text Available Dans le cadre des procédés en développement pour la synthèse d'alcools à partir de syngas (CO + H2, ce mémoire présente certains résultats récents de l'Institut Français du Pétrole (IFP (France et Idemitsu Kosan (Japon. La première démonstration du procédé, sous programme R et D du RAPAD-Japon, a confirmé les performances et la faisabilité. Les alcools sélectivement produits, après fractionnement, présentent de bonnes propriétés pour l'usage carburant. L'optimisation de l'ensemble constitué par la production du syngas, la synthèse, le fractionnement des alcools, a permis une simplification sensible du procédé, une optimisation spécifique des performances, ce qui conduit à des données économiques plus favorables. Within the framework of processes being developed for alcohol synthesis from syngas, this article describes some recent results obtained by Idemitsu-Kosan (Japan and Institut Français du Pétrole (IFP (France. The first demonstration of the process as part of the RAPAD-Japan R & D program has confirmed both its performances and feasibility. The alcohols selectively produced, after suitable fractionation, present good properties as a blend for motor fuels. The optimization of the overall process for syngas production, alcohol synthesis and alcohol fractionation has led to a significant simplification of the process and to the optimization of its performances, leading to better economics.

  8. Advances in carbide fuel element development for fast reactor application

    International Nuclear Information System (INIS)

    Dienst, W.; Kleykamp, H.; Muehling, G.; Reiser, H.; Steiner, H.; Thuemmler, F.; Wedermeyer, H.; Weimar, P.

    1977-01-01

    The features of the carbide fuel development programme are reviewed and evaluated. Single pin and bundle irradiations are carried out under thermal, epithermal and fast flux conditions, the latter in the DFR and KNK-II reactors. Several fuel concepts in the region of representative SNR clad temperatures are compared by parameter and performance tests. A conservative concept is based on He-bonded 8 mm pins with (U,Pu)C pellets and a smear density of 75% TD, operating at 800 W/cm rod power and burnup to 70 MWd/kg. The preparation of mixed carbide fuels is carried out by carbothermic reduction of the oxides in different methods supported by equivalent carbon content, grain size and phase distribution analysis. The fuel for subassembly performance tests is produced in a pilot plant of 0,5 t/year capacity. Compatibility studies reveal that cladding carburization is the only chemical interaction with carbide fuels. This effect leads to a reduction in ductility of the stainless steel. Fission products apparently play no role in the compatibility behaviour. Comprehensive studies lead to reliable information on the chemical and thermodynamic state of the fuel under irradiation. The swelling of carbide fuels and the fission gas release are examined and analysed. Cladding plastic strain by fuel swelling occurs during steady-state operation because the irradiation creep is rather slow compared to oxide fuels. The cladding strain observed depends on the fuel porosity and the cladding strength. The development of carbide fuel pins is complemented by the application of comprehensive computer models. In addition to the steady-state tests power cycling and safety tests are under performance. Up to 1980 the results are summarized for the final design and specification. The development target of the present program is to fabricate several subassemblies for test operation in the SNR 300 by 1981

  9. Electrochemical Impedance Response of the surface treated FMS in Liquid Sodium Environment

    International Nuclear Information System (INIS)

    Lee, Jeong Hyeon; Shin, Sang Hun; Kim, Ji Hyun

    2014-01-01

    HT9 and Gr.92 are known as compatible in sodium environment because the usual refueling time of SFRs is designed about 54 months. It is very important to investigate the corrosion-related behavior such as surface corrosion rate, carburization, decarburization and mechanical properties for its operation time. SiC and Si 3 N 4 CVD coating for decarburization barrier on the surface of FMS is considered in this study. The decarburization process where dissolved carbon near the specimen surface disused in to the liquid sodium. This process can originate from the difference between dissolved carbon in the material and liquid sodium. A compatibility test the cladding tube revealed that a decrease of the mechanical property instigated by the aging proves governed the whole mechanical property. To monitor the corrosion behavior of these candidate materials in sodium environment, Electrochemical Impedance Spectroscopy (EIS) method is first introduced and investigated in this study. The compatibility of cladding and structural materials with sodium has to be carefully investigated, as sodium could promote corrosion of cladding and structural materials in two ways. One is produced by the dissolution of alloy constituents into the sodium, and the other is produced through a chemical reaction with impurities (especially oxygen and carbon) in the sodium environment. EIS test with pre-oxidized Gr. 92 specimen in 200 .deg. C liquid sodium environment was carried out in this study. A clear Nyquist and Bode plots were obtained in liquid metal environment and the resistance of sodium and the oxide, and the capacitance of the oxide were measured from this result

  10. Anisotropic atomic packing model for abnormal grain growth mechanism of WC-25 wt.% Co alloy

    International Nuclear Information System (INIS)

    Ryoo, H.S.; Hwang, S.K.

    1998-01-01

    During liquid phase sintering, cemented carbide particles grow into either faceted or non-faceted grain shapes depending on ally system. In case of WC-Co alloy, prism-shape faceted grains with (0001) planes and {1 bar 100} planes on each face are observed, and furthermore an abnormal grain growth has been reported to occur. When abnormal grain growth occurs in WC crystals, dimension ratio, R, of the length of the side of the triangular prism face to the height of the prism is higher than 4 whereas that for normal grains is approximately 2. Abnormal grain growth in this alloy is accelerated by the fineness of starting powders and by high sintering temperature. To account for the mechanism of the abnormal grain growth, there are two proposed models which drew much research attention: nucleation and subsequent carburization and transformation of η (W 3 Co 3 C) phase into WC, and coalescence of coarse WC grains through dissolution and re-precipitation. Park et al. proposed a two-dimensional nucleation theory to explain the abnormal grain growth of faceted grains. There are questions, however, on the role of η phase on abnormal grain growth. The mechanism of coalescence of spherical grains as proposed by Kingery is also unsuitable for faceted grains. So far theories on abnormal grain growth do not provide a satisfactory explanation on the change of R value during the growth process. In the present work a new mechanism of nucleation and growth of faceted WC grains is proposed on the ground of anisotropic packing sequence of each atom

  11. The structure of para-toluidine by X-ray and neutron diffraction; Etude de la structure de la para-toluidine par la diffraction des rayons X et des neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Bertinotti, A L [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-12-01

    The crystal and molecular structure of para-toluidine has been solved by X-ray and neutron diffraction counter techniques. The molecules are arranged in the form of infinite chains in the crystal, each molecule being linked to two neighbours by hydrogen bonds. The presence of the H bonds makes clear the difference in the melting points between para-toluidine and benzene hydrocarbons of related symmetry and molecular weight. Their direction accounts for the (001) cleavage and the growth anisotropy of crystals from supersaturated vapour phase. A structure-seeking method by computer has been elaborated, using lattice energy calculations applied to molecules treated as rigid bodies and making use of a simplex method for function minimization without calculation of derivatives. The way the available information is handled allows to increase the range of convergence, as shown in the case of para-toluidine. (author) [French] La structure cristalline et moleculaire de la para-toluidine a ete resolue a l'aide de la diffraction des rayons X et des neutrons. L'analyse a revele que la structure presentait un encha ement particulier des molecules, liees entre elles par des ponts hydrogene. La presence des liaisons rend compte de l'elevation du point de fusion de la para-toluidine par rapport a celui des carbures benzeniques de symetrie et de poids moleculaires voisins. La direction des liaisons explique le clivage facile (001) des cristaux obtenus par fusion et l'anisotropie de croissance des cristaux en phase vapeur. Une methode de recherche de structures par ordinateur a ete elaboree, faisant usage du concept d'energie reticulaire applique aux molecules considerees comme rigides et faisant appel a une methode de simplexe pour la minimisation des fonctions sans calcul de derivees. La maniere dont est exploitee l'information disponible permet d'accro re, comme cela est montre dans le cas de la para-toluidine, l'etendue du domaine de convergence. (auteur)

  12. High temperature corrosion of metals

    International Nuclear Information System (INIS)

    Quadakkers, W.J.; Schuster, H.; Ennis, P.J.

    1988-08-01

    This paper covers three main topics: 1. high temperature oxidation of metals and alloys, 2. corrosion in sulfur containing environments and 3. structural changes caused by corrosion. The following 21 subjects are discussed: Influence of implanted yttrium and lanthanum on the oxidation behaviour of beta-NiA1; influence of reactive elements on the adherence and protective properties of alumina scales; problems related to the application of very fine markers in studying the mechanism of thin scale formation; oxidation behaviour of chromia forming Co-Cr-Al alloys with or without reactive element additions; growth and properties of chromia-scales on high-temperature alloys; quantification of the depletion zone in high temperature alloys after oxidation in process gas; effects of HC1 and of N2 in the oxidation of Fe-20Cr; investigation under nuclear safety aspects of Zircaloy-4 oxidation kinetics at high temperatures in air; on the sulfide corrosion of metallic materials; high temperature sulfide corrosion of Mn, Nb and Nb-Si alloys; corrosion behaviour or NiCrAl-based alloys in air and air-SO2 gas mixtures; sulfidation of cobalt at high temperatures; preoxidation for sulfidation protection; fireside corrosion and application of additives in electric utility boilers; transport properties of scales with complex defect structures; observations of whiskers and pyramids during high temperature corrosion of iron in SO2; corrosion and creep of alloy 800H under simulated coal gasification conditions; microstructural changes of HK 40 cast alloy caused by exploitation in tubes in steam reformer installation; microstructural changes during exposure in corrosive environments and their effect on mechanical properties; coatings against carburization; mathematical modeling of carbon diffusion and carbide precipitation in Ni-Cr-based alloys. (MM)

  13. Advanced Gear Alloys for Ultra High Strength Applications

    Science.gov (United States)

    Shen, Tony; Krantz, Timothy; Sebastian, Jason

    2011-01-01

    Single tooth bending fatigue (STBF) test data of UHS Ferrium C61 and C64 alloys are presented in comparison with historical test data of conventional gear steels (9310 and Pyrowear 53) with comparable statistical analysis methods. Pitting and scoring tests of C61 and C64 are works in progress. Boeing statistical analysis of STBF test data for the four gear steels (C61, C64, 9310 and Pyrowear 53) indicates that the UHS grades exhibit increases in fatigue strength in the low cycle fatigue (LCF) regime. In the high cycle fatigue (HCF) regime, the UHS steels exhibit better mean fatigue strength endurance limit behavior (particularly as compared to Pyrowear 53). However, due to considerable scatter in the UHS test data, the anticipated overall benefits of the UHS grades in bending fatigue have not been fully demonstrated. Based on all the test data and on Boeing s analysis, C61 has been selected by Boeing as the gear steel for the final ERDS demonstrator test gearboxes. In terms of potential follow-up work, detailed physics-based, micromechanical analysis and modeling of the fatigue data would allow for a better understanding of the causes of the experimental scatter, and of the transition from high-stress LCF (surface-dominated) to low-stress HCF (subsurface-dominated) fatigue failure. Additional STBF test data and failure analysis work, particularly in the HCF regime and around the endurance limit stress, could allow for better statistical confidence and could reduce the observed effects of experimental test scatter. Finally, the need for further optimization of the residual compressive stress profiles of the UHS steels (resulting from carburization and peening) is noted, particularly for the case of the higher hardness C64 material.

  14. Insights on finite size effects in ab initio study of CO adsorption and dissociation on Fe 110 surface

    Energy Technology Data Exchange (ETDEWEB)

    Chakrabarty, Aurab, E-mail: aurab.chakrabarty@qatar.tamu.edu; Bouhali, Othmane [Texas A& M University at Qatar, P.O. Box 23874, Doha (Qatar); Mousseau, Normand [Département de Physique and RQMP, Université de Montréal, Case Postale 6128, Succursale Centre-ville, Montréal, Québec H3C 3J7 (Canada); Becquart, Charlotte S. [UMET, UMR CNRS 8207, ENSCL, Université Lille I, 59655 Villeneuve d' Ascq Cédex (France); El-Mellouhi, Fedwa [Qatar Environment and Energy Research Institute, Hamad Bin Khalifa University, P.O. Box 5825, Doha (Qatar)

    2016-08-07

    Adsorption and dissociation of hydrocarbons on metallic surfaces represent crucial steps on the path to carburization, eventually leading to dusting corrosion. While adsorption of CO molecules on Fe surface is a barrier-less exothermic process, this is not the case for the dissociation of CO into C and O adatoms and the diffusion of C beneath the surface that are found to be associated with large energy barriers. In practice, these barriers can be affected by numerous factors that combine to favour the CO-Fe reaction such as the abundance of CO and other hydrocarbons as well as the presence of structural defects. From a numerical point of view, studying these factors is challenging and a step-by-step approach is necessary to assess, in particular, the influence of the finite box size on the reaction parameters for adsorption and dissociation of CO on metal surfaces. Here, we use density functional theory (DFT) total energy calculations with the climbing-image nudged elastic band method to estimate the adsorption energies and dissociation barriers for different CO coverages with surface supercells of different sizes. We further compute the effect of periodic boundary condition for DFT calculations and find that the contribution from van der Waals interaction in the computation of adsorption parameters is important as they contribute to correcting the finite-size error in small systems. The dissociation process involves carbon insertion into the Fe surface causing a lattice deformation that requires a larger surface system for unrestricted relaxation. We show that, in the larger surface systems associated with dilute CO-coverages, C-insertion is energetically more favourable, leading to a significant decrease in the dissociation barrier. This observation suggests that a large surface system with dilute coverage is necessary for all similar metal-hydrocarbon reactions in order to study their fundamental electronic mechanisms, as an isolated phenomenon, free from

  15. Theoretical and experimental study of multilayers interferential reflectors for neutrons: SUPERMIRRORS

    International Nuclear Information System (INIS)

    Maaza, M.

    1991-10-01

    The aim of this study was the realization of (Ni-Ti) supermirror neutron guides which have good performances both optically and morphologically. To achieve this, we closed in gradually to evaluate better fundamental and technological problems. In the beginning, the study was oriented towards decoupling the effects of the different defects in the (Ni-Ti) multilayer and to tackle them one by one. In the first part, we present the classical neutrons guides and their limits and compare them with the supermirror guides and their advantages. Next, we describe the neutron optics formalism in analogy with electromagnetic classical optics, in particular X ray radiation. We have essentially employed the Grazing Angle Neutron Reflectometry technique for the investigation of our samples. These experimental results have been complemented by those of other surface investigation techniques: -optical, magnetic, electronic and ionic ones. The results were in almost overall agreement. More precisely, the neutron reflectivity profiles were treated by using the Abeles matrix formalism for an electromagnetic wave in S polarized state. In the third time, we present the whole of the experimental results obtained. The combination of the latter two effects (hydrogenation of titanium and carburation of nickel) which has not yet been achieved constitutes a direct continuation of this work. This could improve even further both the neutron reflectivity and the critical angle by coupling Mezei-Dagleish and Hayter-Mook stacks. A simulation has shown that a stack of this type consists of 15 bilayers (Ni x C-TiH 2 ) has the same reflectivity as a stack of 60 bilayers (Ni-Ti). (author)

  16. Electrolytic plasma processing of steel surfaces

    International Nuclear Information System (INIS)

    Bejar, M.A; Araya, R.N; Baeza, B

    2006-01-01

    The thermo-chemical treatments of steels with plasma is normally carried out in low-pressure ionized gaseous atmospheres. Among the treatments used most often are: nitruration, carburization and boronized. A plasma can also generate at atmospheric pressure. One way to produce it is with an electrochemical cell that works at a relatively high inter-electrode voltage and under conditions of heavy gas generation. This type of plasma is known as electrolytic plasma. This work studies the feasibility of using electrolytic plasma for the surface processing of steels. Two processes were selected: boronized and nitruration., for the hardening of two types of steel: one with low carbon (1020) and one with low alloy (4140). In the case of the nitruration, the 1020 steel was first aluminized. The electrolytes were aqueous solutions of borax for the boronizing and urea for the nitruration. The electrolytic plasmas were classified qualitatively, in relation with their luminosity by low, medium and high intensity. The boronizing was carried out with low intensity plasmas for a period of one hour. The nitruration was performed with plasmas of different intensities and for period of a few minutes to half an hour. The test pieces processed by electrolytic plasma were characterized by micro-hardness tests and X-ray diffraction. The maximum surface hardnesses obtained for the 1020 and 4140 steels were the following: 300 and 700 HV for the boronizing, and 1650 and 1200 HV for the nitruration, respectively. The utilization of an electrolytic plasma permits the surface processing of steels, noticeably increasing their hardness. With this type of plasma some thermo-chemical surface treatments can be done very rapidly as well (CW)

  17. Chemical sensors for monitoring non-metallic impurities in liquid sodium coolant

    International Nuclear Information System (INIS)

    Ganesan, Rajesh; Jayaraman, V.; Rajan Babu, S.; Sridharan, R.; Gnanasekaran, T.

    2011-01-01

    Liquid sodium is the coolant of choice for fast breeder reactors. Liquid sodium is highly compatible with structural steels when the concentration of dissolved non-metallic impurities such as oxygen and carbon are low. However, when their concentrations are above certain threshold limits, enhanced corrosion and mass transfer and carburization of the steels would occur. The threshold concentration levels of oxygen in sodium are determined by thermochemical aspects of various ternary oxides of Na-M-O systems (M alloying elements in steels) which take part in corrosion and mass transfer. Dissolved carbon also influences these threshold levels by establishing relevant carbide equilibria. An event of steam leak into sodium at the steam generator, if undetected at its inception itself, can lead to extensive wastage of the tubes of the steam generator and prolonged shutdown. Air ingress into the argon cover gas and leak of hydrocarbon oil used as cooling fluids of the shafts of the centrifugal pumps of sodium are the sources of oxygen and carbon impurities in sodium. Continuous monitoring of the concentration of dissolved hydrogen, carbon and oxygen in sodium coolant will help identifying their ingress at inception itself. An electrochemical hydrogen sensor based on CaHBr-CaBr 2 hydride ion conducting solid electrolyte has been developed for detecting the steam leak during normal operating conditions of the reactor. A nickel diffuser based sensor system using thermal conductivity detector (TCD) and Pd-doped tin oxide thin film sensor has been developed for use during low power operations of the reactor or during its start up. For monitoring carbon in sodium, an electrochemical sensor with molten Na 2 CO 3 -LiCO 3 as the electrolyte and pure graphite as reference electrode has been developed. Yttria Doped Thoria (YDT) electrolyte based oxygen sensor is under development for monitoring dissolved oxygen levels in sodium. Fabrication, assembly, testing and performance of

  18. Presence de Carbone-13 dans les elements combustibles de type (U,Pu)O 2 irradies en reacteur rapide

    Science.gov (United States)

    Kryger, Bernard; Hagemann, Robert

    1982-06-01

    Du carbone-13 produit par la réaction de capture neutronique 168O + 10n → 136C + 42He se forme dans les combustibles de type oxyde irradiés en neutrons rapides. Cette réaction, dont le seuil d'énergie se situe à 2.35 MeV, conduit à la formation d'une quantité de carbone-13 qui peut varier notablement suivant le spectre neutronique du réacteur (entre 20 et 40 × 10 -6g 13C/g (U,Pu)O 2 pour une fluence de 2 × 10 23 n/cm 2). DES mesures effectuées sur le combustible et la gaine par spectrométrie de masse après irradiation montrent qu'une fraction égale ou supérieure à la moitié du carbone-13 produit dans l'oxyde peut être transférée dans la gaine. Un tel comportement nous fait considérer le carbone-13 comme un véritable marqueur du carbone plus généralement contenu dans l'oxyde et, à ce titre, la détection de cet isotope devrait contribuer à élucider tout particulièrement les mécanismes de carburation de la gaine par les combustibles (U,Pu)O 2 des réacteurs surgénérateurs.

  19. Nanodiamond for tuning the properties of energetic composites.

    Science.gov (United States)

    Pichot, Vincent; Comet, Marc; Miesch, Julien; Spitzer, Denis

    2015-12-30

    Bismuth oxide (Bi2O3) particles were coated by detonation nanodiamonds. The resulting nanocomposite materials were mixed with an aluminum nanopowder (≈ 100 nm) to prepare nanothermites, with reduced sensitivity to friction and electrostatic discharge (ESD). The use of nanodiamond for this purpose is reported here for the first time. Their numerous qualities such as their small size, antifriction properties and thermal conductivity make them ideal candidates. Small amounts of detonation nanodiamonds allow obtaining impressive desensitization, making thus modified Bi2O3/Al nanothermite safe to handle. A composition containing around 1 wt.% of nanodiamond has a sensitivity threshold to friction superior to 100 N instead of 5 N for the thermite without nanodiamond. Furthermore, the sensitivity threshold to electrostatic discharge increases to 20 times when the nanodiamond content reaches 1.8 wt.%. The antifriction properties of nanodiamond limit the scratching of Bi2O3 surface by Al particles. The desensitization to ESD is observed for a sufficient coverage of the oxide particles (1.8 wt.% of ND), which restrains the effect of the melt dispersion mechanism of aluminum and prevents the mixing of the oxidizing and the reducing parts of the composites. A good reactivity of the thermite could be maintained for nanodiamond content up to 2.6 wt.%. The carburizing of aluminum coming on contact with nanodiamond during the thermite reaction could be evidenced by X-ray Diffraction and calorimetry measurements and also participates to the desensitization of the nanothermite. This kind of desensitization by using detonation nanodiamond can also be applied to other nanothermites having low sensitivity threshold to friction and ESD. Copyright © 2015 Elsevier B.V. All rights reserved.

  20. Effect of sodium environment on the creep-rupture and low-cycle fatigue behavior of austenitic stainless steels

    International Nuclear Information System (INIS)

    Natesan, K.; Chopra, D.K.; Zeman, G.J.; Smith, D.L.; Kassner, T.F.

    1977-01-01

    Austenitic stainless steels used for in-core structural components, piping, valves, and the intermediate heat exchanger in Liquid-Metal Fast-Breeder Reactors (LMFBRs) are subjected to sodium at elevated temperatures and to complex stress conditions. As a result, the materials can undergo compositional and microstructural changes as well as mechanical deformation by creep and cyclic fatigue processes. In the present paper, information is presented on the creep-rupture and low-cycle fatigue behavior of Types 304 and 316 stainless steel in the solution-annealed condition and after long-term exposure to flowing sodium. The nonmetallic impurity-element concentrations in the sodium were controlled at levels similar to those in EBR-II primary sodium. Strain-time relationships developed from the experimental creep data were used to generate isochronous stress-creep strain curves as functions of sodium-exposure time and temperature. The low-cycle fatigue data were used to obtain relationships between plastic strain range and cycles-to-failure based on the Coffin-Manson formalism and a damage-rate approach developed at ANL. An analysis of the cyclic stress-strain behavior of the materials showed that the strain-hardening rates for the sodium-exposed steels were larger than those for the annealed material. However, the sodium-exposed specimens showed significant softening, as evidenced by the lower stress at half the fatigue life. Microstructural information obtained from the different specimens suggests that crack initiation is more difficult in the long-term sodium-exposed specimens when compared with the solution-annealed material. Based on the expected carbon concentrations in LMFBR primary system sodium, moderate carburization of the austenitic stainless steels will not degrade the mechanical properties to a significant extent, and therefore, will not limit the performance of out-of-core components. (author)