Carbon-13 isotope effects on 199Hg nuclear shielding
International Nuclear Information System (INIS)
Sebald, Angelika; Wrackmeyer, Bernd
1985-01-01
Secondary 13 C/ 12 C isotope effects on 199 Hg nuclear shielding (Δdeltasup(i)( 199 Hg)) are of interest because of the unusual shift to high frequency which has been observed for a few alkyl mercury compounds. Continuing interest in the NMR parameters of mercury compounds prompted a search for the values Δdeltasup(i)( 199 Hg) in a greater variety of organomercurials. This should help to find out about the range of Δdeltasup(i)( 199 Hg) and to obtain a firmer basis for the discussion of the high-frequency shifts. The data and experimental conditions are given for chemical shifts delta 199 Hg, coupling constants sup(n)J( 199 Hg 13 C) and 13 C/ 12 C isotope shifts Δdeltasup(i)( 199 Hg) of fourteen 199 Hg organomercury compounds. The results are discussed. (author)
Nuclear spin circular dichroism
International Nuclear Information System (INIS)
Vaara, Juha; Rizzo, Antonio; Kauczor, Joanna; Norman, Patrick; Coriani, Sonia
2014-01-01
Recent years have witnessed a growing interest in magneto-optic spectroscopy techniques that use nuclear magnetization as the source of the magnetic field. Here we present a formulation of magnetic circular dichroism (CD) due to magnetically polarized nuclei, nuclear spin-induced CD (NSCD), in molecules. The NSCD ellipticity and nuclear spin-induced optical rotation (NSOR) angle correspond to the real and imaginary parts, respectively, of (complex) quadratic response functions involving the dynamic second-order interaction of the electron system with the linearly polarized light beam, as well as the static magnetic hyperfine interaction. Using the complex polarization propagator framework, NSCD and NSOR signals are obtained at frequencies in the vicinity of optical excitations. Hartree-Fock and density-functional theory calculations on relatively small model systems, ethene, benzene, and 1,4-benzoquinone, demonstrate the feasibility of the method for obtaining relatively strong nuclear spin-induced ellipticity and optical rotation signals. Comparison of the proton and carbon-13 signals of ethanol reveals that these resonant phenomena facilitate chemical resolution between non-equivalent nuclei in magneto-optic spectra
International Nuclear Information System (INIS)
Mellink, W.A.
1978-01-01
Carbon-13 NMR spectroscopy and photoelectron spectroscopy have been used to study the electronic structure of symmetric dithienothiophenes and corresponding sulphones. The physical data obtained from both spectroscopic techniques have been interpreted with the aid of quantum mechanical calculations. (Auth.)
Immediate analysis of the oil content of seeds by carbon-13 nuclear magnetic resonance
Energy Technology Data Exchange (ETDEWEB)
Leal, K Z; Costa, V E.U.; Seidl, P R; Campos, M P.A.; Colnago, L A [Instituto Militar de Engenharia, Rio de Janeiro (Brazil). Secao de Quimica
1981-11-01
The carbon 13 nuclear magnetic resonance (CMR) spectra of a series of Brazilian oilseeds was registered. The main constituents of the oils are identified and signals for each carbon atom are assigned. Chemical shifts are estimated for the free fatty acids and compared to those observed from the seeds, with good results. Besides being non-destructive, the RMC method proves to be fast and is useful in the determination of the principal components of the oil fraction of different types of seeds.
Immediate analysis of the oil content of seeds by carbon-13 nuclear magnetic resonance
International Nuclear Information System (INIS)
Leal, K.Z.; Costa, V.E.U.; Seidl, P.R.; Campos, M.P.A.; Colnago, L.A.
1981-01-01
The carbon 13 nuclear magnetic resonance (CMR) spectra of a series of Brazilian oilseeds was registered. The main constituents of the oils are identified and signals for each carbon atom are assigned. Chemical shifts are estimated for the free fatty acids and compared to those observed from the seeds, with good results. Besides being non-destructive, the RMC method proves to be fast and is useful in the determination of the principal components of the oil fraction of different types of seeds. (Author) [pt
Dynamic nuclear spin polarization
Energy Technology Data Exchange (ETDEWEB)
Stuhrmann, H B [GKSS-Forschungszentrum Geesthacht GmbH (Germany)
1996-11-01
Polarized neutron scattering from dynamic polarized targets has been applied to various hydrogenous materials at different laboratories. In situ structures of macromolecular components have been determined by nuclear spin contrast variation with an unprecedented precision. The experiments of selective nuclear spin depolarisation not only opened a new dimension to structural studies but also revealed phenomena related to propagation of nuclear spin polarization and the interplay of nuclear polarisation with the electronic spin system. The observation of electron spin label dependent nuclear spin polarisation domains by NMR and polarized neutron scattering opens a way to generalize the method of nuclear spin contrast variation and most importantly it avoids precontrasting by specific deuteration. It also likely might tell us more about the mechanism of dynamic nuclear spin polarisation. (author) 4 figs., refs.
International Nuclear Information System (INIS)
Da Silva Pinto, P.S.; Eustache, R.P.; Audenaert, M.; Bernassau, J.M.
1996-01-01
This work deals with carbon 13 nuclear magnetic resonance chemical shifts empiric calculations by multi linear regression and molecular modeling. The multi linear regression is indeed one way to obtain an equation able to describe the behaviour of the chemical shift for some molecules which are in the data base (rigid molecules with carbons). The methodology consists of structures describer parameters definition which can be bound to carbon 13 chemical shift known for these molecules. Then, the linear regression is used to determine the equation significant parameters. This one can be extrapolated to molecules which presents some resemblances with those of the data base. (O.L.). 20 refs., 4 figs., 1 tab
Korenev, V. L.
2007-01-01
Linearly polarized light tuned slightly below the optical transition of the negatively charged exciton (trion) in a single quantum dot causes the spontaneous nuclear spin polarization (self-polarization) at a level close to 100%. The effective magnetic field of spin-polarized nuclei brings the optical transition energy into resonance with photon energy. The resonantly enhanced Overhauser effect sustains the stability of the nuclear self-polarization even in the absence of spin polarization of...
Carbon-13 nuclear magnetic resonance of strained organic molecules: III estimates of steric effects
International Nuclear Information System (INIS)
Seidl, P.R.; Leal, K.Z.; Costa, V.E.U.; Rio Grande do Sul Univ., Porto Alegre
1985-01-01
A study of cyclic organic molecules using carbon-13 NMR spectroscopy is analysed. The preparation of compounds and the use of norbornyl compounds as a basis for chemical shifts, bicyclic, tricyclic and tetracyclic derivatives are compared. Relevant distances, angles and non-bonded interactions are shown. (M.J.C.) [pt
Nuclear spins in nanostructures
International Nuclear Information System (INIS)
Coish, W.A.; Baugh, J.
2009-01-01
We review recent theoretical and experimental advances toward understanding the effects of nuclear spins in confined nanostructures. These systems, which include quantum dots, defect centers, and molecular magnets, are particularly interesting for their importance in quantum information processing devices, which aim to coherently manipulate single electron spins with high precision. On one hand, interactions between confined electron spins and a nuclear-spin environment provide a decoherence source for the electron, and on the other, a strong effective magnetic field that can be used to execute local coherent rotations. A great deal of effort has been directed toward understanding the details of the relevant decoherence processes and to find new methods to manipulate the coupled electron-nuclear system. A sequence of spectacular new results have provided understanding of spin-bath decoherence, nuclear spin diffusion, and preparation of the nuclear state through dynamic polarization and more general manipulation of the nuclear-spin density matrix through ''state narrowing.'' These results demonstrate the richness of this physical system and promise many new mysteries for the future. (Abstract Copyright [2009], Wiley Periodicals, Inc.)
International Nuclear Information System (INIS)
1984-01-01
The focus for nuclear energy research in the UK has been mainly the generation of electricity. However, nuclear technology is also applied in many areas other than energy production. Nuclear Spin Off shows how technology has been transferred to industry, agriculture, medicine and other areas, creating considerable material benefit. Nuclear research has produced revolutionary new materials and measuring and detection techniques. This film shows a wide range of uses. (author)
Indian Academy of Sciences (India)
IAS Admin
ments have shown that in some cases the nuclear spin systems may be held in special configurations called .... these methods have been commercialized, and used for clinical trials, in which hyperpolarized NMR is used to .... symmetric under exchange, meaning that exchanging the two nuclei leaves the state unchanged.
International Nuclear Information System (INIS)
1981-11-01
This booklet gives examples of 'nuclear spin off', from research programmes carried out for the UKAEA, under the following headings; non destructive testing; tribology; environmental protection; flow measurement; material sciences; mechanical engineering; marine services; biochemical technology; electronic instrumentation. (U.K.)
Terletska, Hanna; Dobrovitski, Viatcheslav
2015-03-01
The electron spin of the NV center in diamond is a promising platform for spin sensing. Applying the dynamical decoupling, the NV electron spin can be used to detect the individual weakly coupled carbon-13 nuclear spins in diamond and employ them for small-scale quantum information processing. However, the nuclear spins within this approach remain unprotected from decoherence, which ultimately limits the detection and restricts the fidelity of the quantum operation. Here we investigate possible schemes for combining the resonant decoupling on the NV spin with the decoherence protection of the nuclear spins. Considering several schemes based on pulse and continuous-wave decoupling, we study how the joint electron-nuclear spin dynamics is affected. We identify regimes where the all-spin coherence protection improves the detection and manipulation. We also discuss potential applications of the all-spin decoupling for detecting spins outside diamond, with the purpose of implementing the nanoscale NMR. This work was supported by the US Department of Energy Basic Energy Sciences (Contract No. DE-AC02-07CH11358).
Spin temperature concept verified by optical magnetometry of nuclear spins
Vladimirova, M.; Cronenberger, S.; Scalbert, D.; Ryzhov, I. I.; Zapasskii, V. S.; Kozlov, G. G.; Lemaître, A.; Kavokin, K. V.
2018-01-01
We develop a method of nonperturbative optical control over adiabatic remagnetization of the nuclear spin system and apply it to verify the spin temperature concept in GaAs microcavities. The nuclear spin system is shown to exactly follow the predictions of the spin temperature theory, despite the quadrupole interaction that was earlier reported to disrupt nuclear spin thermalization. These findings open a way for the deep cooling of nuclear spins in semiconductor structures, with the prospect of realizing nuclear spin-ordered states for high-fidelity spin-photon interfaces.
Nuclear spin conversion in formaldehyde
Chapovsky, Pavel L.
2000-01-01
Theoretical model of the nuclear spin conversion in formaldehyde (H2CO) has been developed. The conversion is governed by the intramolecular spin-rotation mixing of molecular ortho and para states. The rate of conversion has been found equal 1.4*10^{-4}~1/s*Torr. Temperature dependence of the spin conversion has been predicted to be weak in the wide temperature range T=200-900 K.
Erlingsson, S.I.
2003-01-01
The main theme of this thesis is the hyperfine interaction between the many lattice nuclear spins and electron spins localized in GaAs quantum dots. This interaction is an intrinsic property of the material. Despite the fact that this interaction is rather weak, it can, as shown in this thesis,
Electron spin and nuclear spin manipulation in semiconductor nanosystems
International Nuclear Information System (INIS)
Hirayama, Yoshiro; Yusa, Go; Sasaki, Satoshi
2006-01-01
Manipulations of electron spin and nuclear spin have been studied in AlGaAs/GaAs semiconductor nanosystems. Non-local manipulation of electron spins has been realized by using the correlation effect between localized and mobile electron spins in a quantum dot- quantum wire coupled system. Interaction between electron and nuclear spins was exploited to achieve a coherent control of nuclear spins in a semiconductor point contact device. Using this device, we have demonstrated a fully coherent manipulation of any two states among the four spin levels of Ga and As nuclei. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Nuclear spin and isospin excitations
International Nuclear Information System (INIS)
Osterfeld, F.
1992-01-01
A review is given of our present knowledge of collective spin-isospin excitations in nuclei. Most of this knowledge comes from intermediate-energy charge-exchange reactions and from inelastic electron- and proton-scattering experiments. The nuclear-spin dynamics is governed by the spin-isospin-dependent two-nucleon interaction in the medium. This interaction gives rise to collective spin modes such as the giant Gamow-Teller resonances. An interesting phenomenon is that the measured total Gamow-Teller transition strength in the resonance region is much less than a model-independent sum rule predicts. Two physically different mechanisms have been discussed to explain this so-called quenching of the total Gamow-Teller strength: coupling to subnuclear degrees of freedom in the form of Δ-isobar excitation and ordinary nuclear configuration mixing. Both detailed nuclear structure calculations and extensive analyses of the scattering data suggest that the nuclear configuration mixing effect is the more important quenching mechanism, although subnuclear degrees of freedom cannot be ruled out. The quenching phenomenon occurs for nuclear-spin excitations at low excitation energies (ω∼10--20 MeV) and small-momentum transfers (q≤0.5 fm -1 ). A completely opposite effect is anticipated in the high (ω,q)-transfer region (0≤ω≤500 MeV, 0.5≤q≤3 fm -1 ). The nuclear spin-isospin response might be enhanced due to the attractive pion field inside the nucleus. Charge-exchange reactions at GeV incident energies have been used to study the quasifree peak region and the Δ-resonance region. An interesting result of these experiments is that the Δ excitation in the nucleus is shifted downwards in energy relative to the Δ excitation of the free proton
Iida, K; Hidoh, O; Fukami, J; Kajiwara, M
1991-01-01
Carbon-13 nuclear magnetic resonance spectroscopy has been used to observe the transformations of [1-13C]-D-glucose to [1,1'-13C2]-D-trehalose, and [3-13C]-L-alanine to [2-13C]-L-glutamic acid in the living body of Gryllodes sigillatus. [3-13C]-D-Alanine was not metabolized. The metabolic rate of [1-13C]-D-glucose was found to be altered by prior injection of boric acid.
High-spin nuclear spectroscopy
International Nuclear Information System (INIS)
Diamond, R.M.
1986-07-01
High-spin spectroscopy is the study of the changes in nuclear structure, properties, and behavior with increasing angular momentum. It involves the complex interplay between collective and single-particle motion, between shape and deformation changes, particle alignments, and changes in the pairing correlations. A review of progress in theory, experimentation, and instrumentation in this field is given
International Nuclear Information System (INIS)
Inoue, Yoshio; Hanafusa, Yoshito; Toda, Masakazu; Chujo, Riichiro
1982-01-01
The effects of retinal and vitamin A on the dynamic structure and stability of hen egg yolk lecithin bilayers have been studied by means of carbon-13 and proton NMR spectroscopies. 13 C spin-lattice relaxation and paramagnetic ion permeability studies on lecithin bilayers indicate a marked decrease in flexibility of the lipid acyl chain and a breakdown of membrane impermeableness to ion by the intercalated all-trans- and 11-cis-retinal, whereas the effect of incorporated vitamin A on the fluidity of bilayers is small and its impermeableness to ion remains effective even in the presence of higher concentration of vitamin A. The experimental results are discussed in connection with the mechanism of the permeability change in photoreceptive disk membrane. (author)
Nuclear spin noise in the central spin model
Fröhling, Nina; Anders, Frithjof B.; Glazov, Mikhail
2018-05-01
We study theoretically the fluctuations of the nuclear spins in quantum dots employing the central spin model which accounts for the hyperfine interaction of the nuclei with the electron spin. These fluctuations are calculated both with an analytical approach using homogeneous hyperfine couplings (box model) and with a numerical simulation using a distribution of hyperfine coupling constants. The approaches are in good agreement. The box model serves as a benchmark with low computational cost that explains the basic features of the nuclear spin noise well. We also demonstrate that the nuclear spin noise spectra comprise a two-peak structure centered at the nuclear Zeeman frequency in high magnetic fields with the shape of the spectrum controlled by the distribution of the hyperfine constants. This allows for direct access to this distribution function through nuclear spin noise spectroscopy.
Control of electron spin decoherence in nuclear spin baths
Liu, Ren-Bao
2011-03-01
Nuclear spin baths are a main mechanism of decoherence of spin qubits in solid-state systems, such as quantum dots and nitrogen-vacancy (NV) centers of diamond. The decoherence results from entanglement between the electron and nuclear spins, established by quantum evolution of the bath conditioned on the electron spin state. When the electron spin is flipped, the conditional bath evolution is manipulated. Such manipulation of bath through control of the electron spin not only leads to preservation of the center spin coherence but also demonstrates quantum nature of the bath. In an NV center system, the electron spin effectively interacts with hundreds of 13 C nuclear spins. Under repeated flip control (dynamical decoupling), the electron spin coherence can be preserved for a long time (> 1 ms) . Thereforesomecharacteristicoscillations , duetocouplingtoabonded 13 C nuclear spin pair (a dimer), are imprinted on the electron spin coherence profile, which are very sensitive to the position and orientation of the dimer. With such finger-print oscillations, a dimer can be uniquely identified. Thus, we propose magnetometry with single-nucleus sensitivity and atomic resolution, using NV center spin coherence to identify single molecules. Through the center spin coherence, we could also explore the many-body physics in an interacting spin bath. The information of elementary excitations and many-body correlations can be extracted from the center spin coherence under many-pulse dynamical decoupling control. Another application of the preserved spin coherence is identifying quantumness of a spin bath through the back-action of the electron spin to the bath. We show that the multiple transition of an NV center in a nuclear spin bath can have longer coherence time than the single transition does, when the classical noises due to inhomogeneous broadening is removed by spin echo. This counter-intuitive result unambiguously demonstrates the quantumness of the nuclear spin bath
QED approach to the nuclear spin-spin coupling tensor
International Nuclear Information System (INIS)
Romero, Rodolfo H.; Aucar, Gustavo A.
2002-01-01
A quantum electrodynamical approach for the calculation of the nuclear spin-spin coupling tensor of nuclear-magnetic-resonance spectroscopy is given. Quantization of radiation fields within the molecule is considered and expressions for the magnetic field in the neighborhood of a nucleus are calculated. Using a generalization of time-dependent response theory, an effective spin-spin interaction is obtained from the coupling of nuclear magnetic moments to a virtual quantized magnetic field. The energy-dependent operators obtained reduce to usual classical-field expressions at suitable limits
Nuclear spin polarization of targets
International Nuclear Information System (INIS)
Happer, W.
1990-01-01
Lasers can be used to produce milligrams to grams of noble gas nuclei with spin polarizations in excess of 50%. These quantities are sufficient to be very useful targets in nuclear physics experiments. Alkali-metal atoms are used to capture the angular momentum of circularly polarized laser photons, and the alkali-metal atoms transfer their angular momentum to noble gas atoms in binary or three-body collisions. Non-radiative collisions between the excited alkali atoms and molecular quenching gases are essential to avoid radiation trapping. The spin exchange can involve gas-phase van der Waals molecules, consisting of a noble gas atom and an alkali metal atom. Surface chemistry is also of great importance in determining the wall-induced relaxation rates of the noble gases
International Nuclear Information System (INIS)
Newman, R.H.; Theng, B.K.G.; Filip, Z.
1987-01-01
Municipal refuse was disposed of in simulated landfills and left for periods of more than 20 months. Three different 40 m 3 systems of disposals were studied, namely (i) where the refuse was compacted, (ii) where it was mixed with sewage sludge and left uncompacted, and (iii) where it was compacted with sewage sludge. At 2, 6, 12 and 20 months, the humic substances were extracted from each system, purified, and characterised by cross-polarisation 13 C NMR spectroscopy with 'magic-angle' sample spinning. The areas under the various signals were related to carbon percentages in different structural categories. The aromaticity of the humic acids increased with time of decomposition; those from refuse mixed with sewage sludge were particularly high in phenolic content. A signal at 174 p.p.m., assigned primarily to secondary amide linkages, reached maximum strength after 6 to 12 months decomposition. The carbohydrate contents of the humic acids showed only small variations as decomposition progressed. Polymethylene chains in lipids, particularly for the uncompacted system, accounted for a diminishing fraction of total carbon as time of refuse disposal increased. The spectrum of a soil humic acid showed features similar to those observed in spectra of humic acids derived from refuse, but the signals were less well resolved. 19 refs.; 8 figs.; 3 tabs
Controlling a nuclear spin in a nanodiamond
Knowles, Helena S.; Kara, Dhiren M.; Atatüre, Mete
2017-09-01
The sensing capability of a single optically bright electronic spin in diamond can be enhanced by making use of proximal dark nuclei as ancillary spins. Such systems, so far realized only in bulk diamond, can provide orders of magnitude higher sensitivity and spectral resolution in the case of magnetic sensing, as well as improved readout fidelity and state storage time in quantum information schemes. Nanodiamonds offer opportunities for scanning and embedded nanoscale probes, yet electronic-nuclear spin complexes have so far remained inaccessible. Here, we demonstrate coherent control of a 13C nuclear spin located 4 Å from a nitrogen-vacancy center in a nanodiamond and show coherent exchange between the two components of this hybrid spin system. We extract a free precession time T2* of 26 μ s for the nuclear spin, which exceeds the bare-electron free-precession time in nanodiamond by two orders of magnitude.
Electron and nuclear spin system polarization in semiconductors by light
Energy Technology Data Exchange (ETDEWEB)
Zakharchenya, B; Flejsher, V
1981-02-01
Discussed are the principles of optical electron spin orientation, dynamic polarization and cooling of nuclear spin systems in optical electron orientation, and behavioural characteristics of bound electron and nuclear spin systems of a semiconductor in the optical orientation situation.
Algorithm for the generation of nuclear spin species and nuclear spin statistical weights
International Nuclear Information System (INIS)
Balasubramanian, K.
1982-01-01
A set of algorithms for the computer generation of nuclear spin species and nuclear spin statistical weights potentially useful in molecular spectroscopy is developed. These algorithms generate the nuclear spin species from group structures known as generalized character cycle indices (GCCIs). Thus the required input for these algorithms is just the set of all GCCIs for the symmetry group of the molecule which can be computed easily from the character table. The algorithms are executed and illustrated with examples
Modulation Algorithms for Manipulating Nuclear Spin States
Liu, Boyang; Zhang, Ming; Dai, Hong-Yi
2013-01-01
We exploit the impact of exact frequency modulation on transition time of steering nuclear spin states from theoretical point of view. 1-stage and 2-stage Frequency-Amplitude-Phase modulation (FAPM) algorithms are proposed in contrast with 1-stage and 3-stage Amplitude-Phase modulation (APM) algorithms. The sufficient conditions are further present for transiting nuclear spin states within the specified time by these four modulation algorithms. It is demonstrated that transition time performa...
Optical switching of nuclear spin-spin couplings in semiconductors.
Goto, Atsushi; Ohki, Shinobu; Hashi, Kenjiro; Shimizu, Tadashi
2011-07-05
Two-qubit operation is an essential part of quantum computation. However, solid-state nuclear magnetic resonance quantum computing has not been able to fully implement this functionality, because it requires a switchable inter-qubit coupling that controls the time evolutions of entanglements. Nuclear dipolar coupling is beneficial in that it is present whenever nuclear-spin qubits are close to each other, while it complicates two-qubit operation because the qubits must remain decoupled to prevent unwanted couplings. Here we introduce optically controllable internuclear coupling in semiconductors. The coupling strength can be adjusted externally through light power and even allows on/off switching. This feature provides a simple way of switching inter-qubit couplings in semiconductor-based quantum computers. In addition, its long reach compared with nuclear dipolar couplings allows a variety of options for arranging qubits, as they need not be next to each other to secure couplings.
International Nuclear Information System (INIS)
Kaul, Ravi.
1974-01-01
After examining world-wide reactions of the foreign governments and news media to the India's peaceful nuclear experiment (PNE) in the Rajasthan Desert on 18 May 1974, development of nuclear technology in India is assessed and its economic advantages are described. Implications of the Non-Proliferation Treaty are explained. Psychological impact of India's PNE on India's neighbours and superpowers and associated political problems in context of proliferation of nuclear weapons are discussed in detail. (M.G.B.)
Experimental energy-dependent nuclear spin distributions
International Nuclear Information System (INIS)
Egidy, T. von; Bucurescu, D.
2009-01-01
A new method is proposed to determine the energy-dependent spin distribution in experimental nuclear-level schemes. This method compares various experimental and calculated moments in the energy-spin plane to obtain the spin-cutoff parameter σ as a function of mass A and excitation energy using a total of 7202 levels with spin assignment in 227 nuclei between F and Cf. A simple formula, σ 2 =0.391 A 0.675 (E-0.5Pa ' ) 0.312 , is proposed up to about 10 MeV that is in very good agreement with experimental σ values and is applied to improve the systematics of level-density parameters.
Interference elimination: nuclear spin in the cabin
International Nuclear Information System (INIS)
Anon.
1984-01-01
Constructed on Michael Faraday's cage principle, such cabins enable nuclear spin tomographs to operate undisturbed by foreign radiation. The working signals of these medical research apparatus are screened from the environment so that radio and television reception are not affected. Details are given of the structure of the cabin, of the prefabricated structural elements of non-magnetic materials (chromium-nickel steel). (Auth.)
Nuclear moment of inertia and spin distribution of nuclear levels
International Nuclear Information System (INIS)
Alhassid, Y.; Fang, L.; Liu, S.; Bertsch, G.F.
2005-01-01
We introduce a simple model to calculate the nuclear moment of inertia at finite temperature. This moment of inertia describes the spin distribution of nuclear levels in the framework of the spin-cutoff model. Our model is based on a deformed single-particle Hamiltonian with pairing interaction and takes into account fluctuations in the pairing gap. We derive a formula for the moment of inertia at finite temperature that generalizes the Belyaev formula for zero temperature. We show that a number-parity projection explains the strong odd-even effects observed in shell model Monte Carlo studies of the nuclear moment of inertia in the iron region
Nuclear superdeformation at high spins
International Nuclear Information System (INIS)
Dudek, J.
1991-01-01
The newly discovered forms of nuclear behavior at exotic shape configurations are discussed from the theoretical point of view. The main emphasis is set on superdeformed nuclei and the strange mechanisms influencing their properties. In particular the feeding properties, alignment, pairing properties and the problem of anomalous degeneracies are discussed
Core Technology Development of Nuclear spin polarization
International Nuclear Information System (INIS)
Yoo, Byung Duk; Gwon, Sung Ok; Kwon, Duck Hee; Lee, Sung Man
2009-12-01
In order to study nuclear spin polarization, we need several core technologies such as laser beam source to polarize the nuclear spin, low pressured helium cell development whose surface is essential to maintain polarization otherwise most of the polarized helium relaxed in short time, development of uniform magnetic field system which is essential for reducing relaxation, efficient vacuum system, development of polarization measuring system, and development of pressure raising system about 1000 times. The purpose of this study is to develop resonable power of laser system, that is at least 5 watt, 1083 nm, 4GHz tuneable. But the limitation of this research fund enforce to develop amplifying system into 5 watt with 1 watt system utilizing laser-diod which is already we have in stock. We succeeded in getting excellent specification of fiber laser system with power of 5 watts, 2 GHz linewidth, more than 80 GHz tuneable
Physics of high spin nuclear states
Energy Technology Data Exchange (ETDEWEB)
Wyss, R [Joint Inst. for Heavy Ion Research, Oak Ridge, TN (United States); [MSI, Frescativ, Stockholm (Sweden)
1992-08-01
High spin physics is a vast topic addressing the variety of nuclear excitation modes. In the present paper, some general aspects related to recent highlights of nuclear spectroscopy are discussed. The relation between signature splitting and shape changes in the unique parity orbitals is elucidated. The relevance of the Pseudo SU(3) symmetry in the understanding of rotational band structure is addressed. Specific features of rotational bands of intruder configurations are viewed as a probe of the neutron-proton interaction. (author). 36 refs., 5 figs.
Electron and nuclear spin system polarization in semiconductors by light
International Nuclear Information System (INIS)
Zakharchenya, B.; Flejsher, V.
1981-01-01
Discussed are the principles of optical electron spin orientation, dynamic polarization and cooling of nuclear spin systems in optical electron orientation, and behavioural characteristics of bound electron and nuclear spin systems of a semiconductor in the optical orientation situation. (J.P.)
Nuclear spin states and quantum logical operations
International Nuclear Information System (INIS)
Orlova, T.A.; Rasulov, E.N.
2006-01-01
Full text: To build a really functional quantum computer, researchers need to develop logical controllers known as 'gates' to control the state of q-bits. In this work , equal quantum logical operations are examined with the emphasis on 1-, 2-, and 3-q-bit gates.1-q-bit quantum logical operations result in Boolean 'NOT'; the 'NOT' and '√NOT' operations are described from the classical and quantum perspective. For the 'NOT' operation to be performed, there must be a means to switch the state of q-bits from to and vice versa. For this purpose either a light or radio pulse of a certain frequency can be used. If the nucleus has the spin-down state, the spin will absorb a portion of energy from electromagnetic current and switch into the spin-up state, and the radio pulse will force it to switch into state. An operation thus described from purely classical perspective is clearly understood. However, operations not analogous to the classical type may also be performed. If the above mentioned radio pulses are only half the frequency required to cause a state switch in the nuclear spin, the nuclear spin will enter the quantum superposition state of the ground state (↓) and excited states (↑). A recurring radio pulse will then result in an operation equivalent to 'NOT', for which reason the described operation is called '√NOT'. Such an operation allows for the state of quantum superposition in quantum computing, which enables parallel processing of several numbers. The work also treats the principles of 2-q-bit logical operations of the controlled 'NOT' type (CNOT), 2-q-bit (SWAP), and the 3-q-bit 'TAFFOLI' gate. (author)
Quantum dynamics of nuclear spins and spin relaxation in organic semiconductors
Mkhitaryan, V. V.; Dobrovitski, V. V.
2017-06-01
We investigate the role of the nuclear-spin quantum dynamics in hyperfine-induced spin relaxation of hopping carriers in organic semiconductors. The fast-hopping regime, when the carrier spin does not rotate much between subsequent hops, is typical for organic semiconductors possessing long spin coherence times. We consider this regime and focus on a carrier random-walk diffusion in one dimension, where the effect of the nuclear-spin dynamics is expected to be the strongest. Exact numerical simulations of spin systems with up to 25 nuclear spins are performed using the Suzuki-Trotter decomposition of the evolution operator. Larger nuclear-spin systems are modeled utilizing the spin-coherent state P -representation approach developed earlier. We find that the nuclear-spin dynamics strongly influences the carrier spin relaxation at long times. If the random walk is restricted to a small area, it leads to the quenching of carrier spin polarization at a nonzero value at long times. If the random walk is unrestricted, the carrier spin polarization acquires a long-time tail, decaying as 1 /√{t } . Based on the numerical results, we devise a simple formula describing the effect quantitatively.
Evolution of nuclear shapes at high spins
International Nuclear Information System (INIS)
Johnson, N.R.
1985-01-01
The dynamic electric quadrupole (E2) moments are a direct reflection of the collective aspects of the nuclear wave functions. For this, Doppler-shift lifetime measurements have been done utilizing primarily the recoil-distance technique. The nuclei with neutron number N approx. 90 possess many interesting properties. These nuclei have very shallow minima in their potential energy surfaces, and thus, are very susceptible to deformation driving influences. It is the evolution of nuclear shapes as a function of spin or rotational frequency for these nuclei that has commanded much interest in the lifetime measurements discussed here. There is growing evidence that many deformed nuclei which have prolate shapes in their ground states conform to triaxial or oblate shapes at higher spins. Since the E2 matrix elements along the yrast line are sensitive indicators of deformation changes, measurements of lifetimes of these states to provide the matrix elements has become the major avenue for tracing the evolving shape of a nucleus at high spin. Of the several nuclei we have studied with N approx. 90, those to be discussed here are /sup 160,161/Yb and 158 Er. In addition, the preliminary, but interesting and surprising results from our recent investigation of the N = 98 nucleus, 172 W are briefly discussed. 14 refs., 5 figs
The nuclear spin-orbit coupling
International Nuclear Information System (INIS)
Bell, J.S.; Skyrme, T.H.R.
1994-01-01
Analysis of the nucleon-nucleon scattering around 100 MeV has determined the spin-orbit coupling part of the two-body scattering matrix at that energy, and a reasonable extrapolation to lower energies is possible. This scattering amplitude has been used, in the spirit of Brueckner's nuclear model, to estimate the resultant single-body spin-orbit coupling for a single nucleon interacting with a large nucleus. This resultant potential has a radial dependence approximately proportional to r -1 d ρ /dr, and with a magnitude in good agreement with that required to explain the doublet splittings in nuclei and the polarization of nucleons scattered elastically off nuclei. (author). 14 refs, 2 figs
Nuclear spin polarized H and D by means of spin-exchange optical pumping
Stenger, Jörn; Grosshauser, Carsten; Kilian, Wolfgang; Nagengast, Wolfgang; Ranzenberger, Bernd; Rith, Klaus; Schmidt, Frank
1998-01-01
Optically pumped spin-exchange sources for polarized hydrogen and deuterium atoms have been demonstrated to yield high atomic flow and high electron spin polarization. For maximum nuclear polarization the source has to be operated in spin temperature equilibrium, which has already been demonstrated for hydrogen. In spin temperature equilibrium the nuclear spin polarization PI equals the electron spin polarization PS for hydrogen and is even larger than PS for deuterium. We discuss the general properties of spin temperature equilibrium for a sample of deuterium atoms. One result are the equations PI=4PS/(3+PS2) and Pzz=PSṡPI, where Pzz is the nuclear tensor polarization. Furthermore we demonstrate that the deuterium atoms from our source are in spin temperature equilibrium within the experimental accuracy.
Electronic Spin Storage in an Electrically Readable Nuclear Spin Memory with a Lifetime >100 Seconds
McCamey, D. R.; Van Tol, J.; Morley, G. W.; Boehme, C.
2010-12-01
Electron spins are strong candidates with which to implement spintronics because they are both mobile and able to be manipulated. The relatively short lifetimes of electron spins, however, present a problem for the long-term storage of spin information. We demonstrated an ensemble nuclear spin memory in phosphorous-doped silicon, which can be read out electrically and has a lifetime exceeding 100 seconds. The electronic spin information can be mapped onto and stored in the nuclear spin of the phosphorus donors, and the nuclear spins can then be repetitively read out electrically for time periods that exceed the electron spin lifetime. We discuss how this memory can be used in conjunction with other silicon spintronic devices.
International Conference on Spin Observables of Nuclear Probes
Goodman, Charles; Walker, George; Spin Observables of Nuclear Probes
1988-01-01
The proceedings of the "International Conference on Spin Observables of Nuclear Probes" are presented in this volume. This conference was held in Telluride, Colorado, March 14 -17, 1988, and was the fourth in the Telluride series of nuclear physics conferences. A continuing theme in the Telluride conference series has been the complementarity of various intermediate-energy projectiles for elucidating the nucleon-nucleon interaction and nuclear structure. Earlier conferences have contributed significantly to an understanding of spin currents in nuclei, in particular the distribution of Gamow-Teller strength using charge-exchange reactions. The previous conference on "Antinucleon and Nucleon Nucleus Interactions" compared nuclear information from tra tional probes to recent results from antinucleon reactions. The 1988 conference on Spin Observables of Nuclear Probes, put special emphasis on spin observables and brought together experts using spin information to probe nuclear structure. Spin observabl...
High-resolution proton and carbon-13 NMR of membranes: why sonicate?
International Nuclear Information System (INIS)
Oldfield, E.; Bowers, J.L.; Forbes, J.
1987-01-01
The authors have obtained high-field (11.7-T) proton and carbon-13 Fourier transform (FT) nuclear magnetic resonance (NMR) spectra of egg lecithin and egg lecithin-chloresterol (1:1) multibilayers, using magic-angle sample spinning (MASS) techniques, and sonicated egg lecithin and egg lecithin-cholesterol (1:1) vesicles, using conventional FT NMR methods. Resolution of the proton and carbon-13 MASS NMR spectra of the pure egg lecithin samples is essentially identical with that of sonicated samples, but spectra of the unsonicated lipid, using MASS, can be obtained very much faster than with the more dilute, sonicated systems. With the 1:1 lecithin-cholesterol system, proton MASS NMR spectra are virtually identical with conventional FT spectra of sonicated samples, while the 13 C NMR, the authors demonstrate that most 13 C nuclei in the cholesterol moiety can be monitored, even though these same nuclei are essentially invisible, i.e., are severely broadened, in the corresponding sonicated systems. In addition, 13 C MASS NMR spectra can again be recorded much faster than with sonicated samples, due to concentration effects. Taken together, these results strongly suggest there will seldom be need in the future to resort to ultransonic disruption of lipid bilayer membranes in order to obtain high-resolution proton or carbon-13 NMR spectra
Robust techniques for polarization and detection of nuclear spin ensembles
Scheuer, Jochen; Schwartz, Ilai; Müller, Samuel; Chen, Qiong; Dhand, Ish; Plenio, Martin B.; Naydenov, Boris; Jelezko, Fedor
2017-11-01
Highly sensitive nuclear spin detection is crucial in many scientific areas including nuclear magnetic resonance spectroscopy, magnetic resonance imaging (MRI), and quantum computing. The tiny thermal nuclear spin polarization represents a major obstacle towards this goal which may be overcome by dynamic nuclear spin polarization (DNP) methods. The latter often rely on the transfer of the thermally polarized electron spins to nearby nuclear spins, which is limited by the Boltzmann distribution of the former. Here we utilize microwave dressed states to transfer the high (>92 % ) nonequilibrium electron spin polarization of a single nitrogen-vacancy center (NV) induced by short laser pulses to the surrounding 13C carbon nuclear spins. The NV is repeatedly repolarized optically, thus providing an effectively infinite polarization reservoir. A saturation of the polarization of the nearby nuclear spins is achieved, which is confirmed by the decay of the polarization transfer signal and shows an excellent agreement with theoretical simulations. Hereby we introduce the polarization readout by polarization inversion method as a quantitative magnetization measure of the nuclear spin bath, which allows us to observe by ensemble averaging macroscopically hidden polarization dynamics like Landau-Zener-Stückelberg oscillations. Moreover, we show that using the integrated solid effect both for single- and double-quantum transitions nuclear spin polarization can be achieved even when the static magnetic field is not aligned along the NV's crystal axis. This opens a path for the application of our DNP technique to spins in and outside of nanodiamonds, enabling their application as MRI tracers. Furthermore, the methods reported here can be applied to other solid state systems where a central electron spin is coupled to a nuclear spin bath, e.g., phosphor donors in silicon and color centers in silicon carbide.
Inelastic electron tunneling spectroscopy of a single nuclear spin.
Delgado, F; Fernández-Rossier, J
2011-08-12
Detection of a single nuclear spin constitutes an outstanding problem in different fields of physics such as quantum computing or magnetic imaging. Here we show that the energy levels of a single nuclear spin can be measured by means of inelastic electron tunneling spectroscopy (IETS). We consider two different systems, a magnetic adatom probed with scanning tunneling microscopy and a single Bi dopant in a silicon nanotransistor. We find that the hyperfine coupling opens new transport channels which can be resolved at experimentally accessible temperatures. Our simulations evince that IETS yields information about the occupations of the nuclear spin states, paving the way towards transport-detected single nuclear spin resonance.
Nuclear Spin Nanomagnet in an Optically Excited Quantum Dot
Korenev, V. L.
2007-12-01
Linearly polarized light tuned slightly below the optical transition of the negatively charged exciton (trion) in a single quantum dot causes the spontaneous nuclear spin polarization (self-polarization) at a level close to 100%. The effective magnetic field of spin-polarized nuclei shifts the optical transition energy close to resonance with photon energy. The resonantly enhanced Overhauser effect sustains the stability of the nuclear self-polarization even in the absence of spin polarization of the quantum dot electron. As a result the optically selected single quantum dot represents a tiny magnet with the ferromagnetic ordering of nuclear spins—the nuclear spin nanomagnet.
Exploring Localization in Nuclear Spin Chains
Wei, Ken Xuan; Ramanathan, Chandrasekhar; Cappellaro, Paola
2018-02-01
Characterizing out-of-equilibrium many-body dynamics is a complex but crucial task for quantum applications and understanding fundamental phenomena. A central question is the role of localization in quenching thermalization in many-body systems and whether such localization survives in the presence of interactions. Probing this question in real systems necessitates the development of an experimentally measurable metric that can distinguish between different types of localization. While it is known that the localized phase of interacting systems [many-body localization (MBL)] exhibits a long-time logarithmic growth in entanglement entropy that distinguishes it from the noninteracting case of Anderson localization (AL), entanglement entropy is difficult to measure experimentally. Here, we present a novel correlation metric, capable of distinguishing MBL from AL in high-temperature spin systems. We demonstrate the use of this metric to detect localization in a natural solid-state spin system using nuclear magnetic resonance (NMR). We engineer the natural Hamiltonian to controllably introduce disorder and interactions, and observe the emergence of localization. In particular, while our correlation metric saturates for AL, it slowly keeps increasing for MBL, demonstrating analogous features to entanglement entropy, as we show in simulations. Our results show that our NMR techniques, akin to measuring out-of-time correlations, are well suited for studying localization in spin systems.
Spin squeezing of atomic ensembles via nuclear-electronic spin entanglement
DEFF Research Database (Denmark)
Fernholz, Thomas; Krauter, Hanna; Jensen, Kasper
2008-01-01
quantum limit for quantum memory experiments and applications in quantum metrology and is thus a complementary alternative to spin squeezing obtained via inter-atom entanglement. Squeezing of the collective spin is verified by quantum state tomography.......We demonstrate spin squeezing in a room temperature ensemble of 1012 Cesium atoms using their internal structure, where the necessary entanglement is created between nuclear and electronic spins of each individual atom. This state provides improvement in measurement sensitivity beyond the standard...
Repetitive readout of a single electronic spin via quantum logic with nuclear spin ancillae.
Jiang, L; Hodges, J S; Maze, J R; Maurer, P; Taylor, J M; Cory, D G; Hemmer, P R; Walsworth, R L; Yacoby, A; Zibrov, A S; Lukin, M D
2009-10-09
Robust measurement of single quantum bits plays a key role in the realization of quantum computation and communication as well as in quantum metrology and sensing. We have implemented a method for the improved readout of single electronic spin qubits in solid-state systems. The method makes use of quantum logic operations on a system consisting of a single electronic spin and several proximal nuclear spin ancillae in order to repetitively readout the state of the electronic spin. Using coherent manipulation of a single nitrogen vacancy center in room-temperature diamond, full quantum control of an electronic-nuclear system consisting of up to three spins was achieved. We took advantage of a single nuclear-spin memory in order to obtain a 10-fold enhancement in the signal amplitude of the electronic spin readout. We also present a two-level, concatenated procedure to improve the readout by use of a pair of nuclear spin ancillae, an important step toward the realization of robust quantum information processors using electronic- and nuclear-spin qubits. Our technique can be used to improve the sensitivity and speed of spin-based nanoscale diamond magnetometers.
Thermodynamics of Rh nuclear spins calculated by exact diagonalization
DEFF Research Database (Denmark)
Lefmann, K.; Ipsen, J.; Rasmussen, F.B.
2000-01-01
We have employed the method of exact diagonalization to obtain the full-energy spectrum of a cluster of 16 Rh nuclear spins, having dipolar and RK interactions between first and second nearest neighbours only. We have used this to calculate the nuclear spin entropy, and our results at both positi...
On the spin saturation and thermal properties of nuclear matter
International Nuclear Information System (INIS)
Hassan, M.Y.M.; Ramadan, S.
1983-12-01
The binding energy and the incompressibility of nuclear matter with degree of spin saturation D is calculated using the Skyrme interaction and two forms of a velocity dependent effective potential. The effect of the degree of spin saturation D on the thermal properties of nuclear matter is also discussed. It is found that generally the pressure decreases with increasing D. (author)
Spin Modes in Nuclei and Nuclear Forces
International Nuclear Information System (INIS)
Suzuki, Toshio; Otsuka, Takaharu
2011-01-01
Spin modes in stable and unstable exotic nuclei are studied and important roles of tensor and three-body forces on nuclear structure are discussed. New shell model Hamiltonians, which have proper tensor components, are shown to explain shell evolutions toward drip-lines and spin properties of both stable and exotic nuclei, for example, Gamow-Teller transitions in 12 C and 14 C and an anomalous M1 transition in 17 C. The importance and the necessity of the repulsive monopole corrections in isospin T = 1 channel to the microscopic two-body interactions are pointed out. The corrections are shown to lead to the proper shell evolutions in neutron-rich isotopes. The three-body force, in particular the Fujita-Miyazawa force induced by Δ excitations, is pointed out to be responsible for the repulsive corrections among the valence neutrons. The important roles of the three-body force on the energies and transitions in exotic oxygen and calcium isotopes are demonstrated.
Optically induced dynamic nuclear spin polarisation in diamond
International Nuclear Information System (INIS)
Scheuer, Jochen; Naydenov, Boris; Jelezko, Fedor; Schwartz, Ilai; Chen, Qiong; Plenio, Martin B; Schulze-Sünninghausen, David; Luy, Burkhard; Carl, Patrick; Höfer, Peter; Retzker, Alexander; Sumiya, Hitoshi; Isoya, Junichi
2016-01-01
The sensitivity of magnetic resonance imaging (MRI) depends strongly on nuclear spin polarisation and, motivated by this observation, dynamical nuclear spin polarisation has recently been applied to enhance MRI protocols (Kurhanewicz et al 2011 Neoplasia 13 81). Nuclear spins associated with the 13 C carbon isotope (nuclear spin I = 1/2) in diamond possess uniquely long spin lattice relaxation times (Reynhardt and High 2011 Prog. Nucl. Magn. Reson. Spectrosc. 38 37). If they are present in diamond nanocrystals, especially when strongly polarised, they form a promising contrast agent for MRI. Current schemes for achieving nuclear polarisation, however, require cryogenic temperatures. Here we demonstrate an efficient scheme that realises optically induced 13 C nuclear spin hyperpolarisation in diamond at room temperature and low ambient magnetic field. Optical pumping of a nitrogen-vacancy centre creates a continuously renewable electron spin polarisation which can be transferred to surrounding 13 C nuclear spins. Importantly for future applications we also realise polarisation protocols that are robust against an unknown misalignment between magnetic field and crystal axis. (paper)
Nuclear spin-lattice relaxation in nitroxide spin-label EPR
DEFF Research Database (Denmark)
Marsh, Derek
2016-01-01
that the definition of nitrogen nuclear relaxation rate Wn commonly used in the CW-EPR literature for 14N-nitroxyl spin labels is inconsistent with that currently adopted in time-resolved EPR measurements of saturation recovery. Redefinition of the normalised 14N spin-lattice relaxation rate, b = Wn/(2We), preserves...... of spin-lattice relaxation in this three-level system. Expressions for CW-saturation EPR with the revised definitions are summarised. Data on nitrogen nuclear spin-lattice relaxation times are compiled according to the three-level scheme for 14N-relaxation: T1 n = 1/Wn. Results are compared and contrasted...
Stimulated nuclear spin echos and spectral diffusion in glasses
International Nuclear Information System (INIS)
Borges, N.M.; Engelsberg, M.
1984-01-01
Experimental results of stimulated nuclear spin echos decay in glasses are presented. The measurements were performed in B 2 O 3 glasses, at the 23Na and 11 B resonance lines. The data analysis allows the study of Spectral diffusion at an inhomogeneous nuclear magnetic (NMR) resonance line, broadened for a desordered system of nuclear spins. A model is proposed to explain the time constants, and the particular form of the decay. (A.C.A.S.) [pt
Statistical methods of spin assignment in compound nuclear reactions
International Nuclear Information System (INIS)
Mach, H.; Johns, M.W.
1984-01-01
Spin assignment to nuclear levels can be obtained from standard in-beam gamma-ray spectroscopy techniques and in the case of compound nuclear reactions can be complemented by statistical methods. These are based on a correlation pattern between level spin and gamma-ray intensities feeding low-lying levels. Three types of intensity and level spin correlations are found suitable for spin assignment: shapes of the excitation functions, ratio of intensity at two beam energies or populated in two different reactions, and feeding distributions. Various empirical attempts are examined and the range of applicability of these methods as well as the limitations associated with them are given. 12 references
Statistical methods of spin assignment in compound nuclear reactions
International Nuclear Information System (INIS)
Mach, H.; Johns, M.W.
1985-01-01
Spin assignment to nuclear levels can be obtained from standard in-beam gamma-ray spectroscopy techniques and in the case of compound nuclear reactions can be complemented by statistical methods. These are based on a correlation pattern between level spin and gamma-ray intensities feeding low-lying levels. Three types of intensity and level spin correlations are found suitable for spin assignment: shapes of the excitation functions, ratio of intensity at two beam energies or populated in two different reactions, and feeding distributions. Various empirical attempts are examined and the range of applicability of these methods as well as the limitations associated with them are given
The electron-spin--nuclear-spin interaction studied by polarized neutron scattering.
Stuhrmann, Heinrich B
2007-11-01
Dynamic nuclear spin polarization (DNP) is mediated by the dipolar interaction of paramagnetic centres with nuclear spins. This process is most likely to occur near paramagnetic centres at an angle close to 45 degrees with respect to the direction of the external magnetic field. The resulting distribution of polarized nuclear spins leads to an anisotropy of the polarized neutron scattering pattern, even with randomly oriented radical molecules. The corresponding cross section of polarized coherent neutron scattering in terms of a multipole expansion is derived for radical molecules in solution. An application using data of time-resolved polarized neutron scattering from an organic chromium(V) molecule is tested.
An endohedral fullerene-based nuclear spin quantum computer
International Nuclear Information System (INIS)
Ju Chenyong; Suter, Dieter; Du Jiangfeng
2011-01-01
We propose a new scalable quantum computer architecture based on endohedral fullerene molecules. Qubits are encoded in the nuclear spins of the endohedral atoms, which posses even longer coherence times than the electron spins which are used as the qubits in previous proposals. To address the individual qubits, we use the hyperfine interaction, which distinguishes two modes (active and passive) of the nuclear spin. Two-qubit quantum gates are effectively implemented by employing the electronic dipolar interaction between adjacent molecules. The electron spins also assist in the qubit initialization and readout. Our architecture should be significantly easier to implement than earlier proposals for spin-based quantum computers, such as the concept of Kane [B.E. Kane, Nature 393 (1998) 133]. - Research highlights: → We propose an endohedral fullerene-based scalable quantum computer architecture. → Qubits are encoded on nuclear spins, while electron spins serve as auxiliaries. → Nuclear spins are individually addressed using the hyperfine interaction. → Two-qubit gates are implemented through the medium of electron spins.
Nuclear spin cooling by electric dipole spin resonance and coherent population trapping
Li, Ai-Xian; Duan, Su-Qing; Zhang, Wei
2017-09-01
Nuclear spin fluctuation suppression is a key issue in preserving electron coherence for quantum information/computation. We propose an efficient way of nuclear spin cooling in semiconductor quantum dots (QDs) by the coherent population trapping (CPT) and the electric dipole spin resonance (EDSR) induced by optical fields and ac electric fields. The EDSR can enhance the spin flip-flop rate and may bring out bistability under certain conditions. By tuning the optical fields, we can avoid the EDSR induced bistability and obtain highly polarized nuclear spin state, which results in long electron coherence time. With the help of CPT and EDSR, an enhancement of 1500 times of the electron coherence time can been obtained after a 500 ns preparation time.
Spin polarized states in strongly asymmetric nuclear matter
International Nuclear Information System (INIS)
Isayev, A.A.; Yang, J.
2004-01-01
The possibility of appearance of spin polarized states in strongly asymmetric nuclear matter is analyzed within the framework of a Fermi liquid theory with the Skyrme effective interaction. The zero temperature dependence of the neutron and proton spin polarization parameters as functions of density is found for SLy4 and SLy5 effective forces. It is shown that at some critical density strongly asymmetric nuclear matter undergoes a phase transition to the state with the oppositely directed spins of neutrons and protons while the state with the same direction of spins does not appear. In comparison with neutron matter, even small admixture of protons strongly decreases the threshold density of spin instability. It is clarified that protons become totally polarized within a very narrow density domain while the density profile of the neutron spin polarization parameter is characterized by the appearance of long tails near the transition density
Nuclear spin-lattice relaxation in carbon nanostructures
Energy Technology Data Exchange (ETDEWEB)
Panich, A.M., E-mail: pan@bgu.ac.i [Department of Physics, Ben-Gurion University of the Negev, P.O. Box 653, Beer Sheva 84105 (Israel); Sergeev, N.A. [Institute of Physics, University of Szczecin, 70-451 Szczecin (Poland)
2010-04-15
Interpretation of nuclear spin-lattice relaxation data in the carbon nanostructures is usually based on the analysis of fluctuations of dipole-dipole interactions of nuclear spins and anisotropic electron-nuclear interactions responsible for chemical shielding, which are caused by molecular dynamics. However, many nanocarbon systems such as fullerene and nanotube derivatives, nanodiamonds and carbon onions reveal noticeable amount of paramagnetic defects with unpaired electrons originating from dangling bonds. The interaction between nuclear and electron spins strongly influences the nuclear spin-lattice relaxation, but usually is not taken into account, thus the relaxation data are not correctly interpreted. Here we report on the temperature dependent NMR spectra and spin-lattice relaxation measurements of intercalated fullerenes C{sub 60}(MF{sub 6}){sub 2} (M=As and Sb), where nuclear relaxation is caused by both molecular rotation and interaction between nuclei and unpaired electron spins. We present a detailed theoretical analysis of the spin-lattice relaxation data taking into account both these contributions. Good agreement between the experimental data and calculations is obtained. The developed approach would be useful in interpreting the NMR relaxation data in different nanostructures and their intercalation compounds.
Nuclear spin content and constraints on exotic spin-dependent couplings
International Nuclear Information System (INIS)
Kimball, D F Jackson
2015-01-01
There are numerous recent and ongoing experiments employing a variety of atomic species to search for couplings of atomic spins to exotic fields. In order to meaningfully compare these experimental results, the coupling of the exotic field to the atomic spin must be interpreted in terms of the coupling to electron, proton, and neutron spins. Traditionally, constraints from atomic experiments on exotic couplings to neutron and proton spins have been derived using the single-particle Schmidt model for nuclear spin. In this model, particular atomic species are sensitive to either neutron or proton spin couplings, but not both. More recently, semi-empirical models employing nuclear magnetic moment data have been used to derive new constraints for non-valence nucleons. However, comparison of such semi-empirical models to detailed large-scale nuclear shell model calculations and analysis of known physical effects in nuclei show that existing semi-empirical models cannot reliably be used to predict the spin polarization of non-valence nucleons. The results of our re-analysis of nuclear spin content are applied to searches for exotic long-range monopole–dipole and dipole–dipole couplings of nuclei leading to significant revisions of some published constraints. (paper)
Electronic readout of a single nuclear spin using a molecular spin transistor
Vincent, R.; Klyastskaya, S.; Ruben, M.; Wernsdorfer, W.; Balestro, F.
2012-02-01
Quantum control of individual spins in condensed matter devices is an emerging field with a wide range of applications ranging from nanospintronics to quantum computing [1,2]. The electron, with its spin and orbital degrees of freedom, is conventionally used as carrier of the quantum information in the devices proposed so far. However, electrons exhibit a strong coupling to the environment leading to reduced relaxation and coherence times. Indeed quantum coherence and stable entanglement of electron spins are extremely difficult to achieve. We propose a new approach using the nuclear spin of an individual metal atom embedded in a single-molecule magnet (SMM). In order to perform the readout of the nuclear spin, the quantum tunneling of the magnetization (QTM) of the magnetic moment of the SMM in a transitor-like set-up is electronically detected. Long spin lifetimes of an individual nuclear spin were observed and the relaxation characteristics were studied. The manipulation of the nuclear spin state of individual atoms embedded in magnetic molecules opens a completely new world, where quantum logic may be integrated.[4pt] [1] L. Bogani, W. Wernsdorfer, Nature Mat. 7, 179 (2008).[0pt] [2] M. Urdampilleta, S. Klyatskaya, J.P. Cleuziou, M. Ruben, W. Wernsdorfer, Nature Mat. 10, 502 (2011).
Evolution of nuclear collectivity at high spins and temperatures
International Nuclear Information System (INIS)
Baktash, C.
1989-01-01
In the past few years, we have utilized the Spin Spectrometer and a variety of complementary probes (continuum γrays, proton-γ coincidence spectroscopy and γ decay of GDR) to study the nuclear response to the DIFFERENTIAL effects of increasing spin and temperature for constant values of excitation energy or spin, respectively. In this paper we shall describe two of the experiments that trace the properties of rapidly-rotating nuclei at small to moderate excitation energies. 22 refs., 7 figs
Polarization of nuclear spins by a cold nanoscale resonator
International Nuclear Information System (INIS)
Butler, Mark C.; Weitekamp, Daniel P.
2011-01-01
A cold nanoscale resonator coupled to a system of nuclear spins can induce spin relaxation. In the low-temperature limit where spin-lattice interactions are ''frozen out,'' spontaneous emission by nuclear spins into a resonant mechanical mode can become the dominant mechanism for cooling the spins to thermal equilibrium with their environment. We provide a theoretical framework for the study of resonator-induced cooling of nuclear spins in this low-temperature regime. Relaxation equations are derived from first principles, in the limit where energy donated by the spins to the resonator is quickly dissipated into the cold bath that damps it. A physical interpretation of the processes contributing to spin polarization is given. For a system of spins that have identical couplings to the resonator, the interaction Hamiltonian conserves spin angular momentum, and the resonator cannot relax the spins to thermal equilibrium unless this symmetry is broken by the spin Hamiltonian. The mechanism by which such a spin system becomes ''trapped'' away from thermal equilibrium can be visualized using a semiclassical model, which shows how an indirect spin-spin interaction arises from the coupling of multiple spins to one resonator. The internal spin Hamiltonian can affect the polarization process in two ways: (1) By modifying the structure of the spin-spin correlations in the energy eigenstates, and (2) by splitting the degeneracy within a manifold of energy eigenstates, so that zero-frequency off-diagonal terms in the density matrix are converted to oscillating coherences. Shifting the frequencies of these coherences sufficiently far from zero suppresses the development of resonator-induced correlations within the manifold during polarization from a totally disordered state. Modification of the spin-spin correlations by means of either mechanism affects the strength of the fluctuating spin dipole that drives the resonator. In the case where product states can be chosen as energy
Synthesis of carbon-13 labeled ibuprofen
International Nuclear Information System (INIS)
Hsi, R.S.P.; Stelzer, L.S.; Stolle, W.T.
1989-01-01
This report describes the synthesis of 2-[4-(2-methyl)propyl-phenyl]propionic acid (ibuprofen) labeled with carbon-13 either at the terminal methyl carbons, or at the methine carbon of the isobutyl side chain. The synthetic route involves the removal of the isopropyl group in the isobutyl side-chain of ibuprofen via 2-[4-(2-methyl-1-propenyl)phenyl]propionic acid, followed by restoration of the isopropyl group with a Wittig reaction, using appropriate carbon-13 labeled acetone as the precursor of the isopropyl group. Interesting NMR coupling data attributable to phosphorous and carbon-13 are presented in the experimental section. (author)
Quantum computation with nuclear spins in quantum dots
Energy Technology Data Exchange (ETDEWEB)
Christ, H.
2008-01-24
The role of nuclear spins for quantum information processing in quantum dots is theoretically investigated in this thesis. Building on the established fact that the most strongly coupled environment for the potential electron spin quantum bit are the surrounding lattice nuclear spins interacting via the hyperfine interaction, we turn this vice into a virtue by designing schemes for harnessing this strong coupling. In this perspective, the ensemble of nuclear spins can be considered an asset, suitable for an active role in quantum information processing due to its intrinsic long coherence times. We present experimentally feasible protocols for the polarization, i.e. initialization, of the nuclear spins and a quantitative solution to our derived master equation. The polarization limiting destructive interference effects, caused by the collective nature of the nuclear coupling to the electron spin, are studied in detail. Efficient ways of mitigating these constraints are presented, demonstrating that highly polarized nuclear ensembles in quantum dots are feasible. At high, but not perfect, polarization of the nuclei the evolution of an electron spin in contact with the spin bath can be efficiently studied by means of a truncation of the Hilbert space. It is shown that the electron spin can function as a mediator of universal quantum gates for collective nuclear spin qubits, yielding a promising architecture for quantum information processing. Furthermore, we show that at high polarization the hyperfine interaction of electron and nuclear spins resembles the celebrated Jaynes-Cummings model of quantum optics. This result opens the door for transfer of knowledge from the mature field of quantum computation with atoms and photons. Additionally, tailored specifically for the quantum dot environment, we propose a novel scheme for the generation of highly squeezed collective nuclear states. Finally we demonstrate that even an unprepared completely mixed nuclear spin
Quantum computation with nuclear spins in quantum dots
International Nuclear Information System (INIS)
Christ, H.
2008-01-01
The role of nuclear spins for quantum information processing in quantum dots is theoretically investigated in this thesis. Building on the established fact that the most strongly coupled environment for the potential electron spin quantum bit are the surrounding lattice nuclear spins interacting via the hyperfine interaction, we turn this vice into a virtue by designing schemes for harnessing this strong coupling. In this perspective, the ensemble of nuclear spins can be considered an asset, suitable for an active role in quantum information processing due to its intrinsic long coherence times. We present experimentally feasible protocols for the polarization, i.e. initialization, of the nuclear spins and a quantitative solution to our derived master equation. The polarization limiting destructive interference effects, caused by the collective nature of the nuclear coupling to the electron spin, are studied in detail. Efficient ways of mitigating these constraints are presented, demonstrating that highly polarized nuclear ensembles in quantum dots are feasible. At high, but not perfect, polarization of the nuclei the evolution of an electron spin in contact with the spin bath can be efficiently studied by means of a truncation of the Hilbert space. It is shown that the electron spin can function as a mediator of universal quantum gates for collective nuclear spin qubits, yielding a promising architecture for quantum information processing. Furthermore, we show that at high polarization the hyperfine interaction of electron and nuclear spins resembles the celebrated Jaynes-Cummings model of quantum optics. This result opens the door for transfer of knowledge from the mature field of quantum computation with atoms and photons. Additionally, tailored specifically for the quantum dot environment, we propose a novel scheme for the generation of highly squeezed collective nuclear states. Finally we demonstrate that even an unprepared completely mixed nuclear spin
Distinction of nuclear spin states with the scanning tunneling microscope.
Natterer, Fabian Donat; Patthey, François; Brune, Harald
2013-10-25
We demonstrate rotational excitation spectroscopy with the scanning tunneling microscope for physisorbed H(2) and its isotopes HD and D(2). The observed excitation energies are very close to the gas phase values and show the expected scaling with the moment of inertia. Since these energies are characteristic for the molecular nuclear spin states we are able to identify the para and ortho species of hydrogen and deuterium, respectively. We thereby demonstrate nuclear spin sensitivity with unprecedented spatial resolution.
Nuclear spin-lattice relaxation in nitroxide spin-label EPR.
Marsh, Derek
2016-11-01
Nuclear relaxation is a sensitive monitor of rotational dynamics in spin-label EPR. It also contributes competing saturation transfer pathways in T 1 -exchange spectroscopy, and the determination of paramagnetic relaxation enhancement in site-directed spin labelling. A survey shows that the definition of nitrogen nuclear relaxation rate W n commonly used in the CW-EPR literature for 14 N-nitroxyl spin labels is inconsistent with that currently adopted in time-resolved EPR measurements of saturation recovery. Redefinition of the normalised 14 N spin-lattice relaxation rate, b=W n /(2W e ), preserves the expressions used for CW-EPR, whilst rendering them consistent with expressions for saturation recovery rates in pulsed EPR. Furthermore, values routinely quoted for nuclear relaxation times that are deduced from EPR spectral diffusion rates in 14 N-nitroxyl spin labels do not accord with conventional analysis of spin-lattice relaxation in this three-level system. Expressions for CW-saturation EPR with the revised definitions are summarised. Data on nitrogen nuclear spin-lattice relaxation times are compiled according to the three-level scheme for 14 N-relaxation: T 1 n =1/W n . Results are compared and contrasted with those for the two-level 15 N-nitroxide system. Copyright © 2016 Elsevier Inc. All rights reserved.
Calculation of nuclear spin-spin coupling constants using frozen density embedding
Energy Technology Data Exchange (ETDEWEB)
Götz, Andreas W., E-mail: agoetz@sdsc.edu [San Diego Supercomputer Center, University of California San Diego, 9500 Gilman Dr MC 0505, La Jolla, California 92093-0505 (United States); Autschbach, Jochen [Department of Chemistry, University at Buffalo, State University of New York, Buffalo, New York 14260-3000 (United States); Visscher, Lucas, E-mail: visscher@chem.vu.nl [Amsterdam Center for Multiscale Modeling (ACMM), VU University Amsterdam, Theoretical Chemistry, De Boelelaan 1083, 1081 HV Amsterdam (Netherlands)
2014-03-14
We present a method for a subsystem-based calculation of indirect nuclear spin-spin coupling tensors within the framework of current-spin-density-functional theory. Our approach is based on the frozen-density embedding scheme within density-functional theory and extends a previously reported subsystem-based approach for the calculation of nuclear magnetic resonance shielding tensors to magnetic fields which couple not only to orbital but also spin degrees of freedom. This leads to a formulation in which the electron density, the induced paramagnetic current, and the induced spin-magnetization density are calculated separately for the individual subsystems. This is particularly useful for the inclusion of environmental effects in the calculation of nuclear spin-spin coupling constants. Neglecting the induced paramagnetic current and spin-magnetization density in the environment due to the magnetic moments of the coupled nuclei leads to a very efficient method in which the computationally expensive response calculation has to be performed only for the subsystem of interest. We show that this approach leads to very good results for the calculation of solvent-induced shifts of nuclear spin-spin coupling constants in hydrogen-bonded systems. Also for systems with stronger interactions, frozen-density embedding performs remarkably well, given the approximate nature of currently available functionals for the non-additive kinetic energy. As an example we show results for methylmercury halides which exhibit an exceptionally large shift of the one-bond coupling constants between {sup 199}Hg and {sup 13}C upon coordination of dimethylsulfoxide solvent molecules.
Dzhioev, R. I.; Korenev, V. L.
2007-07-01
The nuclear quadrupole interaction eliminates the restrictions imposed by hyperfine interaction on the spin coherence of an electron and nuclei in a quantum dot. The strain-induced nuclear quadrupole interaction suppresses the nuclear spin flip and makes possible the zero-field dynamic nuclear polarization in self-organized InP/InGaP quantum dots. The direction of the effective nuclear magnetic field is fixed in space, thus quenching the magnetic depolarization of the electron spin in the quantum dot. The quadrupole interaction suppresses the zero-field electron spin decoherence also for the case of nonpolarized nuclei. These results provide a new vision of the role of the nuclear quadrupole interaction in nanostructures: it elongates the spin memory of the electron-nuclear system.
Spin-off technologies developed through nuclear activities
International Nuclear Information System (INIS)
1993-01-01
Given the changing role of government research establishments and the interest in maximizing return on capital and intellectual investment, determining the best way to apply or ''spin-off'' technologies from the nuclear field into other industrial and commercial sectors is of increasing concern. This study by the OECD Nuclear Energy Agency draws on expertise from numerous countries to determine what the spin-offs are, where they come from, and how they can best be fostered. It looks both at the results and process of spin-offs, and helps decision-makers in government and project leaders and managers in industry to maximize their benefits. (author)
Relaxation of nuclear spin on holes in semiconductors
International Nuclear Information System (INIS)
Gr'ncharova, E.I.; Perel', V.I.
1977-01-01
The longitudienal relaxation time T 1 of nuclear spins due to dipole-dipole interaction with holes in semiconductors is calculated. Expressions for T 1 in cubic and uniaxial semiconductors are obtained for non-degenerate and degenerate cases. On the basis of comparison with available experimental data for silicon the agreement with the theoretical results is obtained. It is demonstrated that in uniaxial semiconductors the time of relaxation on holes for a nuclear spin directed along the c axis is considerably greater than that for a spin in the normal direction
Study by magnetic resonance and relaxation of carbon 13 of some paramagnetic coordination complexes
International Nuclear Information System (INIS)
Ronfard-Haret, Jean-Claude
1977-01-01
This research thesis reports the study of coordination complexes by using NMR. After a brief recall of the theoretical background required for the processing of experimental data (hyper-fine coupling and magnetic resonance, spin density distribution, chemical displacement, dipolar, scalar and electronic relaxation), the author describes the conditions in which experiments have been performed and presents measurement methods (pulsed nuclear magnetic resonance, relaxation time measurement, determination of hyper-fine coupling constants, spectrometers and reactants). The next chapters address the study of different coordination complexes: [(pyridine-N-oxide) 2 Ni(acetylacetonate) 2 ], carbon 13 in alkyl-anilines-Ni II, complexation of 1- and 2-aminonaphthalene by transition ions, complexation of pyridine-N-oxide by the nickel Ni ++ ion in presence of water
Nuclear data for the high-spin community
Energy Technology Data Exchange (ETDEWEB)
Firestone, R B [Lawrence Berkeley Lab., CA (United States); Singh, B [McMaster Univ., Hamilton, ON (Canada). Tandem Accelerator Lab.
1992-08-01
The Isotopes Project at Berkeley is developing the Evaluated High-Spin Data File, a subset of the Evaluated Nuclear Structure Data File (ENSDF). The following products were under development at the time of the conference: eighth edition of the Table of Isotopes, electronic table of isotopes, data bases, nuclear charts, nuclear wallet cards, nuclear CD-ROM, FAX data services, on-line data services.
Energy Technology Data Exchange (ETDEWEB)
Amaha, S., E-mail: s-amaha@riken.jp [Quantum Spin Information Project, Japan Science and Technology Agency, ICORP, 3-1, Morinosato Wakamiya, Atsugi-shi, Kanagawa 243-0198 (Japan); Quantum Functional System Research Group, RIKEN Center for Emergent Matter Science, RIKEN, 3-1 Wako-shi, Saitama 351-0198 (Japan); Hatano, T. [Quantum Spin Information Project, Japan Science and Technology Agency, ICORP, 3-1, Morinosato Wakamiya, Atsugi-shi, Kanagawa 243-0198 (Japan); Department of Physics, Tohoku University, Sendai-shi, Miyagi 980-8578 (Japan); Tarucha, S. [Quantum Spin Information Project, Japan Science and Technology Agency, ICORP, 3-1, Morinosato Wakamiya, Atsugi-shi, Kanagawa 243-0198 (Japan); Quantum Functional System Research Group, RIKEN Center for Emergent Matter Science, RIKEN, 3-1 Wako-shi, Saitama 351-0198 (Japan); Department of Applied Physics, School of Engineering, University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Gupta, J. A.; Austing, D. G. [National Research Council of Canada, M50, Montreal Road, Ottawa, Ontario K1A 0R6 (Canada)
2015-04-27
We investigate nuclear spin pumping with five-electron quadruplet spin states in a spin-blockaded weakly coupled vertical double quantum dot device. Two types of hysteretic steps in the leakage current are observed on sweeping the magnetic field and are associated with bidirectional polarization of nuclear spin. Properties of the steps are understood in terms of bias-voltage-dependent conditions for the mixing of quadruplet and doublet spin states by the hyperfine interaction. The hysteretic steps vanish when up- and down-nuclear spin pumping processes are in close competition.
Optical hyperpolarization of 13C nuclear spins in nanodiamond ensembles
Chen, Q.; Schwarz, I.; Jelezko, F.; Retzker, A.; Plenio, M. B.
2015-11-01
Dynamical nuclear polarization holds the key for orders of magnitude enhancements of nuclear magnetic resonance signals which, in turn, would enable a wide range of novel applications in biomedical sciences. However, current implementations of DNP require cryogenic temperatures and long times for achieving high polarization. Here we propose and analyze in detail protocols that can achieve rapid hyperpolarization of 13C nuclear spins in randomly oriented ensembles of nanodiamonds at room temperature. Our protocols exploit a combination of optical polarization of electron spins in nitrogen-vacancy centers and the transfer of this polarization to 13C nuclei by means of microwave control to overcome the severe challenges that are posed by the random orientation of the nanodiamonds and their nitrogen-vacancy centers. Specifically, these random orientations result in exceedingly large energy variations of the electron spin levels that render the polarization and coherent control of the nitrogen-vacancy center electron spins as well as the control of their coherent interaction with the surrounding 13C nuclear spins highly inefficient. We address these challenges by a combination of an off-resonant microwave double resonance scheme in conjunction with a realization of the integrated solid effect which, together with adiabatic rotations of external magnetic fields or rotations of nanodiamonds, leads to a protocol that achieves high levels of hyperpolarization of the entire nuclear-spin bath in a randomly oriented ensemble of nanodiamonds even at room temperature. This hyperpolarization together with the long nuclear-spin polarization lifetimes in nanodiamonds and the relatively high density of 13C nuclei has the potential to result in a major signal enhancement in 13C nuclear magnetic resonance imaging and suggests functionalized and hyperpolarized nanodiamonds as a unique probe for molecular imaging both in vitro and in vivo.
International Nuclear Information System (INIS)
Agrawal, P.K.
1989-01-01
The present book has been written with the objective of introducing the organic chemists with the conceptual and experimental basis required for interpretation of 13 C NMR spectra of a flavonoid and to a discussion of general usefulness of the technique in solving flavonoid structural problem. After a brief general introduction to the essential aspects of flavonoids and 13 C NMR spectroscopy, considerable emphasis has been placed in chapter 2 on the various experimental methods and the interpretation of spectral details which enable individual resonance lines to be associated with the appropriate carbons in a molecule. The whole bulk of the literature, published on 13 C NMR of flavonoids in the major journals upto 1986 alongwith some recent references of 1987 has been classified in several categories such as: flavonoids, isflavonoids, other flavonoids, flavonoid glycosides, chalconoids and flavanoids. Each category constitutes a chapter. Finally the last chapter is devoted largely to a discussion for the differentiation of various categories and subcategories of flavonoids and for the establishment of aromatic substitution pattern in these compounds. It should be emphasized that the book is a data book and only concerned with the actual analysis of 13 C NMR spectra, thus a reasonable familiarity with basic instrumentation of 13 C NMR and general pattern of nuclear chemical shifts has been assumed. (author). refs.; figs.; tabs
International conference on spin observables of nuclear probes: Summary talk
International Nuclear Information System (INIS)
Garvey, G.T.
1988-01-01
A selected summary of the presentation and discussions at the 4th Telluride Conference is presented. The summary deals mainly with the effects of nuclear spin and isospin on the interaction between nucleons and their consequences in nuclear structure. 11 figs
The domestication of nuclear spins by chemists and biologists
Ernst, R
1992-01-01
The usage of nuclear spins in chemistry and biology for exploring the structure and dynamics of matter is discussed. The main emphasis is put on the methodological aspects of multidimensional nuclear magnetic resonance (NMR) spectroscopy that are responsible for the success of this powerful analytical technique.
Polarization transfer from polarized nuclear spin to μ- spin in muonic atom
International Nuclear Information System (INIS)
Kuno, Yoshitaka; Nagamine, Kanetada; Yamazaki, Toshimitsu.
1987-02-01
A theoretical study of polarization transfer from an initially-polarized nuclear spin to a μ - spin in a muonic atom is given. The switching of the hyperfine interaction at excited muonic states as well as at the ground 1s state is taken into account. The upper state of hyperfine doublet at the muonic 1s state is considered to proceed down to the lower state. It is found that as the hyperfine interaction becomes effective at higher excited muonic orbitals, a less extent of polarization is transferred from the nuclear spin to the μ - spin. The theoretical values obtained are compared with the recent experiment of μ - repolarization in a polarized 209 Bi target. (author)
Dephasing due to Nuclear Spins in Large-Amplitude Electric Dipole Spin Resonance.
Chesi, Stefano; Yang, Li-Ping; Loss, Daniel
2016-02-12
We analyze effects of the hyperfine interaction on electric dipole spin resonance when the amplitude of the quantum-dot motion becomes comparable or larger than the quantum dot's size. Away from the well-known small-drive regime, the important role played by transverse nuclear fluctuations leads to a Gaussian decay with characteristic dependence on drive strength and detuning. A characterization of spin-flip gate fidelity, in the presence of such additional drive-dependent dephasing, shows that vanishingly small errors can still be achieved at sufficiently large amplitudes. Based on our theory, we analyze recent electric dipole spin resonance experiments relying on spin-orbit interactions or the slanting field of a micromagnet. We find that such experiments are already in a regime with significant effects of transverse nuclear fluctuations and the form of decay of the Rabi oscillations can be reproduced well by our theory.
Nuclear spin relaxation by translational diffusion in solids
International Nuclear Information System (INIS)
Barton, W.A.; Sholl, C.A.
1978-01-01
The theory of nuclear spin relaxation by translational diffusion in solids developed in previous papers is applied to two-spin systems and third-nearest-neighbour jump models in FCC crystals. The two-spin systems describe the dipole-dipole interactions between stationary host spins and spins migrating amongst either the tetrahedral or the octahedral interstitial sites. The tetrahedral sites in a FCC crystal form a SC lattice and two models, the symmetric and asymmetric jump models, are considered for third-nearest-neighbour jumps on this lattice. Numerical results for the correlation function relevant for single crystals and polycrystals are presented over the entire temperature range. It is found that the simpler, but unphysical, symmetric jump model is a good approximation to the more complicated asymmetric jump model. (author)
Nuclear spin warm up in bulk n -GaAs
Kotur, M.; Dzhioev, R. I.; Vladimirova, M.; Jouault, B.; Korenev, V. L.; Kavokin, K. V.
2016-08-01
We show that the spin-lattice relaxation in n -type insulating GaAs is dramatically accelerated at low magnetic fields. The origin of this effect, which cannot be explained in terms of well-known diffusion-limited hyperfine relaxation, is found in the quadrupole relaxation, induced by fluctuating donor charges. Therefore, quadrupole relaxation, which governs low field nuclear spin relaxation in semiconductor quantum dots, but was so far supposed to be harmless to bulk nuclei spins in the absence of optical pumping, can be studied and harnessed in the much simpler model environment of n -GaAs bulk crystal.
Entanglement measures in embedding quantum simulators with nuclear spins
Xin, Tao; Pedernales, Julen S.; Solano, Enrique; Long, Gui-Lu
2018-02-01
We implement an embedding quantum simulator (EQS) in nuclear spin systems. The experiment consists of a simulator of up to three qubits, plus a single ancillary qubit, where we are able to efficiently measure the concurrence and the three-tangle of two-qubit and three-qubit systems as they undergo entangling dynamics. The EQS framework allows us to drastically reduce the number of measurements needed for this task, which otherwise would require full-state reconstruction of the qubit system. Our simulator is built of the nuclear spins of four 13C atoms in a molecule of trans-crotonic acid manipulated with NMR techniques.
Schematic model of nuclear spin excitations
International Nuclear Information System (INIS)
Boucher, P.M.
1990-01-01
A simple model to estimate the strength of spin and nonspin collective states is presented. The model was inspired by early schematic models based on energy-weighted sum rules and is a useful tool for interpreting experimental data without the complexities of realistic microscopic calculations. The strength of collective states is calculated by assuming that a single collective state completely exhausts the energy-weighted sum rule. 19 refs
Generating highly polarized nuclear spins in solution using dynamic nuclear polarization
DEFF Research Database (Denmark)
Wolber, J.; Ellner, F.; Fridlund, B.
2004-01-01
A method to generate strongly polarized nuclear spins in solution has been developed, using Dynamic Nuclear Polarization (DNP) at a temperature of 1.2K, and at a field of 3.354T, corresponding to an electron spin resonance frequency of 94GHz. Trityl radicals are used to directly polarize 13C...... and other low-γ nuclei. Subsequent to the DNP process, the solid sample is dissolved rapidly with a warm solvent to create a solution of molecules with highly polarized nuclear spins. Two main applications are proposed: high-resolution liquid state NMR with enhanced sensitivity, and the use...
Bobbert, P.A.
2014-01-01
The growing interest in spin manipulation in the field of spin electronics, or "spintronics," is due to the wealth of exciting possibilities that it offers in areas of magnetic sensing, new types of information storage, low-power electronics, and quantum information processing. Nuclear spin
Squeezing and entangling nuclear spins in helium 3
DEFF Research Database (Denmark)
Reinaudi, Gael; Sinatra, Alice; Dantan, Aurelien Romain
2007-01-01
We present a realistic model for transferring the squeezing or the entanglement of optical field modes to the collective ground state nuclear spin of 3He using metastability exchange collisions. We discuss in detail the requirements for obtaining good quantum state transfer efficiency and study t...
Increasing Spin Coherence in Nanodiamond via Dynamic Nuclear Polarization
Gaebel, Torsten; Rej, Ewa; Boele, Thomas; Waddington, David; Reilly, David
Nanodiamonds are of interest for quantum information technology, as metrological sensors, and more recently as a probe of biological environments. Here we present results examining how intrinsic defects can be used for dynamic nuclear polarization that leads to a dramatic increase in both T1 and T2 for 13C spins in nanodiamond. Mechanisms to explain this enhancement are discussed.
Nuclear moments of inertia at high spins
International Nuclear Information System (INIS)
Deleplanque, M.A.
1984-01-01
For nuclei in high spin states a yrast-like part of a continuum γ-ray spectrum shows naturally how angular momentum is generated as a function of frequency. In rotational nuclei, the rotational frequency is omega = dE/dI approx. E/sub γ/2, half the collective E2 transition energy. The height of the spectrum for a rotor is proportional to dN/dE/sub γ/ = dI/4d omega. dI/d omega is a dynamic (second derivative of energy with spin) moment of inertia. It contains both alignments and collective effects and is therefore an effective moment of inertia J/sub eff//sup (2)/. It shows how much angular momentum is generated at each frequency. If the collective moment of inertia J/sub band//sup (2)/(omega) is measured (from γ-γ correlation experiments) for the same system, the collective and aligned (Δi) contributions to the increase of angular momentum ΔI in a frequency interval Δ omega can be separated: Δi/ΔI = 1 - J/sub band//sup (2)//J/sub eff//sup (2)/. This is at present the only way to extract such detailed information at the highest spin states where discrete lines cannot be resolved. An example of the spectra obtained in several Er nuclei is shown. They are plotted in units of the moment of inertia J/sub eff//sup (2)/. The high-energy part of the spectra has been corrected for incomplete feeding at these frequencies
Hanle effect in (In,Ga)As quantum dots: Role of nuclear spin fluctuations
Kuznetsova, M. S.; Flisinski, K.; Gerlovin, I. Ya.; Ignatiev, I. V.; Kavokin, K. V.; Verbin, S. Yu.; Yakovlev, D. R.; Reuter, D.; Wieck, A. D.; Bayer, M.
2013-01-01
The role of nuclear spin fluctuations in the dynamic polarization of nuclear spins by electrons is investigated in (In,Ga)As quantum dots. The photoluminescence polarization under circularly polarized optical pumping in transverse magnetic fields (Hanle effect) is studied. A weak additional magnetic field parallel to the optical axis is used to control the efficiency of nuclear spin cooling and the sign of nuclear spin temperature. The shape of the Hanle curve is drastically modified with cha...
Nuclear moments of inertia at high spin
International Nuclear Information System (INIS)
Deleplanque, M.A.
1982-10-01
The competition between collective motion and alignment at high spin can be evaluated by measuring two complementary dynamic moments of inertia. The first, I band, measured in γ-γ correlation experiments, relates to the collective properties of the nucleus. A new moment of inertia I/sub eff/ is defined here, which contains both collective and alignment effects. Both of these can be measured in continuum γ-ray spectra of rotational nuclei up to high frequencies. The evolution of γ-ray spectra for Er nuclei from mass 160 to 154 shows that shell effects can directly be observed in the spectra of the lighter nuclei
Symmetry rules for the indirect nuclear spin-spin coupling tensor revisited
Buckingham, A. D.; Pyykkö, P.; Robert, J. B.; Wiesenfeld, L.
The symmetry rules of Buckingham and Love (1970), relating the number of independent components of the indirect spin-spin coupling tensor J to the symmetry of the nuclear sites, are shown to require modification if the two nuclei are exchanged by a symmetry operation. In that case, the anti-symmetric part of J does not transform as a second-rank polar tensor under symmetry operations that interchange the coupled nuclei and may be called an anti-tensor. New rules are derived and illustrated by simple molecular models.
Quantum information generation, storage and transmission based on nuclear spins
Zaharov, V. V.; Makarov, V. I.
2018-05-01
A new approach to quantum information generation, storage and transmission is proposed. It is shown that quantum information generation and storage using an ensemble of N electron spins encounter unresolvable implementation problems (at least at the present time). As an alternative implementation we discuss two promising radical systems, one with N equivalent nuclear spins and another with N nonequivalent nuclear spins. Detailed analysis shows that only the radical system containing N nonequivalent nuclei is perfectly matched for quantum information generation, storage and transmission. We develop a procedure based on pulsed electron paramagnetic resonance (EPR) and we apply it to the radical system with the set of nonequivalent nuclei. The resulting EPR spectrum contains 2N transition lines, where N is the number of the atoms with the nuclear spin 1/2, and each of these lines may be encoded with a determined qudit sequence. For encoding the EPR lines we propose to submit the radical system to two magnetic pulses in the direction perpendicular to the z axis of the reference frame. As a result, the radical system impulse response may be measured, stored and transmitted through the communications channel. Confirming our development, the ab initio analysis of the system with three anion radicals was done showing matching between the simulations and the theoretical predictions. The developed method may be easily adapted for quantum information generation, storage, processing and transmission in quantum computing and quantum communications applications.
Axial currents and nuclear spin orientation
International Nuclear Information System (INIS)
Minamisono, T.; Nojiri, Y.; Matsuta, K.
1984-01-01
This paper discusses the symmetries in the phenomena in which weak interaction is involved are largely violated, and it is still the up-to-date fore-front to study the structure of the nuclear weak currents and to learn the limitations on the applicabilities of the various relevant conservation laws as well as the nuclear structures studied by the β-decay. In this meeting, research works on the β-decay processes for the past 10 years have focused on the recoil order experiments designed to determine the limits of validity of the conserved vector current (CVC) theory and to test the G parity conservation i.e. the search for the second class currents (SCC), as well as to study the structure of the axial currents. Concerning the SCC, after intensive studies, but with not conclusive results, on the ft values of mirror β-decays in the early seventies, the correlation-type measurements on mass A=8, 12, 19 and 20 systems have been also carried out in various laboratories from 1975. Among those, concerns have been with the mass A=12 nuclear triad, /sup 12/B-/sup 12/C-/sup 12/N, the energy diagram of which is well known. The choice of this triad is because of the test done for the strong CVC predictions using the spectrum shapes of β-rays combined with the experimental analogue γ-width in /sup 12/C as well as those relevant nuclear structures. Thus, this A=12 system provides the best testing ground for the research described above
Relaxation of coupled nuclear spin systems
International Nuclear Information System (INIS)
Koenigsberger, E.
1985-05-01
The subject of the present work is the relaxation behaviour of scalarly coupled spin-1/2 systems. In the theoretical part the semiclassical Redfield equations are used. Dipolar (D), Chemical Shift Anisotropy (CSA) and Random Field (RF) interactions are considered as relaxation mechanisms. Cross correlations of dipolar interactions of different nuclei pairs and those between the D and the CSA mechanisms are important. The model of anisotropic molecular rotational relaxation and the extreme narrowing approximation are used to obtain the spectral density functions. The longitudinal relaxation data are analyzed into normal modes following Werbelow and Grant. The time evolution of normal modes is derived for the AX system with D-CSA cross terms. In the experimental part the hypothesis of dimerization in the cinnamic acid and the methyl cinnamate - AMX systems with DD cross terms - is corroborated by T 1 -time measurements and a calculation of the diffusion constants. In pentachlorobenzene - an AX system - taking into account of D-CSA cross terms enables the complete determination of movements anosotropy and the determination of the sign of the indirect coupling constant 1 Jsub(CH). (G.Q.)
Nuclear spin response studies in inelastic polarized proton scattering
International Nuclear Information System (INIS)
Jones, K.W.
1988-01-01
Spin-flip probabilities S/sub nn/ have been measured for inelastic proton scattering at incident proton energies around 300 MeV from a number of nuclei. At low excitation energies S/sub nn/ is below the free value. For excitation energies above about 30 MeV for momentum transfers between about 0.35 fm/sup /minus/1/ and 0.65 fm/sup / minus/1/ S/sub nn/ exceeds free values significantly. These results suggest that the relative ΔS = 1(ΔS = 0 + ΔS = 1) nuclear spin response approaches about 90% in the region of the enhancement. Comparison of the data with slab response calculations are presented. Decomposition of the measured cross sections into σ(ΔS = 0) and σ(ΔS = 1) permit extraction of nonspin-flip and spin-flip dipole and quadrupole strengths. 29 refs., 11 figs
Nuclear spin: Fifty years of ups and downs
Energy Technology Data Exchange (ETDEWEB)
Pines, A. [Lawrence Berkeley National Lab., CA (United States)
1996-12-31
Rumors of its demise notwithstanding, nuclear magnetic resonance (NMR) continues to flourish fifty years after our birth. The lecture will be a reminiscence about moments of excitation, coherence and relaxation in the history of NMR which produced, among other developments, spin echoes and time reversal, Fourier transform and multidimensional spectroscopy, magnetic resonance imaging, and high resolution solid state NMR. Applications of modern NMR spectroscopy cut across the boundaries of physics, chemistry, materials, biology and medicine.
The electron-nuclear spin system in (In,Ga)As quantum dots
International Nuclear Information System (INIS)
Auer, Thomas
2008-01-01
For a long time, the nuclear spins in quantum dots were virtually ignored. It was thought that the interaction strength was so small that the interaction between the nuclei and electrons could only be observed under very specific optical pumping conditions. Then, in the pursuit of long living electron spins as a building block for quantum information storage and processing, their destructive action on the lifetime of the electron spin became apparent. The nuclear spin system increasingly gained the attention of the quantum dot community. It seemed that the randomly oriented, fluctuating nuclear spins can only be counteracted by strong magnetic fields suppressing the depolarising effect of the random nuclear spin fluctuation fields on a single electron spin. Gradually, however, the work done thirty years before on the electron-nuclear spin system in bulk semiconductors attracted the notice of scientists again. Some of the old experiments could be performed with quantum dots as well. It could be shown that the nuclear spins in quantum dots may well be polarised by optical orientation and that their action is not always destructive at all. The nuclear spins in quantum dots are increasingly used in order to create and tailor a specific environment for a single electron in a quantum dot. In this way quantum dots contain their own ''nuclear nanomagnet''. This might be the future of the studies on the electron-nuclear spin system. The aim of this work is to shed some more light on the complex interdependent system formed of an electron spin and the nuclear spin ensemble in quantum dots. The effects are manifold, often unexpected, sometimes miraculous. Nevertheless, I believe that this work is another tiny step towards the understanding of this challenging system. I have shown that the randomly polarised nuclear spin system always affects the electron spin of a single electron in quantum dots. Further we have seen, however, that the nuclear spin system can easily be
Nuclear spin dynamics in double quantum dots : Fixed points, transients, and intermittency
Rudner, M.S.; Koppens, F.H.L.; Folk, J.A.; Vandersypen, L.M.K.; Levitov, L.S.
2011-01-01
Transport through spin-blockaded quantum dots provides a means for electrical control and detection of nuclear spin dynamics in the host material. Although such experiments have become increasingly popular in recent years, interpretation of their results in terms of the underlying nuclear spin
Nuclear high-spin data for A = 174, 176 and 184
Energy Technology Data Exchange (ETDEWEB)
Junde, Huo [Jilin Univ. (China). Dept. of Physics
1996-06-01
Nuclear high-spin data are important in the frontier areas of nuclear structure physics. The information on A = 174, 176 and 184 mass chains from various reaction experiments together with their adopted high-spin levels and gamma transition properties are presented and discussed. High-spin data for A = 174, 176 and 184 mass chains were evaluated in 1995.
Long lived quantum memory with nuclear atomic spins
International Nuclear Information System (INIS)
Sinatra, A.; Reinaudi, G.; Dantan, A.; Giacobino, E.; Pinard, M.
2005-01-01
We propose store non-classical states of light into the macroscopic collective nuclear spin (10 18 atoms) of a 3 He vapor, using metastability exchange collisions. We show that these collisions currently used to transfer orientation from the metastable state 2 3 S 1 to the ground state state of 3 He, may conserve quantum correlations and give a possible experimental scheme to perfectly map a squeezed vacuum field state onto a nuclear spin state, which should allow for extremely long storage times (hours). In addition to the apparent interest for quantum information, the scheme offers the intriguing possibility to create a long-lived non classical state for spins. During a metastability exchange collision an atom in the ground state state and an atom in the metastable triplet state 2 3 S exchange their electronic spin variables. The ground state atom is then brought into the metastable state and vice-versa. A laser transition is accessible from the metastable state so that the metastable atoms are coupled with light. This, together with metastability exchange collisions, provides an effective coupling between ground state atoms and light. In our scheme, a coherent field and a squeezed vacuum field excite a Raman transition between Zeeman sublevels of the metastable state, after the system is prepared in the fully polarized state by preliminary optical pumping. According to the intensity of the coherent field, which acts as a control parameter, the squeezing of the field can be selectively transferred either to metastable or to ground state atoms. Once it is encoded in the purely nuclear spin of the ground state of 3 He, which is 20 eV apart from the nearest excited state and interacts very little with the environment, the quantum state can survive for times as long as several hours. By lighting up only the coherent field in the same configuration as for the 'writing' phase, the nuclear spin memory can be 'read' after a long delay, the squeezing being transferred
Nuclear structure at high and very high spin theoretical description
International Nuclear Information System (INIS)
Szymanski, Z.
1983-11-01
When the existence of nuclear shell structure is ignored and nuclear motion is assumed to be classical we may expect that the nuclear rotation resembles that of a liquid drop. Energy of the nucleus can be thus considered as a sum of three terms: surface energy, Coulomb energy and rotational energy. Nuclear moment of inertia is assumed to be that of a rigid-body. The results of a calculation of the energy surfaces in rotating nuclei by Cohen, Plasil and Swiatecki are discussed. Cranking procedure is analysed as a tool to investigate nucleonic orbits in a rotating nuclear potential. Some predictions concerning the possible onset of a superdeformed phase are given. The structure of nuclear rotation is examined in the presence of the short-range pairing forces that generate the superfluid correlations in the nucleus. Examples of the Bengtsson-Frauendorf plots (quasiparticle energies versus angular velocity of rotation) are given and discussed. The backbending phenomenon is analysed in terms of band crossing. The dependence of the crossing frequency on the pairing-force strength is discussed. Possibilities of the role of new components in the two-body force (quadrupole-pairing) are considered. Possibilities of the phase transition from superfluid to normal states in the nucleus are analysed. The role of the second (dynamic) moment of inertia I(2) in this analysis is discussed. In spherical weekly deformed nuclei (mostly oblate) angular momentum is aligned parallel to the nuclear symmetry axis. Rotation is of non collective origin in this case. Examples of the analysis of nuclear spectra in this case (exhibiting also the isomeric states called yrast (traps)) are given. Possible forms of the collective excitations superimposed on top of the high-spin states are discussed. In particular, the giant resonance excitations formed on top of the high-spin states are considered and their properties discussed
Isoscalar spin-spin interaction within the quasiparticle-phonon nuclear model
International Nuclear Information System (INIS)
Dao Tien Khoa; Ponomarev, V.Yu.; Vdovin, A.I.
1986-01-01
The isoscalar spin-spin interaction constant in the quasiparticle-phonon nuclear model (QPM) has been determined from the available experimental data on the isoscalar 1 + state (E x =5.846 MeV) in 208 Pb. The isoscalar spin-spin interaction turns out to be weaker than the isovector one by an order of magnitude. The cross sections of (e, e') and (p, p') reactions with the excitation of this 1 + -state have been calculated. The QPM gives a good description of the behaviour of (e, e')-cross section at q eff -1 and reproduces absolute value of this cross section with the effective g s -factors weaker than the g s -factors for free nucleon by 20%. The description of the (p, p')-angular distribution of 201 MeV photon inelastic scattering is poorer. The absolute value of the calculated (p, p') cross section overestimates the experimental data by a factor of about 1.4. This is consistent with the quenching factor for (e, e') cross section. The interaction with two-phonon configurations influences very weakly the isoscalar 1 + -level
Nuclear spin-spin coupling in a van der Waals-bonded system: xenon dimer.
Vaara, Juha; Hanni, Matti; Jokisaari, Jukka
2013-03-14
Nuclear spin-spin coupling over van der Waals bond has recently been observed via the frequency shift of solute protons in a solution containing optically hyperpolarized (129)Xe nuclei. We carry out a first-principles computational study of the prototypic van der Waals-bonded xenon dimer, where the spin-spin coupling between two magnetically non-equivalent isotopes, J((129)Xe - (131)Xe), is observable. We use relativistic theory at the four-component Dirac-Hartree-Fock and Dirac-density-functional theory levels using novel completeness-optimized Gaussian basis sets and choosing the functional based on a comparison with correlated ab initio methods at the nonrelativistic level. J-coupling curves are provided at different levels of theory as functions of the internuclear distance in the xenon dimer, demonstrating cross-coupling effects between relativity and electron correlation for this property. Calculations on small Xe clusters are used to estimate the importance of many-atom effects on J((129)Xe - (131)Xe). Possibilities of observing J((129)Xe - (131)Xe) in liquid xenon are critically examined, based on molecular dynamics simulation. A simplistic spherical model is set up for the xenon dimer confined in a cavity, such as in microporous materials. It is shown that the on the average shorter internuclear distance enforced by the confinement increases the magnitude of the coupling as compared to the bulk liquid case, rendering J((129)Xe - (131)Xe) in a cavity a feasible target for experimental investigation.
International Nuclear Information System (INIS)
Kaliambos, L.A.
2008-01-01
Fundamental interactions of spinning electrons at an interelectron separation less than 578.8 fm yield attractive electromagnetic forces with S = 0 creating vibrations under a motional emf. They explain the indistinguishability of electrons and give a vibration energy able for calculating the ground-state energies of many-electron atoms without using any perturbative approximation. Such forces create two-electron orbitals able to account for the exclusion principal and the mechanism of covalent bonds. In the outer subshells of atoms the penetrating orbitals interact also as pair-pair systems and deform drastically the probability densities of the quantum mechanical electron clouds. Such a dynamics of deformation removes the degeneracy and leads to the deviation from the shell scheme. However in the interior of atoms the large nuclear charge leads to a spherically symmetric potential with non-interacting pairs for creating shells of degenerate states giving an accurate explanation of the X-ray lines. On the other hand, considerable charge distributions in nucleons as multiples of 2e/3 and - e/3 determined by the magnetic moments, interact for creating the nuclear structure with p-n bonds. Such spin-spin interactions show that the dominant concept of the untisymmetric wave function for fermions is inapplicable not only in the simple p-n, p-p, and n-n systems but also in the LS coupling of atoms in which the electrons interact from different quantum states giving either S = 0 or S = l. (author)
Response function of spin-isospin nuclear excitations
International Nuclear Information System (INIS)
Salvetti, A.R.
1986-01-01
The selected aspects of spin-isospir nuclear excitations are studied. The spreading width of M/ states in even Ca isotopes for the purpose of trying to understand the missing strenght specially in 44 Ca, was estimated. The doorway calculation, was used, considering the level of complexity next to the independent particle M/ state. Using a nuclear matter context, the system response function to a spin-isospin probe and verify how the response function behaves for free fermions and in the ring approximation was studied. Higher correlations to polarization propagation such as the induced interaction and self-energy corrections was introduced. The dopping of colletive effects by such collisions terms was verified. It was investigate how to estimate the short range term of the effective interaction in the spin-isospin channel and the possibility of detecting a difference between these short range terms in the longitudinal and the transverse channel, for understanding the absence of pior condensation precursor states and negative results in a recent attempt to detect differences between longitudinal and transverse response functions one naively expects theoretically. (author) [pt
Nuclear structure at high-spin and large-deformation
International Nuclear Information System (INIS)
Shimizu, Yoshifumi R.
2000-01-01
Atomic nucleus is a finite quantal system and shows various marvelous features. One of the purposes of the nuclear structure study is to understand such features from a microscopic viewpoint of nuclear many-body problem. Recently, it is becoming possible to explore nuclear states under 'extreme conditions', which are far different from the usual ground states of stable nuclei, and new aspects of such unstable nuclei attract our interests. In this lecture, I would like to discuss the nuclear structure in the limit of rapid rotation, or the extreme states with very large angular momenta, which became accessible by recent advent of large arrays of gamma-ray detecting system; these devices are extremely useful to measure coincident multiple γ-rays following heavy-ion fusion reactions. Including such experimental aspects as how to detect the nuclear rotational states, I review physics of high-spin states starting from the elementary subjects of nuclear structure study. In would like also to discuss the extreme states with very large nuclear deformation, which are easily realized in rapidly rotating nuclei. (author)
Optical switching of nuclear spin–spin couplings in semiconductors
Goto, Atsushi; Ohki, Shinobu; Hashi, Kenjiro; Shimizu, Tadashi
2011-01-01
Two-qubit operation is an essential part of quantum computation. However, solid-state nuclear magnetic resonance quantum computing has not been able to fully implement this functionality, because it requires a switchable inter-qubit coupling that controls the time evolutions of entanglements. Nuclear dipolar coupling is beneficial in that it is present whenever nuclear–spin qubits are close to each other, while it complicates two-qubit operation because the qubits must remain decoupled to prevent unwanted couplings. Here we introduce optically controllable internuclear coupling in semiconductors. The coupling strength can be adjusted externally through light power and even allows on/off switching. This feature provides a simple way of switching inter-qubit couplings in semiconductor-based quantum computers. In addition, its long reach compared with nuclear dipolar couplings allows a variety of options for arranging qubits, as they need not be next to each other to secure couplings. PMID:21730962
Optical pumping of electron and nuclear spin in a negatively-charged quantum dot
Bracker, Allan; Gershoni, David; Korenev, Vladimir
2005-03-01
We report optical pumping of electron and nuclear spins in an individual negatively-charged quantum dot. With a bias-controlled heterostructure, we inject one electron into the quantum dot. Intense laser excitation produces negative photoluminescence polarization, which is easily erased by the Hanle effect, demonstrating optical pumping of a long-lived resident electron. The electron spin lifetime is consistent with the influence of nuclear spin fluctuations. Measuring the Overhauser effect in high magnetic fields, we observe a high degree of nuclear spin polarization, which is closely correlated to electron spin pumping.
High-spin nuclear structure studies with radioactive ion beams
International Nuclear Information System (INIS)
Baktash, C.
1992-01-01
Two important developments in the sixties, namely the advent of heavy-ion accelerators and fabrication of Ge detectors, opened the way for the experimental studies of nuclear properties at high angular momentum. Addition of a new degree of freedom, namely spin, made it possible to observe such fascinating phenomena as occurrences and coexistence of a variety of novel shapes, rise, fall and occasionally rebirth of nuclear collectivity, and disappearance of pairing correlations. Today, with the promise of development of radioactive ion beams (RIB) and construction of the third-generation Ge-detection systems (GAMMASPHERE and EUROBALL), nuclear physicists are poised to explore new and equally fascinating phenomena that have been hitherto inaccessible. With the addition of yet another dimension, namely the isospin, they will be able to observe and verify predictions for exotic shapes as varied as rigid triaxiality, hyperdeformation and triaxial-octupole shapes, or to investigate the T=O pairing correlations. In this paper, the author reviews, separately for neutron-deficient and neutron-rich nuclei, these and a few other new high-spin physics opportunities that may be realized with RIB. Following this discussion, a list of the beam species, intensities and energies that are needed to fulfill these goals is presented. The paper concludes with a description of the experimental techniques and instrumentations that are required for these studies
Characterization of coal structure by CP/MAS carbon-13 NMR spectrometry
International Nuclear Information System (INIS)
Yoshida, T.; Maekawa, Y.
1987-01-01
Cross-polarization (CP)/magic angle spinning (MAS) carbon-13 nuclear magnetic resonance (n.m.r.) spectrometry has been applied to the analysis of the whole structures of different ranks of coal. Three basic structural parameters, namely carbon aromaticity fa, new carbon aromaticity fa', and atomic H/C ratio for the hypothetical unsubstituted aromatic nuclei Haru/Car, were derived from the combined data of ultimate analysis, the distributions of carbon and oxygen functional groups obtained from the spectrum and the distribution of four types of methylene carbon groups in coal. Both fa and fa' values generally increased with coal rank and ranged from 0.51 to 0.71 and from 0.62 to 0.76, respectively. Haru/Car value tended to decrease with coal rank although the value was greatly affected by the types of hydroaromatic methylene carbons to aromatic rings. The values indicated that lower-rank coals consisted mainly of 1-3 aromatic rings, and higher-rank coals, 3-5 aromatic rings. 24 refs.; 5 figs.; 4 tabs
Spin-off strategies for the improvement of the performance national nuclear R and D project
International Nuclear Information System (INIS)
Lee, T. J.; Kim, H. J.; Jung, H. S.; Yang, M. H.; Choi, Y. M.
1998-01-01
In the light of the strategic utilization of the national R and D projects, this paper is to induce the spin-off strategies to improve the national R and D effectiveness through analyzing the spin-off characteristics of nuclear technologies, the spin-off status of the advanced countries and the case study of Korean nuclear spin-offs. Spin-off process is viewed as a three-stage operation, such as preparation stage, implementation stage and maintenance stage. In order to find the correlation between the influencing factors and spin-off effectiveness, the Spearman's correlation coefficient was employed as a specific statistical technique. By integrating this correlation, spin-off process and spin-off strategies, this paper presents an efficient frame work to improve the spin-off effectiveness
Graham, Michael J; Krzyaniak, Matthew D; Wasielewski, Michael R; Freedman, Danna E
2017-07-17
Quantum information processing (QIP) has the potential to transform numerous fields from cryptography, to finance, to the simulation of quantum systems. A promising implementation of QIP employs unpaired electronic spins as qubits, the fundamental units of information. Though molecular electronic spins offer many advantages, including chemical tunability and facile addressability, the development of design principles for the synthesis of complexes that exhibit long qubit superposition lifetimes (also known as coherence times, or T 2 ) remains a challenge. As nuclear spins in the local qubit environment are a primary cause of shortened superposition lifetimes, we recently conducted a study which employed a modular spin-free ligand scaffold to place a spin-laden propyl moiety at a series of fixed distances from an S = 1 / 2 vanadium(IV) ion in a series of vanadyl complexes. We found that, within a radius of 4.0(4)-6.6(6) Å from the metal center, nuclei did not contribute to decoherence. To assess the generality of this important design principle and test its efficacy in a different coordination geometry, we synthesized and investigated three vanadium tris(dithiolene) complexes with the same ligand set employed in our previous study: K 2 [V(C 5 H 6 S 4 ) 3 ] (1), K 2 [V(C 7 H 6 S 6 ) 3 ] (2), and K 2 [V(C 9 H 6 S 8 ) 3 ] (3). We specifically interrogated solutions of these complexes in DMF-d 7 /toluene-d 8 with pulsed electron paramagnetic resonance spectroscopy and electron nuclear double resonance spectroscopy and found that the distance dependence present in the previously synthesized vanadyl complexes holds true in this series. We further examined the coherence properties of the series in a different solvent, MeCN-d 3 /toluene-d 8 , and found that an additional property, the charge density of the complex, also affects decoherence across the series. These results highlight a previously unknown design principle for augmenting T 2 and open new pathways for the
Determination of the percentage of quitine desacetilation reaction by solid state carbon-13 NMR
International Nuclear Information System (INIS)
Ferracin, Ricardo J.; Cass, Quezia B.; Bassi, Ana L.
1997-01-01
Quitine is a bi-polymer largely found in invertebrates. As most compounds of this class are insoluble in common organic solvents, the des-acetylation percentile was obtained by carbon-13 solid state nuclear magnetic resonance. The methodology is presented. Results are presented
Nuclear spin dynamics in soap solutions and related systems
International Nuclear Information System (INIS)
Bloom, M.
1973-01-01
Soap molecules consist of a hydrophilic head and a hydrophobic lipid tail. For example, potassium laureate, the soap molecule on which the most complete study of nuclear spin dynamics has been made has the chemical formula KCOO(CH 2 ) 10 CH 3 . High concentration (greater than or approximately equal to 20% soap molecules by weight) soap solutions in water form ordered, liquid crystal structures in which the polar heads are arranged on regular surfaces which define a lattice having long range order. The soap molecules diffuse very rapidly parallel to the surfaces and undergo rapid conformational changes. Studies of T 1 , Tsub(1p) and Tsub(D) have indicated a wide spectrum of correlation times associated with these changes. Because of the orientational order of the soap molecules, the dipolar interactions between nuclear spins on a single molecule are not averaged to zero by the molecular motions. Thus, it is possible to use NMR techniques normally applied to solids (i.e. transfer of Zeeman into dipolar order, etc.) to study their static and dynamical properties. These systems are unusual in that they are basically one-dimensional systems in which the effective, time-averaged, dipolar coupling constants become progressively stronger for protons closer to the polar heads ot the molecules. A review will be presented of the experimental and theoretical NMR work performed on such systems to date. (author)
International Nuclear Information System (INIS)
Sarmento, E.F.
1980-01-01
Results are found for the correlation dynamic functions (or the correspondent green functions) between any combination including pairs of electronic anel nuclear spin operators in an antiferromagnet semi-infinite media., at low temperature T N . These correlation functions, are used to investigate, at the same time, the properties of surface spin waves in volume and surface. The dispersion relatons of nuclear and electronic spin waves coupled modes, in surface are found, resolving a system of linearized equatons of spin operators a system of linearized equations of spin operators. (author) [pt
Fingerprints of single nuclear spin energy levels using STM - ENDOR.
Manassen, Yishay; Averbukh, Michael; Jbara, Moamen; Siebenhofer, Bernhard; Shnirman, Alexander; Horovitz, Baruch
2018-04-01
We performed STM-ENDOR experiments where the intensity of one of the hyperfine components detected in ESR-STM is recorded while an rf power is irradiated into the tunneling junction and its frequency is swept. When the latter frequency is near a nuclear transition a dip in ESR-STM signal is observed. This experiment was performed in three different systems: near surface SiC vacancies where the electron spin is coupled to a next nearest neighbor 29 Si nucleus; Cu deposited on Si(111)7x7 surface, where the unpaired electron of the Cu atom is coupled to the Cu nucleus ( 63 Cu, 65 Cu) and on Tempo molecules adsorbed on Au(111), where the unpaired electron is coupled to a Nitrogen nucleus ( 14 N). While some of the hyperfine values are unresolved in the ESR-STM data due to linewidth we find that they are accurately determined in the STM-ENDOR data including those from remote nuclei, which are not detected in the ESR-STM spectrum. Furthermore, STM-ENDOR can measure single nuclear Zeeman frequencies, distinguish between isotopes through their different nuclear magnetic moments and detect quadrupole spectra. We also develop and solve a Bloch type equation for the coupled electron-nuclear system that facilitates interpretation of the data. The improved spectral resolution of STM - ENDOR opens many possibilities for nanometric scale chemical analysis. Copyright © 2018 Elsevier Inc. All rights reserved.
Solid state nuclear magnetic resonance: investigating the spins of nuclear related materials
International Nuclear Information System (INIS)
Charpentier, Th.
2007-10-01
The author reviews his successive research works: his research thesis work on the Multiple Quantum Magic Angle Spinning (MQMAS) which is a quadric-polar nucleus multi-quanta correlation spectroscopy method, the modelling of NMR spectra of disordered materials, the application to materials of interest for the nuclear industry (notably the glasses used for nuclear waste containment). He presents the various research projects in which he is involved: storing glasses, nuclear magnetic resonance in paramagnetism, solid hydrogen storing matrices, methodological and instrument developments in high magnetic field and high resolution solid NMR, long range distance measurement by solid state Tritium NMR (observing the structure and dynamics of biological complex systems at work)
Voltage switching technique for detecting nuclear spin polarization in a quantum dot
International Nuclear Information System (INIS)
Takahashi, Ryo; Kono, Kimitoshi; Tarucha, Seigo; Ono, Keiji
2010-01-01
We have introduced a source-drain voltage switching technique for studying nuclear spins in a vertical double quantum dot. Switching the source-drain voltage between the spin-blockade state and the zero-bias Coulomb blockade state can tune the energy difference between the spin singlet and triplet, and effectively turn on/off the hyperfine interaction. Since the change in the nuclear spin state affects the source-drain current, nuclear spin properties can only be detected by transport measurement. Using this technique, we have succeeded in measuring the timescale of nuclear spin depolarization. Furthermore, combining this technique and an RF ac magnetic field, we successfully detected continuous-wave NMR signals of 75 As, 69 Ga, and 71 Ga, which are contained in a quantum dot. (author)
Nuclear-spin-dependent parity-nonconserving effects in thallium, lead and bismuth atoms
International Nuclear Information System (INIS)
Khriplovich, I.B.
1994-01-01
Nuclear-spin-dependent P-odd optical activity in atomic Tl, Pb and Bi is calculated. Its magnitude is expressed analytically through the main contribution to the optical rotation, which is independent of nuclear spin. The accuracy of results is discussed. 31 refs., 2 tabs
Cadiz, Fabian; Djeffal, Abdelhak; Lagarde, Delphine; Balocchi, Andrea; Tao, Bingshan; Xu, Bo; Liang, Shiheng; Stoffel, Mathieu; Devaux, Xavier; Jaffres, Henri; George, Jean-Marie; Hehn, Michel; Mangin, Stephane; Carrere, Helene; Marie, Xavier; Amand, Thierry; Han, Xiufeng; Wang, Zhanguo; Urbaszek, Bernhard; Lu, Yuan; Renucci, Pierre
2018-04-11
The emission of circularly polarized light from a single quantum dot relies on the injection of carriers with well-defined spin polarization. Here we demonstrate single dot electroluminescence (EL) with a circular polarization degree up to 35% at zero applied magnetic field. The injection of spin-polarized electrons is achieved by combining ultrathin CoFeB electrodes on top of a spin-LED device with p-type InGaAs quantum dots in the active region. We measure an Overhauser shift of several microelectronvolts at zero magnetic field for the positively charged exciton (trion X + ) EL emission, which changes sign as we reverse the injected electron spin orientation. This is a signature of dynamic polarization of the nuclear spins in the quantum dot induced by the hyperfine interaction with the electrically injected electron spin. This study paves the way for electrical control of nuclear spin polarization in a single quantum dot without any external magnetic field.
Antiferromagnetic spin phase transition in nuclear matter with effective Gogny interaction
International Nuclear Information System (INIS)
Isayev, A.A.; Yang, J.
2004-01-01
The possibility of ferromagnetic and antiferromagnetic phase transitions in symmetric nuclear matter is analyzed within the framework of a Fermi liquid theory with the effective Gogny interaction. It is shown that at some critical density nuclear matter with the D1S effective force undergoes a phase transition to the antiferromagnetic spin state (opposite directions of neutron and proton spins). The self-consistent equations of spin polarized nuclear matter with the D1S force have no solutions corresponding to ferromagnetic spin ordering (the same direction of neutron and proton spins) and, hence, the ferromagnetic transition does not appear. The dependence of the antiferromagnetic spin polarization parameter as a function of density is found at zero temperature
Atomic-Scale Nuclear Spin Imaging Using Quantum-Assisted Sensors in Diamond
Directory of Open Access Journals (Sweden)
A. Ajoy
2015-01-01
Full Text Available Nuclear spin imaging at the atomic level is essential for the understanding of fundamental biological phenomena and for applications such as drug discovery. The advent of novel nanoscale sensors promises to achieve the long-standing goal of single-protein, high spatial-resolution structure determination under ambient conditions. In particular, quantum sensors based on the spin-dependent photoluminescence of nitrogen-vacancy (NV centers in diamond have recently been used to detect nanoscale ensembles of external nuclear spins. While NV sensitivity is approaching single-spin levels, extracting relevant information from a very complex structure is a further challenge since it requires not only the ability to sense the magnetic field of an isolated nuclear spin but also to achieve atomic-scale spatial resolution. Here, we propose a method that, by exploiting the coupling of the NV center to an intrinsic quantum memory associated with the nitrogen nuclear spin, can reach a tenfold improvement in spatial resolution, down to atomic scales. The spatial resolution enhancement is achieved through coherent control of the sensor spin, which creates a dynamic frequency filter selecting only a few nuclear spins at a time. We propose and analyze a protocol that would allow not only sensing individual spins in a complex biomolecule, but also unraveling couplings among them, thus elucidating local characteristics of the molecule structure.
Electron and nuclear spin interactions in the optical spectra of single GaAs quantum dots.
Gammon, D; Efros, A L; Kennedy, T A; Rosen, M; Katzer, D S; Park, D; Brown, S W; Korenev, V L; Merkulov, I A
2001-05-28
Fine and hyperfine splittings arising from electron, hole, and nuclear spin interactions in the magneto-optical spectra of individual localized excitons are studied. We explain the magnetic field dependence of the energy splitting through competition between Zeeman, exchange, and hyperfine interactions. An unexpectedly small hyperfine contribution to the splitting close to zero applied field is described well by the interplay between fluctuations of the hyperfine field experienced by the nuclear spin and nuclear dipole/dipole interactions.
Recursive polarization of nuclear spins in diamond at arbitrary magnetic fields
International Nuclear Information System (INIS)
Pagliero, Daniela; Laraoui, Abdelghani; Henshaw, Jacob D.; Meriles, Carlos A.
2014-01-01
We introduce an alternate route to dynamically polarize the nuclear spin host of nitrogen-vacancy (NV) centers in diamond. Our approach articulates optical, microwave, and radio-frequency pulses to recursively transfer spin polarization from the NV electronic spin. Using two complementary variants of the same underlying principle, we demonstrate nitrogen nuclear spin initialization approaching 80% at room temperature both in ensemble and single NV centers. Unlike existing schemes, our approach does not rely on level anti-crossings and is thus applicable at arbitrary magnetic fields. This versatility should prove useful in applications ranging from nanoscale metrology to sensitivity-enhanced NMR
Room-temperature coupling between electrical current and nuclear spins in OLEDs
Malissa, H.; Kavand, M.; Waters, D. P.; van Schooten, K. J.; Burn, P. L.; Vardeny, Z. V.; Saam, B.; Lupton, J. M.; Boehme, C.
2014-09-01
The effects of external magnetic fields on the electrical conductivity of organic semiconductors have been attributed to hyperfine coupling of the spins of the charge carriers and hydrogen nuclei. We studied this coupling directly by implementation of pulsed electrically detected nuclear magnetic resonance spectroscopy in organic light-emitting diodes (OLEDs). The data revealed a fingerprint of the isotope (protium or deuterium) involved in the coherent spin precession observed in spin-echo envelope modulation. Furthermore, resonant control of the electric current by nuclear spin orientation was achieved with radiofrequency pulses in a double-resonance scheme, implying current control on energy scales one-millionth the magnitude of the thermal energy.
Nuclear reactivity indices in the context of spin polarized density functional theory
International Nuclear Information System (INIS)
Cardenas, Carlos; Lamsabhi, Al Mokhtar; Fuentealba, Patricio
2006-01-01
In this work, the nuclear reactivity indices of density functional theory have been generalized to the spin polarized case and their relationship to electron spin polarized indices has been established. In particular, the spin polarized version of the nuclear Fukui function has been proposed and a finite difference approximation has been used to evaluate it. Applications to a series of triatomic molecules demonstrate the ability of the new functions to predict the geometrical changes due to a change in the spin multiplicity. The main equations in the different ensembles have also been presented
Order and chaos in the nonlinear response of driven nuclear spin systems
Energy Technology Data Exchange (ETDEWEB)
Brun, E; Derighetti, B; Holzner, R; Ravani, M [Zurich Univ. (Switzerland). Inst. fuer Physik
1984-01-01
The authors report on observations of ordered and chaotic behavior of a nonlinear system of strongly polarized nuclear spins inside the tuning coil of an NMR detector. The combined system: spins plus LC-circuit, may act as a nonlinear bistable absorber or a spin-flip laser, depending on the sign of the nuclear spin polarization. For the NMR laser experimental evidence is presented for limit-cycle behavior, sequences of bifurcations which lead to chaos, intermittency, multistability, and pronounced hysteresis effects. The experimental facts are compared with computer solutions of appropriate Bloch equations for the macroscopic order parameters.
Optical-coupling nuclear spin maser under highly stabilized low static field
Energy Technology Data Exchange (ETDEWEB)
Yoshimi, A., E-mail: yoshimi@ribf.riken.jp [RIKEN Nishina Center (Japan); Inoue, T.; Uchida, M.; Hatakeyama, N.; Asahi, K. [Tokyo Institute of Technology, Department of Physics (Japan)
2008-01-15
A nuclear spin maser of a new type, that employs a feedback scheme based on optical nuclear spin detection, has been fabricated. The spin maser is operated at a low static field of 30 mG by using the optical detection method. The frequency stability and precision of the spin maser have been improved by a highly stabilized current source for the static magnetic field. An experimental setup to search for an electric dipole moment (EDM) in {sup 129}Xe atom is being developed.
Monte Carlo simulation of nuclear spin relaxation in disordered system
International Nuclear Information System (INIS)
Luo, X.; Sholl, C.A.
2002-01-01
Full text: Nuclear spin relaxation is a very useful technique for obtaining information about diffusion in solids. The present work is motivated by relaxation experiments on H diffusing in disordered systems such as metallic glasses or quasicrystalline materials. A theory of the spectral density functions of the magnetic dipolar interactions between diffusing spins is required in order to relate the experimental data to diffusional parameters. In simple ordered systems, the spectral density functions are well understood and a simple BPP (exponential correlation function) model is often used to interpret the data. Diffusion in disordered systems involves a distribution of activation energies and the simple extension of the BPP model that has been used traditionally is of doubtful validity. A more rigorously based BPP model has been developed, and this model has recently been applied to H diffusion in a metal quasicrystal. The improved BPP model still, however, involves approximations and the accuracy of the parameters deduced from it is not clear. The present work involves a Monte Carlo simulation of diffusion in disordered systems and the calculation of the spectral density functions and relaxation rates. The simulations use two algorithms (discrete time and continuous time) for the time-development of the system, and correctly incorporate the Fermi-Dirac distribution for equilibrium occupation of sites, as required by the principle of detailed balance and only single site occupancy of sites. The results are compared with the BPP models for some site- and barrier-energy distributions arising from the structural disorder of the system. The improved BPP model is found to give reasonable values for the diffusion and disorder parameters. Quantitative estimates of the errors involved are determined
Nuclear spin bath effects in molecular nanomagnets: Direct quantum mechanical simulations
Sinitsyn, N. A.; Dobrovitski, V. V.
2004-11-01
We investigate the influence of nuclear spins on the electronic spin tunneling in magnetic molecules such as Fe8 , focusing on the role of the spin diffusion in the nuclear spin bath. We simulate the quantum spin dynamics by numerically solving the time-dependent Schrödinger equation for the compound system (the electronic spin plus the bath spins). Our results demonstrate that the effect of the spin bath cannot always be modeled as a randomly varying magnetic field acting on the electronic spin. We consider two dynamical regimes: the spin relaxation in a constant magnetic field, and the spin tunneling in the linearly varying magnetic field passing the avoided level crossing, so-called Landau-Zener-Stückelberg (LZS) transition. For the first regime, we confirmed that the hole in the magnetization distribution has the width of the hyperfine fields distribution. For the second regime, we found that the transition probability for moderately slow sweeps deviates from the standard LZS prediction, while for the fast sweeps the deviation is negligible.
Boundary between the thermal and statistical polarization regimes in a nuclear spin ensemble
International Nuclear Information System (INIS)
Herzog, B. E.; Cadeddu, D.; Xue, F.; Peddibhotla, P.; Poggio, M.
2014-01-01
As the number of spins in an ensemble is reduced, the statistical fluctuations in its polarization eventually exceed the mean thermal polarization. This transition has now been surpassed in a number of recent nuclear magnetic resonance experiments, which achieve nanometer-scale detection volumes. Here, we measure nanometer-scale ensembles of nuclear spins in a KPF 6 sample using magnetic resonance force microscopy. In particular, we investigate the transition between regimes dominated by thermal and statistical nuclear polarization. The ratio between the two types of polarization provides a measure of the number of spins in the detected ensemble.
The origin of nuclear spin and its effect durning intermediate energy heavy ion collisions
International Nuclear Information System (INIS)
Zhang Guoqiang; Cao Xiguang; Fu Yao; Ma Yugang; Cai Xiangzhou; Wang Hongwei; Fang Deqing; Tian Wendong; Chen Jingen; Guo Wei; Liu Guihua
2010-01-01
We use the heavy-ion phase-space exploration (HIPSE) model to discuss the origin of the nuclear spin and its effect in Intermediate energy nuclear reaction. It is found that the spin of projectile depends on the impact parameter of the reaction system heavily, while on the violence lightly by contrast. Some interesting multifragmentation phenomena related to the spin are shown, especially those of phase transition. At the same time, the role of excited energy for multifragmentation is also invested. We find the later plays a more robust role durning the nuclear disintegration. (authors)
DEFF Research Database (Denmark)
Denning, Emil Vosmar; Iles-Smith, Jake; McCutcheon, Dara P. S.
2017-01-01
Multiphoton entangled states are a crucial resource for many applications inquantum information science. Semiconductor quantum dots offer a promising route to generate such states by mediating photon-photon correlations via a confinedelectron spin, but dephasing caused by the host nuclear spin...... environment typically limits coherence (and hence entanglement) between photons to the spin T2* time of a few nanoseconds. We propose a protocol for the deterministic generation of multiphoton entangled states that is inherently robust against the dominating slow nuclear spin environment fluctuations, meaning...... that coherence and entanglement is instead limited only by the much longer spin T2 time of microseconds. Unlike previous protocols, the present schemeallows for the generation of very low error probability polarisation encoded three-photon GHZ states and larger entangled states, without the need for spin echo...
Photoinduced nuclear spin conversion of methyl groups of single molecules
International Nuclear Information System (INIS)
Sigl, A.
2007-01-01
A methyl group is an outstanding quantum system due to its special symmetry properties. The threefold rotation around one of its bond is isomorphic to the group of even permutations of the remaining protons, a property which imposes severe quantum restrictions on the system, for instance a strict correlation of rotational states with nuclear spin states. The resulting long lifetimes of the rotational tunneling states of the methyl group can be exploited for applying certain high resolution optical techniques, like hole burning or single molecule spectroscopy to optically switch the methyl group from one tunneling state to another therebye changing the nuclear spin of the protons. One goal of the thesis was to perform this switching in single methyl groups. To this end the methyl group was attached to a chromophoric system, in the present case terrylene, which is well suited for single molecule spectroscopy as well as for hole burning. Experiments were performed with the bare terrylene molecule in a hexadecane lattice which served as a reference system, with alphamethyl terrylene and betamethyl terrylene, both embedded in hexadecane, too. A single molecular probe is a highly sensitive detector for dynamic lattice instabilities. Already the bare terrylene probe showed a wealth of interesting local dynamic effects of the hexadecane lattice which could be well acounted for by the assumption of two nearly degenerate sites with rather different optical and thermal properties, all of which could be determined in a quantitative fashion. As to the methylated terrylene systems, the experiments verified that for betamethyl terrylene it is indeed possible to measure rotational tunneling events in single methyl groups. However, the spectral patterns obtained was much more complicated than expected pointing to the presence of three spectroscopically different methyl groups. In order to achieve a definite assignement, molecular mechanics simulations of the terrylene probes in the
High-spin nuclear target of 178m2Hf: creation and nuclear reaction studies
International Nuclear Information System (INIS)
Oganessyan, Yu.Ts.; Karamyan, S.A.; Gangrskij, Yu.P.
1993-01-01
A long-lived (31 years) four-quasiparticle isomer 178m 2 Hf(I,K π =16,16 + ) was produced in microweight quantities using the nuclear reaction 176 Yb( 4 He, 2n). Methods of precision chemistry and mass-separation for the purification of the produced Hf material have been developed. Thin targets of isomeric hafnium-178 on carbon backings were prepared and used in experiments on a neutron, proton and deuteron beams. First results on nuclear reactions on a high-spin exotic target were obtained. Experiments on electromagnetic interactions of the isomeric hafnium using methods of the collinear laser spectroscopy as well as of the nuclear orientation of hafnium implanted into a crystalline media were started. 11 refs.; 11 figs.; 2 tabs
USING MAGNETIC MOMENTS TO UNVEIL THE NUCLEAR STRUCTURE OF LOW-SPIN NUCLEAR STATES
Directory of Open Access Journals (Sweden)
Diego A. Torres
2011-07-01
Full Text Available The experimental study of magnetic moments for nuclear states near the ground state, I ≤ 2, provides a powerful tool to test nuclear structure models. Traditionally, the use of Coulomb excitation reactions has been used to study low spin states, mostly I = 2. The use of alternative reaction channels, such as α transfer, for the production of radioactive species that, otherwise, will be only produced in future radioactive beam facilities has proved to be an alternative to measure not only excited states with I > 2, but to populate and study long-live radioactive nuclei. This contribution will present the experimental tools and challenges for the use of the transient field technique for the measurement of g factors in nuclear states with I ≤ 2, using Coulomb excitation and α-transfer reactions. Recent examples of experimental results near the N = 50 shell closure, and the experimental challenges for future implementations with radioactive beams, will be discussed.
International Nuclear Information System (INIS)
Hassan, M.Y.; Ramadan, S.
1978-01-01
The binding energy of nuclear matter with an excess of neutrons, with spin-up neutrons and spin-up protons (characterized by the corresponding parameters αsub(tau)=(N-Z)/A, αsub(n)=(N(up)-N(down))/A, and αsub(p)=(Z(up)-Z(down))/A) contains three symmetry energies: the isospin symmetry energy epsilon sub(tau), the spin symmetry energy epsilon sub(sigma) and the spin-isospin symmetry energy epsilon sub(sigma tau). These energies are calculated using velocity-dependent effective potential of s-wave interaction, which was developed by Dzhibuti and Mamasakhlisov. The spin, isospin and spin-isospin dependent parts of the single-particle potential in nuclear matter are also calculated using the same effective nucleon-nucleon potentials. The spin-spin part of the optical model potential is estimated. (author)
Carbon-13 Labeling Used to Probe Cure and Degradation Reactions of High- Temperature Polymers
Meador, Mary Ann B.; Johnston, J. Christopher
1998-01-01
High-temperature, crosslinked polyimides are typically insoluble, intractible materials. Consequently, in these systems it has been difficult to follow high-temperature curing or long-term degradation reactions on a molecular level. Selective labeling of the polymers with carbon-13, coupled with solid nuclear magnetic resonance spectrometry (NMR), enables these reactions to be followed. We successfully employed this technique to provide insight into both curing and degradation reactions of PMR-15, a polymer matrix resin used extensively in aircraft engine applications.
Energy Technology Data Exchange (ETDEWEB)
Cho, Herman M.; Washton, Nancy M.; Mueller, Karl T.; Sears, Jr., Jesse A.; Townsend, Mark R.; Ewing, James R.
2016-06-14
A magic-angle-spinning (MAS) nuclear magnetic resonance (NMR) probe is described that includes double containment enclosures configured to seal and contain hazardous samples for analysis. The probe is of a modular design that ensures containment of hazardous samples during sample analysis while preserving spin speeds for superior NMR performance and convenience of operation.
The determination of the in situ structure by nuclear spin contrast variation
Energy Technology Data Exchange (ETDEWEB)
Stuhrmann, H.B. [GKSS Forschungszentrum, Geesthacht (Germany); Nierhaus, K.H. [Max-Planch-Institut fuer Molekulare Genetik, Berlin (Germany)
1994-12-31
Polarized neutron scattering from polarized nuclear spins in hydrogenous substances opens a new way of contrast variation. The enhanced contrast due to proton spin polarization was used for the in situ structure determination of tRNA of the functional complex of the E.coli ribosome.
Dynamical nuclear spin polarization induced by electronic current through double quantum dots
International Nuclear Information System (INIS)
Lopez-Monis, Carlos; Platero, Gloria; Inarrea, Jesus
2011-01-01
We analyse electron-spin relaxation in electronic transport through coherently coupled double quantum dots (DQDs) in the spin blockade regime. In particular, we focus on hyperfine (HF) interaction as the spin-relaxation mechanism. We pay special attention to the effect of the dynamical nuclear spin polarization induced by the electronic current on the nuclear environment. We discuss the behaviour of the electronic current and the induced nuclear spin polarization versus an external magnetic field for different HF coupling intensities and interdot tunnelling strengths. We take into account, for each magnetic field, all HF-mediated spin-relaxation processes coming from different opposite spin level approaches. We find that the current as a function of the external magnetic field shows a peak or a dip and that the transition from a current dip to a current peak behaviour is obtained by decreasing the HF coupling or by increasing the interdot tunnelling strength. We give a physical picture in terms of the interplay between the electrons tunnelling out of the DQD and the spin-flip processes due to the nuclear environment.
Energy Technology Data Exchange (ETDEWEB)
Berman, Gennady P [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Bishop, Alan R [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Chernobrod, Boris M [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Hawley, Marilyn E [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Brown, Geoffrey W [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Tsifrinovich, Vladimir I [Polytechnic University, Brooklyn, NY 11201 (United States)
2006-05-15
A novel approach for measurement of single electron and nuclear spin states is suggested. Our approach is based on optically detected magnetic resonance in a nano-probe located at the apex of an AFM tip. The method provides single electron spin sensitivity with nano-scale spatial resolution.
International Nuclear Information System (INIS)
Berman, Gennady P; Bishop, Alan R; Chernobrod, Boris M; Hawley, Marilyn E; Brown, Geoffrey W; Tsifrinovich, Vladimir I
2006-01-01
A novel approach for measurement of single electron and nuclear spin states is suggested. Our approach is based on optically detected magnetic resonance in a nano-probe located at the apex of an AFM tip. The method provides single electron spin sensitivity with nano-scale spatial resolution
The determination of the in situ structure by nuclear spin contrast variation
International Nuclear Information System (INIS)
Stuhrmann, H.B.; Nierhaus, K.H.
1994-01-01
Polarized neutron scattering from polarized nuclear spins in hydrogenous substances opens a new way of contrast variation. The enhanced contrast due to proton spin polarization was used for the in situ structure determination of tRNA of the functional complex of the E.coli ribosome
International Nuclear Information System (INIS)
Sarmento, E.F.
1981-01-01
Results are found for the dynamical correlation functions (or its corresponding Green's functions) among any combination including operator pairs of electronic and nuclear spins in an antiferromagnet semi-infinite medium, at low temperatures T [pt
The 40th anniversary of the discovery of NMR-chemical shift and nuclear spin-spin coupling
International Nuclear Information System (INIS)
Zhu Zhenghe; Gou Qingquan
1989-01-01
After the discovery of NMR Phenomenon in the physics laboratories of E.M.Purcell at Harvard and F.Bloch at Stanford in 1946, W.G.Proctor and F.C.Yu made the successful discovery of NMR-chemical shift and nuclear spin-spin coupling at Stanford in 1950, Which brought NMR spectroscopy from the physics laboratory to the laboratories of many different fields. This is worth memorizing. Retrospecting the past 40 years, it is sure that chemical shift theory will be much more prosperous prospects
External magnetic field induced anomalies of spin nuclear dynamics in thin antiferromagnetic films
International Nuclear Information System (INIS)
Tarasenko, S.V.
1995-01-01
It is shown that if the thickness of homogeneously magnetized plate of high-axial antiferromagnetic within H external magnetic field becomes lower the critical one, then the effect of dynamic magnetoelastic interaction on Soul-Nakamura exchange of nuclear spins results in formation of qualitatively new types of spreading nuclear spin waves no else compared neither within the model of unrestricted magnetic nor at H = 0 in case of thin plate of high-axial antiferromagnetic. 10 refs
Nuclear spin of 185Au and hyperfine structure of 188Au
International Nuclear Information System (INIS)
Ekstroem, C.; Ingelman, S.; Wannberg, G.
1977-03-01
The nuclear spin of 185 Au, I = 5/2, and the hyperfine separation of 188 Au, Δγ = +- 2992(30) MHz, have been measured with the atomic-beam magnetic resonance method. The spin of 185 Au indicates a deformed nuclear shape in the ground state. The small magnetic moment of 188 Au is close in value to those of the heavier I = 1 gold isotopes 190 192 194 Au, being located in a typical transition region. (Auth.)
All-electric control of donor nuclear spin qubits in silicon
Sigillito, Anthony J.; Tyryshkin, Alexei M.; Schenkel, Thomas; Houck, Andrew A.; Lyon, Stephen A.
2017-10-01
The electronic and nuclear spin degrees of freedom of donor impurities in silicon form ultra-coherent two-level systems that are potentially useful for applications in quantum information and are intrinsically compatible with industrial semiconductor processing. However, because of their smaller gyromagnetic ratios, nuclear spins are more difficult to manipulate than electron spins and are often considered too slow for quantum information processing. Moreover, although alternating current magnetic fields are the most natural choice to drive spin transitions and implement quantum gates, they are difficult to confine spatially to the level of a single donor, thus requiring alternative approaches. In recent years, schemes for all-electrical control of donor spin qubits have been proposed but no experimental demonstrations have been reported yet. Here, we demonstrate a scalable all-electric method for controlling neutral 31P and 75As donor nuclear spins in silicon. Using coplanar photonic bandgap resonators, we drive Rabi oscillations on nuclear spins exclusively using electric fields by employing the donor-bound electron as a quantum transducer, much in the spirit of recent works with single-molecule magnets. The electric field confinement leads to major advantages such as low power requirements, higher qubit densities and faster gate times. Additionally, this approach makes it possible to drive nuclear spin qubits either at their resonance frequency or at its first subharmonic, thus reducing device bandwidth requirements. Double quantum transitions can be driven as well, providing easy access to the full computational manifold of our system and making it convenient to implement nuclear spin-based qudits using 75As donors.
Search for electric dipole moment in 129Xe atom using active nuclear spin maser
Directory of Open Access Journals (Sweden)
Ichikawa Y.
2014-03-01
Full Text Available An experimental search for an electric dipole moment in the diamagnetic atom 129Xe is in progress through the precision measurement of spin precession frequency using an active nuclear spin maser. A 3He comagnetometer has been incorporated into the active spin maser system in order to cancel out the long-term drifts in the external magnetic field. Also, a double-cell geometry has been adopted in order to suppress the frequency shifts due to interaction with polarized Rb atoms. The first EDM measurement with the 129Xe active spin maser and the 3He comagnetometer has been conducted.
Tensor quasiparticle interaction and spin-isospin sound in nuclear matter
International Nuclear Information System (INIS)
Haensel, P.
1979-01-01
The effect of the tensor components of the quasiparticle interaction in nuclear matter on the spin-isospin sound type excitations is studied. Numerical results are obtained using a simplified model of the quasiparticle interaction in nuclear matter. The quasiparticle distribution matrix corresponding to the spin-isospin sound is found to be qualitatively different from that obtained for purely central quasiparticle interaction. The macroscopic effects, however, are restricted to a small change in the phase velocity of the spin-isospin sound. (Auth.)
Nuclear and hadronic reaction mechanisms producing spin asymmetry
Indian Academy of Sciences (India)
We brieﬂy review concept of the quark recombination (QRC) model and a general success of the model. To solve the existing problem, so called anomalous spin observables, in the high energy hyperon spin phenomena, we propose a mechanism; the primarily produced quarks, which are predominantly and quarks, ...
Nuclear and hadronic reaction mechanisms producing spin asymmetry
Indian Academy of Sciences (India)
naka
are predominantly u and d quarks, act as the leading partons to form the hyperons. Extension of the quark recombination concept with this mechanism is successful in providing a good account of the anomalous spin observables. Another kind of anomaly, the non-zero analysing power and spin depolarization in the A ...
Ramachandran, R.; Narasimhan, P. T.
The results of theoretical and experimental studies of Zeeman-perturbed nuclear quadrupole spin echo envelope modulations (ZSEEM) for spin 3/2 nuclei in polycrystalline specimens are presented. The response of the Zeeman-perturbed spin ensemble to resonant two pulse excitations has been calculated using the density matrix formalism. The theoretical calculation assumes a parallel orientation of the external r.f. and static Zeeman fields and an arbitrary orientation of these fields to the principal axes system of the electric field gradient. A numerical powder averaging procedure has been adopted to simulate the response of the polycrystalline specimens. Using a coherent pulsed nuclear quadrupole resonance spectrometer the ZSEEM patterns of the 35Cl nuclei have been recorded in polycrystalline specimens of potassium chlorate, barium chlorate, mercuric chloride (two sites) and antimony trichloride (two sites) using the π/2-τ-π/2 sequence. The theoretical and experimental ZSEEM patterns have been compared. In the case of mercuric chloride, the experimental 35Cl ZSEEM patterns are found to be nearly identical for the two sites and correspond to a near-zero value of the asymmetry parameter, η, of the electric field gradient tensor. The difference in the η values for the two 35Cl sites (η ˜0·06 and η˜0·16) in antimony trichloride is clearly reflected in the experimental and theoretical ZSEEM patterns. The present study indicates the feasibility of evaluating η for spin 3/2 nuclei in polycrystalline specimens from ZSEEM investigations.
Noise-Resilient Quantum Computing with a Nitrogen-Vacancy Center and Nuclear Spins.
Casanova, J; Wang, Z-Y; Plenio, M B
2016-09-23
Selective control of qubits in a quantum register for the purposes of quantum information processing represents a critical challenge for dense spin ensembles in solid-state systems. Here we present a protocol that achieves a complete set of selective electron-nuclear gates and single nuclear rotations in such an ensemble in diamond facilitated by a nearby nitrogen-vacancy (NV) center. The protocol suppresses internuclear interactions as well as unwanted coupling between the NV center and other spins of the ensemble to achieve quantum gate fidelities well exceeding 99%. Notably, our method can be applied to weakly coupled, distant spins representing a scalable procedure that exploits the exceptional properties of nuclear spins in diamond as robust quantum memories.
Multitudes of Stable States in a Periodically Driven Electron-Nuclear Spin System in a Quantum Dot
Korenev, V. L.
2010-01-01
The periodical modulation of circularly polarized light with a frequency close to the electron spin resonance frequency induces a sharp change of the single electron spin orientation. Hyperfine interaction provides a feedback, thus fixing the precession frequency of the electron spin in the external and the Overhauser field near the modulation frequency. The nuclear polarization is bidirectional and the electron-nuclear spin system (ENSS) possesses a few stable states. A similar frequency-loc...
Synthesis of carbon-13 and carbon-14 labeled paldimycin tri-sodium salt
International Nuclear Information System (INIS)
Hsi, R.S.P.; Witz, D.F.; Visser, J.; Stolle, W.T.; Ditto, C.L.
1989-01-01
Carbon-14 labeled paldimycin trisodium salt was prepared by addition of N-acetyl-L-cysteine to [ 14 C]paulomycin, the radioactive antibiotic produced by fermentation of Streptomyces paulus in the presence of L-methionine labeled with carbon-14 in the S-methyl group. Carbon-13 nuclear magnetic resonance (NMR) spectra of paulomycin produced when the fermentation was carried out in the presence of L-[S-methyl- 13 C]methionine showed that the isotope incorporation had occurred specifically at the methoxy group of ring C, i.e., the 2-deoxy sugar portion of paulomycin. With sustained slow feed of labeled precursors during the optimum antibiotic production period, carbon-14 isotope yields of up to 17.5% with specific activity of up to 11.4 μCi per milligram of paulomycin, and carbon-13 isotope yields of up to 24% with 17-fold isotope enrichment over natural abundance, were achieved. (author)
Schemes of detecting nuclear spin correlations by dynamical decoupling based quantum sensing
Ma, Wen-Long Ma; Liu, Ren-Bao
Single-molecule sensitivity of nuclear magnetic resonance (NMR) and angstrom resolution of magnetic resonance imaging (MRI) are the highest challenges in magnetic microscopy. Recent development in dynamical decoupling (DD) enhanced diamond quantum sensing has enabled NMR of single nuclear spins and nanoscale NMR. Similar to conventional NMR and MRI, current DD-based quantum sensing utilizes the frequency fingerprints of target nuclear spins. Such schemes, however, cannot resolve different nuclear spins that have the same noise frequency or differentiate different types of correlations in nuclear spin clusters. Here we show that the first limitation can be overcome by using wavefunction fingerprints of target nuclear spins, which is much more sensitive than the ''frequency fingerprints'' to weak hyperfine interaction between the targets and a sensor, while the second one can be overcome by a new design of two-dimensional DD sequences composed of two sets of periodic DD sequences with different periods, which can be independently set to match two different transition frequencies. Our schemes not only offer an approach to breaking the resolution limit set by ''frequency gradients'' in conventional MRI, but also provide a standard approach to correlation spectroscopy for single-molecule NMR.
Nuclear spin-orbit splitting from an intermediate Δ excitation
International Nuclear Information System (INIS)
Ohta, K.; Terasawa, T.; Tohyama, M.
1980-01-01
The strength of the single particle spin-orbit potential is calculated from the two pion exchange box diagrams involving an intermediate Δ(1232) resonance excitation by taking account of the exclusion principle for the intermediate nucleon states. The effect of the rho meson is also considered. The predicted strength is found to account for a substantial part of the empirical spin-orbit splittings
International Nuclear Information System (INIS)
Thurber, Kent R.; Tycko, Robert
2014-01-01
We report solid state 13 C and 1 H nuclear magnetic resonance (NMR) experiments with magic-angle spinning (MAS) on frozen solutions containing nitroxide-based paramagnetic dopants that indicate significant perturbations of nuclear spin polarizations without microwave irradiation. At temperatures near 25 K, 1 H and cross-polarized 13 C NMR signals from 15 N, 13 C-labeled L-alanine in trinitroxide-doped glycerol/water are reduced by factors as large as six compared to signals from samples without nitroxide doping. Without MAS or at temperatures near 100 K, differences between signals with and without nitroxide doping are much smaller. We attribute most of the reduction of NMR signals under MAS near 25 K to nuclear spin depolarization through the cross-effect dynamic nuclear polarization mechanism, in which three-spin flips drive nuclear polarizations toward equilibrium with spin polarization differences between electron pairs. When T 1e is sufficiently long relative to the MAS rotation period, the distribution of electron spin polarization across the nitroxide electron paramagnetic resonance lineshape can be very different from the corresponding distribution in a static sample at thermal equilibrium, leading to the observed effects. We describe three-spin and 3000-spin calculations that qualitatively reproduce the experimental observations
Thurber, Kent R; Tycko, Robert
2014-05-14
We report solid state (13)C and (1)H nuclear magnetic resonance (NMR) experiments with magic-angle spinning (MAS) on frozen solutions containing nitroxide-based paramagnetic dopants that indicate significant perturbations of nuclear spin polarizations without microwave irradiation. At temperatures near 25 K, (1)H and cross-polarized (13)C NMR signals from (15)N,(13)C-labeled L-alanine in trinitroxide-doped glycerol/water are reduced by factors as large as six compared to signals from samples without nitroxide doping. Without MAS or at temperatures near 100 K, differences between signals with and without nitroxide doping are much smaller. We attribute most of the reduction of NMR signals under MAS near 25 K to nuclear spin depolarization through the cross-effect dynamic nuclear polarization mechanism, in which three-spin flips drive nuclear polarizations toward equilibrium with spin polarization differences between electron pairs. When T1e is sufficiently long relative to the MAS rotation period, the distribution of electron spin polarization across the nitroxide electron paramagnetic resonance lineshape can be very different from the corresponding distribution in a static sample at thermal equilibrium, leading to the observed effects. We describe three-spin and 3000-spin calculations that qualitatively reproduce the experimental observations.
Energy Technology Data Exchange (ETDEWEB)
Thurber, Kent R., E-mail: thurberk@niddk.nih.gov; Tycko, Robert [Laboratory of Chemical Physics, National Institute of Diabetes and Digestive and Kidney Diseases, National Institutes of Health, Bethesda, Maryland 20892-0520 (United States)
2014-05-14
We report solid state {sup 13}C and {sup 1}H nuclear magnetic resonance (NMR) experiments with magic-angle spinning (MAS) on frozen solutions containing nitroxide-based paramagnetic dopants that indicate significant perturbations of nuclear spin polarizations without microwave irradiation. At temperatures near 25 K, {sup 1}H and cross-polarized {sup 13}C NMR signals from {sup 15}N,{sup 13}C-labeled L-alanine in trinitroxide-doped glycerol/water are reduced by factors as large as six compared to signals from samples without nitroxide doping. Without MAS or at temperatures near 100 K, differences between signals with and without nitroxide doping are much smaller. We attribute most of the reduction of NMR signals under MAS near 25 K to nuclear spin depolarization through the cross-effect dynamic nuclear polarization mechanism, in which three-spin flips drive nuclear polarizations toward equilibrium with spin polarization differences between electron pairs. When T{sub 1e} is sufficiently long relative to the MAS rotation period, the distribution of electron spin polarization across the nitroxide electron paramagnetic resonance lineshape can be very different from the corresponding distribution in a static sample at thermal equilibrium, leading to the observed effects. We describe three-spin and 3000-spin calculations that qualitatively reproduce the experimental observations.
All-optical control of long-lived nuclear spins in rare-earth doped nanoparticles.
Serrano, D; Karlsson, J; Fossati, A; Ferrier, A; Goldner, P
2018-05-29
Nanoscale systems that coherently couple to light and possess spins offer key capabilities for quantum technologies. However, an outstanding challenge is to preserve properties, and especially optical and spin coherence lifetimes, at the nanoscale. Here, we report optically controlled nuclear spins with long coherence lifetimes (T 2 ) in rare-earth-doped nanoparticles. We detect spins echoes and measure a spin coherence lifetime of 2.9 ± 0.3 ms at 5 K under an external magnetic field of 9 mT, a T 2 value comparable to those obtained in bulk rare-earth crystals. Moreover, we achieve spin T 2 extension using all-optical spin dynamical decoupling and observe high fidelity between excitation and echo phases. Rare-earth-doped nanoparticles are thus the only nano-material in which optically controlled spins with millisecond coherence lifetimes have been reported. These results open the way to providing quantum light-atom-spin interfaces with long storage time within hybrid architectures.
Teiji, KUNIHIRO; Tatsuyuki, TAKATSUKA; Ryozo, TAMAGAKI; Department of National Sciences, Ryukoku University; College of Humanities and Social Sciences, Iwate University; Department of Physics, Kyoto University
1985-01-01
Pion condensation in the symmetric nuclear matter is investigated on the basis of the ALS (alternating-layer-spin) model which provides a good description for the π^0 condensation. We perform energy calculations in a realistic way where the isobar (Δ)-mixing, the short range effects and the exchange energy of the interaction are taken into account. The Δ-mixing effect is built in the model state as previously done in the neutron matter. We preferentially employ G-0 force of Sprung and Banerje...
Solid-state nuclear-spin quantum computer based on magnetic resonance force microscopy
International Nuclear Information System (INIS)
Berman, G. P.; Doolen, G. D.; Hammel, P. C.; Tsifrinovich, V. I.
2000-01-01
We propose a nuclear-spin quantum computer based on magnetic resonance force microscopy (MRFM). It is shown that an MRFM single-electron spin measurement provides three essential requirements for quantum computation in solids: (a) preparation of the ground state, (b) one- and two-qubit quantum logic gates, and (c) a measurement of the final state. The proposed quantum computer can operate at temperatures up to 1 K. (c) 2000 The American Physical Society
Chip-Scale Combinatorial Atomic Navigator (C-SCAN) Low Drift Nuclear Spin Gyroscope
2018-01-01
suggestions for reducing this burden, to Department of Defense, Washington Headquarters Services, Directorate for Information Operations and Reports (0704...spin-exchange relaxation in a finite magnetic field. We operated the gyroscope using a Ramsey-type interrogation sequence with nuclear spin precession...shift by a factor of 105. Here we use the approach of a Ramsey clock interrogation scheme, where the optical pumping, free evolution, and measurement
The MONSTER solves nuclear structure problems at low and high spins
International Nuclear Information System (INIS)
Hammaren, E.; Schmid, K.W.; Gruemmer, F.
1984-01-01
A microscopic, particle-number and spin conserving nuclear structure model is discussed. Within a unique theory the model can describe excitation energies, moments, transitions and spectroscopic factors at low and high spins of odd-mass and doubly-even nuclei in all mass regions. With a realistic two-body Hamiltonian extracted via a G-matric description from nucleon-nucleon scattering data. The model is here applied to nuclei in the A=130 region
RPA spin-isospin nuclear response in the deep inelastic region
International Nuclear Information System (INIS)
Alberico, W.M.; Molinari, A.; De Pace, A.; Johnson, M.B.; Ericson, M.
1985-11-01
The spin-isospin volume responses of a finite nucleus are evaluated in the RPA frame, utilizing a harmonic oscillator basis. Particular emphasis is given to the mixing between the longitudinal and transverse couplings, which arise at the nuclear surface. We show that it reduces somewhat the contrast between the two spin responses. We compare the calculated transverse response with the experimental one extracted from deep inelastic electron scattering
{beta}-Ray angular distribution from purely nuclear spin aligned {sup 20}F
Energy Technology Data Exchange (ETDEWEB)
Nagatomo, T., E-mail: nagatomo@riken.jp [RIKEN Nishina Center (Japan); Matsuta, K. [Osaka University (Japan); Minamisono, K. [NSCL/MSU (United States); Sumikama, T. [Tokyo University of Science (Japan); Mihara, M. [Osaka University (Japan); Ozawa, A.; Tagishi, Y. [University of Tsukuba (Japan); Ogura, M.; Matsumiya, R.; Fukuda, M. [Osaka University (Japan); Yamaguchi, M.; Yasuno, T.; Ohta, H.; Hashizume, Y. [University of Tsukuba (Japan); Fujiwara, H. [Osaka University (Japan); Chiba, A. [University of Tsukuba (Japan); Minamisono, T. [Fukui University of Technology (Japan)
2007-11-15
The alignment correlation term in the {beta}-ray angular distribution from purely nuclear spin aligned {sup 20}F has been measured to test the G-parity conservation law which is one of the fundamental symmetries in the weak nucleon current. We utilized the hyperfine interaction of {sup 20}F in an MgF{sub 2} single crystal and successfully created the pure alignment from the polarization by means of the spin manipulation technique based on the {beta}-NMR method.
International Nuclear Information System (INIS)
Hoodbhoy, P.; Massachusetts Inst. of Tech., Cambridge; Quaid-i-Azam Univ., Islamabad
1990-01-01
Inclusive photo-production from polarized targets of arbitrary spin is analyzed by using multipoles. The Drell-Hearn-Gerasimov sum rule, which was originally fromulated for spin-1/2 targets, is generalized to all spins and multipoles, and shown to have some interesting consequences. Measurements to test the new rules, or to derive nuclear structure information from them, could be incorporated into existing plans at electron accelerator facilities. Finally, the possible relevance of these generalized sum rules to sum rules measurable in polarized lepton-polarized target deep inelastic inclusive scattering is discussed. (orig.)
Optical Pumping of the Electronic and Nuclear Spin of Single Charge-Tunable Quantum Dots
Bracker, A. S.; Stinaff, E. A.; Gammon, D.; Ware, M. E.; Tischler, J. G.; Shabaev, A.; Efros, Al. L.; Park, D.; Gershoni, D.; Korenev, V. L.; Merkulov, I. A.
2005-02-01
We present a comprehensive examination of optical pumping of spins in individual GaAs quantum dots as we change the net charge from positive to neutral to negative with a charge-tunable heterostructure. Negative photoluminescence polarization memory is enhanced by optical pumping of ground state electron spins, which we prove with the first measurements of the Hanle effect on an individual quantum dot. We use the Overhauser effect in a high longitudinal magnetic field to demonstrate efficient optical pumping of nuclear spins for all three charge states of the quantum dot.
Origin of the finite nuclear spin and its effect in intermediate energy heavy ion collisions
International Nuclear Information System (INIS)
Zhang Guoqiang; Cao Xiguang; Fu Yao
2012-01-01
The heavy-ion phase-space exploration (HIPSE) model is used to discuss the origin of the nuclear spin in intermediate energy heavy-ion collision (HIC). The spin of maximal projectile-like fragment is found to depend strongly on impact parameter of a reaction system,while it relates weakly to the collision violence. Some interesting multi-fragmentation phenomena related to the spin are shown. We also found that the excitation energy in the de-excitation stage plays a robust role at the de-excitation stage in HIC. (authors)
DEFF Research Database (Denmark)
Faber, Rasmus; Sauer, Stephan P. A.
2018-01-01
The basis set convergence of nuclear spin-spin coupling constants (SSCC) calculated at the coupled cluster singles and doubles (CCSD) level has been investigated for ten difficult molecules. Eight of the molecules contain fluorine atoms and nine contain double or triple bonds. Results obtained...
DEFF Research Database (Denmark)
Enevoldsen, Thomas; Oddershede, Jens; Sauer, Stephan P. A.
1998-01-01
We present correlated calculations of the indirect nuclear spin-spin coupling constants of HD, HF, H2O, CH4, C2H2, BH, AlH, CO and N2 at the level of the second-order polarization propagator approximation (SOPPA) and the second-order polarization propagator approximation with coupled-cluster sing...
International Nuclear Information System (INIS)
Hassan, M.Y.M.; Ramadan, S.
1983-11-01
The binding energy of nuclear matter with an excess of neutrons, of spin-up neutrons, and of spin-up protons (characterized by the corresponding parameters, αsub(tau)=(N-Z/A), αsub(n)=(Nup-Ndown)/A, and αsub(rho)=(Zup-Zdown)/A), contains three symmetry energies: the isospin symmetry energy Esub(tau), the spin symmetry energy Esub(σ), and spin-isospin symmetry energy Esub(σtau). General expressions for Esub(σ), Esub(tau) and Esub(σtau) are given in the case of the Skyrme interaction. These values are compared with previous results obtained by Dabrowski and Haensel (DH) with Brueckner-Gammel-Thaler, the Hamada-Johnston, and the Reid soft core nucleon-nucleon potentials. The spin, isospin and spin-isospin dependent parts of the single-particle potential in nuclear matter are also calculated using the Skyrme interaction. The spin, isospin and spin-isospin incompressibility are calculated using the Skyrme interaction. The spin-spin part of the optical model potential is estimated. The results are compared with those of Dabrowski and Haensel (DH) and Hassan and Ramadan. (author)
Anomalous longitudinal relaxation of nuclear spins in CaF{sub 2}
Energy Technology Data Exchange (ETDEWEB)
Kropf, Chahan M. [Institute of Physics, University of Freiburg, Hermann-Herder-Str. 3, D-79104, Freiburg (Germany); Kohlrautz, Jonas; Haase, Juergen [University of Leipzig, Faculty of Physics and Earth Sciences, Linnestr. 5, 04103, Leipzig (Germany); Fine, Boris V. [Skolkovo Institute of Science and Technology, 100 Novaya Str., Skolkovo, Moscow Region, 143025 (Russian Federation); Institute for Theoretical Physics, University of Heidelberg, Philosophenweg 12, 69120, Heidelberg (Germany)
2017-06-15
We consider the effect of non-secular resonances for interacting nuclear spins in solids which were predicted theoretically to exist in the presence of strong static and strong radio-frequency magnetic fields. These resonances imply corrections to the standard secular approximation for the nuclear spin-spin interaction in solids, which, in turn, should lead to an anomalous longitudinal relaxation in nuclear magnetic resonance experiments. In this article, we investigate the feasibility of the experimental observation of this anomalous longitudinal relaxation in calcium fluoride (CaF{sub 2}) and conclude that such an observation is realistic. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Thurber, Kent R; Tycko, Robert
2012-08-28
We present theoretical calculations of dynamic nuclear polarization (DNP) due to the cross effect in nuclear magnetic resonance under magic-angle spinning (MAS). Using a three-spin model (two electrons and one nucleus), cross effect DNP with MAS for electron spins with a large g-anisotropy can be seen as a series of spin transitions at avoided crossings of the energy levels, with varying degrees of adiabaticity. If the electron spin-lattice relaxation time T(1e) is large relative to the MAS rotation period, the cross effect can happen as two separate events: (i) partial saturation of one electron spin by the applied microwaves as one electron spin resonance (ESR) frequency crosses the microwave frequency and (ii) flip of all three spins, when the difference of the two ESR frequencies crosses the nuclear frequency, which transfers polarization to the nuclear spin if the two electron spins have different polarizations. In addition, adiabatic level crossings at which the two ESR frequencies become equal serve to maintain non-uniform saturation across the ESR line. We present analytical results based on the Landau-Zener theory of adiabatic transitions, as well as numerical quantum mechanical calculations for the evolution of the time-dependent three-spin system. These calculations provide insight into the dependence of cross effect DNP on various experimental parameters, including MAS frequency, microwave field strength, spin relaxation rates, hyperfine and electron-electron dipole coupling strengths, and the nature of the biradical dopants.
Multiple-Quantum Transitions and Charge-Induced Decoherence of Donor Nuclear Spins in Silicon
Franke, David P.; Pflüger, Moritz P. D.; Itoh, Kohei M.; Brandt, Martin S.
2017-06-01
We study single- and multiquantum transitions of the nuclear spins of an ensemble of ionized arsenic donors in silicon and find quadrupolar effects on the coherence times, which we link to fluctuating electrical field gradients present after the application of light and bias voltage pulses. To determine the coherence times of superpositions of all orders in the 4-dimensional Hilbert space, we use a phase-cycling technique and find that, when electrical effects were allowed to decay, these times scale as expected for a fieldlike decoherence mechanism such as the interaction with surrounding Si 29 nuclear spins.
Heisterkamp, F.; Greilich, A.; Zhukov, E. A.; Kirstein, E.; Kazimierczuk, T.; Korenev, V. L.; Yugova, I. A.; Yakovlev, D. R.; Pawlis, A.; Bayer, M.
2015-12-01
Optically induced nuclear spin polarization in a fluorine-doped ZnSe epilayer is studied by time-resolved Kerr rotation using resonant excitation of donor-bound excitons. Excitation with helicity-modulated laser pulses results in a transverse nuclear spin polarization, which is detected as a change of the Larmor precession frequency of the donor-bound electron spins. The frequency shift in dependence on the transverse magnetic field exhibits a pronounced dispersion-like shape with resonances at the fields of nuclear magnetic resonance of the constituent zinc and selenium isotopes. It is studied as a function of external parameters, particularly of constant and radio frequency external magnetic fields. The width of the resonance and its shape indicate a strong spatial inhomogeneity of the nuclear spin polarization in the vicinity of a fluorine donor. A mechanism of optically induced nuclear spin polarization is suggested based on the concept of resonant nuclear spin cooling driven by the inhomogeneous Knight field of the donor-bound electron.
Carbon magnetic resonance spectroscopy on carbon-13-labeled uracil in 5S ribonucleic acid
International Nuclear Information System (INIS)
Hamill, W.D.; Grant, D.M.; Cooper, R.B.; Harmon, S.A.
1978-01-01
The carbon-13 nuclear magnetic resonance spectra of the 13 C-enriched C-4 uridine carbons in 5S ribosomal ribonucleic acid of Salmonella typhimurium, strain JL-1055, was obtained. The most striking feature of the 5S RNA spectrum was the large number of well-resolved lines in the uridine band covering a chemical shift range of approximately 3.6 ppM. This data was used to obtain information on the secondary structure. The number of uridines involved in secondary interactions is estimated to be at least 75% and may be as high as 95%
Nuclear spin relaxation in a spin-1/2 antiferromagnetic Heisenberg chain at high fields
International Nuclear Information System (INIS)
Lyo, S.K.
1981-01-01
The proton spin relaxation rate is calculated in the one-dimensional spin-1/2 Heisenberg antiferromagnet α-bis (N-methylsalicylaldiminato)-copper (II), α-CuNSal by using a fermion representation for magnons above the critical field where the magnon spectrum develops a gap. The one-magnon process which is dominant below the critical field is shown to be absent in the presence of a gap in contrast to a previous theory. Instead, we find that the three-magnon rate is large enough to explain the data at low fields. The two-magnon off-resonance damping which enters the expression for the three-magnon rate is calculated by solving the two-magnon scattering exactly, leading to a much smaller value of the rate than that predicted by the Born approximation. Also, in an unsuccessful attempt to resolve the discrepancy between the recently calculated two-magnon rate (dominant at high fields) and the data of α-CuNSal reported by Azevedo et al., we carry out the vertex correction for the spin-density correlation function by summing the RPA series as well as the exchange ladders for the polarization part. We find that, although the exchange enhancement is significantly large, it is nearly canceled out by the RPA correction, and the net effect of the vertex correction is small. This result agrees with the recent data of the similar spin-1/2 antiferromagnetic Heisenberg chain system CuSO 4 x5H 2 O reported by Groen et al. On the other hand, it disagrees with a recent calculation of the two-magnon rate based on a boson representation of spins. To resolve this discrepancy we examine the effect of the boson self-energy correction on the two-magnon rate. The boson spectral shift is found to be quite large in the region where the cited two-boson rate deviates from the two-fermion rate. As a result the two-boson rate is significantly reduced, leading to reasonable agreement with the two-fermion rate
Experimental status of the nuclear spin scissors mode
Balbutsev, E. B.; Molodtsova, I. V.; Schuck, P.
2018-04-01
With the Wigner function moments (WFM) method the scissors mode of the actinides and rare earth nuclei are investigated. The unexplained experimental fact that in 232Th a double hump structure is found finds a natural explanation within WFM. It is predicted that the lower peak corresponds to an isovector spin scissors mode whereas the higher-lying states corresponds to the conventional isovector orbital scissors mode. The experimental situation is scrutinized in this respect concerning practically all results of M 1 excitations.
Canadian experience with spin-offs from nuclear technology
International Nuclear Information System (INIS)
Lennox, C.G.; Garvey, P.M.
1989-01-01
The innovation process introduced into AECL's research laboratories is described, with its achievements in increased commercial and spin-off businesses. In particular, the role of the champion or entrepreneur is emphasized in the manner in which he/she interacts within a dedicated team to pursue each opportunity. Examples are provided of several commercial and business development opportunities resulting from the background research programs
International Nuclear Information System (INIS)
Oliveira, Joao Paulo Cavalcante; Mota, F. de Brito; Rivelino, Roberto
2011-01-01
Full text. Carbon nano wires made of long linear atomic chains have attracted considerable interest due to their potential applications in nano electronics. We report a density-functional-theory study of the nuclear spin-spin coupling constants for nano assemblies made of two coronene molecules bridged by carbon linear chains, considering distinct sizes and spin multiplicities. Also, we examine the effects of two terminal conformations (syn and anti) of the terminal anchor pieces on the magnetic properties of the carbon chains via 13 C NMR calculations. Our results reveal that simplified chemical models such as those based on cumulenes or polyynes are not appropriate to describe the linear chains with sp 2 terminations. For these types of atomic chains, the electronic ground state of the even-numbered chains can be singlet or triplet, whereas the ground state of the odd-numbered chains can be doublet or quartet. We discuss how the 13 C NMR chemical shift absorption is affected by increasing the size and changing the parity of the linear carbon chains. We have found that the J coupling constants between the carbon atoms in the linear chains present a well-defined pattern, in good accordance with our electronic structure calculations. For example, in the -C 4 - units we obtain couplings of 43.8, 114.5, 84.6, 114.5, and 43.8 Hz from one end to the other
International Nuclear Information System (INIS)
Repisky, Michal; Komorovsky, Stanislav; Malkina, Olga L.; Malkin, Vladimir G.
2009-01-01
The relativistic four-component density functional approach based on the use of restricted magnetically balanced basis (mDKS-RMB), applied recently for calculations of NMR shielding, was extended for calculations of NMR indirect nuclear spin-spin coupling constants. The unperturbed equations are solved with the use of a restricted kinetically balanced basis set for the small component while to solve the second-order coupled perturbed DKS equations a restricted magnetically balanced basis set for the small component was applied. Benchmark relativistic calculations have been carried out for the X-H and H-H spin-spin coupling constants in the XH 4 series (X = C, Si, Ge, Sn and Pb). The method provides an attractive alternative to existing approximate two-component methods with transformed Hamiltonians for relativistic calculations of spin-spin coupling constants of heavy-atom systems. In particular, no picture-change effects arise in our method for property calculations
Nuclear effects in electron spin resonance of crystalline solids
International Nuclear Information System (INIS)
Ursu, I.; Nistor, S.V.
1976-01-01
A survey on the theory of paramagnetic ions in crystals is given. Some recent applications in which nuclear properties are studied by means of the ESR method are presented against this background. Finer effects in the hyperfine structure of ESR spectra, temperature dependance of the hyperfine coupling of S-state ions, observation of nuclear isotopic shift in ESR represent the applications discussed
Towards the improvement of spin-isospin properties in nuclear energy density functionals
International Nuclear Information System (INIS)
Roca-Maza, X.; Colò, G.; Liang, H. Z.; Sagawa, H.; Meng, J.; Ring, P.; Zhao, P. W.
2016-01-01
We address the problem of improving existing nuclear Energy Density Functionals (EDFs) in the spin-isospin channel. For that, we propose two different ways. The first one is to carefully take into account in the fitting protocol some of the key ground state properties for an accurate description of the most studied spin-isospin resonances: the Gamow-Teller Resonance (GTR) [1]. The second consists in providing a strategy to build local covariant EDF keeping the main features from their non-local counterparts [2]. The RHF model based on a Lagrangian where heavy mesons carry the nuclear effective interaction have been shown to be successful in the description of spin-isospin resonances [3]. (paper)
Spin Coherence in Semiconductor Nanostructures
National Research Council Canada - National Science Library
Flatte, Michael E
2006-01-01
... dots, tuning of spin coherence times for electron spin, tuning of dipolar magnetic fields for nuclear spin, spontaneous spin polarization generation and new designs for spin-based teleportation and spin transistors...
The role of level anti-crossings in nuclear spin hyperpolarization
Ivanov, Konstantin L.; Pravdivtsev, Andrey N.; Yurkovskaya, Alexandra V.; Vieth, Hans Martin; Kaptein, R
2014-01-01
Nuclear spin hyperpolarization is an important resource for increasing the sensitivity of NMR spectroscopy and MRI. Signal enhancements can be as large as 3-4 orders of magnitude. In hyperpolarization experiments, it is often desirable to transfer the initial polarization to other nuclei of choice,
DEFF Research Database (Denmark)
Jacobsen, H.J.; Skibsted, J.; Kristensen, Martin
2001-01-01
Magic-angle spinning nuclear magnetic resonance spectra of 31P and 29Si have been achieved for a thin silica film doped with only 1.8% 31P and deposited by plasma enhanced chemical vapor deposition on a pure silicon wafer. The observation of a symmetric 31P chemical shift tensor is consistent...
Shell structure at high spin and the influence on nuclear shapes
International Nuclear Information System (INIS)
Khoo, T.L.; Chowdhury, P.; Ahmad, I.
1982-01-01
Nuclear structure at high spin is influenced by a combination of liquid-drop and shell-structure effects. For N 90. The competition between oblate and prolate driving effects leads to a prolate-to-oblate shape transition in 154 Dy 88 . The role of rotation-aligned configurations in the shape change is discussed
Isotopic and spin-nuclear effects in solid hydrogens (Review Article)
Freiman, Yuri A.; Crespo, Yanier
2017-12-01
The multiple isotopic family of hydrogens (H2, HD, D2, HT, DT, T2) due to large differences in the de Boer quantum parameter and inertia moments displays a diversity of pronounced quantum isotopic solid-state effects. The homonuclear members of this family (H2, D2, T2) due to the permutation symmetry are subjects of the constraints of quantum mechanics which link the possible rotational states of these molecules to their total nuclear spin giving rise to the existence of two spin-nuclear modifications, ortho- and parahydrogens, possessing substantially different properties. Consequently, hydrogen solids present an unique opportunity for studying both isotope and spin-nuclear effects. The rotational spectra of heteronuclear hydrogens (HD, HT, DT) are free from limitations imposed by the permutation symmetry. As a result, the ground state of these species in solid state is virtually degenerate. The most dramatic consequence of this fact is an effect similar to the Pomeranchuk effect in 3He which in the case of the solid heteronuclear hydrogens manifests itself as the reentrant broken symmetry phase transitions. In this review article we discuss thermodynamic and kinetic effects pertaining to different isotopic and spin-nuclear species, as well as problems that still remain to be solved.
Calculation of nuclear-spin-relaxation rate for spin-polarized atomic hydrogen
International Nuclear Information System (INIS)
Ahn, R.M.C.; Eijnde, J.P.H.W.V.; Verhaar, B.J.
1983-01-01
Approximations introduced in previous calculations of spin relaxation for spin-polarized atomic hydrogen are investigated by carrying out a more exact coupled-channel calculation. With the exception of the high-temperature approximation, the approximations turn out to be justified up to the 10 -3 level of accuracy. It is shown that at the lowest temperatures for which experimental data are available, the high-temperature limit underestimates relaxation rates by a factor of up to 2. For a comparison with experimental data it is also of interest to pay attention to the expression for the atomic hydrogen relaxation rates in terms of transition amplitudes for two-particle collisions. Discrepancies by a factor of 2 among previous derivations of relaxation rates are pointed out. To shed light on these discrepancies we present two alternative derivations in which special attention is paid to identical-particle aspects. Comparing with experiment, we find our theoretical volume relaxation rate to be in better agreement with measured values than that obtained by other groups. The theoretical surface relaxation rate, however, still shows a discrepancy with experiment by a factor of order 50
Nuclear spin measurement using the angular correlation method
International Nuclear Information System (INIS)
Schapira, J.-P.
The double angular correlation method is defined by a semi-classical approach (Biendenharn). The equivalence formula in quantum mechanics are discussed for coherent and incoherent angular momentum mixing; the correlations are described from the density and efficiency matrices (Fano). The ambiguities in double angular correlations can be sometimes suppressed (emission of particles with a high orbital momentum l), using triple correlations between levels with well defined spin and parity. Triple correlations are applied to the case where the direction of linear polarization of γ-rays is detected [fr
CSIR Research Space (South Africa)
Chunilall, Viren
2012-03-01
Full Text Available , extractives and hemicelluloses supporting bundles of tightly packed cellulose fibrils.1 Cellulose, the major component of the cell wall, is a polysaccharide made up of (1-4)-?-D-glucopyranose units. After cellulose, hemicelluloses constitute the most... abundant group of carbohydrates in the wood cell walls. Hemicelluloses are branched polymers made up of several monosaccharides. Lignin, the second most abundant polymer in wood, consists of phenyl propane units and plays an important supporting role...
Nuclear structure of 94,95Mo at high spins
International Nuclear Information System (INIS)
Kharraja, B.; Ghugre, S.S.; Garg, U.; Janssens, R.V.; Carpenter, M.P.; Crowell, B.; Khoo, T.L.; Lauritsen, T.; Nisius, D.; Reviol, W.; Mueller, W.F.; Riedinger, L.L.; Kaczarowski, R.
1998-01-01
The high-spin level structures of 94,95 Mo (N=52,53) have been investigated via the 65 Cu( 36 S, αp2n) 94 Mo and 65 Cu( 36 S, αpn) 95 Mo reactions at 142 MeV. The level schemes have been extended up to spin J∼19ℎ and excitation energies E x ∼12 MeV. Spherical shell-model calculations have been performed and compared with the experimental energy levels. The level structure of 94 Mo exhibits a single-particle nature and the higher-angular-momentum states are dominated by the excitation of a g 9/2 neutron across the N=50 shell gap. The level sequences observed in 95 Mo have been interpreted on the basis of the spherical shell model and weak coupling of a d 5/2 or a g 7/2 neutron to the 94 Mo core. copyright 1998 The American Physical Society
Carbon-13 NMR of glycogen: Hydration response studied by using solids methods
International Nuclear Information System (INIS)
Jackson, C.L.; Bryant, R.G.
1989-01-01
The carbon-13 NMR spectra of glycogen are reported by using the methods of magic-angle sample spinning and high-power proton decoupling to provide a dynamic report on the glucose monomer behavior as a function of hydration. Although the glycogen behaves as a typical polymer in the dry state, addition of water makes a significant difference in the spectral appearance. Water addition decreases the carbon spin-lattice relaxation times by 2 orders of magnitude over the range from 7% to 70% water by weight. The proton-carbon dipole-dipole coupling, which broadens the carbon spectrum and permits cross-polarization spectroscopy, is lost with increasing hydration over this range. By 60% water by weight, scalar decoupling methods are sufficient to achieve a reasonably high-resolution spectrum. Further, at this concentration, the carbon spin-lattice relaxation times are near their minimum values at a resonance frequency of 50.3 MHz, making acquisition of carbon spectra relatively insensitive to intensity distortions associated with saturation effects. Though motional averaging places the spectrum in the solution phase limit, the static spectrum shows a residual broader component that would not necessarily be detected readily by using high-resolution liquid-state experiments
Magnetic pseudo-fields in a rotating electron-nuclear spin system
Wood, A. A.; Lilette, E.; Fein, Y. Y.; Perunicic, V. S.; Hollenberg, L. C. L.; Scholten, R. E.; Martin, A. M.
2017-11-01
Analogous to the precession of a Foucault pendulum observed on the rotating Earth, a precessing spin observed in a rotating frame of reference appears frequency-shifted. This can be understood as arising from a magnetic pseudo-field in the rotating frame that nevertheless has physically significant consequences, such as the Barnett effect. To detect these pseudo-fields, a rotating-frame sensor is required. Here we use quantum sensors, nitrogen-vacancy (NV) centres, in a rapidly rotating diamond to detect pseudo-fields in the rotating frame. Whereas conventional magnetic fields induce precession at a rate proportional to the gyromagnetic ratio, rotation shifts the precession of all spins equally, and thus primarily affect 13C nuclear spins in the sample. We are thus able to explore these effects via quantum sensing in a rapidly rotating frame, and define a new approach to quantum control using rotationally induced nuclear spin-selective magnetic fields. This work provides an integral step towards realizing precision rotation sensing and quantum spin gyroscopes.
Advances and applications of dynamic-angle spinning nuclear magnetic resonance
Energy Technology Data Exchange (ETDEWEB)
Baltisberger, Jay Harvey [Univ. of California, Berkeley, CA (United States)
1993-06-01
This dissertation describes nuclear magnetic resonance experiments and theory which have been developed to study quadrupolar nuclei (those nuclei with spin greater than one-half) in the solid state. Primarily, the technique of dynamic-angle spinning (DAS) is extensively reviewed and expanded upon in this thesis. Specifically, the improvement in both the resolution (two-dimensional pure-absorptive phase methods and DAS angle choice) and sensitivity (pulse-sequence development), along with effective spinning speed enhancement (again through choice of DAS conditions or alternative multiple pulse schemes) of dynamic-angle spinning experiment was realized with both theory and experimental examples. The application of DAS to new types of nuclei (specifically the {sup 87}Rb and {sup 85}Rb nuclear spins) and materials (specifically amorphous solids) has also greatly expanded the possibilities of the use of DAS to study a larger range of materials. This dissertation is meant to demonstrate both recent advances and applications of the DAS technique, and by no means represents a comprehensive study of any particular chemical problem.
Advances and applications of dynamic-angle spinning nuclear magnetic resonance
International Nuclear Information System (INIS)
Baltisberger, J.H.
1993-06-01
This dissertation describes nuclear magnetic resonance experiments and theory which have been developed to study quadrupolar nuclei (those nuclei with spin greater than one-half) in the solid state. Primarily, the technique of dynamic-angle spinning (DAS) is extensively reviewed and expanded upon in this thesis. Specifically, the improvement in both the resolution (two-dimensional pure-absorptive phase methods and DAS angle choice) and sensitivity (pulse-sequence development), along with effective spinning speed enhancement (again through choice of DAS conditions or alternative multiple pulse schemes) of dynamic-angle spinning experiment was realized with both theory and experimental examples. The application of DAS to new types of nuclei (specifically the 87 Rb and 85 Rb nuclear spins) and materials (specifically amorphous solids) has also greatly expanded the possibilities of the use of DAS to study a larger range of materials. This dissertation is meant to demonstrate both recent advances and applications of the DAS technique, and by no means represents a comprehensive study of any particular chemical problem
Determination of nuclear spins of short-lived isotopes by laser induced fluorescence
International Nuclear Information System (INIS)
Buchinger, F.; Dabkiewicz, P.; Kremmling, H.; Kuehl, T.; Mueller, A.C.; Schuessler, H.A.
1980-01-01
The spins of several nuclear ground and isomeric states have been measured for a number of mercury isotopes. The fluorescent light from the 6s6p 3 P 1 state is observed at 2537 Angstroem after excitation with the frequency doubled output of a pulsed dye laser. Four different laser induced fluorescence techniques were tested for their applicability: double resonance, Hanle effect, time delayed integral Hanle beats, and time resolved quantum beats. The sensitivity and selectivity of these models are compared with emphasis on the determination of spins of nuclei far from beta-stability, where short half lives and low production yields restrict the number of available atoms. The experiments were carried out on-line with the ISOLDE isotope separator at CERN at densities as low as 10 6 atoms/cm 3 . Results for the very neutron deficient high spin mercury isomers with half lives of several seconds, but also for the ground states of the abundant low spin stable mercury isotopes, are given as examples. The test measurements determined the nuclear spins of the odd sup(185m-191m)Hg isomers to be I = 13/2. (orig.)
Nuclear spin dominated relaxation of atomic tunneling systems in glasses
Energy Technology Data Exchange (ETDEWEB)
Luck, Annina
2016-11-16
The measurements performed in this thesis have revealed a non phononic relaxation channel for atomic tunneling systems in glasses at very low temperatures due to the presence of nuclear electric quadrupoles. Dielectric measurements on the multicomponent glasses N-KZFS11 and HY-1, containing {sup 181}Ta and {sup 165}Ho, respectively, that both carry very large nuclear electric quadrupole moments, show a relaxation rate in the kilohertz range, that is constant for temperatures exceeding the nuclear quadrupole splitting of the relevant isotopes. The results are compared to measurements performed on the glasses Herasil and N-BK7 that both contain no large nuclear quadrupole moments. Using three different setups to measure the complex dielectric function, the measurements cover almost eight orders of magnitude in frequency from 60 Hz to 1 GHz and temperatures down to 7.5 mK. This has allowed us a detailed study of the novel effects observed within this thesis and has led to a simplified model explaining the effects of nuclear electric quadrupoles on the behavior of glasses at low temperatures. Numeric calculations based on this model are compared to the measured data.
Nuclear spin optical rotation and Faraday effect in gaseous and liquid water.
Pennanen, Teemu S; Ikäläinen, Suvi; Lantto, Perttu; Vaara, Juha
2012-05-14
Nuclear spin optical rotation (NSOR) of linearly polarized light, due to the nuclear spins through the Faraday effect, provides a novel probe of molecular structure and could pave the way to optical detection of nuclear magnetization. We determine computationally the effects of the liquid medium on NSOR and the Verdet constant of Faraday rotation (arising from an external magnetic field) in water, using the recently developed theory applied on a first-principles molecular dynamics trajectory. The gas-to-liquid shifts of the relevant antisymmetric polarizability and, hence, NSOR magnitude are found to be -14% and -29% for (1)H and (17)O nuclei, respectively. On the other hand, medium effects both enhance the local electric field in water and, via bulk magnetization, the local magnetic field. Together these two effects partially cancel the solvation influence on the single-molecular property. We find a good agreement for the hydrogen NSOR with a recent pioneering experiment on H(2)O(l).
Superdeformed and high-spin nuclear structure data on the INTERNET
International Nuclear Information System (INIS)
Singh, B.; Firestone, R.B.; Chu, S.Y.F.
1997-01-01
With the advent of the large detector arrays GAMMASPHERE, EUROGAM, and GASP, a wealth of new information about the properties of nuclei at high spin has become available. Superdeformed and high-spin nuclear structure data and associated bibliographic information made available on INTERNET by the Isotopes Project at LBNL are described. The Table of Superdeformed Bands and Fission Isomers on the INTERNET will be updated continuously, and new recent reference lists will be provided approximately every three months. This information will also be published annually in the Table of Isotopes CD-ROM updates. (author)
Influence of the spin-orbit coupling on nuclear superfluidity along the N=Z line
International Nuclear Information System (INIS)
Juillet, O.; Josse, S.
2000-01-01
We show that the spin-orbit potential of the nuclear mean field destroys isoscalar superfluid correlations in self-conjugate nuclei. Using group theory and boson mapping techniques on a Hamiltonian including single particle splittings and a SO ST (8) pairing interaction, we give analytical expression for the spin-orbit dependence of some N =Z properties such as the relative position of T = 0 and T = 1 states in odd-odd systems or double binding-energy differences of even-even nuclei. (authors)
International Nuclear Information System (INIS)
Wylie, Benjamin J.; Dzikovski, Boris G.; Pawsey, Shane; Caporini, Marc; Rosay, Melanie; Freed, Jack H.; McDermott, Ann E.
2015-01-01
We demonstrate that dynamic nuclear polarization of membrane proteins in lipid bilayers may be achieved using a novel polarizing agent: pairs of spin labels covalently bound to a protein of interest interacting at an intermolecular interaction surface. For gramicidin A, nitroxide tags attached to the N-terminal intermolecular interface region become proximal only when bimolecular channels forms in the membrane. We obtained signal enhancements of sixfold for the dimeric protein. The enhancement effect was comparable to that of a doubly tagged sample of gramicidin C, with intramolecular spin pairs. This approach could be a powerful and selective means for signal enhancement in membrane proteins, and for recognizing intermolecular interfaces
International Nuclear Information System (INIS)
Vertij, A.A.; Gavrilov, S.P.; Shestopalov, V.P.
1990-01-01
Interaction of incident nuclear particle beam with J = 1/2 (neutrons) spin and (J = 1/2) protons with the target substance is considered. It is shown that neutron polarization at the target exit and neutron transparency (G) of the target depend significantly on incident wave amplitude level and physical parameter values which characterize the target, such as target temperature, resonator mirror reflection factor, number of spins interacting with the field, etc. Under interaction of neutrons with a target resonator which features a high mirror reflection factor and low losses for absorption which is not related to magnetic dipole absorption, a bistable response of neutron polarization and G manifests itself. 1 ref
Beyond RPA in nuclear rotation and wobbling motion at high spin
International Nuclear Information System (INIS)
Kaneko, Kazunari
1991-01-01
A quantum mechanical method of the nuclear rotation and the wobbling motion at high spin beyond the small-oscillation approximation is represented within the framework of time-dependent mean-field theory with some constraints. The constraints which determine the choice of the rotating reference frame are considered in the spin-orientation frame and the principal-axis frame. The quantization under such constraints is performed by making use of the Dirac bracket. Then the commutation relations of the angular momentum are derived. (orig.)
Ma, Wen-Long; Liu, Ren-Bao
2016-08-01
Single-molecule sensitivity of nuclear magnetic resonance (NMR) and angstrom resolution of magnetic resonance imaging (MRI) are the highest challenges in magnetic microscopy. Recent development in dynamical-decoupling- (DD) enhanced diamond quantum sensing has enabled single-nucleus NMR and nanoscale NMR. Similar to conventional NMR and MRI, current DD-based quantum sensing utilizes the "frequency fingerprints" of target nuclear spins. The frequency fingerprints by their nature cannot resolve different nuclear spins that have the same noise frequency or differentiate different types of correlations in nuclear-spin clusters, which limit the resolution of single-molecule MRI. Here we show that this limitation can be overcome by using "wave-function fingerprints" of target nuclear spins, which is much more sensitive than the frequency fingerprints to the weak hyperfine interaction between the targets and a sensor under resonant DD control. We demonstrate a scheme of angstrom-resolution MRI that is capable of counting and individually localizing single nuclear spins of the same frequency and characterizing the correlations in nuclear-spin clusters. A nitrogen-vacancy-center spin sensor near a diamond surface, provided that the coherence time is improved by surface engineering in the near future, may be employed to determine with angstrom resolution the positions and conformation of single molecules that are isotope labeled. The scheme in this work offers an approach to breaking the resolution limit set by the "frequency gradients" in conventional MRI and to reaching the angstrom-scale resolution.
Energy Technology Data Exchange (ETDEWEB)
Goldmann, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires
1967-02-15
This work describes methods of dynamic nuclear polarization in solids based on the thermal mixing between nuclear spin systems. The description of the thermal mixing processes involves most of the fundamental aspects of the spin temperature theory. The experiments, conducted with paradichlorobenzene and para-dibromobenzene, yield a detailed confirmation of the theoretical predictions. (author) [French] Ce travail decrit des methodes de polarisation dynamique nucleaire dans les solides basees sur le melange thermique entre systemes de spins nucleaires. La description des processus de melange thermique met en jeu la plupart des aspects fondamentaux de la theorie de la temperature de spin. Les experiences, realisees avec du paradichlorobenzene et du paradibromobenzene, apportent une confirmation detaillee des previsions theoriques. (auteur)
An elementary quantum network using robust nuclear spin qubits in diamond
Kalb, Norbert; Reiserer, Andreas; Humphreys, Peter; Blok, Machiel; van Bemmelen, Koen; Twitchen, Daniel; Markham, Matthew; Taminiau, Tim; Hanson, Ronald
Quantum registers containing multiple robust qubits can form the nodes of future quantum networks for computation and communication. Information storage within such nodes must be resilient to any type of local operation. Here we demonstrate multiple robust memories by employing five nuclear spins adjacent to a nitrogen-vacancy defect centre in diamond. We characterize the storage of quantum superpositions and their resilience to entangling attempts with the electron spin of the defect centre. The storage fidelity is found to be limited by the probabilistic electron spin reset after failed entangling attempts. Control over multiple memories is then utilized to encode states in decoherence protected subspaces with increased robustness. Furthermore we demonstrate memory control in two optically linked network nodes and characterize the storage capabilities of both memories in terms of the process fidelity with the identity. These results pave the way towards multi-qubit quantum algorithms in a remote network setting.
Kotlarchyk, Michael; Thurston, George M
2016-12-28
In this work we study the potential for utilizing the scattering of polarized neutrons from nuclei whose spin has been modulated using nuclear magnetic resonance (NMR). From first principles, we present an in-depth development of the differential scattering cross sections that would arise in such measurements from a hypothetical target system containing nuclei with non-zero spins. In particular, we investigate the modulation of the polarized scattering cross sections following the application of radio frequency pulses that impart initial transverse rotations to selected sets of spin-1/2 nuclei. The long-term aim is to provide a foundational treatment of the scattering cross section associated with enhancing scattering signals from selected nuclei using NMR techniques, thus employing minimal chemical or isotopic alterations, so as to advance the knowledge of macromolecular or liquid structure.
Spectroscopic Measurement of LEAD-204 Isotope Shift and LEAD-205 Nuclear Spin.
Schonberger, Peter
The isotope shift of ('204)Pb and the nuclear spin of 1.4 x 10('7)-y ('205)Pb was determined from a high -resolution optical measurement of the 6p('2) ('3)P(,o) -6p7s('3)P(,1)('o) 283.3-nm resonance line. The value of the shift, relative to ('208)Pb is -140.2(8) x 10('-3)cm(' -1), the negative sign indicating a shift to lower wave numbers. The precision is 3-4 times greater than that of previous measurements. The spin of ('205)Pb l = 5/2 was obtained from the measurement of the relative intensities of its three hyperfine components. This method of absorption spectroscopy determination of ground state nuclear spin is applicable to any stable or longlived isotope. High resolution optical absorption spectra were obtained with a 25.4cm diffraction grating in a 9.1m focal length Czerny-Turner spectrometer. A signal-averaging scanning technique was used to record the spectra. Increased precision in the isotope shift measurement was attained by using separated isotope samples of ('204)Pb and ('207)Pb. A controlled amount of the later was incorporated in the absorption cell to provide internal calibration by its 6p7s ('3)P(,1)('o) hfs separation. Absorption spectra were recorded for several optical thicknesses of the absorber. A single spin value of increased precision was derived from the entire set of combined data.
Effect of deformation and orientation on spin orbit density dependent nuclear potential
Mittal, Rajni; Kumar, Raj; Sharma, Manoj K.
2017-11-01
Role of deformation and orientation is investigated on spin-orbit density dependent part VJ of nuclear potential (VN=VP+VJ) obtained within semi-classical Thomas Fermi approach of Skyrme energy density formalism. Calculations are performed for 24-54Si+30Si reactions, with spherical target 30Si and projectiles 24-54Si having prolate and oblate shapes. The quadrupole deformation β2 is varying within range of 0.023 ≤ β2 ≤0.531 for prolate and -0.242 ≤ β2 ≤ -0.592 for oblate projectiles. The spin-orbit dependent potential gets influenced significantly with inclusion of deformation and orientation effect. The spin-orbit barrier and position gets significantly influenced by both the sign and magnitude of β2-deformation. Si-nuclei with β220. The possible role of spin-orbit potential on barrier characteristics such as barrier height, barrier curvature and on the fusion pocket is also probed. In reference to prolate and oblate systems, the angular dependence of spin-orbit potential is further studied on fusion cross-sections.
Spin assignments of nuclear levels above the neutron binding energy in $^{88}$Sr
Neutron resonances reveal nuclear levels in the highly excited region of the nucleus around the neutron binding energy. Nuclear level density models are therefore usually calibrated to the number of observed levels in neutron-induced reactions. The gamma-ray cascade from the decay of the highly excited compound nucleus state to the ground state show dierences dependent on the initial spin. This results in a dierence in the multiplicity distribution which can be exploited. We propose to use the 4${\\pi}$ total absorption calorimeter (TAC) at the n TOF facility to determine the spins of resonances formed by neutrons incident on a metallic $^{87}$Sr sample by measuring the gamma multiplicity distributions for the resolved resonances. In addition we would like to use the available enriched $^{87}$Sr target for cross section measurements with the C$\\scriptscriptstyle{6}$D$\\scriptscriptstyle{6}$ detector setup.
Sum rule approach to the nuclear response in the isovector spin channel
International Nuclear Information System (INIS)
Alberico, W.M.; Ericson, M.; Molinari, A.
1982-01-01
We study the global features of the response of infinite nuclear matter in the spin-isospin channel through the energy weighted sum rules S 1 and Ssub(-) 1 . In particular we compare the outcome of the ring approximation with the exact RPA evaluation of the sum rules. We also investigate the influence of the collective character of the response, induced by the particle hole force for a longitudinal and transverse spin couplings. We show that S 1 is insensitive to the collectivity of the response, as long as the Δ degree of freedom is ignored. The inverse energy weighted sum rule on the other hand, which is linked to the paramagnetic susceptibility, always reflects the hardening or softening of the nuclear response, due to the repulsive or attractive character of the p-h force. This quantity is well suited to the comparison with the experiments, which we perform for 12 C and 56 Fe. (orig.)
Nuclear spin relaxation due to chemical shift anisotropy of gas-phase 129Xe.
Hanni, Matti; Lantto, Perttu; Vaara, Juha
2011-08-14
Nuclear spin relaxation provides detailed dynamical information on molecular systems and materials. Here, first-principles modeling of the chemical shift anisotropy (CSA) relaxation time for the prototypic monoatomic (129)Xe gas is carried out, both complementing and predicting the results of NMR measurements. Our approach is based on molecular dynamics simulations combined with pre-parametrized ab initio binary nuclear shielding tensors, an "NMR force field". By using the Redfield relaxation formalism, the simulated CSA time correlation functions lead to spectral density functions that, for the first time, quantitatively determine the experimental spin-lattice relaxation times T(1). The quality requirements on both the Xe-Xe interaction potential and binary shielding tensor are investigated in the context of CSA T(1). Persistent dimers Xe(2) are found to be responsible for the CSA relaxation mechanism in the low-density limit of the gas, completely in line with the earlier experimental findings.
International Nuclear Information System (INIS)
Mentink-Vigier, Frederic
2011-01-01
Quantum information processing is a major challenge both on fundamental and technological grounds. In this research field, the spin bus concept relies on the use of both the electronic and nuclear spins in which the electron is used as a reading and writing head over the nuclei system which makes the qubit register. The requested material to build a spin bus must have unpaired electrons delocalized over a great number of nuclear spins having long decoherence time. In this work, we studied a spin system composed of titanium (III) interacting with multiple gallium nuclei in gallium oxide. We synthesized and studied the titanium paramagnetic center in gallium oxide single crystals by continuous wave EPR and ENDOR spectroscopy and showed that the electron is delocalized over eight neighbouring gallium nuclei. This study also revealed a strong isotopic effect on the nucleus-nucleus interaction mediated by the electron. When the two nearest gallium nuclei surrounding the titanium are identical (same isotopes) this interaction is one order of magnitude higher than in the case of inequivalent nuclei. This effect can be used in order to reduce the computation time. Finally, the dynamical properties of the spin system have been characterized by pulsed EPR and ENDOR spectroscopy. The electron spin decoherence is driven by instantaneous and spectral diffusion. The nuclear dynamical properties have also been studied in order to determine the order of magnitude of nuclear spin relaxation and decoherence time. (author) [fr
Hsu, Chen-Hsuan; Stano, Peter; Klinovaja, Jelena; Loss, Daniel
2018-03-01
The electrons in the edge channels of two-dimensional topological insulators can be described as a helical Tomonaga-Luttinger liquid. They couple to nuclear spins embedded in the host materials through the hyperfine interaction, and are therefore subject to elastic spin-flip backscattering on the nuclear spins. We investigate the nuclear-spin-induced edge resistance due to such backscattering by performing a renormalization-group analysis. Remarkably, the effect of this backscattering mechanism is stronger in a helical edge than in nonhelical channels, which are believed to be present in the trivial regime of InAs/GaSb quantum wells. In a system with sufficiently long edges, the disordered nuclear spins lead to an edge resistance which grows exponentially upon lowering the temperature. On the other hand, electrons from the edge states mediate an anisotropic Ruderman-Kittel-Kasuya-Yosida nuclear spin-spin interaction, which induces a spiral nuclear spin order below the transition temperature. We discuss the features of the spiral order, as well as its experimental signatures. In the ordered phase, we identify two backscattering mechanisms, due to charge impurities and magnons. The backscattering on charge impurities is allowed by the internally generated magnetic field, and leads to an Anderson-type localization of the edge states. The magnon-mediated backscattering results in a power-law resistance, which is suppressed at zero temperature. Overall, we find that in a sufficiently long edge the nuclear spins, whether ordered or not, suppress the edge conductance to zero as the temperature approaches zero.
Contrast generation in the nuclear-spin tomography by pulsed ultrasound
International Nuclear Information System (INIS)
Oehms, Ole Benjamin
2009-01-01
In the framework of this thesis a combined method of ultrasound and nuclear-spin tomography is presented. Via ultrasound pulses by the sound-radiation force in liquids and tissue phantoms motions are generated, which depend on ther viscoelastic properties. This motions are made visible by a motion-sensitive tomograph sequence in the phase image of the tomograph in form of a phase change. The first measurements on simple phantoms and liquids are presented. [de
International Nuclear Information System (INIS)
Chapelet-Letourneux, G.
1969-01-01
N-t-butyl-N-phenyl nitroxide is obtained by: a) action of t-butyl-magnesium chloride on nitrobenzene, or of phenyl-magnesium bromide on nitro-t-butane, b) oxidation of N-t-butyl-N-phenylhydroxylamine, c) oxidation of N-t-butylaniline. In these latter two cases, it has been possible to isolate the pure radical and to study it using UV, IR and EPR. It decomposes to give N-t-butylaniline and the N-oxide of N-t-butyl-p-quinon-imine. The action of peracids such as p-nitro-perbenzoic or m-chloro-perbenzoic acids on amines or hydroxylamines leads to the formation of stable or unstable nitroxide radicals easily observable by EPR. Finally, with a view to obtaining definite values for the coupling between the free electron of a nitroxide and carbon 13, the preparation of such radicals marked with 13 C in the α or β position of the nitroxide function has been carried out. The coupling with an α carbon 13 is negative and does not appear to vary with the spin density on the nitrogen. The interaction with the p nuclei of the nitrogen depends on the nature of the substituents: the two benzyl protons have a hyperfine splitting a H which is always less than that of the ethyl. On the other hand, the 13 C coupling is greater in the first case. The usually adopted conformations for the compounds having the carbonyl group cannot account for the observed values of the β couplings. (author) [fr
Nikolaev, M. A.; Klapdor-Kleingrothaus, H. V.
1993-06-01
We present calculations of the nuclear from factors for spin-dependent elastic scattering of dark matter WIMPs from123Te and131Xe isotopes, proposed to be used for dark matter detection. A method based on the theory of finite Fermi systems was used to describe the reduction of the single-particle spin-dependent matrix elements in the nuclear medium. Nucleon single-particle states were calculated in a realistic shell model potential; pairing effects were treated within the BCS model. The coupling of the lowest single-particle levels in123Te to collective 2+ excitations of the core was taken into account phenomenologically. The calculated nuclear form factors are considerably less then the single-particle ones for low momentum transfer. At high momentum transfer some dynamical amplification takes place due to the pion exchange term in the effective nuclear interaction. But as the momentum transfer increases, the difference disappears, the momentum transfer increases and the quenching effect disappears. The shape of the nuclear form factor for the131Xe isotope differs from the one obtained using an oscillator basis.
International Nuclear Information System (INIS)
Nikolaev, M.A.; Klapdor-Kleingrothaus, H.V.
1993-01-01
We present calculations of the nuclear from factors for spin-dependent elastic scattering of dark matter WIMPs from 123 Te and 131 Xe isotopes, proposed to be used for dark matter detection. A method based on the theory of finite Fermi systems was used to describe the reduction of the single-particle spin-dependent matrix elements in the nuclear medium. Nucelon single-particle states were calculated in a realistic shell model potential; pairing effects were treated within the BCS model. The coupling of the lowest single-particle levels in 123 Te to collective 2 + excitations of the core was taken into account phenomenologically. The calculated nuclear form factors are considerably less then the single-particle ones for low momentum transfer. At high momentum transfer some dynamical amplification takes place due to the pion exchange term in the effective nuclear interaction. But as the momentum transfer increases, the difference disappears, the momentum transfer increases and quenching effect disappears. The shape of the nuclear form factor for the 131 Xe isotope differs from the one obtained using an oscillator basis. (orig.)
Analytic treatment of nuclear spin-lattice relaxation for diffusion in a cone model
Sitnitsky, A. E.
2011-12-01
We consider nuclear spin-lattice relaxation rate resulted from a diffusion equation for rotational wobbling in a cone. We show that the widespread point of view that there are no analytical expressions for correlation functions for wobbling in a cone model is invalid and prove that nuclear spin-lattice relaxation in this model is exactly tractable and amenable to full analytical description. The mechanism of relaxation is assumed to be due to dipole-dipole interaction of nuclear spins and is treated within the framework of the standard Bloemberger, Purcell, Pound-Solomon scheme. We consider the general case of arbitrary orientation of the cone axis relative the magnetic field. The BPP-Solomon scheme is shown to remain valid for systems with the distribution of the cone axes depending only on the tilt relative the magnetic field but otherwise being isotropic. We consider the case of random isotropic orientation of cone axes relative the magnetic field taking place in powders. Also we consider the cases of their predominant orientation along or opposite the magnetic field and that of their predominant orientation transverse to the magnetic field which may be relevant for, e.g., liquid crystals. Besides we treat in details the model case of the cone axis directed along the magnetic field. The latter provides direct comparison of the limiting case of our formulas with the textbook formulas for free isotropic rotational diffusion. The dependence of the spin-lattice relaxation rate on the cone half-width yields results similar to those predicted by the model-free approach.
The role of spin-orbit potential in nuclear prolate-shape dominance
Energy Technology Data Exchange (ETDEWEB)
Takahara, Satoshi, E-mail: staka@ks.kyorin-u.ac.jp [Kyorin University, School of Medicine, Mitaka, Tokyo 181-8611 (Japan); Onishi, Naoki [University of Tokyo (Japan); University of Yamanashi (Japan); Shimizu, Yoshifumi R. [Department of Physics, Graduate School of Science, Kyushu University, Fukuoka 812-8581 (Japan); Tajima, Naoki [Department of Applied Physics, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507 (Japan)
2011-08-26
It is confirmed, in terms of the Woods-Saxon-Strutinsky method, that the spin-orbit potential plays a decisive role in the predominance of prolate deformation, which has been a long standing problem in nuclear physics. It is originated from the combined effects of the spin-orbit coupling and the diffused surface of the potential, in agreement with the previous work based on a more schematic Nilsson-Strutinsky method. The degree of prolate-shape dominance exhibits an oscillatory behavior with respect to the strength of spin-orbit potential and, the prolate-shape dominance is realized at the proper strength of the spin-orbit potential together with the standard surface diffuseness; this oscillatory behavior disappears in case of small diffuseness corresponding to ellipsoidal cavity. The calculated energy differences between oblate and prolate minima in this Letter are consistent with those of our extensive self-consistent calculations of the Hartree-Fock + BCS method with the Skyrme interaction.
The role of spin-orbit potential in nuclear prolate-shape dominance
International Nuclear Information System (INIS)
Takahara, Satoshi; Onishi, Naoki; Shimizu, Yoshifumi R.; Tajima, Naoki
2011-01-01
It is confirmed, in terms of the Woods-Saxon-Strutinsky method, that the spin-orbit potential plays a decisive role in the predominance of prolate deformation, which has been a long standing problem in nuclear physics. It is originated from the combined effects of the spin-orbit coupling and the diffused surface of the potential, in agreement with the previous work based on a more schematic Nilsson-Strutinsky method. The degree of prolate-shape dominance exhibits an oscillatory behavior with respect to the strength of spin-orbit potential and, the prolate-shape dominance is realized at the proper strength of the spin-orbit potential together with the standard surface diffuseness; this oscillatory behavior disappears in case of small diffuseness corresponding to ellipsoidal cavity. The calculated energy differences between oblate and prolate minima in this Letter are consistent with those of our extensive self-consistent calculations of the Hartree-Fock + BCS method with the Skyrme interaction.
The nuclear spin response to intermediate energy protons and deuterons at low momentum transfer
International Nuclear Information System (INIS)
Baker, F.T.; Djalali, C.; Glashausser, C.; Lenske, H.; Love, W.G.; Tomasi-Gustafsson, E.; Wambach, J.
1997-01-01
Measurements of polarization transfer in the inelastic scattering of intermediate energy protons and deuterons have yielded a wealth of data on the spin response of nuclei. This work complements the well-known studies of Gamow-Teller strength in charge-exchange reactions. The emphasis here is on a consistent determination of the S=1, T=0 response, practical only with deuterons, and on the proper separation of S=0 and S=1 strength in proton spectra for appropriate comparison with sum rules. We concentrate on two nuclei, 40 Ca and 12 C, at momentum transfers below about 1 fm -1 and on excitations up to about 50 MeV. The continuum second random phase approximation provides the primary theoretical tool for calculating and interpreting the response in terms of properties of the nucleon-nucleon force inside the nuclear medium. The reaction mechanism is described by the DWIA, applied here to continuum proton scattering almost as rigorously as it is usually applied to low energy excitations. A new DWIA formalism for the description of spin observables in deuteron scattering is used. Comparison of the proton and deuteron data with each other and with RPA/DWIA calculations yields interesting insights into the current state of understanding of collectivity and the nuclear spin response. (orig.)
Spectroscopic measurement of 204Pb isotope shift and 205Pb nuclear spin
International Nuclear Information System (INIS)
Schonberger, P.
1984-01-01
The isotope shift of 204 Pb and the nuclear spin of 1.4 X 10 7 -y 205 Pb was determined from a high-resolution optical measurement of the 6p 23 P 0 -6p7s 3 P 1 0 283.3-nm resonance line. The value of the shift, relative to 208 Pb is -140.2(8) x 10 -3 cm -1 , the negative sign indicating a shift to lower wave numbers. The precision is 3-4 times greater than that of previous measurements. The spin of 205 Pb I = 5/2 was obtained from the measurement of the relative intensities of its three hyperfine components. This method of absorption spectroscopy determination of ground state nuclear spin is applicable to any stable or long-lived isotope. High resolution optical absorption spectra were obtained with a 25.4 cm diffraction grating in a 9.1 m focal length Czerny-Turner spectrometer. A signal-averaging scanning technique was used to record the spectra. Increased precision in the isotope shift measurement was attained by using separated isotope samples of 204 Pb and 207 Pb
Hyperfine structure, nuclear spins and magnetic moments of some cesium isotopes
International Nuclear Information System (INIS)
Ekstroem, C.; Ingelman, S.; Wannberg, G.
1977-03-01
Using an atomic-beam magnetic resonance apparatus connected on-line with the ISOLDE isotope separator, CERN, hyperfine structure measurements have been performed in the 2 Ssub(1/2) electronic ground state of some cesium isotopes. An on-line oven system which efficiently converts a mass separated ion-beam of alkali isotopes to an atomic beam is described in some detail. Experimentally determined nuclear spins of sup(120, 121, 121m, 122, 122m, 123, 124, 126, 128, 130m, 135m)Cs and magnetic moments of sup(122, 123, 124, 126, 128, 130)Cs are reported and discussed in terms of different nuclear models. The experimental data indicate deformed nuclear shapes of the lightest cesium isotopes. (Auth.)
Impact of hadronic and nuclear corrections on global analysis of spin-dependent parton distributions
Energy Technology Data Exchange (ETDEWEB)
Jimenez-Delgado, Pedro [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Accardi, Alberto [Hampton University, Hampton, VA (United States); Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Melnitchouk, Wally [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States)
2014-02-01
We present the first results of a new global next-to-leading order analysis of spin-dependent parton distribution functions from the most recent world data on inclusive polarized deep-inelastic scattering, focusing in particular on the large-x and low-Q^2 regions. By directly fitting polarization asymmetries we eliminate biases introduced by using polarized structure function data extracted under nonuniform assumptions for the unpolarized structure functions. For analysis of the large-x data we implement nuclear smearing corrections for deuterium and 3He nuclei, and systematically include target mass and higher twist corrections to the g_1 and g_2 structure functions at low Q^2. We also explore the effects of Q^2 and W^2 cuts in the data sets, and the potential impact of future data on the behavior of the spin-dependent parton distributions at large x.
Pure spin-3/2 propagator for use in particle and nuclear physics
Kristiano, J.; Clymton, S.; Mart, T.
2017-11-01
We propose the use of a pure spin-3/2 propagator in the (3 /2 ,0 )⊕(0 ,3 /2 ) representation in particle and nuclear physics. To formulate the propagator in a covariant form we use the antisymmetric tensor spinor representation and we consider the Δ resonance contribution to the elastic π N scattering as an example. We find that the use of a conventional gauge-invariant interaction Lagrangian leads to a problem: the obtained scattering amplitude does not exhibit the resonance behavior. To overcome this problem we modify the interaction by adding a momentum dependence. As in the case of the Rarita-Schwinger formalism, we find that a perfect resonance description could be obtained in the pure spin-3/2 formulation only if hadronic form factors were considered in the interactions.
Size dependence of 13C nuclear spin-lattice relaxation in micro- and nanodiamonds
Panich, A. M.; Sergeev, N. A.; Shames, A. I.; Osipov, V. Yu; Boudou, J.-P.; Goren, S. D.
2015-02-01
Size dependence of physical properties of nanodiamond particles is of crucial importance for various applications in which defect density and location as well as relaxation processes play a significant role. In this work, the impact of defects induced by milling of micron-sized synthetic diamonds was studied by magnetic resonance techniques as a function of the particle size. EPR and 13C NMR studies of highly purified commercial synthetic micro- and nanodiamonds were done for various fractions separated by sizes. Noticeable acceleration of 13C nuclear spin-lattice relaxation with decreasing particle size was found. We showed that this effect is caused by the contribution to relaxation coming from the surface paramagnetic centers induced by sample milling. The developed theory of the spin-lattice relaxation for such a case shows good compliance with the experiment.
Nuclear Spin relaxation mediated by Fermi-edge electrons in n-type GaAs
Kotur, M.; Dzhioev, R. I.; Kavokin, K. V.; Korenev, V. L.; Namozov, B. R.; Pak, P. E.; Kusrayev, Yu. G.
2014-03-01
A method based on the optical orientation technique was developed to measure the nuclear-spin lattice relaxation time T 1 in semiconductors. It was applied to bulk n-type GaAs, where T 1 was measured after switching off the optical excitation in magnetic fields from 400 to 1200 G at low (< 30 K) temperatures. The spin-lattice relaxation of nuclei in the studied sample with n D = 9 × 1016 cm-3 was found to be determined by hyperfine scattering of itinerant electrons (Korringa mechanism) which predicts invariability of T 1 with the change in magnetic field and linear dependence of the relaxation rate on temperature. This result extends the experimentally verified applicability of the Korringa relaxation law in degenerate semiconductors, previously studied in strong magnetic fields (several Tesla), to the moderate field range.
Culture of microalgae Spirulina platensis with isotope stable Carbon-13
International Nuclear Information System (INIS)
Cronemberger, Luiz C.A.; Costa, Vladimir E.
2017-01-01
Gastric emptying time abnormalities cause complications that affect the quality of life in humans and scintigraphy is the gold standard for this diagnosis. However its application has restrictions due to the use of the radiopharmaceutical 99m Tc. An alternative to this method is the stable carbon isotope respiratory test. This is a non-radioactive, noninvasive technique with no contraindications. Its application varies according to the substrate used. For evaluation of gastric emptying time one of the substrates that can be used in the respiratory test is Spirulina platensis labeled at 97% carbon atoms with the stable isotope carbon-13 ( 13 C). In Brazil, there is no production of this substrate and its high cost (US$475.00/g, excluding import taxes) makes it difficult to apply the test. Thus, the objective of the work is to cultivate labeled S. platensis at 97% of 13 C for use in the respiratory test for gastric emptying and to establish optimization parameters for the best cost-benefit of this culture. In the cultivation process the microalgae will be kept in a closed sterilized glass volumetric flask, with deionized water and a pure 13 C source. The light (photoperiod 12h light / dark), pH (∼ 9.5) and temperature (30 deg C) will be controlled and after 35-40 days of growth, the cyanobacteria will be lyophilized and ground for the acquisition of a powder that will be analyzed by IRMS and compared to S. platensis, which will be our reference standard
Resonance-inclined optical nuclear spin polarization of liquids in diamond structures
Chen, Q.; Schwarz, I.; Jelezko, F.; Retzker, A.; Plenio, M. B.
2016-02-01
Dynamic nuclear polarization (DNP) of molecules in a solution at room temperature has the potential to revolutionize nuclear magnetic resonance spectroscopy and imaging. The prevalent methods for achieving DNP in solutions are typically most effective in the regime of small interaction correlation times between the electron and nuclear spins, limiting the size of accessible molecules. To solve this limitation, we design a mechanism for DNP in the liquid phase that is applicable for large interaction correlation times. Importantly, while this mechanism makes use of a resonance condition similar to solid-state DNP, the polarization transfer is robust to a relatively large detuning from the resonance due to molecular motion. We combine this scheme with optically polarized nitrogen-vacancy (NV) center spins in nanodiamonds to design a setup that employs optical pumping and is therefore not limited by room temperature electron thermal polarization. We illustrate numerically the effectiveness of the model in a flow cell containing nanodiamonds immobilized in a hydrogel, polarizing flowing water molecules 4700-fold above thermal polarization in a magnetic field of 0.35 T, in volumes detectable by current NMR scanners.
Generalized nuclear Fukui functions in the framework of spin-polarized density-functional theory
International Nuclear Information System (INIS)
Chamorro, E.; Proft, F. de; Geerlings, P.
2005-01-01
An extension of Cohen's nuclear Fukui function is presented in the spin-polarized framework of density-functional theory (SP-DFT). The resulting new nuclear Fukui function indices Φ Nα and Φ Sα are intended to be the natural descriptors for the responses of the nuclei to changes involving charge transfer at constant multiplicity and also the spin polarization at constant number of electrons. These generalized quantities allow us to gain new insights within a perturbative scheme based on DFT. Calculations of the electronic and nuclear SP-DFT quantities are presented within a Kohn-Sham framework of chemical reactivity for a sample of molecules, including H 2 O, H 2 CO, and some simple nitrenes (NX) and phosphinidenes (PX), with X=H, Li, F, Cl, OH, SH, NH 2 , and PH 2 . Results have been interpreted in terms of chemical bonding in the context of Berlin's theorem, which provides a separation of the molecular space into binding and antibinding regions
Improved characterization of the botanical origin of sugar by carbon-13 SNIF-NMR applied to ethanol.
Thomas, Freddy; Randet, Celia; Gilbert, Alexis; Silvestre, Virginie; Jamin, Eric; Akoka, Serge; Remaud, Gerald; Segebarth, Nicolas; Guillou, Claude
2010-11-24
Until now, no analytical method, not even isotopic ones, had been able to differentiate between sugars coming from C4-metabolism plants (cane, maize, etc.) and some crassulacean acid metabolism plants (e.g., pineapple, agave) because in both cases the isotope distributions of the overall carbon-13/carbon-12 and site-specific deuterium/hydrogen isotope ratios are very similar. Following recent advances in the field of quantitative isotopic carbon-13 NMR measurements, a procedure for the analysis of the positional carbon-13/carbon-12 isotope ratios of ethanol derived from the sugars of pineapples and agave using the site-specific natural isotopic fractionation-nuclear magnetic resonance (SNIF-NMR) method is presented. It is shown that reproducible results can be obtained when appropriate analytical conditions are used. When applied to pineapple juice, this new method demonstrates a unique ability to detect cane and maize sugar, which are major potential adulterants, with a detection limit in the order of 15% of the total sugars, which provides an efficient mean of controlling the authenticity of juices made from this specific fruit. When applied to tequila products, this new method demonstrates a unique ability to unambiguously differentiate authentic 100% agave tequila, as well as misto tequila (made from at least 51% agave), from products made from a larger proportion of cane or maize sugar and therefore not complying with the legal definition of tequila.
Nuclear spin-lattice relaxation in n -type insulating and metallic GaAs single crystals
Lu, J.; Hoch, M. J. R.; Kuhns, P. L.; Moulton, W. G.; Gan, Z.; Reyes, A. P.
2006-09-01
The coupling of electron and nuclear spins in n-GaAs changes significantly as the donor concentration n increases through the insulator-metal critical concentration nC˜1.2×1016cm-3 . The present measurements of the Ga71 relaxation rates W made as a function of magnetic field (1-13T) and temperature (1.5-300K) for semi-insulating GaAs and for three doped n-GaAs samples with donor concentrations n=5.9×1015 , 7×1016 , and 2×1018cm-3 , show marked changes in the relaxation behavior with n . Korringa-like relaxation is found in both metallic samples for T30K phonon-induced nuclear quadrupolar relaxation is dominant. The relaxation rate measurements permit determination of the electron probability density at Ga71 sites. A small Knight shift of -3.3ppm was measured on the most metallic (2×1018cm-3) sample using magic-angle spinning at room temperature. For the n=5.9×1015cm-3 sample, a nuclear relaxation model involving the Fermi contact hyperfine interaction, rapid spin diffusion, and exchange coupled local moments is proposed. While the relaxation rate behavior with temperature for the weakly metallic sample, n=7×1016cm-3 , is similar to that found for the just-insulating sample, the magnetic field dependence is quite different. For the 5.9×1015cm-3 sample, increasing the magnetic field leads to a decrease in the relaxation rate, while for the 7×1016cm-3 sample this results in an increase in the relaxation rate ascribed to an increase in the density of states at the Fermi level as the Landau level degeneracy is increased.
Nuclear relaxation study of the spin dynamics in a one-dimensional Heisenberg system, TMMC
International Nuclear Information System (INIS)
Bakheit, M.A.
1974-01-01
Changes in the nuclear relaxation time as a function of the magnetic field intensity in TMMC are very different wether the field direction is parallel or perpendicular to the direction of the exchange chains (vector c). In parallel field, the relaxation probability increases as the field decreases. The process of spin diffusion in a one-dimensional system is well illustrated by the changes experimentally observed. In perpendicular field, the relaxation probability is constant as far as H 0 >2kG, it clearly decreases for H 0 [fr
International Nuclear Information System (INIS)
O'Brien, J.L.; Schofield, S.R.; Simmons, M.Y.; Clark, R.G.; Dzurak, A.S.; Prawer, S.; Adrienko, I.; Cimino, A.
2000-01-01
Full text: In the vigorous worldwide effort to experimentally build a quantum computer, recent intense interest has focussed on solid state approaches for their promise of scalability. Particular attention has been given to silicon-based proposals that can readily be integrated into conventional computing technology. For example the Kane design uses the well isolated nuclear spin of phosphorous donor nuclei (I=1/2) as the qubits embedded in isotopically pure 28 Si (I=0). We demonstrate the ability to fabricate a precise array of P atoms on a clean Si surface with atomic-scale resolution compatible with the fabrication of the Kane quantum computer
Discretization of the total magnetic field by the nuclear spin bath in fluorine-doped ZnSe.
Zhukov, E A; Kirstein, E; Kopteva, N E; Heisterkamp, F; Yugova, I A; Korenev, V L; Yakovlev, D R; Pawlis, A; Bayer, M; Greilich, A
2018-05-16
The coherent spin dynamics of fluorine donor-bound electrons in ZnSe induced by pulsed optical excitation is studied in a perpendicular applied magnetic field. The Larmor precession frequency serves as a measure for the total magnetic field exerted onto the electron spins and, surprisingly, does not increase linearly with the applied field, but shows a step-like behavior with pronounced plateaus, given by multiples of the laser repetition rate. This discretization occurs by a feedback mechanism in which the electron spins polarize the nuclear spins, which in turn generate a local Overhauser field adjusting the total magnetic field accordingly. Varying the optical excitation power, we can control the plateaus, in agreement with our theoretical model. From this model, we trace the observed discretization to the optically induced Stark field, which causes the dynamic nuclear polarization.
Quantum correlations in a system of nuclear s = 1/2 spins in a strong magnetic field
International Nuclear Information System (INIS)
Fel’dman, E B; Kuznetsova, E I; Yurishchev, M A
2012-01-01
Entanglement and quantum discord for a pair of nuclear spins s = 1/2 in a nanopore filled with a gas of spin-carrying molecules (atoms) are studied. The correlation functions describing dynamics of dipolar-coupled spins in a nanopore are found. The dependence of spin-pair entanglement on the temperature and the number of spins is obtained from the reduced density matrix, which is centrosymmetric (CS). An analytic expression for the concurrence is obtained for an arbitrary CS density matrix. It is shown that the quantum discord as a measure of quantum correlations attains a significant value at low temperatures. It is also shown that the discord in the considered model has ‘flickering’ character and disappears periodically in the course of time evolution of the system. The geometric discord is studied for arbitrary 4 × 4 CS density matrices. (paper)
Energy Technology Data Exchange (ETDEWEB)
Xiao, Yunlong; Zhang, Yong; Liu, Wenjian, E-mail: liuwjbdf@gmail.com [Beijing National Laboratory for Molecular Sciences, Institute of Theoretical and Computational Chemistry, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, and Center for Computational Science and Engineering, Peking University, Beijing 100871 (China)
2014-10-28
Both kinetically balanced (KB) and kinetically unbalanced (KU) rotational London orbitals (RLO) are proposed to resolve the slow basis set convergence in relativistic calculations of nuclear spin-rotation (NSR) coupling tensors of molecules containing heavy elements [Y. Xiao and W. Liu, J. Chem. Phys. 138, 134104 (2013)]. While they perform rather similarly, the KB-RLO Ansatz is clearly preferred as it ensures the correct nonrelativistic limit even with a finite basis. Moreover, it gives rise to the same “direct relativistic mapping” between nuclear magnetic resonance shielding and NSR coupling tensors as that without using the London orbitals [Y. Xiao, Y. Zhang, and W. Liu, J. Chem. Theory Comput. 10, 600 (2014)].
Energy Technology Data Exchange (ETDEWEB)
Křístková, Anežka; Malkin, Vladimir G. [Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, SK-84536 Bratislava (Slovakia); Komorovsky, Stanislav; Repisky, Michal [Centre for Theoretical and Computational Chemistry, University of Tromsø - The Arctic University of Norway, N-9037 Tromsø (Norway); Malkina, Olga L., E-mail: olga.malkin@savba.sk [Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, SK-84536 Bratislava (Slovakia); Department of Inorganic Chemistry, Comenius University, Bratislava (Slovakia)
2015-03-21
In this work, we report on the development and implementation of a new scheme for efficient calculation of indirect nuclear spin-spin couplings in the framework of four-component matrix Dirac-Kohn-Sham approach termed matrix Dirac-Kohn-Sham restricted magnetic balance resolution of identity for J and K, which takes advantage of the previous restricted magnetic balance formalism and the density fitting approach for the rapid evaluation of density functional theory exchange-correlation response kernels. The new approach is aimed to speedup the bottleneck in the solution of the coupled perturbed equations: evaluation of the matrix elements of the kernel of the exchange-correlation potential. The performance of the new scheme has been tested on a representative set of indirect nuclear spin-spin couplings. The obtained results have been compared with the corresponding results of the reference method with traditional evaluation of the exchange-correlation kernel, i.e., without employing the fitted electron densities. Overall good agreement between both methods was observed, though the new approach tends to give values by about 4%-5% higher than the reference method. On the average, the solution of the coupled perturbed equations with the new scheme is about 8.5 times faster compared to the reference method.
International Nuclear Information System (INIS)
Křístková, Anežka; Malkin, Vladimir G.; Komorovsky, Stanislav; Repisky, Michal; Malkina, Olga L.
2015-01-01
In this work, we report on the development and implementation of a new scheme for efficient calculation of indirect nuclear spin-spin couplings in the framework of four-component matrix Dirac-Kohn-Sham approach termed matrix Dirac-Kohn-Sham restricted magnetic balance resolution of identity for J and K, which takes advantage of the previous restricted magnetic balance formalism and the density fitting approach for the rapid evaluation of density functional theory exchange-correlation response kernels. The new approach is aimed to speedup the bottleneck in the solution of the coupled perturbed equations: evaluation of the matrix elements of the kernel of the exchange-correlation potential. The performance of the new scheme has been tested on a representative set of indirect nuclear spin-spin couplings. The obtained results have been compared with the corresponding results of the reference method with traditional evaluation of the exchange-correlation kernel, i.e., without employing the fitted electron densities. Overall good agreement between both methods was observed, though the new approach tends to give values by about 4%-5% higher than the reference method. On the average, the solution of the coupled perturbed equations with the new scheme is about 8.5 times faster compared to the reference method
International Nuclear Information System (INIS)
Furukawa, Takeshi; Wakui, Takashi; Yang, Xiaofei; Fujita, Tomomi; Imamura, Kei; Yamaguchi, Yasuhiro; Tetsuka, Hiroki; Tsutsui, Yoshiki; Mitsuya, Yosuke; Ichikawa, Yuichi; Ishibashi, Yoko; Yoshida, Naoki; Shirai, Hazuki; Ebara, Yuta; Hayasaka, Miki; Arai, Shino; Muramoto, Sosuke
2013-01-01
Highlights: • Development of a novel nuclear laser spectroscopy method using superfluid helium. • Observation of the Zeeman resonance with the 85 Rb beam introduced into helium. • Demonstration of deducing the nuclear spins from the observed resonance spectrum. -- Abstract: We have been developing a novel nuclear laser spectroscopy method “OROCHI” for determining spins and moments of exotic radioisotopes. In this method, we use superfluid helium as a stopping material of energetic radioisotope beams and then stopped radioisotope atoms are subjected to in situ laser spectroscopy in superfluid helium. To confirm the feasibility of this method for rare radioisotopes, we carried out a test experiment using a 85 Rb beam. In this experiment, we have successfully measured the Zeeman resonance signals from the 85 Rb atoms stopped in superfluid helium by laser-RF double resonance spectroscopy. This method is efficient for the measurement of spins and moments of more exotic nuclei
Nuclear magnetic resonance applied to the study of polymeric nano composites
International Nuclear Information System (INIS)
Tavares, Maria Ines Bruno
2011-01-01
Polymers and nanoparticles based nano composites were prepared by intercalation by solution. The obtained nano composites were characterized mainly by the nuclear magnetic spectroscopy (NMR), applying the analysis of carbon-13 (polymeric matrix), silicon-29 (nanoparticle), and by determination of spin-lattice relaxation of the hydrogen nucleus (T 1 H) (polymeric matrix). The NMR have presented a promising technique in the characterization of the nano charge dispersion in the studied polymeric matrixes.
Albert, Brice J; Pahng, Seong Ho; Alaniva, Nicholas; Sesti, Erika L; Rand, Peter W; Saliba, Edward P; Scott, Faith J; Choi, Eric J; Barnes, Alexander B
2017-10-01
Cryogenic sample temperatures can enhance NMR sensitivity by extending spin relaxation times to improve dynamic nuclear polarization (DNP) and by increasing Boltzmann spin polarization. We have developed an efficient heat exchanger with a liquid nitrogen consumption rate of only 90L per day to perform magic-angle spinning (MAS) DNP experiments below 85K. In this heat exchanger implementation, cold exhaust gas from the NMR probe is returned to the outer portion of a counterflow coil within an intermediate cooling stage to improve cooling efficiency of the spinning and variable temperature gases. The heat exchange within the counterflow coil is calculated with computational fluid dynamics to optimize the heat transfer. Experimental results using the novel counterflow heat exchanger demonstrate MAS DNP signal enhancements of 328±3 at 81±2K, and 276±4 at 105±2K. Copyright © 2017 Elsevier Inc. All rights reserved.
Nuclear spin polarized alkali beams (Li and Na): Production and acceleration
International Nuclear Information System (INIS)
Jaensch, H.; Becker, K.; Blatt, K.; Leucker, H.; Fick, D.
1987-01-01
Recent improvements of the Heidelberg source for polarized heavy ions (PSI) are described. By means of optical pumping in combination with the existing multipole separation magnet the beam figure of merit (polarization 2 x intensity) was doubled. 7 Li and 23 Na atomic beams can now be produced in pure hyperfine magnetic substates. Fast switching of the polarization is achieved by an adiabatic medium field transition. The hyperfine magnetic substate population is determined by laser-induced fluorescence spectroscopy. In routine operation atomic beams with nuclear polarization p α ≥0.85 (α=z, zz) are obtained. The acceleration of polarized 23 Na - ions by a 12 MV tandem accelerator introduces a new problem: the energy at the terminal stripper foil is not sufficient to produce a usable yield of naked ions. For partially stripped ions hyperfine interaction of the remaining electrons with the nuclear spin reduces the nuclear polarization. Using in addition the Heidelberg postaccelerator 23 Na 9+ beams of energies between 49 and 184 MeV were obtained with an alignment on target of P zz ≅0.45. 7 Li beams have also been accelerated up to 45 MeV with an alignment of P zz =0.69. (orig.)
International Nuclear Information System (INIS)
Soubies, B.; Boulc'h, J.; Elsensohn, O.; Le Meur, M.; Henry, J.Y.
1994-01-01
The process of licensing nuclear power plants for operation consists of mandatory steps featuring detailed examination of the instrumentation and control system. Significant changes were introduced by the operator in the process of designing and producing 1400 MWe pressurized water reactor safety systems and, in particular, in the case of the Digital Integrated Protection System, (French abbreviation SPIN). The methodology applied by the Institute of Protection and Nuclear Safety (IPSN) to examine the software of this system is described. It consists of the methods used by the manufacturer to develop SPIN software for the 1400 MWe PWRs, and the approach adopted by the IPSN to evaluate SPIN safety softwares of the protection system for the N4 series of reactors. (R.P.). 2 refs
Modelling the molecular composition and nuclear-spin chemistry of collapsing prestellar sources
Hily-Blant, P.; Faure, A.; Rist, C.; Pineau des Forêts, G.; Flower, D. R.
2018-04-01
We study the gravitational collapse of prestellar sources and the associated evolution of their chemical composition. We use the University of Grenoble Alpes Astrochemical Network (UGAN), which includes reactions involving the different nuclear-spin states of H2, H+3, and of the hydrides of carbon, nitrogen, oxygen, and sulfur, for reactions involving up to seven protons. In addition, species-to-species rate coefficients are provided for the ortho/para interconversion of the H_3^+ + H2 system and isotopic variants. The composition of the medium is followed from an initial steady state through the early phase of isothermal gravitational collapse. Both the freeze-out of the molecules on to grains and the coagulation of the grains were incorporated in the model. The predicted abundances and column densities of the spin isomers of ammonia and its deuterated forms are compared with those measured recently towards the prestellar cores H-MM1, L16293E, and Barnard B1. We find that gas-phase processes alone account satisfactorily for the observations, without recourse to grain-surface reactions. In particular, our model reproduces both the isotopologue abundance ratios and the ortho:para ratios of NH2D and NHD2 within observational uncertainties. More accurate observations are necessary to distinguish between full scrambling processes—as assumed in our gas-phase network—and direct nucleus- or atom-exchange reactions.
International Nuclear Information System (INIS)
Schlick, S.; Kevan, L.
1982-01-01
The room temperature gamma irradiation degradation of the lithographic polymers, poly(methylmethacrylate) (PMMA), poly(methyl-α-chloroacrylate) (PMCA), poly(methyl-α-fluoroacrylate) (PMFA), and poly(methylacrylonitrile) (PMCN), have been studied by electron spin resonance and electron nuclear double resonance (ENDOR) to assess their molecular degradation processes of relevance to electron beam lithography. Two classes of radicals are found, chain radicals and chain scission radicals. PMMA and PMCA mainly form chain scission radicals consistent with degradation while for PMCN the resolution is poorer, and this is only probable. PMFA forms mainly chain radicals consistent with predominant crosslinking. The total radical yield is greatest in PMCA and PMCN. ENDOR is used to assess the compactness of the radiation degradation region for PMMA and PMCA and hence the potential resolution of the resist; this appears to be about the same for these methacrylate polymers
Theory of radiative muon capture with applications to nuclear spin and isospin doublets
International Nuclear Information System (INIS)
Hwang, W.P.; Primakoff, H.
1978-01-01
A theory of radiative muon capture, with applications to nuclear spin and isospin doublets, is formulated on the basis of the conservation of the hadronic electromagnetic current, the conservation of the hadronic weak polar currents, the partial conservation of the hadronic weak axial-vector current, the SU(2) x SU(2) current algebra for the various hadronic current, and a simplifying dynamical approximation for the hadron-radiating part of the transition amplitude: the ''linearity hypothesis''. The resultant total transition amplitude, which also includes the muon-radiating part, is worked out explicitly and applied to treat the processes μ - p → ν/sub μ/nγ and μ - 3 He → ν/sub μ/ 3 Hγ
International Nuclear Information System (INIS)
Heckmann, J.; Meyer, W.; Radtke, E.; Reicherz, G.; Goertz, S.
2006-01-01
ESR spectroscopy is an important tool in polarized solid target material research, since it allows us to study the paramagnetic centers, which are used for the dynamic nuclear polarization (DNP). The polarization behavior of the different target materials is strongly affected by the properties of these centers, which are added to the diamagnetic materials by chemical doping or irradiation. In particular, the ESR linewidth of the paramagnetic centers is a very important parameter, especially concerning the deuterated target materials. In this paper, the results of the first precise ESR measurements of the deuterated target materials at a DNP-relevant magnetic field of 2.5 T are presented. Moreover, these results allowed us to experimentally study the correlation between ESR linewidth and maximum deuteron polarization, as given by the spin-temperature theory
Role of nuclear penetration effects in spin assignments. [J, transitions, internal conversion
Energy Technology Data Exchange (ETDEWEB)
Sahota, H S [Punjabi Univ., Patiala (India). Dept. of Physics
1976-04-01
Nuclear penetrations have been found to affect the internal conversion process of the retarded magnetic dipole transitions. In all cases where the penetration coefficient has been found to be essentially different from unity the transition is 1-forbidden. This criterian has been applied to the case of 191 keV transition in /sup 197/Au where the spin of the 268 keV level could not be deduced uniquely by any of the existing methods. The result is that the 199 keV transition has a dynamic contribution to its internal conversion process with the penetration coefficient lambda = 5.5 +- 0.9. To illustrate the applicability of the criterian further two more cases namely that of the 92 keV transition in /sup 131/Cs and 182 keV transition in /sup 129/Cs are also included.
Mentink-Vigier, Frédéric; Binet, Laurent; Vignoles, Gerard; Gourier, Didier; Vezin, Hervé
2010-11-01
The hyperfine interactions of the unpaired electron with eight surrounding G69a and G71a nuclei in Ti-doped β-Ga2O3 were analyzed by electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) spectroscopies. They are dominated by strong isotropic hyperfine couplings due to a direct Fermi contact interaction with Ga nuclei in octahedral sites of rutile-type chains oriented along b axis, revealing a large anisotropic spatial extension of the electron wave function. Titanium in β-Ga2O3 is thus best described as a diffuse (Ti4+-e-) pair rather than as a localized Ti3+ . Both electron and G69a nuclear spin Rabi oscillations could be observed by pulsed EPR and pulsed ENDOR, respectively. The electron spin decoherence time is about 1μs (at 4 K) and an upper bound of 520μs (at 8 K) is estimated for the nuclear decoherence time. Thus, β-Ga2O3:Ti appears to be a potential spin-bus system for quantum information processing with a large nuclear spin quantum register.
Fuson, Michael M.
2017-01-01
Laboratories studying the anisotropic rotational diffusion of bromobenzene using nuclear spin relaxation and molecular dynamics simulations are described. For many undergraduates, visualizing molecular motion is challenging. Undergraduates rarely encounter laboratories that directly assess molecular motion, and so the concept remains an…
Thurber, Kent R; Potapov, Alexey; Yau, Wai-Ming; Tycko, Robert
2013-01-01
We describe an apparatus for solid state nuclear magnetic resonance (NMR) with dynamic nuclear polarization (DNP) and magic-angle spinning (MAS) at 20-25 K and 9.4 Tesla. The MAS NMR probe uses helium to cool the sample space and nitrogen gas for MAS drive and bearings, as described earlier, but also includes a corrugated waveguide for transmission of microwaves from below the probe to the sample. With a 30 mW circularly polarized microwave source at 264 GHz, MAS at 6.8 kHz, and 21 K sample temperature, greater than 25-fold enhancements of cross-polarized (13)C NMR signals are observed in spectra of frozen glycerol/water solutions containing the triradical dopant DOTOPA-TEMPO when microwaves are applied. As demonstrations, we present DNP-enhanced one-dimensional and two-dimensional (13)C MAS NMR spectra of frozen solutions of uniformly (13)C-labeled l-alanine and melittin, a 26-residue helical peptide that we have synthesized with four uniformly (13)C-labeled amino acids. Published by Elsevier Inc.
The nuclear deformation versus spin-flip like excitations and the suppression of the 2νββ amplitude
International Nuclear Information System (INIS)
Raduta, A.A.; Delion, D.S.; Faessler, Amand
1997-01-01
We were the first who investigated the influence of spin-flip and non-spin-flip configuration on the separation of the transition amplitude of the Gamow-Teller double beta decay. A realistic Hamiltonian and a projected spherical single particle basis is considered, while the effects are generated by three antagonistic sources: spin-flip, non-spin-flip like excitation and nuclear deformation. Moreover, by a smooth variation of a deformation parameter one could bridge the spherical and deformed pictures. Although our application is not aimed at describing the experimental situation we chose as input data those corresponding to the transition 82 Se → 82 Kr. For near spherical case there are two resonances in M GT , one having a spin-flip structure and identified as GT resonance and one of non-spin-flip structure, placed at low energy. For large deformation and vanishing g pp coupling constant there are two resonances of spin-flip and non-spin-flip natures (ΔI = 1 and 0, respectively) and located at the same energy, what indicates that the deformation acts against the separation of this resonances. In conclusion, our calculation showed that the mechanism of M GT suppression is different for spherical and deformed nuclei. In both cases approaching the critical value of g pp where the RPA breaks down, a lot of strength is accumulated in lowest RPA state and, while in the spherical case this has a non spin-flip nature, in the deformed case the state is a mixture of both types of configurations
International Nuclear Information System (INIS)
Lainetti, Paulo E.O.
2013-01-01
Nuclear spin-off has at least two dimensions. It may provide benefits to the society such as enlarge knowledge base, strengthen infrastructure and benefit technology development. Besides this, to emphasize that some useful technologies elapsed from nuclear activities can affect favorably the public opinion about nuclear energy. In this paper is described a technology developed initially by the Rockwell Int. company in the USA more than thirty years ago to solve some problems of nuclear fuel cycle wastes. For different reasons the technology was not employed. In the last years the interest in the technology was renewed and IPEN has developed his version of the method applicable mainly to the safe degradation of hazardous wastes. This study was motivated by the world interest in the development of advanced processes of waste decomposition, due to the need of safer decomposition processes, particularly for the POPs - persistent organic pollutants and particularly for the organ chlorides. A tendency observed at several countries is the adoption of progressively more demanding legislation for the atmospheric emissions, resultants of the waste decomposition processes. The suitable final disposal of hazardous organic wastes such as PCBs (polychlorinated biphenyls), pesticides, herbicides and hospital residues constitutes a serious problem. In some point of their life cycles, these wastes should be destroyed, in reason of the risk that they represent for the human being, animals and plants. The process involves using a chemical reactor containing molten salts, sodium carbonate or some alkaline carbonates mixtures to decompose the organic waste. The decomposition is performed by submerged oxidation and the residue is injected below the surface of a turbulent salt bath along with the oxidizing agent. Decomposition of halogenated compounds, among which some pesticides, is particularly effective in molten salts. The process presents properties such as intrinsically safe
Proposal to realize a cost breakthrough in carbon-13 production by photochemical separation
International Nuclear Information System (INIS)
Marling, J.B.
1979-10-01
A cost breakthrough can now be made in photochemical production of the rare stable isotope carbon-13. This cost breakthrough is achieved by CO 2 laser infrared multiple-photon dissociation of any of several halocarbons (Freon derivatives) such as CF 3 Cl, CF 3 Br, or CF 2 Cl 2 . The single-step carbon-13 enrichment factor for this process is approximately 50, yielding 30% pure C-13 in one step, or up to 97% pure C-13 in two steps. A three-fold carbon-13 cost reduction to below $20/gram is expected to be achieved in a small laboratory-scale demonstration facility capable of producing 4 to 8 kg/year of carbon-13, using presently available pulsed CO 2 TEA lasers at an average power level of 50 watts. Personnel costs dominate the attainable C-13 production costs in a small photochemical enrichment facility. A price reduction to $2/gm carbon-13 is feasible at carbon-13 production levels of 100 to 1000 kg/year, dominated by the Freon raw material costs
Mananga, Eugene Stephane; Charpentier, Thibault
2015-04-01
In this paper we present a theoretical perturbative approach for describing the NMR spectrum of strongly dipolar-coupled spin systems under fast magic-angle spinning. Our treatment is based on two approaches: the Floquet approach and the Floquet-Magnus expansion. The Floquet approach is well known in the NMR community as a perturbative approach to get analytical approximations. Numerical procedures are based on step-by-step numerical integration of the corresponding differential equations. The Floquet-Magnus expansion is a perturbative approach of the Floquet theory. Furthermore, we address the " γ -encoding" effect using the Floquet-Magnus expansion approach. We show that the average over " γ " angle can be performed for any Hamiltonian with γ symmetry.
Altuntaş, Emine; Ammon, Jeffrey; Cahn, Sidney B.; DeMille, David
2018-04-01
Nuclear-spin-dependent parity violation (NSD-PV) effects in atoms and molecules arise from Z0 boson exchange between electrons and the nucleus and from the magnetic interaction between electrons and the parity-violating nuclear anapole moment. It has been proposed to study NSD-PV effects using an enhancement of the observable effect in diatomic molecules [D. DeMille et al., Phys. Rev. Lett. 100, 023003 (2008), 10.1103/PhysRevLett.100.023003]. Here we demonstrate highly sensitive measurements of this type, using the test system 138Ba19F. We show that systematic errors associated with our technique can be suppressed to at least the level of the present statistical sensitivity. With ˜170 h of data, we measure the matrix element W of the NSD-PV interaction with uncertainty δ W /(2 π )<0.7 Hz for each of two configurations where W must have different signs. This sensitivity would be sufficient to measure NSD-PV effects of the size anticipated across a wide range of nuclei.
Energy Technology Data Exchange (ETDEWEB)
Robin, Caroline; Litvinova, Elena [Western Michigan University, Department of Physics, Kalamazoo, MI (United States)
2016-07-15
A new theoretical approach to spin-isospin excitations in open-shell nuclei is presented. The developed method is based on the relativistic meson-exchange nuclear Lagrangian of Quantum Hadrodynamics and extends the response theory for superfluid nuclear systems beyond relativistic quasiparticle random phase approximation in the proton-neutron channel (pn-RQRPA). The coupling between quasiparticle degrees of freedom and collective vibrations (phonons) introduces a time-dependent effective interaction, in addition to the exchange of pion and ρ-meson taken into account without retardation. The time-dependent contributions are treated in the resonant time-blocking approximation, in analogy to the previously developed relativistic quasiparticle time-blocking approximation (RQTBA) in the neutral (non-isospin-flip) channel. The new method is called proton-neutron RQTBA (pn-RQTBA) and is applied to the Gamow-Teller resonance in a chain of neutron-rich nickel isotopes {sup 68-78}Ni. A strong fragmentation of the resonance along with quenching of the strength, as compared to pn-RQRPA, is obtained. Based on the calculated strength distribution, beta-decay half-lives of the considered isotopes are computed and compared to pn-RQRPA half-lives and to experimental data. It is shown that a considerable improvement of the half-life description is obtained in pn-RQTBA because of the spreading effects, which bring the lifetimes to a very good quantitative agreement with data. (orig.)
Demonstration of a Sensitive Method to Measure Nuclear-Spin-Dependent Parity Violation
Altuntaş, Emine; Ammon, Jeffrey; Cahn, Sidney B.; DeMille, David
2018-04-01
Nuclear-spin-dependent parity violation (NSD-PV) effects in atoms and molecules arise from Z0 boson exchange between electrons and the nucleus, and from the magnetic interaction between electrons and the parity-violating nuclear anapole moment. We demonstrate measurements of NSD-PV that use an enhancement of the effect in diatomic molecules, here using the test system 138Ba 19. Our sensitivity surpasses that of any previous atomic parity violation measurement. We show that systematic errors can be suppressed to at least the level of the present statistical sensitivity. We measure the matrix element W of the NSD-PV interaction with total uncertainty δ W /(2 π )<0.7 Hz , for each of two configurations where W must have different signs. This sensitivity would be sufficient to measure NSD-PV effects of the size anticipated across a wide range of nuclei including 137Ba in 137BaF, where |W |/(2 π )≈5 Hz is expected.
Nuclear spin-isospin excitations from covariant quasiparticle-vibration coupling
Robin, Caroline; Litvinova, Elena
2016-09-01
Methods based on the relativistic Lagrangian of quantum hadrodynamics and nuclear field theory provide a consistent framework for the description of nuclear excitations, naturally connecting the high- and medium-energy scales of mesons to the low-energy domain of nucleonic collective motion. Applied in the neutral channel, this approach has been quite successful in describing the overall transition strength up to high excitation energies, as well as fine details of the low-lying distribution. Recently, this method has been extended to the description of spin-isospin excitations in open-shell nuclei. In the charge-exchange channel, the coupling between nucleons and collective vibrations generates a time-dependent proton-neutron effective interaction, in addition to the static pion and rho-meson exchange, and introduces complex configurations that induce fragmentation and spreading of the resonances. Such effects have a great impact on the quenching of the strength and on the computing of weak reaction rates that are needed for astrophysics modeling. Gamow-Teller transitions in medium-mass nuclei and associated beta-decay half-lives will be presented. Further developments aiming to include additional ground-state correlations will also be discussed. This work is supported by US-NSF Grants PHY-1404343 and PHY-1204486.
Weber, Stefan; Kothe, Gerd; Norris, James R.
1997-04-01
The influence of anisotropic hyperfine interaction on transient nutation electron paramagnetic resonance (EPR) of light-induced spin-correlated radical pairs is studied theoretically using the density operator formalism. Analytical expressions for the time evolution of the transient EPR signal during selective microwave excitation of single transitions are derived for a model system comprised of a weakly coupled radical pair and one hyperfine-coupled nucleus with I=1/2. Zero-quantum electron coherence and single-quantum nuclear coherence are created as a result of the sudden light-induced generation of the radical pair state from a singlet-state precursor. Depending on the relative sizes of the nuclear Zeeman frequency and the secular and pseudo-secular parts of the hyperfine coupling, transitions between levels with different nuclear spin orientations are predicted to modulate the time-dependent EPR signal. These modulations are in addition to the well-known transient nutations and electron zero-quantum precessions. Our calculations provide insight into the mechanism of recent experimental observations of coherent nuclear modulations in the time-resolved EPR signals of doublets and radical pairs. Two distinct mechanisms of the modulations are presented for various microwave magnetic field strengths. The first modulation scheme arises from electron and nuclear coherences initiated by the laser excitation pulse and is "read out" by the weak microwave magnetic field. While the relative modulation depth of these oscillations with respect to the signal intensity is independent of the Rabi frequency, ω1, the frequencies of this coherence phenomenon are modulated by the effective microwave amplitude and determined by the nuclear Zeeman interaction and hyperfine coupling constants as well as the electron-electron spin exchange and dipolar interactions between the two radical pair halves. In a second mechanism the modulations are both created and detected by the microwave
International Nuclear Information System (INIS)
Gerken, T.A.; Jentoft, N.
1987-01-01
Nearly all of the resonances in the 13 C NMR spectrum of porcine submaxillary mucin glycoprotein (PSM) have been assigned to the peptide core carbons and to the carbons in the eight different oligosaccharide side chains that arise from the incomplete biosynthesis of the sialylated A blood group pentasaccharide. By use of these assignments, a nearly complete structural analysis of intact PSM has been performed without resorting to degradative chemical methods. Considerable structural variability in the carbohydrate side chains was observed between mucins obtained from different animals, while no variability was observed between glands in a single animal. The dynamics of the PSM core and carbohydrate side chains were examined by using the carbon-13 nuclear magnetic resonance relaxation times and nuclear Overhauser enhancements of each assigned carbon resonance. The peptide core of PSM exhibits internal segmental flexibility that is virtually identical with that of ovine submaxillary mucin (OSM), whose carbohydrate side chain consists of the α-NeuNAc(2-6)α-Ga1NAc disaccharide. These results differ from most reports of glycoprotein dynamics, which typically find the terminal carbohydrate residues to be undergoing rapid internal rotation about their terminal glycosidic bonds. The results reported here are consistent with previous studies on the conformations of the A and H determinants derived from model oligosaccharides and further indicate that the conformations of these determinants are unchanged when covalently bound to the mucin peptide core. In spite of their carbohydrate side-chain heterogeneity, mucins appear to be ideal glycoproteins for the study of O-linked oligosaccharide conformation and dynamics and for the study of the effects of glycosylation on polypeptide conformation and dynamics
Klos, P.; Menéndez, J.; Gazit, D.; Schwenk, A.
2013-01-01
We perform state-of-the-art large-scale shell-model calculations of the structure factors for elastic spin-dependent WIMP scattering off 129,131Xe, 127I, 73Ge, 19F, 23Na, 27Al, and 29Si. This comprehensive survey covers the non-zero-spin nuclei relevant to direct dark matter detection. We include a pedagogical presentation of the formalism necessary to describe elastic and inelastic WIMP-nucleus scattering. The valence spaces and nuclear interactions employed have been previously used in nucl...
Energy Technology Data Exchange (ETDEWEB)
Chapelet-Letourneux, G [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires
1967-07-01
N-t-butyl-N-phenyl nitroxide is obtained by: a) action of t-butyl-magnesium chloride on nitrobenzene, or of phenyl-magnesium bromide on nitro-t-butane, b) oxidation of N-t-butyl-N-phenylhydroxylamine, c) oxidation of N-t-butylaniline. In these latter two cases, it has been possible to isolate the pure radical and to study it using UV, IR and EPR. It decomposes to give N-t-butylaniline and the N-oxide of N-t-butyl-p-quinon-imine. The action of peracids such as p-nitro-perbenzoic or m-chloro-perbenzoic acids on amines or hydroxylamines leads to the formation of stable or unstable nitroxide radicals easily observable by EPR. Finally, with a view to obtaining definite values for the coupling between the free electron of a nitroxide and carbon 13, the preparation of such radicals marked with {sup 13}C in the {alpha} or {beta} position of the nitroxide function has been carried out. The coupling with an {alpha} carbon 13 is negative and does not appear to vary with the spin density on the nitrogen. The interaction with the p nuclei of the nitrogen depends on the nature of the substituents: the two benzyl protons have a hyperfine splitting a{sub H} which is always less than that of the ethyl. On the other hand, the {sup 13}C coupling is greater in the first case. The usually adopted conformations for the compounds having the carbonyl group cannot account for the observed values of the {beta} couplings. (author) [French] Le N-t-butyl-N-phenyl nitroxyde est obtenu par: a) action du chlorure de t-butylmagnesium sur le nitrobenzene, ou du bromure de phenylmagnesium sur le nitro-t-butane, b) oxydation de la N-t-butyl-N-phenylhydroxylamine, c) oxydation de la N-t-butylaniline. Dans ces deux derniers cas, le radical a pu etre isole pur et etudie par UV, IR et RPE. Il se decompose en N-t-butylaniline et N-oxyde de N-t-butyl-p-quinonimine. L'action de peracides (p-nitroperbenzoique ou m-chloroperbenzoique) sur des amines ou des hydroxylamines conduit a des radicaux nitroxydes
Note on sideband intensities in one-dimensional magic angle spinning nuclear magnetic resonance
Well, van H.F.J.M.; Vankan, J.M.J.; Janssen, A.J.E.M.
1991-01-01
It is well known that in the NMR spectra of solid samples spinning at the magic angle centrebands and sidebands occur. The centrebands are found at the isotropic value of the chemical shift and the sidebands are found at integral multiples of the spinning frequency as long as the spinning frequency
Energy Technology Data Exchange (ETDEWEB)
Grohmann, Thomas
2012-05-31
In this thesis the wave packet dynamics of nuclear spin isomers of polyatomic molecules after interaction with static and time-dependent magnetic fields and moderate intense nonresonant laser pulses is investigated. In particular, the process of inducing (internal) molecular rotation as well as alignment of molecules by manipulating their rotational or rotational-torsional degrees of freedom is studied. In the first part of the thesis all theoretical concepts for identifying nuclear spin isomers and for describing their quantum dynamics will be discussed. Especially the symmetrization postulate and themolecular symmetry group will be introduced and illustrated for some examples of molecules. These concepts will be extended to the case of identifying nuclear spin isomers in the presence of an external field. In the second part it is shown for nitromethane that magnetic fields are able to induce unidirectional rotations in opposite directions for different nuclear spin isomers of molecules containing methyl groups if the dipolar interaction is included. Additionally, it is demonstrated that different nuclear spin isomers of a chemical compound may show different alignment after the interaction with a moderate intense laser pulse. As shown for the rigid symmetric top propadien and the rigid asymmetric tops ethene and analogues, distinct pairs of nuclear spin isomers show at certain points in time a complementary behavior: while one isomer is showing alignment the partner isomer is showing anti-alignment. Moreover, it is illustrated that not every nuclear spin isomer can be aligned equally efficient. The alignment of non-rigid molecules is considered as well. As an example for a molecule with feasible torsion in the electronic ground state, the alignment of diboron tetrafluoride is investigated. It becomes apparent that not only rotational but also the torsional dynamics of the molecules is nuclear spin selective; different nuclear spin isomers have at distinct points
International Nuclear Information System (INIS)
Carretta, P.; Rigamonti, A.; Sala, R.
1997-01-01
63 Cu nuclear quadrupole resonance (NQR) relaxation measurements in La 2 CuO 4 doped Zn are used in order to investigate the temperature dependence of the in-plane magnetic correlation length ξ 2D and the effects associated to spin vacancies in two dimensional quantum Heisenberg antiferromagnets (QHAF). The relaxation rates T 1 -1 and T 2 -1 have been related to the static generalized susceptibility χ(q,0) and to the decay rate Γ q of the normal excitations. By using scaling arguments for χ(q,0) and Γ q , the relaxation rates have been expressed in close form in terms of ξ 2D (x,T) and its dependence on temperature and spin doping x thus extracted. The experimental findings are analyzed in light of the renormalized classical (RC) and quantum critical (QC) behaviors predicted for ξ 2D by recent theories for S=1/2 HAF in square lattices. It is first shown that in pure La 2 CuO 4 , ξ 2D is consistent with a RC regime up to about 900 K, with tendency toward the QC regime above. The spin vacancies reduce the Nacute eel temperature according to the law T N (x)∼T N (0)(1 3.5x). From the temperature dependence of 63 Cu NQR relaxation rate T 1 -1 , T 2 -1 and from the composition dependence of T N it is consistently proved that the effect on ξ 2D can be accounted for by the modification of the spin stiffness in a simple dilutionlike model, the system still remaining in the RC regime, at least for T≤900 K. copyright 1997 American Institute of Physics
Energy Technology Data Exchange (ETDEWEB)
Soubies, B.; Henry, J.Y.; Le Meur, M. [and others
1995-04-01
1300 MWe pressurised water reactors (PWRs), like the 1400 MWe reactors, operate with microprocessor-based safety systems. This is particularly the case for the Digital Integrated Protection System (SPIN), which trips the reactor in an emergency and sets in action the safeguard functions. The softwares used in these systems must therefore be highly dependable in the execution of their functions. In the case of SPIN, three players are working at different levels to achieve this goal: the protection system manufacturer, Merlin Gerin; the designer of the nuclear steam supply system, Framatome; the operator of the nuclear power plants, Electricite de France (EDF), which is also responsible for the safety of its installations. Regulatory licenses are issued by the French safety authority, the Nuclear Installations Safety Directorate (French abbreviation DSIN), subsequent to a successful examination of the technical provisions adopted by the operator. This examination is carried out by the IPSN and the standing group on nuclear reactors. This communication sets out: the methods used by the manufacturer to develop SPIN software for the 1400 MWe PWRs (N4 series); the approach adopted by the IPSN to evaluate the safety software of the protection system for the N4 series of reactors.
Energy Technology Data Exchange (ETDEWEB)
Merkulov, I A; Papava, Y I; Ponomarenko, V V [Leningradskij Gosudarstvennyj Univ., Leningrad (Russian Federation); Vasiliev, S I [Carleton Univ., Ottawa, ON (Canada). Dept. of Physics
1988-02-01
A phase transition of the nuclear spin system of a solid with dipolar and indirect scalar interactions is considered. Monte Carlo simulations of the spin-system isothermic states and of the adiabatic demagnetization process have been made. The structures and energies of the ground states and the values of the critical temperatures, T[sub C], and minimal polarizations, [rho][sub C], at which adiabatic demagnetization leads to spontaneous spin ordering, calculated for the GaAs and CaF[sub 2] nuclear spin systems, are presented. The results of numerical simulations are compared with the experimental data for CaF[sub 2]. The Weiss-field model is extended to the case of adiabatic demagnetization. The fluctuations of the local field are taken into account in the Gaussian approximation. It is shown that the proposed approach allows one to obtain asymptotically correct results both for T >> T[sub C] and T << T[sub C]. The results of the calculations in the Gaussian approximation are compared with the numerical simulations. (10 refs., 9 figs., tab.).
International Nuclear Information System (INIS)
Hejduk, Michal; Dohnal, Petr; Varju, Jozef; Rubovič, Peter; Plašil, Radek; Glosík, Juraj
2012-01-01
We have applied a continuous-wave near-infrared cavity ring-down spectroscopy method to study the parameters of a H 3 + -dominated plasma at temperatures in the range 77–200 K. We monitor populations of three rotational states of the ground vibrational state corresponding to para and ortho nuclear spin states in the discharge and the afterglow plasma in time and conclude that abundances of para and ortho states and rotational temperatures are well defined and stable. The non-trivial dependence of a relative population of para- H 3 + on a relative population of para-H 2 in a source H 2 gas is described. The results described in this paper are valuable for studies of state-selective dissociative recombination of H 3 + ions with electrons in the afterglow plasma and for the design of sources of H 3 + ions in a specific nuclear spin state. (paper)
Hejduk, Michal; Dohnal, Petr; Varju, Jozef; Rubovič, Peter; Plašil, Radek; Glosík, Juraj
2012-04-01
We have applied a continuous-wave near-infrared cavity ring-down spectroscopy method to study the parameters of a H_3^+ -dominated plasma at temperatures in the range 77-200 K. We monitor populations of three rotational states of the ground vibrational state corresponding to para and ortho nuclear spin states in the discharge and the afterglow plasma in time and conclude that abundances of para and ortho states and rotational temperatures are well defined and stable. The non-trivial dependence of a relative population of para- H_3^+ on a relative population of para-H2 in a source H2 gas is described. The results described in this paper are valuable for studies of state-selective dissociative recombination of H_3^+ ions with electrons in the afterglow plasma and for the design of sources of H_3^+ ions in a specific nuclear spin state.
Dynamical suppression of nuclear-spin decoherence time in Si and GaAs using inversion pulses
International Nuclear Information System (INIS)
Watanabe, S.; Harada, J.; Sasaki, S.; Hirayama, Y.
2007-01-01
We found that nuclear-spin decoherence is suppressed by applying inversion pulses such as alternating phase Carr-Purcell (APCP) and Carr-Purcell-Meiboom-Gill (CPMG) sequences in silicon and GaAs. The decoherence time reaches ∼1.3s by applying inversion pulses, which is ∼200 times as long as the characteristic decay time obtained from the Hahn echo sequence (∼6ms) in silicon
Lamb shift and fine structure at n =2 in a hydrogenlike muonic atom with the nuclear spin I =0
Korzinin, Evgeny Yu.; Shelyuto, Valery A.; Ivanov, Vladimir G.; Karshenboim, Savely G.
2018-01-01
The paper is devoted to the Lamb shift and fine structure in a hydrogenlike muonic atom with a spinless nucleus up to the order α5m with all the recoil corrections included. Enhanced contributions of a higher order are also considered. We present the results on the pure QED contribution and on the finite-nuclear-size contribution, proportional to RN2, with the higher-order corrections included. We also consider the consistency of the pure QED theory and the evaluation of the nuclear-structure effects. Most of the QED theory is the same as the theory for the case of the nuclear spin 1/2. Additional nuclear-spin-dependent terms are considered in detail. The issue of the difference for the theories with a spinor nucleus and a scalar one is discussed for the recoil contributions in the order (Zα ) 4m ,α (Zα ) 4m , and (Zα ) 5m . The numerical results are presented for the muonic atoms with two lightest scalar nuclei, helium-4 and beryllium-10. We compare the theory of those muonic atoms with theory for the muonic hydrogen. Some higher-order finite-nuclear-size corrections for the Lamb shift in muonic hydrogen are revisited.
Dynamic-angle spinning and double rotation of quadrupolar nuclei
International Nuclear Information System (INIS)
Mueller, K.T.; California Univ., Berkeley, CA
1991-07-01
Nuclear magnetic resonance (NMR) spectroscopy of quadrupolar nuclei is complicated by the coupling of the electric quadrupole moment of the nucleus to local variations in the electric field. The quadrupolar interaction is a useful source of information about local molecular structure in solids, but it tends to broaden resonance lines causing crowding and overlap in NMR spectra. Magic- angle spinning, which is routinely used to produce high resolution spectra of spin-1/2 nuclei like carbon-13 and silicon-29, is incapable of fully narrowing resonances from quadrupolar nuclei when anisotropic second-order quadrupolar interactions are present. Two new sample-spinning techniques are introduced here that completely average the second-order quadrupolar coupling. Narrow resonance lines are obtained and individual resonances from distinct nuclear sites are identified. In dynamic-angle spinning (DAS) a rotor containing a powdered sample is reoriented between discrete angles with respect to high magnetic field. Evolution under anisotropic interactions at the different angles cancels, leaving only the isotropic evolution of the spin system. In the second technique, double rotation (DOR), a small rotor spins within a larger rotor so that the sample traces out a complicated trajectory in space. The relative orientation of the rotors and the orientation of the larger rotor within the magnetic field are selected to average both first- and second-order anisotropic broadening. The theory of quadrupolar interactions, coherent averaging theory, and motional narrowing by sample reorientation are reviewed with emphasis on the chemical shift anisotropy and second-order quadrupolar interactions experienced by half-odd integer spin quadrupolar nuclei. The DAS and DOR techniques are introduced and illustrated with application to common quadrupolar systems such as sodium-23 and oxygen-17 nuclei in solids
Dynamic-angle spinning and double rotation of quadrupolar nuclei
Energy Technology Data Exchange (ETDEWEB)
Mueller, K.T. (Lawrence Berkeley Lab., CA (United States) California Univ., Berkeley, CA (United States). Dept. of Chemistry)
1991-07-01
Nuclear magnetic resonance (NMR) spectroscopy of quadrupolar nuclei is complicated by the coupling of the electric quadrupole moment of the nucleus to local variations in the electric field. The quadrupolar interaction is a useful source of information about local molecular structure in solids, but it tends to broaden resonance lines causing crowding and overlap in NMR spectra. Magic- angle spinning, which is routinely used to produce high resolution spectra of spin-{1/2} nuclei like carbon-13 and silicon-29, is incapable of fully narrowing resonances from quadrupolar nuclei when anisotropic second-order quadrupolar interactions are present. Two new sample-spinning techniques are introduced here that completely average the second-order quadrupolar coupling. Narrow resonance lines are obtained and individual resonances from distinct nuclear sites are identified. In dynamic-angle spinning (DAS) a rotor containing a powdered sample is reoriented between discrete angles with respect to high magnetic field. Evolution under anisotropic interactions at the different angles cancels, leaving only the isotropic evolution of the spin system. In the second technique, double rotation (DOR), a small rotor spins within a larger rotor so that the sample traces out a complicated trajectory in space. The relative orientation of the rotors and the orientation of the larger rotor within the magnetic field are selected to average both first- and second-order anisotropic broadening. The theory of quadrupolar interactions, coherent averaging theory, and motional narrowing by sample reorientation are reviewed with emphasis on the chemical shift anisotropy and second-order quadrupolar interactions experienced by half-odd integer spin quadrupolar nuclei. The DAS and DOR techniques are introduced and illustrated with application to common quadrupolar systems such as sodium-23 and oxygen-17 nuclei in solids.
Carbon-13 isotopic composition of distillation fractions of some Egyptian crude oils
International Nuclear Information System (INIS)
Aly, A.I.M.; Hamza, M.S.; Abd Elsamie, S.G.
1991-01-01
13 C/ 13 C ratios were determined for some crude oil fields in the Gulf of Suez and Western Desert provinces. The crude oil was subjected to distillation at atmospheric pressure and subsequently under vacuum. Distillation fractions were collected at 25 degree C intervals. Carbon-13 content of these distillation fractions showed some differences in the degree of isotopic fractionation. The results were interpreted in view of the age of the source rocks and the degree of maturation process. The carbon-13 content of distillation fractions may be helpful in revealing petroleum mechanisms which can be exploited in exploration.4 fig
Nuclear shape transitions and some properties of aligned-particle configurations at high spin
International Nuclear Information System (INIS)
Koo, T.L.; Chowdhury, P.; Emling, H.
1982-01-01
Two topics are addressed in this paper. First, we discuss the variation of shapes with spin and neutron number for nuclei in the N approx. = 88 transitional region. Second, we present comments on the feeding times of very high spin single-particle yrast states
Collective spin by linearization of the Schrodinger equation for nuclear collective motion
International Nuclear Information System (INIS)
Greiner, M.; Scheid, W.; Herrmann, R.
1988-01-01
The free Schrodinger equation for multipole degrees of freedom is linearized so that energy and momentum operators appear only in first order. As an example, the authors demonstrate the linearization procedure for quadrupole degrees of freedom. The wave function solving this equation carries a spin. The authors derive the operator of the collective spin and its eigen values depending on multipolarity
Energy Technology Data Exchange (ETDEWEB)
Ferracin, Ricardo J. [Sao Carlos Univ., SP (Brazil). Centro de Caracterizacao e Desenvolvimento; Cass, Quezia B.; Bassi, Ana L. [Sao Carlos Univ., SP (Brazil). Lab. de Sintese Organica
1997-12-31
Quitine is a bi-polymer largely found in invertebrates. As most compounds of this class are insoluble in common organic solvents, the des-acetylation percentile was obtained by carbon-13 solid state nuclear magnetic resonance. The methodology is presented. Results are presented 3 refs., 1 figs.
Theory of long-lived nuclear spin states in methyl groups and quantum-rotor induced polarisation.
Dumez, Jean-Nicolas; Håkansson, Pär; Mamone, Salvatore; Meier, Benno; Stevanato, Gabriele; Hill-Cousins, Joseph T; Roy, Soumya Singha; Brown, Richard C D; Pileio, Giuseppe; Levitt, Malcolm H
2015-01-28
Long-lived nuclear spin states have a relaxation time much longer than the longitudinal relaxation time T1. Long-lived states extend significantly the time scales that may be probed with magnetic resonance, with possible applications to transport and binding studies, and to hyperpolarised imaging. Rapidly rotating methyl groups in solution may support a long-lived state, consisting of a population imbalance between states of different spin exchange symmetries. Here, we expand the formalism for describing the behaviour of long-lived nuclear spin states in methyl groups, with special attention to the hyperpolarisation effects observed in (13)CH3 groups upon rapidly converting a material with low-barrier methyl rotation from the cryogenic solid state to a room-temperature solution [M. Icker and S. Berger, J. Magn. Reson. 219, 1 (2012)]. We analyse the relaxation properties of methyl long-lived states using semi-classical relaxation theory. Numerical simulations are supplemented with a spherical-tensor analysis, which captures the essential properties of methyl long-lived states.
Theory of long-lived nuclear spin states in methyl groups and quantum-rotor induced polarisation
International Nuclear Information System (INIS)
Dumez, Jean-Nicolas; Håkansson, Pär; Mamone, Salvatore; Meier, Benno; Stevanato, Gabriele; Hill-Cousins, Joseph T.; Roy, Soumya Singha; Brown, Richard C. D.; Pileio, Giuseppe; Levitt, Malcolm H.
2015-01-01
Long-lived nuclear spin states have a relaxation time much longer than the longitudinal relaxation time T 1 . Long-lived states extend significantly the time scales that may be probed with magnetic resonance, with possible applications to transport and binding studies, and to hyperpolarised imaging. Rapidly rotating methyl groups in solution may support a long-lived state, consisting of a population imbalance between states of different spin exchange symmetries. Here, we expand the formalism for describing the behaviour of long-lived nuclear spin states in methyl groups, with special attention to the hyperpolarisation effects observed in 13 CH 3 groups upon rapidly converting a material with low-barrier methyl rotation from the cryogenic solid state to a room-temperature solution [M. Icker and S. Berger, J. Magn. Reson. 219, 1 (2012)]. We analyse the relaxation properties of methyl long-lived states using semi-classical relaxation theory. Numerical simulations are supplemented with a spherical-tensor analysis, which captures the essential properties of methyl long-lived states
Energy Technology Data Exchange (ETDEWEB)
Castola, V.; Bighelli, A. [Universite de Corse, Equipe Chimie et Biomasse, Ajaccio (France); Conti, L.; Scano, G.; Mascia, S. [Universita di Sassari, Dipartimento di Chimica, Sassari (Italy); Casanova, J. [Universite de Corse, Equipe Chimie et Biomasse, Ajaccio (France)
2000-07-01
We described a method which allowed identification and quantitation of anhydrosugars in biomass pyrolysis liquids using carbon-13 NMR spectroscopy. The quantitative procedure was checked and validated (accuracy, precision and response linearity) with pure compounds and artificial mixtures. This method was then applied to the analysis of the glucidic fraction obtained after a simple and rapid fractionation of the bio oil. (author)
Studying biosphere-atmosphere exchange of CO2 through Carbon-13 stable isotopes
Velde, van der I.R.
2015-01-01
Summary Thesis ‘Studying biosphere-atmosphere exchange of CO2 through
carbon-13 stable isotopes’
Ivar van der Velde
Making predictions of future climate is difficult, mainly due to large uncertainties in the carbon cycle. The rate at which carbon is stored in the oceans and
Nuclear magnetic relaxation by the dipolar EMOR mechanism: Multi-spin systems
Chang, Zhiwei; Halle, Bertil
2017-08-01
In aqueous systems with immobilized macromolecules, including biological tissues, the longitudinal spin relaxation of water protons is primarily induced by exchange-mediated orientational randomization (EMOR) of intra- and intermolecular magnetic dipole-dipole couplings. Starting from the stochastic Liouville equation, we have previously developed a rigorous EMOR relaxation theory for dipole-coupled two-spin and three-spin systems. Here, we extend the stochastic Liouville theory to four-spin systems and use these exact results as a guide for constructing an approximate multi-spin theory, valid for spin systems of arbitrary size. This so-called generalized stochastic Redfield equation (GSRE) theory includes the effects of longitudinal-transverse cross-mode relaxation, which gives rise to an inverted step in the relaxation dispersion profile, and coherent spin mode transfer among solid-like spins, which may be regarded as generalized spin diffusion. The GSRE theory is compared to an existing theory, based on the extended Solomon equations, which does not incorporate these phenomena. Relaxation dispersion profiles are computed from the GSRE theory for systems of up to 16 protons, taken from protein crystal structures. These profiles span the range from the motional narrowing limit, where the coherent mode transfer plays a major role, to the ultra-slow motion limit, where the zero-field rate is closely related to the strong-collision limit of the dipolar relaxation rate. Although a quantitative analysis of experimental data is beyond the scope of this work, it is clear from the magnitude of the predicted relaxation rate and the shape of the relaxation dispersion profile that the dipolar EMOR mechanism is the principal cause of water-1H low-field longitudinal relaxation in aqueous systems of immobilized macromolecules, including soft biological tissues. The relaxation theory developed here therefore provides a basis for molecular-level interpretation of endogenous soft
International Nuclear Information System (INIS)
SivaRanjan, Uppala; Ramachandran, Ramesh
2014-01-01
A quantum-mechanical model integrating the concepts of reduced density matrix and effective Hamiltonians is proposed to explain the multi-spin effects observed in rotational resonance (R 2 ) nuclear magnetic resonance (NMR) experiments. Employing this approach, the spin system of interest is described in a reduced subspace inclusive of its coupling to the surroundings. Through suitable model systems, the utility of our theory is demonstrated and verified with simulations emerging from both analytic and numerical methods. The analytic results presented in this article provide an accurate description/interpretation of R 2 experimental results and could serve as a test-bed for distinguishing coherent/incoherent effects in solid-state NMR
Energy Technology Data Exchange (ETDEWEB)
SivaRanjan, Uppala; Ramachandran, Ramesh, E-mail: rramesh@iisermohali.ac.in [Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Sector 81, Manauli, P.O. Box-140306, Mohali, Punjab (India)
2014-02-07
A quantum-mechanical model integrating the concepts of reduced density matrix and effective Hamiltonians is proposed to explain the multi-spin effects observed in rotational resonance (R{sup 2}) nuclear magnetic resonance (NMR) experiments. Employing this approach, the spin system of interest is described in a reduced subspace inclusive of its coupling to the surroundings. Through suitable model systems, the utility of our theory is demonstrated and verified with simulations emerging from both analytic and numerical methods. The analytic results presented in this article provide an accurate description/interpretation of R{sup 2} experimental results and could serve as a test-bed for distinguishing coherent/incoherent effects in solid-state NMR.
International Nuclear Information System (INIS)
Wind, Robert A.; Hu, Jian Zhi
2005-01-01
Proton NMR in Biological Objects Submitted to Magic Angle Spinning, In Encyclopedia of Analytical Science, Second Edition (Paul J. Worsfold, Alan Townshend and Colin F. Poole, eds.), Elsevier, Oxford 6:333-342. Published January 1, 2005. Proposal Number 10896
International Nuclear Information System (INIS)
Hayashida, H; Kira, H; Miyata, N; Akutsu, K; Mizusawa, M; Parker, J D; Matsumoto, Y; Oku, T; Sakai, K; Hiroi, K; Shinohara, T; Takeda, M; Yamazaki, D; Oikawa, K; Harada, M; Ino, T; Imagawa, T; Ohkawara, M; Ohoyama, K; Kakurai, K
2016-01-01
We have been developing a 3 He neutron spin filter (NSF) using the spin exchange optical pumping (SEOP) technique. The 3 He NSF provides a high-energy polarized neutron beam with large beam size. Moreover the 3 He NSF can work as a π-flipper for a polarized neutron beam by flipping the 3 He nuclear spin using a nuclear magnetic resonance (NMR) technique. For NMR with the in-situ SEOP technique, the polarization of the laser must be reversed simultaneously because a non-reversed laser reduces the polarization of the spin-flipped 3 He. To change the polarity of the laser, a half-wavelength plate was installed. The rotation angle of the half-wavelength plate was optimized, and a polarization of 97% was obtained for the circularly polarized laser. The 3 He polarization reached 70% and was stable over one week. A demonstration of the 3 He nuclear spin flip system was performed at the polarized neutron reflectometer SHARAKU (BL17) and NOBORU (BL10) at J-PARC. Off-specular measurement from a magnetic Fe/Cr thin film and magnetic imaging of a magnetic steel sheet were performed at BL17 and BL10, respectively. (paper)
Song, Xuerui; Wang, Liujun; Feng, Fupan; Lou, Liren; Diao, Wenting; Duan, Chongdi
2018-03-01
Developing gyroscopes based on quantum systems are important for inertial sensing applications, and its underlying physics is of fundamental interest. In this paper, we proposed a new type of gyroscope based on the Berry phase generated during rotation of the quantum system by using a single 13C nuclear spin coupled with a nearby nitrogen-vacancy center in diamond. Due to the atom-scale size of the quantum system, rotation information can be obtained with high spatial resolution. The gyroscope can be manipulated at room temperature and without the need for a strong magnetic field, which is also beneficial to its further applications.
Efficient calculation of nuclear spin-rotation constants from auxiliary density functional theory
Energy Technology Data Exchange (ETDEWEB)
Zuniga-Gutierrez, Bernardo, E-mail: bzuniga.51@gmail.com [Departamento de Ciencias Computacionales, Universidad de Guadalajara, Blvd. Marcelino García Barragán 1421, C.P. 44430 Guadalajara, Jalisco (Mexico); Camacho-Gonzalez, Monica [Universidad Tecnológica de Tecámac, División A2, Procesos Industriales, Carretera Federal México Pachuca Km 37.5, Col. Sierra Hermosa, C.P. 55740 Tecámac, Estado de México (Mexico); Bendana-Castillo, Alfonso [Universidad Tecnológica de Tecámac, División A3, Tecnologías de la Información y Comunicaciones, Carretera Federal México Pachuca Km 37.5, Col. Sierra Hermosa, C.P. 55740 Tecámac, Estado de México (Mexico); Simon-Bastida, Patricia [Universidad Tecnlógica de Tulancingo, División Electromecánica, Camino a Ahuehuetitla No. 301, Col. Las Presas, C.P. 43642 Tulancingo, Hidalgo (Mexico); Calaminici, Patrizia; Köster, Andreas M. [Departamento de Química, CINVESTAV, Avenida Instituto Politécnico Nacional 2508, A.P. 14-740, México D.F. 07000 (Mexico)
2015-09-14
The computation of the spin-rotation tensor within the framework of auxiliary density functional theory (ADFT) in combination with the gauge including atomic orbital (GIAO) scheme, to treat the gauge origin problem, is presented. For the spin-rotation tensor, the calculation of the magnetic shielding tensor represents the most demanding computational task. Employing the ADFT-GIAO methodology, the central processing unit time for the magnetic shielding tensor calculation can be dramatically reduced. In this work, the quality of spin-rotation constants obtained with the ADFT-GIAO methodology is compared with available experimental data as well as with other theoretical results at the Hartree-Fock and coupled-cluster level of theory. It is found that the agreement between the ADFT-GIAO results and the experiment is good and very similar to the ones obtained by the coupled-cluster single-doubles-perturbative triples-GIAO methodology. With the improved computational performance achieved, the computation of the spin-rotation tensors of large systems or along Born-Oppenheimer molecular dynamics trajectories becomes feasible in reasonable times. Three models of carbon fullerenes containing hundreds of atoms and thousands of basis functions are used for benchmarking the performance. Furthermore, a theoretical study of temperature effects on the structure and spin-rotation tensor of the H{sup 12}C–{sup 12}CH–DF complex is presented. Here, the temperature dependency of the spin-rotation tensor of the fluorine nucleus can be used to identify experimentally the so far unknown bent isomer of this complex. To the best of our knowledge this is the first time that temperature effects on the spin-rotation tensor are investigated.
Efficient calculation of nuclear spin-rotation constants from auxiliary density functional theory
International Nuclear Information System (INIS)
Zuniga-Gutierrez, Bernardo; Camacho-Gonzalez, Monica; Bendana-Castillo, Alfonso; Simon-Bastida, Patricia; Calaminici, Patrizia; Köster, Andreas M.
2015-01-01
The computation of the spin-rotation tensor within the framework of auxiliary density functional theory (ADFT) in combination with the gauge including atomic orbital (GIAO) scheme, to treat the gauge origin problem, is presented. For the spin-rotation tensor, the calculation of the magnetic shielding tensor represents the most demanding computational task. Employing the ADFT-GIAO methodology, the central processing unit time for the magnetic shielding tensor calculation can be dramatically reduced. In this work, the quality of spin-rotation constants obtained with the ADFT-GIAO methodology is compared with available experimental data as well as with other theoretical results at the Hartree-Fock and coupled-cluster level of theory. It is found that the agreement between the ADFT-GIAO results and the experiment is good and very similar to the ones obtained by the coupled-cluster single-doubles-perturbative triples-GIAO methodology. With the improved computational performance achieved, the computation of the spin-rotation tensors of large systems or along Born-Oppenheimer molecular dynamics trajectories becomes feasible in reasonable times. Three models of carbon fullerenes containing hundreds of atoms and thousands of basis functions are used for benchmarking the performance. Furthermore, a theoretical study of temperature effects on the structure and spin-rotation tensor of the H 12 C– 12 CH–DF complex is presented. Here, the temperature dependency of the spin-rotation tensor of the fluorine nucleus can be used to identify experimentally the so far unknown bent isomer of this complex. To the best of our knowledge this is the first time that temperature effects on the spin-rotation tensor are investigated
Efficient calculation of nuclear spin-rotation constants from auxiliary density functional theory.
Zuniga-Gutierrez, Bernardo; Camacho-Gonzalez, Monica; Bendana-Castillo, Alfonso; Simon-Bastida, Patricia; Calaminici, Patrizia; Köster, Andreas M
2015-09-14
The computation of the spin-rotation tensor within the framework of auxiliary density functional theory (ADFT) in combination with the gauge including atomic orbital (GIAO) scheme, to treat the gauge origin problem, is presented. For the spin-rotation tensor, the calculation of the magnetic shielding tensor represents the most demanding computational task. Employing the ADFT-GIAO methodology, the central processing unit time for the magnetic shielding tensor calculation can be dramatically reduced. In this work, the quality of spin-rotation constants obtained with the ADFT-GIAO methodology is compared with available experimental data as well as with other theoretical results at the Hartree-Fock and coupled-cluster level of theory. It is found that the agreement between the ADFT-GIAO results and the experiment is good and very similar to the ones obtained by the coupled-cluster single-doubles-perturbative triples-GIAO methodology. With the improved computational performance achieved, the computation of the spin-rotation tensors of large systems or along Born-Oppenheimer molecular dynamics trajectories becomes feasible in reasonable times. Three models of carbon fullerenes containing hundreds of atoms and thousands of basis functions are used for benchmarking the performance. Furthermore, a theoretical study of temperature effects on the structure and spin-rotation tensor of the H(12)C-(12)CH-DF complex is presented. Here, the temperature dependency of the spin-rotation tensor of the fluorine nucleus can be used to identify experimentally the so far unknown bent isomer of this complex. To the best of our knowledge this is the first time that temperature effects on the spin-rotation tensor are investigated.
International Nuclear Information System (INIS)
Wakasa, Tomotsugu
1997-01-01
We have measured a complete set of polarization transfer observables has been measured for quasi-free (p vector, n vector) reactions on 2 H, 6 Li, 12 C, 40 Ca, and 208 Pb at a bombarding energy of 346MeV and a laboratory scattering angle of 22deg (q=1.7 fm -1 ). The polarization transfer observables for all five targets are remarkably similar. These polarization observables yield separated spin-longitudinal (σ·q) and spin-transverse (σxq) nuclear responses. These results are compared to the spin-transverse responses measured in deep-inelastic electron scattering as well as to nuclear responses based on the random phase approximation. Such a comparison reveals an enhancement in the (p vector, n vector) spin-transverse channel, which masks the effect of pionic correlations in the response ratio. Second, the double differential cross sections at θ lab between 0deg and 12.3deg and the polarization transfer D NN at 0deg for the 90 Zr(p,n) reaction are measured at a bombarding energy of 295MeV. The Gamow-Teller(GT) strength B(GT) in the continuum deduced from the L=0 cross section is compared both with the perturbative calculation by Bertsch and Hamamoto and with the second-order random phase approximation calculation by Drozdz et al. The sum of B(GT) values up to 50MeV excitation becomes S β- =28.0±1.6 after subtracting the contribution of the isovector spin-monopole strength. This S β- value of 28.0±1.6 corresponds to about (93±5)% of the minimum value of the sum-rule 3(N-Z)=30. Last, first measurements of D NN (0deg) for (p vector, n vector) reactions at 295MeV yield large negative values up to 50MeV excitation for the 6 Li, 11 B, 12 C, 13 C(p vector, n vector) reactions. DWIA calculations using the Franey and Love (FL) 270MeV interaction reproduce differential cross sections and D NN (0deg) values, while the FL 325MeV interaction yield D NN (0deg) values less negative than the experimental values. (J.P.N.)
13 Facile application de la RMN du carbone-13 à l'identification et à ...
African Journals Online (AJOL)
AKA BOKO
de bois [13] en utilisant l'analyse directe avec RMN du carbone-13 assistée par ordinateur sans séparation préalable ont démontré la facilité et fiabilité de cette méthode éminemment non invasive. Dans une étude antérieure, nous avons appliqué cette méthodologie dans l'analyse qualitative et quantitative des sucres.
Thurber, Kent; Tycko, Robert
2016-03-01
We describe novel instrumentation for low-temperature solid state nuclear magnetic resonance (NMR) with dynamic nuclear polarization (DNP) and magic-angle spinning (MAS), focusing on aspects of this instrumentation that have not been described in detail in previous publications. We characterize the performance of an extended interaction oscillator (EIO) microwave source, operating near 264 GHz with 1.5 W output power, which we use in conjunction with a quasi-optical microwave polarizing system and a MAS NMR probe that employs liquid helium for sample cooling and nitrogen gas for sample spinning. Enhancement factors for cross-polarized (13)C NMR signals in the 100-200 range are demonstrated with DNP at 25K. The dependences of signal amplitudes on sample temperature, as well as microwave power, polarization, and frequency, are presented. We show that sample temperatures below 30K can be achieved with helium consumption rates below 1.3 l/h. To illustrate potential applications of this instrumentation in structural studies of biochemical systems, we compare results from low-temperature DNP experiments on a calmodulin-binding peptide in its free and bound states. Published by Elsevier Inc.
Carbon-13 nuclear magnetic resonance of heterocyclic salts and its precursors
International Nuclear Information System (INIS)
Freire, H.R.
1989-01-01
The synthesis of 1,2,3,6 - tetrahydro - 1, 1 dimethyl - 3 - oxo - 5 phenylpyridinium bromides containing the substituents: H, Me, Cl, Br, OMe and NO 2 is described. The phenacyl bromides (8a-f) were characterized by their melting points and by their I.r. and 1 H n.m.r. spectra. Some studies on 13 C n.m.r. spectra of the phenacyl bromides (8a-f), the quartenary ammonium salts (7a-f) and the cyclic salts(6a-f) are shown. The effect of substituents on the eletronic structure of these compounds and on the chemical shifts of the different carbon atoms in terms of electronic and steric effects are discussed. (M.J.C.) [pt
International Nuclear Information System (INIS)
Saunders, M.; Telkowski, L.; Kates, M.R.
1977-01-01
The large chemical shifts in 13 C NMR were used to measure the deuterium induced splittings and shifts in the 1 H NMR spectra of dimethylcyclopentyl and dimethylnorbornyl cations, where the deuterium perturbs the degenerate equilibrium. The isotope splitting obtained are tabulated
International Nuclear Information System (INIS)
Maskalick, D.G.
1984-01-01
It is expected that the internal motions of amino acid side chains and protein backbone segments influence and are in turn affected by charge-charge and related interactions, steric constraints, hydrophobic forces, and hydrogen bonding. As an initial test of this theory 13 C-enriched glycine, alanine, and isoleucine have been substituted for the amino terminal valine of sperm whale myoglobin using semisynthetic techniques. 13 C-NMR has been used to analyze the motions of the side chain and the protonation state of the alpha amino group as a function of pH. The addition of a single methyl group to the side chain can alter the alpha amino pK value by as much as 0.3 pH units indicating a delicately balanced set of change-charge interactions between the alpha amino group and the rest of the protein. Further evidence in support of the state theory was found upon examination of the internal motions of seven of nine isoleucine vectors. These motions were extracted from natural abundance 13 C-NMR relaxation data. The results suggest a strong possibility that concerted motions are important. Also, an increase in temperature from 32 0 C to 52 0 C leads to an electrostatically driven tightening of the myoglobin structure as evidenced by no significant increase in motion amplitude of most of the vectors
Devices and process for high-pressure magic angle spinning nuclear magnetic resonance
Energy Technology Data Exchange (ETDEWEB)
Hoyt, David W.; Sears, Jesse A.; Turcu, Romulus V. F.; Rosso, Kevin M.; Hu, Jian Zhi
2017-12-05
A high-pressure magic angle spinning (MAS) rotor is detailed that includes a high-pressure sample cell that maintains high pressures exceeding 150 bar. The sample cell design minimizes pressure losses due to penetration over an extended period of time.
Charged pion electroproduction, a selective probe of nuclear spin isospin responses
International Nuclear Information System (INIS)
Chanfray, G.; Delorme, J.
1983-05-01
We study the reaction of pion electroproduction on nuclei in the quasi-elastic region. We show that detection of the pion in the direction of the virtual photon permits the separation of the spin longitudinal and transverse responses through a Rosenbluth plot. Emphasis is also put on consistency between medium effects and gauge invariance
Determination of spins and radioactive widths of tellurium nuclear levels with capturre gamma rays
International Nuclear Information System (INIS)
Bianchini, F.G.
1973-01-01
Spins and levels widths of the tellurium, mainly 128 Te and 130 Te, were determinated by gamma spectroscopy. Measurements of inelastic and elastic scattering, angular distribution and scattering temperature dependence, were still made. Energy levels of this isotopes, were also determinated [pt
Devices and process for high-pressure magic angle spinning nuclear magnetic resonance
Hoyt, David W; Sears, Jr., Jesse A; Turcu, Romulus V.F.; Rosso, Kevin M; Hu, Jian Zhi
2014-04-08
A high-pressure magic angle spinning (MAS) rotor is detailed that includes a high-pressure sample cell that maintains high pressures exceeding 150 bar. The sample cell design minimizes pressure losses due to penetration over an extended period of time.
Fu, Chenghua; Hu, Zhanning
2018-03-01
In this paper, we investigate the characteristics of the nuclear spin entanglement generated by an intermedium with an optically excited triplet. Significantly, the interaction between the two nuclear spins presents to be a direct XY coupling in each of the effective subspace Hamiltonians which are obtained by applying a transformation on the natural Hamiltonian. The quantum concurrence and negativity are discussed to quantitatively describe the quantum entanglement, and a comparison between them can reveal the nature of their relationship. An innovative general equation describing the relationship between the concurrence and negativity is explicitly obtained.
Matsuo, Mamoru; Saitoh, Eiji; Maekawa, Sadamichi
2017-01-01
We investigate the interconversion phenomena between spin and mechanical angular momentum in moving objects. In particular, the recent results on spin manipulation and spin-current generation by mechanical motion are examined. In accelerating systems, spin-dependent gauge fields emerge, which enable the conversion from mechanical angular momentum into spins. Such a spin-mechanical effect is predicted by quantum theory in a non-inertial frame. Experiments which confirm the effect, i.e., the resonance frequency shift in nuclear magnetic resonance, the stray field measurement of rotating metals, and electric voltage generation in liquid metals, are discussed.
Nuclear spin-magnon relaxation in two-dimensional Heisenberg antiferromagnets
International Nuclear Information System (INIS)
Wal, A.J. van der.
1979-01-01
Experiments are discussed of the dependence on temperature and magnetic field of the longitudinal relaxation time of single crystals of antiferromagnetically ordered insulators, i.e. in the temperature range below the Neel temperature and in fields up to the spin-flop transition. The experiments are done on 19 F nuclei in the Heisenberg antiferromagnets K 2 MnF 4 and K 2 NiF 4 , the magnetic structure of which is two-dimensional quadratic. (C.F.)
Study on gamma-ray transitions induced in nuclear spin isomers by X-rays
International Nuclear Information System (INIS)
Yang Tianli; Hao Fanhua; Liu Xiaoya; Gong Jian
2005-10-01
The development of induced X-ray has been summarized for high spin isomer. the radiation model, transition mechanism and experiment plan have been introduced. The experiments about isomers 180m Ta and 178m2 Hf have been narrated in detail respectively, and the analysis between those results have been obtained. The reasonable theoretical frame and good experimental data have offered the powerful technique base for pumping γ-ray laser with low energy. (authors)
Komorovsky, Stanislav; Repisky, Michal; Malkin, Elena; Demissie, Taye B; Ruud, Kenneth
2015-08-11
We present an implementation of the nuclear spin-rotation (SR) constants based on the relativistic four-component Dirac-Coulomb Hamiltonian. This formalism has been implemented in the framework of the Hartree-Fock and Kohn-Sham theory, allowing assessment of both pure and hybrid exchange-correlation functionals. In the density-functional theory (DFT) implementation of the response equations, a noncollinear generalized gradient approximation (GGA) has been used. The present approach enforces a restricted kinetic balance condition for the small-component basis at the integral level, leading to very efficient calculations of the property. We apply the methodology to study relativistic effects on the spin-rotation constants by performing calculations on XHn (n = 1-4) for all elements X in the p-block of the periodic table and comparing the effects of relativity on the nuclear SR tensors to that observed for the nuclear magnetic shielding tensors. Correlation effects as described by the density-functional theory are shown to be significant for the spin-rotation constants, whereas the differences between the use of GGA and hybrid density functionals are much smaller. Our calculated relativistic spin-rotation constants at the DFT level of theory are only in fair agreement with available experimental data. It is shown that the scaling of the relativistic effects for the spin-rotation constants (varying between Z(3.8) and Z(4.5)) is as strong as for the chemical shieldings but with a much smaller prefactor.
Syntheses of protoporphyrin-IX regioselectivity carbon-13 labelled at the alpha-vinyl carbons
International Nuclear Information System (INIS)
Smith, K.M.; Fujinari, E.M.
1986-01-01
A method for transformation of readily available beta-vinyl 99% carbon-13 enriched derivatives of protoporphyrin-IX dimethyl ester into the less accessible alpha-vinyl labelled isomers is described. The procedure involves thallium(III) promoted vinyl carbon rearrangement, and proceeds through 2,2-dimethoxyethyl, formylmethyl, 2-hydroxyethyl and 2-chloroethyl porphyrins; the rearranged vinyl groups are regenerated from 2-chloroethyl in the last step by treatment with base. No evidence of vinyl carbon scrambling in the sequence is observed, and spectroscopic data of the products are given. (author)
Chang, Zhiwei; Halle, Bertil
2013-10-14
In complex biological or colloidal samples, magnetic relaxation dispersion (MRD) experiments using the field-cycling technique can characterize molecular motions on time scales ranging from nanoseconds to microseconds, provided that a rigorous theory of nuclear spin relaxation is available. In gels, cross-linked proteins, and biological tissues, where an immobilized macromolecular component coexists with a mobile solvent phase, nuclear spins residing in solvent (or cosolvent) species relax predominantly via exchange-mediated orientational randomization (EMOR) of anisotropic nuclear (electric quadrupole or magnetic dipole) couplings. The physical or chemical exchange processes that dominate the MRD typically occur on a time scale of microseconds or longer, where the conventional perturbation theory of spin relaxation breaks down. There is thus a need for a more general relaxation theory. Such a theory, based on the stochastic Liouville equation (SLE) for the EMOR mechanism, is available for a single quadrupolar spin I = 1. Here, we present the corresponding theory for a dipole-coupled spin-1/2 pair. To our knowledge, this is the first treatment of dipolar MRD outside the motional-narrowing regime. Based on an analytical solution of the spatial part of the SLE, we show how the integral longitudinal relaxation rate can be computed efficiently. Both like and unlike spins, with selective or non-selective excitation, are treated. For the experimentally important dilute regime, where only a small fraction of the spin pairs are immobilized, we obtain simple analytical expressions for the auto-relaxation and cross-relaxation rates which generalize the well-known Solomon equations. These generalized results will be useful in biophysical studies, e.g., of intermittent protein dynamics. In addition, they represent a first step towards a rigorous theory of water (1)H relaxation in biological tissues, which is a prerequisite for unravelling the molecular basis of soft
Energy Technology Data Exchange (ETDEWEB)
Crooker, S. A.; Kelley, M. R.; Martinez, N. J. D.; Nie, W.; Mohite, A.; Nayyar, I. H.; Tretiak, S.; Smith, D. L. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Liu, F.; Ruden, P. P. [University of Minnesota, Minneapolis, Minnesota 55455 (United States)
2014-10-13
We use spectrally resolved magneto-electroluminescence (EL) measurements to study the energy dependence of hyperfine interactions between polaron and nuclear spins in organic light-emitting diodes. Using layered devices that generate bright exciplex emission, we show that the increase in EL emission intensity I due to small applied magnetic fields of order 100 mT is markedly larger at the high-energy blue end of the EL spectrum (ΔI/I ∼ 11%) than at the low-energy red end (∼4%). Concurrently, the widths of the magneto-EL curves increase monotonically from blue to red, revealing an increasing hyperfine coupling between polarons and nuclei and directly providing insight into the energy-dependent spatial extent and localization of polarons.
Energy Technology Data Exchange (ETDEWEB)
Oehms, Ole Benjamin
2009-07-10
In the framework of this thesis a combined method of ultrasound and nuclear-spin tomography is presented. Via ultrasound pulses by the sound-radiation force in liquids and tissue phantoms motions are generated, which depend on ther viscoelastic properties. This motions are made visible by a motion-sensitive tomograph sequence in the phase image of the tomograph in form of a phase change. The first measurements on simple phantoms and liquids are presented. [German] Im Rahmen dieser Arbeit wird eine kombinierte Methode aus Ultraschall und Kernspintomographie vorgestellt. Ueber Ultraschallpulse werden durch die Schallstrahlungskraft in Fluessigkeiten und Gewebephantomen Bewegungen erzeugt, die von den viskoelastischen Eigenschaften abhaengen. Diese Bewegungen werden mit einer bewegungssensitiven Tomographensequenz im Phasenbild des Tomographen in Form einer Phasenaenderung sichtbar gemacht. Die ersten Messungen an einfachen Phantomen und Fluessigkeiten werden praesentiert. (orig.)
Thermal coupling in low fields between the nuclear and electronic spins in Tm2+ doped CaF2
International Nuclear Information System (INIS)
Urbina, Cristian.
1977-01-01
It is shown that in a CaF 2 crystal doped with divalent thulium ions there is in low fields, a thermal coupling between the electron magnetic moments of Tm 2+ and the nuclear moments of 19 F. When these ones have been lowered down to temperature through dynamical high-field polarization and adiabatic demagnetization in succession the resulting polarisation of the formed ones can overstep their original polarization in high field. A trial is given to explain this Zeeman electronic energy cooling through nuclear Zeeman energy with invoking a thermal coupling between both systems through the spin-spin electronic interaction but no theoretical model is developed in view of a quantitative explanation of the dynamics of such a process. The magnetic resonance spectrum of Tm 2 + in low field is also investigated: an important shift and narrowing of the electron resonance line in low field are obtained when 19 F nuclei are very cold. This special spectral characters are explained as due to magnetic interactions between electronic impurities and the neighbouring 19 F nuclei and a theoretical model is developed (based on the local Weiss field approximation) which explains rather well the changes in the spectral shift as a function of the 19 F nucleus temperature. A second theoretical model has also been developed in view of a quantitative explanation of both the narrowing and shift of the spectrum, but its prediction disagree with the experimental results. It is shown that in low fieldsx it is possible to get rid of paramagnetic impurities after they have been reused as reducing agents for 19 F nucleus entropy populating at about 80%, a non magnetic metastable state with these impurities [fr
Ashbrook, Sharon E; Wimperis, Stephen
2009-11-21
Spin-locking of spin I=3/2 and I=5/2 nuclei in the presence of small resonance offset and second-order quadrupolar interactions has been investigated using both exact and approximate theoretical and experimental nuclear magnetic resonance (NMR) approaches. In the presence of second-order quadrupolar interactions, we show that the initial rapid dephasing that arises from the noncommutation of the state prepared by the first pulse and the spin-locking Hamiltonian gives rise to tensor components of the spin density matrix that are antisymmetric with respect to inversion, in addition to those symmetric with respect to inversion that are found when only a first-order quadrupolar interaction is considered. We also find that spin-locking of multiple-quantum coherence in a static solid is much more sensitive to resonance offset than that of single-quantum coherence and show that good spin-locking of multiple-quantum coherence can still be achieved if the resonance offset matches the second-order shift of the multiple-quantum coherence in the appropriate reference frame. Under magic angle spinning (MAS) conditions, and in the "adiabatic" limit, we demonstrate that rotor-driven interconversion of central-transition single- and three-quantum coherences for a spin I=3/2 nucleus can be best achieved by performing the spin-locking on resonance with the three-quantum coherence in the three-quantum frame. Finally, in the "sudden" MAS limit, we show that spin I=3/2 spin-locking behavior is generally similar to that found in static solids, except when the central-transition nutation rate matches a multiple of the MAS rate and a variety of rotary resonance phenomena are observed depending on the internal spin interactions present. This investigation should aid in the application of spin-locking techniques to multiple-quantum NMR of quadrupolar nuclei and of cross-polarization and homonuclear dipolar recoupling experiments to quadrupolar nuclei such as (7)Li, (11)B, (17)O, (23)Na, and
Nilsson, Tomas; Halle, Bertil
2012-08-07
The frequency dependence of the longitudinal relaxation rate, known as the magnetic relaxation dispersion (MRD), can provide a frequency-resolved characterization of molecular motions in complex biological and colloidal systems on time scales ranging from 1 ns to 100 μs. The conformational dynamics of immobilized proteins and other biopolymers can thus be probed in vitro or in vivo by exploiting internal water molecules or labile hydrogens that exchange with a dominant bulk water pool. Numerous water (1)H and (2)H MRD studies of such systems have been reported, but the widely different theoretical models currently used to analyze the MRD data have resulted in divergent views of the underlying molecular motions. We have argued that the essential mechanism responsible for the main dispersion is the exchange-mediated orientational randomization (EMOR) of anisotropic nuclear (electric quadrupole or magnetic dipole) couplings when internal water molecules or labile hydrogens escape from orientationally confining macromolecular sites. In the EMOR model, the exchange process is thus not just a means of mixing spin populations but it is also the direct cause of spin relaxation. Although the EMOR theory has been used in several studies to analyze water (2)H MRD data from immobilized biopolymers, the fully developed theory has not been described. Here, we present a comprehensive account of a generalized version of the EMOR theory for spin I = 1 nuclides like (2)H. As compared to a previously described version of the EMOR theory, the present version incorporates three generalizations that are all essential in applications to experimental data: (i) a biaxial (residual) electric field gradient tensor, (ii) direct and indirect effects of internal motions, and (iii) multiple sites with different exchange rates. In addition, we describe and assess different approximations to the exact EMOR theory that are useful in various regimes. In particular, we consider the experimentally
Syntheses of carbon-13 labeled protoporphyrin-IX for spectroscopic studies of heme proteins
International Nuclear Information System (INIS)
Fujinari, E.M.
1985-01-01
The development of various methodologies for synthesis of selectively tailored protoporphyrin-IX dimethyl ester are presented. The iron(II) complex of protoporphyrin-IX is the heme, the prosthetic group for Hb, Mb, cytochromes and peroxidases. The significance of this research is to provide direct means to establish definitive carbon-13 NMR assignments of heme proteins in order to study not only the structure-function relationships, but also protein dynamics of these vital systems. Carbon-13 labeling at the beta-vinyl position was first achieved by ozonolysis of protoporphyrin-IX dimethyl ester. Column LC method were used to first isolate 2,4-diformyldeuteroporphyrin-IX dimethyl ester. Concomitantly, monofomyl-monovinyl porphyrins were obtained as a mixture of two isomers. This mixture was separated by MPLC or prep HPLC to afford the isomerically pure products, Spirographis porphyrin dimethyl ester and Iso-Spirographis porphyrin dimethyl ester. A Wittig reaction to each of these porphyrins with 13 C-methyltriphenylphosphonium iodide gave 2,4-bis[ 13 C 2 ]-vinyl protoporphyrin-IX dimethyl ester, 2-[ 13 C 2 ]-vinyl protoporphyrin-IX dimethyl ester, and the 4-[ 13 C 2 ]-vinyl protoporphyrin-IX dimethyl ester, respectively
Carbon 13 and oxygen 18 isotope record of the early eocene nammal formation, salt range, pakistan
International Nuclear Information System (INIS)
Ghazi, S.; Sajid, Z.
2014-01-01
The Nammal Formation is the lowermost unit of the Early Eocene succession in the Salt Range, Pakistan. It is well exposed throughout the Salt Range. The Nammal Formation having 30 to 35 meters thickness is predominantly composed of nodular limestone interbedded with marl and shale. The present study was focussed on stable carbon 13 and oxygen 18 isotopic analysis based on data from two stratigraphically important sections. The samples from the Nilawahan section provided with the delta 13C values varied between 1.34 to -1.56 (VPDB) and values of delta 18O fluctuated between -4.47 to -6.59 (VPDB). Likewise the sample analysis of BadshahPur section exhibited that the delta 13C values changes from 1.09 to -1.65 (VPDB) and delta 18O values range from -4.17 to -6.85 (VPDB). The isotopic records of carbon 13 and oxygen 18 indicated the shallow marine deposition of the Nammal Formation under tropical conditions. It highlighted the palaeo climatic and diagenetic conditions of the Nammal Formation at the time of deposition in the Salt Range region. (author)
Nuclear spin relaxation due to hydrogen diffusion in b.c.c. metals
International Nuclear Information System (INIS)
Faux, D.A.; Hall, C.K.
1989-01-01
We present Monte Carlo simulation results for the proton-proton contribution to the T 1 -1 relaxation rate for hydrogen spins diffusing on the tetrahedral sites of a b.c.c. metal. It is assumed that each hydrogen blocks all sites to the zeroth (no multiple-occupancy), second or third neighbour and that longer-range interactions may be neglected. Comparisons are made to the BPP and Torrey models. It is found that both the BPP and Torrey models give reasonable values for the peak height but that their predictions for the peak position and the high- and low-temperature limit are in error, particularly for large blocking distances. (orig.)
Effect of nuclear spin on chemical reactions and internal molecular rotation
International Nuclear Information System (INIS)
Sterna, L.L.
1980-12-01
Part I of this dissertation is a study of the magnetic isotope effect, and results are presented for the separation of 13 C and 12 C isotopes. Two models are included in the theoretical treatment of the effect. In the first model the spin states evolve quantum mechanically, and geminate recombination is calculated by numerically integrating the collision probability times the probability the radical pair is in a singlet state. In the second model the intersystem crossing is treated via first-order rate constants which are average values of the hyperfine couplings. Using these rate constants and hydrodynamic diffusion equations, an analytical solution, which accounts for all collisions, is obtained for the geminate recombination. The two reactions studied are photolysis of benzophenone and toluene and the photolytic decomposition of dibenzylketone (1,3-diphenyl-2-propanone). No magnetic isotope effect was observed in the benzophenone reaction. 13 C enrichment was observed for the dibenzylketone reaction, and this enrichment was substantially enhanced at intermediate viscosities and low temperatures. Part II of this dissertation is a presentation of theory and results for the use of Zeeman spin-lattice relaxation as a probe of methyl group rotation in the solid state. Experimental results are presented for the time and angular dependences of rotational polarization, the methyl group magnetic moment, and methyl-methyl steric interactions. The compounds studied are 2,6-dimethylphenol, methyl iodide, 1,4,5,8-tetramethylanthracene, 1,4,5,8-tetramethylnaphthalene, 1,2,4,5-tetramethylbenzene, and 2,3-dimethylmaleicanhydride
Utilization of carbon 13-labelled stable isotopes for studying drug toxicity on cellular metabolism
International Nuclear Information System (INIS)
Herve, M.; Wietzerbin, J.; Tran-Dinh, S.
1994-01-01
A new approach for studying the effects of two drugs, amphotericine B (AMB), an anti-fungal antibiotic, and 2-deoxy-D-glucose (DG), on the glucose metabolism in brewer yeast cells (Saccharomyces cerevisiae), is presented; AMB interacts with the membrane sterols, inducing formation of pores through which ions and small molecules can pass. DG may enter in the cytosol, where it is phosphoryled by hexokinase into deoxy-D-glucose 6-phosphate (DG6P) which disappears very slowly. DG slows down the glycolysis process and induces the formation of new substances. This paper shows the advantages of utilizing carbon 13-labelled substrates combined to the NMR-13C and NMR-1H techniques. 6 figs., 5 refs
One-carbon 13C-labeled synthetic intermediates. Comparison and evaluation of preparative methods
International Nuclear Information System (INIS)
Ott, D.G.
1978-01-01
Frequently the biggest stumbling block to the synthesis of a structurally complex labeled compound is obtaining the required low molecular weight, structurally simple, isotopic intermediates. Selection of a particular scheme from various alternatives depends on the available capabilities and quantity of product desired, as well as on anticipated future requirements and need for related compounds. Many of the newer reagents for organic synthesis can be applied effectively to isotopic preparations with improvements of yields and simplification of procedures compared to established classical methods. New routes developed for higher molecular weight compounds are sometimes not directly adaptable to the one-carbon analogs, either because of isolation difficulties occasioned by physical properties or by chemical reactivities peculiar to their being first members of homologous series. Various routes for preparation of carbon-13 labeled methanol, formaldehyde, and cyanide are compared
International Nuclear Information System (INIS)
Slaets, Johanna I.F.; Chen, Janet; Resch, Christian; Mayr, Leopold; Weltin, Georg; Heiling, Maria; Gruber, Roman; Dercon, Gerd
2017-01-01
Carbon-13 ("1"3C) and nitrogen-15 ("1"5N) labelled plant material is increasingly being used to trace the fate of plant-derived C and N into the atmosphere, soil, water and organisms in many studies, including those investigating the potential of soils to store greenhouse gases belowground. Storage of C in soils can offset and even reduce atmospheric levels of the greenhouse gas, CO_2, and interest in such studies is growing due to problems associated with anthropogenic greenhouse gas emissions impacting climate change. Reduction of N loss in soils is also of great interest, as it reduces release of the greenhouse gas, N_2O, into the atmosphere. However, accurate quantitative tracing of plant-derived C and N in such research is only possible if plant material is labelled both homogeneously and in sufficient quantities.
Pravdivtsev, A.N.; Yurkovskaya, A.V.; Kaptein, R.; Miesel, K.; Vieth, H.-M.; Ivanov, K.L.
2013-01-01
Spin hyperpolarization can be coherently transferred to other nuclei in field-cycling NMR experiments. At low magnetic fields spin polarization is redistributed in a strongly coupled network of spins. Polarization transfer is most efficient at fields where level anti-crossings (LACs) occur for the
Fukuda, Takamitsu; Matsumura, Kazuya; Ishikawa, Naoto
2013-10-10
Nuclear spin driven quantum tunneling of magnetization (QTM) phenomena, which arise from admixture of more than two orthogonal electronic spin wave functions through the couplings with those of the nuclear spins, are one of the important magnetic relaxation processes in lanthanide single molecule magnets (SMMs) in the low temperature range. Although recent experimental studies have indicated that the presence of the intramolecular f-f interactions affects their magnetic relaxation processes, little attention has been given to their mechanisms and, to the best of our knowledge, no rational theoretical models have been proposed for the interpretations of how the nuclear spin driven QTMs are influenced by the f-f interactions. Since quadruple-decker phthalocyanine complexes with two terbium or dysprosium ions as the magnetic centers show moderate f-f interactions, these are appropriate to investigate the influence of the f-f interactions on the dynamic magnetic relaxation processes. In the present paper, a theoretical model including ligand field (LF) potentials, hyperfine, nuclear quadrupole, magnetic dipolar, and the Zeeman interactions has been constructed to understand the roles of the nuclear spins for the QTM processes, and the resultant Zeeman plots are obtained. The ac susceptibility measurements of the magnetically diluted quadruple-decker monoterbium and diterbium phthalocyanine complexes, [Tb-Y] and [Tb-Tb], have indicated that the presence of the f-f interactions suppresses the QTMs in the absence of the external magnetic field (H(dc)) being consistent with previous reports. On the contrary, the faster magnetic relaxation processes are observed for [Tb-Tb] than [Tb-Y] at H(dc) = 1000 Oe, clearly demonstrating that the QTMs are rather enhanced in the presence of the external magnetic field. Based on the calculated Zeeman diagrams, these observations can be attributed to the enhanced nuclear spin driven QTMs for [Tb-Tb]. At the H(dc) higher than 2000 Oe, the
Electron spin resonance of Gd in the nuclear cooling agent: PrNi5 single crystals
International Nuclear Information System (INIS)
Levin, R.; Davidov, D.; Grayevsky, A.; Shaltiel, D.; Zevin, V.
1980-01-01
The ESR of Gd in single crystals of PrNi 5 is observed to exhibit significant angular dependence of the resonance position and linewidth at low temperatures. This is interpreted in terms of the axial spin Hamiltonian which takes the anisotropic susceptibility and the Gd-Pr exchange into consideration. From lineshape analysis the axial crystal field parameter and isotropic Gd-Pr exchange are derived. The Gd ESR linewidth increases with temperature; the thermal broadening is angularly dependent. This is similar to that observed for the Pr NMR in PrNi 5 single crystals. Both the NMR and ESR thermal broadenings are attributed to low-frequency fluctuations of the Pr ions induced by the Pr-Pr exchange coupling. A model for hexagonal Van-Vleck compounds is given and with the linewidth enables the Pr-Pr exchange coupling, under the assumption of a Gaussian or a Lorenzian distribution of the low-frequency fluctuation spectra, to be extracted. It is suggested that the angular dependence of the ESR thermal broadening is due to the Gd-Pr exchange coupling. (UK)
Energy Technology Data Exchange (ETDEWEB)
Passos, Adriano A; Tavares, Maria I.B.; Neto, Roberto C.P.; Moreira, Leonardo A; Ferreira, Antonio G., E-mail: mibt@ima.ufrj.br [Centro de Tecnologia, Instituto de Macromoleculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ (Brazil)
2011-07-01
Nano composites of poly(ethylene-co-vinyl acetate)/silica (SiO{sub 2}) with dimensions of ca. 40 nm were prepared via solution intercalation employing chloroform as a solvent. They were mainly characterized with nuclear magnetic resonance spectroscopy (NMR) employing carbon-13 (polymeric matrix), silicon-29 (nanoparticles) and through the determination of the proton spin-lattice relaxation time in the rotating frame (T{sub 1{rho}H}) (polymer matrix). From the NMR results it was inferred that up to 5% of silica in mass a well dispersed nano composite was obtained, owing to a strong interaction between silica and the EVA matrix. (author)
Difusão de spins nucleares em meios porosos - uma abordagem computacional da RMN
Éverton Lucas-Oliveira
2015-01-01
A Ressonância Magnética Nuclear (RMN) é uma importante técnica empregada nas principais áreas de conhecimento, tais como, Física, Química e Medicina. Importantes trabalhos da RMN aplicada ao estudo da dinâmica de moléculas em fluidos presentes em meios porosos permitiram que esta técnica ganhasse também notoriedade na indústria do petróleo. O presente projeto é fundamentado em alguns destes trabalhos seminais, reproduzindo, através de modelos físico-computacionais, os principais efeitos físic...
International Nuclear Information System (INIS)
Raduta, A. A.; Delion, D. S.; Faessler, A.
1998-01-01
The suppression mechanism of the Gamow-Teller double beta decay amplitude M GT is studied using a many body Hamiltonian which describes a composite system of protons and neutrons moving in a projected spherical single particle basis. Alike nucleons interact through pairing, while protons and neutrons by a separable dipole-dipole force both in the particle-hole (ph) and particle-particle (pp) channels. The spin-flip and non-spin-flip components of the QRPA phonons have different contributions to the M GT value. The relative magnitudes and phases depend on both the strength of the particle-particle interaction (g pp ) and nuclear deformation. The deformation yields a fragmentation of the M GT value on one hand and washes out the separation of states of pure spin-flip and non spin-flip structures. Due to this effect, M GT has only one fragmented resonance structure in the low part of the spectrum. The mechanism of M GT suppression is different for spherical and deformed nuclei. While for spherical situation the resonances of pure spin-flip and non spin-flip character are separated in energy, for deformed case the two resonances coincide. In both cases, approaching the critical value of g pp , where the Random Phase Approximation (RPA) breaks down, a lot of strength is accumulated in the lowest RPA state. The difference is that, while in the spherical case this has a non spin-flip nature, in the deformed case the state is a mixture of both types of configurations. (authors)
Jiang, Feng-Jian; Ye, Jian-Feng; Jiao, Zheng; Jiang, Jun; Ma, Kun; Yan, Xin-Hu; Lv, Hai-Jiang
2018-05-01
We perform a proof-of-principle experiment that uses a single negatively charged nitrogen–vacancy (NV) color center with a nearest neighbor 13C nuclear spin in diamond to detect the strength and direction (including both polar and azimuth angles) of a static vector magnetic field by optical detection magnetic resonance (ODMR) technique. With the known hyperfine coupling tensor between an NV center and a nearest neighbor 13C nuclear spin, we show that the information of static vector magnetic field could be extracted by observing the pulsed continuous wave (CW) spectrum. Project supported by the National Natural Science Foundation of China (Grant Nos. 11305074, 11135002, and 11275083), the Key Program of the Education Department Outstanding Youth Foundation of Anhui Province, China (Grant No. gxyqZD2017080), and the Education Department Natural Science Foundation of Anhui Province, China (Grant No. KJHS2015B09).
International Nuclear Information System (INIS)
Bohler, C.L.; Schearer, L.D.; Leduc, M.; Nacher, P.J.; Zachorowski, L.; Milner, R.G.; McKeown, R.D.; Woodward, C.E.
1988-01-01
Several Nd:YAP lasers were constructed which could be broadly tuned in the 1083-nm region which includes the helium 2 3 S-2 3 P transition, using a Lyot filter and thin, uncoated etalons within the laser cavity. 1 W of power could be extracted at 1083 nm through a 1% transmitting output coupler. This laser beam was used to optically pump metastable 4 He and 3 He 2 3 S helium atoms in a weak discharge cell, spin polarizing the metastable ensemble. In a 3 He cell the polarization is transferred to the nuclear spin system. A 3 He target cell at 0.3 Torr was polarized to 52% in a few minutes. We describe the application of this system to the design of polarized targets for experiments in nuclear physics
Chatterji, T; Jalarvo, N; Kumar, C M N; Xiao, Y; Brückel, Th
2013-07-17
We have investigated low energy nuclear spin excitations in the strongly correlated electron compound HoCrO3. We observe clear inelastic peaks at E = 22.18 ± 0.04 μeV in both energy loss and gain sides. The energy of the inelastic peaks remains constant in the temperature range 1.5-40 K at which they are observed. The intensity of the inelastic peak increases at first with increasing temperature and then decreases at higher temperatures. The temperature dependence of the energy and intensity of the inelastic peaks is very unusual compared to that observed in other Nd, Co, V and also simple Ho compounds. Huge quasielastic scattering appears at higher temperatures presumably due to the fluctuating electronic moments of the Ho ions that get increasingly disordered at higher temperatures. The strong quasielastic scattering may also originate in the first Ho crystal-field excitations at about 1.5 meV.
International Nuclear Information System (INIS)
Luo Xinjun; Sholl, C.A.
2002-01-01
Two Bloembergen-Purcell-Pound (BPP) models for analysing nuclear spin relaxation data for translational diffusion in disordered systems are compared with Monte Carlo simulations. One model (the a-BPP model, 'a' standing for average) is commonly used for disordered systems and the other (the Cameron-Sholl BPP model) is more rigorously based and can distinguish between site-and barrier-energy disorder. Simulated relaxation data produced using Gaussian distributions of energy disorder are analysed using the models, and the parameters obtained from the fits are compared with the values used for the simulations. It is found that both models can give reasonable fits to the data. Both models also give reasonable agreement with the simulation parameters provided that the standard deviation of the energy distribution for the a-BPP model is interpreted as the average of the site-and barrier-energy standard deviations. Quantitative estimates are given of the accuracy of the parameters from the fits. (author)
Relation between molecular electronic structure and nuclear spin-induced circular dichroism
DEFF Research Database (Denmark)
Štěpánek, Petr; Coriani, Sonia; Sundholm, Dage
2017-01-01
with spatially localized, high-resolution information. To survey the factors relating the molecular and electronic structure to the NSCD signal, we theoretically investigate NSCD of twenty structures of the four most common nucleic acid bases (adenine, guanine, thymine, cytosine). The NSCD signal correlates...... with the spatial distribution of the excited states and couplings between them, reflecting changes in molecular structure and conformation. This constitutes a marked difference to the nuclear magnetic resonance (NMR) chemical shift, which only reflects the local molecular structure in the ground electronic state....... The calculated NSCD spectra are rationalized by means of changes in the electronic density and by a sum-over-states approach, which allows to identify the contributions of the individual excited states. Two separate contributions to NSCD are identified and their physical origins and relative magnitudes...
Fabrication of 121Sb isotopic targets for the study of nuclear high spin features
Devi, K. Rojeeta; Kumar, Suresh; Kumar, Neeraj; Abhilash, S. R.; Kabiraj, D.
2018-06-01
Isotopic 121Sb targets with 197Au backing have been prepared by Physical Vapor Deposition (PVD) method using the diffusion pump based coating unit at target laboratory, Inter University Accelerator Centre (IUAC), New Delhi, India. The target thickness was measured by stylus profilo-meter and the purity of the targets was investigated by Energy Dispersive X-ray Analysis (EDXA). One of these targets has been used in an experiment which was performed at IUAC for nuclear structure study through fusion evaporation reaction. The excitation function of the 121Sb(12C, yxnγ) reaction has been performed for energies 58 to 70 MeV in steps of 4 MeV. The experimental results were compared with the calculations of statistical models : PACE4 and CASCADE. The methods adopted to achieve best quality foils and good deposition efficiency are reported in this paper.
Directory of Open Access Journals (Sweden)
Quade, U.
2005-12-01
Full Text Available In the 1980ies, Siempelkamp foundry in Krefeld, Germany, developed a process to melt medium and slightly radioactive metals from decommissioning and maintenance works in nuclear power plants. Since 1989, in the CARLA melting plant which is licensed according to the German radiation protection ordinance (StrlSchV, metals are being molten which, for the largest part, can be reused. Since 1998, in a second plant, the GERTA melting plant, metals with a content of mercury up to 1 weight %, natural radioactivity up to 500 Bq/g and other chemical contaminations are being molten and completely decontaminated, so that these metals can be reused in the steel cycle. The following text is describing the melting process, acceptance criteria for contaminated scrap and recycling paths for the produced ingots and slags.
La fundición Siempelkamp en Krefeld, Alemania, desarrolló, en los años 80, un proceso para fundir metales mediana y levemente radioactivos, procedentes de reparaciones o desmantelamiento de plantas nucleares. En la planta de fundición CARLA, que cumple los requisitos del decreto de protección contra radiaciones de la República Federal de Alemania, se funden metales desde 1989, de los cuales la mayor parte puede ser utilizada nuevamente. Desde 1998, en una segunda planta, fundición GERTA, se funden y descontaminan totalmente, metales de hasta un 1 % de peso de mercurio, con una radioactividad natural de hasta 500 Bq/g y con otros contaminantes químicos. De este modo los metales pueden ser nuevamente utilizados en el ciclo metálico. El texto adjunto describe el método para el fundido, los criterios para aceptar chatarra contaminada y las vías de utilización para los bloques de metal y escorias generadas en el proceso.
Wood, R. M.; Saha, D.; McCarthy, L. A.; Tokarski, J. T.; Sanders, G. D.; Kuhns, P. L.; McGill, S. A.; Reyes, A. P.; Reno, J. L.; Stanton, C. J.; Bowers, C. R.
2014-10-01
A combined experimental-theoretical study of optically pumped nuclear magnetic resonance (OPNMR) has been performed in a GaAs /A l0.1G a0.9As quantum well film epoxy bonded to a Si substrate with thermally induced biaxial strain. The photon energy dependence of the Ga OPNMR signal was recorded at magnetic fields of 4.9 and 9.4 T at a temperature of 4.8-5.4 K. The data were compared to the nuclear spin polarization calculated from the electronic structure and differential absorption to spin-up and spin-down states of the electron conduction band using a modified k .p model based on the Pidgeon-Brown model. Comparison of theory with experiment facilitated the assignment of features in the OPNMR energy dependence to specific interband Landau level transitions. The results provide insight into how effects of strain and quantum confinement are manifested in optical nuclear polarization in semiconductors.
Characterization of Chemical Exchange Using Relaxation Dispersion of Hyperpolarized Nuclear Spins.
Liu, Mengxiao; Kim, Yaewon; Hilty, Christian
2017-09-05
Chemical exchange phenomena are ubiquitous in macromolecules, which undergo conformational change or ligand complexation. NMR relaxation dispersion (RD) spectroscopy based on a Carr-Purcell-Meiboom-Gill pulse sequence is widely applied to identify the exchange and measure the lifetime of intermediate states on the millisecond time scale. Advances in hyperpolarization methods improve the applicability of NMR spectroscopy when rapid acquisitions or low concentrations are required, through an increase in signal strength by several orders of magnitude. Here, we demonstrate the measurement of chemical exchange from a single aliquot of a ligand hyperpolarized by dissolution dynamic nuclear polarization (D-DNP). Transverse relaxation rates are measured simultaneously at different pulsing delays by dual-channel 19 F NMR spectroscopy. This two-point measurement is shown to allow the determination of the exchange term in the relaxation rate expression. For the ligand 4-(trifluoromethyl)benzene-1-carboximidamide binding to the protein trypsin, the exchange term is found to be equal within error limits in neutral and acidic environments from D-DNP NMR spectroscopy, corresponding to a pre-equilibrium of trypsin deprotonation. This finding illustrates the capability for determination of binding mechanisms using D-DNP RD. Taking advantage of hyperpolarization, the ligand concentration in the exchange measurements can reach on the order of tens of μM and protein concentration can be below 1 μM, i.e., conditions typically accessible in drug discovery.
Conformational effects on Carbon-13 NMR spectra of half-cage alcohols
Energy Technology Data Exchange (ETDEWEB)
Seidl, Peter Rudolf [Universidade Federal (UFRJ), Rio de Janeiro, RJ (Brazil). Escola de Quimica; Carneiro, J. Walkimar de M. [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Dept. de Quimica Geral e Inorganica; Tostes, Glauco R. [Universidade Federal do Norte Fluminense (UENSP). Campos dos Goytacazes, RJ (Brazil). Centro de Ciencias e Tecnologia; Pinto, Paulo S.S. [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil). Dept. de Engenharia Quimica; Costa, Valentim E.U.; Alifantes, Joao [Rio Grande do Sul Univ. (UFRGS), Porto Alegre (Brazil). Inst. de Quimica; Bernassau, Jean-Marie; Sizun, Philippe [SANOFI Recherche, Montpellier (France)
1999-05-01
Rotation around the carbon=oxygen bond of the hydroxyl group of half-cage alcohols affects bond lengths and angles as well as charge distribution on carbon and hydrogen atoms. As derivatives of half-cage compounds have played an important role in the investigation of several phenomena of interest in the interpretation of NMR parameters, we calculated carbon -13 chemical shift for the three conformers of half-cage alcohols that were investigated at the 6-31 G{sup *} level. GIAO chemical shifts for 1 A, 1 B and 1 C (C{sub 6}-C{sub 5}-O-H dihedral angles of respectively, -73.6 deg C, 64.8 deg C and 178.0 deg C) were calculated by HF/6-31 g (d)// B3 LYP/6-31 g (d) and by B3LYP/6-31 g (d)//B3LYP/6-31 g (d). Since the later gave better agreement with the published chemical shifts and correctly predicts the order of shifts for 2-exo-norbornol, the bicyclic analog of 1, we took these calculations as a basis for analysis of conformational effects.
Monitoring of liver glycogen synthesis in diabetic patients using carbon-13 MR spectroscopy
International Nuclear Information System (INIS)
Tomiyasu, Moyoko; Obata, Takayuki; Nishi, Yukio; Nakamoto, Hiromitsu; Nonaka, Hiroi; Takayama, Yukihisa; Autio, Joonas; Ikehira, Hiroo; Kanno, Iwao
2010-01-01
To investigate the relationship between liver glucose, glycogen, and plasma glucose in diabetic patients, in vivo liver carbon-13 magnetic resonance spectroscopy ( 13 C MRS) with a clinical 3.0 T MR system was performed. Subjects were healthy male volunteers (n = 5) and male type-2 diabetic patients (n = 5). Pre- and during oral glucose tolerance tests (OGTT), 13 C MR spectra without proton decoupling were acquired in a monitoring period of over 6 h, and in total seven spectra were obtained from each subject. For OGTT, 75 g of glucose, including 5 g of [1- 13 C]glucose, was administered. The MR signals of liver [1- 13 C]glucose and glycogen were detected and their time-course changes were assessed in comparison with the plasma data obtained at screening. The correlations between the fasting plasma glucose level and liver glycogen/glucose rate (Spearman: ρ = -0.68, p 13 C MRS can perform noninvasive measurement of glycogen storage/degradation ability in the liver individually and can assist in tailor-made therapy for diabetes. In conclusion, 13 C MRS has a potential to become a powerful tool in diagnosing diabetes multilaterally.
International Nuclear Information System (INIS)
Burgunder, G.
2011-12-01
The spin-orbit interaction depends on the spin orientation of the nucleons with respect to their angular momenta as well as on the derivative of the nuclear density. Even though this density dependence is used in all mean field model, it has never been tested yet due to the lack of data. We propose an original method to test this density dependence by comparing a bubble nucleus ( 34 Si) to a normal nucleus ( 36 S). The 34 Si exhibits a central density which is depleted by a factor of two which induces a non-zero central density derivative and should change the strength of the spin orbit interaction for the inner orbits such as the p orbits (L=1). By performing (d,p) transfer reactions with 36 S and 34 Si beams, the p(3/2) and p(1/2) spin orbit splitting can be inferred for these nuclei. Depending on the models, the spin-orbit splitting varies from 7% (VlowK interaction) up to 70% (Relativistic mean field approach). Beams of 36 S and 34 Si, produced at the LISE spectrometer at 20 A.MeV, were impinged onto a CD 2 target. Tracking the beam particles was achieved using 2 xy beam tracking gas detectors. Protons emitted were detected by 4 multi-segmented Si detectors (MUST2) placed at backwards angles. Gammas issued from the excited states decay were detected in the 4 EXOGAM segmented Germanium detectors. Transfer like nuclei were identified with an ionization chamber and a plastic detector. The excitation energy spectra of the 37 S and 35 Si are determined up to about 7 MeV. Spectroscopic factors and energies of p and f states are derived for the first time in 35 Si. The two nuclei show strong similarity for the f spin-orbit partners, whereas the p(3/2) - p(1/2) energy gap is reduced by 55%. (author)
Devi, Elok A.; Rachman, Faisal; Satyana, Awang H.; Fahrudin; Setyawan, Reddy
2018-02-01
The Eocene Lower Ngimbang carbonaceous shales are geochemically proven hydrocarbon source rocks in the East Java Basin. Sedimentary facies of source rock is important for the source evaluation that can be examined by using biomarkers and carbon-13 isotopes data. Furthermore, paleogeography of the source sedimentation can be reconstructed. The case study was conducted on rock samples of Lower Ngimbang from two exploration wells drilled in Cepu area, East Java Basin, Kujung-1 and Ngimbang-1 wells. The biomarker data include GC and GC-MS data of normal alkanes, isoprenoids, triterpanes, and steranes. Carbon-13 isotope data include saturate and aromatic fractions. Various crossplots of biomarker and carbon-13 isotope data of the Lower Ngimbang source samples from the two wells show that the source facies of Lower Ngimbang shales changed from transitional/deltaic setting at Kujung-1 well location to marginal marine setting at Ngimbang-1 well location. This reveals that the Eocene paleogeography of the Cepu area was composed of land area in the north and marine setting to the south. Biomarkers and carbon-13 isotopes are powerful data for reconstructing paleogeography and paleofacies. In the absence of fossils in some sedimentary facies, these geochemical data are good alternatives.
A study on the improvement of spin-off effectiveness of national nuclear R and D activities
International Nuclear Information System (INIS)
Yang, Maeng Ho; Lee, T. J.
1997-02-01
This study consists of two parts. One is to identify factors affecting technological effectiveness of the spin-off process that is defined as the technology transfer process from government sponsored research institutes (GRI's) to the civilian sector. The other is to analyze the environment of the spin-off process and to suggest guidelines for addition, this study also examines spin-off effectiveness with technology transfer types. To validate the conceptual model and hypotheses of the spin-off process, data are collected from 12 cases through in-depth interviews and questionnaires. Spearman correlation analysis is employed in order to test the hypotheses on the spin-off process. (author). 50 refs., 17 tabs., 12 figs
International Nuclear Information System (INIS)
Raduta, A.A.; Delion, D.S.; Faessler, A.
1997-01-01
The suppression mechanism of the Gamow-Teller double beta decay amplitude M GT is studied using a many body Hamiltonian which describes a composite system of protons and neutrons moving in a projected spherical single particle basis. Alike nucleons interact through pairing while protons and neutrons by a separable dipole-dipole force both in the particle-hole (ph) and particle-particle (pp) channels. The spin-flip and non-spin-flip components of the QRPA phonons have a differents contribution to the M GT values. The relative magnitudes and phases depend both on the strength of the particle-particle interaction (g pp ) and on the nuclear deformation. The deformation yields a fragmentation of the M GT value on one hand and washes out the separation of states of pure spin-flip and non-spin-flip structures. Due to this effect M GT has only one fragmented resonance structure in the low part of the spectrum. (orig.)
International Nuclear Information System (INIS)
Herbst, Christian; Herbst, Jirada; Leppert, Joerg; Ohlenschlaeger, Oliver; Goerlach, Matthias; Ramachandran, Ramadurai
2009-01-01
An approach for the efficient implementation of RN n ν symmetry-based pulse schemes that are often employed for recoupling and decoupling of nuclear spin interactions in biological solid state NMR investigations is demonstrated at high magic-angle spinning frequencies. RF pulse sequences belonging to the RN n ν symmetry involve the repeated application of the pulse sandwich {R φ R -φ }, corresponding to a propagator U RF = exp(-i4φI z ), where φ = πν/N and R is typically a pulse that rotates the nuclear spins through 180 o about the x-axis. In this study, broadband, phase-modulated 180 o pulses of constant amplitude were employed as the initial 'R' element and the phase-modulation profile of this 'R' element was numerically optimised for generating RN n ν symmetry-based pulse schemes with satisfactory magnetisation transfer characteristics. At representative MAS frequencies, RF pulse sequences were implemented for achieving 13 C- 13 C double-quantum dipolar recoupling and through bond scalar coupling mediated chemical shift correlation and evaluated via numerical simulations and experimental measurements. The results from these investigations are presented here
International Nuclear Information System (INIS)
Luo Xinjun; Sholl, C A
2003-01-01
Magnetization recoveries for nuclear spin relaxation of like spins due to magnetic dipolar coupling and diffusion on inequivalent sites involve a sum of exponentials. The theory is applied to diffusion on octahedral and tetrahedral interstitial sites in the face-centred cubic structure. Monte Carlo simulations have been used to generate relaxation data for parameters typical for H in metals. It is found that only a single exponential would be observable in the high- and low-temperature limits, but that two-exponential recoveries could be observable in the vicinity of the maximum in the relaxation rate as a function of temperature. The Monte Carlo relaxation data has been fitted using a Bloembergen-Pound-Purcell (BPP) model to assess the accuracy of the BPP model
2002-01-01
We aim at establishing an unambiguous spin determination of the ground and isomeric states in the neutron rich Cu-isotopes from A=72 up to A=78 and to measure the magnetic and quadrupole moments between the N=28 and N=50 shell closures. This study will provide information on the double-magicity of $^{56}$Ni and $^{78}$Ni, both at the extremes of nuclear stability. It will provide evidence on the suggested inversion of ground state spin around A$\\approx$74, due to the monopole migration of the $\\pi f_{5/2}$ level. The collinear laser spectroscopy technique will be used, which furthermore provides information on the changes in mean square charge radii between both neutron shell closures, probing a possible onset of deformation in this region.
Energy Technology Data Exchange (ETDEWEB)
Kath, Matthias
2009-11-06
In this thesis the experimental study of the spin dynamics of solid {sup 3}He is described. By means of magnetization measurements above 3 mK a Curie-Weiss behaviour was found with {theta}{sub W}{approx}2.1 mK and by this an order parameter of J={theta}{sub W}k{sub B}/{approx}-0.5 Kk{sub B} was observed, while in the range of 1 to 3 mK a pure Curie behaviour was found. By means of NMR measurements the values of {tau}{sub 1}(6 mK)=240 ms{+-}12 ms and {tau}{sub 1}(1 mK){approx} 40 ms were determined, while spin-echo measurements yielded the spin-spin relaxation time {tau}{sub 2}(6 mK)=4540 {mu}s{+-}140 {mu}s. Furthermore neutron scattering studies were performed. (HSI)
Chang, Zhiwei; Halle, Bertil
2016-02-28
In aqueous systems with immobilized macromolecules, including biological tissue, the longitudinal spin relaxation of water protons is primarily induced by exchange-mediated orientational randomization (EMOR) of intra- and intermolecular magnetic dipole-dipole couplings. We have embarked on a systematic program to develop, from the stochastic Liouville equation, a general and rigorous theory that can describe relaxation by the dipolar EMOR mechanism over the full range of exchange rates, dipole coupling strengths, and Larmor frequencies. Here, we present a general theoretical framework applicable to spin systems of arbitrary size with symmetric or asymmetric exchange. So far, the dipolar EMOR theory is only available for a two-spin system with symmetric exchange. Asymmetric exchange, when the spin system is fragmented by the exchange, introduces new and unexpected phenomena. Notably, the anisotropic dipole couplings of non-exchanging spins break the axial symmetry in spin Liouville space, thereby opening up new relaxation channels in the locally anisotropic sites, including longitudinal-transverse cross relaxation. Such cross-mode relaxation operates only at low fields; at higher fields it becomes nonsecular, leading to an unusual inverted relaxation dispersion that splits the extreme-narrowing regime into two sub-regimes. The general dipolar EMOR theory is illustrated here by a detailed analysis of the asymmetric two-spin case, for which we present relaxation dispersion profiles over a wide range of conditions as well as analytical results for integral relaxation rates and time-dependent spin modes in the zero-field and motional-narrowing regimes. The general theoretical framework presented here will enable a quantitative analysis of frequency-dependent water-proton longitudinal relaxation in model systems with immobilized macromolecules and, ultimately, will provide a rigorous link between relaxation-based magnetic resonance image contrast and molecular parameters.
Presence de Carbone-13 dans les elements combustibles de type (U,Pu)O 2 irradies en reacteur rapide
Kryger, Bernard; Hagemann, Robert
1982-06-01
Du carbone-13 produit par la réaction de capture neutronique 168O + 10n → 136C + 42He se forme dans les combustibles de type oxyde irradiés en neutrons rapides. Cette réaction, dont le seuil d'énergie se situe à 2.35 MeV, conduit à la formation d'une quantité de carbone-13 qui peut varier notablement suivant le spectre neutronique du réacteur (entre 20 et 40 × 10 -6g 13C/g (U,Pu)O 2 pour une fluence de 2 × 10 23 n/cm 2). DES mesures effectuées sur le combustible et la gaine par spectrométrie de masse après irradiation montrent qu'une fraction égale ou supérieure à la moitié du carbone-13 produit dans l'oxyde peut être transférée dans la gaine. Un tel comportement nous fait considérer le carbone-13 comme un véritable marqueur du carbone plus généralement contenu dans l'oxyde et, à ce titre, la détection de cet isotope devrait contribuer à élucider tout particulièrement les mécanismes de carburation de la gaine par les combustibles (U,Pu)O 2 des réacteurs surgénérateurs.
Energy Technology Data Exchange (ETDEWEB)
Lafon, Olivier [Universite de Lille Nord de France; Thankamony, Aany S. Lilly [Universite de Lille Nord de France; Kokayashi, Takeshi [Ames Laboratory; Carnevale, Diego [Ecole Polytechnique Federale de Lausanne; Vitzthum, Veronika [Ecole Polytechnique Federale de Lausanne; Slowing, Igor I. [Ames Laboratory; Kandel, Kapil [Ames Laboratory; Vezin, Herve [Universite de Lille Nord de France; Amoureux, Jean-Paul [Universite de Lille Nord de France; Bodenhausen, Geoffrey [Ecole Polytechnique Federale de Lausanne; Pruski, Marek [Ames Laboratory
2012-12-21
We show that dynamic nuclear polarization (DNP) can be used to enhance NMR signals of 13C and 29Si nuclei located in mesoporous organic/inorganic hybrid materials, at several hundreds of nanometers from stable radicals (TOTAPOL) trapped in the surrounding frozen disordered water. The approach is demonstrated using mesoporous silica nanoparticles (MSN), functionalized with 3-(N-phenylureido)propyl (PUP) groups, filled with the surfactant cetyltrimethylammonium bromide (CTAB). The DNP-enhanced proton magnetization is transported into the mesopores via 1H–1H spin diffusion and transferred to rare spins by cross-polarization, yielding signal enhancements εon/off of around 8. When the CTAB molecules are extracted, so that the radicals can enter the mesopores, the enhancements increase to εon/off ≈ 30 for both nuclei. A quantitative analysis of the signal enhancements in MSN with and without surfactant is based on a one-dimensional proton spin diffusion model. The effect of solvent deuteration is also investigated.
International Nuclear Information System (INIS)
Azgui, F.; Emling, H.; Grosse, E.; Michel, C.; Simon, R.S.; Spreng, W.; Wollersheim, H.J.; Khoo, T.L.; Chowdhury, P.; Frekers, D.; Janssens, R.V.F.; Pakkanen, A.; Daly, P.J.; Kortelahti, M.; Schwalm, D.; Seiler-Clark, G.
1985-01-01
Measurements of feeding times of high spin yrast states up to spin 30 (h/2π) in 154 Dy and 36 (h/2π) in 152 Dy were utilized to obtain information about possible spin dependent shape changes. The reactions 25 Mg ( 134 Xe, 5n), 124 Sn ( 34 S, 4n) and 25 Mg ( 132 Xe, 5n), 122 Sn ( 34 S, 4n) were used to populate the high spin states in 154 Dy and 152 Dy, respectively. Feeding times as well as lifetimes were determined with the recoil distance technique. In 152 Dy only long feeding times (>=10 ps) could be identified, indicating that the aligned-particle yrast states are fed through configurations of similar character, with little direct population from collective cascades in the continuum region. In 154 Dy discrete states with I<=30 (h/2π) have lifetimes which are characteristically collective, whereas the preyrast cascades exhibit both fast (< or approx.1 ps) and slow (proportional10 ps) feeding components. The latter imply a change with increasing spin from collective to aligned-particle character, probably associated with a prolate to oblate shape transition. (orig.)
Little, Reginald B; McClary, Felicia; Rice, Bria; Jackman, Corine; Mitchell, James W
2012-12-14
The recent observation of the explosive oxidation of graphene with enhancement for decreasing temperature and the requirements for synchronizing oxidants for collective oxidation-reduction (redox) reactions presented a chemical scenario for the thermal harvesting by the magnetic spin Hall Effect. More experimental data are presented to demonstrate such spin Hall Effect by determining the influence of spins of so-called spectator fermionic cations. Furthermore, the so-called spectator bosonic cations are discovered to cause a Klein tunneling effect during the redox reaction of graphene. The Na(+) and K(+), fermionic cations and the Mg(2+) and Ca(2+), bosonic cations were observed and compared under a variety of experimental conditions: adiabatic reactions with initial temperatures (18-22 °C); reactions toward infinite dilution; isothermal reactions under nonadiabatic conditions at low temperature of 18 °C; reactions under paramagnetic O(2) or diamagnetic N(2) atmospheres of different permeabilities; reactions in applied and no applied external magnetic field; and reactions toward excess concentrations of common and uncommon Na(+) and Mg(2+) cations. The observed reaction kinetics and dynamics under these various, diverse conditions are consistent with the spin Hall mechanism, energy harvesting and short time violation of Second Law of Thermodynamics for redox reactions of graphene by the Na(+)K(+) mixture and are consistent with the Klein tunnel mechanism for the redox reactions of graphene by the Mg(2+)Ca(2+) mixture. Mixed spin Hall and Klein tunnel mechanisms are discovered to slow and modulate explosive redox reactions. Such spin Hall Effect also gives explanation of recent tunneling of electrons through boron nitride.
Valenzuela, Sergio O; Saitoh, Eiji; Kimura, Takashi
2012-01-01
In a new branch of physics and technology called spin-electronics or spintronics, the flow of electrical charge (usual current) as well as the flow of electron spin, the so-called 'spin current', are manipulated and controlled together. This book provides an introduction and guide to the new physics and application of spin current.
NUCLEON SPIN: Enigma confirmed
International Nuclear Information System (INIS)
Anon.
1994-01-01
In 1987 the European Muon Collaboration (EMC - June 1988, page 9) reported results from a polarized muon-proton scattering experiment at CERN which puzzled the particle and nuclear physics communities. Contrary to the prediction of the naive quark model, the EMC found that little of the proton spin seemed to be carried by the spins of the quarks. An extensive experimental programme was therefore immediately proposed at CERN, SLAC (Stanford) and DESY (Hamburg) to measure the spin structure function of the neutron and to repeat the proton measurement with improved accuracy
International Nuclear Information System (INIS)
Khan, H.
1990-01-01
This thesis explores deep inelastic scattering of a lepton beam from a polarized nuclear target with spin J=1. After reviewing the formation for spin-1/2, the structure functions for a spin-1 target are defined in terms of the helicity amplitudes for forward compton scattering. A version of the convolution model, which incorporates relativistic and binding energy corrections is used to calculate the structure functions of a neutron target. A simple parameterization of these structure functions is given in terms of a few neutron wave function parameters and the free nucleon structure functions. This allows for an easy comparison of structure functions calculated using different neutron models. (author)
International Nuclear Information System (INIS)
Quiroga, Luis
1982-01-01
In a first part, autocorrelation functions are calculated taking into account the symmetry of molecular motions by group theoretical techniques. This very general calculation method is then used to evaluate the NMR spin-lattice relaxation times T 1 and T 1 p as a function of the relative orientations of the magnetic field, the crystal and the rotation axis, in particular for cyclic, dihedral and cubic groups. Models of molecular reorientations such as jumps between a finite number of allowed orientations, rotational diffusion and superimposed reorientations are all investigated with the same formalism. In part two, the effect of the coherent excitation of spins, by multipulse sequences of the WHH-4 type, on the evolution of the heat capacity and spin temperature of the dipolar reservoir is analysed. It is shown both theoretically and experimentally that adiabatic (reversible) reduction of the dipolar Hamiltonian and its spin temperature is obtained when the amplitude of pulses (rotation angle) is slowly raised. The sudden switching on and off of the HW-8 sequence is then shown to lead to the same reversible reduction in a shorter time. It is also shown that, by this way, sensibility and selectivity of double resonance measurements of weak gyromagnetic ratio nuclei are strongly increased. This is experimentally illustrated in some cases. (author) [fr
Directory of Open Access Journals (Sweden)
Guyon Francois
2017-01-01
Full Text Available Measurements performed on a set of 32 authentic wines (not submitted to any oenological treatment and their ethanol, recovered by distillation, show high correlation between δ13C of bulk wine and its ethanol. These measurements were performed by isotope ratio monitoring by mass spectrometry coupled to an elemental analyzer (irm-EA/MS. Then a series of wines produced by vines of which water status was assessed during the growing season with predawn leaf water potential measurements, was studied by irm-EA/MS. As expected δ13C is correlated to vine water status conditions, as a result of stomatal closure. The ethanol of these specific wines was also analyzed by isotope ratio monitoring and by nuclear magnetic resonance (irm-13C NMR to determine carbon-13 composition on the two specific sites of the ethanol skeleton. If these measurements confirm the correlation between 13C composition and vine growth conditions, the 13C stereospecific information does not make vine water status assessment more precise.
Geometrical spin symmetry and spin
International Nuclear Information System (INIS)
Pestov, I. B.
2011-01-01
Unification of General Theory of Relativity and Quantum Mechanics leads to General Quantum Mechanics which includes into itself spindynamics as a theory of spin phenomena. The key concepts of spindynamics are geometrical spin symmetry and the spin field (space of defining representation of spin symmetry). The essence of spin is the bipolar structure of geometrical spin symmetry induced by the gravitational potential. The bipolar structure provides a natural derivation of the equations of spindynamics. Spindynamics involves all phenomena connected with spin and provides new understanding of the strong interaction.
International Nuclear Information System (INIS)
Jehenson, P.; Syrota, A.; Labrune, P.; Odievre, M.; Fardeau, M.
1995-01-01
We have developed a method for the evaluation of the muscle glycogen content by natural abundance C13 NMR and we here evaluate its diagnostic value on a large number of muscle diseases (20 glycogenoses and 42 other myopathies) and 8 normal subjects. The results show high values of the glycogen/creatine ratio in muscle glycogenoses, with no overlap with other diseased or normal subjects. This evaluation of the muscle glycogen content, which is performed at rest and thus easily applicable, in particular for children, is thus very sensitive and specific for the diagnosis of muscle glycogenosis. (authors). 9 refs
International Nuclear Information System (INIS)
Yoshida, M.; Kano, H.; Ishida, N.; Yoshida, T.
1989-01-01
The signals of fatty acids in the form of triglycerides were observed in the 13 C NMR spectrum of an intact soybean seed. The major fatty acid component composition of triglycerides in a soybean seed, which includes linoleic acid, oleic acid and palmitic acid, was estimated by subtracting the spectra of authentic fatty acids from the spectrum of the intact soybean seeds. The fatty acid compositions of seeds of 11 Japanese soybean cultivars and 5 lines bred at the Asian Vegetable Research and Development Center (AVRDC) were estimated by this rapid (within 1hr for one seed) and nondestructive analytical method. (author)
Directory of Open Access Journals (Sweden)
X. H. Liu
2015-10-01
Full Text Available We report a novel method of measuring the spin polarization of alkali-metal atoms by detecting the NMR frequency shifts of noble gases. We calculated the profile of 87Rb D1 line absorption cross sections. We then measured the absorption profile of the sample cell, from which we calculated the 87Rb number densities at different temperatures. Then we measured the frequency shifts resulted from the spin polarization of the 87Rb atoms and calculated its polarization degrees at different temperatures. The behavior of frequency shifts versus temperature in experiment was consistent with theoretical calculation, which may be used as compensative signal for the NMRG closed-loop control system.
International Nuclear Information System (INIS)
Baker, F.T.
1999-01-01
The work supported by this grant has had two main thrusts. One involved study of the spin, isospin, and multipole content of the continuum of nuclei, a continuation and completion of work done at LAMPF, Saturne, and TRIUMF. Most of the work has used (bar p, bar pprime) or (bar d, bar dprime) reactions, measuring spin observable to infer properties of the target nuclei. Publications resulting from this work have included seven refereed articles and letters, five abstracts and conference talks, one of which was invited. The second thrust involved preparatory work for experiments at CEBAF. The author was involved in Hall A work and the construction, installation, and initial experiments using the proton focal plane polarimeter. Experiments began in 1997 and no referred publications have yet been completed; ten abstracts and conference talks have been published
International Nuclear Information System (INIS)
Chanfray, G.
1988-01-01
We derive a semi-classical Wigner-Kirkwood expansion (Planck constant expansion) of the linear response functions. We find that the semi-classical results compare very well to the quantum mechanical calculations. We apply our formalism to the spin-isospin responses and show that surface-peaked Planck constant 2 corrections considerably decrease the ratio longitudinal/transverse as obtained through the Los Alamos (longitudinal momentum) experiment
Energy Technology Data Exchange (ETDEWEB)
Ikeno, R; Nakamura, H; Kohara, T [Graduate School of Material Science, University of Hyogo, Kamigori, Ako-gun, Hyogo 678-1297 (Japan)
2007-01-31
The cluster-spin dynamics of the tetrahedral Mo{sub 4} cluster, involved in AlMo{sub 4}S{sub 8} with a cubic GaMo{sub 4}S{sub 8} type structure, was investigated by NMR of the nonmagnetic {sup 27}Al site located outside the cluster. The nuclear spin-lattice relaxation is described well by the conventional local moment model assuming the presence of S=1/2 at each cluster, indicating that each Mo{sub 4} cluster behaves like a local spin with rigid magnitude. This behaviour is in contrast to the in-cluster relaxation, which reflects the spin-density fluctuations inside the cluster as a small unit of metal.
Jankowska, Marzena; Kupka, Teobald; Stobiński, Leszek; Faber, Rasmus; Lacerda, Evanildo G; Sauer, Stephan P A
2016-02-05
Hartree-Fock and density functional theory with the hybrid B3LYP and general gradient KT2 exchange-correlation functionals were used for nonrelativistic and relativistic nuclear magnetic shielding calculations of helium, neon, argon, krypton, and xenon dimers and free atoms. Relativistic corrections were calculated with the scalar and spin-orbit zeroth-order regular approximation Hamiltonian in combination with the large Slater-type basis set QZ4P as well as with the four-component Dirac-Coulomb Hamiltonian using Dyall's acv4z basis sets. The relativistic corrections to the nuclear magnetic shieldings and chemical shifts are combined with nonrelativistic coupled cluster singles and doubles with noniterative triple excitations [CCSD(T)] calculations using the very large polarization-consistent basis sets aug-pcSseg-4 for He, Ne and Ar, aug-pcSseg-3 for Kr, and the AQZP basis set for Xe. For the dimers also, zero-point vibrational (ZPV) corrections are obtained at the CCSD(T) level with the same basis sets were added. Best estimates of the dimer chemical shifts are generated from these nuclear magnetic shieldings and the relative importance of electron correlation, ZPV, and relativistic corrections for the shieldings and chemical shifts is analyzed. © 2015 Wiley Periodicals, Inc.
International Nuclear Information System (INIS)
Herbst, Christian; Herbst, Jirada; Kirschstein, Anika; Leppert, Joerg; Ohlenschlaeger, Oliver; Goerlach, Matthias; Ramachandran, Ramadurai
2009-01-01
The CN n ν class of RF pulse schemes, commonly employed for recoupling and decoupling of nuclear spin interactions in magic angle spinning solid state NMR studies of biological systems, involves the application of a basic 'C' element corresponding to an RF cycle with unity propagator. In this study, the design of CN n ν symmetry-based RF pulse sequences for achieving 13 C- 13 C double-quantum dipolar recoupling and through bond scalar coupling mediated 13 C- 13 C chemical shift correlation has been examined at high MAS frequencies employing broadband, constant-amplitude, phase-modulated basic 'C' elements. The basic elements were implemented as a sandwich of a small number of short pulses of equal duration with each pulse characterised by an RF phase value. The phase-modulation profile of the 'C' element was optimised numerically so as to generate efficient RF pulse sequences. The performances of the sequences were evaluated via numerical simulations and experimental measurements and are presented here
International Nuclear Information System (INIS)
Bendali, N.; Duong, H.T.; Saint-Jalm, J.M.; Vialle, J.L.
1984-01-01
Measurement of nuclear spin in the collinear laser spectroscopy method has been investigated using a fast sodium atomic beam excited collinearly by a C.W. single mode dye laser beam. The atomic magnetic moments are first aligned by optical pumping process, then they interact with a static magnetic field H 0 . The magnetic alignment of the atomic system just at the exit of the magnetic field is monitored by the laser induced fluorescence. Upon varying the amplitude of H 0 , the fluorescence signal presents a fringed structure. This structure is due to the Larmor precession of the aligned magnetic moments around H 0 , and therefore it is a signature of the spin involved. The modulation patterns corresponding to different relative orientations of H 0 and light polarization direction, are fitted by an analytical formula. In a second step, a classical magnetic resonance experiment with a static magnetic field and a radiofrequency field has been performed. The monocinetic character of our fast atomic beam allowed us to observe, even at high r.f. power, resonances line shapes in agreement with the Majorana formula
International Nuclear Information System (INIS)
Soubies, B.; Boulc'h, J.; Elsensohn, O.; Le Meur, M.; Henry, J.Y.
1994-06-01
The licensing procedures process of nuclear plants features compulsory steps which bring about a thorough exam of the commands control system. This analysis accounts for the aspects linked to technologies (integrated circuits, software packages) which have been chosen by the manufacturer for the programmed systems in charge of safety functions. Important innovations have been introduced in terms of design and manufacturing processes of safety systems of 1400 MWe pressurized water reactors, more precisely for the integrated numerical protection system (SPIN). The methodology used by the IPSN for the exam of the software of this system is presented in the communication. This methodology leads the IPSN to carry out studies and developments of tools keeping in sight as their main goal to bring substantial help to analysis. (authors). 2 refs
Righi, Valeria; Parenti, Francesca; Tugnoli, Vitaliano; Schenetti, Luisa; Mucci, Adele
2015-09-30
Intact Crocus sativus petals were studied for the first time by high-resolution magic angle spinning nuclear magnetic resonance (HR-MAS NMR) spectroscopy, revealing the presence of kinsenoside (2) and goodyeroside A (3), together with 3-hydroxy-γ-butyrolactone (4). These findings were confirmed by HR-NMR analysis of the ethanol extract of fresh petals and showed that, even though carried out rapidly, partial hydrolysis of glucopyranosyloxybutanolides occurs during extraction. On the other hand, kaempferol 3-O-sophoroside (1), which is "NMR-silent" in intact petals, is present in extracts. These results suggest to evaluate the utilization of saffron petals for phytopharmaceutical and nutraceutical purposes to exploit a waste product of massive production of commercial saffron and point to the application of HR-MAS NMR for monitoring bioactive compounds directly on intact petals, avoiding the extraction procedure and the consequent hydrolysis reaction.
Directory of Open Access Journals (Sweden)
Piotto Martial
2012-01-01
Full Text Available Abstract Introduction Providing information on cancerous tissue samples during a surgical operation can help surgeons delineate the limits of a tumoral invasion more reliably. Here, we describe the use of metabolic profiling of a colon biopsy specimen by high resolution magic angle spinning nuclear magnetic resonance spectroscopy to evaluate tumoral invasion during a simulated surgical operation. Case presentation Biopsy specimens (n = 9 originating from the excised right colon of a 66-year-old Caucasian women with an adenocarcinoma were automatically analyzed using a previously built statistical model. Conclusions Metabolic profiling results were in full agreement with those of a histopathological analysis. The time-response of the technique is sufficiently fast for it to be used effectively during a real operation (17 min/sample. Metabolic profiling has the potential to become a method to rapidly characterize cancerous biopsies in the operation theater.
Vingerhoets, P; Avgoulea, M; Billowes, J; Bissell, M L; Blaum, K; Brown, B A; Cheal, B; De Rydt, M; Forest, D H; Geppert, Ch; Honma, M; Kowalska, M; Kramer, J; Krieger, A; Mane, E; Neugart, R; Neyens, G; Nortershauser, W; Otsuka, T; Schug, M; Stroke, H H; Tungate, G; Yordanov, D T
2010-01-01
Measurements of the ground-state nuclear spins, magnetic and quadrupole moments of the copper isotopes from 61Cu up to 75Cu are reported. The experiments were performed at the ISOLDE facility, using the technique of collinear laser spectroscopy. The trend in the magnetic moments between the N=28 and N=50 shell closures is reasonably reproduced by large-scale shell-model calculations starting from a 56Ni core. The quadrupole moments reveal a strong polarization of the underlying Ni core when the neutron shell is opened, which is however strongly reduced at N=40 due to the parity change between the $pf$ and $g$ orbits. No enhanced core polarization is seen beyond N=40. Deviations between measured and calculated moments are attributed to the softness of the 56Ni core and weakening of the Z=28 and N=28 shell gaps.
International Nuclear Information System (INIS)
Glyde, H.R.; Hernadi, S.I.
1986-01-01
Several ground state properties of (electron) spin-polarized deuterium (D) such as the energy, single quasiparticle energies and lifetimes, Landau parameters and sound velocities are evaluated. The calculations begin with the Kolos-Wolneiwicz potential and use the Galitskii-FeynmanHartree-Fock (GFHF) approximation. The deuteron nucleas has spin I = 1, and spin states I/sub z/ = 1,0,-1. We explore D 1 , D 2 and D 3 in which, respectively, one spin state only is populated, two states are equally populated, and three states are equally populated. We find the GFHF describes D 1 well, but D 2 and D 3 less well. The Landau parameters, F/sub L/, are small compared to liquid 3 He and very small for doubly polarized D 1 (i.e. the F/sub L/ decrease with nuclear polarization)
Hu, Jian Zhi; Hu, Mary Y.; Townsend, Mark R.; Lercher, Johannes A.; Peden, Charles H. F.
2015-10-06
Re-usable ceramic magic angle spinning (MAS) NMR rotors constructed of high-mechanic strength ceramics are detailed that include a sample compartment that maintains high pressures up to at least about 200 atmospheres (atm) and high temperatures up to about least about 300.degree. C. during operation. The rotor designs minimize pressure losses stemming from penetration over an extended period of time. The present invention makes possible a variety of in-situ high pressure, high temperature MAS NMR experiments not previously achieved in the prior art.
Jenni, Kevin; Scherthan, Lena; Faus, Isabelle; Marx, Jennifer; Strohm, Cornelius; Herlitschke, Marcus; Wille, Hans-Christian; Würtz, Peter; Schünemann, Volker; Wolny, Juliusz A
2017-07-26
Nuclear inelastic scattering (NIS) experiments have been performed in order to study the vibrational dynamics of the low- and high-spin states of the polynuclear 1D spin crossover compound [Fe(1,2,4-triazole) 2 (1,2,4-triazolato)](BF 4 ) (1). Density functional theory (DFT) calculations using the functional B3LYP* and the basis set CEP-31G for heptameric and nonameric models of the compound yielded the normal vibrations and electronic energies for high-spin and low-spin isomers of three models differing in the distribution of anionic trz - ligands and BF 4 - anions. On the basis of the obtained energies a structural model with a centrosymmetric Fe(trzH) 4 (trz - ) 2 coordination core of the mononuclear unit of the chain is proposed. The obtained distribution of the BF 4 - counteranions in the proposed structure is similar to that obtained on the basis of X-ray powder diffraction studies by Grossjean et al. (Eur. J. Inorg. Chem., 2013, 796). The NIS data of the system diluted to 10% Fe(ii) content in a 90% Zn(ii) matrix (compound (2)) show a characteristic change of the spectral pattern of the low-spin centres, compared to the low-spin phase of the parent Fe(ii) complex (1). DFT calculations reveal that this is caused by a change of the structure of the neighbours of the low-spin centres. The spectral pattern of the high-spin centres in (2) is within a good approximation identical to that of the high-spin Fe(ii) isomer of (1). The inspection of the molecular orbitals of the monomeric model systems of [Fe(trzH) 4 (trz - ) 2 ] and [Fe(trzH) 6 ], together with calculations of spin transition energies, point towards the importance of an electrostatic effect caused by the negatively charged ligands. This results in the stabilisation of the low-spin state of the complex containing the anionic ligand and shortening of the Fe-N(trz - ) compared to the Fe-N(trzH) bond in high-spin, but not in low-spin [Fe(trzH) 4 (trz - ) 2 ].
Spin physics in semiconductors
Dyakonov, Mikhail I
2008-01-01
This book describes beautiful optical and transport phenomena related to the electron and nuclear spins in semiconductors with emphasis on a clear presentation of the physics involved. Recent results on quantum wells and quantum dots are reviewed. The book is intended for students and researchers in the fields of semiconductor physics and nanoelectronics.
International Nuclear Information System (INIS)
Sen, P.N.; Andre, A.; Axelrod, S.
1999-01-01
We study the influence of restriction on Carr - Purcell - Meiboom - Gill spin echoes response of magnetization of spins diffusing in a bounded region in the presence of a constant magnetic field gradient. Depending on three main length scales: L S pore size, L G dephasing length and L D diffusion length during half-echo time, three main regimes of decay have been identified: free, localization and motionally averaging regime. In localization regime, the decay exponent depends on a fractional power (2/3) of the gradient, denoting a strong breakdown of the second cumulant or the Gaussian phase approximation (GPA). In the other two regimes, the exponent depends on the gradient squared, and the GPA holds. We find that the transition from the localization to the motionally averaging regime happens when the magnetic field gradients approach special values, corresponding to branch points of the eigenvalues. Transition from one regime to another as a function of echo number for a certain range of parameters is discussed. In this transition region, the signal shows large oscillations with echo number. For large n, asymptotic behavior sets in as a function of n for the decay exponent per echo. This is true for all values of the parameters L S , L G , and L D . copyright 1999 American Institute of Physics
NMR studies of spin dynamics in cuprates
International Nuclear Information System (INIS)
Takigawa, M.; Mitzi, D.B.
1994-01-01
The authors report recent NMR results in cuprates. The oxygen Knight shift and the Cu nuclear spin-lattice relaxation rate in Bi 2.1 Sr 1.94 Ca 0.88 Cu 2.07 O 8+σ single crystals revealed a gapless superconducting state, which can be most naturally explained by a d-wave pairing state and the intrinsic disorder in this material. The Cu nuclear spin-spin relaxation rate in underdoped YBa 2 Cu 3 O 6.63 shows distinct temperature dependence from the spin-lattice relaxation rate, providing direct evidence for a pseudo spin-gap near the antiferromagnetic wave vector
NMR studies of spin dynamics in cuprates
Takigawa, M.; Mitzi, D. B.
1994-04-01
We report recent NMR results in cuprates. The oxygen Knight shift and the Cu nuclear spin-lattice relaxation rate in Bi2.1Sr1.94Ca0.88Cu2.07O8+δ single crystals revealed a gapless superconducting state, which can be most naturally explained by a d-wave pairing state and the intrinsic disorder in this material. The Cu nuclear spin-spin relaxation rate in underdoped YBa2Cu3O6.63 shows distinct temperature dependence from the spin-lattice relaxation rate, providing direct evidence for a pseudo spin-gap near the antiferromagnetic wave vector.
International Nuclear Information System (INIS)
Zielinski, M.; Zielinska, A.; Papiernik-Zielinska, H.; McKenzie, J.A.; Bernasconi, S.; Paul, H.
1998-01-01
Carbon-13 and oxygen-18 isotope effects in the decarboxylation of nicotinic acid of natural isotopic composition above and below its melting temperature have been studied and compared with the primary (PKIE) and secondary kinetic isotope effects (SKIE) of 13 C and 18 O, respectively, in the decarboxylation of other heterocyclic acids. The temperature dependence of the secondary oxygen-18 isotope effects is negative in the total 221-255 deg C temperature interval investigated initially. The 13 C KIE measured above melting point of N.A. (temperature interval 235-270 deg C) are located in the range 1.007-1.009. Below melting point of nicotinic acid the 13 C KIE are larger and reveal the negative temperature dependence ( 13 C KIE decreases with decreasing the reaction temperature from 1.013/at 230 deg C to 1.0114/at 221 deg C). A discussion of the above isotopic results is presented. (author)
Summary of spin physics sessions
International Nuclear Information System (INIS)
Roser, T.
1988-01-01
The list of topics in the many talks given during the Spin Physics sessions of this Intersections conference is nearly as long as the one of this conference: P and T Violation NN Interaction πp and πd Elastic Scattering Nuclear Matter Spin Effects Muon (g-2) Polarized Proton Beams Polarized Gas Targets This points to the almost trivial fact that spin is fundamental to our understanding of nuclear and particle physics. I will discuss in some detail only four of these topics. Needless to say this choice is very much personally biased and I apologize to all the speakers whose excellent contributions I did not include
International Nuclear Information System (INIS)
Hussin, R.; Holland, D.; Dupree, R.
2000-01-01
Crystalline products of sodium germanate glasses system with composition from 10 mol% to 50 mol% Na 2 O have been investigated using 23 Na magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy and x-ray diffraction (XRD). Fitting of the 23 Na NMR spectra of the crystalline phases concerning different crystallographically sodium atom in sodium germanate system are reasonably reproducible as observed by the spectra obtained. The line shape simulations of the 23 Na NMR spectra yielded NMR quadrupolar parameters such as nuclear quadrupole coupling constants (C Q ), asymmetry parameters (η), and isotropic chemical shifts (δ i ). 23 Na NMR isotropic chemical shift may also provide further information on the structural environment of the sodium atom. A simple correlation between structure and NMR parameters to be tested can be used to probe the structure of sodium germanate glasses. The experimental 23 Na chemical shifts correlate well with an empirical shift parameter based on the total oxygen-cation bond valence and Na-O distances of all oxygen atoms in the first coordination sphere of the sodium cation. In this study the different phases in the sodium germanate system were identified. These results show that 23 Na NMR can provide examples of the types of structural information for sodium germanate system. (Author)
International Nuclear Information System (INIS)
Raghunath, B.; Iyer, M.R.; Samant, S.D.
1995-01-01
Solid state nuclear track detectors (SSNTD) are widely used in the detection and measurement of ionizing particles. Cellulose nitrate (CN) films are commonly used as SSNTD for the measurement of radon/thoron gases and their decay products. A simple method for making uniform thin CN films of various thickness has been developed. Performance of these films is compared with commercially available film. (Author)
Energy Technology Data Exchange (ETDEWEB)
Raghunath, B.; Iyer, M.R. [Bhabha Atomic Research Centre, Bombay (India); Samant, S.D. [Bombay Univ. (India). Dept. of Chemical Technology
1995-01-01
Solid state nuclear track detectors (SSNTD) are widely used in the detection and measurement of ionizing particles. Cellulose nitrate (CN) films are commonly used as SSNTD for the measurement of radon/thoron gases and their decay products. A simple method for making uniform thin CN films of various thickness has been developed. Performance of these films is compared with commercially available film. (Author).
International Nuclear Information System (INIS)
Mahieu, Nathalie
1992-01-01
The work reported in this research thesis aimed at characterizing micellar phases formed by some surfactants (sodium carboxylates) in aqueous solution. After some recalls on nuclear magnetic resonance dealing with spin relaxation (longitudinal relaxation, transverse relaxation, relaxation in the rotating coordinate system, and crossed relaxation), and comments on the dipolar mechanism responsible of relaxation phenomena, the author presents the methods used for relaxation parameter measurement and the data processing software issued from experiments. He presents experiments which allowed the self-diffusion coefficient to be measured, reports data processing, and addresses problems of special diffusion and of coherence transfers during diffusion measurements. Results of proton relaxation measurements are then presented and discussed. They are used to determine the micellar state of the studied carboxylates. The case of the oleate is also addressed. Measurements of carbon-13 relaxation times are reported, and exploited in terms of structural parameters by using the Relaxator software. An original method of the hetero-nuclear Overhauser method is presented, and used to assess the average distance between water molecules and micelle surface [fr
Valenzuela, Sergio O; Saitoh, Eiji; Kimura, Takashi
2017-01-01
Since the discovery of the giant magnetoresistance effect in magnetic multilayers in 1988, a new branch of physics and technology, called spin-electronics or spintronics, has emerged, where the flow of electrical charge as well as the flow of electron spin, the so-called “spin current,” are manipulated and controlled together. The physics of magnetism and the application of spin current have progressed in tandem with the nanofabrication technology of magnets and the engineering of interfaces and thin films. This book aims to provide an introduction and guide to the new physics and applications of spin current, with an emphasis on the interaction between spin and charge currents in magnetic nanostructures.
Experimental status of high-spin states
International Nuclear Information System (INIS)
Stephens, F.S.
1975-09-01
Changes occurring in high spin nuclear states are discussed. Experimental methods for studying reduction and eventual quenching of pairing interactions, changes in nuclear shapes, and alignment of individual particle angular momenta with increasing spin are reviewed. Emphasis is placed on the study of continuum gamma rays following heavy ion reactions. (12 figures)
Vozková, Markéta
2011-01-01
1 ABSTRACT The aim of this text is to provide an analysis of the phenomenon of spin doctoring in the Euro-Atlantic area. Spin doctors are educated people in the fields of semiotics, cultural studies, public relations, political communication and especially familiar with the infrastructure and the functioning of the media industry. Critical reflection of manipulative communication techniques puts spin phenomenon in historical perspective and traces its practical use in today's social communica...
International Nuclear Information System (INIS)
Mechergui, M.; Daaloul, A.; Snane, M.H.
1995-01-01
Carbon-13 isotope discrimination method and water balance model Using neutron probe are the two tools used in this study to genotypes for water use efficiency. It is a three years experiment and the results presented will be for the last year. Four durum wheat Cvs were selected and planted in a randomnized block design with 6 replicates. Total consumption of water was calculated. Grain and strow yields and other parameters were recorded. The carbon isotope ratio which illustrates carbon 13 dicrimination is measured for each genotype in grain and strow. The total and the grain water use efficiency were calculated and correlated to the G C-13 isotope dicrimination to compare genotypes between them. The main results presented in this paper revealed that. Carbon-13 discrimination technique is an excellent screening technique for screening for water use in cultivars in semi-arid conditions. 2 fig., 3 tabs
Energy Technology Data Exchange (ETDEWEB)
Mechergui, M; Daaloul, A [Institut National Agronomique de Tunisie, 43, Avenue Charles Nicolle - 1082 Tunis Mahrajene - (Tunisia); Snane, M H [Institut National Agronomique de (Tunisia)
1995-10-01
Carbon-13 isotope discrimination method and water balance model Using neutron probe are the two tools used in this study to genotypes for water use efficiency. It is a three years experiment and the results presented will be for the last year. Four durum wheat Cvs were selected and planted in a randomnized block design with 6 replicates. Total consumption of water was calculated. Grain and strow yields and other parameters were recorded. The carbon isotope ratio which illustrates carbon 13 dicrimination is measured for each genotype in grain and strow. The total and the grain water use efficiency were calculated and correlated to the G C-13 isotope dicrimination to compare genotypes between them. The main results presented in this paper revealed that. Carbon-13 discrimination technique is an excellent screening technique for screening for water use in cultivars in semi-arid conditions. 2 fig., 3 tabs.
Directory of Open Access Journals (Sweden)
A. Gover
2006-06-01
Full Text Available The problems of spin-polarized free-electron beam interaction with electromagnetic wave at electron-spin resonance conditions in a magnetic field and of superradiant spin-flip radiative emission are analyzed in the framework of a comprehensive classical model. The spontaneous emission of spin-flip radiation from electron beams is very weak. We show that the detectivity of electron spin resonant spin-flip and combined spin-flip/cyclotron-resonance-emission radiation can be substantially enhanced by operating with ultrashort spin-polarized electron beam bunches under conditions of superradiant (coherent emission. The proposed radiative spin-state modulation and the spin-flip radiative emission schemes can be used for control and noninvasive diagnostics of polarized electron/positron beams. Such schemes are of relevance in important scattering experiments off nucleons in nuclear physics and off magnetic targets in condensed matter physics.
Energy Technology Data Exchange (ETDEWEB)
Sigl, A.
2007-12-28
A methyl group is an outstanding quantum system due to its special symmetry properties. The threefold rotation around one of its bond is isomorphic to the group of even permutations of the remaining protons, a property which imposes severe quantum restrictions on the system, for instance a strict correlation of rotational states with nuclear spin states. The resulting long lifetimes of the rotational tunneling states of the methyl group can be exploited for applying certain high resolution optical techniques, like hole burning or single molecule spectroscopy to optically switch the methyl group from one tunneling state to another therebye changing the nuclear spin of the protons. One goal of the thesis was to perform this switching in single methyl groups. To this end the methyl group was attached to a chromophoric system, in the present case terrylene, which is well suited for single molecule spectroscopy as well as for hole burning. Experiments were performed with the bare terrylene molecule in a hexadecane lattice which served as a reference system, with alphamethyl terrylene and betamethyl terrylene, both embedded in hexadecane, too. A single molecular probe is a highly sensitive detector for dynamic lattice instabilities. Already the bare terrylene probe showed a wealth of interesting local dynamic effects of the hexadecane lattice which could be well acounted for by the assumption of two nearly degenerate sites with rather different optical and thermal properties, all of which could be determined in a quantitative fashion. As to the methylated terrylene systems, the experiments verified that for betamethyl terrylene it is indeed possible to measure rotational tunneling events in single methyl groups. However, the spectral patterns obtained was much more complicated than expected pointing to the presence of three spectroscopically different methyl groups. In order to achieve a definite assignement, molecular mechanics simulations of the terrylene probes in the
International Nuclear Information System (INIS)
Anton, Gisela
1990-01-01
The idea of the intrinsic angular momentum, or 'spin', of a particle has played an essential part in fundamental physics for more than 60 years, and its continuing importance was underlined at the 9th International Symposium on High Energy Spin Physics, held in September in Bonn.
Energy Technology Data Exchange (ETDEWEB)
Anton, Gisela
1990-12-15
The idea of the intrinsic angular momentum, or 'spin', of a particle has played an essential part in fundamental physics for more than 60 years, and its continuing importance was underlined at the 9th International Symposium on High Energy Spin Physics, held in September in Bonn.
Energy Technology Data Exchange (ETDEWEB)
D' Ariano, G M [Quantum Optics and Information Group, INFM Udr Pavia, Dipartimento di Fisica ' Alessandro Volta' and INFM, Via Bassi 6, 27100 Pavia (Italy); Maccone, L [Quantum Optics and Information Group, INFM Udr Pavia, Dipartimento di Fisica ' Alessandro Volta' and INFM, Via Bassi 6, 27100 Pavia (Italy); Paini, M [Quantum Optics and Information Group, INFM Udr Pavia, Dipartimento di Fisica ' Alessandro Volta' and INFM, Via Bassi 6, 27100 Pavia (Italy)
2003-02-01
We propose a tomographic reconstruction scheme for spin states. The experimental set-up, which is a modification of the Stern-Gerlach scheme, can be easily performed with currently available technology. The method is generalized to multiparticle states, analysing the spin-1/2 case for indistinguishable particles. Some Monte Carlo numerical simulations are given to illustrate the technique.
International Nuclear Information System (INIS)
D'Ariano, G M; Maccone, L; Paini, M
2003-01-01
We propose a tomographic reconstruction scheme for spin states. The experimental set-up, which is a modification of the Stern-Gerlach scheme, can be easily performed with currently available technology. The method is generalized to multiparticle states, analysing the spin-1/2 case for indistinguishable particles. Some Monte Carlo numerical simulations are given to illustrate the technique
Bovier, Anton
2007-01-01
Spin glass theory is going through a stunning period of progress while finding exciting new applications in areas beyond theoretical physics, in particular in combinatorics and computer science. This collection of state-of-the-art review papers written by leading experts in the field covers the topic from a wide variety of angles. The topics covered are mean field spin glasses, including a pedagogical account of Talagrand's proof of the Parisi solution, short range spin glasses, emphasizing the open problem of the relevance of the mean-field theory for lattice models, and the dynamics of spin glasses, in particular the problem of ageing in mean field models. The book will serve as a concise introduction to the state of the art of spin glass theory, usefull to both graduate students and young researchers, as well as to anyone curious to know what is going on in this exciting area of mathematical physics.
Energy Technology Data Exchange (ETDEWEB)
Anon.
1989-01-15
The recent 8th International Symposium on High Energy Spin Physics at the University of Minnesota in Minneapolis, Minnesota, opened with a bang when L. Pondrom (Wisconsin), donning a hard hat borrowed from construction workers, ventured that 'spin, the notorious inessential complication of hadronic physics, is finally telling us what real QCD (quantum chromodynamics, the field theory of quarks and gluons) looks like.' He was referring to an animated discussion on the meaning of the recent spin oriented (polarized) scattering results from the European Muon Collaboration (EMC) at CERN and reported at the Symposium by R. Garnet (Liverpool) and P. Schuler (Yale) which show that the proton spin is not simply a reflection of the spins of its constituent quarks.
Shishmarev, Dmitry; Wright, Alan J; Rodrigues, Tiago B; Pileio, Giuseppe; Stevanato, Gabriele; Brindle, Kevin M; Kuchel, Philip W
2018-03-01
Fumarate is an important probe of metabolism in hyperpolarized magnetic resonance imaging and spectroscopy. It is used to detect the release of fumarase in cancer tissues, which is associated with necrosis and drug treatment. Nevertheless, there are limited reports describing the detailed kinetic studies of this enzyme in various cells and tissues. Thus, we aimed to evaluate the sub-minute kinetics of human red blood cell fumarase using nuclear magnetic resonance (NMR) spectroscopy, and to provide a quantitative description of the enzyme that is relevant to the use of fumarate as a probe of cell rupture. The fumarase reaction was studied using time courses of 1 H spin-echo and 13 C-NMR spectra. 1 H-NMR experiments showed that the fumarase reaction in hemolysates is sufficiently rapid to make its kinetics amenable to study in a period of approximately 3 min, a timescale characteristic of hyperpolarized 13 C-NMR spectroscopy. The rapid-dissolution dynamic nuclear polarization (RD-DNP) technique was used to hyperpolarize [1,4- 13 C]fumarate, which was injected into concentrated hemolysates. The kinetic data were analyzed using recently developed FmR α analysis and modeling of the enzymatic reaction using Michaelis-Menten equations. In RD-DNP experiments, the decline in the 13 C-NMR signal from fumarate, and the concurrent rise and fall of that from malate, were captured with high spectral resolution and signal-to-noise ratio, which allowed the robust quantification of fumarase kinetics. The kinetic parameters obtained indicate the potential contribution of hemolysis to the overall rate of the fumarase reaction when 13 C-NMR RD-DNP is used to detect necrosis in animal models of implanted tumors. The analytical procedures developed will be applicable to studies of other rapid enzymatic reactions using conventional and hyperpolarized substrate NMR spectroscopy. Copyright © 2018 John Wiley & Sons, Ltd.
Mazzei, Pierluigi; Vinale, Francesco; Woo, Sheridan Lois; Pascale, Alberto; Lorito, Matteo; Piccolo, Alessandro
2016-05-11
Trichoderma fungi release 6-pentyl-2H-pyran-2-one (1) and harzianic acid (2) secondary metabolites to improve plant growth and health protection. We isolated metabolites 1 and 2 from Trichoderma strains, whose different concentrations were used to treat seeds of Solanum lycopersicum. The metabolic profile in the resulting 15 day old tomato leaves was studied by high-resolution magic-angle-spinning nuclear magnetic resonance (HRMAS NMR) spectroscopy directly on the whole samples without any preliminary extraction. Principal component analysis (PCA) of HRMAS NMR showed significantly enhanced acetylcholine and γ-aminobutyric acid (GABA) content accompanied by variable amount of amino acids in samples treated with both Trichoderma secondary metabolites. Seed germination rates, seedling fresh weight, and the metabolome of tomato leaves were also dependent upon doses of metabolites 1 and 2 treatments. HRMAS NMR spectroscopy was proven to represent a rapid and reliable technique for evaluating specific changes in the metabolome of plant leaves and calibrating the best concentration of bioactive compounds required to stimulate plant growth.
International Nuclear Information System (INIS)
Deaton, M. Brett; Duez, Matthew D.; Foucart, Francois; O'Connor, Evan; Ott, Christian D.; Scheel, Mark A.; Szilagyi, Bela; Kidder, Lawrence E.; Muhlberger, Curran D.
2013-01-01
Neutrino emission significantly affects the evolution of the accretion tori formed in black hole-neutron star mergers. It removes energy from the disk, alters its composition, and provides a potential power source for a gamma-ray burst. To study these effects, simulations in general relativity with a hot microphysical equation of state (EOS) and neutrino feedback are needed. We present the first such simulation, using a neutrino leakage scheme for cooling to capture the most essential effects and considering a moderate mass (1.4 M ☉ neutron star, 5.6 M ☉ black hole), high-spin (black hole J/M 2 = 0.9) system with the K 0 = 220 MeV Lattimer-Swesty EOS. We find that about 0.08 M ☉ of nuclear matter is ejected from the system, while another 0.3 M ☉ forms a hot, compact accretion disk. The primary effects of the escaping neutrinos are (1) to make the disk much denser and more compact, (2) to cause the average electron fraction Y e of the disk to rise to about 0.2 and then gradually decrease again, and (3) to gradually cool the disk. The disk is initially hot (T ∼ 6 MeV) and luminous in neutrinos (L ν ∼ 10 54 erg s –1 ), but the neutrino luminosity decreases by an order of magnitude over 50 ms of post-merger evolution
Kennedy, Gordon J; Afeworki, Mobae; Calabro, David C; Chase, Clarence E; Smiley, Randolph J
2004-06-01
Distinct hydrogen species are present in important inorganic solids such as zeolites, silicoaluminophosphates (SAPOs), mesoporous materials, amorphous silicas, and aluminas. These H species include hydrogens associated with acidic sites such as Al(OH)Si, non-framework aluminum sites, silanols, and surface functionalities. Direct and quantitative methodology to identify, measure, and monitor these hydrogen species are key to monitoring catalyst activity, optimizing synthesis conditions, tracking post-synthesis structural modifications, and in the preparation of novel catalytic materials. Many workers have developed several techniques to address these issues, including 1H MAS NMR (magic-angle spinning nuclear magnetic resonance). 1H MAS NMR offers many potential advantages over other techniques, but care is needed in recognizing experimental limitations and developing sample handling and NMR methodology to obtain quantitatively reliable data. A simplified approach is described that permits vacuum dehydration of multiple samples simultaneously and directly in the MAS rotor without the need for epoxy, flame sealing, or extensive glovebox use. We have found that careful optimization of important NMR conditions, such as magnetic field homogeneity and magic angle setting are necessary to acquire quantitative, high-resolution spectra that accurately measure the concentrations of the different hydrogen species present. Details of this 1H MAS NMR methodology with representative applications to zeolites, SAPOs, M41S, and silicas as a function of synthesis conditions and post-synthesis treatments (i.e., steaming, thermal dehydroxylation, and functionalization) are presented.
International Nuclear Information System (INIS)
Holmlid, Leif
2009-01-01
Clusters of the electronically excited condensed matter Rydberg matter (RM) are planar and sixfold symmetric with specific magic numbers N as shown by rotational spectroscopy of potassium K N clusters [L. Holmlid, Mol. Phys. 105 (2007) 933; L. Holmlid, J. Mol. Struct. 885 (2008) 122]. In radio frequency emission spectra from such clusters, features are observed that are due to the hyperfine interaction between the atomic nucleus 39 K and two Rydberg electrons. These electrons exist in a doubly excited K atom at n'' = 5 or 6 in a 'sleeping-top' type rotating cluster. Such low excited electrons were observed recently in optical intra-cavity experiments in K(RM), where the electrons in the conduction band are involved in the angular momentum conservation in the stimulated emission. Here we show that the agreement with the theoretical description of circular Rydberg states is excellent within ±0.2% in the magnetic field, invoking angular momentum conservation by electrons in the condensed phase. Sleeping-top clusters may form stacks of clusters, and it is likely that such stacks are the emitting entities involved in the two nuclear spin series observed.
Energy Technology Data Exchange (ETDEWEB)
Kaiser, Carlos R; Rittner, Roberto [Universidade Estadual de Campinas, SP (Brazil). Inst. de Quimica; Basso, Ernani A [Universidade Estadual de Maringa, PR (Brazil). Dept. de Quimica Inorganica
1994-12-31
This work presents and discusses the empirical effects of substitution groups in the carbon-13 NMR spectra of tri-substituted camphors and their correlation with the chemical properties of such substitution groups such as electronegativity. The obtained results are presented and discussed
Caspers, W J
1989-01-01
This book is about spin systems as models for magnetic materials, especially antiferromagnetic lattices. Spin-systems are well-defined models, for which, in special cases, exact properties may be derived. These special cases are for the greater part, one- dimensional and restricted in their applicability, but they may give insight into general properties that also exist in higher dimension. This work pays special attention to qualitative differences between spin lattices of different dimensions. It also replaces the traditional picture of an (ordered) antiferromagnetic state of a Heisenberg sy
Nuclear magnetic resonance data of C36H30Br2OSb2
Mikhova, B. M.
This document is part of Part 6 `Organic Metalloid Compounds' of Subvolume D 'Chemical Shifts and Coupling Constants for Carbon-13' of Landolt-Börnstein III/35 'Nuclear Magnetic Resonance Data', Group III 'Condensed Matter'.
Nuclear magnetic resonance data of C36H30Cl2OSb2
Mikhova, B. M.
This document is part of Part 6 `Organic Metalloid Compounds' of Subvolume D 'Chemical Shifts and Coupling Constants for Carbon-13' of Landolt-Börnstein III/35 'Nuclear Magnetic Resonance Data', Group III 'Condensed Matter'.
Buhrman, Robert; Daughton, James; Molnár, Stephan; Roukes, Michael
2004-01-01
This report is a comparative review of spin electronics ("spintronics") research and development activities in the United States, Japan, and Western Europe conducted by a panel of leading U.S. experts in the field. It covers materials, fabrication and characterization of magnetic nanostructures, magnetism and spin control in magnetic nanostructures, magneto-optical properties of semiconductors, and magnetoelectronics and devices. The panel's conclusions are based on a literature review and a series of site visits to leading spin electronics research centers in Japan and Western Europe. The panel found that Japan is clearly the world leader in new material synthesis and characterization; it is also a leader in magneto-optical properties of semiconductor devices. Europe is strong in theory pertaining to spin electronics, including injection device structures such as tunneling devices, and band structure predictions of materials properties, and in development of magnetic semiconductors and semiconductor heterost...
International Nuclear Information System (INIS)
Anon.
1983-01-01
The 5th International Symposium on High Energy Spin Physics met in September at Brookhaven. The symposium has evolved to include a number of diverse specialities: theory, including parity violations and proposed quantum chromodynamics (QCD) tests with polarized beams; experiment, including the large spin effects discovered in high transverse momentum elastic scattering and hyperon production, dibaryons, and magnetic moments; acceleration and storage of polarized protons and electrons; and development of polarized sources and targets
Energy Technology Data Exchange (ETDEWEB)
Okamoto, K.; Tsukada, Y. [Toshiba Corp., Tokyo (Japan)
1998-10-10
Carbon-13 magnetic resonance spectroscopy ({sup 13}C-MRS) and research and development efforts for brain metabolism measurement are described. Brain metabolism is a process characterized in that it not only extracts energy by disintegrating grape sugar that is the practically sole source of energy into H2O, CO2, etc., but also vigorously synthesizes amino acids that perform important functions in neural transmission, such as glutamic acid, glutamine, and {gamma}-amino acid. MRS is a technique that utilizes the magnetic resonance, which is generated when an atomic nucleus with a spin is placed in a magnetic field, for the isolation and identification of chemicals in a living body through examining the delicate difference in the magnetic resonance frequencies of the nuclei under observation. Since the signals from {sup 13}C are low in intensity as compared with those from other nuclides, a method was contrived around 1980, which observes {sup 1}H combined with {sup 13}C in grape sugar and amino acids, named the HSQC (heteronuclear single quantum coherence) method. The author et al., combining gradient magnetic pulses with HSQC, actually measure Homo sapiens brain metabolism using {sup 13}C-MRS, and now believe that the technology will be put to practical application. 7 refs., 10 figs., 1 tab.
Energy Technology Data Exchange (ETDEWEB)
Shingledecker, Christopher N.; Le Gal, Romane; Hincelin, Ugo; Herbst, Eric [Department of Chemistry, University of Virginia, Charlottesville, VA 22904 (United States); Bergner, Jennifer B. [Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138 (United States); Öberg, Karin I., E-mail: shingledecker@virginia.edu [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)
2016-10-20
The chemistry of dense interstellar regions was analyzed using a time-dependent gas–grain astrochemical simulation and a new chemical network that incorporates deuterated chemistry, taking into account nuclear spin states for the hydrogen chemistry and its deuterated isotopologues. With this new network, the utility of the [HCO{sup +}]/[DCO{sup +}] abundance ratio as a probe of the cosmic-ray ionization rate has been re-examined, with special attention paid to the effect of the initial value of the ortho-to-para ratio (OPR) of molecular hydrogen. After discussing the use of the probe for cold cores, we compare our results with previous theoretical and observational results for a molecular cloud close to the supernova remnant W51C, which is thought to have an enhanced cosmic-ray ionization rate ζ caused by the nearby γ -ray source. In addition, we attempt to use our approach to estimate the cosmic-ray ionization rate for L1174, a dense core with an embedded star. Beyond the previously known sensitivity of [HCO{sup +}]/[DCO{sup +}] to ζ , we demonstrate its additional dependence on the initial OPR and, secondarily, on the age of the source, its temperature, and its density. We conclude that the usefulness of the [HCO{sup +}]/[DCO{sup +}] abundance ratio in constraining the cosmic-ray ionization rate in dense regions increases with the age of the source and the ionization rate as the ratio becomes far less sensitive to the initial value of the OPR.
Energy Technology Data Exchange (ETDEWEB)
Deaton, M. Brett; Duez, Matthew D. [Department of Physics and Astronomy, Washington State University, Pullman, WA 99164 (United States); Foucart, Francois; O' Connor, Evan [Canadian Institute for Theoretical Astrophysics, University of Toronto, Toronto, Ontario M5S 3H8 (Canada); Ott, Christian D.; Scheel, Mark A.; Szilagyi, Bela [TAPIR, MC 350-17, California Institute of Technology, Pasadena, CA 91125 (United States); Kidder, Lawrence E.; Muhlberger, Curran D., E-mail: mbdeaton@wsu.edu, E-mail: m.duez@wsu.edu [Center for Radiophysics and Space Research, Cornell University, Ithaca, NY 14853 (United States)
2013-10-10
Neutrino emission significantly affects the evolution of the accretion tori formed in black hole-neutron star mergers. It removes energy from the disk, alters its composition, and provides a potential power source for a gamma-ray burst. To study these effects, simulations in general relativity with a hot microphysical equation of state (EOS) and neutrino feedback are needed. We present the first such simulation, using a neutrino leakage scheme for cooling to capture the most essential effects and considering a moderate mass (1.4 M{sub ☉} neutron star, 5.6 M{sub ☉} black hole), high-spin (black hole J/M {sup 2} = 0.9) system with the K{sub 0} = 220 MeV Lattimer-Swesty EOS. We find that about 0.08 M{sub ☉} of nuclear matter is ejected from the system, while another 0.3 M{sub ☉} forms a hot, compact accretion disk. The primary effects of the escaping neutrinos are (1) to make the disk much denser and more compact, (2) to cause the average electron fraction Y{sub e} of the disk to rise to about 0.2 and then gradually decrease again, and (3) to gradually cool the disk. The disk is initially hot (T ∼ 6 MeV) and luminous in neutrinos (L{sub ν} ∼ 10{sup 54} erg s{sup –1}), but the neutrino luminosity decreases by an order of magnitude over 50 ms of post-merger evolution.
Papaemmanouil, Christina; Tsiafoulis, Constantinos G; Alivertis, Dimitrios; Tzamaloukas, Ouranios; Miltiadou, Despoina; Tzakos, Andreas G; Gerothanassis, Ioannis P
2015-06-10
We report a rapid, direct, and unequivocal spin-chromatographic separation and identification of minor components in the lipid fraction of milk and common dairy products with the use of selective one-dimensional (1D) total correlation spectroscopy (TOCSY) nuclear magnetic resonance (NMR) experiments. The method allows for the complete backbone spin-coupling network to be elucidated even in strongly overlapped regions and in the presence of major components from 4 × 10(2) to 3 × 10(3) stronger NMR signal intensities. The proposed spin-chromatography method does not require any derivatization steps for the lipid fraction, is selective with excellent resolution, is sensitive with quantitation capability, and compares favorably to two-dimensional (2D) TOCSY and gas chromatography-mass spectrometry (GC-MS) methods of analysis. The results of the present study demonstrated that the 1D TOCSY NMR spin-chromatography method can become a procedure of primary interest in food analysis and generally in complex mixture analysis.
Energy Technology Data Exchange (ETDEWEB)
Meyer, Benjamin Michael [Iowa State Univ., Ames, IA (United States)
2003-01-01
As time progresses, the world is using up more of the planet's natural resources. Without technological advances, the day will eventually arrive when these natural resources will no longer be sufficient to supply all of the energy needs. As a result, society is seeing a push for the development of alternative fuel sources such as wind power, solar power, fuel cells, and etc. These pursuits are even occurring in the state of Iowa with increasing social pressure to incorporate larger percentages of ethanol in gasoline. Consumers are increasingly demanding that energy sources be more powerful, more durable, and, ultimately, more cost efficient. Fast Ionic Conducting (FIC) glasses are a material that offers great potential for the development of new batteries and/or fuel cells to help inspire the energy density of battery power supplies. This dissertation probes the mechanisms by which ions conduct in these glasses. A variety of different experimental techniques give a better understanding of the interesting materials science taking place within these systems. This dissertation discusses Nuclear Magnetic Resonance (NMR) techniques performed on FIC glasses over the past few years. These NMR results have been complimented with other measurement techniques, primarily impedance spectroscopy, to develop models that describe the mechanisms by which ionic conduction takes place and the dependence of the ion dynamics on the local structure of the glass. The aim of these measurements was to probe the cause of a non-Arrhenius behavior of the conductivity which has been seen at high temperatures in the silver thio-borosilicate glasses. One aspect that will be addressed is if this behavior is unique to silver containing fast ion conducting glasses. more specifically, this study will determine if a non-Arrhenius correlation time, τ, can be observed in the Nuclear Spin Lattice Relaxation (NSLR) measurements. If so, then can this behavior be modeled with a new single
Directory of Open Access Journals (Sweden)
Angel Esteban
2003-02-01
Full Text Available Abstract: The known solvent dependence of 1J(Cc,Hf and 2J(C1,Hf couplings in acetaldehyde is studied from a theoretical viewpoint based on the density functional theory approach where the dielectric solvent effect is taken into account with the polarizable continuum model. The four terms of scalar couplings, Fermi contact, paramagnetic spin orbital, diamagnetic spin orbital and spin dipolar, are calculated but the solvent effect analysis is restricted to the first term since for both couplings it is by far the dominant contribution. Experimental trends of ÃŽÂ”1J(Cc,Hf and ÃŽÂ”2J(C1,Hf Vs ÃŽÂµ (the solvent dielectric constant are correctly reproduced although they are somewhat underestimated. Specific interactions between solute and solvent molecules are studied for dimethylsulfoxide, DMSO, solutions considering two different one-to-one molecular complexes between acetaldehyde and DMSO. They are determined by interactions of type C=O---H---C and S=O---H---C, and the effects of such interactions on 1J(Cc,Hf and 2J(C1,Hf couplings are analyzed. Even though only in a semiquantitative way, it is shown that the effect of such interactions on the solvent effects, of ÃŽÂ”1J(Cc,Hf and ÃŽÂ”2J(C1,Hf, tend to improve the agreement between calculated and experimental values. These results seem to indicate that a continuum dielectric model has not enough flexibility for describing quantitatively solvent effects on spin-spin couplings. Apparently, even for relatively weak hydrogen bonding, the contribution from Ã¢Â€ÂœdirectÃ¢Â€Â interactions is of the same order of magnitude as the Ã¢Â€ÂœdielectricÃ¢Â€Â effect.
International Nuclear Information System (INIS)
Gaarde, C.
1985-01-01
An analysis of spectra of (p,n) reactions showed that they were very selective in exciting spin modes. Charge exchange reactions at intermediate energies give important new understanding of the M1-type of excitations and of the spin structure of continuum p spectra in general. In this paper, the author discusses three charge exchange reactions: (p,n); ( 3 H,t); and (d,2p) at several targets. Low-lying states and the Δ region are discussed separately. Finally, the charge exchange reaction with heavy ion beams is briefly discussed. (G.J.P./Auth.)
Energy Technology Data Exchange (ETDEWEB)
Lim, Ae Ran [Department of Science Education, Jeonju University, Jeonju 560-759, Chonbuk (Korea, Republic of)], E-mail: aeranlim@hanmail.net; Shin, Chang Woo [Solid State Analysis Team, Korea Basic Science Institute, Daegu 702-701 (Korea, Republic of)
2008-11-30
Successive phase transitions in a Na{sub 3}H(SO{sub 4}){sub 2} single crystal were found at 296, 513, and 533 K. To investigate the mechanism of the phase transition at 296 K, the {sup 1}H and {sup 23}Na spin-lattice relaxation time and the spin-spin relaxation time of Na{sub 3}H(SO{sub 4}){sub 2} were measured near the phase transition temperature using a FT NMR spectrometer. The spin-lattice relaxation time, T{sub 1}, for {sup 1}H in Na{sub 3}H(SO{sub 4}){sub 2} crystals exhibits a minimum below T{sub C1} (=296 K) indicating the presence of distinct molecular motion governed by the Bloembergen-Purcell-Pound (BPP) theory. Although the results for the {sup 1}H and {sup 23}Na relaxation times provide no evidence of the phase transition at T{sub C1}, the separation of the {sup 23}Na resonance lines changes abruptly at T{sub C1}. The phase transition at 296 K produces a change in the separation of the Na resonance line that is associated with a change in the atomic positions in the vicinity of the Na ions. Also, the nuclear spin-lattice relaxation process in Na{sub 3}H(SO{sub 4}){sub 2} crystals with the electric-quadrupole-type interaction proceed via Raman process. These results are compared with those obtained for other M{sub 3}H(SO{sub 4}){sub 2} (M=K, Rb, and Cs) crystals, which have similar hydrogen-bonded structures.
T violating neutron spin rotation asymmetry
International Nuclear Information System (INIS)
Masuda, Yasushiro.
1993-01-01
A new experiment on T-violation is proposed, where a spin-rotating-neutron transmission through a polarized nuclear target is measuered. The method to control the neutron spin is discussed for the new T-violation experiment. The present method has possibility to provide us more accurate T-violation information than the neutron EDM measurement
High spin isomer beam line at RIKEN
Energy Technology Data Exchange (ETDEWEB)
Kishida, T.; Ideguchi, E.; Wu, H.Y. [Institute of Physical and Chemical Research, Saitama (Japan)] [and others
1996-12-31
Nuclear high spin states have been the subject of extensive experimental and theoretical studies. For the production of high spin states, fusion reactions are usually used. The orbital angular momentum brought in the reaction is changed into the nuclear spin of the compound nucleus. However, the maximum induced angular momentum is limited in this mechanism by the maximum impact parameter of the fusion reaction and by the competition with fission reactions. It is, therefore, difficult to populate very high spin states, and as a result, large {gamma}-detector arrays have been developed in order to detect subtle signals from such very high spin states. The use of high spin isomers in the fusion reactions can break this limitation because the high spin isomers have their intrinsic angular momentum, which can bring the additional angular momentum without increasing the excitation energy. There are two methods to use the high spin isomers for secondary reactions: the use of the high spin isomers as a target and that as a beam. A high spin isomer target has already been developed and used for several experiments. But this method has an inevitable shortcoming that only {open_quotes}long-lived{close_quotes} isomers can be used for a target: {sup 178}Hf{sup m2} (16{sup +}) with a half-life of 31 years in the present case. By developing a high spin isomer beam, the authors can utilize various short-lived isomers with a short half-life around 1 {mu}s. The high spin isomer beam line of RIKEN Accelerator Facility is a unique apparatus in the world which provides a high spin isomer as a secondary beam. The combination of fusion-evaporation reaction and inverse kinematics are used to produce high spin isomer beams; in particular, the adoption of `inverse kinematics` is essential to use short-lived isomers as a beam.
International Nuclear Information System (INIS)
Sotty, C.
2013-01-01
The underlying structure in the region A ∼ 100, N ∼ 60 has been under intensive and extensive investigation, mainly by β-decay and γ-ray spectroscopy from fission processes. Around N ∼ 60, by adding just few neutrons, protons a rapid shape change occurs from spherical-like to well deformed g.s. shape. Shape coexistence has been observed in the Sr and Zr nuclei, and is expected to take place in the whole region. The mechanisms involved in the appearance of the deformation is not well understood. The interplay between down-sloping and up-sloping neutron Nilsson orbital is evoked as one of the main reasons for the sudden shape change. However, a clear identification of the active proton and neutron orbitals was still on-going. For that purpose, the neutron rich 93;95;97;99 Rb isotopes have been studied by Coulomb excitation at CERN (ISOLDE) using the REX-ISOLDE post-accelerator and the MINIBALL setup. The completely unknown structures of 97;99 Rb have been populated and observed. Prompt γ-ray coincidences of low-lying states have been observed and time-correlated in order to build level schemes. The associated transition strengths have been extracted with the GOSIA code. The observed matrix elements of the electromagnetic operator constituted new inputs of further theoretical calculations giving new insight on the involved orbitals. The sensitivity of such experiment can be increased using nuclear spin polarized radioactive ion beam. For that purpose the Tilted Foils Technique (TFT) of polarization has been investigated at CERN. This technique consists to spin polarize the ion beam, passing through thin foils tilted at an oblique angle with respect to the beam direction. The initially obtained atomic polarization is transferred to the nucleus by hyperfine interaction. This technique does not depend on the chemical nature of the element. Short lived nuclei can be polarized in-flight without any need to be stopped in a catcher. It opens up the possibility to
International Nuclear Information System (INIS)
Lai, A.; Monduzzi, M.; Saba, G.
1980-01-01
Spin-lattice relaxation rates (R 1 ) from naturally occuring C-13 F.T. N.M.R. spectra of some catecholamines and parent compounds with Iron(III) at pD = 4 were determined in order to elucidate the molecular mechanism underlying their association in aqueous solutions. Complexation was observed only for catecholic ligands. The R 1 values were used to calculate iron-carbon scaled distances, and two complexation models were proposed where the catecholic function binds Fe(III) in the first and second coordination spheres respectively. The latter case was shown to be the consistent with the molecular geometries. (orig.)
Spin resonance with trapped ions
Energy Technology Data Exchange (ETDEWEB)
Wunderlich, Ch; Balzer, Ch; Hannemann, T; Mintert, F; Neuhauser, W; Reiss, D; Toschek, P E [Institut fuer Laser-Physik, Universitaet Hamburg, Jungiusstrasse 9, 20355 Hamburg (Germany)
2003-03-14
A modified ion trap is described where experiments (in particular related to quantum information processing) that usually require optical radiation can be carried out using microwave or radio frequency electromagnetic fields. Instead of applying the usual methods for coherent manipulation of trapped ions, a string of ions in such a modified trap can be treated like a molecule in nuclear magnetic resonance experiments taking advantage of spin-spin coupling. The collection of trapped ions can be viewed as an N-qubit molecule with adjustable spin-spin coupling constants. Given N identically prepared quantum mechanical two-level systems (qubits), the optimal strategy to estimate their quantum state requires collective measurements. Using the ground state hyperfine levels of electrodynamically trapped {sup 171}Yb{sup +}, we have implemented an adaptive algorithm for state estimation involving sequential measurements on arbitrary qubit states.
Spin resonance with trapped ions
International Nuclear Information System (INIS)
Wunderlich, Ch; Balzer, Ch; Hannemann, T; Mintert, F; Neuhauser, W; Reiss, D; Toschek, P E
2003-01-01
A modified ion trap is described where experiments (in particular related to quantum information processing) that usually require optical radiation can be carried out using microwave or radio frequency electromagnetic fields. Instead of applying the usual methods for coherent manipulation of trapped ions, a string of ions in such a modified trap can be treated like a molecule in nuclear magnetic resonance experiments taking advantage of spin-spin coupling. The collection of trapped ions can be viewed as an N-qubit molecule with adjustable spin-spin coupling constants. Given N identically prepared quantum mechanical two-level systems (qubits), the optimal strategy to estimate their quantum state requires collective measurements. Using the ground state hyperfine levels of electrodynamically trapped 171 Yb + , we have implemented an adaptive algorithm for state estimation involving sequential measurements on arbitrary qubit states
Relativistic fluid dynamics with spin
Florkowski, Wojciech; Friman, Bengt; Jaiswal, Amaresh; Speranza, Enrico
2018-04-01
Using the conservation laws for charge, energy, momentum, and angular momentum, we derive hydrodynamic equations for the charge density, local temperature, and fluid velocity, as well as for the polarization tensor, starting from local equilibrium distribution functions for particles and antiparticles with spin 1/2. The resulting set of differential equations extends the standard picture of perfect-fluid hydrodynamics with a conserved entropy current in a minimal way. This framework can be used in space-time analyses of the evolution of spin and polarization in various physical systems including high-energy nuclear collisions. We demonstrate that a stationary vortex, which exhibits vorticity-spin alignment, corresponds to a special solution of the spin-hydrodynamical equations.
Schwarz, H.
2017-01-01
The thesis "Spinning Worlds" is about the characterisation of two types of gas-giant exoplanets: Hot Jupiters, with orbital periods of fewer than five days, and young, wide-orbit gas giants, with orbital periods as long as thousands of years. The thesis is based on near-infrared observations of 1
Adiabatic quantum computing with spin qubits hosted by molecules.
Yamamoto, Satoru; Nakazawa, Shigeaki; Sugisaki, Kenji; Sato, Kazunobu; Toyota, Kazuo; Shiomi, Daisuke; Takui, Takeji
2015-01-28
A molecular spin quantum computer (MSQC) requires electron spin qubits, which pulse-based electron spin/magnetic resonance (ESR/MR) techniques can afford to manipulate for implementing quantum gate operations in open shell molecular entities. Importantly, nuclear spins, which are topologically connected, particularly in organic molecular spin systems, are client qubits, while electron spins play a role of bus qubits. Here, we introduce the implementation for an adiabatic quantum algorithm, suggesting the possible utilization of molecular spins with optimized spin structures for MSQCs. We exemplify the utilization of an adiabatic factorization problem of 21, compared with the corresponding nuclear magnetic resonance (NMR) case. Two molecular spins are selected: one is a molecular spin composed of three exchange-coupled electrons as electron-only qubits and the other an electron-bus qubit with two client nuclear spin qubits. Their electronic spin structures are well characterized in terms of the quantum mechanical behaviour in the spin Hamiltonian. The implementation of adiabatic quantum computing/computation (AQC) has, for the first time, been achieved by establishing ESR/MR pulse sequences for effective spin Hamiltonians in a fully controlled manner of spin manipulation. The conquered pulse sequences have been compared with the NMR experiments and shown much faster CPU times corresponding to the interaction strength between the spins. Significant differences are shown in rotational operations and pulse intervals for ESR/MR operations. As a result, we suggest the advantages and possible utilization of the time-evolution based AQC approach for molecular spin quantum computers and molecular spin quantum simulators underlain by sophisticated ESR/MR pulsed spin technology.
Hanana, H.; Simon, G.; Kervarec, N.; Cérantola, S.
2014-01-01
Tributyltin (TBT) is a highly toxic pollutant present in many aquatic ecosystems. Its toxicity in mollusks strongly affects their performance and survival. The main purpose of this study was to elucidate the mechanisms of TBT toxicity in clam Ruditapes decussatus by evaluating the metabolic responses of heart tissues, using high-resolution magic angle-spinning nuclear magnetic resonance (HRMAS NMR), after exposure to TBT (10−9, 10−6 and 10−4 M) during 24 h and 72 h. Results show that response...
High spin studies with radioactive ion beams
International Nuclear Information System (INIS)
Garrett, J.D.
1992-01-01
The variety of new research possibilities afforded by the culmination of the two frontier areas of nuclear structure: high spin and studies far from nuclear stability (utilizing intense radioactive ion beams) are discussed. Topics presented include: new regions of exotic nuclear shape (e.g. superdeformation, hyperdeformation, and reflection-asymmetric shapes); the population of and consequences of populating exotic nuclear configurations; and complete spectroscopy (i.e. the overlap of state of the art low-and high-spin studies in the same nucleus)
High spin studies with radioactive ion beams
Energy Technology Data Exchange (ETDEWEB)
Garrett, J D [Oak Ridge National Lab., TN (United States)
1992-08-01
The variety of new research possibilities afforded by the culmination of the two frontier areas of nuclear structure: high spin and studies far from nuclear stability (utilizing intense radioactive ion beams) are discussed. Topics presented include: new regions of exotic nuclear shape (e.g. superdeformation, hyperdeformation, and reflection-asymmetric shapes); the population of and consequences of populating exotic nuclear configurations; and, complete spectroscopy (i.e. the overlap of state of the art low- and high-spin studies in the same nucleus). (author). 47 refs., 8 figs.
Influence of spin on fission fragments anisotropy
Directory of Open Access Journals (Sweden)
Ghodsi Omid N.
2005-01-01
Full Text Available An analysis of selected fission fragment angular distribution when at least one of the spins of the projectile or target is appreciable in induced fission was made by using the statistical scission model. The results of this model predicate that the spins of the projectile or target are affected on the nuclear level density of the compound nucleus. The experimental data was analyzed by means of the couple channel spin effect formalism. This formalism suggests that the projectile spin is more effective on angular anisotropies within the limits of energy near the fusion barrier.
Cuc, Diana; Bouguet-Bonnet, Sabine; Morel-Desrosiers, Nicole; Morel, Jean-Pierre; Mutzenhardt, Pierre; Canet, Daniel
2009-08-06
We have studied the complexes formed between the p-sulfonatocalix[4]arene and cesium or thallium metal cation, first by carbon-13 longitudinal relaxation of the calixarene molecule at two values of the magnetic field B(0). From the longitudinal relaxation times of an aromatic carbon directly bonded to a proton, thus subjected essentially to the dipolar interaction with that proton, we could obtain the correlation time describing the reorientation of the CH bond. The rest of this study has demonstrated that it is also the correlation time describing the tumbling of the whole calixarene assembly. From three non-proton-bearing carbons of the aromatic cycles (thus subjected to the chemical shift anisotropy and dipolar mechanisms), we have been able to determine the variation of the chemical shift anisotropy when going from the free to the complex form of the calixarene. These variations not only provide the location of the cation inside the calixarene cavity but also constitute a direct experimental proof of the cation-pi interactions. These results are complemented by cesium and thallium relaxation measurements performed again at two values of the magnetic field B(0). An estimation of the mean distance between the cation and the calixarene protons could be obtained. These measurements have also revealed an important chemical shift anisotropy of thallium upon complexation.
Aidala, C.; Akiba, Y.; Alfred, M.; Andrieux, V.; Aoki, K.; Apadula, N.; Asano, H.; Ayuso, C.; Azmoun, B.; Babintsev, V.; Bagoly, A.; Bandara, N. S.; Barish, K. N.; Bathe, S.; Bazilevsky, A.; Beaumier, M.; Belmont, R.; Berdnikov, A.; Berdnikov, Y.; Blau, D. S.; Boer, M.; Bok, J. S.; Brooks, M. L.; Bryslawskyj, J.; Bumazhnov, V.; Butler, C.; Campbell, S.; Canoa Roman, V.; Cervantes, R.; Chi, C. Y.; Chiu, M.; Choi, I. J.; Choi, J. B.; Citron, Z.; Connors, M.; Cronin, N.; Csanád, M.; Csörgő, T.; Danley, T. W.; Daugherity, M. S.; David, G.; Deblasio, K.; Dehmelt, K.; Denisov, A.; Deshpande, A.; Desmond, E. J.; Dion, A.; Dixit, D.; Do, J. H.; Drees, A.; Drees, K. A.; Dumancic, M.; Durham, J. M.; Durum, A.; Elder, T.; Enokizono, A.; En'yo, H.; Esumi, S.; Fadem, B.; Fan, W.; Feege, N.; Fields, D. E.; Finger, M.; Finger, M.; Fokin, S. L.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fukuda, Y.; Gal, C.; Gallus, P.; Garg, P.; Ge, H.; Giordano, F.; Goto, Y.; Grau, N.; Greene, S. V.; Grosse Perdekamp, M.; Gunji, T.; Guragain, H.; Hachiya, T.; Haggerty, J. S.; Hahn, K. I.; Hamagaki, H.; Hamilton, H. F.; Han, S. Y.; Hanks, J.; Hasegawa, S.; Haseler, T. O. S.; He, X.; Hemmick, T. K.; Hill, J. C.; Hill, K.; Hollis, R. S.; Homma, K.; Hong, B.; Hoshino, T.; Hotvedt, N.; Huang, J.; Huang, S.; Imai, K.; Imrek, J.; Inaba, M.; Iordanova, A.; Isenhower, D.; Ito, Y.; Ivanishchev, D.; Jacak, B. V.; Jezghani, M.; Ji, Z.; Jiang, X.; Johnson, B. M.; Jorjadze, V.; Jouan, D.; Jumper, D. S.; Kang, J. H.; Kapukchyan, D.; Karthas, S.; Kawall, D.; Kazantsev, A. V.; Khachatryan, V.; Khanzadeev, A.; Kim, C.; Kim, D. J.; Kim, E.-J.; Kim, M.; Kim, M. H.; Kincses, D.; Kistenev, E.; Klatsky, J.; Kline, P.; Koblesky, T.; Kotov, D.; Kudo, S.; Kurita, K.; Kwon, Y.; Lajoie, J. G.; Lallow, E. O.; Lebedev, A.; Lee, S.; Leitch, M. J.; Leung, Y. H.; Lewis, N. A.; Li, X.; Lim, S. H.; Liu, L. D.; Liu, M. X.; Loggins, V.-R.; Lökös, S.; Lovasz, K.; Lynch, D.; Majoros, T.; Makdisi, Y. I.; Makek, M.; Malaev, M.; Manko, V. I.; Mannel, E.; Masuda, H.; McCumber, M.; McGaughey, P. L.; McGlinchey, D.; McKinney, C.; Mendoza, M.; Metzger, W. J.; Mignerey, A. C.; Mihalik, D. E.; Milov, A.; Mishra, D. K.; Mitchell, J. T.; Mitsuka, G.; Miyasaka, S.; Mizuno, S.; Montuenga, P.; Moon, T.; Morrison, D. P.; Morrow, S. I. M.; Murakami, T.; Murata, J.; Nagai, K.; Nagashima, K.; Nagashima, T.; Nagle, J. L.; Nagy, M. I.; Nakagawa, I.; Nakagomi, H.; Nakano, K.; Nattrass, C.; Niida, T.; Nouicer, R.; Novák, T.; Novitzky, N.; Novotny, R.; Nyanin, A. S.; O'Brien, E.; Ogilvie, C. A.; Orjuela Koop, J. D.; Osborn, J. D.; Oskarsson, A.; Ottino, G. J.; Ozawa, K.; Pantuev, V.; Papavassiliou, V.; Park, J. S.; Park, S.; Pate, S. F.; Patel, M.; Peng, W.; Perepelitsa, D. V.; Perera, G. D. N.; Peressounko, D. Yu.; Perezlara, C. E.; Perry, J.; Petti, R.; Phipps, M.; Pinkenburg, C.; Pisani, R. P.; Pun, A.; Purschke, M. L.; Radzevich, P. V.; Read, K. F.; Reynolds, D.; Riabov, V.; Riabov, Y.; Richford, D.; Rinn, T.; Rolnick, S. D.; Rosati, M.; Rowan, Z.; Runchey, J.; Safonov, A. S.; Sakaguchi, T.; Sako, H.; Samsonov, V.; Sarsour, M.; Sato, K.; Sato, S.; Schaefer, B.; Schmoll, B. K.; Sedgwick, K.; Seidl, R.; Sen, A.; Seto, R.; Sexton, A.; Sharma, D.; Shein, I.; Shibata, T.-A.; Shigaki, K.; Shimomura, M.; Shioya, T.; Shukla, P.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Singh, B. K.; Singh, C. P.; Singh, V.; Skoby, M. J.; Slunečka, M.; Smith, K. L.; Snowball, M.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Sourikova, I. V.; Stankus, P. W.; Stoll, S. P.; Sugitate, T.; Sukhanov, A.; Sumita, T.; Sun, J.; Syed, S.; Sziklai, J.; Takeda, A.; Tanida, K.; Tannenbaum, M. J.; Tarafdar, S.; Taranenko, A.; Tarnai, G.; Tieulent, R.; Timilsina, A.; Todoroki, T.; Tomášek, M.; Towell, C. L.; Towell, R. S.; Tserruya, I.; Ueda, Y.; Ujvari, B.; van Hecke, H. W.; Vazquez-Carson, S.; Velkovska, J.; Virius, M.; Vrba, V.; Vukman, N.; Wang, X. R.; Wang, Z.; Watanabe, Y.; Watanabe, Y. S.; Wong, C. P.; Woody, C. L.; Xu, C.; Xu, Q.; Xue, L.; Yalcin, S.; Yamaguchi, Y. L.; Yamamoto, H.; Yanovich, A.; Yin, P.; Yoo, J. H.; Yoon, I.; Yu, H.; Yushmanov, I. E.; Zajc, W. A.; Zelenski, A.; Zharko, S.; Zou, L.; Phenix Collaboration
2018-01-01
During 2015, the Relativistic Heavy Ion Collider (RHIC) provided collisions of transversely polarized protons with Au and Al nuclei for the first time, enabling the exploration of transverse-single-spin asymmetries with heavy nuclei. Large single-spin asymmetries in very forward neutron production have been previously observed in transversely polarized p +p collisions at RHIC, and the existing theoretical framework that was successful in describing the single-spin asymmetry in p +p collisions predicts only a moderate atomic-mass-number (A ) dependence. In contrast, the asymmetries observed at RHIC in p +A collisions showed a surprisingly strong A dependence in inclusive forward neutron production. The observed asymmetry in p +Al collisions is much smaller, while the asymmetry in p +Au collisions is a factor of 3 larger in absolute value and of opposite sign. The interplay of different neutron production mechanisms is discussed as a possible explanation of the observed A dependence.
Energy Technology Data Exchange (ETDEWEB)
Bowman, M K; Kevan, L [Wayne State Univ., Detroit, Mich. (USA). Dept. of Chemistry
1977-01-01
The spin lattice relaxation of trapped electrons in aqueous and organic glasses and trapped hydrogen atoms in phosphoric acid glass has been directly studied as a function of temperature by the saturation recovery method. Below 50 to 100 K, the major spin lattice relaxation mechanism involves modulation of the electron nuclear dipolar (END) interaction with nuclei in the radical's environment by tunnelling of those nuclei between two or more positions. This relaxation mechanism occurs with high efficiency and has a characteristic linear temperature dependence. The tunnelling nuclei around trapped electrons do not seem to involve the nearest neighbor nuclei which are oriented by the electron in the process of solvation. Instead the tunnelling nuclei typically appear to be next nearest neighbors to the trapped electron. The identities of the tunnelling nuclei have been deduced by isotopic substitution and are attributed to: Na in 10 mol dm/sup -3/ NaOH aqueous glass, ethyl protons in ethanol glass, methyl protons in methanol glass and methyl protons in MTHF glass. For trapped hydrogen atoms in phosphoric acid, the phosphorus nuclei appear to be the effective tunnelling nuclei. Below approximately 10 K the spin lattice relaxation is dominated by a temperature independent cross relaxation term for H atoms in phosphoric acid glass and for electrons in 10 mol dm/sup -3/ NaOH aqueous glass, but not for electrons in organic glasses. This is compared with recent electron-electron double resonance studies of cross relaxation in these glasses. The spin lattice relaxation of O/sup -/ formed in 10 mol dm/sup -3/ NaOH aqueous glass was also studied and found to be mainly dominated by a Raman process with an effective Debye temperature of about 100 K.
Energy Technology Data Exchange (ETDEWEB)
Solomon, I. [Commissariat a l' energie atomique et aux energies alternatives - CEA, Centre d' Etudes Nucleaires de Saclay, BP2, Gif-sur-Yvette (France)
1959-07-01
Torrey has observed the free precession of nuclear spins around an r-f field H{sub 1}, fixed in a frame rotating at the Larmor frequency ω{sub 0} = γH{sub 0} around a large d-c magnetic field H{sub 0}. He showed that for an H{sub 1}, much larger than inhomogeneity of H{sub 0}, the latter has a negligible effect on the decay of the spin magnetization which is mainly due to the inhomogeneity of H{sub 1}. We report here on a method of overcoming the inhomogeneity of H{sub 1}, by production of echoes in the rotating frame ('rotary echoes'). These echoes are obtained by a 180 deg. phase shift at t = τ on the r-f field so that H{sub 1}, is suddenly reversed, producing a re-focussing of the magnetization vectors at the time t = 2 τ. The rotary echoes so obtained are very similar to the usual spin-echoes with, however some specific features that make them particularly suitable for the measurement of long relaxation times. Reprint of a paper published in Physical Review Letters, vol. 2, no. 7, Apr 1959, p. 301-302.
International Nuclear Information System (INIS)
Solomon, I.
1959-01-01
Torrey has observed the free precession of nuclear spins around an r-f field H 1 , fixed in a frame rotating at the Larmor frequency ω 0 = γH 0 around a large d-c magnetic field H 0 . He showed that for an H 1 , much larger than inhomogeneity of H 0 , the latter has a negligible effect on the decay of the spin magnetization which is mainly due to the inhomogeneity of H 1 . We report here on a method of overcoming the inhomogeneity of H 1 , by production of echoes in the rotating frame ('rotary echoes'). These echoes are obtained by a 180 deg. phase shift at t = τ on the r-f field so that H 1 , is suddenly reversed, producing a re-focussing of the magnetization vectors at the time t = 2 τ. The rotary echoes so obtained are very similar to the usual spin-echoes with, however some specific features that make them particularly suitable for the measurement of long relaxation times. Reprint of a paper published in Physical Review Letters, vol. 2, no. 7, Apr 1959, p. 301-302
Scalable Spin-Qubit Circuits with Quantum Dots
2006-12-31
Anisotropic Heisenberg Spin Rings” cond-mat/0608642. 13. Karyn Le Hur (Yale), Pascal Simon, and Daniel Loss, “Transport through a quantum dot with SU(4...Daniel Loss, “Nuclear spin state narrowing via gate--controlled Rabi oscillations in a double quantum dot” Phys. Rev. B 73, 205302 (2006). 27. Jörg...single spin read out (Delft), sqrt-of-swap (Harvard) and single spin Rabi oscillations. At the end of this program and based on our theoretical
DEFF Research Database (Denmark)
Faber, Rasmus; Sauer, Stephan P. A.
2015-01-01
We present zero-point vibrational corrections to the indirect nuclear spin-spin coupling constants in ethyne, ethene, cyclopropene and allene. The calculations have been carried out both at the level of the second order polarization propagator approximation (SOPPA) employing a new implementation ...
Double-spin-flip resonance of rhodium nuclei at positive and negative spin temperatures
DEFF Research Database (Denmark)
Tuoriniemi, J.T.; Knuuttila, T.A.; Lefmann, K.
2000-01-01
Sensitive SQUID-NMR measurements were used to study the mutual interactions in the highly polarized nuclear-spin system of rhodium metal. The dipolar coupling gives rise to a weak double-spin-flip resonance. The observed frequency shifts allow deducing separately the dipolarlike contribution...
International Nuclear Information System (INIS)
2014-01-01
This document proposes a presentation and discussion of the main notions, issues, principles, or characteristics related to nuclear energy: radioactivity (presence in the environment, explanation, measurement, periods and activities, low doses, applications), fuel cycle (front end, mining and ore concentration, refining and conversion, fuel fabrication, in the reactor, back end with reprocessing and recycling, transport), the future of the thorium-based fuel cycle (motivations, benefits and drawbacks), nuclear reactors (principles of fission reactors, reactor types, PWR reactors, BWR, heavy-water reactor, high temperature reactor of HTR, future reactors), nuclear wastes (classification, packaging and storage, legal aspects, vitrification, choice of a deep storage option, quantities and costs, foreign practices), radioactive releases of nuclear installations (main released radio-elements, radioactive releases by nuclear reactors and by La Hague plant, gaseous and liquid effluents, impact of releases, regulation), the OSPAR Convention, management and safety of nuclear activities (from control to quality insurance, to quality management and to sustainable development), national safety bodies (mission, means, organisation and activities of ASN, IRSN, HCTISN), international bodies, nuclear and medicine (applications of radioactivity, medical imagery, radiotherapy, doses in nuclear medicine, implementation, the accident in Epinal), nuclear and R and D (past R and D programmes and expenses, main actors in France and present funding, main R and D axis, international cooperation)
International Nuclear Information System (INIS)
Jouvensal, L.
1997-01-01
The metabolism of skeleton muscles gave rise to numerous research works since the beginning of the century in order to make some reply about the muscle physiology with the will to improve the sport performances or the understanding of muscles diseases. This metabolism is complex and the lactate has an importance place; the purpose of this work is to answer these questions with some strategy studies by nuclear magnetic resonance spectroscopy. (N.C.)
16th Workshop on High Energy Spin Physics
2016-01-01
The Workshop will cover a wide range of spin phenomena at high and intermediate energies such as: recent experimental data on spin physics the nucleon spin structure and GPD's spin physics and QCD spin physics in the Standard Model and beyond T-odd spin effects polarization and heavy ion physics spin in gravity and astrophysics the future spin physics facilities spin physics at NICA polarimeters for high energy polarized beams acceleration and storage of polarized beams the new polarization technology related subjects The Workshop will be held in the Bogoliubov Laboratory of Theoretical Physics of the Joint Institute for Nuclear Research, 141980 Dubna, Moscow Region, Russia. The program of the workshop will include plenary and parallel (if necessary) sessions. Plenary sessions will be held in the Conference Hall. Parallel sections will take place in the same building. There will be invited talks (up to 40 min) and original reports (20 min). The invited speakers will present new experimental and theoretical re...
Spin noise spectroscopy of donor-bound electrons in ZnO
Horn, H.; Balocchi, A.; Marie, X.; Bakin, A.; Waag, A.; Oestreich, M.; Hübner, J.
2013-01-01
We investigate the intrinsic spin dynamics of electrons bound to Al impurities in bulk ZnO by optical spin noise spectroscopy. Spin noise spectroscopy enables us to investigate the longitudinal and transverse spin relaxation time with respect to nuclear and external magnetic fields in a single spectrum. On one hand, the spin dynamic is dominated by the intrinsic hyperfine interaction with the nuclear spins of the naturally occurring 67Zn isotope. We measure a typical spin dephasing time of 23 ns, in agreement with the expected theoretical values. On the other hand, we measure a third, very high spin dephasing rate which is attributed to a high defect density of the investigated ZnO material. Measurements of the spin dynamics under the influence of transverse as well as longitudinal external magnetic fields unambiguously reveal the intriguing connections of the electron spin with its nuclear and structural environment.
International Nuclear Information System (INIS)
Mookerjee, Abhijit
1976-01-01
''Spin glasses'', are entire class of magnetic alloys of moderate dilution, in which the magnetic atoms are far enough apart to be unlike the pure metal, but close enough so that the indirect exchange energy between them (mediated by the s-d interaction between local moments and conduction electrons) dominates all other energies. Characteristic critical phenomena displayed such as freezing of spin orientation at 'Tsub(c)' and spreading of magnetic ordering, are pointed out. Anomalous behaviour, associated with these critical phenomena, as reflected in : (i) Moessbauer spectroscopy giving hyperfine splitting at Tsub(c), (ii) maxima in susceptibility and remanent magnetism, (iii) thermopower maxima and change in slope, (iv) Characteristic cusp in susceptibility and its removal by very small magnetic fields, and (v) conductivity-resistivity measurements, are discussed. Theoretical developments aimed at explaining these phenomena, in particular, the ideas from percolation and localisation theories, and the approach based on the gellations of polymers, are discussed. Finally, a new approach based on renormalisation group in disordered systems is also briefly mentioned. (K.B.)
International Nuclear Information System (INIS)
Ohnuma, Yuichi; Matsuo, Mamoru; Maekawa, Sadamichi; Saitoh, Eeiji
2017-01-01
Spin Seebeck and spin Peltier effects, which are mutual conversion phenomena of heat and spin, are discussed on the basis of the microscopic theory. First, the spin Seebeck effect, which is the spin-current generation due to heat current, is discussed. The recent progress in research on the spin Seebeck effect are introduced. We explain the origin of the observed sign changes of the spin Seebeck effect in compensated ferromagnets. Next, the spin Peltier effect, which is the heat-current generation due to spin current, is discussed. Finally, we show that the spin Seebeck and spin Peltier effects are summarized by Onsager's reciprocal relation and derive Kelvin's relation for the spin and heat transports. (author)
Entangled spins and ghost-spins
Directory of Open Access Journals (Sweden)
Dileep P. Jatkar
2017-09-01
Full Text Available We study patterns of quantum entanglement in systems of spins and ghost-spins regarding them as simple quantum mechanical toy models for theories containing negative norm states. We define a single ghost-spin as in [20] as a 2-state spin variable with an indefinite inner product in the state space. We find that whenever the spin sector is disentangled from the ghost-spin sector (both of which could be entangled within themselves, the reduced density matrix obtained by tracing over all the ghost-spins gives rise to positive entanglement entropy for positive norm states, while negative norm states have an entanglement entropy with a negative real part and a constant imaginary part. However when the spins are entangled with the ghost-spins, there are new entanglement patterns in general. For systems where the number of ghost-spins is even, it is possible to find subsectors of the Hilbert space where positive norm states always lead to positive entanglement entropy after tracing over the ghost-spins. With an odd number of ghost-spins however, we find that there always exist positive norm states with negative real part for entanglement entropy after tracing over the ghost-spins.
Anisotropic interactions of a single spin and dark-spin spectroscopy in diamond
Epstein, R. J.; Mendoza, F. M.; Kato, Y. K.; Awschalom, D. D.
2005-11-01
Experiments on single nitrogen-vacancy (N-V) centres in diamond, which include electron spin resonance, Rabi oscillations, single-shot spin readout and two-qubit operations with a nearby13C nuclear spin, show the potential of this spin system for solid-state quantum information processing. Moreover, N-V centre ensembles can have spin-coherence times exceeding 50 μs at room temperature. We have developed an angle-resolved magneto-photoluminescence microscope apparatus to investigate the anisotropic electron-spin interactions of single N-V centres at room temperature. We observe negative peaks in the photoluminescence as a function of both magnetic-field magnitude and angle that are explained by coherent spin precession and anisotropic relaxation at spin-level anti-crossings. In addition, precise field alignment unmasks the resonant coupling to neighbouring `dark' nitrogen spins, otherwise undetected by photoluminescence. These results demonstrate the capability of our spectroscopic technique for measuring small numbers of dark spins by means of a single bright spin under ambient conditions.
Pramanik, S.; bandyopadhyay, S.; Cahay, M.
2003-01-01
We study high-field spin transport of electrons in a quasi one-dimensional channel of a $GaAs$ gate controlled spin interferometer (SPINFET) using a semiclassical formalism (spin density matrix evolution coupled with Boltzmann transport equation). Spin dephasing (or depolarization) is predominantly caused by D'yakonov-Perel' relaxation associated with momentum dependent spin orbit coupling effects that arise due to bulk inversion asymmetry (Dresselhaus spin orbit coupling) and structural inve...
International Nuclear Information System (INIS)
Byrski, T.; Beck, F.A.; Sharpey-Schafer, J.F.
1987-01-01
High-spin states of 159,160 Yb have been studied using the escape-suppressed array TESSA 2. Extensions of yrast and lateral bands have been found up to I ∼40. Experimental data suggest strong correlations between maximum alignment configurations of the valence nucleons and related collective states. Theoretical analysis fully supports the idea of prolate-collective vs. oblate-non-collective correlations. Band termination interpretation is discussed
Optical pumping production of spin polarized hydrogen
International Nuclear Information System (INIS)
Knize, R.J.; Happer, W.; Cecchi, J.L.
1984-01-01
There has been much interest recently in the production of large quantities of spin polarized hydrogen in various fields including controlled fusion, quantum fluids, high energy, and nuclear physics. One promising method for the development of large quantities of spin polarized hydrogen is the utilization of optical pumping with a laser. Optical pumping is a process where photon angular momentum is converted into electron and nuclear spin. The advent of tunable CW dye lasers (approx. 1 watt) allow the production of greater than 10 18 polarized atoms/sec. We have begun a program at Princeton to investigate the physics and technology of using optical pumping to produce large quantities of spin polarized hydrogen. Initial experiments have been done in small closed glass cells. Eventually, a flowing system, open target, or polarized ion source could be constructed
Internal spin structure of the nucleon
International Nuclear Information System (INIS)
Hughes, V.W.; Kuti, J.
1983-01-01
The study of the structure of the proton and neutron through deep inelastic scattering, initially with electrons but subsequently with muons and neutrinos as well, has played a central role in establishing the quark-parton theory of the composition of hadrons and of quantum chromodynamics (QCD). One important aspect of these theoretical and experimental developments is the two spin-dependent structure functions, which are independent of the two spin-averaged structure functions and define the internal spin structure of the nucleon. Since both quarks and gluons possess spin and the forces between them are spin dependent, we can expect important information on these forces and on nucleon structure to be obtained through the study of the spindependent aspects of the nucleon wave function, as has been the case before in atomic and nuclear physics
Stimulated polarization wave process in spin 3/2 chains
International Nuclear Information System (INIS)
Furman, G. B.
2007-01-01
Stimulated wave of polarization, triggered by a flip of a single spin, presents a simple model of quantum amplification. Recently, it has been demonstrated that, in an idealized one-dimensional Ising spin 1/2 chain with nearest-neighbor interactions and realistic spin 1/2 chain including the natural dipole-dipole interactions, irradiated by a weak resonant transverse field, a wave of flipped spins can be triggered by a single spin flip. Here we focuse on control of polarization wave in chain of spin 3/2, where the nuclear quadrupole interaction is dominant. Results of simulations for 1D spin chains and rings with up to five spins are presented.
Magnetic Nanostructures Spin Dynamics and Spin Transport
Farle, Michael
2013-01-01
Nanomagnetism and spintronics is a rapidly expanding and increasingly important field of research with many applications already on the market and many more to be expected in the near future. This field started in the mid-1980s with the discovery of the GMR effect, recently awarded with the Nobel prize to Albert Fert and Peter Grünberg. The present volume covers the most important and most timely aspects of magnetic heterostructures, including spin torque effects, spin injection, spin transport, spin fluctuations, proximity effects, and electrical control of spin valves. The chapters are written by internationally recognized experts in their respective fields and provide an overview of the latest status.
On the thermal properties of polarized nuclear matter
International Nuclear Information System (INIS)
Hassan, M.Y.M.; Montasser, S.S.; Ramadan, S.
1979-08-01
The thermal properties of polarized nuclear matter are calculated using Skyrme III interaction modified by Dabrowski for polarized nuclear matter. The temperature dependence of the volume, isospin, spin and spin isospin pressure and energies are determined. The temperature, isospin, spin and spin isospin dependence of the equilibrium Fermi momentum is also discussed. (author)
Yoshitake, Junki; Nasu, Joji; Motome, Yukitoshi
2016-10-07
Experimental identification of quantum spin liquids remains a challenge, as the pristine nature is to be seen in asymptotically low temperatures. We here theoretically show that the precursor of quantum spin liquids appears in the spin dynamics in the paramagnetic state over a wide temperature range. Using the cluster dynamical mean-field theory and the continuous-time quantum Monte Carlo method, which are newly developed in the Majorana fermion representation, we calculate the dynamical spin structure factor, relaxation rate in nuclear magnetic resonance, and magnetic susceptibility for the honeycomb Kitaev model whose ground state is a canonical example of the quantum spin liquid. We find that dynamical spin correlations show peculiar temperature and frequency dependence even below the temperature where static correlations saturate. The results provide the experimentally accessible symptoms of the fluctuating fractionalized spins evincing the quantum spin liquids.
Czech Academy of Sciences Publication Activity Database
Stone, J.; Ohya, S.; Rikovska, J.; Woehr, A.; Betts, P.; Dupák, Jan; Fogelberg, B.; Jacobsson, L.
č. 133 (2001), s. 111 - 115 ISSN 0304-3843 Institutional research plan: CEZ:AV0Z2065902 Keywords : nuclear orientation * Korringa constant Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.634, year: 2001
Quenching of spin-flip quadrupole transitions
International Nuclear Information System (INIS)
Castel, B.; Blunden, P.; Okuhara, Y.
1985-01-01
An increasing amount of experimental data indicates that spin-flip quadrupole transitions exhibit quenching effects similar to those reported earlier in (p,n) reactions involving l = 0 and l = 1 transitions. We present here two model calculations suggesting that the E2 spin-flip transitions are more affected than their M1 and M3 counterparts by the tensor and spin-orbit components of the nuclear force and should exhibit the largest quenching. We also review the experimental evidence corroborating our observations
Spin freezing in geometrically frustrated magnetic molecule Fe30 revealed by NMR
International Nuclear Information System (INIS)
Furukawa, Yuji; Borsa, Ferdinando; Fang Xikui; Kögerler, Paul; Micotti, Edoardo; Lascialfari, Alessandro; Kumagai, Ken-ichi
2012-01-01
Static and dynamical properties of Fe 3+ (3d 5 ; S = 5/2) spins in geometrically frustrated magnetic molecule Fe30 have been investigated by nuclear magnetic resonance (NMR) in the temperature range T = 0.1–300 K From a measurement of nuclear spin-lattice relaxation rates as a function of temperature, the fluctuation frequency of Fe 3+ spins is found to decrease with decreasing temperature, indicating spin freezing at low temperatures.
Spin-polarized spin excitation spectroscopy
International Nuclear Information System (INIS)
Loth, Sebastian; Lutz, Christopher P; Heinrich, Andreas J
2010-01-01
We report on the spin dependence of elastic and inelastic electron tunneling through transition metal atoms. Mn, Fe and Cu atoms were deposited onto a monolayer of Cu 2 N on Cu(100) and individually addressed with the probe tip of a scanning tunneling microscope. Electrons tunneling between the tip and the substrate exchange energy and spin angular momentum with the surface-bound magnetic atoms. The conservation of energy during the tunneling process results in a distinct onset threshold voltage above which the tunneling electrons create spin excitations in the Mn and Fe atoms. Here we show that the additional conservation of spin angular momentum leads to different cross-sections for spin excitations depending on the relative alignment of the surface spin and the spin of the tunneling electron. For this purpose, we developed a technique for measuring the same local spin with a spin-polarized and a non-spin-polarized tip by exchanging the last apex atom of the probe tip between different transition metal atoms. We derive a quantitative model describing the observed excitation cross-sections on the basis of an exchange scattering process.
International Nuclear Information System (INIS)
Anon.
2000-01-01
The first text deals with a new circular concerning the collect of the medicine radioactive wastes, containing radium. This campaign wants to incite people to let go their radioactive wastes (needles, tubes) in order to suppress any danger. The second text presents a decree of the 31 december 1999, relative to the limitations of noise and external risks resulting from the nuclear facilities exploitation: noise, atmospheric pollution, water pollution, wastes management and fire prevention. (A.L.B.)
Spin nematics next to spin singlets
Yokoyama, Yuto; Hotta, Chisa
2018-05-01
We provide a route to generate nematic order in a spin-1/2 system. Unlike the well-known magnon-binding mechanism, our spin nematics requires neither the frustration effect nor spin polarization in a high field or in the vicinity of a ferromagnet, but instead appears next to the spin singlet phase. We start from a state consisting of a quantum spin-1/2 singlet dimer placed on each site of a triangular lattice, and show that interdimer ring exchange interactions efficiently dope the SU(2) triplets that itinerate and interact, easily driving a stable singlet state to either Bose-Einstein condensates or a triplet crystal, some hosting a spin nematic order. A variety of roles the ring exchange serves includes the generation of a bilinear-biquadratic interaction between nearby triplets, which is responsible for the emergent nematic order separated from the singlet phase by a first-order transition.
International Nuclear Information System (INIS)
Tanida, Hiroshi; Takagi, Shigeru; Suzuki, Hiroyuki S.; Satoh, Isamu; Komatsubara, Takemi
2006-01-01
Microscopic properties have been investigated on a cubic nonmagnetic non-Kramers Γ 3 doublet ground-state (GS) system PrAg 2 In by complementarily utilizing 115 In (I=9/2) and 109 Ag (I=1/2) NMR with particular emphasis on the low-frequency (low-ω) dipole and multipole (octupole and/or quadrupole) fluctuations of f-electrons as probed by the nuclear spin relaxation rates 1/ 115 T 1 and 1/ 109 T 1 . We show that 1/ 115 T 1 and 1/ 109 T 1 are anomalously enhanced respectively below≅50 K and ≅100K over those expected for the low-ω dipole fluctuations of the excited magnetic Γ 4 and Γ 5 states in a simple crystalline-electric-field model for a Γ 3 GS system. By comparing 1/( 115 T 1 T) and 1/( 109 T 1 T) and also by considering an invariant form of the hyperfine and/or quadrupole couplings of Γ 3 octupole and/or quadrupole moments with Ag/In nuclear dipole and/or quadrupole moments, we show that Γ 3 octupole fluctuations dominate 1/ 109 T 1 and quadrupole ones can possibly contribute to 1/ 115 T 1 at low T. (author)
Uspenskaya, Yu. A.; Mamin, G. V.; Babunts, R. A.; Badalyan, A. G.; Edinach, E. V.; Asatryan, H. R.; Romanov, N. G.; Orlinskii, S. B.; Khanin, V. M.; Wieczorek, H.; Ronda, C.; Baranov, P. G.
2018-03-01
The presence of aluminum and gallium isotopes with large nuclear magnetic and quadrupole moments in the nearest environment of impurity ions Mn2+ and Ce3+ in garnets made it possible to use hyperfine and quadrupole interactions with these ions to determine the spatial distribution of the unpaired electron and the gradient of the electric field at the sites of aluminum and gallium in the garnet lattice. High-frequency (94 GHz) electron spin echo detected electron paramagnetic resonance and electron-nuclear double resonance measurements have been performed. Large difference in the electric field gradient and quadrupole splitting at octahedral and tetrahedral sites allowed identifying the positions of aluminum and gallium ions in the garnet lattice and proving that gallium first fills tetrahedral positions in mixed aluminum-gallium garnets. This should be taken into account in the development of garnet-based scintillators and lasers. It is shown that the electric field gradient at aluminum nuclei near Mn2+ possessing an excess negative charge in the garnet lattice is ca. 2.5 times larger than on aluminum nuclei near Ce3+.
Gordon Conference on Nuclear Research
International Nuclear Information System (INIS)
Austin, S.M.
1983-09-01
Session topics were: quarks and nuclear physics; anomalons and anti-protons; the independent particle structure of nuclei; relativistic descriptions of nuclear structure and scattering; nuclear structure at high excitation; advances in nuclear astrophysics; properties of nuclear material; the earliest moments of the universe; and pions and spin excitations in nuclei
The decay of /sup 185/Hg low-spin states in /sup 185/Au as a probe of the nuclear models
Bourgeois, C; Kilcher, P; Roussière, B; Sauvage-Letessier, J
1981-01-01
The /sup 185/Au has been studied from the beta /sup +//EC decay of /sup 185m+g/Hg using the ISOCELE facility. Conversion electron measurements have been performed by means of a semi-circular magnetic spectrograph: new low-energy transitions have been observed. A 330 keV very converted transition has also been found. Its existence is discussed. In addition to the usual states observed in heavier gold isotopes, numerous negative-parity low-spin states have been located. The experimental states corresponding to a prolate shaped nucleus are compared with those extracted from an 'axial rotor+quasi-particle' coupling model. They could be identified with two state families, the first one arising from the h9/2+f5/2 sub-shells, the second from the p3/2+f7/2 sub-shells. (12 refs).
International Nuclear Information System (INIS)
Astier, A.
2013-01-01
Two fusion-fission experiments have been performed and studied with the Euroball Ge array: 12 C+ 238 U at 90 MeV bombarding energy, and 18 O + 208 Pb at 85 MeV. Among the lot of new information extracted during the last decade, the latest results discussed here are the discovery of the high-spin states of 119-126 Sn. The maximum value of angular momentum available in the Vh 11/2 shell, i.e. for mid-occupation and the breaking of the three neutron pairs (seniority v = 6), has been identified in several tin isotopes. It is the first time that such high-seniority states are established in spherical nuclei. (authors)
International Nuclear Information System (INIS)
1995-01-01
For the most part the work supported by this grant has involved study of the spin, isospin, and multipole content of the continuum of nuclei. Most of the work has used polarized (p,p') or (d,d') reactions, measuring spin observables to infer properties of the target nuclei. In addition some work has been done using the (p,nx) reaction to study the Δ excitation region of the continuum. Publications resulting from this work have included seventeen refereed articles and letters, seventeen abstracts and conference talks, three of which were invited. Experiments included: 12 C(p,p), E=318 MeV; 48 Ca(p,p), E=318 MeV; 40 Ca(p,p), E=800 MeV; 208 Pb(p,p), E=200 MeV; H, 12 C(n,p); 40 Ca(p,p), E=580 MeV; 208 Pb(p,p), E=200 MeV; 12 C(d,d), E d =400 MeV; 40 Ca(p,p), E=500 MeV; 12 C(p,p), E=800 MeV; 40 Ca(d,d), E d =400 MeV; 40 Ca(p,p), E p =318 MeV; 208 Pb(p,p), E p =200 MeV; 12 C(d,d), E d =400 MeV; 2 H, 12 C(p,nπ), E p =800 MeV; 12 C(d,d), E d =600 MeV
International Nuclear Information System (INIS)
Roger, Michel.
1980-06-01
The model presented in this thesis, with only two adjustable parameters, is alone able to account quantitatively for all the results described in chapter I and interpreted in chapter II. The development of this model was based originally on two essential ideas: - the simple model given in introduction suggests that in a hard-sphere quantum solid, three- and four-particle exchanges may be as important and even more favourable than two-atom exchanges. - By accounting for four-spin exchange terms in the Hamiltonian of the system, fourth power terms of the order parameter (polarisation) liable to give first-order transitions are introduced into the equation of free energy in a molecular field. On the basis of these two ideas the thesis is arranged in two parts: 1) Part one (ch. III to VIII) analyses the consequences, from the viewpoint of magnetic and thermodynamic properties, of a phenomenological Hamiltonian including four-spin exchanges. 2) The aim of part two is to estimate from microscopic equations the hierarchy amongst 2, 3 and 4-particle exchanges. A new approach, due to J.M. Delrieu, is proposed for a realistic wave function approximation accounting for the geometric correlations between hard cores. Reasons are given to justify the existence of a strong four-particle exchange in body-centred cubic 3 He. In a compact hexagonal lattice on the other hand the three-particle exchange is shown to be predominant. However three-particle exchanges promote ferromagnetism, so an ordered ferromagnetic phase is foreseen for compact hexagonal 3 He. A crucial test for our model would be to measure the sign of the Curie-Weiss constant in c.h. 3 He [fr
Vuichoud , Basile; Milani , Jonas; Chappuis , Quentin; Bornet , Aurélien; Bodenhausen , Geoffrey; Jannin , Sami
2015-01-01
Dynamic nuclear polarization at 1.2 K and 6.7 T allows one to achieve spin temperatures on the order of a few millikelvin, so that the high-temperature approximation (Delta E < kT) is violated for the nuclear Zeeman interaction Delta E = gamma B(0)h/(2 pi) of most isotopes. Provided that, after rapid dissolution and transfer to an NMR or MRI system, the hyperpolarized molecules contain at least two nuclear spins I and S with a scalar coupling J(IS), the polarization of spin I (short for 'inve...
DEFF Research Database (Denmark)
Jankowska, Marzena; Kupka, Teobald; Stobiński, Leszek
2016-01-01
Hartree-Fock and density functional theory with the hybrid B3LYP and general gradient KT2 exchange-correlation functionals were used for non-relativistic and relativistic nuclear magnetic shielding calculations of helium, neon, argon, krypton and xenon dimers and free atoms. Relativistic...
Selected topics in nuclear structure
International Nuclear Information System (INIS)
1994-01-01
The collection of abstracts on selected topics in nuclear structure are given. Special attention pays to collective excitations and high-spin states of nuclei, giant resonance structure, nuclear reaction mechanisms and so on
Spin microscope based on optically detected magnetic resonance
Berman, Gennady P.; Chernobrod, Boris M.
2007-12-11
The invention relates to scanning magnetic microscope which has a photoluminescent nanoprobe implanted in the tip apex of an atomic force microscope (AFM), a scanning tunneling microscope (STM) or a near-field scanning optical microscope (NSOM) and exhibits optically detected magnetic resonance (ODMR) in the vicinity of unpaired electron spins or nuclear magnetic moments in the sample material. The described spin microscope has demonstrated nanoscale lateral resolution and single spin sensitivity for the AFM and STM embodiments.
Spin Coherence in Silicon-based Quantum Structures and Devices
2017-08-31
Using electron spin resonance (ESR) to measure the den- sity of shallow traps, we find that the two sets of devices are nearly identical , indicating...experiments which cannot utilize a clock transition or a field-cancelling decoherence-free subspace. Our approach was to lock the microwave source driving...the electron spins to a strong nuclear spin signal. In our initial experiments we locked to the proton signal in a water cell. However, the noise in
Ultracoherent operation of spin qubits with superexchange coupling
Rančić, Marko J.; Burkard, Guido
2017-11-01
With the use of nuclear-spin-free materials such as silicon and germanium, spin-based quantum bits (qubits) have evolved to become among the most coherent systems for quantum information processing. The new frontier for spin qubits has therefore shifted to the ubiquitous charge noise and spin-orbit interaction, which are limiting the coherence times and gate fidelities of solid-state qubits. In this paper we investigate superexchange, as a means of indirect exchange interaction between two single electron spin qubits, each embedded in a single semiconductor quantum dot (QD), mediated by an intermediate, empty QD. Our results suggest the existence of "supersweet spots", in which the qubit operations implemented by superexchange interaction are simultaneously first-order-insensitive to charge noise and to errors due to spin-orbit interaction. The proposed spin-qubit architecture is scalable and within the manufacturing capabilities of semiconductor industry.
CNI polarimetry and the hadronic spin dependence of pp scattering
International Nuclear Information System (INIS)
Trueman, T.L.
1996-01-01
Methods for limiting the size of hadronic spin-flip in the Coulomb- Nuclear Interference. region are critically assessed. This work was presented at the High Energy Polarimetry Workshop in Amsterdam, Sept. 9, 1996 and the RHIC Spin Collaboration meeting in Marseille, Sept. 17, 1996
Wüst, Gunter Johannes
2015-01-01
Self-assembled semiconductor quantum dots (QD) are excellent single photon sources and possible hosts for electron spin qubits, which can be initialized, manipulated and read-out optically. The nuclear spins in nano-structured semiconductors play a central role in quantum applications. The nuclear spins represent a useful resource for generating local magnetic fields but nuclear spin noise represents a major source of dephasing for spin qubits. Controlling the nuclear spins enhances the resou...
Energy Technology Data Exchange (ETDEWEB)
NONE
2006-07-01
The following topics were ealt with: Hadron physics with proton and deuteron probes, physics projects with Georgian participation, spin physics with antiprotons and leptons, spin filtering experiments, ISTC projects, technical issues for FAIR. (HSI)
International Nuclear Information System (INIS)
Ji Xiangdong
2003-01-01
Spin is a beautiful concept that plays an ever important role in modern physics. In this talk, I start with a discussion of the origin of spin, and then turn to three themes in which spin has been crucial in subatomic physics: a lab to explore physics beyond the standard model, a tool to measure physical observables that are hard to obtain otherwise, a probe to unravel nonperturbative QCD. I conclude with some remarks on a world without spin
Latli, Bachir; Hrapchak, Matt; Chevliakov, Maxim; Li, Guisheng; Campbell, Scot; Busacca, Carl A; Senanayake, Chris H
2015-05-30
Deleobuvir, (2E)-3-(2-{1-[2-(5-bromopyrimidin-2-yl)-3-cyclopentyl-1-methyl-1H-indole-6-carboxamido]cyclobutyl}-1-methyl-1H-benzimidazol-6-yl)prop-2-enoic acid (1), is a non-nucleoside, potent, and selective inhibitor of hepatitis C virus NS5B polymerase. Herein, we describe the detailed synthesis of this compound labeled with carbon-13 and carbon-14. The synthesis of its three major metabolites, namely, the reduced double bond metabolite (2) and the acyl glucuronide derivatives of (1) and (2), is also reported. Aniline-(13) C6 was the starting material to prepare butyl (E)-3-(3-methylamino-4-nitrophenyl-(13) C6 )acrylate [(13) C6 ]-(11) in six steps. This intermediate was then used to obtain [(13) C6 ]-(1) and [(13) C6 ]-(2) in five and four more steps, respectively. For the radioactive synthesis, potassium cyanide-(14) C was used to prepare 1-cylobutylaminoacid [(14) C]-(23) via Buchrer-Bergs reaction. The carbonyl chloride of this acid was then used to access both [(14) C]-(1) and [(14) C]-(2) in four steps. The acyl glucuronide derivatives [(13) C6 ]-(3), [(13) C6 ]-(4) and [(14) C]-(3) were synthesized in three steps from the acids [(13) C6 ]-(1), [(13) C6 ]-(2) and [(14) C]-(1) using known procedures. Copyright © 2015 John Wiley & Sons, Ltd.
International Nuclear Information System (INIS)
Zielinski, M.; Zielinska, A.; Papiernik-Zielinska, H.
2000-01-01
C-13 isotope fractionation in the decarboxylation of pure phenylpropiolic acid (PPA) below and above its melting point and the decarboxylation of PPA in phenylacetylene solutions has been investigated in sealed under vacuum reaction vessels. The reactive PPA undergoing decarboxylation polymerizes with the liquid product, phenylacetylene in reaction cage producing a condensation compound, which does not decarboxylate measurably in the 120-190 o C. Especially low final carbon dioxide yields (about 11%) have been obtained in the decarboxylation of PPA in phenylacetylene solution at 132 o C and below this temperature. The carbon dioxide is depleted in carbon-13. The ratio of the carbon isotope ratios of carboxylic carbon of PPA before decarboxylation, R( 13 C/ 12 C so ), and of the first portions of carbon dioxide obtained at partial decarboxylation R( 13 C/ 12 C) pf , located in the range 1.007-1.010, indicates that the pure kinetic fractionation of 13 C in the elementary decarboxylation step is negligible and the C-13 fractionation in the condensed phase dimer/monomer equilibria contributes mainly to the resultant experimental carbon isotope fractionation. A preliminary discussion of the experimental isotope findings is presented. (author)
International Nuclear Information System (INIS)
Anon.
1980-01-01
From 25 September to 1 October, some 150 spin enthusiasts gathered in Lausanne for the 1980 International Symposium on High Energy Physics with Polarized Beams and Polarized Targets. The programme was densely packed, covering physics interests with spin as well as the accelerator and target techniques which make spin physics possible
DEFF Research Database (Denmark)
Yu, Xiao-Qin; Zhu, Zhen-Gang; Su, Gang
2017-01-01
The thermoelectric performance of a topological energy converter is analyzed. The H-shaped device is based on a combination of transverse topological effects involving the spin: the inverse spin Hall effect and the spin Nernst effect. The device can convert a temperature drop in one arm into an e...
Cross, Rod
2013-01-01
Measurements are presented on the rise of a spinning egg. It was found that the spin, the angular momentum and the kinetic energy all decrease as the egg rises, unlike the case of a ballerina who can increase her spin and kinetic energy by reducing her moment of inertia. The observed effects can be explained, in part, in terms of rolling friction…
Energy Technology Data Exchange (ETDEWEB)
Queiroz, Jorge F. de; San Gil, Rosane A.S. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Inst. de Quimica; Marques, Rosana G.G. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas
1994-12-31
This work presents studies concerning the utilization of carbon-13, hydrogen-1, NMR as chemical analytical technique to evaluate molecular characteristics of alkyl-benzene fractions. The methodology is described, including standards solutions and their preparations, as well as the experimental techniques used. The results are presented and discussed 2 refs., 4 tabs.
International Nuclear Information System (INIS)
Laloee, F.; Freed, J.H.
1988-01-01
Low-density gases, in which atoms are separated by large distances, have long provided an enjoyable playground for physicists. One might suppose the pleasure of the playground would by now have been exhausted by the very simplicity of low-density gases. Recent work by a number of investigators including the author shows that this is not the case low-density gases continue to serve up a rich variety of phenomena as well as counterintuitive surprises. In particular, the macroscopic properties of a gas composed of individual hydrogen or helium atoms can under special circumstances by changed dramatically by quantum-mechanical effects. According to quantum theory, the nucleus of an atom behaves in a way similar to a rotating top, which has angular momentum about its axis of rotation; that is, the nucleus has spin, known more precisely as spin angular momentum. If the atoms of a gas are spin-polarized, so that their nuclei all have their spins pointing in the same direction, the viscosity of the gas can be changed enormously and so can its ability to conduct heat. Quantum-mechanical correlations among the nuclei called spin waves, which up to now had been observed only in certain liquids and solids such as magnets, can also arise. The changes are large enough for one to say the quantum-mechanical effects have caused the gas to take on entirely new properties. In a certain sense it is amazing to think that polarizing the nuclear spins can have any effect on the macroscopic properties of the gas, since the nuclear spins are son weakly coupled to the outside world. Yet the observations are in full agreement with with theory. Moreover, because spin-polarized gases are still fairly simple systems, they can be understood in terms fundamental principles, something that is still not possible to do in the case of liquids and solids
Technologic spin-off from CNEA's activities
International Nuclear Information System (INIS)
Belinco, Cesar G.
2001-01-01
An analysis is made of the spin-off of technology from the nuclear activities in Argentina. Several examples are mentioned in fields such as material sciences, non-destructive testing, forensic research, space activities, instrumentation as well as in environmental studies
The spin-orbit interaction in nuclei
International Nuclear Information System (INIS)
Skyrme, T.H.R.
1994-01-01
The analysis previously made of the average nuclear potential has been extended to consideration of the spin-orbit interactions. It has not been possible to find a satisfactory two-body interaction consistent with all the data; that suggested by the phase-shift analysis of nucleon-nucleon scattering is just within the region of possible forms. (author). 13 refs, 1 fig