WorldWideScience

Sample records for carbon dioxide cooled reactors

  1. Lessons Learned From Gen I Carbon Dioxide Cooled Reactors

    Energy Technology Data Exchange (ETDEWEB)

    David E. Shropshire

    2004-04-01

    This paper provides a review of early gas cooled reactors including the Magnox reactors originating in the United Kingdom and the subsequent development of the Advanced Gas-cooled Reactors (AGR). These early gas cooled reactors shared a common coolant medium, namely carbon dioxide (CO2). A framework of information is provided about these early reactors and identifies unique problems/opportunities associated with use of CO2 as a coolant. Reactor designers successfully rose to these challenges. After years of successful use of the CO2 gas cooled reactors in Europe, the succeeding generation of reactors, called the High Temperature Gas Reactors (HTGR), were designed with Helium gas as the coolant. Again, in the 21st century, with the latest reactor designs under investigation in Generation IV, there is a revived interest in developing Gas Cooled Fast Reactors that use CO2 as the reactor coolant. This paper provides a historical perspective on the 52 CO2 reactors and the reactor programs that developed them. The Magnox and AGR design features and safety characteristics were reviewed, as well as the technologies associated with fuel storage, reprocessing, and disposal. Lessons-learned from these programs are noted to benefit the designs of future generations of gas cooled nuclear reactors.

  2. Lessons learned from Gen-I carbon dioxide cooled reactors

    International Nuclear Information System (INIS)

    This paper provides a review of early gas cooled reactors including the Magnox reactors originating in the United Kingdom and the subsequent development of the Advanced Gas-cooled Reactors (AGR). These early gas cooled reactors shared a common coolant medium, namely carbon dioxide (CO2). A framework of information is provided about these early reactors and identifies unique problems/opportunities associated with use of CO2 as a coolant. Reactor designers successfully rose to these challenges. After years of successful use of the CO2 gas cooled reactors in Europe, the succeeding generation of reactors, called the High Temperature Gas Reactors (HTGR), were designed with Helium gas as the coolant. Again, in the 21. century, with the latest reactor designs under investigation in Generation IV, there is a revived interest in developing Gas Cooled Fast Reactors that use CO2 as the reactor coolant. This paper provides a historical perspective on the 52 CO2 reactors and the reactor programs that developed them. The Magnox and AGR design features and safety characteristics were reviewed, as well as the technologies associated with fuel storage, reprocessing, and disposal. Lessons-learned from these programs are noted to benefit the designs of future generations of gas cooled nuclear reactors. (author)

  3. Coolant chemistry of the advanced carbon dioxide cooled reactor

    International Nuclear Information System (INIS)

    The large scale production of electricity by uranium fission has been achieved in the United Kingdom exclusively by reactors which are gas cooled and moderated by graphite. In this way the use of uranium with close to the natural isotopic content was possible. Once the choice of graphite as moderator had been made then the selection of a suitable gas to transport heat from the core to the steam generating equipment was limited and, in fact, only two have been identified as having suitable chemical and nuclear properties, namely helium and carbon dioxide. The first of these has the disadvantage of being expensive but has a high heat transfer capability and is fundamentally inert, its reactivity being controlled entirely by the level of impurities such as hydrogen and water. With the closure of the OECD Dragon High Temperature Reactor Project interest in helium cooling for nuclear plant has faded in the UK. The alternative coolant, carbon dioxide, which is cheap but chemically reactive is used in the first generation Magnox power stations and in the Commercial Advanced Gas Cooled Reactor (CAGR) design. In the more highly rated CAGR design the fuel consists of enriched uranium in the form of dioxide encased in stainless steel; the gas outlet temperature of the core is increased to around 6000C. The purpose of this paper is to provide an insight into the current thinking about the nature of the complex chemistry associated with the CAGR coolant and how this chemistry influences the rate of deposition onto the fuel pin surfaces and the rate of graphite moderator oxidation. The application of these ideas to the prediction of the behaviour of a CAGR core with particular reference to the calculation of coolant composition within the porous moderator structure at points remote from the surface, is outlined and the use of all this information to define a satisfactory range of coolant composition is also described

  4. A carbon dioxide partial condensation direct cycle for advanced gas cooled fast and thermal reactors

    International Nuclear Information System (INIS)

    A carbon dioxide partial condensation direct cycle concept has been proposed for gas cooled fast and thermal reactors. The fast reactor with the concept are evaluated to be a potential alternative option to liquid metal cooled fast reactors, providing comparable cycle efficiency at the same core outlet temperature, eliminating the safety problems, simplifying the heat transport system and making easier plant maintenance. The thermal reactor with the concept is expected to be an alternative solution to current high temperature gas cooled reactors (HTGRs) with helium gas turbines, allowing comparable cycle efficiency at the moderate temperature of 650 C instead of 800 C in HTGRs. (author)

  5. Coupling a Supercritical Carbon Dioxide Brayton Cycle to a Helium-Cooled Reactor.

    Energy Technology Data Exchange (ETDEWEB)

    Middleton, Bobby [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Pasch, James Jay [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Kruizenga, Alan Michael [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Walker, Matthew [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

    2016-01-01

    This report outlines the thermodynamics of a supercritical carbon dioxide (sCO2) recompression closed Brayton cycle (RCBC) coupled to a Helium-cooled nuclear reactor. The baseline reactor design for the study is the AREVA High Temperature Gas-Cooled Reactor (HTGR). Using the AREVA HTGR nominal operating parameters, an initial thermodynamic study was performed using Sandia's deterministic RCBC analysis program. Utilizing the output of the RCBC thermodynamic analysis, preliminary values of reactor power and of Helium flow rate through the reactor were calculated in Sandia's HelCO2 code. Some research regarding materials requirements was then conducted to determine aspects of corrosion related to both Helium and to sCO2 , as well as some mechanical considerations for pressures and temperatures that will be seen by the piping and other components. This analysis resulted in a list of materials-related research items that need to be conducted in the future. A short assessment of dry heat rejection advantages of sCO2> Brayton cycles was also included. This assessment lists some items that should be investigated in the future to better understand how sCO2 Brayton cycles and nuclear can maximally contribute to optimizing the water efficiency of carbon free power generation

  6. Supercritical Carbon Dioxide turbomachinery design for water-cooled Small Modular Reactor application

    International Nuclear Information System (INIS)

    Highlights: • We described the concept of coupling the S-CO2 Brayton cycle to the water-cooled SMRs. • We describe a turbomachinery design code called KAISDTMD that can use real gases too. • We suggest changes to the S-CO2 cycle layout with multiple-independent shafts. • KAISTTMD was used to design the turbomachinery of suggested layout. - Abstract: The Supercritical Carbon Dioxide (S-CO2) Brayton cycle has been gaining attention due to its compactness and high efficiency at moderate turbine inlet temperature. Previous S-CO2 cycle research works in the field of nuclear engineering were focused on its application to the next generation reactor with higher turbine inlet temperature than the existing conventional water-cooled nuclear power plants. However, it was shown in authors’ previous paper that the advantages of the S-CO2 Brayton cycle can be also further applied to the water-cooled Small Modular Reactor (SMR) with a success, since SMR requires minimal overall footprint while retaining high performance. One of the major issues in the S-CO2 Brayton cycle is the selection and design of appropriate turbomachinery for the designed cycle. Because most of the nuclear industry uses incompressible working fluids or ideal gases in the turbomachinery, a more detailed examination of the design of the turbomachinery is required for a power system that uses S-CO2 as working fluid. This is because the S-CO2 Brayton cycle high efficiency is the result of the non-ideal variation of properties near the CO2 critical point. Thus, the major focus of this paper is to suggest the design of the turbomachinery necessary for the S-CO2 Brayton cycle coupled to water cooled SMRs. For this reason, a S-CO2 Brayton cycle turbomachinery design methodology was suggested and the suggested design methodology was first tested with the existing experimental data to verify its capability. After then, it was applied to the proposed reference system to demonstrate its capability and to

  7. Computational Analysis of Supercritical Carbon Dioxide Gas Turbine for Liquid Metal Cooled Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Wi S.; Suh, Kune Y. [Seoul National University, Seoul (Korea, Republic of)

    2008-10-15

    Energy demands at a remote site are increased as the world energy requirement diversifies so that they should generate power on their own site. A Small Modular Reactor (SMR) becomes a viable option for these sites. Generally, the economic feasibility of a high power reactor is greater than that for SMR. As a result the supercritical fluid driven Brayton cycle is being considered for a power conversion system to increase economic competitiveness of SMR. The Brayton cycle efficiency is much higher than that for the Rankine cycle. Moreover, the components of the Brayton cycle are smaller than Rankine cycle's due to high heat capacity when a supercritical fluid is adopted. A lead (Pb) cooled SMR, BORIS, and a supercritical fluid driven Brayton cycle, MOBIS, are being developed at the Seoul National University (SNU). Dostal et al. have compared some advanced power cycles and proposed the use of a supercritical carbon dioxide (SCO{sub 2}) driven Brayton cycle. According to their suggestion SCO{sub 2} is adopted as a working fluid for MOBIS. The turbo machineries are most important components for the Brayton cycle. The turbo machineries of Brayton cycle consists of a turbine to convert kinetic energy of the fluid into mechanical energy of the shaft, and a compressor to recompress and recover the driving force of the working fluid. Therefore, turbine performance is one of the pivotal factors in increasing the cycle efficiency. In MOBIS a supercritical gas turbine is designed in the Gas Advanced Turbine Operation (GATO) and analyzed in the Turbine Integrated Numerical Analysis (TINA). A three-dimensional (3D) numerical analysis is employed for more detailed design to account for the partial flow which the one-dimensional (1D) analysis cannot consider.

  8. Thermal hydraulic feasibility of supercritical carbon dioxide Brayton cycle power conversion for the KALIMER-150 sodium-cooled fast reactor

    International Nuclear Information System (INIS)

    One possible approach to achieving a significant reduction in the overnight and operating costs of a sodium-cooled fast reactor is to replace the traditional Rankine steam cycle with an advanced power converter that consists of a gas turbine Brayton cycle that utilizes supercritical carbon dioxide (S-CO2) as the working fluid. A joint project between Argonne National Laboratory and the Korea Atomic Energy Research Institute has been initiated to investigate the thermal-hydraulic feasibility of coupling the S-CO2 Brayton cycle to the KALIMAR-150 sodium-cooled fast reactor conceptual design. As an initial step in investigating the system aspects of coupling the reactor to the S-CO2 Brayton cycle, the case is investigated in which the intermediate heat transfer loop is eliminated in order to achieve additional cost reductions. The main objectives are to determine the potential gain in plant efficiency and to estimate the size of the key Brayton cycle components. A S-CO2 Brayton cycle efficiency of 43.2% is calculated. Accounting for primary pump power and other in-house loads, a net plant efficiency of 40.8% is obtained, compared to 38.2% for the current (Rankine cycle) plant. If higher Na temperatures could be accommodated, then a 1% gain in plant efficiency could be obtained for each 20degC incremental increase in sodium core outlet temperature. Further investigation of the thermal sizing of the Na/S-Co2 heat exchanger is also carried out; parametric sensitivity studies are performed for the case in which the intermediate heat transport system is retained as well as the case in which it is eliminated. (author)

  9. Investigation of alternative layouts for the supercritical carbon dioxide Brayton cycle for a sodium-cooled fast reactor

    International Nuclear Information System (INIS)

    Analyses of supercritical carbon dioxide (S-CO2) Brayton cycle performance have largely settled on the recompression supercritical cycle (or Feher cycle) incorporating a flow split between the main compressor downstream of heat rejection, a recompressing compressor providing direct compression without heat rejection, and high and low temperature recuperators to raise the effectiveness of recuperation and the cycle efficiency. Alternative cycle layouts have been previously examined by Angelino (Politecnico, Milan), by MIT (Dostal, Hejzlar, and Driscoll), and possibly others but not for sodium-cooled fast reactors (SFRs) operating at relatively low core outlet temperature. Thus, the present authors could not be sure that the recompression cycle is an optimal arrangement for application to the SFR. To ensure that an advantageous alternative layout has not been overlooked, several alternative cycle layouts have been investigated for a S-CO2 Brayton cycle coupled to the Advanced Burner Test Reactor (ABTR) SFR preconceptual design having a 510 deg. C core outlet temperature and a 470 deg. C turbine inlet temperature to determine if they provide any benefit in cycle performance (e.g., enhanced cycle efficiency). No such benefits were identified, consistent with the previous examinations, such that attention was devoted to optimizing the recompression supercritical cycle. The effects of optimizing the cycle minimum temperature and pressure are investigated including minimum temperatures and/or pressures below the critical values. It is found that improvements in the cycle efficiency of 1% or greater relative to previous analyses which arbitrarily fixed the minimum temperature and pressure can be realized through an optimal choice of the combination of the minimum cycle temperature and pressure (e.g., for a fixed minimum temperature there is an optimal minimum pressure). However, this leads to a requirement for a larger cooler for heat rejection which may impact the

  10. Carbon dioxide methanation for intensified reactors

    OpenAIRE

    Coronado Martín, Irene

    2015-01-01

    The present work is related to the development of sustainable energy systems based on the Power-to-Gas concept. The main objective is to utilise renewable hydrogen and carbon dioxide to produce methane for storage in the natural gas infrastructure. Multitubular fixed-bed reactors are established at industrial scale for CO2 methanation. Catalytic pellets commonly loaded in this type of reactor involve poor heat transfer and high pressure drop that lead to inefficient processes. Today, reac...

  11. Transient Accident Analysis of a Supercritical Carbon Dioxide Brayton Cycle Energy Converter Coupled to an Autonomous Lead-Cooled Fast Reactor

    International Nuclear Information System (INIS)

    The Supercritical Carbon Dioxide (S-CO2) Brayton Cycle is a promising advanced alternative to the Rankine saturated steam cycle and recuperated gas Brayton cycle for the energy converters of specific reactor concepts belonging to the U.S. Department of Energy Generation IV Nuclear Energy Systems Initiative. A new plant dynamics analysis computer code has been developed for simulation of the S-CO2 Brayton cycle coupled to an autonomous, natural circulation Lead-Cooled Fast Reactor (LFR). The plant dynamics code was used to simulate the whole-plant response to accident conditions. The specific design features of the reactor concept influencing passive safety are discussed and accident scenarios are identified for analysis. Results of calculations of the whole-plant response to loss-of-heat sink, loss-of-load, and pipe break accidents are demonstrated. The passive safety performance of the reactor concept is confirmed by the results of the plant dynamics code calculations for the selected accident scenarios. (authors)

  12. Carbon dioxide direct cycle modular reactor

    International Nuclear Information System (INIS)

    Recently, as the micro gas-turbine power generation is clean for environment and has high convenience, it is focused as a small size dispersion electric source for super markets, hospitals, factories, and so on. And, a modular high temperature gas reactor (PBMR) adopting the gas turbine is also focused recently, and is progressed on its construction in South Africa and reported on construction plan of the Exelon Inc. in U.S.A. PBMR has specific safety for a small size and pebble-bed reactor and also has some characters on low construction cost similar to that of LWR due to simplification and small size module adoption of its plant. The PBMR uses helium for its coolants, of which exit temperature is set for at 900degC to get higher thermal efficiency. This is because of its adoption of Brayton cycle to fast reduce the efficiency with falling temperature. However, as helium is a costly and easy-emission vapor, it is desired to alternate to cheaper and more difficult-emission vapor. Here were introduced on carbon dioxide (CO2) direct cycle using carbon dioxide with extremely higher thermal efficiency than helium and its applicability to nuclear reactors. (G.K.)

  13. Electrochemical Reactor for Producing Oxygen From Carbon Dioxide Project

    Data.gov (United States)

    National Aeronautics and Space Administration — An electrochemical reactor is proposed by MicroCell Technologies, LLC to electrochemically reduce carbon dioxide to oxygen. In support of NASA's advanced life...

  14. The ISIS operation: Robotics repair work on the CHINON A3 natural uranium, carbon dioxide cooled, graphite moderated reactor

    International Nuclear Information System (INIS)

    After describing the upper internal support structures of the CHINON A3 reactor, the problems resulting from their degradation due to corrosion and to the difficulties of the ISIS operation are presented here. The repair method is as follows: all tools and repair parts reach the working area by the feeding-pipes drilled through the 7 m thick concrete vessel surrounding the reactor core; the robots handle into the reactor, the tool heads and the repair parts which are automatically positioned and welded around the corroded structure, thus restoring the support of measurement devices. The parts are either linked together or to the existing structure by means of 2 studs of 12 mm in diameter. The different phases to sort out a problem are: in-core topography, reconforming of the full-scale mock-up with the repair area, learning on this mock-up and in-core repair. The technical specificities of the robots used are the following: they have an 11 meter long, 0.22 meter across telescopic mast with jointed arms reaching a radius of 2.7 m. Then the useful load is 70 daN and the repeatability 0.1 mm. Different tool heads can be handled by the robot: telemeter and laser reconstruction: it allows to locate the in core points and to materialize them on the mock-up by a laser crossed-beams locating technique; scouring: it cleans the corroded parts of the structures before welding; welding: it allows the parts handling and the carried studs welding; screwing; tensile test: carried out when the stud welds are defective. A high level computerized control system is organized around a central unit which calculates the displacements of robots and synchronises the actions of different tools by communicating with several local units. A 100,000 hour designing, a 200,000 hour building and assembling and a 450,000 hour operating on working area were necessary to repair 15 out of the 102 corroded structures by fitting and welding 205 repair parts. 10 figs

  15. Development of a plant dynamics computer code for analysis of a supercritical carbon dioxide Brayton cycle energy converter coupled to a natural circulation lead-cooled fast reactor.

    Energy Technology Data Exchange (ETDEWEB)

    Moisseytsev, A.; Sienicki, J. J.

    2007-03-08

    STAR-LM is a lead-cooled pool-type fast reactor concept operating under natural circulation of the coolant. The reactor core power is 400 MWt. The open-lattice core consists of fuel pins attached to the core support plate, (the does not consist of removable fuel assemblies). The coolant flows outside of the fuel pins. The fuel is transuranic nitride, fabricated from reprocessed LWR spent fuel. The cladding material is HT-9 stainless steel; the steady-state peak cladding temperature is 650 C. The coolant is single-phase liquid lead under atmospheric pressure; the core inlet and outlet temperatures are 438 C and 578 C, respectively. (The Pb coolant freezing and boiling temperatures are 327 C and 1749 C, respectively). The coolant is contained inside of a reactor vessel. The vessel material is Type 316 stainless steel. The reactor is autonomous meaning that the reactor power is self-regulated based on inherent reactivity feedbacks and no external power control (through control rods) is utilized. The shutdown (scram) control rods are used for startup and shutdown and to stop the fission reaction in case of an emergency. The heat from the reactor is transferred to the S-CO{sub 2} Brayton cycle in in-reactor heat exchangers (IRHX) located inside the reactor vessel. The IRHXs are shell-and-tube type heat exchangers with lead flowing downwards on the shell side and CO{sub 2} flowing upwards on the tube side. No intermediate circuit is utilized. The guard vessel surrounds the reactor vessel to contain the coolant, in the very unlikely event of reactor vessel failure. The Reactor Vessel Auxiliary Cooling System (RVACS) implementing the natural circulation of air flowing upwards over the guard vessel is used to cool the reactor, in the case of loss of normal heat removal through the IRHXs. The RVACS is always in operation. The gap between the vessels is filled with liquid lead-bismuth eutectic (LBE) to enhance the heat removal by air by significantly reducing the thermal

  16. Carbon Dioxide Direct Cycle Modular Reactors for Decentralized Energy Sources

    International Nuclear Information System (INIS)

    Carbon dioxide is achievable higher cycle efficiency than helium in a direct gas turbine cycle system due to the real gas effect or inter molecular attraction force in the compression process especially in the vicinity of the critical points. Analyzing the cycle thermal performance of full, partial and non condensation cycles, the cycle efficiency is highest in the partial condensation cycle. A fast reactor employing the partial condensation cycle is expected to be a potential alternative option to LMFRs, allowing higher cycle efficiency than LMFRs at the same core outlet temperature, and excluding the problems related to safety, cost and maintenance. A thermal reactor employing the partial condensation cycle provides higher cycle efficiency (48%) at the moderate core outlet temperature of 650? than that of PBMR (46%) operated at 900? (author)

  17. Microscopical examination of carbon deposits formed in the Windscale advanced gas cooled reactor

    International Nuclear Information System (INIS)

    Methods are described of sampling and examining carbon deposits on fuel cladding in the Windscale advanced gas-cooled reactor. Deposition is observed on fuel cladding in both the reactor core and experimental loops in carbon dioxide coolants containing various amounts of carbon monoxide and methane. Deposit distribution over the cladding surface indicated that nucleation is dependent on local surface conditions. Microscopical examination showed that deposit thickness increases by carbon filament growth into the coolant gas stream and that the process can be markedly influenced by metallic impurities. There is evidence that nickel can play a particularly significant role in deposition in loop experiments but similar effects have not been observed in the reactor core. (author)

  18. Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor

    Science.gov (United States)

    Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

    2012-11-13

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  19. Self-Cleaning Boudouard Reactor for Full Oxygen Recovery from Carbon Dioxide

    Science.gov (United States)

    Hintze, Paul E.; Muscatello, Anthony C.; Gibson, Tracy L.; Captain, James G.; Lunn, Griffin M.; Devor, Robert W.; Bauer, Brint; Parks, Steve

    2016-01-01

    Oxygen recovery from respiratory carbon dioxide is an important aspect of human spaceflight. Methods exist to sequester the carbon dioxide, but production of oxygen needs further development. The current International Space Station Carbon Dioxide Reduction System (CRS) uses the Sabatier reaction to produce water (and ultimately breathing air). Oxygen recovery is limited to 50% because half of the hydrogen used in the Sabatier reactor is lost as methane which is vented overboard. The Bosch reaction, which converts carbon dioxide to oxygen and solid carbon, is capable of recovering all the oxygen from carbon dioxide, and it is a promising alternative to the Sabatier reaction. However, the last reaction in the cycle, the Boudouard reaction, produces solid carbon, and the resulting carbon buildup eventually fouls the catalyst, reducing reactor life and increasing consumables. To minimize this fouling and increase efficiency, a number of self-cleaning catalyst designs have been created. This paper will describe recent results evaluating one of the designs.

  20. Transcritical carbon dioxide small commercial cooling applications analysis

    Energy Technology Data Exchange (ETDEWEB)

    Cecchinato, Luca; Corradi, Marco [Dipartimento di Fisica Tecnica, Universita di Padova, via Venezia 1, I-35131 Padova (Italy)

    2011-01-15

    This paper presents a project to develop an R744 commercial single door bottle cooler that is cost competitive and matches the performance of typical cost optimised R404A and R134a systems. Compressors with different displacement and efficiency values are evaluated for refrigerating systems with fin and tube and steel wire-on-tube gas coolers. Capillary tubes are tested. A methodology to properly sizing them and to optimize the combination of capillary tube and refrigerant charge is developed. The problem of optimal cycle high pressure is addressed and Liao's approximated solution questioned. Tests demonstrate that the CO{sub 2} energy consumption systems are higher than traditional ones especially at ambient temperatures above 25 C. Carbon dioxide appears to be a feasible option for stand-alone refrigerating equipment in terms of total equivalent warming impact (TEWI) compared to HFC refrigerants with actual single stage R744 compressor technology, only if the refrigeration units operate at medium-low gas cooler inlet temperature. (author)

  1. Pre-Combustion Carbon Dioxide Capture by a New Dual Phase Ceramic-Carbonate Membrane Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Jerry

    2014-09-30

    This report documents synthesis, characterization and carbon dioxide permeation and separation properties of a new group of ceramic-carbonate dual-phase membranes and results of a laboratory study on their application for water gas shift reaction with carbon dioxide separation. A series of ceramic-carbonate dual phase membranes with various oxygen ionic or mixed ionic and electronic conducting metal oxide materials in disk, tube, symmetric, and asymmetric geometric configurations was developed. These membranes, with the thickness of 10 μm to 1.5 mm, show CO2 permeance in the range of 0.5-5×10-7 mol·m-2·s-1·Pa-1 in 500-900oC and measured CO2/N2 selectivity of up to 3000. CO2 permeation mechanism and factors that affect CO2 permeation through the dual-phase membranes have been identified. A reliable CO2 permeation model was developed. A robust method was established for the optimization of the microstructures of ceramic-carbonate membranes. The ceramic-carbonate membranes exhibit high stability for high temperature CO2 separations and water gas shift reaction. Water gas shift reaction in the dual-phase membrane reactors was studied by both modeling and experiments. It is found that high temperature syngas water gas shift reaction in tubular ceramic-carbonate dual phase membrane reactor is feasible even without catalyst. The membrane reactor exhibits good CO2 permeation flux, high thermal and chemical stability and high thermal shock resistance. Reaction and separation conditions in the membrane reactor to produce hydrogen of 93% purity and CO2 stream of >95% purity, with 90% CO2 capture have been identified. Integration of the ceramic-carbonate dual-phase membrane reactor with IGCC process for carbon dioxide capture was analyzed. A methodology was developed to identify optimum operation conditions for a membrane tube of given dimensions that would treat coal syngas with targeted performance. The calculation results show that the dual-phase membrane reactor could

  2. Self-Cleaning Boudouard Reactor for Full Oxygen Recovery from Carbon Dioxide

    Science.gov (United States)

    Coutts, Janelle; Hintze, Paul E.; Muscatello, Anthony C.; Gibson, Tracy L.; Captain, James G.; Lunn, Griffin M.; Devor, Robert W.; Bauer, Brint; Parks, Steve

    2016-01-01

    Oxygen recovery from respiratory carbon dioxide is an important aspect of human spaceflight. Methods exist to sequester the carbon dioxide, but production of oxygen needs further development. The current International Space Station Carbon Dioxide Reduction System (CRS) uses the Sabatier reaction to produce water (and ultimately breathing air). Oxygen recovery is limited to 50 because half of the hydrogen used in the Sabatier reactor is lost as methane, which is vented overboard. The Bosch reaction, which converts carbon dioxide to oxygen and solid carbon is capable of recovering all the oxygen from carbon dioxide, and is the only real alternative to the Sabatier reaction. However, the last reaction in the cycle, the Boudouard reaction, produces solid carbon and the resulting carbon buildup will eventually foul the nickel or iron catalyst, reducing reactor life and increasing consumables. To minimize this fouling and increase efficiency, a number of self-cleaning catalyst designs have been created. This paper will describe recent results evaluating one of the designs.

  3. Technology of steam generators for gas-cooled reactors. Proceedings of a specialists' meeting

    International Nuclear Information System (INIS)

    The activity of the IAEA in the field of the technology of gas-cooled reactors was formalized by formation of an International Working Group on Gas-Cooled Reactors (IWGCR). The gas cooled reactor program considered by the IWGCR includes carbon-dioxide-cooled thermal reactors, helium cooled thermal high temperature reactors for power generation and for process heat applications and gas-cooled fast breeder reactors. This report covers the papers dealing with operating experience, steam generators for next generation of gas-cooled reactors, material development and corrosion problems, and thermohydraulics

  4. Energy analysis and carbon dioxide emission of Tokamak fusion power reactors

    International Nuclear Information System (INIS)

    Energy gain and carbon dioxide (CO2) emission of tokamak fusion power reactors are evaluated in this study compared with other reactor types, structural materials, and other Japanese energy sources currently in use. The reactors treated in this study are (1) a conventional physics performance international thermonuclear experimental reactor (ITER), like a reactor based upon the ITER engineering design activity (ITER-EDA), (2) a RS (reversed shear) reactor using the reversed shear safety-factor/plasma current profile, and (3) a ST (spherical torus) reactor based upon the final version of the advanced reactor innovative engineering study ST (ARIES-ST). The input energy and CO2 emission from these reactors are calculated by multiplying the weight or cost of the fusion reactor components by the energy intensity and/or with the CO2 intensity data, which are updated as often as possible. The ITER cost estimation is estimated based on the component unit costs. The following results were obtained: (1) The RS and the ST reactor can double the energy gain and reduce CO2 emission by one-half compared with the ITER-like reactor. (2) Silicon carbide (SiC) used as the structural material of inner vessel components is best for energy gain and CO2 emission reduction. (3) The ITER-like reactor is slightly superior to a photovoltaic (PV) with regard to CO2 emission. (4) The energy gain and CO2 emission intensity of the RS reactor and the ST reactor are as excellent as those of a fission reactor and a hydro-powered generator. These results indicate that a tokamak fusion power reactor can be one of the most effective power-generating technologies both in high-energy payback gains and reduction of CO2

  5. Super-critical carbon dioxide based brayton cycle for Indian High Temperature Reactors

    International Nuclear Information System (INIS)

    The most effective way to improve economic competitiveness of NPPs is to enhance its efficiency which has remained static at around 33% since the first commercial LWR came into operation. New generation reactor designs including the six Gen-IV reactor concepts aim to increase the NPPs efficiency to almost 50%. This is proposed to be achieved by high temperature designs using Brayton cycle based power conversion systems. World over, Super-critical Carbon dioxide Brayton Cycle (SCBC) for power generation is an important R and D area. High efficiency SCBC power conversion system is proposed as power conversion system for Indian Molten Salt Breeder Reactor (IMSBR) and Innovative High Temperature Reactor (IHTR). This section provides the details regarding design and development of SCBC for these reactors. (author)

  6. Features of supercritical carbon dioxide Brayton cycle coupled with reactor

    International Nuclear Information System (INIS)

    In order to obtain acceptable cycle efficiency, current helium gas turbine power cycle technology needs high cycle temperature which means that the cycle needs high core-out temperature. The technology has high requirements on reactor structure and fuel elements materials, and also on turbine manufacture. While utilizing CO2 as cycle working fluid, it can guarantee to lower the cycle temperature and turbo machine Janume but achieve the same cycle efficiency, so as to enhance the safety and economy of reactor. According to the laws of thermodynamics, a calculation model of supercritical CO2 power cycle was established to analyze the feature, and the decisive parameters of the cycle and also investigate the effect of each parameter on the cycle efficiency in detail were obtained. The results show that supercritical CO2 power cycle can achieve quite satisfied efficiency at a lower cycle highest temperature than helium cycle, and CO2 is a promising working fluid. (authors)

  7. Compact and Lightweight Sabatier Reactor for Carbon Dioxide Reduction

    Science.gov (United States)

    Junaedi, Christian; Hawley, Kyle; Walsh, Dennis; Roychoudhury, Subir; Abney, Morgan B.; Perry, Jay L.

    2011-01-01

    The utilization of CO2 to produce life support consumables, such as O2 and H2O, via the Sabatier reaction is an important aspect of NASA s cabin Atmosphere Revitalization System and In-Situ Resource Utilization architectures for both low-earth orbit and long-term manned space missions. In the current International Space Station (ISS) and other low orbit missions, metabolically-generated CO2 is removed from the cabin air and vented into space, resulting in a net loss of O2. This requires a continuous resupply of O2 via water electrolysis, and thus highlights the need for large water storage capacity. For long-duration space missions, the amount of life support consumables is limited and resupply options are practically nonexistent, thus atmosphere resource management and recycle becomes crucial to significantly reduce necessary O2 and H2O storage. Additionally, the potential use of the Martian CO2-rich atmosphere and Lunar regolith to generate life support consumables and propellant fuels is of interest to NASA. Precision Combustion, Inc. (PCI) has developed a compact, lightweight Microlith(Registered TradeMark)-based Sabatier (CO2 methanation) reactor which demonstrates the capability of achieving high CO2 conversion and near 100% CH4 selectivity at space velocities of 30,000-60,000 hr-1. The combination of the Microlith(Registered TradeMark) substrates and durable, novel catalyst coating permitted efficient Sabatier reactor operation that favors high reactant conversion, high selectivity, and long-term durability. This paper presents the reactor development and performance results at various operating conditions. Additionally, results from 100-hr durability tests and mechanical vibration tests are discussed.

  8. HBGS (hydrate based gas separation) process for carbon dioxide capture employing an unstirred reactor with cyclopentane

    International Nuclear Information System (INIS)

    The effect of CP (cyclopentane) as a promoter/additive, in the HBGS (hydrate based gas separation) process for pre-combustion gas mixture was investigated by employing an unstirred reactor configuration. Gas uptake measurements were performed at two different temperatures (275.7 K and 285.7 K) and at an experimental pressure of 6.0 MPa to determine the kinetics of hydrate formation. Experiments were conducted with three different volumes (7.5, 15 and 22 ml) of CP and based on induction time and the rate of hydrate growth, 15 ml of CP was determined to be the optimal volume for carbon dioxide capture at 6.0 MPa and 275.7 K. In addition, the effect of a kinetic promoter, SDS (sodium dodecyl sulfate), was investigated. Surprisingly, no improvement in kinetic performance was observed at 6.0 MPa and 275.7 K in the presence of SDS and CP. From the study, it was found that at the optimal 15 ml CP (CP layer thickness of 1.8 mm), the average composition of carbon dioxide in the hydrate phase was 90.36 mol% with a separation factor of 17.82. Furthermore, the unstirred reactor also yielded better kinetic performance over the stirred tank reactor with the unstirred reactor having a 2.28 times higher average gas uptake. - Highlights: • HBGS process for pre-combustion capture in an unstirred reactor is presented. • Effect of cyclopentane as a thermodynamic promoter and sodium dodecyl sulfate as a kinetic promoter is investigated. • Cyclopentane significantly reduces the operating conditions and improves the kinetics for the HBGS process. • In this study, kinetic performance in an unstirred reactor is better than stirred tank reactor

  9. Carbon Dioxide reduction by non-equilibrium electrocatalysis plasma reactor

    Science.gov (United States)

    Amouroux, J.; Cavadias, S.; Doubla, A.

    2011-03-01

    A possible strategy to increase the added value from CCS, is to consider it as a raw material for the production of liquid fuels, or chemical products. The most studied ways related to CO2 reduction, with formation of molecules such as CH3OH or syngas, is the reaction with H2 (exothermic reaction needing catalytic activation), or CH4 (endothermic reaction taking place at high temperature) with the use of a catalyst. The synthesis of CH3OH is performed on Lewis acid type sites (default of electrons) Cu/Zn/Al2O3. However the products of the reaction i.e. the water and methanol molecules, are very polar, resulting in a very low desorption rate. So in this reaction the key step is water desorption (Lewis basis). The increase of temperature in order to increase this desorption rate, leads to a cracking and the deposition of carbon in the catalyst, limiting its lifetime. Plasma driven catalysis allows firstly, a vibrational activation of CO2, H2 or CH4 through electron-molecule collisions, making easier their dissociation at low temperature and secondly expels water from the catalyst sites by supplying electrons (electropolarisation). The results show an increase of the yield in CH3OH with plasma and catalyst, confirming the action of the plasma. However energy consumption remains relatively high.

  10. Carbon Dioxide reduction by non-equilibrium electrocatalysis plasma reactor

    International Nuclear Information System (INIS)

    A possible strategy to increase the added value from CCS, is to consider it as a raw material for the production of liquid fuels, or chemical products. The most studied ways related to CO2 reduction, with formation of molecules such as CH3OH or syngas, is the reaction with H2 (exothermic reaction needing catalytic activation), or CH4 (endothermic reaction taking place at high temperature) with the use of a catalyst. The synthesis of CH3OH is performed on Lewis acid type sites (default of electrons) Cu/Zn/Al2O3. However the products of the reaction i.e. the water and methanol molecules, are very polar, resulting in a very low desorption rate. So in this reaction the key step is water desorption (Lewis basis). The increase of temperature in order to increase this desorption rate, leads to a cracking and the deposition of carbon in the catalyst, limiting its lifetime. Plasma driven catalysis allows firstly, a vibrational activation of CO2, H2 or CH4 through electron-molecule collisions, making easier their dissociation at low temperature and secondly expels water from the catalyst sites by supplying electrons (electropolarisation). The results show an increase of the yield in CH3OH with plasma and catalyst, confirming the action of the plasma. However energy consumption remains relatively high.

  11. HYDRODYNAMIC BEHAVIOR AND ABSORPTION OF CARBON DIOXIDE BY CHEMICAL REACTION WITH GLUCOSAMINE IN AN AIR-LIFT REACTOR

    OpenAIRE

    Alicia García-Abuín; Diego Gómez-Díaz; Navaza, José M.; Isabel Vidal-Tato

    2010-01-01

    In this work, it has been studied the behavior of aqueous solutions of glucosamine used as absorbent phase in the carbon dioxide capture process using an air-lift reactor. The experimental results indicate that the reagent (glucosamine) shows a similar behavior related to absorption rate, than previously observed for aqueous solutions of other amines widely used for carbon dioxide capture. The value of mass transfer rate has been determined, as well as the effect of these operation conditions...

  12. Wet process of external gelation of uranium for preparation of uranium dioxide kernel of high temperature gas-cooled reactors

    International Nuclear Information System (INIS)

    In order to prepare the dense uranium dioxide (UO2) kernel for high temperature gas-cooled reactors (HTGR) fuel, the conventional sol-gel processes are optimized and modified. The wet process of modified extemal gelation of uranium (EGU) is introduced, which includes the dissolution of U3O8, i.e. the preparation of acid-deficiency uranyl nitrate, preparation of broth solution, casting and gelation of broth solution and aging, washing and drying of the gelled spheres, and etc. The mechanism of wet process of EGU is also discussed. With the optimized wet process, the ammonium diuranate (ADU) microspheres with good sphericity, uniform diameter and perfect porous structure are prepared. After the subsequent treatments of dry processes such as calcination, reduction and sintering, the eligible dense UO2 kernels for HTGR fuel are manufactured. (authors)

  13. Carbon dioxide and methane exchange at a cool-temperate freshwater marsh

    International Nuclear Information System (INIS)

    Freshwater marshes have been shown to be strong sinks for carbon dioxide (CO2) on an annual basis relative to other wetland types; however it is likely that these ecosystems are also strong emitters of methane (CH4), reducing their carbon (C) sequestration potential. Multiyear C balances in these ecosystems are necessary therefore to determine their contribution to the global C cycle. Despite this, the number of multiyear studies in marshes is few, with, to the best of our knowledge, only one other Northern marsh C balance reported. This study presents five years of eddy covariance flux measurements of CO2, and four years of warm-season chamber measurements of CH4 at a cool-temperate Typha angustifolia marsh. Annual average cumulative net ecosystem exchange of CO2 (NEE) at the marsh was −224 ± 54 g C m−2 yr−1 (±SD) over the five-year period, ranging from −126 to −284 g C m−2 yr−1. Enhancement of the ecosystem respiration during warmer spring, autumn and winter periods appeared the strongest determinant of annual NEE totals. Warm season fluxes of CH4 from the Typha vegetation (avg. 1.0 ± 1.2 g C m−2 d−1) were significantly higher than fluxes from the water surface (0.5 ± 0.4 g C m−2 d−1) and unvegetated mats (0.2 ± 0.2 g C m−2 d−1). Air temperature was a primary driver of all CH4 fluxes, while water table was not a significant correlate as water levels were always at or above the vegetative mat surfaces. Weighting by the surface cover proportion of water and vegetation yielded a net ecosystem CH4 emission of 127 ± 19 g C m−2 yr−1. Combining CO2 and CH4, the annual C sink at the Mer Bleue marsh was reduced to −97 ± 57 g C m−2 yr−1, illustrating the importance of accounting for CH4 when generating marsh C budgets. (letter)

  14. Supercritical carbon dioxide Brayton power conversion cycle for battery optimized reactor integral system

    International Nuclear Information System (INIS)

    Supercritical carbon dioxide (SCO2) promises a high power conversion efficiency of the recompression Brayton cycle due to its excellent compressibility reducing the compression work at the bottom of the cycle and to a higher density than helium or steam decreasing the component size. The SCO2 Brayton cycle efficiency as high as 45% furnishes small sized nuclear reactors with economical benefits on the plant construction and maintenance. A 23 MWth lead-cooled Battery Optimized Reactor Integral System (BORIS) is being developed as an ultra-long-life, versatile-purpose, fast-spectrum reactor. BORIS is coupled to the SCO2 Brayton cycle needing less room relative to the Rankine steam cycle because of its smaller components. The SCO2 Brayton cycle of BORIS consists of a 16 MW turbine, a 32 MW high temperature recuperator, a 14 MW low temperature recuperator, an 11 MW precooler and 2 and 2.8 MW compressors. Entering six heat exchangers between primary and secondary system at 19.9 MPa and 663 K, the SCO2 leaves the heat exchangers at 19.9 MPa and 823 K. The promising secondary system efficiency of 45% was calculated by a theoretical method in which the main parameters include pressure, temperature, heater power, the turbine's, recuperators' and compressors' efficiencies, and the flow split ratio of SCO2 going out from the low temperature recuperator. Development of Modular Optimized Brayton Integral System (MOBIS) is being devised as the SCO2 Brayton cycle energy conversion cycle for BORIS. MOBIS consists of Loop Operating Brayton Optimization Study (LOBOS) for experimental Brayton cycle loop and Gas Advanced Turbine Operation Study (GATOS) for the SCO2 turbine. Liquid-metal Energy Exchanger Integral System (LEXIS) serves to couple BORIS and MOBIS. LEXIS comprises Physical Aspect Thermal Operation System (PATOS) for SCO2 thermal hydraulic characteristics, Shell-and-tube Overall Layout Optimization Study (SOLOS) for shell-and-tube heat exchanger, Printed-circuit Overall

  15. Design Construction and Operation of a Supercritical Carbon Dioxide (sCO2) Loop for Investigation of Dry Cooling and Natural Circulation Potential for Use in Advanced Small Modular Reactors Utilizing sCO2 Power Conversion Cycles.

    Energy Technology Data Exchange (ETDEWEB)

    Middleton, Bobby D. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rodriguez, Salvador B. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Carlson, Matthew David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-11-01

    This report outlines the work completed for a Laboratory Directed Research and Development project at Sandia National Laboratories from October 2012 through September 2015. An experimental supercritical carbon dioxide (sCO 2 ) loop was designed, built, and o perated. The experimental work demonstrated that sCO 2 can be uti lized as the working fluid in an air - cooled, natural circulation configuration to transfer heat from a source to the ultimate heat sink, which is the surrounding ambient environment in most ca ses. The loop was also operated in an induction - heated, water - cooled configuration that allows for measurements of physical parameters that are difficult to isolate in the air - cooled configuration. Analysis included the development of two computational flu id dynamics models. Future work is anticipated to answer questions that were not covered in this project.

  16. Calcium oxide/carbon dioxide reactivity in a packed bed reactor of a chemical heat pump for high-temperature gas reactors

    International Nuclear Information System (INIS)

    The thermal performance of a chemical heat pump that uses a calcium oxide/carbon dioxide reaction system was discussed as a heat storage system for utilizing heat output from high temperature gas reactors (HTGR). Calcium oxide/carbon dioxide reactivity for the heat pump was measured using a packed bed reactor containing 1.0 kg of reactant. The reactor was capable of storing heat at 900 deg. C by decarbonation of calcium carbonate and generating up to 997 deg. C by carbonation of calcium oxide. The amount of stored heat in the reactor was 800-900 kJ kg-1. The output temperature of the reactor could be controlled by regulating the carbonation pressure. The thermal storage performance of the reactor was superior to that of conventional sensible heat storage systems. A heat pump using this CaO/CO2 reactor is expected to contribute to thermal load leveling and to realize highly efficient utilization of HTGR output due to the high heat storage density and high-quality temperature output of the heat pump

  17. Gas-cooled reactors

    International Nuclear Information System (INIS)

    The present study is the second part of a general survey of Gas Cooled Reactors (GCRs). In this part, the course of development, overall performance and present development status of High Temperature Gas Cooled Reactors (HTCRs) and advances of HTGR systems are reviewed. (author)

  18. Supercritical Carbon Dioxide Brayton Power Conversion Cycle Design for Optimized Battery-Type Integral Reactor System

    International Nuclear Information System (INIS)

    Supercritical carbon dioxide (SCO2) promises a high power conversion efficiency of the recompression Brayton cycle due to its excellent compressibility reducing the compression work at the bottom of the cycle and to a higher density than helium or steam decreasing the component size. Therefore, the high SCO2 Brayton cycle efficiency as high as 45 % furnishes small sized nuclear reactors with economical benefits on the plant construction and maintenance. A 23 MWth BORIS (Battery Optimized Reactor Integral System) is being developed as a multipurpose reactor. BORIS, an integral-type optimized fast reactor with an ultra long life core, is coupled to the SCO2 Brayton cycle needing less room relative to the Rankine steam cycle because of its smaller components. The SCO2 Brayton cycle of BORIS consists of a 16 MW turbine, a 32 MW high temperature recuperator, a 14 MW low temperature recuperator, an 11 MW pre-cooler and 2 and 2.8 MW compressors. Entering six heat exchangers between primary and secondary system at 19.9 MPa and 663 K, the SCO2 leaves the heat exchangers at 19.9 MPa and 823 K. The promising secondary system efficiency of 45 % was calculated by a theoretical method in which the main parameters include pressure, temperature, heater power, the turbine's, recuperators' and compressors' efficiencies, and the flow split ratio of SCO2 going out from the low temperature recuperator. Test loop SOLOS (Shell-and-tube Overall Layout Optimization Study) is utilized to develop advanced techniques needed to adopt the shell-and-tube type heat exchanger in the secondary loop of BORIS by studying the SCO2 behavior from both thermal and hydrodynamic points of view. Concurrently, a computational fluid dynamics (CFD) code analysis is being conducted to develop an optimal analytical method of the SCO2 turbine efficiency having the parameters of flow characteristics of SCO2 passing through buckets of the turbine. These simultaneous experimental and analytical methods for designing

  19. Water cooled nuclear reactor

    International Nuclear Information System (INIS)

    The description is given of a water cooled nuclear reactor comprising a core, cooling water that rises through the core, vertical guide tubes located inside the core and control rods vertically mobile in the guide tubes. In this reactor the cooling water is divided into a first part introduced at the bottom end of the core and rising through it and a second part introduced at the top end of the guide tubes so as to drop in them

  20. An investigation of heat exchanger fouling in dust suspension cooling systems using graphite powder and carbon dioxide gas

    International Nuclear Information System (INIS)

    Some experiments have been performed to study the fouling of heat exchanger surfaces where heat is being transferred from a heated fluid to a cooled surface. The fluid studied was a suspension of 4-5 microns mean diameter graphite powder in carbon dioxide gas at near atmospheric pressures. The solids loading range covered was from 5 to 30 lb. graphite/lb. carbon dioxide, and gas Reynolds numbers from 6000 to 16000. Temperature gradients across the cooler of from 20 to 120 deg. C were obtained. The heat transfer ratio is correlated to show the dependence upon the solids loading ratio of the suspension, the gas Reynolds number and the temperature gradient across the cooler. The results have demonstrated that stringent precautions are necessary to ensure complete dryness of the graphite powder and the loop flow surfaces before any quantitative fouling data can be obtained, as the presence of entrained moisture will accelerate the deposition of material on the cold walls of the heat exchanger and can result in plugging. The heat transfer coefficient showed no obvious dependency upon either the gas Reynolds number or the temperature gradient across the cooler over the range investigated. The measured heat transfer coefficient was considerably lower than that obtained when the heat is transferred from a hot wall to a cooler fluid. At a solids loading of 30 lb, graphite/lb. carbon dioxide, the heat transfer coefficient was only 50% of that for heat transfer from a heated wall. At solids loadings below 7 lb/lb., the heat transfer was less than that for a gas alone. (author)

  1. Optimization of carbon dioxide supply in raceway reactors: Influence of carbon dioxide molar fraction and gas flow rate.

    Science.gov (United States)

    Duarte-Santos, T; Mendoza-Martín, J L; Acién Fernández, F G; Molina, E; Vieira-Costa, J A; Heaven, S

    2016-07-01

    Influence of CO2 composition and gas flow rate to control pH in a pilot-scale raceway producing Scenedesmus sp. was studied. Light and temperature determined the biomass productivity whereas neither the CO2 molar fraction nor the gas flow rate used influenced it; because pH was always controlled and carbon limitation did not take place. The CO2 molar fraction and the gas flow rate influenced carbon loss in the system. At low CO2 molar fraction (2-6%) or gas flow rate (75-100l·min(-1)) the carbon efficiency in the sump was higher than 95%, 85% of the injected carbon being transformed into biomass. Conversely, at high CO2 molar fraction (14%) or gas flow rate (150l·min(-1)) the carbon efficiency in the sump was lower than 67%, 32% of the carbon being fixed as biomass. Analysis here reported allows the pH control to be optimized and production costs to be reduced by optimizing CO2 efficiency. PMID:27085148

  2. The carbon dioxide cycle

    Science.gov (United States)

    James, P.B.; Hansen, G.B.; Titus, T.N.

    2005-01-01

    The seasonal CO2 cycle on Mars refers to the exchange of carbon dioxide between dry ice in the seasonal polar caps and gaseous carbon dioxide in the atmosphere. This review focuses on breakthroughs in understanding the process involving seasonal carbon dioxide phase changes that have occurred as a result of observations by Mars Global Surveyor. ?? 2004 COSPAR. Published by Elsevier Ltd. All rights reserved.

  3. High-temperature gas-cooled reactors (HTGRs) and their potential for non-electric application

    International Nuclear Information System (INIS)

    This paper presents High Temperature Gas cooled Reactors (HTGR). It also enumerates the potentials for non electrical applications such as delivering hot water, generating steam, producing hydrogen and carbon monoxide via conversion of natural gas. Then the author presents the contribution of HTGRs to reduce carbon dioxide emissions. (TEC). 4 figs., 1 ref

  4. Carbon Dioxide Removal via Passive Thermal Approaches

    Science.gov (United States)

    Lawson, Michael; Hanford, Anthony; Conger, Bruce; Anderson, Molly

    2011-01-01

    A paper describes a regenerable approach to separate carbon dioxide from other cabin gases by means of cooling until the carbon dioxide forms carbon dioxide ice on the walls of the physical device. Currently, NASA space vehicles remove carbon dioxide by reaction with lithium hydroxide (LiOH) or by adsorption to an amine, a zeolite, or other sorbent. Use of lithium hydroxide, though reliable and well-understood, requires significant mass for all but the shortest missions in the form of lithium hydroxide pellets, because the reaction of carbon dioxide with lithium hydroxide is essentially irreversible. This approach is regenerable, uses less power than other historical approaches, and it is almost entirely passive, so it is more economical to operate and potentially maintenance- free for long-duration missions. In carbon dioxide removal mode, this approach passes a bone-dry stream of crew cabin atmospheric gas through a metal channel in thermal contact with a radiator. The radiator is pointed to reject thermal loads only to space. Within the channel, the working stream is cooled to the sublimation temperature of carbon dioxide at the prevailing cabin pressure, leading to formation of carbon dioxide ice on the channel walls. After a prescribed time or accumulation of carbon dioxide ice, for regeneration of the device, the channel is closed off from the crew cabin and the carbon dioxide ice is sublimed and either vented to the environment or accumulated for recovery of oxygen in a fully regenerative life support system.

  5. Carbon Dioxide Fountain

    Science.gov (United States)

    Kang, Seong-Joo; Ryu, Eun-Hee

    2007-01-01

    This article presents the development of a carbon dioxide fountain. The advantages of the carbon dioxide fountain are that it is odorless and uses consumer chemicals. This experiment also is a nice visual experiment that allows students to see evidence of a gaseous reagent being consumed when a pressure sensor is available. (Contains 3 figures.)…

  6. SEPARATION OF HYDROGEN AND CARBON DIOXIDE USING A NOVEL MEMBRANE REACTOR IN ADVANCED FOSSIL ENERGY CONVERSION PROCESS; F

    International Nuclear Information System (INIS)

    Inorganic membrane reactors offer the possibility of combining reaction and separation in a single operation at high temperatures to overcome the equilibrium limitations experienced in conventional reactor configurations. Such attractive features can be advantageously utilized in a number of potential commercial opportunities, which include dehydrogenation, hydrogenation, oxidative dehydrogenation, oxidation and catalytic decomposition reactions. However, to be cost effective, significant technological advances and improvements will be required to solve several key issues which include: (a) permselective thin solid film, (b) thermal, chemical and mechanical stability of the film at high temperatures, and (c) reactor engineering and module development in relation to the development of effective seals at high temperature and high pressure. In this project, we are working on the development and application of palladium and palladium-silver alloy thin-film composite membranes in membrane reactor-separator configuration for simultaneous production and separation of hydrogen and carbon dioxide at high temperature. From our research on Pd-composite membrane, we have demonstrated that the new membrane has significantly higher hydrogen flux with very high perm-selectivity than any of the membranes commercially available. The steam reforming of methane by equilibrium shift in Pd-composite membrane reactor is being studied to demonstrate the potential application this new development. To have better understanding of the membrane reactor, during this reporting period, we developed a two-dimensional pseudo-homogeneous reactor model for steam reforming of methane by equilibrium shift in a tubular membrane reactor. In numerical solution of the reactor model equations, numerical difficulties were encountered and we seeking alternative solution techniques to overcome the problem

  7. Mathematical Modelling of Catalytic Fixed-Bed Reactor for Carbon Dioxide Reforming of Methane over Rh/Al2O3 Catalyst

    OpenAIRE

    Nor Aishah Saidina Amin; Istadi Istadi; New Pei Yee

    2010-01-01

    A one-dimensional mathematical model was developed to simulate the performance of catalytic fixed bed reactor for carbon dioxide reforming of methane over Rh/Al2O3 catalyst at atmospheric pressure. The reactions involved in the system are carbon dioxide reforming of methane (CORM) and reverse water gas shift reaction (RWGS). The profiles of CH4 and CO2 conversions, CO and H2 yields, molar flow rate and mole raction of all species as well as reactor temperature along the axial bed...

  8. Experimental performance evaluation for a carbon dioxide light commercial cooling application under transcritical and subcritical conditions

    International Nuclear Information System (INIS)

    CO2 is one of the most interesting non toxic, nor flammable, low GWP natural fluid to be used in applications with a large direct contribution to global warming, such as vending machines. In this paper the results of an experimental investigation on a small capacity, air-forced refrigerating plant working with CO2 are presented. The air inlet temperatures at gas cooler and evaporator were varied between 16 °C and 31 °C and between −25 °C and 25 °C, respectively, to cover the range of temperatures under conditions typical of commercial refrigeration, during quasi-steady operation. The thermodynamic analysis of the system performance was carried on varying independently the pressure at the gas cooler, by overfeeding the liquid receiver to point out the effect of refrigerant charge. The results allow to describe the performance of the system in a map varying the boundary conditions; at the same time the corresponding variations of the thermodynamic cycle, the COP and the mass flow rate are reported. -- Highlights: ► A light commercial refrigerating plant working with CO2 was tested in order to evaluate its performance. ► 71 experimental points were collected varying the flow rates, the temperatures of air sources and the refrigerant charge. ► Mass flow rate, cooling capacity, electrical power and COP were evaluated as a function of pressures and superheating. ► The segregate influence of each operating parameter on each performance indicator was calculated. ► A map of plant performance as a function of air source temperatures is reported

  9. THERAPEUTIC OF SKIN AGING WITH CARBON DIOXIDE LASER SKIN RESURFACING AND COMBINATION WITH AIR COOLING

    Directory of Open Access Journals (Sweden)

    NKA Maya Damayanti

    2013-12-01

    Full Text Available Normal 0 false false false EN-US X-NONE X-NONE MicrosoftInternetExplorer4 So far, a lot of people who want their face skin always looks young though age continued to grow. It cannot be denied that aging will occur in everyone although some faster or later occur. Various ways were developed by scientists to fix this issue. Laser Skin Resurfacing (LSR technique to tighten facial skin is a procedure that is popular among the public and the practice of medicine. CO2 LSR technique is still a gold standard was used. Pain during surgery can be reduced when this technique was combined with air cooling. In addition, the adverse effects of post-operative might be tolerated.   /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0in 5.4pt 0in 5.4pt; mso-para-margin:0in; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New Roman"; mso-bidi-theme-font:minor-bidi;}

  10. Carbon Dioxide Collection and Pressurization Technology Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Reactive Innovations, LLC, proposes a Phase I SBIR program to develop a compact and lightweight electrochemical reactor to separate and pressurize carbon dioxide...

  11. Dissociation of carbon dioxide using a microhollow cathode discharge plasma reactor: effects of applied voltage, flow rate and concentration

    International Nuclear Information System (INIS)

    This paper reports an experimental study on dissociating carbon dioxide (CO2) using a microhollow cathode discharge (MHCD) plasma reactor operated at 1 atm. The MHCD plasma reactors can be a promising technology for dissociating gases, including CO2, as they do not require catalysts, they operate at around room temperature, and can be inexpensively built and operated. In this study, CO2 balanced with the carrier gas argon (Ar) was fed through the MHCD reactor, and parametric experiments were conducted to investigate the effects of applied voltage, flow rate, and CO2 mole fraction in the influent on the composition of the products, energy conversion efficiency, and yield. Within the investigated parameter ranges, the maximum energy conversion efficiency of 14% was achieved when the specific energy input was 1.1 eV mol−1, whereas the maximum CO yield of 10.5% was achieved when the specific energy input was 4 eV mol−1. The results also showed that diluting CO2 with Ar increased the yield at an expense of a decrease in energy conversion efficiency. The results of this study provide insights for operating MHCD reactors for efficient gas dissociation at atmospheric pressure. (paper)

  12. Mathematical Modelling of Catalytic Fixed-Bed Reactor for Carbon Dioxide Reforming of Methane over Rh/Al2O3 Catalyst

    Directory of Open Access Journals (Sweden)

    Nor Aishah Saidina Amin

    2010-10-01

    Full Text Available A one-dimensional mathematical model was developed to simulate the performance of catalytic fixed bed reactor for carbon dioxide reforming of methane over Rh/Al2O3 catalyst at atmospheric pressure. The reactions involved in the system are carbon dioxide reforming of methane (CORM and reverse water gas shift reaction (RWGS. The profiles of CH4 and CO2 conversions, CO and H2 yields, molar flow rate and mole raction of all species as well as reactor temperature along the axial bed of catalyst were simulated. In addition, the effects of different reactor temperature on the reactor performance were also studied. The models can also be applied to analyze the performances of lab-scale micro reactor as well as pilot-plant scale reactor with certain modifications and model verification with experimental data. © 2008 BCREC UNDIP. All rights reserved.[Received: 20 August 2008; Accepted: 25 September 2008][How to Cite: N.A.S. Amin, I. Istadi, N.P. Yee. (2008. Mathematical Modelling of Catalytic Fixed-Bed Reactor for Carbon Dioxide Reforming of Methane over Rh/Al2O3 Catalyst. Bulletin of Chemical Reaction Engineering and Catalysis, 3 (1-3: 21-29.  doi:10.9767/bcrec.3.1-3.7120.21-29][How to Link/DOI: http://dx.doi.org/10.9767/bcrec.3.1-3.7120.21-29 || or local: http://ejournal.undip.ac.id/index.php/bcrec/article/view/7120

  13. Water cooled nuclear reactor

    International Nuclear Information System (INIS)

    In the reactor operating with supercritical pressure and temperature part of the water flowing through the moderator tubes is deflected at the outlet and mixed with a residual partial flow of the coolant fed into the core as well as passed along the fuel rods in opposite direction. By special guiding of the flow downward through the guide tubes of the control rods insertion of the control rods is simplified because of reduced frictional forces. By this means it is also achieved to design less critical the control rod cooling with respect to flow rate control and operating behavior in case of a scram. (orig.)

  14. Carbon dioxide recycling

    Science.gov (United States)

    The recycling of carbon dioxide to methanol and dimethyl ether is seen to offer a substantial route to renewable and environmentally carbon neutral fuels. One of the authors has championed the “Methanol Economy" in articles and a book. By recycling ambient CO2, the authors argue ...

  15. Nonlinear Modeling and Application of PI Control on Pre-cooling Session of a Carbon Dioxide Storage Tank at Normal Temperature and Pressure

    International Nuclear Information System (INIS)

    Storage tanks of Carbon dioxide (CO2) carriers utilized for the purpose of carbon capture and storage (CCS) into subsea strata have to undergo a pre-cooling session before beginning to load cryogenic liquid cargos in order to prevent physical and thermal deterioration of tanks which may result from cryogenic CO2 contacting tank walls directly. In this study we propose dynamic model to calculate the tank inflow of CO2 gas injected for precooling process and its dynamic simulation results under proportional-integral control algorithm. We selected two cases in which each of them had one controlled variable (CV) as either the tank pressure or the tank temperature and discussed the results of that decision-making on the pre-cooling process. As a result we demonstrated that the controlling instability arising from nonlinearity and singularity of the mathematical model could be avoided by choosing tank pressure as CV instead of tank temperature

  16. Carbon dioxide and climate

    International Nuclear Information System (INIS)

    Global climate change is a serious environmental concern, and the US has developed ''An Action Agenda'' to deal with it. At the heart of the US effort is the US Global Change Research Program (USGCRP), which has been developed by the Committee on Earth and Environmental Sciences (CEES) of the Federal Coordinating Council for Sciences, Engineering, and Technology (FCCSET). The USGCRP will provide the scientific basis for sound policy making on the climate-change issue. The DOE contribution to the USGCRP is the Carbon Dioxide Research Program, which now places particular emphasis on the rapid improvement of the capability to predict global and regional climate change. DOE's Carbon Dioxide Research Program has been addressing the carbon dioxide-climate change connection for more than twelve years and has provided a solid scientific foundation for the USGCRP. The expansion of the DOE effort reflects the increased attention that the Department has placed on the issue and is reflected in the National Energy Strategy (NES) that was released in 1991. This Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1991 and gives a brief overview of objectives, organization, and accomplishments. The Environmental Sciences Division of the Office of Health and Environmental Research, Office of Energy Research supports a Carbon Dioxide Research Program to determine the scientific linkage between the rise of greenhouse gases in the atmosphere, especially carbon dioxide, and climate and vegetation change. One facet is the Core CO2 Program, a pioneering program that DOE established more than 10 years ago to understand and predict the ways that fossil-fuel burning could affect atmospheric CO2 concentration, global climate, and the Earth's biosphere. Major research areas are: global carbon cycle; climate detection and models of climate change; vegetation research; resource analysis; and, information and integration

  17. Mathematical Modelling of Catalytic Fixed-Bed Reactor for Carbon Dioxide Reforming of Methane over Rh/Al2O3 Catalyst

    Directory of Open Access Journals (Sweden)

    New Pei Yee

    2008-04-01

    Full Text Available A one-dimensional mathematical model was developed to simulate the performance of catalytic fixed bedreactor for carbon dioxide reforming of methane over Rh/Al2O3 catalyst at atmospheric pressure. The reactionsinvolved in the system are carbon dioxide reforming of methane (CORM and reverse water gas shiftreaction (RWGS. The profiles of CH4 and CO2 conversions, CO and H2 yields, molar flow rate and molefraction of all species as well as reactor temperature along the axial bed of catalyst were simulated. In addition,the effects of different reactor temperature on the reactor performance were also studied. The modelscan also be applied to analyze the performances of lab-scale micro reactor as well as pilot-plant scale reactorwith certain modifications and model verification with experimental data. © 2008 BCREC UNDIP. All rights reserved.[Received: 20 August 2008; Accepted: 25 September 2008][How to Cite: N.A.S. Amin, I. Istadi, N.P. Yee. (2008. Mathematical Modelling of Catalytic Fixed-Bed Reactor for Carbon Dioxide Reforming of Methane over Rh/Al2O3 Catalyst. Bulletin of Chemical Reaction Engineering and Catalysis, 3 (1-3: 21-29. doi:10.9767/bcrec.3.1-3.19.21-29

  18. Deposition of carbon dioxide

    International Nuclear Information System (INIS)

    In Norway, there is currently a debate about whether or not to build gas power stations. To meet the possibility of reduced emission quotas for carbon dioxide in the future, current interest focuses on the incorporation of large-scale separation and deposition of carbon dioxide when such plants are planned. A group of experts concludes that this technology will become self-financing by means of environmental taxes. From the environmental point of view, taxes upon production are to be preferred over taxes on consumption

  19. Sodium-cooled nuclear reactors

    International Nuclear Information System (INIS)

    This book first explains the choice of sodium-cooled reactors by outlining the reasons of the choice of fast neutron reactors (fast neutrons instead of thermal neutrons, recycling opportunity for plutonium, full use of natural uranium, nuclear waste optimization, flexibility of fast neutron reactors in nuclear material management, fast neutron reactors as complements of water-cooled reactors), and by outlining the reasons for the choice of sodium as heat-transfer material. Physical, chemical, and neutron properties of sodium are presented. The second part of the book first presents the main design principles for sodium-cooled fast neutron reactors and their core. The third part proposes an historical overview and an assessment of previously operated sodium-cooled fast neutron reactors (French reactors from Rapsodie to Superphenix, other reactors in the world), and an assessment of the main incidents which occurred in these reactors. It also reports the experience and lessons learned from the dismantling of various sodium-cooled fast breeder reactors in the world. The next chapter addresses safety issues (technical and safety aspects related to the use of sodium) and environmental issues (dosimetry, gaseous and liquid releases, solid wastes, and cooling water). Then, various technological aspects of these reactors are addressed: the energy conversion system, main components, sodium chemistry, sodium-related technology, advances in in-service inspection, materials used in reactors and their behaviour, and fuel system. The next chapter addresses the fuel cycle in these reactors: its integrated specific character, report of the French experience in fast neutron reactor fuel processing, description of the transmutation of minor actinides in these reactors. The last chapter proposes an overview of reactors currently projected or under construction in the world, presents the Astrid project, and gives an assessment of the economy of these reactors. A glossary and an index

  20. Recovery of carbon dioxide from fuel cell exhaust

    Energy Technology Data Exchange (ETDEWEB)

    Healy, H.C.; Kolodney, M.; Levy, A.H.; Trocciola, P.

    1988-06-14

    An acid fuel cell power plant system operable to produce carbon dioxide as a by-product is described comprising: (a) fuel cell stack means having anode means, cathode means, and fuel cell cooling means, the cooling means using a water coolant; (b) means for delivering a hydrogen-rich fuel gas which contains carbon dioxide to the anode means for consumption of hydrogen by the anode means in an electrochemical reaction in the stack; (c) carbon dioxide absorber means including an absorbent for stripping carbon dioxide from gaseous mixtures thereof; (d) means for delivering hydrogen-depleted exhaust gas containing carbon dioxide from the anode means to the carbon dioxide absorber means for absorption of carbon dioxide from the exhaust gas; (e) an absorbent regenerator; (f) means for delivering carbon dioxide-enriched absorbent from the absorber means to the regenerator for separation of carbon dioxide from the absorbent; (g) means for exhausting carbon dioxide from the regenerator, the means for exhausting further including means for cooling and compressing carbon dioxide exhausted from the regenerator; and (h) means for removing the compressed carbon dioxide from the power plant.

  1. Carbon dioxide laser guidelines

    Directory of Open Access Journals (Sweden)

    Krupa Shankar D

    2009-01-01

    Full Text Available The carbon dioxide (CO 2 laser is a versatile tool that has applications in ablative lasing and caters to the needs of routine dermatological practice as well as the aesthetic, cosmetic and rejuvenation segments. This article details the basics of the laser physics as applicable to the CO 2 laser and offers guidelines for use in many of the above indications.

  2. Carbon dioxide dangers demonstration model

    Science.gov (United States)

    Venezky, Dina; Wessells, Stephen

    2010-01-01

    Carbon dioxide is a dangerous volcanic gas. When carbon dioxide seeps from the ground, it normally mixes with the air and dissipates rapidly. However, because carbon dioxide gas is heavier than air, it can collect in snowbanks, depressions, and poorly ventilated enclosures posing a potential danger to people and other living things. In this experiment we show how carbon dioxide gas displaces oxygen as it collects in low-lying areas. When carbon dioxide, created by mixing vinegar and baking soda, is added to a bowl with candles of different heights, the flames are extinguished as if by magic.

  3. Liquid cooled nuclear reactors

    International Nuclear Information System (INIS)

    A construction is described for a liquid metal cooled fast reactor, in which the core is supported in a pool of liquid coolant, wherein a catchment tray is provided for any debris falling from the core. The tray comprises a complex of open top collecting vessels with central support struts, the vessels being spaced apart and arranged in layers in a lattice pitch. The lattice pitches of the vessels in each layer are off-set to the lattice pitches of the vessels in the other layers, so that upper vessels partially overlap lower vessels, and the support struts extend through interspaces defined by the vessels in off-set pitch to a common supporting sub-structure. The complex of vessels offers a complete catchment area for falling debris, whilst being pervious to liquid coolant circulating upwardly by convection. The collecting vessels preferably comprise conical dishes and are arranged in triangular lattice pitch in each layer, and the complex of vessels comprises three layers. Alternatively the collecting vessels may be rectilinear and arranged on a square lattice. The catchment tray may comprise two or more such complexes in stacked array. (U.K.)

  4. Carbon Dioxide, the Coolant Gas of the G2/G3 Reactors: Leaks, Analysis, Activity

    International Nuclear Information System (INIS)

    This paper first describes very briefly the coolant gas circuits of the G2 and G3 reactors. The first part of the paper contains a detailed study of gas leaks together with relevant operating results. This study was carried out with the purpose of reducing still further the daily leakage rate and thus the operating costs of the reactors. The classification of CO2 circuits is based on the kinematics of the gas in the main reactor vessel and in the storage and feed systems. In this way a distinction is made between the feed circuits, the heat-exchange circuits and the leakage zones. While it cannot be claimed that this work alone has reduced by one-half the daily leakage rate between the initial operating period of the reactors and the present period of normal operation, it has certainly contributed to a greater understanding of the dynamics of the coolant gas and helped in the investigation of leaks. This study is virtually indispensable when the leakage rate is very low (3t/day) in relation to reactor capacity and it helps in the investigation of very small leaks. The second part of the paper describes various installations for chemical analysis and for measuring the activity of the coolant gas of the G2 and G3 reactors, presenting operating results for a period of several years. It also contains an outline of the various methods employed, of modifications and improvements to the original installations made with a view to providing more information about the sensitive and vital points in the installations and about the measurement parameters affecting the behaviour of the reactors (humidity, argon content, etc.). (author)

  5. CARBON DIOXIDE FIXATION.

    Energy Technology Data Exchange (ETDEWEB)

    FUJITA,E.

    2000-01-12

    Solar carbon dioxide fixation offers the possibility of a renewable source of chemicals and fuels in the future. Its realization rests on future advances in the efficiency of solar energy collection and development of suitable catalysts for CO{sub 2} conversion. Recent achievements in the efficiency of solar energy conversion and in catalysis suggest that this approach holds a great deal of promise for contributing to future needs for fuels and chemicals.

  6. Gas-cooled nuclear reactor

    International Nuclear Information System (INIS)

    The invention aims at simplying gas-cooled nuclear reactors. For the cooling gas, the reactor is provided with a main circulation system comprising one or several energy conversion main groups such as gas turbines, and an auxiliary circulation system comprising at least one steam-generating boiler heated by the gas after its passage through the reactor core and adapted to feed a steam turbine with motive steam. The invention can be applied to reactors the main groups of which are direct-cycle gas turbines

  7. Syngas Production Using an Oxygen-Permeating Membrane Reactor with Cofeed of Methane and Carbon Dioxide

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    CH4-CO2-O2 reforming to syngas in a novel Ba0.5Sr0.5Co0.8Fe0.2O3-d oxygen-permeable membrane reactor using LiLaNiO/g -Al2O3 as catalyst was successfully reported. Excellent reaction performance was achieved with around 92% methane conversion efficiency, 95% CO2 conversion rate, and nearly 8.5mL/min.cm2 oxygen permeation flux. In contrast to the oxygen permeation model with the presence of large concentration of CO2 (under such condition the oxygen permeation flux deteriorates with time), the oxygen permeation flux is really stable under the CH4-CO2-O2 reforming condition.

  8. Pre-combustion capture of carbon dioxide in a fixed bed reactor using the clathrate hydrate process

    International Nuclear Information System (INIS)

    Hydrate based gas separation (HBGS) process with silica sand and silica gel as contact medium was employed to capture CO2 from fuel gas mixture. Gas uptake measurement at three different pressures (7.5, 8.5 and 9.0 MPa) and 274.15 K were conducted for hydrate formation kinetics and overall conversion of water to hydrate, rate of hydrate formation were determined. Water conversion of up to 36% was achieved with silica sand bed compared to 13% conversion in the silica gel bed. Effect of driving force on the rate of hydrate formation and gas consumption was significant in silica sand bed whereas it was found to be insignificant in silica gel bed. Hydrate dissociation experiments by thermal stimulation (at constant pressure) alone and a combination of depressurization and thermal stimulation were carried out for complete recovery of the hydrated gas. A driving force of 23 K was found to be sufficient to recover all the hydrated gas within 1 h. This study indicates that silica sand can be an effective porous media for separation of CO2 from fuel gas when compared to silica gel. - Highlights: ► The clathrate process for pre-combustion capture of carbon dioxide in a novel fixed bed reactor is presented. ► Performance of two contact media (silica gel and silica sand) was investigated. ► Water to hydrate conversion was higher in a silica sand column. ► A pressure reduction and thermal stimulation approach is presented for a complete recovery of the hydrated gas

  9. Carbon dioxide (hydrogen sulfide) membrane separations and WGS membrane reactor modeling for fuel cells

    Science.gov (United States)

    Huang, Jin

    Acid-gas removal is of great importance in many environmental or energy-related processes. Compared to current commercial technologies, membrane-based CO2 and H2S capture has the advantages of low energy consumption, low weight and space requirement, simplicity of installation/operation, and high process flexibility. However, the large-scale application of the membrane separation technology is limited by the relatively low transport properties. In this study, CO2 (H2S)-selective polymeric membranes with high permeability and high selectivity have been studied based on the facilitated transport mechanism. The membrane showed facilitated effect for both CO2 and H2S. A CO2 permeability of above 2000 Barrers, a CO2/H2 selectivity of greater than 40, and a CO2/N2 selectivity of greater than 200 at 100--150°C were observed. As a result of higher reaction rate and smaller diffusing compound, the H2S permeability and H2S/H2 selectivity were about three times higher than those properties for CO2. The novel CO2-selective membrane has been applied to capture CO 2 from flue gas and natural gas. In the CO2 capture experiments from a gas mixture with N2 and H2, a permeate CO 2 dry concentration of greater than 98% was obtained by using steam as the sweep gas. In CO2/CH4 separation, decent CO 2 transport properties were obtained with a feed pressure up to 500 psia. With the thin-film composite membrane structure, significant increase on the CO2 flux was achieved with the decrease of the selective layer thickness. With the continuous removal of CO2, CO2-selective water-gas-shift (WGS) membrane reactor is a promising approach to enhance CO conversion and increase the purity of H2 at process pressure under relatively low temperature. The simultaneous reaction and transport process in the countercurrent WGS membrane reactor was simulated by using a one-dimensional non-isothermal model. The modeling results show that a CO concentration of less than 10 ppm and a H2 recovery of greater

  10. Cooling system for reactor container

    International Nuclear Information System (INIS)

    Purpose: To effectively cool a reactor container upon reactor shutdown with no intrusion of metal corrosion products in coolants into the main steam pipe in a BWR type reactor. Constitution: A clean up system comprising a pipeway, a recycling pump, a non-regenerative heat exchanger and a primary coolant purifier and a regenerative heat exchanger is provided branched from a residual heat removing system and the clean up system is connected by way of a valve to a feedwater pipeway, as well as connected by way of the pipeway to the main steam pipeway at the midway of two main steam separation valves outside of the reactor container. This enables to prevent metal corrosion products floating on the surface of reactor water from introducing into the main steam pipe when the pressure vessel is filled with water. Then, since the pressure vessel is filled with primary coolants, the pressure vessel can be cooled uniformly in a short time. (Ikeda, J.)

  11. Carbon dioxide sequestration by mineral carbonation

    NARCIS (Netherlands)

    Huijgen, W.J.J.

    2007-01-01

    The increasing atmospheric carbon dioxide (CO2) concentration, mainly caused by fossil fuel combustion, has lead to concerns about global warming. A possible technology that can contribute to the reduction of carbon dioxide emissions is CO2 sequestration by mineral carbonation. The basic concept beh

  12. Carbon dioxide and climate

    Energy Technology Data Exchange (ETDEWEB)

    1990-10-01

    Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

  13. Emergency cooling apparatus for reactor

    International Nuclear Information System (INIS)

    A nuclear reactor is described which has the core surrounded by coolant and an inert cover gas all sealed within a container, an emergency cooling apparatus employing a detector that will detect cover gas or coolant, particularly liquid sodium, leaking from the container of the reactor, to release a heat exchange material that is inert to the coolant, which heat exchange material is cooled during operation of the reactor. The heat exchange material may be liquid niitrogen or a combination of spheres and liquid nitrogen, for example, and is introduced so as to contact the coolant that has leaked from the container quickly so as to rapidly cool the coolant to prevent or extinguish combustion. (Official Gazette)

  14. Metal corrosion in a supercritical carbon dioxide - liquid sodium power cycle.

    Energy Technology Data Exchange (ETDEWEB)

    Moore, Robert Charles; Conboy, Thomas M.

    2012-02-01

    A liquid sodium cooled fast reactor coupled to a supercritical carbon dioxide Brayton power cycle is a promising combination for the next generation nuclear power production process. For optimum efficiency, a microchannel heat exchanger, constructed by diffusion bonding, can be used for heat transfer from the liquid sodium reactor coolant to the supercritical carbon dioxide. In this work, we have reviewed the literature on corrosion of metals in liquid sodium and carbon dioxide. The main conclusions are (1) pure, dry CO{sub 2} is virtually inert but can be highly corrosive in the presence of even ppm concentrations of water, (2) carburization and decarburization are very significant mechanism for corrosion in liquid sodium especially at high temperature and the mechanism is not well understood, and (3) very little information could be located on corrosion of diffusion bonded metals. Significantly more research is needed in all of these areas.

  15. Maximizing carbon dioxide content of shell eggs by rapid cooling treatment and its effect on shell egg quality.

    Science.gov (United States)

    Banerjee, P; Keener, K M

    2012-06-01

    Rapid cooling of shell eggs using liquid CO₂ has been shown to cool eggs to 7°C within minutes, as opposed to days required by traditional cooling treatments. This quick-cooling technique is component in the maintenance of egg quality and extended shelf life beyond the current 30- to 45-d period. The hypothesis for the current study was that maximizing CO₂ content of the eggs during cooling may increase Haugh units and thus extend shelf life (physical quality factors). The objective of this study was to maximize CO₂ content of shell eggs during rapid cooling with liquid CO₂ and determine its effect on egg quality during 12 wk of refrigerated storage. Three cooling conditions selected for the study were -45°C for 18 min (treatment A), -60°C for 15 min (treatment B), and -75°C for 12 min (treatment C). After rapid-cooling treatment, it took approximately 25 min for the internal temperature of eggs to equilibrate to 7°C. The Haugh units of the rapidly cooled eggs were significantly higher than the traditionally cooled (control) eggs. After 12 wk of refrigerated (5-7°C) storage, control eggs were only 37% AA-grade, 57% A-grade, and 6% B-grade. In comparison, all the rapidly cooled eggs averaged to 80% AA-grade and 20% A-grade. After 6 wk, the average quality of control eggs reduced to grade A, whereas rapid cooling treatment was able to maintain AA quality up to 12 wk. The CO₂ content of the rapidly cooled eggs (1.8 mg of CO₂/g of albumen) showed no difference between treatments A, B, and C, but it was significantly higher than the control (1.3 mg of CO₂/g of albumen). In addition, the vitelline membrane strength of the control decreased 65% during storage and was between 30 and 50% of the vitelline membrane strength of CO₂-cooled eggs at 12 wk. Rapid cooling with liquid CO₂ extends shelf life of shell eggs. PMID:22582306

  16. Development and validation of models for simulation of supercritical carbon dioxide Brayton cycles and application to self-propelling heat removal systems in boiling water reactors

    OpenAIRE

    Venker, Jeanne

    2015-01-01

    The objective of the current work was to develop a model that is able to describe the transient behavior of supercritical carbon dioxide (sCO2) Brayton cycles, to be applied to self-propelling residual heat removal systems in boiling water reactors. The developed model has been implemented into the thermohydraulic system code ATHLET. By means of this improved ATHLET version, novel residual heat removal systems, which are based on closed sCO2 Brayton cycles, can be assessed as a retrofit measu...

  17. Water Cooled FBNR Nuclear Reactor

    International Nuclear Information System (INIS)

    A new era of nuclear energy is emerging through innovative nuclear reactors that are to satisfy the new philosophies and criteria that are developed by the INPRO program of the International Atomic Energy Agency (IAEA). The IAEA is establishing a new paradigm in relation to nuclear energy. The future reactors should meet the new standards in respect to safety, economy, non-proliferation, nuclear waste, and environmental impact. The Fixed Bed Nuclear Reactor (FBNR) is a small (70 MWe) nuclear reactor that meets all the established requirements. It is an inherently safe and passively cooled reactor that is fool proof against nuclear proliferation. It is simple in design and economic. It can serve as a dual purpose plant to produce simultaneously both electricity and desalinated water thus making it especially suitable to the needs of most of developing countries. FBNR is developed with the support of the IAEA under its program of Small Reactors Without On-Site Refuelling (SRWOSR). The FBNR reactor uses the pressurized water reactor (PWR) technology. It fulfills the objectives of design simplicity, inherent and passive safety, economy, standardization, shop fabrication, easy transportability and high availability. The inherent safety characteristic of the reactor dispenses with the need for containment; however, a simple underground containment is envisaged for the reactor in order to reduce any adverse visual impact. (author)

  18. Carbon dioxide sequestration by mineral carbonation

    OpenAIRE

    Huijgen, W.J.J.

    2007-01-01

    The increasing atmospheric carbon dioxide (CO2) concentration, mainly caused by fossil fuel combustion, has lead to concerns about global warming. A possible technology that can contribute to the reduction of carbon dioxide emissions is CO2 sequestration by mineral carbonation. The basic concept behind mineral CO2 sequestration is the mimicking of natural weathering processes in which calcium or magnesium containing minerals react with gaseous CO2 and form solid calcium or magnesium carbonate...

  19. Application of a fluidized bed reactor charged with aragonite for control of alkalinity, pH and carbon dioxide in marine recirculating aquaculture systems

    Science.gov (United States)

    Paul S Wills, PhD; Pfeiffer, Timothy; Baptiste, Richard; Watten, Barnaby J.

    2016-01-01

    Control of alkalinity, dissolved carbon dioxide (dCO2), and pH are critical in marine recirculating aquaculture systems (RAS) in order to maintain health and maximize growth. A small-scale prototype aragonite sand filled fluidized bed reactor was tested under varying conditions of alkalinity and dCO2 to develop and model the response of dCO2 across the reactor. A large-scale reactor was then incorporated into an operating marine recirculating aquaculture system to observe the reactor as the system moved toward equilibrium. The relationship between alkalinity dCO2, and pH across the reactor are described by multiple regression equations. The change in dCO2 across the small-scale reactor indicated a strong likelihood that an equilibrium alkalinity would be maintained by using a fluidized bed aragonite reactor. The large-scale reactor verified this observation and established equilibrium at an alkalinity of approximately 135 mg/L as CaCO3, dCO2 of 9 mg/L, and a pH of 7.0 within 4 days that was stable during a 14 day test period. The fluidized bed aragonite reactor has the potential to simplify alkalinity and pH control, and aid in dCO2 control in RAS design and operation. Aragonite sand, purchased in bulk, is less expensive than sodium bicarbonate and could reduce overall operating production costs.

  20. The oxidation of moderator graphites irradiated in carbon dioxide containing carbon monoxide, methane and water

    International Nuclear Information System (INIS)

    The Advanced Gas Cooled Reactor (AGR) was introduced for the second generation of British nuclear power stations. It was recognised that problems of compatibility between the carbon dioxide coolant and the moderator graphite would arise because of the increased power rating of the reactor compared with the first generation MAGNOX system. This led to the realisation that it would be necessary to reduce the rate of oxidation of the moderator to acceptable levels by the addition of inhibitors to the coolant and to this end carbon monoxide and methane were chosen. This paper describes experiments which have been made in a materials testing reactor at AERE Harwell in which moderator graphite reaction rates have been measured in carbon dioxide containing carbon monoxide at concentrations between 0.03% and 2% and methane concentrations up to 600 vpm. The effect of impressing a flow of coolant through the graphite structure, the so-called ventilation effect, and the role of coolant temperature and pressure have also been assessed. The results confirm the inhibiting power of methane and carbon monoxide on the graphite/CO2 reaction and demonstrate that the application of ventilation in the presence of these inhibitors enhances their effect. A minimum or 'terminal' oxidation rate may be achieved by the CAGR Gilso carbon graphites when irradiated in the presence of 200 vpm methane, or more, under appropriate conditions. (author)

  1. Slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures

    Science.gov (United States)

    Aines, Roger D.; Bourcier, William L.; Viani, Brian

    2013-01-29

    A slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures includes the steps of dissolving the gas mixture and carbon dioxide in water providing a gas, carbon dioxide, water mixture; adding a porous solid media to the gas, carbon dioxide, water mixture forming a slurry of gas, carbon dioxide, water, and porous solid media; heating the slurry of gas, carbon dioxide, water, and porous solid media producing steam; and cooling the steam to produce purified water and carbon dioxide.

  2. Design and analysis of a small-scale natural gas liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling

    International Nuclear Information System (INIS)

    With the growth of energy consumption and environmental protection concerns, it is of enormous economic and environmental values for the development of stranded gas. As a means for exploitation and transportation of stranded gas to market, a novel small-scale liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling is put up with in this paper. Taking unit energy consumption as the target function, Aspen HYSYS is employed to simulate and optimize the process to achieve the liquefaction rate of 0.77 with unit energy consumption of 9.90 kW/kmol/h. Furthermore, the adaptability of this process under different pressure, temperature and compositions of feed gas is studied. Based on the optimization results, the exergy losses of main equipment in the process are evaluated and analyzed in details. With compact device, safety operation, simple capability, this liquefaction process proves to be suitable for the development of small gas reserves, satellite distribution fields of gas or coalbed methane fields. - Highlights: •A novel small-scale liquefaction process used in stranded gas is designed. •The adaptability of this process under different pressure, temperature and compositions of feed gas is studied. •The exergy analysis of main equipment in the process is analyzed

  3. Gas-cooled nuclear reactor

    International Nuclear Information System (INIS)

    The gas temperature of a hot gas loop in gas-cooled nuclear reactor plants shall be able to be modified without influencing the gas temperature of the other loops. If necessary, it should be possible to stop the loop. This is possible by means of a mixer which is places below the heat absorbing component in the hot channel and which is connected to a cold gas line. (orig.)

  4. Carbon Dioxide Embolism during Laparoscopic Surgery

    OpenAIRE

    Park, Eun Young; Kwon, Ja-Young; Kim, Ki Jun

    2012-01-01

    Clinically significant carbon dioxide embolism is a rare but potentially fatal complication of anesthesia administered during laparoscopic surgery. Its most common cause is inadvertent injection of carbon dioxide into a large vein, artery or solid organ. This error usually occurs during or shortly after insufflation of carbon dioxide into the body cavity, but may result from direct intravascular insufflation of carbon dioxide during surgery. Clinical presentation of carbon dioxide embolism ra...

  5. Passive Safety Optimization in Liquid Sodium-Cooled Reactors

    International Nuclear Information System (INIS)

    The governing equations and the solutions schemes are developed for the three-dimensional thermal-hydraulic model.A detailed constitutive relations are also developed through the analysis with a CFD code. The developed model is able to obtain a detailed thermal hydraulic information in a subassemlby of a liquid metal-cooled reactor core. The model has been integrated with the system analysis codes SASSYS-1 and SSC-K to be validated for the SHRT-17 test performed in the EBR-II reactor. The baseline analyses were performed with the customary thermal-hydraulic model and with the new model for the reference design of KALIMER-150. The results point out that increased detail in the thermal-hydraulic analysis must be matched by increased detail in the reactivity feedback modeling, especially the radial core expansion model, in order to provide distinguishable differences. The analyses performed to identify certain key safety features have indicated that the adjustment of core restraint system is able to provide beneficial bending of hexcans, resulting in enhanced negative reactivity feedback in unprotected accidents. Tasks were performed to identify and assess the implications for plant safety of proposed specific approaches for reducing capital and operating costs of next generation sodium-cooled fast reactors. A new plant design of the sodium-cooled reactor concept is developed utilizing a gas turbine Brayton cycle, which uses supercritical carbon dioxide (S-CO2) as the working fluid. In addition, the design innovations are incorporated in modular sodium-to-supercritical carbon dioxide heat exchangers that enable the traditional intermediate heat transport circuit to be eliminated. Several evaluations and analyses for the safety design and efficiency suggest that the developed system is safe and cost-effective. Test plans are developed for the measurement of phenomenological data describing freezing of molten metallic fuel, melt relocation and interaction with steel

  6. Reactor pressure vessel cooling device

    International Nuclear Information System (INIS)

    A spray pipeline for the head of a pressure vessel is connected to a spray for the pressure vessel head of the reactor pressure vessel. The pipeline is equipped with a spray flow rate control valve for controlling the flow rate of spray jetted from the head spray to the inside of the reactor and a thermometer for spray water. A reactor pressure vessel cooling and controlling portion intakes temperature signals sent from a thermometer for the head of the pressure vessel, a thermometer for the flange of the pressure vessel and a thermometer for the body of the pressure vessel, and a thermometer for spray water. Then, it outputs restriction signal for the opening degree of the spray flow rate control valve to restrict the spray water flow rate within an appropriate range when the difference between the temperature of each portion of the pressure vessel and the temperature of spray water is increased to greater than an allowable temperature difference. With such procedures, spray operation for the head of the pressure vessel can be conducted not only upon emergency but also during reactor cooling operation. (I.N.)

  7. Carbon Dioxide Reduction Technology Trade Study

    Science.gov (United States)

    Jeng, Frank F.; Anderson, Molly S.; Abney, Morgan B.

    2011-01-01

    For long-term human missions, a closed-loop atmosphere revitalization system (ARS) is essential to minimize consumables. A carbon dioxide (CO2) reduction technology is used to reclaim oxygen (O2) from metabolic CO2 and is vital to reduce the delivery mass of metabolic O2. A key step in closing the loop for ARS will include a proper CO2 reduction subsystem that is reliable and with low equivalent system mass (ESM). Sabatier and Bosch CO2 reduction are two traditional CO2 reduction subsystems (CRS). Although a Sabatier CRS has been delivered to International Space Station (ISS) and is an important step toward closing the ISS ARS loop, it recovers only 50% of the available O2 in CO2. A Bosch CRS is able to reclaim all O2 in CO2. However, due to continuous carbon deposition on the catalyst surface, the penalties of replacing spent catalysts and reactors and crew time in a Bosch CRS are significant. Recently, technologies have been developed for recovering hydrogen (H2) from Sabatier-product methane (CH4). These include methane pyrolysis using a microwave plasma, catalytic thermal pyrolysis of CH4 and thermal pyrolysis of CH4. Further, development in Sabatier reactor designs based on microchannel and microlith technology could open up opportunities in reducing system mass and enhancing system control. Improvements in Bosch CRS conversion have also been reported. In addition, co-electrolysis of steam and CO2 is a new technology that integrates oxygen generation and CO2 reduction functions in a single system. A co-electrolysis unit followed by either a Sabatier or a carbon formation reactor based on Bosch chemistry could improve the overall competitiveness of an integrated O2 generation and CO2 reduction subsystem. This study evaluates all these CO2 reduction technologies, conducts water mass balances for required external supply of water for 1-, 5- and 10-yr missions, evaluates mass, volume, power, cooling and resupply requirements of various technologies. A system

  8. Carbon Dioxide Captured from Flue Gas by Modified Ca-based Sorbents in Fixed-bed Reactor at High Temperature

    Institute of Scientific and Technical Information of China (English)

    YANG Lei; YU Hongbing; WANG Shengqiang; WANG Haowen; ZHOU Qibin

    2013-01-01

    Four kinds of Ca-based sorbents were prepared by calcination and hydration reactions using different precursors: calcium hydroxide,calcium carbonate,calcium acetate monohydrate and calcium oxide.The CO2 absorption capacity of those sorbents was investigated in a fixed-bed reactor in the temperature range of 350 650 ℃.It was found that all of those sorbents showed higher capacity for CO2 absorption when the operating temperature higher than 450 ℃.The CaAc2-CaO sorbent showed the highest CO2 absorption capacity of 299 mg·g-1.The morphology of those sorbents was examined by scanning electron microscope(SEM),and the changes of composition before and after carbonation were also determined by X-ray diffraction(XRD).Results indicated that those sorbents have the similar chemical compositions and crystalline phases before carbonation reaction [mainly Ca(OH)2],and CaCO3 is the main component after carbonation reaction.The SEM morphology shows clearly that the sorbent pores were filled with reaction products after carbonation reaction,and became much denser than before.The N2 adsorption-desorption isotherms indicated that the CaAc2-CaO and CaCO3-CaO sorbents have higher specific surface area,larger pore volume and appropriate pore size distribution than that of CaO-CaO and Ca(OH)2-CaO.

  9. Separation of carbon dioxide from flue emissions using Endex principles

    CERN Document Server

    Ball, R

    2009-01-01

    In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

  10. European supercritical water cooled reactor

    International Nuclear Information System (INIS)

    Highlights: → The HPLWR reactor design is an example of a supercritical water cooled reactor. → Cladding material tests have started but materials are not yet satisfactory. → Numerical heat transfer predictions are promising but need further validation. → The research project is most suited for nuclear education and training. - Abstract: The High Performance Light Water Reactor (HPLWR), how the European Supercritical Water Cooled Reactor is called, is a pressure vessel type reactor operated with supercritical water at 25 MPa feedwater pressure and 500 oC average core outlet temperature. It is designed and analyzed by a European consortium of 10 partners and 3 active supporters from 8 Euratom member states in the second phase of the HPLWR project. Most emphasis has been laid on a core with a thermal neutron spectrum, consisting of small fuel assemblies in boxes with 40 fuel pins each and a central water box to improve the neutron moderation despite the low coolant density. Peak cladding temperatures of the fuel rods have been minimized by heating up the coolant in three steps with intermediate coolant mixing. The containment design with its safety and residual heat removal systems is based on the latest boiling water reactor concept, but with different passive high pressure coolant injection systems to cause a forced convection through the core. The design concept of the steam cycle is indicating the envisaged efficiency increase to around 44%. Moreover, it provides the constraints to design the components of the balance of the plant. The project is accompanied by numerical studies of heat transfer of supercritical water in fuel assemblies and by material tests of candidate cladding alloys, performed by the consortium and supported by additional tests of the Joint Research Centre of the European Commission. Besides the scientific and technical progress, the HPLWR project turned out to be most successful in training the young generation of nuclear engineers

  11. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Thomas Nelson; Brian S. Turk; Jeffrey W. Portzer; Raghubir P. Gupta

    2005-04-01

    This report describes research conducted between January 1, 2005 and March 31, 2005 on the use of dry regenerable sorbents for removal of carbon dioxide from flue gas. Engineered sorbents composed of sodium carbonate on a ceramic support were tested in a laboratory fluidized bed reactor system and found to be capable of essentially complete removal of carbon dioxide at 60 C in a short residence time. Upon breakthrough the sorbents can be thermally regenerated to recover essentially all of the absorbed carbon dioxide. An optimized supported sorbent tested in a pilot-scale entrained bed absorber retained its reactivity in multicycle tests and experienced no attrition. Removal of >90% of carbon dioxide in simulated flue gas was achieved in an entrained bed reactor.

  12. Analysis of characteristics of different working fluids for gas turbine cycle with high temperature gas-cooled reactor

    International Nuclear Information System (INIS)

    Gas turbine cycle with high temperature gas-cooled reactor is the main direction of nuclear energy generation, which is with the advantages in terms of the safety and economy. The thermal and physical properties of helium, nitrogen, carbon dioxide and the mixtures were compared and analyzed in this paper. Further more, the heat transfer coefficient, pressure loss and the stage number of turbo-machines have been also compared. Results indicate that taking the mixture of helium and carbon dioxide as the working fluid of gas turbine cycle with high temperature gas-cooled reactor can not only improve the heat transfer coefficient and decrease the stage number of turbo-machinery, but also can limit the pressure loss to a certain level. (authors)

  13. Carbon Dioxide - Our Common "Enemy"

    Science.gov (United States)

    James, John T.; Macatangay, Ariel

    2009-01-01

    Health effects of brief and prolonged exposure to carbon dioxide continue to be a concern for those of us who manage this pollutant in closed volumes, such as in spacecraft and submarines. In both examples, considerable resources are required to scrub the atmosphere to levels that are considered totally safe for maintenance of crew health and performance. Defining safe levels is not a simple task because of many confounding factors, including: lack of a robust database on human exposures, suspected significant variations in individual susceptibility, variations in the endpoints used to assess potentially adverse effects, the added effects of stress, and the fluid shifts associated with micro-gravity (astronauts only). In 2007 the National Research Council proposed revised Continuous Exposure Guidelines (CEGLs) and Emergency Exposure Guidelines (EEGLs) to the U.S. Navy. Similarly, in 2008 the NASA Toxicology Group, in cooperation with another subcommittee of the National Research Council, revised Spacecraft Maximum Allowable Concentrations (SMACs). In addition, a 1000-day exposure limit was set for long-duration spaceflights to celestial bodies. Herein we examine the rationale for the levels proposed to the U.S. Navy and compare this rationale with the one used by NASA to set its limits. We include a critical review of previous studies on the effects of exposure to carbon dioxide and attempt to dissect out the challenges associated with setting fully-defensible limits. We also describe recent experiences with management of carbon dioxide aboard the International Space Station with 13 persons aboard. This includes the tandem operations of the Russian Vozduk and the U.S. Carbon Dioxide Removal System. A third removal system is present while the station is docked to the Shuttle spacecraft, so our experience includes the lithium hydroxide system aboard Shuttle for the removal of carbon dioxide. We discuss strategies for highly-efficient, regenerable removal of carbon

  14. Water cooled FBNR nuclear reactor

    International Nuclear Information System (INIS)

    elements from the fuel chamber up into the core. A fixed suspended core is formed in the reactor. In the shut down condition, the suspended core breaks down and the fuel elements leave the core and fall back into the fuel chamber by the force of gravity. The fuel elements are made of UO2 micro spheres embedded in zirconium and cladded by zircaloy. Any signal from any of the detectors, due to any initiating event, will cut-off power to the pump, causing the fuel elements to leave the core and fall back into the fuel chamber, where they remain in a highly subcritical and passively cooled conditions. The fuel chamber is cooled by natural convection transferring heat to the water in the tank housing the fuel chamber. The nest step in the development of FBNR is the construction of its prototype. Efforts are being made to secure participants in such an endeavor. (author)

  15. Physics of gas-cooled reactors

    International Nuclear Information System (INIS)

    This paper deals with technical aspects of the gas-cooled reactors safety and design. It content five main parts: the new safety requirements for innovative reactors; the concept of a non-meltable nuclear reactor; the new concepts of decay heat removal from the reactor system; the behaviour of reactor system in case of extreme reactivity accidents; technical innovations in the reactor technology and necessary developments and proof tests. (A.L.B.)

  16. Liquid metal cooled nuclear reactors

    International Nuclear Information System (INIS)

    Reference is made to liquid metal cooled nuclear reactors of the 'pool' type. In such reactors the core, the heat exchangers, and the coolant circulating pumps are submerged in a pool of liquid metal. In operation of the reactor it is necessary to be able to locate and identify components submerged in the pool, and before moving rotating shields in the roof of the pool-containing vault it is necessary to ensure that all the normally suspended absorber rods have been inserted in the core and released from their suspensions. Television cameras are unsuitable for use in the opaque liquid metal but ultrasound in the megahertz range has been used to give a television screen kind of display. There is some difficulty, however, in transmitting ultrasound signals from a transducer into the pool of coolant because the transducer must be protected from the high temperature environment of the coolant. This difficulty has been partially overcome, however, by transmitting the signals by way of a wave guide extending from the transducer into the coolant pool. Such a wave guide may comprise a column of liquid metal within a dip tube. The column of liquid coolant is uninterrupted by a supporting diaphragm. Such a system is here described. (U.K.)

  17. Carbon dioxide heat pump for dual-temperature drinking fountain

    Institute of Scientific and Technical Information of China (English)

    杨大章; 吕静; 何哲彬; 黄秀芝

    2009-01-01

    Carbon dioxide trans-critical heat pump system for heating and cooling water was designed,and its thermodynamic steady-state concentration model was established. Based on the steady-state model,parameters of the carbon dioxide trans-critical heat pump were calculated by computer programming. According to these parameters,the effects and application prospect of the heat pump system were analyzed for dual-temperature drinking fountains.

  18. Supercritical carbon dioxide cycle control analysis.

    Energy Technology Data Exchange (ETDEWEB)

    Moisseytsev, A.; Sienicki, J. J. (Nuclear Engineering Division)

    2011-04-11

    This report documents work carried out during FY 2008 on further investigation of control strategies for supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle energy converters. The main focus of the present work has been on investigation of the S-CO{sub 2} cycle control and behavior under conditions not covered by previous work. An important scenario which has not been previously calculated involves cycle operation for a Sodium-Cooled Fast Reactor (SFR) following a reactor scram event and the transition to the primary coolant natural circulation and decay heat removal. The Argonne National Laboratory (ANL) Plant Dynamics Code has been applied to investigate the dynamic behavior of the 96 MWe (250 MWt) Advanced Burner Test Reactor (ABTR) S-CO{sub 2} Brayton cycle following scram. The timescale for the primary sodium flowrate to coast down and the transition to natural circulation to occur was calculated with the SAS4A/SASSYS-1 computer code and found to be about 400 seconds. It is assumed that after this time, decay heat is removed by the normal ABTR shutdown heat removal system incorporating a dedicated shutdown heat removal S-CO{sub 2} pump and cooler. The ANL Plant Dynamics Code configured for the Small Secure Transportable Autonomous Reactor (SSTAR) Lead-Cooled Fast Reactor (LFR) was utilized to model the S-CO{sub 2} Brayton cycle with a decaying liquid metal coolant flow to the Pb-to-CO{sub 2} heat exchangers and temperatures reflecting the decaying core power and heat removal by the cycle. The results obtained in this manner are approximate but indicative of the cycle transient performance. The ANL Plant Dynamics Code calculations show that the S-CO{sub 2} cycle can operate for about 400 seconds following the reactor scram driven by the thermal energy stored in the reactor structures and coolant such that heat removal from the reactor exceeds the decay heat generation. Based on the results, requirements for the shutdown heat removal system may be defined

  19. Supercritical carbon dioxide cycle control analysis

    International Nuclear Information System (INIS)

    This report documents work carried out during FY 2008 on further investigation of control strategies for supercritical carbon dioxide (S-CO2) Brayton cycle energy converters. The main focus of the present work has been on investigation of the S-CO2 cycle control and behavior under conditions not covered by previous work. An important scenario which has not been previously calculated involves cycle operation for a Sodium-Cooled Fast Reactor (SFR) following a reactor scram event and the transition to the primary coolant natural circulation and decay heat removal. The Argonne National Laboratory (ANL) Plant Dynamics Code has been applied to investigate the dynamic behavior of the 96 MWe (250 MWt) Advanced Burner Test Reactor (ABTR) S-CO2 Brayton cycle following scram. The timescale for the primary sodium flowrate to coast down and the transition to natural circulation to occur was calculated with the SAS4A/SASSYS-1 computer code and found to be about 400 seconds. It is assumed that after this time, decay heat is removed by the normal ABTR shutdown heat removal system incorporating a dedicated shutdown heat removal S-CO2 pump and cooler. The ANL Plant Dynamics Code configured for the Small Secure Transportable Autonomous Reactor (SSTAR) Lead-Cooled Fast Reactor (LFR) was utilized to model the S-CO2 Brayton cycle with a decaying liquid metal coolant flow to the Pb-to-CO2 heat exchangers and temperatures reflecting the decaying core power and heat removal by the cycle. The results obtained in this manner are approximate but indicative of the cycle transient performance. The ANL Plant Dynamics Code calculations show that the S-CO2 cycle can operate for about 400 seconds following the reactor scram driven by the thermal energy stored in the reactor structures and coolant such that heat removal from the reactor exceeds the decay heat generation. Based on the results, requirements for the shutdown heat removal system may be defined. In particular, the peak heat removal

  20. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Thomas Nelson; Brian S. Turk; Paul Box; Weijiong Li; Raghubir P. Gupta

    2005-07-01

    This report describes research conducted between April 1, 2005 and June 30, 2005 on the use of dry regenerable sorbents for removal of carbon dioxide from flue gas from coal combustion and synthesis gas from coal gasification. Supported sodium carbonate sorbents removed up to 76% of the carbon dioxide from simulated flue gas in a downflow cocurrent flow reactor system, with an approximate 15 second gas-solid contact time. This reaction proceeds at temperatures as low as 25 C. Lithium silicate sorbents remove carbon dioxide from high temperature simulated flue gas and simulated synthesis gas. Both sorbent types can be thermally regenerated and reused. The lithium silicate sorbent was tested in a thermogravimetric analyzer and in a 1-in quartz reactor at atmospheric pressure; tests were also conducted at elevated pressure in a 2-in diameter high temperature high pressure reactor system. The lithium sorbent reacts rapidly with carbon dioxide in flue gas at 350-500 C to absorb about 10% of the sorbent weight, then continues to react at a lower rate. The sorbent can be essentially completely regenerated at temperatures above 600 C and reused. In atmospheric pressure tests with synthesis gas of 10% initial carbon dioxide content, the sorbent removed over 90% of the carbon dioxide. An economic analysis of a downflow absorption process for removal of carbon dioxide from flue gas with a supported sodium carbonate sorbent suggests that a 90% efficient carbon dioxide capture system installed at a 500 MW{sub e} generating plant would have an incremental capital cost of $35 million ($91/kWe, assuming 20 percent for contingencies) and an operating cost of $0.0046/kWh. Assuming capital costs of $1,000/kW for a 500 MWe plant the capital cost of the down flow absorption process represents a less than 10% increase, thus meeting DOE goals as set forth in its Carbon Sequestration Technology Roadmap and Program Plan.

  1. Effect of carbon dioxide concentration on the bioleaching of a pyrite-arsenopyrite ore concentrate

    Energy Technology Data Exchange (ETDEWEB)

    Nagpal, S.; Dahlstrom, D. (Univ. of Utah, Salt Lake City (United States)); Oolman, T. (Radian Corp., Austin, TX (United States))

    1993-02-20

    The effect of carbon dioxide concentration on the bacterial leaching of a pyrite-arsenopyrite ore concentrate was studied in continuous-flow reactors. Steady-state operation with two feed slurry densities, 6 wt% and 16wt% solids, were tested for the effect of carbon dioxide concentration. Bacterial growth rates were estimated via the measurement of carbon dioxide consumption rates. Aqueous-phase carbon dioxide concentrations in excess of 10 mg/L were found to be inhibitory to bacterial growth.

  2. High capacity carbon dioxide sorbent

    Energy Technology Data Exchange (ETDEWEB)

    Dietz, Steven Dean; Alptekin, Gokhan; Jayaraman, Ambalavanan

    2015-09-01

    The present invention provides a sorbent for the removal of carbon dioxide from gas streams, comprising: a CO.sub.2 capacity of at least 9 weight percent when measured at 22.degree. C. and 1 atmosphere; an H.sub.2O capacity of at most 15 weight percent when measured at 25.degree. C. and 1 atmosphere; and an isosteric heat of adsorption of from 5 to 8.5 kilocalories per mole of CO.sub.2. The invention also provides a carbon sorbent in a powder, a granular or a pellet form for the removal of carbon dioxide from gas streams, comprising: a carbon content of at least 90 weight percent; a nitrogen content of at least 1 weight percent; an oxygen content of at most 3 weight percent; a BET surface area from 50 to 2600 m.sup.2/g; and a DFT micropore volume from 0.04 to 0.8 cc/g.

  3. Carbon dioxide transport over complex terrain

    OpenAIRE

    Sun, RC

    2004-01-01

    The nocturnal transport of carbon dioxide over complex terrain was investigated. The high carbon dioxide under very stable conditions flows to local low-ground. The regional drainage flow dominates the carbon dioxide transport at the 6 m above the ground and carbon dioxide was transported to the regional low ground. The results show that the local drainage flow was sensitive to turbulent mixing associated with local wind shear.

  4. Perspectives in the use of carbon dioxide

    OpenAIRE

    1999-01-01

    The mitigation of carbon dioxide is one of the scientific and technological challenges of the 2000s. Among the technologies that are under assessment, the recovery of carbon dioxide from power plants or industrial flue gases plays a strategic role. Recovered carbon dioxide can be either disposed in natural fields or used. The availability of large amounts of carbon dioxide may open new routes to its utilisation in biological, chemical and innovative technological processes. In this paper, the...

  5. Modelling Sublimation of Carbon Dioxide

    Science.gov (United States)

    Winkel, Brian

    2012-01-01

    In this article, the author reports results in their efforts to model sublimation of carbon dioxide and the associated kinetics order and parameter estimation issues in their model. They have offered the reader two sets of data and several approaches to determine the rate of sublimation of a piece of solid dry ice. They presented several models…

  6. Graphite suspension in carbon dioxide

    International Nuclear Information System (INIS)

    Since 1963 the Atomic Division of SNECMA has been conducting, under a contract with the CEA, an experimental work with a two-component fluid comprised of carbon dioxide and small graphite particles. The primary purpose was the determination of basic engineering information pertaining to the stability and the flowability of the suspension. The final form of the experimental loop consists mainly of the following items: a light-phase compressor, a heavy-phase pump, an electrical-resistance type heater section, a cooling heat exchanger, a hairpin loop, a transparent test section and a separator. During the course of the testing, it was observed that the fluid could be circulated quite easily in a broad range of variation of the suspension density and velocity - density from 30 to 170 kg/m3 and velocity from 2 to 24 m/s. The system could be restarted and circulation maintained without any difficulty, even with the heavy-phase pump alone. The graphite did not have a tendency to pack or agglomerate during operation. No graphite deposition was observed on the wall of the tubing. A long period run (250 hours) has shown the evolution of the particle dimensions. Starting with graphite of surface area around 20 m2/g (graphite particles about 1 μ), the powder surface area reaches an asymptotic value of 300 m2/g (all the particles less than 0.3 μ). Moisture effect on flow stability, flow distribution between two parallel channels, pressure drop in straight tubes, recompression ratio in diffusers were also investigated. (author)

  7. 21 CFR 582.1240 - Carbon dioxide.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Carbon dioxide. 582.1240 Section 582.1240 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS....1240 Carbon dioxide. (a) Product. Carbon dioxide. (b) Conditions of use. This substance is...

  8. Nongovernmental valorization of carbon dioxide

    International Nuclear Information System (INIS)

    Carbon dioxide (CO2) is considered the largest contributor to the greenhouse gas effect. Most attempts to manage the flow of CO2 or carbon into our environment involve reducing net emissions or sequestering the gas into long-lived sinks. Using CO2 as a chemical feedstock has a long history, but using it on scales that might impact the net emissions of CO2 into the atmosphere has not generally been considered seriously. There is also a growing interest in employing our natural biomes of carbon such as trees, vegetation, and soils as storage media. Some amelioration of the net carbon emissions into the atmosphere could be achieved by concomitant large withdrawals of carbon. This report surveys the potential and limitations in employing carbon as a resource for organic chemicals, fuels, inorganic materials, and in using the biome to manage carbon. The outlook for each of these opportunities is also described

  9. Helium-cooled high temperature reactors

    International Nuclear Information System (INIS)

    Experience with several helium cooled reactors has been favorable, and two commercial plants are now operating. Both of these units are of the High Temperature Graphite Gas Cooled concept, one in the United States and the other in the Federal Republic of Germany. The initial helium charge for a reactor of the 1000 MW(e) size is modest, approx.15,000 kg

  10. CARBON DIOXIDE AS A FEEDSTOCK.

    Energy Technology Data Exchange (ETDEWEB)

    CREUTZ,C.; FUJITA,E.

    2000-12-09

    This report is an overview on the subject of carbon dioxide as a starting material for organic syntheses of potential commercial interest and the utilization of carbon dioxide as a substrate for fuel production. It draws extensively on literature sources, particularly on the report of a 1999 Workshop on the subject of catalysis in carbon dioxide utilization, but with emphasis on systems of most interest to us. Atmospheric carbon dioxide is an abundant (750 billion tons in atmosphere), but dilute source of carbon (only 0.036 % by volume), so technologies for utilization at the production source are crucial for both sequestration and utilization. Sequestration--such as pumping CO{sub 2} into sea or the earth--is beyond the scope of this report, except where it overlaps utilization, for example in converting CO{sub 2} to polymers. But sequestration dominates current thinking on short term solutions to global warming, as should be clear from reports from this and other workshops. The 3500 million tons estimated to be added to the atmosphere annually at present can be compared to the 110 million tons used to produce chemicals, chiefly urea (75 million tons), salicylic acid, cyclic carbonates and polycarbonates. Increased utilization of CO{sub 2} as a starting material is, however, highly desirable, because it is an inexpensive, non-toxic starting material. There are ongoing efforts to replace phosgene as a starting material. Creation of new materials and markets for them will increase this utilization, producing an increasingly positive, albeit small impact on global CO{sub 2} levels. The other uses of interest are utilization as a solvent and for fuel production and these will be discussed in turn.

  11. High temperature gas-cooled reactor technology

    International Nuclear Information System (INIS)

    The high temperature gas-cooled reactor (HTGR) with a direct cycle helium system has drawn attention as the next generation nuclear power plant that is closest to commercialization. Fuji Electric participated in the design, manufacture and construction of JAPCO's Tokai-1 plant, a 'Colder Hall' type reactor, which was the first commercial nuclear power plant in Japan, and JAERI's high temperature engineering test reactor (HTTR), which was the first high temperature gas-cooled reactor in Japan. Fuji Electric, a pioneer of gas-cooled reactors, worked on the design, construction and development of these reactors. This paper provides brief descriptions of the air-cooled spent fuel storage system of the HTTR, material test facilities for the HTTR, and the development of an inherently safe and highly efficient commercial HTGR power plant as examples of Fuji Electric's recent activities in the HTGR field. (author)

  12. Perspectives in the use of carbon dioxide

    Directory of Open Access Journals (Sweden)

    Aresta Michele

    1999-01-01

    Full Text Available The mitigation of carbon dioxide is one of the scientific and technological challenges of the 2000s. Among the technologies that are under assessment, the recovery of carbon dioxide from power plants or industrial flue gases plays a strategic role. Recovered carbon dioxide can be either disposed in natural fields or used. The availability of large amounts of carbon dioxide may open new routes to its utilisation in biological, chemical and innovative technological processes. In this paper, the potential of carbon dioxide utilisation in the short-, medium-term is reviewed.

  13. High Purity Hydrogen Production with In-Situ Carbon Dioxide and Sulfur Capture in a Single Stage Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Nihar Phalak; Shwetha Ramkumar; Daniel Connell; Zhenchao Sun; Fu-Chen Yu; Niranjani Deshpande; Robert Statnick; Liang-Shih Fan

    2011-07-31

    Enhancement in the production of high purity hydrogen (H{sub 2}) from fuel gas, obtained from coal gasification, is limited by thermodynamics of the water gas shift (WGS) reaction. However, this constraint can be overcome by conducting the WGS in the presence of a CO{sub 2}-acceptor. The continuous removal of CO{sub 2} from the reaction mixture helps to drive the equilibrium-limited WGS reaction forward. Since calcium oxide (CaO) exhibits high CO{sub 2} capture capacity as compared to other sorbents, it is an ideal candidate for such a technique. The Calcium Looping Process (CLP) developed at The Ohio State University (OSU) utilizes the above concept to enable high purity H{sub 2} production from synthesis gas (syngas) derived from coal gasification. The CLP integrates the WGS reaction with insitu CO{sub 2}, sulfur and halide removal at high temperatures while eliminating the need for a WGS catalyst, thus reducing the overall footprint of the hydrogen production process. The CLP comprises three reactors - the carbonator, where the thermodynamic constraint of the WGS reaction is overcome by the constant removal of CO{sub 2} product and high purity H{sub 2} is produced with contaminant removal; the calciner, where the calcium sorbent is regenerated and a sequestration-ready CO{sub 2} stream is produced; and the hydrator, where the calcined sorbent is reactivated to improve its recyclability. As a part of this project, the CLP was extensively investigated by performing experiments at lab-, bench- and subpilot-scale setups. A comprehensive techno-economic analysis was also conducted to determine the feasibility of the CLP at commercial scale. This report provides a detailed account of all the results obtained during the project period.

  14. Analysis of water cooled reactors stability

    International Nuclear Information System (INIS)

    A model for stability analysis of non-boiling water cooled nuclear system is developed. The model is based on linear reactor kinetics and space averaged heat transfer in reactor and heat-exchanger. The transfer functions are defined and the analysis was applied to nuclear reactor RA at 'Boris Kidric' Institute - Vinca. (author)

  15. Advanced gas-cooled reactors (AGR)

    International Nuclear Information System (INIS)

    The paper describes the advanced gas-cooled reactor system, Hunterston ''B'' power station, which is a development of the earlier natural uranium Magnox type reactor. Data of construction, capital cost, operating performance, reactor safety and also the list of future developments are given

  16. Gas-cooled fast breeder reactor

    International Nuclear Information System (INIS)

    Almost all the R D works of gas-cooled fast breeder reactor in the world were terminated at the end of the year 1980. In order to show that the R D termination was not due to technical difficulties of the reactor itself, the present paper describes the reactor plant concept, reactor performances, safety, economics and fuel cycle characteristics of the reactor, and also describes the reactor technologies developed so far, technological problems remained to be solved and planned development schedules of the reactor. (author)

  17. Comparison of various Brayton cycles for a Sodium-cooled Fast Reactor

    International Nuclear Information System (INIS)

    The nuclear energy is considered as one of the most realistic energy sources for both reducing the carbon dioxide emission and attaining sufficient and stable electricity supply for economy development. As a part of the nuclear energy development, many countries around the world are focusing on the next generation reactor development. One of the next generation reactors that is seriously being considered is the Sodium-cooled Fast Reactor (SFR). However, current SFR design faces the difficulty in public acceptance due to the potential threat from sodium-water reaction (SWR) when the current conventional steam Rankine cycle is utilized as a power conversion system for SFR. To substitute the violent sodium-water reaction with milder or no reaction, several Brayton cycle concepts including the S-CO2 cycle, helium cycle and nitrogen cycle are considered by many research organizations. This paper discusses these Brayton cycles'performance for SFR application compared to the current steam Rankine cycle

  18. Carbon dioxide retention in divers

    Energy Technology Data Exchange (ETDEWEB)

    Florio, J.T.; Mackenzie, D.A.R.; McKenzie, R.S. [ARE Physiological Laboratory, Gosport (United Kingdom)

    1998-04-01

    This report summarises the work carried out at the ARE Physiological Laboratory (ARE(PL)) between July 1978 and December 1983. The work was intended to examine the proposition that some divers have a low ventilatory response to carbon dioxide; that this results in a low ventilatory response to exercise with consequent hypercapnia; and that these characteristics put the diver at a greater-than-normal risk by increasing the individual`s susceptibility to oxygen toxicity and to other hazards associated with diving (e.g. nitrogen narcosis, decompression sickness and hypothermia). The specific aims of the project can be summarised as follows: (a) to demonstrate the existence of divers who exhibit the tendency to `retain carbon dioxide` when working in hyperbaric conditions; (b) to define the circumstances under which such individuals are at risk; (c) to assess the magnitude of the risk; and (d) to recommend ways to eliminate or to reduce the risk. (author)

  19. Summer Ice and Carbon Dioxide

    Science.gov (United States)

    Kukla, G.; Gavin, J.

    1981-10-01

    The extent of Antarctic pack ice in the summer, as charted from satellite imagery, decreased by 2.5 million square kilometers between 1973 and 1980. The U.S. Navy and Russian atlases and whaling and research ship reports from the 1930's indicate that summer ice conditions earlier in this century were heavier than the current average. Surface air temperatures along the seasonally shifting belt of melting snow between 55 degrees and 80 degrees N during spring and summer were higher in 1974 to 1978 than in 1934 to 1938. The observed departures in the two hemispheres qualitatively agree with the predicted impact of an increase in atmospheric carbon dioxide. However, since it is not known to what extent the changes in snow and ice cover and in temperature can be explained by the natural variability of the climate system or by other processes unrelated to carbon dioxide, a cause-and-effect relation cannot yet be established.

  20. Method for carbon dioxide sequestration

    Science.gov (United States)

    Wang, Yifeng; Bryan, Charles R.; Dewers, Thomas; Heath, Jason E.

    2015-09-22

    A method for geo-sequestration of a carbon dioxide includes selection of a target water-laden geological formation with low-permeability interbeds, providing an injection well into the formation and injecting supercritical carbon dioxide (SC--CO.sub.2) into the injection well under conditions of temperature, pressure and density selected to cause the fluid to enter the formation and splinter and/or form immobilized ganglia within the formation. This process allows for the immobilization of the injected SC--CO.sub.2 for very long times. The dispersal of scCO2 into small ganglia is accomplished by alternating injection of SC--CO.sub.2 and water. The injection rate is required to be high enough to ensure the SC--CO.sub.2 at the advancing front to be broken into pieces and small enough for immobilization through viscous instability.

  1. Oxygen and carbon dioxide sensing

    Science.gov (United States)

    Ren, Fan (Inventor); Pearton, Stephen John (Inventor)

    2012-01-01

    A high electron mobility transistor (HEMT) capable of performing as a CO.sub.2 or O.sub.2 sensor is disclosed, hi one implementation, a polymer solar cell can be connected to the HEMT for use in an infrared detection system. In a second implementation, a selective recognition layer can be provided on a gate region of the HEMT. For carbon dioxide sensing, the selective recognition layer can be, in one example, PEI/starch. For oxygen sensing, the selective recognition layer can be, in one example, indium zinc oxide (IZO). In one application, the HEMTs can be used for the detection of carbon dioxide and oxygen in exhaled breath or blood.

  2. Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Raghubir P. Gupta; William J. McMichael; Thomas Nelson; Santosh Gangwal; Ya Liang; Tyler Moore; Margaret Williams; Douglas P. Harrison

    2004-09-30

    sodium carbonate in these tests is initially very rapid and high degrees of removal are possible. The exothermic nature of the carbonation reaction resulted in a rise in bed temperature and subsequent decline in removal rate. Good temperature control, possibly through addition of supplemental water and evaporative cooling, appears to be the key to getting consistent carbon dioxide removal in a full-scale reactor system. The tendency of the alkali carbonate sorbents to cake on contact with liquid water complicates laboratory investigations as well as the design of larger scale systems. Also their low attrition resistance appears unsuitable for their use in dilute-phase transport reactor systems. Sodium and potassium carbonate have been incorporated in ceramic supports to obtain greater surface area and attrition resistance, using a laboratory spray dryer. The caking tendency is reduced and attrition resistance increased by supporting the sorbent. Supported sorbents with loading of up to 40 wt% sodium and potassium carbonate have been prepared and tested. These materials may improve the feasibility of large-scale CO{sub 2} capture systems based on short residence time dilute-phase transport reactor systems.

  3. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Raghubir P. Gupta; William J. McMichael; Thomas Nelson

    2004-11-01

    sodium carbonate in these tests is initially very rapid and high degrees of removal are possible. The exothermic nature of the carbonation reaction resulted in a rise in bed temperature and subsequent decline in removal rate. Good temperature control, possibly through addition of supplemental water and evaporative cooling, appears to be the key to getting consistent carbon dioxide removal in a full-scale reactor system. The tendency of the alkali carbonate sorbents to cake on contact with liquid water complicates laboratory investigations as well as the design of larger scale systems. Also their low attrition resistance appears unsuitable for their use in dilute-phase transport reactor systems. Sodium and potassium carbonate have been incorporated in ceramic supports to obtain greater surface area and attrition resistance, using a laboratory spray dryer. The caking tendency is reduced and attrition resistance increased by supporting the sorbent. Supported sorbents with loading of up to 40 wt% sodium and potassium carbonate have been prepared and tested. These materials may improve the feasibility of large-scale CO{sub 2} capture systems based on short residence time dilute-phase transport reactor systems.

  4. The oxygen and carbon dioxide balance in the earth's atmosphere

    Science.gov (United States)

    Johnson, F. S.

    1975-01-01

    The oxygen-carbon dioxide cycle is described in detail, and steps which are sensitive to perturbation or instability are identified. About half of the carbon dioxide consumption each year in photosynthesis occurs in the oceans. Phytoplankton, which are the primary producers, have been shown to assimilate insecticides and herbicides. The impact of such materials on phytoplankton photosynthesis, both direct and as the indirect result of detrimental effects higher up in the food chain, cannot be assessed. Net oxygen production is very small in comparison with the total production and occurs almost exclusively in a few ocean areas with anoxic bottom conditions and in peat-forming marshes which are sensitive to anthropogenic disturbances. The carbon dioxide content of the atmosphere is increasing at a relatively rapid rate as the result of fossil fuel combustion. Increases in photosynthesis as the result of the hothouse effect may in turn reduce the carbon dioxide content of the atmosphere, leading to global cooling.

  5. Cooling device upon reactor isolation

    International Nuclear Information System (INIS)

    A vacuum breaking valve is disposed to a sucking pipeline of vacuum pumps. A sucking port of the breaking valve is connected with an exhaustion side of a relief valve of a liquid nitrogen-filled tank by way of communication pipes. When a cooling device is operated upon reactor isolation and the vacuum pumps are operated, a three directional electromagnetic valve is operated, and nitrogen discharged out of the exhaustion port of the relief valve of the liquid nitrogen-filled tank is sent to a nitrogen releasing port on the suction side of the vacuum breaking valve by way of the communication pipes and released to atmosphere. When the pressure in the vacuum tank is excessively lowered in this state and the vacuum breaking valve is opened, nitrogen flows from the nitrogen discharge port into the vacuum tank through the breaking valve, and are sent to a pressure suppression chamber by the vacuum pumps. Since a great amount of nitrogen is sent to the pressure suppression chamber, and the inflow of the air is reduced, increase of oxygen concentration in the pressure suppression chamber can be suppressed. (I.N.)

  6. International symposium on evolutionary water cooled reactors: strategic issues, technologies and economic viability. Book of extended synopses

    International Nuclear Information System (INIS)

    Within the frame of growing energy demand caused by global economic growth and taking into account the Kyoto protocol on carbon dioxide emissions nuclear power plants attaining a new role. The presented papers deal mostly with improvements in NPP design, construction and safety. Some new concepts are proposed, especially in the field of inherent or passive reactor safety as well as computerised control systems. Water cooled reactors achieved already the necessary cost reduction but require some radical thinking in fuel design, construction rate, built-in safety. The key factor will be mass production in order to attain capital cost of half today's level

  7. Calcium carbonate decomposition in white-body tiles during firing in the presence of carbon dioxide

    OpenAIRE

    Escardino Benlloch, Agustín; Gómez Tena, María Pilar; Feliu Mingarro, Carlos; García Ten, Francisco Javier; Saburit Llaudis, Alejandro

    2013-01-01

    This study examines the thermal decomposition process of the calcium carbonate (calcite powder) contained in test pieces of porous ceramics, of the same composition as that used in manufacturing ceramic wall tile bodies, in the presence of carbon dioxide, in the temperature range 1123–1223 K. The experiments were carried out in a tubular reactor, under isothermal conditions, in a gas stream comprising different concentrations of air and carbon dioxide. Assuming that the relationship betwe...

  8. The Addition of Noncondensable Gases into RELAP5-3D for Analysis of High Temperature Gas-Cooled Reactors

    International Nuclear Information System (INIS)

    Oxygen, carbon dioxide, and carbon monoxide have been added to the RELAP5-3D computer code as noncondensable gases to support analysis of high temperature gas-cooled reactors. Models of these gases are required to simulate the effects of air ingress on graphite oxidation following a loss-of-coolant accident. Correlations were developed for specific internal energy, thermal conductivity, and viscosity for each gas at temperatures up to 3000 K. The existing model for internal energy (a quadratic function of temperature) was not sufficiently accurate at these high temperatures and was replaced by a more general, fourth-order polynomial. The maximum deviation between the correlations and the underlying data was 2.2% for the specific internal energy and 7% for the specific heat capacity at constant volume. The maximum deviation in the transport properties was 4% for oxygen and carbon monoxide and 12% for carbon dioxide

  9. Testing stand for cosmic gas-cooling fast reactor's sample

    International Nuclear Information System (INIS)

    For carrying out of technical decision and nuclear, radiation and technological safety of gas-cooling space nuclear power plants is elaborating gas-cooling fast reactor's testing stand. In the base of its draft is taken conception of the reactor with filling up type reactor core on the base of ball fuel elements and radial coolant flowing. On the testing stand would suggested carrying out testing for study neutron and physical parameters of gas-cooling reactor, its behaviour under accident simulation. In the reactor core will suggest use carbon nitrides fuel elements with tungsten cover, provides under nominal regime relatively low fission products yield to first contour of device. Construction of fuel element was carrying out on reactor and non reactor testing and its calculated on working resource about 3000 hours. Constructive materials of reactor core have lower melting temperature, that provides organized in good time remove fuel element to containers placed under reactor in case connected with hypothetical accident. In the construction of reactor for seen tree-contours system of heat transfer and its provides multistage system of barriers against fission products yield to environment. tabs.1

  10. Gas-cooled Fast Reactor (GFR) fuel and In-Core Fuel Management

    International Nuclear Information System (INIS)

    The Gas-Cooled Fast Reactor (GCFR) has been chosen as one of six candidates for development as a Generation IV nuclear reactor based on: its ability to fully utilize fuel resources; minimize or reduce its own (and other systems) actinide inventory; produce high efficiency electricity; and the possibility to utilize high temperature process heat. Current design approaches include a high temperature (2 850 C) helium cooled reactor using a direct Brayton cycle, and a moderate temperature (550 C - 650 C) helium or supercritical carbon dioxide (S-CO2) cooled reactor using direct or indirect Brayton cycles. These design choices have thermal efficiencies that approach 45% to 50%, and have turbomachinery sizes that are much more compact compared to steam plants. However, there are challenges associated with the GCFR, which are the focus of current research. This includes safety system design for decay heat removal, development of high temperature/high fluence fuels and materials, and development of fuel cycle strategies. The work presented here focuses on the fuel and preliminary in-core fuel management, where advanced ceramic-ceramic (cercer) dispersion fuels are the main focus, and average burnups to 266 M Wd/kg appear achievable for the reference Si C/(U,TRU)C block/plate fuel. Solid solution (pellet) fuel in composite ceramic clad (Si C/Si C) is also being considered, but remains as a backup due to cladding fabrication challenges, and high centerline temperatures in the fuel. (Author)

  11. Gas-cooled Fast Reactor (GFR) fuel and In-Core Fuel Management

    Energy Technology Data Exchange (ETDEWEB)

    Weaver, K.D.; Sterbentz, J. [Idaho National Engineering and Environmental Laboratory, P.O. Box 1625, Idaho Falls, Idaho 83415-3850 (United States); Meyer, M. [Argonne National Laboratory- West (United States); Lowden, R. [Oak Ridge National Laboratory (United States); Hoffman, E.; Wei, T.Y.C. [Argonne National Laboratory (United States)]. e-mail: weavkd@inel.gov

    2004-07-01

    The Gas-Cooled Fast Reactor (GCFR) has been chosen as one of six candidates for development as a Generation IV nuclear reactor based on: its ability to fully utilize fuel resources; minimize or reduce its own (and other systems) actinide inventory; produce high efficiency electricity; and the possibility to utilize high temperature process heat. Current design approaches include a high temperature (2 850 C) helium cooled reactor using a direct Brayton cycle, and a moderate temperature (550 C - 650 C) helium or supercritical carbon dioxide (S-CO{sub 2}) cooled reactor using direct or indirect Brayton cycles. These design choices have thermal efficiencies that approach 45% to 50%, and have turbomachinery sizes that are much more compact compared to steam plants. However, there are challenges associated with the GCFR, which are the focus of current research. This includes safety system design for decay heat removal, development of high temperature/high fluence fuels and materials, and development of fuel cycle strategies. The work presented here focuses on the fuel and preliminary in-core fuel management, where advanced ceramic-ceramic (cercer) dispersion fuels are the main focus, and average burnups to 266 M Wd/kg appear achievable for the reference Si C/(U,TRU)C block/plate fuel. Solid solution (pellet) fuel in composite ceramic clad (Si C/Si C) is also being considered, but remains as a backup due to cladding fabrication challenges, and high centerline temperatures in the fuel. (Author)

  12. Optimal design study of cylindrical finned reactor for solar adsorption cooling machine working with activated carbon-ammonia pair

    International Nuclear Information System (INIS)

    This paper presents a model describing the heat and mass transfer in cylindrical finned reactor of solar adsorption refrigerator. Giving the meteorological data as boundary conditions on the reactor; the model computes the solar coefficient of performance (COPs). The validity of the model has been tested by using experimental results. An analysis of the sensitivity of the COPs versus the geometrical parameters of the reactor (radius of the reactor, fins thickness and fins number) is mad. Then the model is applied to optimize the solar reactor. The COPs is used as an optimization criterion. The geometrical parameters where the COPs of the machine reach a maximum have been calculated

  13. Absorption of carbon dioxide in waste tanks

    International Nuclear Information System (INIS)

    Air flow rates and carbon dioxide concentrations of air entering and exiting eight H-Area waste tanks were monitored for a period of one year. The average instanteous concentration of carbon dioxide in air is within the range reported offsite, and therefore is not affect by operation of the coal-fired power plant adjacent to the tank farm. Waste solutions in each of the tanks were observed to be continuously absorbing carbon dioxide. The rate of absorption of carbon dioxide decreased linearly with the pH of the solution. Personnel exposure associated with the routine sampling and analysis of radioactive wastes stored at SRP to determine the levels of corrosion inhibitors in solution could be reduced by monitoring the absorption of carbon dioxide and using the relationship between pH and carbon dioxide absorption to determine the free hydroxide concentration in solution

  14. Kinetic of formation for single carbon dioxide and mixed carbon dioxide and tetrahydrofuran hydrates in water and sodium chloride aqueous solution

    NARCIS (Netherlands)

    Sabil, K.M.; Duarte, A.R.C.; Zevenbergen, J.F.; Ahmad, M.M.; Yusup, S.; Omar, A.A.; Peters, C.J.

    2010-01-01

    A laboratory-scale reactor system is built and operated to measure the kinetic of formation for single and mixed carbon dioxide-tetrahydrofuran hydrates. The T-cycle method, which is used to collect the kinetic data, is briefly discussed. For single carbon dioxide hydrate, the induction time decreas

  15. Gas-cooled reactors and their applications

    International Nuclear Information System (INIS)

    The purpose of the meeting was to review and discuss the current status and recent progress made in the technology and design of gas-cooled reactors and their application for electricity generation, process steam and process heat production. The meeting was attended by more than 200 participants from 25 countries and International Organizations presenting 34 papers. The technical part of the meeting was subdivided into 7 sessions: A. Overview of the Status of Gas-Cooled Reactors and Their Prospects (2 papers); B. Experience with Gas-Cooled Reactors (5 papers); C. Description of Current GCR Plant Designs (10 papers); D. Safety Aspects (4 papers); E. Gas-Cooled Reactor Applications (3 papers); F. Gas-Cooled Reactor Technology (6 papers); G. User's Perspectives on Gas-Cooled Reactors (4 papers). At the end of the meeting a round table discussion was organized in order to summarize the meeting and to make recommendations for future activities. A separate abstract was prepared for each of the 34 presentations of this meeting. Refs, figs and tabs

  16. Transformation and utilization of carbon dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Bhanage, Bhalchandra M. [Institute of Chemical Technology, Mumbai (India). Dept. of Chemistry; Arai, Masahiko (ed.) [Hokkaido Univ., Sapporo (Japan). Division of Chemical Process Engineering

    2014-04-01

    This book shows the various organic, polymeric and inorganic compounds which result from the transformation of carbon dioxide through chemical, photocatalytic, electrochemical, inorganic and biological processes. The book consists of twelve chapters demonstrating interesting examples of these reactions, depending on the types of reaction and catalyst. It also includes two chapters dealing with the utilization of carbon dioxide as a reaction promoter and presents a wide range of examples of chemistry and chemical engineering with carbon dioxide.

  17. 21 CFR 184.1240 - Carbon dioxide.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Carbon dioxide. 184.1240 Section 184.1240 Food and... Substances Affirmed as GRAS § 184.1240 Carbon dioxide. (a) Carbon dioxide (empirical formula CO2, CAS Reg. No.... The solid form, dry ice, sublimes under atmospheric pressure at a temperature of −78.5 °C....

  18. Regeneration of oxygen from carbon dioxide and water.

    Science.gov (United States)

    Weissbart, J.; Smart, W. H.; Wydeven, T.

    1972-01-01

    In a closed ecological system it is necessary to reclaim most of the oxygen required for breathing from respired carbon dioxide and the remainder from waste water. One of the advanced physicochemical systems being developed for generating oxygen in manned spacecraft is the solid electrolyte-electrolysis system. The solid electrolyte system consists of two basic units, an electrolyzer and a carbon monoxide disproportionator. The electrolyzer can reclaim oxygen from both carbon dioxide and water. Electrolyzer preparation and assembly are discussed together with questions of reactor design and electrolyzer performance data.

  19. Thermal calculations for water cooled research reactors

    International Nuclear Information System (INIS)

    The formulae and the more important numerical data necessary for thermic calculations on the core of a research reactor, cooled with low pressure water, are presented. Most of the problems met by the designer and the operator are dealt with (calculations margins, cooling after shut-down). Particular cases are considered (gas release, rough walls, asymmetric cooling slabs etc.), which are not generally envisaged in works on general thermics

  20. Carbon dioxide-guided angioplasty

    International Nuclear Information System (INIS)

    Revascularization procedures are frequently necessary in patients with severe peripheral vascular disease and renal insufficiency (often coexistent with diabetes mellitus). This paper examines the use of carbon dioxide as the contrast agent in percutaneous revascularization procedures (balloon angioplasty). Over the past 10 months, our protocol has used CO2 as the contrast agent for balloon angioplasty in a select group of patients (n = 12) with peripheral vascular disease and renal insufficiency. Some had coexistent diabetes mellitus. With digital subtraction angiography, CO2 was the only contrast agent used during revascularization. Pressure gradients were obtained in appropriate patients

  1. Adaptation of phytoplankton-degrading microbial communities to thermal reactor effluent in a new cooling reservoir

    International Nuclear Information System (INIS)

    In water column and sediment inocula from a nuclear reactor cooling reservoir, natural phytoplankton substrate labeled with 14C was used to determine aerobic and anaerobic mineralization rates for a range of temperatures (25, 40, 55, and 700C) expected during reactor operation. For experiments that were begun during reactor shutdown, aerobic decomposition occurred at temperatures of 0C. After two months of reactor operation, aerobic rates increased substantially at 55 and 700C, although maximum rates were observed at temperatures of ≤ 400C. The temperature range for which maximum anaerobic mineralization (i.e., the sum of CH4 and CO2) was observed was 25 to 400C when the reactor was off, expanding to 25 to 550C during reactor operation. Increased rates of 550C, but not 700C, correlated with an increase in the ratio of cumulative methane to carbon dioxide produced over 21 days. When reduced reactor power lowered the maximum temperature of the reservoir to 420C, aerobic decomposition at 700C was negligible, but remained substantial at 550C. Selection for thermophilic decomposers occurred rapidly in this system in both aerobic and anaerobic communities and did not require prolonged exposure to elevated temperatures

  2. Facilitating Conceptual Understanding of Gas-Liquid Mass Transfer Coefficient through a Simple Experiment Involving Dissolution of Carbon Dioxide in Water in a Surface Aeration Reactor

    Science.gov (United States)

    Utgikar, Vivek P.; MacPherson, David

    2016-01-01

    Students in the undergraduate "transport phenomena" courses typically have a greater difficulty in understanding the theoretical concepts underlying the mass transport phenomena as compared to the concepts of momentum and energy transport. An experiment based on dissolution of carbon dioxide in water was added to the course syllabus to…

  3. French activities on gas cooled reactors

    International Nuclear Information System (INIS)

    The gas cooled reactor programme in France originally consisted of eight Natural Uranium Graphite Gas Cooled Reactors (UNGG). These eight units, which are now permanently shutdown, represented a combined net electrical power of 2,375 MW and a total operational history of 163 years. Studies related to these reactors concern monitoring and dismantling of decommissioned facilities, including the development of methods for dismantling. France has been monitoring the development of HTRs throughout the world since 1979, when it halted its own HTR R and D programme. France actively participates in three CRPs set up by the IAEA. (author). 1 tab

  4. Technological innovations for FBR reactor cooling system

    International Nuclear Information System (INIS)

    The fast breeder reactor (FBR) is expected to be commercialized early in the 21st century. In order to realize this goal, technological innovations are desired in order to extensively enhance economic performance, and improvement of the reactor cooling system is of primary importance in this regard. Over the past 10 years, Toshiba has developed a succession of new technologies in the field of reactor cooling systems, including a compact type intermediate heat exchanger (IHX), an integral once-through type steam generator (SG), a double-wall-tube type steam generator, and a sodium-immersed high-temperature type electromagnetic pump (EMP). As a synthesis of the fruits of such research and development we have formulated innovative concepts for a reactor cooling system and its constituent components. These advances in research and development activities will significantly contribute to the commercialization of FBRs. (author)

  5. IAEA high temperature gas cooled reactor activities

    International Nuclear Information System (INIS)

    IAEA activities on high temperature gas cooled reactors are conducted with the review and support of Member States, primarily through the International Working Group on Gas Cooled Reactors (IWGGCR). This paper summarises the results of the IAEA gas cooled reactor project activities in recent years along with ongoing current activities through a review of Co-ordinated Research Projects (CRPs), meetings and other international efforts. A series of three recently completed CRPs have addressed the key areas of reactor physics for LEU fuel, retention of fission products, and removal of post shutdown decay heat through passive heat transport mechanisms. These activities along with other completed and ongoing supporting CRPs and meetings are summarised with reference to detailed documentation of the results. (author)

  6. Nuclear Reactor RA Safety Report, Vol. 5, Reactor cooling systems

    International Nuclear Information System (INIS)

    RA reactor cooling system enable cooling during normal operation and under possible accidental conditions and include: technical water system, heavy water system, helium gas system, system for heavy water purification and emergency cooling system. Primary cooling system is a closed heavy water circulation system. Heavy water system is designed to enable permanent circulation and twofold function of heavy water. In the upward direction of cooling it has a coolant role and in the downward direction it is the moderator. Separate part of the primary coolant loop is the system for heavy water purification. This system uses distillation and ion exchange processes

  7. Carbon dioxide reducing processes; Koldioxidreducerande processer

    Energy Technology Data Exchange (ETDEWEB)

    Svensson, Fredrik

    1999-12-01

    This thesis discusses different technologies to reduce or eliminate the carbon dioxide emissions, when a fossil fuel is used for energy production. Emission reduction can be accomplished by separating the carbon dioxide for storage or reuse. There are three different ways of doing the separation. The carbon dioxide can be separated before the combustion, the process can be designed so that the carbon dioxide can be separated without any energy consumption and costly systems or the carbon dioxide can be separated from the flue gas stream. Two different concepts of separating the carbon dioxide from a combined cycle are compared, from the performance and the economical point of view, with a standard natural gas fired combined cycle where no attempts are made to reduce the carbon dioxide emissions. One concept is to use absorption technologies to separate the carbon dioxide from the flue gas stream. The other concept is based on a semi-closed gas turbine cycle using carbon dioxide as working fluid and combustion with pure oxygen, generated in an air-separating unit. The calculations show that the efficiency (power) drop is smaller for the first concept than for the second, 8.7 % points compared to 13.7 % points, when power is produced. When both heat and power are produced, the relation concerning the efficiency (power) remains. Regarding the overall efficiency (heat and power) the opposite relation is present. A possible carbon dioxide tax must exceed 0.21 SEK/kg CO{sub 2} for it to be profitable to separate carbon dioxide with any of these technologies.

  8. Carbon Dioxide Reforming of Methane to Syngas by Thermal Plasma

    Institute of Scientific and Technical Information of China (English)

    孙艳朋; 聂勇; 吴昂山; 姬登祥; 于凤文; 计建炳

    2012-01-01

    Experiments were conducted on syngas preparation from dry reforming of methane by carbon dioxide with a DC arc plasma at atmospheric pressure. In all experiments, nitrogen gas was used as the working gas for thermal plasma to generate a high-temperature jet into a horizontal tube reactor. A mixture of methane and carbon dioxide was fed vertically into the jet. In order to obtain a higher conversion rate of methane and carbon dioxide, chemical energy efficiency and fuel production efficiency, parametric screening studies were conducted, in which the volume ratio of carbon dioxide to methane in fed gases and the total flux of fed gases were taken into account. Results showed that carbon dioxide reforming of methane to syngas by thermal plasma exhibited a larger processing capacity, higher conversion of methane and carbon dioxide and higher chemical energy efficiency and fuel production efficiency. In addition, thermodynamic simulation for the reforming process was conducted. Experimental data agreed well with the thermodynamic results, indicating that high thermal efficiency can be achieved with the thermal plasma reforming process.

  9. Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor

    International Nuclear Information System (INIS)

    Three groups of hydrate-bearing sediment samples with/without underlying gas were prepared using a three-dimensional middle-size reactor to investigate the favorable conditions for methane recovery from hydrate reservoir with gaseous CO2. The experimental results indicated that hydrate reservoir with underlying free gas, high saturation of free gas and low saturation of water is appropriate for recovering CH4 with CO2. For the replacement mechanism, it is assumed that the CO2–CH4 replacement chiefly includes two parts: CH4 hydrate dissociation and mixed hydrate re-formation from the dissociated water and free water. In the re-formed hydrate, CO2 molecules mainly occupy the large cage and CH4 molecules mainly occupy the small cage. A kinetics model was constructed to describe the replacement process, which considers not only the kinetic reaction of CH4–CO2 replacement but also the reaction between CO2 and free water. The calculated results agree well with the experimental data. The influencing factors on the replacement rate were also discussed according to the developed model. It is found that the replacement rate and the mole fraction of CH4 in gas phase increase with the increase of initial CO2 mole fraction, the decrease of system pressure, and the increase of diffusion coefficient of CH4 in hydrate layer. -- Highlights: ► Three classes of hydrate reservoir samples are prepared using a three-dimensional reactor. ► For reservoir class with low water saturation, the replacement effect is encouraged. ► CO2–CH4 replacement includes CH4 hydrate dissociation and mixed hydrate re-formation. ► A kinetics model was constructed to describe the replacement process.

  10. Carbon dioxide disposal in solid form

    Energy Technology Data Exchange (ETDEWEB)

    Lackner, K.S.; Butt, D.P.; Sharp, D.H. [Los Alamos National Lab., NM (United States); Wendt, C.H. [Auxon Corp., (United States)

    1995-12-31

    Coal reserves can provide for the world`s energy needs for centuries. However, coal`s long term use may be severely curtailed if the emission of carbon dioxide into the atmosphere is not eliminated. We present a safe and permanent method of carbon dioxide disposal that is based on combining carbon dioxide chemically with abundant raw materials to form stable carbonate minerals. We discuss the availability of raw materials and potential process designs. We consider our initial rough cost estimate of about 3{cents}/kWh encouraging. The availability of a carbon dioxide fixation technology would serve as insurance in case global warming, or the perception of global warming, causes severe restrictions on carbon dioxide emissions. If the increased energy demand of a growing world population is to be satisfied from coal, the implementation of such a technology would quite likely be unavoidable.

  11. Robust optical carbon dioxide isotope analyzer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Isotopic analysis of carbon dioxide is an important tool for characterization of the exchange and transformation of carbon between the biosphere and the atmosphere....

  12. Supercritical-pressure light water cooled reactors

    CERN Document Server

    Oka, Yoshiaki

    2014-01-01

    This book focuses on the latest reactor concepts, single pass core and experimental findings in thermal hydraulics, materials, corrosion, and water chemistry. It highlights research on supercritical-pressure light water cooled reactors (SCWRs), one of the Generation IV reactors that are studied around the world. This book includes cladding material development and experimental findings on heat transfer, corrosion and water chemistry. The work presented here will help readers to understand the fundamental elements of reactor design and analysis methods, thermal hydraulics, materials and water

  13. Carbon dioxide production in animal houses

    DEFF Research Database (Denmark)

    Pedersen, Søren; Blanes-Vidal, Victoria; Joergensen, H.;

    2008-01-01

    This article deals with carbon dioxide production from farm animals; more specifically, it addresses the possibilities of using the measured carbon dioxide concentration in animal houses as basis for estimation of ventilation flow (as the ventilation flow is a key parameter of aerial emissions from...... animal houses). The investigations include measurements in respiration chambers and in animal houses, mainly for growing pigs and broilers. Over the last decade a fixed carbon dioxide production of 185 litres per hour per heat production unit, hpu (i.e. 1000 W of the total animal heat production at 20o......C) has often been used. The article shows that the carbon dioxide production per hpu increases with increasing respiration quotient. As the respiration quotient increases with body mass for growing animals, the carbon dioxide production per heat production unit also increases with increased body mass...

  14. Gas-cooled reactor for space power systems

    International Nuclear Information System (INIS)

    Reactor characteristics based on extensive development work on the 500-MWt reactor for the Pluto nuclear ramjet are described for space power systems useful in the range of 2 to 20 MWe for operating times of 1 y. The modest pressure drop through the prismatic ceramic core is supported at the outlet end by a ceramic dome which also serves as a neutron reflector. Three core materials are considered which are useful at temperatures up to about 2000 K. Most of the calculations are based on a beryllium oxide with uranium dioxide core. Reactor control is accomplished by use of a burnable poison, a variable-leakage reflector, and internal control rods. Reactivity swings of 20% are obtained with a dozen internal boron-10 rods for the size cores studied. Criticality calculations were performed using the ALICE Monte Carlo code. The inherent high-temperature capability of the reactor design removes the reactor as a limiting condition on system performance. The low fuel inventories required, particularly for beryllium oxide reactors, make space power systems based on gas-cooled near-thermal reactors a lesser safeguard risk than those based on fast reactors

  15. Encapsulated liquid sorbents for carbon dioxide capture

    Science.gov (United States)

    Vericella, John J.; Baker, Sarah E.; Stolaroff, Joshuah K.; Duoss, Eric B.; Hardin, James O.; Lewicki, James; Glogowski, Elizabeth; Floyd, William C.; Valdez, Carlos A.; Smith, William L.; Satcher, Joe H.; Bourcier, William L.; Spadaccini, Christopher M.; Lewis, Jennifer A.; Aines, Roger D.

    2015-02-01

    Drawbacks of current carbon dioxide capture methods include corrosivity, evaporative losses and fouling. Separating the capture solvent from infrastructure and effluent gases via microencapsulation provides possible solutions to these issues. Here we report carbon capture materials that may enable low-cost and energy-efficient capture of carbon dioxide from flue gas. Polymer microcapsules composed of liquid carbonate cores and highly permeable silicone shells are produced by microfluidic assembly. This motif couples the capacity and selectivity of liquid sorbents with high surface area to facilitate rapid and controlled carbon dioxide uptake and release over repeated cycles. While mass transport across the capsule shell is slightly lower relative to neat liquid sorbents, the surface area enhancement gained via encapsulation provides an order-of-magnitude increase in carbon dioxide absorption rates for a given sorbent mass. The microcapsules are stable under typical industrial operating conditions and may be used in supported packing and fluidized beds for large-scale carbon capture.

  16. Materials for advanced water cooled reactors

    International Nuclear Information System (INIS)

    The current IAEA programme in advanced nuclear power technology promotes technical information exchange between Member States with major development programmes. The International Working Group on Advanced Technologies for Water Cooled Reactors recommended to organize a Technical Committee Meeting for the purpose of providing an international forum for technical specialists to review and discuss aspects regarding development trends in material application for advanced water cooled reactors. The experience gained from the operation of current water cooled reactors, and results from related research and development programmes, should be the basis for future improvements of material properties and applications. This meeting enabled specialists to exchange knowledge about structural materials application in the nuclear island for the next generation of nuclear power plants. Refs, figs, tabs

  17. Design challenges for sodium cooled fast reactors

    International Nuclear Information System (INIS)

    It is of vital importance for commercialized fast reactor to achieve component design with excellent integrity and economics. In the phase II of feasibility study till 2005, a system design for commercialized fast reactor for sodium cooling was achieved. For economical improvement, the system design was undertaken along the guideline including innovative technology for system simplification and new material development. In this paper, the results from the design for shortening of cooling pipings, new components and three dimensional seismic isolation are described, which are design challenges for the sodium cooled fast reactor. Furthermore, in-service inspection and repair is mentioned. Finally, economics for the simplification and the mass reduction employing above technologies are examined

  18. Carbon dioxide cleaning pilot project

    International Nuclear Information System (INIS)

    In 1989, radioactive-contaminated metal at the Rocky Flats Plant (RFP) was cleaned using a solvent paint stripper (Methylene chloride). One-third of the radioactive material was able to be recycled; two-thirds went to the scrap pile as low-level mixed waste. In addition, waste solvent solutions also required disposal. Not only was this an inefficient process, it was later prohibited by the Resource Conservation and Recovery Act (RCRA), 40 CFR 268. A better way of doing business was needed. In the search for a solution to this situation, it was decided to study the advantages of using a new technology - pelletized carbon dioxide cleaning. A proof of principle demonstration occurred in December 1990 to test whether such a system could clean radioactive-contaminated metal. The proof of principle demonstration was expanded in June 1992 with a pilot project. The purpose of the pilot project was three fold: (1) to clean metal so that it can satisfy free release criteria for residual radioactive contamination at the Rocky Flats Plant (RFP); (2) to compare two different carbon dioxide cleaning systems; and (3) to determine the cost-effectiveness of decontamination process in a production situation and compare the cost of shipping the metal off site for waste disposal. The pilot project was completed in August 1993. The results of the pilot project were: (1) 90% of those items which were decontaminated, successfully met the free release criteria , (2) the Alpheus Model 250 was selected to be used on plantsite and (3) the break even cost of decontaminating the metal vs shipping the contaminated material offsite for disposal was a cleaning rate of 90 pounds per hour, which was easily achieved

  19. Liquid-cooled nuclear reactor

    International Nuclear Information System (INIS)

    Hydrogen can be added to nuclear reactors with a liquid hydrogen-containing coolant on the suction side of a high pressure pump in the purification system. According to the invention this is performed by means of a liquid jet condenser which uses the coolant as liquid and which is preferably charged from the pressure side of the high pressure pump and conveys the liquid to a mixer connected in series with the high pressure pump. The invention is to be used especially in pressurized water reactors. (orig./PW)

  20. Liquid-cooled nuclear reactor

    International Nuclear Information System (INIS)

    Hydrogen can be added to nuclear reactors with a liquid hydrogen-containing coolant on the suction side of a high pressure pump in the purification system. According to the invention this is performed by means of a liquid jet condenser which uses the coolant as liquid and which is preferably charged from the pressure side of the high pressure pump and conveys the liquid to a mixer connected in series with the high pressure pump. The invention is to be used especially in pressurized water reactors. (orig.)

  1. Liquid metal cooled nuclear reactor constructions

    International Nuclear Information System (INIS)

    A liquid metal cooled nuclear reactor construction is described comprising a reactor core submerged in a pool of liquid metal coolant contained in a vessel which is housed in a concrete containment vault, the roof structure of the vault having thermal insulation comprising a series of super-imposed spaced plates, with baffles disposed so as to restrict convectional flow of metal vapour through the interspaces of the plates and between the uppermost plate or plates and the vault roof structure. (author)

  2. Process evaluation of use of high temperature gas-cooled reactors to an ironmaking system based on active carbon recycling energy system

    International Nuclear Information System (INIS)

    Reducing coking coal consumption and CO2 emissions by application of iACRES (ironmaking system based on active carbon recycling energy system) was investigated using process flow modeling to show effectiveness of HTGRs (high temperature gas-cooled reactors) adoption to iACRES. Two systems were evaluated: a SOEC (solid oxide electrolysis cell) system using CO2 electrolysis and a RWGS (reverse water-gas shift reaction) system using RWGS reaction with H2 produced by iodine-sulfur process. Both reduction of the coking coal consumption and CO2 emissions were greater in the RWGS system than those in the SOEC system. It was the reason of the result that excess H2 not consumed in the RWGS reaction was used as reducing agent in the blast furnace as well as CO. Heat balance in the HTGR, SOEC and RWGS modules were evaluated to clarify process components to be improved. Optimization of the SOEC temperature was desired to reduce Joule heat input for high efficiency operation of the SOEC system. Higher H2 production thermal efficiency in the IS process for the RWGS system is effective for more efficient HTGR heat utilization. The SOEC system was able to utilize HTGR heat to reduce CO2 emissions more efficiently by comparing CO2 emissions reduction per unit heat of the HTGR. (author)

  3. Development of a Supercritical Carbon Dioxide Brayton Cycle: Improving VHTR Efficiency and Testing Material Compatibility - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Chang H. Oh

    2006-06-01

    Generation IV reactors will need to be intrinsically safe, having a proliferation-resistant fuel cycle and several advantages relative to existing light water reactor (LWR). They, however, must still overcome certain technical issues and the cost barrier before it can be built in the U.S. The establishment of a nuclear power cost goal of 3.3 cents/kWh is desirable in order to compete with fossil combined-cycle, gas turbine power generation. This goal requires approximately a 30 percent reduction in power cost for stateof-the-art nuclear plants. It has been demonstrated that this large cost differential can be overcome only by technology improvements that lead to a combination of better efficiency and more compatible reactor materials. The objectives of this research are (1) to develop a supercritical carbon dioxide Brayton cycle in the secondary power conversion side that can be applied to the Very-High-Temperature Gas-Cooled Reactor (VHTR), (2) to improve the plant net efficiency by using the carbon dioxide Brayton cycle, and (3) to test material compatibility at high temperatures and pressures. The reduced volumetric flow rate of carbon dioxide due to higher density compared to helium will reduce compression work, which eventually increase plant net efficiency.

  4. Thermohydraulic relationships for advanced water cooled reactors

    International Nuclear Information System (INIS)

    This report was prepared in the context of the IAEA's Co-ordinated Research Project (CRP) on Thermohydraulic Relationships for Advanced Water Cooled Reactors, which was started in 1995 with the overall goal of promoting information exchange and co-operation in establishing a consistent set of thermohydraulic relationships which are appropriate for use in analyzing the performance and safety of advanced water cooled reactors. For advanced water cooled reactors, some key thermohydraulic phenomena are critical heat flux (CHF) and post CHF heat transfer, pressure drop under low flow and low pressure conditions, flow and heat transport by natural circulation, condensation of steam in the presence of non-condensables, thermal stratification and mixing in large pools, gravity driven reflooding, and potential flow instabilities. The objectives of the CRP are (1) to systematically list the requirements for thermohydraulic relationships in support of advanced water cooled reactors during normal and accident conditions, and provide details of their database where possible and (2) to recommend and document a consistent set of thermohydraulic relationships for selected thermohydraulic phenomena such as CHF and post-CHF heat transfer, pressure drop, and passive cooling for advanced water cooled reactors. Chapter 1 provides a brief discussion of the background for this CRP, the CRP objectives and lists the participating institutes. Chapter 2 provides a summary of important and relevant thermohydraulic phenomena for advanced water cooled reactors on the basis of previous work by the international community. Chapter 3 provides details of the database for critical heat flux, and recommends a prediction method which has been established through international co-operation and assessed within this CRP. Chapter 4 provides details of the database for film boiling heat transfer, and presents three methods for predicting film boiling heat transfer coefficients developed by institutes

  5. High-temperature gas-cooled-reactor steam-methane reformer design

    International Nuclear Information System (INIS)

    The concept of the long distance transportation of process heat energy from a High Temperature Gas Cooled Reactor (HTGR) heat source, based on the steam reforming reaction, is currently being evaluated as an energy source/application for use early in the 21st century. The steam-methane reforming reaction is an endothermic reaction at temperatures approximately 7000C and higher, which produces hydrogen, carbon monoxide and carbon dioxide. The heat of the reaction products can then be released, after being pumped to industrial site users, in a methanation process producing superheated steam and methane which is then returned to the reactor plant site. In this application the steam reforming reaction temperatures are produced by the heat energy from the core of the HTGR through forced convection of the primary or secondary helium circuit to the catalytic chemical reactor (steam reformer). This paper summarizes the design of a helium heated steam reformer utilized in conjunction with a 1170 MW(t) intermediate loop, 8500C reactor outlet temperature, HTGR process heat plant concept. This paper also discusses various design considerations leading to the mechanical design features, the thermochemical performance, materials selection and the structural design analysis

  6. Neutronic of heterogenous gas cooled reactors

    International Nuclear Information System (INIS)

    At present, one of the main technical features of the advanced gas cooled reactor under development is its fuel element concept, which implies a neutronic homogeneous design, thus requiring higher enrichment compared with present commercial nuclear power plants.In this work a neutronic heterogeneous gas cooled reactor design is analyzed by studying the neutronic design of the Advanced Gas cooled Reactor (AGR), a low enrichment, gas cooled and graphite moderated nuclear power plant.A search of merit figures (some neutronic parameter, characteristic dimension, or a mixture of both) which are important and have been optimized during the reactor design stage is been done, to aim to comprise how a gas heterogeneous reactor is been design, given that semi-infinity arrangement criteria of rods in LWRs and clusters in HWRs can t be applied for a solid moderator and a gas refrigerator.The WIMS code for neutronic cell calculations is been utilized to model the AGR fuel cell and to calculate neutronic parameters such as the multiplication factor and the pick factor, as function of the fuel burnup.Also calculation is been done for various nucleus characteristic dimensions values (fuel pin radius, fuel channel pitch) and neutronic parameters (such as fuel enrichment), around the design established parameters values.A fuel cycle cost analysis is carried out according to the reactor in study, and the enrichment effect over it is been studied.Finally, a thermal stability analysis is been done, in subcritical condition and at power level, to study this reactor characteristic reactivity coefficients.Present results shows (considering the approximation used) a first set of neutronic design figures of merit consistent with the AGR design.

  7. Perspectives of nuclear power and carbon dioxide abatement

    International Nuclear Information System (INIS)

    The papers presented at the conference particularly look at reactor safety aspects and nuclear power programmes worldwide, which are discussed in connection with the demand for ensuring power supplies in the future, and reducing atmospheric pollution by carbon dioxide. The CO2 problem as it is encountered at present and strategies for CO2 abatement are explained in some papers, whereas other papers are concerned with nuclear power reactors and the related major aspects of safety engineering, nuclear fuel supply and radioactive waste management, and further development of nuclear installations, comparing the technical details and pro and cons of LWR, HTR, and breeder reactor programmes. (DG)

  8. Mixed oxide fuel for water cooled reactors

    International Nuclear Information System (INIS)

    The problems connected with introduction of plutonium extracted from spent fuels of operating NPPs into water cooled reactor fuel cycle are considered. The trends in formation of the World market of mixed fuel are illustrated taking as examples Great Britain and Japan

  9. Coolant technology of water cooled reactors. V. 1: Chemistry of primary coolant in water cooled reactors

    International Nuclear Information System (INIS)

    This report is a summary of the work performed within the framework of the Coordinated Research Programme on Investigations on Water Chemistry Control and Coolant Interaction with Fuel and Primary Circuit Materials in Water Cooled Power Reactors organized by the IAEA and carried out from 1987 to 1991. It is the continuation of a programme entitled Reactor Water Chemistry Relevant to Coolant-Cladding Interaction (IAEA-TECDOC-429), which ran from 1981 to 1986. Subsequent meetings resulted in the title of the programme being changed to Coolant Technology of Water Cooled Reactors. The results of this Coordinated Research Programme are published in four volumes with an overview in the Technical Reports Series. The titles of the volumes are: Volume 1: Chemistry of Primary Coolant in Water Cooled Reactors; Volume 2: Corrosion in the Primary Coolant Systems of Water Cooled Reactors; Volume 3: Activity Transport Mechanisms in Water Cooled Reactors; Volume 4: Decontamination of Water Cooled Reactors. These publications should be of interest to experts in water chemistry at nuclear power plants, experts in engineering, fuel designers, research and development institutes active in the field and to consultants to these organizations. Refs, figs and tabs

  10. Heavy water moderated gas-cooled reactors

    International Nuclear Information System (INIS)

    France has based its main effort for the production of nuclear energy on natural Uranium Graphite-moderated gas-cooled reactors, and has a long term programme for fast reactors, but this country is also engaged in the development of heavy water moderated gas-cooled reactors which appear to present the best middle term prospects. The economy of these reactors, as in the case of Graphite, arises from the use of natural or very slightly enriched Uranium; heavy water can take the best advantages of this fuel cycle and moreover offers considerable development potential because of better reactor performances. A prototype plant EL 4 (70 MW) is under construction and is described in detail in another paper. The present one deals with the programme devoted to the development of this reactor type in France. Reasons for selecting this reactor type are given in the first part: advantages and difficulties are underlined. After reviewing the main technological problems and the Research and Development carried out, results already obtained and points still to be confirmed are reported. The construction of EL 4 is an important step of this programme: it will be a significant demonstration of reactor performances and will afford many experimentation opportunities. Now the design of large power reactors is to be considered. Extension and improvements of the mechanical structures used for EL 4 are under study, as well as alternative concepts. The paper gives some data for a large reactor in the present state of technology, as a result from optimization studies. Technical improvements, especially in the field of materials could lead to even more interesting performances. Some prospects are mentioned for the long run. Investment costs and fuel cycles are discussed in the last part. (authors)

  11. Carbon dioxide conversion over carbon-based nanocatalysts.

    Science.gov (United States)

    Khavarian, Mehrnoush; Chai, Siang-Piao; Mohamed, Abdul Rahman

    2013-07-01

    The utilization of carbon dioxide for the production of valuable chemicals via catalysts is one of the efficient ways to mitigate the greenhouse gases in the atmosphere. It is known that the carbon dioxide conversion and product yields are still low even if the reaction is operated at high pressure and temperature. The carbon dioxide utilization and conversion provides many challenges in exploring new concepts and opportunities for development of unique catalysts for the purpose of activating the carbon dioxide molecules. In this paper, the role of carbon-based nanocatalysts in the hydrogenation of carbon dioxide and direct synthesis of dimethyl carbonate from carbon dioxide and methanol are reviewed. The current catalytic results obtained with different carbon-based nanocatalysts systems are presented and how these materials contribute to the carbon dioxide conversion is explained. In addition, different strategies and preparation methods of nanometallic catalysts on various carbon supports are described to optimize the dispersion of metal nanoparticles and catalytic activity. PMID:23901504

  12. Monitoring carbon dioxide in mechanically ventilated patients during hyperbaric treatment

    DEFF Research Database (Denmark)

    Bjerregård, Asger; Jansen, Erik

    2012-01-01

    Measurement of the arterial carbon dioxide (P(a)CO(2)) is an established part of the monitoring of mechanically ventilated patients. Other ways to get information about carbon dioxide in the patient are measurement of end-tidal carbon dioxide (P(ET)CO(2)) and transcutaneous carbon dioxide (PTCCO2...

  13. 46 CFR 97.37-9 - Carbon dioxide alarm.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Carbon dioxide alarm. 97.37-9 Section 97.37-9 Shipping... Markings for Fire and Emergency Equipment, Etc. § 97.37-9 Carbon dioxide alarm. (a) All carbon dioxide alarms shall be conspicuously identified: “WHEN ALARM SOUNDS—VACATE AT ONCE. CARBON DIOXIDE...

  14. 46 CFR 78.47-9 - Carbon dioxide alarm.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 3 2010-10-01 2010-10-01 false Carbon dioxide alarm. 78.47-9 Section 78.47-9 Shipping... and Emergency Equipment, Etc. § 78.47-9 Carbon dioxide alarm. (a) All carbon dioxide alarms shall be conspicuously identified: “WHEN ALARM SOUNDS—VACATE AT ONCE. CARBON DIOXIDE BEING RELEASED.” (b)...

  15. 46 CFR 196.37-9 - Carbon dioxide alarm.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Carbon dioxide alarm. 196.37-9 Section 196.37-9 Shipping... Markings for Fire and Emergency Equipment, etc. § 196.37-9 Carbon dioxide alarm. (a) All carbon dioxide alarms shall be conspicuously identified: “WHEN ALARM SOUNDS—VACATE AT ONCE. CARBON DIOXIDE...

  16. 46 CFR 108.627 - Carbon dioxide alarm.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Carbon dioxide alarm. 108.627 Section 108.627 Shipping... EQUIPMENT Equipment Markings and Instructions § 108.627 Carbon dioxide alarm. Each carbon dioxide alarm must be identified by marking: “WHEN ALARM SOUNDS VACATE AT ONCE. CARBON DIOXIDE BEING RELEASED” next...

  17. 46 CFR 95.15-20 - Carbon dioxide storage.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Carbon dioxide storage. 95.15-20 Section 95.15-20... PROTECTION EQUIPMENT Carbon Dioxide Extinguishing Systems, Details § 95.15-20 Carbon dioxide storage. (a... of not more than 300 pounds of carbon dioxide, may have the cylinders located within the...

  18. 46 CFR 76.15-20 - Carbon dioxide storage.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 3 2010-10-01 2010-10-01 false Carbon dioxide storage. 76.15-20 Section 76.15-20... EQUIPMENT Carbon Dioxide Extinguishing Systems, Details § 76.15-20 Carbon dioxide storage. (a) Except as... than 300 pounds of carbon dioxide, may have the cylinders located within the space protected. If...

  19. 46 CFR 169.732 - Carbon dioxide alarm.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Carbon dioxide alarm. 169.732 Section 169.732 Shipping... Control, Miscellaneous Systems, and Equipment Markings § 169.732 Carbon dioxide alarm. Each carbon dioxide alarm must be conspicuously identified: “WHEN ALARM SOUNDS—VACATE AT ONCE. CARBON DIOXIDE BEING RELEASED.”...

  20. Detecting Climate Change due to Increasing Carbon Dioxide.

    Science.gov (United States)

    Madden, R A; Ramanathan, V

    1980-08-15

    The observed interannual variability of temperature at 60 degrees N has been investigated. The results indicate that the surface warming due to increased carbon dioxide which is predicted by three-dimensional climate models should be detectable now. It is not, possibly because the predicted warming is being delayed more than a decade by ocean thermal inertia, or because there is a compensating cooling due to other factors. Further consideration of the uncertainties in model predictions and of the likely delays introduced by ocean thermal inertia extends the range of time for the detection of warming, if it occurs, to the year 2000. The effects of increasing carbon dioxide should be looked for in several variables simultaneously in order to minimize the ambiguities that could result from unrecognized compensating cooling. PMID:17753291

  1. Reactive Capture of Carbon Dioxide Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this Phase I SBIR, Reactive Innovations, LLC (RIL) proposes to develop a compact and lightweight electrochemical to capture carbon dioxide in the martian...

  2. Supercritical carbon dioxide hop extraction

    Directory of Open Access Journals (Sweden)

    Pfaf-Šovljanski Ivana I.

    2005-01-01

    Full Text Available The hop of Magnum cultivar was extracted using supercritical carbon dioxide (SFE-as extractant. Extraction was carried out in the two steps: the first one being carried out at 150 bar and 40°C for 2.5 h (Extract A, and the second was the extraction of the same hop sample at 300 bar and 40°C for 2.5 h (Extract B. Extraction kinetics of the system hop-SFE-CO2 was investigated. Two of four most common compounds of hop aroma (α-humulene and β-caryophyllene were detected in Extract A. Isomerised α-acids and β-acids were detected too. a-Acid content in Extract B was high (that means it is a bitter variety of hop. Mathematical modeling using empirical model characteristic time model and simple single sphere model has been performed on Magnum cultivar extraction experimental results. Characteristic time model equations, best fitted experimental results. Empirical model equation, fitted results well, while simple single sphere model equation poorly approximated the results.

  3. Extraction of Uranium Using Nitrogen Dioxide and Carbon Dioxide for Spent Fuel Reprocessing

    International Nuclear Information System (INIS)

    For the reprocessing of spent nuclear fuels, a new method to extract actinides from spent fuel using highly compressed gases, nitrogen dioxide and carbon dioxide was proposed. Uranium extraction from broken pieces, whose average grain size was 5 mm, of uranium dioxide pellet with nitrogen dioxide and carbon dioxide was demonstrated in the present study. (authors)

  4. Bench-to-bedside review: Carbon dioxide

    OpenAIRE

    Curley, Gerard; Laffey, John G; Kavanagh, Brian P.

    2010-01-01

    Carbon dioxide is a waste product of aerobic cellular respiration in all aerobic life forms. PaCO2 represents the balance between the carbon dioxide produced and that eliminated. Hypocapnia remains a common - and generally underappreciated - component of many disease states, including early asthma, high-altitude pulmonary edema, and acute lung injury. Induction of hypocapnia remains a common, if controversial, practice in both adults and children with acute brain injury. In contrast, hypercap...

  5. Arterialisation of transcutaneous oxygen and carbon dioxide.

    OpenAIRE

    Broadhurst, E; Helms, P; Vyas, H; Cheriyan, G

    1988-01-01

    We compared previously calculated global correction factors for oxygen and carbon dioxide arterial/transcutaneous ratios with individual in vivo calibrations from the first arterial sample. In infants beyond the neonatal period and older children in vivo calibration confers little benefit over the use of a global calibration correction factor for transcutaneous carbon dioxide, and may reduce the precision with which arterial oxygen can be estimated from transcutaneous oxygen.

  6. Emergency reactor core cooling system of BWR type reactor

    International Nuclear Information System (INIS)

    The present invention provides an emergency reactor core cooling system which can reduce a capacity of a power source required upon occurrence of emergency, extending an start-up time of an emergency reactor core cooling system (ECCA) to provide a plant endurable to a common factor accident and can provide time margin up to the start-up time. Namely, the system of the present invention comprises a division I equipped with an isolation condenser (IC), an after-heat removing system (low pressure system)(LPFL/RHR) and an emergency gas turbine generator (GT), a division II equipped with a diesel driving water injection system (high pressure system)(HDIS), LPFL/RHR, and GT, and a division III equipped with a reactor isolation time cooling system (high pressure system)(ARCIC), LPFL/RHR and GT. With such a constitution, since the IC, HDIS and ARCIC are used in combination as a high pressure system, an electromotive pump required to be operated upon high pressure state can be saved. In addition, if a static reactor cooling system (PCCS) is adopted and is provided with a back-up function for LPFL/RHR with respect to heat removal of the container upon occurrence of an accident, the countermeasure for occurrence of severe accidents can be enhanced. (I.S.)

  7. Extended Cooling System for High Power Reactors

    International Nuclear Information System (INIS)

    In-vessel retention (IVR) of core melt is a key severe accident management strategy adopted by some operating nuclear power plants (NPPs) and proposed for advanced light water reactors (LWRs). However, it is not clear that currently proposed external reactor vessel cooling (ERVC) could provide sufficient heat removal for higher power reactors. This paper proposes a dual retention strategy to realize fail-proof defense-in-depth in the APR1400 (Advanced Power Reactor 1400 MWe) and the OPR 1000 (Optimized Power Reactor 1000 MWe). The dual retention has the advantage of IVR-ERVC as well as ex-vessel cooling (EVC) strategies. The multilateral, multidisciplinary project calls for national and international cutting-edge technologies to research and produce (R and P) the D2R2 (Duel Retention Demonstration Reactor) equipped with OASIS (Optimized Advanced Safety Injection System) and ROSIS (Reactor Outer Safety Injection System) to cope with design-basis accidents and beyond in a coherent, continual, comprehensive manner. The enterprise aims to develop the design-basis and severe accident engineering solutions. The enterprise aims to develop the design-basis and severe accident engineering solutions. The former embraces ISAIAH (Injection System Annular Interactive Aero Hydrodynamics) and MESIAH (Methodical Evaluation System Interactive Aero Hydrodynamics). The latter comprises GODIVA (Geo metrics of Direct Injection Versatile Arrangement), SONATA (Simulation of Narrow Annular Thermomechanical Arrest or), TOCATA (Termination of Corium Ablation Thermal Attack) and STRADA (Solution to Reactor Advanced Design Alternatives). D2R2 will contribute to enhancement of both safety and economics for an advanced high power particular and nuclear power in general

  8. Passive cooling systems in power reactors

    International Nuclear Information System (INIS)

    This paper reviews several R and D activities associated with the subject of passive cooling systems, conducted by the N.R.C.Negev thermohydraulic group. A short introduction considering different types of thermosyphons and their applications is followed by a detailed description of the experimental work, its results and conclusions. An ongoing research project is focused on the evaluation of the external dry air passive containment cooling system (PCCS) in the AP-600 (Westinghouse advanced pressurized water reactor). In this context some preliminary theoretical results and planned experimental research are for the fature described

  9. Startup of the FFTF sodium cooled reactor

    International Nuclear Information System (INIS)

    The Fast Flux Test Facility (FFTF), located on the Department of Energy (DOE) Hanford Reservation near Richland, Washington, is a 3 Loop 400 MW(t) sodium cooled fast reactor with a primary mission to test fuels and materials for development of the Liquid Metal Fast Breeder Reactor (LMFBR). Bringing FFTF to a condition to accomplish this mission is the goal of the Acceptance Test Program (ATP). This program was the mechanism for achieving startup of the FFTF. Highlights of the ATP involving the system inerting, liquid metal and inerted cell testing and initial ascent to full power are discussed

  10. Liquid metal cooled fast breeder nuclear reactor

    International Nuclear Information System (INIS)

    A liquid metal cooled fast breeder nuclear reactor has a core comprising a plurality of fuel assemblies supported on a diagrid and submerged in a pool of liquid metal coolant within a containment vessel, the diagrid being of triple component construction and formed of a short cylindrical plenum mounted on a conical undershell and loosely embraced by a fuel store carrier. The plenum merely distributes coolant through the fuel assemblies, the load of the assemblies being carried by the undershell by means of struts which penetrate the plenum. The reactor core, fuel store carrier and undershell provide secondary containment for the plenum. (UK)

  11. CEA programme on gas cooled reactors

    International Nuclear Information System (INIS)

    Future nuclear energy systems studies conducted by the CEA aim at investigating and developing promising technologies for future reactors, fuels and fuel cycles, for nuclear power to play a major part in sustainable energy policies. Reactors and fuel cycles are considered as integral parts of a nuclear system to be optimised as a whole. Major goals assigned to future nuclear energy systems are the following: reinforced economic competitiveness with other electricity generation means, with a special emphasis on reducing the investment cost; enhanced reliability and safety, through an improved management of reactor operation in normal and abnormal plant conditions; minimum production of long lived radioactive waste; resource saving through an effective and flexible use of the available resources of fissile and fertile materials; enhanced resistance to proliferation risks. The three latter goals are essential for the sustainability of nuclear energy in the long term. Additional considerations such as the potentialities for other applications than electricity generation (co-generation, production of hydrogen, sea water desalination) take on an increasing importance. Sustainability goals call for fast neutron spectra (to transmute nuclear waste and to breed fertile fuel) and for recycling actinides from the spent fuel (plutonium and minor actinides). New applications and economic competitiveness call for high temperature technologies (850 deg C), that afford high conversion efficiencies and hence less radioactive waste production and discharged heat. These orientations call for breakthroughs beyond light water reactors. Therefore, as a result of a screening review of candidate technologies, the CEA has selected an innovative concept of high temperature gas cooled reactor with a fast neutron spectrum, robust refractory fuel, direct conversion with a gas turbine, and integrated on-site fuel cycle as a promising system for a sustainable energy development. This objective

  12. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; William J. McMichael; Douglas P. Harrison; Ya Liang

    2002-04-01

    The objective of this project is to develop a simple, inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbents being investigated in this project are primarily alkali carbonates, and particularly sodium carbonate and potassium carbonate, which are converted to bicarbonates, through reaction with carbon dioxide and water vapor. Bicarbonates are regenerated to carbonates when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. This quarter, electrobalance tests conducted at LSU indicated that exposure of sorbent to water vapor prior to contact with carbonation gas does not significantly increase the reaction rate. Calcined fine mesh trona has a greater initial carbonation rate than calcined sodium bicarbonate, but appears to be more susceptible to loss of reactivity under severe calcination conditions. The Davison attrition indices for Grade 5 sodium bicarbonate, commercial grade sodium carbonate and extra fine granular potassium carbonate were, as tested, outside of the range suitable for entrained bed reactor testing. Fluidized bed testing at RTI indicated that in the initial stages of reaction potassium carbonate removed 35% of the carbon dioxide in simulated flue gas, and is reactive at higher temperatures than sodium carbonate. Removals declined to 6% when 54% of the capacity of the sorbent was exhausted. Carbonation data from electrobalance testing was correlated using a shrinking core reaction model. The activation energy of the reaction of sodium carbonate with carbon dioxide and water vapor was determined from nonisothermal thermogravimetry.

  13. Turning carbon dioxide into fuel.

    Science.gov (United States)

    Jiang, Z; Xiao, T; Kuznetsov, V L; Edwards, P P

    2010-07-28

    Our present dependence on fossil fuels means that, as our demand for energy inevitably increases, so do emissions of greenhouse gases, most notably carbon dioxide (CO2). To avoid the obvious consequences on climate change, the concentration of such greenhouse gases in the atmosphere must be stabilized. But, as populations grow and economies develop, future demands now ensure that energy will be one of the defining issues of this century. This unique set of (coupled) challenges also means that science and engineering have a unique opportunity-and a burgeoning challenge-to apply their understanding to provide sustainable energy solutions. Integrated carbon capture and subsequent sequestration is generally advanced as the most promising option to tackle greenhouse gases in the short to medium term. Here, we provide a brief overview of an alternative mid- to long-term option, namely, the capture and conversion of CO2, to produce sustainable, synthetic hydrocarbon or carbonaceous fuels, most notably for transportation purposes. Basically, the approach centres on the concept of the large-scale re-use of CO2 released by human activity to produce synthetic fuels, and how this challenging approach could assume an important role in tackling the issue of global CO2 emissions. We highlight three possible strategies involving CO2 conversion by physico-chemical approaches: sustainable (or renewable) synthetic methanol, syngas production derived from flue gases from coal-, gas- or oil-fired electric power stations, and photochemical production of synthetic fuels. The use of CO2 to synthesize commodity chemicals is covered elsewhere (Arakawa et al. 2001 Chem. Rev. 101, 953-996); this review is focused on the possibilities for the conversion of CO2 to fuels. Although these three prototypical areas differ in their ultimate applications, the underpinning thermodynamic considerations centre on the conversion-and hence the utilization-of CO2. Here, we hope to illustrate that advances

  14. The addition of non-condensable gases into RELAP5-3D for analysis of high temperature gas-cooled reactors

    International Nuclear Information System (INIS)

    Oxygen, carbon dioxide, and carbon monoxide have been added to the RELAP5-3D computer code as noncondensable gases to support analysis of high temperature gas-cooled reactors. Models of these gases are required to simulate the effects of air ingress on graphite oxidation following a loss-of- coolant accident. Correlations were developed for specific internal energy, thermal conductivity, and viscosity for each gas at temperatures up to 3000 K. The existing model for internal energy (a quadratic function of temperature) was not sufficiently accurate at these high temperatures and was replaced by a more general, fourth-order polynomial. The maximum deviation between the correlations and the underlying data was 2.2% for the specific internal energy and 7% for the specific heat capacity at constant volume. The maximum deviation in the transport properties was 4% for oxygen and carbon monoxide and 12% for carbon dioxide

  15. Emergency cooling system for nuclear reactors

    International Nuclear Information System (INIS)

    Upon the occasion of loss of coolant in a nuclear reactor as when a coolant supply or return line breaks, or both lines break, borated liquid coolant from an emergency source is supplied in an amount to absorb heat being generated in the reactor even after the control rods have been inserted. The liquid coolant flows from pressurized storage vessels outside the reactor to an internal manifold from which it is distributed to unused control rod guide thimbles in the reactor fuel assemblies. Since the guide thimbles are mounted at predetermined positions relative to heat generating fuel elements in the fuel assemblies, holes bored at selected locations in the guide thimble walls, sprays the coolant against the reactor fuel elements which continue to dissipate heat but at a reduced level. The cooling water evaporates upon contacting the fuel rods thereby removing the maximum amount of heat (970 BTU per pound of water) and after heat absorption will leave the reactor in the form of steam through the break which is the cause of the accident to help assure immediate core cooldown

  16. Sintering furnace with hydrogen carbon dioxide atmosphere

    International Nuclear Information System (INIS)

    A heated furnace for sintering structures of uranium oxide containing composition being introduced to the furnace is described. The furnace receives an atmosphere comprising a mixture of hydrogen and carbon dioxide as initially introduced to the furnace, and this mixture reacts in the furnace to give the presence of water vapor and carbon monoxide

  17. The new cooling system of the IPR-RI reactor

    International Nuclear Information System (INIS)

    A 250 Kw cooling system was designed and installed to cool the demineralized water of the IPR-RI reactor (Triga Mark I). The primary circuit is made of 304 stainless steel. The secondary circuit is made of carbon steel, and the cooling tower of fiberglass.The heat exchanger is of the shell-and-tube type with four tube passes. The demineralized water (primary side) flows through the shell and the ordinary water flows inside the tubes. This arrangement allows cleaning of the tubes (straight tubes) by simply disassembling the top of the heat exchanger. The cooling system was designed to operate at a pool temperature of 40.7 deg C. Cold water returns to the reactor tank in summer days at a maximum temperature of 33.1 deg C. The water flow in the primary side can be varied from 28 m3/h to 32 m3/h. Interlocks and protection devices coupled to pressure gauges, temperature and water level meters provide a very safe and reliable performance to the cooling system. (author)

  18. Method for Extracting and Sequestering Carbon Dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Rau, Gregory H.; Caldeira, Kenneth G.

    2005-05-10

    A method and apparatus to extract and sequester carbon dioxide (CO2) from a stream or volume of gas wherein said method and apparatus hydrates CO2, and reacts the resulting carbonic acid with carbonate. Suitable carbonates include, but are not limited to, carbonates of alkali metals and alkaline earth metals, preferably carbonates of calcium and magnesium. Waste products are metal cations and bicarbonate in solution or dehydrated metal salts, which when disposed of in a large body of water provide an effective way of sequestering CO2 from a gaseous environment.

  19. Carbon dioxide catastrophes: Past and future menace

    Science.gov (United States)

    Baur, Mario E.

    1988-01-01

    Carbon dioxide is important in its role as coupler of the terrestrial biosphere to inorganic chemical processes and as the principal greenhouse gas controlling Earth's surface temperature. The hypothesis that atmospheric CO2 levels have diminished with time, with the resulting cooling effect offsetting an increase in the solar constant, seems firmly established, and it is shown that feedback mechanisms exist which can maintain the terrestrial surface in a relatively narrow temperature range over geological time. Of the factors involved in such CO2 variation, the oceanic reservoir appears the most important. Surface waters are probably in approximate equilibrium with regard to CO2 exchange with the ambient atmosphere in most regions, but data from deep-ocean water sampling indicates that such waters are somewhat undersaturated in the sense that they would tend to absorb CO2 from the atmosphere if brought to the surface without change in composition or temperature. If major impacts into the ocean can result in loss of a substantial portion of the atmospheric CO2 reservoir, then any such future event could imperil the continuation of most higher forms of life on Earth. The most likely candidate for an inverse Nyos global event in previous Earth history is the Cretaceous-Tertiary terminal extinction event. The Cretaceous was characterized by warm, equable temperatures presumably indicative of relatively high CO2 levels and an intense greenhouse heating. Cooling of the oceans in absence of massive transfer of CO2 to the oceanic reservoir in itself would promote a condition of CO2 undersaturation in abyssal waters, and this is made even more extreme by the pattern of ocean water circulation. It is possible to envision a situation in which deep ocean waters were at least occasionally profoundly undersaturated with regard to CO2. Turnover of a major fraction of such an ocean would then remove, on a very short time scale, as much as 90 percent of the atmospheric CO2

  20. SEQUESTERING CARBON DIOXIDE IN COALBEDS

    Energy Technology Data Exchange (ETDEWEB)

    K.A.M. Gasem; R.L. Robinson, Jr.; J.E. Fitzgerald; Z. Pan; M. Sudibandriyo

    2003-04-30

    The authors' long-term goal is to develop accurate prediction methods for describing the adsorption behavior of gas mixtures on solid adsorbents over complete ranges of temperature, pressure, and adsorbent types. The originally-stated, major objectives of the current project are to: (1) measure the adsorption behavior of pure CO{sub 2}, methane, nitrogen, and their binary and ternary mixtures on several selected coals having different properties at temperatures and pressures applicable to the particular coals being studied, (2) generalize the adsorption results in terms of appropriate properties of the coals to facilitate estimation of adsorption behavior for coals other than those studied experimentally, (3) delineate the sensitivity of the competitive adsorption of CO{sub 2}, methane, and nitrogen to the specific characteristics of the coal on which they are adsorbed; establish the major differences (if any) in the nature of this competitive adsorption on different coals, and (4) test and/or develop theoretically-based mathematical models to represent accurately the adsorption behavior of mixtures of the type for which measurements are made. As this project developed, an important additional objective was added to the above original list. Namely, we were encouraged to interact with industry and/or governmental agencies to utilize our expertise to advance the state of the art in coalbed adsorption science and technology. As a result of this additional objective, we participated with the Department of Energy and industry in the measurement and analysis of adsorption behavior as part of two distinct investigations. These include (a) Advanced Resources International (ARI) DOE Project DE-FC26-00NT40924, ''Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Mixtures on Wet Tiffany Coal'', and (b) the DOE-NETL Project, ''Round Robin: CO{sub 2} Adsorption on Selected Coals''. These activities, contributing

  1. Advanced gas cooled reactors - Designing for safety

    International Nuclear Information System (INIS)

    The Advanced Gas-Cooled Reactor Power Stations recently completed at Heysham in Lancashire, England, and Torness in East Lothian, Scotland represent the current stage of development of the commercial AGR. Each power station has two reactor turbo-generator units designed for a total station output of 2x660 MW(e) gross although powers in excess of this have been achieved and it is currently intended to uprate this as far as possible. The design of both stations has been based on the successful operating AGRs at Hinkley Point and Hunterston which have now been in-service for almost 15 years, although minor changes were made to meet new safety requirements and to make improvements suggested by operating experience. The construction of these new AGRs has been to programme and within budget. Full commercial load for the first reactor at Torness was achieved in August 1988 with the other three reactors following over the subsequent 15 months. This paper summarises the safety principles and guidelines for the design of the reactors and discusses how some of the main features of the safety case meet these safety requirements. The paper also summarises the design problems which arose during the construction period and explains how these problems were solved with the minimum delay to programme

  2. Carbon dioxide and methane emissions from estuaries

    OpenAIRE

    Abril, G.; Borges, Alberto

    2005-01-01

    Carbon dioxide and methane emissions from estuaries are reviewed in relationwith biogeochemical processes and carbon cycling. In estuaries, carbondioxide and methane emissions show a large spatial and temporalvariability, which results from a complex interaction of river carbon inputs,sedimentation and resuspension processes, microbial processes in watersand sediments, tidal exchanges with marshes and flats and gas exchangewith the atmosphere. The net mineralization of land-derived organic ca...

  3. Small power sodium cooled fast nuclear reactors

    International Nuclear Information System (INIS)

    1.5 MW(e), 12 MW(e) and 170 MW(e) small power sodium cooled fast reactors have been developed. The reactor plants were developed as universal power units for economically effective energy and industrial steam generation and heat supply. The main features increasing the power unit economic efficiency are: serial fabrication of standard RPs at the factory and delivery of reactor vessels in ready made form; realization of self-protection principles and use of passive systems in RP; use of standard machine room equipment, fabricated in accordance with the rules of conventional heat power engineering; use of turbine plant with thermodynamic coefficient, exceeding the corresponding value for the plants of PWR type. For MBRU-1.5 and MBRU-12 RPs it is proposed to use a core without FA replacement during the whole service life (30 years) and for BMN-170 RP it is proposed to use a core with a 4 year operating period and 1 year between the refueling shutdowns. During the whole service life a minimal number of operating personnel will be needed for the plant servicing. The personnel functions will be periodically to observe the parameters of technological process. Passive principles are used in the main RP safety systems: a passive type system of emergency residual heat removal system provides heat removal directly through the reactor vessel forced air cooling due to the natural air chimney effect; an emergency reactor shut-down system is provided by emergency protection rods with active-passive action. (author)

  4. Bacterial pathogens in a reactor cooling reservoir

    International Nuclear Information System (INIS)

    The results of the sampling in both Par Pond and Clark Hill Reservoir are given. The frequency of isolation is a qualitative parameter which indicates how often the specified bacterium was isolated from each habitat. Initial scoping experiments demonstrated that a wider variety of pathogenic bacteria occur in Par Pond than in Clark Hill Reservoir. Such findings are interesting because Par Pond does not receive any human wastes directly, yet bacteria generally associated with human wastes are more frequently isolated from Par Pond. Previous studies have demonstrated that certain non-spore-forming enteric bacteria do not survive the intense heat associated with the cooling water when the reactor is operating. However, even when the reactor is not operating, cooling water, consisting of 10% makeup water from Savannah River, continues to flow into Par Pond. This flow provides a source of bacteria which inoculate Par Pond. Once the reactor is again operating, these same bacteria appear to be able to survive and grow within the Par Pond system. Thus, Par Pond and the associated lakes and canals of the Par Pond system provide a pool of pathogens that normally would not survive in natural waters

  5. Design codes for gas cooled reactor components

    International Nuclear Information System (INIS)

    High-temperature gas-cooled reactor (HTGR) plants have been under development for about 30 years and experimental and prototype plants have been operated. The main line of development has been electricity generation based on the steam cycle. In addition the potential for high primary coolant temperature has resulted in research and development programmes for advanced applications including the direct cycle gas turbine and process heat applications. In order to compare results of the design techniques of various countries for high temperature reactor components, the IAEA established a Co-ordinated Research Programme (CRP) on Design Codes for Gas-Cooled Reactor Components. The Federal Republic of Germany, Japan, Switzerland and the USSR participated in this Co-ordinated Research Programme. Within the frame of this CRP a benchmark problem was established for the design of the hot steam header of the steam generator of an HTGR for electricity generation. This report presents the results of that effort. The publication also contains 5 reports presented by the participants. A separate abstract was prepared for each of these reports. Refs, figs and tabs

  6. [Pharmaceutical applications of supercritical carbon dioxide].

    Science.gov (United States)

    Delattre, L

    2007-01-01

    The supercritical state of a fluid is intermediate between that of gases and liquids. Supercritical fluids exhibit some solvent power which is tunable in function of pressure and temperature. In the pharmaceutical field, supercritical carbon dioxide is by far the most commonly used fluid; of course, the first applications of supercritical fluids were the replacement of organic solvents in extraction processes; other applications appeared during the last twenty years: supercritical fluids are also used as eluents in chromatography, as solvents in organic synthesis or for the processing of solid dosage forms by drug micronization, by the production of nanospheres, of solid dispersions, of porous polymeric matrices containing different active substances. Supercritical carbon dioxide has been proposed for encapsulating both hydrophilic and hydrophobic drug substances into liposomes as well as for including different active substances into cyclodextrins. There are also future prospects for the use of pressurized carbon dioxide as a sterilizing agent. PMID:17299352

  7. Design study of cooling system for tokamak fusion reactor

    International Nuclear Information System (INIS)

    Design study of the reactor cooling system for a tokamak fusion reactor has been carried out. In the cooling system of an experimental 150 MWt fusion reactor, to grasp the plant concept and clarify the R and D items the main cooling system and the tritium recovery system were designed and the auxiliary system was examined. In the cooling system of a commercial 2000 MWt fusion reactor, to study the plant and environment safety the main cooling system and the tritium recovery system were designed, including the evaluation of water leakage and tritium penetration in the steam generators. (auth.)

  8. Emergency reactor cooling systems for the experimental VHTR

    International Nuclear Information System (INIS)

    Performances and design of the panel cooling system which has been proposed to be equipped as an emergency reactor cooling system for the experimental multi purpose very high temperature gas-cooled reactor are explained. Effects of natural circulation flow which would develop in the core and temperature transients of the panel in starting have been precisely investigated. Conditions and procedures for settling accidents with the proposed panel cooling system have been also studied. Based on these studies, it has been shown that the panel cooling system is effective and useful for the emergency reactor cooling of the experimental VHTR. (author)

  9. Synthesis of fluoropolymers in supercritical carbon dioxide

    International Nuclear Information System (INIS)

    Fluoropolymers are used in many technologically demanding applications because of their balance of high-performance properties. A significant impediment to the synthesis of variants of commercially available amorphous fluoropolymers is their general insolubility in most solvents except chlorofluorocarbons (CFCs). The environmental concerns about CFCs can be circumvented by preparing these technologically important materials in supercritical fluids. The homogeneous solution polymerization of highly fluorinated acrylic monomers can be achieved in supercritical carbon dioxide by using free radical methods. In addition, detailed decomposition rates and efficiency factors were measured for azobisisobutyronitrile in supercritical carbon dioxide and were compared to those obtained with conventional liquid solvents

  10. Superpulsed carbon dioxide laser: an update on cutaneous surgical applications

    Science.gov (United States)

    Wheeland, Ronald G.

    1990-06-01

    Superpulsing the carbon dioxide laser allows delivery of high energy pulses separated by short pauses during which tissue cooling can occur.1 This new technology can provide several important advantages in cutaneous surgery over similar procedures performed with conventional continuous discharge carbon dioxide laser systems. In the excisional mode, there is a two-thirds reduction in thermal necrosis of the wound edge.2 This should translate into more rapid healing3 and increased rate of gain in tensile strength. In the vaporizational mode, precise, superficial and bloodless ablation of multiple benign appendigeal tumors is possible with less thermal damage yielding excellent cosmetic results. The establishment through additional research of accurate laser parameters, pulse duration, peak energy levels, and frequency of pulses, will help improve the specificity of the laser-tissue interaction to provide even better surgical results.

  11. Global deforestation: contribution to atmospheric carbon dioxide.

    Science.gov (United States)

    Woodwell, G M; Hobbie, J E; Houghton, R A; Melillo, J M; Moore, B; Peterson, B J; Shaver, G R

    1983-12-01

    A study of effects of terrestrial biota on the amount of carbon dioxide in the atmosphere suggests that the global net release of carbon due to forest clearing between 1860 and 1980 was between 135 x 10(15) and 228 x 10(15) grams. Between 1.8 x 10(15) and 4.7 x 10(15) grams of carbon were released in 1980, of which nearly 80 percent was due to deforestation, principally in the tropics. The annual release of carbon from the biota and soils exceeded the release from fossil fuels until about 1960. Because the biotic release has been and remains much larger than is commonly assumed, the airborne fraction, usually considered to be about 50 percent of the release from fossil fuels, was probably between 22 and 43 percent of the total carbon released in 1980. The increase in carbon dioxide in the atmosphere is thought by some to be increasing the storage of carbon in the earth's remaining forests sufficiently to offset the release from deforestation. The interpretation of the evidence presented here suggests no such effect; deforestation appears to be the dominant biotic effect on atmospheric carbon dioxide. If deforestation increases in proportion to population, the biotic release of carbon will reach 9 x 10(15) grams per year before forests are exhausted early in the next century. The possibilities for limiting the accumulation of carbon dioxide in the atmosphere through reduction in use of fossil fuels and through management of forests may be greater than is commonly assumed. PMID:17747369

  12. Emergency cooling of pressurized water reactors

    International Nuclear Information System (INIS)

    The operating conditions of the reactor are first described during emergency cooling (system aspect) taking as example a Westinghouse type reactor (cold branch injection). Mention is then made of the different variants employed either by Westinghouse or by other manufacturers (top of vessel injection, hot branch injection, equalizing valve, etc.). The importance of accurately knowing the pressure drops throughout the system is demonstrated. Particular attention is given to heat exchanges in the core: non-wet area, heat transfer by convection and radiation with a two-phase flow; re-wetting area, effect of axial conduction and of the condition of the fuel. Finally, the models used for the overall study of the system and for the treatment of local heat transfer, are briefly presented

  13. Liquid metal cooled nuclear reactor constructions

    International Nuclear Information System (INIS)

    In a liquid metal cooled nuclear reactor with a nuclear fuel assembly in a coolant-containing primary vessel housed within a concrete containment vault, there is thermal insulation to protect the concrete, the insulation being disposed between vessel and concrete and being hung from metal structure secured to and projecting from the concrete, the insulation consisting of a plurality of adjoining units each unit incorporating a pack of thermal insulating material and defining a contained void co-extensive with said pack and situated between pack and concrete, the void of each unit being connected to the voids of adjoining units so as to form continuous ducting for a fluid coolant. (author)

  14. Methanol synthesis from recycled carbon dioxide and hydrogen from high temperature steam electrolysis with the nuclear heat of an HTGR

    International Nuclear Information System (INIS)

    Global warming resulting from increasing carbon dioxide is a crucial and imperative issue to cope with. Curving CO2 emission is a must to prevent global warming. This paper addresses a study of an environment-friendly plant concept in which reduction of emissions is attained by utilizing nuclear generated heat to methanol production. The process of the plant is as follows: (1) High-temperature heat energy is obtained from MHTGRs (MHTGR: Modular High-Temperature Gas-Cooled Reactor) that emit no CO2. (2) The high-temperature heat electrolyzes steam into hydrogen. (3) Hydrogen reacts with carbon dioxide emitted from a thermal power plant producing methanol: a promising and easily transportable. This paper describes the results studied by Sub-Group ''Methanol Synthesis from Recycled Carbon Dioxide and Hydrogen from High Temperature Steam Electrolysis'' which branches out of ''Study Group'' belonging to ''The Committee on Uses of Reactor Heat'' organized by Japan Industrial Forum (JAIF). (author). 5 refs, 7 figs, 1 tab

  15. A Feasibility Study of a Steam Methane Reforming Hydrogen Production Plant with a Sodium-Cooled Fast Reactor

    International Nuclear Information System (INIS)

    A thermal source for hydrogen production is an attractive utilization of nuclear energy. Hydrogen production from natural gas is a promising method in an early stage of hydrogen society, though hydrogen production with water splitting without carbon dioxide emission is the final goal. Steam methane reforming is a well-known method for producing hydrogen from natural gas. A hydrogen separation membrane makes the reforming temperature much lower than that of the equilibrium condition, and a sodium-cooled fast reactor, which supplies heat at ∼500 deg. C, can be used as a heat source for hydrogen production.In this study, a hydrogen production plant with the membrane reforming method using a sodium-cooled reactor as a thermal source has been designed, and its economic potential is roughly evaluated. The hydrogen production cost is estimated to be about $1.67/kg, achieving the economic target of $1.7/kg. The construction cost is largely shared by the reformers' cost, and it can be decreased using a more efficient hydrogen separation membrane. This shows that steam methane reforming hydrogen production with a sodium-cooled reactor has high economical potential

  16. Changes in plasma potassium concentration during carbon dioxide pneumoperitoneum

    DEFF Research Database (Denmark)

    Perner, A; Bugge, K; Lyng, K M;

    1999-01-01

    to either carbon dioxide pneumoperitoneum or abdominal wall lifting for laparoscopic colectomy. Despite an increasing metabolic acidosis, prolonged carbon dioxide pneumoperitoneum resulted in only a slight increase in plasma potassium concentrations, which was both statistically and clinically...

  17. Enhancement of enterotoxin production by carbon dioxide in Vibrio cholerae.

    OpenAIRE

    Shimamura, T; Watanabe, S; Sasaki, S.

    1985-01-01

    We found that Vibrio cholerae 569B produced much more cholera enterotoxin in the presence of added carbon dioxide than in its absence. An atmosphere of 10% carbon dioxide was optimal for maximal enterotoxin production.

  18. Magnesian calcite sorbent for carbon dioxide capture

    Energy Technology Data Exchange (ETDEWEB)

    Mabry, J.C.; Mondal, K. [Southern Illinois University, Carbondale, IL (United States)

    2011-07-01

    Magnesian calcite with controlled properties was synthesized for the removal of carbon dioxide. The results from characterization, reactivity and CO{sub 2} capture capacity for different synthesis conditions are reported. The magnesian calcite samples (CaCO{sub 3}:MgCO{sub 3}) were synthesized by the coprecipitation of specific amounts of commercially available CaO and MgO by carbon dioxide. Characterization was done with BET, SEM/EDS, particle size analysis and XRD. The capacity was measured using TGA cycles at 800 {sup o}C and compared for different preparation conditions. The effects of CaO, MgO and surfactant loading on the physical properties and carbonation activity were studied to determine the optimal synthesis condition. A long-term carbonation-calcination cycling test was conducted on the optimal sample. It was observed that the sample maintained its capacity to 86% of its original uptake even after 50 cycles.

  19. Heat transfer and pressure drop of supercritical carbon dioxide flowing in several printed circuit heat exchanger channel patterns

    International Nuclear Information System (INIS)

    Closed-loop Brayton cycles using supercritical carbon dioxide (SCO2) show potential for use in high-temperature power generation applications including High Temperature Gas Reactors (HTGR) and Sodium-Cooled Fast Reactors (SFR). Compared to Rankine cycles SCO2 Brayton cycles offer similar or improved efficiency and the potential for decreased capital costs due to a reduction in equipment size and complexity. Compact printed-circuit heat exchangers (PCHE) are being considered as part of several SCO2 Brayton designs to further reduce equipment size with increased energy density. Several designs plan to use a gas cooler operating near the pseudo-critical point of carbon dioxide to benefit from large variations in thermophysical properties, but further work is needed to validate correlations for heat transfer and pressure-drop characteristics of SCO2 flows in candidate PCHE channel designs for a variety of operating conditions. This paper presents work on experimental measurements of the heat transfer and pressure drop behavior of miniature channels using carbon dioxide at supercritical pressure. Results from several plate geometries tested in horizontal cooling-mode flow are presented, including a straight semi-circular channel, zigzag channel with a bend angle of 80 degrees, and a channel with a staggered array of extruded airfoil pillars modeled after a NACA 0020 airfoil with an 8.1 mm chord length facing into the flow. Heat transfer coefficients and bulk temperatures are calculated from measured local wall temperatures and local heat fluxes. The experimental results are compared to several methods for estimating the friction factor and Nusselt number of cooling-mode flows at supercritical pressures in millimeter-scale channels. (authors)

  20. Plant Responses to Rising Carbon Dioxide and Nitrogen Relations

    OpenAIRE

    Bloom, Arnold J.

    2009-01-01

    The responses of higher plants to rising carbon dioxide concentration in the atmosphere are strongly dependent on their ability to acquire mineral nitrogen, ammonium and nitrate. Elevated atmospheric carbon dioxide limits both sources and sinks of plant mineral nitrogen. With regard to sources, elevated carbon dioxide stimulates microbial immobilization and inhibits nitrogen fixation. With regard to sinks, elevated carbon dioxide inhibits nitrate assimilation into amino acids within the shoo...

  1. LFR "Lead-Cooled Fast Reactor"

    Energy Technology Data Exchange (ETDEWEB)

    Cinotti, L; Fazio, C; Knebel, J; Monti, S; Abderrahim, H A; Smith, C; Suh, K

    2006-05-11

    The main purpose of this paper is to present the current status of development of the Lead-cooled Fast Reactor (LFR) in Generation IV (GEN IV), including the European contribution, to identify needed R&D and to present the corresponding GEN IV International Forum (GIF) R&D plan [1] to support the future development and deployment of lead-cooled fast reactors. The approach of the GIF plan is to consider the research priorities of each member country in proposing an integrated, coordinated R&D program to achieve common objectives, while avoiding duplication of effort. The integrated plan recognizes two principal technology tracks: (1) a small, transportable system of 10-100 MWe size that features a very long refuelling interval, and (2) a larger-sized system rated at about 600 MWe, intended for central station power generation. This paper provides some details of the important European contributions to the development of the LFR. Sixteen European organizations have, in fact, taken the initiative to present to the European Commission the proposal for a Specific Targeted Research and Training Project (STREP) devoted to the development of a European Lead-cooled System, known as the ELSY project; two additional organizations from the US and Korea have joined the project. Consequently, ELSY will constitute the reference system for the large lead-cooled reactor of GEN IV. The ELSY project aims to demonstrate the feasibility of designing a competitive and safe fast power reactor based on simple technical engineered features that achieves all of the GEN IV goals and gives assurance of investment protection. As far as new technology development is concerned, only a limited amount of R&D will be conducted in the initial phase of the ELSY project since the first priority is to define the design guidelines before launching a larger and expensive specific R&D program. In addition, the ELSY project is expected to benefit greatly from ongoing lead and lead-alloy technology

  2. Immobilized Ruthenium Catalyst for Carbon Dioxide Hydrogenation

    Institute of Scientific and Technical Information of China (English)

    Ying Min YU; Jin Hua FEI; Yi Ping ZHANG; Xiao Ming ZHENG

    2006-01-01

    Three kinds of cross linked polystyrene resin (PS) supported ruthenium complexes were developed as catalysts for the synthesis of formic acid from carbon dioxide hydrogenation. Many factors, such as the functionalized supports, solvents and ligands, could influence their activities and reuse performances greatly. These immobilized catalysts also offer the industrial advantages such as easy separation.

  3. Carbon Dioxide in Arable Soil Profiles

    DEFF Research Database (Denmark)

    Chirinda, Ngoni; Plauborg, Finn; Heckrath, Goswin Johann;

    2014-01-01

    Carbon dioxide (CO2) concentrations in arable soil profiles are influenced by autotrophic and heterotrophic respiration as well as soil physical properties that regulate gas transport. Whereas different methods have been used to assess dynamics of soil CO2 concentrations, our understanding on the...

  4. Tourism Transport, Technology, and Carbon Dioxide Emissions

    NARCIS (Netherlands)

    Peeters, P.M.

    2010-01-01

    Technological development from horse-drawn carriages to the new Airbus A380 has led to a remarkable increase in both the capacity and speed of tourist travel. This development has an endogenous systemic cause and will continue to increase carbon dioxide emissions/energy consumption if left unchecked

  5. Heat transfer coefficient for boiling carbon dioxide

    DEFF Research Database (Denmark)

    Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik

    1998-01-01

    Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The calculated heat transfer coeeficient has been compared with the Chart correlation of Shah. The Chart Correlation predits too low heat transfer coefficient but the ratio...

  6. Heat transfer coeffcient for boiling carbon dioxide

    DEFF Research Database (Denmark)

    Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik

    1997-01-01

    Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The pipe is heated by condensing R22 outside the pipe. The heat input is supplied by an electrical heater wich evaporates the R22. With the heat flux assumed constant over...

  7. Biofixation of Carbon dioxide by Chlamydomonas sp. in a Tubular Photobioreactor

    Directory of Open Access Journals (Sweden)

    H Hadiyanto

    2012-02-01

    Full Text Available The biogas production from anaerobic digestion is a potential fuel for power generators application, if biogas can be upgraded to the same standards as fossil natural gas by CO2, H2S, and other non-combustible component removal. Microalgae Chlamydomonas sp. has potency to biofix the carbon dioxide and can be used as an additional food ingredient. The variations of flow rate and carbon dioxide concentration in the process resulting different value of biomass production and carbon dioxide biofixation. Biomass production at 40% carbon dioxide concentration obtained 5.685 gr/dm3 at 10% carbon dioxide concentration obtained 4.892 gr/dm3. The greatest value of carbon dioxide absorption occurs at a 40% concentration amounting to 12.09%. The rate of growth and productivity of microalgae tend to rise in 10% and 20% (%v carbon dioxide concentration, but began started a constant at 30% and 40% (%v carbon dioxide concentration. Biomass production tends to increase in light conditions while a constant in dark conditions. This study used Chlamydomonas sp. as media culture and performed on bubble column and tubular reactor with 6 litres of culture medium at a temperature of 28oC and atmospheric pressure.

  8. Biofixation of Carbon dioxide by Chlamydomonas sp. in a Tubular Photobioreactor

    Directory of Open Access Journals (Sweden)

    H Hadiyanto

    2012-04-01

    Full Text Available The biogas production from anaerobic digestion is a potential fuel for power generators application, if biogas can be upgraded to the same standards as fossil natural gas by CO2, H2S, and other non-combustible component removal. Microalgae Chlamydomonas sp. has potency to biofix the carbon dioxide and can be used as an additional food ingredient. The variations of flow rate and carbon dioxide concentration in the process resulting different value of biomass production and carbon dioxide biofixation. Biomass production at 40% carbon dioxide concentration obtained 5.685 gr/dm3 at 10% carbon dioxide concentration obtained 4.892 gr/dm3. The greatest value of carbon dioxide absorption occurs at a 40% concentration amounting to 12.09%. The rate of growth and productivity of microalgae tend to rise in 10% and 20% (%v carbon dioxide concentration, but began started a constant at 30% and 40% (%v carbon dioxide concentration. Biomass production tends to increase in light conditions while a constant in dark conditions. This study used Chlamydomonas sp. as media culture and performed on bubble column and tubular reactor with 6 litres of culture medium at a temperature of 28oC and atmospheric pressure.

  9. 46 CFR 169.565 - Fixed carbon dioxide system.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Fixed carbon dioxide system. 169.565 Section 169.565... Lifesaving and Firefighting Equipment Firefighting Equipment § 169.565 Fixed carbon dioxide system. (a) The number of pounds of carbon dioxide required for each space protected must be equal to the gross volume...

  10. 27 CFR 26.222 - Still wines containing carbon dioxide.

    Science.gov (United States)

    2010-04-01

    ... carbon dioxide. 26.222 Section 26.222 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND... ISLANDS Formulas for Products From the Virgin Islands § 26.222 Still wines containing carbon dioxide. (a) General. Still wines may contain not more than 0.392 gram of carbon dioxide per 100 milliliters of...

  11. 27 CFR 26.52 - Still wines containing carbon dioxide.

    Science.gov (United States)

    2010-04-01

    ... carbon dioxide. 26.52 Section 26.52 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND... ISLANDS Formulas for Products From Puerto Rico § 26.52 Still wines containing carbon dioxide. (a) General. Still wines may contain not more than 0.392 gram of carbon dioxide per 100 milliliters of wine;...

  12. 9 CFR 313.5 - Chemical; carbon dioxide.

    Science.gov (United States)

    2010-01-01

    ... 9 Animals and Animal Products 2 2010-01-01 2010-01-01 false Chemical; carbon dioxide. 313.5... INSPECTION AND CERTIFICATION HUMANE SLAUGHTER OF LIVESTOCK § 313.5 Chemical; carbon dioxide. The slaughtering of sheep, calves and swine with the use of carbon dioxide gas and the handling in...

  13. 27 CFR 24.319 - Carbon dioxide record.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Carbon dioxide record. 24..., DEPARTMENT OF THE TREASURY LIQUORS WINE Records and Reports § 24.319 Carbon dioxide record. A proprietor who uses carbon dioxide in still wine shall maintain a record of the laboratory tests conducted...

  14. Optimization of structured cellular foam-based catalysts for low-temperature carbon dioxide methanation in a platelet milli-reactor

    International Nuclear Information System (INIS)

    Here, we present a preliminary study to choose a catalyst with enough catalytic activity at temperatures below 250 C, in order to study heat transfer in a platelet milli-reactor (PMR) with an infrared camera and a commercial window inserted on the top of our reactor that only withstands a maximal temperature of 250 C. The higher methane productivity of foam catalysts compared to powder catalysts was revealed. Foam catalysts, all impregnated with the same amount of active phase (Ni + Ru) and with different coatings, were compared to SiC only impregnated with Ni + Ru. The different coatings studied were: carbon nano-fibers (CNF), ceria-zirconia (CZ) and the combination of both. Both CNF and CZ wash-coats were able to increase the low specific surface area of the SiC foam. Moreover, the presence of ceria-zirconia was proven to be essential for ensuring high methane productivities. The catalyst combining both CNF and CZ showed the best results. (authors)

  15. Cooling of core debris within the reactor vessel lower head

    International Nuclear Information System (INIS)

    Under severe accident conditions, the most crucial action for recovery from the accident state is to cool the core debris and prevent or terminate attack on the remaining fission product barriers. One means of preventing attack on the containment structures is to retain the core debris within the reactor vessel. The TMI-2 accident demonstrated that this could be accomplished by water resident within the reactor vessel combined with injection on a continual basis to quench the debris and remove decay heat over the long term. Some accident situations could result in the transport of molten core debris to the lower plenum, as occurred in TMI-2, the boiloff of water in the lower plenum, and the inability to add water to the reactor coolant system (RCS). Even in this extreme set of circumstances, sufficient cooling may be available to prevent failure of the reactor pressure vessel (RPV) lower head and thereby retain the core debris within the vessel. Containment configurations like Zion would result in substantial accumulation of water around the lower parts of the reactor vessel for most accident sequences. For some PWR containments, there could be substantial water accumulation around the reactor vessel and the hot and cold legs. If this water could directly contact the carbon steel vessel surface and RCS piping, substantial energy could be removed from the primary system and in particular the RPV lower head. Experiments discussed in this paper demonstrate nucleate boiling heat removal rates from the outer surface of a simulated RPV lower head surrounded by typical reflective insulation used in nuclear power plants

  16. Electrochemistry of Water-Cooled Nuclear Reactors

    International Nuclear Information System (INIS)

    This project developed a comprehensive mathematical and simulation model for calculating thermal hydraulic, electrochemical, and corrosion parameters, viz. temperature, fluid flow velocity, pH, corrosion potential, hydrogen injection, oxygen contamination, stress corrosion cracking, crack growth rate, and other important quantities in the coolant circuits of water-cooled nuclear power plants, including both Boiling Water Reactors (BWRs) and Pressurized Water Reactors (PWRs). The model is being used to assess the three major operational problems in Pressurized Water Reactors (PWR), which include mass transport, activity transport, and the axial offset anomaly, and provide a powerful tool for predicting the accumulation of SCC damage in BWR primary coolant circuits as a function of operating history. Another achievement of the project is the development of a simulation tool to serve both as a training tool for plant operators and as an engineering test-bed to evaluate new equipment and operating strategies (normal operation, cold shut down and others). The development and implementation of the model allows us to estimate the activity transport or ''radiation fields'' around the primary loop and the vessel, as a function of the operating parameters and the water chemistry

  17. Electrochemistry of Water-Cooled Nuclear Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Macdonald, Dgiby; Urquidi-Macdonald, Mirna; Pitt, Jonathan

    2006-08-08

    This project developed a comprehensive mathematical and simulation model for calculating thermal hydraulic, electrochemical, and corrosion parameters, viz. temperature, fluid flow velocity, pH, corrosion potential, hydrogen injection, oxygen contamination, stress corrosion cracking, crack growth rate, and other important quantities in the coolant circuits of water-cooled nuclear power plants, including both Boiling Water Reactors (BWRs) and Pressurized Water Reactors (PWRs). The model is being used to assess the three major operational problems in Pressurized Water Reactors (PWR), which include mass transport, activity transport, and the axial offset anomaly, and provide a powerful tool for predicting the accumulation of SCC damage in BWR primary coolant circuits as a function of operating history. Another achievement of the project is the development of a simulation tool to serve both as a training tool for plant operators and as an engineering test-bed to evaluate new equipment and operating strategies (normal operation, cold shut down and others). The development and implementation of the model allows us to estimate the activity transport or "radiation fields" around the primary loop and the vessel, as a function of the operating parameters and the water chemistry.

  18. Ocean uptake of carbon dioxide

    International Nuclear Information System (INIS)

    Factors controlling the capacity of the ocean for taking up anthropogenic C02 include carbon chemistry, distribution of alkalinity, pCO2 and total concentration of dissolved C02, sea-air pCO2 difference, gas exchange rate across the sea-air interface, biological carbon pump, ocean water circulation and mixing, and dissolution of carbonate in deep sea sediments. A general review of these processes is given and models of ocean-atmosphere system based on our understanding of these regulating processes axe used to estimate the magnitude of C02 uptake by the ocean. We conclude that the ocean can absorb up to 35% of the fossil fuel emission. Direct measurements show that 55% Of C02 from fossil fuel burning remains in the atmosphere. The remaining 10% is not accounted for by atmospheric increases and ocean uptake. In addition, it is estimated that an amount equivalent to 30% of recent annual fossil fuel emissions is released into the atmosphere as a result of deforestation and farming. To balance global carbon budget, a sizable carbon sink besides the ocean is needed. Storage of carbon in terrestrial biosphere as a result of C02 fertilization is a potential candidate for such missing carbon sinks

  19. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Douglas P. Harrison; Ya Liang

    2001-10-01

    The objective of this project is to develop a simple, inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. Testing conducted previously confirmed that the reaction rate and achievable CO{sub 2} capacity of sodium carbonate decreased with increasing temperature, and that the global rate of reaction of sodium carbonate to sodium bicarbonate increased with an increase in both CO{sub 2} and H{sub 2}O concentrations. Energy balance calculations indicated that the rate of heat removal from the particle surface may determine the reaction rate for a particular particle system. This quarter, thermogravimetric analyses (TGA) were conducted which indicated that calcination of sodium bicarbonate at temperatures as high as 200 C did not cause a significant decrease in activity in subsequent carbonation testing. When sodium bicarbonate was subjected to a five cycle calcination/carbonation test, activity declined slightly over the first two cycles but was constant thereafter. TGA tests were also conducted with two other potential sorbents. Potassium carbonate was found to be less active than sodium carbonate, at conditions of interest in preliminary TGA tests. Sodium carbonate monohydrate showed negligible activity. Testing was also conducted in a 2-inch internal diameter quartz fluidized-bed reactor system. A five cycle test demonstrated that initial removals of 10 to 15 percent of the carbon dioxide in a simulated flue gas could be achieved. The carbonation reaction proceeded at temperatures as low as 41 C. Future work by TGA and in fixed

  20. Status of and prospects for gas-cooled reactors

    International Nuclear Information System (INIS)

    The IAEA International Working Group on Gas-Cooled Reactors (IWGGCR) (see Annex I), which was established in 1978, recommended to the Agency that a report be prepared in order to provide an up-to-date summary of gas-cooled reactor technology. The present Technical Report is based mainly on submissions of Member Countries of the IWGGCR and consists of four main sections. Beside some general information about the gas-cooled reactor line, section 1 contains a description of the incentives for the development and deployment of gas-cooled reactors in various Agency Member States. These include both electricity generation and process steam and process heat production for various branches of industry. The historical development of gas-cooled reactors is reviewed in section 2. In this section information is provided on how, when and why gas-cooled reactors have been developed in various Agency Member States and, in addition, a detailed description of the different gas-cooled reactor lines is presented. Section 3 contains information about the technical status of gas-cooled reactors and their applications. Gas-cooled reactors that are under design or construction or in operation are listed and shortly described, together with an outlook for future reactor designs. In this section the various applications for gas-cooled reactors are described in detail. These include both electricity generation and process steam and process heat production. The last section (section 4) is entitled ''Special features of gas-cooled reactors'' and contains information about the technical performance, fuel utilization, safety characteristics and environmental impact, such as radiation exposure and heat rejection

  1. Basic Engineering Research for D and D of R Reactor Storage Pond Sludge: Electrokinetics, Carbon Dioxide Extraction, and Supercritical Water Oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Michael A. Matthews; David A. Bruce,; Thomas A. Davis; Mark C. Thies; John W. Weidner; Ralph E. White

    2002-04-01

    Large quantities of mixed low level waste (MLLW) that fall under the Toxic Substances Control Act (TSCA) exist and will continue to be generated during D and D operations at DOE sites across the country. The standard process for destruction of MLLW is incineration, which has an uncertain future. The extraction and destruction of PCBs from MLLW was the subject of this research Supercritical Fluid Extraction (SFE) with carbon dioxide with 5% ethanol as cosolvent and Supercritical Waster Oxidation (SCWO) were the processes studied in depth. The solid matrix for experimental extraction studies was Toxi-dry, a commonly used absorbent made from plant material. PCB surrogates were 1.2,4-trichlorobenzene (TCB) and 2-chlorobiphenyl (2CBP). Extraction pressures of 2,000 and 4,000 psi and temperatures of 40 and 80 C were studied. Higher extraction efficiencies were observed with cosolvent and at high temperature, but pressure little effect. SCWO treatment of the treatment of the PCB surrogates resulted in their destruction below detection limits.

  2. Optimal design study of cylindrical finned reactor for solar adsorption cooling machine

    Energy Technology Data Exchange (ETDEWEB)

    Allouache, N. [Univ. des Sciences et de la Technologie Houari Boumediene, Bab Ezzouar (Algeria). Faculte de Genie Mecanique et de Genie des Procedes; Al Mers, A. [Moulay Ismail Univ., Meknes (Morocco). Ecole National Superieure d' Art et Metiers

    2010-07-01

    Solid adsorption cooling machines use medium temperature industrial waste heat together with a renewable energy source, such as solar energy. The adsorption cooling machine consists of an evaporator, a condenser and a reactor containing a solid adsorbent. In this study, a model was developed for thermodynamic performance analysis and optimization of a cylindrical finned solar reactor in an adsorption refrigerator working with activated carbon-ammonia. The heat and mass transfer in the adsorption cooling machine was determined. The model was validated using experimental results. The study investigated the sensitivity of the machine performance versus the geometrical configuration of the reactor. The study showed that for an optimized reactor, a higher fin number significantly reduces the heat losses of the reactor. It was concluded that the solar coefficient of performance (COP) of an optimized reactor can reach 45 per cent when the number of fins varies between 5 and 6. 10 refs., 4 figs.

  3. Testing Of Secondary Cooling Component Of TRIGA Mark Reactor

    International Nuclear Information System (INIS)

    The aim of this activity is to improve the knowledge of the mechanical testing technology of the research reactor cooling pipe material. The way which was chosen is through a series of testing to know the mechanical properties of carbon steel pipe used in TRIGA-MARK II secondary cooling pipe. Scopes of these testing activities are tensile testing, hardness testing, chemical composition analysis, and metallography analysis. Visual examination shows that thickness of the pipe was reduced over the range 0.31-1.76 mm and there was scales inside the pipe about 7.1-9.1 mm. Result of the mechanical testing shows that ultimate tensile strength, yield strength, elongation and. hardness of that material are 39 kg mm2, 34 kg/mm2, 38 %, and HV161, respectively. That yield strength value is on the design range

  4. Water cooled reactor technology: Safety research abstracts no. 1

    International Nuclear Information System (INIS)

    The Commission of the European Communities, the International Atomic Energy Agency and the Nuclear Energy Agency of the OECD publish these Nuclear Safety Research Abstracts within the framework of their efforts to enhance the safety of nuclear power plants and to promote the exchange of research information. The abstracts are of nuclear safety related research projects for: pressurized light water cooled and moderated reactors (PWRs); boiling light water cooled and moderated reactors (BWRs); light water cooled and graphite moderated reactors (LWGRs); pressurized heavy water cooled and moderated reactors (PHWRs); gas cooled graphite moderated reactors (GCRs). Abstracts of nuclear safety research projects for fast breeder reactors are published independently by the Nuclear Energy Agency of the OECD and are not included in this joint publication. The intention of the collaborating international organizations is to publish such a document biannually. Work has been undertaken to develop a common computerized system with on-line access to the stored information

  5. Effects of doubled carbon dioxide on rainfall responses to radiative processes of water clouds

    Science.gov (United States)

    Li, Xiaofan; Li, Tingting; Lou, Lingyun

    2014-12-01

    The effects of doubled carbon dioxide on rainfall responses to radiative processes of water clouds are investigated in this study. Two groups of two-dimensional cloud-resolving model sensitivity experiments with regard to pre-summer heavy rainfall around the summer solstice and tropical rainfall around the winter solstice are conducted and their five-day averages over the model domain are analyzed. In the presence of radiative effects of ice clouds, doubled carbon dioxide changes pre-summer rainfall from the decrease associated with the enhanced atmospheric cooling to the increase associated with the enhanced infrared cooling as a result of the exclusion of radiative effects of water clouds. Doubled carbon dioxide leads to the reduction in tropical rainfall, caused by the removal of radiative effects of water clouds through the suppressed infrared cooling. In the absence of radiative effects of ice clouds, doubled carbon dioxide changes pre-summer rainfall from the increase associated with the strengthened atmospheric warming to the decrease associated with the weakened release of latent heat caused by the elimination of radiative effects of water clouds. The exclusion of radiative effects of water clouds increases tropical rainfall through the strengthened infrared cooling, which is insensitive to the change in carbon dioxide.

  6. 40 CFR 86.316-79 - Carbon monoxide and carbon dioxide analyzer specifications.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Carbon monoxide and carbon dioxide... Test Procedures § 86.316-79 Carbon monoxide and carbon dioxide analyzer specifications. (a) Carbon monoxide and carbon dioxide measurements are to be made with nondispersive infrared (NDIR) an analyzers....

  7. Carbon dioxide stripping in aquaculture. part 1: terminology and reporting

    Science.gov (United States)

    Colt, John; Watten, Barnaby; Pfeiffer, Tim

    2012-01-01

    The removal of carbon dioxide gas in aquacultural systems is much more complex than for oxygen or nitrogen gas because of liquid reactions of carbon dioxide and their kinetics. Almost all published carbon dioxide removal information for aquaculture is based on the apparent removal value after the CO2(aq) + HOH ⇔ H2CO3 reaction has reached equilibrium. The true carbon dioxide removal is larger than the apparent value, especially for high alkalinities and seawater. For low alkalinity freshwaters (carbon dioxide removal.

  8. Materials for carbon dioxide separation

    International Nuclear Information System (INIS)

    The CO2 adsorption capacities at room temperature have been investigated by comparing carbon nanotubes, fullerene, graphenes, graphite and granular activated carbons. It turned out that the amount of the micropore surface area was dominating the CO2 adsorption ability. Another promising class of materials for CO2 capture and separation are CaO derived from the eggshells. Two aspects were studied in present work: a new hybrid materials synthesized by doping the CaTiO3 and the relationship between physisorption and chemisorption properties of CaO-based materials.

  9. Carbon dioxide research conference: carbon dioxide, science and consensus

    International Nuclear Information System (INIS)

    The DOE program focuses on three areas each of which requires more research before the many CO2-related questions can be answered. These areas include the global carbon cycle, climate effects, and vegetation effects. Additional information is needed to understand the sources and sinks of CO2. Research efforts include an attempt to estimate regional and global changes in temperature and precipitation. Increased atmospheric CO2 may be a potential benefit to vegetation and crops because it is an essential element required for plant growth. Eight separate papers are included

  10. Simplified numerical simulation of hot channel in sodium cooled reactor

    International Nuclear Information System (INIS)

    The thermal-hydraulic parameter values that restrict the operation of a liquid sodium cooled reactor are not established by the average conditions of the coolant in the reactor core but by the extreme conditions of the hot channel. The present work was developed to analysis of hot channel of a sodium cooled reactor, adapting to this reactor an existent simplified model for hot channel of pressurized water reactor. The model was applied for a standard sodium reactor and the results are considered satisfatory. (author)

  11. Status of national gas cooled reactor programmes

    International Nuclear Information System (INIS)

    This report has been compiled as a central source of summary-level information on the present status of High Temperature Gas-Cooled Reactor (HTGR) programmes in the world and on future plans for the continued development and deployment of HTGRs. Most of the information concerns the programmes in the United States, Germany, Japan and the Soviet Union, countries that have had large programmes related to HTGR technology for several years. Summary-level information is also provided in the report on HTGR-related activities in several other countries who either have an increasing interest in the technology and/or who are performing some development efforts related to HTGR technology. The report contains a summary-level update on the MAGNOX and AGR programmes. This is the twelfth issue of the document, the first of which was issued in March, 1979. The report has been prepared in the IAEA Nuclear Power Technology Development Section. Figs and tabs

  12. Technological readiness of evolutionary water cooled reactors

    International Nuclear Information System (INIS)

    Nuclear energy has evolved to a mature industry that supplies over 16% of the world's electricity, and it represents an important option for meeting the global energy demands of the coming century in an environmentally acceptable manner. New, evolutionary water cooled reactor designs that build on successful performance of predecessors have been developed; these designs have generally been guided by wishes to reduce cost, to improve availability and reliability, and to meet increasingly stringent safety objectives. These three aspects are important factors in what has been called technological readiness for an expanded deployment of nuclear power; a major increase in utilization of nuclear power will only occur if it is economically competitive, and meets safety expectations. To this end, the industry will also have to maintain or improve the public perception of nuclear power as a benign, economical and reliable energy source. (author)

  13. Seismic behaviour of gas cooled reactor components

    International Nuclear Information System (INIS)

    On invitation of the French Government the Specialists' Meeting on the Seismic Behaviour of Gas-Cooled Reactor Components was held at Gif-sur-Yvette, 14-16 November 1989. This was the second Specialists' Meeting on the general subject of gas-cooled reactor seismic design. There were 27 participants from France, the Federal Republic of Germany, Israel, Japan, Spain, Switzerland, the United Kingdom, the Soviet Union, the United States, the CEC and IAEA took the opportunity to present and discuss a total of 16 papers reflecting the state of the art of gained experiences in the field of their seismic qualification approach, seismic analysis methods and of the capabilities of various facilities used to qualify components and verify analytical methods. Since the first meeting, the sophistication and expanded capabilities of both the seismic analytical methods and the test facilities are apparent. The two main methods for seismic analysis, the impedance method and the finite element method, have been computer-programmed in several countries with the capability of each of the codes dependent on the computer capability. The correlations between calculation and tests are dependent on input assumptions such as boundary conditions, soil parameters and various interactions between the soil, the buildings and the contained equipment. The ability to adjust these parameters and match experimental results with calculations was displayed in several of the papers. The expanded capability of some of the new test facilities was graphically displayed by the description of the SAMSON vibration test facility at Juelich, FRG, capable of dynamically testing specimens weighing up to 25 tonnes, and the TAMARIS facility at the CEA laboratories in Gif-sur-Yvette where the largest table is capable of testing specimens weighing up to 100 tonnes. The proceedings of this meeting contain all 16 presented papers. A separate abstract was prepared for each of these papers. Refs, figs and tabs

  14. Carbon Dioxide Mitigation Benefit of High-Speed Railway in Terms of Carbon Tax

    OpenAIRE

    Fu Yanbing; Zhang Sufen; Xie Meiquan; Li Shuping; Huang Zelin

    2013-01-01

    This paper calculates the carbon dioxide mitigation benefit of high-speed railway based on the carbon dioxide tax policy. We define the carbon dioxide emission system boundary for high-speed railway in its whole life cycle and estimate the life cycle carbon dioxide inventories during its construction, application, and recovery stages. And then we establish a theoretical model to calculate the life cycle carbon dioxide mitigation quantity for high-speed railway when compared with road transpor...

  15. Fast reactor cooled by supercritical light water

    Energy Technology Data Exchange (ETDEWEB)

    Ishiwatari, Yuki; Mukouhara, Tami; Koshizuka, Seiichi; Oka, Yoshiaki [Tokyo Univ., Nuclear Engineering Research Lab., Tokai, Ibaraki (Japan)

    2001-09-01

    This report introduces the result of a feasibility study of a fast reactor cooled by supercritical light water (SCFR) with once-through cooling system. It is characterized by (1) no need of steam separator, recirculation system, or steam generator, (2) 1/7 of core flow rate compared with BWR or PWR, (3) high temperature and high pressure permits small turbine and high efficiency exceeding 44%, (4) structure and operation of major components are already experienced by LWRs or thermal power plants. Modification such as reducing blanket fuels and increasing seed fuels are made to achieve highly economic utilization of Pu and high power (2 GWe). The following restrictions were satisfied. (1) Maximum linear heat rate 39 kW/m, (2) Maximum surface temperature of Inconel cladding 620degC, (3) Negative void reactivity coefficient, (4) Fast neutron irradiation rate at the inner surface of pressure vessel less than 2.0x10{sup 19} n/cm{sup 2}. Thus the high power density of 167 MW/m{sup 3} including blanket is thought to contributes economy. The high conversion is attained to be 0.99 Pu fission residual rate by the outer radius of fuel rod of 0.88 mm. The breeding of 1.034 by Pu fission residual rate can be achieved by using briquette (tube-in-shell) type fuel structure. (K. Tsuchihashi)

  16. Carbon dioxide emissions from biochar in soil

    DEFF Research Database (Denmark)

    Bruun, S; Clauson-Kaas, S; Bobul'ská, L;

    2014-01-01

    -sterilized soils. It emerged that carbonate may be concentrated or form during or after biochar production, resulting in significant carbonate contents. If CO2 released from carbonates in short-term experiments is misinterpreted as mineralization of biochar, the impact of this process may be significantly over...... evolution. Finally, we found that both production temperature and clay content affect biochar mineralization. As protective mechanisms hypothesized to prevent degradation of organic matter in soil usually implicate clay, we conclude that biochar is likely to be protected from mineralization during the early......The stability of biochar in soil is of importance if it is to be used for carbon sequestration and long-term improvement of soil properties. It is well known that a significant fraction of biochar is highly stable in soil, but carbon dioxide (CO2) is also released immediately after application...

  17. Carbon dioxide in vascular imaging and intervention

    Energy Technology Data Exchange (ETDEWEB)

    Yang Xiaoming [Dept. of Clinical Radiology, Univ. Hospital, Kuopio (Finland); Manninen, H. [Dept. of Clinical Radiology, Univ. Hospital, Kuopio (Finland); Soimakallio, S. [Dept. of Clinical Radiology, Univ. Hospital, Kuopio (Finland)

    1995-07-01

    Angiography with iodinated contrast agents is bound up with the risks of contrast-induced nephrotoxicity and hypersensitivity, which led to the idea of using carbon dioxide (CO{sub 2}) gas as a negative contrast medium to eliminate these drawbacks. During the last decade, refinements and experiences have proved carbon dioxide digital subtraction angiography (CO{sub 2}-DSA) to be an accurate, safe, and clinically promising vascular imaging modality, with the advantages of no hypersensitivity and no nephrotoxicity as well as minimal patient discomfort. In this article, we have reviewed the history, physical and chemical aspects, techniques, and pathophysiologic changes with the use of CO{sub 2}-DSA as well as some clinical trials. Applications of CO{sub 2} gas in vascular interventions and other imagings, and the advantages and limitations of using CO{sub 2} gas in DSA are also discussed. (orig.).

  18. Carbon dioxide in vascular imaging and intervention.

    Science.gov (United States)

    Yang, X; Manninen, H; Soimakallio, S

    1995-07-01

    Angiography with iodinated contrast agents is bound up with the risks of contrast-induced nephrotoxicity and hypersensitivity, which led to the idea of using carbon dioxide (CO2) gas as a negative contrast medium to eliminate these drawbacks. During the last decade, refinements and experiences have proved carbon dioxide digital subtraction angiography (CO2-DSA) to be an accurate, safe, and clinically promising vascular imaging modality, with the advantages of no hypersensitivity and no nephrotoxicity as well as minimal patient discomfort. In this article, we have reviewed the history, physical and chemical aspects, techniques, and pathophysiologic changes with the use of CO2-DSA as well as some clinical trials. Applications of CO2 gas in vascular interventions and other imagings, and the advantages and limitations of using CO2 gas in DSA are also discussed. PMID:7619608

  19. Recycling technology of emitted carbon dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Arakawa, Hironori [National Inst. of Materials and Chemical Research (NIMC), Ibaraki (Japan)

    1993-12-31

    Ways to halt global warming are being discussed worldwide. Global warming is an energy problem which is mainly attributed to the large volumes of carbon dioxide (CO{sub 2}) released into the atmosphere from the rapid increase in energy consumption since the Industrial Revolution. The basic solution to the problem, therefore, is to cut consumption of fossil fuels. To this end, it is important to promote energy conservation by improving the fuel efficiency of machines, as well as shift to energy sources that do not emit carbon dioxide and develop related technologies. If current trends in economic growth continue in the devloping world as well as the developed countries, there can be no doubt that energy consumption will increase. Therefore, alongside energy conservation and the development of alternative energies, the importance of technologies to recover and fix CO{sub 2} will increase in the fight against global warming.

  20. Sequestering ADM ethanol plant carbon dioxide

    Science.gov (United States)

    Finley, R.J.; Riddle, D.

    2008-01-01

    Archer Daniels Midland Co. (ADM) and the Illinois State Geological Survey (ISGS) are collaborating on a project in confirming that a rock formation can store carbon dioxide from the plant in its pores. The project aimed to sequester the gas underground permanently to minimize release of the greenhouse gas into the atmosphere. It is also designed to store one million tons of carbon dioxide over a three-year period. The project is worth $84.3M, funded by $66.7M from the US Department Energy, supplemented by co-funding from ADM and other corporate and state resources. The project will start drilling of wells to an expected depth over 6500 feet into the Mount Simon Sandstone formation.

  1. Supercritical carbon dioxide decontamination of PAH contaminants

    International Nuclear Information System (INIS)

    Before the 1940's, more than 2,000 manufactured gas plant sites existed across North America for the production of a low Btu gas for heating and lighting. These sites, now abandoned, are contaminated with polycyclic aromatic hydrocarbons (PAHs), a coal gasification byproduct that was dumped on-site into unlined pits. The potential for ground water contamination of PAHs has made these sites an environmental concern. The remediation of PAH contaminated sites is difficult to achieve by conventional cleaning methods. In this work, supercritical carbon dioxide extraction has been investigated on a town gas soil containing 3.37 wt% contamination. The soil has been remediated in a 300 cm3 semi-continuous extraction vessel and the effects of solvent temperature, pressure, and density will be discussed. Supercritical carbon dioxide extraction is an emerging technology that can extract compounds that are difficult or impossible by conventional processes

  2. Carbon dioxide in vascular imaging and intervention

    International Nuclear Information System (INIS)

    Angiography with iodinated contrast agents is bound up with the risks of contrast-induced nephrotoxicity and hypersensitivity, which led to the idea of using carbon dioxide (CO2) gas as a negative contrast medium to eliminate these drawbacks. During the last decade, refinements and experiences have proved carbon dioxide digital subtraction angiography (CO2-DSA) to be an accurate, safe, and clinically promising vascular imaging modality, with the advantages of no hypersensitivity and no nephrotoxicity as well as minimal patient discomfort. In this article, we have reviewed the history, physical and chemical aspects, techniques, and pathophysiologic changes with the use of CO2-DSA as well as some clinical trials. Applications of CO2 gas in vascular interventions and other imagings, and the advantages and limitations of using CO2 gas in DSA are also discussed. (orig.)

  3. Fluorination of uranium and plutonium dioxides in flame tower reactors

    International Nuclear Information System (INIS)

    Fluorination of uranium and plutonium dioxides by fluorine is discussed for the flame tower reactor, which is one of possible reactors is FLUOREX process, a hybrid reprocessing combining a fluoride volatility process and a solvent extraction. A reaction model for a shrinking particle with an un-reacted shrinking core is applied to the fluorination of plutonium dioxide and the reaction rate constants are determined in low temperature range around 400degC using the reported kinetic data [Iwasaki et al., J. Nucl. Sci. Technol., 11, 403 (1974)]. The determined rate equations are used to analyze the fluorination of uranium and plutonium dioxides in the high temperature range (800-1,200degC), where the flame tower reactor is operated. For uranium dioxides the diffusion of fluorine to the particle controls the overall fluorination reaction, and the model can predict the recovery of uranium to the product of uranium hexafluoride. For plutonium dioxides, however, the recoveries of plutonium calculated by the presented model do not agree with the experimental recoveries. It is suggested that the reaction mechanism for the fluorination of plutonium dioxide in the high temperature range is different from that in the low temperature range. (author)

  4. Plasma beam discharge in carbon dioxide

    International Nuclear Information System (INIS)

    The paper deals with the dissociation of carbon dioxide in nonequilibrium plasma of a stationary plasma-beam discharge. Experimental results of spectroscopic and probe measurements of plasma parameters are given. Moreover, a mass-spectrometric analysis of gaseous products of the chemical reactions is presented. In addition the measurement of the deposition rate of solid products by means of a quartz oscillator is described. The results show that plasma beam discharge is an effective tool for inducing plasma-chemical reactions. (author)

  5. Pulsed discharge plasmas in supercritical carbon dioxide

    OpenAIRE

    Kiyan, Tsuyoshi; Uemura, A.; Tanaka, K.; Zhang, C. H.; Namihira, Takao; Sakugawa, Takashi; Katsuki, Sunao; Akiyama, Hidenori; Roy, B.C; Sasaki, M.; Goto, M; キヤン, ツヨシ; ナミヒラ, タカオ; サクガワ, タカシ; カツキ, スナオ

    2005-01-01

    In recent years, several studies about electrical discharge plasma in supercritical carbon dioxide (CO2) have been carried out. One of the unique characteristics of supercritical fluid is a large density fluctuation near the critical point that can result in marked dramatic changes of thermal conductivity. Therefore, the electrical discharge plasma produced in supercritical fluid has unique features and reactions unlike those of normal plasma produced in gas phase. In our experiments, two typ...

  6. CIVIL AVIATION CARBON DIOXIDE EMISSIONS IN CHINA

    OpenAIRE

    Chen, Sainan

    2013-01-01

    With the social and economic development, the civil aviation industry of China is experiencing rapid growth. This growth will lead to more CO2 emissions. Carbon dioxide emissions and greenhouse effect are already serious problems especially in China, but also all over the world. Civil aviation has brought environmental pollution in the context of improving social activity and economic growth. Because of civil aviation, the rapid increase of the total amount of air pollutants are also in...

  7. Pre-Analysis of Triga Mark II Reactor Cooling System

    OpenAIRE

    AKAY, Orhan Erdal

    2012-01-01

    In this study, work of the reactor cooling system is divided into two time zone. The second cooling circuit has been that the conditions required operating. Cooling system which is the center of the heat exchanger total heat transfer coefficient correlations were calculated using the theoretical. The design values were compared with results obtained by calculation.

  8. Carbon dioxide in Arctic and subarctic regions

    Energy Technology Data Exchange (ETDEWEB)

    Gosink, T. A.; Kelley, J. J.

    1981-03-01

    A three year research project was presented that would define the role of the Arctic ocean, sea ice, tundra, taiga, high latitude ponds and lakes and polar anthropogenic activity on the carbon dioxide content of the atmosphere. Due to the large physical and geographical differences between the two polar regions, a comparison of CO/sub 2/ source and sink strengths of the two areas was proposed. Research opportunities during the first year, particularly those aboard the Swedish icebreaker, YMER, provided additional confirmatory data about the natural source and sink strengths for carbon dioxide in the Arctic regions. As a result, the hypothesis that these natural sources and sinks are strong enough to significantly affect global atmospheric carbon dioxide levels is considerably strengthened. Based on the available data we calculate that the whole Arctic region is a net annual sink for about 1.1 x 10/sup 15/ g of CO/sub 2/, or the equivalent of about 5% of the annual anthropogenic input into the atmosphere. For the second year of this research effort, research on the seasonal sources and sinks of CO/sub 2/ in the Arctic will be continued. Particular attention will be paid to the seasonal sea ice zones during the freeze and thaw periods, and the tundra-taiga regions, also during the freeze and thaw periods.

  9. Carbon dioxide embolism during laparoscopic sleeve gastrectomy

    Directory of Open Access Journals (Sweden)

    Amir Abu Zikry

    2011-01-01

    Full Text Available Bariatric restrictive and malabsorptive operations are being carried out in most countries laparoscopically. Carbon dioxide or gas embolism has never been reported in obese patients undergoing bariatric surgery. We report a case of carbon dioxide embolism during laparoscopic sleeve gastrectomy (LSG in a young super obese female patient. Early diagnosis and successful management of this complication are discussed. An 18-year-old super obese female patient with enlarged fatty liver underwent LSG under general anesthesia. During initial intra-peritoneal insufflation with CO 2 at high flows through upper left quadrant of the abdomen, she had precipitous fall of end-tidal CO 2 and SaO 2 % accompanied with tachycardia. Early suspicion led to stoppage of further insufflation. Clinical parameters were stabilized after almost 30 min, while the blood gas analysis was restored to normal levels after 1 h. The area of gas entrainment on the damaged liver was recognized by the surgeon and sealed and the surgery was successfully carried out uneventfully. Like any other laparoscopic surgery, carbon dioxide embolism can occur during bariatric laparoscopic surgery also. Caution should be exercised when Veress needle is inserted through upper left quadrant of the abdomen in patients with enlarged liver. A high degree of suspicion and prompt collaboration between the surgeon and anesthetist can lead to complete recovery from this potentially fatal complication.

  10. High Temperature Gas-Cooled Test Reactor Options Status Report

    Energy Technology Data Exchange (ETDEWEB)

    Sterbentz, James William [Idaho National Lab. (INL), Idaho Falls, ID (United States); Bayless, Paul David [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-08-01

    Preliminary scoping calculations are being performed for a 100 MWt gas-cooled test reactor. The initial design uses standard prismatic blocks and 15.5% enriched UCO fuel. Reactor physics and thermal-hydraulics simulations have been performed to identify some reactor design features to investigate further. Current status of the effort is described.

  11. Development of studies on helium cooled fast reactors

    International Nuclear Information System (INIS)

    A necessity is shown of developing breeders with high reproductive properties. Helium cooled fast reactor is considered. The reactor performances, heating circuit with the use of a steam turbine unit in the secondary circuit is outlined. The reactor design and fuel assemblies are described

  12. Performance improvement options for the supercritical carbon dioxide brayton cycle

    International Nuclear Information System (INIS)

    The supercritical carbon dioxide (S-CO2) Brayton cycle is under development at Argonne National Laboratory as an advanced power conversion technology for Sodium-Cooled Fast Reactors (SFRs) as well as other Generation IV advanced reactors as an alternative to the traditional Rankine steam cycle. For SFRs, the S-CO2 Brayton cycle eliminates the need to consider sodium-water reactions in the licensing and safety evaluation, reduces the capital cost of the SFR plant, and increases the SFR plant efficiency. Even though the S-CO2 cycle has been under development for some time and optimal sets of operating parameters have been determined, those earlier development and optimization studies have largely been directed at applications to other systems such as gas-cooled reactors which have higher operating temperatures than SFRs. In addition, little analysis has been carried out to investigate cycle configurations deviating from the selected 'recompression' S-CO2 cycle configuration. In this work, several possible ways to improve S-CO2 cycle performance for SFR applications have been identified and analyzed. One set of options incorporates optimization approaches investigated previously, such as variations in the maximum and minimum cycle pressure and minimum cycle temperature, as well as a tradeoff between the component sizes and the cycle performance. In addition, the present investigation also covers options which have received little or no attention in the previous studies. Specific options include a 'multiple-recompression' cycle configuration, intercooling and reheating, as well as liquid-phase CO2 compression (pumping) either by CO2 condensation or by a direct transition from the supercritical to the liquid phase. Some of the options considered did not improve the cycle efficiency as could be anticipated beforehand. Those options include: a double recompression cycle, intercooling between the compressor stages, and reheating between the turbine stages. Analyses carried

  13. Carbon-14 measurement using carbon dioxide absorption method - Our experience

    International Nuclear Information System (INIS)

    Carbon-C14 measurement using absorption technique consists of direct absorption of sample carbon dioxide into an absorber - scintillator mixture. This technique is a simple, fast, less expensive and less hazardous technique compared to benzene synthesis or any other technique. This techniques enable us in preparing six/seven samples in a day while benzene synthesis technique takes two days for the preparation of one sample. It is useful for radiocarbon age up to about 38,000 a BP (∼1 pMC), which is adequate for most of the hydrological investigations. All the total dissolved inorganic carbon (TDIC) is precipitated as barium carbonate from the ∼60 to 70 liters of water at the site. In the laboratory, it is reacted with orthophosphoric acid to give carbon dioxide (CO2). This carbon dioxide is transferred into 0.5 L capacity cylinder. The reaction and collection of gas is done under vacuum using a glass vacuum line. Carbon dioxide is directly absorbed in 11.5 ml of carbasorb + 11 ml of Permaflour V (commercially not available) or its equivalent scintillator in the specially made absorption apparatus. Since, absorption process is exothermic, temperature of the medium is maintained at about 220 deg. C, it results in the absorption of ∼7 m moles of carbon dioxide per mL of cabasorb. As reaction progresses, bubbles can be seen rising slowly. The end point is marked by rapid rise in the solution level. Carbon dioxide obtained from oxalic acid (Standard) and background carbon dioxide are also absorbed in the same quantity of absorber and scintillator mixture. Samples, standard and background are transferred in 22 mL teflon vials and counted in low level liquid scintillation counter (LKB Wallac 1220 Quantulus) for 1000 minutes. The counting efficiency at best factor of merit (AON/ON/√B) is ∼60 % where AON is normalized net count rate of standard and B is the background count rate. The mean count rate of last fifteen background samples is 0.64 ± .0005 cpm with an

  14. Enzymatic conversion of carbon dioxide.

    Science.gov (United States)

    Shi, Jiafu; Jiang, Yanjun; Jiang, Zhongyi; Wang, Xueyan; Wang, Xiaoli; Zhang, Shaohua; Han, Pingping; Yang, Chen

    2015-10-01

    With the continuous increase in fossil fuels consumption and the rapid growth of atmospheric CO2 concentration, the harmonious state between human and nature faces severe challenges. Exploring green and sustainable energy resources and devising efficient methods for CO2 capture, sequestration and utilization are urgently required. Converting CO2 into fuels/chemicals/materials as an indispensable element for CO2 capture, sequestration and utilization may offer a win-win strategy to both decrease the CO2 concentration and achieve the efficient exploitation of carbon resources. Among the current major methods (including chemical, photochemical, electrochemical and enzymatic methods), the enzymatic method, which is inspired by the CO2 metabolic process in cells, offers a green and potent alternative for efficient CO2 conversion due to its superior stereo-specificity and region/chemo-selectivity. Thus, in this tutorial review, we firstly provide a brief background about enzymatic conversion for CO2 capture, sequestration and utilization. Next, we depict six major routes of the CO2 metabolic process in cells, which are taken as the inspiration source for the construction of enzymatic systems in vitro. Next, we focus on the state-of-the-art routes for the catalytic conversion of CO2 by a single enzyme system and by a multienzyme system. Some emerging approaches and materials utilized for constructing single-enzyme/multienzyme systems to enhance the catalytic activity/stability will be highlighted. Finally, a summary about the current advances and the future perspectives of the enzymatic conversion of CO2 will be presented. PMID:26055659

  15. Design Considerations for Economically Competitive Sodium Cooled Fast Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Hongbin Zhang; Haihua Zhao

    2009-05-01

    The technological viability of sodium cooled fast reactors (SFR) has been established by various experimental and prototype (demonstration) reactors such as EBR-II, FFTF, Phénix, JOYO, BN-600 etc. However, the economic competitiveness of SFR has not been proven yet. The perceived high cost premium of SFRs over LWRs has been the primary impediment to the commercial expansion of SFR technologies. In this paper, cost reduction options are discussed for advanced SFR designs. These include a hybrid loop-pool design to optimize the primary system, multiple reheat and intercooling helium Brayton cycle for the power conversion system and the potential for suppression of intermediate heat transport system. The design options for the fully passive decay heat removal systems are also thoroughly examined. These include direct reactor auxiliary cooling system (DRACS), reactor vessel auxiliary cooling system (RVACS) and the newly proposed pool reactor auxiliary cooling system (PRACS) in the context of the hybrid loop-pool design.

  16. Sodium cooling FBR type reactor plant

    International Nuclear Information System (INIS)

    In a sodium cooling FBR type reactor plant, a steam electrolysis type hydrogen forming device using high temperature steams as the starting material and a steam turbine power generator operated by high pressure/high temperature steams are disposed. During day time when a power demand is increased, a steam switch valve on the side of the hydrogen forming device is closed and the steam switch valve on the side of the power generator is opened to introduce substantially entire amount of steams to the steam turbine. During mid night when the power demand is decreased, the steam switch valve on the side of the power generator is closed and the steam switch valve on the side of the hydrogen forming device is opened to introduce substantially entire amount of steams to the steam electrolysis device, or the exhausted gases from the steam turbine type power generator is heated again by a heat exchanger and low pressure/high temperature steams are introduced to the steam electrolysis device. In this case, electric power is applied between a hydrogen electrode and an oxygen electrode to form a hydrogen gas and an oxygen gas, and the hydrogen gas is stored in a hydrogen storage vessel. It can easily cope with the fluctuation of the power demand, as well as hydrogen can be efficiently produced. (N.H.)

  17. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Alejandro Lopez-Ortiz; Douglas P. Harrison; Ya Liang

    2001-07-01

    Sodium based sorbents including sodium carbonate may be used to capture carbon dioxide from flue gas. A relatively concentrated carbon dioxide stream may be recoverable for sequestration when the sorbent is regenerated. Electrobalance tests indicated that sodium carbonate monohydrate was formed in a mixture of helium and water vapor at temperatures below 65 C. Additional compounds may also form, but this could not be confirmed. In the presence of carbon dioxide and water vapor, both the initial reaction rate of sodium carbonate with carbon dioxide and water and the sorbent capacity decreased with increasing temperature, consistent with the results from the previous quarter. Increasing the carbon dioxide concentration at constant temperature and water vapor concentration produced a measurable increase in rate, as did increasing the water vapor concentration at constant carbon dioxide concentration and temperature. Runs conducted with a flatter TGA pan resulted in a higher initial reaction rate, presumably due to improved gas-solid contact, but after a short time, there was no significant difference in the rates measured with the different pans. Analyses of kinetic data suggest that the surface of the sodium carbonate particles may be much hotter than the bulk gas due to the highly exothermic reaction with carbon dioxide and water, and that the rate of heat removal from the particle may control the reaction rate. A material and energy balance was developed for a cyclic carbonation/calcination process which captures about 26 percent of the carbon dioxide present in flue gas available at 250 C.

  18. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    International Nuclear Information System (INIS)

    The objective of this project is to develop a simple, inexpensive process to separate CO(sub 2) as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, or ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO(sub 2) stream after condensation of water vapor. This quarter, five cycle thermogravimetric tests were conducted at the Louisiana State University (LSU) with sodium bicarbonate Grade 3 (SBC(numbersign)3) which showed that carbonation activity declined slightly over 5 cycles following severe calcination conditions of 200 C in pure CO(sub 2). Three different sets of calcination conditions were tested. Initial carbonation activity (as measured by extent of reaction in the first 25 minutes) was greatest subsequent to calcination at 120 C in He, slightly less subsequent to calcination in 80% CO(sub 2)/20% H(sub 2)O, and lowest subsequent to calcination in pure CO(sub 2) at 200 C. Differences in the extent of reaction after 150 minutes of carbonation, subsequent to calcination under the same conditions followed the same trend but were less significant. The differences between fractional carbonation under the three calcination conditions declined with increasing cycles. A preliminary fixed bed reactor test was also conducted at LSU. Following calcination, the sorbent removed approximately 19% of the CO(sub 2) in the simulated flue gas. CO(sub 2) evolved during subsequent calcination was consistent with an extent of carbonation of approximately 49%. Following successful testing of SBC(numbersign)3 sorbent at RTI reported in the last quarter, a two cycle fluidized bed reactor test was conducted with trona as the sorbent precursor, which was calcined to sodium carbonate. In the first carbonation cycle, CO

  19. attenuation of reactor neutrons by uranium and thorium dioxides

    International Nuclear Information System (INIS)

    A formula is given which allows to calculate the total thermal cross-section of a crystalline uranium and thorium dioxide as function of crystal constants temperature and neutron wavelength. A computer codes PUO and SUO were developed to calculate the total attenuation of reactor neutrons through poly and mono-crystalline respectively. The calculated values of the neutrons cross-section of ploy crystalline uranium and thorium dioxide were compared with the available experimental ones in the energy range from 4 MeV to eV. The obtained agreement shows that the deduced formula fits the experimental data within accuracy less than 10%. A feasibility study on using depleted polycrystalline uranium dioxide as a cold neutron filter and the single crystal as a thermal one is given. The optimum crystal parameters and thickness for efficiently transmitting the thermal reactor neutrons while strongly attenuating both fast neutrons and γ-rays accompanying the thermal ones is also given

  20. Effects of carbon dioxide on Penicillium chrysogenum: an autoradiographic study

    International Nuclear Information System (INIS)

    Previous research has shown that dissolved carbon dioxide causes significant changes in submerged penicillin fermentations, such as stunted, swollen hyphae, increased branching, lower growth rates, and lower penicillin productivity. Influent carbon dioxide levels of 5 and 10% were shown through the use of autoradiography to cause an increase in chitin synthesis in submerged cultures of Penicillium chrysogenum. At an influent 5% carbon dioxide level, chitin synthesis is ca. 100% greater in the subapical region of P. chrysogenum hyphae than that of the control, in which there was no influent carbon dioxide. Influent carbon dioxide of 10% caused an increase of 200% in chitin synthesis. It is believed that the cell wall must be plasticized before branching can occur and that high amounts of dissolved carbon dioxide cause the cell to lose control of the plasticizing effect, thus the severe morphological changes occur

  1. The carbon dioxide thermometer and the cause of global warming

    International Nuclear Information System (INIS)

    Carbon dioxide in the air may be increasing because the world is warming. This possibility, which contradicts the hypothesis of an enhanced greenhouse warming driven by manmade emissions, is here pursued in two ways. First, increments in carbon dioxide are treated as readings of a natural thermometer that tracks global and hemispheric temperature deviations, as gauged by meteorologists' thermometers. Calibration of the carbon dioxide thermometer to conventional temperatures then leads to a history of carbon dioxide since 1856 that diverges from the ice-core record. Secondly, the increments of carbon dioxide can also be accounted for, without reference to temperature, by the combined effects of cosmic rays, El Nino and volcanoes. The most durable effect is due to cosmic rays. A solar wind history, used as a long-term proxy for the cosmic rays, gives a carbon dioxide history similar to that inferred from the global temperature deviations. (author)

  2. Nuclear power and carbon dioxide free automobiles

    International Nuclear Information System (INIS)

    Nuclear energy has been developed as a major source of electric power in Canada. Electricity from nuclear energy already avoids the emission of about 100 million tonnes of carbon dioxide to the atmosphere in Canada. This is a significant fraction of the 619 million tonnes of Canadian greenhouse gas emissions in 1995. However, the current scope of application of electricity to end use energy needs in Canada limits the contribution nuclear energy can make to carbon dioxide emission reduction. Nuclear energy can also contribute to carbon dioxide emissions reduction through expansion of the use of electricity to less traditional applications. Transportation, in particular contributed 165 million tonnes of carbon dioxide to the Canadian atmosphere in 1995. Canada's fleet of personal vehicles consisted of 16.9 million cars and light trucks. These vehicles were driven on average 21,000 km/year and generated 91 million tonnes of greenhouse gases expressed as a C02 equivalent. Technology to improve the efficiency of cars is under development which is expected to increase the energy efficiency from the 1995 level of about 10 litres/100 km of gasoline to under 3 litres/100km expressed as an equivalent referenced to the energy content of gasoline. The development of this technology, which may ultimately lead to the practical implementation of hydrogen as a portable source of energy for transportation is reviewed. Fuel supply life cycle greenhouse gas releases for several personal vehicle energy supply systems are then estimated. Very substantial reductions of greenhouse gas emissions are possible due to efficiency improvements and changing to less carbon intensive fuels such as natural gas. C02 emissions from on board natural gas fueled versions of hybrid electric cars would be decreased to approximately 25 million t/year from the current 91 million tonnes/year. The ultimate reduction identified is through the use of hydrogen fuel produced via electricity from CANDU power

  3. Interaction of carbon dioxide with Cu overlayers on Pt(111)

    DEFF Research Database (Denmark)

    Schumacher, N.; Andersson, Klas Jerker; Grabow, L.C.;

    2008-01-01

    Experimental and theoretical studies on the interaction of carbon dioxide with pseudomorphic and rough copper layers deposited on a platinum (111) single crystal are reported. Evidence for carbon dioxide dissociation and carbonate formation is presented and the relevance to methanol synthesis is...

  4. Catalytic conversion of methane: Carbon dioxide reforming and oxidative coupling

    KAUST Repository

    Takanabe, Kazuhiro

    2012-01-01

    Natural gas conversion remains one of the essential technologies for current energy needs. This review focuses on the mechanistic aspects of the development of efficient and durable catalysts for two reactions, carbon dioxide reforming and the oxidative coupling of methane. These two reactions have tremendous technological significance for practical application in industry. An understanding of the fundamental aspects and reaction mechanisms of the catalytic reactions reviewed in this study would support the design of industrial catalysts. CO 2 reforming of methane utilizes CO 2, which is often stored in large quantities, to convert as a reactant. Strategies to eliminate carbon deposition, which is the major problem associated with this reaction, are discussed. The oxidative coupling of methane directly produces ethylene in one reactor through a slightly exothermic reaction, potentially minimizing the capital cost of the natural gas conversion process. The focus of discussion in this review will be on the attainable yield of C 2 products by rigorous kinetic analyses.

  5. TITAN program and direct cycle fast reactor

    Energy Technology Data Exchange (ETDEWEB)

    Kato, Yasuyoshi; Yoshizawa, Yoshio; Nitawaki, Takeshi [Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, Tokyo (Japan)

    2000-07-01

    In December 1999, the Research Laboratory for Nuclear Reactors of the Tokyo Institute of Technology (TIT) started a new program for the development of advanced nuclear reactors with small and medium size. TITAN is the acronym for the program. A novel concept of a carbon dioxide cooled direct cycle fast reactor with a Rankin cycle has been proposed as the advanced nuclear reactors and evaluated for an alternative option to liquid metal cooled fast reactors (LMFRs). The use of carbon dioxide as coolant eliminates major safety related problems of sodium cooled fast reactors: positive sodium void reactivity, hazardous reaction between sodium and water or air. The decay heat is passively removed by allocating a storage tank of liquidized carbon dioxide between the regenerator and the condenser, and by introducing naturally the carbon dioxide vaporized from the tank into the core in the event of the depressurization accident. The direct cycle results in considerable simplification of the heat transport system owing to the absence of intermediate cooling and water-steam loops comparing with the LMFRs. The thermal efficiency of the direct cycle is evaluated as 34.3 %, which is slightly higher than those in the current BWRs and PWRs. (author)

  6. Elevated atmospheric carbon dioxide and ozone concentrations alter LAI through changes in phenology and leaf growth

    Science.gov (United States)

    Leaves are critical for harvesting light energy, taking up carbon dioxide (CO2) and transpiring water for cooling. Changes in leaf growth, expansion or development can integrate across the plant canopy and growing season to significantly impact productivity, yield and plant-atmosphere fluxes. Althou...

  7. PREPARATION OF MESOPOROUS CARBON BY CARBON DIOXIDE ACTIVATION WITH CATALYST

    Institute of Scientific and Technical Information of China (English)

    W.Z.Shen; A.H.Lu; J.T.Zheng

    2002-01-01

    A mesoporous activated carbon (AC) can be successfully prepared by catalytic activa-tion with carbon dioxide. For iron oxide as catalyst, there were two regions of mesoporesize distribution, i.e. 2-5nm and 30-70nm. When copper oxide or magnesium oxidecoexisted with iron oxide as composite catalyst, the content of pores with sizes of 2-5nm was decreased, while the pores with 30 70nm were increased significantly. Forcomparison, AC reactivated by carbon dioxide directly was also investigated. It wasshown that the size of mesopores of the resulting AC concentrated in 2-5nm with lessvolume. The adsorption of Congo red was tested to evaluate the property of the result-ing AC. Furthermore, the factors affecting pore size distribution and the possibility ofmesopore formation were discussed.

  8. Supercritical carbon dioxide: a solvent like no other

    Directory of Open Access Journals (Sweden)

    Jocelyn Peach

    2014-08-01

    Full Text Available Supercritical carbon dioxide (scCO2 could be one aspect of a significant and necessary movement towards green chemistry, being a potential replacement for volatile organic compounds (VOCs. Unfortunately, carbon dioxide has a notoriously poor solubilising power and is famously difficult to handle. This review examines attempts and breakthroughs in enhancing the physicochemical properties of carbon dioxide, focusing primarily on factors that impact solubility of polar and ionic species and attempts to enhance scCO2 viscosity.

  9. Supercritical carbon dioxide: a solvent like no other

    OpenAIRE

    Jocelyn Peach; Julian Eastoe

    2014-01-01

    Supercritical carbon dioxide (scCO2) could be one aspect of a significant and necessary movement towards green chemistry, being a potential replacement for volatile organic compounds (VOCs). Unfortunately, carbon dioxide has a notoriously poor solubilising power and is famously difficult to handle. This review examines attempts and breakthroughs in enhancing the physicochemical properties of carbon dioxide, focusing primarily on factors that impact solubility of polar and ionic species and at...

  10. Carbon dioxide kinetics and capnography during critical care

    OpenAIRE

    Anderson, Cynthia T; Breen, Peter H

    2000-01-01

    Greater understanding of the pathophysiology of carbon dioxide kinetics during steady and nonsteady state should improve, we believe, clinical care during intensive care treatment. Capnography and the measurement of end-tidal partial pressure of carbon dioxide (PETCO2) will gradually be augmented by relatively new measurement methodology, including the volume of carbon dioxide exhaled per breath (VCO2,br) and average alveolar expired PCO2 (PA̅E̅CO2). Future directions include the study of oxy...

  11. Designed amyloid fibers as materials for selective carbon dioxide capture

    OpenAIRE

    Li, Dan; Furukawa, Hiroyasu; Deng, Hexiang; Liu, Cong; Yaghi, Omar M.; Eisenberg, David S.

    2013-01-01

    New and improved materials capable of binding carbon dioxide are essential to addressing the global threat of accelerating climate change. The presently used industrial methods for carbon dioxide capture have severe drawbacks, including toxicity and energy inefficiency. Newer porous materials are so far less effective in water, invariably a component of combustion gases. Here, we present a material for carbon dioxide capture. This material, amyloid fibers in powdered form, selectively capture...

  12. Six-fold Coordinated Carbon Dioxide VI

    Energy Technology Data Exchange (ETDEWEB)

    Iota, V; Yoo, C; Klepeis, J; Jenei, Z

    2006-03-01

    Under standard conditions, carbon dioxide (CO{sub 2}) is a simple molecular gas and an important atmospheric constituent while silicon dioxide (SiO{sub 2}) is a covalent solid, and represents one of the fundamental minerals of the planet. The remarkable dissimilarity between these two group IV oxides is diminished at higher pressures and temperatures as CO{sub 2} transforms to a series of solid phases, from simple molecular to a fully covalent extended-solid V, structurally analogous to SiO{sub 2} tridymite. Here, we present the discovery of a new extended-solid phase of carbon dioxide (CO{sub 2}): a six-fold coordinated stishovite-like phase VI, obtained by isothermal compression of associated CO{sub 2}-II above 50GPa at 530-650K. Together with the previously reported CO{sub 2}-V and a-carbonia, this new extended phase indicates a fundamental similarity between CO{sub 2}--a prototypical molecular solid, and SiO{sub 2}--one of Earth's fundamental building blocks. The phase diagram suggests a limited stability domain for molecular CO{sub 2}-I, and proposes that the conversion to extended-network solids above 40-50 GPa occurs via intermediate phases II, III, and IV. The crystal structure of phase VI suggests strong disorder along the caxis in stishovite-like P4{sub 2}/mnm, with carbon atoms manifesting an average six-fold coordination within the framework of sp{sup 3} hybridization.

  13. Changes in plasma potassium concentration during carbon dioxide pneumoperitoneum

    DEFF Research Database (Denmark)

    Perner, A; Bugge, K; Lyng, K M;

    1999-01-01

    Hyperkalaemia with ECG changes had been noted during prolonged carbon dioxide pneumoperitoneum in pigs. We have compared plasma potassium concentrations during surgery in 11 patients allocated randomly to undergo either laparoscopic or open appendectomy and in another 17 patients allocated randomly...... to either carbon dioxide pneumoperitoneum or abdominal wall lifting for laparoscopic colectomy. Despite an increasing metabolic acidosis, prolonged carbon dioxide pneumoperitoneum resulted in only a slight increase in plasma potassium concentrations, which was both statistically and clinically...... insignificant. Thus hyperkalaemia is unlikely to develop in patients with normal renal function undergoing carbon dioxide pneumoperitoneum for laparoscopic surgery....

  14. [Determination of carbon dioxide released from soil at different humidities].

    Science.gov (United States)

    Imshenetskiĭ, A A; Murzakov, B G

    1978-01-01

    The detection of soil microorganisms by their evolution of carbon dioxide does not always correlate with the number of microorganisms and the rate of biochemical processes in soil. New microbial populations appear in the incubation chamber as the concentration of carbon dioxide increases; this results in an increase in the activity of such processes as photosynthesis, chemosynthesis and heterotrophic assimilation of carbon dioxide. Life detection on other planets by determining carbon dioxide evolved from the ground may lead to erroneous conclusions on the presence of microorganism in the ground. PMID:745559

  15. The carbon dioxide capture and geological storage

    International Nuclear Information System (INIS)

    This road-map proposes by the Group Total aims to inform the public on the carbon dioxide capture and geological storage. One possible means of climate change mitigation consists of storing the CO2 generated by the greenhouse gases emission in order to stabilize atmospheric concentrations. This sheet presents the CO2 capture from lage fossil-fueled combustion installations, the three capture techniques and the CO2 transport options, the geological storage of the CO2 and Total commitments in the domain. (A.L.B.)

  16. Nuclear energy significantly reduces carbon dioxide emissions

    International Nuclear Information System (INIS)

    This article is devoted to nuclear energy, to its acceptability, compatibility and sustainability. Nuclear energy is non-dispensable part of energy sources with vast innovation potential. The safety of nuclear energy, radioactive waste deposition, and prevention of risk from misuse of nuclear material have to be very seriously adjudged and solved. Nuclear energy is one of the ways how to decrease the contamination of atmosphere with carbon dioxide and it solves partially also the problem of global increase of temperature and climate changes. Given are the main factors responsible for the renaissance of nuclear energy. (author)

  17. Carbon Dioxide Mitigation by Microalgal Photosynthesis

    International Nuclear Information System (INIS)

    Algal growth studies of Chlorella strains were conducted in a batch mode with bench type experiments. Carbon dioxide fixation rates of the following green microalgae were determined: Chlorella sp. H84, Chlorella sp. A2, Chlorella sorokiniana UTEX 1230, Chlorella vulgaris, and Chlorella pyrenoidosa. C. vulgaris, among other strains of microalgae, showed the highest growth rate (1.17 optical density/5 days). Cultivating conditions for C. vulgaris that produced the highest growth rate were at concentrations of 243 μg CO2/mL, 10 mM ammonia, and 1 mM phosphate, with an initial pH range of 7-8

  18. Carbon dioxide capture and geological storage

    OpenAIRE

    2013-01-01

    Sustainable Carbon dioxide Capture and Storage, or CCS, can be achieved using geological means, an approach that differs in many ways from CO2 capture and storage in vegetation. Firstly, it differs because this latter approach enables CO2 to be stored only temporarily – for less than one year in annual plants or for several centuries in tree phytomass. Secondly, CO2 capture is associated with bioconversion of the sun’s energy which is then stored in biochemical form in the phytomass. As the t...

  19. Carbon dioxide detection in adult Odonata.

    Science.gov (United States)

    Piersanti, Silvana; Frati, Francesca; Rebora, Manuela; Salerno, Gianandrea

    2016-04-01

    The present paper shows, by means of single-cell recordings, responses of antennal sensory neurons of the damselfly Ischnura elegans when stimulated by air streams at different CO2 concentrations. Unlike most insects, but similarly to termites, centipedes and ticks, Odonata possess sensory neurons strongly inhibited by CO2, with the magnitude of the off-response depending upon the CO2 concentration. The Odonata antennal sensory neurons responding to CO2 are also sensitive to airborne odors; in particular, the impulse frequency is increased by isoamylamine and decreased by heptanoic and pentanoic acid. Further behavioral investigations are necessary to assign a biological role to carbon dioxide detection in Odonata. PMID:26831359

  20. Seismic stability of VGM type high temperature gas cooled reactors

    International Nuclear Information System (INIS)

    The main principles of the design provision of high temperature gas cooled VGM reactors seismic stability and the results of calculations, performed by linear-spectral method are presented. (author). 1 ref., 10 figs

  1. Killing wild geese with carbon dioxide or a mixture of carbon dioxide and argon

    NARCIS (Netherlands)

    Gerritzen, M.A.; Reimert, H.G.M.; Lourens, A.; Bracke, M.B.M.; Verhoeven, M.T.W.

    2013-01-01

    The killing of animals is the subject of societal and political debate. Wild geese are caught and killed on a regular basis for fauna conservation and damage control. Killing geese with carbon dioxide (CO2) is commonly practiced, but not listed in legislation on the protection of flora and fauna, an

  2. Conceptual design study of small sodium cooled reactors

    International Nuclear Information System (INIS)

    A conceptual design of various small metal fuel sodium cooled reactors has been studied in the feasibility study on commercialized fast breeder reactor cycle system. In FY2004 study, a 50 MWe power plant for remote places with a long life core without refueling and a 300 MWe modular reactor which pursues standardization for learning effect and reduction of capital risks. In the small reactor with a long life core, the reactor vessel is minimized without a permanent fuel handling system and the cooling system is simplified adopting 1 loop. The total mass of the reactor vessel and the cooling system is dramatically reduced and the concept has a potential to be an attractive power source for remote places. In the 300 MWe modular reactor, the cooling system adopts 1 loop and the ex-vessel fuel storage tank for spent fuels is eliminated adapting the in-vessel storage (IVS) which has a capacity for a 4 year storage. The reactor building is minimized without the ex-vessel storage. This concept has a potential to be an power source for key grids with modular constructions and a first plant with a small fuel cycle facility can demonstrate the metal fuel fast reactor cycle. (author)

  3. Mineralization of Carbon Dioxide: Literature Review

    Energy Technology Data Exchange (ETDEWEB)

    Romanov, V; Soong, Y; Carney, C; Rush, G; Nielsen, B; O' Connor, W

    2015-01-01

    CCS research has been focused on CO2 storage in geologic formations, with many potential risks. An alternative to conventional geologic storage is carbon mineralization, where CO2 is reacted with metal cations to form carbonate minerals. Mineralization methods can be broadly divided into two categories: in situ and ex situ. In situ mineralization, or mineral trapping, is a component of underground geologic sequestration, in which a portion of the injected CO2 reacts with alkaline rock present in the target formation to form solid carbonate species. In ex situ mineralization, the carbonation reaction occurs above ground, within a separate reactor or industrial process. This literature review is meant to provide an update on the current status of research on CO2 mineralization. 2

  4. Emergency cooling system for nuclear reactors

    International Nuclear Information System (INIS)

    Upon loss of coolant in a nuclear reactor as when a coolant supply or return line breaks, or both lines break, borated liquid coolant from an emergency source is supplied in an amount to absorb heat being generated in the reactor even after the control rods have been inserted. The liquid coolant flows from pressurized storage vessels outside the reactor to an internal manifold from which it is distributed to unused control rod guide thimbles in the reactor fuel assemblies. (author)

  5. Limiting Factors for External Reactor Vessel Cooling

    International Nuclear Information System (INIS)

    The method of external reactor vessel cooling (ERVC) that involves flooding of the reactor cavity during a severe accident has been considered a viable means for in-vessel retention (IVR). For high-power reactors, however, there are some limiting factors that might adversely affect the feasibility of using ERVC as a means for IVR. In this paper, the key limiting factors for ERVC have been identified and critically discussed. These factors include the choking limit for steam venting (CLSV) through the bottleneck of the vessel/insulation structure, the critical heat flux (CHF) for downward-facing boiling on the vessel outer surface, and the two-phase flow instabilities in the natural circulation loop within the flooded cavity. To enhance ERVC, it is necessary to eliminate or relax these limiting factors. Accordingly, methods to enhance ERVC and thus improve margins for IVR have been proposed and demonstrated, using the APR1400 as an example. The strategy is based on using two distinctly different methods to enhance ERVC. One involves the use of an enhanced vessel/insulation design to facilitate steam venting through the bottleneck of the annular channel. The other involves the use of an appropriate vessel coating to promote downward-facing boiling. It is found that the use of an enhanced vessel/insulation design with bottleneck enlargement could greatly facilitate the process of steam venting through the bottleneck region as well as streamline the resulting two-phase motions in the annular channel. By selecting a suitable enhanced vessel/insulation design, not only the CLSV but also the CHF limits could be significantly increased. In addition, the problem associated with two-phase flow instabilities and flow-induced mechanical vibration could be minimized. It is also found that the use of vessel coatings made of microporous metallic layers could greatly facilitate downward-facing boiling on the vessel outer surface. With vessel coatings, the local CHF limits at

  6. Role of small lead-cooled fast reactors for international deployment in worldwide sustainable nuclear energy supply

    International Nuclear Information System (INIS)

    , there is a need for small and medium size fast reactors in non-fuel cycle states operating in a converter mode as well as large sodium-cooled fast breeders in fuel cycle states. Desired attributes for exportable small fast reactors include: proliferation resistance features such as restricted access to fuel; long core life further restricting access by reducing or eliminating the need for refueling; restricted potential to be misused in a breeding mode; fuel form that is unattractive in the safeguards sense; and a conversion ratio of unity to self-generate as much fissile material as is consumed. Desired attributes for exportable small reactor deployments in developing nations and remote sites also include: a small power level to match the smaller demand of towns or sites that are off-grid or on immature local grids; low enough cost to be economically competitive with alternative energy sources available to developing nation customers (e.g. diesel generators in remote locations); readily transported and assembled from transportable modules; simple to operate and highly reliable reducing plant operating staff requirements; as well as high reliability and passive safety reducing the number of accident initiators and need for safety systems as well as reducing the size of the exclusion and emergency planning zones. The Lead-Cooled Fast Reactor (LFR) has the desired attributes. An example of a small exportable LFR concept is the 20 MWe (45 MWt) Small Secure Transportable Autonomous Reactor (SSTAR) incorporating proliferation resistance, fissile selfsufficiency, autonomous load following, a high degree of passive safety, and supercritical carbon dioxide Brayton cycle energy conversion for high plant efficiency and improved economic competitiveness.

  7. Design Requirements of an Advanced HANARO Reactor Core Cooling System

    International Nuclear Information System (INIS)

    An advanced HANARO Reactor (AHR) is an open-tank-type and generates thermal power of 20 MW and is under conceptual design phase for developing it. The thermal power is including a core fission heat, a temporary stored fuel heat in the pool, a pump heat and a neutron reflecting heat in the reflector vessel of the reactor. In order to remove the heat load, the reactor core cooling system is composed of a primary cooling system, a primary cooling water purification system and a reflector cooling system. The primary cooling system must remove the heat load including the core fission heat, the temporary stored fuel heat in the pool and the pump heat. The purification system must maintain the quality of the primary cooling water. And the reflector cooling system must remove the neutron reflecting heat in the reflector vessel of the reactor and maintain the quality of the reflector. In this study, the design requirement of each system has been carried out using a design methodology of the HANARO within a permissible range of safety. And those requirements are written by english intend to use design data for exporting the research reactor

  8. Gas-cooled reactor application for a university campus

    International Nuclear Information System (INIS)

    Large urban areas with unfavourable topographic and meteorological conditions suffer severe air pollution during the winter months. Use of low grade lignites, imported higher quality coal or imported fuel oil are the sources of air pollution in the form of sulphur dioxide, fly ash and soot. Large housing complexes or old and historical locations within the city are in need of pollution free centralized district heating systems. Natural gas imported from the Soviet Union is a solution for this problem. Lack of gas distribution network for high pressure gas within the city is the main bottle-neck for the heating systems utilizing natural gas. Concern of the safety of flammable high pressure gas circulating within the city is another drawback for the natural gas heating systems. Nuclear district heating is an environmentally viable option worth looking into it. Localized urban nuclear heating is an interesting solution for large urban areas with old and historical character. The results of a feasibility study on the HGR application for the Hacettepe University presented here, summarizes the concept of gas-cooled heating reactors specially designed for urban centers. The inherently safe characteristics of the pebble bed heating reactor makes localized urban nuclear heating a viable alternative to other heat sources. An economical analysis of various heat sources with equal power levels is done for the Beytepe campus of Hacettepe University in Ankara. Under special boundary conditions, the price for heat generation can be much lower for nuclear heating with GHR 20 than for hard coal or fuel oil. It is also possible that if the price escalation rate for natural gas exceeds 3%, then nuclear heating with GHR can be more competitive. It is concluded that the nuclear heating of Beytepe campus with a GHR 20 is feasible and economical. (author) 3 figs., 5 refs

  9. Natural circulating passive cooling system for nuclear reactor containment structure

    Science.gov (United States)

    Gou, Perng-Fei; Wade, Gentry E.

    1990-01-01

    A passive cooling system for the contaminant structure of a nuclear reactor plant providing protection against overpressure within the containment attributable to inadvertent leakage or rupture of the system components. The cooling system utilizes natural convection for transferring heat imbalances and enables the discharge of irradiation free thermal energy to the atmosphere for heat disposal from the system.

  10. Passive cooling system for nuclear reactor containment structure

    Science.gov (United States)

    Gou, Perng-Fei; Wade, Gentry E.

    1989-01-01

    A passive cooling system for the contaminant structure of a nuclear reactor plant providing protection against overpressure within the containment attributable to inadvertent leakage or rupture of the system components. The cooling system utilizes natural convection for transferring heat imbalances and enables the discharge of irradiation free thermal energy to the atmosphere for heat disposal from the system.

  11. Pharmaceutical applications of supercritical carbon dioxide.

    Science.gov (United States)

    Kaiser, C S; Römpp, H; Schmidt, P C

    2001-12-01

    The appearance of a supercritical state was already observed at the beginning of the 19th century. Nevertheless, the industrial extraction of plant and other natural materials started about twenty years ago with the decaffeination of coffee. Today carbon dioxide is the most common gas for supercritical fluid extraction in food and pharmaceutical industry. Since pure supercritical carbon dioxide is a lipophilic solvent, mixtures with organic solvents, especially alcohols, are used to increase the polarity of the extraction fluid; more polar compounds can be extracted in this way. The main fields of interest are the extraction of vegetable oils from plant material in analytical and preparative scale, the preparation of essential oils for food and cosmetic industry and the isolation of substances of pharmaceutical relevance. Progress in research was made by the precise measurement of phase equilibria data by means of different methods. Apart from extraction, supercritical fluid chromatography was introduced in the field of analytics, as well as micro- and nanoparticle formation using supercritical fluids as solvent or antisolvent. This review presents pharmaceutical relevant literature of the last twenty years with special emphasis on extraction of natural materials. PMID:11802652

  12. Adaptation to carbon dioxide tax in shipping

    International Nuclear Information System (INIS)

    This note discusses the consequences for the sea transport sector between Norway and continental Europe of levying a carbon dioxide tax on international bunker. The influence of such a tax on the operational costs of various types of ship and various transport routes is calculated. The profit obtainable from the following ways of adapting to an increased tax level is assessed: (1) Reducing the speed, (2) Rebuilding the engine to decrease fuel consumption, (3) Changing the design speed for new ships. It is found that a carbon dioxide tax of NOK 200 per tonne of CO2 will increase the transport costs by 3 - 15 percent. In the long run much of this may be transferred to the freight rates since so much of the sea transport are in segments in which the demand for the service is not sensitive to the prices. Even if the freight rates are not changed, a tax this size will not make it necessary to reduce the speed of the existing fleet. The income lost by taking fewer trips will exceed the costs saved in reducing the speed. However, the optimum design speed for new ships may be somewhat reduced (0.5 knots). Rebuilding engines to reduce the fuel consumption would pay off were it not for the fact that the remaining life of the present fleet is probably too short for this to be interesting

  13. Use of supercritical carbon dioxide extraction

    Energy Technology Data Exchange (ETDEWEB)

    Taniguchi, Masayuki (Niigata Univ., Faculty of Engineering, Niigata, (Japan))

    1989-09-25

    Supercritical fluid extraction is a novel diffusion and separation technique which exploits simultaneously the increase of vapor pressure and the difference of chemical affinities of fluids near the critical point. A solvent which is used as the supercritical fluid has the following features: the critical point exists in the position of relatively ease of handling, the solvent is applicable to the extraction of a physiological active substance of thermal instability. Carbon dioxide as the solvent is non-flammable, non-corrosive, non-toxic, cheap, and readily available of high purity. The results of studies on the use of supercritical carbon dioxide (SC-CO{sub 2}) as a solvent for natural products in the fermentation and food industries, were collected. SC-CO{sub 2} extraction are used in many fields, examples for the application are as follows: removal of organic solvents from antibiotics; extraction of vegetable oils contained in wheat germ oil, high quality mustard seeds, rice bran and so on; brewing of sake using rice and rice-koji; use as a non-aqueous medium for the synthesis of precursors of the Aspartame; and use in sterilization. 66 refs., 17 figs., 21 tabs.

  14. Efficient Water Management in Water Cooled Reactors

    International Nuclear Information System (INIS)

    number of the countries that have recently begun to consider the introduction of nuclear power are in water scarce regions, which would certainly limit the possibility for deployment of nuclear power plants, in turn hindering these countries' development and energy security. Thus, there is a large incentive to enhance efforts to introduce innovative water use, water management practices and related technologies. Water management for nuclear power plants is gaining interest in IAEA Member States as an issue of vital importance for the deployment of nuclear power. Recent experience has shown that some nuclear power plants are susceptible to prolonged drought conditions, forcing reactors to be shut down or power to be reduced to a minimal level. In some cases, environmental issues have resulted in regulations that limit the possibility for water withdrawal as well as water discharge. Regarding the most common design for cooling nuclear power plants, this has led to a complicated siting procedure for new plants and expensive retrofits for existing ones. The IAEA has already provided its Member States with reports and documents that address the issue. At the height of nuclear power expansion in the 1970s, the need for guidance in the area resulted in publications such as Thermal Discharges at Nuclear Power Stations - Their Management and Environmental Impact (Technical Reports Series No. 155) and Environmental Effects of Cooling Systems (Technical Reports Series No. 202). Today, amid the so-called nuclear renaissance, it is of vital importance to offer guidance to the Member States on the issues and possibilities that nuclear power water management brings. Management of water at nuclear power plants is an important subject during all phases of the construction, operation and maintenance of any nuclear power plant. Water management addresses the issue of securing water for condenser cooling during operation, for construction (during the flushing phase), and for inventory

  15. Gas cooled fast reactor research and development program

    International Nuclear Information System (INIS)

    The research and development work in the field of core thermal-hydraulics, steam generator research and development, experimental and analytical physics and carbide fuel development carried out 1978 for the Gas Cooled Fast Breeder Reactor at the Swiss Federal Institute for Reactor Research is described. (Auth.)

  16. Gas cooled fast reactor research and development program

    International Nuclear Information System (INIS)

    The research and development work in the field of core thermal-hydraulics, steam generator research and development, experimental and analytical physics and carbide fuel development carried out 1979 for the Gas Cooled Fast Breeder Reactor at the Swiss Federal Institute for Reactor Research is described. (Auth.)

  17. Gas cooled fast reactor research and development program

    International Nuclear Information System (INIS)

    The research and development work in the field of core thermal-hydraulics, experimental and analytical physics and carbide fuel development carried out 1978 for the Gas Cooled Fast Breeder Reactor at the Swiss Federal Institute for Reactor Research is described. (Auth.)

  18. Passive cooling in modern nuclear reactors

    International Nuclear Information System (INIS)

    This paper presents some recent experimental results performed with the aim of understanding the mechanism of passive cooling. The AP 600 passive containment cooling system is simulated by an electrically heated vertical pipe, which is cooled by a naturally induced air flow and by a water film descending under gravity. The results demonstrate that although the presence of the water film improved the heat transfer significantly, the mode of heat transfer was very dependent on the experimental parameters. Preheating the water improved both film stability and overall cooling performance

  19. The economics of sodium-cooled fast reactors

    International Nuclear Information System (INIS)

    Specific technical features of fast reactors make them more expensive than water-cooled reactors in terms of initial investment, an over cost of 30% is acknowledged in this study. Their consumption of natural uranium is negligible being fed on depleted uranium (except for the very first cycle when an important quantity of plutonium is necessary). In the context of the scarcity of natural uranium, fast reactors could provide a competitive KWh compared with PWR. The study shows that sodium-cooled fast reactor could be economically competitive somewhere in the second part of the 21. century. The development of fast reactors could be accelerated by other arguments than economic competitiveness, for instance some governments might value more the energy independence given by a fleet of fast reactors or by considerations linked to non-proliferation or to the burning of actinides. In addition the article details the worldwide resource in natural uranium. (A.C.)

  20. Materials science research for sodium cooled fast reactors

    Indian Academy of Sciences (India)

    Baldev Raj

    2009-06-01

    The paper gives an insight into basic as well as applied research being carried out at the Indira Gandhi Centre for Atomic Research for the development of advanced materials for sodium cooled fast reactors towards extending the life of reactors to nearly 100 years and the burnup of fuel to 2,00,000 MWd/t with an objective of providing fast reactor electricity at an affordable and competitive price.

  1. Analysis of the Microbial Community in an Acidic Hollow-Fiber Membrane Biofilm Reactor (Hf-MBfR Used for the Biological Conversion of Carbon Dioxide to Methane.

    Directory of Open Access Journals (Sweden)

    Hyun Chul Shin

    Full Text Available Hydrogenotrophic methanogens can use gaseous substrates, such as H2 and CO2, in CH4 production. H2 gas is used to reduce CO2. We have successfully operated a hollow-fiber membrane biofilm reactor (Hf-MBfR for stable and continuous CH4 production from CO2 and H2. CO2 and H2 were diffused into the culture medium through the membrane without bubble formation in the Hf-MBfR, which was operated at pH 4.5-5.5 over 70 days. Focusing on the presence of hydrogenotrophic methanogens, we analyzed the structure of the microbial community in the reactor. Denaturing gradient gel electrophoresis (DGGE was conducted with bacterial and archaeal 16S rDNA primers. Real-time qPCR was used to track changes in the community composition of methanogens over the course of operation. Finally, the microbial community and its diversity at the time of maximum CH4 production were analyzed by pyrosequencing methods. Genus Methanobacterium, related to hydrogenotrophic methanogens, dominated the microbial community, but acetate consumption by bacteria, such as unclassified Clostridium sp., restricted the development of acetoclastic methanogens in the acidic CH4 production process. The results show that acidic operation of a CH4 production reactor without any pH adjustment inhibited acetogenic growth and enriched the hydrogenotrophic methanogens, decreasing the growth of acetoclastic methanogens.

  2. Disintegration of Carbon Dioxide Molecules in a Microwave Plasma Torch

    Science.gov (United States)

    Kwak, Hyoung S.; Uhm, Han S.; Hong, Yong C.; Choi, Eun H.

    2015-12-01

    A pure carbon dioxide torch is generated by making use of 2.45 GHz microwave. Carbon dioxide gas becomes the working gas and produces a stable carbon dioxide torch. The torch volume is almost linearly proportional to the microwave power. Temperature of the torch flame is measured by making use of optical spectroscopy and thermocouple. Two distinctive regions are exhibited, a bright, whitish region of high-temperature zone and a bluish, dimmer region of relatively low-temperature zone. Study of carbon dioxide disintegration and gas temperature effects on the molecular fraction characteristics in the carbon dioxide plasma of a microwave plasma torch under atmospheric pressure is carried out. An analytical investigation of carbon dioxide disintegration indicates that substantial fraction of carbon dioxide molecules disintegrate and form other compounds in the torch. For example, the normalized particle densities at center of plasma are given by nCO2/nN = 6.12 × 10-3, nCO/nN = 0.13, nC/nN = 0.24, nO/nN = 0.61, nC2/nN = 8.32 × 10-7, nO2/nN = 5.39 × 10-5, where nCO2, nCO, nC, nO, nC2, and nO2 are carbon dioxide, carbon monoxide, carbon and oxygen atom, carbon and oxygen molecule densities, respectively. nN is the neutral particle density. Emission profiles of the oxygen and carbon atom radicals and the carbon monoxide molecules confirm the theoretical predictions of carbon dioxide disintegration in the torch.

  3. Porous Carbon Based Solid Adsorbents for Carbon Dioxide Capture

    OpenAIRE

    Travis, W.

    2015-01-01

    The aim of this project is the design, synthesis and characterisation of porous carbon structures capable of the selective capture of carbon dioxide (CO2) from the exhaust gases of coal and gas post-combustion power stations. In such systems, the fossil fuel is burnt in an air environment producing CO2 as just one of a multi-component flue gas. This flue gas is expected to contain nitrogen and water among other constituents. It is at ambient pressures and temperatures of ≥323 K. Successful ca...

  4. Activation of Carbon Dioxide and Synthesis of Propylene Carbonate

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Cycloaddition of carbon dioxide and propylene oxide to propylene carbonate catalyzed by tetra-tert-butyl metal phthalocyanine in the presence of tributylamine (TBA) shows higher yield than catalyzed by unsubstituted metal phthalocyanine. Comparing different catalysts of diverse metals, (t-Bu)4PcMg is more active than (t-Bu)4PcFe. But (t-Bu)4PcCo and (t-Bu)4PcNi only have low catalytic activities towards the reaction. Moreover, the yield will increase as the temperature increases.

  5. Remediation of Contaminated Soils By Supercritical Carbon Dioxide Extraction

    Science.gov (United States)

    Ferri, A.; Zanetti, M. C.; Banchero, M.; Fiore, S.; Manna, L.

    superficial velocity of the supercritical carbon dioxide; therefore, the mass transfer resistance can be reduced increasing such velocity. In this work, higher values of superficial velocity were investigated. The experimental apparatus includes a pump, an extraction vessel, an adjustable restrictor and a trap to collect the extracted substance. Liquid carbon dioxide coming from a cylinder with a dip-tube is cooled by a cryostatic bath and then it is compressed by a pneumatic drive pump (the max- imum available pressure is 69 MPa). Subsequently, the pressurised current flows into 1 a heating coil and then into the extraction vessel, which is contained in a stove; the outlet flow is depressurised in an adjustable restrictor and the extracted substance is collected in a trap by dissolution into a solvent. The extracted naphthalene quantity was obtained by weighting the solvent and measuring the naphthalene concentration with a gas chromatograph. The soil sample is a sandy soil geologically representative of the North of Italy that was sampled and physically and chemically characterized: particle-size distribution analysis, diffractometric analysis, Cation Exchange Capac- ity, Total Organic Carbon, iron content and manganese content in order to evaluate the potential sorption degree. The soil was artificially polluted by means of a naphta- lene and methylene chloride solution. The experimental work consists in a number of naphthalene extractions from the spiked soil, that were carried out at different operat- ing conditions, temperature, pressure and flow rate by means of supercritical carbon dioxide evaluating the corresponding recovery efficiencies. The results obtained were analysed and compared in order to determine which parameters influence the system. [1] G. A. Montero, T.D. Giorgio, and K. B. Schnelle, Jr..Removal of Hazardous ,1994, Contaminants form Soils by Supercritical Fluid Extraction. Innovations in Supercriti- cal Fluids. ACS Symposium Series, 608, 280-197. 2

  6. An Analysis of Methanol and Hydrogen Production via High-Temperature Electrolysis Using the Sodium Cooled Advanced Fast Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Shannon M. Bragg-Sitton; Richard D. Boardman; Robert S. Cherry; Wesley R. Deason; Michael G. McKellar

    2014-03-01

    Integration of an advanced, sodium-cooled fast spectrum reactor into nuclear hybrid energy system (NHES) architectures is the focus of the present study. A techno-economic evaluation of several conceptual system designs was performed for the integration of a sodium-cooled Advanced Fast Reactor (AFR) with the electric grid in conjunction with wind-generated electricity. Cases in which excess thermal and electrical energy would be reapportioned within an integrated energy system to a chemical plant are presented. The process applications evaluated include hydrogen production via high temperature steam electrolysis and methanol production via steam methane reforming to produce carbon monoxide and hydrogen which feed a methanol synthesis reactor. Three power cycles were considered for integration with the AFR, including subcritical and supercritical Rankine cycles and a modified supercritical carbon dioxide modified Brayton cycle. The thermal efficiencies of all of the modeled power conversions units were greater than 40%. A thermal efficiency of 42% was adopted in economic studies because two of the cycles either performed at that level or could potentially do so (subcritical Rankine and S-CO2 Brayton). Each of the evaluated hybrid architectures would be technically feasible but would demonstrate a different internal rate of return (IRR) as a function of multiple parameters; all evaluated configurations showed a positive IRR. As expected, integration of an AFR with a chemical plant increases the IRR when “must-take” wind-generated electricity is added to the energy system. Additional dynamic system analyses are recommended to draw detailed conclusions on the feasibility and economic benefits associated with AFR-hybrid energy system operation.

  7. Carbon Dioxide, a Solvent and Synthon for Green Chemistry

    OpenAIRE

    Ballivet-Tkatchenko, D.; Camy, Séverine; Condoret, Jean-Stéphane

    2005-01-01

    Carbon dioxide is a renewable resource of carbon when we consider the reuse of existing CO2 as a carbon source for producing chemicals. The development of new applications is of major interest from the point of view of carbon dioxide sequestration and within the scope of green chemistry. For example, using CO2 instead of CO or COCl2 for chemical synthesis constitutes an attractive alternative avoiding hazardous and toxic reactants. However, it has the lowest chemical reactivity, which i...

  8. Carbon Dioxide and Global Warming: A Failed Experiment

    Science.gov (United States)

    Ribeiro, Carla

    2014-01-01

    Global warming is a current environmental issue that has been linked to an increase in anthropogenic carbon dioxide in the atmosphere. To raise awareness of the problem, various simple experiments have been proposed to demonstrate the effect of carbon dioxide on the planet's temperature. This article describes a similar experiment, which…

  9. Carbon dioxide emission during forest fires ignited by lightning

    OpenAIRE

    Pelc, Magdalena; Osuch, Radoslaw

    2009-01-01

    In this paper we developed the model for the carbon dioxide emission from forest fire. The master equation for the spreading of the carbon dioxide to atmosphere is the hyperbolic diffusion equation. In the paper we study forest fire ignited by lightning. In that case the fores fire has the well defined front which propagates with finite velocity.

  10. Interglacials, Milankovitch Cycles, Solar Activity, and Carbon Dioxide

    OpenAIRE

    Marsh, Gerald E.

    2014-01-01

    The existing understanding of interglacial periods is that they are initiated by Milankovitch cycles enhanced by rising atmospheric carbon dioxide concentrations. During interglacials, global temperature is also believed to be primarily controlled by carbon dioxide concentrations, modulated by internal processes such as the Pacific Decadal Oscillation and the North Atlantic Oscillation. Recent work challenges the fundamental basis of these conceptions.

  11. Investigating Diffusion and Entropy with Carbon Dioxide-Filled Balloons

    Science.gov (United States)

    Jadrich, James; Bruxvoort, Crystal

    2010-01-01

    Fill an ordinary latex balloon with helium gas and you know what to expect. Over the next day or two the volume will decrease noticeably as helium escapes from the balloon. So what happens when a latex balloon is filled with carbon dioxide gas? Surprisingly, carbon dioxide balloons deflate at rates as much as an order of magnitude faster than…

  12. Carbon dioxide capture processes: Simulation, design and sensitivity analysis

    DEFF Research Database (Denmark)

    Zaman, Muhammad; Lee, Jay Hyung; Gani, Rafiqul

    Carbon dioxide is the main greenhouse gas and its major source is combustion of fossil fuels for power generation. The objective of this study is to carry out the steady-state sensitivity analysis for chemical absorption of carbon dioxide capture from flue gas using monoethanolamine solvent. First...

  13. Flexible substrates as basis for photocatalytic reduction of carbon dioxide

    DEFF Research Database (Denmark)

    Jensen, Jacob; Mikkelsen, Mette; Krebs, Frederik C

    2011-01-01

    A photocatalytic system for converting carbon dioxide into carbon monoxide was designed and constructed. The system relies on thin films of the photocatalyst prepared at low temperature using spray coating. We formulated inks based on the well-known photocatalyst titanium dioxide and characterized...

  14. Balance and forecasts of french carbon dioxide emissions

    International Nuclear Information System (INIS)

    This paper strikes the balance of carbon dioxide emissions in France between 1986 and 1991 and gives forecasts till 2010. Since 1986, France has reduced its efforts for energy conservation and air pollution by carbon dioxide begins to growth again in connection with consumption growth in transport area, development of computer and simulation needs

  15. Carbon dioxide capture processes: Simulation, design and sensitivity analysis

    DEFF Research Database (Denmark)

    Zaman, Muhammad; Lee, Jay Hyung; Gani, Rafiqul

    2012-01-01

    Carbon dioxide is the main greenhouse gas and its major source is combustion of fossil fuels for power generation. The objective of this study is to carry out the steady-state sensitivity analysis for chemical absorption of carbon dioxide capture from flue gas using monoethanolamine solvent. First...

  16. International working group on gas-cooled reactors. Summary report

    Energy Technology Data Exchange (ETDEWEB)

    1981-01-15

    The purpose of the meeting was to provide a forum for exchange of information on safety and licensing aspects for gas-cooled reactors in order to provide comprehensive review of the present status and of directions for future applications and development. Contributions were made concerning the operating experience of the Fort St. Vrain (FSV) HTGR Power Plant in the United States of America, the experimental power station Arbeitsgemeinschaft Versuchsreaktor (AVR) in the Federal Republic of Germany, and the CO/sub 2/-cooled reactors in the United Kingdom such as Hunterson B and Hinkley Point B. The experience gained at each of these reactors has proved the high safety potential of Gas-cooled Reactor Power Plants.

  17. 75 FR 29534 - Inorganic Nitrates-Nitrite, Carbon and Carbon Dioxide, and Sulfur Registration Review; Draft...

    Science.gov (United States)

    2010-05-26

    ... AGENCY Inorganic Nitrates-Nitrite, Carbon and Carbon Dioxide, and Sulfur Registration Review; Draft... draft ecological risk assessment for the registration review of inorganic nitrates - nitrites, carbon... occur for all inorganic nitrates- nitrites, carbon and carbon dioxide uses, as well as gas...

  18. Pin-Type Gas Cooled Reactor for Nuclear Electric Propulsion

    Science.gov (United States)

    Wright, Steven A.; Lipinski, Ronald J.

    2003-01-01

    This paper describes a point design for a pin-type Gas-Cooled Reactor concept that uses a fuel pin design similar to the SP100 fuel pin. The Gas-Cooled Reactor is designed to operate at 100 kWe for 7 years plus have a reduced power mode of 20% power for a duration of 5 years. The power system uses a gas-cooled, UN-fueled, pin-type reactor to heat He/Xe gas that flows directly into a recuperated Brayton system to produce electricity. Heat is rejected to space via a thermal radiator that unfolds in space. The reactor contains approximately 154 kg of 93.15 % enriched UN in 313 fuel pins. The fuel is clad with rhenium-lined Nb-1Zr. The pressures vessel and ducting are cooled by the 900 K He/Xe gas inlet flow or by thermal radiation. This permits all pressure boundaries to be made of superalloy metals rather than refractory metals, which greatly reduces the cost and development schedule required by the project. The reactor contains sufficient rhenium (a neutron poison) to make the reactor subcritical under water immersion accidents without the use of internal shutdown rods. The mass of the reactor and reflectors is about 750 kg.

  19. New technology for carbon dioxide at high pressure

    International Nuclear Information System (INIS)

    Carbon dioxide has long been the nemesis of environmentalists because of its role in global warming, but under just the right conditions-namely, high pressure and high temperature its one of nature's best and most environmentally benign solvents. Decaf-coffee lovers, for instance, benefit from its ability to remove caffeine from coffee beans.During the last few years, carbon dioxide has also made inroads in the dry-cleaning industry, providing a safe cleaning alternative to the chemical perchloroethylene. But it's on the high-tech front that carbon dioxide may make its biggest impact. There are huge opportunities. Scientists have known for more than a century that at 75 times atmospheric pressure and 31 degree centigrade, carbon dioxide goes into and odd state that chemists called supercritical. What's interesting to industry is that supercritical carbon dioxide may be an enabling technology for going to smaller dimensions.(Author)

  20. Adverse effects of the automotive industry on carbon dioxide emissions

    Directory of Open Access Journals (Sweden)

    Mpho Bosupeng

    2016-05-01

    Full Text Available This study aims to determine the effects of the automotive industry on carbon dioxide emissions for the period from 1997 to 2010 for diverse economies, as well as the relationships between carbon dioxide discharges and output. The study applies cointegration and causality tests to validate these associations. The results of the Johansen cointegration test depict long-run associations between the quantity of passenger cars and carbon dioxide emissions in France, Sweden, Spain, Hungary and Japan. In addition, significant relations were observed between output and carbon dioxide discharges in Spain, Canada, India and Japan. Changes in output had substantial impact on emissions in Germany, Canada and India. The results also show that the number of passenger cars influences the magnitude of emissions in multiple economies. In conclusion, the automotive industry has to be considered in policies that aim to reduce carbon dioxide emissions.

  1. Safety analysis of reactor's cooling system

    International Nuclear Information System (INIS)

    Results of the analysis of reactor's RBMK-1500 coolant system during normal operation mode, hydrodynamic testing and in the case of earthquake are presented. Analysis was performed using RELAP5 code. Calculations showed the most vulnerable place in the reactor's coolant system. It was found that in the case of earthquake the horizontal support system of drum separator could be damaged

  2. Photobiological hydrogen production and carbon dioxide sequestration

    Science.gov (United States)

    Berberoglu, Halil

    Photobiological hydrogen production is an alternative to thermochemical and electrolytic technologies with the advantage of carbon dioxide sequestration. However, it suffers from low solar to hydrogen energy conversion efficiency due to limited light transfer, mass transfer, and nutrient medium composition. The present study aims at addressing these limitations and can be divided in three parts: (1) experimental measurements of the radiation characteristics of hydrogen producing and carbon dioxide consuming microorganisms, (2) solar radiation transfer modeling and simulation in photobioreactors, and (3) parametric experiments of photobiological hydrogen production and carbon dioxide sequestration. First, solar radiation transfer in photobioreactors containing microorganisms and bubbles was modeled using the radiative transport equation (RTE) and solved using the modified method of characteristics. The study concluded that Beer-Lambert's law gives inaccurate results and anisotropic scattering must be accounted for to predict the local irradiance inside a photobioreactor. The need for accurate measurement of the complete set of radiation characteristics of microorganisms was established. Then, experimental setup and analysis methods for measuring the complete set of radiation characteristics of microorganisms have been developed and successfully validated experimentally. A database of the radiation characteristics of representative microorganisms have been created including the cyanobacteria Anabaena variabilis, the purple non-sulfur bacteria Rhodobacter sphaeroides and the green algae Chlamydomonas reinhardtii along with its three genetically engineered strains. This enabled, for the first time, quantitative assessment of the effect of genetic engineering on the radiation characteristics of microorganisms. In addition, a parametric experimental study has been performed to model the growth, CO2 consumption, and H 2 production of Anabaena variabilis as functions of

  3. Degradation of graphite in gas cooled reactors due to radiolytic oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Moskovic, R., E-mail: robert.moskovic@magnoxnorthsites.com

    2014-04-01

    Magnox reactors employ pile grade A (PGA) graphite as a moderator. Reactor cores are constructed typically of twelve to thirteen layers of graphite bricks. Fuel channels (FC) are in the centre of all bricks and interstitial channels (IC) at the centre of the corners of every second set of four bricks. The reactor core is cooled by carbon dioxide, the temperature of graphite core increases from 250 °C at the bottom to 360 °C at the top of the core. The neutron dose increases progressively with the operating time of the reactor. The graphite core looses mass as a result of radiolytic oxidation. The process is dependent on both total energy deposition and temperature which correlates with core height. Fast neutron dose accumulates at the same rate as the total energy deposited and is readily available. The reduction of density of moderator graphite increases the porosity and in turn changes both the physical and mechanical properties of graphite. The mechanical properties and density of graphite are measured either on samples installed in the reactor prior to service or trepanned from graphite bricks. The data obtained on these samples are interrogated using probability modelling to establish trends with increasing service life. Results of the analyses are illustrated in the paper. PGA graphite is an aggregate of coarse needle coke filler particles within a matrix of fine coke flour particles mixed with pitch binder. The bricks are fabricated in the green condition by extrusion of dry calcinated coke impregnated with liquid pitch binder and then graphitized at 2800 °C. This produces a polygranular aggregate with orthotropic properties. The strength properties of graphite are measured using different types of tests. The most commonly used tests involve bending, uniaxial and diametral compression. The initiation and propagation of cracks was investigated to improve understanding of strength behaviour. Cracking was examined on macro-scale using optical microscopy and

  4. Ruthenium-catalysed alkoxycarbonylation of alkenes with carbon dioxide.

    Science.gov (United States)

    Wu, Lipeng; Liu, Qiang; Fleischer, Ivana; Jackstell, Ralf; Beller, Matthias

    2014-01-01

    Alkene carbonylations represent a major technology for the production of value-added bulk and fine chemicals. Nowadays, all industrial carbonylation processes make use of highly toxic and flammable carbon monoxide. Here we show the application of abundantly available carbon dioxide as C1 building block for the alkoxycarbonylations of industrially important olefins in the presence of a convenient and inexpensive ruthenium catalyst system. In our system, carbon dioxide works much better than the traditional combination of carbon monoxide and alcohols. The unprecedented in situ formation of carbon monoxide from carbon dioxide and alcohols permits an efficient synthesis of carboxylic acid esters, which can be used as detergents and polymer-building blocks. Notably, this transformation allows the catalytic formation of C-C bonds with carbon dioxide as C1 source and avoids the use of sensitive and/or expensive reducing agents (for example, Grignard reagents, diethylzinc or triethylaluminum). PMID:24518431

  5. Packed-Bed Reactor Study of NETL Sample 196c for the Removal of Carbon Dioxide from Simulated Flue Gas Mixture

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, James S.; Hammache, Sonia; Gray, McMahan L.; Fauth Daniel J.; Pennline, Henry W.

    2012-04-24

    An amine-based solid sorbent process to remove CO2 from flue gas has been investigated. The sorbent consists of polyethylenimine (PEI) immobilized onto silica (SiO2) support. Experiments were conducted in a packed-bed reactor and exit gas composition was monitored using mass spectrometry. The effects of feed gas composition (CO2 and H2O), temperature, and simulated steam regeneration were examined for both the silica support as well as the PEI-based sorbent. The artifact of the empty reactor was also quantified. Sorbent CO2 capacity loading was compared to thermogravimetric (TGA) results to further characterize adsorption isotherms and better define CO2 working capacity. Sorbent stability was monitored by periodically repeating baseline conditions throughout the parametric testing and replacing with fresh sorbent as needed. The concept of the Basic Immobilized Amine Sorbent (BIAS) Process using this sorbent within a system where sorbent continuously flows between the absorber and regenerator was introduced. The basic tenet is to manipulate or control the level of moisture on the sorbent as it travels around the sorbent circulation path between absorption and regeneration stages to minimize its effect on regeneration heat duty.

  6. Carbon dioxide removal from coal-fired power plants

    International Nuclear Information System (INIS)

    To diminish the threat of a rapidly changing climate, emissions of CO2 should be reduced. One way to reduce these emissions is CO2 removal -the recovery of carbon dioxide from energy conversion processes and storage outside the atmosphere. This book gives an extensive description of three methods of capturing CO2 from flue gases of a conventional coal-fired power plant using amines, polymer membranes; and low temperature distillation, and two methods that are based on the modification of an integrated coal gasifier combined cycle plant, one using a shift reactor and a scrubber, the other using membrane separation and a CO2 gas turbine. The present state of the technology is described and optimized recovery designs are presented. Energy use is calculated in detail and elaborate cost calculations are given. In the last chapter, global storage potentials and costs of CO2 in aquifers, empty natural gas, and oil fields, are discussed. 170 refs

  7. Gas-Cooled Reactors: the importance of their development

    International Nuclear Information System (INIS)

    Gas-Cooled Reactors are considered to have a significant future impact on the application of fission energy. The specific types are the steam-cycle High-Temperature Gas-Cooled Reactor, the Gas-Cooled Fast Breeder Reactor, the gas-turbine HTGR, and the Very High-Temperature Process Heat Reactor. The importance of developing the above systems is discussed relative to alternative fission power systems involving Light Water Reactors, Heavy Water Reactors, Spectral Shift Controlled Reactors, and Liquid-Metal-Cooled Fast Breeder Reactors. A primary advantage of developing GCRs as a class lies in the technology and cost interrelations, permitting cost-effective development of systems having diverse applications. Further, HTGR-type systems have highly proliferation-resistant characteristics and very attractive safety features. Finally, such systems and GCFRs are mutally complementary. Overall, GCRs provide interrelated systems that serve different purposes and needs; their development can proceed in stages that provide early benefits while contributing to future needs. It is concluded that the long-term importance of the various GCRs is as follows: HTGR, providing a technology for economic GCFRs and HTGR-GTs, while providing a proliferation-resistant reactor system having early economic and fuel utilization benefits; GCFR, providing relatively low cost fissile fuel and reducing overall separative work needs at capital costs lower than those for LMFBRs; HTGR-GT (in combination with a bottoming cycle), providing a very high thermal efficiency system having low capital costs and improved fuel utilization and technology pertinent to VHTRs; HTGR-GT, providing a power system well suited for dry cooling conditions for low-temperature process heat needs; and VHTR, providing a high-temperature heat source for hydrogen production processes

  8. Filter for reactor emergency cooling system

    International Nuclear Information System (INIS)

    The invention describes the design of a filter for the emergency cooling system. The new type of filter can be rinsed by flushing water backwards through the filter. The arrangement will prevent the filter from being silt up

  9. Modeling and performance of the MHTGR [Modular High-Temperature Gas-Cooled Reactor] reactor cavity cooling system

    International Nuclear Information System (INIS)

    The Reactor Cavity Cooling System (RCCS) of the Modular High- Temperature Gas-Cooled Reactor (MHTGR) proposed by the U.S. Department of Energy is designed to remove the nuclear afterheat passively in the event that neither the heat transport system nor the shutdown cooling circulator subsystem is available. A computer dynamic simulation for the physical and mathematical modeling of and RCCS is described here. Two conclusions can be made form computations performed under the assumption of a uniform reactor vessel temperature. First, the heat transferred across the annulus from the reactor vessel and then to ambient conditions is very dependent on the surface emissivities of the reactor vessel and RCCS panels. These emissivities should be periodically checked to ensure the safety function of the RCCS. Second, the heat transfer from the reactor vessel is reduced by a maximum of 10% by the presence of steam at 1 atm in the reactor cavity annulus for an assumed constant in the transmission of radiant energy across the annulus can be expected to result in an increase in the reactor vessel temperature for the MHTGR. Further investigation of participating radiation media, including small particles, in the reactor cavity annulus is warranted. 26 refs., 7 figs., 1 tab

  10. Study of redox reactions to split water and carbon dioxide

    Science.gov (United States)

    Arifin, Darwin

    The development of carbon-neutral, environmentally-sustainable energy carrier is a technological imperative necessary to mitigate the impact of anthropogenic carbon dioxide on earth's climate. One compelling approach rapidly gaining international attention is the conversion of solar energy into renewable fuels, such as H2 or CO, via a two-step thermochemical cycle driven by concentrated solar power. In accordance with the increased interest in this process, there is a need to better understand the gas splitting chemistry on the metal oxide intermediates encountered in such solar-driven processes. Here we measured the H2 and CO production rates during oxidation by H2O and CO2 in a stagnation flow reactor. Redox cycles were performed over various metal oxide chemistries such as hercynite and ceria based materials that are thermally reduced by laser irradiation. In addition to cycle capacity evaluation, reaction kinetics intrinsic to the materials were extracted using a model-based analytical approach to account for the effects of mixing and dispersion in the reactor. Investigation of the "hercynite chemistry" with raman spectroscopy verifies that, at the surface, the cycle proceeds by stabilizing the reduced and oxidized moieties in two different compounds, which allows the thermal reduction reaction to occur to a greater extent at a temperature 150 °C lower than a similarly prepared CoFe2O4-coated m-ZrO2. Investigation of the ceria cycle shows that the water splitting reaction, in the range of 750 - 950 °C and 20 - 40 vol.% H2O, can best be described by a first-order kinetic model with low apparent activation energy (29 kJ/mol). The carbon dioxide splitting reaction, in the range of 650 - 875 °C and 10 - 40 vol.% CO2, is a more complex surface-mediated phenomena that is controlled by a temperature-dependent surface site blocking mechanism involving adsorbed carbon. Moreover, we find that lattice substitution of ceria with zirconium can increase H2 production by

  11. Carbon dioxide problems. Countermeasures to the carbon dioxide problem in hydrocarbon-fired plants

    International Nuclear Information System (INIS)

    Among the environmental problems discussed in this paper, global warming and the restriction of CFC are primarily thermal engineering issues. In particular, global warming, likely to be caused by an increase in the atmospheric carbon dioxide concentration, is one of the most essential and urgent environmental problems. In recent international conferences, held for example by UNEP, a proposal was made that carbon dioxide concentration be controlled under its 1898 level. However, this proposal may not be so forceful, since it is not clear whether the control is to be imposed on each country separately or on the developed countries as a whole. The vague content of the proposal may be attributed to the existing international situation, whereby the energy resources available to each country differ substantially

  12. Carbon dioxide emission from bamboo culms.

    Science.gov (United States)

    Zachariah, E J; Sabulal, B; Nair, D N K; Johnson, A J; Kumar, C S P

    2016-05-01

    Bamboos are one of the fastest growing plants on Earth, and are widely considered to have high ability to capture and sequester atmospheric carbon, and consequently to mitigate climate change. We tested this hypothesis by measuring carbon dioxide (CO2 ) emissions from bamboo culms and comparing them with their biomass sequestration potential. We analysed diurnal effluxes from Bambusa vulgaris culm surface and gas mixtures inside hollow sections of various bamboos using gas chromatography. Corresponding variations in gas pressure inside the bamboo section and culm surface temperature were measured. SEM micrographs of rhizome and bud portions of bamboo culms were also recorded. We found very high CO2 effluxes from culm surface, nodes and buds of bamboos. Positive gas pressure and very high concentrations of CO2 were observed inside hollow sections of bamboos. The CO2 effluxes observed from bamboos were very high compared to their carbon sequestration potential. Our measurements suggest that bamboos are net emitters of CO2 during their lifespan. PMID:26802362

  13. Global carbon dioxide emissions from inland waters

    Science.gov (United States)

    Raymond, Peter A.; Hartmann, Jens; Lauerwald, Ronny; Sobek, Sebastian; McDonald, Cory P.; Hoover, Mark; Butman, David; Striegl, Rob; Mayorga, Emilio; Humborg, Christoph; Kortelainen, Pirkko; Durr, Hans H.; Meybeck, Michel; Ciais, Philippe; Guth, Peter

    2013-01-01

    Carbon dioxide (CO2) transfer from inland waters to the atmosphere, known as CO2 evasion, is a component of the global carbon cycle. Global estimates of CO2 evasion have been hampered, however, by the lack of a framework for estimating the inland water surface area and gas transfer velocity and by the absence of a global CO2 database. Here we report regional variations in global inland water surface area, dissolved CO2 and gas transfer velocity. We obtain global CO2 evasion rates of 1.8   petagrams of carbon (Pg C) per year from streams and rivers and 0.32  Pg C yr−1 from lakes and reservoirs, where the upper and lower limits are respectively the 5th and 95th confidence interval percentiles. The resulting global evasion rate of 2.1 Pg C yr−1 is higher than previous estimates owing to a larger stream and river evasion rate. Our analysis predicts global hotspots in stream and river evasion, with about 70 per cent of the flux occurring over just 20 per cent of the land surface. The source of inland water CO2 is still not known with certainty and new studies are needed to research the mechanisms controlling CO2 evasion globally.

  14. Miniaturized remission sensor for carbon dioxide detection

    International Nuclear Information System (INIS)

    Recently, optical sensors for detection of carbon dioxide (CO2) have been explored for variety of applications in chemistry, industry, and medicine. This paper deals with the development of a planar optical remission sensor employing a dye immobilized in a polymer layer designed for gaseous CO2 detection. The principle of CO2 detection was based on colour changes of Tetraethylammonium Cresol red immobilized in a special composed polymer layer that was irradiated by LED diodes. Absorption properties of the dye were changed due to its chemical reaction with CO2 and corresponding colour changes were detected by PIN diodes. These changes were analyzed by using a PC-controlled board connected by USB. The sensitivity, response time, and the detection limit of the remission sensor were characterized.

  15. Carbon dioxide neutral, integrated biofuel facility

    Energy Technology Data Exchange (ETDEWEB)

    Powell, E.E.; Hill, G.A. [Department of Chemical Engineering, University of Saskatchewan, 57 Campus Drive, Saskatoon, Saskatchewan, S7N 5A9 (Canada)

    2010-12-15

    Algae are efficient biocatalysts for both capture and conversion of carbon dioxide in the environment. In earlier work, we have optimized the ability of Chlorella vulgaris to rapidly capture CO{sub 2} from man-made emission sources by varying environmental growth conditions and bioreactor design. Here we demonstrate that a coupled biodiesel-bioethanol facility, using yeast to produce ethanol and photosynthetic algae to produce biodiesel, can result in an integrated, economical, large-scale process for biofuel production. Each bioreactor acts as an electrode for a coupled complete microbial fuel cell system; the integrated cultures produce electricity that is consumed as an energy source within the process. Finally, both the produced yeast and spent algae biomass can be used as added value byproducts in the feed or food industries. Using cost and revenue estimations, an IRR of up to 25% is calculated using a 5 year project lifespan. (author)

  16. Carbon dioxide (CO2) angiography in children

    International Nuclear Information System (INIS)

    Background. When iodinated contrast material is contraindicated, carbon dioxide (CO2) gas can be injected intravascularly to produce high-quality digital subtraction angiograms. Objective. CO2 angiography, although previously described in adults, has never before been reported in children. Materials and methods. We present three children with renal transplants who required renal angiography. Because of elevated creatinine levels, iodinated contrast was not used to search for possible renal artery stenosis. Instead, CO2 angiography was used to evaluate the renal artery anastomosis. Results. In all three cases, the renal artery anastomosis was clearly visualized using CO2 angiography and showed no evidence of renal artery stenosis. Conclusion. Digital CO2 angiography is an effective method for pediatric renal angiography. The technique can easily be adapted for virtually any angiographic laboratory capable of digital subtraction imaging. Digital CO2 angiography also lacks the risks of a conventional iodinated contrast medium, namely nephrotoxicity, allergic reaction and volume overload. (orig.). With 1 fig

  17. Carbon dioxide removal with inorganic membranes

    Energy Technology Data Exchange (ETDEWEB)

    Judkins, R.R.; Fain, D.E. [Oak Ridge National Laboratory, TN (United States)

    1993-12-31

    The increasing concentrations of greenhouse gases, particularly carbon dioxide, in the atmosphere has sparked a great deal of interest in the removal of CO{sub 2} from flue gases of fossil fueled plants. Presently, several techniques for the removal of CO{sub 2} are considered to have potential, but are lacking in practicality. For example, amine scrubbing of flue gas streams is potential, but are lacking in practically. For example, amine scrubbing of flue gas streams is effective in removing CO{sub 2}, but costs are high; efficiency suffers; and other acid gases must be removed prior to amine stripping. Membrane systems for CO{sub 2} removal are held in high regard, and inorganic, particularly ceramic, membranes offer the potential for high temperature, thus energy saving, removal.

  18. The Fluid Mechanics of Carbon Dioxide Sequestration

    Science.gov (United States)

    Huppert, Herbert E.; Neufeld, Jerome A.

    2014-01-01

    Humans are faced with a potentially disastrous global problem owing to the current emission of 32 gigatonnes of carbon dioxide (CO2) annually into the atmosphere. A possible way to mitigate the effects is to store CO2 in large porous reservoirs within the Earth. Fluid mechanics plays a key role in determining both the feasibility and risks involved in this geological sequestration. We review current research efforts looking at the propagation of CO2 within the subsurface, the possible rates of leakage, the mechanisms that act to stably trap CO2, and the geomechanical response of the crust to large-scale CO2 injection. We conclude with an outline for future research.

  19. Biochemical Capture and Removal of Carbon Dioxide

    Science.gov (United States)

    Trachtenberg, Michael C.

    1998-01-01

    We devised an enzyme-based facilitated transport membrane bioreactor system to selectively remove carbon dioxide (CO2) from the space station environment. We developed and expressed site-directed enzyme mutants for CO2 capture. Enzyme kinetics showed the mutants to be almost identical to the wild type save at higher pH. Both native enzyme and mutant enzymes were immobilized to different supports including nylons, glasses, sepharose, methacrylate, titanium and nickel. Mutant enzyme could be attached and removed from metal ligand supports and the supports reused at least five times. Membrane systems were constructed to test CO2 selectivity. These included proteic membranes, thin liquid films and enzyme-immobilized teflon membranes. Selectivity ratios of more than 200:1 were obtained for CO2 versus oxygen with CO2 at 0.1%. The data indicate that a membrane based bioreactor can be constructed which could bring CO2 levels close to Earth.

  20. Thermodynamical effects during carbon dioxide release

    Science.gov (United States)

    Singh, A. K.; Böttcher, N.; Görke, U.-J.; Kolditz, O.

    2012-04-01

    Pruess [1] investigated the risk of carbon dioxide leakage from shallow storage sites by modeling scenarios. Such a fluid release is associated with mechanical work performed by formation fluid against expansion without taking heat from ambient environment. Understanding of heat related to mechanical work is essential to predict the temperature at the leak. According to the first law of thermodynamics, internal energy of working fluid decreases with an amount which is equivalent to this work hence, working fluid lost its own heat. Such kind of heat loss depends strongly on whether the expansion process is adiabatic or isothermal. Isothermal expansion allows the working fluid to interact thermally with the solid matrix. Adiabatic expansion is an isenthalpic process that takes heat from the working fluid and the ambient environment remains unchanged. This work is part of the CLEAN research project [6]. In this study, thermodynamic effects of mechanical work during eventual carbon dioxide leakage are investigated numerically. In particular, we are interested to detect the temperature at leakage scenarios and its deviation with different thermodynamic processes. Finite element simulation is conducted with a two-dimensional rectangular geometry representing a shallow storage site which bottom was located at -300m below the land surface. A fully saturated porous medium is assumed where the pore space is filled completely with carbon dioxide. Carbon dioxide accumulated in the secondary trap at 30 Bar and 24 °C is allowed to leak from top right point of rectangle with atmospheric pressure. With (i) adiabatic and (ii) isothermal compressibility factors, temperature around leakage area has been calculated which show a significant difference. With some simplification, this study detects leak temperature which is very close with [1]. Temporal evaluation at the leaky area shows that the working fluid temperature can be reduced to -20 °C when the leakage scenario is performed

  1. Carbon dioxide and the radiation budget

    International Nuclear Information System (INIS)

    This chapter addresses the radiative forcing of the Earth-atmosphere system caused by an increase in carbon dioxide (CO2) levels that can lead to climate change. The importance of the Earth's radiation budget is described, and the radiative properties of CO2 and other radiatively important gases are presented. Methods of computing gaseous absorption and their accuracy are discussed. Components of the radiation budget (solar and longwave) are described along with the effect of variations in CO2 concentration. Because aerosols and clouds also have important radiative properties, the effects of changes in aerosol and cloud amounts are also discussed. The purpose of this chapter is to provide an overview of the radiative effects of CO2 and other atmospheric constituents that are important in determining the potential climatic effects of changes in atmospheric composition

  2. Status of liquid metal cooled fast reactor technology

    International Nuclear Information System (INIS)

    During the period 1985-1998, there have been substantial advances in fast reactor technology development. Chief among these has been the demonstration of reliable operation by several prototypes and experimental reactors, the reliable operation of fuel at high burnup. At the IAEA meetings on liquid metal cooled fast reactor technology (LMFR), it became evident that there have been significant technological advances as well as changes in the economic and regulatory environment since 1985. Therefore the International working group on Fast Reactors has recommended the preparation of a new status report on fast reactors. The present report intends to provide comprehensive and detailed information on LMFR technology. The focus is on practical issues that are useful to engineers, scientists, managers, university students and professors, on the following topics: experience in construction and operation, reactor physics and safety, sore structural material and fuel technology, fast reactor engineering and activities in progress on LMFR plants

  3. Stationary plume induced by carbon dioxide dissolution

    International Nuclear Information System (INIS)

    In this paper, laminar convection flows induced by carbon dioxide absorption are addressed from experimental, numerical and theoretical points of view. A vertical glass tube (of centimetre scale) filled with distilled water is subjected to a sudden increase in the partial pressure of carbon dioxide. As a result of the diffusion of the gas into the unsaturated solution, a thin layer of fluid located underneath the surface becomes heavier. This initial density gradient first destabilizes to form a plume, which goes downwards through the entire cell. After a first transient pulsating regime (periodic succession of such Rayleigh-Benard plumes), a stationary flow settles in the tube, which is maintained by the constant supply of gas at the surface. At late stages, this stationary regime is followed by an aperiodic regime, which lasts until the complete saturation of the solution (thermodynamic equilibrium). The present study only focuses on the stationary regime, whose characteristics appear to be almost independent of the Bond number and the aspect ratio but strongly dependent on the chemical Rayleigh number. Three decades of Rayleigh numbers are explored using particle image velocimetry measurements, which allows for a precise determination of the scaling exponents for the vertical velocity amplitude and the plume width. The assumption that gravity and a constant pressure gradient balance the viscous effects enables us to derive an analytic expression for the stationary vertical velocity on the axis, which scales as Ra2/3 (ln Ra)1/3. As a consequence, the width of the plume scales as Ra-1/6 (ln Ra)-1/3 and the mass Nusselt number as (Ra= ln Ra)1/3. These scalings are in excellent agreement with the experimental and numerical results. The multiplicative constants of these scalings can also be calculated and show a fairly good agreement if a rigid boundary condition (no-slip) is assumed at the free surface. (authors)

  4. Six-fold coordinated carbon dioxide VI

    Energy Technology Data Exchange (ETDEWEB)

    Iota, Valentin; Yoo, Choong-Shik; Klepeis, Jae-Hyun; Jenei, Zsolt; Evans, William; Cynn, Hyunchae (LLNL)

    2008-06-16

    Under standard conditions, carbon dioxide (CO{sub 2}) is a simple molecular gas and an important atmospheric constituent, whereas silicon dioxide (SiO{sub 2}) is a covalent solid, and one of the fundamental minerals of the planet. The remarkable dissimilarity between these two group IV oxides is diminished at higher pressures and temperatures as CO{sub 2} transforms to a series of solid phases, from simple molecular to a fully covalent extended-solid V, structurally analogous to SiO{sub 2} tridymite. Here, we present the discovery of an extended-solid phase of CO{sub 2}: a six-fold coordinated stishovite-like phase VI, obtained by isothermal compression of associated CO{sub 2}-II above 50 GPa at 530-650 K. Together with the previously reported CO{sub 2}-V and a-carbonia, this extended phase indicates a fundamental similarity between CO{sub 2} (a prototypical molecular solid) and SiO{sub 2} (one of Earth's fundamental building blocks). We present a phase diagram with a limited stability domain for molecular CO{sub 2}-I, and suggest that the conversion to extended-network solids above 40-50 GPa occurs via intermediate phases II, III and IV. The crystal structure of phase VI suggests strong disorder along the c axis in stishovite-like P4{sub 2}/mnm, with carbon atoms manifesting an average six-fold coordination within the framework of sp{sup 3} hybridization.

  5. Six-fold coordinated carbon dioxide VI.

    Science.gov (United States)

    Iota, Valentin; Yoo, Choong-Shik; Klepeis, Jae-Hyun; Jenei, Zsolt; Evans, William; Cynn, Hyunchae

    2007-01-01

    Under standard conditions, carbon dioxide (CO2) is a simple molecular gas and an important atmospheric constituent, whereas silicon dioxide (SiO2) is a covalent solid, and one of the fundamental minerals of the planet. The remarkable dissimilarity between these two group IV oxides is diminished at higher pressures and temperatures as CO2 transforms to a series of solid phases, from simple molecular to a fully covalent extended-solid V, structurally analogous to SiO2 tridymite. Here, we present the discovery of an extended-solid phase of CO2: a six-fold coordinated stishovite-like phase VI, obtained by isothermal compression of associated CO2-II (refs 1,2) above 50 GPa at 530-650 K. Together with the previously reported CO2-V (refs 3-5) and a-carbonia, this extended phase indicates a fundamental similarity between CO2 (a prototypical molecular solid) and SiO2 (one of Earth's fundamental building blocks). We present a phase diagram with a limited stability domain for molecular CO2-I, and suggest that the conversion to extended-network solids above 40-50 GPa occurs via intermediate phases II (refs 1,2), III (refs 7,8) and IV (refs 9,10). The crystal structure of phase VI suggests strong disorder along the c axis in stishovite-like P42/mnm, with carbon atoms manifesting an average six-fold coordination within the framework of sp3 hybridization. PMID:17160005

  6. Thermal management systems for cooling nuclear reactor during emergency

    International Nuclear Information System (INIS)

    This paper discusses two different thermal management systems for nuclear reactor during emergency situation. First system will provide safer and reliable heat pipe based emergency core cooling system (ECCS) for nuclear-reactor, with initial 10 sec gravity feed water for accelerated cooling response. The designed loop type heat pipe ECCS is composed of cylindrical evaporator with 62 vertical tubes, each 150 mm diameter and 6 m length, mounted around the circumference of nuclear fuel assembly and 21 m x 10 m x 5 m naturally cooled finned condenser installed outside the primary containment. Proposed ECCS will be able to cool down core after reactor shutdown from 282degC to below 250degC within 4.3 hours of shutdown thereby providing safer environment to nuclear power plants. Second system proposes debris cooling system for nuclear reactor chamber, based on open air Bryton cycle. Such a system will provide cleaner and safer system for the nuclear reactor chamber after accident. (author)

  7. Materials development and materials selection for sodium cooled fast reactors

    International Nuclear Information System (INIS)

    As applied to operational conditions of fast reactors a combined investigations of structural materials are accomplished. Steels 10Kh18N9, 08Kh16N11M3 are recommended to be used for reactor vessels, steel 10Kh2M - for steam generators, a strain hardened steel 08Kh16N11M3T and steel 05Kh12N2M - for fuel assembly cans. The investigations provided for designing such sodium cooled fast reactors as Bor-60, BN-350, BN-600. The investigation results are now in use in construction of a new fast reactor BN-800

  8. Conceptual designs of hydrogen production, purification, compression and carbon dioxide capture

    International Nuclear Information System (INIS)

    Highlights: • Two types of heat-integrated processes, SWP and SCWP, are presented. • From economic aspects, it is verified that SWP is superior to SCWP. • From aspects of energy utilization, it is verified that SCWP is superior to SWP. • From aspects of CO2 capture, it is verified that SCWP is superior to SWP. - Abstract: The design of hydrogen production, purification, compression and carbon dioxide capture is developed as two types of heat-integrated processes. The SWP (SMR + WGS + PCC) is mainly composed of the steam methane reforming (SMR) reactor, the low temperature water–gas-shift (WGS) reactor and the process of hydrogen purification, compression and carbon dioxide capture (PCC), and the SCWP (SMR + CO2R + WGS + PCC) primarily consists of the SMR reactor, the carbon dioxide reforming of methane (CO2R) reactor, the WGS reactor and the PCC. From economic aspects, it is expectable that the SWP process is superior to the SCWP process due to lower energy demand and less equipment. From aspects of energy utilization and CO2 capture, it is verified that the SCWP process is superior to the SWP process

  9. Does carbon dioxide pool or stream in the subsurface?

    CERN Document Server

    Cardoso, Silvana S S

    2014-01-01

    Pools of carbon dioxide are found in natural geological accumulations and in engineered storage in saline aquifers. It has been thought that once this CO2 dissolves in the formation water, making it denser, convection streams would transport it efficiently to depth, but this may not be so. Here, we assess the impact of natural chemical reactions between the dissolved CO2 and the rock formation on the convection streams in the subsurface. We show that, while in carbonate rocks the streaming of dissolved carbon dioxide persists, the chemical interactions in silicate-rich rocks may curb this transport drastically and even inhibit it altogether. New laboratory experiments confirm the curtailing of convection by reaction. Wide and narrow streams of dense carbon-rich water are shut-off gradually as reaction strength increases until all transport of the pooled carbon dioxide occurs by slow molecular diffusion. These results show that the complex fluid dynamic and kinetic interactions between pooled carbon dioxide an...

  10. Enhanced kinetics for the clathrate process in a fixed bed reactor in the presence of liquid promoters for pre-combustion carbon dioxide capture

    International Nuclear Information System (INIS)

    In this work, we present enhanced kinetics of hydrate formation for the clathrate process in the presence of two liquid promoters namely THF (tetrahydrofuran) and TBAB (tetra-n-butyl ammonium bromide) in a FBR (fixed bed reactor) for pre-combustion capture of CO2. Silica sand was used as a medium to capture CO2 from CO2/H2 gas mixture by hydrate crystallisation. Experiments were performed at different temperatures (274.2 K and 279.2 K) and 6.0 MPa to determine the total gas uptake, induction time and rate of hydrate formation. The observed trends indicated that higher driving force resulted in higher gas consumption and significantly reduced induction time. For the same driving force, higher gas consumption and shorter induction time was achieved by THF as compared to TBAB. 5.53 mol% THF attained higher gas consumption than 1.0 mol% THF whereas 3.0 mol% TBAB attained lower gas consumption than 0.3 mol% TBAB. A highest gas uptake of 51.95 (±5.183) mmol of gas/mol of water and a highest rate of 51.21(±8.91) mol.min−1.m−3 were obtained for 5.53 mol% THF at 6.0 MPa and 279.2 K. Overall, this study indicated better hydrate formation kinetics with the use of THF in an FBR configuration for CO2 capture from a fuel gas mixture. - Highlights: • Better kinetic performance with THF compared to TBAB for CO2 capture in a fixed bed reactor. • Highest CO2 uptake (126.99 ± 12.67 mg of gas/g of water) was obtained for 5.53 mol% THF. • Highest growth rate (51.21 ± 8.91 mol min−1.m−3) for 30 min was obtained for 5.53 mol% THF. • Waste heat (ΔT = 20) is sufficient to recover all the hydrated gas

  11. Estimated Carbon Dioxide Emissions in 2008: United States

    Energy Technology Data Exchange (ETDEWEB)

    Smith, C A; Simon, A J; Belles, R D

    2011-04-01

    Flow charts depicting carbon dioxide emissions in the United States have been constructed from publicly available data and estimates of state-level energy use patterns. Approximately 5,800 million metric tons of carbon dioxide were emitted throughout the United States for use in power production, residential, commercial, industrial, and transportation applications in 2008. Carbon dioxide is emitted from the use of three major energy resources: natural gas, coal, and petroleum. The flow patterns are represented in a compact 'visual atlas' of 52 state-level (all 50 states, the District of Columbia, and one national) carbon dioxide flow charts representing a comprehensive systems view of national CO{sub 2} emissions. Lawrence Livermore National Lab (LLNL) has published flow charts (also referred to as 'Sankey Diagrams') of important national commodities since the early 1970s. The most widely recognized of these charts is the U.S. energy flow chart (http://flowcharts.llnl.gov). LLNL has also published charts depicting carbon (or carbon dioxide potential) flow and water flow at the national level as well as energy, carbon, and water flows at the international, state, municipal, and organizational (i.e. United States Air Force) level. Flow charts are valuable as single-page references that contain quantitative data about resource, commodity, and byproduct flows in a graphical form that also convey structural information about the system that manages those flows. Data on carbon dioxide emissions from the energy sector are reported on a national level. Because carbon dioxide emissions are not reported for individual states, the carbon dioxide emissions are estimated using published energy use information. Data on energy use is compiled by the U.S. Department of Energy's Energy Information Administration (U.S. EIA) in the State Energy Data System (SEDS). SEDS is updated annually and reports data from 2 years prior to the year of the update. SEDS

  12. Measurement of carbon dioxide diffusion coefficient of concrete

    OpenAIRE

    Villain, G.; PAVOINE, A; Thiery, M.

    2006-01-01

    The carbonation of concrete is a chemical reaction, which can be at the origin of the premature degradation of reinforced concrete structures. In order to predict service life of reinforced concrete structures, many models based on gas diffusion were developed. The carbon dioxide diffusion coefficient of concrete is thus a significant input datum for these models. The objective of this article is to present a simple reliable testing method to quantify the carbon dioxide diffusion coefficient ...

  13. Fuel Development For Gas-Cooled Fast Reactors

    Energy Technology Data Exchange (ETDEWEB)

    M. K. Meyer

    2006-06-01

    The Generation IV Gas-cooled Fast Reactor (GFR) concept is proposed to combine the advantages of high-temperature gas-cooled reactors (such as efficient direct conversion with a gas turbine and the potential for application of high-temperature process heat), with the sustainability advantages that are possible with a fast-spectrum reactor. The latter include the ability to fission all transuranics and the potential for breeding. The GFR is part of a consistent set of gas-cooled reactors that includes a medium-term Pebble Bed Modular Reactor (PBMR)-like concept, or concepts based on the Gas Turbine Modular Helium Reactor (GT-MHR), and specialized concepts such as the Very High Temperature Reactor (VHTR), as well as actinide burning concepts [ ]. To achieve the necessary high power density and the ability to retain fission gas at high temperature, the primary fuel concept proposed for testing in the United States is a dispersion coated fuel particles in a ceramic matrix. Alternative fuel concepts considered in the U.S. and internationally include coated particle beds, ceramic clad fuel pins, and novel ceramic ‘honeycomb’ structures. Both mixed carbide and mixed nitride-based solid solutions are considered as fuel phases.

  14. Design study on sodium-cooled large-scale reactor

    International Nuclear Information System (INIS)

    In Phase 1 of the 'Feasibility Study on Commercialized Fast Reactor Cycle Systems (F/S)', an advanced loop type reactor has been selected as a promising concept of sodium-cooled large-scale reactor, which has a possibility to fulfill the design requirements of the F/S. In Phase 2 of the F/S, it is planed to precede a preliminary conceptual design of a sodium-cooled large-scale reactor based on the design of the advanced loop type reactor. Through the design study, it is intended to construct such a plant concept that can show its attraction and competitiveness as a commercialized reactor. This report summarizes the results of the design study on the sodium-cooled large-scale reactor performed in JFY2001, which is the first year of Phase 2. In the JFY2001 design study, a plant concept has been constructed based on the design of the advanced loop type reactor, and fundamental specifications of main systems and components have been set. Furthermore, critical subjects related to safety, structural integrity, thermal hydraulics, operability, maintainability and economy have been examined and evaluated. As a result of this study, the plant concept of the sodium-cooled large-scale reactor has been constructed, which has a prospect to satisfy the economic goal (construction cost: less than 200,000yens/kWe, etc.) and has a prospect to solve the critical subjects. From now on, reflecting the results of elemental experiments, the preliminary conceptual design of this plant will be preceded toward the selection for narrowing down candidate concepts at the end of Phase 2. (author)

  15. Design requirements, operation and maintenance of gas-cooled reactors

    International Nuclear Information System (INIS)

    At the invitation of the Government of the USA the Technical Committee Meeting on Design Requirements, Operation and Maintenance of Gas-Cooled Reactors, was held in San Diego on September 21-23, 1988, in tandem with the GCRA Conference. Both meetings attracted a large contingent of foreign participants. Approximately 100 delegates from 18 different countries participated in the Technical Committee meeting. The meeting was divided into three sessions: Gas-cooled reactor user requirement (8 papers); Gas-cooled reactor improvements to facilitate operation and maintenance (10 papers) and Safety, environmental impacts and waste disposal (5 papers). A separate abstract was prepared for each of these 23 papers. Refs, figs and tabs

  16. Study on the conversion of H2 and CO from the helium carrier gas of high temperature gas-cooled reactor

    International Nuclear Information System (INIS)

    The conversions of hydrogen and carbon monoxide into water vapor and carbon dioxide on CuO-ZnO-Al2O3 catalyst are studied. The effects of different temperature, system atmospheric pressure, impurity gas concentration, flow and dew point on properties of cupric oxide bed are investigated. The conversion characteristics curves of H2 and CO are given. Experimental data of conversion capacity, action period and conversion efficiency of CuO-ZnO-Al2O3 are obtained and the optimal parameters are determined. The results show that the concentration of H2 and CO of the effluent gas after purification can reach below 2 x 10-6, respectively. So it can meet the demands of high temperature gas-cooled reactor and also provide optimal design parameters and reliable data for conversion of H2 and CO on CuO-ZnO-Al2O3 catalyst

  17. Comparative study of solvent properties for carbon dioxide absorption

    Energy Technology Data Exchange (ETDEWEB)

    Aschenbrenner, O.; Styring, P. [University of Sheffield, Sheffield (United Kingdom)

    2010-07-01

    Several inexpensive and non-toxic solvents with low vapour pressures were investigated for their suitability as alternative solvents for the absorption of carbon dioxide from flue gas. The solvents include poly(ethylene glycol)s, poly(ethylene glycol) ethers, poly(ethylenimine) and glycerol-based substances. Solvent properties such as thermal stability, solubility of carbon dioxide and selectivity over nitrogen were investigated in a systematic study using a thermogravimetric analyser. Absorption results are reported for pure carbon dioxide and nitrogen as well as a mixture of both gases. Desorption and long-term sorption behaviour are also discussed. Glycerol and poly(ethylene glycol)s show a high solubility of carbon dioxide. Due to the high viscosity of the solvent, carbon dioxide absorption in poly(ethylenimine) is very slow in spite of the presence of favourable amine groups. PEG 300 was found to be the best solvent in this study and shows a high carbon dioxide solubility as well as good selectivity over nitrogen. The advantages of high stability, low solvent loss and low desorption energy of PEG 300 may outweigh its lower absorption capacity compared to the state-of-the-art solvent monoethanolamine, making it a potentially advantageous solvent for industrial carbon dioxide absorption processes.

  18. Modeling and calculation of open carbon dioxide refrigeration system

    International Nuclear Information System (INIS)

    Highlights: • A model of open refrigeration system is developed. • The state of CO2 has great effect on Refrigeration capacity loss by heat transfer. • Refrigeration capacity loss by remaining CO2 has little relation to the state of CO2. • Calculation results are in agreement with the test results. - Abstract: Based on the analysis of the properties of carbon dioxide, an open carbon dioxide refrigeration system is proposed, which is responsible for the situation without external electricity unit. A model of open refrigeration system is developed, and the relationship between the storage environment of carbon dioxide and refrigeration capacity is conducted. Meanwhile, a test platform is developed to simulation the performance of the open carbon dioxide refrigeration system. By comparing the theoretical calculations and the experimental results, several conclusions are obtained as follows: refrigeration capacity loss by heat transfer in supercritical state is much more than that in two-phase region and the refrigeration capacity loss by remaining carbon dioxide has little relation to the state of carbon dioxide. The results will be helpful to the use of open carbon dioxide refrigeration

  19. The Formation of Ethane from Carbon Dioxide under Cold Plasma

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Pulsed-corona plasma has been used as a new method for ethane dehydrogenation at low temperature and normal pressure using carbon dioxide as an oxidant in this paper. The effect of carbon dioxide content in the feed, power input, and flow rate of the reactants on the ethane dehydrogenation has been investigated. The experimental results show that the conversion of ethane increases with the increase in the amount of carbon dioxide in the feed. The yield of ethylene and acetylene decreases with the increase in the yield of carbon monoxide, indicating that the increased carbon dioxide leads to the part of ethylene and acetylene being oxidized to carbon monoxide. Power input is primarily an electrical parameter in pulsed-corona plasma, which plays an important role in reactant conversion and product formation. When the power input reaches 16 W, ethane conversion is 41.0% and carbon dioxide conversion is 26.3%. The total yield of ethylene and acetylene is 15.6%. The reduced flow rate of feed improves the conversion of ethane,carbon dioxide and the yield of acetylene, and induces carbon deposit as well.

  20. Forest management techniques for carbon dioxide storage

    Energy Technology Data Exchange (ETDEWEB)

    Fujimori, Takao [Forestry and Forest Products Research Inst., Tsukuba, Ibaraki (Japan)

    1993-12-31

    In the global ecosystem concerning carbon dioxide content in the atmosphere, the forest ecosystem plays an important role. In effect, the ratio of forest biomass to total terrestrial biomass is about 90%, and the ratio of carbon stored in the forest biomass to that in the atmosphere is two thirds. When soils and detritus of forests are added, there is more C stored in forests than in the atmosphere, about 1.3 times or more. Thus, forests can be regarded as the great holder of C on earth. If the area of forest land on the earth is constantly maintained and forests are in the climax stage, the uptake of C and the release of C by and from the forests will balance. In this case, forests are neither sinks nor sources of CO{sub 2} although they store a large amount of C. However, when forests are deforested, they become a source of C; through human activities, forests have become a source of C. According to a report by the IPCC, 1.6{+-}1.2 PgC is annually added to the atmosphere by deforestation. According to the FAO (1992), the area of land deforested annually in the tropics from 1981 to 1990 was 16.9 x 10{sup 6} ha. This value is nearly half the area of Japanese land. The most important thing for the CO{sub 2} environment concerning forests is therefore how to reduce deforestation and to successfully implement a forestation or reforestation.

  1. Carbon dioxide warming of the early Earth

    Science.gov (United States)

    Arrhenius, G.

    1997-01-01

    Svante Arrhenius' research in atmospheric physics extended beyond the recent past and the near future states of the Earth, which today are at the center of sociopolitical attention. His plan encompassed all of the physical phenomena known at the time to relate to the formation and evolution of stars and planets. His two-volume textbook on cosmic physics is a comprehensive synopsis of the field. The inquiry into the possible cause of the ice ages and the theory of selective wavelength filter control led Arrhenius to consider the surface states of the other terrestrial planets, and of the ancient Earth before it had been modified by the emergence of life. The rapid escape of hydrogen and the equilibration with igneous rocks required that carbon in the early atmosphere prevailed mainly in oxidized form as carbon dioxide, together with other photoactive gases exerting a greenhouse effect orders of magnitude larger than in our present atmosphere. This effect, together with the ensuing chemical processes, would have set the conditions for life to evolve on our planet, seeded from spores spreading through an infinite Universe, and propelled, as Arrhenius thought, by stellar radiation pressure.

  2. Sintering uranium oxide in the reaction product of hydrogen-carbon dioxide mixtures

    International Nuclear Information System (INIS)

    Compacted pellets of uranium oxide alone or containing one or more additives such as plutonium dioxide, gadolinium oxide, titanium dioxide, silica, and alumina are heated to 900 to 15990C in the presence of a mixture of hydrogen and carbon dioxide, either alone or with an inert carrier gas and held at the desired temperature in this atmosphere to sinter the pellets. The sintered pellets are then cooled in an atmosphere having an oxygen partial pressure of 10-4 to 10-18 atm of oxygen such as dry hydrogen, wet hydrogen, dry carbon monoxide, wet carbon monoxide, inert gases such as nitrogen, argon, helium, and neon and mixtures of ayny of the foregoing including a mixture of hydrogen and carbon dioxide. The ratio of hydrogen to carbon dioxide in the gas mixture fed to the furnace is controlled to give a ratio of oxygen to uranium atoms in the sintered particles within the range of 1.98:1 to about 2.10:1. The water vapor present in the reaction products in the furnace atmosphere acts as a hydrolysis agent to aid removal of fluoride should such impurity be present in the uranium oxide. (U.S.)

  3. Simple analysis of an External Vessel Cooling Thermosyphon for a Sodium-cooled Fast Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Jae Young; Jeong, Yong Hoon [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Song, Sub Lee [Handong Global University, Pohang (Korea, Republic of)

    2015-05-15

    KALIMER has three different DHR systems: two non-safety grade systems and one safety grade system. The non-safety grade systems are an IRACS (Intermediate Reactor Auxiliary Cooling System) and a steam/feedwater system. The safety grade system is a PDRC (Passive Decay Heat Removal Circuit). In case of the foreign reactor designs, ABTR (Advanced Burner Test Reactor) has a DRACS (Direct Reactor Auxiliary Cooling System), a PFBR (Indian Prototype Fast Breeder Reactor) has an SGDHRS (Safety Grade Decay Heat Removal System), and an EFR (European Fast Reactor) has DRC (Direct Reactor Cooling). Those designs have advantage on relatively high decay heat removal capacity. However, larger vessel size due to subsidiary in-vessel structure and possible accident propagation to reactor induced by sodium fire. In this paper, an ex-vessel thermosyphon design was proposed for the removal of decay heat for an iSFR. The proposed ex-vessel thermosyphon was designed to remove decay heat in both transient cases and BDBA cases, such as vessel failure. Proper working fluid was selected based on thermodynamic properties and chemical stability. Mercury was chosen as the working fluid, and SUS 314 was used for the corresponding structure material. Possible chemical reactions and adverse effects from using the thermosyphon were inherently eliminated by the system layout. A model for a high-temperature thermosyphon and numerical algorithms were used for the analysis. As a result of the simulation, the thermosyphon design was optimized, and it showed sufficient DHR performance to maintain core integrity.

  4. Simple analysis of an External Vessel Cooling Thermosyphon for a Sodium-cooled Fast Reactor

    International Nuclear Information System (INIS)

    KALIMER has three different DHR systems: two non-safety grade systems and one safety grade system. The non-safety grade systems are an IRACS (Intermediate Reactor Auxiliary Cooling System) and a steam/feedwater system. The safety grade system is a PDRC (Passive Decay Heat Removal Circuit). In case of the foreign reactor designs, ABTR (Advanced Burner Test Reactor) has a DRACS (Direct Reactor Auxiliary Cooling System), a PFBR (Indian Prototype Fast Breeder Reactor) has an SGDHRS (Safety Grade Decay Heat Removal System), and an EFR (European Fast Reactor) has DRC (Direct Reactor Cooling). Those designs have advantage on relatively high decay heat removal capacity. However, larger vessel size due to subsidiary in-vessel structure and possible accident propagation to reactor induced by sodium fire. In this paper, an ex-vessel thermosyphon design was proposed for the removal of decay heat for an iSFR. The proposed ex-vessel thermosyphon was designed to remove decay heat in both transient cases and BDBA cases, such as vessel failure. Proper working fluid was selected based on thermodynamic properties and chemical stability. Mercury was chosen as the working fluid, and SUS 314 was used for the corresponding structure material. Possible chemical reactions and adverse effects from using the thermosyphon were inherently eliminated by the system layout. A model for a high-temperature thermosyphon and numerical algorithms were used for the analysis. As a result of the simulation, the thermosyphon design was optimized, and it showed sufficient DHR performance to maintain core integrity

  5. Alkali metal carbon dioxide electrochemical system for energy storage and/or conversion of carbon dioxide to oxygen

    Science.gov (United States)

    Hagedorn, Norman H. (Inventor)

    1993-01-01

    An alkali metal, such as lithium, is the anodic reactant; carbon dioxide or a mixture of carbon dioxide and carbon monoxide is the cathodic reactant; and carbonate of the alkali metal is the electrolyte in an electrochemical cell for the storage and delivery of electrical energy. Additionally, alkali metal-carbon dioxide battery systems include a plurality of such electrochemical cells. Gold is a preferred catalyst for reducing the carbon dioxide at the cathode. The fuel cell of the invention produces electrochemical energy through the use of an anodic reactant which is extremely energetic and light, and a cathodic reactant which can be extracted from its environment and therefore exacts no transportation penalty. The invention is, therefore, especially useful in extraterrestrial environments.

  6. Evaluation for External Reactor Vessel Cooling System using CFD Simulation

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Seok Bin; Park, Seong Dae; Bang, In Cheol [Ulsan National Institute of Science and Technology, Ulsan (Korea, Republic of)

    2012-05-15

    To ensure the safety of the nuclear plants, there are lots of safety systems in the nuclear plant. One of them is External Reactor Vessel Cooling system (ERVC) which is operated when a molten corium is relocated in a lower head of a reactor vessel. As ERVC system runs, coolant flows down into a reactor cavity to remove a decay heat from the molten corium. This work simulated the ERVC system which is applied to APR1400 with CFD. To estimate the efficiency of the ERVC system, we designed the reactor cavity of the ERVC system of APR1400 in a full scale. From the designed model, we measured temperature distribution of the reactor vessel outer wall. Two kinds of coolant were used in this computational approach. One is present flooding matter which is water. The other is liquid metal gallium. With varying the area of the inlet and outlet of reactor cavity, we evaluated the importance of each variable

  7. Preliminary evaluation of alternate-fueled gas cooled fast reactors

    International Nuclear Information System (INIS)

    A preliminary evaluation of various alternative fuel cycles for the Gas-Cooled Fast Reactor (GCFR) is presented. Both homogeneous and heterogeneous oxide-fueled GCFRs are considered. The scenario considered is the energy center/dispersed reactor concept in which proliferation-resistant denatured reactors are coupled to 233U production reactors operating in secure energy centers. Individual reactor performance characteristics and symbiotic system parameters are summarized for several possible alternative fuel concepts. Comparisons are made between the classical homogeneous GCFR and the advanced heterogeneous concept on the basis of breeding ratio, doubling time, and net fissile gain. In addition, comparisons are made between a three-dimensional reactor model and the R-Z heterogeneous configuration utilized for the depletion and fuel management calculations. Lastly, thirty-year mass balance data are given for the various GCFR fuel cycles studied

  8. Feasibility and deployment strategy of water cooled thorium breeder reactor

    International Nuclear Information System (INIS)

    The author have studied water cooled thorium breeder reactor based on matured pressurized water reactor (PWR) plant technology for several years. Through these studies it is concluded that reduced moderated core by arranging fuel pins in a triangular tight lattice array with heavy water coolant in the primary loop by replacing original light water is appropriate for achieving sufficient breeding performance as sustainable fission system and high enough burn-up as an economical power plant. The heavy water cooled thorium reactor is feasible to be introduced by using Pu recovered from spent fuel of LWR, keeping continuity with current LWR infrastructure. This thorium reactor can be operated as sustainable energy supplier and also MA transmuter to realize future society with less long-lived nuclear waste

  9. The case for the gas cooled fast reactor

    International Nuclear Information System (INIS)

    Although gas-cooling for fast reactors had been the subject of consideration since the early days of nuclear power, it was when the concept of the prestressed concrete pressure vessel turned into practical fact, that convincing arguments could be made to overcome safety objections. In terms of hardware, the Gas Cooled Fast Breeder Reactor can rely on existing and available technologies; as far as fuel is concerned, valuable information will be derived from the Liquid Metal Fast Breeder Reactor programme. The GCFR can be made very flexible; its capital cost will not exceed by more than 20% the one for reactor built at present on commercial scale; the overall economy of its fuel cycle is good. It could play an important role in the future breeder family

  10. Passive safety features in current and future water cooled reactors

    International Nuclear Information System (INIS)

    Better understanding of the passive safety systems and components in current and future water-cooled reactors may enhance the safety of present reactors, to the extend passive features are backfitted. This better understanding should also improve the safety of future reactors, which can incorporate more of these features. Passive safety systems and components may help to prevent accidents, core damage, or release radionuclides to the environment. The Technical Committee Meeting which was hosted by the USSR State Committee for Utilization of Nuclear Energy was attended by about 80 experts from 16 IAEA Member States and the NEA-OECD. A total of 21 papers were presented during the meeting. The objective of the meeting was to review and discuss passive safety systems and features of current and future water cooled reactor designs and to exchange information in this area of activity. A separate abstract was prepared for each of the 21 papers published in this proceedings. Refs, figs and tabs

  11. Application of Hastelloy X in Gas-Cooled Reactor Systems

    DEFF Research Database (Denmark)

    Brinkman, C. R.; Rittenhouse, P. L.; Corwin, W.R.;

    1976-01-01

    Hastelloy X, an Ni--Cr--Fe--Mo alloy, may be an important structural alloy for components of gas-cooled reactor systems. Expected applications of this alloy in the High-Temperature Gas-Cooled Reactor (HTGR) are discussed, and the development of interim mechanical properties and supporting data...... extensive amount of information has been generated on this material at Oak Ridge National Laboratory and elsewhere concerning behavior in air, which is reviewed. However, only limited data are available from tests conducted in helium. Comparisons of the fatigue and subcritical growth behavior in air between...... Hastelloy X and a number of other structural alloys are given....

  12. PARAMETRIC SENSITIVITY STUDY OF A FUSION REACTOR DIVERTOR COOLING FINGER

    OpenAIRE

    Martin, Oliver; SIMONOVSKI IGOR

    2012-01-01

    In this paper the results of coupled thermal-mechanical Finite Element (FE) analysis on the design of a fusion reactor divertor cooling finger are presented. Beside its main purpose, to remove alpha particles, helium and other impurities from the plasma stream, a divertor has to remove approximately 15% of the total thermal power of the fusion reactor. The aim of the analysis is to assess the influence of a number of physical properties of the brazing layer (BL) of the cooling finger on the o...

  13. Histidine-catalyzed synthesis of cyclic carbonates in supercritical carbon dioxide

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The coupling reaction of carbon dioxide with epoxides was investigated using naturally occurring α-amino acids as the catalyst in supercritical carbon dioxide and it was found that L-histidine is the most active catalyst.In the presence of 0.8 mol% of L-histidine at 130°C under 8 MPa of CO2,the reaction of carbon dioxide with epoxides proceeded smoothly,affording corresponding cyclic carbonates in good to excellent yields.

  14. Gas-cooled reactor safety and accident analysis

    International Nuclear Information System (INIS)

    The Specialists' Meeting on Gas-Cooled Reactor Safety and Accident Analysis was convened by the International Atomic Energy Agency in Oak Ridge on the invitation of the Department of Energy in Washington, USA. The meeting was hosted by the Oak Ridge National Laboratory. The purpose of the meeting was to provide an opportunity to compare and discuss results of safety and accident analysis of gas-cooled reactors under development, construction or in operation, to review their lay-out, design, and their operational performance, and to identify areas in which additional research and development are needed. The meeting emphasized the high safety margins of gas-cooled reactors and gave particular attention to the inherent safety features of small reactor units. The meeting was subdivided into four technical sessions: Safety and Related Experience with Operating Gas-Cooled Reactors (4 papers); Risk and Safety Analysis (11 papers); Accident Analysis (9 papers); Miscellaneous Related Topics (5 papers). A separate abstract was prepared for each of these papers

  15. Supercritical water-cooled nuclear reactors: NPP layouts and thermal design options of pressure channels

    International Nuclear Information System (INIS)

    Research activities are currently underway worldwide to develop generation IV nuclear reactor concepts with the objective of improving thermal efficiency and increasing economic competitiveness of generation IV nuclear power plants (NPPs) compared to modern NPPs. The supercritical water-cooled reactor (SCWR) concept is one of six generation-IV options chosen for further investigation and development in many countries worldwide, including Canada. Water-cooled reactors operating at subcritical pressures (7 - 16 MPa) have provided significant electricity production for the past 50 years. However, the thermal efficiency of current NPPs is not very high (30 - 35%). As such, more competitive designs with higher thermal efficiencies, close to those of modern supercritical (Sc) thermal power plants (45 - 50%), need to be developed and implemented. Previous studies have shown that direct cycles with single-reheat and no-reheat configurations are the best options for an SCWR concept. There are a few technical challenges associated with the single-reheat and no-reheat supercritical water (SCW) NPP configurations. The single-reheat cycle requires nuclear steam-reheat, thus increasing the complexity of the reactor core design. Conversely, the major technical challenge associated with an Sc no-reheat turbine is high moisture content in the low-pressure-turbine exhaust. The SCWR-core concept investigated in this paper is based on a generic pressure-tube (pressure-channel) reactor with a 43-element bundle string cooled with supercritical water. The considered 1200-MW el reactor has the following operating parameters: pressure of 25 MPa and reactor inlet/outlet temperatures of 350/625 C. Previous studies have shown that is uranium dioxide (UO2) is used, the fuel centerline temperature might exceed the industry accepted limit of 1850 C. Therefore, this paper investigates a possibility of using uranium carbide (UC), uranium nitride (UN), uranium dicarbide (UC2), uranium dioxide plus

  16. Energy and carbon dioxide implications of building construction

    Energy Technology Data Exchange (ETDEWEB)

    Buchanan, A.H. (Canterbury Univ., Christchurch (New Zealand)); Honey, B.G. (Canterbury Univ., Christchurch (New Zealand))

    1994-01-01

    This paper investigates the amount of energy required to construct buildings, and the resulting carbon dioxide emissions to the atmosphere from the fossil fuel components of that energy. Energy requirements and carbon dioxide emissions are compared for typical commercial, industrial and residential buildings, using New Zealand as an example. A modest change from concrete and steel to more wood construction could lead to a substantial reduction in energy requirements and carbon dioxide emissions, but the sustainability of such a change has significant forestry implications. (orig.)

  17. Disintegration of Carbon Dioxide Molecules in a Microwave Plasma Torch

    OpenAIRE

    Kwak, Hyoung S.; Uhm, Han S.; Yong C. Hong; Eun H. Choi

    2015-01-01

    A pure carbon dioxide torch is generated by making use of 2.45 GHz microwave. Carbon dioxide gas becomes the working gas and produces a stable carbon dioxide torch. The torch volume is almost linearly proportional to the microwave power. Temperature of the torch flame is measured by making use of optical spectroscopy and thermocouple. Two distinctive regions are exhibited, a bright, whitish region of high-temperature zone and a bluish, dimmer region of relatively low-temperature zone. Study o...

  18. Production and emission of methane and carbon dioxide by ruminants

    International Nuclear Information System (INIS)

    Animal digestion is responsible for the production of both carbon dioxide and methane, while breathing produces only carbon dioxide. The author described the digestion mechanism of ruminants, explaining that they produce higher levels of methane and carbon dioxide than other animals. Fermentation stoichiometry of ruminants was also discussed along with the influence that diet has on methane production. It was noted that methane production can be decreased by increasing animal productivity, or by using ionophore antibiotics and long chain fatty acids. Test results from each of these methods have revealed side effects and none appears to be applicable for the time being. 10 refs., 1 tab., 1 fig

  19. Carbon dioxide and nisin act synergistically on Listeria monocytogenes

    DEFF Research Database (Denmark)

    Nilsson, Lilian; Chen, Y.H.; Chikindas, M.L.;

    2000-01-01

    This paper examines the synergistic action of carbon dioxide and nisin on Listeria monocytogenes Scott A wild-type and nisin-resistant (Nis(r)) cells grown in broth at 4 degrees C. Carbon dioxide extended the lag phase and decreased the specific growth rate of both strains, but to a greater degree...... delayed for cultures in CO2. This synergism between nisin and CO2 was examined mechanistically by following the leakage of carboxyfluorescein (CF) from listerial liposomes. Carbon dioxide enhanced nisin-induced CF leakage, indicating that the synergistic action of CO2 and nisin occurs at the cytoplasmic...

  20. Carbon dioxide fluid-flow modeling and injectivity calculations

    Science.gov (United States)

    Burke, Lauri

    2011-01-01

    At present, the literature lacks a geologic-based assessment methodology for numerically estimating injectivity, lateral migration, and subsequent long-term containment of supercritical carbon dioxide that has undergone geologic sequestration into subsurface formations. This study provides a method for and quantification of first-order approximations for the time scale of supercritical carbon dioxide lateral migration over a one-kilometer distance through a representative volume of rock. These calculations provide a quantified foundation for estimating injectivity and geologic storage of carbon dioxide.

  1. Capital cost: gas cooled fast reactor plant

    Energy Technology Data Exchange (ETDEWEB)

    1977-09-01

    The results of an investment cost study for a 900 MW(e) GCFR central station power plant are presented. The capital cost estimate arrived at is based on 1976 prices and a conceptual design only, not a mature reactor design.

  2. Capital cost: gas cooled fast reactor plant

    International Nuclear Information System (INIS)

    The results of an investment cost study for a 900 MW(e) GCFR central station power plant are presented. The capital cost estimate arrived at is based on 1976 prices and a conceptual design only, not a mature reactor design

  3. High-Temperature Gas-Cooled Test Reactor Point Design

    Energy Technology Data Exchange (ETDEWEB)

    Sterbentz, James William [Idaho National Laboratory; Bayless, Paul David [Idaho National Laboratory; Nelson, Lee Orville [Idaho National Laboratory; Gougar, Hans David [Idaho National Laboratory; Kinsey, James Carl [Idaho National Laboratory; Strydom, Gerhard [Idaho National Laboratory; Kumar, Akansha [Idaho National Laboratory

    2016-04-01

    A point design has been developed for a 200 MW high-temperature gas-cooled test reactor. The point design concept uses standard prismatic blocks and 15.5% enriched UCO fuel. Reactor physics and thermal-hydraulics simulations have been performed to characterize the capabilities of the design. In addition to the technical data, overviews are provided on the technological readiness level, licensing approach and costs.

  4. Safety Design Criteria of Indian Sodium Cooled Fast Reactors

    International Nuclear Information System (INIS)

    • Important feedback has been gained through the design and safety review of PFBR. • The safety criteria document prepared by AERB and IGCAR would provide important input to prepare the dedicated document for the Sodium cooled Fast Reactors at the national and international level. • A common approach with regard to safety, among countries pursuing fast reactor program, is desirable. • Sharing knowledge and experimental facilities on collaborative basis. • Evolution of strong safety criteria – fundamental to assure safety

  5. Carbon Dioxide-Water Emulsions for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Ryan, David; Golomb, Dan; Shi, Guang; Shih, Cherry; Lewczuk, Rob; Miksch, Joshua; Manmode, Rahul; Mulagapati, Srihariraju; Malepati, Chetankurmar

    2011-09-30

    This project involves the use of an innovative new invention Particle Stabilized Emulsions (PSEs) of Carbon Dioxide-in-Water and Water-in-Carbon Dioxide for Enhanced Oil Recovery (EOR) and Permanent Sequestration of Carbon Dioxide. The EOR emulsion would be injected into a semi-depleted oil reservoir such as Dover 33 in Otsego County, Michigan. It is expected that the emulsion would dislocate the stranded heavy crude oil from the rock granule surfaces, reduce its viscosity, and increase its mobility. The advancing emulsion front should provide viscosity control which drives the reduced-viscosity oil toward the production wells. The make-up of the emulsion would be subsequently changed so it interacts with the surrounding rock minerals in order to enhance mineralization, thereby providing permanent sequestration of the injected CO{sub 2}. In Phase 1 of the project, the following tasks were accomplished: 1. Perform laboratory scale (mL/min) refinements on existing procedures for producing liquid carbon dioxide-in-water (C/W) and water-in-liquid carbon dioxide (W/C) emulsion stabilized by hydrophilic and hydrophobic fine particles, respectively, using a Kenics-type static mixer. 2. Design and cost evaluate scaled up (gal/min) C/W and W/C emulsification systems to be deployed in Phase 2 at the Otsego County semi-depleted oil field. 3. Design the modifications necessary to the present CO{sub 2} flooding system at Otsego County for emulsion injection. 4. Design monitoring and verification systems to be deployed in Phase 2 for measuring potential leakage of CO{sub 2} after emulsion injection. 5. Design production protocol to assess enhanced oil recovery with emulsion injection compared to present recovery with neat CO{sub 2} flooding. 6. Obtain Federal and State permits for emulsion injection. Initial research focused on creating particle stabilized emulsions with the smallest possible globule size so that the emulsion can penetrate even low-permeability crude

  6. Gas-cooled fast breeder reactor. Quarterly progress report, February 1-April 30, 1980

    Energy Technology Data Exchange (ETDEWEB)

    1980-05-01

    Information is presented concerning the reactor vessel; reactivity control mechanisms and instrumentation; reactor internals; primary coolant circuits;core auxiliary cooling system; reactor core; systems engineering; and reactor safety and reliability;

  7. Three decades of experience with cooling water system of a fast reactor

    International Nuclear Information System (INIS)

    The cooling water system constitutes the terminal heat exchange system for the fast breeder test reactor (FBTR) which is a sodium cooled fast reactor of 40 MWt capacity. It transfers the residual heat to atmosphere through a cooling tower. Cooling water system of FBTR comprises two sub-systems namely condenser cooling water system and service water system. Condenser cooling water is circulated through main condenser, dump condenser, condensate cooler, generator air cooler and turbine oil cooler. Service water system removes heat from several heat exchangers of auxiliary systems like air compressor, cold trap cooling, nitrogen plant, Biological Shield Cooling (BSC), Diesel Generator (DG) and steam-water system sample coolers. The cooling water system consists of an open recirculating type with an induced draft cooling tower as the ultimate heat sink. Initially, Palar river water was used as the cooling medium. At present, due to scarcity of river water, sub soil water and output from Nuclear Desalination Demonstration Plant (NDDP) are also used as cooling water. The material of construction of pipe line is carbon steel and the heat exchanger tube and other equipment materials are copper, admiralty brass, aluminium brass, bronze, Cu-Ni and carbon steel. The construction of the cooling water system of FBTR was completed in 1980. Since then the sub-systems were commissioned one by one. Whenever a sub system was commissioned, it generated a lot of impurities which affected the existing treatment programme. Sodium hexa meta phosphate treatment, Langelier Index monitoring, chlorination, global and target dispersant addition at high heat flux heat exchanger, chemical cleaning of corroded pipelines, corrosion monitoring, side stream filtration, addition of phosphonate-based corrosion inhibitor, broad spectrum biocide and specific biocide for iron oxidising bacteria are some of the phases of the cooling water treatment programme. At present, corrosion rates are generally

  8. Understanding how individuals perceive carbon dioxide. Implications for acceptance of carbon dioxide capture and storage

    Energy Technology Data Exchange (ETDEWEB)

    Itaoka, K.; Saito, A. [Mizuho Information and Research Institute, Tokyo (Japan); Paukovic, M.; De Best-Waldhober, M. [ECN Policy Studies, Petten (Netherlands); Dowd, A.M.; Jeanneret, T.; Ashworth, P.; James, M. [The Global CCS Institute, Canberra (Australia)

    2012-06-15

    Carbon dioxide capture and storage (CCS) presents one potential technological solution for mitigating the atmospheric emission of carbon dioxide sources. However, CCS is a relatively new technology with associated uncertainties and perceived risks. For this reason, a growing body of research now focuses on public perceptions and potential for societal acceptance of CCS technology. Almost all explanations of CCS technology make reference to carbon dioxide, with an assumption that the general public understands CO2. It has become apparent that the general public’s knowledge and understanding of CO2’s properties influences how they engage with CO2 emitting industries and CCS technologies. However, surprisingly little research has investigated public perceptions, knowledge, and understanding of CO2. This investigation attempts to fill that gap. This report describes an investigation of how citizens of three countries (Japan, Australia, and the Netherlands) perceive CO2. Furthermore, it attempts to relate individual perceptions of CO2 to perceptions of CCS, and to determine how information provision about the underlying properties and characteristics of CO2 influences individual attitudes towards low carbon energy options, particularly CCS. In brief, the research had four ultimate aims. It aimed to: Explore the public’s knowledge and understanding of the properties of CO2; Examine the influence of that knowledge on their perceptions of CO2 and CCS; Investigate how information provision about the underlying properties and characteristics of CO2 influences individual attitudes towards CCS; and Identify if any differences between countries exist in relation to values and beliefs, knowledge of CO2’s properties, and CCS perceptions.

  9. Evolution of design of steam generator for sodium cooled reactors

    International Nuclear Information System (INIS)

    The first sodium cooled reactor was the experimental breeder reactor (EBR-I) in usa which was commissioned in 1951 and was incidentally the first nuclear reactor to generate electrical energy. This was followed by fast breeder reactors in USSR, UK, france, USA, japan, germany and India. The use of sodium as a coolant is due to its low moderation which helps in breeding fissile fuel from fertile materials and also its high heat transfer coefficient at comparatively low velocities. The good heat transfer properties introduce thermal stresses when there are rapid changes in the sodium temperatures. Also sodium has a chemical affinity with air and water. The steam generators for sodium cooled reactors have to allow for these novel conditions and in addition, unlike other components. Choices have to be made whether it is a recirculation type as in most fossil plants or an once through unit, the power rating, shape of the tube (straight, helical, U-tube), materials (Ferritic or austenitic), with free level of sodium or not, sodium on tube side or shell side and so on. With higher pressures and steam temperatures reheating steam after partial expansion in the turbine becomes essential as in conventional turbines. For this purpose the choice of reheating fluid viz sodium or live main steam has to be made. This paper traces the evolution of steam generator designs in the different sodium cooled reactors (chronologically) and the operation experience. 16 figs., 1 tab

  10. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; William J. McMichael; Douglas P. Harrison; Ya Liang

    2002-01-01

    The objective of this project is to develop a simple, inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, or ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. This quarter, five cycle thermogravimetric tests were conducted at the Louisiana State University (LSU) with sodium bicarbonate Grade 3 (SBC{number_sign}3) which showed that carbonation activity declined slightly over 5 cycles following severe calcination conditions of 200 C in pure CO{sub 2}. Three different sets of calcination conditions were tested. Initial carbonation activity (as measured by extent of reaction in the first 25 minutes) was greatest subsequent to calcination at 120 C in He, slightly less subsequent to calcination in 80% CO{sub 2}/20% H{sub 2}O, and lowest subsequent to calcination in pure CO{sub 2} at 200 C. Differences in the extent of reaction after 150 minutes of carbonation, subsequent to calcination under the same conditions followed the same trend but were less significant. The differences between fractional carbonation under the three calcination conditions declined with increasing cycles. A preliminary fixed bed reactor test was also conducted at LSU. Following calcination, the sorbent removed approximately 19% of the CO{sub 2} in the simulated flue gas. CO{sub 2} evolved during subsequent calcination was consistent with an extent of carbonation of approximately 49%. Following successful testing of SBC{number_sign}3 sorbent at RTI reported in the last quarter, a two cycle fluidized bed reactor test was conducted with trona as the sorbent precursor, which was calcined to sodium carbonate. In the first

  11. Synthesis of dimethyl carbonate in supercritical carbon dioxide

    Directory of Open Access Journals (Sweden)

    D. Ballivet-Tkatchenko

    2006-03-01

    Full Text Available The reactivity of carbon dioxide with methanol to form dimethyl carbonate was studied in the presence of the n-butylmethoxytin compounds n-Bu3SnOCH3, n-Bu2Sn(OCH32 , and [n-Bu2(CH3OSn]2 O. The reaction occurred under solventless conditions at 423 K and was produced by an increase in CO2 pressure. This beneficial effect is primarily attributed to phase behavior. The mass transfer under liquid-vapor biphasic conditions was not limiting when the system reached the supercritical state for a CO2 pressure higher than 16 MPa. Under these conditions, CO2 acted as a reactant and a solvent.

  12. Membranes for separation of carbon dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Ku, Anthony Yu-Chung (Rexford, NY); Ruud, James Anthony (Delmar, NY); Ramaswamy, Vidya (Niskayuna, NY); Willson, Patrick Daniel (Latham, NY); Gao, Yan (Niskayuna, NY)

    2011-03-01

    Methods for separating carbon dioxide from a fluid stream at a temperature higher than about 200.degree. C. with selectivity higher than Knudsen diffusion selectivity include contacting a porous membrane with the fluid stream to preferentially transport carbon dioxide. The porous membrane includes a porous support and a continuous porous separation layer disposed on a surface of the porous support and extending between the fluid stream and the porous support layer. The porous support comprises alumina, silica, zirconia, stabilized zirconia, stainless steel, titanium, nickel-based alloys, aluminum-based alloys, zirconium-based alloys or a combination thereof. Median pore size of the porous separation layer is less than about 10 nm, and the porous separation layer comprises titania, MgO, CaO, SrO, BaO, La.sub.2O.sub.3, CeO.sub.2, HfO.sub.2, Y.sub.2O.sub.3, VO.sub.z, NbO.sub.z, TaO.sub.z, ATiO.sub.3, AZrO.sub.3, AAl.sub.2O.sub.4, A.sup.1FeO.sub.3, A.sup.1MnO.sub.3, A.sup.1CoO.sub.3, A.sup.1NiO.sub.3, A.sup.2HfO.sub.3, A.sup.3 CeO.sub.3, Li.sub.2ZrO.sub.3, Li.sub.2SiO.sub.3, Li.sub.2TiO.sub.3, Li.sub.2HfO.sub.3, A.sup.4N.sup.1.sub.yO.sub.z, Y.sub.xN.sup.1.sub.yO.sub.z, La.sub.xN.sup.1.sub.yO.sub.z, HfN.sup.2.sub.yO.sub.z, or a combination thereof; wherein A is La, Mg, Ca, Sr or Ba; A.sup.1 is La, Ca, Sr or Ba; A.sup.2 is Ca, Sr or Ba; A.sup.3 is Sr or Ba; A.sup.4 is Mg, Ca, Sr, Ba, Ti or Zr; N.sup.1 is V, Nb, Ta, Cr, Mo, W, Mn, Si or Ge; N.sup.2 is V, Mo, W or Si; x is 1 or 2; y ranges from 1 to 3; and z ranges from 2 to 7.

  13. Atmospheric carbon dioxide: its role in maintaining phytoplankton standing crops

    Energy Technology Data Exchange (ETDEWEB)

    Schindler, D.W.; Brunskill, G.J.; Emerson, S.; Broecker, W.S.; Peng, T.H.

    1972-01-01

    The rate of invasion of carbon dioxide into an artificially eutrophic Canadian Shield Lake with insuffient internal sources of carbon was determined by two methods: Measuring the carbon:nitrogen:phosphorus ratios of seston after weekly additions of nitrogen and phosphorus, and measuring the loss of radon-/sup 222/ tracer from the epilimnion. Both methods gave an invasion rate of about 0.2 gram of carbon per square meter per day. The results demonstrate that invasion of atmospheric carbon dioxide may be sufficient to permit eutrophication of any body of water receiving an adequate supply of phosphorus and nitrogen.

  14. Elements of Design Consideration of Once-Through Cycle, Supercritical-Pressure Light Water Cooled Reactor

    International Nuclear Information System (INIS)

    The paper describes elements of design consideration of supercritical-pressure, light water cooled reactors as well as the status and prospects of the research and development. It summarizes the results of the conceptual design study at the University of Tokyo from 1989. The research and development started in Japan, Europe and USA. The major advantages of the reactors are 1. Compact reactor and turbines due to high specific enthalpy of supercritical water 2.Simple plant system because of the once-through coolant cycle 3.Use of the experience of LWR and fossil-fired power plants. The temperatures of the major components such as reactor pressure vessel, coolant pipes, pumps and turbines are within the experience, in spite of the high outlet coolant temperature. 4.Similarity to LWR safety design and criteria, but no burnout phenomenon 5.Potential cost reduction due to smaller material expenditure and short construction period 6.The smallest reactor not in power rating, but in plant sizes. 7.High-thermal efficiency and low coolant flow rate because of high enthalpy rise. 8.Water cooled reactors potentially free from SCC (stress corrosion cracking) problems. 9.Compatibility of tight-fuel-lattice fast reactor core due to small coolant flow rate, potentially easy shift to fast breeder reactor without changing coolant technology. 10.Potential of producing energy products such as hydrogen and high quality hydro carbons. (authors)

  15. Cooling of concrete structure in advanced heavy water reactor

    International Nuclear Information System (INIS)

    Innovative nuclear power plants are being designed by incorporation of passive systems to the extent possible for enhancing the safety by elimination of active components. BARC has designed Advanced Heavy Water Reactor (AHWR) incorporating several passive systems to facilitate the fulfillment of safety functions of the reactor during normal operation, residual heat removal, emergency core cooling, confinement of radioactivity etc. In addition to these passive systems, an innovative passive technology is being developed to protect, the concrete structure in high temperature zone (V1-volume). Passive Concrete Cooling System (PConCS) uses the principle of natural circulation to provide cooling outside the insulation cabinet encompassing high temperature piping. Cooling water is circulated from overhead GDWP in cooling pipes fixed over corrugated plate on outer surface of insulation cabinet and maintains low temperature of concrete structure. Modular construction of insulation cabinet and cooling pipes external to the concrete surface simplifies the design, construction and refurbishment if required. The paper describes the details of passive technology for concrete cooling. (author)

  16. Carbon Dioxide in Exoplanetary Atmospheres: Rarely Dominant Compared to Carbon Monoxide and Water

    CERN Document Server

    Heng, Kevin

    2015-01-01

    We present a comprehensive study of the abundance of carbon dioxide in exoplanetary atmospheres. We construct analytical models of systems in chemical equilibrium that include carbon monoxide, carbon dioxide, water, methane and acetylene and relate the equilibrium constants of the chemical reactions to temperature and pressure via the tabulated Gibbs free energies. We prove that such chemical systems may be described by a quintic equation for the mixing ratio of methane. By examining the abundances of these molecules across a broad range of temperatures (spanning equilibrium temperatures from 600 to 2500 K), pressures (via temperature-pressure profiles that explore albedo and opacity variations) and carbon-to-oxygen ratios (from 0.1 to 100), we conclude that carbon dioxide is subdominant compared to carbon monoxide and water. Atmospheric mixing does not alter this conclusion if carbon dioxide is subdominant everywhere in the atmosphere. Carbon dioxide and carbon monoxide may attain comparable abundances if th...

  17. Gamma spectroscopy in water cooled reactors

    International Nuclear Information System (INIS)

    Gamma spectroscopy analysis of spent fuels in power reactors; study of two typical cases: determination of the power distribution by the mean of the activity of a low periodic element (Lanthanum 140) and determination of the burnup absolute rate by examining the ratio of Cesium 134 and Cesium 137 activities. Measures were realized on fuel solutions and on fuel assemblies. Development of a power distribution map of the assemblies and comparison with the results of a three dimensional calculation of core evolution

  18. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Aines, Roger D.; Bourcier, William L.

    2014-08-19

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  19. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    Science.gov (United States)

    Aines, Roger D.; Bourcier, William L.

    2010-11-09

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  20. Past explosive outbursts of entrapped carbon dioxide in salt mines provide a new perspective on the hazards of carbon dioxide

    DEFF Research Database (Denmark)

    Hedlund, Frank Huess

    2013-01-01

    This paper reports on a source of past carbon dioxide accidents which so far has only been sporadically mentioned in the literature. Violent and highly destructive outbursts of hundreds of tons of CO2 occurred regularly, if not routinely, in the now closed salt mines of the former DDR. The...... Menzengraben mine experienced an extreme outburst in 1953, possibly involving a several thousand tons of carbon dioxide. This source of accidents fills an important gap in the available carbon dioxide accident history and may provide a unique empirical perspective on the hazards of handling very large amounts...

  1. A district heating system as a sink for carbon dioxide

    International Nuclear Information System (INIS)

    Within a strategy of carbn dioxide (CO2) abatement, district heating systems, driven by small nuclear heating reactors, could be used not only to deliver sensible heat to the consumers, but also as a CO2-absorber/desorber system for the collection of diffusively scattered CO2-sources. For this, potassium carbonate (K2CO3) is dissolved in the heating system which converts into potassium bicarbonate (KHCO3) when CO2 from flue gases is absorbed. At the heating reactor CO2 is desorbed and disposed of. Hence, a district heating system could work as a 'CO2-collecting system', too. Using this additional feature of a district heating system, its so-called effective, climate-related, CO2-neutrality factor is increased by almost a factor of three compared with the direct substitution effect of the CO2-free nuclear heating energy alone. Such a hybrid system could be of interest in a transitional phase when nuclear district heating energy will penetrate into a yet fossil-fuelled heating market. (orig.)

  2. 49 CFR 195.4 - Compatibility necessary for transportation of hazardous liquids or carbon dioxide.

    Science.gov (United States)

    2010-10-01

    ... hazardous liquids or carbon dioxide. 195.4 Section 195.4 Transportation Other Regulations Relating to... necessary for transportation of hazardous liquids or carbon dioxide. No person may transport any hazardous liquid or carbon dioxide unless the hazardous liquid or carbon dioxide is chemically compatible with...

  3. 75 FR 75059 - Mandatory Reporting of Greenhouse Gases: Injection and Geologic Sequestration of Carbon Dioxide

    Science.gov (United States)

    2010-12-01

    ... Sequestration of Carbon Dioxide; Final Rule #0;#0;Federal Register / Vol. 75 , No. 230 / Wednesday, December 1... sequestration of carbon dioxide and all other facilities that conduct injection of carbon dioxide. This rule... may determine''). These regulations will affect owners or operators of carbon dioxide (CO...

  4. Amazon river carbon dioxide outgassing fuelled by wetlands

    OpenAIRE

    Abril, G.; Martinez, J M; Artigas, L.F.; Moreira-Turcq, P.; Benedetti, M. F.; Vidal, L.; Meziane, T.; Kim, J. -H.; Bernardes, M. C.; Savoye, N.; Deborde, J; Souza, E.L.; Alberic, P; de Souza, M.F.L.; Roland, F.

    2014-01-01

    River systems connect the terrestrial biosphere, the atmosphere and the ocean in the global carbon cycle(1). A recent estimate suggests that up to 3 petagrams of carbon per year could be emitted as carbon dioxide (CO2) from global inland waters, offsetting the carbon uptake by terrestrial ecosystems(2). It is generally assumed that inland waters emit carbon that has been previously fixed upstream by land plant photosynthesis, then transferred to soils, and subsequently transported downstream ...

  5. Precision remote sensor for oxygen and carbon dioxide Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Mesa Photonics proposes development of a passive optical sensor for simultaneous high-precision measurement of oxygen and carbon dioxide profiles within the full...

  6. Monthly Carbon Dioxide in Troposphere (AIRS on AQUA)

    Data.gov (United States)

    National Aeronautics and Space Administration — Carbon dioxide (CO2) is an important greenhouse gas released through natural processes such as respiration and volcano eruptions and through huma activities such as...

  7. Miniature Carbon Dioxide Sensor for Small Unmanned Aircraft Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — There is a growing need to develop improved technologies for precise airborne measurements of carbon dioxide, CO2. CO2 measurements are of great importance to many...

  8. Carbon dioxide and nitrous oxide in the North Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    DileepKumar, M.; Naqvi, S.W.A.; Jayakumar, D.A.; George, M.D.; Narvekar, P.V.; DeSousa, S.N.

    The understanding of biogeochemical cycling of carbon dioxide and nitrous oxide in the oceans is essential for predicting the fate of anthropogenically emitted components. The North Indian Ocean, with its diverse regimes, provides us with a natural...

  9. Use of the electrosurgical unit in a carbon dioxide atmosphere.

    Science.gov (United States)

    Culp, William C; Kimbrough, Bradly A; Luna, Sarah; Maguddayao, Aris J; Eidson, Jack L; Paolino, David V

    2016-01-01

    The electrosurgical unit (ESU) utilizes an electrical discharge to cut and coagulate tissue and is often held above the surgical site, causing a spark to form. The voltage at which the spark is created, termed the breakdown voltage, is governed by the surrounding gaseous environment. Surgeons are now utilizing the ESU laparoscopically with carbon dioxide insufflation, potentially altering ESU operating characteristics. This study examines the clinical implications of altering gas composition by measuring the spark gap distance as a marker of breakdown voltage and use of the ESU on a biologic model, both in room air and carbon dioxide. Paschen's Law predicted a 35% decrease in gap distance in carbon dioxide, while testing revealed an average drop of 37-47% as compared to air. However, surgical model testing revealed no perceivable clinical difference. Electrosurgery can be performed in carbon dioxide environments, although surgeons should be aware of potentially altered ESU performance. PMID:26745650

  10. Energy costs of carbon dioxide concentrating mechanisms in aquatic organisms

    Czech Academy of Sciences Publication Activity Database

    Raven, John A.; Beardall, J.; Giordano, Mario

    2014-01-01

    Roč. 121, 2-3 (2014), s. 111-124. ISSN 0166-8595 Institutional support: RVO:61388971 Keywords : carbon dioxide * environmental change * radiation Subject RIV: EE - Microbiology, Virology Impact factor: 3.502, year: 2014

  11. Miniature Carbon Dioxide Sensor for Small Unmanned Aircraft Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Phase 1 has seen the development of a revolutionary new type of sensor for making carbon dioxide (CO2) measurements from small Unmanned Aircraft Systems (UAS) and...

  12. System design study of a membrane reforming hydrogen production plant using a small sized sodium cooled reactor

    International Nuclear Information System (INIS)

    In this study, a membrane reforming hydrogen production plant using a small sized sodium cooled reactor was designed as one of promising concepts. In the membrane reformer, methane and steam are reformed into carbon dioxide and hydrogen with sodium heat at a temperature 500 deg-C. In the equilibrium condition, steam reforming proceeds with catalyst at a temperature more than 800 deg-C. Using membrane reformers, the steam reforming temperature can be decreased from 800 to 500 deg-C because the hydrogen separation membrane removes hydrogen selectively from catalyst area and the partial pressure of hydrogen is kept much lower than equilibrium condition. In this study, a hydrogen and electric co-production plant has been designed. The reactor thermal output is 375 MW and 25% of the thermal output is used for hydrogen production (70000 Nm3/h). The hydrogen production cost is estimated to 21 yen/Nm3 but it is still higher than the economical goal (17 yen/Nm3). The major reason of the high cost comes from the large size of hydrogen separation reformers because of the limit of hydrogen separation efficiency of palladium membrane. A new highly efficient hydrogen separation membrane is needed to reduce the cost of hydrogen production using membrane reformers. There is possibility of multi-tube failure in the membrane reformers. In future study, a design of measures against tube failure and elemental experiments of reaction between sodium and reforming gas will be needed. (authors)

  13. Effects of carbon dioxide on laryngeal receptors

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, J.W.; Sant' Ambrogio, F.B.; Orani, G.P.; Sant' Ambrogio, G.; Mathew, O.P. (Univ. of Texas, Galveston (United States))

    1990-02-26

    Carbon dioxide (CO{sub 2}) either stimulates or inhibits laryngeal receptors in the cat. The aim of this study was to correlate the CO{sub 2} response of laryngeal receptors with their response to other known stimuli (i.e. pressure, movement, cold, water and smoke). Single unit action potentials were recorded from fibers in the superior laryngeal nerve of 5 anesthetized, spontaneously breathing dogs together with CO{sub 2} concentration, esophageal and subglottic pressure. Constant streams of warm, humidified air or 10% CO{sub 2} in O{sub 2} were passed through the functionally isolated upper airway for 60 s. Eight of 13 randomly firing or silent receptors were stimulated by CO{sub 2} (from 0.4{plus minus}0.1 to 1.8{plus minus}0.4 imp.s). These non-respiratory-modulated receptors were more strongly stimulated by solutions lacking Cl{sup {minus}} and/or cigarette smoke. Six of 21 respiratory modulated receptors (responding to pressure and/or laryngeal motion) were either inhibited or stimulated by CO{sub 2}. Our results show that no laryngeal receptor responds only to CO{sub 2}. Silent or randomly active receptors were stimulated most often by CO{sub 2} consistent with the reflex effect of CO{sub 2} in the larynx.

  14. Carbon dioxide removal in gas treating processes

    Energy Technology Data Exchange (ETDEWEB)

    Lidal, H.

    1992-06-01

    The main contribution of this work is the development of a simple and reliable modelling technique on carbon dioxide removal describing the vapor-liquid equilibria of CO{sub 2} in aqueous alkanolamine solutions. By making use of measured pH data, the author has circumvented the problem of estimating interaction parameters, activity coefficients, and equilibrium constants in the prediction of vapor-liquid equilibria. The applicability of the model is best demonstrated on the tertiary amine system using MDEA. For this system, the VLE is accurately represented for temperatures in the range 25 to 140{sup o}C, for CO{sub 2} loadings from 0.001 to 1 mol/mol, and for amine molarities usually encountered in acid gas treating processes. The absorption of CO{sub 2} into solutions containing the sterically hindered amine AMP, is also well described by the model. The equilibrium of CO{sub 2} in mixed solvents containing a glycol (TEG,DEG) and an alkonolamine (MEA,DEA) has been measured at temperatures encountered in the absorption units. An equilibrium model has been developed for the CO{sub 2}/TEG/MEA system for estimation of CO{sub 2} partial pressures, covering loadings and temperatures for both absorption and desorption conditions. An important spin-off of the work described is that two new experimental set-ups have been designed and built. 154 refs., 38 figs., 22 tabs.

  15. Carbon dioxide removal in gas treating processes

    International Nuclear Information System (INIS)

    The main contribution of this work is the development of a simple and reliable modelling technique on carbon dioxide removal describing the vapor-liquid equilibria of CO2 in aqueous alkanolamine solutions. By making use of measured pH data, the author has circumvented the problem of estimating interaction parameters, activity coefficients, and equilibrium constants in the prediction of vapor-liquid equilibria. The applicability of the model is best demonstrated on the tertiary amine system using MDEA. For this system, the VLE is accurately represented for temperatures in the range 25 to 140oC, for CO2 loadings from 0.001 to 1 mol/mol, and for amine molarities usually encountered in acid gas treating processes. The absorption of CO2 into solutions containing the sterically hindered amine AMP, is also well described by the model. The equilibrium of CO2 in mixed solvents containing a glycol (TEG,DEG) and an alkonolamine (MEA,DEA) has been measured at temperatures encountered in the absorption units. An equilibrium model has been developed for the CO2/TEG/MEA system for estimation of CO2 partial pressures, covering loadings and temperatures for both absorption and desorption conditions. An important spin-off of the work described is that two new experimental set-ups have been designed and built. 154 refs., 38 figs., 22 tabs

  16. Low-temperature data for carbon dioxide

    CERN Document Server

    Azreg-Aïnou, Mustapha

    2014-01-01

    We investigate the empirical data for the vapor pressure (154$ \\leq$$T$$\\leq$196 K) and heat capacity (15.52$ \\leq$$T$$\\leq$189.78 K) of the solid carbon dioxide. The approach is both theoretical and numerical, using a computer algebra system (CAS). From the latter point of view, we have adopted a cubic piecewise polynomial representation for the heat capacity and reached an excellent agreement between the available empirical data and the evaluated one. Furthermore, we have obtained values for the vapor pressure and heat of sublimation at temperatures below 195 right down to 0 K. The key prerequisites are the: 1) Determination of the heat of sublimation of 26250 J$\\cdot$mol\\textsuperscript{-1} at vanishing temperature and 2) Elaboration of a `linearized' vapor pressure equation that includes all the relevant properties of the gaseous and solid phases. It is shown that: 1) The empirical vapor pressure equation derived by Giauque & Egan remains valid below the assumed lower limit of 154 K (similar argument ...

  17. Euthanasia of neonatal mice with carbon dioxide

    Science.gov (United States)

    Pritchett, K.; Corrow, D.; Stockwell, J.; Smith, A.

    2005-01-01

    Exposure to carbon dioxide (CO2) is the most prevalent method used to euthanize rodents in biomedical research. The purpose of this study was to determine the time of CO2 exposure required to euthanize neonatal mice (0 to 10 days old). Multiple groups of mice were exposed to 100% CO 2 for time periods between 5 and 60 min. Mice were placed in room air for 10 or 20 min after CO2 exposure, to allow for the chance of recovery. If mice recovered at one time point, a longer exposure was examined. Inbred and outbred mice were compared. Results of the study indicated that time to death varied with the age of the animals and could be as long as 50 min on the day of birth and differed between inbred and outbred mice. Institutions euthanizing neonatal mice with CO2 may wish to adjust their CO 2 exposure time periods according the age of the mice and their genetic background. Copyright 2005 by the American Association for Laboratory Animal Science.

  18. Carbon Dioxide Angiography: Scientific Principles and Practice.

    Science.gov (United States)

    Cho, Kyung Jae

    2015-09-01

    Carbon dioxide (CO2) is a colorless, odorless gas which occurs naturally in the atmosphere and human body. With the advent of digital subtraction angiography, the gas has been used as a safe and useful alternative contrast agent in both arteriography and venography. Because of its lack of renal toxicity and allergic potential, CO2 is a preferred contrast agent in patients with renal failure or contrast allergy, and particularly in patients who require large volumes of contrast medium for complex endovascular procedures. Understanding of the unique physical properties of CO2 (high solubility, low viscosity, buoyancy, and compressibility) is essential in obtaining a successful CO2 angiogram and in guiding endovascular intervention. Unlike iodinated contrast material, CO2 displaces the blood and produces a negative contrast for digital subtraction imaging. Indications for use of CO2 as a contrast agent include: aortography and runoff, detection of bleeding, renal transplant arteriography, portal vein visualization with wedged hepatic venous injection, venography, arterial and venous interventions, and endovascular aneurysm repair. CO2 should not be used in the thoracic aorta, the coronary artery, and cerebral circulation. Exploitation of CO2 properties, avoidance of air contamination and facile catheterization technique are important to the safe and effective performance of CO2 angiography and CO2-guided endovascular intervention. PMID:26509137

  19. Carbon dioxide balneotherapy and cardiovascular disease

    Science.gov (United States)

    Pagourelias, Efstathios D.; Zorou, Paraskevi G.; Tsaligopoulos, Miltiadis; Athyros, Vasilis G.; Karagiannis, Asterios; Efthimiadis, Georgios K.

    2011-09-01

    Carbon dioxide (CO2) balneotherapy is a kind of remedy with a wide spectrum of applications which have been used since the Middle Ages. However, its potential use as an adjuvant therapeutic option in patients with cardiovascular disease is not yet fully clarified. We performed a thorough review of MEDLINE Database, EMBASE, ISI WEB of Knowledge, COCHRANE database and sites funded by balneotherapy centers across Europe in order to recognize relevant studies and aggregate evidence supporting the use of CO2 baths in various cardiovascular diseases. The three main effects of CO2 hydrotherapy during whole body or partial immersion, including decline in core temperature, an increase in cutaneous blood flow, and an elevation of the score on thermal sensation, are analyzed on a pathophysiology basis. Additionally, the indications and contra-indications of the method are presented in an evidence-based way, while the need for new methodologically sufficient studies examining the use of CO2 baths in other cardiovascular substrates is discussed.

  20. Emergency core cooling during an SRS reactor LOPA

    International Nuclear Information System (INIS)

    The loss-of-pumping accident (LOPA) is a Savannah River site (SRS) reactor design-basis accident. The most limiting LOPA is caused by a double-ended guillotine break in a secondary cooling system inlet header and is the topic of this discussion. Upon break detection, the reactor scrams and the secondary cooling water pumps and alternating-current (ac) primary pump motors trip off. The direct-current (dc) motors continue to drive the primary pumps at about one-third capacity. Gravity flow through the broken header continues flooding the building after the cooling pumps are off. The emergency cooling system (ECS) is activated prior to flood-out of the dc motors. The design-basis accident reactor power limit ensures the reactor will shut down safely should a LOPA occur. The simulated LOPA has five phases: steady state, ac coastdown, dc flow, dc coastdown, and fully developed ECS flow. Analyses of LOPAs have shown that ECS is the most limiting phase of the accident. This paper concentrates on the role of ECS in LOPA limits

  1. Control rod drive for high temperature gas cooled reactor

    Institute of Scientific and Technical Information of China (English)

    DengJun-Xian; XuJi-Ming; 等

    1998-01-01

    This control rod drive is developed for HTR-10 high temperature gas cooled test reactor.The stepmotor is prefered to improve positioning of the control rod and the scram behavior.The preliminary test in 1600170 ambient temperature shows that the selected stepmotor and transmission system can meet the main operation function requirements of HTR-10.

  2. IAEA activities in Gas-cooled Reactor technology development

    International Nuclear Information System (INIS)

    The International Atomic Energy Agency (IAEA) has the charter to ''foster the exchange of scientific and technical information'', and ''encourage and assist research on, and development and practical application of, atomic energy for peaceful uses throughout the world''. This paper describes the Agency's activities in Gas-cooled Reactor (GCR) technology development

  3. IAEA activities in gas-cooled reactor technology development

    International Nuclear Information System (INIS)

    The International Atomic Energy Agency (IAEA) has the charter to ''foster the exchange of scientific and technical information'', and ''encourage and assist research on, and development and practical application of, atomic energy for peaceful uses throughout the world''. This paper describes the Agency's activities in Gas-cooled Reactor (GCR) technology development

  4. Windscale advanced gas-cooled reactor (WAGR) decommissioning project overview

    International Nuclear Information System (INIS)

    The current BNFL reactor decommissioning projects are presented. The projects concern power reactor sites at Berkely, Trawsfynydd, Hunterstone, Bradwell, Hinkley Point; UKAEA Windscale Pile 1; Research reactors within UK Scottish Universities at East Kilbride and ICI (both complete); WAGR. The BNFL environmental role include contract management; effective dismantling strategy development; implementation and operation; sentencing, encapsulation and transportation of waste. In addition for the own sites it includes strategy development; baseline decommissioning planning; site management and regulator interface. The project objectives for the Windscale Advanced Gas-Cooled Reactor (WAGR) are 1) Safe and efficient decommissioning; 2) Building of good relationships with customer; 3) Completion of reactor decommissioning in 2005. The completed WAGR decommissioning campaigns are: Operational Waste; Hot Box; Loop Tubes; Neutron Shield; Graphite Core and Restrain System; Thermal Shield. The current campaign is Lower Structures and the remaining are: Pressure vessel and Insulation; Thermal Columns and Outer Vault Membrane. An overview of each campaign is presented

  5. Carbon dioxide sequestration by mineral carbonation. Literature Review

    International Nuclear Information System (INIS)

    In order to prevent CO2 concentrations in the atmosphere rising to unacceptable levels, carbon dioxide can be separated from the flue gas of, for example, a power plant and subsequently sequestrated. Various technologies for carbon dioxide sequestration have been proposed, such as storage in depleted gas fields, oceans and aquifers. An alternative sequestration route is the so-called 'mineral CO2 sequestration' route in which CO2 is chemically stored in solid carbonates by the carbonation of minerals. As mineral feedstock, rocks that are rich in alkaline earth silicates can be used. Examples are olivine (MgSiO4) and wollastonite (CaSiO3). Mineral CO2 sequestration has some fundamental advantages compared to other sequestration routes. The formed products are thermodynamically stable and therefore the sequestration of CO2 is permanent and safe. Furthermore, the sequestration capacity is large because large suitable feedstock deposits are available worldwide. Finally, the carbonation reactions are exothermic and occur spontaneously in nature. The reaction rates of the process at atmospheric conditions, however, are much too slow for an industrial process. Therefore, research focuses on increasing the reaction rate in order to obtain an industrial viable process. Optimisation of the process conditions is constrained by the thermodynamics of the process. Increasing the temperature and CO2 pressure accelerates the reaction rate, but gaseous CO2 is favoured over mineral carbonates at high temperatures. Using water or another solvent to extract the reactive component from the matrix accelerates the process. Pre-treatment of the mineral by size reduction and thermal or mechanical activation and optimisation of the solution chemistry result in major improvements of the reaction rate. During recent years, laboratory-scale experiments have shown major improvements of the conversion rates by developing various process routes and optimising process conditions. The most

  6. Economic Growth, Carbon Dioxide Emissions, Renewable Energy and Globalization

    OpenAIRE

    Nuno Carlos LEITÃO

    2014-01-01

    This article investigates the correlation between economic growth, carbon dioxide emissions, renewable energy and globalization for the period 1970-2010, using time series (OLS,GMM, unit root test, VEC model, and Granger causality) to Portuguese economy. OLS estimator and GMM model demonstrate that carbon dioxide emissions and renewable energy are positively correlated with economic growth. The econometric models also show that the overall index of globalization has a positive effect...

  7. A simple, disposable end-tidal carbon dioxide detector.

    OpenAIRE

    Rosenberg, M; Block, C. S.

    1991-01-01

    Detection of expired carbon dioxide is one of the most reliable methods of avoiding accidental esophageal intubation. Although capnography has become a standard monitoring technique in the hospital operating room, it is rarely available in the office setting or other arenas where emergency endotracheal intubation may be required. A new and inexpensive device, however, has been developed for assessing end-tidal carbon dioxide. This semi-quantitative detector fits between the endotracheal tube ...

  8. Seawater pH and Anthropogenic Carbon Dioxide

    CERN Document Server

    Marsh, Gerald E

    2008-01-01

    In 2005, the Royal Society published a report titled "Ocean acidification due to increasing atmospheric carbon dioxide". The report's principal conclusion-that average ocean pH could decrease by 0.5 units by 2100-is demonstrated here to be consistent with a linear extrapolation of very limited data. It is also shown that current understanding of ocean mixing, and of the relationship between pH and atmospheric carbon dioxide concentration, cannot justify such an extrapolation.

  9. Carbon dioxide capture by means of cyclic organic nitrogen compounds

    OpenAIRE

    García Abuín, Alicia

    2012-01-01

    The research work included in present PhD Thesis involves the research studies to capture carbon dioxide using different cyclic nitrogen organic compounds (glucosamine (GA), chitosan (C), alkyl-pyrrolidones, pyrrolidine (PYR) and piperidine (PIP). This investigation is based on the study of three experimental systems. Each of them has characteristics potentially suitable to achieve the aim of this work, that is to say, to improve the carbon dioxide capture process, which is pre...

  10. Proceedings of 'workshop on Pb-alloy cooled fast reactor'

    International Nuclear Information System (INIS)

    The objective of 'Workshop on Pb-Alloy Cooled Fast Reactor', held in Taejeon, Korea on May 6, 2003, is to enhance the basic knowledge in this area by facilitating the exchange of information and discussions about problematic area of design aspects. There were five presentations from three different countries and about 25 participants gathered during the workshop. The topics covered in the workshop include benefits and drawbacks of Pb-alloy and Sodium coolant, two Pb-alloy cooled 900 MWt reactor designs using both B4C rods and NSTs, BREST-300 breakeven reactor and transmutation effectiveness of LLFPs in the typical thermal/fast neutron systems. The generic conclusion for the Pb-alloy cooled fast reactor from this workshop is as follows: 1) It has a potential to satisfy the goals established for the Generation-IV reactor concepts, so it has a bright future. 2) As a fast neutron system with a moderate breeding or a conversion, it is flexible in its roles and has superior safety characteristics over sodium coolant because of Pb-alloy's chemical inertness with water/air and high boiling temperature

  11. Radiolytic reactions in the coolant of helium cooled reactors

    International Nuclear Information System (INIS)

    The success of helium cooled reactors is dependent upon the ability to prevent significant reaction between the coolant and the other components in the reactor primary circuit. Since the thermal reaction of graphite with oxidizing gases is rapid at temperatures of interest, the thermal reactions are limited primarily by the concentration of impurity gases in the helium coolant. On the other hand, the rates of radiolytic reactions in helium are shown to be independent of reactive gas concentration until that concentration reaches a very low level. Calculated steady-state concentrations of reactive species in the reactor coolant and core burnoff rates are presented for current U. S. designed, helium cooled reactors. Since precise base data are not currently available for radiolytic rates of some reactions and thermal reaction rate data are often variable, the accuracy of the predicted gas composition is being compared with the actual gas compositions measured during startup tests of the Fort Saint Vrain high temperature gas-cooled reactor. The current status of these confirmatory tests is discussed. 12 references

  12. Consequences of reactor fuel damage: - Production of radioactive wastes. - Radioactivity in the reactor cooling system

    International Nuclear Information System (INIS)

    The report describes the consequences of damage of reactor fuel cladding. The types of damage and the release of fission products into the reactor cooling system are described as well as detection methods. The report also gives suggestions to reduce the consequences of a damage. (62 figs., 13 tabs.)

  13. Mycorrhizal mediation of soil organic carbon decomposition under elevated atmospheric carbon dioxide

    Science.gov (United States)

    Significant effort in global change research has recently been directed towards assessing the potential of soil as a carbon sink under future atmospheric carbon dioxide scenarios. Attention has focused on the impact of elevated carbon dioxide on plant interactions with mycorrhizae, a symbiotic soil...

  14. Beneficial Use of Carbon Dioxide in Precast Concrete Production

    Energy Technology Data Exchange (ETDEWEB)

    Shao, Yixin [McGill Univ., Montreal, QC (Canada)

    2014-06-26

    The feasibility of using carbon dioxide as feedstock in precast concrete production is studied. Carbon dioxide reacts with calcium compounds in concrete, producing solid calcium carbonates in binding matrix. Two typical precast products are examined for their capacity to store carbon dioxide during the production. They are concrete blocks and fiber-cement panels. The two products are currently mass produced and cured by steam. Carbon dioxide can be used to replace steam in curing process to accelerate early strength, improve the long-term durability and reduce energy and emission. For a reaction within a 24-hour process window, the theoretical maximum possible carbon uptake in concrete is found to be 29% based on cement mass in the product. To reach the maximum uptake, a special process is developed to promote the reaction efficiency to 60-80% in 4-hour carbon dioxide curing and improve the resistance to freeze-thaw cycling and sulfate ion attack. The process is also optimized to meet the project target of $10/tCO2 in carbon utilization. By the use of self-concentrating absorption technology, high purity CO2 can be produced at a price below $40/t. With low cost CO2 capture and utilization technologies, it is feasible to establish a network for carbon capture and utilization at the vicinity of carbon sources. If all block produces and panel producers in United States could adopt carbon dioxide process in their production in place of steam, carbon utilization in these two markets alone could consume more than 2 Mt CO2/year. This capture and utilization process can be extended to more precast products and will continue for years to come.

  15. Balancing passive and active systems for evolutionary water cooled reactors

    International Nuclear Information System (INIS)

    Advanced concepts of the water-cooled reactors are intended to improve safety, economics and public perception of nuclear power. The potential inclusion of new passive means in addition or instead of traditional active systems is being considered by nuclear plant designers to reach these goals. With respect to plant safety, application of the passive means is mainly intended to simplify the safety systems and to improve their reliability, to mitigate the effect of human errors and equipment malfunction. However, some clear drawbacks and the limited experience and testing of passive systems may raise additional questions that have to be addressed in the design process for each advanced reactor. Therefore the plant designer should find a reasonable balance of active and passive means to effectively use their advantages and compensate their drawbacks. Some considerations that have to be taken into account when balancing active/passive means in advanced water-cooled reactors are discussed in this paper. (author)

  16. Medium-size high-temperature gas-cooled reactor

    International Nuclear Information System (INIS)

    This report summarizes high-temperature gas-cooled reactor (HTGR) experience for the 40-MW(e) Peach Bottom Nuclear Generating Station of Philadelphia Electric Company and the 330-MW(e) Fort St. Vrain Nuclear Generating Station of the Public Service Company of Colorado. Both reactors are graphite moderated and helium cooled, operating at approx. 7600C (14000F) and using the uranium/thorium fuel cycle. The plants have demonstrated the inherent safety characteristics, the low activation of components, and the high efficiency associated with the HTGR concept. This experience has been translated into the conceptual design of a medium-sized 1170-MW(t) HTGR for generation of 450 MW of electric power. The concept incorporates inherent HTGR safety characteristics [a multiply redundant prestressed concrete reactor vessel (PCRV), a graphite core, and an inert single-phase coolant] and engineered safety features

  17. Phase equilibrium condition of marine carbon dioxide hydrate

    International Nuclear Information System (INIS)

    Highlights: ► CO2 hydrate phase equilibrium was studied in simulated marine sediments. ► CO2 hydrate equilibrium temperature in NaCl and submarine pore water was depressed. ► Coarse-grained silica sand does not affect CO2 hydrate phase equilibrium. ► The relationship between equilibrium temperature and freezing point was discussed. - Abstract: The phase equilibrium of ocean carbon dioxide hydrate should be understood for ocean storage of carbon dioxide. In this paper, the isochoric multi-step heating dissociation method was employed to investigate the phase equilibrium of carbon dioxide hydrate in a variety of systems (NaCl solution, submarine pore water, silica sand + NaCl solution mixture). The experimental results show that the depression in the phase equilibrium temperature of carbon dioxide hydrate in NaCl solution is caused mainly by Cl− ion. The relationship between the equilibrium temperature and freezing point in NaCl solution was discussed. The phase equilibrium temperature of carbon dioxide hydrate in submarine pore water is shifted by −1.1 K to lower temperature region than that in pure water. However, the phase equilibrium temperature of carbon dioxide hydrate in mixture samples of coarsed-grained silica sand and NaCl solution is in agreement with that in NaCl solution with corresponding concentrations. The relationship between the equilibrium temperature and freezing point in mixture samples was also discussed.

  18. Carbon Dioxide/Methane Separation by Adsorption on Sepiolite

    Institute of Scientific and Technical Information of China (English)

    José A.Delgado; María A.Uguina; José L.Sotelo; Beatriz Ruíz; Marcio Rosário

    2007-01-01

    In this work,the use of sepiolite for the removal of carbon dioxide from a carbon dioxide/methane mixture by a pressure swing adsorption (PSA) process has been researched.Adsorption equilibrium and kinetics have been measured in a fixed-bed.and the adsorption equilibrium parameters of carbon dioxide and methane on sepiolite have been obtained.A model based on the LDF approximation has been employed to simulate the fixed-bed kinetics.using the Langmuir equation to describe the adsotption equilibrium isotherm.The functioning of a PSA cycle for separating carbon dioxide/methane mixtures using sepiolite as adsorbent has also been studied.The experimental results were compared with the ones predicted by the model adapted to a PSA system.Methane with purity higher than 97% can be obtained from feeds containing carbon dioxide with concentrations ranging from 34% to 56% with the proposed PSA cycle.These results suggest that sepiolite is an adsorbent with good properties for its employment in a PSA cycle for carbon dioxide removal from landfill gases.

  19. Status report on the Small Secure Transportable Autonomous Reactor (SSTAR); Lead-cooled Fast Reactor (LFR) and supporting research and development

    International Nuclear Information System (INIS)

    This report provides an update on development of a pre-conceptual design for the Small Secure Transportable Autonomous Reactor (SSTAR) Lead-Cooled Fast Reactor (LFR) plant concept and supporting research and development activities. SSTAR is a small, 20 MWe (45 MWt), natural circulation, fast reactor plant for international deployment concept incorporating proliferation resistance for deployment in non-fuel cycle states and developing nations, fissile self-sufficiency for efficient utilization of uranium resources, autonomous load following making it suitable for small or immature grid applications, and a high degree of passive safety further supporting deployment in developing nations. In FY 2006, improvements have been made at ANL to the pre-conceptual design of both the reactor system and the energy converter which incorporates a supercritical carbon dioxide Brayton cycle providing higher plant efficiency (44 %) and improved economic competitiveness. The supercritical CO2 Brayton cycle technology is also applicable to Sodium-Cooled Fast Reactors providing the same benefits. One key accomplishment has been the development of a control strategy for automatic control of the supercritical CO2 Brayton cycle in principle enabling autonomous load following over the full power range between nominal and essentially zero power. Under autonomous load following operation, the reactor core power adjusts itself to equal the heat removal from the reactor system to the power converter through the large reactivity feedback of the fast spectrum core without the need for motion of control rods, while the automatic control of the power converter matches the heat removal from the reactor to the grid load. The report includes early calculations for an international benchmarking problem for a LBE-cooled, nitride-fueled fast reactor core organized by the IAEA as part of a Coordinated Research Project on Small Reactors without Onsite Refueling; the calculations use the same neutronics

  20. Status report on the Small Secure Transportable Autonomous Reactor (SSTAR) /Lead-cooled Fast Reactor (LFR) and supporting research and development.

    Energy Technology Data Exchange (ETDEWEB)

    Sienicki, J. J.; Moisseytsev, A.; Yang, W. S.; Wade, D. C.; Nikiforova, A.; Hanania, P.; Ryu, H. J.; Kulesza, K. P.; Kim, S. J.; Halsey, W. G.; Smith, C. F.; Brown, N. W.; Greenspan, E.; de Caro, M.; Li, N.; Hosemann, P.; Zhang, J.; Yu, H.; Nuclear Engineering Division; LLNL; LANL; Massachusetts Inst. of Tech.; Ecole des Mines de Paris; Oregon State Univ.; Univ.of California at Berkley

    2008-06-23

    This report provides an update on development of a pre-conceptual design for the Small Secure Transportable Autonomous Reactor (SSTAR) Lead-Cooled Fast Reactor (LFR) plant concept and supporting research and development activities. SSTAR is a small, 20 MWe (45 MWt), natural circulation, fast reactor plant for international deployment concept incorporating proliferation resistance for deployment in non-fuel cycle states and developing nations, fissile self-sufficiency for efficient utilization of uranium resources, autonomous load following making it suitable for small or immature grid applications, and a high degree of passive safety further supporting deployment in developing nations. In FY 2006, improvements have been made at ANL to the pre-conceptual design of both the reactor system and the energy converter which incorporates a supercritical carbon dioxide Brayton cycle providing higher plant efficiency (44 %) and improved economic competitiveness. The supercritical CO2 Brayton cycle technology is also applicable to Sodium-Cooled Fast Reactors providing the same benefits. One key accomplishment has been the development of a control strategy for automatic control of the supercritical CO2 Brayton cycle in principle enabling autonomous load following over the full power range between nominal and essentially zero power. Under autonomous load following operation, the reactor core power adjusts itself to equal the heat removal from the reactor system to the power converter through the large reactivity feedback of the fast spectrum core without the need for motion of control rods, while the automatic control of the power converter matches the heat removal from the reactor to the grid load. The report includes early calculations for an international benchmarking problem for a LBE-cooled, nitride-fueled fast reactor core organized by the IAEA as part of a Coordinated Research Project on Small Reactors without Onsite Refueling; the calculations use the same neutronics

  1. Investigation of vessel exterior air cooling for a HLMC reactor

    International Nuclear Information System (INIS)

    The Secure Transportable Autonomous Reactor (STAR) concept under development at Argonne National Laboratory provides a small (300 MWt) reactor module for steam supply that incorporates design features to attain proliferation resistance, heightened passive safety, and improved cost competitiveness through extreme simplification. Examples are the achievement of 100%+ natural circulation heat removal from the low power density/low pressure drop ultra-long lifetime core and utilization of lead-bismuth eutectic (LBE) coolant enabling elimination of main coolant pumps as well as the need for an intermediate heat transport circuit. It is required to provide a passive means of removing decay heat and effecting reactor cooldown in the event that the normal steam generator heat sink, including its normal shutdown heat removal mode, is postulated to be unavailable. In the present approach, denoted as the Reactor Exterior Cooling System (RECS), passive decay heat removal is provided by cooling the outside of the containment/guard vessel with air. RECS is similar to the Reactor Vessel Auxiliary Cooling System (RVACS) incorporated into the PRISM design. However, to enhance the heat removal, RECS incorporates fins on the containment vessel exterior to enhance heat transfer to air as well as removable steel venetian conductors that provide a conduction heat transfer path across the reactor vessel-containment vessel gap to enhance heat transfer between the vessels. The objective of the present work is to investigate the effectiveness of air cooling in removing heat from the vessel and limiting the coolant temperature increase following a sudden complete loss of the steam generator heat sink

  2. The role of renewable bioenergy in carbon dioxide sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Kinoshita, C.M. [Hawaii Natural Energy Inst., Honolulu, HI (United States)

    1993-12-31

    The use of renewable resources represents a sound approach to producing clean energy and reducing the dependence on diminishing reserves of fossil fuels. Unfortunately, the widespread interest in renewable energy in the 1970s, spurred by escalating fossil fuel prices, subsided with the collapse of energy prices in the mid 1980s. Today, it is largely to reverse alarming environmental trends, particularly the buildup of atmospheric carbon dioxide, rather than to reduce the cost of energy, that renewable energy resources are being pursued. This discussion focuses on a specific class of renewable energy resources - biomass. Unlike most other classes of renewable energy touted for controlling atmospheric carbon dioxide concentrations, e.g., hydro, direct solar, wind, geothermal, and ocean thermal, which produce usable forms of energy while generating little or no carbon dioxide emissions, bioenergy almost always involves combustion and therefore generates carbon dioxide; however, if used on a sustained basis, bio-energy would not contribute to the build-up of atmospheric carbon dioxide because the amount released in combustion would be balanced by that taken up via photosynthesis. It is in that context, i.e., sustained production of biomass as a modern energy carrier, rather than reforestation for carbon sequestration, that biomass is being discussed here, since biomass can play a much greater role in controlling global warming by displacing fossil fuels than by being used strictly for carbon sequestration (partly because energy crop production can reduce fossil carbon dioxide emissions indefinitely, whereas under the reforestation strategy, carbon dioxide abatement ceases at forest maturity).

  3. Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

    2007-06-30

    Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that

  4. Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction

    Science.gov (United States)

    Kumar, Bijandra; Asadi, Mohammad; Pisasale, Davide; Sinha-Ray, Suman; Rosen, Brian A.; Haasch, Richard; Abiade, Jeremiah; Yarin, Alexander L.; Salehi-Khojin, Amin

    2013-12-01

    The development of an efficient catalyst system for the electrochemical reduction of carbon dioxide into energy-rich products is a major research topic. Here we report the catalytic ability of polyacrylonitrile-based heteroatomic carbon nanofibres for carbon dioxide reduction into carbon monoxide, via a metal-free, renewable and cost-effective route. The carbon nanofibre catalyst exhibits negligible overpotential (0.17 V) for carbon dioxide reduction and more than an order of magnitude higher current density compared with the silver catalyst under similar experimental conditions. The carbon dioxide reduction ability of carbon nanofibres is attributed to the reduced carbons rather than to electronegative nitrogen atoms. The superior performance is credited to the nanofibrillar structure and high binding energy of key intermediates to the carbon nanofibre surfaces. The finding may lead to a new generation of metal-free and non-precious catalysts with much greater efficiency than the existing noble metal catalysts.

  5. High temperature gas-cooled reactors - perspective of thermal reactor concept with high thermal efficiency

    International Nuclear Information System (INIS)

    The present HTR development is based worldwide on the extensive experience gained in the construction and operation of gas-cooled reactors of the Magnox type and on the successful operation of the experimental high temperature reactors Dragon, Peach Bottom and AVR. The advanced CO2-cooled reactors, as well as the HTR prototype power plants for St. Vrain and THTR, are all suffering considerable delays in construction and commissioning. The commercial HTR plants have not yet achieved the decisive breakthrough onto the market. Increasing interest is being shown in advanced HTR systems, i.e., HTR with gas turbine, HTR process heat reactors and gas-cooled fast breeders. The key problem in the coming years will be the closing of the fuel cycle. Development work in this connection has already started. (orig.)

  6. A preliminary assessment of carbon dioxide mitigation options

    International Nuclear Information System (INIS)

    The purpose of this paper is to place the potential needs to control global carbon dioxide emissions in perspective. In order to limit carbon dioxide levels in the earth's atmosphere to no more than twice pre- anthropogenic levels, it will be necessary to limit carbon emissions to approximately 10 gigatons per year by 2050. The implications of such a constraint to the developed countries, developing countries, and international community are assessed. It is clear that international priorities must be established and specific approaches developed in the first quarter of the 21st century to define the necessary, minimum- cost mitigation strategies. Because of the complexity of establishing a meaningful policy approach, imposition of an arbitrary carbon tax is unlikely to provide the constraints necessary to achieve a satisfactory earth atmosphere - carbon dioxide equilibrium state

  7. It is time to put carbon dioxide to work

    Energy Technology Data Exchange (ETDEWEB)

    Lipinsky, E.S. [Battelle, Columbus, OH (United States)

    1993-12-31

    The need to control emissions of carbon dioxide into the atmosphere is the subject of vigorous debate at this time. There is growing evidence that rising levels of carbon dioxide increase global warming, with perhaps highly adverse impacts for the human economy. There are calls for carbon taxes and other harsh measures. Japan has established a national goal of holding carbon dioxide emissions in the year 2000 to 1990 levels. I hope that this conference will be a turning point in the United States position on this issue. The current major end uses for CO{sub 2} include refrigeration, beverage carbonation, soda ash production, fire fighting, and urea fertilizer production. They are all based on chemistry that would not surprise a good chemist of the 19th century. Consumption of carbon dioxide in synthesis of industrial chemicals is limited. Usually one explains low production of chemicals from a candidate feedstock in terms of poor availability, price, purity, or reactivity. We can eliminate the first three as the causes of the underutilization of carbon dioxide.

  8. Critical experiments and reactor physics calculations for low enriched high temperature gas cooled reactors

    International Nuclear Information System (INIS)

    On the recommendation of the IAEA International Working Group on Gas Cooled Reactors, the IAEA established a Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low-Enriched High Temperature Gas Cooled Reactors (HTGRs) in 1990. The objective of the CRP was to provide safety-related physics data for low-enriched uranium (LEU) fueled HTGRs for use in validating reactor physics codes used by the participating countries for analyses of their designs. Experience on low-enriched uranium, graphite-moderated reactor systems from research institutes and critical facilities in participating countries were brought into the CRP and shared among participating institutes. The status of experimental data and code validation for HTGRs and the remaining needs at the initiation of this CRP were addressed in detail at the IAEA Specialists Meeting on Uncertainties in Physics Calculations for HTGR Cores held at the Paul Scherrer Institute (PSI), Villigen, Switzerland in May, 1990. The main activities of the CRP were conducted within an international project at the PROTEUS critical experiment facility at the Paul Scherrer Institute, Villigen, Switzerland. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters. Fuel for the experiments was provided by the KFA Research Center, Juelich, Germany. Initial criticality was achieved on July 7, 1992. These experiments were conducted over a range of experimental parameters such as carbon-to-uranium ratio, core height-to-diameter ratio, and simulated moisture concentration. To assure that the experiments being conducted are appropriate for the design of the participants, specialists from each of the countries have participated

  9. Urban carbon dioxide in Portland, Oregon

    Science.gov (United States)

    Bostrom, G. A.; Brooks, M.; Rice, A. L.

    2010-12-01

    Ambient concentrations of atmospheric carbon dioxide (CO2) are reported for the Portland, Oregon (USA) metropolitan region since late July, 2009. Three stationary locations were established: a downtown location on the campus of Portland State University; a residential site in southeast Portland; and a rural station on Sauvie Island, located ~30km northwest of Portland in the Columbia River Gorge. Continuous measurements of CO2 at the sites average 400-410ppm and show considerable variability due to CO2 sources, sinks and meteorological drivers of ventilation. Within this variability, a marked 20-30ppm diurnal cycle is observed due to photosynthetic activity and variations in the planetary boundary layer. In-city CO2 concentrations are on average enhanced by 5-6ppm over the Sauvie Island site during upgorge wind conditions, a difference which is greatest in the afternoon. Measurements of the 13C/12C ratio of CO2 in downtown Portland are significantly depleted in 13C relative to 12C compared with background air and suggest that regional CO2 is dominated by petroleum sources (70-80%). High degrees of relationship between CO2 variability and primary air pollutants CO and NO (r2=0.70 to 0.80), measured by the Oregon Department of Environmental Quality at the Southeast Portland location, corroborate this finding and illustrate the importance of traffic emissions on elevated ambient CO2 concentrations. In addition to CO2 at the fixed sites, measurements of street-level CO2 concentrations were obtained using a mobile instrument mounted in a bike trailer. Results from these field data show relatively homogenous CO2 concentrations throughout residential Portland neighborhoods with significant enhancements in CO2 on busy roadways or near areas of traffic congestion.

  10. Nuclear power and the carbon dioxide problem

    International Nuclear Information System (INIS)

    This study deals with the question, which contribution can be delivered by nuclear power to the redution of the emission of carbon dioxide (CO2) from the power supply. The emphasis lays upon the following aspects: the emissions of CO2 which occur in the nuclear-power cycle (the so-called indirect emission of CO2 power plants); the amount of uranium stocks; the change of CO2 emission caused by replacement of fossil fuels, in particular coal, by nuclear power. First an energy-analysis of the nuclear power cycle is presented. On the base of this analysis the CO2 uranium can be calculated. The role of nuclear power in the reduction of CO2 emission depends on the development of the final power demand. Therefore in this study two scenarios derived from the 'IIASA-low' scenario; 'low-energy'-scenario in which the world-energy consumption remains at about the same level. In the calculations the indirect emissions of CO2, also dependent on the ore richness and the technology used, have always been taken into account. In the calculations two uranium-reserve variants of resp. 5.7 and 30 mln. tons have been assumed. From the results of the calculations it can be concluded that whether or not taking account of the indirect emissions of CO2 in the nuclear power cycle, has only limited effect on the calculated contribution of nuclear power to the solution of the greenhouse effect. The uranium reserves turn out to be determining for the potential contribution of nuclear power. By putting on the surely available reserve of 5.7 mln. tons, or the speculative reserve of 30 mln. tons, with the actual technology, an emission of resp. 130-140 billion and 880 billion tons CO2 can be avoided in replacing coal. With maximal employment of improved conversion techniques these contributions may be doubled. (H.W.). 40 refs.; 13 figs.; 10 tabs

  11. COMPARISON OF COOLING SCHEMES FOR HIGH HEAT FLUX COMPONENTS COOLING IN FUSION REACTORS

    OpenAIRE

    Phani Kumar Domalapally; Slavomir Entler

    2015-01-01

    Some components of the fusion reactor receives high heat fluxes either during the startup and shutdown or during the operation of the machine. This paper analyzes different ways of enhancing heat transfer using helium and water for cooling of these high heat flux components and then conclusions are drawn to decide the best choice of coolant, for usage in near and long term applications.

  12. Natural Circulation Phenomena and Modelling for Advanced Water Cooled Reactors

    International Nuclear Information System (INIS)

    The role of natural circulation in advanced water cooled reactor design has been extended with the adoption of passive safety systems. Some designs utilize natural circulation to remove core heat during normal operation. Most passive safety systems used in evolutionary and innovative water cooled reactor designs are driven by natural circulation. The use of passive systems based on natural circulation can eliminate the costs associated with the installation, maintenance and operation of active systems that require multiple pumps with independent and redundant electric power supplies. However, considering the weak driving forces of passive systems based on natural circulation, careful design and analysis methods must be employed to ensure that the systems perform their intended functions. Several IAEA Member States with advanced reactor development programmes are actively conducting investigations of natural circulation to support the development of advanced water cooled reactor designs with passive safety systems. To foster international collaboration on the enabling technology of passive systems that utilize natural circulation, in 2004 the IAEA initiated a coordinated research project (CRP) on Natural Circulation Phenomena, Modelling and Reliability of Passive Systems that Utilize Natural Circulation. Three reports were published within the framework of this CRP. The first report (IAEA-TECDOC-1474) contains the material developed for the first IAEA training course on natural circulation in water cooled nuclear power plants. The second report (IAEA-TECDOC-1624) describes passive safety systems in a wide range of advanced water cooled nuclear power plant designs, with the goal of gaining insights into system design, operation and reliability. This third, and last, report summarizes the research studies completed by participating institutes during the CRP period.

  13. Advanced gas cooled nuclear reactor materials evaluation and development program

    Energy Technology Data Exchange (ETDEWEB)

    1977-01-01

    Results of work performed from January 1, 1977 through March 31, 1977 on the Advanced Gas Cooled Nuclear Reactor Materials Evaluation and Development Program are presented. The objectives of this program are to evaluate candidate alloys for Very High Temperature Reactor (VHTR) Process Heat and Direct Cycle Helium Turbine (DCHT) applications, in terms of the effect of simulated reactor primary coolant (impure Helium), high temperatures, and long time exposures, on the mechanical properties and structural and surface stability of selected candidate alloys. A second objective is to select and recommend materials for future test facilities and more extensive qualification programs. Work covered in this report includes progress to date on alloy selection for VHTR Nuclear Process Heat (NPH) applications and for DCHT applications. The present status on the simulated reactor helium loop design and on designs for the testing and analysis facilities and equipment is discussed.

  14. Advanced gas cooled nuclear reactor materials evaluation and development program

    International Nuclear Information System (INIS)

    Results of work performed from January 1, 1977 through March 31, 1977 on the Advanced Gas Cooled Nuclear Reactor Materials Evaluation and Development Program are presented. The objectives of this program are to evaluate candidate alloys for Very High Temperature Reactor (VHTR) Process Heat and Direct Cycle Helium Turbine (DCHT) applications, in terms of the effect of simulated reactor primary coolant (impure Helium), high temperatures, and long time exposures, on the mechanical properties and structural and surface stability of selected candidate alloys. A second objective is to select and recommend materials for future test facilities and more extensive qualification programs. Work covered in this report includes progress to date on alloy selection for VHTR Nuclear Process Heat (NPH) applications and for DCHT applications. The present status on the simulated reactor helium loop design and on designs for the testing and analysis facilities and equipment is discussed

  15. 77 FR 36014 - Initial Test Program of Emergency Core Cooling Systems for Boiling-Water Reactors

    Science.gov (United States)

    2012-06-15

    ... COMMISSION Initial Test Program of Emergency Core Cooling Systems for Boiling-Water Reactors AGENCY: Nuclear...-1277, ``Initial Test Program of Emergency Core Cooling Systems for Boiling- Water Reactors.'' This... testing features of emergency core cooling systems (ECCSs) for boiling-water reactors (BWRs)....

  16. Liquid-cooled nuclear reactor, especially a boiling water reactor

    International Nuclear Information System (INIS)

    A nuclear reactor with a special arrangement of fuel rods in the core is designed. Each fuel element has its shaft which is made of sheets, has the same cross section as the fuel element and protrudes at least the length of the control rod above the reactor core. Made of a zirconium alloy in the core area and of stainless steel above it, the shaft is equipped with channels for sliding the rods in and out and serves to spatially secure the position of the rods. Coolant flow is provided by the chimney effect. The shaft can conveniently enclose the control rod drive. It can also serve to bear the water separator. Moreover, it can constitute a part of the casing which surrounds the fuel rods and keeps the fuel in an intimate contact with the coolant; the other part of this casing is constituted by inserted sheets which can conveniently have the shape of angles. The walls of neighboring shafts form a compartment accommodating a neutron absorber plate. (M.D.). 11 figs

  17. Recent Progress in the Synthesis of Polymers Based on Carbon Dioxide

    Institute of Scientific and Technical Information of China (English)

    H. Sugimoto; S. Inoue

    2005-01-01

    @@ 1Introduction Carbon dioxide is the most fundamental carbon resource indispensable for all living systems including human being via photosynthesis by green plants. On the other hand, chemical utilization of carbon dioxide has been rather limited.

  18. Carbon Dioxide Effects Research and Assessment Program. Carbon Dioxide Research Progress Report, fiscal year 1979

    Energy Technology Data Exchange (ETDEWEB)

    Dahlman, R. C.; Gross, T.; Machta, L.; Elliott, W.; MacCracken, M.

    1980-04-01

    Research on the global carbon cycle and the effects of increased carbon dioxide on the global climate system is reported. Environmental and societal effects related to CO/sub 2/ and environmental control technology for CO/sub 2/ are also discussed. Lists of research projects and reports and publications of the Carbon Dioxide and Climate Research Program are included. An expanded CO/sub 2/ monitoring network is providing increased coverage for interpretation of patterns of sources and sinks seasonal variability, and documentation of the global growth of CO/sub 2/. Modeling studies emphasized that knowledge of the transport and mixing of surface ocean waters is important in understanding deep oceanic circulation. Initial studies in the equatorial Pacific are helping quantify estimates of the amount of outgassing CO/sub 2/ from tropical waters. During fiscal year 1979, there was a substantial increase in appreciation of the role of the ocean in controlling not only atmospheric CO/sub 2/ concentrations but also the climatic response to changes in concentration. Model simulations of the effect of doubled CO/sub 2/ concentration carried out with fixed ocean temperatures a situation that is possible during perhaps the next 20 years, showed relatively small summer heating over land areas. On the other hand, simulations in which the oceanic temperatures could come into instantaneous equilibrium with atmospheric conditions continued to show global temperature increases of 3 +- 1.5/sup 0/C, accentuated at high latitudes. To improve understanding of possible regional climate changes, there were increased efforts to reconstruct regional climatic patterns prevailing during past warm periods that might serve as analogs of future climatic conditions. Particular attention was directed to the climates of the United States and other countries bordering the North Atlantic Ocean during the warm period 5000 to 7000 years ago.

  19. Surface chemistry of polymers. The adsorption of carbon dioxide and sulfur dioxide on polyvinylidene chloride

    OpenAIRE

    Stoeckli, Fritz

    2007-01-01

    Isotherms for the adsorption of nitrogen (77 K), carbon dioxide (195-247 K) and sulfur dioxide (254-293 K) on polyvinylidene chloride have been measured volumetrically. The B.E.T. cross-sectional areas of 18 Å2 (CO2) and 24 Å2 (SO2) are comparable to liquid density values. The isosteric heat of adsorption of CO2 is constant for 0.2

  20. System Study: Reactor Core Isolation Cooling 1998–2013

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, John Alton [Idaho National Lab. (INL), Idaho Falls, ID (United States). Risk Assessment and Management Services Dept.

    2015-01-31

    This report presents an unreliability evaluation of the reactor core isolation cooling (RCIC) system at 31 U.S. commercial boiling water reactors. Demand, run hours, and failure data from fiscal year 1998 through 2013 for selected components were obtained from the Institute of Nuclear Power Operations (INPO) Consolidated Events Database (ICES). The unreliability results are trended for the most recent 10-year period, while yearly estimates for system unreliability are provided for the entire active period. No statistically significant trends were identified in the RCIC results.

  1. Startup of the FFTF sodium cooled reactor. [Acceptance Test Program

    Energy Technology Data Exchange (ETDEWEB)

    Redekopp, R.D.; Umek, A.M.

    1981-03-01

    The Fast Flux Test Facility (FFTF), located on the Department of Energy (DOE) Hanford Reservation near Richland, Washington, is a 3 Loop 400 MW(t) sodium cooled fast reactor with a primary mission to test fuels and materials for development of the Liquid Metal Fast Breeder Reactor (LMFBR). Bringing FFTF to a condition to accomplish this mission is the goal of the Acceptance Test Program (ATP). This program was the mechanism for achieving startup of the FFTF. Highlights of the ATP involving the system inerting, liquid metal and inerted cell testing and initial ascent to full power are discussed.

  2. System Study: Reactor Core Isolation Cooling 1998-2014

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, John Alton [Idaho National Lab. (INL), Idaho Falls, ID (United States). Risk Assessment and Management Services Dept.

    2015-12-01

    This report presents an unreliability evaluation of the reactor core isolation cooling (RCIC) system at 31 U.S. commercial boiling water reactors. Demand, run hours, and failure data from fiscal year 1998 through 2014 for selected components were obtained from the Institute of Nuclear Power Operations (INPO) Consolidated Events Database (ICES). The unreliability results are trended for the most recent 10 year period, while yearly estimates for system unreliability are provided for the entire active period. No statistically significant trends were identified in the RCIC results.

  3. Assessing Carbon Dioxide Emissions from Energy Use at a University

    Science.gov (United States)

    Riddell, William; Bhatia, Krishan Kumar; Parisi, Matthew; Foote, Jessica; Imperatore, John, III

    2009-01-01

    Purpose: The purpose of this paper is to assess the carbon dioxide emissions associated with electric, HVAC, and hot water use from a US university. Design/methodology/approach: First, the total on-campus electrical, natural gas and oil consumption for an entire year was assessed. For each category of energy use, the carbon associated with…

  4. Carbon dioxide accounting:2014 Commonwealth Games Atheletes’ Village

    OpenAIRE

    Sampson, Jennifer; Biesta, Mark; Crapper, Martin; Hall, Iain; Shepherd, Alan

    2013-01-01

    A spreadsheet-based tool for whole-life carbon dioxide accounting of soil remediation projects has been created. The tool carries out whole-life analysis of projects, including supply chain emissions. It was applied to the Glasgow 2014 Commonwealth Games Athletes' Village remediation project, for which a calculated total ‘carbon footprint’ of 2328 t of carbon dioxide equivalent emission (tCO2e) was obtained. This is 71 tCO2e/ha of the site or 13·3 kgCO2e/t whole life of soil treated. These fi...

  5. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Raghubir P.Gupta; William J. McMichael; Ya Liang; Douglas P. Harrison

    2002-10-01

    The objective of this project is to develop a simple and inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable sorbent. The sorbents being investigated in this project are primarily alkali carbonates, and particularly sodium carbonate and potassium carbonate, which are converted to bicarbonates through reaction with carbon dioxide and water vapor. Bicarbonates are regenerated to carbonates when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. This quarter, electrobalance tests suggested that higher temperature calcination of trona leds to reduced carbonation activity in subsequent cycles, but that calcination in dry carbon dioxide did not result in decreased activity relative to calcination in helium. Following higher temperature calcination, sodium bicarbonate (SBC) No.3 has greater activity than either coarse or fine grades of trona. Fixed bed testing of calcined SBC No.3 at 70 C confirmed that high rates of carbon dioxide absorption are possible and that the resulting product is a mixture of Wegscheider's salt and sodium carbonate. In fluidized bed testing of supported potassium carbonate, very rapid carbonation rates were observed. Activity of the support material complicated the data analysis. A milled, spherical grade of SBC appeared to be similar in attrition and abrasion characteristics to an unmilled, less regularly shaped SBC. The calcination behavior, at 107 C, for the milled and unmilled materials was also similar.

  6. Molecular Simulation of Carbon Dioxide Adsorbed in a Slit Carbon Pore

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Both the grand canonical Monte Carlo and molecular dynamics simulation methods are used to investigate the adsorption and diffusion of carbon dioxide confined in a 1.86 nm slit carbon pore at 4 temperatures from subcritical (120 K) to supercritical (313 K) conditions. Layering transition, capillary condensation and adsorption hysteresis are found at 120 K. The microstructure of carbon dioxide fluid in the slit carbon pore is analyzed. The diffusion coefficients of carbon dioxide parallel to the slit wall are significantly larger than those normal to the slit wall.

  7. Robust direct effect of carbon dioxide on tropical circulation and regional precipitation

    Science.gov (United States)

    Bony, Sandrine; Bellon, Gilles; Klocke, Daniel; Sherwood, Steven; Fermepin, Solange; Denvil, Sébastien

    2013-06-01

    Predicting the response of tropical rainfall to climate change remains a challenge. Rising concentrations of carbon dioxide are expected to affect the hydrological cycle through increases in global mean temperature and the water vapour content of the atmosphere. However, regional precipitation changes also closely depend on the atmospheric circulation, which is expected to weaken in a warmer world. Here, we assess the effect of a rise in atmospheric carbon dioxide concentrations on tropical circulation and precipitation by analysing results from a suite of simulations from multiple state-of-the-art climate models, and an operational numerical weather prediction model. In a scenario in which humans continue to use fossil fuels unabated, about half the tropical circulation change projected by the end of the twenty-first century, and consequently a large fraction of the regional precipitation change, is independent of global surface warming. Instead, these robust circulation and precipitation changes are a consequence of the weaker net radiative cooling of the atmosphere associated with higher atmospheric carbon dioxide levels, which affects the strength of atmospheric vertical motions. This implies that geo-engineering schemes aimed at reducing global warming without removing carbon dioxide from the atmosphere would fail to fully mitigate precipitation changes in the tropics. Strategies that may help constrain rainfall projections are suggested.

  8. Fuel performance and fission product behaviour in gas cooled reactors

    International Nuclear Information System (INIS)

    The Co-ordinated Research Programme (CRP) on Validation of Predictive Methods for Fuel and Fission Product Behaviour was organized within the frame of the International Working Group on Gas Cooled Reactors. This International Working Group serves as a forum for exchange of information on national programmes, provides advice to the IAEA on international co-operative activities in advanced technologies of gas cooled reactors (GCRs), and supports the conduct of these activities. The objectives of this CRP were to review and document the status of the experimental data base and of the predictive methods for GCR fuel performance and fission product behaviour; and to verify and validate methodologies for the prediction of fuel performance and fission product transport

  9. Decay heat removal in GEN IV gas cooled fast reactors

    International Nuclear Information System (INIS)

    The safety goal of the current designs of advanced high-temperature thermal gas-cooled reactors (HTRs) is that no core meltdown would occur in a depressurization event with a combination of concurrent safety system failures. This study focused on the analysis of passive decay heat removal (DHR) in a GEN IV direct-cycle gas-cooled fast reactor (GFR) which is based on the technology developments of the HTRs. Given the different criteria and design characteristics of the GFR, an approach different from that taken for the HTRs for passive DHR would have to be explored. Different design options based on maintaining core flow were evaluated by performing transient analysis of a depressurization accident using the system code RELAP5-3D. The study also reviewed the conceptual design of autonomous systems for shutdown decay heat removal and recommends that future work in this area should be focused on the potential for Brayton cycle DHRs.

  10. Economic competitiveness requirements for evolutionary water cooled reactors

    International Nuclear Information System (INIS)

    This paper analyses the necessary economic conditions for evolutionary water cooled reactors to be competitive. Utilising recent national cost data for fossil-fired base load plants expected to be commissioned by 2005 -2010, target costs for nuclear power plants are discussed. Factors that could contribute to the achievement of those targets by evolutionary water cooled reactors are addressed. The feed-back from experience acquired in implementing nuclear programmes is illustrated by some examples from France and the Republic of Korea. The paper discusses the impacts on nuclear power competitiveness of globalisation and deregulation of the electricity market and privatisation of the electricity sector. In addition, issues related to external cost internalisation are considered. (author)

  11. Core Seismic Tests for a Sodium-Cooled Fast Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Koo, Gyeong Hoi; Lee, J. H

    2007-01-15

    This report describes the results of the comparison of the core seismic responses between the test and the analysis for the reduced core mock-up of a sodium-cooled fast reactor to verify the FAMD (Fluid Added Mass and Damping) code and SAC-CORE (Seismic Analysis Code for CORE) code, which implement the application algorithm of a consistent fluid added mass matrix including the coupling terms. It was verified that the narrow fluid gaps between the duct assemblies significantly affect the dynamic characteristics of the core duct assemblies and it becomes stronger as a number of duct increases within a certain level. As conclusion, from the comparison of the results between the tests and the analyses, it is verified that the FAMD code and the SAC-CORE code can give an accurate prediction of a complex core seismic behavior of the sodium-cooled fast reactor.

  12. Experimental Validation of Passive Safety System Models: Application to Design and Optimization of Fluoride-Salt-Cooled, High-Temperature Reactors

    Science.gov (United States)

    Zweibaum, Nicolas

    The development of advanced nuclear reactor technology requires understanding of complex, integrated systems that exhibit novel phenomenology under normal and accident conditions. The advent of passive safety systems and enhanced modular construction methods requires the development and use of new frameworks to predict the behavior of advanced nuclear reactors, both from a safety standpoint and from an environmental impact perspective. This dissertation introduces such frameworks for scaling of integral effects tests for natural circulation in fluoride-salt-cooled, high-temperature reactors (FHRs) to validate evaluation models (EMs) for system behavior; subsequent reliability assessment of passive, natural- circulation-driven decay heat removal systems, using these validated models; evaluation of life cycle carbon dioxide emissions as a key environmental impact metric; and recommendations for further work to apply these frameworks in the development and optimization of advanced nuclear reactor designs. In this study, the developed frameworks are applied to the analysis of the Mark 1 pebble-bed FHR (Mk1 PB-FHR) under current investigation at the University of California, Berkeley (UCB). (Abstract shortened by UMI.).

  13. Status of advanced technology and design for water cooled reactors: Heavy water reactors

    International Nuclear Information System (INIS)

    In 1987 the IAEA established the International Working Group on Advanced Technologies for Water-Cooled Reactors (IWGATWR). Within the framework of the IWGATWR the IAEA Technical Report on Status of Advanced Technology and Design for Water Cooled Reactors, Part I: Light Water Reactors and Part II: Heavy Water Reactors, has been undertaken to document the major current activities and trends of technological improvement and development for future water reactors. Part I of the report dealing with Light Water Reactors (LWRs) was published in 1988 (IAEA-TECDOC-479). Part II of the report covers Heavy Water Reactors (HWRs) and has now been prepared. This report is based largely upon submissions from Member States. It has been supplemented by material from the presentations at the IAEA Technical Committee and Workshop on Progress in Heavy Water Reactor Design and Technology held in Montreal, Canada, December 6-9, 1988. It is hoped that this part of the report, containing the status of advanced heavy water reactor technology up to 1988 and ongoing development programmes will aid in disseminating information to Member States and in stimulating international cooperation. Refs, figs and tabs

  14. Liner insulation for gas cooled reactors - a personal history

    International Nuclear Information System (INIS)

    The paper describes briefly the development work leading to the foil and mesh insulation used at Oldbury and the fibre insulation used in the Hinkley and Hunterston reactors. The subject is covered under the headings: cooling system; insulation specification; thermal problems; Oldbury (choice of insulant; conductivity tests; commissioning); Hinkley (choice of insulant; thermal performance; mechanical details; acoustic testing; thermal cycling tests); commissioning tests; Torness and Heysham. (U.K.)

  15. Gas turbine modeling for NPP with helium cooled reactor

    International Nuclear Information System (INIS)

    The performance analyzes of closed helium cycle for NPPs with high-temperature gas-cooled reactors was carried out. Air-turbine units and helium-turbine units were compared. Helium turbine features were particularized in comparison with conventional air turbines. Simulation results of gas turbine setting with helium as a working medium were presented. Problems concerning high economic efficiency advance of helium turbines were discussed

  16. The status of graphite development for gas cooled reactors

    International Nuclear Information System (INIS)

    The meeting was convened by the IAEA on the recommendation of the International Working Group on Gas Cooled Reactors. It was attended by 61 participants from 6 countries. The meeting covered the following subjects: overview of national programs; design criteria, fracture mechanisms and component test; materials development and properties; non-destructive examination, inspection and surveillance. The participants presented 33 papers on behalf of their countries. A separate abstract was prepared for each of these papers. Refs, figs, tabs, photos and diagrams

  17. Advanced technologies for water cooled reactors 1990. Pt. 1

    International Nuclear Information System (INIS)

    The meeting was attended by 20 participants from 12 countries who reviewed and discussed the status and progress of national programmes on advanced water-cooled reactors and recommended to the Scientific Secretary a comprehensive programme for 1991/1992 which would support technology development programmes in IWGATWR Member States. This summary report outlines the activities of IWGATWR since its Second Meeting in June 1988 and main results of the Third Meeting

  18. Advanced technologies for water cooled reactors 1990. Pt. 2

    International Nuclear Information System (INIS)

    The main purpose of the meeting was to review and discuss the status of national programmes, the progress achieved since the last meeting held in June 1988 in the field of advanced technologies and design trends for existing and future water cooled reactors. 24 specialists from 14 countries and the IAEA took part in the meeting and 12 papers were presented. A separate abstract was prepared for each of these papers. Refs, figs and tabs

  19. Direct carbon dioxide emissions from civil aircraft

    Science.gov (United States)

    Grote, Matt; Williams, Ian; Preston, John

    2014-10-01

    Global airlines consume over 5 million barrels of oil per day, and the resulting carbon dioxide (CO2) emitted by aircraft engines is of concern. This article provides a contemporary review of the literature associated with the measures available to the civil aviation industry for mitigating CO2 emissions from aircraft. The measures are addressed under two categories - policy and legal-related measures, and technological and operational measures. Results of the review are used to develop several insights into the challenges faced. The analysis shows that forecasts for strong growth in air-traffic will result in civil aviation becoming an increasingly significant contributor to anthropogenic CO2 emissions. Some mitigation-measures can be left to market-forces as the key-driver for implementation because they directly reduce airlines' fuel consumption, and their impact on reducing fuel-costs will be welcomed by the industry. Other mitigation-measures cannot be left to market-forces. Speed of implementation and stringency of these measures will not be satisfactorily resolved unattended, and the current global regulatory-framework does not provide the necessary strength of stewardship. A global regulator with ‘teeth' needs to be established, but investing such a body with the appropriate level of authority requires securing an international agreement which history would suggest is going to be very difficult. If all mitigation-measures are successfully implemented, it is still likely that traffic growth-rates will continue to out-pace emissions reduction-rates. Therefore, to achieve an overall reduction in CO2 emissions, behaviour change will be necessary to reduce demand for air-travel. However, reducing demand will be strongly resisted by all stakeholders in the industry; and the ticket price-increases necessary to induce the required reduction in traffic growth-rates place a monetary-value on CO2 emissions of approximately 7-100 times greater than other common

  20. Biomass combustion for greenhouse carbon dioxide enrichment

    International Nuclear Information System (INIS)

    Greenhouses in northern climates have a significant heat requirement that is mainly supplied by non-renewable fuels such as heating oil and natural gas. This project's goal was the development of an improved biomass furnace able to recover the heat and the CO2 available in the flue gas and use them in the greenhouse. A flue gas purification system was designed, constructed and installed on the chimney of a wood pellet furnace (SBI Caddy Alterna). The purification system consists of a rigid box air filter (MERV rating 14, 0.3 μm pores) followed by two sets of heating elements and a catalytic converter. The air filter removes the particulates present in the flue gas while the heating elements and catalysers transform the noxious gases into less harmful gases. Gas analysis was sampled at different locations in the system using a TESTO 335 flue gas analyzer. The purification system reduces CO concentrations from 1100 cm3 m−3 to less than 1 cm3 m−3 NOx from 70 to 5.5 cm3 m−3 SO2 from 19 cm3 m−3 to less than 1 cm3 m−3 and trapped particulates down to 0.3 μm with an efficiency greater than 95%. These results are satisfactory since they ensure human and plant safety after dilution into the ambient air of the greenhouse. The recuperation of the flue gas has several obvious benefits since it increases the heat usability per unit biomass and it greatly improves the CO2 recovery of biomass heating systems for the benefit of greenhouse grown plants. - Highlights: • Biomass furnace shows high potential for greenhouse carbon dioxide enrichment. • Flue gas recuperation significantly increases the thermal efficiency of a furnace. • Catalytic converter can reduce CO and NOx below humans and plants exposure limit. • Particulates control is essential to maintain the efficiency of the catalytic conversion. • CO2 recovery from biomass heating systems reduces farmer's reliance on fossil fuel