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Sample records for caracterizacao clinica radiografica

  1. Clinical, radiographic and scintigraphic aspects of the trapeziometacarpal osteoarthritis; Caracterizacao clinica, radiografica e cintilografica da osteoartrose trapeziometacarpiana

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    Kaziyama, Helena Hideko Seguchi

    1996-12-31

    Trapeziometacarpal osteoarthritis occurs mainly in women during the menopausal period. It is related to manual activities and is usually bilateral. The onset is insidious and the evolution is slow and progressive. It is characterized by of strength and pain in the basis of the thumb resulting in limitation of the use and function of the hand. The diagnosis of this condition is based on the physical examination. The manouver of compression axial-rotation of the trapezimetacarpal joint is a common positive finding. Typical findings of osteoarthritis are present in the radiological studies. Scintigraphic images have a predictive value. The early diagnosis is important to avoid the risk factors and to prevent disabilities of the hand. (author) 102 refs., 18 figs., 10 tabs.

  2. Avaliação clinica e radiografica da carie dental em escolares de região de agua fluoretada e submetidos a aplicação de fluor e selantes

    OpenAIRE

    Cristina Maria Dumit Sewell

    1990-01-01

    Resumo: O objetivo do presente trabalho foi avaliar clinica e radiograficamente a evolução do processo de carie em escolares de 6 a 8 anos de Piracicaba, SP, que bebiam agua fluoretada e foram submetidos a aplicação de fluor e selantes ... Observação: O resumo, na íntegra poderá ser visualizado no texto completo da tese digital Abstract: The aim of this study was to evaluate clinically and radiographically the evolution of the caries process in school children of 6 to 8 years old of Pirac...

  3. An evening at "La Clinica del Pueblo".

    Science.gov (United States)

    Shefsky, M L

    1986-01-01

    This article describes a typical evening at the Clinica del Pueblo in the Hispanic neighborhood of Adams-Morgan in Washington, D.c. The Clinical del Pueblo began operating in 1983 in response to the urgen medical needs of Central American refugees arriving in the Washington D.c. area. The refugees bring with them severe trauma, fear, and health problems caused by the civil was and exacerbated by inadequate or non-existant health services. Approximately 80,000 Salvadoran refugees live in the area. They do not receive adequate health care for 3 reasons. 1) Because the US goverment is unwilling to recognize them as true refugees, they live with the constant threat of deportatin back to the violence from which they have fled. 2) Refugees lack the ability to pay for private care. 3) Langauage and culture create frightening barriers to health care for the refugees. For those who do seek care, these barriers can lead to the inadequate or incomplete diagnoses and poor compliance and follow-up. Plenty International and the Central American Refugee Center responded to these problems by organizing a free clinic to provide not only medical care but also a training course for volunteers. The director of the clinic organizes the course, the classes are taught by a variety of people including the clinic's volunteer physicians, nurses, and public health educators as well as graduates of previus training courses and people from the wider community. The services of the clinic reach only a small portion of the population in need. However, the fact that free medical services are now available to some Central American refugees make the Clinica del Pueblo an important program.

  4. The first century of the "clinica del lavoro" in Milan.

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    Bertazzi, Pier Alberto; Foà, Vito

    2005-01-01

    The Clinica del Lavoro was created in Milan at the beginning of the 20th century by Luigi Devotto, who deemed it essential for physicians and health researchers to get involved in the life and health problems of working populations. The main roles of the Clinica del Lavoro were to educate medical students and train physicians; study actual workplaces, examine health and safety hazards and their noxious effects; and create initiatives and services to protect and promote workers' health. Important scientific contributions were made in several fields, including chemical carcinogenesis, effects of mineral and biologicalfibers, mechanism of action of silica dust, methods for the detection and measurements of toxic substances in both the work environment and workers' biological media.

  5. Book review. Semeiologia Clinica Veterinaria. (a cura di Paolo Ciaramella

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    Manuel Graziani

    2014-09-01

    Full Text Available Il grado di specializzazione raggiunto nel settore clinico veterinario non è dissimile da quello presente in campo umano, soprattutto se si pensa agli animali d'affezione che sono oramai considerati parte integrante di una società moderna e civile in cui anche il fattore benessere animale ha acquisito importanza non secondaria, in particolare nell'allevamento degli animali da reddito. In questo contesto è sempre più richiesta la figura di uno specialista competente e aggiornato, in grado di risolvere in modo adeguato le problematiche che gli vengono proposte, in un mercato in concorrenza che non contempla imperizia, inesperienza e ignoranza professionale. Lo studio della semeiologia clinica è uno dei primi passi di questo lungo e affascinate cammino che permette di apprendere un metodo di analisi sistematico, affidabile, efficiente e accurato per educare il futuro medico veterinario verso le procedure della buona pratica clinica. La semeiotica insegna ad allenare i propri sensi: a guardare attraverso l'osservazione diretta e indiretta, a sentire ascoltando suoni o rumori, a percepire sensazioni tattili e, non da ultimo, a saper discernere con cognizione e competenza quando ricorrere alle indagini strumentali e di laboratorio; sempre e comunque nella consapevolezza che non possono in nessun modo sostituire l'esame fisico diretto del paziente. Paolo Ciaramella, professore ordinario di Clinica Medica Veterinaria all'Università Federico II di Napoli, presenta così il volume che ha curato: "L'idea di questo libro ha preso forma durante un simposio di medicina interna tenutosi a Torino nel 2008. Con alcuni colleghi presenti si pensò alla possibilità di elaborare un nuovo testo di Semeiotica Medica che potesse ampliare e aggiornare il glorioso Messieri e Moretti, non tanto perché esso avesse perduto il suo valore intrinseco, quanto piuttosto perché nel corso degli anni sono cambiate la patologia animale e con essa la semeiotica e la clinica

  6. Acta Clinica Croatica: progress of a journal step by step.

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    Ramljak, Gordana

    2014-03-01

    The journal Acta Clinica Croatica (ACC) was founded in 1962 under the title Anali Bolnice Dr. M. Stojanović. In 1995, the title of the journal was changed into its present form and ever since all papers have been published in English. In 2000, the electronic (online) edition of the ACC was released in addition to the print version. The paper presents development of the journal from 1962 to 2012 based on the analysis of the following SCOPUS citation index parameters: type and number of documents published in the journal; number of citations; and number of domestic and foreign authors. The studied period was analyzed in three time segments: the period from 1995 to 1999, the period from 2000 to 2006 and the period from 2007 to 2012. The same parameters were analyzed in the Web of Science/SCI-Expanded bibliographic and citation index for the 2007-2012 period. The increasing number of documents, authors (both domestic and foreign) and citations demonstrates gradual rise in the quality, visibility and impact of the journal. The fifty years of experience show that a goal, at first very distant and almost unachievable, may be reached by progressing step by step.

  7. Construction of a homogeneous phantom for radiographic image standardization; Construcao de um fantoma homogeneo para padronizacao de imagens radiograficas

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    Pina, Diana Rodrigues de

    1996-12-31

    The principle of radiodiagnosis consists in the fact the X-ray beam is attenuated at different degrees by distinct tissues. For this reason, the anatomical structures have distinct radiological opacities, that produce the radiographic image. The progresses in radiology are related to the development if new radiographic image formation systems that enable an amplification in the quality, with low dose and/or risk to the patient. The objective of this work is the sensitometric valuation of a screen-film combination, that is still the most used, for the standardization, of radiographic images. Thinking about this, were constructed homogeneous phantoms of the chest, skull and pelvis, for the calibration of X-ray beams, with the purpose of obtaining radiographic images of good quality, basing in the routine of a radiodiagnosis service and in the scientific knowledge. Questions were approached about the choice of the suitable equipment, that allow the obtention of k Vp and m As combinations, to produce radiographic images of good quality, and the reproduction of these combinations to any conventional equipment of diagnostic X-rays. Also presented are the comparison of the doses imparted by these combinations and those used in routine of the Hospital das Clinicas da Faculdade de Medicina de Ribeirao Preto`s radiodiagnosis service. (author) 24 refs., 27 figs., 12 tabs.

  8. OC ToGo: bed site image integration into OpenClinica with mobile devices

    Science.gov (United States)

    Haak, Daniel; Gehlen, Johan; Jonas, Stephan; Deserno, Thomas M.

    2014-03-01

    Imaging and image-based measurements nowadays play an essential role in controlled clinical trials, but electronic data capture (EDC) systems insufficiently support integration of captured images by mobile devices (e.g. smartphones and tablets). The web application OpenClinica has established as one of the world's leading EDC systems and is used to collect, manage and store data of clinical trials in electronic case report forms (eCRFs). In this paper, we present a mobile application for instantaneous integration of images into OpenClinica directly during examination on patient's bed site. The communication between the Android application and OpenClinica is based on the simple object access protocol (SOAP) and representational state transfer (REST) web services for metadata, and secure file transfer protocol (SFTP) for image transfer, respectively. OpenClinica's web services are used to query context information (e.g. existing studies, events and subjects) and to import data into the eCRF, as well as export of eCRF metadata and structural information. A stable image transfer is ensured and progress information (e.g. remaining time) visualized to the user. The workflow is demonstrated for a European multi-center registry, where patients with calciphylaxis disease are included. Our approach improves the EDC workflow, saves time, and reduces costs. Furthermore, data privacy is enhanced, since storage of private health data on the imaging devices becomes obsolete.

  9. [The role of the "Clinica del Lavoro Luigi Devoto" in international research].

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    Bertazzi, P A; Forni, Alessandra M

    2003-01-01

    During its long history, the Clinica del Lavoro Luigi Devoto has produced numerous internationally recognized scientific contributions in the specific field of occupational medicine and health, and in other broader areas as, for example, immunology, toxicology, cytogenetics. Pivotal in this activity was the figure of Enrico C. Vigliani, director of the Clinica for over 35 years. We mention here, in particular, the results of the study of "early" markers of lead intoxication; the research on the carcinogenicity of benzene and aromatic amines; the study of the pathogenesis of silicosis and byssinosis; the study of cytogenetic damage after exposure to industrial toxic chemicals; the technical research for dust abatement in mines. Such research also played a major role in the development of pulmonary medicine, toxicology and immunology in Italy, and conferred scientific dignity on the newborn "industrial hygiene" discipline thanks to the work of Nicola Zurlo. Today, the Clinica's research is maintained at international standards especially by the work of thematic Research Centers recently established within the Clinica, covering fields such as occupational and environmental toxicology, occupational oncology, ergonomics, respiratory disease and allergy, psycho-social risk factors. These Centers are also devoted to the development of innovative methods in epidemiology, toxicology, psychology, molecular biology, and ergonomic measurement for the identification and evaluation of health risks at work.

  10. Hiperprolactinemia : expressao clinica, hormonal e radiologica em pacientes femininas, antes e durante o tratamento clinico

    OpenAIRE

    Elaine Sangali Mallmann

    1993-01-01

    A hiperprolactinemia constitui-se num achado laboratorial que quando resultante de secreção inapropriada, pode indicar tanto um processo patológico orgânico, como uma desordem funcional reversível. Representa o distúrbio hipofisário mais frequentemente encontrado na prática clinica e constitui um dos aspectos mais importantes no estudo da endocrinologia da reprodução. As hiperprolactinemias de causas não fisiológicas são secundárias mais frequentemente a efeito farmacológico, presença de tumo...

  11. Biblioterapia: uma experiência com pacientes internados em clinica médica/Bibliotherapy: an experience with patients interned in medical clinica

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    Eva Seitz

    2005-01-01

    Full Text Available O presente artigo tem por finalidade apresentar resultados do estudo biblioterapêutico, realizado com pacientes internados em clinica médica. O foco central foi verificar o nível de aceitação da leitura como atividade de lazer por pacientes internados em clínica médica. A prática biblioterapêutica com pacientes internados em clínica médica demonstrou ser útil no processo de hospitalização, como fonte de lazer e de informação, na interação biblioterapeuta/paciente/enfermagem e, no processo de sociabilização, além, de proporcionar momentos de descontração e alegria aos pacientes, contribuindo para o bem estar mental dos mesmos. O estudo aponta para o importante papel da leitura enquanto atividade de lazer para pacientes hospitalizados, humanizando o processo de hospitalização. The present article has for purpose to present resulted of the library-therapeutic study, carried through with patients interned in medical clinic. The central focus was to verify the reading acceptance as leisure activity by in-patients at Medical Clinic, through library-therapy practice. The library-therapy practice with in-patients at Medical clinic showed to be useful in the hospitalization process as leisure source and information, in library-therapist/patient/nursing interaction and, in the socialization process. Besides, it brought pleasant moments and joy to the patients, contributing for mental welfare of them. The study points out the important role of reading while leisure activity for hospitalized patients, humanizing the hospitalization process.

  12. Neurosurgical experience with tumours of the pineal region at Clinica Puerta de Hierro.

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    Vaquero, J; Ramiro, J; Martínez, R; Bravo, G

    1992-01-01

    The clinicopathological experience with 50 cases of pineal region tumours at Clinica Puerta de Hierro is presented. In this series, 88% of the patients were evaluated by CT-scan. Pineal region tumours make up approximately 0.7% of the intracranial expansive processes in the Spanish population. The largest group of lesions appearing in this localization is that of the germinomas (38%), followed by nontumoural lesions (20%) and tumours generally considered to be of the vicinity, such as meningiomas, gliomas and metastases (18%), tumours of the pineal parenchyma (14%), and non-germinoma germinal tumours (10%). In our series, in addition to an intracranial hypertension syndrome, an ophthalmological and, to a minor degree, an endocrinological syndrome predominate in germ-cell tumours, with a cerebellar syndrome appearing in gliomas of the pineal region. All the patients in the series diagnosed as having a germinoma and treated by irradiation are alive, and free of disease, after follow-up ranging from 2 to 20 years (mean: 8 years). The experience obtained with the present series supports the opinion that, in radiosensitive tumours, surgical resection adds no therapeutic benefit to treatment with radiotherapy alone. We suggest that when dealing with a tumour of the pineal region, CT-scan and clinical assessment now permit an initial selection of patients susceptible to surgery as a first therapeutic option, indicating those patients who, because they are considered to have either a "probable germinoma" or a "tumour of uncertain diagnosis", should undergo stereotaxic biopsy or trial radiotherapy and, only when this has proved a failure, should be subjected to open surgery.

  13. Evaluation of skin entry kerma in radiological examinations at the Hospital de Clinicas, Parana, Brazil; Avaliacao de kerma de entrada na pele em exames radiologicos no Hospital de Clinicas do Parana, Brasil

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    Porto, Lorena E.; Schelin, Hugo R.; Santos, Amanda C. dos; Bunick, Ana Paula; Paschuk, Sergei; Denyak, Valeriy [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil); Tilly Junior, Joao G. [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil). Hospital de Clinicas; Khoury, Helen J., E-mail: khoury@ufpe.b [Universidade Federal de Pernambuco (UFPE/DEN), Recife, PE (Brazil). Dept. de Energia Nuclear

    2011-10-26

    This paper evaluates the skin entry dose of pediatric and adults patients when submitted to radiological examinations at the Hospital de Clinicas do Parana, Brazil, as part integrate of the data assessment of International Atomic Energy Agency (IAEA) for Latin America. It was performed measurements of dose for evaluation of skin entry kerma in pediatric patients in thorax AP/PA examinations, adults of thorax in AP/PA, cranio caudal mammography and median lateral and patients of computerized tomography in examination of head, thorax and abdomen. The obtained data demonstrate the necessity of verification of diagnostic analysis standards. The great value amplitudes demonstrate the incompatibility of examination executions with those recommended by the literature. The dose values presented partially inside the range recommended and the other over the expected for the due examination when compared with the literature

  14. Comparative study of bridge plate associated to the intramedullary pin and the dynamic compression plate on the experimental osteotomy fixation of femoral in rabbits (Oryctolagus cuniculus). Clinical, radiographic, histological and scintigraphy analyses; Estudo comparativo da placa em ponte associada ao pino intramedular e da placa de compressao dinamica na fixacao de osteotomia experimental em femur de coelhos (Oryctolagus cuniculus). Analises clinica, radiografica, histologica e cintilografica

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    Borges, Natalie Ferreira

    2011-07-01

    The objectives were to benchmark and monitor the fracture healing of femoral osteotomy in rabbits after fixation with dynamic compression plate and bridge plate associated with intramedullary pin. Were used 14 New Zealand rabbits, four months old with mean weight of 3.5 pounds, from the Experimental Farm Professor Helio Barbosa of the Veterinary School of Minas Gerais Federal Univ. (UFMG). The animals were randomly divided into two groups (I and II). All rabbits underwent osteotomy across the middle third of right femur. In the group I was made to fix the osteotomy with the bridge plate (BP) associated with intramedullary pin, introduced the technique of minimal invasion. In group II, we used dynamic compression plate (DCP) via the conventional approach. Both groups were evaluated clinical, radiographic, histologic and scintigraphic findings. Clinical assessments were performed weekly until the 12{sup th} postoperative week and radiographic examinations were performed before, immediately after, at 15, 30, 45, 60 and 90 days. The bone scintigraphy were performed before and at 20, 50 and 90 days after surgery to monitor the bone metabolism qualitatively and quantitatively. Observed perfusion and bone healing process. After 90 days of study, there was histopathologic evaluation of the osteotomized area and the insertion of screws. In the region of the osteotomy was observed predominance of trabecular bone in group I and group II, the predominance of bone osteons, compatible with the original bone. On insertion of the screws did not differ between groups and there was cortical discontinuity, little necrosis and local hemorrhage. The two types of fixation have led to consolidation within the scheduled period, maturing in early fixation with DCP fixation compared with BP. Scintigraphy demonstrated by the indices of activity and image characteristics, the process of bone healing was significantly greater in animals undergoing early fixation with DCP. (author)

  15. Virtual-reality-based attention assessment of ADHD: ClinicaVR: Classroom-CPT versus a traditional continuous performance test.

    Science.gov (United States)

    Neguț, Alexandra; Jurma, Anda Maria; David, Daniel

    2016-06-03

    Virtual-reality-based assessment may be a good alternative to classical or computerized neuropsychological assessment due to increased ecological validity. ClinicaVR: Classroom-CPT (VC) is a neuropsychological test embedded in virtual reality that is designed to assess attention deficits in children with attention deficit hyperactivity disorder (ADHD) or other conditions associated with impaired attention. The present study aimed to (1) investigate the diagnostic validity of VC in comparison to a traditional continuous performance test (CPT), (2) explore the task difficulty of VC, (3) address the effect of distractors on the performance of ADHD participants and typically-developing (TD) controls, and (4) compare the two measures on cognitive absorption. A total of 33 children diagnosed with ADHD and 42 TD children, aged between 7 and 13 years, participated in the study and were tested with a traditional CPT or with VC, along with several cognitive measures and an adapted version of the Cognitive Absorption Scale. A mixed multivariate analysis of covariance (MANCOVA) revealed that the children with ADHD performed worse on correct responses had more commissions and omissions errors than the TD children, as well as slower target reaction times . The results showed significant differences between performance in the virtual environment and the traditional computerized one, with longer reaction times in virtual reality. The data analysis highlighted the negative influence of auditory distractors on attention performance in the case of the children with ADHD, but not for the TD children. Finally, the two measures did not differ on the cognitive absorption perceived by the children.

  16. Definizione di un modello di prioritá clinica per la gestione dei tempi e delle liste di attesa

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    L. Bruno

    2003-05-01

    Full Text Available La gestione dei tempi di attesa, per la complessità dei determinanti che vi concorrono, costituisce una delle criticità del SSN frequentemente affrontata come un’emergenza. Per individuare soluzioni appropriate, garantendo tempi di attesa non tanto brevi quanto certi e adeguati al bisogni clinici, la Regione Lazio recependo gli indirizzi nazionali ha dato mandato ai Direttori Generali di definire e realizzare un’azione di governo clinico, che adegui l’offerta al bisogno reale. A tal fine la ASL Roma E ha progettato il presente studio pilota per la definizione di un modello di sperimentazione di priorità clinica, focalizzato su alcune prestazioni ambulatoriali critiche e sulle patologie oncologiche della mammella, del polmone e dell’apparato gastroenterico. Materiali e metodi: è stato costituito un gruppo di Progetto multidisciplinare per il coordinamento, il monitoraggio e la valutazione dello studio che ha coinvolto i medici prescrittori (MMGG e specialisti ambulatoriali, i medici dei Presidi ospedalieri, i Distretti, il CUP. In considerazione dell’estensione del territorio della ASL, della elevata densità di popolazione, della distribuzione dei presidi erogatori, la sperimentazione è stata circoscritta ad un ambito territoriale ristretto, corrispondente a quello del Municipio XVII. Sono stati arruolati 24 MMGG, individuati fra quelli inseriti in forme associative, con una popolazione di circa 30.000 assistiti. Sono state coinvolte sei strutture a gestione diretta insistenti nel Municipio. È stato previsto l’adattamento della procedura informatica di prenotazione, il coinvolgimento e la formazione degli operatori interni ai reparti ospedalieri interessati e del personale addetto al front - office. Risultati: definizione dei criteri clinici di arruolamento nelle classi di prioritarizzazione delle prestazioni ambulatoriali e delle patologie oncologiche con esplicitazione della graduazione del bisogno clinico. Creazione di un

  17. Clinical scientific research with ionizing radiations in Italy. Jurisprudential aspects; Ricerca scientifica clinica con radiazioni ionizzanti in Italia: aspetti normativi e giuridici

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    Valle, G.; Frusciante, V. [Casa Sollievo della Sofferenza, S. Giovanni Rotondo, FG (Italy). Servizio di Medicina Nucleare; Petrucelli, L. [Ospedale Civile Comiugi Bernardini, Palestrina, RM (Italy). Lab. di Analisi; Podagrosi, V. [Ospedale Santo Spirito, Rome (Italy). Div. di Chirurgia Generale e d' Urgenza; Giustini, A. [Ospedale Santo Spirito, Rome (Italy). Pronto Soccorso

    1999-09-01

    The paper reviews the laws that regulate the clinical scientific research with ionizing radiations in Italy and the effects of ICRP 62, introduced in Italy by the Minister's Decree 21/11/1997, renders invalid all previous rules and regulations which contrast with them. [Italian] Vengono esposte le norme di legge che regolano in Italia la ricerca scientifica clinica con radiazioni ionizzanti e discusse gli effetti dell'introduzione dell'ICRP 62 nella normativa italiana (DM 21/11/1997). Esso tratta in maniera esaustiva l'intera tematica e offre le fondamentali linee guida.

  18. La clinica parapsicologica

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    Evrard Renaud

    2007-09-01

    Full Text Available Gli ultimi due decenni hanno visto nascere una disciplina nuova: l'accoglienza e il sostegno psicologico delle persone che vivono esperienze eccezionali. Avere l'impressione di vivere in una casa abitata, testimoniare l’apparizione di OVNI, interrogarsi sulle possibilità di influenze telepatiche o anche conservare per sé la sensazione irreale di uscire “fuori dal corpo”, sono alcuni esempi di ciò che provano queste persone. L'eterogeneità di queste testimonianze le classifica spesso nella categoria delle "esperienze vissute come paranormali". Se tali resoconti sono sempre pervenuti agli esperti, si deve ai recenti lavori di ripristino dell'ascolto di queste persone.

  19. [The scientific progress of the "Clinica del Lavoro Luigi Devoto" as seen through the contents of the journal "La Medicina del Lavoro". ].

    Science.gov (United States)

    Foà, V; Camerino, Donatella

    2003-01-01

    On occasion of the Centenary of the "Clinica del Lavoro Luigi Devoto", its researchers suggested that awareness of its historical identity and scientific development should constitute the basis for the future of the Institution. The directors of the Institute who have succeeded one to the other over the years have left a vivid report of the vast amount of work developed in several research fields and also of the original results achieved with significant impact on the scientific community and on society. Content analysis of "La Medicina del Lavoro" allowed us to shed light on strong bonds existing between manufacturing techniques, work organization and health, in the different political and social periods in which they developed. Many actions have been defined and several research subjects have been renewed (according to current demands and new methodological possibilities) between the past and the present, nevertheless many new approaches need to be taken in the fields of epidemiology, indoor air quality, ergophthalmology, muskuloskeletal disorders, environmental and molecular toxicology, and further research will be undertaken thanks to the potential of this discipline for the future. The aim of this report is also to express our thanks to all the medical and non-medical staff who have made their contribution over 100 years of engagement.

  20. Chilhood leprosy: Clinical and epidemiological study in the Department of Dermatology, Clinicas Hospital, Faculty of Medical Sciences, National University of Asuncion-Paraguay, 2005-2014

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    Beatriz Di Martino Ortiz

    2016-01-01

    Full Text Available Introduction: Leprosy in childhood is not a common finding. The risk of a child to develop the disease is 4 times greater in contact with close people and 9 times higher among household contacts. The maximum risk observed is when the contact is Multibacillary (MB and intradomicilliary. Leprosy in childhood reflects the clinical characteristics of adult, with some peculiar aspects. Non-contagious forms (IL and TT are common during childhood. The contagious forms (BB, LB and LL are less frequent due to higher required incubation period. Aim: To describe the clinical and epidemiological characteristics of childhood leprosy in the Department of Dermatology, Clinicas Hospital from January 2005 to July 2014. Methods: Retrospective, observational cross-sectional study with an analytical component. Results: The total number of leprosy patients was 369, and of these 11 were pediatric patients (2.98% with a predominance of males (8/11 from 3 to 16 years. The BI ranged from negative to 3+. 6/11 were MB. The evolution was good in all cases and two patients developed leprorreactions. The lesions were predominant in facial location. 6/11 patients had family contacts. Conclusions: Leprosy in children is more common than is reported, especially in endemic areas. In <5 years, the disease is very rare. More than half of the cases of children with leprosy have a positive contact. It is considered that in <5 years the spread is always intradomiciliary; this shows the importance of monitoring contacts, which will be possible with the determination of all stakeholders in order to banish the undetected cases and prevent damage.

  1. [The centenary of the founding of the "Clinica del Lavoro Luigi Devoto" in Milan (1902-2002). The oldest health organization in the world for the study, treatment, and prevention of occupational diseases].

    Science.gov (United States)

    Grieco, A

    2003-01-01

    The foundation of the Clinica del Lavoro by Luigi Devoto cannot be dated back to the specific date of an event or, worse, to the official inauguration as has happened so far. It can rather be considered as a process started on November 20, 1902 (date of the first resolution by the Milan Municipality Council), continuing with the national law n. 365 of July 9, 1905, then with the laying of the first stone on December 11, 1907 bearing the motto of the Milanese School "In aliis vivimus, movemur et sumus" and finally the official inauguration on March 20, 1910. The Founder Luigi Devoto was born in 1864 at Borzonasca (Genoa) and took a degree of medicine and surgery at the Genoa University in 1888. After a period in Prague and then in Genoa, he was appointed temporary teacher of medical pathology in Pavia. He published several scientific contributions in different fields of occupational health (lead intoxication, ankylostomiasis, strain cardiopathy, etc.) and in other branches (tuberculosis, pellagra, etc.) that he considered as indirectly work-related diseases. He died in Milan in 1936. Three issues characterize the ingenious intuition of Luigi Devoto and his thirty-year direction of the Clinica del Lavoro: 1. Full respect for the principles of discipline and scientific method suggested by Bernardino Ramazzini; 2. The extremely broad conception of the diseases that had to be considered as "workers' diseases"; 3. The constant social attention towards the application of scientific knowledge also through workers' information and updating of regulations to improve working conditions. Many of the conflicts and events associated with the foundation of the Clinica del Lavoro can be summarized in the name chosen by the Founder. Actually to those asking why "Clinic of Work" and not "Clinic of Workers", Devoto used to reply that it was work that was ill and therefore it was necessary to treat the work to prevent workers' illnesses.

  2. System precision assessment ExacTrac 6D® BrainLab of the Hospital das Clinicas da Faculdade de Medicina da USP; Avaliacao da precisao do sistema Exactrac 6D® BrainLab do Hospital das Clinicas da Faculdade de Medicina da USP

    Energy Technology Data Exchange (ETDEWEB)

    Maistro, Carlos E.B., E-mail: carloseduardo.bravinmaistro@gmail.com [Programa de Residencia Multiprofissional em Fisica Medica, Faculdade de Medicina de Sao Paulo, SP (Brazil); Nakandakari, Marcos V.N.; Ribeiro, Victor A.B.; Sales, Camila P. de; Rodrigues, Laura N. [Universidade de Sao Paulo (USP), SP (Brazil). Instituto de Radiologia. Servico de Radioterapia. Hospital das Clinicas

    2015-08-15

    The goal of this study was to evaluate the precision of ExacTrac 6D® Brainlab system, installed at Hospital das Clinicas da Faculdade de Medicina da USP, in frameless radiosurgery treatments. Four sets of tests were performed for different purposes in order to assess the following parameters: the accuracy of location through infrared system; evaluation of the reproducibility of fusion algorithm; evaluation of the X-ray system; and the end-to-end test with the goal of assess the overall accuracy of the system. It was found that the infrared system showed a maximum deviation of 0.5 mm in terms of positioning and the X-ray system showed a precision of 0.15 mm and 0.6°. The reproducibility of fusion algorithms provided a maximum deviation in position which was less than 0.5 mm and 0.5° and the quantitative analysis of the results for end-to-end test showed an overall accuracy of the system better than 0.8 mm. (author)

  3. [The preparation and characterization of fine dusts carried out in the Clinica del Lavoro di Milano in support of experimental studies].

    Science.gov (United States)

    Occella, E; Maddalon, G; Peruzzo, G F; Foà, V

    1999-01-01

    This paper aims to illustrate the conditions selected at the Clinica del Lavoro of the University of Milan to prepare and analyze a large number of fine dust samples produced over a period of about 50 years, that were initially used for studies within the Clinic performed in its own facilities, and since 1956 were sent to other Italian and overseas laboratories (Luxembourg, UK, Germany, Norway, Sweden, South Korea, USA). The total quantity of material distributed (with maximum size 7-10 microns) was about 2 kg and consisted of the following mineral and artificial compounds: quartz, HF-treated quartz, tridymite, HF-treated tridymite, cristobalite, chromite, anthracite, quartz sand for foundry moulds, sand from the Lybian desert, vitreous silica, pumice, cement, as well small quantities of metallic oxides, organic resins, chrysotile, crocidolite, fibres (vitreous, cotton and polyamidic). About half of the entire quantity of dusts produced consisted of partially HF-treated tridymite. Initially, research on the etiology of silicosis used quartz dust samples, simply sieved or ventilated (consisting of classes finer than 0.04 mm, containing a 15-20% respirable fraction). From 1956 to 1960 the dusts were produced by manual grinding in an agate mortar, below about 10 microns, starting from quartz from Quincinetto (near Ivrea, Province of Turin), containing about 99.5% quartz: particle size and composition were checked using an optical-petrographic technique, with identification of the free and total silica content. Subsequently, the dusts used for biological research were obtained by grinding coarse material with a cast iron pestle and planetary mills, agate and corundum jars. The grinding products were sized by means of centrifugal classification, using the selector developed by N. Zurlo, ensuring control of dust size both optically and by means of wet levigators and hydraulic classifiers (in cooperation with the Institute of Mines of Turin Polytechnic School). After 1990

  4. Clinical manifestations of peripheral nervous system involvement in human chronic chagas disease Manifestaciones clinicas de compromiso del sistema nervioso periférico en el estádio crônico de la enfermedad de Chagas

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    Osvaldo Genovese

    1996-06-01

    Full Text Available We conducted a clinical and electromyographical study in patients with Chagas' disease in the indeterminate or chronic stages of the illness. Altogether 841 patients were examined. Only 511 were admitted within the protocol; the remainder patients were rejected because they showed other causes able to damage the nervous system. Fifty two (10.17% out of the 511 patients showed signs and symptoms of peripheral nervous system involvement in the form of sensory impairment and diminished tendon jerks suggesting the presence of neuropathy. Forty five of them were submitted to a conventional electromyographical examination. Fifteen of mem showed normal results, while the remainder 30 disclosed a reduced interference pattern, being most of the remaining motor unit potentials fragmented or poliphasic, reduced sensory and motor conduction velocities and diminished amplitude of the sensory action potential. The findings suggest that some chagasic patients in the indeterminate or chronic stages of the disease may develop a clinical mild sensory-motor peripheral neuropathy.El estúdio presente fue diseftado con ei objeto de pesquizar Ia existência de manifestaciones clinicas en pacientes afectados por enfermedad de Chagas, en estádio indeterminado o crônico, que tuviesen, ai menos, 2 reacciones serologicas positivas. En total fueron examinados 841 enfermos. De ellos solo 511 fueron admitidos en ei protocolo; los restantes fueron rechazados por mostrar Ia presencia de otras causas que hubiesen podido danar su sistema nervioso. Dentro de los 511 pacientes admitidos, 52 (10.17% evidenciaron alteraciones objetivas y subjetivas de Ia sensibilidad y disminucion de los reflejos osteotendinosos. Estos signos y sintomas, que sugieren la presencia de neuropatia, podian combinarse de diferente manera. Como complemento dei examen clinico, se efectuo estúdio electromiografico convencional en 45 de estos pacientes. En 15 los hallazgos fueron normales, en tanto que en

  5. Mastite clinica caprina causada por Arcanobacterium pyogenes

    OpenAIRE

    Garino Jr,F.; R.A.T. Matos; Miranda Neto,E.G; Bernardino,J.N.N.; Santos,E.D.; Aguiar,G.M.N.

    2012-01-01

    This paper reports the occurrence of goat mastitis due to Arcanobacterium pyogenes in Paraiba State - Brazil. The diagnosis was confirmed by clinical symptoms and microbiological culture. Amastectomywasperformedasclinical treatment.

  6. Dialogo tra Epistemologia Clinica ed Epistemologia antropologica

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    Maurizia Tinti

    2013-12-01

    Full Text Available Il viaggio può assumere funzioni diverse se osservato all’interno delle discipline psicoterapeutica e antropologica: da un lato è un tipo di cura, mentre dall’altro permette lo studio di culture altre. Questo confronto introduce la comparazione tra l’esperienza della follia e quella della cultura, analizzate attraverso lo sguardo critico di Foucault e della critica post-moderna in antropologia. Esperienze, queste, che hanno in comune il fatto di essere il prodotto di discorsività “scientifiche”, positiviste, che hanno assunto un certa autorità nel parlare di determinate alterità – il medico con il “suo” folle e l’antropologo con il “suo” selvaggio –, e che sono state esperite lungo la storia delle due discipline, particolarmente in età moderna, quando stabilirono il loro apparato epistemologico e metodologico. Con la post-modernità, si realizzò quindi una svolta epistemologica secondo cui il ricercatore e l’analisi da lui prodotta non possono essere oggettivi: tanto la soggettività dello studioso quanto quella dell’oggetto di analisi contribuiscono a modificare il contesto e l’interazione tra i soggetti. La psicoterapia e l’antropologia verranno quindi considerate sul piano fenomenologico, e la produzione di sapere diverrà polifonica e condivisa.

  7. Clinica use of platelet additive solutions.

    Science.gov (United States)

    van Rhenen, Dick J

    2007-12-01

    Randomised clinical trial (RCT) to study the clinical efficacy and safety of new platelet products using platelet additive solutions are scarce. In this paper a number of recent RCT's is discussed. It can be the start of a development where new transfusion products enter a RCT before the product is applied in clinical practice.

  8. Individualization of radiographic techniques in computerized radiology; Individualizacao das tecnicas radiograficas em radiologia computadorizada

    Energy Technology Data Exchange (ETDEWEB)

    Abrantes, M.E.S.; Oliveira, A.H. de, E-mail: marcosabrantes2003@yahoo.com.br [Universidade Federal de Minas Gerais (DEN/UFMG), Belo Horizonte, MG (Brazil). Departamento de Engenharia Nuclear; Feliz, W.F.; Stoppa, L.G.; Paiva, O.A. [Universidade Federal de Minas Gerais (UFADTI/UFMG), Belo Horizonte, MG (Brazil). Hospital das Clinicas. Unidade Funcional Apoio Diagnostico e Terapeutica por Imagem; Oliveira, G.A.P. [Universidade Federal de Minas Gerais (DEN/UFMG), Belo Horizonte, MG (Brazil). Departamento de Anatomia e Imagem

    2015-07-01

    This work aims to produce information for image quality implementation in a radiology sector based on previous assessments of the images by questionnaires, acceptance and quality, as step of recognition of the parameters used in radiographic techniques. After this research data raised were divided into male group, female, PA and PF thickness, body mass index, type of biotypes, anthropomorphic parameters, body evaluation associated with the constant tension and additional filtration. The results show the predominance of the 35 and 40 constant with additional filtering from 0.5 to 1.5 mmAl, voltage for male gender (PA PF) 86-92 kV and 96-112 kV voltage for female gender of 85-98 kV and 96-112 kV, respectively. The load applied to the tube for males (PA and PF) is between 5-10 and 5-16 mA.s mA.s and for females (PA and PF) is between 6.3 to 8 mA.s and 9-14 mA.s.

  9. Workshop Euratom Directive 97/43. New trends in radiation protection in clinical practice, in research and in regulation; Giornata di studio La Direttiva Europea 97/43: nuovi orientamenti per la radioprotezione nella pratica clinica, nella ricerca e nel quadro normativo

    Energy Technology Data Exchange (ETDEWEB)

    Mazzei, F. [ed.] [Istituto Superiore di Sanita' , Rome (Italy). Lab. di Fisica

    1999-07-01

    The Euratom Directive 97/43 on health protection of individuals against the dangers of ionizing radiation in relation to medical exposure is presented. In particular the following topics are focused, with a multidisciplinary approach, on: diagnostic reference levels in radiodiagnostics and nuclear medicine; radiation protection in paediatrics, in interventional radiology and in computer tomography; radiation protection radiotherapy, radiation protection in medical research; radiation protection in prenatal and neonatal exposure; radiation protection in medical-legal exposures. [Italian] Il rapporto raccoglie una presentazione della Direttiva Euratom 97/43 riguardante la protezione sanitaria delle persone contro i pericoli delle radiazioni ionizzanti connessi a esposizioni mediche. In particolare sono affrontati in modo interdisciplinare i seguenti argomenti: livelli diagnostici di riferimento in radiodiagnostica e in medicina nucleare; radioprotezione nelle esposizioni in eta' pediatrica, in radiologica interventistica e in tomografia computerizzata; radioprotezione in radioterapia; radioprotezione nella ricerca scientifica clinica; radioprotezione nell'esposizione in eta' prenatale e neonatale; esposizioni potenziali e radioprotezione nelle esposizioni medico-legali.

  10. Isolation of Pseudomonas aeruginosa strains from dental office environments and units in Barretos, state of São Paulo, Brazil, and analysis of their susceptibility to antimicrobial drugs Isolamento de cepas de Pseudomonas aeruginosa provenientes do meio ambiente e de equipos dentarios em clinicas dentarias em Barretos, São Paulo, Brasil; analises da susceptibilidade das cepas a drogas antimicrobianas

    Directory of Open Access Journals (Sweden)

    Ana Claudia de Oliveira

    2008-09-01

    Full Text Available A wide variety of opportunistic pathogens has been detected in the tubing supplying water to odontological equipment, in special in the biofilm lining of these tubes. Among these pathogens, Pseudomonas aeruginosa, one of the leading causes of nosocomial infections, is frequently found in water lines supplying dental units. In the present work, 160 samples of water, and 200 fomite samples from forty dental units were collected in the city of Barretos, State of São Paulo, Brazil and evaluated between January and July, 2005. Seventy-six P. aeruginosa strains, isolated from the dental environment (5 strains and water system (71 strains, were tested for susceptibility to six antimicrobial drugs most frequently used against P. aeruginosa infections. Susceptibility to ciprofloxacin, followed by meropenem was the predominant profile. The need for effective means of reducing the microbial burden within dental unit water lines is emphasized, and the risk of exposure and cross-infection in dental practice, in special when caused by opportunistic pathogens like P. aeruginosa, are highlighted.Uma ampla variedade de patógenos oportunistas tem sido detectadas nos tubos de alimentação de água dos equipos odontológicos, particularmente no biofilme formado na superfície do tubo. Entre os patógenos oportunistas encontrados nos tubos de água, Pseudomonas aeruginosa é reconhecida como uma das principais causadoras de infecções nosocomiais. Foram coletadas 160 amostras de água e 200 amostras de fomites em quarenta clinicas odontológicas na cidade de Barretos, São Paulo, Brasil, durante o período de Janeiro a Julho de 2005. Setenta e seis cepas de P. aeruginosa, isoladas a partir dos fomites (5 cepas e das amostras de água (71 cepas, foram analisadas quanto à susceptibilidade à seis drogas antimicrobianas freqüentemente utilizadas para o tratamento de infecções provocadas por P. aeruginosa. As principais suscetibilidades observadas foram para a

  11. Ruolo ed organizzazione della microbiologia clinica di domani

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    Giorgio Mucignat

    2006-12-01

    Full Text Available Infectious diseases continue to represent an important preventive and clinical problem especially in the light of the emergence of new pathogens, of the return of infrequent pathogens and of the increased risk of infective pathologies associated with migratory flow. Another critical point is represented by the possible insurgence of infections due to agents used in bioterrorism. More than ever it is indispensable for our country to define a network of structures able to give an organized response to these relevant problems both in terms of prevention and assistance. It is therefore important to define a protocol for clinical microbiology on a national basis that responds to different levels of activity. Keeping in mind that the fundamental objectives of microbiology are: - diagnosis of infective diseases - determination of resistance to antimicrobic drugs as a valid instrument to allow the clinician to proceed with specific treatment - control of infection spreading in the sanitary structures (hospital infections - to develop front line defence in new infections and bioterrorism, in collaboration with the department of prevention - to be a reference centre for specific training The principals on which one must base the reorganization are essentially three: 1. to configurate the microbiology service on the basis of real needs of the local population 2. to give qualitatively optimal results in real time 3. supporting “good clinical practice” to assure adequate patient results and acceptable costs for the regionale sanitary system (SSR The organization of microbiology should therefore foresee a microbiology department, structured on a provincial basis or a vast area including a structured centralized complex with peripheral structures (even simplified. This must integrate actively with the department of prevention in regard to the dynamics of infectious diseases in the territory and with the Division of Infectious Diseases (where this exists. In parallel an active interaction with research structures (IRCCS and University present in the territory to enable the coordinated implementation of the guidelines of research and its relapse on diagnostic exams. Keeping in mind that the quality of diagnostic performance is closely linked to the professional experience of the operators it is good practice centralizing some diagnostic procedures by identifying a reference centre. In a regional network organized in this way it is important to include a coordinating structure, since it is necessary to activate a complete level of communication, information exchange, activity planning, and complete problem solving.

  12. L'Identificazione della sindrome metabolica nella pratica clinica

    OpenAIRE

    Sturani, Alessandra

    2009-01-01

    The definition of “Metabolic Syndrome” was proposed to identify those subjects at high cardiovascular risk although without any feature of actual or possible cardiovascular damage. Clinical (such as blood presure and abdominal obesity) and laboratory characteristics (such as glycemia, HDL-cholesterol, triglycerides) able to predict cardiovascular risk, either idividually or combined each other, were chosen. Despite a widespread evaluation in the context of several clinical trials, the real cl...

  13. Construcao de subconjuntos terminologicos: contribuicoes a pratica clinica do enfermeiro

    Directory of Open Access Journals (Sweden)

    Jorge Wilker Bezerra Clares

    2013-08-01

    Full Text Available A Classificação Internacional para a Prática de Enfermagem (CIPE® é um sistema de classificação unificador dos elementos da prática de enfermagem (diagnósticos, resultados e intervenções, que possibilita elucidar elementos da linguagem própria da Enfermagem por meio da construção de subconjuntos terminológicos. Neste ensaio reflexivo, destacam-se aspectos relevantes para a construção de subconjuntos terminológicos CIPE®, bem como suas contribuições para a prática clínica do enfermeiro. Discute-se a elaboração de subconjuntos como ferramenta que contribui para a universalização da linguagem da Enfermagem, facilita o processo comunicativo, bem como o avanço científico e tecnológico da profissão. Portanto, incentiva-se seu uso por enfermeiros de todo o mundo.

  14. SINDROME DE OVARIO POLIQUISTICO: PRESENTACION CLINICA, BIOQUIMICA Y ULTRASONOGRAFICA

    OpenAIRE

    Pérez C.,Jorge; Méndez R.,María J.; Fuhrer F.,Juan; Marquez N.,Juan; Cumsille,Miguel A.; Fuhrer C.,Juan

    2003-01-01

    En forma retrospectiva se efectúa una revisión de 115 historias clínicas de pacientes con Síndrome de Ovario Poliquístico (SOP) que consultan en la Unidad de Endocrinología del Servicio de Ginecología del Hospital San José en el periodo comprendido entre los años 1996 y 2002. Se determinó la prevalencia y se estableció una caracterización demográfica, hormonal y ultrasonográfica de estas pacientes. Destaca la presencia de un alto porcentaje de obesidad que alcanzó el 63% y una insulinoresiste...

  15. Enterite da Campylobacter upsaliensis: un paradigma della microbiologia clinica

    Directory of Open Access Journals (Sweden)

    Maria Letizia D’Annibale

    2006-12-01

    Full Text Available The Authors describe a case of acute enteritis in a adult woman with severe hepatitis C infection caused by a strain of Campylobacter upsaliensis.The clinical isolate was obtained only on blood agar because filter membrane technique was performed. In fact for this strain it was no growth on selective Campy agar, which include cephalotin too; C. upsaliensis is sensitive to this antibiotic molecule. So, the use of filter membrane on blood agar or charcoal agar at 37°C in microaerophilic atmosphere is recommended for isolation of all campylobacters responsible of human enteritis.

  16. Levetiracetam: review clinica ed economica di un nuovo antiepilettico

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    Orietta Zaniolo

    2004-06-01

    Full Text Available Uncontrolled epilepsy has a significant negative impact on patient’s quality of life, on his emotional well-being and his social functioning. Seizure places an undue economic burden on the patient and community. The increased costs are direct and indirect (e.g.,inpatient care and loss of earnings associated with time lost from work. Levetiracetam is a new antiepileptic drug used as adjuntive therapy in the treatment of refractory epilepsy. Its nonconventional mechanism of action is not completely understood, but preclinical studies suggest that its antiepileptic action.may depend on a reversible, saturable and stereoselective binding site in CNS membranes. In this paper, we review the main clinical and economic data available in the scientific literature. Levetiracetam has a favourable pharmacokinetic profile characterised by rapid and nearly complete absorption, very low potential for drug interactions and a prolonged pharmacodynamic effect that permits twice-daily dosing. Several placebo-controlled clinical trials have demonstrated that its efficacy has enabled many patients who were refractory to treatment with other antiepileptic drugs to achieve long-term seizure freedom; furthermore in levetiracetam trials the frequency of adverse events is low and withdrawal rates are comparable with those of placebo. A cost/effectiveness analysis compared direct medical costs of levetiracetam add-on therapy with maintenance of standard therapy alone within the UK National Health Service. A 1-year dose escalation decision model was set up in refractory patients who failed to respond to two or more other currently available therapies, with seizure freedom selected as the measure of effectiveness. Available pharmacoeconomic data show that the incremental cost of treating patients with levetiracetam is low when compared with the benefits of seizure freedom, at least in the UK. Furthermore, current studies suggest that this antiepileptic drug has a potential as first-line treatment for many types of epilepsy and in many different patient populations.

  17. La diagnostica molecolare nel laboratorio di patologia clinica veterinaria

    OpenAIRE

    Zambon, Elisa

    2015-01-01

    La prima parte del nostro studio riguarda la tecnica LAMP (Loop-mediated isothermal amplification), una tecnica di amplificazione isotermica recentemente inventata (Notomi et al., 2000). Essa presenta notevoli vantaggi rispetto alle tradizionali PCR: non necessita di strumentazioni sofisticate come i termociclatori, può essere eseguita da personale non specializzato, è una tecnica altamente sensibile e specifica ed è molto tollerante agli inibitori. Tutte queste caratteristiche fanno sì c...

  18. ENFERMEDAD DE VOGT KOYANAGI HARADA EN UNA SERIE CLINICA DE PACIENTES. EN RED DE SALUD UC: CLASIFICACION Y EVOLUCION CLINICA.

    Directory of Open Access Journals (Sweden)

    Enzo Castiglione A.

    2007-12-01

    Full Text Available La enfermedad de Vogt - Koyanagi - Harada (VKH es una panuveítisgranulomatosa bilateral con compromiso extraocular enel sistema auditivo, meníngeo y piel (1. Clínicamente se puedepresentar por ojo rojo profundo, bilateral, dolor ocular o compromisode la agudeza visual. Los hallazgos del examen clínicodependerán del estadío clínico de la enfermedad. Hay manifestacionestempranas como coroiditis (con o sin uveítis anterior o hiperemiadel disco óptico o desprendimientos retinales serosos,como también manifestaciones de enfermedad tardías: despigmentaciónocular, cicatrices coriorretinales o uveítis recurrente.Los tratamientos propuestos son múltiples: desde la observaciónhasta la corticoterapia por distintas vías de administración,inmunomoduladores, antimetabolitos o agentes alquilantes,dado que es desconocido el tratamiento más efectivo con lasmenores complicaciones a largo plazo. El diagnóstico diferencialincluye formas graves de retinopatía central serosa, traumaocular penetrante (quirúrgico o accidental y diversas causas deuveítis posterior y pan uveítis. Con el fin de definir poblacioneshomogéneas de pacientes con VKH para comenzar a desarrollarestudios clínicos y establecer de mejor manera su diagnóstico,tratamiento y pronóstico, en el año 2001 fueron replanteadoslos criterios diagnósticos de VKH por un comité internacional,determinando categorías de la enfermedad (2. Así, la enfermedadde VKH puede clasificarse como completa (enfermedad ocularmás compromiso de tegumentos y neurológicos, incompleta(enfermedad ocular más compromiso de tegumentos o compromisoneurológico y probable (enfermedad ocular pura.Nuestro objetivo fue clasificar a los pacientes con VKH evaluadosen la Red de Salud UC según los criterios del Comité Internacionalpara el estudio de la Enfermedad de VKH y evaluar susrespuestas a tratamiento y desarrollo de complicaciones.

  19. Osteosarcoma and chondrosarcoma: radiographic differentiation by means of computed tomography; Osteossarcoma e condrossarcoma - diferenciacao radiografica por meio da tomografia computadorizada

    Energy Technology Data Exchange (ETDEWEB)

    Tossato, Patricia dos Santos; Pereira, Amanda Caceres; Cavalcanti, Marcelo Gusmao Paraiso [Sao Paulo Univ., SP (Brazil). Faculdade de Odontologia. Dept. de Estomatologia

    2002-03-01

    The purpose of this paper was to associate and compare the radiographic patterns of osteosarcoma and those of chondrosarcoma by means of computed tomography (CT). Computed tomographs of five cases of osteosarcoma and five cases of chondrosarcoma of the head and neck region were analyzed. The sensitivity of CT was calculated based on the results of histopathological examinations. We concluded that CT can facilitate the establishment of the final diagnosis since it is possible to distinguish the individual characteristics of osteosarcomas and chondrosarcomas in that exam. (author)

  20. Study on radiographic and minerals characteristics of renal calculus; Estudo das caracteristicas radiograficas e minerais de calculos renais

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, Marco A.R., E-mail: mfernandes@fmb.unesp.b [Universidade Estadual Paulista Julio de Mesquita Filho (FMB/UNESP), Botucatu, SP (Brazil). Fac. de Medicina. Dept. de Dermatologia e Radioterapia; Goldberg, Jose [Universidade Estadual Paulista Julio de Mesquita Filho (FMB/UNESP), Botucatu, SP (Brazil). Fac. de Medicina. Dept. de Urologia; Sakate, Makoto [Universidade Estadual Paulista Julio de Mesquita Filho (FMB/UNESP), Botucatu, SP (Brazil). Fac. de Medicina. Dept. de Doencas Tropicais e Diagnostico por Imagem; Louzada, Mario J.Q. [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Aracatuba, SP (Brazil). Curso de Medicina Veterinaria; Fernandes, Marco F.S. [Santa Casa de Misericordia de Sao Jose do Rio Preto, SP (Brazil). Dept. de Cirurgia Geral

    2010-07-01

    Radiological Images of kidneys stones were analyzed, quantifying the optical density (D.O.) and the blackening degree in the radiographic film of the samples. Studies of the literature, analyses of samples and interviews with specialists of the Center of Sciences and Technologies of Materials (CCTM) of the Institute of Energy and Nuclear Researches (IPEN/CNEN-SP), after crystallographic analysis for absorption techniques and diffraction of ray-X, showed that D.O. of the stones it is more directly dependent of their dimensions of what of their contents concentration. It is the researchers' consensus that as larger D.O. of the radiographic image of the calculation renal, larger her density (g/cm{sup 3}) and therefore larger the importance of the application of an appropriate energy for the fragmentation of the calculation. This energy, supplied by the equipment extracorporeal shock wave lithotripsy (ESWL) it depends on several parameters inside the ones which the anatomy and the patient's position and of the own limitations of the lithotripsy equipment. This interpretation, at least for the analyzed samples, it disappoints a simplistic correlation among the parameters of the shock waves used in the lithotripsy procedures and the measures of D.O. and characteristics minerals. Another restriction factor is the discrepancy of the radiological image the kidneys stones camped in the patient, surrounded by the organs and interposed bone structures, and gotten her through the analysis of the fragments expelled after the accomplishment of ESWL, which present great variety of granulations. (author)

  1. Optimization of radiation protection in gamma radiography facilities; Otimizacao do sistema de radioprotecao nas instalacoes radiograficas de gamagrafia

    Energy Technology Data Exchange (ETDEWEB)

    Antonio Filho, Joao

    1999-07-01

    To determine optimized dose limits for workers, a study of optimization of radiation protection was undertaken in gamma radiography facilities closed, using the Technique Multiple Attributes Utility Analysis. A total of 217 protection options, distributed in 34 irradiation scenarios for tree facility types ( fixed open, moveable and closed (bunker) were analyzed. In the determination of the optimized limit dose, the following attributes were considered; costs of the protection barriers, costs attributed to the biological detriment for different alpha (the reference value of unit collective dose), size of the isolation area, constrained limits dose of annual individual equivalent doses and collective dose. The variables studied in the evaluation included: effective work load, type and activity of the sources of radiation ({sup 192}Ir and {sup 60}Co), source-operator distance related to the characteristic of the length of the command cable and the guide tube, type and thickness of the materials used in the protection barriers (concrete, barite, ceramic, lead, steel alloy and tungsten). The optimal analytic solutions obtained in the optimization process that resulted in the indication of the optimized dose limit were determined by means of a sensitivity analysis and by direct and logic evaluations, thus, independent of the values of the monetary coefficient attributed to the biological detriment, of the annual interest rate applied to the protection cost and of the type of installation studied, it was concluded that the primary limit of annual equivalent dose for workers (now 50 mSv) can be easily reduced to an optimized annual dose limit of 5 mSv. (author)

  2. Methodology to evaluation of the density in radiographic image; Metodologia para avaliacao de densidade em imagem radiografica

    Energy Technology Data Exchange (ETDEWEB)

    Louzada, M.J.Q. [UNESP, Aracatuba, SP (Brazil). Curso de Medicina Veterinaria; Pela, C.A. [Sao Paulo Univ., Ribeirao Preto, SP (Brazil). Faculdade de Filosofia, Ciencias e Letras; Belangero, W.D. [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Ciencias Medicas; Santos-Pinto, R. [UNESP, Aracatuba, SP (Brazil). Faculdade de Odontologia

    1998-12-01

    This study was designed in order to optimize the optical densitometry technique in radiographic images by the setorization of the characteristic curves of the radiographic films. We used 24 radiographs of a stepped aluminium wedge that were taken without rigorous control development and manually revealed. The densitometric values of the steps images and its thickness, for each radiographic, was utilized to generate its particular mathematics expressions that represent its characteristic densitometric curves and then it were used for setorization. The densitometric values were obtained by a Macbeth TD528 densitometer. The study showed an optimization in the representation of the relationship between the optical density of the steps images of the wedge and its correspondent thickness, provided by the setorization, with mean square error around 10{sup -5}. This optimization will allow the use of this methodology in quantitative evaluations of bone mass, by radiographic images. (author)

  3. Legionnaires' disease in the renal transplant unit of "Hospital das Clinicas, FMUSP": during a five year period (1988-1993 Doença dos legionários na Unidade de Transplante Renal (UTR do Hospital das Clínicas FMUSP, no período de 1988 a 1993

    Directory of Open Access Journals (Sweden)

    Neusa Augusta de Oliveira Mazieri

    1994-06-01

    Full Text Available Several reports have related Legionella pneumophila with pneumonia in renal transplant patients, however this association has not been systematically documented in Brazil. Therefore this paper reports the incidence, by serologycal assays, of Legionella pneumophila serogroup 1 in these patients during a five year period. For this purpose sera from blood samples of 70 hospitalized patients with pneumonia from the Renal Transplant Unit of Hospital das Clinicas, FMUSP collected at the acute and convalescent phase of infection were submitted to indirect immunofluorescence assay (IFA to demonstrate anti-Legionella pneumophila serogroup 1 antibodies. Of these 70 patients studied during the period of 1988 to 1993,18 (25.71 % had significant rises in specific antibody titers for Legionella pneumophila serogroup 1. Incidence was interrupted following Hospital water decontamination procedures, with recurrence of infections after treatment interruption. In this study, the high susceptibility (25.71% of immunodepressed renal transplant patients to Legionella pneumophila serogroup 1 nosocomial infections is documented. The importance of the implementation and maintenance of water decontamination measures for prophylaxis of the infection is also clearly evident.Embora vários trabalhos tem mostrado a presença de Legionella pneumophila associado a pneumopatias infecciosas em transplantados renais, tal associação não fora antes realizado de maneira sistemática no Brasil. Os autores julgaram oportuno a determinação da incidência por comprovação sorológica da Legionella pneumophila sorogrupo 1 em transplantados renais num período de 5 anos. Para tanto amostras de soros de 70 pacientes com pneumopatia infecciosa internados na UTR do HC-FMUSP, colhidos na fase aguda e convalescente da infecção, foram submetidas à reação de imunofluo-rescência indireta para pesquisa de anticorpos anti-Legionella pneumophila sorogrupo 1. Dos 70 pacientes

  4. Ophthalmology emergency room at the University of São Paulo General Hospital: a tertiary hospital providing primary and secondary level care Pronto-Socorro de Oftalmologia do Hospital das Clinicas da Universidade de São Paulo: um hospital terciário para atendimento de nível primário e secundário

    Directory of Open Access Journals (Sweden)

    Regina de Souza Carvalho

    2007-01-01

    Full Text Available OBJECTIVE: To assess the need for emergency care in a tertiary hospital, in the Ophthalmology Emergency Room of the University of the São Paulo Medical School General Hospital. MATERIALS AND METHODS: A cross-sectional analytic study of the treatment complexity level was carried out in a readily available sample, n = 574, of patients seen at the Ophthalmology Emergency Room of the University of São Paulo Medical School General Hospital, during a typical week. RESULTS: Of the 574 treated patients, 69.0% of the cases were diagnosed as requiring a simple treatment for their problem. The most frequent diagnoses were related to ocular inflammation and infection (55.0%, mainly including conjunctivitis (29.4% and eyelid inflammations (10.5%. Next in frequency were ocular trauma (19.2%, particularly foreign bodies on the cornea (7.5% and blunt trauma (5.2%. Refractive errors (3.1% was the most prevalent diagnosis in the "other ocular modifications" category. CONCLUSION: Most of the cases (69.0% treated at the Ophthalmology Emergency Room of the University of São Paulo Medical School General Hospital could have been diagnosed and treated in primary or secondary care units. Also, the fact that return visits to check recovery are seen in the ER demonstrates the lack of referral services. The fact that patients come to a tertiary hospital with rather simple cases shows the poor structure of the Brazilian Public Healthcare System, which overloads the tertiary care facilities, where costs for human resources, materials, and other items are higher.OBJETIVO: Verificar a necessidade de atendimento em hospital terciário de casos emergenciais do Pronto-Socorro de Oftalmologia do Hospital das Clinicas da Faculdade de Medicina da Universidade de São Paulo. MATERIAL E MÉTODO: Realizou-se um estudo transversal analítico em amostra prontamente acessível, n= 574, de pacientes emergenciais atendidos no Pronto-Socorro Oftalmológico do Hospital das Clínicas da

  5. Análisis y caracterización de la farmacoterapéutica de las heparinas de bajo peso molecular prescritas en pacientes hospitalizados en el Hospital Clínica Bíblica (Costa Rica durante el periodo de marzo a agosto del 2010 Analysis and Characterization of the Pharmacotherapy of Low Molecular Weight Heparins Prescribed in Hospitalized Patients at the Hospital ClinicaBiblica (Costa Rica from March to August 2010

    Directory of Open Access Journals (Sweden)

    Gustavo Céspedes-Orozco

    2012-03-01

    ón adecuada de la farmacoterapia con HBPM en este hospital, donde existe una alta proporción de pacientes que pueden desarrollar eventos tromboembólicos.Aim: To analyze the prescription of low molecular weight heparins in hospitalized patients at the Clinica Biblica Hospital (private hospital in Costa Rica based on the guidelines established by the American College of Chest Physicians (ACCP;2008. Material and methods: This study included 1651 hospitalized patients in the period from March to August 2010 who were treated with low molecular weight heparins, 250 patients were analyzed and randomly selected. A compilation of documents and information required for each patient for the analysis was made. Results: A total of 43% of the hospitalized patients used low molecular weight heparins (707 patients. In 91% of cases low molecular weight heparins were used with a prophylactic purpose. 2% of patients did not need to use prophylactic heparin therapy. In 90% of cases the dose was correct. 18% of cases required dose adjustments. In 80% of the patients had clinically relevant drug interactions, 4% of patients had some form of bleeding, where 2% of cases this effect was linked to the use of low molecular weight heparins. In 9% of cases in which LMWH were used as treatment were addressed in accordance with established guidelines. Conclusion: In the Hospital Clinica Biblica low molecular weight heparins were used according to the recommendations established by the guidelines of the ACCP despite the non-existence at the time of a hospital protocol. A pharmacotherapeutic analysis by the clinical pharmacist can provide important information to the medical doctor in order to take corrective and / or preventive actions associated with the correct use of medications. Make correct risk stratification and individualization of treatment facilitates proper implementation of drug therapy with low molecular weight heparins in this hospital where there is a high proportion of patients that may

  6. Biopolymer chitin: extraction and characterization; Biopolimero quitina: extracao e caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    The biopolymers are materials made from renewable sources such as soybean, corn, cane sugar, cellulose and chitin. Chitin is the most abundant biopolymer found in nature, after cellulose. The chemical structure of chitin is distinguished by the hydroxyl group, of structure from cellulose, located at position C-2, which in the chitin is replaced by acetamine group. The objective of this study was to develop the chitin from exoskeletons of Litopenaeus vannamei shrimp, which are discarded as waste, causing pollutions, environmental problems and thus obtain better utilization of these raw materials. It also, show the extraction process and deacetylation of chitosan. The extraction of chitin followed steps of demineralization, desproteinization and deodorization. Chitin and chitosan were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and the thermals properties were analyzed by thermogravimetry (TG/DTG). (author)

  7. Energetic characterization of Amazonian biomass; Caracterizacao energetica de biomassas amazonicas

    Energy Technology Data Exchange (ETDEWEB)

    Feitosa Netto, Genesio Batista; Oliveira, Antonio Geraldo de Paula; Coutinho, Hebert Willian Martins; Nogueira, Manoel Fernandes Martins; Rendeiro, Goncalo [Universidade Federal do Para (UFPA), Belem, PA (Brazil). Dept. de Engenharia Mecanica

    2006-07-01

    In order to asses the potentiality of Amazon biomasses to generate power, either to supply electric energy to the grid or as fuel to plants supplying power for off-grid location, data for their proximate analysis must be available. A literature review on the subject indicated a lack of information and data concerning typical Amazon rain forest species. This work aimed to characterize (proximate analysis) 43 Amazon species in order to evaluate the energy resource from woody biomass wastes in Amazon region. Higher heating value, carbon, volatile and ash contents were measured in a dry basis. The measurements were performed obeying the following Brazilian standards, NBR 6923, NBR 8112, NBR 8633, NBR 6922. (author)

  8. Chemical characterization of marajoara ceramics; Caracterizacao quimica da ceramica marajoara

    Energy Technology Data Exchange (ETDEWEB)

    Toyota, Rosimeiri Galbiati

    2009-07-01

    In this study the elemental concentration of Ce, Co, Cr, Cs, Eu, Fe, Hf, K, La, Lu, Na, Nd, Rb, Sc, Sm, Ta, Tb, Th, U, Yb and Zn were determined by instrumental neutron activation analysis (INAA) in 204 fragments of Marajoara archaeological ceramics, of which 156 were provided by the Archaeology and Ethnology Museum of Sao Paulo University (MAE) and 48 were provided by Dr. Denise Pahl Schaan, Marajo Museum curator. Also, 9 contemporary ceramics produced and marketed at Marajo Island were analyzed. Electron paramagnetic resonance (EPR) analyses were performed in 8 archaeological samples and 1 contemporary sample in order to identify the burning temperature of the samples. X-ray diffraction (XRD) analyses were performed in 13 archaeological samples and 2 contemporary samples for the investigation of their mineralogical composition. Mahalanobis distance was used for the study of outlier while modified filter was used for the study of the temper added to the ceramic paste. Result interpretation was performed using cluster analysis, principal components analysis and discriminant analysis. Procrustes analysis was used for variable selection and it showed that the Ce, Fe, Eu, Hf, K and Th variables are adequate for the characterization of the analyzed samples. The comparative study among the archaeological and contemporary ceramics showed the arrangement of two well-defined and close groups for the archaeological samples and a third, distant group for the contemporary ones. This result indicates that the archaeological and contemporary ceramics differ in their composition. EPR and XRD analysis were inconclusive for the differentiation of archaeological and contemporary ceramics. (author)

  9. Obtention and characterization of biodiesel; Obtencao e caracterizacao do biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Leonidas B.O. dos; Caitano, Moises; Aranda, Donato A.G.; Mothe, Cheila G. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil)

    2004-07-01

    Biodiesel is an ester resulting from the transesterification reaction of an alcohol and an oil obtained from biomass. The products of the transesterification are an ester and the glycerol. The biodiesel and the petroleum commercial diesel have similar properties, and they can be mixed and used in diesel motors. The use of biodiesel will allow a better exploration of the energetic potential of our cultures. The biodiesel has some advantages compared to others combustibles, such as adaptability to usual diesel motors and non-generation of NO{sub x} and SO{sub x} compounds. Many experiments with biodiesel have been made in Brazil since the 70's. This work made samples of biodiesel by transesterification batch reactions to many blends of soybean oil and residual fry oil, at room temperature, using mechanical mixture or magnetic agitation by a magnetic stirrer, using as catalysts sodium methoxide and potassium hydroxide. For each obtained sample tests to determine the Acidity Index (ABNT-MB-74), Saponification Index (ABNT-MB-75), Iodine Wijz Index (ABNT-MB- 77), thermal analysis by DTA and TG (TA Instruments SDT 2960, 30 to 800 deg C, 10 deg C/min at nitrogen atmosphere) and rheological test (Haake RS 150 Rheo Stress rheometer) were done. (author)

  10. Characterization of cellulose nanowhiskers; Caracterizacao do nanowhiskers de celulose

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, Nayra R.; Pinheiro, Ivanei F.; Morales, Ana R.; Ravagnani, Sergio P.; Mei, Lucia, E-mail: 25nareis@gmail.com [Universidade Estadual de Campinas (UNICAMP), SP (Brazil)

    2013-07-01

    Cellulose is the most abundant polymer earth. The cellulose nanowhiskers can be extracted from the cellulose. These have attracted attention for its use in nanostructured materials for various applications, such as nanocomposites, because they have peculiar characteristics, among them, high aspect ratio, biodegradability and excellent mechanical properties. This work aims to characterize cellulose nanowhiskers from microcrystalline cellulose. Therefore, these materials were characterized by X-ray diffraction (XRD) to assess the degree of crystallinity, infrared spectroscopy (FT-IR), transmission electron microscopy (TEM) to the morphology of nanowhiskers and thermal stability was evaluated by Thermogravimetric Analysis (TGA). (author)

  11. Correlacion clinica-patologica de corioamnionitis en pacientes que ingresan al servicio ginecologia en el año 2009 en el Hospital Universitario Clinica San Rafael

    OpenAIRE

    2011-01-01

    Este trabajo tuvo como utilidad básica determinar cuál es la correlación del diagnóstico clínico con los criterios de Gibss y con el Gold estándar que es la patología en las paciente con corioamnionitis para así poder establecer si el diagnostico se realizó en forma adecuada y cuáles son los criterios más relevantes para su diagnóstico. Dicha investigación se realizó de la siguiente manera: 1. Se Identificaron las pacientes que ingresaron al servicio de urgencias...

  12. Digital systems to acquire radiological imaging. Characteristics and quality control; Sistemas digitales de adquisicion de imagenes radiograficas. Caracteristicas y Control de Calidad

    Energy Technology Data Exchange (ETDEWEB)

    Torres Cabrera, R.; Hernando Gonzalez, I.

    2006-07-01

    Due to its special characteristics, quality control in digital radiographic systems is very important, even more than in conventional film-screen systems. Differences between digital and analogical images,a in terms of dynamics range, spatial and contrast resolution, and the flexibility of data post-processing require some actions to maintain clinical images in an optimum quality level. Revision 1 of the Spanish Protocol of Quality Control in Diagnostic Radiology includes a chapter dedicated to the quality control of these digital systems for the acquisition of radiographic images. In this paper the different parameters for quality control procedures are described. Also some difficulties to be concerned about (absence of levels of tolerance, access to the raw-data images and related information, availability of use anthropomorphic phantoms, etc, etc) are noted, as well as the most significant aspects of the differences in relation to the ana logical systems. (Author) 15 refs.

  13. Evaluation of X ray attenuation by means of radiographic images; Avaliacao da atenuacao da radiacao X por meio de imagens radiograficas

    Energy Technology Data Exchange (ETDEWEB)

    Barros, Frieda Saicla, E-mail: saicla@utfpr.edu.b [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil); Paredes, Ramon S.C., E-mail: ramon@ufpr.b [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil); Godoi, Walmor C., E-mail: walmor.godoi@gmail.co [Faculdade de Tecnologia Camoes (FATEC), Curitiba, PR (Brazil); Souza, Gabriel Pinto de [Universidade Estadual Paulista (UNESP), SP (Brazil)

    2011-07-01

    This paper's main goal is to adopt a qualitative methodology to evaluate the attenuation of x-radiation through X-ray images in polymeric materials plus residual lead. To determinate the images it was initially used an experimental setup at the Laboratory for Materials Diagnostics LACTEC. These results correspond to a more qualitative analysis, even with quantitative answers. Through analysis of radiographic images we can measure the intensity of radiation that goes through the plate, making possible to establish a relationship between the attenuation coefficient and the thickness of the material. (author)

  14. Development of a computer code for shielding calculation in X-ray facilities; Desenvolvimento de um codigo computacional para calculos de blindagem em salas radiograficas

    Energy Technology Data Exchange (ETDEWEB)

    Borges, Diogo da S.; Lava, Deise D.; Affonso, Renato R.W.; Moreira, Maria de L.; Guimaraes, Antonio C.F., E-mail: diogosb@outlook.com, E-mail: deise_dy@hotmail.com, E-mail: raoniwa@yahoo.com.br, E-mail: malu@ien.gov.br, E-mail: tony@ien.gov.br [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2014-07-01

    The construction of an effective barrier against the interaction of ionizing radiation present in X-ray rooms requires consideration of many variables. The methodology used for specifying the thickness of primary and secondary shielding of an traditional X-ray room considers the following factors: factor of use, occupational factor, distance between the source and the wall, workload, Kerma in the air and distance between the patient and the receptor. With these data it was possible the development of a computer program in order to identify and use variables in functions obtained through graphics regressions offered by NCRP Report-147 (Structural Shielding Design for Medical X-Ray Imaging Facilities) for the calculation of shielding of the room walls as well as the wall of the darkroom and adjacent areas. With the built methodology, a program validation is done through comparing results with a base case provided by that report. The thickness of the obtained values comprise various materials such as steel, wood and concrete. After validation is made an application in a real case of radiographic room. His visual construction is done with the help of software used in modeling of indoor and outdoor. The construction of barriers for calculating program resulted in a user-friendly tool for planning radiographic rooms to comply with the limits established by CNEN-NN-3:01 published in September / 2011.

  15. An automatic approach for nondestructive radiographic inspection of pipeline weld joint; Uma abordagem automatica aplicada a inspecao radiografica nao-destrutiva de soldas em tubulacoes

    Energy Technology Data Exchange (ETDEWEB)

    Felisberto, Marcelo K.; Schneider, Guilherme A.; Centeno, Tania M.; Arruda, Lucia V.R. de [Centro Federal de Educacao Tecnologica do Parana, Curitiba, PR (Brazil). CPGEI - Programa de Pos-graduacao em Engenharia Eletrica e Informatica Industrial

    2005-07-01

    The current work contributes to the research in the area of pipelines non-destructive testing by presenting new methodologies for the automatic analysis of welds radiographs. Object recognition techniques based on genetic algorithms were used for the automatic weld bead detection. In addiction, an image digital filter was also tested in the weld bead images and, as a result, supposed defects are highlighted, making them easier to be detected. These methodologies were tested for 120 digital radiographs from carbon steel pipeline welded joints. These images were acquired by a storage phosphor system, using double-wall radiographic exposing technique with single-wall radiographic viewing, according to the ASME V code. As a result, even human vision hard-perceptible defects are automatically highlighted and extracted from the whole image to be separately analyzed. (author)

  16. Radiographic evaluation of adenoidal size in children: methods of measurement and parameters of normality; Avaliacao radiografica da adenoide em criancas: metodos de mensuracao e parametros da normalidade

    Energy Technology Data Exchange (ETDEWEB)

    Araujo Neto, Severino Aires de [Centro de Assistencia Integral a Saude da Mulher (CAISM), Campinas, SP (Brazil)]. E-mail: severinoaires@hotmail.com; Queiroz, Suelio Marinho de [Tomovale, Sao Jose dos Campos, SP (Brazil); Baracat, Emilio Carlos Elias [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Ciencias Medicas. Dept. de Pediatria; Pereira, Ines Minniti Rodrigues [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Ciencias Medicas. Dept. de Radiologia

    2004-12-01

    Radiograph of the nasopharynx is still the most commonly used imaging method to investigate the adenoidal tissue. Due to the variety and complexity of proposed methods to measure the adenoid size, some radiologists prefer subjective evaluation, which can, however, be imprecise and inaccurate. We review and describe several methods to determine the adenoid size, taking into account the practicity, accuracy and precision with the aim of pointing out the best methods to be applied in daily routine practice. (author)

  17. Study of an optimization protocol for radiographic techniques in computerized radiology; Estudo de um protocolo de otimizacao para as tecnicas radiograficas em radiologia computadorizada

    Energy Technology Data Exchange (ETDEWEB)

    Abrantes, Marcos Eugenio Silva

    2015-07-01

    This work is designed to produce information for the improvement of image quality to deployment in a radiology department based on previous reviews of the images by questionnaires of acceptance and quality e recognition of the parameters used in chest radiographic techniques. The data collected were divided by male, female, PA and LAT thickness, body mass index, biotypes, anthropomorphic parameters and body evaluation associated with constant voltage and the additional filtration. The results show the predominance of 35 and 40 constants with additional filtration from 0.5 to 1.5 mmAl, voltage in male: (PA and LAT) 86-92 kV and 96-112 kV, female: 85-98 kV and 96-112 kV. The charge applied to the tube for males: (PA and LAT) 5-10 mA.s and 5-16 mA.s, female: (PA and LAT) 6.3-8 mA.s and 9-14 mA.s. Absorbed doses for males: (PA and PF) 0.04-0.17 mGy and 0.03-0.19 mGy and from female (PA and PF) from 0.03-0.22 mGy and 0, 04-0.17 mGy. This procedure can be used in radiology department to implement and acceptance in the quality of images. (author)

  18. Avaliação radiografica de duas tecnicas, para o registro da relação centrica em pacientes classe I de Angle

    OpenAIRE

    Guilherme da Gama Ramos

    2007-01-01

    Resumo: Este estudo teve como objetivo comparar, por meio de radiografias transcranianas (técnica Accurad), duas técnicas descritas na literatura para a obtenção da relação cêntrica e posição das cabeças da mandíbula nas fossas mandibulares. Uma delas, a manipulação bilateral descrita por DAWSON em 1974. A outra, um traçado gráfico dos movimentos mandibulares no plano horizontal, denominado por GYSI, em 1910, de arco gótico, obtido por meio de um dispositivo, chamado de registro intra-oral. F...

  19. Lesões desportivas no atletismo: comparação entre informações obtidas em prontuários e inquéritos de morbidade referida Lesiones deportivas en el atletismo: comparacion entre las informaciones obtenidas en historias clinicas y consultas de la morbilidad referida Sports injuries in track and field: comparison between information obtained in medical records and reported morbidity inquires

    Directory of Open Access Journals (Sweden)

    Carlos Marcelo Pastre

    2004-02-01

    ões desportivas para a população investigada.Para comprender las lesiones deportivas (LD es necesario cuantificarlas, asociandolas a factores causales particulares al esporte. Aún así, faltan registros sobre estas patologías en las instituciones deportivas, sobretodo en el atletismo brasileño, donde pocos son los clubes que poseen servicios de asistencia de la salud. La ausencia de tales registros, estudios en el área de Salud Pública, se utilizan otros recursos epidemiológicos para colectas, tales como las consultas de morbilidad referida. A partir de esta escasez de información y de la facilidad de obtención de datos junto a los propios atletas, se objetivó, para esta pesquisa, levantar informaciones sobre las LD referidas por los atletas de alto rendimento, retrocediendo ocho meses, y comparándolas con los registros de historias clínicas. Por lo tanto, fueron tomados veinticinco atletas de elite, dieciseis de género masculino y nueve del femenino, con edades de 25,7 ± 4,4 años, altura de 1,74 ± 0,10 m, peso 70,4 ± 13,15 kg e tiempo médio de entrenamiento de 8,38 ± 4,06 años. Dos fisioterapeutas fueron entrenados separadamente para recolectar información sobre LD. Uno de ellos en historias clinicas y el otro de los propios atletas a través de entrevistas (Interrogatorio de Morbidade Referida - IMR. El estudio de concordancia de respuestas para las dos formas de colecta fué realizado por el test de proporción binomial, estabeleciendose límites de 95% de confianza para la concordancia. Los resultados mostraron que en todas las variables estudiadas los valores estaban dentro de los límites de confianza estabelecidos para los tests estadísticos, siendo: 88,33% para las variables tipo de lesión o agravio y mecanismo de lesión o aumento de los síntomas, 90% para la variable calidad del reintegro a las actividades deportivas el 91,67% para las variables local anatómico y período de entrenamiento. Se concluye por lo tanto, que ha habido una elevada

  20. Corrimentos vaginais em gestantes: comparacao da abordagem sindromica com exames da pratica clinica da enfermagem

    Directory of Open Access Journals (Sweden)

    Thais Marques Lima

    2013-12-01

    Full Text Available Estudo avaliativo de abordagem quantitativa, com amostra de 104 gestantes, com o objetivo de comparar os achados de infecções vaginais em gestantes obtidos por meio do fluxograma de corrimento vaginal com exames presentes na prática clínica da Enfermagem. Os dados foram coletados por meio de entrevista e exame ginecológico realizados de janeiro a julho de 2011. O fluxograma não se mostrou eficaz na identificação de candidíase e tricomoníase, apresentou baixa sensibilidade (0,0%; 50% e valor preditivo positivo (0,0%; 3,6% para as duas infecções e baixa especificidade para tricomoníase (46%. Mostrou-se satisfatório para vaginose bacteriana, com alta sensibilidade (100%, valor preditivo negativo (100% e acurácia (74%. Conclui-se que o emprego do fluxograma precisa ser reavaliado, visto que não foi eficaz em identificar infecções importantes em gestantes. Os esforços para o desenvolvimento de testes eficazes devem ser contínuos, com intuito de prevenir a disseminação de infecções e reduzir tratamentos desnecessários.

  1. MR cholangio pancreatography: clinical applications; Colangiopancreatografia por ressonancia magnetica: aplicacoes clinicas

    Energy Technology Data Exchange (ETDEWEB)

    D`Ippolito, Giuseppe; Galvao Filho, Mario; Jesus, Paulo Eduardo Marinho de; Wolosker, Angela; Borri, Maria Lucia [Hospital Sao Luiz, Sao Paulo, SP (Brazil). Centro Diagnostico

    1998-05-01

    MR cholangio-pancreatography (MRCP) has been replacing diagnostic conventional cholangio-pancreatography. MRCP is a new, noninvasive and rapidly evolving technique for imaging diseases of the biliary tree and pancreatic ducts. Images are obtained without administration of oral or intravenous contrast. Our objective is to demonstrate the main clinical applications of MPCP, its limits and advantages over other methods. In our series of 60 patients we have detected choledocholithiasis, sclerosing cholecystitis, chronic pancreatitis, pancreatic and ampullary tumors. (author) 16 refs., 14 figs.

  2. Campylobacteriosi nel perugino nel primo biennio del nuovo secolo: alcuni aspetti e considerazioni di microbiologia clinica

    Directory of Open Access Journals (Sweden)

    Daniele Crotti

    2004-03-01

    Full Text Available 794 faecal specimens of outpatients with enteritis during 2001-02 were examined for pathogens. Campylobacter jejuni/coli (14.2% and Salmonella spp (15.1% prevailed among bacteria. 3 strains of Arcobacter butzleri were isolated too (0.4%. C. jejuni prevailed (85.7% in respect of C. coli (11.8% and A. butzleri (2.5%, as in children as in adults. C. jejuni biotype 1 was prevalent (68.6% in respect of C. jejuni b. 2 (29.4% or C. jejuni b. 3 (2.0%; also C. coli b. 1 prevailed (78.6%.The average of infected people was 4 years for children (0-14 years old and 48 for adults, with a range between 3 moths and 84 years. Regarding patterns of resistance to antibiotics, were observed 6.7% of resistance (R to erytromycin, 49.5% to norfloxacin (and similar quinolones, 37.8% to tetracycline, 31.1% to minocycline, 1.7% to amoxicyllin + clavulanate, 0.8% to gentamycin and chloramphenicole. No particular correlations were observed between age, sex, clinical findings and species or biotype of isolated Campylobacter. Concluding, the filter membrane technique is preferable for isolating these spirilla, the identification of genus and species could be rational, macrolides are always the first choice molecules for therapy when mandatory.

  3. Hidroxiapatita Porosa Coralina Hap-200. 15 Años de Aplicaciones Clinicas

    OpenAIRE

    Ramón González Santos

    2005-01-01

    La Hidroxiapatita Porosa Coralina HAP-200 es un biomaterial de implante óseo desarrollado en Cuba hace más de 15 años y se ha aplicado con éxito como sustituto del injerto óseo y como implante ocular integrado. En el presente trabajo se brinda una información resumida de los principales resultados obtenidos en la etapa de desarrollo y aplicaciones clínicas del mismo. Este biomaterial en forma de bloques y esferas con diferentes dimensiones así como granulados con distintos tamaños de las part...

  4. SOPORTE SOCIAL Y FAMILIAR: EXPERIENCIAS CON FAMILIAS DE PACIENTES ATENDIDOS EN UNA CLINICA UNIVERSITARIA

    OpenAIRE

    María Eugenia Agudelo Bedoya; María Clara Vélez,

    2016-01-01

    Este artículo está basado en una investigación realizada sobre problemáticas familiares de 133 pacientes interconsultados y atendidos por Trabajo Social en los servicios de internación de la Clínica Universitaria Bolivariana (CUB) entre febrero-julio de 2013.1 Se utilizó un diseño mixto, integrando aspectos cuantitativos y cualitativos para describir las familias, variables de la atención ofrecida por trabajo social y la manera como se organizaban las familias para el cuidado del paciente en ...

  5. A clinica como pratica arborifica e rizomorfica do trabalho em enfermagem cirurgica

    Directory of Open Access Journals (Sweden)

    Lenice Dutra de Sousa

    2013-12-01

    Full Text Available Foi realizada uma pesquisa qualitativa e exploratória, na forma de um estudo de caso, em uma unidade de internação cirúrgica de um hospital universitário, que objetivou analisar o trabalho do enfermeiro sob a ótica da produção de cuidados em saúde e do exercício da clínica. Os sujeitos do estudo foram seis enfermeiros e foram realizadas observações não participantes, pesquisa documental e entrevistas em profundidade com posterior análise textual discursiva. Verificou-se que o trabalho da enfermagem é organizado segundo duas perspectivas interconectadas e interdependentes: a do modelo clínico, que compõe a estrutura-mestre de sua prática, e uma estrutura composta por elementos múltiplos e heterogêneos. O modelo clínico de assistência organiza-se como uma estrutura centrada que possibilita a resolutividade das necessidades biológicas e atua como base para a conexão de outros saberes e práticas que expandem o fazer do enfermeiro por meio de interligações com o ambiente.

  6. Miastenia grave: avaliação clinica e terapêutica de 55 casos

    Directory of Open Access Journals (Sweden)

    Lineu Cesar Werneck

    1987-12-01

    Full Text Available Foram estudados 55 casos de miastenia grave, avaliando os sinais e sintomas clínicos que ocorreram no início e na evolução dos pacientes, bem como os procedimentos diagnósticos e avaliação das medidas terapêuticas utilizadas. No manejo dos pacientes foram utilizados anticolinesterásicos, corticoesteróides, azathioprina, plasmaferese e timectomia, sem que fosse possível encontrar relação estatística significante entre os diferentes procedimentos com respeito à resolução da doença. Dos 55 casos, 9 (16,6% obtiveram remissão total, 41 (74,5% permaneceram com a doença ativa necessitando de tratamento sintomático e 5 (9.09% faleceram. Houve relação estatística significante entre os sinais de insuficiência respiratória, crises miastênicas e timoma somente no grupo de pacientes que faleceram (um por insuficiência respiratória restritiva secundária a cifoescoliose severa, três com timoma e um caso durante a timectomia.

  7. Two patients walk into a clinic...a genomics perspective on the future of schizophrenia

    LENUS (Irish Health Repository)

    Corvin, Aiden P

    2011-11-11

    Abstract Progress is being made in schizophrenia genomics, suggesting that this complex brain disorder involves rare, moderate to high-risk mutations and the cumulative impact of small genetic effects, coupled with environmental factors. The genetic heterogeneity underlying schizophrenia and the overlap with other neurodevelopmental disorders suggest that it will not continue to be viewed as a single disease. This has radical implications for clinical practice, as diagnosis and treatment will be guided by molecular etiology rather than clinical diagnostic criteria.

  8. SOIL-TRANSMITTED HELMINTHS IN CHILDREN WITH CLINICA L SYMPTOMS OF INFECTION

    Directory of Open Access Journals (Sweden)

    Rudramuneswara Swamy

    2013-04-01

    Full Text Available ABSTRACT: The study was conducted to know the prevalence of s oil-transmitted helminths (STH in children aged 1-14 years attending outpati ents and inpatients from both urban and rural background. Out of the 550 stool samples exami ned, 450 were from the study group and 100 from the control group. All the 450 children of the study group presented one or more of the classical symptoms like abdominal pain, low grade fever, diarrhoea, dysentery, constipation and pica. Hundred children from the control group did not have any classical symptoms. Thirty five per cent from the study group and 21 per cent fro m the control group were found positive for one or more of the helminthic infection. The prevalence of Ascaris lumbricoides, Trichuris tr ichiura, Ancylostoma duodenale & Necator americanus (hookworm, Hymenolepis nana and Enterobius vermicularis were 27%, 15%, 0.4%, 2% and 0.22%, respectively in the study g roup and 15%, 10%, 4%, 2%, and 2%, respectively in the control group. Strongyloides ster coralis was not found either in the study or control groups. Helminthic infections were more comm on in 7-9 years of age group, urban children with low socio-economic strata, and with m ale preponderance. Majority of children who harboured STH were suffering from abdominal pain and low grade fever. Total 450 clinical samples (control group examined b y direct wet mount, saturated salt floatation, and formalin-ether sedimentation; and o nly 391 samples examined by Kato-Katz semiquantitative techniques. Twenty six per cent posi tive by direct wet mount, 35% by both saturated salt floatation and formalin-ether sedime ntation whereas 38% of the samples were found positive by Kato-Katz semiquantitative techniq ue. In conclusion, concentration techniques like saturated salt floatation and forma lin-ether sedimentation are the best diagnostic tools to get authentic and reliable resu lts and to rule out fallacious inference caused by relying only on direct wet mount preparation, whe reas Kato-Katz, a semiquantitative technique is the best diagnostic method to know the prevalence and intensity of the STH infection. This technique is simple, rapid, reliable, and mild infections can also be detected. No special equipment and expertise are needed and it can be performed in the field survey.

  9. The Clinicaal and Angiograghic Outcome of 290 Cases after Stent Placement in Small Coronary Vessels

    Institute of Scientific and Technical Information of China (English)

    郭文怡; 贾国良; 李伟杰; 秦涛; 李成祥; 栾荣华; 吕安林; 王小燕; 李媛

    2003-01-01

    Objectives To invest the success procedure,immediate outcome after procedure,the rate of main adverse cardiac events after procedure and restenosis after stent placement in small coronary vessels. Methods 290 patients with selected or emergency stent implantation in small vessels from April, 1997 to March, 2002. Total 299 vessels, 304 lesions and 316 stents were statisted. The successs rate of procedure, immediate outcome after procedure, the rate of main adverse cardiac events after procedure and restenosis after stent placement in small coronary vessels were assessed. The patients were followed up l month to 4 years. Re-catheter angiography were done in 122/290 patients. Results The narrow rate of lesion dropped from 89% ± 12% before procedure to 5% ±5% after procedure (diameter). 202 patients were followed up 1 month(69.7% ). 197/202 cases were survival. 5/202 cases died in 3hrs to 7days. 2/5 cases died of persistent hypotension after procedure. 1/5 case died of acute left heart failure. 2/5 cases died of sudden death. 180 cases were followed up 5 months to 4 years. The non-event survival (NES) rate was 73.3% (132/180). The re-angiography were done in 122 cases. Restenosis happened in 39 cases (30.3%). 37 patients repeated PCI. 2 patients went to CABG. 2 cases got angina recurrence and were proved second time restenosis by re-angiography. The third time PCI was done in 1 patient. The other patients went to CABG. 1 case died of chronic heart failure after 2 years. 1 case suffered acute myocardial infarction on artery stent implanted. Conclusions There are high success rate of procedure and perfect immediate outcome in stent placement in small vessels.Main adverse cardiac events did not increased. Non-event survial was satisfied in long term follow - up.Restenosis rate was showed slightly higher than the one of main vessels.

  10. Policitemia vera - caracterização clinica e molecular e novas abordagens terapêuticas

    OpenAIRE

    Amaral, Cecília Beatriz Alves

    2009-01-01

    Dissertação de mestrado integrado em Medicina (Hematologia), apresentado á Faculdade de Medicina da Universidade de Coimbra. A Policitemia Vera (PV) é uma doença clonal de etiologia desconhecida, na maior parte dos casos, que envolve a célula estaminal progenitora hematopoiética multipotencial. É uma neoplasia mieloproliferativa crónica (NMP) que se caracteriza pela expansão das três linhas celulares hematopoiéticas: eritróide, granulocítica e megacariocítica, com predomínio da primeira, d...

  11. Coronary CT: clinical indications and future directions; Tomografia de coronarias: indicacoes clinicas e perspectivas futuras

    Energy Technology Data Exchange (ETDEWEB)

    Nomura, Cesar H.; Serpa, Bruna S.; Kay, Fernando U.; Szarf, Gilberto; Passos, Rodrigo B.; Neto, Roberto S.; Chate, Rodigo C.; Funar, Marcelo B., E-mail: cesarnomura@gmail.com [Hospital Israelita Albert Einstein, Sao Paulo, SP (Brazil); Cury, Roberto C. [Hospital Samaritano, Sao Paulo, SP (Brazil)

    2011-01-15

    Multidetector computed tomography (MDCT) has started its implementation in cardiology with calcium quantification of coronary plaques in the study without contrast, using the calcium score, demonstrating an important independent predictor of future cardiac events. The examination with intravenous contrast, coronary angiography, appeared later as a noninvasive method for evaluation of anatomy and obstructive coronary disease, characterizing the degree of stenosis and the presence of non calcified atherosclerotic plaques, assessing not only the lumen, but also the vessel wall. With the advent of new machines with more detectors and higher temporal resolution has been a reduction in radiation dose and the possibility of new applications. (author)

  12. Psicoterapia breve gestaltica para homens com HIV/AIDS em contexto de clinica ampliada

    OpenAIRE

    LOBO, Warlington Luz

    2013-01-01

    O presente trabalho visou investigar qual a importância da Psicoterapia em homens doentes de aids marcados pela proximidade com a morte ou a finitude existencial internados em uma enfermaria hospitalar. A intervenção psicológica, na área da saúde e da clínica psicológica, foi procedimento interventivo que permitiu efetivar a escuta socialmente engajada visando superar a premissa acerca da doença enquanto centro do tratamento, transmitida ao longo da história e veiculando a concepção de um suj...

  13. Guías clinicas de RCP y SRI enfermería

    OpenAIRE

    Donis Mulero, Elena

    2015-01-01

    La reanimación cardiopulmonar (RCP) es un procedimiento de emergencia para salvar vidas que se lleva a cabo cuando una persona se encuentra en parada cardiorrespiratoria (PCR). Tanto la técnica de RCP como la de intubación, son aspectos olvidados por los profesionales de la salud. Recopilar las últimas recomendaciones sobre RCP para poder elaborar un programa sencillo enfocado a la enfermería. Elaborar una guía sencilla de secuencia rápida de intubación (SRI). Revisión bibliográfica en la que...

  14. Radio sterilized human ligaments and their clinical application;Ligamentos humanos radioesterilizados y su aplicacion clinica

    Energy Technology Data Exchange (ETDEWEB)

    Luna Z, D.; Reyes F, M. L. [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico); Diaz M, I.; Hernandez R, G., E-mail: daniel.luna@inin.gob.m [Centro Estatal de Trasplantes del Estado de Mexico, Pablo Sidar No. 602, Col. Universidad, 50130 Toluca, Estado de Mexico (Mexico)

    2009-10-15

    The ligaments are human tissues that are used in the transplantation area. A ligament is an anatomical structure in band form, composed by resistant fibers that connect the tissues that unite the bones with the articulations. In an articulation, the ligaments allow and facilitate the movement inside the natural anatomical directions, while it restricts those movements that are anatomically abnormal, impeding lesions that could arise of this type of movements. The kneecap ligament is a very important tissue in the knee mobility and of walking in the human beings. This ligament can injure it because of automobile accidents, for sport lesions or illnesses, and in many cases the only form of recovering the knee movement is carried out a transplant with the purpose of replacing the damage ligament by allo gen kneecap ligament processed in specialized Tissue Banks where the tissue is sterilized with gamma radiation of {sup 60}Co at very low temperatures, obtaining high quality ligaments for clinical application in injured patients. The kneecap ligaments are processed in the Tissue Banks with a segment of kneecap bone, a segment of tibial bone, the contained ligament between both bones and in some cases a fraction of the quadriceps tendon. In this work is given a description of the selection method of the tissue that includes the donor's serologic control, the kneecap ligament processing in the Radio Sterilized Tissues Bank, its sterilization with gamma radiation of {sup 60}Co, also it is indicated like the clinical application of the allo gen ligament was realized in a hasty patient and whose previous crossed ligament was injured. Finally the results are presented from the tissue obtaining until the clinical application of it is, and in this case is observed a favorable initial evolution of the transplantation patient. (Author)

  15. The equivalent Histograms in clinical practice; Los histogramas equivalentes en la practica clinica

    Energy Technology Data Exchange (ETDEWEB)

    Pizarro Trigo, F.; Teijeira Garcia, M.; Zaballos Carrera, S.

    2013-07-01

    Is frequently abused of The tolerances established for organ at risk [1] in diagrams of standard fractionation (2Gy/session, 5 sessions per week) when applied to Dose-Volume histograms non-standard schema. The purpose of this work is to establish when this abuse may be more important and realize a transformation of fractionation non-standard of histograms dosis-volumen. Is exposed a case that can be useful to make clinical decisions. (Author)

  16. Two patients walk into a clinic...a genomics perspective on the future of schizophrenia

    Directory of Open Access Journals (Sweden)

    Corvin Aiden P

    2011-11-01

    Full Text Available Abstract Progress is being made in schizophrenia genomics, suggesting that this complex brain disorder involves rare, moderate to high-risk mutations and the cumulative impact of small genetic effects, coupled with environmental factors. The genetic heterogeneity underlying schizophrenia and the overlap with other neurodevelopmental disorders suggest that it will not continue to be viewed as a single disease. This has radical implications for clinical practice, as diagnosis and treatment will be guided by molecular etiology rather than clinical diagnostic criteria.

  17. [Food status peculiarities, anthropometric, clinica and biochemical indices at professional sportsmen].

    Science.gov (United States)

    Gapparova, K M; Nikitiuk, D B; Zaĭnudinov, Z M; Tserekh, A A; Chekhonina, Iu G; Golubeva, A A; Sil'vestrova, G A; Rusakova, D S; Grigor'ian, O N

    2011-01-01

    Under steady state conditions in 66 athletes involved in weightlifting, bodybuilding, judo and taekwondo have studied features of the metabolic status. Data on matter-of-fact nutrition, body weight content within the inter-competition period, energy exchange, clinical and biochemical indices and physical acceptability indices were analyzed. As a result, the decrease indexes of metabolism at all the sportsmen and high-level caloric value at sportsmen who are engaged in weightlifting, which corresponds their energy expenditures, was revealed.

  18. Hepatitis C Virus-related Mixed Cryoglobulinemia: Pathogenesis, Clinica Manifestations, and New Therapies.

    Science.gov (United States)

    Schamberg, Neal J; Lake-Bakaar, Gerond V

    2007-09-01

    Within the past decade, it has been recognized that a majority of patients with essential mixed cryoglobulinemia (MC) are chronically infected with hepatitis C virus (HCV). Although the underlying mechanisms have not been fully elucidated, cryoglobulin formation is clearly linked to the attempt of the host to clear the significant quantities of virions generated daily by the chronic infection. This review summarizes the current understanding of the relationship between chronic HCV infection and the development of MC, and discusses the interaction between the immune system and HCV and how this interaction can lead to the development of lymphoproliferative disorders.

  19. [Alarming signs and symptoms in the early diagnostics of late onset Pompe disease: super omnia clinica].

    Science.gov (United States)

    Nikitin, S S; Kurbatov, S A; Bredelev, V A; Kovalchuk, M O

    2015-01-01

    Pompe disease (PD) is a rare autosomal recessive muscle lysosomal glycogenosis caused by a deficiency of acid-α-glucosidase. There are two main forms of the disease: aggressive infantile PD started within the first year of life with a severe enzyme deficiency and multiorgan involvement, and late onset PD (LOPD) with progressive signs and symptoms including predominant proximal, axial muscle weakness and respiratory insufficiency started at any time from 1 till 75 years and older. Usually due to physician's unawareness, most adults with PD are diagnosed with great delay. The typical features and early nonspecific signs in four patients, aged between 35 and 72 years, with confirmed LOPD are delineated and discussed in correspondence with the age of first signs, age development of muscle weakness, distribution and age of final diagnosis. The disorders for differential diagnosis and spectrum of conditions that expanded the possibility of PB are listed. The fluorometrically analyzed level of acid α-glucosidase from dried blood spots is considered to be the first choice diagnostic method for clinically suspected cases of LOPD.

  20. CONSENTIMIENTO INFORMADO EN LA PRÁCTICA CLINICA: RETOS DEL PERSONAL DE SALUD

    Directory of Open Access Journals (Sweden)

    Francisco Javier Bonilla Escobar

    2013-08-01

    Full Text Available El consentimiento informado es una herramienta cotidiana en la práctica clínica; para comprenderlo se requiere de un proceso formativo y académico que genere las actitudes para proponer consentimientos informados éticamente aceptables y que estos abarquen la perspectiva del paciente. El consentimiento requiere de un uso adecuado y de su entendimiento por parte del paciente como del profesional de salud que lo administra, siendo de utilidad ética y legal, motivo por el cual no debe ser subestimado. Es importante que dicho conocimiento implique en forma clara el reconocimiento tanto del médico como del paciente de la(s intervención(es, de las posibles consecuencias y situaciones a las que pudiera estar expuesto. Este artículo es una revisión al respecto del consentimiento informado, partiendo de su historia, evolución e implicaciones para el personal de la salud en general, con el objetivo de orientar e informar sobre su uso y evolución en la práctica clínica. El área bioética y los temas concernientes al consentimiento informado son necesidades de difusión e investigación en Latinoamérica para la protección del paciente y la buena práctica del personal de salud.

  1. Fracture liaison service in a non-regional orthopaedic clinic--a cost-effective service.

    LENUS (Irish Health Repository)

    Ahmed, M

    2012-01-01

    Fracture liaison services (FLS) aim to provide cost-effective targeting of secondary fracture prevention. It is proposed that a dedicated FLS be available in any hospital to which a patient presents with a fracture. An existing orthopaedic clinic nurse was retrained to deliver a FLS. Proformas were used so that different nurses could assume the fracture liaison nurse (FLN) role, as required. Screening consisted of fracture risk estimation, phlebotomy and DXA scanning. 124 (11%) of all patients attending the orthopaedic fracture clinic were reviewed in the FLS. Upper limb fractures accounted for the majority of fragility fractures screened n=69 (55.6%). Two-thirds of patients (n=69) had reduced bone mineral density (BMD). An evidence based approach to both non-pharmacological and pharmacotherapy was used and most patients (76.6%) receiving pharmacotherapy received an oral bisphosphonate (n=46). The FLS has proven to be an effective way of delivering secondary prevention for osteoporotic fracture in a non-regional fracture clinic, without increasing staff costs.

  2. Applicazione della spettrometria di massa MALDI-TOF in microbiologia clinica

    OpenAIRE

    Piergianni, Maddalena

    2016-01-01

    Riassunto La spettrometria di massa (MS) nata negli anni ’70 trova oggi, grazie alla tecnologia Matrix-Assisted Laser Desorption Ionization-Time of Flight (MALDI-TOF), importanti applicazioni in diversi settori: biotecnologico (per la caratterizzazione ed il controllo di qualità di proteine ricombinanti ed altre macromolecole), medico–clinico (per la diagnosi di laboratorio di malattie e per lo sviluppo di nuovi trattamenti terapeutici mirati), alimentare ed ambientale. Negli ultimi ann...

  3. CONSENTIMIENTO INFORMADO EN LA PRÁCTICA CLINICA: RETOS DEL PERSONAL DE SALUD

    Directory of Open Access Journals (Sweden)

    Francisco Javier Bonilla Escobar

    2012-01-01

    Full Text Available El consentimiento informado es una herramienta cotidiana en la práctica clínica; para comprenderlo se requiere de un proceso formativo y acadé- mico que genere las actitudes para proponer consentimientos informados éticamente aceptables y que estos abarquen la perspectiva del paciente. El consentimiento requiere de un uso adecuado y de su entendimiento por parte del paciente como del profesional de salud que lo administra, siendo de utilidad ética y legal, motivo por el cual no debe ser subestimado. Es importante que dicho conocimiento implique en forma clara el reconoci- miento tanto del médico como del paciente de la(s intervención(es, de las posibles consecuencias y situaciones a las que pudiera estar expuesto. Este artículo es una revisión al respecto del consentimiento informado, partiendo de su historia, evolución e implicaciones para el personal de la salud en general, con el objetivo de orientar e informar sobre su uso y evolución en la práctica clínica. El área bioética y los temas concernientes al consentimiento informado son necesidades de difusión e investigación en Latinoamérica para la protección del paciente y la buena práctica del personal de salud.

  4. Hidroxiapatita Porosa Coralina Hap-200. 15 Años de Aplicaciones Clinicas

    Directory of Open Access Journals (Sweden)

    Ramón González Santos

    2005-01-01

    Full Text Available La Hidroxiapatita Porosa Coralina HAP-200 es un biomaterial de implante óseo desarrollado en Cuba hace más de 15 años y se ha aplicado con éxito como sustituto del injerto óseo y como implante ocular integrado. En el presente trabajo se brinda una información resumida de los principales resultados obtenidos en la etapa de desarrollo y aplicaciones clínicas del mismo. Este biomaterial en forma de bloques y esferas con diferentes dimensiones así como granulados con distintos tamaños de las partículas ha sido evaluado teniendo en cuenta todos los parámetros de su comportamiento "in vivo" tanto preclínico como clínico según exigen las normas de evaluación y registro de biomateriales del CCEEM del MINSAP de Cuba. Se han realizado varios protocolos de ensayos clínicos, tanto controlados como multicéntricos, de postproducción, de seguimiento y estudio del comportamiento clínico a largo plazo, de extensión e introducción en el sistema nacional de salud así como los estudios y diseño del sistema productivo y de gestión de la calidad que avalan la obtención de varios certificados de registro sanitario tanto en Cuba como en el extranjero así como los certificados de buenas prácticas de fabricación. Durante los 15 años de aplicaciones clínicas en Cuba se han tratado 9 613 pacientes en las especialidades de estomatología, incluyendo la cirugía maxilofacial, 783 personas han recibido implantes oculares y 2 592 han sido tratadas por defectos óseos de los huesos largos y otros en ortopedia y traumatología. Solo se ha reportado un 3,2 % de fracaso de los implantes por diferentes causas asociadas al tratamiento quirúrgico y en ningún caso por causa del biomaterial, demostrando este último una excelente biocompatibilidad con integración e incorporación a la dinámica natural del tejido óseo al cabo del tiempo. Los resultados obtenidos son excelentes tanto desde el punto de vista de las características y propiedades del biomaterial como de su comportamiento ¿in vivo¿ y el impacto en la salud y calidad de vida de nuestra población.

  5. Epidemiology of septic arthritis of the knee at Hospital das Clinicas, Universidade de Sao Paulo

    Directory of Open Access Journals (Sweden)

    Camilo Partezani Helito

    2014-01-01

    Full Text Available Background: Septic arthritis is an infrequent disease although very important due to the possibility of disastrous outcomes if treatment is not adequately established. Adequate information concerning the epidemiology of septic arthritis is still lacking due to the uncommon nature of the disease as well as the struggle to establish a correct case-definition. Objective: To epidemiologically characterize the population seen at Hospital das Clínicas, University of São Paulo with a diagnosis of septic arthritis between 2006 and 2011. Methods: Sixty-one patients diagnosed with septic arthritis of the knee between 2006 and 2011 were retrospectively evaluated. The patients' clinical and epidemiological characteristics, the microorganisms that caused the infection and the patients' treatment and evolution were analyzed. Results: Septic arthritis of the knee was more common among men, with distribution across a variety of age ranges. Most diagnoses were made through positive synovial fluid cultures. The most prevalent clinical comorbidities were systemic arterial hypertension and diabetes mellitus, and the most commonly reported joint disease was osteoarthritis. Staphylococcus aureus was the prevailing pathogen. Fever was present in 36% of the cases. All patients presented elevation in inflammatory tests. Gram staining was positive in only 50.8% of the synovial fluid samples analyzed. Six patients presented complications and unfavorable evolution of their condition. Conclusion: S. aureus is still the most common pathogen in acute knee infections in our environment. Gram staining, absence of fever and normal leukocyte count cannot be used to rule out septic arthritis.

  6. Development of practical digital radiographic image viewing and commitment dose/image quality; Desarrollo de practicas de visualizacion de imagenes radiograficas digitales y su compromiso dosis/calidad de imagen

    Energy Technology Data Exchange (ETDEWEB)

    Chinillach Ferrando, N.; Salvador, R.; Diez, S.; Reinado, D.; Cortina, T.; Lopez, F. J.; Jover, A.; Cebrian, R.; Gonzalez, R.; Dalmases, F.; Romero, C.; Rosello, J.

    2011-07-01

    Today it is essential to use X-ray diagnosis in health, so it is essential that professionals have a strong background in all aspects of radiological images dependent. It is also necessary to understand the dependence between dose and image quality and thus introduce the concept of optimization in the performance of radiologic studies, from a simple test to a complex, establishing a dependency between patient dose and the aim of the study to be performed.

  7. Correction of the counting up number by dead time in detector systems for radiograph images; Correccion del numero de conteos por tiempo muerto en sistemas detectores para imagenes radiograficas

    Energy Technology Data Exchange (ETDEWEB)

    Cerdeira E, A. [Telital Spa, Trieste (Italy); Cicuttin, A. [Laboratory of Microprocessors, ICTP-INFN, Trieste (Italy); Cerdeira, A.; Estrada, M.; Luca, A. de [Depto. de Ingenieria Electrica, 07000 Mexico D.F. (Mexico)

    2002-07-01

    The effect of the dead time in a detection system by counting up of particles and the contribution of this error in the final image resolution is analysed. It is given a statistical criteria for the optimization of electronic parameters such as dead time and counting up memory which help in the implementation of these systems with the minimum necessary characteristics which satisfy the resolution requirements. (Author)

  8. Calculation of the thicknesses of the walls of the radiographic inspection building of the NKS enterprise; Calculo de los espesores de los muros del edificio de inspeccion radiografica de la empresa NKS

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez A, G.; Gutierrez R, C

    1983-07-15

    During the month of February, 1983, the Structural Civil Department of the Latin American of Engineering, S.A. de C.V. company (LATISA), outline to the Engineering and Industry Applications Management of the ININ that the industrial group NKS had taken charge them the design of a building where it would lodge a linear electron accelerator of 4 MeV, one source of Co-60 of 30 Ci and an X-ray equipment, tube type, of range of 60 to 300 KV and that to make the design they required to know the necessary thickness of the walls, doors and roof to protect to the workers, outside of the building, of the X and gamma radiations generated by the sources mentioned during the radiographic inspections of metal-mechanical pieces. (Author)

  9. Determination of bone mineral density of the distal extremity of the radio in Rottweiller, by radiographic optic densitometry;Determinacao da densidade mineral ossea da extremidade distal do radio de caes da raca Rottweiller, por meio da densitometria optica radiografica

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Jefferson Douglas Soares, E-mail: radiologia@unifeob.edu.b [Fundacao de Ensino Octavio Bastos (UNIFEOB), Sao Joao da Boa Vista, SP (Brazil). Fac. de Medicina e Veterinaria; Sterman, Franklin de Almeida [Universidade de Sao Paulo (USP), Butanta, SP (Brazil). Fac. de Medicina Veterinaria e Zootecnia. Dept. de Cirurgia

    2010-06-15

    This study allowed the standardization of the bone mineral density (BMD) of the distal extremity of the radio of 36 dogs adults in Rottweiler breed by radiographic optic densitometry. The limbs of the animals were radiographed with scale of aluminum that served as a reference. The radiographs images were digitalized and analyzed by a computer program for comparison of gray tones between the standard image and the image of the reference scale radiographed with the bone. Afterwards the values of density were expressed in millimeters of aluminum. Also studied the correlations between BMD and the sex, weight and external measures as the length of spine, height of the animal and circumference the distal extremity of the limb in study. The mean values and standard deviations of the bone mineral density of the distal extremity of the radio were: for the metaphyseal region the average of BMD of 7,88+-0,89 mmAl, the diaphyseal region 1 the average of BMD of 8,58+-0,80 mmAl and for diaphyseal region 2 of BMD of 9,00+-0,74 mmAl. (author)

  10. Positron Emission Tomography (PET) in the oncologic clinical practice; Tomografia por Emision de Positrones (PET) en la practica clinica oncologica

    Energy Technology Data Exchange (ETDEWEB)

    Serna M, J.A.; Luviano, C.; Martinez V, D. [Hospital Angeles del Pedregal Mexico DF (Mexico); Maldonado S, A. [Centro PET Complutense, Madrid (Spain)

    2005-07-01

    We intended to determine the frequency with that the computer axial tomography (TAC), it was able to visualize the lesions extra neoplasia detected by the PET tomography in patients with fully identified primary malignant neoplasia. (Author)

  11. Selection, processing and clinical application of muscle-skeletal tissue; Seleccion, Procesamiento y Aplicacion Clinica de Tejido Musculo-Esqueletico

    Energy Technology Data Exchange (ETDEWEB)

    Luna Z, D.; Reyes F, M.L.; Lavalley E, C.; Castaneda J, G. [ININ, Carretera Mexico-Toluca s/n, 52750 La Marquesa, Ocoyoacac, Estado de Mexico (Mexico)]. e-mail: dlz@nuclear.inin. mx

    2007-07-01

    Due to the increase in the average of the world population's life, people die each time to more age, this makes that the tissues of support of the human body, as those muscle-skeletal tissues, when increasing the individual's age go weakening, this in turn leads to the increment of the illnesses like the osteoporosis and the arthritis, that undoubtedly gives as a result more injure of the muscle-skeletal tissues joined a greater number of traffic accidents where particularly these tissues are affected, for that the demand of tissues muscle-skeletal for transplant every day will be bigger. The production of these tissues in the Bank of Radio sterilized Tissues, besides helping people to improve its quality of life saved foreign currencies because most of the muscle-skeletal tissues transplanted in Mexico are of import. The use of the irradiation to sterilize tissues for transplant has shown to be one of the best techniques with that purpose for what the International Atomic Energy Agency believes a Technical cooperation program to establish banks of tissues using the nuclear energy, helping mainly to countries in development. In this work the stages that follows the bank of radio sterilized tissues of the National Institute of Nuclear Research for the cadaverous donor's of muscle-skeletal tissue selection are described, as well as the processing and the clinical application of these tissues. (Author)

  12. L’emergenza della resistenza batterica agli antibiotici e il suo impatto sul laboratorio di microbiologia clinica*

    Directory of Open Access Journals (Sweden)

    Pietro E. Varaldo

    2003-03-01

    Full Text Available Le riflessioni qui riportate sono state elaborate, in parte, in occasione di riunioni dell’AMCLI Marche (Jesi, 19.10.2001 e del Comitato AMCLI per lo Studio degli Antibiotici (CoSA (Milano, 11.12.2001 e Firenze, 11.4.2002 e, in parte, in un Leading Article su Journal of Antimicrobial Chemotherapy (Varaldo PE.Antimicrobial resistance and susceptibility testing: an evergreen topic. J.Antimicrob. Chemother. 2002; 50: 1-4.

  13. [Instituto de Investigaciones Clinicas "Dr. Américo Negrette": 55 years of excellent research versus global economic recession].

    Science.gov (United States)

    Valero Cedeño, Nereida Josefina

    2014-12-01

    The Instituto de Investigaciones Clínicas "Dr. Américo Negrette" belongs to the Faculty of Medicine at University of Zulia in Maracaibo, Zulia State, Venezuela. It was created on December 4, 1959 by Dr. Américo Negrette. Today, with 55 years of existence, the Institute seeks to fulfill the mission that characterizes it, based on the values instilled by its founder and maintained by subsequent generations, whose research projects are implemented through seven research sections: Biochemistry, Hematologic Research, Neuropharmacology and Neuroscience, Immunology and Cell Biology, Clinical Neurochemistry, Parasitology and Virology. The research originated in these laboratories have become national and international points of reference, despite the current economic situation with budget deficits that put at risk the quality and originality of their projects with negative consequences on the productivity and applications for health population, reasons of biomedical research.

  14. Recuperación Clinica Pero No Cognitiva En Esquizofrenia A Traves De La Experiencia Del Cine De Ficcion

    Directory of Open Access Journals (Sweden)

    J. Peña

    2015-12-01

    Discusión: Una intervención breve basada en actividades de la vida diaria puede ser transformada en herramienta eficaz de rehabilitación psiquiátrica. Sin embargo, con las características actuales y en la muestra de este estudio, la misma intervención no aportó beneficios en parámetros de cognición.

  15. Frecuencia y tiempo promedio para la rehabilitación postendodontica en una Clinica Dental Docente Peruana

    OpenAIRE

    Oliveira-Ruiz, Gaby; Machicao-Chacon, Norka Giuliana; Hernández-Añaños, Juan Felipe

    2016-01-01

    Objetivo: Determinar la frecuencia del tipo de rehabilitación y tiempo promedio que pasa desde la obturación de los conductos radiculares y la rehabilitación postendodóntica en la clínica dental docente de la Facultad de Estomatologia de la Universidad Peruana Cayetano Heredia en el año 2012. Materiales y Métodos: Se revisaron historias clínicas de pacientes atendidos en el Pregrado y en el Postgrado en el año 2012. Muchas historias clínicas fueron excluidas, debido a que no especifi caba dat...

  16. Leitura rapida do KDIGO 2012: Diretrizes para avaliacao e manuseio da doenca renal cronica na pratica clinica

    Directory of Open Access Journals (Sweden)

    Gianna Mastroianni Kirsztajn

    2014-03-01

    Full Text Available Os autores desta "leitura rápida" apresentam os dados que consideraram mais relevantes na versão 2012 do KDIGO referente à avaliação e manuseio da doença renal crônica. Não se trata da opinião dos autores, mas sim de uma apresentação mais concisa das diretrizes, que podem ser úteis na prática clínica.

  17. APRENDIZAJE COOPERATIVO SOBRE LA PRÁCTICA CLINICA EN ENFERMERÍA: EVALUACIÓN DE DOCENTES

    Directory of Open Access Journals (Sweden)

    María-Aurora Rodríguez Borrego

    2011-01-01

    Full Text Available El proyecto se desarrolló entre las Universidades de Córdoba y A Coruña en España y consistió en una experiencia de aprendizaje cooperativo intercultural e Interuniversitario con alumnos/as del primer curso de la Diplomatura de Enfermería que estaban realizando sus prácticas clínicas, con los objetivos de encontrar puntos de encuentro a la habitual distorsión entre teoría y práctica que detecta el alumnado cuando realiza sus primeras prácticas clínicas, trabajar en grupo cooperativo y ganar habilidad para la crítica y la autocrítica. Se presenta la evaluación de la experiencia por los docentes participantes con el modelo DAFO (Dificultades, Amenazas, Fortalezas y Oportunidades. Para los alumnos, el encuentro de la igualdad en la diferencia se constituyo en una gran oportunidad de aprendizaje, si bien contrastó con la dificultad de trabajar en grupo cooperativo. Como conclusión se puede decir que el método docente empleado mostró su efectividad y su dificultad.

  18. Phyllodes tumor: clinical, radiological and pathological correlation in 50 cases; Tumor filodes: correlacion clinica, radiologica y anatomopatologica en 50 casos

    Energy Technology Data Exchange (ETDEWEB)

    Higueras, A.; Alvarez, M.; Jimenez, A.; Garcia Revillo, J.; Cano, A. [Hospital Universitario Reina Sofia. Cordoba (Spain)

    2000-07-01

    To review the radiological features of the phyllodes tumor, correlating them with the clinical presentation, histological type and response to treatment. Fifty phyllodes tumors in 29 patients aged 16 to 59 years (mean: 41 years) were analyzed retrospectively. The series included 12 cases of recurrence, 1 of bilateral tumor and 6 of multiple tumor. Forty-five lesions were studied by mammography and 36 by ultrasound. Clinically guided fine-needle aspiration cytology was performed in 8 cases. The pathological diagnosis was obtained by means of surgical biopsy in every case (31 benign and 19 malignant). Twenty-four patients underwent postoperative clinical and radiological follow-up for a mean period of 32 months. Mammography revealed the presence of a nodule or mass in 42 cases, asymmetrical density in two and a generalized increase in density in one: Multifocal lesions were detected in six cases. The size varied widely, with masses measuring >5 cm showing a greater probability of malignancy (p<0.01). Calcifications were observed in 13% of the cases. Ultrasound revealed the presence of heterogeneous, hypoechoic nodules, with cystic areas in five tumors, all of which were malignant (p<0.01). Local recurrence was detected in 31% of the cases and bone metastases in one. The phyllodes tumor is an uncommon fibroepithelial tumor that has a potential for recurrence and distant metastasis. Mammographic and ultrasound features are similar to those of the fibroadenoma, a lesion with which it is occasionally associated. Multiple lesions are not infrequent and it can present with calcifications. The presence of cystic areas and a tumor size of >5 cm are the only radiological findings that are statistically associated with malignancy. The recurrence rate is greater in malignant tumors than in benign lesions, especially in patients treated by tumor resection. (Author) 28 refs.

  19. Design and construction of ophthalmic simulators for clinical applications; Projeto e confeccao de simuladores oftalmicos para aplicacoes clinicas

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez, Andrea

    2006-07-01

    This work presents a calculational methodology for dose determination in human eye structures, such as: sclera, choroid, retina, lens, vitreous body, optic nerve and disc, and cornea, as well as tumor due to treatment to the eye plaques. A human eye model was constructed taking into consideration its main structural and dimension characteristics. Beyond that a mathematical model for the Co-60 and 1-125 plaques with all geometric details were built employing the MCNP-4C code. This model is able to calculate the axial and radial doses in any point of the eye and for each of its structures. An acrylic eye simulator was also built with the aim to obtain experimental results for the both model validations. This simulator is made of an acrylic sphere split into foils of 1 mm thickness which allow the introduction of a radiographic film to measure the axial and radial doses. The experimental data were used to validate the MCNP-4C results. The data from the mathematical model will serve as the basis to build a data bank for all the eye structures allowing different position and sizes of tumor as well as the replacement of all ophthalmic plaques used in the treatment. This data bank will be the principal part for the construction of a national software for the dose calculation and can be of great help for a reliable treatment system planning in radiotherapy/brachytherapy. (author)

  20. Actinomicose cerebral: observação anatomo-clinica e revisão da literatura brasileira

    Directory of Open Access Journals (Sweden)

    Luciano de Souza Queiroz

    1975-12-01

    Full Text Available Os autores relatam a observação anátomo-clínica de um paciente de 33 anos, com síndrome de hipertensão intracraniana e hemiparesia à direita. O líquido cefalorraqueano revelava discreta hipercitose linfomonocitária. A autópsia mostrou três abscessos cerebrais, com edema difuso mais intenso no hemisfério cerebral esquerdo, sem leptomeningite purulenta. O exame histopatológico demonstrou grãos actinomicóticos nos abscessos cerebrais e pulmonares. A literatura brasileira sobre neuroactinomicose é analisada, com encontro de seis casos, publicados entre 1934 e 1946. São discutidos aspectos clínicos e anátomo-patológicos relevantes dos casos nacionais.

  1. Materials characterization by photoelectron spectroscopy; Caracterizacao de materiais por espectroscopia de fotoeletrons

    Energy Technology Data Exchange (ETDEWEB)

    Nascente, P.A.P., E-mail: nascente@ufscar.b [Universidade Federal de Sao Carlos (DEMa/UFSCar), SP (Brazil). Dept. de Engenharia de Materiais

    2010-07-01

    Low energy electrons are suitable for investigating surfaces due to their low mean free path in solids, which correspond to a few atomic layers (0.5 to 3.0 nm), and could be used in one of the following ways: incident electrons cause the emission of backscattered and secondary electrons and the electrons are excited by irradiated photons. The first case includes the emission of Auger electrons, while photoemission corresponds to the second case. X-ray photoelectron spectroscopy (XPS) is one of the most used surface analysis techniques since it is able to identify not only the surface constituents but also their chemical states. XPS can be employed in several areas of science and engineering, but in this report it will be presented only few examples of its use in the characterization of metallic materials, with an emphasis on thin films of noble and transition metals. (author)

  2. Hydrogeological characterization of Itataia mine, Ceara, Brazil; Caracterizacao hidrogeologica da jazida de Itataia, CE

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Jose Roberto de Alcantara e

    2003-07-01

    This work analyzes the geological-geotechnical-geophysical behavior, aiming to define the characteristics of a karstic-fissural aquifer in the mid-northern region of the State of Ceara, named as Itataia Phosphor-Uranium Deposit. This area is constituted of marbles and gneisses from Itataia Group, which are morphologically located at a higher point to the south and at a lower point to the north, related to Paleoproterozoic Era. Fracture system led to the implantation of two karstic marble phases, being the oldest from Cambrian Period and the most recent from Tertiary/Quaternary Period. Porosity is secondary to fractures, fissures and crushed zones which act as hydraulic channels for groundwater flow. Major geophysics defined conducting lines are controlled by normal fractures and faults in both N70 deg E and N80 deg W directions, and secondarily in both N10 deg E and N30 deg W directions, dipping 70 deg -85 deg into the northern quadrant of the main axes. Fault characteristics are typical of graben and horst patterns. Rocks in the area are distributed into three classes of geotechnical massif: healthy rock, moderately altered and fractured rock, and strongly altered and fractured rock. The latter occurs predominantly in the center of the area, from the soil surface to an average depth of 150 meters. Groundwater flow is characterized by fractures which enlarged by the karstic phenomenon dissolution, and then become closer as deeper they are. This flow may be slower or even discontinue in light of silty-argillaceous alteration material that fill the open fracture gaps. Water level is not lower than 5 m or higher than 90 m, averaging by 30 m ali over the area. The synoptic piezometry map shows a general south-north direction; however in the southwestern portion - the recharge zone - it takes the south direction, while in the southeastern portion it takes the southeast direction. (author)

  3. Synthesis and characterization of new ionic liquids; Sintese e caracterizacao de novos liquidos ionicos

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, L.M.C. de; Mattedi, S.; Boaventura, J.S., E-mail: luanaufrn@hotmail.co [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Escola Politecnica. Programa de Pos-Graduacao em Engenharia Quimica; Iglesias, M. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Escola Politecnica. Programa de Pos-Graduacao em Engenharia Quimica; Universidad de Santiago de Compostela (Spain). Escuela Tecnica Superior de Ingenieria. Dept. de Ingenieria Quimica

    2010-07-01

    In recent years, ionic liquids have been highlighted for its potential in various industrial applications. Among them, the salts of Broensted has a promising profile for the low toxicity, low cost and simple synthesis. This paper presents the synthesis and characterization of new salts of Bronsted with branched (lactate) or large chain anions (oleate) for future use as additives promoters of proton conductivity in fuel cells of ethanol. Experimental data were measured for density, sound velocity and conductivity of pure ionic liquids and mixtures. The density decreases linearly with increasing temperature, and sound velocity shows a similar trend, but not linear. The conductivity increases according to the Arrhenius model with activation energy less than 10 J/mol. Tests NMR, FTIR and TGA confirm ionic structure and thermal stability up to 165 deg C. (author)

  4. Naphthenic acid characterization and distribution in crude oils; Caracterizacao e distribuicao de acidos naftenicos em petroleos

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Regina C.L.; Gomes, Alexandre de O. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2008-07-01

    Naphthenic acid corrosion was observed for the first time during the distillation process of some kind of crude oils in 1920. Recent reports about naphthenic acid corrosion have been found in China, India, Venezuela, Eastern Europe, Russia and the USA. In Brazil, heavy and acid crude oil processing is rising. Some brazilian crude oils have TAN around 3,0 mg KOH/g. The presence of relatively high levels of naphthenic acids in crude oils is a bane of petroleum refiners; and more recently, of producers as well, who have reported problems during production with calcium and sodium naphthenate . Essentially, these acids which are found to greater or lesser extent in virtually all crude oils are corrosive and tend to cause equipment failures, lead to high maintenance costs and may pose environmental disposal problems. In order to give these information to PETROBRAS, The Research and Development Center of PETROBRAS (CENPES) has been working in house and with brazilian universities developing analytical technicians to know better molecular structures and distribution of these acids compounds in crude oils. This work presents the actual methods and some results from these developments. (author)

  5. Thermodegradation of biodiesel: thermoanalytical and rheological characterization; Degradacao termica de biodiesel: caracterizacao termoanalitica e reologica

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Everson L.; Carvalho, Laura H.; Araujo, Gilmar T.; Gadelha, Tatiana S. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2008-07-01

    Brazil is a country of extensive agricultural land and great oil consumption and these factors favor biodiesel production in this country. In order for diesel/biodiesel mixtures to be effectively employed in diesel engines, a rigid quality control of these mixtures is needed. Biodiesel and mixtures must have their quality monitored with respect to oxidative resistance, thermal stability, fluidity and volatility, properties which can be modified by the adverse transport and stock conditions prior to consumption. Oxidation is the main degradation mechanism of products under transport and stock conditions, which can lead to significant economical losses. In this work sought the thermal degradation of neat biodiesel, synthesized in our laboratories was monitored. Thermal aging was conducted at 210 deg C for up to 1000 h. Virgin and thermally degraded samples were characterized by rheological measurements (in different shear conditions); FTIR; density and by color changes. We concluded that the soy biodiesel was successfully synthesized and that thermal exposure caused thermal-oxidative degradation of the biodiesel sample, significantly changing its properties as a function of thermal exposure times. (author)

  6. Synthesis and characterization of boron nitrides nanotubes; Sintese e caracterizacao de nanotubos de nitreto de boro

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, T.H.; Sousa, E.M.B. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil). Servico de Nanotecnologia

    2010-07-01

    This paper presents a new synthesis for the production of boron nitride nanotubes (BNNT) from boron powder, ammonium nitrate and hematite tube furnace CVD method. The samples were subjected to some characterization techniques as infrared spectroscopy, thermal analysis, X-ray diffraction and scanning electron microscopy and transmission. By analyzing the results can explain the chemical reactions involved in the process and confirm the formation of BNNT with several layers and about 30 nanometers in diameter. Due to excellent mechanical properties and its chemical and thermal stability this material is promising for various applications. However, BNNT has received much less attention than carbon nanotubes, it is because of great difficulty to synthesize appreciable quantities from the techniques currently known, and this is one of the main reasons this work.(author)

  7. Production and characterization of ceramics for armor application; Producao e caracterizacao de ceramicas para blindagem balistica

    Energy Technology Data Exchange (ETDEWEB)

    Alves, J.T.; Lopes, C.M.A. [Instituto Tecnologico de Aeronautica (ITA), Sao Jose dos Campos, SP (Brazil). Div. de Engenharia Mecanica-Aeronautica; Assis, J.M.K.; Melo, F.C.L., E-mail: cmoniz@iae.cta.b [Instituto de Aeronautica e Espaco (IAE), Sao Jose dos Campos, SP (Brazil). Div. de Materiais

    2010-07-01

    The fabrication of devices for ballistic protection as bullet proof vests and helmets and armored vehicles has been evolving over the past years along with the materials and models used for this specific application. The requirements for high efficient light-weight ballistic protection systems which not interfere in the user comfort and mobility has driven the research in this area. In this work we will present the results of characterization of two ceramics based on alumina and silicon carbide. The ceramics were produced in lab scale and the specific mass, scanning electron microscopy (SEM) microstructure, Vickers hardness, flexural resistance at room temperature and X-ray diffraction were evaluated. Ballistic tests performed in the selected materials showed that the ceramics present armor efficiency. (author)

  8. Preparation and characterization of bentonite organo clay; Preparacao de caracterizacao de argilas bentonitas organofilicas

    Energy Technology Data Exchange (ETDEWEB)

    Bertagnolli, C.; Almeida Neto, A.F. [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Fac. de Engenharia Quimica. Lab. de Engenharia Ambiental; Silva, M.G.C., E-mail: meuris@feq.unicamp.b [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Fac. de Engenharia Quimica

    2009-07-01

    Bentonite clays organically modified have great potential use for environmental remediation, especially in the separation of organic compounds from the water. The aim of this work was the preparation of organophilic clays from 'Verde-Lodo' bentonite clay with the quaternary ammonium salts cetyl-pyridinium chloride and benzalkonium chloride. The materials obtained were characterized by XRD, thermogravimetric analyses, Helium picnometry, SEM and energy dispersive X-ray techniques. The results show consistently successful synthesis of the organoclay through the increase in the basal spacing, as well as salt elimination picks and presence of carbon and chlorine in the modified clays; they are inexistent elements in the natural clay. (author)

  9. Socio environmental characterization of the planned electric power system; Caracterizacao socioembiental do sistema eletrico planejado

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The following aspects are covered by this chapter: reference alternative of the generation system; socio environmental analysis of the enterprise generations; reference configuration of the transmission system.

  10. Characterization of nanocomposites PHBV/attapulgite organophilic; Caracterizacao de nanocompositos PHBV/atapulgita organofilica

    Energy Technology Data Exchange (ETDEWEB)

    Silva, L.C.A.; Barreto, L.S., E-mail: lilianealcantara@msn.co [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil). Programa de Pos-graduacao em Ciencia e Engenharia de Materiais; Thire, R.M.S.M. [Coordenacao dos Programas de Pos-Graduacao de Engenharia (PEMM/COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Metalurgica e de Materiais

    2010-07-01

    Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) - PHBV is a biodegradable polyester which have been studied as an option for the production of disposable goods. This thermoplastic has some disadvantages that limit its use in industrial scale applications: the relative difficulty of processing, high degree of crystallinity and high cost of production relative to conventional polymers. An alternative to improve the properties of PHBV is the incorporation of small amounts of clay to the polymer. The aim of this work was to produce and characterize PHBV nanocomposites reinforced with organophilic attapulgite in different compositions. Natural attapulgite was modified with hexadecylmethylammonium chloride. The nanocomposites were characterized by XRD, SEM and Thermal analysis. It was observed reduction of the degree of crystallinity, melting and glass transition temperatures and the thermal stability of polymer in function on the addition of clay to the matrix of the PHBV. The best results were obtained for PHBV films containing 3% and 5% attapulgite. These films presented a slight increasing in processing window and decreasing in crystalline temperature and in degree of crystallinity as compared to pure PHBV. (author)

  11. Magnetic ionic liquids: synthesis and characterization; Liquidos ionicos magneticos: sintese e caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Medeiros, Anderson M.M.S.; Parize, Alexandre L.; Oliveira, Vanda M.; Neto, Brenno A.D.; Rubim, Joel C. [Universidade de Brasilia (LMC/IQ/UnB), DF (Brazil). Inst. de Quimica. Lab de Materiais e Combustiveis

    2010-07-01

    The synthesis of magnetic ionic liquids (MILs) based on the stable dispersions of magnetic nanoparticles (MNPs) of {gamma}-Fe{sub 2}O{sub 3}, Fe{sub 3}O{sub 4}, and CoFe{sub 2}O{sub 4} in the ionic liquid 1-n-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (BMI.NTf{sub 2}) is reported. The MNPs were obtained by the coprecipitation method. The surface of the {alpha}-Fe{sub 2}O{sub 3}, Fe{sub 3}O{sub 4}, and CoFe{sub 2}O{sub 4} MNPs with mean sizes (XRD) of 9.3, 12.3, and 11.0 nm, respectively were functionalized by 1-n-butyl-3-(3'-trimethoxypropylsilane)- imidazolium chloride. The non functionalized and functionalized MNPs were further characterized by Raman, FTIR-ATR, and FTNIR spectroscopy and by TGA. The stability of the MILs was assigned to the formation of at least one monolayer of the surface modifier agent that mimics the structure of the BMI.NTf{sub 2} IL. (author)

  12. Surface characterization of titanium based dental implants; Caracterizacao de implantes odontologicos a base de titanio

    Energy Technology Data Exchange (ETDEWEB)

    Castilho, Guilherme Augusto Alcaraz

    2006-07-01

    Dental implantology uses metallic devices made of commercially pure titanium in order to replace lost teeth. Titanium presents favorable characteristics as bio material and modern implants are capable of integrate, witch is the union between bone and implant without fibrous tissue development. Three of the major Brazilian implant manufacturers were chosen to join the study. A foreign manufacturer participated as standard. The manufacturers had three specimens of each implant with two different surface finishing, as machined and porous, submitted to analysis. Surface chemical composition and implant morphology were analyzed by X-ray photoelectron spectroscopy (XP S), scanning electron microscopy (SEM) and microprobe. Implant surface is mainly composed of titanium, oxygen and carbon. Few contaminants commonly present on implant surface were found on samples. Superficial oxide layer is basically composed of titanium dioxide (TiO{sub 2}), another oxides as Ti O and Ti{sub 2}O{sub 3} were also found in small amount. Carbon on implant surface was attributed to manufacturing process. Nitrogen, Phosphorous and Silicon appeared in smaller concentration on surface. There was no surface discrepancy among foreign and Brazilian made implants. SEM images were made on different magnification, 35 X to 3500 X, and showed similarity among as machined implants. Porous surface finishing implants presented distinct morphology. This result was attributed to differences on manufacturing process. Implant bioactivity was accessed through immersion on simulated body solution (SBF) in order to verify formation of an hydroxyapatite (HA) layer on surface. Samples were divided on three groups according to immersion time: G1 (7 days), G2 (14 days), G3 (21 days), and deep in SBF solution at 37 deg C. After being removed from solution, XPS analyses were made and then implants have been submitted to microprobe analysis. XPS showed some components of SBF solution on sample surface but microprobe examinations did not confirmed the formation of HA layer. However, it was observed NaCl crystals on some implant surface. (author)

  13. Characterization of grog of bricks; Caracterizacao de chamote de blocos de vedacao

    Energy Technology Data Exchange (ETDEWEB)

    Candido, V.S.; Pinheiro, R.M.; Monteiro, S.N.; Vieira, C.M.F. [Universidade Estadual do Norte Fluminense Darcy Ribeiro (LAMAV/CCT/UENF), Campos dos Goytacazes, RJ (Brazil). Lab. de Materiais Avancados

    2010-07-01

    This work aims to characterize a waste of red ceramic, grog, generated from the milling of defective pieces of bricks fired in a Hoffmann type furnace by a industry from Campos dos Goytacazes-RJ. The grog was tested for X-ray diffraction, X-ray fluorescence, thermogravimetric and differential thermal analysis, dilatometry, sieving and sedimentation by gravity and optical microscopy. The results indicated that the grog is predominantly constituted of quartz, muscovite mica and hematite. The presence of kaolinite indicates that the bricks were fired at low temperatures, below 600 deg C. Finally, the characterization results indicated that the grog presents itself as an alternative non plastic material to be used in mixtures with clays for the production of red ceramics. (author)

  14. Cellulose whiskers: preparation, characterization and surface modification; Whiskers de celulose: preparacao, caracterizacao e modificacao de superficie

    Energy Technology Data Exchange (ETDEWEB)

    Taipina, Marcia O.; Ferrarezi, Marcia M.F.; Goncalves, Maria C., E-mail: maria@iqm.unicamp.br [Instituto de Quimica, Universidade Estadual de Campinas, Campinas, SP (Brazil)

    2011-07-01

    The main objectives of this work were to produce cellulose whiskers (from cotton fibers) by acid hydrolysis and subsequently modify the surface of these whiskers with 3-iso-cyanate-propyltrietoxy-silane. Cellulose whiskers structures were characterized by X-ray diffraction and Fourier transform infrared and their morphologies were investigated by scanning and transmission electron microscopy. Due to the hydrophilic nature of native cellulose, the formation of cellulose whisker nanocomposites is limited to water-soluble polymers. The applied methodology for surface modification of the whiskers allowed to obtain nanofibers with surface features more appropriate to allow the adhesion at fiber-matrix interface, which may result in a better performance of these fibers as reinforcing agents of hydrophobic polymer matrices. (author)

  15. Preparation and characterization of bacterial cellulose nano crystals; Preparacao e caracterizacao de nanocristais de celulose bacteriana

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Daniele B. dos; Lima, Lais R. de; Barud, Hernane S.; Messaddeq, Younes; Ribeiro, Sidney J.L. [Universidade Estadual Paulista Julio de Mesquita Filho. Unesp, Instituto de Quimica, Araraquara, SP (Brazil)

    2011-07-01

    In this work we described the preparation of bacterial cellulose nano crystals (BCNC) by hydrolysis of bacterial cellulose with concentrated sulfuric acid. The influence of hydrolysis time in the nano crystals formation was evaluated and the materials characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TG) and X-ray diffraction analysis. The SEM images showed the whiskers formation and its reveal that the morphology and size of BCNC not changes significantly with hydrolysis time. The X-rays diffractogram analysis showed an increase on BCNC crystallinity as compared with pure bacterial cellulose. The TG curves revealed a decreasing on thermal stability of BCNC samples with increase of the hydrolysis time. (author)

  16. Characterization of clay of Vitoria da Conquista - BA - Brazil; Caracterizacao de uma argila caulinitica por Rietveld

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, O.M.; Zandonadi, A.R.; Martins, M.V. Surmani; Carrio, J.A.G.; Munhoz Junior, A.H., E-mail: orley10@yahoo.com.br [Universidade Presbiteriana Mackenzie, Sao Paulo, SP (Brazil)

    2011-07-01

    Kaolinitic clays are vastly used in ceramic industry. Kaolinitic clay that are not coloured after firing are very useful in the production of ceramics because of their aesthetic aspect after firing. In this work clay material from Vitoria da Conquista (South- West Bahia, Brazil) was characterized by several techniques. The differential Scanning Calorimetry (DSC) shows a kaolinite characteristic curve with an endothermic peak at 492 deg C, which corresponds to the kaolinite - metakaolinite transformation. The transformation of alpha to beta quartz characterized by a 573 deg C peak was also observed in DSC. The samples were also characterized by water absorption and x rays powder diffraction. The 1100 deg C burned samples were tested by flexural strength. (author)

  17. Characterization of hydroxyapatite substituted with silicon; Caracterizacao de hiroxiapatita substituida com silicio

    Energy Technology Data Exchange (ETDEWEB)

    Silva, H.M. da; Soares, G.A., E-mail: helena@metalmat.ufrj.b [Universidade Federal do Rio de Janeiro (COPPE/UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao em Engenharia. Lab. de Biomateriais para Engenharia Ossea; Mateescu, M.; Anselme, K. [Universite de Haute-Alsace (UHA/IS2M), Mulhouse (France). Inst. de Science des Materiaux; Palard, M.; Champion, E. [Universite de Limoges (France). Fac. des Sciences et Techniques

    2009-07-01

    Incorporation of silicon (Si) ions into hydroxyapatite structure (HA) influences on physical, chemical and physiological properties. Some studies reported the improved bioactivity Si substitution, and it also accelerates the biomineralization process. The main objective of this work is to characterize stoichiometric hydroxyapatite and hydroxyapatite substituted with 1.13% in weight of Si (SiHA) using a wet precipitation method followed by a heat treatment. SEM/EDS, AFM, DRX and FTIR analyses were used to characterize the samples. EDS and FTIR results confirmed the presence of Si. Silicon induces small changes on crystal structure of HA, not detected on X-ray diffraction patterns of sintered tablets of SiHA and HA. No secondary phases were observed, that indicates the Si had entered the HA lattice. (author)

  18. Synthesis and characterization of biomorphic ceramics; Sintese e caracterizacao de ceramicas biomorficas

    Energy Technology Data Exchange (ETDEWEB)

    Rambo, Carlos Renato

    2001-07-01

    Biotemplating represents a recently developed technology for manufacturing of biomorphous ceramics from naturally grown plant structures. This approach allows the production of ceramic materials with cellular structure, where the microstructural features of the ceramic product are similar to the native plant. After processing, the biomorphic ceramic exhibits directed pore morphology in the micrometer range. Biomorphic SiC fibers were produced from bamboo by carbothermal reduction of SiO{sub 2} originally present in the bamboo structure. Bamboo pieces were heated up to 1500 deg C in argon to promote the reaction between carbon and silica. Biomorphic alumina, mullite and zirconia ceramics were manufactured via the sol-gel route by repeated infiltration of low viscous oxide precursors (sols) into rattan, pine and bamboo structures. The raw samples were pyrolyzed at 800 deg C in nitrogen for 1h and subsequently annealed at 1550 deg C in air. The microstructure and physical properties of the biomorphic ceramics were characterized by X-ray diffraction (XRD) and high temperature-XRD, scanning electron microscopy (SEM), porosimetry and picnometry. Thermal analysis (TGA/DTA) was performed on the infiltrated samples in order to evaluate the reactions and the total weight loss during the thermal process. The mechanical properties were evaluated by compressive strength tests. In contrast to conventional processed ceramic foam of similar porosity, the microstructure highly porous biomorphic ceramics shows uniaxial pore morphology with anisotropic properties. These properties are favorable for applications in catalyst support, filters or low-density heat insulation structures, or as biomaterials. (author)

  19. Bio-inspired synthesis and characterization of superparamagnetic particles; Sintese e caracterizacao bioinspirada de particulas superparamagneticas

    Energy Technology Data Exchange (ETDEWEB)

    Castro, Vinicius F., E-mail: vfc_mg@yahoo.com.br [Universidade Federal de Itajuba (UNIFEI), MG (Brazil); Queiroz, Alvaro A.A. [Universidade Federal de Itajuba (UNIFEI), MG (Brazil). Centro de Estudos e Inovacao em Materiais Biofuncionais Avancados

    2012-08-15

    This paper discusses the bio-inspired synthesis of type YFeAl ferrites encapsulated into polyglycerol dendrimers (PGLD) generation 3. The structure and morphological properties of the system YFeAl/PGLD was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The magnetic properties were studied through the techniques of Moessbauer spectroscopy and magnetization. The cytotoxicity of the nanoparticles encapsulated in dendrimers PGLD G3 at the cell membrane was studied against mammalian cell line CHO.K1 measuring the amount of lactate dehydrogenase (LDH) released by the cell damage. Microscopy TEM and XRD analysis indicate that spherical nanoparticles were obtained highly crystalline and monodisperse with size 20 nm

  20. Mullite process and characterization for radome applications; Obtencao e caracterizacao de mulita para radomes

    Energy Technology Data Exchange (ETDEWEB)

    Silverio, G.R., E-mail: gustavorsilverio@hotmail.com [Universidade de Sao Paulo (USP/EEL/DEMAR), Lorena, SP (Brazil). Escola de Engenharia. Departamento de Engenharia de Materiais; Piorino Neto, F.; Melo, F.C.L.; Junqueira, C.C.M.; Assis, J.M.K.; Gambin, E. [Instituto de Aeronautica e Espaco (IAE/AMR/AEL), Sao Jose dos Campos, SP (Brazil)

    2012-07-01

    Mullite is an aluminosilicate with potential for application in aerospace radomes. The study was based on three compositions with sintering in air at different temperatures. The mullite formation was evaluated by X-ray diffraction Was measured Vickers hardness, density, shrinkage rate, fracture toughness was calculated and the coefficient of thermal expansion. The electromagnetic characterization was performed following the method of Hakki Colemann. Microstructural characterization was performed by scanning electron microscopy. The best results were divided into two compositions sintered at 1600 ° C and 1650 ° C with up to 97% densification. (author)

  1. Characterization of X-ray irradiator RS-2000; Caracterizacao do irradiador de raios X RS-2000

    Energy Technology Data Exchange (ETDEWEB)

    Mazaro, Sarah Jessica; Pavoni, Juliana Fernandes [Universidade de Sao Paulo (USP), Ribeirao Preto, SP (Brazil). Departamento de Fisica; Silva, Maelson do Nascimento; Bianchini, Adriano L.B.; Amaral, Leonardo Lira do, E-mail: sarahmazaro@yahoo.com.br [Universidade de Sao Paulo (HC/FMRP/USP), Ribeirao Preto, SP (Brazil). Hospital das Clinicas. Faculdade de Medicina. Servico de Radioterapia

    2014-04-15

    Gamma irradiators are being replaced by the x - rays ones which are more economical and have greater safety benefits compared to the radionuclide irradiators. Some tests are usually performed to ensure quality control while working with radiation, as constancy, linearity, repeatability, reproducibility, radiometric survey and security tests. Evaluating the technical parameters and the instrument and equipment performance quickly. The irradiator characterization determines its operation, by ensuring that the deposited dose is the one desired. This study aims to characterize x-rays irradiators through dosimetric tests. The equipment used in this study stable in dose rate free space and regularity for safety test. Furthermore, the measurements were reproducible with a maximum variation of 10% and the radiometric survey showed that the results are consistent with the exemption requirements of radiological protection described in regulatory position 3.01/001:2011. (author)

  2. Produção e caracterização de maltodextrinas a partir de amidos de mandioca e batata-doce

    OpenAIRE

    Coutinho, Ana Paula Cerino [UNESP

    2007-01-01

    As maltodextrinas sao produtos da hidrolise parcial do amido e tem sido largamente usadas nas industrias de alimentos em muitos tipos de alimentos processados. Maltodextrinas sao classificadas de acordo com o grau de hidrolise do amido, que e expressa em dextrose equivalente (DE). Varias propriedades funcionais, como docura, solubilidade e viscosidade variam de acordo com a degradacao enzimatica e a fonte botanica do amido, e somente a caracterizacao pela dextrose equivalente (DE) se tornou i...

  3. Characterization of a new sealer MTA/HAp; Caracterizacao de um novo cimento endodontico MTA/HAp

    Energy Technology Data Exchange (ETDEWEB)

    Barros, C.M.B.; Oliveira, S.V.; Costa, A.C.F.M. [Universidade Federal de Campina Grande (UFCG), PB (Brazil); Dantas, D.C.R.E.; Fontes, L.B.C. [Universidade Estadual da Paraiba (UEPB), PB (Brazil); Viana, K.M.S., E-mail: kalineviana@ect.ufrn.br [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2012-07-01

    Filling materials (cement-based calcium hydroxide, amalgam, glass ionomer and IRM) are often used as sealers. However, none of them meets the desirable characteristics of a suitable sealing material. This study aims to characterize the new sealer, MTA/HAp from the incorporation of 5% by weight of synthetic hydroxyapatite to the MTA and to investigate the influence of the addition of HAp on the characteristic structural, chemical and consistency of the MTA. For this, we used MTA Angelus ® and HAp synthesized in the laboratory. We used the ratio by mass 95%MTA/5%HAp, where the hydroxyapatite added the characteristic of the MTA osteoconduction. The tests were performed: XRD, XRF and consistency. The results showed that both the new cement had the same crystalline phases as the same chemical composition of its precursors, yet having suitable consistency (plastic mass) of a sealer as well as the pure MTA. (author)

  4. Rheological characterization of nanocomposites Nylon 6/bentonite clay; Caracterizacao reologica de nanocompositos de poliamida 6/argila bentonitica

    Energy Technology Data Exchange (ETDEWEB)

    Silva, T.R.G.; Fernandes, P.C.; Oliveira, S.V., E-mail: taci_gouveia@yahoo.com.b [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Curso de Pos-Graduacao em Ciencia e Engenharia de Materiais; Araujo, E.M.; Melo, T.J.A. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais

    2010-07-01

    Polymer nanocomposites are a class of materials that have been widely used in various applications. Among them, has been emphasizing the preparation of polymer films with barrier properties for applications in polymer membranes. In this work, nanocomposites of nylon 6/bentonite clay were obtained from a Homogenizer, in the ratios of 1, 3 and 5 wt% clay. The Brasgel PA bentonite clay was treated organically with Praepagen HY salt, to make it organophilic. By X-ray diffraction (XRD), it was showed that the efficiency of the incorporation of salt in the clay. The rheological curves showed that for the AST clay the torque did not change when compared with the pure nylon 6, while for the clay ACT, the torque increased gradually with the percentage of clay. (author)

  5. Commissioning of Portal Dosimetry and characterization of an EPID; Comissionamento de Portal Dosimetry e caracterizacao de EPID

    Energy Technology Data Exchange (ETDEWEB)

    Olbi, D.S.; Sales, C.P. [Universidade de Sao Paulo (USP), SP (Brazil). Faculdade de Medicina; Nakandakari, M.V.N., E-mail: diego.olbi@hc.fm.usp.br [Instituto do Cancer do Estado de Sao Paulo, SP (Brazil). Servico de Radioterapia

    2016-07-01

    The development of technologies compensator blocks, MLC, high dose rate accelerators, treatment planning systems, among others, permitted that new treatment techniques in radiotherapy were created. Such techniques have the capacity to modulate radiation beam fluency (IMRT, VMAT), or to deliver high doses in few fractions or unique fractions (SRS). Following the same tendency, quality control of planning became more complex. It is necessary to evaluate the fluency delivered by the accelerator. Its levels of does and its spatial distribution should co-occur with the fluency calculated by TPS. Acquisition of new detector devices in quality control of treatments is fundamental to apply techniques. Portal Vision is a device EPID has the capacity to operate either in image mode or dosimetry mode, with the allowance of Portal Dosimetry. To evaluated planning in IMRT, the device is irradiated using planning e, therefore, the fluency measured is compared with calculated fluency, through gamma analysis. The aim of this work was to perform tests of commissioning of this device. (author)

  6. Beneficiation of Candiota`s coal. I - characterization of circuits; Beneficiamento do carvao de Candiota. I - caracterizacao de circuitos

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Julio Cesar de; Sampaio, Carlos Hoffmann [Rio Grande do Sul Univ., Porto Alegre, RS (Brazil). Programa de Pos-graduacao em Engenharia Metalurgica e dos Materiais

    1991-12-31

    This work presents a study of different preparation plants for the coal from Candiota aiming at concentrates with about 35% ash content. Flowsheets of the coarse as well as the fine coal beneficiation plants are presented and discussed. The partition curves of the equipment used in the paper were characterized by the Erasmus mathematical model. With the results of the coarse and fine circuits operational parameters as granulometry, yield, etc.. were determined. (author). 10 refs., 4 tabs

  7. XPS utilization in the characterization of glycerol based polyesters; Utilizacao de XPS na caracterizacao de poliesteres a base de glicerol

    Energy Technology Data Exchange (ETDEWEB)

    Brioude, M.M.; Miranda, C.S.; Pereira, R.; Ohara, L.; Bargiela, P.; Rocha, M.G.M.C.; Jose, N.M., E-mail: mgcr@ufba.b [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Escola Politecnica. Inst. de Quimica

    2010-07-01

    X-ray photoelectron spectroscopy-XPS allows the determination of all elements of the periodical table, except hydrogen and helium, and is a very used technique for the polymers characterization, its spectra constitutes a 'fingerprint' of the material. Two samples of polymers were prepared from glycerol and fumaric acid and glycerol and terephthalic acid, with a molar ratio of 1:1 and 1:1.5. The general spectra show the presence of carbon and oxygen, the main components of the polymer. From the binding energies values of the C1s and O1s high resolution spectra it was possible to determine the carbon functional groups. Their concentration were determined and the presence of the aromatic carbon in the terephthalic polyesters was observed, and also similar proportions of aliphatic carbon and ester groups in the fumaric acid polyesters. For both polyesters, an amount of carboxyl group appears, indicating the terminal non-reacted groups. These results were confirmed qualitatively by FTIR. (author)

  8. Characterization of natural fiber from agricultural-industrial residues; Caracterizacao de fibras naturais provenientes de residuos agroindustriais

    Energy Technology Data Exchange (ETDEWEB)

    Prado, Karen S.; Spinace, Marcia A.S., E-mail: marcia.spinace@ufabc.edu.br [Centro de Ciencias Naturais e Humanas, CCNH, Universidade Federal do ABC - UFABC, Campus de Santo Andre, SP (Brazil)

    2011-07-01

    Natural fibers show great potential for application in polymer composites. However, instead of the production of inputs for this purpose, an alternative that can also minimize solid waste generation is the use of agro-industrial waste for this purpose, such as waste-fiber textiles, rice husks residues and pineapple crowns. In this work the characterization of these three residues and evaluate their properties in order to direct the application of polymer composites. Was analyzed the moisture, density, scanning electron microscopy, X-ray diffraction and thermogravimetric analysis of the fibers. The results show that the use of these wastes is feasible both from an environmental standpoint and because its properties suitable for this application. (author)

  9. Synthesis and characterization of type silicoaluminophosphates catalytic support; Sintese e caracterizacao de suportes cataliticos do tipo silicoaluminofosfatico

    Energy Technology Data Exchange (ETDEWEB)

    Leite, C.E.T.; Carvalho, M.W.N.C.; Pereira, K.R.O., E-mail: carlosedisio@hotmail.co [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia Quimica. Lab. de Catalise, Adsorcao e Biocombustiveis

    2010-07-01

    The refining processes, the catalytic hydrocracking is the future of diesel oil in Brazil and the first units are already scheduled to be inaugurated. Among the catalysts used in this process, silicoaluminophosphates (SAPO's) have considerable potential for use as they have been effective in the isomerization of n-alkanes, the isomerization of olefins and alkylation of aromatics. Because of this, the objective is to develop catalysts that will be used in hydrocracking reactions. The media like SAPO-5 were synthesized with different ratios silicon/aluminum, which is used as a catalytic support and have the function of crack organic molecules, since it has acidic character. The materials were characterized by techniques: X-ray diffraction, chemical analysis and textural by BET. After summarizing the media found that they had agreements with the crystalline phases presented in the literature.(author)

  10. Poly(vinylpyrrolidone)/silver nanoparticles: preparation and characterization; Nanoparticulas de prata/poli(vinilpirrolidona): obtencao e caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, P.F.; Goncalves, M.C. [Instituto de Quimica - UNICAMP, Campinas, SP (Brazil)], e-mail: patandrade@iqm.unicamp.br

    2010-07-01

    In this work silver nanoparticles were prepared by chemical reduction method using PVP as dispersant agent. The formation of silver nanoparticles was investigated by UV-vis optical spectroscopy and X-ray diffraction. FT-IR spectroscopy confirmed the formation of Ag/PVP complex. The transmission electron microscopy images indicated that the concentration of Ag{sup +} precursor influenced the nanoparticles dispersion and size distribution significantly. The results indicated that dispersed nanoparticles with uniform size distribution can be prepared by this methodology to obtain polymeric nano composites. (author)

  11. Bauxite and bauxite residue, characterization and electron microscopy study; Bauxita e seu residuo, caracterizacao e estudo por microscopia eletronica

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, M.L.P.; Conceicao, F.T., E-mail: malu@sorocaba.unesp.br [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Sorocaba, SP (Brazil); Toledo, S.P.; Kiyohara, P.K. [Universidade de Sao Paulo (IF/LME/USP), SP (Brazil)

    2012-07-01

    Through the Bayer process, bauxite is refined and alumina is produced. In this process, a highly alkaline residue, red mud is generated and its disposal represents an environmental problem. The aim of this paper is to present the characterization of Brazilian bauxite and Brazilian red mud by: X-ray diffraction, specific surface area, chemical composition analysis by ICP-MS, transmission electron microscopy (TEM) and energy dispersive X-ray spectrometry (EDS), and scanning electron microscopy (SEM) and discuss possible applications of this residue. The results identify as a constituent of both materials: Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, TiO{sub 2} and SiO{sub 2} and the presence of Na{sub 2}O in residue. The analysis by electron microscopy of Bauxite shows particles with hexagonal shape and red mud shows small particles size. (author)

  12. Characterization of electric arc furnace dust aiming reuse; Caracterizacao da poeira de aciaria eletrica visando o seu reaproveitamento

    Energy Technology Data Exchange (ETDEWEB)

    Grillo, F.F.; Oliveira, E.B.G.; Oliveira, J.R. de, E-mail: fgrillo@ifes.edu.b [Instituto Federal de Ciencia e Tecnologia do Espirito Santo (IFES), Vitoria, ES (Brazil); Telles, V.B.; Tenorio, J.A.S. [Universidade de Sao Paulo (USP), SP (Brazil)

    2010-07-01

    This work aims to study the characterize of steelmaking dust, from the primary refining of steel in Electric Arc Furnace, in order to verify feasibility of reuse through the addition of hot metal in the form of briquette. The techniques used to characterize the dust was chemical analyses, size separation tests, X-ray diffraction analyses (XRD), Scanning Electron Microscopy (SEM). After characterization, was the calculation of reductant considering the complete reduction of iron oxides and then to briquetting. The waste sample is composed essentially of spherical particles and has a very small particle size (85% below 10 {mu}m). The XRD has presented compounds such as ZnFe{sub 2}O{sub 4}, Fe{sub 3}O{sub 4}, ZnO e SiO{sub 2}. This work showed that its possible recovery approximately 92% of metal iron from dust generated during steelmaking.This (author)

  13. Viscosity and density study for characterization of oil mixtures; Estudo da viscosidade e densidade para caracterizacao das misturas de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Michelle I.; Azevedo, Vildomar S.; Jacinto, Tulio Wagner B. [Aurizonia Petroleo S.A, Natal, RN (Brazil); Vieira, Mariane; Vidal, Rosangela Regia Lima; Garcia, Rosangela Balaban [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2008-07-01

    The oil can be defined as a mixture of hydrocarbons and sulphur, nitrogen and oxygenated organic derivatives at lower amount. There is a practical difficulty of analytical determination of the oil composition, mainly due to the large quantity of medium and heavy oil fractions. For heavier fractions, it is necessary to infer the composition of the cut from properties that can be readily obtained in the laboratory, such as refraction index, density and viscosity. The analysis of oil composition and its fractions is important information on various aspects (IOB et al., 1996): determining the operating conditions of refining, selection of suitable catalysts and mixing operations ('blending'), the economic evaluation of mixtures and analysis of environmental impact due to emissions. The first study on characterization of fractions of the oil was reported by Hill and Coats (1928), who set an empirical relationship between the density and Saybolt viscosity named viscosity-density constant (VGC). The statement was obtained from the analysis of the density with the oil viscosity changes. Physical properties such as density, boiling point and viscosity can be used to classify the oil. The aim of this work was to classify oil fractions based on viscosity-density constant, using mixtures of oils with different APIs. The results showed that there is an optimum composition for each mixture, and the addition of more oil of medium classification does not lead to potential commercial oil. (author)

  14. Characterization of poly pyrrole/montmorillonite electro polymerised onto Pt; Caracterizacao de filmes PPy/montmorilonita eletropolimerizados sobre Pt

    Energy Technology Data Exchange (ETDEWEB)

    Castagno, K.R.L., E-mail: katiarlc@pelotas.ifsul.edu.b [Instituto Federal Sul-rio-grandense (IFSul), RS (Brazil). Dept. de Quimica; Azambuja, D.S.; Dalmoro, V.; Mauller, R.S. [Universidade Federal do Rio Grande do Sul (UFRGS), Pelotas, RS (Brazil). Inst. de Quimica

    2010-07-01

    In this study films of polypyrrole/montmorillonite (PPy/MT) were electropolymerized on platinum in order to evaluate the performance of this technique in the preparation of nanocomposite materials and to determine the thermal properties and conductivity of the composites. The films were synthesized from a solution containing pyrrole, dodecylbenzene sulfonate, acid and two types of clays: montmorillonite-Na + (MT-Na) and montmorillonite-30B (MT-M). The characterization of the films we have used FT-IR, TEM, XRD, TGA, DSC and resistivity measurement by the four-point van der Pauw method. The study showed that the adopted method of exfoliation and the electropolymerization method used, allows obtaining nanocomposite materials. Analyses of FT-IR, TEM and XRD show that the clays are exfoliated in the polymer matrix. Thermal analysis of the films indicates that the addition of clay reflects an enhancement in the thermal properties of the matrix of PPy, but decreases the conductivity of the same. (author)

  15. Characterization of the inclusion complex ropivacaine: {beta}-cyclodextrin; Caracterizacao do complexo de inclusso ropivacaina: {beta}-ciclodextrina

    Energy Technology Data Exchange (ETDEWEB)

    Fraceto, Leonardo Fernandes [Universidade Estadual Paulista Julio de Mesquita Filho, Sorocaba, SP (Brazil). Dept. de Engenharia Ambiental]. E-mail: leonardo@sorocaba.unesp.br; Goncalves, Marcos Moises [Universidade de Sorocaba, SP (Brazil); Moraes, Carolina Morales; Araujo, Daniele Ribeiro de; Zanella, Luciana; Paula, Eneida de [Universidade Estadual de Campinas (UNICAMP), Campinas, SP (Brazil). Inst. de Biologia. Dept. de Bioquimica; Pertinhez, Thelma de Aguiar [Universidade de Parma (Italy). Dept. de Medicina Experimental

    2007-09-15

    Ropivacaine (RVC) is a widely used local anesthetic. The complexation of RVC with {beta}-cyclodextrin ({beta}-CD) is of great interest for the development of more efficient local anesthetic formulations. The present work focuses on the characterization of the RVC:{beta}-CD complex by nuclear magnetic resonance (NMR). The stoichiometry of the complex is 1:2 RVC:{beta}-CD. DOSY-NMR shows that the association constant is 55.5 M{sup -1}. Longitudinal relaxation time results show that RVC changes its mobility in the presence of {beta}-CD. This study is focused on the physicochemical characterization of inclusion complexes that are potentials options for pain treatment. (author)

  16. Nickel coating electroplated characterization with and without carbon nanotubes; Caracterizacao de niquel eletrodepositado na presenca de nanotubos de carbono

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, A.C.; Banczek, E.P.; Cunha, M.T.; Rodrigues, P.R.P. [Universidade Estadual do Centro-Oeste, Guarapuava, PR (Brazil). Dept. de Quimica; Costa, I. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Terada, M. [Universidade de Sao Paulo (EPUSP), SP (Brazil). Escola Politecnica. Dept. de Engenharia Metalurgica e de Materiais

    2010-07-01

    The metals have great application, but when their properties are not suitable they should be improved through treatments to increase corrosion resistance, mechanical and wear. The metals electrodeposition such as nickel is one of treatment options. This study aims the development a nickel coating with and without (CNT), obtained by electrodeposition on aluminum alloy AA6061. The nickel electrodeposition was performed with cyclic voltammetry and chronoamperometry. Open circuit potential and anodic polarization curves were carried out samples characterization. The microstructure and the chemical composition of the M{sub x}O{sub z} coating were studied using the scanning electron microscopy, energy dispersion spectroscopy and X-ray diffraction. The results indicated that the nickel coating improve the corrosion resistance of aluminum in the presence of CNT. (author)

  17. Characterization of clay of Santa Maria Madalena-RJ (Brazil); Caracterizacao do solo do municipio de Santa Maria Madalena

    Energy Technology Data Exchange (ETDEWEB)

    Freitas, R.A.; Borges, B.F.; Rosario, S. do; Alexandre, J.; Beiral, W.V.; Anderson, R.B.; Pessanha, E.F., E-mail: jonas@uenf.br, E-mail: wevuenf@yahoo.com.br [Universidade Estadual do Norte Fluminense Darcy Ribeiro (LECIV/UENF), Campos dos Goytacazes, RJ (Brazil). Laboratorio de Engenharia Civil

    2011-07-01

    The city of Santa Maria Madalena, located in the mountainous region of Rio de Janeiro State, has a region of rocky and extensive area of native forest. Its economy is primarily intended for farming, agriculture and tourism. Characterization studies were conducted in this region, aiming to determine the optimal production process for its application in the ceramics industry. The tests were conducted in the laboratories of the Universidade Estadual Norte Fluminense Darcy Ribeiro - UENF and were determined and the physical, chemical and mineralogical characteristic. Were performed Granulometric Analysis, Atterberg Limit, Chemical Analysis, X Ray Diffraction. The specimens used in evidence were extruded and then fired at the following temperatures: 750 ° C and 850 ° C, and subsequently conducted measurements of absorption, linear shrinkage and resistance to flexion-compression. (author)

  18. Production and characterization of poly(styrene-co-methylmethacrylate);Producao e caracterizacao de poliestireno-co-metacrilato de metila

    Energy Technology Data Exchange (ETDEWEB)

    Augustinho, Tiago R.; Coan, Thais; Abarca, Silvia A.C.; Testoni, Alex A.S.; Baumgarten, Bruno P.; Machado, Ricardo A.F., E-mail: tiagoqmc@gmail.co [Universidade Federal de Santa Catarina (UFSC), Florianopolis (Brazil). Dept. de Engenharia Quimica e Alimentos

    2009-07-01

    Polystyrene (PS) is a polymer used in diverse industrial segments. It is easy to process and has a low cost when compared to other materials. However, PS has low mechanical resistance, which limits its application in some areas. Thus, a methodology that is sufficiently used is the synthesis of a copolymer, formed of two or more monomers to get products that have characteristics that are not possible to obtain with only one monomer. In this work, the styrene and methyl methacrylate monomers had been carried through reactions of copolymerization by means of polymerization in suspension using (MMA) with styrene in a bigger percentage. MMA was selected for being a monomer that results in a polymeric configuration more resistant than the PS. The copolymerization was proven to occur by infra-red spectroscopy (IR) and Nuclear Magnetic Resonance (NMR). Different analyses were performed using different initiators, weight molar and conversion studies. (author)

  19. Development of radiometric methods for radioactive waste characterization; Desenvolvimento de metodos radiometricos para a caracterizacao de rejeitos radioativos

    Energy Technology Data Exchange (ETDEWEB)

    Tessaro, Ana Paula Gimenes

    2015-07-01

    The admission of radioactive waste in a final repository depends among other things on the knowledge of the radioisotopic inventory of the waste. To obtain this information it is necessary make the primary characterization of the waste so that it is composition is known, to guide the next steps of radioactive waste management. Filter cartridges that are used in the water polishing system of IEA-R1 research reactor is one of these wastes. The IEA-R1 is a pool-type research reactor, operating between 2 and 5 MW that uses water as coolant, moderator and biological shield. Besides research, it is used for production of radioisotopes and irradiation of samples with neutron and gamma beams. It is located in the Nuclear and Energy Research Institute at the University of Sao Paulo campus. The filter cartridges are used to retain particles that are suspended in the cooling water. When filters become saturated and are unable to maintain the flow within the established limits, they are replaced and disposed of as radioactive waste. After a period of decay, they are sent to the Radioactive Waste Management Department. The aim of this work is to present the studies to determine the activity of gamma emitters present in the cartridge filters. The activities were calculated using the dose rates measured with hand held detectors, after the ratios of the emission rates of photons were evaluated by gamma spectrometry, by the Point Kernel method, which correlates the activity of a source with dose rates at various distances. The method described can be used to determine routinely the radioactive inventory of these filters, avoiding the necessity of destructive radiochemical analysis, or the necessity of calibrating the geometry of measurement. (author)

  20. Preparation and characterization of hybrid materials from natural chrysotile; Preparacao e caracterizacao de materiais hibridos a partir da crisotila natural

    Energy Technology Data Exchange (ETDEWEB)

    Giraldelli, M.G.; Silva, M.L.C.P., E-mail: marciogiraldelli@hotmail.co [Universidade de Sao Paulo (EEL/USP), Lorena, SP (Brazil). Escola de Engenharia

    2010-07-01

    Special attention has been given to the development of new materials from natural chrysotile. This fiber has about 40% silicon oxide in its structure with an outer layer of brucite (MgOH{sub 2}). With the aim of obtaining a material with a more uniform structure, acid leaching was performed to remove the outer layer of brucite, resulting in a silicon oxide hydrate. This material was used as support for the deposition of Nb{sub 2}O{sub 5}.nH{sub 2}O. The Nb{sub 2}O{sub 5}.nH{sub 2}O was prepared by conventional precipitation using as starting material niobium metallic. In this study, we performed the synthesis and characterization of the material SiO{sub 2}.nH{sub 2}O / Nb{sub 2}O{sub 5}.nH{sub 2}O 1:1. Both chrysotile as niobium are widely available national resources, which confirms the economic viability of resource use. The materials studied were characterized by XRD, SEM and TG/DTG. (author)

  1. Fabrication and characterization of calcium phosphate cement scaffolds; Obtencao e caracterizacao de scaffolds de cimento de fosfato de calcio

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, E. de; Motisuke, M., E-mail: eliandra.sousa@unifesp.br [Universidade Federal de Sao Paulo (UNIFESP), Sao Jose dos Campos, SP (Brazil). Instituto de Ciencia e Tecnologia; Bertran, C.A. [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Instituto de Quimica

    2011-07-01

    In Tissue Engineering, the need for scaffolds which are capable of guiding the organization, differentiation and growth of cells leading to the formation of new tissues is highly relevant. For the development of new scaffolds focused on bone tissue therapy, calcium phosphate cements (CPC) have great potential, because besides their resorbability, they present morphology and chemical composition similar to the bone mineral phase. Moreover, there are several processing techniques to produce ceramic scaffolds: polymeric sponge replication, incorporation of organic material into the ceramic powder, gelcasting, emulsion, among others. The aim of this work was to obtain CPCs scaffolds by using two techniques, emulsion and gelcasting. The scaffolds were characterized by their physical and mechanical properties and the crystalline phases formed after the setting reaction of cement were determined by X-ray diffraction. The samples obtained by both methods presented porosity between 61-65% and the microstructure consists of nearly spherical pores (d5o = 50-100 μm). The mechanical strength of the samples ranged from 5.5 to 1.5 MPa. The crystalline phases found were monetite (CaHPO{sub 4}) and brushite (CaHPO{sub 4} 2H{sub 2}O). (author)

  2. Hydrodynamic characterization in areas under influence in the petroleum industry; Caracterizacao hidrodinamica em areas sob influencia na industria petrolifera

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Daniel Alexsander Silva dos; Silva, Andre Giskard Aquino da [Rio Grande do Norte Univ., Natal, RN (Brazil)]. E-mail: danielsandersilva@hotmail.com; Vital, Helenice [Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq), Brasilia, DF (Brazil); Silveira, Iracema Miranda da [Museu Camara Cascudo, Natal, RN (Brazil); Chaves, Marcelo dos Santos; Lima, Zuleide Maria Carvalho [Rio Grande do Norte Univ., Natal, RN (Brazil). Programa de Pos-graduacao em Geodinamica e Geofisica

    2003-07-01

    For elaboration of contingency plans it is necessary to execute the mapping of sensitive areas to oil spill, as well as to create suitable forecast models for oil pollution movements. These models should start from a consistent database, so that it can encompass the several phases of the environmental monitoring. In both cases hydrodynamic data are essential. The analysis of hydrodynamic parameters is also an important phase for the knowledge of the Holocene evolution of the study area, as well as for execution of a suitable development policy to be applied on the area. The activities developed in this research involve collection of data 'in situ' at the Galinhos-Guamare and Diogo Lopes lagoons, as well as data manipulation referring to the littoral drift collected monthly along the North coast of the state of Rio Grande do Norte by members of the Grupo de Geologia e Geofisica Marinha e Melhoramento Ambiental (GGEMMA) from UFRN.

  3. Remote operation vehicles hydrodynamics (characterization of inertial hydrodynamic power); Hidrodinamica de veiculos de operacao remota (caracterizacao da forca hidrodinamica inercial)

    Energy Technology Data Exchange (ETDEWEB)

    Troyman, A.C.R.; Conceicao, C.A.L. da; Hirata, M.H. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia

    1989-12-31

    The hydrodynamic forces acting on a Remote Operation Vehicle (Rov) were identified in a previous work thus enabling one to write down the equations of motions. The main objective of this is to simulate the dynamic of the vehicle in real time which may be of great importance for operations in deep water. In the present work one deals with the inertial hydrodynamic forces for open frame type Rov. The added mass coefficients are calculated numerically using the Hess and Smith technique. (author). 4 refs., 5 figs., 2 tabs.

  4. Model of systemic characterization of the energy supply options; Modelo de caracterizacao sistemica das opcoes de oferta energetica

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, Ricardo Junqueira; Galvao, Luiz C. Ribeiro [Universidade de Sao Paulo (USP), SP (Brazil). Dept. de Engenharia de Energia e Automacao Eletricas. Grupo de Energia]. E-mails: ricardo_fujii@pea.usp.br; lcgalvao@pea.usp.br; Udaeta, Miguel Edgar Morales [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Eletrotecnica e Energia]. E-mail: udaeta@iee.usp.br

    2006-07-01

    This paper presents an alternative change of the traditional approach through a proposition of a model of energy resources by integrating all these dimensions. The objectives are: supplying a methodology for the evaluation of a global cost of the energy resources and another one to estimate such a resources potential. To facilitate the evaluation process, the model suggests the use of CCE - Completed Cost Evaluation, which allows the qualitative and quantitative costs, reducing the necessity of quantitative data limited in certain cases. The model can be applied jointly to portfolios selection and analysis tools for evaluation of the best offers for the expansion energy offers.

  5. Radiochemical characterization of uranium and thorium isotopes in phosphogypsum; Caracterizacao radioquimica dos isotopos de uranio e torio no fosfogesso

    Energy Technology Data Exchange (ETDEWEB)

    Paes, Vanessa Palmiro

    2001-07-01

    Phosphogypsum is the by-product of the phosphoric acid industry and it is obtained by reacting phosphate rock with sulfuric acid. Approximately 69 million tons of this by-product have already been produced by the phosphate fertilizer industry in Brazil, whose production is 5.4 million tons per year. The accumulation of phosphogypsum, which is stockpiled and has no close destination, has become more and more problematical. The main objective of this study is to determine activity concentrations of {sup 226}Ra, {sup 40}K and uranium and thorium isotopes in phosphogypsum, which might help to find out an eventual future application for this material. A methodology has been developed and checked in order to determine {sup 238}U, {sup 234}U, {sup 230}Th, {sup 232}Th and {sup 228}Th in phosphate rock and phosphogypsum samples. This methodology is based on solvent extraction and ion exchange resins. The measurements were performed by alpha spectrometry. {sup 226}Ra, {sup 232}Th and {sup 40}K were also analysed by gamma spectrometry. The results showed that {sup 226}Ra migrates preferentially in the phosphogypsum, form 4 to 20%, and thorium concentrated about 80% in the phosphogypsum. The radioactive concentration of uranium isotopes ranged between 11 and 1700 Bq/kg. The radioactive concentration of thorium isotopes ranged between 7 and 850 Bq/kg. The concentration of {sup 226}Ra ranged between 22 and 1410 Bq/kg, and for {sup 40}K, it ranged between the detection limit and 41 Bq/kg. (author)

  6. Preparation, characterization and certification of uranium isotope reference materials; Preparacao, Caracterizacao e certificacao de materiais de referencia isotopicos de uranio

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira Junior, Olivio Pereira de

    2006-07-01

    This work describes the preparation, characterization and certification of a set of uranium isotope reference materials ranging from 0.5 to 20.0 % of {sup 235}U in mass. The most important concepts of metrology in chemical measurements were applied so that the certified quantities in these materials could be directly traceable to the International System of Units (SI). As a consequence of this approach, these materials can be used in the instruments calibration, estimation of measurement uncertainty, method validation, assessment of performance of analysts, quality control routines and interlaboratory comparison programmes. The most advanced methods and techniques in mass spectrometry, that is, gas source mass spectrometry (GSMS), thermal ionisation mass spectrometry (TIMS) and inductively coupled plasma mass spectrometry (ICPMS) were investigated to identify which are the dominant components in the uncertainty and to quantify its contribution to the final value of the measurement uncertainty of the isotopic ratio. The results obtained were then compared to verify which are the methods and techniques associated to the lowest measurement uncertainty values. The isotope amount ratio n({sup 235}U)/n({sup 238}U) was certified in the materials produced to expanded uncertainties ranging from 0.02 to 0.10 % and the ratios n({sup 234}U)/n({sup 238}U) and n({sup 236}U)/n({sup 238}U), to uncertainties ranging from 0.03 to 2.20 %. These values fully comply to the requirements of the isotopic characterization of nuclear fuel as well as the analysis of environmental samples for nuclear safeguards. (author)

  7. Synthesis, characterization and thermal behavior of rare earth amido sulfonates; Sintese, caracterizacao e comportamento termico de amidossulfonatos de terras raras

    Energy Technology Data Exchange (ETDEWEB)

    Luiz, Jose Marques; Nunes, Ronaldo Spezia, E-mail: jmluiz@feg.unesp.br [Universidade Estadual Paulista Julio Mesquita Filho (UNESP), Guaratingueta, SP (Brazil). Faculdade de Engenharia. Departamento de Fisica e Quimica; Matos, Jivaldo do Rosario [Universidade de Sao Paulo (USP), SP (Brazil). Instituto de Quimica

    2013-09-01

    Hydrated compounds prepared in aqueous solution by reaction between amidosulfonic acid [H{sub 3}NSO{sub 3}] and suspensions of rare earth hydroxycarbonates [Ln{sub 2}(OH){sub x}(CO{sub 3}){sub y}.zH{sub 2}O] were characterized by elemental analysis (% Ln, % N and % H), infrared spectroscopy (FTIR) and thermogravimetry (TG). The compounds presented the stoichiometry Ln(NH{sub 2}SO{sub 3}){sub 3}.xH{sub 2}O (where x = 1, 5, 2.0 or 3.0). The IR spectra showed absorptions characteristic of H{sub 2}O molecules and NH{sub 2}SO{sub 3} groups. Degree of hydration, thermal decomposition steps and formation of stable intermediates of the type [Ln{sub 2}(SO{sub 4}){sub 3}] and (Ln{sub 2}O{sub 2}SO{sub 4}), besides formation of their oxides, was determined by thermogravimetry. (author)

  8. Electrochemical characterization of proton exchange membrane fuel cells; Caracterizacao eletroquimica de celulas a combustivel de membrana polimerica trocadora de protons

    Energy Technology Data Exchange (ETDEWEB)

    Furtado, Jose Geraldo de Melo; Serra, Eduardo Torres [Centro de Pesquisas de Energia Eletrica (CEPEL), Rio de Janeiro, RJ (Brazil)]. E-mail: furtado@cepel.br; Codeceira Neto, Alcides [Companhia HidroEletrica do Sao Francisco (CHESF), Recife, PE (Brazil)

    2008-07-01

    This paper describes the electrochemical behavior of a proton exchange membrane fuel cell in function of temperature and time of operation. Different polarization phenomena are considered in the 30 to 70 deg C temperature range, as well as the degradation of electrochemical behavior of the fuel cell analyzed up to 1260 hours of operation. The results show that there is a tendency for the experimental values approaching the theoretical as it increases the temperature of the membrane electrolyte. The electrochemical behavior of the PEMFC studied proved to be less stable at 70 deg C. On the other hand, at 30 deg C the fuel cell performance proved to be considerably lower than at other temperatures. Also, it was found that in certain current ranges occurs greater overlay in potential-current curves, and in some cases reversing between these curves depending on the electric current required for the data obtained at 60 and 70 deg C, indicating, perhaps, that at 70 deg C the characteristics of the electrolyte are slightly inferior to those at 70 deg C, corresponding to an electrolyte degradation. Additionally, for the system studied, we found that the rate of variation of the potential difference in function of the temperature is quite high at the beginning of the operation process and tends to stabilize in a level of around 2,3-2,5 {mu}V per minute for times greater than 330 hours of operation. (author)

  9. Dosimetric characterization of a commercial two-dimensional array detector; Caracterizacao dosimetrica de um detector matricial bidimensional comercial

    Energy Technology Data Exchange (ETDEWEB)

    Gialluisi, Bruno L.; Santos, Gabriela R. dos; Sales, Camila P. de; Resende, Guilherme R.A.; Habitzreuter, Angela B.; Rodrigues, Laura N., E-mail: brunogialluisi@gmail.com [Universidade de Sao Paulo (HCFMRP/USP), Sao Paulo, SP (Brazil). Hospital das Clinicas. Servico de Radioterapia

    2013-04-15

    This paper investigates the dosimetric characteristics and performance of an array detector commercially available. The device is the I'mRT MatriXX® which is a two-dimensional detector array used in the verification of complex radiotherapy plans. It consists of 1,020 parallel plate ion chamber arranged in a 32x32 grid. Dose linearity was studied and its response was linear within the range of 5 to 1000 MU (R{sup 2} = 1). Dose rate dependence showed a maximum deviation of 0,62% comparatively with readings to 320 cGy/min. The detector stability was verified through repeated irradiations. Output factors matched well with measurements made with a Farmer chamber with an average deviation of 1,54%. The detector's effective point of measurement was determined and the inverse square law was also verified with a percentage deviation smaller than 3%. The results show that this detector can be used for quality control in IMRT thus reducing the time spent in the dosimetric verification of radiation fields. (author)

  10. Characterization of AA7050 aluminium alloy processed by ECAP; Caracterizacao da liga de aluminio AA7050 processada por ECAP

    Energy Technology Data Exchange (ETDEWEB)

    Cardoso, K.R.; Guido, V. [Universidade do Vale do Paraiba (UNIVAP), Sao Jose dos Campos, SP (Brazil). Inst. de Pesquisa e Desenvolvimento; Travessa, D.N. [Empresa Brasileira de Aeronautica (EMBRAER), Sao Jose dos Campos, SP (Brazil); Jorge Junior, A.M. [Universidade Federal de Sao Carlos (DEMa/UFSCar), SP (Brazil). Dept. de Engenharia de Materiais

    2010-07-01

    The commercial AA7050 aluminium alloy in the solution heat treated condition (W) was processed by ECAP through route A. Two pressing temperatures (room and 150 deg C and velocities (5 and 30mm/min) were used, as well as different number of passes. The effect of such variables on the microstructure evolution was evaluated using optical and transmission electron microscopy with EDX microanalysis, and xray diffraction. It was found that the microstructure has been refined by ECAP, as a result of subgrains formed within deformation bands. ECAP at 150 deg C resulted in intense precipitation of plate like {eta} phase, which evolves to equiaxial morphology as the number of passes increases. (author)

  11. Preparation and characterization of the fish reference material; Preparacao e caracterizacao de um material de referencia de peixe

    Energy Technology Data Exchange (ETDEWEB)

    Ulrich, Joao Cristiano

    2011-07-01

    The certified reference materials (CRMs) play an important role in obtaining measurement results traceable to the International System of Units, through an unbroken chain of comparisons. Thus, the demand for new certified reference materials (CRMs) increases every day in all areas of knowledge. The availability of reference materials, mainly in Brazil is still incipient, given that the demand far exceeds the available variety of these materials. The amount of certified reference materials available in the country is insufficient to meet the need of the scientific community and demands for development of new methodologies. Among the many areas in need of reference materials, we highlight the importance for the food trade balance for these products within the country. The certification of food products, intended both for export and for domestic consumption, requires analysis methods that provide precise and accurate results to ensure product quality. This paper describes the preparation and certification of a reference material in the fish matrix in mercury and methylmercury. The study brings together since the stage of material selection, preparation, development of homogeneity and stability studies and characterization. The certification was performed by means of measurements using two analytical techniques, flow injection analysis - cold vapor atomic absorption spectrometry (FIA-CV-AAS) and isotope dilution applied to mass spectrometry (IDMS), which is a primary method. In this work the standards of the ISO 30 (ABNT 30-34) and ISO Guide 35 was used as the basis for the preparation and characterization of the material. For the calculation of uncertainties was used the GUM and Eurachem guide. As a result, was produced and certified a lot of material in relation to the concentration of mercury (Hg = 0.271 {+-} 0.057 mg g{sup -1}) and methylmercury (MeHg = 0.245 {+-} 0.038 mg g{sup -1}), and informational values of lead and arsenic. (author)

  12. Characterization and stabilization of suspension of bovine bone ash; Caracterizacao e estabilizacao de suspensao de po de ossos bovinos

    Energy Technology Data Exchange (ETDEWEB)

    Carus, L.A.; Bento, L.; Takimi, A.S.; Braganca, S.R., E-mail: laucarus@gmail.com [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Programa de Pos-Graduacao em Engenharia de Minas Metalurgica e de Materiais

    2012-07-01

    The bovine bone powder is the main component in the production of bone china, which is known to be one of the finest and most expensive tableware. This special type of porcelain has unique aesthetic characteristics, among which stands out the whiteness, translucency and brightness. The properties of this porcelain, as well as its manufacture, depend on the characteristics of the bone ash. In this study the rheological properties of the suspensions using exclusively bovine bone ash were evaluated by testing the influence of the concentration of solids in suspension, the calcination temperature and the use of dispersing agents. It was found that the powder calcination temperature affects the rheology of the suspension by lowering the viscosity. (author)

  13. Synthesis and characterization of tungsten or calcium doped PZT ceramics; Sintese e caracterizacao do PZT dopado com W ou Ca

    Energy Technology Data Exchange (ETDEWEB)

    Santos, D.M.; Caracas, L.B.; Noronha, R.G.; Santos, M.M.T. dos [Universidade Federal do Maranhao (UFMA), Sao Luis, MA (Brazil). Dept. de Desenho e Tecnologia. Curso de Desenho Industrial; Paiva-Santos, C.O., E-mail: denilson@ufma.b [Universidade Estadual Paulista (IQ/UNESP), Araraquara, SP (Brazil). Inst. de Quimica

    2009-07-01

    Pure and doped (tungsten or calcium) PZT ceramics were prepared by association of the polymeric precursor and partial oxalate method. The phase formation was investigated by thermal analysis (TG/DSC) and X-ray diffraction (XRD). The affect of W or Ca doping PZT and their electrical properties was evaluated. Substitution of W by Ti and Ca by Pb leads to an increase of Curie temperature and broadening of dielectric constant. A typical hysteresis loop was observed at room temperature and the remnant polarization was increased with the content of W and Ca. (author)

  14. Characterization of ionizing radiation effects on human skin allografts; Caracterizacao dos efeitos da radiacao ionizante em pele humana para aloenxerto

    Energy Technology Data Exchange (ETDEWEB)

    Bourroul, Selma Cecilia

    2004-07-01

    The skin has a fundamental role in the viability of the human body. In the cases of extensive wounds, allograft skin provides an alternative to cover temporarily the damaged areas. After donor screening and preservation in glycerol (above 85%), the skin can be stored in the Skin Banks. The glycerol at this concentration has a bacteriostatic effect after certain time of preservation. On the other hand, skin sterilization by ionizing radiation may reduces the quarantine period for transplantation in patients and its safety is considered excellent. The objectives of this work were to establish procedures using two sources of ionizing radiation for sterilization of human skin allograft, and to evaluate the skin after gamma and electron beam irradiation. The analysis of stress-strain intended to verify possible effects of the radiation on the structure of preserved grafts. Skin samples were submitted to doses of 25 kGy and 50 kGy in an irradiator of {sup 60}Co and in an electron beam accelerator. Morphology and ultra-structure studies were also accomplished. The samples irradiated with a dose of 25 kGy seemed to maintain the bio mechanic characteristics. The gamma irradiated samples with a dose of 50 kGy and submitted to an electron beam at doses of 25 kGy and 50 kGy presented significant differences in the values of the elasticity modulus, in relation to the control. The analysis of the ultramicrographies revealed modifications in the structure and alterations in the pattern of collagen fibrils periodicity of the irradiated samples. (author)

  15. Synthesis and characterization of poly(glycerol citrate/sebacate); Preparacao de caracterizacao do poli(glicerol citrato/sebacato)

    Energy Technology Data Exchange (ETDEWEB)

    Brioude, Michel M.; Guimaraes, Danilo H.; Fiuza, Raigenis P.; Boaventura, Jaime S.; Jose, Nadia M., E-mail: mbrioude@gmail.com [Universidade Federal da Bahia - UFBA, Instituto de Quimica, Salvador, BA (Brazil)

    2011-07-01

    In this work were prepared and characterized the poly(glycerol citrate/sebacate) in three different ratios between acids. The polymers were prepared by a polycondensation reaction between glycerol and citric/sebacic acids and characterized by X-ray diffraction (XRD), infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning differential calorimetry (DSC), scanning electron microscopy (SEM). The results showed that the polymers are polyesters and its crystallinity, thermal and morphological properties were modified by sebacic acid adding. (author)

  16. Synthesis and characterization of poly aniline for electrochemical biosensor construction; Sintese e caracterizacao de polianilina para construcao de biossensor electroquimico

    Energy Technology Data Exchange (ETDEWEB)

    Magalhaes, Gleice S.L.; Southgate, Erica F.; Alhadeff, Eliana M.; Guimaraes, Maria Jose O.C., E-mail: ema@eq.ufrj.br [Escola de Quimica, Universidade Federal do Rio de Janeiro - UFRJ, Rio de Janeiro, RJ (Brazil)

    2011-07-01

    Conductors polymers have many attractive interests to the industry due their highly technological applications. This work treats specially of polyaniline because it's large electrical conductivity, electrochemical properties, associate to the chemical stability in environmental conditions and synthesis facility. The main of this work is the application in a construction of an electrochemical biosensor for ethanol detection and quantification. Different conditions of synthesis of the conductor emeraldine polyaniline form were studied, investigated the influence of the dopant agent and the reactional environment conditions temperature on the reaction yield and conductivities. The polyaniline that showed the best conductivity were characterized by differential and thermal gravimetric analysis, infrared spectroscopy, X ray diffraction, and cycle voltammetry, comparing with the commercial polyaniline. (author)

  17. Characterization of superconducting coil for fault current limitation; Caracterizacao de bobina supercondutora para limitacao de corrente de curto-circuito

    Energy Technology Data Exchange (ETDEWEB)

    Polasek, Alexander; Dias, Rodrigo; Niedu, Daniel Brito; Ogasawara, Tsuneharu; Oliveira Filho, Orsino Borges de; Serra, Eduardo Torres [Centro de Pesquisas de Energia Eletrica (CEPEL), Rio de Janeiro, RJ (Brazil); Gomes Junior, George; Amorim, Helio Salim [Coordenacao dos Programas de Pos-Graduacao em Engeharia (COPPE/UFRJ), Rio de Janeiro, RJ (Brazil)

    2010-07-01

    The increasing power demand has been raising fault currents up to dangerous levels. Superconducting fault current limiters are a promising solution for this problem. In the present work, we studied a superconducting Bi-2212 coil that is used for fault current limitation. Samples were analyzed by XRD, SEM/EDS and measurement of critical temperature (Tc). The Rietveld method was employed for phase quantification. Relatively high Bi-2212 fractions were found. However, Tc varies from a sample to another one. Variations of local Tc are attributed to variations of oxygen content in Bi- 2212 phase. (author)

  18. Characterization of products of combustion of mineral coal; Caracterizacao de produtos solidos da combustao do carvao mineral

    Energy Technology Data Exchange (ETDEWEB)

    Pinheiro, H.S.; Albuquerque, J. S. V.; Sales, J.C.; Nogueira, R.E.F.Q., E-mail: hs.pinheiro@metalmat.ufc.br [Universidade Federal do Ceara (UFCE), Fortaleza, CE (Brazil). Centro de Tecnologia. Departamento de Engenharia Metalurgica e de Materiais

    2011-07-01

    During the burning of coal in power plants, various types of waste or by products are generated. These materials have been the subject of several studies. They contain ashes and have many technological applications, such as in the production of various types of ceramic pieces. The objective of this work was to study the feasibility of adding the coal combustion products as filler for ceramics. X-ray fluorescence analysis was used to identify and quantify the proportions of the elements contained in the sample and x-ray diffraction to identify the phases present. The analysis by X-ray diffraction revealed a diffraction pattern of silicon sulfide, calcium silicate and sulfide phases of Aluminium, Potassium and Titanium. X-ray fluorescence analysis showed silica (37.14%), calcium (21.86%), aluminum (14.69%) and sulfur (8.70%). These results show characteristics of materials with potential for incorporation in ceramic bodies, provided that some processing is done to eliminate the sulfur. (author)

  19. Development and characterization of the lead iodide semiconductor detector; Desenvolvimento e caracterizacao do detector semicondutor de iodeto de chumbo

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Icimone Braga de

    2001-07-01

    A methodology for purification and growth of PbI{sub 2} crystal as well as for its characterization as a room temperature radiation detector was developed in this work. Commercial salts were purified using the zone refining method and, for the purified material growth, the Bridgman method was used. To calculate the purification efficiency, studies of the decrease impurities concentrations were made in the salts and in three sections of the materials purified, using the neutron activation analysis technique. The results showed that the impurities segregate preferentially in the ingot final section. A significant decrease of the impurities concentration in function of the purification pass number was observed. The grown crystals presented good crystalline quality according to the results of the X-ray diffraction analysis. To evaluate the crystal as a semiconductor detector, measurements of dark leakage current, resistivity and the response of ({sup 241}Am) alpha particle and ({sup 241}Am, {sup 57}Co, {sup 133}Ba and {sup 137}Cs) gamma rays were carried out. The radiation response is strongly dependent on the crystals purity. The crystals purified with 500 passes exhibited energy resolution of 10% for {sup 241} Am alpha particle and the gamma rays resolution was compatible with the literature. The photosensibility of the PbI{sub 2} crystal found in the wavelength from 400 to 600 nm range suggests an another application at this crystal as a photodetector to be coupled to scintillators. (author)

  20. Clay characterization for making pressed and burned blocks; Caracterizacao da argila para confeccao de blocos prensados e queimados

    Energy Technology Data Exchange (ETDEWEB)

    Alexandre, J.; Silva, C.L. de A.P. e, E-mail: jonas@uenf.br, E-mail: caio_lobato_414@hotmail.com [Universidade Estadual do Norte Fluminense Darcy Ribeiro (UENF), Campos dos Goytacazes, RJ (Brazil)

    2012-07-01

    The municipality of Campos dos Goytacazes, located in the state of Rio de Janeiro, at 275 km from the capital, are the largest industrial ceramic state and he has over 100 unionized industries. The production of these industries is based on tiles, building blocks and bricks. Seeking the improvement and diversification of production, the North Fluminense State University has 18 years working in partnership with local industry, with students and teachers. One of the researches is the production of blocks pressed and burned. In this work are presented in many lab tests performed, morphology and some of technological properties. (author)

  1. Characterization of film-converter screens systems for neutron radiography; Caracterizacao de sistemas filme-conversor para radiografia com neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Marcos Leandro Garcia

    2002-07-01

    In general a good quality radiography is that one able to furnish high contrast and sharp edge images. Technically 'high contrast' means high capability to discern material thickness and 'sharp edges', high resolution power. In the present work the optimal conditions to obtain neutron radiography images by using the following film-converter screen systems, Kodak-AA/Gd vaporated; Kodak-AA/Gd metallic; Kodak-AA/LiF; Min-R/GdS{sub 2}O{sub 4}, have been determined. The irradiations were performed in a radiographic facility which was designed and constructed by the neutron radiography working group and is installed at the beamhole 08 of the IEA-R1 nuclear research reactor of the IPEN-CNEN/SP. In order to determine such conditions, the start point was to evaluate the neutron exposure interval for which the optical contrast is maximal and so quantify the sensitivity or capability to discern material thickness, as well as the spatial resolution achieved in the radiographic image, for these systems. The best results have been obtained for the Kodak-AA/Gd vaporated system which is able to discern, for example, 0,024 cm of lucite, with a maximal resolution of 22{mu}m. The radiography images presently obtained in IPEN-CNEN/SP have similar quality when compared to the ones from several other research centers, around the world, whose making use of the same film-converter screens systems. (author)

  2. Preparation and characterization of zirconium based colloidal suspensions; Preparacao e caracterizacao de suspensoes coloidais a base de zirconio

    Energy Technology Data Exchange (ETDEWEB)

    Chiavacci, Leila Aparecida; Pulcinelli, Sandra Helena; Santilli, Celso Valentim [UNESP, Araraquara, SP (Brazil). Inst. de Quimica

    1995-12-31

    Attention has been paid to zirconia based ceramic materials due to its technological applications, like catalysts, ionic changers, sensors, etc. Colloidal suspensions based on zirconium, containing different cation/anion molar ratio, have been prepared aiming the improvement of its extrinsical properties. The systems have been characterized by turbidimetry and the xerogels have been analysed by scanning electronic microscopy, infrared spectroscopy and x-ray diffraction. Results make evident the viability of preparation of transparent colloidal suspensions, gel and powders, in which the particles size and morphology could be controlled. (author) 3 figs.

  3. Synthesis and characterization of sulfonated polyesters derived from glycerol; Sintese e caracterizacao de poliesteres sulfonados obtidos a partir do glicerol

    Energy Technology Data Exchange (ETDEWEB)

    Fiuza, R.A.; Jose, N.M.; Boaventura, J.S. [Universidade Federal da Bahia (IQ/UFBA), Salvador, BA (Brazil). Inst. de Quimica; Fiuza, R.P. [Universidade Federal da Bahia (EP/UFBA), Salvador, BA (Brazil). Escola Politecnica. Curso de Mestrado em Engenharia Quimica

    2010-07-01

    In this work were synthesized polyesters from glycerol and acid sulfonated phthalic previously. The materials were characterized by DSC, TGA, FTIR, SEM, XRD and XRF. The results showed effective sulfonation of phthalic acid. The presence of sulfonic groups promoted strong changes in the crystallinity of the new material makes the lens. The polyesters made from phthalic acid sulfonated combine characteristics such as heat resistance and groups that drivers potentiate the electrolyte for application in fuel cells proton exchange membrane and also for gas separation. (author)

  4. Characterization of food market wastes as substrate for anaerobic digestion; Caracterizacao do lixo de CEASA como substrato para biodigestao anaerobia

    Energy Technology Data Exchange (ETDEWEB)

    Benincasa, Maria [UNESP, Botucatu, SP (Brazil). Faculdade de Ciencias Agronomicas; Lucas Junior, Jorge de [UNESP, Jaboticabal, SP (Brazil). Faculdade de Ciencias Agrarias e Veterinarias

    2000-03-01

    This research was carried out in order to study organic wastes from food markets as a substrate for anaerobic digestion. The experiment was conducted at the Department of Rural Engineering - Campus of Jaboticabal/UNESP, S P, Brazil. Biogas production data indicated the garbage potential, the fermentation time and the solids reduction for fresh garbage and dry and milled garbage. The biogas yield was 0,422 m{sup 3}/kg V S added. (author)

  5. Synthesis and characterization of hydroxyapatite-doped silver nanoparticles; Sintese e caracterizacao de hidroxiapatita dopada com nanoparticulas de prata

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Flavio Augusto Cavadas da Silva; Rollo, Joao Manuel Domingos de Almeida, E-mail: flavio.andrade@usp.br [Universidade de Sao Paulo (EESC/FMRP/IQSC/USP), Sao Carlos, SP (Brazil). Programa de Pos-Graduacao Interunidades Bioengenharia; Rigo, Eliana Cristina da Silva; Vercik, Andres; Vercik, Luci Cristina de Oliveira; Valencia, German Ayala; Ferreira, Leticcia Gaviao [Universidade de Sao Paulo (USP), Pirassununga, SP (Brazil). Faculdade de Zootecnia e Engenharia de Alimentos. Departamento de Ciencias Basicas

    2012-07-01

    Hydroxyapatite-doped silver nanoparticles was obtained by immersing the powder in increasing dilutions of a solution containing AGNPS which were synthesized in different times and were characterized by UV-vis spectroscopy. The X-ray diffraction (XRD)studies demonstrate no change in the major phase of HA. Scanning Electron Microscopy (SEM) revealed morphological characteristics of powders after doping and the presence of silver was confirmed by energy dispersive X-ray (EDAX) analysis.The antibacterial effect of the doped powders was evaluated using strain of Staphylococcus aureus by disc-diffusion test. The zone of inhibition was found to vary with the amount of silver nanoparticle in the doped powder even for low concentrations of AgNPs. These results indicate that the method of immersion hydroxyapatite in solutions containing AgNPs is promising to obtain bioactive materials with low cytotoxicity and antibacterial effects. (author)

  6. Chemistry characterization and samples beryllium process impurity determination; Caracterizacao quimica e determinacao de impurezas de amostras de processo de berilio

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Leonel Mathry de

    1992-12-01

    Brazil is the greatest world producer of beryl (3 Be O.Al{sub 2}O{sub 3}.6SiO{sub 2}) and has recently begun to produce beryllium compounds by means of a pilot plant constructed at Governador Valadares city (Minas Gerais - Brazil). The aim of this work was the determination of trace level impurities and macro constituents in the tenth % range to support analytical control process of plant production and characterization of beryllium compounds. The impurities separations and purification process was developed by two steps procedure. The first one using EDTA complexation has separated and reduced some impurities to less than 1 {mu}g/ml level. In the second one it was used a chelating resin (Chelex 100) and the separation efficiency was about 75 to 97 % related with the element tested. High pure berylium oxide standard was obtained from purification of Be(OH)2. The R X fluorescence presented only traces of Cu and Si < 1 % Fe and Mn, Zn, Ca, Al, Na and S were completely removed. The beryllium content was determined by direct atomic emission spectroscopy in argon plasma (Dcp) and compared with classic gravimetric method as Be O. The results were in agreement (49,2+/-0,2 % and 48,3+/-0,1 % respectively) between 95 % of confidence. A low temperature gravimetric method for beryllium determination was also studied using Oxine with microwave furnace. A total of 24 elements including macro and trace level were determined by Dcp and/or spectrophotometric methods. The Be/B separation was studied using anionic resin in poly alcohols medium. A more detailed study of equilibrium conditions is necessary. This work was realized at Laboratorio de Analise Mineral (LAM) of Comissao Nacional de Energia Nuclear - Rio de Janeiro (CNEN). (author)

  7. Characterization of beta radiation fields using radiochromic films; Caracterizacao de campos de radiacao beta utilizando filmes radiocromicos

    Energy Technology Data Exchange (ETDEWEB)

    Benavente, Jhonny A.; Silva, Teogenes A. da, E-mail: jabc@cdtn.b [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil). Programa de Pos-Graduacao em Ciencia e Tecnologia das Radiacoes, Minerais e Materiais; Meira-Belo, Luiz C.; Reynaldo, Sibele R. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2011-07-01

    The objective of this work was to study the response of radiochromic films for beta radiation fields in terms of absorbed dose. The reliability of the EBT model Gafchromic radiochromic film was studied. A 9800 XL model Microtek, transmission scanner, a 369 model X-Rite optical densitometer and a Mini 1240 Shimadzu UV spectrophotometer were used for measurement comparisons. Calibration of the three systems was done with irradiated samples of radiochromic films with 0.1; 0.3; 0.5; 0.8; 1.0; 1.5; 2.0; 2.5; 3.0; 3.5; 4.5 e 5.0 Gy in beta radiation field from a Sr-90/Y-90 source. Calibration was performed by establishing a correlation between the absorbed dose values and the corresponding radiochromic responses. Results showed significant differences in the absorbed dose values obtained with the three methods. Absorbed dose values showed errors from 0.6 to 4.4%, 0.3 to 31.8% and 0.2 to 47.3% for the Microtek scanner, the X-Rite Densitometer and the Shimadzu spectrophotometer, respectively. Due to the easy acquisition and use for absorbed dose measurements, the densitometer and the spectrophotometer showed to be suitable techniques to evaluate radiation dose in relatively homogeneous fields. In the case of inhomogeneous fields or for a two dimension mapping of radiation fields to identify anisotropies, the scanner technique is the most recommended. (author)

  8. Characterization of montmorillonite-Ca to use polymer nanocomposites; Caracterizacao de argila esmectitica modificada visando seu uso em nanocompositos polimericos

    Energy Technology Data Exchange (ETDEWEB)

    Neto, Joao E.; Neto, Jose C.M.; Campo, Eduardo R.B. del, E-mail: joao_evengelista_neto@yahoo.com [Universidade do Estado do Amazonas (UEAM), Manaus, AM (Brazil). Coordenacao de Engenharia de Materiais; Nascimento, Nayra R. do [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Departamento de Engenharia de Materiais e Bioprocessos; Diaz, Francisco Rolando Valenzuela [Universidade de Sao Paulo (USP), SP (Brazil). Departamento de Engenharia Metalurgica e Materiais

    2013-07-01

    Bentonite is an important type of industrial clays due to its rheological properties or accession that are dependent on its high hydrophilicity. This clay has the capability of being modified with organic compounds by treatment with ammonium quaternary salts. After the clay treatment with these salts it presents a high degree of swelling property in organic liquids. Due to this swelling characteristics, the bentonite can be used in dispersions of organic liquids viscous and thixotropic. Another focus of interest this clay is in industry and academia because of its potential use in the adsorption of toxic substances and as fillers in nanocomposites clay / polymer. The objective of this study is to characterize a Cuban calcium bentonite modified with sodium dodecyl sulfate. The clay was characterized by X-ray diffraction, particle size analysis by laser diffraction and scanning electron microscopy. (author)

  9. ISO 9001 certification in the clinical dosimetry process in physics medical service; Certificacion ISO9001 en el proceso de dosimetria clinica en un servicio de fisica medica

    Energy Technology Data Exchange (ETDEWEB)

    Font Gomez, J. A.; Andres Redondo, M. M.; Gandia Martinez, A.; Jimenez Albericio, F. J.; Mengual Gil, M. A.

    2013-07-01

    The objective of this work is to simply name a series of procedures that are part of the certification and technical instructions (manuals about how to perform specific tasks) without going into details. (Author)

  10. La farmacoutilizzazione delle statine nella pratica clinica: risultati di uno studio di popolazione condotto su database amministrativi e di medici di medicina generale

    Directory of Open Access Journals (Sweden)

    Mirko Di Martino

    2003-05-01

    Full Text Available In spite of findings of large-scale clinical trials which showed an overall reduction of morbidity and mortality from coronary heart disease in patients treated with 3-hydroxy-3-metylglutaryl coenzyme-A reductase inhibitors (statins, relatively little is still known about the real prevalence of treatment in general practice setting, particularly in patients with a high cardiovascular risk. The objective of this study was to investigate among patients with cardiovascular risk profile estimated according to the Framingham Heart Prediction Risk Study, the percentage of those exposed to statins, and the proportion of patients reaching total cholesterol (TC target levels. A cross-sectional analysis was conducted on a large cohort of patients listed in the administrative databases of the Local Health Unit of Ravenna (total resident population of 356,000. In 2001, every single patient who received a prescription for a statin, and/or with a recorded plasma TC level, and/or with a hospital admission for cardiovascular reasons (identified by ICD-9 code, and/or with a clinical appraisal based on the presence of cardiovascular risk factors, was defined eligible. Sebsequently, pharmaceutical, and nosocomial databases, were cross-linked with that of 50 general practitioners in order to assess the pharmacoutilization of statins on a patient-by-patient basis. A cohort of 9,208 patients with a well documented cardiovascular risk profile were analyzed. The mean age of those patients was 57 (SD=17 years and 42% of them was male. On the basis of raised TC levels and cardiovascular risk profiles, patients for whom a statin treatment was suggested amounted to 7,233. However, the number of those who received statins was significantly lower (n = 1,343, corresponding to 18.6%. In those exposed to statins, just a small group of patients reached a level of TC below 190 mg/dl (n = 271, equivalent to 20.2%. In the group of treated who did not achieve recommended TC target levels, 31.7% (n = 340 of patients was at very high cardiovascular risk. Moreover, among all patients with high plasma TC levels (n=5,890, there was a 45.7% (n = 2,690 who did not received any lipid lowering drug even though they had a high cardiovascular risk profile. Results from large population-based administrative databases suggest a remarkable level of undertreatment among patients with cardiovascular risk factors. Furthermore, many patients did not achieve recommended TC target levels with their statin treatment. Pharmacoutilization of statins in general practice reveals the need of a more careful pursuing of therapeutic goals.

  11. Normal behaviour of circulatory parameters during exercise. Reference values for heart rate and systemic blood pressure. The ECCIS Project data. Epidemiologia e Clinica della Cardiopatia Ischemica Silente.

    Science.gov (United States)

    Menghini, F; Dally, L; Fazzini, P F; Menotti, A; Prati, P L; Rovelli, F; Antoniucci, D; Seccareccia, F

    1995-08-01

    The study of simultaneous variations in heart rate (HR) and systemic blood pressure is of great interest in ergometric practice complementing the analysis of the ST segment by ECG. This paper examines data proceeding from 500 consecutive, normal, exercise stress tests with the aim of offering reference values on the step-by-step behaviour of HR, systolic and diastolic blood pressure (SBP, DBP) during exercise in a normal population. The sample comes from a large epidemiological study (ECCIS Project) conducted on 4842 healthy, working men, aged 40-59, which proposes to identify, by a 3 stage procedure, subjects with totally asymptomatic coronary artery disease (type I silent ischemia). A further aim of our paper is to examine the influence of some physiological variables (age, height, weight, body mass index, resting HR, SBP and DBP) on the response to effort of HR, SBP and DBP; reciprocal HR/SBP adjustment during exercise; maximal attained workload and recovery time. Due to a preliminary observation that the rate of step-by-step increase in HR and SBP is inversely related to total duration, the population was split into 4 groups according to exercise tolerance (defined by maximal attained workload) to elaborate reference values. Furthermore our data demonstrate that: 1) SBP increases more rapidly with respect to HR for older and heavier subjects; 2) Exercise tolerance is inversely related to age, baseline HR and SBP, and directly related to weight and height; 3) return to baseline conditions, during recovery, is quicker for subjects with better exercise tolerance and lower baseline HR, SBP and weight.

  12. Analysis of imaging findings and clinical abnormalities in patients with lymphoma; Analise de achados de imagem e alteracoes clinicas em pacientes com linfoma

    Energy Technology Data Exchange (ETDEWEB)

    Caldas, Flavio Augusto Ataliba; Montomiya, Carolina Tsumori [Faculdade de Medicina de Marilia, SP (Brazil)]. E-mail: flavio_caldas@hotmail.com; Silva, Helena Cristina da [Faculdade de Medicina de Marilia, SP (Brazil). Hospital de Clinicas

    2002-04-01

    Computed tomography is currently the method of choice for the diagnostic and staging of lymphomas. Computed tomography enables accurate measurements of both tumor extent and volume and provides information that can be used to plan an appropriate strategy for the treatment. The purpose of the present article is to describe and analyze the chest and abdomen computed tomography and ultrasound findings in HIV-negative patients with lymphoma. Clinical abnormalities, such as the reason the patient sought medical assistance already showing evidence of lymphocytic disease (not yet diagnosed at this point) and the physical examination abnormalities seen on the first consultation were also studied. This study comprised 30 patients: 40% with non-Hodgkin lymphoma, 46,6% with Hodgkin lymphoma, 10% with Burkitt's lymphoma and 3,3% with lymphoblastic lymphoma. (author)

  13. Evolution of sensitivity to fosfomycin in bacteria isolated in 1973, 1974 and 1975 in the Servicio de Microbiologia y Epidemiologia of the 'Clinica Puerta de Hierro', Madrid.

    Science.gov (United States)

    Dámaso, D; Moreno-López, M; Martínez-Beltrán, J

    1977-01-01

    The bacteriostatic activity of fosfomycin was studied in vitro against 1,243 clinical isolations of gram-positive cocci and 4,086 isolations of gram-negative bacilli that were obtained in 1973, 1974 and in the period from January to May of 1975. MIC was determined by the agar diffusion method, quantifying it by means of the standard curve that was worked out with the strain of E. coli NCTC 10,418. A slight increase in resistance was observed in the gram-positive cocci: 64 mug/ml were inhibitory for 63% of the 249 isolations obtained in 1973, 59.1% of the 716 isolations obtained in 1974, and 57.5% of the 278 isolations from 1975. A slight loss of sensitivity was also observed in the gram-negative bacilli: the aforementioned concentration of fosfomycin inhibited 36% of the 742 isolations from 1973, 33.6% of the 2,387 isolations from 1974 and 32.6% of the 957 isolations from 1975. 933 g of this antibiotic were consumed in our hospital in 1973, 4,203 g in 1974 and 957 g in 1975. The consumption rate per patient per year was 0.15, 0.72 and 0.20 g, respectively. In conclusion, although no change was observed in the sensitivity of some bacterial strains to fosfomycin, the overall study indicates a slight decrease in the sensitivity, although it does not apparently have any relationship to the consumption of fosfomycin in our hospital.

  14. 中医药治疗病毒性心肌炎临床研究进展%Clinica Research Progress of Chinese Materia Medica for Virus Cadiomyositis

    Institute of Scientific and Technical Information of China (English)

    韩丽华; 王振涛; 尚东丽

    2002-01-01

    @@ 病毒性心肌炎是临床常见病、多发病,近年来其发病率呈上升趋势.西医对本病无特效疗法[1],而祖国医学注重整体调节,辨证治疗,显示出对本病治疗的良好前景.现将近年来中医药临床研究概况综述如下.

  15. Clinical manifestations in patients with computerized tomography diagnosis of neurocysticercosis; Manifestacoes clinicas de pacientes com diagnostico de neurocisticercose por tomografia computadorizada

    Energy Technology Data Exchange (ETDEWEB)

    Pfuetzenreiter, Marcia Regina [Universidade do Estado de Santa Catarina (UDESC), Florianopolis, SC (Brazil). Dept. de Medicina Veterinaria Preventiva e Tecnologia]. E-mail: a2mrp@cav.udesc.br; Avila-Pires, Fernando Dias de [Santa Catarina Univ., Florianopolis, SC (Brazil). Dept. de Saude Publica

    1999-09-01

    A survey was conducted in the urban area of Lages using patients who had been submitted to a computed tomography of the skull in the period of March-December, 1996, for different reasons. Forty-two patients with a provisional diagnosis of neurocysticercosis, and 57 negatives were personally interviewed by one of the authors (Pfuetzenreiter), using a semi-structured procedure. More individuals with a provisional diagnostic of neurocysticercosis reported clinical manifestations related to this infection than those found negative. this difference is more marked among women, except in relation to convulsions, more frequently reported by men (19.05%) than by women (7.14%). The greater percentage of inactive forms (83.33%0 and a longer history of perceived symptoms among those positives suggest that the condition is not new. (author)

  16. Avaliação clinica do valor terapeutico do barbexaclone incluindo determinação de niveis plasmaticos do barbiturico

    OpenAIRE

    1980-01-01

    São apresentados os resultados de um ensaio clínico usando barbexaclone (ciclo-hexil-aminopropano) associado com fenil-etil-barbitúrico, como único anti-convulsivante. Foram selecionados 70 pacientes dos quais 36 eram do sexo feminino e 34 do sexo masculino, sendo 52 crianças e 18 adultos. Todos apresentavam crises de epilepsia tipo grande-mal e tiveram duas ou mais crises antes de serem incluídos na pesquisa. Cinqüenta e três pacientes foram observados durante 18 meses, dos quais 96% ficaram...

  17. Radiological protection in the interventional techniques: experience in the Pain Clinic of the CIMEQ; Proteccion radiologica en las tecnicas intervencionistas: experiencia en la Clinica del Dolor del CIMEQ

    Energy Technology Data Exchange (ETDEWEB)

    Guerrero C, M. C.; Benitez N, P. P.; Gonzalez G, Y. [Centro de Investigaciones Medico Quirurgicas, Av. 216 Esq. 11B, Playa Siboney, 6096 La Habana (Cuba); Martinez G, A.; Gonzalez R, N. [Centro de Proteccion e Higiene de las Radiaciones, Carretera de la Cantera, Victoria II, Km. 21.5 Guanabacoa, La Habana (Cuba); Sanchez Z, L. R., E-mail: mayka@infomed.sld.cu [Hospital C. Q. Hermanos Ameijeiras, San Lazaro 701, Centro Habana, La Habana (Cuba)

    2014-08-15

    The Pain Clinic of the CIMEQ offers treatment to patients with different pathologies, using interventional techniques as the radiology like visual guide to reach the target structure and to apply the election technique. The personnel that carry out these procedures are inserted in the program of radiological surveillance of the institution, reason for which a radiological event could be detected where the main physician responsible of the service was implied. In this work the results of an investigation are presented realized with the objective of to know the causes of the event and to determine the necessary measures to avoid that this repeats again. The investigation was oriented to three fundamental aspects: medical exam of the affected worker; evaluation of the operational procedures from the radiological protection view point; and dosimetric measurements simulating the real conditions of work for which were used ionization chamber, radiometer and PMMA mannequin. As a result of the medical exam was detected that the main physician of the service did not use during the execution of all the procedures the extremities dosimetry and that he presented a radio induced erythema in the right hand, reason for which he was separated of the activity with ionizing radiations, until the conclusion of the investigation. With relationship to the evaluation of the operational procedures from the radiological protection view point, was verified that the medical physician not carried out any collimation of the beam and he was located in the positions where the dose rate reached the maximum values, frequently introducing the hands in the direct beam; that which implied an overexposure of the superior extremities and a not optimized exposure for whole body. This result was proven with the realized experimental measurements, which gave dose estimated values in extremities of the order of the deterministic effects. The investigation facilitated to introduce modifications in the operational procedures from the radiological protection view point that allowed optimizing the occupational exposure and to avoid the appearance of deterministic effects on the workers of this practice. Parallel was carried out the completion of the protection individual media and working media that allowed the proper application of the mentioned procedures were substituted. On the other hand, this investigation pointed to that the personnel training in radiological protection matter and the control of the occupational exposure in the interventional techniques are indispensable for the safe performance of the medical practice. (author)

  18. Laser diagnostic and therapy of dental caries: the clinic point of view; Laser diagnostico e tratamento da carie dental: uma visao clinica

    Energy Technology Data Exchange (ETDEWEB)

    Paiva, Priscila Faria

    2001-07-01

    Dental caries's diagnosis is a major dentistry problem from the clinic point of view. The laser beam on the region of 655 nm induces the fluorescence of the compounds present in the hard tissue, quantifying differences between sound and carious enamel and dentine. Diagnodent (Kavo, Germany), showed to be effective regarding dental caries's diagnosis in the present research sampling. The Er:YAG laser (Kavo Key Laser 2, Germany) performed efficient cavity preparations in caries lesions of I and V class type, using up energies that ranged from 300 mJ to 350 mJ with 4 Hz repetition rate for the enamel; and from 250 mJ to 300 mJ with 4 Hz repetition rate for the dentine, and with 80 mJ with 6 Hz of repetition rate for laser conditioning. In the Er:YAG laser preparations no patient was anesthetized even when there were deeper cavities, and the maximum degree of pain ( which ranged from 0 to 10) was 4. In the control group with conventional high-speed drill two patients were anesthetized and the maximum degree of pain was 7. Restorations performed by conventional method of composite were equally satisfying both in caries groups of I and V class type and in the control group. The laser application in the operative dentistry office as a new method of diagnosis and dental preparations should be a good alternative to the use of the conventional dental drill. Nevertheless, dentistry practice has a lot to improve from technology progress, as well as new researches on laser dentistry are necessary in a long term. New types of lasers will come about and will increasingly improve the dental practice assistance and procedures quality. (author)

  19. Utilizzo dell'esame dermoscopico nella valutazione clinica e nel follow up dei nevi melanocitici in sede acrale dell'età pediatrica: studio retrospettivo osservazionale

    OpenAIRE

    Bentivogli, Margherita

    2012-01-01

    La dermoscopia, metodica non invasiva, di pratico utilizzo e a basso costo si è affermata negli ultimi anni come valido strumento per la diagnosi e il follow up delle lesioni cutanee pigmentate e non pigmentate. La presente ricerca è stata incentrata sullo studio dermoscopico dei nevi melanocitici a localizzazione palmo-plantare, acquisiti e congeniti, in età pediatrica: a questo scopo sono state analizzate le immagini dei nevi melanocitici acrali nei pazienti visitati c/o l’ambulatorio di...

  20. Dermatoses pediátricas no Hospital das Clínicas da Universidade Federal de Pernambuco Pediatric dermatoses at the Clinicas Hospital, Federal University of Pernambuco

    Directory of Open Access Journals (Sweden)

    Josemir Belo dos Santos

    2004-05-01

    Full Text Available FUNDAMENTOS: Numerosas condições dermatológicas podem afetar a população pediátrica. Há poucos estudos sobre a dermatologia pediátrica no Brasil. OBJETIVOS: Estudar as dermatoses pediátricas no Hospital das Clínicas do Recife, Pernambuco - Brasil. MATERIAL E MÉTODOS: Durante o período de maio de 1999 a maio de 2000, foram analisados 307 prontuários de crianças atendidas no Ambulatório de Dermatologia da Universidade Federal de Pernambuco. Foram encontrados os dados referentes a caracterização individual, procedência, motivo da consulta, diagnóstico clínico laboratorial e tratamentos previamente realizados. RESULTADOS: As dermatoses alérgicas foram as mais freqüentes (17,64%, seguidas pelas desordens pigmentares (15,54% e infecções virais (13,44%. CONCLUSÃO: Os dados encontrados estão de acordo com a literatura. Quanto às infecções, representam um grande percentual dos casos analisados, devendo-se isso provavelmente ao baixo nível socioeconômico dos pacientes em estudo. A caracterização da epidemiologia dos problemas cutâneos em crianças deve ser uma prioridade de estudos futuros.BACKGROUND: Numerous skin conditions can affect the pediatric population. There are few studies on Pediatric Dermatology in Brazil. OBJECTIVES: To study the pediatric skin diseases at the Hospital das Clínicas in Recife, Pernambuco State - Brazil. MATERIAL E METHODS: From May 1999 to May 2000, 307 cases of children treated at the Dermatology Clinic of the Federal University of Pernambuco were studied. Details of the patients' features, origin, reason for consultation, clinical laboratory diagnosis and previous treatment were examined. RESULTS: Allergic dermatosis was the most frequent disease (17.64%, followed by disorders of pigmentation (15.54% and viral diseases (13.44%. CONCLUSION: This agrees with the literature. Infections represent a large percentage of cases studied and are probably due to the low socioeconomic level of the patients examined. Characterization of the epidemiology of cutaneous problems in children should be a priority in future studies.

  1. Breast cancer only detected at US. Incidental finding or clinical evidence?; Le neoplasie mammarie visualizzabili solo con esame ecografico. Reperti incidentali o realta' clinica?

    Energy Technology Data Exchange (ETDEWEB)

    Nori, J.; Masi, A.; Boeri, C.; Vivian, A.; Nori Bufalini, F. [Azienda Ospedaliera Careggi, Florence (Italy). Unita' Operativa di Radiodiagnostica 2; Cariti, G. [Florence Univ., Florence (Italy). Dipt. di Ginecologia e Ostetricia

    2000-06-01

    Mammography is the only technique of proven efficacy in the early diagnosis of breast cancer, even though its sensitivity is much lower in breasts that are dense or with a high parenchymal-stroma component. In the past malignant breast nodules detected at US in patients with negative mammographic and physical findings were considered incidental findings, but more recent papers report increasing numbers of breast cancers detected only at US. It was investigated the yield of US performed as a diagnostic complement in asymptomatic women with mammographic findings that were either negative or poorly readable because of dense breast. 13 women were examined: 37 to 55 years old (mean 47): 9 of them were asymptomatic and 4 had poorly specific physical findings. The patients underwent physical examination, mammography, US, micro histologic biopsy with 14G needles under US guidance and surgery. Fourteen breast lesions 7.0-15 mm in diameter were detected only by US. Mammography (2 or 3 standard views) was negative in all cases. The lesions detected only by US (10% of all carcinomas) were typified with US-guided needle biopsy and finally confirmed surgically. Though obtained in a small series, the results seem to suggest that US should be included in the diagnostic work-up, especially of women with dense breast. Also, any hypoechoic lesion detected at breast US in clinically asymptomatic women with negative mammographic findings should be further investigated with US, needle aspiration or core biopsy to make the final diagnosis. [Italian] Si intende con questo lavoro valutare l'utilita' dell'esame ecografico, eseguito come completamento diagnostico in donne clinicamente negative e con mammografia negativa o comunque scarsamente leggibile in relazione alla elevata densita' del parenchima mammario (mammelle dense). Tredici donne con eta' compresa tra 37 e 55 anni (eta' media 47 anni) asintomatiche o con quadri clinici vaghi o comunque non orientativi per patologia neoplastica della mammella hanno eseguito esame clinico, mammografia, ecografia mammaria, prelievo microistologico ecoguidato e intervento operatorio. Quattordici neoplasie mammarie, con dimensioni comprese tra 7 e 15 mm sono state evidenziate solo ecograficamente. La mammografia eseguita nelle 2 o 3 incidenze abituali, e' risultata sempre negativa. Le lesioni neoplastiche evidenziate solamente con l'esame ecografico (10% di tutti i carcinomi) sono state caratterizzate con biopsia istologica con ago da 14G e definitivamente confermate con intervento chirurgico. I risultati ottenuti permettono di suggerire che l'esame ecografico debba essere metodica da includere nell'iter diagnostico nelle donne con mammelle scarsamente leggibili. Le lesioni nodulari ipoecogene sospette rilevate all'esame ecografico in una donna con visita e mammografia negative meritano di essere ulteriormente approfondite (controllo con ecografia, agoaspirazione per citologia o biopsia istologica con ago) al fine di ottenere la definitiva caratterizzazione.

  2. Management units radio physics hospital clinic: New management model; Unidades de gestion clinica de radiofisica hospitalaria, ¿nuevo modelo de gestion?

    Energy Technology Data Exchange (ETDEWEB)

    Iborra Oquendo, M.; Angulo Pain, E.; Castro Ramirez, I.; Quinones Rodriguez, L. A.; Urena Llinares, A.; Richarter Reina, J. M.; Lupiani Castellanos, J.; Ramos Caballero, L. I.

    2011-07-01

    Clinical management in the Andalusian Health Service is a process of organizational design that allows professionals to incorporate the management of resources used in their own clinical practice. In the Clinical Management Units activity develops according to different objectives, among them: encourage the involvement of health professionals in managing the centers, enhance continuity of care between the two levels of care, improve work organization and raise patient satisfaction.

  3. Schistosomiasis of the central nervous system: clinical and radiologic correlation; Apresentacoes da esquistossomose no sistema nervoso central: correlacao clinica e radiologica

    Energy Technology Data Exchange (ETDEWEB)

    Faria, Andreia Vasconcelos; Cerqueira, Elza Maria Figueiras Pedreira de; Reis, Fabiano; Menezes Neto, Jose Ribeiro; Zanardi, Veronica de Araujo [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Ciencias Medicas. Dept. de Radiologia]. E-mail: andrea.vf@ig.com.br; Pirani, Clodoaldo; Damasceno, Benito Pereira [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Ciencias Medicas. Dept. de Neurologia

    2002-02-01

    We report four cases of patients with schistosomiasis in the central nervous system and describe and correlate the radiologic findings with clinical manifestations. In one patient, cerebral involvement presented as a pseudotumoral lesion confirmed by autopsy. Three other patients had schistosomiasis in the spinal cord characterized by an intramedullary mass and radicular and leptomeningeal enhancement after administration of gadolinium. Our findings show the importance of considering schistosomiasis in the differential diagnosis of intramedullary or cerebral lesions in patients of endemic areas of schistosomiasis. (author)

  4. [Congenital toxoplasmosis: clinical manifestation, treatment and follow-up] [Article in Italian] • Il neonato con toxoplasmosi congenita: clinica, terapia e follow-up

    Directory of Open Access Journals (Sweden)

    Lina Bollani

    2014-01-01

    Full Text Available Toxoplamosis is a parasitic zoonosis which occurs worldwide, but is prevalent in Europe, South America and Africa. When infection occurs for the first time during pregnancy, mother to child transmission of the parasite can cause congenital toxoplasmosis. Rate of congenital infection ranges from less than 0.1 to approximately 1 per 1,000 live births. The risk of transmission depends on the gestational age at the time of maternal infection. A diagnosis of congenital toxoplasmosis is usually considered in infants who present: hydrocephalus, chorioretinitis, and intracranial calcifications, but this triade is very rare. Approximately 85% of the infants with congenital toxoplasmosis are clinically normal at birth; however, sequelae of infection may become apparent only months or even years later. Chorioretinitis is the main complication of congenital toxoplasmosis, late onset retinal lesions and relapse can appear many years after birth, but the overall ocular prognosis is satisfactory when infection is identified and treated accordingly. Fortunately, serious neonatal forms and severe neurological impairment have become rare, but prompt treatment of children with convulsions, abnormal muscle tone, hydrocephalus, may improve the prognosis and result in almost normal outcome. For infants who have congenital toxoplasmosis, treatment soon after birth for 1 year with pyrimetamine, sulfadiazine and leukoverin led to remarkable resolution of serious, active disease. A long follow-up is necessary to assess the long-term outcome of children and young adults with congenital toxoplasmosis, that is favourable for the majority of cases. Epidemiological surveillance needs to be improved in order to determine the effectiveness of prevention programs.Articoli Selezionati del “3° Convegno Pediatrico del Medio Campidano” · Guspini · 25 Maggio 2013Guest Editor: Roberto Antonucci

  5. Alienacion de la Madre, Psicopatoligia y la Practica Clinica en Mexico. (Alienation of the Mother, Psychopathology, and the Practice Clinic in Mexico).

    Science.gov (United States)

    Diaz-Guerrero, Rogelio; And Others

    1979-01-01

    The study related the role of the maternal figure to the affective behavior of the Mexican. Two hundred adolescents judged the concept of "Insult to the Mother" in relation to other similarly charged affective concepts, e.g., "death", "suicide", "drunkenness", etc. Results showed that "Insult to the…

  6. MonitorNet: studio italiano osservazionale multicentrico per la valutazione del profilo rischio-beneficio dei farmaci biologici nella pratica clinica reumatologica

    Directory of Open Access Journals (Sweden)

    S. Bombardieri

    2011-06-01

    Full Text Available Over the last decade, several new biologic agents have become available for the treatment of patients with rheumatoid arthritis (RA, psoriatic arthritis (PsA, ankylosing spondylitis (AS and psoriasis (Ps. In contrast to conventional disease modifying anti-rheumatic drugs (DMARDs, these biological agents have rapid onset of action and pronounced disease reducing activity when administered as monotherapy or in combination with MTX. Pre-registration randomised clinical trials have compared biological agents against placebo over a limited time span (1-3. Wider use of biologics has resulted in reports of a wide range of adverse events (4, including evidence of reactivation of latent tuberculosis, increased incidence...

  7. Hepatic hemangio-endothelioma: radiological findings and clinical evolution of a case; Hemangioendotelioma hepatico: aspectos radiologicos e evolucao clinica de um caso

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho Neto, Arnolfo de; Souza, Carolina Althoff; Yanaga, Ricardo Hideki [Parana Univ., Curitiba, PR (Brazil). Hospital de Clinicas. Servico de Radiologia; Albonei, Mara [Parana Univ., Curitiba, PR (Brazil). Hospital de Clinicas. Dept. de Pediatria]. E-mail: carolina_althoff@hotmail.com

    2003-02-01

    Vascular tumors encompass a spectrum of lesions, which may vary from benign hemangiomas to malignant angio sarcomas. Hemangio-endotheliomas can be considered intermediary between these two types of lesions. We report a case of hepatic hemangio endothelioma in a newborn female and review the most important aspects of this disease. (author)

  8. Development of software for management of radioactive waste in biological research and clinical assistance; Desenvolvimento do software para gerenciamento de rejeitos radioativos em pesquisa biologica e assistencia clinica

    Energy Technology Data Exchange (ETDEWEB)

    Maciel, Bianca; Mattos, Maria Fernanda S.S.; Medeiros, Regina B. [Universidade Federal de Sao Paulo (UNIFESP/EPM), Sao Paulo, SP (Brazil). Dept. de Diagnostico por Imagem. Nucleo de Protecao Radiologica; Franca Junior, Jose Antonio de, E-mail: fernanda@cfhr.epm.b, E-mail: rbitelli@cfhr.epm.b, E-mail: jafjunior@unifesp.b [Universidade Federal de Sao Paulo (UNIFESP/EPM), Sao Paulo, SP (Brazil). Dept. de Tecnologia da Informacao. Div. de Sistema de Informacao

    2011-10-26

    This paper describes the development of software which facilitates the automation of this process by mean of the Safety Analysis Report generating a data base allowing the statistic analysis and elaboration of radioactive wastes inventory. The software was developed in PHP language and the information is stored in a data base generated in Oracle and organized in different tables which allows to calculate the storage time of waste and to register the specificities of radioisotopes, cadastral data of the professionals which handle that radioisotope and also the characteristics of handling laboratories. That tool collaborates for a effective control on the use of radioisotopes in research laboratories and assistance areas as well

  9. Discussão genetico-clinica sobre a Síndrome de Apert: a propósito de um caso

    Directory of Open Access Journals (Sweden)

    Aguinaldo Gonçalves

    1976-09-01

    Full Text Available Após breve introdução sobre a síndrome de Apert, é relatado um caso clínico, sendo destacada a conduta genético-clínica. A discussão revela como os aspectos genéticos envolvidos orientam o raciocínio clínico.

  10. Proposta de uma definição generica do narcisismo como fundamento epistemologico para a sua investigação na teoria e na clinica psicanaliticas

    OpenAIRE

    Paulo de Tarso Ubinha

    2004-01-01

    Resumo: Este trabalho visa construir uma definição genérica ficientemente ampla do narcisismo, que abarque todas as linhas possíveis de investigação, sem privilegiar nenhuma delas, para estabelecer um terreno conceitual comum para toda pesquisa sobre este tema. Para tanto, o autor estudou quatro versões correntes do mito grego de Narciso, assinalando os aspectos relevantes do ponto de vista psicanalítico, procedeu a uma análise do texto capital de Freud, "Sobre o Narcisismo: uma Introdução", ...

  11. EFECTO DE LOS TRATAMIENTOS ODONTOLOGICOS EN LA DISFUNCION TEMPORO MANDIBULAR EN ALUMNOS DE LA CLINICA ODONTOLOGICA EN LA UNIVERSIDAD CATOLICA DE SANTA MARÍA, AREQUIPA 2008

    OpenAIRE

    DÍAZ ANDRADE, CARLOS JAVIER

    2015-01-01

    DISFUNCION TEMPORO MANDIBULAR TRATAMIENTO DE LOS TRASTORNOS DE LOS MÚSCULOS MASTICATORIOS CO-CONTRACCIÓN PROTECTORA (FIJACIÓN MUSCULAR) DOLOR MUSCULAR LOCAL (MIALGIA NO INFLAMATORIA) CARACTERÍSTICAS CLÍNICAS TRATAMIENTO DEFINITIVO DOLOR MIOFASCIAL (MIALGIA POR PUNTOS GATILLO) MIALGIA CRÓNICA DE MEDIACIÓN CENTRAL (MIOSITIS CRÓNICA) FIBROMIALGIA (FIBROSITIS) TRATAMIENTO DEL BRUXISMO NOCTURNO TRATAMIENTOS ODONTOLOGICOS TRATAMIENTO CON FÉRULAS OCLUSALES

  12. Alienacion de la Madre, Psicopatoligia y la Practica Clinica en Mexico. (Alienation of the Mother, Psychopathology, and the Practice Clinic in Mexico).

    Science.gov (United States)

    Diaz-Guerrero, Rogelio; And Others

    1979-01-01

    The study related the role of the maternal figure to the affective behavior of the Mexican. Two hundred adolescents judged the concept of "Insult to the Mother" in relation to other similarly charged affective concepts, e.g., "death", "suicide", "drunkenness", etc. Results showed that "Insult to the Mother" was viewed very negatively. (NQ)

  13. Gli antagonisti del recettore GPIIb/IIIa: farmacologia, clinica ed economia nelle sindromi coronariche acute NSTEMI e nelle rivascolarizzazioni per via percutanea

    Directory of Open Access Journals (Sweden)

    Lorenzo Pradelli

    2005-12-01

    Full Text Available Inhibition of platelet glycoprotein IIb/IIIa (GP IIb/IIIa receptor prevents platelet aggregation by controlling its final common pathway, the cross-binding of fibrinogen, bridging across adjacent platelets. Three pharmacological agents capable of inhibiting GP IIb/IIIa are available for use in Italy: abciximab, eptifibatide and tirofiban. In this paper, some relevant studies on the pharmacology of GP IIb/IIIa inhibitors are summarized, as well as the main clinical trials assessing their use in the management of unstable angina (UA and during percutaneous coronary interventions (PCI. Furthermore, the recommendations on their appropriate use in UA and PCI issued by authoritative scientific societies are presented. Finally, some of the pharmacoeconomic evidence published in the international literature is reviewed and implications in the Italian health care setting are discussed.

  14. ClinicaI Reversible Myelopathy in T-Cell Lymphoblastic Lymphoma Treated with Nelarabine and Radiotherapy: Report of a Case and Review of Literature of an Increasing Complication

    Directory of Open Access Journals (Sweden)

    Maria Chiara Tisi

    2015-02-01

    Full Text Available To date, eleven cases of irreversible neurological defects in T- ALL patients treated with nelarabine have been described in the last 4 years, seven of these after stem cell transplantation (SCT for T Lymphoblastic Lymphoma (T-LBL. Most of patients had an unfavorable outcome or irreversible damage. We report the case of a 41-year-old woman suffering from T-LBL who presented severe but reversible myelopathy after nelarabine based treatment and mediastinum radiotherapy, and we perform a review of literature.

  15. Valutazione analitica e applicazione clinica di un metodo Real Time PCR per il dosaggio della carica virale di Epstein-Barr virus

    Directory of Open Access Journals (Sweden)

    Maria Teresa Bortolin

    2004-03-01

    Full Text Available We assessed the performance of a Real Time PCR assay to be used for EBV viremia evaluation in clinical specimens. Sensitivity and intra-/interassay reproducibility were evaluated by using DNA serial dilutions from the Namalwa cell line. EBV DNA was analyzed in serum samples from 39 patients (pts with undifferentiated type nasopharyngeal carcinoma (UCNT, from 5 infectious mononucleosis (IM pts and from 18 healthy donors. Results obtained by Real Time PCR were compared with those obtained by quantitative competitive (QC-PCR assay.We thereafter measured the dynamics of EBV DNA load in 5 HIV-seropositive (HIV+ and 9 HIV-seronegative (HIV-, as controls pts with lymphoma, treated with high-dose chemotherapy (HCT followed by autologus stem-cell transplantation (ASCT. We found a sensitivity of 100% at 10 EBV copies. The Spearman correlation for both the intra- and the interassay reproducibility was statistically significant (r=0.99; p20 copies/reaction and >30% for EBV viral loads <20 copies/reaction. No EBV DNA was detected in healthy donors. Higher EBV DNA loads were found by Real Time PCR (range 1173-46328 copies/ml than by QC-PCR (range 450-5000 copies/ml (p<0.05. 54% of UCNT and 100% of IM pts were EBV DNA positive. Two HIV+(40% and 2 HIV-(22% pts with lymphoma had detectable EBV viremia during the follow-up. The Real Time PCR is a suitable technique for high-throughput screening and frequent monitoring of patients at risk for developing EBV-associated diseases.

  16. Lo studio FAST: FAringotonsillite STreptococcica in età pediatrica Impatto farmacoeconomico delle Linee Guida dell’American Academy of Pediatrics sulla pratica clinica di 600 pediatri italiani

    Directory of Open Access Journals (Sweden)

    G. L. Colombo

    2002-06-01

    Full Text Available The American Academy of Pediatrics (AAP has recently published its new guidelines for the treatment of pediatric tonsillopharyngitis; a diagnostic test for the detection of streptococci is recommended, followed by a treatment with penicillins (10 days or cephalosporins (5 days in case of positivity, and by no treatment otherwise. The success of a guideline, in general, depends on its diffusion in practice and on its adaptability to different local settings. The aim of the present study (FAST was the evaluation of the clinical and economical impact of the application of the AAP guidelines in the Italian reality. The study was conducted with the cooperation of 600 pediatricians, uniformly distributed on the Italian territory, and involved 3072 patients. The pediatricians were left free to decide whether to follow the guidelines or not. The results of the analysis indicate that only some 20% of the pediatricians adhered to the suggested protocol; the total cost (calculated in the perspective of the National Health System, with a time horizon of about 3 months per patient, nonetheless, resulted inferior in the group treated according to the proposed protocol (50,45 • vs. 53,30 •. Furthermore, a lower incidence of complications occurred in these patients. Among the “off-protocol” behaviors, two showed particularly evident misuse of health resources: inappropriate treatment after test positivity (59,15 •/patient, and treatment after test negativity (14% of the total population. Another interesting, although not surprising, result of this study was the evidence that penicillins are as effective as cephalosporins in the short-term, but significantly inferior in terms of complications, positivity for streptococci at the control test, and complications detected at follow-up.

  17. Gallbladder carcinoma in the "Hospital de Clinicas" of Uruguay: 1998-2002. A clinicopathologic study of five cases in 802 cholecystectomies.

    Science.gov (United States)

    Barcia, Juan José; Rodríguez, Ana; Siri, Leonardo; Masllorens, Ana; Szwebel, Patricia; Acosta, Gisĕle

    2004-02-01

    Five cases of primary carcinoma of the gallbladder are presented. The cases were identified after a study of 802 cholecystectomies in a period of 5 years. The patients are three women and two men between the ages of 43 and 60 years (mean, 55.8 years). In three cases the clinical diagnosis was that of carcinoma, while in two other patients the clinical diagnosis was that of acute cholecystitis. Grossly, all cases were characterized by a gray-white diffuse or focal plaque-like thickening of the gallbladder wall, with loss of the normal velvety mucosal surface and fibrosis of the organ. Histologically, four cases belong to moderately to poorly differentiated adenocarcinoma and were characterized by infiltrative, irregularly shaped and sized glands, islands, nests, and cords. The cells showed pleomorphic nuclei with clumped chromatin and frequent single nucleoli. One case was a mucinous adenocarcinoma characterized by large pools of mucoid material with neoplastic glands and cells "floating" within. Pathologic staging was pT3 in three cases; pT2 in one case; and pT2N1 in one other case. The present study highlights the importance of careful gross and histopathologic evaluation of gallbladders otherwise removed with the history of chronic or acute cholecystitis. In addition, it highlights the incidence of gallbladder carcinoma in a particular institution.

  18. Use of semiconductor detector c-Si microstrip type in obtaining the digital radiographic imaging of phantoms and biological samples of mammary glands; Empleo de detector semiconductor de c-Si del tipo microbandas en la obtencion de imagenes radiograficas digitales de maniquies y muestras biologicas de mamas

    Energy Technology Data Exchange (ETDEWEB)

    Leyva, A.; Cabal, A.; Pinera, I.; Abreu, Y.; Cruz, C. M. [Centro de Estudios Avanzados y Desarrollo Nuclear, C. Habana, Cuba (Cuba); Montano, L. M.; Diaz, C. C.; Fontaine, M. [IPN, Centro de Investigaciones y Estudios Avanzados, Mexico D. F. (Mexico); Ortiz, C. M. [ISSSTE, Hospital General Tacuba, Clinica de Mama y Gineco-oncologia, Mexico D. F. (Mexico); Padilla, F. [Instituto Superior de Tecnologias y Ciencias Aplicadas, C. Habana, Cuba (Cuba); De la Mora, R. [Centro de Control Estatal de Equipos Medicos, C. Habana, Cuba (Cuba)], e-mail: aleyva@ceaden.edu.cu

    2009-07-01

    The present work synthesizes the experimental results obtained in the characterization of 64 micro strips crystalline silicon detector designed for experiments in high energies physics, with the objective of studying its possible application in advanced medical radiography, specifically in digital mammography and angiography. The research includes the acquisition of two-dimensional radiography of a mammography phantom using the scanning method, and its comparison with similar images simulated mathematically for different X rays sources. The paper also shows the experimental radiography of two biological samples taken from biopsies of mammas, where it is possible to identify the presence of possible pathological lesions. The results reached in this work point positively toward the effective possibility of satisfactorily introducing those advanced detectors in medical digital imaging applications. (Author)

  19. Image quality control of mammography equipment -Mammography System MX-300- of the Teachers Hospital of UNSA and dose measurement in breasts with radiographic films; Control de calidad de imagen del equipo de mamografia -Mammography System MX-300- del Hospital de Docentes de la UNSA y medicion de dosis en mamas con peliculas radiograficas

    Energy Technology Data Exchange (ETDEWEB)

    Quispe F, L. K.; Vega R, J., E-mail: karinaqflores839@gmail.com [Universidad Nacional de San Agustin, Escuela Profesional de Fisica, Arequipa (Peru)

    2015-10-15

    This work is part of medical imaging for the evaluation of quality. Will have an accredited breast phantom Rmi-156 that allows evaluating the image quality of mammography equipment and through a series of techniques and processes that will submit to mammography films we obtain characteristic curves, which allows to evaluate different parameters that will serve for our study. Images were acquired with different k Vp and m As of the equipment, also with different thicknesses of the breast phantom. Also we want to use the lowest possible dose for obtaining our images. In this paper we develop a simple protocol that aims to unify the conditions under which are acquired the images for later evaluation. By obtaining these characteristic curves demonstrate that the Kodak film is the most suitable for our study because it requires lower dose for obtaining our images. (Author)

  20. Utilização de um novo material mesoporoso funcionalizado PABA-MCM-41 na remoção de hidrocarbonetos policíclicos aromáticos (HPAs)

    OpenAIRE

    Costa, José Arnaldo Santana

    2013-01-01

    Este trabalho descreve a sintese e caracterizacao do material mesoporoso MCM-41 e do novo material mesoporoso funcionalizado PABA-MCM-41 para serem utilizados como materiais adsorventes na remocao dos HPAs benzo[k]fluoranteno (B[k]F), benzo[a]pireno (B[a]P) e benzo[b]fluoranteno (B[b]F). Os dois materiais foram sintetizados pelo metodo hidrotermal, sendo que PABA-MCM-41 foi sintetizado pelo metodo hidrotermal/co-condensacao, o qual foi funcionalizado pelo acido 4-aminobenzoico modificado. Os ...

  1. Study and rheological characterization of various bone ash porcelain formulations; Estudo e caracterizacao reologica de diferentes formulacoes de porcelana de cinza de ossos

    Energy Technology Data Exchange (ETDEWEB)

    Carus, L.A.; Bento, L.; Braganca, S.R., E-mail: laucarus@gmail.com [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Programa de Pos-Graduacao em Engenharia de Minas, Metalurgica e de Materiais

    2012-07-01

    The bone ash porcelain is a widely accepted product on the market because their qualities such as high strength and whiteness, to differ from common table porcelains. Its traditional formulation comes from an English recipe, consisting of 25% of kaolin, 25% of feldspar and 50% of bovine bone ash. In some studies, this proportion is adapted to regional conditions, optimizing the formulation according to the raw materials available. In this study, the rheological behavior of bone porcelain suspensions, in which the flux feldspar is partially substituted by an alternative flux (espudomenio, wollastonite and glass). The results show that the rheological behavior of porcelain is affected by the size, shape, surface area and particle size distribution of particles in suspension.

  2. Synthesis and characterization of alumina precursor and alumina to be used as nano composite; Sintese e caracterizacao de precursores de alumina e alumina para uso em nanocompositos

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, M.L.P., E-mail: malu@sorocaba.unesp.b [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Sorocaba, SP (Brazil); Santos, H. Souza [Universidade de Sao Paulo (IF/USP), SP (Brazil). Inst. de Fisica; Santos, P. Souza [Universidade de Sao Paulo (EP/USP), SP (Brazil). Escola Politecnica

    2009-07-01

    With the evolution of nanomaterials technology, mainly in the 90s, it was possible to observe produced composites with alumina matrix and nanomaterial as reinforcing materials. It results in a significant improvement of mechanical proprieties of these composites. Thenceforth the study of synthesis and characterization of nanostructured materials has attracted great scientific interest. In this perspective, the aim of this work is to present an experimental procedure to obtain nordstrandite (aluminum hydroxide) with nanometric dimensions. Nordstrandite synthesis, obtained by the reaction of slightly amalgamated aluminum foil with aqueous ethylene glycol, which allows the control of the size of crystal produced. This control could be confirmed by X-Ray Diffraction and Electron Microscopy. Thermal transformation study is also presented. This study allowed the identification of transition aluminas that have potential to produce nanometric aluminas. (author)

  3. Characterization and evaluation of residue 'grits' of the cellulose industry; Caracterizacao e avaliacao do resisduo 'grits' da industria de celulose

    Energy Technology Data Exchange (ETDEWEB)

    Destefani, A.Z.; Santos, M.M.; Holanda, J.N.F. [Universidade Estadual do Norte Fluminense Darcy Ribeiro (LAMAV/CCT/UENF), Campos dos Goytacazes, RJ (Brazil). Lab. de Materiais Avancados

    2010-07-01

    The cellulose industry generates huge amounts of solid waste residue called 'grits'. These wastes have been willing over time in landfills near the mills. However, this type of disposal is not environmentally friendly and can cause degradation and environmental pollution. In addition, environmental legislation increasingly severe and the high costs of landfill have led the search for new alternatives for final disposition of this abundant waste. In this context, this study is to characterize waste grits, generated by the cellulose industry in the region of Aracruz-ES. The residue samples were characterized in terms of chemical composition, X-ray diffraction, particle size distribution and thermal analysis (DTA and TGA). The characterization of the residual 'grits' demonstrated its potential as a feedstock for production of soil-cement bricks. (author)

  4. Resources partial characterization of energy offer for the resources integrated planning; Caracterizacao parcial de recursos de oferta de energia para o planejamento integrado de recursos

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Felipe Coelho; Grimoni, Jose Aquiles Baesso; Galvao, Luiz Claudio Ribeiro [Universidade de Sao Paulo (EPUSP), SP (Brazil). Escola Politecnica. Dept. de Engenharia e Automacao Eletricas. Grupo de Energia], e-mail: felipecoelhocosta@gmail.com; Udaeta, Miguel Edgar Morales [Universidade de Sao Paulo (IEE/USP), SP (Brazil). Inst. de Eletrotecnica e Energia

    2008-07-01

    This paper characterizes the assessment process of the Offer Side Energy Resources (OSER) in the Resources Integrated Planning (RIP) of the Administrative Region of Aracatuba, Sao Paulo. The complete characterization included the main biomass resources of the region. The characterization, or valuation, of the energetic resources encompass different four dimension criteria which are technical-economical, environmental, social and political, by using attributes and sub-attributes which allow the description in a complete way the resources.

  5. Methodology for the analysis and characterization of the demand side energy resources; Metodologia para analise e caracterizacao dos recursos energeticos do lado da demanda

    Energy Technology Data Exchange (ETDEWEB)

    Baitelo, Ricardo Lacerda; Udaeta, Miguel Edgar Morales [Universidade de Sao Paulo (USP), SP (Brazil). Dept. de Energia e Automacao Eletricas. Grupo de Energia; Burani, Geraldo Francisco; Grimoni, Jose Aquiles Baesso [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Energia e Eletrotecnica

    2006-07-01

    This abstract aims at describing briefly a model for the assessment of demand side energy resources This model intends to comprehend every kind of action and measure related to demand side management and energy conservation, evaluating them in a holistic way, into four dimensions: technical-economical, environmental, social and political. Different aspects regarding the resources are also accounted, such as energetic potentials (theoretical, accomplishable and economic). At last, scenarios concerning the introduction of evaluated resources through a period of time are elaborated. (author)

  6. Structural characterization of aquatic humic substance extracted from Itapanhau and Ribeira de Iguape rivers; Caracterizacao estrutural das substancias humicas aquaticas extraidas dos Rios Itapanhau e Ribeira de Iguape

    Energy Technology Data Exchange (ETDEWEB)

    Goveia, Danielle; Rocha, Julio Cesar [UNESP, Araraquara, SP (Brazil). Inst. de Quimica; Oliveira, Luciana Camargo de [Universidade Federal de Sao Carlos (UFSCar), Sorocaba, SP (Brazil); Morais, Leandro Cardoso de; Campos, Valquiria de; Fraceto, Leonardo Fernandes; Rosa, Andre Henrique [UNESP, Sorocaba, SP (Brazil). Dept. de Engenharia Ambiental

    2011-07-01

    The knowledge of the structure characteristic of the Organic Matter is important for the understanding of the natural process. In this context aquatic humic substances (principal fraction) were isolated from water sample collected from the two distinct rivers, using procedure recommended for International Humic Substances Society and characterized by elemental analysis, electron paramagnetic resonance and nuclear magnetic resonance (1{sup 3C} NMR). The results were interpreted using principal component analysis (PCA) and the statistical analyses showed different in the structural characteristics of the aquatic humic substances studied. (author)

  7. Synthesis of zeolites from boiler fly ash: physical, chemical and mineralogical characterization; Sintese de zeolitas a partir de cinza volante de caldeiras: caracterizacao fisica, quimica e mineralogica

    Energy Technology Data Exchange (ETDEWEB)

    Rocha Junior, C.A.F.; Santos, S.C.A.; Souza, C.A.G., E-mail: augustorocha2@gmail.com [Programa de Pos Graduacao em Engenharia Quimica (PPEQ-UFPA), Belem, PA (Brazil); Angelica, R.S.; Neves, R.F. [Programa de Pos-Graduacao em Geologia e Geoquimica, Instituto de Geociencias (PPGG-IG-UFPA), Ananindeua, PA (Brazil)

    2012-01-15

    Along the years, worldwide industrial development has causing a growing generation of residues, bringing potentials environmental problems. A study of the characteristics of these wastes, as well as the development of techniques for their use in new processes becomes indispensable for the environment preservation. The main purpose of this work is to evaluate the possible use of two important industrial residues from the Amazon region for zeolite synthesis: (a) the fly ash (particle size < 100 {mu}m) that comes from burning of mineral coal in boiler; and (b) the micro silica, a by-product of the reaction between quartz and coal in the production of metallic silicon and alloys iron-silicon.The following chemical, physical and mineralogical characterization methods were carried out: X-ray diffractometry, X-ray fluorescence, scanning electron microscopy, granulometric analysis, differential thermal and thermogravimetric analysis (DTA-TG). The analyses were carried out at the following conditions: 60, 100, 150 and 190 deg C, Na{sub 2}O/Al{sub 2}O{sub 3} molar ratio of 5 and Si/Al molar ratio ranging from 2.12 to 15, and reaction time of 24 h. The results of the fly characterization demonstrate its enormous potential as raw material for the zeolite synthesis. SiO{sub 2} and Al{sub 2}O{sub 3} represent more than 50% of its composition, mineralogical phases defined, low humidity content, low particle size (d{sub 90} < 10 {mu}m), among others. Mineralogical analyses of the synthesized products showed the formation of some zeolite types, as follow: analcime, phillipsite, sodalite, zeolite P and tobermorite. The results show that the mixture fly ash-micro silica in these reaction conditions point to a promising material for zeolite synthesis (author)

  8. Physical-chemical characterization of sediments from Lapa Grande de Taquaracu archaeological site, MG; Caracterizacao fisico-quimica de sedimentos do sitio arqueologico Lapa Grande de Taquaracu, MG

    Energy Technology Data Exchange (ETDEWEB)

    Tudela, Diego Renan Giclioti

    2013-07-01

    In this project the elemental concentrations of Ce, Co, Cr, Cs, Eu, Fe, Hf, K, La, Lu, Na, Nd, Rb, Sc, Sm, Ta, Tb, Th, U, Yb and Zn were determined by instrumental neutron activation analysis (INAA) in 60 sediment samples from Lapa Grande de Taquaracu archaeological site, located in MG State. The samples were provided by Dr. Astolfo Gomes de Mello Araujo from the Museum of Archaeology and Ethnology, University of Sao Paulo. This site is a palaeoindian rockshelter located near Lagoa Santa karst with characteristics which could be used to test karst abandonment model during the Middle Holocene related to dry conditions. The results of elemental concentrations, interpreted by multivariate statistical analysis, showed the formation of three different compositional and well-defined groups. The variable selection study by means of Procrusts analysis was also carried out. X-ray diffraction (XRD) analyses were also performed in 8 samples to study their mineralogical composition and they showed that there are distinctions in crystalline structure between the samples of the three elemental compositional groups, being quartz, calcite, dolomite and mica the main crystalline phases present in the samples. (author)

  9. Characterization and comparison of a agricultural and forestry residues for energy purpose; Caracterizacao e comparacao de residuos agricolas e florestais para a producao de energia

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Jofran Luiz de; Silva, Jadir Nogueira da; Pereira, Emanuele Graciosa; Machado, Cassio Silva; Bezerra, Maria da Conceicao Trindade [Universidade Federal de Vicosa (UFV), MG (Brazil). Dept. de Engenharia Agricola], Emails: jofranluiz@yahoo.com.br, jadir@ufv.br

    2010-07-01

    The large volume of waste generated by the industry of wood processing and agriculture is a problem existing in almost all regions of Brazil. Several environmental problems occur as contamination of soil and groundwater due to the accumulation and improper disposal of residues from forestry and agriculture industries. Brazil has agricultural and economic conditions to develop and take advantage of technologies to use wood and other biomass for energy purposes, for being privileged in terms of territorial extension, sunlight and water, essential factors for biomass production on a large scale. The wood chips and coffee husks are low cost residues, renewable and sometimes under utilized, they are environmentally friendly and potentially capable of generating heat, steam and electric power, thus they can contribute as an alternative fuel for generation of energy. In this context, this study aims to characterize and compare residues from the production of coffee and furniture industry. The biomasses were characterized and analyzed for density, heating value, proximate analysis (volatiles, ash and fixed carbon) and elemental composition. Results indicates large energy potential for coffee husks, with HHV equals to 18,6 MJ/Kg slightly higher than the HHV of the eucalyptus chip (17,3 MJ/Kg). (author)

  10. Characterization of polypropylene films modified for using as ion exchange membrane; Caracterizacao de filmes de polipropileno modificados para uso como membrana trocadora de protons

    Energy Technology Data Exchange (ETDEWEB)

    Zen, H.A.; Geraldes, A.N.; Parra, D.F.; Geraldo, A.B.C.; Araujo, S.G.; Lugao, A.B.; Linardi, M. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2006-07-01

    This paper presents previous results of polypropylene films modified by graft process via ionising radiation. The styrene monomer was used in the graft process in presence of toluene as 100%, 80% and 20% proportions of styrene. The samples were irradiated in a cobalt-60 source at 40 and 80 doses. The TGA, DSC, FTIR characterizations were made and degree of grafting (DOG) was determinate. The results of DOG were confirmed by the FTIR analysis although the most samples were less thermal stable. (author)

  11. Morphologic characterization and quantitative analysis on in vitro bacteria by nuclear techniques of measurement; Caracterizacao morfologica e analise quantitativa de bacterias in vitro por tecnicas nucleares de medidas

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, Joana D' Arc Ramos

    2001-10-01

    The great difficulty to identify microorganisms (bacteria) from infectious processes is related to the necessary time to obtain a reliable result, about 72 hours. The purpose of this work is to establish a faster method to characterize bacterial morphologies through the use of neutron radiography, which can take about 5 hours. The samples containing the microorganisms, bacteria with different morphologies, after the appropriate microbiologic procedures were incubated with B{sup 10} for 30 minutes and soon after deposited in a plate of a solid detector of nuclear tracks (SSNTD), denominated CR-39. To obtain the images relative to bacteria, the detector was submitted to the flow of thermal neutrons of the order of 2.2 x 10{sup 5} n/cm{sup 2}.s from the J-9 channel of the Reactor Argonauta (IEN/CNEN). To observe the images from bacteria in each sample under an optical microscope, the sheets were chemically developed. The analysis of the images revealed morphologic differences among the genera (Gram positive from Gram-negative and coccus from bacillus), in samples containing either isolated or mixed bacteria. We thus verified the viability of the technique to achieve morphological characterization of different microorganisms. A quantitative approach seemed also to be feasible with the technique. The whole process took about 2 hours. (author)

  12. Treatment and characterization of fiber licuri for synthesis of polymeric composites; Tratamento e caracterizacao da fibra de licuri para sintese de compositos polimericos

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, J.C.; Miranda, C.S.; Carvalho, R.F.; Jose, N.M.; Boaventura, J.S., E-mail: jamersonoliveira1@hotmail.co [Universidade Federal da Bahia (GECIM/UFBA), Salvador, BA (Brazil). Inst. de Quimica. Grupo de Energia e Ciencias dos Materiais

    2010-07-01

    Natural fibers are materials of increasing use of polymeric composites, due to several advantageous properties compared to synthetic fibers: low cost, density, toxicity and excellent biodegradability. Licuri fiber is widely used in the manufacture of handicrafts, with a wide range of possible applications. Before this, characterize the properties of the fiber is of great interest economic, technological and social. This study characterized the fibers in nature, which were washed with water, treated with 5% H{sub 2}SO{sub 4} or 5% NaOH. Techniques were used FTIR, DSC, TGA and XRD, as well as analysis of surface reactivity of the acid and base. All treatments altered the surface of licuri, exposing reactive sites. It was observed that sodium hydroxide licuri changed significantly, as expected. These results are very significant for the recovery of a natural fiber (licuri), abundant in poor regions of the country. (author)

  13. Biochemical and immunological characterization of the main products of crotoxin irradiation; Caracterizacao bioquimica e imunologica dos principais produtos gerados pela irradiacao de crotoxina

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, Nanci do

    1995-07-01

    Irradiation of crotoxin and its subunits with 2,000 Gy of {gamma}-rays from {sup 60} Co source leads to aggregation and generation of lower molecular wight breakdown products. Aggregates separated by gel filtration retain at least part of their higher-ordered structure, based on their reactivity with monoclonal antibodies known to react with conformation epitopes in native crotoxin. These same aggregates can serve as antigens to raise antisera that cross-reacts and neutralizes crotoxin. Compared with native crotoxin, aggregates appears less myotoxic, are largely devoid of phospholipase activity, and are virtually non-toxic in mice. These results indicate that irradiation of toxic proteins can promote significant detoxification, but still retain many of the original antigenic and immunological properties of native crotoxin. (author)

  14. Dosimetric properties characterization of silicon diodes used in photon beam radiotherapy; Caracterizacao das propriedades dosimetricas de diodos de silicio empregados em radioterapia com fotons

    Energy Technology Data Exchange (ETDEWEB)

    Bizetto, Cesar Augusto

    2013-07-01

    In the current work it was studied the performance of epitaxial (EPI) and float zone (FZ) silicon diodes as on-line dosimeters for megavoltage (EPI diode) and orthovoltage (EPI and FZ diode) photon beam radiotherapy. In order to be used as dosimeters the diodes were enclosed in black polymethylmethacrylate (PMMA) probes. The devices were then connected, on photovoltaic mode, to an electrometer KeithleyÒ 6517B to allow measurements of the photocurrent. The irradiations were performed with 6 and 18 MV photon beams (Siemens PrimusÒ linear accelerator), 6 and 15 MV (Novalis TXÒ) and 10, 25, 30 and 50 kV of a Pantak / Seifert X ray radiation device. During the measurements with the Siemens PrimusÒ the diodes were held between PMMA plates placed at 10.0 cm depth. When using Novalis TXÒ the devices were held between solid water plates placed at 50 cm depth. In both cases the diodes were centered in a radiation field of 10 x 10 cm{sup 2}, with the source-to-surface distance (SSD) kept at 100 cm. In measurements with orthovoltage photon beams the diodes were placed 50.0 cm from the tube in a radiation field of 8 cm diameter. The dose-rate dependency was studied for 6 and 15 MV (varying the dose-rate from 100 to 600 monitor units per minute) and for the 50 kV beam by varying the current tube from 2 to 20 mA. All devices showed linear response with dose rate and, within uncertainties the charge collected is independent of dose rate. The current signals induced showed good instantaneous repeatability of the diodes, characterized by coefficients of variation of current (CV) smaller than 1.14% (megavoltage beams) and 0.15% for orthovoltage beams and coefficients of variation of charge (CV) smaller than 1.84% (megavoltage beams) and 1.67% (orthovoltage beams). The dose response curves were quite linear with linear correlation coefficients better than 0.9999 for all diodes. (author)

  15. Dosimetric properties characterization of silicon diodes used in photon beam radiotherapy; Caracterizacao das propriedades dosimetricas de diodos de silicio empregados em radioterapia com feixe de fotons

    Energy Technology Data Exchange (ETDEWEB)

    Bizetto, Cesar Augusto

    2013-07-01

    In the current work it was studied the performance of epitaxial (EPI) and float zone (FZ) silicon diodes as on-line dosimeters for megavoltage (EPI diode) and orthovoltage (EPI and FZ diode) photon beam radiotherapy. In order to be used as dosimeters the diodes were enclosed in black polymethylmethacrylate (PMMA) probes. The devices were then connected, on photovoltaic mode, to an electrometer Keithley Registered-Sign 6517B to allow measurements of the photocurrent. The irradiations were performed with 6 and 18 MV photon beams (Siemens Primus Registered-Sign linear accelerator), 6 and 15 MV (Novalis TX Registered-Sign ) and 10, 25, 30 and 50 kV of a Pantak / Seifert X ray radiation device. During the measurements with the Siemens Primus the diodes were held between PMMA plates placed at 10.0 cm depth. When using Novalis TX Registered-Sign the devices were held between solid water plates placed at 50 cm depth. In both cases the diodes were centered in a radiation field of 10 x 10 cm{sup 2}, with the source-to-surface distance (SSD) kept at 100 cm. In measurements with orthovoltage photon beams the diodes were placed 50.0 cm from the tube in a radiation field of 8 cm diameter. The dose-rate dependency was studied for 6 and 15 MV (varying the dose-rate from 100 to 600 monitor units per minute) and for the 50 kV beam by varying the current tube from 2 to 20 mA. All devices showed linear response with dose rate and, within uncertainties the charge collected is independent of dose rate. The current signals induced showed good instantaneous repeatability of the diodes, characterized by coefficients of variation of current (CV) smaller than 1.14% (megavoltage beams) and 0.15% for orthovoltage beams and coefficients of variation of charge (CV) smaller than 1.84% (megavoltage beams) and 1.67% (orthovoltage beams). The dose response curves were quite linear with linear correlation coefficients better than 0.9999 for all diodes. (author)

  16. Crystallographic characterization of cement pastes hydrated with NaCl; Caracterizacao cristalografica de pastas de cimento hidratadas com NaCl

    Energy Technology Data Exchange (ETDEWEB)

    Melo, Carina Gabriela de Melo e; Martinelli, Antonio Eduardo; Melo, Dulce Maria Araujo; Melo, Marcus Antonio de Freitas; Melo, Vitor Rodrigo de Melo e [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2012-07-01

    One of the major current challenges faced by oil companies is the exploration of pre salt basins. Salt layers deposited upon the evaporation of ocean water and continental separation are mainly formed by NaCl and isolate immense oil reservoirs. The mechanical stability and zonal isolation of oil wells that run through salt layers must be fulfilled by cement sheaths saturated with NaCl to assure chemical compatibility between cement and salt layer. The present study aimed at evaluating the effect of NaCl addition on the hydration of oil well cement slurries as well as identifying the nature of crystalline phases present in the hardened cement. To that end, cement slurries containing NaCl were mixed, hardened and characterized by X-ray diffraction. The results revealed that the presence of NaCl affects the formation of hydration products by the presence of Friedel's salt. The intensity of the corresponding peaks increase as the contents of NaCl in the slurry increase. High concentrations of NaCl in Portland slurries increase the setting time of cement and the presence of Friedel's salt decreases the strength of the hardened cement. (author)

  17. Silica-gel structural characterization during the initial phases of gelation and drying; Caracterizacao estrutural de geis de silica durante as etapas iniciais de gelacao e secagem

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Max Passos

    1996-12-31

    For centuries, glasses and ceramics have been made via melting or solid state reactions at temperatures above 100 deg C. The sol-gel process offers new approaches to the synthesis of glasses and ceramics, combining control of composition and structure at the molecular level with the ability to shape materials in bulk, powder, fiber and thin-film forms. The growth of sol-gel technology research is due to the many unique features of that class of materials. Major applications include optical elements and integrated optical devices, ceramic filters, membranes, supercondutors, magnetic, catalytic and manostructured materials to antioxidant, anticorrosion coatings and composite and biomedical materials. In this work a variety of techniques like spectroscopy, Raman spectroscopy, ultraviolet-visible spectroscopy, light scattering nuclear magnetic resonance, X ray diffraction and nitrogen adsorption have been employed to investigate the initial phase of the sol-gel transition of gamma ray irradiated tetramethoxysilane (TMOS) solutions and non-irradiated TMOS solution and to get information about the structure of the silica gels obtained under different gelation conditions. Typically the tetramethoxysilane solutions were prepared using a molar ratio of TMOS to demineralized water of 1 to 16. Some experiments were made under catalysed conditions. The mixing was carried out at room temperature. The turbidity and light scattering experiments on the polycondensation of tetramethoxysilane show that exists no drastic difference in the gelling time of a gamma ray irradiated and a non-irradiated TMOS+H{sub 2}O (1+16 M) solution. In the absence of a catalyst, the gelling time for both reactions occurs in about 3.30 h. When HNO{sub 3} (o.03 M) was used, the gelling time observed was 3 days. Raman and ultraviolet-visible spectroscopy show no drastic difference during the initial phase at the sol-gel transition under ambient temperature/pressure and under gamma radiation. The gels heated-treated at 70 deg C appeared to be almost completely amorphous with no evidence of peaks attributable to crystalline materials, with average pore radii usually around 11 A. The surface areas found ranged from {approx} 460 M{sup 2}. G{sup -1} (gelation under magnetic field) to {approx} 770 M{sup 2}. g{sup -1} (polymerization under catalysed condition and gelation under gamma radiation) while the total pore volume ranged from 0.27 cm{sup -3}.g{sup -1} (gelation under magnetic field) to 0.43 cm{sup -3}.g{sup -1} (polymerization under catalysed condition and gelation under gamma radiation). (author) 151 refs., 34 figs., 7 tabs.

  18. 2D seismostratigraphic inversion applied to a thin reservoir characterization; Inversao sismoestratigrafica 2D aplicada a caracterizacao de um reservatorio delgado

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Antonio Carlos de Almeida

    1998-12-01

    The purpose of this work is to estimate thin reservoir properties even without counting on a good quality and a homogeneous database. Following a regional geological setting, well data such as logs, reports, cores had led to an interpretation of the depositional model in which the sandstone interval is inserted as an filling an incised valley system. This knowledge is essential to provide elements for a final work judgement. The main geological properties were then extracted from logs. The geophysical approach has counted on a 1D modeling of the main well acoustic parameters and a 2D Seismostratigraphic Inversion with a {alpha} priori acoustic impedance, which was able to enhance the frequency content of the original data. After the interpretation of the inverted data, seismic attributes were then extracted. A multivariate statistics was performed in order to establish which correlations between geological and seismic would be carried forward. An Ordinary Kriging was applied to the 2D seismic attributes. The External Drift Kriging was used to derive maps of the geological properties with the constraint of seismic variables. The final geological properties maps are similar in shape and coherent with the depositional model proposed. (author)

  19. Isotopic characterization of uranium in soils of the Ipanema National Forest (FLONA-Ipanema); Caracterizacao isotopica de uranio em solos da Floresta Nacional de Ipanema (FLONA-Ipanema)

    Energy Technology Data Exchange (ETDEWEB)

    Silva, F.B.; Marques, F.H., E-mail: fernandobaliani@yahoo.com.br, E-mail: fernando_henrique06@hotmail.com [Laboratorio de Pocos de Caldas (LAPOC/CNEN-MG), Pocos de Caldas, MG (Brazil); Enzweiler, J.; Ladeira, F.S.B., E-mail: Jacinta@ige.unicamp.br, E-mail: fsbladeira@ige.unicamp.br [Universidade Estadual de Campinas (UNICAMP), Campinas, SP (Brazil). Instituto de Geociencias

    2015-07-01

    The National Forest of Ipanema (FLONA) is situated on a geological anomaly, known as 'Domo de Aracoiaba'. The soils of the area include Oxisols, Inceptsols and Alfisols. The amount of uranium and respective isotope activities in a soil depend on the parental rock and on the pedologic processes. The aim of this study was to investigate the activities for uranium isotopes ({sup 238}U, {sup 234}U, {sup 235}U) and the activity ratio (AR) {sup 234}U/ {sup 238}U or secular equilibrium for different soil types of the area collected at horizons A and B. The amount of uranium showed no significant differences for soils generated from alkaline intrusive rocks and sandstone, however, secular equilibrium was observed for Oxisol (RA = 1), while Inceptsol presented RA> 1 and the other soils, Alfisols, presented RA values <1. (author)

  20. Planning and production of a low cost cryostat for electrical characterization of materials; Planejamento e producao de um criostato de baixo custo para caracterizacao eletrica de materiais

    Energy Technology Data Exchange (ETDEWEB)

    Torsoni, G.B.; Carvalho, C.L.; Brito, G.A. [UNESP, Ilha Solteira, SP (Brazil). Dept. de Fisica e Quimica. Grupo de Vidros e Ceramicas

    2010-07-01

    The system BSCCO can show three main Bi{sub 2}Sr{sub 2}CuO, Bi{sub 2}Sr{sub 2}CaCu{sub 2}O and Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O with critical temperatures around 20 K, 80 K and 110 K, respectively. Therefore, it is fundamental to study these materials in details at lowest temperatures, with simple systems and low cost equipment. In this work was projected a cryogenic system with capacity to reach temperatures below the liquid nitrogen temperature (77 K). Based on thermodynamic principles, which is used with liquid nitrogen system, with the vacuum application and control, it has been achieved temperatures about 63 K (freezing nitrogen temperature) in the sample holder. With the availability of a large range temperature becomes possible to identify at least two superconducting phases as in system BSCCO, which also involves a cost/benefit ratio more favorable, avoiding the use of more expensive refrigerates as liquid helium. (author)

  1. Mineralogical characterization of historical portuguese wall tiles of Sao Luis, Maranhao, Brazil; Caracterizacao mineralogica de azulejos portugueses do Centro Historico de Sao Luis do Maranhao

    Energy Technology Data Exchange (ETDEWEB)

    Rivas Mercury, J.M.; Vasconcelos, N.S.L.S.; Cabral, A.A., E-mail: rivascefetma@gmail.co [Instituto Federal de Educacao, Ciencia e Tecnologia do Maranhao (IFMA), Sao Luis, MA (Brazil). Programa de Mestrado em Engenharia de Materiais; Pereira, D.J. Costa [Centro de Criatividade Odylo Costa Filho (SECMA), Sao Luis, MA (Brazil). Centro Historico; Angelica, R.S. [Universidade Federal do Para (CG/UFPA), Belem, PA (Brazil). Inst. de Geociencias

    2010-07-01

    Portuguese wall tiles from centuries, XVII, XVIII and XIX, found in Sao Luis Maranhao has been studied by X-ray diffraction, in order to interpret the possible raw material and burning temperature. The mineral phases, Quartz, Wollastonite, Calcite and Gehlenite were identified in all samples. Based on the results it is possible to affirm that the main raw materials used to manufacture this materials was probably mixtures of kaolinite clay and calcite. Based on the mineralogical information it was also possible to state that burning temperature of this wall tiles was lower than 1000 deg C. (author)

  2. Characterization of UO{sub 2} by infrared absorption spectroscopy; Caracterizacao de UO{sub 2} por espectroscopia de absorcao no infravermelho

    Energy Technology Data Exchange (ETDEWEB)

    Machado, G.C.; Faeda, K.C.M.; Lameiras, F.S. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2010-07-01

    The system U-O presents various oxides such as UO{sub 2} {sub =-x}, U{sub 4}O{sub 9}, U{sub 3}O{sub 8} and UO{sub 3}. The UO{sub 2} has great technological importance, because it is used as fuel in nuclear power reactors. The control of O/U relation is critical to its manufacturing process. In this work the infrared spectroscopy was used to identify the presence of other oxides in the U-O system from UO{sub 2} powder samples that can not be identified by thermogravimetry and X-ray diffraction, usually employed to control the O/U relation and the identification of phases.(author)

  3. Characterization of ceramic bodies to produce bricks from Campos Goytacazes, Brazil; Caracterizacao de massas de blocos de vedacao de Campos dos Goytacazes, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, L.L.P. de; Maia, F.S.; Petrucci, L.J.T.; Pessanha, E.M.; Paixao, L.P. [Faetec, Campos dos Goytacazes, RJ (Brazil). Centro Vocacional Tecnologico. Ceramica; Vieira, C.M.F. [Universidade Estadual do Norte Fluminense Darcy Ribeiro (UENF), Campos dos Goytacazes, RJ (Brazil)

    2010-07-01

    This work has for objective to study comparatively the characteristics and technological properties of four typical ceramic bodies from the region of Campos dos Goytacazes-RJ used to fabricate red ceramics. The characterization techniques used were: X-ray fluorescence, X-ray diffraction, differential thermal analysis (DTA), thermogravimetric analysis (TGA) and dilatometry. Specimens were molded by extrusion and then fired at 750, 850 and 950 deg C. The evaluated firing properties were: linear shrinkage and water absorption. The results showed that the investigated ceramic bodies have similar chemical and mineralogical composition. It is also concluded that the bodies are adequate to produce bricks. (author)

  4. Characterization of deactivated catalytic cracking catalyst and evaluation as absorbent material; Caracterizacao de catalisador de craqueamento catalitico desativado e avaliacao como material adsorvente

    Energy Technology Data Exchange (ETDEWEB)

    Valt, R.B.G.; Kaminari, N.M.S.; Cordeiro, B.; Ponte, M.J.J.S.; Ponte, H.A. [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil)

    2010-07-01

    One of the main uses of catalysts in the petroleum industry is in step catalytic cracking, which after use and regeneration cycles generates large quantities of waste material. In this research the deactivated FCC catalyst was characterized before and after the electrokinetic remediation process, in order to assess the change of its structure and possible adsorptive capacity. Analyses of X-Ray Fluorescence Spectroscopy, Scanning Electron Microscopy and BET surface area measurement were performed. The analysis showed no structural change due to the process employed and that electrokinetic remediation has recovered 42% of adsorption capacity of the material, by removing about 89% of heavy metals adhered initially in the catalyst surface. (author)

  5. Preparation and characterization of organoclays for use in polymer nanocomposites; Preparacao e caracterizacao de argilas bentoniticas organofilicas para a utilizacao em nanocompositos polimericos

    Energy Technology Data Exchange (ETDEWEB)

    Nobrega, K.C. [Universidade Federal de Campina Grande (UEMa/UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais; Leite, A.M.D.; Souza, D.D. de; Araujo, E.M.; Melo, T.J.A. de [Universidade Federal de Campina Grande (DEMa/UFCG), PB (Brazil). Dept. de Engenharia de Materiais

    2010-07-01

    The aim of this work is to obtain organoclays from a sodium bentonite clay using two organic salts, Cetremide and Dodigen, and characterize them for nanocomposites use. The obtained results by X-ray diffraction (XRD) confirmed the obtaining of organoclay, since the originally submitted sodium bentonite interlayer distance of 12,81 A, and the cation exchange when it made with two different quaternary ammonium salts (Cetremide and Dodigen), the distance expanded to 18,48 A in both treatments, indicating the effective intercalation of the organic cation. By means of infrared spectroscopy (FTIR), it was observed the appearance of adsorption bands related to the CH{sub 2} and CH{sub 3} groups, confirming the presence of chains of organic salts from the clay, no significant structural differences between the clays treated with different salts. (author)

  6. Isolation and characterization of soluble sulfated polysaccharide from the red seaweed Glucaric cornea; Isolamento e caracterizacao do polissacarideo sulfatado soluvel extraido da alga vermelha Gracilaria cornea

    Energy Technology Data Exchange (ETDEWEB)

    Melo, Marcia R.S.; Freitas, Ana L.P. [Ceara Univ., Fortaleza, CE (Brazil). Dept. de Bioquimica e Biologia Molecular]. E-mail: rubiamelo@yahoo.com; Feitosa, Judith P.A.; Paula, Regina C.M. de [Ceara Univ., Fortaleza, CE (Brazil). Dept. de Quimica Organica e Inorganica]. E-mail: judith@dqoi.ufc.br

    2001-07-01

    The composition, structure and rheological properties of soluble sulphated polysaccharide Glucaric cornea from Brazilian red seaweeds were investigated. The main components of polysaccharide were 3,6-anhydrogalactose (24.7%) and galactose (64.6%). In addition, minor components as 6-O-methyl-galactose (8.5%), glucose (1.5%), xylose (0.7%) and sulfated groups (4.8%) were detected. Comparison between sulphates content determined by Ft-IR spectroscopy and micro elemental analysis was made. Data from {sup 13}C NMR and FT-IR provided evidence of sulphation in C-4 and C-6 of galactose. No gelation with 1.5, 2.0 and 3.0 % (w/v) aqueous solution was observed, even cooled up to 4 deg C. GPC indicated two majors polysaccharide fractions of M{sub pk} 7.4 x 10{sup 4} and 1.8 x 10{sup 4} g/mol and a minor fraction of M{sub pk} 2.1 x 10{sup 6} g/mol. (author)

  7. Characterization of the profile of energy consumption in isolated regions of Mozambique; Caracterizacao do perfil de consumo energetico em regioes isoladas de Mocambique

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Afonso Henriques Moreira; Cruz, Ricardo A. Passos da; Magalhaes, Ricardo Nogueira

    2008-07-01

    This article summarizes the characterization of energy demand in isolated regions of Mozambique, the result of a work for government of that country. In essence, the profile does not differ much from Brazilian reality in poor regions, except for tribal characteristics, absent here. The importance of anthropogenic energy and almost no zoogenic energy are still points of major difference between the two realities.

  8. Characterization of steel grit recovered from ornamental rocks waste by magnetic separation; Caracterizacao da granalha de aco recuperada do residuo de rochas ornamentais por separacao magnetica

    Energy Technology Data Exchange (ETDEWEB)

    Junca, E.; Telles, V.B.; Rodrigues, G.F.; Oliveira, J.R. de; Tenorio, J.A.S., E-mail: eduardojunca@gmail.co [Universidade de Sao Paulo (USP), SP (Brazil). Dept. de Engenharia Metalurgica e de Materiais; Instituto Federal de Ciencia e Tecnologia do Espirito Santo (IFES), Vitoria, ES (Brazil)

    2010-07-01

    The aim of this work is characterization of steel grit recovered from ornamental rock waste by magnetic separation. The magnetic separation was realized in three steps: first, using a high intensity wet magnetic separator, which used only the remaining magnetic field of equipment. In the second step, the magnetic material obtained in the first phase was subjected to a new manual magnetic separation using rare earth magnets. In a third step, magnetic material obtained with rare earth magnets was subjected to manual magnetic separation using ferrite magnets. After the magnetic separation, the material was sent to characterization which was obtained by chemical analysis, scanning electron microscopy, X-ray diffraction and size analysis. The size analysis showed that the concentrate range from 0,5 to 563,67 {mu}m with 4 wt.% over 100 {mu}m and content metallic iron of 93 wt%. (author)

  9. Development and characterization of special ionization chambers for computed tomography beams; Desenvolvimento e caracterizacao de camaras de ionizacao especiais para feixes de tomografia computadorizada

    Energy Technology Data Exchange (ETDEWEB)

    Castro, Maysa Costa de

    2016-10-01

    The use of computed tomography (CT) for imaging procedures is growing due to advances in the CT equipment technology, because they allow the obtention of images with better resolution than through other techniques. Therefore, they are responsible for increasing the dose radiation of patients during the procedure. This fact led to a greater concern about the doses received by patients who undergo this type of examination. To perform the dosimetry in CT beams, the most widely used instrument is the pencil type ionization chamber, because this dosimeter has a uniform response to the incident radiation beam for all angles. The conventional ionization chamber, which is available on the market, has a sensitive volume length of 10 cm; however, some studies have shown that this dosimeter has underestimated the dose values. Therefore, in this study two ionization chambers with sensitive volume lengths of 10 cm and 30 cm, making use of low cost national materials, were developed at the Calibration Laboratory of Instruments (LCI-IPEN/CNEN). The characterization of these chambers was performed, and the results were obtained within the international recommended limits. As an application, the developed ionization chambers and a commercial chamber were tested in a clinical tomograph. The developed ionization chambers were analyzed in a complete way for their possible uses. (author)

  10. Synthesis and characterization of NiO nanoparticles by Pechini method; Sintese e caracterizacao de nanoparticulas de NiO pelo metodo Pechini

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, A.; Ribeiro, M.A.; Costa, A.C.F.M.; Gama, L. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Dept. de Engenharia de Materiais; Bernardi, M.I.B. [Universidade de Sao Paulo (IFSC/USP), Sao Carlos, SP (Brazil). Inst. de Fisica

    2009-07-01

    In recent years, ultrafine magnetic particles of NiO have attracting the attention because of its unknown behavior, enormous scientific potential and technological application. Some of its more important properties are accented magnetic moments, double dynamic exchange, quantization of wave of spin and etc. In this context, this work has for objective to synthesize and to characterize nanoparticles of NiO for the Pechini method. The powder was analyzed by X-rays diffraction. The results of scanning electron microscopy, adsorption of nitrogen. The analysis of X-rays diffraction of the sample showed single-phase peaks of NiO, with crystallite size close to 38 nm. The surface area was 6.44 m{sup 2}/g. The image from scanning electron microscopy shows soft homogeneous agglomerates. The Pechini synthesis was efficient in the production of powders of NiO nano metrics and single-phase. (author)

  11. Preparation and characterization of bentonite clays mixture destined to the removal of heavy metals; Preparacao e caracterizacao da mistura de argilas bentoniticas destinadas a remocao de metais pesados

    Energy Technology Data Exchange (ETDEWEB)

    Almeida Neto, A.F. de; Silva, M.G.C. da, E-mail: ambrosio@feq.unicamp.b [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Fac. de Engenharia Quimica. Dept. de Termofluidodinamica

    2009-07-01

    In this work a mixture was prepared with 50% wt. of the Bofe and Verde-lodo clays. The characterization methods used they were: thermal analyses (TG and DTG), X-ray diffraction, fisissorption of N{sub 2}, scanning electron microscopy and X-ray energy dispersive spectroscopy. The rehearsals of adsorption we accomplished in system of finite bath using as adsorbent the mixture loamy in natura or it mixes calcined. Starting from TG and DTG a thermal treatment was accomplished to 500 deg C of the loamy mixture. Through the results of the copper adsorption, it was verified that mixes loamy it provokes chemical precipitation of the copper while the calcined sample presents amount metal adsorbed around 7.31 mg of copper/g of adsorbent. The value of removal percentage obtained by the calcined sample it was of 63.02%. (author)

  12. Production and characterization of charcoal from species and varieties of bamboos; Producao e caracterizacao do carvao vegetal de especies e variedades de bambu

    Energy Technology Data Exchange (ETDEWEB)

    Brito, J.O.; Tomazello Filho, M. [Sao Paulo Univ., Piracicaba, SP (Brazil). Escola Superior de Agricultura Luiz de Queiroz; Barros Salgado, A.L. de [Instituto Agronomico de Campinas, SP (Brazil)

    1987-12-31

    Samples of bamboo culms (B. vulgaris var. vittata, B vulgaris, B. tuldoides. Dendrocalamus, Guandua angustifolia) were collected in three longitudinal positions from adult culms and carbonized in laboratory conditions. Eucalypt (E. urophilla hybrid) wood was used as a comparative parameter. Differences between the charcoal from the bamboo species and Eucalypt were observed. The bamboo culms presented higher values of lignin and holorcelulose in relation to wood samples. The bamboo culms provided higher charcoal yields and non-condensable gases.The bamboo charcoal was denser and with higher ash content in relation to wood charcoal. (author). 17 refs., 5 tabs

  13. Wind turbine OHM-30 kW power curve characterization; Turbina eolica OHM-30 kW - caracterizacao da curva de potencia

    Energy Technology Data Exchange (ETDEWEB)

    Feitosa, Everaldo; Pereira, Alexandre; Barros, Maria Eliza; Rosas, Pedro [Pernambuco Univ., Recife, PE (Brazil). Dept. de Engenharia Mecanica. Grupo de Energia Eolica]. E-mail: windcenter@npd.ufpe.br

    1997-07-01

    An experimental 30 kW wind turbine OHM-30 has been installed in the project is development of special wind turbines for moderate wind. This paper presents the first part of the project involving the measurement of the power curve of the turbine OHM-30 according to I.E.A. (International Energy Agency). Several modifications in the turbine rotor and control strategies are emphasized. (author)

  14. Characterization of a clay from Vitoria da Conquista, Bahia, Brazil, by thermal analysis; Caracterizacao de uma argila de Vitoria da Conquista, BA, por analise termica

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, O.M.; Zandonadi, A.R.; Martins, M.V. Surmani; Carrio, J.A.G.; Munhoz Junior, A.H. [Universidade Presbiteriana Mackenzie, Sao Paulo, SP (Brazil)

    2010-07-01

    Kaolinitic clays are vastly used in ceramic industry. Light coloration burned clays are very useful in the coatings production because of their aesthetic. In this work clay material from Vitoria da Conquista (south-west Bahia, Brazil) was characterized by various techniques. Differential Scanning Calorimetry (DSC) shows a kaolinite characteristic curve with an endothermic peak at 492 deg C, which corresponds to the kaolinite - metakaolinite transformation. Transformation alpha to beta quartz is characterized by a 573 deg C peak. The samples were also characterized by water absorption and x rays powder diffraction. The 1100 deg C burned samples were tested by rupture tension with acceptable results. (author)

  15. Experimental characterization of a radiant porous burner for low temperatures using natural gas; Caracterizacao experimental de um queimador poroso radiante a gas natural para baixas temperaturas

    Energy Technology Data Exchange (ETDEWEB)

    Catapan, Rafael C.; Hissanaga, Newton Junior; Pereira, Fernando M.; Oliveira Junior, Amir A.M. de [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil). Dept. de Engenharia Mecanica; Serfaty, Ricardo [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES); Freire, Luiz G.M. [PETROBRAS - RedeGasEnergia, RJ (Brazil)

    2004-07-01

    This article describes the experimental characterization of a radiant porous burner for temperatures between 500 deg C and 900 deg C. These low temperature radiant burners can be used in many practical applications as drying of paper and wood, plastic coating, food cooking and ambient heating. Two different configurations of silicon carbide porous ceramic foams were tested: one with a radian reflecting region (RRR) at the outlet and another without this region. Both configurations were able to sustain the reaction with equivalent ratio under 0,35. The configuration with a reflecting region was able to sustain flames with a minimum power of 60 kW/m{sup 2} and the other configuration with 100 W/m{sup 2}.The configuration with the RRR reached minimum superficial temperatures about 100 deg C lower than the other one. These results show that the reflecting region increases the heat recirculation inside the porous burner. The radiant efficiency varied from 20% to 35% for both burners. (author)

  16. Modification and characterization of the AISI 410 martensitic stainless steels surface; Modificacao e caracterizacao da superficie do aco inoxidavel martensitico AISI 410

    Energy Technology Data Exchange (ETDEWEB)

    Bincoleto, A.V.L. [Universidade Federal de Sao Carlos (PPG-CEM/UFSCar), SP (Brazil). Programa de Pos-Graduacao em Ciencia e Engenharia de Materiais; Nascente, P.A.P. [Universidade Federal de Sao Carlos (DEMa/UFSCar), SP (Brazil). Dept. de Engenharia de Materiais

    2010-07-01

    Steam turbines are used in the generation of more than half the electric energy produced in the world nowadays. It is important the study which aims to improve the efficiency by means of the optimization of leaks and of the aerodynamic profiles, as well as to maintain the integrity of the components. The martensitic stainless steels are widely employed due to the combination of their good mechanical properties with higher corrosion resistance. However, their lower wear resistance and their poor tribological behavior limit their use, since they decrease the component life time. In order to evaluate the improvement in the performance of the AISI 410 stainless steel, several process of surface modification were employed. Five samples were produced: the first one was not treated, the second one received liquid nitriding, the third, gas nitriding, the forth, thermal aspersion of tungsten carbide, and the fifth, boronizing. The samples were characterized by optical microscopy, surface microhardness, and X-ray diffractometry. (author)

  17. Characterization of an electronic system for Image acquisition portal to open field dosimetry; Caracterizacao de um sistema eletronico de aquisicao de imagem portal para dosimetria em radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Barbi, Gustavo L.; Oliveira, Harley F.; Bertucci, Edenyse C.; Amaral, Leonardo L.; Borges, Leandro F., E-mail: gustavobarbi@usp.br [Universidade de Sao Paulo (USP), Ribeirao Preto, SP (Brazil). Hospital das Clinicas. Centro de Ciencias das Imagens e Fisica Medica

    2012-08-15

    The objective was to characterize and enable an electronic portal imaging device (EPID) to use like a portal dosimetry device - PDI, in non-transit mode, without interposition of scattering between the beam and EPID for measurement to open fields. The images as well as the DICOM header data are extracted from software ImageJ and the information are used in the basic algorithm for converting pixel to dose. The linearity and reproducibility of response were analyzed, and the maximum deviation found of 2,3% to 800 monitor units (MU) for linearity and -0,9% for reproducibility of signal measured daily. A 512x512 matrix with a resolution of 0,8mm was established to restore the shape of beam from the image. The field size dependence was evaluated, by obtaining the ratio of total scattering of ionization chamber and EPID. Finally, a calibration factor of 28470.88{+-}170.73 pixel/cGy was established for the central area of the image. Comparative analyzes between the PDI, radiochromic film and array of ionization chambers (MatriXX) showed good agreement for fields greater then 5 x 5 cm{sup 2} to reestablishment of form field and dose, however, for fields between 3x3 cm{sup 2} and 5x5 cm{sup 2}, the agreement to shape of beam was best established by film. (author)

  18. Spectroscopic and thermal characterization of bovine enamel and dentine using the photoacoustic effect; Caracterizacao espectroscopica e termica de esmalte e dentina bovinos utilizando o efeito fotoacustico

    Energy Technology Data Exchange (ETDEWEB)

    Stolf, Sandro Fernando

    2003-07-01

    The optical and thermal properties of dental tissues determine the nature and extent of the tissue response through the processes of absorption, transmission, reflection and scattering of the laser light and the heat produced by the absorption of that light. The spectroscopic characterization of bovine dentine and enamel, and the determination of the thermal diffusivity were the aim of this study. The photoacoustic spectra from these tissues were obtained in the Near-Infrared range 900 - 2500 nm, which is the clinical range for odontological application of most lasers. Photoacoustic spectra were taken from block, slices and powder of enamel and dentine. Also photoacoustic spectra were registered before and after 2, 5 and 10 h of topical fluoride (2.26%) application. Using the same technique spectra were taken from dentine and enamel after irradiation with Nd:YAG, Er:YAG, Ho:YLF and CO{sub 2}. It is evident from the results that the presence of O-H in the composition of hydroxyapatite and the water present in the teeth tissue make the obtention of spectrum from components other than O-H bond a very difficult task. In this way, only bands assigned to overtones and combinations of O-H stretch were observed. The thermal diffusivity of the bovine dentine was also measured using the photoacoustic technique. The thermal diffusivity is the physical quantity which measures the rate of heat diffusion throughout the sample. For higher values of the thermal diffusivity the heat diffusion and temperature rise will be faster. As there is many studies devoted to the processes of heat transfer throughout dental tissues using bovine teeth, it is important the determination of its thermal diffusivity. The measured value was found to be a = 2.0 ({+-}0.1).1O{sup -3} cm{sup 2}/s for the both direction, perpendicular and parallel to the dentinal tubules. These {sup a}lues indicate that there is no difference between the thermal diffusivities for the both directions. (author)

  19. Physico-chemical characterization of biodiesel from pests attacked corn oil; Caracterizacao fisico-quimica do biodiesel de oleo de milho danificado por pragas

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Fabia M.; Correa, Paulo C.; Martins, Marcio A.; Santos, Silmara B.; Damian, Amanda D. [Universidade Federal de Vicosa (UFV), MG (Brazil)], Emails: copace@ufv.br, aredes@ufv.br, syllmara@vicosa.ufv.br

    2009-07-01

    The biodiesel is a renewable energy source alternative to fossil fuels. The biodiesel synthesis can be made by many types of triglycerides transesterification, it is possible to use this biofuel in vehicles if it has the quality required from Agencia Nacional de Petroleo, Gas Natural e Biocombustiveis (ANP). Searching an application for pests attacked corn, there is feasibility technical for the biodiesel production from this corn oil. The biodiesel synthesis was made through ethyl transesterification process with alkaline catalyst using ethanol. The biodiesel physical-chemical characterization was performed using ANP methods. (author)

  20. Characterization of nanocomposites containing Ecoflex®, LDPE and organophilic bentonite; Caracterizacao de nanocompositos de PEBD contendo Ecoflex® e bentonita organofilizada

    Energy Technology Data Exchange (ETDEWEB)

    Rios, A.R.; Rosa, D.S., E-mail: derval.rosa@ufabc.edu.br [Universidade Federal do ABC (UFABC), SP (Brazil); Poveda, P.N.S. [Colorfix Itamaster Ltda, SP (Brazil); Viana, H. [Centro Universitario Fundacao Santo Andre, SP (Brazil)

    2011-07-01

    Considering the need for development of environmentally degradable polymers for high performance, this study aimed to develop and characterize compounds of LDPE containing different levels of Ecoflex® (biodegradable) and organophilic bentonite (environmentally correct, low cost and plentiful). The clay showed interlayer distance (d{sub 001}) of 17.59 Å, which confirms the organophilization organization and salts in monolayer lateral between the layers of bentonite. Through the test IF it can be verified that the fluidity of the compounds was reduced proportionately with the addition of nano clay, improving the dimensional stability of the material. The mechanical test showed that the addition of nano clay increased the maximum stress and elastic modulus of the composites. The FTIR assay corroborated the mechanical results, indicating the presence of interfacial interactions polymer/clay, through axial deformation bands OH related to hydroxyl groups of clay. (author)

  1. Planning of experimental removal of cadmium in finite bath system using the chocolate clay B as adsorbent; Caracterizacao de adsorvente (argila chocolate B) visando a remocao de cadmio

    Energy Technology Data Exchange (ETDEWEB)

    Mota, J.D.; Rodrigues, M.G.F.; Lima, W.S.; Souza, R.S., E-mail: wsl_20@yahoo.com.br, E-mail: meiry@deq.ufcg.edu.br [Universidade Federal de Campina Grande (LABNOV/UFCG), PB (Brazil). Unidade Academica de Engenharia Quimica. Lab. de Desenvolvimento de Novos Materiais

    2012-07-01

    The smectite clays are characterized by having a high cation exchange capacity and ability to remove metal ions. They have great industrial importance, for its abundance and low cost. The first part of this work was to characterize the clay called Chocolate B through the techniques of X-Ray Diffraction, X-Ray Spectroscopy and Energy Dispersive Physical Adsorption of Nitrogen. The second part of the work aims to evaluate the significance of the variables: pH and initial concentration on removal of cadmium in a batch system. In the experimental design used was a 2{sup 2} factorial analysis with the addition at the central point, and evaluated the percentage of removal (Rem%) and removal capacity (EQF). XRD results corroborating the chemical analysis (EDX), characterized as a B Chocolate smectite clays. Statistical analysis showed a strong influence of variable pH on the removal of cadmium. (author)

  2. Mineralogical and technology characterization of raw materials of clay used for ceramic blocks fabrication; Caracterizacao tecnologica e mineralogica da materia-prima utilizada na fabricacao de blocos ceramicos

    Energy Technology Data Exchange (ETDEWEB)

    Campos, N.Q.; Tapajos, N.S., E-mail: q.campos@hotmail.com [Instituto de Educacao, Ciencia e Tecnologia do Para (IFPA/LABEM), Belem, PA (Brazil). Lab. de Beneficiamento de Menerios

    2012-07-01

    In the state of Para, the red ceramic industry has several segments highly generators of jobs and a strong social appeal. With so many companies focused on this productive sector emerge, but many without any administration quality. Therefore, this study focused the technological and mineralogical characterization of the raw material used in the manufacture of ceramic blocks, by Ceramica Vermelha Company, located in the district of Inhangapi-PA. The raw material was obtained by the techniques of X-ray diffraction (XRD) to determine the present crystalline phases through an accurate and efficient procedure, where it was possible to identify the peaks relating to montmorillonite, illite and kaolinite clay in the sample, and kaolinite and quartz in the sample laterite. Another important result was the absorption of water, with average satisfactory according to the standards. According to a sieve analysis, the laterite the sand fraction showed a greater extent compared to the other, while the clay silt exceeding 80% was found to be too plastic material. The resistance to compression, the results were below the required by the standard, suggesting more accurate test methods. (author)

  3. Chemical characterization of diets consumed in the COSEAS restaurant, by neutron activation analysis; Caracterizacao quimica de dietas consumidas no restaurante do COSEAS/USP-SP, por ativacao neutronica

    Energy Technology Data Exchange (ETDEWEB)

    Favaro, Deborah I.T. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil). Lab. de Analise por Ativacao Neutronica]. E-mail: defavaro@ipen.br; Chioccola, Gabriella S.; Bortoli, Maritsa C.; Cozzolino, Silvia M.F. [Sao Paulo Univ., SP (Brazil). Faculdade de Ciencias Farmaceuticas. Lab. de Alimentos e Nutricao Experimental]. E-mail: gabich@usp.br

    2005-07-01

    This study presents the results of chemical characterization of meals (lunch) offered by COSEAS/USP-SP restaurant, during 5 non consecutive days. These meals were collected in triplicate, in the same way they are offered to the users, being freeze-dried and prepared for chemical analysis. In the total, 15 samples were collected. The proximate composition was determined by using the standard methodologies according to AOAC (1995). The contents of some micronutrients (Ca, Fe, K, Na, Se and Zn) were determined by instrumental neutron activation analysis. The methodology validation was performed by certified reference materials analyses: Oyster Tissue (NIST SRM 1566{sup b}), Orchard Leaves (NIST SRM 1541) and Peach Leaves (NIST SRM 1547). >From concentration results the daily intake of each micronutrient was calculated considering this meal as 40% of the total daily intake and the values were compared to the new dietary recommendations of micronutrients (Dietary Reference Intakes-DRIs, Institute of Medicine, USA), for the women in the life stage from 19 to 30 years. Comparing the average values found with the recommended values, it was verified that macronutrients and Fe, Se and Zn micronutrients reached the values set by new DRIs. For Ca and K the daily intake was inadequate and Na, exceeded the recommended value. (author)

  4. Preliminary characterization in the development of the nano composite low density polyethylene with attapulgite clay; Caracterizacao preliminar no desenvolvimento de nanocompositos polietileno de baixa densidade/argila atapulgita

    Energy Technology Data Exchange (ETDEWEB)

    Domingos, Luanda G.; Rego, Jose K.M.A. do [Universidade Federal do Rio Grande do Norte, Programa de Pos-graduacao em Ciencia e Engenharia de Materiais, PPGCEM/UFRN, Natal, RN (Brazil); Ito, Edson N. [Universidade Federal do Rio Grande do Norte, Depto de Engenharia de Materiais, DEMat/UFRN, Natal, RN(Brazil); Acchar, Wilson [Universidade Federal do Rio Grande do Norte, Depto de Fisica, DF/UFRN, Natal, RN (Brazil)

    2011-07-01

    The aim of this study was a preliminary study of the physical, thermal and rheological properties of the materials to be used in the development of nano composite low density polyethylene (LDPE) with Brazilian attapulgite clay (ATP), with and without the use of a compatibilizing agent interfacial, polyethylene grafted with maleic anhydride (PE-g-MAH). The materials were characterized by X-ray diffraction (XRD), thermogravimetry (TG) and torque rheometry. The materials were characterized and potentially could be developed polymeric nano composites with technological applications using attapulgite fibers in the nanometer scale. (author)

  5. Characterization of composite high density polyethylene and layered zirconium phosphate; Caracterizacao de composito de polietileno de alta densidade (HDPE) e fosfato de zirconio lamelar

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    Zirconium phosphate (ZrP) (2 w%), synthesized by direct precipitation method, was used in the preparation of composite with high density polyethylene (HDPE), through extrusion processing in the molten state. Wide angle x-ray diffraction (WAXD), stress-strain mechanical analysis and scanning electron microscopy (SEM) techniques were used for ZrP, neat polymer and composite mechanical and morphologic characterization. Although there was a slight increase in the Young modulus, WAXD and SEM analysis showed that the intercalation of the HDPE matrix in the filler galleries did not occur, probably due to the insufficient lamellae spacing to intercalate the polymer chains. Then, a microcomposite was achieved. (author)

  6. Characterization of crumbe rubber and modified asphalt from brazilian petroleum; Caracterizacao de borracha de pneu moido e de asfalto modificado oriundo de petroleo brasileiro

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Expedito F. dos; Feitosa, Judith P.A. [Ceara Univ., Fortaleza, CE (Brazil). Dept. de Quimica Organica e Inorganica]. E-mail: judith@dqoi.ufc.br, expeditoflavio@uol.com.br; Soares, Jorge B. [Ceara Univ., Fortaleza, CE (Brazil). Dept. de Engenharia de Transporte; Leite, Leni F.M. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    2003-07-01

    Initially it was made an evaluation of the thermal behavior, grain composition and elastomer content of a crumb rubber sample. It was verified a thermal resistance of the crumb rubber and an elastomer content ranging from 56 to 68 %. The asphalt binders were obtained from Brazilian CAP (Fazenda Alegre, State of Espirito Santo) and blended with crumb rubber from 2 to 22 %. The asphalt binder presented smaller penetration than pure CAP. The pure asphalt and binder was aged by the RTFOT system. It was observed a C=O band due oxidation. In the asphalt binder with 2 and 5 % of crumb rubber was verified a smaller effect of the oxygen than in the pure asphalt, which suggests larger aging resistance. Apparent viscosity analysis showed that the pure asphalt has a Newtonian behavior in temperature higher than 150 deg C, while a pseudoplastic behavior of the asphalt binder increases with crumb rubber concentration. (author)

  7. Polymeric foam characterization for packing use for radioactive wastes transportation; Caracterizacao de espuma polimerica para uso em embalagens para transporte de rejeitos radioativos

    Energy Technology Data Exchange (ETDEWEB)

    Mourao, Rogerio Pimenta [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil)] E-mail: mouraor@urano.cdtn.br; Mattar Neto, Miguel [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)] E-mail: mmattar@net.ipen.br

    2002-07-01

    Impact limiters are sacrificial components widely used to protect radioactive waste packages against damage arising from falls, fires and collisions with protruding objects. Several materials have been used as impact limiter filling: wood, expanded cement and polymeric foams. One of the most popular materials among package designers is the petroleum rigid polyurethane foam, owing to its toughness, workability, low specific weight, low costs and commercial availability. In Brazil, a new foam was developed using the polymer extracted from the castor-oil plant (Ricinus communis), a renewable source. Besides, no greenhouse gases are used during its manufacture. For a better performance, a detailed knowledge of the foam physical and mechanical properties is essential. A relatively vast amount of data about regular polymeric foams can be found in the literature and in several manufacturers' brochures, but no data has been published so far about the properties of the castor-oil foam. This paper presents the testing program carried out as part of ongoing research program aimed at developing a packaging for the transport of radioactive wastes. The results obtained reveal that the castor-oil foam has a mechanical behavior similar to that of regular foams, with good property reproducibility and homogeneity. (author)

  8. Characterisation of titanium nitride films obtained by metalorganic chemical vapor deposition (MOCVD); Caracterizacao de filmes de nitreto de titanio obtidos por MOCVD

    Energy Technology Data Exchange (ETDEWEB)

    Pillis, M.F., E-mail: mfpillis@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (CCTM/IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro de Ciencia e Tecnologia de Materiais; Franco, A.C. [Universidade de Sao Paulo (IF/USP), SP (Brazil). Inst. de Fisica; Araujo, E.G. de [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Sacilotti, M. [Universidade Federal de Pernambuco (IF/UFPE), Recife, PE (Brazil). Inst. de Fisica; Fundacao de Amparo a Ciencia e Tecnologia de Pernambuco (FACEPE), Recife, PE (Brazil)

    2009-07-01

    Ceramic coatings have been widely used as protective coating to improve the life of cutting tools, for corrosion protection and in microelectronics, optical and medical areas. Transition metals nitrides are of special interest due to its high hardness and thermal stability. In this work thin films of titanium nitride were obtained by MOCVD (metalorganic chemical vapor deposition) process. The tests were carried out for 1h at 700 deg C under 80 and 100 mbar of pressure. The characterization was made by using scanning electron microscopy coupled with dispersive energy analysis, and X-ray diffraction. Preliminary results suggested that Ti{sub 2}N phase was formed and that the growth rate varied between 4 and 13 nm/min according to the process parameter considered. (author)

  9. Mineralogical characterization of quarry fines from Tracuateua city, state of Para, Brazil; Caracterizacao mineralogica dos finos de pedreira do municipio de Tracuateua-PA

    Energy Technology Data Exchange (ETDEWEB)

    Costa, J.H.B. da; Negrao, R.C.; Angelica, R.S., E-mail: jhcosta@ig.com.br [Instituto Federal de Educacao, Ciencia e Tecnologia do Para (IFPA), Belem, PA (Brazil). Departamento de Recursos Naturais. Coordenacao de Mineracao; Universidade Federal do Para (UFPA), Belem, PA (Brazil). Instituto de Geociencias

    2011-07-01

    The aim of this study was to characterize the mineralogy quarry fines samples for its reuse and thus contributing to mitigate the environmental impact caused by this waste. In order to achieve the results, samples were collected and prepared for assays and identification of the mineralogical phases present in the quarry fines from the samples. X-ray diffraction and optical microscopy techniques were used. The quarry of fines characterization was based on qualitatively identification the minerals present in the samples. It was detected the presence of quartz, muscovite and feldspar (albite and microclinite) by x-ray diffraction technique and microscopic and macroscopic observations. Moreover, the size distribution was determined, and the samples presented a medium to fine size (ranging from 9,5 mm to 0,075 mm) and the grains presented an irregular and angular shapes. (author)

  10. Synthesis and characterization of poly(styrene-co-methyl methacrylate); Sintese e caracterizacao do poli(estireno-co-metacrilato de metila)

    Energy Technology Data Exchange (ETDEWEB)

    Augustinho, Tiago R.; Abarca, Silvia A.C.; Machado, Ricardo A.F. [Departamento de Engenharia Quimica e Alimentos - Universidade Federal de Santa Catarina - UFSC, Florianopolis, SC (Brazil)

    2011-07-01

    Polystyrene (PS) is nowadays commonly used due its advantages over competitors. PS presents a lower cost when compared with Acrylonitrile Butadiene Styrene (ABS) and with Polyethylene Tere-phthalate (PET), and can be easier processed than polypropylene (PP). At expandable form (EPS), can be used as projective equipment, thermal insulation, floating boards, refrigerators, isothermal, and low cost applications such as packaging and disposable material. Searching for more resistant materials and with a low cost, researches with copolymers materials are being developed. In this study, copolymerization reactions were carried out by suspension polymerization using monomers styrene and methyl methacrylate (MMA) with styrene. Styrene was in the highest percentage in relation to the MMA. The MMA was selected because is a monomer that presents a higher resistance than PS. The copolymerization was confirmed by performing infrared spectroscopy (IR), nuclear magnetic resonance of hydrogen (RMN{sup 1}H), differential scanning calorimetry (DSC) and thermogravimetry (TGA). (author)

  11. Chemical and radiological characterization of meals served by the COSEAS (USP-SP); Caracterizacao quimica e radiologica de refeicoes servidas pelo COSEAS/USP-SP

    Energy Technology Data Exchange (ETDEWEB)

    Favaro, Deborah Ines Teixeira [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), SP (Brazil). Centro do Reator de Pesquisas. Lab. de Analise por Ativacao Neutronica], e-mail: defavaro@ipen.br; Chioccola, Gabriella Saitta; Bortoli, Maritsa; Cozzolino, Silvia Maria Franciscato [Universidade de Sao Paulo (USP), SP (Brazil). Faculdade de Ciencias Farmaceuticas. Lab. de Alimentos e Nutricao Experimental; Taddei, Maria Helena [Comissao Nacional de Energia Nuclear (CNEN), Pocos de Caldas, MG (Brazil). Coordenacao do Laboratrio de Pocos de Caldas (COLAB); Mazzilli, Barbara Paci [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), SP (Brazil). Div. de Radiometria Ambiental

    2009-01-15

    This study presents the results obtained for the chemical and radiological analyses of lunch meals served in the cafeteria at the University of Sao Paulo-USP (COSEAS restaurant) in Brazil, on 5 non-consecutive days. On each of the five days, the meals were collected in triplicate and then freeze-dried for analysis totalizing 15 samples. The determination of the proximate composition complied with the AOAC standardized methodologies. The content of Ca, Fe, K, Na, Se, and Zn was determined by instrumental neutron activation analysis and the method validation was performed by certified reference materials analyses. Based on the concentration data, the daily intake of each mineral was calculated (corresponding to 40% of the total daily intake) and compared to the new recommendations set by the National Research Council (USA) considering the 19-30 year-old women range group. Comparing the average values obtained in this study with the recommended values, it was possible to verify that for macronutrients and the micronutrients Fe, Se, and Zn the recommendations were followed; for Ca and K they were deficient and exceeded the recommendation value for Na. The radionuclides {sup 40}K, {sup 60}Co, {sup 137}Cs, and {sup 131}I were determined by gamma spectrometry; {sup 90}Sr by liquid scintillation and {sup 210}Po, {sup 234}U, {sup 232}Th, {sup 238}U, {sup 235}U, {sup 228}Th, {sup 230}Th, and {sup 232}Th by alpha spectrometry. All radionuclides are present in concentrations below the limits set by the Food and Agriculture Organization (FAO). (author)

  12. Application of the semantic import approach for characterization of geological contacts; Aplicacao da abordagem da importacao semantica (IS) para caracterizacao de contatos geologicos

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Fabio Roque da Silva; Almeida Filho, Raimundo de; Camara, Gilberto [Instituto Nacional de Pesquisas Espaciais (INPE), Sao Jose dos Campos, SP (Brazil)]. E-mails: fmoreira@ltid.inpe.br; rai@ltid.inpe.br; gilberto@dpi.inpe.br

    2001-07-01

    This work describes the use of semantic import approach (SI) as a way to characterize the sort of geological boundaries in GIS projects. The technique applies fuzzy sets to represent the nature of the lithological boundary (defined and inferred) in a spatial inference modelling study for mapping potential areas for radioactive mineral prospecting in the Pocos de Caldas alkaline complex. (author)

  13. Superficial characterization of titanium league when submitted to abrasive blasting; Caracterizacao superficial de titanio liga ao ser submetido a tratamento de jateamento

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, L.Y.; Leite, I.V.; Szesz, E.M.; Siqueira, C.J.M., E-mail: lsuzuki@neoortho.com.b [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil)

    2010-07-01

    Commercially pure titanium and some of its alloys exhibit a good biocompatibility. These characteristics are frequently used in the manufacture of orthopedic and dental implants. It is possible to modify its surface making it the bioactive using various methods, such as deposition of hydroxyapatite by plasma spray and increasing the roughness of the surface by abrasive blasting. This work is to modify the surface of titanium alloy Ti6Al4V ELI (ASTM F136: 02a) for abrasive blasting and study the morphology, crystallographic phases and the mechanical characteristics of the surface obtained. For such purpose, SEM images, diffraction of X-rays and tests of risk produced by nanoindenter. The sandblasting was done using alumina powder and blasting time of 6s. The morphology of the surfaces of Ti6Al4V ELI changed after sandblasting with increased roughness. It is possible to conclude that after sandblasting the titanium surface do not have a ductile behavior. (author)

  14. Desenvolvimento, caracterizacao e aplicacao da matriz FTO/POLI(3-aminofenol) na deteccao de marcador de lesao cardiaca por fotoluminescencia de quantum dots

    OpenAIRE

    Rodrigues, Luciano Pereira

    2011-01-01

    O coração é um órgão vital propulsor de sangue, que transporta oxigênio e nutrientes para todo organismo, todavia quando estes componentes não chegam a ele devido à obstrução arterial, ocorre instabilidade elétrica no processo de contração deste músculo, causando arritmias que, normalmente em menos de uma hora, promovem o infarto agudo do miocárdio, que juntamente com os problemas vasculares cerebrais são os maiores responsáveis pela mortalidade em todo o mundo. O diagnóstic...

  15. Characterization of polyurethane/organophilic montmorillonite nanocomposites by low field NMR; Caracterizacao de nanocompositos de poliuretano/montmorilonita organofilica por RMN de baixo campo

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Marcos Anacleto da [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Laboratorio de Nanocompositos Polimericos; Tavares, Maria I.B.; Nascimento, Suelen A.M.; Rodrigues, Elton J. da R [Universidade Federal do Rio de Janeiro (NUCAT/PEQ/COPPE/UFRJ), RJ (Brazil). Laboratorio de Nanocompositos Polimericos

    2012-07-01

    Polyurethanes are important and versatile materials, mainly due to some of their properties, such as high resistance to abrasion and tearing, excellent absorption of mechanical shocks and good flexibility and elasticity. However, they have some drawbacks as well, such as low thermal stability and barrier properties. To overcome these disadvantages, various studies have been conducted involving organophilic polyurethane/montmorillonite nanocomposites. The investigation of the structure of polyurethane/clay nanocomposites has mainly been done by X-ray diffraction (XRD) and transmission electron microscopy (TEM). In this work, PU/clay nanocomposite films obtained by solution intercalation were studied. The nanocomposites were characterized by XRD and low-field nuclear magnetic resonance (LF-NMR). The LF-NMR measurements, with determination of the spin-lattice relaxation time of the hydrogen nucleus, supplied important information about the molecular dynamics of these nanocomposites. The X-ray diffraction measurements validated the results found by NMR. The thermal stability of the material was also determined by thermogravimetric analysis (TGA) under an inert atmosphere. A slight improvement in this stability was observed in the nanocomposite in comparison with polyurethane (author)

  16. Mechanical and morphological characterization of a bio-nanocomposite hydroxyapatite / polyurethane; Caracterizacao mecanica e morfologica de um bionanocomposito hidroxiapatita/poliuretano

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Sabina da Memoria Cardoso de, E-mail: sabina_memoria@yahoo.com.br [Instituto Federal de Educacao Ciencia e Tecnologia do Para (IFPA), Belem, PA (Brazil); Dias, Carmen Gilda Barroso Tavares [Universidade Federal do Para (UFPA), Belem, PA (Brazil). Departamento de Engenharia Mecanica; Zavaglia, Cecilia Amelia de Carvalho [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Departamento de Engenharia Mecanica

    2011-07-01

    Nanocomposites based on biocompatible polymers and hydroxyapatite are wide acceptance as bone grafts, the composition, structure and similarity to natural bone and also due to the properties functional, such as surface and mechanical strength. This work there was the making of a bionanocomposite, using nanostructured hydroxyapatite interconnected by polyurethane, generated from the actions of poly(vinylalcohol) and toluene isocyanate HDT. The formation kinetics was monitored by the bionanocomposite spectroscopy and Fourier transform infrared FTIR. The material showed good properties both mechanical and morphology. (author)

  17. Solar dehydration of the water hyacinth and his characterization as fuel; Desidratacao solar do jacinto d'agua e sua caracterizacao como combustivel

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Marcio Amaral de [Universidade Salgado de Oliveira, Niteroi, RJ (Brazil). Dept. de Ciencias Exatas e Tecnologicas; Pinto, Carmen Lucia R. [Instituto Nacional de Tecnologia (INT), Rio de Janeiro, RJ (Brazil). Div. de Meio Ambiente; Pereira, Roberto Guimaraes [Universidade Federal Fluminense, Niteroi, RJ (Brazil). Dept. de Engenharia Mecanica

    1998-07-01

    Because of a new technology for waste water treatment utilizing water treatment utilizing water hyacinth as an instrument for water pollution control, studies were developed to profit the resultant biomass from this process proposing its utilization like an energy source after its dehydration. A direct exposition solar dryer with double glazing was utilized in the process. During the process were evaluated the following parameters: time of drying: physicochemistry characteristics of the plant; and inlet air, outlet air and inside air temperatures during the whole process of drying. (author)

  18. EPR response characterization of drugs excipients for applying in accident dosimetry; Caracterizacao da resposta RPE dos excipientes dos medicamentos para aplicacao em dosimetria de acidente

    Energy Technology Data Exchange (ETDEWEB)

    Marczewski, Barbara S.; Rodrigues Junior, Orlando; Galante, Ocimar L.; Costa, Zelia M. da; Campos, Leticia L. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)

    2002-07-01

    Some drugs are widely used by the population and can be employed to dose retrospective. The carbohydrates (saccharides), commonly used as excipients in the pharmaceutical industry, produce a quantity of free radicals after gamma irradiation, making them useful for dosimetry in emergency or accident situations that imply in dose evaluation from the materials found nearly or in contact with victims. In general, EPR signal from pulverized pills of some drugs are very complex due to the variety of components in the formulation. Because of this fact, some pharmaceutical excipients identified in the pill composition were also analysed by EPR spectrometry. On the counter drugs were studied: Cebion glucose, AAS, Aspirina, Conmel, Lacto-Purga and sugar substitutive ZeroCal. The excipients were: lactose, amide, anhydrous glucose and magnesium stearate. In some samples the number of radicals produced increased with the dose, showing a linear response for a dose range of interest and an adequate sensibility for dosimetry in accident cases.

  19. Resveratrol-loaded poly({epsilon}-caprolactone) microparticles: preparation and characterization; Microparticulas de poli({epsilon}-caprolactona) contendo resveratrol: preparacao e caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    Resveratrol-loaded poly({epsilon}-caprolactone) (PCL) microparticles were obtained by simple emulsion/solvent evaporation method. Three drug-loaded formulations were prepared with the aim of investigating the influence of composition on the encapsulation efficiency. Morphological and spectroscopic methods were performed for these materials. The microparticles revealed residual moisture close to 1.5% and encapsulation efficiency above 80%. Spherical shape and smooth surface were observed by SEM. No pores were either verified. Resveratrol-loaded microparticles showed an average particle size of around 50 {mu}m. X-ray diffraction analysis demonstrated that the microencapsulation reduced the drug crystallinity. The FTIR results suggest that no chemical bond was formed between polymer and drug. (author)

  20. Characterization of ceramics used in mass ceramic industry Goianinha/RN; Caracterizacao de massa ceramica utilizada em industria ceramica de Goianinha/RN

    Energy Technology Data Exchange (ETDEWEB)

    Sales Junior, J.C.C.; Nascimento, R.M. do; Andrade, J.C.S.; Saldanha, K.M., E-mail: jccalado@gmail.com [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil); Dutra, R.P.S. [Universidade Federal da Paraiba (UFPB), PB (Brazil). Laboratorio de Materiais Ceramicos

    2011-07-01

    The preparation of the the ceramic mass is one of the most important steps in the manufacture of ceramic products, since the characteristics of the raw materials used, and the proportions that they are added, directly influence the final properties of ceramic products and the operational conditions of processing. The objective of this paper is to present the results of the characterization of a ceramic mass used in the manufacture of sealing blocks by a red ceramic industry of the city of Goianinha / RN. We analyzed the chemical and mineralogical composition; thermogravimetric and differential thermal analysis; granulometric analysis; evaluation of plasticity; and determining the technological properties of specimens used in test firing at 700, 900 and 1100 ° C. The results show that the ceramic body studied has characteristics that allow use in the manufacture of sealing blocks when burned at a temperature of 900 ° C. (author)

  1. Characterization of microstructure and catalytic of cerium oxide obtained by colloidal solution; Caracterizacao da microestrutura e da atividade catalitica de oxido de cerio obtido por solucao coloidal

    Energy Technology Data Exchange (ETDEWEB)

    Senisse, C.A.L.; Bergmann, C.P.; Alves, A.K., E-mail: carolinasenisse@hotmail.com [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alege, RS (Brazil). Lab. de Materiais Ceramicos

    2012-07-01

    This study investigated to obtain particles of cerium oxide, for use as catalysts for the combustion of methane using the technique of through polymeric colloidal solution. Obtaining the colloidal system is based on hydrolysis of salts such as cerium acetylacetonate, cerium nitrate in the presence of additives such as polyvinylbutyral (PVB), polyvinylpyrrolidone (PVP) and polyvinyl acetate (PVA), at concentrations of 5, 10 and 15% in aqueous or alcoholic medium. These solutions containing ions of interest were subjected to a heat treatment at 650° C for 30 minutes, with heating rate of 2 ° C/ min. After heat treatment, the fibers were characterized according to their morphology, surface area, crystallinity, weight loss and catalytic activity. Samples obtained from cerium acetylacetonate were more reactive than the cerium nitrate to the combustion of methane, as showed greater conversions and higher temperatures reached during the process, which is of utmost importance since the combustion catalytic methane is used for generating thermal energy. After the reaction with methane, the samples underwent significant change in surface area, probably due to the intensity of combustion reactions of the nitrate and the generation of heat involved in this reaction, which gave rise to coarse particles. During the combustion process using the obtained from particles of cerium acetylacetonate, there was the release of large quantities of nitrogen compared to the results of assays with the particles obtained with cerium nitrate. (author)

  2. Characterization of sugar cane bagasse ash as raw material for the production of ceramics; Caracterizacao de cinzas de bagaco de cana como materia prima para producao de ceramica

    Energy Technology Data Exchange (ETDEWEB)

    Fredericci, C.; Indelicato, R.L.; Ferreira Neto, J.B.; Ribeiro, T.R.; Landgraf, F.J.G., E-mail: catiaf@ipt.br [Instituto de Pesquisas Tecnologicas do Estado de Sao Paulo (IPT), Sao Paulo, SP (Brazil). Lab. de Metalurgia e Materiais Ceramicos; Silva, G.F.B. Lenz e [Universidade de Sao Paulo (Poli/USP), Sao Paulo, SP (Brazil). Escola Politecnica. Departamento de Engenharia Metalurgica e de Materiais

    2012-07-01

    The aim of this paper was to analyze the sugar cane bagasse ash from three Sugar and Alcohol Plant of the State of Sao Paulo - Brazil. We intend to show the discrepancies between them, so that this raw material could be used with greater quality control in ceramic industries. The bagasse were analyzed by differential scanning calorimetry (DSC), thermogravimetry (TG) and scanning electron microscopy. The ashes were analyzed by X-ray diffraction, X-ray fluorescence, scanning electron microscopy, energy dispersive spectroscopy, and granulometric separation. The results indicated that the content of SiO{sub 2} ranging from 50-80% by weight depends on the granulometry of the bagasse and on the region where it was collected. The analyses of X-ray diffraction indicate SiO{sub 2}, Fe{sub 2}O{sub 3}, K{sub 2}SO{sub 4} and Mg{sub 2}P{sub 2}O{sub 7} as crystalline phases. (author)

  3. Cloning, periplasmic expression, purification and structural characterization of human ribosomal protein L10; Clonagem, expressao, purificacao e caracterizacao estrutural da proteina ribossomal L10 humana recombinante

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Larissa Miranda

    2009-07-01

    The ribosomal protein L10 (RP L10) is a strong candidate to be included in the class of tumor suppressor proteins. This protein, also denominated as QM, is known to participate in the binding of ribosomal subunits 60S and 40S and the translation of mRNAs. It has a molecular weight that varies between 24 and 26 kDa and an isoelectric point of (pI) 10.5. The sequence of the protein QM is highly conserved in mammals, plants, invertebrates, insects and yeast which indicates its critical functions in a cell. As a tumor suppressor, RP L10 has been studied in strains of Wilm's tumor (WT-1) and tumor cells in the stomach, where was observed a decrease in the amount of its mRNA. More recently, the RP L10 was found in low amounts in the early stages of prostate adenoma and showed some mutation in ovarian cancer, what indicates its role as a suppressor protein in the development of these diseases. It has also been described that this protein interacts with c-Jun and c-Yes inhibiting growth factors and consequently, cell division. This work has an important role on the establishment of soluble expression of QM to give base information for further studies on expression that aim to evaluate the specific regions where it acts binding the 60S and 40S ribosomal subunits and translation, as well as its binding to proto-oncogenes. The cDNA for QM protein was amplified by PCR and cloned into periplasmic expression vector p3SN8. The QM protein was expressed in E. coli BL21 (DE3) in the region of cytoplasm and periplasm, the best condition was obtained from the expression of the recombinant plasmid QM p1813{sub Q}M at 25 degree C or 30 degree C, the soluble protein was obtained with small amounts of contaminants. The assays of secondary structure showed that the QM protein is predominantly alpha-helix, but when it loses the folding, this condition changes and the protein is replaced by {beta}- sheet feature. (author)

  4. Ostrich eggshell as an alternative raw material for hydroxyapatite synthesis; Sintese e caracterizacao de hidroxiapatita a partir da casca de ovo de avestruz

    Energy Technology Data Exchange (ETDEWEB)

    Caliman, L.B.; Gouvea, D., E-mail: orenabatistacaliman@usp.br [Universidade de Sao Paulo (USP), SP (Brazil). Departamento de Engenharia Metalurgica; Della, V.P. [Institutlo Federal do Espirito Santo (IFES), ES (Brazil)

    2011-07-01

    The goal of this study was to investigate the use of ostrich eggshell for hydroxyapatite synthesis, a biomaterial of great medical importance due to its high biocompatibility. The eggshell was used as calcium ions source due its great containing of CaCO3. For its utilization, the eggshell was calcined and the obtained oxide (CaO) was transformed into Ca(OH){sub 2}. Hydroxyapatite synthesis consisted in a wet precipitation reaction between Ca(OH){sub 2} and commercial H{sub 3}PO{sub 4}. The X ray Diffraction analysis has shown that the precipitated Hydroxyapatite calcined at 800°C resulted in a bifasic powder of Hydroxyapatite and β-Tricalcium Phosphate, which proves that this precipitated Hydroxyapatite was deficient in calcium. The Infrared Spectroscopy, showed the presence of CO{sub 3}{sup 2-} ions, result of carrying out the reaction in open atmosphere. By Scanning Electron Microscopy nanometric particles arranged in agglomerates were observed and Specific Surface Area measurement resulted in 11,70 m²/g. Following this procedure, the ostrich eggshell gets a technological profitable reuse also environmentally friendly, being transformed in a new product of high aggregate value. (author)

  5. Obtaining and characterization of chitosan biocomposites / HAP for application as biomaterial; Obtencao e caracterizacao de biocomposito quitosana/hidroxiapatita para aplicacao como biomaterial

    Energy Technology Data Exchange (ETDEWEB)

    Leal, R.C.A.; Nascimento, I.V.S.R.; Fook, M.V.L.; Furtado, G.T.F.S., E-mail: ritaalvesleal@hotmail.com [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Departamento de Engenharia de Materiais

    2011-07-01

    The hydroxyapatite is one of the most biocompatible materials known by encouraging bone growth. However, the main drawback it is the poor mechanical strength. A method to overcome this problem is the addition of the biopolymer chitosan, suitable for applications as biomaterials. In this study was obtained a hydroxyapatite - chitosan biocomposites for application as a biomaterial. In the FTIR analysis it was identified characteristic bands of hydroxyapatite and a possible overlap of the amino group of chitosan by carbonate. XRD analysis showed that there was no change in the profile of HA after chitosan incorporation. In SEM analysis of the biocomposites HA / chitosan, it is observed that there wasn't a complete dispersion of HA particles in the chitosan. In the image of calcined biocomposite, it was found that after heat treatment at 900 ° C chitosan was eliminated, resulting in a porous material. The analysis has shown that the presence of chitosan did not cause significant changes in the phase of hydroxyapatite. (author)

  6. Synthesis and characterization of a nanostructured matrix hydroxyapatite ceramic bone reconstruction; Sintese e caracterizacao de uma matriz ceramica nanoestruturada de hidroxiapatita para reconstituicao ossea

    Energy Technology Data Exchange (ETDEWEB)

    Correa, P.; Camargo, N.H.A.; Silva, D.F. [Universidade do Estado de Santa Catarina (PGCEM/UDESC), SC (Brazil). Programa de Pos-Graduacao em Ciencia e Engenharia de Materiais

    2012-07-01

    The nanostructured ceramics have been shown promise as biomaterials for bone reconstruction. Among calcium phosphates, hydroxyapatite Ca/P ratio = 1.67 mol stands out because of its crystallographic similarity with the mineral bone phase and biocompatibility. This work was based on synthesis and characterization of a nanostructured hydroxyapatite for use in reconstituting bone tissue. The synthesis method for obtaining the bioceramic powder occurred at process of dissolution/precipitation, involving CaO solid/liquid and phosphoric acid required for forming the composition of Ca/P = 1.67 mole. The material recovered from the synthesis was calcined at 900 ° C/2h, providing the hydroxyapatite powder nanometer. This was subjected to mechanical fragmentation process in mill attritor, providing a hydroxyapatite with modified surface morphology. The results presented relate to morphological characterization studies (SEM), mineralogical (XRD), chemical (FTIR) and particle size distribution, using the laser particle size analysis method. Such results showed the formation of hydroxyapatite phase and morphology satisfactory for use in reconstituting bone tissue.

  7. Fishing activity characterization in areas under influence of seismic activity; Caracterizacao da atividade pesqueira em areas sob influencia da atividade sismica

    Energy Technology Data Exchange (ETDEWEB)

    Fuse, Izabel Yukimi; Zanella, Joao Francisco Illa Font; Eliseire Junior, Dirceu; Pereira, Edisio [Hidrosfera Oceanografia e Meio Ambiente, Rio de Janeiro, RJ (Brazil); Souza, Sergio Augusto Coelho de; Ferraz, Alexandre; Costa, Leandro Soares da; Vidal, Leonardo; Duppre, Mauricio [Okeanos Consultoria e Meio Ambiente Ltda. (Brazil); Uller, George [CGG do Brasil, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    Seismic surveys are an important method in prospecting for oil and gas reservoirs in the marine environment. The ELPN/IBAMA has required that companies develop an adequate social programme in parallel with the seismic surveys to establish a better interaction with the communities influenced by these operations and reduce possible negative effects. Between January and October 2003, CGG Brazil studied coastal communities in the following areas. BM-CE-1 e BM -CE-2, Ceara; Fragata, BM-ES-5 e BM-ES-6, Espirito Santo; BM BAR-1 e BM BAR-3, Maranhao and BM-C-25 and BM-C-16 off Campos basin. Communities and groups that could potentially be influenced by the surveys were visited to mitigate direct and indirect impacts. Preliminary results show that fisheries were the main group to be monitored. A standard questionnaire was used to characterize the local fisheries and interviews were held with fishermen, boat owners and members of the fishery industries (n=422). In Ceara the fishery is typically handmade and occurs in water depths up to 200 meters. The main boat propulsion is sail and the 'Cacoeira' is the most popular gear used. Off Espirito Santo, small and medium motored boats are usually used and line is the main gear among the fishermen. At Barreirinhas (Maranhao), boats are usually up to 14 meters long, and operate in water depths of up to 120 metres. Again the 'cacoeira' is the proffered gear. We concluded that Programs carried out by CGG reached their purpose. This is confirmed by low incident rate between seismic ships and the fisheries fleet. (author)

  8. Purification and characterization of a gentiohexaose obtained from botryosphaeran by partial acid hydrolysis; Purificacao e caracterizacao de uma gentioexaose obtida de botriosferana por hidrolise acida parcial

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Iara Ribeiro; Monteiro, Nilson Kobori; Martinez, Paula Felippe; Izeli, Nataly Lino; Vasconcelos, Ana Flora Dalberto; Cardoso, Marilsa de Stefani; Silva, Maria de Lourdes Corradi da [UNESP, Presidente Prudente, SP (Brazil). Faculdade de Ciencias e Tecnologia. Dept. de Fisica, Quimica e Biologia]. E-mail: corradi@fct.unesp.br; Barbosa, Aneli de Melo [Universidade Estadual de Londrina (UEL), PR (Brazil). Dept. de Bioquimica e Biotecnologia; Dekker, Robert F.H. [Universidad de Castilla-La Mancha-IRICA, Ciudad Real (Spain); Silva, Gil Valdo Jose da; Moraes, Luis Alberto Beraldo de [Universidade de Sao Paulo (USP), Ribeirao Preto, SP (Brazil). Faculdade de Filosofia, Ciencias e Letras. Dept. de Quimica

    2008-07-01

    A hexa-oligosaccharide was obtained by partial acid hydrolysis from botryosphaeran, an exopolysaccharide (EPS) {beta}(1{yields}3; 1{yields}6)-D-glucan type, produced by the ascomyceteous fungus Botryosphaeria rhodina. The oligosaccharide was purified by gel filtration and charcoal-Celite column chromatography and the analysis was followed by HPAEC/ PAD. The structure was determined by NMR spectroscopy and mass spectrometry, which showed that the oligosaccharide consists of six {beta}-D-glucopyranosyl units O-6 substituted (gentiohexaose). (author)

  9. X-ray microtomography in the micromorphologic characterization of soil submitted to different management; Microtomografia de raios-X na caracterizacao micromorfologica de solo submetido a diferentes manejos

    Energy Technology Data Exchange (ETDEWEB)

    Passoni, Sabrina

    2013-07-01

    The X-ray computed microtomography (CT) represents a non-invasive technique that can be used with success to analyze physical properties by the soil scientists without destroying the structure of the soil. The technique has as advantage over conventional methods the characterization of the soil porous system in three dimensions, which allow morphological property analyses such as connectivity and tortuosity of the pores. However, as the soil is a non-homogeneous and complex system, the CT technique needs specific methodologies for digital image processing, mainly during the segmentation procedure. The objectives of this work were: 1) to develop a methodology for microtomographic digital image processing; 2) to characterize the soil structure by using micromorphology analysis of samples submitted to non-tillage and conventional systems collected in three distinct layers (0-10, 10-20 and 20-30 cm); and 3) to identify possible changes in the porous system of the soil analyzed due to the effect of different management systems. The use of the CT technique and the procedures adopted for microtomographic digital image processing show to be efficient for the micromorphologic characterization of soil porous system. Soil under non-tillage system presented the best results from the agricultural point of view regarding porosity, total number of pores, connectivity and tortuosity in comparison to the conventional tillage. (author)

  10. Preparation and characterization of polymer nanocomposites based on chitosan and clay minerals; Preparacao e caracterizacao de nanocompositos polimerico baseados em quitosana e argilo minerais

    Energy Technology Data Exchange (ETDEWEB)

    Fiori, Ana Paula Santos de Melo; Gabiraba, Victor Parizio; Praxedes, Ana Paula Perdigao [Instituto Federal de Alagoas (IFAL), Marechal Deodoro, AL (Brazil); Nunes, Marcelo Ramon da Silva; Balliano, Tatiane L.; Silva, Rosanny Christhinny da; Tonholo, Josealdo; Ribeiro, Adriana Santos, E-mail: aribeiro@qui.ufal.br [Universidade Federal de Alagoas (UFAL), Maceio, AL (Brazil)

    2014-09-15

    In this work nanocomposites based on chitosan and different clays were prepared using polyethyleneglycol (PEG) as plasticizer. The samples obtained were characterized by Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), thermogravimetric analysis (TGA/DTG) and by mechanical characterization (tensile test) with the aim of investigating the interactions between chitosan and clay. The nanocomposite films prepared using sodium bentonite (Ben) showed an increase of 81.2% in the maximum tensile stress values and a decrease of 16.0% in the Young’s modulus when compared to the chitosan with PEG (QuiPEG) films, evidencing that the introduction of the clay into the polymer matrix provided a more flexible and resistant film, whose elongation at break was 93.6% higher than for the QuiPEG film. (author)

  11. Characterization of acai seeds as a feedstock for electricity generation via gasification; Caracterizacao do caroco de acai como insumo para geracao de eletricidade via gaseificacao

    Energy Technology Data Exchange (ETDEWEB)

    Seye, Omar; Souza, Rubem Cesar Rodrigues de; Bacellar, Atlas Augusto; Morais, Marcia Rodrigues de [Universidade Federal do Amazonas (CDEAM/UFAM), Manaus, AM (Brazil). Fac. de Tecnologia. Centro de Desenvolvimento Energetico Amazonico], emails: omar_seye@hotmail.com, rubem_souza@yahoo.com.br, abacellar@ufam.edu.br, marcia_morais2004@yahoo.com.br

    2008-07-01

    This work presents an overview of the characterization physical-chemistry and energy of the aca pit used as input in process of generation of electricity through gasification. Acai pits analyses were accomplished with relationship to the acai pit drying, energy content, proximate and ultimate analyses, size, TGA experiments, bulk density. It was observed that the acai pit can be used as bioenergy but, it presents a low energy content (16,36 MJ/kg) in relationship that of the ' typical' biomass (21 MJ/kg ) and this is not due to the ash content that is very low (1,15%), but yes, the only composition that resembles each other more the Carbohydrates than to the typical composition of the usual biomass. The average diameter of 10 pits chosen at random was 9.5 mm. The acai pits have an angle of repose of {approx}20 degrees, making them ideal for feeding into gasification and combustion processes. (author)

  12. Chemical characterization of Xanthan biopolymers synthesized by Xanthomonas campestris pv pruni strains; Caracterizacao quimica de biopolimeros sintetizados por Xanthomonas campestris pv pruni

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Angelita da S.; Vendruscolo, Claire T.; Furlan, Ligia [Universidade Federal de Pelotas, RS (Brazil). Centro de Biotecnologia]. E-mail: angelita@ufpel.tche.br; claire@ufpel.tche.br; ligia@ufpel.tche.br; Galland, Griselda [Rio Grande do Sul Univ., Porto Alegre, RS (Brazil). Inst. de Qumica

    2001-07-01

    In this work we describe the characterisation of Xanthan biopolymers synthesized by two Xanthomonas campestris pv pruni strains, in aerobic fermentation. By chromatography on TLC we could notice the presence of Mannose monomer in higher proportion in the 82 strain with relation to the another ones. The viscosity results showed the temperature dependence. The 06 and 82 strains had their viscosity increased whereas for the 87 strain we could observe a reduction with temperature increasing. The {sup 13}C NMR spectrum of 87 strain showed the characteristic signals at approximately 92.8, 70.4 and 61.4 ppm, attributed to C1, C4 and C6 from glucose monomer, with higher intensity. (author)

  13. Mineralogical characterization of the argillaceous material from the Municipality of Santa Barbara, Para, Brazil; Caracterizacao mineralogica de material argiloso proveniente do municipio de Santa Barbara, Para, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Hildebrando, E.A., E-mail: edemarino@ufpa.b [Universidade Federal do Para (UFPA), Maraba, PA (Brazil). Fac. de Engenharia de Materiais. Lab. de Materiais Ceramicos; Sheller, T.; Angelica, R.S. [Universidade Federal do Para (UFPA), Belem, PA (Brazil). Fac. de Geologia. Inst. de Geociencias; Neves, R.S. [Universidade Federal do Para (UFPA), Belem, PA (Brazil). Fac. de Engenharia Quimica. Inst. de Tecnologia

    2009-07-01

    In the present work were investigated mineralogical phases in a material with argillaceous characteristic of the region of Genipauba, Santa Barbara, State of Para. Characterization of the collected sample was performed by X-ray diffraction (XRD), differential thermal analysis (DTA), thermogravimetric analysis (TG) and infrared spectroscopy (IR). The results of the assays indicate the presence of the clay minerals like kaolinite and muscovite, as well as minerals as quartz and anatase. (author)

  14. Synthesis and characterization of barium titanate, doped with europium and neodymium; Sintese e caracterizacao de titanato de bario, dopados com europio e neodimio

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, Fernanda L.C.; Cabral, Alciney M.; Silva, Ademir O.; Oliveiro, Joao B.L., E-mail: nanda_louise@yahoo.com.br [Universidade Federal do Rio Grande do Norte (UFRN), Natal (Brazil). Instituto de Quimica

    2013-07-01

    This work aims at synthesize and characterize mixed oxides in Barium Titanium matrix in doping with Neodymium and Europium analyzing thermogravimetric curves, characteristic bands at infrared region of the polymer complex, which are intermediates to mixed oxides, and identify the formation thereof, and the crystallinity using XRD analysis.

  15. Synthesis and characterization photocatalyst of titanium oxide obtained by the Pechini; Sintese e caracterizacao fotocatalitica do oxido de titanio obtido pelo Metodo Pechini

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, P.C.; Costa, A.C.F.M.; Lira, H.L. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Departamento de Engenharia de Materiais; Sasaki, J.M. [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Departamento de Fisica; Santos, S.K., E-mail: pollyanacae@yahoo.com.br [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Departamento de Engenharia Quimica

    2011-07-01

    The photocatalysis using TiO{sub 2} semiconductor has shown great efficiency in the treatment of toxic pollutants and non-biodegradable materials, commonly present in air and domestic and industrial effluents. Thus, the aim of this work is to study the evaluation of photocatalytic activity of TiO{sub 2} samples synthesized by the Pechini method at a ratio of citric acid / metal cation of 2:1 and 4:1. The synthesized samples were characterized by X-ray diffraction, quantification of phases using the Rietveld method of refinement of the structure and after analyzed in photocatalytic bench tests using methyl red dye. The results showed that in a 2:1 ratio, the sample resulted in the formation of 100% of anatase phase, while in the 4:1 ratio sample showed 73.51% of anatase phase and 10.5% of rutile phase. The 4:1 sample showed the best performance discoloring over 70% of the dye for a period close to 24h. (author)

  16. Synthesis, characterization and electrical properties of solid electrolyte for solid oxide fuel cell; Preparacao, caracterizacao e propriedades eletricas de eletrolito solido para celula a combustivel de oxido solido

    Energy Technology Data Exchange (ETDEWEB)

    Berton, Marco Antonio Coelho; Garcia, Carlos Mario; Matos, Jeferson Hrenechen [Instituto de Tecnologia para o Desenvolvimento (LACTEC), Curitiba, PR (Brazil)], Emails: felsky@latec.org.br, garcia@latec.org.br, jeferson.h@latec.org.br

    2010-04-15

    Solid electrolytes of BaCe{sub 08}Gd{sub O29} were prepared by the polymeric precursor method. X-ray diffraction data shows a single phase with orthorhombic crystalline structure. The densification process was followed by scanning electronic microscopy and apparent density measurements. The apparent density was developed for different temperatures of sintering, reaching > 96% for sintered temperature of 1550 {sup 0}C deg . The electrochemical impedance analysis was development in the temperature of 400-700 deg C, in air atmosphere at 700 deg C a value of 30,6 mS.cm{sup -1} was obtained. The results of conductivity have confirmed the gadolinium doped barium cerate has a great potential for use as solid electrolyte for intermediate temperature solid oxide fuel cell, at experimental controlled conditions. (author)

  17. Characterization of nanocomposites produced from aqueous mini emulsion containing silver nanoparticles; Caracterizacao de nanocompositos produzidos a partir de miniemulsao aquosa contendo nanoparticulas de prata

    Energy Technology Data Exchange (ETDEWEB)

    Reis, Milvia O.; Orefice, Rodrigo L., E-mail: milviareis@yahoo.com.br [Universidade Federal de Minas Gerais, Escola de Engenharia, Dept. de Engenharia Metalurgica e de Materiais, Belo Horizonte, MG (Brazil)

    2011-07-01

    nanocomposites based on butyl acrylate and styrene monomers were synthesized through the process of free radical polymerization in miniemulsion. An aqueous solution of silver nanoparticles was synthesized and incorporated as the continuous phase (aqueous) to the dispersed phase (oil). To this mixture was added the hydrophobic agent hexadecane and subject to thermodynamic stabilization bu ultrasonification. The nanocomposite films were characterized by FTIR and XRF and their thermal properties evaluated by DSC and TGA. (author)

  18. Synthesis and characterization of gold nanoparticles as diagnostic and therapeutic tool; Sintese e caracterizacao de nanoparticulas de ouro como ferramenta terapeutica e diagnostica

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Pryscila Rodrigues da

    2012-07-01

    Nanomedicine covers the use of nanoparticles to the targeted site of action as platforms for building imaging and therapeutic agents against cancer and other human diseases. In particular, gold nanoparticles (AuNp's) have proven to be efficient for the diagnosis and therapy. Interest in the development of AuNp's is due to their extraordinary physical and chemical properties resulting from the effect of its size in the nanoscale, to have an area of easy modification and the radioactive {gamma} and {beta} emitter ({sup 198}Au; E{gamma} = 0,411 MeV, {beta}{sub max} = 0,96 MeV; T{sub 1/2} = 2,69 days), having the advantage of being able to be applied as a diagnostic tool for molecular photon emission tomography (SPECT) using only a small amount of radioactive gold . In this study were synthesized AuNp's, whose surface is functionalized with a biocompatible polymer (modified polyethylene glycol) and folic acid in order to render them stealth and specific tumors that over express the folate receptors. The techniques of Dynamic Light Scattering (DLS), zeta potential ({zeta}), transmission electron microscopy (TEM) and UV-Visible absorption spectroscopy were employed to characterization of the size and geometry of the nanoparticles, in addition to confirming its binding to thiol -PEG and PEG-thiol Folate. The results of UV-Visible and TEM showed the formation of dispersed AuNp's ranging in size from 8-12 nm with a strong absorption around 520 nm, relating to a maximum of surface plasmon resonance. DLS results showed a hydrodynamic diameter of 10 and 14 nm. The (pH {approx} 5.0 to 6.0) ranged {zeta} potential values of the dispersions prepared between -16.2 and -42.1 mV, indicating stable colloidal suspensions. To determine the real concentration of gold in the samples, it was used neutron activation in the nuclear reactor TRIGA MARK I IPR-R1 CDTN / CNEN of Belo Horizonte. Biocompatibility studies in vitro and in vivo of the samples were carried out showing that they have low toxicity in the models used. We evaluated studies of the internalization of gold nanoparticles functionalized with thiol-PEG-folate-FITC in cells over expressing folate receptors. It was found that the nanoparticles are able to enter the cell, is distributed throughout the cytoplasm and nucleus. According to the results obtained, it can be concluded that it was produced gold nanoparticles dispersed stealth and specific for tumors that overexpression folate. (author)

  19. Obtaining and characterization of thin films polyelectrolyte with gold nanoparticles; Obtencao e caracterizacao de filmes finos de polieletrolitos com nanoparticulas de ouro

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    Thin films of polyelectrolytes are manufactured via sequential adsorption of weak polyelectrolytes from aqueous solutions based on electrostatic interaction of oppositely charged polymers. Metal containing polymeric compounds are of particular interest to the production of materials with electrical interface and optical properties. In this sense, the objective of this study was to obtain thin films of weak polyelectrolytes and analyze the distribution of gold nanoparticles stabilized by sodium citrate and by poly (vinylpyrrolidone). The characterization was performed using UV-visible, X-ray diffraction and atomic force microscopy. The techniques of UV-visible and X-ray diffraction was confirmed the presence of gold in the films, the atomic force microscopy images were used to analyze the morphology of the films and check the behavior of the diffusion of gold nanoparticles. (author)

  20. Characterization of clays used in the red ceramics industry at Itabaianinha-SE (Brazil); Caracterizacao das argilas utilizadas na industria de ceramica vermelha em Itabaianinha-SE

    Energy Technology Data Exchange (ETDEWEB)

    Azevedo, T.F.; Andrade, C.E.C. de; Santos, C.R. dos; Barreto, L.S., E-mail: thiago_figueiredo91@yahoo.com.br [Nucleo de Ciencia e Engenharia de Materiais, Sao Cristovao, SE (Brazil)

    2011-07-01

    The Local Cluster of red ceramic industry in the state of Sergipe comprises Itabaianinha-SE, Itabaiana and Baixo Sao Francisco municipalities (Propria and Santana do Sao Francisco). The city of Itabaianinha concentrates a large number of ceramics and potteries producing ceramic bricks and tiles. The study was conducted in a red ceramic industry of the region. The focus of this work was an incremental innovation in the process and product. It was analyzed three types of clays used for manufacturing of ceramic bricks (barro preto, diamante and jardim). The samples were prepared by pressing and heat treated between 600 ° C - 1100 C °. The samples characterization was by thermogravimetry, X-ray diffraction and physical tests (water absorption, linear retraction and three points flection). The clays are composed mainly of kaolinite, illite-muscovite and quartz. The results showed that the Barro Preto clay showed better results in retraction, absorption and mechanical strain. (author)

  1. Characterization, analysis and dating of archaeological ceramics from the Amazon basin through nuclear techniques; Caracterizacao, analise e datacao de ceramicas arqueologicas da Bacia Amazonica atraves de tecnicas nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Latini, Rose Mary

    1998-07-01

    The aim of this work is to contribute to the research in the reconstruction of part of the pre-history of the Amazon Basin by means of an analytical methods combined with multivariate analysis, given a analytic basis that can be continued by the archaeological work, through the identification, classification, provenance and dating the ceramics found in different archaeological sites of the Hydro graphic Basin of the Purus river. Neutron activation analysis in conjunction multivariate statistical methods were used for the identification and classification and thermoluminescence was used for the dating. Chemical composition results were in better agreement with archaeological classification for the archaeologically define Iquiri, Quinan and Xapuri phases and less characteristics the Iaco and Jacuru archaeological phase were not well characterized. An homogeneous group was established by most of the samples collected from the Los Angeles Archaeological Site (LA) and was distinct from all the other groups analysed. The provenance studies made with ceramics collected at this site shows that they were made with clay from nearby river (Rio Ina). From the LA ceramics dating the average date of site occupation was 1660 years. The ceramic dating results from the external wall of a circular earth wall construction confirm the relation with the local pre-history. Beyond the Acre material two urns were dated from the Archaeological Site Morro Grande and Sao Jose at Araruama, Rio de Janeiro. (author)

  2. Obtention and characterization of chitin and chitosan from M. rosenbergii; Obtencao e caracterizacao de quitina e quitosana a partr de M. rosenbergii

    Energy Technology Data Exchange (ETDEWEB)

    Battisti, Marcos V.; Campana Filho, Sergio P. [Sao Paulo Univ., Sao Carlos, SP (Brazil). Inst. de Quimica]. E-mail: scampana@iqsc.sc.usp.br

    2001-07-01

    Chitin was extracted from previously ground shells of Macrobrachium rosenbergii by applying acid and alkaline treatments, aiming at its demineralization and deprotenization, respectively. Its characteristics and properties were compared with those exhibited by commercial samples of chitin. Commercial chitosan and samples produced by the deacetylation of chitin obtained from M. rosenbergii shells were also compared. Average degrees of acetylation and intrinsic viscosities of the chitosan were determined by {sup 1}H NMR spectroscopy and by capillary viscosimetry, respectively. The results show that the chitin extracted from Macrobrachium rosenbergii has a lower content of inorganic materials as compared to commercial samples but the chitosan obtained from the former chitin sample is very similar to commercial chitosan. (author)

  3. Characterization of silicates and calcium carbonates applied to high-dose dosimetry; Caracterizacao de silicatos e carbonatos de calcio aplicados a dosimetria de doses altas

    Energy Technology Data Exchange (ETDEWEB)

    Vila, Gustavo Barreto

    2012-07-01

    The predominant isomorphous form in the biominerals studied in this work (oyster shell, coral, mother of pearl and shell) was aragonite. The appearance of the calcite phase occurred at 500 deg C at a heating rate of 10 deg {sup C}/s for all samples except for the coral sample, which was 400 deg C, independent of the heating rate. The most abundant element in the biominerals samples was Ca in the CaO form, and in the silicates (tremolite, diopside and rhodonite) Si in the SiO form. The most common trace element observed in the biominerals samples was Fe. The analyses of electron paramagnetic resonance showed lines of Mn{sup 2+} in the coral and mother-of-pearl samples before irradiation. In the case of the irradiated samples, the defects found were CO{sub 2}{sup -}, CO{sub 3}{sup 3-}, CO{sub 3}{sup -} and SO{sub 2}{sup -}, in the g range between 2.0010 and 2.0062. In the analyses by optical absorption of biominerals, transitions due to the presence of Mn in the samples were found. A thermoluminescent (TL) peak at approximately 140 deg C was found for the biominerals and at 180 deg C for silicates, which intensity depends directly on the dose. For samples exposed to different types of radiation, the TL peak occurred at lower temperatures. From the dose-response curves obtained for these materials, it was possible to determine a linear range for which their application in high dose dosimetry becomes possible. Taking into account the radiation type, among biominerals and silicates, the lowest detectable dose (40mGy) to gamma radiation was achieved for oyster shell samples using the measuring technique of optically stimulated luminescence (OSL). Using beta radiation, for diopside and tremolite samples the lowest detectable dose of 60mGy was obtained. For all samples, using the TL, OSL and thermally stimulated exoelectron emission (TSEE) techniques in alpha, beta and gamma radiation beans a good response reproducibility was obtained. Therefore, the samples characterized in this work are suitable to be used as high dose detectors/dosimeters. (author)

  4. Sugar cane bagasse pyrolysis: process optimization and products characterization; Pirolise do bagaco de cana: otimizacao do processo e caracterizacao dos produtos

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Sergio

    1994-07-01

    The ghost of drying of natural resources, mainly the petroleum, desolate the Earth. Although the concern with this fact is recent, it has motivated a run in search of the alternative sources that can replace their self. An alternative source that come earning special attention is biomass, whose research come increasing annually. In Brazil, an important form of biomass, that is rejected like waste and utilized to little noble aim, is the sugar cane bagasse. The objective of this work is to present a conversion process of the bagasse in fuels and raw materials for the chemistry industry. The conversion method adopted was the pyrolysis. To the realization of this conversion, it was constructed a horizontal bed oven, with continuous flow of nitrogen, which carried the pyrolised volatile material, for the trap, during the process. The pyrolysis study was done in the range of 400 deg C to 900 deg C and was optimized utilizing the factorial design. The char, which is a pyrolysis product, was characterized by thermogravimetric and spectroscopic techniques. The tar, which is another pyrolysis product, was characterized by chromatographic and spectroscopic techniques. The results obtained shows that the tar is abundant in organic acids, such fenols and carboxylic acids, which has great utility as raw materials in the chemistry industry. The char, obtained in the range of 400 deg C to 600 deg C, is rich inorganic material, making possible its posterior processing to obtain oils. (author)

  5. Application of artificial neural networks on the characterization of radioactive waste drums; Aplicacao de redes neurais artificiais na caracterizacao de tambores de rejeito radioativo

    Energy Technology Data Exchange (ETDEWEB)

    Potiens Junior, Ademar Jose; Hiromoto, Goro, E-mail: apotiens@ipen.b, E-mail: hiromoto@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-10-26

    The methodology consist of system simulation of drum-detector by Monte Carlo for obtention of counting efficiency. The obtained data were treated and a neural artificial network (RNA) were constructed for evaluation of total activity of drum. For method evaluation measurements were performed in ten position parallel to the drum axis and the results submitted to the RNA. The developed methodology showed to be effective for isotopic characterization of gamma emitter radioactive wastes distributed in a heterogeneous way in a 200 litters drum. The objective of this work as to develop a methodology of analyse for quantification and localization of radionuclides not homogeneous distributed in a 200 liters drum based on the mathematical techniques

  6. Morphological characterization of nanocomposites of membrane PEI/regional clay; Caracterizacao morfologica de membranas de nanocompositos de PEI/argila regional

    Energy Technology Data Exchange (ETDEWEB)

    Medeiros, Vanessa da N.; Leite, Amanda M.D.; Paz, Rene A. da; Araujo, Edcleide M., E-mail: vanismedeiros@gmail.com [Dept. de Engenharia de Materiais, Universidade Federal de Campina Grande - UFCG, Campina Grande, PB (Brazil); Pessan, Luiz A. [Universidade Federal de Sao Carlos - UFSCar, Sao Carlos, SP (Brazil)

    2011-07-01

    The interest in the nanotechnology development in the last decade allows the increase in the nanocomposite area due to the special properties presented by these materials. In the nanocomposite, the nanometric particles are dispersed in the polymer matrix. The membrane separation process, although is recently, is increasing in applications such as purification, fractioning and concentration of substances in several industries. The membranes to gas separation present specific advantages when compared with conventional separation process (such as, cryogenic distillation and adsorption). The aim of this work is to prepare plane membrane by evaporation-precipitation method. These membranes were obtained from polyetherimide (PEI) with bentonite clay from Paraiba/Brazil. The results showed that by XRD, it can be observed there is not practically intercalation of polymer molecules between the layers of clay and was seen by SEM that the membranes have dense structures, ie, favorable for application in gas separation. (author)

  7. Characterization of polymorphism in pharmaceuticals by solid state nuclear magnetic resonance; Caracterizacao de polimorfismo em farmacos por ressonancia magnetica nuclear no estado solido

    Energy Technology Data Exchange (ETDEWEB)

    Aguiar, Monica Regina Marques Palermo de [Universidade do Estado, Rio de Janeiro, RJ (Brazil). Inst. de Quimica. Dept. de Quimica Organica; Gemal, Andre Luis; San Gil, Rosane Aguiar da Silva [Universidade Federal, Rio de Janeiro, RJ (Brazil). Inst. de Quimica. Dept. de Quimica Organica

    1999-08-01

    This review aims to present some features about solid state NMR and its application in the field of pharmaceutical chemistry, for the characterization of polymorphism of pharmaceutical molecules. (author)

  8. Kinetic characterization and of recrystallization of the aluminum alloy 6063 after S work hardening treatment; Caracterizacao e cinetica de recristalizacao da liga de aluminio 6063 apos tratamentos termomecanicos

    Energy Technology Data Exchange (ETDEWEB)

    Esposito, Iara Maria

    2006-07-01

    The aluminum 6063 alloy possesses a great industrial interest, presenting characteristics that justify its frequent use, when compared to the other aluminum alloys: the precipitation hardening and high cold work capacity. These alloys present high ductility, that allows their use in operations with high deformation degrees, as the cold work. The objective of this work is to show comparative analysis of the hardness Vickers of the commercial aluminum 6063 alloy, after cold work with different area reduction degree and thermal treatment. Considering the frequent utilization aluminium 6063 alloy, this work studies the characterization and recrystallization of this alloy, after the plastic deformation in different area reduction degrees, thermal treatment and convenient treatment times - Thermo mechanic Treatments. (author)

  9. Characterization of the main automotive gasoline compounds by using gas chromatography; Caracterizacao dos principais componentes da gasolina automotiva atraves de cromatografia gasosa

    Energy Technology Data Exchange (ETDEWEB)

    Assis, Julio Cesar Rosa; Jaeger, Helena Valli; Almeida, Selmo Queiroz; Teixeira, Leonardo Sena Gomes; Pontes, Luiz Antonio Magalhaes; Vitor Sobrinho, Eledir; Guimaraes, Paulo Roberto Britto; Vianna, Regina Ferreira [Universidade Salvador - UNIFACS, Salvador, BA (Brazil). Dept. de Engenharia e Arquitetura]. E-mail: julio.assis@posgrad.unifacs.br

    2003-07-01

    Gasoline is composed of a number of hydrocarbons of varied structure and different functional groups, which have a marked influence on the final quality of the former. It is thus important to identify the main components of gasoline and how they influence some of its characteristics. This research work is concerned with the development of a technique, based on gas chromatography, for the separation and identification of more than 350 organic compounds likely to be present in gasoline. The study involved 50 gasoline samples collected at gas stations located in Salvador-Bahia (Brazil). The hydrocarbons identified were classified according to their main functional groups and compositions were obtained via a statistical treatment of the raw data. The results have shown that the gasoline used in Salvador has isopentane as the prevalent saturated compound, while m-xylene and methyl-butene are the most frequently found aromatic and olefin, respectively. (author)

  10. Characterization of chemical compounds for dosimetry of the radiation in industrial processes; Caracterizacao de compostos quimicos para dosimetria das radiacaoes em processos industriais

    Energy Technology Data Exchange (ETDEWEB)

    Galante, Ana Maria Sisti

    1999-07-01

    Different chemical compounds have been studied to optimize dosimetric systems in irradiation processes. In this study 2,3,5 Triphenyl -2H- Tetrazolium Chloride, Brilliant Cresyl Blue, Bromocresol Green and Potassium Nitrate were investigated for their merits or faults, for {sup 60} Co gamma field, in order to verify if can be considered as dosimeters. Fricke solution was used as reference dosimeter to determine absorption dose rates at the gamma facilities.Only Bromocresol Green and Potassium Nitrate are recommended for dosimetry purposes since the main characteristics were achieved. The other two compounds could be used in dosimetry with changes in their formulation. Bromocresol Green and potassium Nitrate are reproducible and radiation sensitive for absorbed doses from 300 Gy to 150 kGy Bromocresol Green was used in liquid form and Potassium Nitrate was prepared in solid pellets form. Spectrophotometry in the visible region was used as the main detection technique, which allows relating optical absorption, before and after irradiation, with the absorbed dose. The maximum absorption wavelength for each compound was observed at 450-460nm for bromocresol Green and 546nm for Potassium Nitrate. Dose calibration curves are linear for both compounds in all dose intervals. When irradiated with accelerated electrons, with energies between o,9 MeV and 1,5MeV, optical absorption intensification, of about 2,6 times, was observed when comparing results for Potassium Nitrate, with those for gamma rays. All the evaluations are presented in this work. (author)

  11. Chemical characterization of the gels produced by the diazotrophic bacteria Rhizobium tropici and Mesorhizobium sp; Caracterizacao quimica dos geis produzidos pelas bacterias diazotroficas Rhizobium tropici e Mesorhizobium sp.

    Energy Technology Data Exchange (ETDEWEB)

    Monteiro, Nilson Kobori [Departamento de Engenharia e Tecnologia de Alimentos, Instituto de Biociencias, Letras e Ciencias Exatas, Universidade Estadual Paulista, Sao Jose do Rio Preto - SP (Brazil); Aranda-Selverio, Gabriel; Exposti, Diego Tadeu Degli; Silva, Maria de Lourdes Corradi da [Departamento de Fisica, Quimica e Biologia, Faculdade de Ciencias e Tecnologia, Universidade Estadual Paulista, Presidente Prudente - SP (Brazil); Lemos, Eliana Gertrudes Macedo; Campanharo, Joao Carlos [Departamento de Tecnologia, Faculdade de Ciencias Agrarias e Veterinaria, Universidade Estadual Paulista, Jaboticabal - SP (Brazil); Silveira, Joana Lea Meira [Departamento de Bioquimica e Biologia Molecular, Universidade Federal do Parana, Curitiba - PR (Brazil)

    2012-07-01

    The exopolysaccharides with characteristics of gel produced by Rhizobium tropici (EPSRT) and Mesorhizobium sp (EPSMR) are acidic heteropolysaccharide composed mainly of glucose and galactose in a molar ratio of 4:1 and 5:1 respectively, with traces of mannose ({approx} 1%). Chemical analysis showed the presence of uronic acid, pyruvate and acetyl-substituents in the structures of both polymers. Experiments of gel permeation chromatography and polyacrylamide gel electrophoresis showed that EPSRT and EPSMR are homogeneous molecules with low grade of polydispersity. The EPS were characterized using spectroscopic techniques of FT-IR, {sup 1}H and {sup 13}C-NMR. (author)

  12. Characterization of isolated communities: application in the city of Ubatuba, Sao Paulo state, Brazil; Caracterizacao de comunidades isoladas: aplicacao em comunicade de Ubatura/SP

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Maria Julita Guerra [Secretaria de Estado de Energia, Recursos Hidricos e Saneamento (SERHS), Sao Paulo, SP (Brazil)], e-mail: mjulita@sp.gov.br; Pilla, Adelina Teixeira Fonseca de [Equilibrio, Desenvolvimento Ambiental Ltda., Sao Paulo, SP (Brazil)], e-mail: adelina.fonseca@uol.com.br

    2004-07-01

    This paper presents a methodology for characterization of isolated communities, developed on a consultant work for the Ministry of Mines and Energy - MME. It still presents the application of this methodology of analysis on a isolated community in the city of Ubatuba, Sao Paulo state. (author)

  13. Characterization of Nafion ionomer and its change due to X radiation; Caracterizacao do ionomero Nafion e sua modificacao por irradiacao de raios X

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Selma Helena de

    1996-07-01

    In this study, first the characterization of Nafion-117 membranes in the acid form (Nafion-H) and in the salt forms (Na{sup +}, K{sup +}, Rb{sup +} and Cs{sup +}) was performed. In another step, the X-ray effects on membranes (Nafion-H and Nafion-Na) were investigated. The samples were irradiated with X-ray, at 160 kGy/h, with 80-1280 kGy dosages. The characterization of samples (irradiated and unirradiated samples) was performed by X-ray diffractometry, vibrational spectroscopy (photoacoustic in infrared region and Raman scattering), electronic absorption spectroscopy (UV/Vis), electronic paramagnetic resonance spectroscopy (EPR) and thermal analysis (TG and DCS). The studies showed that the membranes submitted to high temperature or to hydration structural changes, as evidence by IR and UV/Vis spectra and DSC curves. This behavior can be assigned to the reorganization of the clusters, resulting in redistribution of the ions and reorientation of the polymers. UV/Vis spectra and DSC curves indicates that the conformational changes induced by temperature and hydration effect continue to occur slowly in the membrane due to relaxation of the polymer. TG analysis indicated that the thermal decomposition mechanism by Nafion-H is different from the mechanism by Nafion-Na. Nafion-H membranes degraded in at least three stages, while Nafion-Na membranes, which showed higher thermal stability than Nafion-H, degraded in only one stage. For irradiation dose higher than 320 kGy, the samples became brittle, which enhanced with increasing doses. This behavior indicates that the predominant effect was the chain scission. The results obtained by different technique showed that the main effects of X-rays on Nafion membranes are the following: decrease in the mechanical properties, peroxy radical production, formation of unsaturated species (C=C and C=O), scissions in the C-O and C-S bonds and SO{sub 2} production. The Nafion-Na membrane showed higher thermal stability and higher resistance to X-ray compared to Nafion-H. UV/Vis and IR spectra of the irradiated samples revealed that additional degradation continues to occur for long time after irradiation process. (author)

  14. Characterization of two clays - attapulgite and sepiolite - before and after acid activation; Caracterizacao de duas argilas - atapulgita e sepiolita - antes e apos ativacao acida com HCl

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, R.N.; Soares, G.A., E-mail: renataoliveira@poli.ufrj.b [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Centro de Tecnologia; Barreto, L.S. [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil)

    2009-07-01

    Among the special clays, two of them are distinguished by their large surface area: attapulgite and sepiolite. Although, being natural clays, when they are removed from the formation sites, their structural channels may be filled of impurities. The process done to clean these channels is called acid activation. The present work aim to treated samples from both clays by using 3M and 5M HCl solution under ultrasonic waves for 1 hour. The characterization of the clays before and after activation was carried out by SEM/EDS, XRD and surface area measure by method BET. The acid treatments employed were too aggressive, in special that with 5M HCl solution, which results in partial lixiviation of these clays. (author)

  15. Physicochemical characterization of ceramics from Sao Paulo II archaeological site; Caracterizacao fisico-quimica da ceramica do sitio arqueologico Sao Paulo II

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, Rogerio Baria

    2013-08-01

    Archaeometry is a consolidated field with a wide application of nuclear analytical techniques for the characterization, protection, and restoration of archaeological pieces. This project aimed at studying the elementary chemical composition of 70 ceramic fragments samples from Sao Paulo II archaeological site, located along the Solimoes River channel, next to Coari city, in Brazilian Amazon. The characterization of samples was performed by neutron activation analysis (NAA). By the determination of 24 elements in the ceramic fragments ( Ce, Co, Cr, Cs, Eu, Fe, Hf, K, La, Lu, Na, Nd, Sb, Sm. Rb, Se, Ta, Tb, Th, U, Yb and Zn), it was possible to define groups of samples regarding the similarity/dissimilarity in elementary chemical composition. For such a task, the multivariate statistical methods employed were cluster analysis (C A), principal component analysis (PCA) and discriminant analysis (DA). Afterwards, seven ceramic fragments were selected based on the groups previously established, for the characterization of the site temporal horizon. Those ceramic fragments were analyzed by thermoluminescence (TL) and EPR for dating purposes. The firing temperatures were determined by electron paramagnetic resonance (EPR) technique, in order to infer about some aspects of the ceramic manufacture employed by the ancient peoples that lived in Sao Paulo 11. By the results obtained in this study, it was possible to identify the quantity of clay sources employed by the ceramists and the age of the ceramic pieces. Therefore, the results of this research may contribute to the study on the occupation dynamics in the pre-colonial Brazilian Amazon. (author)

  16. For production of ceramic plates coating using waste kaolin, granite and marble; Caracterizacao de residuos de caulim, granito e marmore para uso em massas ceramicas

    Energy Technology Data Exchange (ETDEWEB)

    Sales, J.L.; Morais, C.R.S.; Lima, L.M.R.; Altidis, M.E.D., E-mail: josyanne27@yahoo.com.br [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2011-07-01

    The objective is to benefit and characterize waste from kaolin, marble and granite studying their thermal properties and spectroscopic in employment perspective on ceramic production of flooring boards. The residues were benefited through the process of dry grinding mill in greyhounds and passed through sieve 0.074 mm (ABNT No. 200), observing their suitability for the formulation of ceramic pastes. Tests were performed physicochemical characterization (particle size analysis, X-ray fluorescence and X-ray diffraction) and thermal (differential thermal analysis and thermogravimetry). The results showed that these residues showed satisfactory properties for the purpose for which it proposes, and contribute to reducing environmental impacts, allowing the reuse of the production of ceramic plates (author)

  17. Synthesis and characterization of tricalcium phosphate ceramics doped with zinc; Sintese e caracterizacao de ceramicas de tricalcio fosfato dopadas com zinco

    Energy Technology Data Exchange (ETDEWEB)

    Kai, K.C.; Marchi, J., E-mail: kai.kc@hotmail.com, E-mail: juliana.marchi@ufabc.edu.br [Universidade Federal do ABC (CCNH/UFABC), Santo Andre, SP (Brazil). Centro de Ciencias Naturais e Humanas; Ussui, V.; Bressiani, A.H.A. [Instituto de Pesquisas Energeticas e Nucleares (CCTM/IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro de Ciencia e Tecnologia de Materiais

    2011-07-01

    Due to its biocompatibility, the tricalcium phosphate (TCP) is used as a biomaterial for bone replacement and reconstruction. Zinc (Zn) can replace calcium in the crystal structure of TCP to be added in small quantities, can result in stimulatory effects on bone formation in vitro and in vivo. In this work, pure TCP and Zn-TCP, with general formula (Ca{sub 1-x}Zn{sub x}){sub 3} (PO{sub 4}){sub 2} and 0 ≤ x ≤ 0.0225, were prepared by wet synthesis, from precursors Ca(OH){sub 2}, H{sub 3}PO{sub 4} and ZnO, after calcinated at 800 deg C and characterized by X-ray diffraction, specific surface area, agglomerate size distribution, differential thermal analysis and scanning electron microscopy. The results showed that the addition of small amounts of Zn resulted in TCP with suitable densification and higher specific surface area, may be promising as biomaterial due to the stimulatory effects of zinc associated with suitable mechanical properties of the final material. (author)

  18. FTIR Spectroscopy characterization of PVC films grafted and heparinized by gamma radiation; Caracterizacao de fimes de PVC enxertados e heparinizados via radiacao gama por espectroscopia FTIR

    Energy Technology Data Exchange (ETDEWEB)

    Panzarini, Luz C.G.A. [Centro Universitario da FEI, Sao Bernardo do Campo, SP (Brazil). Dept. de Engenharia Quimica]. E-mail: luz_con@yahoo.com.br; Guedes, Selma M.L. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2005-07-01

    Polymeric biomaterials with surface hemo compatibility properties had been successfully synthesized by the grafting of hydrophilic monomers onto commercial polymeric films by the simultaneous gamma irradiation process. In this work was studied the simultaneous gamma irradiation of flexible PVC films in systems containing the hydrophilic monomer DMAEMA in different concentrations (30% and 45%) and heparin sodium salt aqueous solution (0,25% w/v). The irradiation of the samples was carried out in a {sup 60}Co source, with doses of 0-16 kGy and dose rates of 0,5 to 0,8 kGy h{sup -1}. The grafted copolymers obtained by this method were characterized by FTIR-ATR and PAS spectroscopy in both DMAEMA studied concentrations. The graft copolymer characterization, accomplished by FTIR-PAS evidenced the largest grafting levels for the irradiated samples with 45% of DMAEMA, however heparin presence was only evident on irradiated samples with 30% of DMAEMA. This studies shows that the grafting of the monomer occurs in the surface of the films and the excess of the grafting difficult the heparin linkages in the polymeric matrix. (author)

  19. Synthesis and characterization of polypropylene/graphite nano composite preparation for in situ polymerization; Sintese e caracterizacao de nanocompositos polipropileno/grafite obtidos pela polimerizacao in situ

    Energy Technology Data Exchange (ETDEWEB)

    Montagna, L.S.; Fim, F. de C.; Galland, G.B. [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Inst. de Quimica; Basso, N.R.S., E-mail: nrbass@pucrs.b [Pontificia Universidade Catolica do Rio Grande do Sul (PUC-RS), Porto Alegre, RS (Brazil)

    2010-07-01

    This paper presents the synthesis of polypropylene/graphite nanocomposites through in situ polymerization, using the metallocene catalyst C{sub 20}H{sub 16}Cl{sub 2}Zr (dichloro(rac-ethylenebis(indenyl))zircon(IV)). The graphite nanosheets in nano dimensions were added to the polymer matrix in percentages of 0.6;1.0;4.2;4.8 and 6.0% (w/w). The TEM images indicated that the thickness of graphite nanosheets ranged from 4 to 60 nm and by means of XRD analysis it was observed that the physical and chemical treatment did not destroyed the graphite layers. The presence of nanosheets did not decrease the catalytic activity of the nanocomposites. TEM images and XRD analysis of nanocomposites showed a good dispersion of the graphite nanosheets in the polypropylene matrix. (author)

  20. Chemical characterization of polymeric surge arresters and insulators used in high voltage lines; Caracterizacao quimica de para-raios e isoladores utilizados em linhas de alta tensao

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira Junior, Joao B. de; Castro Junior, Joao B. de; Silva, Maria Elisa S.R. e; Freitas, Roberto F.S.; Sousa, Ricardo G. de [Lab. de Ciencia e Tecnologia de Polimeros, Dept. de Engenharia Quimica da EE.UFMG, Belo Horizonte, MG (Brazil); Souza, Breno P.G. de [CEMIG Distribuicao S/A, Belo Horizonte, MG (Brazil)], e-mail: bpgsouza@gmail.com

    2011-07-01

    In the last two decades, traditional porcelain and glass surge arresters and insulators, used in the electrical system, have been replaced by polymeric materials. For this type of application it is recommended that these devices have a high resistance to environmental stresses and impacts without suffering degradation process. Considering the environmental conditions these polymers are exposed to, when used for this purpose, studies of their chemical composition are needed. In this work, polymeric materials present in surge arresters and insulators used in electrical system were chemically characterized by Fourier Transform Infrared Spectroscopy (FTIR). FTIR analysis showed that the samples tested are made of poly(dimethylsiloxane) - PDMS (silicone) and additives such as alumina trihydrated [Al (OH)3] and calcium carbonate. (author)

  1. Synthesis and characterization of cellulose derivatives obtained from bacterial cellulose; Sintese e caracterizacao de derivados celulosicos obtidos a partir da celulose bacteriana

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Rafael L. de; Barud, Hernane; Ribeiro, Sidney J.L.; Messaddeq, Younes, E-mail: rafael.tu@gmail.com [Instituto de Quimica - Universidade Estadual Paulista Julio de Mesquita Filho - UNESP, Araraquara, SP (Brazil)

    2011-07-01

    The chemical modification of cellulose leads to production of derivatives with different properties from those observed for the original cellulose, for example, increased solubility in more traditional solvents. In this work we synthesized four derivatives of cellulose: microcrystalline cellulose, cellulose acetate, methylcellulose and carboxymethylcellulose using bacterial cellulose as a source. These were characterized in terms of chemical and structural changes by examining the degree of substitution (DS), infrared spectroscopy (FTIR) and nuclear magnetic resonance spectroscopy - NMR {sup 13}C. The molecular weight and degree of polymerization were evaluated by viscometry. The characterization of the morphology of materials and thermal properties were performed with the techniques of X-ray diffraction, electron microscopy images, differential scanning calorimetry (DSC) and thermogravimetric analysis. (author)

  2. Extraction and characterization of whiskers from Panicum grass cellulose fibers; Extracao e caracterizacao de whiskers a partir das fibras de celulose do capim mombaca

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Douglas F.; Vieira, Julia G.; Pasquini, Daniel [Instituto de Quimica - Universidade Federal de Uberlandia - UFU, Campus Santa Monica, Uberlandia, MG (Brazil)

    2011-07-01

    In this work are presented studies of the extraction of cellulose whiskers from Panicum grass fibers (Panicum maximum) by acid hydrolysis performed with H{sub 2}SO{sub 4} 11.22 M. The fibers used in the hydrolysis process were previously purified and the efficiency of the purification process was evaluated by determining the lignin content by Klason method, before and after purification. The hydrolysis was performed at 40 degree C for 30 minutes. The whiskers were characterized by x-ray diffraction (XRD) and thermogravimetric analysis (TGA). It was verified a reduction in the crystallinity index and also a reduction of the degradation temperature of the whiskers in relation to the purified grass Panicum fibers. (author)

  3. Preparation and characterization of nanocomposites of the carboxymethyl cellulose reinforced with cellulose nanocrystals; Preparacao e caracterizacao de nanocompositos de carboximetilcelulose reforcados com nanocristais de celulose

    Energy Technology Data Exchange (ETDEWEB)

    Flauzino Neto, Wilson P.; Silverio, Hudson A.; Vieira, Julia G.; Silva, Heden C.; Rosa, Joyce R.; Pasquini, Daniel, E-mail: wilsonpfneto@yahoo.com.br [Instituto de Quimica - Universidade Federal de Uberlandia - UFU, MG (Brazil); Assuncao, Rosana M.N. [Fac. de Ciencias Integradas do Pontal - FACIP, Universidade Federal de Uberlandia, Ituiutaba, MG (Brazil)

    2011-07-01

    Nanocrystals of cellulose (NCC) isolated from Eucalyptus urograndis Kraft pulp were used to prepare nanocomposites employing carboxymethyl cellulose (CMC) as matrix. The nanocrystals were isolated by hydrolysis with H{sub 2}SO{sub 4} 64% solution, for 20 minutes at 45 deg C. The nanocrystals were characterized by X-ray diffraction to evaluate the crystallinity of them. The amount of NCC used in the preparation of nanocomposites varied from 0 to 15%. The nanocomposites were characterized by thermal and mechanical analysis. A large reinforcing effect of NCC on the CMC matrix was observed. With the incorporation of the NCC, the tensile strength of nanocomposites was significantly improved by 107%, the elongation at break decreased by 48% and heat resistance to decomposition increased subtle. The improvement in thermo-mechanical properties are attributed to strong interactions between nanoparticles and CMC matrix. (author)

  4. Preparation and characterization of blends containing silk fibroin and chitosan;Obtencao e caracterizacao de blendas de fibroina de seda e quitosana

    Energy Technology Data Exchange (ETDEWEB)

    Moraes, Mariana A. de; Nogueira, Grinia M.; Weska, Raquel F.; Beppu, Marisa M., E-mail: beppu@feq.unicamp.b [Universidade Estadual de Campinas (FEQ/UNICAMP), SP (Brazil). Faculdade de Engenharia Quimica

    2009-07-01

    The aim of this study was to prepare and characterize blend membranes of silk fibroin and chitosan. Moreover, a conformation of fibroin to a more stable form induced by the addition of chitosan was verified. Blend membranes of fibroin/chitosan were prepared in different proportions and had their crystallinity, structural conformation and thermal stability characterized. The results of crystallographic analysis (XRD) indicated the tendency to higher structural organization caused by the addition of chitosan. FTIR showed that, mainly in a content of chitosan of only 25%, fibroin is present in a more stable form. Thermal analyzes indicate that fibroin is thermally stable and that when its proportion in the blend increases, the temperature in which the degradation is initiated also does so. (author)

  5. Synthesis and characterization of dense membranes of silk fibroin with glycerin;Sintese e caracterizacao de membranas densas de fibroina de seda com glicerina

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Mariana F.; Moraes, Mariana A. de; Weska, Raquel F.; Nogueira, Grinia M.; Beppu, Marisa M., E-mail: beppu@feq.unicamp.b [Universidade Estadual de Campinas (FEQ/UNICAMP), SP (Brazil). Faculdade de Engenharia Quimica

    2009-07-01

    The addition of plasticizers seeks improvements in mechanical properties of dense membranes of silk fibroin with possible interactions by hydrogen bonds. The aim of the present study was to produce and characterize dense membranes of silk fibroin containing glycerin in two different concentrations. The characterization of the membranes was performed from scanning electron microscopy (SEM), mechanical traction tests, infrared spectroscopy (FTIR-ATR) and X-ray diffraction (XRD). The results indicated that the addition of glycerin allowed obtaining homogeneous and more crystalline membranes and improved their properties of elongation. (author)

  6. Characterization of ceramic product of the Apodi region in Rio Grande do Norte, Brazil; Caracterizacao do produto ceramico da regiao do Apodi no Rio Grande do Norte

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, Maria R.; Freire, Juvenise T.C., E-mail: rosimar.sousa@jfrn.edu.br, E-mail: juvenise.costa@ifrn.edu.br [Instituto Federal de Educacao, Ciencia e Tecnologia do Rio Grande do Norte (IFRN), Mossoro, RN (Brazil)

    2011-07-01

    Due to the great precariousness of information on ceramics products, as the brick of Rio Grande do Norte state, the purpose of this work was to analyze the physical and mechanical characteristics of ceramic bricks for construction manufactured in Assu region of the state. Therefore, samples were collected in cities belonging to different potters poles. The bricks were subjected to several tests: visual, absorption, suction, compressive strength, dimensions and flatness deviation from the square. According to ABNT standard, the products need some improvement in quality.

  7. Characterization of the Ni-45wt% Ti shape memory alloy rapidly solidified; Caracterizacao da liga Ni-45wt%Ti com efeito de memoria de forma solidificadas rapidamente

    Energy Technology Data Exchange (ETDEWEB)

    Anselmo, G.C.S.; Castro, W.B. de; Araujo, C.J. de, E-mail: walman@dem.ufcg.edu.b [Universidade Federal de Campina Grande (UAEM/UFCG), PB (Brazil). Unidade Academica de Engenharia Mecanica

    2010-07-01

    One important challenge of microsystems design is the implementation of miniaturized actuation principles efficient at the micro-scale. Shape memory alloys (SMAs) have early on been considered as a potential solution to this problem as these materials offer attractive properties like a high-power to weight ratio, large deformation and the capability to be processed at the micro-scale. shape memory characteristics of Ni-45wt%Ti alloy ribbons prepared by melt spinning were investigated by means of differential scanning calorimetry and X-ray. In these experiments particular attention has been paid to change the velocity of cooling wheel from 30 to 50 m/s. Then the cooling rates of ribbons were controlled. The effect of this cooling rate on martensitic transformation behaviors and structure are discussed. (author)

  8. Microstructural characterization of titanium dental implants by electron microscopy and mechanical tests; Caracterizacao microestrutural de implantes dentarios de titanio por microscopia eletronica e ensaios mecanicos

    Energy Technology Data Exchange (ETDEWEB)

    Helfenstein, B.; Muniz, N.O.; Dedavid, B.A., E-mail: bruhelfenstein@hotmail.co [Pontificia Univ. Catolica do Rio Grande do Sul (FE/PUC/RS), Porto Alegre, RS (Brazil). Fac. de Engenharia; Gehrke, S.A. [Universidade Federal de Santa Maria (FE/UFSM), RS (Brazil). Fac. de Engenharia; Vargas, A.L.M. [Parque Tecnologico da PUCRS (TECNOPUC/GEPSI), Porto Alegre, RS (Brazil). Grupo de Estudos de Propriedades de Superficies e Interfaces

    2010-07-01

    Mini screw types for titanium implants, with differentiated design, were tested for traction and torsion for behavior analysis of the shape relative to the requirements of ASTM F136. All implants showed mechanical tensile strength above by the standard requirement, being that 83.3% of them broke above the doughnut, in support of the prosthesis. Distinct morphologies in ruptured by mechanical tests, were obtained. However, both fracture surfaces showed fragile comportments. Metallographic tests, x-ray diffraction (XRD) and microhardness were used for microstructural characterization of material, before and after heat treatment. The presences of {beta} phase in screw surface after quenching treatment proves that the thermal treatment can contribute for mechanical resistance in surface implants. (author)

  9. The importance of using diffraction of X ray in clays characterization; A importancia da utilizacao da difracao de raios X na caracterizacao de argilas

    Energy Technology Data Exchange (ETDEWEB)

    Piccoli, R.; Nascimento, G.C.; Vitoretti, P.P.; Wernck, A.S.W., E-mail: rosaura@sc.senai.b [SENAI, Criciuma, SC (Brazil). Centro de Tecnologia em Ceramica; Perdona, C.R. [Universidade Barriga Verde, Cocal do Sul, SC (Brazil). Curso de Engenharia Ceramica; Perucchi, P. [Universidade do Extremo Sul Catarinense, Criciuma, SC (Brazil). Curso de Ciencia e Engenharia de Materiais

    2009-07-01

    The objective of this work is to demonstrate how the identification of crystalline phases and deg of crystallinity by diffractometry technique of X-ray (XRD) combined with chemical analysis of a sample can help in the study and characterization of raw materials, mainly those used in ceramic compositions. This study also aims to address the inherent limitations of this technique in relation to types of crystalline phases present in the sample of interest for analysis. (author)

  10. Characterization of polymers and analysis of inorganic constituents in metallized plastic packages; Caracterizacao de polimeros e determinacao de constituintes inorganicos em embalangens plasticas metalizadas

    Energy Technology Data Exchange (ETDEWEB)

    Soares, Eufemia P.; Nunes, Edilene de Cassia D. [Escola SENAI Mario Amato, Sao Paulo, SP (Brazil)]. E-mail: eufemia_paez@hotmail.com; Saiki, Mitiko [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil); Wiebeck, Helio [Sao Paulo Univ., SP (Brazil). Escola Politecnica

    2002-09-01

    This paper presents analytical results of metallized plastic materials obtained by neutron activation analysis (NAA) and the results of identification of polymers by infrared spectroscopy (IR) and differential scanning calorimetry (DSC). Metallized plastic samples were collected from packages of foodstuffs and cosmetics. Results of IR and DSC tests indicated that polyethylene, polypropylene, poly(ethylene terephthalate) and polystyrene are polymers used in metallized plastics. The NAA consisted of irradiating samples and standards with thermal neutron flux of the IEA-R1 nuclear reactor, followed by induced gamma ray activities measurements using a hyper pure germanium detector coupled to a gamma ray spectrometer. Toxic elements such as arsenic, cadmium, chromium, nickel and antimony as well as non-toxic elements as barium, calcium, cobalt,iron, scandium,, selenium and zinc were determined and their concentrations presented a large variability between the samples. The analyses of polymer and toxic elements are of great interest to develop adequate and safe processes for recycling or incineration of metallized plastic packages without causing damage to the environment. (author)

  11. Synthesis, characterization and thermal behaviour on solid pyruvates of light trivalent lanthanides; Sintese, caracterizacao e comportamento termico dos piruvatos de lantanideos leves no estado solido

    Energy Technology Data Exchange (ETDEWEB)

    Siqueira, A.B.; Carvalho, C.T. de; Ionashiro, M. [UNESP, Araraquara, SP (Brazil). Inst. de Quimica]. E-mail: massaoi@iq.unesp.br; Rodrigues, E.C. [Fundacao Educacional de Barretos, SP (Brazil); Ionashiro, E.Y.; Bannach, G. [Universidade Estadual de Ponta Grossa (UEPG), PR (Brazil). Dept. de Quimica

    2007-07-01

    Solid State Ln-L compounds, where Ln stands for light trivalent lanthanides (La - Gd) and L is pyruvate, have been synthesized. Thermogravimetry and derivative thermogravimetry (TG/DTG), differential scanning calorimetry (DSC), X-Ray powder diffractometry, infrared spectroscopy, elemental analysis, and complexometry were used to characterize and to study the thermal behaviour of these compounds. The results led to information about the composition, dehydration, ligand denticity, thermal behaviour and thermal decomposition of the isolated compounds. (author)

  12. Hydrocarbons origin and classification of the Sergipe-Alagoas Basin: geochemical characterization; Origem e classificacao dos hidrocarbonetos da Bacia Sergipe-Alagoas: caracterizacao geoquimica

    Energy Technology Data Exchange (ETDEWEB)

    Babinski, Nelson A.; Santos, Regina C.R. dos [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    1987-05-01

    Researches made on Sergipe-Alagoas sedimentary basin, found some oil and gas accumulations. Geochemical characterization based on isotopics and chromatographic studies, and chemical analysis of these oils are discussed. These analysis permitted identification of three oils types with distinct characteristics. The correlation between these oils with the generator rocks, construction of a model to demonstrate the generation, transport and accumulation of oil on these basin, are also related. 12 figs., 5 refs

  13. Characterization of red ceramic pastes incorporated with sugarcane bagasse ash wastes; Caracterizacao de massa ceramica vermelha incorporada com residuo de cinzas de bagaco de cana-de-acucar

    Energy Technology Data Exchange (ETDEWEB)

    Faria, K.C.P.; Gurgel, R.F.; Holanda, J.N.F., E-mail: katiacpfaria@hotmail.co, E-mail: holanda@uenf.b [Universidade Estadual do Norte Fluminense (LAMAV/UENF), Campos dos Goytacazes, RJ (Brazil). Lab. de Materiais Avancados. Grupo de Materiais Ceramicos

    2010-07-01

    The alcohol industry is one sector that stands out most in the Brazilian agribusiness. Currently there is an increasing demand for sugar and ethanol for use as fuel. The processes of manufacturing these products generate large amounts of waste, the sugarcane bagasse ash waste one of the most abundant. For its chemical and mineralogical characteristics, this waste has aroused the interest of its reuse in the field of red ceramic. This study analyzes the characteristics of a red ceramic paste incorporated with up to 20 wt.% of waste. The following characteristics were performed: chemical composition, X-ray diffraction, particle size, morphology, and Atterberg limits. The results show that the incorporation of sugarcane bagasse ash waste influences the physical-chemical and mineralogical characteristics of red ceramic paste. (author)

  14. Isolation and characterization of delta toxin from the venom of Crotalus durissus terrificus; Isolamento e caracterizacao da delta toxina do veneno de Crotalus durissus terrificus

    Energy Technology Data Exchange (ETDEWEB)

    Campos, Lucelia de Almeida

    2006-07-01

    The Crotalus durissus terrificus venom has been so far described as being of low complexity, with four major components described: convulxin, gyroxin, crotoxin and crotamine. In recent studies, other components of this venom were characterized as, for example, an analgesic factor. In 1980, Vital Brazil predicted the existence of a toxin which could be involved in platelet aggregation, and named it delta toxin. However, this toxin has never been isolated or characterized. The aim of the present work was to purify and characterize this toxin. After FPLC size exclusion chromatography followed by reverse phase HPLC, an homogeneous fraction was obtained, with a molecular weight of 14,074.92 Da. When analyzed by SOS-PAGE, this toxin presented an anomalous behavior, with a molecular weight of 14 kDa, while in 2D gels, spots around 40 kDa and with an isoelectrical point between 4 and 5 were observed suggesting isoforms with glicosilation microheterogeneity. After trypsin digestion, the fragments were submitted to the swissprot databank showing high homology (43% coverage, 15 matching peptides) with trocarin, a prothrombin activator from Tropidechis carinatus. These data were further confirmed by aminoacid analysis. The toxin was tested for its ability to activate factor II and X using synthetic substrates. Our data indicate a direct activation of factor X. The same toxin also behaved as a potent direct platelet aggregation activator on washed platelets. Assays with specific inhibitors indicate that neither metalloproteinase, nor serinoproteinase or t lectin domains are involved in the aggregating activity, since EDTA, benzamidin and D-galactose did not inhibit the toxin. In the present work, we were able to identify, purify and characterize a new toxin from the brazilian rattlesnake. It behaved as predicted by Vital-Brazil and displayed direct factor X activating properties, also inducing platelet aggregation, even at low concentrations. Our data also indicate that it is probably a homotrimer with the subunities linked by hydrophobic and/or electrostatic interactions. (author)

  15. Methodological development and characterization of welded joints in Poly (vinylidene fluoride) (PVDF); Desenvolvimento metodologico e caracterizacao de juntas soldadas de PVDF

    Energy Technology Data Exchange (ETDEWEB)

    Cedrola, S.M.L.; Costa, M.F. da; Pasqualino, I.P., E-mail: samanta@metalmat.ufrj.b [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil)

    2010-07-01

    Pipelines are of great concern in the transport sector of oil and gas industries, mainly due to the natural internal aging process caused by contact with the different transported fluids. Installation of polymeric pipes called liners is a good option for rehabilitation of long segments of deteriorated pipelines. Among the potential materials for such application is Poly (vinylidene fluoride) (PVDF). Meanwhile the installation process cannot be carried out in one single step and the polymeric pipe must be cut in sections that are welded during the installation process. In this research welding methodology was studied aiming to optimize welding conditions and the mechanical properties of the joined materials. The first step was processing the PVDF via compression molding on different conditions. Then, the sample was cut and butt-welded. Welding parameters such as, time control, temperature and contact pressure were studied. Afterwards, the stress-strain properties of the welded material was evaluated and physical characterization was carried by x-ray diffraction (DRX). (author)

  16. Structural analysis and magmatism characterization of the Major Gercino shear zone, Santa Catarina State, Brazil; Analise estrutural e caracterizacao do magmatismo da zona de cisalhamento Major Gercino, SC

    Energy Technology Data Exchange (ETDEWEB)

    Passarelli, Claudia Regina

    1996-12-31

    This work describes the geometric and kinematic characteristics of the Major Gercino Shear Zone (MGSZ) in the Canelinha-Garcia area. This shear zone is one of the major lineaments that affect all southern Brazilian precambrian terrains. In Santa Catarina State, it separates, along its whole extension, the supracrustal rocks of the Brusque belt (northern part) from the Granitoid belt (southern). This zone is characterized by a regional NE trend and a dextral sense of movement where ductile-brittle structures predominate. The MGSZ is composed of two mylonitic belts separated by granitoid rocks probably associated to the development of the shear zone. Both shear zones show cataclastic to ultra mylonitic rocks, but mylonites and protomylonites conditions at high strain rate. The calc-alkaline granitoids present in the area can be grouped in two granitoid associations with meta to peraluminous affinities. The Rolador Granitoid Association is characterized by grayish porphyritic biotite-monzogranites and the Fernandes Granitoid Association by coarsed-grained to porphyritic pinkish amphibole-syenogranites. The U-Pb and Rb-Sr ages range from 670 to 590 Ma with the Sr{sup 87} / Sr{sup 86} initial ratios suggesting a crustal contribution in the generation of these rocks. The importance of the pure shear component is also emphasized by the results of the Fry method. Many z axes of the strain ellipses are at high angle to the shear foliation. Symmetric porphyroclasts also corroborate this hypothesis. The micaceous minerals formed during the shear development indicate K-Ar ages around 555 {+-} 15 Ma. Brittle reactivations of the shear zone have been placed by K-Ar in fine-fraction materials at Triassic time (215 {+-} 15 Ma.) 220 refs., 107 figs., 18 tabs., 4 maps

  17. Multi-wire detector characterization for daily quality control on IMRT; Caracterizacao de um detector planar de multiplos fios para controle de qualidade diario de tratamentos com IMRT

    Energy Technology Data Exchange (ETDEWEB)

    Ferrari, Vilma A.; Watanabe, Erika Y.; Santos, Gabriela R.; Menegussi, Gisela, E-mail: vilmaferrari@uol.com.br [Instituto do Cancer do Estado de Sao Paulo (ICESP), SP (Brazil). Setor de Radioterapia

    2012-08-15

    Several dosimetry devices are being developed for quality control of radiation treatments using modern techniques as, for example, the Intensity Modulated Radiation Therapy (IMRT). The main function of these devices are to daily quality control of treatments of patients submitted to IMRT technique. The aim of this study is to characterize a type of planar multi-wire detector - DAVID (PTW) - for use in clinical practice. It was evaluated the influence of the system in the radiation beam by measuring the absorption factors and surface dose. We also analyzed the dose-linearity, reproducibility, the dependence with the dose rate and the angle of the linac head. Small errors in the position of the multi-leaf were inserted to evaluate the sensitivity of the system. The results showed that the detector can absorb up to 6.7% of the dose, depending of the energy beam and the field size. A significant increase in surface dose was observed, indicating that individual analysis is necessary for each patient. The system showed good reproducibility, linear response with dose, low dependence with dose rate and low dependence with the angle of the linac head. When small errors were inserted in the position of the multi-leaf, the system was able to detect them. Thus, the detector DAVID proved to be suitable for daily verification of IMRT treatments. (author)

  18. Characterization of a extrapolation chamber in standard X-ray beam, radiodiagnosis level; Caracterizacao de uma camara de extrapolacao em feixes padroes de raios X, nivel radiodiagnostico

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Eric A.B. da; Caldas, Linda V.E., E-mail: ebrito@usp.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-10-26

    The extrapolation chamber is a ionization chamber used for detection low energy radiation and can be used as an standard instrument for beta radiation beams. This type of ionization chamber have as main characteristic the variation of sensible volume. This paper performs a study of characterization of a PTW commercial extrapolation chamber, in the energy interval of the qualities of conventional radiodiagnostic

  19. Characterization and origin of the `3-Dedos` marker bed (Santonian) of the Campos Basin; Caracterizacao e origem do marco 3-Dedos (Santoniano) da Bacia de Campos

    Energy Technology Data Exchange (ETDEWEB)

    Caddah, Luiz F.G.; Hanashiro, Mauro [E and P BC, Macae, RJ (Brazil); Alves, Daisy B.; Mizusaki, Ana M.P. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    1994-04-01

    The 3-Dedos Marker bed, which appears in the Santonian pelitic section of the Ubatuba Formation in the SE of the Campos Basin, is characterized in electrical well-logs by three peaks of low resistivity and very high porosity. Each peak corresponds to a 1 to 2 m thick bed of greenish gray, high hygroscopy, homogeneous and nonbioturbated clay stone. These beds are separated by 5 to 10 m of intensely bioturbated shales and siltstones representing the usual marine sedimentation. Contrasting with these polymineralic pelitic rocks, the clay stones are almost exclusively composed of homogeneous, highly expandable and disordered dioctahedral illite/smectite mixed-layers. The high free water content of these minerals is responsible for the low resistivity values that were determined. The anomalous porosity corresponds to microporosity created by the random distribution of the minute crystals. The mode of occurrence of the clay stones suggests their origin from the deposition of trachytic volcanic ashes that are deeply altered. For these reasons, based on compositional and genetic criteria as well, such clay stones can be classified as bentonite. The `3-Dedos` Marker bed was originated by successive brief events and represents an ideal horizon for chrono stratigraphic correlation. It was possible to trace this marker over an extensive area of the Campos Basin that covers, up to the present, the Marimba and Pirauna oil fields, the area of the RJS-116 wildcat well, and part of the Enchova, Pampo and Bonito oil fields. (author). 9 figs., 3 tabs.

  20. Synthesis and characterization of activated carbon materials for natural gas storage; Sintese e caracterizacao de materiais carbonosos ativados para armazenamento de gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Coutinho, A.R.; Mendez, M.O.; Capobianco, G. [MULTIVACUO Industria e Comercio de Filtros Ltda., Campinas, SP (Brazil); Otani, C.; Petraconi, G.; Maciel, H.; Massi, M.; Urruchi, W. [Centro Tecnico Aeroespacial, Sao Jose dos Campos, SP (Brazil). Inst. Tecnologico de Aeronautica; Campos, F.B. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES); Campos, M.F.; Furin, R. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2004-07-01

    The activated carbon (AC) materials are characterized by a highly porous structure and high specific surface area, giving the capacity to adsorb molecules in liquid and gaseous phase. The present work has the objectives: project and construction of a pilot plant for production of 30 kg/month of AC; development of hybrid process of AC production using physical and/or chemical activation and cold plasma. The biomass raw materials are used, like pinnus wood and macadamia shell. The samples are prepared in form of grains or briquettes, and inserted in reactor inside of the furnace for the pre-activation process. This process is realized in temperatures of 600 deg C - 900 deg C, with heating rates of 1 deg C.min{sup -1} - 10 deg C.min{sup -1}, using different flow rate of inert gas (200 ml.min{sup -1} - 1000 ml.min{sup -1}); with two kinds of a activating agent: steam and CO{sub 2}. After the withdrawal of the samples of the reactor, the samples are submitted to the final process of activation, in oxidant plasma reactor, varying the following process parameters: pressure, gas flow rate, power and residence time. The chemical activation process consists of adding to the raw material the activating agents, as ZnCl{sub 2}, KOH, and others, in varied ratios. The AC had been characterized by: scanning electronic microscopy (SEM), specific surface area (SSA) by the BET and DR techniques. The preliminary results presents AC produced by the chemical activation with a SSA of 1700 m{sup 2}.g{sup -1} and pore volume of 0,8 cm{sup 3}.g{sup -1}, with average pore diameter of 2,0 nm and burn-off degree of 50%. The AC prepared by plasma process shown values of SSA up to 3200 m{sup 2}.g{sup -1}. (Project supported by Rede Gas Energia - PETROBRAS TC 540.4.049.03-0). (author)

  1. Characterization of different cassava samples by nuclear magnetic resonance spectroscopy; Caracterizacao de diferentes amostras de mandioca por espectroscopia de ressonancia magnetica nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Iulianelli, Gisele C.V.; Tavares, Maria I.B., E-mail: gisele@ima.ufrj.br [Centro de Tecnologia, Instituto de Macromoleculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ (Brazil)

    2011-07-01

    Cassava root (Manihot esculenta Crantz) is grown in all Brazilian states, being an important product in the diet of Brazilians. For many families of the North and Northeast states, it may represent the main energy source. The cassava root flour has high levels of starch, in addition to containing fiber, lipids and some minerals. There is, however, great genetic variability, which results in differentiation in its chemical composition and structural aspect. Motivated by the economic, nutritional and pharmacological importance of this product, this work is aimed at characterizing six cassava flour samples by NMR spectroscopy. The spectra revealed the main chemical groups. Furthermore, the results confirmed differences on chemical and structural aspect of the samples. For instance, the F1 sample is richer in carbohydrates, while the F4 sample has higher proportion of glycolipids, the F2 sample has higher amylose content and the F6 sample exhibits a greater diversity of glycolipid types. Regarding the molecular structure, the NMR spectra indicated that the F1 sample is more organized at the molecular level, while the F3 and F5 samples are similar in amorphicity and in the molecular packing. (author)

  2. Microstructural characterization of Ta-Si alloy as cast; Caracterizacao microestrutural de ligas Ta-Si no estado bruto de fusao

    Energy Technology Data Exchange (ETDEWEB)

    Silva, A.A.A.P. da; Coelho, G.C.; Nunes, C.A.; Suzuki, P.A.; Borges, S.P.T., E-mail: antonioaaps@gmail.co [Universidade de Sao Paulo (EEL/USP), Lorena, SP (Brazil). Escola de Engenharia; Faria, M.I.S.T. [Centro Universitario de Volta Redonda (UNIFOA), RJ (Brazil)

    2010-07-01

    Recent experimental studies developed in our group involving systems containing transition metals and silicon differed from the phase diagrams actually accepted. The objective of this study is to experimentally re-evaluate the invariant reactions involving liquid phase of the binary Ta-Si. Samples with different compositions were melted in arc furnace with non-consumable tungsten electrode in the copper crucible cooled water under argon atmosphere and titanium getter, using materials of high purity (minimum purity of 99.5% Ta and 99.999% Si). The samples were melted four times to ensure the microstructural and compositional homogeneity. The microstructures of the samples as cast were characterized by scanning electron microscopy (SEM/EDS) and X-ray diffraction (XRD). The results of this analysis led to a proposal for the phase diagram of Ta-Si slightly different than the diagram currently accepted. (author)

  3. Synthesis and characterization on titanium dioxide prepared by precipitation and hydrothermal treatment; Sintese e caracterizacao de dioxido de titanio preparado por precipitacao e tratamento hidrotermico

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Andre V.P. dos; Yoshito, Walter K.; Lazar, Dolores R.R.; Ussui, Valter, E-mail: vussui@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2012-07-01

    Surface properties of titanium dioxide (titania) are outstanding among ceramic materials and enables uses as catalysts, photoelectrochemical devices, solar cells and others. In many of these applications, it is necessary to keep the anatase phase, that is stable only in low temperatures (<400 deg C). In the present work, the influence of hydrothermal treatment on physical characteristics and crystal structure of titania powders synthesized by precipitation was investigated. Characterizations of obtained powders were carried out by X-ray diffraction, surface area analysis by N2 gas sorption (BET) and microstructure of powders and ceramics were analyzed by scanning electron microscopy. As prepared powders were formed as cylindrical pellets by uniaxial pressing and sintered at 1500 deg C for 01 hour. Results showed that anatase phase without formation of rutile phase can be formed in hydrothermally treated samples . Rutile phase is predominant in calcined and/or sintered samples (author)

  4. Synthesis and characterization of lead oxides for preparation of nanocomposites with polyamide; Sintese e caracterizacao de oxido de chumbo para preparacao de nanocompositos com poliamida

    Energy Technology Data Exchange (ETDEWEB)

    Cado, Ronan Gorski; Severo, Vinicius A.; Bulhores, Luis Otavio S. [Centro Universitario Franciscano, Santa Maria, RS (Brazil). Programa de Pos-Graduacao em Nanociencias. Lab. de Desenvolvimento de Materiais Nanoestruturados

    2016-07-01

    Lead oxide nanoparticles with diameters between 100 to 250 nm were obtained using a polymeric precursor method in the presence of citric acid and ethylene glycol. X-ray diffraction (XRD) and dynamic light scattering to measure the size and zeta potential in solution in dispersions with different pH were used to characterize the as-obtained samples. The nanoparticles were incorporated into polyamide 6.6 and composite films were prepared by electrospinning being evaluated the variation of the mechanical properties of the polymer and its effectiveness in attenuation of X-rays. (author)

  5. Production and characterization of setting hydraulic cements based on calcium phosphate; Obtencao e caracterizacao de cimentos de fosfato de calcio de pega hidraulica

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Luci C. de; Rigo, Eliana C.S.; Santos, Luis A dos; Boschi, Anselmo Ortega [Sao Carlos Univ., SP (Brazil). Dept. de Engenharia de Materiais; Carrodeguas, Raul G. [Universidad de La Habana, Habana (Cuba). Centro de Biomateriales

    1997-12-31

    Setting hydraulic cements based on calcium phosphate has risen great interest in scientific literature during recent years due to their total bio compatibility and to the fact that they harden `in situ`, providing easy handling and adaptation to the shape and dimensions of the defect which requires correction, differently from the predecessors, the calcium phosphate ceramics (Hydroxy apatite, {beta}-tri calcium phosphate, biphasic, etc) in the shape of dense or porous blocks and grains. In the work, three calcium-phosphate cement compositions were studied. The resulting compositions were characterized according to the following aspects: setting times, pH, mechanical resistance, crystalline phases, microstructure and solubility in SBF (Simulated Body Fluid). The results show a potential use for the compositions. (author) 6 figs., 4 tabs.

  6. Antimicrobial compounds in polyethylene films - characterization and content measurement techniques;Compostos antimicrobianos em filme de polietileno - tecnicas de caracterizacao e quantificacao

    Energy Technology Data Exchange (ETDEWEB)

    Pires, Marcia; Santos, Ramon V.; Perao, Leandro; Ellwangler, Manoela W.; Nonemacher, Regina F.; Moraes, Lilian T. de; Gorski, Sandro; Staub, Simone, E-mail: marcia.pires@braskem.com.b [Braskem S.A., Triunfo, RS (Brazil). III Polo Petroquimico. Centro de Tecnologia e Inovacao; Petzhold, Cesar L. [Universidade Federal do Rio Grande do Sul (PGCIMAT/UFRGS), Porto Alegre, RS (Brazil). Pos-Graduacao em Ciencia dos Materiais

    2009-07-01

    Developments have been done in the packaging market to attend the continuous changes in consumer demands and also to keep safety and shelf life of products during transportation and storage. Active packaging is the most innovative concepts in the market. It has been defined as a packaging that changes its conditions to extend shelf life. The objective of this work is the production and characterization of active polyethylene films with antimicrobial compounds. The initial results show that analytical techniques as RX fluorescence and FTIR can be used to characterize and quantify these compounds in polyethylene films. (author)

  7. Synthesis and characterization of nanocomposite powders of calcium phosphate/silica-gel; Sintese e caracterizacao de pos nanoestruturados de fosfato de calcio/silica-gel

    Energy Technology Data Exchange (ETDEWEB)

    Muller, D.T.; Delima, S.A. [Universidade do Estado de Santa Catarina (UDESC), Joinville, SC (Brazil). Dept. de Engenharia Mecanica; Santos, R.B.M.; Camargo, N.H.A., E-mail: dem2nhac@joinville.udesc.b [Universidade do Estado de Santa Catarina (UDESC), Joinville, SC (Brazil). Programa de Pos Graduacao em Ciencia e Engenharia de Materiais

    2009-07-01

    In the recent years ceramics of calcium phosphate are pointed out as an outstanding material in substitution and regeneration in defects from osseous tissue, in reason of their similar mineralogical characteristics of apatite of bone structure. However, the challenge with phosphate calcium ceramics find out about the mechanical properties and the development of biomaterials similar of the bone structure, what sometimes is not so easy, about fragile materials. The aim of this work focused in synthesis and characterization nanocomposites powders of calcium phosphate/silica-gel with percentages 1, 2, 3 e 5% of nanometric silica. The method synthesis used for the compositions elaboration was dissolution-precipitation. The presented results are related with the optimization to method elaboration of nanostructured powders, the mineralogical characterization with X-ray diffraction, thermal behavior with thermal differential analysis, differential scanning calorimetry here is ADT and dilatometer. The scanning electronic microscopy was used to help of morphological characterization the nanostructured powders and the surfaces from body test recovered from the mechanical test. (author)

  8. Physical Characterization Of High Amylose/Pectin Mixtures Cross-Linked With Sodium Trimetaphosphate; Caracterizacao fisica de misturas alta amilose/pectina reticuladas com trimetafosfato de sodio

    Energy Technology Data Exchange (ETDEWEB)

    Carbinatto, F.M.; Cury, B.S.F.; Evangelista, R.C., E-mail: curybsf@fcfar.unesp.b [UNESP, Araraquara, SP (Brazil). Fac. de Ciencias Farmaceuticas

    2010-07-01

    Some researches have reported that pectin and high amylose mixtures presented superior mechanical properties in relation to those of the isolated polymers. In this work, mixtures at different ratios (1:4; 1:1) of pectin and high amylose were crosslinked with sodium trimetaphosphate at different degrees by varying reaction conditions. All samples were characterized by rheological and X-ray diffraction analyses. Samples without cross-linker were prepared as control. The oscillatory dynamic tests showed that all samples exhibited predominant elastic behavior, although cross-linked samples presented higher G' values, suggesting that crosslinking by phosphorylation resulted in more strength structures. The diffractograms showed that cross-linked samples underwent structural modifications that resulted in increase of crystallinity due to cross-linking process. (author)

  9. Synthesis and characterization of zeolite from coal ashes modified by cationic surfactant; Sintese e caracterizacao de zeolita de cinzas de carvao modificada por surfactante cationico

    Energy Technology Data Exchange (ETDEWEB)

    Fungaro, D.A.; Borrely, S.I., E-mail: dfungaro@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2012-01-15

    Zeolite synthesized from coal fly ash was modified with different concentrations (2 and 20 mmol.L{sup -1}) of hexadecyltrimethylammonium bromide (HDTMA-Br). The Non-Modified Zeolite (NMZ) and Surfactant-Modified Zeolites (SMZ) were characterized by X-ray fluorescence spectrometry, X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy, thermogravimetric analysis, among others. The SMS presented negative charge probably due to the formation of a partial bilayer of HDTMA on exchangeable active sites on the external surface of NMZ. A decrease in surface area was observed for SMZ as compared to NMZ indicating zeolite surface coverage with HDTMA-Br molecules. The crystalline nature of the zeolite remained intact after adsorption of surfactant and heating for drying. FTIR analysis indicated that there were no significant changes in the structure of the zeolite after adsorption of surfactant. (author)

  10. Characterization of Sr{sub 2}Fe{sub 2}O{sub 5} ferrite; Processamento e caracterizacao de hexaferrita de estroncio

    Energy Technology Data Exchange (ETDEWEB)

    Monteiro Filho, F.; Rocha, W.A.; Correa, R.R. [Centro Federal de Educaco Tecnologica do Maranhao (CEFET-MA), Sao Luis, MA (Brazil). Programa de Pos-Graduacao em Engenharia de Materiais; Almeida, R.M.; Paschoal, C.W.A. [Universidade Federal do Maranhao (UFMA), Sao Luis, MA (Brazil). Dept. de Fisica

    2009-07-01

    In the present work, the Sr{sub 2}Fe{sub 2}O{sub 5} ferrite was obtained by the high energy milling technique using a milling power of 4:1 under different times (1, 5 and 10h). The product was calcined, grounded for the particles size reduction and sintered at temperatures of 1100, 1200 and 1300 deg C. Further, x-ray diffraction and scanning electron microscopy experiments were carried out in order to identify the phases and analyze the particles morphology, respectively. DC electrical conductivity measurements indicated that the strontium ferrite behaves as a semiconductor. At low temperatures, the bands conduction mechanism predominated; while the load carrier mobility diminished at high temperatures. The electrical conductivity of the strontium ferrite samples changed from 15.2 to 85({Omega}cm){sup -1}, and its resistivity assumed values between 0.012 to 0.066({Omega}cm). (author)

  11. Obtaining and characterization of films of stereo complexes PLLA-PDLA; Obtencao e caracterizacao de filmes de estereocomplexos de PLLA-PDLA

    Energy Technology Data Exchange (ETDEWEB)

    Goncalves, R.P.; Dias, M.L.; Picciani, P.H.S., E-mail: raquelpires@ima.ufrj.b [Universidade Federal do Rio de Janeiro (IMA/UFRJ), RJ (Brazil). Inst. de Macromoleculas Professora Eloisa Mano

    2010-07-01

    Polilactides stereorregulars as poly (L-lactide) (PLLA) has wide application in biomedical and packaging, but despite the structure regular, have relatively low crystallization rate, which limits some applications. The formation of stereocomplexes the mixture of PLLA with poly (D-lactide) (PDLA) has been a strategy used to modify the crystalline structure of these materials, which has an important role in controlling its degradation. In this work we prepared films of PLLA and PDLA alone and their mixtures, aiming to produce stereocomplexes. The PLLA and PDLA were synthesized using different catalysts: tin octoate and calcium methoxide, to investigate the effect of microstructure of polymers in the formation of stereocomplex. The films were obtained by pressing at different temperatures. The materials were characterized by X-ray diffraction and GPC. The results indicate that stereocomplexes with different characteristics are obtained when synthesized with two types of catalysts. (author)

  12. Characteristics of the radiochromic film Gafchromictm EBT3 model for use in brachytherapy; Caracterizacao do filme radiocromico Gafchromictm modelo EBT3 para uso em braquiterapia

    Energy Technology Data Exchange (ETDEWEB)

    Luvizotto, Jessica

    2015-07-01

    Brachytherapy is a radiotherapy treatment modality using radioactive sealed sources within walking distance of the tumor, reducing the risk of applying an unwanted dose to adjacent healthy tissues. For brachytherapy is reliable, it is necessary to establish a dosimetric practices program aimed at determining the optimal dose of radiation for this radiotherapy practice. This paper presents the application of two methodologies for the dosimetry using radiochromic films. Experimental measurements were performed with EBT3 films in phantoms consisting of homogeneous and heterogeneous material (lung, bone and soft tissue) built especially for dose measurements in brachytherapy. The processing and analysis of the resulting images of the experimental procedure were performed with ImageJ software and MATLAB. The results were evaluated from comparisons dose of experimental measurements and simulations obtained by the Monte Carlo method. (author)

  13. Physical-chemistry characterization of oil and biodiesel from Crambe abyssinica Hochst; Caracterizacao fisico-quimica do oleo e do biodiesel de DE Crambe abyssinica Hochst

    Energy Technology Data Exchange (ETDEWEB)

    Jasper, Samir Paulo; Biaggioni, Marco Antonio Martin; Silva, Paulo Roberto Arbex; Seki, Andre Satoshi; Saath, Reni [Universidade Estadual Paulista (FCA/UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas], E-mail: jasper@fca.unesp.br

    2010-07-01

    Currently, the production of biodiesel in the world is growing so rapidly, this interest and demand for biodiesel promote an increase in demand for raw materials, or lipids. Biodiesel is a substitute for diesel oil obtained by transesterification, acid or base, of the lipids present in oils and fats. The Crambe abyssinica Hochst is species plant that has attracted interest of Brazilian producers due to oil content, rusticity and mechanized cultivation, mainly as a crop of winter it becomes an option for most farmers in this period. This study aimed to characterize physical-chemical oil and biodiesel from Crambe abyssinica Hochst, in accordance with Resolution n. 42 of the ANP. The analysis of fatty acids of oil crambe showed high concentration of unsaturated fatty acids, which may not be suitable for the use of biodiesel in very cold regions, where it is used pure or in mixtures with diesel in large proportions. The biodiesel produced from Crambe abyssinica Hochst be revealed within the standards established by the National Agency of Petroleum, Natural Gas and Biofuels. (author)

  14. Synthesis and characterization of zeolite material from coal ashes modified by surfactant; Sintese e caracterizacao de material zeolitico de cinzas de carvao modificado por surfactante

    Energy Technology Data Exchange (ETDEWEB)

    Fungaro, D.A., E-mail: dfungaro@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (CQMA/IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro de Quimica e Meio Ambiente; Borrely, S.I. [Instituto de Pesquisas Energeticas e Nucleares (CTR/IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro de Tecnologia das Radiacoes

    2010-07-01

    Coal ash was used as starting material for zeolite synthesis by means of hydrothermal treatment. The surfactant-modified zeolite (SMZ) was prepared by adsorbing the cationic surfactant hexadecyltrimethylammonium bromide (HDTMA-Br) on the external surface of the zeolite from coal ash. The zeolite structure stability was monitored during the characterization of the materials by FTIR, XDR and SEM. The structural parameters of surfactant-modified zeolite are very close to that of corresponding non-modified zeolite which indicates that the crystalline nature of the zeolite remained intact after required chemical treatment with HDTMA-Br molecules and heating treatment for drying. The most intense peaks in the FTIR spectrum of HDTMA-Br were observed in SMZ spectrum confirming adsorption of surfactant on zeolites. (author)

  15. Esterification and characterization of lignin aiming the synthesis of polymeric composite; Esterificacao e caracterizacao da lignina visando a sintese de compositos polimericos

    Energy Technology Data Exchange (ETDEWEB)

    Victor, Priscilla A.; Machado, Fabricio, E-mail: fmachado@unb.br [Universidade de Brasilia (UnB), DF (Brazil). Instituto de Quimica; Goncalves, Silvia B., E-mail: silvia.belem@embrapa.br [Embrapa Agroenergia, Parque Estacao Biologica (PqEB), Brasilia, DF (Brazil)

    2013-07-01

    Lignin is a natural polymer derived from lignocellulosic materials with high availability, presenting a huge potential for production of new materials. Due to its complex macromolecular structure, and its low compatibility with styrene, eucalyptus wood-extracted lignin method was esterified with methacrylic anhydride - exhibiting a yield of 64% - in order to ensure homogeneity in the organic phase into the reaction medium. The evaluation of both the natural and esterified lignin through infrared (IR) spectroscopy showed a decrease of the hydroxyl band, characteristic of natural lignin (3200-3400 cm{sup -1}) and an increase of the characteristic ester band (1720 to 1740 cm{sup -1}). According to nuclear magnetic resonance ({sup 1}H NMR) analysis on esterified lignin, intense peaks were observed in the range from 1.7 to 2.05 ppm (-CH{sub 3}) and 5.4 ppm to 6.2 ppm (=CH{sub 2}), related to methacrylic anhydride. According to the thermogravimetric analysis (TGA), the esterified lignin showed a decrease in its thermal stability when compared to natural lignin, exhibiting two main weight losses between 200 °C and 300 °C and in the interval from 550 °C to 800 °C. Comparatively, the esterified lignin also displayed an increase in its glass transition temperature (Tg = 98 °C) for, when compared to natural lignin, whose Tg value was determined to be equal to 91 °C. (author)

  16. Preparation and characterization of polyhedral oligomer silsesquioxane nanocomposites incorporated in epoxy resin; Elaboracao e caracterizacao de nanocompositos de oligomero poliedrico de silsesquioxano incorporados na resina epoxidica

    Energy Technology Data Exchange (ETDEWEB)

    Longhi, Marielen; Zini, Lucas Pandolphi; Birriel, Eliena Jonko; Kunst, Sandra Raquel; Zattera, Ademir Jose, E-mail: marielen_longhi@hotmail.com [Universidade de Caxias do Sul (LPOL/UCS), RS (Brazil). Laboratorio de Polimeros; Pistor, Vinicius [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil)

    2013-07-01

    The incorporation of nanofiller in thermosetting like epoxy resin as has been studied in order to modify its properties. In this research, nanocomposites were obtained by incorporating 5% by weight of three polyhedral oligomeric silsesquioxane (POSS) with different number of functionalization: Glicidilisobutil-POSS, Triglicidilisobutil- POSS and Glicicil POSS in an epoxy matrix by sonification process. The nanocomposites were characterized by analysis of X-ray diffraction (DRX), transmission electron microscopy (TEM) and thermogravimetric analysis (TGA). The DRX analysis showed the characteristic peak of POSS and TEM images showed that there is a difference in the dispersion of nanocages for the difference in the number of epoxy groups on the POSS. The incorporation of Glicidilisobutil-POSS showed a significant increase in the glass transition temperature (Tg) value, and also that the most effective from the viewpoint of the dispersion, on the other hand, the Glycidyl-POSS had a greater influence on the thermal stability demonstrating that the dispersion medium is an important characteristic to define the most desirable properties. (author)

  17. Characterization of taquara-lixa (Merostachys skvortzovii Sendulsky) fibers for use in polymer composites; Caracterizacao de fibras de taquara-lixa (Merostachys skvortzovii Sendulsky) utilizaveis em compositos polimericos

    Energy Technology Data Exchange (ETDEWEB)

    Borges Neto, Camilo; Flores-Sahagun, Thais H.S.; Andrade, Alan S. de; Mazzaro, Irineu, E-mail: cyborg@ufpr.br [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil)

    2013-07-01

    Characterization of untreated or alkali-treated 'taquara-lixa' (Merostachys skvortzovii Sendulsky ), a low cost Brazilian bamboo fiber, was performed by determining their chemical composition (moisture, ash, lignin and extractives contents), solubility in hot or cold water, pH values and crystallinity index. Thermal analysis showed that fibers begin to degrade at 250 deg C. Samples of taquara-lixa/epoxy resin composites were prepared with 56% w/w aligned long fibers (280 mm) and with 54% (w/w) dispersed short fibers (25 mm) and a sandwich-beam sample shaped in three layers was prepared with two outer long fiber composite layers separated by a thicker layer of the short fiber material. Composites were characterized by x-ray diffraction patterns, water and moisture absorption and flexural tests. Elasticity and shear modulus of composites (15500 MPa and 932 MPa/6800 MPa and 1042 MPa for long and short composites, respectively) indicated that these materials can be used for structural applications, with the advantage of low water (8.4%) and low moisture (2.4-2.8%) absorption. (author)

  18. Extraction and characterization of galactomannan extracted from Prosopis juliflora seeds; Extracao e caracterizacao de galactomanana extraida a partir de sementes de Prosopis juliflora

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Delane da C.; Cunha, Arcelina P.; Oliveira, Williara Q. de; Gallao, Maria Izabel, E-mail: izagalao@gmail.com [Rede Nordeste de Biotecnologia (RENORBIO), Fortaleza, CE (Brazil). Centro de Ciencia; Azeredo, Henriette M.C. de [EMBRAPA Agroindustria Tropical, Fortaleza, CE (Brazil)

    2013-07-01

    Different seeds are rich in polysaccharides, which are widely used in research and in industry. The objective was to extract galactomannan from mesquite seeds (Prosopis juliflora) and evaluate their chemical properties for future application in edible films. To test the feasibility of using the polysaccharide, the yield was obtained and the material analyzed by Thermal Analysis (TGA-Thermogravimetric Analysis and Calorimetry Differential Scanning-DSC), Spectroscopy Infrared Region Fourier Transform (FTIR) and Nuclear Magnetic Resonance (NMR). According to the results, the galactomannan was equivalent with the polysaccharides extracted from other sources except for the low yield (6.6%). (author)

  19. Characterization of polyurethane based on polyol synthesized from glycerol and hexamethylene diisocyanate;Caracterizacao de poliuretano baseado em poliol sintetizado a partir de glicerol e hexametileno diisocianato

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Sabrina M.; Weber, Vanessa; Silva, Tailu N.; Barreto, Pedro L.M., E-mail: barreto@cca.ufsc.b [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC(Brazil). Dept. de Ciencia e Tecnologia de Alimentos. Lab. de Reologia e Polimeros Naturais

    2009-07-01

    A new polyol based on glycerol was synthesized and used in the production of polyurethane by reaction with hexamethylene diisocyanate. The polyol was characterized by nuclear magnetic resonance spectroscopy (NMR) and Fourier transform-infrared spectroscopy (FTIR). The polyurethane produced was characterized by FTIR, thermogravimetry (TG), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The polyol was shown to be reactive with hexamethylene diisocyanate, as the FTIR spectrum showed no free isocyanate groups and identified the presence of group -C=O of urethane groups. Analysis by DSC showed that the sample of polyurethane has a glass transition temperature around -8.53 deg C and SEM micrographs showed fracture and surface continuous and not broken. The thermogravimetric analysis showed that the polyurethane produced has a high thermal stability with a temperature of maximum degradation around 430 deg C. (author)

  20. Methodology for characterization of corrosive agents of thermal insulating foams; Desenvolvimento de metodologia para caracterizacao de agentes corrosivos de espumas de isolamento termico

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, Flavio V. Vasques de [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Fundacao Coordenacao de Projetos, Pesquisas e Estudos Tecnologicos - COPPETEC; Mattos, Oscar R.; Mota, Rafael O. da [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Programa de Engenharia Metalurgica e de Materiais; Margarit-Mattos, Isabel C.P. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Escola de Quimica. Dept. de Processos Organicos; Quintela, Joaquim P. [PETROBRAS, Rio de Janeiro, RJ (Brazil); Vieira, Magda M. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    2005-07-01

    Warming up oil and derivatives is a required procedure to make their transportation more efficient due to the increase in fluidity. Therefore, the use of thermally insulated pipeline becomes essential. The commonly practice has been the use of pipelines covered with an optional anticorrosive coating, followed by a polyurethane foam layer, as thermal insulator, and a polyethylene top coating for mechanical protection. During the life time of the pipeline, local ruptures of the polyethylene coating frequently occur, allowing the water permeation throughout the thermal insulator. This water may cause foam leaching that would release corrosive agents on the external wall pipe. The objective of the present work was to investigate the effects of the blowing agents, the addition of flame retardant to the foam as well as operating temperatures on the generation of corrosive solutions on the external wall of thermally insulated pipes. In this sense, polyurethane foams expanded with HCFC-141b, CFC-11 and CO{sub 2}, with and without flame retardant, were evaluated at the temperatures of 80 and 120 deg C. (author)

  1. Biochemical and pharmacological characterization of irradiated crotamine by gamma rays of {sup 60}Co; Caracterizacao bioquimica e farmacologica da crotamina irradiada por raios gama de {sup 60}Co

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Karina Corleto

    2014-07-01

    The serum production in Brazil, the only effective treatment in cases of snakebites, uses horses that although large size, have reduced l lifespan compared with horses not immunized. Ionizing radiation has been shown as an excellent tool in reducing the toxicity of venoms and toxins isolated, and promote the achievement of better immunogens for serum production, and contributing to the welfare of serum-producing animals. It is known, however, that the effects of ionizing radiation on protein are characterized by various chemical modifications, such as fragmentation, cross-linking due to aggregation and oxidation products generated by water radiolysis. However, the action of gamma radiation on toxins is not yet fully understood structurally and pharmacologically, a fact that prevents the application of this methodology in the serum production process. So we proposed in this paper the characterization of crotamine, an important protein from the venom of Crotalus durissus terrificus species, irradiated with {sup 60}Co gamma rays. After isolating the toxin by chromatographic techniques and testing to prove the obtaining of pure crotamine, it was irradiated with gamma rays and subjected to structural analysis, Fluorescence and Circular Dichroism. Using high hydrostatic pressure tests were also conducted in order to verify that the conformational changes caused by radiation suffer modifications under high pressures. From the pharmacological point of view, muscle contraction tests were conducted with the objective of limiting the action of crotamine in smooth muscle as well as the change in the action of toxin caused structural changes to the front. Analysis of Circular Dichroism and Fluorescence showed changes in structural conformation of crotamine when subjected to gamma radiation and that such changes possibly occurring in the secondary and tertiary structure of the protein. The observed in pharmacological tests showed that the irradiated crotamine was less effective in lowering the vas deferens twitch in rats in comparison to native crotamine. In addition, the behavior of irradiated toxin in tonic contraction, modulated by noradrenaline, was different from that observed for the native toxin. (author)

  2. Synthesis and characterization of semi-IPNs based on PVP and PLLA; Sintese e caracterizacao de semi-IPNs envolvendo os homopolimeros PVP e PLLA

    Energy Technology Data Exchange (ETDEWEB)

    Camilo, A.P.R.; Mano, V., E-mail: mano@ufsj.edu.b [Universidade Federal de Sao Joao del Rei (UFSJ), MG (Brazil). Dept. de Ciencias Naturais; Felisberti, M.I. [Universidade Estadual de Campinas (IQ/UNICAMP), SP (Brazil). Inst. de Quimica

    2010-07-01

    The specific interest in the synthesis of semi-IPNs based on PLLA and PVP homopolymers due to the fact these are biodegradable and biocompatible, which allows us to infer applications in the medical field as sutures, implants, matrices for controlled release of drugs etc. The objective was to prepare a multicomponent material amphiphile in the form of semi-interpenetrating polymer networks, based on poly (L-lactide), PLLA, hydrophobic homopolymer, and poly (vinylpyrrolidone), PVP, hydrophilic component. The preparation of semi-IPN combined the polymerization and crosslinking of N-vinylpyrrolidone in the presence of poly (L-lactide). The products were characterized by spectroscopic and thermal methods. (author)

  3. Disease: H01244 [KEGG MEDICUS

    Lifescience Database Archive (English)

    Full Text Available H01244 T+B+Severe combined immunodeficiencies (SCIDs) Recently, several groups reported a novel clinica...nsion of TCR-gamma/delta T cells combined with TCR-alpha/beta T cell lymphopenia. The clinica

  4. Early Treatment of Shock and Injury

    Science.gov (United States)

    2013-10-01

    Resuscitation from Shock. FELANPE, Federation Latinoamericana de Terapia Nutricional, Nutrition Clinica, y Metabolisma. October 5, 2011. (Asuncion...Resuscitation from Shock. FELANPE, Federation Latinoamericana de Terapia Nutricional, Nutrition Clinica, y Metabolisma. October 5, 2011

  5. Splenic marginal zone lymphoma with Evans' syndrome, autoimmunity, and peripheral gamma/delta T cells

    OpenAIRE

    2008-01-01

    Splenic marginal zone lymphoma with Evans? syndrome, autoimmunity, and peripheral gamma/delta T cells (Garcia-Mu?oz, Ricardo) Hematology Service, Clinica Universitaria, University of Navarra - Pamplona - SPAIN (Garcia-Mu?oz, Ricardo) Hematology Service, Clinica Universitaria, University of Navarra - Pamplona - SPAIN (Rodriguez-Otero, Paula) Hematology Service, Clinica Universitaria, University of Navarra - Pamplona - SPAIN (Pegenaute, Carlota) Department of...

  6. Estudio retrospectivo de las afecciones obstructivas de las vias aereas superiores en equinos adultos presentados a la clinica para grandes animales de la universidad nacional de colombia entre 1993 y 2007

    OpenAIRE

    Martínez, D. A.; Oliver, O. J.

    2012-01-01

    Un total de 44 historias de animales admitidos en la Clínica para Grandes Animales de la Universidad Nacional de Colombia fueron analizadas, para determinar cuales fueron las entidades más prevalentes en el tracto respiratorio superior (cavidad nasal, faringe y laringe) de estos equinos. Se determinó que el desplazamiento dorsal del paladar blando, la hemiplejia laríngea, la hiperplasia faríngea linfoide y las neoplasias fueron las mas prevalentes con 38.64%, 34.09%, 18.18% y 9.09% respectiva...

  7. Influence of the curve density relative electron in dosimetry clinic in treatments stereo tactics; Influencia de la curva de densidad electronica relativa en la dosimetria clinica en tratamientos estereotaxicos

    Energy Technology Data Exchange (ETDEWEB)

    Moreno Saiz, C.; Benitez Villegas, E. M.; Casado Villalon, F. J.; Parra Osorio, V.; Bodineau Gil, C.; Garcia Pareja, S.

    2013-07-01

    The objective of this study is to analyze the difference between clinical dosimetry in the treatments with radiosurgery and stereotactic radiotherapy fractional obtained from the relative Electron density curve (Schneider 1996) tabulated and provided with the scanner's radiation therapy. (Author)

  8. Percepción de los usuarios de la clinica Roque Armando López (RAL) respecto a la prestación de los servicios de saud y atención brindada en el servicio de consulta externa

    OpenAIRE

    Gómez Chamorro, Lina María; Gómez García, Elizabeth; López Vargas, Jhoan Manuel

    2015-01-01

    Tesis(Especialista en Administración de la Salud). Universidad Católica de Manizales. Facultad de salud, 2015 Con frecuencia se escucha hablar de satisfacción del usuario al recibir servicios de salud, dado que es un punto importante que determina que los clientes externos deseen y busquen recibir servicios de salud en nuestras instituciones; por lo tanto con este trabajo se buscó determinar el grado de satisfacción del usuario atendido en la Clínica Roque Armando López, estableciendo la...

  9. Ventilatory-perfusory pulmonary scintigraphy as non invasive election procedure in patients with clinical suspicion of pulmonary thrombo emboli; Centelleografia pulmonar ventilatoria-perfusoria, como procedimiento no invasivo de eleccion en pacientes con sospecha clinica de tromboembolia pulmonar

    Energy Technology Data Exchange (ETDEWEB)

    Altamirano L, J

    2004-07-01

    30 patients were studied with suspicion of pulmonary thrombo emboli PTE, in a period of 9 months (January-September of 1992), 20 women and 10 men, with an age range of 26 to 88 years, average of 57.59 18.89. With respect to the clinical data, 24 presented breathing inadequacy (80%). 16 tachycardia (54%), 15 with thoracic pain (50%) and 4 with hemoptysis (13%). Of the cabinet studies, 12 presented electrocardiographic changes (IF, QIII, and TIII) (40%), 14 presented abnormalities in arterial gases. In the thorax tele, 8 presented abnormality; as spill, pneumonia, diaphragmatic elevation, etc. (26.6%) and of 14 the result was not reported (46 6%). They were carried out in all the patients, the ventilatory studies and perfusories in that order. A Siemens mark scintillation camera was used, with a collimator of low energy and of high resolution; the information was stored in a floppy disk, and later on they were printed in radiographic plaques of high resolution. The ventilatory study was carried out with 30 mCi of {sup 99m} Tc-DTPA, in radio aerosol form, emitted by a micro nebulizer, to which was applied a pressure of oxygen of 10 ml-min; during 10 to 15 minutes. They took projections antero, posterior, oblique antero left and right, oblique posterior left and right, each one with an acquisition of 150000 counts, or during 5 minutes. Later on and remaining the patient in supine position, was carried out the perfusory study, applying 3-4 mCi of {sup 99} Tc-MAA for endo venous via; they took the same projections that the ventilatory study, but with a density of information greater (500 000 counts each one). Both studies are printed in a radiographic plaque of high resolution, with which is interpreted and the study is filed. (Author)

  10. Clinic implementation of method Zacarias for the correction of errors of convergence of optimization of IMRT in lung; Implementacion clinica del metodo Zacarias para la correccion de errores de convergencia de optimizacion en la IMRT en pulmon

    Energy Technology Data Exchange (ETDEWEB)

    Pardo Perez, E.; Molina Lopez, M. Y.; Ruiz Maqueda, S.; Castro Novais, J.; Counago Lorenzo, F.

    2013-07-01

    The implemented procedure is acceptable per a unit of radiophysic since it does not increase planning time in more than 30 - 45 minutes. Plans thus obtained show an improvement in dosimetric parameters for a small increase in the complexity of the plan, without appreciable increase risk organ doses. (Author)

  11. Octavius 4D: Initial state of reference and clinical implementation of a new equipment for checks VMAT; Octavius 4D: Estado de referencia inicial e implementacion clinica de un nuevo equipamiento para verificaciones VMAT

    Energy Technology Data Exchange (ETDEWEB)

    Eno Olmos, J.; Carmona Mesequer, V.; Lliso Vlaverde, F.; Garcia Martinez, M. t.; Pujades Claumarchiran, M. C.; Palomo Llinares, R.; Ballester Pallares, F.; Perez-Calatayud, J.

    2013-07-01

    The objective of this work is the establishment of the State of initial reference of a new system of measurement with the above capabilities, as well as the evaluation of its use in clinical routine. (Author)

  12. Method for calibration of asymmetric jaws in hemi fields techniques and effects in clinical practice; Metodo para la calibracion de las mandibulas asimetricas en tecnicas de hemicampos y efectos en la practica clinica

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez Masgrau, V.; Sempau Roma, J.; Abella Cereigido, R.; Lopez Sanchez, M.; Perez Fernandez, M.; Gonzalez Leyba, M.; Artigues Pedrola, M.

    2013-07-01

    This paper presents a method improved very significantly the accuracy of calibration, providing a good homogeneity of the dose distribution in the area of union of fields. Also evaluates the effect that has this new calibration in clinical practice. (Author)

  13. Use of clinical practice as a motivating tool of radioprotection teaching and radiopharmacology in early semesters of pharmacy course; Uso da pratica clinica como ferramenta motivadora de ensino de radioprotecao e radiofarmacologia em semestres iniciais em cursos de farmacia

    Energy Technology Data Exchange (ETDEWEB)

    Andrighetto, Daniela; Lüdke, Everton, E-mail: daniela.andrighetto@hotmail.com, E-mail: evertonludke@gmail.com [Universidade Federal de Santa Maria (CCNE/DEFIS/UFSM), RS (Brazil). Departamento de Fisica

    2014-07-01

    The research teaching methods aimed at the success of the higher education student in pharmacology and medicine courses in technical expertise in the fields of radiological protection, radiopharmacology and interventional radiology is extremely important in view of the progress of these sectors. The objective of this work is to propose a methodological sequence of teaching work with first-year students of pharmacy and medicine courses within a biophysical discipline where the integrated knowledge to clinical practice can be used for this purpose. The methodology was to assess individual learning of a group of N = 49 students of the first half in the age group of 17-19 years through conceptual acquisition by the traditional method of 'blackboard and chalk' and developed method that includes four pedagogical moments focused on the area health. An analysis of the evaluation student performance through Variance Analysis of a pathway showed improved scores with respect to the performance of application issues of knowledge concerning radiation protection and biological mechanisms of radiation with respect to the method of 'blackboard and chalk' with p < 0.05. Therefore, work with students with respect to the content in the form of six steps of clinical interest are a promising technique for radiation protection education in the early grades of college courses with experimental effectiveness.

  14. Dosimetry characterization and clinical application of Exa skin: Bolus of high of high density for use with photons; Caracterizacion dosimetrica y aplicacion clinica de Exaskin: bolus de alta densidad para uso con fotones

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz Seidel, M.; Velazquez Miranda, S.

    2013-07-01

    Bolus of high density eXaSkin of density 1.6 g/cm{sub 3} is calculated correctly in the planning systems, is easy to use and generates optimum coupling with the radiation area, at the same time which is easily reproducible in their placement, avoiding the use of electron beams. On the other hand its behavior varies very slightly with the presence of air gaps. (Author)

  15. Clinical characterization of OSL dosimeters for use in dosimetry of teletherapy beams in conventional fractionation; Caracterizacion clinica de dosimetros OSL para su uso en dosimetria de haces de teleterapia en fraccionamiento convencional

    Energy Technology Data Exchange (ETDEWEB)

    Lopez V, A.; Gutierrez M, J. G.; Rivera M, T. [IPN, Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada, Av. Legaria No. 694, Col. Irrigacion, 11500 Mexico D. F. (Mexico); Velazquez T, J. J., E-mail: jggm25@yahoo.com.mx [Centro Medico Nacional Siglo XXI, Hospital de Oncologia, Departamento de Fisica Medica, Av. Cuauhtemoc No. 330, Col. Doctores, 06720 Mexico D. F. (Mexico)

    2015-10-15

    Optically stimulated materials are increasingly used for dosimetry in clinical settings; to be sure of the obtained reading their proper clinical characterization is necessary. Is important to know the homogeneity of a batch, reproducibility, be exposed to the same conditions of irradiation repeatedly and other dependences that could present such as energy, angular, the type of radiation which are exposed and the dose deposited in them. For characterization they were designed and implemented tests for each of the factors of interest, taking into account the need for them (calculations, manufacture of mannequins, conditions, practicality, etc.) It was shown that we can apply this dosimetry in clinical practice within a radiotherapy center, relying on the readings and practicality. (Author)

  16. 肾脏相关标志物在评估妊娠高血压综合征肾损伤的研究%Clinica value of markers related kidney in assessing renal dysfunction in pregnancy induced hypertension women

    Institute of Scientific and Technical Information of China (English)

    陈志晓; 谢淑贤; 陈金玲; 陈国卫; 利定建; 吴修宇

    2015-01-01

    目的 评价胱抑素C(Cys C)、同型半胱氨酸(Hcy)、24小时尿蛋白定量(24 h-UPE)、尿素(UREA)、肌酐(Scr)在妊娠高血压综合征(PIH)早期肾损伤及损伤程度应用的价值.方法 检测133例PIH患者的Cys C、Hcy、24 h-UPE、UREA、Scr等指标 ;PIH患者分为轻度、中度重度组并与30例健康妊娠者(健康对照组)作比较.结果 轻度PIH组各项指标均高于健康对照组 ,中度、重度PIH组显著高于健康对照组、轻度PIH组 ,差异有统计学意义(P<0 .05);Cys C和24 h-UPE具有高度的相关性(r=0 .780 ,P<0 .01).结论 联合检测Cys C、Hcy、24 h-UPE、UREA、Scr能更准确和客观地反映PIH患者肾脏损伤程度 ,有利于早期诊断与治疗.%Objective To evaluate the significance of the serum cystatin C (Cys-C) Homocysteine(Hcy) ,24 h urinary protein excretion(24 h-UPE) ,UREA and Scr in assessing renal dysfunction in Pregnancy induced hyperten-sion(PIH) women .Methods Biochemistry was used to evaluate the level of Cys-C ,Hcy ,24 h-UPE ,UREA and Scr in 133 PIH patients (study group) who were divided into 3 groups ,the low group ,medium group and severe group , compared with 30 normal pregnant women(control group) .Results The concentrations of Cys-C ,Hcy ,24 h-UPE , UREA and Scr were significantly higher in the low PIH group than in the control group ,all in the medium PIH group and severe PIH group higher in the control group and low PIH group .Correlation analyses demonstrated significant correlations between Cys-C and 24 h-UPE in all the 133 pregnant women ,r=0 .780(P<0 .01) .Conclusion Cys-C , Hcy ,24 h-UPE ,UREA and Scr can reflect the degree of renal function damage in patients with PIH .

  17. Importance of the effective atomic number (Z{sub eff}) of TL materials for radiation dosimetry in clinical applications; Importancia del numero atomico efectivo (Z{sub eff}) de materiales TL para dosimetria de la radiacion en aplicaciones clinicas

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez M, P.R. [ININ, 52750 La Marquesa, Estado de Mexico (Mexico)]. e-mail: pgm@nuclear.inin.mx

    2008-07-01

    The electric power generation, it has been one of the radiation applications of bigger weight, mainly in developed countries. Another sector of more impact is without a doubt that of the medicine. However, for a sure operation with radiations, those international organisms of radiological safety, exist every time more precise detection systems. The thermoluminescent dosimetry is one of the more reliable methods for this purpose, for that several groups of investigators from different parts of the world, they have guided its investigations in the development of new TL materials. However, to avoid underestimate or overestimation of the measured dose with the use of these materials, it should take into account it effective atomic number (Z{sub eff}) it is well known that some TL materials considered as equivalent to the tissue, presents smaller TL intensity when being irradiated with low energy photons, while the TL material known as not equivalent to the tissue, they present the supra sensitivity effect for this radiation type. Nowadays, the estimate of the Z{sub eff} has not been clear, in this work the Z{sub eff} is determined by means of the traditional methods and an own method is presented for its determination. The results of the TL signal of different materials, when being irradiated with photons of effective energy between 24 keV and 1.25 MeV and their relationship with their calculated Z{sub eff} are also presented. (Author)

  18. Analysis of the systems for management of radioactive wastes from nuclear medicine clinics of the city of Recife, Pernambuco, Brazil; Analise dos sistemas de gerenciamento de rejeitos radioativos de clinicas de medicina nuclear da cidade de Recife, PE

    Energy Technology Data Exchange (ETDEWEB)

    Lira, Renata Farias de; Lopes, Ferdinand de Jesus; Passos, Robson Silva; Silva, Valeria Cosma Bento da; Belo, Igor Burgo, E-mail: renatafariasdelira@hotmail.co, E-mail: ferdinand.lopes@oi.com.b, E-mail: robson.passos@hotmail.co, E-mail: Valleria_@hotmail.co, E-mail: Igor.burgo@gmail.co [Instituto Federal de Educacao, Ciencia e Tecnologia de Pernambuco, Recife, PE (Brazil); Santos, Marcus Aurelio Pereira dos, E-mail: masantos@cnen.gov.b [Centro Regional de Ciencias Nucleares (CRCN-NE/CNEN-PE), Recife, PE (Brazil)

    2009-07-01

    In nuclear medicine compounds marked with radionuclides, called radiopharmaceuticals, for obtention diagnostic information and for diseases treatment. The physicochemical characteristics of the radiopharmaceuticals determine his fixation at target-organ, and the physical characteristics determine the compound application in diagnostic or therapy. The handling of radiopharmaceuticals generates solid, liquid and gas wastes. The presence of these wastes implies in a adequate management according to regulation standards established by the Brazilian Nuclear Energy Commission (CNEN). The objective of safe management of radioactive wastes is to protect the human being and the preservation of the environment, limiting possible radiological impacts for the future generation, and comprehend a set of technical and administrative activities involved in the collection, segregation, handling, conditioning, transportation, storage, control and elimination, or the final deposition. This work intends to verify if the radioactive waste management systems from the nuclear medicine clinics at the city of Recife are conformal with te normative regulations issued by the CNEN. The initial obtained results are used to elaboration of conformal verification spreadsheet and its application in six nuclear medicine clinics at Recife

  19. Elements determination of clinical relevance in biological tissues Dmd{sup mdx}/J dystrophic mice strains investigated by NAA; Determinacao de elementos de relevancia clinica em tecidos biologicos de camundongos distroficos Dmd{sup mdx}/J por AAN

    Energy Technology Data Exchange (ETDEWEB)

    Metairon, Sabrina

    2012-07-01

    In this work the determination of chemistry elements in biological tissues (whole blood, bones and organs) of dystrophic mice, used as animal model of Duchenne Muscular Dystrophy (DMD), was performed using analytical nuclear technique. The aim of this work was to determine reference values of elements of clinical (Ca, Cl, K, Mg, Na) and nutritional (Br and S) relevance in whole blood, tibia, quadriceps and hearts from Dmdmdx/J (10 males and 10 females) dystrophic mice and C57BL/6J (10 males) control group mice, using Neutron Activation Analysis technique (NAA). To show in more details the alterations that this disease may cause in these biological tissues, correlations matrixes of the DMD{sup mdx}/J mouse strain were generated and compared with C57BL/6J control group. For this study 119 samples of biological tissue were irradiated in the IEA-R1 nuclear reactor at IPEN (Sao Paulo, Brazil). The concentrations of these elements in biological tissues of Dmd{sup mdx}/J and C57B/6J mice are the first indicative interval for reference values. Moreover, the alteration in some correlation coefficients data among the elements in the health status and in the diseased status indicates a connection between these elements in whole blood, tibia, quadriceps and heart. These results may help the researchers to evaluate the efficiency of new treatments and to compare the advantages of different treatment approaches before performing tests in patients with muscular dystrophy. (author)

  20. Administered activities of {sup 18}F-FDG PET clinics in pediatrics patients in Brazil- preliminary study; Atividades administradas de {sup 18}F-FDG aos pacientes pediatricos nas clinicas PET no Brasil - estudo preliminar

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Cassio Miri, E-mail: cmo@cdtn.br [Universidade Federal de Minas Gerais (PCTN/UFMG), Belo Horizonte, MG (Brazil). Pos-Graduacao em Ciencias e Tecnicas Nucleares; Silva, Teogenes A. da, E-mail: silvata@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil); Sa, Lidia V. de, E-mail: lidia@ird.gov.br [Instituto de Radioprotecao e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2013-07-01

    A survey was conducted among the Brazilian clinical PET, with the purpose of investigating the activities administered to pediatric oncology patients and assess whether significant differences between the protocols adopted. In addition, this survey can cooperate to the suggestion diagnostic reference levels (DRLs) in nuclear medicine. Although the methodology for delivering doses by most clinics be based on patient's weight, the results showed variations of up to 191, 6% between the activities administered in clinics, even for similar devices. The average value of the distribution of activities reported was 4.46 {+-} 1,6 MBq /kg. These data demonstrate the need for harmonization and optimization of {sup 18}F-FDG/PET procedures, as well as training for professionals involved in the clinical routine.

  1. Specialized consultant in radiological safety to the Reforma peripheral clinic, PEMEX. - I. - May-June of 2003; Asesoria especializada en seguridad radiologica a la clinica periferica Reforma, PEMEX.- I.- Mayo-Junio de 2003

    Energy Technology Data Exchange (ETDEWEB)

    Torres P, A.; Garcia A, J.; Rodriguez A, F

    2003-07-15

    The Reforma peripheral clinic, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray equipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the clinic can conserve its respective sanitary license.(Author)

  2. Specialized consultant in radiological safety to the Macuspana peripheral clinic, PEMEX. - IV. - November and December of 2002; Asesoria especializada en seguridad radiologica a la clinica periferica Macuspana, PEMEX.- IV.- Noviembre y Diciembre de 2002

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Hernandez C, J. E.; Garcia A, J.; Rodriguez A, F

    2003-02-15

    The Macuspana peripheral clinic, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray equipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the clinic can conserve its respective sanitary license.(Author)

  3. Temporal evolution of the environmental dose remaining in a clinical irradiation bunker after the cessation of irradiation; Evolucion temporal de la Dosis ambiental remanente en un bunker de irradiacion clinica tras el cese de la irradiacion

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz Egea, E.; Sanchez Carrascal, M.; Torres Pozas, S.; Monja Ray, P. de la; Perez Molina, J. L.; Madan Rodriguez, C.; Luque Japon, L.; Morera Molina, A.; Hernandez Perez, A.; Barquero Bravo, Y.; Morengo Pedagna, I.; Oliva Gordillo, M. C.; Martin Olivar, R.

    2011-07-01

    In this paper we try to quantify the dose emitted by different radioactive processes that occur in the head of a clinical linear accelerator and the patient is irradiated, or walls of the bunker, converted into tertiary sources of radiation trying to establish the origin of the came in different parts of the bunker.

  4. Gunshot wounds to the head. Correlations between CT and clinical findings, neurosurgical treatment and long-term sequels; Traumi cranio-encefalici da proiettile: correlazione tra tomografia computerizzata, clinica, trattamento neurochirurgico e sequele a distanza

    Energy Technology Data Exchange (ETDEWEB)

    Salzano, A.; Nocera, V. [Ospedale S. Giovanni di Dio, Frattamaggiore, NA (Italy). Servizio di Radiologia; De Rosa, A.; Nunziata, A. [Ospedale Loreto Mare, Neaples (Italy). Servizio di Radiologia; Rossi, E.; Brunese, L. [Universita' degli Studi Federico II, Neaples (Italy). Ist. di Scienze Radiologiche; Tuccillo, M. [Azienda Ospedaliera di Rilievo Nazionale A. Cardarelli, Neaples (Italy). Servizio di Radiologia; Grassi, R. [Seconda Universita' degli Studi, Neaples (Italy). Ist. di Radiologia

    2000-03-01

    With the aim of demonstrating the usefulness of computerised tomography (CT) findings in the planning of brain neurosurgery in gunshot victims, for prompt and successful treatment, 30 patients with brain gunshot wounds were examined with CT over 5 years. The mortality rate of firearm wounds of the skull base was 34% higher than that of the hemisphere; this is due to carotid hemorrhage and midbrain damage. Such traumas require emergency radiological diagnosis and neurosurgical treatment because of their severity and early irreversible complications. Complex operations and skilled surgeons may prevent disabling postoperative sequels. CT findings are indispensable and must be correctly interpreted. The radiologist and the neurosurgeon must collaborate closely and both must consider several diagnostic factors affecting surgical planning. [Italian] Scopo dello studio e' stato quello di dimostrare l'utilita' della semeiologia della tomografia computerizzata in relazione con la pianificazione dell'intervento neochirurgico, al fine di attuare con tempestivita' interventi chirurgici soddisfacenti e meno lesivi. Lo studio comprende 30 casi di lesioni cranio-encefaliche da arma da fuoco esaminate con tomografia computerizzata nel periodo di 5 anni. Materiali e metodi utilizzati sono analiticamente descritti. L'esperienza dimostra che nelle lesioni da arma da fuoco del basicranio si nota una mortalita' del 34% superiore rispetto a quelle piu' craniali come quelle emisferiche in relazione a emorragie carotidee e lesioni tronco-mesencefaliche. Tali traumi esigono diagnosi radiologica e terapia neurochirurgica d'urgenza per la gravita' e le precoci complicanze irreversibili. Cio' richiede interventi complessi e manualita' esperte e rapide al fine di evitare sequele postoperatorie invalidanti. La corretta e indispensabile interpretazione dei segni radiologici della tomografia computerizzata deve avvenire in stretta collaborazione tra il radiologo e il neurochirurgo, ed entrambi devono tenere conto di una vasta gamma di fattori diagnostici, prognostici e di strategia terapeutica, che influenzano il tipo di decisionalita' e di aggressivita' chirurgica.

  5. ERI and initial clinical experience with dosimetry check, a commercial software for dosimetry in vivo volumetric; ERI y experiencia clinica inicial con dosimetry check, un software comercial para dosimetria in vivo volumetrica

    Energy Technology Data Exchange (ETDEWEB)

    Pujades Claumarchirant, M. C.; Gimeno Olmos, J.; Garcia Martinez, T.; Carmona Meseguer, V.; Lliso Valverde, F.; Palomo Llinares, R.; Ballester Pallares, F.; Perez Calatayud, J.

    2013-07-01

    The objective of this work is to study the differences in dose at a point of reference between the result of calculation of dose and the planning system to establish a level of uncertainty of the system. In addition, evaluates its use in clinical routine and presents results obtained with the first patients. (Author)

  6. 滤泡辅助性T细胞在类风湿关节炎发病中的临床意义%ClinicaI significance of T follicuLar helper cells in rheumatoid arthritis

    Institute of Scientific and Technical Information of China (English)

    李云春; 方忠俊; 钟立; 王悦; 阳帆; 稽晓赟

    2015-01-01

    Objective To investigate the percentages of T follicuLar helper cells (Tfh)and interleukin-21(IL-21)in the plasma of patients with rheumatoid arthritis,and the immunological mechanism of Tfh cells in the development of rheumatoid arthritis. Methods According to ACR and DAS28,patients with rheumatoid arthritis were divided into low,moderate and high activity group.The percentages of CD3 + CD4 + CXCR+ 、CD3 + CD4 + ICOS+ and CD3 + CD4 + CXCR+ ICOS+ Tfh cells were detected by Flow Cytometry.While the levels of IL-21 、RF-IgM and anti-CCP in plasma were measured by ELlSA test.The analysis was performed by t-test and Spearman′s correlation analysis.Results The expression of CD3 + CD4 + CXCR+ ICOS+ Tfh cells in PBMCs of rheu-matoid arthritis was significantly higher than that in the normal controls(P <0.05).Meanwhile the results of the three rheumatoid arthritis groups(low,moderate and high activity groups)showed that the expression of Tfh increased accordingly(P <0.05).The expression of Tfh in rheumatoid arthritis was positively related with the levels of IL-21 ,ESR,CRP,RF and anti-CCP respectively. Conclusion The expression of Tfh and IL-21 increases significantly and is closely related to the disease activity in rheumatoid ar-thritis.The results indicate that the abnormality of Tfh may play an important role in the pathogenesis of rheumatoid arthritis.%目的:通过检测类风湿关节炎(RA)患者外周血滤泡辅助性 T 淋巴细胞(Tfh))和白细胞介素-21(IL-21)等的表达,探讨其在 RA 发病过程中可能的免疫学发病机制。方法根据病情活动度不同将病例组分为轻、中、重度活动组(各30例),健康对照组30例;流式细胞仪检测 RA 和健康对照组外周血单个核细胞(PBMCs)中 CD4-异硫氰酸荧光素(FITC)、CXCR5-藻红蛋白(PE)、ICOS-别藻蓝蛋白(APC)标记的 CD3+ CD4+ CXCR+、CD3+ CD4+ ICOS+及 CD3+ CD4+ CXCR+ICOS+ Tfh 百分率;酶联免疫吸附试验(ELISA)检测 IL-21、类风湿因子(RF-IgM)、抗环瓜氨酸肽(CCP)抗体(CCP-IgG)及红细胞沉降率(ESR)、C 反应蛋白(CRP),分析其与 Tfh 的相关性。结果RA 轻、中、重度活动组患者外周血中 Tfh 百分率明显高于健康对照组(P <0.05);Tfh百分率随着 RA 活动度的增加呈上升趋势,组间差异有统计学意义(P <0.05);Tfh 细胞百分率与 RA 患者 ESR、CRP、RF 及抗CCP 抗体滴度呈正相关,差异有统计学意义(P <0.05)。结论RA 患者外周血 Tfh、IL-21、CRP、ESR、RF 及 CCP 水平明显升高,与疾病活动度等有明显相关性,提示 Tfh 细胞可能在 RA 发病中起着一定的作用。

  7. Clinical and morphologic evaluation of Er:YAG laser action at the front of cervical dentinal hypersensitivity; Avaliacao clinica e morfologica da acao do laser de Er:YAG frente a hipersensibilidade dentinaria cervical

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Dalva Maria

    2001-07-01

    This work was achieved in vivo and in vitro to evaluate the efficiency of Er:YAG laser in the cervical dentinal hypersensitivity treatment (HSDC). The Clinical study was achieved in patients with HSDC. The treatment was realized in five sessions: the first for selection, the second for exams (clinic and X-Ray) and trying to remove the etiologic factors that could cause the HSDC. The third and fourth sessions were subjected to the radiation with that protocol: 60 mJ energy ,2 Hz frequency, 6 mm out of focus, under air cooling, 20 seconds each application which the same was repeated four times with one minute breaks, which scanning movements and without using anaesthetics. The fifth was evaluation. The patients were evaluated and registered in a subject scale of pain 0 to 3, in the beginning and end of each session of irradiation, and one month after the last session. The results showed that for the irradiated group occurs significant differences in the beginning of each session and between. For the control group did not occur significant differences in the beginning and after each session, but did show a difference between the sessions. As the control group as the irradiated group, had reduction of sensibility between the session. For the morphologic study nine teeth were selected, 7 molars and 2 pre-molars from operative dentistry discipline. Half of the surface was irradiated with Er:YAG laser, the same protocol used in vivo, and the other half was used as a control without receiving any laser irradiation. Subsequently, specimens were prepared for SEM examinations. The results showed that laser treated surfaces showed a reduction of dentine tubular diameter with partial or total closure of the dentine tubules. For the control group, it was observed bigger amounts smear layer and open dentine tubular. The results obtained indicated that the Er:YAG laser can contribute to the HSDC treatment. (author)

  8. Specialized consultant in radiological safety to the south central hospital of high speciality, PEMEX. IV. - October of 2001; Asesoria especializada en seguridad radiologica a la clinica al hospital central sur de alta especialidad, PEMEX. IV.- Octubre de 2001

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Vizuet G, J.; Benitez S, J. A.; Garcia A, J.; Rodriguez A, F

    2002-01-15

    The south central hospital of high speciality, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray equipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the hospital can conserve its respective sanitary license.(Author)

  9. Pineal metastasis as first clinical manifestation of colorectal adenocarcinoma: case report Metástase pineal como primeira manifestação clinica de adenocarcinoma colorretal: relato de caso

    Directory of Open Access Journals (Sweden)

    RICARDO RAMINA

    1999-03-01

    Full Text Available Cerebral metastases from colorectal adenocarcinomas occur in 8% of the cases. Diagnosis is usually made when primary disease and widespread metastases are already known. We report the case of a patient with single metastases in the pineal region as the first clinical manifestation of a colorectal adenocarcinoma. A 48-year-old female with Parinaud's syndrome for 15 days prior her admission was evaluated in our clinic. She had no symptoms or signs of colorectal disease. MRI examination revealed an heterogeneous lesion with peritumoral gadolinium enhancement, located in the pineal region. The tumor was radically resected through an infratentorial/supracerebellar approach. Histology showed metastatic carcinoma and immunohistochemical examination showed gastrointestinal tract adenocarcinoma. Metastases to the pineal region are extremely rare and should be considered in the differential diagnosis of tumors of this region.Metástases cerebrais derivadas de adenocarcinomas colorretais ocorrem em 8% dos casos. Geralmente a doença primária e as metástases em outros órgãos já são conhecidas quando do momento das manifestações neurológicas. Descrevemos um caso de metástase única na região pineal que promoveu a primeira manifestação clínica de adenocarcinoma colorretal. Uma mulher de 48 anos de idade apresentava há quinze dias de sua admissão ao nosso serviço diplopia e síndrome de Parinaud . O exame de ressonância magnética revelou lesão heterogênea localizada na região pineal. O tumor foi completamente retirado por acesso infratentorial/supracerebelar. O exame histológico revelou tumor metastático indiferenciado e o exame imuno-histoquímico demostrou adenocarcinoma do trato gastrointestinal moderadamente diferenciado. Metástases para a região pineal são extremamente raras e devem ser consideradas no diagnóstico diferencial de tumores nesta região.

  10. Development of a kit for RBC labelling with /sup 99m/Tc and its clinic evaluation. Desarrollo y evaluacion clinica de un juego de reactivos para la marcacion de globulos rojos con /sup 99m/Tc

    Energy Technology Data Exchange (ETDEWEB)

    Marafuschi, A.M.; Mondino, M.H.; Nowotny, G.A.; Palcos, M.C.; Rotta, M. del C.

    1980-01-01

    A kit for labelling red blood cells (RBC) with /sup 99m/Tc based on a Tin Pyro-phosphate mixture freeze-dried and a saline solution saturated with nitrogen, has been prepared for spleen and placenta scanning, circulatory studies and blood volume determinations. The stannous tin is intended to reduce the /sup 99m/Tc pertechnetate, obtained either from generators or from solvent extraction, to the appropriate valence state suitable for labelling. The labelling yield (95% to 88%) and its stability has been checked by in vitro measurements, up to four hours after labelling. The biological distribution and spleen uptake have been determined in rats and rabbits. An interesting application is shown in babies with congenital cardiac defects and suspected absence of spleen, where the scan gave a good image of the existing spleen. 7 refs., 4 figs., 2 tabs.

  11. Dissection of the sentry ganglion by laparoscopic boarding in patients with cervix uterine cancer clinical stages IA2 at IIB; Diseccion de ganglio centinela por abordaje laparoscopico en pacientes con cancer cervicouterino etapas clinicas IA2 a IIB

    Energy Technology Data Exchange (ETDEWEB)

    Valdez U, J.J.; Pichardo M, P.A.; Cortes M, G.; Escudero de los Rios, P. [Hospital de Oncologia. Centro Medico Nacional Siglo XXI. IMSS, Mexico D.F. (Mexico)

    2005-07-01

    The obtained results in presently study demonstrate that the feasibility of the detection of the sentry ganglion in cervix uterine cancer using a boarding by laparoscopic via, being necessary the use of twice labelled as much with patent blue and radioisotope (colloid of labelled rhenium with {sup 99m}Tc, total dose of 3 MCi) to achieve the identification of the ganglion. (Author)

  12. Infecções causadas por fungos demácios e suas correlações anátomo-clinicas Infections caused by dematiaceous fungi and their anatomoclinical correlations

    Directory of Open Access Journals (Sweden)

    Camila de Camargo Hoffmann

    2011-02-01

    Full Text Available O gênero Exophiala é composto por fungos melanizados dimórficos, responsáveis por um espectro de doenças, incluindo feohifomicoses, micetomas, cromoblastomicoses e fungemia. A espécie E. jeanselmei é a predominante nestas infecções, seguida de E. dermatitidis. Este trabalho tem como objetivo relatar quatro casos e discutir aspectos clínicos, histológicos, micológicos e epidemiológicos para o seu diagnóstico.The Exophiala genus comprises dimorphic melanized fungi responsible for a spectrum of diseases including phaeohyphomycosis, mycetoma, chromoblastomycosis and fungemia. The E. jeanselmei species is predominant in such infections, followed by E. dermatitidis. This paper aims at reporting four cases and at discussing clinical, histologycal, mycologycal and epidemiologycal aspects for its diagnosis.

  13. Specialized consultant in radiological safety to the clinical north central hospital of high speciality, PEMEX. IV. - December of 2001; Asesoria especializada en seguridad radiologica a la clinica hospital central norte de alta especialidad, PEMEX. IV.- Diciembre de 2001

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Vizuet G, J.; Benitez S, J. A.; Garcia A, J.; Rodriguez A, F

    2002-01-15

    The clinical north central hospital of high speciality, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray equipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the hospital can conserve its respective sanitary license.(Author)

  14. Security in inserting data into the system scheduler registration and verification and medical history; Seguridad en la insercion de los datos del planificador en el sistema de registro y verificacion y en la historica clinica

    Energy Technology Data Exchange (ETDEWEB)

    Camara, A.; Martinez, D.; Melchor, M.; Candela, F.; Asensio, M.; Gil, S.; Borreda, V.

    2011-07-01

    A critical process Service Radio physics and Radiation Protection is to manage the data resulting from the treatment planning of Radiation Oncology, including both its insertion in the registration and verification of the linear accelerator (data that will be treated later patients) as its final registration in the medical record.

  15. Avaliação clínica da vertebroplastia percutânea transpedicular Evaluación clinica de la vertebroplastia transpedicular percutánea Clinic evaluation of transpedicular percutaneous vertebroplasty

    Directory of Open Access Journals (Sweden)

    André Rafael Hubner

    2011-01-01

    Full Text Available OBJETIVO: Avaliar a eficácia do efeito analgésico da vertebroplastia com polimetilmetacrilato (PMMA e da estabilização vertebral obtida nos pacientes com fraturas vertebrais patológicas e realizar uma revisão detalhada da técnica da vertebroplastia percutânea, analisando suas indicações. MÉTODOS: Análise retrospectiva de 64 procedimentos de vertebroplastia percutânea em 46 pacientes. Foram realizadas avaliações dos prontuários e das radiografias pré e pós-operatórias e em nova consulta de rotina, na qual foi aplicado o questionário de dor (escala analógica visual da dor. RESULTADOS: Entre os 46 pacientes analisados, 37 (80,4% eram do sexo feminino e 9 (19,6% do sexo masculino, com média de idade de 71 anos (desvio-padrão +/- 9,2, variando de 50 a 90 anos. Foram operados 64 níveis, com predomínio do segmento toracolombar, sendo realizadas 17 (26,6% vertebroplastias a maioria em pedículos de T12. Trinta e um pacientes (67,4% apresentaram apenas um nível fraturado, 12 (26,1% apresentaram 02 níveis operados e três pacientes (6,5% apresentaram 03 ou mais níveis operados. O diagnóstico de osteoporose foi o mais comum (33 casos, 71,7%. Quanto ao alívio da dor no pós-operatório, houve um alto índice de satisfação de 90 a 100% em 37 (80% pacientes. CONCLUSÃO: A vertebroplastia demonstra ser um procedimento eficaz no tratamento da dor por fratura patológica de coluna, sendo tamb��m utilizada em investigação diagnóstica (biópsia óssea. É um procedimento seguro com baixas taxas de complicações.OBJETIVO: Evaluar la eficacia del efecto analgésico y estabilización vertebral de la vertebroplastia con polimetilmetacrilato (PMMA en pacientes con fracturas patológicas de la columna vertebral, y realizar una revisión detallada de la técnica de vertebroplastia percutánea, analizando sus indicaciones. MÉTODOS: Evaluación retrospectiva de 64 fracturas tratadas en 46 pacientes sometidos a vertebroplastia percutánea en el período de enero de 2000 a diciembre de 2008. Los pacientes fueron evaluados por las historias clínicas, por las radiografías pre y postoperatorias y consultas de rutina en las cuales se realizaron encuestas de dolor (escala universal visual del dolor. RESULTADOS: 37 (80,4% eran mujeres y 9 (19,6% eran varones, con edad promedio de 71 años (desvío estándar de + / - 9,2, que oscila entre 50 y 90 años. 64 niveles fueron operados, con predominio de lo segmento torácico-lumbar, se realizaron 17 (26,6% la mayoría en pedículos vertebroplastia de T12. Treinta y un pacientes (67,4% tenían sólo un nivel de fractura, 12 pacientes (26,1% tenían 02 niveles y 03 (6,5% pacientes tenían 03 o más niveles de fractura. El diagnóstico de osteoporosis fue el más común (33 casos, el 71,7%. Cuanto al alivio del dolor postoperatorio, hubo un alto índice de satisfacción de 90 a 100% en 37 (80% pacientes. CONCLUSIÓN: La vertebroplastia es un procedimiento que probó ser eficaz en el tratamiento del dolor por fractura patológica de la columna, y también se utiliza con fines de diagnóstico (biopsia de hueso. Es un procedimiento seguro y tiene bajas tasas de complicaciones.OBJECTIVE: This paper evaluates the analgesic effect and obtained vertebral stability of percutaneous vertebroplasty with polymethylmethacrylate (PMMA in patients with vertebral pathological fractures, and performs a detailed revision of this technique. METHODS: A retrospective analysis of 64 percutaneous vertebroplasty procedures in 46 patients was performed. Patients were evaluated by medical records, pre and post-operative radiographs, and by pain status (visual analog pain scale. RESULTS: 37 (80.4% patients were female and 9 (19.6% male, with mean age of 71 years (standard deviation + / - 9.2, ranging from 50 to 90 years. Sixty-four levels were treated, with a predominance of thoracic-lumbar segment, the majority 17 (26.6% of vertebroplaties at T12 pedicle. Thirty-one patients (67.4% presented only one fractured level, 12 patients (26.1% presented 02 levels and three (6.5% presented 03 or more treated levels. Osteoporosis was the most common diagnosis (33 cases, 71.7%. A high satisfaction rate of 90 to 100% was observed to the majority of patients when considering relief of pain postoperatively. CONCLUSIONS: Vertebroplasty has proven to be an effective procedure to treat pain caused by pathological fracture, and it is also used for diagnostic investigation (bone biopsy. The technique is secure and has provided low complications rates.

  16. Gingival healing after gingivectomy procedure and low intensity laser irradiation. A clinical and biometrical study in anima nobile; Reparacao gengival apos a tecnica de gengivectomia e aplicacao de laser em baixa intensidade. Avaliacao clinica e biometrica em humanos

    Energy Technology Data Exchange (ETDEWEB)

    Amorim, Jose Claudio Faria

    2001-07-01

    For the present study seven patients presenting periodontal disease were selected in a way that they required the performance of gingivectomy procedure in the region of premolars in both sides, being this in the upper or lower region. After the surgical procedure one side was submitted to low intensity laser radiation, wavelength 685 nm, power 50 mW and fluency of 4J/cm{sup 2}, contact mode. The other side was used as a control, not receiving any laser irradiation. Healing process for both sides, was clinically and biometrically evaluated and compared using photographs for the periods: pre-operative, immediate post-operative, 3, 7,14,21, 28 and 35 days. The analysis was performed by 3 specialists in Periodontology considering aspects of healing. Results were submitted to statistical analysis. Biometrical evaluation showed improvement of healing for the period of 21 and 28 days in the lased group. Clinical evaluation showed better reparation mainly after the third day for the active group. Laser group was considered to present an improved healing when compared to the control group. (author)

  17. OCTAVIUS 4D: Commissioning and routine clinical use of a device for VMAT verifications; OCTAVIUS 4D: establecimiento del estado de referencia inicial y uso en rutina clinica de un dispositivo para verifiicaciones VMAT

    Energy Technology Data Exchange (ETDEWEB)

    Gimeno Olmos, J.; Candela Juan, C.; Palomo Linares, R.; Carmona Meseguer, V.; Lliso Valverde, F.; Ballester Pallares, F.; Perez Calatayud, J.

    2015-07-01

    Purpose: To commission OCTAVIUS 4D and its arrays 729 and 1000 SRS for VMAT patient-specific QA verifications, and to provide clinical results obtained with this device. Methods: The performance of both arrays was analysed by evaluating: homogeneity, linearity, reproducibility and leakage current. The accuracy of the dose reconstruction of OCTAVIUS 4D with array 729 was evaluated through ion chamber measurements at several points of interest. The performance of both arrays was compared for the same clinical plans. Finally, results of the 3D gamma analysis performed in our hospital for more than 900 patient plans are provided. Results: Both arrays present good homogeneity, linearity, reproducibility, and negligible leakage current. Dose differences between OCTAVIUS-calculated doses and ion chamber measurements or TPS-calculated doses were within 2% for single field plans, and within 4% for clinical plans. The mean value of the local gamma passing rate (3%/3 mm) of clinical plans verified with array 729 is 89.7%, whereas for 1000 SRS it is 97.8%. Conclusions: OCTAVIUS 4D provides accurate 3D dose reconstructions from 2D dose measurements. Clinical results here presented may be used to establish reference levels for VMAT verifications with this device. (Author)

  18. WITHDRAWN: Corrigendum to "High-sensitive cardiac troponin I (hs-cTnl) values in patients with stable cardiovascular disease: An initial foray" [Clinica Chimica Acta 411 (2010) 812--817].

    Science.gov (United States)

    Schulz, Olaf; Reinicke, Markus; Berghoefer, Gunnar H; Bensch, Ricarda; Kraemer, Jochen; Schimke, Ingolf; Jaffe, Allan S

    2010-05-18

    This article has been withdrawn at the request of the author(s) and/or editor. The Publisher apologizes for any inconvenience this may cause. The full Elsevier Policy on Article Withdrawal can be found at http://www.elsevier.com/locate/withdrawalpolicy.

  19. Accounting of costs in a service of physical health. Relative units of value in dosimetry clinic in teletherapy; Contabilidad de costes en un servicio de fisica medica. Unidades relativas de valor en dosimetria clinica en teleterapia

    Energy Technology Data Exchange (ETDEWEB)

    Font Gomez, J. A.; Gandia Martinez, A.; Jimenez Albericio, F. J.; Andres Redondon, M. M.; Mengual Gil, M. A.

    2013-07-01

    A single - although laborious - start in the economic and clinical management of our units can be come to the knowledge of the time invested in the tasks functional, having to differentiate them, name them and even encrypt them. The time spent in performing the tasks multiplied by the annual number of these will indicate the resources necessary to achieve our objectives. In addition, pooling the values of times that members of the Unit provide analysed inter-workers dispersal, their causes and possible solutions. The establishment of relative units of value in any process benefits all workers involved in the process since it allows to know the dispersion of the times that each person employed in the development of the tasks. (Author)

  20. Specialized consultant in radiological safety to the Reforma peripheral clinic, PEMEX. - IV. - November and December of 2002; Asesoria especializada en seguridad radiologica a la clinica periferica Reforma, PEMEX.- IV.- Noviembre y Diciembre de 2002

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Hernandez C, J. E.; Rodriguez A, F.; Garcia A, J

    2003-02-15

    The Reforma peripheral clinic, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray quipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the clinic can conserve its respective sanitary license.(Author)

  1. Development and clinical implementation of a global software use and analysis of radiochromic s films; Desarrollo e implementacion clinica de un software global de uso y analisis de peliculas radiocromicas

    Energy Technology Data Exchange (ETDEWEB)

    Gimeno Olmos, J.; Martinez Fernandez, J. M.; Pastor Sanchis, V.; Gonzalez Perez, V.; Guardino de la Flor, C.; Dolores Alemany, V. de los; Crispin Contreras, V.

    2011-07-01

    The aim of this study was to gather information in one solution the different processes that occur with the use of radiochromic films: calibration, reading, corrections, step-absorbed dose, dose distribution analysis and comparison with reference distributions.

  2. Specialized consultant in radiological safety to the Reforma peripheral clinic, PEMEX. - III. - September and October of 2002; Asesoria especializada en seguridad radiologica a la clinica periferica Reforma, PEMEX.- III.- Septiembre y Octubre de 2002

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Rodriguez A, F.; Garcia A, J

    2003-02-15

    The Reforma peripheral clinic, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray equipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the clinic can conserve its respective sanitary license.(Author)

  3. COMPARACION DE LA REABSORCION RADICULAR EN DIENTES VITALES Y DIENTES CON ENDODONCIA A LOS 12 MESES DE TRATAMIENTO ORTODONCICO. MEDIANTE LA MEDICION DE LA LONGITUD RADICULAR. CLINICA DE ORTODONCIA DE LA U.M.S.N.H MORELIA MICH 2007.

    OpenAIRE

    Melendez Rodriguez, Verenice

    2012-01-01

    Han sido mucho las investigaciones clínicas que han demostrado la asociación entre reabsorción radicular y movimiento dentario ortodoncico. Desde que Schwarzkopf, en 1887, y Ottolengi, en 1914, observaron la aparición de acortamiento radicular tras el tratamiento. Hasta nuestros días, han sido múltiples los estudios que han tratado de relacionar en términos matemáticos la extensión del fenómeno con factores biológicos. Ketcham, en 1927, encontró reabsorción en el 22% de un g...

  4. Contributions to the problems of generalization in the phonological intervention: a clinical approach Contribuições para os problemas de generalização em intervenção fonológica: uma abordagem clinica

    Directory of Open Access Journals (Sweden)

    Víctor M. Acosta Rodríguez

    2007-03-01

    Full Text Available PURPOSE: to describe the procedure which could be useful for teachers and speech therapists engaged within a school context, in the treatment of the phonological mistakes exhibited by children during their primary-school education. It is an attempt to present an intra-subject study and to observe the generalization suffered by the untrained phonemes and processes during the training of a phoneme. METHODS: two children with phonological impairment participated in this research. A Test of Phonology Acosta et al. (1998 was used for the analysis of the simplifications and, later on, an intervention program by minimal pairs was applied. RESULTS: the results seem to indicate that the treatment should start with the process affecting more phonemes and that the most difficult; for example, the phoneme where the process is compulsory applied, should be chosen as the one to be trained. CONCLUSION: the results showed that treatment must begin with the process that affects a major number of phonemes which have more difficulty in their production.OBJETIVO: descrever procedimento de intervenção fonológica. MÉTODOS: duas crianças com transtorno fonológico participaram do estudo. Foi aplicada a prova de Fonologia de Acosta et al. (1998 para o levantamento das simplificações e, posteriormente, aplicado o programa de intervenção por pares mínimos. RESULTADOS: observou-se generalização dos fonemas e processos fonológicos não treinados durante o tratamento. CONCLUSÃO: os resultados indicam que o tratamento deve começar por aqueles processos que afetam um maior número de fonemas e que apresentam maior dificuldade em sua produção.

  5. Spatial map dose of nuclear medicine service of the Clinical Hospital of Botucatu, SP, Brazil; Mapa espacial de dose do servico de medicina nuclear do Hospital das Clinicas de Botucatu

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Caio V.; Mendonca, Caroline; Silva, Eduardo T.; Moriguchi, Sonia M.; Koga, Katia H., E-mail: caiov_oliveira@yahoo.com.br [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil). Faculdade de Medicina

    2013-12-15

    This study was conducted to describe levels of occupational and environmental exposure of the Nuclear Medicine Service of the Clinical Hospital of Botucatu. To this end, measurements were made of the radiometric levels of points strategically defined, in all the environments, for a period of six months, sampling different days and times, during operation normal routine of the sector. The results allow to estimate the expected dose for each environment, comparing them to the dose limitation established by the National Commission of Nuclear Energy (CNEN), allowing better targeting of occupationally exposed individuals, indicating the points where the occupation should be the minimum required, enabling the reduction of risks to potential exposures. (author)

  6. Confronto tra ecocardiografia tridimensionale real-time e tomografia assiale computerizzata a 64 strati nella valutazione della funzione ventricolare sinistra nella pratica clinica, usando la risonanza magnetica cardiaca come standard di riferimento

    OpenAIRE

    Bertorelli, Marcello

    2011-01-01

    L'obiettivo della tesi è di confrontare la valutazione dei volumi e della frazione di eiezione del ventricolo sinistro, eseguita con ecocardiografia tridimensionale e con tomografia computerizzata a 64 strati, in una serie consecutiva di pazienti, utilizzando la risonanza magnetica come standard di riferimento

  7. EFECTO IN VITRO DE LA UNCARIA TOMENTOSA, DEL MTA Y DEL HIDROXIDO DE CALCIO EN LA VIABILIDAD CELULAR, MORFOLOGIA NUCLEAR Y INTEGRIDAD DEL ADN EN PULPA DENTAL DE PIEZAS DENTARIAS EXTRAIDAS, CLINICA ODONTOLOGICA PARTICULAR. AREQUIPA, 2011

    OpenAIRE

    LÓPEZ HUAMÁN, GIOVANNI

    2013-01-01

    UNCARIA TOMENTOSA ANTECEDENTES HISTÓRICOS CLASIFICACIÓN BOTÁNICA COMPOSICIÓN QUÍMICA PROPIEDADES FARMACOLÓGICAS TOXICIDAD Y CONTRAINDICACIONES EFECTOS MTA HIDRÓXIDO DE CALCIO COMPLEJO DENTINO PULPAR RECUBRIMIENTO PULPAR DIRECTO VIABILIDAD CELULAR MORFOLOGÍA NUCLEAR ESTRUCTURA DEL ADN

  8. Nd:YAG laser in caries prevention: a clinical study; Avaliacao clinica da eficiencia do laser de Nd:YAG associado ao fluor fosfato acidulado na prevencao de caries de sulcos e fissuras de criancas e adolescentes

    Energy Technology Data Exchange (ETDEWEB)

    Boari, Heloisa Gomes Dimiranda

    2000-07-01

    The caries prevention by using laser irradiation has been investigated during the last 30 years. The Nd: YAG laser associated with acidulated phosphate fluoride has been shown as a very promising technique for enamel caries prevention. The aim of this work was to clinically evaluate the efficiency of Nd: YAG laser associated with acidulated phosphate fluoride in pit and fissure caries prevention of children and adolescents. In this work it was determined the dye that enhance the effect of Nd: YAG laser in enamel. It was selected 242 pre-molar and molar teeth from 33 children and adolescents, aged from 7 to 15 years old. The selected teeth were free from caries or decalcification marks (active white marks) to the clinical and radiographic exams. The teeth were divided into two groups: the first group was laser irradiated and their homologous remained as a control. The right side teeth were dye-assisted Nd:YAG laser irradiated. The dye solution was a moisture of dust coal and equal parts of water and alcohol. The irradiation conditions were 60 mJ/10 Hz, optical fiber in contact mode, with diameter of 300 {mu}m, resulting in an energy density of 84,9 J/cm{sup 2}. The oclusal surface of the teeth was completely irradiated, specially on the slopes and in the deepest part of the pits and fissures. This procedure was repeated three times. In the sequence it was applied the acidulated phosphate fluoride for 4 minutes. On the left side teeth - control group- only acidulated phosphate fluoride was applied for the same time. The final examination considered the presence of caries and active white marks after a period of one year. There were statistical significant differences (p < 0.01) between the lased + fluoride group and the non irradiated group. The present study concluded that the technique used in this work can be an alternative clinical method for caries prevention. (author)

  9. Dosimetric characterization of the PTW Seven29 dosimeter and Octavius Phantom for IMRT quality control; Caracterizacao dosimetrica do dosimetro PTW Seven29 e Octavius Phantom para controle de qualidade em IMRT

    Energy Technology Data Exchange (ETDEWEB)

    Goncalves, Leandro R.; Habitzreuter, Angela B.; Santos, Gabriela R.; Watanabe, Erica Y.; Silva, Marco A.; Menegussi, Gisela; Rodrigues, Laura N.; Furnari, Laura, E-mail: leandrorg11@hotmail.com [Instituto do Cacer do Estado de Sao Paulo (ICESP), SP (Brazil). Servico de Radioterapia

    2012-12-15

    Techniques like IMRT, VMAT and tomotherapy has been used to improve dose conformity in the target, while sparing adjacent normal tissues. The complexity of this techniques challenge to correctly verify the dose delivery, in an independent way. Matrix detectors have been used for this purpose. Although, to exactly understand the dosimeter response and to identify his limitations, characterization measurements need to be performed. These dosimeters, for instance, can present angular dependence. Phantoms has been designed to, when used together the detector, eliminate this angular dependence. The aim of this work was to characterize PTW Seven 29 dosimeter and also his use with Octavius Phantom (PTW). The dosimeter showed reproducible with 0.25% the biggest standard deviation, good dose linearity and dose rate independence. Differences for output factors were obtained (<6%), but a clinical case measurement showed that the set can be used for IMRT verification. When used with Octavius Phantom the dosimeter showed low angular dependence. (author)

  10. Characterization of commercial ceramic adsorbents and their application on naphthenic acids removal of petroleum distillates; Caracterizacao de adsorventes ceramicos comerciais e sua aplicacao na remocao de acidos naftenicos de destilados de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Silva, J.P.; Senna, L.F. de; Lago, D.C.B. do; Silva Junior, P.F. da; Figueiredo, M.A.G. de; Dias, E.G. [Universidade do Estado do Rio de Janeiro (UERJ), RJ (Brazil)], e-mail: julia_psi@yahoo.com.br; Chiaro, S.S.X. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2006-07-01

    One denominates 'naphthenic acids' to the mixture of carboxylic acids that is present in petroleum oil, and is directly responsible for its acidity and corrosiveness in liquid phase during the refine process. These acids are also presents in distilled fraction of petroleum, causing several problems in final products quality. A possible way to remove them from petroleum distilled fractions is the adsorption in porous materials. However, the published results indicate that ion exchange resins would be the best adsorbents for this process, which would probably increase its cost. In this work, two commercial adsorbents (clay and activated alumina) were characterized by a set of physical-chemistry techniques and evaluated concerning their capacity of removing naphthenic acids from a light petroleum fraction. It was also verified the influence of a previous thermal treatment to the adsorption in their physical-chemistry characteristics and its properties. (author)

  11. Characterization of an extrapolation chamber and radiochromic films for verifying the metrological coherence among beta radiation fields; Caracterizacao de uma camara de extrapolacao e filmes radiocromicos para verificacao da coerencia metrologica entre campos padroes de radiacao beta

    Energy Technology Data Exchange (ETDEWEB)

    Castillo, Jhonny Antonio Benavente

    2011-07-01

    The metrological coherence among standard systems is a requirement for assuring the reliability of dosimetric quantities measurements in ionizing radiation field. Scientific and technologic improvements happened in beta radiation metrology with the installment of the new beta secondary standard BSS2 in Brazil and with the adoption of the internationally recommended beta reference radiations. The Dosimeter Calibration Laboratory of the Development Center for Nuclear Technology (LCD/CDTN), in Belo Horizonte, implemented the BSS2 and methodologies are investigated for characterizing the beta radiation fields by determining the field homogeneity, the accuracy and uncertainties in the absorbed dose in air measurements. In this work, a methodology to be used for verifying the metrological coherence among beta radiation fields in standard systems was investigated; an extrapolation chamber and radiochromic films were used and measurements were done in terms of absorbed dose in air. The reliability of both the extrapolation chamber and the radiochromic film was confirmed and their calibrations were done in the LCD/CDTN in {sup 90}Sr/{sup 90}Y, {sup 85}Kr and {sup 147}Pm beta radiation fields. The angular coefficients of the extrapolation curves were determined with the chamber; the field mapping and homogeneity were obtained from dose profiles and isodose with the radiochromic films. A preliminary comparison between the LCD/CDTN and the Instrument Calibration Laboratory of the Nuclear and Energy Research Institute / Sao Paulo (LCI/IPEN) was carried out. Results with the extrapolation chamber measurements showed in terms of absorbed dose in air rates showed differences between both laboratories up to de -I % e 3%, for {sup 90}Sr/{sup 90}Y, {sup 85}Kr and {sup 147}Pm beta radiation fields, respectively. Results with the EBT radiochromic films for 0.1, 0.3 and 0.15 Gy absorbed dose in air, for the same beta radiation fields, showed differences up to 3%, -9% and -53%. The beta radiation field mappings with radiochromic films in both BSS2 showed that some of them were not geometrically aligned. (author)

  12. Synthesis and characterization of copolymers 4,5-dihydroisoxazole and (-)-menthyl acrylates; Sintese e caracterizacao de copolimeros de cadeia lateral derivados de acrilatos de 4,5-di-hidroisoxazol e do (-)-mentol

    Energy Technology Data Exchange (ETDEWEB)

    Passo, Joel A.; Merlo, Aloir A. [Universidade Federal do Rio Grande do Sul, Porto Alegre, RS (Brazil). Inst. de Quimica; Eccher, Juliana; Bechtold, Ivan H. [Universidade Federal de Santa Catarina, Florianopolis, SC (Brazil). Campus Universitario Trindade. Dept. de Fisica; Kelly, Stephen M., E-mail: aloir@iq.ufrgs.br [University of Hull, Hull (United Kingdom). Dept. of Chemistry

    2012-07-01

    Five monomers 5-[4-(5-cyano-4,5-dihydroisoxazol-3-yl)phenoxy]undecyl acrylate (7a); n-alkyl 3-{l_brace}4-[5-(acryloyloxyundecyl)oxyphenyl]{r_brace}-4,5-dihydroisoxazole-5-carboxylate (7b,c for n-butyl and n-hexyl, respectively); 3-{l_brace}4-[5-(acryloyloxyundecyl) oxyphenyl]{r_brace}-4,5-dihydroisoxazole-5-carboxylic acid (7d) and (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl acrylate (9) and the corresponding copolymers 10a-d,11 and homopolymers 12 from 7a and 13 from 9 were designed and synthesized. Except for acrylate 9 which is derived from (-)-menthol, all of the monomers belong to the series containing the isoxazoline ring linked to the acrylate unit by a flexible spacer chain of eleven methylene units. They presented low glass temperature and despite birefringence behavior, these copolymers showed no mesomorphic properties. (author)

  13. Chemometrics application in fuel's MTR type chemical characterization by X-ray fluorescence; Aplicacao da quimiometria para caracterizacao quimica de combustiveis tipo MTR por fluorescencia de raios-X

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Clayton Pereira da

    2012-07-01

    In Brazil and worldwide the nuclear power has occupied a prominent position with many applications in industry, power generation, environment and medicine, improving the quality of tests and treatments, therefore people's lives. Uranium is the main element used in nuclear facilities and it s employed as base material to generation of electricity in the manufacture of radiopharmaceuticals. In the '50s, during the Cold War, the then newly created International Atomic Energy Agency proposed to oversee nuclear facilities and encourage the manufacture of nuclear fuels with low-enriched uranium (LEU) fuel came then type Material Test Reactor (MTR), manufactured initially in U{sub 3}O{sub 8} and U{sub 3}Si{sub 2} later, both dispersed in aluminum. The use of this technology requires a constant improvement of all processes involving the manufacture of MTR subject to several international protocols, which seek to ensure the reliability of the fuel from the standpoint of practical and environmental. In this context, the control of impurities, from the point of view of neutron economy, directly affects the quality of any nuclear fuel, so strict control is necessary. The literature has reported procedures which, beyond generating residues, are lengthy and costly, they need calibration curve and consequently reference materials. The aim of this work is to establish and validate a methodology for nondestructive quantitative chemical analysis, low cost and analysis time, as well as minimize the generation of waste, for multielement determination of major constituents (Utotal and Si) and impurities (B, Mg, Al, Cr, Mn, Fe, Co, Ni, Cu, Zn, Mo, Cd and others) present in U3O8 and U{sub 3}Si{sub 2}, meeting the needs of nuclear reactors in the nuclear fuel qualification type MTR. For that purposes, will be applied the X-ray fluorescence technique which allows fast chemical and nondestructive analysis, aside from sample preparation procedures that do not require previous chemical treatments (dissolving, digesting, and others). To corrections like effects of spectral and matrix were applied and evaluated the fundamental parameter method, univariate calibration curve and multivariate calibration. The results were compared by means of statistical tests in accordance with ISO 17025 in MRCs (123 (1-7) and 124 (1-7)) MCRs of U{sub 3}O{sub 8} from New Brunswick Laboratory (NBL) and 16 U{sub 3}Si{sub 2} samples provided by CC of IPEN/CNEN-SP. The chemometrics is a promising method to determination of minor and major constituents on the U3Si2 and U3O8 basis nuclear fuel, because the precision and accuracy are statistically equal volumetric analysis, gravimetric and ICPOES methods. (author)

  14. Chemical characterization of composites developed from glycerol and dicarboxylic acids rein forced with piassava fiber; Caracterizacao quimica de compositos desenvolvidos a partir do glicerol e acidos dicarboxilicos reforcados com fibra de piacava

    Energy Technology Data Exchange (ETDEWEB)

    Miranda, Cleidiene S.; Oliveira, Jamerson C.; Guimaraes, Danilo H.; Jose, Nadia M., E-mail: cleidienesm@gmail.com [Universidade Federal da Bahia, Instituto de Quimica, GECIM - Programa de Pos-Graduacao em Engenharia Quimica, Salvador, BA (Brazil); Carvalho, Ricardo F. [Universidade Federal da Bahia, Escola Politecnica, Mestrado em Engenharia Ambiental Urbana, Salvador, BA (Brazil)

    2011-07-01

    In search of alternative technologies that enable the use of products with lower environmental impact, This study aims to develop a composite polymer-based piassava fiber. The sludge, waste and byproduct of commercial uses currently being used as reinforcement in polymer matrices, due to presence of lignocellulosic materials. The matrix polymer used was synthesized from glycerol with dicarboxylic acids, in order to open future perspectives on the use of glycerin generated from purified biodiesel production plastics. Composites with 2, 5, 10 wt% of piassava fiber cut into 5 mm raw and treated were obtained a mixture of solution. The materials were characterized by TGA, DSC, XRD and SEM. It was observed that the material under study is promising for the industrial market, because it has good compatibility with natural fibers allowing wider application of fiber natural and glycerol, producing semicrystalline composites and with good thermal properties. (author)

  15. Characterization and zircon SHRIMP U-Pb geochronology of the subvolcanic rocks from Yarumalito Porphyry System, Marmato District, Colombia; Caracterizacao e geocronologia SHRIMP U-Pb em zircao das rochas subvulcanicas do sistema porfiro Yarumalito, Distrito de Marmato, Colombia

    Energy Technology Data Exchange (ETDEWEB)

    Henrichs, Isadora A.; Frantz, Jose Carlos; Marques, Juliana C.; Castoldi, Marco S., E-mail: isahenrichs@gmail.com, E-mail: jose.frantz@ufrgs.br, E-mail: juliana.marques@ufrgs.br [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil). Instituto de Geociencias; Ordonez-Carmona, Oswaldo, E-mail: oswaldo.geologo@gmail.com [Universidad Nacional de Colombia, Medellin (Colombia). Facultad de Minas; Sato, Kei, E-mail: keisato@usp.br [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Centro de Pesquisas Geocronologicas

    2014-09-15

    The mining District of Marmato, located in the Central Cordillera, is considered one of the oldest gold districts in Colombia and its exploration dates back to the Inca’s times, being exploited regularly for more than a thousand years. Inserted in this context lies the Yarumalito porphyry system (YPS), characterized to concentrate ore in structure related veins and stockworks. The YPS is related to the Miocene magmatism of the Combia Formation. In this paper, the subvolcanic rocks directly associated with the mineralized zones were described in order to obtain U-Pb ages in zircon to the intrusions. Selected samples from two fertile intrusions, one andesitic (more abundant in the area) and other dioritic (more restricted), were carefully described and dated by SHRIMP. The results points to a very restricted interval for the ages, with weighted average {sup 206}Pb/{sup 238}U varying from 7,00 ± 0,15 Ma for the andesitic porphyry and 6.95 ± 0.16 Ma for the dioritic porphyry. These results constrain the Yarumalito system to the final stages of the Combia magmatism and suggest a brief period for the crystallization of the mineralized subvolcanic rocks in the area and in the Marmato District. (author)

  16. Development of methodology for characterization of cartridge filters from the IEA-R1 using the Monte Carlo method; Desenvolvimento de uma metodologia para caracterizacao do filtro cuno do reator IEA-R1 utilizando o Metodo Monte Carlo

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Priscila

    2014-07-01

    The Cuno filter is part of the water processing circuit of the IEA-R1 reactor and, when saturated, it is replaced and becomes a radioactive waste, which must be managed. In this work, the primary characterization of the Cuno filter of the IEA-R1 nuclear reactor at IPEN was carried out using gamma spectrometry associated with the Monte Carlo method. The gamma spectrometry was performed using a hyperpure germanium detector (HPGe). The germanium crystal represents the detection active volume of the HPGe detector, which has a region called dead layer or inactive layer. It has been reported in the literature a difference between the theoretical and experimental values when obtaining the efficiency curve of these detectors. In this study we used the MCNP-4C code to obtain the detector calibration efficiency for the geometry of the Cuno filter, and the influence of the dead layer and the effect of sum in cascade at the HPGe detector were studied. The correction of the dead layer values were made by varying the thickness and the radius of the germanium crystal. The detector has 75.83 cm{sup 3} of active volume of detection, according to information provided by the manufacturer. Nevertheless, the results showed that the actual value of active volume is less than the one specified, where the dead layer represents 16% of the total volume of the crystal. A Cuno filter analysis by gamma spectrometry has enabled identifying energy peaks. Using these peaks, three radionuclides were identified in the filter: {sup 108m}Ag, {sup 110m}Ag and {sup 60}Co. From the calibration efficiency obtained by the Monte Carlo method, the value of activity estimated for these radionuclides is in the order of MBq. (author)

  17. Study and characterization of dosimeter LiF:Mg,Cu,P for using in aeronautical dosimetry; Estudo e caracterizacao do dosimetro de LiF:Mg,Cu,P para utilizacao em dosimetria aeronautica

    Energy Technology Data Exchange (ETDEWEB)

    Flavia, Hanna, E-mail: hannasantana.f@gmail.com [Universidade Paulista (UNIP), Sao Jose dos Campos, SP (Brazil); Federico, Claudio; Lelis, Odair; Pereira, Heloisa; Pereira, Marlon, E-mail: claudiofederico@ieav.cta.br [Instituto de Estudos Avancados (EFA-A/IEAV), Sao Jose dos Campos, SP (Brazil). Div. de Fisica Aplicada

    2014-07-01

    The effects of cosmic ionizing radiation incidents in aircraft components and crews has been a source of concern and motivated increasingly studies and improvements in the area. The low dose rates involved in this radiation field in aircraft flight altitudes imply Dosimetric necessity of using materials with high efficiency of detection, to enable studies lower cumulative doses resulting in shorter routes or lower altitude. The choice of thermoluminescent dosimeters LiF: Mg, Cu, P was done by having a detection efficiency of about fifteen times higher than its predecessor (LiF: Mg, Ti), and therefore, applied in very low doses dosimetry, and environmental dosimetry . The implementation of the use of pair dosimetric TLD-600H and 700H-TLD will serve as support for testing and studies on the effects of low doses of cosmic radiation in environmental dosimetry applied in the aviation environment in the usual flight altitudes. In this paper are presented the results of development of a methodology for dosimetry low doses of gamma radiation and neutrons using the pair dosimetric TLD-600H and 700H-TLD. The results demonstrate a sensitivity of dosimeters well above the dosimeters LiF: Mg, Ti confirming its suitability for dosimetry of low doses.

  18. Characterization of dispersion of a nano composites PP/TiO{sub 2} non modified; Caracterizacao da dispersao dos nanocompositos de PP/TiO{sub 2} nao modificados

    Energy Technology Data Exchange (ETDEWEB)

    Soares, Igor L.; Tavares, Maria I.B.; Silva, Vanessa A. da; Legramanti, Cintia, E-mail: igorl@ima.ufrj.br [Universidade Federal do Rio de Janeiro - UFRJ, Instituto de Macromoleculas - IMA (Brazil); Luetkmeyer, Leandro [Universidades Federais do Mato Grosso - UFMT, Escritorio de Inovacao Tecnologica - EIT (Brazil)

    2011-07-01

    Polymeric nano composites are composite materials where an inorganic particle, which has a dimension in the nanometer range, is dispersed in a polymer matrix. Nano composites, using polypropylene (PP) as matrix polymer and titanium dioxide (TiO{sub 2}) as filler, have great versatility in marketing applications, this factor is inherent in the PP and the inherent ability photo degraded TiO{sub 2} particles. This combination can lead to a widely used material and a degradation time after discharge reduced, there by becoming, a residue of low environmental impact. This study aimed to evaluate the dispersion and particle distribution of TiO{sub 2}, non modified, in PP matrix, using the process of preparation by melt extrusion pathway and characterization of the materials obtained: on the molecular dynamics, using low field NMR solid state, measures the relaxation time spin-network (T{sub 1}H); morphology using XRD technique, and thermal analysis technique with the TGA of pure PP and nano composites PP/TiO{sub 2}. (author)

  19. Development of a pilot fluidized bed combustion to NOx reduction using natural gas: characterization and dimensioning; Desenvolvimento de um combustor piloto a leito fluidizado para reducao de NOx usando gas natural: caracterizacao e dimensionamento

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Douglas A.; Lucena, Sergio [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil)

    2004-07-01

    At the present time, the operation of combustion systems and the design of combustors continue being important problems in the Engineering, and don't involve just the size increase of combustors, but also changes of characteristics in the details of projects. The combustors applications are directly related to the needs, like: material transformation for heating, drying or incineration; and all have the inconvenience of emanating of pollutant gaseous (such like NOx). In combustion systems of gases, NOx is basically created in the reaction between nitrogen and oxygen to high temperatures ({approx} 1200 deg C). Below such conditions, the contribution of thermal NOx is recognisably small. The efficient reduction, safe control and economical elimination of pollutant emissions in the systems of burning are the main focuses of environmental legislation and concern to several industrialized countries, besides Brazil. Furthermore, in appeal at the Environmental Laws and at the rising consumption of combustible gases (Natural Gas), new technologies more attractive and economically viable have been studied, for example the combustion systems in fluidized bed. In this kind of system is possible to obtain high combustion efficiency at low temperatures ({approx} 900 deg C) with NOx reduction. In this work is intended of characterizing and dimensioning an industrial fluidized bed combustor that uses Natural Gas like feedstock in the combustion system, with smaller amounts of emitted NOx. (author)

  20. Lighting measurement station: measurements of natural lighting for characterization of sky and zenith illuminance; Estacao de medicao de iluminacao: medicao de niveis de iluminacao natural para caracterizacao de iluminancias de ceu e luminancia de zenite

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Roberta Vieira Goncalves de [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Escola de Arquitetura. Dept. de Tecnologia da Arquitetura e do Urbanismo]. E-mail: roberta@arq.ufmg.br; Pereira, Fernando Oscar Ruttkay [Santa Catarina Univ., Florianopolis, SC (Brazil). Dept. de Arquitetura. Lab. de Conforto Ambiental]. E-mail: feco@arq.ufsc.br

    2002-07-01

    This paper describes the assembly of a standard station for measuring the day lighting for evaluation of the natural light availability. The mounting and data obtention form will also be described from a standard IDMP day lighting station for measuring the data from measuring zenith, horizontal, and vertical illuminance of the sky and vertical irradiance for the cardinal points.

  1. Polymers and composites synthesis and characterization for application on PEM type fuel cells; Sintese e caracterizacao de polimeros e compositos para aplicacao em celulas a combustivel do tipo PEM

    Energy Technology Data Exchange (ETDEWEB)

    Fiuza, Raigenis da Paz; Souza, Daniele Ribeiro; Barreto, Ednardo Gomes; Boaventura Filho, Jaime Soares; Jose, Nadia Mamede [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil)]. E-mail: raigenis@gmail.com

    2006-07-01

    The PEM (proton exchanging membrane) type fuel cell presents good potential for the energy production without the residue generation. However, its manufacture presents high costs for commercial application, mainly due to the electrolyte. Sulfonated Peek (polish-ether-ether-ketone) supported or auto immobilized the in a silicone matrix is an interesting alternative as electrolyte for PEM fuel cells. The commercial PEEK in powder form was functionalized with sulfuric acid, giving the SPEEK (Sulfonated PEEK). The membranes were produced by hot pressing the SPEEK immobilized in a silicone matrix produced by the sol-gel process. The membranes obtained were characterized by DRX, FTIR, TGA, MEV, DSC and protonic conductivity measurements. (author)

  2. Microstructural characterization of industrial foams by gamma ray transmission and X-ray microtomography; Caracterizacao microestrutural de espumas industriais por transmissao de raios gama e microtomografia de raios X

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Luiz Eduardo

    2004-07-01

    This work presents the total porosity measurements of the aluminum and silicon carbide (SiC) foams samples. For porosity determination the gamma ray transmission and X-ray microtomography with conic beam techniques were used. These methods have more advantage than conventional ones, because they are non destructive and provide more details of the analyzed material porous structure. The aluminum foam samples with 10, 20, 30, 40 and 45 ppi (pores per inch) and SiC ceramic foam samples with 20, 30, 45, 60, 75, 80 and 90 ppi were analysed by gamma transmission. The SiC 60, 75 and 90 ppi samples were also analyzed by X-ray microtomography. For the gamma ray transmission measurements it was used an {sup 241} Am source (59.53 keV), a NaI(Tl) scintillation detector, collimators, a XYZ micrometric table and standard gamma spectrometry electronics connected to a multichannel analyzer, at the LFNA/UEL. For the X-ray microtomographic measurements, the Fein Focus X-ray system of the Nuclear Instrumentation Laboratory of the COPPE, located at the Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ, was used. This equipment provide us images with micrometric resolution (53.48 {mu}m) using a conic X-ray beam and bidimensional detection. The microtomographic images were pre-processed and analyzed by the Imago software, developed at Porous Media and Materials Thermophysical Properties Laboratory (LMPT) of the Mechanical Engineering Department, located at Universidade Federal de Santa Catarina, Florianopolis, SC. Employing the The Imago software it was calculated the total porosity, pore size distribution and autocorrelation function C(u) of the binarized microtomographic images of the each sample. The microtomographic 3-D image of each sample was compared with 3-D image reconstructed by the Gaussian truncated method. This method generates a periodic 3-D porous structure by using of the autocorrelation function of one 2-D cross sectional image of the sample. (author)

  3. {sup 1}H-NMR characterization of cellulose acetate obtained from sugarcane bagasse; Caracterizacao de acetato de celulose obtido a partir do bagaco de cana-de-acucar por {sup 1}H-RMN

    Energy Technology Data Exchange (ETDEWEB)

    Cerqueira, Daniel A., E-mail: daniel.cerqueira@ufba.b [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Ciencias Ambientais e Desenvolvimento Sustentavel; Rodrigues Filho, Guimes [Universidade Federal de Uberlandia (UFU), MG (Brazil). Inst. de Quimica; Carvalho, Rui de A. [Universidade de Coimbra (Portugal). Dept. de Bioquimica; Valente, Artur J.M. [Universidade de Coimbra (Portugal). Dept. de Quimica

    2010-07-01

    Cellulose from sugarcane bagasse was used for synthesizing cellulose acetate with different degrees of substitution, which were characterized by {sup 1}H-NMR through the relationship between the peak areas of the hydrogen atoms of the acetate groups (-(C=O)OCH{sub 3}) and the peaks of the hydrogen bonded to the carbon atoms of the glycosidic rings. Suppression of some signals was carried out in order to remove the residual water resonance in the materials and those related to impurities in cellulose triacetate as well. A deconvolution method for the computation of the degree of substitution of acetylation is proposed. The degrees of substitution for the cellulose samples were 2.94 and 2.60, in good agreement with those obtained by chemical determination through an acid-base titration. (author)

  4. ETBP (Extended True Boiling Point) curve extension of extra heavy crudes; Extensao da curva PEV (Ponto de Ebulicao Verdadeiro) de petroleos extrapesados por destilacao molecular e ampliacao da caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Rodrigo S.; Batistella, Cesar B.; Maciel, Maria Regina W.; Maciel Filho, Rubens [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Faculdade de Engenharia Quimica; Medina, Lilian C. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2008-07-01

    For the determination of the TBP (True Boiling Point) Curve, which defines the yield of petroleum products, the ASTM D2892 method for petroleum distillation and ASTM D5236 method for vacuum distillation of heavy hydrocarbons were applied. Furthermore, from these distillations, cuts that are submitted to several analyses to determine its physical-chemical properties are obtained, and all this information generates the evaluation of petroleum. For heavy petroleum, these conventional methods have been limited, since the total distilled percentage determined for temperatures up to 565 deg C (maximum reached with ASTM D5236 method) is lower for these oils, reducing the points of the curve, limiting its information. To improve this data set for heavy oils, a methodology for the extension of TBP curve through molecular distillation was established. It was possible to reach values up to 700 deg C, representing a considerable progress for the extension of TBP curve. The objective of this work is to present the results of Extended TBP curve for a heavy petroleum and characterization carried out through the cuts and residues obtained in molecular distillation of the residue 'Zeta' 400 deg C+ (fancy name), made by ASTM D2892 method. (author)

  5. Micellar copolymerization of poly(acrylamide-g-propylene oxide): rheological evaluation and solution characterization; Copolimerizacao micelar de poli(acrilamida-g-oxido de propileno): avaliacao reologica e caracterizacao de suas solucoes

    Energy Technology Data Exchange (ETDEWEB)

    Sadicoff, Bianca L.; Brandao, Edimir M.; Lucas, Elizabete F. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Inst. de Macromoleculas]. E-mail: elucas@ima.ufrj.br; Amorim, Marcia C.V. [Universidade Estadual, Rio de Janeiro, RJ (Brazil). Inst. de Quimica

    2001-06-01

    Graft copolymers of polyacrylamide and poly(propylene oxide) were synthesized by a micellar copolymerization technique. The rheological properties of the copolymers solutions were evaluated and compared with literature data for solutions of the same copolymers, synthesized by solution polymerization. The effect of hydrophobe content, salt addition and surfactant addition on the rheological properties were also investigated. Increasing hydrophobe content resulted in higher solution viscosities in the semi-dilute regime. Upon addition of salts, the hydrophobic groups associated to minimize their exposure to water. In the semi-dilute region, higher contents of surfactant added resulted in lower reduced viscosities of the polymer solutions. The copolymers were qualitatively characterized by infra-red spectrometry. (author)

  6. Isotopic characterization of metabasites and amphibolites of the Acungui and Setuva Groups at the southern portion of de Ribeira Belt; Caracterizacao isotopica de metabasitos e anfibolitos dos Grupos Acungui e Setuva na porcao sul da Faixa Ribeira

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Marcos Aurelio Farias de; Daitx, Elias Carneiro [Universidade Estadual Paulista (UNESP), Rio Claro, SP (Brazil). Dept. de Petrologia e Metalogenia; Maniesi, Vanderlei [Universidade Federal de Rondonia (UNIR), Porto Velho (Brazil); Teixeira, Wilson [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias. Centro de Pesquisas Geocronologicas

    2002-12-15

    Pb, Rb, Sr, Sm and Nd isotope analyses were carried out on amphibolitic rocks from Campo Largo (PR), Rio Branco do Sul (PR) and Adrianopolis (PR) and for the metabasite from Adrianopolis and Apiai (SP), all belonging to the Acungui and Setuva Groups, southern portion of the Ribeira Belt. These occurrences were chosen because each exhibits geochemical data indicative of a mantle source, having different signatures. Geochronologic determinations are available only for the Apiai metagabro with Neoproterozoic ages of 617 +- 4 Ma (U/Pb in zircon) and 839 +- 85 Ma (Rb/Sr, whole rock). Age determinations by Sm/Nd mineral isochron using whole rock, plagioclase and pyroxene yield values of 885 +- 53 Ma for the Apiai metagabro and 820 +- 84 Ma for the Adrianopolis metabasite. These results agree within error with the Rb/Sr isochron of 839 +- 85 Ma may possibly be interpreted as the time of extraction of the magma from the mantle, as suggested by positive epsilon{sub Nd(850)} values (+2,76) from an Adrianopolis sample. An epsilon{sub Nd} values versus 87 Sr/86 Sr diagram shows that each studied occurrence plots in a different position, following approximately the mantle array trend, the most primitive being the metabasite of Adrianopolis, near the MORB field, and the most enriched being the amphibolite from the same region, near the enriched mantle and or crustal contamination field. The distinct difference in isotopic signatures between the amphibolite and metabasite suggest derivation from different mantle sources, as supported by available geochemical data. Nevertheless, some of the samples show isotopic evidence of the action of metamorphism, crustal contamination and weathering. (author)

  7. Characterization of a Planetary Boundary Layer model to evaluate radionuclides releases in nuclear installations; Caracterizacao de um modelo de camada limite planetaria para avaliar liberacoes de radionuclideos em instalacoes nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Molnary, Leslie de

    1993-07-01

    A two layer bulk model is used to simulate numerically the time and spatial evolution of concentration of radionuclides in the Planetary Boundary Layer (PBL) for convective and stable conditions. In this model, the closure hypothesis are based on the integrated version of the Turbulent Kinetics Energy (TKE) equation (Smeda,1979). This type of model was adopted here because it is numerically simple to be applied operationally in routine and emergency support systems of atmospheric releases at nuclear power plants, and the hypothesis of the efficiency of the vertical mixing seems to be physically reasonable to simulated PBL evolution for high wind conditions and stable conditions in Subtropical latitudes regions. In order to validate the model to the nuclear power plants of the Centro Experimental Aramar (CEA), located in Ipero, State of Sao Paulo, Brazil, numerical simulations were carried out with initial and boundary conditions based on vertical profiles of temperature and horizontal wind speed and direction obtained from tethered balloon soundings, synoptic charts at 850 hPa and surface observations. Comparisons between a 24 hour long numerical simulation and observations indicate that the model is capable of reproduce the diurnal evolution of temperature and horizontal wind during the convective regime. During stable conditions, the slab model was able to simulate the intensity of the surface inversion as a difference between the mixed layer and surface temperatures. The simulated mixed layer height matches with observations during the convective and stable regime. A daytime release of radionuclides was simulated for CEA region and the results indicated that the maximum relative concentration reaches a distance about 15 Km in 1 hour, varing from 100 times background at the moment of the release to 15 times the background. For night releases, the maximum concentration reaches the same distance in 45 minutes, varing from 100 to 30 times the background values. (author)

  8. Petrographic characterization and preliminary lithogeochemistry of albitites from Folha Bramado, northwest of Bahia state, Brazil; Caracterizacao petrografica e litogeoquimica preliminar dos abititos da Folha Brumado - NW do estado da Bahia, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Burgos, Cristina Maria; Pinho, Ivana Conceicao de Araujo; Martins, Adriano Alberto Marques; Teixeira, Leo Rodrigues; Oliveira, Rita Cunha Leal Menezes de; Cruz Filho, Basilio Elesbao da; Wosniak, Ricardo, E-mail: cristina.burgos@cprm.gov.br, E-mail: ivana.pinho@cprm.gov.br, E-mail: adriano.martins@cprm.gov.br, E-mail: leo.teixeira@cprm.gov.br, E-mail: rita.oliveira@cprm.gov.br, E-mail: basilio.filho@cprm.gov.br, E-mail: ricardo.wosniak@cprm.gov.br [Servico Geologico do Brasil (CPRM), Salvador, BA (Brazil). Superintendencia Regional

    2011-07-01

    The mapping geological works carried out by CPRM, in the scope of the Brumado-Condeuba Project, had proceeded to the sampling from granitoids in the 'Folha Brumado'. The majority of the samples were classified as biotite gneiss and two of them recognized as albitites. Lithogeochemical data had proved that the rocks are alkaline, metaluminous, potash-rich (except for the two classified as albitites that are soda-rich), enriched in rare earth elements, with negative anomaly in europium and typical standards of A-type granitoids. They had been located in the field of the within-plate granites in the discrimination diagrams for the tectonic interpretation. The albitites of the 'Folha Brumado' are similar to the albitites that had been described in the Uranium Province of Lagoa Real. (author)

  9. Structural characterization and photocatalytic analysis of BaFe{sub 2}O{sub 4} obtained at low temperatures; Caracterizacao estrutural e analise fotocatalitica de BaFe{sub 2}O{sub 4} obtido via sintese por combustao

    Energy Technology Data Exchange (ETDEWEB)

    Da Dalt, S.; Sousa, B.B.; Alves, A.K.; Bergmann, C.P., E-mail: silvana.da.dalt@ufrgs.b [Universidade Federal do Rio Grande do Sul (LACER/UFRGS), Porto Alegre, RS (Brazil). Dept. de Materiais. Lab. de Materiais Ceramicos

    2010-07-01

    Barium monoferrite BaFe{sub 2}O{sub 4} classified as permanent magnet stands out among other ceramic magnets due to its high chemical stability, corrosion resistance and low production cost. In addition, experiments conducted on photocatalytic degradation of methyl orange and UV transmittance by spectrophotometry showed that this material has photocatalytic properties. The spinel ferrite has importance in many technological areas as computing, communication and security. Many techniques for synthesis were studied to optimize the properties of this material. The synthesis of BaFe{sub 2}O{sub 4} by conventional processes often occurs at temperatures above 1000 deg C. In this work we obtained the phase BaFe{sub 2}O{sub 4} at low temperatures (600 deg C) from the combustion reaction using nitrates and maleic anhydride as metal complexing agent. Techniques of X-ray diffraction, specific surface area, thermogravimetry analysis and analysis photocatalytic were employed to characterize the products obtained. (author)

  10. Characterization of ceramic electrical insulators discarded by the electricity distribution networks and compared with similar products without use; Caracterizacao dos isoladores eletricos ceramicos descartados pelas redes de distribuicao de eletricidade e comparacao com produtos similares sem uso

    Energy Technology Data Exchange (ETDEWEB)

    Franco, C.S.; Mantovani, V.A.; Favero, M. [Universidade Estadual Julio de Mesquisa Filho (UNESP), Sorocaba, SP (Brazil); Morales, J.; Hasegawa, H.L. [2-Universidade de Sorocaba (UNISO), SP (Brazil)

    2010-07-01

    The maintenance of distribution networks for electricity generates a large amount of waste. Among these, one of the most representative weights is from porcelain, found in para-rays, braces, insulators. The aim of this study was to evaluate the recycling potential of two models of ceramic insulators, new and used. It had been subjected to comparative tests of scanning electron microscopy, coupled with Energy Dispersive Spectroscopy, x-ray diffraction, contact angle, volatile content and density. In general, samples of new and used ceramic showed no differences that might be associated of material degradation by using. This indicates that the materials discarded and new ones are very close, which may encourage the reuse and recycling. (author)

  11. Technological characterization of clays from the city of Anapolis. Goias, Brazil, for the usage in ceramic products; Caracterizacao tecnologica de argilas do municipio de Anapolis, Goias, Brasil, para a utilizacao em produtos ceramicos

    Energy Technology Data Exchange (ETDEWEB)

    Chrispim, Z.M.P.; Alves, M.G.; Ramos, I.S.; Silva, A.L.; Fraga, F.A., E-mail: lezira@ig.com.b [Universidade Estadual do Norte Fluminense Darcy Ribeiro (LECIV/CCT/UENF), Campos dos Goytacazes, RJ (Brazil). Engenharia Civil; Almeida, L.L.P. de [Universidade Estadual do Norte Fluminense Darcy Ribeiro (LAMAV/CCT/UENF), Campos dos Goytacazes, RJ (Brazil). Lab. de Materiais Avancados

    2010-07-01

    The city of Annapolis is located 48 kilometers from the capital, Goiania, in Goias Center Mesorregion, which forms part of the Annapolis-Brasilia-Goiania axis, with an economy focused on manufacturing industry, pharmaceuticals, ceramics, wholesale and automobile industry, having a population of 335, 960 inhabitants (IBGE, 2009). The objective of this work is the physical and mineralogical characterization of three samples of clay of that region. The clays were characterized by granulometry determining distribution, Atterberg limits, chemical composition, X-ray diffraction and differential thermal analysis and thermogravimetry. Samples (cps) were obtained by extrusion and fired at 750 deg, 950 deg and 1050 deg C. After the burning process it was determined the water absorption, bending rupture's modulus. The analyzed results show the physical and mineralogical composition of raw materials and concluded that this characterization allows to estimate that the three samples are appropriate or not for the production of ceramic products.(author)

  12. Hardness and microstructural characterization of API 5L X70 steel pipes welded by HF/ERW process; Caracterizacao microestrutural e de dureza em tubos de aco API 5L X70 soldados pelo processo HF/ERW

    Energy Technology Data Exchange (ETDEWEB)

    Calcada, Mauricio Vieira; Voorwald, Herman Jacobus Cornelis; Nascimento, Marcelino Pereira do [UNESP, Guaratingueta, SP (Brazil). Faculdade de Engenharia

    2010-07-01

    The materials that stand in the manufacture of steel pipes are called API, that should have, high mechanical resistance, high corrosion resistance, high fatigue resistance, good weldability, and other properties. Thus, the purpose of this project was to evaluate the microstructure and hardness of welded joints by the HF/ERW process of API 5L X70 steel pipes. The microstructural analysis was performed using a surface finish with grit sizes from 220 to 25 {mu}m e polishing with diamond paste from 9 {mu}m to 0.05 {mu}m; the revelation was made with 3% Nital attack. The Vickers hardness was performed across the welded joint by 33 points to indentation. The results were: 80.5 {+-} 3.4% of ferrite and 19.5 {+-} 3.4% of perlite for microanalysis. As for hardness, the values were: 215.69 HV10 for weld line, 218.65 HV10 for ZTA and 218.95 HV10 for base metal. (author)

  13. Synthesis and characterization of M-type barium hexferrite by ultrasonic inter-dispersion of chemical precipitate; Sintese e caracterizacao de hexaferrita de bario tipo M por interdispersao ultrassonica de precipitado quimico

    Energy Technology Data Exchange (ETDEWEB)

    Garcia Junior, E.S.; Gomes Junior, G.G.; Ogasawara, T., E-mail: edil@metalmat.ufrj.b [Universidade Federal do Rio de Janeiro (COPPE/UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia. Dept. de Eng. Metalurgica e Materiais

    2010-07-01

    This work is concerned with the study the synthesis and characterization of M-type barium hexaferrite powder by chemical precipitation type and ultrasonic interdispersion of precursor materials Fe(OH){sub 3} and Ba(OH){sub 2},separately and ultrasonic inter-dispersion, followed by drying and calcining. In order to guide the experimental work was carried out a preliminary thermodynamic analysis of the system Ba-Fe-H{sub 2}O at 25 deg C. The study shows that the phase formation of M-type barium hexaferrite is obtained at a calcination at 1000 deg C, characterized by X-ray diffraction, the grain growth of the final product of synthesis depending on the calcination temperature is visible by SEM. The synthesis method developed in this research is an option to achieve the results that would be obtained if the co-precipitation of ferric and barium hydroxide was thermodynamically possible, where you can get crystallization of barium hexaferrite in a calcination at 1000 deg C. (author)

  14. Project, construction and characterization of ionization chambers for use as standard systems in X and gamma radiation beams; Projeto, construcao e caracterizacao de camaras de ionizacao para utilizacao como sistemas padroes em feixes de radiacao X e gama

    Energy Technology Data Exchange (ETDEWEB)

    Perini, Ana Paula

    2013-07-01

    Ionization chambers present some advantages in relation to other dosimeters: easiness of handling, low energy dependence and high precision. The advantages associated to ionization chambers and the large number of diagnostic radiology exams and therapeutic treatments motivated the development of this PhD program. In this project ionization chambers were developed and characterized to be applied in diagnostic radiology and therapy beam dosimetry, with high precision and performance, in compliance with international recommendations. They were assembled in a simple way, utilizing low-cost national materials, so they can be reproduced and applied at calibration laboratories. The project of these ionization chambers presents some differences in relation to commercial ionization chambers, as the materials utilized and geometrical arrangements. Besides the development of the ionization chambers to be utilized in standard X-ray beam dosimetry as work standard systems, two graphite parallel-plate ionization chambers were developed and characterized to be applied as reference standard systems for determining the air kerma rates of gamma radiation sources. Comparing the air kerma rates determined with the reference standard of the Calibration Laboratory of IPEN, a Farmer ionization chamber, with the values of the air kerma rates obtained with the graphite ionization chambers, the maximum differences obtained were only 1.7% and 1.2% for the G1 and G2 graphite ionization chambers, respectively. Moreover, these ionization chambers presented correction factors close to 1.000, which is ideal for an ionization chamber be characterized as a reference standard system. (author)

  15. Microstructural characterization of IF steel after severe plastic deformation via ARB and subsequent heat treatment; Caracterizacao microestrutural de um aco IF apos deformacao plastica severa via ARB e posterior recozimento

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, F.C.; Abrantes, A.L.A.; Lins, J.F.C., E-mail: cristinafo2@hotmail.co [Universidade Federal Fluminense (PPGEM/UFF), Volta Redonda, RJ (Brazil). Programa de Pos-graduacao em Engenharia Metalurgica

    2010-07-01

    This study aimed to evaluate the microstructural evolution of a titanium stabilized IF steel deformed to warm through the ARB process for 5 consecutive cycles and then annealing at 600 deg C for 1 h. The material was characterized with the aid of the techniques of scanning electron microscopy and electron backscatter diffraction (Electron Backscatter Diffraction - EBSD). An intense process of microstructural refinement was observed in the deformed material and the phenomenon of dynamic recovery was predominant. It can be concluded that the annealing of severely deformed material was not sufficient for a complete recrystallization of the microstructure. (author)

  16. Characterization of jade and silicates of the jade family for application in radiation dosimetry; Caracterizacao do jade e dos silicatos da familia do jade para aplicacao em dosimetria das radiacoes

    Energy Technology Data Exchange (ETDEWEB)

    Melo, Adeilson Pessoa de

    2007-07-01

    The main dosimetric properties of jade and of Brazilian silicates of the jade family were studied for application in radiation dosimetry of high doses. Jade is a common denomination of two different silicates: jadeite, Na Al(Si{sub 2}O{sub 6}), and nephrite, Ca{sub 2}(Mg, Fe){sub 5}(Si{sub 4}O{sub 11}){sub 2} (OH){sub 2}, that belong to the subclasses of the pyroxenes and amphiboles respectively. The jade samples studied in this work were from: Austria, New Zealand, United States and Brazil. The Brazilian silicates of the jade family studied in this work were the amphiboles: tremolite,Ca{sub 2}Mg{sub 5}(Si{sub 4}O{sub 11}){sub 2}(OH){sub 2} e actinolite, Ca{sub 2}Fe{sub 5}(Si{sub 4}O{sub 11}){sub 2}(OH){sub 2}; and the pyroxenes: rhodonite, MnSiO{sub 3} and diopside, Ca Mg(Si{sub 2}O{sub 6}). The mineralogical and chemical composition of these materials were obtained using the neutron activation analysis and X-ray diffraction techniques. The main dosimetric properties (emission curves, calibration curves, reproducibility, lower detection limits, angular and energy dependence, etc) were studied using the thermoluminescent (T L), thermally stimulated exo-emission (TSEE) and electronic paramagnetic resonance (EPR) techniques. The jade-Teflon and the silicate-Teflon samples present two T L peaks around 115 deg C (peak 1) and 210 deg C (peak 2). The calibration curves of the studied materials present a linear behaviour between 0.5 Gy and 1 kGy. The TSEE emission peak occurs at 240 deg C for all samples, and the calibration curves present a sub linear behaviour between 100 Gy and 20 kGy. In the case of the EPR technique, only jade USA has a potential application for radiation dosimetry. A static computational simulation of the most probable intrinsic and extrinsic defects in rhodonite was also realized. Among the basic defects, the Schottky defects of rhodonite are the most probable to occur and, among the extrinsic defects, the divalent and trivalent dopants present the best possibility of inclusion in rhodonite. (author)

  17. Proposal of a methodology to be applied for the characterization of external exposure risk of employees in nuclear medicine services; Proposta de uma metodologia para caracterizacao de risco de exposicao externa de funcionarios de servicos de medicina nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Simoes, Rafael Figueiredo Pohlmann

    2010-07-01

    Nuclear medicine procedure requires the administration of radioactive material by injection, ingestion or inhalation. After incorporation, the patient becomes a mobile source of radiation and, after their examination; they can irradiate everyone on their way out of the Nuclear Medicine Service (NMS). A group of workers in this path is considered a critical group, but there are no conviction on this classification, because there are not measurements available. Thus, workers claiming for occupationally exposed individual's (OEI) rights are common. Employers are always in a complex situation, because if they decided to undertake the individual external monitoring of the critical working groups, the Court considers all as OEI and employers are taxed. On the other hand, if they do not provide monitoring, it is impossible to prove that these workers were not exposed to effective doses higher than individual annual public's limit and they lose the actions, too. This work proposes a methodology to evaluate, using TLD environmental monitors, air kerma rate at critical staff points in a NMS. This method provides relevant information about critical groups' exposure. From these results, the clinic or hospital may prove technically, without individual monitoring of employees, the classification of areas and can estimate the maximum flow of patients in the free areas which guarantees exposures below the public individual dose limit. This methodology has been applied successfully to a private clinic in Rio de Janeiro, which operates a NMS. The only critical group that received exposure statistically different from clinic background radiation was that on the antechamber of the NMS. This is a site that should be characterized as a supervised area and the group of workers in this environment as OEI, as the estimated extrapolated annual effective dose in this position was 1.2 +- 0.7 mSv/year, above the public annual limit (1,0 mSv/year). Normalizing by the number of patients, it can be seen that on average each patient contributes to the effective dose with about 1.0 {mu}Sv at this point, considering the conditions of the clinic at the time of analysis. Therefore, the maximum number of patients that could be attended in this area as a free area would be 1000 patients per year. (author)

  18. Combustion synthesis by reaction and characterization of nano ferrites: study of fuel aniline, citric and its mixture; Sintese por reacao de combustao e caracterizacao de nanoferritas Ni-Zn: estudo dos combustiveis anilina, acido citrico e sua mistura

    Energy Technology Data Exchange (ETDEWEB)

    Silva, M.C. da; Coutinho, J.P.; Costa, A.C.F.M., E-mail: normanda@ufcg.edu.br [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais; Kiminami, R.H.G.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Departamento de Engenharia de Materiais; Freitas, N.L. de [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Tecnologia do Desenvolvimento

    2012-07-01

    The present study aims to evaluate the influence of aniline and citric acid used alone and combined in a ratio of 50% each in the characterization of NiZn ferrite synthesized by combustion reaction method in a muffle furnace. Measurements were made of temperature and reaction time. The nano-powders were characterized by XRD, EDX, textural analysis and SEM. The highest temperature was achieved by the reaction using the mixture of fuel and increased reaction time using citric acid. The nano ferrites using different fuels, and the mixture changed phases, the crystallite size and decreased surface area of the samples with aniline, citric acid and a mixture of both, respectively. The powder morphology ranged from presenting the formation of irregular blocks for the use of citric agglomerated in the form of skeins with aniline and a mixture to agglomerate larger particles. (author)

  19. Radiation beans characterization and implantation for study of lead equivalent individual protection device used in radiodiagnostic practices; Caracterizacao e implantacao de feixes de radiacao para estudo de dispositivos de protecao individual com equivalencia em chumbo utilizados em praticas de radiodiagnostico

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Leslie Silva

    2004-07-01

    The protective shielding (IPC) must be used by occupationally exposed professionals, patients and volunteers, in order to optimize the doses who receive due to radiological practices. International and national norms establish the methodology to be adopted for determination of the IPC attenuation. In this work, the IPC had been submitted to X-rays beams with known characteristics, standardized for determination of their attenuation equivalent thickness by comparison to an experimental lead attenuation slope. This comparison technique allowed insurance estimative of the IPC attenuation equivalent thickness in mm of lead. Thus, it was possible to verify the conformity of the attenuation equivalent thickness determined experimentally and the value of the thickness indicated by the manufacturer. To carry out this work, it was necessary the implementation of experimental setups stated in the specifics norms, the study of the X-rays beams original features and the determination of combined additional filters, in order to allow the X-ray equipment used operates in compliance with Norm IEC 61331-1 IEC. The radiation quality selected is characterized by a 100 kV voltage and a 0.25 mm of copper overall filtration. The implementation of this radiation quality it was carried through of its first and second HVL (Half Value Layer). Thus, a methodology according to the international Norms has been implemented in the laboratory. The results of the present work provide suitable and useful information about radiation beams features related to the determination techniques of the attenuation properties. Once implemented the procedures for conformity evaluation of the protection devices, it will be possible to carry out specific quality control tests, which will be helpful to manufacturers, customers, as well as authorities in the radiological protection and health areas. (author)

  20. Physical-chemical properties of the gasoline-ethanol flex-fuel by infrared adsorption spectroscopy; Caracterizacao fisico-quimica do combustivel flexivel (gasolina + AEHC) por espectroscopia de infravermelho

    Energy Technology Data Exchange (ETDEWEB)

    Pires, Camila Reis; Araujo, Antonio Sousa de [Universidade Federal do Rio Grande do Norte, Natal, RN (Brazil). Dept. de Quimica. Lab. de Combustiveis e Lubrificantes

    2004-07-01

    Gasoline and ethanol are the components studied in the Flex-Fuel technology, in order to provide an innovative and alternative new option of vehicular fuel. To determine their conformity, these fuels were previously analyzed according to the following ANP regulations: density, alcoholic tenor, octane number and distillation. In order to obtain Flex-Fuel samples, the proportions of 20, 40, 60 and 80 vol% of alcohol in gasoline were mixed and homogenized. The obtained mixtures were submitted to the same analysis for evaluation of the physical-chemical behavior. The physical-chemical characterization of the Flex-Fuel was carried out by infrared spectroscopy, using an equipment Fuel Analyzer, manufactured by Petrospec model GS1000, in agreement with the MB 457, D 2700, D2699 rules, and the obtained data: MON (motor method), RON (method researches), and IAD were compared to the results of a type 'C' gasoline. In this work, infrared (IR) absorption spectroscopy showed to be a good tool to readily estimate the octane number of gasoline-ethanol fuel. From IR spectroscopy, was established a method to derive the octane number from the intensities of absorption bands related to methyl, methylene and aromatic compounds, by considering the absorption groups with C-H stretching vibration. According to the Flex-Fuel technology, the obtained results showed that the addition of moisturized ethanol increases the octane number, for instance, for each 5% of alcohol in gasoline an increase of ca. 2% in the octane was observed. (author)

  1. Preparation and physico-chemical characterization of inclusion complexes between local anesthetics and hydroxypropyl-{beta}-cyclodextrin; Preparacao e caracterizacao fisico-quimica de complexos de inclusao entre anestesicos locais e hidroxipropil-{beta}-ciclodextrina

    Energy Technology Data Exchange (ETDEWEB)

    Moraes, Carolina Morales; Abrami, Priscila; Goncalves, Marcos Moises; Andreo Filho, Newton [Universidade de Sorocaba, SP (Brazil); Fernandes, Sergio Antonio; Paula, Eneida de [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Inst. de Biologia. Dept. de Bioquimica; Fraceto, Leonardo Fernandes [UNESP, Sorocaba, SP (Brazil). Dept. de Engenharia Ambiental]. E-mail: leonardo@sorocaba.unesp.br

    2007-07-15

    S(-) Bupivacaine (S(-)BVC) and Lidocaine (LDC) are widely used local anesthetics (LA). Hydroxypropyl {beta}-cyclodextrin (HP-{beta}-CD) is used as a drug-carrier system. The aim of this work was to characterize inclusion complexes between LA and HP-{beta}-CD. The affinity constants determined at different pHs show favourable complexation. The release kinetics experiments showed that S(-)BVC and LDC changed the released profiles in the presence of HP-{beta}-CD. Nuclear magnetic resonance experiments gave information about the interaction between LA and the cyclodextrin cavity. This study focused on the physicochemical characterization of drug-delivery formulations that come out as potentially new therapeutic options for pain treatment. (author)

  2. Bee waxes: a model of characterization for using as base simulator tissue in teletherapy with photons; Ceras de abelha: um modelo de caracterizacao para sua utilizacao como tecido simulador base em teleterapia com fotons

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Rogerio Matias Vidal da; Souza, Divanizia do Nascimento

    2011-10-26

    This paper presents a model of characterization and selection of bee waxes which makes possible to certify the usage viability of that base simulator tissue in the manufacture of appropriated objects for external radiotherapy with mega volt photon beams. The work was divide into three stages, where was evaluated physical and chemical properties besides the aspects related to the capacity of beam attenuation. All the process was carefully accompanied related to the wax origin such as the bee specimen and the flora surrounding the beehives. The chemical composition of the waxes is similar to others simulators usually used in radiotherapy. The behavior of mass attenuation coefficient in the radiotherapeutic energy range is comparable to other simulators, and consequently to the soft tissue. The proposed model is efficient and allows the affirmative that the usage of determined bee wax as base simulator tissue is convenient

  3. Aging and characterization of PVC compound used as flat-panel of a low cost solar collector; Envelhecimento e caracterizacao de compostos de PVC usado em placas de coletores solares de baixo custo

    Energy Technology Data Exchange (ETDEWEB)

    Prado, Bruna R.; Pinto, Tatiana T.; Bartoli, Julio R. [Depto. de Tecnologia de Polimeros, Faculdade de Engenharia Quimica/Universidade Estadual de Campinas. FEQ/UNICAMP, SP (Brazil)], e-mail: bartoli@feq.unicamp.br; Fernandes, Elizabeth G. [Tezca P and D Celulas Solares (Brazil)

    2011-07-01

    Regardless the excellent amount of solar irradiation in Brazil, the development and production of solar water heating systems did not reach the low-income families yet. The relatively high cost of conventional solar water heaters is still the main reason to prevent it. The development of a low cost solar water heater (around US$ 200), easy technology, was the scope of previous work. All-plastic solar collector prototypes were developed using unplasticized Poly (vinyl chloride) ceiling panels and tubes, commodities from building engineering. Nevertheless, the main thermal and photo degradation mechanisms for PVC are well known; the unusual application of PVC as solar collector materials should need a specific investigation on environmental aging. This work presents a study on outdoor aging and characterization of PVC flat-plate absorber of solar collectors after 5 years on use. (author)

  4. Synthesis and characterization of polyaniline/clay conducting nanocomposites for use in protective coatings; Sintese e caracterizacao de nanocompositos condutores de polianilina/argila para utilizacao em revestimentos protetores

    Energy Technology Data Exchange (ETDEWEB)

    Baldissera, A.F.; Ferreira, C.A.; Senisse, C.A.L.; Oliveira, L.S., E-mail: alebaldissera@hotmail.co [Universidade Federal do Rio Grande do Sul (LAPOL/UFRGS), Porto Alegre, RS (Brazil). Lab. de Materiais Polimericos

    2010-07-01

    Nanomaterials have been shown highly promising materials for various technological applications. In engineering, may be noted the polymer nanocomposites, which are a new class of composite materials, where a nanoclay, or charge with nanometric dimensions, is dispersed in a polymer matrix at low concentration or volume. The clays are more common and when added in quantities less than 5% in the nanocomposites, cause a significant increase in these properties, such as mechanical, optical, magnetic barrier, and especially permeability and flammability. In this context, this work aimed at obtaining the polymeric nanocomposites of polyaniline (PAni) with different commercial clays (cloisite Na{sup +}, 10A and 30B). The preparation of PAni-MMT nanocomposites was performed by in situ polymerization of aniline in acidic (HCl). Electrical conductivity measurements, infrared spectroscopy and X-ray diffraction were some of the techniques used to characterize the nanocomposites. (author)

  5. Characterization of barium titanate powder doped with sodium and potassium ions by using Rietveld refining; Caracterizacao do po de titanato de bario dopado com ions sodio e potasio com o refinamento de Rietveld

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, M.C.; Assis, J.T.; Pereira, F.R., E-mail: mcalixto@iprj.uerj.b [Universidade do Estado do Rio de Janeiro (IPRJ/UERJ), Nova Friburgo, RJ (Brazil). Instituto Politecnico; Araujo, J.C. [Universidade do Estado do Rio de Janeiro (FFP/UERJ), Sao Goncalo, RJ (Brazil). Fac. de Formacao de Professores; Moreira, E.L.; Moraes, V.C.A.; Lopes, A.R. [Centro Brasileiro de Pesquisas Fisicas (CBPF/MCT), Rio de Janeiro, RJ (Brazil)

    2009-07-01

    A solid-reaction synthesis of doped barium titanate was done by employing barium carbonates, sodium, potassium and titanium oxides with classic procedures. Rietveld refining of X ray diffraction data of perovskite samples with tetragonal symmetry was applying and show good agreement. Besides, the treatment performed from 600 deg C produces nanocrystals of barium titanate with average size of 33 nm. The presence of endothermic peaks related to BaTiO{sub 3} formation at relatively low temperatures was determined by thermal analysis. A pseudo-Voigt Thompson-Cox-Hastings function was used to fit the standard samples of barium titanate. The Rietveld method has showed be efficient to detect the influences of temperature and doping on barium titanate microstructures. (author)

  6. Preparation and characterization of electrocatalysts based on palladium for electro-oxidation of alcohols in alkaline medium; Preparacao e caracterizacao de eletrocatalisadores a base de paladio para oxidacao eletroquimica de alcoois em meio alcalino

    Energy Technology Data Exchange (ETDEWEB)

    Brandalise, Michele

    2012-07-01

    In this study Pd/C, Au/C, PdAu/C, PdAuPt/C, PdAuBi/C and PdAuIr/C electrocatalysts were prepared by the sodium borohydride reduction method for the electrochemical oxidation of methanol, ethanol and ethylene glycol. This methodology consists in mix an alkaline solution of sodium borohydride to a mixture containing water/isopropyl alcohol, metallic precursors and the Vulcan XC 72 carbon support. The electrocatalysts were characterized by energy dispersive X-ray (EDX), X-ray diffraction (XRD), transmission electron microscopy (TEM) and cyclic voltammetry. The electrochemical oxidation of the alcohols was studied by chronoamperometry using a thin porous coating technique. The mechanism of ethanol electro-oxidation was studied by Fourier Transformed Infrared (FTIR) in situ. The most effective electrocatalysts were tested in alkaline single cells directly fed with methanol, ethanol or ethylene glycol. Preliminary studies showed that the most suitable atomic composition for preparing the ternary catalysts is 50:45:05. Electrochemical data in alkaline medium show that the electrocatalysts PdAuPt/C (50:45:05) showed the better activity for methanol electro oxidation, while PdAuIr/C was the most active for ethanol oxidation and PdAuBi/C (50:45:05) was the most effective for ethylene glycol oxidation in alkaline medium. These results show that the addition of gold in the composition of electrocatalysts increases their catalytic activities. The spectroelectrochemical FTIR in situ data permitted to conclude that C-C bond is not broken and the acetate is formed. (author)

  7. Characterization of peat and humic acid in the margins of Mogi-Guacu river, Sao Paulo state, Brazil; Caracterizacao da turfa e dos acidos humicos das margens do rio Mogi-Guacu, SP

    Energy Technology Data Exchange (ETDEWEB)

    Prado, Alexandre G.S.; Rezende, Mara O. de O. [Sao Paulo Univ., Sao Carlos, SP (Brazil). Inst. de Quimica. Lab. de Radioquimica e Quimica Ambiental

    1999-07-01

    The slow chemical and microbiological decomposition of flooded soils form a material with high proportion of organic matter known as peat. The presence of favorable areas for peat formation is a characteristic of the Brazilian territory; even so, the potential of this material is seldom used. Peat can be used as a fertilizer complement in agriculture, as source of energy, and as a pollutant extractor. The peat samples studied were collected in the margins of the Mogi Guacu river, in Sao Paulo state. The peat samples and the humic acids extracted from peat were characterized by several techniques. The results showed that the material can be applied in agriculture and presents a great potential for removal of environmental contaminants, besides being a good source of humic acids. (author)

  8. Characterization of a free-air ionization chamber in direct X-ray beams as used in mammography; Caracterizacao de uma camara de ionizacao de ar-livre em feixes diretos de raios X utilizados em mamografia

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Mateus Hilario de

    2014-08-01

    At this work stability and characterization tests were undertaken on a Victoreen free-air ionization chamber, model 481. The tests were realized using direct X-ray beams as a contribution for its establishment as a primary standard system of the quantity air kerma. The characterization tests were: saturation curve, ion collection efficiency, polarity effect, response linearity with the air kerma rate and response linearity with the chamber volume variation. The ion collection efficiency allowed the determination of the ion recombination factor. Most of the test results showed agreement with the limits established by international standards. Furthermore, the air attenuation factors for the mammography beams with aluminum and molybdenum filters were obtained. The factors for photon transmission and scattering at the diaphragm edges were also determined for mammography beams with aluminum filter and for the standard beam with molybdenum filter. (author)

  9. Characterization of radiation qualities used for the determination of characteristic in CT application according to IEC 61267:2005;Caracterizacao das qualidades de radiacao usadas na determinacao das caracteristicas em aplicacoes de CT de acordo com a IEC 61267: 2005

    Energy Technology Data Exchange (ETDEWEB)

    Dias, Daniel M.; Silva Junior, Iremar A. da; Potiens, Maria da Penha A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2009-07-01

    The purpose of this study was to establish the standard RQT radiation qualities which represent simulations of the unattenuated beam used in Computed Tomography (CT). Thus, to avoiding excessive efforts for establishing a radiation quality by means of the spectral distribution of the photon fluence, the characterization of these standard radiation qualities was expressed in terms of the X-ray tube voltage, first and second half-value layer (HVL). To establishing the standard radiation beam, according to the IEC 61267 and the TRS 457 was measured first of all the correct values of the X ray tube voltages in terms of Practical Peak Voltage. The standard radiation qualities RQT were produced using the same set up mounted for the RQR qualities which had been early established, and for simulating the patient in order to achieve the standard RQT series, suitable thicknesses of layers of copper were used to obtain the values of the first HVL according to IEC 61267. (author)

  10. Preparation and characterization of high density polyethylene and residual fibre of Attalea funifera Mart (piacava) composites; Preparacao e caracterizacao de compositos de polietileno de alta densidade com residuos de fibras de piacava da especie Attalea funifera Mart

    Energy Technology Data Exchange (ETDEWEB)

    Agrela, Sara P.; Guimaraes, Danilo H.; Jose, Nadia M., E-mail: saraagrela@hotmail.co [Universidade Federal da Bahia (GECIM/IQ/UFBA), Salvador, BA (Brazil). Inst. de Quimica. Grupo de Energia e Ciencias dos Materiais; Carvalho, Gleidson G.P. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Escola de Medicina Veterinaria. Dept. de Producao Animal; Carvalho, Ricardo F. [Universidade Federal da Bahia (EP/UFBA), Salvador, BA (Brazil). Escola Politecnica. Curso de Mestrado em Engenharia Ambiental Urbana

    2009-07-01

    The use of natural fiber reinforcement thermoplastic polymer is continuously increasing. This fact is manly due to its advantages as low cost, availability, recyclability, low energy demand and then environmental appeal if compared to synthetics fibers. The composites were prepared in different fiber volume ratios (5%, 10% and 20%) mixed with high density polyethylene (HDPE) and heated at 190 deg C. Thermogravimetric analysis and differential scanning calorimetry were used to investigate thermal stability. The composites structure was characterized by Fourier Transform Infrared spectroscopy, X-ray diffractometry. Fiber and residue of piassava (Attalea funifera Mart) chemical composition were determined by Van Soest Method. The results indicate that thermo stability of the composites of HDPE prepared with fiber volume ratios up to 20% is only slightly lowered. (author)

  11. Production and characterization of bio plastics from potato starch, poly-hydroxybutyrate and poly-hydroxybutyrate-co-valerate;Producao e caracterizacao de bioplasticos a partir de amido de batata, poli-hidroxibutirato e poli-hidroxibutirato-co-valerato

    Energy Technology Data Exchange (ETDEWEB)

    Mendes, Fernanda M.; Curvelo, Antonio A.S., E-mail: fernanda@iqsc.usp.b [Universidade de Sao Paulo (IQ/USP), Sao Carlos, SP (Brazil). Inst. de Quimica

    2009-07-01

    This work describes the study of thermoplastic starch (TPS) blends obtained from potato starch (plasticised with glycerol) with biodegradable polymers poly-hydroxybutyrate (PHB) and poly-hydroxybutyrate-co-valerate (PHB V). For this purpose it were developed several formulations with TPS/PHB, TPS/PHB V and TPS/PHB/PHB V prepared by physical mixing and water and glycerol as plasticizers. The amount of glycerol was 30% based on starch (dry basis). The starting materials (starch, PHB and PHB V) were characterized by scanning electron microscopy and X-ray diffraction. Then, it was determined the optimal processing conditions for the samples, performed by using an intensive mixer. The materials were hot pressed to produce the standardized samples employed in the characterizations: mechanical testing (tensile strength), dynamic-mechanical thermal analysis (DMTA), scanning electron microscopy and X-ray diffractometry. (author)

  12. Researches, development and characterization of dosimetric materials for monitoring in irradiation processes with high doses; Pesquisa, desenvolvimento e caracterizacao de materiais dosimetricos para monitoramento em processos de irradiacao com doses altas

    Energy Technology Data Exchange (ETDEWEB)

    Galante, Ana Maria Sisti

    2003-07-01

    Dosimetric materials that can be produced in Brazil with material acquired in the national market to replace the imported dosimeters used in radiation processing were developed in this work. Mixtures of potassium nitrate and sensitizers compounds as manganese dioxide, barium nitrate and potassium bromide were prepared in the pellet form. Dosimetric characteristics such as dose-response useful range, sensitivity, environmental conditions and dose rate influences were evaluated in {sup 60}Co gamma radiation fields. Dyed polymethylmethacrylate detectors were also produced and its dosimetric characteristics were evaluated. The main characteristics evaluated in this case were: dose response useful range sensitivity, environmental conditions, dose rate influences and radiation energy dependence in gamma radiation fields and accelerated electrons beam of 0.8 to 1.5 MeV. The applied analytic technique was spectrophotometry. The calibration was performed in the irradiation facilities belonging to IPEN and certified by the International Atomic Energy Agency by means of the program IDAS (International Dose Assurance Service ) using the Fricke dosimeter. The mixture of potassium nitrate and manganese dioxide presented the best results and a wide dose range between 200 and 600 kGy. The response of the developed polymethylmethacrylate detectors are similar to the imported detectors and the dose range is characteristic to each detector and depends on the dye added in its formulation. (author)

  13. Chemical characterization of bottom ashes generated during combustion of a Colombian mineral coal in a thermal power plant; Caracterizacao quimica das cinzas de fundo originadas pela combustao, em usina termoeletrica, de um carvao mineral do nordeste da Colombia

    Energy Technology Data Exchange (ETDEWEB)

    Pinheiro, H.S.; Nogueira, R.E.F.Q.; Lobo, C.J.S.; Nobre, A.I.S.; Sales, J.C.; Silva, C.J.M., E-mail: hspfisica@hotmail.com [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Centro de Tecnologia. Dept. de Engenharia Metalurgica e de Materiais

    2012-07-01

    Bottom ashes generated during combustion of a mineral coal from Colombia were characterized by X-ray fluorescence spectrometry and X-ray diffraction. The interest in this particular coal is due to the fact that it will be used by a thermal power plant in Ceara, Northeastern Brazil, where it could produce over 900 tons of different residues/combustion products every day. Results from Xray fluorescence allowed identification and quantification of elements present in the sample: silicon (59,17%), aluminum (13,17%), iron (10,74%), potassium (6,11%), titanium (2,91%), calcium (4,97%), sulphur (0,84%) and others (2,09%). The X-ray diffraction revealed patterns from silica, mullite, calcium sulphate and hydrated sodium. Results obtained so far indicate that the material is a potential raw-material for use in the formulation of ceramic components (author)

  14. Characterization of waste ceramic process for lost wax casting for employment as pozzolan; Caracterizacao do residuo de casca ceramica do processo de fundicao por cera perdida para emprego como pozolana

    Energy Technology Data Exchange (ETDEWEB)

    Machado, C.F.; Moravia, W.G., E-mail: carineferreiramachado@yahoo.com.br [Centro Federal de Educacao Tecnologica de Minas Gerais (CEFET/MG), Belo Horizonte, MG (Brazil). Departamento de Materiais

    2012-07-01

    There are about 30 companies of Lost Wax Casting in Brazil, and each one of them disposes around 50 to 100 tons of waste ceramic shell monthly. This work is concerned in the physical, chemical and microstructural characterization to evaluated the reactivity of this material. It was analyzed also the environmental risk of the material. The tests were made with a ceramic shell ground to evaluate the aspect of sustainable waste. In the physical characterization of the waste the density, specific surface area and distribution of the particle size were analyzed. In the chemical characterization, the powder was subjected to essays of fluorescence and pozzolanic activity. As for microstructural characterization scanning electron microscopy and Xray diffraction were carried out. The analysis of results shows that the ceramic shell powder is classified as non-inert waste, II-A Class, with density of 2,59 g/cm³. (author)

  15. Development of a impact limiter for radioactive material transport packages - characterization of the polymeric material used; Desenvolvimento de amortecedor de impacto para embalagens para transporte de material radioativo - caracterizacao do material polimerico utilizado

    Energy Technology Data Exchange (ETDEWEB)

    Mourao, Rogerio Pimenta [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil)]. E-mail: mouraor@urano.cdtn.br; Mattar Neto, Miguel [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: mmattar@net.ipen.br

    2000-07-01

    Impact limiters are sacrificial components widely used to protect radioactive waste packages against damages arising from falls, fires and collisions with protruding objects. Several materials have been used as impact limiter filling: wood, aluminum honeycomb, and metallic or polymeric foams. Besides, hollow structures are also used as shock absorbers, either as a single shell or as a tube array. One of the most popular materials among package designers is rigid polyurethane foam, owing to its toughness, workability, low specific weight, low costs and commercial availability. In Brazil, a foam developed using the polymer extracted from the castor oil plant (Ricinus communis) is being studied as a potential impact limiter filling. For a better performance of this material, it is necessary to minimize the impact limiter dimensions without compromising the package safety. For this, a detailed knowledge of the foam physical and mechanical properties is essential. A relatively vast amount of data about regular polymeric foams can be found in the literature and in foreign manufacturers brochures, but no data has been published about the properties of the castor oil foam. This paper presents data gathered in an ongoing research program aiming at the development of a Type-B packaging. Foam samples were submitted to uniaxial static compression tests and to hydrostatic tests. The results obtained reveal that the castor oil foam has a mechanical behavior similar to that of regular foams, with good property reproducibility and homogeneity. (author)

  16. New routes of preparation of polyaniline films and dosimetric characterization for high-doses gamma radiation; Novas rotas de preparacao de filmes de polianilina e caracterizacao dosimetrica para radiacao gama em altas doses

    Energy Technology Data Exchange (ETDEWEB)

    Pacheco, Ana Paula Lima

    2003-08-15

    This work presents a new conducting polymeric material based on polyaniline thin films that will be used in the confection of dosimetric devices. On preparation of the films a homogeneous and viscous solution of poly (acrylic acid) and MnO{sub 2} is deposited on PMMA surface, which after dried, is immersed in an acid aniline solution. The films formed present low resistivity (6.10{sup 2} {omega}m), good mechanical resistance and adherence on the electrodes. The films were characterized by infrared spectroscopy, conductivity measurements and manganese elemental analyses. The resistance variations show linear correlation (r{sup 2} = 0,9928) with gamma irradiation dose in the range of 1000 to 6000 Gy, with medium error less than 5% and sensitivity response. The dosimetric devices present as advantage real time measurements, low cost, use in calibration of industrial radioactive sources. Moreover, this composite could in future replace Fricke dosimeter and its applications. A calibration curve is showed for PANI dosimeter, here proposed, to use at high gamma doses. (author)

  17. Neutron field characterization in the installation for BNCT study in the IEA-R1 reactor; Caracterizacao do campo de neutrons na instalacao para estudo em BNCT no reator IEA-R1

    Energy Technology Data Exchange (ETDEWEB)

    Carneiro Junior, Valdeci

    2008-07-01

    This work aims to characterize the mixed neutron and gamma field, in the sample irradiation position, in a research installation for Boron Neutron Capture Therapy (BNCT), in the IPEN IEA-R1 reactor. The BNCT technique has been studied as a safe and selective option in the treatment of resistant cancerigenous tumors or considered non-curable by the conventional techniques, for example, the Glioblastoma Multiform - a brain cancerigenous tumor. Neutron flux measurements were carried out: thermal, resonance and fast, as well as neutron and gamma rays doses, in the sample position, using activation foils detectors and thermoluminescent dosimeters. For the determination of the neutron spectrum and intensity, a set of different threshold activation foils and gold foils covered and uncovered with cadmium irradiated in the installation was used, analyzed by a high Pure Germanium semiconductor detector, coupled to an electronic system suitable for gamma spectrometry. The results were processed with the SAND-BP code. The doses due to gamma and neutron rays were determined using thermoluminescent dosimeters TLD 400 and TLD 700 sensitive to gamma and TLD 600, sensitive to neutrons. The TLDs were selected and used for obtaining the calibration curves - dosimeter answer versus dose - from each of the TLD three types, which were necessary to calculate the doses due to neutron and gamma, in the sample position. The radiation field, in the sample irradiation position, was characterized flux for thermal neutrons of 1.39.10{sup 8} {+-} 0,12.10{sup 8} n/cm{sup 2}s the doses due to thermal neutrons are three times higher than those due to gamma radiation and confirm the reproducibility and consistency of the experimental findings obtained. Considering these results, the neutron field and gamma radiation showed to be appropriated for research in BNCT. (author)

  18. Dosimetry characterization of the commercial CaF{sub 2} for beta radiation of {sup 90}Sr + {sup 90}Y; Caracterizacao dosimetrica de CaF{sub 2} comercial para radiacao beta de {sup 90}Sr + {sup 90}Y

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Mercia L.; Caldas, Linda V.E. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)], e-mail: mlolivei@ipen.br, e-mail: lcaldas@ipen.br

    2003-07-01

    This work studies the dosimetric characteristics of the CaF{sub 2} commercial dosimetry for detection of {sup 90}Sr + {sup 90}Y beta radiation for using in the calibration of flat and concave appliers. Were determined the repetitiousness and linearity of answers of the samples, and their calibration curves.

  19. Spectral characterization of crude oil using fluorescence (synchronous and time-resolved) and NIR (Near Infrared Spectroscopy); Caracterizacao espectral do petroleo utilizando fluorescencia (sincronizada e resolvida no tempo) e NIR (Near Infrared Spectroscopy)

    Energy Technology Data Exchange (ETDEWEB)

    Falla Sotelo, F.; Araujo Pantoja, P.; Lopez-Gejo, J.; Le Roux, G.A.C.; Nascimento, C.A.O. [Universidade de Sao Paulo (USP), SP (Brazil). Dept. de Engenharia Quimica. Lab. de Simulacao e Controle de Processos; Quina, F.H. [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Quimica. Centro de Capacitacao e Pesquisa em Meio Ambiente (CEPEMA)

    2008-07-01

    The objective of the present work is to evaluate the performance of two spectroscopic techniques employed in the crude oil characterization: NIR spectroscopy and fluorescence spectroscopy (Synchronous fluorescence - SF and Time Resolved Fluorescence - TRF) for the development of correlation models between spectral profiles of crude oil samples and both physical properties (viscosity and API density) and physico-chemical properties (SARA analysis: Saturated, Aromatic, Resins and Asphaltenes). The better results for viscosity and density were obtained using NIR whose prediction capacity was good (1.5 cP and 0.5 deg API, respectively). For SARA analysis, fluorescence spectroscopy revealed its potential in the model calibration showing good results (R2 coefficients greater than 0.85). TRF spectroscopy had better performance than SF spectroscopy. (author)

  20. Characterization and standardized radiation qualities deployment - NBR IEC 61225 - in a animal irradiator; Caracterizacao e implantacao de qualidades de radiacao pradronizadas - NBR IEC 61225 - em um irradiador de animais

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Samara; Magalhaes, Luis Alexandre Goncalves, E-mail: samaracarvalho@gmail.com [Universidade do Estado do Rio de Janeiro (LCR/UERJ), Rio de Janeiro, RJ (Brazil). Lab. de Ciencias Radiologicas; Pereira, Leslie [Instituto de Radioprotecao e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2015-07-01

    The present work consisted in the determination of additional aluminum filters, so that the Animal Irradiator of the Laboratory of Radiological Sciences-UERJ can operate in accordance with standard IEC 61267: 2005. In order to perform the measurements necessary for the determination of these filters, it was developed an additional filter positioning system coupled to the X-ray tube. The determination of these filters was performed to obtain the first half value layer (HVL) according to the window with the values given by the IEC 61267: 2005. It was used IPEN SRS-78 (Institute of Physics and Engineering in Medicine) software for the estimation of the total amount of the additional filtration through the measurements values of the first HVL. (author)

  1. Methyl biodiesel from Dipteryx lacunifera: preparation, characterization and effect of antioxidant on the oxidation stability; Biodiesel metilico de Dipteryx lacunifera: preparacao, caracterizacao e efeito de antioxidantes na estabilidade a oxidacao

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Francisca Diana da Silva; Moura, Carla Veronica Rodarte de; Chaves, Mariana H., E-mail: mariana@ufpi.edu.b [Universidade Federal do Piaui (UFPI), Teresina, PI (Brazil). Dept. de Quimica

    2010-07-01

    The objective of this work was to study the potentialities of Dipteryx lacunifera Ducke seeds oil for biodiesel production. The yield in oil was of 46.11 {+-} 0.37%. Methyl biodiesel was prepared by base catalyzed transesterification yielding 88.13% and percentage conversion of triglycerides to corresponding methyl ester of 89.1%. The addition of the tertiary butylhydroquinone (TBHQ, 50 ppm), butylated hydroxytoluene (BHT, 50 ppm) and cashew nut shell liquid (CNSL, 2000 ppm) antioxidants in the biodiesel contributed to the increase of the induction period of 2.97 h for 8.08; 6.06 and 6.02 h, respectively. (author)

  2. Synthesis and characterization of biocements from fossilized calcareous shells: innovation in reconstruction and regeneration of bone tissue; Sintese e caracterizacao de um biocimento a partir de conchas calcarias fossilizadas: inovacao na reconstituicao e regeneracao de tecidos osseos

    Energy Technology Data Exchange (ETDEWEB)

    Silva, D.F.; Camargo, N.H.A.; Gemelli, E. [Universidade do Estado de Santa Catarina (CCT/UDESC), Joinville, SC (Brazil). Centro de Ciencias Tecnologicas. Programa de Pos-Graduacao em Ciencias e Engenharia de Materiais; Angioletto, E.; Bernardin, A.M., E-mail: by-daya@hotmail.com [Universidade do Extremo Sul Catarinense (UNESC), SC (Brazil)

    2011-07-01

    It is known that with the loss of a certain critical volume of bone, about one cm{sup 3}, the bone structure is unable to regenerate spontaneously, causing the need for better treatment for the patient. The present research aimed to use calcium carbonate (CaCO{sub 3}) from fossilized shells as raw material in the synthesis of microstructured biocement. Biocement compositions were elaborated in concentrations of 1, 0.75, 0.5 and 0.25 moles of H{sub 3}PO{sub 4}, mixed with 4% of Na{sub 2}PO{sub 4} and 1% of KH2PO4 respectively. The wet way synthesis method was used for the reaction / dissolution of CaCO{sub 3} formation of calcium phosphate by the addition of H{sub 3}PO{sub 4}. With the method of synthesis post microstructured calcium phosphate hydrate was obtained. A modification of the phases in the compositions, was found and it varied according to acid concentration. The biocements obtained from heat treatment at 1300 deg C/2h presented brushite phase, which are composed of fine crystals that favour their application in bone regeneration and reconstructions. (author)

  3. Hydrodynamic characterization of a alluvial flow plain soil of Cajueiro in Tuparetama, Pernambuco State, Brazil - instantaneous profile method; Caracterizacao hidrodinamica de um solo aluvial do acude Cajueiro em Tuparetama, PE - metodo do perfil instantaneo

    Energy Technology Data Exchange (ETDEWEB)

    Robalinho, Aviani Maria B.; Maciel Netto, Andre; Antonino, Antonio Celso Dantas [Pernambuco Univ., Recife, PE (Brazil). Dept. de Energia Nuclear; Audry, Pierre [Institut de Recherche pour le Developpement (IRD), Paris (France)

    2000-07-01

    The knowledge of the hydraulic properties of soil K({theta}) and h({theta}) is required to better management of water transfers in the soils. Determining these properties is highly important in solving problems related to irrigation and drainage, and the transport of nutrients and salts. The experiment was carried out in an alluvial flow plain soil of Cajueiro Dam in Tuparetama, PE. By applying the Instantaneous Profile Method, it was possible to evaluate the hydraulic conductivity of the soil. A parcel of 3.5 m x 3.5 m was delimited for the experiment of internal drainage, and instrumented with an access tube for the neutron probe (water content measurement) and ten tensiometers (measurement of water potential in the soil). The soil profile of Cajueiro Dam is classified as varying from loamy sand (0-80 cm) to sandy (80-100 cm). As to its retention curves h({theta}) and hydraulic conductivity K({theta}), it is classified according to three horizons (0-20 cm), (30-50 cm) and (60-100 cm). In addition, the determination of the hydraulic properties K({theta}) and h({theta}) of the soil gives subsidies for a more efficient handling of this flood plain starting from simulations of soil water transfer processes in the horizons under study. (author)

  4. Hydrodynamic characterization of fractured aquifers from Pocos de Caldas and adjacent areas using groundwater environmental radioactive isotopes; Caracterizacao hidrodinamica do meio aquifero fraturado na area de Pocos de Caldas e adjacencias, mediante a analise do conteudo radioisotopico das aguas subterraneas

    Energy Technology Data Exchange (ETDEWEB)

    Scudino, Paulo Cyro Baptista

    1992-04-01

    The geothermal system of Pocos de Caldas belongs to a complex volcanic system of fractured alkaline rocks. High geothermal gradients and natural occurences of two thermal springs furnishes a total yield of about 18m{sup 3}/h, within a temperature range of 40 to 44{sup 0}C. Aiming at establishing a functional model for the fractures aquifers of this specific system, the {sup 3} H and {sup 14} C radioisotopes were employed with complementary informations from the stable isotopes {sup 13} C, {sup 18} O and {sup 2} H. Furthermore structural-geological, geochemical hydrological, hydrochemical, and geothermal data were also introduced for evaluation. Three aquifer zones were identified: a shallow zone, where oxidizing environment is predominant, the water has a low mineralization, high CO{sub 2}, neutral pH, transit time in the range of 1 to 10 years. Relatively high concentration of {sup 18} O and {sup 2} H isotopes reflects at the present time the precipitation composition. The groundwater from the intermediate aquifer zone lies between 100 and 200m. Its age is in the range of 60 to 3,850 years and its chemical and isotopic compositions suggest a mix of different fraction with deep circulation of groundwater. The thermal water, from the deep zone, represents the final process related to chemical and isotopic groundwater evolution, and it comes from past precipitations, with low contents of {sup 18} O and {sup 2} H. It can be easily distinguished from the waters of the shallow zone due to its reducing conditions, a transit time around 12,500 years, HCO{sub 3}, Na{sup +}, SO{sup 2-}{sub 4} and silica high concentrations, together with F{sup -}, high pH and a quite rich {sup 18} O content when compared with its original composition. (author). 90 refs., 19 figs., 15 tabs.

  5. Evaluating factorial kriging for seismic attributes filtering: a geostatistical filter applied to reservoir characterization; Avaliacao da krigagem fatorial na filtragem de atributos sismicos: um filtro geoestatistico aplicado a caracterizacao de reservatorios

    Energy Technology Data Exchange (ETDEWEB)

    Mundim, Evaldo Cesario

    1999-02-01

    In this dissertation the Factorial Kriging analysis for the filtering of seismic attributes applied to reservoir characterization is considered. Factorial Kriging works in the spatial, domain in a similar way to the Spectral Analysis in the frequency domain. The incorporation of filtered attributes via External Drift Kriging and Collocated Cokriging in the estimate of reservoir characterization is discussed. Its relevance for the reservoir porous volume calculation is also evaluated based on comparative analysis of the volume risk curves derived from stochastic conditional simulations with collocated variable and stochastic conditional simulations with collocated variable and stochastic conditional simulations with external drift. results prove Factorial Kriging as an efficient technique for the filtering of seismic attributes images, of which geologic features are enhanced. The attribute filtering improves the correlation between the attributes and the well data and the estimates of the reservoir properties. The differences between the estimates obtained by External Drift Kriging and Collocated Cokriging are also reduced. (author)

  6. Microstructural characterization of porous materials by X-ray microtomography and gamma ray transmission techniques; Caracterizacao da microestrutura de materiais porosos por microtomografia de raios X e transmissao de raios gama

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Anderson Camargo

    2006-07-01

    This work presents the application of the X-ray microtomography and gamma ray transmission techniques for the microstructure characterization of different kinds of materials. Total porosity, pore size distribution and the two point correlation functions were measured. The two point correlation function, which allows the reconstruction of 3D models, was carried out for two samples. Seven ceramic tablets of Alumina (Al{sub 2}O{sub 3}), seven tablets of Boron Carbide (B{sub 4}C), three samples of sedimentary rocks and one sample of Titanium foam were analyzed. The experimental set up for the Gamma Ray Transmission technique consisted of: a 2'' x 2'' crystal NaI(Tl) detector, an {sup 241} Am radioactive source (59,53 keV, 100 mCi), an automatic micrometric table for the sample XZ movement and standard gamma spectrometry electronics. Two microtomography systems were used: a Fein Focus system, constituted by an X-ray tube, operated at 160 kV and 0.3 to 1.1 mA, a CCD camera and the movement sample system, and a Skyscan system, model 1072, with a X-ray tube operated at 100 kV and 100{mu}A, and a CCD camera. The ceramic tablets, analyzed by the gamma ray transmission technique presented results for most of the porosities data with smaller confidence intervals and inside the intervals supplied by the tablets manufacturer. The Titanium porous sample was analyzed by the two techniques, its microtomography images achieved a resolution of 17{mu}m, obtained employing the Fein Focus system. For both techniques, this sample showed high porosity, which allows its application for this purpose. The sandstones samples were analyzed by the Skyscan system, achieving resolutions of 19{mu}m, 11{mu}m and 3.8{mu}m for each sample, respectively. The resolutions of 11{mu}m and 3.8{mu}m were the ones that generated better 2D sections for the respective samples and, consequently, more reliable porosities. The 3.8{mu}m resolution was the one that best quantified the pore size distribution data, showing information not shown by the 11{mu}m resolution, showing that pores with 15 to 45{mu}m radius are predominant, constituting 57% of the porous phase of this sample, and 1 % are just constituted by pores with radius up to 3.8{mu}m. These results show that resolution better than 3.8{mu}m could be necessary only for specific cases. (author)

  7. Water isotopic characterization of hypersaline formation of a petroleum field Reconcavo basin, Brazil; Caracterizacao isotopica de aguas de formacao hipersalinas de um campo de petroleo da Bacia do Reconcavo, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Teles, Danilo Ribeiro de Sa; Azevedo, Antonio Expedito Gomes de, E-mail: danilosateles@yahoo.com.br, E-mail: expedito@ufba.br [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Fisica. Centro de Pesquisa em Geofisica e Geologia; Santos, Christian Pereira Lopes dos, E-mail: cplsgs@gmail.com [Instituto Federal Baiano, Salvador, BA (Brazil)

    2010-04-15

    Formation water is the water present in reservoir rock pores, produced together with petroleum. Usually it is hyper saline with concentrations that can be higher than 250 g/l of dissolved solids. The concentration of the dissolved elements and the isotopic composition of the water and of some of the dissolved elements can be excellent tracers to study the dynamic of underground fluid flux, the mixing of distinct sources and the origin of salinization of these waters. This work reports the isotopic composition ({delta}{sup 2}H , {delta}{sup 18}O) and electrical conductivity (EC) of formation waters from 10 wells of a petroleum field of the Reconcavo Basin, looking for their evolution, interaction with the minerals and rocks and reservoir interconnection. The samples have electric conductivity ranging from 84 to 137 mS/cm, with conductivity increasing with depth of production zone. It is observed an enrichment of deuterium and oxygen-18 with the depth of production zone, probably due to water-rock interactions that were probably increased by higher temperatures of the deeper levels and longer residence times. The samples from the production zone between 1450 to 1520 m, drained by 7 of the 10 wells sampled, show a small range in isotopic composition and in electric conductivity, indicating homogeneity in this level of the reservoir. In the shallow level of 450 m the values of {delta}{sup 2}H , {delta}{sup 18}O and EC are lower, with isotopic composition similar to the oceanic water, possibly representing the original water that entered the reservoir during the sedimentation of the basin. (author)

  8. Study and development of nanocomposites PBT/bentonite clay treated by ionizing radiation: preparation and characterization; Estudo e desenvolvimento de nanocompositos PBT/argila bentonita tratados por radiacao ionizante: preparacao e caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Sartori, Mariana do Nascimento

    2014-07-01

    This work describes the preparation and characterization of composites based on poly (butylene terephthalate) - PBT and brazilian modified clay prepared by the melt intercalation. PBT nanocomposites with 3 and 5 % by weight of organically modified clay, by the addition of a quaternary ammonium salt, were prepared by extrusion using a twin-screw extruder machine. After the extrusion process, the materials were injected to obtain specimens tests samples for the characterization tests. Part of the specimens samples were irradiated using an electron beam accelerator with 1.5 MeV at room temperature in the presence of air. Samples of pure PBT and irradiated and non-irradiated nanocomposites were characterized by mechanical tests of tensile, flexural and impact, heat distortion temperature (HDT), X - ray diffraction (XRD), scanning electron microscopy (SEM), melt flow index (MFI) thermogravimetry (TG) and differential scanning calorimetry (DSC) and the correlation between the properties was discussed. The results showed that the addition of clay, in both percentages, promoted an increase greater than 50 % in tensile strength at break and a gain of around 35% in heat distortion temperature when compared to the pure polymer. The treatment with ionizing radiation of electron beam at the doses used in this study showed no significant changes in material properties. (author)

  9. Synthesis and characterization of Sr doped LaMnO{sub 3} electrospun fibers; Obtencao por electrospinning e caracterizacao de fibras de LaMnO{sub 3} dopadas com estroncio

    Energy Technology Data Exchange (ETDEWEB)

    Lubini, M.; Alves, A. K.; Bergmann, C.P., E-mail: marcilubini@gmail.com.br [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Escola de Engenharia. Lab. de Materiais Ceramicos; Malfatti, C. [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Escola de Engenharia. Lab. de Pesquisa em Corrosao

    2012-07-01

    In this paper, fibers of lanthanum manganite doped with strontium were obtained by electrospinning using lanthanum chloride, manganese nitrate, strontium chloride and polyvinyl butyral as precursors. During the electrospinning process, we studied the influences of parameters such as the concentration of polymer (10 and 15 wt%), the flow, and the distance between the electrodes in the morphologic characteristics of the fibers. After synthesis the fibers were heat treated at different temperatures. Morphological characterization was performed by electron microscopy, thermal analysis was used to evaluate the thermal behavior, and X-ray diffraction to identify the phases present. We observed the formation of micro-and nanostructured fibers consisting mainly of LaMnO{sub 3}. (author)

  10. Characterization by X ray diffraction of deleterious phases precipitated in a super duplex stainless steel; Caracterizacao por difracao de raios X de fases deleterias precipitadas em aco inoxidavel superduplex

    Energy Technology Data Exchange (ETDEWEB)

    Pardal, Juan M.; Tavares, Sergio S. Maior; Fonseca, Maria P. Cindra; Montenegro, Talles Ribeiro, E-mail: juanpardal@vm.uff.b [Universidade Federal Fluminense (PGEMEC/UFF), Niteroi, RJ (Brazil). Programa de Pos-graduacao em Engenharia Mecanica; Dias, Antonio Jose N.; Almeida, Sergio L. de [Instituto Nacional de Tecnologia (INT), Rio de Janeiro, RJ (Brazil). Div. de Materiais Ceramicos e Metalicos. Lab. de Tecnologia de Materiais

    2010-07-01

    In this work the identification and quantification of deleterious phases in two super duplex stainless steels grade UNS S32750, with quite different grain sizes, was performed by X-ray diffraction. The materials were isothermally aged in the 800 . 950 deg C range. Direct comparison method was used to quantify the ferrite phase in each sample. The amount of deleterious phases ({sigma}, {chi} and {gamma}2) formed was calculated by the difference of the amount of ferrite phase measured in each specimen to the amount of ferrite initially measured in the un-aged steel. The results obtained give an useful contribution to the understanding of kinetics of deleterious phases precipitation in super duplex steels. (author)

  11. Characterization of a red ceramic body used in the manufacture of ceramic bricks in the region of Campos dos Goytacazes, RJ, Brazil; Caracterizacao de massa ceramica vermelha utilizada na fabricacao de blocos ceramicos na regiao de Campos dos Goytacazes

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, L.L.P. de; Petrucci, L.J.T.; Pessanha, E.M.; Paixao, L.P.; Maia, F.S. [Faetec, Campos dos Goytacazes, RJ (Brazil). Centro Vocacional Tecnologico. Ceramica

    2010-07-01

    This work aims at the physical and mineralogical characterization of a ceramic body, used industrially in the manufacture of ceramic bricks in the region of Campos dos Goytacazes. The clay was characterized by chemical composition, X-ray diffraction, dilatometry, differential thermal analysis and gravimetric. We test specimens were obtained by extrusion. The bodies were burned from 750 to 1000 deg C and then it was determined water absorption, linear shrinkage, loss on ignition and modulus of rupture. The results showed that the ceramic body consists mainly of kaolinite, quartz and feldspar is thus suitable for mass production of ceramic bricks in accordance with technical standards. (author)

  12. Combustion synthesis by reaction and characterization of structural Ni-Zn ferrite doped with copper; Sintese por reacao de combustao e caracterizacao estrutural de ferritas Ni-Zn dopadas com cobre

    Energy Technology Data Exchange (ETDEWEB)

    Dantas, J.; Santos, J.R.D.; Cunha, R.B.L.; Feitosa, C.A.; Costa, A.C.F.M., E-mail: joeldadantas@yahoo.com.br, E-mail: jakelineedm@gmail.com [Universidade Federal de Campina Grande (LabSMac/UFCG), PB (Brazil). Lab. de Sintese de Materiais Ceramicos

    2012-07-01

    The present stud aims to evaluate the effect of doping with Cu{sup 2+} ions concentrations of 0.0, 0.1, 0.2, 0.3 and 0.4 mol in the synthesis and structure of Ni-Zn ferrite. Samples were synthesized by the method of the combustion reaction and characterized by measuring the temperature as a function of reaction time, X-ray diffraction (XRD) and infrared spectroscopy in Fourier transform (FTIR). The combustion temperature and time were 646, 900, 989, 975 and 735°C and 210, 175, 220, 210 and 110 seconds for the sample doped with 0.0, 0.1, 0.2, 0.3 and 0.4 mol of copper, respectively. XRD results show that all concentrations of copper evaluated, there was only a training phase inverse spinel ferrite and Ni-Zn FTIR spectra show absorption bands below 1000cm{sup -1}, which are characteristics of the spinel type AB{sub 2}O{sub 4-} (author)

  13. Development of ceramic materials based on zirconia-titania as biomaterial applications: synthesis and characterization; Desenvolvimento de materiais ceramicos a base de zirconia-titania para aplicacoes enquanto biomaterial: sintese e caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Amorim, E.M.; Marchi, J., E-mail: eric.amorim@ufabc.edu.br, E-mail: juliana.marchi@ufabc.edu.br [Universidade Federal do ABC (CCNH/UFABC), Santo Andre, SP (Brazil). Centro de Ciencias Naturais e Humanas; Lazar, D.R.R.; Ussui, V. [Instituto de Pesquisas Energeticas e Nucleares (CCTM/IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro de Ciencia e Tecnologia de Materiais

    2011-07-01

    Ceramics materials such as tetragonal zirconia polycrystalline (Y-TZP) and titania (TiO{sub 2}) are targets of studies in the scientific and industrial fields after mixing these oxides in different ratio, the final ceramic can be optimized by the mechanical and biological properties. In this work we produced samples of Y-TZP containing up to 30 mol% TiO{sub 2} using the technique of co-precipitation with ammonia. The ceramic powders were characterized by XDR, MEV and BET, and then calcinated, conformed and sintered. The sintered ceramics were characterized by density, surface roughness, x-ray diffraction, scanning electron microscopy, diffuse reflectance infrared. The samples showed high density after sintering, except the sample with 20 mol% TiO{sub 2}, due to the interconnected pores. It was found that titania favored the growth of Y-TZP phase. The ceramic materials seems to have suitable physico-chemical characteristics to be used as biomaterials for bone replacement. (author)

  14. Physical and microstructural characterization of clay base ceramic product produced in Icoaraci (PA, Brazil); Caracterizacao fisica e microestrutural de produto ceramico de base argilosa produzido no Polo de Icoaraci (PA)

    Energy Technology Data Exchange (ETDEWEB)

    Santos, N.S.S.; Mendes, J.F.; Pamplona, V.M.S. [Universidade do Estado do Para (UEPA), PA (Brazil); Andrade, S.M.C. [Instituto Federal do Para (IFPA), PA (Brazil); Dias, C.G.B.T., E-mail: nubiatrib@yahoo.com.br [Universidade Federal do Para (UFPA), PA (Brazil)

    2011-07-01

    The pottery currently produced in the pole ceramist Icoaraci (PA) is an artistic legacy of indigenous peoples who inhabited the Amazon region. In the pole are produced artifacts such as vases and other decorative items, and household appliances. In this work characterizations were obtained from samples of the final product (after firing), using the technique of scanning electron microscopy (SEM) analysis by Fourier transform spectrometry (FTIR), X-ray diffraction (XRD) and determining the density of the material. The objective was to evaluate the physical, microstructural and composition of the ceramics after firing. The results revealed the existence of pores and impurities, all of which can influence the quality of the final product, as well as the main elements that constitute mineralogical and chemical material. The photomicrographs showed a considerable degree of porosity, which agrees with the density results. (author)

  15. Radiochemical characterization and environmental radiological impact in tin and lead processing from cassiterite; Caracterizacao radioquimica e impacto radiologico ambiental no processamento de cassiterita para producao de estanho e chumbo metalicos

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, Marcia Aparecida Antico

    2009-07-01

    The tin and lead industry located in Pirapora do Bom Jesus in the state of Sao Paulo, Brazil, is responsible for the production of about 7000 ton year-1 of tin and 350 ton year-1 of lead. The raw material used in this facility is cassiterite, which presents in its composition concentrations of natural radionuclides from the uranium and thorium series up to 660 kBq kg{sup -1} and 450 kBq kg{sup -1}, respectively. The smelting and refining processes may lead to concentrations of these radionuclides, mainly in the precipitated dust and in slag. In the operational process, intermediate refining and final slag are obtained and are stored in piles in open air. It is estimated that the amount of waste stored is about 600000 ton. This work aims to study the environmental radiological impact of the operation of this facility and to establish its Environmental Radiological Monitoring Program. In order to accomplish this task the content of radioactivity was determined in the raw material, products, byproducts, residue, deposition pond and exhausting systems. Although in the raw material the radionuclides from the uranium and thorium series are almost in equilibrium, during the processing this equilibrium is disrupted and the radionuclides migrate according to their chemical properties. Concentrations up to 31 kBq kg{sup -1} for {sup 238}U, 69 kBq kg{sup -1} for {sup 226}Ra, 2.5 kBq kg{sup -1} for {sup 210}Pb, 130 kBq kg{sup -1} for {sup 232}Th and 120 kBq kg{sup -1} for {sup 228}Ra were obtained in the slag. The environmental radiological impact was established by measuring the radionuclides in the critical compartments that is the ones that may cause exposure to the public. If the residue pile is considered, the critical pathways are the internal exposition from the dust inhalation and the water ingestion, due to re suspension and dispersion of the pile dust and groundwater contamination, respectively; and external exposure due to immersion in the radioactive cloud and soil contamination. For the emission of gaseous and particulate effluents from the chimneys, the critical pathways are the internal exposition from the radon inhalation and external exposure due to immersion in the radioactive cloud and due to soil contamination. The environmental matrices defined as critical were: ground water, soil and air; and the critical radionuclides were U, Th, {sup 226}Ra, {sup 228}Ra and {sup 210}Pb. (author)

  16. Synthesis and characterization of hydroxyapatite porous matrixes for application as radiation sources in brachytherapy; Sintese e caracterizacao de matrizes porosas de hidroxiapatita para aplicacao como fontes radioativas em braquiterapia

    Energy Technology Data Exchange (ETDEWEB)

    Lacerda, Kassio Andre; Lameiras, Fernando Soares; Silva, Viviane Viana [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)]. E-mail: kassiolacerda@yahoo.com.br

    2006-04-15

    Porous ceramic materials based on calcium phosphate compounds (CPC) have been studied aiming at different biomedical applications such as implants, drug delivery systems and radioactive sources for brachytherapy. Two kinds of hydroxyapatite (HAp) powders and their ceramic bodies were characterized by a combination of different techniques (X-rays diffraction and fluorescence, infrared spectrophotometry, BET method, thermal analysis, and scanning electron microscopy) to evaluate their physico-chemical and microstructural characteristics in terms of chemical composition, segregated phases, microstructure, porosity, and chemical and thermal stability. The results revealed that these systems presented potential for use as porous biodegradable radioactive sources able to be loaded with a wide range of radionuclides for cancer treatment by the brachytherapy technique. (author)

  17. Study of characteristics of a two phase biomaterial hydroxyapatite / β -tricalcium phosphate 60/40 the composition in volume; Estudo de caracterizacao de um biomaterial bifasico hidroxiapatita/fosfato tricalcio - β na composicao 60/40 em volume

    Energy Technology Data Exchange (ETDEWEB)

    Dalmonico, G.M.L.; Passoni, L.; Prandi, R.G.; Camargo, N.H.A.; Gemelli, E., E-mail: gidalmonico@gmail.com [Universidade do Estado de Santa Catarina (CCT/UDESC), Joinville, SC (Brazil). Centro de Ciencias Tecnologicas. Programa de Pos-Graduacao em Ciencias e Engenharia de Materiais

    2011-07-01

    This work has developed on the preparation and characterization of the composition of biphasic hydroxyapatite /β-calcium phosphate = 60/40%. The mixture composition was performed using the mechanical fragmentation process in an attrition mill for 1 hour. The powder recovered from the biphasic attrition mill after drying, was subjected to compression, to obtain the specimens, the dimensions of 10mm height and 5mm in diameter. The specimens obtained from compaction were sintered at temperature of 1100 ° C/2h. The recovered material was subjected to sintering studies of characterization: compression, hardness and porosity. The results showed a breakdown voltage greater than 76.27 ± 13.56, higher than the microhardness 572.80 ± 13.31 MPa and the porosity of around 40% by volume. The results of the composition biphasic hydroxyapatite /β-calcium phosphate are encouraging, since the biomaterial presented favorable conditions for biomedical applications in the reconstitution of the bone structure. (author)

  18. Synthesis and characterization of a nanoestructered hydroxyapatite: elaboration of nanocomposites HA/SiO{sub 2}n; Sintese e caracterizacao de uma hidroxiapatita nanoestruturada: elaboracao de nanocompositos HA/Si{sub 2}n

    Energy Technology Data Exchange (ETDEWEB)

    Passoni, L.S.; Camargo, N.H.A.; Gemelli, E.; Dalmonico, G.M.L.; Prandi, R.G., E-mail: laispassoni@gmail.com [Universidade do Estado de Santa Catarina (UESC), SC (Brazil)

    2011-07-01

    Hydroxyapatite is a synthetic bone matrix, known as a promising biomaterial in bone reconstruction. The development of nanostructured biomaterials based on hydroxyapatite has been showing as a technological innovation conducive to reconstruction of bone tissue. The biphasic compositions HA/SiO2, have led to obtaining nanocomposites biomaterials with new microestructural and nanostructured characteristics. This study aimed to characterize the raw materials for subsequent synthesis of hydroxyapatite phase and nanocomposite HA/SiO2n. Were prepared four compositions of Nanocomposites as follows: 0.5% 1% 2%, 3% in volume of SiO{sub 2}n. The synthesis method used was wet through the dissolution-precipitation reaction involving solid phase / liquid CaO and phosphoric acid required for the formation of compositions in the Ca / P ratio = 1.67 molar. The results presented refer to the characterization by the technique of x-ray diffraction, infrared spectrometry by Fourier Transforms and scanning electron microscopy. (author)

  19. Processing and characterization of biocomposites Poly (3-hydroxybutyrate) / hydroxyapatite for temporary support in bone regeneration; Processamento e caracterizacao de biocompositos Poli (3-hidroxibutirato) / hidroxiapatita para suporte temporario na regeneracao ossea

    Energy Technology Data Exchange (ETDEWEB)

    Cardoso, Cyntia Esteves; Ferreira, Willian Hermogenes; Andrade, Cristina Tristao [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil). Centro de Tecnologia. Instituto de Macromoleculas Professora Eloisa Mano

    2011-07-01

    Composite materials like biopolymer / hydroxyapatite (HA) has been attracting the interest of researchers because of its applications in medicine. These materials have been used as temporary supports during the regeneration of bone tissue. In this work, poly (3-hydroxybutyrate) (PHB) was chosen as matrix because it has good processability and biocompatibility. The HA was obtained by precipitation from calcium hydroxide and phosphoric acid, varying the speed of dripping, the synthesis temperature and time of calcination. The techniques of infrared absorption spectroscopy and X-ray diffraction (XRD) were used to characterize the samples synthesized HA. The biocomposites were prepared in an internal mixer, with compositions PHB / HA varied. After processing, the biocomposites were ground, characterized by XRD analysis and the crystallinity index. The aim of this study was to examine the variables during the synthesis of HA and its thermal treatment in order to obtain a powder of HA using a simple technique and accessible, creating good properties for the biocomposites prepared. (author)

  20. Processing and rheological characterization of poly(butylene adipate co-terephalate)/montmorillonite nanocomposites;Processamento e caracterizacao reologica de nanocompositos de poli(butileno adipato co-tereftalato)/montmorilonita

    Energy Technology Data Exchange (ETDEWEB)

    Beatrice, Cesar A.G.; Marini, Juliano; Bretas, Rosario E.S., E-mail: bretas@power.ufscar.b [Universidade Federal de Sao Carlos (PPGUFSCar), SP (Brazil). Programa de Pos-Graduacao em Ciencia e Engenharia de Materiais; Branciforti, Marcia C.; Favaro, Marcia M. [Universidade Federal de Sao Carlos (DEMa/UFSCar), SP (Brazil). Dept. de Engenharia de Materiais

    2009-07-01

    The rheological steady state and the linear viscoelastic properties of poly(butylene adipate co-terephthalate) (PBAT) / nanoclay nanocomposites were investigated. For this study, nanocomposites of PBAT and a chemically modified montmorillonite (MMT) were prepared by melt blending in a Haake Rheomix 600p rheometer at 140 and 160 deg C. The concentration of nanoclay was 5wt%. The samples obtained were characterized by x-ray diffraction (WAXS) and rheological measurements in an ARES (Rheometric Scientific) and AR-G2 (TA) rheometers, both with parallel plates geometry. It was confirmed by WAXS that the platelets of the nanoclay were intercalated in all samples, as the discernible sharp reflection of the (001) clay's diffraction was found in the x-ray diffractions patterns. The storage moduli (G') and the loss moduli (G) of the nanocomposites increased with nanoclay content, at low frequencies. The presence of nanoclay caused these nanocomposites melts to have solid-like behaviors, which can be explained in terms of the development of a percolated network structure. (author)

  1. Study of characterization of trace elements in marine shells of Sambaqui: correlation between recent and old shells; Estudo de caracterizacao de elementos tracos em conchas marinhas de Sambaqui: correlacao entre conchas recentes e antigas

    Energy Technology Data Exchange (ETDEWEB)

    Gomez, Mauro Roger Batista Pousada; Rocha, Flavio Roberto; Silva, Paulo Sergio Cardoso da, E-mail: mauro_bpgomez@yahoo.com.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2013-07-01

    Calcium carbonate of recent and ancient C. rhizophorae oyster shells was analyzed for the determination of trace elements by instrumental neutron activation analysis. The ancient shells belong to a Sambaqui located in Cananeia region, South of Sao Paulo state and the recent ones are from an oyster production farm in the same region Studies related to the element concentrations in molluscs shell has been done as a tentative of establishing the element concentrations with palio-environmental factor. In this study it was aimed to verify differences in the elemental constitution of recent and ancient oyster shells that present potential for being used as indicator of marine changes. Results indicated that the elements Br, Ce, La, Na, Sm and An are higher in recent shells and the elements Cr, Fe Sc and Th are higher in ancient shells. Statistical analyses performed indicated that the enrichment of the light rare earth elements related to Ca are possibly good candidates for these palio-environmental studies. (author)

  2. Characterization of TiO{sub 2} thin films obtained by metal-organic chemical vapour deposition; Caracterizacao de filmes finos de TiO{sub 2} obtidos por deposicao quimica em fase vapor

    Energy Technology Data Exchange (ETDEWEB)

    Carriel, Rodrigo Crociati

    2015-07-01

    Titanium dioxide (TiO{sub 2}) thin films were grown on silicon substrate (100) by MOCVD process (chemical deposition of organometallic vapor phase). The films were grown at 400, 500, 600 and 700 ° C in a conventional horizontal equipment. Titanium tetraisopropoxide was used as source of both oxygen and titanium. Nitrogen was used as carrier and purge gas. X-ray diffraction technique was used for the characterization of the crystalline structure. Scanning electron microscopy with field emission gun was used to evaluate the morphology and thickness of the films. The films grown at 400 and 500°C presented anatase phase. The film grown at 600ºC presented rutile besides anatase phase, while the film grown at 700°C showed, in addition to anatase and rutile, brookite phase. In order to evaluate the electrochemical behavior of the films cyclic voltammetry technique was used. The tests revealed that the TiO2 films formed exclusively by the anatase phase exhibit strong capacitive character. The anodic current peak is directly proportional to the square root of the scanning rate for films grown at 500ºC, suggesting that linear diffusion is the predominant mechanism of cations transport. It was observed that in the film grown during 60 minutes the Na+ ions intercalation and deintercalation easily. The films grown in the other conditions did not present the anodic current peak, although charge was accumulated in the film. (author)

  3. Characterization of dental cement obtained from a glass prepared by the polymeric precursor method; Caracterizacao de cimento odontologico obtido a partir de um vidro preparado pelo metodo dos precursores polimericos

    Energy Technology Data Exchange (ETDEWEB)

    Bertolini, Marcio Jose; Zaghete, Maria Aparecida; Gimenes, Rossano; Paiva-Santos, Carlos de Oliveira [UNESP, Araraquara, SP (Brazil). Inst. de Quimica]. E-mail: marciobert@yahoo.com.br; Palma-Dibb, Regina Guenka [Sao Paulo Univ., Ribeirao Preto, SP (Brazil). Faculdade de Odontologia

    2005-09-15

    Glass ionomer cements are glass and polymer composite materials. These materials currently find use in dentistry. The purpose of this work is to obtain glass powders based on the composition 4.5SiO{sub 2} - 3Al{sub 2}O{sub 3} - 2CaO to be used in dentistry. The powders were prepared by a chemical route at 700 deg C. The properties of glass ionomer cements obtained from powders prepared at 700 deg C were studied. Diametral tensile strength and microhardness were evaluated for the experimental glass ionomer cements and a commercial material. It was concluded that the properties of experimental cements were similar to those of the commercial ones. (author)

  4. The geomechanical characterization of the rocky mass foundation of the Tijuco Alto hydroelectric power plant, Ribeira River, Sao Paulo/Parana States, Brazil; Caracterizacao geomecanica do Macico de Fundacao da UHE Tijuco Alto (Rio Ribeira - SP/PR)

    Energy Technology Data Exchange (ETDEWEB)

    Figueiredo, Amarilis Lucia Casteli de

    1996-07-01

    This work has as its main objective the geomechanical characterization on the future rocky mass foundation of the Tijuco Alto dam, sited at the Ribeira river, in the cities of Ribeirao, Sao Paulo state and Adrianopolis, Parana state, Brazil, owned by the Companhia Brasileira de Aluminio (Brazilian company of Aluminium). To reach that target, field studies were made to qualify the geotechnical parameters of the rocky mass, in the axis area open galleries. It was also used in situ deformability and stress test results performed in those galleries, that were reinterpreted for a better adaptation of the mass values. The knowledge of the mass inherent characteristics together with the laboratories test results, allowed for the geomechanical classification applications in several different gallery sectors. The geomechanical data obtained allowed through mathematical expressions, to reach the rocky mass values correlations of interest to the work (deformability and strength), that could be compared to the in situ test results. That analysis permitted, besides the classification critical system evaluation, the geomechanical characterization of the rocky mass, focusing its ability to the dam arch construction. (author)

  5. Characterization of elements in trace amounts in imperial topaz through neutron activation analysis; Caracterizacao de elementos em teores de traco em topazio imperial atraves da analise por ativacao neutronica

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Ester Figueiredo de [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil); Sabioni, Antonio C. S. [Ouro Preto Univ., MG (Brazil). Dept de Fisica; Ferreira, Cesar M. [Ouro Preto Univ., MG (Brazil). Dept de Geologia

    2000-07-01

    This work deals with the mineral characterization of the elements in trace amounts of imperial topaz, original form Mina Capao da Lama, Ouro Preto, MG, Brazil, through the neutron activation analysis. Recent results have permitted to quantify Cr, Cs, Mn, Na, Ga, Sb and Au. The main goal of this study is the contribution to the mineral and gemological research of the imperial topaz.

  6. Characterized and cleaning process of montmorillonite clay from Parelhas, Rio Grande do Norte state, Brazil; Caracterizacao e processo de purificacao de argila montmorilonitica da cidade de Parelhas, RN, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Melo, G.N; Costa, T.C.C; Paskocimas, C.A, E-mail: gudson.nicolau@gmail.co [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2010-07-01

    The application of montmorillonite nano composites has been improved in order to obtain dispersed phase with particles of nano metric dimensions. To obtain these nanoparticles, the clays must pass an effective purification process for removing unwanted materials, which would undermine the processes of intercalation and exfoliation of montmorillonite in a polymer matrix. This study intention to characterize and purify a montmorillonite clay from deposit recently discovered in the city of Parelhas in Rio Grande do Norte, through the separation of coarser materials by decantation followed by a chemical attack that promoted oxidation in samples where it was realized reduction of impurities such as organic matter and other substances that would hinder the achievement of nanoparticles. Under these conditions, the clay is suitable for the work as dispersed phase in a polymer matrix nano composite. The results were demonstrated by analysis of scanning electron microscopy (SEM), chemical analysis, BET and X-ray diffraction (XRD). (author)

  7. Preparation and characterization of sugar cane bagasse fiber modified with nanoparticles of zirconium oxide; Preparacao e caracterizacao de fibras de bagaco de cana modificadas com nanoparticulas de oxido de zirconio

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, K.C.C. de; Mulinari, D.R.; Voorwald, H.C.J.; Cioffi, M.O.H., E-mail: kcccarvalho@hotmail.com.b [UNESP, Guaratingueta, SP (Brazil). Fac. de Engenharia. Dept. de Materiais e Tecnologia(FEG)

    2010-07-01

    The sugar cane bagasse fiber are renewable materials and have great application potential when used as reinforcement in a polymer matrix to give rise to composite materials and as supports for adsorption of heavy metals. This paper therefore describes the preparation and characterization of bleached and hydrated zirconium oxide modified sugar cane bagasse fiber by conventional precipitation method. Through the technique of electron microscopy we observed the presence of oxide nanoparticles on the fiber surface, proving the efficiency of the conventional precipitation method. With the X-ray diffraction analysis it was determined a decrease of 6.2% in the crystallinity index of modified fibers when compared to the bleached fibers showing the deposition of amorphous zirconium oxide on the fiber surface. (author)

  8. Synthesis and characterization of cement slurries additives with epoxy resins - kinetics, thermodynamic and calorimetric analysis; Sintese e caracterizacao de pastas de cimento aditivadas com resinas epoxi - analises cineticas, termodinamicas e calorimetricas

    Energy Technology Data Exchange (ETDEWEB)

    Tavares, A.M.G.; Andrade Junior, M.A.S.; Cestari, A.R.; Vieira, E.F.S., E-mail: macleybiane@gmail.co [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil)

    2010-07-01

    Cement has been used in the world, presenting a wide versatility. However, due to its chemical nature, it is subject to several types of chemical damages, especially for agents of acidic nature. With the purpose of increase its life-time, new cement slurries have been modified with the addition of specific additives. The objective of this work is to modify cement slurries with epoxy resins, which promote higher resistance of those materials in relation to acid attacks. Three cement slurries were synthesized with epoxy resins and a standard slurries, which was composed by cement and water. After 30 days of hydration, the samples were characterized by XDR, FTIR and thermal analysis (TG and DSC). The hydration processes of the cement slurries were studied by heat-conduction microcalorimetry. A kinetic study of HCl interaction with the new slurries were performed by the batch methodology at 25, 35, 45 e 55 deg C. It was verified that the addition of the polymers delayed the processes of hydration of the slurries, decreasing the flow of heat released as a function of the amount of added resin and, increased the resistance of those slurries to the acid attack. (author)

  9. Synthesis and characterization of ZSM-12 type zeolytic catalysts by using different aluminium sources in the petroleum industry; Sintese e caracterizacao de catalisadores zeoliticos do tipo ZSM-12 utilizando diferentes fontes de aluminio na industria do petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Moraes, Marilia R.F.S.; Jesus, Daniela B.; Souza, Marcelo J.B. [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil). Dept. de Engenharia Quimica; Santos, Consuelo D.; Machado, Sanny W.M.; Pedrosa, Anne M. Garrido [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil). Dept. de Quimica

    2010-12-15

    The main objective was to synthesize and characterize ZSM-12 zeolites from different sources of aluminium, using hydrothermal method and characterize the catalysts synthesized by X-ray diffractions, thermal analysis and infrared absorption spectroscopy. The X-ray diffractogram showed the formation of zeolites of the family pantasil crystalline. Thermogravimetric curves and FTIR spectra were utilized by monitoring the removal of template and by monitoring the maintenance of zeolite structure. (author)

  10. Synthesis and characterization of rare earth molybdates nanoparticles for detection of specific prostatic cancer (PSA); Preparacao e caracterizacao de nanoparticulas de molibdatos de terras raras para deteccao do antigeno especifico da prostata (PSA)

    Energy Technology Data Exchange (ETDEWEB)

    Dias, Clarissa Lombardi

    2013-07-01

    The interest in using rare earths to investigate the properties and functions of biochemical systems as well as to determinate biological substances has increased in several fields, including biomarkers in immunology (fluoro immunoassays). Nowadays the use of lanthanides in the diagnosis of various diseases have become more important through the development of commercial diagnostic kits. As main feature, these rare earths can show a long lifetime, photo stability and emission bands of atomic like behavior and well defined, in the visible region, demonstrating unique advantages when compared to other luminescent species. The present work had as its goal to synthesize rare earth molybdates by the co-precipitation method as well as to characterize these materials by X-ray diffraction, near infrared spectroscopy, thermogravimetric analysis, scanning electronic microscopy, transmission electronic microscopy and luminescent studies. In this work, three different studied were developed: the influence of the vortex speed variation during co-precipitation in the structure of the final product, morphology and luminescence properties; the influence of the annealing temperature also in the structure, morphology and luminescence properties; and the influence of concentration of the doping in the luminescence properties. Another important step of this work was the functionalization of nanoparticles using an organosilane (APTES) to coat and establish points for binding the particles to biological species. It was proved that this process was very efficient by the characterization results and the silica incorporation was well succeeded. Specific prostatic cancer (PSA) was then linked to the functionalized nanoparticles to diagnostic prostatic cancer by fluoroimmunoassay and levels for detection were established. (author)

  11. Impregnation of 12-tungstophosphoric acid on silica - part I: determination of impregnation parameters, characterization and evaluation of catalytic activity; Impregnacao do acido 12-fosfotungstico em silica - parte I: determinacao de parametros de impregnacao, caracterizacao e avaliacao da atividade catalitica

    Energy Technology Data Exchange (ETDEWEB)

    Scroccaro, Karine Isabel; Tanobe, Valcineide Oliveira de Andrade; Cocco, Lilian Cristina; Yamamoto, Carlos Itsuo, E-mail: karineisabel@yahoo.com.br [Universidade Federal do Parana, Curitiba, PR (Brazil). Centro Politecnico. Dept. de Engenharia Quimica; Wypych, Fernando [Universidade Federal do Parana, Curitiba, PR (Brazil). Centro Politecnico. Dept. de Quimica

    2012-07-01

    Catalyst based on Kegging-type heteropolyacids (H{sub 3}PW{sub 12}O{sub 40} - HPA), supported on SiO{sub 2} (H{sub 3}PW), were prepared by the impregnation method under different thermal treatment conditions. The materials were characterized by different instrumental techniques and used as catalysts in the methyl esterification reactions of stearic acid. Using the catalyst with 15% of HPA, conversions higher than 60% were obtained after 2 h of reaction at 65 deg C. Recovery studies using hot-filtration with ethanol at 75 deg C showed satisfactory activity for two additional reaction cycles. (author)

  12. Study of ceramics from circular archaeological sites of Amazonic Basin by geochemical methods: dating and characterization; Estudo de ceramicas de sitios arqueologicos circulares da Bacia Amazonica por meio de metodos geoquimicos: datacao e caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Nicoli, Ieda Gomes

    2000-09-01

    The aim of this work is to examine by means of characterization and dating pottery recently discovery inside archaeological sites recognized with circular earth structure in Acre State - Brazil which may contribute to the research in the reconstruction of part of the pre-history of the Amazonic Basin. These sites are located mainly in the Hydrographic Basin of High Purus River. Three of them were strategic chosen which provide the ceramics: Lobao, in Sena Madureira County at north; Alto Alegre, in Rio Branco County at east and Xipamanu I, in Xapuri County at south. The X-ray diffraction mineral analysis made possible to identify two types of crystal structures of ceramic minerals: quartz and M-Kaolinite. Neutron activation analysis in conjunction with multivariate statistical methods were applied for the ceramic characterization and classification. An homogeneous group was established by all sherds collected from Alto Alegre and was distinct from all the other two groups analyzed. Some of the sherds collected from Xipamanu I appeared in Lobao's urns, probably because they had the same fabrication process. The Lobao's urns presented a homogeneous group. Geochronology of these materials was carried out by Thermoluminescence. The Xipamanu I was the oldest site and Lobao the youngest. The average age of Xipamanu I and Alto Alegre were 2600 and 2070 years respectively. The average age of of occupation was 400 years to Alto Alegre and 970 years to Xipamanu I. The most probably date for Lobao was 1880 years. (author)

  13. Construction and characterization in vitro of a bicistronic retroviral vector coding endostatin and interleukin-2 for use in gene therapy; Construcao e caracterizacao in vitro de um vetor retroviral bicistronico codificando endostatina e interleucina-2 para utilizacao em terapia genica

    Energy Technology Data Exchange (ETDEWEB)

    Calvo, Fernanda Bernardes

    2009-07-01

    Gene therapy has been used in preclinical studies and clinical trials in order to alleviate or cure a disease. Retroviral vectors are a tool for gene transfer is widely used. Bicistronic vectors are an attractive alternative for treatment of complex diseases. A variety of options exists to simultaneously express two genes in genetically modified cells. The most common approach relies on bicistronic vectors in which the genes are linked to each other by an internal ribosome entry site allowing co-translational expression of both cistrons. Endostatin, the C-terminal fragment of collagen XVIII, is a potent angiogenesis inhibitor. At present, ES has been widely used in anti-angiogenic in a variety of experimental tumor models, and clinical trials to test it as an anti-tumor agent are already under way. Immunotherapy has been used as adjuvant treatment for tumors and has been used in several preclinical studies and clinical trials. The objective of this project was to construct and characterize 'in vitro' an IRES-based bicistronic retroviral vector encoding endostatin and interleukin-2. The construction of the vector was performed in three stages, the final construction was analyzed by restriction analysis and sequencing. Packaging cells were prepared. The endostatin and interleukin-2 levels were determined by Dot blot. Monocistronic and bicistronic mRNA expression were analyzed by real time RT-PCR. Bicistronic vector showed high levels of virus trites, ranging from 4.20x10{sup 5} to 1.53x10{sup 6}UFC/ml. Secreted levels of endostatin and interleukin-2 ranged from 1.08 to 2.08{mu}g/10{sup 6}cells.24h and 0.66 - 0.89{mu}g/10{sup 6}cells.24h, respectively. The mRNA expression of ES in the NIH3T3 clone pLend-IRES-IL2SN was 2 times higher than the level presented by the NIH3T3 clone pLendSN. The endostatin promoted inhibition (40%) of endothelial cell proliferation. Interleukin-2 promoted a proliferation of 10.6% lymphocytes CD4 and 8.9% of CD8. We conclude that the IRES bicistronic vector provides a powerful tool for studies of cell biology of cancer and new therapeutic strategies. (author)

  14. Characterization of diesel oil mixtures with soy oil used for activation of engines of internal combustion; Caracterizacao de misturas de oleo diesel com oleo de soja reutilizado para acionamento de motores de combustao interna

    Energy Technology Data Exchange (ETDEWEB)

    Siqueira, Wagner da Cunha; Fernandes, Haroldo Carlos; Teixiera, Mauri Martins; Abrahao, Selma Alves; Leite, Daniel Mariano [Universidade de Vicosa, (DEA/UFV), MG (Brazil). Dept. de Engenharia Agricola], Emails: wagner.siqueira@ufv.br, haroldo@ufv.br, mauri@ufv.br, selma.abrahao@ufv.br, daniel.mariano@ufv.br

    2011-07-01

    Alternative energy sources have been studied in several countries, with emphasis on ways of obtaining and using more efficient. The objective of this work to evaluate and characterize mixtures of diesel oil (DO) with soybean oil reused (OSR), the ratios of 0, 25, 50, 75, and 100% of OSR in relation to specific gravity index viscosity and calorific value. To determine the specific gravity was used beaker, thermometer and a balance for each mixture was adjusted a regression model to estimate the bulk density as a function of temperature (25 to 90 deg C). We analyzed the viscosity of the mixtures using an orifice-type viscometer Saybolt, through regression analysis models were fit to estimate the viscosity as a function of temperature, heating the OSR 100% from 40 to 90 deg C decreased by up 90.4% to its viscosity. The tests were performed calorimetric using a bomb calorimeter determines the calorific value , the variation in calorific value followed a descending order with respect to OD with the increasing content of OSR. The OSR is efficient for use in internal combustion engines in small proportions. (author)

  15. Dating and characterization of archaeological ceramics of the Araruama area at Rio de Janeiro, Brazil; Datacao e caracterizacao de ceramicas arqueologicas da regiao de Araruama no Estado do Rio de Janeiro

    Energy Technology Data Exchange (ETDEWEB)

    Vinagre Filho, Ubirajara M. [Instituto de Engenharia Nuclear (IEN), Rio de Janeiro, RJ (Brazil); Bellido, Alfredo V.B.; Latini, Rose M. [Universidade Federal Fluminense, Niteroi, RJ (Brazil). Inst. de Quimica; Buarque, Angela [Museu Nacional, Rio de Janeiro, RJ (Brazil); Rossi, Alexandre M. [Centro Brasileiro de Pesquisas Fisicas (CBPF), Rio de Janeiro, RJ (Brazil)

    2000-07-01

    Ceramic of three archaeological sites (Serrano, Morro Grande, and condominium Bela Vista) of the Araruama area (Rio de Janeiro/Brazil), are being dated by the thermoluminescence technique. These ceramics are being characterized, in your elementary chemical composition, by INAA. Preliminary results are presented and the samples treatment method is described. (author)

  16. Synthesis and characterization of polyurethanes derived from cyclodextrins and poli (ethyleneglycol); Sintese, caracterizacao e avaliacao da capacidade de inclusao de poliuretanos derivados de cicodextrina e poli(etileno)glicol

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Marcia V.G. de; Vieira, Joao V.F.; Zawadzki, Sonia F., E-mail: zawadzki@ufpr.br [Universidade Federal do Parana - UFPR, Dept. de Quimica, Lab. de Polimeros Sinteticos (LABPOL), Curitiba, PR (Brazil)

    2011-07-01

    Cyclodextrins are natural cyclic oligosaccharides that have the ability to form inclusion complexes with various chemical species. In this work, the polymers with beta-cyclodextrin (BCD) or hydroxypropyl-beta-cyclodextrin (HPBCD) were synthesized from the reaction with poly (ethylene) glycol (PEG400, PEG1500, PEG4000) and diisocyanate, toluene 2,4 and 3,6 (TDI) in a solution of dimethylformamide (DMF). The polymers were characterized by infrared Fourier transform spectroscopy (FTIR), thermogravimetric analysis (TGA) and X-ray diffraction (XRD). The encapsulation capacity was evaluated by calorimetric method of discoloration of the alkaline solution of phenolphthalein. FTIR analysis revealed that assignments confirmed the formation of urethane linkages. TGA was evidenced by the mass loss in three stages and the evaluation results by XRD showed a crosslinking process. The evaluation of the encapsulation capacity of the units of the cyclodextrin crosslinked polymer showed that encapsulation increased proportionally to the mass of polymer used. (author)

  17. Synthesis and characterization of chitosan-graft-poly(acrylic acid)/rice husk ash hydrogels composites; Sintese e caracterizacao de hidrogeis compositos de cinza da casca de arroz e quitosana enxertada com poli(acido acrilico)

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Francisco H.A. [Universidade Estadual Vale do Acarau - UVA, Sobral, CE (Brazil); Lopes, Gabriel V.; Pereira, Antonio G.B.; Fajardo, Andre R.; Muniz, Edvani C. [Universidade Estadual de Maringa - UEM, PR (Brazil)

    2011-07-01

    According to environmental concerns, super absorbent hydrogel composites were synthesized based on rice husk ash (RHA), an industrial waste, and Chitosan-graft-poly(acrylic acid). The WAXS and FTIR data confirmed the syntheses of hydrogel composites. The effect of crystalline or amorphous RHA on water uptake was investigated. It was found that the RHA in crystalline form induces higher water capacity (W{sub eq}) of composites hydrogels due to the fact that the intra-interactions among silanol groups on RHA make available new sites in the polymer matrix, which could interact to water. (author)

  18. Characterization of the wind behavior in Botucatu-SP region (Brazil) by Weibull distributing; Caracterizacao do comportamento eolico da regiao de Botucatu-SP atraves da distribuicao de Weibull

    Energy Technology Data Exchange (ETDEWEB)

    Gabriel Filho, Luis Roberto Almeida [Universidade Estadual Paulista (CE/UNESP), Tupa, SP (Brazil). Coordenacao de Estagio; Cremasco, Camila Pires [Faculdade de Tecnologia de Presidente Prudente, SP (Brazil); Seraphim, Odivaldo Jose [Universidade Estadual Paulista (FCA/UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas; Cagnon, Jose Angelo [Universidade Estadual Paulista (FEB/UNESP), Bauru, SP (Brazil). Faculdade de Engenharia

    2008-07-01

    The wind behavior of a region can be described by frequency distribution that provide information and characteristics needed for a possible deployment of wind energy harvesting in the region. These characteristics, such as the annual average speed, the variance and shunting line standard of the registered speeds and the density of aeolian power average hourly, can be gotten by the frequency of occurrence of determined speed, that in turn must be studied through analytical expressions. The more adjusted analytical function for aeolian distributions is the function of density of Weibull, that can be determined by numerical methods and linear regressions. Once you have determined this function, all wind characteristics mentioned above may be determined accurately. The objective of this work is to characterize the aeolian behavior in the region of Botucatu-SP and to determine the energy potential for implementation of aeolian turbines. For the development of the present research, was used an Monitorial Young Wind anemometer of Campbell company installed a 10 meters of height. The experiment was developed in the Nucleus of Alternative Energies and Renewed - NEAR of the Laboratory of Agricultural Energize of the Department of Agricultural Engineering of the UNESP, Agronomy Sciences Faculty, Lageado Experimental Farm, located in the city of Botucatu - SP. The geographic localization is defined by the coordinates 22 deg 51' South latitude (S) and 48 deg 26' Longitude West (W) and average altitude of 786 meters above sea level. The analysis was carried through using registers of speed of the wind during the period of September of 2004 the September of 2005. After determined the distribution of frequencies of the hourly average speed of the wind, it was determined function of associated Weibull, thus making possible the determination of the annual average speed of the wind (2,77 m/s), of the shunting line standard of the registered speeds (0,55 m/s), of the coefficient of variation (20%) and of the density of aeolian power average hourly (24,58 W/m{sup 2}). (author)

  19. Purification and characterization of b-lapachone and stability study of the crystals under different storing conditions; Purificacao e caracterizacao da b-lapachona e estudo de estabilidade dos cristais em diferentes condicoes de armazenamento

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Geisiane Maria Cavalcante; Rolim, Larissa Araujo; Rolim Neto, Pedro Jose; Leite, Ana Cristina Lima; Brondani, Dalci Jose [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Dept. de Ciencias Farmaceuticas]. E-mail: pedro.rolim@pq.cnpq.br; Medeiros, Flavia Patricia Morais de [Laboratorio Farmaceutico do Estado de Pernambuco, Recife, PE (Brazil); Bieber, Lothar W. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Dept. de Quimica Fundamental; Mendonca Junior, Francisco Jaime Bezerra [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Dept. de Antibioticos

    2008-07-01

    The beta-lapachone is a product obtained from the Ipe Roxo tree [Tabebuia avellandae], which has proved its excellent antineoplasic potential acting through a particular mechanism of apoptosis against various cancer types. This study aims at determining the identity card of beta-lapachone by means of physico-chemical and pharmaco-technical characterization. A purifying process has been performed, as well as the isolation of a contaminant, its isomer alpha-lapachone. A stability study was also performed, determining the ideal storing conditions for beta-lapachone, essential for the ongoing pre-formulation studies for obtaining the different classic pharmaceutical forms and modified release systems. (author)

  20. L-alanine detector characterization for dosimetry of small fields in SBRT with VMAT techniques; Caracterizacao do detector de L-alanina para dosimetria de campos pequenos em SBRT com a tecnica de VMAT

    Energy Technology Data Exchange (ETDEWEB)

    Mazaro, Sarah J.; Peres, Leonardo [Instituto Nacional de Cancer (INCA), Rio de Janeiro, RJ (Brazil); Baffa, Oswaldo, E-mail: sarahmazaro@yahoo.com.br [Universidade de Sao Paulo (USP), Ribeirao Preto, SP (Brazil). Faculdade de Filosofia, Ciencias e Letras. Departamento de Fisica

    2016-07-01

    New radiotherapy treatment techniques have some problems such as: the dosimetric and geometric of the beam and small fields. Determination of the prescribed dose on the target volume in small fields is hampered due to lack of lateral electronic equilibrium and steep dose gradient along the edges of fields. The choice of radiation better detector becomes important in the dosimetry of small fields. Alanine detector has been shown to be a good choice for measurements of high doses of radiation in small fields. This study aims to characterize the L-alanine detector through the dosimetric tests for SBRT in VMAT techniques. L-alanine response showed a strong linear correlation with the dose (R ² = 0.9865), with significant angles and dose rate dependencies (14%) and (15%) respectively, and minor with the small field size (maximum 4% deviation). (author)

  1. Technological characterization of basaltic rocks of Canoas I Hydroelectric Power Plant, Paranapanema river, Sao Paulo - Parana states, Brazil; Caracterizacao tecnologica das rochas basalticas da Usina Hidroeletrica Canoas I, Rio Paranapanema, SP/PR

    Energy Technology Data Exchange (ETDEWEB)

    Marrano, Antonio

    1997-07-01

    Basaltic litotypes from the rock mass foundation of Canoas I Hydroelectric Power Plant were submitted to technological characterization tests, in order to verify their suitability as construction material. Physical and mechanical properties (density, porosity, water absorption, ultrasonic velocity, compressive and splitting tensile strength, among others) were determined, besides petrographic analyses. Weather ability tests were also performed, not only through wetting-drying cycles and by immersion in ethylene glycol but by outdoor exposure as well, using crushed and core drilled specimens. Detailed procedures for the weather ability test using core specimens from rotary drilling are given. It is analyzed the influence of a geological feature (fault zone, about 10 meters thick and 20 degrees dip), that occurs in the rock mass foundation, on the technological properties of these rocks. Basaltic litotypes selected as construction material are then pointed out. (author)

  2. Characterization of gadolinia-doped ceria with manganese addition synthesized by the cation complexation technique; Caracterizacao de ceria-gadolinia e ceria-gadolinia-manganes sintetizados pelo metodo de complexacao de cations

    Energy Technology Data Exchange (ETDEWEB)

    Yang, J.D.; Muccillo, R.; Muccillo, E.N.S., E-mail: enavarro@usp.b [Instituto de Pesquisas Energeticas e Nucleares (CCTM/IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro de Ciencia e Tecnologia de Materiais; Rocha, R.A. [Universidade Federal do ABC (CEMCSA/UFABC), Santo Andre, SP (Brazil). Centro de Engenharia, Modelagem e Ciencias Sociais Aplicadas

    2010-07-01

    Ceria-based compounds may be used for several technological applications like catalysts, grinding media and materials for electrolyte and electrodes in solid oxide fuel cells. For most of these applications fine powders are required. In this work, nanostructured ceria powders containing 20 mol % gadolinia with and without manganese addition were synthesized by the cation complexation technique. The prepared powders were calcined at 600 deg C for thermal decomposition of the metal citrate precursors. Results of X-ray diffraction, scanning electron microscopy and specific surface area evidenced the role of manganese on physical characteristics of the nanostructured materials. The cation complexation technique revealed to be a promising method for obtaining nanostructured powders with high yield and suitable physical properties for several technological applications. (author)

  3. Fabrication, characterization and tests on Si{sub 3} N{sub 4} cutting tools; Fabricacao, caracterizacao e testes em ferramentas de corte de Si{sub 3} N{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Oliverio Moreira de Macedo; Silva, Cosme Roberto Moreira da; Piorino Neto, Francisco [Centro Tecnico Aeroespacial (CTA), Sao Jose dos Campos, SP (Brazil)

    1997-12-31

    Silicon nitride based ceramic cutting tools were developed in Brazil. Itria and aluminium nitride has been used as sintering aids. The samples evaluations were performed using, specific mass determination, X ray diffraction, microhardness testing, fracture toughness by by indentation method and microstructural examination via scanning electron microscopy. After samples evaluation, some pressureless sintering silicon nitride based ceramic cutting tools were made. A piece of cast iron was machined using these cutting tools. For the purpose of comparison, a commercial hard metal cutting tools have also been used to perform the same machining. (author) 5 refs., 6 figs., 5 tabs.

  4. Sintering and microstructural characterization of the silicon nitride activated with niobium, praseodymium and neodymium oxides; Sinterizacao e caracterizacao microestrutural do nitreto de silicio aditivado com niobia, preaseodimia e neodimia

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Cosme Roberto Moreira da; Folgueras, Luiza de Castro [Centro Tecnico Aeroespacial (CTA), Sao Jose dos Campos, SP (Brazil). Inst. de Atividades Espaciais

    1997-12-31

    The aim of this work is the sintering and characterization of silicon nitride with neodimia, niobia and praseodimia additions. The sintering process was performed at 1750 deg C, during 30 minutes. The characterization induced porosity determination, additive distribution X-ray diffraction and Knoop microhardness evaluation. Higher density and more effective {alpha}-> {beta} transformation has been achieved on samples with praseodimia/neodimia additions. These results are associated with more effective liquid phase sintering mechanism, operative for such compositions. It will enable bigger wetting of silicon nitride grains, higher solubility and diffusion via liquid phase, in comparison with niobia/neodimia samples. (author) 9 refs., 4 figs., 2 tabs.

  5. Description of station waste water treatment and study of reclaiming industry ceramic red; Caracterizacao de residuos de estacao de tratamento de agua e estudo de reaproveitamento na industria de ceramica vermelha

    Energy Technology Data Exchange (ETDEWEB)

    Yadava, Y.P.; Rego, S.A.B.C.; Junior, B.S.; Bezerra, L.P.; Ferreira, R.A.S., E-mail: yadava@ufpe.br [Universidade Federal de Pernambuco (UFPE), PE (Brazil)

    2012-07-01

    So that the water meets potability standards required by the laws it passes through various treatment processes which generate waste called WTS (Water Treatment Sludge). This sludge is disposed of without any processing, however, environmental agencies and the public are demanding alternatives to this situation. Knowing this, this study aims to characterize the sludge from the Water Treatment Plant Botafogo and analyze its viability as a feedstock in the manufacture of red bricks. (author)

  6. Synthesis and characterization of {alpha}zirconium (IV) hydrogenphosphate containing metallic copper clusters; Sintese e caracterizacao de {alpha}-fosfato de zirconio(IV) contendo agregados de cobre metalico

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Alexilda Oliveira de [Universidade Estadual do Sudoeste da Bahia, Itapetinga, BA (Brazil). Dept. de Estudos Basicos e Instrumentais; Rangel, Maria do Carmo [Bahia Univ., Salvador, BA (Brazil). Inst. de Quimica. Dept. de Fisico-Quimica; Alves, Oswaldo Luiz [Universidade Estadual de Campinas, SP (Brazil). Inst. de Quimica. Dept. de Quimica Inorganica]. E-mail: alexilda@uesb.br

    2005-02-01

    The {alpha}-zirconium (IV) hydrogenphosphate ({alpha}-ZrP) has received great attention in the last years due to its properties like ion exchange, intercalation, ionic conductivity and catalytic activity. This work reports a method to produce metallic copper clusters on {alpha}-ZrP to be used as catalysts in petrochemical processes. It was found that the solids were non-crystalline regardless of the uptake of copper and the reduction. The specific surface area increased as a consequence of the increase of the interlayer distance to accept the copper ions between the layers. During the reduction, big clusters of copper (0,5-11{mu}) with different sizes and shapes were produced. (author)

  7. Physical characterisation of particles and rheological of a heterogeneous system used in low-pressure injection moulding; Caracterizacao fisica de particulas e reologica de um sistema heterogeneo utilizado em moldagem de pos por injecao a baixa pressao

    Energy Technology Data Exchange (ETDEWEB)

    Zampieron, Joao Vicente

    2002-07-01

    The powder injection moulding process is a recent technology, which offers as advantages a high production of complex geometry metal parts, with low cost, where secondary operations of machinery are unnecessary. The main of this thesis was centered on a coarse powders feedstock injection. The process begins with the composition of the mass, that is the combination of metal powders with organic binders. The following steps succeed injection in moulds, debinding, sintering and, if necessary, cleaning. For the formulation of the feedstock it is indispensable the characterisation of the powders. This is little mentioned in the open literature and brings up controversy among authors. At first, a series of powders characterisations of AISI 316 L stainless steel (below 25 {mu}m) was adopted. The next step was to characterise the rheological behaviour of the feedstock using different rheological apparatus, so as to find the most appropriate equipment to the low-pressure powder injection molding process. The mass has to present a favourable rheological behaviour, which is low viscosity. The results of the physical characterisation were correlated among themselves and with the rheological characterisation. This was undertaken with the purpose of finding agreement among their values. Finally, the possibility of injection of water and gas atomised stainless steel coarse powders feedstock was studied. This presents as main advantage, the reduction of costs for the process. According to the literature, only powders with size below 25 {mu}m are possible to be injected. Hence, starting from the physical characterisation of particles and rheological characterisation of the feedstock, the formulation of an appropriate mass was found for the coarse powders. These coarse powders were characterised by particles below 45 {mu}m. In this case it was necessary to alter drastically the feedstock composition, using high amounts of wax, which lead to unstable rheological conditions. But, it was verified that feedstock constituted of coarse metallic powders which were gas atomised, are injectable, although, these powders resulted in samples with a high porosity level, while, coarse water atomised powders did not present work conditions, being therefore, discarded. (author)

  8. Fabrication and electrical characterization of polyaniline-silicon heterojunction for gamma radiation dosimetry application; Fabricacao e caracterizacao eletrica de heterojuncoes de polianilina - silicio para aplicacao em dosimetria de radiacao gama

    Energy Technology Data Exchange (ETDEWEB)

    Laranjeira, Jane Maria Goncalves

    2004-08-15

    In this work a technique has been developed to fabricate high quality polyaniline-silicon heterojunction diodes for use as gas and/or ionizing radiation sensors. Polyaniline thin films (40 nm thick) produced by spin-coating on silicon substrates, were the active part of the junction structure. The devices presented excellent reproducibility of their electrical characteristics with high rectification ratio, 60,000 at {+-}1.0 V, and typical reverse current at - 1.0 V of 3 nA at 295 K. A G/I x G plot has been used to analyze the current-voltage characteristics, yielding typical series resistance of 4 k{omega} {+-} 5% and ideality factor in a range of 1,9 {+-} 0.5%. The heterojunction diode presents high sensitivity to gamma radiation in the dose range of 3 x 10{sup -2} to 7 kGy with a linear response in the forward and reverse bias. The excellent electrical characteristics together with the linear response with the dose, strongly suggest the application of this device for spectrometry or dosimetry of high doses of gamma radiation. These devices presented high sensitivity to gas moistures such as ammonia, nitric acid and trichloroethylene. In both cases the sensitivity was observed through shifts of the current-voltage curves, which can be easily monitored to provide a calibration curve of the sensor either as a radiation dosimeter or as a gas sensor for use in applications for gas monitoring or radiation dosimetry. Several aspects of the reliability physics of silicon-polyaniline heterojunction, such as degradation effects induced by local heating, charge trapping and temperature changes, have been discussed. These results further confirm the quality of the devices electrical characteristics and their suitability for radiation and gas sensors applications. Another interesting results presented in this work was the use of polyemeraldine nanofilms (thickness in the range 30-50 nm) deposited by 'spin coating' on glass substrates as an optical dosimeter for gamma radiation based on the color change of the polymer. The nanofilms devices were characterized by UV visible absorption spectroscopy. The deep blue color, characteristic of undoped polyaniline films before irradiation, becomes subsequently green as the film is being irradiated, and the film absorption coefficient exhibits a linear dependence with the logarithm of the irradiation dose from I to 10 kGy. (author)

  9. Co-coagulation of the NBR latex and clay aqueous suspension: preparation and characterization;Co-coagulacao de latex de NBR e suspensao aquosa de argila: preparacao e caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Reis, Raquel S.; Brum, Elisson; Silva, Vanessa M. [Nitriflex S/A Industria e Comercio, Rio de Janeiro, RJ (Brazil); Souza, Diego H.S.; Gomes, Ailton de S.; Nunes, Regina C.R., E-mail: rcnunes@ima.ufrj.b [Universidade Federal do Rio de Janeiro (IMA/UFRJ), RJ (Brazil). Inst. de Macromoleculas Profa. Eloisa Mano

    2009-07-01

    Blends of nitrile rubber (NBR) and sodium montmorillonite (MMT-Na) were prepared by co-coagulation of the NBR latex with aqueous suspension of clay. The content of MMT was varied from 0 to 7 phr and different mixtures were analyzed by X-ray diffraction, light scattering, gel content, thermogravimetric analysis and the oscillating disk rheometer. The different methods used indicated that there was formation of a structure interspersed in the mixtures studied, and that increasing the content MMT-Na enhances the values obtained. Rheological measurements on compositions with NBR showed the influence of clay on increasing the time of healing in terms of its content, as is the gel content and the thermal resistance. All results were compared to composition of NBR without MMT. (author)

  10. Synthesis and characterization of particles derived of poly(vinyl alcohol) (PVA) for treatment of embolization and chemoembolization;Sintese e caracterizacao de particulas derivadas de poli(alcool vinilico) (PVA) para embolizacao e quimioembolizacao

    Energy Technology Data Exchange (ETDEWEB)

    Semenzim, Vinicius L.; Basso, Glaucia G.; Passos, Rodrigo A.; Nery, Jose G. [UNESP, Sao Jose do Rio Preto, SP (Brazil); Agreli, Guilherme; Oliveira, Ana P.M.L.; Kawasaki-Oyama, Rosa S.; Braile, Domingo M., E-mail: nery@ibilce.unesp.b [Braile Biomedica Industria e Comercio Representacoes S.A., Sao Jose do Rio Preto, SP (Brazil)

    2009-07-01

    The most effective way to treat cancerous tumors is by surgically removing them. However in some types of cancer, such as liver and uterine cancer, more than two-thirds of patients have no indication for surgery due to the size and location of the tumor, such as into the blood vessels. Doctors and researchers have invested in alternative and less invasive methods such as chemoembolization. The objectives of this research project are the synthesis and characterization of poly(vinyl alcohol) (PVA) particles for use in cancer treatment. PVA particles will be combined with chemotherapeutic agent Doxorubicin, drug commonly used in the treatment of cancers and carcinomas. The particles, obtained by controlled polymerization reaction followed by saponification, were characterized by SEM, XRD and NMR-CP/MAS. The functionalization of the particles with the drug is the next step of this study. (author)

  11. Fractioning of sodium polyphosphate and characterization by {sup 31}P NMR: a experience to physical-chemistry lessons; Fracionamento de polifosfato de sodio e caracterizacao por RMN de 31P: um experimento para aulas de Fisico-Quimica

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Emilia Celma de Oliveira; Alcantara, Glaucia Braz Alcantara; Damasceno, Fernando Cruvinel, E-mail: elima@quimica.ufg.b [Universidade Federal de Goias (UFG), Goiania, GO (Brazil). Inst. de Quimica; Moita Neto, Jose Machado [Universidade Federal do Piaui (UFPI), Teresina, PI (Brazil). Dept. de Quimica; Galembeck, Fernando [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Inst. de Quimica

    2010-07-01

    This text describes an experiment on fractional precipitation of a polymer together with determination of average degree of polymerization by NMR. Commercial sodium polyphosphate was fractionated by precipitation from aqueous solution by adding increasing amounts of acetone. The polydisperse salt and nine fractions obtained from it were analyzed by {sup 31}P nuclear magnetic resonance and the degree of polymerization of the salts and of the fractions were calculated. Long-chain sodium polyphosphate was also synthesized and analyzed. This experiment was tested in a PChem lab course but it can be used also to illustrate topics of inorganic polymers and analytical chemistry. (author)

  12. Preparation and characterization of zirconia-yttria porous ceramics with addition of potassium iodide; Preparacao e caracterizacao de ceramicas porosas de zirconia-itria com adicao de iodeto de potassio

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, S.G.M.; Muccillo, R., E-mail: sabrina.carvalho@usp.br, E-mail: muccillo@usp.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP/CCTM), Sao Paulo, SP (Brazil). Centro de Ciencia e Tecnologia de Materiais

    2012-07-01

    Porous zirconia stabilized with 8 mol% of yttria were prepared by adding different amounts of KI followed by its removal upon sintering. The thermal removal was evaluated by thermogravimetric and differential thermal analysis and dilatometric measurements. The samples were prepared and sintered at 1400 deg C/2h. All samples were characterized by X-ray diffraction and topographic analysis of polished and thermally etched surface to evaluate pore content. The additive content was evaluated by X-ray fluorescence analysis, showing that KI was removed during sintering. The electrical behavior was analyzed by impedance spectroscopy. The X- ray diffraction analyses show that all samples are single phase, cubic fluorite-type. The impedance diagrams allowed evaluating the increase in intergranular and intragranular resistivity with increasing content of pores. (author)

  13. Structural and morphological characterization of TiO{sub 2} powders prepared using Pechini and combustion reaction; Caracterizacao estrutural e morfologica de nanopos de TiO{sub 2} preparados pelo metodo Pechini e por reacao de combustao

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, P.C.; Almeida, E.P.; Costa, A.C.F.M. da; Lira, H.L., E-mail: pollyanacae@yahoo.com.b [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Dept. de Engenharia de Materiais; Kiminami, R.H.G.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Dept. de Engenharia de Materiais

    2010-07-01

    TiO{sub 2} is a semiconductor oxide and polymorphic and can exist in three crystallographic forms: anatase, rutile and broquita, and forms anatase and rutile are the major interests in scientific research. Thus, this study aims to synthesize TiO{sub 2} by Pechini methods and combustion reaction and to evaluate the influence of synthesis methods in structural and morphological characteristics of the samples. The nanopowders were characterized by X-ray diffraction, nitrogen adsorption, and particle size distribution and scanning electron microscopy. The results of X-ray diffraction showed that the samples obtained by the Pechini method showed the single phase anatase with crystallite size of 20 nm and surface area of 49.44 m{sup 2}/g, whereas the samples synthesized by combustion reaction using glycine as fuel showed the rutile phase as major phase and traces of anatase phase, with crystallite size of 65 nm and surface area 4.34 m{sup 2}/g. (author)

  14. Synthesis of poly(D,L-lactide-co-glycolide) copolymers and its chemical characterization by NMR and FTIR; Sintese e caracterizacao quimica por RMN e FTIR do copolimero poli(D,L-lactideo-co-glicolideo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    Poly(D,L-lactide-co-glycolide) copolymer is of great interest for medical applications. This interest is justified by the fact that it is bioreabsorbable, biocompatible and non-toxic, while its degradation kinetics can be modified by the copolymerization ratio of the monomers. In this study, copolymers were synthesized at 175 deg C by opening the rings of the cyclic dimers of the D,L-lactide and glycolide monomers in the presence of stannous octoate initiator and lauryl alcohol co-initiator. The efficient application of a vacuum to the reaction medium, coupled with adequate stirring, is fundamental for the success of the synthesis. The following analysis techniques were used to characterize the synthesized copolymers: Nuclear Magnetic Resonance Spectroscopy (NMR) and Fourier Transform Infrared Spectroscopy (FTIR). The chemical composition and the ratio of the monomers in the synthesized copolymer were determined. (author)

  15. E-waste: development of recycling process and chemical characterization of circuit printed - motherboard; Lixo eletronico: desenvolvimento de processo de reciclagem e caracterizacao quimica de placa de circuito impresso - motherboard

    Energy Technology Data Exchange (ETDEWEB)

    Junior, O.L.F.; Vargas, R.A.; Andreoli, M.; Martinelli, J.R.; Seo, E.S.M., E-mail: olfjunior@usp.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN-CNEN/SP), Sao Paulo, SP (Brazil)

    2011-07-01

    The electro-electronic industry has been regulated by the National Politic of Solid Residues Act (PNRS) and Bill no. 7.404, concerning the actions, procedures, and method to collect, recycle and promotion of environmentally acceptable final destination of residues. The present work contributes to develop recycling process of printed circuit used in microcomputers and in its chemical characterization. The experimental procedure consisted of grinding, classification, magnetic and electrostatic separation, and separation based on density difference, followed by chemical characterization of the metallic and non metallic materials in the motherboard. It was determined that the amounts of Ag, Al, Ba, Cl, Cr, Cu, Fe, Mn, Pb, and Zn in the residue are above the toxicity allowable levels, and they are in the samples of the decanted material. Among the samples of the floating material, Al, Ba, Br, Ca, Cu, Fe, Pb (in less quantity), Si (in more quantity), and Sn, Ti and Zn were detected. Those materials can be useful in the preparation of red ceramics. (author)

  16. Characterization of the oligosaccharide structure of human glycosylated prolactin (G-hPRL) native and recombinant; Caracterizacao da estrutura oligossacaridica de prolactina glicosilada humana (G-hPRL) nativa e recombinante

    Energy Technology Data Exchange (ETDEWEB)

    Marcos Vinicius Nucci Capone

    2013-07-01

    Human prolactin (hPRL) is a polypeptide hormone secreted by the anterior pituitary under the regulation of the hypothalamus, involved in a variety of biological processes such as mammary gland development and lactation. The recombinant product is important in medical diagnosis and treatment of failure of lactation. This hormone may occur in the form of non-glycosylated protein (NGhPRL) and glycosylated (G-hPRL) with molecular weights of approximately 23 and 25 kilodalton (kDa), respectively; has a single N-glycosylation site located at asparagine (Asn) position 31, which is partially occupied, thus being a particularly interesting model of glycosylation. The biological activity of G-hPRL is lower compared to NG-hPRL (~4 times) and its physiological function is not well defined: the portion of carbohydrate appears to have an important role in the hormone biosynthesis, secretion, biological activity, and plasma survival of the hormone. The main objective of this study was to compare the structures of N-glycans present in glycosylated pituitary prolactin (G-hPRL-NHPP) with those present in the recombinant. To obtain the recombinant G-hPRL the production was performed in laboratory scale from Chinese hamster ovary cells (CHO), genetically modified and adapted to growth in suspension. Cycloheximide (CHX), whose main effect was to increase the ratio G-hPRL/NG-hPRL from 5% to 38% was added to the culture medium, thereby facilitating the purification of G-hPRL. The G-hPRL was purified in two steps, a cation exchanger followed by a purification by reversed-phase high performance liquid chromatography (RP-HPLC) which demonstrated the efficient separation of the two isoforms of hPRL. Recombinant G-hPRL-IPEN was well characterized by several techniques confirming its purity and biological activity, including comparisons with other reference preparation of pituitary origin purchased from the {sup N}ational Hormone & Peptide Program (NHPPU. S.){sup .} The composition of N-glycans present in the G-hPRL, produced by CHO cells, and that of native G-hPRL, produced by the human pituitary gland, were also determined for the first time, allowing the two structures of carbohydrates to be compared and thus, achieving one of the main goals of this project. Among the main differences in N-glycan structures, we highlight the low presence of sialic acid (NeuAc) and the high percentage of sulfated glycans (74.0%) and of fucose (Fuc) (93.3%) in the pituitary sample and the tendency of the recombinant preparation to present glycans with higher molecular weight and less isoforms variation. (author)

  17. OSBRA right of way characterization in Vila Estrutural, Brasilia, Brazil; Caracterizacao de faixa do OSBRA na Vila Estrutural em Brasilia - evidencia de uma nova relacao da TRANSPETRO com a comunidade

    Energy Technology Data Exchange (ETDEWEB)

    Brito, Walderes Lima de; Castro, Newton Camelo de [TRANSPETRO - PETROBRAS Transporte S.A., Rio de Janeiro, RJ (Brazil); Braga, Gilberto Vieira [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2005-07-01

    In this project we will introduce the relationship experience between TRANSPETRO and Vila Estrutural community, located in Guara, D.C., what we consider a social responsibility practice and an important tool of the integrity maintenance of right of way pipelines, considering the risks caused by other people actions. In this specific case, Vila Estrutural is the most critical one, of Sao Paulo - Brasilia pipelines (OSBRA): irregular occupations, with an estimated population by 25,000 people, with an inhabit strangle and development constructions tendency in the straight ahead direction of pipelines. To deal with this reality, OSBRA management created a strategy called 'Acquaintance Communication', increasing the knowledge about the community (diagnostic), promoting to yours employees an acquaintance culture (qualifying); developing communications strategies with those that live nearby right of the pipelines way (relationship); and finally, building the stonemason of the characterization of the right of way pipelines as a real device and right of the way protection (framing). This work is lined up with the idea of an integrated communication, using many strategies (visits, meetings, argument groups, etc.), constituting in a corporative social responsibility practice, admitting the community right of information and knowing it the right manner of living nearby the right of way pipeline, resulting in the equipment integrity, asserting the community safety and environment maintenance. (author)

  18. Bio diesel from soybean: characterization and consumption in an energy generator; Biodiesel de soja - taxa de conversao em esteres etilicos, caracterizacao fisico-quimica e consumo em gerador de energia

    Energy Technology Data Exchange (ETDEWEB)

    Ferrari, Roseli Aparecida; Oliveira, Vanessa da Silva; Scabio, Ardalla [Universidade Estadual de Ponta Grossa, PR (Brazil). Dept. de Engenharia de Alimentos]. E-mail: ferrarir@uepg.br

    2005-02-01

    Biodiesel was produced by the transesterification of neutral soybean oil and anhydrous ethanol using NaOH as catalyst. Combinations of biodiesel and diesel in the proportions of 0, 5, 10, 20, 40, 60, 80 and 100% were tested, respectively, as fuel in an energy generator. The average consumption and mixture performance were analysed. The tests showed a reduction in Diesel oil consumption when mixed with up to 20% of biodiesel. The quality characteristics of these fuels were analyzed. (author)

  19. Obtention of polyester-montmorillonite (MMT) nanocomposites applied to powder coating - part 1: nanocomposites characterization;Obtencao de nanocompositos de poliester-montmorilonita (MMT) aplicados em tinta em po - parte 1: caracterizacao dos nanocompositos

    Energy Technology Data Exchange (ETDEWEB)

    Piazza, Diego; Zattera, Ademir J., E-mail: piazza@nol.com.b [Universidade de Caxias do Sul (UCS), RS (Brazil). Lab. de Polimeros; Silveira, Debora S.; Lorandi, Natalia P.; Birriel, Eliena J.; Scienza, Lisete C., E-mail: ajzattera@terra.com.b [Universidade de Caxias do Sul (UCS), RS (Brazil). Lab. de Corrosao

    2009-07-01

    The development and obtention of polymeric nanocomposites in the nanotechnology and nanoscience field have attracted great attention due to diversity of potential applications and significant property improvement when compared to conventional composites. In this work, commercial formulations of polyester-based powder coating with 0, 2 and 4% (w/w) of montmorillonite (MMT) were obtained by incorporation in the melting state and characterized by TEM, SEM, DSC, TGA and XRD. The nanocoatings were applied on the mild carbon steel panels by electrostatic paint. The microscopy analysis showed MMT in the coating film, predominantly in the exfoliated form, corroborated by XRD results. Some tactoid structures and a surface film with some defects and porous were also revealed. Progressive reduction of crosslinking temperature and thermal stability was observed in thermal analysis. The best clay dispersion in the coating and a higher quality film were achieved at 2% MMT concentration. (author)

  20. Preparation and characterization of polymer blends based on recycled PET and polyester derived by terephthalic acid; Preparacao e caracterizacao de blendas polimericas a base de PET reciclado e poliester derivado do acido tereftalico

    Energy Technology Data Exchange (ETDEWEB)

    Ohara, L.; Miranda, C.S.; Fiuza, R.P.; Luporini, S.; Carvalho, R.F.; Jose, N.M., E-mail: leandro.ohara@gmail.co [Universidade Federal da Bahia (GECIM/UFBA), Salvador, BA (Brazil). Inst. de Quimica. Grupo de Energia e Ciencias dos Materiais

    2010-07-01

    Environmentally friendly materials, made from industrial waste, are being increasingly used as a solution to the growing amount of waste generated by society, but also as a cheaper alternative to replace conventional materials for use in construction. In this work were investigated the properties of polymer blends based on recycled PET and a polyester derived from terephthalic acid and glycerin, a co-product of biodiesel. The samples were characterized by XRD, TGA, DSC, FTIR and SEM. The polyester synthesized showed a degradation event near 300 deg C. The blends with higher ratio of PET showed thermal behavior similar to pure PET. The X-ray diffraction showed that the polymer blends are semicrystalline materials. The micrographs presents the presence of a smooth surface, indicating the possibility of miscibility between the arrays. Therefore, the blending makes possible the fabrication of low-cost materials with applications in several areas. (author)