WorldWideScience

Sample records for capillary pressure saturation

  1. Pore capillary pressure and saturation of methane hydrate bearing sediments

    Institute of Scientific and Technical Information of China (English)

    SUN Shicai; LIU Changling; YE Yuguang; LIU Yufeng

    2014-01-01

    To better understand the relationship between the pore capillary pressure and hydrate saturation in sedi-ments, a new method was proposed. First, the phase equilibria of methane hydrate in fine-grained silica sands were measured. As to the equilibrium data, the pore capillary pressure and saturation of methane hydrate were calculated. The results showed that the phase equilibria of methane hydrates in fine-grained silica sands changed due to the depressed activity of pore water caused by the surface group and negatively charged characteristic of silica particles as well as the capillary pressure in small pores together. The capil-lary pressure increased with the increase of methane hydrate saturation due to the decrease of the available pore space. However, the capillary-saturation relationship could not yet be described quantitatively because of the stochastic habit of hydrate growth.

  2. A total pressure-saturation formulation of two-phase flow incorporating dynamic effects in the capillary-pressure-saturation relationship

    Energy Technology Data Exchange (ETDEWEB)

    Dahle, H.K.; Celia, M.A.; Hassanizadeh, S.M.; Karlsen, K.H.

    2002-07-01

    New theories suggest that the relationship between capillary pressure and saturation should be enhanced by a dynamic term that is proportional to the time rate of change of saturation. This so-called dynamic capillary pressure formulation is supported by laboratory experiments, and can be included in various forms of the governing equations for two-phase flow in porous media. An extended model of two-phase flow in porous media may be developed based on fractional flow curves and a total pressure - saturation description that includes the dynamic capillary pressure terms. A dimensionless form of the resulting equation set provides an ideal tool to study the relative importance of the dynamic capillary pressure effect. This equation provides a rich set of mathematical research questions, and numerical solutions to the equation provide insights into the behavior of two-phase immiscible flow. For typical two-phase flow systems, dynamic capillary pressure acts to retard infiltration fronts, with responses dependent on system parameters including boundary conditions. Recent theoretical work suggests that the traditional algebraic relationship between capillary pressure and saturation may be inadequate. Instead, a so-called dynamic capillary pressure formulation is needed, where capillary pressure is defined as a thermodynamic variable, and the difference between phase pressures is only equal to the capillary pressure at equilibrium. Under dynamic conditions, the disequilibrium between phase-pressure differences and the capillary pressure is taken to be proportional to the time rate of change of saturation. A recent study by Hassanizadeh et al. presents experimental evidence, culled from the literature, to support this claim. Numerical simulations using dynamic pore-scale network models and upscaling also support the claim. Hassanizadeh et al. also presented numerical solutions for an enhanced version of Richards' equation that included the dynamic terms. A

  3. Determination of the relationship among capillary pressure, saturation and interfacial area: a pore unit assembly approach

    Directory of Open Access Journals (Sweden)

    Nikooee E.

    2016-01-01

    Full Text Available Three state variables namely, degree of saturation (Sw, capillary pressure (Pc and specific air-water interfacial area (aaw are indispensable for modelling coupled processes relevant to unsaturated soils mechanics, agriculture, and contaminant hydrology. They play a key role in simulating various phenomena and the determination of various parameters and physical characteristics such as the unsaturated soil shear strength, field capacity, wilting point, air and water diffusivity and the rate of dissolution of contaminants. The determination of soil water retention curve (Sw-Pc as well as the specific interfacial area (aaw using available experimental techniques is a challenging and time consuming task. Therefore, a numerical technique that employs basic soil properties to obtain these variables is of much value and high practical and theoretical importance. In the current study, the porous network extracted from a discrete element model (the so-called pore unit-assembly has been used to directly model the drying and wetting processes inside a granular soil packing and to obtain the values of Pc, Sw and aaw. The results of the simulations are in good agreement with the experimental data, which points to the efficacy and adequacy of the introduced algorithms and involved assumptions for this purpose.

  4. The criterion of subscale sufficiency and its application to the relationship between static capillary pressure, saturation and interfacial areas

    Science.gov (United States)

    Kurzeja, Patrick

    2016-05-01

    Modern imaging techniques, increased simulation capabilities and extended theoretical frameworks, naturally drive the development of multiscale modelling by the question: which new information should be considered? Given the need for concise constitutive relationships and efficient data evaluation; however, one important question is often neglected: which information is sufficient? For this reason, this work introduces the formalized criterion of subscale sufficiency. This criterion states whether a chosen constitutive relationship transfers all necessary information from micro to macroscale within a multiscale framework. It further provides a scheme to improve constitutive relationships. Direct application to static capillary pressure demonstrates usefulness and conditions for subscale sufficiency of saturation and interfacial areas.

  5. The Effect of Films on the Capillary Pressure - Saturation Hysteresis in a Smooth-walled Wedge Channel

    Science.gov (United States)

    Liu, Y.; Nolte, D.; Pyrak-Nolte, L. J.

    2010-12-01

    Thin fluid films are central to many multiphase flow applications; however, experimental investigation of films requires direct detection and measurement of films. Water film thicknesses can range from a few nanometers to several micrometers and may vary depending on local pore structures and material properties. In this study, laser confocal microscopy was employed to image volumetric fluid distribution and 3D interfaces during drainage and imbibition processes in a smooth-walled channel. Confocal microscopy provides an effective method to image directly 3D thin films and to measure film thickness, volume, and other parameters. The detection resolution is 1.19 μm/pixel through a 10x objective lens and is 0.72 μm/pixel through a 20x lens. A smooth-walled wedge channel was fabricated to study the generation and relaxation of water films in the non-wetting phase of air. The effect of films on contact angle, interfacial area per volume (IAV), and capillary pressure - saturation (Pc - Sw) hysteresis were also investigated. Micromodels were fabricated using a negative photoresist (SU-8) sandwiched between two cover glasses. An all-SU-8 smooth-walled wedge channel was fabricated by laser direct-writing two-photon polymerization, 100 μm wide at the outlet and 20 μm at the inlet with a constant aperture of 40 μm. A laser scanning confocal microscope was used to image the wetting (water) and non-wetting (air) phase distributions by labeling the wetting phase with a fluorophore, Alex Fluor-488, 1.0% by wieght. The 3D air-water interfaces were imaged and then reconstructed using a stack of confocal images. The samples were initially saturated with water, the wetting phase. A series of drainage and imbibition cycles were performed by incrementing or decrementing the air pressure. At each pressure, the system was allowed to equilibrate and then a stack of scans in depth was collected to acquire the 3D fluid distribution for the given pressure. The confocal images were

  6. Modeling Relations Among Relative Permeabilities, Fluid Saturations, and Capillary Pressures in Mixed-Wet Porous Media: Model Testing and Application to Oil-Water Systems

    Energy Technology Data Exchange (ETDEWEB)

    Oostrom, Mart (BATTELLE (PACIFIC NW LAB)); Lenhard, Robert J.(INEEL); Delshad, M; Robertson, S D.(Spirit 76, Midland, TX); M.Th. van Genuchten, F.J. Leij and L. Wu

    1998-01-01

    A critical component of all multiphase flow codes is how relationships among relative permeabilities, fluid saturations, and capillary pressures (i.e., k-S-P relations) are described. Models that are able to mimic fundamental fluid-flow processes to predict k S-P relations are preferable than extrapolating measured data points to estimate k-S-P relations because they may have greater utility and may be more consistent. Furthermore, different saturation-path histories may be simulated with a computer code than those measured in the k-S-P experiments. Because the geometry of the pore spaces in natural porous media is very complex and will likely never be precisely known to predict k-S-P behavior from fundamental relationships, k-S-P models are largely empirical. In this paper, an empirical model based on theoretical considerations is developed to predict hysteretic k-S-P relations in porous media in which the smaller pores are water-wet and the larger pores are oil-wet, i.e., mixed-w et. At high oil-water capillary pressures, the water saturation is modeled to approach the residual water saturation. At low oil-water capillary pressures (i.e., negative), the oil saturation is modeled to approach the residual oil saturation. Relative permeabilities are predicted using parameters that describe main-drainage S-P relations and accounting for the distribution of water and oil in the pore spaces of mixed-wet porous media. The proposed algebraic expressions are easy to implement in multiphase flow codes and can be used to predict k-S-P relations for any saturation-path history. In addition, the model is relatively easy to calibrate to porous media.

  7. Numerical study of two-phase flows in porous media : extraction of a capillary pressure saturation curve free from boundary effects

    Science.gov (United States)

    Fiorentino, Eve-Agnès; Moura, Marcel; Jørgen Måløy, Knut; Toussaint, Renaud; Schäfer, Gerhard

    2015-04-01

    The capillary pressure saturation relationship is a key element in the resolution of hydrological problems that involve the closure partial-flow Darcy relations. This relationship is derived empirically, and the two typical curve fitting equations that are used to describe it are the Brooks-Corey and Van Genüchten models. The question we tackle is the influence of the boundary conditions of the experimental set-up on the measurement of this retention curve, resulting in a non physical pressure-saturation curve in porous media, due the "end effects" phenomenon. In this study we analyze the drainage of a two-phase flow from a quasi 2D random porous medium, and compare it to simulations arising from an invasion percolation algorithm. The medium is initially saturated with a viscous fluid, and as the pressure difference is gradually increased, air penetrates from an open inlet, thus displacing the fluid which leaves the system from the outlet in the opposing side. In the initial stage, the liquid-air interface evolves from a planar front to the fractal structure characteristic of slow drainage processes, giving the initial downward curvature. In the final stage, air spreads all along the filter, and must reach narrower pores, calling for an increase of the pressure difference, reflected by the final upward curvature. Measuring the pressure-saturation (P-S) law in subwindows located at the inlet, outlet and middle of the network, we emphasize that these boundary effects are the fact of a fraction of pores that is likely to be negligible for high scale systems. We analyze the value of the air saturation at the end of the experiment for a series of simulations with different sample geometries : we observe that this saturation converges to a plateau when the distance between the inlet ant outlet increases, and that the value of this plateau is determined by the distance between the lateral walls. We finally show that the pressure difference between the two phases

  8. Influence of phase connectivity on the relationship among capillary pressure, fluid saturation, and interfacial area in two-fluid-phase porous medium systems

    Science.gov (United States)

    McClure, James E.; Berrill, Mark A.; Gray, William G.; Miller, Cass T.

    2016-09-01

    Multiphase flows in porous medium systems are typically modeled at the macroscale by applying the principles of continuum mechanics to develop models that describe the behavior of averaged quantities, such as fluid pressure and saturation. These models require closure relations to produce solvable forms. One of these required closure relations is an expression relating the capillary pressure to fluid saturation and, in some cases, other topological invariants such as interfacial area and the Euler characteristic (or average Gaussian curvature). The forms that are used in traditional models, which typically consider only the relationship between capillary pressure and saturation, are hysteretic. An unresolved question is whether the inclusion of additional morphological and topological measures can lead to a nonhysteretic closure relation. Relying on the lattice Boltzmann (LB) method, we develop an approach to investigate equilibrium states for a two-fluid-phase porous medium system, which includes disconnected nonwetting phase features. A set of simulations are performed within a random close pack of 1964 spheres to produce a total of 42 908 distinct equilibrium configurations. This information is evaluated using generalized additive models to quantitatively assess the degree to which functional relationships can explain the behavior of the equilibrium data. The variance of various model estimates is computed, and we conclude that, except for the limiting behavior close to a single fluid regime, capillary pressure can be expressed as a deterministic and nonhysteretic function of fluid saturation, interfacial area between the fluid phases, and the Euler characteristic. To our knowledge, this work is unique in the methods employed, the size of the data set, the resolution in space and time, the true equilibrium nature of the data, the parametrizations investigated, and the broad set of functions examined. The conclusion of essentially nonhysteretic behavior provides

  9. Capillary pressure-saturation relations for supercritical CO2 and brine in limestone/dolomite sands: implications for geologic carbon sequestration in carbonate reservoirs.

    Science.gov (United States)

    Wang, Shibo; Tokunaga, Tetsu K

    2015-06-16

    In geologic carbon sequestration, capillary pressure (Pc)-saturation (Sw) relations are needed to predict reservoir processes. Capillarity and its hysteresis have been extensively studied in oil-water and gas-water systems, but few measurements have been reported for supercritical (sc) CO2-water. Here, Pc-Sw relations of scCO2 displacing brine (drainage), and brine rewetting (imbibition) were studied to understand CO2 transport and trapping behavior under reservoir conditions. Hysteretic drainage and imbibition Pc-Sw curves were measured in limestone sands at 45 °C under elevated pressures (8.5 and 12.0 MPa) for scCO2-brine, and in limestone and dolomite sands at 23 °C (0.1 MPa) for air-brine using a new computer programmed porous plate apparatus. scCO2-brine drainage and imbibition curves shifted to lower Pc relative to predictions based on interfacial tension, and therefore deviated from capillary scaling predictions for hydrophilic interactions. Fitting universal scaled drainage and imbibition curves show that wettability alteration resulted from scCO2 exposure over the course of months-long experiments. Residual trapping of the nonwetting phases was determined at Pc = 0 during imbibition. Amounts of trapped scCO2 were significantly larger than for those for air, and increased with pressure (depth), initial scCO2 saturation, and time. These results have important implications for scCO2 distribution, trapping, and leakage potential.

  10. Measurement and evaluation of the relationships between capillary pressure, relative permeability, and saturation for surrogate fluids for laboratory study of geological carbon sequestration

    Science.gov (United States)

    Mori, H.; Trevisan, L.; Sakaki, T.; Cihan, A.; Smits, K. M.; Illangasekare, T. H.

    2013-12-01

    Multiphase flow models can be used to improve our understanding of the complex behavior of supercritical CO2 (scCO2) in deep saline aquifers to make predictions for the stable storage strategies. These models rely on constitutive relationships such as capillary pressure (Pc) - saturation (Sw) and relative permeability (kr) - saturation (Sw) as input parameters. However, for practical application of these models, such relationships for scCO2 and brine system are not readily available for geological formations. This is due to the complicated and expensive traditional methods often used to obtain these relationships in the laboratory through high pressure and/or high-temperature controls. A method that has the potential to overcome the difficulty in conducting such experiments is to replicate scCO2 and brine with surrogate fluids that capture the density and viscosity effects to obtain the constitutive relationships under ambient conditions. This study presents an investigation conducted to evaluate this method. An assessment of the method allows us to evaluate the prediction accuracy of multiphase models using the constitutive relationships developed from this approach. With this as a goal, the study reports multiple laboratory column experiments conducted to measure these relationships. The obtained relationships were then used in the multiphase flow simulator TOUGH2 T2VOC to explore capillary trapping mechanisms of scCO2. A comparison of the model simulation to experimental observation was used to assess the accuracy of the measured constitutive relationships. Experimental data confirmed, as expected, that the scaling method cannot be used to obtain the residual and irreducible saturations. The results also showed that the van Genuchten - Mualem model was not able to match the independently measured kr data obtained from column experiments. Simulated results of fluid saturations were compared with saturation measurements obtained using x-ray attenuations. This

  11. Impacts on oil recovery from capillary pressure and capillary heterogeneities

    Energy Technology Data Exchange (ETDEWEB)

    Bognoe, Thomas

    2008-07-01

    The main conclusions drawn from this thesis are; 7 scientific papers are published on a broad variety of subjects, and describes in detail the experiments and research treated in this thesis. Scientific research has been performed, investigating the subjects of capillary pressure and capillary heterogeneities from different angles. This thesis discusses the findings in this study and aims to illustrate the benefits of the results obtained for further development of other experiments, and/or even the industrial benefits in field development. The methods for wettability alteration have developed throughout the work. From producing heterogeneous wettability alterations, the methods have improved to giving both radial and lateral uniform wettability alterations, which also remains unaltered throughout the duration of the experimental work. The alteration of wettability is dependent on initial water saturation, flow rate, aging time and crude oil composition. Capillary pressure and relative permeability curves have been measured for core plugs at different wettabilities using conventional centrifuge methods. The trends observed are mostly consistent with theory. The production mechanisms of strongly and moderately water wet chalk has been investigated. At strongly water wet conditions in fractured chalk; the flow is governed by capillary forces, showing strong impact from the fractures. At moderately water wet conditions, the impact of the fractures are absent, and a dispersed water front is observed during the displacement. The oil recovery is about the same, at the two wettabilities. Fracture crossing mechanisms at the same wettability conditions have been mapped. And the observations are consistent with those of the water floods. During strongly water wet displacement, the fracture crossing is occurring once the inlet core has reached endpoint of spontaneous imbibition. At moderately water wet conditions the fracture crossing is less abrupt, and creation of wetting

  12. A Prediction Model of the Capillary Pressure J-Function

    Science.gov (United States)

    Xu, W. S.; Luo, P. Y.; Sun, L.; Lin, N.

    2016-01-01

    The capillary pressure J-function is a dimensionless measure of the capillary pressure of a fluid in a porous medium. The function was derived based on a capillary bundle model. However, the dependence of the J-function on the saturation Sw is not well understood. A prediction model for it is presented based on capillary pressure model, and the J-function prediction model is a power function instead of an exponential or polynomial function. Relative permeability is calculated with the J-function prediction model, resulting in an easier calculation and results that are more representative. PMID:27603701

  13. Development of a numerical workflow based on μ-CT imaging for the determination of capillary pressure-saturation-specific interfacial area relationship in 2-phase flow pore-scale porous-media systems: a case study on Heletz sandstone

    Science.gov (United States)

    Peche, Aaron; Halisch, Matthias; Bogdan Tatomir, Alexandru; Sauter, Martin

    2016-05-01

    In this case study, we present the implementation of a finite element method (FEM)-based numerical pore-scale model that is able to track and quantify the propagating fluid-fluid interfacial area on highly complex micro-computed tomography (μ-CT)-obtained geometries. Special focus is drawn to the relationship between reservoir-specific capillary pressure (pc), wetting phase saturation (Sw) and interfacial area (awn). The basis of this approach is high-resolution μ-CT images representing the geometrical characteristics of a georeservoir sample. The successfully validated 2-phase flow model is based on the Navier-Stokes equations, including the surface tension force, in order to consider capillary effects for the computation of flow and the phase-field method for the emulation of a sharp fluid-fluid interface. In combination with specialized software packages, a complex high-resolution modelling domain can be obtained. A numerical workflow based on representative elementary volume (REV)-scale pore-size distributions is introduced. This workflow aims at the successive modification of model and model set-up for simulating, such as a type of 2-phase problem on asymmetric μ-CT-based model domains. The geometrical complexity is gradually increased, starting from idealized pore geometries until complex μ-CT-based pore network domains, whereas all domains represent geostatistics of the REV-scale core sample pore-size distribution. Finally, the model can be applied to a complex μ-CT-based model domain and the pc-Sw-awn relationship can be computed.

  14. On the propagation of a coupled saturation and pressure front

    Energy Technology Data Exchange (ETDEWEB)

    Vasco, D. W.

    2010-12-01

    Using an asymptotic technique, valid for a medium with smoothly varying heterogeneity, I derive an expression for the velocity of a propagating, coupled saturation and pressure front. Due to the nonlinearity of the governing equations, the velocity of the propagating front depends upon the magnitude of the saturation and pressure changes across the front in addition to the properties of the medium. Thus, the expression must be evaluated in conjunction with numerical reservoir simulation. The propagation of the two-phase front is governed by the background saturation distribution, the saturation-dependent component of the fluid mobility, the porosity, the permeability, the capillary pressure function, the medium compressibility, and the ratio of the slopes of the relative permeability curves. Numerical simulation of water injection into a porous layer saturated with a nonaqueous phase liquid indicates that two modes of propagation are important. The fastest mode of propagation is a pressure-dominated disturbance that travels through the saturated layer. This is followed, much later, by a coupled mode with a large saturation change. These two modes are also observed in a simulation using a heterogeneous porous layer. A comparison between the propagation times estimated from the results of the numerical simulation and predictions from the asymptotic expression indicates overall agreement.

  15. Macroscopic theory for capillary-pressure hysteresis.

    Science.gov (United States)

    Athukorallage, Bhagya; Aulisa, Eugenio; Iyer, Ram; Zhang, Larry

    2015-03-03

    In this article, we present a theory of macroscopic contact angle hysteresis by considering the minimization of the Helmholtz free energy of a solid-liquid-gas system over a convex set, subject to a constant volume constraint. The liquid and solid surfaces in contact are assumed to adhere weakly to each other, causing the interfacial energy to be set-valued. A simple calculus of variations argument for the minimization of the Helmholtz energy leads to the Young-Laplace equation for the drop surface in contact with the gas and a variational inequality that yields contact angle hysteresis for advancing/receding flow. We also show that the Young-Laplace equation with a Dirichlet boundary condition together with the variational inequality yields a basic hysteresis operator that describes the relationship between capillary pressure and volume. We validate the theory using results from the experiment for a sessile macroscopic drop. Although the capillary effect is a complex phenomenon even for a droplet as various points along the contact line might be pinned, the capillary pressure and volume of the drop are scalar variables that encapsulate the global quasistatic energy information for the entire droplet. Studying the capillary pressure versus volume relationship greatly simplifies the understanding and modeling of the phenomenon just as scalar magnetic hysteresis graphs greatly aided the modeling of devices with magnetic materials.

  16. The Phase Envelope of Multicomponent Mixtures in the Presence of a Capillary Pressure Difference

    DEFF Research Database (Denmark)

    Sandoval Lemus, Diego Rolando; Yan, Wei; Michelsen, Michael Locht;

    2016-01-01

    Confined fluids such as oil and gas mixtures inside tight reservoirs are systems that can experience high capillary pressure difference between the liquid and gas phases. This capillary pressure difference has an effect on the phase equilibrium and in some cases is considerably high. We presented...... the correct direction of the phase envelope shift. Combined with the multicomponent Clapeyron equation, the equations reveal why the shift changes direction for the saturation pressure at the cricondentherm and for the saturation temperature at the cricondenbar. The equations can be used to estimate...

  17. Determining CO2-brine relative permeability and capillary pressure simultaneously: an insight to capillary entrance and end effects

    Science.gov (United States)

    Chen, X.; Kianinejad, A.; DiCarlo, D. A.

    2014-12-01

    CO2-brine relative permeability relations are important parameters in modeling scenarios such as CO2 sequestration in saline aquifers and CO2 enhanced recovery in oil reservoir. Many steady-state experimental studies on CO2-brine relative permeability showed that the CO2-brine relative permeability differs greatly from typical oil-brine relative permeability. Particularly, they reported a very small endpoint CO2 relative permeability of 0.1~0.2 at a relative high residual water saturation of 0.4~0.6. In this study, we hypothesize the measured low endpoint CO2 relative permeability in previous studies was an experimental artifact that is primary due to low CO2 viscosity. We conducted steady-state CO2 drainage experiments by co-injecting equlibrated CO2 and brine into a long (60.8 cm) and low permeability (116-mD) Berea sandstone core at 20 °C and 1500 psi. During every experiment, both the overall pressure drop across the core and the pressure drops of the five independent and continuous sections of the core were monitored. The in-situ saturation was measured with a medical X-ray Computed Tomography (CT) scanner. In the center three sections where saturation was uniform, we determined the relative permeability to both brine and CO2 phases. In the entrance and exit sections, both measured pressure gradients and saturation were non-uniform. To cope with this, we make several self-consistent assumptions that reveal the nature of capillary entrance and effect in steady-state two-phase core flooding experiments. Based on these assumptions we determined the relative permeability to CO2 and CO2-brine capillary pressure simultaneously using measured pressure drops. We found: (1) a much higher endpoint CO2 relative permeability of 0.58 at a water saturation of 48%, (2) the entrance region with non-uniform saturation expanded CO2 relative permeability data to much lower water saturation, (3) the determined CO2-brine capillary pressure curve is self-consistent and matches

  18. The effect of capillary pressure for concave liquid-vapor interface on interfacial evaporation

    Institute of Scientific and Technical Information of China (English)

    张金涛; 王补宣; 彭晓峰

    2001-01-01

    The analysis in this paper demonstrates that the capillary pressure on the concave liquid-vapor interface will promote the interfacial evaporation, therefore clarifying the confusion over the great difference between the estimated and real rate of interfacial evaporation. This difference increases with decreasing capillary radius, and becomes more apparent for liquid with high latent heat. The present analysis also shows that the capillary pressure on the concave interface will result in a decrease in liquid phase equilibrium temperature, which can explain the possibility of vapor bubble formation on micro liquid layer interfacial evaporation under low superheat, or even below the nominal saturated temperature.

  19. Capillary forces in the acoustics of patchy-saturated porous media.

    Science.gov (United States)

    Tserkovnyak, Yaroslav; Johnson, David Linton

    2003-11-01

    A linearized theory of the acoustics of porous elastic formations, such as rocks, saturated with two different viscous fluids is generalized to take into account a pressure discontinuity across the fluid boundaries. The latter can arise due to the surface tension of the membrane separating the fluids. We show that the frequency-dependent bulk modulus K(omega) for wavelengths longer than the characteristic structural dimensions of the fluid patches has a similar analytic behavior to the case of a vanishing membrane stiffness and depends on the same parameters of the fluid-distribution topology. The effect of the capillary stiffness can be accounted for by renormalizing the coefficients of the leading terms in the low-frequency limit of K(omega).

  20. A direct method for determining complete positive and negative capillary pressure curves for reservoir rock using the centrifuge

    Energy Technology Data Exchange (ETDEWEB)

    Spinler, E.A.; Baldwin, B.A. [Phillips Petroleum Co., Bartlesville, OK (United States)

    1997-08-01

    A method is being developed for direct experimental determination of capillary pressure curves from saturation distributions produced during centrifuging fluids in a rock plug. A free water level is positioned along the length of the plugs to enable simultaneous determination of both positive and negative capillary pressures. Octadecane as the oil phase is solidified by temperature reduction while centrifuging to prevent fluid redistribution upon removal from the centrifuge. The water saturation is then measured via magnetic resonance imaging. The saturation profile within the plug and the calculation of pressures for each point of the saturation profile allows for a complete capillary pressure curve to be determined from one experiment. Centrifuging under oil with a free water level into a 100 percent water saturated plug results in the development of a primary drainage capillary pressure curve. Centrifuging similarly at an initial water saturation in the plug results in the development of an imbibition capillary pressure curve. Examples of these measurements are presented for Berea sandstone and chalk rocks.

  1. Direct measurement of the capillary pressure characteristics of water-air-gas diffusion layer systems for PEM fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Gostick, Jeff T.; Ioannidis, Marios A.; Fowler, Michael W.; Pritzker, Mark D. [Department of Chemical Engineering, University of Waterloo, 200 University Avenue West, Waterloo, ON (Canada)

    2008-10-15

    A method and apparatus for measuring the relationship between air-water capillary pressure and water saturation in PEMFC gas diffusion layers (GDL) is described. Capillary pressure data for water injection and withdrawal from typical GDL materials are obtained, which demonstrate permanent hysteresis between water intrusion and water withdrawal. Capillary pressure, defined as the difference between the water and gas pressures at equilibrium, is positive during water injection and negative during water withdrawal. The results contribute to the understanding of liquid water behavior in GDL materials which is necessary for the development of effective PEMFC water management strategies. (author)

  2. A mimetic finite difference method for two-phase flow models with dynamic capillary pressure and hysteresis

    CERN Document Server

    Zhang, Hong

    2016-01-01

    Saturation overshoot and pressure overshoot are studied by incorporating dynamic capillary pressure, capillary pressure hysteresis and hysteretic dynamic coefficient with a traditional fractional flow equation. Using the method of lines, the discretizations are constructed by applying Castillo-Grone's mimetic operators in the space direction and explicit trapezoidal integrator in the time direction. Convergence tests and conservation property of the schemes are presented. Computed profiles capture both the saturation overshoot and pressure overshoot phenomena. Comparisons between numerical results and experiments illustrate the effectiveness and different features of the models.

  3. Pressure drop in saturated flow boiling

    Energy Technology Data Exchange (ETDEWEB)

    Collado, Francisco J. [Universidad de Zaragoza, Zaragoza (Spain)

    2003-07-01

    A new mass balance for flow boiling have been recently suggested by the author following a quite simple idea: if the phases have different velocities, they can not cover the same distance -the control volume length for a 1-d system- in the same time. Thus, the time scales of the phases have to be different, and we should scale the time dependent magnitudes of one phase to the other one before combining them. Furthermore, it is reasonable to think that conservation equations should have to include in some manner this evident physical fact. In complete coherence with the former mass balance, a new energy balance, which does include the slip ratio has been also stated. This work, whilst reviews these new fundamentals for saturated flow boiling, stresses those aspects related with the prediction of the pressure drop in saturated flow boiling. The new correlations found for the data carefully measured by Thom during the Cambridge project would confirm the new two-phase flowapproach.

  4. Three-Phase Capillary Pressure, Hysteresis and Trapping in a Porous Glass-Bead Column

    Science.gov (United States)

    Andersson, L.; Schlüter, S.; Li, T.; Brown, K. I.; Helland, J. O.; Wildenschild, D.

    2015-12-01

    Enhanced oil recovery (EOR) strategies employing water-alternate-gas (WAG) injections may improve oil mobility and production recovery. WAG injections for EOR create regions in the reservoir with simultaneous flow of oil, water and air dominated by capillary and gravity forces. As a result of the dynamics in the transition zones, the invading fluid may snap off compartments of the displaced fluid which could then be trapped in the pore space, contributing to the hysteresis of the three-phase capillary pressure curves. Three-phase capillary pressure curves are needed to model the three-phase transition zone movements in the reservoir. In reservoir simulation models, the common practice has been to implement three-phase capillary pressure curves based on two-phase gas-oil and oil-water capillary pressure data. However, experimental and modelling studies of three-phase fluid distributions at the pore scale have shown that this procedure is not always valid; three-phase capillary pressure curves exhibit hysteresis and depend on the saturation history of the three phases which cannot be derived from two-phase capillary pressure curves. We have developed three-phase experiments that provide capillary pressures and 3D-image data of fluid distributions in the entire saturation space of oil, water and air in water-wet porous glass-bead columns; a time-consuming and technically challenging exercise. The 3D data with a resolution of 6.38 μm were derived from high-resolution synchrotron x-ray computed micro-tomography (CMT), collected at the GSECARS beam line 13-BM-D at the Advanced Photon Source, Argonne National Laboratory. In particular, we discuss how three-phase pore-scale mechanisms, such as oil layer existence and multiple displacement events, affect the mobility and trapping of oil in the porous medium. We also show that wettability-alterations of the porous medium in contact with the three-phase fluid system and exposure to x-rays can be avoided by using iodine

  5. Soil water retention and maximum capillary drive from saturation to oven dryness

    Science.gov (United States)

    Morel-Seytoux, H. J.; Nimmo, J.R.

    1999-01-01

    This paper provides an alternative method to describe the water retention curve over a range of water contents from saturation to oven dryness. It makes two modifications to the standard Brooks and Corey [1964] (B-C) description, one at each end of the suction range. One expression proposed by Rossi and Nimmo [1994] is used in the high-suction range to a zero residual water content. (This Rossi-Nimmo modification to the Brooks-Corey model provides a more realistic description of the retention curve at low water contents.) Near zero suction the second modification eliminates the region where there is a change in suction with no change in water content. Tests on seven soil data sets, using three distinct analytical expressions for the high-, medium-, and low-suction ranges, show that the experimental water retention curves are well fitted by this composite procedure. The high-suction range of saturation contributes little to the maximum capillary drive, defined with a good approximation for a soil water and air system as H(cM) = {???)/(o) k(rw) dh(c), where k(rw) is relative permeability (or conductivity) to water and h(c) is capillary suction, a positive quantity in unsaturated soils. As a result, the modification suggested to describe the high-suction range does not significantly affect the equivalence between Brooks-Corey (B-C) and van Genuchten [1980] parameters presented earlier. However, the shape of the retention curve near 'natural saturation' has a significant impact on the value of the capillary drive. The estimate using the Brooks-Corey power law, extended to zero suction, will exceed that obtained with the new procedure by 25 to 30%. It is not possible to tell which procedure is appropriate. Tests on another data set, for which relative conductivity data are available, support the view of the authors that measurements of a retention curve coupled with a speculative curve of relative permeability as from a capillary model are not sufficient to accurately

  6. Capillary Pressure and Contact Line Force on a Soft Solid

    CERN Document Server

    Marchand, Antonin; Snoeijer, Jacco H; Andreotti, Bruno

    2012-01-01

    The surface free energy, or surface tension, of a liquid interface gives rise to a pressure jump when the interface is curved. Here we show that a similar capillary pressure arises at the interface of soft solids. We present experimental evidence that immersion of a thin elastomeric wire into a liquid induces a substantial elastic compression due to the solid capillary pressure at the bottom. We quantitatively determine the effective surface tension from the elastic displacement field, and find a value comparable to the liquid-vapor surface tension. Most importantly, these results also reveal the way the liquid pulls on the solid close to the contact line: the capillary force is not oriented along the liquid-air interface, nor perpendicularly to the solid surface, as previously hypothesized, but towards the interior of the liquid.

  7. Uniqueness of Specific Interfacial Area–Capillary Pressure–Saturation Relationship Under Non-Equilibrium Conditions in Two-Phase Porous Media Flow

    KAUST Repository

    Joekar-Niasar, Vahid

    2012-02-23

    The capillary pressure-saturation (P c-S w) relationship is one of the central constitutive relationships used in two-phase flow simulations. There are two major concerns regarding this relation. These concerns are partially studied in a hypothetical porous medium using a dynamic pore-network model called DYPOSIT, which has been employed and extended for this study: (a) P c-S w relationship is measured empirically under equilibrium conditions. It is then used in Darcy-based simulations for all dynamic conditions. This is only valid if there is a guarantee that this relationship is unique for a given flow process (drainage or imbibition) independent of dynamic conditions; (b) It is also known that P c-S w relationship is flow process dependent. Depending on drainage and imbibition, different curves can be achieved, which are referred to as "hysteresis". A thermodynamically derived theory (Hassanizadeh and Gray, Water Resour Res 29: 3389-3904, 1993a) suggests that, by introducing a new state variable, called the specific interfacial area (a nw, defined as the ratio of fluid-fluid interfacial area to the total volume of the domain), it is possible to define a unique relation between capillary pressure, saturation, and interfacial area. This study investigates these two aspects of capillary pressure-saturation relationship using a dynamic pore-network model. The simulation results imply that P c-S w relation not only depends on flow process (drainage and imbibition) but also on dynamic conditions for a given flow process. Moreover, this study attempts to obtain the first preliminary insights into the global functionality of capillary pressure-saturation-interfacial area relationship under equilibrium and non-equilibrium conditions and the uniqueness of P c-S w-a nw relationship. © 2012 The Author(s).

  8. Separation of iron-free and iron-saturated forms of transferrin and lactoferrin via capillary electrophoresis performed in fused-silica and neutral capillaries.

    Science.gov (United States)

    Nowak, Paweł; Śpiewak, Klaudyna; Brindell, Małgorzata; Woźniakiewicz, Michał; Stochel, Grażyna; Kościelniak, Paweł

    2013-12-20

    A capillary electrophoresis-based method for the cost-effective and high efficient separation of iron-free and iron-saturated forms of two members of transferrin family: transferrin and lactoferrin has been developed. The proposed qualitative method relying on the SDS application allowed us to separate iron-free and iron-saturated forms of these proteins, as well as human serum albumin, used as an internal standard. Owing to the distinct migration times under established conditions, the combination of transferrin and lactoferrin assays within a single analytical procedure was feasible. The performance of the method using a fused-silica capillary has been compared with the results obtained using the same method but performed with the use of a neutral capillary of the same dimensions. Neutral capillary has been used as an alternative, since the comparable resolution has been achieved with a concomitant reduction of the electroosmotic flow. Despite of this fact, the migration of analytes occurred with similar velocity but in opposite order, due to the reverse polarity application. A quantitative method employing fused-silica capillary for iron saturation study has been also developed, to evaluate the iron saturation in commercial preparations of lactoferrin.

  9. RESEARCH METHODS OF SATURATED VAPOR PRESSURE AND EXPERIMENTAL INSTALLATIONS

    Directory of Open Access Journals (Sweden)

    Kharchenko P. M.

    2015-02-01

    Full Text Available The static method is the most common, because it is applicable for measuring SVP of substances in wide ranges of temperatures and pressures. The essence of the method consists in measuring of vapor pressure in equilibrium with its liquid at a given temperature. Dynamic method is based on measurement of the boiling point of the liquid at a certain pressure. Saturation method of moving gas used in the case when the SVP does not exceed a few mm Hg. The method consists the following: the liquid is passed through the inert gas and saturated with vapor of liquids and then it flows into a cooler where the absorbed vapors are condensed. Knowing the amount of absorbed liquid and gas, as well as their molecular weight, allow us calculate saturated vapor pressure of the liquid. Knudsen effusion method is applicable for the measurement of very low pressures (up to 100 Pa. This method consists in researching of depending between the pressure and volume of saturated steam at a constant temperature. At the point of saturation an isotherm should have a break and turn into a straight line. Chromatographic method is based on complete chromatographic analysis of liquid and calculating the sum of partial pressures of all mixture components. Also, the article has a description of existing experimental installation for these researches and their advantages and disadvantages compared with each other

  10. Uniaxial creep as a control on mercury intrusion capillary pressure in consolidating rock salt

    Energy Technology Data Exchange (ETDEWEB)

    Dewers, Thomas [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Heath, Jason E. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Leigh, Christi D. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

    2015-09-01

    The nature of geologic disposal of nuclear waste in salt formations requires validated and verified two - phase flow models of transport of brine and gas through intact, damaged, and consolidating crushed salt. Such models exist in oth er realms of subsurface engineering for other lithologic classes (oil and gas, carbon sequestration etc. for clastics and carbonates) but have never been experimentally validated and parameterized for salt repository scenarios or performance assessment. Mo dels for waste release scenarios in salt back - fill require phenomenological expressions for capillary pressure and relative permeability that are expected to change with degree of consolidation, and require experimental measurement to parameterize and vali date. This report describes a preliminary assessment of the influence of consolidation (i.e. volume strain or porosity) on capillary entry pressure in two phase systems using mercury injection capillary pressure (MICP). This is to both determine the potent ial usefulness of the mercury intrusion porosimetry method, but also to enable a better experimental design for these tests. Salt consolidation experiments are performed using novel titanium oedometers, or uniaxial compression cells often used in soil mech anics, using sieved run - of - mine salt from the Waste Isolation Pilot Plant (WIPP) as starting material. Twelve tests are performed with various starting amounts of brine pore saturation, with axial stresses up to 6.2 MPa (%7E900 psi) and temperatures to 90 o C. This corresponds to UFD Work Package 15SN08180211 milestone "FY:15 Transport Properties of Run - of - Mine Salt Backfill - Unconsolidated to Consolidated". Samples exposed to uniaxial compression undergo time - dependent consolidation, or creep, to various deg rees. Creep volume strain - time relations obey simple log - time behavior through the range of porosities (%7E50 to 2% as measured); creep strain rate increases with temperature and applied stress as

  11. Measurement of rock-core capillary pressure curves using a single-speed centrifuge and one-dimensional magnetic-resonance imaging.

    Science.gov (United States)

    Chen, Quan; Balcom, Bruce J

    2005-06-01

    Capillary pressure curves are widely used in materials, soil, and environmental sciences, and especially in the petroleum industry. The traditional (Hassler-Brunner) interpretation of centrifugal capillary pressure data is based on several assumptions. These assumptions are known to lead to significant errors in the measurement of capillary pressure curves. In this work, we propose a new "single-shot" method to measure the capillary pressure curve of a long sedimentary rock core using a single-speed centrifuge experiment and magnetic-resonance imaging to directly determine the water saturation distribution along the length of the sample. Since only a single moderate centrifuge speed is employed, the effect of gravity can be ignored and the outlet boundary condition of the core plug was maintained. The capillary pressure curve obtained by the single-shot method is remarkably consistent with results determined with conventional mercury-intrusion methods. The proposed method is much faster and more precise than traditional centrifuge methods.

  12. Prevalence of Sensor Saturation in Wheelchair Seat Interface Pressure Mapping.

    Science.gov (United States)

    Wininger, Michael; Crane, Barbara A

    2015-01-01

    Pressure mapping is a frequently used tool with great power to provide information about the forces between a patient and a wheelchair seat. One widely recognized limitation to this paradigm is the possibility of data loss due to sensor saturation. In this study, we seek to quantify and describe the saturation observed in the measurement of interface pressures of wheelchair users. We recorded approximately two minutes of interface pressure data from 22 elderly wheelchair users (11M/11F, 80 ± 10 years) and found that 4.7% of data frames had 1 saturated sensor, and 9.0% had more than one saturated sensor, for a total of 13.7% of all frames of data. Data from three of the 22 subjects (13.6%) were substantially affected by the persistent presence of saturated sensors. We conclude that for this population of elderly wheelchair users, sensor saturation may be a concern and should be factored properly into study design a priori.

  13. Stress dependent thermal pressurization of a fluid-saturated rock

    CERN Document Server

    Ghabezloo, Siavash

    2008-01-01

    Temperature increase in saturated porous materials under undrained conditions leads to thermal pressurization of the pore fluid due to the discrepancy between the thermal expansion coefficients of the pore fluid and of the solid matrix. This increase in the pore fluid pressure induces a reduction of the effective mean stress and can lead to shear failure or hydraulic fracturing. The equations governing the phenomenon of thermal pressurization are presented and this phenomenon is studied experimentally for a saturated granular rock in an undrained heating test under constant isotropic stress. Careful analysis of the effect of mechanical and thermal deformation of the drainage and pressure measurement system is performed and a correction of the measured pore pressure is introduced. The test results are modelled using a non-linear thermo-poro-elastic constitutive model of the granular rock with emphasis on the stress-dependent character of the rock compressibility. The effects of stress and temperature on therma...

  14. Gas-bubble snap-off under pressure driven flow in constricted noncircular capillaries

    Energy Technology Data Exchange (ETDEWEB)

    Kovscek, A.R.; Radke, C.J.

    1996-04-01

    A model for snap-off of a gas thread in a constricted cornered pore is developed. The time for wetting liquid to accumulate at a pore throat into an unstable collar is examined, as for the resulting pore-spanning lens to be displaced from the pore so that snap-off is the time may repeat. A comer-flow hydrodynamic analysis for the accumulation rate of wetting liquid due to both gradients in interfacial curvature and in applied liquid-phase pressure reveals that wetting-phase pressure gradients significantly increase the frequency of liquid accumulation for snap-off as compared to liquid rearrangement driven only by differences in pore-wall curvature. For moderate and large pressure gradients, the frequency of accumulation increases linearly with pressure gradient because of the increased rate of wetting liquid flow along pore comers. Pore topology is important to the theory, for pores with relatively small throats connected to large bodies demonstrate excellent ability to snapoff gas threads even when the initial capillary pressure is high or equivalently when the liquid saturation is low. A macroscopic momentum balance across the lens resulting from snap-off reveals that lens displacement rates are not linear with the imposed pressure drop. Instead, the frequency of lens displacement scales with powers between 0.5 and 0.6 for pores with dimensionless constriction radii between 0.15 and 0.40. Statistical percolation arguments are employed to form a generation rate expression and connect pore-level foam generation events to macroscopic pressure gradients in porous media. The rate of foam generation by capillary snap-off increases linearly with the liquid-phase pressure gradient and according to a power-law relationship with respect to the imposed gas-phase pressure gradient.

  15. Improved Magnus` form approximation of saturation vapor pressure

    Energy Technology Data Exchange (ETDEWEB)

    Alduchov, O.A.; Eskridge, R.E. [National Oceanic and Atmospheric Administration, Asheville, NC (United States). National Climatic Data Center

    1997-11-01

    Relative humidity is usually measured in aerological observations and dew point depression is usually reported in upper-air reports. These variables must frequently be converted to other moisture variables in meteorological analysis. If relative humidity is converted to vapor pressure, most humidity variables can then be determined. Elliott and Gaffen reviewed the practices and procedures of the US radiosonde system. In their paper, a comparison of the relative errors was made between the saturation vapor pressure formulations of Tetens (1930), Goff-Gratch (1946), Wexler (1976), and Buck (1981). In this paper, the authors will expand the analysis of Elliott and Gaffen by deriving several new saturation vapor pressure formulas, and reviewing the various errors in these formulations. They will show that two of the new formulations of vapor pressure over water and ice are superior to existing formulas. Upper air temperature data are found to vary from about +50 C to {minus}80 C. This large variation requires a saturation vapor pressure equation to be accurate over a large temperature range. While the errors introduced by the use of relatively inaccurate conversion equations are smaller than the errors due to the instruments, dewpoint coding errors, and dewpoint conversion algorithms (Elliott and Gaffen, 1993); they introduce additional systematic errors in humidity data. The most precise formulation of vapor pressure over a plane surface of water was given by Wexler (1976). The relative errors of Tetens` (1930) formula and one due to Buck (1981) (Buck`s equation is recommended in the Federal Meteorological Handbook No. 3, 1991) are shown. The relative errors in this table are the predicted value minus the Wexler value divided by the Wexler value.

  16. Pore-scale modeling of vapor transport in partially saturated capillary tube with variable area using chemical potential

    DEFF Research Database (Denmark)

    Addassi, Mouadh; Schreyer, Lynn; Johannesson, Björn

    2016-01-01

    Here we illustrate the usefulness of using the chemical potential as the primary unknown by modeling isothermal vapor transport through a partially saturated cylindrically symmetric capillary tube of variable cross-sectional area using a single equation. There are no fitting parameters...... of the Fick-Jacobs equation. We thus conclude that for a single, axisymmetric pore, the enhancement factor depends upon relative humidity boundary conditions at the liquid bridge interfaces, distance between liquid bridges, and bridge lengths....

  17. Relating oxygen partial pressure, saturation and content: the haemoglobin–oxygen dissociation curve

    Directory of Open Access Journals (Sweden)

    Julie-Ann Collins

    2015-09-01

    The delivery of oxygen by arterial blood to the tissues of the body has a number of critical determinants including blood oxygen concentration (content, saturation (SO2 and partial pressure, haemoglobin concentration and cardiac output, including its distribution. The haemoglobin–oxygen dissociation curve, a graphical representation of the relationship between oxygen satur­ation and oxygen partial pressure helps us to understand some of the principles underpinning this process. Historically this curve was derived from very limited data based on blood samples from small numbers of healthy subjects which were manipulated in vitro and ultimately determined by equations such as those described by Severinghaus in 1979. In a study of 3524 clinical specimens, we found that this equation estimated the SO2 in blood from patients with normal pH and SO2 >70% with remarkable accuracy and, to our knowledge, this is the first large-scale validation of this equation using clinical samples. Oxygen saturation by pulse oximetry (SpO2 is nowadays the standard clinical method for assessing arterial oxygen saturation, providing a convenient, pain-free means of continuously assessing oxygenation, provided the interpreting clinician is aware of important limitations. The use of pulse oximetry reduces the need for arterial blood gas analysis (SaO2 as many patients who are not at risk of hypercapnic respiratory failure or metabolic acidosis and have acceptable SpO2 do not necessarily require blood gas analysis. While arterial sampling remains the gold-standard method of assessing ventilation and oxygenation, in those patients in whom blood gas analysis is indicated, arterialised capillary samples also have a valuable role in patient care. The clinical role of venous blood gases however remains less well defined.

  18. Diagnostics of atmospheric pressure capillary DBD oxygen plasma jet

    CERN Document Server

    Roy, N C; Pramanik, B K

    2015-01-01

    Atmospheric pressure capillary dielectric barrier oxygen discharge plasma jet is developed to generate non-thermal plasma using unipolar positive pulse power supply. Both optical and electrical techniques are used to investigate the characteristics of the produced plasma as function of applied voltage and gas flow rate. Analytical results obtained from the optical emission spectroscopic data reveal the gas temperature, rotational temperature, excitation temperature and electron density. Gas temperature and rotational temperature are found to decrease with increasing oxygen flow rate but increase linearly with applied voltage. It is exposed that the electron density is boosting up with enhanced applied voltage and oxygen flow rate, while the electron excitation temperature is reducing with rising oxygen flow rate. Electrical characterization demonstrates that the discharge frequency is falling with flow rate but increasing with voltage. The produced plasma is applied preliminarily to study the inactivation yie...

  19. Atmospheric sugar alcohols: evaporation rates and saturation vapor pressures

    Science.gov (United States)

    Bilde, M.; Zardini, A. A.; Hong, J.; Tschiskale, M.; Emanuelsson, E.

    2014-12-01

    The atmospheric partitioning between gas and condensed phase of organic molecules is poorly understood, and discrepancies exist between predicted and observed concentrations of secondary organic aerosols. A key problem is the lack of information about thermodynamic properties of semi- and low volatile organic molecules. Saturation vapor pressure and the associated temperature dependence (dH) are key parameters for improving predictive atmospheric models. In this work we combine experiments and thermodynamic modeling to investigate these parameters for a series of polyols, so-called sugar alcohols. These polyols are common in the water soluble fraction of atmospheric aerosols. In our experimental system sub-micron particles are generated by nebulization from aqueous solution, and a mono disperse fraction of the aerosol is selected using a differential mobility analyzer. The particles are allowed to evaporate in a laminar flow reactor, and changes in particle size as function of evaporation time are determined using a scanning mobility particle sizer system. In this work saturation vapor pressures of sugar alcohols at several temperatures have been inferred from such measurements using thermodynamic modeling. Results are presented and discussed in context of atmospheric gas to particle partitioning.

  20. Tilting oil-water contact in the chalk of Tyra Field as interpreted from capillary pressure data

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Rana, M.A.

    2010-01-01

    -trends from logs were compared with normalized water saturation depth-trends predicted from capillary pressure core data. The ten wells lie close to a SW–NE cross section of the field. For the gas–oil contact, a free contact measured in one well corresponds to a practically horizontal contact interpreted from......The Tyra Field in the central North Sea is located in Palaeogene and Upper Cretaceous chalk. It contains a natural gas zone underlain by an oil leg. Based on analysis of logs and core data from ten wells drilled prior to the field being put into production, normalized water saturation depth...... logging data in the remaining wells. A westerly dipping oil–water contact was found from logging data. Comparison of the depth-wise trends in normalized water saturation among the different wells indicates a regional pattern: in the western side of the field, the trends correspond to a situation...

  1. Investigation of pressure drop in capillary tube for mixed refrigerant Joule-Thomson cryocooler

    Energy Technology Data Exchange (ETDEWEB)

    Ardhapurkar, P. M. [Mechanical Engineering Department, Indian Institute of Technology Bombay, Mumbai, MS 400 076 India and S. S. G. M. College of Engineering Shegaon, MS 444 203 (India); Sridharan, Arunkumar; Atrey, M. D. [Mechanical Engineering Department, Indian Institute of Technology Bombay, Mumbai, MS 400 076 (India)

    2014-01-29

    A capillary tube is commonly used in small capacity refrigeration and air-conditioning systems. It is also a preferred expansion device in mixed refrigerant Joule-Thomson (MR J-T) cryocoolers, since it is inexpensive and simple in configuration. However, the flow inside a capillary tube is complex, since flashing process that occurs in case of refrigeration and air-conditioning systems is metastable. A mixture of refrigerants such as nitrogen, methane, ethane, propane and iso-butane expands below its inversion temperature in the capillary tube of MR J-T cryocooler and reaches cryogenic temperature. The mass flow rate of refrigerant mixture circulating through capillary tube depends on the pressure difference across it. There are many empirical correlations which predict pressure drop across the capillary tube. However, they have not been tested for refrigerant mixtures and for operating conditions of the cryocooler. The present paper assesses the existing empirical correlations for predicting overall pressure drop across the capillary tube for the MR J-T cryocooler. The empirical correlations refer to homogeneous as well as separated flow models. Experiments are carried out to measure the overall pressure drop across the capillary tube for the cooler. Three different compositions of refrigerant mixture are used to study the pressure drop variations. The predicted overall pressure drop across the capillary tube is compared with the experimentally obtained value. The predictions obtained using homogeneous model show better match with the experimental results compared to separated flow models.

  2. Atmospheric sugar alcohols: evaporation rates and saturation vapor pressures

    DEFF Research Database (Denmark)

    Bilde, Merete; Zardini, Alessandro Alessio; Hong, Juan

    volatile organic molecules. Saturation vapor pressure and the associated temperature dependence (dH) are key parameters for improving predictive atmospheric models. In this work we combine experiments and thermodynamic modeling to investigate these parameters for a series of polyols, so-called sugar......The atmospheric partitioning between gas and condensed phase of organic molecules is poorly understood, and discrepancies exist between predicted and observed concentrations of secondary organic aerosols. A key problem is the lack of information about thermodynamic properties of semi- and low...... alcohols. These polyols are common in the water soluble fraction of atmospheric aerosols. In our experimental system sub-micron particles are generated by nebulization from aqueous solution, and a mono disperse fraction of the aerosol is selected using a differential mobility analyzer. The particles...

  3. Predicted Disappearance of Saturation Hysteresis in Coarse Granular Media Based on Capillary and Gravity Scaling, and Experimental Tests

    Science.gov (United States)

    Tokunaga, T. K.; Olson, K. R.; Wan, J.

    2002-12-01

    Since the classic work of W. B. Haines (1930), hysteresis in the relation between matric (capillary) potential versus water content has been recognized as a basic aspect of interactions between water and variably saturated porous media. This lack of unique correspondence between potential and saturation has well-recognized consequences for equilibrium, flow, and transport. Although hysteresis in moisture characteristic relations has several causes, the existence of different pore-sizes within porous media (the "ink bottle" effect) is primary. This capillarity-dependent phenomenon has a grain-size limit imposed by the influence of gravity, and more generally by the relations between surface and body forces, and length scales. Above this limit, capillary hysteresis vanishes. The grain-size associated with vanishing of capillary hysteresis was predicted in two ways; first with a simple pore-size model, and second by Miller-Miller scaling. Both methods predict that hysteresis vanishes when characteristic grain-sizes exceed about 8 mm, when the water-air surface tension is 72 mN/m, and when the body force is due to ordinary gravity. More generally, capillary hysteresis is predicted to disappear when the Haines Number (dependent on grain-size, surface tension, the body force, density difference between immiscible fluids) exceeds 8. The predicted critical grain-size was experimentally supported through measurements of drainage and wetting curves of sands and gravels, with grain-sizes ranging from 0.2 up to 11 mm. We also consider effects of interfacial tension variation (surfactants), variation of the body force (centrifugal field), and capillarity associated with grain-surface roughness.

  4. Low internal pressure in femtoliter water capillary bridges reduces evaporation rates.

    Science.gov (United States)

    Cho, Kun; Hwang, In Gyu; Kim, Yeseul; Lim, Su Jin; Lim, Jun; Kim, Joon Heon; Gim, Bopil; Weon, Byung Mook

    2016-03-01

    Capillary bridges are usually formed by a small liquid volume in a confined space between two solid surfaces. They can have a lower internal pressure than the surrounding pressure for volumes of the order of femtoliters. Femtoliter capillary bridges with relatively rapid evaporation rates are difficult to explore experimentally. To understand in detail the evaporation of femtoliter capillary bridges, we present a feasible experimental method to directly visualize how water bridges evaporate between a microsphere and a flat substrate in still air using transmission X-ray microscopy. Precise measurements of evaporation rates for water bridges show that lower water pressure than surrounding pressure can significantly decrease evaporation through the suppression of vapor diffusion. This finding provides insight into the evaporation of ultrasmall capillary bridges.

  5. Facilitating protein crystal cryoprotection in thick-walled plastic capillaries by high-pressure cryocooling.

    Science.gov (United States)

    Chen, Yi-Fan; Tate, Mark W; Gruner, Sol M

    2009-06-01

    Many steps in the X-ray crystallographic solution of protein structures have been automated. However, the harvesting and cryocooling of crystals still rely primarily on manual handling, frequently with consequent mechanical damage. An attractive alternative is to grow crystals directly inside robust plastic capillaries that may be cryocooled and mounted on the beamline goniometer. In this case, it is still desirable to devise a way to cryoprotect the crystals, which is difficult owing to the poor thermal conductivity of thick plastic capillary walls and the large thermal mass of the capillary and internal mother liquor. A method is described to circumvent these difficulties. It is shown that high-pressure cryocooling substantially reduced the minimal concentrations of cryoprotectants required to cryocool water inside capillaries without formation of ice crystals. The minimal concentrations of PEG 200, PEG 400 and glycerol necessary for complete vitrification under pressure cryocooling were determined.

  6. Prediction of Three-Phase Capillary Pressure using a Network Model Anchored to Two-Phase Data

    OpenAIRE

    Dale, Elisabeth Iren; Dijke, Marinus I. J. van; Skauge, Arne

    2008-01-01

    Three-phase capillary pressure is difficult to measure experimentally and therefore has to be estimated by other methods. In this work a network model was applied to generate a consistent set of two-phase and three-phase capillary pressure curves. Experimental data for two-phase, gas-oil and oil-water, capillary pressure from a North Sea reservoir was used in this study. The network model was anchored to the measured two-phase data, and three-phase capillary pressure was constr...

  7. Capillary pressure and liquid wicking in three-dimensional nonwoven materials

    Science.gov (United States)

    Mao, N.; Russell, S. J.

    2008-08-01

    The capillary pressure and liquid wicking in fibrous nonwoven materials depend on the structural arrangement of fibers in three dimensions, which is influenced by the method and conditions used to manufacture the material. By adapting the hydraulic radius mechanism and drag force theory, a model is established for predicting the directional capillary pressure in three-dimensional nonwoven materials. As a case study, equations to predict the velocity of liquid wicking in a one-dimensional wicking strip test for nonwovens having a three-dimensional fiber orientation distribution are given based on the newly established capillary pressure model. These models and equations are based on measurable structural parameters including the fiber orientation distribution, fiber diameter, and fabric porosity.

  8. A Comprehensive Review on Measurement and Correlation Development of Capillary Pressure for Two-Phase Modeling of Proton Exchange Membrane Fuel Cells

    Directory of Open Access Journals (Sweden)

    Chao Si

    2015-01-01

    Full Text Available Water transport and the corresponding water management strategy in proton exchange membrane (PEM fuel cells are quite critical for the improvement of the cell performance. Accuracy modeling of water transport in porous electrodes strongly depends on the appropriate constitutive relationship for capillary pressure which is referred to as pc-s correlation, where pc is the capillary pressure and s is the fraction of saturation in the pores. In the present PEM fuel cell two-phase models, the Leverett-Udell pc-s correlation is widely utilized which is proposed based on fitting the experimental data for packed sands. However, the size and structure of pores for the commercial porous electrodes used in PEM fuel cells differ from those for the packed sands significantly. As a result, the Leverett-Udell correlation should be improper to characterize the two-phase transport in the porous electrodes. In the recent decade, many efforts were devoted to measuring the capillary pressure data and developing new pc-s correlations. The objective of this review is to review the most significant developments in recent years concerning the capillary pressure measurements and the developed pc-s correlations. It is expected that this review will be beneficial to develop the improved PEM fuel cell two-phase model.

  9. Simultaneous analysis of saturated and unsaturated fatty acids present in pequi fruits by capillary electrophoresis

    Directory of Open Access Journals (Sweden)

    Patrícia M. de Castro Barra

    2013-01-01

    Full Text Available In the current study, an alternative method has been proposed for simultaneous analysis of palmitic, stearic, oleic, linoleic, and linolenic acids by capillary zone electrophoresis (CZE using indirect detection. The background electrolyte (BGE used for the analysis of these fatty acids (FAs consisted of 15.0 mmol L−1 NaH2PO4/Na2HPO4 at pH 6.86, 4.0 mmol L−1 SDBS, 8.3 mmol L−1 Brij 35, 45% v/v acetonitrile (can, and 2.1% n-octanol. The FAs quantification of FAs was performed using a response factor approach, which provided a high analytical throughput for the real sample. The CZE method, which was applied successfully for the analysis of pequi pulp, has advantages such as short analysis time, absence of lipid fraction extraction and derivatization steps, and no significant difference in the 95% confidence intervals for FA quantification results, compared to the gas chromatography official method (AOCS Ce 1h-05.

  10. Seismic attenuation in partially saturated Berea sandstone submitted to a range of confining pressures

    Science.gov (United States)

    Chapman, Samuel; Tisato, Nicola; Quintal, Beatriz; Holliger, Klaus

    2016-03-01

    Using the forced oscillation method, we measure the extensional-mode attenuation and Young's modulus of a Berea sandstone sample at seismic frequencies (0.5-50 Hz) for varying levels of water saturation (~0-100%) and confining pressures (2-25 MPa). Attenuation is negligible for dry conditions and saturation levels <80%. For saturation levels between ~91% and ~100%, attenuation is significant and frequency dependent in the form of distinct bell-shaped curves having their maxima between 1 and 20 Hz. Increasing saturation causes an increase of the overall attenuation magnitude and a shift of its peak to lower frequencies. On the other hand, increasing the confining pressure causes a reduction in the attenuation magnitude and a shift of its peak to higher frequencies. For saturation levels above ~98%, the fluid pressure increases with increasing confining pressure. When the fluid pressure is high enough to ensure full water saturation of the sample, attenuation becomes negligible. A second series of comparable experiments reproduces these results satisfactorily. Based on a qualitative analysis of the data, the frequency-dependent attenuation meets the theoretical predictions of mesoscopic wave-induced fluid flow (WIFF) in response to a heterogeneous water distribution in the pore space, so-called patchy saturation. These results show that mesoscopic WIFF can be an important source of seismic attenuation at reservoir conditions.

  11. Measurements of Rotational Temperatures in Atmospheric-Pressure Capillary Plasma Electrode (CPE) Discharge

    Science.gov (United States)

    Figus, Margaret; Abramzon, Nina; Becker, Kurt

    2003-10-01

    We report the results of rotational temperature measurements in atmospheric-pressure capillary plasma electrode (CPE) discharges in ambient air using the unresolved N2 second positive band. Assuming that the emitting N2 molecules can be described by a Maxwell-Boltzmann distribution characterized by a single rotational temperature, this temperature is determined from a fit of the measured emission spectrum to a calculated spectrum. If the emitting species are in equilibrium with the bulk gas in the plasma, then this temperature can be interpreted as the gas kinetic temperature in the plasma. We determined rotational temperatures for three different plasma regions: inside the capillary by analyzing radiation emitted along the axis of the capillary, between the capillaries, and perpendicular to the axis of the capillary. Each region has a different plasma density and, therefore, a different gas temperature with the plasma inside the capillary being the hottest. We also measured the rotational temperatures in each region as a function of the plasma power. As expected, the rotational temperatures increase with increasing discharge power. Work supported by the NSF and by ARO through a DURIP award.

  12. Simultaneous measurement of hysteresis in capillary pressure and electric permittivity for multiphase flow through porous media

    NARCIS (Netherlands)

    Plug, W.J.; Slob, E.C.; Bruining, J.; Moreno Tirado, L.M.

    2007-01-01

    We present a tool that simultaneously measures the complex permittivity and the capillary pressure characteristics for multiphase flow. The sample holder is a parallel plate capacitor. A precision component analyzer is used to measure the impedance amplitude and phase angle as a function of frequenc

  13. Simulation of coupled flow and mechanical deformation using IMplicit Pressure-Displacement Explicit Saturation (IMPDES) scheme

    KAUST Repository

    El-Amin, Mohamed

    2012-01-01

    The problem of coupled structural deformation with two-phase flow in porous media is solved numerically using cellcentered finite difference (CCFD) method. In order to solve the system of governed partial differential equations, the implicit pressure explicit saturation (IMPES) scheme that governs flow equations is combined with the the implicit displacement scheme. The combined scheme may be called IMplicit Pressure-Displacement Explicit Saturation (IMPDES). The pressure distribution for each cell along the entire domain is given by the implicit difference equation. Also, the deformation equations are discretized implicitly. Using the obtained pressure, velocity is evaluated explicitly, while, using the upwind scheme, the saturation is obtained explicitly. Moreover, the stability analysis of the present scheme has been introduced and the stability condition is determined.

  14. The Interface Conditions for Pressures at Oil-water Flood Front in the Porous Media Considering Capillary Pressure

    CERN Document Server

    Peng, Xiaolong; Du, Zhimin

    2016-01-01

    Flood front is the jump interface where fluids distribute discontinuously, whose interface condition is the theoretical basis of a mathematical model of the multiphase flow in porous medium. The conventional interface condition at the jump interface is expressed as the continuous Darcy velocity and fluid pressure (named CPVCM). This paper has inspected it via the studying the water-oil displacement in one dimensional reservoir with considering capillary pressure but ignoring the compressibility and gravity. It is proved theoretically that the total Darcy velocity and total pressure (defined by Antoncev etc.), instead of the Darcy velocities and pressures of water and oil, are continuous at the flood front without considering the compressibility of fluid and porous media. After that, new interface conditions for the pressures and Darcy velocity of each fluid are established, which are collectively named as Jump Pressures and Velocities Conditions Model (JPVCM) because the model has shown the jump pressures and...

  15. Capillary viscometer with a pressure sensor: a subject for student projects

    Science.gov (United States)

    Massalha, Taha; Digilov, Rafael M.

    2015-11-01

    We describe a vacuum-based pressure-detecting capillary viscometer for the viscosity determination of Newtonian fluids without known density. The viscometer operates on the principle that the variation in air pressure of the vacuum vessel p≤ft(t\\right) replaces the flow rate and pressure drop measurements which are usually required for the operation of a capillary tube viscometer. The mathematical expression for p≤ft(t\\right), found in the terms of the Lambert-W function, is used to fit the experimental data for viscosity determination. The results for viscosities of distilled water and 50 wt.% glycerol aqueous solution obtained under ambient temperature condition were compared to reference data and a good agreement was observed. The viscometer is suitable for undergraduate laboratories due to its low cost and simplicity in experimental setup. Moreover, the experimental with the vacuum vessel setup provides an in-depth understanding of fluid flow.

  16. Determination of saturation functions and wettability for chalk based on measured fluid saturations

    Energy Technology Data Exchange (ETDEWEB)

    Olsen, D.; Bech, N.; Moeller Nielsen, C.

    1998-08-01

    The end effect of displacement experiments on low permeable porous media is used for determination of relative permeability functions and capillary pressure functions. Saturation functions for a drainage process are determined from a primary drainage experiment. A reversal of the flooding direction creates an intrinsic imbibition process in the sample, which enables determination if imbibition saturation functions. The saturation functions are determined by a parameter estimation technique. Scanning effects are modelled by the method of Killough. Saturation profiles are determined by NMR. (au)

  17. Poor agreement between pulmonary capillary wedge pressure and left ventricular end-diastolic pressure in a veteran population.

    Directory of Open Access Journals (Sweden)

    Abbas Bitar

    Full Text Available BACKGROUND: Accurate determination of left ventricular filling pressure is essential for differentiation of pre-capillary pulmonary hypertension (PH from pulmonary venous hypertension (PVH. Previous data suggest only a poor correlation between left ventricular end-diastolic pressure (LVEDP and its commonly used surrogate, the pulmonary capillary wedge pressure (PCWP. However, no data exist on the diagnostic accuracy of PCWP in veterans. Furthermore, the effects of age and comorbidities on the PCWP-LVEDP relationship remain unknown. METHODS: We investigated the PCWP-LVEDP relationship in 101 patients undergoing simultaneous right and left heart catherization at a large VA hospital. PCWP performance was evaluated using correlation and Bland-Altman analyses. Area under Receiver Operating Characteristics curves (AUROC for PCWP were determined. RESULTS: PCWP-LVEDP correlation was moderate (r = 0.57. PCWP-LVEDP calibration was poor (Bland-Altman limits of agreement -17.2 to 11.4 mmHg; mean bias -2.87 mmHg. 59 patients (58.4% had pulmonary hypertension; 15 (25.4% of those met pre-capillary PH criteria based on PCWP. However, if LVEDP was used instead of PCWP, 7/15 patients (46.6% met criteria for PVH rather than pre-capillary PH. When restricting analysis to patients with a mean pulmonary artery pressure of ≥25 mmHg and pulmonary vascular resistance of >3 Wood units (n = 22, 10 patients (45.4% were classified as pre-capillary PH based on PCWP ≤15 mmHg. However, if LVEDP was used, 4/10 patients (40% were reclassified as PVH. Among patients with any type of pulmonary hypertension, PCWP discriminated moderately between high and normal LVEDP (AUROC, 0.81; 95%CI 0.69-0.94. PCWP-LVEDP correlation was particularly poor in patients with COPD or obesity. CONCLUSION: Reliance on PCWP rather than LVEDP results in misclassification of veterans as having pre-capillary PH rather than PVH in almost 50% of cases. This is clinically relevant, as

  18. Determination of Minimum Miscibility Pressure in supercritical extractor using oil saturated sample

    DEFF Research Database (Denmark)

    Rudyk, Svetlana Nikolayevna; Søgaard, Erik Gydesen; Abbasi, Waqas A.

    2009-01-01

    , in order to investigate the MMP, we suggest another method by using a supercritical extractor. Spe-ed SFE equipment with oil saturated natural rock samples were used for the purpose. The clean chalk samples were saturated with oil from the Dan field under vacuum. The CO2 gas was injected into the extractor...... vessel containing the sample at different increasing pressure levels. The oil displaced in such a way was collected and measured. The volume of extracted oil was plotted against the increasing pressure. The form of the graph is similar to that typically obtained from a slim tube experiment.  Following...

  19. Analysis of Critical Permeabilty, Capillary Pressure and Electrical Properties for Mesaverde Tight Gas Sandstones from Western U.S. Basins

    Energy Technology Data Exchange (ETDEWEB)

    Alan Byrnes; Robert Cluff; John Webb; John Victorine; Ken Stalder; Daniel Osburn; Andrew Knoderer; Owen Metheny; Troy Hommertzheim; Joshua Byrnes; Daniel Krygowski; Stefani Whittaker

    2008-06-30

    Although prediction of future natural gas supply is complicated by uncertainty in such variables as demand, liquefied natural gas supply price and availability, coalbed methane and gas shale development rate, and pipeline availability, all U.S. Energy Information Administration gas supply estimates to date have predicted that Unconventional gas sources will be the dominant source of U.S. natural gas supply for at least the next two decades (Fig. 1.1; the period of estimation). Among the Unconventional gas supply sources, Tight Gas Sandstones (TGS) will represent 50-70% of the Unconventional gas supply in this time period (Fig. 1.2). Rocky Mountain TGS are estimated to be approximately 70% of the total TGS resource base (USEIA, 2005) and the Mesaverde Group (Mesaverde) sandstones represent the principal gas productive sandstone unit in the largest Western U.S. TGS basins including the basins that are the focus of this study (Washakie, Uinta, Piceance, northern Greater Green River, Wind River, Powder River). Industry assessment of the regional gas resource, projection of future gas supply, and exploration programs require an understanding of reservoir properties and accurate tools for formation evaluation. The goal of this study is to provide petrophysical formation evaluation tools related to relative permeability, capillary pressure, electrical properties and algorithms for wireline log analysis. Detailed and accurate moveable gas-in-place resource assessment is most critical in marginal gas plays and there is need for quantitative tools for definition of limits on gas producibility due to technology and rock physics and for defining water saturation. The results of this study address fundamental questions concerning: (1) gas storage; (2) gas flow; (3) capillary pressure; (4) electrical properties; (5) facies and upscaling issues; (6) wireline log interpretation algorithms; and (7) providing a web-accessible database of advanced rock properties. The following text

  20. A comparison of pulmonary arterial occlusion algorithms for estimation of pulmonary capillary pressure.

    Science.gov (United States)

    Pellett, A A; Johnson, R W; Morrison, G G; Champagne, M S; deBoisblanc, B P; Levitzky, M G

    1999-07-01

    Using the arterial occlusion method, we compared five literature-based estimates of pulmonary capillary pressure (Ppc) with the corresponding double occlusion pressures (Pdo) in anesthetized dogs whose chests had been closed after sternotomy for instrumentation. Arterial occlusions were performed with a balloon-tipped pulmonary artery catheter that housed pressure transducers immediately proximal and distal to the balloon. Separation of the proximal and distal pressure waveforms during balloon inflation allowed us to precisely define the moment of occlusion. We fit a monoexponential curve to pressure data beginning 200 ms after the onset of occlusion and a biexponential curve to data beginning at the instant of occlusion, with data obtained over a range of vascular states (control, serotonin infusion, histamine infusion). In addition, we investigated the use of sampling of the raw data to estimate capillary pressure. Three of the five literature-based estimates of Ppc yielded values similar to Pdo. The optimal (least average difference from Pdo) interpolation/extrapolation time points of the curve fits varied, depending on the type of curve fitting and the state of the pulmonary vasculature. We also determined that a close approximation of Pdo may be derived from the raw data, as an alternative to exponential curve fitting.

  1. Arterial blood oxygen saturation during blood pressure cuff-induced hypoperfusion

    Science.gov (United States)

    Kyriacou, P. A.; Shafqat, K.; Pal, S. K.

    2007-10-01

    Pulse oximetry has been one of the most significant technological advances in clinical monitoring in the last two decades. Pulse oximetry is a non-invasive photometric technique that provides information about the arterial blood oxygen saturation (SpO2) and heart rate, and has widespread clinical applications. When peripheral perfusion is poor, as in states of hypovolaemia, hypothermia and vasoconstriction, oxygenation readings become unreliable or cease. The problem arises because conventional pulse oximetry sensors must be attached to the most peripheral parts of the body, such as finger, ear or toe, where pulsatile flow is most easily compromised. Pulse oximeters estimate arterial oxygen saturation by shining light at two different wavelengths, red and infrared, through vascular tissue. In this method the ac pulsatile photoplethysmographic (PPG) signal associated with cardiac contraction is assumed to be attributable solely to the arterial blood component. The amplitudes of the red and infrared ac PPG signals are sensitive to changes in arterial oxygen saturation because of differences in the light absorption of oxygenated and deoxygenated haemoglobin at these two wavelengths. From the ratios of these amplitudes, and the corresponding dc photoplethysmographic components, arterial blood oxygen saturation (SpO2) is estimated. Hence, the technique of pulse oximetry relies on the presence of adequate peripheral arterial pulsations, which are detected as photoplethysmographic (PPG) signals. The aim of this study was to investigate the effect of pressure cuff-induced hypoperfusion on photoplethysmographic signals and arterial blood oxygen saturation using a custom made finger blood oxygen saturation PPG/SpO2 sensor and a commercial finger pulse oximeter. Blood oxygen saturation values from the custom oxygen saturation sensor and a commercial finger oxygen saturation sensor were recorded from 14 healthy volunteers at various induced brachial pressures. Both pulse

  2. Arterial blood oxygen saturation during blood pressure cuff-induced hypoperfusion

    Energy Technology Data Exchange (ETDEWEB)

    Kyriacou, P A [School of Engineering and Mathematical Sciences, City University, London EC1V 0HB (United Kingdom); Shafqat, K [School of Engineering and Mathematical Sciences, City University, London EC1V 0HB (United Kingdom); Pal, S K [St Andrew' s Centre for Plastic Surgery and Burns, Broomfield Hospital, Chelmsford, CM1 7ET (United Kingdom)

    2007-10-15

    Pulse oximetry has been one of the most significant technological advances in clinical monitoring in the last two decades. Pulse oximetry is a non-invasive photometric technique that provides information about the arterial blood oxygen saturation (SpO{sub 2}) and heart rate, and has widespread clinical applications. When peripheral perfusion is poor, as in states of hypovolaemia, hypothermia and vasoconstriction, oxygenation readings become unreliable or cease. The problem arises because conventional pulse oximetry sensors must be attached to the most peripheral parts of the body, such as finger, ear or toe, where pulsatile flow is most easily compromised. Pulse oximeters estimate arterial oxygen saturation by shining light at two different wavelengths, red and infrared, through vascular tissue. In this method the ac pulsatile photoplethysmographic (PPG) signal associated with cardiac contraction is assumed to be attributable solely to the arterial blood component. The amplitudes of the red and infrared ac PPG signals are sensitive to changes in arterial oxygen saturation because of differences in the light absorption of oxygenated and deoxygenated haemoglobin at these two wavelengths. From the ratios of these amplitudes, and the corresponding dc photoplethysmographic components, arterial blood oxygen saturation (SpO{sub 2}) is estimated. Hence, the technique of pulse oximetry relies on the presence of adequate peripheral arterial pulsations, which are detected as photoplethysmographic (PPG) signals. The aim of this study was to investigate the effect of pressure cuff-induced hypoperfusion on photoplethysmographic signals and arterial blood oxygen saturation using a custom made finger blood oxygen saturation PPG/SpO{sub 2} sensor and a commercial finger pulse oximeter. Blood oxygen saturation values from the custom oxygen saturation sensor and a commercial finger oxygen saturation sensor were recorded from 14 healthy volunteers at various induced brachial pressures

  3. The influence of low-permeability cap on capillary pressure during pumping in unconfined aquifer

    Institute of Scientific and Technical Information of China (English)

    黄辉; 钱家忠; 匡星星; 陈冰宇; 马雷; 吴亚楠

    2013-01-01

    The pumping test in an unconfined aquifer with and without a low-permeability soil was studied experimentally to reveal the influence of the negative air pressure (NP) caused by the upper layer on the water content(w), the water pressure(Pw), as well as on the capillary pressure(Pc). The study demonstrates that the NP generated in the vadose zone during pumping in the capper aquifer has a significant influence onw,wP andPc. ThecP obtained from the capped aquifer is smaller than that without the upper layer. After the NP reaches a peak, the influence of the NP onPc is gradually declined as the air inflows through the upper layer which makes the NP gradually return to zero. When the air pressure returns to the atmospheric pressure,Pc in the vadose zone is only correlated withPw, the same as the case with no upper layer.

  4. Saturated vapor pressure above the amalgam of alkali metals in discharge lamps

    Science.gov (United States)

    Gavrish, S. V.

    2011-12-01

    A theoretical and numerical analysis of the evaporation process of two-component compounds in vapors of alkali metals in discharge lamps is presented. Based on the developed mathematical model of calculation of saturated vapor pressure of the metal above the amalgam, dependences of mass fractions of the components in the discharge volume on design parameters and thermophysical characteristics of the lamp are obtained.

  5. Pressure-Saturation Effects from AVO Attributes in CO2 Monitoring of Weyburn Reservoir, Saskatchewan, Canada

    Science.gov (United States)

    Gao, L.; Morozov, I. B.

    2011-12-01

    In order to measure pore-pressure and saturation effects due to CO2 injection, amplitude variation with offset (AVO) could be a most valuable discriminator. The AVO technique is applied to monitoring the Weyburn reservoir, located in southeast Saskatchewan, using 3D/3C surface seismic datasets. A baseline (1999) and two monitor surveys (2001 and 2002) acquired by EnCana as part of the International Energy Agency GHG Weyburn-Midale CO2 Monitoring and Storage Project are included in this study. Two-term linear AVO attributes including the intercept (I), gradient (G), S-wave reflectivity (I-G)/2 and I+G are derived. Attribute I - G is shown to be most sensitive to pressure variations, and I + G - to CO2 saturation. In addition, several secondary attributes based on statistical distributions of (I, G) values are also examined. The time-lapse AVO attributes indicate areas of pore-pressure and potentially CO2 saturation variations between the horizontal injection wells. The results indicate that AVO technology allows estimating reservoir pressure and fluid saturation variations from time-lapse seismic data.

  6. [Evaluation of the hypomagnetic environment effects on capillary blood circulation, blood pressure and heart rate].

    Science.gov (United States)

    Gurfinkel, Iu I; Vasin, A L; Matveeva, T A; Sasonko, M L

    2014-01-01

    Impact of attenuated magnetic field (MF) on human health is a hard-core issue of present-day cosmonautics. A series of experiments with animals exposed in attenuated MF revealed violent disorders in cardiovascular system development. Purpose of the work was to study effects of the hypomagnetic environment (HME) on capillary blood circulation, blood pressure (BP) and heart rate (HR) in normal people. Participants (n = 34) were 24 men and 10 women free from cardiovascular symptoms. Mean age was 43.3 +/- 15.4 years. Thirteen participants, i.e. 8 men and 5 women, were randomly selected for a repeated investigation in the usual conditions (imaginary exposure); mean age in the group made up 47.9 +/- 18 years. Cardiac rhythm and heart rate were recorded using cardiac monitor Astrocard (Russia). BP was measured with the help of automatic blood pressure monitor Tonocard (Russia). Capillary circulation was determined using a digital capillaroscope (Russia) with high-speed CMOS-camera (100 frames/s). Time of HME exposure was 60 min. It was demonstrated that in healthy people free from cardiovascular symptoms HME increases capillary circulation rate by 22.4% as compared with records made under the usual conditions. There was a reliable HR reduction by the end of HME exposure with reference to the measurements taken at the onset. At the end of exposure, diastolic BP dropped considerably relative to mid-exposure values and systolic BP, on the contrary, made a significant rise.

  7. Impact of sample geometry on the measurement of pressure-saturation curves: experiments and simulations

    CERN Document Server

    Moura, M; Måløy, Knut Jørgen; Schäfer, G; Toussaint, R

    2015-01-01

    In this paper we study the influence of sample geometry on the measurement of pressure-saturation relationships, by analyzing the drainage of a two-phase flow from a quasi-2D random porous medium. The medium is transparent, which allows for the direct visualization of the invasion pattern during flow, and is initially saturated with a viscous liquid (a dyed glycerol-water mix). As the pressure in the liquid is gradually reduced, air penetrates from an open inlet, displacing the liquid which leaves the system from an outlet on the opposite side. Pressure measurements and images of the flow are recorded and the pressure-saturation relationship is computed. We show that this relationship depends on the system size and aspect ratio. The effects of the system's boundaries on this relationship are measured experimentally and compared with simulations produced using an invasion percolation algorithm. The pressure build up at the beginning and end of the invasion process are particularly affected by the boundaries of...

  8. An air-pressure-free elastomeric valve for integrated nucleic acid analysis by capillary electrophoresis

    Science.gov (United States)

    Jung, Wooseok; Barrett, Matthew; Brooks, Carla; Rivera, Andrew; Birdsell, Dawn N.; Wagner, David M.; Zenhausern, Frederic

    2015-12-01

    We present a new elastomeric valve for integrated nucleic acid analysis by capillary electrophoresis. The valve functions include metering to capture a designated volume of biological sample into a polymerase chain reaction (PCR) chamber, sealing to preserve the sample during PCR cycling, and transfer of the PCR-products and on-chip formamide post-processing for the analysis of DNA fragments by capillary gel electrophoresis. This new valve differs from prior art polydimethylsiloxane (PDMS) valves in that the valve is not actuated externally by air-pressure or vacuum so that it simplifies a DNA analysis system by eliminating the need for an air-pressure or vacuum source, and off-cartridge solenoid valves, control circuit boards and software. Instead, the new valve is actuated by a thermal cycling peltier assembly integrated within the hardware instrument that tightly comes in contact with a microfluidic cartridge for thermal activation during PCR, so that it spontaneously closes the valve without an additional actuator system. The valve has bumps in the designated locations so that it has a self-alignment that does not require precise alignment of a valve actuator. Moreover, the thickness of the new valve is around 600 μm with an additional bump height of 400 μm so that it is easy to handle and very feasible to fabricate by injection molding compared to other PDMS valves whose thicknesses are around 30-100 μm. The new valve provided over 95% of metering performance in filling the fixed volume of the PCR chamber, preserved over 97% of the sample volume during PCR, and showed very comparable capillary electrophoresis peak heights to the benchtop assay tube controls with very consistent transfer volume of the PCR-product and on-chip formamide. The new valve can perform a core function for integrated nucleic acid analysis by capillary electrophoresis.

  9. CONSTRUCTION OF EXPERIMENTAL INSTALLATION FOR RESEARCHING OF DENSITY AND SATURATED VAPOR PRESSURE (SVP OF PETROLEUM PRODUCTS

    Directory of Open Access Journals (Sweden)

    Kharchenko P. M.

    2015-03-01

    Full Text Available The most important physical properties that characterize the substance are density and saturated vapor pressure (SVP. These parameters are required for the development of new technical processes in the petroleum and chemical industries, design of pipelines, pumping and fuel equipment, etc. Existing methods for calculating of density near and on the saturation lines are imperfect, and finding of the analytic dependence of SVP of petroleum products from all defining parameters associated with great difficulties. The purpose of present work is an experimental research and development of methods for calculating the density (specific volume near and on saturation lines, and saturated vapor pressure of gasoline straight-run fraction derived from petroleums from three fields: Mangyshlaksky, Trinity-Anastasevsky and West Siberian. The choice of objects for research is due to the necessity of creating methods for calculating of density and SVP of oils obtained from various hydrocarbon group composition petroleums. Area of state parameters in the present work by temperature (20 ÷ 320°C and pressure (0,03 ÷ 30 MPa provides the ability to research gasoline fractions to supercritical regions. Measurement of density and SVP of petroleum fractions performed with help of a specially created for this purpose experimental installation

  10. Properties of meso-Erythritol; phase state, accommodation coefficient and saturation vapour pressure

    Science.gov (United States)

    Emanuelsson, Eva; Tschiskale, Morten; Bilde, Merete

    2016-04-01

    Introduction Saturation vapour pressure and the associated temperature dependence (enthalpy ΔH), are key parameters for improving predictive atmospheric models. Generally, the atmospheric aerosol community lack experimentally determined values of these properties for relevant organic aerosol compounds (Bilde et al., 2015). In this work we have studied the organic aerosol component meso-Erythritol. Methods Sub-micron airborne particles of meso-Erythritol were generated by nebulization from aqueous solution, dried, and a mono disperse fraction of the aerosol was selected using a differential mobility analyser. The particles were then allowed to evaporate in the ARAGORN (AaRhus Atmospheric Gas phase OR Nano particle) flow tube. It is a temperature controlled 3.5 m long stainless steel tube with an internal diameter of 0.026 m (Bilde et al., 2003, Zardini et al., 2010). Changes in particle size as function of evaporation time were determined using a scanning mobility particle sizer system. Physical properties like air flow, temperature, humidity and pressure were controlled and monitored on several places in the setup. The saturation vapour pressures were then inferred from the experimental results in the MATLAB® program AU_VaPCaP (Aarhus University_Vapour Pressure Calculation Program). Results Following evaporation, meso-Erythriol under some conditions showed a bimodal particle size distribution indicating the formation of particles of two different phase states. The issue of physical phase state, along with critical assumptions e.g. the accommodation coefficient in the calculations of saturation vapour pressures of atmospheric relevant compounds, will be discussed. Saturation vapour pressures from the organic compound meso-Erythritol will be presented at temperatures between 278 and 308 K, and results will be discussed in the context of atmospheric chemistry. References Bilde, M. et al., (2015), Chemical Reviews, 115 (10), 4115-4156. Bilde, M. et. al., (2003

  11. [Effect of artificial ventilation on pulmonary capillary pressure in acute respiratory insufficiency].

    Science.gov (United States)

    Labrousse, J; Tenaillon, A; Massabie, P; Simonneau, G; Lissac, J

    1977-05-07

    To determine the influence of intermittent positive pressure breathing (IPPB), the level of pulmonary capillary wedge pressure (PCWP) was compared during IPPB and after a short period off the respirator in 68 occasions on 42 patients with an acute respiratory failure (ARF) of various etiologies. During IPPB, the average PCWP was in the normal range in patients with toxic or neurologic comas and in cases of increased pulmonary capillary permeability edema (IPCPE), PCWP slightly increased within chronic obstructive pulmonary disease (COPD) complicated with ARF and in hemodynamic acute pulmonary edema (HAPE). During the weaning stage, PCWP decreased in the groups of coma, COPD, and IPCPE, but increased in HAPE. The weaning test demonstrates that IPPB influenced PCWP in all patients. Therefore, PCWP cannot be assumed to represent the left ventricle filling pressure. The weaning test allows differentiation of IPCPE from HAPE. In the event of over-infusion or hypovolemia, PCWP measured under IPPB can lead to misinterpretation if not followed up by a second measurement off the respirator.

  12. Exact solution of unsteady flow generated by sinusoidal pressure gradient in a capillary tube

    Directory of Open Access Journals (Sweden)

    M. Abdulhameed

    2015-12-01

    Full Text Available In this paper, the mathematical modeling of unsteady second grade fluid in a capillary tube with sinusoidal pressure gradient is developed with non-homogenous boundary conditions. Exact analytical solutions for the velocity profiles have been obtained in explicit forms. These solutions are written as the sum of the steady and transient solutions for small and large times. For growing times, the starting solution reduces to the well-known periodic solution that coincides with the corresponding solution of a Newtonian fluid. Graphs representing the solutions are discussed.

  13. Comparison of CO2 trapping in highly heterogeneous reservoirs with Brooks-Corey and van Genuchten type capillary pressure curves

    CERN Document Server

    Gershenzon, Naum I; Dominic, David F; Mehnert, Edward; Okwen, Roland T

    2015-01-01

    Geological heterogeneities essentially affect the dynamics of a CO2 plume in subsurface environments. Previously we showed how the dynamics of a CO2 plume is influenced by the multi-scale stratal architecture in deep saline reservoirs. The results strongly suggest that representing small-scale features is critical to understanding capillary trapping processes. Here we present the result of simulation of CO2 trapping using two different conventional approaches, i.e. Brooks-Corey and van Genuchten, for the capillary pressure curves. We showed that capillary trapping and dissolution rates are very different for the Brooks-Corey and van Genuchten approaches when heterogeneity and hysteresis are both represented.

  14. Distribution of pore water pressure in an earthen dam considering unsaturated-saturated seepage analysis

    Directory of Open Access Journals (Sweden)

    Venkatesh Kumar

    2016-01-01

    Full Text Available The variation of pore water pressure in earthen dams plays an important role in maintaining its stability. The pore water pressure within the dam are altered by the external loading conditions like rapid drawdown of reservoir water, earthquake loading and raise of water table caused by infiltration of rainfall. The seepage through an earthen dam involves saturated and unsaturated flows but to avoid complexity in solving the non-linear partial differential equations, the flow in unsaturated zone is neglected and seepage analysis is carried by constructing the flow net in which the pore water pressures beyond the free surface is taken as zero. In actual conditions negative pore water pressure develops beyond the free surface due to the capillarity which leads development to the matrix suction of the soil. In this paper a comparative study on distribution of pore pressure in a zoned earthen dam under steady state and transient conditions had been carried out considering unsaturated-saturated seepage theory. To solve the non-linear partial differential equations, finite element method has been adopted in the present study. The earthen dam has been modeled in different stages. At each stage a new parameter was added and parametric analysis was carried out. The results indicate that negative pore water pressure developed at the downstream side and the pore pressures at the mid-levels of the core are high. This specifies that, soils with low permeability have higher pore pressure. The pore pressures appeared to be higher in upstream side during rapid drawdown compared to steady state.

  15. Detection of elevated pulmonary capillary wedge pressure in elderly patients with various cardiac disorders by the Valsalva manoeuvre.

    NARCIS (Netherlands)

    Remmen, J.J.; Aengevaeren, W.R.M.; Verheugt, F.W.A.; Jansen, R.W.M.M.

    2006-01-01

    In the present study, we assessed whether elevated (> or =15 mmHg) PCWP (pulmonary capillary wedge pressure) can be detected using the blood pressure response to the Valsalva manoeuvre in a group of elderly patients with various cardiac disorders, including atrial fibrillation and valvular heart dis

  16. Saturated fluorescence measurements of the hydroxyl radical in laminar high-pressure flames

    Science.gov (United States)

    Carter, Campbell D.; King, Galen B.; Laurendeau, Normand M.

    1990-01-01

    The efficacy of laser saturated fluorescence (LSF) for OH concentration measurements in high pressure flames was studied theoretically and experimentally. Using a numerical model describing the interaction of hydroxyl with nonuniform laser excitation, the effect of pressure on the validity of the balanced cross-rate model was studied along with the sensitivity of the depopulation of the laser-coupled levels to the ratio of rate coefficients describing: (1) electronic quenching to (sup 2) Sigma (+) (v double prime greater than 0), and (2) vibrational relaxation from v double prime greater than 0 to v double prime = 0. At sufficiently high pressures and near-saturated conditions, the total population of the laser-coupled levels reaches an asymptotic value, which is insensitive to the degree of saturation. When the ratio of electronic quenching to vibrational relaxation is small and the rate of coefficients for rotational transfer in the ground and excited electronic states are nearly the same, the balanced cross-rate model remains a good approximation for all pressures. When the above ratio is large, depopulation of the laser-coupled levels becomes significant at high pressures, and thus the balanced cross-rate model no longer holds. Under these conditions, however, knowledge of the depletion of the laser-coupled levels can be used to correct the model. A combustion facility for operation up to 20 atm was developed to allow LSF measurements of OH in high pressure flames. Using this facility, partial saturation in laminar high pressure (less than or equal to 12.3 atm) C2H6/O2/N2 flames was achieved. To evaluate the limits of the balanced cross-rate model, absorption and calibrated LSF measurements at 3.1 and 6.1 atm were compared. The fluorescence voltages were calibrated with absorption measurements in an atmospheric flame and corrected for their finite sensitivity to quenching with: (1) estimated quenching rate coefficients, and (2) an in situ measurement from a

  17. The influence of temperature, pressure, salinity and capillary force on the formation of methane hydrate

    Directory of Open Access Journals (Sweden)

    Zhenhao Duan

    2011-04-01

    Full Text Available We present here a thermodynamic model for predicting multi-phase equilibrium of methane hydrate liquid and vapor phases under conditions of different temperature, pressure, salinity and pore sizes. The model is based on the 1959 van der Waals–Platteeuw model, angle-dependent ab initio intermolecular potentials, the DMW-92 equation of state and Pitzer theory. Comparison with all available experimental data shows that this model can accurately predict the effects of temperature, pressure, salinity and capillary radius on the formation and dissociation of methane hydrate. Online calculations of the p–T conditions for the formation of methane hydrate at given salinities and pore sizes of sediments are available on: www.geochem-model.org/models.htm.

  18. Pore Water Pressure Response of a Soil Subjected to Traffic Loading under Saturated and Unsaturated Conditions

    Science.gov (United States)

    Cary, Carlos

    This study presents the results of one of the first attempts to characterize the pore water pressure response of soils subjected to traffic loading under saturated and unsaturated conditions. It is widely known that pore water pressure develops within the soil pores as a response to external stimulus. Also, it has been recognized that the development of pores water pressure contributes to the degradation of the resilient modulus of unbound materials. In the last decades several efforts have been directed to model the effect of air and water pore pressures upon resilient modulus. However, none of them consider dynamic variations in pressures but rather are based on equilibrium values corresponding to initial conditions. The measurement of this response is challenging especially in soils under unsaturated conditions. Models are needed not only to overcome testing limitations but also to understand the dynamic behavior of internal pore pressures that under critical conditions may even lead to failure. A testing program was conducted to characterize the pore water pressure response of a low plasticity fine clayey sand subjected to dynamic loading. The bulk stress, initial matric suction and dwelling time parameters were controlled and their effects were analyzed. The results were used to attempt models capable of predicting the accumulated excess pore pressure at any given time during the traffic loading and unloading phases. Important findings regarding the influence of the controlled variables challenge common beliefs. The accumulated excess pore water pressure was found to be higher for unsaturated soil specimens than for saturated soil specimens. The maximum pore water pressure always increased when the high bulk stress level was applied. Higher dwelling time was found to decelerate the accumulation of pore water pressure. In addition, it was found that the higher the dwelling time, the lower the maximum pore water pressure. It was concluded that upon further

  19. A FORTRAN program for interpretation of relative permeability from unsteady-state displacements with capillary pressure included

    Science.gov (United States)

    Udegbunam, E.O.

    1991-01-01

    This paper presents a FORTRAN program for the determination of two-phase relative permeabilities from unsteady-state displacement data with capillary pressure terms included. The interpretative model employed in this program combines the simultaneous solution of a variant of the fractional flow equation which includes a capillary pressure term and an integro-differential equation derived from Darcy's law without assuming the simplified Buckley-Leverett flow. The incorporation of capillary pressure in the governing equations dispenses with the high flowrate experimental requirements normally employed to overcome capillarity effects. An illustrative example is presented herein which implements this program for the determination of oil/water relative permeabilities from a sandstone core sample. Results obtained compares favorably with results previously given in the literature. ?? 1991.

  20. Pore Pressure Response to Groundwater Fluctuations in Saturated Double-Layered Soil

    Directory of Open Access Journals (Sweden)

    Hongwei Ying

    2015-01-01

    Full Text Available Analytical solutions are developed for one-dimensional consolidation of double-layered saturated soil subjected to groundwater fluctuations. The solutions are derived by an explicit mathematical procedure using Duhamel’s theorem in conjunction with a Fourier series, when groundwater fluctuation is described by a general time-dependent function and assumed to be the pore water pressure variations at the upper boundary. Taking as an example the harmonic groundwater fluctuation, the relevant response of the excess pore water pressure is discussed in detail, and the main influencing factors of the excess pore pressure distribution are analyzed. A dimensionless parameter θ has been introduced because it significantly affects the phase and the amplitude of excess pore pressures. The influences of the coefficients of permeability and compressibility of soil on the excess pore pressure distribution are different and cannot be incorporated into the coefficient of consolidation in double-layered soil. The relative permeability ratio of two clayey soils also plays an important role on the curves of the distributions of the excess pore pressures. The effects of the thickness of the soil layer on the excess pore pressure distribution should be considered together with the dimensionless parameter θ and the permeability and compressibility of the double-layered soil system.

  1. Feasibility of hydroxyl concentration measurements by laser-saturated fluorescence in high-pressure flames

    Science.gov (United States)

    Carter, Campbell D.; King, Galen B.; Laurendeau, Normand M.; Salmon, J. Thaddeus

    1987-01-01

    The effect of pressure on the laser-saturated fluorescence method for measuring OH concentration in high-pressure flames is studied using calculations for the burned-gas region of a stoichiometric H2-O2 flame at 2000 K. A numerical model of the excitation dynamics of OH is developed to explore the validity of the balanced cross-rate model at higher pressures. It is shown that depopulation of the laser-coupled levels is sensitive to collisions which depopulate v-double-prime (VDP) = 0 and to rate coefficients for rotational transfer in the ground state which are smaller than those in the excited state. In particular, it is shown that the depopulation of VDP = 0, and hence the laser-coupled levels, depends on the probability of electronic quenching to vibrational levels for which VDP is greater than 0 and vibrational relaxation to VDP = 0.

  2. Pressure-accelerated azide-alkyne cycloaddition: micro capillary versus autoclave reactor performance.

    Science.gov (United States)

    Borukhova, Svetlana; Seeger, Andreas D; Noël, Timothy; Wang, Qi; Busch, Markus; Hessel, Volker

    2015-02-01

    Pressure effects on regioselectivity and yield of cycloaddition reactions have been shown to exist. Nevertheless, high pressure synthetic applications with subsequent benefits in the production of natural products are limited by the general availability of the equipment. In addition, the virtues and limitations of microflow equipment under standard conditions are well established. Herein, we apply novel-process-window (NPWs) principles, such as intensification of intrinsic kinetics of a reaction using high temperature, pressure, and concentration, on azide-alkyne cycloaddition towards synthesis of Rufinamide precursor. We applied three main activation methods (i.e., uncatalyzed batch, uncatalyzed flow, and catalyzed flow) on uncatalyzed and catalyzed azide-alkyne cycloaddition. We compare the performance of two reactors, a specialized autoclave batch reactor for high-pressure operation up to 1800 bar and a capillary flow reactor (up to 400 bar). A differentiated and comprehensive picture is given for the two reactors and the three methods of activation. Reaction speedup and consequent increases in space-time yields is achieved, while the process window for favorable operation to selectively produce Rufinamide precursor in good yields is widened. The best conditions thus determined are applied to several azide-alkyne cycloadditions to widen the scope of the presented methodology.

  3. Diamond synthesis at atmospheric pressure by microwave capillary plasma chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Hemawan, Kadek W.; Gou, Huiyang; Hemley, Russell J. [Geophysical Laboratory, Carnegie Institution of Washington, 5251 Broad Branch Rd., NW, Washington, DC 20015 (United States)

    2015-11-02

    Polycrystalline diamond has been synthesized on silicon substrates at atmospheric pressure, using a microwave capillary plasma chemical vapor deposition technique. The CH{sub 4}/Ar plasma was generated inside of quartz capillary tubes using 2.45 GHz microwave excitation without adding H{sub 2} into the deposition gas chemistry. Electronically excited species of CN, C{sub 2}, Ar, N{sub 2}, CH, H{sub β}, and H{sub α} were observed in the emission spectra. Raman measurements of deposited material indicate the formation of well-crystallized diamond, as evidenced by the sharp T{sub 2g} phonon at 1333 cm{sup −1} peak relative to the Raman features of graphitic carbon. Field emission scanning electron microscopy images reveal that, depending on the growth conditions, the carbon microstructures of grown films exhibit “coral” and “cauliflower-like” morphologies or well-facetted diamond crystals with grain sizes ranging from 100 nm to 10 μm.

  4. Influence of clay and silica on permeability and capillary entry pressure of chalk reservoirs in the North Sea

    DEFF Research Database (Denmark)

    Røgen, Birte; Fabricius, Ida Lykke

    2002-01-01

    The permeability and capillary entry pressure of chalk reservoirs are controlled by their porosity and specific surface area. Measured permeabilities are in the range 0.025-5.3 mD and are successfully predicted by use of the Kozeny equation. In this paper we focus on the factors that control...

  5. Vibration pore water pressure characteristics of saturated fine sand under partially drained condition

    Institute of Scientific and Technical Information of China (English)

    王炳辉; 陈国兴

    2008-01-01

    Vibration pore water pressure characteristics of saturated fine sand under partially drained condition were investigated through stress-controlled cyclic triaxial tests employed varied fine content of samples and loading frequency. In order to simulate the partially drained condition, one-way drainage for sample was implemented when cyclic loading was applied. The results show that the vibration pore water pressure’s response leads the axial stress and axial strain responses, and is lagged behind or simultaneous with axial strain-rate’s response for all samples in this research. In addition, the satisfactory linear relationship between vibration pore water pressure amplitude and axial strain-rate amplitude is also obtained. It means that the direct cause of vibration pore water pressure generation under partially drained conditions is not the axial stress or axial strain but the axial strain-rate. The lag-phase between pore water pressure and axial strain-rate increases with the increase of the fine content or the loading frequency.

  6. Preparation and Characterization of β-Cyclodextrin Derivatized Ovalbumin Used as Chiral Selector in Pressure Capillary Electrochromatography

    Institute of Scientific and Technical Information of China (English)

    YU Yu-hong; TANG Li; DAI Rong-ji; DENG Yu-lin; FU Ruo-nong

    2007-01-01

    Synthesis and properties of β-cyclodextrin derivatized ovalbumin used as chiral selector were investigated.β-cyclodextrin derivatized ovalbumin was synthesized using β-cyclodextrin and ovalbumin in the presence of ethylene glycol diglycidyl ether in boric acid buffer at pH value 8.7 at 37 ℃.Amino group was coated on the internal surface of the silica capillary by sol-gel technology with triethoxylmethylsiloxane and (3-arninopropyl)trimethoxysiloxane.Covalent binding of β-cyclodextrin derivatized ovalbumin was performed by glutaraldehyde.Enantiomers of chlorpheniramine,phenylalanine and atropine were separated by pressure capillary electrochromatography column coated with β-cyclodextrin derivatized ovalbumin.

  7. Signal-Pressure Curves of Cascaded Four-Wave Mixing in Gas-Filled Capillary by fs Pulses

    Institute of Scientific and Technical Information of China (English)

    CHEN Bao-Zhen; HUANG Zu-Qia

    2005-01-01

    The theoretical framework for the cascaded four waves mixing (CFWM) in gas-filled capillary by fs pulses is constructed. Based on the theoretical framework, the signal-pressure curves (SPC) of the CFWM in gas-filled capillary by fs pulses are calculated. With a comparison between the theoretical and experimental SPC we have discussed the influence of the walk-off and Phase modulation on the SPC. At the same time, we have discussed the possible origin of the first three peaks of the SPC.

  8. Microwave air plasmas in capillaries at low pressure I. Self-consistent modeling

    Science.gov (United States)

    Coche, P.; Guerra, V.; Alves, L. L.

    2016-06-01

    This work presents the self-consistent modeling of micro-plasmas generated in dry air using microwaves (2.45 GHz excitation frequency), within capillaries (model couples the system of rate balance equations for the most relevant neutral and charged species of the plasma to the homogeneous electron Boltzmann equation. The maintenance electric field is self-consistently calculated adopting a transport theory for low to intermediate pressures, taking into account the presence of O- ions in addition to several positive ions, the dominant species being O{}2+ , NO+ and O+ . The low-pressure small-radius conditions considered yield very-intense reduced electric fields (˜600-1500 Td), coherent with species losses controlled by transport and wall recombination, and kinetic mechanisms strongly dependent on electron-impact collisions. The charged-particle transport losses are strongly influenced by the presence of the negative ion, despite its low-density (˜10% of the electron density). For electron densities in the range (1-≤ft. 4\\right)× {{10}12} cm-3, the system exhibits high dissociation degrees for O2 (˜20-70%, depending on the working conditions, in contrast with the  ˜0.1% dissociation obtained for N2), a high concentration of O2(a) (˜1014 cm-3) and NO(X) (5× {{10}14} cm-3) and low ozone production (<{{10}-3}% ).

  9. High Q silica microbubble resonators fabricated by heating a pressurized glass capillary

    Science.gov (United States)

    Yu, Zhe; Liu, Tiegen; Jiang, Junfeng; Liu, Kun; Chen, Wenjie; Zhang, Xuezhi; Lin, Xujun; Liu, Wenhui

    2014-11-01

    Microbubble resonators combine the unique properties of whispering gallery mode resonators with the capability of integrated microfluidics. The microbubble resonator is fabricated by heating the tapered tip of a pressurized glass capillary with oxyhydrogen flame. Firstly, a microtube with a diameter of 250um is stretched under heating of oxyhydrogen flame, the heating zone length is set to be 20mm and the length of stretch is set to be 7000um.Then nitrogen will be pumped in to the tapered microtube with the pressure of 0.1Mpa, the tapered tip will be heated by the oxyhydrogen flame continuously until a microbubble forms. An optical fiber taper with a diameter of 2 um, fabricated by stretching a single-mode optical fiber under flame was brought in contact with the microbubble to couple the light from a 1550nm tunable diode laser into the whispering gallery mode. The microbubble resonator has a Q factors up to 1.5 × 107 around 1550nm. Different concentrations of ethanol solution (from 5% to 30%) are filled into it in order to test the refractive index sensing capabilities of such resonator, which shows a sensitivity of 82nm/RIU.

  10. Relation of blood pressure to reported intake of salt, saturated fats, and alcohol in healthy middle-aged population.

    OpenAIRE

    Salonen, J.T.; Tuomilehto, J; A. Tanskanen

    1983-01-01

    The association of blood pressure with reported intake of salt, saturated fats, and alcohol was studied in a sample of 8479 subjects based on a cross sectional survey in a population aged 30 to 64 years. A consistent association was found between the mean arterial pressure and the intake of alcohol (p less than 0.001) and saturated fats (p less than 0.01). There was also a weak association between blood pressure and dietary salt intake, but this association was mostly explained by the correla...

  11. Intrinsic advantages of packed capillaries over narrow-bore columns in very high-pressure gradient liquid chromatography.

    Science.gov (United States)

    Gritti, Fabrice; McDonald, Thomas; Gilar, Martin

    2016-06-17

    250μm×100mm fused silica glass capillaries were packed with 1.8μm high-strength silica (HSS) fully porous particles. They were prepared without bulky stainless steel endfittings and metal frits, which both generate significant sample dispersion. The isocratic efficiencies and gradient peak capacities of these prototype capillary columns were measured for small molecules (n-alkanophenones) using a home-made ultra-low dispersive micro-HPLC instrument. Their resolution power was compared to that of standard 2.1mm×100mm very high-pressure liquid chromatography (vHPLC) narrow-bore columns packed with the same particles. The results show that, for the same column efficiency (25000 plates) and gradient steepness (0.04min(-1)), the peak capacity of the 250μm i.d. capillary columns is systematically 15-20% higher than that of the 2.1mm i.d. narrow-bore columns. A validated model of gradient chromatography enabled one to predict accurately the observed peak capacities of the capillary columns for non-linear solvation strength retention behavior and under isothermal conditions. Thermodynamics applied to the eluent quantified the temperature difference for the thermal gradients in both capillary and narrow-bore columns. Experimental data revealed that the gradient peak capacity is more affected by viscous heating than the column efficiency. Unlike across 2.1mm i.d. columns, the changes in eluent composition across the 250μm i.d. columns during the gradient is rapidly relaxed by transverse dispersion. The combination of (1) the absence of viscous heating and (2) the high uniformity of the eluent composition across the diameter of capillary columns explains the intrinsic advantage of capillary over narrow-bore columns in gradient vHPLC.

  12. A high pressure triaxial cell with improved measurement sensitivity for saturated water permeability of high performance concrete

    Energy Technology Data Exchange (ETDEWEB)

    El-Dieb, A.S.; Hooton, R.D. (Univ. of Toronto, Ontario (Canada). Dept. of Civil Engineering)

    1994-01-01

    The measurement of the saturated water permeability of concrete is of great interest, but with the rapid improvements in properties of high performance concretes, the most common problem is the ability and accuracy of measuring the very small flow volumes. A high pressure triaxial cell with improved measurement sensitivity, capable of continuously measuring saturated water permeability of the order of < 10[sup [minus]15] m/s, is presented in this paper.

  13. Elastic response of mesoporous silicon to capillary pressures in the pores

    Science.gov (United States)

    Gor, Gennady Y.; Bertinetti, Luca; Bernstein, Noam; Hofmann, Tommy; Fratzl, Peter; Huber, Patrick

    2015-06-01

    We study water adsorption-induced deformation of a monolithic, mesoporous silicon membrane traversed by independent channels of ˜8 nm diameter. We focus on the elastic constant associated with the Laplace pressure-induced deformation of the membrane upon capillary condensation, i.e., the pore-load modulus. We perform finite-element method (FEM) simulations of the adsorption-induced deformation of hexagonal and square lattices of cylindrical pores representing the membrane. We find that the pore-load modulus weakly depends on the geometrical arrangement of pores, and can be expressed as a function of porosity. We propose an analytical model which relates the pore-load modulus to the porosity and to the elastic properties of bulk silicon (Young's modulus and Poisson's ratio), and provides an excellent agreement with FEM results. We find good agreement between our experimental data and the predictions of the analytical model, with the Young's modulus of the pore walls slightly lower than the bulk value. This model is applicable to a large class of materials with morphologies similar to mesoporous silicon. Moreover, our findings suggest that liquid condensation experiments allow one to elegantly access the elastic constants of a mesoporous medium.

  14. [The effect of growth media on recovery of test microorganisms after exposure to saturated steam under pressure].

    Science.gov (United States)

    Krzywicka, H; Jakimiak, B; Zarzycka, E

    1996-01-01

    The aim of this study was to find out which growth media give the best condition for the development of test bacteria after exposure to saturated steam under pressure. The test organisms were strains of Bacillus subtilis NCTC 3610 and Bacillus stearothermophilus NCTC 8923. The test prepared from spore suspension were exposed to saturated steam under pressure 0.2 atn-B.subtilis, and 0.7 atn-B. stearothermophilus with various length of exposure /sublethal conditions/. After the exposure the tests were placed in growth media. The obtained results show that the compositions of the medium in which spore-forming bacteria are grown after the exposure under sublethal conditions to saturated steam under pressure affects the recovery of the test organism. The media with glucose, tryptose and L-alanine provided the best conditions for growth.

  15. Accurate relations between pore size and the pressure of capillary condensation and the evaporation of nitrogen in cylindrical pores.

    Science.gov (United States)

    Morishige, Kunimitsu; Tateishi, Masayoshi

    2006-04-25

    To examine the theoretical and semiempirical relations between pore size and the pressure of capillary condensation or evaporation proposed so far, we constructed an accurate relation between the pore radius and the capillary condensation and evaporation pressure of nitrogen at 77 K for the cylindrical pores of the ordered mesoporous MCM-41 and SBA-15 silicas. Here, the pore size was determined from a comparison between the experimental and calculated X-ray diffraction patterns due to X-ray structural modeling recently developed. Among the many theoretical relations that differ from each other in the degree of theoretical improvements, a macroscopic thermodynamic approach based on Broekhoff-de Boer equations was found to be in fair agreement with the experimental relation obtained in the present study.

  16. Compensation for the Effects of Ambient Conditions on the Calibration of Multi-Capillary Pressure Drop Standards

    Directory of Open Access Journals (Sweden)

    Colard S

    2014-12-01

    Full Text Available Cigarette draw resistance and filter pressure drop (PD are both major physical parameters for the tobacco industry. Therefore these parameters must be measured reliably. For these measurements, specific equipment calibrated with PD transfer standards is used. Each transfer standard must have a known and stable PD value, such standards usually being composed of several capillary tubes associated in parallel. However, PD values are modified by ambient conditions during calibration of such standards, i.e. by temperature and relative humidity (RH of air, and atmospheric pressure. In order to reduce the influence of these ambient factors, a simplified model was developed for compensating the effects of ambient conditions on the calibration of multi-capillary PD standards.

  17. Demonstration of gain saturation and double-pass amplification of a 69.8  nm laser pumped by capillary discharge.

    Science.gov (United States)

    Zhao, Yongpeng; Liu, Tao; Zhang, Wenhong; Li, Wei; Cui, Huaiyu

    2016-08-15

    With a 45-cm-long capillary, we obtained a saturated 69.8 nm laser with a gain coefficient of 0.4  cm-1 and a gain length product of 18. In order to increase the laser energy further, a double-pass amplification of the 69.8 nm laser was first realized with a SiC mirror without a coating. With a half cavity, the effective plasma column length and the effective gain length product can reach 84 cm and 33.7, respectively. The amplitude of a laser pulse for double-pass amplification is 9 times larger than that for single-pass amplification. In addition, the full width at half-maximum (FWHM) pulse width of a laser pulse and FWHM divergence for single-pass amplification are 1.4 ns and 0.5 mrad, respectively, which increase to 2.2 ns and 3.4 mrad for double-pass amplification.

  18. Dietary saturated and unsaturated fats as determinants of blood pressure and vascular function.

    Science.gov (United States)

    Hall, Wendy L

    2009-06-01

    The amount and type of dietary fat have long been associated with the risk of CVD. Arterial stiffness and endothelial dysfunction are important risk factors in the aetiology of CHD. A range of methods exists to assess vascular function that may be used in nutritional science, including clinic and ambulatory blood pressure monitoring, pulse wave analysis, pulse wave velocity, flow-mediated dilatation and venous occlusion plethysmography. The present review focuses on the quantity and type of dietary fat and effects on blood pressure, arterial compliance and endothelial function. Concerning fat quantity, the amount of dietary fat consumed habitually appears to have little influence on vascular function independent of fatty acid composition, although single high-fat meals postprandially impair endothelial function compared with low-fat meals. The mechanism is related to increased circulating lipoproteins and NEFA which may induce pro-inflammatory pathways and increase oxidative stress. Regarding the type of fat, cross-sectional data suggest that saturated fat adversely affects vascular function whereas polyunsaturated fat (mainly linoleic acid (18 : 2n-6) and n-3 PUFA) are beneficial. EPA (20 : 5n-3) and DHA (22 : 6n-3) can reduce blood pressure, improve arterial compliance in type 2 diabetics and dyslipidaemics, and augment endothelium-dependent vasodilation. The mechanisms for this vascular protection, and the nature of the separate physiological effects induced by EPA and DHA, are priorities for future research. Since good-quality observational or interventional data on dietary fatty acid composition and vascular function are scarce, no further recommendations can be suggested in addition to current guidelines at the present time.

  19. Capillary flow through heat-pipe wicks

    Science.gov (United States)

    Eninger, J. E.

    1975-01-01

    Theoretical expressions are obtained for the capillary-pressure limit and permeability of a fibrous wick in terms of the porosity and fiber diameter. Hysteresis in capillary pressure is included through the introduction of an empirical hysteresis constant. A partial-saturation model based on the statistical distribution of local porosity requires an additional empirical constant, the standard deviation. The theory is compared to results of a beta-ray absorption experiment that measured the liquid content of a partially saturated wick and to results of permeability measurements on partially and fully saturated wicks. A simple wick-weighing experiment is described that yields values for the empirical hysteresis constant and the standard deviation. Theoretical results are used to design an optimum wick.

  20. Capillary pressure overshoot for unstable wetting fronts is explained by Hoffman's velocity-dependent contact-angle relationship

    Science.gov (United States)

    Baver, Christine E.; Parlange, J.-Yves; Stoof, Cathelijne R.; DiCarlo, David A.; Wallach, Rony; Durnford, Deanna S.; Steenhuis, Tammo S.

    2014-06-01

    Pore velocity-dependent dynamic contact angles provide a mechanism for explaining the formation of fingers/columns in porous media. To study those dynamic contact angles when gravity is present, rectangular capillary tubes were used to facilitate observation of the complete interface without geometric distortion. Results show that the Hoffman (1975) relationship between dynamic contact angle and water velocity applies to gravity-affected flow fields, and that it (when adjusted for nonzero static contact angles) can be used to model dynamic capillary pressures for unstable wettings fronts in porous media by assuming that (1) pressure at the wetting front is discontinuous, (2) the flow field behind the fingertip is highly heterogeneous, and (3) the front line advances one or a few pores at the time. We demonstrate the utility of the Hoffman relationship for porous media with a published infiltration experiment by calculating the capillary pressure successfully at the unstable wetting front as a function of the flux of water in the finger and the grain size diameter.

  1. Reducing Mechanical Formation Damage by Minimizing Interfacial Tension and Capillary Pressure in Tight Gas

    Science.gov (United States)

    Ahmed, Arshad; Talib Shuker, Muhannad; Rehman, Khalil; Bahrami, Hassan; Memon, Muhammad Khan

    2013-12-01

    Tight gas reservoirs incur problems and significant damage caused by low permeability during drilling, completion, stimulation and production. They require advanced improvement techniques to achieve flow gas at optimum rates. Water blocking damage (phase Trapping/retention of fluids) is a form of mechanical formation damage mechanism, which is caused by filtrate invasion in drilling operations mostly in fracturing. Water blocking has a noticeable impact on formation damage in gas reservoirs which tends to decrease relative permeability near the wellbore. Proper evaluation of damage and the factors which influence its severity is essential to optimize well productivity. Reliable data regarding interfacial tension between gas and water is required in order to minimize mechanical formation damage potential and to optimize gas production. This study was based on the laboratory experiments of interfacial tension by rising drop method between gas-brine, gas-condensate and gas-brine. The results showed gas condensate has low interfacial tension value 6 - 11 dynes/cm when compared to gas-brine and gas- diesel which were 44 - 58 dynes/cm and 14 - 19 dynes/cm respectively. In this way, the capillary pressure of brine-gas system was estimated as 0.488 psi, therefore diesel-gas system was noticed about 0.164 psi and 0.098 psi for condensate-gas system. A forecast model was used by using IFT values to predict the phase trapping which shows less severe phase trapping damage in case of condensate than diesel and brine. A reservoir simulation study was also carried out in order to better understand the effect of hysteresis on well productivity and flow efficiency affected due to water blocking damage in tight gas reservoirs.

  2. Influence of charge accumulation on a dielectric capillary atmospheric pressure plasma jet

    Science.gov (United States)

    Sands, Brian; Huang, Shih; Speltz, Jared; Niekamp, Matthew; Ganguly, Biswa

    2011-10-01

    Using a single ring electrode configuration and a positive unipolar pulsed voltage source, we examine the influence of the dielectric barrier on the distribution of ionization in a streamer-like dielectric capillary plasma jet utilizing a rare gas flow as a function of anode placement and pulse repetition frequency. At low frequencies, when the anode is recessed at least 5 mm along the capillary, two regions of enhanced ionization can be resolved near the anode and near the capillary tip that are associated with two distinct peaks in the discharge current and locally increased emission intensity in the residual streamer channel. With the anode placed ~20 mm from the capillary tip, the two current peaks were ~13 mA. Increasing the frequency between 6 and 10 kHz, the capillary tip enhancement expanded towards the anode and concentrated there at higher frequencies. The discharge current over this frequency range rose to 18 mA and was increasingly dominated by the earlier peak associated with ionization near the anode. This increased charging of the dielectric surface and reduced the potential available to the ionization front outside the capillary as indicated by a 25% drop in velocity and reduced emission intensity. The surface charging effect is visualized at discharge inception using a Phantom high-frame-rate CCD camera.

  3. Spectral properties of molecular iodine absorption cells filled to saturation pressure

    Science.gov (United States)

    Hrabina, Jan; Sarbort, Martin; Cip, Ondrej; Lazar, Josef

    2014-05-01

    The absorption cells - optical frequencies references - represent the crucial part of setups for practical realization of the meter unit - highly stable laser standards, where varied laser sources are frequency locked to the selected absorption transitions. Furthermore, not only in the most precise laboratory instruments, but also in less demanding interferometric measuring setups the frequency stabilization of the lasers throught the absorption in suitable media ensure the direct traceability to the fundamental standard of length. We present the results of measurement and evaluation of spectral properties of molecular iodine absorption cells filled to saturation pressure of absorption media. A set of cells filled with different amounts of molecular iodine was prepared and an agreement between expected and resulting spectral properties of these cells was observed and evaluated. The cells made of borosilicate glass instead of common fused silica were tested for their spectral properties in greater detail with special care for the absorption media purity - the measured hyperfine transitions linewidths were compared to cells traditionally made of fused silica glass with well known iodine purity. The usage of borosilicate glass material represents easier manufacturing process and also significant costs reduction but a great care must be taken to control/avoid the risk of absorption media contamination. An approach relying on measurement of linewidth of the hyperfine transitions is proposed and discussed.

  4. An experimental study of constant-pressure steam injection and transient condensing flow in an air-saturated porous medium

    NARCIS (Netherlands)

    Brouwers, H.J.H.

    1996-01-01

    In this paper the unsteady process of constant pressure steam injection into an air–saturated porous medium is studied experimentally. To this end, vertical glass tubes are packed with dry quartz sand and injected with dry steam. The propagation of the steam front appears to be proportional to t. It

  5. Microwave air plasmas in capillaries at low pressure II. Experimental investigation

    Science.gov (United States)

    Stancu, G. D.; Leroy, O.; Coche, P.; Gadonna, K.; Guerra, V.; Minea, T.; Alves, L. L.

    2016-11-01

    This work presents an experimental study of microwave (2.45 GHz excitation frequency) micro-plasmas, generated in dry air (N2 80%: O2 20%) within a small radius silica capillary (345 µm inner radius) at low pressure (300 Pa) and low powers (80-130 W). Experimental diagnostics are performed using optical emission spectroscopy calibrated in absolute intensity. Axial-resolved measurements (50 µm spatial resolution) of atomic transitions N(3p4S)  →  N(3s4P) O(3p5P)  →  O(3s5S) and molecular transitions N2(C,v‧)  →  N2(B,v″) \\text{N}2+ (B,v‧)  →  \\text{N}2+ (X,v″) allow us to obtain, as a function of the coupled power, the absolute densities of N(3p4S), O(3p5P), N2(C), N2(B) and \\text{N}2+ (B), as well as the gas (rotational) temperature (700-1000 K), the vibrational temperature of N2(C,v) (7000-10 000 K) and the excitation temperatures of N2(C) and N2(B) (11 000 K). The analysis of the H β line-width gives an upper limiting value of 1013 cm-3 for the electron density; its axial variation (4  ×  1011-6  ×  1012 cm-3) being estimated by solving the wave electrodynamics equations for the present geometry, plasma length and electron-neutral collision frequency. The experimental results were compared with the results from a 0D model, presented in companion paper I [1], which couples the system of rate balance equations for the dominant neutral and charged plasma species to the homogeneous two-term electron Boltzmann equation, taking the measured gas temperature and the estimated electron density as input parameters. Good qualitative agreement is found between the measurements and calculations of the local species densities for various powers and axial positions. The dissociation degree of oxygen is found above 10%. Moreover, both the measurements and calculations show evidence of the non-equilibrium behavior of low-temperature plasmas, with vibrational and excitation temperatures at least

  6. Angular Momentum Transport by MHD Turbulence in Accretion Disks: Gas Pressure Dependence of the Saturation Level of the Magnetorotational Instability

    CERN Document Server

    Sano, T; Turner, N J; Stone, J M; Sano, Takayoshi; Inutsuka, Shu-ichiro; Turner, Neal J.; Stone, James M.

    2004-01-01

    The saturation level of the magnetorotational instability (MRI) is investigated using three-dimensional MHD simulations. The shearing box approximation is adopted and the vertical component of gravity is ignored, so that the evolution of the MRI is followed in a small local part of the disk. We focus on the dependence of the saturation level of the stress on the gas pressure, which is a key assumption in the standard alpha disk model. From our numerical experiments it is found that there is a weak power-law relation between the saturation level of the Maxwell stress and the gas pressure in the nonlinear regime; the higher the gas pressure, the larger the stress. Although the power-law index depends slightly on the initial field geometry, the relationship between stress and gas pressure is independent of the initial field strength, and is unaffected by Ohmic dissipation if the magnetic Reynolds number is at least 10. The relationship is the same in adiabatic calculations, where pressure increases over time, an...

  7. Vapor Pressure of Saturated Aqueous Solutions of Potassium Sulfate from 310 K to 345 K

    Directory of Open Access Journals (Sweden)

    Matias O. Maggiolo

    2011-01-01

    Full Text Available The experimental evaluation of the vapor pressure of saturated aqueous solutions of potassium sulfate was carried out in the range of temperatures 310 K≤T≤345 K. The experimental data were used to determine the corresponding values of the water activity in such solutions. The analytical expressions as a function of temperature of both, vapor pressure and water activity, were obtained from the correlation of the experimental results. The vapor pressure expression was also extrapolated to a different temperature range in order to make a comparison with the results obtained by other authors.

  8. An improved method for predicting permeability by combining electrical measurements and mercury injection capillary pressure data

    Science.gov (United States)

    Zhang, Chong; Cheng, Yuan; Zhang, Chaomo

    2017-02-01

    The applicability of the representative elemental volume (REV) model is analyzed on the basis of the capillary pressure curves, resistivity, porosity and permeability, taken from the experimental measurement data of 83 sandstone core samples from three different blocks mined in China. The results show that the permeability error (the ratio of core permeability to the permeability calculated by the REV model) can be controlled from 0.5 to 2 when the core permeability is more than 3 mD. On the whole, the permeability error is more than 2, and the calculated permeability is lower than the core permeability when the core permeability is less than 3 mD. The reason for the poor calculation accuracy of the REV model in low permeability sandstone is analyzed, and the research suggests that the ∫dS v/(P c)2 in the REV model characterizes the pore-throat radius of the rock. In reality, the permeability is influenced by the throat radius rather than the pore radius. When the core permeability is large enough, there is no obvious difference between the pore radius and the throat radius. So, the error between the core permeability and the permeability calculated by the REV model is small. However, when the core permeability is small, the difference between the pore radius and the throat radius is apparent, and, in general, the pore radius is larger than the throat radius. In these conditions, the pore radius plays a leading role in ∫dS v/(P c)2, thus making the error between the core permeability and the permeability calculated by the REV model apparent. Based on the above, we have derived an improved REV model by introducing the pore-throat radius ratio on the basis of Poiseuille’s law and Darcy’s law. Using the same experimental data, we make a comparison analysis between the improved model, the REV model and the Swanson model. The results show that compared with the REV model and the Swanson model, the accuracy of the calculated permeability of the improved model is

  9. Pore-lining composition and capillary breakthrough pressure of mudstone caprocks : sealing efficiency at geologic CO2 storage sites.

    Energy Technology Data Exchange (ETDEWEB)

    Heath, Jason E.; Nemer, Martin B.; McPherson, Brian J. O. L. (University of Utah, Salt Lake City, UT); Dewers, Thomas A.; Kotula, Paul Gabriel

    2010-12-01

    Subsurface containment of CO2 is predicated on effective caprock sealing. Many previous studies have relied on macroscopic measurements of capillary breakthrough pressure and other petrophysical properties without direct examination of solid phases that line pore networks and directly contact fluids. However, pore-lining phases strongly contribute to sealing behavior through interfacial interactions among CO2, brine, and the mineral or non-mineral phases. Our high resolution (i.e., sub-micron) examination of the composition of pore-lining phases of several continental and marine mudstones indicates that sealing efficiency (i.e., breakthrough pressure) is governed by pore shapes and pore-lining phases that are not identifiable except through direct characterization of pores. Bulk X-ray diffraction data does not indicate which phases line the pores and may be especially lacking for mudstones with organic material. Organics can line pores and may represent once-mobile phases that modify the wettability of an originally clay-lined pore network. For shallow formations (i.e., < {approx}800 m depth), interfacial tension and contact angles result in breakthrough pressures that may be as high as those needed to fracture the rock - thus, in the absence of fractures, capillary sealing efficiency is indicated. Deeper seals have poorer capillary sealing if mica-like wetting dominates the wettability. We thank the U.S. Department of Energy's National Energy Technology Laboratory and the Office of Basic Energy Sciences, and the Southeast and Southwest Carbon Sequestration Partnerships for supporting this work.

  10. Quantification of Viscosity and Capillary Pressure Anomalies for Polar Liquids in 2D Hydrophilic Nano-Confinements

    Science.gov (United States)

    Kelly, S. A.; Torres-Verdin, C.; Balhoff, M.

    2014-12-01

    Interest in liquid and interfacial behavior within nano-confinements spans many disciplines. Geophysical interest originates from a desire to understand flow mechanisms through hydrocarbon-rich nano-porous shale media, especially communication between fractures and the adjacent nano-porous matrix (imbibition). This work investigates the extent of boundary layer nucleation during polar liquid flows in hydrophilic nano-confinements via discrepancies seen in viscosity and capillary pressure from their bulk values. We perform our experiments in two-dimensional nanochannels of varying size and as small as 30 nm x 60 nm in cross section and still obtain visual data with reflected differential interference contrast (DIC) microscopy. The simple geometry of the nanochannels enables the comparison against analytical transport solutions. By designing a nanochannel experiment that allows us to monitor the rate of fluid imbibition and volume loss of a trapped air pocket the liquid is imbibing into, we are able to decouple capillary pressure and viscosity from imbibition data, as well as gain information about gas partitioning at the meniscus interface. Our current experiments are performed with organic solvents within siliceous nanochannels and the results of the decoupling scheme indicate that for rectangular nanochannels with heights of 60 nm and varying widths, effective viscosity is consistently between 4-12 times higher than the bulk value and capillary pressure is around 50% less than the macroscopic Young-Laplace equation prediction. These results equate to the nucleation of wall boundary layers on the order of tens of molecular layers thick. Structured boundary layers have an inherently increased viscosity compared to the liquid bulk value, resulting in a significant reduction in imbibition efficacy. This presence of approximately 15 nm boundary layers in on the threshold of two different theories - thin bimolecular boundary layers and exclusion zones (thick boundary

  11. Thermodynamics of the multicomponent vapor-liquid equilibrium under capillary pressure difference

    DEFF Research Database (Denmark)

    Shapiro, Alexander; Stenby, Erling Halfdan

    2001-01-01

    , not for the multicomponent mixtures. The importance is emphasized on the space of the intensive variables P, T and mu (i), where the laws of capillary equilibrium have a simple geometrical interpretation. We formulate thermodynamic problems specific to such an equilibrium, and outline changes to be introduced to common...

  12. Memory Effects on Nonlinear Temperature and Pressure Wave Propagation in the Boundary between Two Fluid-Saturated Porous Rocks

    OpenAIRE

    Garra, R.; Salusti, E.; Droghei, R.

    2015-01-01

    The evolution of strong transients of temperature and pressure in two adjacent fluid-saturated porous rocks is described by a Burgers equation in an early model of Natale and Salusti (1996). We here consider the effect of a realistic intermediate region between the two media and infer how transient processes can also happen, such as chemical reactions, diffusion of fine particles, and filter cake formations. This suggests enlarging our analysis and taking into account not only punctual quanti...

  13. Experimental effects of pressure and fluorine on apatite saturation in mafic magmas, with reference to layered intrusions and massif anorthosites

    Science.gov (United States)

    Tollari, N.; Baker, D. R.; Barnes, S.-J.

    2008-08-01

    Apatite is a cumulate phase in the upper parts of some mafic layered intrusions and anorthositic complexes. We investigated the effect of pressure and fluorine on apatite saturation in mafic magmas to better understand under which conditions this mineral crystallizes. Apatite saturation gives information about the formation of silicate rocks, and is of interest in explaining the formation of apatite-oxide-rich rocks (e.g. nelsonites comprising approximately, one-third apatite and two-third Fe-Ti oxide). Two models of formation are proposed for this rock type: crystal fractionation followed by accumulation of apatite and Fe-Ti oxides and liquid immiscibility. New experiments carried out with mafic compositions at 500 MPa confirm that the most important variables on phosphate saturation are SiO2 and CaO. Fluorine addition leads to apatite saturation at lower SiO2 and higher CaO concentrations. Comparison of our results with those of previous experimental studies on liquid-liquid immiscibility at upper-to-mid-crustal conditions allows us to investigate the relative importance of apatite saturation versus liquid-liquid immiscibility in the petrogenesis of nelsonites and similar rocks. The liquid line of descent of three natural examples studied (the Sept-Îles intrusive suite, the anorthositic Complex of the Lac-St-Jean and the Skaergaard layered intrusion) do not cross the liquid-liquid immiscibility field before they reach apatite saturation. Thus, the apatite-oxide-rich rock associated with these three intrusive suites are best explained by crystal fractionation followed by accumulation of apatite and Fe-Ti oxides.

  14. The capillary hysteresis model HYSTR: User`s guide

    Energy Technology Data Exchange (ETDEWEB)

    Niemi, A.; Bodvarsson, G.S.

    1991-11-01

    The potential disposal of nuclear waste in the unsaturated zone at Yucca Mountain, Nevada, has generated increased interest in the study of fluid flow through unsaturated media. In the near future, large-scale field tests will be conducted at the Yucca Mountain site, and work is now being done to design and analyze these tests. As part of these efforts a capillary hysteresis model has been developed. A computer program to calculate the hysteretic relationship between capillary pressure {phi} and liquid saturation (S{sub 1}) has been written that is designed to be easily incorporated into any numerical unsaturated flow simulator that computes capillary pressure as a function of liquid saturation. This report gives a detailed description of the model along with information on how it can be interfaced with a transport code. Although the model was developed specifically for calculations related to nuclear waste disposal, it should be applicable to any capillary hysteresis problem for which the secondary and higher order scanning curves can be approximated from the first order scanning curves. HYSTR is a set of subroutines to calculate capillary pressure for a given liquid saturation under hysteretic conditions.

  15. Phase equilibria and physical properties of CO2-saturated cocoa butter mixtures at elevated pressures

    NARCIS (Netherlands)

    Venter, M.J.; Willems, P.; Kareth, S.; Weidner, E.; Kuipers, N.J.M.; Haan, de A.B.

    2007-01-01

    The melting point and phase behaviour of cocoa butter under CO2 pressure were observed in a high-pressure view cell. The melting point decreases from 35 to 23 °C at CO2 pressures higher than 5 MPa. A static analytical procedure was used to measure the solubility of CO2 in cocoa butter at 40, 80 and

  16. Steam pressure induced in crack-like cavities in moisture saturated polymer matrix composities during rapid heating

    Energy Technology Data Exchange (ETDEWEB)

    Chung Yuen Hui; Muralidhharan, V. [Cornell Univ., Ithaca, NY (United States). Dept. of Theoretical and Applied Mechanics; Thompson, M.O. [Cornell Univ., Ithaca, NY (United States). Dept. of Material Science and Engineering

    2005-02-01

    The time history of steam pressure inside an isolated ''crack-like'' micro-cavity in a polymer matrix composite is studied by assuming that the chemical potential of water is continuous across the cavity/polymer interface. Steam pressure inside the cavity is due to rapid heating of moisture-saturated composites from its initial temperature to a final temperature T{sub f}. Exact closed form solutions are obtained for a ''crack-like'' cavity inside an infinite and a finite plate. For the case of an infinite plate, the exact solution shows that the steam pressure approaches the saturated steam pressure p{sub sat}(T{sub f}) at a characteristic time t{sub c}{approx_equal}25h{sup 2}/D{sub f}(M{sub w}p{sub sat}(T{sub f})/RT{sub f}{psi}{sub 0}){sup 2}, where h is the cavity height, D{sub f} is the diffusivity of water at T{sub f}, M{sub w} is the molecular weight of water, {psi}{sub 0} is the initial moisture concentration of the composite and R is the universal gas constant. When moisture is allowed to escape from the composite, such as in the case of a finite plate, the maximum steam pressure depends on a single dimensionless parameter {alpha}=LRT{sub f}{psi}{sub 0}/hM{sub w}p{sub sat}(T{sub f}), where L is the thickness of the composite plate. For large {alpha}, the maximum steam pressure approaches p{sub sat}(T{sub f}). However, the maximum steam pressure can be significantly less than p{sub sat}(T{sub f}) when {alpha} {<=} 4. The present model can also be used to study the 'popcorning' observed in electronic packages. (author)

  17. Effect of an oxygen pressure injection (OPI) device on the oxygen saturation of patients during dermatological methyl aminolevulinate photodynamic therapy.

    Science.gov (United States)

    Blake, E; Allen, J; Thorn, C; Shore, A; Curnow, A

    2013-05-01

    Methyl aminolevulinate photodynamic therapy (MAL-PDT) (a topical treatment used for a number of precancerous skin conditions) utilizes the combined interaction of a photosensitizer (protoporphyrin IX (PpIX)), light of the appropriate wavelength, and molecular oxygen to produce singlet oxygen and other reactive oxygen species which induce cell death. During treatment, localized oxygen depletion occurs and is thought to contribute to decreased efficacy. The aim of this study was to investigate whether an oxygen pressure injection (OPI) device had an effect on localized oxygen saturation levels and/or PpIX fluorescence of skin lesions during MAL-PDT. This study employed an OPI device to apply oxygen under pressure to the skin lesions of patients undergoing standard MAL-PDT. Optical reflectance spectrometry and fluorescence imaging were used to noninvasively monitor the localized oxygen saturation and PpIX fluorescence of the treatment area, respectively. No significant changes in oxygen saturation were observed when these data were combined for the group with OPI and compared to the group that received standard MAL-PDT without OPI. Additionally, no significant difference in PpIX photobleaching or clinical outcome at 3 months between the groups of patients was observed, although the group that received standard MAL-PDT demonstrated a significant increase (pMAL-PDT. Further investigation is therefore required to find a more effective method of MAL-PDT enhancement.

  18. Sensitivity analysis of effective fluid and rock bulk modulus due to changes in pore pressure, temperature and saturation

    Science.gov (United States)

    Bhakta, Tuhin; Avseth, Per; Landrø, Martin

    2016-12-01

    Fluid substitution plays a vital role in time-lapse seismic modeling and interpretation. It is, therefore, very important to quantify as exactly as possible the changes in fluid bulk modulus due to changes in reservoir parameters. In this paper, we analyze the sensitivities in effective fluid bulk modulus due to changes in reservoir parameters like saturation, pore-pressure and temperature. The sensitivities are analyzed for two extreme bounds, i.e. the Voigt average and the Reuss average, for various fluid combinations (i.e. oil-water, gas-water and gas-oil). We quantify that the effects of pore-pressure and saturation changes are highest in the case of gas-water combination, while the effect of temperature is highest for oil-gas combination. Our results show that sensitivities vary with the bounds, even for same amount of changes in any reservoir parameter. In 4D rock physics studies, we often neglect the effects of pore-pressure or temperature changes assuming that those effects are negligible compare to the effect due to saturation change. Our analysis shows that pore-pressure and temperature changes can be vital and sometimes higher than the effect of saturation change. We investigate these effects on saturated rock bulk modulus. We first compute frame bulk modulus using the Modified Hashin Shtrikman (MHS) model for carbonate rocks and then perform fluid substitution using the Gassmann equation. We consider upper bound of the MHS as elastic behavior for stiffer rocks and lower bound of the MHS as elastic behavior for softer rocks. We then investigate four various combinations: stiff rock with upper bound (the Voigt bound) as effective fluid modulus, stiff rock with lower bound (Reuss bound) as effective fluid modulus, soft rock with upper bound as effective fluid modulus and soft rock with lower bound as effective fluid modulus. Our results show that the effect of any reservoir parameter change is highest for soft rock and lower bound combination and lowest

  19. Study on the interrelated effects of capillary diameter, background electrolyte concentration, and flow rate in pressure assisted capillary electrophoresis with contactless conductivity detection.

    Science.gov (United States)

    Mai, Thanh Duc; Hauser, Peter C

    2013-06-01

    A detailed study on the effect of the buffer concentration and the magnitude of the superimposed hydrodynamic flow on separation performance in CZE with contactless conductivity detection was carried out with capillaries of 10, 25, and 50 μm internal diameter. It was confirmed that capillaries of narrow internal diameters require higher buffer concentrations for best sensitivities. For all diameters it was found that electrodispersion was the most pronounced band-broadening factor for relatively long residence times. For shorter times, Joule heating related band broadening appears to be the most significant factor, which means that best separation efficiencies are obtained with the narrowest capillaries. As detection limits are as good for capillaries of 10 μm internal diameters as for the other diameters when using contactless conductivity detection, these narrow capillaries are, therefore, generally of benefit when employing this detection technique. Hydrodyamic flow was found to have only a very limited effect on band broadening; an effect was only noticeable for the 50 μm capillary and relatively high flow rates.

  20. The effect of water saturation on methane breakthrough pressure: An experimental study on the Carboniferous shales from the eastern Qaidam Basin, China

    Science.gov (United States)

    Zhang, Cheng; Yu, Qingchun

    2016-12-01

    Breakthrough pressure plays an important role in shale gas flow, mining, and caprock evaluation. A series of breakthrough experiments were conducted under different water saturation conditions for four shales taken from the Carboniferous Hoit Taria Formation in the eastern Qaidam Basin, China to investigate the influence of water saturation on breakthrough pressure. Relevant geochemical tests (mineral composition, clay content, total organic carbon, thermal maturity and vitrinite reflectance) and micro structural characteristics of micro pores were also conducted. Breakthrough pressures under at least five different water saturations (from 0 to 100%) were obtained and relationship between breakthrough pressure and water saturation was fitted for each sample. We found that breakthrough pressure increases exponentially with water saturation. The decrease in effective pore diameter caused by both the bound water films and the swelling of the clay minerals resulted in the increase in the breakthrough pressure. After water saturation reached about 60%, breakthrough pressure increased rapidly from connectivity reduction, caused by the sealing off of smaller pores and partial water saturation of the macropores. By analyzing the correlation between breakthrough pressure and pore structure characteristics, breakthrough pressure is inversely related to porosity, and is primarily affected by macropores. Because macropores consist of many microfractures with lengths up to dozens of micrometers, they determine the porosity and then affect the connectivity of the rock. Correlation analysis between the mineral compositions and breakthrough pressure showed that TOC content exhibits a positive correlation with breakthrough pressure, but neither quartz content nor the clay mineral content exhibits a correlation. By combining this information with Field Emission Scanning Electron Microscope results, we found that microfractures are easily created where the TOC (total organic carbon

  1. MEASUREMENTS OF CAPILLARY PRESSURE-SATURATION RELATIONSHIPS AND DNAPL DISTRIBUTION IN SILICA SANDS USING LIGHT TRANSMISSION VISUALIZATION

    Science.gov (United States)

    This study is a part of an ongoing research project that aims at assessing the environmental benefits of partial DNAPL removal. The laboratory part of the research project is to examine the functional relationship between DNAPL (modeled by PCE) architecture, mass removal and cont...

  2. Mechanisms for Induction of Pulmonary Capillary Hemorrhage by Diagnostic Ultrasound: Review and Consideration of Acoustical Radiation Surface Pressure.

    Science.gov (United States)

    Miller, Douglas L

    2016-12-01

    Diagnostic ultrasound can induce pulmonary capillary hemorrhage (PCH) in rats and other mammals. This phenomenon represents the only clearly demonstrated biological effect of (non-contrast enhanced) diagnostic ultrasound and thus presents a uniquely important safety issue. However, the physical mechanism responsible for PCH remains uncertain more than 25 y after its discovery. Experimental research has indicated that neither heating nor acoustic cavitation, the predominant mechanisms for bioeffects of ultrasound, is responsible for PCH. Furthermore, proposed theoretical mechanisms based on gas-body activation, on alveolar resonance and on impulsive generation of liquid droplets all appear unlikely to be responsible for PCH, owing to unrealistic model assumptions. Here, a simple model based on the acoustical radiation surface pressure (ARSP) at a tissue-air interface is hypothesized as the mechanism for PCH. The ARSP model seems to explain some features of PCH, including the approximate frequency independence of PCH thresholds and the dependence of thresholds on biological factors. However, ARSP evaluated for experimental threshold conditions appear to be too weak to fully account for stress failure of pulmonary capillaries, gauging by known stresses for injurious physiologic conditions. Furthermore, consideration of bulk properties of lung tissue suggests substantial transmission of ultrasound through the pleura, with reduced ARSP and potential involvement of additional mechanisms within the pulmonary interior. Although these recent findings advance our knowledge, only a full understanding of PCH mechanisms will allow development of science-based safety assurance for pulmonary ultrasound.

  3. Determination of N-Methylcarbamate Pesticides in Vegetables by Solid-phase Extraction and Pressurized Capillary Electrochromatography

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ Introduction Capillary electrochromatography(CEC) is a hybrid technique that couples the good selectivity of high-performance liquid chromatography ( HPLC ) and the high separation efficiency of capillary electrophoresis (CE).

  4. CO(2) partial pressure and calcite saturation in springs - useful data for identifying infiltration areas in mountainous environments.

    Science.gov (United States)

    Hilberg, Sylke; Brandstätter, Jennifer; Glück, Daniel

    2013-04-01

    Mountainous regions such as the Central European Alps host considerable karstified or fractured groundwater bodies, which meet many of the demands concerning drinking water supply, hydropower or agriculture. Alpine hydrogeologists are required to describe the dynamics in fractured aquifers in order to assess potential impacts of human activities on water budget and quality. Delineation of catchment areas by means of stable isotopes and hydrochemical data is a well established method in alpine hydrogeology. To achieve reliable results, time series of (at least) one year and spatial and temporal close-meshed data are necessary. In reality, test sites in mountainous regions are often inaccessible due to the danger of avalanches in winter. The aim of our work was to assess a method based on the processes within the carbonic acid system to delineate infiltration areas by means of single datasets consisting of the main hydrochemical parameters of each spring. In three geologically different mountainous environments we managed to classify the investigated springs into four groups. (1) High PCO2 combined with slight super-saturation in calcite, indicating relatively low infiltration areas. (2) Low PCO2 near atmospheric conditions in combination with calcite saturation, which is indicative of relatively high infiltration areas and a fractured aquifer which is not covered by topsoil layers. (3) High PCO2 in combination with sub-saturation in calcite, representing a shallow aquifer with a significant influence of the topsoil layer. (4) The fourth group of waters is characterized by low PCO2 and sub-saturation in calcite, which is interpreted as evidence for a shallow aquifer without significant influence of any hard rock aquifer or topsoil layer. This study shows that CO2-partial pressure can be an ideal natural tracer to estimate the elevation of infiltration areas, especially in non-karstified fractured groundwater bodies.

  5. Kinetics of hydrothermal crystallization under saturated steam pressure and the self-healing effect by nanocrystallite for hydroxyapatite coatings.

    Science.gov (United States)

    Yang, Chung-Wei; Lui, Truan-Sheng

    2009-09-01

    Hydroxyapatite coatings (HACs) with a low crystalline state were prepared using the plasma spraying process followed by hermetic autoclaving hydrothermal treatment at 100, 150 and 200 degrees C. Experimental evidence confirmed that the HACs became significantly crystallized and the content of amorphous calcium phosphate decreased by performing the autoclaving hydrothermal treatment in an ambient saturated steam pressure system. The obvious chemisorbed hydroxy groups (OH) peak in the X-ray photoelectron spectra detected from the hydrothermally crystallized HAC specimens means that the hydroxyl-deficient state of plasma-sprayed HACs is significantly improved by the abundant replenished OH groups. The HA nanocrystallite observed from scanning electron microscopy and transmission electron microscopy images within hydrothermally treated HACs is the result of nucleation and grain growth through the replenishment of OH groups into the hydroxyl-deficient HA crystal structure. The microstructural self-healing effect is a result of reduction in defects (pores, microcracks and lamellar boundaries) due to new-growth HA nanocrystallite. According to the systematic derivation of the Arrhenius equation, the HA crystallization is a second-order Arrhenius reaction kinetics. Besides the effects of heating temperature and an atmosphere with abundant water molecules, the saturated steam pressure is a crucial factor which significantly improves the crystallization rate constant and further reduces the activation energy for the hydrothermal HA crystallization.

  6. Determining Fuel Losses in Storage Tanks Based on Factual Saturation Pressures

    Science.gov (United States)

    Levitin, R. E.; Tryascin, R. A.

    2016-10-01

    At present, evaluation of fuel evaporative losses is based on a number of indirect parameters. Accuracy of such methods leaves much to be desired. The paper presents a method developed following the author's laboratory tests. An effective operation range of pressure vent valves in various tanks is provided, as well as low A92 gasoline losses for horizontal steel tanks at all operation temperatures.

  7. The generation of gravity-capillary solitary waves by a pressure source moving at a trans-critical speed

    Science.gov (United States)

    Masnadi, Naeem; Duncan, James H.

    2017-01-01

    The unsteady response of a water free surface to a localized pressure source moving at constant speed $U$ in the range $0.95c_\\mathrm{min} \\lesssim U \\leq 1.02 c_\\mathrm{min}$, where $c_\\mathrm{min}$ is the minimum phase speed of linear gravity-capillary waves in deep water, is investigated through experiments and numerical simulations. This unsteady response state, which consists of a V-shaped pattern behind the source and features periodic shedding of pairs of depressions from the tips of the V, was first observed qualitatively by Diorio et al. (Phys. Rev. Let., 103, 214502, 2009) and called state III. In the present investigation, cinematic shadowgraph and refraction-based techniques are utilized to measure the temporal evolution of the free surface deformation pattern downstream of the source as it moves along a towing tank, while numerical simulations of the model equation described by Cho et al. (J. Fluid Mech., 672, 288-306, 2011) are used to extend the experimental results over longer times than are possible in the experiments. From the experiments, it is found that the speed-amplitude characteristics and the shape of the depressions are nearly the same as those of the freely propagating gravity-capillary lumps of inviscid potential theory. The decay rate of the depressions is measured from their height-time characteristics, which are well fitted by an exponential decay law with an order 1 decay constant. It is found that the shedding period of the depression pairs decreases with increasing source strength and speed. As the source speed approaches $c_\\mathrm{min}$, this period tends to about 1~s for all source magnitudes. At the low-speed boundary of state III, a new response with unsteady asymmetric shedding of depressions is found. This response is also predicted by the model equation.

  8. A novel technique to predict pulmonary capillary wedge pressure utilizing central venous pressure and tissue Doppler tricuspid/mitral annular velocities.

    Science.gov (United States)

    Uemura, Kazunori; Inagaki, Masashi; Zheng, Can; Li, Meihua; Kawada, Toru; Sugimachi, Masaru

    2015-07-01

    Assessing left ventricular (LV) filling pressure (pulmonary capillary wedge pressure, PCWP) is an important aspect in the care of patients with heart failure (HF). Physicians rely on right ventricular (RV) filling pressures such as central venous pressure (CVP) to predict PCWP, assuming concordance between CVP and PCWP. However, the use of this method is limited because discordance between CVP and PCWP is observed. We hypothesized that PCWP can be reliably predicted by CVP corrected by the relationship between RV and LV function, provided by the ratio of tissue Doppler peak systolic velocity of tricuspid annulus (S(T)) to that of mitral annulus (S(M)) (corrected CVP:CVP·S(T)/S(M)). In 16 anesthetized closed-chest dogs, S T and S M were measured by transthoracic tissue Doppler echocardiography. PCWP was varied over a wide range (1.8-40.0 mmHg) under normal condition and various types of acute and chronic HF. A significantly stronger linear correlation was observed between CVP·S(T)/S(M) and PCWP (R2 = 0.78) than between CVP and PCWP (R2 = 0.22) (P 10.5 mmHg predicted PCWP >18 mmHg with 85% sensitivity and 88% specificity. Area under ROC curve for CVP·S T/S M to predict PCWP >18 mmHg was 0.93, which was significantly larger than that for CVP (0.66) (P < 0.01). Peripheral venous pressure (PVP) corrected by S T/S M (PVP·S(T)/S(M) also predicted PCWP reasonably well, suggesting that PVP·S(T)/S (M) may be a minimally invasive alternative to CVP·S(T)/S(M) In conclusion, our technique is potentially useful for the reliable prediction of PCWP in HF patients.

  9. Effects of Capillary Pressure on Multiphase Flow during CO2 Injection in Saline Aquifer

    Directory of Open Access Journals (Sweden)

    Pau J.S.

    2014-07-01

    Full Text Available This paper focused on supercritical CO2 injection into saline aquifer, in particular its capillarity’s effects on the plume migration, reservoir pressure alteration and CO2 flux density. The numerical method used to solve the incompressible two-phase flow equations is based on the mimetic method, which conserves the mass and fluxes simultaneously. The investigation showed that exclusion of capillarity can greatly underestimate the CO2 plume migration and resulted in distinctive reservoir pressure distribution. It is found that capillarity showed no significant effect on the flux intensity of CO2.

  10. Capillary electrophoresis-atmospheric pressure chemical ionization-mass spectrometry using an orthogonal interface: set-up and system parameters.

    Science.gov (United States)

    Hommerson, Paul; Khan, Amjad M; de Jong, Gerhardus J; Somsen, Govert W

    2009-07-01

    The feasibility of atmospheric pressure chemical ionization (APCI) as an alternative ionization technique for capillary electrophoresis-mass spectrometry (CE-MS) was investigated using a grounded sheath-flow CE-MS sprayer and an orthogonal APCI source. Infusion experiments indicated that highest analyte signals were achieved when the sprayer tip was in close vicinity of the vaporizer entrance. The APCI-MS set-up enabled detection of basic, neutral, and acidic compounds, whereas apolar and ionic compounds could not be detected. In the positive ion mode, analytes could be detected in the entire transfer voltage range (0-5 kV), whereas highest signal intensities were observed when the corona discharge current was between 1000 and 2000 nA. In the negative ion mode, the transfer voltage typically was 500 V and the optimum corona discharge current was 6000 nA. Analyte signals were raised with increasing nebulizing gas pressure, but the pressure was limited to 25 psi to avoid siphoning and current drops. Signal intensities appeared to be optimal and constant over a wide range of sheath liquid flow rate (5-25 microL/min) and vaporizer temperature (200-350 degrees C). APCI-MS signals were unaffected by the composition of the background electrolyte (BGE), even when it contained sodium phosphate and sodium dodecyl sulfate (SDS). Consequently, BGE composition, sheath-liquid flow rate, and vaporizer temperature can be optimized with respect to the CE separation without affecting the APCI-MS response. The analysis of a mixture of basic compounds and a steroid using volatile and nonvolatile BGEs further demonstrates the feasibility of CE-APCI-MS. Detection limits (S/N = 3) were 1.6-10 microM injected concentrations.

  11. Multiphase Transport in Porous Media: Gas-Liquid Separation Using Capillary Pressure Gradients International Space Station (ISS) Flight Experiment Development

    Science.gov (United States)

    Wheeler, Richard R., Jr.; Holtsnider, John T.; Dahl, Roger W.; Deeks, Dalton; Javanovic, Goran N.; Parker, James M.; Ehlert, Jim

    2013-01-01

    Advances in the understanding of multiphase flow characteristics under variable gravity conditions will ultimately lead to improved and as of yet unknown process designs for advanced space missions. Such novel processes will be of paramount importance to the success of future manned space exploration as we venture into our solar system and beyond. In addition, because of the ubiquitous nature and vital importance of biological and environmental processes involving airwater mixtures, knowledge gained about fundamental interactions and the governing properties of these mixtures will clearly benefit the quality of life here on our home planet. The techniques addressed in the current research involving multiphase transport in porous media and gas-liquid phase separation using capillary pressure gradients are also a logical candidate for a future International Space Station (ISS) flight experiment. Importantly, the novel and potentially very accurate Lattice-Boltzmann (LB) modeling of multiphase transport in porous media developed in this work offers significantly improved predictions of real world fluid physics phenomena, thereby promoting advanced process designs for both space and terrestrial applications.This 3-year research effort has culminated in the design and testing of a zero-g demonstration prototype. Both the hydrophilic (glass) and hydrophobic (Teflon) media Capillary Pressure Gradient (CPG) cartridges prepared during the second years work were evaluated. Results obtained from ground testing at 1-g were compared to those obtained at reduced gravities spanning Martian (13-g), Lunar (16-g) and zero-g. These comparisons clearly demonstrate the relative strength of the CPG phenomena and the efficacy of its application to meet NASAs unique gas-liquid separation (GLS) requirements in non-terrestrial environments.LB modeling software, developed concurrently with the zero-g test effort, was shown to accurately reproduce observed CPG driven gas-liquid separation

  12. Memory Effects on Nonlinear Temperature and Pressure Wave Propagation in the Boundary between Two Fluid-Saturated Porous Rocks

    Directory of Open Access Journals (Sweden)

    R. Garra

    2015-01-01

    Full Text Available The evolution of strong transients of temperature and pressure in two adjacent fluid-saturated porous rocks is described by a Burgers equation in an early model of Natale and Salusti (1996. We here consider the effect of a realistic intermediate region between the two media and infer how transient processes can also happen, such as chemical reactions, diffusion of fine particles, and filter cake formations. This suggests enlarging our analysis and taking into account not only punctual quantities but also “time averaged” quantities. These boundary effects are here analyzed by using a “memory formalism”; that is, we replace the ordinary punctual time-derivatives with Caputo fractional time-derivatives. We therefore obtain a nonlinear fractional model, whose explicit solution is shown, and finally discuss its geological importance.

  13. Condensation heat transfer and pressure drop of R-134a saturated vapour inside a brazed compact plate fin heat exchanger with serrated fin

    Science.gov (United States)

    Ramana Murthy, K. V.; Ranganayakulu, C.; Ashok Babu, T. P.

    2017-01-01

    This paper presents the experimental heat transfer coefficient and pressure drop measured during R-134a saturated vapour condensation inside a small brazed compact plate fin heat exchanger with serrated fin surface. The effects of saturation temperature (pressure), refrigerant mass flux, refrigerant heat flux, effect of fin surface characteristics and fluid properties are investigated. The average condensation heat transfer coefficients and frictional pressure drops were determined experimentally for refrigerant R-134a at five different saturated temperatures (34, 38, 40, 42 and 44 °C). A transition point between gravity controlled and forced convection condensation has been found for a refrigerant mass flux around 22 kg/m2s. In the forced convection condensation region, the heat transfer coefficients show a three times increase and 1.5 times increase in frictional pressure drop for a doubling of the refrigerant mass flux. The heat transfer coefficients show weak sensitivity to saturation temperature (Pressure) and great sensitivity to refrigerant mass flux and fluid properties. The frictional pressure drop shows a linear dependence on the kinetic energy per unit volume of the refrigerant flow. Correlations are provided for the measured heat transfer coefficients and frictional pressure drops.

  14. Glycemic control influences lung membrane diffusion and oxygen saturation in exercise-trained subjects with type 1 diabetes: alveolar-capillary membrane conductance in type 1 diabetes.

    Science.gov (United States)

    Wheatley, Courtney M; Baldi, James C; Cassuto, Nicholas A; Foxx-Lupo, William T; Snyder, Eric M

    2011-03-01

    Lung diffusing capacity (DLCO) is influenced by alveolar-capillary membrane conductance (D (M)) and pulmonary capillary blood volume (V (C)), both of which can be impaired in sedentary type 1 diabetes mellitus (T1DM) subjects due to hyperglycemia. We sought to determine if T1DM, and glycemic control, affected DLNO, DLCO, D (M), V (C) and SaO(2) during maximal exercise in aerobically fit T1DM subjects. We recruited 12 T1DM subjects and 18 non-diabetic subjects measuring DLNO, DLCO, D (M), and V (C) along with SaO(2) and cardiac output (Q) at peak exercise. The T1DM subjects had significantly lower DLCO/Q and D (M)/Q with no difference in Q, DLNO, DLCO, D (M), or V (C) (DLCO/Q = 2.1 ± 0.4 vs. 1.7 ± 0.3, D (M)/Q = 2.8 ± 0.6 vs. 2.4 ± 0.5, non-diabetic and T1DM, p diffusing capacity in aerobically fit athletes with T1DM at peak exercise, but suggests that maintaining near-normoglycemia potentially averts lung diffusion impairments.

  15. Theoretical Analysis of the Pressure Oscillation Phenomena in Capillary Pumped Loop

    Institute of Scientific and Technical Information of China (English)

    ZhangJiaxun; HouZengqi; 等

    1998-01-01

    Based on the physical model of caplillary pumped loop(CPL)system,the phenomena of pressure oscillation are simplified and analyzed.From a set of non-linear differential equations,the influence of ststem parameters on the performance of the CPL is discussed,including the working temperature (the set point),loop resistance,vapor volume etc.From the analysis,some measures were taken to improve the performance of the loop,Meanwhile ,the reason why the deprive of the CPL occurs during the operation is given by analyzing the theoretical calculation results.

  16. Differential equations governing slip-induced pore-pressure fluctuations in a water-saturated granular medium

    Science.gov (United States)

    Iverson, R.M.

    1993-01-01

    Macroscopic frictional slip in water-saturated granular media occurs commonly during landsliding, surface faulting, and intense bedload transport. A mathematical model of dynamic pore-pressure fluctuations that accompany and influence such sliding is derived here by both inductive and deductive methods. The inductive derivation shows how the governing differential equations represent the physics of the steadily sliding array of cylindrical fiberglass rods investigated experimentally by Iverson and LaHusen (1989). The deductive derivation shows how the same equations result from a novel application of Biot's (1956) dynamic mixture theory to macroscopic deformation. The model consists of two linear differential equations and five initial and boundary conditions that govern solid displacements and pore-water pressures. Solid displacements and water pressures are strongly coupled, in part through a boundary condition that ensures mass conservation during irreversible pore deformation that occurs along the bumpy slip surface. Feedback between this deformation and the pore-pressure field may yield complex system responses. The dual derivations of the model help explicate key assumptions. For example, the model requires that the dimensionless parameter B, defined here through normalization of Biot's equations, is much larger than one. This indicates that solid-fluid coupling forces are dominated by viscous rather than inertial effects. A tabulation of physical and kinematic variables for the rod-array experiments of Iverson and LaHusen and for various geologic phenomena shows that the model assumptions commonly are satisfied. A subsequent paper will describe model tests against experimental data. ?? 1993 International Association for Mathematical Geology.

  17. The Generation of Gravity-Capillary Solitary Waves by a Pressure Source Moving at a Trans-critical Speed

    CERN Document Server

    Masnadi, Naeem

    2016-01-01

    The unsteady response of a water free surface to a localized pressure source moving at constant speed $U$ in the range $0.95c_\\mathrm{min} \\lesssim U \\leq 1.02 c_\\mathrm{min}$, where $c_\\mathrm{min}$ is the minimum phase speed of linear gravity-capillary waves in deep water, is investigated through experiments and numerical simulations. This unsteady response state, which consists of a V-shaped pattern behind the source and features periodic shedding of pairs of depressions from the tips of the V, was first observed qualitatively by Diorio et al. (Phys. Rev. Let., 103, 214502, 2009) and called state III. In the present investigation, cinematic shadowgraph and refraction-based techniques are utilized to measure the temporal evolution of the free surface deformation pattern downstream of the source as it moves along a towing tank, while numerical simulations using the model equation proposed by Cho et al. (J. Fluid Mech., 672, 288-306, 2011) are used to extend the experimental results over longer times than are...

  18. Correlation of retention times on liquid crystal capillary column with reported vapor pressures and half-lives of compounds used in pheromone formulations.

    Science.gov (United States)

    Heath, R R; Tumlinson, J H

    1986-11-01

    A method has been developed to determine by capillary gas chromatography on liquid crystal stationary phases the relative vapor pressures and half-lives of many compounds used as insect pheromones. This study demonstrated that the retention time of seven acetates on a liquid crystal column (cholesteryl-p-chlorocinnamate) could be correlated closely to the reported vapor pressures of the compounds. For 13 additional pheromonal acetates and alcohols, reported half-lives showed a high degree of correlation with their retention times on the liquid crystal column. Thus chromatography on capillary liquid crystal gas Chromatographie columns appears to be a useful method for determining the relative volatilities of many pheromones to facilitate the development of more precise formulations.

  19. Impaired training-induced adaptation of blood pressure in COPD patients: implication of the muscle capillary bed

    Directory of Open Access Journals (Sweden)

    Gouzi F

    2016-09-01

    Full Text Available Fares Gouzi,1,2 Jonathan Maury,1,3 François Bughin,1,2 Marine Blaquière,1,2 Bronia Ayoub,1,2 Jacques Mercier,1,2 Antonia Perez-Martin,4,5 Pascal Pomiès,1 Maurice Hayot1,2 1PhyMedExp, INSERM U1046, CNRS UMR 9214, University of Montpellier, 2Department of Clinical Physiology, Montpellier University Hospital, Montpellier, 3Pulmonary Rehabilitation Center “La Solane”, 5 Santé Group, Osséja, 4Dysfunction of Vascular Interfaces Laboratory, EA 2992, University of Montpellier, 5Department of Vascular Medicine and Investigations, Nîmes University Hospital, Nîmes, France Background and aims: Targeting the early mechanisms in exercise-induced arterial hypertension (which precedes resting arterial hypertension in its natural history may improve cardiovascular morbidity and mortality in COPD patients. Capillary rarefaction, an early event in COPD before vascular remodeling, is a potential mechanism of exercise-induced and resting arterial hypertension. Impaired training-induced capillarization was observed earlier in COPD patients; thus, this study compares the changes in blood pressure (BP during exercise in COPD patients and matches control subjects (CSs after a similar exercise training program, in relationship with muscle capillarization. Methods: Resting and maximal exercise diastolic pressure (DP and systolic pressure (SP were recorded during a standardized cardiopulmonary exercise test, and a quadriceps muscle biopsy was performed before and after training.Results: A total of 35 CSs and 49 COPD patients (forced expiratory volume in 1 second=54%±22% predicted completed a 6-week rehabilitation program and improved their symptom-limited maximal oxygen uptake (VO2SL: 25.8±6.1 mL/kg per minute vs 27.9 mL/kg per minute and 17.0±4.7 mL/kg per minute vs 18.3 mL/kg per minute; both P<0.001. The improvement in muscle capillary-to-fiber (C/F ratio was significantly greater in CSs vs COPD patients (+11%±9% vs +23%±21%; P<0.05. Although maximal

  20. Direct measurement of relative permeability in rocks from unsteady-state saturation profiles

    Science.gov (United States)

    Kianinejad, Amir; Chen, Xiongyu; DiCarlo, David A.

    2016-08-01

    We develop a method to measure liquid relative permeability in rocks directly from transient in situ saturation profiles during gravity drainage experiments. Previously, similar methods have been used for sandpacks; here, this method is extended to rocks by applying a slight overpressure of gas at the inlet. Relative permeabilities are obtained in a 60 cm long vertical Berea sandstone core during gravity drainage, directly from the measured unsteady-state in situ saturations along the core at different times. It is shown that for obtaining relative permeability using this method, if certain criteria are met, the capillary pressure of the rock can be neglected. However, it is essential to use a correct gas pressure gradient along the core. This involves incorporating the pressure drop at the outlet of the core due to capillary discontinuity effects. The method developed in this work obtains relative permeabilities in unsteady-state fashion over a wide range of saturations quickly and accurately.

  1. Saturated fluorescence measurements of the hydroxyl radical in laminar high-pressure C2H6/O2/N2 flames

    Science.gov (United States)

    Carter, Campbell D.; King, Galen B.; Laurendeau, Normand M.

    1992-01-01

    Saturation of a transition of the OH molecule in high-pressure flames is demonstrated by obtaining saturation curves in C2H6/O2/N2 laminar flames at 1, 6.1, 9.2, and 12.3 atm. Quantitative fluorescence measurements of OH number density at pressures to 12.3 atm are presented. To assess the efficacy of the balanced cross-rate model for high-pressure flames, laser-saturated fluorescence measurements, which were calibrated in an atmospheric-pressure flame, are compared with absorption measurements at 3.1 and 6.1 atm. At 3.1 atm the absorption and fluorescence measurements compare well. At 6.1 atm, however, the concentrations given by lasre-saturated fluorescence are about 25 percent lower than the absorption values, indicating some depletion of the laser-coupled levels beyond that at atmospheric pressure. By using a reasonable estimate for the finite sensitivity to quenching, it is anticipated that fluorescence measurements that are calibrated at 1 atm can be applied to flames at about 10 atm with absolute errors within +/- 50 percent.

  2. Experimental, in-situ carbon solution mechanisms and isotope fractionation in and between (C-O-H)-saturated silicate melt and silicate-saturated (C-O-H) fluid to upper mantle temperatures and pressures

    Science.gov (United States)

    Mysen, Bjorn

    2017-02-01

    Our understanding of materials transport processes in the Earth relies on characterizing the behavior of fluid and melt in silicate-(C-O-H) systems at high temperature and pressure. Here, Raman spectroscopy was employed to determine structure of and carbon isotope partitioning between melts and fluids in alkali aluminosilicate-C-O-H systems. The experimental data were recorded in-situ while the samples were at equilibrium in a hydrothermal diamond anvil cell at temperatures and pressures to 825 °C and >1300 MPa, respectively. The carbon solution equilibrium in both (C-O-H)-saturated melt and coexisting, silicate-saturated (C-O-H) fluid is 2CO3 + H2O + 2Qn + 1 = 2HCO3 + 2Qn. In the Qn-notation, the superscript, n, is the number of bridging oxygen in silicate structural units. At least one oxygen in CO3 and HCO3 groups likely is shared with silicate tetrahedra. The structural behavior of volatile components described with this equilibrium governs carbon isotope fractionation factors between melt and fluid. For example, the ΔH equals 3.2 ± 0.7 kJ/mol for the bulk 13C/12C exchange equilibrium between fluid and melt. From these experimental data, it is suggested that at deep crustal and upper mantle temperatures and pressures, the δ13C-differences between coexisting silicate-saturated (C-O-H) fluid and (C-O-H)-saturated silicate melts may change by more than 100‰ as a function of temperature in the range of magmatic processes. Absent information on temperature and pressure, the use of carbon isotopes of mantle-derived magma to derive isotopic composition of magma source regions in the Earth's interior, therefore, should be exercised with care.

  3. A two-dimensional model of the pressing section of a paper machine including dynamic capillary effects

    KAUST Repository

    Iliev, Oleg P.

    2013-05-15

    Paper production is a problem with significant importance for society; it is also a challenging topic for scientific investigation. This study is concerned with the simulation of the pressing section of a paper machine. A two-dimensional model is developed to account for the water flow within the pressing zone. A Richards-type equation is used to describe the flow in the unsaturated zone. The dynamic capillary pressure-saturation relation is adopted for the paper production process. The mathematical model accounts for the coexistence of saturated and unsaturated zones in a multilayer computational domain. The discretization is performed by the MPFA-O method. Numerical experiments are carried out for parameters that are typical of the production process. The static and dynamic capillary pressure-saturation relations are tested to evaluate the influence of the dynamic capillary effect. © 2013 Springer Science+Business Media Dordrecht.

  4. A comparison of ground and satellite observations of cloud cover to saturation pressure differences during a cold air outbreak

    Energy Technology Data Exchange (ETDEWEB)

    Alliss, R.J.; Raman, S. [North Carolina State Univ., Raleigh, NC (United States)

    1996-04-01

    The role of clouds in the atmospheric general circulation and the global climate is twofold. First, clouds owe their origin to large-scale dynamical forcing, radiative cooling in the atmosphere, and turbulent transfer at the surface. In addition, they provide one of the most important mechanisms for the vertical redistribution of momentum and sensible and latent heat for the large scale, and they influence the coupling between the atmosphere and the surface as well as the radiative and dynamical-hydrological balance. In existing diagnostic cloudiness parameterization schemes, relative humidity is the most frequently used variable for estimating total cloud amount or stratiform cloud amount. However, the prediction of relative humidity in general circulation models (GCMs) is usually poor. Even for the most comprehensive GCMs, the predicted relative humidity may deviate greatly from that observed, as far as the frequency distribution of relative humidity is concerned. Recently, there has been an increased effort to improve the representation of clouds and cloud-radiation feedback in GCMs, but the verification of cloudiness parameterization schemes remains a severe problem because of the lack of observational data sets. In this study, saturation pressure differences (as opposed to relative humidity) and satellite-derived cloud heights and amounts are compared with ground determinations of cloud cover over the Gulf Stream Locale (GSL) during a cold air outbreak.

  5. DETERMINATION OF SATURATION VAPOR PRESSURE OF LOW VOLATILE SUBSTANCES THROUGH THE STUDY OF EVAPORATION RATE BY THERMOGRAVIMETRIC ANALYSIS

    Directory of Open Access Journals (Sweden)

    R. V. Ralys

    2015-11-01

    Full Text Available Subject of Study.Research of vapor pressure of low volatile substances is a complicated problem due to both direct experimental implementation complexity and, most significantly, the issues faced correctness of the analysis and processing of experimental data. That is why it is usually required engaging the reference substances (with vapor pressures well studied. The latter drastically reduces the effectiveness of the experimental methods used and narrows their applicability. The paper deals with an approach to the evaporation process description (sublimation of low volatile substances based on molecular kinetic description in view of diffusive and convection processes. The proposed approach relies on experimental thermogravimetricfindingsina wide range of temperatures, flow rates ofthe purge gas and time. Method. A new approach is based on the calculation of the vapor pressure and uses the data about the speed of evaporation by thermogravimetric analysis depending on the temperature, the flow rate of the purge gas, and the evaporation time. The basis for calculation is the diffusion-kinetic description of the process of evaporation (mass loss of the substance from the exposed surface. The method is applicable to determine the thermodynamic characteristics for both the evaporation (the equilibrium liquid - vapor and sublimation (the equilibrium solid - vapor. We proposed the appropriate method of the experiment and analysis of its data in order to find the saturated vapor pressure of individual substances of low volatility. Main Results. The method has been tested on substances with insufficiently reliable and complete study of the thermodynamic characteristics but, despite this, are often used (because of the other data limitations as reference ones. The vaporization process (liquid-vapor has been studied for di-n-butyl phthalate C16H22O4 at 323,15–443,15 К, and sublimation for benzoic acid C7H6O2at 303,15–183,15 К. Both processes have

  6. A Review of Methods to Calculate Relative Permeability Curve by Using Capillary Pressure Curve%用毛细管压力曲线计算相对渗透率曲线的方法综述

    Institute of Scientific and Technical Information of China (English)

    唐永强; 吕成远; 侯吉瑞

    2015-01-01

    相对渗透率曲线对研究地下流体的渗流规律及驱替特征具有重要的意义。利用毛细管压力与饱和度的关系来计算相渗曲线的方法进行了综述。叙述了相渗曲线的计算原理,及引入分形理论的原理。按照公式相似性及继承关系,分组介绍了毛细管压力法的研究历程,及主要研究成果。认为提出Kr-S关系来简化算法和分形理论的引入,推动毛细管压力法的发展;认为各方法没有优劣之分,只是适应性不同;利用特定的实验数据,对各方法的优劣进行评价,本身有一定的局限性。据此将毛细管压力法分为三个时期。通过对比评价各方法的特点及相互关系,阐释算法发展规律。最后提出毛细管压力将有三个主要发展方向:①测定非常规储层的相对渗透率曲线;②测定特殊流体的相对渗透率曲线;③与其他岩心检测手段相结合来检测岩心。希望对今后的研究起到参考的作用。%The relative permeability is important for researching seepage fluid mechanics and driving character-istics. The emphasis of this review is methods to calculate relative permeability curves by using the relationship be-tween capillary pressure and saturation. The pressure-saturation relationship and fractal theory are considered as a key technology to push the development of the methods. According to the introduction of the fractal theory, the methods were divided into two categories. The principle to calculate relative permeability curve and the principle of fractal theory were described. The research history and current situation of methods to calculate relative permeabili-ty by using capillary pressure were introduced, which includes the main outcomes of the researchers. Finally, three main directions of the capillary pressure had been pointed out:①determination of the relative permeability curves to unconventional reservoirs;② the determination of

  7. Superfast non-linear diffusion: Capillary transport in particulate porous media

    CERN Document Server

    Lukyanov, A V; Baines, M J; Theofanous, T G

    2013-01-01

    The migration of liquids in porous media, such as sand, has been commonly considered at high saturation levels with liquid pathways at pore dimensions. In this letter we reveal a low saturation regime observed in our experiments with droplets of extremely low volatility liquids deposited on sand. In this regime the liquid is mostly found within the grain surface roughness and in the capillary bridges formed at the contacts between the grains. The bridges act as variable-volume reservoirs and the flow is driven by the capillary pressure arising at the wetting front according to the roughness length scales. We propose that this migration (spreading) is the result of interplay between the bridge volume adjustment to this pressure distribution and viscous losses of a creeping flow within the roughness. The net macroscopic result is a special case of non-linear diffusion described by a superfast diffusion equation (SFDE) for saturation with distinctive mathematical character. We obtain solutions to a moving bounda...

  8. Capillary sample

    Science.gov (United States)

    ... several times a day using capillary blood sampling. Disadvantages to capillary blood sampling include: Only a limited ... do not constitute endorsements of those other sites. Copyright 1997-2017, A.D.A.M., Inc. Duplication ...

  9. Pressure-assisted electrokinetic injection for on-line enrichment in capillary electrophoresis-mass spectrometry: a sensitive method for measurement of ten haloacetic acids in drinking water.

    Science.gov (United States)

    Zhang, Huijuan; Zhu, Jiping; Aranda-Rodriguez, Rocio; Feng, Yong-Lai

    2011-11-07

    Haloacetic acids (HAAs) are by-products of the chlorination of drinking water containing natural organic matter and bromide. A simple and sensitive method has been developed for determination of ten HAAs in drinking water. The pressure-assisted electrokinetic injection (PAEKI), an on-line enrichment technique, was employed to introduce the sample into a capillary electrophoresis (CE)-electrospray ionization-tandem mass spectrometry system (ESI-MS/MS). HAAs were monitored in selected reaction monitoring mode. With 3 min of PAEKI time, the ten major HAAs (HAA10) in drinking water were enriched up to 20,000-fold into the capillary without compromising resolution. A simple solid phase clean-up method has been developed to eliminate the influence of ionic matrices from drinking water on PAEKI. Under conditions optimized for mass spectrometry, PAEKI and capillary electrophoresis, detection limits defined as three times ratio of signal to noise have been achieved in a range of 0.013-0.12 μg L(-1) for ten HAAs in water sample. The overall recoveries for all ten HAAs in drinking water samples were between 76 and 125%. Six HAAs including monochloro- (MCAA), dichloro- (DCAA), trichloro- (TCAA), monobromo- (MBAA), bromochloro- (BCAA), and bromodichloroacetic acids (BDCAA) were found in tap water samples collected.

  10. On the response of a water surface to a surface pressure source moving at trans-critical gravity-capillary wave speeds

    Science.gov (United States)

    Masnadi, Naeem; Cho, Yeunwoo; Duncan, James H.; Akylas, Triantaphyllos

    2015-11-01

    The non-linear response of a water free surface to a pressure source moving at speeds near the minimum speed of linear gravity-capillary waves (Cmin ~ 23 cm/s) is investigated with experiments and theory. In the experiments, waves are generated by a vertically oriented air-jet that moves at a constant speed over the water surface in a long tank. The 3-D surface shape behind the air-jet is measured using a cinematic refraction-based technique combined with an LIF technique. At towing speeds just below Cmin, an unsteady pattern is formed where localized depressions periodically appear in pairs and move away from the source along the arms of a downstream V-shaped pattern. This behavior is analogous to the periodic shedding of solitary waves upstream of a source moving at the maximum wave speed in shallow water. The gravity-capillary depressions are rapidly damped by viscosity and their speed-amplitude characteristics closely match those from inviscid calculations of gravity-capillary lumps. The shedding frequency of the lumps in the present experiments increases with both increasing towing speed and air-flow rate. Predictions of this behavior using a model equation that incorporates damping and a quadratic nonlinearity are in good agreement with the experiments. The partial support of the National Science Foundation under grant OCE0751853 is gratefully acknowledged.

  11. Pressurized nano-liquid-junction interface for coupling capillary electrochromatography and nano-liquid chromatography with mass spectrometry.

    Science.gov (United States)

    D'Orazio, Giovanni; Fanali, Salvatore

    2013-11-22

    A new nano-liquid-junction interface for coupling both capillary electrochromatography (CEC) or nano-liquid chromatography (nano-LC) with mass spectrometry (MS) was studied. The interface was a small T piece of polymeric material where capillary column and tip capillary were positioned at 180° while the third exit (at 90°) was occupied by a capillary delivering a liquid-assisting spray ionization for CEC experiments or by the electrode for the high voltage spray for nano-LC. Experiments were carried out analyzing mixtures of some organophosphorus pesticides (OPPs) or anti-inflammatory and related acidic drugs with MS detection in positive or negative ion mode, respectively. Analyzed OPPs compounds were baseline resolved utilizing the novel interface in both nano-LC and CEC obtaining good sensitivity and repeatability. For CEC-MS, the limits of detection ranged between 0.03 and 6.80 μg/mL and the intra-day repeatability was RSD interface was easy to handle and good reproducibility, between 2.5 and 3.5% for the retention time and interface was installed by two different analysts. Furthermore, it could be used for both CEC and nano-LC.

  12. Performance and characteristics of a high pressure, high temperature capillary cell with facile construction for operando x-ray absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Bansode, Atul; Urakawa, Atsushi, E-mail: aurakawa@iciq.es [Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona (Spain); Guilera, Gemma; Simonelli, Laura; Avila, Marta [ALBA Synchrotron Light Source, Crta. BP 1413, Km. 3.3, 08290 Cerdanyola del Vallès, Barcelona (Spain); Cuartero, Vera [ALBA Synchrotron Light Source, Crta. BP 1413, Km. 3.3, 08290 Cerdanyola del Vallès, Barcelona (Spain); European Synchrotron Radiation Facility (ESRF), CS40220, F-38043, Grenoble Cedex (France)

    2014-08-15

    We demonstrate the use of commercially available fused silica capillary and fittings to construct a cell for operando X-ray absorption spectroscopy (XAS) for the study of heterogeneously catalyzed reactions under high pressure (up to 200 bars) and high temperature (up to 280 °C) conditions. As the first demonstration, the cell was used for CO{sub 2} hydrogenation reaction to examine the state of copper in a conventional Cu/ZnO/Al{sub 2}O{sub 3} methanol synthesis catalyst. The active copper component of the catalyst was shown to remain in the metallic state under supercritical reaction conditions, at 200 bars and up to 260 °C. With the coiled heating system around the capillary, one can easily change the length of the capillary and control the amount of catalyst under investigation. With precise control of reactant(s) flow, the cell can mimic and serve as a conventional fixed-bed micro-reactor system to obtain reliable catalytic data. This high comparability of the reaction performance of the cell and laboratory reactors is crucial to gain insights into the nature of actual active sites under technologically relevant reaction conditions. The large length of the capillary can cause its bending upon heating when it is only fixed at both ends because of the thermal expansion. The degree of the bending can vary depending on the heating mode, and solutions to this problem are also presented. Furthermore, the cell is suitable for Raman studies, nowadays available at several beamlines for combined measurements. A concise study of CO{sub 2} phase behavior by Raman spectroscopy is presented to demonstrate a potential of the cell for combined XAS-Raman studies.

  13. A Semi-Analytical Method for Rapid Estimation of Near-Well Saturation, Temperature, Pressure and Stress in Non-Isothermal CO2 Injection

    Science.gov (United States)

    LaForce, T.; Ennis-King, J.; Paterson, L.

    2015-12-01

    Reservoir cooling near the wellbore is expected when fluids are injected into a reservoir or aquifer in CO2 storage, enhanced oil or gas recovery, enhanced geothermal systems, and water injection for disposal. Ignoring thermal effects near the well can lead to under-prediction of changes in reservoir pressure and stress due to competition between increased pressure and contraction of the rock in the cooled near-well region. In this work a previously developed semi-analytical model for immiscible, nonisothermal fluid injection is generalised to include partitioning of components between two phases. Advection-dominated radial flow is assumed so that the coupled two-phase flow and thermal conservation laws can be solved analytically. The temperature and saturation profiles are used to find the increase in reservoir pressure, tangential, and radial stress near the wellbore in a semi-analytical, forward-coupled model. Saturation, temperature, pressure, and stress profiles are found for parameters representative of several CO2 storage demonstration projects around the world. General results on maximum injection rates vs depth for common reservoir parameters are also presented. Prior to drilling an injection well there is often little information about the properties that will determine the injection rate that can be achieved without exceeding fracture pressure, yet injection rate and pressure are key parameters in well design and placement decisions. Analytical solutions to simplified models such as these can quickly provide order of magnitude estimates for flow and stress near the well based on a range of likely parameters.

  14. Upscaling of CO 2 vertical migration through a periodic layered porous medium: The capillary-free and capillary-dominant cases

    Science.gov (United States)

    Mouche, Emmanuel; Hayek, Mohamed; Mügler, Claude

    2010-09-01

    We present an upscaled model for the vertical migration of a CO 2 plume through a vertical column filled with a periodic layered porous medium. This model may describe the vertical migration of a CO 2 plume in a perfectly layered horizontal aquifer. Capillarity and buoyancy are taken into account and semi-explicit upscaled flux functions are proposed in the two following cases: (i) capillarity is the main driving force and (ii) buoyancy is the only driving force. In both cases, we show that the upscaled buoyant flux is a bell-shaped function of the saturation, as in the case of a homogeneous porous medium. In the capillary-dominant case, we show that the upscaled buoyant flux is the harmonic mean of the buoyant fluxes in each layer. The upscaled saturation is governed by the continuity of the capillary pressure at the interface between layers. In the capillary-free case, the upscaled buoyant flux and upscaled saturation are determined by the flux continuity condition at the interface. As the flux is not continuous over the entire range of saturation, the upscaled saturation is only defined where continuity is verified, i.e. in two saturation domains. As a consequence, the upscaled buoyant flux is described by a piecewise continuous function. Two analytical approximations of this flux are proposed and this capillary-free upscaled model is validated for two cases of heterogeneity. Upscaled and cell averaged saturations are in good agreement. Furthermore, the proposed analytical upscaled fluxes provide satisfactory approximations as long as the saturation set at the inlet of the column is in a range where analytical and numerical upscaled fluxes are close.

  15. Lattice Boltzmann simulations of supercritical CO2-water drainage displacement in porous media: CO2 saturation and displacement mechanism.

    Science.gov (United States)

    Yamabe, Hirotatsu; Tsuji, Takeshi; Liang, Yunfeng; Matsuoka, Toshifumi

    2015-01-06

    CO2 geosequestration in deep aquifers requires the displacement of water (wetting phase) from the porous media by supercritical CO2 (nonwetting phase). However, the interfacial instabilities, such as viscous and capillary fingerings, develop during the drainage displacement. Moreover, the burstlike Haines jump often occurs under conditions of low capillary number. To study these interfacial instabilities, we performed lattice Boltzmann simulations of CO2-water drainage displacement in a 3D synthetic granular rock model at a fixed viscosity ratio and at various capillary numbers. The capillary numbers are varied by changing injection pressure, which induces changes in flow velocity. It was observed that the viscous fingering was dominant at high injection pressures, whereas the crossover of viscous and capillary fingerings was observed, accompanied by Haines jumps, at low injection pressures. The Haines jumps flowing forward caused a significant drop of CO2 saturation, whereas Haines jumps flowing backward caused an increase of CO2 saturation (per injection depth). We demonstrated that the pore-scale Haines jumps remarkably influenced the flow path and therefore equilibrium CO2 saturation in crossover domain, which is in turn related to the storage efficiency in the field-scale geosequestration. The results can improve our understandings of the storage efficiency by the effects of pore-scale displacement phenomena.

  16. Influence of local capillary trapping on containment system effectiveness

    Energy Technology Data Exchange (ETDEWEB)

    Bryant, Steven [University Of Texas At Austin, Austin, TX (United States). Center for Petroleum and Geosystems Engineering

    2014-03-31

    Immobilization of CO2 injected into deep subsurface storage reservoirs is a critical component of risk assessment for geologic CO2 storage (GCS). Local capillary trapping (LCT) is a recently established mode of immobilization that arises when CO2 migrates due to buoyancy through heterogeneous storage reservoirs. This project sought to assess the amount and extent of LCT expected in storage formations under a range of injection conditions, and to confirm the persistence of LCT if the seal overlying the reservoir were to lose its integrity. Numerical simulation using commercial reservoir simulation software was conducted to assess the influence of injection. Laboratory experiments, modeling and numerical simulation were conducted to assess the effect of compromised seal integrity. Bench-scale (0.6 m by 0.6 m by 0.03 m) experiments with surrogate fluids provided the first empirical confirmation of the key concepts underlying LCT: accumulation of buoyant nonwetting phase at above residual saturations beneath capillary barriers in a variety of structures, which remains immobile under normal capillary pressure gradients. Immobilization of above-residual saturations is a critical distinction between LCT and the more familiar “residual saturation trapping.” To estimate the possible extent of LCT in a storage reservoir an algorithm was developed to identify all potential local traps, given the spatial distribution of capillary entry pressure in the reservoir. The algorithm assumes that the driving force for CO2 migration can be represented as a single value of “critical capillary entry pressure” Pc,entrycrit, such that cells with capillary entry pressure greater/less than Pc,entrycrit act as barriers/potential traps during CO2 migration. At intermediate values of Pc,entrycrit, the barrier regions become more laterally extensive in the reservoir

  17. Effects of water-saturation on strength and ductility of three igneous rocks at effective pressures to 50 MPA and temperatures to partial melting

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, S.J.; Friedman, M.; Handin, J.

    1981-01-01

    The short-term failure strengths and strains at failure of room-dry and water-saturated, cylindrical specimens (2 by 4 cm) of Charcoal Granodiorite (CG), Mt. Hood Andesite (MHA), and Cuerbio Basalt (CB) at a strain rate of 10/sup -4/s/sup -1/, at effective confining pressures of 0, 50, and 100 MPa and at temperatures to partial melting were investigated. Data from water-saturated specimens of the granodiorite and andesite, compared to room-dry counterparts, indicate (1) the pore pressures are essentially communicated throughout each test specimen so that they are fully effective; (2) at P/sub e/ = 0 and 50 MPa the granodiorite does not water-weaken; (3) at these same effective pressures the more porous and finer-grained andesite begins to exhibit water-weakening at about 600/sup 0/C; (4) at P/sub e/ = 0 and 870 to 900/sup 0/C the andesite's strength averages 20 MPa while the strength of dry specimens at the same P and T exhibit a strength of 100 MPa; (5) at P/sub e/ = 50 MPa compared to 160 MPa dry; (6) the basalt at P/sub e/ = 0, appears to be water-weakened at 800/sup 0/C; (7) water saturated specimens deformed at temperatures less than that of melting exhibit ultimate strengths at less than 2% shortening and then work-soften along faults; (8) again as do the dry counterparts, the wet specimens deform primarily by microscopic fracturing that coalesces into one or more macroscopic faults; and (9) the temperature for incipient melting of the andesite is decreased >150/sup 0/C in the water-saturated tests.

  18. Phase field modeling of partially saturated deformable porous media

    Science.gov (United States)

    Sciarra, Giulio

    2016-09-01

    A poromechanical model of partially saturated deformable porous media is proposed based on a phase field approach at modeling the behavior of the mixture of liquid water and wet air, which saturates the pore space, the phase field being the saturation (ratio). While the standard retention curve is expected still^ to provide the intrinsic retention properties of the porous skeleton, depending on the porous texture, an enhanced description of surface tension between the wetting (liquid water) and the non-wetting (wet air) fluid, occupying the pore space, is stated considering a regularization of the phase field model based on an additional contribution to the overall free energy depending on the saturation gradient. The aim is to provide a more refined description of surface tension interactions. An enhanced constitutive relation for the capillary pressure is established together with a suitable generalization of Darcy's law, in which the gradient of the capillary pressure is replaced by the gradient of the so-called generalized chemical potential, which also accounts for the "force", associated to the local free energy of the phase field model. A micro-scale heuristic interpretation of the novel constitutive law of capillary pressure is proposed, in order to compare the envisaged model with that one endowed with the concept of average interfacial area. The considered poromechanical model is formulated within the framework of strain gradient theory in order to account for possible effects, at laboratory scale, of the micro-scale hydro-mechanical couplings between highly localized flows (fingering) and localized deformations of the skeleton (fracturing).

  19. Normative Values of Retinal Oxygen Saturation in Rhesus Monkeys: The Beijing Intracranial and Intraocular Pressure (iCOP Study.

    Directory of Open Access Journals (Sweden)

    Jing Li

    Full Text Available To study the normal values of the retinal oxygen saturation in Rhesus monkeys and to evaluated repeatability and reproducibility of retinal oxygen saturation measurements.Eighteen adult Rhesus macaque monkeys were included in this experimental study. An Oxymap T1 retinal oximeter (Oxymap, Reykjavik, Iceland was used to perform oximetry on all subjects. Global arterial (SaO2 and venous oxygen saturation (SvO2, arteriovenous difference in SO2 were measured. In the first examination, each eye was imaged three times. At the following two examinations, each eye was imaged once. All examinations were finished in one month. P values were calculated to evaluate the difference between the measurements during three visits by performing an ANOVA. Intra-visit and inter-visit intraclass correlation coefficient (ICC was determined.At baseline, the average SaO2 and SvO2 were 89.48 ± 2.64% and 54.85 ± 2.18%, respectively. The global A-V difference was 34.63 ± 1.91%. The difference between the three visits was not significant (p>0.05. The highest A-V difference in SO2 and lowest saturations were found in the inferotemporal quadrant. Intra-session and inter-visit repeatability were both high. For all oxygen saturation parameters, the ICC values of the intra-session repeatability ranged between 0.92 and 0.96. As found previously, a relatively high ICC value for inter-visit repeatability also was found for all oxygen saturation measurements, ranging between 0.86 and 0.94, with the lowest values in the infero-nasal quadrant.Our study is the first to describe retinal SO2 in healthy Rhesus monkeys. In normal monkey eyes, the reproducibility and repeatability of retinal oximetry oxygen saturation measurements were high in the retinal arterioles and venules. Our results support that Oxymap T1 retinal oximetry is a suitable and reliable technique in monkey studies.

  20. Pump for Saturated Liquids

    Science.gov (United States)

    Elliott, D. G.

    1986-01-01

    Boiling liquids pumped by device based on proven components. Expanding saturated liquid in nozzle and diverting its phases along separate paths in liquid/vapor separator raises pressure of liquid. Liquid cooled in process. Pump makes it unnecessary to pressurize cryogenic liquids in order to pump them. Problems of introducing noncondensable pressurizing gas avoided.

  1. A Multi-capillary Inlet Jet Disruption Electrodynamic Ion Funnel Interface for Improved Sensitivity Using Atmospheric Pressure Ion Sources

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Tae Man (ASSOC WESTERN UNIVERSITY); Tang, Keqi (BATTELLE (PACIFIC NW LAB)); Udseth, Harold R.(BATTELLE (PACIFIC NW LAB)); Smith, Richard D.(BATTELLE (PACIFIC NW LAB))

    2001-09-01

    A new multicapillary inlet and ion funnel interface for electrospray ionization-mass spectrometry has been developed and demonstrated to achieve higher ion transmission efficiency compared to a single capillary inlet and ion funnel interface. Even though the distance between the end of the ESI inlet capillary and the exit of the ion funnel (10 cm) is significantly longer than that of the conventional interface (typically a few mm), a significant part of the directed gas flow persists into the first stage of pumping and results in an increased gas load to the second chamber. A jet disrupter made of a circular metal disk placed on axis in the ion funnel enhanced the dispersion of the directed gas flow from a multi-capillary inlet and was found to improve the ion transmission. The ion funnel with the jet disrupter demonstrated a 15% improvement in ion transmission compared to that without the jet disrupter, and simultaneously reduced the pumping speed required for the first or second stage by a factor of 2 to 3. Compared to the sensitivity with the standard mass spectrometer interface (an API 3000, SCIEX, Concord, ON, Canada) in MS/MS operation using an interface equipped with the jet disrupter and ion funnel, a factor of 5.3 to 10.7 enhancement in signal was observed for samples with concentrations of 100 to 500 pg/ul and 10.2 to 14.1 for concentrations of 10 to 50 pg/ul. The decreased enhancement at higher concentrations is attributed to space change effects.

  2. Effect of Initial Hydraulic Conditions on Capillary Rise in a Porous Medium: Pore-Network Modeling

    KAUST Repository

    Joekar-Niasar, V.

    2012-01-01

    The dynamics of capillary rise in a porous medium have been mostly studied in initially dry systems. As initial saturation and initial hydraulic conditions in many natural and industrial porous media can be variable, it is important to investigate the influence of initial conditions on the dynamics of the process. In this study, using dynamic pore-network modeling, we simulated capillary rise in a porous medium for different initial saturations (and consequently initial capillary pressures). Furthermore, the effect of hydraulic connectivity of the wetting phase in corners on the height and velocity of the wetting front was studied. Our simulation results show that there is a trade-off between capillary forces and trapping due to snap-off, which leads to a nonlinear dependence of wetting front velocity on initial saturation at the pore scale. This analysis may provide a possible answer to the experimental observations in the literature showing a non-monotonic dependency between initial saturation and the macroscopic front velocity. © Soil Science Society of America.

  3. The Effects of Massage with Coconut and Sunflower Oils on Oxygen Saturation of Premature Infants with Respiratory Distress Syndrome Treated With Nasal Continuous Positive Airway Pressure

    Directory of Open Access Journals (Sweden)

    Sousan Valizadeh

    2012-11-01

    Full Text Available Introduction: Nowadays particular emphasis is placed on the developmental aspects of premature infants care. Massage therapy is one of the best-known methods of caring. Due to the minimal touch policy in neonatal intensive care units (NICUs, massaging is not usually performed on premature infants. However, there is not sufficient evidence to support the claim that newborn infants with complex medical conditions should not be massaged. This study aimed to determine the effects of massage with coconut and sunflower oils on oxygen saturation of infants with respiratory distress syndrome (RDS treated with nasal continuous positive airway pressure (NCPAP. Methods: This was a randomized controlled trial on 90 newborns who were admitted to Alzahra Hospital (Tabriz, Iran. The infants were divided into control and massage therapy groups (massage with coconut and sunflower oils. Data was collected using a hospital documentation form. A 15-minute daily massage was performed for 3 days. Respiratory rate (RR, fraction of inspired oxygen (FiO2 and oxygen saturation were measured 5 minutes before the massage, 3 times during the massage, and 5 minutes after the massage. The collected data was analyzed using a mixed model. Results: In comparison to coconut oil and control groups, mean oxygen saturation of sunflower oil group was improved. In addition, the coconut massage group showed lower oxygen saturation than the control group but was all values were within the normal range. Although massage decreased oxygen saturation, there was no need to increase FiO2. Conclusion: Massage therapy can provide developmental care for infants treated with NCPAP.

  4. 利用低压饱和蒸汽发电的实例%Examples of Power Generation by Use of Low-pressure Saturated Steam

    Institute of Scientific and Technical Information of China (English)

    莫宾; 蔡鸣; 蒋洁

    2011-01-01

    Use of the low-pressure saturated steam which is the byproduct of the patent technology of "thermal phosphoric acid production of heat recovery",for power generation,the problem of excess low-pressure saturated steam in the thermal phosphoric acid production enterprises is solved.Via examples,the performance characteristics of generating units,power generation process and connection considerations with the external network are explained.With this technology,the electricity load in thermal phosphoric acid can be met,product energy consumption and cost can be reduced.It provides a new way for the comprehensive utilization of low-pressure saturated steam in thermal phosphoric acid production for the domestic enterprises.%利用"热法磷酸生产热能回收"专利技术副产的低压饱和蒸汽发电,解决了热法磷酸生产企业低压饱和蒸汽过剩的问题。通过实例,讲述了发电机组的性能特点、发电的工艺流程及与外网联接的注意事项。通过此技术的应用,基本能满足热法磷酸装置用电负荷,可降低产品的能耗和成本,达到节能减排的效果,为国内热法磷酸生产企业和其它行业低压饱和蒸汽的综合利用提供了一条新途径。

  5. Probing liquid distribution in partially saturated porous materials with hydraulic admittance.

    Science.gov (United States)

    Cheung, P; Fairweather, J F; Schwartz, D T

    2011-09-01

    The distribution of two immiscible fluids in a complex porous material during displacement is often central to understanding its function. Characterization of this distribution is traditionally determined via optically transparent flow cells. However, for opaque or thin porous materials of the order of hundreds of microns, optical visualization proves to be difficult and requires sophisticated imaging techniques that are expensive and difficult to come by. We describe here a bench-top tool that dynamically probes the hydraulic pathways leading to each free-interface within a single capillary and a bundle of seven capillaries at various saturations (i.e., hydraulic path lengths). A small volumetric displacement was applied to each interface such that the interfaces remained pinned at the capillary walls and the resultant oscillatory pressure drop was measured to determine the hydraulic admittance at each applied oscillation frequency. When the magnitude of the hydraulic admittance was plotted vs. applied oscillation frequency, a resonance peak was found for each degenerately filled capillary. The corresponding peaks were represented by a half-loop (100% filled) and full loops (partially filled) in a Nyquist plot. We compared the theoretical and measured admittance curves and found good agreement for both capillary systems at high filled states. The theoretical predictions became worse when the hydraulic path length was comparable to the capillary radius. The analysis for the hydraulic admittance of a bundle of capillaries is developed here and experimentally validated for the first time.

  6. Seven-Day Mortality Can Be Predicted in Medical Patients by Blood Pressure, Age, Respiratory Rate, Loss of Independence, and Peripheral Oxygen Saturation (the PARIS Score)

    DEFF Research Database (Denmark)

    Brabrand, Mikkel; Lassen, Annmarie Touborg; Knudsen, Torben

    2015-01-01

    BACKGROUND: Most existing risk stratification systems predicting mortality in emergency departments or admission units are complex in clinical use or have not been validated to a level where use is considered appropriate. We aimed to develop and validate a simple system that predicts seven....... The outcome was defined as seven-day all-cause mortality. 76 patients (2.5%) met the endpoint in the development cohort, 57 (2.0%) in the first validation cohort, and 111 (4.3%) in the second. Systolic blood Pressure, Age, Respiratory rate, loss of Independence, and peripheral oxygen Saturation were...

  7. Temporal redistribution of plantar pressure points in diabetic and control subjects: A time-series analysis of neuro-capillary chaos

    Directory of Open Access Journals (Sweden)

    Devesh V Oberoi

    2010-02-01

    Full Text Available BackgroundIn diabetic individuals (DI, neuropathy hinders theredistribution of plantar pressure points thus leading tosusceptible areas where there is constant capillaryblanching which may develop into trophic ulcers. Theredistribution of pressure points may precede evidenceof clinical neuropathy. In this study we comparetemporal redistribution of plantar pressure points (areasof capillary blanching between normal subjects taken ascontrols and DI with no clinical signs of neuropathy.MethodFour adults (45±4.55 years diagnosed to have Type-2Diabetes, without signs of clinical neuropathy andage -matched controls (43±3.74 years were studied.The subjects were asked to stand on a glass slab and a10 minute video recording of 10 selected plantarpressure points was made. Changes in the distance ofthese points with reference to a defined point onMayer’s line were measured at every 10 seconds.Standard deviation of difference of redistributedconsecutive pressure point (SDPP in cms., andfractal dimension (FD was used to compare the twogroups.ResultsCombined mean SDPP (DI =0.013 ± 0.008 cms,controls= 0.196±0.233 cms, P <0.001 and FD (DI=1.000 ± 0.000, controls= 1.010±0.017, P <0.001 ofdiabetic patients were significantly lower thancontrols. Pressure point at base of the 4th toe andthe lower limit of blanching to the left Mayers line atthe heel did not differ significantly between DI andcontrols.ConclusionThere is impaired redistribution of plantar pressurepoints in individuals with diabetes without signs ofclinical neuropathy. This can be attributed to loss ofchaos generating mechanisms in DI. Redistributionof pressure points may be essential in theprevention of trophic ulcers in susceptibleindividuals.

  8. Two-Phase Critical Discharge of Initially Saturated or Subcooled Water Flowing in Sharp-Edgred Tubes at High Pressure

    Institute of Scientific and Technical Information of China (English)

    1995-01-01

    The transient critical flow experiment with sharp-deged tubes as the break geometries is conducted in high pressure convective circulation test loop of Xi'an Jiantong University.The initial Steady operation pressure is up to 22.0MPa.An empirical correlation was made to obtain the critical mass flow rates,the critical pressure ratio and the thermal nonequilibrium number were correlated as the functions of the tube length to tube diameter ratio L/D.The predicted critical mass flow rate gets a higher accureacy for short tubes with L/D 12.

  9. Two-phase heat transfer and pressure drop of LNG during saturated flow boiling in a horizontal tube

    Science.gov (United States)

    Chen, Dongsheng; Shi, Yumei

    2013-12-01

    Two-phase heat transfer and pressure drop of LNG (liquefied natural gas) have been measured in a horizontal smooth tube with an inner diameter of 8 mm. The experiments were conducted at inlet pressures from 0.3 to 0.7 MPa with a heat flux of 8-36 kW m-2, and mass flux of 49.2-201.8 kg m-2 s-1. The effect of vapor quality, inlet pressure, heat flux and mass flux on the heat transfer characteristic are discussed. The comparisons of the experimental data with the predicted value by existing correlations are analyzed. Zou et al. (2010) correlation shows the best accuracy with 24.1% RMS deviation among them. Moreover four frictional pressure drop methods are also chosen to compare with the experimental database.

  10. CO2 Exsolution from CO2 Saturated Water: Core-Scale Experiments and Focus on Impacts of Pressure Variations.

    Science.gov (United States)

    Xu, Ruina; Li, Rong; Ma, Jin; Jiang, Peixue

    2015-12-15

    For CO2 sequestration and utilization in the shallow reservoirs, reservoir pressure changes are due to the injection rate changing, a leakage event, and brine withdrawal for reservoir pressure balance. The amounts of exsolved CO2 which are influenced by the pressure reduction and the subsequent secondary imbibition process have a significant effect on the stability and capacity of CO2 sequestration and utilization. In this study, exsolution behavior of the CO2 has been studied experimentally using a core flooding system in combination with NMR/MRI equipment. Three series of pressure variation profiles, including depletion followed by imbibitions without or with repressurization and repetitive depletion and repressurization/imbibition cycles, were designed to investigate the exsolution responses for these complex pressure variation profiles. We found that the exsolved CO2 phase preferentially occupies the larger pores and exhibits a uniform spatial distribution. The mobility of CO2 is low during the imbibition process, and the residual trapping ratio is extraordinarily high. During the cyclic pressure variation process, the first cycle has the largest contribution to the amount of exsolved CO2. The low CO2 mobility implies a certain degree of self-sealing during a possible reservoir depletion.

  11. Capillary states of granular materials in the funicular state

    Science.gov (United States)

    Delenne, Jean-Yves; Richefeu, Vincent; Radjai, Farhang

    2013-06-01

    Using a multi-phase lattice Boltzmann model, we investigate the capillary states of a 2D granular packing gradually saturated by condensation from a homogeneously injected vapor phase. The internal stresses induced by surface tension and Laplace pressure are directly calculated from the forces acting on the grains with increasing amount of liquid. The evolution of cohesive strength with the amount of liquid reveals four different states reflecting the connectivity of the liquid phase and local grain environments. It increases in the pendular state, characterized by binary liquid bridges holding the grains together, and within the funicular state with an increasing number of liquid clusters connected to several grains. Beyond 40% of saturation, the cohesive strength falls off due to a decreasing Laplace pressure of liquid clusters.

  12. A semi-analytical model for computation of capillary entry pressures and fluid configurations in uniformly-wet pore spaces from 2D rock images

    Science.gov (United States)

    Frette, O. I.; Helland, J. O.

    2010-08-01

    A novel semi-analytical model for computation of capillary entry pressures and associated fluid configurations in arbitrary, potentially non-convex, 2D pore space geometries at uniform wettability is developed. The model computes all possible centre positions of circular arcs, and physically sound criteria are implemented to determine the set of these arcs that correspond to geometrically allowed interfaces. Interfaces and pore boundary segments are connected to form closed boundaries of identified geometrical regions. These regions are classified as either oil regions, located in the wider parts of the pore space, or as water regions located in pore space constrictions. All possible region combinations are identified and evaluated for each radius value in an iterative procedure to determine the favourable entry radius and corresponding configuration based on minimisation of free energy. The model has been validated by comparison with known analytical solutions in idealised pore geometries. In cases where different analytical solutions are geometrically possible, the model generates several oil and water regions, and the valid solution is determined by the region combination that corresponds to the most favourable entry pressure, consistent with the analytical solution. Entry pressure radii and configurations are computed in strongly non-convex pore spaces extracted from an image of Bentheimer sandstone, which demonstrates that the model captures successfully well-known characteristics of capillary behaviour at different wetting conditions. The computations also demonstrate the importance of selecting the fluid configuration of minimum change in free energy. In some cases, a merged region formed by a combination of oil and water regions corresponds to the favourable entry configuration of oil, whereas in other cases, an individual oil region may correspond to the favourable oil entry configuration. It is also demonstrated that oil entry configurations may

  13. H2O-fluid-saturated melting of subducted continental crust facilitates exhumation of ultrahigh-pressure rocks in continental subduction zones

    Science.gov (United States)

    Labrousse, L.; Duretz, T.; Gerya, T.

    2015-10-01

    We present two-dimensional numerical models of plate subduction and collision inspired by the Scandinavian Caledonian orogeny to investigate the possible impact of continental crust partial melting on the exhumation of ultra-high pressure metamorphic rocks. Three possible reactions were tested: low temperature solidus representing H2O-fluid-saturated partial melting, and two end-member reaction curves for dehydration melting. Thermo-mechanical effects of partial melting were implemented as (1) a viscosity decrease as a determined rheologically critical melt percentage was reached (here 0.1), (2) a change in effective heat capacity and adiabatic heating/cooling accounting for a latent heat term in the heat equation. Among the 3 tested reactions, only H2O-fluid-saturated partial melting drastically modifies the collision dynamics from the non-melting reference model holding all other parameters constant. A substantially low general viscosity truncation (here 1017 Pa s) is needed to properly resolve the effect of partial melting on deep collision processes. Low temperature melting indeed induces the development of a low viscosity buoyant plume prior to slab detachment, where migmatites exhume from UHP conditions at rates and with pressure-temperature paths similar to the natural values acknowledged for the Norwegian Caledonides. High temperature melting has no drastic influence on early collision dynamics. While positive buoyancy remains the first order driver for the exhumation of buried continental rocks, exhumation initiates in these cases with eduction subsequent to slab detachment. Melting and formation of a migmatite plume can later occur along decompression path while continental crust undergoes thermal reequilibration at temperatures above 900 °C. Some of the partially molten material can also relaminate in the overriding plate rather than exhume within the collision zone. Even if minor in terms of amount of magma produced, H2O-fluid-saturated partial melting

  14. Temperature- and pressure-dependent densities, self-diffusion coefficients, and phase behavior of monoacid saturated triacylglycerides: toward molecular-level insights into processing.

    Science.gov (United States)

    Greiner, Maximilian; Reilly, Anthony M; Briesen, Heiko

    2012-05-23

    Using molecular-dynamics (MD) simulations the densities and self-diffusion coefficients of a range of liquid monoacid triacylglycerides (TAGs) have been studied as a function of temperature and, for the first time, pressure. While offset by their ambient properties, the response of the TAGs to temperature and pressure is qualitatively similar. Application of pressure was found to significantly increase densities and reduce diffusion of the TAG molecules, suggesting that it may have as much a role in processing and crystallizing TAGs as supercooling does. A solution of glycerol tripalmitate and glycerol trihexanoate was also studied, showing that application of pressure should lead to a significant decrease in the saturation point of the solution, which is an important consideration for processing TAGs. Different solid/liquid interfaces of glycerol tripalmitate have also been investigated. Although crystal growth could not be observed, dissolution of one interface was seen in the MD simulations. The results suggest that over moderate distances the melting of TAGs may be cooperative in nature, rather than involving dissolution of individual TAG molecules.

  15. A novel capillary electrophoresis method with pressure assisted field amplified sample injection in determination of thiol collectors in flotation process waters.

    Science.gov (United States)

    Sihvonen, T; Aaltonen, A; Leppinen, J; Hiltunen, S; Sirén, H

    2014-01-17

    A new capillary electrophoresis method was developed for the quantification of diisobutyldithiophosphate (DTP), diisobutyldithiophosphinate (DTPI) and ethyl and isobutyl xanthates (EX, IBX) all of which are used as thiol collectors in froth flotation. This method uses pressure assisted field amplified sample injection (PA-FASI) to concentrate the analytes at the capillary inlet. The background electrolyte in electrophoretic separation was 60millimolar (mM) from 3-(cyclohexylamino)propane-1-sulfonic acid (CAPS) in 40mM NaOH solution. The similar CAPS electrolyte solution has earlier been used for screening for diuretics that contained sulphonamide and/or carboxylic groups. In this study, the functional groups are xanthate, phosphate and phosphinate. The method was developed using actual flotation process waters. The results showed that the water delivered from the plant did not contain significant amount of collectors; therefore, method development was accomplished by spiking analytes in these waters. Separation of analytes was achieved in 15min. The range of quantification was 0.27-66.6mg/L (R(2) 0.9991-0.9999) for all analytes other than ethyl xanthate, for which the range was 0.09-66.6mg/L (R(2) 0.9999). LOD (S/N=3) and LOQ (S/N=10) values for DTP, DTPI, IBX and EX were 0.05, 0.07, 0.06 and 0.01mg/L and 0.16, 0.25, 0.21 and 0.04mg/L, respectively. No interference from the matrices was observed, when the method was tested at a gold concentrator plant.

  16. Occurrence of methane hydrate in saturated and unsaturated solutions of sodium chloride and water in dependence of temperature and pressure

    Energy Technology Data Exchange (ETDEWEB)

    de Roo, J.L.; Diepen, G.A.M.; Lichtenthaler, R.N.; Peters, C.J.

    1983-07-01

    Experimental results of the formation of methane hydrate in dependence of temperature and pressure in unsaturated solutions of NaCl in water will be presented in a temperature range from 261.85 to 285.98 K and pressure up to 11.0 MPa. Furthermore the four-phase equilibrium NaCl X 2H/sub 2/O /SUB s/ -CH/sub 4/ X nH/sub 2/O /SUB s/ -L-G has been calculated from the experimental results. Also the heats of transformation of several other equilibria in the ternary system CH/sub 4/-H/sub 2/O-NaCl are obtained.

  17. Critical Capillary Number of Interfacial Film Displacement in a Capillary Tube

    CERN Document Server

    Yan, Changfei

    2016-01-01

    The role of surface tension and wettability in the dynamics of air-liquid interfaces during immiscible fluid displacement flows in capillary tube driven by pressure has been investigated. The contact angle and capillary number drive the force wetting processes which is controlled by the balance between the capillary and the viscous lubrication forces. The dynamic wetting condition with the critical capillary number is studied analytically and validated experimentally, which demonstrates that the critical capillary number is associated with the contact angle, slip length and capillary radius.

  18. Assessment of a five-layer laminate technique to measure the saturation solubility of drug in pressure-sensitive adhesive film.

    Science.gov (United States)

    Reismann, Simone; Lee, Geoffrey

    2012-07-01

    A five-layer laminate technique is used to determine the saturation solubility of a drug in a thin polymer film, c(p)(s), of pressure-sensitive adhesive (PSA) used to prepare transdermal patches. A drug-loaded donor polymer film is attached via a separating membrane to an initially drug-free acceptor polymer film. Diffusion of drug occurs into the acceptor up to saturation solubility equilibrium. This systematic study of the technique using the drug tamsulosin and the PSA Duro Tak 87-4098 was a kinetic analysis of the diffusion process. It was found that the technique gives an equilibrium value for c(p)(s) in a PSA polymer film in the presence of crystalline phase of the drug in the donor. A highly permeable Perthese-separating membrane caused overshoot in the acceptor, most likely induced by initial supersaturation of the donor. Change to a less-permeable ethylene-vinyl-acetate-separating membrane avoided overshoot, but gave a prolonged time, >300 days, to equilibrium. Preloading the acceptor accelerated the equilibration process to approximately 50 days with the Perthese. Suitable experimental conditions are identified that, if performed correctly, allow the technique to give an equilibrium value for c(p)(s).

  19. Relation Between Capillary Wedge Pressure Measured by Echocardiography Through Tissue Doppler Imaging (TDI Method and Catheterism in Patients with Mitral Valve Stenosis

    Directory of Open Access Journals (Sweden)

    Mashallah Dehghani

    2006-07-01

    Full Text Available Background: Considering suggested formula in the references and PCWP measured by catheterism, in the present study the relation between pulmonary capillary wedge pressure (PCWP measured the flow velocity of mitral valve and mitral annulus motion through tissue doppler imaging is evaluated Methods: 52 cases of severe MS were admitted for Balloon Mitral Valvolotomy (BMV are included in this study. Mean age was 35±5 years consisting of 40 females and 12 males. Valve area, Pulmonary artery systolic pressure (PAP, E (Maximum Velocity of mitral valve at the beginning of diastole & Em (Maximum rate of mitral annular motion at the beginning of diastole which is recorded through septal or lateral wall annulus site velocity and left atrial (LA size were also measured by echocardiography and PCWP & PAP through catheterism. All patients had normal ejection fraction (EF and coronary arteries; there was no other valvular diseases and shunts. Results: There was a significant correlation between PAP in echocardiography and catheterism. Mean PAP was 53±19 mmHg in echocardiography and 53.9±17.8mmHg in catheterism. There wasn't any correlation between PCWP in echocardiography and catheterism (P=0.33 and also no relation between PCWP and mitral valve area (MVA or LA size (P=0.2. E/Em ratio increased in severe MS cases.Conclusion: E/Em ratio and suggested formula would overestimate the wedge pressure so echocardiography is not a reliable method for measuring PCWP in severe MS. Em velocity and E/Em ratio may be used for estimating MS severity.

  20. ESTIMATES OF THE ERROR OF EXPERIMENTAL DATA AT STUDIES OF DENSITY AND THE SATURATED VAPOR PRESSURE (SVP PETROLEUM PRODUCTS

    Directory of Open Access Journals (Sweden)

    Kharchenko P. M.

    2015-10-01

    Full Text Available At calculations, we have used the next assumptions: 1. Not excluded systematic errors distributed with equal probability; 2. Random errors are normally distributed; 3. Total error is the composition of not excluded systematic and random errors. In calculating of measurement error of pressure, we proceeded from working formula. The confidence interval of each variable less than instrumental error, therefore, to characterize the total error of the measured value P, we use the instrumental errors of all variables. In estimating of temperature measurement error was consider the systematic and random error. To estimate random error we used measurement data of the specific volume of water on six isotherms. Obtained values were compared with published data. As an approximate estimate of the random error of our experimental data, we can take it as a total for all the isotherms of the specific volume in comparison with the published data. For studied fractions confidence limit of total error of measurement results located in the range of 0,03 ч 0,1%. At temperatures close to the critical increasing influence of errors of reference and the error associated with the introduction of corrections on the thermal expansion of the piezometer. In the two-phase area confidence limit of total error increases and located between 0,08 ч 0,15%. This is due to the sharp increase in this area of reference error of pressure and error in determining to the weight of the substance in the piezometer

  1. Influence of local capillary trapping on containment system effectiveness

    Energy Technology Data Exchange (ETDEWEB)

    Bryant, Steven [University Of Texas At Austin, Austin, TX (United States). Center for Petroleum and Geosystems Engineering

    2014-03-31

    Immobilization of CO2 injected into deep subsurface storage reservoirs is a critical component of risk assessment for geologic CO2 storage (GCS). Local capillary trapping (LCT) is a recently established mode of immobilization that arises when CO2 migrates due to buoyancy through heterogeneous storage reservoirs. This project sought to assess the amount and extent of LCT expected in storage formations under a range of injection conditions, and to confirm the persistence of LCT if the seal overlying the reservoir were to lose its integrity. Numerical simulation using commercial reservoir simulation software was conducted to assess the influence of injection. Laboratory experiments, modeling and numerical simulation were conducted to assess the effect of compromised seal integrity. Bench-scale (0.6 m by 0.6 m by 0.03 m) experiments with surrogate fluids provided the first empirical confirmation of the key concepts underlying LCT: accumulation of buoyant nonwetting phase at above residual saturations beneath capillary barriers in a variety of structures, which remains immobile under normal capillary pressure gradients. Immobilization of above-residual saturations is a critical distinction between LCT and the more familiar “residual saturation trapping.” To estimate the possible extent of LCT in a storage reservoir an algorithm was developed to identify all potential local traps, given the spatial distribution of capillary entry pressure in the reservoir. The algorithm assumes that the driving force for CO2 migration can be represented as a single value of “critical capillary entry pressure” Pc,entrycrit, such that cells with capillary entry pressure greater/less than Pc,entrycrit act as barriers/potential traps during CO2 migration. At intermediate values of Pc,entrycrit, the barrier regions become more laterally extensive in the reservoir

  2. Novel empirical correlations for estimation of bubble point pressure, saturated viscosity and gas solubility of crude oils

    Institute of Scientific and Technical Information of China (English)

    Ehsan Khamehchi; Fariborz Rashidi; Hanieh Rasouli; Amir Ebrahi-mian

    2009-01-01

    Knowledge of petroleum fluid properties is crucial for the study of reservoirs and their development. Estimation of reserves in an oil reservoir or determination of its performance and economics requires a good knowledge of the fluid physical properties. Bubble point pressure, gas solubility and viscosity of oils are the most important parameters in use for petroleum and chemical engineers. In this study a simple-to-use, straight-forward mathematical model was correlated on a set of 94 crude oil data. Three correlations were achieved based on an exponential regression, which were different from conventional empirical correlations, and were evaluated against 12 laboratory data other than those used for the regression. It is concluded that the new exponential equation is of higher precision and accuracy than the conventional correlations and is a more convenient mathematical formulation.

  3. The effect of hydrate saturation on water retention curves in hydrate-bearing sediments

    Science.gov (United States)

    Mahabadi, Nariman; Zheng, Xianglei; Jang, Jaewon

    2016-05-01

    The experimental measurement of water retention curve in hydrate-bearing sediments is critically important to understand the behavior of hydrate dissociation and gas production. In this study, tetrahydrofuran (THF) is selected as hydrate former. The pore habit of THF hydrates is investigated by visual observation in a transparent micromodel. It is confirmed that THF hydrates are not wetting phase on the quartz surface of the micromodel and occupy either an entire pore or part of pore space resulting in change in pore size distribution. And the measurement of water retention curves in THF hydrate-bearing sediments with hydrate saturation ranging from Sh = 0 to Sh = 0.7 is conducted for excess water condition. The experimental results show that the gas entry pressure and the capillary pressure increase with increasing hydrate saturation. Based on the experimental results, fitting parameters for van Genuchten equation are suggested for different hydrate saturation conditions.

  4. Raman spectroscopic measurements of CO2 density: Experimental calibration with high-pressure optical cell (HPOC) and fused silica capillary capsule (FSCC) with application to fluid inclusion observations

    Science.gov (United States)

    Wang, X.; Chou, I.-Ming; Hu, W.; Burruss, R.C.; Sun, Q.; Song, Y.

    2011-01-01

    Raman spectroscopy is a powerful method for the determination of CO2 densities in fluid inclusions, especially for those with small size and/or low fluid density. The relationship between CO2 Fermi diad split (??, cm-1) and CO2 density (??, g/cm3) has been documented by several previous studies. However, significant discrepancies exist among these studies mainly because of inconsistent calibration procedures and lack of measurements for CO2 fluids having densities between 0.21 and 0.75g/cm3, where liquid and vapor phases coexist near room temperature.In this study, a high-pressure optical cell and fused silica capillary capsules were used to prepare pure CO2 samples with densities between 0.0472 and 1.0060g/cm3. The measured CO2 Fermi diad splits were calibrated with two well established Raman bands of benzonitrile at 1192.6 and 1598.9cm-1. The relationship between the CO2 Fermi diad split and density can be represented by: ??=47513.64243-1374.824414????+13.25586152????2-0.04258891551????3 (r2=0.99835, ??=0.0253g/cm3), and this relationship was tested by synthetic fluid inclusions and natural CO2-rich fluid inclusions. The effects of temperature and the presence of H2O and CH4 on this relationship were also examined. ?? 2011 Elsevier Ltd.

  5. Linear stability of a surfactant-laden annular film in a time-periodic pressure-driven flow through a capillary.

    Science.gov (United States)

    Wei, Hsien-Hung; Halpern, David; Grotberg, James B

    2005-05-15

    This paper analyzes the effect of surfactant on the linear stability of an annular film in a capillary undergoing a time-periodic pressure gradient force. The annular film is thin compared to the radius of the tube. An asymptotic analysis yields a coupled set of equations with time-periodic coefficients for the perturbed fluid-fluid interface and the interfacial surfactant concentration. Wei and Rumschitzki (submitted for publication) previously showed that the interaction between a surfactant and a steady base flow could induce a more severe instability than a stationary base state. The present work demonstrates that time-periodic base flows can modify the features of the steady-flow-based instability, depending on surface tension, surfactant activity, and oscillatory frequency. For an oscillatory base flow (with zero mean), the growth rate decreases monotonically as the frequency increases. In the low-frequency limit, the growth rate approaches a maximum corresponding to the growth rate of a steady base flow having the same amplitude. In the high-frequency limit, the growth rate reaches a minimum corresponding to the growth rate in the limit of a stationary base state. The underlying mechanisms are explained in detail, and extension to other time-periodic forms is further exploited.

  6. Effect of varying alveolar oxygen partial pressure on diffusing capacity for nitric oxide and carbon monoxide, membrane diffusing capacity and lung capillary blood volume.

    Science.gov (United States)

    Borland, C D; Cox, Y

    1991-12-01

    1. To examine the effect of varying oxygen partial pressure (PAO2) on nitric oxide (DLNO) and carbon monoxide (DLCO) diffusing capacity (transfer factor), 10 subjects performed combined DLCO/DLNO measurements with the inspired mixture made up with three different oxygen concentrations (25%, 18% and 15%) to give PAO2 values of 12-20 kPa. 2. A novel method is described for calculating membrane diffusing capacity (DM) and pulmonary capillary volume (Qc) from DLNO and DLCO. 3. The mean DMCO was 52.89 mmol min-1 kPa-1 and Qc was 0.056 litre. Reducing PAO2 from 20 to 12 kPa resulted in an increase in DLCO = -0.124 (O2%) + 11.67 (P less than 0.001) and a fall in DLNO = 0.538 (O2%) + 32.01 (P less than 0.001) and a fall in DLNO/DLCO = 0.107 (O2%) + 2.52 (P less than 0.001). DM (P = 0.59) and Qc (P = 0.64) also tended to fall with falling PAO2. 4. It appears more likely that the minor reduction in DLNO that we have observed with falling PAO2 is due to diffusion rather than reaction limitation.

  7. Capillary origami

    OpenAIRE

    Py, Charlotte; Reverdy, Paul; Doppler, L.; J. Bico; Roman, B.; Baroud, Charles,

    2007-01-01

    International audience; The hairs of a wet dog rushing out from a pond assemble into bundles; this is a common example of the effect of capillary forces on flexible structures. From a practical point of the deformation and adhesion of compliant structures induced by interfacial forces may lead to disastrous effects in mechanical microsystems.

  8. Liquid morphologies and capillary forces between three spherical beads

    Science.gov (United States)

    Semprebon, Ciro; Scheel, Mario; Herminghaus, Stephan; Seemann, Ralf; Brinkmann, Martin

    2016-07-01

    Equilibrium shapes of coalesced pendular bridges in a static assembly of spherical beads are computed by numerical minimization of the interfacial energy. Our present study focuses on generic bead configurations involving three beads, one of which is in contact to the two others while there is a gap of variable size between the latter. In agreement with previous experimental studies, we find interfacial "trimer" morphologies consisting of three coalesced pendular bridges, and "dimers" of two coalesced bridges. In a certain range of the gap opening we observe a bistability between the dimer and trimer morphology during changes of the liquid volume. The magnitude of the corresponding capillary forces in presence of a trimer or dimer depends, besides the gap opening, only on the volume or Laplace pressure of the liquid. For a given Laplace pressure, and for the same gap opening, the capillary forces induced by a trimer are only slightly larger than the corresponding forces in the presence of three pendular bridges. This observation is consistent with a plateau of capillary cohesion in terms of the saturation of a wetting liquid in the funicular regime, as reported in the experimental work [Scheel et al., Nat. Mater. 7, 189 (2008), 10.1038/nmat2117].

  9. Time-resolved characterization of a filamentary argon discharge at atmospheric pressure in a capillary using emission and absorption spectroscopy

    Science.gov (United States)

    Schröter, Sandra; Pothiraja, Ramasamy; Awakowicz, Peter; Bibinov, Nikita; Böke, Marc; Niermann, Benedikt; Winter, Jörg

    2013-11-01

    An argon/nitrogen (0.999/0.001) filamentary pulsed discharge operated at atmospheric pressure in a quartz tube is characterized using voltage-current measurements, microphotography, optical emission spectroscopy (OES) and absorption spectroscopy. Nitrogen is applied as a sensor gas for the purpose of OES diagnostic. The density of argon metastable atoms Ar(3P2) is determined using tunable diode laser absorption spectroscopy (TDLAS). Using a plasma chemical model the measured OES data are applied for the characterization of the plasma conditions. Between intense positive pulses the discharge current oscillates with a damped amplitude. It is established that an electric current flows in this discharge not only through a thin plasma filament that is observed in the discharge image but also through the whole cross section of the quartz tube. A diffuse plasma fills the quartz tube during a time between intense current pulses. Ionization waves are propagating in this plasma between the spike and the grounded area of the tube producing thin plasma channels. The diameter of these channels increases during the pause between the propagation of ionization waves probably because of thermal expansion and diffusion. Inside the channels electron densities of ˜2 × 1013 cm-3, argon metastable densities ˜1014 cm-3 and a reduced electric field about 10 Td are determined.

  10. Kinetics and dynamics of nanosecond streamer discharge in atmospheric-pressure gas bubble suspended in distilled water under saturated vapor pressure conditions

    Science.gov (United States)

    Sharma, Ashish; Levko, Dmitry; Raja, Laxminarayan L.; Cha, Min Suk

    2016-10-01

    We perform computational studies of nanosecond streamer discharges generated in helium bubbles immersed in distilled water under atmospheric pressure conditions. The model takes into account the presence of water vapor in the gas bubble for an accurate description of the discharge kinetics. We find that the dynamic characteristics of the streamer discharge are different at low and high positive trigger voltages with the axial streamer evolution dominant for low voltages and a surface hugging mode favored for high voltages. We also find a substantial difference in initiation, transition and evolution stages of discharge for positive and negative trigger voltages with the volumetric distribution of species in the streamer channel much more uniform for negative trigger voltages on account of the presence of multiple streamers. We observe that the presence of water vapor does not affect the breakdown voltage even for oversaturated conditions but significantly influences the composition of dominant species in the trail of the streamer as well as the flux of the dominant species on the bubble surface.

  11. Kinetics and dynamics of nanosecond streamer discharge in atmospheric-pressure gas bubble suspended in distilled water under saturated vapor pressure conditions

    KAUST Repository

    Sharma, Ashish

    2016-09-08

    We perform computational studies of nanosecond streamer discharges generated in helium bubbles immersed in distilled water under atmospheric pressure conditions. The model takes into account the presence of water vapor in the gas bubble for an accurate description of the discharge kinetics. We find that the dynamic characteristics of the streamer discharge are different at low and high positive trigger voltages with the axial streamer evolution dominant for low voltages and a surface hugging mode favored for high voltages. We also find a substantial difference in initiation, transition and evolution stages of discharge for positive and negative trigger voltages with the volumetric distribution of species in the streamer channel much more uniform for negative trigger voltages on account of the presence of multiple streamers. We observe that the presence of water vapor does not affect the breakdown voltage even for oversaturated conditions but significantly influences the composition of dominant species in the trail of the streamer as well as the flux of the dominant species on the bubble surface. © 2016 IOP Publishing Ltd.

  12. Application of Low-pressure Saturated Steam Power Generating Technology in Steel Enterprises%低压饱和蒸汽发电技术在钢铁企业的应用

    Institute of Scientific and Technical Information of China (English)

    刘颖; 马永锋

    2016-01-01

    介绍了钢铁企业饱和蒸汽发电主要的应用技术,并通过某钢厂的低压饱和蒸汽利用方案,对比了饱和蒸汽汽轮机和饱和蒸汽螺杆发电机应用的优缺点.%The main application technology of saturated steam power generating in steel enterprises is introduced. Taking the utilization program of low-pressure saturated steam pow-er generating of some steelmaker as an example, the advantages and disadvantages of saturat-ed steam turbine generator and saturated steam screw generator are compared.

  13. Diving under a microscope--a new simple and versatile in vitro diving device for fluorescence and confocal microscopy allowing the controls of hydrostatic pressure, gas pressures, and kinetics of gas saturation.

    Science.gov (United States)

    Wang, Qiong; Belhomme, Marc; Guerrero, François; Mazur, Aleksandra; Lambrechts, Kate; Theron, Michaël

    2013-06-01

    How underwater diving effects the function of the arterial wall and the activities of endothelial cells is the focus of recent studies on decompression sickness. Here we describe an in vitro diving system constructed to achieve real-time monitoring of cell activity during simulated dives under fluorescent microscopy and confocal microscopy. A 1-mL chamber with sapphire windows on both sides and located on the stage of an inverted microscope was built to allow in vitro diving simulation of isolated cells or arteries in which activities during diving are monitored in real-time via fluorescent microscopy and confocal microscopy. Speed of compression and decompression can range from 20 to 2000 kPa/min, allowing systemic pressure to range up to 6500 kPa. Diving temperature is controlled at 37°C. During air dive simulation oxygen partial pressure is optically monitored. Perfusion speed can range from 0.05 to 10 mL/min. The system can support physiological viability of in vitro samples for real-time monitoring of cellular activity during diving. It allows regulations of pressure, speeds of compression and decompression, temperature, gas saturation, and perfusion speed. It will be a valuable tool for hyperbaric research.

  14. Neuroprotection of hyperbaric oxygen therapy in sub-acute traumatic brain injury:not by immediately improving cerebral oxygen saturation and oxygen partial pressure

    Institute of Scientific and Technical Information of China (English)

    Bao-chun Zhou; Li-jun Liu; Bing Liu

    2016-01-01

    Although hyperbaric oxygen (HBO) therapy can promote the recovery of neural function in patients who have suffered traumatic brain injury (TBI), the underlying mechanism is unclear. We hypothesized that hyperbaric oxygen treatment plays a neuroprotective role in TBI by increasing regional transcranial oxygen saturation (rSO2) and oxygen partial pressure (PaO2). To test this idea, we compared two groups:a control group with 20 healthy people and a treatment group with 40 TBI patients. The 40 patients were given 100% oxygen of HBO for 90 minutes. Changes in rSO2 were measured. The controls were also examined for rSO2 and PaO2, but received no treatment. rSO2 levels in the patients did not differ signiifcantly after treatment, but levels before and after treatment were signiifcantly lower than those in the control group. PaO2 levels were signiifcantly decreased after the 30-minute HBO treatment. Our ifndings suggest that there is a disorder of oxygen metabolism in patients with sub-acute TBI. HBO does not immediately affect cerebral oxygen metabolism, and the underlying mechanism still needs to be studied in depth.

  15. Optimization of pressurized liquid extraction (PLE) for rapid determination of mineral oil saturated (MOSH) and aromatic hydrocarbons (MOAH) in cardboard and paper intended for food contact.

    Science.gov (United States)

    Moret, Sabrina; Sander, Maren; Purcaro, Giorgia; Scolaro, Marianna; Barp, Laura; Conte, Lanfranco S

    2013-10-15

    Packaging can represent a primary source of food contamination with mineral oil saturated hydrocarbons (MOSH) and aromatic hydrocarbons (MOAH), especially when recycled cardboard or mineral oil based printing inks are used. A pressurized liquid extraction (PLE) method, followed by on-line LC-GC analysis, has been optimized for rapid mineral oil determination in cardboard and paper samples. The proposed method involves extraction with hexane (2 cycles) at 60°C for 5 min, and allows for the processing of up to 6 samples in parallel with minimal sample manipulation and solvent consumption. It gave good repeatability (coefficient of variation lower than 5%) and practically quantitative extraction yield (less than 2% of the total contamination found in a third separate cycle). The method was applied to different cardboards and paper materials intended for food contact. Results obtained were similar to those obtained by applying classical solvent extraction with hexane/ethanol 1:1 (v/v) as described by Lorenzini et al. [20].

  16. Determination of Wastewater Compounds in Sediment and Soil by Pressurized Solvent Extraction, Solid-Phase Extraction, and Capillary-Column Gas Chromatography/Mass Spectrometry

    Science.gov (United States)

    Burkhardt, Mark R.; Zaugg, Steven D.; Smith, Steven G.; ReVello, Rhiannon C.

    2006-01-01

    A method for the determination of 61 compounds in environmental sediment and soil samples is described. The method was developed in response to increasing concern over the effects of endocrine-disrupting chemicals in wastewater and wastewater-impacted sediment on aquatic organisms. This method also may be used to evaluate the effects of combined sanitary and storm-sewer overflow on the water and sediment quality of urban streams. Method development focused on the determination of compounds that were chosen on the basis of their endocrine-disrupting potential or toxicity. These compounds include the alkylphenol ethoxylate nonionic surfactants and their degradates, food additives, fragrances, antioxidants, flame retardants, plasticizers, industrial solvents, disinfectants, fecal sterols, polycyclic aromatic hydrocarbons, and high-use domestic pesticides. Sediment and soil samples are extracted using a pressurized solvent extraction system. The compounds of interest are extracted from interfering matrix components by high-pressure water/isopropyl alcohol extraction. The compounds were isolated using disposable solid-phase extraction (SPE) cartridges containing chemically modified polystyrene-divinylbenzene resin. The cartridges were dried with nitrogen gas, and then sorbed compounds were eluted with methylene chloride (80 percent)-diethyl ether (20 percent) through Florisil/sodium sulfate SPE cartridge, and then determined by capillary-column gas chromatography/mass spectrometry. Recoveries in reagent-sand samples fortified at 4 to 72 micrograms averaged 76 percent ?13 percent relative standard deviation for all method compounds. Initial method reporting levels for single-component compounds ranged from 50 to 500 micrograms per kilogram. The concentrations of 20 out of 61 compounds initially will be reported as estimated with the 'E' remark code for one of three reasons: (1) unacceptably low-biased recovery (less than 60 percent) or highly variable method performance

  17. The Capillary Pressure Curve Reconstruction Based on Conventional Log Physical Properties%利用常规测井物性曲线重构毛细管压力曲线

    Institute of Scientific and Technical Information of China (English)

    王培春; 李兴丽; 张琳琳; 邢仁东

    2012-01-01

    为更好地研究盖层封闭能力和储层的岩石孔隙结构,提出一种利用常规测井曲线获得毛细管压力曲线的方法.介绍了压汞毛细管压力曲线的双曲线特征,指出毛细管压力曲线的形态由完全连通的孔隙体积、门槛压力和孔喉几何因子确定.分析了现有计算方法的不足,结合现有常规测井物性资料,对重构毛细管压力曲线的关键参数进行了大量统计分析.门槛压力与孔渗比值存在很好的拟合关系,通过建立二者之间的回归关系式可直接求取门槛压力.利用渤海地区压汞资料和常规测井曲线拟合出了压汞毛细管压力曲线.实际资料验证表明该方法能够满足油田勘探开发以及科研需要.%In order to study the seal ability of cap rock and the rock pore structure of reservoir in depth, a new method is provided to get capillary pressure curve with conventional well logging data. Introduced is hyperbolic curve feature of the capillary pressure curve, and it is indicated that the curve shape is determined by completely interconnected pore bulk, threshold pressure and pore throat geometrical factor. Analyzed are the disadvantages of existing computing methods. Combining with conventional logging data, a large number of statistic analyses are used for key parameters of restructuring capillary pressure curves. It is believed that the threshold pressure has good fitting relationship with porosity-permeability ratio, and it is possible to get the threshold pressure directly by structuring regression equation between them. Mercury injection capillary pressure curve of Bohai area is fitted with mercury-injection and conventional well logging data in this area. Practical application indicates that this method can meet oilfield exploration and research demand.

  18. Nuclear determination of saturation profiles in core plugs. Status report

    Energy Technology Data Exchange (ETDEWEB)

    Sletsgaard, J. [DTU, Inst. for Automation (Denmark)

    1996-01-01

    A method to determine liquid saturations in core plugs during flooding is of importance when the relative permeability and capillary pressure function are to be determined. This part of the EFP-93 project uses transmission of {gamma}-radiation to determine these saturations. In {gamma}-transmission measurements, the electron density of the given substance is measured. This is an advantage as compared to methods that use electric conductivity, since neither oil nor gas conducts electricity. At the moment a single {sup 137}Cs-source is used, but a theoretical investigation of whether it is possible to determine three saturations, using two radioactive sources with different {gamma}-energies, has been performed. Measurements were made on three core plugs. To make sure that the measurements could be reproduced, all the plugs had a point of reference, i.e. a mark so that it was possible to place the plug same way every time. Two computer programs for calculation of saturation and porosity and the experimental setup are listed. (EG).

  19. Capillary imbibition in parallel tubes

    Science.gov (United States)

    McRae, Oliver; Ramakrishnan, T. S.; Bird, James

    2016-11-01

    In modeling porous media two distinct approaches can be employed; the sample can be examined holistically, using global variables such as porosity, or it can be treated as a network of capillaries connected in series to various intermediate reservoirs. In forced imbibition this series-based description is sufficient to characterize the flow, due to the presence of an externally maintained pressure difference. However, in spontaneous imbibition, flow is driven by an internal capillary pressure, making it unclear whether a series-based model is appropriate. In this talk, we show using numerical simulations the dynamics of spontaneous imbibition in concentrically arranged capillary tubes. This geometry allows both tubes access to a semi-infinite reservoir but with inlets in close enough proximity to allow for interference. We compare and contrast the results of our simulations with theory and previous experiments. Schlumberger-Doll Research.

  20. Saturation curve of SiO{sub 2} component in rutile-type GeO{sub 2}: A recoverable high-temperature pressure standard from 3 GPa to 10 GPa

    Energy Technology Data Exchange (ETDEWEB)

    Leinenweber, Kurt, E-mail: kurtl@asu.edu [Dept of Chemistry, Arizona State University, Tempe, AZ (United States); Gullikson, Amber L. [Dept of Chemistry, Arizona State University, Tempe, AZ (United States); Stoyanov, Emil; Malik, Abds-Sami [Sandvik Hyperion, 6325 Huntley Rd., Worthington, OH, 43229 (United States)

    2015-09-15

    The accuracy and precision of pressure measurements and the pursuit of reliable and readily available pressure scales at simultaneous high temperatures and pressures are still topics in development in high pressure research despite many years of work. In situ pressure scales based on x-ray diffraction are widely used but require x-ray access, which is lacking outside of x-ray beam lines. Other methods such as fixed points require several experiments to bracket a pressure calibration point. In this study, a recoverable high-temperature pressure gauge for pressures ranging from 3 GPa to 10 GPa is presented. The gauge is based on the pressure-dependent solubility of an SiO{sub 2} component in the rutile-structured phase of GeO{sub 2} (argutite), and is valid when the argutite solid solution coexists with coesite. The solid solution varies strongly in composition, mainly in pressure but also somewhat in temperature, and the compositional variations are easily detected by x-ray diffraction of the recovered products because of significant changes in the lattice parameters. The solid solution is measured here on two isotherms, one at 1200 °C and the other at 1500 °C, and is developed as a pressure gauge by calibrating it against three fixed points for each temperature and against the lattice parameter of MgO measured in situ at a total of three additional points. A somewhat detailed thermodynamic analysis is then presented that allows the pressure gauge to be used at other temperatures. This provides a way to accurately and reproducibly evaluate the pressure in high pressure experiments and applications in this pressure-temperature range, and could potentially be used as a benchmark to compare various other pressure scales under high temperature conditions. - Graphical abstract: The saturation curve of SiO{sub 2} in TiO{sub 2} shows a strong pressure dependence and a strong dependence of unit cell volume on composition. This provides an opportunity to use this

  1. Usefulness of the Sum of Pulmonary Capillary Wedge Pressure and Right Atrial Pressure as a Congestion Index that Prognosticates Heart Failure Survival (from the Evaluation Study of Congestive Heart Failure and Pulmonary Artery Catheterization Effectiveness Trial).

    Science.gov (United States)

    Ma, Tony S; Paniagua, David; Denktas, Ali E; Jneid, Hani; Kar, Biswajit; Chan, Wenyaw; Bozkurt, Biykem

    2016-09-15

    In the Evaluation Study of Congestive Heart Failure and Pulmonary Artery Catheterization Effectiveness (ESCAPE) trial, use of a pulmonary artery catheter did not significantly affect advanced heart failure outcomes. However, the success of achieving the targeted hemodynamic goals of pulmonary capillary wedge pressure (PCWP) of 15 mm Hg and right atrial pressure (RAP) of 8 mm Hg and the association of these goals with clinical outcomes were not addressed. Furthermore, goals with 2 independent variables, PCWP and RAP, left room for uncertainties. We assessed the ability of a single hemodynamic target to achieve a threshold sum of PCWP and RAP as a predictor of all-cause mortality, death-or-transplantation (DT), or death-or-rehospitalization (DR) at 6 months in the pulmonary artery catheter-guided treatment arm of ESCAPE (n = 206). Patients with a posttreatment PCWP + RAP of <30 mm Hg had characteristics similar to those of the population who achieved the ESCAPE hemodynamic goals. This group had 8.7% mortality, 13.0% DT, and 58.7% DR at 6 months. The contrasting cohort with PCWP + RAP of ≥30 mm Hg had 45.3% mortality, 54.7% DT, and 84.9% DR at 6 months, with greater relative risk (RR) of death (RR 5.76), DT (RR 4.92), and DR (RR 1.80) and higher prevalence of jugular venous pulsation, edema, hepatomegaly, and ascites at admission and discharge. In conclusion, PCWP + RAP of 30 mm Hg posttreatment, obtained early in the index hospitalization, may represent as a simple congestion index that has prognostic value for heart failure survival and readmission rates at 6 months and as a warning signal for more aggressive intervention, thus warranting further validation.

  2. Harvesting liquid from unsaturated vapor - nanoflows induced by capillary condensation

    Science.gov (United States)

    Vincent, Olivier; Marguet, Bastien; Stroock, Abraham

    2016-11-01

    A vapor, even subsaturated, can spontaneously form liquid in nanoscale spaces. This process, known as capillary condensation, plays a fundamental role in various contexts, such as the formation of clouds or the dynamics of hydrocarbons in the geological subsurface. However, large uncertainties remain on the thermodynamics and fluid mechanics of the phenomenon, due to experimental challenges as well as outstanding questions about the validity of macroscale physics at the nanometer scale. We studied experimentally the spatio-temporal dynamics of water condensation in a model nanoporous medium (pore radius 2 nm), taking advantage of the color change of the material upon hydration. We found that at low relative humidities (diffusive fashion, while it occurred through a well-defined capillary-viscous imbibition front at > 60 % RH, driven by a balance between the pore capillary pressure and the condensation stress given by Kelvin equation. Further analyzing the imbibition dynamics as a function of saturation allowed us to extract detailed information about the physics of nano-confined fluids. Our results suggest excellent extension of macroscale fluid dynamics and thermodynamics even in pores 10 molecules in diameter.

  3. Advanced Technologies for Monitoring CO2 Saturation and Pore Pressure in Geologic Formations: Linking the Chemical and Physical Effects to Elastic and Transport Properties

    Energy Technology Data Exchange (ETDEWEB)

    Mavko, G.; Vanorio, T.; Vialle, S.; Saxena, N.

    2014-03-31

    Ultrasonic P- and S-wave velocities were measured over a range of confining pressures while injecting CO2 and brine into the samples. Pore fluid pressure was also varied and monitored together with porosity during injection. Effective medium models were developed to understand the mechanisms and impact of observed changes and to provide the means for implementation of the interpretation methodologies in the field. Ultrasonic P- and S-wave velocities in carbonate rocks show as much as 20-50% decrease after injection of the reactive CO2-brine mixture; the changes were caused by permanent changes to the rock elastic frame associated with dissolution of mineral. Velocity decreases were observed under both dry and fluid-saturated conditions, and the amount of change was correlated with the initial pore fabrics. Scanning Electron Microscope images of carbonate rock microstructures were taken before and after injection of CO2-rich water. The images reveal enlargement of the pores, dissolution of micrite (micron-scale calcite crystals), and pitting of grain surfaces caused by the fluid- solid chemical reactivity. The magnitude of the changes correlates with the rock microtexture – tight, high surface area samples showed the largest changes in permeability and smallest changes in porosity and elastic stiffness compared to those in rocks with looser texture and larger intergranular pore space. Changes to the pore space also occurred from flow of fine particles with the injected fluid. Carbonates with grain-coating materials, such as residual oil, experienced very little permanent change during injection. In the tight micrite/spar cement component, dissolution is controlled by diffusion: the mass transfer of products and reactants is thus slow and the fluid is expected to be close to thermodynamical equilibrium with the calcite, leading to very little dissolution, or even precipitation. In the microporous rounded micrite and macropores, dissolution is controlled by

  4. Modeling the Capillary Pressure for the Migration of the Liquid Phase in Granular Solid-Liquid-Vapor Systems: Application to the Control of the Composition Profile in W-Cu FGM Materials

    Science.gov (United States)

    Missiaen, Jean-Michel; Raharijaona, Jean-Joël; Delannay, Francis

    2016-11-01

    A model is developed to compute the capillary pressure for the migration of the liquid phase out or into a uniform solid-liquid-vapor system. The capillary pressure is defined as the reduction of the overall interface energy per volume increment of the transferred fluid phase. The model takes into account the particle size of the solid particle aggregate, the packing configuration (coordination number, porosity), the volume fractions of the different phases, and the values of the interface energies in the system. The model is used for analyzing the stability of the composition profile during processing of W-Cu functionally graded materials combining a composition gradient with a particle size gradient. The migration pressure is computed with the model in two stages: (1) just after the melting of copper, i.e., when sintering and shape accommodation of the W particle aggregate can still be neglected and (2) at high temperature, when the system is close to full density with equilibrium particle shape. The model predicts well the different stages of liquid-phase migration observed experimentally.

  5. Leukocytes in capillary flow.

    Science.gov (United States)

    Schmid-Schönbein, G W; Lee, J

    1995-01-01

    During disease, the flow of blood cells through the capillary network is one of the most perilous events in the microcirculation. Capillary distensibility, cytoplasmic activity of endothelial cells, red cells and leukocytes play an important role in capillary perfusion. Occlusion of capillaries is one of the early signs of vascular failure and is encountered in many different conditions and organs. Adhesion of leukocytes to the endothelium via expression of membrane adhesion molecules leads to microvascular entrapment with capillary occlusion.

  6. Measurement of Capillary Radius and Contact Angle within Porous Media.

    Science.gov (United States)

    Ravi, Saitej; Dharmarajan, Ramanathan; Moghaddam, Saeed

    2015-12-01

    The pore radius (i.e., capillary radius) and contact angle determine the capillary pressure generated in a porous medium. The most common method to determine these two parameters is through measurement of the capillary pressure generated by a reference liquid (i.e., a liquid with near-zero contact angle) and a test liquid. The rate of rise technique, commonly used to determine the capillary pressure, results in significant uncertainties. In this study, we utilize a recently developed technique for independently measuring the capillary pressure and permeability to determine the equivalent minimum capillary radii and contact angle of water within micropillar wick structures. In this method, the experimentally measured dryout threshold of a wick structure at different wicking lengths is fit to Darcy's law to extract the maximum capillary pressure generated by the test liquid. The equivalent minimum capillary radii of different wick geometries are determined by measuring the maximum capillary pressures generated using n-hexane as the working fluid. It is found that the equivalent minimum capillary radius is dependent on the diameter of pillars and the spacing between pillars. The equivalent capillary radii of micropillar wicks determined using the new method are found to be up to 7 times greater than the current geometry-based first-order estimates. The contact angle subtended by water at the walls of the micropillars is determined by measuring the capillary pressure generated by water within the arrays and the measured capillary radii for the different geometries. This mean contact angle of water is determined to be 54.7°.

  7. Capillary Micro-Flow Through a Fiber Bundle(Ⅰ)

    Institute of Scientific and Technical Information of China (English)

    ZHU Ying-dan; WANG Ji-hui; TAN Hua; GAO Guo-qiang

    2004-01-01

    The present work considered the capillary micro-flow through a fiber bundle. The resin heights in the fiber bundle as a function of time were used to determine the experimental values of capillary pressure and the permeability by the nonlinear regression fitting method. The fitting curves showed a good agreement with experiments. However, these values of capillary pressure from short- time experiments were much lower than the theoretical results from the Yang-Laplace Equation. More accurate capillary pressure was predicted from the presented long-run experiment.

  8. Incorporation of the capillary hysteresis model HYSTR into the numerical code TOUGH

    Energy Technology Data Exchange (ETDEWEB)

    Niemi, A.; Bodvarsson, G.S.; Pruess, K.

    1991-11-01

    As part of the work performed to model flow in the unsaturated zone at Yucca Mountain Nevada, a capillary hysteresis model has been developed. The computer program HYSTR has been developed to compute the hysteretic capillary pressure -- liquid saturation relationship through interpolation of tabulated data. The code can be easily incorporated into any numerical unsaturated flow simulator. A complete description of HYSTR, including a brief summary of the previous hysteresis literature, detailed description of the program, and instructions for its incorporation into a numerical simulator are given in the HYSTR user`s manual (Niemi and Bodvarsson, 1991a). This report describes the incorporation of HYSTR into the numerical code TOUGH (Transport of Unsaturated Groundwater and Heat; Pruess, 1986). The changes made and procedures for the use of TOUGH for hysteresis modeling are documented.

  9. Selection of materials for tokamak plasma facing elements based on a liquid tin capillary pore system

    Science.gov (United States)

    Lyublinski, I. E.; Vertkov, A. V.; Zharkov, M. Yu; Sevryukov, O. N.; Dzhumaev, P. S.; Shumskiy, V. A.; Ivannikov, A. A.

    2016-09-01

    Capillary-Pore Systems (CPS) filled by liquid metals are considered as an alternative solution of materials choice for plasma facing component of tokamak reactor. Tin is viewed as one of the candidates for CPS because it has lower corrosiveness than gallium and lower saturated vapour pressure compared to lithium. The corrosion resistance of Mo, Nb and W in pure liquid tin was investigated. The corrosion tests were carried out in the static isothermal conditions at a temperature up to 1050°C. As a result of the corrosion study, it was found that Mo does not corrode in liquid Sn, as opposed to Nb and is compatible with liquid tin in temperatures of up to approx. 1000°C. This allows considering Mo as an alloy base material of the in-vessel tokamak elements based on liquid tin capillary pore systems.

  10. Design and performance test of miniature capillary pumped loop for electronics cooling

    Institute of Scientific and Technical Information of China (English)

    万珍平; 皮丕辉; 付永清; 汤勇

    2008-01-01

    Considering two characteristics of compact heat dissipation room and high heat flux, a novel miniature capillary pumped loop (MCPL) for electronics cooling was proposed. MCPL consists of evaporator, condenser, vapor and liquid line dissipates heat by boiling and condensation of working fluids with no extra power consumption. Working fluid circulation is ensured by vapor pressure and capillary head. Saturated wick screens vapor and liquid, and ensures one-way flow of working fluid with no extra valve. In order to promote heat dissipation capacity of MCPL, the intensified boiling and condensation structures are embedded into evaporator and condenser respectively, which are useful to increasing boiling and condensation efficiency. Startup and run characteristics are tested by experiments in the condition of different power inputs and working fluids. MCPL is capable of dissipating 80 W of thermal energy and keeping the bottom substrate temperature of evaporator at 80 ℃.

  11. Using X-ray computed tomography to evaluate the initial saturation resulting from different saturation procedures

    DEFF Research Database (Denmark)

    Christensen, Britt Stenhøj Baun; Wildenschild, D; Jensen, K.H.

    2006-01-01

    saturation. In this study three techniques often applied in the laboratory have been evaluated for a fine sand sample: (1) venting of the sample with carbon dioxide prior to saturation, (2) applying vacuum to the sample in the beginning of the saturation procedure, and finally (3) the use of degassed water...... with pressurized nitrogen between each saturation and allowed to saturate for the same length of time for all the different procedures. Both gravimetric measurements and CT attenuation levels showed that venting the sample with carbon dioxide prior to saturation clearly improved initial saturation whereas the use...

  12. Saturation process of nonlinear standing waves

    Institute of Scientific and Technical Information of China (English)

    马大猷; 刘克

    1996-01-01

    The sound pressure of the nonlinear standing waves is distorted as expected, but also tends to saturate as being found in standing-wave tube experiments with increasing sinusoidal excitation. Saturation conditions were not actually reached, owing to limited excitation power, but the evidence of tendency to saturation is without question. It is the purpose of this investigation to find the law of saturation from the existing experimental data. The results of curve fitting indicate that negative feedback limits the growth of sound pressure with increasing excitation, the growth of the fundamental and the second harmonic by the negative feedback of their sound pressures, and the growth of the third and higher harmonics, however, by their energies (sound pressures squared). The growth functions of all the harmonics are derived, which are confirmed by the experiments. The saturation pressures and their properties are found.

  13. Generalized formula for the surface stiffness of fluid-saturated porous media containing parallel pore channels

    Energy Technology Data Exchange (ETDEWEB)

    Nagy, P.B.; Nayfeh, A.H. [Department of Aerospace Engineering and Engineering Mechanics, University of Cincinnati, Cincinnati, Ohio 45221 (United States)

    1995-09-25

    The surface stiffness of a fluid-saturated porous solid is defined as the ratio between a small change in capillary pressure and the average displacement of the boundary due to the resulting rise or fall of the fluid level in the pore channels. When the surface pores are structurally open, the surface stiffness is entirely due to the stiffness of the microscopic fluid membranes extended by capillary forces over the surface pores. Due to interfacial tension between the immiscible wetting fluid in the pores and nonwetting fluid (air) above the surface, essentially closed-pore boundary conditions can prevail at the interface. It has recently been shown that the surface stiffness of a porous material containing cylindrical pores can be calculated simply as the surface tension of the saturating fluid divided by the static permeability of the porous solid [P. B. Nagy, Appl. Phys. Lett. {bold 60}, 2735 (1992)]. In this letter, we show that the same simple relationship can be generalized for the surface stiffness of fluid-saturated porous media containing parallel prismatic pore channels of any number, size, or shape. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  14. Dynamic characterization of partially saturated engineered porous media and gas diffusion layers using hydraulic admittance

    Science.gov (United States)

    Cheung, Perry; Fairweather, Joseph D.; Schwartz, Daniel T.

    2012-09-01

    Simple laboratory methods for determining liquid water distribution in polymer electrolyte membrane fuel cell gas diffusion layers (GDLs) are needed to engineer better GDL materials. Capillary pressure vs. liquid saturation measurements are attractive, but lack the ability to probe the hydraulic interconnectivity and distribution within the pore structure. Hydraulic admittance measurements of simple capillary bundles have recently been shown to nicely measure characteristics of the free-interfaces and hydraulic path. Here we examine the use of hydraulic admittance with a succession of increasingly complex porous media, starting with a laser-drilled sample with 154 asymmetric pores and progress to the behavior of Toray TGP-H090 carbon papers. The asymmetric laser-drilled sample clearly shows hydraulic admittance measurements are sensitive to sample orientation, especially when examined as a function of saturation state. Finite element modeling of the hydraulic admittance is consistent with experimental measurements. The hydraulic admittance spectra from GDL samples are complex, so we examine trends in the spectra as a function of wet proofing (0% and 40% Teflon loadings) as well as saturation state of the GDL. The presence of clear peaks in the admittance spectra for both GDL samples suggests a few pore types are largely responsible for transporting liquid water.

  15. Chromatographic selectivity of poly(alkyl methacrylate-co-divinylbenzene) monolithic columns for polar aromatic compounds by pressure-driven capillary liquid chromatography.

    Science.gov (United States)

    Lin, Shu-Ling; Wang, Chih-Chieh; Fuh, Ming-Ren

    2016-10-05

    In this study, divinylbenzene (DVB) was used as the cross-linker to prepare alkyl methacrylate (AlMA) monoliths for incorporating π-π interactions between the aromatic analytes and AlMA-DVB monolithic stationary phases in capillary LC analysis. Various AlMA/DVB ratios were investigated to prepare a series of 30% AlMA-DVB monolithic stationary phases in fused-silica capillaries (250-μm i.d.). The physical properties (such as porosity, permeability, and column efficiency) of the synthesized AlMA-DVB monolithic columns were investigated for characterization. Isocratic elution of phenol derivatives was first employed to evaluate the suitability of the prepared AlMA-DVB columns for small molecule separation. The run-to-run (0.16-1.20%, RSD; n = 3) and column-to-column (0.26-2.95%, RSD; n = 3) repeatabilities on retention times were also examined using the selected AlMA-DVB monolithic columns. The π-π interactions between the aromatic ring and the DVB-based stationary phase offered better recognition on polar analytes with aromatic moieties, which resulted in better separation resolution of aromatic analytes on the AlMA-DVB monolithic columns. In order to demonstrate the capability of potential environmental and/or food safety applications, eight phenylurea herbicides with single benzene ring and seven sulfonamide antibiotics with polyaromatic moieties were analyzed using the selected AlMA-DVB monolithic columns.

  16. Numerical solution for 5-layer laminate technique to determine saturation solubility of a drug in a thin film of pressure sensitive adhesive.

    Science.gov (United States)

    Bänsch, Eberhard; Reismann, Simone; Lee, Geoffrey

    2014-08-01

    A numerical solution of the one-dimensional diffusion equation is presented to describe the 5-layer laminate technique for estimating the saturation solubility of a drug in a thin polymer film. The boundary and initial conditions encompass a donor layer, a separating membrane, and an acceptor layer. Alteration of the drug's partition coefficient between donor and separating membrane has little influence on drug accumulation with the acceptor. The diffusivity in the separating membrane should be high to promote a short experimental time to achieve saturation equilibrium in the acceptor layer. The essential parameter to give rapid equilibrium is the thickness of the acceptor polymer film. For values of diffusivity typical for drugs of molecular weight around 500 an acceptor layer thickness of 10 µm-20 µm is required to achieve equilibrium within less than 10 d. These simulations allow the selection of suitable experimental conditions to make the 5-layer laminate technique a viable method for routine use.

  17. Proper Use of Capillary Number in Chemical Flooding

    Directory of Open Access Journals (Sweden)

    Hu Guo

    2017-01-01

    Full Text Available Capillary number theory is very important for chemical flooding enhanced oil recovery. The difference between microscopic capillary number and the microscopic one is easy to confuse. After decades of development, great progress has been made in capillary number theory and it has important but sometimes incorrect application in EOR. The capillary number theory was based on capillary tube bundles and Darcy’s law hypothesis, and this should always be kept in mind when used in chemical flooding EOR. The flow in low permeability porous media often shows obvious non-Darcy effects, which is beyond Darcy’s law. Experiments data from ASP flooding and SP flooding showed that remaining oil saturation was not always decreasing as capillary number kept on increasing. Relative permeability was proved function of capillary number; its rate dependence was affected by capillary end effects. The mobility control should be given priority rather than lowering IFT. The displacement efficiency was not increased as displacement velocity increased as expected in heavy oil chemical flooding. Largest capillary number does not always make highest recovery in chemical flooding in heterogeneous reservoir. Misuse of CDC in EOR included the ignorance of mobility ratio, Darcy linear flow hypothesis, difference between microscopic capillary number and the microscopic one, and heterogeneity caused flow regime alteration. Displacement of continuous oil or remobilization of discontinuous oil was quite different.

  18. Behavior of water in supercritical CO2: adsorption and capillary condensation in porous media

    Science.gov (United States)

    Heath, J. E.; Bryan, C. R.; Dewers, T. A.; Wang, Y.

    2011-12-01

    The chemical potential of water in supercritical CO2 (scCO2) may play an important role in water adsorption, capillary condensation, and evaporation under partially saturated conditions at geologic CO2 storage sites, especially if initially anhydrous CO2 is injected. Such processes may affect residual water saturations, relative permeability, shrink/swell of clays, and colloidal transport. We have developed a thermodynamic model of water or brine film thickness as a function of water relative humidity in scCO2. The model is based on investigations of liquid water configuration in the vadose zone and uses the augmented Young-Laplace equation, which incorporates both adsorptive and capillary components. The adsorptive component is based on the concept of disjoining pressure, which reflects force per area normal to the solid and water/brine-scCO2 interfaces. The disjoining pressure includes van der Waals, electrostatic, and structural interactions. The van der Waals term includes the effects of mutual dissolution of CO2 and water in the two fluid phases on partial molar volumes, dielectric coefficients, and refractive indices. Our approach treats the two interfaces as asymmetric surfaces in terms of charge densities and electrostatic potentials. We use the disjoining pressure isotherm to evaluate the type of wetting (e.g., total or partial wetting) for common reservoir and caprock minerals and kerogen. The capillary component incorporates water activity and is applied to simple pore geometries with slits and corners. Finally, we compare results of the model to a companion study by the coauthors on measurement of water adsorption to mineral phases using a quartz-crystal microbalance. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  19. Saturated fat (image)

    Science.gov (United States)

    Saturated fat can raise blood cholesterol and can put you at risk for heart disease and stroke. You ... or limit any foods that are high in saturated fat. Sources of saturated fat include whole-milk dairy ...

  20. Capillary Interactions between a Probe Tip and a Nanoparticle

    Institute of Scientific and Technical Information of China (English)

    SUN Li-Ning; WANG Le-Feng; RONG Wei-Bin

    2008-01-01

    To understand capillary interactions between probe tips and nanoparticles under ambient conditions,a theoretical model of capillary forces between them is developed based on the geometric relations. It is found that the contribution of surface tension force to the total capillary force attains to similar order of magnitude as the capillary pressure force in many cases.It is also shown that the tip shape and the radial distance of the meniscus have great influence on the capillary force.The capillary force decreases with the increasing separation distances,and the variance of the contact angles may change the magnitudes of capillary forces several times at large radial distances.The applicability of the symmetric meniscus approximation is discussed.

  1. 二甲基苯基乙氧基硅烷饱和蒸汽压的研究%Saturated vapor pressure of pure ethoxydimethylphenylsilane

    Institute of Scientific and Technical Information of China (English)

    张宝华; 伍川; 董红; 蒋剑雄

    2012-01-01

    High pure ethoxydimethylphenylsilane was obtained by vacuum distillation method and its saturated vapor temperature from 1. 325 kPa to 99. 325 kPa was measured by inclined ebulliometer. The An-toine constants were obtained,I. E. ,A =5. 077 80,B =969. 550,C = - 152. 478 K. The maximum relative difference between the calculated saturated temperature and the experimental data was no more than 0. 24% . The molar enthalpy of vaporization ( △vapHm) of ethoxydimethylphenylsilane from 348. 32 K to 467. 92 K was estimated by Clausius-Clapeyron equation.%通过真空减压精馏分离得到高纯度二甲基苯基乙氧基硅烷,利用斜式沸点仪测定二甲基苯基乙氧基硅烷在1.325~99.325 kPa范围内的饱和温度并利用Antoine方程进行关联,得到Antoine常数A=5.077 80,B=969.550,C=-152.478 K.饱和温度计算值与实测值之间的最大相对偏差不大于0.24%.还利用Clausius-Clapeyron方程估算了348.32 ~467.92 K范围内二甲基苯基乙氧基硅烷的摩尔蒸发焓.

  2. Advances in Capillary Chromatography%毛细管色谱的进展

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Capillary columns are used in both capillary liquid chromatography and capillary electrochromatography. The design for capillary liquid chromatography is discussed in comparison with capillary gas chromatography. The difference of diffusion coefficient in gas and liquid phase is a key role. The study for obtaining a high performance capillary liquid chromatography is discussed. Capillary electrochromatography is recently interesting for its instinct ability to realize a high performance chromatography. Capillary electrochromatography with and without pressurized flow is reviewed briefly. Instrumentation for capillary electrochromatography with pressurized flow is discussed. The port of splitting, and gradient elution of both solution and potential are described. The new findings of both the variation of column resistance and capacity factor according to the value of applied electric voltage are also discussed.

  3. 甘蔗糖厂静压饱和浸渗提汁实验研究%Juice Extraction Progress of Static Pressure Saturated Infiltration in Cane Sugar Factory

    Institute of Scientific and Technical Information of China (English)

    孙潇; 陆浩; 高俊永; 黄向阳

    2011-01-01

    提出了一种适用于甘蔗糖厂的静压饱和浸渗提汁工艺,通过一定压力作用于蔗渣,采用回流饱和浸渗工艺,达到提汁的目的.实验结果表明:采用新工艺后可使蔗渣的水分、锤度、转光度比传统压榨降低6.6%、9.7%、5.8%,抽出率提高0.4%,可为甘蔗提汁领域提供新途径.%A new juice extraction process was presented using Static Pressure Saturated Infiltration method. In this method, a certain pressure was applied to bagasse, and saturated infiltration technique was employed to extract sugar juice. The results show that the new technology can decrease bagasse moisture, Brix, poi by 6.6%,9.7%, 5.8% respectively, and increase sucrose extraction by 0.4%, as compared to the traditional press. It can provide a new way for sugar cane juice extraction process.

  4. Evolution Characteristics of Saturated Hydrocarbons of Enclosed Organic Matter in Carbonate Minerals in Tieling Limestone Under High Temperature and High Pressure

    Institute of Scientific and Technical Information of China (English)

    解启来; 陆明勇; 等

    2000-01-01

    The enclosed organic matter chiefly releases lower carbon-number n-alkanes under high temperature and high pressure,while the kerogen mainly produces higher carbon-number n-alkanes.The rsidual hydrocarbons generated by both kerogen and enclosed organic matter in the Tieling limestone contain abundant tricyclic terpanes,pentacyclic triterpanes and steranes,but the contents of tetracyclic terpanes and 25-norhopane are lower.The residual enclosed orgainc matter shows the same distribution characteristics of n-alkanes,steranes and terpanes as that of the original bitumaen A,i.e.,the higher contents of triterpanes and tetracyclic terpanes,the higher ratios of 25-norhopanes over regular hopanes and markedly degraded steranes.By comparing the residual hydrocarbon.residual enclosed orgainc matter and original enclosed orgainc matter.it can be concluded that steranes and terpanes in the residual hydrocarbons are produced mainly by the kerogen and subordinately by the residual enclosed organic matter,the steranes and terpanes do not enter into the residual enclosed organic matter,and the thermal evolution of the residual enclosed organic matter maintains its unique character.Furthermore,pressure retards the pyrolysis of higher carbon-number alkanes and influences the isomerization ratios of C29-steranes,making 20S/(20S+20R) lower under the higher pressure than that under lower pressure,Higher pressure retards the thermal evolution of organic matter.

  5. Uptake of water droplets by nonwetting capillaries

    CERN Document Server

    Willmott, Geoff R; Hendy, Shaun C

    2010-01-01

    We present direct experimental evidence that water droplets can spontaneously penetrate non-wetting capillaries, driven by the action of Laplace pressure due to high droplet curvature. Using high-speed optical imaging, microcapillaries of radius 50 to 150 micron, and water microdroplets of average radius between 100 and 1900 micron, we demonstrate that there is a critical droplet radius below which water droplets can be taken up by hydrophobised glass and polytetrafluoroethylene (PTFE) capillaries. The rate of capillary uptake is shown to depend strongly on droplet size, with smaller droplets being absorbed more quickly. Droplet size is also shown to influence meniscus motion in a pre-filled non-wetting capillary, and quantitative measurements of this effect result in a derived water-PTFE static contact angle between 96 degrees and 114 degrees. Our measurements confirm recent theoretical predictions and simulations for metal nanodroplets penetrating carbon nanotubes (CNTs). The results are relevant to a wide ...

  6. DNA Sequencing Using capillary Electrophoresis

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Barry Karger

    2011-05-09

    The overall goal of this program was to develop capillary electrophoresis as the tool to be used to sequence for the first time the Human Genome. Our program was part of the Human Genome Project. In this work, we were highly successful and the replaceable polymer we developed, linear polyacrylamide, was used by the DOE sequencing lab in California to sequence a significant portion of the human genome using the MegaBase multiple capillary array electrophoresis instrument. In this final report, we summarize our efforts and success. We began our work by separating by capillary electrophoresis double strand oligonucleotides using cross-linked polyacrylamide gels in fused silica capillaries. This work showed the potential of the methodology. However, preparation of such cross-linked gel capillaries was difficult with poor reproducibility, and even more important, the columns were not very stable. We improved stability by using non-cross linked linear polyacrylamide. Here, the entangled linear chains could move when osmotic pressure (e.g. sample injection) was imposed on the polymer matrix. This relaxation of the polymer dissipated the stress in the column. Our next advance was to use significantly lower concentrations of the linear polyacrylamide that the polymer could be automatically blown out after each run and replaced with fresh linear polymer solution. In this way, a new column was available for each analytical run. Finally, while testing many linear polymers, we selected linear polyacrylamide as the best matrix as it was the most hydrophilic polymer available. Under our DOE program, we demonstrated initially the success of the linear polyacrylamide to separate double strand DNA. We note that the method is used even today to assay purity of double stranded DNA fragments. Our focus, of course, was on the separation of single stranded DNA for sequencing purposes. In one paper, we demonstrated the success of our approach in sequencing up to 500 bases. Other

  7. Intramedullary capillary haemangioma.

    LENUS (Irish Health Repository)

    Kelleher, T

    2012-02-03

    Intramedullary capillary haemangioma is extremely rare and only four cases have been previously reported. We describe a further case, outlining the clinical, radiological, surgical and pathological features.

  8. Characterization of immiscible fluid displacement processes with various capillary numbers and viscosity ratios in 3D natural sandstone

    Science.gov (United States)

    Tsuji, Takeshi; Jiang, Fei; Christensen, Kenneth T.

    2016-09-01

    To characterize the influence of reservoir conditions upon multiphase flow, we calculated fluid displacements (drainage processes) in 3D pore spaces of Berea sandstone using two-phase lattice Boltzmann (LB) simulations. The results of simulations under various conditions were used to classify the resulting two-phase flow behavior into three typical fluid displacement patterns on the diagram of capillary number (Ca) and viscosity ratio of the two fluids (M). In addition, the saturation of the nonwetting phase was calculated and mapped on the Ca-M diagram. We then characterized dynamic pore-filling events (i.e., Haines jumps) from the pressure variation of the nonwetting phase, and linked this behavior to the occurrence of capillary fingering. The results revealed the onset of capillary fingering in 3D natural rock at a higher Ca than in 2D homogeneous granular models, with the crossover region between typical displacement patterns broader than in the homogeneous granular model. Furthermore, saturation of the nonwetting phase mapped on the Ca-M diagram significantly depends on the rock models. These important differences between two-phase flow in 3D natural rock and in 2D homogeneous models could be due to the heterogeneity of pore geometry in the natural rock and differences in pore connectivity. By quantifying two-phase fluid behavior in the target reservoir rock under various conditions (e.g., saturation mapping on the Ca-M diagram), our approach could provide useful information for investigating suitable reservoir conditions for geo-fluid management (e.g., high CO2 saturation in CO2 storage).

  9. Modeling seismic stimulation: Enhanced non-aqueous fluid extraction from saturated porous media under pore-pressure pulsing at low frequencies

    Science.gov (United States)

    Lo, Wei-Cheng; Sposito, Garrison; Huang, Yu-Han

    2012-03-01

    Seismic stimulation, the application of low-frequency stress-pulsing to the boundary of a porous medium containing water and a non-aqueous fluid to enhance the removal of the latter, shows great promise for both contaminated groundwater remediation and enhanced oil recovery, but theory to elucidate the underlying mechanisms lag significantly behind the progress achieved in experimental research. We address this conceptual lacuna by formulating a boundary-value problem to describe pore-pressure pulsing at seismic frequencies that is based on the continuum theory of poroelasticity for an elastic porous medium permeated by two immiscible fluids. An exact analytical solution is presented that is applied numerically using elasticity parameters and hydraulic data relevant to recent proof-of-principle laboratory experiments investigating the stimulation-induced mobilization of trichloroethene (TCE) in water flowing through a compressed sand core. The numerical results indicated that significant stimulation-induced increases of the TCE concentration in effluent can be expected from pore-pressure pulsing in the frequency range of 25-100 Hz, which is in good agreement with what was observed in the laboratory experiments. Sensitivity analysis of our numerical results revealed that the TCE concentration in the effluent increases with the porous medium framework compressibility and the pulsing pressure. Increasing compressibility also leads to an optimal stimulation response at lower frequencies, whereas changing the pulsing pressure does not affect the optimal stimulation frequency. Within the context of our model, the dominant physical cause for enhancement of non-aqueous fluid mobility by seismic stimulation is the dilatory motion of the porous medium in which the solid and fluid phases undergo opposite displacements, resulting in stress-induced changes of the pore volume.

  10. An Integrated Capillary, Buoyancy, and Viscous-Driven Model for Brine/CO2Relative Permeability in a Compositional and Parallel Reservoir Simulator

    KAUST Repository

    Kong, X.

    2012-11-03

    The effectiveness of CO2 storage in the saline aquifers is governed by the interplay of capillary, viscous, and buoyancy forces. Recent experimental study reveals the impact of pressure, temperature, and salinity on interfacial tension (IFT) between CO2 and brine. The dependence of CO2-brine relative permeability and capillary pressure on pressure (IFT) is also clearly evident in published experimental results. Improved understanding of the mechanisms that control the migration and trapping of CO2 in subsurface is crucial to design future storage projects that warrant long-term and safe containment. Simulation studies ignoring the buoyancy and also variation in interfacial tension and the effect on the petrophysical properties such as trapped CO2 saturations, relative permeability, and capillary pressure have a poor chance of making accurate predictions of CO2 injectivity and plume migration. We have developed and implemented a general relative permeability model that combines effects of pressure gradient, buoyancy, and IFT in an equation of state (EOS) compositional and parallel simulator. The significance of IFT variations on CO2 migration and trapping is assessed.

  11. Evaluating the Influence of Pore Architecture and Initial Saturation on Wettability and Relative Permeability in Heterogeneous, Shallow-Shelf Carbonates

    Energy Technology Data Exchange (ETDEWEB)

    Byrnes, Alan P.; Bhattacharya, Saibal; Victorine, John; Stalder, Ken

    2007-09-30

    Thin (3-40 ft thick), heterogeneous, limestone and dolomite reservoirs, deposited in shallow-shelf environments, represent a significant fraction of the reservoirs in the U.S. midcontinent and worldwide. In Kansas, reservoirs of the Arbuckle, Mississippian, and Lansing-Kansas City formations account for over 73% of the 6.3 BBO cumulative oil produced over the last century. For these reservoirs basic petrophysical properties (e.g., porosity, absolute permeability, capillary pressure, residual oil saturation to waterflood, resistivity, and relative permeability) vary significantly horizontally, vertically, and with scale of measurement. Many of these reservoirs produce from structures of less than 30-60 ft, and being located in the capillary pressure transition zone, exhibit vertically variable initial saturations and relative permeability properties. Rather than being simpler to model because of their small size, these reservoirs challenge characterization and simulation methodology and illustrate issues that are less apparent in larger reservoirs where transition zone effects are minor and most of the reservoir is at saturations near S{sub wirr}. These issues are further augmented by the presence of variable moldic porosity and possible intermediate to mixed wettability and the influence of these on capillary pressure and relative permeability. Understanding how capillary-pressure properties change with rock lithology and, in turn, within transition zones, and how relative permeability and residual oil saturation to waterflood change through the transition zone is critical to successful reservoir management and as advanced waterflood and improved and enhanced recovery methods are planned and implemented. Major aspects of the proposed study involve a series of tasks to measure data to reveal the nature of how wettability and drainage and imbibition oil-water relative permeability change with pore architecture and initial water saturation. Focus is placed on

  12. MRI investigation of water-oil two phase flow in straight capillary, bifurcate channel and monolayered glass bead pack.

    Science.gov (United States)

    Liu, Yu; Jiang, Lanlan; Zhu, Ningjun; Zhao, Yuechao; Zhang, Yi; Wang, Dayong; Yang, Mingjun; Zhao, Jiafei; Song, Yongchen

    2015-09-01

    The study of immiscible fluid displacement between aqueous-phase liquids and non-aqueous-phase liquids in porous media is of great importance to oil recovery, groundwater contamination, and underground pollutant migration. Moreover, the attendant viscous, capillary, and gravitational forces are essential to describing the two-phase flows. In this study, magnetic resonance imaging was used to experimentally examine the detailed effects of the viscous, capillary, and gravitational forces on water-oil flows through a vertical straight capillary, bifurcate channel, and monolayered glass-bead pack. Water flooding experiments were performed at atmospheric pressure and 37.8°C, and the evolution of the distribution and saturation of the oil as well as the characteristics of the two-phase flow were investigated and analyzed. The results showed that the flow paths, i.e., the fingers of the displacing phase, during the immiscible displacement in the porous medium were determined by the viscous, capillary, and gravitational forces as well as the sizes of the pores and throats. The experimental results afford a fundamental understanding of immiscible fluid displacement in a porous medium.

  13. The microbial-kill characteristics of saturated steam plus 1,000 to 10,000 ppm hydrogen peroxide at atmospheric pressure.

    Science.gov (United States)

    Pflug, Irving J; Melgaard, Hans L; Schaffer, Shawn M; Lysfjord, Jack P

    2008-01-01

    This is the report of a project carried out to determine the microbial-kill characteristics of saturated steam plus hydrogen peroxide (H2O2) using a specially-constructed test apparatus. Spores on stainless-steel planchets were inserted into a flowing gaseous atmosphere of steam plus H2O2 for a timed exposure to the lethal agent. The specially-designed test apparatus and its operating parameters are described. Geobacillus stearothermophilus (former name, Bacillus stearothermophilus) spore-death rates were evaluated in several spore-planchet handling modes. Enumeration microbial recovery methods were used. The data were analyzed using survivor-curve methods; D-values were calculated using the initial number of spores per planchet and the number of spores surviving the process. Extensive tests were carried out using Geobacillus stearothermophilus spores; limited tests were carried out using Bacillus smithii ATCC 51232 (former name, Bacillus coagulans), Bacillus macerans, and Bacillus subtilis, subtilis ATCC 35021 spores (former name, Bacillus subtilis, CCC 5230, Kerns 15U). For G. stearothermophilus spores subjected to steam plus H2O2 and recovered using the 2B procedure (planchets deposited in sterile, 100-mL bottles containing 50.0 mL of buffer immediately after they were subjected to the steam-H2O2 condition; 11 experiments), the mean D-value was 0.48 min at 2,500 ppm and 0.22 min at 7,500 ppm. The application of steam plus H2O2 to the sterilization of barrier isolator enclosures is discussed.

  14. An axial approach to detection in capillary electrophoresis

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, J.A.

    1993-05-01

    Our approach involves on-axis illumination of the compounds inside the capillary detection region and is applied to absorbance and fluorescence detection. Absorbance measurements were made by focussing an incident laser beam into one capillary end; by using signals collected over the entire length of analyte band, this enhances the analytical path length of conventional absorbance detection 60x. This instrument offers a 15x improvement in detection limits. Three fluorescence detection experiments are discussed, all of which involve insertion of an optical fiber into capillary. The first uses a high refractive index liquid phase to obtain total internal reflectance along capillary axis, this reducing light scatter. The second uses a charge-coupled device camera for simultaneous imaging of a capillary array (this may be useful in genome sequencing, etc.). The third is a study of fluid motion inside the capillary under pressure-driven and electroosmotic flow. The thesis is divided into four parts. Figs, tabs.

  15. Capillary Bridges between Soft Substrates

    Science.gov (United States)

    Wexler, Jason S.; Heard, Tiara M.; Stone, Howard A.

    2014-02-01

    A wetting droplet trapped in the thin gap between two elastic bodies will deflect the bodies towards one another. The deformation increases the total capillary adhesion force by increasing the contact radius and narrowing the gap height. For flat droplets, with a large ratio of radius to gap height, the Laplace pressure causes surface deformations that are orders of magnitude larger than those induced by a sessile droplet of the same radius. We present experiments, scalings, and closed-form solutions that describe the deformation. Using variational techniques, we also show that the problem exhibits a bifurcation, where the gap spontaneously closes due to an incremental increase in drop volume.

  16. Application of Power Generation Technology with Low-pressure Saturated Steam in Xuanhua Steel%低压饱和蒸汽发电技术在宣钢的应用

    Institute of Scientific and Technical Information of China (English)

    闫新明

    2014-01-01

    利用低压饱和蒸汽发电已成为钢铁企业的共识,就2013年宣钢新建一台14 MW级间再热补凝汽式汽轮发电机的成功典例,说明余热蒸汽发电的节能效益和推广价值。%The technology of power generation with low-pressure saturated steam has been generally accepted in domestic steel industry. The energy saving effect and promotion value of power generation with vapour from waste heat are demonstrated with the successful example of the 14 MW reheat condensing steam turbine newly built in Xuanhua Steel.

  17. Nuclear reactions in deuterium-saturated palladium under irradiation by 10 MeV γ-quanta, in dense molecular deuterium at 1.2 kbar pressure

    Science.gov (United States)

    Didyk, A. Yu.; Wisniewski, R. S.

    2013-08-01

    A high-pressure chamber with a Pd-rod inside was filled up with 1.2 kbar molecular deuterium (DHPC). Then the saturated by deuterium palladium rod was irradiated during 18 hours by 11 MeV braking γ-quanta at 11-13 μA electron beam using the MT-25 electron accelerator. The element compositions of all the DHPC surfaces which had been in contact with dense deuterium gas were studied using scanning electronic microscopes with Roentgen microprobe analysis. It was determined that all the surfaces, including surfaces of the high-purity Pd-rod (99.995%), were covered either by a partially homogeneous layer or large microparticles of lead. Also, light elements as C, O, Na, Mg, Al, Si, Ti, Mn, Fe, Cu, Zn and heavy metals as Ag, Ta, W, Pt, Au and Pb were observed on the chambers inner surfaces.

  18. Performance Evaluation of Automated Passive Capillary Sampler for Estimating Water Drainage in the Vadose Zone

    Science.gov (United States)

    Passive capillary samplers (PCAPs) are widely used to monitor, measure and sample drainage water under saturated and unsaturated soil conditions in the vadose zone. The objective of this study was to evaluate the performance and accuracy of automated passive capillary sampler for estimating drainage...

  19. Pressure Effect on Entrance Flow

    DEFF Research Database (Denmark)

    Christensen, Jens Horslund; Couch, Mark

    1997-01-01

    The paper reports on experimentally determined pressure drops associated with orifice and capillary dies, where the exit pressure is elevated. The effect of hydrostatic pressure up to 70 MPa is reported for PS, LDPE and PP melts.......The paper reports on experimentally determined pressure drops associated with orifice and capillary dies, where the exit pressure is elevated. The effect of hydrostatic pressure up to 70 MPa is reported for PS, LDPE and PP melts....

  20. 饱和蒸汽压式波纹管疏水阀热动元件实验研究%Experimental study on the saturated vapor pressure type thermostatic bellows for steam traps

    Institute of Scientific and Technical Information of China (English)

    李树勋; 徐登伟; 把桥环

    2011-01-01

    针对液体膨胀式波纹管蒸汽疏水阀排量不稳定、漏汽率高等问题,分析波纹管热动元件的热工特性.基于Riedel蒸汽压方程和气液平衡方程,建立饱和蒸汽压式波纹管热动元件的热力学模型,设计相应实验系统,进行不同参数下的实验研究.结果表明,饱和蒸汽压式波纹管热动元件伸长量是相变温度的单值函数,近似呈指数关系;采用不同混合比、刚度及填充方式,可调节疏水阀的排水过冷度.%In view of the instabilities of displacement and high steam leakage rate for the liquid-expansion type ther-mostatic bellows steam traps, thermodynamic characteristical of thermostatic bellows was analyzed. Based on the Riedel equation and the vapor-liquid equilibrium equation, thermodynamic model of the saturated vapor pressure type thermostatic bellows was set up, corresponding experimental system was designed, and experimental studies with different parameters was carried out. The experimental results agree well with the theoretical analysis. The results show that the elongation A/I of the saturated vapor pressure type thermostatic bellows is monodrome function of phase transition temperature T, and relationship between the elongation A/I and the phase change temperature t is an exponential function. The subcooled temperature of steam trap can be adjusted by using different mixture ratio, different bellows' stiffness and different sufficient attire method. This paper establishes theoretical and experimental foundation for improving the performance of thermostatic bellows steam traps.

  1. A comparative study on analytical method of total alkaloids from cortex Phellodendri amurens by reversed phase high performance liquid chromatography (RP-HPLC and pressurized capillary electrochromatography (pCEC

    Directory of Open Access Journals (Sweden)

    Bo Yang

    2011-02-01

    Full Text Available A pressurized capillary electrochromatography (pCEC method with post-column detection cell has been developed for the analysis of total alkaloids of cortex Phellodendron amurense Rupr., Rutaceae. The separation of total alkaloids (berberine, palmatine, oatrorrhizine, magnoflorine, phellodendrine, candicine, menisperine was optimized by compositions of the mobile phase, ionic strength of buffers, pH value, and applied voltage. Separation of total alkaloids was achieved within 11 min by using a mobile phase of Na2HPO4-citric acid solution-acetonitrile (pH 4.00; 3 mM (60:40, v/v and applying a voltage of -10 kV. This method showed satisfactory retention times and peak shapes. Meanwhile, a reversed phase high performance liquid chromatography (RP-HPLC has also been established for the separation of total alkaloids extracted from cortex Phellodendri amurens. Baseline separation of total alkaloids was achieved within 25 min by using a mobile phase of acetonitrile-0.1% phosphoric acid with 0.1 g sodium dodecanesulphonate per 100 mL (35:65, v/v. Compared to conventional RP-HPLC, pCEC led to higher column efficiency, less consumption of reagent, and shorter analysis time.

  2. Investigation of the kinetics of water uptake into partially saturated shales

    Science.gov (United States)

    Roshan, H.; Andersen, M. S.; Rutlidge, H.; Marjo, C. E.; Acworth, R. I.

    2016-04-01

    Several processes have been proposed to describe the low recovery of hydraulic fracturing fluid in unconventional shale reservoirs which has caused both technical and environmental concerns. This study describes novel hydraulic experiments to quantitatively investigate the kinetics of water uptake into partially saturated shale through investigating the pressure response of injecting fluids (NaCl, KCl, MgCl2, and CaCl2 with different ionic concentrations) into crushed and sieved shale fragments. The results of the study indicate that the cumulative water uptake under pressure is likely to be controlled by three processes: surface hydration, capillary hydration including advective flow, and osmotic hydration. Each of these processes is a function of the differences between the in situ pore fluid and the injection fluid (solution chemistry and concentration) and the shale physicochemical properties, in particular the contact surface area, pore diameter, and the Cation Exchange Capacity (CEC). The uptake is not instantaneous, but is diffusion limited, with the rate governed by a number of kinetic processes. Uptake proceeds in three stages, each associated with a different process: (1) predominantly surface hydration, (2) predominantly capillary hydration and finally, (3) predominantly osmotic hydration. It was also shown that shale can take up a significant amount of water compared to its available solid volume. However, contrary to the conventional understanding, the increase in salinity of the injection fluid does not necessarily lead to reduced water uptake into shales, but is dependent on the type and concentration of cations within the shale and injecting fluid.

  3. Improved Refrigerant Characteristics Flow Predictions in Adiabatic Capillary Tube

    Directory of Open Access Journals (Sweden)

    Shodiya Sulaimon

    2012-07-01

    Full Text Available This study presents improved refrigerant characteristics flow predictions using homogenous flow model in adiabatic capillary tube, used in small vapor compression refrigeration system. The model is based on fundamental equations of mass, momentum and energy. In order to improve the flow predictions, the inception of vaporization in the capillary tube is determined by evaluating initial vapor quality using enthalpy equation of refrigerant at saturation point and the inlet entrance effect of the capillary tube is also accounted for. Comparing this model with experimental data from open literature showed a reasonable agreement. Further comparison of this new model with earlier model of Bansal showed that the present model could be use to improve the performance predictions of refrigerant flow in adiabatic capillary tube.

  4. Elastic Waves Push Residual Organic Fluids From Saturated Rock

    Science.gov (United States)

    Beresnev, I. A.; Vigil, R. D.; Li, W.

    2004-12-01

    With world oil reserves dwindling and production shifting to increasingly forbidding environments, the emphasis is greater than ever on the more efficient extraction of the existing oil. Yet typically up to two-thirds of the U. S. domestic oil is abandoned underground. Elastic waves have been observed to increase productivity of oil wells, although the reason for the vibratory motion mobilizing the residual organic fluids has remained unclear. Residual oil is entrapped as blobs or ganglia in narrow pore constrictions due to the resisting capillary forces that prevent free motion of non-wetting fluids driven by water. A finite external pressure gradient, exceeding an "unplugging" threshold, is needed to carry the residual ganglia through. We show that vibrations help overcome the resistance of capillary forces by adding an oscillatory inertial forcing to the external gradient; when the vibratory forcing acts along the gradient and the threshold is exceeded, instant "unplugging" occurs. This mechanism predicts the mobilization effect to be proportional to the amplitude and inversely proportional to the frequency of vibrations. We observe this dependence in a laboratory experiment, in which residual saturation of an organic fluid is created in a glass micromodel, and mobilization of the dyed ganglia is monitored using digital photography. We also directly demonstrate the release of an entrapped ganglion from a pore constriction by the application of vibrations in a computational fluid-dynamics simulation. The technologies that can utilize this phenomenon are not limited to enhanced oil recovery, but also apply to the remediation of groundwater contaminated by leaks from underground storage tanks and surface spills of organic fluids.

  5. Micro-injector for capillary electrophoresis.

    Science.gov (United States)

    Sáiz, Jorge; Koenka, Israel Joel; García-Ruiz, Carmen; Müller, Beat; Chwalek, Thomas; Hauser, Peter C

    2015-08-01

    A novel micro-injector for capillary electrophoresis for the handling of samples with volumes down to as little as 300 nL was designed and built in our laboratory for analyses in which the available volume is a limitation. The sample is placed into a small cavity located directly in front of the separation capillary, and the injection is then carried out automatically by controlled pressurization of the chamber with compressed air. The system also allows automated flushing of the injection chamber as well as of the capillary. In a trial with a capillary electrophoresis system with contactless conductivity detector, employing a capillary of 25 μm diameter, the results showed good stability of migration times and peak areas. To illustrate the technique, the fast separation of five inorganic cations (Na(+) , K(+) , NH4 (+) , Ca(2+) , and Mg(2+) ) was set up. This could be achieved in less than 3 min, with good limits of detection (10 μM) and linear ranges (between about 10 and 1000 μM). The system was demonstrated for the determination of the inorganic cations in porewater samples of a lake sediment core.

  6. Trapped liquid drop at the end of capillary.

    Science.gov (United States)

    Wang, Zhengjia; Yen, Hung-Yu; Chang, Cheng-Chung; Sheng, Yu-Jane; Tsao, Heng-Kwong

    2013-10-01

    The liquid drop captured at the capillary end, which is observed in capillary valve and pendant drop technique, is investigated theoretically and experimentally. Because of contact line pinning of the lower meniscus, the lower contact angle is able to rise from the intrinsic contact angle (θ*) so that the external force acting on the drop can be balanced by the capillary force. In the absence of contact angle hysteresis (CAH), the upper contact angle remains at θ*. However, in the presence of CAH, the upper contact angle can descend to provide more capillary force. The coupling between the lower and upper contact angles determines the equilibrium shape of the captured drop. In a capillary valve, the pinned contact line can move across the edge as the pressure difference exceeds the valving pressure, which depends on the geometrical characteristic and wetting property of the valve opening. When CAH is considered, the valving pressure is elevated because the capillary force is enhanced by the receding contact angle. For a pendant drop under gravity, the maximal capillary force is achieved as the lower contact angle reaches 180° in the absence of CAH. However, in the presence of CAH, four regimes can be identified by three critical drop volumes. The lower contact angle can exceed 180°, and therefore the drop takes on the shape of a light bulb, which does not exist in the absence of CAH. The comparisons between Surface Evolver simulations and experiments are quite well.

  7. Saturated Switching Systems

    CERN Document Server

    Benzaouia, Abdellah

    2012-01-01

    Saturated Switching Systems treats the problem of actuator saturation, inherent in all dynamical systems by using two approaches: positive invariance in which the controller is designed to work within a region of non-saturating linear behaviour; and saturation technique which allows saturation but guarantees asymptotic stability. The results obtained are extended from the linear systems in which they were first developed to switching systems with uncertainties, 2D switching systems, switching systems with Markovian jumping and switching systems of the Takagi-Sugeno type. The text represents a thoroughly referenced distillation of results obtained in this field during the last decade. The selected tool for analysis and design of stabilizing controllers is based on multiple Lyapunov functions and linear matrix inequalities. All the results are illustrated with numerical examples and figures many of them being modelled using MATLAB®. Saturated Switching Systems will be of interest to academic researchers in con...

  8. Albuterol Improves Alveolar-Capillary Membrane Conductance in Healthy Humans

    Science.gov (United States)

    Taylor, Natalie E.; Baker, Sarah E.; Olson, Thomas P.; Lalande, Sophie; Johnson, Bruce D.; Snyder, Eric M.

    2016-01-01

    BACKGROUND Beta-2 adrenergic receptors (β2ARs) are located throughout the body including airway and alveolar cells. The β2ARs regulate lung fluid clearance through a variety of mechanisms including ion transport on alveolar cells and relaxation of the pulmonary lymphatics. We examined the effect of an inhaled β2-agonist (albuterol) on alveolar-capillary membrane conductance (DM) and pulmonary capillary blood volume (VC) in healthy humans. METHODS We assessed the diffusing capacity of the lungs for carbon monoxide (DLCO) and nitric oxide (DLNO) at baseline, 30 minutes, and 60 minutes following nebulized albuterol (2.5 mg, diluted in 3 mL normal saline) in 45 healthy subjects. Seventeen subjects repeated these measures following nebulized normal saline (age = 27 ± 9 years, height = 165 ± 21 cm, weight = 68 ± 12 kg, BMI = 26 ± 9 kg/m2). Cardiac output (Q), heart rate, systemic vascular resistance (SVR), blood pressure, oxygen saturation, forced expiratory volume at one-second (FEV1), and forced expiratory flow at 50% of forced vital capacity (FEF50) were assessed at baseline, 30 minutes, and 60 minutes following the administration of albuterol or saline. RESULTS Albuterol resulted in a decrease in SVR, and an increase in Q, FEV1, and FEF50 compared to saline controls. Albuterol also resulted in a decrease in VC at 60 minutes post albuterol. Both albuterol and normal saline resulted in no change in DLCO or DM when assessed alone, but a significant increase was observed in DM when accounting for changes in VC. CONCLUSION These data suggest that nebulized albuterol improves pulmonary function in healthy humans, while nebulization of both albuterol and saline results in an increase in DM/VC. PMID:27773996

  9. Modeling variably saturated multispecies reactive groundwater solute transport with MODFLOW-UZF and RT3D

    Science.gov (United States)

    Bailey, Ryan T.; Morway, Eric D.; Niswonger, Richard G.; Gates, Timothy K.

    2013-01-01

    A numerical model was developed that is capable of simulating multispecies reactive solute transport in variably saturated porous media. This model consists of a modified version of the reactive transport model RT3D (Reactive Transport in 3 Dimensions) that is linked to the Unsaturated-Zone Flow (UZF1) package and MODFLOW. Referred to as UZF-RT3D, the model is tested against published analytical benchmarks as well as other published contaminant transport models, including HYDRUS-1D, VS2DT, and SUTRA, and the coupled flow and transport modeling system of CATHY and TRAN3D. Comparisons in one-dimensional, two-dimensional, and three-dimensional variably saturated systems are explored. While several test cases are included to verify the correct implementation of variably saturated transport in UZF-RT3D, other cases are included to demonstrate the usefulness of the code in terms of model run-time and handling the reaction kinetics of multiple interacting species in variably saturated subsurface systems. As UZF1 relies on a kinematic-wave approximation for unsaturated flow that neglects the diffusive terms in Richards equation, UZF-RT3D can be used for large-scale aquifer systems for which the UZF1 formulation is reasonable, that is, capillary-pressure gradients can be neglected and soil parameters can be treated as homogeneous. Decreased model run-time and the ability to include site-specific chemical species and chemical reactions make UZF-RT3D an attractive model for efficient simulation of multispecies reactive transport in variably saturated large-scale subsurface systems.

  10. Gas-Filled Capillary Model

    Science.gov (United States)

    Steinhauer, L. C.; Kimura, W. D.

    2006-11-01

    We have developed a 1-D, quasi-steady-state numerical model for a gas-filled capillary discharge that is designed to aid in selecting the optimum capillary radius in order to guide a laser beam with the required intensity through the capillary. The model also includes the option for an external solenoid B-field around the capillary, which increases the depth of the parabolic density channel in the capillary, thereby allowing for propagation of smaller laser beam waists. The model has been used to select the parameters for gas-filled capillaries to be utilized during the Staged Electron Laser Acceleration — Laser Wakefield (STELLA-LW) experiment.

  11. Impact of sample saturation on the detected porosity of hardened concrete using low temperature calorimetry

    DEFF Research Database (Denmark)

    Wu, Min; Johannesson, Björn

    2014-01-01

    The present work studied the impact of sample saturation on the analysis of pore volume and pore size distribution by low temperature (micro-)calorimetry. The theoretical background was examined, which emphasizes that the freezing/melting temperature of water/ice confined in non-fully saturated...... pores is further depressed compared with that when the pores are fully saturated. The study of the experimental data on hardened concrete samples showed that for a same concrete mix, the total pore volume detected from the capillary saturated samples was always lower than that of the vacuum saturated...

  12. Calculation Metho d of Power Law Fluid Equivalent Permeability Considering Capillary Shap e

    Institute of Scientific and Technical Information of China (English)

    YANG Er-long; LI Huan; GAO Hui-juan; GU Ting-ting

    2015-01-01

    While studying the flow of oil and gas in the reservoir, it is not realistic that capillary with circular section is only used to express the pores. It is more representative to simulate porous media pore with kinds of capillary with triangle or rectangle section etc. In the condition of the same diameter, when polymer for oil displacement flows in the porous medium, there only exists shear flow which can be expressed with power law model. Based on fluid flow-pressure drop equation in single capillary, this paper gives a calculation method of equivalent permeability of power law fluid of single capillary and capillary bundles with different sections.

  13. Derivatization in Capillary Electrophoresis.

    Science.gov (United States)

    Marina, M Luisa; Castro-Puyana, María

    2016-01-01

    Capillary electrophoresis is a well-established separation technique in analytical research laboratories worldwide. Its interesting advantages make CE an efficient and potent alternative to other chromatographic techniques. However, it is also recognized that its main drawback is the relatively poor sensitivity when using optical detection. One way to overcome this limitation is to perform a derivatization reaction which is intended to provide the analyte more suitable analytical characteristics enabling a high sensitive detection. Based on the analytical step where the CE derivatization takes place, it can be classified as precapillary (before separation), in-capillary (during separation), or postcapillary (after separation). This chapter describes the application of four different derivatization protocols (in-capillary and precapillary modes) to carry out the achiral and chiral analysis of different compounds in food and biological samples with three different detection modes (UV, LIF, and MS).

  14. How Capillary Rafts Sink

    CERN Document Server

    Protiere, S; Aristoff, J; Stone, H

    2010-01-01

    We present a fluid dynamics video showing how capillary rafts sink. Small objects trapped at an interface are very common in Nature (insects walking on water, ant rafts, bubbles or pollen at the water-air interface, membranes...) and are found in many multiphase industrial processes. Thanks to Archimedes principle we can easily predict whether an object sinks or floats. But what happens when several small particles are placed at an interface between two fluids. In this case surface tension also plays an important role. These particles self-assemble by capillarity and thus form what we call a "capillary raft". We show how such capillary rafts sink for varying sizes of particles and define how this parameter affects the sinking process.

  15. An experimental investigation of thermo-capillary convection in solution of lithium bromide at non-isothermal absorption

    Directory of Open Access Journals (Sweden)

    Bufetov N. S.

    2016-09-01

    Full Text Available The aim of this work is to obtain new experimental data on the development of thermo-capillary convection in a solution of lithium bromide with non-isothermal absorption of water vapor in a confined vessel. In experiments the contactless method of measuring the temperature of the interface based on using thermal imaging equipment, and the visualization method of the flow arising in the absorbent layer by introducing markers into solution have been used. The immobile layer of lithium bromide solution with an initial concentration of 58 % and a layer thickness of 20 mm in a confined vessel of 70 mm in diameter has been chosen as an object of investigation. The water vapor has been used as the absorbed gas, whose pressure was kept constant during the absorption (approximately 2 000 Pa. The absorption process has started after the steam supply to the absorber where the initial pressure has corresponded to saturated water vapor pressure at the temperature of the solution (250–300 Pa. The speed and duration of convective motion in the layer absorption on the basis of imaging arising due to thermo-capillary convection have been measured. The thermograms of the interface for various operating parameters have been obtained with the development of thermo-concentration convection. The characteristic time of the thermo-capillary convection development has been determined. Based on the experimental data analysis the empirical expressions for duration of the convective motion depending on the vapor pressure in the absorber and the thickness of the absorbent layer have been proposed. It has been shown that lowering the initial temperature of the solution leads to enhancement of thermo-concentration convection. The results are useful for the design and optimization of elements of refrigeration engineering of the absorption type.

  16. A Novel Protocol to Analyze Short- and Long-Chain Fatty Acids Using Nonaqueous Microchip Capillary Electrophoresis

    Science.gov (United States)

    Cable, M. L.; Stockton, A. M.; Mora, Maria F; Willis, P. A.

    2013-01-01

    We propose a new protocol to identify and quantify both short- and long-chain saturated fatty acids in samples of astrobiological interest using non-aqueous microchip capillary electrophoresis (micronNACE) with laser induced fluorescence (LIF).

  17. DNA Sequencing Using capillary Electrophoresis

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Barry Karger

    2011-05-09

    The overall goal of this program was to develop capillary electrophoresis as the tool to be used to sequence for the first time the Human Genome. Our program was part of the Human Genome Project. In this work, we were highly successful and the replaceable polymer we developed, linear polyacrylamide, was used by the DOE sequencing lab in California to sequence a significant portion of the human genome using the MegaBase multiple capillary array electrophoresis instrument. In this final report, we summarize our efforts and success. We began our work by separating by capillary electrophoresis double strand oligonucleotides using cross-linked polyacrylamide gels in fused silica capillaries. This work showed the potential of the methodology. However, preparation of such cross-linked gel capillaries was difficult with poor reproducibility, and even more important, the columns were not very stable. We improved stability by using non-cross linked linear polyacrylamide. Here, the entangled linear chains could move when osmotic pressure (e.g. sample injection) was imposed on the polymer matrix. This relaxation of the polymer dissipated the stress in the column. Our next advance was to use significantly lower concentrations of the linear polyacrylamide that the polymer could be automatically blown out after each run and replaced with fresh linear polymer solution. In this way, a new column was available for each analytical run. Finally, while testing many linear polymers, we selected linear polyacrylamide as the best matrix as it was the most hydrophilic polymer available. Under our DOE program, we demonstrated initially the success of the linear polyacrylamide to separate double strand DNA. We note that the method is used even today to assay purity of double stranded DNA fragments. Our focus, of course, was on the separation of single stranded DNA for sequencing purposes. In one paper, we demonstrated the success of our approach in sequencing up to 500 bases. Other

  18. Mach-like capillary-gravity wakes.

    Science.gov (United States)

    Moisy, Frédéric; Rabaud, Marc

    2014-08-01

    We determine experimentally the angle α of maximum wave amplitude in the far-field wake behind a vertical surface-piercing cylinder translated at constant velocity U for Bond numbers Bo(D)=D/λ(c) ranging between 0.1 and 4.2, where D is the cylinder diameter and λ(c) the capillary length. In all cases the wake angle is found to follow a Mach-like law at large velocity, α∼U(-1), but with different prefactors depending on the value of Bo(D). For small Bo(D) (large capillary effects), the wake angle approximately follows the law α≃c(g,min)/U, where c(g,min) is the minimum group velocity of capillary-gravity waves. For larger Bo(D) (weak capillary effects), we recover a law α∼√[gD]/U similar to that found for ship wakes at large velocity [Rabaud and Moisy, Phys. Rev. Lett. 110, 214503 (2013)]. Using the general property of dispersive waves that the characteristic wavelength of the wave packet emitted by a disturbance is of order of the disturbance size, we propose a simple model that describes the transition between these two Mach-like regimes as the Bond number is varied. We show that the new capillary law α≃c(g,min)/U originates from the presence of a capillary cusp angle (distinct from the usual gravity cusp angle), along which the energy radiated by the disturbance accumulates for Bond numbers of order of unity. This model, complemented by numerical simulations of the surface elevation induced by a moving Gaussian pressure disturbance, is in qualitative agreement with experimental measurements.

  19. Hydrologic Mechanisms Governing Fluid Flow in a Partially Saturated, Fractured, Porous Medium

    Science.gov (United States)

    Wang, J. S. Y.; Narasimhan, T. N.

    1985-12-01

    In contrast to the saturated zone within which fluid moves rapidly along fractures, the fractures (with apertures large relative to the size of matrix pores) will desaturate first during the drainage process, and the bulk of fluid flow would be through interconnected pores in the matrix. Within a partially drained fracture, the presence of a relatively continuous air phase will produce practically an infinite resistance to liquid flow in the direction parallel to the fracture. The residual liquid will be held by capillary force, in regions around fracture contact areas where the apertures are small. Normal to the fracture surfaces, the drained portion of the fractures will reduce the effective area for liquid flow from one matrix block to another matrix block. A general statistical theory is constructed for flow along the fracture and for flow between the matrix blocks to the fractures under partially saturated conditions. Results are obtained from an aperture distribution model for fracture saturation, hydraulic conductivity, and effective matrix-fracture flow areas as functions of pressure. The effects of distortion of flow paths by the air pockets are taken into account by a phase-separation constriction factor in a generalized cubic law for fracture flow under a partially saturated condition. The reduction of matrix-fracture flow area is taken into account by summing the aperture distribution function to a saturation cutoff aperture, which is inversely proportional to the suction head. Drainage from a column of fractured tuff is simulated using available parameters for the densely welded tuff of the Topopah Spring Member at Yucca Mountain, southern Nevada. The column is bounded by discrete vertical fractures and dissected by horizontal fractures with the fracture spacings determined by the frequencies and orientations of fractured cores. The fraction of fracture surfaces with coatings is assumed to correspond to the fraction of in situ fracture contact area

  20. Non-Boussinesq Dissolution-Driven Convection in Two- and Three-Dimensional Porous Media at Partially-Saturated Condition

    Science.gov (United States)

    Amooie, Mohammad Amin; Soltanian, Mohammad Reza; Moortgat, Joachim

    2016-11-01

    Sequestrated carbon dioxide (CO2) into saline aquifers, increases brine density through dissolution, and leads to gravitational instability and convective mixing. Traditionally, only the underlying brine-saturated subdomain is studied to avoid two-phase systems while replacing the gas cap atop with a constant, fully-saturated boundary condition. This violates the interface movement, neglects the capillary transition zone across original phases, and imposes constant density at top boundary insensitive to convective downwelling flow. Moreover, dissolution causes volume swelling, reflected as pressure build-up in absence of interface (movement), which further increases the fluid density -not captured under Boussinesq approximation. Here we accurately model the nonlinear phase behavior of brine-CO2 mixture, altered by dissolution and compressibility. We inject CO2 at a sufficiently low injection rate to maintain the single, partially-saturated phase, with no constraint on pressure and composition, so that density at top is free to change against the rate at which dissolved CO2 migrates downwards. We discover new flow regimes and present quantitative scaling relations for their temporal evolution in both two- and three-dimensional porous media.

  1. Effect of Stepwise Pressure Change on Porosity Evolution during Directional Solidification in Small Cylindrical Channels

    Science.gov (United States)

    Grugel, R.N.; Lee, C.P.; Cox, M.C.; Blandford, B.T.; Anilkumar, A.V.

    2008-01-01

    Controlled directional solidification experiments were performed in capillary channels, using nitrogen-saturated succinonitrile, to examine the effect of an in-situ stepwise processing pressure increase on an isolated pore evolution. Two experiments were performed using different processing pressure input profiles. The results indicate that a processing pressure increase has a transient effect on pore growth geometry characterized by an initial phase of decreasing pore diameter, followed by a recovery phase of increasing pore diameter. The experimental results also show that processing pressure can be used as a control parameter to either increase or terminate porosity formation. A theoretical model is introduced which indicates that the pore formation process is limited by the diffusion of solute-gas through the melt, and that the observed response toa pressure increase is attributed to the re-equilibration of solute concentration in the melt associated with the increased melt pressure.

  2. Saturating Sperner families

    CERN Document Server

    Gerbner, Dániel; Lemons, Nathan; Pálvölgyi, Dömötör; Palmer, Cory; Patkós, Balázs

    2011-01-01

    A family $\\cF \\subseteq 2^{[n]}$ saturates the monotone decreasing property $\\cP$ if $\\cF$ satisfies $\\cP$ and one cannot add any set to $\\cF$ such that property $\\cP$ is still satisfied by the resulting family. We address the problem of finding the minimum size of a family saturating the $k$-Sperner property and the minimum size of a family that saturates the Sperner property and that consists only of $l$-sets and $(l+1)$-sets.

  3. Saturated Domino Coverings

    CERN Document Server

    Buchanan, Andrew; Ryba, Alex

    2011-01-01

    A domino covering of a board is saturated if no domino is redundant. We introduce the concept of a fragment tiling and show that a minimal fragment tiling always corresponds to a maximal saturated domino covering. The size of a minimal fragment tiling is the domination number of the board. We define a class of regular boards and show that for these boards the domination number gives the size of a minimal X-pentomino covering. Natural sequences that count maximal saturated domino coverings of square and rectangular boards are obtained. These include the new sequences A193764, A193765, A193766, A193767, and A193768 of OEIS.

  4. Capillary permeability in adipose tissue

    DEFF Research Database (Denmark)

    Paaske, W P; Nielsen, S L

    1976-01-01

    of about 7 ml/100 g-min. This corresponds to a capillary diffusion capacity of 2.0 ml/100 g-min which is half the value reported for vasodilated skeletal muscle having approximately twice as great capillary surface area. Thus, adipose tissue has about the same capillary permeability during slight metabolic...

  5. Storm pulse chemographs of saturation index and carbon dioxide pressure: implications for shifting recharge sources during storm events in the karst aquifer at Fort Campbell, Kentucky/Tennessee, USA

    Science.gov (United States)

    Vesper, Dorothy J.; White, William B.

    Continuous records of discharge, specific conductance, and temperature were collected through a series of storm pulses on two limestone springs at Fort Campbell, western Kentucky/Tennessee, USA. Water samples, collected at short time intervals across the same storm pulses, were analyzed for calcium, magnesium, bicarbonate, total organic carbon, and pH. Chemographs of calcium, calcite saturation index, and carbon dioxide partial pressure were superimposed on the storm hydrographs. Calcium concentration and specific conductance track together and dip to a minimum either coincident with the peak of the hydrograph or lag slightly behind it. The CO2 pressure continues to rise on the recession limb of the hydrograph and, as a result, the saturation index decreases on the recession limb of the hydrograph. These results are interpreted as being due to dispersed infiltration through CO2-rich soils lagging the arrival of quickflow from sinkhole recharge in the transport of storm flow to the springs. Karst spring hydrographs reflect not only the changing mix of base flow and storm flow but also a shift in source of recharge water over the course of the storm. L'enregistrement en continu du débit, de la conductivité et de la température de l'eau a été réalisé au cours d'une série de crues à deux sources émergeant de calcaires, à Fort Campbell (Kentucky occidental, Tennessee, États-Unis). Des échantillons d'eau, prélevés à de courts pas de temps lors de ces crues, ont été analysés pour le calcium, le magnésium, les bicarbonates, le carbone organique total et le pH. Les chimiogrammes de calcium, d'indice de saturation de la calcite et de la pression partielle en CO2 ont été superposés aux hydrogrammes de crue. La concentration en calcium et la conductivité de l'eau se suivent bien et passent par un minimum correspondant au pic de l'hydrogramme ou légèrement retardé. La pression partielle en CO2 continue de croître au cours de la récession de l

  6. Saturation and geometrical scaling

    CERN Document Server

    Praszalowicz, Michal

    2016-01-01

    We discuss emergence of geometrical scaling as a consequence of the nonlinear evolution equations of QCD, which generate a new dynamical scale, known as the saturation momentum: Qs. In the kinematical region where no other energy scales exist, particle spectra exhibit geometrical scaling (GS), i.e. they depend on the ratio pT=Qs, and the energy dependence enters solely through the energy dependence of the saturation momentum. We confront the hypothesis of GS in different systems with experimental data.

  7. Screening of Newborn Saturation

    Directory of Open Access Journals (Sweden)

    Senem Ozgur

    2014-08-01

    Full Text Available In terms of the incidence, congenital heart diseases ranks first among congenital problems in the neonatal period. Although some of those diseases are with significant clinical findings, they might be insignificant in most cases. Standardization methods have been studied in variety of points, and oxygen saturation by pulse oximetry is thougt to be a good alternative to physical examination. In several studies, it is mentioned that some of congenital heart diseases are diagnosed by saturation screening. However, the benefits of this method are marred with the false negative and false positive rates. Therefore, in 2011 American Academy of Pediatrics has revised its saturation algorithm for scanning. It was aimed to have a standardization in saturation detecting time and evaluation of achieved saturation in newborns. Despite all efforts, some newborns with congenital heart disease are not diagnosed before discharging. We beleive that the details of saturation measurements are needed to be carefully evaluated because although these measurements are widely used their details are not well known. [Archives Medical Review Journal 2014; 23(4.000: 587-604

  8. Seven-day mortality can be predicted in medical patients by blood pressure, age, respiratory rate, loss of independence, and peripheral oxygen saturation (the PARIS score: a prospective cohort study with external validation.

    Directory of Open Access Journals (Sweden)

    Mikkel Brabrand

    Full Text Available Most existing risk stratification systems predicting mortality in emergency departments or admission units are complex in clinical use or have not been validated to a level where use is considered appropriate. We aimed to develop and validate a simple system that predicts seven-day mortality of acutely admitted medical patients using routinely collected variables obtained within the first minutes after arrival.This observational prospective cohort study used three independent cohorts at the medical admission units at a regional teaching hospital and a tertiary university hospital and included all adult (≥ 15 years patients. Multivariable logistic regression analysis was used to identify the clinical variables that best predicted the endpoint. From this, we developed a simplified model that can be calculated without specialized tools or loss of predictive ability. The outcome was defined as seven-day all-cause mortality. 76 patients (2.5% met the endpoint in the development cohort, 57 (2.0% in the first validation cohort, and 111 (4.3% in the second. Systolic blood Pressure, Age, Respiratory rate, loss of Independence, and peripheral oxygen Saturation were associated with the endpoint (full model. Based on this, we developed a simple score (range 0-5, ie, the PARIS score, by dichotomizing the variables. The ability to identify patients at increased risk (discriminatory power and calibration was excellent for all three cohorts using both models. For patients with a PARIS score ≥ 3, sensitivity was 62.5-74.0%, specificity 85.9-91.1%, positive predictive value 11.2-17.5%, and negative predictive value 98.3-99.3%. Patients with a score ≤ 1 had a low mortality (≤ 1%; with 2, intermediate mortality (2-5%; and ≥ 3, high mortality (≥ 10%.Seven-day mortality can be predicted upon admission with high sensitivity and specificity and excellent negative predictive values.

  9. 可压缩流体饱和孔隙介质中孔隙压力波传播数值分析%Numerical analysis of propagation of pore pressure waves in compressible fluid saturated porous media

    Institute of Scientific and Technical Information of China (English)

    杨多兴; 李琦; 王舒

    2014-01-01

    首次将高精度时空守恒元/解元方法推广到可压缩流体饱和孔隙介质中孔隙压力波传播的数值计算中。将孔隙度梯度从源(汇)项中分离,直接引入流通量,改进了理论模型。通过对孔隙介质激波问题的数值模拟,验证了方法的精度和有效性。在此基础上,提出了孔隙介质中二维黎曼问题,并揭示了孔隙压力波存在接触间断、激波、膨胀波、压缩波等复杂的结构特征。该成果对二氧化碳地质封存、二氧化碳提高石油采收率、页岩气压裂开采以及地震破裂过程的研究具有重要的理论与应用意义。%The governing equations of the propagation of shock waves in compressible fluid saturated deformable porous media are improved by the way the porosity gradient terms are treated in the flow flux vector. An updated space-time conservation element and solution element (CE/SE) method, which is a new approach in computational fluid dynamics (CFD), is presented to depict global and local flux conservation in space-time domain. The physical model and the CE/SE method are both validated with the experimental study based on the head-on collision of a planar shock wave through a rigid porous material;and then good agreements are found to be evident. After that, the two-dimensional Riemann problem in the porous media is established. It is found that the wave structures of the pore pressure consist of shock waves, compaction waves, expansion waves and the contact discontinuity. To our best knowledge, this is the first time that pore pressure waves have been successfully simulated with the CE/SE method inside a multiphase deformable porous medium. The findings are potentially applicable to CO2 geological storage, CO2 enhanced oil recovery, shale gas exploration and earthquake rupture processes.

  10. DESIGN AND CALIBRATION OF A CAPILLARY FLOWMETER SET FOR MEASUREMENT OF GAS FLOWS

    Directory of Open Access Journals (Sweden)

    Menderes LEVENT

    1998-01-01

    Full Text Available In this study, design and calibration of a capillary flowmeter set was represented. The capillary flowmeters will be used for measurements of small gas flows having laminar flow regime. The gases (such as, nitrogen, argon, methane, hydrogen and carbon-dioxide supplied from high pressure gas bottles and passed through capillary flowmeters (1 to 3 at various times. Each capillary flowmeter was made of glass and calibrated with one or two gases. Outlet of the capillary flowmeters were connected to the needle valves which have been used for regulating gas flowrates of the capillary flowmeters. Gases individually passed to a bubble flowmeter, and residence time of gases are recorded by using a stop watch. Then, from collected experimental results actual gas flowrates through the capillary flowmeters are calculated by using Hagen-Poiseuille equation.

  11. Estimating the failure potential of a partially saturated slope from combined continuum and limit equilibrium modeling (Invited)

    Science.gov (United States)

    Borja, R. I.; White, J. A.; Liu, X.; Wu, W.

    2010-12-01

    Rainfall weakens an earth slope and triggers mass movement. Relevant triggering mechanisms are complex and include reduction of capillary pressure due to increased saturation and frictional drag on the sediment induced by fluid flow. Physics-based continuum models utilizing modern computational tools are useful for understanding the mechanisms of deformation in partially saturated slopes; however, they do not provide a scalar indicator called "factor of safety" that measures the potential of a given slope for mass movement. In the present work we employ sequential calculations consisting of a physics-based finite element modeling that couples solid deformation with fluid flow to quantify the stress and deformation fields in a steep hillside slope subjected to rainfall infiltration. This is followed by a limit equilibrium calculation based on the method of slices that evaluates the desired factor of safety. The field condition investigated is similar to the steep experimental catchment CB1 near Coos Bay, Oregon, which failed as a large debris flow from heavy rainfall. We find the pore pressure variation to be a strong link between the continuum and limit-equilibrium solutions: for the same pore pressure variation within the slope, the continuum and limit-equilibrium solutions consistently predicted the same scarp zone for a given slope. Material parameters such as the effective cohesion and friction angle of the sediment tend to influence the timing of failure, but not the failure mechanism itself. Slope topography and rainfall history impact the slope failure mechanism to a great extent.

  12. due to Capillary Forces

    Directory of Open Access Journals (Sweden)

    Hassen M. Ouakad

    2009-01-01

    Full Text Available We present modeling and analysis for the static behavior and collapse instabilities of doubly-clamped and cantilever microbeams subjected to capillary forces. These forces can be as a result of a volume of liquid trapped underneath the microbeam during the rinsing and drying process in fabrication. The model considers the microbeam as a continuous medium, the capillary force as a nonlinear function of displacement, and accounts for the mid-plane stretching and geometric nonlinearities. The capillary force is assumed to be distributed over a specific length underneath the microbeam. The Galerkin procedure is used to derive a reduced-order model consisting of a set of nonlinear algebraic and differential equations that describe the microbeams static and dynamic behaviors. We study the collapse instability, which brings the microbeam from its unstuck configuration to touch the substrate and gets stuck in the so-called pinned configuration. We calculate the pull-in length that distinguishes the free from the pinned configurations as a function of the beam thickness and gap width for both microbeams. Comparisons are made with analytical results reported in the literature based on the Ritz method for linear and nonlinear beam models. The instability problem, which brings the microbeam from a pinned to adhered configuration is also investigated. For this case, we use a shooting technique to solve the boundary-value problem governing the deflection of the microbeams. The critical microbeam length for this second instability is also calculated.

  13. Invasion Percolation on Correlated and Elongated Lattices : Implications for the Interpretation of Residual Saturations in Rock Cores

    NARCIS (Netherlands)

    Knackstedt, Mark A.; Marrink, S.J.; Sheppard, Adrian P.; Pinczewski, W.V.; Sahimi, Muhammad

    2001-01-01

    The invasion percolation model is used to investigate the effect of correlated heterogeneity on capillary dominated displacements in porous media. The breakthrough and residual saturations are shown to be strongly influenced by the correlations. Correlated heterogeneity leads to lower residual satur

  14. Saturated versus non-saturated two-scales permeability

    Science.gov (United States)

    Lopez, Elena; Ammar, Amine; Abisset-Chavanne, Emmanuelle; Binetruy, Christophe; Chinesta, Francisco

    2016-10-01

    A crucial step in many composites manufacturing processes is the impregnation of fibrous medium with the resin. The fundamental property needed to quantify the flow is the permeability of the fibrous medium. Process models require the permeability as input data to predict flow patterns and pressure fields. Efficient numerical techniques are needed to solve homogenization problems with geometrical data coming from high-resolution images, involving two-scales and linear fluids. Within this frame-work, this work addresses the question of how to compute the macroscopic permeability from a microscopic description consisting of a viscous fluid flow model defined in a two-scale porous medium, considering the saturated and unsaturated cases.

  15. Modelling capillary trapping using finite-volume simulation of two-phase flow directly on micro-CT images

    Science.gov (United States)

    Raeini, Ali Q.; Bijeljic, Branko; Blunt, Martin J.

    2015-09-01

    We study capillary trapping in porous media using direct pore-scale simulation of two-phase flow on micro-CT images of a Berea sandstone and a sandpack. The trapped non-wetting phase saturations are predicted by solving the full Navier-Stokes equations using a volume-of-fluid based finite-volume framework to simulate primary drainage followed by water injection. Using these simulations, we analyse the effects of initial non-wetting-phase saturation, capillary number and flow direction on the residual saturation. The predictions from our numerical method are in agreement with published experimental measurements of capillary trapping curves. This shows that our direct simulation method can be used to elucidate the effect of pore structure and flow pattern of capillary trapping and provides a platform to study the physics of multiphase flow at the pore scale.

  16. Evolutions of Compaction Bands of Saturated Soils

    Institute of Scientific and Technical Information of China (English)

    鲁晓兵; 王义华; 崔鹏

    2004-01-01

    The development of compaction bands in saturated soils, which is coupling-rate, inertial and pore-pressure-dependent, under axisymmetric loading was discussed, using a simple model and a matching technique at the moving boundary of a band. It is shown that the development of compaction bands is dominated by the coupling-rate and pore-pressure effects of material. The soil strength makes the band shrinking, whilst pore pressure diffusion makes the band expand. Numerical simulations were carried out in this paper.

  17. Rapid, Simple and Ultrasensitive Analysis of Paraquat in Drinking Water by Field-Amplified Sample Injection Combined with Pressure-Assisted Capillary Zone Electrophoresis%场放大样品进样-压力辅助毛细管区带电泳测定饮用水中的百草枯

    Institute of Scientific and Technical Information of China (English)

    王明明; 沈菁; 宋婷; 李胜清; 陈浩

    2012-01-01

    Field-amplified sample injection (FASI) combined with pressure-assisted capillary zone electrophoresis (CZE) was developed for the determination of paraquat in drinking water. High reproducibility in FASI-CZE process could be attained with constant pressure applied at both ends of capillary. Compared with conventional hydrodynamic injection, the enrichment factor of 1174 was achieved for paraquat by FASI. Several parameters including length of water plug, injection time and composition of sample solution were systematically optimized. Linearity, sensitivity, precision and accuracy were investigated to validate the proposed method. The result showed that the calibration curve was linear at the concentration of 1.0 100 (ig/L with a correlation coefficient of 0. 9975. The limit of detection was 0. 039 ng/L (S/N=3). Mean recovery of paraquat was ranged from 78. 4% to 94. 5% with relative standard deviation ranging from 3. 0% to 10. 4%. Finally, the method proposed was applied for the determination of paraquat in real drinking water.

  18. Gas Flow Dynamics in Inlet Capillaries: Evidence for non Laminar Conditions

    Science.gov (United States)

    Wißdorf, Walter; Müller, David; Brachthäuser, Yessica; Langner, Markus; Derpmann, Valerie; Klopotowski, Sebastian; Polaczek, Christine; Kersten, Hendrik; Brockmann, Klaus; Benter, Thorsten

    2016-09-01

    In this work, the characteristics of gas flow in inlet capillaries are examined. Such inlet capillaries are widely used as a first flow restriction stage in commercial atmospheric pressure ionization mass spectrometers. Contrary to the common assumption, we consider the gas flow in typical glass inlet capillaries with 0.5 to 0.6 mm inner diameters and lengths about 20 cm as transitional or turbulent. The measured volume flow of the choked turbulent gas stream in such capillaries is 0.8 L·min-1 to 1.6 L·min-1 under typical operation conditions, which is in good agreement to theoretically calculated values. Likewise, the change of the volume flow in dependence of the pressure difference along the capillary agrees well with a theoretical model for turbulent conditions as well as with exemplary measurements of the static pressure inside the capillary channel. However, the results for the volume flow of heated glass and metal inlet capillaries are neither in agreement with turbulent nor with laminar models. The velocity profile of the neutral gas in a quartz capillary with an inner diameter similar to commercial inlet capillaries was experimentally determined with spatially resolved ion transfer time measurements. The determined gas velocity profiles do not contradict the turbulent character of the flow. Finally, inducing disturbances of the gas flow by placing obstacles in the capillary channel is found to not change the flow characteristics significantly. In combination the findings suggest that laminar conditions inside inlet capillaries are not a valid primary explanation for the observed high ion transparency of inlet capillaries under common operation conditions.

  19. Capillary Micro-flow Through a Fiber Bundle(Part 2)

    Institute of Scientific and Technical Information of China (English)

    ZHU Yingdan; WANG Jihui; TAN Hua; GAO Guoqiang

    2005-01-01

    A numerical model was proposed to simulate the capillary micro-flow through a fiber bundle.The capillary pressure was predicted by the Young-Laplace equation and the corresponding optimal values of permeability were found by a trial-and-error method. The empirical Kozeny constants which are dependent on fiber volume fraction were recommended for the prediction of permeability.

  20. Analysis of electrokinetic pumping efficiency in capillary tubes.

    Science.gov (United States)

    Chein, Reiyu; Liao, Jenchen

    2007-02-01

    A mathematical model for predicting the maximum pumping efficiency and pressure difference generation by an electrokinetic-driven fluid pumping system through a capillary tube is presented in this study. Both the maximum pumping efficiency and optimum pressure difference generation are found to depend on a single variable. This single variable is termed as the figure of merit since it determines the performance of electrokinetic pumping. The figure of merit is found to depend on three dimensionless parameters, the normalized Debye length, zeta potential, and Levine number indicating the nominal ratio of convective current to conductive current. All three parameters can be related to the pH value and concentration of aqueous salt solution by the introduction of concentration-dependent electrical conductivity and pH-dependent zeta potential. By presenting the maximum pumping efficiency and optimum pressure difference generation as functions of pH value, salt concentration, and capillary tube radius, it is found that both maximum pumping efficiency and optimum pressure difference generation increase with the decrease in capillary radius and salt concentration. The optimum pH values at which the maximum pumping efficiency and optimum pressure difference generation occur are found to be in the range between 6 and 9. For the salt concentration of 10(-6) M, pH 6.9, and a capillary tube radius value of 0.5 micro m, the predicted maximum pumping efficiency is 5.4% which is close to the experimental measurement reported in the literature.

  1. Pseudo Rayleigh wave in a partially saturated non-dissipative porous solid

    Science.gov (United States)

    Sharma, M. D.

    2016-09-01

    Propagation of surface waves is studied at the pervious boundary of a porous solid saturated with a mixture of two immiscible fluids. An approach, based on continuum mixture theory, is used to derive a secular equation for the propagation of harmonic waves at the stress-free plane surface of this non-dissipative medium. Numerical analysis shows that this secular equation may not represent the propagation of true surface wave in the porous aggregate. Then, this equation is solved numerically for the propagation of pseudo Rayleigh wave or the leaky surface waves. To ensure the existence of pseudo Rayleigh wave, capillary effect between two (wetting and non-wetting) pore-fluids is related to the partial saturation. Effects of porosity and partial saturation coupled with capillary effect are observed on the phase velocity of pseudo Rayleigh waves in sandstone saturated with water-CO2 mixture.

  2. LASER PLASMA AND LASER APPLICATIONS: Plasma transparency in laser absorption waves in metal capillaries

    Science.gov (United States)

    Anisimov, V. N.; Kozolupenko, A. P.; Sebrant, A. Yu

    1988-12-01

    An experimental investigation was made of the plasma transparency to heating radiation in capillaries when absorption waves propagated in these capillaries as a result of interaction with a CO2 laser pulse of 5-μs duration. When the length of the capillary was in excess of 20 mm, total absorption of the radiation by the plasma was observed at air pressures of 1-100 kPa. When the capillary length was 12 mm, a partial recovery of the transparency took place. A comparison was made with the dynamics and recovery of the plasma transparency when breakdown of air took place near the free surface.

  3. Evaluating the Influence of Pore Architecture and Initial Saturation on Wettability and Relative Permeability in Heterogeneous, Shallow-Shelf Carbonates

    Energy Technology Data Exchange (ETDEWEB)

    Byrnes, Alan P.; Bhattacharya, Saibal; Victorine, John; Stalder, Ken

    2007-09-30

    Thin (3-40 ft thick), heterogeneous, limestone and dolomite reservoirs, deposited in shallow-shelf environments, represent a significant fraction of the reservoirs in the U.S. midcontinent and worldwide. In Kansas, reservoirs of the Arbuckle, Mississippian, and Lansing-Kansas City formations account for over 73% of the 6.3 BBO cumulative oil produced over the last century. For these reservoirs basic petrophysical properties (e.g., porosity, absolute permeability, capillary pressure, residual oil saturation to waterflood, resistivity, and relative permeability) vary significantly horizontally, vertically, and with scale of measurement. Many of these reservoirs produce from structures of less than 30-60 ft, and being located in the capillary pressure transition zone, exhibit vertically variable initial saturations and relative permeability properties. Rather than being simpler to model because of their small size, these reservoirs challenge characterization and simulation methodology and illustrate issues that are less apparent in larger reservoirs where transition zone effects are minor and most of the reservoir is at saturations near S{sub wirr}. These issues are further augmented by the presence of variable moldic porosity and possible intermediate to mixed wettability and the influence of these on capillary pressure and relative permeability. Understanding how capillary-pressure properties change with rock lithology and, in turn, within transition zones, and how relative permeability and residual oil saturation to waterflood change through the transition zone is critical to successful reservoir management and as advanced waterflood and improved and enhanced recovery methods are planned and implemented. Major aspects of the proposed study involve a series of tasks to measure data to reveal the nature of how wettability and drainage and imbibition oil-water relative permeability change with pore architecture and initial water saturation. Focus is placed on

  4. Conformal invariant saturation

    CERN Document Server

    Navelet, H

    2002-01-01

    We show that, in onium-onium scattering at (very) high energy, a transition to saturation happens due to quantum fluctuations of QCD dipoles. This transition starts when the order alpha^2 correction of the dipole loop is compensated by its faster energy evolution, leading to a negative interference with the tree level amplitude. After a derivation of the the one-loop dipole contribution using conformal invariance of the elastic 4-gluon amplitude in high energy QCD, we obtain an exact expression of the saturation line in the plane (Y,L) where Y is the total rapidity and L, the logarithm of the onium scale ratio. It shows universal features implying the Balitskyi - Fadin - Kuraev - Lipatov (BFKL) evolution kernel and the square of the QCD triple Pomeron vertex. For large L, only the higher BFKL Eigenvalue contributes, leading to a saturation depending on leading log perturbative QCD characteristics. For initial onium scales of same order, however, it involves an unlimited summation over all conformal BFKL Eigen...

  5. Tapered capillary optics

    Science.gov (United States)

    Hirsch, Gregory

    1998-01-01

    A metal or glass wire is etched with great precision into a very narrowly tapering cone which has the shape of the desired final capillary-optics bore. By controlling the rate of removal of the wire from an etchant bath, a carefully controlled taper is produced. A sensor measures the diameter of the wire as it leaves the surface of the etchant. This signal is used for feedback control of the withdrawal speed. The etched wire undergoes a treatment to produce an extremely low surface-roughness. The etched and smoothed wire is coated with the material of choice for optimizing the reflectivity of the radiation being focused. This could be a vacuum evaporation, sputtering, CVD or aqueous chemical process. The coated wire is either electroplated, built up with electroless plating, or encapsulated in a polymer cylinder such as epoxy to increase the diameter of the wire for easier handling and greater robustness. During this process, the wire is vertically oriented and tensioned to assure that the wire is absolutely straight. The coated and electroformed wire is bonded to a flat, rigid substrate and is then periodically segmented by cutting or etching a series of narrow slits or grooves into the wire. The wire is vertically oriented and tensioned during the bonding process to assure that it is straight. The original wire material is then chemically etched away through the slits or otherwise withdrawn to leave the hollow internal bore of the final tapered-capillary optical element.

  6. Capillary condensation as a morphological transition.

    Science.gov (United States)

    Kornev, Konstantin G; Shingareva, Inna K; Neimark, Alexander V

    2002-02-25

    The process of capillary condensation/evaporation in cylindrical pores is considered within the idea of symmetry breaking. Capillary condensation/evaporation is treated as a morphological transition between the wetting film configurations of different symmetry. We considered two models: (i) the classical Laplace theory of capillarity and (ii) the Derjaguin model which takes into account the surface forces expressed in terms of the disjoining pressure. Following the idea of Everett and Haynes, the problem of condensation/evaporation is considered as a transition from bumps/undulations to lenses. Using the method of phase portraits, we discuss the mathematical mechanisms of this transition hidden in the Laplace and Derjaguin equations. Analyzing the energetic barriers of the bump and lens formation, it is shown that the bump formation is a prerogative of capillary condensation: for the vapor-liquid transition in a pore, the bump plays the same role as the spherical nucleus in a bulk fluid. We show also that the Derjaguin model admits a variety of interfacial configurations responsible for film patterning at specific conditions.

  7. THEORETICAL RESEARCH AND APPLICATION OF THE CAPILLARY PRESSURE EFFECT ON THE PHASE EQUILIBRIUM IN OIL AND GAS SYSTEM%毛细管压力影响油气体系相平衡的理论研究与应用

    Institute of Scientific and Technical Information of China (English)

    张茂林; 吴清松; 梅海燕; 郭平; 孙良田; 李士伦

    2000-01-01

    在油气藏中,油气流体和储层多孔介质是一个相互作用的系统,油气体系相平衡计算应考虑多孔介质中的界面现象的影响。文章从热力学基本理论出发,建立了考虑毛细管压力的相平衡计算模型。为了论证毛细管压力对油气体系相平衡的影响程度,针对我国两个凝析气藏,分别对油气体系的毛细管压力、露点压力、反凝析液量和p-T相图形态进行了相态模拟计算。并利用热力学亚稳态和新相生成理论中的开尔文(Kelvin)方程对其相态模拟计算结果作出了满意的解释。%There exists an interactional system between oil and gas fluids and porous media in oil and gas reservoirs. The effect of interface phenomena in porous media should be taken into consideration if phase equilibrium is to be calculated in oil and gas system. Based on the basic thermodynamics, phase equilibrium calculation model is set up concerning the effect of capillary pressure. In order to prove in what degree the capillary pressure has an effect on the oil and gas phase equilibrium, two condensate reservoirs in China were taken as examples to carry on phase behavoir simulation calculation of capillary pressure, dew points pressure, retrograde condensate liquid contents and P-T plase diagram of oil and gas system. The phase simulation results are well explained by using the Kelvin equation of the thermodynamic metastable state and new phase formation theory.

  8. Characterization of the Basic Operational Properties of the Capillary Plasma Electrode (CPE) Discharge

    Science.gov (United States)

    Lopez, Jose; Zhu, Weidong; Figus, Margaret; Becker, Kurt

    2008-10-01

    Various approaches have been pursued to create stable atmospheric pressure discharges by extending the lifetime of the diffuse phase of the discharge to hundreds of microseconds. Previous research showed that the stability of the diffuse mode is dependent on the frequency (in the kHz range), gas type, power, mode of the excitation, and geometrical confinement. The Capillary Plasma Electrode (CPE) discharge is able to produce stable atmospheric pressure nonequilibrium plasmas. The CPE is similar in design to a barrier-electrode discharge, but has perforated dielectrics. This configuration, aside from exhibiting a diffuse mode of operation, also exhibits the so-called ``capillary jet'' mode, in which the capillaries ``turn on'' and a bright plasma jet emerges from the capillaries. The capillary jets from adjacent capillaries overlap so that the discharge appears uniform when the electrode contains an array of holes. There appears to be a threshold frequency for the capillary jet formation, which is strongly dependent on the L/D ratio of the capillaries, where D is the diameter of a capillary and L its length. This current work explores these modes of operation of the CPE by characterizing the electrical and optical emission properties of this discharge.

  9. Capillaries modified by noncovalent anionic polymer adsorption for capillary zone electrophoresis, micellar electrokinetic capillary chromatography and capillary electrophoresis mass spectrometry

    DEFF Research Database (Denmark)

    Bendahl, L; Hansen, S H; Gammelgaard, Bente

    2001-01-01

    A simple coating procedure for generation of a high and pH-independent electroosmotic flow in capillary zone electrophoresis (CZE) and micellar electrokinetic capillary chromatography (MEKC) is described. The bilayer coating was formed by noncovalent adsorption of the ionic polymers Polybrene...

  10. Acoustic wave propagation simulation in a poroelastic medium saturated by two immiscible fluids using a staggered finite-difference with a time partition method

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Based on the three-phase theory proposed by Santos, acoustic wave propagation in a poroelastic medium saturated by two immiscible fluids was simulated using a staggered high-order finite-difference algorithm with a time partition method, which is firstly applied to such a three-phase medium. The partition method was used to solve the stiffness problem of the differential equations in the three-phase theory. Considering the effects of capillary pressure, reference pressure and coupling drag of two fluids in pores, three compressional waves and one shear wave predicted by Santos have been correctly simulated. Influences of the parameters, porosity, permeability and gas saturation on the velocities and amplitude of three compressional waves were discussed in detail. Also, a perfectly matched layer (PML) absorbing boundary condition was firstly implemented in the three-phase equations with a staggered-grid high-order finite-difference. Comparisons between the proposed PML method and a commonly used damping method were made to validate the efficiency of the proposed boundary absorption scheme. It was shown that the PML works more efficiently than the damping method in this complex medium. Additionally, the three-phase theory is reduced to the Biot’s theory when there is only one fluid left in the pores, which is shown in Appendix. This reduction makes clear that three-phase equation systems are identical to the typical Biot’s equations if the fluid saturation for either of the two fluids in the pores approaches to zero.

  11. Acoustic wave propagation simulation in a poroelastic medium saturated by two immiscible fluids using a staggered finite-difference with a time partition method

    Institute of Scientific and Technical Information of China (English)

    ZHAO HaiBo; WANG XiuMing

    2008-01-01

    Based on the three-pheee theory proposed by Santos, acoustic wave propagation in a poroelastic medium saturated by two immiscible fluids was simulated using a staggered high-order finite-difference algorithm with a time partition method, which is firstly applied to such a three-phase medium. The partition method was used to solve the stiffness problem of the differential equations in the three-pheee theory. Considering the effects of capillary pressure, reference pressure and coupling drag of two fluids in pores, three compressional waves and one shear wave predicted by Santos have been correctly simulated. Influences of the parameters, porosity, permeability and gas saturation on the velocities and amplitude of three compres-sional waves were discussed in detail. Also, a perfectly matched layer (PML) absorbing boundary condition was firstly implemented in the three-phase equations with a staggered-grid high-order finite-difference. Comparisons between the proposed PML method and a commonly used damping method were made to validate the efficiency of the proposed boundary absorption scheme. It was shown that the PML works more efficiently than the damping method in this complex medium.Additionally, the three-phase theory is reduced to the Blot's theory when there is only one fluid left in the pores, which is shown in Appendix. This reduction makes clear that three-phase equation systems are identical to the typical Blot's equations if the fluid saturation for either of the two fluids in the pores approaches to zero.

  12. Fundamentals of Reservoir Surface Energy as Related to Surface Properties, Wettability, Capillary Action, and Oil Recovery from Fractured Reservoirs by Spontaneous Imbibition

    Energy Technology Data Exchange (ETDEWEB)

    Norman Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Zhengxin Tong; Evren Unsal; Siluni Wickramathilaka; Shaochang Wo; Peigui Yin

    2008-06-30

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the non-wetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed

  13. FUNDAMENTALS OF RESERVOIR SURFACE ENERGY AS RELATED TO SURFACE PROPERTIES, WETTABILITY, CAPILLARY ACTION, AND OIL RECOVERY FROM FRACTURED RESERVOIRS BY SPONTANEOUS IMBIBITION

    Energy Technology Data Exchange (ETDEWEB)

    Norman R. Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Peigui Yin; Shaochang Wo

    2005-02-01

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the nonwetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed

  14. FUNDAMENTALS OF RESERVOIR SURFACE ENERGY AS RELATED TO SURFACE PROPERTIES, WETTABILITY, CAPILLARY ACTION, AND OIL RECOVERY FROM FRACTURED RESERVOIRS BY SPONTANEOUS IMBIBITION

    Energy Technology Data Exchange (ETDEWEB)

    Norman R. Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Peigui Yin; Shaochang Wo

    2004-10-01

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the nonwetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed

  15. FUNDAMENTALS OF RESERVOIR SURFACE ENERGY AS RELATED TO SURFACE PROPERTIES, WETTABILITY, CAPILLARY ACTION, AND OIL RECOVERY FROM FRACTURED RESERVOIRS BY SPONTANEOUS IMBIBITION

    Energy Technology Data Exchange (ETDEWEB)

    Norman R. Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Peigui Yin; Shaochang Wo

    2005-04-01

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the nonwetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed

  16. Fundamentals of reservoir surface energy as related to surface properties, wettability, capillary action, and oil recovery from fractured reservoirs by spontaneous imbibition

    Energy Technology Data Exchange (ETDEWEB)

    Norman R. Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Jason Zhengxin Tong; Peigui Yin; Shaochang Wo

    2006-02-01

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the nonwetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed

  17. Gravimetric capillary method for kinematic viscosity measurements

    Science.gov (United States)

    Rosenberger, Franz; Iwan, J.; Alexander, D.; Jin, Wei-Qing

    1992-01-01

    A novel version of the capillary method for viscosity measurements of liquids is presented. Viscosity data can be deduced in a straightforward way from mass transfer data obtained by differential weighing during the gravity-induced flow of the liquid between two cylindrical chambers. Tests of this technique with water, carbon tetrachloride, and ethanol suggest that this arrangement provides an accuracy of about +/- 1 percent. The technique facilitates operation under sealed, isothermal conditions and, thus can readily be applied to reactive and/or high vapor pressure liquids.

  18. Ion guiding in alumina capillaries

    DEFF Research Database (Denmark)

    Juhász, Z.; Sulik, B.; Biri, S.;

    2009-01-01

    Transmission of a few keV impact energy Ne ions through capillaries in anodic alumina membranes has been studied with different ion counting methods using an energy dispersive electrostatic spectrometer, a multichannel plate (MCP) array and sensitive current-measurement. In the present work, we...... focus our attention to the measurements with the MCP array. The alumina capillaries were prepared by electro-chemical oxidation of aluminium foils. For the present experiments guiding of 3-6 keV Ne ions has been studied in two samples with capillary diameter of about 140 nm and 260 nm and with capillary...... length of about 15 μm. At these energies, the ions have been efficiently guided by the capillaries up to few degrees tilt angle. In this work, we compare the results obtained by the energy dispersive spectrometer to those studied by the MCP array. © 2008 Elsevier B.V. All rights reserved....

  19. Biomedical applications of capillary electrophoresis

    Science.gov (United States)

    Kartsova, L. A.; Bessonova, E. A.

    2015-08-01

    The review deals with modern analytical approaches used in capillary electrophoresis for solving medical and biological problems: search for biomarkers of various diseases and rapid diagnosis based on characteristic profiles of biologically active compounds by capillary electrophoresis with mass spectrometric detection; monitoring of the residual drugs in biological fluids for evaluating the efficiency of drug therapy; testing of the enantiomeric purity of pharmaceutical products; the use of novel materials as components of stationary and pseudo-stationary phases in capillary electrophoresis and capillary electrochromatography to increase the selectivity of separation of components of complex matrices; and identification of various on-line preconcentration techniques to reduce the detection limits of biologically active analytes. A topical trend in capillary electrophoresis required in clinical practice, viz., the design of microfluidic systems, is discussed. The bibliography includes 173 references.

  20. Micro-magnetic particles frit for capillary electrochromatography.

    Science.gov (United States)

    Oguri, Shigeyuki; Oga, Chiari; Takeda, Haruna

    2007-07-20

    This paper presents a new method for making frit using soft-ferrite-based micro-magnetic particles (MMPs) in a micro-space, such as in a capillary tube. The MMPs-frit was made by injecting an aliquot of 10 microm (outer diameter; o.d.)-MMPs-suspension in methanol (ca. 1mg/ml) into a capillary tube (75 microm inner diameter (i.d.) x 375 microm o.d. x ca. 35 cm length) that was already sandwiched between a pair of cylindrical Neodium (Nd-Fe-B) magnets (1.5 mm o.d. x 1.5 mm height, 280 mT) at a position where the frit was made. The MMPs were trapped in the capillary tube as a frit due to the attraction of the magnets placed at surface on the capillary tube. With regard to durability, the frit was stable for methanol flow with a flow rate of 400 microl/min at room temperature. Using such a frit, a capillary column (20 cm long) was prepared by injecting a 5 microm (o.d.)-ODS-particle suspension in methanol (ca. 0.4 mg/microl) into the capillary tube. The MMPs-frits-ODS-packed column was stable for methanol for a flow pressure less than 20MPa. When comparing the present column with a conventional sintered-frits-ODS-packed column for the purposes of separating five kinds of biogenic amines by means of an on-column derivatization capillary electrochromatography (CEC), the performance of the MMPs-frits capillary column was almost equivalent to that of the sintered-frits-ODS-packed column.

  1. Capillaries for use in a multiplexed capillary electrophoresis system

    Science.gov (United States)

    Yeung, E.S.; Chang, H.T.; Fung, E.N.

    1997-12-09

    The invention provides a side-entry optical excitation geometry for use in a multiplexed capillary electrophoresis system. A charge-injection device is optically coupled to capillaries in the array such that the interior of a capillary is imaged onto only one pixel. In Sanger-type 4-label DNA sequencing reactions, nucleotide identification (``base calling``) is improved by using two long-pass filters to split fluorescence emission into two emission channels. A binary poly(ethyleneoxide) matrix is used in the electrophoretic separations. 19 figs.

  2. Multidimensional capillary electrophoresis.

    Science.gov (United States)

    Grochocki, Wojciech; Markuszewski, Michał J; Quirino, Joselito P

    2015-01-01

    Multidimensional separation where two or more orthogonal displacement mechanisms are combined is a promising approach to increase peak capacity in CE. The combinations allow dramatic improvement of analytical performance since the total peak capacity is given by a product of the peak capacities of all methods. The initial reports were concentrated on the construction of effective connections between capillaries for 2D analysis. Today, 2D and 3D CE systems are now able to separate real complex biological or environmental mixtures with good repeatability, improved resolution with minimal loss of sample. This review will present the developments in the field of multidimensional CE during the last 15 years. The endeavors in this specific field were on the development of interfaces, interface-free techniques including integrated separations, microdevices, and on-line sample concentration techniques to improve detection sensitivity.

  3. Fractal analysis of fracture increasing spontaneous imbibition in porous media with gas-saturated

    KAUST Repository

    Cai, Jianchao

    2013-08-01

    Spontaneous imbibition (SI) of wetting liquid into matrix blocks due to capillary pressure is regarded as an important recovery mechanism in low permeability fractured reservoir. In this paper, an analytical model is proposed for characterizing SI horizontally from a single plane fracture into gas-saturated matrix blocks. The presented model is based on the fractal character of pores in porous matrix, with gravity force included in the entire imbibition process. The accumulated mass of wetting liquid imbibed into matrix blocks is related to a number of factors such as contact area, pore fractal dimension, tortuosity, maximum pore size, porosity, liquid density and viscosity, surface tension, contact angle, as well as height and tilt angle of the fracture. The mechanism of fracture-enhanced SI is analyzed accordingly. Because of the effect of fracture, the gravity force is positive to imbibition process. Additionally, the farther away from the fracture top of the pore, the more influential the hydrostatic pressure is upon the imbibition action. The presented fractal analysis of horizontal spontaneous imbibition from a single fracture could also shed light on the scaling study of the mass transfer function between matrix and fracture system of fractured reservoirs. © 2013 World Scientific Publishing Company.

  4. Capillary Pumped Heat Transfer (CHT) Experiment

    Science.gov (United States)

    Hallinan, Kevin P.; Allen, J. S.

    1998-01-01

    The operation of Capillary Pumped Loops (CPL's) in low gravity has generally been unable to match ground-based performance. The reason for this poorer performance has been elusive. In order to investigate the behavior of a CPL in low-gravity, an idealized, glass CPL experiment was constructed. This experiment, known as the Capillary-driven Heat Transfer (CHT) experiment, was flown on board the Space Shuttle Columbia in July 1997 during the Microgravity Science Laboratory mission. During the conduct of the CHT experiment an unexpected failure mode was observed. This failure mode was a result of liquid collecting and then eventually bridging the vapor return line. With the vapor return line blocked, the condensate was unable to return to the evaporator and dry-out subsequently followed. The mechanism for this collection and bridging has been associated with long wavelength instabilities of the liquid film forming in the vapor return line. Analysis has shown that vapor line blockage in present generation CPL devices is inevitable. Additionally, previous low-gravity CPL tests have reported the presence of relatively low frequency pressure oscillations during erratic system performance. Analysis reveals that these pressure oscillations are in part a result of long wavelength instabilities present in the evaporator pores, which likewise lead to liquid bridging and vapor entrapment in the porous media. Subsequent evaporation to the trapped vapor increases the vapor pressure. Eventually the vapor pressure causes ejection of the bridged liquid. Recoil stresses depress the meniscus, the vapor pressure rapidly increases, and the heated surface cools. The process then repeats with regularity.

  5. Study of the operational properties of the Capillary Plasma Electrode (CPE) discharges

    Science.gov (United States)

    Lopez, Jose; Jacome, David; Zhu, Wei-Dong; Figus, Margaret; Becker, Kurt H.

    2009-03-01

    Various approaches have been pursued to create stable atmospheric pressure discharges by extending the lifetime of the diffuse phase of the discharge to hundreds of microseconds. Previous research showed that the stability of the diffuse mode is dependent on the frequency (in the kHz range), gas type power, mode of the excitation, and geometrical confinement. Some of the most promising approaches are based on the recognition of the arc formation in high-pressure plasmas can be avoided and stable high-pressure plasma can be generated and maintained when the plasma are spatially constricted to the dimensions of tens to hundreds of microns. The Capillary Plasma Electrode (CPE) discharge is stable to produce stable atmospheric pressure nonequilibrium plasma. The CPE is similar in design to the Barrier Electrode Discharge, but has perforated dielectrics. The configuration, aside from exhibiting a diffuse mode of operation, also exhibits the so-called ``capillary jet'' mode, in which the capillaries “turn on” and a bright plasma jet emerges from the capillaries. The capillary jets from adjacent capillaries overlap so that the discharge appears uniform when the electrode contains an array of holes. There appears to be a threshold frequency for the capillary jet formation, which is strongly dependent on the L/D ratio of the capillaries, where D is diameter of the capillary and L its length. However, the operating principles and basic properties of this behavior are not well understood. The current work explores these modes of operations of the CPE by characterizing the electrical and optical emission properties of this discharge by examining a multi-hole discharge as well as a single capillary discharge reactor.

  6. Capillary flow solder wettability test

    Energy Technology Data Exchange (ETDEWEB)

    Vianco, P.T.; Rejent, J.A.

    1996-01-01

    A test procedure was developed to assess the capillary flow wettability of solders inside of a confined geometry. The test geometry was comprised of two parallel plates with a controlled gap of constant thickness (0.008 cm, 0.018 cm, 0.025 cm, and 0.038 cm). Capillary flow was assessed by: (1) the meniscus or capillary rise of the solder within the gap, (2) the extent of void formation in the gap, and (3) the time-dependence of the risen solder film. Tests were performed with the lead-free solders.

  7. Laser-driven plasma waves in capillary tubes.

    Science.gov (United States)

    Wojda, F; Cassou, K; Genoud, G; Burza, M; Glinec, Y; Lundh, O; Persson, A; Vieux, G; Brunetti, E; Shanks, R P; Jaroszynski, D; Andreev, N E; Wahlström, C-G; Cros, B

    2009-12-01

    The excitation of plasma waves over a length of up to 8 cm is demonstrated using laser guiding of intense laser pulses through hydrogen-filled glass capillary tubes. The plasma waves are diagnosed by spectral analysis of the transmitted laser radiation. The dependence of the spectral redshift-measured as a function of filling pressure, capillary tube length, and incident laser energy-is in excellent agreement with simulation results. The longitudinal accelerating field inferred from the simulations is in the range of 1-10 GV/m.

  8. Pressure Effect on Extensional Viscosity

    DEFF Research Database (Denmark)

    Christensen, Jens Horslund; Kjær, Erik Michael

    1999-01-01

    The primary object of these experiments was to investigate the influence of hydrostatic pressure on entrance flow. The effect of pressure on shear and extensional viscosity was evaluated using an axis symmetric capillary and a slit die where the hydrostatic pressure was raised with valves...

  9. Pressure cryocooling protein crystals

    Science.gov (United States)

    Kim, Chae Un; Gruner, Sol M.

    2011-10-04

    Preparation of cryocooled protein crystal is provided by use of helium pressurizing and cryocooling to obtain cryocooled protein crystal allowing collection of high resolution data and by heavier noble gas (krypton or xenon) binding followed by helium pressurizing and cryocooling to obtain cryocooled protein crystal for collection of high resolution data and SAD phasing simultaneously. The helium pressurizing is carried out on crystal coated to prevent dehydration or on crystal grown in aqueous solution in a capillary.

  10. Analysis of Capillary Rise in Asymmetric Branch-Like Capillary

    Science.gov (United States)

    Li, Caoxiong; Shen, Yinghao; Ge, Hongkui; Yang, Zhihui; Su, Shuai; Ren, Kai; Huang, Heyu

    2016-05-01

    Transport in porous media is common in nature, attracting many attentions for a long time. Tree-like network model is often used as a simplification for porous space, expressing the complexity of pore spaces instead of capillary bundle. To investigate spontaneous imbibition characteristics in this network, a dynamic asymmetric branch-like capillary model is used to represent basic network structure, using fractal method to represent tortuosity. This work investigates the influence of parameters on imbibition process in the branch-like capillary model. An analytical equation for the imbibition mass versus time is derived. Parameters from capillary structures to liquid properties are taken into account and analyzed based on the numerical solution of the equation. It is found that the imbibition process in asymmetric branch-like capillary model can be recognized by four sections and brunching tubes are positive for imbibition process. Concomitantly, meniscus arrest event is simulated and discussed. Moreover, the influence of parameters on imbibition process is discussed. These parameters can be classified as static and dynamic. Static parameters mainly change the capillary force, which are related to the ultimate imbibition mass or imbibition ability, while dynamic parameters mainly have influence on resistance of flowing fluid, which are related to the imbibition speed in the imbibition process.

  11. Saturation dynamics and working limits of saturated absorption cavity ringdown spectroscopy.

    Science.gov (United States)

    Sadiek, Ibrahim; Friedrichs, Gernot

    2016-08-17

    Cavity ringdown spectroscopy (CRDS) in the linear absorption regime is a well-established method for sensitive trace gas detection, but only a few studies have addressed quantitative measurements in the presence of a saturated sample. In fact, saturation is usually avoided in order to escape from the required complex modeling of the saturation process that depends on the characteristics of the absorbing species, its interaction with the surrounding gas as well as on the temporal and spectral characteristics of the cavity excitation. Conversely, the novel saturated-absorption cavity ringdown spectroscopy approach (SCAR/Sat-CRDS) takes advantage of sample saturation in order to allow one to extract both the gas absorption and the empty cavity loss rates from a single ringdown event. Using a new continuous-wave infrared CRD spectrometer equipped with a tunable narrow-bandwidth high-power OPO laser system and a 18 bit digitizer, the transient dynamics of absorption saturation and the working limits of the Sat-CRDS approach in terms of its ability to extract reliable trace gas concentrations have been experimentally studied in this work. Using a strong methane transition as a test case, the excitation power P0 and saturation power PS have been systematically varied to explore a wide range of saturation regimes. At pressures 5 μbar γc, a pronounced coupling between the two parameters has been observed. Finally, a standard error analysis was performed revealing that the Sat-CRDS approach holds its advantages over conventional CRDS implementations in particular when the attainable ultimate detection sensitivity is limited by uncertainties in the empty cavity ringdown constant.

  12. DNA typing by capillary electrophoresis

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, N.

    1997-10-08

    Capillary electrophoresis is becoming more and more important in nucleic acid analysis including DNA sequencing, typing and disease gene measurements. This work summarized the background of DNA typing. The recent development of capillary electrophoresis was also discussed. The second part of the thesis showed the principle of DNA typing based on using the allelic ladder as the absolute standard ladder in capillary electrophoresis system. Future work will be focused on demonstrating DNA typing on multiplex loci and examples of disease diagnosis in the on-line format of PCR-CE. Also capillary array electrophoresis system should allow high throughput, fast speed DNA typing. Only the introduction and conclusions for this report are available here. A reprint was removed for separate processing.

  13. Selectivity in capillary electrokinetic separations

    NARCIS (Netherlands)

    de Zeeuw, R.A; de Jong, G.J.; Ensing, K

    1999-01-01

    This review gives a survey of selectivity modes in capillary electrophoresis separations in pharmaceutical analysis and bioanalysis. Despite the high efficiencies of these separation techniques, good selectivity is required to allow quantitation or identification of a Chemistry and Toxicology, parti

  14. Stress failure of pulmonary capillaries: role in lung and heart disease

    Science.gov (United States)

    West, J. B.; Mathieu-Costello, O.

    1992-01-01

    Pulmonary capillaries have extremely thin walls to allow rapid exchange of respiratory gases across them. Recently it has been shown that the wall stresses become very large when the capillary pressure is raised, and in anaesthetised rabbits, ultrastructural damage to the walls is seen at pressures of 40 mm Hg and above. The changes include breaks in the capillary endothelial layer, alveolar epithelial layer, and sometimes all layers of the wall. The strength of the thin part of the capillary wall can be attributed to the type IV collagen in the extracellular matrix. Stress failure of pulmonary capillaries results in a high-permeability form of oedema, or even frank haemorrhage, and is apparently the mechanism of neurogenic pulmonary oedema and high-altitude pulmonary oedema. It also explains the exercise-induced pulmonary haemorrhage that occurs in all racehorses. Several features of mitral stenosis are consistent with stress failure. Overinflation of the lung also leads to stress failure, a common cause of increased capillary permeability in the intensive care environment. Stress failure also occurs if the type IV collagen of the capillary wall is weakened by autoantibodies as in Goodpasture's syndrome. Neutrophil elastase degrades type IV collagen and this may be the starting point of the breakdown of alveolar walls that is characteristic of emphysema. Stress failure of pulmonary capillaries is a hitherto overlooked and potentially important factor in lung and heart disease.

  15. New type of capillary for use as ion beam collimator and air-vacuum interface

    Energy Technology Data Exchange (ETDEWEB)

    Stoytschew, V., E-mail: valostoytschew@hotmail.com [Ruđer Bošković Institute, Bijenicka Cesta 54, 10000 Zagreb (Croatia); Schulte-Borchers, M. [Laboratory of Ion Beam Physics, ETH Zurich, Otto-Stern-Weg 5, CH-8093 Zurich (Switzerland); Božičević Mihalića, Iva [Ruđer Bošković Institute, Bijenicka Cesta 54, 10000 Zagreb (Croatia); Perez, R.D. [FaMAF, Universidad Nacional de Córdoba, (5000) Ciudad Universitaria, Córdoba (Argentina)

    2016-08-01

    Glass capillaries offer a unique way to combine small diameter ion beam collimation with an air-vacuum interface for ambient pressure ion beam applications. Usually they have an opening diameter of a few microns, limiting the air inflow sufficiently to maintain stable conditions on the vacuum side. As the glass capillaries generally are quite thin and fragile, handling of the capillary in the experiment becomes difficult. They also introduce an X-ray background produced by the capillary wall material, which has to be shielded or subtracted from the data for Particle Induced X-ray Emission (PIXE) applications. To overcome both drawbacks, a new type of conical glass capillary has been developed. It has a higher wall thickness eliminating the low energy X-ray background produced by common capillaries and leading to a more robust lens. The results obtained in first tests show, that this new capillary is suitable for ion beam collimation and encourage further work on the capillary production process to provide thick wall capillaries with an outlet diameter in the single digit micro- or even nanometre range.

  16. Capillary Rise of Magnetohydrodynamics Liquid into Deformable Porous Material

    Directory of Open Access Journals (Sweden)

    Javed I Siddique

    2016-01-01

    Full Text Available We have developed a mathematical model for capillary rise of magnetohydrodynamic fluids. The liquid starts to imbibe because of capillary suction in an undeformed and initially dry sponge-like porous material. The driving force in our model is a pressure gradient across the evolving porous material that induces a stress gradient which in turn causes deformation that is characterized by a variable solid fraction. The problem is formulated as a non–linear moving boundary problem which we solve using the method of lines approach after transforming to a fixed computational domain. The summary of our finding includes a notable reduction in capillary rise and a decrease in solid deformation due to magnetic effects.

  17. On the capillary self-focusing in a microfluidic system

    CERN Document Server

    Hein, M; Afkhami, S

    2016-01-01

    A computational framework is developed to address capillary self-focusing in Step Emulsification. The microfluidic system consists of a single shallow and wide microchannel that merges into a deep reservoir. A continuum approach coupled with a volume of fluid method is used to model the capillary self-focusing effect. The original governing equations are reduced using the Hele-Shaw approximation. We show that the interface between the two fluids takes the shape of a neck narrowing in the flow direction just before entering the reservoir, in agreement with our experimental observations. Our computational model relies on the assumption that the pressure at the boundary, where the fluid exits into the reservoir, is the uniform pressure in the reservoir. We investigate this hypothesis by comparing the numerical results with experimental data. We conjecture that the pressure boundary condition becomes important when the width of the neck is comparable to the depth of the microchannel. A correction to the exit pres...

  18. Casimir experiments showing saturation effects

    CERN Document Server

    Sernelius, Bo E

    2009-01-01

    We address several different Casimir experiments where theory and experiment disagree. First out is the classical Casimir force measurement between two metal half spaces; here both in the form of the torsion pendulum experiment by Lamoreaux and in the form of the Casimir pressure measurement between a gold sphere and a gold plate as performed by Decca et al.; theory predicts a large negative thermal correction, absent in the high precision experiments. The third experiment is the measurement of the Casimir force between a metal plate and a laser irradiated semiconductor membrane as performed by Chen et al.; the change in force with laser intensity is larger than predicted by theory. The fourth experiment is the measurement of the Casimir force between an atom and a wall in the form of the measurement by Obrecht et al. of the change in oscillation frequency of a 87 Rb Bose-Einstein condensate trapped to a fused silica wall; the change is smaller than predicted by theory. We show that saturation effects can exp...

  19. Controls on Highly Siderophile Element Concentrations in Martian Basalt: Sulfide Saturation and Under-Saturation

    Science.gov (United States)

    Righter, Kevin

    2009-01-01

    Highly siderophile elements (HSE; Re, Au and the platinum group elements) in shergottites exhibit a wide range from very high, similar to the terrestrial mantle, to very low, similar to sulfide saturated mid ocean ridge basalt (e.g., [1]). This large range has been difficult to explain without good constraints on sulfide saturation or under-saturation [2]. A new model for prediction of sulfide saturation places new constraints on this problem [3]. Shergottite data: For primitive shergottites, pressure and temperature estimates are between 1.2-1.5 GPa, and 1350-1470 C [4]. The range of oxygen fugacities is from FMQ-2 to IW, where the amount of Fe2O3 is low and thus does not have a significant effect on the S saturation values. Finally, the bulk compositions of shergottites have been reported in many recent studies (e.g., [5]). All of this information will be used to test whether shergottites are sulfide saturated [3]. Modeling values and results: The database for HSE partition coefficients has been growing with many new data for silicates and oxides [6-8] to complement a large sulfide database [9- 11]. Combining these data with simple batch melting models allows HSE contents of mantle melts to be estimated for sulfide-bearing vs. sulfide-free mantle. Combining such models with fractional crystallization modeling (e.g., [12]) allows HSE contents of more evolved liquids to be modeled. Most primitive shergottites have high HSE contents (and low S contents) that can be explained by sulfide under-saturated melting of the mantle. An exception is Dhofar 019 which has high S contents and very low HSE contents suggesting sulfide saturation. Most evolved basaltic shergottites have lower S contents than saturation, and intermediate HSE contents that can be explained by olivine, pyroxene, and chromite fractionation. An exception is EET A79001 lithology B, which has very low HSE contents and S contents higher than sulfide saturation values . evidence for sulfide saturation

  20. Saturated Zone Colloid Transport

    Energy Technology Data Exchange (ETDEWEB)

    H. S. Viswanathan

    2004-10-07

    This scientific analysis provides retardation factors for colloids transporting in the saturated zone (SZ) and the unsaturated zone (UZ). These retardation factors represent the reversible chemical and physical filtration of colloids in the SZ. The value of the colloid retardation factor, R{sub col} is dependent on several factors, such as colloid size, colloid type, and geochemical conditions (e.g., pH, Eh, and ionic strength). These factors are folded into the distributions of R{sub col} that have been developed from field and experimental data collected under varying geochemical conditions with different colloid types and sizes. Attachment rate constants, k{sub att}, and detachment rate constants, k{sub det}, of colloids to the fracture surface have been measured for the fractured volcanics, and separate R{sub col} uncertainty distributions have been developed for attachment and detachment to clastic material and mineral grains in the alluvium. Radionuclides such as plutonium and americium sorb mostly (90 to 99 percent) irreversibly to colloids (BSC 2004 [DIRS 170025], Section 6.3.3.2). The colloid retardation factors developed in this analysis are needed to simulate the transport of radionuclides that are irreversibly sorbed onto colloids; this transport is discussed in the model report ''Site-Scale Saturated Zone Transport'' (BSC 2004 [DIRS 170036]). Although it is not exclusive to any particular radionuclide release scenario, this scientific analysis especially addresses those scenarios pertaining to evidence from waste-degradation experiments, which indicate that plutonium and americium may be irreversibly attached to colloids for the time scales of interest. A section of this report will also discuss the validity of using microspheres as analogs to colloids in some of the lab and field experiments used to obtain the colloid retardation factors. In addition, a small fraction of colloids travels with the groundwater without any significant

  1. Image-Based Modeling of Blood Flow and Oxygen Transfer in Feto-Placental Capillaries

    Science.gov (United States)

    Brownbill, Paul; Janáček, Jiří; Jirkovská, Marie; Kubínová, Lucie; Chernyavsky, Igor L.; Jensen, Oliver E.

    2016-01-01

    During pregnancy, oxygen diffuses from maternal to fetal blood through villous trees in the placenta. In this paper, we simulate blood flow and oxygen transfer in feto-placental capillaries by converting three-dimensional representations of villous and capillary surfaces, reconstructed from confocal laser scanning microscopy, to finite-element meshes, and calculating values of vascular flow resistance and total oxygen transfer. The relationship between the total oxygen transfer rate and the pressure drop through the capillary is shown to be captured across a wide range of pressure drops by physical scaling laws and an upper bound on the oxygen transfer rate. A regression equation is introduced that can be used to estimate the oxygen transfer in a capillary using the vascular resistance. Two techniques for quantifying the effects of statistical variability, experimental uncertainty and pathological placental structure on the calculated properties are then introduced. First, scaling arguments are used to quantify the sensitivity of the model to uncertainties in the geometry and the parameters. Second, the effects of localized dilations in fetal capillaries are investigated using an idealized axisymmetric model, to quantify the possible effect of pathological placental structure on oxygen transfer. The model predicts how, for a fixed pressure drop through a capillary, oxygen transfer is maximized by an optimal width of the dilation. The results could explain the prevalence of fetal hypoxia in cases of delayed villous maturation, a pathology characterized by a lack of the vasculo-syncytial membranes often seen in conjunction with localized capillary dilations. PMID:27788214

  2. Two-dimensional capillary electrophoresis using tangentially connected capillaries.

    Science.gov (United States)

    Sahlin, Eskil

    2007-06-22

    A novel type of fused silica capillary system is described where channels with circular cross-sections are tangentially in contact with each other and connected through a small opening at the contact area. Since the channels are not crossing each other in the same plane, the capillaries can easily be filled with different solutions, i.e. different solutions will be in contact with each other at the contact point. The system has been used to perform different types of two-dimensional separations and the complete system is fully automated where a high voltage switch is used to control the location of the high voltage in the system. Using two model compounds it is demonstrated that a type of two-dimensional separation can be performed using capillary zone electrophoresis at two different pH values. It is also shown that a compound with acid/base properties can be concentrated using a dynamic pH junction mechanism when transferred from the first separation to the second separation. In addition, the system has been used to perform a comprehensive two-dimensional capillary electrophoresis separation of tryptic digest of bovine serum albumin using capillary zone electrophoresis followed by micellar electrokinetic chromatography.

  3. Development of a capillary electrophoresis-mass spectrometry method using polymer capillaries for metabolomic analysis of yeast.

    Science.gov (United States)

    Tanaka, Yoshihide; Higashi, Tetsuji; Rakwal, Randeep; Wakida, Shin-ichi; Iwahashi, Hitoshi

    2008-05-01

    Metabolomics is an emerging field in analytical biochemistry, and the development of such a method for comprehensive and quantitative analysis of organic acids, carbohydrates, and nucleotides is a necessity in the era of functional genomics. When a concentrated yeast extract was analyzed by CE-MS using a successive multiple ionic-polymer layer (SMIL)-coated capillary, the adsorption of the contaminants on the capillary wall caused severe problems such as no elution, band-broadening, and asymmetric peaks. Therefore, an analytical method for the analysis of anionic metabolites in yeast was developed by pressure-assisted CE using an inert polymer capillary made from poly(ether etherketone) (PEEK) and PTFE. We preferred to use the PEEK over the PTFE capillary in CE-MS due to the easy-to-use PEEK capillary and its high durability. The separation of anionic metabolites was successfully achieved with ammonium hydrogencarbonate/formate buffer (pH 6.0) as the electrolyte solution. The use of 2-propanol washing after every electrophoresis run not only eliminated wall-adsorption phenomena, but allowed for good repeatability to be obtained for migration times in the metabolomic analysis.

  4. Saturated fats: what dietary intake?

    Science.gov (United States)

    German, J Bruce; Dillard, Cora J

    2004-09-01

    Public health recommendations for the US population in 1977 were to reduce fat intake to as low as 30% of calories to lower the incidence of coronary artery disease. These recommendations resulted in a compositional shift in food materials throughout the agricultural industry, and the fractional content of fats was replaced principally with carbohydrates. Subsequently, high-carbohydrate diets were recognized as contributing to the lipoprotein pattern that characterizes atherogenic dyslipidemia and hypertriacylglycerolemia. The rising incidences of metabolic syndrome and obesity are becoming common themes in the literature. Current recommendations are to keep saturated fatty acid, trans fatty acid, and cholesterol intakes as low as possible while consuming a nutritionally adequate diet. In the face of such recommendations, the agricultural industry is shifting food composition toward lower proportions of all saturated fatty acids. To date, no lower safe limit of specific saturated fatty acid intakes has been identified. This review summarizes research findings and observations on the disparate functions of saturated fatty acids and seeks to bring a more quantitative balance to the debate on dietary saturated fat. Whether a finite quantity of specific dietary saturated fatty acids actually benefits health is not yet known. Because agricultural practices to reduce saturated fat will require a prolonged and concerted effort, and because the world is moving toward more individualized dietary recommendations, should the steps to decrease saturated fatty acids to as low as agriculturally possible not wait until evidence clearly indicates which amounts and types of saturated fatty acids are optimal?

  5. Testing Saturation at Hadron Colliders

    CERN Document Server

    Marquet, C

    2003-01-01

    We extend the saturation models a la Golec-Biernat and Wusthoff to cross-sections of hard processes initiated by virtual-gluon probes separated by large rapidity intervals at hadron colliders. We derive their analytic expressions and apply them to physical examples, such as saturation effects for Mueller-Navelet jets. By comparison to gamma*-gamma* cross-sections we find a more abrupt transition to saturation. We propose to study observables with a potentially clear saturation signal and to use heavy vector and flavored mesons as alternative virtual-gluon probes.

  6. Experimental study of crossover from capillary to viscous fingering for supercritical CO2-water displacement in a homogeneous pore network.

    Science.gov (United States)

    Wang, Ying; Zhang, Changyong; Wei, Ning; Oostrom, Mart; Wietsma, Thomas W; Li, Xiaochun; Bonneville, Alain

    2013-01-02

    Carbon sequestration in saline aquifers involves displacing brine from the pore space by supercritical CO(2) (scCO(2)). The displacement process is considered unstable due to the unfavorable viscosity ratio between the invading scCO(2) and the resident brine. The mechanisms that affect scCO(2)-water displacement under reservoir conditions (41 °C, 9 MPa) were investigated in a homogeneous micromodel. A large range of injection rates, expressed as the dimensionless capillary number (Ca), was studied in two sets of experiments: discontinuous-rate injection, where the micromodel was saturated with water before each injection rate was imposed, and continuous-rate injection, where the rate was increased after quasi-steady conditions were reached for a certain rate. For the discontinuous-rate experiments, capillary fingering and viscous fingering are the dominant mechanisms for low (logCa ≤ -6.61) and high injection rates (logCa ≥ -5.21), respectively. Crossover from capillary to viscous fingering was observed for logCa = -5.91 to -5.21, resulting in a large decrease in scCO(2) saturation. The discontinuous-rate experimental results confirmed the decrease in nonwetting fluid saturation during crossover from capillary to viscous fingering predicted by numerical simulations by Lenormand et al. (J. Fluid Mech.1988, 189, 165-187). Capillary fingering was the dominant mechanism for all injection rates in the continuous-rate experiment, resulting in monotonic increase in scCO(2) saturation.

  7. 高压饱和蒸汽热处理对小叶杨结晶特性的影响%INFLUENCE OF HIGH PRESSURE SATURATED STEAM HEAT TREATMENT ON XRD PROPERTIES OF Populus simonii

    Institute of Scientific and Technical Information of China (English)

    赵红霞; 安珍

    2012-01-01

    In this paper, we take populus simonii as test material, which has been considered as common species in Ordos region of Inner Mongolia. Choose saturated steam as the heat transfer medium, and the saturated steam heat treatment temperature are 160℃ (0. 6MPa) 1701℃(0.8MPa)and 180℃(1.0MPa) ,the heat time are lh,2h and 3h for each temperature. The influence of heat treatment temperature and time on XRD characteristics have been analyzed and studied by using X - Ray duTractomer. The results indicate that the relative crystallinity of heat treatment samples show a tendency of rising, with the increase in temperature and time. And when the saturated steam heat treatment temperature is 180℃ (1. OMPa), the heat time is 3h, the relative crystallinity of treatment sample up to 68.51% , which is 24.35% higher than untreated samples.%H本文以内蒙古鄂尔多斯地区常见树种小叶杨为试材,饱和蒸汽为传热介质,饱和蒸汽温度为160℃ (0.6MPa)、170℃ (0.8MPa)和180℃(1.0MPa),处理时间为1h、2h和3h对试材进行不同条件的热处理,通过X射线衍射仪研究和分析热处理温度、热处理时间对处理材结晶特性的影响,结果表明:处理材的相对结晶度随温度的升高和时间的延长而增大;当饱和蒸汽温度为180℃(1.0MPa)、时间为3h时,处理材的相对结晶度最高为68.51%,比对照组高24.35%.

  8. Saturated fats: a perspective from lactation and milk composition.

    Science.gov (United States)

    German, J Bruce; Dillard, Cora J

    2010-10-01

    For recommendations of specific targets for the absolute amount of saturated fat intake, we need to know what dietary intake is most appropriate? Changing agricultural production and processing to lower the relative quantities of macronutrients requires years to accomplish. Changes can have unintended consequences on diets and the health of subsets of the population. Hence, what are the appropriate absolute amounts of saturated fat in our diets? Is the scientific evidence consistent with an optimal intake of zero? If not, is it also possible that a finite intake of saturated fats is beneficial to overall health, at least to a subset of the population? Conclusive evidence from prospective human trials is not available, hence other sources of information must be considered. One approach is to examine the evolution of lactation, and the composition of milks that developed through millennia of natural selective pressure and natural selection processes. Mammalian milks, including human milk, contain 50% of their total fatty acids as saturated fatty acids. The biochemical formation of a single double bond converting a saturated to a monounsaturated fatty acid is a pathway that exists in all eukaryotic organisms and is active within the mammary gland. In the face of selective pressure, mammary lipid synthesis in all mammals continues to release a significant content of saturated fatty acids into milk. Is it possible that evolution of the mammary gland reveals benefits to saturated fatty acids that current recommendations do not consider?

  9. Saturation of Zonal Flows

    Science.gov (United States)

    Kim, Eun-Jin

    2002-11-01

    Zonal flows (ZF) are generated by drift wave (DW) turbulence and then regulate it near marginality by shear suppression. Since collisions damp ZF while ZF suppress DW, the amplitude of DW turbulence (i.e. turbulent transport) is, in turn, proportional to collisionality. A key question is then what happens away from marginality, namely what is the saturation mechanism of ZF in that regime? This raises the interesting physical question of how ZF interact with mne 0, poloidally non-axisymmetric modes [1], both linearly and non linearly. We investigate this issue by exploring the nonlinear excitation of GKH modes by modulational instability in the background of finite amplitude of DW turbulence, as well as the linear inflection-type instability of ZF. In a simple model with cold ions, we show that ZF can grow faster than the linear GKH for γ/ωGKH modes can be comparable to their linear generation. Here, γ and ω are the growth rate and frequency of DW, and p and k are the characteristic wavenumbers of ZF and DW. These findings imply that the linear analysis of GKH may not always be valid and also that there may be no clear distinction between secondary (ZF) and tertiary mode (GKH). The effect of finite ion temperature fluctuations is incorporated in a simple toroidal ion temperature gradient model, within which both zonal flow and temperature are generated by modulational instability. The phase between the two is calculated self-consistently and shown to be positive. Furthermore, the correction to nonlinear generation of GKH modes appears to be small. [1] We refer to these low mne 0 modes as Generalized Kelvin-Helmholtz (GKH) modes, since they will appear as mne 0 distortions of a shear layer.

  10. Observations of gravity-capillary lump interactions

    CERN Document Server

    Masnadi, Naeem

    2016-01-01

    In this experimental study, we investigate the interaction of gravity-capillary solitary waves generated by two surface pressure sources moving side by side at constant speed. The nonlinear response of a water surface to a single source moving at a speed just below the minimum phase speed of linear gravity-capillary waves in deep water ($c_{min}\\approx23$ cm s$^{-1}$) consists of periodic generation of pairs of three-dimensional solitary waves (or lumps) in a V-shaped pattern downstream of the source. In the reference frame of the laboratory, these unsteady lumps propagate in a direction oblique to the motion of the source. In the present experiments, the strength of the two sources is adjusted to produce nearly identical responses and the free surface deformations are visualized using photography-based techniques. The first lumps generated by the two sources move in intersecting directions that make a half angle of approximately 15 degrees and collide in the center-plane between the sources. A steep depressi...

  11. Brief Review of Saturation Physics

    CERN Document Server

    Kovchegov, Yuri V

    2014-01-01

    We present a short overview of saturation physics followed by a summary of the recent progress in our understanding of nonlinear small-$x$ evolution. Topics include McLerran-Venugopalan model, Glauber-Mueller approximation, nonlinear BK/JIMWLK evolution equations, along with the running-coupling and NLO corrections to these equations. We conclude with selected topics in saturation phenomenology.

  12. Brine Distribution after Vacuum Saturation

    DEFF Research Database (Denmark)

    Hedegaard, Kathrine; Andersen, Bertel Lohmann

    1999-01-01

    Experiments with the vacuum saturation method for brine in plugs of chalk showed that a homogeneous distribution of brine cannot be ensured at saturations below 20% volume. Instead of a homogeneous volume distribution the brine becomes concentrated close to the surfaces of the plugs...

  13. Non-Aqueous Capillary Electrophoresis

    Science.gov (United States)

    Szumski, Michał; Buszewski, Bogusław

    Non-aqueous capillary electrophoresis and capillary electrochromatography are special variants of these techniques. Here, organic solvents or their mixtures with or without dissolved electrolytes are used as separation buffer or mobile phase, respectively. The most important features of non-aqueous systems are: better solubility of more hydrophobic ionic substances (many natural products) than in water, much less current and Joule heating allows for using highly concentrated buffers and/or larger capillary internal diameters, polar interactions are enhanced in organic solvents which is often highly advantageous in chiral separation systems. This chapter presents most frequently used solvents, their properties, as well as shows pH* scale which is often used in non-aqueous systems.

  14. Capillary Action in a Crack on the Surface of Asteroids with an Application to 433 Eros

    CERN Document Server

    Jiang, Yu

    2016-01-01

    Some asteroids contain water ice, and a space mission landing on an asteroid may take liquid to the surface of the asteroid. Gas pressure is very weak on the surface of asteroids. Here we consider the capillary action in a crack on the surface of irregular asteroids. The crack is modelled as a capillary which has a fixed radius. An asteroid s irregular gravitational potential influences the height of the liquid in the capillary. The height of the liquid in the capillary on the surface of such asteroids is derived from the asteroid s irregular gravitational potential. Capillary mechanisms are expected to produce an inhomogeneaous distribution of emergent liquid on the surface. This result is applied to asteroid 433 Eros, which has an irregular, elongated, and concave shape. Two cases are considered 1) we calculate the height of the liquid in the capillary when the direction of the capillary is perpendicular to the local surface of the asteroid; 2) we calculate the height of the liquid in the capillary when the...

  15. Shear distortion and failure of capillary bridges. Wetting information beyond contact angle analysis.

    Science.gov (United States)

    Wang, Liming; McCarthy, Thomas J

    2013-06-25

    Water capillary bridges are prepared that span hydrophilic pinning features on parallel opposing smooth, flat, and hydrophobic surfaces. These bridges are distorted by shearing the parallel plates at a low rate. The capillary bridges lengthen and distort to balance Laplace pressure (equilibrate mean curvature) as the features are separated and eventually rupture at a distance that is a function of the liquid volume, the advancing and receding contact angles of the surfaces, the separation between the parallel surfaces, and in particular, the shape and orientation of the hydrophilic pinning features. Two modes of capillary bridge failure are observed: (1) tensile, in which the capillary bridge breaks to form sessile drops on both the upper and lower surfaces, and (2) sessile, in which sessile capillary bridge rupture occurs on one surface to form a puddle (contact-line-distorted sessile drop) on the feature and a retained capillary bridge spanning the hydrophobic surface and the hydrophilic feature on the opposing surface. The shape and orientation of the features control the mode of capillary bridge failure as well as the distribution of water between the two separate sessile drops or the retained capillary bridge and the puddle.

  16. A Numerical Modeling Study of Effect of Heterogeneity on Capillary Trapping of Geologically Sequestrated CO2

    Science.gov (United States)

    Cihan, A.; Birkholzer, J. T.; Zhou, Q.; Trevisan, L.; Illangasekare, T. H.; Rodriguez, D.; Sakaki, T.

    2011-12-01

    Heterogeneities at multiple scales influence migration and trapping of geologically sequestrated CO2 during injection and post-injection periods. Understanding of small-scale processes is crucial to device upscaling methodologies for incorporating them into macroscopic-scale models. The upscaled models are in turn used to get insights into the complex field-scale processes involved in the migration of supercritical CO2. Theoretical research based on numerical model analysis presented in this study focuses on capillary entrapment in homogeneous and heterogeneous small-scale and intermediate-scale laboratory experiments with surrogate fluids, presented in a companion presentation (Treviso et al., 2011). An improved understanding of pore-scale and larger scale processes on capillary entrapment may be achieved by combining pore-scale and macroscopic-scale modeling approaches. Capillarity controlled entrapped non-wetting phase saturation in macroscopic-scale models is generally either provided as an input parameter after laboratory scale measurements or estimated empirically. A particle trajectory modeling approach with pore-scale physics included is used to gain insights to development of physically-based models for the capillary entrapment in homogeneous and heterogeneous systems. The particle trajectory modeling generates functional relationships between phase saturation, entrapped phase saturation, hydraulic properties of the medium, and velocity of injected phase, which eventually are planned to be used for developing macroscopic scale models of capillary entrapment. The predictions of entrapped fluid saturation from the particle trajectory model are verified with measurements from the small scale experimental test systems. Macroscopic two-phase flow modeling approach with existing and modified constitutive models is tested by comparisons with both small-scale and intermediate-scale experimental results. T2VOC module based on TOUGH2 is used to simulate two

  17. Biodegradation of phenol, salicylic acid, benzenesulfonic acid, and iomeprol by Pseudomonas fluorescens in the capillary fringe

    Science.gov (United States)

    Hack, Norman; Reinwand, Christian; Abbt-Braun, Gudrun; Horn, Harald; Frimmel, Fritz H.

    2015-12-01

    Mass transfer and biological transformation phenomena in the capillary fringe were studied using phenol, salicylic acid, benzenesulfonic acid, and the iodinated X-ray contrast agent iomeprol as model organic compounds and the microorganism strain Pseudomonas fluorescens. Three experimental approaches were used: Batch experiments (uniform water saturation and transport by diffusion), in static columns (with a gradient of water saturation and advective transport in the capillaries) and in a flow-through cell (with a gradient of water saturation and transport by horizontal and vertical flow: 2-dimension flow-through microcosm). The reactors employed for the experiments were filled with quartz sand of defined particle size distribution (dp = 200…600 μm, porosity ε = 0.42). Batch experiments showed that phenol and salicylic acid have a high, whereas benzenesulfonic acid and iomeprol have a quite low potential for biodegradation under aerobic conditions and in a matrix nearly close to water saturation. Batch experiments under anoxic conditions with nitrate as electron acceptor revealed that the biodegradation of the model compounds was lower than under aerobic conditions. Nevertheless, the experiments showed that the moisture content was also responsible for an optimized transport in the liquid phase of a porous medium. Biodegradation in the capillary fringe was found to be influenced by both the moisture content and availability of the dissolved substrate, as seen in static column experiments. The gas-liquid mass transfer of oxygen also played an important role for the biological activity. In static column experiments under aerobic conditions, the highest biodegradation was found in the capillary fringe (e.g. βt/β0 (phenol) = 0 after t = 6 d) relative to the zone below the water table and unsaturated zone. The highest biodegradation occurred in the flow-through cell experiment where the height of the capillary fringe was largest.

  18. Biodegradation of phenol, salicylic acid, benzenesulfonic acid, and iomeprol by Pseudomonas fluorescens in the capillary fringe.

    Science.gov (United States)

    Hack, Norman; Reinwand, Christian; Abbt-Braun, Gudrun; Horn, Harald; Frimmel, Fritz H

    2015-12-01

    Mass transfer and biological transformation phenomena in the capillary fringe were studied using phenol, salicylic acid, benzenesulfonic acid, and the iodinated X-ray contrast agent iomeprol as model organic compounds and the microorganism strain Pseudomonas fluorescens. Three experimental approaches were used: Batch experiments (uniform water saturation and transport by diffusion), in static columns (with a gradient of water saturation and advective transport in the capillaries) and in a flow-through cell (with a gradient of water saturation and transport by horizontal and vertical flow: 2-dimension flow-through microcosm). The reactors employed for the experiments were filled with quartz sand of defined particle size distribution (dp=200...600 μm, porosity ε=0.42). Batch experiments showed that phenol and salicylic acid have a high, whereas benzenesulfonic acid and iomeprol have a quite low potential for biodegradation under aerobic conditions and in a matrix nearly close to water saturation. Batch experiments under anoxic conditions with nitrate as electron acceptor revealed that the biodegradation of the model compounds was lower than under aerobic conditions. Nevertheless, the experiments showed that the moisture content was also responsible for an optimized transport in the liquid phase of a porous medium. Biodegradation in the capillary fringe was found to be influenced by both the moisture content and availability of the dissolved substrate, as seen in static column experiments. The gas-liquid mass transfer of oxygen also played an important role for the biological activity. In static column experiments under aerobic conditions, the highest biodegradation was found in the capillary fringe (e.g. βt/β0 (phenol)=0 after t=6 d) relative to the zone below the water table and unsaturated zone. The highest biodegradation occurred in the flow-through cell experiment where the height of the capillary fringe was largest.

  19. Capillary interactions in Pickering emulsions

    Science.gov (United States)

    Guzowski, J.; Tasinkevych, M.; Dietrich, S.

    2011-09-01

    The effective capillary interaction potentials for small colloidal particles trapped at the surface of liquid droplets are calculated analytically. Pair potentials between capillary monopoles and dipoles, corresponding to particles floating on a droplet with a fixed center of mass and subjected to external forces and torques, respectively, exhibit a repulsion at large angular separations and an attraction at smaller separations, with the latter resembling the typical behavior for flat interfaces. This change of character is not observed for quadrupoles, corresponding to free particles on a mechanically isolated droplet. The analytical results are compared with the numerical minimization of the surface free energy of the droplet in the presence of spherical or ellipsoidal particles.

  20. Molecular transport through capillaries made with atomic-scale precision

    Science.gov (United States)

    Radha, B.; Esfandiar, A.; Wang, F. C.; Rooney, A. P.; Gopinadhan, K.; Keerthi, A.; Mishchenko, A.; Janardanan, A.; Blake, P.; Fumagalli, L.; Lozada-Hidalgo, M.; Garaj, S.; Haigh, S. J.; Grigorieva, I. V.; Wu, H. A.; Geim, A. K.

    2016-10-01

    Nanometre-scale pores and capillaries have long been studied because of their importance in many natural phenomena and their use in numerous applications. A more recent development is the ability to fabricate artificial capillaries with nanometre dimensions, which has enabled new research on molecular transport and led to the emergence of nanofluidics. But surface roughness in particular makes it challenging to produce capillaries with precisely controlled dimensions at this spatial scale. Here we report the fabrication of narrow and smooth capillaries through van der Waals assembly, with atomically flat sheets at the top and bottom separated by spacers made of two-dimensional crystals with a precisely controlled number of layers. We use graphene and its multilayers as archetypal two-dimensional materials to demonstrate this technology, which produces structures that can be viewed as if individual atomic planes had been removed from a bulk crystal to leave behind flat voids of a height chosen with atomic-scale precision. Water transport through the channels, ranging in height from one to several dozen atomic planes, is characterized by unexpectedly fast flow (up to 1 metre per second) that we attribute to high capillary pressures (about 1,000 bar) and large slip lengths. For channels that accommodate only a few layers of water, the flow exhibits a marked enhancement that we associate with an increased structural order in nanoconfined water. Our work opens up an avenue to making capillaries and cavities with sizes tunable to ångström precision, and with permeation properties further controlled through a wide choice of atomically flat materials available for channel walls.

  1. Modeling of Water Movement Near Saturation

    Science.gov (United States)

    Ippisch, O.; Graf, H.; Bastian, P.; Roth, K.

    Water transport in unsaturated porous media is often described using Richards' equa- tion. However Richards' equation is based on the assumption that the gas phase is mobile enough to be always (nearly) at atmospheric pressure. This assumption is not valid if the porous medium is nearly saturated with water. The difference between model calculations using Richards' equation and a multiphase formulation is analyzed and compared to results from multistep outflow experiments with columns of sintered glass. The chosen parameterization for the hydraulic param- eters (van Genuchten/Brooks-Corey) proves to expecially important.

  2. Characterization of pulsed capillary channel gas puff target using EUV shadowgraphy

    Energy Technology Data Exchange (ETDEWEB)

    Wachulak, P.W., E-mail: wachulak@gmail.com; Bartnik, A.; Węgrzyński, Ł.; Fok, T.; Kostecki, J.; Szczurek, M.; Jarocki, R.; Fiedorowicz, H.

    2015-02-15

    Characterization measurements of a pulsed capillary channel gas puff target, developed for applications in laser-matter interaction experiments, are presented. The target is produced by pulsed injection of gas through a slit-shaped nozzle into a capillary channel and has been characterized by EUV radiography at 13.5 nm wavelength. Time dependent gas flow effects and flow shaping by capillary walls were visualized. Density measurements for argon were performed on axis for variable timing conditions and variable backing pressures. This target, due to its advantages, might be an interesting alternative for lower repetition rate and higher energy laser-matter interaction experiments.

  3. Fabrication and modeling of narrow capillaries for vacuum system gas inlets

    DEFF Research Database (Denmark)

    Quaade, Ulrich; Jensen, Søren; Hansen, Ole

    2005-01-01

    Micrometer-sized cylindrical capillaries with well-controlled dimensions are fabricated using deep reactive ion etching. The flow through the capillaries is experimentally characterized for varying pressures, temperatures, and diameters. For the parameters used, it is shown that the Knudsen numbe...... is in the intermediate flow regime, and Knudsen's expression for the flow fit the data well. The flow properties of the capillaries make them ideal for introducing gas into vacuum systems and in particular mass spectrometers. ©2005 American Institute of Physics...

  4. Pore-scale Simulations of Capillary Trapping of Supercritical CO2 after Multiple Drainage and Imbibition Cycles

    Science.gov (United States)

    Schaap, M. G.

    2015-12-01

    Carbon capture and storage (CCS) of carbon dioxide emissions generated by production or combustion of fossil fuels is a technologically viable means to reduce the build-up of CO2 in the atmosphere and oceans. On a fundamental level, capillary trapping of scCO2 is a pore-scale process that shares mechanisms that are relevant, for example in oil recovery and remediation of NAPL-contaminated aquifers. Capillary trapping of scCO2 differs rather significantly from trapping of oil recovery and NAPL remediation in that the goal is to maximize the amount of NWP storage, whereas the objective of the other applications is to minimize the amount of residual NWP. This difference makes research into capillary trapping of scCO2 unique, but also complex because scCO2 phase properties (e.g. viscosity, density, and interfacial tension) exhibit large shifts with pressure and temperature which can strongly alter the trapping potential and efficiency. In this presentation we compare direct pore-scale observations of the Brine-CO2 drainage and imbibition process with lattice Boltzmann model simulations. The observations were conducted with the synchrotron-based x-ray microtomography facility at the Advanced Photon Source (APS) at Argonne National Laboratory using a novel x-ray compatible, high-pressure, elevated temperature setup. The "large" volumes (~1200 mm3; 6.3 mm diameter and 40 mm in length) were segmented into solid phase (Bentheimer Sandstone), Brine (KI, 1140 kg/m3) and scCO2. We will present LB simulations of small (64^3 voxels) and large sections of the scanned cores with a simple Shan-Chen-type model and a more advanced Equation of State-type model and compare model results to pressure and CO2 saturation levels that were observed for the CO2 invasion and Brine re-imbibition process. We will present results for the smaller sections under multiple drainage and imbibition cycles to investigate whether this will lead to enhanced trapping of scCO2 as found in earlier research.

  5. METHODOLOGY FOR CALCULATION OF HORIZONTAL WATER PERMEABILITY COEFFICIENT IN SOIL CAPILLARY BORDER

    Directory of Open Access Journals (Sweden)

    E. I. Michnevich

    2011-01-01

    Full Text Available The paper shows that for overall estimation of soil water permeability it is necessary to know a horizontal water permeability value of a soil capillary border in addition to coefficients of filtration and permeability. Relations allowing to determine soil permeability in the area of incomplete saturation, are given in the paper. For a fully developed capillary border some calculation formulae have been obtained in the form of algebraic polynomial versus soil grading (grain composition. These formulae allow to make more accurate calculations while designing and operating  reclamation works.

  6. An Improvement on the Method for Calculating the Capillary Limit of Axial—Grooved Heat Piper

    Institute of Scientific and Technical Information of China (English)

    ChenHanzhuo; MaTongze

    1993-01-01

    A new model has been developed to predict the capillary limit of axial-grooved heat pipe.In the model the concepts of liquid saturation or liquid fraction of the cross-sectional area of groove,the modified relative permeability,absolute permeability of groove and Leverrt's function are used.The Leverrt's function is well represented by the functionf(s)=1(1/√5)(1/2-)0.175.In the model the effects of gravitational force,capillary force and viscous force are considered.The calcuated results are in good agreement with existing experimental data reported in the literature.

  7. Experimental Comparison of Capillary Pinching Discharge in Argon and Nitrogen

    Science.gov (United States)

    Jancarek, A.; Pina, L.; Vrbova, M.; Tamas, M.; Havlikova, R.; Palinek, S.; Vrba, P.; Kolacek, K.; Schmidt, J.; Strauss, J.

    Experiments with CAPEX-U apparatus were done to more understand the differences between Ar and N active media created during the pinch compression, respectively. Capillary discharge current, X-ray narrow band radiation and EUV spectrum temporal behavior were measured. Results of laboratory experiments for both gas fillings under various currents and initial pressures are shown. Computer simulations show that current quasi-period shortening and higher amplitude is needed.

  8. Fast capillary electrophoresis-time-of-flight mass spectrometry using capillaries with inner diameters ranging from 75 to 5 μm.

    Science.gov (United States)

    Grundmann, Marco; Matysik, Frank-Michael

    2011-04-01

    Fast electrophoretic separations in fused silica capillaries (CE) coupled to time-of-flight mass spectrometry (TOF-MS) are presented. CE separations of the model analytes (epinephrine, norepinephrine, dopamine, histidine, and isoproterenol) under conditions of high electric field strengths of up to 1.25 kV cm(-1) are completed in 20 s. Coupling of CE with TOF-MS is accomplished using a coaxial sheath liquid electrospray ionization interface. The influence of parameters inherent to the interface and their effects, including suction pressure and dilution, are discussed. In addition to standard capillaries of 75 and 50 μm inner diameter (ID), separations in capillaries with IDs of 25, 15, and 5 μm have been successfully applied to this setup. The analytical performance is compared over this range of capillary dimensions, and both advantages and disadvantages are discussed.

  9. Conditions necessary for capillary hysteresis in porous media: Tests of grain-size and surface tension influences

    OpenAIRE

    Tokunaga, Tetsu K.; Olson, Keith R.; Wan, Jiamin

    2004-01-01

    Hysteresis in the relation between water saturation and matric potential is generally regarded as a basic aspect of unsaturated porous media. However, the nature of an upper length scale limit for saturation hysteresis has not been previously addressed. Since hysteresis depends on whether or not capillary rise occurs at the grain scale, this criterion was used to predict required combinations of grain size, surface tension, fluid-fluid density differences, and acceleration in monodisper...

  10. Optimal oxygen saturation in premature infants

    Directory of Open Access Journals (Sweden)

    Meayoung Chang

    2011-09-01

    Full Text Available There is a delicate balance between too little and too much supplemental oxygen exposure in premature infants. Since underuse and overuse of supplemental oxygen can harm premature infants, oxygen saturation levels must be monitored and kept at less than 95% to prevent reactive oxygen species-related diseases, such as retinopathy of prematurity and bronchopulmonary dysplasia. At the same time, desaturation below 80 to 85% must be avoided to prevent adverse consequences, such as cerebral palsy. It is still unclear what range of oxygen saturation is appropriate for premature infants; however, until the results of further studies are available, a reasonable target for pulse oxygen saturation (SpO2 is 90 to 93% with an intermittent review of the correlation between SpO2 and the partial pressure of arterial oxygen tension (PaO2. Because optimal oxygenation depends on individuals at the bedside making ongoing adjustments, each unit must define an optimal target range and set alarm limits according to their own equipment or conditions. All staff must be aware of these values and adjust the concentration of supplemental oxygen frequently.

  11. Pharmacologic Atrial Natriuretic Peptide Reduces Human Leg Capillary Filtration

    Science.gov (United States)

    Watenpaugh, Donald E.; Vissing, Susanne F.; Lane, Lynda D.; Buckey, Jay C.; Firth, Brian G.; Erdman, William; Hargens, Alan R.; Blomqvist, C. Gunnar

    1995-01-01

    Atrial natriuretic peptide (ANP) is produced and secreted by atrial cells. We measured calf capillary filtration rate with prolonged venous-occlusion plethys-mography of supine health male subjects during pharmacologic infusion of ANP (48 pmol/kg/min for 15 min; n equals 6) and during placebo infusion (n equals 7). Results during infusions were compared to prior control measurements. ANP infusion increased plasma (ANP) from 30 plus or minus 4 to 2,568 plus or minus 595 pmol/L. Systemic hemoconcentration occurred during ANP infusion; mean hematocrit and plasma colloid osmotic pressure increased 4.6 and 11.3 percent respectively, relative to pre-infusion baseline values (p is less than 0.05). Mean calf filtration, however was significantly reduced from 0.15 to 0.08 ml/100 ml/min with ANP. Heart rate increased 20 percent with ANP infusion, wheras blood pressure was unchanged. Calf conductance (blood flow/arterial pressure) and venous compliance were unaffected by ANP infusion. Placebo infusion had no effect relative to prior baseline control measurements. Although ANP induced systemic capillary filtration, in the calf, filtration was reduced with ANP. Therefore, phamacologic ANP infusion enhances capillary filtration from the systemic circulation, perhaps at upper body or splanchic sites or both, while having the opposite effect in the leg.

  12. Filling of charged cylindrical capillaries

    NARCIS (Netherlands)

    Das, Siddhartha; Chanda, Sourayon; Eijkel, J.C.T.; Tas, N.R.; Chakraborty, Suman; Mitra, Sushanta K.

    2014-01-01

    We provide an analytical model to describe the filling dynamics of horizontal cylindrical capillaries having charged walls. The presence of surface charge leads to two distinct effects: It leads to a retarding electrical force on the liquid column and also causes a reduced viscous drag force because

  13. Capillary thinning of polymeric filaments

    DEFF Research Database (Denmark)

    Kolte, Mette Irene; Szabo, Peter

    1999-01-01

    The capillary thinning of filaments of a Newtonian polybutene fluid and a viscoelastic polyisobutylene solution are analyzed experimentally and by means of numerical simulation. The experimental procedure is as follows. Initially, a liquid sample is placed between two cylindrical plates. Then, th...... and quantified. (C) 1999 The Society of Rheology. [S0148-6055(99)00103-0]....

  14. Hysteresis of the Contact Angle of a Meniscus Inside a Capillary with Smooth, Homogeneous Solid Walls.

    Science.gov (United States)

    Kuchin, Igor V; Starov, Victor M

    2016-05-31

    A theory of contact angle hysteresis of a meniscus inside thin capillaries with smooth, homogeneous solid walls is developed in terms of surface forces (disjoining/conjoining pressure isotherm) using a quasi-equilibrium approach. The disjoining/conjoining pressure isotherm includes electrostatic, intermolecular, and structural components. The values of the static receding θr, advancing θa, and equilibrium θe contact angles in thin capillaries were calculated on the basis of the shape of the disjoining/conjoining pressure isotherm. It was shown that both advancing and receding contact angles depend on the capillary radius. The suggested mechanism of the contact angle hysteresis has a direct experimental confirmation: the process of receding is accompanied by the formation of thick β-films on the capillary walls. The effect of the transition from partial to complete wetting in thin capillaries is predicted and analyzed. This effect takes place in very thin capillaries, when the receding contact angle decreases to zero.

  15. Broadband fast semiconductor saturable absorber.

    Science.gov (United States)

    Jacobovitz-Veselka, G R; Kellerm, U; Asom, T

    1992-12-15

    Kerr lens mode-locked (KLM) solid-state lasers are typically not self-starting. We address this problem by introducing a broadband semiconductor saturable absorber that could be used as a tunable, all-solid-state, passive starting mechanism. We extend the wavelength tunability of a semiconductor saturable absorber to more than 100 nm using a band-gap-engineered low-temperature molecular-beam-epitaxy (MBE)-grown bulk AlGaAs semiconductor saturable absorber in which the absorption edge of the saturable absorber has been artificially broadened by continuously reducing the Al concentration during the MBE growth. We demonstrate its tunability and its feasibility as a starting mechanism for KLM with a picosecond resonant passive mode-locked Ti:sapphire laser. The extension to femtosecond KLM lasers has been discussed previously.

  16. Interstitial capillary changes in lithium nephropathy: effects of antihypertensive treatment.

    Science.gov (United States)

    Skyum, Helle; Marcussen, Niels; Nielsen, Steen Horne; Christensen, Sten

    2004-10-01

    Histopathological changes were investigated in the tubulointerstitium and in the capillaries of male Wistar rats with lithium-induced nephropathy using stereological methods. Two antihypertensive drugs with opposite effects on the renin-angiotensin system, an ACE inhibitor (angiotensin converting enzyme inhibitor) and a thiazide diuretic, modified the nephropathy. Generally, there was a significant positive correlation between the reduction in GFR (glomerular filtration rate) and the reduction in the volume of intact tubular structures and interstitial capillaries. A significant negative correlation was seen between the reduction in GFR and the increase in tubulocapillary distance and the absolute volume of interstitial connective tissue, respectively. Treatment with perindopril, and to some extent hydrochlorothiazide, reversed the rise in systolic blood pressure associated with lithium-induced nephropathy but did not affect the progression to terminal uraemia, the structural renal changes or the mortality. In conclusion, severe tubular and capillary changes are seen in this model of chronic renal failure. Tubular atrophy is associated with a decrease in interstitial capillaries and with an increase in the tubulocapillary distance. Systemic hypertension or activation of the renin-angiotensin system may not be important factors for the progression to terminal renal failure.

  17. Computer modeling of capillary flow with superimposed pulsations

    Science.gov (United States)

    Yaganova, A. E.; Marfin, E. A.

    2016-11-01

    Increasing efficiency of methods of oil production can be achieved by the influence of elastic vibrations. It is a well-known fact that shift viscosity of oil changes under the effect of elastic vibrations. This change depends on properties of the oil and exposure mode. Existing approaches to the research of the way wave exposure impacts on viscosity are based on measuring it after the processing. This article concerns development of methods to measure viscosity of liquid right during its exposure to elastic vibrations. The suggested approach is based on combining numerical and natural experiments. We investigated the pulsating flow of viscid liquid in a capillary numerically in this article. We received allocations of fields of average velocity and pressure in a capillary. It is demonstrated that imposed pulsations in a capillary do not impact on hydrodynamics of the flow. We offered the scheme of an experimental installation for a research of the impact that wave exposure has on the viscosity of liquids. The installation is based on a capillary viscometer.

  18. Law of nonlinear flow in saturated clays and radial consolidation

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    It was derived that micro-scale amount level of average pore radius of clay changed from 0.01 to 0.1 micron by an equivalent concept of flow in porous media. There is good agreement between the derived results and test ones. Results of experiments show that flow in micro-scale pore of saturated clays follows law of nonlinear flow. Theoretical analyses demonstrate that an interaction of solid-liquid interfaces varies inversely with permeability or porous radius. The interaction is an important reason why nonlinear flow in saturated clays occurs. An exact mathematical model was presented for nonlinear flow in micro-scale pore of saturated clays. Dimension and physical meanings of parameters of it are definite. A new law of nonlinear flow in saturated clays was established. It can describe characteristics of flow curve of the whole process of the nonlinear flow from low hydraulic gradient to high one. Darcy law is a special case of the new law. A mathematical model was presented for consolidation of nonlinear flow in radius direction in saturated clays with constant rate based on the new law of nonlinear flow. Equations of average mass conservation and moving boundary, and formula of excess pore pressure distribution and average degree of consolidation for nonlinear flow in saturated clay were derived by using an idea of viscous boundary layer, a method of steady state in stead of transient state and a method of integral of an equation. Laws of excess pore pressure distribution and changes of average degree of consolidation with time were obtained. Results show that velocity of moving boundary decreases because of the nonlinear flow in saturated clay. The results can provide geology engineering and geotechnical engineering of saturated clay with new scientific bases. Calculations of average degree of consolidation of the Darcy flow are a special case of that of the nonlinear flow.

  19. Elastic laboratory measurements and modeling of saturated basalts

    Science.gov (United States)

    Adam, Ludmila; Otheim, Thomas

    2013-03-01

    Understanding the elastic behavior of basalt is important to seismically monitor volcanoes, subsea basalts, and carbon sequestration in basalt. We estimate the elastic properties of basalt samples from the Snake River Plain, Idaho, at ultrasonic (0.8 MHz) and seismic (2-300 Hz) frequencies. To test the sensitivity of seismic waves to the fluid content in the pore structure, measurements are performed at three saturation conditions: saturated with liquid CO2, water, and dry. When CO2 replaces water, the P-wave velocity drops, on average, by 10%. Vesicles and cracks, observed in the rock microstructure, control the relaxation of pore-fluid pressures in the rock as a wave propagates. The bulk and shear moduli of basalts saturated with liquid CO2 are not frequency dependent, suggesting that fluid pore pressures are in equilibrium between 2 Hz and 0.8 MHz. However, when samples are water saturated, the bulk modulus of the rock is frequency dependent. Modeling with Gassmann's equations predicts the measured saturated rock bulk modulus for all fluids for frequencies below 20 Hz but underpredicts the water-saturated basalt bulk modulus for frequencies greater than 20 Hz. The most likely reason is that the pore-fluid pressures are unrelaxed. Instead, the ultrasonic frequency rock moduli are modeled with high-frequency elastic theories of squirt flow and Kuster-Toksöz (KT). Although KT's model is based on idealized pore shapes, a combination of spheres (vesicles) and penny-shaped cracks (fractures) interpreted and quantified from petrographical data predicts the ultrasonic dry and saturated rock moduli for the measured basalts.

  20. The Transverse Energy as a Barometer of a Saturated Plasma

    CERN Document Server

    Dumitru, A; Dumitru, Adrian; Gyulassy, Miklos

    2002-01-01

    The evolution of the gluon plasma produced with saturation initial conditions is calculated via Boltzmann transport theory for nuclear collisions at high energy. The saturation scale increases with the nuclear size and the beam energy, and thus we find that the perturbative rescattering rate decreases relative to the initial longitudinal expansion rate of the plasma. The effective longitudinal pressure remains significantly below the lattice QCD pressure until the plasma cools to near the confinement scale. Therefore, the transverse energy per unit of rapidity and its dependence on beam energy provides a sensitive test of gluon saturation models: the fractional transverse energy loss due to final state interactions is smaller and exhibits a weaker energy dependence than if ideal (nondissipative) hydrodynamics applied throughout the evolution.

  1. Pore scale mechanisms for enhanced vapor transport through partially saturated porous media

    Science.gov (United States)

    Shahraeeni, Ebrahim; Or, Dani

    2012-05-01

    Recent theoretical and experimental studies of vapor transport through porous media question the existence and significance of vapor transport enhancement mechanisms postulated by Philip and de Vries. Several enhancement mechanisms were proposed to rectify shortcomings of continuum models and to reconcile discrepancies between predicted and observed vapor fluxes. The absence of direct experimental and theoretical confirmation of these commonly invoked pore scale mechanisms prompted alternate explanations considering the (often neglected) role of transport via capillary connected pathways. The objective of this work was to quantify the specific roles of liquid bridges and of local thermal and capillary gradients on vapor transport at the pore scale. We considered a mechanistic pore scale model of evaporation and condensation dynamics as a building block for quantifying vapor diffusion through partially saturated porous media. Simulations of vapor diffusion in the presence of isolated liquid phase bridges reveal that the so-called enhanced vapor diffusion under isothermal conditions reflects a reduced gaseous diffusion path length. The presence of a thermal gradient may augment or hinder this effect depending on the direction of thermal relative to capillary gradients. As liquid phase saturation increases, capillary transport becomes significant and pore scale vapor enhancement is limited to low water contents as postulated by Philip and deVries. Calculations show that with assistance of a mild thermal gradient water vapor flux could be doubled relative to diffusion of an inert gas through the same system.

  2. Effects of hydrocarbon physical properties on caprock’s capillary sealing ability

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    A new mechanics formula of caprock’s capillary sealing ability has been established in this paper, in which the boundary layer resistance was considered and characterized by starting pressure gradient. The formula shows that capillary sealing ability of caprock is determined not only by the capillary force of rock and the buoyancy of hydrocarbon column, but also by the starting pressure gradient of hydrocarbons and the thickness of caprock. The buoyancy of hydrocarbon column, the starting pressure gradient of hydrocarbon, and the capillary force of caprock are affected by hydrocarbon density, hydrocarbon viscosity, and hydrocarbon-water interface tension respectively. Based on hydrocarbon property data of reservoirs of Jiyang Depression and equations from literature, the effects of hydrocarbon density, hydrocarbon viscosity, and hydrocarbon-water interface tension on the sealing ability of caprock are analyzed. Under formational conditions, the sealing ability of oil caprock can vary up to dozens times because of the variations of the oil density, oil viscosity, and oil-water interface tension. Thus, the physical characters of hydrocarbon should be considered when evaluating the capillary sealing ability of caprocks. Study of the effects of physical characters on sealing ability of caprock can provide guidance to exploring special physical property hydrocarbon resources, such as viscous oils, and hydrocarbon resources in special pressure-temperature environments.

  3. Cyclic Shearing Deformation Behavior of Saturated Clays

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The apparatus for static and dynamic universal triaxial and torsional shear soil testing is employed to perform stress-controlled cyclic single-direction torsional shear tests and two-direction coupled shear tests under unconsolidated-undrained conditions. Through a series of tests on saturated clay, the effects of initial shear stress and stress reversal on the clay's strain-stress behavior are examined, and the behavior of pore water pressure is studied. The experimental results indicate that the patterns of stress-strain relations are distinctly influenced by the initial shear stress in the cyclic single-direction shear tests. When the initial shear stress is large and no stress reversal occurs, the predominant deformation behavior is characterized by an accumulative effect. When the initial shear stress is zero and symmetrical cyclic stress occurs, the predominant deformation behavior is characterized by a cyclic effect. The pore water pressure fluctuates around the confining pressure with the increase of cycle number. It seems that the fluctuating amplitude increases with the increase of the cyclic stress. But a buildup of pore water pressure does not occur. The deformations of clay samples under the complex initial and the cyclic coupled stress conditions include the normal deviatoric deformation and horizontal shear deformation, the average deformation and cyclic deformation. A general strain failure criterion taking into account these deformations is recommended and is proved more stable and suitable compared to the strain failure criteria currently used.

  4. Central venous oxygen saturation during hypovolaemic shock in humans

    DEFF Research Database (Denmark)

    Madsen, P; Iversen, H; Secher, N H

    1993-01-01

    We compared central venous oxygen saturation and central venous pressure (CVP) as indices of the effective blood volume during 50 degrees head-up tilt (anti-Trendelenburg's position) induced hypovolaemic shock in eight healthy subjects. Head-up tilt increased thoracic electrical impedance from 31...

  5. The experiment on the saturation polarization of Rb vapour

    Institute of Scientific and Technical Information of China (English)

    Huang Xiang-You; You Pei-Lin; Du Wei-Min

    2004-01-01

    @@ A cylindrical capacitor containing rubidium vapour is made. The capacitance of it at. different voltages is measured under a certain Rb vapour pressure. The experimental C-V curve shows that the saturation polarization of Rb vapour is easily observed. The experiment further supports the idea that the Rb atom has a large permanent electric dipole moment.

  6. Passing on the legacy: teaching capillary filtration and developing presentation skills using classic papers.

    Science.gov (United States)

    McGeown, J Graham

    2006-09-01

    Capillary filtration is a key area in the understanding of cardiovascular function and has both physiological and pathophysiological relevance in nearly every organ system. This article describes how classic papers in the Legacy collection of American Physiological Society publications can be used in a teaching symposium exploring the evidence supporting current concepts of capillary fluid exchange. Individual students are given papers to read, edit, and present to the class. The appropriate selection and sequencing of these papers allows the development of important physiological concepts to be tracked. A series of papers concerned with capillary filtration is suggested, and the contribution of each to the developing story is outlined. This approach allows students to develop critical and presentation skills and provides them with a case study of the scientific method as it is applied to physiology as well as establishing an appropriate knowledge base concerning the role of hydrostatic and oncotic forces in capillary fluid exchange. Relevant teaching points are explored further using questions based on a figure from one of the three classic papers used: "Microinjection studies of capillary permeability: II. The relationship between capillary pressure and the rate at which fluid passes through the walls of single capillaries," by E. M. Landis (Am J Physiol 82: 217-238, 1927).

  7. Properties of the microcirculation in capillary bundles of rat spinotrapezius muscle fascia

    Science.gov (United States)

    Jacobitz, Frank; Engebrecht, Cheryn; Metzger, Ian; Porterfield, Colin

    2006-11-01

    Properties of the microcirculation in capillary bundles of rat spinotrapezius muscle fascia are investigated using microscope observations, empirical modeling, and numerical simulations. Capillary bundles consist of a network of feeding arterioles, draining venules, and capillary vessels. A dozen samples of muscle fascia tissue were prepared for microscope observation. The chosen method of preparation allows for the long-term preservation of the tissue samples for future studies. Capillary bundles are photographed under a microscope with 40x magnification. From the images, the microvasculature of the tissue samples is reconstructed. It was found, for example, that the distribution of vessel length in a capillary bundle follows a log-normal law. In addition to a statistical analysis of the vessel data, the network topology is used for numerical simulations of the flow in the capillary bundles. The numerical approach uses a sparse-matrix solver and it considers vessel elasticity and blood rheology. The numerical simulations show, for example, a strong pressure drop across the capillary vessels of the bundle.

  8. NRL capillary Z-pinch experiment

    Energy Technology Data Exchange (ETDEWEB)

    Sethian, J.D.; Gerber, K.A.; Robson, A.E. [Naval Research Lab., Washington, DC (United States); DeSilva, A.W. [Sachs/Freeman Associates, Inc., Landover, MD (United States)]|[Maryland Univ., College Park, MD (United States)

    1984-12-31

    The current renewed interest in the dense linear z-pinch is due in large part to a recent Los Alamos Study which concluded that a z- pinch based reactor could produce 4.4 KJ of fusion energy per pulse for the modest input of 140 kJ per pulse, if a straight pinch could be maintained for 2 {mu}sec. Early attempts to achieve suitable high density z-pinches were of the implosion type which produced hollow pressure profiles that quickly resulted in disruptive m = 0 instabilities. These instabilities are not found in the gas embedded pinch in which an initially small diameter plasma is kept in radial equilibrium by following a prescribed current waveform. Unfortunately, these pinches are prone to a rapid accretion of the surrounding gas during the early stages of formation. Our approach is to form the pinch inside small diameter quartz capillaries filled with neutral hydrogen. This fixes the line density. By driving currents through the pinch at a rate that exceeds that necessary for radial equilibrium, we expect the pinch to contract away from the walls and be subject to compressional, as well as ohmic heating. This contraction will, of course, produce a plasma between the pinch and the capillary wall, but we anticipate this ``corona`` will be kept at a low temperature (i.e., high resistance) by radiation and hence shunt only a small fraction of the pinch current. We also expect negligible impurities in the pinch as the classical mixing time will be much longer than the pinch duration at the densities (10{sup 21}- 10{sup 22} ions/cm{sup 3}) and magnetic fields (1 - 10 MG) involved. However, we do expect the presence of the dense corona to reduce the growth rate of the m = 1 instability. Our results demonstrate that a z-pinch can be formed inside a capillary, but our limited current rise rates and peak current have limited our test abilities. Planned improvements in electrical equipment should yield successful testing results.

  9. Mixed Capillary Venous Retroperitoneal Hemangioma

    Directory of Open Access Journals (Sweden)

    Mohit Godar

    2013-01-01

    Full Text Available We report a case of mixed capillary venous hemangioma of the retroperitoneum in a 61-year-old man. Abdominal ultrasonography showed a mass to be hypoechoic with increased flow in color Doppler imaging. Dynamic contrast-enhanced computed tomography revealed a centripetal filling-in of the mass, located anterior to the left psoas muscle at the level of sacroiliac joint. On the basis of imaging features, preoperative diagnosis of hemangioma was considered and the mass was excised by laparoscopic method. Immunohistochemical studies were strongly positive for CD31 and CD34, and negative for calretinin, EMA, WT1, HMB45, Ki67, synaptophysin, and lymphatic endothelial cell marker D2–40. Histologically, the neoplasm was diagnosed as mixed capillary venous hemangioma.

  10. Statistical analysis of liquid seepage in partially saturated heterogeneous fracture systems

    Energy Technology Data Exchange (ETDEWEB)

    Liou, Tai -Sheng [Univ. of California, Berkeley, CA (United States)

    1999-12-01

    Field evidence suggests that water flow in unsaturated fracture systems may occur along fast preferential flow paths. However, conventional macroscale continuum approaches generally predict the downward migration of water as a spatially uniform wetting front subjected to strong inhibition into the partially saturated rock matrix. One possible cause of this discrepancy may be the spatially random geometry of the fracture surfaces, and hence, the irregular fracture aperture. Therefore, a numerical model was developed in this study to investigate the effects of geometric features of natural rock fractures on liquid seepage and solute transport in 2-D planar fractures under isothermal, partially saturated conditions. The fractures were conceptualized as 2-D heterogeneous porous media that are characterized by their spatially correlated permeability fields. A statistical simulator, which uses a simulated annealing (SA) algorithm, was employed to generate synthetic permeability fields. Hypothesized geometric features that are expected to be relevant for seepage behavior, such as spatially correlated asperity contacts, were considered in the SA algorithm. Most importantly, a new perturbation mechanism for SA was developed in order to consider specifically the spatial correlation near conditioning asperity contacts. Numerical simulations of fluid flow and solute transport were then performed in these synthetic fractures by the flow simulator TOUGH2, assuming that the effects of matrix permeability, gas phase pressure, capillary/permeability hysteresis, and molecular diffusion can be neglected. Results of flow simulation showed that liquid seepage in partially saturated fractures is characterized by localized preferential flow, along with bypassing, funneling, and localized ponding. Seepage pattern is dominated by the fraction of asperity contracts, and their shape, size, and spatial correlation. However, the correlation structure of permeability field is less important

  11. Modelling the effect of pore structure and wetting angles on capillary rise in soils having different wettabilities

    Science.gov (United States)

    Czachor, Henryk

    2006-09-01

    SummaryCapillary rise in axis symmetrical sinusoidal capillary (SC) has been modelled. Analytical formula for meniscus radius, capillary pressure and meniscus rate in SC have been found. Capillary shape described by wall waviness highly influences all of them. The limit between wettability and repellency in such capillary is described by critical value of contact angle θc which is related to the pore geometry by the equation ctg( θc) = πd2, where d2 - pore wall waviness. Kinetics of capillary rise in sinusoidal capillary has been determined by numerical integration of meniscus rate equation for a wide range of pore wall waviness and several values of contact angles. Application of Washburn theory to the data obtained from simulation gives the contact angle value much higher than the true one. In contrast, the obtained pore radius value is usually well correlated with capillary neck. However, in some cases a calculated radius can be even smaller. Above conclusions have been qualitatively confirmed by experiments performed on glass beads and soils. Contact angle measured on flat glass was 27.4°. The calculations concerning the data from capillary rise experiments on 90-1000 μm fraction of glass powder and Washburn theory gave values ca. 80°. The contact angle values for peat soils and loamy sand have close values, which supports the opinion that non-cylindrical shape of soil pores highly influences both the wettability/repellency and the water flux in soils.

  12. Intermediate-Scale Investigation of Capillary and Dissolution Trapping during CO2 Injection and Post-Injection in Heterogeneous Geological Formations

    Science.gov (United States)

    Cihan, A.; Illangasekare, T. H.; Zhou, Q.; Birkholzer, J. T.; Rodriguez, D.

    2010-12-01

    The capillary and dissolution trapping processes are believed to be major trapping mechanisms during CO2 injection and post-injection in heterogeneous subsurface environments. These processes are important at relatively shorter time periods compared to mineralization and have a strong impact on storage capacity and leakage risks, and they are suitable to investigate at reasonable times in the laboratory. The objectives of the research presented is to investigate the effect of the texture transitions and variability in heterogeneous field formations on the effective capillary and dissolution trapping at the field scale through multistage analysis comprising of experimental and modeling studies. A series of controlled experiments in intermediate-scale test tanks are proposed to investigate the key processes involving (1) viscous fingering of free-phase CO2 along high-permeability (or high-K) fast flow pathways, (2) dynamic intrusion of CO2 from high-K zones into low-K zones by capillarity (as well as buoyancy), (3) diffusive transport of dissolved CO2 into low-K zones across large interface areas, and (4) density-driven convective mass transfer into CO2-free regions. The test tanks contain liquid sampling ports to measure spatial and temporal changes in concentration of dissolved fluid as the injected fluid migrates. In addition to visualization and capturing images through digital photography, X-ray and gamma attenuation methods are used to measure phase saturations. Heterogeneous packing configurations are created with tightly packed sands ranging from very fine to medium fine to mimic sedimentary rocks at potential storage formations. Effect of formation type, injection pressure and injection rate on trapped fluid fraction are quantified. Macroscopic variables such as saturation, pressure and concentration that are measured will be used for testing the existing macroscopic models. The applicability of multiphase flow theories will be evaluated by comparing with

  13. Capillary electrophoresis systems and methods

    Science.gov (United States)

    Dorairaj, Rathissh; Keynton, Robert S.; Roussel, Thomas J.; Crain, Mark M.; Jackson, Douglas J.; Walsh, Kevin M.; Naber, John F.; Baldwin, Richard P.; Franco, Danielle B.

    2011-08-02

    An embodiment of the invention is directed to a capillary electrophoresis apparatus comprising a plurality of separation micro-channels. A sample loading channel communicates with each of the plurality of separation channels. A driver circuit comprising a plurality of electrodes is configured to induce an electric field across each of the plurality of separation channels sufficient to cause analytes in the samples to migrate along each of the channels. The system further comprises a plurality of detectors configured to detect the analytes.

  14. Capillary electrophoresis in food authenticity.

    Science.gov (United States)

    Kvasnicka, Frantisek

    2005-06-01

    Food authenticity is a term which simply refers to whether the food purchased by the consumer matches its description. False description can occur in many forms, from the undeclared addition of water or other cheaper materials, or the wrong declaration of the amount of a particular ingredient in the product, to making false statements about the source of ingredients i.e., their geographic, plant, or animal origin. The aim of this review is to summarize applications of capillary electrophoresis in food authentication.

  15. Physics of Fluid Transport in Hybrid Biporous Capillary Wicking Microstructures.

    Science.gov (United States)

    Ravi, Saitej; Dharmarajan, Ramanathan; Moghaddam, Saeed

    2016-08-23

    The mass transport capacity (i.e., the capillary limit,) of homogeneous wicks is limited by the inverse relation between the capillary pressure and permeability. Hybrid wicks with two or more distinct pore sizes have been proposed as alternative geometries to enhance the capillary limit. In this study, the impact of the two hybridization schemes-in-plane and out-of-plane-on the capillary transport of hybrid wicks is studied. Experimental data from in-plane hybrid wicks in conjunction with a theoretical model show that local changes in the curvature of the liquid-vapor meniscus (i.e., pore size) do not result in a higher mass flow rate than that of a comparable homogeneous wick. Instead, a global change in the curvature of the liquid-vapor meniscus (as occurring in out-of-plane hybrid wicks) is necessary for obtaining mass flow rates greater than that of a homogeneous wick. Therefore, the physics of capillary limit and dryout in out-of-plane hybrid wicks is investigated using a hybrid wick consisting of a 1-μm-thick highly porous mesh suspended over a homogeneous array of micropillars. A study of the dryout process within the structure revealed that the presence of the mesh strongly alters the dryout mechanism. Visualization studies showed that out-of-plane hybrid wicks remain operational only as long as the liquid is constrained within the mesh pores; recession of the meniscus just below the mesh results in instantaneous local dryout. To maintain liquid within the mesh structure, the mesh thickness was increased, and it was determined that the mesh thickness plays the key role in the performance of an out-of-plane hybrid wick.

  16. 原状饱和黏土静止土压力系数试验研究%EXPERIMENTAL STUDIES OF STATIC EARTH PRESSURE COEFFICIENT OF UNDISTURBED SATURATED CLAY

    Institute of Scientific and Technical Information of China (English)

    黄博; 胡俊清; 廖先斌; 黄雄

    2013-01-01

    A number of K0-consolidation tests are carried out on the undisturbed mud/silt clay and silty clay samples of Hong Kong-Zhuhai-Macao bridge by using advanced triaxial apparatus. The changes of static soil pressure coefficient K0 under different loading and unloading paths are studied;and the applicability of using common formula and recommended value of specifications to estimate the K0 are analyzed,as well as the prediction equation based on test results is given. The results show that:K0 of mud/silt clay at the bottom of the Hong Kong-Zhuhai-Macao bridge immersed tunnel is a basically constant value(0.47). K0 of silty clay is proportional to the preconsolidation pressure and K0 is between 0.30 and 0.45;both of the bounds are lower than the recommended values of specifications and manuals for similar soil. In addition to soil properties,the cementation of the undisturbed samples also could make the K0 reduce. K0 of the strong structural undisturbed soil would decrease to below the values of normally consolidated clay and then rebound and gradually stabilize during loading stages. We can use the empirical formula given by the predecessors to estimate the K0 of normally consolidated and over-consolidated undisturbed clays;and the internal friction angle should be the effective peak internal friction angle of normally consolidated soil.%利用先进三轴仪进行港珠澳大桥岛隧工程原状土K0固结试验,研究不同加、卸载路径下土体静止土压力系数K0变化,分析常用经验公式及规范推荐值所估计静止土压力系数的适用性,并给出基于本次试验结果的预测公式。结果表明:港珠澳沉管隧道底面处的黏土层 K0基本为一定值,为0.47;粉质黏土层 K0与其先期固结压力成正比,在0.30~0.45范围内,均低于规范和手册对同类土的推荐值;除土性自身的原因外,原状样的胶结作用也会使其K0降低。结构性较强的原状土,在

  17. Capillary Electrophoresis - Optical Detection Systems

    Energy Technology Data Exchange (ETDEWEB)

    Sepaniak, M. J.

    2001-08-06

    Molecular recognition systems are developed via molecular modeling and synthesis to enhance separation performance in capillary electrophoresis and optical detection methods for capillary electrophoresis. The underpinning theme of our work is the rational design and development of molecular recognition systems in chemical separations and analysis. There have been, however, some subtle and exciting shifts in our research paradigm during this period. Specifically, we have moved from mostly separations research to a good balance between separations and spectroscopic detection for separations. This shift is based on our perception that the pressing research challenges and needs in capillary electrophoresis and electrokinetic chromatography relate to the persistent detection and flow rate reproducibility limitations of these techniques (see page 1 of the accompanying Renewal Application for further discussion). In most of our work molecular recognition reagents are employed to provide selectivity and enhance performance. Also, an emerging trend is the use of these reagents with specially-prepared nano-scale materials. Although not part of our DOE BES-supported work, the modeling and synthesis of new receptors has indirectly supported the development of novel microcantilevers-based MEMS for the sensing of vapor and liquid phase analytes. This fortuitous overlap is briefly covered in this report. Several of the more significant publications that have resulted from our work are appended. To facilitate brevity we refer to these publications liberally in this progress report. Reference is also made to very recent work in the Background and Preliminary Studies Section of the Renewal Application.

  18. Capillary stretching of elastic fibers

    Science.gov (United States)

    Protiere, Suzie; Stone, Howard A.; Duprat, Camille

    2014-11-01

    Fibrous media consisting of constrained flexible fibers can be found in many engineered systems (membranes in filters, woven textile, matted paper). When such materials interact with a liquid, the presence of liquid/air interfaces induces capillary forces that deform the fibers. To model this interaction we study the behaviour of a finite volume of liquid deposited on two parallel flexible fibers clamped at both ends. A tension along the fibers is imposed and may be varied. We show that the system undergoes various morphological changes as the interfiber distance, the elasticity and the tension of the fibers are varied. For a certain range of parameters, the liquid spreads along the fibers and pulls them together, leading to the ``zipping'' of the fibers. This capillary adhesion can then be enhanced or reduced by changing the tension within the fibers. We will show that balancing stretching and capillary forces allows the prediction of this transition as well as the conditions for which detachment of the fibers occurs. These results may be used to prevent the clogging of fibrous membranes or to optimize the capture of liquids.

  19. Phase Behaviors of Reservoir Fluids with Capillary Eff ect Using Particle Swarm Optimization

    KAUST Repository

    Ma, Zhiwei

    2013-05-06

    The study of phase behavior is important for the oil and gas industry. Many approaches have been proposed and developed for phase behavior calculation. In this thesis, an alternative method is introduced to study the phase behavior by means of minimization of Helmholtz free energy. For a system at fixed volume, constant temperature and constant number of moles, the Helmholtz free energy reaches minimum at the equilibrium state. Based on this theory, a stochastic method called Particle Swarm Optimization (PSO) algorithm, is implemented to compute the phase diagrams for several pure component and mixture systems. After comparing with experimental and the classical PT-ash calculation, we found the phase diagrams obtained by minimization of the Helmholtz Free Energy approach match the experimental and theoretical diagrams very well. Capillary effect is also considered in this thesis because it has a significant influence on the phase behavior of reservoir fluids. In this part, we focus on computing the phase envelopes, which consists of bubble and dew point lines. Both fixed and calculated capillary pressure from the Young-Laplace equation cases are introduced to study their effects on phase envelopes. We found that the existence of capillary pressure will change the phase envelopes. Positive capillary pressure reduces the dew point and bubble point temperatures under the same pressure condition, while the negative capillary pressure increases the dew point and bubble point temperatures. In addition, the change of contact angle and pore radius will affect the phase envelope. The effect of the pore radius on the phase envelope is insignificant when the radius is very large. These results may become reference for future research and study. Keywords: Phase Behavior; Particle Swarm Optimization; Capillary Pressure; Reservoir Fluids; Phase Equilibrium; Phase Envelope.

  20. Theory of graphene saturable absorption

    CERN Document Server

    Marini, A; de Abajo, F J Garcia

    2016-01-01

    Saturable absorption is a non-perturbative nonlinear optical phenomenon that plays a pivotal role in the generation of ultrafast light pulses. Here we show that this effect emerges in graphene at unprecedentedly low light intensities, thus opening avenues to new nonlinear physics and applications in optical technology. Specifically, we theoretically investigate saturable absorption in extended graphene by developing a non-perturbative single-particle approach, describing conduction-electron dynamics in the atomically-thin material using the two-dimensional Dirac equation for massless Dirac fermions, which is recast in the form of generalized Bloch equations. By solving the electron dynamics non-perturbatively, we account for both interband and intraband contributions to the intensity-dependent saturated conductivity and conclude that the former dominates regardless of the intrinsic doping state of the material. The results are in excellent agreement with atomistic quantum-mechanical simulations including high...

  1. High-Throughput Proteomics Using High Efficiency Multiple-Capillary Liquid Chromatography With On-Line High-Performance ESI FTICR Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Yufeng (BATTELLE (PACIFIC NW LAB)); Tolic, Nikola (BATTELLE (PACIFIC NW LAB)); Zhao, Rui (ASSOC WESTERN UNIVERSITY); Pasa Tolic, Ljiljana (BATTELLE (PACIFIC NW LAB)); Li, Lingjun (Illinois Univ Of-Urbana/Champa); Berger, Scott J.(ASSOC WESTERN UNIVERSITY); Harkewicz, Richard (BATTELLE (PACIFIC NW LAB)); Anderson, Gordon A.(BATTELLE (PACIFIC NW LAB)); Belov, Mikhail E.(BATTELLE (PACIFIC NW LAB)); Smith, Richard D.(BATTELLE (PACIFIC NW LAB))

    2000-12-01

    We report on the design and application of a high-efficiency multiple-capillary liquid chromatography (LC) system for high-throughput proteome analysis. The multiple-capillary LC system was operated at the pressure of 10,000 psi using commercial LC pumps to deliver the mobile phase and newly developed passive feedback valves to switch the mobile phase flow and introduce samples. The multiple-capillary LC system was composed of several serially connected dual-capillary column devices. The dual-capillary column approach was designed to eliminate the time delay for regeneration (or equilibrium) of the capillary column after its use under the mobile phase gradient condition (i.e. one capillary column was used in separation and the other was washed using mobile phase A). The serially connected dual-capillary columns and ESI sources were operated independently, and could be used for either''backup'' operation or with other mass spectrometer(s). This high-efficiency multiple-capillary LC system uses switching valves for all operations and is highly amenable to automation. The separations efficiency of dual-capillary column device, optimal capillary dimensions (column length and packed particle size), suitable mobile phases for electrospray, and the capillary re-generation were investigated. A high magnetic field (11.5 tesla) Fourier transform ion cyclotron resonance (FTICR) mass spectrometer was coupled on-line with this high-efficiency multiple-capillary LC system through an electrospray ionization source. The capillary LC provided a peak capacity of {approx}600, and the 2-D capillary LC-FTICR provided a combined resolving power of > 6 x 10 7 polypeptide isotopic distributions. For yeast cellular tryptic digests, > 100,000 polypeptides were typically detected, and {approx}1,000 proteins can be characterized in a single run.

  2. Progression of Diabetic Capillary Occlusion: A Model.

    Directory of Open Access Journals (Sweden)

    Xiao Fu

    2016-06-01

    Full Text Available An explanatory computational model is developed of the contiguous areas of retinal capillary loss which play a large role in diabetic maculapathy and diabetic retinal neovascularization. Strictly random leukocyte mediated capillary occlusion cannot explain the occurrence of large contiguous areas of retinal ischemia. Therefore occlusion of an individual capillary must increase the probability of occlusion of surrounding capillaries. A retinal perifoveal vascular sector as well as a peripheral retinal capillary network and a deleted hexagonal capillary network are modelled using Compucell3D. The perifoveal modelling produces a pattern of spreading capillary loss with associated macular edema. In the peripheral network, spreading ischemia results from the progressive loss of the ladder capillaries which connect peripheral arterioles and venules. System blood flow was elevated in the macular model before a later reduction in flow in cases with progression of capillary occlusions. Simulations differing only in initial vascular network structures but with identical dynamics for oxygen, growth factors and vascular occlusions, replicate key clinical observations of ischemia and macular edema in the posterior pole and ischemia in the retinal periphery. The simulation results also seem consistent with quantitative data on macular blood flow and qualitative data on venous oxygenation. One computational model applied to distinct capillary networks in different retinal regions yielded results comparable to clinical observations in those regions.

  3. 263~373 K温度区间2-氯-3,3,3-三氟丙烯饱和蒸气压的实验研究%Measurement of Saturated Vapor Pressure of 2-Chloro-3,3,3-Trifluoropropene at 263~373 K

    Institute of Scientific and Technical Information of China (English)

    张伟; 杨志强; 吕婧; 吕剑

    2014-01-01

    Saturated vapor pressures of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) were measured in a temperature range of 263.15~372.90 K by a static method. A total of 97 experimental points were obtained. The temperature and pressure fluctuation were within 2 mK and 1.2 kPa, respectively. The measured saturated vapor pressures and temperature were correlated by Antoine equation lnP=A-B/(T+C), and the constants of the equation were determined as A=15.119, B=3070.575 and C=7.198. The relative deviations between the calculated results from the Antoine equation and the experimental data are less than ±1%. The average molar evaporation heat of HCFO-1233xf was also estimated at 263.15~372.90 K by Clausius-Clapeyron equation which is 24363.31 J⋅mol-1. The normal boiling point is 285.22 K calculated from the Antoine equation.%采用静态法,测定了2-氯-3,3,3-三氟丙烯(HCFO-1233xf)的饱和蒸气压97个数据点,温度263.15~372.90 K,温度不确定度小于±2 mK,压力不确定度小于±1.2 kPa,并用 Antoine 方程 lnP=A-B/(T+C)进行关联,确定了蒸气压方程的三个参数 A、B、C 的值分别为15.119、3070.575和7.198。Antoine方程计算得到的饱和蒸气压与实验数据吻合较好,相对误差均在±1%以内。通过 Clausius-Clapeyron方程计算得到 HCFO-1233xf 在263.15~372.90 K 的平均摩尔蒸发热为24363.31 J⋅mol-1,通过 Antoine 方程计算得到的常压沸点为285.22 K。

  4. Heterogeneous Nucleation Induced by Capillary Wave During Acoustic Levitation

    Institute of Scientific and Technical Information of China (English)

    吕勇军; 解文军; 魏炳波

    2003-01-01

    The rapid solidification of acoustically levitated drops of Pb-61.9 wt. %Sn eutectic alloy is accomplished. A surface morphology of spreading ripples is observed on a sample undercooled by 15 K. The ripples originate from the centre of sample surface, which is also the heterogeneous nucleation site for eutectic growth. The Faraday instability excited by forced surface vibration has brought about these ripples. They are retained in the solidified sample if the sound pressure level exceeds the threshold pressure required for the appearance of capillary waves.Theoretical calculations indicate that both the pressure and displacement maxima exist in the central part of a levitated drop. The pressure near the sample centre can promote heterogeneous nucleation, which is in agreement qualitatively with the experimental results.

  5. High-shear-rate capillary viscometer for inkjet inks

    Energy Technology Data Exchange (ETDEWEB)

    Wang Xi [FUJIFILM Dimatix, Inc., Lebanon, New Hampshire 03766 (United States); Carr, Wallace W.; Bucknall, David G. [School of Polymer, Textile, and Fiber Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Morris, Jeffrey F. [Department of Chemical Engineering and Benjamin Levich Institute for Physico-Chemical Hydrodynamics, City College of New York, New York, New York 10031 (United States)

    2010-06-15

    A capillary viscometer developed to measure the apparent shear viscosity of inkjet inks at high apparent shear rates encountered during inkjet printing is described. By using the Weissenberg-Rabinowitsch equation, true shear viscosity versus true shear rate is obtained. The device is comprised of a constant-flow generator, a static pressure monitoring device, a high precision submillimeter capillary die, and a high stiffness flow path. The system, which is calibrated using standard Newtonian low-viscosity silicone oil, can be easily operated and maintained. Results for measurement of the shear-rate-dependent viscosity of carbon-black pigmented water-based inkjet inks at shear rates up to 2x10{sup 5} s{sup -1} are discussed. The Cross model was found to closely fit the experimental data. Inkjet ink samples with similar low-shear-rate viscosities exhibited significantly different shear viscosities at high shear rates depending on particle loading.

  6. A Simulation of Blood Cells in Branching Capillaries

    CERN Document Server

    Isfahani, Amir H G; Freund, Jonathan B

    2008-01-01

    The multi-cellular hydrodynamic interactions play a critical role in the phenomenology of blood flow in the microcirculation. A fast algorithm has been developed to simulate large numbers of cells modeled as elastic thin membranes. For red blood cells, which are the dominant component in blood, the membrane has strong resistance to surface dilatation but is flexible in bending. Our numerical method solves the boundary integral equations built upon Green's functions for Stokes flow in periodic domains. This fluid dynamics video is an example of the capabilities of this model in handling complex geometries with a multitude of different cells. The capillary branch geometries have been modeled based upon observed capillary networks. The diameter of the branches varies between 10-20 mum. A constant mean pressure gradient drives the flow. For the purpose of this fluid dynamics video, the red blood cells are initiated as biconcave discs and white blood cells and platelets are initiated as spheres and ellipsoids resp...

  7. Anomalous capillary filling and wettability reversal in nanochannels

    CERN Document Server

    Gravelle, Simon; Bocquet, Lydéric; Joly, Laurent

    2016-01-01

    This work revisits capillary filling dynamics in the regime of nanometric to subnanometric channels. Using molecular dynamics simulations of water in carbon nanotubes, we show that for tube radii below one nanometer, both the filling velocity and the Jurin rise vary non-monotonically with the tube radius. Strikingly, with fixed chemical surface properties, this leads to confinement-induced reversal of the tube wettability from hydrophilic to hydrophobic for specific values of the radius. By comparing with a model liquid metal, we show that these effects are not specific to water. Using complementary data from slit channels, we then show that they can be described using the disjoin-ing pressure associated with the liquid structuring in confinement. This breakdown of the standard continuum framework is of main importance in the context of capillary effects in nanoporous media, with potential interests ranging from membrane selectivity to mechanical energy storage.

  8. Solid-phase based on-chip DNA purification through a valve-free stepwise injection of multiple reagents employing centrifugal force combined with a hydrophobic capillary barrier pressure.

    Science.gov (United States)

    Zhang, Hainan; Tran, Hong Hanh; Chung, Bong Hyun; Lee, Nae Yoon

    2013-03-21

    In this paper, we demonstrate a simple technique for sequentially introducing multiple sample liquids into microchannels driven by centrifugal force combined with a hydrophobic barrier pressure and apply the technique for performing solid-phase based on-chip DNA purification. Three microchannels with varying widths, all equipped with independent sample reservoirs at the inlets, were fabricated on a hydrophobic elastomer, poly(dimethylsiloxane) (PDMS). First, glass beads were packed inside the reaction chamber, and a whole cell containing the DNA extract was introduced into the widest channel by applying centrifugal force for physical adsorption of the DNA onto the glass beads. Next, washing and elution solutions were sequentially introduced into the intermediate and narrowest microchannels, respectively, by gradually increasing the amount of centrifugal force. Through a precise manipulation of the centrifugal force, the DNA adsorbed onto the glass beads was successfully washed and eluted in a continuous manner without the need to introduce each solution manually. A stepwise injection of liquids was successfully demonstrated using multiple ink solutions, the results of which corresponded well with the theoretical analyses. As a practical application, the D1S80 locus of human genomic DNA, which is widely used for forensic purposes, was successfully purified using the microdevice introduced in this study, as demonstrated through successful target amplification. This will pave the way for the construction of a control-free valve system for realizing on-chip DNA purification, which is one of the most labor-intensive and hard-to-miniaturize components, on a greatly simplified and miniaturized platform employing hydrophobic PDMS.

  9. Thermal expansion pump for capillary high-performance liquid chromatography.

    Science.gov (United States)

    Tao, Qian; Wu, Qian; Zhang, Xiangmin

    2010-02-01

    A thermal expansion pump (TEP) based on a principle of liquid thermal expansion for capillary high-performance liquid chromatography has been developed. The novel pump is capable of generating a continuous flow at high pressure for constant and stable delivery of binary solvents from nanoliters to microliters per minute without splitting. Theoretical equations for controlling fluidic output of this pump have been established and validated by a series of experiments. Factors affecting flow rate, such as density discrepancy, liquid compressibility, and mass loss in output, were taken into account. An assembly of the pump system employing two groups of thermal expansion pumps (TEPs) working in turns were fabricated, and a controlling strategy for the pump system to maintain a continuous delivery without pressure fluctuation even at switching points was also developed. Both isocratic and gradients of binary solvent delivery by the TEPs were performed. Reproducibility and standard deviation at different flow rates were determined. A capillary high-performance liquid chromatography (micro-HPLC) system consisting of the TEPs, an injection valve, a homemade packed capillary column (20 cm x 100 microm i.d. with 5 microm C18), and a laser-induced fluorescence detector was set up, and sample separations were carried out. Results of RSD = 4% for flow and RSD = 2% for retention times at 500 nL/min were achieved. Such a pump system has almost no moving parts except for the solvent switches. Its overall costs of manufacture and running are very low. It is proven that the TEPs system has great potential and competitive capabilities in capillary liquid chromatography.

  10. Capillary pumped loop body heat exchanger

    Science.gov (United States)

    Swanson, Theodore D. (Inventor); Wren, deceased, Paul (Inventor)

    1998-01-01

    A capillary pumped loop for transferring heat from one body part to another body part, the capillary pumped loop comprising a capillary evaporator for vaporizing a liquid refrigerant by absorbing heat from a warm body part, a condenser for turning a vaporized refrigerant into a liquid by transferring heat from the vaporized liquid to a cool body part, a first tube section connecting an output port of the capillary evaporator to an input of the condenser, and a second tube section connecting an output of the condenser to an input port of the capillary evaporator. A wick may be provided within the condenser. A pump may be provided between the second tube section and the input port of the capillary evaporator. Additionally, an esternal heat source or heat sink may be utilized.

  11. Measurement of Liquid Viscosities in Tapered or Parabolic Capillaries.

    Science.gov (United States)

    Ershov; Zorin; Starov

    1999-08-01

    The possibility of using tapered or parabolic capillaries for measurement of liquid viscosities is investigated both experimentally and theoretically. It is demonstrated that even small deviations in capillary radius from a constant value may substantially affect measurement results. Equations are derived which allow correct analysis of the measurement results in tapered or parabolic capillaries. The following cases are analyzed: a water imbibition into a tapered or parabolic capillary and displacement of one liquid by another immiscible liquid in tapered or parabolic capillaries. Two possibilities are considered: (a) the narrow end of the capillary as capillary inlet and (b) the wide end of the capillary as capillary inlet. Copyright 1999 Academic Press.

  12. On capillary self-focusing in a microfluidic system

    Science.gov (United States)

    Hein, M.; Seemann, R.; Afkhami, S.

    2016-12-01

    A computational framework is developed to address capillary self-focusing in step emulsification. The microfluidic system consists of a single shallow and wide microchannel that merges into a deep reservoir. A continuum approach coupled with a volume of fluid method is used to model the capillary self-focusing effect. The original governing equations are reduced using the Hele-Shaw approximation. We show that the interface between the two fluids takes the shape of a neck narrowing in the flow direction just before entering the reservoir, in agreement with our experimental observations. Our computational model relies on the assumption that the pressure at the boundary, where the fluid exits into the reservoir, is the uniform pressure in the reservoir. We investigate this hypothesis by comparing the numerical results with experimental data. We conjecture that the pressure boundary condition becomes important when the width of the neck is comparable to the depth of the microchannel. A correction to the exit pressure boundary condition is then proposed, which is determined by comparison with experimental data. We also present the experimental observations and the numerical results of the transitions of breakup regimes.

  13. Saturation and High Density QCD

    OpenAIRE

    Mueller, A. H.

    2005-01-01

    Recent progress in understanding general properties of high energy scattering near the unitarity limit, where high density gluon components of the wavefunction are dominant, is reviewed. The similarity of the QCD problem and that of reaction-diffusion processes in statistical physics is emphasized. The energy dependence of the saturation momentum and the status of geometric scaling are discussed.

  14. Thermal fields and saturation discussion in a PEMFC single cell

    Energy Technology Data Exchange (ETDEWEB)

    Ramousse, J. [Quebec Univ., Trois-Rivieres, PQ (Canada). Institut de recherche sur l' hydrogene; Didierjean, S.; Lottin, O.; Maillet, D. [Nancy-Univ., Vandoeuvre (France). Laboratoire d' Energetique et de Mecanique Theorique et Appliquee

    2007-07-01

    Water condensation in a fuel cell can imply drastic cell voltage drops. This is caused by flooding the electrodes or by forming water caps in the feeding channels. For high current densities, water condensation is an important point worth studying. Saturation mechanisms significantly depend on temperature fields through the saturation pressure. Vapour water partial pressure as well as thermal fields have to be known to analyse water condensation preferential sites. In order to get the temperature distribution for any operating condition, using numerical simulations, this paper presented the results of a study on the nature of heat sources and of the thermal properties of each element in the cell including: membrane, gas diffusion layers, and bipolar plates. The study then evaluated water saturation pressure and compared it to vapour water pressure to predict water condensation conditions. Vapour water pressure was obtained from a mass transport model. The paper provided a detailed discussion about heat source quantification and localization. A two-dimensional steady state thermal model that relied on a previous model of charge and mass transfer was then presented. A discussion about water condensation in the cell was also provided. It was concluded that the good thermal conductivity of the bipolar plates improved thermal transfer near the ribs. Temperatures were therefore lower at this location than near the gas channels. 52 refs., 3 tabs., 7 figs.

  15. A New Conductivity Detector for Capillary Electrophoresis

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A new conductivity detector for capillary electrophoresis consisting of an electrochemical cell and a conductive meter was developed. In the cell, the microelectrode and capillary were inserted through the cell wall and fixed by screws and sealing ring, the ends of microelectrode and capillary were located by a guide with two cross holes. LOD for K+ was 1.5×10-5 mol/L.

  16. Fluid trapping during capillary displacement in fractures

    Science.gov (United States)

    Yang, Zhibing; Neuweiler, Insa; Méheust, Yves; Fagerlund, Fritjof; Niemi, Auli

    2016-09-01

    The spatial distribution of fluid phases and the geometry of fluid-fluid interfaces resulting from immiscible displacement in fractures cast decisive influence on a range of macroscopic flow parameters. Most importantly, these are the relative permeabilities of the fluids as well as the macroscopic irreducible saturations. They also influence parameters for component (solute) transport, as it usually occurs through one of the fluid phase only. Here, we present a numerical investigation on the critical role of aperture variation and spatial correlation on fluid trapping and the morphology of fluid phase distributions in a geological fracture. We consider drainage in the capillary dominated regime. The correlation scale, that is, the scale over which the two facing fracture walls are matched, varies among the investigated geometries between L/256 and L (self-affine fields), L being the domain/fracture length. The aperture variability is quantified by the coefficient of variation (δ), ranging among the various geometries from 0.05 to 0.25. We use an invasion percolation based model which has been shown to properly reproduce displacement patterns observed in previous experiments. We present a quantitative analysis of the size distribution of trapped fluid clusters. We show that when the in-plane curvature is considered, the amount of trapped fluid mass first increases with increasing correlation scale Lc and then decreases as Lc further increases from some intermediate scale towards the domain length scale L. The in-plane curvature contributes to smoothening the invasion front and to dampening the entrapment of fluid clusters of a certain size range that depends on the combination of random aperture standard deviation and spatial correlation.

  17. Experimental study and mechanical modelling of the effects of water-driving in an oil saturated chalk. Application to the petroleum industry; Etude experimentale et modelisation mecanique des effets du balayage a l'eau dans une craie saturee d'huile. Application a l'industrie petroliere

    Energy Technology Data Exchange (ETDEWEB)

    Mata, C.

    2001-01-01

    The production of hydrocarbons may sometimes lead to compaction of the oil-reservoir layers with substantial collapse of the soil surface; this mechanism is usually mentioned as Subsidence. Classical remedy to this problem is to sustain the fluid pressure with the help of water injection. However, in presence of high porosity chalk (porosity > 30%), this technique does not give effective results: the subsidence rate at North Sea reservoirs (Ekofisk field), after injection, has remained unchanged. Some justify the subsistence in the chalk as caused by phenomena of dissolution of the carbonates; others think it is connected to the destruction of capillary menisci. In this research, we follow this second approach. This study is finalized to a better understanding of the compaction mechanisms in pure carbonates when water is injected. This is done by proposing -in micro-scale first and in macro-scale after- a physical model that agrees with empirical observations. In order to meet this target, IFP skills and experience in physical and chemical measurements (taken before, after and during mechanical tests) have proficiently joined ENPC laboratory (CERMMO) knowledge of micro and macro modelling. The soft rock studied is a Paris basin's white chalk (Craie de Guerville). Its physical and chemical characterisation (i.e.: silica content, porosity, permeability) is very similar to North Sea chalk, but Guerville chalk has never been in contact with oil and generally it crops out of the ground surface. Strength parameters of this rock have been first determined by standard triaxial tests. Three different saturation configurations have been examined: dry, fully oil-saturated and fully water-saturated. As literature clearly state, dry chalk is stronger than oil saturated chalk and the first two are largely stronger than water saturated chalk. Therefore uniaxial strain water injection tests have been performed on oil saturated samples. Results, coupled with previous physical

  18. Vibrating Liquefaction Experiment and Mechanism Study in Saturated Granular Media

    Institute of Scientific and Technical Information of China (English)

    Li Jianhua; Xu Ming; Ju Haiyan; Zhao Jiangqian; Huang Hongyuan; Sun Yezhi

    2006-01-01

    By the vibrating liquefaction experiment of tailings and fine-ores of iron, it is observed and noted that the change of pore water pressure when the vibrating liquefaction takes place. Based on relevant suppositions, the equation of wave propagation in saturated granular media is obtained. This paper postulates the potential vector equation and the velocity expression of three kinds of body waves under normal conditions.Utilizing the wave theory and the experimental results, the influence of three body waves on pore water pressure and granules has been analyzed in detail. This revealed the rapid increment mechanism of pore water pressure and the wave mechanism of vibrating liquefaction.

  19. Slope wavenumber spectrum models of capillary and capillary-gravity waves

    Institute of Scientific and Technical Information of China (English)

    贾永君; 张杰; 王岩峰

    2010-01-01

    Capillary and capillary-gravity waves possess a random character, and the slope wavenumber spectra of them can be used to represent mean distributions of wave energy with respect to spatial scale of variability. But simple and practical models of the slope wavenumber spectra have not been put forward so far. In this article, we address the accurate definition of the slope wavenumber spectra of water surface capillary and capillary-gravity waves. By combining the existing slope wavenumber models and using th...

  20. A capillary viscometer designed for the characterization of biocompatible ferrofluids

    Energy Technology Data Exchange (ETDEWEB)

    Nowak, J., E-mail: johannes.nowak@tu-dresden.de; Odenbach, S.

    2016-08-01

    Suspensions of magnetic nanoparticles are receiving a growing interest in biomedical research. These ferrofluids can, e.g., be used for the treatment of cancer, making use of the drug targeting principle or using an artificially induced heating. To enable a safe application the basic properties of the ferrofluids have to be well understood, including the viscosity of the fluids if an external magnetic field is applied. It is well known that the viscosity of ferrofluids rises if a magnetic field is applied, where the rise depends on shear rate and magnetic field strength. In case of biocompatible ferrofluids such investigations proved to be rather complicated as the experimental setup should be close to the actual application to allow justified predictions of the effects which have to be expected. Thus a capillary viscometer, providing a flow situation comparable to the flow in a blood vessel, has been designed. The glass capillary is exchangeable and different inner diameters can be used. The range of the shear rates has been adapted to the range found in the human organism. The application of an external magnetic field is enabled with two different coil setups covering the ranges of magnetic field strengths required on the one hand for a theoretical understanding of particle interaction and resulting changes in viscosity and on the other hand for values necessary for a potential biomedical application. The results show that the newly designed capillary viscometer is suitable to measure the magnetoviscous effect in biocompatible ferrofluids and that the results appear to be consistent with data measured with rotational rheometry. In addition, a strong change of the flow behaviour of a biocompatible ferrofluid was proven for ranges of the shear rate and the magnetic field strength expected for a potential biomedical application. - Highlights: • A capillary viscometer to characterize biocompatible ferrofluids is presented. • Shear rates and capillary diameters

  1. LiBr-[BMIM]Cl/H2O工质对的饱和蒸气压、结晶温度和腐蚀性%Saturated vapor pressure, crystallization temperature and corrosivity of LiBr-[BMIM]Cl/H2O working pair

    Institute of Scientific and Technical Information of China (English)

    罗春欢; 张渊; 苏庆泉

    2016-01-01

    In order to solve the problems of crystallization and corrosion for LiBr/H2O, LiBr-[BMIM]Cl/H2O and LiBr-[BMIM]Br/H2O were proposed as new working pairs. The influences of ionic liquids on crystallization temperatures and saturated vapor pressures of LiBr/H2O were investigated. The saturated vapor pressures, crystallization temperatures and corrosivity of LiBr-IL/H2O with a mass ratio of 2.5 were measured and compared with that of LiBr/H2O. The results showed that the saturated vapor pressures of [BMIM]Cl/H2O and [BMIM]Br/H2O were almost the same as that of LiBr/H2O with a 8%—9% lower concentration. In general operation concentration range, the crystallization temperatures of LiBr-[BMIM]Cl/H2O were about 30℃ lower than that of LiBr/H2O with the same absorption ability. Under the same corrosion conditions, the corrosion rate of carbon steel for LiBr-[BMIM]Cl/H2O was obviously smaller than that for LiBr/H2O,and the corrosion rate of copper for LiBr-[BMIM]Cl/H2O was nearly the same as that for LiBr/H2O. As an alternative working pair, LiBr-[BMIM]Cl/H2O has a great potential for absorption heat pump systems.%为了解决LiBr/H2O工质对易结晶和腐蚀性强的问题,提出了LiBr-[BMIM]Cl/H2O和LiBr-[BMIM]Br/H2O新型工质对,研究了离子液体[BMIM]Cl和[BMIM]Br对LiBr/H2O结晶温度和饱和蒸气压的影响。对质量比为2.5的LiBr-IL(ionic liquids)/H2O的饱和蒸气压、结晶温度和腐蚀性进行了测定并与LiBr/H2O的进行了比较,结果表明[BMIM]Cl/H2O和[BMIM]Br/H2O的饱和蒸气压与质量分数低8%~9%的LiBr/H2O的饱和蒸气压基本相同。在常用工作浓度范围内,LiBr-[BMIM]Cl/H2O 的结晶温度比相同吸收能力的LiBr/H2O 的低约30℃。在相同的腐蚀条件下,LiBr-[BMIM]Cl/H2O 对碳钢的腐蚀性明显小于 LiBr/H2O,对紫铜的腐蚀性与 LiBr/H2O 的基本相同。因此,采用LiBr-[BMIM]Cl/H2O作为替代工质对具有一定的应用潜力。

  2. High lung volume increases stress failure in pulmonary capillaries

    Science.gov (United States)

    Fu, Z.; Costello, M. L.; Tsukimoto, K.; Prediletto, R.; Elliott, A. R.; Mathieu-Costello, O.; West, J. B.

    1992-01-01

    We previously showed that when pulmonary capillaries in anesthetized rabbits are exposed to a transmural pressure (Ptm) of approximately 40 mmHg, stress failure of the walls occurs with disruption of the capillary endothelium, alveolar epithelium, or sometimes all layers. The present study was designed to test whether stress failure occurred more frequently at high than at low lung volumes for the same Ptm. Lungs of anesthetized rabbits were inflated to a transpulmonary pressure of 20 cmH2O, perfused with autologous blood at 32.5 or 2.5 cmH2O Ptm, and fixed by intravascular perfusion. Samples were examined by both transmission and scanning electron microscopy. The results were compared with those of a previous study in which the lung was inflated to a transpulmonary pressure of 5 cmH2O. There was a large increase in the frequency of stress failure of the capillary walls at the higher lung volume. For example, at 32.5 cmH2O Ptm, the number of endothelial breaks per millimeter cell lining was 7.1 +/- 2.2 at the high lung volume compared with 0.7 +/- 0.4 at the low lung volume. The corresponding values for epithelium were 8.5 +/- 1.6 and 0.9 +/- 0.6. Both differences were significant (P less than 0.05). At 52.5 cmH2O Ptm, the results for endothelium were 20.7 +/- 7.6 (high volume) and 7.1 +/- 2.1 (low volume), and the corresponding results for epithelium were 32.8 +/- 11.9 and 11.4 +/- 3.7. At 32.5 cmH2O Ptm, the thickness of the blood-gas barrier was greater at the higher lung volume, consistent with the development of more interstitial edema. Ballooning of the epithelium caused by accumulation of edema fluid between the epithelial cell and its basement membrane was seen at 32.5 and 52.5 cmH2O Ptm. At high lung volume, the breaks tended to be narrower and fewer were oriented perpendicular to the axis of the pulmonary capillaries than at low lung volumes. Transmission and scanning electron microscopy measurements agreed well. Our findings provide a physiological

  3. Capillary electrophoresis theory and practice

    CERN Document Server

    Grossman, Paul D

    1992-01-01

    This book is designed to be a practical guide, used by wide audience, including those new to CE, those more experienced, routine users, those interested in technology development, and those involved with applications research. References have been emphasized to allow the reader to explore the detailed specifics and theoretical foundations.This book draws together the rapidly evolving, diverse, and multidisciplinary subject of capillary electrophoresis (CE). It is designed as a practical guide to be used by a wide audience, including those new to CE as well as more experienced users. T

  4. Electromigration dispersion in Capillary Electrophoresis

    CERN Document Server

    Chen, Zhen; 10.1007/s11538-011-9708-7

    2012-01-01

    In a previous paper (S. Ghosal and Z. Chen Bull. Math. Biol. 2010, vol. 72, pg. 2047) it was shown that the evolution of the solute concentration in capillary electrophoresis is described by a nonlinear wave equation that reduced to Burger's equation if the nonlinearity was weak. It was assumed that only strong electrolytes (fully dissociated) were present. In the present paper it is shown that the same governing equation also describes the situation where the electrolytic buffer consists of a single weak acid (or base). A simple approximate formula is derived for the dimensionless peak variance which is shown to agree well with published experimental data.

  5. Computational micro-scale model of control of extravascular water and capillary perfusion in the air blood barrier.

    Science.gov (United States)

    Mazzuca, Enrico; Aliverti, Andrea; Miserocchi, Giuseppe

    2016-07-01

    A computational model of a morphologically-based alveolar capillary unit (ACU) in the rabbit is developed to relate lung fluid balance to mechanical forces between capillary surface and interstitium during development of interstitial edema. We hypothesize that positive values of interstitial liquid pressure Pliq impact on capillary transmural pressure and on blood flow. ACU blood flow, capillary recruitment and filtration are computed by modulating vascular and interstitial pressures. Model results are compared with experimental data of Pliq increasing from ~-10 (control) up to ~4cmH2O in two conditions, hypoxia and collagenase injection. For hypoxia exposure, fitting data requires a linear increase in hydraulic conductivity Lp and capillary pressure PC, that fulfils the need of increase in oxygen delivery. For severe fragmentation of capillary endothelial barrier (collagenase injection), fitting requires a rapid increase in both hydraulic and protein permeability, causing ACU de-recruitment, followed by an increase in PC as a late response to restore blood flow. In conclusion, the model allows to describe the lung adaptive response to edemagenic perturbations; the increase in Pliq, related to the low interstitial compliance, provides an efficient control of extravascular water, by limiting microvascular filtration.

  6. Existence for a global pressure formulation of water-gas flow in porous media

    Directory of Open Access Journals (Sweden)

    Brahim Amaziane

    2012-06-01

    Full Text Available We consider a model of water-gas flow in porous media with an incompressible water phase and a compressible gas phase. Such models appear in gas migration through engineered and geological barriers for a deep repository for radioactive waste. The main feature of this model is the introduction of a new global pressure and it is fully equivalent to the original equations. The system is written in a fractional flow formulation as a degenerate parabolic system with the global pressure and the saturation potential as the main unknowns. The major difficulties related to this model are in the nonlinear degenerate structure of the equations, as well as in the coupling in the system. Under some realistic assumptions on the data, including unbounded capillary pressure function and non-homogeneous boundary conditions, we prove the existence of weak solutions of the system. Furthermore, it is shown that the weak solution has certain desired properties, such as positivity of the saturation. The result is proved with the help of an appropriate regularization and a time discretization of the coupled system. We use suitable test functions to obtain a priori estimates and a compactness result in order to pass to the limit in nonlinear terms.

  7. Sieve plugs in fenestrae of glomerular capillaries--site of the filtration barrier?

    DEFF Research Database (Denmark)

    Rostgaard, Jørgen; Qvortrup, Klaus

    2002-01-01

    The exact location of the filtration barrier of the glomerular capillary wall, which consists of an endothelium, a basement membrane and a visceral epithelium, has not yet been determined. Apparent discrepancies between different investigators in the past could be explained if postmortem...... artifactual tissue changes, due to subnormal blood pressure or anoxia, have taken place in the endothelium before the tissue and tracers have been sufficiently fixed and immobilized by the fixative. To test this supposition, a new method of fixation, which includes a technique to maintain a physiological...... perfusion pressure and a fixative composed of an oxygen-carrying blood substitute fluid containing glutaraldehyde, was employed combined with contrast enhancement. New observations of the glomerular capillary wall revealed that filamentous plugs (about 90 nm in height) filled the capillary fenestrae...

  8. Atomic Force Controlled Capillary Electrophoresis

    Science.gov (United States)

    Lewis, Aaron; Yeshua, Talia; Palchan, Mila; Lovsky, Yulia; Taha, Hesham

    2010-03-01

    Lithography based on scanning probe microscopic techniques has considerable potential for accurate & localized deposition of material on the nanometer scale. Controlled deposition of metallic features with high purity and spatial accuracy is of great interest for circuit edit applications in the semiconductor industry, for plasmonics & nanophotonics and for basic research in surface enhanced Raman scattering & nanobiophysics. Within the context of metal deposition we will review the development of fountain pen nanochemistry and its most recent emulation Atomic Force Controlled Capillary Electrophoresis (ACCE). Using this latter development we will demonstrate achievement of unprecedented control of nanoparticle deposition using a three-electrode geometry. Three electrodes are attached: one on the outside of a metal coated glass probe, one on the inside of a hollow probe in a solution containing Au nanoparticles in the capillary, and a third on the surface where the writing takes place. The three electrodes provide electrical pulses for accurate control of deposition and retraction of the liquid from the surface overcoming the lack of control seen in both dip pen lithography & fountain pen nanochemistry when the tip contacts the surface. With this development, we demonstrate depositing a single 1.3 nm Au nanoparticle onto surfaces such as semiconductors.

  9. Two-dimensional capillary origami

    Energy Technology Data Exchange (ETDEWEB)

    Brubaker, N.D., E-mail: nbrubaker@math.arizona.edu; Lega, J., E-mail: lega@math.arizona.edu

    2016-01-08

    We describe a global approach to the problem of capillary origami that captures all unfolded equilibrium configurations in the two-dimensional setting where the drop is not required to fully wet the flexible plate. We provide bifurcation diagrams showing the level of encapsulation of each equilibrium configuration as a function of the volume of liquid that it contains, as well as plots representing the energy of each equilibrium branch. These diagrams indicate at what volume level the liquid drop ceases to be attached to the endpoints of the plate, which depends on the value of the contact angle. As in the case of pinned contact points, three different parameter regimes are identified, one of which predicts instantaneous encapsulation for small initial volumes of liquid. - Highlights: • Full solution set of the two-dimensional capillary origami problem. • Fluid does not necessarily wet the entire plate. • Global energy approach provides exact differential equations satisfied by minimizers. • Bifurcation diagrams highlight three different regimes. • Conditions for spontaneous encapsulation are identified.

  10. Saturation of the turbulent dynamo.

    Science.gov (United States)

    Schober, J; Schleicher, D R G; Federrath, C; Bovino, S; Klessen, R S

    2015-08-01

    The origin of strong magnetic fields in the Universe can be explained by amplifying weak seed fields via turbulent motions on small spatial scales and subsequently transporting the magnetic energy to larger scales. This process is known as the turbulent dynamo and depends on the properties of turbulence, i.e., on the hydrodynamical Reynolds number and the compressibility of the gas, and on the magnetic diffusivity. While we know the growth rate of the magnetic energy in the linear regime, the saturation level, i.e., the ratio of magnetic energy to turbulent kinetic energy that can be reached, is not known from analytical calculations. In this paper we present a scale-dependent saturation model based on an effective turbulent resistivity which is determined by the turnover time scale of turbulent eddies and the magnetic energy density. The magnetic resistivity increases compared to the Spitzer value and the effective scale on which the magnetic energy spectrum is at its maximum moves to larger spatial scales. This process ends when the peak reaches a characteristic wave number k☆ which is determined by the critical magnetic Reynolds number. The saturation level of the dynamo also depends on the type of turbulence and differs for the limits of large and small magnetic Prandtl numbers Pm. With our model we find saturation levels between 43.8% and 1.3% for Pm≫1 and between 2.43% and 0.135% for Pm≪1, where the higher values refer to incompressible turbulence and the lower ones to highly compressible turbulence.

  11. Experimental methods for the simulation of supercritical CO2 injection at laboratory scale aimed to investigate capillary trapping

    Science.gov (United States)

    Trevisan, L.; Illangasekare, T. H.; Rodriguez, D.; Sakaki, T.; Cihan, A.; Birkholzer, J. T.; Zhou, Q.

    2011-12-01

    Geological storage of carbon dioxide in deep geologic formations is being considered as a technical option to reduce greenhouse gas loading to the atmosphere. The processes associated with the movement and stable trapping are complex in deep naturally heterogeneous formations. Three primary mechanisms contribute to trapping; capillary entrapment due to immobilization of the supercritical fluid CO2 within soil pores, liquid CO2 dissolving in the formation water and mineralization. Natural heterogeneity in the formation is expected to affect all three mechanisms. A research project is in progress with the primary goal to improve our understanding of capillary and dissolution trapping during injection and post-injection process, focusing on formation heterogeneity. It is expected that this improved knowledge will help to develop site characterization methods targeting on obtaining the most critical parameters that capture the heterogeneity to design strategies and schemes to maximize trapping. This research combines experiments at the laboratory scale with multiphase modeling to upscale relevant trapping processes to the field scale. This paper presents the results from a set of experiments that were conducted in an intermediate scale test tanks. Intermediate scale testing provides an attractive alternative to investigate these processes under controlled conditions in the laboratory. Conducting these types of experiments is highly challenging as methods have to be developed to extrapolate the data from experiments that are conducted under ambient laboratory conditions to high temperatures and pressures settings in deep geologic formations. We explored the use of a combination of surrogate fluids that have similar density, viscosity contrasts and analogous solubility and interfacial tension as supercritical CO2-brine in deep formations. The extrapolation approach involves the use of dimensionless numbers such as Capillary number (Ca) and the Bond number (Bo). A set of

  12. Simulation of Partially Saturated - Saturated Flow in the Caspar Creek E-Road Groundwater System

    Science.gov (United States)

    Fisher, J.; Fisher, J.

    2001-12-01

    Over the past decade, the U.S. Forest Service has monitored the subsurface hillslope flow of the E-Road swale. The swale is located in the Caspar Creek watershed near Fort Bragg, California. In hydrologic year 1990 a logging road was built across the middle section of the hillslope followed by a total clearcut of the area during the following year. Development of the logging road has resulted in a large build up of subsurface waters upslope of the road. The increase in pore pressures behind the road is of major concern for slope stability and road failure. A conceptual model is developed to describe the movement of water within the E-Road groundwater system. The two-dimensional SUTRA model is used to describe both saturated and partially saturated flow within the system. SUTRA utilizes a finite element and integrated finite difference method to approximate the governing equation for flow. The model appears to reproduce the uniquely different frequency responses within the E-Road groundwater system. A comparison of simulated and historical piezometric responses demonstrates the model's inability to reproduce historical drainage rates. The low rates of simulated drainage are attributed to the absence of pipeflow within the model. Finally, road consolidation is associated with increased water pressures beneath the road bed.

  13. Flow distributions and spatial correlations in human brain capillary networks

    Science.gov (United States)

    Lorthois, Sylvie; Peyrounette, Myriam; Larue, Anne; Le Borgne, Tanguy

    2015-11-01

    The vascular system of the human brain cortex is composed of a space filling mesh-like capillary network connected upstream and downstream to branched quasi-fractal arterioles and venules. The distribution of blood flow rates in these networks may affect the efficiency of oxygen transfer processes. Here, we investigate the distribution and correlation properties of blood flow velocities from numerical simulations in large 3D human intra-cortical vascular network (10000 segments) obtained from an anatomical database. In each segment, flow is solved from a 1D non-linear model taking account of the complex rheological properties of blood flow in microcirculation to deduce blood pressure, blood flow and red blood cell volume fraction distributions throughout the network. The network structural complexity is found to impart broad and spatially correlated Lagrangian velocity distributions, leading to power law transit time distributions. The origins of this behavior (existence of velocity correlations in capillary networks, influence of the coupling with the feeding arterioles and draining veins, topological disorder, complex blood rheology) are studied by comparison with results obtained in various model capillary networks of controlled disorder. ERC BrainMicroFlow GA615102, ERC ReactiveFronts GA648377.

  14. SATURATED PICRIC ACID PREVENTS AUTOPHAGIA

    Directory of Open Access Journals (Sweden)

    V Rahimi-Movaghar

    2008-08-01

    Full Text Available "nThe dysesthesia and paresthesia that occurs in laboratory rats after spinal cord injury (SCI results in autophagia. This self-destructive behavior interferes with functional assessments in designed studies and jeopardizes the health of the injured rat. In this study, we evaluated role of saturated picric acid in the prevention of autophagia and self-mutilation. All rats were anesthetized with an intraperitoneal injection of a mixture of ketamine (100 mg/kg and xylazine (10 mg/kg for the SCI procedures. In the first 39 rats, no solution applied to the hind limbs, but in the next 26 cases, we smeared the saturated picric acid on the tail, lower extremities, pelvic, and abdomen of the rats immediately after SCI. In the rats without picric acid, 23 rats died following autophagia, but in the 26 rats with picric acid, there was no autophagia (P < 0.001. Picric acid side effects in skin and gastrointestinal signs such as irritation, redness and diarrhea were not seen in any rat. Saturated picric acid is a topical solution that if used appropriately and carefully, might be safe and effectively prevents autophagia and self-mutilation. When the solution is applied to the lower abdomen and limbs, we presume that its bitterness effectively prevents the rat from licking and biting the limb.

  15. Laboratory measurements of seismic attenuation in partially saturated rocks

    Science.gov (United States)

    Chapman, Samuel; Tisato, Nicola; Quintal, Beatriz; Holliger, Klaus

    2014-05-01

    Laboratory measurements of seismic attenuation and transient pore fluid pressure are performed on partially saturated Berea sandstone and synthetic borosilicate samples. Various degrees of water (liquid) and nitrogen (gas) saturation are considered. These measurements are carried out at room temperature and under confining pressures varying from ambient conditions up to 25 MPa. The cylindrical samples are 25 cm long and have a diameter of 7.6 cm. In the context of the experimental setup, the solid frames of both the Berea sandstone and the borosilicate samples can be considered homogenous, which in turn allows for isolating and exploring the effects of partial saturation on seismic attenuation. We employ the sub-resonance method, which is based on the application of a time-harmonic vertical stress to the top of the sample and the measurement of the thus resulting strain. For any given frequency, the attenuation is then inferred as the tangent of the phase shift between the applied stress and the observed strain. Using five equally spaced sensors along the central axis of the cylindrical sample, we measure the transient fluid pressure induced by the application of a step-function-type vertical stress to the top of the sample. Both the sensors and the sample are sealed off with the regard to the confining environment. Together with the numerical results from corresponding compressibility tests based on the quasi-static poroelastic equations, these transient fluid pressure measurements are then used to assist the interpretation of the seismic attenuation measurements.

  16. Sheathless interface for coupling capillary electrophoresis with mass spectrometry

    Science.gov (United States)

    Wang, Chenchen; Tang, Keqi; Smith, Richard D.

    2014-06-17

    A sheathless interface for coupling capillary electrophoresis (CE) with mass spectrometry is disclosed. The sheathless interface includes a separation capillary for performing CE separation and an emitter capillary for electrospray ionization. A portion of the emitter capillary is porous or, alternatively, is coated to form an electrically conductive surface. A section of the emitter capillary is disposed within the separation capillary, forming a joint. A metal tube, containing a conductive liquid, encloses the joint.

  17. Capillary waveguide optrodes for Medical applications

    Science.gov (United States)

    Kieslinger, Dietmar; Weigl, Bernhard H.; Draxler, Sonja; Lippitsch, Max E.

    1997-01-01

    Glass capillaries with a chemically sensitive coating on the inner surface are used as optical sensors for medical diagnostics. The capillary simultaneously serves as a sample compartment, a sensor element, and an inhomogeneous optical waveguide. Different optical setups have been investigated and compared regarding its waveguiding properties.

  18. Modeling capillary forces for large displacements

    NARCIS (Netherlands)

    Mastrangeli, M.; Arutinov, G.; Smits, E.C.P.; Lambert, P.

    2014-01-01

    Originally applied to the accurate, passive positioning of submillimetric devices, recent works proved capillary self-alignment as effective also for larger components and relatively large initial offsets. In this paper, we describe an analytic quasi-static model of 1D capillary restoring forces tha

  19. Capillary electrophoresis using core-based hyperbranched polyethyleneimine (CHPEI) static-coated capillaries.

    Science.gov (United States)

    Boonyakong, Cheerapa; Tucker, Sheryl A

    2009-10-01

    With unique 3-D architecture, the application of core-based hyperbranched polyethyleneimine (CHPEI), as a capillary coating in capillary electrophoresis, is demonstrated by manipulation of the electroosmotic mobility (EOF). CHPEI coatings (CHPEI5, M(w) approximately 5000 and CHPEI25, M(w) approximately 25,000) were physically adsorbed onto the inner surface of bare fused-silica capillary (BFS) via electrostatic interaction of the oppositely charged molecules by rinsing the capillaries with different CHPEI aqueous solutions. The EOF values of the coated capillaries were measured over the pH range of 4.0-9.0. At higher pH (pH >6) the coated capillary surface possesses excess negative charges, which causes the reversal of the EOF. The magnitudes of the EOF obtained from the coated capillaries were three-fold lower than that of BFS capillary. Desirable reproducibility of the EOF with % RSD (n = 5) capillaries were successfully utilized to separate phenolic compounds, B vitamins, as well as basic drugs and related compounds with reasonable analysis time (capillary and capillary).

  20. Visualization experiment to investigate capillary barrier performance in the context of a Yucca Mountain emplacement drift.

    Science.gov (United States)

    Tidwell, Vincent C; Glass, Robert J; Chocas, Connie; Barker, Glenn; Orear, Lee

    2003-01-01

    The use of capillary barriers as engineered backfill systems to divert water away from radioactive waste potentially stored in a Yucca Mountain emplacement drift is investigated. We designed and conducted a flow visualization experiment to investigate capillary barrier performance in this context. A two-dimensional, thin slab, test system replicated the physical emplacement drift to one-quarter scale (1.4-m diameter) and included the simulated drift wall, waste canister, pedestal, capillary barrier backfill, and host-rock fracture system. Water was supplied at the top of the simulated drift and allowed to discharge by way of wicks located along the left wall of the cell (simulated fractures) or by a gravity drain at the bottom of the right side (simulated impermeable rock with floor drain). Photographs captured the migration of water and a blue dye tracer within the system, analytical balances measured the mass balance of water, while tensiometers measured the capillary pressure at numerous locations. Of particular concern to this test was the drainage of the capillary barrier, which terminates against the drift wall. We found that while the simulated fractures (left side) and drain (right side) each influenced the performance of the capillary barrier at early time, they had little differential affect at later times. Also of concern was the small disparity in capillary properties between the fine and coarse layer (limited by the need of a fine-grained material that would not filter into the coarse layer under dry conditions). While the capillary barrier was able to divert the majority of flow toward the edges of the system and away from the simulated waste canister, the barrier did not preclude flow in the coarse layer, which was noted to be visually wet next to the waste canister on day 92 and was continuing to take on water at termination on day 112.

  1. Experimental study on subharmonic and ultraharmonic acoustic waves in water-saturated sandy sediment.

    Science.gov (United States)

    Kim, Byoung-Nam; Lee, Kang Il; Yoon, Suk Wang

    2007-04-01

    Experimental observations of the subharmonic and ultraharmonic acoustic waves in water-saturated sandy sediment are reported in this paper. Acoustic pressures of both nonlinear acoustic waves strongly depend on the driving acoustic pressure at a transducer. The first ultraharmonic wave reaches a saturation value as the driving acoustic pressure increases. The acoustic pressure levels of both nonlinear acoustic waves exhibit some fluctuations in comparison with that of the primary acoustic wave as the receiving distance of hydrophone increases in sediment. The subharmonic and the ultraharmonic phenomena in this study show close resemblance to those produced in bubbly water.

  2. Theoretical Design of adiabatic capillary tube of a domestic refrigerator using refrigerant R-600a.

    Directory of Open Access Journals (Sweden)

    Sahoo. K. C

    2016-08-01

    Full Text Available This paper develops a more accurate theoretical procedure for the design of adiabatic capillary tube of a domestic refrigerator considering a rigorous pressure drop analysis on the refrigerant R-600a while expanding through that tube accompanied with phase change through flash vaporization. Here this eliminates the contradiction of existing concepts on the negative value of the frictional pressure drop after a short distance of expansion due to a large part contribution of the actual pressure drop towards the momentum gain pressure drop. Also this verifies that the momentum gain through phase change is by consumption of internal energy part of the enthalpy and no part of the actual pressure drop energy is used in this respect. So with the concept of nearly total pressure drop being used in overcoming the friction the design of an adiabatic capillary tube of available I mm diameter for 0.1 ton refrigeration capacity has been carried out here. This design procedure causes some increase in the required length of the capillary for a given refrigeration capacity due to the omission of momentum pressure drop concept of different references, but is more accurate with consideration of actual changes involved in the expansion. The procedure is applicable for any other refrigerant of any refrigeration capacity

  3. Analysis of effect of electrolyte types on electrokinetic energy conversion in nanoscale capillaries.

    Science.gov (United States)

    Chein, Reiyu; Tsai, Kunyong; Yeh, Liying

    2010-01-01

    An analytical study on the effect of electrolyte types on the electrokinetic energy conversion is presented using nanoscale cylindrical capillary, which is either positively or negatively charged. The sign of surface charge determines the role and concentration magnitude of ions in the capillary and the energy conversion performance. Our study shows that the electrokinetic energy conversion performance (maximum efficiency, pressure rise and streaming potential) are approximately identical for 1:1 (KCl), 2:1 (CaCl2) and 3:1 (LaCl3) electrolytes when capillary is positively charged. For negatively charged capillary, energy conversion performance degrades significantly with the increase of counter-ion valence. For both positively and negatively charged capillaries, higher maximum efficiency can be resulted in low bulk concentration and surface charge density regimes. However, high maximum pressure rise generation for the pumping is found in the low bulk concentration and high surface charge density regimes. For the electric power generation, higher maximum streaming potential is found when both bulk concentration and surface charge density are low.

  4. Analytical study of Joule heating effects on electrokinetic transportation in capillary electrophoresis.

    Science.gov (United States)

    Xuan, Xiangchun; Li, Dongqing

    2005-02-04

    Electric fields are often used to transport fluids (by electroosmosis) and separate charged samples (by electrophoresis) in microfluidic devices. However, there exists inevitable Joule heating when electric currents are passing through electrolyte solutions. Joule heating not only increases the fluid temperature, but also produces temperature gradients in cross-stream and axial directions. These temperature effects make fluid properties non-uniform, and hence alter the applied electric potential field and the flow field. The mass species transport is also influenced. In this paper we develop an analytical model to study Joule heating effects on the transport of heat, electricity, momentum and mass species in capillary-based electrophoresis. Close-form formulae are derived for the temperature, applied electrical potential, velocity, and pressure fields at steady state, and the transient concentration field as well. Also available are the compact formulae for the electric current and the volume flow rate through the capillary. It is shown that, due to the thermal end effect, sharp temperature drops appear close to capillary ends, where sharp rises of electric field are required to meet the current continuity. In order to satisfy the mass continuity, pressure gradients have to be induced along the capillary. The resultant curved fluid velocity profile and the increase of molecular diffusion both contribute to the dispersion of samples. However, Joule heating effects enhance the sample transport velocity, reducing the analysis time in capillary electrophoretic separations.

  5. Surface Deformation by Thermo-capillary Convection -Sounding Rocket COMPERE Experiment SOURCE

    Science.gov (United States)

    Fuhrmann, Eckart; Dreyer, Michael E.

    The sounding rocket COMPERE experiment SOURCE was successfully flown on MASER 11, launched in Kiruna (ESRANGE), May 15th, 2008. SOURCE has been intended to partly ful-fill the scientific objectives of the European Space Agency (ESA) Microgravity Applications Program (MAP) project AO-2004-111 (Convective boiling and condensation). Three parties of principle investigators have been involved to design the experiment set-up: ZARM for thermo-capillary flows, IMFT (Toulouse, France) for boiling studies, EADS Astrium (Bremen, Ger-many) for depressurization. The scientific aims are to study the effect of wall heat flux on the contact line of the free liquid surface and to obtain a correlation for a convective heat transfer coefficient. The experiment has been conducted along a predefined time line. A preheating sequence at ground was the first operation to achieve a well defined temperature evolution within the test cell and its environment inside the rocket. Nearly one minute after launch, the pressurized test cell was filled with the test liquid HFE-7000 until a certain fill level was reached. Then the free surface could be observed for 120 s without distortion. Afterwards, the first depressurization was started to induce subcooled boiling, the second one to start saturated boiling. The data from the flight consists of video images and temperature measurements in the liquid, the solid, and the gaseous phase. Data analysis provides the surface shape versus time and the corresponding apparent contact angle. Computational analysis provides information for the determination of the heat transfer coefficient in a compensated gravity environment where a flow is caused by the temperature difference between the hot wall and the cold liquid. Correlations for the effective contact angle and the heat transfer coefficient shall be delivered as a function of the relevant dimensionsless parameters. The data will be used for benchmarking of commercial CFD codes and the tank design

  6. Pressure-assisted electrokinetic injection stacking for citalopram drug to achieve highly sensitive detection and enantioseparation by capillary electrophoresis%毛细管电泳-压力辅助电动进样技术对药物西酞普兰的高灵敏检测及手性拆分

    Institute of Scientific and Technical Information of China (English)

    徐中其; 叶峰; 王永乐; 李爱梅

    2015-01-01

    应用压力辅助电动进样( pressure⁃assisted electrokinetic injection, PAEKI)技术开发了毛细管电泳( CE)对阳离子手性药物西酞普兰( citalopram, CIT)拆分的高灵敏度分析方法。在电动进样( electrokinetic injection, EKI)过程中,由于CIT的两个对映异构体与手性选择试剂( sulfated⁃β⁃cyclodextrin, S⁃β⁃CD)之间的动态平衡常数存在差异而导致了电动歧视效应。因此,在EKI过程前向毛细管中充满不含手性选择剂的背景电解质,从而抑制电动进样歧视。通过两个步骤优化PAEKI过程中的关键参数得到电渗流和反向压力之间的平衡条件。在最优的PAEKI条件下(+10 kV,0�2 psi(约1�4 kPa)),两个对映异构体在205 nm紫外检测条件下的检出限( LOD;S/N=3)达到1�1和2�2 ng/mL。灵敏度较常规的压力进样平均提高了62倍,方法的检测灵敏度达到了ng/mL ( ppb),有望成为检测人体体液中CIT对映异构体的有效方法。%Pressure⁃assisted electrokinetic injection ( PAEKI) was applied to the highly sensitive enantiosepara⁃tion of the positively charged drug citalopram ( CIT) by capillary electrophoresis ( CE) . It was found that the in⁃jection discrimination occurred in electrokinetic injection ( EKI) process due to the different dynamic equilibri⁃um constant between chiral selector ( sulfated⁃β⁃cyclodextrin, S⁃β⁃CD) and two isomers of CIT. Herein, it was proposed to use the background electrolyte ( BGE) without chiral selector to fill the capillary, and then start the EKI step to eliminate the injection discrimination of free analytes. The critical parameters in PAEKI could be optimized in two steps to seek the balance between the electroosmotic flow ( EOF ) and the counterbalance pressure. Under the optimized PAEKI conditions (+10 kV, 0�2 psi ( ca. 1�4 kPa) ) , the obtained LODs ( S/N=3) of the two isomers were 1�1

  7. Measuring Viscosities of Gases at Atmospheric Pressure

    Science.gov (United States)

    Singh, Jag J.; Mall, Gerald H.; Hoshang, Chegini

    1987-01-01

    Variant of general capillary method for measuring viscosities of unknown gases based on use of thermal mass-flowmeter section for direct measurement of pressure drops. In technique, flowmeter serves dual role, providing data for determining volume flow rates and serving as well-characterized capillary-tube section for measurement of differential pressures across it. New method simple, sensitive, and adaptable for absolute or relative viscosity measurements of low-pressure gases. Suited for very complex hydrocarbon mixtures where limitations of classical theory and compositional errors make theoretical calculations less reliable.

  8. Thermodynamically coupled mass transport processes in a saturated clay

    Energy Technology Data Exchange (ETDEWEB)

    Carnahan, C.L.

    1984-11-01

    Gradients of temperature, pressure, and fluid composition in saturated clays give rise to coupled transport processes (thermal and chemical osmosis, thermal diffusion, ultrafiltration) in addition to the direct processes (advection and diffusion). One-dimensional transport of water and a solute in a saturated clay subjected to mild gradients of temperature and pressure was simulated numerically. When full coupling was accounted for, volume flux (specific discharge) was controlled by thermal osmosis and chemical osmosis. The two coupled fluxes were oppositely directed, producing a point of stagnation within the clay column. Solute flows were dominated by diffusion, chemical osmosis, and thermal osmosis. Chemical osmosis produced a significant flux of solute directed against the gradient of solute concentration; this effect reduced solute concentrations relative to the case without coupling. Predictions of mass transport in clays at nuclear waste repositories could be significantly in error if coupled transport processes are not accounted for. 14 references, 8 figures, 1 table.

  9. Capillary Discharge XUV Radiation Source

    Directory of Open Access Journals (Sweden)

    M. Nevrkla

    2009-01-01

    Full Text Available A device producing Z-pinching plasma as a source of XUV radiation is described. Here a ceramic capacitor bank pulse-charged up to 100 kV is discharged through a pre-ionized gas-filled ceramic tube 3.2 mm in diameter and 21 cm in length. The discharge current has amplitude of 20 kA and a rise-time of 65 ns. The apparatus will serve as experimental device for studying of capillary discharge plasma, for testing X-ray optics elements and for investigating the interaction of water-window radiation with biological samples. After optimization it will be able to produce 46.9 nm laser radiation with collision pumped Ne-like argon ions active medium. 

  10. Copolymers For Capillary Gel Electrophoresis

    Science.gov (United States)

    Liu, Changsheng; Li, Qingbo

    2005-08-09

    This invention relates to an electrophoresis separation medium having a gel matrix of at least one random, linear copolymer comprising a primary comonomer and at least one secondary comonomer, wherein the comonomers are randomly distributed along the copolymer chain. The primary comonomer is an acrylamide or an acrylamide derivative that provides the primary physical, chemical, and sieving properties of the gel matrix. The at least one secondary comonomer imparts an inherent physical, chemical, or sieving property to the copolymer chain. The primary and secondary comonomers are present in a ratio sufficient to induce desired properties that optimize electrophoresis performance. The invention also relates to a method of separating a mixture of biological molecules using this gel matrix, a method of preparing the novel electrophoresis separation medium, and a capillary tube filled with the electrophoresis separation medium.

  11. Two-dimensional capillary origami

    Science.gov (United States)

    Brubaker, N. D.; Lega, J.

    2016-01-01

    We describe a global approach to the problem of capillary origami that captures all unfolded equilibrium configurations in the two-dimensional setting where the drop is not required to fully wet the flexible plate. We provide bifurcation diagrams showing the level of encapsulation of each equilibrium configuration as a function of the volume of liquid that it contains, as well as plots representing the energy of each equilibrium branch. These diagrams indicate at what volume level the liquid drop ceases to be attached to the endpoints of the plate, which depends on the value of the contact angle. As in the case of pinned contact points, three different parameter regimes are identified, one of which predicts instantaneous encapsulation for small initial volumes of liquid.

  12. Capillary Separation: Micellar Electrokinetic Chromatography

    Science.gov (United States)

    Terabe, Shigeru

    2009-07-01

    Micellar electrokinetic chromatography (MEKC), a separation mode of capillary electrophoresis (CE), has enabled the separation of electrically neutral analytes. MEKC can be performed by adding an ionic micelle to the running solution of CE without modifying the instrument. Its separation principle is based on the differential migration of the ionic micelles and the bulk running buffer under electrophoresis conditions and on the interaction between the analyte and the micelle. Hence, MEKC's separation principle is similar to that of chromatography. MEKC is a useful technique particularly for the separation of small molecules, both neutral and charged, and yields high-efficiency separation in a short time with minimum amounts of sample and reagents. To improve the concentration sensitivity of detection, several on-line sample preconcentration techniques such as sweeping have been developed.

  13. Dynamic effects in multiphase flow: A pore-scale network approach

    NARCIS (Netherlands)

    Gielen, T.; Hassanizadeh, S.M.; Leijnse, A.; Nordhaug, H.F.

    2005-01-01

    Current theories of multiphase flow rely on capillary pressure and saturation relationships that are commonly measured under static conditions. To incorporate transient behaviour, new multiphase flow theories have been proposed. These include an extended capillary pressure-saturation relationship th

  14. Measurement of residual CO2 saturation at a geological storage site using hydraulic tests

    Science.gov (United States)

    Rötting, T. S.; Martinez-Landa, L.; Carrera, J.; Russian, A.; Dentz, M.; Cubillo, B.

    2012-12-01

    Estimating long term capillary trapping of CO2 in aquifers remains a key challenge for CO2 storage. Zhang et al. (2011) proposed a combination of thermal, tracer, and hydraulic experiments to estimate the amount of CO2 trapped in the formation after a CO2 push and pull test. Of these three types of experiments, hydraulic tests are the simplest to perform and possibly the most informative. However, their potential has not yet been fully exploited. Here, a methodology is presented to interpret these tests and analyze which parameters can be estimated. Numerical and analytical solutions are used to simulate a continuous injection in a porous medium where residual CO2 has caused a reduction in hydraulic conductivity and an increase in storativity over a finite thickness (a few meters) skin around the injection well. The model results are interpreted using conventional pressure build-up and diagnostic plots (a plot of the drawdown s and the logarithmic derivative d s / d ln t of the drawdown as a function of time). The methodology is applied using the hydraulic parameters estimated for the Hontomin site (Northern Spain) where a Technology Demonstration Plant (TDP) for geological CO2 storage is planned to be set up. The reduction of hydraulic conductivity causes an increase in observed drawdowns, the increased storativity in the CO2 zone causes a delay in the drawdown curve with respect to the reference curve measured before CO2 injection. The duration (characteristic time) of these effects can be used to estimate the radius of the CO2 zone. The effects of reduced permeability and increased storativity are well separated from wellbore storage and natural formation responses, even if the CO2-brine interface is inclined (i.e. the CO2 forms a cone around the well). We find that both skin hydraulic conductivity and storativity (and thus residual CO2 saturation) can be obtained from the water injection test provided that water flow rate is carefully controlled and head build

  15. Promoter analysis by saturation mutagenesis

    Directory of Open Access Journals (Sweden)

    Baliga Nitin

    2001-01-01

    Full Text Available Gene expression and regulation are mediated by DNA sequences, in most instances, directly upstream to the coding sequences by recruiting transcription factors, regulators, and a RNA polymerase in a spatially defined fashion. Few nucleotides within a promoter make contact with the bound proteins. The minimal set of nucleotides that can recruit a protein factor is called a cis-acting element. This article addresses a powerful mutagenesis strategy that can be employed to define cis-acting elements at a molecular level. Technical details including primer design, saturation mutagenesis, construction of promoter libraries, phenotypic analysis, data analysis, and interpretation are discussed.

  16. Avalanches in dry and saturated disordered media at fracture.

    Science.gov (United States)

    Milanese, Enrico; Yılmaz, Okan; Molinari, Jean-François; Schrefler, Bernhard

    2016-04-01

    This paper analyzes fracturing in inhomogeneous media under dry and fully saturated conditions. We adopt a central force model with continuous damage to study avalanche behavior in a two-dimensional truss lattice undergoing dilation. Multiple fractures can develop at once and a power-law distribution of the avalanche size is observed. The values for the power-law exponent are compared with the ones found in the literature and scale-free behavior is suggested. The fracture evolves intermittently in time because only some avalanches correspond to fracture advancement. A fully saturated model with continuous damage based on the extended Biot's theory is developed and avalanche behavior is studied in the presence of fluid, varying the fluid boundary conditions. We show that power-law behavior is destroyed when the fluid flux governs the problem. Fluid pressure behavior during intermittent crack tip advancement is studied for the continuous-damage fully saturated model. It is found that when mechanical loading prevails, the pressure rises when the crack advances, while when fluid loading prevails, the pressure drops when the crack advances.

  17. Compositional numerical simulation with implicit formulation and gravitational and capillary effects; Simulacao numerica composicional com formulacao implicita e efeitos gravitacional e capilar

    Energy Technology Data Exchange (ETDEWEB)

    Caminha, Romulo de Athayde

    1999-03-01

    This work aims to present an isothermal, one-dimensional, compositional numerical simulator. A two-phase (oil and gas) multicomponent flow is treated implicitly in pressure, saturation and compositions. Flow terms consider gravitational effect, which allows the study of flow in inclined reservoir. The highly non-linear equations, which are necessary to equate the problem, require a numerical solution, which is obtained by the Newton-Raphson method. The one-dimensional treatment given to the problem yields a tridiagonal block Jacobian matrix. It is assumed that the two-phase flow is dominated by convection and that the dispersive effects are neglected. No mobile water is considered in the porous media, and the original gas-oil capillary pressure curve, obtained from the laboratory, is modified to include the variations of interfacial tensions. Instantaneous thermodynamic equilibrium is admitted and it is computed by means of the Peng and Robinson equation of state. The fluids densities are calculated with the equation of state. Gas and oil viscosities are computed using the Lohrenz method. The medium is considered incompressible, homogeneous and isotropic, chemically and physically inert to the fluids. (author)

  18. [A simple preparation method of an electric heating apparatus for heating capillary chromatographic columns and its application in liquid chromatography-mass spectrometry system].

    Science.gov (United States)

    Jin, Zuyao; Lü, Yayao; Zhou, Shanshan; Hao, Feiran; Fu, Bin; Ying, Wantao; Qian, Xiaohong; Zhang, Yangjun

    2015-06-01

    For deep coverage of proteome, especially in performing qualitative identification and quantitative analysis of low-abundance proteins, the most commonly used method is the application of a longer capillary chromatographic column or a capillary column packed with smaller particle sizes. However, this causes another problem, the very high back pressure which results in liquid leaks in some connection parts in a liquid chromatograph. To solve this problem, an electric heating apparatus was developed to raise the temperature of a capillary column for reducing its back pressure, which was further applied in a capillary high performance liquid chromatography-tandem mass spectrometry system (cHPLC-MS/MS), and evaluated in the terms of chromatographic column back pressure and chromatographic column efficiency using bovine serum albumin (BSA) tryptic digests and yeast tryptic digests, separately. The results showed that at the optimum current, our electric heating apparatus could reduce the column pressure of a capillary column packed with 3 µm packing materials by at least 50% during the separation of BSA tryptic digestion and yeast tryptic digestion, compared with that without electric heating. The column efficiency was also increased slightly. This suggested that the electric heating apparatus can significantly reduce the column pressure, which provides an efficient way to use capillary chromatographic columns packed with smaller sizes of particles at a lower pressure.

  19. Using Neutron Radiography to Quantify Water Transport and the Degree of Saturation in Entrained Air Cement Based Mortar

    Science.gov (United States)

    Lucero, Catherine L.; Bentz, Dale P.; Hussey, Daniel S.; Jacobson, David L.; Weiss, W. Jason

    Air entrainment is commonly added to concrete to help in reducing the potential for freeze thaw damage. It is hypothesized that the entrained air voids remain unsaturated or partially saturated long after the smaller pores fill with water. Small gel and capillary pores in the cement matrix fill quickly on exposure to water, but larger pores (entrapped and entrained air voids) require longer times or other methods to achieve saturation. As such, it is important to quantitatively determine the water content and degree of saturation in air entrained cementitious materials. In order to further investigate properties of cement-based mortar, a model based on Beer's Law has been developed to interpret neutron radiographs. This model is a powerful tool for analyzing images acquired from neutron radiography. A mortar with a known volume of aggregate, water to cement ratio and degree of hydration can be imaged and the degree of saturation can be estimated.

  20. Experimental study on nonmonotonicity of capillary desaturation curves in a 2-D pore-network

    Energy Technology Data Exchange (ETDEWEB)

    Rodriquez de Castro, Antonio [Univ. of Manchester (United Kingdom); Shokri, Nima [Univ. of Manchester (United Kingdom); Karadimitriou, Nikolaos [Univ. of Manchester (United Kingdom); Oostrom, Martinus [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Joekar-Niasar, Vahid [Univ. of Manchester (United Kingdom)

    2015-10-28

    Immiscible displacement in a porous medium is important in many applications such as soil remediation and enhanced oil recovery. When gravitational forces are negligible, two-phase immiscible displacement at the pore level is controlled by capillary and viscous forces whose relative importance is quantified through the dimensionless capillary number Ca and the viscosity ratio M between liquid phases. Depending on the values of Ca and M, capillary fingering, viscous fingering, or stable displacement may be observed resulting in a variety of patterns affecting the phase entrapment. The Capillary Desaturation Curve (CDC), which represents the relationship between the residual oils saturation and Ca, is an important relation to describe the phase entrapment at a given Ca. In the present study, we investigate the CDC as influenced by the viscosity ratio. A comprehensive series of experiments using a high-resolution microscope and state-of-the-art micromodels were conducted. The CDCs were calculated and the effects of Ca and M on phase entrapments were quantified. The results show that CDCs are not necessarily monotonic for all M.

  1. Computing oil saturation using capillary pressure data:Case study of well 23 in Suizhong 36-1 oilfield%利用毛管压力资料求原始含油饱和度方法探讨——以绥中36-1油田23井为例

    Institute of Scientific and Technical Information of China (English)

    管耀

    2009-01-01

    以绥中36-1油田23井16块岩心的毛管压力与物性分析资料为基础,总结了利用毛管压力资料求原始含油饱和度的3种方法,并分别对各方法进行了评价.这3种方法分别是Purcell法,含油高度法和J函数直接拟合法.虽然它们都是以J函数为基础求原始含油饱和度的,但Purcell法和J函数直接拟合法考虑了更多的地层条件,而含油高度法偏重于理论计算.通过与密闭取心分析得到的含油饱和度对比,3种方法均可以得到较为满意的解释结果.

  2. CFD simulation and optimization of the capillary throttling of air-flotation unit

    Science.gov (United States)

    Bin, Huang; Yi, Jiajing; Tao, Jiayue; Lu, Rongsheng

    2016-01-01

    With respect to orifice throttling or compensating, capillary throttling has following advantages: smaller mass flow rate and stronger anti-interference ability. This paper firstly gives the required average pressure of air-film when shipping a piece of LCD glass. Then, dimensional flow model of the capillary throttling of air-flotation unit is established. Based on the model, we firstly analyze the flowing process of the lubricated air through the capillary. Secondly, the pressure distribution equation of air-film is derived from the Navier-Stokes Equation. Furthermore, the approximate functional relations between model parameters and static characteristics of the air-film, such as mass flow rate, static bearing capacity, are obtained and then influence of the former on the latter is analyzed . Finally, according to the continuity of air flow, the function relation between model parameters and pressure of core nodes in the air-film is also derived. On foundation of theoretical analysis, the impacts of each model parameter on static characteristics of the air-film flow field, are respectively simulated and analyzed by CFD software Fluent. Based on these simulations and analysis, radius and length of the capillary, density of the gas supply orifices and other model parameters are optimized. Finally, the best unit model is acquired, which greatly improves the static working performance of air-film in air-flotation unit. Research results of this paper can provide guidance and basis for the design and optimization of air-flotation transporting system.

  3. Nanoparticle-based capillary electroseparation of proteins in polymer capillaries under physiological conditions

    DEFF Research Database (Denmark)

    Nilsson, C.; Harwigsson, I.; Becker, K.

    2010-01-01

    Totally porous lipid-based liquid crystalline nanoparticles were used as pseudostationary phase for capillary electroseparation with LIF detection of proteins at physiological conditions using unmodified cyclic olefin copolymer capillaries (Topas (R), 6.7 cm effective length). In the absence of n...... at protein friendly conditions. The developed capillary-based method facilitates future electrochromatography of proteins on polymer-based microchips under physiological conditions and enables the initial optimization of separation conditions in parallel to the chip development....

  4. The use of saturation in qualitative research.

    Science.gov (United States)

    Walker, Janiece L

    2012-01-01

    Understanding qualitative research is an important component of cardiovascular nurses' practice and allows them to understand the experiences, stories, and perceptions of patients with cardiovascular conditions. In understanding qualitative research methods, it is essential that the cardiovascular nurse understands the process of saturation within qualitative methods. Saturation is a tool used for ensuring that adequate and quality data are collected to support the study. Saturation is frequently reported in qualitative research and may be the gold standard. However, the use of saturation within methods has varied. Hence, the purpose of this column is to provide insight for the cardiovascular nurse regarding the use of saturation by reviewing the recommendations for which qualitative research methods it is appropriate to use and how to know when saturation is achieved. In understanding saturation, the cardiovascular nurse can be a better consumer of qualitative research.

  5. Sleep patterns during 30-m nitrox saturation dives and in a confined atmospheric environment.

    Science.gov (United States)

    Nagashima, Hidetoshi; Matsumoto, Kazuya; Seo, Yoojin; Mohri, Motohiko; Naraki, Nobuo; Matsuoka, Shigeaki

    2002-06-01

    Sleep patterns during saturation dives equivalent to a 30-m depth (pressurized condition) and habitation in a confined environment at 1 atm absolute pressure (non-pressurized condition) were studied to determine the effects of environmental pressure. Eight inexperienced divers experienced the pressurized condition of the saturation dives, and nine healthy subjects experienced the non-pressurized condition. Standard polysomnographs were recorded for 262 nights. For both conditions, reductions in total sleep time accompanied by lengthening in sleep latency and reduction in sleep efficiency were observed from the latter part of the experiments through to the recovery periods. These findings suggest that changes were related to psychological and physiological stresses caused by long stays in a confined environment and not by the environmental pressure.

  6. Applicability of chemically modified capillaries in chiral capillary electrophoresis for methamphetamine profiling.

    Science.gov (United States)

    Iwata, Yuko T; Mikuma, Toshiyasu; Kuwayama, Kenji; Tsujikawa, Kenji; Miyaguchi, Hajime; Kanamori, Tatsuyuki; Inoue, Hiroyuki

    2013-03-10

    We examined the applicability of chemically modified capillaries on the chiral capillary electrophoresis of essential compounds for methamphetamine (MA) profiling (MA, amphetamine, ephedrine, pseudoephedrine, norephedrine, and norpseudoephedrine) using highly sulfated γ-cyclodextrin as a chiral selector. Four types of chemically modified capillaries, namely, FunCap-CE/Type D (possessing diol groups), Type A (amino groups), Type C (carboxyl groups), and Type S (sulfate groups), were evaluated. Repeatability, speed, and good chiral resolution sufficient for routine MA profiling were achieved with the Type S capillary.

  7. Cycloaliphatic epoxy resin coating for capillary electrophoresis.

    Science.gov (United States)

    Shah, Roopa S; Wang, Qinggang; Lee, Milton L

    2002-04-05

    Coating the interior surface of a fused-silica capillary with a polymeric material has long been used in capillary electrophoresis (CE) to reduce or eliminate electroosmotic flow and suppress adsorption. A cycloaliphatic epoxide-based resin was bonded to silane treated capillaries and crosslinked with a curing agent. The epoxy resin coating significantly reduced electroosmotic flow over a pH range of 3-10. This coating was sufficiently hydrophilic to suppress protein adsorption. The epoxy resin coated capillary was used to separate several acidic and basic proteins and peptides. Separation efficiencies greater than 400,000 theoretical plates were achieved. The relative standard deviations in migration times for proteins were methods.

  8. Capillary detectors for high resolution tracking

    CERN Document Server

    Annis, P

    1997-01-01

    We present a new tracking device based on glass capillary bundles or layers filled with highly purified liquid scintillator and read out at one end by means of image intensifiers and CCD devices. A large-volume prototype consisting of 5 × 105 capillaries with a diameter of 20 μm and a length of 180 cm and read out by a megapixel CCD has been tested with muon and neutrino beams at CERN. With this prototype a two track resolution of 33 μm was achieved with passing through muons. Images of neutrino interactions in a capillary bundle have also been acquired and analysed. Read-out chains based on Electron Bombarded CCD (EBCCD) and image pipeline devices are also investigated. Preliminary results obtained with a capillary bundle read out by an EBCCD are presented.

  9. CAPILLARY ELECTROPHORETIC BEHAVIOR OF SEVEN SULFONYLUREAS

    Science.gov (United States)

    The electrophoretic behavior of bensulfuron Me, sulfometuron Me, nicosulfuron (Accent), chlorimuron Et, thifensulfuron Me (Harmony), metsulfuron Me, and chlorsulfuron was studied under capillary zone electrophoresis (CZE) and micellar electrokinetic chromatography (MEKC) conditio...

  10. Capillary electrochromatography using fibers as stationary phases.

    Science.gov (United States)

    Jinno, K; Watanabe, H; Saito, Y; Takeichi, T

    2001-10-01

    Fiber-packed capillary columns have been evaluated in chromatographic performance in capillary electrochromatography (CEC). The change of electroosmotic flow (EOF) velocity and selectivity using different kinds of fiber materials was examined. Although the EOF velocity among the different fiber packed columns was almost the same, retention of parabens was larger on the Kevlar-packed column than on the Zylon-packed one, and was larger on the as-span-type fiber-packed column than on the high-modulus-type packed one. Using 200 microm ID x 5 cm Kevlar packed column combined with a 100 microm ID x 20 cm precolumn capillary and a 530 microm ID x 45 cm postcolumn capillary, the separation of three parabens within 30 s was achieved. Other compounds were also separated in a few minutes by the fiber-packed CEC method.

  11. Capillary Optics generate stronger X-rays

    Science.gov (United States)

    1996-01-01

    NASA scientist, in the Space Sciences lab at Marshall, works with capillary optics that generate more intense X-rays than conventional sources. This capability is useful in studying the structure of important proteins.

  12. Contact Angle Effects on Pore and Corner Arc Menisci in Polygonal Capillary Tubes Studied with the Pseudopotential Multiphase Lattice Boltzmann Model

    Directory of Open Access Journals (Sweden)

    Soyoun Son

    2016-02-01

    Full Text Available In porous media, pore geometry and wettability are determinant factors for capillary flow in drainage or imbibition. Pores are often considered as cylindrical tubes in analytical or computational studies. Such simplification prevents the capture of phenomena occurring in pore corners. Considering the corners of pores is crucial to realistically study capillary flow and to accurately estimate liquid distribution, degree of saturation and dynamic liquid behavior in pores and in porous media. In this study, capillary flow in polygonal tubes is studied with the Shan-Chen pseudopotential multiphase lattice Boltzmann model (LBM. The LB model is first validated through a contact angle test and a capillary intrusion test. Then capillary rise in square and triangular tubes is simulated and the pore meniscus height is investigated as a function of contact angle θ. Also, the occurrence of fluid in the tube corners, referred to as corner arc menisci, is studied in terms of curvature versus degree of saturation. In polygonal capillary tubes, the number of sides leads to a critical contact angle θc which is known as a key parameter for the existence of the two configurations. LBM succeeds in simulating the formation of a pore meniscus at θ > θc or the occurrence of corner arc menisci at θ < θc. The curvature of corner arc menisci is known to decrease with increasing saturation and decreasing contact angle as described by the Mayer and Stoewe-Princen (MS-P theory. We obtain simulation results that are in good qualitative and quantitative agreement with the analytical solutions in terms of height of pore meniscus versus contact angle and curvature of corner arc menisci versus saturation degree. LBM is a suitable and promising tool for a better understanding of the complicated phenomena of multiphase flow in porous media.

  13. Holographic Pomeron: Saturation and DIS

    CERN Document Server

    Stoffers, Alexander

    2012-01-01

    We briefly review the approach to dipole-dipole scattering in holographic QCD developed in ARXIV:1202.0831. The Pomeron is modeled by exchanging closed strings between the dipoles and yields Regge behavior for the elastic amplitude. We calculate curvature corrections to this amplitude in both a conformal and confining background, identifying the holographic direction with the virtuality of the dipoles. The it wee-dipole density is related to the string tachyon diffusion in both virtuality and the transverse directions. We give an explicit derivation of the dipole saturation momentum both in the conformal and confining metric. Our holographic result for the dipole-dipole cross section and the it wee-dipole density in the conformal limit are shown to be identical in form to the BFKL pomeron result when the non-critical string transverse dimension is $D_\\perp=3$. The total dipole-dipole cross section is compared to DIS data from HERA.

  14. Molar volume and adsorption isotherm dependence of capillary forces in nanoasperity contacts.

    Science.gov (United States)

    Asay, David B; Kim, Seong H

    2007-11-20

    The magnitude of the capillary force at any given temperature and adsorbate partial pressure depends primarily on four factors: the surface tension of the adsorbate, its liquid molar volume, its isothermal behavior, and the contact geometry. At large contacting radii, the adsorbate surface tension and the contact geometry are dominating. This is the case of surface force apparatus measurements and atomic force microscopy (AFM) experiments with micrometer-size spheres. However, as the size of contacting asperities decreases to the nanoscale as in AFM experiments with sharp tips, the molar volume and isotherm of the adsorbate become very important to capillary formation as well as capillary adhesion. This effect is experimentally and theoretically explored with simple alcohol molecules (ethanol, 1-butanol, and 1-pentanol) which have comparable surface tensions but differing liquid molar volumes. Adsorption isotherms for these alcohols on silicon oxide are also reported.

  15. Manufacturing and microstructural characterization of sintered nickel wicks for capillary pumps

    Directory of Open Access Journals (Sweden)

    Reimbrecht Eduardo Gonçalves

    1999-01-01

    Full Text Available Sintered nickel powder is proposed to be used as porous wicks in heat pipes and capillary pumps. In this work the manufacturing procedure for tubular wicks for capillary pump application is discussed. The porosity, mechanical resistance and roundness of tubular wicks made of carbonila powder, atomized powder and a powder mixture of both are analyzed. A powder mixture was selected as the best raw material. In this case, pore size in the range of 2 to 24 mm and porosity about 50% were measured. First tests carried out in the laboratory, using acetone as the working fluid, show capillary pumping pressures up to 4 kPa and heat fluxes of about 1 W/cm2 in a two-phase heat transfer loop.

  16. Test results of reliable and very high capillary multi-evaporators / condenser loop

    Energy Technology Data Exchange (ETDEWEB)

    Van Oost, S.; Dubois, M.; Bekaert, G. [Societe Anonyme Belge de Construction Aeronautique - SABCA (Belgium)

    1996-12-31

    The paper present the results of various SABCA activities in the field of two-phase heat transport system. These results have been based on a critical review and analysis of the existing two-phase loop and of the future loop needs in space applications. The research and the development of a high capillary wick (capillary pressure up to 38 000 Pa) are described. These activities have led towards the development of a reliable high performance capillary loop concept (HPCPL), which is discussed in details. Several loop configurations mono/multi-evaporators have been ground tested. The presented results of various tests clearly show the viability of this concept for future applications. Proposed flight demonstrations as well as potential applications conclude this paper. (authors) 7 refs.

  17. Unusual intraosseous capillary hemangioma of the mandible.

    Science.gov (United States)

    Dereci, Omur; Acikalin, Mustafa Fuat; Ay, Sinan

    2015-01-01

    Intraosseous hemangioma is a benign vascular neoplasm, which is mostly seen in vertebrae, maxillofacial bones, and long bones. Intraosseous hemangioma is rarely seen on jaw bones compared to other skeletal bones and usually occurs in the cavernous form. Capillary intraosseous hemangioma of jaws is an uncommon form of intraosseous hemangioma and has not been thoroughly described so far. In this study, a case of capillary intraosseous hemangioma of the mandible was presented with relevant literature review.

  18. Unusual intraosseous capillary hemangioma of the mandible

    OpenAIRE

    Dereci, Omur; Acikalin, Mustafa Fuat; Ay, Sinan

    2015-01-01

    Intraosseous hemangioma is a benign vascular neoplasm, which is mostly seen in vertebrae, maxillofacial bones, and long bones. Intraosseous hemangioma is rarely seen on jaw bones compared to other skeletal bones and usually occurs in the cavernous form. Capillary intraosseous hemangioma of jaws is an uncommon form of intraosseous hemangioma and has not been thoroughly described so far. In this study, a case of capillary intraosseous hemangioma of the mandible was presented with relevant liter...

  19. Elasto-capillary collapse of floating structures - Non-linear response of elastic structures under capillary forces

    CERN Document Server

    Adami, N; Roman, B; Bico, J; Caps, H

    2013-01-01

    Flexible rings and rectangle structures floating at the surface of water are prone to deflect under the action of surface pressure induced by the addition of surfactant molecules on the bath. While the frames of rectangles bend inward or outward for any surface pressure difference, circles are only deformed by compression beyond a critical buckling load. However, compressed frames also undergo a secondary buckling instability leading to a rhoboidal shape. Following the pioneering works of \\cite{Hu} and \\cite{Zell}, we describe both experimentally and theoretically the different elasto-capillary deflection and buckling modes as a function of the material parameters. In particular we show how this original fluid structure interaction may be used to probe the adsorption of surfactant molecules at liquid interfaces.

  20. Bundled capillary electrophoresis using microstructured fibres.

    Science.gov (United States)

    Rogers, Benjamin; Gibson, Graham T T; Oleschuk, Richard D

    2011-01-01

    Joule heating, arising from the electric current passing through the capillary, causes many undesired effects in CE that ultimately result in band broadening. The use of narrow-bore capillaries helps to solve this problem as smaller cross-sectional area results in decreased Joule heating and the rate of heat dissipation is increased by the larger surface-to-volume ratio. Issues arising from such small capillaries, such as poor detection sensitivity, low loading capacity and high flow-induced backpressure (complicating capillary loading) can be avoided by using a bundle of small capillaries operating simultaneously that share buffer reservoirs. Microstructured fibres, originally designed as waveguides in the telecommunication industry, are essentially a bundle of parallel ∼5 μm id channels that extend the length of a fibre having otherwise similar dimensions to conventional CE capillaries. This work presents the use of microstructured fibres for CZE, taking advantage of their relatively high surface-to-volume ratio and the small individual size of each channel to effect highly efficient separations, particularly for dye-labelled peptides.

  1. Ion guiding in curved glass capillaries

    Energy Technology Data Exchange (ETDEWEB)

    Kojima, Takao M. [Atomic Physics Laboratory, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Ikeda, Tokihiro [Nishina Center for Accelerator-Based Science, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Kanai, Yasuyuki; Yamazaki, Yasunori [Atomic Physics Laboratory, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan)

    2015-07-01

    Straight and curved glass capillaries were tested for the guiding of 8 keV Ar{sup 8+} ion beams. The straight capillary was about 50 mm long and 0.87 mm/1.1 mm in inner/outer diameter. One of the two curved capillaries was similar, but was curved with a 270 mm radius. The other was 53 mm long, had diameters of 2.34 mm/2.99 mm, and was curved with a 150 mm radius. The corresponding bending angles of the two curved capillaries were 9.6° and 17.5°, respectively. Transmission through the straight capillary disappeared when the tilt angle was larger than 5°. The curved capillaries guided the ion beams into their corresponding bending angles, which were much larger than 5°, with transmission efficiencies of a few tens percent. This demonstrates the possibility of developing a new scheme of simple small beam deflectors and related beam optics.

  2. Cell adhesion during bullet motion in capillaries.

    Science.gov (United States)

    Takeishi, Naoki; Imai, Yohsuke; Ishida, Shunichi; Omori, Toshihiro; Kamm, Roger D; Ishikawa, Takuji

    2016-08-01

    A numerical analysis is presented of cell adhesion in capillaries whose diameter is comparable to or smaller than that of the cell. In contrast to a large number of previous efforts on leukocyte and tumor cell rolling, much is still unknown about cell motion in capillaries. The solid and fluid mechanics of a cell in flow was coupled with a slip bond model of ligand-receptor interactions. When the size of a capillary was reduced, the cell always transitioned to "bullet-like" motion, with a consequent decrease in the velocity of the cell. A state diagram was obtained for various values of capillary diameter and receptor density. We found that bullet motion enables firm adhesion of a cell to the capillary wall even for a weak ligand-receptor binding. We also quantified effects of various parameters, including the dissociation rate constant, the spring constant, and the reactive compliance on the characteristics of cell motion. Our results suggest that even under the interaction between P-selectin glycoprotein ligand-1 (PSGL-1) and P-selectin, which is mainly responsible for leukocyte rolling, a cell is able to show firm adhesion in a small capillary. These findings may help in understanding such phenomena as leukocyte plugging and cancer metastasis.

  3. Variables of state and charateristics for isentropic discharge phenomena of water, starting with saturation

    Energy Technology Data Exchange (ETDEWEB)

    Baudisch, H.

    1968-03-15

    The tables presented in this report contain the thermodynamic values of isentropic change of state for water in the two-phase region starting from the saturation line down to 0.01 at. The variables have been computed in the pressure range from 5-100 at. in equal pressure intervals of 5 at. and in the range from 100-170 at. in intervals of 10 at. Assuming a one-dimensional flow and a known saturation pressure, the dimensions of a discharge nozzle may be determined by interpolation of the calculated values for an isentropic discharge. 4 figs., 29 tabs., 23 refs.

  4. Development of hydrophobic clay–alumina based capillary membrane for desalination of brine by membrane distillation

    Directory of Open Access Journals (Sweden)

    Rakhi Das

    2016-09-01

    Full Text Available Clay–alumina compositions of 0, 20, 40 and 55 weight percent (wt% clay and rest alumina were maintained in porous support preparation by extrusion followed by sintering at 1300 °C for 2.5 h to obtain 3 mm/2 mm (outer diameter/inner diameter capillary. 1H,1H,2H,2H-perfluorodecyltriethoxysilane (97% (C8 was used to modify the capillary surface of all compositions without any intermediate membrane layer to impart hydrophobic characteristics and compared in terms of contact angle produced by the capillaries with water and liquid entry pressure (LEPw. FTIR analysis showed that the hydrophilic surface of the capillary membranes was efficiently modified by the proposed grafting method. Capillary with 55 wt% clay produced a pore size of 1.43 micron and was considered as an ideal candidate for grafting with C8 polymer to impart surface hydrophobicity. The contact angle and LEPw value obtained for this modified membrane (C-55-M were 145° and 1 bar, respectively. The modified capillary membrane was applied for desalination of brine by air gap membrane distillation (AGMD at a feed pressure of 0.85 bar. Maximum flux obtained for C-55-M membrane was 98.66 L/m2 day at a temperature difference of 60 °C with salt rejection of 99.96%. Mass transfer coefficient of C-55-M was 16 × 10−3 mm/s at feed temperature of 70 °C.

  5. Capillary SFC-APCI-MS characterization of PACs obtained by the fractionation of a contaminated pond sediment

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, D.; Sim, P.G.; Crain, S.M. [National Research Council, Halifax (Canada); Benoit, F.M. [Health Canada, Ottawa, Ontario (Canada)

    1994-12-31

    Capillary supercritical fluid chromotography can be directly coupled to a mass spectrometer by utilizing interfaces based on the direct fluid interface. In these, the capillary restrictor passes through a probe, at the end of which is positioned a heating element used to directly heat the end of the capillary restrictor to prevent solute precipitation and freezing of the mobile phase in the restrictor during decompression. Such SFC interfaces, which pass directly into the source of the MS, suffer from sensitivity problems, especially in the electron impact mode. Many of the problem associated with SFC-MS could effectively be removed if the ionization of the compounds were to occur at atmospheric pressure. Capillary SFC was combined with APCI-MS via heated pneumatic nebulizer interfaces modified for use with SFC, and applied to analyze a complex mixture of polycyclic aromatic compounds obtained by the fractionation of a contaminated pond sediment.

  6. Increased capillary permeability for plasma proteins in oral contraceptive users.

    Science.gov (United States)

    Tollan, A; Kvenild, K; Strand, H; Oian, P; Maltau, J M

    1992-05-01

    The transcapillary fluid balance was examined in eleven women before administration of a monophasic oral contraceptive (desogestrel 0.15 mg, ethinylestradiol 0.03 mg), and after three and six months of use. The interstitial colloid osmotic pressure was measured by the "wick" method, and the interstitial hydrostatic pressure by the "wick-in-needle" method in subcutaneous tissue on thorax and leg. During the six-month observation period, the following changes were observed: Plasma colloid osmotic pressure decreased (mean 1.8 mmHg, p = 0.047), as well as serum albumin (mean 5.1 g/l, p = 0.0006), total protein concentration (mean 2.8 g/l, p = 0.0006), hemoglobin (mean 0.5 g/dl, p = 0.014) and hematocrit (mean 1.8%, p = 0.047). Blood pressure and body weight remained unchanged, but foot volume showed a significant increase. The colloid osmotic pressure gradient (plasma-interstitium) was significantly reduced. The results indicate an increase in plasma volume in addition to an increased capillary permeability to plasma proteins during oral contraceptive use. We suggest that the observed changes in transcapillary fluid balance is caused by the estrogen component of the oral contraceptive pill.

  7. Crossover from shear-driven to thermally activated drainage of liquid-infused microscale capillaries

    Science.gov (United States)

    Colosqui, Carlos E.; Wexler, Jason S.; Liu, Ying; Stone, Howard A.

    2016-10-01

    The shear-driven drainage of capillary grooves filled with viscous liquid is a dynamic wetting phenomenon relevant to numerous industrial processes and lubricant-infused surfaces for drag reduction and antifouling. Prior work has reported that a finite length L∞ of the capillary groove can remain indefinitely filled with liquid even when large shear stresses are applied. The mechanism preventing full drainage is attributed to a balance between the shear-driven flow and a counterflow driven by capillary pressures caused by deformation of the free surface. In this work, we examine closely the approach to the final equilibrium length L∞ and report a crossover to a slow drainage regime that cannot be described by conventional dynamic models considering solely hydrodynamic and capillary forces. The slow drainage regime observed in experiments can be instead modeled by a kinetic equation describing a sequence of random thermally activated transitions between multiple metastable states caused by surface defects with nanoscale dimensions. Our findings provide insights on the critical role that natural or engineered surface roughness with nanoscale dimensions can play in the imbibition and drainage of capillaries and other dynamic wetting processes in microscale systems.

  8. Study of the electroosmotic flow as a means to propel the mobile phase in capillary electrochromatography in view of further miniaturization of capillary electrochromatography systems.

    Science.gov (United States)

    Szekely, Laszlo; Freitag, Ruth

    2005-05-01

    In this paper, we investigate the phenomenon of electroosmosis as a means to propel a mobile phase, in particular in view of an application in microfluidic systems, which are characterized by significantly smaller volumes of the reservoirs and the separation channels compared to conventional instrumentation. In the microfluidic chip, pH changes due to water electrolysis quickly showed an effect on the electroosmotic flow (EOF), which could be counteracted by either regularly exchanging or buffering the mobile phase. Surface treatment was of no effect in regard to EOF stabilization in empty channels but may have an influence in channels filled with a charged monolith. In fused-silica capillaries the EOF was generally found to decrease from 'naked' to surface-treated to monolith-filled capillaries. The EOF tended to be higher when an organic solvent (acetonitrile) was added to the mobile phase and could be further increased by substituting the water with equal amounts of methanol. In addition, the hydrostatic pressure exerted by the EOF was investigated. In a microfluidic chip with empty (cross-)channels such an effect could be responsible for a redirection of the flow. In capillaries partially filled with a noncharged (non-EOF-generating) monolith, a linear relationship could be established between the EOF created in the empty section of the capillary (apparent mobility) and the length of the monolith (backpressure). In capillaries partially filled with a charged (EOF-producing) monolith, flow inhomogeneities must be expected as a consequence of a superimposition of hydrodynamic pressure and EOF as mobile phase driving force.

  9. Improving prediction of hydraulic conductivity by constraining capillary bundle models to a maximum pore size

    Science.gov (United States)

    Iden, Sascha C.; Peters, Andre; Durner, Wolfgang

    2015-11-01

    The prediction of unsaturated hydraulic conductivity from the soil water retention curve by pore-bundle models is a cost-effective and widely applied technique. One problem for conductivity predictions from retention functions with continuous derivatives, i.e. continuous water capacity functions, is that the hydraulic conductivity curve exhibits a sharp drop close to water saturation if the pore-size distribution is wide. So far this artifact has been ignored or removed by introducing an explicit air-entry value into the capillary saturation function. However, this correction leads to a retention function which is not continuously differentiable. We present a new parameterization of the hydraulic properties which uses the original saturation function (e.g. of van Genuchten) and introduces a maximum pore radius only in the pore-bundle model. In contrast to models using an explicit air entry, the resulting conductivity function is smooth and increases monotonically close to saturation. The model concept can easily be applied to any combination of retention curve and pore-bundle model. We derive closed-form expressions for the unimodal and multimodal van Genuchten-Mualem models and apply the model concept to curve fitting and inverse modeling of a transient outflow experiment. Since the new model retains the smoothness and continuous differentiability of the retention model and eliminates the sharp drop in conductivity close to saturation, the resulting hydraulic functions are physically more reasonable and ideal for numerical simulations with the Richards equation or multiphase flow models.

  10. Viscous Coalescence of Two Drops in a Saturated Vapor Phase

    Science.gov (United States)

    Baroudi, Lina; Nagel, Sidney R.; Morris, Jeffrey F.; Lee, Taehun

    2016-11-01

    When two liquid drops come into contact, a microscopic liquid bridge forms between them and rapidly expands until the two drops merge into a single bigger drop. Numerous studies have been devoted to the investigation of the coalescence singularity in the case where the drops coalesce in a medium of negligible vapor pressure such as vacuum or air. However, coalescence of liquid drops may also take place in a medium of relatively high vapor pressure (condensable vapor phase), where the effect of the surrounding vapor phase should not be neglected, such as the merging of drops in clouds. In this study, we carry out Lattice Boltzmann numerical simulations to investigate the dynamics of viscous coalescence in a saturated vapor phase. Attention is paid to the effect of the vapor phase on the formation and growth dynamics of the liquid bridge in the viscous regime. We observe that the onset of the coalescence occurs earlier and the expansion of the bridge initially proceeds faster when the coalescence takes place in a saturated vapor compared to the coalescence in a non-condensable gas. The initially faster evolution of the coalescence process in the saturated vapor is caused by the vapor transport through condensation during the early stages of the coalescence.

  11. Power flow control using distributed saturable reactors

    Energy Technology Data Exchange (ETDEWEB)

    Dimitrovski, Aleksandar D.

    2016-02-13

    A magnetic amplifier includes a saturable core having a plurality of legs. Control windings wound around separate legs are spaced apart from each other and connected in series in an anti-symmetric relation. The control windings are configured in such a way that a biasing magnetic flux arising from a control current flowing through one of the plurality of control windings is substantially equal to the biasing magnetic flux flowing into a second of the plurality of control windings. The flow of the control current through each of the plurality of control windings changes the reactance of the saturable core reactor by driving those portions of the saturable core that convey the biasing magnetic flux in the saturable core into saturation. The phasing of the control winding limits a voltage induced in the plurality of control windings caused by a magnetic flux passing around a portion of the saturable core.

  12. Capillary electrophoresis in a fused-silica capillary with surface roughness gradient.

    Science.gov (United States)

    Horká, Marie; Šlais, Karel; Karásek, Pavel; Růžička, Filip; Šalplachta, Jiří; Šesták, Jozef; Kahle, Vladislav; Roth, Michal

    2016-10-01

    The electro-osmotic flow, a significant factor in capillary electrophoretic separations, is very sensitive to small changes in structure and surface roughness of the inner surface of fused silica capillary. Besides a number of negative effects, the electro-osmotic flow can also have a positive effect on the separation. An example could be fused silica capillaries with homogenous surface roughness along their entire separation length as produced by etching with supercritical water. Different strains of methicillin-resistant and methicillin-susceptible Staphylococcus aureus were separated on that type of capillaries. In the present study, fused-silica capillaries with a gradient of surface roughness were prepared and their basic behavior was studied in capillary zone electrophoresis with UV-visible detection. First the influence of the electro-osmotic flow on the peak shape of a marker of electro-osmotic flow, thiourea, has been discussed. An antifungal agent, hydrophobic amphotericin B, and a protein marker, albumin, have been used as model analytes. A significant narrowing of the detected zones of the examined analytes was achieved in supercritical-water-treated capillaries as compared to the electrophoretic separation in smooth capillaries. Minimum detectable amounts of 5 ng/mL amphotericin B and 5 μg/mL albumin were reached with this method.

  13. Impaired skin capillary recruitment in essential hypertension is caused by both functional and structural capillary rarefaction

    NARCIS (Netherlands)

    Serne, EH; Gans, ROB; ter Maaten, JC; Tangelder, GJ; Donker, AJM; Stehouwer, CDA

    2001-01-01

    Capillary rarefaction occurs in many tissues in patients with essential hypertension and may contribute to an increased vascular resistance and impaired muscle metabolism. Rarefaction may be caused by a structural (anatomic) absence of capillaries, functional nonperfusion, or both. The aim of this s

  14. Two-dimensional capillary electrophoresis: capillary isoelectric focusing and capillary zone electrophoresis with laser-induced fluorescence detection.

    Science.gov (United States)

    Dickerson, Jane A; Ramsay, Lauren M; Dada, Oluwatosin O; Cermak, Nathan; Dovichi, Norman J

    2010-08-01

    CIEF and CZE are coupled with LIF detection to create an ultrasensitive 2-D separation method for proteins. In this method, two capillaries are joined through a buffer-filled interface. Separate power supplies control the potential at the injection end of the first capillary and at the interface; the detector is held at ground potential. Proteins are labeled with the fluorogenic reagent Chromeo P503, which preserves the isoelectric point of the labeled protein. The labeled proteins were mixed with ampholytes and injected into the first-dimension capillary. A focusing step was performed with the injection end of the capillary at high pH and the interface at low pH. To mobilize components, the interface was filled with a high pH buffer, which was compatible with the second-dimension separation. A fraction was transferred to the second-dimension capillary for separation. The process of fraction transfer and second dimension separation was repeated two dozen times. The separation produced a spot capacity of 125.

  15. NMR study comparing capillary trapping in Berea sandstone of air, carbon dioxide, and supercritical carbon dioxide after imbibition of water

    Science.gov (United States)

    Prather, Cody A.; Bray, Joshua M.; Seymour, Joseph D.; Codd, Sarah L.

    2016-02-01

    Nuclear magnetic resonance (NMR) techniques were used to study the capillary trapping mechanisms relevant to carbon sequestration. Capillary trapping is an important mechanism in the initial trapping of supercritical CO2 in the pore structures of deep underground rock formations during the sequestration process. Capillary trapping is considered the most promising trapping option for carbon sequestration. NMR techniques noninvasively monitor the drainage and imbibition of air, CO2, and supercritical CO2 with DI H2O at low capillary numbers in a Berea sandstone rock core under conditions representative of a deep underground saline aquifer. Supercritical CO2 was found to have a lower residual nonwetting (NW) phase saturation than that of air and CO2. Supercritical CO2 behaves differently than gas phase air or CO2 and leads to a reduction in capillary trapping. NMR relaxometry data suggest that the NW phase, i.e., air, CO2, or supercritical CO2, is preferentially trapped in larger pores. This is consistent with snap-off conditions being more favorable in macroscale pores, as NW fluids minimize their contact area with the solid and hence prefer larger pores.

  16. VERTICAL VIBRATION ANALYSIS OF AXISYMMETRIC SATURATED SOIL

    Institute of Scientific and Technical Information of China (English)

    CAI Yuan-qiang; XU Chang-jie; ZHENG Zao-feng; WU Da-zhi

    2006-01-01

    Based on Biot's dynamic consolidation equations, by means of Laplace-Hankel transform technology, the integral solutions of stress and displacement in saturated soil with subjacent rock-stratum under axisymmetric arbitrary excitations were derived. Influence of the reflected wave generated by the boundary was revealed. Numerical results indicate that the vibration frequency has some effect on the vertical displacement of saturated soil. The vertical displacement at the surface of saturated soil lags in phase with the load. Furthermore, the dynamic permeability coefficient of saturated soil has significant effect on the vertical displacement at the initial stage of load applied, but when the load becomes stable, the effect is inapparent.

  17. A Novel Polybrene/Chondroitin Sulfate C Double Coated Capillary and Its Application in Capillary Electrophoresis

    Institute of Scientific and Technical Information of China (English)

    DU,Ying-Xiang(杜迎翔); HONDA,Susumu; TAGA,Atsushi; LIU,Wen-Ying(刘文英); SUZUKI,Shigeo

    2002-01-01

    A new capillary coated by double polymer, polybrene/chondroitin sulfate C (P/CC), was developed using a simple procedure. The P/CC double coated capillary showed long lifetime,strong chemical stability and good reproducibility. It endured during more than 100 replicated analyses and was also tolerant to HCl (1 mol/L), NaOH (0.01 mol/L), CH3OH and CH3CN. The P/CC double coated capillary can be applied to basic drug analyses. The adsorption of basic drugs to the capillary wall was suppressed and the peak tailing greatly decreased. The use of the P/CC double coated capillary allowed excelent separation of the enantiomers of some basic drugs by using chondroitin sulfate C as the chiral selector, ami the peak symmetry of basic drugs was further improved under these conditions.

  18. A discrete element model for simulating saturated granular soil

    Institute of Scientific and Technical Information of China (English)

    Mahan Lamei; Ali Asghar Mirghasemi

    2011-01-01

    A numerical model is developed to simulate saturated granular soil,based on the discrete element method.Soil particles are represented by Lagrangian discrete elements,and pore fluid,by appropriate discrete elements which represent alternately Lagrangian mass of water and Eulerian volume of space.Macroscale behavior of the model is verified by simulating undrained biaxial compression tests.Micro-scale behavior is compared to previous literature through pore pressure pattern visualization during shear tests,it is demonstrated that dynamic pore pressure patterns are generated by superposed stress waves.These pore-pressure patterns travel much faster than average drainage rate of the pore fluid and may initiate soil fabric change,ultimately leading to liquefaction in loose sands.Thus,this work demonstrates a tool to roughly link dynamic stress wave patterns to initiation of liquefaction phenomena.

  19. LIQUEFACTION AND DISPLACEMENT OF SATURATED SAND UNDER VERTICAL VIBRATION LOADING

    Institute of Scientific and Technical Information of China (English)

    LU Xiaobing; TAN Qingming; CHENG C.M.; YU Shanbing; CUI Peng

    2004-01-01

    In order to investigate the influence of the vertical vibration loading on the liquefaction of saturated sand, one dimensional model for the saturated sand with a vertical vibration is presented based on the two phase continuous media theory. The development of the liquefaction and the liquefaction region are analyzed. It is shown that the vertical vibration loading could induce liquefaction.The rate of the liquefaction increases with the increase of the initial limit strain or initial porosity or amplitude and frequency of loading, and increases with the decrease of the permeability or initial modulus. It is shown also that there is a phase lag in the sand column. When the sand permeability distribution is non-uniform, the pore pressure and the strain will rise sharply where the permeability is the smallest, and fracture might be induced. With the development of liquefaction, the strength of the soil foundation becomes smaller and smaller. In the limiting case, landslides or debris flows could occur.

  20. A model for wave propagation in a porous solid saturated by a three-phase fluid.

    Science.gov (United States)

    Santos, Juan E; Savioli, Gabriela B

    2016-02-01

    This paper presents a model to describe the propagation of waves in a poroelastic medium saturated by a three-phase viscous, compressible fluid. Two capillary relations between the three fluid phases are included in the model by introducing Lagrange multipliers in the principle of virtual complementary work. This approach generalizes that of Biot for single-phase fluids and allows to determine the strain energy density, identify the generalized strains and stresses, and derive the constitutive relations of the system. The kinetic and dissipative energy density functions are obtained assuming that the relative flow within the pore space is of laminar type and obeys Darcy's law for three-phase flow in porous media. After deriving the equations of motion, a plane wave analysis predicts the existence of four compressional waves, denoted as type I, II, III, and IV waves, and one shear wave. Numerical examples showing the behavior of all waves as function of saturation and frequency are presented.

  1. Restructuring and aging in a capillary suspension.

    Science.gov (United States)

    Koos, Erin; Kannowade, Wolfgang; Willenbacher, Norbert

    2014-12-01

    The rheological properties of capillary suspensions, suspensions with small amounts of an added immiscible fluid, are dramatically altered with the addition of the secondary fluid. We investigate a capillary suspension to determine how the network ages and restructures at rest and under applied external shear deformation. The present work uses calcium carbonate suspended in silicone oil (11 % solids) with added water as a model system. Aging of capillary suspensions and their response to applied oscillatory shear is distinctly different from particulate gels dominated by the van der Waals forces. The suspensions dominated by the capillary force are very sensitive to oscillatory flow, with the linear viscoelastic regime ending at a deformation of only 0.1% and demonstrating power-law aging behavior. This aging persists for long times at low deformations or for shorter times with a sudden decrease in the strength at higher deformations. This aging behavior suggests that the network is able to rearrange and even rupture. This same sensitivity is not demonstrated in shear flow where very high shear rates are required to rupture the agglomerates returning the apparent viscosity of capillary suspensions to the same viscosity as for the pure vdW suspension. A transitional region is also present at intermediate water contents wherein the material response depends very strongly on the type, strength, and duration of the external forcing.

  2. Synthetic Capillaries to Control Microscopic Blood Flow

    Science.gov (United States)

    Sarveswaran, K.; Kurz, V.; Dong, Z.; Tanaka, T.; Penny, S.; Timp, G.

    2016-02-01

    Capillaries pervade human physiology. The mean intercapillary distance is only about 100 μm in human tissue, which indicates the extent of nutrient diffusion. In engineered tissue the lack of capillaries, along with the associated perfusion, is problematic because it leads to hypoxic stress and necrosis. However, a capillary is not easy to engineer due to its complex cytoarchitecture. Here, it is shown that it is possible to create in vitro, in about 30 min, a tubular microenvironment with an elastic modulus and porosity consistent with human tissue that functionally mimicks a bona fide capillary using “live cell lithography”(LCL) to control the type and position of cells on a composite hydrogel scaffold. Furthermore, it is established that these constructs support the forces associated with blood flow, and produce nutrient gradients similar to those measured in vivo. With LCL, capillaries can be constructed with single cell precision—no other method for tissue engineering offers such precision. Since the time required for assembly scales with the number of cells, this method is likely to be adapted first to create minimal functional units of human tissue that constitute organs, consisting of a heterogeneous population of 100–1000 cells, organized hierarchically to express a predictable function.

  3. Measurement and correlation of saturated vapor pressure for p -aminophenol- ethanol/water mixed solvent system%对氨基苯酚-乙醇/水复合溶剂体系饱和蒸汽压的测定和关联

    Institute of Scientific and Technical Information of China (English)

    金珊; 孙杰; 金申

    2011-01-01

    Saturated vapor pressures of ethanol -water mixed solvent ( mass fraction of 55% , sample 1) and p - aminophenol - ethanol/water system (mass fraction of 25% .sample 2) were measured by static method at 363 - 423 K, respectively. The non - linear regression of experimental data was conduced by Antoine equation. The results showed that constant terms A,B,C of Antoine equation for sample 1 in turn were 16.042, -3 305.400, -64. 496 , correlation coefficient was 0.999 97.The above values of sample 2 in turn were 10. 525 , -605.260, -269.020,0.999 94. The average deviation of sample 1 between the calculated value and the experimental data was less than 0.60% and the maximum deviation was 1.27% , those of sample 2 were 0. 95% ,2. 30% .respectively.%在363-423 K条件下,采用静态法测定了质量分数为55%的乙醇-水复合溶剂(以下简称试样1)及质量分数为25%的对氨基苯酚-乙醇/水复合溶剂体系(以下简称试样2)的饱和蒸汽压.用Antoine方程对实验数据进行了非线性回归.结果表明,试样1的Antoine方程常数项A,B,C依次为16.042,-3 305.400,- 64.496,相关系数为0.999 97.试样2的上述各值依次为10.525,-605.260,- 269.020,0.999 94.试样1的计算值与实验值的平均偏差为0.60%,最大偏差为1.27%;试样2的分别为0.95%,2.30%.

  4. Protection against high intravascular pressure in giraffe legs

    DEFF Research Database (Denmark)

    Petersen, Karin K; Hørlyck, Arne; Østergaard, Kristine Hovkjær

    2013-01-01

    The high blood pressure in giraffe leg arteries renders giraffes vulnerable to edema. We investigated in 11 giraffes whether large and small arteries in the legs and the tight fascia protect leg capillaries. Ultrasound imaging of foreleg arteries in anesthetized giraffes and ex vivo examination....... All three findings can contribute to protection of the capillaries in giraffe legs from a high arterial pressure....... revealed abrupt thickening of the arterial wall and a reduction of its internal diameter just below the elbow. At and distal to this narrowing, the artery constricted spontaneously and in response to norepinephrine and intravascular pressure recordings revealed a dynamic, viscous pressure drop along...

  5. Directional transport of impinging capillary jet on wettability engineered surfaces

    Science.gov (United States)

    Ghosh, Aritra; Chatterjee, Souvick; Sinha Mahapatra, Pallab; Ganguly, Ranjan; Megaridis, Constantine

    2015-11-01

    Impingement of capillary jet on a surface is important for applications like heat transfer, or for liquid manipulation in bio-microfluidic devices. Using wettability engineered surfaces, we demonstrate pump-less and directional transport of capillary jet on a flat surface. Spatial contrast of surface energy and a wedge-shape geometry of the wettability confined track on the substrate facilitate formation of instantaneous spherical bulges upon jet impingement; these bulges are further transported along the superhydrophilic tracks due to Laplace pressure gradient. Critical condition warranted for formation of liquid bulge along the varying width of the superhydrophilic track is calculated analytically and verified experimentally. The work throws light on novel fluid phenomena of unidirectional jet impingement on wettability confined surfaces and provides a platform for innovative liquid manipulation technique for further application. By varying the geometry and wettability contrast on the surface, one can achieve volume flow rates of ~ O(100 μL/sec) and directionally guided transport of the jet liquid, pumplessly at speeds of ~ O(10cm/sec).

  6. Interpreting HSE Contents of Planetary Basalts: The Importance of Sulfide Saturation and Under-Saturation

    Science.gov (United States)

    Righter, K.

    2000-01-01

    Highly siderophile elements provide important constraints on planetary differentiation due to their siderophile behavior. Their interpretation in terms of planetary differentiation models has so far overlooked the importance of sulfide saturation and under-saturation.

  7. Saturated fat, carbohydrate, and cardiovascular disease.

    Science.gov (United States)

    Siri-Tarino, Patty W; Sun, Qi; Hu, Frank B; Krauss, Ronald M

    2010-03-01

    A focus of dietary recommendations for cardiovascular disease (CVD) prevention and treatment has been a reduction in saturated fat intake, primarily as a means of lowering LDL-cholesterol concentrations. However, the evidence that supports a reduction in saturated fat intake must be evaluated in the context of replacement by other macronutrients. Clinical trials that replaced saturated fat with polyunsaturated fat have generally shown a reduction in CVD events, although several studies showed no effects. An independent association of saturated fat intake with CVD risk has not been consistently shown in prospective epidemiologic studies, although some have provided evidence of an increased risk in young individuals and in women. Replacement of saturated fat by polyunsaturated or monounsaturated fat lowers both LDL and HDL cholesterol. However, replacement with a higher carbohydrate intake, particularly refined carbohydrate, can exacerbate the atherogenic dyslipidemia associated with insulin resistance and obesity that includes increased triglycerides, small LDL particles, and reduced HDL cholesterol. In summary, although substitution of dietary polyunsaturated fat for saturated fat has been shown to lower CVD risk, there are few epidemiologic or clinical trial data to support a benefit of replacing saturated fat with carbohydrate. Furthermore, particularly given the differential effects of dietary saturated fats and carbohydrates on concentrations of larger and smaller LDL particles, respectively, dietary efforts to improve the increasing burden of CVD risk associated with atherogenic dyslipidemia should primarily emphasize the limitation of refined carbohydrate intakes and a reduction in excess adiposity.

  8. Seismic determination of saturation in fractured reservoirs

    Science.gov (United States)

    Brown, R.L.; Wiggins, M.L.; Gupta, A.

    2002-01-01

    Detecting the saturation of a fractured reservoir using shear waves is possible when the fractures have a geometry that induces a component of movement perpendicular to the fractures. When such geometry is present, vertically traveling shear waves can be used to examine the saturation of the fractured reservoir. Tilted, corrugated, and saw-tooth fracture models are potential examples.

  9. Saturation and geometrical scaling in small systems

    CERN Document Server

    Praszalowicz, Michal

    2016-01-01

    Saturation and geometrical scaling (GS) of gluon distributions are a consequence of the non-linear evolution equations of QCD. We argue that in pp GS holds for the inelastic cross-section rather than for the multiplicity distributions. We also discuss possible fluctuations of the proton saturation scale in pA collisions at the LHC.

  10. Semiconductor saturable absorbers for ultrafast terahertz signals

    DEFF Research Database (Denmark)

    Hoffmann, Matthias C.; Turchinovich, Dmitry

    2010-01-01

    We demonstrate saturable absorber behavior of n-type semiconductors GaAs, GaP, and Ge in the terahertz THz frequency range at room temperature using nonlinear THz spectroscopy. The saturation mechanism is based on a decrease in electron conductivity of semiconductors at high electron momentum...

  11. Ultrafast THz Saturable Absorption in Semiconductors

    DEFF Research Database (Denmark)

    Turchinovich, Dmitry; Hoffmann, Matthias C.

    2011-01-01

    We demonstrate THz saturable absorption in n-doped semiconductors GaAs, GaP, and Ge in a nonlinear THz time-domain spectroscopy experiment. Saturable absorption is caused by sample conductivity modulation due to electron heating and satellite valley scattering in the field of a strong THz pulse....

  12. Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Michael Batzle

    2006-04-30

    During this last period of the ''Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs'' project (Grant/Cooperative Agreement DE-FC26-02NT15342), we finalized integration of rock physics, well log analysis, seismic processing, and forward modeling techniques. Most of the last quarter was spent combining the results from the principal investigators and come to some final conclusions about the project. Also much of the effort was directed towards technology transfer through the Direct Hydrocarbon Indicators mini-symposium at UH and through publications. As a result we have: (1) Tested a new method to directly invert reservoir properties, water saturation, Sw, and porosity from seismic AVO attributes; (2) Constrained the seismic response based on fluid and rock property correlations; (3) Reprocessed seismic data from Ursa field; (4) Compared thin layer property distributions and averaging on AVO response; (5) Related pressures and sorting effects on porosity and their influence on DHI's; (6) Examined and compared gas saturation effects for deep and shallow reservoirs; (7) Performed forward modeling using geobodies from deepwater outcrops; (8) Documented velocities for deepwater sediments; (9) Continued incorporating outcrop descriptive models in seismic forward models; (10) Held an open DHI symposium to present the final results of the project; (11) Relations between Sw, porosity, and AVO attributes; (12) Models of Complex, Layered Reservoirs; and (14) Technology transfer Several factors can contribute to limit our ability to extract accurate hydrocarbon saturations in deep water environments. Rock and fluid properties are one factor, since, for example, hydrocarbon properties will be considerably different with great depths (high pressure) when compared to shallow properties. Significant over pressure, on the other hand will make the rocks behave as if they were shallower. In addition to the physical properties, the scale and

  13. Novel absorption detection techniques for capillary electrophoresis

    Energy Technology Data Exchange (ETDEWEB)

    Xue, Yongjun [Iowa State Univ., Ames, IA (United States)

    1994-07-27

    Capillary electrophoresis (CE) has emerged as one of the most versatile separation methods. However, efficient separation is not sufficient unless coupled to adequate detection. The narrow inner diameter (I.D.) of the capillary column raises a big challenge to detection methods. For UV-vis absorption detection, the concentration sensitivity is only at the μM level. Most commercial CE instruments are equipped with incoherent UV-vis lamps. Low-brightness, instability and inefficient coupling of the light source with the capillary limit the further improvement of UV-vis absorption detection in CE. The goals of this research have been to show the utility of laser-based absorption detection. The approaches involve: on-column double-beam laser absorption detection and its application to the detection of small ions and proteins, and absorption detection with the bubble-shaped flow cell.

  14. Capillary rise of water in hydrophilic nanopores

    CERN Document Server

    Gruener, Simon; Wallacher, Dirk; Kityk, Andriy V; Huber, Patrick; 10.1103/PhysRevE.79.067301

    2009-01-01

    We report on the capillary rise of water in three-dimensional networks of hydrophilic silica pores with 3.5nm and 5nm mean radii, respectively (porous Vycor monoliths). We find classical square root of time Lucas-Washburn laws for the imbibition dynamics over the entire capillary rise times of up to 16h investigated. Provided we assume two preadsorbed strongly bound layers of water molecules resting at the silica walls, which corresponds to a negative velocity slip length of -0.5nm for water flow in silica nanopores, we can describe the filling process by a retained fluidity and capillarity of water in the pore center. This anticipated partitioning in two dynamic components reflects the structural-thermodynamic partitioning in strongly silica bound water layers and capillary condensed water in the pore center which is documented by sorption isotherm measurements.

  15. 液压高频振动沉桩的饱和土超静孔压及单桩静载特性试验研究%Experimental studies on pore pressure of saturated soils and bearing capacity of piles driven by high-frequency hydraulic vibrator

    Institute of Scientific and Technical Information of China (English)

    邓俊杰; 陈龙珠; 邢爱国; 宋春雨

    2011-01-01

    为解决常规锤击、电动中低频振动法进行桩基施工时引起较为严重的噪声、振动和增大电网负荷等问题,发达国家已在应用液压高频振动施工技术,但沉桩的土动力学机理以及单桩静力荷载-沉降特性等尚缺乏深入的室内外试验研究.利用大吨位液压高频振动锤,在某深厚饱和软土场地对直径500 mm、长度26~29 m的预应力管桩进行了沉桩施工试验,观测了邻近地基土超静孔压随沉桩深度而上升及其后续消散的过程;在休止期满后进行了单桩怪向静载荷试验,并将实测极限承载力与其它常规施工方法的进行了比较分析.试验结果对推广应用液压高频振动沉桩新技术,具有重要的学术和应用参考价值.%To solve the serious noise and vibration problems as well as the high pressure on the capacity of city power supply caused by the existing piling methods with falling hammers and low-frequency electric vibrators, a new piling technique using high-frequency hydraulic vibrators has been used in some developed european countries and the USA.The piling mechanism related to soil dynamics at high frequency and the bearing capacity of piles after installation with the hydraulic vibrators should be investigated in laboratory and construction sites.Using a high-frequency hydraulic vibrator manufactured by a Shanghai machinery company, pre-casted/pre-stressed concrete pipe piles with diameter of 500 mm and length of 26-29 m are driven into the saturated soft ground in the Minhang campus of Shanghai Jiaotong University in China, and the induced excess pore water pressures of adjacent soil at different depths are investigated for about one month.After the specified interruption period of 28 days after piling, the ultimate bearing capacity of each pile is studied by means of the conventional static loading tests and compared with that of piles installed with falling hammers and statically jetting.The experimental