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Sample records for canadian fuel cell

  1. Canadian fusion fuels technology project

    International Nuclear Information System (INIS)

    The Canadian Fusion Fuels Technology Project was launched in 1982 to coordinate Canada's provision of fusion fuels technology to international fusion power development programs. The project has a mandate to extend and adapt existing Canadian tritium technologies for use in international fusion power development programs. 1985-86 represents the fourth year of the first five-year term of the Canadian Fusion Fuels Technology Project (CFFTP). This reporting period coincides with an increasing trend in global fusion R and D to direct more effort towards the management of tritium. This has resulted in an increased linking of CFFTP activities and objectives with those of facilities abroad. In this way there has been a continuing achievement resulting from CFFTP efforts to have cooperative R and D and service activities with organizations abroad. All of this is aided by the cooperative international atmosphere within the fusion community. This report summarizes our past year and provides some highlights of the upcoming year 1986/87, which is the final year of the first five-year phase of the program. AECL (representing the Federal Government), the Ministry of Energy (representing Ontario) and Ontario Hydro, have given formal indication of their intent to continue with a second five-year program. Plans for the second phase will continue to emphasize tritium technology and remote handling

  2. Canadian used fuel disposal concept review

    International Nuclear Information System (INIS)

    A federal government environmental assessment review of the disposal concept developed under the Canadian Nuclear Fuel Waste Management Program is currently underway. The Canadian concept is, simply stated, the placement of used fuel (or fuel waste) in long-lived containers at a depth between 500 m and 1000 m in plutonic rock of the Canadian Shield. Atomic Energy of Canada Limited submitted an Environmental Impact Statement in 1994 and the public hearing aspect of the concept review is in its final phase. A unique aspect of the Canadian situation is that government has stipulated that site selection can not commence until the concept has been approved. Hence, the safety and acceptability of the concept is being reviewed in the context of a generic site. Some comments and lessons learned to date related to the review process are discussed. (author)

  3. Fuel condition in Canadian CANDU 6 reactors

    Energy Technology Data Exchange (ETDEWEB)

    Hu, R.H.; Macici, N [Hydro-Quebec, Montreal, Quebec (Canada); Gibb, R. [New Brunswick Power, Lepreau, NB (Canada); Purdy, P.L.; Manzer, A.M. [Atomic Energy of Canada Limited, Mississauga, Ontario (Canada); Kohn, E. [Ontario Hydro, Toronto, Ontario (Canada)

    1997-07-01

    The cornerstone of the CANDU concept is its natural uranium fuel, and the success of its reactor operation hinges on the fuel condition in the reactor. Neutron economy, on power refuelling, and simple fuel design are among the unique characteristics of CANDU fuel. In Canadian CANDU 6 reactors (Gentilly 2 and Point Lepreau), the 37-element fuel has provided an enviable record of safe, economic and reliable plant operation for 29 reactor years to date. The fuelling cost is among the lowest in the world - a corollary of high neutron economy, simple fuel design, and judicial fuelling scheme. The reliability of fuel is high: only 21 of the 60000 bundles discharged from Gentilly 2 were confirmed defective and the five-year period from March 1992 to February 1997 saw no defect at all at Gentilly-2. Also, thanks to the inherent on-power refuelling capability and an effective defect detection and removal system, the primary coolant loops are kept extremely clean (very low activity level) - benefiting both maintenance and safety. Moreover, the inventories of fission products in the core and in the channel are maintained within the safety analysis envelope, due to on-power fuelling and sophisticated fuel management. In this paper, CANDU 6 fuel performance is reviewed against the feedback from post-irradiation examinations, and the findings from our ongoing R and D program. The results suggest that the fuel behavior m reactor are basically as originally anticipated, despite an evolutionary 3% increase in bundle uranium mass in the 1980's. For operating conditions within the CANDU 6 37-element experience, the average strains are typically 0.09%; and fission gas release, 2.7%. The UO{sub 2} fuel remains stoichiometric after irradiation. In-core measurements of pressure tube fitting are generally low. All these observations are consistent with the excellent fuel performance statistics coming out of the two Canadian CANDU 6 reactors. Additionally, this paper will briefly

  4. Fuel condition in Canadian CANDU 6 reactors

    International Nuclear Information System (INIS)

    The cornerstone of the CANDU concept is its natural uranium fuel, and the success of its reactor operation hinges on the fuel condition in the reactor. Neutron economy, on power refuelling, and simple fuel design are among the unique characteristics of CANDU fuel. In Canadian CANDU 6 reactors (Gentilly 2 and Point Lepreau), the 37-element fuel has provided an enviable record of safe, economic and reliable plant operation for 29 reactor years to date. The fuelling cost is among the lowest in the world - a corollary of high neutron economy, simple fuel design, and judicial fuelling scheme. The reliability of fuel is high: only 21 of the 60000 bundles discharged from Gentilly 2 were confirmed defective and the five-year period from March 1992 to February 1997 saw no defect at all at Gentilly-2. Also, thanks to the inherent on-power refuelling capability and an effective defect detection and removal system, the primary coolant loops are kept extremely clean (very low activity level) - benefiting both maintenance and safety. Moreover, the inventories of fission products in the core and in the channel are maintained within the safety analysis envelope, due to on-power fuelling and sophisticated fuel management. In this paper, CANDU 6 fuel performance is reviewed against the feedback from post-irradiation examinations, and the findings from our ongoing R and D program. The results suggest that the fuel behavior m reactor are basically as originally anticipated, despite an evolutionary 3% increase in bundle uranium mass in the 1980's. For operating conditions within the CANDU 6 37-element experience, the average strains are typically 0.09%; and fission gas release, 2.7%. The UO2 fuel remains stoichiometric after irradiation. In-core measurements of pressure tube fitting are generally low. All these observations are consistent with the excellent fuel performance statistics coming out of the two Canadian CANDU 6 reactors. Additionally, this paper will briefly discuss our

  5. Canadian Fusion Fuels Technology Project activities report

    International Nuclear Information System (INIS)

    The Canadian Fusion Fuels Technology Project was formally established in 1982. The project is directed toward the further development of Canadian capabilities in five major areas: tritium technology, breeder technology, materials technology, equipment development and safety and the environment. The project is funded by three partners - Government of Canada (50%), Ontario Provincial Government (25%) and Ontario Hydro (25%). The fiscal year 1984/85 represents the third year of operation of the project. In 1984/85, 108 contracts were awarded totalling $4 million. Supplementary funding by subcontractors added approximately $1.9 million to the total project value. More than 200 people participated in the technical work involved in the project. Sixteen people were on attachment to foreign facilities for terms ranging from 1 month to 2.5 years. Five patents were applied for including a tritium discrimination monitor, a new radio-chemical tritium separation method, a new variation of fuel cleanup by gas chromatography, a passive tritium permeation system using bimetallic membranes, and a new breeder process using lithium salts dissolved in heavy water

  6. The Canadian nuclear fuel waste management program

    International Nuclear Information System (INIS)

    An overview is presented of the status of the research and development program, under rsponsibility of the Atomic Energy of Canada Limited (AECL), for assessing the concept of nuclear fuel waste disposal deep in plutonic rock of the Canadian Shield. A passive multi-barrier concept has been adopted for disposal that combines the containment provided by the structural, hydraulic and geochemical characteristics of the rock mass with a series of engineered barriers. The conceptual disposal vault consists of an array of disposal rooms excavated in plutonic rock at a depth between 500 and 1000 m. Prior to disposal, the waste would be placed in cylindrical containers surrounded by a buffer, which is a mixture of bentonite cla and sand. The rooms would be backfilled with mixture of clay, and crushed granite or san. Bulkheads would seal the entrances. Closure would be achieved by backfilling the access tunnels in the same manner as the rooms and than backfilling the shafts with compacted clay and crushed granite separated by a series of supporting bulkheads. Very preliminary results from the case study indicate that the good rock provides the most effective barrier to movement of radionuclides to the surface. The most significant pathways through the geosphere involve diffusion through the good rock to the major fracture intersecting the vault, convection upward along the fracture, and discharge either at topographic lows or through a domestic water supply well used by the critical group. Long-lived non-sorbing radionuclides, available in the gaps between the fuel pellets and the fuel cladding or at the grain boundaries, contribute most to the radiological dose. With appropriate constraints on the location of the waste packages relative to the major fracture zones, radiological risk is expected to satisfy the regulatory criteria. (H.W.) 5 figs

  7. Fuel Cells

    DEFF Research Database (Denmark)

    Smith, Anders; Pedersen, Allan Schrøder

    2014-01-01

    Fuel cells have been the subject of intense research and development efforts for the past decades. Even so, the technology has not had its commercial breakthrough yet. This entry gives an overview of the technological challenges and status of fuel cells and discusses the most promising applications...... of the different types of fuel cells. Finally, their role in a future energy supply with a large share of fluctuating sustainable power sources, e.g., solar or wind, is surveyed....

  8. Fuel cells:

    DEFF Research Database (Denmark)

    Sørensen, Bent

    2013-01-01

    A brief overview of the progress in fuel cell applications and basic technology development is presented, as a backdrop for discussing readiness for penetration into the marketplace as a solution to problems of depletion, safety, climate or environmental impact from currently used fossil...... and nuclear fuel-based energy technologies....

  9. Fuel cells

    Directory of Open Access Journals (Sweden)

    D. N. Srivastava

    1962-05-01

    Full Text Available The current state of development of fuel cells as potential power sources is reviewed. Applications in special fields with particular reference to military requirements are pointed out.

  10. The Canadian nuclear fuel waste management program

    International Nuclear Information System (INIS)

    This report, the fifth of a series of annual reports, reviews the progress that has been made in the research and development program for the safe management and disposal of Canada's nuclear fuel waste. The report summarizes activities over the past year in the following areas: public interaction; used fuel storage and transportation; immobilization of used fuel and fuel recycle waste; geoscience research related to deep underground disposal; environmental research; and environmental and safety assessment

  11. Fuel Cells

    Science.gov (United States)

    Hawkins, M. D.

    1973-01-01

    Discusses the theories, construction, operation, types, and advantages of fuel cells developed by the American space programs. Indicates that the cell is an ideal small-scale power source characterized by its compactness, high efficiency, reliability, and freedom from polluting fumes. (CC)

  12. Detecting, locating and identifying failed fuel in Canadian power reactors

    International Nuclear Information System (INIS)

    This document summarizes how defected fuel elements are detected, located and identified in Canadian CANDU power reactors. Fuel defects are detected by monitoring the primary coolant for gaseous fission products and radioiodines, while location in core is usually performed on-power by delayed neutron monitoring of coolant samples from individual fuel channels or off-power by gamma-ray monitoring of the channel feeder pipes. The systems and techniques used to detect and locate defected fuel in both Ontario Hydro and CANDU 6 power stations are described, along with examples provided by station experience. The ability to detect and locate defected fuel in power stations was greatly enhanced by a fundamental R and D program, which provided an understanding and models of fission-product release and transport, and the post-defect deterioration of failed fuel. Techniques and equipment used to identify and store defected fuel after it has been discharged from the reactor are briefly reviewed

  13. Development of a fuel performance model for evaluating conceptual Th-based Canadian SCWR fuel designs

    International Nuclear Information System (INIS)

    The fuel assembly for the Canadian Super Critical Water Reactor (SCWR) is in the conceptual design phase. The proposed fuel pellets are made of ceramic Th-Pu mixed oxide ((Th,Pu)O2). Neutronics and thermal hydraulics calculations are being undertaken by the nuclear industry to optimize the fuel assembly within a pressure tube. The SCWR working group shave established two conceptual fuel element designs (outer diameter, fuel composition, cladding material, exit burnup etc.) within an assembly for performance assessment. A detailed fuel element performance assessment under in-reactor conditions could be used to determine cladding material thickness/suitability and to optimize the fuel pellet geometry. This work reports the development of a fuel performance model to predict the behaviour of the Canadian SCWR fuel using the finite element method. An initial approach is to develop a thorium-uranium mixed-oxide ((Th,U)O2) model.Preliminary results from this model agree with fuel irradiation data . Uranium dioxide (UO2) fuel, under the same conditions, is also being modeled and compared. A plan to model (Th, Pu)O2 SCWR fuel is briefly presented here. (author)

  14. GSPEL - Fuel Cell Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — The Fuel Cell Lab (FCL) Provides testing for technology readiness of fuel cell systems The FCL investigates, tests and verifies the performance of fuel-cell systems...

  15. Nuclear fuel waste disposal: The Canadian consultative approach

    International Nuclear Information System (INIS)

    Over the past two decades society has demanded more public participation and public input into decision-making governments. Accordingly, development of the Canadian concept for deep geological disposal of used nuclear fuel has taken into account the requirements for social acceptability as well as technical excellence. As the agency responsible for developing the disposal concept, AECL Research, the research and development arm of Atomic Energy of Canada Ltd., has included, in its program, consultation with the various publics that have an interest in the concept. This interactive and consultative process, which has been underway for some 14 years, has attempted to ensure that the public has had the opportunity to become familiar with the technical development of the concept and to provide input into it. This process will continue throughout the concept assessment and review currently in progress

  16. Direct hydrocarbon fuel cells

    Science.gov (United States)

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  17. Materials for fuel cells

    Directory of Open Access Journals (Sweden)

    Sossina M Haile

    2003-03-01

    Full Text Available Because of their potential to reduce the environmental impact and geopolitical consequences of the use of fossil fuels, fuel cells have emerged as tantalizing alternatives to combustion engines. Like a combustion engine, a fuel cell uses some sort of chemical fuel as its energy source but, like a battery, the chemical energy is directly converted to electrical energy, without an often messy and relatively inefficient combustion step. In addition to high efficiency and low emissions, fuel cells are attractive for their modular and distributed nature, and zero noise pollution. They will also play an essential role in any future hydrogen fuel economy.

  18. Modeling: driving fuel cells

    Directory of Open Access Journals (Sweden)

    Michael Francis

    2002-05-01

    Fuel cells were invented in 1839 by Sir William Grove, a Welsh judge and gentleman scientist, as a result of his experiments on the electrolysis of water. To put it simply, fuel cells are electrochemical devices that take hydrogen gas from fuel, combine it with oxygen from the air, and generate electricity and heat, with water as the only by-product.

  19. Microbial fuel cells

    International Nuclear Information System (INIS)

    Microbial fuel cells (MFC) are a promising technology for sustainable production of alternative energy and waste treatment. A microbial fuel cell transformation chemical energy in the chemical bonds in organic compounds to electrical energy through catalytic reactions of microorganisms under anaerobic conditions. It has been known for many years that it is possible to generate electricity directly by using bacteria to break down organic substrates. Key words: microbial fuel cells (MFC), biosensor, wastewater treatment

  20. Solid electrolytic fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, Masayasu; Yamauchi, Yasuhiro; Kamisaka, Mitsuo; Notomi, Kei.

    1989-04-21

    Concerning a solid electrolytic fuel cell with a gas permeable substrate pipe, a fuel electrode installed on this substrate pipe and an air electrode which is laminated on this fuel electrode with the electrolyte in between, the existing fuel cell of this kind uses crystals of CaMnO3, etc. for the material of the air electrode, but its electric resistance is big and in order to avert this, it is necessary to make the film thickness of the air electrode big. However, in such a case, the entry of the air into its inside worsens and the cell performance cannot develop satisfactorily. In view of the above, in order to obtain a high performance solid electrolytic fuel cell which can improve electric conductivity without damaging diffusion rate of the air, this invention proposes with regard to the aforementioned solid electrolytic fuel cell to install a heat resistant and conductive member inside the above air electrode. 6 figs.

  1. Market brief : The hydrogen and fuel cell market in Denmark

    International Nuclear Information System (INIS)

    This report presents an overview of the hydrogen and fuel cell market in Denmark, a global leader in this domain. The main focus of the hydrogen and fuel cell industry in Denmark is on the development of proton exchange membrane fuel cells, solid oxide fuel cells, and stationary applications for fuel cells. The industry is currently in the research and development phase, but commercialization is expected within the coming years. The wind industry in Denmark also intends to produce hydrogen from wind energy. This market brief describes the potential for Canadian suppliers to enter into joint ventures to establish local production facilities in Denmark and to transfer technology expertise. It describes the key factors shaping market growth and opportunities with actual and planned projects. The competitive environment was also discussed with reference to local capabilities, international competition, the Canadian position, and a competitive advantage through Canadian government policies and initiatives. A list of selected Canadian federal funding programs for the hydrogen and fuel cell industry was included. 27 refs., 2 tabs., 1 appendix

  2. Liquid fuel cells.

    Science.gov (United States)

    Soloveichik, Grigorii L

    2014-01-01

    The advantages of liquid fuel cells (LFCs) over conventional hydrogen-oxygen fuel cells include a higher theoretical energy density and efficiency, a more convenient handling of the streams, and enhanced safety. This review focuses on the use of different types of organic fuels as an anode material for LFCs. An overview of the current state of the art and recent trends in the development of LFC and the challenges of their practical implementation are presented.

  3. Fuel cells: Operating flexibly

    Science.gov (United States)

    Lee, Young Moo

    2016-09-01

    Fuel cells typically function well only in rather limited temperature and humidity ranges. Now, a proton exchange membrane consisting of ion pair complexes is shown to enable improved fuel cell performance under a wide range of conditions that are unattainable with conventional approaches.

  4. MICROBIAL FUEL CELL

    DEFF Research Database (Denmark)

    2008-01-01

    A novel microbial fuel cell construction for the generation of electrical energy. The microbial fuel cell comprises: (i) an anode electrode, (ii) a cathode chamber, said cathode chamber comprising an in let through which an influent enters the cathode chamber, an outlet through which an effluent...

  5. HTPEM Fuel Cell Impedance

    DEFF Research Database (Denmark)

    Vang, Jakob Rabjerg

    potentially play an important role in the energy system of the future. One of the fuel cell technologies, that receives much attention from the Danish scientific community is high temperature proton exchange membrane (HTPEM) fuel cells based on polybenzimidazole (PBI) with phosphoric acid as proton conductor...... cells through experimental studies and mathematical modelling. These studies all revolve around the electrochemical impedance spectroscopy (EIS) characterisation method. EIS is performed by applying a sinusoidal current or voltage signal to the fuel cell and calculating the impedance from the response...

  6. Guide to the Canadian nuclear fuel waste management program. 2.ed

    International Nuclear Information System (INIS)

    This document describes the administrative structure and major research and development components of the Canadian Nuclear Fuel Waste Management Program. It outlines the participating organizations, summarizes the program statistics, and describes the international cooperation and external review aspects of the program

  7. Fuel cells: Problems and prospects

    OpenAIRE

    Shukla, AK; Ramesh, KV; Kannan, AM

    1986-01-01

    n recent years, fuel cell technology has advanced significantly. Field trials on certain types of fuel cells have shown promise for electrical use. This article reviews the electrochemistry, problems and prospects of fuel cell systems.

  8. Market brief : the hydrogen and fuel cells industry in Sweden

    International Nuclear Information System (INIS)

    An overview of the Swedish hydrogen industry was presented in this report, which also outlined some of the partnership opportunities available for Canadian hydrogen industry members. Details of research and development in Sweden's hydrogen and fuel cells sector were described. It was noted that in 2006, the Swedish government announced its plan to become the world's first oil-free economy by the year 2020. The development and use of hydrogen and fuel cell energy systems are seen as key to achieving their objectives. The EU's sixth Framework Programme (FP6) has dedicated an estimated $2.5 billion to fuel cells and hydrogen initiatives, and is working towards a target of 5 per cent EC road transport to be hydrogen-powered by 2020. Although Sweden's fuel cell development in a commercial environment had stagnated with the failure of Asea's work in alkaline fuel cells, larger energy utilities are now investing in hydrogen technology and have been responsible for the installation of Sweden's first hydrogen fuelling station in 2003. It was concluded that technological advances in stationary and portable fuel cell systems in Canada may offer good business opportunities for Canadian companies who wish to create partnerships with Sweden and other Nordic countries. Over the last 20 years, the government of Canada has provided more than $200 million in support of emerging Canadian fuel cell and hydrogen technologies. In 2005, the National Research Council's Institute for Fuel Cell Innovation hosted the Nordic-Canadian Hydrogen and Fuel Cell Partnership between Canada and Nordic countries. 55 refs

  9. Mechanical Properties of Fuel Cladding Candidate Alloys for Canadian SCWR Concept

    Science.gov (United States)

    Xu, Su; Amirkhiz, Babak Shalchi

    2016-02-01

    An assessment of tensile and creep of five representative candidate fuel cladding alloys for a Canadian Gen IV super-critical water reactor concept was performed based on database development work and complementary experiments including a transmission electron microscopy study of creep in stainless steels. The limiting property would be creep strength of candidate alloys for the "free-standing" fuel cladding design with a hot-spot peak temperature range of 1073-1123 K (800-850°C).

  10. Rejuvenation of automotive fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Yu Seung; Langlois, David A.

    2016-08-23

    A process for rejuvenating fuel cells has been demonstrated to improve the performance of polymer exchange membrane fuel cells with platinum/ionomer electrodes. The process involves dehydrating a fuel cell and exposing at least the cathode of the fuel cell to dry gas (nitrogen, for example) at a temperature higher than the operating temperature of the fuel cell. The process may be used to prolong the operating lifetime of an automotive fuel cell.

  11. FUEL CELLS IN ENERGY PRODUCTION

    OpenAIRE

    Huang, Xiaoyu

    2011-01-01

    The purpose of this thesis is to study fuel cells. They convert chemical energy directly into electrical energy with high efficiency and low emmission of pollutants. This thesis provides an overview of fuel cell technology.The basic working principle of fuel cells and the basic fuel cell system components are introduced in this thesis. The properties, advantages, disadvantages and applications of six different kinds of fuel cells are introduced. Then the efficiency of each fuel cell is p...

  12. Fuel processors for fuel cell APU applications

    Science.gov (United States)

    Aicher, T.; Lenz, B.; Gschnell, F.; Groos, U.; Federici, F.; Caprile, L.; Parodi, L.

    The conversion of liquid hydrocarbons to a hydrogen rich product gas is a central process step in fuel processors for auxiliary power units (APUs) for vehicles of all kinds. The selection of the reforming process depends on the fuel and the type of the fuel cell. For vehicle power trains, liquid hydrocarbons like gasoline, kerosene, and diesel are utilized and, therefore, they will also be the fuel for the respective APU systems. The fuel cells commonly envisioned for mobile APU applications are molten carbonate fuel cells (MCFC), solid oxide fuel cells (SOFC), and proton exchange membrane fuel cells (PEMFC). Since high-temperature fuel cells, e.g. MCFCs or SOFCs, can be supplied with a feed gas that contains carbon monoxide (CO) their fuel processor does not require reactors for CO reduction and removal. For PEMFCs on the other hand, CO concentrations in the feed gas must not exceed 50 ppm, better 20 ppm, which requires additional reactors downstream of the reforming reactor. This paper gives an overview of the current state of the fuel processor development for APU applications and APU system developments. Furthermore, it will present the latest developments at Fraunhofer ISE regarding fuel processors for high-temperature fuel cell APU systems on board of ships and aircrafts.

  13. PEM regenerative fuel cells

    Science.gov (United States)

    Swette, Larry L.; Laconti, Anthony B.; McCatty, Stephen A.

    1993-11-01

    This paper will update the progress in developing electrocatalyst systems and electrode structures primarily for the positive electrode of single-unit solid polymer proton exchange membrane (PEM) regenerative fuel cells. The work was done with DuPont Nafion 117 in complete fuel cells (40 sq cm electrodes). The cells were operated alternately in fuel cell mode and electrolysis mode at 80 C. In fuel cell mode, humidified hydrogen and oxygen were supplied at 207 kPa (30 psi); in electrolysis mode, water was pumped over the positive electrode and the gases were evolved at ambient pressure. Cycling data will be presented for Pt-Ir catalysts and limited bifunctional data will be presented for Pt, Ir, Ru, Rh, and Na(x)Pt3O4 catalysts as well as for electrode structure variations.

  14. Fuel Cells: Reshaping the Future

    Science.gov (United States)

    Toay, Leo

    2004-01-01

    In conjunction with the FreedomCAR (Cooperative Automotive Research) and Fuel Initiative, President George W. Bush has pledged nearly two billion dollars for fuel cell research. Chrysler, Ford, and General Motors have unveiled fuel cell demonstration vehicles, and all three of these companies have invested heavily in fuel cell research. Fuel cell…

  15. Human health considerations in the assessment of Canadian concept for the disposal of nuclear fuel wastes

    International Nuclear Information System (INIS)

    In 1978, AECL was mandated by the government of Ontario and the federal government to find a permanent disposal solution for spent nuclear fuels. Canada opted for disposal in plutonic rocks of the Canadian shield. The Canadian concept calls for disposal in crystalline rocks at a depth of 500 to 1000 m below the surface. The spent fuel would be contained in a canister, the canister would be emplaced in a vault containing clay-based buffer materials, and the cavity would be backfilled and sealed with natural materials. A Federal Environmental Assessment Review Panel was formed in 1992 to assess the concept for disposal of the spent fuel. In this paper a brief discussion of the human health impacts of the proposed concept is presented. Our assessment is based on the information provided by AECL, namely, the main EIS document, a summary and nine other supporting documents

  16. Alkaline fuel cells applications

    Science.gov (United States)

    Kordesch, Karl; Hacker, Viktor; Gsellmann, Josef; Cifrain, Martin; Faleschini, Gottfried; Enzinger, Peter; Fankhauser, Robert; Ortner, Markus; Muhr, Michael; Aronson, Robert R.

    On the world-wide automobile market technical developments are increasingly determined by the dramatic restriction on emissions as well as the regimentation of fuel consumption by legislation. Therefore there is an increasing chance of a completely new technology breakthrough if it offers new opportunities, meeting the requirements of resource preservation and emission restrictions. Fuel cell technology offers the possibility to excel in today's motive power techniques in terms of environmental compatibility, consumer's profit, costs of maintenance and efficiency. The key question is economy. This will be decided by the costs of fuel cell systems if they are to be used as power generators for future electric vehicles. The alkaline hydrogen-air fuel cell system with circulating KOH electrolyte and low-cost catalysed carbon electrodes could be a promising alternative. Based on the experiences of Kordesch [K. Kordesch, Brennstoffbatterien, Springer, Wien, 1984, ISBN 3-387-81819-7; K. Kordesch, City car with H 2-air fuel cell and lead-battery, SAE Paper No. 719015, 6th IECEC, 1971], who operated a city car hybrid vehicle on public roads for 3 years in the early 1970s, improved air electrodes plus new variations of the bipolar stack assembly developed in Graz are investigated. Primary fuel choice will be a major issue until such time as cost-effective, on-board hydrogen storage is developed. Ammonia is an interesting option. The whole system, ammonia dissociator plus alkaline fuel cell (AFC), is characterised by a simple design and high efficiency.

  17. Fuel cell; Nenryo denchi

    Energy Technology Data Exchange (ETDEWEB)

    Nakayama, T. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1999-07-20

    More than 100 sets of phosphoric acid fuel cells (PAFC) have been installed by now, and accumulated operation performance exceeding 40 thousand hours, which is regarded as a development target, has been achieved. Further, there are also PAFCs that have achieved continuous operation performance exceeding 9,000 hours, thus being most approachable to practical use. On the other hand, developments of the solid oxide fuel cells (SOFC) and the molten carbonate fuel cells (MCFC), which operate at high temperatures, have high power generation efficiencies due to the capability of operating associatively with gas turbines or vapor turbines, and may use coal gasified gases as fuels, are carried out for an aim of realizing the practical use at the begging of the 21st century. Further, in recent years, researches and developments of the polymer electrolyte fuel cells (PEFC) have been accelerated mainly in vehicle business for the purpose of using PEFC as power sources for movable bodies, and researches and development for accelerative development of cell stacks and power generation systems are executed. In this paper, situations of the researches and developments in respect to the above-mentioned four kinds of fuel cells are summarily introduced. (NEDO)

  18. 2009 Fuel Cell Market Report

    Energy Technology Data Exchange (ETDEWEB)

    Vincent, Bill [Breakthrough Technologies Inst., Washington, DC (United States); Gangi, Jennifer [Breakthrough Technologies Inst., Washington, DC (United States); Curtin, Sandra [Breakthrough Technologies Inst., Washington, DC (United States); Delmont, Elizabeth [Breakthrough Technologies Inst., Washington, DC (United States)

    2010-11-01

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of fuel is supplied. Moreover, fuel cells do not burn fuel, making the process quiet, pollution-free and two to three times more efficient than combustion. Fuel cell systems can be a truly zero-emission source of electricity, if the hydrogen is produced from non-polluting sources. Global concerns about climate change, energy security, and air pollution are driving demand for fuel cell technology. More than 630 companies and laboratories in the United States are investing $1 billion a year in fuel cells or fuel cell component technologies. This report provides an overview of trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance. It also provides snapshots of select fuel cell companies, including general.

  19. The development of lower enrichment fuels for Canadian research reactors

    International Nuclear Information System (INIS)

    As part of the world wide move to proliferation resistant fuels, new fuels which use reduced enrichment uranium are being developed for use in the NRX and NRU reactors. A fuel consisting of particles of a USiAl alloy dispersed in an Al matrix has been selected for development along with Al-37 wt% U alloy and Al-U3O8 cermet as backup fuels. This report outlines the progress made in the development of the Al-USiAl and Al-37 wt% U. Results show that good quality extruded rods containing either fuel can be made with techniques similar to those used to fabricate the current NRX and NRU fuels. However, the new fuels will be more expensive to make. Although the oxidation behaviour of the Al-USiAl is not as good as that of the Al-U alloys, its corrosion behaviour in high temperature water does not seem much worse. The oxidation and aqueous corrosion of A-37 wt% U are not much different from those of the Al-U alloys currently used. (author)

  20. Development of lower enrichment fuels for Canadian research reactors

    International Nuclear Information System (INIS)

    As part of the worldwide move to proliferation resistant fuels, new fuels which use reduced enrichment uranium are being developed for use in the NRX and NRU reactors. A fuel consisting of particles of a USiAl alloy dispersed in an Al matrix has been selected for development along with Al-37 wt % U alloy and Al-U3O8 cermet as backup fuels. This report outlines the progress made in the development of the Al-USiAl and Al-37 wt % U. Results show that good quality extruded rods containing either fuel can be made with techniques similar to those used to fabricate the current NRX and NRU fuels. However, the new fuels will be more expensive to make. Although the oxidation behavior of the Al-USiAl is not as good as that of the Al-U alloys, its corrosion behavior in high temperature water does not seem much worse. The oxidation and aqueous corrosion of Al-37 wt % U are not much different from those of the Al-U alloys currently used

  1. Seventh Edition Fuel Cell Handbook

    Energy Technology Data Exchange (ETDEWEB)

    NETL

    2004-11-01

    Provides an overview of fuel cell technology and research projects. Discusses the basic workings of fuel cells and their system components, main fuel cell types, their characteristics, and their development status, as well as a discussion of potential fuel cell applications.

  2. Fuel cell cogeneration

    Energy Technology Data Exchange (ETDEWEB)

    Wimer, J.G. [Dept. of Energy, Morgantown, WV (United States); Archer, D.

    1995-08-01

    The U.S. Department of Energy`s Morgantown Energy Technology Center (METC) sponsors the research and development of engineered systems which utilize domestic fuel supplies while achieving high standards of efficiency, economy, and environmental performance. Fuel cell systems are among the promising electric power generation systems that METC is currently developing. Buildings account for 36 percent of U.S. primary energy consumption. Cogeneration systems for commercial buildings represent an early market opportunity for fuel cells. Seventeen percent of all commercial buildings are office buildings, and large office buildings are projected to be one of the biggest, fastest-growing sectors in the commercial building cogeneration market. The main objective of this study is to explore the early market opportunity for fuel cells in large office buildings and determine the conditions in which they can compete with alternative systems. Some preliminary results and conclusions are presented, although the study is still in progress.

  3. Direct Methanol Fuel Cell, DMFC

    Directory of Open Access Journals (Sweden)

    Amornpitoksuk, P.

    2003-09-01

    Full Text Available Direct Methanol Fuel Cell, DMFC is a kind of fuel cell using methanol as a fuel for electric producing. Methanol is low cost chemical substance and it is less harmful than that of hydrogen fuel. From these reasons it can be commercial product. The electrocatalytic reaction of methanol fuel uses Pt-Ru metals as the most efficient catalyst. In addition, the property of membrane and system designation are also effect to the fuel cell efficient. Because of low power of methanol fuel cell therefore, direct methanol fuel cell is proper to use for the energy source of small electrical devices and vehicles etc.

  4. Fuel processor for fuel cell power system

    Science.gov (United States)

    Vanderborgh, Nicholas E.; Springer, Thomas E.; Huff, James R.

    1987-01-01

    A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

  5. Fuel Cell Testing - Degradation of Fuel Cells and its Impact on Fuel Cell Applications

    OpenAIRE

    Pfrang, Andreas

    2008-01-01

    Fuel cells are expected to play a major role in the future energy supply, especially polymer electrolyte membrane fuel cells could become an integral part in future cars. Reduction of degradation of fuel cell performance while keeping fuel cell cost under control is the key for an introduction into mass markets.

  6. Growing beyond oil delivering our energy future - a report card on the Canadian renewable fuels industry

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-11-15

    The Canadian Renewable Fuels Association (CRFA) has overseen dynamic growth in the domestic biofuels sector. It is guided by the following principles: support for advanced biofuels; building a sustainable industry; building a competitive industry; fiscal responsibility; feedstock neutrality; investment in technology; quality and safety. The development of renewable fuels is also supported by the federal and provincial governments. Some solid results have been achieved in the industry sector: job creation and economic growth; reductions in GHG emissions; agricultural benefits; rural development and forestry benefits; energy security/diversity; and social benefits to Canadians. The federal government has been clear in its commitment to implement the 2% renewable diesel requirement in 2011. The CRFA and member organizations look forward to a continuing dialogue with federal and provincial policy makers to realize our full potential in the clean energy economy of tomorrow.

  7. Biochemical fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Weidlich, E.; Richter, G.

    1978-03-30

    Until now, biochemical fuel cells have suffered a reduction of capacity in operation due to omission of internal contact between the electrodes and the diaphragm. This disadvantage is remedied by the invention by connecting the oxygen electrode with a rigid electrode frame and providing means for pressing the fuel electrode to the diaphragm and the diaphragm to the oxygen electrode on the side of the fuel electrode away from the diaphragm. The means of exerting pressure can be metal springs, but preferably elastomers, particularly silicon rubber, or springy gels are used.

  8. Life cycle assessment of camelina oil derived biodiesel and jet fuel in the Canadian Prairies.

    Science.gov (United States)

    Li, Xue; Mupondwa, Edmund

    2014-05-15

    This study evaluated the environmental impact of biodiesel and hydroprocessed renewable jet fuel derived from camelina oil in terms of global warming potential, human health, ecosystem quality, and energy resource consumption. The life cycle inventory is based on production activities in the Canadian Prairies and encompasses activities ranging from agricultural production to oil extraction and fuel conversion. The system expansion method is used in this study to avoid allocation and to credit input energy to co-products associated with the products displaced in the market during camelina oil extraction and fuel processing. This is the preferred allocation method for LCA analysis in the context of most renewable and sustainable energy programs. The results show that greenhouse gas (GHG) emissions from 1 MJ of camelina derived biodiesel ranged from 7.61 to 24.72 g CO2 equivalent and 3.06 to 31.01 kg CO2/MJ equivalent for camelina HRJ fuel. Non-renewable energy consumption for camelina biodiesel ranged from 0.40 to 0.67 MJ/MJ; HRJ fuel ranged from -0.13 to 0.52 MJ/MJ. Camelina oil as a feedstock for fuel production accounted for the highest contribution to overall environmental performance, demonstrating the importance of reducing environmental burdens during the agricultural production process. Attaining higher seed yield would dramatically lower environmental impacts associated with camelina seed, oil, and fuel production. The lower GHG emissions and energy consumption associated with camelina in comparison with other oilseed derived fuel and petroleum fuel make camelina derived fuel from Canadian Prairies environmentally attractive.

  9. Development of PEM fuel cell technology at international fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Wheeler, D.J.

    1996-04-01

    The PEM technology has not developed to the level of phosphoric acid fuel cells. Several factors have held the technology development back such as high membrane cost, sensitivity of PEM fuel cells to low level of carbon monoxide impurities, the requirement to maintain full humidification of the cell, and the need to pressurize the fuel cell in order to achieve the performance targets. International Fuel Cells has identified a hydrogen fueled PEM fuel cell concept that leverages recent research advances to overcome major economic and technical obstacles.

  10. Proton exchange membrane fuel cells

    CERN Document Server

    Qi, Zhigang

    2013-01-01

    Preface Proton Exchange Membrane Fuel CellsFuel CellsTypes of Fuel CellsAdvantages of Fuel CellsProton Exchange Membrane Fuel CellsMembraneCatalystCatalyst LayerGas Diffusion MediumMicroporous LayerMembrane Electrode AssemblyPlateSingle CellStackSystemCell Voltage Monitoring Module (CVM)Fuel Supply Module (FSM)Air Supply Module (ASM)Exhaust Management Module (EMM)Heat Management Module (HMM)Water Management Module (WMM)Internal Power Supply Module (IPM)Power Conditioning Module (PCM)Communications Module (COM)Controls Module (CM)SummaryThermodynamics and KineticsTheoretical EfficiencyVoltagePo

  11. Fuel cells in transportation

    Energy Technology Data Exchange (ETDEWEB)

    Erdmann, G. [Technische Univ., Berlin (Germany); Hoehlein, B. [Research Center Juelich (Germany)

    1996-12-01

    A promising new power source for electric drive systems is the fuel cell technology with hydrogen as energy input. The worldwide fuel cell development concentrates on basic research efforts aiming at improving this new technology and at developing applications that might reach market maturity in the very near future. Due to the progress achieved, the interest is now steadily turning to the development of overall systems such as demonstration plants for different purposes: electricity generation, drive systems for road vehicles, ships and railroads. This paper does not present results concerning the market potential of fuel cells in transportation but rather addresses some questions and reflections that are subject to further research of both engineers and economists. Some joint effort of this research will be conducted under the umbrella of the IEA Implementing Agreement 026 - Annex X, but there is a lot more to be done in this challenging but also promising fields. (EG) 18 refs.

  12. Fuel cell engineering

    CERN Document Server

    Sundmacher

    2012-01-01

    Fuel cells are attractive electrochemical energy converters featuring potentially very high thermodynamic efficiency factors. The focus of this volume of Advances in Chemical Engineering is on quantitative approaches, particularly based on chemical engineering principles, to analyze, control and optimize the steady state and dynamic behavior of low and high temperature fuel cells (PEMFC, DMFC, SOFC) to be applied in mobile and stationary systems. * Updates and informs the reader on the latest research findings using original reviews * Written by leading industry experts and scholars * Review

  13. Direct Methanol Fuel Cell, DMFC

    OpenAIRE

    Amornpitoksuk, P.

    2003-01-01

    Direct Methanol Fuel Cell, DMFC is a kind of fuel cell using methanol as a fuel for electric producing. Methanol is low cost chemical substance and it is less harmful than that of hydrogen fuel. From these reasons it can be commercial product. The electrocatalytic reaction of methanol fuel uses Pt-Ru metals as the most efficient catalyst. In addition, the property of membrane and system designation are also effect to the fuel cell efficient. Because of low power of methanol fuel cell therefor...

  14. Solid Oxide Fuel Cell

    DEFF Research Database (Denmark)

    2010-01-01

    The solid oxide fuel cell comprising a metallic support material, an active anode layer consisting of a good hydrocarbon cracking catalyst, an electrolyte layer, an active cathode layer, and a transition layer consisting of preferably a mixture of LSM and a ferrite to the cathode current collector...

  15. Fuel cell generator

    International Nuclear Information System (INIS)

    A high temperature solid electrolyte fuel cell generator comprising a housing means defining a plurality of chambers including a generator chamber and a combustion products chamber, a porous barrier separating the generator and combustion product chambers, a plurality of elongated annular fuel cells each having a closed end and an open end with the open ends disposed within the combustion product chamber, the cells extending from the open end through the porous barrier and into the generator chamber, a conduit for each cell, each conduit extending into a portion of each cell disposed within the generator chamber, each conduit having means for discharging a first gaseous reactant within each fuel cell, exhaust means for exhausting the combustion product chamber, manifolding means for supplying the first gaseous reactant to the conduits with the manifolding means disposed within the combustion product chamber between the porous barrier and the exhaust means and the manifolding means further comprising support and bypass means for providing support of the manifolding means within the housing while allowing combustion products from the first and a second gaseous reactant to flow past the manifolding means to the exhaust means, and means for flowing the second gaseous reactant into the generator chamber

  16. Organic fuel cells and fuel cell conducting sheets

    Science.gov (United States)

    Masel, Richard I.; Ha, Su; Adams, Brian

    2007-10-16

    A passive direct organic fuel cell includes an organic fuel solution and is operative to produce at least 15 mW/cm.sup.2 when operating at room temperature. In additional aspects of the invention, fuel cells can include a gas remover configured to promote circulation of an organic fuel solution when gas passes through the solution, a modified carbon cloth, one or more sealants, and a replaceable fuel cartridge.

  17. Microbial studies in the Canadian nuclear fuel waste management program

    International Nuclear Information System (INIS)

    Atomic Energy of Canada Limited (AECL) has developed a concept for permanent geological disposal of nuclear fuel waste in Canada. An accelerated program was initiated in 1991 to address and quantify the potential effects of microbial action on the integrity of the disposal concept's multiple barrier system. This microbial program focuses on answering specific questions in areas such as the survival of bacteria in compacted clay-based buffer materials under relevant radiation and desiccation conditions; mobility of microbes in compacted buffer materials; the potential for microbially-influenced corrosion of containers; microbial gas production in backfill material; introduction of nutrients as a result of vault excavation and operation; the presence and activity of microbes in deep granitic groundwaters; and the effects of biofilms on radionuclide migration in the geosphere. This paper summarizes the current research activities at AECL in these areas. (author)

  18. Fuel Cell Technical Team Roadmap

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-06-01

    The Fuel Cell Technical Team promotes the development of a fuel cell power system for an automotive powertrain that meets the U.S. DRIVE Partnership (United States Driving Research and Innovation for Vehicle efficiency and Energy sustainability) goals.

  19. Fuel cell based hybrid systems

    OpenAIRE

    Davat, B.; Astier, S.; Bethoux, O.; CANDUSSO,D; Coquery, G.; DE-BERNARDINIS, A; DRUART, F; Francois, M; GARCIA ARREGUI, F; Harel, F.

    2009-01-01

    This paper presents different works which are currently developed in the field of fuel cell hybrid systems indifferent public laboratories in France. These works are presented in three sections corresponding to: 1. Hybrid fuel cell/battery or supercapacitor power sources; 2. Fuel cell multistack power sources; 3. Fuel cell in hybrid power systems for distributed generation. The presented works combine simulation and experimental results.

  20. Fuel cell report to congress

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2003-02-28

    This report describes the status of fuel cells for Congressional committees. It focuses on the technical and economic barriers to the use of fuel cells in transportation, portable power, stationary, and distributed power generation applications, and describes the need for public-private cooperative programs to demonstrate the use of fuel cells in commercial-scale applications by 2012. (Department of Energy, February 2003).

  1. Fuel Cell Handbook, Fourth Edition

    Energy Technology Data Exchange (ETDEWEB)

    Stauffer, D.B; Hirschenhofer, J.H.; Klett, M.G.; Engleman, R.R.

    1998-11-01

    Robust progress has been made in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in January 1994. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultra high efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 6 describe the four major fuel cell types and their performance based on cell operating conditions. The section on polymer electrolyte membrane fuel cells has been added to reflect their emergence as a significant fuel cell technology. Phosphoric acid, molten carbonate, and solid oxide fuel cell technology description sections have been updated from the previous edition. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 7, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 8 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

  2. Fuel Cell Handbook, Fifth Edition

    Energy Technology Data Exchange (ETDEWEB)

    Energy and Environmental Solutions

    2000-10-31

    Progress continues in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in November 1998. Uppermost, polymer electrolyte fuel cells, molten carbonate fuel cells, and solid oxide fuel cells have been demonstrated at commercial size in power plants. The previously demonstrated phosphoric acid fuel cells have entered the marketplace with more than 220 power plants delivered. Highlighting this commercial entry, the phosphoric acid power plant fleet has demonstrated 95+% availability and several units have passed 40,000 hours of operation. One unit has operated over 49,000 hours. Early expectations of very low emissions and relatively high efficiencies have been met in power plants with each type of fuel cell. Fuel flexibility has been demonstrated using natural gas, propane, landfill gas, anaerobic digester gas, military logistic fuels, and coal gas, greatly expanding market opportunities. Transportation markets worldwide have shown remarkable interest in fuel cells; nearly every major vehicle manufacturer in the U.S., Europe, and the Far East is supporting development. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultrahigh efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 8 describe the six major fuel cell types and their performance based on cell operating conditions. Alkaline and intermediate solid state fuel cells were added to this edition of the Handbook. New information indicates that manufacturers have stayed

  3. Fuel cell generator with fuel electrodes that control on-cell fuel reformation

    Science.gov (United States)

    Ruka, Roswell J.; Basel, Richard A.; Zhang, Gong

    2011-10-25

    A fuel cell for a fuel cell generator including a housing including a gas flow path for receiving a fuel from a fuel source and directing the fuel across the fuel cell. The fuel cell includes an elongate member including opposing first and second ends and defining an interior cathode portion and an exterior anode portion. The interior cathode portion includes an electrode in contact with an oxidant flow path. The exterior anode portion includes an electrode in contact with the fuel in the gas flow path. The anode portion includes a catalyst material for effecting fuel reformation along the fuel cell between the opposing ends. A fuel reformation control layer is applied over the catalyst material for reducing a rate of fuel reformation on the fuel cell. The control layer effects a variable reformation rate along the length of the fuel cell.

  4. Operando fuel cell spectroscopy

    Science.gov (United States)

    Kendrick, Ian Michael

    The active state of a catalyst only exists during catalysis (1) provided the motivation for developing operando spectroscopic techniques. A polymer electrolyte membrane fuel cell (PEMFC) was designed to interface with commercially available instruments for acquisition of infrared spectra of the catalytic surface of the membrane electrode assembly (MEA) during normal operation. This technique has provided insight of the complex processes occurring at the electrode surface. Nafion, the solid electrolyte used in most modern-day polymer electrolyte membrane fuel cells (PEMFC), serves many purposes in fuel cell operation. However, there is little known of the interface between Nafion and the electrode surface. Previous studies of complex Stark tuning curves of carbon monoxide on the surface of a platinum electrode were attributed the co-adsorption of bisulfite ions originating from the 0.5M H2SO4 electrolyte used in the study(2). Similar tuning curves obtained on a fuel cell MEA despite the absence of supplemental electrolytes suggest the adsorption of Nafion onto platinum (3). The correlation of spectra obtained using attenuated total reflectance spectroscopy (ATR) and polarization modulated IR reflection-absorption spectroscopy (PM-IRRAS) to a theoretical spectrum generated using density functional theory (DFT) lead to development of a model of Nafion and platinum interaction which identified participation of the SO3- and CF3 groups in Nafion adsorption. The use of ethanol as a fuel stream in proton exchange membrane fuel cells provides a promising alternative to methanol. Relative to methanol, ethanol has a greater energy density, lower toxicity and can be made from the fermentation of biomass(4). Operando IR spectroscopy was used to study the oxidation pathway of ethanol and Stark tuning behavior of carbon monoxide on Pt, Ru, and PtRu electrodes. Potential dependent products such as acetaldehyde, acetic acid and carbon monoxide are identified as well as previously

  5. Fuel cell system with interconnect

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Zhien; Goettler, Richard; Delaforce, Philip Mark

    2016-03-08

    The present invention includes a fuel cell system having an interconnect that reduces or eliminates diffusion (leakage) of fuel and oxidant by providing an increased densification, by forming the interconnect as a ceramic/metal composite.

  6. Dynamic behaviour of fuel cells

    OpenAIRE

    Weydahl, Helge

    2006-01-01

    This thesis addresses the dynamic behaviour of proton exchange membrane fuel cells (PEMFCs) and alkaline fuel cells (AFCs). For successful implementation in automotive vehicles and other applications with rapidly varying power demands, the dynamic behaviour of the fuel cell is critical. Knowledge of the load variation requirements as well as the response time of the cell at load change is essential for identifying the need for and design of a buffer system.The transient response of a PEMFC su...

  7. Second interim assessment of the Canadian concept for nuclear fuel waste disposal. Volume 3

    International Nuclear Information System (INIS)

    The nuclear fuel waste disposal concept chosen for development and assessment in Canada involves the isolation of corrosion-resistant containers of waste in a vault located deep in plutonic rock. As the concept and the assessment tools are developed, periodic assessments are performed to permit evaluation of the methodology and provide feedback to those developing the concept. The ultimate goal of these assessments is to predict what impact the disposal system would have on man and the environment if the concept were implemented. The second such assessment was completed in 1984 and is documented in the Second Interim Assessment of the Canadian Concept for Nuclear Fuel Waste Disposal - Volumes 1-4. This, the third volume of the report, summarizes the pre-closure environmental and safety assessments completed by Ontario Hydro for Atomic Energy of Canada Limited. The preliminary results and their sigificance are discussed. 85 refs

  8. Natural analogs in support of the Canadian concept for nuclear fuel waste disposal

    International Nuclear Information System (INIS)

    The assessment of the long-term safety and performance of the Canadian concept for disposal of nuclear fuel waste is a unique and challenging undertaking, because the predictions have to be made for time periods in the range of 104 to 106 a into the future. The data used for the assessment modelling is in large part based on observations from short-term laboratory and field experiments. Natural analogs can provide a reference for the safety assessment, providing both useful data and a qualitative illustration of the interaction of processes and materials in complex natural systems. This report reviews the available natural analog information used in support of the Canadian concept, with particular emphasis on the disposal of used CANDU (CANada Deuterium Uranium) fuel. The introduction gives a definition of natural analogs and an overview of the various types of analogs and analog studies. The review is broken down into sections pertaining to the major components of the disposal system: the vault, the geosphere and the biosphere. Specific examples are given for each. In addition, a section deals with several comprehensive natural systems that contain a number of features and processes similar to the disposal concept and that are under study by a number of countries as part of their waste management programs. (author). 224 refs., 11 tabs., 2 figs

  9. ARPA advanced fuel cell development

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, L.H.

    1995-08-01

    Fuel cell technology is currently being developed at the Advanced Research Projects Agency (ARPA) for several Department of Defense applications where its inherent advantages such as environmental compatibility, high efficiency, and low noise and vibration are overwhelmingly important. These applications range from man-portable power systems of only a few watts output (e.g., for microclimate cooling and as direct battery replacements) to multimegawatt fixed base systems. The ultimate goal of the ARPA program is to develop an efficient, low-temperature fuel cell power system that operates directly on a military logistics fuel (e.g., DF-2 or JP-8). The absence of a fuel reformer will reduce the size, weight, cost, and complexity of such a unit as well as increase its reliability. In order to reach this goal, ARPA is taking a two-fold, intermediate time-frame approach to: (1) develop a viable, low-temperature proton exchange membrane (PEM) fuel cell that operates directly on a simple hydrocarbon fuel (e.g., methanol or trimethoxymethane) and (2) demonstrate a thermally integrated fuel processor/fuel cell power system operating on a military logistics fuel. This latter program involves solid oxide (SOFC), molten carbonate (MCFC), and phosphoric acid (PAFC) fuel cell technologies and concentrates on the development of efficient fuel processors, impurity scrubbers, and systems integration. A complementary program to develop high performance, light weight H{sub 2}/air PEM and SOFC fuel cell stacks is also underway. Several recent successes of these programs will be highlighted.

  10. Hybrid Fuel Cell Technology Overview

    Energy Technology Data Exchange (ETDEWEB)

    None available

    2001-05-31

    For the purpose of this STI product and unless otherwise stated, hybrid fuel cell systems are power generation systems in which a high temperature fuel cell is combined with another power generating technology. The resulting system exhibits a synergism in which the combination performs with an efficiency far greater than can be provided by either system alone. Hybrid fuel cell designs under development include fuel cell with gas turbine, fuel cell with reciprocating (piston) engine, and designs that combine different fuel cell technologies. Hybrid systems have been extensively analyzed and studied over the past five years by the Department of Energy (DOE), industry, and others. These efforts have revealed that this combination is capable of providing remarkably high efficiencies. This attribute, combined with an inherent low level of pollutant emission, suggests that hybrid systems are likely to serve as the next generation of advanced power generation systems.

  11. Unitized regenerative fuel cell system

    Science.gov (United States)

    Burke, Kenneth A. (Inventor)

    2008-01-01

    A Unitized Regenerative Fuel Cell system uses heat pipes to convey waste heat from the fuel cell stack to the reactant storage tanks. The storage tanks act as heat sinks/sources and as passive radiators of the waste heat from the fuel cell stack. During charge up, i.e., the electrolytic process, gases are conveyed to the reactant storage tanks by way of tubes that include dryers. Reactant gases moving through the dryers give up energy to the cold tanks, causing water vapor in with the gases to condense and freeze on the internal surfaces of the dryer. During operation in its fuel cell mode, the heat pipes convey waste heat from the fuel cell stack to the respective reactant storage tanks, thereby heating them such that the reactant gases, as they pass though the respective dryers on their way to the fuel cell stacks retrieve the water previously removed.

  12. PEM fuel cell diagnostic tools

    CERN Document Server

    Wang, Haijiang

    2011-01-01

    PEM Fuel Cell Diagnostic Tools presents various tools for diagnosing PEM fuel cells and stacks, including in situ and ex situ diagnostic tools, electrochemical techniques, and physical/chemical methods. The text outlines the principles, experimental implementation, data processing, and application of each technique, along with its capabilities and weaknesses. The book covers many diagnostics employed in the characterization and determination of fuel cell performance. It discusses commonly used conventional tools, such as cyclic voltammetry, electrochemical impedance spectroscopy, scanning elec

  13. SOME ASPECTS OF FUEL CELLS

    OpenAIRE

    Войтко, Ігор Іванович; Зубрій, О.О.; Козлова, О.М.

    2012-01-01

    This work provides literature data to improve solid oxide fuel cells by a direct methane fuel cell and electrode settings of uninterrupted space. The possibility of electrochemical generators SOFC as synthesis gas from natural gas. We describe progress in the creation of new nanomaterials for components SOFC and modern technologies for their manufacture. Briefly described features of the operation and use molten carbonate fuel cells and their accessories and SOFC in cogeneration system (three...

  14. Molten carbonate fuel cell separator

    Science.gov (United States)

    Nickols, Richard C.

    1986-09-02

    In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

  15. CLIMATE CHANGE FUEL CELL PROGRAM

    Energy Technology Data Exchange (ETDEWEB)

    Steven A. Gabrielle

    2004-12-03

    This report discusses the first year of operation of a fuel cell power plant located at the Sheraton Edison Hotel, Edison, New Jersey. PPL EnergyPlus, LLC installed the plant under a contract with the Starwood Hotels & Resorts Worldwide, Inc. A DFC{reg_sign}300 fuel cell, manufactured by FuelCell Energy, Inc. of Danbury, CT was selected for the project. The fuel cell successfully operated from June 2003 to May 2004. This report discusses the performance of the plant during this period.

  16. Fuel cells problems and solutions

    CERN Document Server

    Bagotsky, Vladimir S

    2012-01-01

    The comprehensive, accessible introduction to fuel cells, their applications, and the challenges they pose Fuel cells-electrochemical energy devices that produce electricity and heat-present a significant opportunity for cleaner, easier, and more practical energy. However, the excitement over fuel cells within the research community has led to such rapid innovation and development that it can be difficult for those not intimately familiar with the science involved to figure out exactly how this new technology can be used. Fuel Cells: Problems and Solutions, Second Edition addresses this i

  17. Comparative analysis of US and Canadian transit ridership response to rising fuel prices

    Energy Technology Data Exchange (ETDEWEB)

    Haire, A.R.; Machemeehl, R.B. [Texas Univ., Austin, TX (United States)

    2007-07-01

    Since worldwide gasoline prices have risen significantly over the last three years, several transit agencies have indicated that fuel price growth is the major impetus to increased transit ridership. This paper presented the results of a research project that builds upon previous research conducted in 2006 which found high correlation between fuel price and transit ridership in several historically auto-based United States cities. This comparative research attempted to determine whether a similar pattern of fuel cost-driven mode choice could be observed in three Canadian cities. The selected cities, Calgary, Ottawa, and Vancouver, were chosen based on their relative levels of auto-orientation and the extent and variety of transit services offered. It was concluded that although ridership and fuel prices grew in all three cities, the rates of growth do not correspond and correlation is unlikely. Reasons for this inconsistency with patterns in American cities may involve higher-density city layouts and commute distances. 3 refs., 3 tabs., 7 figs.

  18. Fuel Cell Powered Lift Truck

    Energy Technology Data Exchange (ETDEWEB)

    Moulden, Steve [Sysco Food Service, Houston, TX (United States)

    2015-08-20

    This project, entitled “Recovery Act: Fuel Cell-Powered Lift Truck Sysco (Houston) Fleet Deployment”, was in response to DOE funding opportunity announcement DE-PS36-08GO98009, Topic 7B, which promotes the deployment of fuel cell powered material handling equipment in large, multi-shift distribution centers. This project promoted large-volume commercialdeployments and helped to create a market pull for material handling equipment (MHE) powered fuel cell systems. Specific outcomes and benefits involved the proliferation of fuel cell systems in 5-to 20-kW lift trucks at a high-profile, real-world site that demonstrated the benefits of fuel cell technology and served as a focal point for other nascent customers. The project allowed for the creation of expertise in providing service and support for MHE fuel cell powered systems, growth of existing product manufacturing expertise, and promoted existing fuel cell system and component companies. The project also stimulated other MHE fleet conversions helping to speed the adoption of fuel cell systems and hydrogen fueling technology. This document also contains the lessons learned during the project in order to communicate the successes and difficulties experienced, which could potentially assist others planning similar projects.

  19. 1986 fuel cell seminar: Program and abstracts

    Energy Technology Data Exchange (ETDEWEB)

    None

    1986-10-01

    Ninety nine brief papers are arranged under the following session headings: gas industry's 40 kw program, solid oxide fuel cell technology, phosphoric acid fuel cell technology, molten carbonate fuel cell technology, phosphoric acid fuel cell systems, power plants technology, fuel cell power plant designs, unconventional fuels, fuel cell application and economic assessments, and plans for commerical development. The papers are processed separately for the data base. (DLC)

  20. Materials for high-temperature fuel cells

    CERN Document Server

    Jiang, San Ping; Lu, Max

    2013-01-01

    There are a large number of books available on fuel cells; however, the majority are on specific types of fuel cells such as solid oxide fuel cells, proton exchange membrane fuel cells, or on specific technical aspects of fuel cells, e.g., the system or stack engineering. Thus, there is a need for a book focused on materials requirements in fuel cells. Key Materials in High-Temperature Fuel Cells is a concise source of the most important and key materials and catalysts in high-temperature fuel cells with emphasis on the most important solid oxide fuel cells. A related book will cover key mater

  1. Materials for low-temperature fuel cells

    CERN Document Server

    Ladewig, Bradley; Yan, Yushan; Lu, Max

    2014-01-01

    There are a large number of books available on fuel cells; however, the majority are on specific types of fuel cells such as solid oxide fuel cells, proton exchange membrane fuel cells, or on specific technical aspects of fuel cells, e.g., the system or stack engineering. Thus, there is a need for a book focused on materials requirements in fuel cells. Key Materials in Low-Temperature Fuel Cells is a concise source of the most important and key materials and catalysts in low-temperature fuel cells. A related book will cover key materials in high-temperature fuel cells. The two books form part

  2. Enzymatic fuel cells: Recent progress

    International Nuclear Information System (INIS)

    There is an increasing interest in replacing non-selective metal catalysts, currently used in low temperature fuel cells, with enzymes as catalysts. Specific oxidation of fuel and oxidant by enzymes as catalysts yields enzymatic fuel cells. If the catalysts can be immobilised at otherwise inert anode and cathode materials, this specificity of catalysis obviates the requirement for fuel cell casings and membranes permitting fuel cell configurations amenable to miniaturisation to be adopted. Such configurations have been proposed for application to niche areas of power generation: powering remotely located portable electronic devices, or implanted biomedical devices, for example. We focus in this review on recent efforts to improve electron transfer between the enzymes and electrodes, in the presence or absence of mediators, with most attention on research aimed at implantable or semi-implantable enzymatic fuel cells that harvest the body's own fuel, glucose, coupled to oxygen reduction, to provide power to biomedical devices. This ambitious goal is still at an early stage, with device power output and stability representing major challenges. A comparison of performance of enzymatic fuel cell electrodes and assembled fuel cells is attempted in this review, but is hampered in general by lack of availability of, and conformity to, standardised testing and reporting protocols for electrodes and cells. We therefore highlight reports that focus on this requirement. Ultimately, insight gained from enzymatic fuel cell research will lead to improved biomimetics of enzyme catalysts for fuel cell electrodes. These biomimetics will mimic enzyme catalytic sites and the structural flexibility of the protein assembly surrounding the catalytic site.

  3. PEM fuel cell degradation

    Energy Technology Data Exchange (ETDEWEB)

    Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory

    2010-01-01

    The durability of PEM fuel cells is a major barrier to the commercialization of these systems for stationary and transportation power applications. While significant progress has been made in understanding degradation mechanisms and improving materials, further improvements in durability are required to meet commercialization targets. Catalyst and electrode durability remains a primary degradation mode, with much work reported on understanding how the catalyst and electrode structure degrades. Accelerated Stress Tests (ASTs) are used to rapidly evaluate component degradation, however the results are sometimes easy, and other times difficult to correlate. Tests that were developed to accelerate degradation of single components are shown to also affect other component's degradation modes. Non-ideal examples of this include ASTs examining catalyst degradation performances losses due to catalyst degradation do not always well correlate with catalyst surface area and also lead to losses in mass transport.

  4. Commercializing fuel cells: managing risks

    Science.gov (United States)

    Bos, Peter B.

    Commercialization of fuel cells, like any other product, entails both financial and technical risks. Most of the fuel cell literature has focussed upon technical risks, however, the most significant risks during commercialization may well be associated with the financial funding requirements of this process. Successful commercialization requires an integrated management of these risks. Like any developing technology, fuel cells face the typical 'Catch-22' of commercialization: "to enter the market, the production costs must come down, however, to lower these costs, the cumulative production must be greatly increased, i.e. significant market penetration must occur". Unless explicit steps are taken to address this dilemma, fuel cell commercialization will remain slow and require large subsidies for market entry. To successfully address this commercialization dilemma, it is necessary to follow a market-driven commercialization strategy that identifies high-value entry markets while minimizing the financial and technical risks of market entry. The financial and technical risks of fuel cell commercialization are minimized, both for vendors and end-users, with the initial market entry of small-scale systems into high-value stationary applications. Small-scale systems, in the order of 1-40 kW, benefit from economies of production — as opposed to economies to scale — to attain rapid cost reductions from production learning and continuous technological innovation. These capital costs reductions will accelerate their commercialization through market pull as the fuel cell systems become progressively more viable, starting with various high-value stationary and, eventually, for high-volume mobile applications. To facilitate market penetration via market pull, fuel cell systems must meet market-derived economic and technical specifications and be compatible with existing market and fuels infrastructures. Compatibility with the fuels infrastructure is facilitated by a

  5. Fuel cells: Hydrogen induced insulation

    Science.gov (United States)

    Zhou, Wei; Shao, Zongping

    2016-06-01

    Coupling high ionic and low electronic conductivity in the electrolyte of low-temperature solid-oxide fuel cells remains a challenge. Now, the electronic conductivity of a perovskite electrolyte, which has high proton conductivity, is shown to be heavily suppressed when exposed to hydrogen, leading to high fuel cell performance.

  6. Microbial issues pertaining to the Canadian concept for the disposal of nuclear fuel waste

    International Nuclear Information System (INIS)

    AECL Research is developing a concept for the permanent disposal of nuclear fuel waste in plutonic rock of the Canadian Shield. The Federal Environmental Assessment Review Panel has issued a set of guidelines to be used by AECL Research in preparing an Environmental Impact Statement (EIS) for this concept. These guidelines require that the EIS address a number of microbiological factors and their potential to affect the integrity of the multiple barrier system on which the disposal concept is based. This report formulates a number of views and positions on microbiological factors that could influence the performance of a disposal vault in plutonic rock. Microbiological factors discussed include the presence and survival of microbes, biofilms, corrosion, biodegradation (of emplaced materials), gas production, geochemical changes, radionuclides migration, colloid formation, mutation, pathogens and methylation. Not all issues can be fully resolved with the current state of knowledge. Studies being performed to underscore and strengthen current knowledge are briefly discussed. (author). 92 refs., 1 tab

  7. Progress in welding studies for Canadian nuclear fuel waste disposal containers

    International Nuclear Information System (INIS)

    This report describes the progress in the development of closure-welding technology for Canadian nuclear fuel waste disposal containers. Titanium, copper and Inconel 625 are being investigated as candidate materials for fabrication of these containers. Gas-tungsten-arc welding, gas metal-arc-welding, resistance-heated diffusion bonding and electron beam welding have been evaluated as candidate closure welding processes. Characteristic weldment properties, relative merits of welding techniques, suitable weld joint configurations and fit-up tolerances, and welding parameter control ranges have been identified for various container designs. Furthermore, the automation requirements for candidate welding processes have been assessed. Progress in the development of a computer-controlled remote gas-shielded arc welding system is described

  8. Biological fuel cells and their applications

    OpenAIRE

    Shukla, AK; Suresh, P; Berchmans, S; Rajendran, A.

    2004-01-01

    One type of genuine fuel cell that does hold promise in the long-term is the biological fuel cell. Unlike conventional fuel cells, which employ hydrogen, ethanol and methanol as fuel, biological fuel cells use organic products produced by metabolic processes or use organic electron donors utilized in the growth processes as fuels for current generation. A distinctive feature of biological fuel cells is that the electrode reactions are controlled by biocatalysts, i.e. the biological redox-reac...

  9. Potential effects of climatic change on radiological doses from disposal of Canadian nuclear fuel waste

    International Nuclear Information System (INIS)

    The environmental assessment of deep geologic disposal of Canadian nuclear fuel waste considers many processes that could affect radionuclide transport to humans over thousands of years. Climatic change is an important feature that will occur over these long times. Glaciation will likely occur within the next 100,000 years over much of Canada, and its impact on radiological doses has been assessed previously. In the present study, we investigate the potential effect of short- term climatic change, usually associated with global warming caused by increases in atmospheric trace gases. We study the main biosphere transport pathways causing a radiological dose to humans from 129I, which is the most important radionuclide in disposal of Canadian used nuclear fuel. Irrigation of a garden with contaminated well water is the main pathway and it can be affected by changes in temperature and precipitation. A cold, wet climate decreases the need for irrigation, and this decreases the radiological dose. A drastic climatic change, such as an increase in temperature from 10 to 20 degrees C and decrease in precipitation from 0.3 to 0.2 m during the growing season, is estimated to increase the dose by a factor of four. This is a relatively small change compared to the range of doses that arise from the variability and uncertainty in many of the parameters used in the environmental assessment models. Therefore, it is likely that the results of probabilistic dose assessment models can include the consequences of short-term climatic change. 39 refs., 3 figs

  10. PEM Fuel Cells - Fundamentals, Modeling and Applications

    Directory of Open Access Journals (Sweden)

    Maher A.R. Sadiq Al-Baghdadi

    2013-01-01

    Full Text Available Part I: Fundamentals Chapter 1: Introduction. Chapter 2: PEM fuel cell thermodynamics, electrochemistry, and performance. Chapter 3: PEM fuel cell components. Chapter 4: PEM fuel cell failure modes. Part II: Modeling and Simulation Chapter 5: PEM fuel cell models based on semi-empirical simulation. Chapter 6: PEM fuel cell models based on computational fluid dynamics. Part III: Applications Chapter 7: PEM fuel cell system design and applications.

  11. PEM Fuel Cells - Fundamentals, Modeling and Applications

    OpenAIRE

    Maher A.R. Sadiq Al-Baghdadi

    2013-01-01

    Part I: Fundamentals Chapter 1: Introduction. Chapter 2: PEM fuel cell thermodynamics, electrochemistry, and performance. Chapter 3: PEM fuel cell components. Chapter 4: PEM fuel cell failure modes. Part II: Modeling and Simulation Chapter 5: PEM fuel cell models based on semi-empirical simulation. Chapter 6: PEM fuel cell models based on computational fluid dynamics. Part III: Applications Chapter 7: PEM fuel cell system design and applications.

  12. PEM fuel cell failure mode analysis

    CERN Document Server

    Wang, Haijiang

    2011-01-01

    PEM Fuel Cell Failure Mode Analysis presents a systematic analysis of PEM fuel cell durability and failure modes. It provides readers with a fundamental understanding of insufficient fuel cell durability, identification of failure modes and failure mechanisms of PEM fuel cells, fuel cell component degradation testing, and mitigation strategies against degradation. The first several chapters of the book examine the degradation of various fuel cell components, including degradation mechanisms, the effects of operating conditions, mitigation strategies, and testing protocols. The book then discus

  13. Fuel-Cell Water Separator

    Science.gov (United States)

    Burke, Kenneth Alan; Fisher, Caleb; Newman, Paul

    2010-01-01

    The main product of a typical fuel cell is water, and many fuel-cell configurations use the flow of excess gases (i.e., gases not consumed by the reaction) to drive the resultant water out of the cell. This two-phase mixture then exits through an exhaust port where the two fluids must again be separated to prevent the fuel cell from flooding and to facilitate the reutilization of both fluids. The Glenn Research Center (GRC) has designed, built, and tested an innovative fuel-cell water separator that not only removes liquid water from a fuel cell s exhaust ports, but does so with no moving parts or other power-consuming components. Instead it employs the potential and kinetic energies already present in the moving exhaust flow. In addition, the geometry of the separator is explicitly intended to be integrated into a fuel-cell stack, providing a direct mate with the fuel cell s existing flow ports. The separator is also fully scalable, allowing it to accommodate a wide range of water removal requirements. Multiple separators can simply be "stacked" in series or parallel to adapt to the water production/removal rate. GRC s separator accomplishes the task of water removal by coupling a high aspect- ratio flow chamber with a highly hydrophilic, polyethersulfone membrane. The hydrophilic membrane readily absorbs and transports the liquid water away from the mixture while simultaneously resisting gas penetration. The expansive flow path maximizes the interaction of the water particles with the membrane while minimizing the overall gas flow restriction. In essence, each fluid takes its corresponding path of least resistance, and the two fluids are effectively separated. The GRC fuel-cell water separator has a broad range of applications, including commercial hydrogen-air fuel cells currently being considered for power generation in automobiles.

  14. Fuel cell with internal flow control

    Science.gov (United States)

    Haltiner, Jr., Karl J.; Venkiteswaran, Arun

    2012-06-12

    A fuel cell stack is provided with a plurality of fuel cell cassettes where each fuel cell cassette has a fuel cell with an anode and cathode. The fuel cell stack includes an anode supply chimney for supplying fuel to the anode of each fuel cell cassette, an anode return chimney for removing anode exhaust from the anode of each fuel cell cassette, a cathode supply chimney for supplying oxidant to the cathode of each fuel cell cassette, and a cathode return chimney for removing cathode exhaust from the cathode of each fuel cell cassette. A first fuel cell cassette includes a flow control member disposed between the anode supply chimney and the anode return chimney or between the cathode supply chimney and the cathode return chimney such that the flow control member provides a flow restriction different from at least one other fuel cell cassettes.

  15. Climate Change Fuel Cell Program

    Energy Technology Data Exchange (ETDEWEB)

    Paul Belard

    2006-09-21

    Verizon is presently operating the largest Distributed Generation Fuel Cell project in the USA. Situated in Long Island, NY, the power plant is composed of seven (7) fuel cells operating in parallel with the Utility grid from the Long Island Power Authority (LIPA). Each fuel cell has an output of 200 kW, for a total of 1.4 mW generated from the on-site plant. The remaining power to meet the facility demand is purchased from LIPA. The fuel cell plant is utilized as a co-generation system. A by-product of the fuel cell electric generation process is high temperature water. The heat content of this water is recovered from the fuel cells and used to drive two absorption chillers in the summer and a steam generator in the winter. Cost savings from the operations of the fuel cells are forecasted to be in excess of $250,000 per year. Annual NOx emissions reductions are equivalent to removing 1020 motor vehicles from roadways. Further, approximately 5.45 million metric tons (5 millions tons) of CO2 per year will not be generated as a result of this clean power generation. The project was partially financed with grants from the New York State Energy R&D Authority (NYSERDA) and from Federal Government Departments of Defense and Energy.

  16. Romanian-Canadian joint program for qualification of FCN as a CANDU fuel supplier

    International Nuclear Information System (INIS)

    RENEL (Romania Power Authority), the co-ordinator of Romanian Nuclear Program, have decided to improve, starting 1990 the existing capability to produce CANDU nuclear fuel at FCN Pitesti. The objective of the program was defined with AAC (AECL - ANSALDO Consortium) for the qualification of FCN fuel plant according to Canadian Z299.2 standard. The Qualification Program was performed under AAC Work Order C-003. The co-ordination was assumed by AECL, as overall Design Authority. ZPI (Zircatec Precision Industries Inc., Canada), were designated to supply technical assistance, equipments and know how where necessary. After a preliminary verification of the FCN fuel plant, including the processes and system investigation, performed under AECL and ZPI assistance, the Qualification Program was defined in all details. The upgrading of documentation on all aspects required by Z299.2 was performed. Few processes needed to be reconsidered and equipment was delivered by ZPI or other suppliers. This includes mainly welding equipments and special inspection equipments. Health Physics was practically fully reconsidered. New equipment and practice were adapted to provide adequate control on health conditions. Every manufacturing and inspection process was checked to determine their performance during a Qualification Run based on acceptance criteria which have been established in the Qualification Plan. Manufacturing Demonstration Run was an important step to prove that all plant functions have been accomplished during the fabrication of 200 fuel bundles. These bundles have been fully accepted and 66 of them have been loaded in the first charge of Unit 1 Cemavoda NPS. The surveillance and audit actions made by AECL and ZPI during this period confirmed the FCN capability to operate an adequate system meeting the to required quality assurance standard. The very open attitude of AECL, Zircatec and FCN staff have stimulated the progress of the project and a successful achievement of the

  17. Fuel Cell Research

    Energy Technology Data Exchange (ETDEWEB)

    Weber, Peter M. [Brown University

    2014-03-30

    Executive Summary In conjunction with the Brown Energy Initiative, research Projects selected for the fuel cell research grant were selected on the following criteria: ➢ They should be fundamental research that has the potential to significantly impact the nation’s energy infrastructure. ➢ They should be scientifically exciting and sound. ➢ They should synthesize new materials, lead to greater insights, explore new phenomena, or design new devices or processes that are of relevance to solving the energy problems. ➢ They involve top-caliper senior scientists with a record of accomplishment, or junior faculty with outstanding promise of achievement. ➢ They should promise to yield at least preliminary results within the given funding period, which would warrant further research development. ➢ They should fit into the overall mission of the Brown Energy Initiative, and the investigators should contribute as partners to an intellectually stimulating environment focused on energy science. Based on these criteria, fourteen faculty across three disciplines (Chemistry, Physics and Engineering) and the Charles Stark Draper Laboratory were selected to participate in this effort.1 In total, there were 30 people supported, at some level, on these projects. This report highlights the findings and research outcomes of the participating researchers.

  18. Fuel Cell Research

    Energy Technology Data Exchange (ETDEWEB)

    Weber, Peter M. [Brown University

    2014-03-30

    Executive Summary In conjunction with the Brown Energy Initiative, research Projects selected for the fuel cell research grant were selected on the following criteria: They should be fundamental research that has the potential to significantly impact the nation’s energy infrastructure. They should be scientifically exciting and sound. They should synthesize new materials, lead to greater insights, explore new phenomena, or design new devices or processes that are of relevance to solving the energy problems. They involve top-caliper senior scientists with a record of accomplishment, or junior faculty with outstanding promise of achievement. They should promise to yield at least preliminary results within the given funding period, which would warrant further research development. They should fit into the overall mission of the Brown Energy Initiative, and the investigators should contribute as partners to an intellectually stimulating environment focused on energy science. Based on these criteria, fourteen faculty across three disciplines (Chemistry, Physics and Engineering) and the Charles Stark Draper Laboratory were selected to participate in this effort.1 In total, there were 30 people supported, at some level, on these projects. This report highlights the findings and research outcomes of the participating researchers.

  19. Chip integrated fuel cell accumulator

    Science.gov (United States)

    Frank, M.; Erdler, G.; Frerichs, H.-P.; Müller, C.; Reinecke, H.

    A unique new design of a chip integrated fuel cell accumulator is presented. The system combines an electrolyser and a self-breathing polymer electrolyte membrane (PEM) fuel cell with integrated palladium hydrogen storage on a silicon substrate. Outstanding advantages of this assembly are the fuel cell with integrated hydrogen storage, the possibility of refuelling it by electrolysis and the opportunity of simply refilling the electrolyte by adding water. By applying an electrical current, wiring the palladium hydrogen storage as cathode and the counter-electrode as anode, the electrolyser produces hydrogen at the palladium surface and oxygen at the electrolyser cell anode. The generated hydrogen is absorbed by the palladium electrode and the hydrogen storage is refilled consequently enabling the fuel cell to function.

  20. The potential for microbial life in a Canadian high-level nuclear fuel waste disposal vault

    International Nuclear Information System (INIS)

    Recent studies have concluded that microbial contamination of a nuclear fuel waste disposal vault is inevitable. Factors that will affect the development of substantial population of micro-organisms include: physiological tolerance of microbes; fluid movement in a vault; availability of nutrients; and availability of energy sources. It is difficult to resolve whether microbial growth will either positively or negatively affect the performance of a vault. One of the necessary steps towards ultimately answering this question is to assess the potential for microbial growth in a disposal vault, based on a nutrient and energy budget. This report gives a quantitative (but conservative) inventory of nutrients and potential energy sources present in a Canadian nuclear fuel waste vault, which hypothetically could support the growth of micro-organisms. Maximum population densities are calculated based on these inventories and assuming that all conditions for microbial growth are optimal, although this will certainly not be the case. Laboratory studies under the vault-relevant conditions are being performed to put realistic boundaries on the calculated numbers. Initial results from these studies, combined with data from a natural analogue site indicate that the calculated population densities could be overestimated by four to five orders of magnitude. Limited data show no effect of the presence of microbes on the transport of Tc, I, and Sr in backfill sand columns. Additional work is needed to address transport effects on buffer and backfill clay columns

  1. The Canadian approach to site characterization for a nuclear fuel waste disposal vault

    International Nuclear Information System (INIS)

    The Canadian Nuclear Fuel Waste Management Program is assessing the concept of deep disposal of nuclear fuel waste in plutonic rock. One of the main objectives of the geoscience research programme is to develop and evaluate methods for characterizing potential disposal sites to assess their long term safety. Demonstrations of the successful use of site characterization methods and the successful application of predictive models to real situations are an important component of the programme. A comparison of structural interpretations, based on surface mapping and gravity modelling, with the results from cored boreholes in a gabbroic pluton showed that there was reasonable agreement and that inferences about gross characteristics were not changed substantially when detailed mapping followed reconnaissance mapping. A more complex comparison of groundwater response in the volume of rock surrounding the shaft of Canada's Underground Research Laboratory, as simulated by a three-dimensional groundwater flow model, with measured responses at 171 measuring points during shaft construction showed a generally good agreement. The rate of groundwater inflow to the shaft was overpredicted by a factor of three. (author)

  2. Water reactive hydrogen fuel cell power system

    Science.gov (United States)

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-01-21

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  3. Fuel cell technology for prototype logistic fuel cell mobile systems

    Energy Technology Data Exchange (ETDEWEB)

    Sederquist, R.A.; Garow, J.

    1995-08-01

    Under the aegis of the Advanced Research Project Agency`s family of programs to develop advanced technology for dual use applications, International Fuel Cells Corporation (IFC) is conducting a 39 month program to develop an innovative system concept for DoD Mobile Electric Power (MEP) applications. The concept is to integrate two technologies, the phosphoric acid fuel cell (PAFC) with an auto-thermal reformer (ATR), into an efficient fuel cell power plant of nominally 100-kilowatt rating which operates on logistic fuels (JP-8). The ATR fuel processor is the key to meeting requirements for MEP (including weight, volume, reliability, maintainability, efficiency, and especially operation on logistic fuels); most of the effort is devoted to ATR development. An integrated demonstration test unit culminates the program and displays the benefits of the fuel cell system, relative to the standard 100-kilowatt MEP diesel engine generator set. A successful test provides the basis for proceeding toward deployment. This paper describes the results of the first twelve months of activity during which specific program aims have remained firm.

  4. Metrology for Fuel Cell Manufacturing

    Energy Technology Data Exchange (ETDEWEB)

    Stocker, Michael [National Inst. of Standards and Technology, Gaithersburg, MD (United States); Stanfield, Eric [National Inst. of Standards and Technology, Gaithersburg, MD (United States)

    2015-02-04

    The project was divided into three subprojects. The first subproject is Fuel Cell Manufacturing Variability and Its Impact on Performance. The objective was to determine if flow field channel dimensional variability has an impact on fuel cell performance. The second subproject is Non-contact Sensor Evaluation for Bipolar Plate Manufacturing Process Control and Smart Assembly of Fuel Cell Stacks. The objective was to enable cost reduction in the manufacture of fuel cell plates by providing a rapid non-contact measurement system for in-line process control. The third subproject is Optical Scatterfield Metrology for Online Catalyst Coating Inspection of PEM Soft Goods. The objective was to evaluate the suitability of Optical Scatterfield Microscopy as a viable measurement tool for in situ process control of catalyst coatings.

  5. Ammonia as a Suitable Fuel for Fuel Cells

    OpenAIRE

    Lan, Rong; Tao, Shanwen

    2014-01-01

    Ammonia, an important basic chemical, is produced at a scale of 150 million tons per year. Half of hydrogen produced in chemical industry is used for ammonia production. Ammonia containing 17.5 wt% hydrogen is an ideal carbon-free fuel for fuel cells. Compared to hydrogen, ammonia has many advantages. In this mini-review, the suitability of ammonia as fuel for fuel cells, the development of different types of fuel cells using ammonia as the fuel and the potential applications of ammonia fuel ...

  6. Low contaminant formic acid fuel for direct liquid fuel cell

    Science.gov (United States)

    Masel, Richard I.; Zhu, Yimin; Kahn, Zakia; Man, Malcolm

    2009-11-17

    A low contaminant formic acid fuel is especially suited toward use in a direct organic liquid fuel cell. A fuel of the invention provides high power output that is maintained for a substantial time and the fuel is substantially non-flammable. Specific contaminants and contaminant levels have been identified as being deleterious to the performance of a formic acid fuel in a fuel cell, and embodiments of the invention provide low contaminant fuels that have improved performance compared to known commercial bulk grade and commercial purified grade formic acid fuels. Preferred embodiment fuels (and fuel cells containing such fuels) including low levels of a combination of key contaminants, including acetic acid, methyl formate, and methanol.

  7. 2009 Fuel Cell Market Report, November 2010

    Energy Technology Data Exchange (ETDEWEB)

    2010-11-01

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of fuel is supplied. Moreover, fuel cells do not burn fuel, making the process quiet, pollution-free and two to three times more efficient than combustion. Fuel cell systems can be a truly zero-emission source of electricity, if the hydrogen is produced from non-polluting sources. Global concerns about climate change, energy security, and air pollution are driving demand for fuel cell technology. More than 630 companies and laboratories in the United States are investing $1 billion a year in fuel cells or fuel cell component technologies. This report provides an overview of trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance. It also provides snapshots of select fuel cell companies, including general.

  8. 14 CFR 31.45 - Fuel cells.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Fuel cells. 31.45 Section 31.45 Aeronautics... STANDARDS: MANNED FREE BALLOONS Design Construction § 31.45 Fuel cells. If fuel cells are used, the fuel cells, their attachments, and related supporting structure must be shown by tests to be capable...

  9. Canadian hydrogen safety program

    International Nuclear Information System (INIS)

    The Canadian hydrogen safety program (CHSP) is a project initiative of the Codes and Standards Working Group of the Canadian transportation fuel cell alliance (CTFCA) that represents industry, academia, government, and regulators. The Program rationale, structure and contents contribute to acceptance of the products, services and systems of the Canadian Hydrogen Industry into the Canadian hydrogen stakeholder community. It facilitates trade through fair insurance policies and rates, effective and efficient regulatory approval procedures and accommodation of the interests of the general public. The Program integrates a consistent quantitative risk assessment methodology with experimental (destructive and non-destructive) failure rates and consequence-of-release data for key hydrogen components and systems into risk assessment of commercial application scenarios. Its current and past six projects include Intelligent Virtual Hydrogen Filling Station (IVHFS), Hydrogen clearance distances, comparative quantitative risk comparison of hydrogen and compressed natural gas (CNG) refuelling options; computational fluid dynamics (CFD) modeling validation, calibration and enhancement; enhancement of frequency and probability analysis, and Consequence analysis of key component failures of hydrogen systems; and fuel cell oxidant outlet hydrogen sensor project. The Program projects are tightly linked with the content of the International Energy Agency (IEA) Task 19 Hydrogen Safety. (author)

  10. 1990 fuel cell seminar: Program and abstracts

    Energy Technology Data Exchange (ETDEWEB)

    1990-12-31

    This volume contains author prepared short resumes of the presentations at the 1990 Fuel Cell Seminar held November 25-28, 1990 in Phoenix, Arizona. Contained herein are 134 short descriptions organized into topic areas entitled An Environmental Overview, Transportation Applications, Technology Advancements for Molten Carbonate Fuel Cells, Technology Advancements for Solid Fuel Cells, Component Technologies and Systems Analysis, Stationary Power Applications, Marine and Space Applications, Technology Advancements for Acid Type Fuel Cells, and Technology Advancement for Solid Oxide Fuel Cells.

  11. System Studies of Fuel Cell Power Plants

    OpenAIRE

    Kivisaari, Timo

    2001-01-01

    This thesis concerns system studies of power plants wheredifferent types of fuel cells accomplish most of the energyconversion. Ever since William Grove observed the fuel cell effect inthe late 1830s fuel cells have been the subject or more or lessintense research and development. Especially in the USA theseactivities intensified during the second part of the 1950s,resulting in the development of the fuel cells used in theApollo-program. Swedish fuel cell activities started in themid-1960s, w...

  12. Automotive Fuel Processor Development and Demonstration with Fuel Cell Systems

    Energy Technology Data Exchange (ETDEWEB)

    Nuvera Fuel Cells

    2005-04-15

    The potential for fuel cell systems to improve energy efficiency and reduce emissions over conventional power systems has generated significant interest in fuel cell technologies. While fuel cells are being investigated for use in many applications such as stationary power generation and small portable devices, transportation applications present some unique challenges for fuel cell technology. Due to their lower operating temperature and non-brittle materials, most transportation work is focusing on fuel cells using proton exchange membrane (PEM) technology. Since PEM fuel cells are fueled by hydrogen, major obstacles to their widespread use are the lack of an available hydrogen fueling infrastructure and hydrogen's relatively low energy storage density, which leads to a much lower driving range than conventional vehicles. One potential solution to the hydrogen infrastructure and storage density issues is to convert a conventional fuel such as gasoline into hydrogen onboard the vehicle using a fuel processor. Figure 2 shows that gasoline stores roughly 7 times more energy per volume than pressurized hydrogen gas at 700 bar and 4 times more than liquid hydrogen. If integrated properly, the fuel processor/fuel cell system would also be more efficient than traditional engines and would give a fuel economy benefit while hydrogen storage and distribution issues are being investigated. Widespread implementation of fuel processor/fuel cell systems requires improvements in several aspects of the technology, including size, startup time, transient response time, and cost. In addition, the ability to operate on a number of hydrocarbon fuels that are available through the existing infrastructure is a key enabler for commercializing these systems. In this program, Nuvera Fuel Cells collaborated with the Department of Energy (DOE) to develop efficient, low-emission, multi-fuel processors for transportation applications. Nuvera's focus was on (1) developing fuel

  13. Scenario analysis for the postclosure assessment of the Canadian concept for nuclear fuel waste disposal

    International Nuclear Information System (INIS)

    AECL Research has developed and evaluated a concept for disposal of Canada's nuclear fuel waste involving deep underground disposal of the waste in intrusive igneous rock of the Canadian Shield. The postclosure assessment of this concept focusses on the effects on human health and the environment due to potential contaminant releases into the biosphere after the disposal vault is closed. Both radiotoxic and chemically toxic contaminants are considered. One of the steps in the postclosure assessment process is scenario analysis. Scenario analysis identifies factors that could affect the performance of the disposal system and groups these factors into scenarios that require detailed quantitative evaluation. This report documents a systematic procedure for scenario analysis that was developed for the postclosure assessment and then applied to the study of a hypothetical disposal system. The application leads to a comprehensive list of factors and a set of scenarios that require further quantitative study. The application also identifies a number of other factors and potential scenarios that would not contribute significantly to environmental and safety impacts for the hypothetical disposal system. (author). 46 refs., 3 tabs., 3 figs., 2 appendices

  14. Development of alkaline fuel cells.

    Energy Technology Data Exchange (ETDEWEB)

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari [Colorado School of Mines, Golden, CO; Horan, James L. [Colorado School of Mines, Golden, CO; Caire, Benjamin R. [Colorado School of Mines, Golden, CO; Ziegler, Zachary C. [Colorado School of Mines, Golden, CO; Herring, Andrew M. [Colorado School of Mines, Golden, CO; Yang, Yuan [Colorado School of Mines, Golden, CO; Zuo, Xiaobing [Argonne National Laboratory, Argonne, IL; Robson, Michael H. [University of New Mexico, Albuquerque, NM; Artyushkova, Kateryna [University of New Mexico, Albuquerque, NM; Patterson, Wendy [University of New Mexico, Albuquerque, NM; Atanassov, Plamen Borissov [University of New Mexico, Albuquerque, NM

    2013-09-01

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassov's research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herring's group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  15. Development of alkaline fuel cells.

    Energy Technology Data Exchange (ETDEWEB)

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari; Horan, James L.; Caire, Benjamin R.; Ziegler, Zachary C.; Herring, Andrew M.; Yang, Yuan; Zuo, Xiaobing; Robson, Michael H.; Artyushkova, Kateryna; Patterson, Wendy; Atanassov, Plamen Borissov

    2013-09-01

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassovs research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herrings group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  16. Carbon-based Fuel Cell

    Energy Technology Data Exchange (ETDEWEB)

    Steven S. C. Chuang

    2005-08-31

    The direct use of coal in the solid oxide fuel cell to generate electricity is an innovative concept for power generation. The C-fuel cell (carbon-based fuel cell) could offer significant advantages: (1) minimization of NOx emissions due to its operating temperature range of 700-1000 C, (2) high overall efficiency because of the direct conversion of coal to CO{sub 2}, and (3) the production of a nearly pure CO{sub 2} exhaust stream for the direct CO{sub 2} sequestration. The objective of this project is to determine the technical feasibility of using a highly active anode catalyst in a solid oxide fuel for the direct electrochemical oxidation of coal to produce electricity. Results of this study showed that the electric power generation from Ohio No 5 coal (Lower Kittanning) Seam, Mahoning County, is higher than those of coal gas and pure methane on a solid oxide fuel cell assembly with a promoted metal anode catalyst at 950 C. Further study is needed to test the long term activity, selectivity, and stability of anode catalysts.

  17. Microfluidic fuel cells and batteries

    CERN Document Server

    Kjeang, Erik

    2014-01-01

    Microfluidic fuel cells and batteries represent a special type of electrochemical power generators that can be miniaturized and integrated in a microfluidic chip. Summarizing the initial ten years of research and development in this emerging field, this SpringerBrief is the first book dedicated to microfluidic fuel cell and battery technology for electrochemical energy conversion and storage. Written at a critical juncture, where strategically applied research is urgently required to seize impending technology opportunities for commercial, analytical, and educational utility, the intention is

  18. Corrugated Membrane Fuel Cell Structures

    Energy Technology Data Exchange (ETDEWEB)

    Grot, Stephen [President, Ion Power Inc.

    2013-09-30

    One of the most challenging aspects of traditional PEM fuel cell stacks is the difficulty achieving the platinum catalyst utilization target of 0.2 gPt/kWe set forth by the DOE. Good catalyst utilization can be achieved with state-of-the-art catalyst coated membranes (CCM) when low catalyst loadings (<0.3 mg/cm2) are used at a low current. However, when low platinum loadings are used, the peak power density is lower than conventional loadings, requiring a larger total active area and a larger bipolar plate. This results in a lower overall stack power density not meeting the DOE target. By corrugating the fuel cell membrane electrode structure, Ion Power?s goal is to realize both the Pt utilization targets as well as the power density targets of the DOE. This will be achieved by demonstrating a fuel cell single cell (50 cm2) with a twofold increase in the membrane active area over the geometric area of the cell by corrugating the MEA structure. The corrugating structure must be able to demonstrate the target properties of < 10 mOhm-cm2 electrical resistance at > 20 psi compressive strength over the active area, in combination with offering at least 80% of power density that can be achieved by using the same MEA in a flat plate structure. Corrugated membrane fuel cell structures also have the potential to meet DOE power density targets by essentially packaging more membrane area into the same fuel cell volume as compared to conventional stack constructions.

  19. Fuel Cell Seminar, 1992: Program and abstracts

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-31

    This year`s theme, ``Fuel Cells: Realizing the Potential,`` focuses on progress being made toward commercial manufacture and use of fuel cell products. Fuel cell power plants are competing for market share in some applications and demonstrations of market entry power plants are proceeding for additional applications. Development activity on fuel cells for transportation is also increasing; fuel cell products have potential in energy and transportation industries, with very favorable environmental impacts. This Seminar has the purpose of fostering communication by providing a forum for the international community interested in development, application, and business opportunities related fuel cells. Over 190 technical papers are included, the majority being processed for the data base.

  20. Direct methanol feed fuel cell and system

    Science.gov (United States)

    Surampudi, Subbarao (Inventor); Frank, Harvey A. (Inventor); Narayanan, Sekharipuram R. (Inventor); Chun, William (Inventor); Jeffries-Nakamura, Barbara (Inventor); Kindler, Andrew (Inventor); Halpert, Gerald (Inventor)

    2009-01-01

    Improvements to non acid methanol fuel cells include new formulations for materials. The platinum and ruthenium are more exactly mixed together. Different materials are substituted for these materials. The backing material for the fuel cell electrode is specially treated to improve its characteristics. A special sputtered electrode is formed which is extremely porous. The fuel cell system also comprises a fuel supplying part including a meter which meters an amount of fuel which is used by the fuel cell, and controls the supply of fuel based on said metering.

  1. Carbon fuel particles used in direct carbon conversion fuel cells

    Science.gov (United States)

    Cooper, John F.; Cherepy, Nerine

    2012-10-09

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  2. Fuel cell development for transportation: Catalyst development

    Energy Technology Data Exchange (ETDEWEB)

    Doddapaneni, N. [Sandia National Lab., Albuquerque, NM (United States)

    1996-04-01

    Fuel cells are being considered as alternate power sources for transportation and stationary applications. With proton exchange membrane (PEM) fuel cells the fuel crossover to cathodes causes severe thermal management and cell voltage drop due to oxidation of fuel at the platinized cathodes. The main goal of this project was to design, synthesize, and evaluate stable and inexpensive transition metal macrocyclic catalysts for the reduction of oxygen and be electrochemically inert towards anode fuels such as hydrogen and methanol.

  3. Polymer Materials for Fuel Cell Membranes :Sulfonated Poly(ether sulfone) for Universal Fuel Cell Operations

    Institute of Scientific and Technical Information of China (English)

    Hyoung-Juhn Kim

    2005-01-01

    @@ 1Introduction Polymer electrolyte fuel cells (PEFCs) have been spotlighted because they are clean and highly efficient power generation system. Proton exchange membrane fuel cells (PEMFCs), which use reformate gases or pure H2 for a fuel, have been employed for automotives and residential usages. Also, liquid-feed fuel cells such as direct methanol fuel cell (DMFC) and direct formic acid fuel cell (DFAFC) were studied for portable power generation.

  4. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    OpenAIRE

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    Proton Exchange Membrane fuel cell (PEMFC) technology for use in fuel cell vehicles and other applications has been intensively developed in recent decades. Besides the fuel cell stack, air and fuel control and thermal and water management are major challenges in the development of the fuel cell for vehicle applications. The air supply system can have a major impact on overall system efficiency. In this paper a fuel cell system model for optimizing system operating conditions was developed wh...

  5. Fuel-Cell Drivers Wanted

    Science.gov (United States)

    Clark, Todd; Jones, Rick

    2004-01-01

    While the political climate seems favorable for the development of fuel-cell vehicles for personal transportation, the market's demand may not be so favorable. Nonetheless, middle level students will be the next generation of drivers and voters, and they need to be able to make informed decisions regarding the nation's energy and transportation…

  6. Corrosion resistant PEM fuel cell

    Science.gov (United States)

    Fronk, Matthew Howard; Borup, Rodney Lynn; Hulett, Jay S.; Brady, Brian K.; Cunningham, Kevin M.

    2002-01-01

    A PEM fuel cell having electrical contact elements comprising a corrosion-susceptible substrate metal coated with an electrically conductive, corrosion-resistant polymer containing a plurality of electrically conductive, corrosion-resistant filler particles. The substrate may have an oxidizable metal first layer (e.g., stainless steel) underlying the polymer coating.

  7. 2007 Fuel Cell Technologies Market Report

    Energy Technology Data Exchange (ETDEWEB)

    McMurphy, K.

    2009-07-01

    The fuel cell industry, which has experienced continued increases in sales, is an emerging clean energy industry with the potential for significant growth in the stationary, portable, and transportation sectors. Fuel cells produce electricity in a highly efficient electrochemical process from a variety of fuels with low to zero emissions. This report describes data compiled in 2008 on trends in the fuel cell industry for 2007 with some comparison to two previous years. The report begins with a discussion of worldwide trends in units shipped and financing for the fuel cell industry for 2007. It continues by focusing on the North American and U.S. markets. After providing this industry-wide overview, the report identifies trends for each of the major fuel cell applications -- stationary power, portable power, and transportation -- including data on the range of fuel cell technologies -- polymer electrolyte membrane fuel cell (PEMFC), solid oxide fuel cell (SOFC), alkaline fuel cell (AFC), molten carbonate fuel cell (MCFC), phosphoric acid fuel cell (PAFC), and direct-methanol fuel cell (DMFC) -- used for these applications.

  8. Fuel Cell/Electrochemical Cell Voltage Monitor

    Science.gov (United States)

    Vasquez, Arturo

    2012-01-01

    A concept has been developed for a new fuel cell individual-cell-voltage monitor that can be directly connected to a multi-cell fuel cell stack for direct substack power provisioning. It can also provide voltage isolation for applications in high-voltage fuel cell stacks. The technology consists of basic modules, each with an 8- to 16-cell input electrical measurement connection port. For each basic module, a power input connection would be provided for direct connection to a sub-stack of fuel cells in series within the larger stack. This power connection would allow for module power to be available in the range of 9-15 volts DC. The relatively low voltage differences that the module would encounter from the input electrical measurement connection port, coupled with the fact that the module's operating power is supplied by the same substack voltage input (and so will be at similar voltage), provides for elimination of high-commonmode voltage issues within each module. Within each module, there would be options for analog-to-digital conversion and data transfer schemes. Each module would also include a data-output/communication port. Each of these ports would be required to be either non-electrical (e.g., optically isolated) or electrically isolated. This is necessary to account for the fact that the plurality of modules attached to the stack will normally be at a range of voltages approaching the full range of the fuel cell stack operating voltages. A communications/ data bus could interface with the several basic modules. Options have been identified for command inputs from the spacecraft vehicle controller, and for output-status/data feeds to the vehicle.

  9. Innovative Fuel Cell Health Monitoring IC Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Energy storage devices, including fuel cells, are needed to enable future robotic and human exploration missions. Historically, the reliability of the fuel cells...

  10. Interconnection of bundled solid oxide fuel cells

    Science.gov (United States)

    Brown, Michael; Bessette, II, Norman F; Litka, Anthony F; Schmidt, Douglas S

    2014-01-14

    A system and method for electrically interconnecting a plurality of fuel cells to provide dense packing of the fuel cells. Each one of the plurality of fuel cells has a plurality of discrete electrical connection points along an outer surface. Electrical connections are made directly between the discrete electrical connection points of adjacent fuel cells so that the fuel cells can be packed more densely. Fuel cells have at least one outer electrode and at least one discrete interconnection to an inner electrode, wherein the outer electrode is one of a cathode and and anode and wherein the inner electrode is the other of the cathode and the anode. In tubular solid oxide fuel cells the discrete electrical connection points are spaced along the length of the fuel cell.

  11. Solid Oxide Fuel Cell Experimental Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — NETL’s Solid Oxide Fuel Cell Experimental Laboratory in Morgantown, WV, gives researchers access to models and simulations that predict how solid oxide fuel cells...

  12. HIGH TEMPERATURE POLYMER FUEL CELLS

    DEFF Research Database (Denmark)

    Jensen, Jens Oluf; Qingfeng, Li; He, Ronghuan;

    2003-01-01

    This paper will report recent results from our group on polymer fuel cells (PEMFC) based on the temperature resistant polymer polybenzimidazole (PBI), which allow working temperatures up to 200°C. The membrane has a water drag number near zero and need no water management at all. The high working...... temperature allows for utilization of the excess heat for fuel processing. Moreover, it provides an excellent CO tolerance of several percent, and the system needs no purification of hydrogen from a reformer. Continuous service for over 6 months at 150°C has been demonstrated....

  13. Strongly correlated perovskite fuel cells.

    Science.gov (United States)

    Zhou, You; Guan, Xiaofei; Zhou, Hua; Ramadoss, Koushik; Adam, Suhare; Liu, Huajun; Lee, Sungsik; Shi, Jian; Tsuchiya, Masaru; Fong, Dillon D; Ramanathan, Shriram

    2016-05-16

    Fuel cells convert chemical energy directly into electrical energy with high efficiencies and environmental benefits, as compared with traditional heat engines. Yttria-stabilized zirconia is perhaps the material with the most potential as an electrolyte in solid oxide fuel cells (SOFCs), owing to its stability and near-unity ionic transference number. Although there exist materials with superior ionic conductivity, they are often limited by their ability to suppress electronic leakage when exposed to the reducing environment at the fuel interface. Such electronic leakage reduces fuel cell power output and the associated chemo-mechanical stresses can also lead to catastrophic fracture of electrolyte membranes. Here we depart from traditional electrolyte design that relies on cation substitution to sustain ionic conduction. Instead, we use a perovskite nickelate as an electrolyte with high initial ionic and electronic conductivity. Since many such oxides are also correlated electron systems, we can suppress the electronic conduction through a filling-controlled Mott transition induced by spontaneous hydrogen incorporation. Using such a nickelate as the electrolyte in free-standing membrane geometry, we demonstrate a low-temperature micro-fabricated SOFC with high performance. The ionic conductivity of the nickelate perovskite is comparable to the best-performing solid electrolytes in the same temperature range, with a very low activation energy. The results present a design strategy for high-performance materials exhibiting emergent properties arising from strong electron correlations.

  14. Strongly correlated perovskite fuel cells

    Science.gov (United States)

    Zhou, You; Guan, Xiaofei; Zhou, Hua; Ramadoss, Koushik; Adam, Suhare; Liu, Huajun; Lee, Sungsik; Shi, Jian; Tsuchiya, Masaru; Fong, Dillon D.; Ramanathan, Shriram

    2016-06-01

    Fuel cells convert chemical energy directly into electrical energy with high efficiencies and environmental benefits, as compared with traditional heat engines. Yttria-stabilized zirconia is perhaps the material with the most potential as an electrolyte in solid oxide fuel cells (SOFCs), owing to its stability and near-unity ionic transference number. Although there exist materials with superior ionic conductivity, they are often limited by their ability to suppress electronic leakage when exposed to the reducing environment at the fuel interface. Such electronic leakage reduces fuel cell power output and the associated chemo-mechanical stresses can also lead to catastrophic fracture of electrolyte membranes. Here we depart from traditional electrolyte design that relies on cation substitution to sustain ionic conduction. Instead, we use a perovskite nickelate as an electrolyte with high initial ionic and electronic conductivity. Since many such oxides are also correlated electron systems, we can suppress the electronic conduction through a filling-controlled Mott transition induced by spontaneous hydrogen incorporation. Using such a nickelate as the electrolyte in free-standing membrane geometry, we demonstrate a low-temperature micro-fabricated SOFC with high performance. The ionic conductivity of the nickelate perovskite is comparable to the best-performing solid electrolytes in the same temperature range, with a very low activation energy. The results present a design strategy for high-performance materials exhibiting emergent properties arising from strong electron correlations.

  15. Development of portable fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Nakatou, K.; Sumi, S.; Nishizawa, N. [Sanyo Electric Co., Ltd., Osaka (Japan)

    1996-12-31

    Sanyo Electric has been concentrating on developing a marketable portable fuel cell using phosphoric acid fuel cells (PAFC). Due to the fact that this power source uses PAFC that operate at low temperature around 100{degrees} C, they are easier to handle compared to conventional fuel cells that operate at around 200{degrees} C , they can also be expected to provide extended reliable operation because corrosion of the electrode material and deterioration of the electrode catalyst are almost completely nonexistent. This power source is meant to be used independently and stored at room temperature. When it is started up, it generates electricity itself using its internal load to raise the temperature. As a result, the phosphoric acid (the electolyte) absorbs the reaction water when the temperature starts to be raised (around room temperature). At the same time the concentration and volume of the phosphoric acid changes, which may adversely affect the life time of the cell. We have studied means for starting, operating PAFC stack using methods that can simply evaluate changes in the concentration of the electrolyte in the stack with the aim of improving and extending cell life and report on them in this paper.

  16. Fuel and control for an integrated fuel cell system

    International Nuclear Information System (INIS)

    The OS/IES (On-Site Integrated Energy System) comprises a phosphoric acid fuel cell driven total energy package that produces electrical energy in the form of AC power (when the DC voltage from the fuel cell is inverted), and heat energy in the form of hot water. The fuel cell prefers a fuel high in hydrogen therefore it becomes necessary to convert as much of the fuel, i.e. natural or pipeline gas into hydrogen as possible using a fuel reformer. Fuel reforming is an endothermic process and in this case waste energy in the form of ''spent'' fuel from the fuel cell is used to supply heat to the reformer. Fuel cell waste heat is also used to raise the steam used in the reforming process. The OS/IES fuel processing system comprises five interrelated subsystems. Each subsystem is controlled independently through a microprocessor but a change in any subsystem function could have an effect on the operation of any or several other subsystems. Thus the controller receives a signal indicating electrical demand and proceeds to balance the subsystems as well as the fuel and air flow to each of the fuel cells. The controller also responds to a number of alarm signals and is capable of starting and stopping the complete OS/IES. It is assisted by a tie to the utility line which can dispense electrical energy for startup or instantaneous load following and accept excess generated power in case of load loss. In this paper we review fuel cell operation and requirements, the components and interactions that make up the reformer system, and the microprocessor control required to integrate the OS/IES

  17. FUEL CELL ENERGY RECOVERY FROM LANDFILL GAS

    Science.gov (United States)

    International Fuel Cells Corporation is conducting a US Environmental Protection Agency (EPA) sponsored program to demonstrate energy recovery from landfill gas using a commercial phosphoric acid fuel cell power plant. The US EPA is interested in fuel cells for this application b...

  18. Fuel cell/gas turbine integration

    Energy Technology Data Exchange (ETDEWEB)

    Knickerbocker, T. [Allison Engine Company, Indianapolis, IN (United States)

    1995-10-19

    The Allison Engine Company`s very high efficiency fuel cell/advanced turbine power cycle program is discussed. The power cycle has the following advantages: high system efficiency potential, reduced emissions inherent to fuel cells, unmanned operation(no boiler) particularly suited for distributed power, and existing product line matches fuel cell operating environment. Cost effectiveness, estimates, and projections are given.

  19. Fuel quality issues in stationary fuel cell systems.

    Energy Technology Data Exchange (ETDEWEB)

    Papadias, D.; Ahmed, S.; Kumar, R. (Chemical Sciences and Engineering Division)

    2012-02-07

    Fuel cell systems are being deployed in stationary applications for the generation of electricity, heat, and hydrogen. These systems use a variety of fuel cell types, ranging from the low temperature polymer electrolyte fuel cell (PEFC) to the high temperature solid oxide fuel cell (SOFC). Depending on the application and location, these systems are being designed to operate on reformate or syngas produced from various fuels that include natural gas, biogas, coal gas, etc. All of these fuels contain species that can potentially damage the fuel cell anode or other unit operations and processes that precede the fuel cell stack. These detrimental effects include loss in performance or durability, and attenuating these effects requires additional components to reduce the impurity concentrations to tolerable levels, if not eliminate the impurity entirely. These impurity management components increase the complexity of the fuel cell system, and they add to the system's capital and operating costs (such as regeneration, replacement and disposal of spent material and maintenance). This project reviewed the public domain information available on the impurities encountered in stationary fuel cell systems, and the effects of the impurities on the fuel cells. A database has been set up that classifies the impurities, especially in renewable fuels, such as landfill gas and anaerobic digester gas. It documents the known deleterious effects on fuel cells, and the maximum allowable concentrations of select impurities suggested by manufacturers and researchers. The literature review helped to identify the impurity removal strategies that are available, and their effectiveness, capacity, and cost. A generic model of a stationary fuel-cell based power plant operating on digester and landfill gas has been developed; it includes a gas processing unit, followed by a fuel cell system. The model includes the key impurity removal steps to enable predictions of impurity breakthrough

  20. Microbially influenced corrosion of copper nuclear fuel waste containers in a Canadian disposal vault

    International Nuclear Information System (INIS)

    An assessment of the potential for microbially influenced corrosion (MIC) of copper nuclear fuel waste containers in a Canadian disposal vault is presented. The assessment is based on a consideration of the microbial activity within a disposal vault, the reported cases of MIC of Cu alloys in the literature and the known corrosion behaviour of Cu. Because of the critical role of biofilms in the reported cases of MIC, their formation and properties are discussed in detail. Next, the literature on the MIC of Cu alloys is briefly reviewed. The various MIC mechanisms proposed are critically discussed and the implications for the corrosion of Cu containers considered. In the majority of literature cases, MIC depends on alternating aerated and deaerated environments, with accelerated corrosion being observed when fresh aerated water replaces stagnant water, e.g., the MIC of Cu-Ni heat exchangers in polluted seawater and the microbially influenced pitting of Cu water pipes. Finally, because of the predominance of corrosion by sulphate-reducing bacteria (SRB) in the MIC literature, the abiotic behaviour of Cu alloys in sulphide solutions is also reviewed. The effect of the evolving environment in a disposal vault on the extent and location of microbial activity is discussed. Biofilm formation on the container surface is considered unlikely throughout the container lifetime, but especially initially when the environmental conditions will be particularly aggressive. Microbial activity in areas of the vault away from the container is possible, however. Corrosion of the container could then occur if microbial metabolic by-products diffuse to the container surface. Sulphide, produced by the action of SRB are considered to be the most likely cause of container corrosion. It is concluded that the only likely form of MIC of Cu containers will result from sulphide produced by SRB diffusing to the container surface. A modelling procedure for predicting the extent of corrosion is

  1. DIGESTER GAS - FUEL CELL - PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Dr.-Eng. Dirk Adolph; Dipl.-Eng. Thomas Saure

    2002-03-01

    GEW has been operating the first fuel cell in Europe producing heat and electricity from digester gas in an environmentally friendly way. The first 9,000 hours in operation were successfully concluded in August 2001. The fuel cell powered by digester gas was one of the 25 registered ''Worldwide projects'' which NRW presented at the EXPO 2000. In addition to this, it is a key project of the NRW State Initiative on Future Energies. All of the activities planned for the first year of operation were successfully completed: installing and putting the plant into operation, the transition to permanent operation as well as extended monitoring till May 2001.

  2. Fuel cell with ionization membrane

    Science.gov (United States)

    Hartley, Frank T. (Inventor)

    2007-01-01

    A fuel cell is disclosed comprising an ionization membrane having at least one area through which gas is passed, and which ionizes the gas passing therethrough, and a cathode for receiving the ions generated by the ionization membrane. The ionization membrane may include one or more openings in the membrane with electrodes that are located closer than a mean free path of molecules within the gas to be ionized. Methods of manufacture are also provided.

  3. Molten carbonate fuel cell matrices

    Energy Technology Data Exchange (ETDEWEB)

    Vogel, Wolfgang M. (Glastonbury, CT); Smith, Stanley W. (Vernon, CT)

    1985-04-16

    A molten carbonate fuel cell including a cathode electrode of electrically conducting or semiconducting lanthanum containing material and an electrolyte containing matrix of an electrically insulating lanthanum perovskite. In addition, in an embodiment where the cathode electrode is LaMnO.sub.3, the matrix may include LaAlO.sub.3 or a lithium containing material such as LiAlO.sub.2 or Li.sub.2 TiO.sub.3.

  4. Fuel cells principles, design, and analysis

    CERN Document Server

    Revankar, Shripad T

    2014-01-01

    ""This book covers all essential themes of fuel cells ranging from fundamentals to applications. It includes key advanced topics important for understanding correctly the underlying multi-science phenomena of fuel cell processes. The book does not only cope with traditional fuel cells but also discusses the future concepts of fuel cells. The book is rich on examples and solutions important for applying the theory into practical use.""-Peter Lund, Aalto University, Helsinki""A good introduction to the range of disciplines needed to design, build and test fuel cells.""-Nigel Brandon, Imperial Co

  5. Fuel cell science theory, fundamentals, and biocatalysis

    CERN Document Server

    Wieckowski, Andrzej

    2011-01-01

    A comprehensive survey of theoretical andexperimental concepts in fuel cell chemistry Fuel cell science is undergoing significant development, thanks, in part, to a spectacular evolution of the electrocatalysis concepts, and both new theoretical and experimental methods. Responding to the need for a definitive guide to the field, Fuel Cell Science provides an up-to-date, comprehensive compendium of both theoretical and experimental aspects of the field. Designed to inspire scientists to think about the future of fuel cell technology, Fuel Cell Science addresses the emerging field of

  6. General Motors automotive fuel cell program

    Energy Technology Data Exchange (ETDEWEB)

    Fronk, M.H.

    1995-08-01

    The objectives of the second phase of the GM/DOE fuel cell program is to develop and test a 30 kW fuel cell powerplant. This powerplant will be based on a methanol fuel processor and a proton exchange membrane PM fuel cell stack. In addition, the 10 kW system developed during phase I will be used as a {open_quotes}mule{close_quotes} to test automotive components and other ancillaries, needed for transient operation.

  7. Ansaldo programs on fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Marcenaro, B.G.; Federici, F. [Ansaldo Ricerche Srl, Genova (Italy)

    1996-12-31

    The growth in traffic and the importance of maintaining a stable ecology at the global scale, particularly with regard to atmospheric pollution, raises the necessity to realize a new generation of vehicles which are more efficient, more economical and compatible with the environment. At European level, the Car of Tomorrow task force has identified fuel cells as a promising alternative propulsion system. Ansaldo Ricerche has been involved in the development of fuel cell vehicles since the early nineties. Current ongoing programs relates to: (1) Fuel cell bus demonstrator (EQHEPP BUS) Test in 1996 (2) Fuel cell boat demonstrator (EQHHPP BOAT) Test in 1997 (3) Fuel cell passenger car prototype (FEVER) Test in 1997 (4) 2nd generation Fuel cell bus (FCBUS) 1996-1999 (5) 2nd generation Fuel cell passenger car (HYDRO-GEN) 1996-1999.

  8. Alkaline fuel cell performance investigation

    Science.gov (United States)

    Martin, R. E.; Manzo, M. A.

    1988-01-01

    An exploratory experimental fuel cell test program was conducted to investigate the performance characteristics of alkaline laboratory research electrodes. The objective of this work was to establish the effect of temperature, pressure, and concentration upon performance and evaluate candidate cathode configurations having the potential for improved performance. The performance characterization tests provided data to empirically establish the effect of temperature, pressure, and concentration upon performance for cell temperatures up to 300 F and reactant pressures up to 200 psia. Evaluation of five gold alloy cathode catalysts revealed that three doped gold alloys had more that two times the surface areas of reference cathodes and therefore offered the best potential for improved performance.

  9. Fuel economy and range estimates for fuel cell powered automobiles

    Energy Technology Data Exchange (ETDEWEB)

    Steinbugler, M.; Ogden, J. [Princeton Univ., NJ (United States)

    1996-12-31

    While a number of automotive fuel cell applications have been demonstrated, including a golf cart, buses, and a van, these systems and others that have been proposed have utilized differing configurations ranging from direct hydrogen fuel cell-only power plants to fuel cell/battery hybrids operating on reformed methanol. To date there is no clear consensus on which configuration, from among the possible combinations of fuel cell, peaking device, and fuel type, is the most likely to be successfully commercialized. System simplicity favors direct hydrogen fuel cell vehicles, but infrastructure is lacking. Infrastructure favors a system using a liquid fuel with a fuel processor, but system integration and performance issues remain. A number of studies have analyzed particular configurations on either a system or vehicle scale. The objective of this work is to estimate, within a consistent framework, fuel economies and ranges for a variety of configurations using flexible models with the goal of identifying the most promising configurations and the most important areas for further research and development.

  10. Microbial fuel cell treatment of fuel process wastewater

    Science.gov (United States)

    Borole, Abhijeet P; Tsouris, Constantino

    2013-12-03

    The present invention is directed to a method for cleansing fuel processing effluent containing carbonaceous compounds and inorganic salts, the method comprising contacting the fuel processing effluent with an anode of a microbial fuel ell, the anode containing microbes thereon which oxidatively degrade one or more of the carbonaceous compounds while producing electrical energy from the oxidative degradation, and directing the produced electrical energy to drive an electrosorption mechanism that operates to reduce the concentration of one or more inorganic salts in the fuel processing effluent, wherein the anode is in electrical communication with a cathode of the microbial fuel cell. The invention is also directed to an apparatus for practicing the method.

  11. The development of microfabricated biocatalytic fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, Satoshi; Karube, Isao [University of Tokyo (Japan). Research Center for Advanced Science and Technology

    1999-02-01

    The production of electricity by biocatalytic fuel cells has been feasible for almost two decades and can produce electric power at a practical level. These fuel cells use immobilized microorganisms or enzymes as catalysts, and glucose as a fuel. A microfabricated enzyme battery has recently been made that is designed to function as a power supply for microsurgery robots or artificial organs. (author)

  12. Hydrogen Fuel Cells: Part of the Solution

    Science.gov (United States)

    Busby, Joe R.; Altork, Linh Nguyen

    2010-01-01

    With the decreasing availability of oil and the perpetual dependence on foreign-controlled resources, many people around the world are beginning to insist on alternative fuel sources. Hydrogen fuel cell technology is one answer to this demand. Although modern fuel cell technology has existed for over a century, the technology is only now becoming…

  13. Hybrid Cars Now, Fuel Cell Cars Later

    Science.gov (United States)

    Demirdöven, Nurettin; Deutch, John

    2004-08-01

    We compare the energy efficiency of hybrid and fuel cell vehicles as well as conventional internal combustion engines. Our analysis indicates that fuel cell vehicles using hydrogen from fossil fuels offer no significant energy efficiency advantage over hybrid vehicles operating in an urban drive cycle. We conclude that priority should be placed on hybrid vehicles by industry and government.

  14. Landfill gas cleanup for fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    EPRI is to test the feasibility of using a carbonate fuel cell to generate electricity from landfill gas. Landfills produce a substantial quantity of methane gas, a natural by-product of decaying organic wastes. Landfill gas, however, contains sulfur and halogen compounds, which are known contaminants to fuel cells and their fuel processing equipment. The objective of this project is to clean the landfill gas well enough to be used by the fuel cell without making the process prohibitively expensive. The cleanup system tested in this effort could also be adapted for use with other fuel cells (e.g., solid oxide, phosphoric acid) running on landfill gas.

  15. Early stage fuel cell funding

    International Nuclear Information System (INIS)

    'Full text:' Early stage venture funding requires an in depth understanding of both current and future markets as well as the key technical hurdles that need to be overcome for new technology to commercialize into successful products for mass markets. As the leading fuel cell and hydrogen investor, Chrysalix continuously reviews global trends and new technologies, evaluates them with industry leaders worldwide and tries to match them up with the best possible management teams when selecting its early stage investments. Chrysalix Energy Limited Partnership is an early-stage venture capital firm focusing on fuel cell and related fueling technology companies and is a private equity joint venture between Ballard Power Systems, BASF Venture Capital, The BOC Group, The Boeing Company, Duke Energy, Mitsubishi Corporation and Shell Hydrogen. Operating independently, Chrysalix offers a unique value proposition to its clients throughout the business planning, start-up and operations phases of development. Chrysalix provides early-stage funding to new companies as well as management assistance, technological knowledge, organized networking with industry players and experience in the management of intellectual property. (author)

  16. 2008 Fuel Cell Technologies Market Report

    Energy Technology Data Exchange (ETDEWEB)

    DOE

    2010-06-01

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of fuel is supplied. Moreover, fuel cells do not burn fuel, making the process quiet, pollution-free and two to three times more efficient than combustion. Fuel cell systems can be a truly zero-emission source of electricity, if the hydrogen is produced from non-polluting sources. Global concerns about climate change, energy security, and air pollution are driving demand for fuel cell technology. More than 630 companies and laboratories in the United States are investing $1 billion a year in fuel cells or fuel cell component technologies. This report provides an overview of trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance. It also provides snapshots of select fuel cell companies, including general business strategy and market focus, as well as, financial information for select publicly-traded companies.

  17. 2008 Fuel Cell Technologies Market Report

    Energy Technology Data Exchange (ETDEWEB)

    Vincent, B. [Breakthrough Technologies Inst., Washington, DC (United States)

    2010-06-30

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of fuel is supplied. Moreover, fuel cells do not burn fuel, making the process quiet, pollution-free and two to three times more efficient than combustion. Fuel cell systems can be a truly zero-emission source of electricity, if the hydrogen is produced from non-polluting sources. Global concerns about climate change, energy security, and air pollution are driving demand for fuel cell technology. More than 630 companies and laboratories in the United States are investing $1 billion a year in fuel cells or fuel cell component technologies. This report provides an overview of trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance. It also provides snapshots of select fuel cell companies, including general business strategy and market focus, as well as, financial information for select publicly-traded companies.

  18. The direct methanol fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Halpert, G.; Narayanan, S.R.; Frank, H. [Jet Propulsion Lab., Pasadena, CA (United States)

    1995-08-01

    This presentation describes the approach and progress in the ARPA-sponsored effort to develop a Direct Methanol, Liquid-Feed Fuel Cell (DMLFFC) with a solid Polymer Electrolyte Membrane (PEM) for battery replacement in small portable applications. Using Membrane Electrode Assemblies (MEAs) developed by JPL and Giner, significant voltage was demonstrated at relatively high current densities. The DMLFFC utilizes a 3 percent aqueous solution of methanol that is oxidized directly in the anode (fuel) chamber and oxygen (air) in the cathode chamber to produce water and significant power. The only products are water and CO{sub 2}. The ARPA effort is aimed at replacing the battery in the BA 5590 military radio.

  19. World wide IFC phosphoric acid fuel cell implementation

    Energy Technology Data Exchange (ETDEWEB)

    King, J.M. Jr

    1996-04-01

    International Fuel Cells, a subsidary of United technologies Corporation, is engaged in research and development of all types of fuel cell technologies and currently manufactures alkaline fuel cell power plants for the U.S. manned space flight program and natural gas fueled stationary power plants using phosphoric acid fuel cells. This paper describes the phosphoric acid fuel cell power plants.

  20. Prospects for UK fuel cells component suppliers

    Energy Technology Data Exchange (ETDEWEB)

    Wilcox, C.; Tunnicliffe, M.

    2002-07-01

    This report examines the capabilities of the UK fuel cell industry in meeting the expected increase in demand, and aims to identify all UK suppliers of fuel cell components, evaluate their products and match them to fuel cell markets, and identify components where the UK is in a competitive position. Component areas are addressed along with the need to reduce costs and ensure efficient production. The well established supplier base in the UK is noted, and the car engine manufacturing base and fuel supply companies are considered. The different strengths of UK suppliers of the various types of fuel cells are listed. The future industry structure, the opportunities and dangers for business posed by fuel cells, the investment in cleaner technologies by the large fuel companies, opportunities for catalyst suppliers, and the residential combined heat and power and portable electronics battery markets are discussed.

  1. Clean energy from a carbon fuel cell

    Science.gov (United States)

    Kacprzak, Andrzej; Kobyłecki, Rafał; Bis, Zbigniew

    2011-12-01

    The direct carbon fuel cell technology provides excellent conditions for conversion of chemical energy of carbon-containing solid fuels directly into electricity. The technology is very promising since it is relatively simple compared to other fuel cell technologies and accepts all carbon-reach substances as possible fuels. Furthermore, it makes possible to use atmospheric oxygen as the oxidizer. In this paper the results of authors' recent investigations focused on analysis of the performance of a direct carbon fuel cell supplied with graphite, granulated carbonized biomass (biocarbon), and granulated hard coal are presented. The comparison of the voltage-current characteristics indicated that the results obtained for the case when the cell was operated with carbonized biomass and hard coal were much more promising than those obtained for graphite. The effects of fuel type and the surface area of the cathode on operation performance of the fuel cell were also discussed.

  2. Portable power applications of fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Weston, M.; Matcham, J.

    2002-07-01

    This report describes the state-of-the-art of fuel cell technology for portable power applications. The study involved a comprehensive literature review. Proton exchange membrane fuel cells (PEMFCs) have attracted much more interest than either direct methanol fuel cells (DMFCs) or solid oxide fuel cells (SOFCs). However, issues relating to fuel choice and catalyst design remain with PEMFCs; DMFCs have excellent potential provided issues relating to the conducting membrane can be resolved but the current high temperature of operation and low power density currently makes SOFCs less applicable to portable applications. Available products are listed and the obstacles to market penetration are discussed. The main barriers are cost and the size/weight of fuel cells compared with batteries. Another key problem is the lack of a suitable fuel infrastructure.

  3. Bringing fuel cells to reality and reality to fuel cells: A systems perspective on the use of fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Saxe, Maria

    2008-10-15

    The hopes and expectations on fuel cells are high and sometimes unrealistically positive. However, as an emerging technology, much remains to be proven and the proper use of the technology in terms of suitable applications, integration with society and extent of use is still under debate. This thesis is a contribution to the debate, presenting results from two fuel cell demonstration projects, looking into the introduction of fuel cells on the market, discussing the prospects and concerns for the near-term future and commenting on the potential use in a future sustainable energy system. Bringing fuel cells to reality implies finding near-term niche applications and markets where fuel cell systems may be competitive. In a sense fuel cells are already a reality as they have been demonstrated in various applications world-wide. However, in many of the envisioned applications fuel cells are far from being competitive and sometimes also the environmental benefit of using fuel cells in a given application may be questioned. Bringing reality to fuel cells implies emphasising the need for realistic expectations and pointing out that the first markets have to be based on the currently available technology and not the visions of what fuel cells could be in the future. The results from the demonstration projects show that further development and research on especially the durability for fuel cell systems is crucial and a general recommendation is to design the systems for high reliability and durability rather than striving towards higher energy efficiencies. When sufficient reliability and durability are achieved, fuel cell systems may be introduced in niche markets where the added values presented by the technology compensate for the initial high cost

  4. POLYMER ELECTROLYTE MEMBRANE FUEL CELLS

    DEFF Research Database (Denmark)

    2001-01-01

    thermoplastic polymers for high temperature polymer electrolyte fuel cells have also been developed. Miscible blends are used for solution casting of polymer membranes (solid electrolytes). High conductivity and enhanced mechanical strength were obtained for the blend polymer solid electrolytes....... With the thermally resistant polymer, e.g., polybenzimidazole or a mixture of polybenzimidazole and other thermoplastics as binder, the carbon-supported noble metal catalyst is tape-cast onto a hydrophobic supporting substrate. When doped with an acid mixture, electrodes are assembled with an acid doped solid...

  5. Photoactivated Fuel Cells (PhotoFuelCells. An alternative source of renewable energy with environmental benefits

    Directory of Open Access Journals (Sweden)

    Stavroula Sfaelou

    2016-03-01

    Full Text Available This work is a short review of Photoactivated Fuel Cells, that is, photoelectrochemical cells which consume an organic or inorganic fuel to produce renewable electricity or hydrogen. The work presents the basic features of photoactivated fuel cells, their modes of operation, the materials, which are frequently used for their construction and some ideas of cell design both for electricity and solar hydrogen production. Water splitting is treated as a special case of photoactivated fuel cell operation.

  6. Photoactivated Fuel Cells (PhotoFuelCells). An alternative source of renewable energy with environmental benefits

    OpenAIRE

    Stavroula Sfaelou; Panagiotis Lianos

    2016-01-01

    This work is a short review of Photoactivated Fuel Cells, that is, photoelectrochemical cells which consume an organic or inorganic fuel to produce renewable electricity or hydrogen. The work presents the basic features of photoactivated fuel cells, their modes of operation, the materials, which are frequently used for their construction and some ideas of cell design both for electricity and solar hydrogen production. Water splitting is treated as a special case of photoactivated fuel cell op...

  7. Steam reforming of fuel to hydrogen in fuel cells

    International Nuclear Information System (INIS)

    A fuel cell is claimed capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst

  8. Modular PEM Fuel Cell SCADA & Simulator System

    Directory of Open Access Journals (Sweden)

    Francisca Segura

    2015-09-01

    Full Text Available The paper presents a Supervision, Control, Data Acquisition and Simulation (SCADA & Simulator system that allows for real-time training in the actual operation of a modular PEM fuel cell system. This SCADA & Simulator system consists of a free software tool that operates in real time and simulates real situations like failures and breakdowns in the system. This developed SCADA & Simulator system allows us to properly operate a fuel cell and helps us to understand how fuel cells operate and what devices are needed to configure and run the fuel cells, from the individual stack up to the whole fuel cell system. The SCADA & Simulator system governs a modular system integrated by three PEM fuel cells achieving power rates higher than tens of kilowatts.

  9. European Fuel Cells R&D Review

    Science.gov (United States)

    Michael, P. D.; Maguire, J.

    1994-09-01

    A review is presented on the status of fuel cell development in Europe, addressing the research, development, and demonstration (RD&D) and commercialization activities being undertaken, identifying key European organizations active in development and commercialization of fuel cells, and detailing their future plans. This document describes the RD&D activities in Europe on alkaline, phosphoric acid, polymer electrolyte, direct methanol, solid oxide, and molten carbonate fuel cell types. It describes the European Commission's activities, its role in the European development of fuel cells, and its interaction with the national programs. It then presents a country-by-country breakdown. For each country, an overview is given, presented by fuel cell type. Scandinavian countries are covered in less detail. American organizations active in Europe, either in supplying fuel cell components, or in collaboration, are identified. Applications include transportation and cogeneration.

  10. Regulation of Power Conversion in Fuel Cells

    Institute of Scientific and Technical Information of China (English)

    SHEN Mu-zhong; ZHANG J.; K. Scott

    2004-01-01

    Here we report a regulation about power conversion in fuel cells. This regulation is expressed as that total power produced by fuel cells is always proportional to the square of the potential difference between the equilibrium potential and work potential. With this regulation we deduced fuel cell performance equation which can describe the potential vs. the current performance curves, namely, polarization curves of fuel cells with three power source parameters: equilibrium potential E0; internal resistance R; and power conversion coefficient K. The concept of the power conversion coefficient is a new criterion to evaluate and compare the characteristics and capacity of different fuel cells. The calculated values obtained with this equation agree with practical performance of different types of fuel cells.

  11. Commercialization of fuel cells: myth or reality?

    CERN Document Server

    Wang, Junye

    2014-01-01

    Despite huge investment and efforts in the last decades, fuel cells are still known as a fledgling industry after 170 years of the first fuel cell. It becomes clear that these investment and efforts did not address the critical questions. Why upscaling of fuel cells failed often when many researchers stated their successes in small scale? Why the fuel cells with simpler structure still lag far from the internal combustion (IC) engines and gas turbines? Could the current investment of the hydrogen infrastructure reduce substantially the fuel cell cost and make a breakthrough to the key issues of durability, reliability and robustness? In this paper, we study these fundamental questions and point out a must-way possible to reduce cost of fuel cells and to substantially improve durability and reliability.

  12. Third annual report of the Canadian nuclear fuel waste management program

    International Nuclear Information System (INIS)

    This report, the third of a series of annual reports, reviews the progress that has been made in the research and development program for the safe management and disposal of Canada's nuclear fuel wastes. The report summarizes activities over the past year, in the areas of public interaction, irradiated fuel storage and transportation, immobilization of irradiated fuel and fuel recycle wastes, research and development associated with deep underground disposal, and environmental and safety assessment

  13. Fourth annual report of the Canadian nuclear fuel waste management program

    International Nuclear Information System (INIS)

    This report, the fourth of a series of annual reports, reviews the progress that has been made in the research and development program for the safe management and disposal of Canada's nuclear fuel waste. The report summarizes activities over the past year in the following areas: public interaction, used fuel storage and transportation, immobilization of used fuel and fuel recycle waste, geoscience research associated with deep underground disposal, environmental research, environmental and safety assessment

  14. Renewable energies - Fuel cell and hydrogen

    International Nuclear Information System (INIS)

    In July 2003 the Fuel Cell Program was established at IPEN in order to contribute to the national development in this area. The program was structured in a cross-cutting way involving human and infrastructure resources from IPEN Technical Departments. Three main areas were developed: PEMFC (Proton Exchange Membrane Fuel Cell): SOFC (Solid Oxide Fuel Cell); and REFORM (H2 production from ethanol reforming)

  15. Review of UK fuel cell. Commercial potential

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-11-15

    The advancement of fuel cell technology in recent years has made commercial viability a reality in many disciplines in the UK. The Carbon Trust and the Department of Trade and Industry have jointly undertaken a study to facilitate and encourage the penetration of fuel cells into the commercial market both at home and overseas. This document summarises the findings of the study and concludes that stationary fuel cells have the greatest potential for market stimulation.

  16. Alkaline fuel cells for the regenerative fuel cell energy storage system

    Science.gov (United States)

    Martin, R. E.

    1983-01-01

    The development of the alkaline Regenerative Fuel Cell System, whose fuel cell module would be a derivative of the 12-kW fuel cell power plant currently being produced for the Space Shuttle Orbiter, is reviewed. Long-term endurance testing of full-size fuel cell modules has demonstrated: (1) the extended endurance capability of potassium titanate matrix cells, (2) the long-term performance stability of the anode catalyst, and (3) the suitability of a lightweight graphite structure for use at the anode. These approaches, developed in the NASA-sponsored fuel cell technology advancement program, would also reduce cell weight by nearly one half.

  17. Fuel Cells in China 2008

    Energy Technology Data Exchange (ETDEWEB)

    Aiken-Xuan Liu; Rissanen, Markku

    2009-01-15

    This report gives an overview of the fuel cell field with some history, the development as per today, the present situation and status of fuel cells in China, with the regard to industry, manufacturers, and suppliers, other organizations, applications, development and trends. USA, Canada, Japan, Korea and Germany are the main countries in the lead of the fuel cell area. When comparing with these countries e.g. the neighboring countries Japan and Korea, China is still behind but they are rapidly catching up, especially in the transportation area where there are many activities ongoing and where the government has put a large focus. In the year 2008 there were many demonstration projects with buses and cars, some in connection with the Olympic Games. Still the activities are mainly driven by research organizations, i.e. Universities and Institutes, but some commercial companies have started to show up. As for investment and financing, the development is dependent on governmental resources but there have been investments made from bus, car and bicycle manufacturers. Other private investments are small. The companies or other organizations that are in the forefront on a worldwide basis are mainly some research institutes as Tsinghua University, Tongji University and Dalian Institute of Chemical Physics and some vehicle manufacturer, e.g. Shanghai Volkswagen. Many of the Chinese organizations, e.g. Chinese Academy of Science have some cooperation with companies abroad to gain experiences and to have a fast development in the area. For the portable and stationary applications there is not as much activity as in the transportation area with demonstrations and media coverage. However, with China's position in the production of batteries for portable devices there are some activities in the battery companies and in the research organizations, but this is not reported extensively. With regards to stationary applications and larger power outputs there are not that many

  18. PEM fuel cell testing and diagnosis

    CERN Document Server

    Wu, Jifeng; Zhang, Jiujun

    2013-01-01

    PEM Fuel Cell Testing and Diagnosis covers the recent advances in PEM (proton exchange membrane) fuel cell systems, focusing on instruments and techniques for testing and diagnosis, and the application of diagnostic techniques in practical tests and operation. This book is a unique source of electrochemical techniques for researchers, scientists and engineers working in the area of fuel cells. Proton exchange membrane fuel cells are currently considered the most promising clean energy-converting devices for stationary, transportation, and micro-power applications due to their

  19. Platinum Porous Electrodes for Fuel Cells

    DEFF Research Database (Denmark)

    Andersen, Shuang Ma

    Fuel cell energy bears the merits of renewability, cleanness and high efficiency. Proton Exchange Membrane Fuel Cell (PEMFC) is one of the most promising candidates as the power source in the near future. A fine management of different transports and electrochemical reactions in PEM fuel cells...... to a genuine picture of a working PEM fuel cell catalyst layer. These, in turn, enrich the knowledge of Three-Phase-Boundary, provide efficient tool for the electrode selection and eventually will contribute the advancement of PEMFC technology....

  20. Fuel Cell and Battery Powered Forklifts

    DEFF Research Database (Denmark)

    Zhang, Zhe; Mortensen, Henrik H.; Jensen, Jes Vestervang;

    2013-01-01

    A hydrogen-powered materials handling vehicle with a fuel cell combines the advantages of diesel/LPG and battery powered vehicles. Hydrogen provides the same consistent power and fast refueling capability as diesel and LPG, whilst fuel cells provide energy efficient and zero emission Electric...... propulsion similar to batteries. In this paper, the performance of a forklift powered by PEM fuel cells and lead acid batteries as auxiliary energy source is introduced and investigated. In this electromechanical propulsion system with hybrid energy/power sources, fuel cells will deliver average power...

  1. Fuel Cell Stations Automate Processes, Catalyst Testing

    Science.gov (United States)

    2010-01-01

    Glenn Research Center looks for ways to improve fuel cells, which are an important source of power for space missions, as well as the equipment used to test fuel cells. With Small Business Innovation Research (SBIR) awards from Glenn, Lynntech Inc., of College Station, Texas, addressed a major limitation of fuel cell testing equipment. Five years later, the company obtained a patent and provided the equipment to the commercial world. Now offered through TesSol Inc., of Battle Ground, Washington, the technology is used for fuel cell work, catalyst testing, sensor testing, gas blending, and other applications. It can be found at universities, national laboratories, and businesses around the world.

  2. Solid Oxide Fuel Cells Operating on Alternative and Renewable Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiaoxing; Quan, Wenying; Xiao, Jing; Peduzzi, Emanuela; Fujii, Mamoru; Sun, Funxia; Shalaby, Cigdem; Li, Yan; Xie, Chao; Ma, Xiaoliang; Johnson, David; Lee, Jeong; Fedkin, Mark; LaBarbera, Mark; Das, Debanjan; Thompson, David; Lvov, Serguei; Song, Chunshan

    2014-09-30

    This DOE project at the Pennsylvania State University (Penn State) initially involved Siemens Energy, Inc. to (1) develop new fuel processing approaches for using selected alternative and renewable fuels – anaerobic digester gas (ADG) and commercial diesel fuel (with 15 ppm sulfur) – in solid oxide fuel cell (SOFC) power generation systems; and (2) conduct integrated fuel processor – SOFC system tests to evaluate the performance of the fuel processors and overall systems. Siemens Energy Inc. was to provide SOFC system to Penn State for testing. The Siemens work was carried out at Siemens Energy Inc. in Pittsburgh, PA. The unexpected restructuring in Siemens organization, however, led to the elimination of the Siemens Stationary Fuel Cell Division within the company. Unfortunately, this led to the Siemens subcontract with Penn State ending on September 23rd, 2010. SOFC system was never delivered to Penn State. With the assistance of NETL project manager, the Penn State team has since developed a collaborative research with Delphi as the new subcontractor and this work involved the testing of a stack of planar solid oxide fuel cells from Delphi.

  3. PLATINUM, FUEL CELLS, AND FUTURE ROAD TRANSPORT

    Science.gov (United States)

    A vehicle powered by a fuel cell will emit virtually no air polution and, depending on fuel choice, can substantially improve fuel economy above that of current technology. Those attributes are complementary to issues of increasing national importance including the effects of tra...

  4. Fuel starvation. Irreversible degradation mechanisms in PEM fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Rangel, Carmen M.; Silva, R.A.; Travassos, M.A.; Paiva, T.I.; Fernandes, V.R. [LNEG, National Laboratory for Energy and Geology, Lisboa (Portugal). UPCH Fuel Cells and Hydrogen Unit

    2010-07-01

    PEM fuel cell operates under very aggressive conditions in both anode and cathode. Failure modes and mechanism in PEM fuel cells include those related to thermal, chemical or mechanical issues that may constrain stability, power and lifetime. In this work, the case of fuel starvation is examined. The anode potential may rise to levels compatible with the oxidization of water. If water is not available, oxidation of the carbon support will accelerate catalyst sintering. Diagnostics methods used for in-situ and ex-situ analysis of PEM fuel cells are selected in order to better categorize irreversible changes of the cell. Electrochemical Impedance Spectroscopy (EIS) is found instrumental in the identification of fuel cell flooding conditions and membrane dehydration associated to mass transport limitations / reactant starvation and protonic conductivity decrease, respectively. Furthermore, it indicates that water electrolysis might happen at the anode. Cross sections of the membrane catalyst and gas diffusion layers examined by scanning electron microscopy indicate electrode thickness reduction as a result of reactions taking place during hydrogen starvation. Catalyst particles are found to migrate outwards and located on carbon backings. Membrane degradation in fuel cell environment is analyzed in terms of the mechanism for fluoride release which is considered an early predictor of membrane degradation. (orig.)

  5. Fuel cell membranes and crossover prevention

    Science.gov (United States)

    Masel, Richard I.; York, Cynthia A.; Waszczuk, Piotr; Wieckowski, Andrzej

    2009-08-04

    A membrane electrode assembly for use with a direct organic fuel cell containing a formic acid fuel includes a solid polymer electrolyte having first and second surfaces, an anode on the first surface and a cathode on the second surface and electrically linked to the anode. The solid polymer electrolyte has a thickness t:.gtoreq..times..times..times..times. ##EQU00001## where C.sub.f is the formic acid fuel concentration over the anode, D.sub.f is the effective diffusivity of the fuel in the solid polymer electrolyte, K.sub.f is the equilibrium constant for partition coefficient for the fuel into the solid polymer electrolyte membrane, I is Faraday's constant n.sub.f is the number of electrons released when 1 molecule of the fuel is oxidized, and j.sub.f.sup.c is an empirically determined crossover rate of fuel above which the fuel cell does not operate.

  6. Durable and Robust Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Hjalmarsson, Per; Knibbe, Ruth; Hauch, Anne;

    The solid oxide fuel cell (SOFC) is an attractive technology for the generation of electricity with high efficiency and low emissions. Risø DTU (now DTU Energy Conversion) works closely together with Topsoe Fuel Cell A/S in their effort to bring competitive SOFC systems to the market. This 2-year...... project had as one of its’ overarching goals to improve durability and robustness of the Danish solid oxide fuel cells. The project focus was on cells and cell components suitable for SOFC operation in the temperature range 600 – 750 °C. The cells developed and/or studied in this project are intended...

  7. Cost targets for domestic fuel cell CHP

    Science.gov (United States)

    Staffell, I.; Green, R.; Kendall, K.

    Fuel cells have the potential to reduce domestic energy bills by providing both heat and power at the point of use, generating high value electricity from a low cost fuel. However, the cost of installing the fuel cell must be sufficiently low to be recovered by the savings made over its lifetime. A computer simulation is used to estimate the savings and cost targets for fuel cell CHP systems. Two pitfalls of this kind of simulation are addressed: the selection of representative performance figures for fuel cells, and the range of houses from which energy demand data was taken. A meta-study of the current state of the art is presented, and used with 102 house-years of demand to simulate the range of economic performance expected from four fuel cell technologies within the UK domestic CHP market. Annual savings relative to a condensing boiler are estimated at €170-300 for a 1 kWe fuel cell, giving a target cost of €350-625 kW -1 for any fuel cell technology that can demonstrate a 2.5-year lifetime. Increasing lifetime and reducing fuel cell capacity are identified as routes to accelerated market entry. The importance of energy demand is seen to outweigh both economic and technical performance assumptions, while manufacture cost and system lifetime are highlighted as the only significant differences between the technologies considered. SOFC are considered to have the greatest potential, but uncertainty in the assumptions used precludes any clear-cut judgement.

  8. Proceedings of the Queen's-RMC Fuel Cell Research Centre fuel cell technology day

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    The Queen's-RMC Fuel Cell Research Centre was formed to conduct research on polymer electrolyte membrane (PEM) and solid oxide (SOFC) fuel cells as well as fuel processing and hydrogen production and storage technologies. The centre focuses on the development of manufacturing methods, mathematical modelling, catalysis and reaction engineering, and computational thermodynamics. The fuel cell technology day provided a forum for research leaders from various institutions to discuss recent studies related to PEM and SOFC fuel cells. Issues related to materials and system degradation in fuel cells were discussed along with recent developments in the micro-engineering of SOFC cathodes. Commercialization plans for megawatt fuel cells were also discussed, and recent spectroscopy and voltammetry studies of PEM fuel cells were presented. A panel discussion was also held to determine research directions for the future. The technology day featured 7 presentations, of which 2 have been catalogued separately for inclusion in this database. tabs., figs.

  9. Long distance relationships : the secret for fuel cell success? fuel cell developers and integrators form trans-oceanic partnerships to crash through cultural barriers

    International Nuclear Information System (INIS)

    The varieties of viable fuel cell applications and widely varying regional market conditions have created global partnerships among entities with complementary attributes. Although it may appear that domestic liaisons among culturally similar players spawned from industry clusters should provide the clearest route to success in this industry, it is the intercontinental groupings which are demonstrating the most potential. This paper discussed the global fuel cell challenge and the vertical integration of multi-national partnerships. The paper also discussed the current global stationary market in perspective. Fuel cells require unique maintenance, support, and refueling including operator instruction and a new supply infrastructure. The paper addressed the fact that fuel cells represent a disruptive technology. A telecom backup status report was also presented. Other topics that were discussed included developing markets as well as specific examples of global organizations such as Canadian Ballard and Danish Dantherm Power and their fuel cell application solutions. It was concluded that after an inconsistent history, fuel cells have finally achieved viability in the real world. However, there is significant cultural resistance to their implementation in the United States. 4 figs

  10. EFFECT OF FUEL IMPURITIES ON FUEL CELL PERFORMANCE AND DURABILITY

    Energy Technology Data Exchange (ETDEWEB)

    Colon-Mercado, H.

    2010-09-28

    A fuel cell is an electrochemical energy conversion device that produces electricity during the combination of hydrogen and oxygen to produce water. Proton exchange membranes fuel cells are favored for portable applications as well as stationary ones due to their high power density, low operating temperature, and low corrosion of components. In real life operation, the use of pure fuel and oxidant gases results in an impractical system. A more realistic and cost efficient approach is the use of air as an oxidant gas and hydrogen from hydrogen carriers (i.e., ammonia, hydrocarbons, hydrides). However, trace impurities arising from different hydrogen sources and production increases the degradation of the fuel cell. These impurities include carbon monoxide, ammonia, sulfur, hydrocarbons, and halogen compounds. The International Organization for Standardization (ISO) has set maximum limits for trace impurities in the hydrogen stream; however fuel cell data is needed to validate the assumption that at those levels the impurities will cause no degradation. This report summarizes the effect of selected contaminants tested at SRNL at ISO levels. Runs at ISO proposed concentration levels show that model hydrocarbon compound such as tetrahydrofuran can cause serious degradation. However, the degradation is only temporary as when the impurity is removed from the hydrogen stream the performance completely recovers. Other molecules at the ISO concentration levels such as ammonia don't show effects on the fuel cell performance. On the other hand carbon monoxide and perchloroethylene shows major degradation and the system can only be recovered by following recovery procedures.

  11. Internet public information for fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Sudhoff, F.A. [Dept. of Energy, Morgantown, WV (United States)

    1995-08-01

    The rapid development and integration of the Internet into the mainstream of professional life provide the fuel cell industry with the opportunity to share new ideas with unprecedented capabilities. The U.S. Department of Energy`s Morgantown Energy Technology Center (METC) has undertaken the task to provide a service where current fuel cell descriptions and information are available to customers, manufactures, academia, and the general public. METC has developed a Fuel Cell Forum where members can exchange ideas and information pertaining to fuel cell technologies using the Internet. Forum membership is encouraged from utilities, industry, universities, and Government. Because of the public nature of the Internet, business sensitive, confidential, or proprietary information should not be placed on this system. The views and opinions of authors expressed in the forum do not necessarily state or reflect those of the U.S. Government or METC. METC, has endeavored to develop a World Wide Web (WWW) location committed to the description and development of the fuel cell. Netscape or compatible software provides access to the METC Homepage. The user then selects Advanced Power Systems, then Fuel Cells. Fuel cell overview and description is followed by a presentation of the fuel cell system characteristics and advantages. Descriptions of major fuel cell projects are provided in the FACTS section. Finally, as a service to METC customers, the homepage provides a calendar and points of contact. Updates to the WWW location are occasionally made revealing current technical advances in fuel cells. In the continuing effort to further improve public knowledge and perception of fuel cell power generation, METC has created two new modes of communication using the Internet.

  12. Fueling war : the impact of Canadian oil investment on the conflict in Columbia

    Energy Technology Data Exchange (ETDEWEB)

    Pearce, S.

    2002-11-15

    Canadian oil companies have become increasingly involved in oil exploration and development in Columbia over the last 2 years. This paper examined the impact of Canadian oil investment on armed conflict in Columbia, and suggested that there is a strong correlation between regions of mineral wealth and regions of political conflict. The role of Canadian companies in contributing to the escalation of political violence was explored, and the economics of civil war from a theoretical perspective were examined with regards to the financing of rebellion and the role of international investment. The origins and evolution of the civil war in Colombia were outlined. Possibilities for ethical oil investment in Colombia were also explored. The paper supported recent assertions that in order to understand the political economy of civil war, the role of the international private sector must be evaluated. The significance of primary resources as a funding source for armed groups was confirmed, as well as the tendency for conflict to centre on areas of resource wealth in the country. A case study of Talisman Energy's activities in Sudan was also presented. It was suggested that oil companies operating in Colombia must become involved in local development projects to improve education and health, and should also design security measures from a corporate social responsibility perspective. It was concluded that in order to work towards the resolution of armed conflict there the root causes of the conflict, issues such as land reform, social inequality, and the terms of foreign investment must be addressed in addition to the means by which illegal armed actors finance themselves. 73 figs.

  13. Proton exchange membrane fuel cells modeling

    CERN Document Server

    Gao, Fengge; Miraoui, Abdellatif

    2013-01-01

    The fuel cell is a potential candidate for energy storage and conversion in our future energy mix. It is able to directly convert the chemical energy stored in fuel (e.g. hydrogen) into electricity, without undergoing different intermediary conversion steps. In the field of mobile and stationary applications, it is considered to be one of the future energy solutions.Among the different fuel cell types, the proton exchange membrane (PEM) fuel cell has shown great potential in mobile applications, due to its low operating temperature, solid-state electrolyte and compactness.This book pre

  14. First annual report of the Canadian nuclear fuel waste management program

    International Nuclear Information System (INIS)

    The research and development program for the safe, permanent disposal of Canada's nuclear fuel wastes has been established. This report, the first of a series of annual reports, reviews in general terms the progress which has been achieved. After briefly reviewing the rationale and organization of the program, the report summarizes activities in the area of public information, used fuel storage and transportation, immobilization of used fuel and fuel reprocessing wastes, research and development associated with deep underground disposal, and environmental and safety assessment. (auth)

  15. Fuel cell and membrane therefore

    Energy Technology Data Exchange (ETDEWEB)

    Aindow, Tai-Tsui

    2016-08-09

    A fuel cell includes first and second flow field plates, and an anode electrode and a cathode electrode between the flow field plates. A polymer electrolyte membrane (PEM) is arranged between the electrodes. At least one of the flow field plates influences, at least in part, an in-plane anisotropic physical condition of the PEM that varies in magnitude between a high value direction and a low value direction. The PEM has an in-plane physical property that varies in magnitude between a high value direction and a low value direction. The PEM is oriented with its high value direction substantially aligned with the high value direction of the flow field plate.

  16. Microbial fuel cell: A green technology

    International Nuclear Information System (INIS)

    Microbial Fuel Cell (MFC) was developed which was able to generate bio energy continuously while consuming wastewater containing organic matters. Even though the bio energy generated is not as high as hydrogen fuel cell, the MFC demonstrated great potential in bio-treating wastewater while using it as fuel source. Thus far, the dual-ability of the MFC to generate bio energy and bio-treating organic wastewater has been examined successfully using synthetic acetate and POME wastewaters. (author)

  17. Fuel Transformer Solid Oxide Fuel Cell

    Energy Technology Data Exchange (ETDEWEB)

    Norman Bessette; Douglas S. Schmidt; Jolyon Rawson; Lars Allfather; Anthony Litka

    2005-08-01

    The following report documents the technical approach and conclusions made by Acumentrics Corporation during latest budget period toward the development of a low cost 10kW tubular SOFC power system. The present program, guided under direction from the National Energy Technology Laboratory of the US DOE, is a nine-year cost shared Cooperative Agreement totaling close to $74M funded both by the US DOE as well as Acumentrics Corporation and its partners. The latest budget period ran from January of 2005 through June 2005. Work focused on cell technology enhancements as well as BOP and power electronics improvements and overall system design. Significant progress was made in increasing cell power enhancements as well as decreasing material cost in a drive to meet the SECA cost targets. The following report documents these accomplishments in detail as well as the layout plans for further progress in next budget period.

  18. FUEL TRANSFORMER SOLID OXIDE FUEL CELL

    Energy Technology Data Exchange (ETDEWEB)

    Norman Bessette; Douglas S. Schmidt; Jolyon Rawson; Lars Allfather; Anthony Litka

    2005-03-24

    The following report documents the technical approach and conclusions made by Acumentrics Corporation during latest budget period toward the development of a low cost 10kW tubular SOFC power system. The present program, guided under direction from the National Energy Technology Laboratory of the US DOE, is a nine-year cost shared Cooperative Agreement totaling close to $74M funded both by the US DOE as well as Acumentrics Corporation and its partners. The latest budget period ran from July of 2004 through January 2004. Work was focused on cell technology enhancements as well as BOP and power electronics improvements and overall system design. Significant progress was made in increasing cell power enhancements as well as decreasing material cost in a drive to meet the SECA cost targets. The following report documents these accomplishments in detail as well as the lay out plans for further progress in next budget period.

  19. Fuel Transformer Solid Oxide Fuel Cell

    Energy Technology Data Exchange (ETDEWEB)

    Norman Bessette; Douglas S. Schmidt; Jolyon Rawson; Rhys Foster; Anthony Litka

    2006-07-27

    The following report documents the technical approach and conclusions made by Acumentrics Corporation during latest budget period toward the development of a low cost 10kW tubular SOFC power system. The present program, guided under direction from the National Energy Technology Laboratory of the US DOE, is a nine-year cost shared Cooperative Agreement totaling close to $74M funded both by the US DOE as well as Acumentrics Corporation and its partners. The latest budget period ran from January of 2006 through June 2006. Work focused on cell technology enhancements as well as BOP and power electronics improvements and overall system design. Significant progress was made in increasing cell power enhancements as well as decreasing material cost in a drive to meet the SECA cost targets. The following report documents these accomplishments in detail as well as the layout plans for further progress in next budget period.

  20. The fuel cell; La pile a combustible

    Energy Technology Data Exchange (ETDEWEB)

    Boursin, P.

    2005-07-01

    This document is an exhaustive review of the history of fuel cells from 1802 to 2004. It focusses mainly on the automotive applications and supplies many technical details about each prototype of fuel cell and/or vehicle. (J.S.)

  1. Fuel cell hybrid drive train test facility

    NARCIS (Netherlands)

    Zafina, I.; Bosma, H.; Tazelaar, Edwin; Bruinsma, J.; Veenhuizen, Bram

    2009-01-01

    Fuel cells are expected to play an important role in the near future as prime energy source on board of road-going vehicles. In order to be able to test all important functional aspects of a fuel cell hybrid drive train, the Automotive Institute of the HAN University has decided to realize a station

  2. Innovative High Temperature Fuel Cell systems

    NARCIS (Netherlands)

    Au, Siu Fai

    2003-01-01

    The world's energy consumption is growing extremely rapidly. Fuel cell systems are of interest by researchers and industry as the more efficient alternative to conventional thermal systems for power generation. The principle of fuel cell conversion does not involve thermal combustion and hence in th

  3. LANDFILL GAS PRETREATMENT FOR FUEL CELL APPLICATIONS

    Science.gov (United States)

    The paper discusses the U.S. EPA's program, underway at International Fuel Cells Corporation, to demonstrate landfill methane control and the fuel cell energy recovery concept. In this program, two critical issues are being addressed: (1) a landfill gas cleanup method that would ...

  4. High temperature polymer electrolyte membrane fuel cells

    DEFF Research Database (Denmark)

    This book is a comprehensive review of high-temperature polymer electrolyte membrane fuel cells (PEMFCs). PEMFCs are the preferred fuel cells for a variety of applications such as automobiles, cogeneration of heat and power units, emergency power and portable electronics. The first 5 chapters...

  5. A Method of Operating a Fuel Cell

    DEFF Research Database (Denmark)

    2013-01-01

    The present invention relates to a method of determining the net water drag coefficient (rd) in a fuel cell. By measuring the velocity of the fluid stream at the outlet of the anode, rd can be determined. Real time monitoring and adjustments of the water balance of a fuel cell may be therefore...

  6. FCTESTNET - Testing fuel cells for transportation

    NARCIS (Netherlands)

    Winkel, R.G.; Foster, D.L.; Smokers, R.T.M.

    2006-01-01

    FCTESTNET (Fuel Cell Testing and Standardization Network) is an ongoing European network project within Framework Program 5. It is a three-year project that commenced January 2003, with 55 partners from European research centers, universities, and industry, working in the field of fuel cell R and D.

  7. Renewable energies - Fuel cell and hydrogen

    International Nuclear Information System (INIS)

    The objectives of the IPEN program are based on the MCT (Brazilian Ministry of Science and Technology) national program, contributing significantly to the national development in this area. The program comprises three main areas of interest: PEMFC (Proton Exchange Membrane Fuel Cell); SOFC(Solid Oxide Fuel Cell); and H2-Production, mainly from ethanol reforming

  8. Organic fuel cell methods and apparatus

    Science.gov (United States)

    Vamos, Eugene (Inventor); Surampudi, Subbarao (Inventor); Narayanan, Sekharipuram R. (Inventor); Frank, Harvey A. (Inventor); Halpert, Gerald (Inventor); Olah, George A. (Inventor); Prakash, G. K. Surya (Inventor)

    2008-01-01

    A liquid organic, fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion.TM.. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon.TM.-binder structure is immersed within a Nafion.TM./methanol bath to impregnate the electrode with Nafion.TM.. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.

  9. Stationary power fuel cell commercialization status worldwide

    Energy Technology Data Exchange (ETDEWEB)

    Williams, M.C. [Dept. of Energy, Morgantown, WV (United States)

    1996-12-31

    Fuel cell technologies for stationary power are set to play a role in power generation applications worldwide. The worldwide fuel cell vision is to provide powerplants for the emerging distributed generation and on-site markets. Progress towards commercialization has occurred in all fuel cell development areas. Around 100 ONSI phosphoric acid fuel cell (PAFC) units have been sold, with significant foreign sales in Europe and Japan. Fuji has apparently overcome its PAFC decay problems. Industry-driven molten carbonate fuel cell (MCFC) programs in Japan and the U.S. are conducting megawatt (MW)-class demonstrations, which are bringing the MCFC to the verge of commercialization. Westinghouse Electric, the acknowledged world leader in tubular solid oxide fuel cell (SOFC) technology, continues to set performance records and has completed construction of a 4-MW/year manufacturing facility in the U.S. Fuel cells have also taken a major step forward with the conceptual development of ultra-high efficiency fuel cell/gas turbine plants. Many SOFC developers in Japan, Europe, and North America continue to make significant advances.

  10. Corrosion free phosphoric acid fuel cell

    Science.gov (United States)

    Wright, Maynard K.

    1990-01-01

    A phosphoric acid fuel cell with an electrolyte fuel system which supplies electrolyte via a wick disposed adjacent a cathode to an absorbent matrix which transports the electrolyte to portions of the cathode and an anode which overlaps the cathode on all sides to prevent corrosion within the cell.

  11. DOE perspective on fuel cells in transportation

    Energy Technology Data Exchange (ETDEWEB)

    Kost, R.

    1996-04-01

    Fuel cells are one of the most promising technologies for meeting the rapidly growing demand for transportation services while minimizing adverse energy and environmental impacts. This paper reviews the benefits of introducing fuel cells into the transportation sector; in addition to dramatically reduced vehicle emissions, fuel cells offer the flexibility than use petroleum-based or alternative fuels, have significantly greater energy efficiency than internal combustion engines, and greatly reduce noise levels during operation. The rationale leading to the emphasis on proton-exchange-membrane fuel cells for transportation applications is reviewed as are the development issues requiring resolution to achieve adequate performance, packaging, and cost for use in automobiles. Technical targets for power density, specific power, platinum loading on the electrodes, cost, and other factors that become increasingly more demanding over time have been established. Fuel choice issues and pathways to reduced costs and to a renewable energy future are explored. One such path initially introduces fuel cell vehicles using reformed gasoline while-on-board hydrogen storage technology is developed to the point of allowing adequate range (350 miles) and refueling convenience. This scenario also allows time for renewable hydrogen production technologies and the required supply infrastructure to develop. Finally, the DOE Fuel Cells in Transportation program is described. The program, whose goal is to establish the technology for fuel cell vehicles as rapidly as possible, is being implemented by means of the United States Fuel Cell Alliance, a Government-industry alliance that includes Detroit`s Big Three automakers, fuel cell and other component suppliers, the national laboratories, and universities.

  12. Fuel cell power system for utility vehicle

    Energy Technology Data Exchange (ETDEWEB)

    Graham, M.; Barbir, F.; Marken, F.; Nadal, M. [Energy Partners, Inc., West Palm Beach, FL (United States)

    1996-12-31

    Based on the experience of designing and building the Green Car, a fuel cell/battery hybrid vehicle, and Genesis, a hydrogen/oxygen fuel cell powered transporter, Energy Partners has developed a fuel cell power system for propulsion of an off-road utility vehicle. A 10 kW hydrogen/air fuel cell stack has been developed as a prototype for future mass production. The main features of this stack are discussed in this paper. Design considerations and selection criteria for the main components of the vehicular fuel cell system, such as traction motor, air compressor and compressor motor, hydrogen storage and delivery, water and heat management, power conditioning, and control and monitoring subsystem are discussed in detail.

  13. Applicability of molten carbonate fuel cells to various fuels

    Science.gov (United States)

    Watanabe, Takao; Izaki, Yoshiyuki; Mugikura, Yoshihiro; Morita, Hiroshi; Yoshikawa, Masahiro; Kawase, Makoto; Yoshiba, Fumihiko; Asano, Koichi

    MCFCs can utilize CO rich and H 2 lean fuel, such as gasified biomass or gasified waste as a Pt catalyst is not used and Pt poisoning by CO does not occur. This feature has become very important due to the worldwide CO 2 depression requirements. CRIEPI has developed MCFC technologies in line with a governmental program, which mainly focused on natural gas fuel. However, CRIEPI has recently been focussing on technologies for various fuel applications. Single cells and stacks were tested with various gas compositions and showed stable performance even with high CO and high fuel utilization conditions. Gasified biomass or waste can contain many kinds of impurities such as H 2S, HCl, HF, NH 3, etc. The effects of these impurities were taken into account for single cells, and the permissible limits were estimated.

  14. ANODE CATALYST MATERIALS FOR USE IN FUEL CELLS

    DEFF Research Database (Denmark)

    2002-01-01

    a substrate material selected from Ru and Os; the respective components being present within specific ranges, display improved properties for use inanodes for low-temperature fuel cell anodes for PENFC fuel cells and direct methanol fuel cells....

  15. Market penetration scenarios for fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, C.E.; James, B.D.; Lomax, F.D. Jr. [Directed Technologies, Inc., Arlington, VA (United States)

    1997-12-31

    Fuel cell vehicles may create the first mass market for hydrogen as an energy carrier. Directed Technologies, Inc., working with the US Department of Energy hydrogen systems analysis team, has developed a time-dependent computer market penetration model. This model estimates the number of fuel cell vehicles that would be purchased over time as a function of their cost and the cost of hydrogen relative to the costs of competing vehicles and fuels. The model then calculates the return on investment for fuel cell vehicle manufacturers and hydrogen fuel suppliers. The model also projects the benefit/cost ratio for government--the ratio of societal benefits such as reduced oil consumption, reduced urban air pollution and reduced greenhouse gas emissions to the government cost for assisting the development of hydrogen energy and fuel cell vehicle technologies. The purpose of this model is to assist industry and government in choosing the best investment strategies to achieve significant return on investment and to maximize benefit/cost ratios. The model can illustrate trends and highlight the sensitivity of market penetration to various parameters such as fuel cell efficiency, cost, weight, and hydrogen cost. It can also illustrate the potential benefits of successful R and D and early demonstration projects. Results will be shown comparing the market penetration and return on investment estimates for direct hydrogen fuel cell vehicles compared to fuel cell vehicles with onboard fuel processors including methanol steam reformers and gasoline partial oxidation systems. Other alternative fueled vehicles including natural gas hybrids, direct injection diesels and hydrogen-powered internal combustion hybrid vehicles will also be analyzed.

  16. Solid polymer MEMS-based fuel cells

    Science.gov (United States)

    Jankowski, Alan F.; Morse, Jeffrey D.

    2008-04-22

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  17. Solid oxide MEMS-based fuel cells

    Science.gov (United States)

    Jankowksi, Alan F.; Morse, Jeffrey D.

    2007-03-13

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  18. Chrysler Pentastar direct hydrogen fuel cell program

    Energy Technology Data Exchange (ETDEWEB)

    Kimble, M.; Deloney, D.

    1995-08-01

    The Chrysler Pentastar Electronics, Inc. Direct Hydrogen Fueled PEM Fuel Cell Hybrid Vehicle Program (DPHV) was initiated 1 July, 1994 with the following mission, {open_quotes}Design, fabricate, and test a Direct Hydrogen Fueled Proton Exchange Membrane (PEM) Fuel Cell System including onboard hydrogen storage, an efficient lightweight fuel cell, a gas management system, peak power augmentation and a complete system controls that can be economically mass produced and comply with all safety environmental and consumer requirements for vehicle applications for the 21st century.{close_quotes} The Conceptual Design for the entire system based upon the selection of an applicable vehicle and performance requirements that are consistent with the PNGV goals will be discussed. A Hydrogen Storage system that has been selected, packaged, and partially tested in accordance with perceived Hydrogen Safety and Infrastructure requirements will be discussed in addition to our Fuel Cell approach along with design of the {open_quotes}real{close_quotes} module. The Gas Management System and the Load Leveling System have been designed and the software programs have been developed and will be discussed along with a complete fuel cell test station that has the capability to test up to a 60 kW fuel cell system.

  19. Continental glaciation and its potential impact on a used-fuel disposal vault in the Canadian Shield

    Energy Technology Data Exchange (ETDEWEB)

    Ates, Y.; Bruneau, D.; Ridgway, W.R

    1997-09-01

    AECL has been assessing the concept of nuclear fuel waste disposal in a vault excavated at a depth ranging between 500 m and 1000 m in a plutonic rock mass of the Canadian Shield. Glaciation is a natural process that has occurred in the past, and is likely to occur in the future, thus causing changes in the loading conditions on the rock mass hosting the disposal vault. Because the rock mass is a natural barrier to the migration of radionuclides, it is important to evaluate its integrity under load changes caused by the glaciation process. Assuming that the magnitude and extent of the future glaciation will be similar to those of the past, we have reviewed published data pertaining to the last continental ice sheet that covered a large area of North America. Estimates have been madefor the magnitude of stresses due to ice sheet loading for a vault located at depths of 500 to 1000 m. These analyses have shown that the uniform loading of a continental ice sheet would reduce the deviatoric stresses in the Canadian Shield, creating more favourable conditions than those existing at the present time, namely, high horizontal stresses. The effects of surface erosion and increase in the in-situ shear stresses have also been examined. Based on the existing data and structural modelling studies, there would be no significant structural effect on a disposal vault located at 1000-m depth in a plutonic rock. At its maximum size, an ice sheet comparable to the Laurentide ice sheet could reactivate the faults and fracture zones along the perimeter areas. Our analyses have been based on fully drained conditions only. At a potential disposal site, it would be important also to consider the potential for excess pore pressure in the analyses. (author)

  20. Reversible (unitized) PEM fuel cell devices

    Energy Technology Data Exchange (ETDEWEB)

    Mitlitsky, F; Myers, B; Smith, W F; Weisberg, Molter, T M

    1999-06-01

    Regenerative fuel cells (RFCs) are enabling for many weight-critical portable applications, since the packaged specific energy (>400 Wh/kg) of properly designed lightweight RFC systems is several-fold higher than that of the lightest weight rechargeable batteries. RFC systems can be rapidly refueled (like primary fuel cells), or can be electrically recharged (like secondary batteries) if a refueling infrastructure is not conveniently available. Higher energy capacity systems with higher performance, reduced weight, and freedom from fueling infrastructure are the features that RFCs promise for portable applications. Reversible proton exchange membrane (PEM) fuel cells, also known as unitized regenerative fuel cells (URFCs), or reversible regenerative fuel cells, are RFC systems which use reversible PEM cells, where each cell is capable of operating both as a fuel cell and as an electrolyzer. URFCs further economize portable device weight, volume, and complexity by combining the functions of fuel cells and electrolyzers in the same hardware, generally without any system performance or efficiency reduction. URFCs are being made in many forms, some of which are already small enough to be portable. Lawrence Livermore National Laboratory (LLNL) has worked with industrial partners to design, develop, and demonstrate high performance and high cycle life URFC systems. LLNL is also working with industrial partners to develop breakthroughs in lightweight pressure vessels that are necessary for URFC systems to achieve the specific energy advantages over rechargeable batteries. Proton Energy Systems, Inc. (Proton) is concurrently developing and commercializing URFC systems (UNIGEN' product line), in addition to PEM electrolyzer systems (HOGEN' product line), and primary PEM fuel cell systems. LLNL is constructing demonstration URFC units in order to persuade potential sponsors, often in their own conference rooms, that advanced applications based on URFC s are

  1. Micro PEM Fuel Cells and Stacks

    Institute of Scientific and Technical Information of China (English)

    Shou-shing; Hsieh

    2007-01-01

    1 Results The effects of different operating parameters on micro proton exchange membrane (PEM) fuel cell performance were experimentally studied for three different flow field configurations (interdigitated,mesh,and serpentine).Experiments with different cell operating temperatures and different backpressures on the H2 flow channels,as well as various combinations of these parameters,have been conducted for three different flow geometries.The micro PEM fuel cells were designed and fabricated in-house t...

  2. The fuel cell yesterday, today and tomorrow

    Directory of Open Access Journals (Sweden)

    Stanojević Dušan D.

    2005-01-01

    Full Text Available The fuel cell has some characteristics of a battery carrying out direct chemical conversion into electric energy. In relation to classical systems used for chemical energy conversion into electric power, through heat energy and mechanical operation, the fuel cell has considerably higher efficiency. The thermo-mechanical conversion of chemical into electric energy, in thermal power plants is carried out with 30% efficiency, while the efficiency of chemical conversion into electric energy, using a fuel cell is up to 60%. With the exception of the space programme, the commercial usage of the fuel cell did not exist up to 1990, when the most developed countries started extensive financial support of this source of energy. By 1995, more than a hundred fuel cells were installed in the process of electricity generation in Europe, USA and Japan, while nowadays there are thousands of installations, of efficient energetic capacity. Because of its superior characteristics, the fuel cell compared to other commercial electric energy producers, fulfills the most important condition - it does not pollute or if it does, the level is minimal. With such characteristics the fuel cell can help solve the growing conflict between the further economic development of mankind and the preservation of a clean and healthy natural environment.

  3. Nanocrystalline cerium oxide materials for solid fuel cell systems

    Energy Technology Data Exchange (ETDEWEB)

    Brinkman, Kyle S

    2015-05-05

    Disclosed are solid fuel cells, including solid oxide fuel cells and PEM fuel cells that include nanocrystalline cerium oxide materials as a component of the fuel cells. A solid oxide fuel cell can include nanocrystalline cerium oxide as a cathode component and microcrystalline cerium oxide as an electrolyte component, which can prevent mechanical failure and interdiffusion common in other fuel cells. A solid oxide fuel cell can also include nanocrystalline cerium oxide in the anode. A PEM fuel cell can include cerium oxide as a catalyst support in the cathode and optionally also in the anode.

  4. Progress in carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Krumpelt, M.; Roche, M.F.

    1995-08-01

    Our objective is to increase both the life and power of the molten carbonate fuel cell (MCFC) by developing improved components and designs. Current activities are as follows: (1) Development of lithium ferrate (LiFeO{sub 2}) and lithium cobaltate (LiCoO{sub 2}) cathodes for extended MCFC life, particularly in pressurized operation, where the present cathode, NiO, provides insufficient life; (2) Development of distributed-manifold MCFC designs for increased volumetric power density and decreased temperature gradients (and, therefore, increased life); (3) Development of components and designs appropriate for high-power-density operation (>2 kW/m{sup 2} and >100 kW/m{sup 3} in an integrated MCFC system); and (4) Studies of pitting corrosion of the stainless-steel interconnects and aluminized seals now being employed in the MCFC (alternative components will also be studied). Each of these activities has the potential to reduce the MCFC system cost significantly. Progress in each activity will be presented during the poster session.

  5. Fuel cells. Citations from the NTIS data base

    Science.gov (United States)

    Cavagnaro, D. M.

    1980-08-01

    Fuel cell applications, components, fabrication, design, catalysts, and chemistry are covered. The citations discuss different types of fuel cells such as hydrogen oxygen cells, hydrocarbon air cells, and biochemical cells.

  6. Micro & nano-engineering of fuel cells

    CERN Document Server

    Leung, Dennis YC

    2015-01-01

    Fuel cells are clean and efficient energy conversion devices expected to be the next generation power source. During more than 17 decades of research and development, various types of fuel cells have been developed with a view to meet the different energy demands and application requirements. Scientists have devoted a great deal of time and effort to the development and commercialization of fuel cells important for our daily lives. However, abundant issues, ranging from mechanistic study to system integration, still need to be figured out before massive applications can be used. Miniaturizatio

  7. Sealant materials for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Krumpelt, M.

    1995-08-01

    The objective of this work is to complete the development of soft glass-ceramic sealants for the solid oxide fuel cell (SOFC). Among other requirements, the materials must soften at the operation temperature of the fuel cell (600-1000{degrees}C) to relieve stresses between stack components, and their thermal expansions must be tailored to match those of the stack materials. Specific objectives included addressing the needs of industrial fuel cell developers, based on their evaluation of samples we supply, as well as working with commercial glass producers to achieve scaled-up production of the materials without changing their properties.

  8. In-membrane micro fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Omosebi, Ayokunle; Besser, Ronald

    2016-09-06

    An in-membrane micro fuel cell comprises an electrically-insulating membrane that is permissive to the flow of cations, such as protons, and a pair of electrodes deposited on channels formed in the membrane. The channels are arranged as conduits for fluids, and define a membrane ridge between the channels. The electrodes are porous and include catalysts for promoting the liberation of a proton and an electron from a chemical species and/or or the recombination of a proton and an electron with a chemical specie. The fuel cell may be provided a biosensor, an electrochemical sensor, a microfluidic device, or other microscale devices fabricated in the fuel cell membrane.

  9. Non-noble metal fuel cell catalysts

    CERN Document Server

    Chen, Zhongwei; Zhang, Jiujun

    2014-01-01

    Written and edited by a group of top scientists and engineers in the field of fuel cell catalysts from both industry and academia, this book provides a complete overview of this hot topic. It covers the synthesis, characterization, activity validation and modeling of different non-noble metal and metalfree electrocatalysts for the reduction of oxygen, as well as their integration into acid or alkaline polymer exchange membrane (PEM) fuel cells and their performance validation, while also discussing those factors that will drive fuel cell commercialization. With its well-structured app

  10. Proton-exchange membrane regenerative fuel cells

    Science.gov (United States)

    Swette, Larry L.; LaConti, Anthony B.; McCatty, Stephen A.

    This paper will update the progress in developing electrocatalyst systems and electrode structures primarily for the positive electrode of single-unit solid polymer proton-exchange membrane (PEM) regenerative fuel cells. The work was done with DuPont Nafion 117 in complete fuel cells (40 cm 2 electrodes). The cells were operated alternately in fuel cell mode and electrolysis mode at 80°C. In fuel cell mode, humidified hydrogen and oxygen were supplied at 207 kPa (30 psi); in electrolysis mode, water was pumped over the positive electrode and the gases were evolved at ambient pressure. Cycling data will be presented for Pt-Ir catalysts and limited bifunctional data will be presented for Pt. Ir, Ru. Rh and Na xPt 3O 4 catalysts as well as for electrode structure variations.

  11. Swiss fuel cell passenger and pleasure boats

    Energy Technology Data Exchange (ETDEWEB)

    Affolter, J.-F.

    2000-07-01

    This paper published by the University of Applied Science in Yverdon-les-Bains, Switzerland, looks at the development of electrically driven small boats that are powered by fuel cells. The various implementations of the test boats are described. Starting with a 100-watt PEM fuel cell built by the Paul Scherrer Institute (PSI) and the University of Applied Science in Solothurn, Switzerland, for educational purposes, a small pedal-boat was electrified. The paper describes the development of four further prototypes and introduces a new project for a 6-passenger leisure boat powered by a 2 kW PEFC fuel cell. Apart from the fuel cells, various other components such as propellers and control electronics are discussed as are the remaining problems still to be solved before the cells and boats can be marketed. Since they were carried out at a technical university, these projects are said to have provided an excellent way of teaching new technologies to students.

  12. Method for Making a Fuel Cell

    Science.gov (United States)

    Cable, Thomas L. (Inventor); Setlock, John A. (Inventor); Farmer, Serene C. (Inventor)

    2014-01-01

    The invention is a novel solid oxide fuel cell (SOFC) stack comprising individual bi-electrode supported fuel cells in which an electrolyte layer is supported between porous electrodes. The porous electrodes may be made from graded pore ceramic tape that has been created by the freeze cast method followed by freeze-drying. Each piece of graded pore tape later becomes a graded pore electrode scaffold that, subsequent to sintering, is made into either an anode or a cathode. The electrode scaffold comprising the anode includes a layer of liquid metal. The pores of the electrode scaffolds gradually increase in diameter as the layer extends away from the electrolyte layer. As a result of this diameter increase, any forces that would tend to pull the liquid metal away from the electrolyte are reduced while maintaining a diffusion path for the fuel. Advantageously, the fuel cell of the invention may utilize a hydrocarbon fuel without pre-processing to remove sulfur.

  13. Fuel cells for electric power generation

    International Nuclear Information System (INIS)

    After having first briefly illustrated the basic design, construction and operating principles of fuel cells, this paper assesses the progress that has been achieved to date in the development of the phosphoric acid (PAFC), molten carbonate (MCFC) and solid oxide (SOFC) fuel cells. Special attention is given to the design, performance and cost characteristics of the phosphoric acid fuel cells. For example, the paper cites the IFC/Toshiba 4.8 and 11.0 MW models, which have attained efficiencies of 37.5 and 41.0% respectively, and points out that these fuel cells, with efficiencies comparable to those of conventional poly-fuelled and combined cycle power plants, offer the advantages of compact size and better environmental compatibility with respect to the latter. However, fuel cells cannot yet compete with the lower per kWh costs of fossil fuel power plants. The paper concludes with an assessment of Italian fuel cell commercialization efforts, especially those centered around the use of methane fuelled PAFC's, and reviews the status of coordinated international research programs involving Japan, the USA and Italy

  14. Development of a 400 W High Temperature PEM Fuel Cell Power Pack:Fuel Cell Stack Test

    OpenAIRE

    Andreasen, Søren Juhl; Bang, Mads; Korsgaard, Anders; Nielsen, Mads Pagh; Kær, Søren Knudsen

    2006-01-01

    When using pressurized hydrogen to fuel a fuel cell, much space is needed for fuel storage. This is undesirable especially with mobile or portable fuel cell systems, where refuelling also often is inconvenient. Using a reformed liquid carbonhydrate can reduce this fuel volume considerably. Nafion based low temperature PEM (LTPEM) fuel cells are very intolerant to reformate gas because of the presence of CO. PBI based high temperature PEM (HTPEM) fuel cells can operate stable at much higher CO...

  15. Opportunities for portable Ballard Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Voss, H.H.; Huff, J.R. [Ballard Power Systems Inc., Burnaby, British Columbia (Canada)

    1996-12-31

    With the increasing proliferation and sophistication of portable electronic devices in both commercial and military markets, the need has arisen for small, lightweight power supplies that can provide increased operating life over those presently available. A solution to this power problem is the development of portable Ballard Fuel Cell power systems that operate with a hydrogen fuel source and air. Ballard has developed PEM fuel cell stacks and power systems in the 25 to 100 watt range for both of these markets. For military use, Ballard has teamed with Ball Corporation and Hydrogen Consultants, Inc. and has provided the Ballard Fuel Cell stack for an ambient PEM fuel cell power system for the DoD. The system provides power from idle to I 00 watts and has the capability of delivering overloads of 125 watts for short periods of time. The system is designed to operate over a wide range of temperature, relative humidity and altitude. Hydrogen is supplied as a compressed gas, metal hydride or chemical hydride packaged in a unit that is mated to the power/control unit. The hydrogen sources provide 1.5, 5 and 15 kWh of operation, respectively. The design of the fuel cell power system enables the unit to operate at 12 volts or 24 volts depending upon the equipment being used. For commercial applications, as with the military, fuel cell power sources in the 25 to 500 watt range will be competing with advanced batteries. Ambient PEM fuel cell designs and demonstrators are being developed at 25 watts and other low power levels. Goals are minimum stack volume and weight and greatly enhanced operating life with reasonable system weight and volume. This paper will discuss ambient PEM fuel cell designs and performance and operating parameters for a number of power levels in the multiwatt range.

  16. High temperature polymer electrolyte membrane fuel cell

    Institute of Scientific and Technical Information of China (English)

    K.Scott; M. Mamlouk

    2006-01-01

    One of the major issues limiting the introduction of polymer electrolyte membrane fuel cells (PEMFCs) is the low temperature of operation which makes platinum-based anode catalysts susceptible to poisoning by the trace amount of CO, inevitably present in reformed fuel. In order to alleviate the problem of CO poisoning and improve the power density of the cell, operating at temperature above 100 ℃ is preferred. Nafion(R) -type perfluorosulfonated polymers have been typically used for PEMFC. However, the conductivity of Nafion(R) -type polymers is not high enough to be used for fuel cell operations at higher temperature ( > 90 ℃) and atmospheric pressure because they dehydrate under these condition.An additional problem which faces the introduction of PEMFC technology is that of supplying or storing hydrogen for cell operation,especially for vehicular applications. Consequently the use of alternative fuels such as methanol and ethanol is of interest, especially if this can be used directly in the fuel cell, without reformation to hydrogen. A limitation of the direct use of alcohol is the lower activity of oxidation in comparison to hydrogen, which means that power densities are considerably lower. Hence to improve activity and power output higher temperatures of operation are preferable. To achieve this goal, requires a new polymer electrolyte membrane which exhibits stability and high conductivity in the absence of liquid water.Experimental data on a polybenzimidazole based PEMFC were presented. A simple steady-state isothermal model of the fuel cell is also used to aid in fuel cell performance optimisation. The governing equations involve the coupling of kinetic, ohmic and mass transport. This paper also considers the advances made in the performance of direct methanol and solid polymer electrolyte fuel cells and considers their limitations in relation to the source and type of fuels to be used.

  17. Optimum Performance of Direct Hydrogen Hybrid Fuel Cell Vehicles

    OpenAIRE

    Zhao, Hengbing; Burke, Andy

    2009-01-01

    Proton Exchange Membrane fuel cell (PEMFC) technology is one of the most attractive candidates for transportation applications due to its inherently high efficiency and high power density. However, the fuel cell system efficiency can suffer because of the need for forced air supply and water-cooling systems. Hence the operating strategy of the fuel cell system can have a significant impact on the fuel cell system efficiency and thus vehicle fuel economy. The key issues are how the fuel cell b...

  18. Fuel cells make gains in power generation market

    International Nuclear Information System (INIS)

    The ultra-low emission, highly efficient natural gas-fueled fuel cell system is beginning to penetrate the electric power generation market in the US and abroad as the fuel cell industry lowers product costs. And, even as the current market continues to grow, fuel cell companies are developing new technology with even higher levels of energy efficiency. The paper discusses fuel cell efficiency, business opportunities, work to reduce costs, and evolving fuel cell technology

  19. Carbon fuel cells with carbon corrosion suppression

    Science.gov (United States)

    Cooper, John F.

    2012-04-10

    An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

  20. Fuel cells: A handbook (Revision 3)

    Energy Technology Data Exchange (ETDEWEB)

    Hirschenhofer, J.H.; Stauffer, D.B.; Engleman, R.R.

    1994-01-01

    Fuel cells are electrochemical devices that convert the chemical energy of reaction directly into electrical energy. In a typical fuel cell, gaseous fuels are fed continuously to the anode (negative electrode) compartment and an oxidant (i.e., oxygen from air) is fed continuously to the cathode (positive electrode) compartment; the electrochemical reactions take place at the electrodes to produce an electric current. A fuel cell, although having similar components and several characteristics, differs from a typical battery in several respects. The battery is an energy storage device, that is, the maximum energy that is available is determined by the amount of chemical reactant stored within the battery itself. Thus, the battery will cease to produce electrical energy when the chemical reactants are consumed (i.e., discharged). In a secondary battery, the reactants are regenerated by recharging, which involves putting energy into the battery from an external source. The fuel cell, on the other hand, is an energy conversion device which theoretically has the capability of producing electrical energy for as long as the fuel and oxidant are supplied to the electrodes. In reality, degradation or malfunction of components limits the practical operating life of fuel cells.

  1. Environmental Impact of Fuel Cell Manufacture

    Energy Technology Data Exchange (ETDEWEB)

    Hart, N.T.; Day, M.J. [Rolls-Royce Strategic Research Centre, PO Box 31, Derby, DE24 8BJ (United Kingdom); Brandon, N.P. [T.H.Huxley School of Environment, Earth Sciences and Engineering, Imperial College of Science Technology and Medicine, London, SW7 2BP (United Kingdom); Shemilt, J.E. [Dept. of Materials Engineering, Brunel University, Uxbridge, UB8 3PH (United Kingdom)

    2000-07-01

    Fuel Cells potentially offer environmental benefits when compared to conventional technology but it is important to consider the full environmental impact including the manufacturing and disposal steps. This paper describes a case study that compares the energy requirements for Solid Oxide Fuel Cell fabrication routes. The results show that that, when compared to the benefits during use, the associated environmental impact is relatively small. Therefore the choice of manufacturing routes will have little effect on the overall advantage of implementing Fuel Cell systems. The total environmental impact of fuel cell fabrication will also include the production of materials. This could contribute a large share of the total environmental burden, however it could be minimised by adopting a design that allows the materials to be recycled in an efficient manner. (author)

  2. Direct formate fuel cells: A review

    Science.gov (United States)

    An, L.; Chen, R.

    2016-07-01

    Direct formate fuel cells (DFFC), which convert the chemical energy stored in formate directly into electricity, are recently attracting more attention, primarily because of the use of the carbon-neutral fuel and the low-cost electrocatalytic and membrane materials. As an emerging energy technology, the DFFC has made a rapid progress in recent years (currently, the state-of-the-art power density is 591 mW cm-2 at 60 °C). This article provides a review of past research on the development of this type of fuel cell, including the working principle, mechanisms and materials of the electrocatalytic oxidation of formate, singe-cell designs and performance, as well as innovative system designs. In addition, future perspectives with regard to the development of this fuel cell system are also highlighted.

  3. CO tolerance of polymer electrolyte fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Gubler, L.; Scherer, G.G.; Wokaun, A. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    Reformed methanol can be used as a fuel for polymer electrolyte fuel cells instead of pure hydrogen. The reformate gas contains mainly H{sub 2}, CO{sub 2} in the order of 20% and low levels of CO in the order of 100 ppm. CO causes severe voltage losses due to poisoning of the anode catalyst. The effect of CO on cell performance was investigated at different CO levels up to 100 ppm. Various options to improve the CO tolerance of the fuel cell were assessed thereafter, of which the injection of a few percents of oxygen into the fuel feed stream proved to be most effective. By mixing 1% of oxygen with hydrogen containing 100 ppm CO, complete recovery of the cell performance could be attained. (author) 2 figs., 2 tabs., 3 refs.

  4. Modular fuel-cell stack assembly

    Science.gov (United States)

    Patel, Pinakin

    2010-07-13

    A fuel cell assembly having a plurality of fuel cells arranged in a stack. An end plate assembly abuts the fuel cell at an end of said stack. The end plate assembly has an inlet area adapted to receive an exhaust gas from the stack, an outlet area and a passage connecting the inlet area and outlet area and adapted to carry the exhaust gas received at the inlet area from the inlet area to the outlet area. A further end plate assembly abuts the fuel cell at a further opposing end of the stack. The further end plate assembly has a further inlet area adapted to receive a further exhaust gas from the stack, a further outlet area and a further passage connecting the further inlet area and further outlet area and adapted to carry the further exhaust gas received at the further inlet area from the further inlet area to the further outlet area.

  5. The quiet revolution: decentralisation and fuel cells

    International Nuclear Information System (INIS)

    This article discusses how major changes in the electricity supply industry can take place in the next few years due to market liberalisation and efforts to reduce the emission of greenhouse gasses. Decentralisation is discussed as being a 'mega-trend' and fuel cells in particular are emphasised as being a suitable means of generating heat and power locally, i.e. where they are needed. Also, the ecological advantages of using natural gas to 'fire' the fuel cell units that are to complement or replace coal-fired or gas-fired combined gas and steam-turbine power stations is discussed. Various types of fuel cell are briefly described. Market developments in the USA, where the power grid is extensive and little reserve capacity is available, are noted. New designs of fuel cell are briefly examined and it is noted that electricity utilities, originally against decentralisation, are now beginning to promote this 'quiet revolution'

  6. Platinum-ruthenium-nickel fuel cell electrocatalyst

    Science.gov (United States)

    Gorer, Alexander

    2005-07-26

    A catalyst suitable for use in a fuel cell, especially as an anode catalyst, that contains platinum, ruthenium, and nickel, wherein the nickel is at a concentration that is less than about 10 atomic percent.

  7. High Efficiency Reversible Fuel Cell Power Converter

    DEFF Research Database (Denmark)

    Pittini, Riccardo

    entitled "High Efficiency Reversible Fuel Cell Power Converter" and it presents the design of a high efficiency dc-dc converter developed and optimized for bidirectional fuel cell applications. First, a brief overview of fuel cell and energy storage technologies is presented. Different system topologies...... as well as different dc-ac and dc-dc converter topologies are presented and analyzed. A new ac-dc topology for high efficiency data center applications is proposed and an efficiency characterization based on the fuel cell stack I-V characteristic curve is presented. The second part discusses the main...... of magnetic components especially for large production volumes. At last, the complete converter design is presented in detailed and characterized in efficiency terms. Both benefits, provided by SiC power devices and by a redesign of the converter layout increased the converter power density up to 2.2 k...

  8. Operating a fuel cell using landfill gas

    Energy Technology Data Exchange (ETDEWEB)

    Trippel, C.E.; Preston, J.L. Jr.; Trocciola, J.; Spiegel, R.

    1996-12-31

    An ONSI PC25{trademark}, 200 kW (nominal capacity) phosphoric acid fuel cell operating on landfill gas is installed at the Town of Groton Flanders Road landfill in Groton, Connecticut. This joint project by the Connecticut Light & Power Company (CL&P) which is an operating company of Northeast Utilities, the Town of Groton, International Fuel Cells (IFC), and the US EPA is intended to demonstrate the viability of installing, operating and maintaining a fuel cell operating on landfill gas at a landfill site. The goals of the project are to evaluate the fuel cell and gas pretreatment unit operation, test modifications to simplify the GPU design and demonstrate reliability of the entire system.

  9. Fuel-Cell Structure Prevents Membrane Drying

    Science.gov (United States)

    Mcelroy, J.

    1986-01-01

    Embossed plates direct flows of reactants and coolant. Membrane-type fuel-cell battery has improved reactant flow and heat removal. Compact, lightweight battery produces high current and power without drying of membranes.

  10. Hydrogen storage and integrated fuel cell assembly

    Science.gov (United States)

    Gross, Karl J.

    2010-08-24

    Hydrogen is stored in materials that absorb and desorb hydrogen with temperature dependent rates. A housing is provided that allows for the storage of one or more types of hydrogen-storage materials in close thermal proximity to a fuel cell stack. This arrangement, which includes alternating fuel cell stack and hydrogen-storage units, allows for close thermal matching of the hydrogen storage material and the fuel cell stack. Also, the present invention allows for tailoring of the hydrogen delivery by mixing different materials in one unit. Thermal insulation alternatively allows for a highly efficient unit. Individual power modules including one fuel cell stack surrounded by a pair of hydrogen-storage units allows for distribution of power throughout a vehicle or other electric power consuming devices.

  11. Diesel fueled ship propulsion fuel cell demonstration project

    Energy Technology Data Exchange (ETDEWEB)

    Kumm, W.H. [Arctic Energies Ltd., Severna Park, MD (United States)

    1996-12-31

    The paper describes the work underway to adapt a former US Navy diesel electric drive ship as a 2.4 Megawatt fuel cell powered, US Coast Guard operated, demonstrator. The Project will design the new configuration, and then remove the four 600 kW diesel electric generators and auxiliaries. It will design, build and install fourteen or more nominal 180 kW diesel fueled molten carbonate internal reforming direct fuel cells (DFCs). The USCG cutter VINDICATOR has been chosen. The adaptation will be carried out at the USCG shipyard at Curtis Bay, MD. A multi-agency (state and federal) cooperative project is now underway. The USCG prime contractor, AEL, is performing the work under a Phase III Small Business Innovation Research (SBIR) award. This follows their successful completion of Phases I and II under contract to the US Naval Sea Systems (NAVSEA) from 1989 through 1993 which successfully demonstrated the feasibility of diesel fueled DFCs. The demonstrated marine propulsion of a USCG cutter will lead to commercial, naval ship and submarine applications as well as on-land applications such as diesel fueled locomotives.

  12. Development of a lateral PEM fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Gruber, Karl; Kronberger, Hermann; Fafilek, Guenter [ECHEM Center of Competence in Applied Electrochemistry, Viktor Kaplanstr.2, A-2700 Wiener Neustadt (Austria); University of Technology Vienna, Institute of Chemical Technologies and Analytic/EC 164, Getreidemarkt 9/164, A-1060 Vienna (Austria); Loibl, Helmut; Schlauf, Thomas [FOTEC Forschungs und Technologietransfer GmbH, Viktor Kaplanstr.2, A-2700 Wiener Neustadt (Austria); Pallanits, Josef [HTP High Tech Plastics AG, A-7201 Neudoerfl (Austria); Gornik, Christian [Battenfeld Kunststoffmaschinen GmbH, Wiener Neustaedterstrasse 81, A-2542 Kottingbrunn (Austria); Nauer, Gerhard [ECHEM Center of Competence in Applied Electrochemistry, Viktor Kaplanstr.2, A-2700 Wiener Neustadt (Austria); University of Vienna, Institute for Physical Chemistry, Waehringerstr. 42, A-1090 Vienna (Austria)

    2007-06-15

    A novel lateral PEM fuel cell was developed. The anodes and cathodes are situated nearby each other on a polymer electrolyte membrane. The transport of the protons takes place in a lateral way in the membrane. All manufacturing steps of the lateral PEM fuel cell were designed to meet the requirements of mass production. The base plate being the central part was made by means of polymer micro injection moulding. (author)

  13. The fuel cell yesterday, today and tomorrow

    OpenAIRE

    Stanojević Dušan D.; Tomić Milorad V.

    2005-01-01

    The fuel cell has some characteristics of a battery carrying out direct chemical conversion into electric energy. In relation to classical systems used for chemical energy conversion into electric power, through heat energy and mechanical operation, the fuel cell has considerably higher efficiency. The thermo-mechanical conversion of chemical into electric energy, in thermal power plants is carried out with 30% efficiency, while the efficiency of chemical conversion into electric energy, usin...

  14. Reviews on Solid Oxide Fuel Cell Technology

    OpenAIRE

    Apinan Soottitantawat; Arnornchai Arpornwichanop; Worapon Kiatkittipong; Wisitsree Wiyaratn; Navadol Laosiripojana; Suttichai Assabumrungrat

    2009-01-01

    Solid Oxide Fuel Cell (SOFC) is one type of high temperature fuel cell that appears to be one of the most promising technology to provide the efficient and clean energy production for wide range of applications (from small units to large scale power plants). This paper reviews the current status and related researches on SOFC technologies. In details, the research trend for the development of SOFC components(i.e. anode, electrolyte, cathode, and interconnect) are presented. Later, the current...

  15. European opportunities for fuel cell commercialisation

    Science.gov (United States)

    Gibbs, C. E.; Steel, M. C. F.

    1992-01-01

    The European electricity market is changing. This paper will look at the background to power generation in Europe and highlight the recent factors which have entered the market to promote change. The 1990s seem to offer great possibilities for fuel cell commercialisation. Awareness of environmental problems has never been greater and there is growing belief that fuel cell technology can contribute to solving some of these problems. Issues which have caused the power industry in Europe to re-think its methods of generation include: concern over increasing carbon dioxide emissions and their contribution to the greenhouse effect; increasing SO x and NO x emissions and the damage cause by acid rain; the possibility of adverse effects on health caused by high voltage transmission lines; environmental restrictions to the expansion of hydroelectric schemes; public disenchantment with nuclear power following the Chernobyl accident; avoidance of dependence on imported oil following the Gulf crisis and a desire for fuel flexibility. All these factors are hastening the search for clean, efficient, modular power generators which can be easily sited close to the electricity consumer and operated using a variety of fuels. It is not only the power industry which is changing. A tightening of the legislation concerning emissions from cars is encouraging European auto companies to develop electric vehicles, some of which may be powered by fuel cells. Political changes, such as the opening up of Eastern Europe will also expand the market for low-emission, efficient power plants as attempts are made to develop and clean up that region. Many Europeans organisations are re-awakening their interest, or strengthening their activities, in the area of fuel cells because of the increasing opportunities offered by the European market. While some companies have chosen to buy, test and demonstrate Japanese or American fuel cell stacks with the aim of gaining operational experience and

  16. Considerations in managing the assessment of the Canadian nuclear fuel waste disposal concept

    International Nuclear Information System (INIS)

    This paper reports that in developing a concept for disposal of Canada's nuclear fuel waste, AECL has faced challenges because the acceptability of the concept must be established before a site is selected, no agency has been made responsible for implementing the concept if it is selected, and many stakeholders in the review must be satisfied if the concept is to be accepted. The challenges have thus far been met by a program that is well-integrated technically and administratively. However, interactions with stakeholders reviewing the concept present a problem in communication. The authors believe the nature of the nuclear fuel waste disposal issue calls for a cooperative rather than an adversarial approach to problem solving to efficiently deal with the requirements of all the stakeholders

  17. Starch and cellulose as fuel sources for low temperature direct mode fuel cells

    OpenAIRE

    Spets, J.-P; KIROS, YOHANNES; Kuosa, M. A.; Rantanen, J; Sallinen, J.; Lampinen, M. J.; Saari, K

    2008-01-01

    This paper is a study about a direct mode fuel cell with a near-neutral-state and alkaline electrolytes. The aim of study was to develop a fuel cell, which operates directly by mixing the fuel with the electrolyte. This arrangement helps to avoid inserting membranes and additional bacterial cultures in fuel cell. The target is also to create a fuel cell with a capacity of few mWcm-2 with the starch as a fuel. Also, glucose and sorbitol have been tested as fuel for the fuel cell. QC 20111124

  18. Tubular solid oxide fuel cell current collector

    Science.gov (United States)

    Bischoff, Brian L.; Sutton, Theodore G.; Armstrong, Timothy R.

    2010-07-20

    An internal current collector for use inside a tubular solid oxide fuel cell (TSOFC) electrode comprises a tubular coil spring disposed concentrically within a TSOFC electrode and in firm uniform tangential electrical contact with the electrode inner surface. The current collector maximizes the contact area between the current collector and the electrode. The current collector is made of a metal that is electrically conductive and able to survive under the operational conditions of the fuel cell, i.e., the cathode in air, and the anode in fuel such as hydrogen, CO, CO.sub.2, H.sub.2O or H.sub.2S.

  19. DOE Hydrogen and Fuel Cells Program Plan (September 2011)

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2011-09-01

    The Department of Energy Hydrogen and Fuel Cells Program Plan outlines the strategy, activities, and plans of the DOE Hydrogen and Fuel Cells Program, which includes hydrogen and fuel cell activities within the EERE Fuel Cell Technologies Program and the DOE offices of Nuclear Energy, Fossil Energy, and Science.

  20. Proceedings of the fuel cells `95 review meeting

    Energy Technology Data Exchange (ETDEWEB)

    George, T.J.

    1995-08-01

    This document contains papers presented at the Fuel Cells `95` Review Meeting. Topics included solid oxide fuel cells; DOE`s transportation program; ARPA advanced fuel cell development; molten carbonate fuel cells; and papers presented at a poster session. Individual papers have been processed separately for the U.S. DOE databases.

  1. PEM Fuel Cells from Single Cell to Stack - Fundamental, Modeling, Analysis, and Applications

    OpenAIRE

    Maher A.R. Sadiq Al-Baghdadi

    2015-01-01

    Part I: Fundamentals Chapter 1: Introduction. Chapter 2: PEM fuel cell thermodynamics, electrochemistry, and performance. Chapter 3: PEM fuel cell components. Chapter 4: PEM fuel cell failure modes. Part II: Modeling and Simulation Chapter 5: PEM fuel cell models based on semi-empirical simulation. Chapter 6: PEM fuel cell models based on computational fluid dynamics (CFD). Part III: Analysis Chapter 7: PEM fuel cell analysis. Chapter 8: PEM fuel cell stack desig...

  2. High power density carbonate fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Yuh, C.; Johnsen, R.; Doyon, J.; Allen, J. [Energy Research Corp., Danbury, CT (United States)

    1996-12-31

    Carbonate fuel cell is a highly efficient and environmentally clean source of power generation. Many organizations worldwide are actively pursuing the development of the technology. Field demonstration of multi-MW size power plant has been initiated in 1996, a step toward commercialization before the turn of the century, Energy Research Corporation (ERC) is planning to introduce a 2.85MW commercial fuel cell power plant with an efficiency of 58%, which is quite attractive for distributed power generation. However, to further expand competitive edge over alternative systems and to achieve wider market penetration, ERC is exploring advanced carbonate fuel cells having significantly higher power densities. A more compact power plant would also stimulate interest in new markets such as ships and submarines where space limitations exist. The activities focused on reducing cell polarization and internal resistance as well as on advanced thin cell components.

  3. Advanced containment research for the Canadian Nuclear Fuel Waste Management Program

    International Nuclear Information System (INIS)

    This document outlines the program on the development of advanced containment systems for the disposal of used fuel in a vault deep in plutonic rock. Possible advanced containment concepts, the strategy adopted in selecting potential container materials, and experimental programs currently underway or planned are presented. Most effort is currently directed toward developing long-term containment systems based on non-metallic materials and massive metal containers. The use of additional independent barriers to extend the lifetime of simple containment systems is also being evaluated. 58 refs

  4. Status of commercial fuel cell powerplant system development

    Science.gov (United States)

    Warshay, Marvin

    The primary focus is on the development of commercial Phosphoric Acid Fuel Cell (PAFC) powerplant systems because the PAFC, which has undergone extensive development, is currently the closest fuel cell system to commercialization. Shorter discussions are included on the high temperature fuel cell systems which are not as mature in their development, such as the Molten Carbonate Fuel Cell (MCFC) and the Solid Oxide Fuel Cell (SOFC). The alkaline and the Solid Polymer Electrolyte (SPE) fuel cell systems, are also included, but their discussions are limited to their prospects for commercial development. Currently, although the alkaline fuel cell continues to be used for important space applications there are no commercial development programs of significant size in the USA and only small efforts outside. The market place for fuel cells and the status of fuel cell programs in the USA receive extensive treatment. The fuel cell efforts outside the USA, especially the large Japanese programs, are also discussed.

  5. Thorium-Based Fuels Preliminary Lattice Cell Studies for Candu Reactors

    International Nuclear Information System (INIS)

    The choice of nuclear power as a major contributor to the future global energy needs must take into account acceptable risks of nuclear weapon proliferation, in addition to economic competitiveness, acceptable safety standards, and acceptable waste disposal options. Candu reactors offer a proven technology, safe and reliable reactor technology, with an interesting evolutionary potential for proliferation resistance, their versatility for various fuel cycles creating premises for a better utilization of global fuel resources. Candu reactors impressive degree of fuel cycle flexibility is a consequence of its channel design, excellent neutron economy, on-power refueling, and simple fuel bundle. These features facilitate the introduction and exploitation of various fuel cycles in Candu reactors in an evolutionary fashion. The main reasons for our interest in Thorium-based fuel cycles have been, globally, to extend the energy obtainable from natural Uranium and, locally, to provide a greater degree of energy self-reliance. Applying the once through Thorium (OTT) cycle in existing and advanced Candu reactors might be seen as an evaluative concept for the sustainable development both from the economic and waste management points of view. Two Candu fuel bundles project will be used for the proposed analysis, namely the Candu standard fuel bundle with 37 fuel elements and the CANFLEX fuel bundle with 43 fuel elements. Using the Canadian proposed scheme - loading mixed ThO2-SEU CANFLEX bundles in Candu 6 reactors - simulated at lattice cell level led to promising conclusions on operation at higher fuel burnups, reduction of the fissile content to the end of the cycle, minor actinide content reduction in the spent fuel, reduction of the spent fuel radiotoxicity, presence of radionuclides emitting strong gamma radiation for proliferation resistance benefit. The calculations were performed using the lattice codes WIMS and Dragon (together with the corresponding nuclear data

  6. Computation of a Canadian SCWR unit cell with deterministic and Monte Carlo codes

    International Nuclear Information System (INIS)

    The Canadian SCWR has the potential to achieve the goals that the generation IV nuclear reactors must meet. As part of the optimization process for this design concept, lattice cell calculations are routinely performed using deterministic codes. In this study, the first step (self-shielding treatment) of the computation scheme developed with the deterministic code DRAGON for the Canadian SCWR has been validated. Some options available in the module responsible for the resonance self-shielding calculation in DRAGON 3.06 and different microscopic cross section libraries based on the ENDF/B-VII.0 evaluated nuclear data file have been tested and compared to a reference calculation performed with the Monte Carlo code SERPENT under the same conditions. Compared to SERPENT, DRAGON underestimates the infinite multiplication factor in all cases. In general, the original Stammler model with the Livolant-Jeanpierre approximations are the most appropriate self-shielding options to use in this case of study. In addition, the 89 groups WIMS-AECL library for slight enriched uranium and the 172 groups WLUP library for a mixture of plutonium and thorium give the most consistent results with those of SERPENT. (authors)

  7. State of the States: Fuel Cells in America, 2010

    Energy Technology Data Exchange (ETDEWEB)

    Curtin, Sandra; Delmont, Elizabeth; Gangi, Jennifer

    2010-04-01

    This report, written by Fuel Cells 2000 and partially funded by the U.S. Department of Energy's Fuel Cell Technologies Program, provides a snapshot of fuel cell and hydrogen activity in the 50 states and District of Columbia. It features the top five fuel cell states (in alphabetical order): California, Connecticut, New York, Ohio, and South Carolina. State activities reported include supportive fuel cell and hydrogen policies, installations and demonstrations, road maps, and level of activism.

  8. Direct fuel cell product design improvement

    Energy Technology Data Exchange (ETDEWEB)

    Maru, H.C.; Farooque, M. [Energy Research Corp., Danbury, CT (United States)

    1996-12-31

    Significant milestones have been attained towards the technology development field testing and commercialization of direct fuel cell power plant since the 1994 Fuel Cell Seminar. Under a 5-year cooperative agreement with the Department of Energy signed in December 1994, Energy Research Corporation (ERC) has been developing the design for a MW-scale direct fuel cell power plant with input from previous technology efforts and the Santa Clara Demonstration Project. The effort encompasses product definition in consultation with the Fuel Cell Commercialization Group, potential customers, as well as extensive system design and packaging. Manufacturing process improvements, test facility construction, cell component scale up, performance and endurance improvements, stack engineering, and critical balance-of-plant development are also addressed. Major emphasis of this product design improvement project is on increased efficiency, compactness and cost reduction to establish a competitive place in the market. A 2.85 MW power plant with an efficiency of 58% and a footprint of 420 m{sup 2} has been designed. Component and subsystem testing is being conducted at various levels. Planning and preparation for verification of a full size prototype unit are in progress. This paper presents the results obtained since the last fuel cell seminar.

  9. Dimethoxymethane and trimethoxymethane as alternative fuels for fuel cells

    Science.gov (United States)

    Chetty, Raghuram; Scott, Keith

    The electrooxidation of dimethoxymethane (DMM) and trimethoxymethane (TMM) was studied at different platinum-based electrocatalysts deposited onto a titanium mesh substrate by thermal decomposition of chloride precursors. Half-cell tests showed an increase in oxidation current for the methoxy fuels at the platinum electrode with the alloying of ruthenium and tin. Increase in reaction temperature and reactant concentration showed an increase in current density for the mesh-based anodes similar to carbon-supported catalysts. Single fuel cell tests, employing the titanium mesh anode with PtRu and PtSn catalysts showed maximum power densities up to 31 mW cm -2 and 48 mW cm -2 for 1.0 mol dm -3 aqueous solutions of DMM and TMM, respectively at 60 °C using oxygen.

  10. Direct Carbon Fuel Cell System Utilizing Solid Carbonaceous Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Turgut Gur

    2010-04-30

    This 1-year project has achieved most of its objective and successfully demonstrated the viability of the fluidized bed direct carbon fuel cell (FB-DCFC) approach under development by Direct Carbon technologies, LLC, that utilizes solid carbonaceous fuels for power generation. This unique electrochemical technology offers high conversion efficiencies, produces proportionately less CO{sub 2} in capture-ready form, and does not consume or require water for gasification. FB-DCFC employs a specialized solid oxide fuel cell (SOFC) arrangement coupled to a Boudouard gasifier where the solid fuel particles are fluidized and reacted by the anode recycle gas CO{sub 2}. The resulting CO is electrochemically oxidized at the anode. Anode supported SOFC structures employed a porous Ni cermet anode layer, a dense yttria stabilized zirconia membrane, and a mixed conducting porous perovskite cathode film. Several kinds of untreated solid fuels (carbon and coal) were tested in bench scale FBDCFC prototypes for electrochemical performance and stability testing. Single cells of tubular geometry with active areas up to 24 cm{sup 2} were fabricated. The cells achieved high power densities up to 450 mW/cm{sup 2} at 850 C using a low sulfur Alaska coal char. This represents the highest power density reported in the open literature for coal based DCFC. Similarly, power densities up to 175 mW/cm{sup 2} at 850 C were demonstrated with carbon. Electrical conversion efficiencies for coal char were experimentally determined to be 48%. Long-term stability of cell performance was measured under galvanostatic conditions for 375 hours in CO with no degradation whatsoever, indicating that carbon deposition (or coking) does not pose any problems. Similar cell stability results were obtained in coal char tested for 24 hours under galvanostatic conditions with no sign of sulfur poisoning. Moreover, a 50-cell planar stack targeted for 1 kW output was fabricated and tested in 95% CO (balance CO{sub 2

  11. A transient fuel cell model to simulate HTPEM fuel cell impedance spectra

    DEFF Research Database (Denmark)

    Vang, Jakob Rabjerg; Andreasen, Søren Juhl; Kær, Søren Knudsen

    2011-01-01

    This paper presents a spatially resolved transient fuel cell model applied to the simulation of high temperature PEM fuel cell impedance spectra. The model is developed using a 2D finite volume method approach. The model is resolved along the channel and across the membrane. The model considers...

  12. The potential for vault-induced seismicity in nuclear fuel waste disposal: experience from Canadian mines

    International Nuclear Information System (INIS)

    A seismic event which causes damage to an underground opening is called a rockburst. Practical experience indicates that these damaging seismic events are associated with deep mines where extraction ratios are greater than 0.6. For the arrangement being considered by AECL for nuclear fuel waste disposal vaults, extraction ratios, for the room and pillar design, will be less than 0.3. At this extraction ratio the stress magnitudes will not be sufficient to induce seismic events that can damage the underground openings. Documented world-wide experience shows that unless the underground opening is very close to the source of a naturally occurring seismic event, such as an earthquake, the opening will also not experience any significant damage. Backfilling a disposal vault will improve its resistance to earthquake damage. Backfilling a disposal vault will also reduce the total convergence of the openings caused by thermal loads and hence minimize the potential for thermally-induced seismic events. (author)

  13. Performance of miniaturized direct methanol fuel cell (DMFC) devices using micropump for fuel delivery

    Science.gov (United States)

    Zhang, Tao; Wang, Qing-Ming

    A fuel cell is a device that can convert chemical energy into electricity directly. Among various types of fuel cells, both polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs) can work at low temperature (mini pumps, the size of the piezoelectric micropump is much smaller and the energy consumption is much lower. Thus, it is very viable and effective to use a piezoelectric valveless micropump for fuel delivery in miniaturized DMFC power systems.

  14. Pressurized solid oxide fuel cell testing

    Energy Technology Data Exchange (ETDEWEB)

    Basel, R.A.; Pierre, J.F.

    1995-08-01

    The goals of the SOFC pressurized test program are to obtain cell voltage versus current (VI) performance data as a function of pressure; to evaluate the effects of operating parameters such as temperature, air stoichiometry, and fuel utilization on cell performance, and to demonstrate long term stability of the SOFC materials at elevated pressures.

  15. Inorganic salt mixtures as electrolyte media in fuel cells

    Science.gov (United States)

    Angell, Charles Austen (Inventor); Belieres, Jean-Philippe (Inventor); Francis-Gervasio, Dominic (Inventor)

    2012-01-01

    Fuel cell designs and techniques for converting chemical energy into electrical energy uses a fuel cell are disclosed. The designs and techniques include an anode to receive fuel, a cathode to receive oxygen, and an electrolyte chamber in the fuel cell, including an electrolyte medium, where the electrolyte medium includes an inorganic salt mixture in the fuel cell. The salt mixture includes pre-determined quantities of at least two salts chosen from a group consisting of ammonium trifluoromethanesulfonate, ammonium trifluoroacetate, and ammonium nitrate, to conduct charge from the anode to the cathode. The fuel cell includes an electrical circuit operatively coupled to the fuel cell to transport electrons from the cathode.

  16. Large stationary fuel cell systems: Status and dynamic requirements

    Science.gov (United States)

    Bischoff, Manfred

    Molten carbonate fuel cell demonstrations to-date, have been able to show the highest fuel-to-electricity conversion efficiencies (>50%) of any stand-alone fuel cell type. The primary developer of this type of fuel cell in United States is Fuel Cell Energy Corporation (FCE), the developer and manufacturer of the Direct FuelCell ™ concept. FCE and MTU CFC Solutions in Germany, a licensee of FCE have demonstrated carbonate fuel cells from 10 kW to 2 MW of electrical output on a variety of fuels. IHI in Japan are also developing carbonate fuel cells for stationary power and have recently successfully demonstrated the technology in Kawagoe, Japan. In Italy, Ansaldo fuel cell have demonstrated a 100 kW carbonate fuel cell in Milan. In Korea, the Ministry of Commerce, Industry and Energy has committed to install 300 fuel cell units, sized 250 kW to 1 MW, for distributed power generation by 2012. Carbonate fuel cell technology is more fuel flexible than lower temperature fuel cell technologies and is well suited for on-site stationary CHP applications as well as to marine, military, and traction applications. The present paper gives an overview about the commercialisation efforts for the molten carbonate fuel cell technology.

  17. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    Energy Technology Data Exchange (ETDEWEB)

    H.C. Maru; M. Farooque

    2005-03-01

    The program was designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE, formerly Energy Research Corporation) from an early state of development for stationary power plant applications. The current program efforts were focused on technology and system development, and cost reduction, leading to commercial design development and prototype system field trials. FCE, in Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations, or at distributed locations near the customers such as hospitals, schools, universities, hotels and other commercial and industrial applications. FCE has designed three different fuel cell power plant models (DFC300A, DFC1500 and DFC3000). FCE's power plants are based on its patented DFC{reg_sign} technology, where a hydrocarbon fuel is directly fed to the fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to the existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating and air conditioning. Several sub-MW power plants based on the DFC design are currently operating in Europe, Japan and the US. Several one-megawatt power plant design was verified by operation on natural gas at FCE. This plant is currently installed at a customer site in King County, WA under another US government program and is currently in operation. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and

  18. Silicon Based Direct Methanol Fuel Cells

    OpenAIRE

    Larsen, Jackie Vincent; Thomsen, Erik Vilain

    2013-01-01

    The purpose of this project has been to investigate and fabricate small scale Micro Direct Methanol Fuel Cells (μDMFC). They are investigated as a possible alternative for Zinc-air batteries in small size consumer devices such as hearing aids. In such devices the conventional rechargeable batteries such as lithium-ion batteries have insufficiently low energy density. Methanol is a promising fuel for such devices due to the high energy density and ease of refueling compared to charging batteri...

  19. SAVANNAH RIVER NATIONAL LABORATORYREGENERATIVE FUEL CELL PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Motyka, T

    2008-11-11

    A team comprised of governmental, academic and industrial partners led by the Savannah River National Laboratory developed and demonstrated a regenerative fuel cell system for backup power applications. Recent market assessments have identified emergency response and telecommunication applications as promising near-term markets for fuel cell backup power systems. The Regenerative Fuel Cell System (RFC) consisted of a 2 kg-per-day electrolyzer, metal-hydride based hydrogen storage units and a 5 kW fuel cell. Coupling these components together created a system that can produce and store its own energy from the power grid much like a rechargeable battery. A series of test were conducted to evaluate the performance of the RFC system under both steady-state and transit conditions that might be encountered in typical backup power applications. In almost all cases the RFC functioned effectively. Test results from the demonstration project will be used to support recommendations for future fuel cell and hydrogen component and system designs and support potential commercialization activities. In addition to the work presented in this report, further testing of the RFC system at the Center for Hydrogen Research in Aiken County, SC is planned including evaluating the system as a renewable system coupled with a 20kW-peak solar photovoltaic array.

  20. Model-based Interpretation of the Performance and Degradation of Reformate Fueled Solid Oxide Fuel Cells

    OpenAIRE

    Kromp, Alexander

    2013-01-01

    Solid oxide fuel cells offer great prospects for the sustainable, clean and safe conversion of various fuels into electrical energy. In this thesis, the performance-determining loss processes for the cell operation on reformate fuels are elucidated via electrochemical impedance spectroscopy. Model-based analyses reveal the electrochemical fuel oxidation mechanism, the coupling of fuel gas transport and reforming chemistry and the impact of fuel impurities on the degradation of each loss process.

  1. Hybrid fuel cells technologies for electrical microgrids

    Energy Technology Data Exchange (ETDEWEB)

    San Martin, Jose Ignacio; Zamora, Inmaculada; San Martin, Jose Javier; Aperribay, Victor; Eguia, Pablo [Department of Electrical Engineering, University of the Basque Country, Alda. de Urquijo, s/n, 48013 Bilbao (Spain)

    2010-09-15

    Hybrid systems are characterized by containing two or more electrical generation technologies, in order to optimize the global efficiency of the processes involved. These systems can present different operating modes. Besides, they take into account aspects that not only concern the electrical and thermal efficiencies, but also the reduction of pollutant emissions. There is a wide range of possible configurations to form hybrid systems, including hydrogen, renewable energies, gas cycles, vapour cycles or both. Nowadays, these technologies are mainly used for energy production in electrical microgrids. Some examples of these technologies are: hybridization processes of fuel cells with wind turbines and photovoltaic plants, cogeneration and trigeneration processes that can be configured with fuel cell technologies, etc. This paper reviews and analyses the main characteristics of electrical microgrids and the systems based on fuel cells for polygeneration and hybridization processes. (author)

  2. Novel Fuel Cells for Coal Based Systems

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Tao

    2011-12-31

    The goal of this project was to acquire experimental data required to assess the feasibility of a Direct Coal power plant based upon an Electrochemical Looping (ECL) of Liquid Tin Anode Solid Oxide Fuel Cell (LTA-SOFC). The objective of Phase 1 was to experimentally characterize the interaction between the tin anode, coal fuel and cell component electrolyte, the fate of coal contaminants in a molten tin reactor (via chemistry) and their impact upon the YSZ electrolyte (via electrochemistry). The results of this work will provided the basis for further study in Phase 2. The objective of Phase 2 was to extend the study of coal impurities impact on fuel cell components other than electrolyte, more specifically to the anode current collector which is made of an electrically conducting ceramic jacket and broad based coal tin reduction. This work provided a basic proof-of-concept feasibility demonstration of the direct coal concept.

  3. Progress in Electrolyte-Free Fuel Cells

    Directory of Open Access Journals (Sweden)

    Yuzheng eLu

    2016-05-01

    Full Text Available Solid Oxide Fuel Cell (SOFC represents a clean electrochemical energy conversion technology with characteristics of high conversion efficiency and low emissions. It is one of the most important new energy technologies in the future. However, the manufacture of SOFCs based on the structure of anode/electrolyte/cathode is complicated and time-consuming. Thus, the cost for the entire fabrication and technology is too high to be affordable and challenges still hinder commercialization. Recently, a novel type of Electrolyte -free fuel cell (EFFC with single component was invented which could be the potential candidate for the next generation of advanced fuel cells. This paper briefly introduces the EFFC, working principle, performance and advantages with updated research progress. A number of key R&D issues about EFFCs have been addressed and future opportunities and challenges are discussed.

  4. Fuel cell power trains for road traffic

    Science.gov (United States)

    Höhlein, Bernd; Biedermann, Peter; Grube, Thomas; Menzer, Reinhard

    Legal regulations, especially the low emission vehicle (LEV) laws in California, are the driving forces for more intensive technological developments with respect to a global automobile market. In the future, high efficient vehicles at very low emission levels will include low temperature fuel cell systems (e.g., polymer electrolyte fuel cell (PEFC)) as units of hydrogen-, methanol- or gasoline-based electric power trains. In the case of methanol or gasoline/diesel, hydrogen has to be produced on-board using heated steam or partial oxidation reformers as well as catalytic burners and gas cleaning units. Methanol could also be used for direct electricity generation inside the fuel cell (direct methanol fuel cell (DMFC)). The development potentials and the results achieved so far for these concepts differ extremely. Based on the experience gained so far, the goals for the next few years include cost and weight reductions as well as optimizations in terms of the energy management of power trains with PEFC systems. At the same time, questions of fuel specification, fuel cycle management, materials balances and environmental assessment will have to be discussed more intensively. On the basis of process engineering analyses for net electricity generation in PEFC-powered power trains as well as on assumptions for both electric power trains and vehicle configurations, overall balances have been carried out. They will lead not only to specific energy demand data and specific emission levels (CO 2, CO, VOC, NO x) for the vehicle but will also present data of its full fuel cycle (FFC) in comparison to those of FFCs including internal combustion engines (ICE) after the year 2005. Depending on the development status (today or in 2010) and the FFC benchmark results, the advantages of balances results of FFC with PEFC vehicles are small in terms of specific energy demand and CO 2 emissions, but very high with respect to local emission levels.

  5. Solid Oxide Fuel Cell Stack Diagnostics

    DEFF Research Database (Denmark)

    Mosbæk, Rasmus Rode; Barfod, Rasmus Gottrup

    repeating units are reported and discussed. The performance and degradation of a 14-cell co-flow stack was monitored for more than 667 hours at steady operating conditions using the sequential impedance measurement setup. The stack was tested galvanostatically (at constant current) with 50% steam...... carried out on an experimental 14-cell SOFC stack at varying frequencies and fuel utilizations. The results illustrated that THD can be used to detect increasing non-linearities in the current-voltage characteristics of the stack when the stack suffers from fuel starvation by monitoring the stack sum...

  6. Fuel cell and advanced turbine power cycle

    Energy Technology Data Exchange (ETDEWEB)

    White, D.J. [Solar Turbines, Inc., San Diego, CA (United States)

    1995-10-19

    Solar Turbines, Incorporated (Solar) has a vested interest in the integration of gas turbines and high temperature fuel cells and in particular, solid oxide fuel cells (SOFCs). Solar has identified a parallel path approach to the technology developments needed for future products. The primary approach is to move away from the simple cycle industrial machines of the past and develop as a first step more efficient recuperated engines. This move was prompted by the recognition that the simple cycle machines were rapidly approaching their efficiency limits. Improving the efficiency of simple cycle machines is and will become increasingly more costly. Each efficiency increment will be progressively more costly than the previous step.

  7. Separator plate for a fuel cell

    Science.gov (United States)

    Petri, Randy J.; Meek, John; Bachta, Robert P.; Marianowski, Leonard G.

    1996-01-01

    A separator plate for a fuel cell comprising an anode current collector, a cathode current collector and a main plate, the main plate disposed between the anode current collector and the cathode current collector. The anode current collector forms a flattened peripheral wet seal structure and manifold wet seal structure on the anode side of the separator plate and the cathode current collector forms a flattened peripheral wet seal structure and manifold wet seal structure on the cathode side of the separator plate. In this manner, the number of components required to manufacture and assemble a fuel cell stack is reduced.

  8. Microfluidic fuel cells for energy generation.

    Science.gov (United States)

    Safdar, M; Jänis, J; Sánchez, S

    2016-08-01

    Sustainable energy generation is of recent interest due to a growing energy demand across the globe and increasing environmental issues caused by conventional non-renewable means of power generation. In the context of microsystems, portable electronics and lab-on-a-chip based (bio)chemical sensors would essentially require fully integrated, reliable means of power generation. Microfluidic-based fuel cells can offer unique advantages compared to conventional fuel cells such as high surface area-to-volume ratio, ease of integration, cost effectiveness and portability. Here, we summarize recent developments which utilize the potential of microfluidic devices for energy generation. PMID:27367869

  9. Fuel cells: a survey of current developments

    Science.gov (United States)

    Cropper, Mark A. J.; Geiger, Stefan; Jollie, David M.

    Since the first practical uses of fuel cells were developed, it has become clear that they could find use in many products over a wide power range of milliwatts to tens of megawatts. Throughout the 1990s, and later, there has been significant work carried out on adapting the various different fuel cell technologies for use in targetted consumer and industrial applications. This paper discusses these developments and gives details on the specific market segments for providing power to vehicles, portable devices and large- and small-scale stationary power generation.

  10. What Happens Inside a Fuel Cell? Developing an Experimental Functional Map of Fuel Cell Performance

    KAUST Repository

    Brett, Daniel J. L.

    2010-08-20

    Fuel cell performance is determined by the complex interplay of mass transport, energy transfer and electrochemical processes. The convolution of these processes leads to spatial heterogeneity in the way that fuel cells perform, particularly due to reactant consumption, water management and the design of fluid-flow plates. It is therefore unlikely that any bulk measurement made on a fuel cell will accurately represent performance at all parts of the cell. The ability to make spatially resolved measurements in a fuel cell provides one of the most useful ways in which to monitor and optimise performance. This Minireview explores a range of in situ techniques being used to study fuel cells and describes the use of novel experimental techniques that the authors have used to develop an \\'experimental functional map\\' of fuel cell performance. These techniques include the mapping of current density, electrochemical impedance, electrolyte conductivity, contact resistance and CO poisoning distribution within working PEFCs, as well as mapping the flow of reactant in gas channels using laser Doppler anemometry (LDA). For the high-temperature solid oxide fuel cell (SOFC), temperature mapping, reference electrode placement and the use of Raman spectroscopy are described along with methods to map the microstructural features of electrodes. The combination of these techniques, applied across a range of fuel cell operating conditions, allows a unique picture of the internal workings of fuel cells to be obtained and have been used to validate both numerical and analytical models. © 2010 Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.

  11. Regenerative fuel cell systems R and D

    Energy Technology Data Exchange (ETDEWEB)

    Mitlitsky, F.; Myers, B.; Weisberg, A.H. [Lawrence Livermore National Lab., Livermore, CA (United States)

    1998-08-01

    Regenerative fuel cell (RFC) systems produce power and electrolytically regenerate their reactants using stacks of electrochemical cells. Energy storage systems with extremely high specific energy (> 400 Wh/kg) have been designed that use lightweight pressure vessels to contain the gases generated by reversible (unitized) regenerative fuel cells (URFCs). Progress is reported on the development, integration, and operation of rechargeable energy storage systems with such high specific energy. Lightweight pressure vessels that enable high specific energies have been designed with performance factors (burst pressure/internal volume/tank weight) > 50 km (2.0 million inches), and a vessel with performance factor of 40 km (1.6 million inches) was fabricated. New generations of both advanced and industry-supplied hydrogen tankage are under development. A primary fuel cell test rig with a single cell (46 cm{sup 2} active area) has been modified and operated reversibly as a URFC (for up to 2010 cycles on a single cell). This URFC uses bifunctional electrodes (oxidation and reduction electrodes reverse roles when switching from charge to discharge, as with a rechargeable battery) and cathode feed electrolysis (water is fed from the hydrogen side of the cell). Recent modifications also enable anode feed electrolysis (water is fed from the oxygen side of the cell). Hydrogen/halogen URFCs, capable of higher round-trip efficiency than hydrogen/oxygen URFCs, have been considered, and will be significantly heavier. Progress is reported on higher performance hydrogen/oxygen URFC operation with reduced catalyst loading.

  12. Hydrogen Fuel Cell development in Columbia (SC)

    Energy Technology Data Exchange (ETDEWEB)

    Reifsnider, Kenneth [Univ. of South Carolina, Columbia, SC (United States); Chen, Fanglin [Univ. of South Carolina, Columbia, SC (United States); Popov, Branko [Univ. of South Carolina, Columbia, SC (United States); Chao, Yuh [Univ. of South Carolina, Columbia, SC (United States); Xue, Xingjian [Univ. of South Carolina, Columbia, SC (United States)

    2012-09-15

    This is an update to the final report filed after the extension of this program to May of 2011. The activities of the present program contributed to the goals and objectives of the Fuel Cell element of the Hydrogen, Fuel Cells and Infrastructure Technologies Program of the Department of Energy through five sub-projects. Three of these projects have focused on PEM cells, addressing the creation of carbon-based metal-free catalysts, the development of durable seals, and an effort to understand contaminant adsorption/reaction/transport/performance relationships at low contaminant levels in PEM cells. Two programs addressed barriers in SOFCs; an effort to create a new symmetrical and direct hydrocarbon fuel SOFC designs with greatly increased durability, efficiency, and ease of manufacturing, and an effort to create a multiphysics engineering durability model based on electrochemical impedance spectroscopy interpretations that associate the micro-details of how a fuel cell is made and their history of (individual) use with specific prognosis for long term performance, resulting in attendant reductions in design, manufacturing, and maintenance costs and increases in reliability and durability.

  13. Hydrogen Fuel Cell Development in Columbia (SC)

    Energy Technology Data Exchange (ETDEWEB)

    Reifsnider, Kenneth

    2011-07-31

    This is an update to the final report filed after the extension of this program to May of 2011. The activities of the present program contributed to the goals and objectives of the Fuel Cell element of the Hydrogen, Fuel Cells and Infrastructure Technologies Program of the Department of Energy through five sub-projects. Three of these projects have focused on PEM cells, addressing the creation of carbon-based metal-free catalysts, the development of durable seals, and an effort to understand contaminant adsorption/reaction/transport/performance relationships at low contaminant levels in PEM cells. Two programs addressed barriers in SOFCs; an effort to create a new symmetrical and direct hydrocarbon fuel SOFC designs with greatly increased durability, efficiency, and ease of manufacturing, and an effort to create a multiphysics engineering durability model based on electrochemical impedance spectroscopy interpretations that associate the micro-details of how a fuel cell is made and their history of (individual) use with specific prognosis for long term performance, resulting in attendant reductions in design, manufacturing, and maintenance costs and increases in reliability and durability.

  14. The Autohumidification Polymer Electrolyte Membrane Fuel Cell

    CERN Document Server

    Benziger, J B; Tulyani, S; Turner, A; Bocarsly, A B; Kevrekidis, Yu G

    2003-01-01

    A PEM fuel cell was specially constructed to determine kinetics under conditions of well-defined gas phase composition and cell temperature. Steady state multiplicity was discovered in the autohumidification PEM fuel cell, resulting from a balance between water production and water removal. Ignition was observed in the PEM fuel cell for a critical water activity of about 0.1. Ignition is a consequence of the exponential increase of proton conductivity with water activity, which creates an autocatalytic feedback between the water production and the proton conduction. The steady state current in the ignited state decreases with increasing temperature between 50 to 105 deg C. At temperatures greater than 70 deg C five steady states were observed in the PEM fuel cell. The steady state performance has been followed with variable load resistance and hysteresis loops have been mapped. The dynamics of transitions between steady states are slow about 10^3 to 10^4 s. These slow dynamics are suggested to result from a c...

  15. Proceedings of the Fourth Annual Fuel Cells Contractors Review Meeting

    Science.gov (United States)

    Huber, W. J.

    1992-07-01

    The objective of the program was to develop the essential technology for private sector commercialization of various fuel cell electrical generation systems, which promise high fuel efficiencies (40-60 percent), possibilities for cogeneration, modularity, possible urban siting, and low emissions. The purpose of this meeting was to provide the R and D participants in the DOE/Fossil Energy-sponsored Fuel Cells Program with a forum. With the near commercialization of phosphoric acid fuel cells, major emphasis was on molten carbonate and solid oxide fuel cells. Twenty-two papers were given in 3 formal sessions: molten carbonate fuel cells; solid oxide fuel cells; and systems and phosphoric acid. In addition, the proceedings also include a welcome to METC address and comments on the Fuel Cells Program from the viewpoint of EPRI and DOE's Vehicular Fuel Cell Program. Separate abstracts have been prepared.

  16. Proceedings of the fourth annual fuel cells contractors review meeting

    International Nuclear Information System (INIS)

    Objective of the program was to develop the essential technology for private sector commercialization of various fuel cell electrical generation systems, which promise high fuel efficiencies (40--60%), possibilities for cogeneration, modularity, possible urban siting, and low emissions. Purpose of this meeting was to provide the R and D participants in the DOE/Fossil Energy-sponsored Fuel Cells Program with a forum. With the near commercialization of phosphoric acid fuel cells, major emphasis was on molten carbonate and solid oxide fuel cells. 22 papers were given in 3 formal sessions: molten carbonate fuel cells; solid oxide fuel cells; and systems and phosphoric acid. In addition, the proceedings also include a welcome to METC address and comments on the Fuel Cells program from the viewpoint of EPRI and DOE's vehicular fuel cell program. Separate abstracts have been prepared

  17. Hybrid regenerative fuel cell systems for space applications

    Science.gov (United States)

    Saucier, David R.

    1988-01-01

    This paper describes a hybrid regenerative fuel cell (RFC) system for space application, which is made up of an alkaline fuel cell (Space Shuttle fuel cell) and an acid electrolysis unit (solid polymer electrolyte). In the RFC, gas produced from the acid electrolysis unit and water produced by the alkaline fuel cell are repeatedly reacted in the other unit. The results of RFC's tests indicate that the system is feasible in terms of fluid/unit compatibility. In addition, the fuel cell thermal-control system proved capable of controlling fuel cell temperatures throughout long open-circuit periods. Diagrams of the RFC and its subsystems are included.

  18. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    Science.gov (United States)

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

    2013-08-13

    A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  19. Solid Acid Fuel Cell Stack for APU Applications

    Energy Technology Data Exchange (ETDEWEB)

    Duong, Hau H. [SAFCell, Inc., Pasadena, CA (United States)

    2011-04-15

    Solid acid fuel cell technology affords the opportunity to operate at the 200-300 degree centigrade regime that would allow for more fuel flexibility, compared to polymer electrode membrane fuel cell, while avoiding the relatively more expensive and complex system components required by solid oxide fuel cell. This project addresses many factors such as MEA size scalability, fuel robustness, stability, etc., that are essential for successful commercialization of the technology.

  20. Past, present and future of fuel cells

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Though the fuel cell was invented by Grove in 1839,there are no commercially viable products at present.The development of fuel cells can be conveniently divided into three phases-exploratory phase(1839-1967).The main emphasis of the work is to increase the area of the three-phase interface at the electrode.The problem was solved by Bacon who invented the dual porosity,biporous nickel electrode.He demonstrated the first H2/O2 fuel cell(180℃,20atm).This cell was later improved and scaled up to power the Apollo lunar mission.However,the cost is too high for civilian applications and we come to the development phase (1967-2001).The main emphasis has been on the use of Teflon bonded electrodes and novel catalysts(PtRu,Pt/WO3 and Pt-Ru/WO3 anode catalyst for the anodic oxidation of impure H2 and methanol.In addition,the recent discovery of gadolinium doped ceria has reduced the operating temperature of solid oxide electrolytes to ~500℃ instead of 1 000℃.From 2001 onwards,we may be entering the breakthrough phase where the most favourable candidates are direct methanol vapor fuel cells and solid oxide electrolyte fuel cells.In the former case,there is a need to reduce the cross-over of methanol to the cathode compartment and the development of air cathode catalyst which are less affected by methanol and in the latter case,there is a need to improve the activity of the anode and cathode catalysts.

  1. Phosphoric acid doped polybenzimidazole membranes: Physiochemical characterization and fuel cell applications [PEM fuel cells

    DEFF Research Database (Denmark)

    Qingfeng, Li; Hjuler, Hans Aage; Bjerrum, Niels

    2001-01-01

    A polymer electrolyte membrane fuel cell operational at temperatures around 150-200 degrees C is desirable for fast electrode kinetics and high tolerance to fuel impurities. For this purpose polybenzimidazole (PBI) membranes have been prepared and H/sub 3/PO/sub 4/-doped in a doping range from 30...

  2. Tubular solid oxide fuel cell demonstration activities

    Energy Technology Data Exchange (ETDEWEB)

    Veyo, S.E.

    1995-08-01

    The development of a viable fuel cell driven electrical power generation system involves not only the development of cell and stack technology, but also the development of the overall system concept, the strategy for control, and the ancillary subsystems. The design requirements used to guide system development must reflect a customer focus in order to evolve a commercial product. In order to obtain useful customer feedback, Westinghouse has practiced the deployment with customers of fully integrated, automatically controlled, packaged solid oxide fuel cell power generation systems. These field units have served to demonstrate to customers first hand the beneficial attributes of the SOFC, to expose deficiencies through experience in order to guide continued development, and to garner real world feedback and data concerning not only cell and stack parameters, but also transportation, installation, permitting and licensing, start-up and shutdown, system alarming, fault detection, fault response, and operator interaction.

  3. Recent Advances in Enzymatic Fuel Cells: Experiments and Modeling

    Directory of Open Access Journals (Sweden)

    Ivan Ivanov

    2010-04-01

    Full Text Available Enzymatic fuel cells convert the chemical energy of biofuels into electrical energy. Unlike traditional fuel cell types, which are mainly based on metal catalysts, the enzymatic fuel cells employ enzymes as catalysts. This fuel cell type can be used as an implantable power source for a variety of medical devices used in modern medicine to administer drugs, treat ailments and monitor bodily functions. Some advantages in comparison to conventional fuel cells include a simple fuel cell design and lower cost of the main fuel cell components, however they suffer from severe kinetic limitations mainly due to inefficiency in electron transfer between the enzyme and the electrode surface. In this review article, the major research activities concerned with the enzymatic fuel cells (anode and cathode development, system design, modeling by highlighting the current problems (low cell voltage, low current density, stability will be presented.

  4. New tigers in the fuel cell tank

    Energy Technology Data Exchange (ETDEWEB)

    Service, R.F.

    2000-06-16

    At last researchers have made critical strides in developing commercially viable fuel cells that extract electricity from natural gas, ethane and other fossil fuels. A new generation of solid oxide fuel cells (SOFCs) such as that described in a paper by Hibino et al in this issue of Science (pp 2031-2033) convert hydrocarbons directly into electricity at low temperatures. New designs overcome the earlier problem of carbon atoms sticking to the anode of the cell and ruining it. Scott Barnett and his colleagues at Northwestern University in Evanston, Illinois, have used an atomic spray-painting technique to grow yttria-stabilized zirconia membranes much thinner than the standard 150 micrometer membranes so oxygen ions can slip through them at temperatures closer to 600{degree}C and also developed a nickel-spiked cerium-oxide anode that works at those temperatures. Lower operating temperatures mean fuel cells could be constructed from steel rather than costly heat-resistant alloys. Another group of researchers have developed a copper based anode that reduces carbon buildup. The novel design of Hibino's groups, at Nagoya University, Japan has a cerium oxide wafer with a nickel anode on one side and a ceramic composite cathode which passes oxygen to form ions which react at the anode to form CO{sub 2} water and electricity. 1 ref., 1 fig., 1 photo.

  5. Proton conducting membrane for fuel cells

    Science.gov (United States)

    Colombo, Daniel G.; Krumpelt, Michael; Myers, Deborah J.; Kopasz, John P.

    2007-03-27

    An ion conducting membrane comprising dendrimeric polymers covalently linked into a network structure. The dendrimeric polymers have acid functional terminal groups and may be covalently linked via linking compounds, cross-coupling reactions, or copolymerization reactions. The ion conducting membranes may be produced by various methods and used in fuel cells.

  6. FUEL CELL BUS DEMONSTRATION IN MEXICO CITY

    Science.gov (United States)

    The report discusses the performance of a cull-size, zero-emission, Proton Exchange Membrane (PEM) fuel-cell-powered transit bus in the atmospheric environment of Mexico City. To address the air quality problems caused by vehicle emissions in Mexico City, a seminar on clean vehic...

  7. Dendronized Polymer Architectures for Fuel Cell Membranes

    DEFF Research Database (Denmark)

    Nielsen, Mads Møller; Dimitrov, Ivaylo; Takamuku, S.;

    2013-01-01

    evaluated as PEMs for use in fuel cells by proton conductivity measurements, and in the case of dendronized architectures: thermal stability. The proposed synthetic strategy facilitates exploration of a non‐fluorous system with various flexible side chains where IEC is tunable by the degree of substitution....

  8. Diffuse Charge Effects in Fuel Cell Membranes

    NARCIS (Netherlands)

    Biesheuvel, P.M.; Franco, A.A.; Bazant, M.Z.

    2009-01-01

    It is commonly assumed that electrolyte membranes in fuel cells are electrically neutral, except in unsteady situations, when the double-layer capacitance is heuristically included in equivalent circuit calculations. Indeed, the standard model for electron transfer kinetics at the membrane/electrode

  9. Fuel Cells and Electrochemical Energy Storage.

    Science.gov (United States)

    Sammells, Anthony F.

    1983-01-01

    Discusses the nature of phosphoric acid, molten carbonate, and solid oxide fuel cells and major features and types of batteries used for electrical energy storage. Includes two tables presenting comparison of major battery features and summary of major material problems in the sodium-sulfur and lithium-alloy metal sulfide batteries. (JN)

  10. Microfabrication of Microchannels for Fuel Cell Plates

    Directory of Open Access Journals (Sweden)

    Ho Su Jang

    2009-12-01

    Full Text Available Portable electronic devices such as notebook computers, PDAs, cellular phones, etc., are being widely used, and they increasingly need cheap, efficient, and lightweight power sources. Fuel cells have been proposed as possible power sources to address issues that involve energy production and the environment. In particular, a small type of fuel-cell system is known to be suitable for portable electronic devices. The development of micro fuel cell systems can be achieved by the application of microchannel technology. In this study, the conventional method of chemical etching and the mechanical machining method of micro end milling were used for the microfabrication of microchannel for fuel cell separators. The two methods were compared in terms of their performance in the fabrication with regards to dimensional errors, flatness, straightness, and surface roughness. Following microchannel fabrication, the powder blasting technique is introduced to improve the coating performance of the catalyst on the surface of the microchannel. Experimental results show that end milling can remarkably increase the fabrication performance and that surface treatment by powder blasting can improve the performance of catalyst coating.

  11. Plant microbial fuel cell applied in wetlands

    NARCIS (Netherlands)

    Wetser, Koen; Liu, Jia; Buisman, Cees; Strik, David

    2015-01-01

    The plant microbial fuel cell (PMFC) has to be applied in wetlands to be able to generate electricity on a large scale. The objective of this PMFC application research is to clarify the differences in electricity generation between a Spartina anglica salt marsh and Phragmites australis peat soil

  12. Hydrogen as a fuel for fuel cell vehicles: A technical and economic comparison

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, J.; Steinbugler, M.; Kreutz, T. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies

    1997-12-31

    All fuel cells currently being developed for near term use in vehicles require hydrogen as a fuel. Hydrogen can be stored directly or produced onboard the vehicle by reforming methanol, ethanol or hydrocarbon fuels derived from crude oil (e.g., Diesel, gasoline or middle distillates). The vehicle design is simpler with direct hydrogen storage, but requires developing a more complex refueling infrastructure. In this paper, the authors compare three leading options for fuel storage onboard fuel cell vehicles: compressed gas hydrogen storage; onboard steam reforming of methanol; onboard partial oxidation (POX) of hydrocarbon fuels derived from crude oil. Equilibrium, kinetic and heat integrated system (ASPEN) models have been developed to estimate the performance of onboard steam reforming and POX fuel processors. These results have been incorporated into a fuel cell vehicle model, allowing us to compare the vehicle performance, fuel economy, weight, and cost for various fuel storage choices and driving cycles. A range of technical and economic parameters were considered. The infrastructure requirements are also compared for gaseous hydrogen, methanol and hydrocarbon fuels from crude oil, including the added costs of fuel production, storage, distribution and refueling stations. Considering both vehicle and infrastructure issues, the authors compare hydrogen to other fuel cell vehicle fuels. Technical and economic goals for fuel cell vehicle and hydrogen technologies are discussed. Potential roles for hydrogen in the commercialization of fuel cell vehicles are sketched.

  13. Ruthenium dissolution in direct methanol fuel cells

    OpenAIRE

    Schökel, Alexander

    2015-01-01

    The lifetime of a direct methanol fuel cell (DMFC) is mostly determined by the degradation of its active component, the membrane electrode assembly (MEA). Besides degradation of the proton conducting membrane, the aging of the electrodes and especially the catalysts therein is the major limiting factor. One of the catalyst degradation mechanisms is ruthenium dissolution. This work is the first extensive study on the dissolution, migration and deposition of ruthenium in a DMFC single cell d...

  14. Solid polymer electrolyte fuel cells

    International Nuclear Information System (INIS)

    The report summarizes the state of art of systems for energy production in electrical vehicles, looking into the general characteristics of electrodes and membranes. The water and thermal balance of the cell in relation to operative conditions, the pressure and temperature influence on the performance are examined. Special emphasis is given to the electrode characteristics-fabrication techniques and assembly of membrane electrodes. The problems related to the oxygen reduction kinetics at the cathode are examined, in relation to the fabrication techniques and to operative conditions of the cells. Finally, the possible alternative catalyzers for anode and cathode are reviewed

  15. Environmental catalysis: the Canadian situation

    Energy Technology Data Exchange (ETDEWEB)

    Aye, T.; Christensen, D.; Gostick, J.; Mogharei, A.; Oskin, G. O.; Won, W.; Aida, T. [Waterloo Univ. ON (Canada)

    2000-10-01

    The Canadian situation with respect to research in environmental catalysis was investigated by analyzing catalysis papers appearing in the 1999 and 2000 issues of major journals devoted to research in catalysis (Journal of Catalysis; Catalysis Today; Applied Catalysis A: General and B: Environmental). A total of 2150 papers were surveyed; of these 34 were by Canadian authors, with Canada ranking twentieth in the world in terms of research in this field. About 40 per cent of the catalysis papers were related to the environment, with nitrogen and sulphur emissions being the most important topics and energy conversion second. Hydrodesulphurization of petroleum oil, use of low sulphur coal and flue gas desulphurization are the principal processes for controlling sulfur emissions into the air, while nitrogen oxides emissions in automobiles are ccontrolled bt three-way catalysts. In power generation, selective catalytic reduction is the preferred method, although not in Canada, where installing low-NOx burners or using low nitrogen fuels such as natural gas are favored. The control of volatile organic compounds is also a serious problem. The two most promising processes for the Canadian situation are adsorption by activated carbon and catalysis using low-temperature catalysts. Water treatment of textile mill effluents, a favorite topics by Canadian authors, includes photocatalytic oxidation with titanium oxide photocatalyst, ozonation with activated carbons and a combination of photocatalysis and biological treatment. Carbon dioxide conversion was also a favoured topic by Canadian researchers; not surprising in view if the fact that Canada is the highest per capita producer of carbon dioxide emissions. Nearly two-thirds of the carbon dioxide emissions is due to the transportation and energy production sectors, therefore, any carbon dioxide mitigation strategies should be applied initially in these areas. Catalytic conversion of carbon dioxide into methanol, which then

  16. 2010 Fuel Cell Technologies Market Report, June 2011

    Energy Technology Data Exchange (ETDEWEB)

    2011-06-01

    This report summarizes 2010 data on fuel cells, including market penetration and industry trends. It also covers cost, price, and performance trends, along with policy and market drivers and the future outlook for fuel cells.

  17. Solid Oxide Fuel Cells: Technology Status

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Prabhakar; Minh, Nguyen Q.

    2004-08-01

    In its most common configuration, solid oxide fuel cell (SOFC) uses an oxygen ion conducting ceramic electrolyte membrane, perovskite cathode and nickel cermet anode electrode. Cells operate in the 600-1000 C temperature range and utilize metallic or ceramic current collectors for cell-to-cell interconnection. Recent development in engineered electrode architectures, component materials chemistry, cell and stack designs and fabrication processes have led to significant improvement in the electrical performance and performance stability as well as reduction in the operating temperature of such cells. Large kW-size power generation systems have been designed and field demonstrated. This paper reviews the status of SOFC power generation systems with emphasis on cell and stack component materials, electrode reactions, materials reactions and corrosion processes

  18. Solid Oxide Fuel Cell Auxiliary Power Unit

    International Nuclear Information System (INIS)

    Solid Oxide Fuel Cell (SOFC) is an attractive, efficient, clean source of power for transportation, military, and stationary applications. Delphi has pioneered its application as an auxiliary Power Unit (APU) for transportation. Delphi is also interested in marketing this technology for stationary applications. Its key advantages are high efficiency and compatibility with gasoline, natural gas and diesel fuel. It's consistent with mechanizations that support the trend to low emissions. Delphi is committed to working with customers and partners to bring this novel technology to market

  19. Tungsten based electrocatalyst for fuel cell applications

    Energy Technology Data Exchange (ETDEWEB)

    Christian, Joel B. [OSRAM SYLVANIA Inc., Global Tungsten and Powders R and D, Hawes Street, Towanda, PA 18848 (United States); Materials Science and Engineering, SUNY Binghamton, Binghamton, NY 13902 (United States); Smith, Sean P.E. [OSRAM SYLVANIA Inc., Global Tungsten and Powders R and D, Hawes Street, Towanda, PA 18848 (United States); Whittingham, M. Stanley [Materials Science and Engineering, SUNY Binghamton, Binghamton, NY 13902 (United States); Abruna, Hector D. [Cornell University, Department of Chemistry and Chemical Biology, Ithaca, NY 14653 (United States)

    2007-08-15

    A barrier to the widespread use of fuel cells is their reliance on expensive and scarce platinum and other precious metal catalysts. We present a catalyst for hydrogen oxidation, prepared electrochemically from high-purity aqueous tungstate salt precursors. The 24-electron reduction of ammonium metatungstate ((NH{sub 4}){sub 6}[H{sub 2}W{sub 12}O{sub 40}]) yields a material with electrocatalytic activity towards the oxidation of hydrogen in acid electrolyte which approaches 25% that of platinum. Moreover, the tungstate catalyst is unusually tolerant to CO and H{sub 2}S contaminants in the fuel stream. (author)

  20. Solid Oxide Fuel Cell Systems PVL Line

    Energy Technology Data Exchange (ETDEWEB)

    Susan Shearer - Stark State College; Gregory Rush - Rolls-Royce Fuel Cell Systems

    2012-05-01

    In July 2010, Stark State College (SSC), received Grant DE-EE0003229 from the U.S. Department of Energy (DOE), Golden Field Office, for the development of the electrical and control systems, and mechanical commissioning of a unique 20kW scale high-pressure, high temperature, natural gas fueled Stack Block Test System (SBTS). SSC worked closely with subcontractor, Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) over a 13 month period to successfully complete the project activities. This system will be utilized by RRFCS for pre-commercial technology development and training of SSC student interns. In the longer term, when RRFCS is producing commercial products, SSC will utilize the equipment for workforce training. In addition to DOE Hydrogen, Fuel Cells, and Infrastructure Technologies program funding, RRFCS internal funds, funds from the state of Ohio, and funding from the DOE Solid State Energy Conversion Alliance (SECA) program have been utilized to design, develop and commission this equipment. Construction of the SBTS (mechanical components) was performed under a Grant from the State of Ohio through Ohio's Third Frontier program (Grant TECH 08-053). This Ohio program supported development of a system that uses natural gas as a fuel. Funding was provided under the Department of Energy (DOE) Solid-state Energy Conversion Alliance (SECA) program for modifications required to test on coal synthesis gas. The subject DOE program provided funding for the electrical build, control system development and mechanical commissioning. Performance testing, which includes electrical commissioning, was subsequently performed under the DOE SECA program. Rolls-Royce Fuel Cell Systems is developing a megawatt-scale solid oxide fuel cell (SOFC) stationary power generation system. This system, based on RRFCS proprietary technology, is fueled with natural gas, and operates at elevated pressure. A critical success factor for development of the full scale system is the capability

  1. Fuel cell hybrid taxi life cycle analysis

    Energy Technology Data Exchange (ETDEWEB)

    Baptista, Patricia, E-mail: patricia.baptista@ist.utl.pt [IDMEC-Instituto Superior Tecnico, Universidade Tecnica de Lisboa, Av. Rovisco Pais, 1, 1049-001 Lisboa (Portugal); Ribau, Joao; Bravo, Joao; Silva, Carla [IDMEC-Instituto Superior Tecnico, Universidade Tecnica de Lisboa, Av. Rovisco Pais, 1, 1049-001 Lisboa (Portugal); Adcock, Paul; Kells, Ashley [Intelligent Energy, Charnwood Building, HolywellPark, Ashby Road, Loughborough, LE11 3GR (United Kingdom)

    2011-09-15

    A small fleet of classic London Taxis (Black cabs) equipped with hydrogen fuel cell power systems is being prepared for demonstration during the 2012 London Olympics. This paper presents a Life Cycle Analysis for these vehicles in terms of energy consumption and CO{sub 2} emissions, focusing on the impacts of alternative vehicle technologies for the Taxi, combining the fuel life cycle (Tank-to-Wheel and Well-to-Tank) and vehicle materials Cradle-to-Grave. An internal combustion engine diesel taxi was used as the reference vehicle for the currently available technology. This is compared to battery and fuel cell vehicle configurations. Accordingly, the following energy pathways are compared: diesel, electricity and hydrogen (derived from natural gas steam reforming). Full Life Cycle Analysis, using the PCO-CENEX drive cycle, (derived from actual London Taxi drive cycles) shows that the fuel cell powered vehicle configurations have lower energy consumption (4.34 MJ/km) and CO{sub 2} emissions (235 g/km) than both the ICE Diesel (9.54 MJ/km and 738 g/km) and the battery electric vehicle (5.81 MJ/km and 269 g/km). - Highlights: > A Life Cycle Analysis of alternative vehicle technologies for the London Taxi was performed. > The hydrogen powered vehicles have the lowest energy consumption and CO{sub 2} emissions results. > A hydrogen powered solution can be a sustainable alternative in a full life cycle framework.

  2. Electrolyte Additives for Phosphoric Acid Fuel Cells

    DEFF Research Database (Denmark)

    Gang, Xiao; Hjuler, H.A.; Olsen, C.A.;

    1993-01-01

    Electrochemical characteristics of a series of modified phosphoric acid electrolytes containing fluorinated car on compounds and silicone fluids as additives are presented. When used in phosphoric acid fuel cells, the modified electrolytes improve the performance due to the enhanced oxygen......, as a fuel-cell performance with the modified electrolytes. Specific conductivity measurements of some of the modified phosphoric acid electrolytes are reported. At a given temperature, the conductivity of the C4F9SO3K-modified electrolyte decreases with an increasing amount of the additive; the conductivity...... of the remains at the same value as the conductivity of the pure phosphoric acid. At a given composition, the conductivity of any modified electrolyte increases with temperature. We conclude that the improved cell performance for modified electrolytes is not due to any increase in conductivity....

  3. Yeast fuel cell: Application for desalination

    Science.gov (United States)

    Mardiana, Ummy; Innocent, Christophe; Cretin, Marc; Buchari, Buchari; Gandasasmita, Suryo

    2016-02-01

    Yeasts have been implicated in microbial fuel cells as biocatalysts because they are non-pathogenic organisms, easily handled and robust with a good tolerance in different environmental conditions. Here we investigated baker's yeast Saccharomyces cerevisiae through the oxidation of glucose. Yeast was used in the anolyte, to transfer electrons to the anode in the presence of methylene blue as mediator whereas K3Fe(CN)6 was used as an electron acceptor for the reduction reaction in the catholyte. Power production with biofuel cell was coupled with a desalination process. The maximum current density produced by the cell was 88 mA.m-2. In those conditions, it was found that concentration of salt was removed 64% from initial 0.6 M after 1-month operation. This result proves that yeast fuel cells can be used to remove salt through electrically driven membrane processes and demonstrated that could be applied for energy production and desalination. Further developments are in progress to improve power output to make yeast fuel cells applicable for water treatment.

  4. Charging system for fuel cell applications; Luftversorgung fuer Brennstoffzellen

    Energy Technology Data Exchange (ETDEWEB)

    Metz, Dietmar; Werner, Juergen; Muenz, Stefan [BorgWarner Turbo Systems, Kirchheimbolanden (Germany). Bereich Advanced Engineering; Becker, Michael [BorgWarner BERU Systems GmbH, Ludwigsburg (Germany)

    2013-04-15

    Vehicles with fuel cells become increasingly important, as OEM have announced to introduce fuel cell vehicles into the market starting in 2015. Similarly to a combustion engine, the fuel cell also needs compressed air to provide high power density. For a longer period, BorgWarner has collaborated with different OEM and has developed a turbocharger for fuel cells with high maturity level which is scalable to support various applications. (orig.)

  5. Performance optimization of a PEM hydrogen-oxygen fuel cell

    OpenAIRE

    Maher A.R. Sadiq Al-Baghdadi

    2013-01-01

    The objective was to develop a semi-empirical model that would simulate the performance of proton exchange membrane (PEM) fuel cells without extensive calculations. A fuel cell mathematical module has been designed and constructed to determine the performance of a PEM fuel cell. The influence of some operating parameters on the performance of PEM fuel cell has been investigated using pure hydrogen on the anode side and oxygen on the cathode side. The present model can be used to investigate t...

  6. Proton Exchange Membrane Fuel Cell Characterization for Electric Vehicle Applications

    OpenAIRE

    Swan, D.H.; Dickinson, B.E.; Arikara, M.P.

    1994-01-01

    This paper presents experimental data and an analysis of a proton exchange membrane fuel cell system for electric vehicle applications. The dependence of the fuel cell system's performance on air stoichiometry, operating temperature, and reactant gas pressure was assessed in terms of the fuel cell's polarity and power density-efficiency graphs. All the experiments were performed by loading the fuel cell with resistive heater coils which could be controlled to provide a constant current or con...

  7. State of the States: Fuel Cells in America

    Energy Technology Data Exchange (ETDEWEB)

    None

    2011-06-15

    This 2011 report, written by Fuel Cells 2000 and partially funded by the U.S. Department of Energy's Fuel Cell Technologies Program, provides an update of fuel cell and hydrogen activity in the 50 states and District of Columbia. State activities reported include new policies and funding, recent and planned fuel cell and hydrogen installations, and recent activities by state industries and universities.

  8. A review of fuel cell systems for maritime applications

    Science.gov (United States)

    van Biert, L.; Godjevac, M.; Visser, K.; Aravind, P. V.

    2016-09-01

    Progressing limits on pollutant emissions oblige ship owners to reduce the environmental impact of their operations. Fuel cells may provide a suitable solution, since they are fuel efficient while they emit few hazardous compounds. Various choices can be made with regard to the type of fuel cell system and logistic fuel, and it is unclear which have the best prospects for maritime application. An overview of fuel cell types and fuel processing equipment is presented, and maritime fuel cell application is reviewed with regard to efficiency, gravimetric and volumetric density, dynamic behaviour, environmental impact, safety and economics. It is shown that low temperature fuel cells using liquefied hydrogen provide a compact solution for ships with a refuelling interval up to a tens of hours, but may result in total system sizes up to five times larger than high temperature fuel cells and more energy dense fuels for vessels with longer mission requirements. The expanding infrastructure of liquefied natural gas and development state of natural gas-fuelled fuel cell systems can facilitate the introduction of gaseous fuels and fuel cells on ships. Fuel cell combined cycles, hybridisation with auxiliary electricity storage systems and redundancy improvements are identified as topics for further study.

  9. Direct FuelCell/Turbine Power Plant

    Energy Technology Data Exchange (ETDEWEB)

    Hossein Ghezel-Ayagh

    2008-09-30

    This report summarizes the progress made in development of Direct FuelCell/Turbine (DFC/T{reg_sign}) power plants for generation of clean power at very high efficiencies. The DFC/T system employs an indirectly heated Turbine Generator to supplement fuel cell generated power. The concept extends the high efficiency of the fuel cell by utilizing the fuel cell's byproduct heat in a Brayton cycle. Features of the DFC/T system include: electrical efficiencies of up to 75% on natural gas, minimal emissions, reduced carbon dioxide release to the environment, simplicity in design, direct reforming internal to the fuel cell, and potential cost competitiveness with existing combined cycle power plants. Proof-of-concept tests using a sub-MW-class DFC/T power plant at FuelCell Energy's (FCE) Danbury facility were conducted to validate the feasibility of the concept and to measure its potential for electric power production. A 400 kW-class power plant test facility was designed and retrofitted to conduct the tests. The initial series of tests involved integration of a full-size (250 kW) Direct FuelCell stack with a 30 kW Capstone microturbine. The operational aspects of the hybrid system in relation to the integration of the microturbine with the fuel cell, process flow and thermal balances, and control strategies for power cycling of the system, were investigated. A subsequent series of tests included operation of the sub-MW Direct FuelCell/Turbine power plant with a Capstone C60 microturbine. The C60 microturbine extended the range of operation of the hybrid power plant to higher current densities (higher power) than achieved in initial tests using the 30kW microturbine. The proof-of-concept test results confirmed the stability and controllability of operating a fullsize (250 kW) fuel cell stack in combination with a microturbine. Thermal management of the system was confirmed and power plant operation, using the microturbine as the only source of fresh air supply

  10. Direct FuelCell/Turbine Power Plant

    Energy Technology Data Exchange (ETDEWEB)

    Hossein Ghezel-Ayagh

    2008-09-30

    This report summarizes the progress made in development of Direct FuelCell/Turbine (DFC/T{reg_sign}) power plants for generation of clean power at very high efficiencies. The DFC/T system employs an indirectly heated Turbine Generator to supplement fuel cell generated power. The concept extends the high efficiency of the fuel cell by utilizing the fuel cell's byproduct heat in a Brayton cycle. Features of the DFC/T system include: electrical efficiencies of up to 75% on natural gas, minimal emissions, reduced carbon dioxide release to the environment, simplicity in design, direct reforming internal to the fuel cell, and potential cost competitiveness with existing combined cycle power plants. Proof-of-concept tests using a sub-MW-class DFC/T power plant at FuelCell Energy's (FCE) Danbury facility were conducted to validate the feasibility of the concept and to measure its potential for electric power production. A 400 kW-class power plant test facility was designed and retrofitted to conduct the tests. The initial series of tests involved integration of a full-size (250 kW) Direct FuelCell stack with a 30 kW Capstone microturbine. The operational aspects of the hybrid system in relation to the integration of the microturbine with the fuel cell, process flow and thermal balances, and control strategies for power cycling of the system, were investigated. A subsequent series of tests included operation of the sub-MW Direct FuelCell/Turbine power plant with a Capstone C60 microturbine. The C60 microturbine extended the range of operation of the hybrid power plant to higher current densities (higher power) than achieved in initial tests using the 30kW microturbine. The proof-of-concept test results confirmed the stability and controllability of operating a fullsize (250 kW) fuel cell stack in combination with a microturbine. Thermal management of the system was confirmed and power plant operation, using the microturbine as the only source of fresh air supply

  11. Catalytic Hydrolysis of Borohydride for Fuel Cells

    Institute of Scientific and Technical Information of China (English)

    WANG Lianbang; ZHAN Xingyue; YANG Zhenzhen; MA Chun'an

    2011-01-01

    Borohydrides present interesting options for the electrochemical power generation acting either as hydrogen source or anodic fuel for direct borohydride fuel cells(DBFC).In this work,Mg-Ni composite synthesized by mechanically alloying method,used as the catalyst for the hydrolysis of borohydride,has been investigated.Co-doping treatment has been carried out for the purpose of improving the hydrolysis rate further.The as-prepared and Co-doped Mg-Ni composites with low cost showed high catalytic activity to the hydrolysis of borohydride for hydrogen generation.After Co-doping,the hydrogen generation rate was around 280 ml·g-1·min-1.Borohydride would be a promising hydrogen source for fuel cells.

  12. Economics of Direct Hydrogen Polymer Electrolyte Membrane Fuel Cell Systems

    Energy Technology Data Exchange (ETDEWEB)

    Mahadevan, Kathyayani

    2011-10-04

    Battelle's Economic Analysis of PEM Fuel Cell Systems project was initiated in 2003 to evaluate the technology and markets that are near-term and potentially could support the transition to fuel cells in automotive markets. The objective of Battelle?s project was to assist the DOE in developing fuel cell systems for pre-automotive applications by analyzing the technical, economic, and market drivers of direct hydrogen PEM fuel cell adoption. The project was executed over a 6-year period (2003 to 2010) and a variety of analyses were completed in that period. The analyses presented in the final report include: Commercialization scenarios for stationary generation through 2015 (2004); Stakeholder feedback on technology status and performance status of fuel cell systems (2004); Development of manufacturing costs of stationary PEM fuel cell systems for backup power markets (2004); Identification of near-term and mid-term markets for PEM fuel cells (2006); Development of the value proposition and market opportunity of PEM fuel cells in near-term markets by assessing the lifecycle cost of PEM fuel cells as compared to conventional alternatives used in the marketplace and modeling market penetration (2006); Development of the value proposition of PEM fuel cells in government markets (2007); Development of the value proposition and opportunity for large fuel cell system application at data centers and wastewater treatment plants (2008); Update of the manufacturing costs of PEM fuel cells for backup power applications (2009).

  13. 77 FR 50488 - Hydrogen and Fuel Cell Technical Advisory Committee

    Science.gov (United States)

    2012-08-21

    ... Hydrogen and Fuel Cell Technical Advisory Committee AGENCY: Department of Energy, Office of Energy... open meeting (Webinar) of the Hydrogen and Fuel Cell Technical Advisory Committee (HTAC). The Federal..., DC 20585. SUPPLEMENTARY INFORMATION: Purpose of the Committee: The Hydrogen and Fuel Cell...

  14. Simplified Load-Following Control for a Fuel Cell System

    Science.gov (United States)

    Vasquez, Arturo

    2010-01-01

    A simplified load-following control scheme has been proposed for a fuel cell power system. The scheme could be used to control devices that are important parts of a fuel cell system but are sometimes characterized as parasitic because they consume some of the power generated by the fuel cells.

  15. Exoelectrogenic bacteria that power microbial fuel cells

    KAUST Repository

    Logan, Bruce E.

    2009-03-30

    There has been an increase in recent years in the number of reports of microorganisms that can generate electrical current in microbial fuel cells. Although many new strains have been identified, few strains individually produce power densities as high as strains from mixed communities. Enriched anodic biofilms have generated power densities as high as 6.9 W per m2 (projected anode area), and therefore are approaching theoretical limits. To understand bacterial versatility in mechanisms used for current generation, this Progress article explores the underlying reasons for exocellular electron transfer, including cellular respiration and possible cell-cell communication.

  16. Tubular solid oxide fuel cell development program

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    This paper presents an overview of the Westinghouse Solid Oxide Fuel Cell (SOFC) development activities and current program status. The Westinghouse goal is to develop a cost effective cell that can operate for 50,000 to 100,000 hours. Progress toward this goal will be discussed and test results presented for multiple single cell tests which have now successfully exceeded 56,000 hours of continuous power operation at temperature. Results of development efforts to reduce cost and increase power output of tubular SOFCs are described.

  17. Fuel Cells for Balancing Fluctuation Renewable Energy Sources

    DEFF Research Database (Denmark)

    Mathiesen, Brian Vad

    2007-01-01

    In the perspective of using fuel cells for integration of fluctuating renewable energy the SOFCs are the most promising. These cells have the advantage of significantly higher electricity efficiency than competing technologies and fuel flexibility. Fuel cells in general also have the advantage of...... with hydrogen production or electric cars, and on the other hand using biomass and bio fuels [11]. Fuel cells can have an important role in these future energy systems.......In the perspective of using fuel cells for integration of fluctuating renewable energy the SOFCs are the most promising. These cells have the advantage of significantly higher electricity efficiency than competing technologies and fuel flexibility. Fuel cells in general also have the advantage...... flexibility, such as SOFCs, heat pumps and heat storage technologies are more important than storing electricity as hydrogen via electrolysis in energy systems with high amounts of wind [12]. Unnecessary energy conversions should be avoided. However in future energy systems with wind providing more than 50...

  18. Advanced methods of solid oxide fuel cell modeling

    CERN Document Server

    Milewski, Jaroslaw; Santarelli, Massimo; Leone, Pierluigi

    2011-01-01

    Fuel cells are widely regarded as the future of the power and transportation industries. Intensive research in this area now requires new methods of fuel cell operation modeling and cell design. Typical mathematical models are based on the physical process description of fuel cells and require a detailed knowledge of the microscopic properties that govern both chemical and electrochemical reactions. ""Advanced Methods of Solid Oxide Fuel Cell Modeling"" proposes the alternative methodology of generalized artificial neural networks (ANN) solid oxide fuel cell (SOFC) modeling. ""Advanced Methods

  19. Status of hydrogen fuel cell electric buses worldwide

    Science.gov (United States)

    Hua, Thanh; Ahluwalia, Rajesh; Eudy, Leslie; Singer, Gregg; Jermer, Boris; Asselin-Miller, Nick; Wessel, Silvia; Patterson, Timothy; Marcinkoski, Jason

    2014-12-01

    This review summarizes the background and recent status of the fuel cell electric bus (FCEB) demonstration projects in North America and Europe. Key performance metrics include accumulated miles, availability, fuel economy, fuel cost, roadcalls, and hydrogen fueling. The state-of-the-art technology used in today's fuel cell bus is highlighted. Existing hydrogen infrastructure for refueling is described. The article also presents the challenges encountered in these projects, the experiences learned, as well as current and future performance targets.

  20. Materials Challenges for Automotive PEM Fuel Cells

    Science.gov (United States)

    Gasteiger, Hubert

    2004-03-01

    Over the past few years, significant R efforts aimed at meeting the challenging cost and performance targets required for the use of Polymer Electrolyte Membrane (PEM) fuel cells in automotive applications. Besides engineering advances in bipolar plate materials and design, the optimization of membrane-electrode assemblies (MEAs) was an important enabler in reducing the cost and performance gaps towards commercial viability for the automotive market. On the one hand, platinum loadings were reduced from several mgPt/cm2MEA [1] to values of 0.5-0.6 mgPt/cm2MEA in current applications and loadings as low as 0.25 mgPt/cm2MEA have been demonstrated on the research level [2]. On the other hand, implementation of thin membranes (20-30 micrometer) [3, 4] as well as improvements in diffusion medium materials, essentially doubled the achievable power density of MEAs to ca. 0.9 W/cm2MEA (at 0.65 V) [5], thereby not only reducing the size of a PEMFC fuel cell system, but also reducing its overall materials cost (controlled to a large extent by membrane and Pt-catalyst cost). While this demonstrated a clear path towards automotive applications, a renewed focus of R efforts is now required to develop materials and fundamental materials understanding to assure long-term durability of PEM fuel cells. This presentation therefore will discuss the state-of-the-art knowledge of catalyst, catalyst-support, and membrane degradation mechanisms. In the area of Pt-catalysts, experience with phosphoric acid fuel cells (PAFCs) has shown that platinum sintering leads to long-term performance losses [6]. While this is less critical at the lower PEMFC operating temperatures (200C), very little is known about the dependence of Pt-sintering on temperature, cell voltage, and catalyst type (i.e., Pt versus Pt-alloys) and will be discussed here. Similarly, carbon-support corrosion can contribute significantly to voltage degradation in PAFCs [7], and even in the PEMFC environment more corrosion

  1. Environmental analysis of solid oxide fuel cells

    Science.gov (United States)

    Zapp, P.

    Nowadays, for a new technology to be succesfully introduced, it should compete not only in terms of economy, but also in terms of ecology. Therefore, end-of-pipe treatments are no longer sufficient, but precautionary environmental protection is also necessary. The aim of the present work is an environmental analysis of the solid oxide fuel cell (SOFC) technology using the 'Environmental Precaution Study'. Constituent materials, energy and emission flows are determined and evaluated throughout the entire life cycle. Cradle to grave considerations embrace the production of raw materials and technical equipment, respectively, operation and dismantling. A reference SOFC cell of the planar cell type, based on the current fuel cell programme of the Research Centre Jülich, has been compared with a conventional technology in the form of a 10 MW gas turbine. The latter has been chosen as the competitive conventional technology, because the power output is similar to the expected SOFC power output and the use of the same fuel, natural gas, facilitates the comparison.

  2. Wireless sensors powered by microbial fuel cells.

    Science.gov (United States)

    Shantaram, Avinash; Beyenal, Haluk; Raajan, Raaja; Veluchamy, Angathevar; Lewandowski, Zbigniew

    2005-07-01

    Monitoring parameters characterizing water quality, such as temperature, pH, and concentrations of heavy metals in natural waters, is often followed by transmitting the data to remote receivers using telemetry systems. Such systems are commonly powered by batteries, which can be inconvenient at times because batteries have a limited lifetime and must be recharged or replaced periodically to ensure that sufficient energy is available to power the electronics. To avoid these inconveniences, a microbial fuel cell was designed to power electrochemical sensors and small telemetry systems to transmit the data acquired by the sensors to remote receivers. The microbial fuel cell was combined with low-power, high-efficiency electronic circuitry providing a stable power source for wireless data transmission. To generate enough power for the telemetry system, energy produced by the microbial fuel cell was stored in a capacitor and used in short bursts when needed. Since commercial electronic circuits require a minimum 3.3 V input and our cell was able to deliver a maximum of 2.1 V, a DC-DC converter was used to boost the potential. The DC-DC converter powered a transmitter, which gathered the data from the sensor and transmitted it wirelessly to a remote receiver. To demonstrate the utility of the system, temporal variations in temperature were measured, and the data were wirelessly transmitted to a remote receiver. PMID:16053108

  3. Design and Control of High Temperature PEM Fuel Cell System

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl

    E-cient fuel cell systems have started to appear in many dierent commercial applications and large scale production facilities are already operating to supply fuel cells to support an ever growing market. Fuel cells are typically considered to replace leadacid batteries in applications where...... or life time losses. In order to evaluate the performance of using HTPEM fuel cells for electricity production in electrical applications, a 400 W fuel cell system is initially designed using a cathode air cooled 30 cell HTPEM stack. The stack runs on pure hydrogen in a deadend anode configuration...... that often during a normal driving cycle. The combination of batteries and super capacitors together with fuel cells can improve the system performance, lifetime and cost. Simple systems can be designed where the fuel cells and batteries are directly connected, but the introduction of power electronics can...

  4. GRID INDEPENDENT FUEL CELL OPERATED SMART HOME

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Mohammad S. Alam

    2003-12-07

    A fuel cell power plant, which utilizes a smart energy management and control (SEMaC) system, supplying the power need of laboratory based ''home'' has been purchased and installed. The ''home'' consists of two rooms, each approximately 250 sq. ft. Every appliance and power outlet is under the control of a host computer, running the SEMaC software package. It is possible to override the computer, in the event that an appliance or power outage is required. Detailed analysis and simulation of the fuel cell operated smart home has been performed. Two journal papers has been accepted for publication and another journal paper is under review. Three theses have been completed and three additional theses are in progress.

  5. A novel supercapacitor-fuel cell hybrid cell

    Institute of Scientific and Technical Information of China (English)

    WANG Y; ZHENG Jim P

    2006-01-01

    A monolithic hybrid fuel cell (MHFC) with a novel configuration was proposed in an effort to improve the fuel cell performance during instantaneous power changes. A modified direct methanol fuel cell (DMFC) with a layer of hydrous ruthenium dioxide (RuO2·xH2O) sandwiched between the anode catalyst layer and membrane was used to demonstrate the principle of the MHFC. Experimental results indicate that the RuO2·xH2O layer is equivalent to a resistor-capacitor transmission line and functions similar to a capacitor in parallel with the anode electrode. The improvement in dynamic response of the MHFC was experimentally confirmed under step current change and square current pulse operating. The ionic conductivity of the RuO2·xH2O layer was also obtained.

  6. Stability of solid oxide fuel cell materials

    Energy Technology Data Exchange (ETDEWEB)

    Armstrong, T.R.; Bates, J.L.; Chick, L.A. [Pacific Northwest Lab., Richland, WA (United States)

    1996-04-01

    Interconnection materials in a solid oxide fuel cell are exposed to both highly oxidizing conditions at the cathode and to highly reducing conditions at the anode. The thermal expansion characteristics of substituted lanthanum and yttrium chromite interconnect materials were evaluated by dilatometry as a function of oxygen partial pressures from 1 atm to 10{sup -18} atm, controlled using a carbon dioxide/hydrogen buffer.

  7. Fuel cell using a hydrogen generation system

    Science.gov (United States)

    Dentinger, Paul M.; Crowell, Jeffrey A. W.

    2010-10-19

    A system is described for storing and generating hydrogen and, in particular, a system for storing and generating hydrogen for use in an H.sub.2/O.sub.2 fuel cell. The hydrogen storage system uses beta particles from a beta particle emitting material to degrade an organic polymer material to release substantially pure hydrogen. In a preferred embodiment of the invention, beta particles from .sup.63Ni are used to release hydrogen from linear polyethylene.

  8. The status of fuel cell technology

    Energy Technology Data Exchange (ETDEWEB)

    O' Sullivan, J.B.

    1991-02-20

    This brief status report provides an introduction to what fuel cells are, why they are important, what uses have been made of them to date, the goals and timetables of current programs, and who the players are in this vital technology. Copies of most of the slides presented and additional diagrams are appended to this paper. Further details can be obtained from the comprehensive texts cited in the bibliography. 11 refs., 44 figs.

  9. Solid-polymer-electrolyte fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Fuller, T.F.

    1992-07-01

    A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich's solution and analysis.

  10. Solid-polymer-electrolyte fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Fuller, T.F.

    1992-07-01

    A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich`s solution and analysis.

  11. Electrocatalysts for direct alcohol fuel cells

    OpenAIRE

    Celorrio, V.

    2013-01-01

    The properties of CNC as well as their surface chemistry can be tuned by an adequate choice of synthesis conditions, favouring the formation of surface oxygen groups. Platinum-based catalysts have been supported on CNCs through different synthesis methods and their catalytic activity has been proven. These results prove that CNCs are promising candidates as alternative to replace Vulcan in order to improve the performance of the direct alcohol fuel cells. In addition, it can be affirmed that ...

  12. Progress in Microbial Fuel Cells Energy Production

    International Nuclear Information System (INIS)

    Microbial fuel cells (MFCs) harness the natural metabolisms of microbes to produce electrical power from almost any kind of organic matter. In addition to the low power densities (about 1mW for a 1-liter reactor), MFCs are presently built with expensive membrane and electrodes. The payback time of MFCs is therefore very long (evaluated to 25000 years for our lab prototype). Progresses in designing low-cost MFCs are necessary before conceiving large scale energy production. (author)

  13. Fuel cell technology development forges ahead

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ On 11 June, 2006, a bright red sightseeing van attracted much attention at the Xinghai Square in Dalian, a coastal city of northeast China's Liaoning Province. This is no ordinary tour coach, as it is jointly driven by fuel cells (FC) and storage batteries. Acting as its "heart," the FC system could generate electricity not only for driving the mini-coach, but also for re-charging the storage battery system when excess power is yielded.

  14. Brazilian hybrid electric fuel cell bus

    Energy Technology Data Exchange (ETDEWEB)

    Miranda, P.E.V.; Carreira, E.S. [Coppe-Federal Univ. of Rio de Janeiro (Brazil). Hydrogen Lab.

    2010-07-01

    The first prototype of a hybrid electric fuel cell bus developed with Brazilian technology is unveiled. It is a 12 m urban-type, low-floor, air-conditioned bus that possesses three doors, air suspension, 29 seats and reversible wheelchair site. The bus body was built based on a double-deck type monoblock vehicle that is able to sustain important load on its roof. This allowed positioning of the type 3 hydrogen tanks and the low weight traction batteries on the roof of the vehicles without dynamic stabilization problems. A novel hybrid energy configuration was designed in such a way that the low-power (77 kWe) fuel cell works on steady-state operation mode, not responding directly to the traction motor load demand. The rate of kinetic energy regeneration upon breaking was optimized by the use of an electric hybrid system with predominance of batteries and also by utilizing supercapacitors. The electric-electronic devices and the security control softwares for the auxiliary and traction systems were developed in-house. The innovative hybrid-electric traction system configuration led to the possibility to decrease the fuel cell power, with positive impact on weight and system volume reduction, as well as to significantly decrease the hydrogen consumption. (orig.)

  15. Intermediate Temperature Solid Oxide Fuel Cell Development

    Energy Technology Data Exchange (ETDEWEB)

    S. Elangovan; Scott Barnett; Sossina Haile

    2008-06-30

    Solid oxide fuel cells (SOFCs) are high efficiency energy conversion devices. Present materials set, using yttria stabilized zirconia (YSZ) electrolyte, limit the cell operating temperatures to 800 C or higher. It has become increasingly evident however that lowering the operating temperature would provide a more expeditious route to commercialization. The advantages of intermediate temperature (600 to 800 C) operation are related to both economic and materials issues. Lower operating temperature allows the use of low cost materials for the balance of plant and limits degradation arising from materials interactions. When the SOFC operating temperature is in the range of 600 to 700 C, it is also possible to partially reform hydrocarbon fuels within the stack providing additional system cost savings by reducing the air preheat heat-exchanger and blower size. The promise of Sr and Mg doped lanthanum gallate (LSGM) electrolyte materials, based on their high ionic conductivity and oxygen transference number at the intermediate temperature is well recognized. The focus of the present project was two-fold: (a) Identify a cell fabrication technique to achieve the benefits of lanthanum gallate material, and (b) Investigate alternative cathode materials that demonstrate low cathode polarization losses at the intermediate temperature. A porous matrix supported, thin film cell configuration was fabricated. The electrode material precursor was infiltrated into the porous matrix and the counter electrode was screen printed. Both anode and cathode infiltration produced high performance cells. Comparison of the two approaches showed that an infiltrated cathode cells may have advantages in high fuel utilization operations. Two new cathode materials were evaluated. Northwestern University investigated LSGM-ceria composite cathode while Caltech evaluated Ba-Sr-Co-Fe (BSCF) based pervoskite cathode. Both cathode materials showed lower polarization losses at temperatures as low as 600

  16. Fuel Cells for Balancing Fluctuation Renewable Energy Sources

    OpenAIRE

    Mathiesen, Brian Vad

    2007-01-01

    In the perspective of using fuel cells for integration of fluctuating renewable energy the SOFCs are the most promising. These cells have the advantage of significantly higher electricity efficiency than competing technologies and fuel flexibility. Fuel cells in general also have the advantage of fast regulation abilities combined with excellent part-load efficiencies. Additionally scaling the cells from W to kW to MW is possible and does not influence the efficiencies of the cells. The feasi...

  17. Protozoan grazing reduces the current output of microbial fuel cells.

    Science.gov (United States)

    Holmes, Dawn E; Nevin, Kelly P; Snoeyenbos-West, Oona L; Woodard, Trevor L; Strickland, Justin N; Lovley, Derek R

    2015-10-01

    Several experiments were conducted to determine whether protozoan grazing can reduce current output from sediment microbial fuel cells. When marine sediments were amended with eukaryotic inhibitors, the power output from the fuel cells increased 2-5-fold. Quantitative PCR showed that Geobacteraceae sequences were 120 times more abundant on anodes from treated fuel cells compared to untreated fuel cells, and that Spirotrichea sequences in untreated fuel cells were 200 times more abundant on anode surfaces than in the surrounding sediments. Defined studies with current-producing biofilms of Geobacter sulfurreducens and pure cultures of protozoa demonstrated that protozoa that were effective in consuming G. sulfurreducens reduced current production up to 91% when added to G. sulfurreducens fuel cells. These results suggest that anode biofilms are an attractive food source for protozoa and that protozoan grazing can be an important factor limiting the current output of sediment microbial fuel cells.

  18. PEM Fuel Cells Redesign Using Biomimetic and TRIZ Design Methodologies

    Science.gov (United States)

    Fung, Keith Kin Kei

    Two formal design methodologies, biomimetic design and the Theory of Inventive Problem Solving, TRIZ, were applied to the redesign of a Proton Exchange Membrane (PEM) fuel cell. Proof of concept prototyping was performed on two of the concepts for water management. The liquid water collection with strategically placed wicks concept demonstrated the potential benefits for a fuel cell. Conversely, the periodic flow direction reversal concepts might cause a potential reduction water removal from a fuel cell. The causes of this water removal reduction remain unclear. In additional, three of the concepts generated with biomimetic design were further studied and demonstrated to stimulate more creative ideas in the thermal and water management of fuel cells. The biomimetic design and the TRIZ methodologies were successfully applied to fuel cells and provided different perspectives to the redesign of fuel cells. The methodologies should continue to be used to improve fuel cells.

  19. Fuel cell commercialization — beyond the 'Notice of Market Opportunity for Fuel Cells' (NOMO)

    Science.gov (United States)

    Serfass, J. A.; Glenn, D. R.

    1992-01-01

    The Notice of Market Opportunity for Fuel Cells (NOMO) was released in Oct. 1988 by the American Public Power Association. Its goal was to identify a manufacturer for commercializing a multi-megawatt fuel cell power plant with attractive cost and performance characteristics, supported by a realistic, yet aggressive commercialization plan, leading to mid-1990s application. Energy Research Corporation's program to commercialize its 2-MW internal-reforming carbonate fuel cell was selected. The program was refined in the development of the Principles and Framework for Commercializing Direct Fuel Cell Power Plants, which defines buyer responsibilities for promotion and coordination of information development, supplier responsibilities for meeting certain milestones and for sharing the results of success in a royalty agreement, and risk management features. Twenty-three electric and gas utilities in the US and Canada have joined the Fuel Cell Commercialization Group to support the buyers' obligations in this program. The City of Santa Clara, CA; Electric Power Research Institute; Los Angeles Department of Water and Power; Southern California Gas Company; Southern California Edison; National Rural Electric Cooperative Association; and Pacific Gas & Electric, have formed the Santa Clara Demonstration Group to build the first 2-MW power plant. The preliminary design for this demonstration is nearly complete. Integrated testing of a 20-kW stack with the complete balance-of-plant, has been successfully accomplished by Pacific Gas & Electric at its test facility in San Ramon, CA.

  20. Solar Airplanes and Regenerative Fuel Cells

    Science.gov (United States)

    Bents, David J.

    2007-01-01

    A solar electric aircraft with the potential to "fly forever" has captured NASA's interest, and the concept for such an aircraft was pursued under Aeronautics Environmental Research Aircraft and Sensor Technology (ERAST) project. Feasibility of this aircraft happens to depend on the successful development of solar power technologies critical to NASA's Exploration Initiatives; hence, there was widespread interest throughout NASA to bring these technologies to a flight demonstration. The most critical is an energy storage system to sustain mission power during night periods. For the solar airplane, whose flight capability is already limited by the diffuse nature of solar flux and subject to latitude and time of year constraints, the feasibility of long endurance flight depends on a storage density figure of merit better than 400-600 watt-hr per kilogram. This figure of merit is beyond the capability of present day storage technologies (other than nuclear) but may be achievable in the hydrogen-oxygen regenerative fuel cell (RFC). This potential has led NASA to undertake the practical development of a hydrogen-oxygen regenerative fuel cell, initially as solar energy storage for a high altitude UAV science platform but eventually to serve as the primary power source for NASAs lunar base and other planet surface installations. Potentially the highest storage capacity and lowest weight of any non-nuclear device, a flight-weight RFC aboard a solar-electric aircraft that is flown continuously through several successive day-night cycles will provide the most convincing demonstration that this technology's widespread potential has been realized. In 1998 NASA began development of a closed cycle hydrogen oxygen PEM RFC under the Aeronautics Environmental Research Aircraft and Sensor Technology (ERAST) project and continued its development, originally for a solar electric airplane flight, through FY2005 under the Low Emissions Alternative Power (LEAP) project. Construction of

  1. Airport electric vehicle powered by fuel cell

    Science.gov (United States)

    Fontela, Pablo; Soria, Antonio; Mielgo, Javier; Sierra, José Francisco; de Blas, Juan; Gauchia, Lucia; Martínez, Juan M.

    Nowadays, new technologies and breakthroughs in the field of energy efficiency, alternative fuels and added-value electronics are leading to bigger, more sustainable and green thinking applications. Within the Automotive Industry, there is a clear declaration of commitment with the environment and natural resources. The presence of passenger vehicles of hybrid architecture, public transport powered by cleaner fuels, non-aggressive utility vehicles and an encouraging social awareness, are bringing to light a new scenario where conventional and advanced solutions will be in force. This paper presents the evolution of an airport cargo vehicle from battery-based propulsion to a hybrid power unit based on fuel cell, cutting edge batteries and hydrogen as a fuel. Some years back, IBERIA (Major Airline operating in Spain) decided to initiate the replacement of its diesel fleet for battery ones, aiming at a reduction in terms of contamination and noise in the surrounding environment. Unfortunately, due to extreme operating conditions in airports (ambient temperature, intensive use, dirtiness, …), batteries suffered a very severe degradation, which took its toll in terms of autonomy. This reduction in terms of autonomy together with the long battery recharge time made the intensive use of this fleet impractical in everyday demanding conditions.

  2. Biorefinery and Hydrogen Fuel Cell Research

    Energy Technology Data Exchange (ETDEWEB)

    K.C. Das; Thomas T. Adams; Mark A. Eiteman; John Stickney; Joy Doran Peterson; James R. Kastner; Sudhagar Mani; Ryan Adolphson

    2012-06-12

    In this project we focused on several aspects of technology development that advances the formation of an integrated biorefinery. These focus areas include: [1] establishment of pyrolysis processing systems and characterization of the product oils for fuel applications, including engine testing of a preferred product and its pro forma economic analysis; [2] extraction of sugars through a novel hotwater extaction process, and the development of levoglucosan (a pyrolysis BioOil intermediate); [3] identification and testing of the use of biochar, the coproduct from pyrolysis, for soil applications; [4] developments in methods of atomic layer epitaxy (for efficient development of coatings as in fuel cells); [5] advancement in fermentation of lignocellulosics, [6] development of algal biomass as a potential substrate for the biorefinery, and [7] development of catalysts from coproducts. These advancements are intended to provide a diverse set of product choices within the biorefinery, thus improving the cost effectiveness of the system. Technical effectiveness was demonstrated in the pyrolysis biooil based diesel fuel supplement, sugar extraction from lignocelluose, use of biochar, production of algal biomass in wastewaters, and the development of catalysts. Economic feasibility of algal biomass production systems seems attractive, relative to the other options. However, further optimization in all paths, and testing/demonstration at larger scales are required to fully understand the economic viabilities. The various coproducts provide a clear picture that multiple streams of value can be generated within an integrated biorefinery, and these include fuels and products.

  3. Durability of solid oxide fuel cells using sulfur containing fuels

    DEFF Research Database (Denmark)

    Hagen, Anke; Rasmussen, Jens Foldager Bregnballe; Thydén, Karl Tor Sune

    2011-01-01

    are critical in this respect. State-of-the-art Ni/YSZ SOFC anodes suffer from being rather sensitive towards sulfur impurities. In the current study, anode supported SOFCs with Ni/YSZ or Ni/ScYSZ anodes were exposed to H2S in the ppm range both for short periods of 24h and for a few hundred hours. In a fuel...... containing significant shares of methane, the reforming activities of the Ni/YSZ and Ni/ScYSZ anodes were severely poisoned already at low H2S concentrations of ∼2ppm H2S. The poisoning effect on the cell voltage was reversible only to a certain degree after exposure of 500h in the state-of-the-art cell, due...... to a loss of percolation of Ni particles in the Ni/YSZ anode layers closest to the electrolyte. Using SOFCs with Ni/ScYSZ anodes improved the H2S tolerance considerably, even at larger H2S concentrations of 10 and 20ppm over a few hundred hours....

  4. A critical assessment of fuel cell technology

    International Nuclear Information System (INIS)

    Cold combustion is a promised technology to mankind since the middle of the last century. The fuel cell may at last become the energy machine of the one to come after a long journey on a road bordered with expectations, successes and disappointments. Ten billion people will need the cell for their well-being. The progress and the state-of-art is assessed by means of figures of merit for performance, normalized to standard conditions, life and variability. State-of-art current densities for multi-kW stacks operating on atmospheric pressure air at 0.74 V cell voltage (50% efficiency, HHV) are estimated to be 150 mA/cm2 for MCFC, 160 mA/cm2 for AFC, 239 mA/cm2 for PEFC and 270 mA/cm2 for SOFC. PAFC gives 260 mA/cm2 at 0.66 V and DMFC 100 mA/cm2 at 0.37 V. Decay rates are about 1%/1000 h for PEFC, PAFC and SOFC compared to 2%/1000 h for AFC and 3%/1000 h for MCFC. Coefficients of variation for cell voltages amount to about 1% for all options, except for MCFC with 3-4%. Improvement of cell performance after 1975 is nil to moderate, except for SOFC with a consistent annual improvement of about 10%. There is room for further development of terrestrial AFCs towards 300-400 mA/cm2 considering the figure 800 mA/cm2 for oxygen AFCs. Life and cost will decide the future of the fuel cell. Prospects are not as good as they could be. The fuel cell community lacks understanding of the basics of fuel processing, as demonstrated by the widespread misbelief ('the CO2 syndrome') that CO2 cannot be removed cost effectively from a hydrogen feed (which is practiced in every NH3 plant around the world). The competition, read the gas turbine, has to be taken very seriously. Emphasis has to be shifted from premature demonstrations to R and D on fundamental problems, which have been around too long. 34 refs

  5. Macroscopic Modeling of Transport Phenomena in Direct Methanol Fuel Cells

    DEFF Research Database (Denmark)

    Olesen, Anders Christian

    An increasing need for energy efficiency and high energy density has sparked a growing interest in direct methanol fuel cells for portable power applications. This type of fuel cell directly generates electricity from a fuel mixture consisting of methanol and water. Although this technology...

  6. Development of new membrane materials for direct methanol fuel cells

    NARCIS (Netherlands)

    Yildirim, Mustafa Hakan

    2009-01-01

    Development of new membrane materials for direct methanol fuel cells Direct methanol fuel cells (DMFCs) can convert the chemical energy of a fuel directly into electrical energy with high efficiency and low emission of pollutants. DMFCs can be used as the power sources to portable electronic devices

  7. Solar energy powered microbial fuel cell with a reversible bioelectrode

    NARCIS (Netherlands)

    Strik, D.P.B.T.B.; Hamelers, H.V.M.; Buisman, C.J.N.

    2010-01-01

    The solar energy powered microbial fuel cell is an emerging technology for electricity generation via electrochemically active microorganisms fueled by solar energy via in situ photosynthesized metabolites from algae, cyanobacteria, or living higher plants. A general problem with microbial fuel cell

  8. Fuel Cells: A Real Option for Unmanned Aerial Vehicles Propulsion

    Directory of Open Access Journals (Sweden)

    Óscar González-Espasandín

    2014-01-01

    Full Text Available The possibility of implementing fuel cell technology in Unmanned Aerial Vehicle (UAV propulsion systems is considered. Potential advantages of the Proton Exchange Membrane or Polymer Electrolyte Membrane (PEMFC and Direct Methanol Fuel Cells (DMFC, their fuels (hydrogen and methanol, and their storage systems are revised from technical and environmental standpoints. Some operating commercial applications are described. Main constraints for these kinds of fuel cells are analyzed in order to elucidate the viability of future developments. Since the low power density is the main problem of fuel cells, hybridization with electric batteries, necessary in most cases, is also explored.

  9. Fuel cells: a real option for Unmanned Aerial Vehicles propulsion.

    Science.gov (United States)

    González-Espasandín, Óscar; Leo, Teresa J; Navarro-Arévalo, Emilio

    2014-01-01

    The possibility of implementing fuel cell technology in Unmanned Aerial Vehicle (UAV) propulsion systems is considered. Potential advantages of the Proton Exchange Membrane or Polymer Electrolyte Membrane (PEMFC) and Direct Methanol Fuel Cells (DMFC), their fuels (hydrogen and methanol), and their storage systems are revised from technical and environmental standpoints. Some operating commercial applications are described. Main constraints for these kinds of fuel cells are analyzed in order to elucidate the viability of future developments. Since the low power density is the main problem of fuel cells, hybridization with electric batteries, necessary in most cases, is also explored.

  10. Structure and Control Strategies of Fuel Cell Vehicle

    Institute of Scientific and Technical Information of China (English)

    宋建国; 张承宁; 孙逢春; 钟秋海

    2004-01-01

    The structure and kinds of the fuel cell vehicle (FCV) and the mathematical model of the fuel cell processor are discussed in detail. FCV includes many parts: the fuel cell thermal and water management, fuel supply, air supply and distribution, AC motor drive, main and auxiliary power management, and overall vehicle control system. So it requires different kinds of control strategies, such as the PID method, zero-pole method, optimal control method, fuzzy control and neural network control. Along with the progress of control method, the fuel cell vehicle's stability and reliability is up-and-up. Experiment results show FCV has high energy efficiency.

  11. Proceedings of the fuel cells 1994 contractors review meeting

    Science.gov (United States)

    Carpenter, C. P., II; Mayfield, M. J.

    1994-08-01

    METC annually sponsors this conference to provide a forum for energy executives, engineers, etc. to discuss advances in fuel cell research and development projects, to exchange ideas with private sector attendees, and to review relevant results in fuel cell technology programs. Two hundred and three people from industry, academia, and Government attended. The conference attempts to showcase the partnerships with the Government and with industry, by seeking activity participation and involvement from the Office of Energy Efficiency and Renewable Energy, EPRI, GRI, and APRA. In addition to sessions on fuel cells (solid oxide, molten carbonate, etc.) for stationary electric power generation, sessions on US DOE's Fuel Cell Transportation Program and on DOD/APRA's fuel cell logistic fuel program were presented. In addition to the 29 technical papers, an abstract of an overview of international fuel cell development and commercialization plans in Europe and Japan is included. Selected papers were indexed separately for inclusion in the Energy Science and Technology Database.

  12. Fuel cell electrode interconnect contact material encapsulation and method

    Energy Technology Data Exchange (ETDEWEB)

    Derose, Anthony J.; Haltiner, Jr., Karl J.; Gudyka, Russell A.; Bonadies, Joseph V.; Silvis, Thomas W.

    2016-05-31

    A fuel cell stack includes a plurality of fuel cell cassettes each including a fuel cell with an anode and a cathode. Each fuel cell cassette also includes an electrode interconnect adjacent to the anode or the cathode for providing electrical communication between an adjacent fuel cell cassette and the anode or the cathode. The interconnect includes a plurality of electrode interconnect protrusions defining a flow passage along the anode or the cathode for communicating oxidant or fuel to the anode or the cathode. An electrically conductive material is disposed between at least one of the electrode interconnect protrusions and the anode or the cathode in order to provide a stable electrical contact between the electrode interconnect and the anode or cathode. An encapsulating arrangement segregates the electrically conductive material from the flow passage thereby, preventing volatilization of the electrically conductive material in use of the fuel cell stack.

  13. Flow and Pressure Distribution in Fuel Cell Manifolds

    DEFF Research Database (Denmark)

    Lebæk, Jesper; Bang, Mads; Kær, Søren Knudsen

    2010-01-01

    The manifold is an essential part of the fuel cell stack. Evidently, evenly distributed reactants are a prerequisite for an efficient fuel cell stack. In this study, the cathode manifold ability to distribute air to the cells of a 70 cell stack is investigated experimentally. By means of 20...

  14. Coal Integrated Gasification Fuel Cell System Study

    Energy Technology Data Exchange (ETDEWEB)

    Chellappa Balan; Debashis Dey; Sukru-Alper Eker; Max Peter; Pavel Sokolov; Greg Wotzak

    2004-01-31

    This study analyzes the performance and economics of power generation systems based on Solid Oxide Fuel Cell (SOFC) technology and fueled by gasified coal. System concepts that integrate a coal gasifier with a SOFC, a gas turbine, and a steam turbine were developed and analyzed for plant sizes in excess of 200 MW. Two alternative integration configurations were selected with projected system efficiency of over 53% on a HHV basis, or about 10 percentage points higher than that of the state-of-the-art Integrated Gasification Combined Cycle (IGCC) systems. The initial cost of both selected configurations was found to be comparable with the IGCC system costs at approximately $1700/kW. An absorption-based CO2 isolation scheme was developed, and its penalty on the system performance and cost was estimated to be less approximately 2.7% and $370/kW. Technology gaps and required engineering development efforts were identified and evaluated.

  15. Nanotubular array solid oxide fuel cell.

    Science.gov (United States)

    Motoyama, Munekazu; Chao, Cheng-Chieh; An, Jihwan; Jung, Hee Joon; Gür, Turgut M; Prinz, Friedrich B

    2014-01-28

    This report presents a demonstration and characterization of a nanotubular array of solid oxide fuel cells (SOFCs) made of one-end-closed hollow tube Ni/yttria-stabilized zirconia/Pt membrane electrode assemblies (MEAs). The tubular MEAs are nominally ∼5 μm long and have up to 660 mV (vs air) and power densities up to 1.3 μW cm(-2) were measured at 550 °C using H2 as fuel. The paper also introduces a fabrication methodology primarily based on a template process involving atomic layer deposition and electrodeposition for building the nanotubular MEA architecture as an important step toward achieving high surface area ultrathin SOFCs operating in the intermediate to low-temperature regime. A fabricated nanotubular SOFC theoretically attains a 20-fold increase in the effective surface, while projections indicate the possibility of achieving up to 40-fold. PMID:24266776

  16. Palladium-based electrocatalysts and fuel cells employing such electrocatalysts

    Science.gov (United States)

    Masel; Richard I. , Zhu; Yimin , Larsen; Robert T.

    2010-08-31

    A direct organic fuel cell includes a fluid fuel comprising formic acid, an anode having an electrocatalyst comprising palladium nanoparticles, a fluid oxidant, a cathode electrically connected to the anode, and an electrolyte interposed between the anode and the cathode.

  17. Cost analysis and economic comparison for alternative fuel cycles in the heavy water cooled canadian reactor (CANDU)

    International Nuclear Information System (INIS)

    Three main options in a CANDU fuel cycle involve use of: (1) natural uranium (0.711 weight percent U-235) fuel, (2) slightly enriched uranium (1.2 weight percent U-235) fuel, and (3) recovered uranium (0.83 weight percent U-235) fuel from light water reactor spent fuel. ORIGEN-2 computer code was used to identify composition of the spent fuel for each option, including the standard LWR fuel (3.3 weight percent U-235). Uranium and plutonium credit calculations were performed using ORIGEN-2 output. WIMSD-5 computer code was used to determine maximum discharge burnup values for each case. For the 3 cycles selected (natural uranium, slightly enriched uranium, recovered uranium), levelized fuel cycle cost calculations are performed over the reactor lifetime of 40 years, using unit process costs obtained from literature. Components of the fuel cycle costs are U purchase, conversion, enrichment, fabrication, SF storage, SF disposal, and reprocessing where applicable. Cost parameters whose effects on the fuel cycle cost are to be investigated are escalation ratio, discount rate and SF storage time. Cost estimations were carried out using specially developed computer programs. Share of each cost component on the total cost was determined and sensitivity analysis was performed in order to show how a change in a main cost component affects the fuel cycle cost. The main objective of this study has been to find out the most economical option for CANDU fuel cycle by changing unit prices and cost parameters

  18. Fuel handling machine and auxiliary systems for a fuel handling cell

    International Nuclear Information System (INIS)

    This working report is an update for as well as a supplement to an earlier fuel handling machine design (Kukkola and Roennqvist 2006). A focus in the earlier design proposal was primarily on the selection of a mechanical structure and operating principle for the fuel handling machine. This report introduces not only a fuel handling machine design but also auxiliary fuel handling cell equipment and its operation. An objective of the design work was to verify the operating principles of and space allocations for fuel handling cell equipment. The fuel handling machine is a remote controlled apparatus capable of handling intensely radiating fuel assemblies in the fuel handling cell of an encapsulation plant. The fuel handling cell is air tight space radiation-shielded with massive concrete walls. The fuel handling machine is based on a bridge crane capable of traveling in the handling cell along wall tracks. The bridge crane has its carriage provided with a carousel type turntable having mounted thereon both fixed and telescopic masts. The fixed mast has a gripper movable on linear guides for the transfer of fuel assemblies. The telescopic mast has a manipulator arm capable of maneuvering equipment present in the fuel handling cell, as well as conducting necessary maintenance and cleaning operations or rectifying possible fault conditions. The auxiliary fuel handling cell systems consist of several subsystems. The subsystems include a service manipulator, a tool carrier for manipulators, a material hatch, assisting winches, a vacuum cleaner, as well as a hose reel. With the exception of the vacuum cleaner, the devices included in the fuel handling cell's auxiliary system are only used when the actual encapsulation process is not ongoing. The malfunctions of mechanisms or actuators responsible for the motion actions of a fuel handling machine preclude in a worst case scenario the bringing of the fuel handling cell and related systems to a condition appropriate for

  19. Fuel handling machine and auxiliary systems for a fuel handling cell

    Energy Technology Data Exchange (ETDEWEB)

    Suikki, M. [Optimik Oy, Turku (Finland)

    2013-10-15

    This working report is an update for as well as a supplement to an earlier fuel handling machine design (Kukkola and Roennqvist 2006). A focus in the earlier design proposal was primarily on the selection of a mechanical structure and operating principle for the fuel handling machine. This report introduces not only a fuel handling machine design but also auxiliary fuel handling cell equipment and its operation. An objective of the design work was to verify the operating principles of and space allocations for fuel handling cell equipment. The fuel handling machine is a remote controlled apparatus capable of handling intensely radiating fuel assemblies in the fuel handling cell of an encapsulation plant. The fuel handling cell is air tight space radiation-shielded with massive concrete walls. The fuel handling machine is based on a bridge crane capable of traveling in the handling cell along wall tracks. The bridge crane has its carriage provided with a carousel type turntable having mounted thereon both fixed and telescopic masts. The fixed mast has a gripper movable on linear guides for the transfer of fuel assemblies. The telescopic mast has a manipulator arm capable of maneuvering equipment present in the fuel handling cell, as well as conducting necessary maintenance and cleaning operations or rectifying possible fault conditions. The auxiliary fuel handling cell systems consist of several subsystems. The subsystems include a service manipulator, a tool carrier for manipulators, a material hatch, assisting winches, a vacuum cleaner, as well as a hose reel. With the exception of the vacuum cleaner, the devices included in the fuel handling cell's auxiliary system are only used when the actual encapsulation process is not ongoing. The malfunctions of mechanisms or actuators responsible for the motion actions of a fuel handling machine preclude in a worst case scenario the bringing of the fuel handling cell and related systems to a condition appropriate for

  20. INVESTIGATION OF PEM FUEL CELL FOR AUTOMOTIVE USE

    OpenAIRE

    A K M Mohiuddin; Ataur Rahman; Mohamed Fadhil Chemani; Mohd Baihaqi Zakaria

    2015-01-01

    This paper provides a brief investigation on suitability of Proton-exchange  membrane fuel cells (PEMFCs) as the source of power for transportation purposes. Hydrogen is an attractive alternative transportation fuel. It is the least polluting fuel that can be used in an internal combustion engine (ICE) and it is widely available. If hydrogen is used in a fuel cell which converts the chemical energy of hydrogen into electricity, (NOx) emissions are eliminated. The investigation was carried out...

  1. Development of internal reforming carbonate fuel cell stack technology

    Energy Technology Data Exchange (ETDEWEB)

    Farooque, M.

    1990-10-01

    Activities under this contract focused on the development of a coal-fueled carbonate fuel cell system design and the stack technology consistent with the system design. The overall contract effort was divided into three phases. The first phase, completed in January 1988, provided carbonate fuel cell component scale-up from the 1ft{sup 2} size to the commercial 4ft{sup 2} size. The second phase of the program provided the coal-fueled carbonate fuel cell system (CGCFC) conceptual design and carried out initial research and development needs of the CGCFC system. The final phase of the program emphasized stack height scale-up and improvement of stack life. The results of the second and third phases are included in this report. Program activities under Phase 2 and 3 were designed to address several key development areas to prepare the carbonate fuel cell system, particularly the coal-fueled CFC power plant, for commercialization in late 1990's. The issues addressed include: Coal-Gas Related Considerations; Cell and Stack Technology Improvement; Carbonate Fuel Cell Stack Design Development; Stack Tests for Design Verification; Full-Size Stack Design; Test Facility Development; Carbonate Fuel Cell Stack Cost Assessment; and Coal-Fueled Carbonate Fuel Cell System Design. All the major program objectives in each of the topical areas were successfully achieved. This report is organized along the above-mentioned topical areas. Each topical area has been processed separately for inclusion on the data base.

  2. Solid oxide fuel cell power system development

    Energy Technology Data Exchange (ETDEWEB)

    Kerr, Rick [Delphi Automotive Systems, LLC., Troy, MI (United States); Wall, Mark [Independent Energy Partners Technology, LLC., Parker, CO (United States); Sullivan, Neal [Colorado School of Mines, Golden, CO (United States)

    2015-06-26

    This report summarizes the progress made during this contractual period in achieving the goal of developing the solid oxide fuel cell (SOFC) cell and stack technology to be suitable for use in highly-efficient, economically-competitive, commercially deployed electrical power systems. Progress was made in further understanding cell and stack degradation mechanisms in order to increase stack reliability toward achieving a 4+ year lifetime, in cost reduction developments to meet the SECA stack cost target of $175/kW (in 2007 dollars), and in operating the SOFC technology in a multi-stack system in a real-world environment to understand the requirements for reliably designing and operating a large, stationary power system.

  3. Fuel cell separator with compressible sealing flanges

    Science.gov (United States)

    Mientek, Anthony P.

    1985-04-30

    A separator for separating adjacent fuel cells in a stack of such cells includes a flat, rectangular, gas-impermeable plate disposed between adjacent cells and having two opposite side margins thereof folded back over one side of the plate to form two first seal flanges and having the other side margins thereof folded back over the opposite side of the plate to form two second seal flanges, each of the seal flanges cooperating with the plate to define a channel in which is disposed a resiliently compressible stack of thin metal sheets. The two first seal flanges cooperate with the electrolyte matrix of one of the cells to form a gas-impermeable seal between an electrode of the one cell and one of two reactant gas manifolds. The second seal flanges cooperate with the electrolyte matrix of the other cell for forming a gas-impermeable seal between an electrode of the other cell and the other of the two reactant gas manifolds. The seal flanges cooperate with the associated compressible stacks of sheets for maintaining a spacing between the plate and the electrolyte matrices while accommodating variation of that spacing.

  4. Dynamic behavior of gasoline fuel cell electric vehicles

    Science.gov (United States)

    Mitchell, William; Bowers, Brian J.; Garnier, Christophe; Boudjemaa, Fabien

    As we begin the 21st century, society is continuing efforts towards finding clean power sources and alternative forms of energy. In the automotive sector, reduction of pollutants and greenhouse gas emissions from the power plant is one of the main objectives of car manufacturers and innovative technologies are under active consideration to achieve this goal. One technology that has been proposed and vigorously pursued in the past decade is the proton exchange membrane (PEM) fuel cell, an electrochemical device that reacts hydrogen with oxygen to produce water, electricity and heat. Since today there is no existing extensive hydrogen infrastructure and no commercially viable hydrogen storage technology for vehicles, there is a continuing debate as to how the hydrogen for these advanced vehicles will be supplied. In order to circumvent the above issues, power systems based on PEM fuel cells can employ an on-board fuel processor that has the ability to convert conventional fuels such as gasoline into hydrogen for the fuel cell. This option could thereby remove the fuel infrastructure and storage issues. However, for these fuel processor/fuel cell vehicles to be commercially successful, issues such as start time and transient response must be addressed. This paper discusses the role of transient response of the fuel processor power plant and how it relates to the battery sizing for a gasoline fuel cell vehicle. In addition, results of fuel processor testing from a current Renault/Nuvera Fuel Cells project are presented to show the progress in transient performance.

  5. Increasing Fuel Efficiency of Direct Methanol Fuel Cell Systems with Feedforward Control of the Operating Concentration

    OpenAIRE

    Youngseung Na; Federico Zenith; Ulrike Krewer

    2015-01-01

    Most of the R&D on fuel cells for portable applications concentrates on increasing efficiencies and energy densities to compete with other energy storage devices, especially batteries. To improve the efficiency of direct methanol fuel cell (DMFC) systems, several modifications to system layouts and operating strategies are considered in this paper, rather than modifications to the fuel cell itself. Two modified DMFC systems are presented, one with an additional inline mixer and a further ...

  6. INTEGRATED GASIFICATION COMBINED CYCLE PROJECT 2 MW FUEL CELL DEMONSTRATION

    Energy Technology Data Exchange (ETDEWEB)

    FuelCell Energy

    2005-05-16

    With about 50% of power generation in the United States derived from coal and projections indicating that coal will continue to be the primary fuel for power generation in the next two decades, the Department of Energy (DOE) Clean Coal Technology Demonstration Program (CCTDP) has been conducted since 1985 to develop innovative, environmentally friendly processes for the world energy market place. The 2 MW Fuel Cell Demonstration was part of the Kentucky Pioneer Energy (KPE) Integrated Gasification Combined Cycle (IGCC) project selected by DOE under Round Five of the Clean Coal Technology Demonstration Program. The participant in the CCTDP V Project was Kentucky Pioneer Energy for the IGCC plant. FuelCell Energy, Inc. (FCE), under subcontract to KPE, was responsible for the design, construction and operation of the 2 MW fuel cell power plant. Duke Fluor Daniel provided engineering design and procurement support for the balance-of-plant skids. Colt Engineering Corporation provided engineering design, fabrication and procurement of the syngas processing skids. Jacobs Applied Technology provided the fabrication of the fuel cell module vessels. Wabash River Energy Ltd (WREL) provided the test site. The 2 MW fuel cell power plant utilizes FuelCell Energy's Direct Fuel Cell (DFC) technology, which is based on the internally reforming carbonate fuel cell. This plant is capable of operating on coal-derived syngas as well as natural gas. Prior testing (1992) of a subscale 20 kW carbonate fuel cell stack at the Louisiana Gasification Technology Inc. (LGTI) site using the Dow/Destec gasification plant indicated that operation on coal derived gas provided normal performance and stable operation. Duke Fluor Daniel and FuelCell Energy developed a commercial plant design for the 2 MW fuel cell. The plant was designed to be modular, factory assembled and truck shippable to the site. Five balance-of-plant skids incorporating fuel processing, anode gas oxidation, heat recovery

  7. Nanostructured Solid Oxide Fuel Cell Electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Sholklapper, Tal Zvi [Univ. of California, Berkeley, CA (United States)

    2007-01-01

    The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

  8. Electrochemical power sources batteries, fuel cells, and supercapacitors

    CERN Document Server

    Bagotsky, Vladimir S; Volfkovich, Yurij M

    2015-01-01

    Electrochemical Power Sources (EPS) provides in a concise way theoperational features, major types, and applications of batteries,fuel cells, and supercapacitors Details the design, operational features, andapplications of batteries, fuel cells, and supercapacitors Covers improvements of existing EPSs and thedevelopment of new kinds of EPS as the results of intense R&Dwork Provides outlook for future trends in fuel cells andbatteries Covers the most typical battery types, fuel cells andsupercapacitors; such as zinc-carbon batteries, alkaline manganesedioxide batteries, mercury-zinc cells, lead

  9. Fuel cell energy service Enron`s commerical program

    Energy Technology Data Exchange (ETDEWEB)

    Jacobson, M.W.

    1996-04-01

    Enron, the premier provider of clean fuels worldwide, has launched a unique energy service based on fuel cell technology. The goal of this program is to bring the benefits of fuel cell power to the broad commercial marketplace. Enron`s Energy Service is currently based on a 200 kilowatt phosphoric acid power plant manufactured by ONSI Corporation. This plant is fueled by natural gas or propane, and exhibits superior performance. Enron offers a `no hassle` package that provides customers with immediate benefits with no upfront capital or technical risks. This paper describes Enron`s fuel cell commercial program.

  10. Stable, Electroinactive Wetting Agent For Fuel Cells

    Science.gov (United States)

    Prakash, Surya G.; Olah, George A.; Narayanan, Sekharipuram R.; Surampudi, Subbarao; Halpert, Gerald

    1994-01-01

    Straight-chain perfluorooctanesulfonic acid (C8 acid) identified as innocuous and stable wetting agent for use with polytetrafluoroethylene-containing electrodes in liquid-feed direct-oxidation fuel cells suggested for use in vehicles and portable power supplies. C8 acid in small concentrations in aqueous liquid solutions of methanol, trimethoxymethane, dimethoxymethane, and trioxane enables oxidation of these substances by use of commercially available electrodes of type designed originally for use with gases. This function specific to C8 acid molecule and not achieved by other related perfluorolkanesulfonic acids.

  11. A high-power carbohydrate fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Larsson, Ragnar [SuFuCell AB, Bytaregatan 23, SE 222 21 Lund (Sweden); Folkesson, Boerje [Bronsaaldersvaegen 21, SE-226 54 Lund (Sweden); Spaziante, Placido M. [Cellennium Co., Ltd., 14th Floor Gypsum Metropolitan Tower, 539 Sri Ayudhaya Rd., Bangkok 10400 (Thailand); Veerasai, Waret [Chemistry Department, Faculty of Science, Mahidol University, Bangkok 10400 (Thailand); Exell, Robert H.B. [Joint Graduate School of Energy and Environment, King Mongkut' s University of Technology Thonburi, 91 Prachauthit Rd., Bangmod, Tungkru, Bangkok 10140 (Thailand)

    2006-04-01

    This paper reports the development of a fuel cell consisting of a vanadium flow battery in which the vanadium ions are reduced by sugar (from a carbohydrate) to oxidation state +3 on one side of a membrane, and are oxidized to state +5 on the other side by oxygen. The theoretical upper limit to the conversion efficiency of the energy in sugar by this method under standard conditions is 54%. We have obtained efficiencies up to 45% in our laboratory tests. This way of using biomass for electricity production avoids the Carnot cycle losses in heat engines. (author)

  12. Hydrogen and Fuel Cells for IT Equipment

    Energy Technology Data Exchange (ETDEWEB)

    Kurtz, Jennifer

    2016-03-09

    With the increased push for carbon-free and sustainable data centers, data center operators are increasingly looking to renewable energy as a means to approach carbon-free status and be more sustainable. The National Renewable Energy Laboratory (NREL) is a world leader in hydrogen research and already has an elaborate hydrogen infrastructure in place at the Golden, Colorado, state-of-the-art data center and facility. This presentation will discuss hydrogen generation, storage considerations, and safety issues as they relate to hydrogen delivery to fuel cells powering IT equipment.

  13. Silicon Based Direct Methanol Fuel Cells

    DEFF Research Database (Denmark)

    Larsen, Jackie Vincent

    collector electrodes. This design is based on catalytic in situ growth of carbon nanotubes and atomic layer deposition of active catalyst particles. The additional two fuel cell designs utilize a porous silicon structure as the mechanical support, using respectively a spray coated catalyst and atomic layer...... deposition for. This method of integration was investigated as a high internal volume support structure with potential for rapid batch fabrication. In characterization of the devices the work presents the development of an electrochemical impedance spectroscopy measurement setup capable of determining...

  14. Robust and reliable fuel cells; Robusta och tillfoerlitliga braensleceller

    Energy Technology Data Exchange (ETDEWEB)

    Nordlund, Joakim [Cellkraft AB, Stockholm (Sweden)

    2012-03-15

    For fuel cells to be a viable alternative for backup power in applications, where reliability is a critical factor, the reliability of fuel cells has to be high and documented. Based on intrinsic properties of fuel cells, it is safe to argue that it is possible to make them highly reliable, but to unleash the full reliability potential of fuel cells, some great engineering work has to be performed. Cellkraft has since many years been addressing this issue and this project is an important piece of this puzzle. The project included both a large number of laboratory testing of fuel cells and long experiments in field environment to verify the results from the laboratory work. The development work performed within this project is a solid base for the continuous work to fulfil Cellkraft's own, tough, technical reliability targets. The project targets below were achieved within this project: 1. The fuel cell start with 100 % reliability. 2. The fuel cell provides nominal power within 30 seconds in 100 % of the cases. 3. The fuel cell keeps providing nominal power as long as there is a demand in 100 % of the cases. 4. No cell in the fuel cell deviates from the mean cell potential with more than 0,1 V at full power.

  15. Proton exchange membrane fuel cell technology for transportation applications

    Energy Technology Data Exchange (ETDEWEB)

    Swathirajan, S. [General Motors R& D Center, Warren, MI (United States)

    1996-04-01

    Proton Exchange Membrane (PEM) fuel cells are extremely promising as future power plants in the transportation sector to achieve an increase in energy efficiency and eliminate environmental pollution due to vehicles. GM is currently involved in a multiphase program with the US Department of Energy for developing a proof-of-concept hybrid vehicle based on a PEM fuel cell power plant and a methanol fuel processor. Other participants in the program are Los Alamos National Labs, Dow Chemical Co., Ballard Power Systems and DuPont Co., In the just completed phase 1 of the program, a 10 kW PEM fuel cell power plant was built and tested to demonstrate the feasibility of integrating a methanol fuel processor with a PEM fuel cell stack. However, the fuel cell power plant must overcome stiff technical and economic challenges before it can be commercialized for light duty vehicle applications. Progress achieved in phase I on the use of monolithic catalyst reactors in the fuel processor, managing CO impurity in the fuel cell stack, low-cost electrode-membrane assembles, and on the integration of the fuel processor with a Ballard PEM fuel cell stack will be presented.

  16. Thermodynamic analysis of biofuels as fuels for high temperature fuel cells

    Science.gov (United States)

    Milewski, Jarosław; Bujalski, Wojciech; Lewandowski, Janusz

    2013-02-01

    Based on mathematical modeling and numerical simulations, applicativity of various biofuels on high temperature fuel cell performance are presented. Governing equations of high temperature fuel cell modeling are given. Adequate simulators of both solid oxide fuel cell (SOFC) and molten carbonate fuel cell (MCFC) have been done and described. Performance of these fuel cells with different biofuels is shown. Some characteristics are given and described. Advantages and disadvantages of various biofuels from the system performance point of view are pointed out. An analysis of various biofuels as potential fuels for SOFC and MCFC is presented. The results are compared with both methane and hydrogen as the reference fuels. The biofuels are characterized by both lower efficiency and lower fuel utilization factors compared with methane. The presented results are based on a 0D mathematical model in the design point calculation. The governing equations of the model are also presented. Technical and financial analysis of high temperature fuel cells (SOFC and MCFC) are shown. High temperature fuel cells can be fed by biofuels like: biogas, bioethanol, and biomethanol. Operational costs and possible incomes of those installation types were estimated and analyzed. A comparison against classic power generation units is shown. A basic indicator net present value (NPV) for projects was estimated and commented.

  17. MEMS-based fuel cells with integrated catalytic fuel processor and method thereof

    Science.gov (United States)

    Jankowski, Alan F.; Morse, Jeffrey D.; Upadhye, Ravindra S.; Havstad, Mark A.

    2011-08-09

    Described herein is a means to incorporate catalytic materials into the fuel flow field structures of MEMS-based fuel cells, which enable catalytic reforming of a hydrocarbon based fuel, such as methane, methanol, or butane. Methods of fabrication are also disclosed.

  18. Stability of solid oxide fuel cell materials

    Energy Technology Data Exchange (ETDEWEB)

    Armstrong, T.R.; Bates, J.L.; Coffey, G.W.; Pederson, L.R. [Pacific Northwest National Lab., Richland, WA (United States)] [and others

    1996-08-01

    Chromite interconnection materials in an SOFC are exposed to both highly oxidizing conditions at the cathode and to highly reducing conditions at the anode. Because such conditions could lead to component failure, the authors have evaluated thermal, electrical, chemical, and structural stabilities of these materials as a function of temperature and oxygen partial pressure. The crystal lattice of the chromites was shown to expand for oxygen partial pressures smaller than 10{sup {minus}10} atm, which could lead to cracking and debonding in an SOFC. Highly substituted lanthanum chromite compositions were the most susceptible to lattice expansion; yttrium chromites showed better dimensional stability by more than a factor of two. New chromite compositions were developed that showed little tendency for lattice expansion under strongly reducing conditions, yet provided a good thermal expansion match to other fuel cell components. Use of these new chromite interconnect compositions should improve long-term SOFC performance, particularly for planar cell configurations. Thermodynamic properties of substituted lanthanum manganite cathode compositions have been determined through measurement of electromotive force as a function of temperature. Critical oxygen decomposition pressures for Sr and Ca-substituted lanthanum manganites were established using cells based on a zirconia electrolyte. Strontium oxide and calcium oxide activities in a lanthanum manganite matrix were determined using cells based on strontium fluoride and calcium fluoride electrolytes, respectively. The compositional range of single-phase behavior of these ABO{sub 3}-type perovskites was established as a function of A/B cation ratios and the extent of acceptor doping. Before this work, very little thermodynamic information was in existence for substituted manganite compositions. Such information is needed to predict the long-term stability of solid oxide fuel cell assemblies.

  19. Assessment of bio-fuel options for solid oxide fuel cell applications

    Science.gov (United States)

    Lin, Jiefeng

    Rising concerns of inadequate petroleum supply, volatile crude oil price, and adverse environmental impacts from using fossil fuels have spurred the United States to promote bio-fuel domestic production and develop advanced energy systems such as fuel cells. The present dissertation analyzed the bio-fuel applications in a solid oxide fuel cell-based auxiliary power unit from environmental, economic, and technological perspectives. Life cycle assessment integrated with thermodynamics was applied to evaluate the environmental impacts (e.g., greenhouse gas emission, fossil energy consumption) of producing bio-fuels from waste biomass. Landfill gas from municipal solid wastes and biodiesel from waste cooking oil are both suggested as the promising bio-fuel options. A nonlinear optimization model was developed with a multi-objective optimization technique to analyze the economic aspect of biodiesel-ethanol-diesel ternary blends used in transportation sectors and capture the dynamic variables affecting bio-fuel productions and applications (e.g., market disturbances, bio-fuel tax credit, policy changes, fuel specification, and technological innovation). A single-tube catalytic reformer with rhodium/ceria-zirconia catalyst was used for autothermal reformation of various heavy hydrocarbon fuels (e.g., diesel, biodiesel, biodiesel-diesel, and biodiesel-ethanol-diesel) to produce a hydrogen-rich stream reformates suitable for use in solid oxide fuel cell systems. A customized mixing chamber was designed and integrated with the reformer to overcome the technical challenges of heavy hydrocarbon reformation. A thermodynamic analysis, based on total Gibbs free energy minimization, was implemented to optimize the operating environment for the reformations of various fuels. This was complimented by experimental investigations of fuel autothermal reformation. 25% biodiesel blended with 10% ethanol and 65% diesel was determined to be viable fuel for use on a truck travelling with

  20. Experimental Characterization and Modeling of PEM Fuel Cells

    DEFF Research Database (Denmark)

    Jespersen, Jesper Lebæk

    Fuel cells are strong candidates to become the power sources of the 21th century. Despite, being close to mass market entry for several years, fuel cells still are still only found in prototypes and very few commercial products. The reason for this is that fuel cells currently suffer from too high...... production prices and too short life times, in relation to market requirements. The focus of this thesis has been to develop experimental techniques, that can aid in the development of making fuel cells cheaper and more durable. The overall purpose of the experiments conducted in this project, is to provide...... fundamental knowledge of the transport and electrochemical processes of PEM fuel cells and to provide methods for obtaining high quality data for PEM fuel cell simulation model validation. In this thesis three different areas of experimental characterization techniques was investigated, they include: Stack...

  1. A gas utility approach to fuel cell commercialisation

    International Nuclear Information System (INIS)

    The most attractive application for fuel cells seems to be in decentralised combined heat and power generation (CHP). The market for energy efficient CHP is growing, partly as a result of the wish to decrease CO2 emissions. Gas utilities are facing this development and can react in different ways. One of these is to operate natural gas powered CHPs themselves. The attractiveness of fuel cell powered CHPs for gas utilities depends firstly on the economy and reliability of CHP in general in the markets considered and secondly on the competitiveness of fuel cells versus, for example, the gas engine and gas turbine based CHP. Important possible activities for a gas utility in relation to fuel cell commercialisation are helping develop the market for CHP, defining the requirements for fuel cells in CHP and helping the fuel cell manufacturers to build up practical experience by participating in demonstration projects. The situation in the Netherlands will be used for examples. (orig.)

  2. Dynamic simulation of a direct carbonate fuel cell power plant

    Energy Technology Data Exchange (ETDEWEB)

    Ernest, J.B. [Fluor Daniel, Inc., Irvine, CA (United States); Ghezel-Ayagh, H.; Kush, A.K. [Fuel Cell Engineering, Danbury, CT (United States)

    1996-12-31

    Fuel Cell Engineering Corporation (FCE) is commercializing a 2.85 MW Direct carbonate Fuel Cell (DFC) power plant. The commercialization sequence has already progressed through construction and operation of the first commercial-scale DFC power plant on a U.S. electric utility, the 2 MW Santa Clara Demonstration Project (SCDP), and the completion of the early phases of a Commercial Plant design. A 400 kW fuel cell stack Test Facility is being built at Energy Research Corporation (ERC), FCE`s parent company, which will be capable of testing commercial-sized fuel cell stacks in an integrated plant configuration. Fluor Daniel, Inc. provided engineering, procurement, and construction services for SCDP and has jointly developed the Commercial Plant design with FCE, focusing on the balance-of-plant (BOP) equipment outside of the fuel cell modules. This paper provides a brief orientation to the dynamic simulation of a fuel cell power plant and the benefits offered.

  3. Direct oxidation of jet fuels and Pennsylvania crude oil in a solid oxide fuel cell

    Science.gov (United States)

    Zhou, Z. F.; Gallo, C.; Pague, M. B.; Schobert, H.; Lvov, S. N.

    A Cu-ceria solid oxide fuel cell (SOFC) is shown to generate electric power using jet fuels and Pennsylvania crude oil through direct oxidation of the fuels. The liquid fuels contained up to 910 ppm of sulfur and were injected into the anode compartment either with or without N 2 dilution. The performance of the fuel cell was stable over 30 h for jet fuels and Pennsylvania crude oil without N 2 dilution whereas N 2 dilution prolonged the stable power generation up to 100 h for jet fuel and up to 80 h for Pennsylvania crude oil. The generated power density was about 0.1 W cm -2 for both fuels.

  4. Fuel cell propulsion for urban duty vehicles: Bavarian fuel cell bus project

    International Nuclear Information System (INIS)

    Following a feasibility study and a detailed specification phase, the realization of a fuel cell city bus prototype was started in autumn 1996. The project is a joint development effort of Siemens, MAN and Linde, which receives a 50 % funding by the Bavarian State Ministry for Economic Affairs, Transport and Technology (BStMWVT) in the context of the Hydrogen Initiative Bavaria. An MAN low-floor bus will be equipped with the components for a fuel cell drive system. The PEM fuel cell is developed by the power generation division of Siemens. Four fuel cell modules deliver a total electrical output of 120 kW to the two electric motors, which are linked by a summation gearbox by the Siemens Transportation Systems Division. MAN Technologie AG is responsible for the compressed hydrogen storage system allowing for a driving range of more than 250 km, while Linde AG takes care of the hydrogen periphery and delivers the hydrogen for the test operation scheduled for the beginning of the year 2000. Project coordination is done by Ludwig-Boelkow System-technik GmbH. The project is divided into four phases. The conceptual design phase is scheduled to last until the end of 1997. The partly overlapping system integration phase will end in the first quarter of 1999. The subsequent test and commissioning phase will prepare the test operation at the beginning of 2000 with a bus operator yet to be defined. (author)

  5. INVESTIGATION OF PEM FUEL CELL FOR AUTOMOTIVE USE

    Directory of Open Access Journals (Sweden)

    A. K. M. Mohiuddin

    2015-11-01

    Full Text Available This paper provides a brief investigation on suitability of Proton-exchange  membrane fuel cells (PEMFCs as the source of power for transportation purposes. Hydrogen is an attractive alternative transportation fuel. It is the least polluting fuel that can be used in an internal combustion engine (ICE and it is widely available. If hydrogen is used in a fuel cell which converts the chemical energy of hydrogen into electricity, (NOx emissions are eliminated. The investigation was carried out on a  fuel cell car model by implementing polymer electrolyte membrane (PEM types of fuel cell as the source of power to propel the prototype car. This PEMFC has capability to propel the electric motor by converting chemical energy stored in hydrogen gas into useful electrical energy. PEM fuel cell alone is used as the power source for the electric motor without the aid of any other power source such as battery associated with it. Experimental investigations were carried out to investigate the characteristics of fuel cell used and the performance of the fuel cell car. Investigated papameters are the power it develops, voltage, current and speed it produces under different load conditions. KEYWORDS: fuel cell; automotive; proton exchange membrane; polymer electrolyte membrane; internal combustion engine

  6. n-Hexadecane Fuel for a Phosphoric Acid Direct Hydrocarbon Fuel Cell

    OpenAIRE

    Yuanchen Zhu; Travis Robinson; Amani Al-Othman; Tremblay, André Y.; Marten Ternan

    2015-01-01

    The objective of this work was to examine fuel cells as a possible alternative to the diesel fuel engines currently used in railway locomotives, thereby decreasing air emissions from the railway transportation sector. We have investigated the performance of a phosphoric acid fuel cell (PAFC) reactor, with n-hexadecane, C16H34 (a model compound for diesel fuel, cetane number = 100). This is the first extensive study reported in the literature in which n-hexadecane is used directly as the fuel....

  7. High Temperature PEM Fuel Cells - Degradation and Durability

    DEFF Research Database (Denmark)

    Araya, Samuel Simon

    A harmonious mix of renewable and alternative energy sources, including fuel cells is necessary to mitigate problems associated with the current fossil fuel based energy system, like air pollution, Greenhouse Gas (GHG) emissions, and economic dependence on oil, and therefore on unstable areas...... of the globe. Fuel cells can harness the excess energy from other renewable sources, such as the big players in the renewable energy market, Photovoltaic (PV) panels and wind turbines, which inherently suffer from intermittency problems. The excess energy can be used to produce hydrogen from water or can...... be stored in liquid alcohols such as methanol, which can be sources of hydrogen for fuel cell applications. In addition, fuel cells unlike other technologies can use a variety of other fuels that can provide a source of hydrogen, such as biogas, methane, butane, etc. More fuel flexibility combined...

  8. Canadian petroleum industry review

    International Nuclear Information System (INIS)

    A wide ranging discussion about the factors that have influenced oil and natural gas prices, the differences of the Canadian market from international markets, the differences between eastern and western Canadian markets, and shareholders' perspectives on recent commodity price developments was presented. Developments in the OPEC countries were reviewed, noting that current OPEC production of 25 mmbbls is about 60 per cent higher than it was in 1985. It is expected that OPEC countries will continue to expand capacity to meet expected demand growth and the continuing need created by the UN embargo on Iraqi oil sales. Demand for natural gas is also likely to continue to rise especially in view of the deregulation of the electricity industry where natural gas may well become the favored fuel for incremental thermal generation capacity. Prices of both crude oil and natural gas are expected to hold owing to unusually low storage levels of both fuels. The inadequacy of infrastructure, particularly pipeline capacity as a key factor in the Canadian market was noted, along with the dynamic that will emerge in the next several years that may have potential consequences for Canadian production - namely the reversal of the Sarnia to Montreal pipeline. With regard to shareholders' expectations the main issues are (1) whether international markets reach back to the wellhead, hence the producer's positioning with respect to transportation capacity and contract portfolios, and (2) whether the proceeds from increased prices are invested in projects that are yielding more than the cost of capital. 28 figs

  9. Thin-Layer Fuel Cell for Teaching and Classroom Demonstrations

    Science.gov (United States)

    Shirkhanzadeh, M.

    2009-01-01

    A thin-layer fuel cell is described that is simple and easy to set up and is particularly useful for teaching and classroom demonstrations. The cell is both an electrolyzer and a fuel cell and operates using a thin layer of electrolyte with a thickness of approximately 127 micrometers and a volume of approximately 40 microliters. As an…

  10. Critical assessment of power trains with fuel-cell systems and different fuels

    Science.gov (United States)

    Höhlein, B.; von Andrian, S.; Grube, Th; Menzer, R.

    Legal regulations (USA, EU) are a major driving force for intensifying technological developments with respect to the global automobile market. In the future, highly efficient vehicles with very low emission levels will include low-temperature fuel-cell systems (PEFC) as units of electric power trains. With alcohols, ether or hydrocarbons used as fuels for these new electric power trains, hydrogen as PEFC fuel has to be produced on board. These concepts including the direct use of methanol in fuel-cell systems, differ considerably in terms of both their development prospects and the results achieved so far. Based on process engineering analyses for net electricity generation in PEFC-powered power trains, as well as on assumptions for electric power trains and vehicle configurations, different fuel-cell performances and fuel processing units for octane, diesel, methanol, ethanol, propane and dimethylether have been evaluated as fuels. The possible benefits and key challenges for different solutions of power trains with fuel-cell systems/on-board hydrogen production and with direct methanol fuel-cell (DMFC) systems have been assessed. Locally, fuel-cell power trains are almost emission-free and, unlike battery-powered vehicles, their range is comparable to conventional vehicles. Therefore, they have application advantages cases of particularly stringent emission standards requiring zero emission. In comparison to internal combustion engines, using fuel-cell power trains can lead to clear reductions in primary energy demand and global, climate-relevant emissions providing the advantage of the efficiency of the hydrogen/air reaction in the fuel cell is not too drastically reduced by additional conversion steps of on-board hydrogen production, or by losses due to fuel supply provision.

  11. State of the States: Fuel Cells in America 2013

    Energy Technology Data Exchange (ETDEWEB)

    Curtin, Sandra; Gangi, Jennifer

    2013-10-31

    This October 2013 report, written by Fuel Cells 2000 and partially funded by the U.S. Department of Energy's Fuel Cell Technologies Office, continues to build on the April 2010 State of the States report that provided a snapshot of fuel cell and hydrogen activity in the 50 states and District of Columbia. This update report provides more details on the progress and activities that happened since the third report, issued in August 2012.

  12. Commercialization of Fuel Cell Bipolar Plate Manufacturing by Electromagnetic Forming

    OpenAIRE

    Daehn, G. S.; Hatkevich, S.; Shang, J.; Wilkerson, L.

    2010-01-01

    The cost of manufacturing bipolar plates is a major component to the overall cost structure of a Proton Exchange Membrane (PEM) fuel cell stack. To achieve the commercialization of PEM fuel cells, a high volume and low cost manufacturing process for the bipolar plate must be developed. American Trim has identified high velocity electromagnetic forming as a suitable technology to manufacture metallic fuel cell bipolar plates, because of its low capital cost, flexible tooling and rapid prototyp...

  13. Power Conversion System Strategies for Fuel Cell Vehicles

    Institute of Scientific and Technical Information of China (English)

    Kaushik Rajashekara

    2005-01-01

    Power electronics is an enabling technology for the development of environmental friendly fuel cell vehicles, and to implement the various vehicle electrical architectures to obtain the best performance. In this paper, power conversion strategies for propulsion and auxiliary power unit applications are described. The power electronics strategies for the successful development of the fuel cell vehicles are presented. The fuel cell systems for propulsion and for auxiliary power unit applications are also discussed.

  14. Analysis of fuel cell hybrid locomotives

    Science.gov (United States)

    Miller, Arnold R.; Peters, John; Smith, Brian E.; Velev, Omourtag A.

    Led by Vehicle Projects LLC, an international industry-government consortium is developing a 109 t, 1.2 MW road-switcher locomotive for commercial and military railway applications. As part of the feasibility and conceptual-design analysis, a study has been made of the potential benefits of a hybrid power plant in which fuel cells comprise the prime mover and a battery or flywheel provides auxiliary power. The potential benefits of a hybrid power plant are: (i) enhancement of transient power and hence tractive effort; (ii) regenerative braking; (iii) reduction of capital cost. Generally, the tractive effort of a locomotive at low speed is limited by wheel adhesion and not by available power. Enhanced transient power is therefore unlikely to benefit a switcher locomotive, but could assist applications that require high acceleration, e.g. subway trains with all axles powered. In most cases, the value of regeneration in locomotives is minimal. For low-speed applications such as switchers, the available kinetic energy and the effectiveness of traction motors as generators are both minimal. For high-speed heavy applications such as freight, the ability of the auxiliary power device to absorb a significant portion of the available kinetic energy is low. Moreover, the hybrid power plant suffers a double efficiency penalty, namely, losses occur in both absorbing and then releasing energy from the auxiliary device, which result in a net storage efficiency of no more than 50% for present battery technology. Capital cost in some applications may be reduced. Based on an observed locomotive duty cycle, a cost model shows that a hybrid power plant for a switcher may indeed reduce capital cost. Offsetting this potential benefit are the increased complexity, weight and volume of the power plant, as well as 20-40% increased fuel consumption that results from lower efficiency. Based on this analysis, the consortium has decided to develop a pure fuel cell road-switcher locomotive

  15. The promise of fuel cell-based automobiles

    Indian Academy of Sciences (India)

    A K Shukla; C L Jackson; K Scott

    2003-02-01

    Fuel cell-based automobiles have gained attention in the last few years due to growing public concern about urban air pollution and consequent environmental problems. From an analysis of the power and energy requirements of a modern car, it is estimated that a base sustainable power of $ca$. 50 kW supplemented with short bursts up to 80 kW will suffice in most driving requirements. The energy demand depends greatly on driving characteristics but under normal usage is expected to be 200 Wh/km. The advantages and disadvantages of candidate fuel-cell systems and various fuels are considered together with the issue of whether the fuel should be converted directly in the fuel cell or should be reformed to hydrogen onboard the vehicle. For fuel cell vehicles to compete successfully with conventional internal-combustion engine vehicles, it appears that direct conversion fuel cells using probably hydrogen, but possibly methanol, are the only realistic contenders for road transportation applications. Among the available fuel cell technologies, polymer–electrolyte fuel cells directly fueled with hydrogen appear to be the best option for powering fuel cell vehicles as there is every prospect that these will exceed the performance of the internal-combustion engine vehicles but for their first cost. A target cost of $ 50/kW would be mandatory to make polymer–electrolyte fuel cells competitive with the internal combustion engines and can only be achieved with design changes that would substantially reduce the quantity of materials used. At present, prominent car manufacturers are deploying important research and development efforts to develop fuel cell vehicles and are projecting to start production by 2005.

  16. The new generation of vehicles: market opportunities for fuel cells

    Science.gov (United States)

    Chalk, Steven G.; Patil, Pandit G.; Venkateswaran, S. R.

    The Partnership for a New Generation of Vehicles (PNGV), a historic US Government-auto industry partnership initiated in 1993, is pursuing three specific, interrelated goals, including the development of the next generation of vehicles capable of achieving up to three times the fuel efficiency of today's comparable vehicles. Fuel cells have been identified as one of three primary propulsion system candidates to meet this triple fuel efficiency goal, since they can dramatically increase automotive propulsion efficiency combined with very low to zero emissions. The US Government is working closely with industry and research institutions in pursuing a strategy of aggressive research and development (R&D) to accelerate the commercialization of fuel cell vehicles. The US Department of Energy has a major role in this fuel cell technology development effort. R&D activities are focused on overcoming the major technical, economic, and infrastructure-related hurdles. The high efficiency, very low emissions, and other favorable characteristics of fuel cells (such as fuel flexibility, low noise, and vibration) create significant market opportunities for fuel cells over the entire spectrum of transportation applications. While the focus of near-term markets for fuel cell vehicles will be urban areas having severe air-quality problems, long-term market prospects are encouraging since fuel cell vehicles can compete on an even ground with conventional vehicles in all key aspects, including vehicle range and refueling. This paper will discuss near- and long-term market opportunities for fuel cells in transportation and provide an update on driving regulatory developments in the USA at the federal and state level. The paper also provides an introduction to the PNGV (focusing on the role and prospects for fuel cells) and discusses the status of fuel cell vehicle development projects.

  17. Petroleum Diesel and Biodiesel Fuels Used in a Direct Hydrocarbon Phosphoric Acid Fuel Cell

    Directory of Open Access Journals (Sweden)

    Yuanchen Zhu

    2015-01-01

    Full Text Available The performance of a direct hydrocarbon phosphoric acid fuel cell, PAFC, was investigated using petroleum diesel, biodiesel, and n-hexadecane as the fuels. We believe this is the first study of a fuel cell being operated with petroleum diesel as the fuel at the anode. Degradation in fuel cell performance was observed prior to reaching steady state. The degradation was attributed to a carbonaceous material forming on the surface of the anode. Regardless of the initial degradation, a steady-state operation was achieved with each of the diesel fuels. After treating the anode with water the fuel cell performance recovered. However, the fuel cell performance degraded again prior to obtaining another steady-state operation. There were several observations that were consistent with the suggestion that the carbonaceous material formed from the diesel fuels might be a reaction intermediate necessary for steady-state operation. Finally, the experiments indicated that water in the phosphoric acid electrolyte could be used as the water required for the anodic reaction. The water formed at the cathode could provide the replacement water for the electrolyte, thereby eliminating the need to provide a water feed system for the fuel cell.

  18. CHP Fuel Cell Durability Demonstration - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Petrecky, James; Ashley, Christopher J

    2014-07-21

    Plug Power has managed a demonstration project that has tested multiple units of its high-temperature, PEM fuel cell system in micro-combined heat and power (μ-CHP) applications in California. The specific objective of the demonstration project was to substantiate the durability of GenSys Blue, and, thereby, verify its technology and commercial readiness for the marketplace. In the demonstration project, Plug Power, in partnership with the National Fuel Cell Research Center (NFCRC) at the University of California, Irvine (UCI), and Sempra, will execute two major tasks: • Task 1: Internal durability/reliability fleet testing. Six GenSys Blue units will be built and will undergo an internal test regimen to estimate failure rates. This task was modified to include 3 GenSys Blue units installed in a lab at UCI. • Task 2: External customer testing. Combined heat and power units will be installed and tested in real-world residential and/or light commercial end user locations in California.

  19. Learning curves for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Rivera-Tinoco, R.; Schoots, K. [Energy research Centre of the Netherlands (Netherlands). Policy Studies; Zwaan, B.C.C. van der [Energy research Centre of the Netherlands (Netherlands). Policy Studies; Columbia Univ., New York City, NY (United States). Lenfest Center for Sustainable Energy

    2010-07-01

    We present learning curves for solid oxide fuel cells (SOFCs) and combined heat and power (CHP) SOFC systems with an electric capacity between 1 and 250 kW. On the basis of the cost breakdown of production cost data from fuel cell manufacturers, we developed a bottom-up model that allows for determining overall manufacturing costs from their respective cost components, among which material, energy, labor, and capital charges. The results obtained from our model prove to deviate by at most 13% from total cost figures quoted in the literature. For the early pilot stage of development, we find for SOFC manufacturing a learning rate between 14% and 17%, and for total SOFC system fabrication between 16% and 19%. We argue that the corresponding cost reductions result largely from learning-by-searching effects (R and D) rather than learning-by-doing. When considering a longer time frame that includes the early commercial production stage, we find learning rates between 14% and 39%, which represent a mix of phenomena such as learning-by-doing, learning-by-searching, economies-of-scale and automation. (orig.)

  20. Alternate Fuel Cell Membranes for Energy Independence

    Energy Technology Data Exchange (ETDEWEB)

    Storey, Robson, F.; Mauritz, Kenneth, A.; Patton, Derek, L.; Savin, Daniel, A.

    2012-12-18

    The overall objective of this project was the development and evaluation of novel hydrocarbon fuel cell (FC) membranes that possess high temperature performance and long term chemical/mechanical durability in proton exchange membrane (PEM) fuel cells (FC). The major research theme was synthesis of aromatic hydrocarbon polymers of the poly(arylene ether sulfone) (PAES) type containing sulfonic acid groups tethered to the backbone via perfluorinated alkylene linkages and in some cases also directly attached to the phenylene groups along the backbone. Other research themes were the use of nitrogen-based heterocyclics instead of acid groups for proton conduction, which provides high temperature, low relative humidity membranes with high mechanical/thermal/chemical stability and pendant moieties that exhibit high proton conductivities in the absence of water, and synthesis of block copolymers consisting of a proton conducting block coupled to poly(perfluorinated propylene oxide) (PFPO) blocks. Accomplishments of the project were as follows: 1) establishment of a vertically integrated program of synthesis, characterization, and evaluation of FC membranes, 2) establishment of benchmark membrane performance data based on Nafion for comparison to experimental membrane performance, 3) development of a new perfluoroalkyl sulfonate monomer, N,N-diisopropylethylammonium 2,2-bis(p-hydroxyphenyl) pentafluoropropanesulfonate (HPPS), 4) synthesis of random and block copolymer membranes from HPPS, 5) synthesis of block copolymer membranes containing high-acid-concentration hydrophilic blocks consisting of HPPS and 3,3'-disulfonate-4,4'-dichlorodiphenylsulfone (sDCDPS), 6) development of synthetic routes to aromatic polymer backbones containing pendent 1H-1,2,3-triazole moieties, 7) development of coupling strategies to create phase-separated block copolymers between hydrophilic sulfonated prepolymers and commodity polymers such as PFPO, 8) establishment of basic

  1. Cornell Fuel Cell Institute: Materials Discovery to Enable Fuel Cell Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Abruna, H.D.; DiSalvo, Francis J.

    2012-06-29

    The discovery and understanding of new, improved materials to advance fuel cell technology are the objectives of the Cornell Fuel Cell Institute (CFCI) research program. CFCI was initially formed in 2003. This report highlights the accomplishments from 2006-2009. Many of the grand challenges in energy science and technology are based on the need for materials with greatly improved or even revolutionary properties and performance. This is certainly true for fuel cells, which have the promise of being highly efficient in the conversion of chemical energy to electrical energy. Fuel cells offer the possibility of efficiencies perhaps up to 90 % based on the free energy of reaction. Here, the challenges are clearly in the materials used to construct the heart of the fuel cell: the membrane electrode assembly (MEA). The MEA consists of two electrodes separated by an ionically conducting membrane. Each electrode is a nanocomposite of electronically conducting catalyst support, ionic conductor and open porosity, that together form three percolation networks that must connect to each catalyst nanoparticle; otherwise the catalyst is inactive. This report highlights the findings of the three years completing the CFCI funding, and incudes developments in materials for electrocatalyts, catalyst supports, materials with structured and functional porosity for electrodes, and novel electrolyte membranes. The report also discusses developments at understanding electrocatalytic mechanisms, especially on novel catalyst surfaces, plus in situ characterization techniques and contributions from theory. Much of the research of the CFCI continues within the Energy Materials Center at Cornell (emc2), a DOE funded, Office of Science Energy Frontier Research Center (EFRC).

  2. Performance optimization of a PEM hydrogen-oxygen fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Sadiq Al-Baghdadi, Maher A.R. [Fuel Cell Research Center, International Energy and Environment Foundation, Al-Najaf, P.O.Box 39 (Iraq)

    2013-07-01

    The objective was to develop a semi-empirical model that would simulate the performance of proton exchange membrane (PEM) fuel cells without extensive calculations. A fuel cell mathematical module has been designed and constructed to determine the performance of a PEM fuel cell. The influence of some operating parameters on the performance of PEM fuel cell has been investigated using pure hydrogen on the anode side and oxygen on the cathode side. The present model can be used to investigate the influence of process variables for design optimization of fuel cells, stacks, and complete fuel cell power system. The possible mechanisms of the parameter effects and their interrelationships are discussed. In order to assess the validity of the developed model a real PEM fuel cell system has been used to generate experimental data. The comparison shows good agreements between the modelling results and the experimental data. The model is shown a very useful for estimating the performance of PEM fuel cell stacks and optimization of fuel cell system integration and operation.

  3. Stack configurations for tubular solid oxide fuel cells

    Science.gov (United States)

    Armstrong, Timothy R.; Trammell, Michael P.; Marasco, Joseph A.

    2010-08-31

    A fuel cell unit includes an array of solid oxide fuel cell tubes having porous metallic exterior surfaces, interior fuel cell layers, and interior surfaces, each of the tubes having at least one open end; and, at least one header in operable communication with the array of solid oxide fuel cell tubes for directing a first reactive gas into contact with the porous metallic exterior surfaces and for directing a second reactive gas into contact with the interior surfaces, the header further including at least one busbar disposed in electrical contact with at least one surface selected from the group consisting of the porous metallic exterior surfaces and the interior surfaces.

  4. State of the States. Fuel Cells in America 2012

    Energy Technology Data Exchange (ETDEWEB)

    Curtin, Sandra [Fuel Cells 2000, Washington, DC (United States); Gangi, Jennifer [Fuel Cells 2000, Washington, DC (United States); Skukowski, Ryan [Fuel Cells 2000, Washington, DC (United States)

    2012-09-01

    This report, written by Fuel Cells 2000 and partially funded by the U.S. Department of Energy's Fuel Cell Technologies Program, continues to build on the April 2010 State of the States report that provided a snapshot of fuel cell and hydrogen activity in the 50 states and District of Columbia. This update report provides more details on the progress and activities that happened since the second report, issued in June 2011. Details reported for each state include new policies and funding, recent and planned fuel cell and hydrogen installations, and recent activity by state industry and universities.

  5. DoD Climate Change Fuel Cell Program

    Energy Technology Data Exchange (ETDEWEB)

    Steven A. Gabrielle

    2007-04-30

    A grant was awarded to PPL EnergyPlus, LLC for two (2) 250kW Molten Carbonate Fuel Cells at Pepperidge Farm, Inc. on 9/30/03. Pepperidge Farm subsequently signed a contract for one 250kW fuel cell. A request was made and granted to apply the award for the second fuel cell to the Sheraton New York Hotel & Towers (see attached email). This report discusses the first year of operation of a fuel cell power plant located at Pepperidge Farm, Inc., Bloomfield, Connecticut and a fuel cell power plant located at Sheraton New York Hotel & Towers, New York, New York. PPL EnergyPlus, LLC installed the plants under a contract with Pepperidge Farm and Starwood Hotels & Resorts Worldwide, Inc. Two DFC 300 fuel cells, manufactured by FuelCell Energy, Inc. of Danbury, CT were selected for the project. The fuel cell located at Pepperidge Farm successfully operated from January 16, 2006 to January 15, 2007. The fuel cell located at Sheraton New York Hotel & Tower successfully operated from May 19, 2005 to May 18, 2006.This report discusses the performance of these plants during these periods.

  6. Functionalized Graphitic Supports for Improved Fuel Cell Catalyst Stability Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Physical Sciences Inc. (PSI) together with the University of Connecticut (UCONN) proposes to demonstrate the improved fuel cell catalyst support durability offered...

  7. Fuel cell added value for early market applications

    Science.gov (United States)

    Hardman, Scott; Chandan, Amrit; Steinberger-Wilckens, Robert

    2015-08-01

    Fuel Cells are often considered in the market place as just power providers. Whilst fuel cells do provide power, there are additional beneficial characteristics that should be highlighted to consumers. Due to the high price premiums associated with fuel cells, added value features need to be exploited in order to make them more appealing and increase unit sales and market penetration. This paper looks at the approach taken by two companies to sell high value fuel cells to niche markets. The first, SFC Energy, has a proven track record selling fuel cell power providers. The second, Bloom Energy, is making significant progress in the US by having sold its Energy Server to more than 40 corporations including Wal-Mart, Staples, Google, eBay and Apple. Further to these current markets, two prospective added value applications for fuel cells are discussed. These are fuel cells for aircraft APUs and fuel cells for fire prevention. These two existing markets and two future markets highlight that fuel cells are not just power providers. Rather, they can be used as solutions to many needs, thus being more cost effective by replacing a number of incumbent systems at the same time.

  8. Electrically Conductive, Hydrophilic Porous Membrane for Fuel Cell Applications Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This Phase I effort seeks to produce a conductive polyethersulfone (PES) microporous membrane for fuel cell water management applications. This membrane will...

  9. Advanced Fuel Cell System Thermal Management for NASA Exploration Missions

    Science.gov (United States)

    Burke, Kenneth A.

    2009-01-01

    The NASA Glenn Research Center is developing advanced passive thermal management technology to reduce the mass and improve the reliability of space fuel cell systems for the NASA exploration program. An analysis of a state-of-the-art fuel cell cooling systems was done to benchmark the portion of a fuel cell system s mass that is dedicated to thermal management. Additional analysis was done to determine the key performance targets of the advanced passive thermal management technology that would substantially reduce fuel cell system mass.

  10. GATE Center for Automotive Fuel Cell Systems at Virginia Tech

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, Douglas [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)

    2011-09-30

    The Virginia Tech GATE Center for Automotive Fuel Cell Systems (CAFCS) achieved the following objectives in support of the domestic automotive industry: Expanded and updated fuel cell and vehicle technologies education programs; Conducted industry directed research in three thrust areas development and characterization of materials for PEM fuel cells; performance and durability modeling for PEM fuel cells; and fuel cell systems design and optimization, including hybrid and plug-in hybrid fuel cell vehicles; Developed MS and Ph.D. engineers and scientists who are pursuing careers related to fuel cells and automotive applications; Published research results that provide industry with new knowledge which contributes to the advancement of fuel cell and vehicle systems commercialization. With support from the Dept. of Energy, the CAFCS upgraded existing graduate course offerings; introduced a hands-on laboratory component that make use of Virginia Tech's comprehensive laboratory facilities, funded 15 GATE Fellowships over a five year period; and expanded our program of industry interaction to improve student awareness of challenges and opportunities in the automotive industry. GATE Center graduate students have a state-of-the-art research experience preparing them for a career to contribute to the advancement fuel cell and vehicle technologies.

  11. Lowering the temperature of solid oxide fuel cells.

    Science.gov (United States)

    Wachsman, Eric D; Lee, Kang Taek

    2011-11-18

    Fuel cells are uniquely capable of overcoming combustion efficiency limitations (e.g., the Carnot cycle). However, the linking of fuel cells (an energy conversion device) and hydrogen (an energy carrier) has emphasized investment in proton-exchange membrane fuel cells as part of a larger hydrogen economy and thus relegated fuel cells to a future technology. In contrast, solid oxide fuel cells are capable of operating on conventional fuels (as well as hydrogen) today. The main issue for solid oxide fuel cells is high operating temperature (about 800°C) and the resulting materials and cost limitations and operating complexities (e.g., thermal cycling). Recent solid oxide fuel cells results have demonstrated extremely high power densities of about 2 watts per square centimeter at 650°C along with flexible fueling, thus enabling higher efficiency within the current fuel infrastructure. Newly developed, high-conductivity electrolytes and nanostructured electrode designs provide a path for further performance improvement at much lower temperatures, down to ~350°C, thus providing opportunity to transform the way we convert and store energy.

  12. A review of liquid metal anode solid oxide fuel cells

    Directory of Open Access Journals (Sweden)

    ALIYA TOLEUOVA

    2013-06-01

    Full Text Available This review discusses recent advances in a solid oxide fuel cell (SOFC variant that uses liquid metal electrodes (anodes with the advantage of greater fuel tolerance and the ability to operate on solid fuel. Key features of the approach are discussed along with the technological and research challenges that need to be overcome for scale-up and commercialisation.

  13. Fuel cell design using a new heuristic method

    International Nuclear Information System (INIS)

    In this paper a new method for the pre-design of a typical fuel cell with a structural array of 10 x 10 fuel elements for a BWR is presented. The method is based on principles of maximum dispersion and minimum peaks of local power within the array of fuel elements. The pre-design of the fuel cells is made by simulation in two dimensions (2-D) through the cells physics code CASMO-4. For this purpose of pre-design the search process is guided by an objective function which is a combination of the main neutronic parameters of the fuel cell. The results show that the method is a promising tool that could be used for the design of fuel cells for use in a nuclear plant BWR. (Author)

  14. High Temperature PEM Fuel Cells and Organic Fuels

    OpenAIRE

    Vassiliev, Anton; Bjerrum, Niels J.; Jensen, Jens Oluf; Li, Qingfeng

    2014-01-01

    Modern way of life demands enormous amounts of energy, which so far has been mainly produced by combustion of various types of fossil fuel. Increased amounts of atmospheric CO2 and global warming leading to severe climate changes are the consequence. There is a need to make the energy production sustainable and break the dependency on fossil fuels. Hydrogen economy provides such a solution, where hydrogen produced by renewables, such as wind and solar power, becomes the energy carrier. The st...

  15. Break-in and Performance Issues on a single cell PBI-based PEM Fuel Cell

    DEFF Research Database (Denmark)

    Kær, Søren Knudsen; Jespersen, Jesper Lebæk

    Depending on the application in question and the load cycle of operation, fuel cell degradation can be a serious problem. Fuel cell degradation of PBI-based MEA's and fuel cells in general is quite complex. The rate of degradation depends on several parameters, where the operating temperature...... and the current drawn from the fuel cell are of great importance. One must therefore choose the point of operation carefully in order for the fuel cell to fulfil the requirements for lifetime perform-ance of the system. Break-in of fuel cells is often done in scientific experiments to improve the performance...... of the fuel cell, even though break-in of a fuel cell implemented in a commercial application would most likely not be feasible. In the present work a commercially available PBI-based high temperature MEA is subject to a break-in procedure, as specified by the manufacturer. The cell was operated at 160 °C...

  16. High Temperature PEM Fuel Cell Systems, Control and Diagnostics

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen; Justesen, Kristian Kjær;

    2015-01-01

    Various system topologies are available when it comes to designing high temperature PEM fuel cell systems. Very simple system designs are possible using pure hydrogen, and more complex system designs present themselves when alternative fuels are desired, using reformer systems. The use of reformed...... fuels utilizes one of the main advantages of the high temperature PEM fuel cell: robustness to fuel quality and impurities. In order for such systems to provide efficient, robust, and reliable energy, proper control strategies are needed. The complexity and nonlinearity of many of the components...

  17. Risk and investment in the fuel cell industry

    International Nuclear Information System (INIS)

    The energy industry is one of the building blocks of the new economy. Currently, the global energy industry is going through a transformation from high carbon content fuels like crude oil to less carbon content fuels like natural gas and hydrogen. Fuel cells are the backbone of the hydrogen economy. Advances in fuel cell technology have the potential to improve the living standards of people in all countries. New sources of financial capital, however, remain a problem. In the fuel cell industry, the future of a firm often depends upon the success or failure of a few key products. This tends to make these firms very risky to invest in and, as a result, makes it difficult for these firms to secure financial investment capital. Oil price movements remain one very important source of risk to fuel cell companies. Conventional wisdom suggests that higher oil prices stimulate interest in alternative energy sources like fuel cells and the stock prices of publicly traded fuel cell companies tend to perform well when oil prices are high. Lower oil prices, however, have the opposite effect. Consequently, oil price movements may affect the rates of return of the companies currently in the fuel cell industry. In this paper, we empirically analyze the stock price sensitivity of a sample of fuel cell companies to oil price risk. In particular, we look at both the impact and magnitude of oil price changes on fuel cell stock prices. Both symmetric and asymmetric oil price changes are considered. Our results indicate that oil price risk is not an important source of risk that impacts the equity returns of fuel cell companies. We find that market risk factors are much more important. We then offer suggestions on how to manage this risk. These results are useful for managers, investors, policy makers, and others who are interested in the strategic management, financing and risk management of firms building the hydrogen economy. (author)

  18. Proceedings of the third annual fuel cells contractors review meeting

    Energy Technology Data Exchange (ETDEWEB)

    Huber, W.J. (ed.)

    1991-06-01

    The overall objective of this program is to develop the essential technology for private sector characterization of the various fuel cell electrical generation systems. These systems promise high fuel to electricity efficiencies (40 to 60 percent), distinct possibilities for cogeneration applications, modularity of design, possibilities of urban siting, and environmentally benign emissions. The purpose of this meeting was to provide the research and development (R D) participants in the DOE/Fossil Energy-sponsored Fuel Cells Program with the opportunity to present key results of their research and to establish closer business contacts. Major emphasis was on phosphoric acid, molten carbonate, and solid oxide technology efforts. Research results of the coal gasification and gas stream cleanup R D activities pertinent to the Fuel Cells Program were also highlighted. Two hundred seventeen attendees from industry, utilities, academia, and Government participated in this 2-day meeting. Twenty-three papers were given in three formal sessions: molten carbonate fuel cells R D (9 papers), solid oxide fuel cells (8 papers), phosphoric acid fuel cells R D (6 papers). In addition to the papers and presentations, these proceedings also include comments on the Fuel Cells Program from the viewpoint of DOE/METC Fuel Cell Overview by Rita A. Bajura, DOE/METC Perspective by Manville J. Mayfield, Electric Power Research Institute by Daniel M. Rastler, Natural Gas by Hugh D. Guthrie, and Transportation Applications by Pandit G. Patil.

  19. High performance zinc air fuel cell stack

    Science.gov (United States)

    Pei, Pucheng; Ma, Ze; Wang, Keliang; Wang, Xizhong; Song, Mancun; Xu, Huachi

    2014-03-01

    A zinc air fuel cell (ZAFC) stack with inexpensive manganese dioxide (MnO2) as the catalyst is designed, in which the circulation flowing potassium hydroxide (KOH) electrolyte carries the reaction product away and acts as a coolant. Experiments are carried out to investigate the characteristics of polarization, constant current discharge and dynamic response, as well as the factors affecting the performance and uniformity of individual cells in the stack. The results reveal that the peak power density can be as high as 435 mW cm-2 according to the area of the air cathode sheet, and the influence factors on cell performance and uniformity are cell locations, filled state of zinc pellets, contact resistance, flow rates of electrolyte and air. It is also shown that the time needed for voltages to reach steady state and that for current step-up or current step-down are both in milliseconds, indicating the ZAFC can be excellently applied to vehicles with rapid dynamic response demands.

  20. Organic dyestuffs as catalysts for fuel cells.

    Science.gov (United States)

    Jahnke, H; Schönborn, M; Zimmermann, G

    1976-01-01

    Electrocatalysis in fuel cells requires as well substances capable of catalyzing the anodic oxidation of fuels as catalysts for the cathodic reduction of oxygen. Several dyestuffs that catalyze oxygen reduction are known, but up to now only one has been described as active in anodic reactions. All these dyestuffs are N4-chelates. Comparative studies have shown that chelates with other types of coordination, in particular N202-, 04-, N2S2- and S4-chelates, are able to catalyze the reduction of oxygen, though they are considerably less active than the N4-compounds. With a given type of coordination, the nature of the central atom has a decisive influence on the catalytic activity of the dyestuff, whereas substitution on the organic skeleton has only a slight effect. Thermal pretreatment of the N4-chelates can considerably increase their stability in electrolytes containing sulfuric acid. All the experimental results point to the conclusion that, with electrocatalysts, as with natural oxygen carriers, the interaction essential for catalysis takes place between the oxygen and the central metal ion. Various assumptions may be made as to the nature of the rate-determining step. The cathodic reduction of oxygen can be regarded as redox catalysis, or it can be considered from the standpoint of molecular orbital theory. The models hitherto suggested for the mechanism of oxygen reduction are tested against the experimental results and a modified model based on MO theory is put forward. PMID:7032

  1. Design of a Fuel Cell Hybrid Electric Vehicle Drive System

    DEFF Research Database (Denmark)

    Schaltz, Erik

    supply system of the truck which was powered by a lead-acid battery package. The FCSPP includes fuel storage, a fuel cell system, an energy storage device, power electronics, an electric machine, and the necessary control. The FCSPP therefore converts the energy of the fuel to a shaft torque and speed...... of the electric machine. In the thesis the High Temperature Proton Exchange Membrane Fuel Cell (HTPEMFC) is used as it has promising properties for being supplied by reformed methanol, instead of pure hydrogen, which is more practical feasible. It takes approximately 6 minutes before the fuel cell is ready...... to produce power. In this period an energy storage device is necessary in order to provide power for the electric machines, and to heat-up the fuel cell stack. The energy storage device also takes care of the peak loads, the high load dynamics, and it utilizes the braking energy in order to increase...

  2. Fuel Cells in the Waste-to-Energy Chain Distributed Generation Through Non-Conventional Fuels and Fuel Cells

    CERN Document Server

    McPhail, Stephen J; Moreno, Angelo

    2012-01-01

    As the availability of fossils fuels becomes more limited, the negative impact of their consumption becomes an increasingly relevant factor in our choices with regards to primary energy sources. The exponentially increasing demand for energy is reflected in the mass generation of by-products and waste flows which characterize current society’s development and use of fossil sources. The potential for recoverable material and energy in these ever-increasing refuse flows is huge, even after the separation of hazardous constituent elements, allowing safe and sustainable further exploitation of an otherwise 'wasted' resource.  Fuel Cells in the Waste-to-Energy Chain explores the concept of waste-to-energy through a 5 step process which reflects the stages during the transformation of  refuse flows to a valuable commodity such as clean energy. By providing selected, integrated alternatives to the current centralized, wasteful, fossil-fuel based infrastructure, Fuel Cells in the Waste-to-Energy Chain explores ho...

  3. 'When you use the term 'long term', how long is that term'. Risk, Exclusion, and the Politics of Knowledge Production in Canadian Nuclear Fuel Waste Management Policy Making

    International Nuclear Information System (INIS)

    Risk operates within Canadian Nuclear Fuel Waste (NFW) management policy making as a heuristic for knowledge production about its effects which reconciles the knowledge of the nuclear industry with the outcomes of the NFW management process. In so doing it marginalizes the present and historical experiences of Aboriginal peoples with the nuclear industry, and removes from view the ways in which they have been implicated in the geography and political economy of the nuclear industry. Risk is a discursive form that protects a particular group's claims about the effects of NFW by providing it a universalizing epistemological structure with which to obscure its connection to context. Further risk discourse provides the nuclear industry with a conceptual vocabulary that deliberately casts all competing knowledge as perceptions, values, or as an object of inquiry. The arguments of Aboriginal peoples about the residual effects of radiation in their lands which hosted nuclear activities, such as uranium mining and disposal, have no representation in how the discourse of risk defines and represents knowledge, and thus no purchase in the policy debate. As a result the challenge they present to the nuclear industry's claims are contained. The arrangements which permit the unloading of the negative effects of nuclear power generation onto Aboriginal peoples are thus reproduced (both materially and conceptually), but not shown, by the policy making process and likely, its outcome. In order to raise critical questions about the democratic abilities of risk, this paper has examined the role of 'risk' in Canadian NFW policy making. I have shown how when the politics of knowledge production within the philosophy of risk is analyzed, and the use and role of the notion of risk are interrogated, difficult questions are posed for the democratic potential of risk. I have suggested, through an analysis of the NWMO's representations of Aboriginal content in their process, that in this

  4. PEM fuel cell bipolar plate material requirements for transportation applications

    Energy Technology Data Exchange (ETDEWEB)

    Borup, R.L.; Stroh, K.R.; Vanderborgh, N.E. [Los Alamos National Lab., NM (United States)] [and others

    1996-04-01

    Cost effective bipolar plates are currently under development to help make proton exchange membrane (PEM) fuel cells commercially viable. Bipolar plates separate individual cells of the fuel cell stack, and thus must supply strength, be electrically conductive, provide for thermal control of the fuel stack, be a non-porous materials separating hydrogen and oxygen feed streams, be corrosion resistant, provide gas distribution for the feed streams and meet fuel stack cost targets. Candidate materials include conductive polymers and metal plates with corrosion resistant coatings. Possible metals include aluminium, titanium, iron/stainless steel and nickel.

  5. Process modeling of fuel cell vehicle power system

    Institute of Scientific and Technical Information of China (English)

    CHEN LiMing; LIN ZhaoJia; MA ZiFeng

    2009-01-01

    Constructed here is a mathematic model of PEM Fuel Cell Vehicle Power System which is composed of fuel supply model, fuel cell stack model and water-heat management model. The model was developed by Matiab/Simulink to evaluate how the major operating variables affect the output performances. Itshows that the constructed model can represent characteristics of the power system closely by comparing modeling results with experimental data, and it can be used in the study and design of fuel cell vehicle power system.

  6. WORKING PARK-FUEL CELL COMBINED HEAT AND POWER SYSTEM

    Energy Technology Data Exchange (ETDEWEB)

    Allan Jones

    2003-09-01

    This report covers the aims and objectives of the project which was to design, install and operate a fuel cell combined heat and power (CHP) system in Woking Park, the first fuel cell CHP system in the United Kingdom. The report also covers the benefits that were expected to accrue from the work in an understanding of the full technology procurement process (including planning, design, installation, operation and maintenance), the economic and environmental performance in comparison with both conventional UK fuel supply and conventional CHP and the commercial viability of fuel cell CHP energy supply in the new deregulated energy markets.

  7. Advanced membrane electrode assemblies for fuel cells

    Science.gov (United States)

    Kim, Yu Seung; Pivovar, Bryan S

    2014-02-25

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  8. Electrocatalysts for direct alcohol fuel cells

    Directory of Open Access Journals (Sweden)

    V. Celorrio

    2013-01-01

    Full Text Available The properties of CNC as well as their surface chemistry can be tuned by an adequate choice of synthesis conditions, favouring the formation of surface oxygen groups. Platinum-based catalysts have been supported on CNCs through different synthesis methods and their catalytic activity has been proven. These results prove that CNCs are promising candidates as alternative to replace Vulcan in order to improve the performance of the direct alcohol fuel cells. In addition, it can be affirmed that the reactivity of Au-Pd core-shell nanostructures toward CO and HCOOH electro-oxidation is not only determined by the composition and structure of Pd overlayer but also by interaction with the support.

  9. Microbial Fuel Cells and Microbial Electrolyzers

    Energy Technology Data Exchange (ETDEWEB)

    Borole, Abhijeet P [ORNL

    2015-01-01

    Microbial Fuel Cells and microbial electrolyzers represent an upcoming technology for production of electricity and hydrogen using a hybrid electrocatalytic-biocatalytic approach. The combined catalytic efficiency of these processes has potential to make this technology highly efficient among the various renewable energy production alternatives. This field has attracted electrochemists, biologists and many other disciplines due to its potential to contribute to the energy, water and environment sectors. A brief introduction to the technology is provided followed by current research needs from a bioelectrochemical perspective. Insights into the operation and limitations of these systems achieved via cyclic voltammetry and impedance spectroscopy are discussed along with the power management needs to develop the application aspects. Besides energy production, other potential applications in bioenergy, bioelectronics, chemical production and remediation are also highlighted.

  10. Platinum-ruthenium-palladium fuel cell electrocatalyst

    Science.gov (United States)

    Gorer, Alexander

    2006-02-07

    A catalyst suitable for use in a fuel cell, especially as an anode catalyst, that contains platinum at a concentration that is between about 20 and about 60 atomic percent, ruthenium at a concentration that is between about 20 and about 60 atomic percent, palladium at a concentration that is between about 5 and about 45 atomic percent, and having an atomic ratio of platinum to ruthenium that is between about 0.7 and about 1.2. Alternatively, the catalyst may contain platinum at a concentration that is between about 25 and about 50 atomic percent, ruthenium at a concentration that is between about 25 and about 55 atomic percent, palladium at a concentration that is between about 5 and about 45 atomic percent, and having a difference between the concentrations of ruthenium and platinum that is no greater than about 20 atomic percent.

  11. Biosensoric potential of microbial fuel cells.

    Science.gov (United States)

    Schneider, György; Kovács, Tamás; Rákhely, Gábor; Czeller, Miklós

    2016-08-01

    Recent progress in microbial fuel cell (MFC) technology has highlighted the potential of these devices to be used as biosensors. The advantages of MFC-based biosensors are that they are phenotypic and can function in either assay- or flow-through formats. These features make them appropriate for contiguous on-line monitoring in laboratories and for in-field applications. The selectivity of an MFC biosensor depends on the applied microorganisms in the anodic compartment where electron transfer (ET) between the artificial surface (anode) and bacterium occurs. This process strongly determines the internal resistance of the sensoric system and thus influences signal outcome and response time. Despite their beneficial characteristics, the number of MFC-based biosensoric applications has been limited until now. The aim of this mini-review is to turn attention to the biosensoric potential of MFCs by summarizing ET mechanisms on which recently established and future sensoric devices are based. PMID:27401925

  12. Microbial fuel cells for biosensor applications.

    Science.gov (United States)

    Yang, Huijia; Zhou, Minghua; Liu, Mengmeng; Yang, Weilu; Gu, Tingyue

    2015-12-01

    Microbial fuel cells (MFCs) face major hurdles for real-world applications as power generators with the exception of powering small sensor devices. Despite tremendous improvements made in the last two decades, MFCs are still too expensive to build and operate and their power output is still too small. In view of this, in recently years, intensive researches have been carried out to expand the applications into other areas such as acid and alkali production, bioremediation of aquatic sediments, desalination and biosensors. Unlike power applications, MFC sensors have the immediate prospect to be practical. This review covers the latest developments in various proposed biosensor applications using MFCs including monitoring microbial activity, testing biochemical oxygen demand, detection of toxicants and detection of microbial biofilms that cause biocorrosion.

  13. Direct dimethyl ether high temperature polymer electrolyte membrane fuel cells

    DEFF Research Database (Denmark)

    Vassiliev, Anton; Jensen, Jens Oluf; Li, Qingfeng;

    A high temperature polybenzimidazole (PBI) polymer fuel cell was fed with dimethyl ether (DME) and water vapour mixture on the anode at ambient pressure with air as oxidant. A peak power density of 79 mW/cm2 was achieved at 200°C. A conventional polymer based direct DME fuel cell is liquid fed......V higher than that of methanol, indicating less fuel crossover....

  14. DOE/FORD fuel cell contract for automotive application

    Energy Technology Data Exchange (ETDEWEB)

    Djong-Gie Oei

    1995-08-01

    The objectives of the contract are twofold. The first objective is to assess the feasibility of using a direct hydrogen fueled PEM fuel cell engine to power a midsize passenger car through the various drive cycles and test such a propulsion system on a test bed. The second objective is to study the supply infrastructure and safety aspects of hydrogen for future practical implementation of PEM fuel cells.

  15. High Temperature PEM Fuel Cells - Degradation and Durability

    OpenAIRE

    Araya, Samuel Simon

    2012-01-01

    A harmonious mix of renewable and alternative energy sources, including fuel cells is necessary to mitigate problems associated with the current fossil fuel based energy system, like air pollution, Greenhouse Gas (GHG) emissions, and economic dependence on oil, and therefore on unstable areas of the globe. Fuel cells can harness the excess energy from other renewable sources, such as the big players in the renewable energy market, Photovoltaic (PV) panels and wind turbines, which inherently s...

  16. Studies on PEM Fuel Cell Noble Metal Catalyst Dissolution

    DEFF Research Database (Denmark)

    Ma, Shuang; Skou, Eivind Morten

    Incredibly vast advance has been achieved in fuel cell technology regarding to catalyst efficiency, improvement of electrolyte conductivity and optimization of cell system. With breathtakingly accelerating progress, Proton Exchange Membrane Fuel Cells (PEMFC) is the most promising and most widely....... Membrane Electrode Assembly (MEA) is commonly considered as the heart of cell system [2]. Degradation of the noble metal catalysts in MEAs especially Three-Phase-Boundary (TPB) is a key factor directly influencing fuel cell durability. In this work, electrochemical degradation of Pt and Pt/Ru alloy were...

  17. High Temperature PEM Fuel Cells and Organic Fuels

    DEFF Research Database (Denmark)

    Vassiliev, Anton

    Modern way of life demands enormous amounts of energy, which so far has been mainly produced by combustion of various types of fossil fuel. Increased amounts of atmospheric CO2 and global warming leading to severe climate changes are the consequence. There is a need to make the energy production...... sustainable and break the dependency on fossil fuels. Hydrogen economy provides such a solution, where hydrogen produced by renewables, such as wind and solar power, becomes the energy carrier. The storage, handling and transportation of hydrogen are the main obstacles on the route to a sustainable future...

  18. Less-expensive & Environment-friendly Fuel Cells

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    @@ The research and develop ment of electrochemical energy conversion and storage devices, including primary and secondary batteries, supercapacitors, fuel cells and dye-sensitized solar cells (DSSC), are of significance for easing the energy crisis and raising living standards.

  19. Fuel Cell Electric Vehicle Evaluation; NREL (National Renewable Energy Laboratory)

    Energy Technology Data Exchange (ETDEWEB)

    Kurtz, Jennifer; Sprik, Sam; Ainscough, Chris; Saur, Genevieve

    2015-06-10

    This presentation provides a summary of NREL's FY15 fuel cell electric vehicle evaluation project activities and accomplishments. It was presented at the U.S. Department of Energy Hydrogen and Fuel Cells Program 2015 Annual Merit Review and Peer Evaluation Meeting on June 10, 2015, in Arlington, Virginia.

  20. Matrix member for containing fuel cell acid electrolyte

    International Nuclear Information System (INIS)

    A matrix member for carrying the acid electrolyte of a fuel cell comprised of a first layer containing a carbon material and a second layer containing a silicon carbide material. A further matrix member is disclosed wherein the mean pore size of the member is substantially equal to or less than that mean pore size of at least one of the fuel cell electrodes

  1. New matrix organisation to make fuel cells a reality

    DEFF Research Database (Denmark)

    Ryde, Marianne Vang

    2006-01-01

    A new matrix organisation provides the framework for a clearly defi ned project: creating a research foundation for the manufacture of effi cient and inexpensive fuel cells.......A new matrix organisation provides the framework for a clearly defi ned project: creating a research foundation for the manufacture of effi cient and inexpensive fuel cells....

  2. 2015 Annual Progress Report: DOE Hydrogen and Fuel Cells Program

    Energy Technology Data Exchange (ETDEWEB)

    None

    2015-12-23

    The 2015 Annual Progress Report summarizes fiscal year 2015 activities and accomplishments by projects funded by the DOE Hydrogen and Fuel Cells Program. It covers the program areas of hydrogen production; hydrogen delivery; hydrogen storage; fuel cells; manufacturing R&D; technology validation; safety, codes and standards; systems analysis; and market transformation.

  3. Platinum and palladium alloys suitable as fuel cell electrodes

    DEFF Research Database (Denmark)

    2014-01-01

    The present invention concerns electrode catalysts used in fuel cells, such as proton exchange membrane (PEM) fuel cells. The invention is related to the reduction of the noble metal content and the improvement of the catalytic5 efficiency by low level substitution of the noble metal to provide n...

  4. Graphene-supported platinum catalysts for fuel cells

    DEFF Research Database (Denmark)

    Seselj, Nedjeljko; Engelbrekt, Christian; Zhang, Jingdong

    2015-01-01

    Increasing concerns with non-renewable energy sources drive research and development of sustainable energy technology. Fuel cells have become a central part in solving challenges associated with energy conversion. This review summarizes recent development of catalysts used for fuel cells over the...

  5. Air intake and exhaust systems in fuel cell engines

    Energy Technology Data Exchange (ETDEWEB)

    Fuesser, R.; Weber, O. [Mann and Hummel (Germany)

    1999-07-01

    This paper describes the design and development of the air intake and exhaust system of a fuel cell powered road vehicle. In this instance the automotive supplier designed both the air intake and the exhaust system. The fuel cell engine gives a cold combustion effect making it possible to manufacture the exhaust from plastic materials. (UK)

  6. Connecticut Transit (CTTRANSIT) Fuel Cell Transit Bus: Preliminary Evaluation Results

    Energy Technology Data Exchange (ETDEWEB)

    Chandler, K.; Eudy, L.

    2008-10-01

    This report provides preliminary results from a National Renewable Energy Laboratory evaluation of a protoptye fuel cell transit bus operating at Connecticut Transit in Hartford. Included are descriptions of the planned fuel cell bus demonstration and equipment; early results and agency experience are also provided.

  7. Method of operating a direct dme fuel cell system

    DEFF Research Database (Denmark)

    2011-01-01

    The present invention relates to a method of operating a fuel cell system comprising one or more fuel cells with a proton exchange membrane, wherein the membrane is composed of a polymeric material comprising acid-doped polybenzimidazole (PBI). The method comprises adjusting the operating...

  8. Modeling Of Proton Exchange Membrane Fuel Cell Systems

    DEFF Research Database (Denmark)

    Nielsen, Mads Pagh

    The objective of this doctoral thesis was to develop reliable steady-state and transient component models suitable to asses-, develop- and optimize proton exchange membrane (PEM) fuel cell systems. Several components in PEM fuel cell systems were characterized and modeled. The developed component...

  9. On direct and indirect methanol fuel cells for transportation applications

    Energy Technology Data Exchange (ETDEWEB)

    Gottesfield, S.

    1996-04-01

    Research on direct oxidation methanol fuel cells (DMFCs) and polymer electrolyte fuel cells (PEFCs) is discussed. Systems considered for transportation applications are addressed. The use of platinum/ruthenium anode electrocatalysts and platinum cathode electrocatalysts in polymer electrolyte DMFCs has resulted in significant performance enhancements.

  10. Center for Intelligent Fuel Cell Materials Design

    Energy Technology Data Exchange (ETDEWEB)

    Santurri, P.R., (Chemsultants International); Hartmann-Thompson, C.; Keinath, S.E. (Michigan Molecular Inst.)

    2008-08-26

    The goal of this work was to develop a composite proton exchange membrane utilizing 1) readily available, low cost materials 2) readily modified and 3) easily processed to meet the chemical, mechanical and electrical requirements of high temperature PEM fuel cells. One of the primary goals was to produce a conducting polymer that met the criteria for strength, binding capability for additives, chemical stability, dimensional stability and good conductivity. In addition compatible, specialty nanoparticles were synthesized to provide water management and enhanced conductivity. The combination of these components in a multilayered, composite PEM has demonstrated improved conductivity at high temperatures and low humidity over commercially available polymers. The research reported in this final document has greatly increased the knowledge base related to post sulfonation of chemically and mechanically stable engineered polymers (Radel). Both electrical and strength factors for the degree of post sulfonation far exceed previous data, indicating the potential use of these materials in suitable proton exchange membrane architectures for the development of fuel cells. In addition compatible, hydrophilic, conductive nano-structures have been synthesized and incorporated into unique proton exchange membrane architectures. The use of post sulfonation for the engineered polymer and nano-particle provide cost effective techniques to produce the required components of a proton exchange membrane. The development of a multilayer proton exchange membrane as described in our work has produced a highly stable membrane at 170°C with conductivities exceeding commercially available proton exchange membranes at high temperatures and low humidity. The components and architecture of the proton exchange membrane discussed will provide low cost components for the portable market and potentially the transportation market. The development of unique components and membrane architecture

  11. Low emission fuel cell ship. Environmental account of fuel cell powered ships

    International Nuclear Information System (INIS)

    Shipping is the dominant mode of global transport, accounting for total global anthropogenic NOx and SOx emissions of 10-14% and 4-6% respectively. Future environmental requirements signalled for shipping may exceed the possibilities within current conventional technology. The work presented document the environmental benefits of using fuel cells compared to diesel engines. The work describes the general principles for modelling emissions to air for ships. The model was calibrated by measurements onboard an offshore supply vessel and a car carrier. For the offshore vessel, the FC model includes 100% of onboard power delivered by FC's. For the car carrier, the FC replaces the auxiliary engines. FC type modelled was a high temperature FC running on natural gas. The work quantifies yearly reduction in atmospheric emissions of CO2, NOx, SOx and PM. Our results show that the installation of fuel cells in ships will improve the environmental performance significantly (e.g. global warming and acidification). (author)

  12. Final Progress Report, Renewable and Logistics Fuels for Fuel Cells at the Colorado School of Mines

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, Neal P. [Colorado School of Mines, Golden, CO (United States)

    2012-08-06

    The objective of this program is to advance the current state of technology of solid-oxide fuel cells (SOFCs) to improve performance when operating on renewable and logistics hydrocarbon fuel streams. Outcomes will include: 1.) new SOFC materials and architectures that address the technical challenges associated with carbon-deposit formation and sulfur poisoning; 2.) new integration strategies for combining fuel reformers with SOFCs; 3.) advanced modeling tools that bridge the scales of fundamental charge-transfer chemistry to system operation and control; and 4.) outreach through creation of the Distinguished Lecturer Series to promote nationwide collaboration with fuel-cell researchers and scientists.

  13. Modeling, analysis and control of fuel cell hybrid power systems

    Science.gov (United States)

    Suh, Kyung Won

    Transient performance is a key characteristic of fuel cells, that is sometimes more critical than efficiency, due to the importance of accepting unpredictable electric loads. To fulfill the transient requirement in vehicle propulsion and portable fuel cell applications, a fuel cell stack is typically coupled with a battery through a DC/DC converter to form a hybrid power system. Although many power management strategies already exist, they all rely on low level controllers that realize the power split. In this dissertation we design controllers that realize various power split strategies by directly manipulating physical actuators (low level commands). We maintain the causality of the electric dynamics (voltage and current) and investigate how the electric architecture affects the hybridization level and the power management. We first establish the performance limitations associated with a stand-alone and power-autonomous fuel cell system that is not supplemented by an additional energy storage and powers all its auxiliary components by itself. Specifically, we examine the transient performance in fuel cell power delivery as it is limited by the air supplied by a compressor driven by the fuel cell itself. The performance limitations arise from the intrinsic coupling in the fluid and electrical domain between the compressor and the fuel cell stack. Feedforward and feedback control strategies are used to demonstrate these limitations analytically and with simulations. Experimental tests on a small commercial fuel cell auxiliary power unit (APU) confirm the dynamics and the identified limitations. The dynamics associated with the integration of a fuel cell system and a DC/DC converter is then investigated. Decentralized and fully centralized (using linear quadratic techniques) controllers are designed to regulate the power system voltage and to prevent fuel cell oxygen starvation. Regulating these two performance variables is a difficult task and requires a compromise

  14. A vapor feed methanol microfluidic fuel cell with high fuel and energy efficiency

    International Nuclear Information System (INIS)

    Highlights: • A microfluidic fuel cell with a vapor feed anode is investigated. • Its advantages include simpler design, direct usage of methanol and better performance. • The prototype achieves a peak power density of 55.4 mW cm−2 under room temperature. • The energy efficiency of 9.4% is much higher than its liquid feed counterpart. - Abstract: In this paper, a prototype of methanol microfluidic fuel cell with vapor feed anode configuration is proposed to improve the fuel and energy efficiency of the conventional liquid feed methanol microfluidic fuel cells. Peak power density of 55.4 mW cm−2 can be achieved with this prototype under room temperature, which is 30% higher than its conventional liquid feed counterpart. Moreover, an energy efficiency of 9.4% is achieved, which is 27.5 times higher than its liquid feed counterpart. This superiority on both cell performance and energy efficiency is directly benefitted from its vapor feed anode configuration, which alleviates the fuel crossover, eliminates the fuel depletion boundary layer, and avoids the bulk anolyte wastage. The tradeoff between cell performance and fuel utilization for conventional liquid feed microfluidic fuel cells is also evaded

  15. Fuel processor and method for generating hydrogen for fuel cells

    Science.gov (United States)

    Ahmed, Shabbir; Lee, Sheldon H. D.; Carter, John David; Krumpelt, Michael; Myers, Deborah J.

    2009-07-21

    A method of producing a H.sub.2 rich gas stream includes supplying an O.sub.2 rich gas, steam, and fuel to an inner reforming zone of a fuel processor that includes a partial oxidation catalyst and a steam reforming catalyst or a combined partial oxidation and stream reforming catalyst. The method also includes contacting the O.sub.2 rich gas, steam, and fuel with the partial oxidation catalyst and the steam reforming catalyst or the combined partial oxidation and stream reforming catalyst in the inner reforming zone to generate a hot reformate stream. The method still further includes cooling the hot reformate stream in a cooling zone to produce a cooled reformate stream. Additionally, the method includes removing sulfur-containing compounds from the cooled reformate stream by contacting the cooled reformate stream with a sulfur removal agent. The method still further includes contacting the cooled reformate stream with a catalyst that converts water and carbon monoxide to carbon dioxide and H.sub.2 in a water-gas-shift zone to produce a final reformate stream in the fuel processor.

  16. Monolithic fuel cell based power source for burst power generation

    Science.gov (United States)

    Fee, D. C.; Blackburn, P. E.; Busch, D. E.; Dees, D. W.; Dusek, J.; Easler, T. E.; Ellingson, W. A.; Flandermeyer, B. K.; Fousek, R. J.; Heiberger, J. J.

    A unique fuel cell coupled with a low power nuclear reactor presents an attractive approach for SDI burst power requirements. The monolithic fuel cell looks attractive for space applications and represents a quantum jump in fuel cell technology. Such a breakthrough in design is the enabling technology for lightweight, low volume power sources for space based pulse power systems. The monolith is unique among fuel cells in being an all solid state device. The capability for miniaturization, inherent in solid state devices, gives the low volume required for space missions. In addition, the solid oxide fuel cell technology employed in the monolith has high temperature reject heat and can be operated in either closed or open cycles. Both these features are attractive for integration into a burst power system.

  17. The Stirred Tank Reactor Polymer Electrolyte Membrane Fuel Cell

    CERN Document Server

    Benziger, J; Karnas, E; Moxley, J; Teuscher, C; Kevrekidis, Yu G; Benziger, Jay

    2003-01-01

    The design and operation of a differential Polymer Electrolyte Membrane (PEM) fuel cell is described. The fuel cell design is based on coupled Stirred Tank Reactors (STR); the gas phase in each reactor compartment was well mixed. The characteristic times for reactant flow, gas phase diffusion and reaction were chosen so that the gas compositions at both the anode and cathode are uniform. The STR PEM fuel cell is one-dimensional; the only spatial gradients are transverse to the membrane. The STR PEM fuel cell was employed to examine fuel cell start- up, and its dynamic responses to changes in load, temperature and reactant flow rates. Multiple time scales in systems response are found to correspond to water absorption by the membrane, water transport through the membrane and stress-related mechanical changes of the membrane.

  18. Platinum and palladium alloys suitable as fuel cell electrodes

    DEFF Research Database (Denmark)

    2014-01-01

    The present invention concerns electrode catalysts used in fuel cells, such as proton exchange membrane (PEM) fuel cells. The invention is related to the reduction of the noble metal content and the improvement of the catalytic efficiency by low level substitution of the noble metal to provide ne...... and innovative catalyst compositions in fuel cell electrodes. The novel electrode catalysts of the invention comprise a noble metal selected from Pt and Pd alloyed with an alkaline earth metal.......The present invention concerns electrode catalysts used in fuel cells, such as proton exchange membrane (PEM) fuel cells. The invention is related to the reduction of the noble metal content and the improvement of the catalytic efficiency by low level substitution of the noble metal to provide new...

  19. Advances in Materials and System Technology for Portable Fuel Cells

    Science.gov (United States)

    Narayanan, Sekharipuram R.

    2007-01-01

    This viewgraph presentation describes the materials and systems engineering used for portable fuel cells. The contents include: 1) Portable Power; 2) Technology Solution; 3) Portable Hydrogen Systems; 4) Direct Methanol Fuel Cell; 5) Direct Methanol Fuel Cell System Concept; 6) Overview of DMFC R&D at JPL; 7) 300-Watt Portable Fuel Cell for Army Applications; 8) DMFC units from Smart Fuel Cell Inc, Germany; 9) DMFC Status and Prospects; 10) Challenges; 11) Rapid Screening of Well-Controlled Catalyst Compositions; 12) Screening of Ni-Zr-Pt-Ru alloys; 13) Issues with New Membranes; 14) Membranes With Reduced Methanol Crossover; 15) Stacks; 16) Hybrid DMFC System; 17) Small Compact Systems; 18) Durability; and 19) Stack and System Parameters for Various Applications.

  20. Proceedings -- US Russian workshop on fuel cell technologies

    Energy Technology Data Exchange (ETDEWEB)

    Baker, B.; Sylwester, A. [comps.

    1996-04-01

    On September 26--28, 1995, Sandia National Laboratories sponsored the first Joint US/Russian Workshop on Fuel Cell Technology at the Marriott Hotel in Albuquerque, New Mexico. This workshop brought together the US and Russian fuel cell communities as represented by users, producers, R and D establishments and government agencies. Customer needs and potential markets in both countries were discussed to establish a customer focus for the workshop. Parallel technical sessions defined research needs and opportunities for collaboration to advance fuel cell technology. A desired outcome of the workshop was the formation of a Russian/American Fuel Cell Consortium to advance fuel cell technology for application in emerging markets in both countries. This consortium is envisioned to involve industry and national labs in both countries. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

  1. Fuel cell commercialization - beyond the 'Notice of Market Opportunity for Fuel Cells' (NOMO)

    International Nuclear Information System (INIS)

    The Notice of Market Opportunity for Fuel Cells (NOMO) was released in Oct. 1988 by the American Public Power Association. Its goal was to identify a manufacturer for commercializing a multi-megawatt fuel cell power plant with attractive cost and performance characteristics, supported by a realistic, yet aggressive commercialization plan, leading to mid-1990s application. Energy Research Corporation's program to commercialize its 2-MW internal-reforming carbonate fuel cell was selected. The City of Santa Clara, CA; Electric Power Research Institute; Los Angeles Department of Water and Power; Southern California Gas Company; Southern California Edison; National Rural Electric Cooperative Association; and Pacific Gas and Electric, have formed the Santa Clara Demonstration Group to build the first 2-MW power plant. The preliminary design for this demonstration is nearly complete. Integrated testing of a 20-kW stack with the complete balance-of-plant, has been successfully accomplished by Pacific Gas and Electric at its test facility in San Ramon, CA. (orig./MM)

  2. Design and performance of a prototype fuel cell powered vehicle

    Energy Technology Data Exchange (ETDEWEB)

    Lehman, P.A.; Chamberlin, C.E. [Humboldt State Univ., Arcata, CA (United States)

    1996-12-31

    The Schatz Energy Research Center (SERC) is now engaged in the Palm Desert Renewable Hydrogen Transportation System Project. The Project involves a consortium which includes the City of Palm Desert, SERC, the U.S. Department of Energy, the South Coast Air Quality Management District, and Sandia and Lawrence Livermore National Laboratories. Its goal to develop a clean and sustainable transportation system for a community will be accomplished by producing a fleet of fuel cell vehicles, installing a refueling infrastructure utilizing hydrogen generated from solar and wind power, and developing and staffing a fuel cell service and diagnostic center. We will describe details of the project and performance goals for the fuel cell vehicles and associated peripheral systems. In the past year during the first stage in the project, SERC has designed and built a prototype fuel cell powered personal utility vehicle (PUV). These steps included: (1) Designing, building, and testing a 4.0 kW proton exchange membrane (PEM) fuel cell as a power plant for the PUV. (2) Designing, building and testing peripherals including the air delivery, fuel storage/delivery, refueling, water circulation, cooling, and electrical systems. (3) Devising a control algorithm for the fuel cell power plant in the PUV. (4) Designing and building a test bench in which running conditions in the PUV could be simulated and the fuel cell and its peripheral systems tested. (5) Installing an onboard computer and associated electronics into the PUV (6) Assembling and road testing the PUV.

  3. The US Army Foreign Comparative Test fuel cell program

    Science.gov (United States)

    Bostic, Elizabeth; Sifer, Nicholas; Bolton, Christopher; Ritter, Uli; Dubois, Terry

    The US Army RDECOM initiated a Foreign Comparative Test (FCT) Program to acquire lightweight, high-energy dense fuel cell systems from across the globe for evaluation as portable power sources in military applications. Five foreign companies, including NovArs, Smart Fuel Cell, Intelligent Energy, Ballard Power Systems, and Hydrogenics, Inc., were awarded competitive contracts under the RDECOM effort. This paper will report on the status of the program as well as the experimental results obtained from one of the units. The US Army has interests in evaluating and deploying a variety of fuel cell systems, where these systems show added value when compared to current power sources in use. For low-power applications, fuel cells utilizing high-energy dense fuels offer significant weight savings over current battery technologies. This helps reduce the load a solider must carry for longer missions. For high-power applications, the low operating signatures (acoustic and thermal) of fuel cell systems make them ideal power generators in stealth operations. Recent testing has been completed on the Smart Fuel Cell A25 system that was procured through the FCT program. The "A-25" is a direct methanol fuel cell hybrid and was evaluated as a potential candidate for soldier and sensor power applications.

  4. Exegoeconomic Analysis On A Proton Electrolyte Membrane Fuel Cell

    International Nuclear Information System (INIS)

    The objective of this study is to perform an exergy and economic analysis on proton electrolyte membrane fuel cell power system (PEMFC) known as exegoeconomic. A 5 kW PEMFC was taken as case study. The fuel cell includes the hydrogen processing system and a fuel cell stack. The hydrogen processing system consisted of an auto-thermal reactor (ATR), a water gas shift reactor (WGS), tubular ceramic membrane module (TCR) and a pressure swing adsorber (PSA). The fuel cell stack was the main power generator. It was obseved that TCM and PSA have low energy efficiency of 0.29 % and 0.09 % respectively. Energy efficiency for the auto-thermal reactor and fuel cell stack were higher at 22.44 % and 31.97 % respectively and both values are comparable with other studies. The exergoeconomics for the 5kW fuel cell system was determined as RM4756.62 per GJ. From the analysis, it is also found that the fuel cell cost can more competitive, if the cost of operation, maintenance and fuel can be reduced. (author)

  5. The California fuel cell partnership: an avenue to clean air

    Science.gov (United States)

    Lloyd, Alan C.

    The California Fuel Cell Partnership presently consists of eight private companies, two state agencies and a federal government representative that will attempt to demonstrate the feasibility of fuel cell cars and buses. California has attempted to advance the commercialization of zero-emission vehicles for much of the past decade to help the state reduce its high levels of air pollution. A special advisory panel convened by the California Air Resources Board concluded last year that fuel cell technology could meet the key requirements for automobiles. The successful commercialization of fuel cell vehicles would help to reduce the levels of ozone, fine particles and toxic air contaminants that pose health risks to California's population. This technology can also help to reduce carbon dioxide emissions. California regulations now encourage the development of zero and near-zero emission vehicle technologies, including fuel cells. The Fuel Cell Partnership will operate approximately 50 fuel cell cars and buses until the year 2003 in order to produce important information on the vehicles and fueling infrastructure needed to support them.

  6. Fuel cells for distributed generation in developing countries - an analysis

    Energy Technology Data Exchange (ETDEWEB)

    Bauen, A. [Imperial College, London (United Kingdom). Centre for Energy Policy and Technology; E4tech (UK) Ltd., London (United Kingdom); Hart, D. [Imperial College, London (United Kingdom). Centre for Energy Policy and Technology; Chase, A. [E4tech (UK) Ltd., London (United Kingdom)

    2003-07-01

    Fuel cells are still in development as power generation technologies. They are potentially efficient and low-emissions power generation technologies with a wide range of applications. Their deployment world wide and in developing countries in particular could result in mitigation of future greenhouse gas emissions and possibly other environmental and social benefits. The economics of the systems and their competitiveness with other power generation systems will be heavily dependent on local costs and infrastructure. Modelling, based energy demand projection and on fuel cell demand curves derived from expert interviews, suggests that worldwide, projected future cost reductions in fuel cells could result in fuel cell penetration of up to 50% of the world distributed generation market by 2020. This penetration, coupled with the use of a mix of low-carbon fuels, such as natural gas, would result in significant avoided emissions of CO{sub 2} over the same period. Also, a comparison of the levelised costs of generation for the Philippines and South Africa suggests that some fuel cell technologies could become competitive with centralised generation within the next decade. Assuming that fuel cell durability can be demonstrated, the potential for fuel cells to be introduced into distributed generation in certain developing countries appears high, from a technical, economic and environmental perspective. (author)

  7. Direct-hydrogen-fueled proton-exchange-membrane fuel cell system for transportation applications

    Energy Technology Data Exchange (ETDEWEB)

    Oei, D.; Adams, J.A.; Kinnelly, A.A. [and others

    1997-07-01

    In partial fulfillment of the U.S. Department of Energy Contract No. DE-ACO2-94CE50389, {open_quotes}Direct Hydrogen-Fueled Proton-Exchange-Membrane (PEM) Fuel Cell System for Transportation Applications{close_quotes}, this conceptual vehicle design report addresses the design and packaging of battery augmented fuel cell powertrain vehicles. This report supplements the {open_quotes}Conceptual Vehicle Design Report - Pure Fuel Cell Powertrain Vehicle{close_quotes} and includes a cost study of the fuel cell power system. The three classes of vehicles considered in this design and packaging exercise are the same vehicle classes that were studied in the previous report: the Aspire, representing the small vehicle class; the AIV (Aluminum Intensive Vehicle) Sable, representing the mid-size vehicle; and the E-150 Econoline, representing the van-size class. A preliminary PEM fuel cell power system manufacturing cost study is also presented. As in the case of the previous report concerning the {open_quotes}Pure Fuel Cell Powertrain Vehicle{close_quotes}, the same assumptions are made for the fuel cell power system. These assumptions are fuel cell system power densities of 0.33 kW/ka and 0.33 kW/l, platinum catalyst loading of less than or equal to 0.25 mg/cm{sup 2} total, and hydrogen tanks containing compressed gaseous hydrogen under 340 atm (5000 psia) pressure. The batteries considered for power augmentation of the fuel cell vehicle are based on the Ford Hybrid Electric Vehicle (HEV) program. These are state-of-the-art high power lead acid batteries with power densities ranging from 0.8 kW/kg to 2 kW/kg. The results reported here show that battery augmentation provides the fuel cell vehicle with a power source to meet instant high power demand for acceleration and start-up. Based on the assumptions made in this report, the packaging of the battery augmented fuel cell vehicle appears to be as feasible as the packaging of the pure fuel cell powered vehicle.

  8. Novel Low Temperature Solid State Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Chonglin [Univ. of Texas, San Antonio, TX (United States); Nash, Patrick [Univ. of Texas, San Antonio, TX (United States); Liu, Jian [Univ. of Texas, San Antonio, TX (United States); Collins, Gregory [Univ. of Texas, San Antonio, TX (United States)

    2010-03-23

    We have successfully fabricated (PrBa)Co2O5+δ and (LaBa)Co2O5+δ epitaxial thin film on various single crystal substrates. Physical and electrochemical properties characterizations were carried out. Highly conductive oxygen-deficient double perovskite LnBaCo2O5+ thin films were grown on single crystal (001) SrTiO3 (STO), (001) MgO, (001) LaAlO3 and (110) NdGaO3} substrate by pulsed laser deposition. Microstructure studies from synchrotron X-ray diffraction and Transmission electron microscopy. High temperature transport properties was carried in different atmosphere (O2,Air, N2) up to ~900K. Resistance response of (LaBa)Co2O5+δ epitaxial thin film was characterized in oxygen, nitrogen and 4% hydrogen over a wide range of temperature from 400 C up to 800 C. To determine the electrode performance and oxygen exchange kinetics of PrBaCo2O5+δ, multi-layered thin film based half cell was deposited on LaAlO3(001) substrate. The temperature dependence of the resistance of this half cell structure was characterized by electrochemical impedance spectroscopy (EIS) within different temperature and gas environments. Anode supported fuel cells, with GCO:YSZ multilayer thin film as electrolyte and PBCO thin film as electrode, are fabricated on tape casted NiO/YSZ substrate. Full cell performance is characterized up to 800 C.

  9. Analysis of accelerated degradation of a HT-PEM fuel cell caused by cell reversal in fuel starvation condition

    DEFF Research Database (Denmark)

    Zhou, Fan; Andreasen, Søren Juhl; Kær, Søren Knudsen;

    2015-01-01

    This paper reports an accelerated degradation test of a high temperature PEM fuel cell under repeated H2 starvation condition. The H2 stoichiometry is cycled between 3.0 and 0.8 every 2 min during the test. The experimental results show that the polarity of the fuel cell is reversed under H2...

  10. Fuel Cell Buses in U.S. Transit Fleets: Current Status 2009

    Energy Technology Data Exchange (ETDEWEB)

    Eudy, L.; Chandler, K.; Gikakis, C.

    2009-10-01

    This report documents progress in meeting the technological challenges of fuel cell propulsion for transportation based on current fuel cell transit bus demonstrations and plans for more fuel cell transit buses and hydrogen infrastructure.

  11. National Fuel Cell Technology Evaluation Center (NFCTEC); (NREL) National Renewable Energy Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Kurtz, Jennifer; Sprik, Sam

    2014-03-11

    This presentation gives an overview of the National Fuel Cell Technology Evaluation Center (NFCTEC), describes how NFCTEC benefits the hydrogen and fuel cell community, and introduces a new fuel cell cost/price aggregation project.

  12. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Remick, R.; Wheeler, D.

    2010-09-01

    This report describes the technical and cost gap analysis performed to identify pathways for reducing the costs of molten carbonate fuel cell (MCFC) and phosphoric acid fuel cell (PAFC) stationary fuel cell power plants.

  13. Modelling and experimental investigation of the porous nickel anode in the molten carbonate fuel cell

    OpenAIRE

    Sparr, Mari

    2005-01-01

    The thesis is focussed on the performance of the fuel cell and the design of the cell for operation with natural gas and renewable fuels, e.g. biogas or gasified biomass. The performance is one of the important issues for the development and commercialisation of fuel cell stacks. In order to operate fuel cell on renewable fuels, without preceding reforming of the fuel, a high temperature fuel cell is needed, i.e. a solid oxide fuel cell (SOFC) or a molten carbonate fuel cell (MCFC). At presen...

  14. FUEL CELL SEBAGAI PENGGANTI MOTOR BAKAR PADA KENDARAAN

    Directory of Open Access Journals (Sweden)

    Hendrata Suhada

    2001-01-01

    Full Text Available Cars powered by engine is one of transport vehicle used in developed countries, which caused ecological problem to the environment, the effect of this problem is faced nowadays especially in big cities. Since medio of 20th century many researches and developments have been done, to cope with that problem, to have less emission in the environment. One of the equipment to replace engines, have been developed since the last decade of 20th century, give a lot of advantages called fuel cell, which can produce energy by electric-chemically process. Due to the differences of fuel cell compare with conventional engine, vehicles using fuel cell has to be redesign, some components have to be changed radically, like the fuel system, drive train and control system. The result of researches and developments which have been done, promise a lot of advantages, which conventional engines can not give, therefore it is probable that fuel cell will replace conventional engine. Abstract in Bahasa Indonesia : Kendaraan bermotor yang merupakan alat transportasi yang sangat dibutuhkan oleh masyarakat di negara-negara modern, menimbulkan masalah besar terhadap lingkungan dan akibat polusinya sudah sangat terasa, terutama di kota-kota besar. Untuk menanggulangi masalah ini, maka sejak pertengahan abad 20 telah banyak dilakukan tindakan-tindakan yang bertujuan mengurangi atau melenyapkan pengaruh gas yang ditimbulkan oleh motor bakar. Sejak akhir abad 20 telah mulai dikembangkan alat untuk menggantikan motor bakar yang ternyata mempunyai beberapa keuntungan yang sangat menonjol, yaitu fuel cell yang dapat menghasilkan energi melalui proses elektro kimiawi. Berhubung fuel cell sangat berbeda dari motor bakar, maka kendaraan yang menggunakannya mengalami perubahan komponen yang cukup radikal diantaranya sistem bahan bakar, sistem penerus energi dan sistem kontrol. Dari hasil pengembangan dan penelitian yang telah dilakukan ternyata jenis fuel cell ini sangat menjanjikan

  15. Grove Medal Address - investing in the fuel cell business

    Science.gov (United States)

    Rasul, Firoz

    Successful commercialization of fuel cells will require significant investment. To attract this funding, the objective must be commercially driven and the financing will have to be viewed as an investment in the business of fuel cells rather than just the funding of technology development. With the recent advancements in fuel cells and demonstrations of fuel cell power systems in stationary and transport applications, an industry has begun to emerge and it is attracting the attention of institutional and corporate investors, in addition to the traditional government funding. Although, the strategic importance of fuel cells as a versatile, efficient and cleaner power source of the future as well as an `engine' for economic growth and job creation has now been understood by several governments, major corporations have just begun to recognize the enormous potential of the fuel cell for it to become as ubiquitous for electrical power as the microprocessor has become for computing power. Viewed as a business, fuel cells must meet the commercial requirements of price competitiveness, productivity enhancement, performance and reliability, in addition to environmental friendliness. As fuel cell-based products exhibit commercial advantages over conventional power sources, the potential for higher profits and superior returns will attract the magnitude of investment needed to finance the development of products for the varied applications, the establishment of high volume manufacturing capabilities, and the creation of appropriate fuel and service infrastructures for these new products based on a revolutionary technology. Today, the fuel cell industry is well-positioned to offer the investing public opportunities to reap substantial returns through their participation at this early stage of growth of the industry.

  16. Study on Fuel Cell Network System Considering Reduction in Fuel Cell Capacity Using Load Leveling and Heat Release Loss

    Science.gov (United States)

    Obara, Shin'ya; Kudo, Kazuhiko

    Reduction in fuel cell capacity linked to a fuel cell network system is considered. When the power demand of the whole network is small, some of the electric power generated by the fuel cell is supplied to a water electrolysis device, and hydrogen and oxygen gases are generated. Both gases are compressed with each compressor and they are stored in cylinders. When the electric demand of the whole network is large, both gases are supplied to the network, and fuel cells are operated by these hydrogen and oxygen gases. Furthermore, an optimization plan is made to minimize the quantity of heat release of the hot water piping that connects each building. Such an energy network is analyzed assuming connection of individual houses, a hospital, a hotel, a convenience store, an office building, and a factory. Consequently, compared with the conventional system, a reduction of 46% of fuel cell capacity is expected.

  17. MEMS-based thin-film fuel cells

    Science.gov (United States)

    Jankowksi, Alan F.; Morse, Jeffrey D.

    2003-10-28

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  18. Demonstration of Passive Fuel Cell Thermal Management Technology

    Science.gov (United States)

    Burke, Kenneth A.; Jakupca, Ian; Colozza, Anthony; Wynne, Robert; Miller, Michael; Meyer, Al; Smith, William

    2012-01-01

    The NASA Glenn Research Center is developing advanced passive thermal management technology to reduce the mass and improve the reliability of space fuel cell systems for the NASA Exploration program. The passive thermal management system relies on heat conduction within highly thermally conductive cooling plates to move the heat from the central portion of the cell stack out to the edges of the fuel cell stack. Using the passive approach eliminates the need for a coolant pump and other cooling loop components within the fuel cell system which reduces mass and improves overall system reliability. Previous development demonstrated the performance of suitable highly thermally conductive cooling plates and integrated heat exchanger technology to collect the heat from the cooling plates (Ref. 1). The next step in the development of this passive thermal approach was the demonstration of the control of the heat removal process and the demonstration of the passive thermal control technology in actual fuel cell stacks. Tests were run with a simulated fuel cell stack passive thermal management system outfitted with passive cooling plates, an integrated heat exchanger and two types of cooling flow control valves. The tests were run to demonstrate the controllability of the passive thermal control approach. Finally, successful demonstrations of passive thermal control technology were conducted with fuel cell stacks from two fuel cell stack vendors.

  19. Implementation of microbial fuel cell in harvesting energy using wastewater

    Science.gov (United States)

    Ramli, N. L.; Wahab, M. S. Abdul; Sharif, S. A. Md; Ramly, N. H.

    2016-02-01

    In this century, most of the companies use the electricity from the fossils fuels such as oil, gas and coal. This method will give negative impact to the environment and the fossils fuel will be run out. This project is to develop a microbial fuels cell that can produce electricity. There are several types of the microbial fuel cell, which are a single chamber, double chamber and continuous. In this paper, the double chamber microbial fuel cell was selected to investigate the effect of suspended sludge into the double chamber microbial fuels cell. The salt bridge will construct between both chambers of the double chamber microbial fuels cell. Carbon graphite rod is selected as an electrode at the cathode and anode to transfer the electron from the anode to the cathode. Electricity is generated from the anaerobic oxidation of organic matter by bacteria. At the end of this project, the microbial fuels cell was successful in generating electricity that can be used for a specific application.

  20. Speeding the transition: Designing a fuel-cell hypercar

    Energy Technology Data Exchange (ETDEWEB)

    Williams, B.D.; Moore, T.C.; Lovins, A.B. [Rocky Mountain Inst., Snowmass, CO (United States). Hypercar Center

    1997-12-31

    A rapid transformation now underway in automotive technology could accelerate the transition to transportation powered by fuel cells. Ultralight, advanced-composite, low-drag, hybrid-electric hypercars--using combustion engines--could be three- to fourfold more efficient and one or two orders of magnitude cleaner than today`s cars, yet equally safe, sporty, desirable, and (probably) affordable. Further, important manufacturing advantages--including low tooling and equipment costs, greater mechanical simplicity, autobody parts consolidation, shorter product cycles, and reduced assembly effort and space--permit a free-market commercialization strategy. This paper discusses a conceptual hypercar powered by a proton-exchange-membrane fuel cell (PEMFC). It outlines the implications of platform physics and component selection for the vehicle`s mass budget and performance. The high fuel-to-traction conversion efficiency of the hypercar platform could help automakers overcome the Achilles` heel of hydrogen-powered vehicles: onboard storage. Moreover, because hypercars would require significantly less tractive power, and even less fuel-cell power, they could adopt fuel cells earlier, before fuel cells` specific cost, mass, and volume have fully matured. In the meantime, commercialization in buildings can help prepare fuel cells for hypercars. The promising performance of hydrogen-fueled PEMFC hypercars suggests important opportunities in infrastructure development for direct-hydrogen vehicles.