WorldWideScience

Sample records for calorimetric dosemeters

  1. Review of international standards for dosemeters.

    Science.gov (United States)

    Behrens, R; Ambrosi, P

    2008-01-01

    International standards for radiation protection dosemeters are published by the International Electrotechnical Commission and the International Organization for Standardization. Several standards exist side by side, although they treat the same measuring task, and specify different requirements, so that dosemeters of different quality result. In this paper, the quality of dosemeters is compared by calculating the uncertainty of dose measurements for dosemeters, which just basely fulfil the respective standard. The results are related to general yardsticks on uncertainty laid down by international organisations. Furthermore, technical differences are standards and addressed and a method to make them conform is presented.

  2. Passive neutron dosemeter with activation detector

    Energy Technology Data Exchange (ETDEWEB)

    Valero L, C.; Banuelos F, A.; Guzman G, K. A.; Borja H, C. G.; Hernandez D, V. M.; Vega C, H. R., E-mail: fermineutron@yahoo.com [Universidad Autonoma de Zacatecas, Unidad Academica de Estudios Nucleares, Calle Cipres No. 10, Fracc. La Penuela, 98068 Zacatecas (Mexico)

    2011-10-15

    A passive neutron dosemeter with {sup 197}Au activation detector has been developed. The area dosemeter was made as a 20.5 {phi} x 20.5 cm{sup 2} polyethylene moderator, with a polyethylene pug where a {sup 197}Au foil can be located either parallel or perpendicular to moderator axis. Using Monte Carlo methods, with the MCNP5 code. With the fluence response and the fluence-to-equivalent dose conversion coefficients from ICRP-74, responses to H*(10) were also calculated, these were compared against responses of commercially available neutron area monitors and dosemeters. (Author)

  3. The relative merits of discriminating and non-discriminating dosemeters

    DEFF Research Database (Denmark)

    Marshal, T. O.; Christensen, Palle; Julius, H. W.;

    1986-01-01

    The need for discriminating and non-discriminating personal dosemeters in the field of radiological protection is examined. The ability of various types of dosemeter to meet these needs is also discussed. It is concluded that there is a need for discriminating dosemeters but in the majority of ca...

  4. Colour dosemeters for high level radiation dosimetry

    DEFF Research Database (Denmark)

    Schönbacher, H.; Coninckx, F.; Miller, A.;

    1990-01-01

    interpretation or a dose measurement with a simple instrument such as a portable reflecting densitometer in the range of 10(3) to 10(6) Gy. Two projects were investigated: (1) a thin plastic film with a self adhesive tape containing a radiochromic dye which induces a colour change when exposed to ionising...... radiation; and (2) a paint containing a base substance with a pigment. The paint dosemeter remained unaffected by irradiation up to 3 x 10(4) Gy while the film dosemeter showed a measurable colour change from 10(4) Gy to 5 x 10(5) Gy. Above 10(6) Gy the film dosemeter is destroyed by radiation. Samples...

  5. Comparison of main thermoluminescent properties of some TL dosemeters

    DEFF Research Database (Denmark)

    Prokic, M.; Bøtter-Jensen, L.

    1993-01-01

    Different types of TL dosemeters that are attractive for dosimetry practice were investigated and compared. The aim of this study was to evaluate the TL characteristics of different TL dosemeters using two basically different types of commercially available TL readers. The findings demonstrate...

  6. The increasing need for active dosemeters in the nuclear industry

    Energy Technology Data Exchange (ETDEWEB)

    Hirning, C.R. [Ontario Hydro, Whitby, ON (Canada). Health Physics Dept.

    1995-12-31

    As a legal and administrative dose limits come down, there is an increasing need in the nuclear industry for greater accuracy in dose measurement, for lower detection limits, and for more rapid reporting of doses, Active (i.e. electronic) dosemeters offer the possibility of substantial improvements in these areas. The advantages of electronic dosemeters are reviewed, some impediments to their more rapid adoption considered, some needs for research and development suggested, and the implications of a change from passive to active dosemeters looked at. A review of the present status of electronic dosemeter testing, standard-setting and system implementation is given. The next major era in the history of radiation dosimetry appears to be well under way. (Author).

  7. Response of Alanine Dosemeter to Heavy Ions

    Institute of Scientific and Technical Information of China (English)

    LiWenjian; SuXu; YangYingjie; YuanJianlei; DangBingrong; WangXiao; MaQiufeng; ZhouLibin; HaoJifang; MaoShuhong

    2003-01-01

    The amino acid L-α-alanine has been investigated for use as a radiation detector in low and high LET radiation fields[1]. The radiatioa detector is cheap and easy to handle. The radiation inducing free radicals are stable at normal laboratory conditions for doses below 104 Gy over a long period of time, which makes the detector useful for intercomparison and documentation purposes. The dosimetric features of alanine-based electron spin resonance (ESR) detectors in high energy electron beams used in radiotherapy were considered[2]. The 5 mm long alanine detectors were found to be the most suitable for carrying out in vivo dosimetry on patients undergoing electron beam radiotherapy. However, data concerning dosimetry of the alanine dosemeter to heavy charged particles are lacking, especially in China.

  8. Prediction analysis of dose equivalent responses of neutron dosemeters used at a MOX fuel facility.

    Science.gov (United States)

    Tsujimura, N; Yoshida, T; Takada, C

    2011-07-01

    To predict how accurately neutron dosemeters can measure the neutron dose equivalent (rate) in MOX fuel fabrication facility work environments, the dose equivalent responses of neutron dosemeters were calculated by the spectral folding method. The dosemeters selected included two types of personal dosemeter, namely a thermoluminescent albedo neutron dosemeter and an electronic neutron dosemeter, three moderator-based neutron survey meters, and one special instrument called an H(p)(10) monitor. The calculations revealed the energy dependences of the responses expected within the entire range of neutron spectral variations observed in neutron fields at workplaces.

  9. Potential clinical utility of a fibre optic-coupled dosemeter for dose measurements in diagnostic radiology.

    Science.gov (United States)

    Jones, A Kyle; Hintenlang, David

    2008-01-01

    Many types of dosemeters have been investigated for absorbed dose measurements in diagnostic radiology, including ionisation chambers, metal-oxide semiconductor field-effect transistor dosemeters, thermoluminescent dosemeters, optically stimulated luminescence detectors, film and diodes. Each of the aforementioned dosemeters suffers from a critical limitation, either the need to interrogate, or read, the dosemeter to retrieve dose information or large size to achieve adequate sensitivity. This work presents an evaluation of a fibre optic-coupled dosemeter (FOCD) for use in diagnostic radiology dose measurement. This dosemeter is small, tissue-equivalent and capable of providing true real-time dose information. The FOCD has been evaluated for dose linearity, angular dependence, sensitivity and energy dependence at energies, beam qualities and beam quantities relevant to diagnostic radiology. The FOCD displayed excellent dose linearity and high sensitivity, while exhibiting minimal angular dependence of response. However, the dosemeter does exhibit positive energy dependence, and is subject to attenuation of response when bent.

  10. Graphite mixed magnesium borate TL dosemeters for beta ray dosimetry

    DEFF Research Database (Denmark)

    Prokic, M; Christensen, Poul

    1984-01-01

    Sintered MgB4O7:Dy dosemeters with graphite contents from 1 to 10% were investigated for application for personnel dosimetry. Data are given on dose response, dose threshold, reproducibility, beta energy response and fading. Furthermore, results from practical field experiments are presented...

  11. Radiological environmental monitoring with LiF-700-H dosemeters

    Energy Technology Data Exchange (ETDEWEB)

    Scarnichia, E.; Levanon, I.; Andres, P.; Miani, C.; Ramirez, S., E-mail: andresp@cab.cnea.gov.ar [Comision Nacional de Energia Atomica, Centro Atomico Bariloche, Grupo Proteccion Radiologica, Exequiel Bustillo 5AV 9500, R8402AGP San Carlos de Bariloche, Rio Negro (Argentina)

    2011-10-15

    Since 2008 a radiological environmental monitoring with LiF-700-H has been carried out as a result of increasing the Ra-6 research reactor core power. The information obtained is used to evaluate and to quantify analytically the air kerma rate, the fading and the associated uncertainty by developing software tools (deconvolution and uncertainty algorithms). LiF-700-H dosemeters were chosen because of their high sensitivity to low air kerma rates. They show a very good stability and a negligible fading for two-month working periods. The air kerma rate detection limit (based on the 3{sigma} criterion) during these working periods is about 0.4 n Gy/h. Air kerma rates of about 70 n Gy/h are measured with this detection limit. Following the Nist guidelines, an algorithm was developed in order to find the associated uncertainty. It considers several aspects, such as the source activity decay, distance source-dosemeter during the calibration procedure, irradiation time, calibration factor, dosemeter readout, dosemeter sensitivity, TLD reader stability and fading. The associated uncertainty is found to be about 25% for a 95% confidence interval (k = 2.025), which can be considered acceptable when taking into account the very low air kerma rates estimated. The LiF-700-H response to different energies and its relationship with climate changes over the calendar year are planned as future tasks. (Author)

  12. Household and workplace chemicals as retrospective luminescence dosemeters

    DEFF Research Database (Denmark)

    Thomsen, Kristina Jørkov; Bøtter-Jensen, L.; Murray, A.S.

    2002-01-01

    In the development of techniques for the retrospective assessment of the close absorbed by communities living and working adjacent to the site of a nuclear accident, attention has concentrated on the use Of natural minerals such as quartz and feldspar as dosemeters. These minerals are widely found...

  13. Calorimetric measurements of losses in HTS cables

    DEFF Research Database (Denmark)

    Tønnesen, Ole; Veje, Niels Erling Winsløv; Rasmussen, Carsten

    2001-01-01

    electrically and compared with the losses obtained with the calorimetric method. The results obtained by the two methods are consistent. Based on an I2 (current) fitting procedure, the loss, caused by the eddy current generated in the stainless steel cryostat housing, and the hysteresis loss generated......A calorimetric test rig is used to investigate various loss components in a 10 m long superconducting cable model. A calorimetric technique, based on thermocouple measurements, is used to measure the losses of the 10 m long superconducting cable model. The current dependent losses are also measured...

  14. Evaluation of BICRON NE MCP DXT-RAD passive extremity dosemeter

    CERN Document Server

    Yuen, P S; Frketich, G; Rotunda, J

    1999-01-01

    Passive extremity dosemeters currently used in dosimetry communities worldwide have shortcomings. In general, an extremity dosemeter has too thick a detector element, and the dosemeter response is highly energy dependent for beta rays with energies ranging from 200 keV to 2 MeV. It often does not have dosemeter identification, causing problems in the chain of custody. It is often read manually, rendering reading/packing operations very labour intensive. As a result of collaboration between AECL and BICRON NE, a new extremity dosemeter, incorporating a highly sensitive LiF:Mg,Cu,P TLD and tentatively code named MCP DXT-RAD, was developed. It has been evaluated for radiological performance against an ISO draft standard for extremity dosemeters in twelve categories: homogeneity, detection threshold, beta ray energy response, beta angular response, photon energy response, photon angular response, reproducibility, stability under various climatic conditions, linearity, residue, self irradiation, and effect of ligh...

  15. Photon and fast neutron dosimetry using aluminium oxide thermoluminescence dosemeters.

    Science.gov (United States)

    Santos, J P; Fernandes, A C; Gonçalves, I C; Marques, J G; Carvalho, A F; Santos, L; Cardoso, J; Osvay, M

    2006-01-01

    Al(2)O(3):Mg,Y thermoluminescence (TL) dosemeters were used to measure photon and fast neutron doses in a fast neutron beam recently implemented at the Portuguese Research Reactor, Nuclear and Technological Institute, Portugal. The activation of Al(2)O(3):Mg,Y by fast neutrons provides information about the fast neutron component by measuring the activity of the reaction products and the self-induced TL signal. Additionally, the first TL reading after irradiation determines the photon dose. The elemental composition of the dosemeters was determined by instrumental neutron activation analysis and by particle induced X-ray emission. Results demonstrate that Al(2)O(3):Mg,Y is an adequate material to discriminate photon and fast neutron fields for reactor dosimetry purposes.

  16. Theoretical aspects of the design of a passive radon dosemeter.

    Science.gov (United States)

    Wilkinson, P; Saunders, B J

    1985-10-01

    Some mathematical aspects of the development and design of a passive radon dosemeter are considered. In particular, a mathematical model is presented that is concerned with the gaseous diffusion of radon into a confined region bounded by a plastic material of known diffusion coefficient. The relationship between the time-integrated radon concentrations, inside and outside a sealed plastic container are derived. Estimates of the exposure of people to radon can be made using the time integrated radon concentration inside a calibrated container containing a CR-39 etched-track device. As a consequence of the analysis, it is possible to design a passive radon dosemeter that will be accurate, resistant to moisture and whose response will be independent of rapid variations in radon concentration. The possibility of using a container of this type for the measurement of diffusion coefficients is discussed.

  17. Development of active environmental and personal neutron dosemeters.

    Science.gov (United States)

    Nakamura, T; Nunomiya, T; Sasaki, M

    2004-01-01

    For neutron dosimetry in the radiation environment surrounding nuclear facilities, two types of environmental neutron dosemeters, the high-sensitivity rem counter and the high-sensitivity multi-moderator, the so-called Bonner ball, have been developed and the former is commercially available from Fuji Electric Co. By using these detectors, the cosmic ray neutrons at sea level have been sequentially measured for about 3 y to investigate the time variation of neutron spectrum and ambient dose equivalent influenced by cosmic and terrestrial effects. Our Bonner ball has also been selected as the neutron detector in the International Space Station and has already been used to measure neutrons in the US experimental module. The real time wide-range personal neutron dosemeter which uses two silicon semiconductor detectors has been developed for personal dosimetry and is commercially available from Fuji Electric Co. This dosemeter has good characteristics, fitted to the fluence-to-dose conversion factor in the energy range from thermal energies to several tens of mega-electron-volts and is now widely used in various nuclear facilities.

  18. New concept of IEC standards for radiation protection dosemeters.

    Science.gov (United States)

    Ambrosi, P; Behrens, R

    2008-01-01

    The International Electrotechnical Commission (IEC) develops new standards for radiation protection dosemeters which follow a new concept. They are much more flexible in detail, but still ensure the same measurement quality. They are, for example, no longer specific for the detector type, but rather specific for the measurement task, e.g. for individual monitoring with active direct-reading instruments. Another example is that they are flexible with respect to the ranges of influence quantities. The conceptual changes are described in this paper, together with the advantages this new concept provides for manufacturers, users and legislators.

  19. Type testing of the Siemens Plessey electronic personal dosemeter

    Energy Technology Data Exchange (ETDEWEB)

    Hirning, C.R. [Ontario Hydro, Health Physics Dept., Whitby, Ontario (Canada); Yuen, P.S

    1994-07-01

    This paper presents the results of a laboratory assessment of the performance of a new type of personal dosimeter, the Electronic Personal Dosemeter made by Siemens Plessey Controls Limited. Twenty pre-production dosimeters and a reader were purchased by Ontario Hydro for the assessment. Tests were performed on radiological performance, including reproducibility, accuracy, linearity, detection threshold, energy response, angular response, neutron response, and response time. There were also tests on the effects of a variety of environmental factors, such as temperature, humidity, pulsed magnetic and electric fields, low- and high-frequency electromagnetic fields, light exposure, drop impact, vibration, and splashing. Other characteristics that were tested were alarm volume, clip force, and battery life. The test results were compared with the relevant requirements of three standards: an Ontario Hydro standard for personal alarming dosimeters, an International Electrotechnical Commission draft standard for direct reading personal dose monitors, and an International Electrotechnical Commission standard for thermoluminescence dosimetry systems for personal monitoring. In general, the performance of the Electronic Personal Dosemeter was found to be quite acceptable: it met most of the relevant requirements of the three standards. However, the following deficiencies were found: slow response time; sensitivity to high-frequency electromagnetic fields; poor resistance to dropping and an alarm that was not loud enough. In addition, the response of the electronic personal dosimeter to low-energy beta rays may be too low for some applications. Problems were experienced with the reliability of operation of the pre-production dosimeters used in these tests. (author)

  20. Tupe testing of the Siemens Plessey electronic personal dosemeter

    Energy Technology Data Exchange (ETDEWEB)

    Hirning, C.R. [Ontario Hydro, Whitby, Ontario (Canada); Yuen, P.S. [Chalk River Laboratories, Chalk River, Ontario (Canada)

    1995-07-01

    This paper presents the results of a laboratory assessment of the performance of a new type of personal dosimeter, the Electronic Personal Dosemeter made by Siemens Plessey Controls Limited. Twenty pre-production dosimeters and a reader were purchased by Ontario Hydro for the assessment. Tests were performed on radiological performance, including reproducibility, accuracy, linearity, detection threshold, energy response, angular response, neutron response, and response time. There were also tests on the effects of a variety of environmental factors, such as temperature, humidity, pulsed magnetic and electric fields, low- and high-frequency electromagnetic fields, light exposure, drop impact, vibration, and splashing. Other characteristics that were tested were compared with the relevant requirements of three standards: an Ontario Hydro standard for personal alarming dosimeters, an International Electrotechnical Commission draft standard for direct reading personal dose monitors, and an International Electrotechnical Commission standard for thermoluminescence dosimetry systems for personal monitoring. In general, the performance of the Electronic Personal Dosemeter was found to be quite acceptable: it met most of the relevant requirements of the three standards. However, the following deficiencies were found: slow response time; sensitivity to high-frequency electromagnetic fields; poor resistance to dropping; and an alarm that was not loud enough. In addition, the response of the electronic personal dosimeter to low-energy beta rays may be too low for some applications. Problems were experienced with the reliability of operation of the pre-production dosimeters used in these tests. 11 refs., 8 figs., 24 tabs.

  1. Type testing of the Siemens Plessey electronic personal dosemeter.

    Science.gov (United States)

    Hirning, C R; Yuen, P S

    1995-07-01

    This paper presents the results of a laboratory assessment of the performance of a new type of personal dosimeter, the Electronic Personal Dosemeter made by Siemens Plessey Controls Limited. Twenty pre-production dosimeters and a reader were purchased by Ontario Hydro for the assessment. Tests were performed on radiological performance, including reproducibility, accuracy, linearity, detection threshold, energy response, angular response, neutron response, and response time. There were also tests on the effects of a variety of environmental factors, such as temperature, humidity, pulsed magnetic and electric fields, low- and high-frequency electromagnetic fields, light exposure, drop impact, vibration, and splashing. Other characteristics that were tested were alarm volume, clip force, and battery life. The test results were compared with the relevant requirements of three standards: an Ontario Hydro standard for personal alarming dosimeters, an International Electrotechnical Commission draft standard for direct reading personal dose monitors, and an International Electrotechnical Commission standard for thermoluminescence dosimetry systems for personal monitoring. In general, the performance of the Electronic Personal Dosemeter was found to be quite acceptable: it met most of the relevant requirements of the three standards. However, the following deficiencies were found: slow response time; sensitivity to high-frequency electromagnetic fields; poor resistance to dropping; and an alarm that was not loud enough. In addition, the response of the electronic personal dosimeter to low-energy beta rays may be too low for some applications. Problems were experienced with the reliability of operation of the pre-production dosimeters used in these tests.

  2. Dosimetric characteristics of a TLD dosemeter with extremities; Caracteristicas dosimetricas de un dosimetro TLD de extremidades

    Energy Technology Data Exchange (ETDEWEB)

    Molina P, D.; Diaz B, E.; Lien V, R. [Centro de Proteccion e Higiene de las Radiaciones, CPHR, Apdo.Postal 6195, Habana 6, CP 10600, Ciudad Habana (Cuba)

    1999-07-01

    It was designed a TLD dosemeter for the monitoring of the extremities. This one consists in a metallic ring with a circular orifice where is arranged a T L detector of LiF: Mg,Ti (Model JR1152C) 5 x 5 x 0.8 mm{sup 3} covered by a polyethylene fine layer. In this work were studied the dosimetric properties of the dosemeter for its application in the dosimetry of extremities for photonic radiation. the results obtained allow conclude that the designed dosemeter can be used for the extremities monitoring. (Author)

  3. Type testing of personal dosemeters for photon energy and angular response

    DEFF Research Database (Denmark)

    Julius, H.W.; Marshall, T.O.; Christensen, Poul;

    1994-01-01

    Performance criteria for personal dosemeters have been recently proposed in the CEC document 'Technical Recommendations for Monitoring Individuals Occupationally Exposed to External Radiation' (EUR 5287, Revised). The current experiment was carried out to demonstrate that TLD-based dosimetry...

  4. Determination of relevant parameters for the use of electronic dosemeters in pulsed fields of ionising radiation.

    Science.gov (United States)

    Zutz, H; Hupe, O; Ambrosi, P; Klammer, J

    2012-09-01

    Active electronic dosemeters using counting techniques are used for radioprotection purposes in pulsed radiation fields in X-ray diagnostics or therapy. The disadvantage of the limited maximum measurable dose rate becomes significant in these radiation fields and leads to some negative effects. In this study, a set of relevant parameters for a dosemeter is described, which can be used to decide whether it is applicable in a given radiation field or not. The determination of these relevant parameters-maximum measurable dose rate in the radiation pulse, dead time of the dosemeter, indication per counting event and measurement cycle time-is specified. The results of the first measurements on the determination of these parameters for an electronic personal dosemeter of the type Thermo Fisher Scientific EPD Mk2 are shown.

  5. Sensitivity of a LR-115 based radon dosemeter

    CERN Document Server

    Bagnoli, F; Bucci, S

    1999-01-01

    The first results of a study on the sensitivity of a LR-115 based radon dosemeter as a function of the absorber thickness are presented. The theoretical sensitivity was analytically calculated considering a constant detector response to alpha particles within a given energy range and up to a critical angle of incidence. The results are presented in two extreme situations: i) both radon and its decay products uniformly distributed in the chamber volume; ii) radon decay products uniformly deposited on the chamber walls. The agreement with the experimental curve shape appears better in the former case, suggesting that either the parameter values of the model could be different from the chosen values, or the model was too simplified.

  6. 1983 ORNL intercomparison of personnel neutron and gamma dosemeters

    Energy Technology Data Exchange (ETDEWEB)

    Swaja, R.E.; Sims, C.S.; Greene, R.T.

    1985-01-01

    The Ninth Personnel Dosimetry Intercomparison Study was conducted during April 19-21, 1983, at the Oak Ridge National Laboratory. Dosemeters from 33 participating agencies were mounted on water-filled polyethylene elliptical phantoms and exposed to a range of low-level dose equivalents (0.02-0.45 mSv gamma and 0.49-11.14 mSv neutron) which could be encountered during routine personnel monitoring in mixed radiation fields. The Health Physics Research Reactor served as the radiation source for six separate exposures which used four different shield conditions: unshielded and shielded with steel, steel/concrete, and concrete. Results of the neutron measurements indicate that it is not unusual for dose equivalent estimates made under the same conditions by different agencies to differ by more than a factor of 2. Albedo systems, which were the most popular neutron monitors in this study, provided the most accurate results with CR-39 recoil track being least accurate. Track and film neutron systems exhibited problems providing measurable indication of neutron exposure at dose equivalents of about 0.50 mSv. Gamma measurements showed that TLD and film systems generally overestimated dose equivalents in the mixed radiation fields with film exhibiting significant problems providing measurable indication of gamma exposure at dose equivalents lower than about 0.15 mSv. Under the conditions of this study in which exposures were carefully controlled and participants had information concerning exposure conditions and incident spectra prior to dosemeter analysis, only slightly more than half of all neutron and gamma dose equivalent estimates met regulatory accuracy standards relative to reference values. These results indicate that continued improvement of mixed-field personnel dosimetry is required by many participating organizations. 15 references, 30 tables.

  7. Calorimetric thermobarometry of experimentally shocked quartz

    Science.gov (United States)

    Ocker, Katherine D.; Gooding, James L.; Hoerz, Friedrich

    1994-01-01

    Structural damage in experimentally shock-metamorphosed, granular quartz is quantitatively measurable by differential scanning calorimetry (DSC). Shock-induced loss of crystallinity is witnessed by disappearance of the alpha/beta phase transformation and evolution of a broad endoenthalpic strain peak at 650-900 K. The strain-energy peak grows rapidly at less than 10 GPa but declines with increasing shock pressure; it approaches zero at 32 GPa where vitrification is extensive. Effects of grain size and post-shock thermal history must be better understood before calorimetric thermobarometry of naturally shocked samples becomes possible.

  8. Numerical and experimental results of the operational neutron dosemeter 'Saphydose-N'.

    Science.gov (United States)

    Lahaye, T; Chau, Q; Ménard, S; Ndontchueng-Moyo, M; Bolognese-Milsztajn, T; Rannou, A

    2004-01-01

    Since 1993, the Institute for Radiological Protection and Nuclear Safety (IRSN) has lead, in association with Electricité de France (EDF), a R&D study of a neutron personal electronic dosemeter. This dosemeter, called 'Saphydose-N', is manufactured by the SAPHYMO company. This paper presents first the optimisation of some detector components using Monte Carlo calculations, and second the test of the manufactured Saphydose-N under radiation following the IEC 1323 standard's recommendations for active personal neutron dosemeters. The measurements with the manufactured dosemeter were performed on the one hand at PTB (Physikalisch-Technische Bundesanstalt) in mono-energetic neutron fields and, on the other hand at IRSN in neutron fields generated by a thermal facility (SIGMA), radionuclide ISO sources and a realistic spectrum (CANEL/T400). The manufactured dosemeter Saphydose-N was also tested during measurement campaigns of the European programme EVIDOS ('Evaluation of Individual Dosimetry in Mixed Neutron and Photon Radiation Fields') at different nuclear workplaces. The study showed that Saphydose-N complies with the recommendations of standard IEC 1323 and can be used at any workplace with no previous knowledge of the neutron field characteristics.

  9. Electrical and calorimetric measurements and related software

    CERN Document Server

    Catalan-Lasheras, N; Koratzinos, M; Rijllart, A; Siemko, A; Strait, J; Tavian, L; Wolf, R

    2009-01-01

    During the incident of sector 3-4 on September 19th, the temperature of a number of magnets increased over the expected values prior to the circuit failure. A review of the data logged during powering tests on all circuits indicated potential resistive splices in sectors 1-2 and 6-7. Calorimetric and electrical measurements confirmed a high resistance in magnet B16. R1 and B32R6. Systematic measurements have been performed in other cold sectors of the LHC during which the temperature increase and voltage across magnets were acquired at different currents. Cryogenic subsectors on which the temperature increase was abnormal were equipped with precise voltmeters to detect eventual resistive splices in the bus-bars. The findings of the measurement campaign will be shown as well as the plans to implement similar diagnostics as a routine check prior to powering the superconducting circuits of the LHC.

  10. Eurados trial performance test for personal dosemeters for external beta radiation

    DEFF Research Database (Denmark)

    Christensen, P.; Bordy, J.M.; Ambrosi, P.

    2001-01-01

    was accomplished, This paper deals with the part of the performance test concerned with exposure to beta radiation. Fifteen dosimetric services participated with whole-body dosemeters intended to measure beta doses (H-p(0.07)) of which 13 used thermoluminescent (TL) detectors and two used photographic films. Eight......On the initiative of the European Dosimetry Group (EURADOS) action group 'Harmonisation and Dosimetric Quality Assurance in Individual Monitoring for External Radiation' a trial performance test for whole-body and extremity personal dosemeters broadly representative of those in use in the EU...... the results obtained from the exercise. In particular, based on the replies to a questionnaire issued to each participant, the results are analysed in relation to important design characteristics of the dosemeters taking part in the test....

  11. Independent evaluation of optically stimulated luminescence (OSL) 'dot' dosemeters for environmental monitoring.

    Science.gov (United States)

    Timilsina, Bindu; Gesell, Thomas F

    2011-01-01

    Optically stimulated luminescence (OSL) 'dot' dosemeters (manufactured by Landauer®) are reported to have a high degree of environmental stability, high level of sensitivity and provide wide range of dose measuring capabilities from 0.05 mGy to 100 Gy. The optical read out method is fast and relatively simple and permits repeated read out, but few studies have been performed about its application in monitoring radiation in the environment. This study was initiated to independently test the performance of OSL dot dosemeters for the application of measuring doses of radiation in the outdoor environment. Testing was performed in the laboratory to evaluate reproducibility and stability and in the field to evaluate accuracy relative to calibrated high-pressure ionisation chambers. The results showed that OSL dot dosemeters had good reproducibility and stability in both laboratory and field tests and met the performance requirements of standards of the American National Standards Institute.

  12. Mixed field personnel dosimetry using a nearly tissue-equivalent multi-element thermoluminescence dosemeter

    Energy Technology Data Exchange (ETDEWEB)

    Moscovitch, M.; Velbeck, K.J.; Bencke, G.M. (Engelhard Corp., Harshaw Crystal and Electronic Products, Solon, OH (USA))

    1990-01-01

    The method of response interpretation for determining dose equivalents of a new multi-element thermoluminescence dosemeter in mixed photon-beta and photon-neutron fields is described. The four TL chips are LiF:Mg,Ti, each covered by its own unique filter. Experiments to determine the response of the dosemeter and to test the dose calculation algorithm were performed according to the standard established by the US Department of Energy Laboratory Accreditation Program (DOELAP). It has been shown that the dosemeter response can be used to identify the mixture type. The accuracy of the system has been proven in blind testing to be well within DOELAP tolerance limits in all test categories. (author).

  13. Theoretical study and calculation of the response of a fast neutron dosemeter based on track detection

    Energy Technology Data Exchange (ETDEWEB)

    Decossas, J.L.; Vareille, J.C.; Moliton, J.P.; Teyssier, J.L. (Limoges Univ., 87 (France). Lab. d' Electronique des Polymeres sous Faisceaux Ioniques)

    1983-01-01

    A fast neutron dosemeter is generally composed of a radiator in which n-p elastic scattering occurs and a detector which registers protons. A theoretical study, and the calculation (FORTRAN program) of the response of such a dosemeter is presented involving two steps: 1) The proton flux emerging from a thick radiator on which monoenergetic neutrons are normally incident is studied. This is characterised by its energy spectrum depending on the neutron energy and on the radiator thickness. 2) Proton detection being achieved with a solid state nuclear track detector whose performance is known, the number of registered tracks are calculated. The dosemeter sensitivity (tracks cm/sup -2/. Sv/sup -1/) is deduced. Then, the calculations show that it is possible to optimise the radiator thickness to obtain the smallest variation in sensitivity with neutron energy. The theoretical results are in good agreement with the experimental ones found in the literature.

  14. Elimination of Cerenkov interference in a fibre-optic-coupled radiation dosemeter.

    Science.gov (United States)

    Justus, Brian L; Falkenstein, Paul; Huston, Alan L; Plazas, Maria C; Ning, Holly; Miller, Robert W

    2006-01-01

    An optical fibre point dosemeter based on the gated detection of the luminescence from a Cu(1+)-doped fused quartz detector effectively eliminated errors due to Cerenkov radiation and native fibre fluorescence. The gated optical fibre dosemeter overcomes serious problems faced by scintillation and optically stimulated luminescence approaches to optical fibre point dosimetry. The dosemeter was tested using an external beam radiotherapy machine that provided pulses of 6 MV X rays. Gated detection was used to discriminate the signal collected during the radiation pulses, which included contributions from Cerenkov radiation and native fibre fluorescence, from the signal collected between the radiation pulses, which contained only the long-lived luminescence from the Cu(1+)-doped fused quartz detector. Gated detection of the luminescence provided accurate, real-time dose measurements that were linear with absorbed dose, independent of dose rate and that were accurate for all field sizes studied.

  15. DESIGN DEVELOPMENT OF A PASSIVE NEUTRON DOSEMETER FOR THE USE AT HIGH-ENERGY ACCELERATORS.

    Science.gov (United States)

    Sokolov, Alexey; Fehrenbacher, Georg; Radon, Torsten

    2016-09-01

    For the radiation survey at intermediate and high-energy accelerators, there is a need for a neutron dosemeter which provides reliable readings of the neutron dose in a wide energy range for continuous and pulsed radiation. The objective of this development is to find a dosemeter that fulfils the necessary requirements and can be reliably used to prove that the radiation levels in areas around accelerators are in accordance with the limits of the respective radiation protection legislation. A simple layout with small dimensions and light weight as well as the usage of common materials to lower the production costs is to be achieved.

  16. Calorimetric examinations of austempered ductile iron ADI

    Directory of Open Access Journals (Sweden)

    F. Binczyk

    2007-12-01

    Full Text Available The study presents the results of calorimetric examinations during heating and cooling of austempered ductile iron ADI after austempering at temperatures of 280, 330 and 380oC. The samples for examinations were taken from cast rods of 20 and 60 mm diameter. Examinations were carried out on a differential scanning calorimeter, type Multi HTC S60. During heating, on a DSC curve one strong exothermic effect has been noted to occur (it does not occur in the case of common-grade cast iron, accompanied by two endothermic effects. The exothermic effect occurs within the range of about 20oC. Depending on the temperature of austempering treatment, its beginning falls to the temperatures from 469 to 490oC. The heat of this effect is proportional to the austenite content in ADI matrix after austempering. The endothermic effects are related with decomposition of pearlite (or bainite and with phase transformation α → γ (ferrite as a constituent of ausferritic matrix.

  17. Testing the direct ion storage dosemeter for personal dosimetry in a nuclear research centre and a hospital.

    Science.gov (United States)

    Vanhavere, F; Covens, P

    2010-03-01

    The direct ion storage (DIS) dosemeter can have some clear advantages in personal dosimetry. Before introducing the DIS into practice in the dosimetry service, a series of tests was performed on the linearity, angular and energy dependence, temperature influences and hard resets. After that, for several months, the DIS dosemeters were worn in parallel with the legal dosemeters (thermoluminescent badge) in a nuclear research centre and in several departments of a university hospital. The conclusions are that the DIS has good characteristics to be used as legal personal dosemeter, and that the comparison with the TLD badge is good. Only in interventional radiology and cardiology fields the DIS gives significant lower values than the TLD badge.

  18. COMPARISON METHODOLOGIES FOR CALIBRATION OF Hp(10) PERSONAL DOSEMETERS USING ISO 4037 AND ISO 29661 STANDARDS.

    Science.gov (United States)

    Cardoso, J; Santos, L; Carvalhal, G; Oliveira, C

    2016-09-01

    The calibration of electronic personal dosemeters at the Portuguese ionizing radiation metrology laboratory uses the standard IEC 61526 for calibration methodology. This standard describes the irradiation geometry for testing and indicates that the standard ISO 4037-1, 2, 3 and 4 should be used. The ISO 4037 establishes that the reference point of test is a point in the radiation monitor, known or established, and the calibration phantom should be placed on its back in order to simulate the trunk body. Recently, ISO published another standard, the ISO 29661, that changes the reference point from the radiation monitor to the front face of the calibration phantom. The aim of this work is to present the result of the comparison of these two methodologies on personal dosemeters from five different manufacturers. The work shows differences in the Hp(10) response up to 4% resulting from the two different reference point concepts.

  19. Measurement models for passive dosemeters in view of uncertainty evaluation using the Monte Carlo method.

    Science.gov (United States)

    van Dijk, J W E

    2014-12-01

    Two measurement models for passive dosemeters such as thermoluminescent dosemeter, optically stimulated luminescence, radio-photoluminescence, photographic film or track etch are discussed. The first model considers the dose evaluation with the reading equipment as a single measurement, the one-stage model. The second model considers the build-up of a latent signal or latent image in the detector during exposure and the evaluation using a reader system as two separate measurements, the two-stage model. It is discussed that the two-stage model better reflects the cause and effect relations and the course of events in the daily practice of a routine dosimetry service. The one-stage model will be non-linear in crucial input quantities which can give rise to erroneous behavior of the uncertainty evaluation based on the law of propagation of uncertainty. Input quantities that show an asymmetric probability distributions propagate through the one-stage model in a physically not relevant way.

  20. Application of TL dosemeters for dose distribution measurements at high temperatures in nuclear reactors.

    Science.gov (United States)

    Osvay, M; Deme, S

    2006-01-01

    Al2O3:Mg,Y ceramic thermoluminescence dosemeters were developed at the Institute of Isotopes for high dose applications at room temperatures. The glow curve of Al2O3:Mg,Y exhibits two peaks--one at 250 degrees C (I) and another peak at approximately 400 degrees C (II). In order to extend the application of these dosemeters to high temperatures, the effect of irradiation temperature was investigated using temperature controlled heating system during high dose irradiation at various temperatures (20-100 degrees C). The new calibration and measuring method has been successfully applied for dose mapping within the hermetic zone of the Paks Nuclear Power Plant even at high temperature parts of blocks.

  1. ENEA extremity dosemeter based on LiF(Mg,Cu,P) to evaluate Hp(3,alpha).

    Science.gov (United States)

    Mariotti, F; Fantuzzi, E; Morelli, B; Gualdrini, G; Botta, M C; Uleri, G; Bordy, J M; Denoziere, M

    2011-03-01

    Recent epidemiological studies suggest a rather low-dose threshold (ORAMED) Project, whose WP2 is aimed at the quantity H(p)(3) and eye lens dosimetry in practice, are taken into account. The paper summarises the main aspects of the study carried out at ENEA-Radiation Protection Institute (Bologna, Italy) to provide practical solutions (in the use and the design) to evaluate the response of the ENEA TL extremity dosemeter in terms of H(p)(3).

  2. ENERGY AND ANGULAR DEPENDENCE OF RADIOPHOTOLUMINESCENT GLASS DOSEMETERS FOR EYE LENS DOSIMETRY.

    Science.gov (United States)

    Silva, E H; Knežević, Ž; Struelens, L; Covens, P; Ueno, S; Vanhavere, F; Buls, N

    2016-09-01

    Recent studies demonstrated that lens opacities can occur at lower radiation doses than previously accepted. In view of these studies, the International Commission of Radiological Protection recommended in 2011 to reduce the eye lens dose limit from 150 mSv/y to 20 mSv/y. This implies in the need of monitoring doses received by the eye lenses. In this study, small rod radiophotoluminescent glass dosemeters (GD-300 series; AGC, Japan) were characterized in terms of their energy (ISO 4037 X-rays narrow spectrum series, S-Cs and S-Co) and angular dependence (0  up to 90 degrees, with 2 ISO energies: N-60 and S-Cs). All acquisitions were performed at SCK•CEN-Belgium, using the ORAMED proposed cylindrical phantom. For selected energies (N-60, N-80, N-100, N-120 and N-250), the response of dosemeters irradiated on the ISO water slab phantom, at the Ruđer Bošković Institute-Croatia, was compared to those irradiated on the cylindrical phantom. GD-300 series showed good energy dependence, relative to S-Cs, on the cylindrical phantom. From 0 up to 45 degrees, the dosemeters showed no significant angular dependence, regardless whether they were tested when placed vertically or horizontally on the cylindrical phantom. However, at higher angles, some angular dependence was observed, mainly when the dosemeters were irradiated with low-energy photons (N-60). Results showed that GD-300 series have good properties related to Hp(3), although some improvements may be necessary.

  3. Individual monitoring in nuclear medicine therapeutic procedures using extremity dosemeters LiF(Mg, Cu, P).

    Science.gov (United States)

    Sarti, G; Del Dottore, F; Fabbri, C; Tassinari, L; Pagan, S; Rustignoli, M; Motta, P

    2011-03-01

    Unsealed beta-gamma-emitting sources are used (15 GBq (90)Y each session) in nuclear medicine therapeutic procedures. Inside the manipulation cell and while giving the injection to the patient, the skin exposure is very high; electron radiation field is not homogeneous and thus the exposure of the extremities is not uniform. Particular individual monitoring is adopted: single thermoluminescence dosemeter, wrapped in polyethylene film and placed on an adhesive tape, is positioned on the tip of the fingers; 6-10 dosemeters are assigned to each operator per session. The energy and angle response is studied for X-ray spectra, (90)Sr/Y and (204)Tl--a unique mean calibration factor is calculated in order to estimate H(p)(0.07). Performance of dosemeter is analysed according to ISO 62387-1(2007) and the combined uncertainty (calculated using the Monte Carlo method) results lie in the order of 11 %. This method reveals the critical step of manipulation and administration and ensures that dose limits are not exceeded.

  4. The 12B counter: an active dosemeter for high-energy neutrons.

    Science.gov (United States)

    Leuschner, A

    2005-01-01

    High-energy accelerators can produce strong time-structured radiation fields. Such dose shots are generated at linear machines with low duty cycles as well as at circular machines when complete fills are instantaneously lost. The main dose component behind thick shielding is due to high-energy neutrons occurring at that time structure. Dosemeters based on Geiger-Mueller tubes or proportional counters fail here completely. The 12B counter, a novel dosemeter made of a plastic scintillator using carbon activation for event-like exposure, has been introduced. High-energy neutrons activate the carbon nuclei by three inelastic reactions. The decay patterns with half-lives between 20 ms and 20 min can be exploited depending on the time structure of the radiation field. The response of the 12B counter was measured along with some other dosemeters, both active and passive, in the radiation field behind the lateral concrete shielding of a 7.5 GeV proton transfer line.

  5. Calorimetric signature of structural heterogeneity in a ternary silicate glass

    DEFF Research Database (Denmark)

    Zhang, Yanfei; Yang, G.; Yue, Yuanzheng

    2013-01-01

    We investigate the structural heterogeneity in a silicate glass by hyperquenching–annealing–calorimetry approach. The results show a striking phenomenon: two separated sub-Tg relaxation peaks appear on the calorimetric curve of the hyperquenched CaO–MgO–SiO2 glass, implying the existence of two d...

  6. Effective dose assessment in the maxillofacial region using thermoluminescent (TLD) and metal oxide semiconductor field-effect transistor (MOSFET) dosemeters: a comparative study

    NARCIS (Netherlands)

    Koivisto, J.; Schulze, D.; Wolff, J.; Rottke, D.

    2014-01-01

    Objectives: The objective of this study was to compare the performance of metal oxide semiconductor field-effect transistor (MOSFET) technology dosemeters with thermoluminescent dosemeters (TLDs) (TLD 100; Thermo Fisher Scientific, Waltham, MA) in the maxillofacial area. Methods: Organ and effective

  7. EXPERIMENTAL STUDY OF INDIVIDUAL THERMOLUMINESCENT DOSEMETERS PERFORMANCES FOR MEASURING THE DOSE EQUIVALENTS IN SKIN AND EYE LENS

    Directory of Open Access Journals (Sweden)

    E. N. Sheleenkova

    2014-01-01

    Full Text Available The article gives a comparative analysis of existing and newly developed thermoluminescent detectors DTG-4, TTLD-580, TLD-1011(TM and DTVS-01 and dosemeters MKD-A and MKD-B for the purposes of individual dosimetric control of skin and eye lens exposure to radiation. The dependence of sensitivity of different thermoluminescent dosemeters, designed for dose equivalents measurements in skin and eye lens on the type (photons and ȕ-particles and energy of radiation was determined experimentally. There are conclusions about the limits of applicability of existing detectors and dosemeters under different radiation exposure conditions. The article evaluates the possibility of different dosimeter use for specific radiation exposure conditions.

  8. Response of neutron dosemeters in radiation protection environments: an investigation of techniques to improve estimates of dose equivalent

    Energy Technology Data Exchange (ETDEWEB)

    Naismith, O.F.; Thomas, D.J. [National Physical Lab., Teddington (United Kingdom); Siebert, B.R.L. [Physikalisch-Technische Bundesanstalt, Braunschweig (Germany)

    1997-09-01

    The response of practicable neutron dosemeters for routine use generally does not match the conversion function from fluence for radiation protection quantities such as the ambient dose equivalent. As a consequence, significant errors may be encountered when monitoring in a neutron energy spectrum different from that in which the dosemeter was calibrated, which is almost inevitably the case. A database of neutron energy spectra, detector response functions, and dosimetric conversion factors has been developed, and has been used to investigate the extent of this problem. The paper examines various ways of improving dosemeter response by `ranking` spectra and deriving correction factors based upon this ordering. In the case of area monitoring, a combination of two responses (e.g. a rem meter and TEPC) may serve to improve the measurement of dose equivalent. (author).

  9. Calorimetric Measurements of Liquid Al-Zn Alloys

    Science.gov (United States)

    Dębski, Adam; Gąsior, Władysław; Szmit, Katarzyna

    2016-10-01

    The integral molar enthalpies of mixing were determined by the drop calorimetric method for binary AL-Zn liquid solutions and compared with the Miedema model as well as the earlier experimental data. The measurements were conducted at two temperatures: 957 K and 1001 K (684 °C and 728 °C), in the entire concentration range. Based on the experimental calorimetric data of this study as well as those available in the literature and the results of the activity studies, the interaction parameters of the Redlich-Kister equation for the liquid Al-Zn phase were worked out with the use of the least square method. The partial and integral Gibbs energies, entropies and enthalpies were calculated and presented in tables and figures. Additionally, the concentration-concentration partial structure factors for the ideal and real Al-Zn solutions were calculated and graphically presented.

  10. Time-Dependent and Light-Induced Fading in Victoreen Model 2600-80 Aluminum Oxide Thermoluminescence Dosemeters

    Science.gov (United States)

    1993-01-01

    2600-80 Aluminium Oxide Thermoluminescence Dosemeters ":"TIC,7 • :+ " 7-t-•CTE S , E 1P 1993 F’ t LEA l E J. H. Musk AFRRI TR93-6 Cleared for Public...SUBTITLE 5. FUNDING NUMBERS Time-Dependent and Light-Induced Fading in Victoreen0 Model 2600-80 Aluminium Oxide Thermoluminescence PE: QAXM...MODEL 2600-80 ALUMINIUM OXIDE THERMOLUMINESCENCE DOSEMETERS J. H. Musk Accesion For NTIS CRA&I DTIC TAB U.,announced D Justification ........ -.. By

  11. Optical fibre dosemeter systems for clinical applications based on radioluminescence and optically stimulated luminescence from Al2O3:C

    DEFF Research Database (Denmark)

    Marckmann, C.J.; Andersen, C.E.; Aznar, M.C.

    2006-01-01

    Optical fibre dosemeter systems based on radioluminescence and optically stimulated luminescence (OSL) from carbon-doped aluminium oxide (Al2O3:C) crystals were developed for in vivo real-time dose rate and absorbed dose measurements in radiotherapy and mammography. A technique was also developed...... for making ultra-small dosemeter probes that can easily be placed inside patients in radiation treatment. These probes have shown excellent properties in both head and neck intensity-modulated radiation therapy treatment and in mammography. The dose-response of the OSL signal for the new optical fibre...

  12. Development of advanced-type multi-functional electronic personal dosemeter.

    Science.gov (United States)

    Nunomiya, T; Abe, S; Aoyama, K; Nakamura, T

    2007-01-01

    An advanced-type small, light, multi-functional electronic personal dosemeter has been developed using silicon semiconductor radiation detectors for dose management of workers at nuclear power plants and accelerator facilities. This dosemeter is 62 x 82 x 27 mm(3) in size and approximately 130 g in weight, which is capable of measuring personal gamma ray and neutron dose equivalents, Hp(10), simultaneously. The neutron dose equivalent can be obtained using two types of silicon semiconductors: a slow-neutron sensor (1 MeV). The slow neutron sensor is a 10 x 10 mm(2) p-type silicon on which a natural boron layer is deposited around an aluminium electrode. The fast neutron sensor is also a 10 x 10 mm(2) p-type silicon crystal on which an amorphous silicon hydride is deposited. The neutron energy response corresponding to the fluence-to-dose-equivalent conversion coefficient given by ICRP Publication 74 has been evaluated using a monoenergetic neutron source from 250 keV to 15 MeV at the Fast Neutron Laboratory of Tohoku University. As the result, the Hp(10) response to neutrons in the energy range of 250 keV and 4.4 MeV within +/-50% difference has been obtained.

  13. In-vivo dosimetry in radiotherapy: a comparison of the response of semiconductor and thermoluminescence (TLD700) dosemeters

    Energy Technology Data Exchange (ETDEWEB)

    Vynckier, S. [Universite Catholique de Louvain, Brussels (Belgium). Cliniques Universitaires St. Luc; Greffe, J.L.; Loncol, T.; Vanneste, F.; Octave-Prignot, M.; Denis, J.M.; De Patoul, N.

    1995-12-01

    Semiconductor dosemeters and thermoluminescence dosemeters were calibrated in view of in-vivo dosimetry. Their response in a 8 MV photon beam and the respective correction factors for the treatment conditions were systematically studied. A total of 249 entrance and exit measurements with this dual detector combination were performed, mainly for treatments of the head and neck region. The resulting entrance and exit doses were compared with the expected doses at these positions, calculated on basis of the treatment and patient parameters. The results at the entrance showed a value of 1.010 (2.8% for the ratio of the measured to the calculated dose by diodes, 1.013) 4.9% for the ratio of the measured to the calculated dose by TLD and 1.003 (3.6% for the ratio of the measured dose by TLD to diodes. With respect the exit dose, the results were 0.998) 4.9%, 1.016 (7.7% and 1.019) 7.0% respectively after correction for the heterogeneity`s. Although the standard deviation for the TLD dosemeters is systematically larger than the standard deviation for the diodes, it is concluded that both dosemeters will yield similar results for-in-vivo dosimetry, if utilized under the same conditions.

  14. Viability of the Fricke dosemeter doped with methylene blue; Viabilidade do dosimetro Fricke dopado com azul de metileno

    Energy Technology Data Exchange (ETDEWEB)

    Souza, V.L.B.; Santos, C.D.A.; Rodrigues, K.R.G.; Cunha, M.S.; Figueiredo, M.D.C.; Melo, R.T. [Centro Regional de Ciencias Nucleares do Nordeste (CRCN-NE/CNEN-PE), Recife, PE (Brazil)

    2009-07-01

    This work aims to find the possible utilization of the Fricke dosemeter doped with methylene blue (FMB) for the dosimetry of photodynamic therapy. The FMB was irradiated wit X rays and light emitted diodes demonstrating positive answers to the stimulus, being probably to be used for dosimetric objectives

  15. A STUDY ON THE UNCERTAINTY FOR THE ROUTINE DOSIMETRY SERVICE AT THE LEBANESE ATOMIC ENERGY COMMISSION USING HARSHAW 8814 DOSEMETERS.

    Science.gov (United States)

    Rizk, C; Vanhavere, F

    2016-09-01

    The personal dosimetry service at the Lebanese Atomic Energy Commission uses Harshaw 8814 cards with LiF:Mg,Ti detectors. The dosemeters are read in a Harshaw 6600 TLD reader. In the process of accreditation for the ISO 17025 standard((1)), different influence factors are investigated and the uncertainty has been determined. The Individual Monitoring Service Laboratory-LAEC reads the dosemeters once it receives them from the customer, and new cards are immediately given for the next wearing period. The wearing period is 2 months. The dosemeter results are reported to the customers without background subtraction. Both Hp(10) and Hp(0.07) are reported. For this paper, only the uncertainty on Hp(10) will be focussed. The following factors are taken into account for the uncertainty: calibration factor, dosemeter homogeneity and repeatability, energy and angular dependence, non-linearity, temperature dependence, etc. Also the detection limit was determined. One of the important factors is the correction for fading. This fading correction depends on the procedure used such as storage temperatures, the time-temperature profile of the read-out, pre-heat and annealing conditions. Pre- and post-irradiation fading curves were measured for a storage period up to 182 d at room temperature (15-25°C). The resulting final combined standard uncertainty on the reported doses is of the order of 24 % for doses of ∼1 mSv.

  16. MCNP simulation of the incident and Albedo neutron response of the IRD Albedo Neutron Dosemeter for {sup 241}Am-Be moderated sources

    Energy Technology Data Exchange (ETDEWEB)

    Freitas, Bruno M.; Martins, Marcelo M.; Mauricio, Claudia L.P.; Mauricio, Claudia L.P. da, E-mail: claudia@ird.gov.br [Instituto de Radioprotecao e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil); Silva, Ademir X. [Coordenacao dos Programas de Pos-Graduacao em Engenharia (COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Nuclear

    2015-07-01

    The IRD TLD Albedo dosemeter measures both incident and albedo neutron component. The incident to Albedo ratio is used to take into account the energy dependence of its response. In this paper, the behavior of the IRD Albedo dosemeter response as a function of the incident to Albedo ratio for {sup 241}Am-Be sources was simulated to improve its algorithm. The simulation was performed in MCNPX transport code and presents a good agreement with experimental measurements. The results obtained in this work are very useful to improve the accuracy of the IRD Albedo dosemeter at real neutron workplace. (author)

  17. Measurement of the calorimetric energy scale in MINOS

    Energy Technology Data Exchange (ETDEWEB)

    Hartnell, Jeffrey J.

    2005-06-01

    MINOS is a long-baseline neutrino oscillation experiment. A neutrino beam is created at the Fermi National Accelerator Laboratory in Illinois and fired down through the Earth. Measurements of the energy spectra and composition of the neutrino beam are made both at the source using the Near detector and 735 km away at the Soudan Underground Laboratory in Minnesota using the Far detector. By comparing the spectrum and flavour composition of the neutrino beam between the two detectors neutrino oscillations can be observed. Such a comparison depends on the accuracy of the relative calorimetric energy scale. This thesis details a precise measurement of the calorimetric energy scale of the MINOS Far detector and Calibration detector using stopping muons with a new ''track window'' technique. These measurements are used to perform the relative calibration between the two detectors. This calibration has been accomplished to 1.7% in data and to significantly better than 2% in the Monte Carlo simulation, thus achieving the MINOS relative calibration target of 2%. A number of cross-checks have been performed to ensure the robustness of the calorimetric energy scale measurements. At the Calibration detector the test-beam energy between run periods is found to be consistent with the detector response to better than 2% after the relative calibration is applied. The muon energy loss in the MINOS detectors determined from Bethe-Bloch predictions, data and Monte Carlo are compared and understood. To estimate the systematic error on the measurement of the neutrino oscillation parameters caused by a relative miscalibration a study is performed. A 2% relative miscalibration is shown to cause a 0.6% bias in the values of {Delta}m{sup 2} and sin{sup 2}(2{theta}).

  18. Measurement of the calorimetric energy scale in MINOS

    Energy Technology Data Exchange (ETDEWEB)

    Hartnell, Jeffrey J. [St. John' s College, Oxford (United Kingdom)

    2005-01-01

    MINOS is a long-baseline neutrino oscillation experiment. A neutrino beam is created at the Fermi National Accelerator Laboratory in Illinois and fired down through the Earth. Measurements of the energy spectra and composition of the neutrino beam are made both at the source using the Near detector and 735 km away at the Soudan Underground Laboratory in Minnesota using the Far detector. By comparing the spectrum and flavour composition of the neutrino beam between the two detectors neutrino oscillations can be observed. Such a comparison depends on the accuracy of the relative calorimetric energy scale. This thesis details a precise measurement of the calorimetric energy scale of the MINOS Far detector and Calibration detector using stopping muons with a new ''track window'' technique. These measurements are used to perform the relative calibration between the two detectors. This calibration has been accomplished to 1.7% in data and to significantly better than 2% in the Monte Carlo simulation, thus achieving the MINOS relative calibration target of 2%. A number of cross-checks have been performed to ensure the robustness of the calorimetric energy scale measurements. At the Calibration detector the test-beam energy between run periods is found to be consistent with the detector response to better than 2% after the relative calibration is applied. The muon energy loss in the MINOS detectors determined from Bethe-Bloch predictions, data and Monte Carlo are compared and understood. To estimate the systematic error on the measurement of the neutrino oscillation parameters caused by a relative miscalibration a study is performed. A 2% relative miscalibration is shown to cause a 0.6% bias in the values of Δm2 and sin2(2θ).

  19. Adiabatic calorimetric decomposition studies of 50 wt.% hydroxylamine/water.

    Science.gov (United States)

    Cisneros, L O; Rogers, W J; Mannan, M S

    2001-03-19

    Calorimetric data can provide a basis for determining potential hazards in reactions, storage, and transportation of process chemicals. This work provides calorimetric data for the thermal decomposition behavior in air of 50wt.% hydroxylamine/water (HA), both with and without added stabilizers, which was measured in closed cells with an automatic pressure tracking adiabatic calorimeter (APTAC). Among the data provided are onset temperatures, reaction order, activation energies, pressures of noncondensable products, thermal stability at 100 degrees C, and the effect of HA storage time. Discussed also are the catalytic effects of carbon steel, stainless steel, stainless steel with silica coating, inconel, titanium, and titanium with silica coating on the reaction self-heat rates and onset temperatures. In borosilicate glass cells, HA was relatively stable at temperatures up to 133 degrees C, where the HA decomposition self-heat rate reached 0.05 degrees C/min. The added stabilizers appeared to reduce HA decomposition rates in glass cells and at ambient temperatures. The tested metals and metal surfaces coated with silica acted as catalysts to lower the onset temperatures and increase the self-heat rates.

  20. Calorimetric monitoring of the serum proteome in schizophrenia patients

    Energy Technology Data Exchange (ETDEWEB)

    Krumova, Sashka [Institute of Biophysics and Biomedical Engineering, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Bl. 21, Sofia 1113 (Bulgaria); Rukova, Blaga [Department of Medical Genetics, Medical University of Sofia, 2 Zdrave Str., Sofia 1431 (Bulgaria); Todinova, Svetla [Institute of Biophysics and Biomedical Engineering, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Bl. 21, Sofia 1113 (Bulgaria); Gartcheva, Lidia [National Specialized Hospital for Active Treating of Haematological Diseases, 6 Plovdivsko pole Str., Sofia 1756 (Bulgaria); Milanova, Vihra [Department of Psychiatry, Medical University of Sofia, 1 Sv. Georgi Sofiiski Str., Sofia 1431 (Bulgaria); Toncheva, Draga [Department of Medical Genetics, Medical University of Sofia, 2 Zdrave Str., Sofia 1431 (Bulgaria); Taneva, Stefka G., E-mail: stefka.germanova@ehu.es [Institute of Biophysics and Biomedical Engineering, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Bl. 21, Sofia 1113 (Bulgaria)

    2013-11-20

    Highlights: • DSC reveals modified thermal behavior of blood serum from schizophrenic patients. • The high-abundance portion of the serum proteome is thermally stabilized in Sz. • The Sz plasma thermograms are classified in four distinct calorimetric groups. • The effectiveness of drug treatment correlates with the plasma thermodynamic behavior. - Abstract: Schizophrenia (Sz) is a multifactorial mental disorder with high frequency. Due to its chronic and relapsing nature there is a strong need for biomarkers for early psychosis detection and objective evaluation of drug (usually antipsychotics) treatment effect. Here differential scanning calorimetry (DSC) is applied to thermodynamically characterize the blood serum proteome of paranoid schizophrenia patients on routine antipsychotic treatment in comparison to healthy controls. DSC revealed significant modifications in the thermodynamic behavior of blood sera from Sz patients, the overall thermal profile being changed in all Sz cases under study. The calorimetric profiles were classified in four distinct groups, reflecting different thermal stabilization of the high-abundance portion of the serum proteome. The observed positive (thermograms becoming closer to the healthy profile) or negative (thermograms deviating stronger from the healthy profile) proteome thermal stability switches and the Sz thermograms persistence in patients’ follow-up corresponded well with the effect of drug treatment.

  1. Performance of Panasonic ZP-1460 Electronic Personal Dosemeter under Exposure Conditions Likely to be Found at Fukushima Daiichi Nuclear Power Plant

    Science.gov (United States)

    Tsujimura, Norio; Yoshida, Tadayoshi; Hoshi, Katsuya; Momose, Takumaro

    A study on the performance of the Panasonic ZP-1460 electronic personal dosemeter, the model used in the aftermath of the Fukushima Daiichi nuclear power plant accident in March 2011, was conducted under actual exposure situations likely encountered in the plant. The tests pertained to (1) the dose rate response over dose rates >100 mSv/h and (2) the angular response on an anthropomorphic phantom exposed to the rotational and isotropic irradiation geometries. The test results confirmed that the dosemeter provides Hp(10) as a reasonably close estimate of the effective dose for any exposure geometries. The dosemeter response data evaluated in this study can be utilized for converting dosemeter readings to the absorbed dose to any organs and tissues for epidemiologic purposes.

  2. Ten years of personnel neutron dosimetry with Albedo dosemeters in the Netherlands

    Energy Technology Data Exchange (ETDEWEB)

    Draaisma, F.S.; Verhagen, H.W

    2002-07-01

    Since 1987, the dosimetry service of the Netherlands Energy Research Foundation has been certified by the Dutch government to perform personal dosimetry, using thermoluminescence dosemeters (TLDs). Performing neutron personal dosimetry requires a rather large investment in readers, TLDs and personnel to operate the service. About 800 persons are subjected to routine neutron monitoring in the Netherlands and their annual neutron doses are a relatively small fraction (less than 10%) of the annual H{sub p}(10). In general, the measured neutron dose values are low (on average 93% of the users receive an annual neutron dose <0.2 mSv). The collective annual (neutron) dose has tended to decrease since 1992, but incidentally high doses have been observed. Leaving these incidents out, the average collective annual neutron doses for the different users of neutron sources are about the same. (author)

  3. Performance of the EPD-N2 dosemeter for monitoring aircrew doses.

    Science.gov (United States)

    Scherpelz, R I; Cezeaux, J R

    2015-03-01

    United States Air Force (USAF) aircrew fly at altitudes and for durations where doses from cosmic radiation are significant enough to warrant monitoring. This study evaluated a candidate radiological monitoring system for USAF aircrew, the Thermo Scientific electronic personnel dosemeter (EPD-N2). The evaluation consisted of characterising the device in a well-characterised radiation field at a European Organization for Nuclear Research (CERN) accelerator, and aboard an USAF aircraft. The performance of the EPDs was evaluated by comparison with accepted values for dose at the CERN facility, comparison with the value calculated by flight dose software and comparison with the value estimated by a tissue-equivalent proportional counter aboard the aircraft. This study recommends that a correction factor of 1/CF = 1/3.9 be applied to EPD-N2 measurements aboard aircraft flights. The uncertainty in this correction factor is 11.8 %.

  4. Measurement analysis using the Fricke dosemeter; Analise de medicoes com o dosimetro Fricke

    Energy Technology Data Exchange (ETDEWEB)

    Pedrosa, G.A.C. [Instituto Nacional de Metrologia (INMETRO), Rio de Janeiro, RJ (Brazil)], e-mail: gcpedrosa@inmetro.gov.br; Dantas, C.C. [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Dept. de Energia Nuclear], e-mail: ccd@ufpe.br; Campos, C.A. [Centro Regional de Ciencias Nucleares do Nordeste (CRCN-NE/CNEN-PE), Recife, PE (Brazil)], e-mail: auster@elogica.com.br

    2003-07-01

    The Fricke dosemeter has been used for absolute determination of the radiation dose between 40 and 350 Gy for X-rays, Gamma rays and fast electrons energies. The great inconvenient of that dosimetric system is the impossibility of using for measurements of exposure or low dose rates. A Fricke dosimetry system was implanted at the Nuclear Sciences Regional Center (CRCN), in Recife, Pernambuco state, Brazil, for the determination of radiation doses for spectrometry and mass dosimetry with plasma source. The statistical analysis of the obtained results have shown that using the spectrometric method that system cna be used for maintenance of factors of CRCN standard calibrations and the dose assessment thru mail system of radiotherapy centers of the country.

  5. CHARACTERIZATION OF AN ACTIVE DOSEMETER ACCORDING TO IEC 61526:2010.

    Science.gov (United States)

    Cardoso, J; Santos, J A M; Santos, L; Alves, J G; Oliveira, C

    2016-09-01

    The active personal dosemeter, RaySafe i2, allows the measurement and record of Hp(10) in real time, every second, via wireless technology for real-time display on a portable computer and/or a local network. The system seems particularly attractive for individual monitoring at clinical facilities where high intensity and varying radiation fields may occur, as it enables the user to acknowledge and optimize the dose and dose rate values in real time for each procedure. Prior to its use, the system was characterized at the Metrology Laboratory of Ionizing Radiation of IST-LPSR aiming at the metrological characterization of the system in accordance with IEC 61526:2010 for metrological control purposes and to verify the technical specifications stated by the manufacturer.

  6. Thermoluminescent dosemeter in a X-ray diffractometer; Dosimetria termoluminiscente en un difractometro de rayos X

    Energy Technology Data Exchange (ETDEWEB)

    Mendoza A, D.; Gonzalez M, P.; Falcon B, T. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, Mexico D.F. (Mexico); Castano, V.M. [Instituto de Fisica, UNAM, Laboratorio Juriquilla, A.P. 1-1010, C.P. 76001, Queretaro (Mexico)

    1999-07-01

    In this work it was presented the results obtained of the dosimetry which was realized in a X-ray diffractometer for powders, trademark Siemens D5000, using the thermoluminescent signal generated by the X-rays in the commercial dosemeter TLD-100 of Harshaw, US. In according to the results obtained, the radiation quantity received by an analysed material in the diffractometer, will be proportional to exposure time and it can vary from unities until tenths of grays. These results are very outstanding when are analysed crystalline materials in a diffractometer, for knowing the present crystalline phases, mainly if these are highly sensitive to the ionizing radiation, as it is the case of the thermoluminescent materials. (Author)

  7. Determination of isodose curves in Radiotherapy using an Alanine/ESR dosemeter; Determinacion de curvas de isodosis en Radioterapia usando un dosimetro de Alanina/ESR

    Energy Technology Data Exchange (ETDEWEB)

    Chen, F.; Baffa, O.; Graeff, C.F.O. [Departamento de Fisica e Matematica. Universidade de Sao Paulo FFCLRP. 14040-901 Ribeirao Preto-SP (Brazil)

    1998-12-31

    It was studied the possible use of an Alanine/ESR dosemeter in the isodose curves mapping in normal treatments of Radiotherapy. It was manufactured a lot of 150 dosemeters with base in a mixture of D-L Alanine dust (80 %) and paraffin (20 %). Each dosemeter has 4.7 mm diameter and 12 mm length. A group of 100 dosemeters of the lot were arranged inside 50 holes of the slice 25 of the phantom Rando Man. The phantom irradiation was realized in two opposed projections (AP and PA) in Co-60 equipment. A group of 15 dosemeters was take of the same lot for obtaining the calibration curve in a 1-20 Gy range. After irradiation the signal of each dosemeter was measured in an ESR spectrometer operating in the X-band ({approx} 9.5 GHz) and the wideness of Alanine ESR spectra central line was correlated with the radiation dose. The wideness dose calibration curve resulted linear with a correlation coefficient 0.9996. The isodose curves obtained show a profile enough similar at comparing with the theoretical curves. (Author)

  8. Study of a selection of 10 historical types of dosemeter: variation of the response to Hp(10) with photon energy and geometry of exposure.

    Science.gov (United States)

    Thierry-Chef, I; Pernicka, F; Marshall, M; Cardis, E; Andreo, P

    2002-01-01

    An international collaborative study of cancer risk among workers in the nuclear industry is tinder way to estimate direetly the cancer risk following protracted low-dose exposure to ionising radiation. An essential aspect of this study is the characterisation and quantification of errors in available dose estimates. One major source of errors is dosemeter response in workplace exposure conditions. Little information is available on energy and geometry response for most of the 124 different dosemeters used historically in participating facilities. Experiments were therefore set up to assess this. using 10 dosemeter types representative of those used over time. Results show that the largest errors were associated with the response of early dosemeters to low-energy photon radiation. Good response was found with modern dosemeters. even at low energy. These results are being used to estimate errors in the response for each dosemeter type, used in the participating facilities, so that these can be taken into account in the estimates of cancer risk.

  9. Calorimetric low temperature detectors for heavy ion physics

    Energy Technology Data Exchange (ETDEWEB)

    Egelhof, P.; Kraft-Bermuth, S. [Gesellschaft fuer Schwerionenforschung mbH, Darmstadt (Germany)]|[Mainz Univ. (Germany). Inst. fuer Physik

    2005-05-01

    Calorimetric low temperature detectors have the potential to become powerful tools for applications in many fields of heavy ion physics. A brief overview of heavy ion physics at present and at the next generation heavy ion facilities is given with a special emphasis on the conditions for heavy ion detection and the potential advantage of cryogenic detectors for applications in heavy ion physics. Two types of calorimetric low temperature detectors for the detection of energetic heavy ions have been developed and their response to the impact of heavy ions was investigated systematically for a wide range of energies (E=0.1-360 MeV/amu) and ion species ({sup 4}He.. {sup 238}U). Excellent results with respect to energy resolution, {delta}E/E ranging from 1 to 5 x 10{sup -3} even for the heaviest ions, and other basic detector properties such as energy linearity with no indication of a pulse height defect, energy threshold, detection efficiency and radiation hardness have been obtained, representing a considerable improvement as compared to conventional heavy ion detectors based on ionization. With the achieved performance, calorimetric low temperature detectors bear a large potential for applications in various fields of basic and applied heavy ion research. A brief overview of a few prominent examples, such as high resolution nuclear spectroscopy, high resolution nuclear mass determination, which may be favourably used for identification of superheavy elements or in direct reaction experiments with radioactive beams, as well as background discrimination in accelerator mass spectrometry, is given, and first results are presented. For instance, the use of cryogenic detectors allowed to improve the sensitivity in trace analysis of {sup 236}U by one order of magnitude and to determine the up to date smallest isotope ratio of {sup 236}U/{sup 238}U = 6.1 x 10{sup -12} in a sample of natural uranium. Besides the detection of heavy ions, the concept of cryogenic detectors also

  10. Calorimetric study of tellurium rich Se-Te-Sn glasses

    Science.gov (United States)

    Heera, Pawan; Kumar, Anup; Jharwal, Manish; Sharma, Raman

    2016-05-01

    We report the calorimetric study of amorphous Se30Te70-x Snx alloys for x= 0, 1.5, 2.5, 4.5 in terms of kinetic parameters. The DSC curves recorded at four different heating rates are analyzed to determine the transition temperatures, activation energy, thermal stability, glass forming ability. The crystallization process has been investigated using Kissinger, Matusita, Augis and Bennett, and Gao and Wang models. Various kinetic parameters have been calculated for a better understanding of the growth mechanism. The glass transition temperatures Tg, onset crystallization Tc, peak crystallization Tp, and melting temperature Tm are found to increase with the increase in Sn content. The system under investigation is found to be thermally stable for at lower at% of Sn. The values of parameters HR, Hw, and S indicate that Glass forming ability (GFA) decays with an increase in Sn content.

  11. A Calorimetric Assay For Enzymatic Saccharification Of Biomass

    DEFF Research Database (Denmark)

    Murphy, Leigh; Borch, Kim; McFarland, K.C.;

    2010-01-01

    A limited selection of assay and screening methodologies for cellulolytic enzymes has been stated as a restriction in biomass research. In this report we test the potential of isothermal calorimetry for this purpose. The primary observable in this technique (the heat flow in Watts), scales...... with the rate of hydrolysis, and unlike other approaches, it provides a continuous picture of the hydrolytic rate. It was found that the activity of a standard enzyme cocktail against purified cellulose substrates and dilute acid pretreated corn stover (PCS) was readily detected in calorimeters of different...... types, and that the calorimetric signal scaled with the enzyme activity measured by established analytical techniques. Hence, it was concluded that the heat flow provided a valid measure of the hydrolytic rate also in a complex biomass. The hydrolysis process was consistently found to be exothermic...

  12. Preparation, structural, and calorimetric characterization of bicomponent metallic photonic crystals

    Science.gov (United States)

    Kozlov, M. E.; Murthy, N. S.; Udod, I.; Khayrullin, I. I.; Baughman, R. H.; Zakhidov, A. A.

    2007-03-01

    We report preparation and characterization of novel bicomponent metal-based photonic crystals having submicron three-dimensional (3D) periodicity. Fabricated photonic crystals include SiO2 sphere lattices infiltrated interstitially with metals, carbon inverse lattices filled with metal or metal alloy spheres, Sb inverse lattices, and Sb inverse lattices filled with Bi spheres. Starting from a face centered SiO2 lattice template, these materials were obtained by sequences of either templating and template extraction or templating, template extraction, and retemplating. Surprising high fidelity was obtained for all templating and template extraction steps. Scanning electron microscopy (SEM), small angle X-ray scattering (SAXS) and differential scanning calorimetry (DSC) were used to characterize the structure and the effects of the structure on calorimetric properties. To the best of our knowledge, SAXS data on metallic photonic crystals were collected for first time.

  13. Preparation, structural, and calorimetric characterization of bicomponent metallic photonic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Kozlov, M.E.; Baughman, R.H.; Zakhidov, A.A. [The University of Texas at Dallas, NanoTech Institute, Richardson, TX (United States); Murthy, N.S. [University of Vermont, Department of Physics, Burlington, VT (United States); Udod, I. [Teva Pharmaceuticals USA, Fairfield, NJ (United States); Khayrullin, I.I. [eMagin Corporation, Hopewell Junction, NY (United States)

    2007-03-15

    We report preparation and characterization of novel bicomponent metal-based photonic crystals having submicron three-dimensional (3D) periodicity. Fabricated photonic crystals include SiO{sub 2} sphere lattices infiltrated interstitially with metals, carbon inverse lattices filled with metal or metal alloy spheres, Sb inverse lattices, and Sb inverse lattices filled with Bi spheres. Starting from a face centered SiO{sub 2} lattice template, these materials were obtained by sequences of either templating and template extraction or templating, template extraction, and retemplating. Surprising high fidelity was obtained for all templating and template extraction steps. Scanning electron microscopy (SEM), small angle X-ray scattering (SAXS) and differential scanning calorimetry (DSC) were used to characterize the structure and the effects of the structure on calorimetric properties. To the best of our knowledge, SAXS data on metallic photonic crystals were collected for first time. (orig.)

  14. Calorimetric measurement and modelling of the equivalent series of capacitors

    Science.gov (United States)

    Seguin, B.; Gosse, J. P.; Ferrieux, J. P.

    1999-12-01

    The equivalent series resistance of polypropylene capacitors has been determined under rated voltage, in the range 1 kHz 1 MHz, between 220 K and 370 K by a calorimetric technique. The original feature of this determination of capacitor losses lies in the use of the isothermal calorimetry and in the measurement of an electrical power and not of a temperature increase. The frequency dependence of the equivalent series resistance, at various temperatures, enables to separate the losses in the conducting material from those in the dielectric and to get their respective variations as a function of frequency and temperature. These variations of the equivalent series resistance with frequency at a given temperature have been reproduced by using an equivalent circuit composed of resistors, inductors and capacitors. This model has been verified for non-sinusoidal waveforms such as those met with in a filtering circuit and is used to evaluate by simulation the losses of the capacitor.

  15. Comparison of neutron dose quantities and instrument and dosemeter readings at representative locations in an MOX fuel fabrication plant

    CERN Document Server

    Bartlett, D T; Tanner, R J; Haley, R M; Cooper, A J

    2002-01-01

    The relationships between operational and protection quantities, and values of personal dosemeter and instrument readings have been determined for a recently designed MOX fuel fabrication plant. The relationships between the quantities, and the readings of personal dosemeters are sensitive to both the energy and direction distribution of neutron fluence. The energy distributions were calculated using the Monte Carlo code MCBEND. The direction distribution was addressed by calculating independently, spectral components for which the direction distribution could be reasonably assumed. At representative locations, and for assumed worker orientations, the radiation field is analysed as having, in general, three components--a direct, unidirectional component from the nearest identified discrete source, which is considered incident A-P, several unidirectional components from other such sources which are treated as a rotational component and a scattered isotropic component. The calculated spectra were folded with co...

  16. Measurement of staff doses in interventional procedures using LiF TL-detectors and a special diode dosemeter

    Energy Technology Data Exchange (ETDEWEB)

    Parviainen, T.; Toivonen, M.; Kosunen, A.; Karppinen, J. [Radiation and Nuclear Safety Authority, Helsinki (Finland); Ylitalo, A. [Satakunta Central Hospital, Division for Cardiology, Pori (Finland)

    2003-06-01

    Personal doses vary considerably among the operational staff in cardiac examination procedures and interventions. Correspondingly, the fluoroscopy time may vary from a few minutes to more than 1 hour. Large personal doses in the range of 35 - 41 mSv were registered to some interventional radiologists and cardiologists in 2001 in Finland. Measurement of doses per intervention from hands, shoulders and ankles (parts of the body outside the lead apron) are therefore of interest, but small and highly sensitive dosemeters have not been commonly available for reliable and practical measurements. Thermoluminescent detectors of LiF:MgCu,P are sensitive enough, but residual luminescence from previous uses of detectors and the dose collected from natural background radiation between preparation for use and readout may be significant sources of uncertainty. The company Unfors Instrumens AB (Billdal, Sweden) has designed a light weight diode dosemeter with long cables between detectors and the electronic part for simultaneous measurement of doses from various parts of the body. The aim of this work is to report doses of the operating staff per a cardiac examination or intervention and study the capabilities of the diode dosemeter in staff dose measurements. (orig.)

  17. Extent-based incremental identification of reaction systems using concentration and calorimetric measurements

    OpenAIRE

    Srinivasan, Sriniketh; Bhatt, Nirav Pravinbhai; Billeter, Julien; Bonvin, Dominique

    2012-01-01

    Extent-based Incremental Model Identification (IMI) uses the concept of extent of reaction and the integral method of parameter estimation to identify reaction kinetics from transient concentration measurements. This study proposes to incorporate calorimetric measurements into the extent-based IMI approach. Calorimetric measurements are added to concentrationmeasurements for two main purposes: (i) to be able to estimate the reaction enthalpies when all the concentrations are measured, and (ii...

  18. Selection of the most appropriate two-dosemeter algorithm for estimating effective dose equivalent during maintenance periods in Korean nuclear power plants.

    Science.gov (United States)

    Kim, Hee Geun; Kong, Tae Young

    2010-07-01

    The application of a two-dosemeter system with its algorithm, as well as a test of its use in an inhomogeneous high-radiation field, is described in this study. The goal was to improve the method for estimating the effective dose equivalent during maintenance periods at Korean Nuclear Power Plants (NPPs). The use of this method in Korean and international NPPs, including those NPPs in the USA and Canada, was also investigated. The algorithms used by the the American National Standards Institute, Lakshmanan, the National Council on Radiation Protection and Measurements (NCRP), the Electric Power Research Institute and Kim were extensively analysed as two-dosemeter algorithms. Their possible application to NPPs was evaluated using data for each algorithm from two-dosemeter results that were obtained from an inhomogeneous high-radiation field during maintenance periods at Korean NPPs. The NCRP algorithm (55:50) was selected as an optimal two-dosemeter algorithm for Korean NPPs by taking into account the field test results and the convenience of wearing two dosemeters.

  19. Active personal dosemeters in interventional radiology: tests in laboratory conditions and in hospitals.

    Science.gov (United States)

    Clairand, I; Bordy, J-M; Daures, J; Debroas, J; Denozière, M; Donadille, L; Ginjaume, M; Itié, C; Koukorava, C; Krim, S; Lebacq, A-L; Martin, P; Struelens, L; Sans-Mercé, M; Tosic, M; Vanhavere, F

    2011-03-01

    The work package 3 of the ORAMED project, Collaborative Project (2008-11) supported by the European Commission within its seventh Framework Programme, is focused on the optimisation of the use of active personal dosemeters (APDs) in interventional radiology and cardiology (IR/IC). Indeed, a lack of appropriate APD devices is identified for these specific fields. Few devices can detect low-energy X rays (20-100 keV), and none of them are specifically designed for working in pulsed radiation fields. The work presented in this paper consists in studying the behaviour of some selected APDs deemed suitable for application in IR/IC. For this purpose, measurements under laboratory conditions, both with continuous and pulsed X-ray beams, and tests in real conditions on site in different European hospitals were performed. This study highlights the limitations of APDs for this application and the need of improving the APD technology so as to fulfil all needs in the IR/IC field.

  20. Study on the response of thermoluminescent dosemeters to synchrotron radiation: experimental method and Monte Carlo calculations.

    Science.gov (United States)

    Bakshi, A K; Chatterjee, S; Palani Selvam, T; Dhabekar, B S

    2010-07-01

    In the present study, the energy dependence of response of some popular thermoluminescent dosemeters (TLDs) have been investigated such as LiF:Mg,Ti, LiF:Mg,Cu,P and CaSO(4):Dy to synchrotron radiation in the energy range of 10-34 keV. The study utilised experimental, Monte Carlo and analytical methods. The Monte Carlo calculations were based on the EGSnrc and FLUKA codes. The calculated energy response of all the TLDs using the EGSnrc and FLUKA codes shows excellent agreement with each other. The analytically calculated response shows good agreement with the Monte Carlo calculated response in the low-energy region. In the case of CaSO(4):Dy, the Monte Carlo-calculated energy response is smaller by a factor of 3 at all energies in comparison with the experimental response when polytetrafluoroethylene (PTFE) (75 % by wt) is included in the Monte Carlo calculations. When PTFE is ignored in the Monte Carlo calculations, the difference between the calculated and experimental response decreases (both responses are comparable >25 keV). For the LiF-based TLDs, the Monte Carlo-based response shows reasonable agreement with the experimental response.

  1. EURADOS INTERCOMPARISONS ON WHOLE-BODY DOSEMETERS FOR PHOTONS FROM 2008 TO 2014.

    Science.gov (United States)

    Figel, Markus; Stadtmann, Hannes; Grimbergen, Tom W M; McWhan, Andrew; Romero, Ana M

    2016-09-01

    Starting in 2008 the European Dosimetry Group (EURADOS) has been performing international intercomparisons on photon whole-body dosemeters for individual monitoring services. These intercomparisons were organised (on a biannual basis) in 2008, 2010, 2012 and 2014, each time with a similar set-up but with small alterations in the subsequent irradiation plans. With an increasing number of participants and participating systems, this intercomparison action has become an important tool for individual monitoring services to test their whole-body dosimetry systems, compare their results with other services or systems and to improve the quality of their dosimetry. The paper presents and compares the results of these four intercomparisons and compares the dosimetric results for the participating system types. Major dosimetric problems of the individual monitoring services are identified, and trends in the dosimetric performance of the different systems are shown. This gives the opportunity to identify some dosimetry issues that should be improved by application of the monitoring services' quality assurance systems and QA procedures.

  2. Structure and chemistry of coals: calorimetric analyses. [Wetting heat

    Energy Technology Data Exchange (ETDEWEB)

    ,

    1979-01-01

    Heats of immersion (h/sub i/) of coals have been shown to be a valuable means of investigating structure and chemistry of coals. This report outlines some of the factors involved. Lower ranked coals imbibe more liquids (i.e., H/sub 2/O) onto more polar sites (carbonyl, phenolic, etc.) than higher ranked coals. Mineral matter reacts strongly with polar liquids (i.e., H/sub 2/O) giving rise to enhanced h/sub i/. Grinding of coals not only decreases particle size but modifies the coal structure to an increasing degree dependent upon the extent and severity of grinding. The magnitude of h/sub i/ and the rate of reaction are both modified consistent with the existence of a shrinking core or unperturbed coal structure serving as substrate to which the modified (less ordered) material is bound. Chemical (alkali) attack seems to loosen the coal structure markedly to allow enhanced access to fluid reagents. These exploratory studies have shown that calorimetric analyses similar to those developed and used by A.C. Zettlemoyer and his coworkers are excellent means for elucidating the structure and chemistry of coals and related materials.

  3. The Calorimetric Glass Transition of Polystyrene Ultrathin Films

    Science.gov (United States)

    Gao, Siyang; Koh, Yung; Simon, Sindee; Texas Tech University Team

    2013-03-01

    The glass transition temperature (Tg) for nanoconfined materials have been widely studied since the early 1990s. For supported polystyrene ultrathin films, Tg differs from bulk value. Recent work has attributed nanoconstrained Tg effects to artifact. In this study, we attempted to resolve this controversy and measure Tg for single polystyrene ultrathin films using Flash DSC. Films have been prepared in two ways: spincast films placed on a layer of inert oil or grease and films directly spincast on the back of the calorimetric chip. For the films on oil or on grease, the 160 nm thick films show no Tg depression. On the other hand, thinner films on oil and on grease show a Tg depression which decreases with increasing cooling rate. The depression reverts to the bulk values over the course of a day at 160 °C due to dewetting and thickening. For directly spincast films, no Tg depression is observed, consistent with results from other nanocalorimetry work. Our results are consistent with literature results that Tg decreases with decreasing substrate surface energy, and they also demonstrate that the Tg depression observed is not due to degradation or to plasticization effects.

  4. Effect of the energy dependence of response of neutron personal dosemeters routinely used in the UK on the accuracy of dose estimation

    CERN Document Server

    Tanner, R J; Thomas, D J

    2002-01-01

    A large set of neutron energy distributions have been classified by workplace to provide a guide to the neutron fields to which workers in particular industries are likely to be exposed. These have been combined (folded) with the results of a major programme of neutron personal dosemeter response function measurements, to provide results for the systematic errors that those dosemeters would give in workplaces. Data for neutron doses recorded for UK classified workers have been taken from the CIDI tables, and related to the results from the folding process. It has hence been possible to draw conclusions about the probable systematic errors that result from the use of the currently available neutron personal dosemeters, which have inherent problems associated with their energy dependence of response.

  5. Study of teflon pads as high doses dosemeters; Estudo de pastilhas de teflon como dosimetros de doses altas

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira, Maria Ines; Caldas, Linda V.E., E-mail: miteixeira@ipen.br, E-mail: lcaldas@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2013-11-01

    The aim of this work is to study the Teflon, which is used as a binder in the manufacture of dosimetric tablets, for the feasibility of this material as high dose dosemeter. In this paper we used the technique of thermally stimulated luminescence (OSL) to characterize the dosimetric properties of Teflon. Teflon samples were exposed to different doses of radiation, using a source of gamma radiation ({sup 60}Co). It was obtained dose-response curve between 100 Gy to 50 kGy and reproducibility of OSL response. The preliminary results show that Teflon is a useful material to high dose dosimetry.

  6. Some problems in adsorption and calorimetric studies of the steps of catalytic processes

    Institute of Scientific and Technical Information of China (English)

    Victor E. Ostrovskii

    2004-01-01

    Principal side factors as well as technical and procedural peculiarities capable of distorting the results of measurements of adsorbed and desorbed amounts, of falsifying the nature of the processes proceeding in the systems under study, and of promoting artifacts in calorimetric and other studies of gas chemisorption on powders are considered. Modified techniques and procedures allowing the elimination of sources of side phenomena and artifacts and freeing traditional glass static adsorption apparatuses and experimental procedures from undesirable factors and peculiarities are proposed.Some available chemisorption and calorimetric data representing artifacts and also some data that are not artifacts but,due to imperfections of chemisorption techniques, show up as artifacts are presented and discussed. Several applications of the improved techniques and procedures to calorimetric and adsorption studies of the steps of catalytic processes proceeding on the basis of natural gas and of products of its processing are presented and discussed.

  7. Modeling protein density of states: additive hydrophobic effects are insufficient for calorimetric two-state cooperativity.

    Science.gov (United States)

    Chan, H S

    2000-09-01

    A well-established experimental criterion for two-state thermodynamic cooperativity in protein folding is that the van't Hoff enthalpy DeltaH(vH) around the transition midpoint is equal, or very nearly so, to the calorimetric enthalpy DeltaH(cal) of the entire transition. This condition is satisfied by many small proteins. We use simple lattice models to provide a statistical mechanical framework to elucidate how this calorimetric two-state picture may be reconciled with the hierarchical multistate scenario emerging from recent hydrogen exchange experiments. We investigate the feasibility of using inverse Laplace transforms to recover the underlying density of states (i.e., enthalpy distribution) from calorimetric data. We find that the constraint imposed by DeltaH(vH)/DeltaH(cal) approximately 1 on densities of states of proteins is often more stringent than other "two-state" criteria proposed in recent theoretical studies. In conjunction with reasonable assumptions, the calorimetric two-state condition implies a narrow distribution of denatured-state enthalpies relative to the overall enthalpy difference between the native and the denatured conformations. This requirement does not always correlate with simple definitions of "sharpness" of a transition and has important ramifications for theoretical modeling. We find that protein models that assume capillarity cooperativity can exhibit overall calorimetric two-state-like behaviors. However, common heteropolymer models based on additive hydrophobic-like interactions, including highly specific two-dimensional Gō models, fail to produce proteinlike DeltaH(vH)/DeltaH(cal) approximately 1. A simple model is constructed to illustrate a proposed scenario in which physically plausible local and nonlocal cooperative terms, which mimic helical cooperativity and environment-dependent hydrogen bonding strength, can lead to thermodynamic behaviors closer to experiment. Our results suggest that proteinlike thermodynamic

  8. About the measurements systems with pen and thermoluminescent dosemeters; Sobre los sistemas de medicion con dosimetros de pluma y los termoluminiscentes

    Energy Technology Data Exchange (ETDEWEB)

    Cortes I, M.E.; Ramirez G, F.P. [Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152. 07730 Mexico D.F. (Mexico)

    1998-12-31

    In this work it is presented dosimetric data obtained with pen and thermoluminescent dosemeters, which are used by the Occupational Exposure Personnel (OEP) of the Mexican Petroleum Institute (IMP)(1). It was marked several great characteristics as for example, the differences among units which use one and another dosemeter type. Likewise, it is given to know diverse problems that were had in the IMP at relating the data obtained with these dosemeters (which utilizes OEP) and the ICRP 60 recommendations 1990. One of the most important difficulties is to satisfy the recommended limits by ICRP, particularly those that are referring to the units and their complex calculations. With respect to the unities, the ICRP makes reference at the concepts `dose equivalent` and `effective dose` with the sievert unit, that the General Regulations for Radiological Safety associates with `dose equivalent` and `effective dose equivalent`. It was illustrated the type of dosimetric statistics which are obtained with the TLD lectures and a OEP pen dosemeter during 1997. (Author)

  9. Classification of calorimetric titration plots for alkyltrimethylammonium and alkylpyridinium cationic surfactants in aqueous solutions

    NARCIS (Netherlands)

    Bijma, K; Engberts, J.B.F.N.; Blandamer, M.J; Cullis, P.M.; Last, P.M.; Irlam, K.D.; Soldi, L.G.

    1997-01-01

    Calorimetric titration plots for deaggregation of micelles formed by alkylpyridinium and alkyltrimethylammonium surfactants are classified into three types, A, B and C, depending on the shape of the plot of the enthalpy of dilution as a function of surfactant concentration. For Type A plots the reco

  10. Integrated calorimetric microreactor in low-temperature cofired ceramic (LTCC) technology

    OpenAIRE

    Maeder, Thomas; Willigens, Raphaël; Fournier, Yannick; Ryser, Peter

    2006-01-01

    Object of this work 1) Explore the feasibility of an LTCC microreactor • Chemical stability: compatible with HCl, NaOH, ... • Thermal stability to >100°C 2) Achieve a high degree of integration • Temperature measurement • Reactant flow measurement • Temperature control • Calorimetric chamber

  11. A calorimetric study of solute effects on the kinetic stability of a-amylase

    DEFF Research Database (Denmark)

    Olsen, Søren Nymand; Andersen, Kim Bruno; Øgendal, Lars Holm;

    2009-01-01

    In this study we evaluated the applications of isothermal titration calorimetry (ITC) to Study solute effects on the kinetics of irreversible protein denaturation. More specifically, denaturation of Bacillus Halmapalus alpha-amylase (BHA) was initiated by addition of EDTA to the calorimetric cell...

  12. Analytical and experimental characterization of a miniature calorimetric sensor in a pulsatile flow

    NARCIS (Netherlands)

    Gelderblom, H.; Horst, van der A.; Haartsen, J.R.; Rutten, M.C.M.; Ven, van de A.A.F.; Vosse, van de F.N.

    2010-01-01

    The behaviour of a miniature calorimetric sensor, which is under consideration for catheter-based coronary-artery-flow assessment, is investigated in both steady and pulsatile tube flows. The sensor is composed of a heating element operated at constant power and two thermopiles that measure flow-ind

  13. TL response of LiF: Mg, Cu, P dosemeters in function of the photon energy; Respuesta TL de dosimetros de LiF: Mg, Cu, P en funcion de la energia del foton

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, P.R. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico); Azorin, J. [UAM-I, 09340 Mexico D.F. (Mexico); Furetta, C. [Universita degli Studi di Roma ' La Sapienza' , Piazzale Aldo Moro 2, 00185 Roma (Italy)

    2005-07-01

    In this work the obtained results of studying the response of dosemeters of LiF: Mg, Cu, P + Ptfe, developed in the ININ, commercial dosemeters GR200A (LiF: Mg, Cu, P) of chinese manufacture and TLD-100 (LiF: Mg, Ti) US are presented, when irradiating them with X rays 16, 24, 34.5, 42, 100 and 145 keV of effective energy, with gamma rays of 662 keV ({sup 137} Cs) and 1252 keV ({sup 60} Co). The results are presented in function of the sensitivity that the dosemeters showed normalized to gamma radiation of {sup 60} Co. It was appreciated that the dosemeters more equivalent to the tissue, they were those of LiF: Mg, Cu, P + Ptfe, while the less equivalent ones were the TLD-100. (Author)

  14. Use of active dosemeters as a optimization tool in hemodynamics; Uso de dosimetros ativos como ferramenta de otimizacao em hemodinamica

    Energy Technology Data Exchange (ETDEWEB)

    Nunes, Rafael; Pereira, Dirceu D. [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil). Inst. de Fisica; Canevaro, Lucia V. [Instituto de Radioprotecao e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil); Rodrigues, Barbara B.D. [Comissao Nacional de Energia Nuclear (CNEN), Rio de Janeiro, RJ (Brazil); Ferreira, Esmeralci [Universidade do Estado do Rio de Janeiro (UERJ), Rio de Janeiro, RJ (Brazil). Faculdade de Medicina. Servico de Hemodinamica

    2016-07-01

    Interventional cardiology procedures are, in general, associated with high doses in patients and professionals. The objective of this study is to measure the radiation levels received by professionals .The professional dosimetry was performed in a department of Hemodynamics of University Hospital in Rio de Janeiro. were followed 331 coronary angiography (CA) and 26 percutaneous transluminal coronary angioplasty (PTCA) procedures. For this, were used active dosemeters to measure the radiation levels at the chest of interventional professionals. The results show that average personal equivalent dose of doctors, per procedure was 100 e 154 μSv. On average, nursing technicians and radiologist receive 12 and 10% of doses of physicians, respectively, during CA procedures. From the results, it appears that the doses of hemodynamics exceed the annual dose limit of the standards. The use of lead shielding is presented as an effective action to reduce doses in these workers. (author)

  15. Performance of the electronic personal dosemeter for neutron 'Saphydose-N' at different workplaces of nuclear facilities.

    Science.gov (United States)

    Lahaye, T; Chau, Q; Ménard, S; Lacoste, V; Muller, H; Luszik-Bhadra, M; Reginatto, M; Bruguier, P

    2006-01-01

    This paper mainly aims at presenting the measurements and the results obtained with the electronic personal neutron dosemeter Saphydose-N at different facilities. Three campaigns were led in the frame of the European contract EVIDOS ('Evaluation of Individual Dosimetry in Mixed Neutron and Photon Radiation Fields'). The first one consisted in the measurements at the IRSN French research laboratory in reference neutron fields generated by a thermal facility (SIGMA), radionuclide ISO sources ((241)AmBe; (252)Cf; (252)Cf(D(2)O)\\Cd) and a realistic spectrum (CANEL/T400). The second one was performed at the Krümmel Nuclear Power Plant (Germany) close to the boiling water reactor and to a spent fuel transport cask. The third one was realised at Mol (Belgium), at the VENUS Research Reactor and at Belgonucléaire, a fuel processing factory.

  16. Absorbed dose measurements in mammography using Monte Carlo method and ZrO{sub 2}+PTFE dosemeters

    Energy Technology Data Exchange (ETDEWEB)

    Duran M, H. A.; Hernandez O, M. [Departamento de Investigacion en Polimeros y Materiales, Universidad de Sonora, Blvd. Luis Encinas y Rosales s/n, Col. Centro, 83190 Hermosillo, Sonora (Mexico); Salas L, M. A.; Hernandez D, V. M.; Vega C, H. R. [Unidad Academica de Estudios Nucleares, Universidad Autonoma de Zacatecas, Cipres 10, Fracc. La Penuela, 98068 Zacatecas (Mexico); Pinedo S, A.; Ventura M, J.; Chacon, F. [Hospital General de Zona No. 1, IMSS, Interior Alameda 45, 98000 Zacatecas (Mexico); Rivera M, T. [Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada, IPN, Av. Legaria 694, Col. Irrigacion, 11500 Mexico D. F.(Mexico)], e-mail: hduran20_1@hotmail.com

    2009-10-15

    Mammography test is a central tool for breast cancer diagnostic. In addition, programs are conducted periodically to detect the asymptomatic women in certain age groups; these programs have shown a reduction on breast cancer mortality. Early detection of breast cancer is achieved through a mammography, which contrasts the glandular and adipose tissue with a probable calcification. The parameters used for mammography are based on the thickness and density of the breast, their values depend on the voltage, current, focal spot and anode-filter combination. To achieve an image clear and a minimum dose must be chosen appropriate irradiation conditions. Risk associated with mammography should not be ignored. This study was performed in the General Hospital No. 1 IMSS in Zacatecas. Was used a glucose phantom and measured air Kerma at the entrance of the breast that was calculated using Monte Carlo methods and ZrO{sub 2}+PTFE thermoluminescent dosemeters, this calculation was completed with calculating the absorbed dose. (author)

  17. Use of a robotic manipulator in the simulation of the automation of a calibration process of dosemeters; Uso de un manipulador robotico en la simulacion de la automatizacion de un proceso de calibracion de dosimetros

    Energy Technology Data Exchange (ETDEWEB)

    Benitez R, J.S.; Najera H, M.C. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2002-07-01

    The development of a system based in a manipulative robot which simulates the operative sequence in a calibration process of dosemeters is presented. In this process it is performed the monitoring of the dosemeter positions and the calibrator by mean of an arm of articulated robot which develops the movement sequences and the taking a decision based on the information coming from the external sensors. (Author)

  18. Methodology for Mixed Field Inhalation Dosimetry in Monazite Areas using a Twin-Cup Dosemeter with Three Track Detectors

    Energy Technology Data Exchange (ETDEWEB)

    Mayya, Y.S.; Eappen, K.P.; Nambi, K.S.V

    1998-07-01

    A methodology is proposed for estimating the gas and potential alpha energy concentrations (PAECs), and inhalation dose rates due to a mixed field of radon, thoron and their progeny present in the indoor atmosphere, using a radon-thoron discriminating dosemeter having three solid state nuclear track detectors (SSNTDs). The gas concentrations present in the vicinity of the dosemeter are directly measured through SSNTDs exposed in the 'cup mode'. The bare track density rates are related to the gas and the progeny concentrations by incorporating ventilation rate dependent spatial profiles for thoron gas. The ventilation rate is extracted as a real positive root of the governing equation and from this, the PAECs as well as the inhalation dose rates are estimated through the use of standard formulae. Error estimates on the dose rates have been carried out. Analyses of the field data from a sample survey of 35 houses situated in monazite bearing high background radiation areas of Kerala indicate that the methodology works successfully in a majority of the cases. Results for 22 cases which showed less than 100% statistical error are presented. These show median values of about 4.8 Bq.m{sup -3} and 462 Bq.m{sup -3} for radon and room averaged thoron concentrations, 0.5 mWL and 129 mWL for radon progeny and thoron progeny PAECs, and 1.21 {mu}Sv.h{sup -1} for inhalation dose rate. Although a complete picture would emerge only at the end of the ongoing large scale survey, the sample survey already indicates that indoor thoron levels in the Kerala monazite area are the highest reported so far in the literature. (author)

  19. A fibre optic scintillator dosemeter for absorbed dose measurements of low-energy X-ray-emitting brachytherapy sources.

    Science.gov (United States)

    Sliski, Alan; Soares, Christopher; Mitch, Michael G

    2006-01-01

    A newly developed dosemeter using a 0.5 mm diameter x 0.5 mm thick cylindrical plastic scintillator coupled to the end of a fibre optic cable is capable of measuring the absorbed dose rate in water around low-activity, low-energy X-ray emitters typically used in prostate brachytherapy. Recent tests of this dosemeter showed that it is possible to measure the dose rate as a function of distance in water from 2 to 30 mm of a (103)Pd source of air-kerma strength 3.4 U (1 U = 1 microGy m(2) h(-1)), or 97 MBq (2.6 mCi) apparent activity, with good signal-to-noise ratio. The signal-to-noise ratio is only dependent on the integration time and background subtraction. The detector volume is enclosed in optically opaque, nearly water-equivalent materials so that there is no polar response other than that due to the shape of the scintillator volume chosen, in this case cylindrical. The absorbed dose rate very close to commercial brachytherapy sources can be mapped in an automated water phantom, providing a 3-D dose distribution with sub-millimeter spatial resolution. The sensitive volume of the detector is 0.5 mm from the end of the optically opaque waterproof housing, enabling measurements at very close distances to sources. The sensitive detector electronics allow the measurement of very low dose rates, as exist at centimeter distances from these sources. The detector is also applicable to mapping dose distributions from more complex source geometries such as eye applicators for treating macular degeneration.

  20. Evaluation of neutron doses received at different organs in radiotherapy treatments using the UAB PADC based dosemeters in an anthropomorphic phantom

    Energy Technology Data Exchange (ETDEWEB)

    Domingo, C., E-mail: carles.domingo@uab.ca [Grup de Fisica de les Radiacions, Departament de Fisica, Edifici C, Universitat Autonoma de Barcelona, E-08193 Bellaterra (Spain); Garcia-Fuste, M.J.; Morales, E.; Amgarou, K.; Castelo, J. [Grup de Fisica de les Radiacions, Departament de Fisica, Edifici C, Universitat Autonoma de Barcelona, E-08193 Bellaterra (Spain); Sanchez-Doblado, F. [Hospital Universitario Virgen Macarena, Servicio de Radiofisica, Sevilla (Spain); Departamento de Fisiologia Medica y Biofisica, Facultad de Medicina, Universidad de Sevilla (Spain)

    2009-10-15

    The NEUTOR project was set up to study radiotherapy patient exposures to the neutrons produced around the LINAC accelerator head by photon radiation above approx8 MeV. These neutrons may reach the patient directly, or they may interact with the surrounding materials until they become thermalised, scattering all over the treatment room and affecting the patient as well. A miniaturised version of the UAB PADC based neutron dosemeter is used, together with thermoluminescence Li-6/Li-7 pairs, in several positions inside an anthropomorphic female phantom to determine doses received by the patient at several organs or tissues. Irradiations were made at a 15 MV LINAC (Hospital Universitario Virgen de la Macarena, Sevilla, Spain), an 18 MV LINAC (Hospital General Universitario de Valencia, Spain) and a 23 MV LINAC (Universitaetsklinikum Heidelberg, Germany). Preliminary patient dose maps obtained from the UAB PADC dosemeter measurements (considering an average calibration factor for all neutron energies) are reported in this work.

  1. Changes in the Calorimetric Value and Ignition Temperature of Composite Solid Propellants During Ageing-A Note

    Directory of Open Access Journals (Sweden)

    K. Kishore

    1986-10-01

    Full Text Available Calorimetric value and ignition temperature of carboxy terminated polybutadiene/ammonium perchlorate propellant decrease during accelerated ageing. The behaviour has been explained on account of binder loss and condensed phase reactions in the propellant matrix.

  2. Determination of the dose index in computerized tomography using thermoluminescent dosemeters; Determinacion del indice de dosis en tomografia computada usando dosimetros termoluminiscentes

    Energy Technology Data Exchange (ETDEWEB)

    Azorin, J.C.; Calderon, A. [Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada-IPN, 11500 Mexico D.F. (Mexico); Azorin, J. [UAM-I, 09340 Mexico D.F. (Mexico)

    2004-07-01

    In this work the obtained results of the determination of the dose index are presented in thorax studies in computed tomography and helical tomography carried out in Mexico using thermoluminescent dosemeters of LiF: Mg,Cu,P + Ptfe developed and manufactured in our country. The results showed that under similar conditions of irradiation and operation (pitch = 1), significant differences don't exist among the doses absorbed measures in the phantom due to the two types of used tomographs. (Author)

  3. Calorimetric study of hydrogen interaction with Sm{sub 2}Fe{sub 17}

    Energy Technology Data Exchange (ETDEWEB)

    Anikina, E.Yu., E-mail: anikina@hydride.chem.msu.ru [Lomonosov Moscow State University, Chemical Department, Moscow 119991 (Russian Federation); Verbetsky, V.N. [Lomonosov Moscow State University, Chemical Department, Moscow 119991 (Russian Federation); Savchenko, A.G.; Menushenkov, V.P.; Shchetinin, I.V. [National University of Science and Technology “MISiS”, 119049 Moscow, Leninskiy prospekt 4, MISiS (Russian Federation)

    2015-10-05

    Highlights: • Sm{sub 2}Fe{sub 17}−H{sub 2} system was studied by calorimetric method for the first time. • Change of partial molar enthalpies vs. hydrogen concentration was obtained. • Assumption about order of filling the interstitial site by hydrogen atoms was made. - Abstract: For the first time hydrogen interaction with Sm{sub 2}Fe{sub 17} was studied by means of calorimetric method with applying of the Tian–Calvet type calorimeter at 200 and 250 °C. The processes of hydrogen absorption and desorption were carried out and pressure–composition isotherms for the Sm{sub 2}Fe{sub 17}−H{sub 2} system and enthalpy change with hydrogen concentration in the metallic matrix were obtained. On the base of collected data supposition about order of filling the interstitial site by hydrogen atoms was made.

  4. Comparing calorimetric and dielectric polarization modes in viscous 2-ethyl-1-hexanol.

    Science.gov (United States)

    Huth, Heiko; Wang, Li-Min; Schick, Christoph; Richert, Ranko

    2007-03-14

    Dielectric relaxation and dynamic heat capacity measurements are compared for 2-ethyl-1-hexanol near its glass transition temperature Tg in order to further clarify the origin of the prominent Debye-type loss peak observed in many monohydroxy alcohols and other hydrogen-bonding liquids. While the dielectric spectrum epsilon" displays two distinct polarization processes that are separated by a factor of 2000 in terms of the peak frequency, the heat capacity cp" shows only a single peak. The dielectric process with lower amplitude and higher peak frequency coincides with the calorimetric signal, whereas the large dielectric Debye signal is not associated with calorimetric modes. The authors conclude that the Debye process corresponds to a transition among states which differ in energy only in the case of an external electric field.

  5. Micro-calorimetric sensor for vapour phase explosive detection with optimized heat profile

    OpenAIRE

    2009-01-01

    A heater design, used in a micro-calorimetric sensor, has been optimized for temperature uniformity and the sensor has been used for detection of trace amounts of explosives. In this abstract the design, characterization and functionality is described. The performance of the novel heater design is characterized by measuring the temperature coefficient of resistivity (TCR) values and by mapping the temperature distribution using Raman spectroscopy. The new heater design has increased the tempe...

  6. A Simple Practical Method for Calculating the Calorimetric Properties of Combustion Gas

    OpenAIRE

    1980-01-01

    The simplified formulae are proposed for the enthalpy and the entropy of combustion gas constituents, by treating each gas constituent as semi-ideal gas. Based on these formulae, there is shown the practical method for calculating directly the calorimetric properties of combustion gas and the adiabatic combustion temperature. This method allows one to analyse the heat processes of combustion gas within the error approvable for practical use and also with practical simplicity. Some calculated ...

  7. Calorimetric examination of mixtures for modification of nickel and cobalt superalloys

    OpenAIRE

    F. Binczyk; J. Sleziona; R. Przeliorz

    2009-01-01

    The study presents the results of thermodynamic calculations and calorimetric examination of thermal reactions taking place at hightemperatures between the nanoparticle inoculants and metallic constituents of nickel and cobalt superalloys. The calculations andmeasurements were made for different compositions, containing cobalt aluminate CoAl2O4, cobalt oxide CoO*Co2O3, zircon flourZrSi2O4, powdered and metallic Al, powdered Ti, and IN-713C alloy. The obtained results have indicated the possib...

  8. The development of a continuous isothermal titration calorimetric method for equilibrium studies.

    Science.gov (United States)

    Markova, Natalia; Hallén, Dan

    2004-08-01

    A continuous isothermal titration calorimetry (cITC) method for microcalorimeters has been developed. The method is based on continuous slow injection of a titrant into the calorimetric vessel. The experimental time for a cITC binding experiment is 12-20 min and the number of data points obtained is on the order of 1000. This gives an advantage over classical isothermal titration calorimetry (ITC) binding experiments that need 60-180 min to generate 20-30 data points. The method was validated using two types of calorimeters, which differ in calorimetric principle, geometry, stirring, and way of delivering the titrant into the calorimetric vessel. Two different experimental systems were used to validate the method: the binding of Ba(2+) to 18-crown-6 and the binding of cytidine 2'-monophosphate to RNAse A. Both systems are used as standard test systems for titration calorimetry. Computer simulations show that the dynamic range for determination of equilibrium constants can be increased by three orders of magnitude compared to that of classical ITC, making it possible to determine high affinities. Simulations also show an improved possibility to elucidate the actual binding model from cITC data. The simulated data demonstrate that cITC makes it easier to discriminate between different thermodynamic binding models due to the higher density of data points obtained from one experiment.

  9. Use of calorimetric assay for operational and accountability measurements of pure plutonium metal

    Energy Technology Data Exchange (ETDEWEB)

    Cremers, Teresa L [Los Alamos National Laboratory; Sampson, Thomas E [Los Alamos National Laboratory

    2010-01-01

    Plutonium pure metal products (PMP) are high purity plutonium metal items produced by electrorefining. The plutonium metal is produced as an approximately 3-kg ring. Accountability measurements for the electro-refining runs are typically balance/weight factor (incoming impure metal), chemistry (pure metal rings), and calorimetric assay or neutron counting of the crucibles and other wastes. The PMP items are qualified for their end use by extensive chemical assay. After PMP materials are made they are often sent to the vault for storage before being sent to the casting process, the next step in the production chain. The chemical assay of PMP items often takes a few weeks; however, before the metal items are allowed into the vault they must be measured. Non-destructive assay personnel measure the metals either by multiplicity neutron counting or calorimetric assay, depending on which instrument is available, thus generating comparisons between non-destructive assay and chemical assay. The suite of measurements, calorimetric assay, chemical assay, and neutron mUltiplicity counting is compared for a large group of PMP items.

  10. Tl response of LiF: Mg, Cu, P + PTFE (Mexico) and GR200A (China) dosemeters; Respuesta Tl de dosimetros de LiF: Mg, Cu, P + PTFE (Mexico) y GR200A (China)

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez M, P.R. [ININ, A.P. 18-1027, Mexico D.F. (Mexico); Azorin N, J.; Furetta, C. [UAM-I, 09340 Mexico D.F. (Mexico)

    2003-07-01

    TLD-100 was the commercial dosemeter more known since some decades ago. This dosemeter was considered for many research groups as the reference material for developing new Tl materials for ionizing radiation dosimetry. Actually it seems that TLD-100 is going to be replaced by the Chinese material GR200A, as reference material due that this material in addition to be considered as a tissue equivalent material, is 30 to 35 times more sensitive that TLD- 100. Results of the study of the Tl response of LiF: Mg, Cu, P + Ptfe developed at ININ-Mexico, comparing them with those of GR200A are presented. These results showed that the sensitivity (s = Tl intensity/weight x dose) to gamma radiation of the LiF: Mg, Cu, P + Ptfe dosimeters was 4.34 meanwhile that of the commercial dosemeter was 3.41. Detection threshold of the dosemeters studied was 2.22 and 0.52 {mu}Gy respectively Repeatability after 10 cycles Irradiation-reading-annealing was {+-}1.39% and {+-}1.86% respectively. Both types of dosemeters presented a linear response as a function of gamma radiation in the range from 0.02 mGy and 100 Gy. (Author)

  11. Measurement of doses to aviator pilots using thermoluminescent dosemeters; Medicion de la dosis a pilotos aviadores usando dosimetros termoluminiscentes

    Energy Technology Data Exchange (ETDEWEB)

    Azorin N, J.; Cruz C, D. [UAM-I, 09340 Mexico D.F. (Mexico); Rivera M, T. [IPN, ESIME Culhuacan (Mexico)]. e-mail: azorin@xanum.uam.mx

    2004-07-01

    During the development of their work, the aviator pilots are exposed at high levels of natural radiation of bottom caused mainly by the cosmic radiation of galactic origin and lot. For such reason, the Metropolitan Autonomous University (UAM) and the Union Association of Aviator Pilots (ASPA), subscribed an agreement with the purpose of to measure the doses of ionizing radiation received by the aviator pilots of diverse air companies that man different types of airships and to determine if these doses surpass the one limit of 0.11 mSv/h settled down by the IAEA for the public in general; and if therefore, these workers should be considered as personnel occupationally exposed. In this work the obtained results when measuring the absorbed dose received by Mexican civil aviator pilots during the development of their work, using thermoluminescent dosemeters of LiF:Mg,Cu,P + Ptfe of national production are presented. The obtained results during the years of 2001 and 2002 show that the monthly doses received by the pilots surpass the one it limits established for the public in general, for what they should be considered as personnel occupationally exposed. (Author)

  12. The former tests realized to a personal neutron dosemeter based on solid nuclear tracks detector; Primeras pruebas realizadas a un dosimetro personal de neutrones basado en detectores solidos de trazas nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Camacho, M.E.; Tavera, L.; Balcazar, M. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1997-07-01

    Due to the increase in the use of neutron radiation a personal neutron dosemeter based on solid nuclear tracks detector (DSTN) was designed and constructed. The personal dosemeter design consists of three arrangements. The first one consists of a plastic nuclear tracks detector (LR115 or CR39) in contact with a LiF pellet. The second one is the same that above but it placed among two cadmium pellets and, the third one is formed by the alone detector without converter neither neutron absorber. The three arrangements are placed inside a plastic porta detector hermetically closed to avoid the bottom produced by environmental radon whichever both detectors (LR115 and CR39) are sensitive. In this work the former tests realized to that dosemeter are presented. (Author)

  13. Nanowell-patterned TiO{sub 2} microcantilevers for calorimetric chemical sensing

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Dongkyu, E-mail: dongkyu@ualberta.ca; Chae, Inseok; Thundat, Thomas [Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 2V4 (Canada); Kim, Seonghwan [Department of Mechanical and Manufacturing Engineering, University of Calgary, Calgary, Alberta T2N 1N4 (Canada); Jeon, Sangmin [Department of Chemical Engineering, Pohang University of Science and Technology, Pohang (Korea, Republic of)

    2014-04-07

    A sensitive calorimetric sensor using a TiO{sub 2} microcantilever with nanowells patterned on one of its sides is described. This single material cantilever is sensitive to temperature change without relying on the metal deposition-based bimetallic effect. The thermomechanical sensitivity originates from the structure dependent variations in both the elastic modulus and thermal expansion coefficient due to the presence of ordered nanowells. These cantilever beams offer an alternate and efficient chemical sensing route for vapor phase analytes using photothermal spectroscopy. Selective and sensitive detection of organophosphorus compounds, as well as their photocatalytic decomposition under ultraviolet light exposure are demonstrated.

  14. The interaction of new piroxicam analogues with lipid bilayers--a calorimetric and fluorescence spectroscopic study.

    Science.gov (United States)

    Maniewska, Jadwiga; Szczęśniak-Sięga, Berenika; Poła, Andrzej; Sroda-Pomianek, Kamila; Malinka, Wiesław; Michalak, Krystyna

    2014-01-01

    The purpose of the present paper was to assess the ability of new piroxicam analogues to interact with the lipid bilayers. The results of calorimetric and fluorescence spectroscopic experiments of two new synthesized analogues of piroxicam, named PR17 and PR18 on the phase behavior of phospholipid bilayers and fluorescence quenching of fluorescent probes (Laurdan and Prodan), which molecular location within membranes is known with certainty, are shown in present work. The presented results revealed that, depending on the details of chemical structure, the studied compounds penetrated the lipid bilayers.

  15. Calorimetric Measuring Systems for Characterizing High Frequency Power Losses in Power Electronic Components and Systems

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Pedersen, John Kim; Ritchie, Andrew Ewen

    2002-01-01

    two different calorimetric measuring systems, one for power losses up to 50 W and one for power losses up to 1500 W. These differ in size and also the systems which can be analysed. The basic concept of calorimetry is discussed and the overall performance of the two systems is specified. Methods...... to calibrate such systems are proposed and different applications of the system are given. Two practical examples end the description of the research. It is concluded that such systems have a relative long time-constant but they are accurate and useful for precise power loss measurement....

  16. Electromagnetic losses in a three-phase high temperature superconducting cable determined by calorimetric measurements

    DEFF Research Database (Denmark)

    Traeholt, C.; Veje, E.; Tønnesen, Ole

    2002-01-01

    A 10 m long high temperature superconducting (HTS) cable conductor was placed in a plane three-phase arrangement. The test-bed enabled us to study the conductor losses for different separations between the phases. The superconductor was fixed symmetrically in the centre, whilst the two outer conv...... a calorimetric technique where the temperature increase in the flowing LN2 was measured with a set of thermo-couples. Results indicate that the total AC loss increases significantly when the separation between the conductors is reduced....

  17. Conduction calorimetric studies of ternary binders based on Portland cement, calcium aluminate cement and calcium sulphate

    OpenAIRE

    Torrens Martín, David; Fernández Carrasco, Lucía; Blanco Varela, M.Teresa

    2013-01-01

    Different binders of Portland cement, calcium aluminate cement and calcium sulphate (PC/CAC/CS) have been investigated to determinate the in¿uence the CAC and CS amount in the reactions mechanism. Several mixtures were studied, ratios of 100, 85/15 and 75/25 of PC/CAC with 0, 3 and 5 % of CS. Conduction calorimetric technique was used to follow the hydration during 100 h. The XRD and FTIR techniques were used as support in the analysis of the hydration products. The results have shown tha...

  18. Determination of the dose rapidity of a {sup 90} Sr beta radiation source using thermoluminescent dosemeters; Determinacion de la rapidez de dosis de una fuente de radiacion beta de {sup 90}Sr usando dosimetros termoluminiscentes

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez M, P.R.; Azorin N, J.; Rivera M, T. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2000-07-01

    The thermoluminescent dosemeters developed in Mexico, have been used efficiently in environmental and personal dosimetry. When the dose rate of some source is not known can be estimated with the use of thermoluminescent dosemeters taking in account the geometrical array used in the irradiations for reproducibility of the results in posterior irradiations. In this work it was estimated the dose rate of a {sup 90} Sr-{sup 90} Y beta radiation source which is property of the Nuclear Sciences Institute, UNAM, therefore it was l ended to the Metropolitan Autonomous University- Iztapalapa Unit for the characterization of new Tl materials, taking account of the institutional collaboration agreements. (Author)

  19. Thermodynamic Properties of Liquid Silver-Antimony-Tin Alloys Determined from Electrochemical and Calorimetric Measurements

    Science.gov (United States)

    Łapsa, Joanna; Onderka, Bogusław

    2016-08-01

    The thermodynamic properties of liquid Ag-Sb-Sn alloys were obtained through use of the drop solution calorimetric method and electromotive force (emf) measurements of galvanic cells with a yttria stabilized zirconia (YSZ) solid electrolyte. The experiments were carried out along Ag0.25Sb0.75, Ag0.5Sb0.5 and Ag0.75Sb0.25 sections of the ternary system in the temperature range from 973 K to 1223 K. From the measured emf, the tin activity in liquid solutions of Ag-Sb-Sn was determined for the first time. The partial and integral enthalpy of mixing were determined from calorimetric measurements at two temperatures. These measurements were performed along two cross-sections: Sb0.5Sn0.5 at 912 K and 1075 K, and Ag0.75Sb0.25 at 1075 K. Both experimental data sets were used to find ternary interaction parameters by applying the Redlich-Kister-Muggianu model of the substitutional solution. Consequently, the set of parameters describing the thermodynamic properties of the liquid phase was derived.

  20. Calorimetric method of ac loss measurement in a rotating magnetic field.

    Science.gov (United States)

    Ghoshal, P K; Coombs, T A; Campbell, A M

    2010-07-01

    A method is described for calorimetric ac-loss measurements of high-T(c) superconductors (HTS) at 80 K. It is based on a technique used at 4.2 K for conventional superconducting wires that allows an easy loss measurement in parallel or perpendicular external field orientation. This paper focuses on ac loss measurement setup and calibration in a rotating magnetic field. This experimental setup is to demonstrate measuring loss using a temperature rise method under the influence of a rotating magnetic field. The slight temperature increase of the sample in an ac-field is used as a measure of losses. The aim is to simulate the loss in rotating machines using HTS. This is a unique technique to measure total ac loss in HTS at power frequencies. The sample is mounted on to a cold finger extended from a liquid nitrogen heat exchanger (HEX). The thermal insulation between the HEX and sample is provided by a material of low thermal conductivity, and low eddy current heating sample holder in vacuum vessel. A temperature sensor and noninductive heater have been incorporated in the sample holder allowing a rapid sample change. The main part of the data is obtained in the calorimetric measurement is used for calibration. The focus is on the accuracy and calibrations required to predict the actual ac losses in HTS. This setup has the advantage of being able to measure the total ac loss under the influence of a continuous moving field as experienced by any rotating machines.

  1. Calorimetric Thermoelectric Gas Sensor for the Detection of Hydrogen, Methane and Mixed Gases

    Directory of Open Access Journals (Sweden)

    Nam-Hee Park

    2014-05-01

    Full Text Available A novel miniaturized calorimeter-type sensor device with a dual-catalyst structure was fabricated by integrating different catalysts on the hot (Pd/θ-Al2O3 and cold (Pt/α-Al2O3 ends of the device. The device comprises a calorimeter with a thermoelectric gas sensor (calorimetric-TGS, combining catalytic combustion and thermoelectric technologies. Its response for a model fuel gas of hydrogen and methane was investigated with various combustor catalyst compositions. The calorimetric-TGS devices detected H2, CH4, and a mixture of the two with concentrations ranging between 200 and 2000 ppm at temperatures of 100–400 °C, in terms of the calorie content of the gases. It was necessary to reduce the much higher response voltage of the TGS to H2 compared to CH4. We enhanced the H2 combustion on the cold side so that the temperature differences and response voltages to H2 were reduced. The device response to H2 combustion was reduced by 50% by controlling the Pt concentration in the Pt/α-Al2O3 catalyst on the cold side to 3 wt%.

  2. Magnetic fluid hyperthermia probed by both calorimetric and dynamic hysteresis measurements

    Science.gov (United States)

    Guibert, Clément; Fresnais, Jérôme; Peyre, Véronique; Dupuis, Vincent

    2017-01-01

    In this paper, we report an investigation of magnetic fluid hyperthermia (MFH) using combined calorimetric and newly implemented dynamic hysteresis measurements for two sets of well characterized size-sorted maghemite nanoparticles (with diameters of about 10 nm and 20 nm) dispersed in water and in glycerol. Our primary goal was to assess the influence of viscosity on the heating efficiency of magnetic nanoparticles described in terms of specific loss power (SLP or specific absorption rate, SAR) and dynamic hysteresis. In particular, we aimed to investigate how this SLP depends on the transition from Néelian to Brownian behavior of nanoparticles expected to occur between 10 nm and 20 nm (for maghemite) and dependent on the viscosity. While we observed a good agreement between calorimetric and dynamic hysteresis measurements, we found that the SLP measured for the different systems do not depend noticeably on the viscosity of solvent. Calculations performed according to Rosensweig's linear model [1] allow us to quantitatively reproduce our results at low field intensities, provided we use a value for the magnetic anisotropy constant much smaller than the one commonly used in the literature. This raises the question of the temperature dependance of the magnetic anisotropy constant and its relevance for a quantitative description of MFH.

  3. Cutting heat dissipation in high-speed machining of carbon steel based on the calorimetric method

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The cutting heat dissipation in chips,workpiece,tool and surroundings during the high-speed machining of carbon steel is quantitatively investigated based on the calorimetric method.Water is used as the medium to absorb the cutting heat;a self-designed container suitable for the high-speed lathe is used to collect the chips,and two other containers are adopted to absorb the cutting heat dissipated in the workpiece and tool,respectively.The temperature variations of the water,chips,workpiece,tool and surroundings during the closed high-speed machining are then measured.Thus,the cutting heat dissipated in each component of the cutting system,total cutting heat and heat flux are calculated.Moreover,the power resulting from the main cutting force is obtained according to the measured cutting force and predetermined cutting speed.The accuracy of cutting heat measurement by the calorimetric method is finally evaluated by comparing the total cutting heat flux with the power resulting from the main cutting force.

  4. Calorimetric Investigation of Hydrogen Bonding of Formamide and Its Methyl Derivatives in Organic Solvents and Water

    Science.gov (United States)

    Varfolomeev, Mikhail A.; Rakipov, Ilnaz T.; Solomonov, Boris N.

    2013-04-01

    Formamide and its derivatives have a large number of practical applications; also they are structural fragments of many biomolecules. Hydrogen bonds strongly affect their physicochemical properties. In the present work a calorimetric study of formamide and its methyl derivatives was carried out. Enthalpies of solution at infinite dilution of formamide, N-methylformamide, and N, N-dimethylformamide in organic solvents at 298.15 K were measured. The relationships between the obtained enthalpies of solvation and the structure of the studied compounds were observed. Hydrogen-bond enthalpies of amides with chlorinated alkanes, ethers, ketones, esters, nitriles, amines, alcohols, and water were determined. The strength of hydrogen bonds of formamide, N-methylformamide, and N, N-dimethylformamide with proton donor solvents is practically equal. Enthalpies of hydrogen bonds of formamide with the proton acceptor solvents are two times larger in magnitude than the enthalpies of N-methylformamide. The process of hydrogen bonding of amides in aliphatic alcohols and water is complicated. The obtained enthalpies of hydrogen bonding in aliphatic alcohols vary considerably from the amide structure due to the competition between solute-solvent and solvent-solvent hydrogen bonds. Fourier transform infrared spectroscopic measurements were carried out to explain the calorimetric data. Hydration enthalpies of methyl derivatives of formamides contain a contribution of the hydrophobic effect. New thermochemical data on the hydrogen bonding of formamides may be useful for predicting the properties of biomacromolecules.

  5. A Multichannel Calorimetric Simultaneous Assay Platform Using a Microampere Constant-Current Looped Enthalpy Sensor Array

    Directory of Open Access Journals (Sweden)

    Hsien-Chin Wei

    2017-02-01

    Full Text Available Calorimetric biochemical measurements offer various advantages such as low waste, low cost, low sample consumption, short operating time, and labor-savings. Multichannel calorimeters can enhance the possibility of performing higher-throughput biochemical measurements. An enthalpy sensor (ES array is a key device in multichannel calorimeters. Most ES arrays use Wheatstone bridge amplifiers to condition the sensor signals, but such an approach is only suitable for null detection and low resistance sensors. To overcome these limitations, we have developed a multichannel calorimetric simultaneous assay (MCSA platform. An adjustable microampere constant-current (AMCC source was designed for exciting the ES array using a microampere current loop measurement circuit topology. The MCSA platform comprises a measurement unit, which contains a multichannel calorimeter and an automatic simultaneous injector, and a signal processing unit, which contains multiple ES signal conditioners and a data processor. This study focused on the construction of the MCSA platform; in particular, construction of the measurement circuit and calorimeter array in a single block. The performance of the platform, including current stability, temperature sensitivity and heat sensitivity, was evaluated. The sensor response time and calorimeter constants were given. The capability of the platform to detect relative enzyme activity was also demonstrated. The experimental results show that the proposed MCSA is a flexible and powerful biochemical measurement device with higher throughput than existing alternatives.

  6. A Multichannel Calorimetric Simultaneous Assay Platform Using a Microampere Constant-Current Looped Enthalpy Sensor Array

    Science.gov (United States)

    Wei, Hsien-Chin; Huang, Su-Hua; Jiang, Joe-Air; Lee, Yeun-Chung

    2017-01-01

    Calorimetric biochemical measurements offer various advantages such as low waste, low cost, low sample consumption, short operating time, and labor-savings. Multichannel calorimeters can enhance the possibility of performing higher-throughput biochemical measurements. An enthalpy sensor (ES) array is a key device in multichannel calorimeters. Most ES arrays use Wheatstone bridge amplifiers to condition the sensor signals, but such an approach is only suitable for null detection and low resistance sensors. To overcome these limitations, we have developed a multichannel calorimetric simultaneous assay (MCSA) platform. An adjustable microampere constant-current (AMCC) source was designed for exciting the ES array using a microampere current loop measurement circuit topology. The MCSA platform comprises a measurement unit, which contains a multichannel calorimeter and an automatic simultaneous injector, and a signal processing unit, which contains multiple ES signal conditioners and a data processor. This study focused on the construction of the MCSA platform; in particular, construction of the measurement circuit and calorimeter array in a single block. The performance of the platform, including current stability, temperature sensitivity and heat sensitivity, was evaluated. The sensor response time and calorimeter constants were given. The capability of the platform to detect relative enzyme activity was also demonstrated. The experimental results show that the proposed MCSA is a flexible and powerful biochemical measurement device with higher throughput than existing alternatives. PMID:28165412

  7. Energy and directional response for the Harshaw dosemeter holders 8814 and 8891, and its effect on the appropriate radiation qualities for absolute calibration.

    Science.gov (United States)

    Børretzen, I; Wøhni, T

    2003-01-01

    The personal dosimetry laboratory at the Norwegian radiation protection authority utilises a two-element dosemeter card for measuring Hp(10) and Hp(0.07), in a Harshaw dosemeter holder type 8814. Energy and directional responses for photons and betas for this holder have been assessed, as well as for the new Harshaw holder type 8891. The energy response characteristics for the 12-1250 keV photon energy range, in terms of TL output per unit Hp(10) and Hp(0.07) have been evaluated. The maximum over-response to under-response ratio for the Hp(10) element was found to be 1.46 for the new type 8891 holder, as compared to 1.55 for the older type 8814. The new holder also displays a more favourable directional response for this element. For the Hp(0.07) element, no significant differences with regard to energy or directional responses were found. Selecting radiation energy for absolute calibration of the Hp(10) and Hp(0.07) elements are discussed.

  8. Energy and directional response for the Harshaw dosemeter holders 8814 and 8891, and its effect on the appropriate radiation qualities for absolute calibration

    Energy Technology Data Exchange (ETDEWEB)

    Borretzen, I.; Wohni, T

    2003-07-01

    The personal dosimetry laboratory at the Norwegian radiation protection authority utilises a two-element dosemeter card for measuring H{sub p}(10) and H{sub p}(0.07), in a Harshaw dosemeter holder type 8814. Energy and directional responses for photons and betas for this holder have been assessed, as well as for the new Harshaw holder type 8891. The energy response characteristics for the 12-1250 keV photon energy range, in terms of TL output per unit H{sub p}(10) and H{sub p}(0.07) have been evaluated. The maximum over-response to under-response ratio for the H{sub p}(10) element was found to be 1.46 for the new type 8891 holder, as compared to 1.55 for the older type 8814. The new holder also displays a more favourable directional response for this element. For the H{sub p}(0.07) element, no significant differences with regard to energy or directional responses were found. Selecting radiation energy for absolute calibration of the H{sub p}(10) and H{sub p}(0.07) elements are discussed. (author)

  9. Effect of some parameters in the response of the Perspex 3042, Lot L amber dosemeters; Efectos de algunos parametros en la respuesta de los dosimetros ambar Perspex 3042, Lote L

    Energy Technology Data Exchange (ETDEWEB)

    Prieto M, E.F.; Barrera G, G. [Centro de Aplicaciones Tecnologicas y Desarrollo Nuclear (CEADEN). Calle 30, No. 502, esq. 5ta. Avenida, Playa, Ciudad de La Habana (Cuba)]. e-mail: efprieto@ceaden.edu.cu

    2004-07-01

    The answer of the dosimetric systems is affected by several factors, for what should know as these factors they influence in each one of the different dosimetric systems and by this way to minimize its effect in the value of the absorbed dose and to obtain exact dose values. One of the dosimetric systems more used in the high dose dosimetry like routine dosemeter for the control of the irradiation process are the Perspex dosemeters, for their speed in the obtaining the information, their easy manipulation and the precision that they present. To this dosemeters group they belong the same as the Red and Clear the Amber, which are adequate for the measurement of the radiation dose in the range of high doses. The objective of the present work is to obtain the calibration curves of the dosemeters Amber Perspex 3042, Lot L under our work conditions, like they are the irradiation temperatures and of storage and to know the influence of the rate dose in the value of the absorbed dose for different measurement wavelengths, as well as, the relationship among the one post-irradiation time and the specific absorbance value induced in function of the absorbed dose. (Author)

  10. Study on routines and procedures of calibration of clinical dosemeter on gamma radiation beams at the IPEN-CNEN/SP, Brazil; Estudo das rotinas e procedimentos de calibracao de dosimetros clinicos em feixes de radiacao gama no IPEN-CNEN/SP

    Energy Technology Data Exchange (ETDEWEB)

    Damatto, Willian B.; Potiens, Maria da Penha A.; Santos, Gelson P.; Vivolo, Vitor, E-mail: wbdamatto@ipen.b, E-mail: mppalbu@ipen.b, E-mail: gpsantos@ipen.b, E-mail: vivolo@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2009-07-01

    The calibration consists in the comparison of the equipment to be calibrated with other equipment already calibrated by another standard, which means the equipment that will accomplish shall be considered secondary or tertiary, depending on the calibration that will be accomplished. As the clinical dosemeters are used for quality control services in the hospitals, these dosemeters need a reliable measurement precision. Therefore, this work intends to demonstrate the importance of the clinical dosemeter and the calibration, requiring special care face to all clinical set

  11. MANU-2: A second generation experiment for calorimetric neutrino mass determination with superconducting Re

    Energy Technology Data Exchange (ETDEWEB)

    Pergolesi, D. [University and INFN of Genoa, Department of Physics, Via Dodecaneso 33, 16146 Genoa (Italy); Gastaldo, L. [University and INFN of Genoa, Department of Physics, Via Dodecaneso 33, 16146 Genoa (Italy); Kichhoff-Institut fur Physik, Universitaet Heidelberg, INF 227, 69120 Heidelberg (Germany); Gatti, F. [University and INFN of Genoa, Department of Physics, Via Dodecaneso 33, 16146 Genoa (Italy)]. E-mail: flavio.gatti@ge.infn.it; Ribeiro Gomes, M. [University and INFN of Genoa, Department of Physics, Via Dodecaneso 33, 16146 Genoa (Italy); Repetto, P. [University and INFN of Genoa, Department of Physics, Via Dodecaneso 33, 16146 Genoa (Italy); Dussoni, S. [University and INFN of Genoa, Department of Physics, Via Dodecaneso 33, 16146 Genoa (Italy); Valle, R. [University and INFN of Genoa, Department of Physics, Via Dodecaneso 33, 16146 Genoa (Italy)

    2006-04-15

    The calorimetric determination of the neutrino mass by means of cryogenic detectors could play a significant role, being in principle able to investigate the 10{sup -1} eV/c {sup 2} region. But the question if the developments in this new technique will allow verify the expected performances is still open. A step forward in the advancement of this technology is represented by the incoming second-generation experiment on the {beta}-decay of Re{sup 187} with superconducting rhenium, microcalorimeters, MANU-2. It is expected that this new experiment with about 300 detectors will achieve a sensitivity of 1.5 eV/c {sup 2} (90% CL), in 1 yr, that allow to cover or improve the present best limit from tritium beta spectroscopy.

  12. Calorimetric and spectroscopic properties of small globular proteins (bovine serum albumin, hemoglobin) after free radical generation

    Energy Technology Data Exchange (ETDEWEB)

    Farkas, N.; Belagyi, J.; Lorinczy, D

    2003-09-04

    Mild oxidation of -SH-containing proteins (serum albumin, hemoglobin) by Ce(IV)-ions in the presence of the spin trap phenyl-tert-butylnitrone (PBN) resulted in the appearance of strongly immobilized nitroxide free radicals which evidences the formation of thiyl radicals on the thiol site of the proteins. In hydroxyl free radical generating system a fraction of strongly immobilized nitroxide radicals was also detected in these proteins, which implies that the oxidation of a fraction of the thiol groups was also involved in the free radical reaction. According to the differential scanning calorimetry (DSC) experiments the melting processes of the proteins were calorimetrically irreversible, therefore the two-state kinetic model was used to evaluate the experiments. The results support the view that site-specific interaction of SH-containing proteins with hydroxyl and thiyl free radicals is able to modify the internal dynamics of proteins and affect the conformation of large molecules.

  13. Analytical and experimental characterization of a miniature calorimetric sensor in pulsatile flow

    CERN Document Server

    Gelderblom, H; Haartsen, J R; Rutten, M C M; van de Ven, A A F; van de Vosse, F N; 10.1017/S0022112010004234

    2011-01-01

    The behaviour of a miniature calorimetric sensor, which is under consideration for catheter-based coronary artery flow assessment, is investigated in both steady and pulsatile tube flow. The sensor is composed of a heating element operated at constant power, and two thermopiles that measure flow-induced temperature differences over the sensor surface. An analytical sensor model is developed, which includes axial heat conduction in the fluid and a simple representation of the solid wall, assuming a quasi-steady sensor response to the pulsatile flow. To reduce the mathematical problem, described by a two-dimensional advection-diffusion equation, a spectral method is applied. A Fourier transform is then used to solve the resulting set of ordinary differential equations and an analytical expression for the fluid temperature is found. To validate the analytical model, experiments with the sensor mounted in a tube have been performed in steady and pulsatile water flow with various amplitudes and Strouhal numbers. E...

  14. Calorimetric examination of mixtures for modification of nickel and cobalt superalloys

    Directory of Open Access Journals (Sweden)

    F. Binczyk

    2009-04-01

    Full Text Available The study presents the results of thermodynamic calculations and calorimetric examination of thermal reactions taking place at hightemperatures between the nanoparticle inoculants and metallic constituents of nickel and cobalt superalloys. The calculations andmeasurements were made for different compositions, containing cobalt aluminate CoAl2O4, cobalt oxide CoO*Co2O3, zircon flourZrSi2O4, powdered and metallic Al, powdered Ti, and IN-713C alloy. The obtained results have indicated the possibility of using certainmixtures as potential inoculating additives for the volume modification of nickel and cobalt superalloys. A characteristic feature of these alloys is the formation of a detrimental structure containing very large columnar crystal, present even in castings of a very high solidification rate. It has been proved that the inoculant most effective in the formation of the structure of equiaxial grains is the inoculant based on cobalt aluminate, colloidal silica and powdered aluminium.

  15. Direct calorimetric verification of thermodynamic instability of lead halide hybrid perovskites.

    Science.gov (United States)

    Nagabhushana, G P; Shivaramaiah, Radha; Navrotsky, Alexandra

    2016-07-12

    Hybrid perovskites, especially methylammonium lead iodide (MAPbI3), exhibit excellent solar power conversion efficiencies. However, their application is plagued by poor chemical and structural stability. Using direct calorimetric measurement of heats of formation, MAPbI3 is shown to be thermodynamically unstable with respect to decomposition to lead iodide and methylammonium iodide, even in the absence of ambient air or light or heat-induced defects, thus limiting its long-term use in devices. The formation enthalpy from binary halide components becomes less favorable in the order MAPbCl3, MAPbBr3, MAPbI3, with only the chloride having a negative heat of formation. Optimizing the geometric match of constituents as measured by the Goldschmidt tolerance factor provides a potentially quantifiable thermodynamic guide for seeking chemical substitutions to enhance stability.

  16. Viscosity, calorimetric, and proton magnetic resonance studies on coal liquid fractions in solution

    Energy Technology Data Exchange (ETDEWEB)

    Tewari, K.C.; Kan, N.; Susco, D.M.; Li, N.C.

    1979-02-01

    Two coal liquid products derived from the same Kentucky hvAb coal have been separated into toluene-insoluble, asphaltene, and pentane-soluble heavy oil fractions. Viscosity and calorimetric studies are reported of the interaction between heavy oil and asphaltene (A) and its acid/neutral (AA) and base (BA) components in solvent benzene. The increase in viscosity and molar enthalpy of interaction, ..delta..H/sup 0/, in the order BA > A > AA, correlates well with the proton magnetic resonance downfield chemical shift of the OH signal of o-phenylphenol, as a function of added asphaltene (A, AA, BA) concentration in solvent CS/sub 2/. The results suggest that when asphaltene and heavy oil are present together, hydrogen-bonding involving largely phenolic OH, is one of the mechanisms by which asphaltene-heavy oil interactions are achieved and, in part, is responsible for the viscosity increase of coal liquids. 4 figures, 3 tables.

  17. Evidence of secondary electron emission during PIII pulses as measured by calorimetric probe

    Science.gov (United States)

    Haase, Fabian; Manova, Darina; Mändl, Stephan; Kersten, Holger

    2016-09-01

    Secondary electrons are an ubiquitous nuisance during plasma immersion ion implantation (PIII) necessitating excessive current supplies and shielding for X-rays generated by them. However, additional effects - especially at low pulse voltages - can include interactions with the plasma and transient increases in the plasma density. Here, it is shown that the transient thermal flux associated with secondary electrons emitted from the pulsed substrate can be directly measured using a passive calorimetric probe mounted near the chamber wall away from the pulsed substrate holder. A small increase of a directed energy flux from the substrate towards the probe is consistently observed on top of the isotropic flux from the plasma surrounding the probe, scaling with pulse frequency, pulse voltage, pulse length - as well as depending on gas and substrate material. A strong correlation between voltage and substrate-probe distance is observed, which should allow further investigation of low energy electrons with the plasma itself.

  18. Calorimetric calibration of head coil SAR estimates displayed on a clinical MR scanner

    Energy Technology Data Exchange (ETDEWEB)

    Gorny, Krzysztof R; Bernstein, Matt A; Felmlee, Joel P; Ward, Heidi A; McGee, Kiaran P; Lanners, Diana M [Department of Radiology, Mayo Clinic, Rochester, MN 55905 (United States); Lee, Kendall H [Department of Neurosurgery, Mayo Clinic, Rochester, MN 5505 (United States)

    2008-05-21

    Calorimetric measurements were performed to determine the average specific absorption rates (SAR) resulting from MRI head examinations. The data were compared with average head coil SAR estimates displayed by the MR scanner in order to refine the imaging protocols used in imaging patients with implanted deep brain stimulators (DBS). The experiments were performed using transmit-receive (TR) head coil on clinical 1.5 T General Electric MR scanners running 11.0 M4 revision software. The average applied SAR was derived from temperature increases measured inside a head phantom, due to deposition of RF energy during MRI scanning with a spin echo imaging sequence. The measurements were repeated for varied levels of RF transmit gain (TG) and analyzed with a range of entered patient weights. The measurements demonstrate that the ratio of the actual average head SAR to the scanner-displayed value (coil correction factor) decreases for decreasing TG or for increasing patient weight and may vary between 0.3 and 2.1. An additional retrospective patient study, however, shows that not all combinations of TG and patient weight are encountered clinically and, instead, TG generally increases with the patient weight. As a result, a much narrower range of coil correction factors (e.g., typically 0.5-1.0) will be encountered in practice. The calorimetric method described in this work could aid the physicians and technologists in refinement of the model-dependent SAR estimates displayed by the MR scanner, and in selection of imaging parameters for MR head examinations within allowable SAR safety levels.

  19. New methodology for simultaneous volumetric and calorimetric measurements: Direct determination of αp and Cp for liquids under pressure

    Science.gov (United States)

    Casás, L. M.; Plantier, F.; Bessières, D.

    2009-12-01

    A new batch cell has been developed to measure simultaneously both isobaric thermal expansion and isobaric heat capacity from calorimetric measurements. The isobaric thermal expansion is directly proportional to the linear displacement of an inner flexible below and the heat capacity is calculated from the calorimetric signal. The apparatus used was a commercial Setaram C-80 calorimeter and together with this type of vessels can be operated up to 20 MPa and in the temperature range of 303.15-523.15 K, In this work, calibration was carried out using 1-hexanol and subsequently both thermophysical properties were determined for 3-pentanol, 3-ethyl-3-pentanol, and 1-octanol at atmospheric pressure, 5 and 10 MPa, and from 303.15 to 423.15 K in temperature. Finally experimental values were compared with the literature in order to validate this new methodology, which allows a very accurate determination of isobaric thermal expansion and isobaric heat capacity.

  20. Calorimetric low temperature detectors for low-energetic heavy ions and their application in accelerator mass spectrometry.

    Science.gov (United States)

    Kraft-Bermuth, S; Andrianov, V A; Bleile, A; Echler, A; Egelhof, P; Kiseleva, A; Kiselev, O; Meier, H J; Meier, J P; Shrivastava, A; Weber, M; Golser, R; Kutschera, W; Priller, A; Steier, P; Vockenhuber, C

    2009-10-01

    The energy-sensitive detection of heavy ions with calorimetric low temperature detectors was investigated in the energy range of E=0.1-1 MeV/amu, commonly used for accelerator mass spectrometry (AMS). The detectors used consist of sapphire absorbers and superconducting aluminum transition edge thermometers operated at T approximately 1.5 K. They were irradiated with various ion beams (13C, 197Au, 238U) provided by the VERA tandem accelerator in Vienna, Austria. The relative energy resolution obtained was DeltaE/E=(5-9) x 10(-3), even for the heaviest ions such as 238U. In addition, no evidence for a pulse height defect was observed. This performance allowed for the first time to apply a calorimetric low temperature detector in an AMS experiment. The aim was to precisely determine the isotope ratio of 236U/238U for several samples of natural uranium, 236U being known as a sensitive monitor for neutron fluxes. Replacing a conventionally used detection system at VERA by the calorimetric detector enabled to substantially reduce background from neighboring isotopes and to increase the detection efficiency. Due to the high sensitivity achieved, a value of 236U/238U=6.1 x 10(-12) could be obtained, representing the smallest 236U/238U ratio measured at the time. In addition, we contributed to establishing an improved material standard of 236U/238U, which can be used as a reference for future AMS measurements.

  1. Calorimetric low temperature detectors for low-energetic heavy ions and their application in accelerator mass spectrometry

    Science.gov (United States)

    Kraft-Bermuth, S.; Andrianov, V. A.; Bleile, A.; Echler, A.; Egelhof, P.; Kiseleva, A.; Kiselev, O.; Meier, H. J.; Meier, J. P.; Shrivastava, A.; Weber, M.; Golser, R.; Kutschera, W.; Priller, A.; Steier, P.; Vockenhuber, C.

    2009-10-01

    The energy-sensitive detection of heavy ions with calorimetric low temperature detectors was investigated in the energy range of E =0.1-1 MeV/amu, commonly used for accelerator mass spectrometry (AMS). The detectors used consist of sapphire absorbers and superconducting aluminum transition edge thermometers operated at T ˜1.5 K. They were irradiated with various ion beams (C13,A197u,U238) provided by the VERA tandem accelerator in Vienna, Austria. The relative energy resolution obtained was ΔE /E=(5-9)×10-3, even for the heaviest ions such as U238. In addition, no evidence for a pulse height defect was observed. This performance allowed for the first time to apply a calorimetric low temperature detector in an AMS experiment. The aim was to precisely determine the isotope ratio of U236/U238 for several samples of natural uranium, U236 being known as a sensitive monitor for neutron fluxes. Replacing a conventionally used detection system at VERA by the calorimetric detector enabled to substantially reduce background from neighboring isotopes and to increase the detection efficiency. Due to the high sensitivity achieved, a value of U236/U238=6.1×10-12 could be obtained, representing the smallest U236/U238 ratio measured at the time. In addition, we contributed to establishing an improved material standard of U236/U238, which can be used as a reference for future AMS measurements.

  2. Effect of Temperature on Xylanase II from Trichoderma reesei QM 9414: A Calorimetric, Catalytic, and Conformational Study

    Directory of Open Access Journals (Sweden)

    Gloria López

    2014-01-01

    Full Text Available The secondary structure of xylanase II from Trichoderma reesei is lost in an apparent irreversible cooperative process as temperature is increased with a midpoint transition of 58.8 ± 0.1°C. The shift of the spectral centre of mass above 50°C is also apparently cooperative with midpoint transition of 56.3 ± 0.2°C, but the existence of two isofluorescent points in the fluorescence emission spectra suggests a non-two-state process. Further corroboration comes from differential scanning calorimetry experiments. At protein concentrations ≤0.56 mg·mL−1 the calorimetric transition is reversible and the data were fitted to a non-two-state model and deconvoluted into six transitions, whereas at concentrations greater than 0.56 mg·mL−1 the calorimetric transition is irreversible with an exothermic contribution to the thermogram. The apparent Tm increased linearly with the scan rate according to first order inactivation kinetics. The effect of additives on the calorimetric transition of xylanase is dependent on their nature. The addition of sorbitol transforms reversible transitions into irreversible transitions while stabilizing the protein as the apparent Tm increases linearly with sorbitol concentration. d-Glucono-1,5-lactone, a noncompetitive inhibitor in xylanase kinetics, and soluble xylan change irreversible processes into reversible processes at high protein concentration.

  3. Effect of sulfoxides on the thermal denaturation of hen lysozyme: A calorimetric and Raman study

    Science.gov (United States)

    Torreggiani, A.; Di Foggia, M.; Manco, I.; De Maio, A.; Markarian, S. A.; Bonora, S.

    2008-11-01

    A multidisciplinary study of the thermal denaturation of lysozyme in the presence of three sulfoxides with different length in hydrocarbon chain (DMSO, DESO, and DPSO) was carried out by means of DSC, Raman spectroscopy, and SDS-PAGE techniques. In particular, the Td and Δ H values obtained from the calorimetric measurements showed that lysozyme is partially unfolded by sulfoxides but most of the conformation holds native state. The sulfoxide denaturing ability increases in the order DPSO > DESO > DMSO. Moreover, only DMSO and DESO have a real effect in preventing the heat-induced inactivation of the protein and their maximum heat-protective ability is reached when the DMSO and DESO amount is ⩾25% w/w. The sulfoxide ability to act as effective protective agents against the heat-induced inactivation was confirmed by the protein analysis. The enzymatic activity, as well as the SDS-PAGE analysis, suggested that DESO, having a low hydrophobic character and a great ability to stabilise the three-dimensional water structure, is the most heat-protective sulfoxide. An accurate evaluation of the heat-induced conformational changes of the lysozyme structure before and after sulfoxide addition was obtained by the analysis of the Raman spectra. The addition of DMSO or DESO in low concentration resulted to sensitively decrease the heat-induced structural modifications of the protein.

  4. Calorimetric studies and lessons on fires and explosions of a chemical plant producing CHP and DCPO.

    Science.gov (United States)

    Hsu, Jing-Ming; Su, Mao-Sheng; Huang, Chiao-Ying; Duh, Yih-Shing

    2012-05-30

    Cumene hydroperoxide (CHP) has been used in producing phenol, dicumyl peroxide (DCPO) and as an initiator for synthesizing acrylonitrile-butadiene-styrene (ABS) resin by copolymerization in Taiwan. Four incidents of fire and explosion induced by thermal runaway reactions were occurred in a same plant producing CHP, DCPO and bis-(tert-butylperoxy isopropyl) benzene peroxide (BIBP). The fourth fire and explosion occurred in the CHP reactor that resulted in a catastrophic damage in reaction region and even spread throughout storage area. Descriptions on the occurrences of these incidents were assessed by the features of processes, reaction schemes and unexpected side reactions. Calorimetric data on thermokinetics and pressure were used for explaining the practical consequences or which the worst cases encountered in this kind of plant. Acceptable risk associated with emergency relief system design is vital for a plant producing organic peroxide. These basic data for designing an inherently safer plant can be conducted from adiabatic calorimetry. An encouraging deduction has been drawn here, these incidents may be avoided by the implementation of API RP 520, API RP 521, DIERS technology, OSHA 1910.119 and AIChE's CCPS recommended PSM elements.

  5. Calorimetric studies and lessons on fires and explosions of a chemical plant producing CHP and DCPO

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, Jing-Ming; Su, Mao-Sheng; Huang, Chiao-Ying [Department of Occupational Safety and Health, Chia Nan University of Pharmacy and Science, Tainan, Taiwan, ROC (China); Duh, Yih-Shing, E-mail: yihshingduh@yahoo.com.tw [Department of Safety, Health and Environmental Engineering, National United University, No. 1 Lien-Da, Miaoli, Taiwan, ROC (China)

    2012-05-30

    Highlights: Black-Right-Pointing-Pointer We analyzed fire and explosion incidents in a plant producing CHP and DCPO. Black-Right-Pointing-Pointer Data from calorimeters reveal causes and phenomena associated with the incidents. Black-Right-Pointing-Pointer The credible worst scenario was thermal explosion. Black-Right-Pointing-Pointer Incidents may be avoided by implementing DIERS methodology. - Abstract: Cumene hydroperoxide (CHP) has been used in producing phenol, dicumyl peroxide (DCPO) and as an initiator for synthesizing acrylonitrile-butadiene-styrene (ABS) resin by copolymerization in Taiwan. Four incidents of fire and explosion induced by thermal runaway reactions were occurred in a same plant producing CHP, DCPO and bis-(tert-butylperoxy isopropyl) benzene peroxide (BIBP). The fourth fire and explosion occurred in the CHP reactor that resulted in a catastrophic damage in reaction region and even spread throughout storage area. Descriptions on the occurrences of these incidents were assessed by the features of processes, reaction schemes and unexpected side reactions. Calorimetric data on thermokinetics and pressure were used for explaining the practical consequences or which the worst cases encountered in this kind of plant. Acceptable risk associated with emergency relief system design is vital for a plant producing organic peroxide. These basic data for designing an inherently safer plant can be conducted from adiabatic calorimetry. An encouraging deduction has been drawn here, these incidents may be avoided by the implementation of API RP 520, API RP 521, DIERS technology, OSHA 1910.119 and AIChE's CCPS recommended PSM elements.

  6. Effect of Experiment Environment on Calorimetric Value of Composite Solid Propellants

    Directory of Open Access Journals (Sweden)

    Lalita S. Jawale

    2013-09-01

    Full Text Available The calorimetric value (cal-val of solid rocket propellants and explosives is determined in the presence of inert atmosphere using industrial nitrogen gas. However, due to presence of trace amount of oxygen, the cal-val is not always correct. To avoid such inaccuracy in cal-val, a systematic study has been carried out by taking different types of solid propellant samples having burning rate in the range of 5 mm/s − 30 mm/s at different pressures. The data obtained were acquired using industrial nitrogen, ultra high pure nitrogen (UHP-N2, ultra high pure argon (UHP-Ar, air and ultra high pure oxygen (UHP-O2. The data reveal that cal-val is highest in the case of UHP-O2 due to complete combustion while in the case of air and industrial nitrogen it is found to be substantially less. Moreover, the cal-val in the presence of UHP-N2 and UHP-Ar meets the standard value with reproducibility. The results, further, confirm that for authentic cal-val, the most suitable environment is UHP-N2/UHP-Ar.

  7. Effect of Experiment Environment on Calorimetric Value of Composite Solid Propellants

    Directory of Open Access Journals (Sweden)

    Lalita S. Jawale

    2013-09-01

    Full Text Available The calorimetric value (cal-val of solid rocket propellants and explosives is determined in the presenceof inert atmosphere using industrial nitrogen gas. However, due to presence of trace amount of oxygen, the cal-val is not always correct. To avoid such inaccuracy in cal-val, a systematic study has been carried out by takingdifferent types of solid propellant samples having burning rate in the range of 5 mm/s − 30 mm/s at different pressures.The data obtained were acquired using industrial nitrogen, ultra high pure nitrogen (UHP-N2, ultra high pureargon (UHP-Ar, air and ultra high pure oxygen (UHP-O2. The data reveal that cal-val is highest in the case ofUHP-O2 due to complete combustion while in the case of air and industrial nitrogen it is found to be substantiallyless. Moreover, the cal-val in the presence of UHP-N2 and UHP-Ar meets the standard value with reproducibility.The results, further, confirm that for authentic cal-val, the most suitable environment is UHP-N2/UHP-Ar.Defence Science Journal, 2013, 63(5, pp.467-472, DOI:http://dx.doi.org/10.14429/dsj.63.2896

  8. Calorimetric measurement of heat load in full non-inductive LHCD plasmas on TRIAM-1M

    Science.gov (United States)

    Hanada, K.; Shinoda, N.; Sugata, T.; Sasaki, K.; Zushi, H.; Nakamura, K.; Sato, K. N.; Sakamoto, M.; Idei, H.; Hasegawa, M.; Kawasaki, S.; Nakashima, H.; Higashijima, A.; Triam Group

    2007-06-01

    Calorimetric measurements using the temperature increment of cooling-water were carried out to estimate the heat load distribution on the plasma facing components (PFCs) in the limiter discharges on TRIAM-1M. Line averaged electron density, ne, and LH power, PLH, dependences of the heat load on PFCs were measured. The heat load on the limiters was proportional to ne1.5 in the range of ne = 0.2-1.0 × 1019 m-3 and PLH1 in the range of PLH = 0.005-0.09 MW. For PLH > 0.1 MW, the plasma transition to an enhanced current drive (ECD) mode appeared and the ne dependences on the heat load on the limiter moderated. This indicates that the heat flux to scrape-off layer (SOL) region was reduced due to the improvement of the plasma confinement. The up-down asymmetry of the heat load on the vacuum vessel was enhanced in the ECD mode, which may be caused by the increasing of the direct loss of energetic electrons.

  9. Phase transitions in the urea/n-nonadecane system by calorimetric techniques

    Energy Technology Data Exchange (ETDEWEB)

    Lopez-Echarri, A [Departamento de Fisica de la Materia Condensada, Facultad de Ciencia y TecnologIa, Universidad del PaIs Vasco, Apartado 644, 48080 Bilbao (Spain); Ruiz-Larrea, I [Departamento de Fisica Aplicada II, Facultad de Ciencia y TecnologIa, Universidad del PaIs Vasco, Apartado 644, 48080 Bilbao (Spain); Fraile-RodrIguez, A [Swiss Light Source, Paul Scherrer Institut, 5232 Villigen PSI (Switzerland); Diaz-Hernandez, J [Facultad de Ciencias FIsico-Matematicas, Universidad Autonoma de Puebla (Mexico); Breczewski, T [Departamento de Fisica Aplicada II, Facultad de Ciencia y TecnologIa, Universidad del PaIs Vasco, Apartado 644, 48080 Bilbao (Spain); Bocanegra, E H [Departamento de Fisica Aplicada II, Facultad de Ciencia y TecnologIa, Universidad del PaIs Vasco, Apartado 644, 48080 Bilbao (Spain)

    2007-05-08

    A calorimetric study of urea/n-nonadecane, CO(NH{sub 2}){sub 2}/C{sub 19}H{sub 40}, and the deuterated derivatives, CO(ND{sub 2}){sub 2}/C{sub 19}D{sub 40} and CO(NH{sub 2}){sub 2}/C{sub 19}D{sub 40}, around the structural phase transition temperature is presented. For this purpose differential scanning (DSC), temperature-modulated (AC) and adiabatic calorimetry have been used and the obtained results are compared. Leaving apart the noticeable peak associated with the main phase transition at 158.5, 149.4 and 154 K respectively, small anomalies of the specific heat are found at lower temperatures and their corresponding entropic and enthalpic changes are reported. Heating and cooling experiments show the influence of the temperature rate and the thermal history on the detailed profile of the specific heat traces. The presence of thermal hysteresis and latent heat as a way to characterize the order of the phase transitions is discussed. Finally, a tentative approach to the urea and the alkyl chain contributions to the specific heat and their influence on the phase transition mechanisms is presented.

  10. Specific binding of a dihydropyrimidinone derivative with DNA: Spectroscopic, calorimetric and modeling investigations

    Energy Technology Data Exchange (ETDEWEB)

    Wang Gongke, E-mail: wanggongke@126.com [School of Chemistry and Environmental Science, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Xinxiang, Henan 453007 (China); Yan Changling; Wang Dongchao; Li Dan [School of Chemistry and Environmental Science, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Xinxiang, Henan 453007 (China); Lu Yan, E-mail: yanlu2001@sohu.com [School of Chemistry and Environmental Science, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Xinxiang, Henan 453007 (China)

    2012-07-15

    One of the dihydropyrimidinone derivative 5-(ethoxycarbonyl)-6-methyl-4-(4-methoxyphenyl) -3,4-dihydropyrimidin-2(1H)-one (EMMD) was synthesized, and its binding properties with calf-thymus DNA (ctDNA) were investigated using spectroscopic, viscometric, isothermal titration calorimetric (ITC) and molecular modeling techniques. Fluorescence spectra suggested that the fluorescence enhancement of the binding interaction of EMMD to ctDNA was a static process with ground state complex formation. The binding constant determined with spectroscopic titration and ITC was found to be in the same order of 10{sup 4} M{sup -1}. According to the results of the viscosity analysis, fluorescence competitive binding experiment, fluorescence quenching studies, absorption spectral and ITC investigations, it can be concluded that EMMD is intercalative binding to ctDNA. Furthermore, the results of molecular modeling confirmed those obtained from spectroscopic, viscosimetric and ITC investigations. Additionally, ITC studies also indicated that the binding interaction is predominantly enthalpy driven. - Highlights: Black-Right-Pointing-Pointer Medically important dihydropyrimidinones derivative EMMD is synthesized. Black-Right-Pointing-Pointer EMMD is intercalative binding into ctDNA helix. Black-Right-Pointing-Pointer Hydrogen bonding may play an essential role in the binding of EMCD with ctDNA. Black-Right-Pointing-Pointer This binding interaction is predominantly enthalpy driven.

  11. The CALorimetric Electron Telescope (CALET for high-energy astroparticle physics on the International Space Station

    Directory of Open Access Journals (Sweden)

    Adriani O.

    2015-01-01

    Full Text Available The CALorimetric Electron Telescope (CALET is a space experiment, currently under development by Japan in collaboration with Italy and the United States, which will measure the flux of cosmic-ray electrons (and positrons up to 20 TeV energy, of gamma rays up to 10 TeV, of nuclei with Z from 1 to 40 up to 1 PeV energy, and will detect gamma-ray bursts in the 7 keV to 20 MeV energy range during a 5 year mission. These measurements are essential to investigate possible nearby astrophysical sources of high energy electrons, study the details of galactic particle propagation and search for dark matter signatures. The main detector of CALET, the Calorimeter, consists of a module to identify the particle charge, followed by a thin imaging calorimeter (3 radiation lengths with tungsten plates interleaving scintillating fibre planes, and a thick energy measuring calorimeter (27 radiation lengths composed of lead tungstate logs. The Calorimeter has the depth, imaging capabilities and energy resolution necessary for excellent separation between hadrons, electrons and gamma rays. The instrument is currently being prepared for launch (expected in 2015 to the International Space Station ISS, for installation on the Japanese Experiment Module - Exposure Facility (JEM-EF.

  12. Calorimetric apparatus for alternating current loss measurements on high-temperature superconductors

    Science.gov (United States)

    Magnusson, N.; Hörnfeldt, S.

    1998-09-01

    The use of high-temperature superconductors in electric power components requires the knowledge of their alternating current (ac) losses. Methods are therefore needed to characterize the conductors with respect to their ac losses under applicationlike conditions. In this article we describe a calorimetric setup for ac loss measurements on long length high-temperature superconductors carrying ac transport currents in ac external magnetic fields at variable temperatures. The variable temperature is achieved by a thermal connection between the sample and a cooling machine. Current in copper coils generates the magnetic field parallel to the plane of the tape and perpendicular to the transport current. This current can be induced in the coil-formed sample. Two slightly different methods are used to determine the ac losses, one in which the temperature rise of the sample, caused by the ac losses, is compared to the temperature rise caused by a reference heater and another in which the increase in power dissipation of the sample is compensated for by a reduction of the power dissipation in the heater. Typical results of the ac loss measurements are presented.

  13. Status and performance of the CALorimetric Electron Telescope (CALET) on the International Space Station

    Energy Technology Data Exchange (ETDEWEB)

    Adriani, O. [University of Florence, IFAC (CNR) and INFN (Italy); Akaike, Y. [ICRR, University of Tokyo (Japan); Asaoka, Y. [Waseda University (Japan); Asano, K. [Tokyo Institute of Technology (Japan); Bagliesi, M.G.; Bigongiari, G. [University of Siena and INFN (Italy); Binns, W.R. [Washington University-St. Louis (United States); Bongi, M. [University of Florence, IFAC (CNR) and INFN (Italy); Buckley, J.H. [Washington University-St. Louis (United States); Cassese, A.; Castellini, G. [University of Florence, IFAC (CNR) and INFN (Italy); Cherry, M.L. [Louisiana State University (United States); Collazuol, G. [University of Padova and INFN (Italy); Ebisawa, K. [JAXA/ISAS (Japan); Di Felice, V. [University of Rome Tor Vergata and INFN (Italy); Fuke, H. [JAXA/ISAS (Japan); Guzik, T.G. [Louisiana State University (United States); Hams, T. [CRESST/NASA/GSFC and University of Maryland (United States); Hasebe, N. [Waseda University (Japan); Hareyama, M. [St. Marianna University School of Medicine (Japan); and others

    2014-11-15

    The CALorimetric Electron Telescope (CALET) space experiment, currently under development by Japan in collaboration with Italy and the United States, will measure the flux of cosmic-ray electrons (including positrons) to 20 TeV, gamma rays to 10 TeV and nuclei with Z=1 to 40 up to 1,000 TeV during a two-year mission on the International Space Station (ISS), extendable to five years. These measurements are essential to search for dark matter signatures, investigate the mechanism of cosmic-ray acceleration and propagation in the Galaxy and discover possible astrophysical sources of high-energy electrons nearby the Earth. The instrument consists of two layers of segmented plastic scintillators for the cosmic-ray charge identification (CHD), a 3 radiation length thick tungsten-scintillating fiber imaging calorimeter (IMC) and a 27 radiation length thick lead-tungstate calorimeter (TASC). CALET has sufficient depth, imaging capabilities and excellent energy resolution to allow for a clear separation between hadrons and electrons and between charged particles and gamma rays. The instrument will be launched to the ISS within 2014 Japanese Fiscal Year (by the end of March 2015) and installed on the Japanese Experiment Module-Exposed Facility (JEM-EF). In this paper, we will review the status and main science goals of the mission and describe the instrument configuration and performance.

  14. Calorimetric features of IgM gammopathies. Implication for patient’s diagnosis and monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Krumova, Sashka; Todinova, Svetla; Danailova, Avgustina [Institute of Biophysics and Biomedical Engineering, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., bl. 21, 1113 Sofia (Bulgaria); Petkova, Violeta; Dimitrova, Keranka; Gartcheva, Lidia [National Specialized Hospital for Active Treating of Haematological Diseases, Sofia 1756 (Bulgaria); Taneva, Stefka G., E-mail: stefka.germanova@ehu.es [Institute of Biophysics and Biomedical Engineering, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., bl. 21, 1113 Sofia (Bulgaria); Unidad de Biofísica (CSIC-UPV/EHU) and Departamento de Bioquímica y Biología Molecular, Universidad del País Vasco, 48080 Bilbao (Spain)

    2015-09-10

    Highlights: • DSC reveals distinct calorimetric features for IgM gammopaties. • Calorimetry sets of IgM multiple myeloma and Waldenström’s macroglobulinemia patients. • DSC features correlate with the level of involved IgM heavy/light chains. • DSC and “Heavylite” are complementary methods for patients diagnostics/monitoring. - Abstract: The serum proteome of patients featuring immunoglobulin M (IgM) gammopathy and diagnosed as having IgM multiple myeloma or Waldenström’s macroglobulinemia was characterized by differential scanning calorimetry and HevyLite™ (HLC) assay. The thermodynamic properties of the thermograms and their deviation from the typical healthy thermogram were found to correlate with the monoclonal protein concentration and the level of the involved (monoclonal) IgM heavy/light chains. Patients monitoring during treatment showed that the variations in the shape of the DSC profiles corresponded to fluctuations of the IgM heavy/light chain levels verifying the two parameters as non-invasive markers for disease progression.

  15. Exposure levels to radiation in a nuclear medicine laboratory: measurements with thermoluminescence dosemeters; Niveles de exposicion a la radiacion en un laboratorio de medicina nuclear: mediciones con dosimetros de termoluminiscencia

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz J, A. [Departamento de Medicina Nuclear del Instituto nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico D.F. (Mexico)

    2000-07-01

    Since 1996 in the Nuclear medicine Department and another routine and research departments of the National Institute of Medical and Nutrition Sciences (INCMNSZ) are working at least with 12 radioactive sources opened and sealed. However, it was unknown if with the Tl personal dosemeters with lithium fluoride crystals (LiF), could be possible to receive information about the equivalent dose for each radionuclide or if there was some radionuclide that by being low energy emissor or beta energy emissor, it did not represent an ionization power sufficient to excite the crystals of the thermoluminescent dosemeters (DTL). In this work the obtained results with control dosemeters of diverse source opened or sealed are shown, which were put at 1 cm of the LiF crystals during a time exposure 18 hours. Therefore the objective of this work is to verify which sources excite or not to DTL crystals and taking the pertinent safety measures for each radionuclide. The conclusion is that the majority of dosemeters were excited by beta or gamma radiation of the radionuclides and that LiF crystals are able to receive equivalent doses until 1200 mSv, being this a guarantee for the staff, that in an any moment could be exposed to high dose in his working day. Also it was corroborated that the radionuclides more energizer are: iodine-131, iodine-125 and sodium-22 while the phosphorus-32 must be managed with careful, since the exposure to hands can result significant, just like the technetium-99m ({sup 99m} Tc). (Author)

  16. New ICRU quantities for the environmental and individual monitoring. Standardization of individual dosemeters by using external beams of photon radiation; Nuevas magnitudes ICRU para la vigilancia radiologica ambiental e individual. Calibracion de dosimetros personales usando haces externos de fotones

    Energy Technology Data Exchange (ETDEWEB)

    Brosed, A.; Delgado, A.; Granados, C. E.

    1987-07-01

    The quantities introduced by ICRU for the radiological monitoring are commented, specially those implied in individual protection against external photons. A procedure is proposed in order to standardize the individual dosemeters by using the kerma in air references of CIEMAT-JEN. The reference radiation beams are described in connection with ISO standards. Provisional values are selected for the appropriate conversion and correction factors. (Author) 23 refs.

  17. Relative thermoluminescent efficiencies proton/gamma and helium/gamma of high temperature peaks in TLD-100 dosemeters; Eficiencias termoluminiscentes relativas proton/gamma y helio/gamma de picos de alta temperatura en dosimetros TLD-100

    Energy Technology Data Exchange (ETDEWEB)

    Flores M, E.; Avila, O.; Rodriguez V, M. [ININ, 52750 La Marquesa, Estado de Mexico (Mexico); Massillon, J.L.G.; Buenfil A, E.; Ruiz T, C.; Brandan, M.E. [IFUNAM, 04500 Mexico D.F. (Mexico); Gamboa De Buen, I. [ICN-UNAM, 04500 Mexico D.F. (Mexico)

    2007-07-01

    This work presents measures of relative thermoluminescent efficiency of those high temperature peaks of TLD-100 dosemeters exposed to protons of 1.5 MeV and to helium nuclei of 3 and 7.5 MeV. A rigorous reading and of deconvolution protocol was used for the calculation of the TL efficiencies. Additionally an Excel program that facilitated the deconvolution adjustment process of the glow curves was elaborated. (Author)

  18. Combined online spectroscopic, calorimetric, and chemometric analysis: reaction enthalpy determinations in single and parallel reactions.

    Science.gov (United States)

    Tjahjono, Martin; Widjaja, Effendi; Garland, Marc

    2009-06-02

    Calorimetry and signal processing: Vibrational spectroscopies, heat-flow microcalorimetry, and multivariate analysis are combined to decouple the reaction enthalpies of parallel reactions [picture: see text]. This methodology allows the evaluation of reaction enthalpy from complex systems without recourse to conventional kinetic modeling. Simultaneous in situ/online spectroscopy and heat-flow measurements as well as multivariate analyses are performed, apparently for the first time, to determine heats of reaction for single and parallel reactions. Two different vibrational spectroscopy techniques, namely Raman and FTIR spectroscopy, are used in conjunction with flow-through TAM III microcalorimetry. With respect to the spectroscopic analysis, the reaction spectra are first analyzed to determine the pure-component spectra and the corresponding concentrations without recourse to external calibration. With respect to the calorimetric analysis, a soft modeling approach is employed to determine the heats of reaction without recourse to any conventional kinetic models. This combined approach is implemented to determine the extents of reaction as well as the corresponding heats of reaction at 298.15 K and 0.1 MPa for a) the hydrolysis of acetic anhydride (single reaction) and b) the hydrolysis of methyl paraben and ethyl paraben in alkaline solution (both single and parallel reactions). In the latter case, the heat-flow contributions from the two simultaneous reactions are successfully decoupled. Taken together, these results demonstrate proof of concept for the present approach. The newly developed methodology appears to be quite general and particularly useful for investigating complex reaction systems. This is particularly true for multiple simultaneous reactions and reactions where the detailed kinetic expressions are not available, or cannot be easily determined. The use of extents of reaction is also very helpful where there is high variability in reaction rates

  19. A high-temperature calorimetric flow sensor employing ion conduction in zirconia

    Science.gov (United States)

    Persson, A.; Lekholm, V.; Thornell, G.; Klintberg, L.

    2015-05-01

    This paper presents the use of the temperature-dependent ion conductivity of 8 mol % yttria-stabilized zirconia (YSZ8) in a miniature high-temperature calorimetric flow sensor. The sensor consists of 4 layers of high-temperature co-fired ceramic (HTCC) YSZ8 tape with a 400 μm wide, 100 μm deep, and 12 500 μm long internal flow channel. Across the center of the channel, four platinum conductors, each 80 μm wide with a spacing of 160 μm, were printed. The two center conductors were used as heaters, and the outer, up- and downstream conductors were used to probe the resistance through the zirconia substrate around the heaters. The thermal profile surrounding the two heaters could be made symmetrical by powering them independently, and hence, the temperature sensing elements could be balanced at zero flow. With nitrogen flowing through the channel, forced convection shifted the thermal profile downstream, and the resistance of the temperature sensing elements diverged. The sensor was characterized at nitrogen flows from 0 to 40 sccm, and resistances at zero-flow from 10 to 50 MΩ. A peak sensitivity of 3.1 MΩ/sccm was obtained. Moreover, the sensor response was found to be linear over the whole flow range, with R2 of around 0.999, and easy to tune with the individual temperature control of the heaters. The ability of the sensor to operate in high temperatures makes it promising for use in different harsh environments, e.g., for close integration with microthrusters.

  20. High-resolution differential scanning calorimetric analysis of the subunits of Escherichia coli aspartate transcarbamoylase.

    Science.gov (United States)

    Edge, V; Allewell, N M; Sturtevant, J M

    1985-10-08

    The thermal denaturation of the catalytic (c3) and regulatory (r2) subunits of Escherichia coli aspartate transcarbamoylase (c6r6) in the absence and presence of various ligands has been studied by means of highly sensitive differential scanning calorimetry. The denaturation of both types of subunit is irreversible as judged by the facts that the proteins coagulate when heated and that no endotherm is observed when previously scanned protein is rescanned. Despite this apparent irreversibility, there is empirical justification for analyzing the calorimetric data in terms of equilibrium thermodynamics as embodied in the van't Hoff equation. The observed curves of excess apparent specific heat vs. temperature are asymmetric and can be expressed within experimental uncertainty as the sums of sequential two-state steps, a minimum of two steps being required for r2 and three for c3. As previously reported [Vickers, K. P., Donovan, J. W., & Schachman, H. K. (1978) J. Biol. Chem. 253, 8493-8498], the addition of the effectors ATP and CTP raises the denaturation temperature of r2 and lowers that of c3 while the addition of the bisubstrate analogue N-(phosphonoacetyl)-L-aspartate raises the denaturation temperature of c3 and lowers that of r2. These effects vary with ligand concentration in the manner expected from the van't Hoff equation, indicating that they are simply manifestations of Le Chatelier's principle rather than being due to "stabilization" or "destabilization" of the proteins. The denaturational enthalpy is increased in those cases of ligand binding in which the denaturation temperature is increased, because of the contribution from the enthalpy of dissociation of the ligand.

  1. Calorimetric studies of dissolution of hydroxypropyl methylcellulose E5 (HPMC E5) in water.

    Science.gov (United States)

    Joshi, H N; Wilson, T D

    1993-10-01

    The interaction of water with polymers is important because it directly or indirectly affects various properties such as rheological and transport properties. In this study, the hydration/dissolution of a hydrophilic polymer was investigated by calorimetric techniques. Hydroxypropyl methylcellulose E5 (Methocel, HPMC E5) was used as the model polymer. A water-insoluble, hydrophobic polymer, ethyl cellulose E4 (Ethocel, EC E4), was selected for comparison. The number of moles of non-freezing and freezing water were determined by differential scanning calorimetry. Moles of non-freezing water per polymer repeat unit were 6.2 +/- 1.3 and 1.6 +/- 0.3 for HPMC E5 and EC E4, respectively. The hydration/dissolution of HPMC E5 was exothermic, with a total heat of dissolution of -24.1 +/- 1.1 cal/g (n = 4). The heat of hydration of water-insoluble EC E4 was -2.6 cal/g (n = 2). The specific heat capacity value of HPMC E5 increased due to the addition of water. The heat of solution and an increase in specific heat capacity values were associated mainly with the addition of tightly bound water to the polymer. The dissolution of HPMC E5 in water is believed to have endothermic and exothermic components. In summary, the study provided insight into the dissolution of a representative hydrophilic polymer in water. The heat of solution and the specific heat capacity values were mainly dependent on the addition of tightly bound water.

  2. Thermoluminescent response of dosemeters TLD-100 exposed to distinct baker protocols, irradiation and reading; Respuesta termoluminiscente de dosimetros TLD-100 sujetos a distintos protocolos de horneado, irradiacion y lectura

    Energy Technology Data Exchange (ETDEWEB)

    Estrada E, D

    2002-07-01

    The interest that motivated the realization of this work is the opposing discrepancy among the values of the efficiency thermoluminescent of heavy charged particles (PCP) regarding gamma radiation ({eta}{sub PCP}, {gamma}) reported in different works and gathered recently for Horowitz (Ho 01). The measures of relative thermoluminescent efficiency have importance in relation to the dosimetry associated to medical therapy with heavy charged particle. The measurement of {eta}{sub PCP}, {gamma} depends of multiple experimental factors. To understand this dependence it was quantified the effect of using different procedures experimental in the estimate of the relative thermoluminescent efficiency of dosemeters TLD-100 (LiF: Ti; Mg) for protons of 3 MeV regarding gamma rays of {sup 60}Co ({eta}{sub PCP}, {gamma}), varying the lot, the presentation, the one baked and the team reader. When was used the same global procedure values they were obtained for ({eta}{sub PCP}, {gamma}) inside the interval [0.30, 0.58] for the peak 5 and [0.35, 0.76] for the total thermoluminescent signal (Tl). At the use different equipment, baked and lot are obtained maximum differences of 30%, 12% and 6% respectively in the values of ({eta}{sub PCP}, {gamma}) for the peak 5, and 25%, 28% and 7% for the total Tl signal. The changes more significant of 36% and 44% for peak 5 and total signal respectively are obtained when changing the presentation of the dosemeter. As a complementary investigation it was studied the distribution of the Tl signal of each peak in the deconvolution of the curve of brightness with regard to the total signal in exposed dosemeters to high fluence of protons (1x10{sup 10} p/cm{sup 2}) varying the experimental protocol. It was found that the distribution of the Tl signal has a difference of the order of 5% when changing the used reading team. It was observed that the contribution of the peak 5 regarding the total signal are preserved when changing baked and that it

  3. Identification of Synchronous Machine Magnetization Characteristics From Calorimetric Core-Loss and No-Load Curve Measurements

    OpenAIRE

    Rasilo, Paavo; Abdallh, Ahmed Abou-Elyazied; Belahcen, Anouar; Arkkio, Antero; Dupre, Luc

    2015-01-01

    The magnetic material characteristics of a wound-field synchronous machine are identified based on global calorimetric core-loss and no-load curve measurements. This is accomplished by solving a coupled experimental-numerical electromagnetic inverse problem, formulated to minimize the difference between a finite-element (FE) simulation-based Kriging surrogate model and the measurement results. The core-loss estimation in the FE model is based on combining a dynamic iron-loss model and a static v...

  4. Spectroscopic and calorimetric studies on the interaction between PAMAM G4-OH and 5-fluorouracil in aqueous solutions

    Science.gov (United States)

    Buczkowski, Adam; Urbaniak, Pawel; Piekarski, Henryk; Palecz, Bartlomiej

    2017-01-01

    The results of spectroscopic measurements (an increase in solubility, equilibrium dialysis, 1H NMR titration) and calorimetric measurements (isothermal titration ITC) indicate spontaneous (ΔG solution. PAMAM G4-OH dendrimer bonds about n = 8 ± 1 molecules of the drug with an equilibrium constant of K = 70 ± 10. The process of saturating the dendrimer active sites by the drug molecules is exothermal (ΔH 0). The parameters of binding 5-fluorouracil by PAMAM G4-OH dendrimer were compared with those of binding this drug by the macromolecules of PAMAM G3-OH and G5-OH.

  5. Testing phase changes in Al-Si alloys with application of thermal analysis and differential calorimetric analysis

    Directory of Open Access Journals (Sweden)

    J. Piątkowski

    2013-10-01

    Full Text Available The paper presents enthalpy of melting and solidification of casting aluminium alloys AlSi6, AlSi12 and AlSi18 during heating and cooling. Calorimetric measurements preceded by tests of thermal analysis ATD were conducted on high-temperature scanning calorimeter multi HTC. A direct method was used for determining parameters of hightemperature processes and enthalpies occurring in phase changes. This method allowed for precise determining of endothermic and exothermic phase changes and, on their basis, the characteristic parameters of solidification necessary to assess the thermal endurance were marked.

  6. Thermoluminescent and optical processes in alkaline halogenides dosemeters contaminated with Europium; Procesos opticos y termoluminiscentes en dosimetros de halogenuros alcalinos contaminados con Europio

    Energy Technology Data Exchange (ETDEWEB)

    Barboza F, M.; Melendrez, R.; Castaneda, B.; Pedroza M, M.; Chernov, V.; Perez S, R.; Aceves, R. [Centro de Investigacion en Fisica, Universidad de Sonora, A.P. 5-088, 83190 Hermosillo, Sonora (Mexico)

    2000-07-01

    Recent research results are presented about the properties of the optical processes of photo transferred thermoluminescence (TLFT), optical whitening (BO), thermoluminescence induced by light (TLL) and its effect in the thermoluminescent curve (Tl) produced by ionizing and non-ionizing radiation. The systematic analysis of all these processes, acquires a singular importance due that actually the alkaline halogenide crystals are object of intense investigations which analyse their potential applications as detectors and radiation dosemeters through stimulated optical luminescence techniques or thermoluminescence. The obtained data show that the Tl curve of material with this nature can be enormously affected by exposure of phosphorus to the environmental light or UV. This is in part due to liberation processes of charge bearers are shouted and makes a subsequent trapping in less temperature traps; at the same time that induce changes in the intensity of determined Tl bands. Additionally, also it is observed that mentioned phenomena are related as with wavelength of incident light as of the illumination time. Finally, the obtained information allows to conclude that although the illumination effect is extremely complex, it is associated and can be explained mainly with phenomena that implicate the electrons excitation trapped in form of F centers and trapping mechanisms or radioactive and non-radioactive recombination. (Author)

  7. Mensuration of equivalent dose with personal dosemeters and instruments of radiological protection in the new operative magnitudes ICRU, for external fields of beta radiation. Part I. Study of the homogeneity of the response personal dosemeters leaves (cards G-1, TLD-100), in radiation fields of Co{sub 60}; Medicion de dosis equivalente con dosimetros personales e instrumentos de proteccion radiologica en las nuevas magnitudes operativas ICRU, para campos de radiacion beta externos. Parte I. Estudio de la homogeneidad de la respuesta dosimetros personales (tarjetas G-1, TLD-100), en campos de radiacion de Co{sub 60}

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez R, J.T. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    1994-01-15

    A sample of 40 composed personal dosemeters by cards model: G-l, (each card is made up of two TLD-100 crystals encapsulated in teflon), Harshaw trademark; those personal dosemeters present a free window and another with a filter of A1 of 171.7 mg cm{sup -2} of mass thickness.The objective of the work is to select of this sample of 40 personal dosemeters a population with the same stocking and standard deviation. The technique used is that of comparison of stockings, (ANOVA; Variance Analysis, when samples of the same one were had size; and/or GLM, Widespread Lineal Models, when the samples were of different size), by means of the use of those Duncan statistics, SNK, Tukey, Gabriel; the results are validated proving the kindness of adjustment of the experimental data to a Normal distribution by means of the Shapiro-Wilks statistics.The experimental design used consists on a test of two vias: a via is the variable card with two levels, (crystal 1 and 2), the other via is the variable irradiation position with four levels, (LS=left superior, SR= right superior, LI= left Inferior, IR = right inferior). The irradiations carried out in blocks of four personal dosemeters in a gamma radiation beam range of Cobalt 60; carrying out three repetitions of the design. With object of proving the homogeneity of the filter of A1 in those personal dosemeters the experimental design was executed for those cards without personal dosemeters.They were also carried out tests of stockings to the readings of bottom and sensibility of the reader equipment, (Harshaw, model marks 2271), certain that doesn{sup t} exist differences for sequence of reading, but if in the stockings of the sensibility, (they were 4 different populations). The responses of the dosemeters were corrected subtracting him the reading correspondence of bottom and by sensibility of the reader equipment before subjecting them to the tests of stockings mentioned. Of the results of the tests of stockings for the cards with

  8. Investigation of a zirconia co-fired ceramic calorimetric microsensor for high-temperature flow measurements

    Science.gov (United States)

    Lekholm, Ville; Persson, Anders; Klintberg, Lena; Thornell, Greger

    2015-06-01

    This paper describes the design, fabrication and characterization of a flow sensor for high-temperature, or otherwise aggressive, environments, like, e.g. the propulsion system of a small spacecraft. The sensor was fabricated using 8 mol% yttria stabilized zirconia (YSZ8) high-temperature co-fired ceramic (HTCC) tape and screen printed platinum paste. A calorimetric flow sensor design was used, with five 80 µm wide conductors, separated by 160 µm, in a 0.4 mm wide, 0.1 mm deep and 12.5 mm long flow channel. The central conductor was used as a heater for the sensor, and the two adjacent conductors were used to resistively measure the heat transferred from the heater by forced convection. The two outermost conductors were used to study the influence of an auxiliary heat source on the sensor. The resistances of the sensor conductors were measured using four-point connections, as the gas flow rate was slowly increased from 0 to 40 sccm, with different power supplied through the central heater, as well as with an upstream or downstream heater powered. In this study, the thermal and electrical integrability of microcomponents on the YSZ8 substrate was of particular interest and, hence, the influence of thermal and ionic conduction in the substrate was studied in detail. The effect of the ion conductivity of YSZ8 was studied by measuring the resistance of a platinum conductor and the resistance between two adjacent conductors on YSZ8, in a furnace at temperatures from 20 to 930 °C and by measuring the resistance with increasing current through a conductor. With this design, the influence of ion conductivity through the substrate became apparent above 700 °C. The sensitivity of the sensor was up to 1 mΩ sccm-1 in a range of 0-10 sccm. The results show that the signal from the sensor is influenced by the integrated auxiliary heating conductors and that these auxiliary heaters provide a way to balance disturbing heat sources, e.g. thrusters or other electronics, in

  9. Calorimetric and spectroscopic studies of aminoglycoside binding to AT-rich DNA triple helices

    Science.gov (United States)

    Xi, Hongjuan; Kumar, Sunil; Dosen-Micovic, Ljiljana; Arya, Dev P.

    2013-01-01

    Calorimetric and fluorescence techniques were used to characterize the binding of aminoglycosides-neomycin, paromomycin, and ribostamycin, with 5′-dA12-x-dT12-x-dT12-3′ intramolecular DNA triplex (x = hexaethylene glycol) and poly(dA).2poly(dT) triplex. Our results demonstrate the following features: (1) UV thermal analysis reveals that the Tm for triplex decreases with increasing pH value in the presence of neomycin, while the Tm for the duplex remains unchanged. (2) The binding affinity of neomycin decreases with increased pH, although there is an increase in observed binding enthalpy. (3) ITC studies conducted in two buffers (sodium cacodylate and MOPS) yield the number of protonated drug amino groups (Δn) as 0.29 and 0.40 for neomycin and paromomycin interaction with 5′-dA12-x-dT12-x-dT12-3′, respectively. (4) The specific heat capacity change (ΔCp) determined by ITC studies is negative, with more negative values at lower salt concentrations. From 100 mM to 250 mM KCl, the ΔCp ranges from −402 to −60 cal/(mol K) for neomycin. At pH 5.5, a more positive ΔCp is observed, with a value of −98 cal/(mol K) at 100 mM KCl. ΔCp is not significantly affected by ionic strength. (5) Salt dependence studies reveal that there are at least three amino groups of neomycin participating in the electrostatic interactions with the triplex. (6) FID studies using thiazole orange were used to derive the AC50 (aminoglycoside concentration needed to displace 50% of the dye from the triplex) values. Neomycin shows a seven fold higher affinity than paromomycin and eleven fold higher affinity than ribostamycin at pH 6.8. (7) Modeling studies, consistent with UV and ITC results, show the importance of an additional positive charge in triplex recognition by neomycin. The modeling and thermodynamic studies indicate that neomycin binding to the DNA triplex depends upon significant contributions from charge as well as shape complementarity of the drug to the DNA triplex

  10. Calorimetric determination of the enthalpy of 1-butyl-3-methylimidazolium bromide synthesis: a key quantity in thermodynamics of ionic liquids.

    Science.gov (United States)

    Paulechka, Yauheni U; Kabo, Andrey G; Blokhin, Andrey V

    2009-11-05

    The enthalpy of the 1-butyl-3-methylimidazolium bromide [C(4)mim]Br ionic liquid synthesis reaction 1-methylimidazole (liq) + 1-bromobutane (liq) --> [C(4)mim]Br (liq) was determined in a homemade small-volume isoperibol calorimeter to be Delta(r)H degrees (298) = -87.7 +/- 1.6 kJ x mol(-1). The activation energy for this reaction in a homogeneous system E(A) = 73 +/- 4 kJ x mol(-1) was found from the results of calorimetric measurements. The formation enthalpies for the crystalline and liquid [C(4)mim]Br were determined from the calorimetric data: Delta(f)H degrees (298)(cr) = -178 +/- 5 kJ x mol(-1) and Delta(f)H degrees (298)(liq) = -158 +/- 5 kJ x mol(-1). The ideal-gas formation enthalpy of this compound Delta(f)H degrees (298)(g) = 16 +/- 7 kJ x mol(-1) was calculated using the methods of quantum chemistry and statistical thermodynamics. The vaporization enthalpy of [C(4)mim]Br, Delta(vap)H degrees (298) = 174 +/- 9 kJ x mol(-1), was estimated from the experimental and calculated formation enthalpies. It was demonstrated that vapor pressure of this ionic liquid cannot be experimentally determined.

  11. Estimating free-energy barrier heights for an ultrafast folding protein from calorimetric and kinetic data.

    Science.gov (United States)

    Godoy-Ruiz, Raquel; Henry, Eric R; Kubelka, Jan; Hofrichter, James; Muñoz, Victor; Sanchez-Ruiz, Jose M; Eaton, William A

    2008-05-15

    Differential scanning calorimetry was used to measure the temperature dependence of the absolute heat capacity of the 35-residue subdomain of the villin headpiece, a protein that folds in 5 mus and is therefore assumed to have a small free-energy barrier separating folded and unfolded states. To obtain an estimate of the barrier height from the calorimetric data, two models, a variable-barrier model and an Ising-like model, were used to fit the heat capacity in excess of the folded state over the temperature range 15-125 degrees C. The variable-barrier model is based on an empirical mathematical form for the density of states, with four adjustable parameters and the enthalpy (H) as a reaction coordinate. The Ising-like model is based on the inter-residue contact map of the X-ray structure with exact enumeration of approximately 10(5) possible conformations, with two adjustable parameters in the partition function, and either the fraction of native contacts (Q) or the number of ordered residues (P) as reaction coordinates. The variable-barrier model provides an excellent fit to the data and yields a barrier height at the folding temperature ranging from 0.4 to 1.1 kcal mol(-1), while the Ising-like model provides a less good fit and yields barrier heights of 2.3 +/- 0.1 kcal mol(-1) and 2.1 +/- 0.1 kcal mol(-1) for the Q and P reaction coordinates, respectively. In both models, the barrier to folding increases with increasing temperature. Assuming a sufficiently large activation energy for diffusion on the free-energy surfaces, both models are consistent with the observation of a temperature-independent folding rate in previously published laser temperature-jump experiments. Analysis of this kinetic data, using an approximate form for the pre-exponential factor of Kramers theory and the 70 ns relaxation time for the fast phase that precedes the unfolding/refolding relaxation to determine the diffusion coefficient, results in a barrier height of 1.6 +/- 0.3 kcal mol

  12. Thermogravimetric and calorimetric characteristics during co-pyrolysis of municipal solid waste components.

    Science.gov (United States)

    Ansah, Emmanuel; Wang, Lijun; Shahbazi, Abolghasem

    2016-10-01

    The thermogravimetric and calorimetric characteristics during pyrolysis of wood, paper, textile and polyethylene terephthalate (PET) plastic in municipal solid wastes (MSW), and co-pyrolysis of biomass-derived and plastic components with and without torrefaction were investigated. The active pyrolysis of the PET plastic occurred at a much higher temperature range between 360°C and 480°C than 220-380°C for the biomass derived components. The plastic pyrolyzed at a heating rate of 10°C/min had the highest maximum weight loss rate of 18.5wt%/min occurred at 420°C, followed by 10.8wt%/min at 340°C for both paper and textile, and 9.9wt%/min at 360°C for wood. At the end of the active pyrolysis stage, the final mass of paper, wood, textile and PET was 28.77%, 26.78%, 21.62% and 18.31%, respectively. During pyrolysis of individual MSW components at 500°C, the wood required the least amount of heat at 665.2J/g, compared to 2483.2J/g for textile, 2059.4J/g for paper and 2256.1J/g for PET plastic. The PET plastic had much higher activation energy of 181.86kJ/mol, compared to 41.47kJ/mol for wood, 50.01kJ/mol for paper and 36.65kJ/mol for textile during pyrolysis at a heating rate of 10°C/min. H2O and H2 peaks were observed on the MS curves for the pyrolysis of three biomass-derived materials but there was no obvious H2O and H2 peaks on the MS curves of PET plastic. There was a significant interaction between biomass and PET plastic during co-pyrolysis if the biomass fraction was dominant. The amount of heat required for the co-pyrolysis of the biomass and plastic mixture increased with the increase of plastic mass fraction in the mixture. Torrefaction at a proper temperature and time could improve the grindability of PET plastic. The increase of torrefaction temperature and time did not affect the temperature where the maximum pyrolytic rates occurred for both biomass and plastic but decreased the maximum pyrolysis rate of biomass and increased the maximum pyrolysis

  13. Determination of kinetic parameters in Tl dosemeters of LiF: Mg, Cu, P + PTFE developed in the ININ; Determinacion de parametros cineticos en dosimetros Tl de LiF: Mg, Cu, P + PTFE desarrollados en el ININ

    Energy Technology Data Exchange (ETDEWEB)

    Basurto G, B.S

    2002-07-01

    The objective of this work, is the one of determining the kinetic parameters of the dosemeter of LiF: Mg, Cu, P + Ptfe; starting from the curves Tl obtained at being irradiated with alpha radiation ({alpha}), beta ({beta}) and gamma ({gamma}). As like to compare its sensitivity with each radiation type, considering the sensitivity of the TLD-100 as the unit. In the Chapter 1, the fundamental structure of the matter is described, making emphasis in the different radiation types, and their interaction with this. In the Chapter 2, the units are described but used in the dosimetry of the radiation. In the Chapter 3, the basic concepts of the phenomenon of Tl are described and those are explained characteristic of the deconvolution method to determine the kinetics of the one phenomenon. In the Chapter 4, the methodology is detailed that was used in the elaboration of this thesis work, describing the material Tl that were considered like reference, as well as the sources of ionizing radiation, with those that the dosemeters were irradiated and the equipment in the one that the curves Tl was obtained. Reference is made to the software used to carry out the deconvolution of the curves Tl that were obtained in the one experimental development. In the Chapter 5, the obtained results of this study are presented, showing the tables of homogenization of dosemeters and the reading of the same one; they are observed the curves Tl obtained to different radiation doses (alpha, beta and gamma), the intensity Tl in function of the dose. Also they are tabulated, the obtained results in the kinetic parameters of the three different study materials (TLD-100H, USA; TLD-100, USA and LiF: Mg, Cu, P + Ptfe developed in the l.N.l.N). They are analyzed shortly for each material Tl their sensitivity to the ionizing radiation as well as their kinetic parameters. The obtained results showed that the Tl dosemeters of LiF: Mg,Cu,P + Ptfe, they presented a bigger sensitivity that the TLD-100 when

  14. Pulsed X-rays for interventional radiology: tests on active personal dosemeters (APD) (European project FP7 ORAMED WP3); Rayons X pulses pour la radiologie interventionnelle: tests sur dosimetres personnel actifs

    Energy Technology Data Exchange (ETDEWEB)

    Denoziere, M.; Bordy, J.M.; Daures, J.; Lecerf, N

    2009-07-01

    this report presents the results of the tests performed on Active Personal dosemeters (A.P.D.) to check their responses in pulsed X-ray beam used in interventional X-ray radiology. this work is one of the goal of O.R.A.M.E.D W.P.3. (Optimization of radiation protection for medical staff)The response of seven A.P.D.s types was measured in terms of dose equivalent Hp (10) for different pulsed X-ray width and dose rate. (author)

  15. Obtention of thermoluminescent efficiencies by means of irradiation of TLD-100 dosemeters with proton beams helium and carbon; Obtencion de eficiencias termoluminiscentes mediante irradiacion de dosimetros TLD-100 con haces de protones, helios y carbon

    Energy Technology Data Exchange (ETDEWEB)

    Avila, O.; Rodriguez V, M.; Aviles, P.; Gamboa de Buen, I.; Buenfil, A.E.; Ruiz T, C.; Brandan, M.E. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2002-07-01

    In this work, the advances of a serial of measurements of relative efficiency thermoluminescent of heavy charged particles (PCP) with respect to gamma radiation for TLD-100, dosemeters of LiF: Mg,Ti manufactured by the Harshaw-Bicron company are reported. The PCP are essentials in the implementation of dosimetry associated with medical applications. The measurements before gamma radiation were carrying out using the Vickrad irradiator of the National Institute of Nuclear Research at dose of 1.663 Gy. The measures which are reported about protons, helium and carbon were realized using the Pelletron accelerator of the Physics Institute of the UNAM. (Author)

  16. Estudio de las interacciones OHÏ€ por espectroscopia infrarroja y calorimetría de solución

    Directory of Open Access Journals (Sweden)

    Nelly Rodríguez C.

    2009-06-01

    Full Text Available Se estudiaron las interacciones moleculares del tipo OH . . . Ï€ existentes entre algunos fenoles y el benceno, usando como solvente tetracloruro de carbono a 25°C, mediante calorimetría de solución y espectroscopia infrarroja. Las entalpias de formación de los complejos, calculadas por métodos calorimétricos en base a las ecuaciones de Bolles-Drago y de Lamberts-Zeegers-Huyskens y de acuerdo a los datos de constantes de equilibrio obtenidos por el método infrarrojo, resultaron ser del orden de —1 a —2 kcal/mol, valores que las sitúan entre las uniones más débiles.

  17. Measurements of Multi-Layer Insulation at High Boundary Temperature, using a Simple Non-Calorimetric Method

    CERN Document Server

    Mazzone, L; Rieubland, Jean Michel; Vandoni, Giovanna

    2002-01-01

    In spite of abundant literature, the thermal performance of Multi-Layer Insulation (MLI) still deserves dedicated investigation for specific applications, as the achievable insulation strongly depends on installation details. Furthermore, less accurate information is available for warm than for cold boundaries, since errors due to edge effects in small test benches increase strongly with warm boundary temperature. We establish here the thermal performance of MLI between 300 K and 77 K or 4 K, without bringing calorimetric methods into play, through the accurate measurement of a temperature profile. A cylinder in thin copper, wrapped with MLI, is cooled at one extremity while suspended under vacuum inside a sheath at room temperature. For known thermal conductivity and thickness of the tube, the heat flux can be inferred from the temperature profile. In-situ measurement of the thermal conductivity is obtained by applying a know heat flow at the warm extremity of the cylinder. Results, cross-checked with a cali...

  18. Thermodynamic properties of liquid silver-gallium alloys determined from e.m.f. and calorimetric measurements

    Energy Technology Data Exchange (ETDEWEB)

    Jendrzejczyk-Handzlik, Dominika, E-mail: djendrze@agh.edu.p [Laboratory of Physical Chemistry and Electrochemistry, Faculty of Non-Ferrous Metals, AGH University of Science and Technology, 30 Mickiewicza Ave., 30-059 Krakow (Poland); Fitzner, Krzysztof [Laboratory of Physical Chemistry and Electrochemistry, Faculty of Non-Ferrous Metals, AGH University of Science and Technology, 30 Mickiewicza Ave., 30-059 Krakow (Poland)

    2011-03-15

    The thermodynamic properties of the liquid Ag-Ga alloys were determined using e.m.f. and calorimetric methods. In the e.m.f. method, solid oxide galvanic cells were used with zirconia electrolyte. The cells of the type W,Ag{sub x}Ga{sub (1-x)},Ga{sub 2}O{sub 3}//ZrO{sub 2}+(Y{sub 2}O{sub 3})//FeO,Fe,W were used in the temperature range from 1098 K to 1273 K, and in the range of mole fraction from x{sub Ga} = 0.1 to x{sub Ga} = 1.0. At first, the Gibbs free energy of formation of pure solid gallium oxide, Ga{sub 2}O{sub 3}, from pure elements was derived. Using values of the measured e.m.f. for the cell with x{sub Ga} = 1.0, the following temperature dependence was obtained: {Delta}{sub f}G{sub m},Ga{sub 2}O{sub 3}{sup 0}({+-}4kJ{center_dot}mol{sup -1}J)=-1061.7235+0.2899T/K. Next, the activity of the gallium was derived as a function of the alloy composition from the values of the measured e.m.f. Activities of silver were calculated using the Gibbs-Duhem equation. The drop calorimetric measurements were carried out at two temperatures, viz. 923 K and 1123 K, using a Setaram MHTC calorimeter. Integral enthalpies of mixing of liquid binary alloys were determined at those temperatures. Finally, thermodynamic properties of the liquid alloys were described with the Redlich-Kister equation using ThermoCalc software.

  19. A Calorimetric Study of Almandine: Are the Thermodynamic Properties of the End-Member Aluminosilicate Garnets Finally Known Quantitatively?

    Science.gov (United States)

    Dachs, E.; Geiger, C. A.; Benisek, A.

    2012-12-01

    The aluminosilicate garnets (E3Al2Si3O12 with E = Fe2+, Mn2+, Ca, Mg) form an important rock-forming mineral group. Much study has been directed toward determining their thermodynamic properties. The iron end-member almandine (Fe3Al2Si3O12) is a key phase in many petrologic investigations. As part of an ongoing calorimetric and thermodynamic study of the aluminosilicate garnets, the heat capacity of three synthetic well-characterized polycrystalline almandine garnets and one natural almandine-rich single crystal was measured. The various garnets were characterized by optical microscopy, electron-microprobe analysis, X-ray powder diffraction and 57Fe Mössbauer spectroscopy. Heat capacity measurements were performed in the temperature range 3 to 300 K using relaxation calorimetry and between 282 and 764 K using DSC methods. From the former, So values between 336.7 ± 0.8 and 337.8 ± 0.8 J/molK are calculated for the different samples. The smaller value is considered the best So for end-member stoichiometric almandine, because it derives from the "best" Fe3+-free synthetic sample. The Cp behavior for almandine at T > 298 K is given by the polynomial (in J/molK): Cp = 649.06(±4) - 3837.57(±122)T-0.5 - 1.44682(±0.06)107T-2 + 1.94834(±0.09)109T-3, which is calculated using DSC data together with one published heat-content datum determined by transposed-drop calorimetry along with a new determination that gives H1181K - H302K = 415.0 ± 3.2 kJ/mole. Almandine shows a λ-type heat-capacity anomaly at low temperatures resulting from a paramagnetic-antiferromagnetic phase transition at about 9 K. The lattice heat capacity was calculated using the single-parameter phonon dispersion model of Komada and Westrum (1997), which allows the non-lattice heat capacity (Cex) behavior to be modelled. An analysis shows the presence of an electronic heat-capacity contribution (Cel - Schottky anomaly) around 17 K that is superimposed on a larger magnetic heat-capacity effect (Cmag

  20. New methodology for simultaneous volumetric and calorimetric measurements: Direct determination of {alpha}{sub p} and C{sub p} for liquids under pressure

    Energy Technology Data Exchange (ETDEWEB)

    Casas, L. M. [Departamento de Fisica Aplicada, Facultad de Ciencias Experimentales, Universidad de Vigo, Lagoas Marcosende s/n, 36310 Vigo (Spain); Plantier, F.; Bessieres, D. [Laboratoire de Thermodynamique et Energetique des Fluides Complexes-UMR 5150, Universite de Pau et des Pays de l' Adour, BP 1155, 64013 Pau (France)

    2009-12-15

    A new batch cell has been developed to measure simultaneously both isobaric thermal expansion and isobaric heat capacity from calorimetric measurements. The isobaric thermal expansion is directly proportional to the linear displacement of an inner flexible below and the heat capacity is calculated from the calorimetric signal. The apparatus used was a commercial Setaram C-80 calorimeter and together with this type of vessels can be operated up to 20 MPa and in the temperature range of 303.15-523.15 K, In this work, calibration was carried out using 1-hexanol and subsequently both thermophysical properties were determined for 3-pentanol, 3-ethyl-3-pentanol, and 1-octanol at atmospheric pressure, 5 and 10 MPa, and from 303.15 to 423.15 K in temperature. Finally experimental values were compared with the literature in order to validate this new methodology, which allows a very accurate determination of isobaric thermal expansion and isobaric heat capacity.

  1. New methodology for simultaneous volumetric and calorimetric measurements: direct determination of alpha(p) and C(p) for liquids under pressure.

    Science.gov (United States)

    Casás, L M; Plantier, F; Bessières, D

    2009-12-01

    A new batch cell has been developed to measure simultaneously both isobaric thermal expansion and isobaric heat capacity from calorimetric measurements. The isobaric thermal expansion is directly proportional to the linear displacement of an inner flexible below and the heat capacity is calculated from the calorimetric signal. The apparatus used was a commercial Setaram C-80 calorimeter and together with this type of vessels can be operated up to 20 MPa and in the temperature range of 303.15-523.15 K, In this work, calibration was carried out using 1-hexanol and subsequently both thermophysical properties were determined for 3-pentanol, 3-ethyl-3-pentanol, and 1-octanol at atmospheric pressure, 5 and 10 MPa, and from 303.15 to 423.15 K in temperature. Finally experimental values were compared with the literature in order to validate this new methodology, which allows a very accurate determination of isobaric thermal expansion and isobaric heat capacity.

  2. Determination of Nuclear Charge Distributions of Fission Fragments from ^{235}U (n_th, f) with Calorimetric Low Temperature Detectors

    Science.gov (United States)

    Grabitz, P.; Andrianov, V.; Bishop, S.; Blanc, A.; Dubey, S.; Echler, A.; Egelhof, P.; Faust, H.; Gönnenwein, F.; Gomez-Guzman, J. M.; Köster, U.; Kraft-Bermuth, S.; Mutterer, M.; Scholz, P.; Stolte, S.

    2016-08-01

    Calorimetric low temperature detectors (CLTD's) for heavy-ion detection have been combined with the LOHENGRIN recoil separator at the ILL Grenoble for the determination of nuclear charge distributions of fission fragments produced by thermal neutron-induced fission of ^{235}U. The LOHENGRIN spectrometer separates fission fragments according to their mass-to-ionic-charge ratio and their kinetic energy, but has no selectivity with respect to nuclear charges Z. For the separation of the nuclear charges, one can exploit the nuclear charge-dependent energy loss of the fragments passing through an energy degrader foil (absorber method). This separation requires detector systems with high energy resolution and negligible pulse height defect, as well as degrader foils which are optimized with respect to thickness, homogeneity, and energy loss straggling. In the present, contribution results of test measurements at the Maier Leibnitz tandem accelerator facility in Munich with ^{109}Ag and ^{127}I beams with the aim to determine the most suitable degrader material, as well as measurements at the Institut Laue-Langevin will be presented. These include a systematic study of the quality of Z-separation of fission fragments in the mass range 82le A le 132 and a systematic measurement of ^{92}Rb fission yields, as well as investigations of fission yields toward the symmetry region.

  3. Surfactants induced release of a red emitting dye from the nanocavity of a molecular container: A spectroscopic and calorimetric study.

    Science.gov (United States)

    Ahmed, Sayeed Ashique; Chatterjee, Aninda; Maity, Banibrata; Seth, Debabrata

    2016-08-01

    Supramolecular interaction of a red emitting dye Nile blue A (NBA) with Cucurbit[7]uril (CB7) in aqueous solution was studied and the release of the dye from the hydrophobic cavity of CB7 was reported. To investigate the supramolecular host-guest complex formation and release of dye, we have used the steady state absorption, fluorescence and time resolved fluorescence emission spectroscopy, (1)H NMR spectroscopy and isothermal titration calorimetry (ITC). The spectral properties of NBA were changed in the presence of CB7. The change in spectral features of NBA in presence of CB7 indicates the formation of supramolecular host-guest complexes. By using the SED equation the diameter of the complex was estimated. The complex formation further affirmed by the (1)H NMR study. Upfield and downfield shifts of the protons of NBA was observed in both the aliphatic and aromatic region. From the ITC measurement, we have drawn up the forces involved for the complexation of NBA with CB7. We have studied the release of NBA from the hydrophobic cavity of CB7 by using ionic, neutral surfactants and ionic liquid with the help of spectroscopic and calorimetric techniques. It is observed that on addition of SDS and ionic liquid (

  4. Evaluation of inductive heating energy of sub-size improved DPC-C conductor by calorimetric method

    Energy Technology Data Exchange (ETDEWEB)

    Ito, Toshinobu; Koizumi, Norikiyo; Wakabayashi, Hiroshi; Miura, Yuushi; Fujisaki, Hiroshi; Matsui, Kunihiro; Takahashi, Yoshikazu; Tsuji, Hiroshi [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan). Naka Fusion Research Establishment

    1996-08-01

    The improved DPC-U conductor consisting of 648 chrome plated NbTi strands was fabricated and its stability has been investigated using 1/24 sub-size conductor. In the stability experiment, the inductive heating method was applied to originate initial normal zone. Since it is difficult to calculate the inductive heating energy deposited on the conductor because of complicate geometry of the twisted multi-strand cable, inductive heating energy had to be experimentally evaluated using calorimetric method. The heating energy is in proportion to integration of square of an applied sinusoidal wave pulsed current over the heating period. The experimental result shows the proportional constants for the conductor and conduit are 2.062 x 10{sup -3} =J/A{sup 2}s= and 0.771 x 10{sup -3} =J/A{sup 2}s=, respectively. The coupling between the eddy currents in the strands and conduit might take effect on the heating energy put in the strands. It was shown this effect was however small in this experiment. Consequently, the inductive heating energy applied in the strands was estimated to be the proportional constant of 1.291 x 10{sup -3} =J/A{sup 2}s= from the difference of the heat energies in the conductor and conduit. (author)

  5. A Study of the Deformation, Network, and Aging of Polyethylene Oxide Films by Infrared Spectroscopy and Calorimetric Measurements

    Directory of Open Access Journals (Sweden)

    Carl Bergeron

    2012-01-01

    Full Text Available The calorimetric and infrared (IR spectroscopy measurements of polyethylene oxide (PEO are used to evaluate the deformation and relaxation that films experience during a temperature cycle (30°C–90°C–30°C. After melting, the intensity of some bands decreases by 10 to 70%. During the temperature cycle, the C–O band in the 1100 cm−1 region and the C–C–O deformation bands at 650 and 500 cm−1 show some new features. A network of cooperative oxygen-hydrogen interactions between the PEO chains form in films with special history, namely, in thermally treated films, in thin films prepared from gel forming solutions, and in thick films after aging. The interchain interaction network is suggested from the IR absorption bands in the 1200 and 900 cm−1 region and also from small bands at 1144 and 956 cm−1. The network seems absent or reduced in thin films. IR spectroscopy appears a sensitive technique to study chain conformations in PEO films and in other materials where order, disorder, and the formation of intermolecular interactions coexist.

  6. Calorimetric Low-Temperature Detectors for X-Ray Spectroscopy on Trapped Highly-Charged Heavy Ions

    Science.gov (United States)

    Kilbourne, Caroline; Kraft-Bermuth, S.; Andrianov, V.; Bleile, A.; Echler, A.; Egelhof, P.; Ilieva, S.; Kilbourne, C.; McCammon, D.

    2012-01-01

    The application of Calorimetric Low-Temperature Detectors (CLTDs) has been proposed at the Heavy-Ion TRAP facility HITRAP which is currently being installed at the Helmholtz Research Center for Heavy Ion Research GSI. This cold ion trap setup will allow the investigation of X-rays from ions practically at rest, for which the excellent energy resolution of CLTDs can be used to its full advantage. However, the relatively low intensities at HITRAP demand larger solid angles and an optimized cryogenic setup. The influence of external magnetic fields has to be taken into account. CLTDs will also be a substantial part of the instrumental equipment at the future Facility for Antiproton and Heavy Ion Research (FAIR), for which a wide variety of high-precision X-ray spectroscopy experiments has been proposed. This contribution will give an overview on the chances and challenges for the application of CLTDs at HITRAP as well as perspectives for future experiments at the FAIR facility.

  7. The B-Li System. Calorimetric and Theoretical Studies / Układ B-Li. Badania Kalorymetryczne I Teoretyczne

    Directory of Open Access Journals (Sweden)

    Dębski A.

    2015-12-01

    Full Text Available The standard enthalpy of formation of the B78Li22 alloy was measured with the use of the water reaction calorimetric method at 25 °C (298 K. An X-ray diffraction study of the prepared sample was conducted. The obtained diffraction pattern was different from the patterns for the B3Li and B14Li3 phases. The standard enthalpy of formation obtained for the B78Li22 alloy was -39.0 ± 0.7 kJ/mole of atoms. This value corresponds well with the formation enthalpies of the phases from the boron-lithium system. Theoretical calculations of the standard enthalpy of formation were conducted for the B78Li22 alloy and the phases from B-Li system, which were investigated earlier. A discussion of the deviations observed between both sets of data (experimental and calculated was performed. Additionally, DTA studies were performed for 14 alloys of the concentrations from 40 to 100 at. % of Li.

  8. Preliminary study on heat load using calorimetric measurement during long-pulse high-performance discharges on EAST

    Science.gov (United States)

    Liu, Y. K.; Hamada, N.; Hanada, K.; Gao, X.; Liu, H. Q.; Yu, Y. W.; Qian, J. P.; Yang, L.; Xu, T. J.; Jie, Y. X.; Yao, Y.; Wang, S. S.; Xu, J. C.; Yang, Z. D.; Li, G. S.; EAST Team

    2017-04-01

    Experimental Advanced Superconducting Tokamak (EAST) aims to demonstrate steady-state advanced high-performance H-mode plasmas with an ITER-like configuration, plasma control and heating schemes. The plasma-facing components in EAST are actively cooled, providing good conditions for researching long-pulse and high-energy discharges. A long-pulse high-performance plasma discharge (#59892 discharge) of up to 103 s with a core electron temperature of up to 4.5 keV was sustained with an injected energy exceeding 0.22 GJ in the 2015–2016 experimental campaign. A calorimetric measurement utilizing the temperature increment of cooling water is carried out to calculate the heat load on the strike point region of the lower divertor during long-pulse discharges in EAST. For the long-pulse and high-energy discharges, the comparison of the measurement results for the heat load measured by divertor Langmuir probes and the calorimetry diagnostic indicates that most of the heat load is delivered to the divertor panels as plasma, not radiation, and charge exchange neutrals. The ratio of the heat load on the strike point region of the lower divertor to the total injected energy is on average 42.5% per discharge with the lower single null divertor configuration. If the radiated energy loss measured by the fast bolometer diagnostic is taken into consideration, the ratio is found to be 61.6%. The experimental results and the analysis of the physics involved in these discharges are reported and discussed.

  9. Locating Malleable Bulk Metallic Glasses in Zr-Ti-Cu-Al Alloys with Calorimetric Glass Transition Temperature as an Indicator

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    We defined the plastic deformability under constrained loading conditions as malleability for bulk metallic glass (BMG) materials. Quaternary Zr-Ti-Cu-Al alloys in the Zr-rich composition range are selected to investigate the compositional dependence of malleability assessed by bending testing and glass transition temperature (Tg ). As indicated, increasing the Al or Cu concentration in the alloys leads to the rise of T g . The Zr(61)Ti2Cu(25)Al(12) (ZT1) and Zr(61.6)Ti(4.4)Cu(24)Al(10) (ZT3) alloys exhibit an optimal combination of lower T g and higher glass-forming ability. The malleable BMGs such as ZT1 manifests two characters during deformation, the stable propagation of a single shear band indicated by large shear offsets and easy proliferation of shear bands. With increasing the T g of BMG, the yield strength σy,Young's modulus and shear modulus simultaneously increase as well, while the Poisson s ratio decreases. The σy of ZT1 BMG is about 1680 MPa in compression and 1600 MPa in tension. In tensile loading, no any visible plasticity appears even when the strain rate increases up to the order of magnitude of 10(-1)s(-1). In consistent with the T g , malleability of Zr-Ti-Cu-Al BMGs manifests significant compositional dependence. The malleable BMG is associated with lower Tg , as well as lower shear modulus or higher Poisson s ratio, which can be understood on the basis of the correlation of Tg with shear energy barrier in metallic glass. Thus, the calorimetric Tg can be used as an indicator to screen malleable BMG-forming composition, with advantage of experimental accessibility.

  10. Energetics of the binding of phototoxic and cytotoxic plant alkaloid sanguinarine to DNA: Isothermal titration calorimetric studies

    Science.gov (United States)

    Adhikari, Anupam; Hossain, Maidul; Maiti, Motilal; Suresh Kumar, Gopinatha

    2008-10-01

    Sanguinarine is a medically important plant alkaloid with remarkable pharmacological and biological activities. DNA binding is considered to be an important aspect in its mode of action. Isothermal titration calorimetric technique was used for the first time to derive the thermodynamic aspects of the interaction of the phototoxic and cytotoxic plant alkaloid sanguinarine with natural calf thymus DNA and four synthetic DNAs of differing base pair sequences under various environmental conditions The affinity of binding of sanguinarine (iminium form) was found to be in the order of 10 5 M -1 to calf thymus DNA. The binding affinity to calf thymus DNA decreased with increase of ionic strength and temperature. The salt dependence of the binding data showed that release of 0.55 U of the cations per bound alkaloid. The binding of the iminium form was exothermic under all conditions, but the uncharged alkanolamine form showed no binding to DNA. The heat capacity changes obtained from the temperature dependence of enthalpy indicated a value of -140 cal/mol K. Sanguinarine showed high specificity to alternating purine-pyrimidine sequences with affinity of the order 10 6 M -1 and the affinity to the polynucleotides varied in the order poly(dG-dC)·poly(dG-dC) > poly(dA-dT)·poly(dA-dT) > poly(dA)·poly(dT) > poly(dG)·poly(dC). The binding to alternating GC polymer was exothermic and enthalpy driven, to the homo GC polymer was exothermic and favoured by both negative enthalpy and positive entropy changes, to the alternating AT polymer was exothermic and enthalpy driven while to the homo AT polymer was endothermic and entropy driven.

  11. In-Plane Thermal Diffusivity Measurement of Thin Films Based on the Alternating-Current Calorimetric Method Using an Optical Reflectivity Technique

    Institute of Scientific and Technical Information of China (English)

    黄正兴; 唐祯安; 许自强; 丁海涛; 顾毓沁

    2004-01-01

    An advanced ac calorimetric method to measure thermal diffusivity of a thin sample is developed by using an optical reflectivity technique. A modulated infrared laser is used to heat the front surface ofa foil specimen. The reflectivity of a continuous-wave He-Ne laser at the rear surface of the specimen is detected by a photoreceiver.According to the temperature dependence of reflectivity, the ac temperature response is obtained. Thermal diffusivity is deduced from a one-dimensional heat conduction equation. A stainless-steel foil and a copper foil are chosen as the samples. The present results agree well with the data in the literature.

  12. Trophic relay and prey switching - A stomach contents and calorimetric investigation of an ambassid fish and their saltmarsh prey

    Science.gov (United States)

    McPhee, Jack J.; Platell, Margaret E.; Schreider, Maria J.

    2015-12-01

    Trophic relay is an ecological model that involves the movement of biomass and energy from vegetation, such as saltmarshes, within estuaries to the open sea via a series of predator-prey relationships. Any potential for trophic relay is therefore affected by water movements within an estuary and by the ability of a predator to "switch" prey in response to fluctuating abundances of those prey. Saltmarsh-dwelling grapsid crabs, which feed on saltmarsh-derived detritus and microphytobenthos, release zoeae into ebbing tides that inundate saltmarshes during spring-tide cycles within tidally-dominated estuaries, such as Brisbane Water Estuary, therefore providing an opportunity to examine whether prey-switching and/or trophic relay may occur in fish that feed on those zoeae (such as the highly abundant estuarine ambassid, Ambassis jacksoniensis). This model was examined by sampling A. jacksoniensis near saltmarshes in a large, temperate south-eastern Australian estuary during flood and ebb tides on days of saltmarsh inundation and non-inundation over four spring-tide events in 2012. Stomach fullnesses of A. jacksoniensis were generally highest during ebb tides on days of saltmarsh inundation, implying that feeding was most marked at these times. Caridean decapods dominated diets during flood tides and on days of no saltmarsh inundation, while crab zoeae dominated diets during ebb tides and on days of inundation, suggesting that, when saltmarsh-derived zoeae became abundant, A. jacksoniensis switched to feeding on those prey. Three potential zooplankton prey (calanoid copepods, caridean decapods and crab zoeae) did not differ calorimetrically, indicating that switching of prey by A. jacksoniensis is not directly related to their preying on energetically greater prey, but reflects opportunistic feeding on more abundant and/or less elusive prey. As A. jacksoniensis is able to switch prey from estuarine caridean decapods to saltmarsh-derived crab zoeae, this very abundant

  13. Calorimetric measuring systems

    DEFF Research Database (Denmark)

    Ritchie, Andrew Ewen; Pedersen, John Kim; Blaabjerg, Frede

    2004-01-01

    the system cooling requirement. A common problem is that high-frequency phenomena like proximity effect, skin effect, hysteresis losses, and eddy current losses appear in the systems. These losses are very difficult to treat both theoretically and in practice. It is often difficult to measure the effect......Power Electronics remains an emerging technology. New materials, new devices, and new circuit topologies reduce the cost, weight, and volume for important applications [1]. Two important factors in power electronic circuits are the switching speed of the devices and the total power losses...... in the system. If the switching speed can be increased, improvements may be possible (e.g., current ripple in an electrical machine or physical size of passive components may be reduced). On the other hand, increased switching speed may cause additional losses in a power electronic system and increase...

  14. The ferrous ammonium sulfate solid system, as dosemeter for processes at low temperatures and high doses of gamma radiation; El sistema sulfato ferroso amoniacal solido, como dosimetro para procesos a bajas temperaturas y altas dosis de radiacion gamma

    Energy Technology Data Exchange (ETDEWEB)

    Juarez C, J.M.; Ramos B, S.; Negron M, A. [ICN-UNAM, 04510 Mexico D.F. (Mexico)

    2005-07-01

    This paper presents the results obtained from a study of the radiation induced oxidation of crystalline ferrous ammonium sulfate with gamma rays at 295 K, 263 K and 77 K and dose from 0 to 300 kGy. The radiation induced decomposition of ferrous ammonium sulfate has been studied by the dissolution of the irradiated salt in 0,8 N sulfuric acid. The main product is Fe{sup 3+} and molar concentration of ferric ion was determined spectrophotometrically in the UV region at 304 nm. The optical density values showed a linear dependence with dose, indicating that the data obtained might be used to create a calibrating curve. Color in irradiated salt changes from blue to green, yellow and orange according to the absorbed dose. The accuracy and the reproducibility of the system were tested. In addition, some other characteristics make possible the use of this system as a dosimeter, similar to Fricke chemical dosemeter, at low temperatures and high dose. (Author)

  15. The use of enriched 6Li and 7Li Lif:Mg,Cu,P glass-rod thermoluminescent dosemeters for linear accelerator out-of-field radiation dose measurements.

    Science.gov (United States)

    Takam, R; Bezak, E; Liu, G; Marcu, L

    2012-06-01

    (6)LiF:Mg,Cu,P and (7)LiF:Mg,Cu,P glass-rod thermoluminescent dosemeters (TLDs) were used for measurements of out-of-field photon and neutron doses produced by Varian iX linear accelerator. Both TLDs were calibrated using 18-MV X-ray beam to investigate their dose-response sensitivity and linearity. CR-39 etch-track detectors (Luxel+, Landauer) were employed to provide neutron dose data to calibrate (6)LiF:Mg,Cu,P TLDs at various distances from the isocentre. With cadmium filters employed, slow neutrons (neutrons. The average in-air photon dose equivalents per monitor unit (MU) ranged from 1.5±0.4 to 215.5±94.6 μSv at 100 and 15 cm from the isocentre, respectively. Based on the cross-calibration factors obtained with CR-39 etch-track detectors, the average in-air fast neutron dose equivalents per MU range from 10.6±3.8 to 59.1±49.9 μSv at 100 and 15 cm from the isocentre, respectively. Contribution of thermal neutrons to total neutron dose equivalent was small: 3.1±7.2 μSv per MU at 15 cm from the isocentre.

  16. A Search for Low-Mass Weakly Interacting Massive Particles Using Voltage-Assisted Calorimetric Ionization Detection in the SuperCDMS Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Agnese, R.; Anderson, A. J.; Asai, M.; Balakishiyeva, D.; Basu Thakur, R.; Bauer, D. A.; Billard, J.; Borgland, A.; Bowles, M. A.; Brandt, D.; Brink, P. L.; Bunker, R.; Cabrera, B.; Caldwell, D. O.; Cerdeno, D. G.; Chagani, H.; Cooley, J.; Cornell, B.; Crewdson, C. H.; Cushman, Priscilla B.; Daal, M.; Di Stefano, P. C.; Doughty, T.; Esteban, L.; Fallows, S.; Figueroa-Feliciano, E.; Godfrey, G. L.; Golwala, S. R.; Hall, Jeter C.; Harris, H. R.; Hertel, S. A.; Hofer, T.; Holmgren, D.; Hsu, L.; Huber, M. E.; Jastram, A.; Kamaev, O.; Kara, B.; Kelsey, M. H.; Kennedy, A.; Kiveni, M.; Koch, K.; Loer, B.; Lopez Asamar, E.; Mahapatra, R.; Mandic, V.; Martinez, C.; McCarthy, K. A.; Mirabolfathi, N.; Moffatt, R. A.; Moore, D. C.; Nadeau, P.; Nelson, R. H.; Page, K.; Partridge, R.; Pepin, M.; Phipps, A.; Prasad, K.; Pyle, M.; Qiu, H.; Rau, W.; Redi, P.; Reisetter, A.; Ricci, Y.; Saab, T.; Sadoulet, B.; Sander, J.; Schneck, K.; Schnee, Richard; Scorza, S.; Serfass, B.; Shank, B.; Speller, D.; Villano, A. N.; Welliver, B.; Wright, D. H.; Yellin, S.; Yen, J. J.; Young, B. A.; Zhang, J.

    2014-01-27

    SuperCDMS is an experiment designed to directly detect weakly interacting massive particles (WIMPs), a favored candidate for dark matter ubiquitous in the Universe. In this Letter, we present WIMP-search results using a calorimetric technique we call CDMSlite, which relies on voltage-assisted Luke-Neganov amplification of the ionization energy deposited by particle interactions. The data were collected with a single 0.6 kg germanium detector running for ten live days at the Soudan Underground Laboratory. A low energy threshold of (electron equivalent) was obtained, which allows us to constrain new WIMP-nucleon spin-independent parameter space for WIMP masses below 6 GeV/c2.

  17. Determination of the Temperature Change by Means of an Outcoming Signal of Electric Resistance in an Isoperibolic Calorimetric Cell. Obtainment of Heat Solution

    Directory of Open Access Journals (Sweden)

    Juan Carlos Moreno-Piraján

    2005-12-01

    Full Text Available An isoperibolic calorimetric cell is built with glass surrounded by plastic insulation. Thecell has a lid on which a thermistor thermometer, an electric resistance to provide the cell with definitequantities of electric work and a container for a glass ampoule, are placed. For measuring the thermalchanges, an NTC thermistor, which provides an electric resistance signal that varies with temperature,is used. Calibration curves of the thermistor and of the stabilization of the system signal in thermalequilibrium are shown, which enable the observation of a good insulation. The calorific capacity of thesystem with water, with a value of 206.7 ± 0.7 J °C-1 is determined; the solution enthalpy for propanolwaterand KCl-water systems is obtained, which shows the behavior of the cell before exothermic andendothermic effects, respectively.

  18. Search for Low-Mass Weakly Interacting Massive Particles Using Voltage-Assisted Calorimetric Ionization Detection in the SuperCDMS Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Agnese, R.; Anderson, A. J.; Asai, M.; Balakishiyeva, D.; Basu Thakur, R.; Bauer, D. A.; Billard, J.; Borgland, A.; Bowles, M. A.; Brandt, D.; Brink, P. L.; Bunker, R.; Cabrera, B.; Caldwell, D. O.; Cerdeno, D. G.; Chagani, H.; Cooley, J.; Cornell, B.; Crewdson, C. H.; Cushman, P.; Daal, M.; Di Stefano, P. C. F.; Doughty, T.; Esteban, L.; Fallows, S.; Figueroa-Feliciano, E.; Godfrey, G. L.; Golwala, S. R.; Hall, J.; Harris, H. R.; Hertel, S. A.; Hofer, T.; Holmgren, D.; Hsu, L.; Huber, M. E.; Jastram, A.; Kamaev, O.; Kara, B.; Kelsey, M. H.; Kennedy, A.; Kiveni, M.; Koch, K.; Loer, B.; Lopez Asamar, E.; Mahapatra, R.; Mandic, V.; Martinez, C.; McCarthy, K. A.; Mirabolfathi, N.; Moffatt, R. A.; Moore, D. C.; Nadeau, P.; Nelson, R. H.; Page, K.; Partridge, R.; Pepin, M.; Phipps, A.; Prasad, K.; Pyle, M.; Qiu, H.; Rau, W.; Redl, P.; Reisetter, A.; Ricci, Y.; Saab, T.; Sadoulet, B.; Sander, J.; Schneck, K.; Schnee, R. W.; Scorza, S.; Serfass, B.; Shank, B.; Speller, D.; Villano, A. N.; Welliver, B.; Wright, D. H.; Yellin, S.; Yen, J. J.; Young, B. A.; Zhang, J.

    2014-01-01

    SuperCDMS is an experiment designed to directly detect Weakly Interacting Massive Particles (WIMPs), a favored candidate for dark matter ubiquitous in the Universe. In this paper, we present WIMP-search results using a calorimetric technique we call CDMSlite, which relies on voltage- assisted Luke-Neganov amplification of the ionization energy deposited by particle interactions. The data were collected with a single 0.6 kg germanium detector running for 10 live days at the Soudan Underground Laboratory. A low energy threshold of 170 eVee (electron equivalent) was obtained, which allows us to constrain new WIMP-nucleon spin-independent parameter space for WIMP masses below 6 GeV/c2.

  19. CDMSlite: A Search for Low-Mass WIMPs using Voltage-Assisted Calorimetric Ionization Detection in the SuperCDMS Experiment

    CERN Document Server

    Agnese, R; Asai, M; Balakishiyeva, D; Thakur, R Basu; Bauer, D A; Billard, J; Borgland, A; Bowles, M A; Brandt, D; Brink, P L; Bunker, R; Cabrera, B; Caldwell, D O; Cerdeno, D G; Chagani, H; Cooley, J; Cornell, B; Crewdson, C H; Cushman, P; Daal, M; Di Stefano, P C F; Doughty, T; Esteban, L; Fallows, S; Figueroa-Feliciano, E; Godfrey, G L; Golwala, S R; Hall, J; Harris, H R; Hertel, S A; Hofer, T; Holmgren, D; Hsu, L; Huber, M E; Jastram, A; Kamaev, O; Kara, B; Kelsey, M H; Kennedy, A; Kiveni, M; Koch, K; Loer, B; Asamar, E Lopez; Mahapatra, R; Mandic, V; Martinez, C; McCarthy, K A; Mirabolfathi, N; Moffatt, R A; Moore, D C; Nadeau, P; Nelson, R H; Page, K; Partridge, R; Pepin, M; Phipps, A; Prasad, K; Pyle, M; Qiu, H; Rau, W; Redl, P; Reisetter, A; Ricci, Y; Saab, T; Sadoulet, B; Sander, J; Schneck, K; Schnee, R W; Scorza, S; Serfass, B; Shank, B; Speller, D; Villano, A N; Welliver, B; Wright, D H; Yellin, S; Yen, J J; Young, B A; Zhang, J

    2014-01-01

    SuperCDMS is an experiment designed to directly detect Weakly Interacting Massive Particles (WIMPs), a favored candidate for dark matter ubiquitous in the Universe. In this paper, we present WIMP-search results using a calorimetric technique we call CDMSlite, which relies on voltage- assisted Luke-Neganov amplification of the ionization energy deposited by particle interactions. The data were collected with a single 0.6 kg germanium detector running for 10 live days at the Soudan Underground Laboratory. A low energy threshold of 170 eVee (electron equivalent) was obtained, which allows us to constrain new WIMP-nucleon spin-independent parameter space for WIMP masses below 6 GeV/c2.

  20. Magnetic and calorimetric investigations of inverse magnetocaloric effect in Pr0.46Sr0.54MnO3

    Science.gov (United States)

    Naik, V. B.; Barik, S. K.; Mahendiran, R.; Raveau, B.

    2011-03-01

    We investigated magnetic entropy change (ΔSm) in the A-type antiferromagnet Pr0.46Sr0.54MnO3 by magnetic and differential scanning calorimetry (DSC) methods. The field-induced antiferromagnetic to ferromagnetic transition is first-order in nature and is accompanied by a large change in the latent heat as evidenced by the DSC data. The ΔSm shows an inverse magnetocaloric effect (ΔSm=+9 J kg-1 K-1 for ΔH =7 T) around the Neel temperature (TN=210±2 K) by magnetic measurement, which closely agrees with the calorimetric results. It is suggested that the large positive ΔSm results from a field-induced structural transition that accompanies the destruction of antiferromagnetism.

  1. Comparison of two models for the X-ray dispersion produced in a Novillo Tokamak with measurements make with thermoluminescent dosemeters; Comparacion de dos modelos para la dispersion de rayos X producidos en un Novillo Tokamak con mediciones efectuadas con dosimetros termoluminiscentes

    Energy Technology Data Exchange (ETDEWEB)

    Flores O, A.; Castillo, A.; Barocio, S.R.; Melendez L, L.; Chavez A, E.; Cruz C, G.J.; Lopez, R.; Olayo, M.G.; Gonzalez M, P. [Instituto Nacional de Investigaciones Nucleares, 52045 Salazar, Estado de Mexico (Mexico); Azorin N, J. [Universidad Autonoma Metropolitana Iztapalapa, 09340 Mexico D.F. (Mexico)

    1999-07-01

    It was presented the results to study about the X-ray dispersion produced in the Novillo Tokamak using thermoluminescent dosemeters (DTL). The measurements were make in the equatorial plane of Tokamak, along twelve radial directions. The dispersion is observed due to the radiation interaction with walls surrounding the machine. It was proposed two types of heuristic mathematical methods for describing the X-ray dispersion, comparing them with the experimental data obtained with Dtl. The predictions of both models are adjusted well to the experimental data. (Author)

  2. Relative thermoluminescent efficiencies proton/gamma and helium/gamma of peaks of high temperature in TLD-100 dosemeters; Eficiencias termoluminiscentes relativas proton/gamma y helio/gamma de picos de alta temperatura en dosimetros TLD-100

    Energy Technology Data Exchange (ETDEWEB)

    Flores M, E. [UNAM, Facultad de Ciencias, 04510 Mexico D.F. (Mexico)

    2007-07-01

    The increase of the applications of ion beams in radiotherapy treatments has generated interest in the study of the thermoluminescent materials (TL) that allow to determine the applied doses. A way to quantify the TL response from these materials to ions is by means of the relative thermoluminescent efficiency. In the group of Thermoluminescent dosimetry of the Institute of Physics of the UNAM (IFUNAM) the thermoluminescent response of the TLD-100 dosemeters has been studied, which present a glow curve characteristic with several peaks that correspond to traps and luminescent centers in the material. The stable peaks know each other as 4, 5, 6a, 6b, 7, 8, 9 and 10. The efficiencies should be measured using the response so much to the radiation of interest (in this case protons and helium ions) as the response to gamma radiation. In previous works with ions of low energy taken place in the Pelletron accelerator of the IFUNAM was only measured the TL efficiency for the peak 5 and the total signal. It had not been possible to measure the efficiency of the peaks of high temperature (6a-10) because, for the gamma radiation, the peaks of high temperature show very small signals; however, recently Massillon carries out measures of efficiency TL of peaks of high temperature for ions of intermediate energy using a protocol special of reading and of deconvolution that allows to measure the signals coming from the peaks of high temperature. In this work is implemented this same protocol to complete the study of TL efficiencies at low energy of protons and helium and to determine if the values of efficiency depend on the used reading protocol. For it is reported it measures of the relative efficiency of the peaks of high temperature from the TLD-100 exposed to protons of 1.5 MeV and nuclei of helium of 3 and 7.5 MeV. (Author)

  3. Mensuration of equivalent dose with personal dosemeters and instruments of radiological protection in the new operative quantities ICRU, for external fields of beta radiation. Part II. I study of the angular response of personal dosemeters TLD-100 in secondary patron fields of beta radiation ({sup 90}Sr / {sup 90}Y); Medicion de dosis equivalente con dosimetros personales e instrumentos de proteccion radiologica en las nuevas magnitudes operativas ICRU, para campos de radiacion beta externos. Parte II. Estudio de la respuesta angular de dosimetros personales TLD-100 en campos patrones secundarios de radiacion beta ({sup 90}Sr/{sup 90}Y)

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez R, J.T. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    1994-01-15

    The objective of this work is to carry out one of the possible ones test type for personal dosemeters TLD, under the recomendations of the ICRU 39, ICRU 43 and the draft of the norm ISO 6980,(1992), with the purpose of verifying the capacity of these detectors to carry out the operative unit: H' (0.07;{alpha}). Since H' (O. 07;{alpha}) this defined one in an expanded field, one of these tests type consist on determining the angular response of these detectors. 20 personal dosemeters TLD-100 was used, (card marks: Harshaw, Model: G-1, with two glasses of TLD-100 absorbed in teflon; the portadosemeters has two windows, a free one and another with a filter of Pb of 171.0 mg cm{sup -2}); these dosemeters they were previously selected, [to see, {sup S}tudy of the Homogeneity of the response of Personal Dosemeters (Cards G-l, TLD-100) in Radiation of Countrysides of {sup 60}Co{sup ,} J.T. Alvarez R. Technician Report GSR/IT/0001/94].The irradiations to effectued in secondary countryside of radiation beta of {sup 90}Sr/{sup 90}Y. The study was undertaken by means of an experimental design of blocks random that contemplate the following variables: intensity of the radiation source, (1850 MBq and 74 MBq); position of irradiation, (four positions); incidence of angle of the radiation (0, 15, 30, 45, 60 and 75 grades) and the absorbed dose in air, (0.005, 0.010, 0.020, 0.050 and 0.100 Gy). Then null hypothesis it was to suppose that there was not difference among the stockings of each treatment, to used the statistical of Duncan to carry out tests of stockings at a level of significance of 5%.These tests of stockings throw the following results in those variables of the experimental design: The irradiations carried out so much with the source pattern secondary of {sup 90}Sr/{sup 90}Y of 1850 MBq and of 74 MBq, they are equivalent reason why they can be used indistinctly. The responses of each one of the glasses of the card are strongly anisotropic for each glass

  4. Simulación de una Celda Calorimétrica mediante Elementos Finitos Simulation of a Calorimetric Cell using Finite Elements

    Directory of Open Access Journals (Sweden)

    Juan C Moreno

    2007-01-01

    Full Text Available Se ha usado el método de los elementos finitos con el fin de determinar la conveniencia de usar una forma de paralelepípedo y diferentes materiales para una celda de un microcalorímetro de conducción tipo Calvet. El empleo las condiciones de frontera en la ecuación de calor permite describir las curvas isotermas que se establecen al interior de la celda calorimétrica cuando se realiza un proceso de transferencia térmica. La existencia de puntos críticos en la geometría de la celda puede afectar la medición y ser un factor de error en la adquisición experimental de datos. La simulación permite conocer la posibilidad de disminuir estos efectos cambiando los materiales de construcción de la misma.Finite elements have been employed in this work with the purpose of determining the convenience of using a parallelepiped geometry and different materials for a cell of a Calvet type conduction microcalorimeter. The heat equation allows to describe isotherm curves established inside the calorimetric cell during the heat transfer process. The existence of critical points in the geometry of the cell can affect the measuring process and be an factor of error during experimental data acquisition. The simulation allows to determine the feasibility of diminishing these effects by changing the construction materials.

  5. Compensated-power differential calorimeter -196 deg. C/400 deg. C; Calorimetre differentiel a puissance compensee -196 deg. C/400 deg. C

    Energy Technology Data Exchange (ETDEWEB)

    Bonjour, E.; Pierre, J.; Agagliate, S.; Bertrand, P.; Faivre, J.; Lagnier, R. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires, Section physico-chimie et basses temperatures

    1967-06-01

    A differential calorimetric device of original design is described. Its allows direct measurements of thermal effects (adsorption or release) during a linear rise of temperature. The self compensated power method which is applied by means of a very sensitive control system, gives a direct value of the different heat capacity between the sample and a dummy of it. The detection threshold is about {+-} 100 micro-watts to {+-} 250 micro-watts. Applications: - Generally measurements of enthalpy changes of massive or powdered samples. - Measurement of Wigner energy after low temperature irradiation (77 deg. K). - Measurements of energy release in low temperature (77 deg. K) cold worked metals. (authors) [French] On decrit un dispositif de calorimetrie differentielle, de conception originale, qui permet de mesurer directement des effets thermiques en absorption ou en degagement de chaleur, au cours d'une montee en temperature lineaire. La methode de compensation automatique de puissance qui est mise en oeuvre au moyen de cha es d'asservissement tres sensibles, conduit a une determination directe de la capacite calorifique differencielle entre l'echantillon et sa reference. Le seuil de detection est de l'ordre de {+-} 100 a {+-} 250 microwatts. Applications: - D'une facon generale, mesure des variations enthalpiques, sur echantillons massifs ou en poudre. - Mesure de l'energie Wigner apres irradiation a basse temperature (77 deg. K). - Mesure de l'energie restauree apres deformation des metaux a basse temperature (77 deg. K). (auteurs)

  6. Study of the influence of heat sources on the out-of-pile calibration curve of calorimetric cells used for nuclear energy deposition quantification

    Energy Technology Data Exchange (ETDEWEB)

    De Vita, C.; Brun, J.; Reynard-Carette, C.; Carette, M.; Amharrak, H. [Aix Marseille Universite, CNRS, Universite de Toulon, IM2NP UMR 7334, 13397, Marseille (France); Lyoussi, A.; Fourmentel, D.; Villard, J.F. [CEA, DEN, DER, Instrumentation Sensors and Dosimetry Laboratory, Cadarache, F-13108 Saint Paul Lez Durance (France)

    2015-07-01

    inside the calorimeter cell head. This discrepancy is higher than in previous experiments because the calorimeter owns a high sensitivity. Consequently, a new prototype was created and instrumented by other heat sources in order to impose an energy deposition on the calorimetric cell structure (in particular in the base) and to improve the calibration step in out-of-pile conditions. In this paper, on the first part a detailed description of the new calorimetric sensor will be given. On the second part, the experimental response of the sensor obtained for several internal heating conditions will be shown. The influence of these conditions on the calibration curve will be discussed. Then the response of this prototype will be also presented for different external cooling fluid conditions (in particular flow temperature). In this part, the comparison between the in-pile and out-of-pile experimental results will be performed. On the last part, these out-of-pile experiments will be completed by 2D axisymmetrical thermal simulations with the CEA code CAST3M using Finite Elements Method. After a comparison between experimental and numerical works, improvements of the sensor prototype will be studied (new heat sources). (authors)

  7. Internal friction, dilatometric and calorimetric study of anelasticity in Fe-13 at.% Ga and Fe-8 at.% Al-3 at.% Ga alloys

    Energy Technology Data Exchange (ETDEWEB)

    Golovin, I.S., E-mail: i.golovin@tu-bs.de [Departments of Physical Materials Science and Physical Metallurgy of Non-Ferrous Metals, National Research Technological University ' MISiS' , Leninskij ave. 4, 119049 Moscow (Russian Federation); Belamri, Z.; Hamana, D. [Phases Transformation Laboratory, Mentouri University of Constantine, Ain El Bey Road, 25000 Constantine (Algeria)

    2011-08-11

    Graphical abstract: Highlights: > Internal friction, dilatometry and DSC are used to study Fe-13% Ga and Fe-8% Al-3% Ga alloys. > Effect obtained in the temperature range of 250-300 deg. C is due to ordering processes. > Several thermally activated peaks are identified by their activation parameters. - Abstract: This paper investigates the structural transitions associated with different cooling rates from a high temperature disordered state and the effect of substitution of Ga atoms by Al atoms in Fe-Ga binary alloys on the ordering processes. Two iron-based low carbon (about 0.04 at.% C) alloys Fe-13 at.% Ga and Fe-8 at.% Al-3 at.% Ga are studied. Internal friction, dilatometric and calorimetric tests are carried out to check ordering in these alloys and contribution of structural defects to relaxation spectrum. Several thermally activated internal friction peaks have been observed and their activation parameters evaluated by means of temperature and frequency dependent internal friction tests using forced vibration. For most of these peaks physical mechanisms are proposed. Apart from these thermally activated relaxation peaks, a structural, frequency independent relaxation takes place at 250-300 deg. C. Dilatometric and DSC curves show the appearance of a contraction effect in the same temperature range. This effect was studied in alloys cooled down with different cooling rates. We believe that the frequency independent internal friction peak (denoted as the P3 peak in this paper) and peaks at dilatometric and DSC curves are controlled by the same structural mechanism and therefore the activation energy for this anelastic mechanism is derived from DSC data.

  8. Calorimetric approach of lanthanides (3) complexation and extraction by malonamides; Approche calorimetrique de la complexation et de l'extraction des lanthanides (3) par les malonamides

    Energy Technology Data Exchange (ETDEWEB)

    Flandin, J.L

    2001-07-01

    In the field of long lived radionuclides separation, diamides are interesting extractants because of their ability to co-extract trivalent lanthanides and actinides, which is a preliminary and essential step in high level radioactive waste reprocessing. The research carried out contributes to a better understanding of the mechanisms and the aim is the determination of thermodynamics properties ({delta}{sub r}G, {delta}{sub r}H et {delta}{sub r}S) related to the complexation and the extraction of lanthanides(III) by malonamides. The first part of the document deals with the complexation of lanthanides(III) by an hydrosoluble diamide. The experimental results obtained by UV-visible spectrometry, TRLIF, NMR and microcalorimetric titration proved that lanthanides(III)-TEMA interactions in aqueous medium are very weak and that the complexation reaction is endothermic. The TEMA ligand still stays in the second coordination sphere of coordination of the lanthanide ion. The second part of this study focuses on the extraction of neodymium(III) nitrate by a lipophilic diamide which is an exothermic reaction. The influence of the composition of aqueous and organic phases on the thermodynamics properties {delta}{sub r}G et {delta}{sub r}H has been studied by microcalorimetric titration. The most influent parameter is the total concentration in extractant. As a consequence, thermodynamic values are very dependent on the organic phase organisation before and alter extraction. At the same time, this study showed the interest of the calorimetric approach for the analysis of basic reactions like diamide dilution and their organisation as oligomeric aggregates. (author)

  9. HSP as bio dosemeters; HSP como biodosimetros

    Energy Technology Data Exchange (ETDEWEB)

    Manzanares A, E.; Vega C, H.R. [Grupo Academico de Radiobiologia, UAZ, A.P. 336, 98000 Zacatecas (Mexico)

    2005-07-01

    A review of the more important passages for the field of the radiological protection, from the discovery, beginnings of the utilization of the radiations emitting, passing to the legislation proposals and the transformations that had been suffer to establish the international standards of radiological protection. The paradigms on the effects and chronologically the emanated discoveries of the cellular research and the measurement of cellular products in the species and the diverse alive beings making emphasis in evaluating the expression of the heat-shock proteins caused by low doses of gamma radiation, these are used as radiation bio monitors and of other agents that cause cellular stress and lastly a prospective of the future of the radiobiology. (Author)

  10. Measurement of the heat production of bacteria in the bioreactor. Calorimetric regulation of bio-processes for the production of recombinant proteins; Messung der Waermeproduktion von Bakterien im Bioreaktor. Kalorimetrische Regelung von Bioprozessen zur Herstellung von rekombinanten Proteinen

    Energy Technology Data Exchange (ETDEWEB)

    Biener, Richard [Hochschule Esslingen (Germany); Steinkaempfer, Anne; Horn, Thomas; Hofmann, Johannes

    2012-09-15

    Recombinant proteins such as insulin or interferons are the most important products of the modern biotechnology. Recombinant proteins are produced with genetically engineered organisms. Here, besides microorganisms (E. coli or yeast cells) also animal cell cultures are used. In order to increase the productivity and the reproducibility of the cultivation process, an automated process control is required. The authors of the contribution under consideration report on the regulation of the specific rate of growth of microorganisms during cultivation in a bioreactor using standard calorimetric methods. This automation strategy results in a significant increase in productivity and reproducibility of the process.

  11. Comparación del gasto energético en reposo determinado mediante calorimetría indirecta y estimado mediante fórmulas predictivas en mujeres con grados de obesidad I a III

    Directory of Open Access Journals (Sweden)

    Alicia Parra-Carriedo

    2013-04-01

    Full Text Available Introducción: La determinación del gasto energético en reposo (GER se calcula cotidianamente a partir de fórmulas predictivas aunque el resultado varía dependiendo de la población. Objetivo: Comparar la determinación del GER mediante calorimetría indirecta y mediante las ecuaciones Harris-Benedict (HB, Mifflin (MF, Organización Mundial de la Salud (OMS, "Institute of Medicine" (IOM, Fórmula Rápida (FR y Valencia (VA en mujeres con grados de obesidad I a III. Métodos: Mujeres adultas mestizas mexicanas se incluyeron en el estudio y formaron 3 grupos a partir del índice de masa corporal (IMC. Obesidad grado I (IMC 30,034,9; n = 42, grado II (IMC 35,0-39,9; n = 38 y grado III (IMC > 40; n = 41. Se determinó el GER mediante calorimetría indirecta y mediante las ecuaciones antes señaladas. ANOVA de Kruskal-Wallis y la prueba de Dunn's se emplearon para el análisis estadístico (p 30. En el grado III VA y FR muestran el mejor desempeño.

  12. Micro-machined calorimetric biosensors

    Science.gov (United States)

    Doktycz, Mitchel J.; Britton, Jr., Charles L.; Smith, Stephen F.; Oden, Patrick I.; Bryan, William L.; Moore, James A.; Thundat, Thomas G.; Warmack, Robert J.

    2002-01-01

    A method and apparatus are provided for detecting and monitoring micro-volumetric enthalpic changes caused by molecular reactions. Micro-machining techniques are used to create very small thermally isolated masses incorporating temperature-sensitive circuitry. The thermally isolated masses are provided with a molecular layer or coating, and the temperature-sensitive circuitry provides an indication when the molecules of the coating are involved in an enthalpic reaction. The thermally isolated masses may be provided singly or in arrays and, in the latter case, the molecular coatings may differ to provide qualitative and/or quantitative assays of a substance.

  13. Estudio del gasto energético en la anorexia nerviosa: concordancia entre calorimetría indirecta y diferentes ecuaciones Study of energy expenditure in anorexia nervosa: agreement between indirect calorimetry and several equations

    OpenAIRE

    M.ª C. Cuerda Compés; A. Ruiz Sancho; C. Moreno Rengel; M.ª T. Iriondo Martínez; C. Velasco Gimeno; I Bretón Lesmes; M Camblor Álvarez; P. García Peris

    2005-01-01

    El tratamiento nutricional es fundamental en la anorexia nerviosa (AN), si bien la reposición de nutrientes debe hacerse de forma progresiva para evitar la aparición del síndrome de realimentación. Objetivo: Comparar el gasto energético en reposo (GER) mediante calorimetría indirecta con el estimado con diferentes fórmulas en mujeres con AN. Material y Métodos: Estudiamos 21 mujeres ingresadas con AN (DSM-IV), edad 17 (DE 5,9) rango 12-34 años. El tiempo de ingreso fue 55,1 ± 20,7 días...

  14. Aplicación del análisis por calorimetría diferencial de barrido (DSC para la caracterización de las modificaciones del almidón

    Directory of Open Access Journals (Sweden)

    ANGELICA SANDOVAL ALDANA

    2005-01-01

    Full Text Available La calorimetría diferencial de barrido (DSC, por sus siglas en ingles es un análisis térmico que ha permitido identificar en un sistema compuesto de almidón y agua las transiciones y modificaciones de la estructura del gránulo de almidón, verificar la asociación de fragmentos de amilosa y amilopectina (retrogradación e identificar los cambios en sus características térmicas como consecuencia de tratamientos combinados de calor y humedad. Esta revisión presenta conceptos sobre el DSC, la estructura y las transiciones de fase del gránulo de almidón. Adicionalmente, se recopilan investigaciones donde se utilizó esta técnica para la caracterización de distintos almidones.

  15. Calibration of photographic dosemeters to evaluate the personal equivalent dose, Hp (10), irradiated by different radiation qualities and angles of incidence; Calibracao de dosimetros fotograficos para avaliar o equivalente de dose pessoal, Hp(10), irradiados por diferentes qualidades de radiacao e angulos de incidencia

    Energy Technology Data Exchange (ETDEWEB)

    Santoro, Christiana; Antonio Filho, Joao, E-mail: chsantoro@gmail.com, E-mail: jaf@ufpe.br [Universidade Federal de Pernambuco (DEN/UFPE), Recife, PE (Brazil). Departamento de Energia Nuclear; Santos, Marcus Aurelio P.; Goncalves Filho, Luiz Carlos, E-mail: masantos@cnen.gov.br, E-mail: l.filho@cnen.gov.br [Centro Regional de Ciencias Nucleares do Nordeste (CRCN-NE/CNEN-PE), Recife, Pe (Brazil)

    2013-07-01

    To use radiation detectors, should periodically perform tests and calibrations on instruments in order to verify its good functionality. One way to ascertain the quality of the instrument is to conduct a study of the angular dependence of the response of the radiation detectors. The photographic dosimetry has been used widely to quantify the radiation doses and to estimate levels of doses received by workers involved with X-and gamma radiation. Photographic dosimeters are used because provide wide range of exposure and good accuracy. One of the sources of error have been introduced by different irradiation geometries between calibration and measurement in radiation fields used in x-ray and gamma ray sources, therefore, there is a need for an evaluation of the sensitivity of dosimeters with variation of the angle of the incident beam. In this study were tested 190 photographic dosemeters in the Metrology Laboratory of the Centro Regional de Ciencias Nucleares do Nordeste (CRCN-NE) using the phantom H{sub p} (10), where the dosimeters are evaluated on the basis of the new operational magnitude for individual monitoring, the equivalent personal dose, H{sub p} (10). Angular dependence of these radiation detectors was studied in X radiation fields (in the range of 45 keV energy to 164 keV) and gamma radiation ({sup 137}Cs-662 keV e {sup 60}Co - 1250 keV)

  16. Temperature-dependent interactions and disorder in the spin-transition compound [Fe(II)(L)2][ClO4]2.C7H8 through structural, calorimetric, magnetic, photomagnetic, and diffuse reflectance investigations.

    Science.gov (United States)

    Mishra, Vibha; Mukherjee, Rabindranath; Linares, Jorge; Balde, Chérif; Desplanches, Cédric; Létard, Jean-François; Collet, Eric; Toupet, Loic; Castro, Miguel; Varret, François

    2008-09-01

    The title compound [Fe (II)(L) 2][ClO 4] 2.C 7H 8 (L = 2-[3-(2'-pyridyl)pyrazol-1-ylmethyl]pyridine) has been isolated while attempting to grow single crystals of the spin-transition (continuous-type) compound [Fe (II)(L) 2][ClO 4] 2, published earlier ( Dalton Trans. 2003, 3392-3397). Magnetic susceptibility measurements, as well as Mossbauer and calorimetric investigations on polycrystalline samples of [Fe(L) 2][ClO 4] 2.C 7H 8 revealed the occurrence of an abrupt HS ( (5) T 2) LS ( (1) A 1) transition with steep and narrow (2 K) hysteresis at approximately 232 K. The photomagnetic properties exhibit features typical for a broad distribution of activation energies, with relaxation curves in the shape of stretched exponentials. We performed a crystal structure determination of the compound at 120, 240, and 270 K. A noteworthy temperature-dependent behavior of the structural parameters was observed, in terms of disorder of both the anions and solvent molecules, leading to a strong thermal dependence of the strength and dimensionality of the interaction network. Additional data were obtained by diffuse reflectance measurements. We model and discuss the antagonistic effects of interactions and disorder by using a two-level cooperative mean-field approach which includes a distribution of barrier energies at the microscopic scale.

  17. Electromagnetic and calorimetric measurements for AC losses of a YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} coated conductor with Ni-alloy substrate

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, D N [Center for Advanced Power Systems, Florida State University, Tallahassee, FL 32310 (United States); Sastry, P V P S S [Center for Advanced Power Systems, Florida State University, Tallahassee, FL 32310 (United States); Knoll, D C [Center for Advanced Power Systems, Florida State University, Tallahassee, FL 32310 (United States); Schwartz, J [Center for Advanced Power Systems, Florida State University, Tallahassee, FL 32310 (United States)

    2006-10-15

    The AC losses of a rolling-assisted-biaxially-textured-substrate (RABiTS(TM)) processed YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} (YBCO) coated conductor (Goyal et al 1996 Appl. Supercond. 4 403-27) with Ni-alloy substrate and Cu stabilizer were measured at 77 K by both calorimetric (CM) and electromagnetic (EM) methods. In the CM method, improvements in the measurement were observed when a Cernox temperature sensor was used to measure the temperature rise on the sample instead of a differential thermocouple. The effect of heat transferred from current leads was taken into account to improve the accuracy of the CM results. In the EM method, the magnetization losses of the sample in a perpendicular applied field were measured by an in-plane pick-up coil. The calculation of the calibration factor C of the pick-up coil is discussed. Good agreement between AC loss results obtained from the CM and EM methods confirmed the validity of our measurements and calculations.

  18. Determination of electronic stopping powers of 0.05-1 MeV/u 131Xe ions in C-, Ni- and Au-absorbers with calorimetric low temperature detectors

    Science.gov (United States)

    Echler, A.; Egelhof, P.; Grabitz, P.; Kettunen, H.; Kraft-Bermuth, S.; Laitinen, M.; Müller, K.; Rossi, M.; Trzaska, W. H.; Virtanen, A.

    2017-01-01

    A new experimental system for precise determination of electronic stopping powers of heavy ions has been set up at the accelerator laboratory of the University of Jyväskylä. The new setup, combining an established B-ToF system and an array of calorimetric low temperature detectors (CLTDs), has been used for the determination of electronic stopping powers of 0.05-1 MeV/u 131Xe ions in carbon, nickel and gold. Thereby advantage of the improved linearity and energy resolution of CLTDs as compared to the previously used ionization detector was taken to reduce energy calibration errors and to increase sensitivity for the energy loss determination, in particular at very low energies. The total uncertainties of 3-4% for C- and Ni-targets, and 5-7% for Au-targets, respectively, are dominated by the target properties, i.e. thickness determination and inhomogeneities. The results are compared to data from literature and to predictions of different theoretical computer codes. In the high energy part of the examined energy range the results are in good agreement with previously published data, while new stopping power data for very heavy ions in different Z2-materials have been obtained at lower energies. Moreover, unexpectedly strong channeling effects for the transmission of the 131Xe ions in thin, partly polycrystalline nickel and gold target foils have been observed and investigated.

  19. Estudio de la reacción de curado del sistema éter diglicidílico del bisfenol-A (DGEBA y la dietilentriamina (DETA por calorimetría diferencial de barrido

    Directory of Open Access Journals (Sweden)

    González Garcia Filiberto

    2000-01-01

    Full Text Available La reacción de curado del sistema compuesto por el éter diglicidílico del bisfenol-A (DGEBA y la dietilentriamina (DETA fue estudiada por calorimetría diferencial de barrido (DSC. Diferentes expresiones cinéticas fueron encontradas por experimentos isotérmicos y dinámicos las que justifican cambios mecanísticos con la temperatura de cura. La cinética de la reacción cumple un segundo orden cinético con una energía de activación de 90 kJ mol-1 a altas temperaturas (mecanismo no catalítico. La cinética de la reacción a bajas temperaturas manifestó la existencia de dos mecanismos competitivos, se determinaron las constantes de velocidades de reacción a 60 y 70ºC y se encontró una energía de activación en el rango de 56.9 a 63.0 kJ mol¹, que está en perfecto acuerdo con la reportada a bajas temperaturas (mecanismo autocatalítico. También se muestra el diagrama de fases del sistema.

  20. Estudio del gasto energético en la anorexia nerviosa: concordancia entre calorimetría indirecta y diferentes ecuaciones Study of energy expenditure in anorexia nervosa: agreement between indirect calorimetry and several equations

    Directory of Open Access Journals (Sweden)

    M.ª C. Cuerda Compés

    2005-12-01

    Full Text Available El tratamiento nutricional es fundamental en la anorexia nerviosa (AN, si bien la reposición de nutrientes debe hacerse de forma progresiva para evitar la aparición del síndrome de realimentación. Objetivo: Comparar el gasto energético en reposo (GER mediante calorimetría indirecta con el estimado con diferentes fórmulas en mujeres con AN. Material y Métodos: Estudiamos 21 mujeres ingresadas con AN (DSM-IV, edad 17 (DE 5,9 rango 12-34 años. El tiempo de ingreso fue 55,1 ± 20,7 días (21-91. La valoración nutricional inicial incluyó antropometría (IMC, PTC, PSE, CMB,CMMB y bioimpedancia tetrapolar (HoltainBC. La calorimetría indirecta (CI se realizó tras ayuno nocturno (Deltatrac TM II MBM-200. En 9 pacientes se repitió el mismo estudio antes del alta. Comparamos el GER (kcal/24 h medido por CI con el obtenido por diferentes ecuaciones [Fleisch, Harris-Benedict (HB, FAO, Schofield-HW (SHW, Schebendach] mediante el coeficiente de correlación intraclase (CCI y el método de Bland y Altman. Resultados: El estado nutricional mejoró significativamente durante la hopitalización. El 50% del peso recuperado fue masa grasa. El GER aumentó significativamente durante el ingreso. Las fórmulas sobrestimaron el GER respecto al obtenido por CI (p Nutritional management is essential in anorexia nervosa (AN, although nutrient replenishment must be done progressively to prevent the occurrence of re-alimentation syndrome. Objective: to compare resting energy expenditure (REE by means of indirect calorimetry and by different equations in AN female patients. Material and methods: we studied 21 women admitted for AN (DSM-IV, mean age 17 years (SD 5.9, range 12-34 years. Admission stay was 55.1 ± 20.7 days (21-91. Initial nutritional assessment included anthropometrics (BMJ, TSF, SSE, MAC, MAMC and tetrapolar bioimpedance (HoltainBC. Indirect calorimetry (IC was done after overnight fasting (DeltatracTM II MBM-200. In 9 patients, the same study

  1. Calorimetric and computational study of thiacyclohexane 1-oxide and thiacyclohexane 1,1-dioxide (thiane sulfoxide and thiane sulfone). Enthalpies of formation and the energy of the S=O bond.

    Science.gov (United States)

    Roux, María Victoria; Temprado, Manuel; Jiménez, Pilar; Dávalos, Juan Zenón; Notario, Rafael; Guzmán-Mejía, Ramón; Juaristi, Eusebio

    2003-03-01

    A rotating-bomb combustion calorimeter specifically designed for the study of sulfur-containing compounds [J. Chem. Thermodyn. 1999, 31, 635] has been used for the determination of the enthalpy of formation of thiane sulfone, 4, Delta(f)H(o) m(g) = -394.8 +/- 1.5 kJ x mol(-1). This value stands in stark contrast with the enthalpy of formation reported for thiane itself, Delta(f)H(o) m(g) = -63.5 +/- 1.0 kJ x mol(-1), and gives evidence of the increased electronegativity of the sulfur atom in the sulfonyl group, which leads to significantly stronger C-SO2 bonds. Given the known enthalpy of formation of atomic oxygen in the gas phase, Delta(f)H(o) m(O,g) = +249.18 kJ x mol(-1), and the reported bond dissociation energy for the S=O bond in alkyl sulfones, BDE(S=O) = +470.0 kJ x mol(-1), it was possible to estimate the enthalpy of formation of thiane sulfoxide, 5, a hygroscopic compound not easy to use in experimental calorimetric measurements, Delta(f)H(o) m(5) = -174.0 kJ x mol(-1). The experimental enthalpy of formation of both 4 and 5 were closely reproduced by theoretical calculations at the G2(MP2)+ level, Delta(f)H(o) m(4) = -395.0 kJ x mol(-1) and Delta(f)H(o) m(5) = -178.0 kJ x mol(-1). Finally, calculated G2(MP2)+ values for the bond dissociation energy of the S=O bond in cyclic sulfoxide 5 and sulfone 4 are +363.7 and +466.2 kJ x mol(-1), respectively.

  2. Calorimetría indirecta en el enfermo crítico: validez de la medición Indirect calorimetry in critical ill patients: validity of measurement for ten minutes

    Directory of Open Access Journals (Sweden)

    P. Marsé Milla

    2004-03-01

    Full Text Available Objetivo: No existen estándares definidos sobre la duración y frecuencia de la medición de la calorimetría indirecta, hecho que tiene importancia en la práctica asistencial diaria. Se valora el grado de concordancia entre el gasto energético en reposo (GER medido en un espacio de tiempo corto (10 minutos frente a otro prolongado (1 hora. Pacientes: Se estudiaron 60 pacientes críticos, sedoanalgesiados y conectados a ventilación mecánica. Intervenciones: El GER se determinó mediante un computador metabólico (Engström Eliza en condiciones de reposo. Se valoró la reproducibilidad y el grado de acuerdo de las mediciones hechas en ambos períodos de tiempo. Resultados: Los valores medios de las determinaciones de GER a 10 y 60 minutos fueron de 1818 ± 319 Kilocalorías/día y de 1815 ± 318 Kcal/día. Los límites de acuerdo entre ambos tiempos fueron de -101 a + 117 Kilocalorías/día y la correlación fue significativa (r = 0.98, p Goal: There are no gold standards on the duration and frequency of the measurement of indirect calorimetry, a fact of importance in daily clinical practice. An assessment of is made of the degree of concordance between energy expenditure at rest (EER measured over a short interval (10 minutes versus another prolonged measurement (1 hour. Patients: Sixty critically-ill patients, under sedation and analgesia with connection to mechanical ventilation, were studied. Interventions: EER values were determined by means of a metabolic computer analysis (Engström Eliza at rest. The reproducibility and the degree of concordance were assessed in the measurements made with both periods. Results: The mean values of the EER determinations at 10 and 60 minutes were 1,818 ± 319 kilocalories/day and 1,815 ± 318 Kcal/day. The limits of the concordance between both times were -101 and +117 kilocalories/day and the correlation was significant (r = 0.98, p < 0.0001. Conclusions: In critically-ill patients under sedation and

  3. The work of walking: a calorimetric study.

    Science.gov (United States)

    Webb, P; Saris, W H; Schoffelen, P F; Van Ingen Schenau, G J; Ten Hoor, F

    1988-08-01

    Experiments were designed to test the traditional assumption that during level walking all of the energy from oxidation of fuel appears as heat and no work is done. Work is force expressed through distance, or energy transferred from a man to the environment, but not as heat. While wearing a suit calorimeter in a respiration chamber, five women and five men walked for 70 to 90 min on a level treadmill at 2.5, 4.6, and 6.7 km.h-1 and pedalled a cycle ergometer for 70 to 90 min against 53 and 92 W loads. They also walked with a weighted backpack and against a horizontal load. During cycling, energy from fuel matched heat loss plus the power measured by the ergometer. During walking, however, energy from fuel exceeded that which appeared as heat, meaning that work was done. The power increased with walking speed; values were 14, 29, and 63 W, which represented 11, 12, and 13% of the incremental cost of fuel above the resting level. Vertical and horizontal loads increased the fuel cost and heat loss of walking but did not alter the power output. This work energy did not re-appear as thermal energy during 18 h of recovery. The most likely explanation of the work done is in the inter-action between the foot and the ground, such as compressing the heel of the shoe and bending the sole. We conclude that work is done in level walking.

  4. Calorimetric studies of macromolecular aqueous solutions

    NARCIS (Netherlands)

    Blandamer, M.J; Cullis, P.M.; Engberts, J.B.F.N.

    1996-01-01

    Both titration and differential scanning microcalorimetric techniques are shown to yield important information concerning the properties of macromolecules in aqueous solution. Application of titration calorimetry is examined in me context of deaggregation of canonic micelles (e.g. hexadecyltrimethyl

  5. Calorimetric and computational study of 7-hydroxycoumarin

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, Clara C.S. [Centro de Investigacao em Quimica, Departamento de Quimica e Bioquimica, Faculdade de Ciencias da Universidade do Porto, Rua do Campo Alegre, 687, P-4169-007 Porto (Portugal); Matos, M. Agostinha R., E-mail: marmatos@fc.up.pt [Centro de Investigacao em Quimica, Departamento de Quimica e Bioquimica, Faculdade de Ciencias da Universidade do Porto, Rua do Campo Alegre, 687, P-4169-007 Porto (Portugal); Morais, Victor M.F., E-mail: vmmoraiss@icbas.up.pt [Centro de Investigacao em Quimica, Departamento de Quimica e Bioquimica, Faculdade de Ciencias da Universidade do Porto, Rua do Campo Alegre, 687, P-4169-007 Porto (Portugal); Instituto de Ciencias Biomedicas Abel Salazar, ICBAS, Universidade do Porto, P-4099-003 Porto (Portugal)

    2011-10-15

    Highlights: > Experimental standard molar enthalpies of formation, sublimation of 7-hydroxycoumarin. > Combustion calorimetry, sublimation microcalorimetry, differential scanning calorimetry. > DFT calculations, MC3BB and MC3MPW methods have been performed for the compound and its isomers. > Computational estimation of enthalpies of formation of 5-, 6-, and 8-hydroxycoumarin. - Abstract: The standard (p{sup o} = 0.1 MPa) molar energy of combustion in oxygen, at T = 298.15 K, of 7-hydroxycoumarin was measured by static bomb calorimetry. The value of the standard molar enthalpy of sublimation was obtained by Calvet microcalorimetry and corrected to T = 298.15 K. Combining these results, the standard molar enthalpy of formation of the compound, in the gas phase, at T = 298.15 K, has been calculated, -(337.5 {+-} 2.3) kJ . mol{sup -1}. The values for the temperature of fusion, T{sub fusion}, and for the fusion enthalpy, at T = T{sub fusion}, are also reported. Additionally, high-level density functional theory calculations using the B3LYP hybrid exchange-correlation energy functional with extended basis sets, the MC3BB and MC3MPW methods and more accurate correlated computational techniques of the MCCM suite have been performed for the compound. The agreement between experiment and theory gives confidence to estimate the enthalpy of formation of the remaining hydroxycoumarins substituted in the benzene ring.

  6. Aluminium nitrate ceramics: A potential UV dosemeter material

    DEFF Research Database (Denmark)

    Trinkler, L.; Bøtter-Jensen, L.; Berzina, B.

    2002-01-01

    dosimetry applications. The features are: (1) the spectral sensitivity covers the 200-350 nm range, in the UV-B region it is similar to that of human skin: (2) the angular dependence of the incident radiation follows the cosine law; (3) high yields of both UVR-induced OSL and TL signals compared to those...

  7. Multisphere neutron spectrometric system with thermoluminescence dosemeters: sensitive improvement.

    Science.gov (United States)

    Gregori, B; Papadópulos, S; Cruzate, J; Kunst, J J

    2002-01-01

    In this work, a neutron spectrometric system based on a set of moderating spheres with thermoluminescence detectors (TLD) is presented. The system at the Nuclear Regulatory Authority (ARN) Dosimetry Laboratory consists of 12 solid spheres made of high-density polyethylene (p = 0.95 g x cm(-3)), with diameters ranging from 2" to 12" and TLD sensitive to thermal and gamma radiation, namely TLD-600 and TLD-700, located at the centre of the spheres. The neutron response matrix for this Bonner Sphere Spectrometer (BSS) was calculated using the MCNP-IVB code and the library ENDF/B-VI in the energy range between thermal neutrons and 100 MeV. The neutron spectrum was obtained using the LOUH182 unfolding code. The improvement in sensitivity of the system is based on the election of a different heating cycle of the TLD that allows an increase in sensitivity by a factor of 2.6 compared with the standard laboratory treatment. The system response for the calibration with an Am-Be source is presented.

  8. A calorimetric and equilibrium investigation of the reaction {l_brace}methyl ferulate(aq) + H{sub 2}O(l) = methanol(aq) + ferulic acid(aq){r_brace}

    Energy Technology Data Exchange (ETDEWEB)

    Goldberg, Robert N., E-mail: robert.goldberg@nist.go [Biochemical Science Division, National Institute of Standards and Technology, Gaithersburg, MD 20876 (United States); Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, Baltimore, MD 21250 (United States); Lang, Brian E., E-mail: brian.lang@nist.go [Biochemical Science Division, National Institute of Standards and Technology, Gaithersburg, MD 20876 (United States); Selig, Michael J., E-mail: michael.selig@nrel.go [National Renewable Energy Laboratory, Biosciences Center, 1617 Cole Boulevard, Golden, CO 80401 (United States); Decker, Stephen R., E-mail: steve.decker@nrel.go [National Renewable Energy Laboratory, Biosciences Center, 1617 Cole Boulevard, Golden, CO 80401 (United States)

    2011-03-15

    Microcalorimetry and high-performance liquid chromatography (HPLC) have been used to conduct a thermodynamic investigation of the reaction: {l_brace}methyl ferulate(aq) + H{sub 2}O(l) = methanol(aq) + ferulic acid(aq){r_brace}, as catalyzed by feruloyl esterase. Values of the apparent equilibrium constant K' = (29.6 {+-} 0.7) (T = 298.15 K, citrate buffer at pH 4.98, ionic strength I = 0.39 mol {center_dot} kg{sup -1}) and of the calorimetrically determined enthalpy of reaction {Delta}{sub r}H(cal) = (4.0 {+-} 0.9) kJ {center_dot} mol{sup -1} (T = 298.15 K and citrate buffer at pH 4.81, I = 0.36 mol {center_dot} kg{sup -1}) were measured. A chemical equilibrium model, together with pKs and standard enthalpies of reaction {Delta}{sub r}H{sup 0} for the H{sup +}(aq) binding reactions of the reactants and products, was then used to calculate the values K = (1.89 {+-} 0.06) . 10{sup -4}, {Delta}{sub r}H{sup o} = (7.3 {+-} 1.7) kJ {center_dot} mol{sup -1}, {Delta}{sub r}G{sup o} = (21.25 {+-} 0.07) kJ {center_dot} mol{sup -1}, and {Delta}{sub r}S{sup o} = - (46.8 {+-} 5.7) J {center_dot} K{sup -1} {center_dot} mol{sup -1} for the chemical reference reaction {l_brace}methyl ferulate(aq) + H{sub 2}O(l) = methanol(aq) + ferulic acid{sup -}(aq) + H{sup +}(aq){r_brace}. These values of K and {Delta}{sub r}H{sup o} are similar in magnitude to the corresponding values reported for the reaction {l_brace}propyl gallate(aq) + H{sub 2}O(l) = 3,4,5-trihydroxybenzoic acid{sup -}(aq) + 1-propanol(aq) + H{sup +}(aq){r_brace}. The results obtained in this study can be used in a chemical equilibrium model to calculate how K' and other standard transformed properties such as the standard transformed enthalpy {Delta}{sub r}H'{sup o}, standard transformed Gibbs free energy {Delta}{sub r}G'{sup o}, and the change in binding of H{sup +}(aq), {Delta}{sub r}N(H{sup +}), vary with the independent variables T, pH, and I.

  9. Spectroscopic and calorimetric investigation of short and intermediate-range structures and energetics of amorphous SiCO, SiCN, and SiBCN polymer-derived ceramics

    Science.gov (United States)

    Widgeon, Scarlett J.

    Polymer-derived ceramics (PDCs) are a new class of amorphous ceramics in the Si-B-C-N system that are synthesized by the pyrolysis of silicon-based organic polymers. PDCs are lightweight and are resistant to creep, crystallization, and oxidation at temperatures near 1800 K making them ideal for a variety of high temperature applications. In spite of being X-ray amorphous, these materials display structural heterogeneity at the nanometer length scale. Their structure and resulting properties can be drastically altered by the utilization of preceramic polymers with differing chemistry and architectures. Fundamental understanding of the atomic structure is critical in deciphering the structure-property relationships and ultimately in controlling their properties for specific engineering applications. The short-range atomic structure has been extensively investigated using a variety of techniques, however, the structures at length scales beyond next-nearest neighbors remained highly controversial. Here we report the results of a spectroscopic and calorimetric study of short and intermediate -range structure and energetic of SiOC and SiBCN PDCs derived from a wide variety of precursors. SiOC PDCs with different carbon contents were synthesized from polysiloxane precurors and their structures were studied using high-resolution 13C and 29Si nuclear magnetic resonance (NMR) spectroscopy. The results suggest that these PDCs consists of a continuous mass fractal backbone of corner-shared SiC xO4-x tetrahedral units with "voids" occupied by sp 2-hybridized graphitic carbon. The oxygen-rich SiCxO 4-x units are located at the interior of this backbone with a mass fractal dimension of ~ 2.5, while the carbon-rich units occupy the two-dimensional interface between the backbone and the free carbon nanodomains. Such fractal topology is expected to give rise to unusual mechanical and transport properties characteristic of fractal percolation networks. For example, elastic moduli and

  10. Photoelectric-calorimetric compound beam profile detector for near-infrared high energy laser%光电/量热复合式近红外高能激光光斑探测器

    Institute of Scientific and Technical Information of China (English)

    冯国斌; 杨鹏翎; 王振宝; 王群书

    2013-01-01

    To measure the beam profile and power density distribution of a far field target in high energy system performance evaluation,a high energy laser detection method is proposed by combining photoelectric and calorimetric methods.In the method,the total energy of incident laser is measured by an absorber and the spatial and temporal distribution of laser profile measured by a photoelectric detector.The detector is developed,which is consisted of a graphite calorimeter,an InGaAs photoelectric detector array,a temperature and voltage amplifier,an analog to digital converter and a signal processor.The system with an effective sensitive area of 22 cm× 22 cm can offer a spatial resolution of 1.1 cm,a temporal resolution of 20 ms,and a low energy measurement uncertainty less than 10%.With the higher temporal resolution and lower energy measurement uncertainty,the system is suitable for high energy and large area near-infrared laser beam measurement.It has been used in field experiments successfully.%为了准确测量高能激光系统远场到靶总能量和功率密度时空分布等参数,本文提出了量热吸收法和光电探测阵列法相结合的复合式测量方法.该方法由热吸收体测量入射激光的总能量,由光电探测阵列测量光斑的时空分布.研制了用于大面积、长脉冲近红外高能激光测量的复合式光斑时空分布探测器.探测器主要由石墨热吸收体、近红外探测器阵列、测温单元和信号处理单元等组成,有效测量光斑面积达到22 cm×22 cm,光斑测量空间分辨力为1.1 cm,时间分辨力为20 ms.该测量系统同时兼顾了光电探测阵列法的高时空分辨能力和量热吸收法的低测量不确定度等优点,适合于高能量、大面积近红外高能激光光斑参数的综合测量,并已成功应用于外场实验.

  11. Acquisition of rheological and calorimetric properties of borosilicate glass to determine the free energy of formation; Determination des energies libres de formation des verres borosilicates par des mesures calorimetriques et viscosimetriques

    Energy Technology Data Exchange (ETDEWEB)

    Linard, Y. [CEA Valrho, (DCC/DRRV/SCD), 30 - Marcoule (France)]|[Institut de Physique du Globe de Paris, Dept. des Geomateriaux, 75 - Paris (France); Advocat, Th. [CEA Valrho, (DCC/DRRV/SSCD), 30 - Marcoule (France)

    2000-07-01

    . These experimental determinations will allow an assessment of glass thermodynamic stability in water. This step will notably involve the correlation of aqueous leaching results with the standard glass chemical potentials based on the measured calorimetric and rheological properties. (authors)

  12. Development of a new analysis method evaluating adsorption energies for the respective ion-exchanged sites on alkali-metal ion-exchanged ZSM-5 utilizing CO as a probe molecule: IR-spectroscopic and calorimetric studies combined with a DFT method.

    Science.gov (United States)

    Kumashiro, Ryotaro; Fujie, Kazuhiko; Kondo, Aki; Mori, Toshinori; Nagao, Mahiko; Kobayashi, Hisayoshi; Kuroda, Yasushige

    2009-07-07

    For alkali-metal ion-exchanged ZSM-5 zeolites (MZSM-5; M: Li, Na, K, Rb, Cs) the analysis of ion-exchangeable sites was performed by means of a combined method based on IR spectroscopic and calorimetric measurements using CO as the probe molecule. The heat of adsorption of CO was found to be correlated with an IR frequency of stretching vibration of C-O in the adsorbed species. It was revealed that there exists at least two types of sites capable of ion-exchanging; for the lithium ion-exchanged ZSM-5 (LiZSM-5) CO adsorption on each type of site is evaluated to give a set of IR bands and heats of adsorption, 2195 cm(-1) and 49 kJ mol(-1), 2185 cm(-1) and 39 kJ mol(-1) with the aid of the newly developed method utilizing the data obtained from a combined microcalorimetric and IR-spectroscopic study. Such types of data were also obtained for Na- and K-ion-exchanged ZSM-5 samples. Furthermore, a linear relationship between the differential heat of adsorption (q(diff)) evaluated and the shift of wavenumber of the C-O stretching vibration from that of a gaseous CO molecule (Deltanu) was established for the systems of MZSM-5-CO, and the bonding nature of the CO molecule with each site can be explained in terms of the electrostatic force. The model of each adsorption site was also examined by the quantum calculation method (density functional theory: DFT). The trends obtained from the experimental data may be substantially supported by the calculation method even adopting a model as simple as the ZSM-5-type zeolite: the composition of MAlSi(4)O(4)H(12).

  13. Thermochemistry of uranium compounds: XVI, Calorimetric determination of the standard molar enthalpy of formation at 298.15 K, low-temperature heat capacity, and high-temperature enthalpy increments of UO{sub 2}(OH){sub 2} {center_dot} H{sub 2}O (schoepite)

    Energy Technology Data Exchange (ETDEWEB)

    Tasker, I.R.; O`Hare, P.A.G.; Lewis, B.M.; Johnson, G.K.; Cordfunke, E.H.P.

    1987-08-01

    Three precise calorimetric methods, viz., low-temperature adiabatic, high-temperatuare drop, and solution-reaction, have been used to determine as a function of temperature the key chemical thermodynamic properties of a pure sample of schoepite, UO{sub 2}(OH){sub 2} {center_dot} H{sub 2}O. The following results have been obtained at the standard reference temperature T = 298.15 K:standard molar enthalpy of formation {Delta}/sub f/H/sub m/{sup 0}(T) = {minus}1825.4 +- 2.1 kJ mol/sup {minus}1/; molar heat capacity C/sub p,m/{sup 0}(T) = 172.07 +- 0.34 JK/sup {minus}1/; and the standard molar entropy S/sub m/{sup 0}(T) = 188.54 +- 0.38 JK/sup {minus}1/ mol/sup {minus}1/. The molar enthalpy increments relative to 298.15 K and the molar heat capacity are given by the polynomials: {H{sub m}{sup 0}(T) {minus} H{sub m}{sup 0}(298.15 K)}/(J mol/sup {minus}1/) = {minus}38209.0 + 84.2375 (T/K) + 0.1472958 (T/K){sup 2} and C/sub p,m/{sup 0}(T)/(JK/sup {minus}1/ mol/sup {minus}1/) = 84.238 + 0.294592 (T/K), where 298.15 K < T < 400 K. The present result for {Delta}/sup f/H/sub m/{sup 0} at 298.15 K has been combined with three other closely-agreeing values from the literature to give a recommended weighted mean {Delta}/sub f/H/sub m/{sup 0} = {minus}1826.4 +- 1.7 kJ mol/sup {minus}1/, from which is calculated the standard Gibbs energy of formation {Delta}/sub f/G/sub m/{sup 0} = {minus}1637.0 +- 1.7 kJ mol/sup {minus}1/ at 298.15 K. Complete thermodynamic properties of schoepite are tabulated from 298.15 to 423.15 K. 19 refs., 6 tabs.

  14. Determinación de la variación de entalpía de la interacción entre el herbicida glifosato, y los iones de calcio, zinc y aluminio en solución acuosa por calorimetría isotérmica de titulación.

    Directory of Open Access Journals (Sweden)

    Flavio Adriano Bastos

    2010-12-01

    Full Text Available El glifosato [N-(fosfonometil glicina] es una molécula no selectivo ampliamente utilizado en Brasil como un desecante en los cultivos sin labranza, entre las hileras de los cultivos perennes y para la eliminación de las malezas en ambientes acuáticos. Es el herbicida más usado en el mundo. Debido a la presencia de grupos amino, carboxílico y fosfónico en su molécula, este herbicida es capaz de formar complejos con metales fuertes. El objetivo de este trabajo fue la determinación de los parámetros de la termodinámica de las interacciones entre el glifosato y el calcio, cobre, zinc y aluminio por calorimetría isotérmica de titulación (ITC. Los experimentos se llevaron a cabo a 298,15 K en una solución acuosa de pH controlado y es igual a 2,00. El tratamiento de los datos se realizó por el Método de la Tangente. Los resultados para el cambio de entalpía (kJ.mol-1, la energía libre de Gibbs (kJ.mol-1 y cambio de entropía (J.mol-1K-1, fueron, respectivamente: Ca (II = + 0,07 ± 0,01; - 18,8 ± 0,5, 63,0 ± 2; Cu (II = + 6,24 ± 0,06, - 67,9 ± 0,5, 249 ± 2; Zn (II = + 0,25 ± 0,01, - 49,7 ± 0,5, 167 ± 2 e Al (III = + 6,84 ± 0,45, - 78,2 ± 0,5, 285 ± 2. Los complejos formados son entrópicamente impulsado, desde el punto de vista energético, las interacciones se presentan muy pobres, que pueden ser observadas por los valores positivos del cambio de entalpia. Esto se debe principalmente a la eliminación de las moléculas de agua de hidratación de los iones de metal para la mayor parte de la solución. Con la información actual, podemos concluir que la complejidad del herbicida con el ion de aluminio es más fuerte que con otro cationes.

  15. Contribution to the micro-calorimetric study of the characteristics of radio-elements and to their qualitative and quantitative analysis; Contribution a l'etude microcalorimetrique des caracteristiques des radio-elements et a leurs analyses qualitative et quantitative

    Energy Technology Data Exchange (ETDEWEB)

    Ozias, Y. [Centre de Production de Plutonium de Marcoule, 30 (France)

    1964-10-01

    The principle of this study consists in using the E. CALVET microcalorimeter for recording the energy flux emitted by radio-elements as a function of time, and in determining from this curve either their characteristics (half-life and radiation energy), or the composition of a mixture of radio-elements. In the first part the theoretical relationships describing radioactivity have been adapted to the microcalorimetric study. In the second part an experimental determination has been made using the E. CALVET microcalorimeter of the characteristics of various radio-elements, yttrium 90, phosphorus 32, sulphur 35, iodine 131, etc and of their mixtures. In particular a study has been made of the isotopic analysis of a {sup 239}Pu - {sup 240}Pu mixture, sometimes in the presence of {sup 241}Pu. The microcalorimetric method is not as sensitive as conventional counting methods, its limit appears to be at the present about 1 micro-watt for the apparatus used, it is however the most direct method in the case of emitters of weakly absorbed radiation ({alpha} and {beta}). For the {gamma} emitters only a part of the energy is absorbed by the walls of the container. The determination of their characteristics and of their masses in the mixtures depends neither on the shape, on the dilution or even less on the auto-absorption of the source. For high activity samples this auto-absorption is the cause of great difficulties in conventional methods which complicate the operations: divisions, dissolutions, dilutions, all of which are liable to introduce errors. The calorimetric method makes it possible to work on the untreated sample. All these measurements have been carried out using the conventional E CALVET calorimeter; to carry out an exact measurement of the energy due to {gamma} radiation, however, it is necessary to build special apparatus with a lead block the size of which is given by the author's calculations. The calorimetric method makes it possible to attain an

  16. Calorimetric determinations and theoretical calculations of polymorphs of thalidomide

    Science.gov (United States)

    Lara-Ochoa, F.; Pérez, G. Espinosa; Mijangos-Santiago, F.

    2007-09-01

    The analysis of the thermograms of thalidomide obtained for the two reported polymorphs α and β by differential scanning calorimetry (DSC) shows some inconsistencies that are discussed in the present work. The conception of a new polymorph form, named β ∗, allowed us to explain the observed thermal behavior more satisfactorily. This new polymorph shows enantiotropy with both α and β polymorphs, reflected in the unique endotherm obtained in the DSC-thermograms, when a heating rate of 10 °C/min is applied. Several additional experiments, such as re-melting of both polymorph forms, showed that there is indeed a new polymorph with an endotherm located between the endotherms of α and β. IR, Raman, and powder X-ray permit us to characterize the isolated compound, resulting from the re-melting of both polymorph forms. Mechanical calculations were performed to elucidate the conformations of each polymorph, and ab initio quantum chemical calculations were performed to determine the energy of the more stable conformers and the spatial cell energy for both polymorphs α and β. These results suggested a possible conformation for the newly discovered polymorph β ∗.

  17. An enzymatic signal amplification system for calorimetric studies of cellobiohydrolases

    DEFF Research Database (Denmark)

    Murphy, Leigh; Baumann, Martin Johannes; Borch, Kim

    2010-01-01

    is heat production. This can be converted to the rate of reaction and allows direct and continuous monitoring of the hydrolysis of complex substrates. To overcome the low molar enthalpy of the hydrolysis of the glycosidic bond, which is typically on the order of −2.5 kJ mol−1, an enzymatic signal......The study of cellulolytic enzymes has traditionally been carried out using endpoint measurements by quantitation of reaction products using high-performance liquid chromatography (HPLC) or overall determination of produced reducing ends. To measure catalytic activity, model substrates...... amplification method has been developed to measure even slow hydrolytically active enzymes such as cellobiohydrolases. This method is explained in detail for the amplification of the heat signal by more than 130 times by using glucose oxidase and catalase. The kinetics of this complex coupled reaction system...

  18. Calorimetric investigations of solids by combined FPPE - TWRC method

    Energy Technology Data Exchange (ETDEWEB)

    Dadarlat, D; Streza, M; Pop, M N; Tosa, V [National R and D Institute for Isotopic and Molecular Technologies, Cluj-Napoca, Donath St. 65-103, 400293 Cluj-Napoca (Romania); Delenclos, S; Longuemart, S; Sahraoui, A Hadj, E-mail: dadarlat@itim-cj.r [Univeriste Lille Nord de France, F-59000 Lille (France); ULCO, LDSMM, F-59140 Dunkerque (France); CNRS UMR8024, F-59140 Dunkerque (France)

    2010-03-01

    An alternative photopyroelectric (PPE) technique that combines the front detection configuration (FPPE) with the thermal-wave-resonator-cavity (TWRC) method is proposed for direct measurement of thermal effusivity of solid materials inserted as backings in the FPPE detection cell. The method uses the scan of the normalized PPE phase as a function of sample's thickness, in the thermally thin regime for the sensor and liquid layer, and thermally thick regime for the backing material. The value of backing's thermal effusivity results from the optimization of the fit of the phase of the signal, performed with sample's thickness and backing's thermal effusivity as fitting parameters. The paper presents experimental results on several solid materials (inserted as backing in the cell), with different values of thermal effusivity (brass, steel, wood) and two liquids (ethylene glycol, water) largely used in the FPPE-TWRC cells. The paper stresses mainly on the sensitivity of the technique to different liquid/backing effusivity ratios. It seems that the method is suitable especially when investigating solids with values of thermal effusivity close to the effusivity of the liquid layer.

  19. A Calorimetric Search on Double Beta Decay of 130Te

    CERN Document Server

    Arnaboldi, C; Bucci, C; Capelli, S; Cremonesi, O; Fiorini, Ettore; Giuliani, A; Nucciotti, A; Pedretti, M; Pobes, C; Pavan, M M; Pessina, G; Pirro, S; Previtali, E; Sisti, M; Vanzini, M

    2003-01-01

    We report on the final results of a series of experiments on double decay of 130Te carried out with an array of twenty cryogenic detectors. The set-up is made with crystals of TeO2 with a total mass of 6.8 kg, the largest operating one for a cryogenic experiment. Four crystals are made with isotopically enriched materials: two in 128Te and two others in 130Te. The remaining ones are made with natural tellurium, which contains 31.7 % and 33.8 % 128Te and 130Te, respectively. The array was run under a heavy shield in the Gran Sasso Underground Laboratory at a depth of about 3500 m.w.e. By recording the pulses of each detector in anticoincidence with the others a 90 % C.L. lower limit of 2.1 x 10^{23}$ years has been obtained at the 90 % C.L. on the lifetime for neutrinoless double beta decay of 130Te. In terms of effective neutrino mass this is the most restrictive limit in direct experiments, after those obtained with Ge diodes. Limits on other lepton violating decays of 130Te and to the neutrinoless double be...

  20. Calorimetric study of binding of some disaccharides with crown ethers

    Energy Technology Data Exchange (ETDEWEB)

    Davydova, Olga I.; Lebedeva, Nataliya Sh.; Parfenyuk, Elena V

    2004-11-01

    Isothermal titration calorimetry has been applied to the determination of the thermodynamic parameters of binding of {beta}-lactose, {alpha},{alpha}-trehalose and sucrose with 15-crown-5 and 18-crown-6 in water at 298.15 K. The formation of 1:1 molecular associates has been found for the systems studied except 18-crown-6 and {beta}-lactose. The associates are preferentially or completely entropy stabilized. The most stable associate is formed between {alpha},{alpha}-trehalose and 18-crown-6. The obtained values of thermodynamic parameters of binding are discussed from the point of view of solute-solvent interactions as well as conformational and structural peculiarities of the disaccharides (DS) and crown ethers (CE)

  1. Calorimetric and neutron scattering studies of plastically crystalline cyclooctanol

    Energy Technology Data Exchange (ETDEWEB)

    Yamamuro, Osamu [Department of Chemistry and Research Centre for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Yamasaki, Hirotaka [Department of Chemistry and Research Centre for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Madokoro, Yasushi [Department of Chemistry and Research Centre for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Tsukushi, Itaru [Department of Physics, Chiba Institute of Technology, Narashino, Chiba 275-0023 (Japan); Matsuo, Takasuke [Department of Chemistry and Research Centre for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)

    2003-08-20

    The heat capacity of cyclooctanol was measured with an adiabatic calorimeter in the temperature range 5-340 K. Liquid cyclooctanol crystallized into crystal I, a plastic (orientationally disordered) phase. Crystal I was supercooled readily and underwent a glass transition at 160 K. Crystal II, obtained by annealing crystal I at about 200 K, also underwent a glass transition at 160 K, indicating that crystal II is also an orientationally disordered phase. On heating, crystal II transformed to crystal I at 261.7 K with a transition entropy of 8.06 J K{sup -1} mol{sup -1} and crystal I fused at 295.3 K with a fusion entropy of 7.00 J K{sup -1} mol{sup -1}. Neutron scattering of cyclooctanol was measured in the temperature range 20-335 K, energy range 0.1-20 meV and momentum transfer range 0.23-2.7 A{sup -1}. A clear boson peak was found around 2.5 meV in both orientational glasses of crystal I and II. Quasielastic scattering appeared at temperatures as low as the glass transition temperature. This may be due to a fast {beta} process which has been observed in most glass-forming liquids. The present results indicate that glass-forming plastic crystals are similar to glass-forming liquids in their dynamical properties in terahertz region.

  2. Calorimetric Measurements of Laser Energy and Power - 1977 Supplement

    Science.gov (United States)

    1977-10-10

    body is in the form of a shallow, slant-bottomed electro - formed copper cup of square cross section. The first absorber is cemented to the bottom of...Actinom- eter for Laser Intensity Measurement in Lasers in Physical Chemistry and Biophysics, J. Joussot- Dubin , Ed. (Elsevier, Amsterdam* 1975). 254. J

  3. Thermodynamic properties for polycyclic systems by non-calorimetric methods

    Energy Technology Data Exchange (ETDEWEB)

    Steele, W.V.; Chirico, R.D.; Klots, T.D.

    1993-03-01

    A detailed vibrational spectroscopic study of furan, pyrrole, and thiophene has been completed. These compounds form part of the base of five-membered ring systems on which the rest of the research program will be built Several methyl-substituted derivatives were also studied. The results will be used to confirm the model for alkyl- substitution in the ring systems. Gas-phase spectra and fundamental- frequency assignments were completed for 2,3- and 2,5-dihydrofuran. Those compounds initiate work on ring-puckering within the research program. A paper describing the need for third virial estimation, when using the virial equation of state to derive thermodynamic properties at pressures greater than 1 bar was completed.

  4. Calorimetric analysis of cryopreservation and freeze-drying formulations.

    Science.gov (United States)

    Sun, Wendell Q

    2015-01-01

    Differential scanning calorimetry (DSC) is a commonly used thermal analysis technique in cryopreservation and freeze-drying research. It has been used to investigate crystallization, eutectic formation, glass transition, devitrification, recrystallization, melting, polymorphism, molecular relaxation, phase separation, water transport, thermochemistry, and kinetics of complex reactions (e.g., protein denaturation). Such information can be used for the optimization of protective formulations and process protocols. This chapter gives an introduction to beginners who are less familiar with this technique. It covers the instrument and its basic principles, followed by a discussion of the methods as well as examples of specific applications.

  5. Calorimetric Determination of Enthalpy of Formation of Natural Gas Hydrates

    Institute of Scientific and Technical Information of China (English)

    高军; KennethN.Marsh

    2003-01-01

    This paper reports the measurements of enthalpies of natural gas hydrates in typical natural gas mixture containing methane, ethane, propane and iso-butane at pressure in the vicinity of 2000 kPa (300 psi) and 6900 kPa(1000psi). The measurements were made in a multi-cell differential scanning calorimeter using modified high pressure cells. The enthalpy of water and the enthalpy of dissociation of the gas hydrate were determined from the calorimeter response during slow temperature scanning at constant pressure. The amount of gas released from the dissociation of hydrate was determined from the pumped volume of the high pressure pump. The occupation ratio (mole ratio) of the water to gas and the enthalpy of hydrate formation are subject to uncertainty of 1.5%.The results show that the enthalpy of hydrate formation and the occupation ratio are essentially independent of pressure.

  6. Calorimetric study of frozen-in disordered solids

    Energy Technology Data Exchange (ETDEWEB)

    Suga, Hiroshi [Faculty of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)

    2003-03-26

    The freezing-in phenomena that occurred in some orientationally disordered crystals and liquid crystals, either in the metastable or in the stable state, are described in comparison with those in liquids. These observations indicate clearly that the glass transitions observed exclusively in liquids are just one example of 'transitions' which must occur widely in condensed states of matter, irrespective of the structural regularity. The interplay between phase and glass transitions in crystals is discussed in relation to useful dopants that accelerate some molecular motions resulting in failure to maintain equilibrium at low temperatures. The structural relaxation occurring in vapour-quenched amorphous solids is studied using an adiabatic calorimeter operated as a low-frequency spectrometer. The anomalous behaviour of the configurational entropy S{sub c} observed for some molecular systems is discussed. The solid-state vitrification of molecular crystals caused by mechanical milling and the formation of molecular alloys for some binary systems are described, with potential applications.

  7. Calorimetric study of frozen-in disordered solids

    Science.gov (United States)

    Suga, Hiroshi

    2003-03-01

    The freezing-in phenomena that occurred in some orientationally disordered crystals and liquid crystals, either in the metastable or in the stable state, are described in comparison with those in liquids. These observations indicate clearly that the glass transitions observed exclusively in liquids are just one example of 'transitions' which must occur widely in condensed states of matter, irrespective of the structural regularity. The interplay between phase and glass transitions in crystals is discussed in relation to useful dopants that accelerate some molecular motions resulting in failure to maintain equilibrium at low temperatures. The structural relaxation occurring in vapour-quenched amorphous solids is studied using an adiabatic calorimeter operated as a low-frequency spectrometer. The anomalous behaviour of the configurational entropy Sc observed for some molecular systems is discussed. The solid-state vitrification of molecular crystals caused by mechanical milling and the formation of molecular alloys for some binary systems are described, with potential applications.

  8. Calorimetric Characterizacion of PLLA-MWCNTs and PLLA-MWCNTsf

    Science.gov (United States)

    Albano, C.; Gonzalez, G.; Karam, A.; Covis, M.

    2010-06-01

    In the present work the thermal characterization of composites of polylactide (PLLA) with pristine or functionalized multiwalled carbon nanotubes (MWCNTs) prepared by the method solution mixing. The effect of % MWCNTs added on the thermal transitions was evaluated.

  9. Calorimetric methods for the study of fungi on building materials

    OpenAIRE

    Li, Yujing

    2004-01-01

    The aim of this project is to study the fungal growth habits on building materials as a function of humidity, temperature and other environmental parameters. The method of calorimetry is used as a way to quantify fungal activity on building materials. Calorimetry is a general, but sensitive method that can continuously monitor biological processes as a function of environmental conditions. In this report, three different studies are presented: (1) A calorespirometric device was developed and ...

  10. Calorimetric Study of Thermal Denaturation of Superoxide Dismutase

    Institute of Scientific and Technical Information of China (English)

    王邦宁; 谈夫

    1994-01-01

    The thermal denaturation of superoxide dismutase (SOD) from bovine erythrocytes was studied at various pH values of different buffers and at various concentrations of solutions of two neutral salts by differential scanning calorimetry. The experiments performed indicate that the PIPES is a buffer non-coordinating with the SOD, and that the binding of the anions studied influences more or less the thermal denaturation of SOD, but the effect on the oxidation form of SOD is more apparent. A new conformer of SOD with lower thermostability was discovered by the experiments performed in different buffers at certain pH values higher than the isoelectric point of SOD, or at higher concentrations of neutral salt solutions. The new conformer may be converted irreversibly into the usual conformer with high thermostability during heating. Based on the thermodynamic parameters obtained in distilled water and by thermodynamic analysis using the Ooi’s model, it is revealed that the large enthalpy △Hdc contributed by

  11. Calorimetric measurements on some undercooled metals and alloys

    Energy Technology Data Exchange (ETDEWEB)

    Baricco, M. [Turin Univ. (Italy). Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali; Battezzati, L. [Turin Univ. (Italy). Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali; Rizzi, P. [Turin Univ. (Italy). Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali

    1995-04-01

    Undercooling was achieved directly in the cell of a high temperature calorimeter (Setaram HTDSC) for Ni, Fe, Cu, Pd and several alloys, using cooling rates between 1 and 15 K min{sup -1}. The samples were immersed in alumina powder inside a standard alumina crucible under flowing helium. Ag, Au and Al were not undercooled significantly. The reproducibility of the measurements was within 1.5%. The heat of solidification of Ni at an undercooling of {Delta}T=220 K was -17.5{+-}0.2 kJ mol{sup -1}, which is the same absolute value of the heat of fusion at the equilibrium melting point T{sub m}. This implies that the specific heat of the undercooled liquid is very close to that of the crystalline solid in this temperature range. Fe appears to display a similar behavior at {Delta}T=220 K. The difference between the heat of fusion at T{sub m} and the heat of solidification at an average value of {Delta}T=95 K is significant for a Pd{sub 77.5}Cu{sub 6}Si{sub 16.5} glass-forming alloy. From these data, we calculated an average specific heat difference between the liquid and crystal phases of 7{+-}5 J mol{sup -1} K{sup -1}. The enthalpy data for Pd{sub 82}Si{sub 18} comply with those of the ternary Pd-Cu-Si. ((orig.))

  12. Estudio cinético del efecto de polifenilsulfona sobre el curado de una resina epoxi/amina mediante calorimetría diferencial de barrido convencional y modulada con temperatura: parte II Kinetic study on the effect of curing polyphenylsulfone epoxy resin/amina by differential calorimetry scanning conventional and modulated temperature: part II

    Directory of Open Access Journals (Sweden)

    Asdrúbal J. Cedeño

    2010-01-01

    Full Text Available En este trabajo se estudió el efecto de la adición del termoplástico lineal polifenilsulfona (PPSU, sobre la cinética de reacción y las propiedades térmicas de una resina epoxídica basada en diglicidil éter de bisfenol - A (DGEBA, curada con diaminodifenilsulfona (DDS. El estudio cinético y la caracterización se realizaron mediante calorimetría diferencial de barrido, DSC estándar y modulado, bajo condiciones isotérmicas y dinámicas. La cinética del curado se discutió en el marco de tres modelos cinéticos: Kissinger, Flynn-Wall-Ozawa y el modelo cinético de orden n. Para describir la reacción de curado en su última etapa, se usó la relación semiempírica propuesta por Chern y Poehlein para considerar la influencia de la difusión sobre la rapidez de reacción. El mecanismo de curado, para todos los sistemas, se ajustó a una cinética de orden n, a pesar del contenido de PPSU, y se observó que éste se hace muy controlado por la difusión conforme aumenta el contenido de PPSU y conforme la temperatura de curado disminuye. El tiempo de vitrificación de los sistemas exhibió una fuerte dependencia con el contenido de PPSU.In this work we studied the effect of the addition of the linear thermoplastic polyphenyl sulfone (PPSU on the cure kinetics and the thermal properties of a resin based on diglycidyl ether of bisphenol-A (DGEBA, cured with 4,4´-diaminodiphenyl sulfone (DDS. The kinetic study and the characterization process have been carried out by using differential scanning calorimetry, DSC, and temperature modulated DSC (TMDSC, under isothermal and dynamic conditions. The curing kinetics was discussed in the framework of three kinetic models: Kissinger, Flynn-Wall-Ozawa, and the model of reaction of order n. To describe the cured reaction in its last stage, we have used the semiempirical relationship proposed by Chern and Poehlein to take into account the influence of diffusion on the reaction rate. The cure mechanism

  13. A glow curve analyzer (GCA) for routine analysis of personnel thermoluminescent dosemeter results

    Energy Technology Data Exchange (ETDEWEB)

    Chase, W.J. [Health Physics Department, Ontario Power Generation, Whitby, Ont. (Canada)], E-mail: john.chase@opg.com; Bezaire, M.D. [Department of Applied Health Sciences, University of Waterloo, Waterloo, Ont. (Canada); Vanderzwet, F.P. [Bruce Power, P.O. Box 1540, Building B13, Tiverton, Ont., N0G 2T0 (Canada); Taylor, C.E. [Health Physics Department, Ontario Power Generation, Whitby, Ont. (Canada)

    2008-02-15

    A glow curve analyzer (GCA) spreadsheet has been developed using Microsoft Excel to perform glow curve analysis on thermoluminescent dosimeter (TLD) data from a personnel dosimetry system. The TLD data come from cards with four LiF:Mg,Ti chips that have been annealed and therefore have a simple glow peak structure. GCA removes spikes in the glow curve data, and then smoothes it. After select start and end points for the glow peak, it fits a Boltzmann function to represent the glow curve signal background under the glow peak. The Boltzmann function is subtracted and two Weibull curves are fit to the remaining net signal between the start and end points. The first Weibull curve is fit to peak 5, and the second one to any small remaining contribution from peaks 3 and 4 or from contaminants. The sum of the two Weibull curves is the glow curve signal result. GCA provides rapid review and correction of all glow curves, improving the quality of the results and reducing the time required for complete processing of official dose results.

  14. The design and implementation of the DIRK system for dosemeter issue and record keeping

    CERN Document Server

    Kendall, G M; Kay, P; Law, D V; Salmon, L; Saw, G M A

    1983-01-01

    DIRK, the computerised system which the National Radiological Protection Board employs for its Personal Monitoring Service, is described. DIRK is also used to store the data for the National Registry for Radiation Workers and could support the Central Index of Dose Information should this be set up. The general principles of the design of DIRK, as well as a detailed description of the system, are included in the report. DIRK is based on a set of interlocked index sequential files manipulated by PL/1 programs. Data compaction techniques are used to reduce by a factor of ten the size of the files stored on magnetic disk. Security of the database is most important and two levels of security have been implemented. Table driven techniques are used for updating the database. A specially designed free-format language is used for specifying changes. Statistics, sorted listings of selected data and summaries are provided by a general purpose program for this type of operation. However, it has still been necessary to w...

  15. Response of TL dosemeters to cosmic radiation on board passenger aircraft

    CERN Document Server

    Bilski, P; Marczewska, B; Olko, P

    2002-01-01

    Measurements were performed with various LiF based TLDs on board seven Polish aircraft, flying long-distance or middle-distance routes. All of the /sup 7/LiF detectors used (various types of /sup 7 /LiF:Mg, Ti and /sup 7/LiF:Mg, Cu, P detectors), which measure the non-neutron component of the radiation field, produced consistent results. It was found that the characteristics of the TLD response (ratio of different detector responses, glow curve shapes) after doses of radiation at flying altitudes differ from those obtained after exposure at the CERN facility (CERF), suggesting a lower contribution of densely ionising radiation. The neutron induced TL signal was also more affected by the thickness of the holder, suggesting the presence of a softer neutron energy spectrum at flight altitudes. Further in-flight and CERF exposures of detectors are planned to resolve these issues. (5 refs).

  16. Dose measurement in periapical radiographic exams using dosemeter pen: a look at the radioprotection

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Renato; Ferreira, Vanessa, E-mail: vanessamachado@ufmg.br [Curso Superior de Tecnologia em Radiologia. Faculdade de Medicina. Universidade Federal de Minas Gerais, Belo Horizonte, MG (Brazil); Pereira, Claubia; Oliveira, Arno H.; Veloso, M.A.F., E-mail: gbarros@nuclear.ufmg.br, E-mail: claubia@nuclear.ufmg.br, E-mail: heeren@nuclear.ufmg.br, E-mail: Dora@nuclear.ufmg.br [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Dept. de Engenharia Nuclear

    2011-07-01

    The use of radiology has been a large increase with the crescent accessibility to dental care, orthodontics and aesthetic. Besides the increase in the number of exams, there was an increase in radiation dose during dental exams such as computed tomography. The objective of this work is to evaluate the radiation dose to which the patient is subjected in a peri apical dental radiography. The dose values were measured with a dosimeter pen during radiographs in real exams peri apical with the X-ray equipment Timex 70 C Gnatus. During the exams realization, was maintained, in the holder, the dosimeter pen near to the region of interest. The values collected were recorded in dosimeter pen. These values were compared with the reference doses of the Portaria 453 of ANVISA, this procedure allows to verify if the recommended dose limits for this exam are being respected. These data indicates if the used equipment is calibrated and in good condition of use. It was performed a comparison between the obtained experimental dose values and the values found from computer simulation with the code MCNPX 2.6.0. (author)

  17. CW-OSL measurement protocols using optical fibre Al2O3:C dosemeters

    DEFF Research Database (Denmark)

    Edmund, J.M.; Andersen, C.E.; Marckmann, C.J.

    2006-01-01

    A new system for in vivo dosimetry during radiotherapy has been introduced. Luminescence signals from a small crystal of carbon-doped aluminium oxide (Al2O3:C) are transmitted through an optical fibre cable to an instrument that contains optical filters, a photomultiplier tube and a green (532 nm......) laser. The prime output is continuous wave optically stimulated luminescence (CW-OSL) used for the measurement of the integrated dose. We demonstrate a measurement protocol with high reproducibility and improved linearity, which is suitable for clinical dosimetry. A crystal-specific minimum pre...

  18. Assessing the potential for using biogenic calcites as dosemeters for luminescence dating

    Energy Technology Data Exchange (ETDEWEB)

    Duller, G.A.T. [Institute of Geography and Earth Sciences, Aberystwyth University, Ceredigion, SY23 3DB (United Kingdom)], E-mail: ggd@aber.ac.uk; Penkman, K.E.H. [BioArCh, Department of Chemistry, University of York, YO10 5DD (United Kingdom); Wintle, A.G. [Institute of Geography and Earth Sciences, Aberystwyth University, Ceredigion, SY23 3DB (United Kingdom)

    2009-05-15

    Calcium carbonate emits an intense thermoluminescence (TL) signal and previous work has explored the potential of using this signal to date both inorganic carbonates such as limestones and stalagmites and biogenic calcite produced by marine organisms. Luminescence analysis of biogenic calcites directly dates the secretion of the mineral by the organism and is therefore not reliant upon exposure of the sample to daylight. A method is outlined for using the TL signals from slug plates, from the Limacidae family, and opercula from the snail Bithynia tentaculata to construct a single-aliquot regenerative-dose growth curve. Analysis of slug plates from a number of Quaternary sites show that the equivalent dose (D{sub e}) of a late Holocene sample is close to zero and that the D{sub e} increases with age over the last 500 ka. The TL signal from snail opercula is shown to increase up to doses over 4000 Gy. Replicate measurements from 16 opercula from a site {approx}220 ka show a broad distribution. Potential causes of this scatter are discussed along with recommendations about how it could be reduced. The major challenge which remains to be solved before slug plates or snail opercula could be used to calculate ages is to develop methods for calculating the dose rate received during burial.

  19. Calibration of an eye lens dosemeter in terms of Hp(3) to be used in interventional radiology

    Science.gov (United States)

    Borges, F. L. S.; Guimarães, M. C.; Da Silva, T. A.; Nogueira Tavares, M. S.

    2014-11-01

    Recently, the International Commission on Radiological Protection has reviewed epidemiological evidences suggesting that there were tissue reaction effects in the eye lens below the previously considered absorbed dose threshold. A new statement related to the eye lens was issued that changed the absorbed dose threshold and reduced the dose limits for occupationally exposed persons. As consequence, some planned exposures require eye lens dosimetry and a debate was raised on the adequacy of the dosimetric quantity and on its method of measurement. The aim of this work was to study the methodology for calibrating the EYE-DTM holder with a TLD-100H Harshaw chip detector and to determine its angular and energy dependences in terms of personal dose equivalent, Hp(3).

  20. Principles for the design and calibration of radiation protection dosemeters for operational and protection quantities for eye lens dosimetry.

    Science.gov (United States)

    Bordy, J M; Gualdrini, G; Daures, J; Mariotti, F

    2011-03-01

    The work package two of the ORAMED project--Collaborative Project (2008-2011) supported by the European Commission within its seventh Framework Programme--is devoted to the study of the eye lens dosimetry. A first approach is to implement the use of H(p)(3) by providing new sets of conversion coefficients and well suited calibration and type test procedures. This approach is presented in other papers in the proceedings of this conference. Taking into account that the eye lens is an organ close to the surface of the body, another approach would be to directly estimate the absorbed dose to the eye lens, D(lens,est) through a special calibration procedure although this quantity is not directly measurable. This paper is a methodological paper that tries to identify the critical aspects of a dosimetry in terms of D(lens).

  1. Measurements of the high energy neutron component of cosmic radiation fields in aircraft using etched track dosemeters

    CERN Document Server

    Bartlett, D T; Tanner, R J; Steele, J D

    2001-01-01

    Measurements of the complex cosmic radiation field in aircraft at altitude are made with a passive survey meter comprising routine-use thermoluminescent detectors and etched track detectors. The energy dependence of response of the etched track detectors used to determine the neutron component has been characterized, partly, up to a neutron energy of 180 MeV. The neutron detectors are routinely calibrated in the CERN EC Ref.Field. The 15% determination level for total dose equivalent is 100 mu Sv. The evidence is that the passive survey meter provides a reliable determination of route dose. (41 refs).

  2. Study and development of new dosemeters for thermal neutrons; Estudio y desarrollo de nuevos dosimetros para neutrones termicos

    Energy Technology Data Exchange (ETDEWEB)

    Urena N, F

    1998-12-31

    An alanine-boron compound, alanine hydroborate, was synthesized and chemically characterized to be used for thermal neutrons fluence measurements. The synthesis of the compound was made by reacting the amino acid alanine with boric acid in three different media: acidic, neutral and alkaline. Physicochemical analysis showed that the alkaline medium is favorable for the synthesis of the alanine hydroborate. The compound was evaluated as a thermal neutron fluence detector by the detection of the free radical yield upon neutron thermal irradiation by Electron Paramagnetic Resonance (EPR). The present work also studies the EPR-signal response of the three preparations to thermal neutron irradiation ({phi} = 5 x 10{sup 7} n/cm{sup 2} -s). The following EPR signal parameters of the samples were investigated: peak-to-peak signal intensity vs. thermal neutron fluence {Phi} = {phi} {Delta}t ; where {Delta}t = 1, 5, 10, 20, 40, 60, 80, 90, 100, 110 and 120 h. , peak-to-peak signal intensity vs. microwave power, signal fading; repeatability, batch homogeneity, stability and zero dose response. It is concluded that these new products could be used in thermal neutron fluence estimations. (Author)

  3. Evaluation of dose equivalent by the electronic personal dosemeter for neutron 'Saphydose-N' at different workplaces of nuclear facilities.

    Science.gov (United States)

    Chau, Q; Lahaye, T

    2007-01-01

    This paper presents the results of measurements made with the electronic personal neutron Saphydose-N during the four campaigns of the European contract EVIDOS (EValuation of Individual DOSimetry in mixed neutron and photon radiation fields). These measurements were performed at Institute for Radiological Protection and Nuclear Safety (IRSN) in France (C0), at the Krümmel Nuclear Power Plant in Germany (C1), at the VENUS Research Reactor and the Belgonucléaire fuel processing plant in Belgium (C2) and at the Ringhals Nuclear Power Plant in Sweden (C3). The results for Saphydose-N are compared with reference values for dose equivalent.

  4. Measuring instruments and challenges in radiation-protection measuring techniques; Messgeraete und Herausforderungen in der Strahlenschutzmesstechnik

    Energy Technology Data Exchange (ETDEWEB)

    Hupe, Oliver [Physikalisch-Technische Bundesanstalt (PTB), Braunschweig (Germany). Arbeitsgruppe ' Photonendosimetrie'

    2013-06-15

    After a description of the different types of radiation detectors the application of these detectors for dosimetry are discussed, whereby personnel dosemeters and stationary dosemeters are considered. (HSI)

  5. Estimation of protein folding free energy barriers from calorimetric data by multi-model Bayesian analysis.

    Science.gov (United States)

    Naganathan, Athi N; Perez-Jimenez, Raul; Muñoz, Victor; Sanchez-Ruiz, Jose M

    2011-10-14

    The realization that folding free energy barriers can be small enough to result in significant population of the species at the barrier top has sprouted in several methods to estimate folding barriers from equilibrium experiments. Some of these approaches are based on fitting the experimental thermogram measured by differential scanning calorimetry (DSC) to a one-dimensional representation of the folding free-energy surface (FES). Different physical models have been used to represent the FES: (1) a Landau quartic polynomial as a function of the total enthalpy, which acts as an order parameter; (2) the projection onto a structural order parameter (i.e. number of native residues or native contacts) of the free energy of all the conformations generated by Ising-like statistical mechanical models; and (3) mean-field models that define conformational entropy and stabilization energy as functions of a continuous local order parameter. The fundamental question that emerges is how can we obtain robust, model-independent estimates of the thermodynamic folding barrier from the analysis of DSC experiments. Here we address this issue by comparing the performance of various FES models in interpreting the thermogram of a protein with a marginal folding barrier. We chose the small α-helical protein PDD, which folds-unfolds in microseconds crossing a free energy barrier previously estimated as ~1 RT. The fits of the PDD thermogram to the various models and assumptions produce FES with a consistently small free energy barrier separating the folded and unfolded ensembles. However, the fits vary in quality as well as in the estimated barrier. Applying Bayesian probabilistic analysis we rank the fit performance using a statistically rigorous criterion that leads to a global estimate of the folding barrier and its precision, which for PDD is 1.3 ± 0.4 kJ mol(-1). This result confirms that PDD folds over a minor barrier consistent with the downhill folding regime. We have further validated the multi-model Bayesian approach through the analysis of two additional protein systems: gpW, a midsize single-domain with α + β topology that also folds in microseconds and has been previously catalogued as a downhill folder, and α-spectrin SH3, a domain of similar size but with a β-barrel fold, slow-folding kinetics and two-state-like thermodynamics. From a general viewpoint, the Bayesian analysis developed here results in a statistically robust, virtually model-independent, method to estimate the thermodynamic free-energy barriers to protein folding from DSC thermograms. Our method appears to be sufficiently accurate to consistently detect small differences in the barrier height, and thus opens up the possibility of characterizing experimentally the changes in thermodynamic folding barriers induced by single-point mutations on proteins within the downhill regime.

  6. Calorimetric Quantification of Cyclodextrin-Mediated Detergent Extraction for Membrane-Protein Reconstitution.

    Science.gov (United States)

    Textor, Martin; Keller, Sandro

    2016-01-01

    For many in vitro studies, purified membrane proteins need to be reconstituted from detergent micelles into lipid bilayers to regain their native structures and functions. Stoichiometric complexation of detergent by cyclodextrin provides a tightly controllable strategy for detergent extraction. Here, we describe a practical approach making use of isothermal titration calorimetry to obtain a complete set of thermodynamic parameters that allows for quantitative prediction of the transition from micelles to bilayer membranes during reconstitution. These parameters include the dissociation constant of the cyclodextrin/detergent inclusion complex, the critical micellar concentration of the detergent, and the phase boundaries of the lipid/detergent phase diagram. The underlying theoretical framework involves linked equilibria among all pseudophases, as described previously (Textor, Vargas, & Keller, 2015). This chapter focuses on practical aspects of the approach and discusses caveats and calorimetry-specific details of data analysis. With the entire parameter set at hand, exploration of different reconstitution trajectories within the lipid/detergent phase diagram is possible. Together with the straightforward control over the rate of detergent extraction offered by cyclodextrin complexation, this opens the possibility of systematically tuning and optimizing the reconstitution process of membrane proteins. Provided some particular precautions are taken, the approach can be adapted to many other combinations of proteins, lipids, detergents, and cyclodextrins.

  7. Solution-reaction Calorimetric Study of Coordination Compounds of Rare Earth Perchlorates with Alanine and Imidazole

    Institute of Scientific and Technical Information of China (English)

    ZHAO, Yan-Ru(赵艳茹); HOU, An-Xin(侯安新); DONG, Jia-Xin(董家新); ZHAO, Shun-Sheng(赵顺省); LIU, Yi(刘义); QU, Song-Sheng(屈松生)

    2004-01-01

    Two coordination compounds of rare earth perchlorates with alanine and imidazole, [RE(Ala)n(Im)(H2O)](ClO4)3(s) (RE=La, n=3; RE=Nd, n=2), have been prepared and characterized. The standard molar enthalpies of reaction for the following two reactions, LaCL·7H2O(s)+3Ala(s)+Im(s)+3NaClO4(s)=[La(Ala).(Im)(H2O)]-(ClO4)3(s)+3NaCl(s)+6H2O(I)(1)and NdCl3·6H2O(s)+2Ala(s)+2Ala(s)+Im(s)+3NaClO4(s)=[Nd(Ala)2(Im)(H2O)]-(ClO4)3(s)+3NaCl(s)+5H2O(l) (2), were determined by solution-reaction calorimetry, at T=298.15 K, as 36.168 ±0.642kJ·mol-1 and 48.590±0.934kJ·mol-1 respectively. From the results and other auxiliary quantities, the standard molar enthalpies of formation of [La(Ala)3(Im)(H2O)](ClO4)3(s) and [Nd(Ala)2(Im)(H2O)] (ClO4)3(s) were derived,△fH(-)m{[La(Ala).(Im)(H2O)](ClO4)3,s}=(-2984.8±1.0)kJ·mol-1 and △fH(-)m{[Nd(Ala).(Im)(H2O)]-(ClO4)3,s}=(-2387.8±0.8)kJ·mol-1, respectively.

  8. Calorimetric determination of rate constants and enthalpy changes for zero-order reactions.

    Science.gov (United States)

    Almeida e Sousa, Luis; Beezer, Anthony E; Hansen, Lee D; Clapham, David; Connor, Joseph A; Gaisford, Simon

    2012-06-07

    Calorimetry is a general method for determination of the rates of zero-order processes, but analysis of the data for the rate constant and reaction enthalpy is difficult because these occur as a product in the rate equation so evaluation of one requires knowledge of the other. Three methods for evaluation of both parameters, without prior knowledge, are illustrated with examples and compared with literature data. Method 1 requires the reaction to be studied in two buffers with different enthalpies of ionization. Method 2 is based on calculation of reaction enthalpy from group additivity functions. Method 3 applies when reaction progresses to completion. The methods are applied to the enzymatic hydrolysis of urea, the hydrolysis of acetylsalicylic acid, and the photodegradation of nifedipine, respectively.

  9. Influence of lipophilicity on drug-cyclodextrin interactions: A calorimetric study

    Energy Technology Data Exchange (ETDEWEB)

    Waters, Laura J., E-mail: l.waters@hud.ac.uk [School of Applied Sciences, University of Huddersfield, Queensgate, Huddersfield, HD1 3DH (United Kingdom); Bedford, Susan; Parkes, Gareth M.B. [School of Applied Sciences, University of Huddersfield, Queensgate, Huddersfield, HD1 3DH (United Kingdom); Mitchell, J.C. [Medway Sciences, School of Science, University of Greenwich at Medway, Chatham Maritime, Kent ME4 4TB (United Kingdom)

    2010-11-20

    This study presents a systematic investigation of the interaction of three functionally related drugs, ibuprofen, ketoprofen and flurbiprofen, with two distinct forms of cyclodextrin at three specific temperatures, 298, 303 and 310 K using isothermal titration calorimetry (ITC). Although all three pharmaceutical compounds have similar pKa values, they exhibit widely differing lipophilicities. While previous authors have presented data regarding the binding of flurbiprofen and ibuprofen with {beta}-cyclodextrin, this is the first report of the interaction of all three drug substances with {beta}-cyclodextrin and 2-(hydroxypropyl)-{beta}-cyclodextrin at controlled pH and temperature. For all scenarios, the associated changes in Gibbs free energy, enthalpy and entropy are presented alongside the stoichiometry and binding constants concerned. In all cases the binding was found to occur at a 1:1 ratio with an associated negative enthalpy and Gibbs free energy with the formation of the complex enthalpically, rather than entropically driven. The data further demonstrates a clear relationship between the thermodynamic behaviour and log P of the drug molecules. This work confirms the suitability of ITC to determine thermodynamic data for drug-cyclodextrin complex formations and provides an insight into the selection of appropriate cyclodextrins for bespoke pharmaceutical formulations.

  10. Calorimetric studies of non-isothermal crystallization in amorphous CuTi100– alloys

    Indian Academy of Sciences (India)

    N Mehta; K Singh; N S Saxena

    2011-12-01

    The present paper reports the composition dependence of pre-exponential factor and activation energy of non-isothermal crystallization in amorphous alloys of CuTi100– system using differential scanning calorimeter (DSC) technique. The applicability of Meyer–Neldel relation between the pre-exponential factor and activation energy of non-isothermal crystallization for amorphous alloys of Cu–Ti system was verified.

  11. Calorimetric and thermal analysis studies on the binding of phenothiazinium dye thionine with DNA polynucleotides

    Energy Technology Data Exchange (ETDEWEB)

    Paul, Puja; Hossain, Maidul [Biophysical Chemistry Laboratory, Indian Institute of Chemical Biology, CSIR, Kolkata 700 032 (India); Suresh Kumar, Gopinatha, E-mail: gskumar@iicb.res.in [Biophysical Chemistry Laboratory, Indian Institute of Chemical Biology, CSIR, Kolkata 700 032 (India)

    2011-07-15

    Research highlights: > Thionine binds to DNA exhibiting alternating guanine-cytosine sequence selectivity. > Exothermic bindings were favoured by negative enthalpy and positive entropy changes. > The binding was characterized by strong thermal stabilization of the polynucleotides. > Complete energetics revealed from the salt and temperature dependent data. - Abstract: Binding of the phenothaizinium dye thionine with four sequence specific deoxyribopolynucleotides, poly(dG-dC).poly(dG-dC), poly(dG).poly(dC), poly(dA-dT).poly(dA-dT), and poly(dA).poly(dT) has been investigated by means of thermal helix melting, isothermal titration calorimetry, and differential scanning calorimetry experiments. The binding affinity values evaluated from isothermal titration calorimetry suggests that thionine exhibits the highest binding affinity to poly(dG-dC).poly(dG-dC). The binding to poly(dG-dC).poly(dG-dC), poly(dA-dT).poly(dA-dT), and poly(dG).poly(dC) is exothermic and favoured by negative enthalpy changes while binding to poly(dA).poly(dT) is endothermic and anomalous. The values of heat capacity changes of the interaction are negative and in the range (-0.4 to -0.5) kJ . K{sup -1} . mol{sup -1}. The binding is characterized by strong stabilization of the polynucleotides against thermal strand separation. The binding affinity values derived from thermal melting data are in excellent agreement with those obtained from isothermal titration calorimetry data. Insights into the energetic aspects and guanine-cytosine selectivity of the DNA interaction of thionine have been obtained from these studies.

  12. A neutron-X-ray, NMR and calorimetric study of glassy Probucol synthesized using containerless techniques

    Energy Technology Data Exchange (ETDEWEB)

    Weber, J.K.R., E-mail: rweber@anl.gov [Materials Development, Inc., Arlington Heights, IL 60004 (United States); Argonne National Laboratory, Argonne, IL 60439 (United States); Benmore, C.J. [Argonne National Laboratory, Argonne, IL 60439 (United States); Department of Physics, Arizona State University, AZ 85287 (United States); Tailor, A.N.; Tumber, S.K. [Materials Development, Inc., Arlington Heights, IL 60004 (United States); Neuefeind, J. [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Cherry, B. [Magnetic Resonance Research Center, Arizona State University, AZ 85287 (United States); Department of Chemistry and Biochemistry, Arizona State University, AZ 85287 (United States); Yarger, J.L. [Department of Physics, Arizona State University, AZ 85287 (United States); Magnetic Resonance Research Center, Arizona State University, AZ 85287 (United States); Department of Chemistry and Biochemistry, Arizona State University, AZ 85287 (United States); Mou, Q. [Magnetic Resonance Research Center, Arizona State University, AZ 85287 (United States); Department of Chemistry and Biochemistry, Arizona State University, AZ 85287 (United States); Weber, W. [Department of Physics, Arizona State University, AZ 85287 (United States); Department of Chemistry and Biochemistry, Arizona State University, AZ 85287 (United States); Byrn, S.R. [Department of Industrial and Physical Pharmacy, Purdue University, IN 47907 (United States)

    2013-10-16

    Highlights: • Acoustic levitation was used to make phase-pure glassy forms of pharmaceutical compounds. • Neutrons, X-rays and NMR were used to characterize the glasses. • The glass comprised of slightly distorted molecules packed in a random network. • Potential for new drug synthesis routes is discussed. - Abstract: Acoustic levitation was used to trap 1–3 mm diameter drops of Probucol and other pharmaceutical materials in containerless conditions. Samples were studied in situ using X-ray diffraction and ex situ using neutron diffraction, NMR and DSC techniques. The materials were brought into non-equilibrium states by supersaturating solutions or by supercooling melts. The glass transition and crystallization temperatures of glassy Probucol were 29 ± 1 and 71 ± 1 °C respectively. The glassy form was stable with a shelf life of at least 8 months. A neutron/X-ray difference function of the glass showed that while molecular sub-groups remain rigid, many of the hydrogen correlations observed in the crystal become smeared out in the disordered material. The glass is principally comprised of slightly distorted Form I Probucol molecules with disordered packing rather than large changes in the individual molecular structure. Avoiding surface contact-induced nucleation provided access to highly non-equilibrium phases and enabled synthesis of phase-pure glasses.

  13. Characterization of Monoclonal Gammopathy of Undetermined Significance by Calorimetric Analysis of Blood Serum Proteome

    Science.gov (United States)

    Barceló, Francisca; Cerdà, Joan J.; Gutiérrez, Antonio; Jimenez-Marco, Teresa; Durán, M. Antonia; Novo, Andrés; Ros, Teresa; Sampol, Antonia; Portugal, José

    2015-01-01

    Monoclonal gammopathy of undetermined significance (MGUS) is a premalignant proliferative disorder that may progress to multiple myeloma, a malignant plasma cell neoplasia. We evaluated differential scanning calorimetry (DSC) as an experimental tool for differentiating serum samples of MGUS patients from healthy individuals. DSC thermograms can be used for monitoring changes in the serum proteome associated with MGUS. MGUS patients showed great variability in serum thermogram characteristics, which depended on the IgG, IgA or IgM isotypes and/or the κ or λ light chains. Thermogram feature parameters distinguished patients with MGUS from healthy people. Serum samples, named as non-MGUS, were also collected from patients with subjacent immunological pathologies who were discarded of having MGUS through serum immunofixation. They were used to verify the sensitivity of DSC for discriminating MGUS from related blood dyscrasias. Only some DSC thermogram feature parameters differentiated, to a lesser extent, between MGUS and non-MGUS individuals. We contemplate DSC as a tool for early diagnosis and monitoring of MGUS. PMID:25794164

  14. A calorimetric study of phosphocholine membranes mixed with desmopressin and its diacylated prodrug derivative (DPP)

    DEFF Research Database (Denmark)

    Pedersen, T.B.; Frokjaer, S.; Mouritsen, Ole G.;

    2002-01-01

    of dimyristoyl, dipalmitoyl and distearoyl phosphatidylcholines the addition of DDAVP at concentrations of up to 10 mol% resulted in an insignificant change in the thermodynamic phase behaviour. In contrast, the dipalmitoylated DPP prodrug caused major changes on the lipid membrane phase behaviour manifested...... as a drastic decrease in the heat capacity peak height and a concomitant broadening of the main phase transition as well as a decrease in the transition enthalpy. In addition, the main phase transition temperature was slightly decreased and the pre-transition of the three phosphatidylcholines was abolished...

  15. Calorimetric measurement of adsorption and adhesion energies of Cu on Pt(111)

    Science.gov (United States)

    James, Trevor E.; Hemmingson, Stephanie L.; Sellers, Jason R. V.; Campbell, Charles T.

    2017-03-01

    The adsorption energies of submonolayer amounts of one metal on the surface of another metal have been measured for decades by temperature programmed desorption. However, that method fails for metals that alloy. We report here the first measurement of the adsorption energy for any such metal-on-metal combination that forms a bulk alloy. The adsorption and interfacial energetics of vapor deposited Cu onto Pt(111) at 300 K has been studied using single crystal adsorption calorimetry (SCAC) and X-ray photoelectron spectroscopy (XPS). The Cu grows as 2D pseudomorphic islands in the first layer and its heat of adsorption decreased linearly from 358 to 339 kJ/mol. This is attributed to increasing lattice strain with island size, associated with the small lattice mismatch (8%). It adsorbs 2 kJ/mol more weakly in the 2nd layer than above 3 ML, where it reaches the bulk heat of sublimation of Cu(solid), 337 kJ/mol. The adhesion energy of multilayer Cu onto Pt(111) is 3.76 J/m2. The extra stability of the first Cu monolayer compared to bulk Cu measured here is 12 kJ/mol, compared to a difference of 83 kJ/mol for underpotential deposition of Cu on a Pt(111) electrode, with the difference attributed to stronger bonding of Cu to the solvent and double layer compared to Pt.

  16. Calorimetric Study of Mesoporous SBA-15 Modified for Controlled Valproic Acid Delivery

    Directory of Open Access Journals (Sweden)

    Liliana Giraldo

    2013-01-01

    Full Text Available SBA-15 ordered mesoporous silica functionalized with (3-aminopropyltriethoxysilane (APTES was used as the carrier for anticonvulsant drug 2-propylpentanoic acid (valproic acid. The surface of SBA-15 containing free silanol groups was modified with 3-aminopropyltriethoxysilane via postsynthetic reaction. Functionalization of the carrier with basic aminopropyl groups resulted in an ionic interaction with acidic valproic acid. The samples of carriers and carrier-drug complexes were characterized by elemental analysis, N2 adsorption, FTIR, and UV spectroscopy. The adsorption of valproic acid on modified mesoporous matrix was proportional to the amount of introduced aminopropyl groups. A thermodynamic study with isothermal titration calorimetry (ITC was made to characterize the modification and encapsulation of SBA-15 with APTES and valproic acid, respectively. The maximum content of deposited drug in modified SBA-15 was close to 30 wt.%. Tests performed in acidic solution (pH 2.0 showed the best pharmaceutical availability.

  17. The Microcalorimeter Arrays for a Rhenium Experiment (MARE): a next-generation calorimetric neutrino mass experiment

    CERN Document Server

    Monfardini, A; Brofferio, C; Capelli, S; Capozzi, F; Cremonesi, O; Enss, C; Fiorini, E; Fleischmann, A; Foggetta, L; Gallinaro, G; Gastaldo, L; Gatti, F; Giuliani, A; Gorla, P; Kelley, R; Kilbourne, C A; Margesin, B; McCammon, D; Nones, C; Nucciotti, A; Pavan, M; Pedretti, M; Pergolesi, D; Pessina, G; Porter, F S; Prest, M; Previtali, E; Repetto, P; Ribeiro-Gomez, M; Sangiorgio, S; Sisti, M

    2006-01-01

    Neutrino oscillation experiments have proved that neutrinos are massive particles, but can't determine their absolute mass scale. Therefore the neutrino mass is still an open question in elementary particle physics. An international collaboration is growing around the project of Microcalorimeter Arrays for a Rhenium Experiment (MARE) for directly measuring the neutrino mass with a sensitivity of about 0.2eV/c2. Many groups are joining their experiences and technical expertise in a common effort towards this challenging experiment. We discuss the different scenarios and the impact of MARE as a complement of KATRIN.

  18. Calorimetric and ionimetric dosimetry intercomparisons II: d + T neutron source at the Antoni Van Leeuwenhoek hospital.

    Science.gov (United States)

    McDonald, J C; Ma, I C; Mijhnheer, B J; Zoetelief, H

    1981-01-01

    A series of dosimetric measurements was carried out at the Antoni van Leeuwenhoek Hospital, Amsterdam, using a Philips d + T generator, which produced neutrons with energies of approximately 14 MeV. A-150 plastic ionization chambers, an A-150 plastic calorimeter, and a GM dosimeter were used to determine total absorbed dose and the photon absorbed dose fraction. The ion chambers were calibrated in a 60Co gamma-ray field in air and compared in a phantom placed in the 60Co gamma-ray beam. Comparison of the total absorbed dose derived from the ionization chamber measurements to that determined using the calorimeter indicated agreement for the neutron measurements between the techniques to within +/- 2%.

  19. Laves phase in alloy 718 fusion zone — microscopic and calorimetric studies

    Energy Technology Data Exchange (ETDEWEB)

    Manikandan, S.G.K., E-mail: nehakutty06@gmail.com [Indian Space Research Organization, India, (India); Sivakumar, D., E-mail: d_sivakumar@vssc.gov.in [Indian Space Research Organization, India, (India); Prasad Rao, K., E-mail: jyothipr@gmail.com [University of Utah, Salt Lake City, UT (United States); Kamaraj, M., E-mail: kamaraj@iitm.ac.in [Indian Institute of Technology Madras (India)

    2015-02-15

    Microstructural characterization of alloy 718 fusion zone welded with both solid solution and age hardenable filler metal has been done. The microsegregation and the aging response were studied by employing three levels of weld cooling rate. Gas Tungsten Arc welding process was used. The fusion zone of solid solution filler metal has been responding to the aging treatment due to the weld process conditions and weld metal chemistry. However the weld metal composition was modified due to the higher molybdenum (Mo) content in solid solution filler metal. The effect of this modification on the phase reaction temperatures was studied and the same was compared with the conventional filler metal. - Graphical abstract: Display Omitted - Highlights: • Interdendritic segregation has been controlled by weld cooling rate. • Laves phase formation has been studied with cooling rate and weld metal chemistry. • Aging response with solid solution filler metal has been demonstrated. • Reduction in Laves phase and alloying element segregation has been confirmed. • Reaction temperatures were found modified because of Mo addition.

  20. Gravimetric analysis and differential scanning calorimetric studies on glycerin-induced skin hydration.

    Science.gov (United States)

    Lee, Ae-Ri Cho; Moon, Hee Kyung

    2007-11-01

    A thermal gravimetric analysis (TGA) and a differential scanning calorimetry (DSC) were carried out to characterize the water property and an alteration of lipid phase transition of stratum corneum (SC) by glycerin. In addition, the relationship between steady state skin permeation rate and skin hydration in various concentrations of glycerin was investigated. Water vapor absorption-desorption was studied in the hairless mouse stratum corneum. Dry SC samples were exposed to different conc. of glycerin (0-50%) followed by exposure to dry air and the change in weight property was monitored over time by use of TGA. In DSC study, significant decrease in DeltaH of the lipid transition in 10% glycerin and water treated sample: the heat of lipid transition of normal, water, 10% glycerin treated SC were 6.058, 4.412 and 4.316 mJ/mg, respectively. In 10% glycerin treated SCs, the Tc of water shifts around 129 degrees C, corresponding to the weakly bound secondary water. In 40% glycerin treated SC, the Tc of water shifts to 144 degrees C corresponding to strongly bound primary water. There was a good correlation between the hydration property of the skin and the steady state skin flux with the correlation coefficient (r2=0.94). As the hydration increased, the steady state flux increased. As glycerin concentration increased, hydration property decreased. High diffusivity induced by the hydration effect of glycerin and water could be the major contributing factor for the enhanced skin permeation of nicotinic acid (NA).

  1. Improved calorimetric procedure for monitoring the approach to thermodynamic equilibrium in glassy polymers

    Energy Technology Data Exchange (ETDEWEB)

    Lagasse, R.R.

    1982-02-01

    Techniques for measuring the enthalpy change during isothermal aging of polymer glasses are discussed. Critical analysis of conventional scanning calorimetry reveals that its accuracy may be suspect under certain circumstances due to the thermal lag inherent in a temperature scanning experiment. An additional problem is that the conventional technique is restricted to certain kinds of paths for reaching the aging temperature. It is proposed that both problems can be overcome by analyzing the output of a scanning calorimeter not only during the steady heating but also during an extension of a method used previously by others in accurate measurements of the much larger heat of fusion of crystalline polymers. Practical feasibility of the improved technique is demonstrated by preliminary measurements of enthalpy relaxation during aging of well-characterized polystyrene at 80/sup 0/C. In particular, the initial departure from equilibrium of a glass prepared by 5/sup 0/C/min cooling from the liquid state is found to be 6.9 +- 0.6 J/g. This measured value agrees with a value calculated on the basis of the glass transition temperature corresponding to 5/sup 0/C/min cooling and at-capacity data from the literature.

  2. Feasibility of large-scale calorimetric efficiency measurement for wind turbine generator drivetrains

    Science.gov (United States)

    Pagitsch, Michael; Jacobs, Georg; Schelenz, Ralf; Bosse, Dennis; Liewen, Christian; Reisch, Sebastian; Deicke, Matthias

    2016-09-01

    In the course of the global energy turnaround, the importance of wind energy is increasing continuously. For making wind energy more competitive with fossil energy, reducing the costs is an important measure. One way to reach this goal is to improve the efficiency. As the major potentials have already been exploited, improvements in the efficiency are made in small steps. One of the main preconditions for enabling these development activities is the sufficiently accurate measurement of the efficiency. This paper presents a method for measuring the efficiency of geared wind turbine generator drivetrains with errors below 0.5% by directly quantifying the power losses. The presented method is novel for wind turbines in the multi- MW-class.

  3. Calorimetric and neutron diffraction studies on transitions of water confined in nanoporous copper rubeanate.

    Science.gov (United States)

    Yamada, Takeshi; Yonamine, Ryo; Yamada, Teppei; Kitagawa, Hiroshi; Yamamuro, Osamu

    2010-07-01

    Copper rubeanate (H(2)C(2)N(2)S(2)Cu) has a nanoporous structure and exhibits high proton conductivity with adsorbing water inside the pores. We have studied the phase behavior and structure of the water confined in copper rubeanate hydrates (H(2)C(2)N(2)S(2)Cu.nH(2)O, n = 0, 2.1, 3.7) by adiabatic calorimetry and neutron powder diffraction. In the hydrate samples, a glass transition and a first-order transition appeared around 150 and 260 K, respectively. The transition entropy was similar to the entropy of fusion of bulk water, indicating that the adsorbed water is disordered above the transition temperature, like bulk water, and ordered below 150 K, like bulk ice. The neutron diffraction data demonstrated that both dry and hydrated copper rubeanates have amorphous structures over the temperature range 100-340 K. The analyses on the diffraction peak owing to the adsorbed water revealed that the transition at 260 K is a liquid-liquid transition due to the condensation of water on the surface of the pores, and the condensed water molecules are gradually ordered below 260 K and frozen-in at the glass transition around 150 K.

  4. New calorimetric system and some results of water phase transition research in plant roots.

    Science.gov (United States)

    Bakradze, N; Kiziria, E; Sokhadze, V; Gogichaishvili, Sh; Vardidze, E

    2007-01-01

    The principle of operation and main parameters of the recently created scanning differential reverse microcalorimeter of the new generation are presented. The microcalorimeter is destined for studying water crystallization and ice melting processes in heterogeneous systems, including plant and animal cells and tissues in the temperature range of 20 to -55 degrees C. In order to obtain maximum information from the experimental results respective algorithms and applied software package were developed. The results of studies of water crystallization and ice melting processes in different parts of common plantain (Plantago major L.) root, as a certain model system, can give us information on the peculiarities of the studied processes in complex, heterogeneous systems.

  5. Calorimetric determination of the water energy dosis; Kalorimetrische Bestimmung der Wasser-Energiedosis

    Energy Technology Data Exchange (ETDEWEB)

    Krauss, Achim [Physikalisch-Technische Bundesanstalt (PTB), Braunschweig (Germany). Arbeitsgruppe ' Einheit der Wasser-Energiedosis'

    2013-06-15

    The water calorimeter of the PTB is described, which consists of a water phantom operated at 4 C, whereby the radiation-induced temperature raise is measured by means of thermistors. As application example the determination of the radiation-quality dependent k{sub Q} factors of ionization chambers for all medical accelerators present in the PTB is described. (HSI)

  6. Spectroscopic and calorimetric studies on the triplex formation with oligonucleotide-ligand conjugates.

    Science.gov (United States)

    Eick, Andrea; Riechert-Krause, Fanny; Weisz, Klaus

    2010-06-16

    Several triplex-forming 9-mer oligonucleotide (TFO) conjugates with a methyl- or methoxy-substituted 5-phenyl-6H-indolo[3,2-b]quinoline (PIQ) attached at the 5'-terminus or 3'-terminus or at an internal C5 thymine position were synthesized and tested for their ability to form and stabilize a triple helix with a double-helical DNA target employing UV melting experiments, fluorescence titrations, and isothermal titration calorimetry (ITC). A considerable thermal stabilization by up to 14 degrees C at pH 6.0 was observed for the 5'- and 3'-conjugates with little influence on the type of substituent but also for a conjugate with the ligand tethered by a short linker to the interior of the 9-mer TFO. A detailed thermodynamic characterization of the unmodified TFO and its 5'-conjugate with a methyl-substituted ligand by ITC experiments yielded a DeltaDeltaG degrees of -1.8 kcal mol(-1) at pH 6.0 for the TFO-attached PIQ-triplex interaction and also revealed a favorable entropic contribution as the major determinant for the free energy of PIQ binding in the conjugate. The pH dependence of triplex thermal stability highlights the importance of ring protonation of the triplex-bound ligand for its effective interaction and triplex stabilization near physiological conditions.

  7. Crystallization kinetics of poly-(lactic acid) with and without talc: Optical microscopy and calorimetric analysis

    Science.gov (United States)

    Refaa, Z.; Boutaous, M.; Rousset, F.; Fulchiron, R.; Zinet, M.; Xin, S.; Bourgin, P.

    2014-05-01

    Poly-(lactic acid) or PLA is a biodegradable polymer synthesized from renewable resources. Recently, the discovery of new polymerization routes has allowed increasing the produced volumes. As a consequence, PLA is becoming of great interest for reducing the dependence on petroleum-based plastics. Because of its interesting mechanical properties, PLA is seen as a potential substitute for some usual polymers. However, its relatively slow crystallization kinetics can be a disadvantage with regard to industrial applications. The crystallization kinetics of PLA can be enhanced by adding nucleating agents, which also influences on crystalline morphology and rheological behavior. In the present work, the isothermal quiescent crystallization kinetics of both neat PLA and PLA/talc composite (5 wt% talc) are investigated. The effects of talc on the overall crystallization kinetics and on the crystalline morphology are analyzed using both optical microscopy measurements and thermal analysis by differential scanning calorimetry.

  8. Direct calorimetric analysis of the enzymatic activity of yeast cytochrome c oxidase.

    Science.gov (United States)

    Morin, P E; Freire, E

    1991-08-27

    The kinetic and thermodynamic parameters associated with the enzymatic reaction of yeast cytochrome c oxidase with its biological substrate, ferrocytochrome c, have been measured by using a titration microcalorimeter to monitor directly the rate of heat production or absorption as a function of time. This technique has allowed determination of both the energetics and the kinetics of the reaction under a variety of conditions within a single experiment. Experiments performed in buffer systems of varying ionization enthalpies allow determination of the net number of protons absorbed or released during the course of the reaction. For cytochrome c oxidase the intrinsic enthalpy of reaction was determined to be -16.5 kcal/mol with one (0.96) proton consumed for each ferrocytochrome c molecule oxidized. Activity measurements at salt concentrations ranging from 0 to 200 mM KCl in the presence of 10 mM potassium phosphate, pH 7.40, and 0.5 mM EDTA display a biphasic dependence of the electron transferase activity upon ionic strength with a peak activity observed near 50 mM KCl. The ionic strength dependence was similar for both detergent-solubilized and membrane-reconstituted cytochrome c oxidase. Despite the large ionic strength dependence of the kinetic parameters, the enthalpy measured for the reaction was found to be independent of ionic strength. Additional experiments involving direct transfer of the enzyme from low to high salt conditions produced negligible enthalpy changes that remained constant within experimental error throughout the salt concentrations studied (0-200 mM KCl). These results indicate that the salt effect on the enzyme activity is of entropic origin and further suggest the absence of a major conformational change in the enzyme due to changes in ionic strength.(ABSTRACT TRUNCATED AT 250 WORDS)

  9. Phase transitions in mixed-valence potassium manganese hexacyanoferrate Prussian blue analogue: Heat capacity calorimetric study

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharjee, A. [Department of Physics, Visva-Bharati, Santiniketan 731235 (India)]. E-mail: ashis@vbphysics.net.in; Saha, S. [Department of Chemistry, Jadavpur University, Kolkata 700032 (India); Koner, S. [Department of Chemistry, Jadavpur University, Kolkata 700032 (India); Miyazaki, Y. [Research Center for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)]. E-mail: miyazaki@chem.sci.osaka-u.ac.jp

    2007-05-15

    Phase transitions in K{sub 0.2}Mn{sub 0.66}{sup II}Mn{sub 1.44}{sup III}[Fe{sub 0.2}{sup II}Fe{sub 0.8}{sup III}(CN){sub 6}]O{sub 0.6}= {sub 6}(CH{sub 3}COO){sub 1.32}].7.6H{sub 2}O-a mixed valence PB analogue have been investigated with the help of heat capacity calorimetry under 0-90kOe magnetic fields in the 1.8-300K temperature range. Two heat capacity anomalies at 2.1 and 7.5K have been detected, which correspond to ferromagnetic and ferrimagnetic transitions, respectively. The magnitudes as well as the position of these thermal anomalies have varied with changing magnetic field. The estimated zero-field magnetic entropy amounted to 29.2JK{sup -1}mol{sup -1}, which is close to the expected value (33.7JK{sup -1}mol{sup -1}). The uniaxial zero-field splitting parameter is estimated to be D/k{sub B}=14.7K. A comparatively stronger antiferromagnetic interaction seems to lead to the magnetic transition around 7.3K, whereas a weaker ferromagnetic interaction gives rise to the thermal anomaly at 2.1K. The present results on magnetic phase transitions are in complete agreement with the earlier observations made through magnetic studies. Additionally, a glass transition at 194K has been observed in the heat capacity study presumably due to freezing of the orientational motion of the H{sub 2}O molecules present in the material. This phenomenon is reflected into the temperature dependence of the estimated Fe{sup III} and Fe{sup II} concentrations in the present material obtained earlier through Mossbauer spectroscopy.

  10. Three Dimensional Thermal Modeling of Li-Ion Battery Pack Based on Multiphysics and Calorimetric Measurement

    DEFF Research Database (Denmark)

    Khan, Mohammad Rezwan; Kær, Søren Knudsen

    2016-01-01

    . Inside the battery cells in the pack a lumped value of heat generation (HG), that works as a volumetric heat source, is used. The measured HG stems from the cell level isothermal calorimeter experiment. The batteries inside the pack stay in the same initial thermal state in the simulation case. The pack......A three-dimensional multiphysics-based thermal model of a battery pack is presented. The model is intended to demonstrate the cooling mechanism inside the battery pack. Heat transfer (HT) and computational fluid dynamics (CFD) physics are coupled for both time-dependent and steady-state simulation...

  11. Optical Fibre Fabry-Perot Interferometers for Calorimetric Heat Transfer Gauges

    Science.gov (United States)

    1992-12-01

    The potential advantages of a fibre optic sensor for made with the "stem on the cndwall of a cascade heat transfer measurement are 0i) high spatial...from the laser diode source to the fibre- The Measurements of heat flux using. a fibre optic - intensitv referencing scheme outlined abov’ý was...reflections and parasitic optical cavities within the platinum thin film resisitance gauges fibre optic network Such reflections were reduced b% design

  12. Calorimetric studies of the effect of -carotenoids on the thermotropic phase behavior of phosphatidylcholine bilayers

    OpenAIRE

    Widomska, Justyna; Kostecka-Gugała, Anna; Latowski, Dariusz; Gruszecki, Wiesław I.; Strzałka, Kazimierz

    2009-01-01

    Abstract Carotenoid geometry is a factor that determines their solubility and orientation in the lipid memebrane as well as antioxidant capacities and bioavailability. The effects of the cis-isomers of carotenoids (zeaxanthin and ?-carotene) on the thermotropic properties of lipid membranes formed with dimyristoylphosphatidylcholine (DMPC) and dipalmitoylphosphatidylcholine (DPPC) were investigated by means of differential scanning calorimetry. The results were compared with the ef...

  13. Functional energetic landscape in the allosteric regulation of muscle pyruvate kinase. 1. Calorimetric study.

    Science.gov (United States)

    Herman, Petr; Lee, J Ching

    2009-10-13

    Rabbit muscle pyruvate kinase (RMPK) is an important allosteric enzyme of the glycolytic pathway catalyzing a transfer of the phosphate from phosphoenolpyruvate (PEP) to ADP. The energetic landscape of the allosteric regulatory mechanism of RMPK was characterized by isothermal titration calorimetry (ITC) in the temperature range from 4 to 45 degrees C. ITC data for RMPK binding to substrates PEP and ADP, for the allosteric inhibitor Phe, and for combination of ADP and Phe were globally analyzed. The thermodynamic parameters characterizing the linked-multiple-equilibrium system were extracted. Four novel insights were uncovered. (1) The binding preference of ADP for either the T or R state is temperature-dependent, namely, more favorable to the T and R states at high and low temperatures, respectively. This crossover of affinity toward R and T states implies that ADP plays a complex role in modulating the allosteric behavior of RMPK. Depending on the temperature, binding of ADP can regulate RMPK activity by favoring the enzyme to either the R or T state. (2) The binding of Phe is negatively coupled to that of ADP; i.e., Phe and ADP prefer not to bind to the same subunit of RMPK. (3) The release or absorption of protons linked to the various equilibria is specific to the particular reaction. As a consequence, pH will exert a complex effect on these linked equilibria, resulting in the proton being an allosteric regulatory ligand of RMPK. (4) The R T equilibrium is accompanied by a significant DeltaC(p), rendering RMPK most sensitive to temperature under physiological conditions. During muscle activity, both pH and temperature fluctuations are known to happen; thus, results of this study are physiologically relevant.

  14. Combined force spectroscopy, AFM and calorimetric studies to reveal the nanostructural organization of biomimetic membranes.

    Science.gov (United States)

    Suárez-Germà, C; Morros, A; Montero, M T; Hernández-Borrell, J; Domènech, Ò

    2014-10-01

    In this work we studied a binary lipid matrix of 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphoethanolamine (POPE) and 1-palmitoyl-2-oleoyl-sn-glycero-3-phospho-(1'-rac-glycerol) (POPG), a composition that mimics the inner membrane of Escherichia coli. More specifically, liposomes with varying fractions of POPG were analysed by differential scanning calorimetry (DSC) and a binary phase diagram of the system was created. Additionally, we performed atomic force microscopy (AFM) imaging of supported lipid bilayers (SLBs) of similar compositions at different temperatures, in order to create a pseudo-binary phase diagram specific to this membrane model. AFM study of SLBs is of particular interest, as it is conceived as the most adequate technique not only for studying lipid bilayer systems but also for imaging and even nanomanipulating inserted membrane proteins. The construction of the above-mentioned phase diagram enabled us to grasp better the thermodynamics of the thermal lipid transition from a gel-like POPE:POPG phase system to a more fluid phase system. Finally, AFM force spectroscopy (FS) was used to determine the nanomechanics of these two lipid phases at 27°C and at different POPG fractions. The resulting data correlated with the specific composition of each phase was calculated from the AFM phase diagram obtained. All the experiments were done in the presence of 10 mM of Ca(2+), as this ion is commonly used when performing AFM with negatively charged phospholipids.

  15. Calorimetric measurement of the SOX anti-neutrino source for sterile neutrino search

    Energy Technology Data Exchange (ETDEWEB)

    Altenmueller, Konrad; Agostini, Matteo; Papp, Laszlo; Schoenert, Stefan [Physik Department and Excellence Cluster Universe, Technische Universitaet Muenchen (Germany); Collaboration: Borexino-Collaboration

    2015-07-01

    A thermal calorimeter is under development to measure with <1% accuracy the heat release of the Cerium anti-neutrino source for the SOX experiment, which is looking for eV-scale sterile neutrinos. The heat release is proportional to the source activity and thus to the emitted neutrino flux, which is an important parameter of the experiment. The calorimeter design is based on a copper heat exchanger mounted around the source with integrated water lines for the heat extraction. Heat loss through conduction and radiation is minimized by suspending the set-up through Kevlar ropes and inserting it inside a thermalized vacuum tank with radiation shields. The device is currently being assembled and tested at TUM in Garching.

  16. First results on neutrinoless double beta decay of Te-130 with the calorimetric cuoricino experiment

    Energy Technology Data Exchange (ETDEWEB)

    Arnaboldi, C.; Artusa, D.R.; Avignone, F.T.; Balata, M.; Bandac, I.; Barucci, M.; Beeman, J.W.; Brofferio, C.; Bucci, C.; Capelli, S.; Capozzi, F.; Carbone, L.; Cebrian, S.; Cremonesi, O.; Creswick, R.J.; de Waard, A.; Farach, H.A.; Fascilla, A.; Fiorini, E.; Frossati, G.; Giuliani, A.; Gorla, P.; Haller, E.E.; McDonald, R.J.; Morales, A.; Norman, E.B.; Nucciotti, A.; Olivieri, E.; Palmieri, E.; Pasca, E.; Pavan, M.; Pedretti, M.; Pessina, G.; Pirro, S.; Pobes, C.; Previtali, E.; Pyle, M.; Risegari, L.; Rosenfeld, C.; Sangiorgio, S.; Sisti, M.; Smith, A.R.; Torres, L.; Ventura, G.

    2003-12-04

    The first results are reported on the limit for neutrinoless double decay of {sup 130}Te obtained with the new bolometric experiment CUORICINO. The set-up consists of 44 cubic crystals of natural TeO{sub 2}, 5 cm on the side and 18 crystals of 3 x 3 x 6 cm{sup 3}. Four of these latter crystals are made with isotopically enriched materials: two in {sup 128}Te and two others in {sup 130}Te . With a sensitive mass of {approx}40 kg, our array is by far the most massive running cryogenic detector to search for rare events. The array is operated at a temperature of {approx}10 mK in a dilution refrigerator under a heavy shield in the Gran Sasso Underground Laboratory at a depth of about 3500 m.w.e. The counting rate in the region of neutrinoless double beta decay is {approx}0.2 counts keV{sup -1} kg{sup -1} year{sup -1}, among the lowest in this type of experiment. No evidence for neutrinoless double beta decay is found with the present statistics obtained in about three months with a live time of 72%. The corresponding lower limit for the lifetime of this process is of 5.5 x 10{sup 23} years at 90% C.L. The corresponding limit for the effective neutrino mass ranges between 0.37 to 1.9 eV depending on the theoretically calculated nuclear matrix elements used. This constraint is the most restrictive one except those obtained with Ge diodes, and is comparable to them.

  17. A Calorimetric Determination of the Half Life of Polonium-210 (Final Report)

    Energy Technology Data Exchange (ETDEWEB)

    Eichelberger, J. F.; Jordan, K. C.; Orr, S. R.; Parks, J. R.

    1953-02-10

    Six determinations have been made of the half life of polonium with four different steady-state, resistance-bridge calorimeters and five different samples of polonium. These six values of the half life have been weighted and combined to give a grand-mean value of the half life of 138.4005 + - 0.0051 days.

  18. Spectroscopic and calorimetric studies of interaction of methimazole with human serum albumin

    Energy Technology Data Exchange (ETDEWEB)

    Afrin, Sadaf [Department of Chemistry, Aligarh Muslim University, Aligarh 202002, Uttar Pradesh (India); Riyazuddeen, E-mail: rz1@rediffmail.com [Department of Chemistry, Aligarh Muslim University, Aligarh 202002, Uttar Pradesh (India); Rabbani, Gulam; Khan, Rizwan Hasan [Interdisciplinary Biotechnology Unit, Aligarh Muslim University, Aligarh 202002, Uttar Pradesh (India)

    2014-07-01

    The interaction of the anti-thyroid drug, 2-mercapto 1-methylimidazole (methimazole) with human serum albumin (HSA) has been examined by fluorescence and isothermal titration calorimetry (ITC) techniques. Fluorescence results indicate that in case of HSA–drug complex the quenching of fluorescence intensity is at 340 nm. The methimazole has an ability to quench the intrinsic fluorescence of HSA tryptophan through a static quenching procedure. The binding constant has been determined using Stern–Volmer modified equation and energy transfer mechanisms of quenching are discussed. The ΔG°, ΔH°, and ΔS° values are also calculated by ITC measurements. The experimental spectroscopic and thermodynamic parameters have been used for understanding the binding mechanism of anti-thyroid drug with HSA. - Highlights: • The binding of methimazole to HSA quenches the intrinsic fluorescence of tryptophan. • The negative ΔG° value suggests the binding of methimazole with HSA is spontaneous. • The main contribution to ΔG° arises from the ΔS° rather than from ΔH°, so hydrophobic forces most likely play a major role in the binding of methimazole to HSA.

  19. Calorimetric Evidence about the Application of the Concept of CMC to Asphaltene Self-Association

    DEFF Research Database (Denmark)

    Garcia, Daniel Merino; Andersen, Simon Ivar

    2005-01-01

    For many years, the concept of critical micellar concentration (CMC) has been projected from surfactant science into asphaltene science. There are several similarities between these two species, such as the stabilization of water-in-oil emulsions and surface activity, which suggested that asphalt......For many years, the concept of critical micellar concentration (CMC) has been projected from surfactant science into asphaltene science. There are several similarities between these two species, such as the stabilization of water-in-oil emulsions and surface activity, which suggested...... that asphaltenes may also have a concentration at which self-association occurs (CMC). This article presents evidence found by calorimetry and spectroscopic techniques, that suggest that this concept may not be adequate for asphaltene self-association in toluene solutions. Isothermal titration calorimetry has been...

  20. Calorimetric evidence for a mobile surface layer in ultrathin polymeric films: poly(2-vinyl pyridine).

    Science.gov (United States)

    Madkour, Sherif; Yin, Huajie; Füllbrandt, Marieke; Schönhals, Andreas

    2015-10-28

    Specific heat spectroscopy was used to study the dynamic glass transition of ultrathin poly(2-vinyl pyridine) films (thicknesses: 405-10 nm). The amplitude and the phase angle of the differential voltage were obtained as a measure of the complex heat capacity. In a traditional data analysis, the dynamic glass transition temperature Tg is estimated from the phase angle. These data showed no thickness dependency on Tg down to 22 nm (error of the measurement of ±3 K). A derivative-based method was established, evidencing a decrease in Tg with decreasing thickness up to 7 K, which can be explained by a surface layer. For ultrathin films, data showed broadening at the lower temperature side of the spectra, supporting the existence of a surface layer. Finally, temperature dependence of the heat capacity in the glassy and liquid states changes with film thickness, which can be considered as a confinement effect.

  1. Higher Order Inclusion Complexes and Secondary Interactions Studied by Global Analysis of Calorimetric Titrations

    DEFF Research Database (Denmark)

    Schönbeck, Jens Christian Sidney; Holm, René; Westh, Peter

    2012-01-01

    ). The results are validated by a 13C NMR titration and negative controls with a bile salt with no secondary binding site (glycocholate) (K = 2.96 ± 0.01 × 103 M–1). The method proved useful for detailed analysis of ITC data and may strengthen its use as a tool for studying molecular systems by advanced binding......This paper investigates the use of isothermal titration calorimetry (ITC) as a tool for studying molecular systems in which weaker secondary interactions are present in addition to a dominant primary interaction. Such systems are challenging since the signal pertaining to the stronger primary...... interaction tends to overshadow the signal from the secondary interaction. The methodology presented here enables a complete and precise thermodynamic characterization of both the primary and the weaker secondary interaction, exemplified by the binding of β-cyclodextrin to the primary and secondary binding...

  2. Calorimetric and Computational Study of Enthalpy of Formation of Diperoxide of Cyclohexanone

    Directory of Open Access Journals (Sweden)

    Alicia H. Jubert

    2007-07-01

    Full Text Available A thermochemical rather simple experimental technique is applied to determinethe enthalpy of formation of Diperoxide of ciclohexanone. The study is complemented withsuitable theoretical calculations at the semiempirical and ab initio levels. A particularsatisfactory agreement between both ways is found for the ab initio calculation at the 6-311G basis This set level. Some possible extensions of the present procedure are pointedout.

  3. Calorimetric analysis of heating and cooling process of nodular cast iron

    Directory of Open Access Journals (Sweden)

    Bińczyk F.

    2007-01-01

    Full Text Available The study presents the results of investigations of the thermal effects which take place during heating and cooling of samples of the nodular graphite cast iron taken from the stepped test casting of the wall thicknesses amounting to 5, 10, 15 and 20 mm. For investigations, a differential scanning calorimeter, type Multi HTC S60, was used. During heating, three endothermic effects related with pearlite decomposition, phase transformation α → γ, and carbon dissolution in austenite were observed on a DSC diagram. During cooling, two exothermic effects related with phase transformation γ→ α and pearlite formation were observed to consecutively take place on a DSC diagram. The values of the enthalpy of these processes differ and depend on the initial microstructure of the examined samples. The metallic matrix in 5 mm sample after the process of heating and cooling changes totally in favour of ferrite. The same effect, though less advanced in intensity, takes place in 10 mm sample, while in 15 and 20 mm samples the matrix constitution remains unchanged. The higher is the content of ferrite in samples, the stronger is the endothermic effect of the α → γ transformation and the weaker is the endothermic effect related with carbon dissolution in austenite. The total of the endothermic effects (heating is reduced, while that of the exothermic effects (cooling increases along with the increasing thickness of walls in a stepped test casting, from which samples for the investigations were taken.

  4. Multispectroscopic and calorimetric studies on the binding of the food colorant tartrazine with human hemoglobin.

    Science.gov (United States)

    Basu, Anirban; Suresh Kumar, Gopinatha

    2016-11-15

    Interaction of the food colorant tartrazine with human hemoglobin was studied using multispectroscopic and microcalorimetric techniques to gain insights into the binding mechanism and thereby the toxicity aspects. Hemoglobin spectrum showed hypochromic changes in the presence of tartrazine. Quenching of the fluorescence of hemoglobin occurred and the quenching mechanism was through a static mode as revealed from temperature dependent and time-resolved fluorescence studies. According to the FRET theory the distance between β-Trp37 of hemoglobin and bound tartrazine was evaluated to be 3.44nm. Synchronous fluorescence studies showed that tartrazine binding led to alteration of the microenvironment around the tryptophans more in comparison to tyrosines. 3D fluorescence and FTIR data provided evidence for conformational changes in the protein on binding. Circular dichroism studies revealed that the binding led to significant loss in the helicity of hemoglobin. The esterase activity assay further complemented the circular dichroism data. Microcalorimetric study using isothermal titration calorimetry revealed the binding to be exothermic and driven largely by positive entropic contribution. Dissection of the Gibbs energy change proposed the protein-dye complexation to be dominated by non-polyelectrolytic forces. Negative heat capacity change also corroborated the involvement of hydrophobic forces in the binding process.

  5. A Simple Calorimetric Experiment that Highlights Aspects of Global Heat Retention and Global Warming

    Science.gov (United States)

    Burley, Joel D.; Johnston, Harold S.

    2007-01-01

    In this laboratory experiment, general chemistry students measure the heating curves for three different systems: (i) 500 g of room-temperature water heated by a small desk lamp, (ii) 500 g of an ice-water mixture warmed by conduction with room-temperature surroundings, and (iii) 500 g of an ice-water mixture heated by a small desk lamp and by…

  6. Isothermal titration calorimetric analysis of the interaction between cationic lipids and plasmid DNA.

    Science.gov (United States)

    Lobo, B A; Davis, A; Koe, G; Smith, J G; Middaugh, C R

    2001-02-01

    The effects of buffer and ionic strength upon the enthalpy of binding between plasmid DNA and a variety of cationic lipids used to enhance cellular transfection were studied using isothermal titration calorimetry at 25.0 degrees C and pH 7.4. The cationic lipids DOTAP (1,2-dioleoyl-3-trimethyl ammonium propane), DDAB (dimethyl dioctadecyl ammonium bromide), DOTAP:cholesterol (1:1), and DDAB:cholesterol (1:1) bound endothermally to plasmid DNA with a negligible proton exchange with buffer. In contrast, DOTAP: DOPE (L-alpha-dioleoyl phosphatidyl ethanolamine) (1:1) and DDAB:DOPE (1:1) liposomes displayed a negative enthalpy and a significant uptake of protons upon binding to plasmid DNA at neutral pH. These findings are most easily explained by a change in the apparent pKa of the amino group of DOPE upon binding. Complexes formed by reverse addition methods (DNA into lipid) produced different thermograms, sizes, zeta potentials, and aggregation behavior, suggesting that structurally different complexes were formed in each titration direction. Titrations performed in both directions in the presence of increasing ionic strength revealed a progressive decrease in the heat of binding and an increase in the lipid to DNA charge ratio at which aggregation occurred. The unfavorable binding enthalpy for the cationic lipids alone and with cholesterol implies an entropy-driven interaction, while the negative enthalpies observed with DOPE-containing lipid mixtures suggest an additional contribution from changes in protonation of DOPE.

  7. Vibrational, calorimetric, and molecular conformational study on calcein interaction with model lipid membrane

    Science.gov (United States)

    Maherani, Behnoush; Arab-Tehrany, Elmira; Rogalska, Ewa; Korchowiec, Beata; Kheirolomoom, Azadeh; Linder, Michel

    2013-07-01

    Nanoliposomes are commonly used as a carrier in controlled release drug delivery systems. Controlled release formulations can be used to reduce the amount of drug necessary to cause the same therapeutic effect in patients. One of the most noticeable factors in release profiles is the strength of the drug-carrier interaction. To adjust the pharmacokinetic and pharmacodynamic properties of therapeutic agents, it is necessary to optimize the drug-carrier interaction. To get a better understanding of this interaction, large unilamellar liposomes containing calcein were prepared using 1,2-dioleoyl- sn-glycero-3-phosphocholine, 1-palmitoyl-2-oleoyl- sn-glycero-3-phosphocholine, and 1,2-palmitoyl- sn-glycero-3-phosphocholine, and a mixture of them; calcein was chosen as a model polar molecule of biological interest. The thermodynamic changes induced by calcein and its location in lipid bilayers were determined by differential scanning calorimetry and Raman spectroscopy, respectively. The results reveal that calcein has no significant influence on thermotropic properties of the lipid membrane, but causing the abolition of pre-transition. The decreasing of the pre-transition can be ascribed to the presence of calcein near the hydrophilic cooperative zone of the bilayer. The change in intensity of the Raman peaks represents the interaction of calcein with choline head groups. Moreover, the impact of calcein on phosphoglyceride Langmuir layers spread at the air-water interface was studied using surface pressure-area and surface potential-area isotherms, as well as polarization-modulation infrared reflection-absorption spectroscopy and Brewster angle microscopy. The results obtained indicate that calcein introduce no major modification on the systems prepared with pure lipids.

  8. Effect of high-pressure on calorimetric, rheological and dielectric properties of selected starch dispersions.

    Science.gov (United States)

    Ahmed, Jasim; Singh, Ajaypal; Ramaswamy, H S; Pandey, Pramod K; Raghavan, G S V

    2014-03-15

    Effects of high-pressure (HP) treatment on the rheological, thermal and dielectric properties of the four selected starch dispersions (two modified starches, one native and one resistant) were evaluated. Differential scanning calorimetry (DSC) and oscillatory rheometry were employed to assess the extent of starch gelatinization and the developed gel rigidity (G') of starch gels after HP treatment. It was observed that starch dispersions gelatinized completely at 500 MPa with a 30-min holding time. The HP-treated starch samples exhibited predominantly solid-like (G'>G") behavior except for the resistant starch. Pressure-induced gel rigidity differed significantly among starch samples. The G' of starch gels increased with the pressure (400-600 MPa) in the studied frequency range (0.1-10 Hz) except for the native starch where a marginal decrease was recorded at similar condition. The holding time (15-30 min) and concentration (20-25% w/w) significantly attributed towards gel rigidity of starch samples. Measurement of dielectric properties of HP-treated samples over the frequency range 450-4450 MHz indicated differences in the dielectric constant (ɛ'), loss factor (ɛ") and penetration depth among starch gels. Pressure did not show any effect on dielectric property of the resistant starch sample. Power penetration depth decreased significantly with frequency and with the pressure.

  9. Three Dimensional Thermal Modeling of Li-Ion Battery Pack Based on Multiphysics and Calorimetric Measurement

    DEFF Research Database (Denmark)

    Khan, Mohammad Rezwan; Kær, Søren Knudsen

    2016-01-01

    A three-dimensional multiphysics-based thermal model of a battery pack is presented. The model is intended to demonstrate the cooling mechanism inside the battery pack. Heat transfer (HT) and computational fluid dynamics (CFD) physics are coupled for both time-dependent and steady-state simulatio...

  10. Characteristic parameters analysis on diagnostic X-ray beams for dosemeter calibration; Analise de parametros caracteristicos de feixes de raios-X diagnostico para calibracao de dosimetros

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Paulo Marcio Campos de

    2008-07-01

    Ionizing radiation metrology is the base to achieve reliable dose measurements in ali areas; it is also part of the framework that is established to assure radiation protection procedures in order to avoid or minimize the harmful biological effect that may be caused by ionizing radiation. A well done metrology means the use of reliable instruments that comply with standard performance requirements worldwide accepted. Those instruments are expected to be calibrated by Metrology Laboratories under well defined conditions. The International Electrotechnical Commission (IEC) in Standard 61267 established the reference radiations for medical diagnostic x-ray equipment that are recommended to be used for calibrating dosimetric systems for diagnostic dosimetry. In this work, X-ray beam qualities were established in a Calibration Laboratory and their characteristics were analyzed through the measurement of beam parameters like inherent tube filtration, beam uniformity and field size, energy spectra and peak voltage for additional filtration with 94.425 por cent and 99.999 por cent purity filters. Also, the first half-value layer and the homogeneity coefficient were measured for the three RQR 2, RQR 6 and RQR 10 IEC beam qualities and they were analyzed according to the IEC standard. Air-kerma measurements were carried out with an ionization chamber that had its reliability confirmed through repetition and reproducibility reading tests. In 50 sets of measurements the maximum standard deviation found of 10 successive readings was 0.19 %; the maximum shift of the reading mean value at a fixed geometry condition was 0.80 % with an overall standard deviation of 0.23 %. Results showed that the use of different purity filters did not cause a relevant influence on the beam energy spectra. An ionization chamber was also calibrated against a standard dosimeter in ali implemented reference radiations and the relevant sources of uncertainties were estimated. Calibration could be done with an expanded uncertainty of 1.50% for a coverage factor of 2 at a 95.45 % confidence level, mainly due to the uncertainty of 0.58% caused by the positioning set-up of the ionization chamber. (author)

  11. Development and characterization of ultra-thin dosemeters of aluminium oxide; Desarrollo y caracterizacion de dosimetros ultra-delgados de oxido de aluminio

    Energy Technology Data Exchange (ETDEWEB)

    Villagran V, E

    2003-07-01

    The aim of the present thesis work has been to investigate the thermoluminescent (Tl) response of aluminium oxide thin films with thicknesses of the order of 300 nm prepared by laser ablation. Aluminium oxide thin films show Tl response after they are subject to ultraviolet, beta and gamma radiation. The Tl curves exhibit peaks around 75 C and 169 C for UV radiation, 112 C and 180 C for beta particles and 110 C and 176 C for gamma radiation. In order to improve the Tl response some growth parameters such as power density and distance target-substrate were varied. The relation dose-response shows a non-linear behavior for UV irradiation; a linear behavior for beta-particles dose from 150 mGy to 50 Gy, and a linear behavior for gamma radiation dose from 5 Gy to 100 Gy. The kinetic Tl parameters were determined by Computerized Glow Curve Deconvolution (CGCD) method as well as using analytical methods. The CGCD results show that the high temperature peak is composed by four peaks with maximums in 165.7, 188.1, 215.3, 246.5 C. These obey a second order kinetics. The trap depth (E) values are 1.4, 1.6, 1.8 and 2.0 eV respectively. The different analytical results show a trap depth values of 0.914, 0.82 and 0.656 eV respectively. Oxide aluminium thin films obtained would be a suitable tool owing to their potential applications in clinical dosimetry, in the dose distributions due to weekly penetrating radiation determination, and in interfaces dosimetry. (Author)

  12. Commercial sugar, an alternative dosemeter for the dose determination in radiological emergency conditions; Azucar comercial, un dosimetro alternativo para la determinacion de dosis en situaciones de emergencia radiologica

    Energy Technology Data Exchange (ETDEWEB)

    Urena N, F.; Galindo, S. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1997-07-01

    It was carried out the dosimetric evaluation of commercial sugar, with the purpose to determine the feasibility to be able to use this type of substance as a dosimetric material in cases to present some radiological emergency cases. The studied parameters using the Electron Paramagnetic Resonance (EPR) technique were: pre-doses signal or depth signal, dose-response stability, reproducibility, reliability and signal clearing decreasing. (Author)

  13. Standardization of calibration of clinic dosemeters using electric currents and charges; Padronizacao da calibracao de dosimetros clinicos utilizando cargas e correntes eletricas

    Energy Technology Data Exchange (ETDEWEB)

    Peres, Marcos Antonio de Lima

    1999-09-15

    Clinical dosimeters used in radiotherapy are calibrated in Latin American countries, including Brazil, as a complete 'system, i.e., ionization chamber and electrometer together. Some countries, as European ones, and USA calibrate them by component, i.e., ionisation chamber apart from electrometer. This method is more advantageous than the previous one, since it makes possible the automation of the calibration process, allowing the acquisition of data related to the chamber and the electrometer measurements independently, as well as the substitution of one of the components, in case of failure. This work proposes a method for standardisation of low intensity electric charge and currents in order to implement electric calibration of electrometers. This will make possible the implementation of a by components calibration technique, by components, of clinical dosimeters in Brazil. The results obtained with the calibration by components prove that the proposed method of standardisation of low electric charges and currents is viable. The difficulties found for the generation and measurement of low intensity electric charges and currents and the procedures adopted for the calibration by components are presented. Additionally, a current source was built to yield reference electric charges that will make possible the quality control clinical dosimeters. This source will also allow the user to identify the defective components of the dosimeters, through a simple verification test. (author)

  14. The development of new generation electronic personal dosimeters

    Energy Technology Data Exchange (ETDEWEB)

    Aoyama, Kei; Nagase, Yoshiyuki; Suzuki, T. [Fuji Electric Co., Ltd., Tokyo (Japan); Watanabe, Shinichi; Taniguchi, Kazufumi; Muramatsu, Kunihiro; Fujita, Mikio; Fujii, Yutaka [Japan Atomic Power Company, Tokyo (Japan)

    2000-05-01

    We have developed two types of new small, light, electronic personal dosemeters (EPDs) which can be used for dose management of workers at nuclear power plants without additional dosemeters. The one is a card size dosemeter to measure gamma exposure dose and the other is a multi sensor dosemeter to measure gamma, beta and neutron dose respectively. With direct reading, alarm and instant readout, these EPDs have ruggedness and if failure happens, memory readout facility can read dose data in the dosemeter. These dosemeters have enough performance characteristics and reliability for use as a dose record dosemeter. The gamma dosemeter has a lightweight credit card size body to reduce workers' burden of wearing it. The multi sensor dosemeter has four hetero junction silicon detectors that detect gamma, beta, thermal and fast neutron respectively and it is smaller and lighter than conventional alarm dosemeters presently used at nuclear power plant. Thermal neutron detector has thin Boron layer deposited on silicon surface and fast neutron detector has polyethylene radiator in front of silicon wafer. These dosemeters with a rechargeable battery can operate more than 15 hours continuously. The data transmission can be made with radiofrequency wave in area smaller than 30 cm distance between dosemeter and readout system. These dosemeters were introduced into Tokai nuclear power plant on October 1997, Tsuruga nuclear power plant on December 1997 of Japan Atomic Power Company and have been operating satisfactorily. At now these EPD have been used as secondary dosemeters. The performance characteristics comparison between EPD and film badge(FB) have been continuing to assure EPD suitable for use as a primary dosemeter. Near future Japco will abolish FB and establish the radiation control system based on the electronic personal dosemeters as a dose record dosemeter. (author)

  15. Calorimetric and Spectroscopic Analysis of the Thermal Stability of Short Duplex DNA-Containing Sugar and Base-Modified Nucleotides.

    Science.gov (United States)

    Fakhfakh, Kareem; Hughesman, Curtis B; Louise Creagh, A; Kao, Vincent; Haynes, Charles

    2016-01-01

    Base- and sugar-modified analogs of DNA and RNA are finding ever expanding use in medicine and biotechnology as tools to better tailor structured oligonucleotides by altering their thermal stability, nuclease resistance, base-pairing specificity, antisense activity, or cellular uptake. Proper deployment of these chemical modifications generally requires knowledge of how each affects base-pairing properties and thermal stabilities. Here, we describe in detail how differential scanning calorimetry and UV spectroscopy may be used to quantify the melting thermodynamics of short dsDNA containing chemically modified nucleosides in one or both strands. Insights are provided into why and how the presence of highly stable base pairs containing modified nucleosides can alter the nature of calorimetry or melting spectroscopy data, and how each experiment must therefore be conducted to ensure high-quality melting thermodynamics data are obtained. Strengths and weaknesses of the two methods when applied to chemically modified duplexes are also addressed.

  16. A calorimetric investigation for the bindings of mushroom tyrosinase to p-phenylene-bis dithiocarbamate and xanthates

    Directory of Open Access Journals (Sweden)

    Rezaei Behbehani Gholam Reza

    2013-01-01

    Full Text Available A comprehensive, simple and rapid thermodynamic study on the interaction of Mushroom Tyrosinase, MT, with three iso-alkyldithiocarbonates (xanthates, as sodium salts, C3H7OCS2Na (I, C4H9OCS2Na (II, C5H11OCS2Na (III and p-phenylene-bis dithiocarbamate (IV, by using isothermal titration calorimetry was carried out to clarify thermodynamics of these bindings as well as structural changes of the enzyme due to its interaction with inhibitors at 300K in phosphate buffer (10 m molL-1; pH 6.8.The extended solvation theory was used to elucidate the effect of the inhibitors on the stability of enzyme. The obtained results indicate that there are two identical and non-cooperative binding sites for these inhibitors.

  17. Calorimetric study on pH-responsive block copolymer grafted lipid bilayers: rational design and development of liposomes.

    Science.gov (United States)

    Pippa, Natassa; Chountoulesi, Maria; Kyrili, Aimilia; Meristoudi, Anastasia; Pispas, Stergios; Demetzos, Costas

    2016-09-01

    This study is focused on chimeric advanced drug delivery nanosystems and specifically on pH-sensitive liposomes, combining lipids and pH-responsive amphiphilic block copolymers. Chimeric liposomes composed of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) and two different forms of block copolymers, i.e. poly(n-butylacrylate)-b-poly(acrylic acid) (PnBA-b-PAA) at 70 and 85% content of PAA at six different molar ratios, each form respectively. PAA block exhibits pH-responsiveness, because of the regulative group of -COOH. -COOH is protonated under acidic pH (pKa ca. 4.2), while remains ionized under basic or neutral pH, leading to liposomes repulse and eventually stability. Lipid bilayers were prepared composed of DPPC and PnBA-b-PAA. Experiments were carried out using differential scanning calorimetry (DSC) in order to investigate their thermotropic properties. DSC indicated disappearance of pre-transition at all chimeric lipid bilayers and slight thermotropic changes of the main transition temperature. Chimeric liposomes have been prepared and their physicochemical characteristics have been explored by measuring the size, size distribution and ζ-potential, owned to the presence of pH-responsive polymer. At percentages containing medium to high amounts of the polymer, chimeric liposomes were found to retain their size during the stability studies. These results were well correlated with those indicated in the DSC measurements of lipid bilayers incorporating polymers in order to explain their physicochemical behavior. The incorporation of the appropriate amount of these novel pH-responsive block copolymers affects thus the cooperativity, the liposomal stabilization and imparts pH-responsiveness.

  18. Standard method for continuous measurement of nitric oxide, nitrogen dioxide, and ozone in the atmosphere. [Calorimetrically using Griess Reagent

    Energy Technology Data Exchange (ETDEWEB)

    1975-01-01

    Nitrogen dioxide is absorbed from the atmosphere in a modified Griess reagent which contains 0.5 percent sulfanilic acid and 50 ppM of N-(1-naphthyl)-ethylene diamine hydrochloride in 5 percent acetic acid that produces a red dye. The red dye is measured continuously in a recording colorimeter by comparison with a blank of unreacted reagent. Nitric oxide from the atmosphere passes through the absorber practically unaffected and is oxidized to nitrogen dioxide by bubbling through a dilute permanganate solution prior to determination with modified Griess reagent in a separate cell. Optionally, ozone in the air sample may be determined in a third absorber-colorimeter cell unit by adding about 0.5 to 1.0 ppM of pure nitric oxide to another sample of air and noting the increase in nitrogen dioxide level due to the rapid oxidation of nitric oxide to nitrogen dioxide by ozone. The overall accuracy of the results of the method is +-10 percent. (BLM)

  19. Kinetics of the epoxy–thiol click reaction initiated by a tertiary amine: Calorimetric study using monofunctional components

    Energy Technology Data Exchange (ETDEWEB)

    Loureiro, Roi Meizoso; Amarelo, Tánia Carballeira [Gairesa, Outeiro 1, Lago (Valdoviño), 15551 A Coruña (Spain); Abuin, Senen Paz, E-mail: senen@gairesa.com [Gairesa, Outeiro 1, Lago (Valdoviño), 15551 A Coruña (Spain); Soulé, Ezequiel R. [Institute of Materials Science and Technology (INTEMA), University of Mar del Plata and National Research Council (CONICET), J. B. Justo 4302, 7600 Mar del Plata (Argentina); Williams, Roberto J.J., E-mail: williams@fi.mdp.edu.ar [Institute of Materials Science and Technology (INTEMA), University of Mar del Plata and National Research Council (CONICET), J. B. Justo 4302, 7600 Mar del Plata (Argentina)

    2015-09-20

    Graphical abstract: - Highlights: • Reaction kinetics of a monoepoxy and a monothiol was studied by DSC. • Benzyldimethylamine (BDMA) was used as initiator. • Reaction exhibited a long induction period followed by a fast autocatalytic rate. • A mechanistic kinetic model provided a reasonable fitting of the kinetic behavior. • The formulation simulates the behavior of room-temperature-cure commercial epoxies. - Abstract: An analysis of the kinetics of the epoxy–thiol reaction in a model stoichiometric system of monofunctional reagents, 3-mercaptopropionate (BMP) and phenylglycidylether (PGE) is reported. Benzyldimethylamine (BDMA) was employed as initiator in amounts ranging from 0.5 to 2 wt%. These formulations showed a kinetic behavior qualitatively similar to that of commercial adhesives and coatings formulated for a room-temperature cure. Isothermal DSC scans revealed the existence of a relatively long induction period preceding a fast autocatalytic reaction step. Dynamic DSC scans showed that the reaction was shifted to a lower temperature range by increasing the storage period of the initial formulation at 20 °C. This unusual kinetic behavior could be modeled assuming that thiolate anions, slowly generated during the induction period, initiated a fast autocatalytic propagation/proton transfer reaction. The kinetic model included a pseudo-steady state for the initiator concentration and an equilibrium reaction between epoxy and OH groups generated by reaction. A reasonable fitting of isothermal and dynamic DSC runs was achieved in a broad range of temperatures and amine concentrations. In particular, both the length of the induction time and the effect of the storage period were correctly predicted.

  20. Effects of organic solvents on the enzyme activity of Trypanosoma cruzi glyceraldehyde-3-phosphate dehydrogenase in calorimetric assays

    DEFF Research Database (Denmark)

    Wiggers, Henrik; Cheleski, J; Zottis, A

    2007-01-01

    is sixfold higher. The favorable effects of the organic solvents on the Michaelis-Menten enzyme-substrate complex formation ensure the consistency of the biological assays, structural integrity of the protein, and reproducibility over the measurement time. The reaction was also kinetically monitored......In drug discovery programs, dimethyl sulfoxide (DMSO) is a standard solvent widely used in biochemical assays. Despite the extensive use and study of enzymes in the presence of organic solvents, for some enzymes the effect of organic solvent is unknown. Macromolecular targets may be affected...... by the presence of different solvents in such a way that conformational changes perturb their active site structure accompanied by dramatic variations in activity when performing biochemical screenings. To address this issue, in this work we studied the effects of two organic solvents, DMSO and methanol (Me...

  1. Combined Spectroscopic and Calorimetric Studies to Reveal Absorption Mechanisms and Conformational Changes of Protein on Nanoporous Biomaterials

    Directory of Open Access Journals (Sweden)

    Saharnaz Ahmadi

    2015-07-01

    Full Text Available In this study the effect of surface modification of mesoporous silica nanoparticles (MSNs on its adsorption capacities and protein stability after immobilization of beta-lactoglobulin B (BLG-B was investigated. For this purpose, non-functionalized (KIT-6 and aminopropyl-functionalized cubic Ia3d mesoporous silica ([n-PrNH2-KIT-6] nanoparticles were used as nanoporous supports. Aminopropyl-functionalized mesoporous nanoparticles exhibited more potential candidates for BLG-B adsorption and minimum BLG leaching than non-functionalized nanoparticles. It was observed that the amount of adsorbed BLG is dependent on the initial BLG concentration for both KIT-6 and [n-PrNH2-KIT-6] mesoporous nanoparticles. Also larger amounts of BLG-B on KIT-6 was immobilized upon raising the temperature of the medium from 4 to 55 °C while such increase was undetectable in the case of immobilization of BLG-B on the [n-PrNH2-KIT-6]. At temperatures above 55 °C the amounts of adsorbed BLG on both studied nanomaterials decreased significantly. By Differential scanning calorimetry or DSC analysis the heterogeneity of the protein solution and increase in Tm may indicate that immobilization of BLG-B onto the modified KIT-6 results in higher thermal stability compared to unmodified one. The obtained results provide several crucial factors in determining the mechanism(s of protein adsorption and stability on the nanostructured solid supports and the development of engineered nano-biomaterials for controlled drug-delivery systems and biomimetic interfaces for the immobilization of living cells.

  2. Calorimetry is not color-blind.Molecular insights on association processes in surfactant-polymer mixtures derived from calorimetric experiments

    Institute of Scientific and Technical Information of China (English)

    LOH Watson; BRINATTI Cesar

    2012-01-01

    This comment will review and discuss recent results obtained with the use of calorimetry in assessing molecular information from complex phenomena such as association in surfactant/polymer mixtures.These examples were selected to support the view that it is possible to ally the great sensitivity of modern calorimeters with carefully planned experiments and,sometimes,ancillary techniques in order to derive detailed information on molecular interactions.

  3. Isothermal Calorimetric Observations of the Effect of Welding on Compatibility of Stainless Steels with High-Test Hydrogen Peroxide Propellant

    Science.gov (United States)

    Gostowski, Rudy

    2003-01-01

    High-Test Hydrogen Peroxide (HTP) is receiving renewed interest as a monopropellant and as the oxidizer for bipropellant systems. HTP is hydrogen peroxide having concentrations ranging from 70 to 98%. In these applications the energy and oxygen released during decomposition of HTP is used for propulsion. In propulsion systems components must be fabricated and connected using available joining processes. Welding is a common joining method for metallic components. The goal of this study was to compare the HTP compatibility of welded vs. unwelded stainless steel.

  4. Calorimetric and magnetic study for Ni50Mn36In14 and relative cooling power in paramagnetic inverse magnetocaloric systems

    Science.gov (United States)

    Chen, Jing-Han; Bruno, Nickolaus M.; Karaman, Ibrahim; Huang, Yujin; Li, Jianguo; Ross, Joseph H.

    2014-11-01

    The non-stoichiometric Heusler alloy Ni50Mn36In14 undergoes a martensitic phase transformation in the vicinity of 345 K, with the high temperature austenite phase exhibiting paramagnetic rather than ferromagnetic behavior, as shown in similar alloys with lower-temperature transformations. Suitably prepared samples are shown to exhibit a sharp transformation, a relatively small thermal hysteresis, and a large field-induced entropy change. We analyzed the magnetocaloric behavior both through magnetization and direct field-dependent calorimetry measurements. For measurements passing through the first-order transformation, an improved method for heat-pulse relaxation calorimetry was designed. The results provide a firm basis for the analytic evaluation of field-induced entropy changes in related materials. An analysis of the relative cooling power (RCP), based on the integrated field-induced entropy change and magnetizing behavior of the Mn spin system with ferromagnetic correlations, shows that a significant RCP may be obtained in these materials by tuning the magnetic and structural transformation temperatures through minor compositional changes or local order changes.

  5. Thermodynamic properties for polycyclic systems by non-calorimetric methods. Progress report, August 1, 1992--September 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Steele, W.V.; Chirico, R.D.; Klots, T.D.

    1993-03-01

    A detailed vibrational spectroscopic study of furan, pyrrole, and thiophene has been completed. These compounds form part of the base of five-membered ring systems on which the rest of the research program will be built Several methyl-substituted derivatives were also studied. The results will be used to confirm the model for alkyl- substitution in the ring systems. Gas-phase spectra and fundamental- frequency assignments were completed for 2,3- and 2,5-dihydrofuran. Those compounds initiate work on ring-puckering within the research program. A paper describing the need for third virial estimation, when using the virial equation of state to derive thermodynamic properties at pressures greater than 1 bar was completed.

  6. Isothermal titration calorimetric and computational studies on the binding of chitooligosaccharides to pumpkin (Cucurbita maxima) phloem exudate lectin.

    Science.gov (United States)

    Narahari, Akkaladevi; Singla, Hitesh; Nareddy, Pavan Kumar; Bulusu, Gopalakrishnan; Surolia, Avadhesha; Swamy, Musti J

    2011-04-14

    The interaction of chitooligosaccharides [(GlcNAc)(2-6)] with pumpkin phloem exudate lectin (PPL) was investigated by isothermal titration calorimetry and computational methods. The dimeric PPL binds to (GlcNAc)(3-5) with binding constants of 1.26-1.53 × 10(5) M(-1) at 25 °C, whereas chitobiose exhibits approximately 66-fold lower affinity. Interestingly, chitohexaose shows nearly 40-fold higher affinity than chitopentaose with a binding constant of 6.16 × 10(6) M(-1). The binding stoichiometry decreases with an increase in the oligosaccharide size from 2.26 for chitobiose to 1.08 for chitohexaose. The binding reaction was essentially enthalpy driven with negative entropic contribution, suggesting that hydrogen bonds and van der Waals' interactions are the main factors that stabilize PPL-saccharide association. The three-dimensional structure of PPL was predicted by homology modeling, and binding of chitooligosaccharides was investigated by molecular docking and molecular dynamics simulations, which showed that the protein binding pocket can accommodate up to three GlcNAc residues, whereas additional residues in chitotetraose and chitopentaose did not exhibit any interactions with the binding pocket. Docking studies with chitohexaose indicated that the two triose units of the molecule could interact with different protein binding sites, suggesting formation of higher order complexes by the higher oligomers of GlcNAc by their simultaneous interaction with two protein molecules.

  7. Crystalline anhydrous {alpha},{alpha}-trehalose (polymorph {beta}) and crystalline dihydrate {alpha},{alpha}-trehalose: A calorimetric study

    Energy Technology Data Exchange (ETDEWEB)

    Pinto, Susana S. [Centro de Quimica Estrutural, Complexo Interdisciplinar, Instituto Superior Tecnico, 1049-001 Lisbon (Portugal)]. E-mail: susanapinto@ist.utl.pt; Diogo, Herminio P. [Centro de Quimica Estrutural, Complexo Interdisciplinar, Instituto Superior Tecnico, 1049-001 Lisbon (Portugal)]. E-mail: hdiogo@ist.utl.pt; Moura-Ramos, Joaquim J. [Centro de Quimica-Fisica Molecular, Complexo Interdisciplinar, Instituto Superior Tecnico, 1049-001 Lisbon (Portugal)]. E-mail: mouraramos@ist.utl.pt

    2006-09-15

    The mean values of the standard massic energy of combustion of crystalline anhydrous {alpha},{alpha}-trehalose (C{sub 12}H{sub 22}O{sub 11}, polymorph {beta}) and crystalline dihydrate {alpha},{alpha}-trehalose (C{sub 12}H{sub 26}O{sub 13}) measured by static-bomb combustion calorimetry in oxygen, at the temperature T=298.15K, are {delta}{sub c}u{sup o}=-(16434.05+/-4.50)J.g{sup -1} and {delta}{sub c}u{sup o}=-(14816.05+/-3.52)J.g{sup -1}, respectively. The standard (p{sup o}=0.1MPa) molar enthalpy of formation of these compounds were derived from the corresponding standard molar enthalpies of combustion, respectively, {delta}{sub f}H{sub m}{sup o} (C{sub 12}H{sub 22}O{sub 11},cr)=-(2240.9+/-3.9)kJ.mol{sup -1}, and {delta}{sub f}H{sub m}{sup o} (C{sub 12}H{sub 26}O{sub 13},cr)=-(2832.6+/-3.6)kJ.mol{sup -1}. The values of the standard enthalpies of formation obtained in this work, together with data on enthalpies of solution at infinite dilution ({delta}{sub sol}H{sup {approx}}) for crystalline dihydrate and amorphous anhydrous trehalose, allow a better insight on the thermodynamic description of the trehalose system which can provide, together with the future research on the subject, a contribution for understanding the metabolism in several organisms, as well as the phase transition between the different polymorphs.

  8. A calorimetric study of energy conversion efficiency of a sonochemical reactor at 500 kHz for organic solvents.

    Science.gov (United States)

    Toma, Maricela; Fukutomi, Satoshi; Asakura, Yoshiyuki; Koda, Shinobu

    2011-01-01

    It would seem that the economic viability is yet to be established for a great number of sonochemical processes, owning to their perfectible ultrasonic equipments. Industrial scale sonoreactors may become more important as a result of mastering the parameters with influence on their energy balance. This work related the solvent type to the energy efficiency as the first step of a complex study aiming to assess the energy balance of sonochemical reactors at 500 kHz. Quantitative measurements of ultrasonic power for water and 10 pure organic solvents were performed by calorimetry for a cylindrically shaped sonochemical reactor with a bottom mounted vibrating plate. It was found that the ultrasonic power is strongly related to the solvent, the energy conversion for organic liquids is half from that of water and there is a drop in energy efficiency for filling levels up to 250 mm organic solvents. Surface tension, viscosity and vapor pressure influence the energy conversion for organic solvents, but it is difficult explain these findings based on physical properties of solvents alone. The apparent intensity of the atomization process shows a good agreement with the experimentally determined values for energy conversion for water and the solvent group studied here. This study revealed that to attain the same ultrasonic power level, more electrical energy is need for organic solvents as compared to water. The energy balance equation has been defined based on these findings by considering an energy term for atomization.

  9. Spectrophotometric and Calorimetric Studies of Np(V) Complexation with Sulfate at 10-70oC

    Energy Technology Data Exchange (ETDEWEB)

    Rao, Linfeng; Tian, Guoxin; Xia, Yuanxian; Friese, Judah I.

    2008-06-16

    Sulfate, one of the inorganic constituents in the groundwater of nuclear waste repository, could affect the migration of radioactive materials by forming complexes. Spectrophotometric and microcalorimetric titrations were performed to identify the Np(V)/sulfate complex and determine the equilibrium constants and enthalpy of complexation at 10-70 C. Results show that the complexation of Np(V) with sulfate is weak but slightly enhanced by the increase in temperature. The complexation is endothermic and becomes more endothermic with the increase in temperature. The enhanced complexation at elevated temperatures is due to the increasingly larger entropy of complexation that exceeds the increase in enthalpy, suggesting that the complexation of Np(V) with sulfate is entropy-driven.

  10. Spectrophotometric and Calorimetric Studies of U(VI) Complexation with Sulfate at 25-70oC

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Guoxin; Rao, Linfeng

    2008-10-30

    Sulfate, one of the inorganic constituents in the groundwater of nuclear waste repository, could affect the migration of radioactive materials by forming complexes. Spectrophotometric and microcalorimetric titrations were performed to identify the U(VI)/sulfate complexes and determine the equilibrium constants and enthalpy of complexation at 25-70 C. Results show that U(VI) forms moderately strong complexes with sulfate, i.e., UO{sub 2}SO{sub 4}(aq) and UO{sub 2}(SO{sub 4}){sub 2}{sup 2-}, in this temperature range and the complexes become stronger as the temperature is increased: 2-fold and 10-fold increases in the stability constants of UO{sub 2}SO{sub 4}(aq) and UO{sub 2}(SO{sub 4}{sub 2}{sup 2-}), respectively, when the temperature is increased from 25 C to 70 C. The complexation is endothermic and entropy-driven, showing typical characteristics of inner-sphere complexation and 'hard acid'/'hard base' interactions. The thermodynamic trends are discussed in terms of dehydration of both the cation (UO{sub 2}{sup 2+}) and the anion (SO{sub 4}{sup 2-}) as well as the effect of temperature on the structure of water.

  11. Spectrophotometric and Calorimetric Studies of Np(V) Complexation with Acetate at Variable Temperatures (T = 283 - 343 K)

    Energy Technology Data Exchange (ETDEWEB)

    Rao, Linfeng; Tian, Guoxin; Srinivasan, Thandankorai G.; Zanonato, PierLuigi; Di Bernardo, Plinio

    2009-12-21

    Spectrophotometric titrations were performed to identify the Np(V)/acetate complex and determine the equilibrium constants at variable temperatures (T = 283 - 343 K) and at the ionic strength of 1.05 mol {center_dot} kg{sup -1}. The enthalpy of complexation at corresponding temperatures was determined by microcalorimetric titrations. Results show that the complexation of Np(V) with acetate is weak but strengthened as the temperature is increased. The complexation is endothermic and is entropy-driven. The enhancement of the complexation at elevated temperatures is primarily due to the increasingly larger entropy gain when the solvent molecules are released from the highly-ordered solvation spheres of NpO{sub 2}{sup +} and acetate to the bulk solvent where the degree of disorder is higher at higher temperatures.

  12. A method for calorimetric analysis in variable conditions heating; Methode d'analyse calorimetrique en regime variable

    Energy Technology Data Exchange (ETDEWEB)

    Berthier, G. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    By the analysis of the thermal transition conditions given by the quenching of a sample in a furnace maintained at a high temperature, it is possible to study the thermal diffusivity of some materials and those of solid state structure transformation on a qualitative as well as a quantitative standpoint. For instance the transformation energy of {alpha}-quartz into {beta}-quartz and the Wigner energy stored within neutron-irradiated beryllium oxide have been measured. (author) [French] L'analyse du regime thermique transitoire, obtenu par la trempe d'un echantillon dans l'enceinte d'un four maintenu a tres haute temperature, peut permettre l'etude de la diffusivite thermique de certains materiaux et celle des transformations structurales en phase solide, tant du point de vue qualitatif que du point de vue quantitatif (mesure de l'energie de transformation du quartz {alpha} en quartz {beta} et determination de l'energie Wigner emmagasinee par l'oxyde de beryllium irradie aux neutrons). (auteur)

  13. Application of a simple calorimetric data analysis on the binding study of cyanide ions by Jack bean urease

    Institute of Scientific and Technical Information of China (English)

    G.Rezaei; Behbehani; A.A.Saboury; M.Mohebbian; S.Ghammamy

    2010-01-01

    Cyanide ion was studied as an effector of Jack bean urease(JBU) at 300 K in 30 mmol/LTris buffer,pH 7 by isothermal titration calorimetry(ITC).The simple novel model was used for CN~- + JBU interaction over the whole range of CN~- concentrations.The binding parameters recovered from the simple novel model were attributed to the cyanide ion interaction.It was found that cyanide ion acted as a noncooperative inhibitor of JBU,and there is a set of 12 identical and independent binding sites for CN~- ions.The...

  14. Quench-induced precipitates in Al–Si alloys: Calorimetric determination of solute content and characterisation of microstructure

    Energy Technology Data Exchange (ETDEWEB)

    Schumacher, Philipp, E-mail: philipp.schumacher@uni-rostock.de [University of Rostock, Faculty of Mechanical Engineering and Marine Technology, Chair of Materials Science, Albert-Einstein-Str. 2, 18051 Rostock (Germany); University of Rostock, Institute of Physics, Polymer Physics Group, Wismarsche Str. 43-45, 18051 Rostock (Germany); Pogatscher, Stefan, E-mail: stefan.pogatscher@mat.ethz.ch [ETH Zurich, Department of Materials, Laboratory of Metal Physics and Technology, Vladimir-Prelog-Weg 4, 8093 Zurich (Switzerland); Starink, Marco J., E-mail: m.j.starink@soton.ac.uk [University of Southampton, Engineering and the Environment, Highfield, SO17 1BJ Southampton (United Kingdom); Schick, Christoph, E-mail: christoph.schick@uni-rostock.de [University of Rostock, Institute of Physics, Polymer Physics Group, Wismarsche Str. 43-45, 18051 Rostock (Germany); Mohles, Volker, E-mail: mohles@imm.rwth-aachen.de [RWTH Aachen University, Institute of Physical Metallurgy and Metal Physics, Kopernikusstr. 14, 52056 Aachen (Germany); Milkereit, Benjamin, E-mail: benjamin.milkereit@uni-rostock.de [University of Rostock, Faculty of Mechanical Engineering and Marine Technology, Chair of Materials Science, Albert-Einstein-Str. 2, 18051 Rostock (Germany); University of Rostock, Institute of Physics, Polymer Physics Group, Wismarsche Str. 43-45, 18051 Rostock (Germany); University of Southampton, Engineering and the Environment, Highfield, SO17 1BJ Southampton (United Kingdom)

    2015-02-20

    Highlights: • A new DSC method gives access to the entire cooling rate range of physical interest. • Two precipitation reactions were identified during cooling of pure binary Al–Si. • A physical model for solute and precipitation fraction is presented and validated. • The model allows to control phase transformations by heat treatments. • This enables to produce and mechanically test targeted microstructures. - Abstract: The present study introduces an experimental approach to investigate mechanical properties of well-defined non-equilibrium states of Al–Si alloys during cooling from solution annealing. The precipitation behaviour of binary Al–Si alloys during the cooling process has been investigated in a wide cooling rate range (2–0.0001 K/s) with differential scanning calorimetry (DSC). To access the low cooling rate range close to equilibrium an indirect DSC measurement method is introduced. Based on the enthalpy change measured by DSC a physically-based model for the calculation of remaining solute Si amount as function of temperature and cooling rate is presented. Microstructural analyses via light optical microscopy, scanning electron microscopy, atom probe tomography and X-ray diffraction have been performed to evaluate the introduced model and for information on cooling rate dependent precipitate formation. It was found that quench-induced particles of different morphology are formed during cooling. Thermomechanical analyses on clearly distinct undercooled Al–Si states show that flow stress during cooling is dependent on temperature as well as cooling rate. The mechanical behaviour is therefore influenced by solute Si content and quench-induced precipitates.

  15. Heat capacities of polycrystalline {sup n}LiH and {sup n}LiD by differential scanning calorimetric method

    Energy Technology Data Exchange (ETDEWEB)

    Jat, Ram Avtar [Product Development Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Parida, S.C., E-mail: sureshp@barc.gov.i [Product Development Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Krishnan, K. [Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Anand, N.S.; Sawant, S.G.; Agarwal, Renu; Singh, Ziley [Product Development Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Aggarwal, S.K. [Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Venugopal, V. [RC and I Group, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India)

    2010-08-27

    The heat capacities of polycrystalline {sup n}LiH and {sup n}LiD were measured by differential scanning calorimeter in the temperature range from 125 to 800 K. The smoothed values of heat capacities were used to calculate various thermodynamic functions for {sup n}LiH and {sup n}LiD from 0 to 800 K. Isotopic effect on heat capacity of {sup n}LiH and {sup n}LiD is predominant at higher temperatures (>80 K) whereas below 80 K the isotopic effect is negligible.

  16. Calorimetric study of the thermal induced transformations of ultrafine silicon carbide powder produced by RF glow discharge

    Energy Technology Data Exchange (ETDEWEB)

    Costa, J.; Sunol, J.J.; Saurina, J.; Roura, P. [Girona Univ. (Spain). Dept. d`Enginyeria Industrial; Viera, G.; Bertran, E. [Dept. de Fisica Aplicada i Electronica, Facultat de Fisica, Univ. de Barcelona (Spain); Martinez, S. [Dept. de cristallografia mineral i diposits minerals, Univ. de Barcelona (Spain)

    1997-12-31

    Nanometric powder of silicon carbide has been produced by plasma-enhanced chemical vapor deposition (PECVD) in a radiofrequency discharge of silane and methane gas mixtures. The as deposited powders consists of amorphous particles which are highly hydrogenated. We will show in this communication, that the powder structure can be improved by thermal annealing at high temperatures. The structural changes have been analyzed by several techniques such as thermal desorption of hydrogen (TDSH), differential scaning calorimetry (DSC), infrared spectroscopy (IR) and transmission electron microscopy (TEM). The kinetic parameters of processes such as Si-H and C-H bond breaking have been determined. After annealing, the particles are crystalline, hydrogen free and do not suffer room temperature oxidation. (orig.) 8 refs.

  17. Calorimetric measurements on Li{sub 4}C{sub 60} and Na{sub 4}C{sub 60}

    Energy Technology Data Exchange (ETDEWEB)

    Inaba, Akira; Miyazaki, Yuji [Research Center for Structural Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Michałowski, Paweł P.; Gracia-Espino, Eduardo; Wågberg, Thomas, E-mail: Thomas.wagberg@physics.umu.se [Department of Physics, Umeå University, S-90187 Umeå (Sweden); Sundqvist, Bertil [Department of Physics, Umeå University, S-90187 Umeå (Sweden); State Key Laboratory for Superhard Materials, Jilin University, Changchun 130012 (China)

    2015-04-28

    We show specific heat data for Na{sub 4}C{sub 60} and Li{sub 4}C{sub 60} in the range 0.4-350 K for samples characterized by Raman spectroscopy and X-ray diffraction. At high temperatures, the two different polymer structures have very similar specific heats both in absolute values and in general trend. The specific heat data are compared with data for undoped polymeric and pristine C{sub 60}. At high temperatures, a difference in specific heat between the intercalated and undoped C{sub 60} polymers of 100 J K{sup −1} mol{sup −1} is observed, in agreement with the Dulong-Petit law. At low temperatures, the specific heat data for Li{sub 4}C{sub 60} and Na{sub 4}C{sub 60} are modified by the stiffening of vibrational and librational molecular motion induced by the polymer bonds. The covalent twin bonds in Li{sub 4}C{sub 60} affect these motions to a somewhat higher degree than the single intermolecular bonds in Na{sub 4}C{sub 60}. Below 1 K, the specific heats of both materials become linear in temperature, as expected from the effective dimensionality of the structure. The contribution to the total specific heat from the inserted metal ions can be well described by Einstein functions with T{sub E} = 386 K for Li{sub 4}C{sub 60} and T{sub E} = 120 K for Na{sub 4}C{sub 60}, but for both materials we also observe a Schottky-type contribution corresponding to a first approximation to a two-level system with ΔE = 9.3 meV for Li{sub 4}C{sub 60} and 3.1 meV for Na{sub 4}C{sub 60}, probably associated with jumps between closely spaced energy levels inside “octahedral-type” ionic sites. Static magnetic fields up to 9 T had very small effects on the specific heat below 10 K.

  18. Study on the interactional behaviour of transition metal ions with myoglobin: A detailed calorimetric, spectroscopic and light scattering analysis

    Science.gov (United States)

    Kaur, Amandeep; Banipal, Parampaul K.; Banipal, Tarlok S.

    2017-03-01

    The energetics and the impact on the conformation of heme containing protein myoglobin (Mb) due to the binding of three transition metal ions (Zn2 +, Ni2 +, and Mn2 +) have been investigated using isothermal titration calorimetry (ITC), dynamic light scattering (DLS), UV-vis, and circular dichroism (CD) spectroscopy under physiological conditions. The binding affinity of the order of 104 M- 1 has been observed for all metal ions from calorimetry as well as from absorption spectroscopy. The binding of these metal ions with Mb is a spontaneous process that exposes the hydrophobic groups away from the protein core as exhibited by the negative Gibbs free energy change (ΔG) and positive heat capacity change (ΔCp) values. Both light scattering and CD results demonstrates that the binding of Zn2 + and Mn2 + ions with Mb results in the folding whereas Ni2 + ion results in the unfolding of the protein. No direct interactions among the transition metal ions and heme moiety of Mb has been observed from absorption study. The results of these studies reveals that Mn2 + ion influences the biological functions of Mb to a larger extent in spite of its lowest affinity followed by Zn2 + and Ni2 + ions.

  19. Microstructure and calorimetric behavior of laser welded open cell foams in CuZnAl shape memory alloy

    Science.gov (United States)

    Biffi, Carlo Alberto; Previtali, Barbara; Tuissi, Ausonio

    Cellular shape memory alloys (SMAs) are very promising smart materials able to combine functional properties of the material with lightness, stiffness, and damping capacity of the cellular structure. Their processing with low modification of the material properties remains an open question. In this work, the laser weldability of CuZnAl SMA in the form of open cell foams was studied. The cellular structure was proved to be successfully welded in lap joint configuration by using a thin plate of the same alloy. Softening was seen in the welded bead in all the investigated ranges of process speed as well as a double stage heat affected zone was identified due to different microstructures; the martensitic transformation was shifted to higher temperatures and the corresponding peaks were sharper with respect to the base material due to the rapid solidification of the material. Anyways, no compositional variations were detected in the joints.

  20. Calorimetric comparison of the interactions between salivary proteins and Streptococcus mutans with and without antigen I/II

    NARCIS (Netherlands)

    Xu, C.P.; Belt-Gritter, van de B.; Busscher, H.J.; Mei, van der H.C.; Norde, W.

    2007-01-01

    Antigen I/II can be found on streptococcal cell surfaces and is involved in their interaction with salivary proteins. In this paper, we determine the adsorption enthalpies of salivary proteins to Streptococcus mutans LT11 and S. mutans IB03987 with and without antigen I/II, respectively, using isoth

  1. Calorimetric comparison of the interactions between salivary proteins and Streptococcus mutans with and without antigen I/II

    NARCIS (Netherlands)

    Xu, Chun-Ping; Belt-Gritter, van de Betsy; Busscher, Henk J.; van der Mei, Henny C.; Norde, Willem

    2007-01-01

    Antigen I/II can be found on streptococcal cell surfaces and is involved in their interaction with salivary proteins. In this paper, we determine the adsorption enthalpies of salivary proteins to Streptococcus mutans LT 11 and S. mutans IB03987 with and without antigen I/II, respectively, using isot

  2. Partial-body dosimetry for photons and beta radiation; Teilkoerperdosimetrie fuer Photonen und Betastrahlung

    Energy Technology Data Exchange (ETDEWEB)

    Behrens, Rolf [Physikalisch-Technische Bundesanstalt (PTB), Braunschweig (Germany). Arbeitsgruppe ' Betadosimetrie'

    2013-06-15

    After a description of typical application positions of partial-body dosimetry in medicine the technical details of such dosemeters mostly based on thermoluminescence detectors are described. then especially eye and finger-ring dosemeters are described more detailedly. Finally different applied dosemeter types are considered. (HSI)

  3. Measurements of radon in dwellings with CR-39 track detectors

    DEFF Research Database (Denmark)

    Majborn, Benny

    1986-01-01

    A passive integrating dosemeter has been designed for measuring natural radiation in dwellings. The dosemeter contains one or two CR-39 track detectors to measure radon and three thermoluminescence dosemeters to measure external radiation. The dosemeter was investigated in a pilot study in 1983....../84, and it is now used in a nationwide survey of natural radiation in Danish dwellings. The characteristics of the dosemeter with respect to radon measurements are presented, and the radon monitoring results obtained in the pilot study are summarized...

  4. Calorimetric studies of 7000 series aluminum alloys. I - Matrix precipitate characterization of 7075. II - Comparison of 7075, 7050, and RX720 alloys

    Science.gov (United States)

    Deiasi, R.; Adler, P. N.

    1977-01-01

    Correlation between differential scanning calorimetry and high temperature transmission electron microscopy for the characterization of preexisting matrix precipitates in the highest-strength and overaged tempers of 7075 aluminum was demonstrated. The solid state reactions undergone by these tempers in the 20-500 C temperature range were elucidated and expressed in terms of thermodynamic and kinetic parameters. The dissolution parameters for each phase are distinguishable and serve as guidelines for a rapid characterization of the matrix microstructure of these alloys.

  5. Differential modulation in binding of ketoprofen to bovine serum albumin in the presence and absence of surfactants: spectroscopic and calorimetric insights.

    Science.gov (United States)

    Misra, Pinaki P; Kishore, Nand

    2013-07-01

    Surfactants have long been implicated in the unique static and dynamic effect on the structure and function of serum albumins. However, there is very little information on the mode of interactions of drugs to serum albumins in presence of surfactants. The importance of such studies lay in the fact that apart from binding to serum albumins, surfactants are known to radically influence the solvents' micro environment and protein structure. Thus, we have studied the binding of the racemic form of ketoprofen with bovine serum albumin at pH 7.4 in the presence and absence of hexadecyl trimethyl ammonium bromide, sodium dodecyl sulfate, Triton X-100, and NaCl. The structural studies of ketoprofen with bovine serum albumin as investigated by circular dichroism spectroscopy revealed a significant stabilization of bovine serum albumin. However, the combined presence of the surfactants, NaCl and ketoprofen, demonstrated an extremely erratic behavior in terms of stabilization. Further the values of Stern-Volmer and dynamic quenching constant suggested the binding site of ketoprofen to be scattered in the region of domain I B and II A, close to Trp 134. The results of differential scanning calorimetry revealed that the binding of ketoprofen to bovine serum albumin leads to its temperature-dependent separation into two units. The binding parameters of bovine serum albumin obtained from isothermal titration calorimetry in the combined presence of ketoprofen and surfactants/NaCl correlate well with the differential scanning calorimetry studies further confirming the localization of ketoprofen in domain I B and II A. In the combined presence of surfactants, NaCl and ketoprofen, the binding of ketoprofen to bovine serum albumin exhibited altered binding parameters far different from the binding of ketoprofen alone. Overall, the experimental findings strongly indicated positive as well as negative modulation in the binding of ketoprofen to bovine serum albumin in the presence of ligands.

  6. The impact of a low glycaemic index (GI diet on simultaneous measurements of blood glucose and fat oxidation: A whole body calorimetric study

    Directory of Open Access Journals (Sweden)

    Bhupinder Kaur

    2016-06-01

    Conclusions: Consumption of LGI meals was capable of attenuating 24-hour blood glucose profiles and decreasing postprandial glucose excursions in healthy Asian males. Additionally, LGI mixed meals were able to promote fat oxidation over carbohydrate oxidation when compared to HGI mixed meals. The consumption of low GI meals may be a strategic approach in improving overall glycaemia and increasing fat oxidation in Asians consuming a high carbohydrate diet.

  7. Structural, functional and calorimetric investigation of MosA, a dihydrodipicolinate synthase from Sinorhizobium meliloti l5-30, does not support involvement in rhizopine biosynthesis.

    Science.gov (United States)

    Phenix, Christopher P; Nienaber, Kurt; Tam, Pui Hang; Delbaere, Louis T J; Palmer, David R J

    2008-07-02

    MosA is an enzyme from Sinorhizobium meliloti L5-30, a beneficial soil bacterium that forms a symbiotic relationship with leguminous plants. MosA was proposed to catalyze the conversion of scyllo-inosamine to 3-O-methyl-scyllo-inosamine (compounds known as rhizopines), despite the MosA sequence showing a strong resemblance to dihydrodipicolinate synthase (DHDPS) sequences rather than to methyltransferases. Our laboratory has already shown that MosA is an efficient catalyst of the DHDPS reaction. Here we report the structure of MosA, solved to 1.95 A resolution, which resembles previously reported DHDPS structures. In this structure Lys161 forms a Schiff base adduct with pyruvate, consistent with the DHDPS mechanism. We have synthesized both known rhizopines and investigated their ability to interact with MosA in the presence and absence of methyl donors. No MosA-catalyzed methyltransferase activity is observed in the presence of scyllo-inosamine and S-adenosylmethionine (SAM). 2-Oxobutyrate can form a Schiff base with MosA, acting as a competitive inhibitor of MosA-catalyzed dihydrodipicolinate synthesis. It can be trapped on the enzyme by reaction with sodium borohydride, but does not act as a methyl donor. The presence of rhizopines does not affect the kinetics of dihydrodipicolinate synthesis. Isothermal titration calorimetry (ITC) shows no apparent interaction of MosA with rhizopines and SAM. Similar experiments with pyruvate as titrant demonstrate that the reversible Schiff base formation is largely entropically driven. This is the first use of ITC to study Schiff base formation between an enzyme and its substrate.

  8. Numerical Modeling and Experimental Validation by Calorimetric Detection of Energetic Materials Using Thermal Bimorph Microcantilever Array: A Case Study on Sensing Vapors of Volatile Organic Compounds (VOCs)

    Science.gov (United States)

    Kang, Seok-Won; Fragala, Joe; Banerjee, Debjyoti

    2015-01-01

    Bi-layer (Au-Si3N4) microcantilevers fabricated in an array were used to detect vapors of energetic materials such as explosives under ambient conditions. The changes in the bending response of each thermal bimorph (i.e., microcantilever) with changes in actuation currents were experimentally monitored by measuring the angle of the reflected ray from a laser source used to illuminate the gold nanocoating on the surface of silicon nitride microcantilevers in the absence and presence of a designated combustible species. Experiments were performed to determine the signature response of this nano-calorimeter platform for each explosive material considered for this study. Numerical modeling was performed to predict the bending response of the microcantilevers for various explosive materials, species concentrations, and actuation currents. The experimental validation of the numerical predictions demonstrated that in the presence of different explosive or combustible materials, the microcantilevers exhibited unique trends in their bending responses with increasing values of the actuation current. PMID:26334276

  9. Numerical Modeling and Experimental Validation by Calorimetric Detection of Energetic Materials Using Thermal Bimorph Microcantilever Array: A Case Study on Sensing Vapors of Volatile Organic Compounds (VOCs

    Directory of Open Access Journals (Sweden)

    Seok-Won Kang

    2015-08-01

    Full Text Available Bi-layer (Au-Si3N4 microcantilevers fabricated in an array were used to detect vapors of energetic materials such as explosives under ambient conditions. The changes in the bending response of each thermal bimorph (i.e., microcantilever with changes in actuation currents were experimentally monitored by measuring the angle of the reflected ray from a laser source used to illuminate the gold nanocoating on the surface of silicon nitride microcantilevers in the absence and presence of a designated combustible species. Experiments were performed to determine the signature response of this nano-calorimeter platform for each explosive material considered for this study. Numerical modeling was performed to predict the bending response of the microcantilevers for various explosive materials, species concentrations, and actuation currents. The experimental validation of the numerical predictions demonstrated that in the presence of different explosive or combustible materials, the microcantilevers exhibited unique trends in their bending responses with increasing values of the actuation current.

  10. A calorimetric investigation of a series of mixed-chain polyunsaturated phosphatidylcholines: effect of sn-2 chain length and degree of unsaturation.

    OpenAIRE

    Niebylski, C D; Salem, N.

    1994-01-01

    Although mammalian tissues contain high levels of polyunsaturated fatty acids, our knowledge of the effects of the degree of unsaturation and double-bond location upon bilayer organization is limited. Therefore, a series of mixed-chain unsaturated phosphatidylcholines (PC) comprised of 18:0 at the sn-1 position and various unsaturates at the sn-2 position (18:1n9, 18:2n6, 18:3n6, 18:3n3, 20:2n6, 20:3n6, 20:4n6, 20:5n3, 22:4n6, 22:5n6, or 22:6n3) was studied with differential scanning calorime...

  11. Mise en service du calorimetre electromagnetique d'Atlas et determination du potentiel de decouverte d'un Z' --> e+e- dans les premieres donnees LHC

    CERN Document Server

    Mangeard, Pierre-Simon

    2009-01-01

    After about fifteen years of development, the ATLAS detector is ready to operate and recorded, in 2008, several millions of cosmic events as well as first LHC data. This achievement is based on the long experience of beam tests and on the large effort towards the detector in situ commissioning undertaken by the ATLAS collaboration. This promises fast ability to perform searches for evidence of Higgs boson and new physics. I heavily contributed to the in situ commissioning of the EM calorimeter. To verify its performance, I studied the first cosmic data taken in 2006 which allowed the first in situ analysis of dead channels, energy reconstruction and detector response uniformity. This participation to the commissioning has continued with the study of the single beam data recorded during the first week of LHC operation (Sept. 2008). Expanding on my expertise of the EM calorimeter, I focused my physics analysis, prepared with simulation, on the promising discovery potential of new physics at LHC via the di-elect...

  12. Stabilization of H sub II phases by low levels of diglycerides and alkanes: An NMR, calorimetric, and X-ray diffraction study

    Energy Technology Data Exchange (ETDEWEB)

    Siegel, D.P; Banschbach, J.; Yeagle, P.L. (Procter Gamble Company, Cincinnati, OH (USA))

    1989-06-13

    Traces of hydrophobic molecules like diglycerides and alkanes substantially reduce the lamellar/inverted hexagonal phase transition temperature of phospholipid systems. Two different mechanisms of which impurities can stabilize nonbilayer phases have been proposed. Each requires a different location for impurity molecules within the H{sub II}-phase unit cell. Here, {sup 2}H, NMR, {sup 31}P NMR, X-ray diffraction, and DSC were used to probe the environment of perdeuterated alkanes and chain-perdeuterated 1,2-dipalmitoylglycerol (DPG-d{sub 62}) in L{sub {alpha}}- and H{sub II}-phase lattices. The host phospholipids were dioleoylphosphatidylcholine (DOPC) and monomethylated dioleoylphosphatidylethanolamine (DOPE-Me), and the samples contained several mole percent of perdeuterated additives. The data collected here generally support the two proposed mechanisms of H{sub II} stabilization. The authors data are consistent with localization of perdeuterated alkane molecules to the periphery of H{sub II} tubes and to the hydrophobic interstices between H{sub II} tubes. X-ray diffraction data show that DPG decreases the lattice constant of the H{sub II} phase at constant temperature. These can modulate the phase behavior of biomembrane lipids. Such modulation may be involved in the control of dynamic processes in biomembranes.

  13. A calorimetric measurement of the strong coupling constant in electron-positron annihilation at a center-of-mass energy of 91.6 GeV

    Energy Technology Data Exchange (ETDEWEB)

    Martirena, S.G.

    1994-04-01

    In this work, a measurement of the strong coupling constant {alpha}{sub s} in e{sup +}e{sup {minus}} annihilation at a center-of-mass energy of 91.6 GeV is presented. The measurement was performed with the SLD at the Stanford Linear Collider facility located at the Stanford Linear Accelerator Center in California. The procedure used consisted of measuring the rate of hard gluon radiation from the primary quarks in a sample of 9,878 hadronic events. After defining the asymptotic manifestation of partons as `jets`, various phenomenological models were used to correct for the hadronization process. A value for the QCD scale parameter {Lambda}{sub bar MS}, defined in the {sub bar MS} renormalization convention with 5 active quark flavors, was then obtained by a direct fit to O({alpha}{sub s}{sup 2}) calculations. The value of {alpha}{sub s} obtained was {alpha}{sub s}(M{sub z0}) = 0.122 {plus_minus} 0.004 {sub {minus}0.007} {sup +0.008} where the uncertainties are experimental (combined statistical and systematic) and theoretical (systematic) respectively. Equivalently, {Lambda}{sub bar MS} = 0.28 {sub {minus}0.10}{sup +0.16} GeV where the experimental and theoretical uncertainties have been combined.

  14. Avalanche criticalities and elastic and calorimetric anomalies of the transition from cubic Cu-Al-Ni to a mixture of 18 R and 2 H structures

    Science.gov (United States)

    Vives, Eduard; Baró, Jordi; Gallardo, María Carmen; Martín-Olalla, José-María; Romero, Francisco Javier; Driver, Sarah L.; Carpenter, Michael A.; Salje, Ekhard K. H.; Stipcich, Marcelo; Romero, Ricardo; Planes, Antoni

    2016-07-01

    We studied the two-step martensitic transition of a Cu-Al-Ni shape-memory alloy by calorimetry, acoustic emission (AE), and resonant ultrasound spectroscopy (RUS) measurements. The transition occurs under cooling from the cubic (β , F m 3 m ) parent phase near 242 K to a mixture of orthorhombic 2 H and monoclinic 18 R phases. Heating leads first to the back transformation of small 18 R domains to β and/or 2 H near 255 K, and then to the transformation 2 H to β near 280 K. The total transformation enthalpy is Δ HT=328 ±10 J/mol and is observed as one large latent heat peak under cooling. The back-transformation entropy under heating breaks down into a large component 18 R to β at 255 K and a smaller, smeared component of the transformation 2 H to β near 280 K. The proportions inside the phase mixture depend on the thermal history of the sample. The elastic response of the sample is dominated by large elastic softening during cooling. The weakening of the elastic shear modulus shows a peak at 242 K, which is typical for the formation of complex microstructures. Cooling the sample further leads to additional changes of the microstructure and domain wall freezing, which is seen by gradual elastic hardening and increasing damping of the RUS signal. Heating from 220 K to room temperature leads to elastic anomalies due to the initial transformation, which is now shifted to high temperatures. The transition is smeared over a wider temperature interval and shows strong elastic damping. The shear modulus of the cubic phase is recovered at 280 K. The phase transformation leads to avalanches, which were recorded by AE and by time-resolved calorimetry. The cooling transition shows very extended avalanche signals in calorimetry with power-law distributions. Cooling and heating runs show AE signals over a large temperature interval above 260 K. Splitting the transformation into two martensite phases leads to power-law exponents ɛ ˜2 (β ↔ 18 R ) and ɛ ˜1.5 (β ↔ 2 H ) while the phase mixture shows an effective AE exponent of 1.7.

  15. Electrochemical and calorimetric investigation of interaction of novel biscationic anticancer agents with DNA; Investigacao eletroquimica e calorimetrica da interacao de novos agentes antitumorais biscationicos com DNA

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Lauris Lucia da; Donnici, Claudio Luis; Lopes, Julio Cesar Dias, E-mail: cdonnici@terra.com.br [Universidade Federal de Minas Gerais, Belo Horizonte, MG (Brazil). Inst. de Ciencias Exatas. Dept. de Quimica; Goulart, Marilia Oliveira Fonseca; Abreu, Fabiane Caxico de; Paula, Francine Santos de [Universidade Federal de Alagoas (UFAL), Maceio, AL (Brazil). Campus A.C. Simoes. Inst. de Quimica e Biotecnologia; Bravo, Carlos E. Salas; Santoro, Marcelo Matos [Universidade Federal de Minas Gerais, Belo Horizonte, MG (Brazil). Dept. de Bioquimica e Imunologia; Denadai, Angelo Marcio Leite [Centro Federal de Educacao Tecnologica, Timoteo, MG (Brazil). Campus VII; Santos, Alexandre Martins Costa [Universidade Federal do Espirito Santo, Vitoria, ES (Brazil). Dept. de Ciencias Fisiologicas; Montanari, Carlos Alberto [Universidade de Sao Paulo, Sao Carlos, SP (Brazil). Inst. de Quimica

    2012-07-01

    Biscationic amidines bind in the DNA minor groove and present biological activity against a range of infectious diseases. Two new biscationic compounds (bis-{alpha}-{omega}-S-thioureido, amino and sulfide analogues) were synthesized in good yields and fully characterized, and their interaction with DNA was also investigated. Isothermal titration calorimetry (ITC) was used to measure the thermodynamic properties of binding interactions between DNA and these ligands. A double stranded calf thymus DNA immobilized on an electrode surface was used to study the possible DNA-interacting abilities of these compounds towards dsDNA in situ. A remarkable interaction of these compounds with DNA was demonstrated and their potential application as anticancer agents was furthered. (author)

  16. New thermodynamic data for CoTiO3, NiTiO3 and CoCO3 based on low-temperature calorimetric measurements

    Directory of Open Access Journals (Sweden)

    Rohrbach Arno

    2011-09-01

    Full Text Available Abstract The low-temperature heat capacities of nickel titanate (NiTiO3, cobalt titanate (CoTiO3, and cobalt carbonate (CoCO3 were measured between 2 and 300 K, and thermochemical functions were derived from the results. Our new data show previously unknown low-temperature lambda-shaped heat capacity anomalies peaking at 37 K for CoTiO3 and 26 K for NiTiO3. From our data we calculate standard molar entropies (298.15 K for NiTiO3 of 90.9 ± 0.7 J mol-1 K-1 and for CoTiO3 of 94.4 ± 0.8 J mol-1 K-1. For CoCO3, we find only a small broad heat capacity anomaly, peaking at about 31 K. From our data, we suggest a new standard entropy (298.15 K for CoCO3 of 88.9 ± 0.7 J mol-1 K-1.

  17. Calibration by precise charge injection of a sub-detector of CMS; Calibration par injection de charge du calorimetre electromagnetique de CMS

    Energy Technology Data Exchange (ETDEWEB)

    Yong-Wook Baek

    2001-01-26

    This thesis was carried out within the framework of the international collaboration which has the responsibility of the experience CMS (Compact Muon Solenoid) on LHC, at CERN. The physics of the fundamental particles which will be explored by this experiment is described within the standard model. The configuration of sub-detector of CMS is briefly described, with a particular weight on the read-out chain of the electromagnetic calorimeter. The work carried out to calibrate this chain by a precise charge injection at the input of preamplifiers is described. The 4 integrated circuits CTRL, TPLS, DAC, and injector which will constitute the components of this chain of calibration are described. The circuit of injection, which is the main circuit in this project, was imagined and developed at the laboratory in DMILL technology. This injector generates a signal which has a form identical to the signal of the detector. The measurements on the linearity of the injectors are presented. In order to know its behavior under real conditions (flow of neutrons {approx} 2 x 10{sup 13} neutrons/cm{sup 2}/10 years) where this circuit is installed in detector CMS, we submitted the prototypes of injector to irradiation and the results are summarized. The research and development on this circuit produced an integrated circuit hardened to irradiations, whose variation of slope is lower than 0.25% for an integrated of 2 x 10{sup 13} neutrons/cm{sup 2} and indestructible under 10{sup 15} neutrons/cm{sup 2}. This circuit has satisfactory qualities to be assembled on the electronic card which will treat the data of calorimeter ECAL of CMS. (author)

  18. Solidification of AM and AZ magnesium alloys characterized by heat-transfer modeled thermal and calorimetric analysis and microsegregation study of directionally solidified microstructure

    Energy Technology Data Exchange (ETDEWEB)

    Mirkovic, Djordje

    2008-05-09

    The micro-scale solidification of commercial Mg alloys of the AZ and AM series is in the focus of the present thesis. Two approaches of investigating solidification are implemented, complementary regarding temperature gradient and solidification rate, and also with respect to the generated microstructure. The first approach considers solidification under a negligible spatial temperature gradient. Here the solidification curves, i.e. fraction solid versus temperature, were determined by developing an improved heat-transfer modeling applicable on both differential thermal analysis (DTA) and differential scanning calorimetry (DSC) signals. The correlation between solidification enthalpy and fraction solid during solidification was tested in detail. A better evaluation of the measured DTA and DSC signals is attained through an independent measurement of the time constant as function of temperature for the applied equipment. A further improvement is achieved through a more impartial interpretation of the measured curves. Both improvements enable a better desmearing of measured signals and reduce the error induced by the operator. The novel tantalum encapsulation enabled appropriate handling of challenging Mg-alloys. The viability and limitations of thermal analysis in general to determine start and end of solidification of AZ magnesium alloys was also studied. The second approach is based on directional solidification in a high temperature gradient and at constant solidification rate, achieved by the Bridgman technique. The resulting dendritic microstructure and inherent microsegregation are studied in this work. The solute profiles, i.e. solute content versus solid phase fraction during solidification, are determined by an advanced treatment of the EPMA data. Problems that are demonstrated in this work are Al-loss and melt pollution due to reaction with typical sample container material made of unprotected steel. The development of an optimized boron nitride (BN) coating to prevent detrimental reaction between Al and sample container is a successful novelty. The interplay between tube material, inside tube coating and details of the Bridgman device was thoroughly investigated. The result enables controlling the reaction on the tube/sample interface. The next novelty is correct implementation of the Scheil model for the solute profile calculation, implying precipitates during multiphase solidification. (orig.)

  19. Measurement of plasma-surface energy fluxes in an argon rf-discharge by means of calorimetric probes and fluorescent microparticles

    Science.gov (United States)

    Maurer, H. R.; Hannemann, M.; Basner, R.; Kersten, H.

    2010-11-01

    Measured energy influx densities toward a tungsten dummy substrate in an argon rf-plasma are presented and a model for the description of the energy influx density based on plasma parameters, which have been obtained by Langmuir probe measurements, is applied. Furthermore, temperature measurements of microparticles are presented, which are confined in the plasma sheath. An extension of the model is developed for the description of the energy influx density to the particles. The comparison of model and experimental results offer the possibility to obtain an improved understanding of plasma-surface interactions.

  20. Differential scanning calorimetric and powder X-ray diffraction studies on a homologous series of -acyl-L-alanine esters with matched chains ( = 9-18)

    Indian Academy of Sciences (India)

    D Sivaramakrishna; Musti J Swamy

    2015-09-01

    A homologous series of two chain derivatives of L-alanine, namely -acyl L-alanine alkyl esters (NAAEs), bearing matched, saturated, acyl and alkyl chains ( = 9-18) have been synthesized. The thermotropic phase transitions and supramolecular structure of NAAEs were investigated by differential scanning calorimetry (DSC) and powder X-ray diffraction (PXRD). Results obtained from DSC studies indicate that the transition temperatures (t), enthalpies ( t) and entropies ( t) exhibit odd-even alternation with compounds bearing odd acyl and alkyl chains showing higher values of t, t and t as compared to NAAEs with even acyl and alkyl chains. However, the transition enthalpies and entropies of the odd- and even chain length series independently exhibit a linear dependence on the chain length. The -spacings obtained from PXRD increase linearly with chain length with an increment of 1.76 Å/CH2, suggesting that NAAEs adopt either a tilted bilayer structure or a bent structure. The present results provide a thermodynamic and structural basis for investigating the interaction of NAAEs with other membrane lipids, which in turn can shed light in understanding how they can enhance the transdermal permeability of stratum corneum.

  1. Analysis of the Magnetocaloric Effect in Heusler Alloys: Study of Ni50CoMn36Sn13 by Calorimetric Techniques

    Directory of Open Access Journals (Sweden)

    Elias Palacios

    2015-03-01

    Full Text Available Direct determinations of the isothermal entropy increment, \\(-\\Delta S_T\\, in the Heusler alloy Ni\\(_{50}\\CoMn\\(_{36}\\Sn\\(_{13}\\ on demagnetization gave positive values, corresponding to a normal magnetocaloric effect. These values contradict the results derived from heat-capacity measurements and also previous results obtained from magnetization measurements, which indicated an inverse magnetocaloric effect, but showing different values depending on the technique employed. The puzzle is solved, and the apparent incompatibilities are quantitatively explained considering the hysteresis, the width of the martensitic transition and the detailed protocol followed to obtain each datum. The results show that these factors should be analyzed in detail when dealing with Heusler alloys.

  2. Calorimetric and magnetic study for Ni{sub 50}Mn{sub 36}In{sub 14} and relative cooling power in paramagnetic inverse magnetocaloric systems

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Jing-Han, E-mail: jhchen@tamu.edu [Department of Physics and Astronomy, Texas A and M University, College Station, Texas 77843 (United States); Bruno, Nickolaus M. [Department of Mechanical Engineering, Texas A and M University, College Station, Texas 77843 (United States); Karaman, Ibrahim [Department of Mechanical Engineering, Texas A and M University, College Station, Texas 77843 (United States); Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States); Huang, Yujin; Li, Jianguo [School of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai 200240 (China); Ross, Joseph H. [Department of Physics and Astronomy, Texas A and M University, College Station, Texas 77843 (United States); Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States)

    2014-11-28

    The non-stoichiometric Heusler alloy Ni{sub 50}Mn{sub 36}In{sub 14} undergoes a martensitic phase transformation in the vicinity of 345 K, with the high temperature austenite phase exhibiting paramagnetic rather than ferromagnetic behavior, as shown in similar alloys with lower-temperature transformations. Suitably prepared samples are shown to exhibit a sharp transformation, a relatively small thermal hysteresis, and a large field-induced entropy change. We analyzed the magnetocaloric behavior both through magnetization and direct field-dependent calorimetry measurements. For measurements passing through the first-order transformation, an improved method for heat-pulse relaxation calorimetry was designed. The results provide a firm basis for the analytic evaluation of field-induced entropy changes in related materials. An analysis of the relative cooling power (RCP), based on the integrated field-induced entropy change and magnetizing behavior of the Mn spin system with ferromagnetic correlations, shows that a significant RCP may be obtained in these materials by tuning the magnetic and structural transformation temperatures through minor compositional changes or local order changes.

  3. Top quark studies with Atlas at the LHC. Electromagnetic calorimeter commissioning; Etude du quark top avec Atlas au LHC. Mise en route du calorimetre electromagnetique

    Energy Technology Data Exchange (ETDEWEB)

    Resende Vaz de Melo Xavier, B

    2007-05-15

    The first proton-proton collisions in the Large Hadron Collider at CERN will take place on 2007. It aims at understanding the origins of mass. and it will also look for new physics. The ATLAS experiment will exploit all those physics potentialities. using a multilayer generalist detector. Quark top studies will be an important step in ATLAS physics program: its properties may reveal hints of new phenomena. One way to look for new physics is through quark top and W boson polarizations. which are studied here. This detailed simulation study has confirmed previous fast simulation results including extensive systematics estimation. ATLAS should thus yield a precision of a few percents with 10 fb{sup -1} of data. that is a year of LHC working. This precision is sufficient to select among several new physics models. Among ATLAS subsystems, the electromagnetic calorimeter plays a crucial role in the characterisation of electrons and photons. which are used in particular for the Higgs boson search. This document deals with the calorimeter commissioning as the time of the first collisions approaches. The detector itself and its electronics will be described, as well as its installation and calibration. Cosmic muons observation will then be presented. as the first overall test of the reading and reconstruction electronics chain in actual working conditions. (author)

  4. 2,6-Bis(2-Benzimidazolyl)Pyridine Fluorescent Red-Shifted Sensor for Recognition of Zinc(II) and a Calorimetric Sensor for Iron Ions.

    Science.gov (United States)

    Vosough Razavi, Bita; Badiei, Alireza; Lashgari, Negar; Mohammadi Ziarani, Ghodsi

    2016-09-01

    The ability of 2,6-bis(2-benzimidazolyl)pyridine (bbp) as an optical sensor was studied by fluorescence spectroscopy, colorimetric and UV-visible techniques. The fluorescence spectra of bbp demonstrated a red-shifted upon addition of Zn(2+) ion, whereas rest of the cations did not induce any shift. Selectivity of the sensor was examined toward Zn(2+) in the presence of a wide range of cations, as interfering agents, that showed no disruption in its function. In addition, the pH effect was tested on the fluorescence response of bbp; which showed the efficiency of the sensor in a wide pH range. The limit of detection for Zn(2+) was estimated as 2.1 μM. Furthermore, the colorimetric studies were carried out and the observations showed a color change from colorless to purple by the addition of Fe(2+) ion and from colorless to yellow by the addition of Fe(3+). The UV-visible studies were carried out to confirm the colorimetric observations. The color changes occurred when Fe(2+) and Fe(3+) were added to the sensors solution, respectively. The detection limits were calculated as 2.8 × 10(-7) M and 3.5 × 10(-6) M for Fe(2+) and Fe(3+), respectively. Hence, bbp can be used as a dual mode optical sensor for detection of Zn(2+) by fluorescence and discriminately detection of Fe(2+) and Fe(3+) visually.

  5. Construction of the ATLAS end cap electromagnetic calorimeter and study of its performances; Construction du bouchon du calorimetre electromagnetique d'ATLAS et etudes de ses performances

    Energy Technology Data Exchange (ETDEWEB)

    Barrillon, P

    2002-09-01

    ATLAS is one of the four experiments which will take place at the LHC, the CERN future protons collider. This accelerator, which should start in 2007, will allow to continue the studies carried out by its predecessors, as the standard model Higgs boson and new physics searches. The very high luminosity -10 fb{sup -1} during the first three functioning years, then 100 fb{sup -1}- and the 14 TeV in the frame center will ease these studies. The Centre de Physique des Particules de Marseille took part in the ATLAS collaboration, taking in charge half of the End-cap electromagnetic calorimeter modules construction. The description of this sub-detector and the construction steps, in particular the electrical tests which allow the stacking validation, are presented in this document. These tests results, obtained for the live first production modules, are analysed. The pre-series module (module 0) performances, obtained with beam tests performed at CERN in 1999, are also presented. The detector uniformity studies have allowed to perform important improvements on the calorimeter components. A 0.6% global constant term has been determined in the End-cap internal region (wheel). (author)

  6. Effect of temperature on the protonation of N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid in aqueous solutions: Potentiometric and calorimetric studies

    Energy Technology Data Exchange (ETDEWEB)

    Li, Xingliang [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Div.; China Academy of Engineering Physics, Mianyang (China). Inst. of Nuclear Physics and Chemistry; Zhang, Zhicheng [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Div.; Endrizzi, Francesco [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Div.; Martin, Leigh R. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Luo, Shunzhong [China Academy of Engineering Physics, Mianyang (China). Inst. of Nuclear Physics and Chemistry; Rao, Linfeng [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Div.

    2015-06-01

    The TALSPEAK process (Trivalent Actinide Lanthanide Separations by Phosphorus-reagent Extraction from Aqueous Komplexes) has been demonstrated in several pilot-scale operations to be effective at separating trivalent actinides (An3+) from trivalent lanthanides (Ln3+). However, fundamental studies have revealed undesired aspects of TALSPEAK, such as the significant partitioning of Na+, lactic acid, and water into the organic phase, thermodynamically unpredictable pH dependence, and the slow extraction kinetics. In the modified TALSPEAK process, the combination of the aqueous holdback complexant HEDTA (N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid) with the extractant HEH[EHP] (2-ethyl(hexyl) phosphonic acid mono-2-ethylhexyl ester) in the organic phase has been found to exhibit a nearly flat pH dependence between 2.5 and 4.5 and more rapid phase transfer kinetics for the heavier lanthanides. To help understand the speciation of Ln3+ and An3+ in the modified TALSPEAK, systematic studies are underway on the thermodynamics of major reactions in the HEDTA system under conditions relevant to the process (e.g., higher temperatures). Thermodynamics of the protonation and complexation of HEDTA with Ln3+ were studied at variable temperatures. Equilibrium constants and enthalpies were determined by a combination of techniques including potentiometry and calorimetry. This paper presents the protonation constants of HEDTA at T = (25 to 70) °C. The potentiometric titrations have demonstrated that, stepwise, the first two protonation constants decrease and the third one slightly increases with the increase of temperature. This trend is in good agreement with the enthalpy of protonation directly determined by calorimetry. The results of NMR analysis further confirm that the first two protonation reactions occur on the diamine nitrogen atoms, while the third protonation reaction occurs on the oxygen of a carboxylate group. These data, in conjunction with the thermodynamic parameters of Ln3+/An3+ complexes with HEDTA at different temperatures, will help to predict the speciation and temperature-dependent behavior of Ln3+/An3+ in the modified TALSPEAK process.

  7. Calorimetric Determination of Enthalpy of Formation of Natural Gas Hydrates%天然气水合物生成焓的实验研究

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    This paper reports the measurements of enthalpies of natural gas hydrates in typical natural gas mixturecontaining methane, ethane, propane and iso-butane at pressure in the vicinity of 2000 kPa (300 psi) and 6900 kPa(1000psi). The measurements were made in a multi-cell differential scanning calorimeter using modified highpressure cells. The enthalpy of water and the enthalpy of dissociation of the gas hydrate were determined fromthe calorimeter response during slow temperature scanning at constant pressure. The amount of gas released fromthe dissociation of hydrate was determined from the pumped volume of the high pressure pump. The occupationratio (mole ratio) of the water to gas and the enthalpy of hydrate formation are subject to uncertainty of 1.5%.The results show that the enthalpy of hydrate formation and the occupation ratio are essentially independent of pressure.

  8. X-ray photoemission, calorimetric, and electrical transport properties of CeCu{sub 4}Mn{sub y}Al{sub 1−y}

    Energy Technology Data Exchange (ETDEWEB)

    Synoradzki, K., E-mail: karol.synoradzki@ifmpan.poznan.pl [Institute of Molecular Physics, Polish Academy of Science, Smoluchowskiego 17, 60-179 Poznań (Poland); Toliński, T. [Institute of Molecular Physics, Polish Academy of Science, Smoluchowskiego 17, 60-179 Poznań (Poland); Chełkowska, G.; Bajorek, A. [Institute of Physics, Silesian University, Uniwersytecka 4, 40-007 Katowice (Poland); Zapotoková, M. [Institute of Experimental Physics, Slovak Academy of Sciences, Watsonova 47, 043 53 Košice (Slovakia); Reiffers, M. [Faculty of Humanities and Natural Sciences, Prešov University, 17. novembra 1, 081 16 Prešov (Slovakia); Hoser, A. [Helmholtz-Zentrum, Glienicker Straße 100, D-14109 Berlin (Germany)

    2014-07-15

    Highlights: • Ce 4f states well localized in the CeCu{sub 4}Mn{sub y}Al{sub 1−y} compounds. • Spin-glass contribution to specific heat has been estimated. • Magnetic phase diagram corroborated for CeCu{sub 4}Mn{sub y}Al{sub 1−y}. • Lack of a long-range magnetic order in CeCu{sub 4}Mn confirmed by neutron diffraction. - Abstract: We report the X-ray photoemission spectra (XPS) and the electrical resistivity measurements for the transition Kondo lattice – spin-glass (SG) in the series CeCu{sub 4}Mn{sub y}Al{sub 1−y}. The study includes additionally the low temperature (down to T = 400 mK) heat capacity results. The XPS measurements revealed that the Ce 4f states are well localized. Electrical resistivity studies illustrate a smooth evolution from the ∼ −ln T relation to the metallic behaviour with the increase of the Mn content. Moreover, the specific heat has been analysed considering the electronic, phonon, Schottky (Crystal Electric Field – CEF), Kondo, and SG contributions. The assumption that the CEF splitting of the energy levels is similar for all the compositions allowed us to estimate the SG and Kondo contribution to the heat capacity. Additionally, the neutron diffraction experiment on the parent CeCu{sub 4}Mn compound has confirmed that it does not show a long-range magnetic order.

  9. The 24-h energy intake of obese adolescents is spontaneously reduced after intensive exercise: a randomized controlled trial in calorimetric chambers.

    Directory of Open Access Journals (Sweden)

    David Thivel

    Full Text Available BACKGROUND: Physical exercise can modify subsequent energy intake and appetite and may thus be of particular interest in terms of obesity treatment. However, it is still unclear whether an intensive bout of exercise can affect the energy consumption of obese children and adolescents. OBJECTIVE: To compare the impact of high vs. moderate intensity exercises on subsequent 24-h energy intake, macronutrient preferences, appetite sensations, energy expenditure and balance in obese adolescent. DESIGN: This randomized cross-over trial involves 15 obese adolescent boys who were asked to randomly complete three 24-h sessions in a metabolic chamber, each separated by at least 7 days: (1 sedentary (SED; (2 Low-Intensity Exercise (LIE (40% maximal oxygen uptake, VO(2max; (3 High-Intensity Exercise (HIE (75%VO(2max. RESULTS: Despite unchanged appetite sensations, 24-h total energy intake following HIE was 6-11% lower compared to LIE and SED (p<0.05, whereas no differences appeared between SED and LIE. Energy intake at lunch was 9.4% and 8.4% lower after HIE compared to SED and LIE, respectively (p<0.05. At dinner time, it was 20.5% and 19.7% lower after HIE compared to SED and LIE, respectively (p<0.01. 24-h energy expenditure was not significantly altered. Thus, the 24-h energy balance was significantly reduced during HIE compared to SED and LIE (p<0.01, whereas those of SED and LIE did not differ. CONCLUSIONS: In obese adolescent boys, HIE has a beneficial impact on 24-h energy balance, mainly due to the spontaneous decrease in energy intake during lunch and dinner following the exercise bout. Prescribing high-intensity exercises to promote weight loss may therefore provide effective results without affecting appetite sensations and, as a result, food frustrations. TRIAL REGISTRATION: ClinicalTrial.gov NCT01036360.

  10. Calorimetric, Viscosimetric, and Light Scattering Studies of the Aggregation of, and the Solubilization of Water by, Triton X-35 in n-Heptane.

    Science.gov (United States)

    Lagerge; Grimberg-Michaud; Guerfi; Partyka

    1999-01-15

    The behavior of a nonionic surfactant TX-35 in solution in n-heptane in the presence and absence of added water has been examined using the microcalorimetric, viscosimetric, and quasielastic light scattering experimental methods. In this paper, we were interested in the aggregation process of the poly(oxyethylene) glycol alkylphenyl ether in n-heptane and in the solubilization of water in the reverse micelle of the surfactant (micellar solubilization). The analysis of the differential molar enthalpies of dilution of TX-35 in dried n-heptane has shown the occurrence of a gradual exothermic aggregation process on a very wide range of concentration which takes place at particular concentration so-called "operational CMC". This operational CMC value has been confirmed by viscosities measurements. The differential molar enthalpies of hydration of TX-35 were also measured and found to be exothermic. The maximal hydration ratio (w0) was found to be equal to 3.2 mol H2O per mole of TX-35 before the point of phase separation. The measurements of the variation of the amount of water contained in TX-35 solutions at different concentrations in n-heptane also show the occurence of a gradual aggregation process and confirm the value of the maximal hydration ratio already determined by microcalorimetry. In the absence of added water, from the quasielastic light scattering experiments, a mean diameter of the aggregates close to 45 Å has been determine, while in the presence of water, a mean diameter of 61 Å was detected and remained unchanged with increasing the hydration ratio indicating that the size of the aggregate is more influenced by the presence of water than by the amount. In the presence of water, it is relevant to discuss aggregates of lamellar or filament shape. Copyright 1999 Academic Press.

  11. Magnetic and calorimetric studies of magnetocaloric effect in La0.7-xPrxCa0.3MnO3

    Science.gov (United States)

    Barik, S. K.; Aparnadevi, M.; Rebello, A.; Naik, V. B.; Mahendiran, R.

    2012-04-01

    We report magnetocaloric effect in La0.7-xPrxCa0.3MnO3 (x = 0, 0.2, 0.3, and 0.4). All these compounds undergo first-order paramagnetic to ferromagnetic transition upon cooling and show field-induced metamagnetic transition (FIMMT) in the paramagnetic state. The FIMMT is accompanied by a release of latent heat and change in temperature of the sample as evidenced from differential scanning calorimetry and thermal analysis data for x = 0.3. The magnetic entropy decreases (-ΔSm = 8.23, 8.1, 7, and 5.38 Jkg-1 K-1 for a field change of ΔH = 5 T, for x = 0, 0.2, 0.3, and 0.4, respectively) and refrigeration capacity (RC) increases with increasing x (RC = 197, 215, 240, and 259 J/kg for x = 0, 0.2, 0.3, and 0.4, respectively). We suggest that collapse of magnetic polarons in the paramagnetic state and magnetovolume effect are responsible for the observed FIMMT and large -ΔSm values.

  12. The influence of cosolvents on hydrophilic and hydrophobic interactions. Calorimetric studies of parent and alkylated cyclomaltooligosaccharides in concentrated aqueous solutions of ethanol or urea.

    Science.gov (United States)

    Castronuovo, Giuseppina; Niccoli, Marcella

    2008-11-03

    Heats of dilution in water and in aqueous 7 mol kg(-1) urea and 3 mol kg(-1) ethanol of binary solutions containing cyclomaltohexaose, cyclomaltoheptaose, cyclomaltooctaose, 2-hydroxypropyl-cyclomaltohexaose (HPαCD), 2-hydroxypropyl-cyclomaltoheptaose (HPβCD), methyl-cyclomaltohexaose (MeαCD), methyl-cyclomaltoheptaose (MeβCD) and 2-hydroxypropyl-cyclomaltooctaose (HPγCD) have been determined at 298.15K by flow microcalorimetry. The purpose of this study is to gain information about the influence of urea and ethanol, which have different effects on water structure, on hydrophilic and hydrophobic interactions. The pairwise interaction coefficients of the virial expansion of the excess enthalpies were evaluated and compared to those previously obtained for binary solutions of cyclomaltohexaose and cyclomaltoheptaose. The particular behaviour of cyclomaltooligosaccharides in water is put in evidence with respect to that shown by simple oligosaccharides. The values of the interaction coefficients greatly change in dependence of the solvent medium. They are negative in water for unsubstituted cyclomaltooligosaccharides, and positive for the alkyl-substituted ones, thus marking the major role of the hydrophobic interactions. In concentrated aqueous ethanol, coefficients are negative, while they are positive in concentrated aqueous urea. Urea solvates the hydroxyl group provoking the attenuation of hydrophilic and hydrophobic interactions. Instead, the presence of the cosolvent ethanol, which lowers the relative permittivity of the medium, enhances the strength of hydrophilic interactions.

  13. Thermodynamics of the interactions of a homologous series of some amino acids with trimethylamine N-oxide: Volumetric, compressibility, and calorimetric studies

    Energy Technology Data Exchange (ETDEWEB)

    Choudhary, Sinjan [Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076 (India); Kishore, Nand, E-mail: nandk@chem.iitb.ac.in [Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076 (India)

    2011-10-15

    Highlights: > Thermodynamics of interaction of amino acids with trimethy N-oxide (TMAO) studied. > Partial molar properties in aqueous osmolyte provide interaction details. > Volumes, compressibilites, enthalpies indicate predominant hydrophobic interactions. > TMAO exerts its effect both by preferential hydration and hydrophobic interactions. > Results suggest hydrophobic interactions lead to destabilization of the protein. - Abstract: The values of apparent molar volume V{sub 2,{phi}} and apparent molar compressibility K{sub S,2,{phi}} of glycine, L-alanine, DL-{alpha}-amino-n-butyric acid, L-valine, and L-leucine have been determined in the aqueous solution of 1 mol . kg{sup -1} and 2 mol . kg{sup -1} trimethylamine N-oxide (TMAO) solutions by density and sound velocity measurements. Isothermal titration calorimetry has been employed to determine the values of heats of dilution q of the aqueous solutions of these amino acids in TMAO at temperatures from T = 288.15 K to T = 308.15 K. These data have been used to calculate values of the infinite dilution standard partial molar volume (V{sub 2,m}{sup 0}), standard partial molar isentropic compressibility (K{sub S,2,m}{sup 0}) and limiting enthalpy of dilution ({Delta}{sub dil}H{sup o}) of the amino acids in aqueous TMAO solutions. The standard partial molar volumes of transfer ({Delta}{sub tr}V{sub 2,m}{sup 0}), isentropic compressibility of transfer ({Delta}{sub tr}K{sub S,2,m}{sup 0}), and enthalpy of dilution of transfer ({Delta}{sub tr{Delta}dil}H{sup o}) of amino acids from water to aqueous TMAO solutions have been calculated from the measured quantities for these thermodynamic quantities. The linear correlation of V{sub 2,m}{sup 0} for a homologous series of amino acids has been utilized to calculate the contribution of the charged end groups (NH{sub 3}{sup +}, COO{sup -}), CH{sub 2} groups, and the other alkyl chains of the amino acids to V{sub 2,m}{sup 0}. The results for the partial molar properties of transfer from water to aqueous TMAO solutions have been interpreted in terms of ion-ion, ion-polar, hydrophilic-hydrophobic, and hydrophobic-hydrophobic group interactions. The volume, compressibility, and enthalpy of dilution of transfer data suggest that hydrophobic interactions predominant in this system. It is inferred that the effect of TMAO on protein stability need not be necessarily due to preferential hydration, it can also interact with the hydrophobic groups of the constituents of protein affecting its stability.

  14. Dose rate range extension of the calibration of dosemeters at LNMRI, Rio de Janeiro, Brazil; Expansao da faixa de taxas de dose para a calibracao de instrumentos de medir radiacao no LNMRI, Rio de Janeiro, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Cabral, T.S.; Carlos, M.T.; Ramos, M.M.O., E-mail: tschirn@ird.gov.b, E-mail: marcia@ird.gov.b, E-mail: mmoramos@ird.gov.b [Instituto de Radioprotecao e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2009-07-01

    The present work has an objective the implantation of a experimental arrange for application of essays of instrument calibration for measurement of low dose rate, which measure rate less than 10 {mu}Sv/h

  15. Dosimetry in non-homogeneous media with alanine/EPR mini dosemeters and simulation with PENELOPE Monte Carlo code;Dosimetria em meios nao-homogeneos com minidosimetros de alanina/EPR e simulacao Monte Carlo com o codigo PENELOPE

    Energy Technology Data Exchange (ETDEWEB)

    Vega Ramirez, J.L.; Chen, F.; Nicolucci, P.; Baffa, O. [Universidade de Sao Paulo (FFCLRP/USP), Ribeirao Preto, SP (Brazil). Faculdade de Filosofia, Ciencias e Letras. Dept. de Fisica e Matematica

    2009-07-01

    The dosimetric system of L-alanine mini dosimeter and K-Band EPR spectrometer was tested for the dosimetry in non-homogeneous media through the determination of the Percentage Depth Dose (PDD) curve for a small radiation field. The alanine mini dosimeters were produced by mechanical pressure of a mixture of L-alanine (95%) and PVA (5%) to nominal dimensions of 1 mm diameter and 3 mm length and 3 - 4 mg. For detecting the EPR signal of the mini dosimeters irradiated to 25 Gy, a K-Band (24 GHz) spectrometer was used. The dosimeters were irradiated in a {sup 60}Co radiotherapy unit using 80 cm source skin distance and field sizes of 2.5 x 2.5 cm{sup 2}. The inhomogeneous phantom consisted of acrylic and cork sheets of 30 x 30 x 1 cm{sup 3}; six cork sheets were sandwiched between five and nine acrylic sheets, which were placed at the top and bottom regions respectively. PDD curves with radiographic film and PENELOPE simulation were also determined. The PDD results for alanine mini dosimeters agreed better than 5.9% with film and PENELOPE. (author)

  16. Utilization of ALANPOL dosemeter composed by alanine and polyethylene for determination of doses in industrial effluents; Utilizacao do dosimetro ALANPOL composto por alanina e polietileno para determinacao de doses em efluentes industriais

    Energy Technology Data Exchange (ETDEWEB)

    Rela, Carolina S.; Sampa, Maria Helena de O.; Napolitano, Celia M. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: csrela@ipen.br; Pontuschka, Walter M. [Sao Paulo Univ., SP (Brazil). Inst. de Fisica

    2005-07-01

    A study of traceability and accuracy was performed with the dosimetry system ALANPOL developed by IVHTJ/ Poland that uses alanine as a dosimeter and EPR as the read out system. The dosimeter ALANPOL is a polymer compound that aggregates alanine. The dosimeter has the outside diameter 3 mm, and the length of 25,4 mm (1 inch). In order to use this dosimeter for monitoring the existing real time calorimetry dosimeter system set up in a electron beam waste treatment plant. Electron beam and gamma irradiation experiments with ALANPOL was carried out under demineralized water and industrial effluent. The result show that in the dose range of 1-40 kGy the ALANPOL dosimeter system is suitable underwater monitoring for absorbed dose and can be applied for the evaluation of the on line calorimetry dosimeter system. (author)

  17. Comparison of characteristics of LiF:Mg,Ti e LiF:Mg,Cu,P thermoluminescent dosemeters; Comparacao das caracteristicas dos dosimetros termoluminescentes LiF:Mg,Ti e LiF:Mg,Cu,P

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, M.S.; Filipov, D., E-mail: dfilipov@utfpr.edu.br [Universidade Tecnologica Federal do Parana (UTFPR/DAFIS), Curitiba, PR (Brazil). Departamento Academicao de Fisica; Schelin, H.R. [Instituto de Pesquisa Pele Pequeno Principe (IPPPP), Curitiba, PR (Brazil)

    2014-07-01

    The aim of the current study was to compare the thermoluminescent dosimeters LiF:Mg,Ti (TLD-100) and LiF:Mg,Cu,P (MCP) data, which were acquired by the Federal Technological University - Parana. Tests were realized, for this purpose, such as: sensitivity (only one MCP TLD did not present results within the limit range), linearity (whose MCP result was better than the TLD-100 one), energy dependence (TLD-100 presented lower variation than MCP TLD) and reproducibility (whose TLD-100 results were better than the MCP ones). The results from both dosimeters show that these TLDs attend radiodiagnostic dosimetry criteria, however MCP had more satisfactory results. (author)

  18. Study of the response to neutrons of a personal dosemeter in mixed fields (n, {gamma}) in function of Hp(10); Estudio de la respuesta a neutrones de un dosimetro personal en campos mixtos (n, {gamma}) en funcion de Hp(10)

    Energy Technology Data Exchange (ETDEWEB)

    Cruzate, J.; Gregori, B.; Carelli, J.; Aguerre, L.; Discacciatti, A. [Autoridad REgulatoria Nuclear, Av. del Libertador 8250 (1429), Buenos Aires (Argentina)]. e-mail: cruzate@cae.arn.gov.ar

    2006-07-01

    In this work it is presented the theoretical study and their experimental validation of the answer of the personal dosimetro in terms of the component of neutrons of the personal equivalent dose Hpn(10) in function of the energy, in presence of fields of neutrons and range. The personal dosimetro, based on detecting termoluminiscentes (TLD), it consists of two detectors 7LiF and two 6LiF, located low filters of plastic and cadmium starting from whose information is evaluated the component range and of neutrons of the dose. Additionally it consists of a detecting CaF2, used basically to discriminate against the energy of the component range and to make the corresponding corrections on the evaluation of the dose range obtained with the 7LiF. The answer to neutrons in function of the energy, defined as the quotient among the one I number of reactions 6Li(n, a)4He taken place in each TLD and the Hpn(10), it was calculated using the code MCNPX and the library ENDF/B-VI. You model the dosimetro under the irradiation conditions proposed by the ISO8529-3. Faces monoenergeticos were simulated in the range of energy understood between 70 keV and 5 MeV. The dispersion in each one of the results of the simulation is smaller than 3%. You I study the existent relationship among the answer te6rica, reactions (n,a)/Hpn(10) and the experimental one, nC/Hpn(10), for a given thermal treatment. The factor of resulting conversion is constant in the energy and similar to 1,71 104 reacciones(n, a)/nC, with a smaller standard deviation to 10%. The experimental answer was obtained starting from the irradiations carried out in the mark of the International Intercomparacion of Dosimetria in Mixed Campos (n,) 2004 organized by the OIEA next to the PTB (Germany) and the IRSN (France). The extension of these calculations to other spectra of neutrons of fields real they will allow to obtain group of factors of application conversion in routine and accidental situations. (Author)

  19. Simulation of ferric ions transfer in dosemeter Fricke-Xylenol-Gel in means no homogeneous; Simulacao da difusao de ions ferricos em dosimetros Fricke-Xilenol-Gel em meios nao homogeneos

    Energy Technology Data Exchange (ETDEWEB)

    Milani, Caio J.; Bevilacqua, Joyce da Silva, E-mail: caio.milani@usp.br, E-mail: joyce@ime.usp.br [Universidade de Sao Paulo (USP), SP (Brazil). Instituto de Matematica e Estatistica. Departamento de Matematica Aplicada; Cavinato, Christianne C.; Rodrigues Junior, Orlando; Campos, Leticia L., E-mail: rodrijr@ipen.br, E-mail: Icrodri@ipen.br, E-mail: ccavinato@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (lPEN/CNEN-SP), Sao Paulo, SP (Brazil). Gerencia de Metrologia das Radiacoes

    2013-11-01

    Dosimetry in three dimensions using Fricke-Xilenol-Gel dosimeters (FXG) allows the confirmation and a better understanding of a treatment by Radiotherapy. The technique involves the assessment of the irradiated volumes by magnetic resonance imaging (MRI) or optical-CT. On both cases, the time elapsed between the irradiation and the measurement is an important factor in the quality of results. The quality of the images can be compromised by the mobility of the ferric ions (Fe{sup 3+}), formed during the the interaction of the radiation with the matter, increasing the uncertainty in the determination of the isodoses in the volume. In this work, the phenomenon of the diffusion of the ferric ions formed by an irradiated region is simulated in a bidimensional domain. The dynamic of the Fe{sup 3+} in Fricke-Gel is modeled by a parabolic partial differential equation and solved by the ADI-Peaceman-Rachford algorithm. Stability and consistency of the method guarantee the convergence of the numerical solution for a pre-defined error magnitude, based on choices for the discretization values of time and space. Homogeneous and non-homogeneous cases are presented considering an irradiated region and a physical barrier that prevents the movement of the ions, on the non-homogeneous case. Graphical visualizations of the phenomenon are presented for better understanding of the process. (author)

  20. Development of a compact electronic dosemeter from CMOS sensor for radon measurement; Developpement d'un dosimetre electronique compact a base de capteurs CMOS pour la mesure du radon

    Energy Technology Data Exchange (ETDEWEB)

    Higueret, St

    2007-12-15

    Radon detection is a long-standing challenge in the field of radioprotection, and the IPHC Institute of Strasbourg has pushed for the development of a fully electronic device, portable and really standalone. Our first prototype of CMOS system-on-chip is presented, together with efficiency tests and the corresponding physics simulations (TRIM, GEANT IV). We describe several electronic boards which have been developed for various kinds of tests, firstly passive detection of {alpha}-particles from gaseous {sup 222}Rn in a large spectrum of activity concentrations. In a second stage, active collection of the daughter isotopes {sup 218}Po and {sup 214}Po was performed: these elements, appearing as attached on the aerosols present in air, are an important contribution to internal {alpha}-irradiation. The final electronic system, of only 10 cm size, includes four independent chips to ensure simultaneous detection of radon gas and its aerosols. An excellent linearity has been measured up to 80 kBq.m{sup -3} on the BACCARA bench of the IRSN at Saclay. A new generation chip is also studied. (author)

  1. Diffusion simulation of ferric ions in dosemeter Fricke-gel with variable diffusion coefficient; Simulacao da difusao de ions ferricos em dosimetros Fricke-gel com coeficiente de difusao variavel

    Energy Technology Data Exchange (ETDEWEB)

    Milani, Caio Jacob; Bevilacqua, Joyce da Silva, E-mail: caio.milani@usp.br, E-mail: joyce@ime.usp.br [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Inst. de Matematica e Estatistica. Dept. de Matematica Aplicada; Rodrigues Junior, Orlando, E-mail: rodrijr@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Gerencia de Metrologia das Radiacoes

    2014-07-01

    Dosimetry using dosimeters Fricke-xylenol-Gel (FXG) allows confirmation and better understanding of radiotherapy treatments. The technique involves the evaluation of volumes irradiated by magnetic resonance imaging (MRI) or CT-optical. In both cases, the time spent between the irradiation and measurement is an important factor that directly influences the results. The quality of the images can be compromised by the mobility of ferric ions (Fe 3+), formed during the interaction of radiation with matter, increasing the uncertainty in determining the isodose. In this work, we simulated the dynamic involving ferric ions formed in one irradiated region irradiated in a two-dimensional domain with a variable diffusion coefficient. This phenomenon is modeled by a differential equation and solved numerically by an efficient algorithm that generalizes the Crank-Nicolson method. The stability and consistency of the method guarantee the convergence of the numerical solution for a predefined tolerance based in the choice of discretization steps of time and space. Different continuous functions were chosen to represent the diffusion coefficient and graphical views of the phenomenon are presented for a better understanding of the process.

  2. Responses of different dosemeters in beta dosimetry of {sup 106}Ru/{sup 106}Rh ophthalmic applicators;Respostas de diferentes dosimetros termoluminescentes na dosimetria beta de aplicadores oftalmicos de {sup 106}Ru/{sup 106}Rh

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, D.F.P.; Daros, K.A.C.; Segreto, R.A.; Medeiros, R.B. [Universidade Federal de Sao Paulo (UNIFESP), Sao Paulo, SP (Brazil)

    2009-07-01

    This work presents the TL response of three kinds of dosimeters from different manufacturing characteristics under irradiation of 106 Ru / 106 Rh sealed sources used in ophthalmic brachytherapy. They are: Ca SO{sub 4}:Dy + teflon (D- Ca SO{sub 4}:Dy -0,4), LiF:Mg, Ti (TLD-100) and Ca SO{sub 4}:Dy (TLD-900). Some of reports accepted by scientific community (NCS report 14 e ICRU report 72) as reference in the quality control of beta applicators dosimetry recommend that the absorbed dose standard uncertainties can be kept below 20%. The TLD Ca SO{sub 4}:Dy + teflon presented proper sensibility and high precision comparing with the others. Considering the similar dimensions of ophthalmic tumors and aside critical structures it is relevant to reduce undesirable effects due to the irradiation of these structures. Therefore, the quality control in the beta dosimetry using this kind of source is a constant challenge. (author)

  3. PPV analysis and tension of spectral peak in an X radiation equipment for dosemeter calibration; Analise do PPV e tensao de pico espectral em um equipamento de raios-X para calibracao de dosimetros

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, P.M.C.; Santana, P.C. [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Departamento de Anatomia e Imagem; Lacerda, M.A.S.; Silva, T.A. da, E-mail: pmco@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2014-07-01

    Dosimetry laboratories around the world try to achieve metrology consistency between the X-rays beams for therapy and diagnostic detectors calibration. One of the parameters to characterize X-ray beam is the practical peak voltage (PPV) assessment. In this work were evaluated the PPV and spectral peak voltage in the potential constant X-ray equipment, that result in a mean difference of 1.4 %. (author)

  4. Monitoring of doses in hemodynamic medical team with dosemeters calibrated to measure the personal dose equivalent; Monitoracao das doses na equipe medica de hemodinamica com dosimetro calibrado em equivalente de dose pessoal

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, T.C. [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Curso de Ciencias e Tecnicas Nucleares]. E-mail: alonso@cdtn.br; Silva, T.A. da [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil)]. E-mail: silvata@cdtn.br

    2005-07-01

    In hemodynamic, the exposure time of the workers to the radiation are larger than in the conventional one. Consequently, the received doses are larger. The dose of the medical team is also affected significantly by the uniqueness of the exams that are accomplished in two ways of irradiation and several angles of incidences, what stands out the need of the dosimeters use with metrologic reliability adapted for such situations. The individual monitoring of the doses received by individuals occupationally exposed to the radiation is accomplished with films dosimeters or thermo luminescent ones, with the main objective to guarantee that the limits of doses are not surpassed. The used in the system Brazilian metrologic system is still the individual dose for photons, in spite of the international recommendations for the use of the equivalent personal dose, that is the greatness adapted to assess the equivalent dose and the effective dose. In this work, the dosimeter composed by the Harshaw-Bicron badge and the detecting thermoluminescent of lithium fluoride was tested and adapted to measure the equivalent of personal dose in the depths 0,07 mm and 10 mm. It was applied in the hemodynamics practices and the doses were compared with those obtained by the routine film dosimeter. The results suggest, for daily use of the interventional services, the indication of the new dosimeter in substitution to the of the type films. (author)

  5. Influence of ultraviolet radiation (UV) on the physicochemical stability of a radon dosemeter: the CN-85; Influence du rayonnement ultraviolet (UV) sur la stabilite physico-chimique d'un dosimetre du radon: le CN-85

    Energy Technology Data Exchange (ETDEWEB)

    Mbodj, M.; Sow, H.T.; Ndoye, O.; Gassama, S.S. [Faculte de Medecine, UCAD, Lab. de Biophysique et Medecine Nucleaire (Senegal); Ndiaye, A.; Diarra, M. [Faculte de Medecine, UCAD, Lab. de Biophysique pharmaceutique (Senegal); Ndiaye, D.; Tidjani, A. [Faculte des Sciences et Techniques, UCAD, Lab. des Rayonnements Naturels et Artificiels (Senegal)

    2007-07-15

    The radon dosimeters such as cellulose nitrates are often degraded under the action of certain physical or chemical factors. In our research we studied the behavior of the CN-85, solid state nuclear track detector, in very sunny tropical atmosphere (natural photo-ageing) and in enclosure S.E.P.A.P. 12/24 (artificial accelerated photo-ageing), before its exposure to a source of particles alpha (Am-241). The results showed chemical modifications of the detector, involving a change of coloring in accelerated as well as in natural photo-ageing, yet more in the first mode. The comparative study of the two modes (of photo-ageing) made it possible to determine an ageing acceleration factor of 2.5. The irradiation of the detectors with the particles alpha has shown a 98% loss of effectiveness after 40 hours of solar exposure, which makes it possible to consider the operational limit duration of the detector as hardly exceeding a week, in tropical atmosphere. This utilization period could be prolonged inside the dwellings due to the fall of the temperature and luminosity. (authors)

  6. Study of performance of electronic dosemeters in continuous and pulsed X-radiation beams; Estudo de desempenho de dosimetros eletronicos em feixes de raios-X continuos e pulsados

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Margarete Cristina

    2014-07-01

    Personal radiation monitoring is a basic procedure to verify the compliance to regulatory requirements for radiological protection. Electronic personal dosimeters (EPD) based on solid state detectors have largely been used for personnel monitoring; including for pulsed radiation beams where their responses are not well known and deficiencies have been reported. In this work, irradiation conditions for testing the response of EPDs in both continuous and pulsed X-ray beams were studied to be established in a constant potential Seifert-Pantak and in a medical Pulsar 800 Plus VMI X-ray machines. Characterization of X-ray beams was done in terms of tube voltage, half-value layer, mean energy and air kerma rate. A Xi R/F Unfors solid state dosimeter used as reference for air kerma measurements was verified against a RC-6 and 10X6-6 Radical ionization chambers as far its metrological coherence. Rad-60 RADOS, PDM- 11 Aloka and EPD MK2 Thermo electron EPDs were selected to be tested in terms of relative intrinsic error and energy response in similar to IEC RQR, IEC RQA and ISO N reference radiations. Results demonstrated the reliability of the solid state Xi R/F Unfors dosimeter to be as reference dosimeter although its response was affected by heavily filtered beams. Results also showed that relative intrinsic errors in the response of the EPDs in terms of personal dose equivalent, Hp(10), were higher than the requirement established for continuous beams. In pulsed beams, some EPDs showed inadequate response and high relative intrinsic errors. This work stressed the need of performing additional checks for EPDs, besides the limited {sup 137}Cs beam calibration, before using them in pulsed X-ray beams. (author)

  7. Implementation of a laboratory for manufacture, repair and electric calibration of dosemeters based in ionization chambers utilized in radiotherapy; Implementacao de um laboratorio para manutencao, reparo e calibracao eletrica de dosimetros baseados em camaras de ionizacao, utilizados em radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Becker, P.H.B.; Peres, M.A.L.; Moreira, A.J.C.; Nette, H.P. [Instituto de Radioprotecao e Dosimetria. Av. Salvador Allende S/N. Barra de Tijuca CEP: 22780-160. Caixa Postal: 37750 Rio de Janeiro-RJ (Brazil)

    1998-12-31

    Manufacturers of ionization chamber dosimeters for radiotherapy maintain only sales representatives in Brazil with no servicing capability causing difficulties to customers/users to get broken equipment back into operation. Aiming to partially solve this problem, a laboratory for maintenance, repair and electrical calibration was started in 1995 with the support of a two year IAEA Technical Assistance Project (BRA/1/031). (Author)

  8. Instrumentation for the individual dosimetry of workers

    CERN Document Server

    Thévenin, J C

    2003-01-01

    The control of the radiation dose exposure of workers and personnel exposed to ionizing radiations (nuclear industry, nuclear medicine, army, university laboratories etc..) is ensured by individual dosemeters. This dosimetry is mandatory for all workers susceptible to be exposed to more than 30% of the regulatory dose limit. dosemeters are worn on the chest and in some particular cases, on the finger (dosemeter rings) or on the wrist. Passive dosemeters allow to measure the dose a posteriori, while electronic dosemeters allow a direct reading and recording of the dose. This article presents successively: 1 - the general principles of individual dosimetry: situations of exposure, radiation detection, operational data, standardization, calibration and quality assurance, measurement uncertainties; 2 - goals and regulatory framework of individual dosimetry: regulation and recommendations, optimization, respect of dose limits, accidental situations; 3 - passive dosemeters: film, thermoluminescent, radio-photolumin...

  9. Personnel photon dosimeter on the base of TLD sup n sup a sup t LiF

    CERN Document Server

    Kaskanov, G Y

    2003-01-01

    A personnel photon dosemeter on the basis of thermoluminescence detectors (TLD) sup n sup a sup t LiF is described. Experimental responses of the dosemeters in the unit of individual equivalent dose H sub p (10) for energy of photons 59.5, 120, 662, and 1250 keV are presented. It is shown that the dosemeter allows one to measure H sub p (10) with admissible uncertainty in the energy range from 60 to 1250 keV.

  10. Optically stimulated luminescence response to Al2O3 to beta radiation

    DEFF Research Database (Denmark)

    Akselrod, A.; Akselrod, M.S.; Agersnap Larsen, N.

    1999-01-01

    High sensitivity dosemeters based on Al2O3:C have been prepared and tested for use as beta dosemeters using optically stimulated luminescence (OSL). Two types of sample were prepared and tested, namely unpolished thick, single crystal chips and thin powder layers on aluminium substrates...

  11. Dosimeter configurations for the measurement of Hs(0.07) and Hp(10) from photons

    DEFF Research Database (Denmark)

    Christensen, P.; Bøtter-Jensen, L.; Ennow, K.

    1990-01-01

    The optimisation is discussed of filter/detector configurations of dosemeters for individual monitoring for photons in the energy range from 20 keV to 1.3 MeV. Experimental data are given on energy and angular responses of dosemeters with different combinations of aluminium and plastic filters. Li...

  12. Performance test of dosimetric services in the EU member states and Switzerland for the routine assessment of individual doses (photon, beta and neutron)

    DEFF Research Database (Denmark)

    Bordy, J.M.; Stadtmann, H.; Ambrosi, P.

    2000-01-01

    The results are given of a consolidated performance test for whole-body, and extremity personal dosemeters broadly representative of those in use in the EU member states and Switzerland. Beta, photon and neutron personal dosemeters were used to assess the routine services ability to determine...

  13. Albedo Neutron Dosimetry in a Deep Geological Disposal Repository for High-Level Nuclear Waste.

    Science.gov (United States)

    Pang, Bo; Becker, Frank

    2016-06-24

    Albedo neutron dosemeter is the German official personal neutron dosemeter in mixed radiation fields where neutrons contribute to personal dose. In deep geological repositories for high-level nuclear waste, where neutrons can dominate the radiation field, it is of interest to investigate the performance of albedo neutron dosemeter in such facilities. In this study, the deep geological repository is represented by a shielding cask loaded with spent nuclear fuel placed inside a rock salt emplacement drift. Due to the backscattering of neutrons in the drift, issues concerning calibration of the dosemeter arise. Field-specific calibration of the albedo neutron dosemeter was hence performed with Monte Carlo simulations. In order to assess the applicability of the albedo neutron dosemeter in a deep geological repository over a long time scale, spent nuclear fuel with different ages of 50, 100 and 500 years were investigated. It was found out, that the neutron radiation field in a deep geological repository can be assigned to the application area 'N1' of the albedo neutron dosemeter, which is typical in reactors and accelerators with heavy shielding.

  14. Eurados trial performance test for photon dosimetry

    DEFF Research Database (Denmark)

    Stadtmann, H.; Bordy, J.M.; Ambrosi, P.

    2001-01-01

    Within the framework of the EURADOS Action entitled Harmonisation and Dosimetric Quality Assurance in Individual Monitoring for External Radiation, trial performance tests for whole-body and extremity personal dosemeters were carried out. Photon, beta and neutron dosemeters were considered....... This paper summarises the results of the whole-body photon dosemeter test. Twenty-six dosimetry services from all EU Member States and Switzerland participated. Twelve different radiation fields were used to simulate various workplace irradiation fields. Dose values from 0.4 mSv to 80 mSv were chosen. From...

  15. Performance test of dosimetric services in the EU member states and Switzerland for the routine assessment of individual doses (photon, beta and neutron)

    DEFF Research Database (Denmark)

    Bordy, J.M.; Stadtmann, H.; Ambrosi, P.;

    2000-01-01

    of the dosimetry of routine services. It was assumed that each service would have already done a type test before performing routine dosimetry: the radiation fields were chosen to simulate, as far as possible, workplace radiation fields by mixing combining energies and incident angles. The results of photon...... dosemeters were good for all fields except for R-F. Beta test results showed that many types of dosemeter were not able accurately to determine personal dose equivalent when large incident angles and low energies were encountered. Neutron dosimetry, results were very dependent on the dosemeter type...

  16. Low temperature dosimetry in LiF: Mg, Cu, P and CaSO{sub 4}: Dy doped crystals; Dosimetria de baja temperatura en cristales dopados LiF: Mg, Cu, P y CaSO{sub 4}: Dy

    Energy Technology Data Exchange (ETDEWEB)

    Cruz Z, E.; Ramos B, S.; Negron M, A.; Rivera, T. [Instituto de Ciencias Nucleares, UNAM, A.P. 70-543, 04510 Mexico D.F. (Mexico)

    2000-07-01

    It is presented a behavior study of LiF solid dosemeters doped with Mg, Cu and P also polycrystalline samples of CaSO{sub 4} with Dy sinterized in laboratory, both of them were subjected at low temperature. In order to analyse linear behavior to the dose of these dosemeters, it was used thermoluminescence. These materials were exposed to gamma radiation coming from a Co-60 source. The samples were irradiated at dose rates 1.08 {+-} 0.01 Gy/min at liquid nitrogen temperature (LNT) and also the response of dosemeters are compared at ambient temperature and LNT. (Author)

  17. Preliminary study on field buses for the control system of the high voltage of the ATLAS hadronic calorimeter; Etude preliminaire d`un reseau de terrain pour le systeme de controle des hautes tensions du calorimetre hadronique d`Atlas

    Energy Technology Data Exchange (ETDEWEB)

    Drevet, F.; Chadelas, R.; Montarou, G.

    1996-12-31

    We present here after a preliminary study on field buses for the control system of the high voltage of the photomultipliers of the TILECAL calorimeter. After some generalities, different commercial buses are reviewed (CAN, ARCET, WorldFIP, Profibus and LonWorks). The Profibus and LonWorks solution are more extensively studies as a possible solution for the high voltage system of the TILE hadronic calorimeter. (authors).

  18. Testing and calibration through laser radiation and muon beams of the hadron calorimeter in ATLAS detector; Controle et etalonnage par lumiere laser et par faisceaux de muons du calorimetre hadronique a tuiles scintillantes d'ATLAS

    Energy Technology Data Exchange (ETDEWEB)

    Garde, V

    2003-10-15

    This study is dedicated to the calibration of the hadronic calorimeter (Tilecal) of the ATLAS detector. This detector will be installed on the LHC collider at CERN. The first data will be taken in 2007. This thesis is divided in two parts. The first part is dedicated to the study of the LASER system. A prototype of the final system was studied. It was shown that the stability and the linearity of this prototype are conform to the specification. Several studies were devoted to measurements which can be done on the Tilecal: The relative gain can be calculated and gives the stability of the Tilecal with a resolution of 0.35 %. The number of photoelectrons per charge unit has been calculated. The linearity was checked for a normal range of functioning and was corrected for the functioning at high charge. In both cases it was shown that the non-linearity was smaller than 0.5 %. The second study is devoted to muons beams in test beam periods. These results are used to find a calibration constant. Several problems which come from the difference of size cells are not totally solved. But the resolution of the calibration constant found by this method cannot exceed 2.3%. (author)

  19. Influencia de las dimensiones y de la disposición térmica en la respuesta de termopilas usadas como sensores en calorimetría de conducción de calor

    Directory of Open Access Journals (Sweden)

    Liliana Giraldo G.

    2010-09-01

    Full Text Available Se determina la sensibilidad y estabilidad para tres tipos de termopilas, con diferentes dimensiones, pero con igual número de termocuplas. Se obtienen sensibilidades que crecen a medida que aumenta el área de cubrimiento de la superficie que genera el efecto térmico: 0,022 VW-1, para la termopila con área de 1764 mm2; de 0,011 VW-1 para las termopilas con un área de 1024 mm', y para las termopilas con área de 882 mm2 se presenta la menor sensibilidad, de 0,009 VW2. La estabilidad permanece constante para todas las termopilas sin importar sus dimensiones.

  20. Test beam results on Atlas electromagnetic end-cap calorimeter: Electrons-jets separation; Resultats des tests en faisceau sur les bouchons du calorimetre electromagnetique d'ATLAS - separation electrons-jets

    Energy Technology Data Exchange (ETDEWEB)

    Serfon, C

    2005-05-15

    ATLAS is one of the four experiments being built on the future proton-proton collider at CERN: the LHC. This experiment has a large physics program, from Standard Model to new physics. The search for the Higgs boson in two photons or in four leptons, or the search of Z' or W' needs a good energy resolution for the electromagnetic calorimeter. This thesis describes the beam tests performed on three modules of the electromagnetic end cap calorimeter. A 0.6% non-uniformity, and a 0.7% energy resolution global constant term (dominant at high energy) has been obtained. Moreover, a study on the separation between electrons and jets is also performed. This study shows that a jets rejection factor of 10{sup 5} can be obtained keeping an electron efficiency better than 78%. (author)

  1. Rotating electrical machines, pt.2: Methods for determining losses and efficiency of rotating electrical machinery form tests (excl. machines for traction vehicles), 1st suppl. Measurement of losses by the calorimetric method

    CERN Document Server

    International Electrotechnical Commission. Geneva

    1974-01-01

    Describes methods for measuring the efficiency of electrical rotating machines either by determining total losses on load or by determination of the segregated losses for air and water cooling mediums. Applies to large generators but may be used for other machines.

  2. Construction of a hadronic calorimeter prototype for the future CERN LHC high energy accelerator; Construction d`un prototype de calorimetre hadronique pour le futur collisionneur a haute energie LHC du CERN

    Energy Technology Data Exchange (ETDEWEB)

    Rival, F.

    1994-06-01

    The study of fragment-fragment correlations at small relative momentum can give informations on the space and time extend of the emitting source, and on the nuclear density, which is one of the variables used in the equation of state. This analysis shows the experimental results obtained with the FOPI detector at GSI Darmstadt, for Au + Au central collisions at 150 and 400 A.MeV. These results are the first studies at such high energies and for heavy systems. Two fragments correlation functions are compared with theoretical calculations of D.H. Boal, including the size of the source as a parameter. We must take into account effects of experimental biases (namely the relative momentum resolution) on the theoretical correlation function, in order to make a comparison with experimental results. The extracted experimental radii correspond to the final phase of the expansion, and the obtained densities are smaller than normal density of nuclear matter. In the final state of the interaction, intermediate mass fragments and their excited states are observed. We note a shift of these excited states at 400 A.MeV, which can be explained by the detector effects. We observe a weak sensibility of the source size versus the centrality of the collision. That can be explained either by a mixing of sources, or by the observation of a source at the end of expansion whose the radius is quite independent of the initial centrality. Energetic particles correspond to smaller size of the source, which can be explained as a higher compression, or as a different stage of the collision. We give some prospectives for the future experiments at GSI-Darmstadt. (author). 116 refs.

  3. Synthesis and characterization of cement slurries additives with epoxy resins - kinetics, thermodynamic and calorimetric analysis; Sintese e caracterizacao de pastas de cimento aditivadas com resinas epoxi - analises cineticas, termodinamicas e calorimetricas

    Energy Technology Data Exchange (ETDEWEB)

    Tavares, A.M.G.; Andrade Junior, M.A.S.; Cestari, A.R.; Vieira, E.F.S., E-mail: macleybiane@gmail.co [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil)

    2010-07-01

    Cement has been used in the world, presenting a wide versatility. However, due to its chemical nature, it is subject to several types of chemical damages, especially for agents of acidic nature. With the purpose of increase its life-time, new cement slurries have been modified with the addition of specific additives. The objective of this work is to modify cement slurries with epoxy resins, which promote higher resistance of those materials in relation to acid attacks. Three cement slurries were synthesized with epoxy resins and a standard slurries, which was composed by cement and water. After 30 days of hydration, the samples were characterized by XDR, FTIR and thermal analysis (TG and DSC). The hydration processes of the cement slurries were studied by heat-conduction microcalorimetry. A kinetic study of HCl interaction with the new slurries were performed by the batch methodology at 25, 35, 45 e 55 deg C. It was verified that the addition of the polymers delayed the processes of hydration of the slurries, decreasing the flow of heat released as a function of the amount of added resin and, increased the resistance of those slurries to the acid attack. (author)

  4. Different Effects of Long- and Short-Chain Ceramides on the Gel-Fluid and Lamellar-Hexagonal Transitions of Phospholipids: A Calorimetric, NMR, and X-Ray Diffraction Study

    Science.gov (United States)

    Sot, Jesús; Aranda, Francisco J.; Collado, M.-Isabel; Goñi, Félix M.; Alonso, Alicia

    2005-01-01

    The effects on dielaidoylphosphatidylethanolamine (DEPE) bilayers of ceramides containing different N-acyl chains have been studied by differential scanning calorimetry small angle x-ray diffraction and 31P-NMR spectroscopy. N-palmitoyl (Cer16), N-hexanoyl (Cer6), and N-acetyl (Cer2) sphingosines have been used. Both the gel-fluid and the lamellar-inverted hexagonal transitions of DEPE have been examined in the presence of the various ceramides in the 0-25 mol % concentration range. Pure hydrated ceramides exhibit cooperative endothermic order-disorder transitions at 93°C (Cer16), 60°C (Cer6), and 54°C (Cer2). In DEPE bilayers, Cer16 does not mix with the phospholipid in the gel phase, giving rise to high-melting ceramide-rich domains. Cer16 favors the lamellar-hexagonal transition of DEPE, decreasing the transition temperature. Cer2, on the other hand, is soluble in the gel phase of DEPE, decreasing the gel-fluid and increasing the lamellar-hexagonal transition temperatures, thus effectively stabilizing the lamellar fluid phase. In addition, Cer2 was peculiar in that no equilibrium could be reached for the Cer2-DEPE mixture above 60°C, the lamellar-hexagonal transition shifting with time to temperatures beyond the instrumental range. The properties of Cer6 are intermediate between those of the other two, this ceramide decreasing both the gel-fluid and lamellar-hexagonal transition temperatures. Temperature-composition diagrams have been constructed for the mixtures of DEPE with each of the three ceramides. The different behavior of the long- and short-chain ceramides can be rationalized in terms of their different molecular geometries, Cer16 favoring negative curvature in the monolayers, thus inverted phases, and the opposite being true of the micelle-forming Cer2. These differences may be at the origin of the different physiological effects that are sometimes observed for the long- and short-chain ceramides. PMID:15695626

  5. Calorimetric Analysis of Antifreeze Activity and the Absorption-inhibition Mechanism of Antifreeze Protein%抗冻蛋白活性的差示扫描量热测定及其吸附-抑制机制

    Institute of Scientific and Technical Information of China (English)

    任禾盛; 许娜飞; 华泽钊

    2004-01-01

    用差示扫描量热技术(DSC)测定了从黄粉虫(Tenebrio molitor)幼虫体内提取的抗冻蛋白(AFP)的活性,结果表明AFP活性随其浓度的增加及初始冰晶量的减少而增大,这与AFP对冰晶的吸附-抑制机制相一致.

  6. The construction of the graphite calorimeter GR9 at LNE-LNHB (geometrical and technical consideration); Construction du calorimetre en graphite GR9 au LNE-LNHB (caracteristiques techniques et geometriques)

    Energy Technology Data Exchange (ETDEWEB)

    Ostrowsky, A.; Daures, J

    2008-07-01

    Calorimetry is the most direct dosimetric technique to reach absorbed dose. A calorimeter gives direct access to the energy imparted to matter by ionizing radiation per mass unit by measuring the heat quantity Q produced under irradiation in its sensitive element which is thermally insulated. Graphite was chosen as construction material because all the energy imparted to graphite by ionizing radiation is converted into heat. Thermistors are used for temperature measurements as well as for the electrical heating of the different bodies of the calorimeter. The construction of a calorimeter is the result of a compromise between dosimetric requirements and mechanical constraints. The difficulties encountered are examined and the solutions chosen are detailed. All technical data are gathered in this document. The aim is to provide a practical operative instruction and guidance document, which can help interested laboratories in designing such an instrument. The electrical and thermal tests have shown a good behaviour of the GR9 calorimeter.

  7. Characterisation and exploitation of Atlas electromagnetic calorimeter performances: muons study and timing resolution use; Caracterisation et exploitation des performances du calorimetre electromagneique d'Atlas: etude des muons et mise a profit de la resolution en temps

    Energy Technology Data Exchange (ETDEWEB)

    Camard, A

    2004-10-01

    The ATLAS detector in LHC involves electromagnetic calorimeters. The purpose of this work is to study the calorimeter response to the muons contaminating the beam used to test the different modules of ATLAS. We have showed how data analysis from the testing beam can be used to assure that the required performance for the study of the detector response to muons provides a complementary diagnostic tool for electrons. We have taken part into the design of a testing bench aimed at assessing the performance of the receiver circuit for timing and triggering signals. We have developed, in the framework of a quick simulation of ATLAS, a tool for the reconstruction in a simple and fast manner of the localization of the main event vertex by using the measurement of the arrival time of particles with ATLAS's calorimeters. It is likely that this tool will be fully used during the starting phase of the ATLAS experiment because it is easier to operate it quickly and is less sensitive to the background noise than traditional tools based on charged-particle tracks recognition inside the detector.

  8. Qualification procedure of the electromagnetic calorimeter of the ATLAS detector; Conception et mise au point de la procedure de qualification du calorimetre electromagnetique a argon liquide du detecteur ATLAS

    Energy Technology Data Exchange (ETDEWEB)

    Massol, N

    2000-04-19

    LHC is the next collider based at CERN in Europe. The purpose of this machine is the Higgs boson and SUSY particles search. The detectors must have an excellent electromagnetic calorimetry to measure electron and photon energy. To maximize the signal to noise ratio for a low mass Higgs, it is fundamental to obtain a constant term as small as possible. LAPP is participating in the construction of the liquid argon electromagnetic calorimeter of the ATLAS collaboration. This technology is well adapted to the LHC experimental conditions. A systematic procedure to qualify the modules of this detector is an essential step to guarantee a 0,7% constant term, which is the collaboration objective. The procedure detailed in this thesis consists of quality monitoring during mechanical assembly and of a set of electrical tests such as electrical continuity, cell and cross-talk capacitance measurement, and high-voltage behaviour. For the whole test, it has been necessary to develop dedicated electronic cards, to develop measurement methods, and the whole operation software. Making the procedure automatic will guarantee the quality of each module during assembly, cabling, and test in liquid argon. (author)

  9. Estudio del gasto energético en una población adulta sana española: calorimetría indirecta "versus" modelos predictivos: propuesta de una nueva ecuación de estimación

    OpenAIRE

    Cruz Marcos, Sandra de la

    2015-01-01

    El organismo humano es un sistema termodinámico que necesita energía para mantener sus funciones y la actividad física habitual. Del equilibrio entre la energía ingerida (alimentación) y la gastada (mantenimiento de la vida, actividad...) depende la estabilidad de las reservas corporales y, en consecuencia, el mantenimiento del peso. Conseguir el equilibrio energético es el principal objetivo de las actuales políticas de salud para la población de los países occidentales.Uno de los “brazos” d...

  10. Study and optimization of the performances of the CMS electromagnetic calorimeter for the physics at LHC; Etude et optimisation des performances du calorimetre electromagnetique de l'experience CMS pour la physique au LHC

    Energy Technology Data Exchange (ETDEWEB)

    Descamps, J

    2007-07-15

    The CMS experiment (Compact Muon Solenoid) is one of the two multi-purpose experiments of the proton-proton collider LHC (Large Hadron Collider). One of the main goals of CMS is the search for the Higgs boson. The collaboration has chosen an electromagnetic calorimeter made of about 75000 scintillating lead tungstate crystals PbWO{sub 4}, at the same time fast, radiation hard, and extremely precise, especially in the energy range for the Higgs boson search, in the channel where it decays in 2 photons. The five first chapters of this thesis present the LHC, the CMS detector and notably the electromagnetic calorimeter (ECAL). The sixth chapter presents a test beam analysis realized in 2004 at CERN with an electron beam of different energies (20-250 GeV) incident on a part (1/36) of the calorimeter barrel called super-module. A study of the energy measurement variation within 9 (3*3) and 25 (5*5) crystals matrices as function of the impact position of the initial electron was done to infer a correction method of the energy measured as function of different parameters. This method has improved very significantly the energy resolution of the calorimeter in the test beam configuration. The last chapter of this thesis presents an application of this correction method for the electrons and photons in the full simulation chain of CMS. The energy reconstruction of photons and electrons is more complicated compared to the test beam case, because of an important amount of matter in front of the calorimeter and of the strong magnetic field in the central part of the CMS detector. The photons have a non negligible probability to convert into an electron-positron pair before the calorimeter, while the electrons (and positrons), whose trajectory is bent in the transverse plan, lose energy in the matter and can emit a random number of Bremsstrahlung photons. A reconstruction algorithm of the electrons and photons energy has been developed to take into account this issue and to apply the correction method studied in the test beam. This new algorithmic approach for an optimal reconstruction of the electromagnetic particles in the ECAL has been tested with physics events Z{sup 0} {yields} e{sup +}e{sup -}, H {yields} Z{sup 0}Z{sup 0} {yields} e{sup +}e{sup -}e{sup +}e{sup -} and H {yields} {gamma}{gamma}, simulated with a LHC luminosity of 10{sup 33} cm{sup -2}s{sup -1}. (author)

  11. Contribution to the study of the readout of the electromagnetic calorimeter crystals in the CMS experiment at LHC; Contribution a l`etude de la lecture des cristaux du calorimetre electromagnetique de l`experience CMS au LHC

    Energy Technology Data Exchange (ETDEWEB)

    Martin, Franck [Universite Claude Bernard Lyon-1, 69 - Lyon (France)

    1998-07-03

    The search for neutral Higgs boson through its decay into two photons provides a very promising signal for a mass between 90 and 150 GeV. It requires an electromagnetic calorimeter of very high resolution. The CMS (Compact Muon Solenoid) electromagnetic calorimeter must be made up of more than 80,000 lead tungstate crystals. In the central part (the barrel), the scintillation light readout is performed by means of avalanche photodiodes, a silicon photo-sensor with internal gain which is a relative novelty in high energy physics. Concerning the readout electronics, the energy available in the centre-of-mass (14 TeV) as well as the collision frequency (40 MHz) of LHC impose constraints with respect to the signal treatment up to the acquisition. The retained solution consists in pairing two avalanche photodiodes, the parameters of which (gain, temperature dependence, dark current, etc) must be controlled, and coupling them to a low noise preamplifier of high dynamical range (5 MeV - 2 TeV) followed by a four-slopes linear compressor and a analog-digital sampling converter of 12 bits, 40 MHz. The thesis presents the prototypes of different electromagnetic calorimeters tested in the high energy beam. An energy resolution of 0.6% at 100 GeV was obtained with a conventional readout circuitry, while the integrated associated circuits were radiation resistant 73 refs., 100 figs., 19 tabs.

  12. Diseño de un prototipo para la medición de flujo de calor mediante calorimetría directa usando sensado por variación de temperatura

    Directory of Open Access Journals (Sweden)

    Oscar Reyes

    2007-01-01

    Full Text Available Este artículo muestra las principales características del módulo para el monitoreo de flujo de calor mediante sensado de temperatura en pacientes que se encuentran en estado post-operatorio, como planteamiento de solución a los inconvenientes y falencias que presentan los actuales métodos de seguimiento del consumo de calorías. Este proyecto es un prototipo que se construye con el fin de guiar estudios posteriores sobre el tema, por lo tanto, las pruebas de calibración de flujo de calor y temperatura no se realizarán en seres humanos sino en generadores de calor controlados.

  13. Consolidação de pastas cimentícias contendo policarboxilatos um estudo calorimétrico e reológico Consolidation of policarboxilates containing cement pastes: a calorimetric and rheological study

    Directory of Open Access Journals (Sweden)

    J. S. Lyra

    2012-06-01

    Full Text Available A utilização de policarboxilatos em concretos é pratica comum no setor de construção civil, visto que esses aditivos auxiliam na dispersão das partículas, possibilitam a redução da quantidade de água de amassamento, permitem melhorar as propriedades no estado fresco e endurecido. Entretanto, é sabido que apesar de possibilitar a produção de concretos de alto desempenho, a presença dos policarboxilatos pode afetar a cinética de reação do cimento e de aglomeração das partículas durante a consolidação. Ao mesmo tempo em que o fluxo de calor liberado durante a reação pode ser quantificado em calorímetros de condução isotérmica, a aglomeração pode também, ser acompanhada a partir de ensaios reológicos oscilatórios com controle de freqüência e deformação. Os resultados obtidos separadamente, quando avaliados conjuntamente podem melhor ilustrar o efeito da presença dos aditivos durante o endurecimento do cimento, abordagem que é apresentada como objetivo principal deste trabalho. Para tanto, pastas cimentícias formuladas com CPIIE-32 foram avaliadas em função da variação do teor de policarboxilato e os resultados mostraram que a taxa de consolidação(promovida pela ação conjunta da reação química e da aglomeraçãoapresenta relação direta com o teor do aditivo.Polycarboxylates are frequently used as additives to concrete production in the construction industry. The additive increases the dispersion of the particles, reduces the amount of water, and improves the mechanical properties of concrete in the fresh and settled state. However, although it is well known that polycarboxylate additives enable the production of high performance concretes, their presence may affect on both kinetics and thermodynamics of cement's particles during hydration reaction through consolidation. While the flow of heat released by the hydration reaction can be measured by isothermal calorimetry, concrete consolidation can be measured by oscillatory rheometry. The results obtained separately, when considered together could better illustrate the effect of the additives on the cement setting. This was the main subject in this work. Therefore, cement pastes containing commercial CPIIE-32 were evaluated by simultaneous heat of hydration and rheological measurements with different amounts of polycarboxylate. The results obtained separately, when considered together can better illustrate the effect of additive content during the hardening, and this approach is presented as a main objective of this work. For this, cement pastes formulated with CPII-32 were evaluated according to the variation of the content of polycarboxylate and the results showed that the rate of consolidation(promoted by the joint action of the chemical reaction and particle agglomerationhas direct relation with the level of the additive.

  14. Study of the optical monitoring system of the scintillating crystal involved in the electromagnetic calorimeter of CMS experiment; Etude du systeme de suivi optique des cristaux scintillants du calorimetre electromagnetique de l`experience CMS

    Energy Technology Data Exchange (ETDEWEB)

    Geleoc, M

    1998-09-04

    The prospect of the experimental discovery of the Higgs boson is one of the motivations to build the large hadron collider (LHC). Proton beams will collide and the emitted particles will be detected by ATLAS and CMS equipment. In each detector the electromagnetic calorimeter will allow the characterisation of the 2 photons coming from one of the disintegration channels of the Higgs boson. CMS collaboration has chosen an homogeneous calorimeter fitted with PbWO{sub 4} crystals. Each crystal with its photodetector and its electronic device forms one detection channel. The resolution of the detection channels should not deteriorate all along the operating time. The optical monitoring system of the crystals logs then controls the response of each detection channel in order to allow an accurate calibration of the calorimeter. The optical properties, the resistance to irradiation of PbWO{sub 4} crystals and the modelling of light collection are investigated in this work. The description of the different components of the optical monitoring system highlights the technical difficulties we had to challenge. An experimental testing bench has been set up to study the coupling between the scintillation signal and the signal that feeds the monitoring system, this coupling has been studied under irradiation in the conditions of CMS operating. (A.C.) 94 refs.

  15. Twist, tilt, and orientational order at the nematic to twist-bend nematic phase transition of 1″,9″-bis(4-cyanobiphenyl-4'-yl) nonane: A dielectric, 2H NMR, and calorimetric study

    Science.gov (United States)

    Robles-Hernández, Beatriz; Sebastián, Nerea; de la Fuente, M. Rosario; López, David O.; Diez-Berart, Sergio; Salud, Josep; Ros, M. Blanca; Dunmur, David A.; Luckhurst, Geoffrey R.; Timimi, Bakir A.

    2015-12-01

    The nature of the nematic-nematic phase transition in the liquid crystal dimer 1″,9″-bis(4-cyanobiphenyl-4'-yl) nonane (CB9CB) has been investigated using techniques of calorimetry, dynamic dielectric response measurements, and 2H NMR spectroscopy. The experimental results for CB9CB show that, like the shorter homologue CB7CB, the studied material exhibits a normal nematic phase, which on cooling undergoes a transition to the twist-bend nematic phase (NTB), a uniaxial nematic phase, promoted by the average bent molecular shape, in which the director tilts and precesses describing a conical helix. Modulated differential scanning calorimetry has been used to analyze the nature of the NTB-N phase transition, which is found to be weakly first order, but close to tricritical. Additionally broadband dielectric spectroscopy and 2H magnetic resonance studies have revealed information on the structural characteristics of the recently discovered twist-bend nematic phase. Analysis of the dynamic dielectric response in both nematic phases has provided an estimate of the conical angle of the heliconical structure for the NTB phase. Capacitance measurements of the electric-field realignment of the director in initially planar aligned cells have yielded values for the splay and bend elastic constants in the high temperature nematic phase. The bend elastic constant is small and decreases with decreasing temperature as the twist-bend phase is approached. This behavior is expected theoretically and has been observed in materials that form the twist-bend nematic phase. 2H NMR measurements characterize the chiral helical twist identified in the twist-bend nematic phase and also allow the determination of the temperature dependence of the conical angle and the orientational order parameter with respect to the director.

  16. Test of the little Higgs model in Atlas at LHC: simulation of the digitization of the electromagnetic calorimeter; Test du modele du petit Higgs dans ATLAS au LHC: simulation de la numerisation du calorimetre electromagnetique

    Energy Technology Data Exchange (ETDEWEB)

    Lechowski, M

    2005-04-15

    LHC is a proton-proton collider with an energy of 14 TeV in the center of mass, which will start operating in 2007 at CERN. Two of its experiments, ATLAS, and CMS, will search and study in particular the Higgs boson, Supersymmetry and other new physics. This thesis was about two aspects of the ATLAS experiment. On one hand the simulation of the liquid Argon electromagnetic calorimeter, with the emulation of the electronic chain in charge of the digitization of the signal and also the evaluation of the electronic noise and the pile-up noise (coming from minimum bias events of inelastic collisions at LHC). These two points have been validated by the analysis of the data taken during beam tests in 2002 and 2004. On the other hand, a physics study concerning the Little Higgs model. This recent model solves the hierarchy problem of the Standard Model, in introducing new heavy particles to cancel quadratic divergences arising in the calculation of the Higgs boson mass. These new particles, with a mass about the TeV/c{sup 2}, are a heavy quark top, heavy gauge bosons Z{sub H}, W{sub H} and A{sub H}, and a heavy Higgs boson triplet. The physics study dealt with the characteristic decays of the model, Z{sub H} in Z + H and W{sub H} in W + H, with a Higgs mass either at 120 GeV/c{sup 2} decaying in two photons or at 200 GeV/c{sup 2} decaying in ZZ or WW. Results show that in both cases, for 300 fb{sup -1} (3 years at high luminosity), an observation of the signal at 5 {sigma} for Z{sub H} et W{sub H} masses less than 2 TeV/c{sup 2} is possible, covering a large part of the parameter space. (author)

  17. Calibration of the Atlas electromagnetic calorimeter. Search for the Higgs boson in its invisible decays; Etalonnage du calorimetre electromagnetique d'ATLAS. Recherche du boson de Higgs dans ses desintegrations invisibles

    Energy Technology Data Exchange (ETDEWEB)

    Neukermans, L

    2002-05-01

    The most promising channels for an intermediate mass Higgs boson discovery at LHC are leptonic and photonic decays. Therefore, a good uniformity of response of the electromagnetic calorimeter is required to reach the 0.7% constant term needed. This thesis deals with the absolute calibration of this detector. An electrical description of the calibration system, the detector and its read-out chain has been made for a better comprehension of the signal pulse shapes. A method, using a convolution of the calibration waveforms, has been developed to predict physics response, leading to absolute calibration. The level of accuracy obtained allows to reach the 0.3% contribution to the constant term required. Test beam analysis of a prototype module showed the performance of the electromagnetic calorimeter in terms of local resolution and linearity. A uniformity study has been made, leading to a 0.8% dispersion on a {delta}{eta} x {delta}{phi} = 1.2 x 0.75 area. In a second part, the observability of an invisible Higgs boson produced via weak boson fusion at the LHC is presented. A level 1 trigger strategy for this purely jet and missing E{sub T} final states is discussed. A method to measure the level of background using physics events is presented. This analysis shows that an invisible branching ratio of 25% could be reached at 95% CL with only 30 fb{sup -1} for a Higgs boson mass of 120 GeV/c{sup 2}. (author)

  18. Study of the leakage current of clinical dosimeters for teletherapy; Estudo da corrente de fuga de dosimetros clinicos para teleterapia

    Energy Technology Data Exchange (ETDEWEB)

    Damatto, Willian B.; Santos, Gelson P.; Potiens, Maria da Penha A.; Caldas, Linda V.E.; Vivolo, Vitor, E-mail: wbdamatto@ipen.b, E-mail: gpsantos@ipen.b, E-mail: mppalbu@ipen.b, E-mail: lcaldas@ipen.b, E-mail: vivolo@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2009-07-01

    This work demonstrates the importance of quality control of clinical dosemeters and therefore the equipment for radiotherapy treatment, exhibiting the necessary care related to answers and sensibilities and the possible defects of the clinical assembly

  19. An automated neutron dosimetry system based on the chemical etch of CR-39

    Energy Technology Data Exchange (ETDEWEB)

    Harvey, J.R.; French, A.P.; Jackson, M. [Ministry of Defence, Gosport (United Kingdom). Defence Radiological Protection Service; Renouf, M.C. [BICRON NE, Reading (United Kingdom); Weeks, A.R. [Magnox Electric plca, Berkeley (United Kingdom)

    1997-09-01

    The dosimetric characteristics of two types of personal neutron dosemeter have recently been extensively assessed. The effects of exposure to various extreme environments have also been studied. Both types of dosemeter utilise chemically etched elements which are read in an automated reader, the Autoscan 60, which uses an edge illumination system to increase the pit image size. One type of dosemeter contains three elements in a pyramid structure. The other uses one or two elements in a planar structure. The results indicate that both types of dosemeter can be used to assess accurately the personal dose from neutrons in a range of harsh environments. Formal approval for the operational use of the system has been received. (author).

  20. Official personnel dosimetry for medical personnel; Amtliche Personendosimetrie fuer Medizin-Personal

    Energy Technology Data Exchange (ETDEWEB)

    Hupe, Oliver [Physikalisch-Technische Bundesanstalt (PTB), Braunschweig (Germany). Arbeitsgruppe ' Photonendosimetrie'

    2013-06-15

    After a description of the quality assurance of dosemeters by construction testing and calibration practical personnel dosimetry is considered. In this connection legally fixed dose limits are presented, which are based on the EURATOM directive 96/29. (HSI)

  1. Manufacture of Single ~(60)Co Source Irradiation Facility

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Reference radiation filed produced by isotope source is necessary for calibration of radiation dose meter. According to the GB/T 12162.1-2002 "X and gamma reference radiation for calibrating dosemeters and doserate meters and for determining

  2. Intercomparison of Environmental Nuclear Radiation Measuring

    Institute of Scientific and Technical Information of China (English)

    GAO; Fei; NI; Ning; HOU; Jin-bing; SONG; Ming-zhe

    2015-01-01

    In 2015,Radiation Metrology Division of China Institute of Atomic Energy organized an environmental monitoring of nuclear radiation measuring intercomparison,and 9laboratories attended.The intercomparison included environmental level dosemeters and protection level

  3. Dosimetry in nuclear power plants; Dosimetria en centrales nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Lastra B, J. A. [CFE, Central Laguna Verde, Km. 42.5 Carretera Cardel-Nautla, Veracruz (Mexico)

    2008-12-15

    To control the occupationally exposed personnel dose working at the Laguna Verde nuclear power plant, two types of dosemeters are used, the thermoluminescent (TLD) which is processed monthly, and the direct reading dosemeter that is electronic and works as daily control of personal dose. In the case of the electronic dosemeters of direct reading conventional, the readings and dose automatic registers and the user identity to which he was assigned to each dosemeter was to carry out the restricted area exit. In activities where the ionizing radiation sources are not fully characterized, it is necessary to relocate the personal dosemeter or assigned auxiliary dosemeters (TLDs and electronics) to determine the dose received by the user to both whole body and in any specific area of it. In jobs more complicated are used a tele dosimetry system where the radiation protection technician can be monitoring the user dose to remote control, the data transmission is by radio. The dosimetry activities are documented in procedures that include dosemeter inventories realization, the equipment and dosemeters calibration, the dosimetry quality control and the discrepancies investigation between the direct reading and TLD systems. TLD dosimetry to have technical expertise in direct and indirect dosimetry and two technicians in TLD dosimetry; electronic dosimetry to have 4 calibration technicians. For the electronic dosemeters are based on a calibrator source of Cesium-137. TLD dosemeters to have an automatic radiator, an automatic reader which can read up to 100 TLD dosemeters per hour and a semiautomatic reader. To keep the equipment under a quality process was development a process of initial entry into service and carried out a periodic verification of the heating cycles. It also has a maintenance contract for the equipment directly with the manufacturer to ensure their proper functioning. The vision in perspective of the dosimetry services of Laguna Verde nuclear power plant

  4. Développement d'un capteur CMOS intégré pour un futur dosimètre électronique personnel de neutrons

    OpenAIRE

    Zhang, Ying

    2012-01-01

    This thesis presents the development of CMOS sensors for a future neutron sensitive electronic individual dosemeter. Active dosemeters, exist but do not yet give results as satisfactory as passive devices, being however, mandatory for workers in addition to the passive dosimetry since 1995 (IEC 1323). The RaMsEs group in the laboratory IPHC is exploring a new compact device based on CMOS sensors for operational neutron dosimetry. In this thesis, a dedicated sensor, AlphaRad-2, with low noise ...

  5. Coincidence in the dose estimation in a OEP by different methods; Coincidencia en la estimacion de dosis en un POE por diferentes metodos

    Energy Technology Data Exchange (ETDEWEB)

    Guerrero C, C.; Arceo M, C.; Brena V, M. [ININ, Km. 36.5, Carretera Mexico-Toluca, 52750 La Marquesa, Estado de Mexico (Mexico)]. e-mail: cgc@nuclear.inin.mx

    2007-07-01

    The case of an apparent overexposure to radiation according to that indicated for the thermoluminescent dosemeter 81.59 mSv (TLD) of a occupationally exposed hard-working (POE), for that was practiced the study of biological dosimetry. The estimated dose was 0.12 Gy with which was proven the marked dose registration by the TLD dosemeter. It was concluded that both doses are the same ones. (Author)

  6. Production of thermoluminescent dosemeters based on MgB{sub 4}O{sub 7}: Dy and MgB{sub 4}O{sub 7}: Tm; Producao de dosimetros termoluminescentes a base de MgB{sub 4}O{sub 7}: Dy e MgB{sub 4}O{sub 7}: Tm

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Luiza Freire de; Souza, Divanizia N., E-mail: luizaf25@hotmail.com, E-mail: divanizi@ufs.br [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil). Programa de Pos-Graduacao em Fisica

    2013-07-01

    The thermoluminescent dosimetry (TL) is a well-established technique for the detection of ionizing radiation in hospitals, clinics, and industrial establishments where there is the need to quantify the radiation. For this practice is require the use phosphors which are sensitive to radiation. Some phosphors are already commonly used in this practice, for example, TLD-100 (LiF: Mg, Ti), CaSO{sub 4}:Tm and CaSO{sub 4}:Dy. A compound that was most recently introduced in dosimetry and has many advantageous features to detect neutrons, electrons and gamma is the magnesium tetraborate (MgB{sub 4}O{sub 7}), but the undoped material is not good for dosimetry, since signal does not show satisfactory thermoluminescence. The present work presents the analysis of the compound MgB{sub 4}O{sub 7} when doped with rare earth elements, thulium (Tm) and dysprosium (Dy). The production of MgB{sub 4}O{sub 7}: Dy and MgB{sub 4}O{sub 7}: Tm occurred under acidic conditions. Following the process of crystal growth, several tests were made on phosphors produced to verify the quality of materials as TL dosimeter. Initially, was made the identification of the crystalline phases found in the material, using the technique of X-ray diffractometry, and then were evaluated and compared the TL emission curves of the crystals with two different types of dopants, to this, the samples were irradiated with different radiation sources: {sup 137}Cs (0,66 MeV), {sup 60}Co (1.25 MeV) and X-rays (0.41 MeV) and based on the results was evaluated the energy dependence of phosphors. Another characteristic analyzed, was the decay of TL signal for the material (fading). The results show that the material can be an excellent TL dosimeter when doped with rare earth elements Dy and Tm. (author)

  7. Quality control for thermoluminescent dosemeters TLD-100 de Li F: Mg, Ti for high dose rate treatments using Ir-192 sources in breast, esophagus and bronchus; Control de calidad con dosimetros thermoluminiscentes TLD-100 de Li F: Mg, Ti para tratamientos de alta tasa de dosis com fuentes de Ir-192 en canceres de seno, esofago y bronchio

    Energy Technology Data Exchange (ETDEWEB)

    Torres, F. [Universidad Nacional de Colombia, Bogota (Colombia)]. E-mail: franciscotorreshoyos@yahoo.com; Plazas, M.C. [Instituto Nacional de Cancerologia, Bogota (Colombia); Cavadia, W. [Universidad de Cordoba (Colombia)

    2004-07-01

    Rods - shaped, TLD - 100, LiF: Mg,Ti thermoluminescence dosimeters are used to check duality control during breast, esophagus and bronchus cancer treatments with high rate dose and Ir -192 source. We conclude that the specificity dose in prescription points is in agreement with parameters given in international protocols. (author)

  8. Dosimetric evaluation of the response of the TLD-100 dosemeters in the IMRT technique by 'Step and Shoot'; Evaluacion dosimetrica de la respuesta de los dosimetros TLD-100 en la tecnica de IMRT por 'Step and Shoot'

    Energy Technology Data Exchange (ETDEWEB)

    Vasquez, J. [Fundacion Clinica Valle del Lili, A.A. 020338, Cali (Colombia); Benavides, S.O. [Depto. de Fisica, Universidad del Valle, A.A. 25360, Cali (Colombia)

    2005-07-01

    We show the results of the dosimetry response of LiF thermoluminescent crystals: TLD-100, where they were radiated in a linear accelerator Siemens Primus Hl using the Intensity Modulated Radiation Therapy (IMRT) by step and shoot technique. Previous to the crystals calibration and response evaluation, the acceptation procedures recommended by the TG-53 protocol for validation of the technique were carried out. The planning system utilized was the Theraplan Plus 3.8, using the algorithm of Pencil Kernel. The register and verification system was Lantis 5.2. The response curve of dose versus charge was obtained from the readings of the TLD in a Harshaw 3500. The crystals were radiated in a Bench- Marck phantom with doses previously determined by using ionization chambers for square radiation fields, in a beam with a 0.68 TPR20,10 corresponding to 6 MV of energy. We compare the response of these through of radiation of segmented fields in a Anthropomorphic phantom and the calculated doses by the planning system. The results obtained in the crystals response show deviations less than 5 % between the measured dose and the calculated dose in the zones of low gradient. It allows its implementation like routine control of quality by IMRT. (Author)

  9. Proposal of a postal system for Ir-192 sources calibration used in high dose rate brachytherapy with LiF:Mn:Ti thermoluminescent dosemeters; Proposta de um sistema postal para a calibracao de fontes de {sup 192} Ir, utilizadas em braquiterapia de alta taxa de dose, com dosimetros termoluminescentes de LiF: Mn: Ti

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, W.S.; Borges, J.C.; Almeida, C.E.V. [Instituto de Radioprotecao e Dosimetria. CNEN Caixa Postal 37750, 22780-160, Rio de Janeiro (Brazil)

    1998-12-31

    A proposal in order to improve the brachytherapy quality control and to allow postal intercomparison of Ir-192 sources used in high dose rate brachytherapy has been presented. The LiF: Mn: Ti (TLD 100) detector has been selected for such purpose. The experimental array and the TLDs irradiation and calibration techniques, at the treatment units, have been specified in the light of more recent methodology of Ir-192 calibration sources. (Author)

  10. Procedures for calibration of clinical dosemeters of radiotherapy with gamma radiation Co-60 in the IPEN-CNEN, Sao Paulo, Brazil;Procedimento de calibracao de dosimetros clinicos de radioterapia em feixes de radiacao gamma de Co-60 no IPEN-CNEN/SP

    Energy Technology Data Exchange (ETDEWEB)

    Damatto, Willian B.; Santos, Gelson P.; Potiens, Maria da Penha A.; Vivolo, Vitor [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2009-07-01

    The periodic calibration of clinic dosimeters is a very important task, because those measurement systems performing the control quality of the radioactive source and for that assure the control quality of the patient dose estimative. This paper shows the calibration procedures and routine improved in the calibration laboratory of IPEN/CNEN-SP to be applied to the clinic dosimeters following international and national recommendations and yet the spend care that the clients should have with the utilization of that measurement systems for control quality of the radiotherapy procedures, for reduce the dose received for patient, and workers, and for increase the confidence level of the measurements.(author)

  11. Measuring the absorbed dose in critical organs during low rate dose brachytherapy with {sup 137} Cs using thermoluminescent dosemeters; Medicion de la dosis absorbida en organos criticos durante braquiterapia de baja tasa de dosis con {sup 137} Cs usando dosimetros termoluminiscentes

    Energy Technology Data Exchange (ETDEWEB)

    Torres, A. [UAEM, Fac. de Medicina, 50180 Toluca, Estado de Mexico (Mexico); Gonzalez, P.R. [ININ, A.P. 18-1027, 11801 Mexico D.F. (Mexico); Furetta, C.; Azorin, J. [UAM-I, 09340 Mexico D.F. (Mexico); Andres, U.; Mendez, G. [Centro Estatal de Cancerologia de Tabasco, A. Gregorio Mendez No. 2838, Col. Atasta, 86100 Villahermosa, Tabasco (Mexico)

    2003-07-01

    Intracavitary Brachytherapy is one of the most used methods for the treatment of the cervical-uterine cancer. This treatment consists in the insertion of low rate dose {sup 137}Cs sources into the patient. The most used system for the treatment dose planning is that of Manchester. This planning is based on sources, which are considered fixed during the treatment. However, the experience has shown that, during the treatment, the sources could be displaced from its initial position, changing the dose from that previously prescribed. For this reason, it is necessary to make measurements of the absorbed dose to the surrounding organs (mainly bladder and rectum). This paper presents the results of measuring the absorbed dose using home-made LiF: Mg, Cu, P + Ptfe thermoluminescent dosimeters (TLD). Measurements were carried out in-vivo during 20 minutes at the beginning and at the end of the treatments. Results showed that the absorbed dose to the critical organs vary significantly due to the movement of the patient during the treatment. (Author)

  12. State of the Art of Environmental Dosimetry: 11th International Intercomparison and Proposed Performance Tests (invited paper)

    Energy Technology Data Exchange (ETDEWEB)

    Klemic, G.; Shebell, P.; Miller, K.; Azziz, N. [New York (United States); Shobe, J.; Lamperti, P.; Soares, C. [Gaithersburg, MD (United States); Sengupta, S.; Holeman, G.; Kahnhauser, H.; Carolan, P.T. [Upton, NY (United States); Moscovitch, M. [Washington, DC (United States)

    1999-07-01

    The eleventh international intercomparison of environmental dosemeters was organised by the Environmental Measurements Laboratory in collaboration with the National Institute of Standards and Technology (NIST) and Brookhaven National Laboratory. One hundred and twenty one participants from 31 countries submitted 174 sets of dosemeters, including thermoluminescence dosemeters (TLDs), film, electrets, and a Geiger-Mueller device. An outdoor field site was used to expose dosemeters to natural radiation for three months, while other dosemeters were exposed to {sup 137}Cs and {sup 241}Am laboratory sources. A pressurised ionisation chamber, operated continuously at the field site, provided an independent measure of the air kerma in the field, and laboratory air kerma values were verified with chambers calibrated by NIST. Results are presented and current issues in environmental dosimetry are highlighted, including the field performance of new hypersensitive TLD materials. Preliminary results are given from a pilot test of a proposed standard from the American National Standards Institute that provides performance test criteria for environmental dosemeters. (author)

  13. Development of an algorithm for TLD badge system for dosimetry in the field of X and gamma radiation in terms of Hp(10).

    Science.gov (United States)

    Bakshi, A K; Srivastava, K; Varadharajan, G; Pradhan, A S; Kher, R K

    2007-01-01

    In view of the introduction of International Commission on Radiation Units and Measurements operational quantities Hp(10) and Hp(0.07), defined for individual monitoring, it became necessary to develop an algorithm that gives direct response of the dosemeter in terms of the operational quantities. Hence, for this purpose and also to improve the accuracy in dose estimation especially in the mixed fields of X ray and gamma, an algorithm was developed based on higher-order polynomial fit of the data points generated from the dose-response of discs under different filter regions of the present TL dosemeter system for known delivered doses. Study on the response of the BARC TL dosemeter system based on CaSO(4):Dy Teflon thermoluminescence dosemeter discs in the mixed fields of X and gamma radiation was carried out to ensure that the accuracies are within the prescribed limits recommended by the international organisations. The prevalent algorithm, based on the ratios of the disc response under various filters regions of the dosemeter to pure photons, was tested for different proportion of two radiations in case of mixed field dosimetry. It was found that the accuracy for few fields is beyond the acceptable limit in case of prevalent algorithm. The new proposed algorithm was also tested in mixed fields of photon fields and to pure photon fields of varied angles. It was found that the response of the dosemeter in mixed fields of photons and its angular response are satisfactory. The new algorithm can be used to record and report the personal dose in terms of Hp(10) as per the international recommendation for the present TL dosemeter.

  14. Determination of the neutron and photon dose equivalent at work places in nuclear facilities of Sweden. An SSI - EURADOS comparison exercise. Part 2: Evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Bartlett, D. [National Radiological Protection Board, Chilton (United Kingdom); Drake, P. [Vattenfall AB, Vaeroebacka (Sweden); Lindborg, L. [Swedish Radiation Protection Inst., Stockholm (Sweden); Klein, H. [Physikalisch-Technische Bundesanstalt, Braunschweig (Germany); Schmitz, Th. [Forschungszentrum Juelich GmbH, Juelich (Germany); Tichy, M

    1999-06-01

    Various mixed neutron-photon fields at workplaces in the containment of pressurised water reactors and in the vicinity of transport containers with spent fuel elements were investigated with spectrometers and dosimeters. The spectral neutron fluences evaluated from measurements with multisphere systems were recommended to be used for the calculation of dosimetric reference values for comparison with the readings of the dosemeters applied simultaneously. It turned out that most of the moderator based area dosemeters overestimated, while the TEPC systems generally underestimated the ambient dose equivalent (DE) values of the rather soft neutron fields encountered at these workplaces. The discrepancies can, however, be explained on the basis of energy dependent responses of the instruments used. The ambient DE values obtained with recently developed area dosemeters based on superheated drop detectors and with track etch based personal dosemeters on phantoms, however, were in satisfying agreement with the reference data. Sets of personal dosemeters simultaneously irradiated on a phantom allowed to roughly estimate the directional dependence of the neutron fluence. Hence, personal and limiting dose equivalent quantities could also be calculated. The personal and ambient DE values were always conservative estimates of the limiting quantities. Unexpectedly, discrepancies were observed for photon DE data measured with GM counters and TEPC systems. The up to 50 % higher readings of the GM counters may be explained by a considerable contribution of high energy photons to the total photon dose equivalent, but photon spectrometry is necessary for final clarification.

  15. Fading of the Tl signal in LiF: Mg, Cu, P during a large post irradiation period; Desvanecimiento de la senal Tl en LiF: Mg, Cu, P durante un largo periodo posradiacion

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, P.R. [ININ, A.P. 18-1027, 11801 Mexico D.F. (Mexico); Azorin, J. [UAM-I, 09340 Mexico D.F. (Mexico); Furetta, C. [Universidad de Roma, Piazzale Aldo Moro 2, Roma (Italy)

    2004-07-01

    In this work the obtained results of the study of the fading of the Tl signal in dosemeters of LiF activated with magnesium, copper and phosphorus (LiF:Mg,Cu,P) are presented. The studied dosemeters were LiF: Mg,Cu,P + Ptfe, developed in the ININ, taking like reference to the commercial dosemeter GR200A of Chinese manufacture. In both cases the Tl curve presents four peaks; in LiF: Mg,Cu,P + Ptfe, the peaks of smaller size appear in 359 K, 389 K and 447 K, the main dosimetric peak appears in 486 K; in GR200A, the peaks of smaller size appear in 360 K, 389 K and 445 K; while the main dosimetric peak appears in 487 K. The highest fading shown by the dosemeters of LiF: Mg,Cu,P + Ptfe, it was of 3.07%, value very below the one recommended for dosimetric purposes. While the commercial dosemeters presented a fading until of 6.23%, surpassing with the recommended values. The observed fading, it corresponds to the lost of the Tl signal of the peaks 1 and 2, since the first one disappears few hours after the irradiation, while the peak 2, it disappears completely after 94 days, the peak 3 remained stable during the six months of study, while the peak 4, it showed a slight increment due to the contribution of the dose of natural environmental radiation. (Author)

  16. Proton/gamma relative thermoluminescence efficiencies of LiF:Mg,Cu,P+PTFE prepared at ININ and TLD-100H

    Energy Technology Data Exchange (ETDEWEB)

    Avila, O.; Gonzalez, P.; Murillo, G. [Departamento de Fisica, ININ, Carretera Mexico-Toluca s/n, Ocoyoacac 52750, Estado de Mexico (Mexico)

    2009-10-15

    Properties of LiF:Mg,Cu,P+PTFE dosemeters developed at ININ have been investigated in order to evaluate their performance compared to those of equivalent commercial dosemeters. In this work both LiF:Mg,Cu,P+PTFE and TLD-100H pellets were exposed to low fluence 3 MeV protons and to low dose gamma radiation to evaluate experimental proton/gamma efficiencies. Gamma irradiation was performed using the Vic krad irradiator at ININ at varying doses between 25 and 500 mGy. For proton irradiation the Tandem Van de Graaff accelerator at ININ was used. Dosemeters were placed on a holder inside a scattering chamber where protons impinge on a gold target and scatter in all directions. The holder allows for several angular positions so that dosemeters receive proton fluence between 10{sup 6} and 10{sup 1}0 p/cm{sup 2}. Experimental efficiency values found for LiF:Mg,Cu,P+PTFE and TLD-100H were 0.18 +- 03 and 0.23 +- 0.03, respectively. These results allow to confirm the reliability of the dosemeters developed at ININ. (Author)

  17. Calorimetry of low mass Pu239 items

    Energy Technology Data Exchange (ETDEWEB)

    Cremers, Teresa L [Los Alamos National Laboratory; Sampson, Thomas E [Los Alamos National Laboratory

    2010-01-01

    Calorimetric assay has the reputation of providing the highest precision and accuracy of all nondestructive assay measurements. Unfortunately, non-destructive assay practitioners and measurement consumers often extend, inappropriately, the high precision and accuracy of calorimetric assay to very low mass items. One purpose of this document is to present more realistic expectations for the random uncertainties associated with calorimetric assay for weapons grade plutonium items with masses of 200 grams or less.

  18. External doses from radioactive fallout. Dosimetry and levels

    Energy Technology Data Exchange (ETDEWEB)

    Woehni, T.

    1995-12-31

    The design, manufacture and calibration of a TL-based dosemeter for measurement of low level external photon radiation are presented. The dosemeter is based on CaF{sub 2} with 2 mm brass filter for energy compensation. It is able to resolve a 8% dose increase relative to natural background radiation. With this dosemeter external dose measurements were made in 6 villages in a heavily contaminated region in Russia (Chernobyl fallout), in order to assess external doses to the population. The results were analyzed in the light of additional existing information on radioactive deposition, social habits, decontamination measures and other influencing technical and physical factors. The observed dose values were lower than theoretical estimates of external doses based on published values for external dose levels relative to the level of contamination. 84 refs., 7 figs., 5 tabs.

  19. Dose evaluation from multiple detector outputs using convex optimisation.

    Science.gov (United States)

    Hashimoto, Makoto; Iimoto, Takeshi; Kosako, Toshiso

    2011-07-01

    A dose evaluation using multiple radiation detectors can be improved by the convex optimisation method. It enables flexible dose evaluation corresponding to the actual radiation energy spectrum. An application to the neutron ambient dose equivalent evaluation is investigated using a mixed-gas proportional counter. The convex derives the certain neutron ambient dose with certain width corresponding to the true neutron energy spectrum. The range of the evaluated dose is comparable to the error of conventional neutron dose measurement equipments. An application to the neutron individual dose equivalent measurement is also investigated. Convexes of particular dosemeter combinations evaluate the individual dose equivalent better than the dose evaluation of a single dosemeter. The combinations of dosemeters with high orthogonality of their response characteristics tend to provide a good suitability for dose evaluation.

  20. Microprocessor controlled portable TLD system

    Science.gov (United States)

    Apathy, I.; Deme, S.; Feher, I.

    1996-01-01

    An up-to-date microprocessor controlled thermoluminescence dosemeter (TLD) system for environmental and space dose measurements has been developed. The earlier version of the portable TLD system, Pille, was successfully used on Soviet orbital stations as well as on the US Space Shuttle, and for environmental monitoring. The new portable TLD system, Pille'95, consists of a reader and TL bulb dosemeters, and each dosemeter is provided with an EEPROM chip for automatic identification. The glow curve data are digitised and analysed by the program of the reader. The measured data and the identification number appear on the LED display of the reader. Up to several thousand measured data together with the glow curves can be stored on a removable flash memory card. The whole system is supplied either from built-in rechargeable batteries or from the mains of the space station.

  1. Analysis of acceptance testing data for more than 800 sheets of CR-39 plastic assessed for the DRPS approved neutron dosimetry service

    Energy Technology Data Exchange (ETDEWEB)

    Jackson, M.; French, A.P. [Ministry of Defence, Gosport (United Kingdom). Defence Radiological Protection Service

    1997-09-01

    The Defence Radiological Protection Service (DRPS) Approved Dosimetry Service issues over 1200 planar CR-39 neutron dosemeters to the Ministry of Defence (Navy) each month. Results of sheet acceptance and calibration data suggest that average sheet background track densities have not varied significantly over the two-year period of the investigation. Average sheet sensitivity values have decreased significantly over the same period due to possible variations in the ageing characteristics of the CR-39 plastic. The data also suggest that sheets with higher initial sensitivities do not age as significantly as sheets with lower initial sensitivity values. The consequences of lowering the neutron dosemeter`s limit of detection was investigated. Results indicate there would be an increase in the number of sheets rejected for use in the neutron dosimetry service by a factor of 2.5. (author).

  2. Dose response of commercially available optically stimulated luminescent detector, Al2O3:C for megavoltage photons and electrons.

    Science.gov (United States)

    Kim, Dong Wook; Chung, Weon Kuu; Shin, Dong Oh; Yoon, Myonggeun; Hwang, Ui-Jung; Rah, Jeong-Eun; Jeong, Hojin; Lee, Sang Yeob; Shin, Dongho; Lee, Se Byeong; Park, Sung Yong

    2012-04-01

    This study examined the dose response of an optically stimulated luminescence dosemeter (OSLD) to megavoltage photon and electron beams. A nanoDot™ dosemeter was used to measure the dose response of the OSLD. Photons of 6-15 MV and electrons of 9-20 MeV were delivered by a Varian 21iX machine (Varian Medical System, Inc. Milpitas, CA, USA). The energy dependency was photons, the dose was linear until 200 cGy. The superficial dose measurements revealed photon irradiation to have an angular dependency. The nanoDot™ dosemeter has potential use as an in vivo dosimetric tool that is independent of the energy, has dose linearity and a rapid response compared with normal in vivo dosimetric tools, such as thermoluminescence detectors. However, the OSLD must be treated very carefully due to the high angular dependency of the photon beam.

  3. Quality control for exposure assessment in epidemiological studies

    DEFF Research Database (Denmark)

    Bornkessel, C; Blettner, M; Breckenkamp, J

    2010-01-01

    In the framework of an epidemiological study, dosemeters were used for the assessment of radio frequency electromagnetic field exposure. To check the correct dosemeter's performance in terms of consistency of recorded field values over the entire study period, a quality control strategy...... was developed. In this paper, the concept of quality control and its results is described. From the 20 dosemeters used, 19 were very stable and reproducible, with deviations of a maximum of +/-1 dB compared with their initial state. One device was found to be faulty and its measurement data had to be excluded...... from the analysis. As a result of continuous quality control procedures, the confidence in the measurements obtained during the field work was strengthened significantly....

  4. Evaluation of the thermoluminescent detector answers of CaSO{sub 4}:Dy, LiF:Mg,Ti and micro LiF:Mg,Ti in photon clinical beams dosimetry using water simulator; Avaliacao da resposta de detectores termoluminescentes de CaSO4:Dy, LiF:Mg,Ti e microLiF:Mg,Ti na dosimetria de feixes clinicos de fotons utilizando simulador de agua

    Energy Technology Data Exchange (ETDEWEB)

    Matsushima, Luciana C.; Veneziani, Glauco R.; Campos, Leticia L., E-mail: lmatsushima@usp.b, E-mail: veneziani@ipen.b, E-mail: lcrodri@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (GMR/IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Gerencia de Metrologia das Radiacoes; Sakuraba, Roberto K.; Cruz, Jose C. da, E-mail: rsakuraba@einstein.b, E-mail: jccruz@einstein.b [Sociedade Beneficente Israelita Brasileira, Sao Paulo, SP (Brazil). Hospital Albert Einstein (HAE)

    2011-10-26

    This paper perform the comparative study of thermoluminescent answer of calcium sulfate dosemeter doped with dysprosium (DaSO{sub 4}:Dy) produced by the IPEN, Sao Paulo, with answer of lithium fluoride dosemeters doped with magnesium and titanium (LiF:Mg, Ti) in the dosimetry of clinical beams of photons (6 and 15 MV) by using water simulator object. Dose-answer curves were obtained for gamma radiation of cobalt-60 in the air and in conditions of electronic equilibrium (plate of PMMA), and clinical photons of CLINAC model 2100C accelerators of the two evaluated hospitals: Hospital das Clinicas of the Faculty of Medicine of Sao Paulo university and Hospital Albert Einstein. It was also evaluated the sensitivity and reproduction of the three dosemeters

  5. Intercomparison of passive dosimetry technology at EDF facilities in France.

    Science.gov (United States)

    Garcier, Y; Cordier, G; Pauron, C; Fazileabasse, J

    2007-01-01

    Since the spring of 1999, new French radiation protection legislation has allowed the use of passive dosemeters, other than the silver emulsion film badge, for the measurement of H(p)(10). Faced with the eventual obsolescence of its dosimetry system, Electricité de France (EDF, the French electricity provider) initiated a comparative study of passive dosemeters, based on different technologies, that had received accreditation by national laboratories and regulatory bodies, namely: TLD, RPL and OSL. An extended field study in nuclear power stations and medical X-ray departments has shown that all technologies provide compatible dosimetric estimates. It also showed that the selected dosemeters based on RPL and OSL technologies gave better results due to their energy responses and to a lower detection threshold compliant with the new regulation. A final suggestion to implement a new OSL based dosimetric system is made due to its overall performance and to its lower cost of implementation.

  6. Elaboration of pellets of LiF: Mg, Cu, P and its dosimetric properties; Elaboracion de pastillas de LiF: Mg, Cu, P y sus propiedades dosimetricas

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez C, A.; Gonzalez M, P.R.; Azorin N, J

    1991-03-15

    The LiF: Mg, Cu, P is at the moment in the entire world one of the TL materials of more interest, by its equivalence with the tissue, as well as for its high sensitivity, which is 25 to 35 times greater than of the TLD-100 of Harshaw (USA). In our laboratory dosemeters of this material have been developed in form of sinterized pellets. The importance of these new dosemeters in pellet form is due to that in this form its manipulation is facilitated. Due to its high sensitivity, these dosemeters result to be those but appropriate to measure the ionizing radiations, in intervals of extremely low dose. In this report the method of elaboration of the pellets, as well as its main dosimetric characteristics are presented. (Author)

  7. Long-term stability of a TLD-based individual monitoring system.

    Science.gov (United States)

    Alves, J G; Abrantes, J N; Margo, O; Rangel, S; Santos, L

    2006-01-01

    The thermoluminescence dosemeter (TLD) system at the Individual Monitoring Service (IMS) of the Nuclear Technology Institute (ITN) at the Radiological Protection and Nuclear Safety Department (DPRSN) comprises two 6600 Harshaw readers and the Harshaw 8814 TL card and the holder containing two LiF:Mg,Ti (TLD-100) dosemeters for the evaluation of H(p)(10) and H(p)(0.07). The readers are calibrated on a monthly basis and as part of the quality assurance programme implemented at the IMS a set of dosemeters is issued monthly to the DPRSN's Standard Dosimetry Laboratory for linearity measurements. The results obtained since November 2001 are presented. Fading and sensitivity change experiments are carried out every month covering 8 week periods so that enough time is given to simulate issuing, integrating and receiving times and respective delays. A set of 96 dosemeters organised in eight subsets of 12 are used. In each subset, four dosemeters are irradiated and stored at room temperature (RT), four are not irradiated at all and the last four are irradiated after storage. The 12 dosemeters of each subset are readout at the same time, one per week, covering the 8 week period. The results from the sets irradiated and stored at different periods allowed for the evaluation of fading and sensitivity changes experienced over the whole monitoring period and respective preparation time and readout delays. Time evolution charts of the reader calibration factors, of the linearity parameters and of the evolution of the integrated area in the region of dosimetric interest with storage at RT were obtained. This paper aims to quantify the long-term stability of the TLD system in use at the IMS.

  8. Study of T L LiF: Mg,Ti (Model JR1152C) material for its use in the environmental monitoring; Estudio del material TL LiF: Mg, Ti (JR1152C) para su empleo en el monitoreo ambiental

    Energy Technology Data Exchange (ETDEWEB)

    Molina P, D.; Diaz B, E.; Prendes A, M. [Centro de Proteccion e Higiene de las Radiaciones, CPHR, Apdo. postal 6195, Habana 6, CP 10600, Ciudad Habana (Cuba)

    1999-07-01

    In order to evaluate the possibility to use the T L material of LiF: Mg,Ti (Model JR1152C) as environmental dosemeter it was realized its characterization of it according to the established criterion in the standard IEC-1066. The properties studied were: homogeneity of the lot, reproducibility, response linearity, detection threshold, auto irradiation, residual signal, response pride (fading) and angular dependence. The results prove the compliment of the IEC requirements and therefore the applicability of this dosemeter in the environmental monitoring. (Author)

  9. Quality assurance and quality control programme in the Personal Dosimetry Department of the Greek Atomic Energy Commission.

    Science.gov (United States)

    Kamenopoulou, V; Drikos, G; Carinou, E; Papadomarkaki, E; Askounis, P; Kyrgiakou, H; Kefalonitis, N

    2002-01-01

    A quality assurance (QA) and quality control (QC) programme was applied to the personal monitoring department (TLD based) of the Greek Atomic Energy Commission (GAEC). This programme was designed according to the recommendations of international bodies such as the International Organization for Standardization (ISO), the International Electrotechnical Commission (IEC), the International Atomic Energy Agency (IAEA) and the European Commission (CEC). This paper deals with the presentation of the QA/QC programme which includes administrative data and information, technical checking of the equipment, acceptance tests of new equipment and dosemeters, issuing and processing of the dosemeters, dose evaluation, record keeping and reporting, traceability and reproducibility, handling of complaints, internal reviews and external audits.

  10. Implantation of radiation qualities for mammography in accordance with the IEC 61627 and TRS 457 criteria; Implantacao das qualidades de radiacao para mamografia, segundo os criterios da IEC 61627 e do TRS 457

    Energy Technology Data Exchange (ETDEWEB)

    Pires, Evandro J.; David, Mariano G.; Almeida, Carlos Eduardo de, E-mail: pires@lcr.uerj.b [Universidade do Estado do Rio de Janeiro (LCR/UERJ), RJ (Brazil). Lab de Ciencias Radiologicas; Peixoto, J. Guilherme, E-mail: guilhem@ird.gov.b [Instituto de Radioprotecao e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2009-07-01

    In this work it is discussed the technical conditions of the implantation of radiation qualities adequate for dosemeter applied to mammography at the Radiological Science Laboratory (RSL) of the University of State of Rio de Janeiro, Brazil. It performed tests for evaluation the homogeneity of the radiation field, the scattering, the half-layers and the system stability. The test results point for adequacy of the laboratory installed at the LCR for calibration of the mentioned dosemeters in seven qualities of radiation and the expanded uncertainty with better capacity of measurement at those qualities was of {+-}1.8% (k = 2)

  11. Dosimetry in a torso phantom during a mammography; Dosimetria en un fantoma de torso durante una mastografia

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez O, M.; Duran M, H. A. [Universidad de Sonora, Blvd. Luis Encinas y Rosales s/n, Hermosillo 93000, Sonora (Mexico); Pinedo S, A.; Salas L, M. A.; Hernandez D, V. M.; Vega C, H. R. [Unidad Academica de Estudios Nucleares, Universidad Autonoma de Zacatecas, Cipres 10, Fracc. La Penuela, 98068 Zacatecas (Mexico); Rivera M, T. [Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada, IPN, Av. Legaria 694, Col. Irrigacion, 11500 Mexico D. F. (Mexico); Ventura M, J. [Hospital General de Zona No. 1, IMSS, Interior Alameda 45, 98000 Zacatecas (Mexico)

    2009-10-15

    Two dosimetric magnitudes, the absorbed dose and the kerma in air to the entrance of torso have been determined. These dosimetric magnitudes are due to the radiation that is dispersed in the mammary gland when the patient undergoes a mammography study. The kerma to the entrance of the torso and the absorbed dose by the torso was obtained in a phantom of paraffin and with thermoluminescent dosemeters of ZrO{sub 2}. The dosemeters were placed on the surface of the torso phantom while the mammography was carried out. (author)

  12. Calorimetry in Tore Supra. An accurate tool and a benchmark for ITER

    Energy Technology Data Exchange (ETDEWEB)

    Vallet, J.-C. E-mail: jcvallet@cea.frvallet@drfc.cad.cea.fr; Chantant, M.; Mitteau, R.; Thouvenin, D.; Cordier, J.J.; Ekedahl, A.; Escourbiac, F.; Kazarian, F.; Loarer, T.; Vulliez, K

    2003-03-01

    In the framework of the Tore Supra-CIEL upgrade, designed for steady-state operation, the calorimetric diagnostic implemented in the cooling water loop has been completely rebuilt. Both the techniques used to increase the diagnostic sensitivity and examples of calorimetric analysis are reported. The interest and relevance of such a diagnostic for ITER or other actively cooled machines are briefly discussed.

  13. Measurement of the total solar energy transmittance (g-value) for conventional glazings

    DEFF Research Database (Denmark)

    Duer, Karsten

    1998-01-01

    Three different glazings have been investigated in the Danish experimental setup METSET. (A device for calorimetric measurement of total solar energy transmittance - g-value).The purpose of the measurements is to increase the confidence in the calorimetric measurements. This is done by comparison...

  14. Cryogenic Laser Calorimetry for Impurity Analysis

    Science.gov (United States)

    Swimm, R. T.

    1985-01-01

    The results of a one-year effort to determine the applicability of laser-calorimetric spectroscopy to the study of deep-level impurities in silicon are presented. Critical considerations for impurity analysis by laser-calorimetric spectroscopy are discussed, the design and performance of a cryogenic laser calorimeter is described, and measurements of background absorption in high-purity silicon are presented.

  15. The CMS electromagnetic calorimeter and the search for the Higgs boson in the decay channel H {yields} WW{sup *} {yields} 2e2{nu}; Le calorimetre electromagnetique de CMS et la recherche du boson de Higgs dans le canal de desintegration H {yields} WW{sup *} {yields} 2e2{nu}

    Energy Technology Data Exchange (ETDEWEB)

    Rovelli, I.Ch

    2006-01-15

    CMS is one of the four experiments that will take data at the LHC. Large part of my work was devoted to the development of electron reconstruction tools aimed at improving the Higgs boson discovery potential in the H {yields} WW{sup *} {yields} 2e2{nu} channel. A major role in the electron reconstruction is played by the electromagnetic calorimeter ECAL, an homogeneous calorimeter made of scintillating PbWO{sub 4} crystals. The first 3 chapters give an overview of LHC and CMS.In chapter 4 the analysis of the data collected during the 2003 electromagnetic calorimeter test beam is presented. First the problem of the intercalibration at the test beam is addressed. This is a major task, since the precision of the intercalibration directly affects the constant term of the energy resolution, for which the CMS goal is to reach a precision better than 0.5%. The good initial intercalibration, anyway, could be spoiled during the data taking by the effects of the radiation on the crystals, which can change the relative responses of the channels. A monitoring laser system is foreseen at CMS. The possibility to check the calibration stability and to correct the changes in the response with a precision within the required limits is demonstrated. Chapter five describes the electron reconstruction and identification in CMS. A crucial problem for the electron reconstruction is represented by the Bremsstrahlung emission in the tracker. A tracking procedure dealing with the Bremsstrahlung energy loss is discussed. Together with an improvement in the reconstruction efficiency, the procedure allows to identify electrons with a small fraction of radiated energy, which can be usefully exploited for the ECAL calibration. The developed algorithms are applied in chapter 6, which presents the study of the CMS discovery potential of the Higgs boson in the H {yields} WW{sup *} {yields} 2e2{nu} channel. This is the discovery channel in the range of masses between 2m{sub W} and 2m{sub Z}. Here the possibility to extend the study also to the low mass region up to m{sub H} = 120 GeV/c{sup 2} is investigated. The CMS sensitivity to the H {yields} WW{sup *} channel is presented.

  16. Calorimetry Hadronic with semidigital reading based on camera of resistive planes of glass for experiments on collision linear e + e-; Calorimetr@a hadr@nica con lectura semidigital basada en c@mara de planos resistivos de vidrio para experimentos en colisionadores lineales e + e-

    Energy Technology Data Exchange (ETDEWEB)

    Berenguer Antequera, J.

    2015-07-01

    Calorimetry Hadronic with semidigital reading based on camera of resistive planes of glass for experiments on collision linear e + e-. Electron-positron linear colliders have been proposed as next generation particle colliders to complement and extend the physics programme of the LHC (Large Hadron Collider) at CERN. Currently, two projects, ILC (International Linear Collider) and CLIC (Compact LInear Collider), have been suggested by the international community to reach this purpose. The requirements for a detector for both linear colliders are defined by the precision needed to fully exploit the physics potential of these colliders. In particular, one of the most important requirements is an excellent jet energy resolution. This can be achieved with the particle-flow concept in which the overall detector performance for jet reconstruction is optimised by reconstructing each particle individually. For this reason, the calorimeter system has to have unprecedented granularity fulfilling the task of shower separation and providing excellent jet energy resolution and background separation. (Author)

  17. Commissioning of the ATLAS electromagnetic calorimeter and Z' {yields} e{sup +}e{sup -} discovery potential in the first LHC data; Mise en service du calorimetre electromagnetique d'Atlas et determination du potentiel de decouverte d'un Z' {yields} e{sup +}e{sup -} dans les premieres donnees LHC

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-15

    After about fifteen years of development, the ATLAS detector is ready to operate and it recorded, in 2008, several millions of cosmic events as well as first LHC data. This achievement is based on the long experience of beam tests and on the large effort towards the detector in situ commissioning undertaken by the ATLAS collaboration. This promises fast ability to perform searches for evidence of the Higgs boson and new physics. I heavily contributed to the in situ commissioning of the electromagnetic calorimeter. To verify its performance, I studied the first cosmic data taken in 2006 which allowed the first in situ analysis of dead channels, energy reconstruction and detector response uniformity. This participation to the commissioning has continued with the study of the single beam data recorded during the first week of LHC operation (Sept. 2008). Expanding on my expertise of the electromagnetic calorimeter, I focused my physics analysis, prepared with simulation, on the promising discovery potential of new physics at LHC via the di-electron/di-photon decay of new heavy gauge boson in the early LHC data (the first 100 pb{sup -1}). Possible limitations coming from early hardware problems or imperfect electron energy calibration in first data have been estimated. According to the new schedule of LHC operation, this analysis will be possible with 10 TeV pp collisions data in 2010. (author)

  18. 等温滴定量热法研究牛血清白蛋白与十二烷基二羟乙基甲基溴化铵的相互作用%Isothermal titration calorimetric study on interactions between bovine serum albumin and N-dodecyl-di(2-hydroxyehtyl)-methyl ammonium bromide

    Institute of Scientific and Technical Information of China (English)

    胡晓环; 童威; 邵爽; 雷群芳; 方文军

    2011-01-01

    用等温滴定热量计测定了牛血清白蛋白(BSA)与十二烷基二羟乙基甲基溴化铵(DDHAB)的相互作用焓,探讨了表面活性剂浓度、温度和盐浓度等对相互作用焓的影响.BSA与表面活性剂相互作用焓是静电作用、去水化作用、疏水作用和表面活性剂胶束化等协同作用的结果,在其他条件保持不变时,相互作用焓随表面活性剂浓度改变,在临界胶束浓度(CMC)前后区域分别出现吸热峰.加入NaCl可引起相互作用焓峰值及其位置的变化.%Interaction enthalpies between bovine serum albumin (BSA) and N-dodecyl-di(2-hydroxyehtyl)-methyl ammonium bromide (DDHAB) have been determined in an isothermal titration calorimeter. The influences of temperature, concentrations of surfactant and the added salt in the solutions on the interaction enthalpy have been discussed. The interaction enthalpies between BSA and a surfactant are resulted from the cooperative effects of electrostatic interaction, dehydration, hydrophobic interaction and surfactant micellization. The interaction enthalpy changes against the surfactant concentration with two endothermic peaks observed in the regions before and after the critical micelle concentration (CMC). The addition of NaCl in the surfactant solution can lead to the value change of the interaction enthalpy and the position change of the endothermic peaks.

  19. Calorimetric investigation of phase transitions in the layered antiferromagnetic molecule-based material {l_brace}N(n-C{sub 5}H{sub 11}){sub 4}[Mn{sup II}Fe{sup III}(ox){sub 3}]{r_brace}{sub {infinity}}(ox=oxalato)

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharjee, A. E-mail: ashis62@rediffmail.com; Miyazaki, Y.; Sorai, M

    2004-09-01

    Heat capacity studies of the layered molecule-based magnetic material {l_brace}N(n-C{sub 5}H{sub 11}){sub 4}[Mn{sup II}Fe{sup III}(ox){sub 3}]{r_brace}{sub {infinity}} (ox=oxalato) have been made in the 2-280 K range. Two distinct heat capacity anomalies were detected at 27.1 K (T{sub N}) and 226 K corresponding to magnetic and structural phase transitions, respectively, along with a hump around 23 K. The magnetic heat capacities above T{sub N} can be well represented by S=5/2 two-dimensional antiferromagnetic Heisenberg model of a honeycomb lattice with intralayer exchange interaction J/k{sub B}=-3.3 K. Application of spin-wave theory indicated the existence of a very weak interlayer magnetic interaction below T{sub N}. The anomaly at 27.1 K is due to the antiferromagnetic transition, in conformity with the magnetic results reported earlier. The hump around 23 K might be associated with the existing uncompensated magnetic moments. The estimated magnetic entropy (33.22 J K{sup -1} mol{sup -1}) is close to the expected magnetic entropy (R ln (6x6)=29.80 J K{sup -1} mol{sup -1}) for the spin multiplicity of high spin Mn{sup II} and Fe{sup III} ions. The heat capacity anomaly at 226 K may be assigned to a structural phase transition of order-disorder type due to increasing conformational change of the n-C{sub 5}H{sub 11} chains in the organic cation.

  20. Calibration of the electromagnetic calorimeter of the Atlas detector: reconstruction of events with non-pointing photons in the frame of a GMSB supersymmetric model; Etalonnage du calorimetre electromagnetique du detecteur Atlas: reconstruction des evenements avec des photons non pointants das le cadre d'un modele supersymetrique GMSB

    Energy Technology Data Exchange (ETDEWEB)

    Prieur, D

    2005-04-15

    The analysis of test-beam data is focused on the calibration of the ATLAS electromagnetic calorimeter. An electrical model has been developed to predict the shape of the physics pulse out of the calibration signal in order to produce optimal filtering coefficients. They are used to compute energy while minimizing electronic noise and getting rid of any possible time shift. Using these coefficients, the uniformity response is 0.6%, in agreement with the 0.7% global constant term required for the whole calorimeter. The study of non pointing photon is driven by the detection of long lived neutralinos predicted by GMSB SUSY models. A systematic study with a detailed simulation of the ATLAS detector was performed to determine the electromagnetic calorimeter angular resolution for such photons. Results were used to parametrized the detector response and to reconstruct SUSY events from this model. (author)

  1. Study of the signal H{sup 0}/A{sup 0} {yields} {tau}{mu} in hadron colliders and inter-calibration of the Ddiameter calorimeter with RUN 2 of Tevatron; Etude du signal H{sup 0}/A{sup 0} {yields} {tau}{mu} aux collisionneurs hadroniques et intercalibration du calorimetre de Ddiametre au RUN 2 du Tevatron

    Energy Technology Data Exchange (ETDEWEB)

    Delsart, P.A

    2003-10-01

    D0 is one of the 2 detectors settled on the Tevatron at Fermilab. This thesis has been made in collaboration with the 'theory' group and the D0 group of IPNL (nuclear physics institute of Lyon). Within the D0 group we have worked on the calibration of the detector's calorimeter: intercalibration. Using the fact that the physics is phi-symmetric in D0 we have created and applied statistical methods for a relative calibration of some phi-symmetric parts of the calorimeter. Work on particle physics concerned the two Higgs doublet model. In such models leptonic number violation is possible: we have simulated the H{sup 0}/A{sup 0} {yields} {tau}{mu} signal in order to study the discovery potential and the constraints on the coupling responsible for this decay. (author)

  2. An in-beam test study of the response of calorimeters in the ATLAS Experiment of LHC to charged pions of 3 to 350 GeV energy range; Etude en faisceau-test de la reponse des calorimetres de l'Experience ATLAS du LHC a des pions charges, d'energie comprise entre 3 et 350 Gev

    Energy Technology Data Exchange (ETDEWEB)

    Giangiobbe Vincent [Ecole Doctorale des Sciences Fondamentales, Universite Blaise Pascal, U.F.R de Recherches Scientifiques et Techniques, 34, avenue Carnot - BP 185, 63006 Clermont-Ferrand Cedex (France)

    2006-11-15

    ATLAS is one of the four main experiments under way of installing within the Large Hadron Project (LHC). LHC will provide two proton beams of high luminosity (1 x 10{sup 34} cm{sup -2} s{sup -1} at peak), colliding in the center of ATLAS detector at a 14 TeV rated COM energy. The aim of this study is an in-beam test characterization of the response of calorimeters in the central part of ATLAS. The study will be focused on the response to pions as main jet components. In the beginning a short presentation of the ATLAS program of physics is given enlightening the basic theoretical and experimental aspects of the experiment. A description of the ATLAS detector is also presented. The second chapter is devoted to detailed description of the central calorimetry of ATLAS. One starts from the mechanism of signal production in calorimeters, through the electronic processing up to the reconstruction of the released energy. The third chapter deals with the processing electronics of the TileCal hadron calorimeter the installation and certification at CERN of which was in charge of Clermont-Ferrand team. The chapter 4 gives a description of the SPS beam line and of the associated instrumentation tested in-beam in 2004. The chapters 6 and 7 are devoted to the study of the response of calorimeters to high energy pions (within 20 to 350 GeV range). The pion selection is described in the chapter 5. In the eighth chapter the calorimeter response to low energy pions (up to 9 GeV) is examined. In conclusion this study has shown that the data concerning pions obtained in-beam in 2004 are usable for energies within 3 to 350 GeV. The response and the energy resolution of LAr and TileCal were measured with a satisfactory accuracy,. A systematic comparison of these results with simulations (in the configuration of in-beam test) can now be done. Should the agreement be satisfying, the modelling could be used for the study of calibration of calorimeter response for the case of works with the jets.

  3. Study and testing of the photomultipliers of TILECAL calorimeter of ATLAS detector. Search for stop t-tilde{sub 1} with ATLAS detector; Etude et caracterisation des photomultiplicateurs du calorimetre a tuiles scintillantes d'atlas. Recherche du stop t-tilde{sub 1} avec le detecteur atlas

    Energy Technology Data Exchange (ETDEWEB)

    Hebrard, Ch

    1999-11-04

    The first part of this thesis presents the prospective study on the possibility that we observe an excess of event with four light quark jets, two b quark jets and missing transverse energy in comparison with the predictions of standard model. In the frame of the SUperGRAvity (SUGRA) these events are produced by the Stop decay. The results show that it will be possible to observe an excess of events if Stop mass is less than 600 GeV. The second part of this work turns on the design of the photomultipliers which will be used in ATLAS Tile Calorimeter. A huge work of development and optimisation has been done to make R7877 Hamamatsu photomultiplier fitting all the specifications dictating by the detector. The measurements developed to characterize the photomultipliers are discussed. An special effort has been done to understand and solve the problem of instability of R7877 photomultiplier. In the future, Tile calorimeter will be equipped with 10000 photomultipliers, so a test bench has been developed in order to characterize all these photomultipliers. The performances of this test bench are inspected for each type of measurement (amplification, quantum efficiency, collection efficiency, dark current, linearity and stability). The specifications and technical design of this test bench are summarized in annexes. (author)

  4. Preparation of the ATLAS experiment in the LHC proton collider, performances of the electromagnetic calorimeter and its potentialities for the top quark; Preparation de l'experience ATLAS aupres du futur grand collisionneur de protons LHC: performances du calorimetre electromagnetique et potentiels pour la physique du quark top

    Energy Technology Data Exchange (ETDEWEB)

    Hubaut, F

    2007-03-15

    ATLAS is the biggest and the more complex detector ever built, it will operate on the LHC and is the outcome of a huge international collaboration of 2000 physicists. This document reviews the theoretical and experimental achievements of one of them, his collaboration spread over 7 years and has followed 2 axis. First, the design, construction and test of the electromagnetic calorimeter of ATLAS and secondly, the development of analysis strategies in the physics of the top quark. The expected important production of top quarks in LHC will allow an accurate measurement of the properties of this particle and in the same way will provide new testing areas for the standard model. The top quark, being extremely massive, might play a significant role in the mechanism of electro-weak symmetry breaking. This document is organized into 5 chapters: 1) ATLAS detector, performance and progress, 2) the optimization of the energy measurement with the electromagnetic calorimeter, 3) the performance of the electromagnetic calorimeter, 4) the physics of the top quark, and 5) the potentialities of ATLAS in the top quark sector. This document presented before an academic board will allow its author to manage research works and particularly to tutor thesis students. (A.C.)

  5. Experimental study of the test module of the electromagnetic end-cap calorimeter for the ATLAS experiment. Study of the spin correlation in the production of pairs tt-bar; Etude experimentale des performances du module 0 du calorimetre electromagnetique bouchon d'ATLAS. Etude de la correlation de spin dans la production des paires tt-bar au LHC

    Energy Technology Data Exchange (ETDEWEB)

    Hinz, L

    2001-06-01

    LHC, the future CERN proton collider, will start in 2006. It will be devoted to a better understanding of the Standard Model and new physics research. With a 10 {integral}b{sup -1} per year at low luminosity during the first three years, then 100 {integral}b{sup -1} per year, and energy of 14 TeV in the center of mass, the LHC is designed to discover the Standard or SUSY Higgs boson, or probe signature of new physics. ATLAS, one of the four experiments at the LHC, can study a large physics range, as Higgs boson, top and bottom, gauge bosons and new particles expected by SUSY model or other models beyond the Standard Model. The CPPM laboratory is responsible of a part of the electromagnetic end-cap calorimeter for the ATLAS experiment. In 1999, an ATLAS-like prototype of module was stacked in Marseille and intensively tested at CERN. Description of the calorimeter and a part of test-beam results are presented in this PhD manuscript. In parallel, a study about potentiality of the tt-bar spin correlation measurement was done. The high tt-bar statistic produced at the LHC allows to explore the quark top properties in details and being sensitive to new physics phenomena. Signatures of such physics can be extracted from tt-bar decay product angular distributions which are sensitive to tt-bar spin correlation. (authors)

  6. Participation to the study of the electromagnetic calorimeter calibration for the CMS experiment and to the study of avalanche photodiodes; Participation a l'etude de la calibration du calorimetre electromagnetique de l'experience CMS et a l'etude de photodiodes a avalanche

    Energy Technology Data Exchange (ETDEWEB)

    Da Ponte Puill, V

    1999-12-13

    The electromagnetic calorimeter CMS (Compact Muon Solenoid) has been chosen to study the Higgs boson production. This calorimeter will be constituted of more than 80000 lead tungstate scintillating crystals radiation resistant. Photodiodes have been especially optimized to detect the scintillating light of these crystals: avalanche photodiodes (APD). This thesis includes two separate parts. A first part deals with the APD submitted to high rate of radiations and tested in the Ulysse reactor of the Cea. The second part deals with the calorimeter calibration. (A.L.B.)

  7. Contribution to the study of electromagnetic calorimeter with PbWO{sub 4} crystals in the CMS experiment at LHC; Contribution a l`etude du calorimetre electromagnetique a cristaux de PbWO{sub 4} de l`experience CMS au LHC

    Energy Technology Data Exchange (ETDEWEB)

    Benhammou, Y. [Lyon-1 Univ., 69 (France)

    1997-01-13

    The Higgs bosons can be observed in the [90-130] GeV mass range in the channel h -> {gamma}{gamma} if a high resolution electromagnetic calorimeter is used. The needed performances are met in the Pb W O{sub 4} crystals. This thesis is devoted to the study of the first Pb W O{sub 4} crystals (23 cm length) and their associated electronic equipment. Of crucial importance it was found to be the behaviour of these crystals under long radiation exposure. The understanding of the radiation effects, the crystal growth procedure mastering and the realization of a green light monitoring system of high performance were successful results obtained in the study described in this thesis. A rather high energy (0.6 % at 100 GeV) and position resolution was achieved by using a APD readout. In addition, the prototype of a final readout chain of large dynamic range and low consumption was built with very encouraging results. Concerning the APDs it was established that increasing the active surface and reduction of exceeding noise factor F improves significantly the stochastic term in the energy resolution. Besides, a complete readout chain comprising current preamplifiers, a linear compressing (multi-slope) system and a fast ADC (40 MHz), were found necessary to met the requirements imposed on the high performing Pb W O{sub 4} calorimeter. Research and development works based on the pioneering studies described in this thesis devoted to the crystal calorimeters are underway 77 refs.

  8. Studies of the LHC detection systems: scintillating fibers projective electromagnetic calorimeter prototype and light reading by avalanche photodiodes; Etudes de systemes de detection pour LHC: prototype d`un calorimetre electromagnetique projectif a fibres scintillantes et lecture de la lumiere par des photodiodes a avalanches

    Energy Technology Data Exchange (ETDEWEB)

    Bouhemaid, N.

    1995-09-22

    In this thesis a study concerning the hardware detection system of ATLAS experiment in preparation for L.H.C. is presented. The study is divided in two parts. After a general introduction of the L.H.C. and the ATLAS detector, the first part concerning the electromagnetic calorimeter, and the second part concerning the readout with avalanche photodiodes, are discussed. For both subjects the basic principles are presented before various test results are described. Within the RD1 program three different electromagnetic calorimeter prototypes, which all use the lead scintillating fibres technique, have been built. The first is a non-projective, compensating calorimeter called ``500{mu}m``, the second is a pseudo projective, non-compensating, called ``1 mm``, and the third is fully projective, called ``Radial``. The last prototype is discussed in more detail. Avalanches photodiodes which are used as readout of the ``1 mm`` calorimeter, have been exposed to both, a dedicated test bench in the laboratory as well as to test beams. The results of these tests are also presented. (author). 35 refs., 96 figs., 30 tabs.

  9. Design of a large dynamics fast acquisition device: application to readout of the electromagnetic calorimeter in the ATLAS experiment; Conception d`un dispositif d`acquisition rapide de grande dynamique: application a la lecture du calorimetre electromagnetique de l`experience ATLAS

    Energy Technology Data Exchange (ETDEWEB)

    Bussat, Jean-Marie [Universite de Paris Sud, 91 - Orsay (France)

    1998-06-05

    The construction of the new particle accelerator, the LHC (Large Hadron Collider) at CERN is entails many research and development projects. It is the case in electronics where the problem of the acquisition of large dynamic range signals at high sampling frequencies occurs. Typically, the requirements are a dynamic range of about 65,000 (around 16 bits) at 40 MHz. Some solutions to this problem will be presented. One of them is using a commercial analog-to-digital converter. This case brings up the necessity of a signal conditioning equipment. This thesis describes a way of building such a system that will be called `multi-gain system`. Then, an application of this method is presented. It involves the realization of an automatic gain switching integrated circuit. It is designed for the readout of the ATLAS electromagnetic calorimeter. The choice and the calculation of the components of this systems are described. They are followed by the results of some measurements done on a prototype made using the AMS 1.2{mu}m BiCMOS foundry. Possible enhancements are also presented. We conclude on the feasibility of such a system and its various applications in a number of fields that are not restricted to particle physics. (author) 33 refs., 132 figs., 22 tabs.

  10. Construction and tests of the Atlas barrel pre sampler and study of the photon/pion rejection in the electromagnetic calorimeter; Realisation du pre-echantillonneur central d'ATLAS et etude de la separation {gamma}/{pi}{sup 0} dans le calorimetre electromagnetique

    Energy Technology Data Exchange (ETDEWEB)

    Saboumazrag, S

    2004-02-01

    ATLAS is one of the detectors which will equip the future proton-proton collider LHC at CERN. The main motivation for the ATLAS experiment is the quest for the Higgs boson. The observation of this particle would be an important step in the understanding of particle physics in the context of the standard model, with or without supersymmetry. This thesis aims to present the construction of the barrel pre-sampler which will equip the front face of the ATLAS electromagnetic calorimeter. The construction and tests of sectors were achieved at the Laboratory of Subatomic Physics and Cosmology of Grenoble. Two of these sectors were mounted on one module of the electromagnetic calorimeter and tested with electron, photon and muon beams at CERN. I participated in these tests and analysed the data. The results were compared to a Monte-Carlo simulation GEANT3. One of the difficulties lies in the necessity to discard photons coming from {pi}{sup 0} {yields} {gamma}{gamma} events because they can be mistaken for photons released in gamma channels of Higgs boson decay. In the mass range spreading from 95 MeV to 150 MeV, H{sup 0} {yields} {gamma}{gamma} is the most adequate process to detect the Higgs boson. A study of the discard parameter {gamma}/{pi}{sup 0} has been performed. For a photon detection efficiency of 90%, the average discard parameter has been assessed to be 2.5 which is slightly lower than the value given by the simulation.

  11. Analysis of the uniformity of the modules forming the barrel of the electromagnetic calorimeter of Atlas. Search for supplementary neutral gauge bosons; Analyse de l'uniformite des modules de serie du calorimetre electromagnetique tonneau d'ATLAS. Recherche de bosons de jauge supplementaires neutres

    Energy Technology Data Exchange (ETDEWEB)

    Gaumer, O

    2004-12-15

    Grand unification theories are a possible extension of the standard model. These theories imply the existence of an extra gauge boson: Z'. The study of the parameters of this boson in its electronic decays, especially its width, needs a good uniformity and a good resolution of the electromagnetic calorimeter. The first part of this thesis is dedicated to the study of the response of the barrel of the electromagnetic calorimeter to a 245 GeV electron beam. The major part of this work was the measurement of the uniformity. To perform this analysis the search of problematic channel has been made and corrections have been developed to take into account effect from the detector and to use all the recorded events. In the second part, I have studied the potential of Atlas in the study of the Z' decaying into lepton pairs (mainly in electron pairs). A study of the kinematic and of the background has been performed. This analysis deals with the possibility to distinguish different grand unification models, and with the possibility to discover the Z' boson, for masses from 1 TeV up to 4 TeV. (author)

  12. Study of performances of the liquid krypton calorimeter of the NA48 experiment for measurement of Re({epsilon}'/{epsilon}); Etude des performances du calorimetre a krypton liquide de l'experience NA48 pour la mesure de Re({epsilon}'/{epsilon})

    Energy Technology Data Exchange (ETDEWEB)

    Ocariz, Jose [Lab. de l' Accelerateur Lineaire, Paris-11 Univ., 91 - Orsay (France)

    1999-04-19

    The purpose of the NA48 experiment is the study of direct violation of CP symmetry in the system of neutral kaons. The double ratio of neutral and charged two pion decays, violating and conserving CP should be measured with an ultimate accuracy of about 0.1%. In attain this objective one of the important ingredients is the liquid krypton calorimeter, which allows to identify the neutral modes with a very good accuracy. One should therefore ensure that the systematic effects are weak. The performances of this calorimeter, particularly in energy response, are studied with data acquired in 1997. These studies are mainly effected for the K{sub e3} semileptonic decays by comparing the energy reconstructed in the calorimeter with the momentum obtained by the magnetic spectrometer. These data allow to constrain significantly the energy resolution, the response non-linearity as well as the detector geometry and to optimize the calibration. The energy resolution achieved is better than 1% for energies above 25 GeV. This allows to reduce the background in the neutral mode at the level of 0.1%. The systematic uncertainties from calorimeter on the measurement of double ratio are estimated for the 1997 data at 0.1%. This value is clearly below the statistical error of 0.27% for these data.

  13. The CMS electromagnetic calorimeter for the Higgs boson search H {yields} ZZ{sup *} {yields} 4e at the LHC; Le calorimetre electromagnetique de CMS pour la recherche du boson de higgs, H {yields} ZZ{sup *} {yields} 4e au LHC

    Energy Technology Data Exchange (ETDEWEB)

    Ferri, F

    2006-01-15

    The work presented in this thesis has focused on the electromagnetic calorimeter (ECAL) of the CMS (Compact Muon Solenoid) detector and on its relevance in the discovery of the Higgs boson in the channel H {yields} ZZ{sup *} {yields} 4e, for which the performance of ECAL is essential. The calorimeter has been studied in detail with test beam data and with simulated data using a complete description of the CMS detector. The test beam studies have been directed to the analysis of the electronic noise and to the amplitude reconstruction of the signal acquired from the calorimeter. A procedure to evaluate the spectral power density of the signals has been determined using the maximum entropy method. Using the full CMS detector simulation, a detailed study of the electron reconstruction inside CMS has pointed out the problems which affect the measurements of the electron energy with the calorimeter. A particular case has been given to electrons of low transverse momentum (p{sub T} < 30 GeV/c) for which these effects are crucial. Namely the Bremsstrahlung effect, which is due to the tracking material in front of the calorimeter and constitutes the major problem, has been examined in depth. These results have been applied in the analysis of the Higgs boson signal in the channel H {yields} ZZ{sup *} {yields} 4e, where the electron and positron coming from the Z with the lowest mass have typically low transverse momentum. A neural network analysis extended to mass points ranging from 115 GeV/c{sup 2} shows that a discovery claim could be made in this channel for Higgs masses between 130 GeV/c{sup 2} and 145 GeV/c{sup 2} and greater than 185 GeV/c{sup 2}. (A.C.)

  14. Blood Plasma Thermograms Dataset Analysisby Means of InterCriteria and Correlation Analyses for the Case of Colorectal Cancer

    Directory of Open Access Journals (Sweden)

    Svetla Todinova

    2016-03-01

    Full Text Available The approaches of InterCriteria Analysis and Correlation Analysis are applied to a dataset of calorimetric and statistical parameters obtained from blood plasma proteome thermograms of colorectal cancer patients. The analysis was performed for four individual predefined subsets of calorimetric profiles. Specific interrelations between the studied criteria were identified that were found to differ among the different calorimetric subsets. For three of the subsets the enthalpy of the thermal profiles was in strong consonance with the excess heat capacity of the immunoglobulins assigned thermal transition. For the calorimetric subsets that differed most from the control healthy set a strong interrelation between the excess heat capacities of the main plasma proteins (albumin and immunoglobulins was additionally evident. Our results demonstrate that these mathematical approaches can complement the analysis of calorimetric datasets generated for a variety of diseases.

  15. Stability of the response and dependence of the optical signal as function of dose rate of the alanine gel dosimeter for electron clinic beams; Estabilidade da resposta e dependencia do sinal optico em funcao da taxa de dose do dosimetro alanina gel para feixes clinicos de eletrons

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Cleber Feijo; Dias, Daniel Menezes; Campos, Leticia Lucente, E-mail: cfsilva@ipen.b, E-mail: dmdias@ipen.b, E-mail: lcrodri@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2009-07-01

    This work evaluates the stability of response and the dependence on the optical response of dose rate of the alanine gel solution developed at the IPEN, Sao Paulo, Brazil, for possible future usage as 3D dosemeter in the medical area, as the area is lack of measure instrumentation for three dimension dose

  16. Absorbed dose determination in photon fields using the tandem method

    CERN Document Server

    Marques-Pachas, J F

    1999-01-01

    The purpose of this work is to develop an alternative method to determine the absorbed dose and effective energy of photons with unknown spectral distributions. It includes a 'tandem' system that consists of two thermoluminescent dosemeters with different energetic dependence. LiF: Mg, Ti, CaF sub 2 : Dy thermoluminescent dosemeters and a Harshaw 3500 reading system are employed. Dosemeters are characterized with sup 9 sup 0 Sr- sup 9 sup 0 Y, calibrated with the energy of sup 6 sup 0 Co and irradiated with seven different qualities of x-ray beams, suggested by ANSI No. 13 and ISO 4037. The answers of each type of dosemeter are adjusted to a function that depends on the effective energy of photons. The adjustment is carried out by means of the Rosenbrock minimization algorithm. The mathematical model used for this function includes five parameters and has a gauss and a straight line. Results show that the analytical functions reproduce the experimental data of the answers, with a margin of error of less than ...

  17. Radiation exposure management systems at Baltimore Gas and Electric`s Clavert Cliffs Nuclear Power Plant

    Energy Technology Data Exchange (ETDEWEB)

    Stallings, G.B. [Baltimore Gas and Electric Co., Lusby, MD (United States). Calvert Cliffs Nuclear Power Plant; Fletcher, R.J. [Siemens Environmental Systems Ltd. (United Kingdom)

    1995-12-31

    This paper documents how BGE has moved from traditional passive dosimetry methods to using the latest electronic systems supported by fully computerized access control and dose record management. One of the cornerstones of these developments is the Electronic Personal Dosemeter (EPD), manufactured by Siemens in the UK. (author).

  18. Alanine and TLD coupled detectors for fast neutron dose measurements in neutron capture therapy (NCT).

    Science.gov (United States)

    Cecilia, A; Baccaro, S; Cemmi, A; Colli, V; Gambarini, G; Rosi, G; Scolari, L

    2004-01-01

    A method was investigated to measure gamma and fast neutron doses in phantoms exposed to an epithermal neutron beam designed for neutron capture therapy (NCT). The gamma dose component was measured by TLD-300 [CaF2:Tm] and the fast neutron dose, mainly due to elastic scattering with hydrogen nuclei, was measured by alanine dosemeters [CH3CH(NH2)COOH]. The gamma and fast neutron doses deposited in alanine dosemeters are very near to those released in tissue, because of the alanine tissue equivalence. Couples of TLD-300 and alanine dosemeters were irradiated in phantoms positioned in the epithermal column of the Tapiro reactor (ENEA-Casaccia RC). The dosemeter response depends on the linear energy transfer (LET) of radiation, hence the precision and reliability of the fast neutron dose values obtained with the proposed method have been investigated. Results showed that the combination of alanine and TLD detectors is a promising method to separate gamma dose and fast neutron dose in NCT.

  19. Estimation of staff lens doses during interventional procedures. Comparing cardiology, neuroradiology and interventional radiology.

    Science.gov (United States)

    Vano, E; Sanchez, R M; Fernandez, J M

    2015-07-01

    The purpose of this article is to estimate lens doses using over apron active personal dosemeters in interventional catheterisation laboratories (cardiology IC, neuroradiology IN and radiology IR) and to investigate correlations between occupational lens doses and patient doses. Active electronic personal dosemeters placed over the lead apron were used on a sample of 204 IC procedures, 274 IN and 220 IR (all performed at the same university hospital). Patient dose values (kerma area product) were also recorded to evaluate correlations with occupational doses. Operators used the ceiling-suspended screen in most cases. The median and third quartile values of equivalent dose Hp(10) per procedure measured over the apron for IC, IN and IR resulted, respectively, in 21/67, 19/44 and 24/54 µSv. Patient dose values (median/third quartile) were 75/128, 83/176 and 61/159 Gy cm(2), respectively. The median ratios for dosemeters worn over the apron by operators (protected by the ceiling-suspended screen) and patient doses were 0.36; 0.21 and 0.46 µSv Gy(-1) cm(-2), respectively. With the conservative approach used (lens doses estimated from the over apron chest dosemeter) we came to the conclusion that more than 800 procedures y(-1) and per operator were necessary to reach the new lens dose limit for the three interventional specialties.

  20. Optimization approach within an interventional radiology department; Demarche d'optimisation au sein d'un service de radiologie interventionnelle

    Energy Technology Data Exchange (ETDEWEB)

    Mozziconacci, J.G.; Brot, A.M. [Centre Hospitalier de Bourges, PCR, 18 (France); Jarrige, V. [Centre Hospitalier de Bourges, PSRPM, 18 (France)

    2009-07-01

    The authors present an approach aimed at optimizing working conditions and radioprotection for the different actors in interventional radiology. This approach comprises a monitoring of personnel dosimetry, a workstation analysis with risk assessment, and the taking into account of patient dosimetry. For each of these aspects, the authors discuss procedures and available devices (dosemeters and other detection or dose measurement equipment)

  1. The interventional radiology: means of reduction and optimization of medical personnel exposure; La radiologie interventionnelle: moyens de reduction et d'optimisation de l'exposition du personnel medical

    Energy Technology Data Exchange (ETDEWEB)

    Maccia, C. [Centre d' Assurance de Qualite des Applications Technologiques dans le Domaine de la Sante, CAATS, 92 - Bourg-la-Reine (France); Vano, E.; Gonzalez, L.; Guibelalde, E. [Faculdad de Medicina, Universidad de Madrid (Spain)

    1998-07-01

    The measures envisaged to make an optimization of the radiation protection are in the use of materials adapted to the situation, the use of dosemeters devoted to the doses evaluation for particularly sensitive organs , the introduction of ophthalmic examinations and finally, the information and training of every category of personnel in radiation protection. (N.C.)

  2. Evaluation of the absorbed dose in odontological computerized tomography; Avaliacao da dose absorvida em tomografia computadorizada odontologica

    Energy Technology Data Exchange (ETDEWEB)

    Legnani, Adriano; Schelin, Hugo R.; Rocha, Anna Silvia P.S. da, E-mail: schelin@utfpr.edu.b, E-mail: anna@utfpr.edu.b [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil); Khoury, Helen J., E-mail: khoury@ufpe.b [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil)

    2011-10-26

    This paper evaluated the absorbed dose at the surface entry known as 'cone beam computed tomography' (CBCT) in odontological computerized tomography. Examination were simulated with CBCT for measurements of dose. A phantom were filled with water, becoming scatter object of radiation. Thermoluminescent dosemeters were positioned on points correspondent to eyes and salivary glands

  3. National Laboratory of Ionizing Radiation Metrology - Brazilian CNEN; Laboratorio Nacional de Metrologia das Radiacoes Ionizantes

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-12-31

    The activities of the Brazilian National Laboratory of Ionizing Radiations Metrology are described. They include research and development of metrological techniques and procedures, the calibration of area radiation monitors, clinical dosemeters and other instruments and the preparation and standardization of reference radioactive sources. 4 figs., 13 tabs.

  4. Recovery of α-Al{sub 2}O{sub 3} from ionizing radiation dosimetric sensors

    Energy Technology Data Exchange (ETDEWEB)

    Sanches, Edgar Aparecido, E-mail: sanches.ufam@gmail.com [Universidade Federal do Amazonas (UFAM), Manaus, AM (Brazil). Dept. de Fisica; Costalonga, Ademir Geraldo Cavallari; Mascarenhas, Yvonne Primerano [Universidade de Sao Paulo (IFSC/USP), Sao Carlos, SP (Brazil). Institute de Fisica; Nascimento, Luana de Freitas [Belgium Nuclear Research Centre, SCK-CEN, Mol (Belgium); Mascarenhas, Yvone Maria [SAPRA S/A Servico de Assessoria e Protecao Radiologica, Sao Carlos, SP, (Brazil)

    2015-01-15

    Corundum, sapphire or α-Al{sub 2}O{sub 3} is an important technological material in many optical and electronic applications such as solid-state lasers, optical windows and, more recently, as a radiation detector. Landauer (Glenwood, IL, USA) accumulated large number of archived and stored Luxel™ dosemeters composed of Al{sub 2}O{sub 3}:C, which were subjected to a recovery process. Due to the importance of this advanced crystalline material in OSL dosimetry, a recovery process was developed based on the dosemeters calcination and Al{sub 2}O{sub 3}:C has been reused in manufacturing of new dosemeters. This paper does not aim to optimize the recovery process, but provides an opportunity to study the involved process parameters and to recover this valuable crystalline material from used dosemeters. To the best of our knowledge no other recovery process involving this dosimetric material was described in scientific literature. Fourier Transform Infrared Spectrometry (FTIR), Thermogravimetry/Differential Thermoanalysis (TG/DTA), Differential Scanning Calorimetry (DSC), X-ray Diffraction (XRD), Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES), Optically Stimulated Luminescence (OSL) and Rietveld Refinement were used to characterize the recovered material and to check for the stability of its structural and dosimetric properties. (author)

  5. Dosimetric study of Na{sub 2}CO{sub 3} by Electron Paramagnetic Resonance; Estudio dosimetrico del Na{sub 2}CO{sub 3} por Resonancia Paramagnetica Electronica

    Energy Technology Data Exchange (ETDEWEB)

    Urena N, F.; Davila B, M.R. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2007-07-01

    Full text: In this work the evaluation of the sodium carbonate, Na{sub 2}CO{sub 3}, for the Electron Paramagnetic Resonance technique, (RPE), to be used as dosemeter in the determination of gamma radiation dose was carried out. The studied parameters were: Response to zero dose; radiosensitivity; intensity of the signal peak to peak vs. dose (linearity); dependence of the dose velocity; repeatability; homogeneity; dissipation of the signal ('fading') and stability of the dosemeters to different environmental conditions. The Na{sub 2}CO{sub 3} when being irradiated with electromagnetic radiation produces free radicals CO{sub 3}{sup 2-} that give place to a RPE signal. The dosemeters without irradiating didn't present RPE signal, the detection limit of radiosensitivity it was of 10 Gy, however the work curve settled down in a range from 20 Gy to 20 kGy. It was found that the Na{sub 2}CO{sub 3} dosemeters present an excellent repeatability and homogeneity, as well as a good stability to normal environmental conditions, by what it can conclude that the dosimetric system Na{sub 2}CO{sub 3}-RPE is reliable for the dose determination of electromagnetic radiation at different levels. (Author)

  6. Viability evaluation of the reading system by CCD for application at the Fricke xylenol gel dosimetry developed by IPEN-Sao Paulo, Brazil; Avaliacao de viabilidade do sistema de leitura por CCD para aplicacao na dosimetria Fricke xilenol gel desenvolvido no IPEN-Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Mangueira, Thyago Fressatti; Dias, Daniel Menezes; Campos, Leticia Lucente, E-mail: thyagomangueira@usp.b, E-mail: dmdias@ipen.b, E-mail: lcrodri@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2009-07-01

    The use of chambers with coupled charge devices - CCD, is already used by research centres for the dose evaluation applying the Fricke xylenol gel dosemeter. This work evaluates the application of this optical reading technique for the FXG developed at the IPEN, Sao Paulo, Brazil

  7. Alanine/RPE dosimetry in the process of blood irradiation; Dosimetria alanina/RPE en el proceso de irradiacion de sangre

    Energy Technology Data Exchange (ETDEWEB)

    Chen, F.; Covas, D.T.; Baffa, O. [Departamento de Fisica e Matematica, FFCLRP, Universidade de Sao Paulo, 14040-901 Ribeirao Preto-SP (Brazil)

    2000-07-01

    A set of eighty dosemeters approximately of Dl- alanine was proportioned to the Hemo center of Hospital das Clinicas of Medicine Faculty at Ribeirao Preto (HC-FRMP) in the Sao Paulo University, with the purpose to realize a quality control of the radiation dose supplied to blood bags. These dosemeters were divided in eight groups and irradiated for a two months period.The dosemeters were adhered to the bags and arranged inside of an acrylic box filled water with dimensions: (40x40x20) cm{sup 3}. The box irradiation was made using two fields parallel-opposed of (40x40) cm{sup 2} at 80 cm distance source-surface, in the Radiotherapy Service of HC-FMRP, with a {sup 60} Co teletherapy unit. The irradiation time was sufficient to supply a dose of 20 Gy approximately in the box center. The RPE measures were realized in a Varian E-4 spectrometer operating in X-band. For the total of dosemeters and for the irradiation volume, the minimum and maximum doses were of 14 Gy and 23 Gy respectively. The mean dose was (18{+-}2) Gy (1 {sigma}), and the variability coefficient 11 %. Around 5 % of the bags received a dose under of the recommended limit by the Brazilian legislation and as consequence, the exposure time was increased. (Author)

  8. Retrospective dosimetry in irradiated foods; Dosimetria retrospectiva en alimentos irradiados

    Energy Technology Data Exchange (ETDEWEB)

    Calderon, T. [Universidad Autonoma de Madrid, Facultad de Ciencias, Dpto. Quimica Agricola, Geologia, Geoquimica, Cantoblanco, Madrid (Spain)

    1999-07-01

    The main objective of this communication is to show the potentiality of certain minerals which accompany the foods (grasses, spices and seasonings) as potential dosemeters and its possible application in the absorbed dose calculations by the same in its hygienic sanitary treatment. (Author)

  9. Remote system for measurement of radon alpha emitter for population safety guards; Sistema remoto de medicion de radon alfa emisor para la salvaguarda poblacional-3599

    Energy Technology Data Exchange (ETDEWEB)

    Jesus, Vasquez, E-mail: jesus.vasguez@lnl.infn.it [Istituto Nazionale di Fisica Nucleare, Legnaro (Italy). Laboratorio Nazionale di Legnaro; Sajo-Bohus, Laszlo; Palacios, Daniel; Barros, Haydn, E-mail: sajobohus@gmail.com, E-mail: sanjuro.perdomo@gmail.com, E-mail: lab.nuclear@gmail.com [Universidad Simon Bolivar (USB), Caracas (Venezuela, Bolivarian Republic of). Laboratorio de Fisica Nuclear

    2013-07-01

    The objective of this research project is to study the OSL properties for high doses of dosemeters traditionally applied in thermoluminescent dosimetry (TL), as CaF2: Dy (TLD 200) and CaF2: Mn (TLD 400), and thus verify the applicability of OSL technique in high-dose dosimetry.

  10. Tl response of LiF: Mg, Cu, P+Ptfe at X rays of 24, 42 and 100 KeV; Respuesta TL de LiF: Mg, Cu, P+Ptfe a rayos X de 24, 42 y 100 KeV

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez M, P.R.; Tovar M, V.M. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico); Azorin N, J. [UAM-I, 09340 Mexico D.F. (Mexico); Furetta, C. [Universita degli Studi di Roma ' La Sapienza' , Piazzale Aldo Moro 2, 00185 Roma (Italy); Quiroz C, M.C. [Facultad de Medicina, UAEM, 50180 Toluca, Estado de Mexico (Mexico)

    2005-07-01

    In this work the obtained results of the irradiation of thermoluminescent dosemeters (Tl) of LiF: Mg,Cu,P + Ptfe with X rays for the effective radiation energy of 24, 42 and 100 keV, in an interval of Kerma in air in the sinus of the air between 0.05 and 1.0 Gy are presented. The rate of Kerma in air was determined with an ionization chamber PTW-1152, gauged by the Laboratoire Central des Industries Electriques (LCIE). As reference commercial TLD-100 dosemeters was used. The results showed that the studied Tl dosemeters presented a lineal response in the interval of mentioned Kerma. On the other hand the estimated Kerma with the Tl dosemeter in the calibration curves for X rays, were similar to the one measured with the previously gauged ionization chamber. The Tl of LiF: Mg, Cu, P + Ptfe, developed in the ININ, are highly reliable for X-ray dosimetry. (Author)

  11. Report of safety of the characterizing system of radioactive waste; Informe de seguridad del sistema caracterizador de desechos radiactivos

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Jimenez D, J.; Reyes L, J. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    1998-09-15

    Report of safety of the system of radioactive waste of the ININ: Installation, participant personnel, selection of the place, description of the installation, equipment. Proposed activities: operations with radioactive material, calibration in energy, calibration in efficiency, types of waste. Maintenance: handling of radioactive waste, physical safety. Organization: radiological protection, armor-plating, personal dosemeter, risks and emergency plan, environmental impact, medical exams. (Author)

  12. Web based dosimetry system for reading and monitoring dose through internet access

    Energy Technology Data Exchange (ETDEWEB)

    Perle, S.C.; Bennett, K.; Kahilainen, J.; Vuotila, M. [Mirion Technologies (United States); Mirion Technologies (Finland)

    2010-07-01

    The Instadose{sup TM} dosemeter from Mirion Technologies is a small, rugged device based on patented direct ion storage technology and is accredited by the National Voluntary Laboratory Accreditation Program (NVLAP) through NIST, bringing radiation monitoring into the digital age. Smaller than a flash drive, this dosemeter provides an instant read-out when connected to any computer with internet access and a USB connection. Instadose devices provide radiation workers with more flexibility than today's dosemeters. Non Volatile Analog Memory Cell surrounded by a Gas Filled Ion Chamber. Dose changes the amount of Electric Charge in the DIS Analog Memory. The total charge storage capacity of the memory determines the available dose range. The state of the Analog Memory is determined by measuring the voltage across the memory cell. AMP (Account Management Program) provides secure real time access to account details, device assignments, reports and all pertinent account information. Access can be restricted based on the role assignment assigned to an individual. A variety of reports are available for download and customizing. The Advantages of the Instadose dosemeter are: - Unlimited reading capability, - Concerns about a possible exposure can be addressed immediately, - Re-readability without loss of exposure data, with cumulative exposure maintained. (authors)

  13. Stability of the post irradiation traps in LiF: Mg, Cu, P; Estabilidad de las trampas posradiacion en LiF: Mg, Cu, P

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, P.R. [ININ, A.P. 18-1027, 11801 Mexico D.F. (Mexico); Furetta, C. [Physics Department, Rome University ' ' La Sapienza' ' , Rome (Italy); Azorin, J. [UAM-I, 09340 Mexico D.F. (Mexico)

    2004-07-01

    In this work the results of the study of the stability of the traps are presented in dosemeters Tl of LiF: Mg,Cu,P, irradiated with gamma radiation of {sup 60} Co. The studied dosemeters were of LiF: Mg,Cu,P + Ptfe, developed in the ININ, taking like reference to the commercial dosemeter GR200A of Chinese manufacture. Before being exposed to the radiation, the dosemeters received their standard treatment from having erased, two hours after the irradiation they took the initial readings. The dosemeters faded again and they were irradiated to the same dose, soon after they stayed under normal conditions, protected of the light, later on they were taken their readings periodically during six months. The readings taken Tl the same day of the irradiation presented four peaks whose energy, determined by the deconvolution method were; 1.30 {+-} 0.01 eV, 1.50 {+-} 0.01 eV, 1.70 {+-} 0.01 eV and 2.58 {+-} 0.02 eV, for LiF: Mg,Cu,P + Ptfe, while GR200A stops the energy they were: 1.33 {+-} 0.11 eV, 1.58 {+-} 0.11 eV, 1.73 {+-} 0.11 eV and 2.60 {+-} 0.03 eV. In both cases the peak 1, with the energy but it lowers, it disappears completely after some later hours to the irradiation, while the peak 2, it disappears completely after 122 days for the local dosemeter and after 94 days for the commercial dosemeter. The energy of the peaks 3 and 4 that remained visible during the whole period of study it was: 1.38 {+-} 0.01 eV and 2.65 {+-} 0.01 eV, for LiF: Mg,Cu,P + Ptfe respectively, in the same order for GR200A, the energies were: 1.51 {+-} 0.02 eV and 2.64 {+-} 0.03 eV. In all the cases the peaks with energy below 2 eV, showed tendency to the drop, while the main peak, showed certain tendency to increase, as they show it the results. (Author)

  14. Personal dose equivalent angular response factors for photons with energies up to 1 GeV.

    Science.gov (United States)

    Veinot, K G

    2013-04-01

    When performing personal dosemeter calibrations, the dosemeters are typically irradiated while mounted on slab-type phantoms and oriented facing the source. Performance testing standards or intercomparison studies may also specify various rotational angles to test the response of the dosemeter and associated algorithm as this rotation introduces changes in the quantity of delivered dose. Correction factors for rotational effects are available, but many have not been updated in recent years and were typically calculated using the kerma approximation. The personal dose equivalent, Hp(d), is the quantity recommended by the International Commission on Radiation Units and Measurements to be used as an approximation of the protection quantity effective dose when performing personal dosemeter calibrations. The personal dose equivalent can be defined for any location and depth within the body, but typically the location of interest is the trunk where personal dosemeters are worn and in this instance a suitable approximation is a 30 cm × 30 cm × 15 cm slab-type phantom. In this work personal dose equivalent conversion coefficients for photons with energies up to 1 GeV have been calculated for depths of 0.007, 0.3 and 1.0 cm in the slab phantom for rotational angles ranging from 15° to 75°. Angular response factors have been determined by comparing the conversion coefficients for each angle and energy to those reported in an earlier work for a non-rotational (e.g. perpendicular to the phantom face) geometry. The angular response factors were determined for discrete angles, but fits of the factors are provided.

  15. Measurement of dose equivalent with personal dosemeters and instrumentation of radiological protection in the new operative ICRU magnitudes, for external fields of beta radiation. Part III. Determination of the joint of factors of angular conversion for the secondary source pattern Nr. - 86 Of (1850) MBq; Medicion de dosis equivalente con dosimetros personales e instrumentacion de proteccion radiologica en las nuevas magnitudes operativas ICRU, para campos de radiacion Beta externos. Parte III. Determinacion del conjunto de factores de conversion angular para la fuente patron secundario Nr.- 86 de (1850) MBq

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez R, J.T. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    1994-02-15

    It determined the assembly of factors of angular conversion T(0;{alpha}), for the source secondary pattern of {sup 90}Sr/{sup 90}Y (1850 MBq) at a distance detecting source of 30 cm, in the following angles: 0, 15, 30, 45, 60 and 75{sup 0}. Obtaining the values of: 1.01, 1.05, 1.13, 1.19 and 0.95, respectively. Their Global uncertainty is smaller to 1.5% for all the cases and its percentage differences with regard to the values reported by the Draft of the norm ISO 6980(1992) they are smaller to 3.0% for all the cases.The technique employee was that of the extrapolation Chamber and the treatment of the uncertainties is made of agreement with the recommendations of the BIPM. (Author)

  16. Electrical stimulation of the ventromedial hypothalamus enhances both fat utilization and metabolic rate that precede and parallel the inhibition of feeding behavior

    NARCIS (Netherlands)

    Ruffin, MP; Nicolaidis, S

    1999-01-01

    The effects of ventromedial hypothalamic (VMH) stimulation on various metabolic parameters in freely moving animals were measured using a specific indirect calorimetric chamber associated with a quantitative measurement of locomotor activity, which allows the separate measurement of locomotor energy

  17. Phase diagrams of lipid mixtures relevant to the study of membrane rafts

    DEFF Research Database (Denmark)

    Goni, Felix; Alonso, Alicia; Bagatolli, Luis

    2008-01-01

    The present paper reviews the phase properties of phosphatidylcholine-sphingomyelin-cholesterol mixtures, that are often used as models for membrane "raft" microdomains. The available data based on X-ray, microscopic and spectroscopic observations, surface pressure and calorimetric measurements, ...

  18. Calorimetry for Fast Authentication of Edible Oils

    Science.gov (United States)

    Angiuli, Marco; Bussolino, Gian Carlo; Ferrari, Carlo; Matteoli, Enrico; Righetti, Maria Cristina; Salvetti, Giuseppe; Tombari, Elpidio

    2009-06-01

    There are little data in the literature on how to authenticate edible oils through calorimetry techniques. However, oil melting curves can be used to represent correlations between calorimetric results and oil quality. A calorimetric method has been developed for studying the solid-liquid phase transitions of olive oil and seed oils, in which melting peak behavior is correlated to the type, quality, and composition of the oil. Good reproducible thermograms were obtained by defining precise protocols for use in testing, which take into account the specific characteristics of a particular oil. This approach does not replace classical analytical methods; nevertheless, it is believed that calorimetric tests could be a useful preliminary stage for quality testing. The calorimetric technique allows the detection of the adulterant (seed oils or refined olive oil), oil origin, and possible photo-oxidation degradation processes, before more complex and expensive procedures and analyses are applied.

  19. Dosimetry at a 400 keV accelerator

    DEFF Research Database (Denmark)

    Miller, A.

    1992-01-01

    Absolute calorimetric dosimetry and relative dose mapping methods are described for a 400 keV electron accelerator used for polymer curing and crosslinking experiments. These methods of dosimetry are also useful at accelerators used in gas cleaning processes.......Absolute calorimetric dosimetry and relative dose mapping methods are described for a 400 keV electron accelerator used for polymer curing and crosslinking experiments. These methods of dosimetry are also useful at accelerators used in gas cleaning processes....

  20. Thermal flow micro sensors

    OpenAIRE

    Elwenspoek, M.

    1999-01-01

    A review is given on sensors fabricated by silicon micromachining technology using the thermal domain for the measurement of fluid flow. Attention is paid especially to performance and geometry of the sensors. Three basic types of thermal flow sensors are discussed: anemometers, calorimetric flow sensors and time of flight flow sensors. Anemometers may comprise several heaters and temperature sensors and from a geometric point of view are similar sometimes for calorimetric flow sensors. We fi...