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Sample records for calmado al aluminio

  1. Evolución de la microestructura y de las propiedades mecánicas durante el recocido isotérmico de un acero de 0,04 % C calmado al aluminio

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    Millán, J.

    2005-12-01

    Full Text Available The effect of heating rate and annealing time on the microstructure and mechanical properties of a commercial 0.04 % C Al-killed steel, cold rolled up to 80% is evaluated in the present study. For this purpose samples were isothermally annealed at various heating rates (12, 20, 40 and 650 °C/min and then soaked at 700°C for 15 h. The microstructural evolution of the samples during the heating process and holding temperature was evaluated by optical microscopy, scanning and transmission electron microscopy. Tensile mechanical properties and hardness measurements were also correlated with the microstructural features. Results showed that with soaking time greater than 6 h, the mechanical properties specified for the material are reached, even though, appropriate plastic anisotropy values were only obtained in samples heated at low rates, where a "pancake" type of structure is also formed.

    Se evaluó el efecto de la velocidad de calentamiento y el tiempo de recocido a 700 °C sobre la microestructura y las propiedades mecánicas de un acero de 0,04 % C calmado al aluminio, con un porcentaje de reducción en frío de 80 %. En tal sentido, muestras de este material fueron sometidas a velocidades de calentamiento de 12, 20, 40 y 650 °C/min y, después, maritenidas por un máximo de 15 h a 700 °C. La evolución microestructural de las muestras durante las etapas de calentamiento y mantenimiento a 700 °C se evaluó mediante microscopía óptica, microscopía electrónica de barrido y transmisión. Las propiedades mecánicas de tracción y dureza se correlacionaron con las características microestructurales observadas. Los resultados mostraron que, con tiempos de mantenimiento a 700 °C superiores a 6 h, se logran obtener las propiedades mecánicas requeridas del producto. No obstante, los valores adecuados de anisotropía plástica se obtuvieron, solamente, en muestras calentadas a bajas velocidades, donde, además, se formaba una

  2. aluminio

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    A. Peña

    2005-01-01

    Full Text Available Se pretende estudiar el efecto del consumo de la cerveza, como fuente de ácido silícico, sobre la biodisponibilidad del aluminio, así como su posible relación en la prevención de la neurotoxicidad de este metal. En una primera etapa se ha analizado la influencia de la cerveza en la cinética de absorción y eliminación del aluminio dietético en ratones machos, en un tratamiento de 3 días de duración. Se utilizaron dos tipos de cerveza: con y sin alcohol, y a dos dosis diferentes, una equivalente a un consumo moderado-bajo en el hombre (0.5 L/día, y otra a moderado-alto (1 L/día, suministrada por cánula esofágica. El aluminio fue determinado por espectrometría de masas de plasma acoplado inductivamente y, el contenido en silicio, por espectrometría de emisión atómica de plasma acoplado inductivamente. Los resultados obtenidos parecen indicar que la suplementación de cerveza, especialmente la cerveza con alcohol y a dosis moderada alta, parece influir sobre la toxicocinética del aluminio presente en la dieta, a través de su contenido en silicio: éste podría limitar la absorción del aluminio en el tracto gastrointestinal, incrementando su excreción por vía fecal. Por tanto, la cerveza podría ejercer un papel protector frente a la toxicidad del aluminio a través de la dieta

  3. Tolerancia de cinco leguminosas al aluminio en solución nutritiva.

    OpenAIRE

    Pérez N Juan Carlos; Osorio V Nelson Walter; Lotero C. Jaime

    2011-01-01

    Se realizó una investigación para determinar el grado de tolerancia a aluminio (Al) de cinco leguminosas tropicales: guandul (Cajanus cajan L. Mills), canavalia (Canavalia ensiformis L.), frijol jacinto (Dolichos lablab L.), leucaena (Leucaena leucocephala (C. Lam.) De Witt) y fríjol terciopelo (Stizolobium deeringianum Bort.). Las plantas crecieron bajo cinco concentraciones de Al: 0, 2, 4, 8 y 16 mg L-1 en solución nutritiva. La leguminosa más afectada por las concentraciones de Al fue L. l...

  4. Tolerancia de cinco leguminosas al aluminio en solución nutritiva.

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    Pérez N Juan Carlos

    2003-06-01

    Full Text Available Se realizó una investigación para determinar el grado de tolerancia a aluminio (Al de cinco leguminosas tropicales: guandul (Cajanus cajan L. Mills, canavalia (Canavalia ensiformis L., frijol jacinto (Dolichos lablab L., leucaena (Leucaena leucocephala (C. Lam. De Witt y fríjol terciopelo (Stizolobium deeringianum Bort.. Las plantas crecieron bajo cinco concentraciones de Al: 0, 2, 4, 8 y 16 mg L-1 en solución nutritiva. La leguminosa más afectada por las concentraciones de Al fue L. leucocephala, la cual exhibió una disminución significativa en la producción de materia seca y en la traslocación de P hacia la parte aérea. En las otras leguminosas la materia seca y la distribución de P fueron poco afectados.

  5. Revisión de los estudios sobre exposición al aluminio y enfermedad de Alzheimer

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    Suay Llopis Loreto

    2002-01-01

    Full Text Available Se ha llevado a cabo una revisión bibliográfica de los estudios epidemiológicos que han evaluado el papel del aluminio como factor de riesgo para el desarrollo de la enfermedad de Alzheimer. Se realizó una búsqueda bibliográfica en la base de datos MedLine combinando los términos del Thesaurus "Aluminum" y "Alzheimer´s disease". En la mayor parte de los estudios revisados se ha examinado la exposición al metal a través del agua de bebida. Los estudios que sugieren que existe una asociación entre el aluminio y la enfermedad presentan riesgos relativos de alrededor de 2 para poblaciones con exposiciones a concentraciones de Al en el agua mayores de 0,1 mg/l. Las exposiciones al metal a través de otras vías (alimentación, medicamentos y exposición laboral han sido poco estudiadas. Estos estudios epidemiológicos presentan limitaciones metodológicas y sus resultados no son consistentes por lo que los resultados disponibles hasta el momento no permiten establecer, de manera clara, que exista una asociación entre la exposición al metal y la etiología de la enfermedad de Alzheimer. No obstante, tampoco es posible descartar un papel tóxico del aluminio sobre la salud, por lo que su exposición debería ser controlada y reducida en lo posible.

  6. Alternativas al cromo en la industria del acabado superficial del aluminio. Tratamientos superficiales de bajo impacto ambiental

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    Aballe Villero, Álvaro

    2001-02-01

    Full Text Available Chromates are one of the most commonly used compounds in anticorrosive protection systems because of its excellent rate efficiency/cost. In the case of aluminium alloys, these compounds are employed as inhibitors as well as in the anticorrosive pretreatments to develop protective films. However, chromates are highly toxic and its use involves a high risk for health and environment. Consequently, in the last years intensive efforts have been achieved in the surface treatment industry to find ecological alternatives to this kind of compounds. In this work, the main alternatives proposed in literature to substitute chromates in the surface treatments of aluminium alloys are reviewed. To begin with, the role of chromates in these systems and their environmental consequences has been briefly reviewed.

    Los cromatos son unas de las sustancias más comúnmente empleadas en los sistemas de protección frente a la corrosión de aleaciones metálicas, debido a su excelente relación eficacia/coste. En el caso de las aleaciones de aluminio, estos compuestos se aplican tanto como inhibidores, incorporados al medio agresivo, como en pretratamientos anticorrosivos para la formación de películas protectoras. Sin embargo, los cromatos son altamente tóxicos y su uso conlleva un elevado riesgo para la salud laboral y el medio ambiente. Por esta razón, dentro de la industria del acabado superficial, en los últimos tiempos, se ha venido realizando un intenso esfuerzo para buscar alternativas ecológicamente aceptables a este tipo de compuestos. En este trabajo se revisan las principales alternativas planteadas en la bibliografía para sustituir a los cromatos en los tratamientos superficiales de las aleaciones de aluminio. Como punto de partida, se ha llevado a cabo un breve repaso al papel que juegan los cromatos en los sistemas de protección frente a la corrosión y las implicaciones medioambientales que conlleva su uso.

  7. Corrosión por picaduras del aluminio y de la aleación Al-6201 en soluciones de NaCl

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    Vera, R.

    1998-06-01

    Full Text Available The susceptibility of pure aluminum and aluminum 6201 alloy to pitting was investigated in sodium chloride solutions through determination of the corrosion, repassivation and pitting potentials. Potentiodynamic polarization including scratching techniques were employed being also determined the type and relative amount of corrosion damage to the metals. The morphology of the attack was determined using scanning electron microscopy (SEM. The results showed a similar performance for aluminum 6201 alloy and aluminum. It was also observed that an increase in chloride concentration resulted in a decrease in the corrosion, pitting and repassivation potentials of both materials.

    Gran cantidad de estudios realizados sobre el comportamiento del aluminio y sus aleaciones han demostrado su excelente resistencia a diversos medios corrosivos. Sin embargo, en las líneas de transmisión de energía eléctrica de aluminio o de la aleación comercial Al-6201, instaladas en las costas de Valparaíso, Chile, se detectaron fallos del material, consistentes en picaduras profundas y roturas. En este estudio se evalúa la corrosión por picaduras sufrida por el aluminio y la aleación Al-6201, utilizando soluciones de diferentes concentraciones de NaCl que es el principal agente agresivo en ambientes marinos. Se determinaron los potenciales de corrosión (Ec, de repasivación (Er y de picado (Ep, mediante el empleo de curvas de polarización potenciodinámicas y técnica de raspado. La morfología del ataque se determinó mediante microscopía electrónica de barrido. Los resultados mostraron un comportamiento similar entre el aluminio y la aleación 6201. También se observó que el aumento en la concentración de cloruro conlleva una disminución en los potenciales de corrosión, de picaduras y de repasivación en ambos materiales.

  8. Respuesta al Desgaste de un Material de Aluminio Reforzado con Circonia Response to wear of an Aluminum Material Reinforced with Zirconia

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    Rosalba Fuentes

    2006-01-01

    Full Text Available Se desarrolló un material compuesto aluminio-circonia por metalurgia de polvos. Los polvos de circonia fueron sintetizados por sol-gel, se mezclaron con polvo de aluminio, se compactaron y se sinterizaron. El tamaño del polvo de aluminio utilizado fue menor a 100 micras. La circonia tuvo como material precursor al n-propóxido de circonio. Se prepararon varias mezclas con ambos polvos, utilizando tres proporciones de circonia de 1%, 3% y 5% en peso. Se aplico una compactación de 58 KN y se sinterizó a 610°C. Posteriormente las piezas fueron sometidas a pruebas de desgaste con objeto de analizar su respuesta. El desgaste se realizó en una máquina de pin-en-disco, con velocidad de 320 rpm y presión de desgaste 9 KN por un período de dos horas. Las pruebas de desgaste muestran el comportamiento tribológico del material compuesto observándose un au>mento de resistencia al desgaste cuando el porcentaje en peso de circonia se incrementa.An aluminum-zirconia composite was developed using powder metallurgy. Zirconia powder was synthesized by a sol-gel method, mixed with aluminum powder, and was compacted and sinterized. The particle size of the aluminum powder utilized was less than 100 microns. The precursor material of zirconia was an n-propoxide of zirconium. Different proportions of zirconia were used in three mixtures at 1%, 3% and 5% by weight. The mixtures were compacted at 58KN and were sinterized at 610°C. Subsequently, the pieces were subjected to wear resistance tests to determine their resistance. The wear test was carried out in a pin-in-disk machine at a speed of 320 rpm and load of 9 KN for a period of two hours. The wear resistance tests showed the tribologic behavior of this composite showing an increase in wear resistance when the weight percentage of zirconia increases.

  9. Fabricación y comportamiento de espumas de aluminio con diferente densidad a partir de un precursor AlSi12

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    Gutiérrez-Vázquez, J. A.

    2010-06-01

    Full Text Available Closed cell aluminium foams were prepared by powder metallurgical method in three different ranges of density using AlSi12 precursor. The objective has been to determine by means of tests the effect that has the density of these materials regarding its mechanical behaviour. The used precursor contained 0.4% of foaming agent of titanium hydride (TiH2, mixed with aluminum and silicon in appropriate amounts to achieve the commercial composition of the AlSi12 precursor. Once cut the samples thermal treatments of foaming were made of 630 °C to 750 °C, by 3 to 20 minutes. The best solidification conditions were determined to avoid the collapse by means of forced air. The samples were prepared with the same weight to different densities, having itself obtained that the best mechanical behaviour was achieved in the high density foams, of 0.70 to 0.81 g/cm3.

    Se han fabricado espumas de aluminio de poro cerrado, de tres diferentes rangos de densidad, utilizando un precursor AlSi12 producido por pulvimetalurgia. El objetivo ha sido determinar el efecto que tiene la densidad de estos materiales respecto a su comportamiento mecánico. El precursor utilizado contenía un 0,4 % de hidruro de titanio (TiH2 como agente espumante, mezclado con aluminio y silicio en cantidades adecuadas para lograr la composición comercial del precursor AlSi12. Una vez cortadas las muestras, se efectuaron tratamientos térmicos de espumación entre 630 y 750 °C, a tiempos de espumación variables entre 3 y 20 min. Se determinaron las mejores condiciones de solidificación para evitar el colapso mediante aire forzado. Las muestras se prepararon con el mismo peso a diferentes densidades, habiéndose obtenido, que el mejor comportamiento mecánico se lograba en las espumas de mayor densidad, comprendidas entre 0,70 y 0,81 g/cm3.

  10. Influencia de la composición y el tratamiento térmico en las propiedades mecánicas de aleaciones de bronce al aluminio

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    Cenoz-Echeverría, I.

    2007-08-01

    Full Text Available Aluminium bronzes are copper-base alloys containing aluminium within the limits between 5-12 %. Additions of Fe, Ni and Mn are used as alloying elements forming a family of complex alloys noted for their exceptional strength and corrosion resistance. In present paper the Ni:Fe ratio and heat treatments have been analyzed by determining the mechanical properties for three different aluminium bronze alloys containing Cu-Al10-Fe3, Cu-Al10-Fe5-Ni5 and Cu-Al10-Fe4-Ni8. The effect of as cast, quenched and quenched and tempered structures has been investigated regarding hardness, proof and ultimate tensile strength, elongation, modulus of elasticity, Poisson ratio, fracture toughness, fatigue strength, crack propagation and Charpy impact properties. The influence of temperature has been studied by testing the elastic modulus, Poisson ratio, the proof stress, tensile strength and the Charpy impact properties at –20 °C, 24 °C and 100 °C.

    Los cuproaluminios son aleaciones de cobre con contenidos de aluminio del 5-12 % que pueden incorporar hierro, níquel, y manganeso para formar una familia de aleaciones con unas excelentes propiedades de resistencia mecánica y a la corrosión. En el presente artículo se estudia el efecto que la relación Ni:Fe y que los tratamientos térmicos ocasionan en las propiedades mecánicas como dureza, límite elástico, tensión de rotura, alargamiento, módulo de elasticidad, coeficiente de Poisson, tenacidad a la fractura estática, resiliencia, fatiga y propagación de grieta. Para ello, se analizan tres aleaciones en tres estados. Las composiciones nominales son Cu-Al10-Fe3, Cu-Al10-Fe5-Ni5 y Cu- Al10-Fe4-Ni8. Las estructuras de las aleaciones son las correspondientes a: bruto de colada, temple y temple seguido de revenido. La caracterización del módulo de elasticidad y coeficiente de Poisson, así como los ensayos de tracción y resiliencia, se realizan a –20 °C, 24 °C y 100 °C.

  11. Determinación de los mecanismos de fractura de un material multicapa de aluminio de alta resistencia y excelente tenacidad a impacto basado en la aleación aeroespacial Al 7075

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    Cepeda-Jiménez, C. M.

    2012-08-01

    Full Text Available An aluminium multilayer laminate has been processed by hot rolling. It is constituted by 19 alternated layers of high-strength aluminium alloy (Al 7075-T6, 82 % vol and thinner pure aluminium layers (Al 1050-H24, 18 % vol. The microstructure of the constituent alloys and the composition gradient across the interfaces has been characterized. The multilayer laminate and the as-received aluminium alloys have been tested at room temperature by Vickers microhardness, three-point bend test and impact Charpy test. The outstanding improvement in damage tolerance, which is 18 times higher than that for the as-received Al 7075 alloy, is due to both intrinsic and extrinsic fracture mechanisms operating in the multilayer laminate during mechanical testing.

    En este trabajo se ha procesado mediante laminación en caliente un material multicapa constituido por 19 capas alternadas de aluminio de alta resistencia (Al 7075-T6, 82 %vol y capas de aluminio puro (Al 1050-H24, 18 %vol de menor espesor. Se ha caracterizado la microestructura de las aleaciones constituyentes después del procesado, así como el gradiente de composición generado alrededor de las intercaras. Las propiedades mecánicas a temperatura ambiente, tanto del material multicapa como de las aleaciones de partida, se han estudiado mediante microdureza Vickers, flexión en tres puntos y ensayos de impacto Charpy. El material multicapa procesado presenta una tenacidad a impacto Charpy 18 veces superior a la de la aleación de partida Al 7075. Este espectacular aumento de tolerancia al daño es debido a los mecanismos de fractura, tanto extrínsecos como intrínsecos, que operan en el material multicapa durante las diferentes solicitaciones mecánicas a las que ha sido sometido.

  12. "Determinación experimental del límite de resistencia a la fatiga por flexión rotativa a alta velocidad (150 Hz) cercano al límite elástico del aluminio (AL 6061-T6)"

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    Tapia Silva, Edgar

    2012-01-01

    Este trabajo de Maestría está orientado al estudio de la resistencia a la fatiga de la aleación de aluminio con nominación AISI-SAE 6061-T6, en condiciones de flexión rotativa y con cargas aplicadas cercanas al límite elástico de este material. Este material fue seleccionado por su amplia utilización en la industria; algunos componentes de ejemplos motores son: de equipamiento combustión aeronáutico, interna, válvulas, accesorios para c...

  13. Resistencia al desgaste de recubrimientos de bronce al aluminio producidos con técnica de proyección térmica//Wear resistance of aluminum bronze coatings produced by thermal spray

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    Dayan Carolina Cárdenas-Feria

    2015-09-01

    Full Text Available Se estudió la resistencia al desgaste adhesivo de recubrimientos de bronce al aluminio depositados con la técnica de proyección térmica por llama sobre bronce fosforado SAE 62. Los recubrimientos fueron fabricados variando las presiones parciales de los gases de combustión, oxígeno y acetileno. El material utilizado fue caracterizado estructuralmente mediante difracción de rayosX (X-ray diffraction, XRD y el estudio morfológico mediante microscopía electrónica de barrido (Scanning electron microscopy, SEM. La resistencia al desgaste adhesivo de los recubrimientos se determinó por medio del ensayo de bola sobre disco, utilizando como bola una esférica de acero 100Cr6. Los resultados obtenidos permiten establecer que los recubrimientos proyectados con una presión de oxigeno de 78 psi y una presión de acetileno de 8 psi presentan la mejor resistencia al desgaste en comparación a los tratamientos producidos. El modo de falla de desgaste en los recubrimientos producidos es discutido en esta investigación.Palabras clave: desgaste abrasivo y adhesivo,  proyección térmica,  recubrimientos.______________________________________________________________________________AbstractWe studied the adhesive wear resistance of aluminum bronze coatings deposited by thermal spray on phosphor bronze SAE 62 substrates. The coatings were deposited by varying the partial pressures of the combustion gases: oxygen and acetylene. The structural characterization was made through X-ray diffraction (XRD and the morphological analysis was performed by scanning electron microscopy (SEM. The adhesive wear resistance of the coatings was determined by the bole on disc test using a spherical ball made of steel 100Cr6 and with a diameter of 6 mm. The results obtained show that the coating projected with an oxygen pressure of 78 psi and an acetylene pressure of 8 psi have the better wear resistance compared with the substrate and the others treatments deposited

  14. Influencia del tratamiento isotérmico en la intercara de los intermetálicos Ni3Al como refuerzo de un compuesto de matriz de aluminio obtenido por pulvimetalurgia

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    Ferrer, C.

    1998-05-01

    Full Text Available The improvement of the mechanical properties of aluminium MMCs reinforced with Ni3Al particles is based on the continuity of the matrix-particle interface as well as on the strength of these particles. This work deals with the influence of different heat treatments on the evolution of new phases in that interface. Samples were prepared following a powder metallurgy route with a final stage of extrusion. Several heat treatments encompassing a broad group of temperatures and times were applied, producing different phases around the primary particles. Samples were analysed via optical and scanning electron microscopy with energy dispersive X ray analysis. Microhardness tests were also conducted on the different phases generated.

    La mejora de las propiedades mecánicas de los composites de aluminio reforzados con partículas de Ni3Al se debe a la continuidad de la unión entre las partículas de refuerzo y la matriz, así como a la resistencia de las primeras. En este trabajo, se analiza la influencia que diferentes tratamientos térmicos tienen en la evolución de nuevas fases en la intercara matriz-partícula. Las muestras se prepararon por vía pulvimetalúrgica con una etapa de extrusión final. Se realizaron diferentes tratamientos térmicos abarcando un amplio espectro de temperaturas y tiempos, que dieron lugar al desarrollo de distintas fases alrededor de las partículas iniciales. Las muestras se analizaron mediante técnicas de microscopía óptica y electrónica de barrido con análisis de elementos por rayos X. Así mismo, se realizaron ensayos de microdureza en las distintas fases generadas.

  15. Modelo predictivo del espesor de la capa de óxido y microdureza en aluminio Al3003-B14 y Al6063-T6 anodizado usando análisis multifactorial Oxide film thickness and microhardness prediction model of Al3003-B14 and Al6063-T6 anodized aluminum using multifactorial analysis

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    Leonardo Eladio Vergara Guillén

    2011-08-01

    Full Text Available En esta investigación se modela a partir de los parámetros del proceso el espesor de la capa de óxido y la microdureza de los aluminios Al3003 y Al6063 anodizados. Para ello se realizaron estudios de la microdureza y espesor de capa de la superficie anodizada, utilizando técnicas de análisis multifactorial y diseño robusto. Se establecieron los siguientes niveles de los parámetros del proceso: temperatura [15 °C, 25 °C], tiempo [30 min; 60 min], concentración de electrolito [1,2 M; 2 M], densidad de corriente [1 Amp/dm²; 3 Amp/dm²], aluminio [Al3003,Al6063] y como variable de ruido, la deformación plástica [0%, 10%, 20%, 30%]. Se propuso un diseño fraccionado 2(7-2 mixto, con el cual se efectuó un total de 48 pruebas usando soluciones electrolíticas de ácido sulfúrico. La medición de microdureza se realizó con un indentador Vickers con carga de 400 g; el espesor de la capa de óxido se captó mediante microscopia electrónica. A los resultados se les realizó un análisis de varianza (ANOVA, para determinar los factores significativos y la robustez de los efectos. Se encontraron resultados de microdureza [HV] [85,74-308,87]; y espesor de óxido [µm] [12,82- 94,69]. Finalmente, se muestran los modelos de predicción de cada una de las respuestas en función de los factores significativos estas ecuaciones permitirán seleccionar la microdureza y espesor de la capa de óxido para cumplir los requerimientos de un producto particular mediante una selección apropiada de los parámetros del proceso.In this research, the thickness of the oxide layer and the microhardness of anodized aluminum Al3003 and Al6063 are modeled based on process parameters. To this end, studies of the microhardness and the thickness layer of the anodized surface were made, via techniques of multifactorial analysis and robust design. The following levels of the process parameters were established: temperature [15°C, 25°C], time [30min; 60min

  16. Estudio del comportamiento térmico del polvo de aluminio estabilizado con el yeso

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    López-Delgado, Aurora; J. Medina; Alonso, P.; Tayibi, Hanan; Pérez, Carlos; López Gómez, Félix Antonio

    2005-01-01

    [ES]El polvo de aluminio (pAl) es un residuo peligroso procedente de la metalurgia secundaría del aluminio. Con objeto de reducir la reactividad del mismo, en el CENIM se ha desarrollado un proceso de estabilización/solidificación mediante su fraguado con yeso. En este trabajo se presenta el estudio del comportamiento térmico del pAl estabilizado con el yeso, con el fin de establecer la influencia del residuo en las reacciones de hidratación/deshidratación del yeso durante el p...

  17. Neurotoxicidad de los metales pesados: plomo, mercurio, aluminio

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    Tostado Martín, Elena

    2014-01-01

    Este trabajo muestra las consecuencias para la salud en la población que sufre una exposición aguda o crónica a metales pesados. Más concretamente, se centra en la afectación del sistema nervioso central y su desarrollo tras la exposición al plomo, el mercurio y el aluminio. Esta revisión comienza con una breve introducción en la que se explica detalladamente las propiedades de cada metal pesado enunciado anteriormente, seguido de un breve repaso epidemiológico acerca de los pa...

  18. El aluminio en el suelo y algunas estrategias de manejo

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    Fabio Emilio Forero-Ulloa

    2011-02-01

    Full Text Available El  suelo  está  compuesto por diversos  elementos entre  los que  se destaca el aluminio, como un metal que, en condiciones  normales,    no  afecta  el desarrollo de las plantas,  pero en suelos ácidos  es un factor limitante en el crecimiento de la mayoría de especies vegetales,  con una afectación cercana al 50% del área sembrada  en el ámbito mundial. En Colombia  cerca del  85% de  los  suelos  son ácidos,  por lo cual es  necesario buscar estrategias de manejo  y  permitir  que  estos  suelos  sean adecuados para  obtener producción  agrícola, máxime  si  en nuestro  territorio existen diversos tipos  de  suelos,  como  consecuencia  de  los diferentes materiales parentales que,  al final, son necesarios    tener en cuenta para  implementar el manejo estratégico del aluminio.

  19. Aproximación al modelado semifísico del flujo de material para la evaluación de la sanidad en juntas de soldadura FSW para aleaciones de Aluminio

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    Hoyos, Pulgarín, Elizabeth

    2014-01-01

    Resumen: Este trabajo presenta la implementación de una metodología para la construcción de modelos semifísicos de base fenomenológica (MSBF), aplicada a la evaluación del flujo de material para el proceso de soldadura por fricción agitación (Friction Stir Welding, FSW). Empleando la aleación de aluminio AA2024 para las actividades experimentales de validación y el software EMSO para la simulación. El modelo obtenido permite evaluar la sanidad de las juntas con bajo costo computacional y con ...

  20. CLARIFICACIÓN DE AGUAS USANDO COAGULANTES POLIMERIZADOS: CASO DEL HIDROXICLORURO DE ALUMINIO

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    JUAN MIGUEL COGOLLO FLÓREZ

    2011-01-01

    Full Text Available En este artículo se realiza un estudio del proceso de clarificación en sistemas de tratamiento de aguas industriales usando un coagulante inorgánico polimerizado (hidroxicloruro de aluminio. Inicialmente, se establecen los elementos conceptuales más importantes de las etapas del proceso de clarificación (coagulación, floculación y sedimentación. Luego, se señalan los principales coagulantes convencionales utilizados en el tratamiento de aguas y se abordan los policloruros de aluminio (PAC´s como integrantes de una nueva generación de coagulantes alternativos cuyo uso se ha incrementado en las últimas décadas dado su mejor desempeño respecto a los coagulantes convencionales; se especifican los aspectos técnicos y operativos que se deben considerar al momento de implementar un proceso de clarificación de aguas usando un PAC como coagulante. Finalmente, se presentan datos comparativos de condiciones operacionales reales de un proceso de clarificación de aguas, producto de un trabajo previo, donde se remplazó un coagulante convencional (sulfato de aluminio por hidroxicloruro de aluminio, donde se corrobora el mejor desempeño del proceso luego del remplazo.

  1. Contaminación con aluminio en sangre en personas dializadas en dos hospitales de Colombia

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    Roberto Fernández-Maestre

    2012-12-01

    Full Text Available Objetivo: Se relacionó el grado de contaminación con aluminio en suero sanguíneo de pacientes sometidos a tratamientos de diálisis con el contenido de aluminio en los líquidos de diálisis que usaron estos pacientes y las alteraciones que mostraron en su salud. Método: Se analizaron por espectrometría de absorción atómica con horno de grafito (EAA muestras de suero sanguíneo de 34 pacientes y dializados de dos instituciones hospitalarias de la ciudad de Cali-Colombia. Las muestras de suero se diluyeron 1:4 con el modificador (nitrato de magnesio y Triton X-100, al 1 %, y las de dializados se acidularon al 1,3 %. Resultados: Los pacientes del Hospital Universitario del Valle (desionizaba el agua para preparar el dializado, mostraron concentraciones de aluminio sérico menores (60 ± 20 mg L-1 que los del Instituto de Seguros Sociales (511 ± 96 mg L-1, donde no trataban esta agua. Los pacientes del Instituto presentaron una mayor incidencia de enfermedades relacionadas con el aluminio que los del Hospital. La exactitud del método analítico estuvo entre 99-101 % y los límites de detección fueron 1,5 para suero sanguíneo y 1,2 mg L-1 para dializados. Conclusión: Hubo una relación directa entre el contenido de aluminio en sangre y dializados con la frecuencia de enfermedades relacionadas con este metal.

  2. Corrosión filiforme del aluminio lacado

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    Bautista, A.

    1996-10-01

    Full Text Available Filiform corrosion is a type of localized corrosion which can affect some painted metals (usually Steel, aluminium and magnesium. It often occurs in specimens exposed to marine environments, and produces protective coating damage and thread-like metal base attack. In the paper a brief review of filiform corrosion on coated aluminium is shown. The survey analyses the role which some factors play in the initiation of the filaments, summarizes their growing mechanism and shows the main proposed solutions to this problem.

    La corrosión filiforme es un tipo de corrosión localizada que puede afectar a algunos metales pintados (normalmente acero, aluminio y magnesio. Suele ocurrir en piezas expuestas a atmósferas marinas, y da lugar al deterioro del recubrimiento protector y a un ataque en forma de filamentos del metal base. En este trabajo se presenta una breve revisión bibliográfica sobre la corrosión filiforme en el aluminio lacado. Igualmente, se analiza el papel que juegan diversos factores en la aparición de los filamentos de corrosión, se resume el mecanismo por el que progresan y se recogen las principales soluciones propuestas para este problema.

  3. Efecto de la precipitación de nitruros de aluminio en la recristalización de aceros de bajo carbono recocidos convencionalmente

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    Monsalve, A.

    2005-10-01

    Full Text Available An important feature of aluminium killed steels is the strong influence that aluminium nitride precipitates produce in both the mechanical properties and the final microstructural characteristics of the steel. This influence is related to the different stages of the fabrication process. This paper deals with a study of the effects of aluminium nitrides on the kinetics of recrystallisation. Different heat treatments were carried out, in one case to dissolve AIN, and in the other in order to precipitate AIN. These steels were subjected to cold rolling, followed by a batch annealing process. The recrystallised fraction was measured, thus obtaining the kinetic curves. The activation energy for recrystallisation was computed in each case. The results showed that AIN precipitation during recrystallisation produces a delay in recrystallisation kinetics through a change in the activation energy value.

    Los aceros calmados con aluminio presentan como característica importante, la gran influencia que ejercen los nitruros de aluminio en las propiedades mecánicas y características microestructurales finales. Esta influencia está, a su vez, relacionada con cada una de la etapas del proceso de fabricación. En el presente trabajo se ha abordado el estudio del efecto de los nitruros de aluminio sobre la cinética de recristalización. Para ello, se han llevado a cabo diversos tipos de tratamientos térmicos, con el objeto de disolver todo el AIN y, en el otro caso, de precipitar todo el AIN. A continuación, los aceros estudiados se deformaron en frío y se les realizó un recocido convencional. Se midió la fracción recristalizada evaluando la energía de activación para la recristalización. Los resultados mostraron que la precipitación de AIN durante la recristalización produce un retraso en la cinética de recristalización, a través del cambio en el valor de la energía de activación

  4. Modificación de probetas de aluminio mediante inmersión en soles de zirconio

    OpenAIRE

    Rosendo Fuentes; E. Rubio; Herrera, A.; Ramos, E.; Jiménez, S.; Castaño, V. M.

    2001-01-01

    Es posible recurrir a la pulvimetalurgia, llamada también metalurgia de polvos, y al proceso sol-gel para obtener materiales compuestos de matriz de aluminio. Este método comienza con la compactación de polvo de aluminio, luego las probetas compactadas se sumergen en una solución coloidal de zirconio. Aprovechando la porosidad, la solución coloidal gela a lo largo de los poros interconectados, y durante la sinterización de las piezas, el gel cristaliza en forma de zirconia monoclínica y tetra...

  5. Influencia de la implantación de iones cromo, aluminio y cerio en el comportamiento a oxidación del Ni3Al a temperaturas comprendidas entre 635 y 1.020°C

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    Pérez, P.

    1998-02-01

    Full Text Available The effect of ion implantation on the oxidation behaviour of a powder metallurgy Ni3Al in the 635- 1,020°C range is studied. The work is carried out by discontinuous thermogravimetry tests in aluminium, chromium and cerium implanted materials as well as in the non implanted intermetallics. The oxidation kinetics and characterization of scale are evaluated. The results show that the chromium implanted material exhibits the best oxidation behaviour up to 930°C. This ion favours the fast formation of a healing (Cr,Al2O3 layer. The Al-implantation does not improve the oxidation behaviour of the intermetallics whereas Ce-implantation produces a harmful effect. At temperatures above 930°C the non-implanted material shows the lower mass-gains.

    En este trabajo se estudia el efecto de la implantación de iones aluminio, cromo y cerio en el intermetálico Ni3Al, procesado por vía pulvimetalúrgica, en la modificación de su comportamiento a oxidación en el intervalo 635-1.020°C. El estudio se realiza mediante termogravimetría discontinua, tanto en el material implantado como en el intermetálico sin implantar. Se evalúa la cinética del proceso de oxidación y se caracterizan los productos formados. Los resultados indican que hasta 930°C el material implantado con cromo es el que presenta el mejor comportamiento a oxidación. El papel que desempeña este elemento es favorecer la rápida formación de una capa protectora de (Cr,Al2O3. La implantación de iones aluminio no mejora la resistencia a la oxidación del intermetálico y el cerio parece empeorarlo. Por encima de 930°C es el intermetálico sin implantar el que presenta las menores ganancias de masa.

  6. Influencia sobre los tratamientos térmicos del contenido de aluminio de aceros no aleados

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    Carreras, L.

    1999-08-01

    Full Text Available The main purpose of this article is to determine the optimal level of aluminum content in plain steels to have the optimal mechanical properties by means of surface heat treatments. Various plain steels with different aluminium content have been studied. The importance of treatment temperature is analyzed. The influence of other factors, like nitrogen content or the homogenous distribution of particles, is evaluated. It is concluded that the aluminum composition of plain steels that are subjected to heat treatments should not exceed 0.02 %.

    El objetivo de este trabajo es determinar el intervalo óptimo de contenidos de aluminio en aceros no aleados para los que se consiguen las propiedades mecánicas óptimas mediante tratamientos térmicos de superficie. Se estudian diferentes coladas de acero en las que varía el contenido de aluminio y las temperaturas de tratamiento. Se evalúa la importancia de otros factores tales como el contenido de nitrógeno y la homogeneidad en la distribución de partículas endurecedoras. Se llega a la conclusión de que los aceros no aleados destinados a tratamientos térmicos no deben tener un contenido de aluminio superior al 0,02 %.

  7. Aluminio pulvimetalúrgico: desarrollo y mejora de sus aleaciones y materiales compuestos

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    Ruiz-Navas, E. M.

    2008-06-01

    Full Text Available Powder metallurgy components demand is increasing in the last few years mainly due to the necessity of products assigned to automotive and aerospace industries, which has allow an important development of aluminium alloys and composites (AMCs. Consolidation of aluminium alloys by sintering present a main problem: the oxide layer that cover aluminium particles. Several alternatives are studied in this work as solution to the oxide layer problem during the sintering of series 2xxx aluminium alloys. One of these solutions is related to the addition of tin traces, and the other is the addition of a second alloy. Moreover, aluminium metal matrix composites are characterized by excellent properties as combination of properties which comes from the matrix and from the reinforcement. The last part of this study is focused to the analysis of one aluminium matrix composite as the influence of several quantities of reinforcement.

    El auge en la demanda de componentes pulvimetalúrgicos destinados principalmente al sector automovilístico y aeroespacial ha permitido un fuerte desarrollo tanto de aleaciones como de MMCs base aluminio (AMCs. El principal problema a la hora de consolidar estos materiales vía pulvimetalúrgica es la capa de óxido que recubre a las partículas de aluminio. En este trabajo se presentan varias alternativas como solución a este problema, aplicadas a la consolidación de aleaciones de aluminio pertenecientes a la serie 2xxx, entre ellas, la adición de trazas de estaño y la adición de una aleación Al-Si. En cuanto a los materiales compuestos de matriz de aluminio, se caracterizan por presentar propiedades únicas como combinación de las propiedades individuales que caracterizan tanto a la matriz como al refuerzo. En la última parte de este trabajo se estudia la consolidación de un material compuesto así como la influencia de las distintas cantidades de refuerzo.

  8. Recuperación del cromo y aluminio del licor de desecho (wl en forma de sales dobles

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    Pedro R. Bassas-Noa

    2006-03-01

    Full Text Available El licor WL es un residual de la industria del níquel agresivo al medio ambiente por su acidez que contiene elementos metálicos de gran valor. Se propone un tratamiento para la separación con  hidróxido de amonio y la recuperación de la mayor cantidad de cromo y aluminio contenidos en el mismo. Se logra precipitar una mezcla de hidróxidos de aluminio que tratada con ácido sulfúrico permite obtener, por cristalización, la sal sulfato de aluminio y amonio dodecahidratada. Posteriomente se cristaliza la sal sulfato doble de cromo y amonio dodecahidratado. Se demuestra que el sulfato doble de cromo y amonio dodecahidratado y el sólido separado presentan características químicas que hacen posible su aplicación en la industria textil y de cerámica, entre otras. El esquema aplicado permite la recuperación de valores metálicos y la disminución del alto poder contaminante del licor de desecho WL.

  9. Comportamiento del aluminio desnudo y anodizado en atmósferas con grados de contaminación muy diferentes

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    Bautista, A.

    1998-05-01

    Full Text Available In the present research, the responses of unprotected and anodized aluminium specimens are compared after they have been exposed to 12 different atmospheres. The significance of the anodizing and the sealing on the atmospheric corrosion behaviour is analysed. The results show that the anodizing and sealing of aluminium exclude the risk of pitting corrosion in marine atmospheres and that the oxide thickness is not determining, at least during the first year of exposure.

    En la presente investigación, comparando las respuestas de muestras de aluminio desnudas y anodizadas, expuestas a 12 atmósferas diferentes, se analiza la repercusión del anodizado y sellado del aluminio en el comportamiento frente a la corrosión atmosférica. Se demuestra que la anodización y sellado del aluminio elimina el riesgo de corrosión por picaduras que afecta a estos materiales en atmósferas marinas, sin que el espesor del recubrimiento resulte determinante, al menos, en el primer año de exposición.

  10. EFECTOS DEL ALUMINIO EN LA DIVISIÓN Y EL ALARGAMIENTO CELULAR EN PLÁNTULAS DE ARROZ (Oryza sativa L.

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    Idioleidys Alvarez Bello

    2012-01-01

    Full Text Available Teniendo en cuenta que la toxicidad por aluminio es el efecto más importante en los suelos ácidos y constituye el mayor factor limitante del crecimiento y la producción vegetal, se desarrolló una investigación que tuvo como objetivo fundamental determinar el efecto del aluminio en los procesos de división y alargamiento celular en dos cultivares comerciales de arroz, así como la relación de estos con la inhibición del crecimiento radical. Se emplearon diferentes niveles de aluminio para imponer la condición de estrés y los ápices radiculares fueron sometidos al procesamiento tradicional para microscopía óptica. Las secciones teñidas se observaron al microscopio óptico (Zeiss con cámara digital acoplada y las dimensiones celulares se cuantificaron mediante el programa morfométrico ImageJ. Se demostró que el aluminio inhibió el crecimiento radical de las plántulas de arroz, como consecuencia del efecto tóxico del metal. Se observó una reducción del índice mitótico para ambos cultivares con el incremento de la concentración de aluminio y el estudio del alargamiento celular evidenció que las células radicales se acortaron en longitud y aumentaron su grosor. Los resultados demostraron que los desórdenes que provoca el metal en los dos procesos celulares evaluados son los responsables fisiológicos de la inhibición del crecimiento radical.

  11. Recubrimientos de aluminio-silicio realizados por deposición química de vapor en lecho fluidizado sobre el acero inoxidable AISI 316

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    José Luddey Marulanda Arevalo

    2013-12-01

    Full Text Available Los recubrimientos de aluminio-silicio fueron depositados sobre el acero inoxidable AISI 316 mediante deposición química de vapor en lecho fluidizado (CVD-FBR, en el rango de temperaturas de 540 a 560 ºC, utilizando un lecho formado por 2,5 g de silicio y 7,5 g de aluminio en polvo, y 90 g de lecho inerte (Alúmina, el cual se hizo fluidizar con Ar. Como gases activadores se usó una mezcla de HCl/H2, en relaciones de 1/10 a 1/16. Además, se varió el tiempo de deposición de los recubrimientos de 45 minutos a 1.5 horas, con una relación en volumen de 50% de gases activos y 50% de gases neutros. Se realizó una simulación termodinámica con la ayuda del programa informático Thermocalc, para obtener información de la posible composición y cantidad de material depositado, para las condiciones seleccionadas. En los recubrimientos se encuentran FeAl2Si, Fe2Al5 y FeAl2. Los recubrimientos aluminio-silicio fueron tratados térmicamente, para mejorar sus propiedades mecánicas y su comportamiento frente a la oxidación, por la interdifusión de los elementos de aleación, ya que el tratamiento térmico hace que el aluminio difunda hacia el substrato, y el hierro difunda hacia la superficie del recubrimiento, logrando la transformación de los compuestos anteriores en FeAl, Al2FeSi, Cr3Si, AlCrFe y AlFeNi.

  12. Formas de hierro y aluminio en suelos con diferentes usos en la zona norte del departamento del Magdalena, Colombia

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    José Rafael Vásquez Polo

    2014-12-01

    Full Text Available En el estudio se evaluaron las diferentes formas de hierro (Fe y aluminio (Al presentes en suelos cultivados y en áreas de bosque de la zona norte del departamento del Magdalena (Colombia. Se seleccionaron seis zonas de muestreo localizadas entre 0 y 1000 m.s.n.m. Se utilizaron tres técnicas selectivas de extracción de Fe y Al con los agentes extractantes: pirofosfato de sodio, oxalato ácido de amonio, y ditionito citrato bicarbonato. Los contenidos totales de Fe y Al fueron determinados mediante un ataque ácido y cuantificación por absorción atómica. El análisis de varianza multivariado mostró diferencias significativas (P 3% del Al total, lo que sugiere que un alto contenido de Al forma parte de estructuras cristalinas.

  13. Aluminio: ingestión, absorción, excreción y toxicidad

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    Roberto Fernández-Maestre

    2014-12-01

    Full Text Available Objetivo: Revisar la toxicidad del aluminio (Al, haciendo seguimiento a su absorción, deposición en los tejidos, patologías relacionadas, y excreción. Cuerpo: La toxicidad del Al, conocida solo desde los años 70´s, se manifiesta especialmente en personas sometidas a diálisis con aguas de alto contenido de este metal y en pacientes con úlcera péptica que han sido tratados por largo tiempo con hidróxido de Al. El Al es responsable de enfermedades óseas, hepatobiliares y anemia. Los efectos nocivos del Al en el cerebro se deben a la inhibición de enzimas y a la deformación estructural de algunas proteínas que causan, entre otras anormalidades, acumulación de placas de alumino-silicatos amorfos en las neuronas y marañas neurofibrilares que causan encefalopatías mortales si no se tratan a tiempo. Además, se le relaciona con la enfermedad de Alzheimer, esclerosis lateral amiotrófica, síndrome de Down, y mal de Parkinson. Conclusión: En condiciones normales (personas con función renal normal, consumo balanceado de alimentos, uso moderado de drogas e ingestión de agua con niveles aceptables de Al éste metal no constituye una amenaza para la salud.

  14. Recubrimientos de aluminio-silicio realizados por deposición química de vapor en lecho fluidizado sobre el acero inoxidable AISI 316

    OpenAIRE

    José Luddey Marulanda Arevalo; Francisco Javier Pérez Trujillo; Aduljay Remolina Millán

    2013-01-01

    Los recubrimientos de aluminio-silicio fueron depositados sobre el acero inoxidable AISI 316 mediante deposición química de vapor en lecho fluidizado (CVD-FBR), en el rango de temperaturas de 540 a 560 ºC, utilizando un lecho formado por 2,5 g de silicio y 7,5 g de aluminio en polvo, y 90 g de lecho inerte (Alúmina), el cual se hizo fluidizar con Ar. Como gases activadores se usó una mezcla de HCl/H2, en relaciones de 1/10 a 1/16. Además, se varió el tiempo de deposición de los recubrimientos...

  15. Influencia del nitruro de aluminio en el crecimiento anormal de grano de aceros microaleados

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    Cabrera, J. M.

    1995-02-01

    Full Text Available After a brief review about concepts and theories involved in control of grain growth by second phase particles, an experimental study of a medium carbon microalloyed steel with two levels of AIN is carried out. A system to study the grain size distributions in order to detect the abnormal grain growth is proposed. Results permit to plot a map of abnormal grain growth-time-temperature. The abnormal grain growth is derived to be due to the AIN dissolution by correlating the above maps with the theoretical volume fraction of precipitates. The importance and effect of the heating rate is also shown: high heating rates can produce a transient oversaturation that can lead to abnormal growing during the dissolution.

    Tras una breve revisión de los conceptos y teorías involucradas en el control del crecimiento de grano por partículas de segunda fase, se efectúa un estudio del mismo en un acero microaleado con contenido medio de carbono con dos niveles de nitruro de aluminio. Se propone un sistema de estudio de las distribuciones de tamaño de grano tendente a poder detectar la presencia de crecimiento anormal de grano. De este modo, se construyen mapas de crecimiento anormal-tiempo-temperatura que, correlacionados con las teóricas fracciones de volumen de los precipitados presentes, permiten comprobar que la disolución del nitruro de aluminio es la responsable fundamental de la aparición del crecimiento anormal de grano. También se muestra el efecto e importancia de la velocidad de calentamiento, ya que altas velocidades pueden producir una sobresaturación transitoria de precipitados que, al disolverse, pueden dar lugar a crecimiento de grano anormal.

  16. Efecto del calcio sobre la toxicidad aguda de aluminio en alevines de trucha arcoiris (Oncorhynchus mykiss expuestos en aguas de diferente pH

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    Rolando Vega

    2015-05-01

    Full Text Available En la producción de alevines de salmón de la región de la Araucanía (sur de Chile se presentan importantes eventos de mortalidad aguda sin rasgos patológicos aparentes. El problema se focaliza en ejemplares de 0,2 a 1 g y las causas apuntan a procesos de acidificación del pH del agua y a la presencia de ciertos metales pesados, entre los cuales destaca el aluminio, que alcanza concentraciones más allá de los rangos de tolerancia de los peces. La información científica indica que concentraciones de 5 mg Ca L-1 en el afluente son suficientes para mantener a salvo los peces del efectos tóxico del aluminio. Sin embargo, los problemas en la producción de alevines de salmón indican que se requiere un mayor conocimiento científico y evidencia experimental que soporte el desarrollo de procesos y tecnologías para el tratamiento de los afluentes de las pisciculturas chilenas. En este trabajo se evaluó el efecto de cuatro concentraciones de calcio (0, 5, 10 y 20 mg Ca L-1 sobre la toxicidad aguda de 500 μg Al L-1 en alevines de trucha arcoiris (Oncorhynchus mykiss de 0,1 g en agua de cultivo a pH 5, 6 y 7. El objetivo del trabajo fue determinar la dosis de calcio que reduce la toxicidad aguda de aluminio y los tiempos mínimos de reacción que podrían disponer los piscicultores para tomar medidas preventivas ante una concentración aguda de aluminio en el agua de cultivo. Los resultados indican que antes de 8 h de exposición a una concentración tóxica de aluminio los piscicultores deberían asegurar en el agua de cultivo una dosis superior a 10 mg Ca L-1 y un pH >6 como medida remedial para reducir el efecto de intoxicación aguda causada por aluminio.

  17. Comparación de metodologías voltamperométricas adsortivas para la determinación de aluminio en agua potable

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    Miriam Barquero Quirós

    2005-11-01

    Full Text Available La determinación cuantitativa de aluminio en diversas técnicas a nivel de μg/L está sujeta a contaminación e interferencias. El aluminio por técnicas voltamperómétricas directas es difícil de reducir debido a su alto potencial. Para superar este problema, se forman complejos solubles de aluminio, que se adsorben en un electrodo de Hg. Luego se reducen siendo la corriente de pico proporcional a la concentración. Se estudiaron dos diferentes complejos de aluminio con alizarina y con cupferrón; en ambos casos se optimizaron las condiciones experimentales de formación de los complejos tales como pH óptimo, concentración de reactivo acomplejante, las condiciones experimentales de medición fueron opimizadas: potencial de acumulación, tiempo de acumulación, frecuencia, amplitud de pulso, tiempo de equilibrio, se determinaron los parámetros de desempeño de ambas determinaciones: veracidad, ámbito lineal, límite de detección, y límite de cuantificación para la técnica de voltamperometría de onda cuadrada (SWV. El complejo de aluminio-alizarina no es electroactivo, y la alternativa es medir la alizarina residual después de la formación del complejo con aluminio, cuya cinética es muy lenta y debe calentarse 5 minutos a 80 °C. Se procedió al estudio de las condiciones experimentales, siendo el pH de 9,25 determinante. Es necesario que el buffer sea de alta capacidad reguladora para obtener la formación del derivado. El límite de detección obtenido a partir de la desviación estándar de 7 blancos fue 3 μg/L, y el coeficiente de variación de los blancos 8 por ciento, la recuperación promedio para 16 μg/L con n=7, fue de 97 por ciento. Las curvas de calibración se realizaron en un ámbito de 8 a 64 μg/L. La aplicación del método a muestras de agua es posible mediante la previa evaporación de estas. Se desarrolló y se validó una metodología apta para cuantificar aluminio en aguas basada en la reacción de Al con

  18. Solubilidad y reacción del aluminio en el suelo

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    Fánor Casierra-Posada

    2011-02-01

    Full Text Available El aluminio que, en condiciones ácidas, proviene de los minerales hacia la solución del suelo, o que está presente en soluciones nutritivas con pH menor a cuatro, aparece principalmente como Al(OH2. La mineralogía, el grado de cristalinidad y de reactividad de los resultantes de la precipitación de Al3+, se ven influenciados principalmente por el pH, los minerales de las arcillas, y por la naturaleza y concentración de los ácidos orgánicos e inorgánicos presentes en los suelos. Existen muchas posibles fases minerales que podrían intervenir en la solubilidad de Al 3+ en los horizontes minerales del suelo, tales como: gibsita, alofano, imogolita y caolinita. En los andosoles, el alofano también contribuye a que se presenten concentraciones altas de Al 3+. En muchos suelos, la solubilidad de Al 3+ también puede estar determinada por las reacciones que conducen a la formación de complejos con la materia orgánica, al menos a corto plazo. El poder buffer de esos suelos depende, ampliamente, de la relación de intercambio H+/Al 3+; esto es, del número de protones consumidos por la fase sólida, cuando se libera Al 3+. En este artículo, se hizo una revisión detallada de los factores responsables de la disponibilidad de Al 3+ en el suelo, tales como solubilidad, formación de complejos con la materia orgánica y la relación de intercambio H+/Al 3+.

  19. Durabilidad del aluminio desnudo y anodizado en atmósferas de muy diferentes corrosividades. I. Aluminio desnudo

    Directory of Open Access Journals (Sweden)

    González, J. A.

    2004-08-01

    Full Text Available The behaviour of bare aluminium is studied in atmospheric exposure at 11 natural testing stations with salinity levels ranging between 2.1 and 684 mg Cl-1m-2d-1. In atmospheres of low or moderate aggressivity aluminium behaves as a passive material, though the insignificant corrosion that is produced is sufficient to spoil its appearance. In contrast, at salinity levels of 50 mg Cl-1m-2d-1 or above, aluminium is susceptible to pitting corrosion even in the first year of atmospheric exposure, or in the second year at salinities of s: 10 mg Cl-1m-2d-1 . For comparative purposes, results are included for aluminium protected with an anodic film of 28 μm thickness exposed at the same testing stations. A 28 μm anodic film, correctly sealed, prevents the risk of localised corrosion even in the most unfavourable situations.

    Se estudia el comportamiento del aluminio desnudo durante la exposición atmosférica en 11 estaciones de ensayos naturales, con salinidades que oscilan entre 2,1 y 684 mg Cl-1m-2d-1. En atmósferas de agresividades bajas y moderadas, el aluminio se comporta como un material pasivo, pero la insignificante corrosión que se produce es suficiente para perjudicar el aspecto. Sin embargo, el aluminio es susceptible a la corrosión por picaduras, ya durante el primer año de exposición atmosférica, para salinidades de 50 mg Cl-1m-2d-1 o superiores y, durante el segundo año, para salinidades > 10 mg Cl-1m-2d-1. A efectos comparativos se incluyen resultados de aluminio protegido con un anodizado de 28 μm de espesor, expuesto en las mismas estaciones de ensayo. Un anodizado de 28 μm, correctamente sellado, evita el riesgo de corrosión localizada, incluso en las situaciones más desfavorables.

  20. Estudio de la degradación de la capa de sellado en perfiles de aluminio anodizado

    Directory of Open Access Journals (Sweden)

    Juan G. Castaño

    2010-01-01

    Full Text Available El anodizado del aluminio es simplemente el refuerzo de un proceso natural y espontáneo: la formación de una capa de alúmina estable y protectora mediante la cual se pueden obtener películas con una subcapa exterior porosa que acepta coloración. Luego la operación de sellado permite la formación de una sustancia gelatinosa compuesta principalmente de bohemita, que obstruye los poros y mejora la conservación del aspecto superficial y la resistencia a la corrosión. Utilizando SEM y EDS, en este trabajo se estudiaron las causas de la degradación de la capa de sellado de algunas piezas de aluminio anodizado, independientemente del medio en donde está expuesto el material, y se encontró su origen en la fotodegradación de un aditivo orgánico añadido en exceso durante la operación de sellado.

  1. Obtención de silicio por reducción de si o2 con aluminio

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    F. Córdoba

    2009-07-01

    Full Text Available En el presente trabajo se ha obtenido silicio por aluminotermia a partir de arena y se ha analizado mediante tres técnicas diferentes. La espectroscopia Auger revela una fuerte concentración de aluminio no aleado y por lo tanto susceptible de ser eliminado por tratamientos ácidos. El análisis con microsonda electrónica muestra una concentración volumétrica mayor al 99% Finalmente, el parámetro de red determinado por difracción de rayos X es 5,4306 (5 A el cual corresponde apreciablemente al característico para el Silicio.

  2. PELÍCULAS DELGADAS DE ZnO IMPURIFICADAS CON ALUMINIO Y FLÚOR PREPARADAS POR SOL-GEL

    OpenAIRE

    Salvador Tirado

    2012-01-01

    Se han fabricado películas delgadas de óxido de cinc impurificadas con aluminio y flúor (ZnO:Al:F), mediante el proceso de sol-gel y la técnica de inmersión repetida. Las películas se depositaron sobre sustratos de vidrio sodo-cálcico. Se ha estudiado el efecto del envejecimiento del sol y el espesor de las películas sobre estructura, morfología, propiedades ópticas y eléctricas. Películas policristalinas ZnO:Al:F resultaron con orientación preferencial del plano (002). Resultó un tamaño de c...

  3. Síntesis coloidal de materiales nanoestructurados de Al-ZrAl 3: Propiedades mecánicas mediante el ensayo miniatura de punzonado

    OpenAIRE

    Díaz, L. A.; Torrecillas, Ramón

    2009-01-01

    [ES]: En este trabajo se describe un nuevo método de procesamiento coloidal para obtener materiales nanoestructurados de base aluminio con partículas intermetálicas ZrAl3. A partir de una mezcla controlada en alcohol, de polvos de aluminio con un alcóxido precursor de zirconio (C12H28O4Zr) se obtiene, mediante un tratamiento térmico en un horno convencional con atmósfera controlada o por prensado uniaxial en caliente, un polvo nanoestructurado formado por cristales de aluminio sobre los que c...

  4. Crecimiento del maíz en vertisoles con alto aluminio en la Baixada Maranhense pre-Amazonia, Brasil.

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    Alessandro Costa-da Silva

    2014-07-01

    Full Text Available El objetivo de este trabajo fue evaluar el crecimiento del maíz en suelos con alto contenido de aluminio. Se midió el efecto del Al3+ en raíces y la cantidad de materia seca (raíz, hoja y tallo de maíz. Se efectuó la caracterización físico-química de cuatro muestras de suelo con alto aluminio colectadas del horizonte Ap, en tres municipios de la región conocida como Baixada Maranhense (Pre-Amazonia, Brasil: Santa Rita (SR, Arari (AR y Vitoria do Mearim (VM y un testigo colectado en el municipio de São Luís, Área del Núcleo de Tecnología Rural (T. El estudio, ejecutado en 2009, se llevó a cabo en invernadero y se utilizó 2 dm3 de suelo por maceta. Asimismo las muestras fueron divididas en muestras con y sin fertilización. La variación en la longitud de la raíz y de materia seca de las hojas difirió significativamente entre tratados con y sin fertilizante, excepto en la muestra de la localidad T. La producción de materia seca de raíz, tallo y hoja fue mayor en todos los suelos cuando se fertilizó. El suelo testigo también superó a todos los demás en cuanto a producción de materia seca en la raíz, posiblemente como resultado de una menor cantidad de Al3+ (1,2 cmolc/dm3 en comparación con los suelos SR, AR y VM (6,8; 8,0 y 7,0 cmolc/dm3 respectivamente. Se concluye la fertilización reduce el efecto detrimental del aluminio en la producción de maíz en la Baixada Maranhense.

  5. Riesgos a la salud por presencia del aluminio en el agua potable

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    Rodolfo Trejo Vázquez

    2004-01-01

    Full Text Available En la actualidad el aluminio tiene una amplia aplicación en la industria alimenticia, farmacéutica, del papel, de la construcción y en el tratamiento de agua para beber y agua residual. Sin embargo, no se ha dado énfasis a los posibles daños a la salud originados por el consumo de este elemento. Una de las enfermedades que ha sido asociada a la ingesta de este elemento es el Alzheimer y se corre el riesgo de desarrollar otros padecimientos. En el presente documento se resumen los resultados obtenidos de una investigación bibliográfica relacionada con los daños a la salud originados por el consumo de aluminio y compuestos fluoroaluminados, la finalidad es poner de manifiesto la importancia que tiene vigilar y controlar el contenido del aluminio en el agua potable

  6. Evolución de las propiedades mecánicas de un residuo de la metalurgia secundaria del aluminio estabilizado con yeso

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    Tayibi, H.

    2005-08-01

    Full Text Available Aluminium dust from aluminium remelting industry is a hazardous residue because of its high reactivity in the presence of water (production of ammonia, methane, hydrogen sulphide ..., potential aluminothermy and its content in leaching heavy metals. In order to apply the new European Directive about landfill of waste, a Stabilization/Solidification (S/S process was developed in the CENIM with the aim of decreasing its reactivity and to assure an easy transport and storage of the residue. Gypsum was used as a binder material. This work summarizes the study of the mechanical properties of the stabilized residue en comparison with the gypsum ones. The reactivity of the dust, before and after the S/S process was investigated by analysing the ammonia and metallic aluminium

    El polvo de aluminio es un residuo de la metalurgia secundaria del aluminio, generado en la molienda y clasificación de las escorias resultantes de los procesos de fusión de chatarras. Se considera un residuo peligroso debido a su elevada reactividad al entrar en contacto con la humedad ambiental (producción de metano, amoniaco y sulfuro de hidrógeno, entre otros, su potencial aluminotermia y su contenido en metales pesados lixiviables. Conforme a la entrada en vigor de la nueva Directiva Europea sobre vertederos, así como a la implementación de la Directiva sobre Control Integrado y Prevención de la Contaminación, que obliga a transformar los residuos peligrosos en materiales inertes antes de su almacenamiento, se ha desarrollado un procedimiento de Estabilización/Solidificación (E/S del polvo de aluminio, basado en la fuerte acción deshidratante del yeso. El objetivo, además de la obtención de un material menos reactivo, era conseguir unos aglomerados consistentes que pudieran ser fácilmente transportados y manipulados. En este trabajo, se ha estudiado la evolución de las propiedades mecánicas, tales como las resistencias a flexotracción, a compresión y

  7. PELÍCULAS DELGADAS DE ZnO IMPURIFICADAS CON ALUMINIO Y FLÚOR PREPARADAS POR SOL-GEL

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    Salvador Tirado

    2012-01-01

    Full Text Available Se han fabricado películas delgadas de óxido de cinc impurificadas con aluminio y flúor (ZnO:Al:F, mediante el proceso de sol-gel y la técnica de inmersión repetida. Las películas se depositaron sobre sustratos de vidrio sodo-cálcico. Se ha estudiado el efecto del envejecimiento del sol y el espesor de las películas sobre estructura, morfología, propiedades ópticas y eléctricas. Películas policristalinas ZnO:Al:F resultaron con orientación preferencial del plano (002. Resultó un tamaño de cristal para las películas en el rango de 18-39 nm. En las mejores películas se registraron valores de 5x10-1 y 12x10-1 Ω cm para la resistividad. Las películas presentaron una transmitancia de 75 a 85%. De los espectros UV se evaluó un ancho de banda de 3.31 a 3.34 eV para las películas. Las películas ZnO:Al:F al 0.5% at., presentan propiedades físicas y químicas tales, que podrían aplicarse en celdas solares en tecnología de película delgada.

  8. Durabilidad del aluminio desnudo y anodizado en atmósferas de muy diferentes corrosividades. II. Aluminio anodizado

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    López, V.

    2004-08-01

    Full Text Available The behaviour of three anodic films with thicknesses of approximately 7,17 and 28 μm is studied in atmospheric exposure at 11 natural testing stations with salinity levels ranging between 2.1 and 684 mg Cl-1m-2d-1 To evaluate the results, use was made of gravimetric techniques, electrochemical impedance spectroscopy (EIS, EDX microanalysis, standard quality control tests, optical microscopy and, occasionally, electron microscopy. It is shown that anodising with correct sealing is an appropriate solution for preventing localised corrosion of aluminium and conserving its appearance, even in atmospheres of high corrosivity, provided that an ill-defined minimum thickness threshold is passed. The 7 μm anodic films suffer corrosion after the second annual cycle in the most aggressive environments. Corrosion, when it occurs, is localised in the form of pitting or filiform corrosion.

    Se estudia el comportamiento de tres anodizados, de 7, 17 y 28 μm, aproximadamente, durante la exposición en 11 estaciones de corrosión atmosférica, con salinidades que oscilan entre 2,1 y 684 mg Cl-1m-2d-1 En la valoración de resultados se utilizaron técnicas gravimétricas, de espectroscopia de impedancia electroquímica (EIE, microanálisis por EDX, ensayos normalizados de control de calidad, microscopía óptica y, ocasionalmente, microscopía electrónica. Se demuestra que la anodización, con un sellado correcto y siempre que supere un umbral mínimo de espesor, no bien definido, es una solución adecuada para prevenir la corrosión localizada del aluminio y conservar el aspecto, incluso, en atmósferas de elevada corrosividad. Los anodizados de 7 μm sufren corrosión, en los ambientes más agresivos, a partir del segundo ciclo anual. La corrosión, cuando se presenta, es localizada, en forma de picaduras o de corrosión filiforme. Palabras clave

  9. Comparación de metodologías voltamperométricas adsortivas para la determinación de aluminio en agua potable

    OpenAIRE

    Miriam Barquero Quirós

    2005-01-01

    La determinación cuantitativa de aluminio en diversas técnicas a nivel de μg/L está sujeta a contaminación e interferencias. El aluminio por técnicas voltamperómétricas directas es difícil de reducir debido a su alto potencial. Para superar este problema, se forman complejos solubles de aluminio, que se adsorben en un electrodo de Hg. Luego se reducen siendo la corriente de pico proporcional a la concentración. Se estudiaron dos diferentes complejos de aluminio con alizarina y con cupferrón; ...

  10. El eurocódigo 9 "Proyecto de estructuras de aluminio"

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    Ramírez, J. L.

    1999-06-01

    Full Text Available Aluminium is an interesting structural material because its lightness and minimum maintenance needs, together with and important strength. The lack of knowledge of design rules with this material owing to the shortage of design guides, together with its higher cost, are factors that leed to the very scarce use of aluminium in the construction of structures. In present article it is dealt with a brief look to the tipology and properties of the structural aluminium alloys, and it is described the content of Eurocode 9 "Design of aluminium structures", approved by CEN (European Committee for Standardization in may 1998 that it is foreseen to be published in Spanish by AENOR in short time.

    El aluminio es un material estructural de interés, por unir ligereza y mínimas necesidades de protección, junto con una resistencia importante. La falta de conocimiento de las reglas de proyecto con el material, debido a la escasa disponibilidad de guías o recomendaciones de diseño, junto con un precio elevado, son factores que condicionan la muy escasa presencia del aluminio en la construcción de estructuras. En el presente artículo se expone una visión sucinta de la tipología y propiedades de las aleaciones de aluminio y se describe el contenido del Eurocódigo 9 "Proyecto de estructuras de aluminio" aprobado por el CEN (Comité Europeo de Normalización en mayo de 1998 y que aparecerá en castellano en breve publicada por AENOR, como Norma Europea Experimental.

  11. Influencia del consumo moderado de cerveza sobre la toxicocinética del aluminio: estudio agudo Influence of moderate beer consumption on aluminium toxico-kynetics: acute study

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    A. Peña

    2007-06-01

    Full Text Available Objetivo: El aluminio constituye uno de los factores de riesgo descritos para la enfermedad de Alzheimer y otros desórdenes neurodegenerativos, debido a su acción oxidativa sobre el cerebro. Según distintas investigaciones, parece ser que el silicio es capaz de interferir en la cinética de este metal. De ahí que, en el presente trabajo se pretenda estudiar el efecto del consumo de la cerveza, como fuente de ácido silícico, sobre la biodisponibilidad del aluminio, así como su posible relación en la prevención de la neurotoxicidad de este metal. Material y métodos: Para ello se ha analizado la influencia de la cerveza en la cinética de absorción y eliminación del aluminio administrado a ratones machos, en un tratamiento agudo de 3 días de duración. Se utilizaron dos tipos de cerveza: con y sin alcohol, y a dos dosis diferentes, una equivalente a un consumo moderado-bajo en el hombre (0,5 L/día; 27,5 g alcohol/día, y otra a moderado-alto (1 L/día; 55 g alcohol/día. El aluminio se determinó por espectrometría de masas de plasma acoplado inductivamente y el silicio mediante espectrometría de emisión atómica de plasma acoplado inductivamente. Resultados: La suplementación con cerveza, especialmente la cerveza con alcohol y a dosis moderada alta, parece tener influencia sobre la toxicocinética del aluminio, debido a su contenido en silicio: éste podría limitar la absorción del aluminio en el tracto gastrointestinal, incrementando su excreción por vía fecal. Además, se apunta una posible interacción de ambos elementos a nivel de distribución y de excreción vía renal. Conclusiones: El consumo moderado de cerveza podría ejercer un papel protector frente al efecto tóxico del aluminio, metal considerado como uno de los factores ambientales determinantes de la enfermedad de Alzheimer.Objective: Aluminium has lately been implicated as one of the possible causal factors contributing to Alzheimer's disease and other

  12. Inflammatory process decrease by gallium-aluminium-arsenide (GaAlAs) low intensity laser irradiation on postoperative extraction of impacted lower third molar; Reducao de processo inflamatorio com aplicacao de laser de arseneto de galio aluminio ({lambda}=830 nm) em pos-operatorio de exodontia de terceiros molares inferiores inclusos ou semi-inclusos

    Energy Technology Data Exchange (ETDEWEB)

    Atihe, Mauricio Martins

    2002-07-01

    This study aimed the observation of inflammatory process decrease by the use of GaAlAs Low Intensity Laser ({lambda}=830 nm; 40 mW) irradiation. Five patients were selected and submitted to surgery of impacted lower third molars, both right and left sides at different occasions. On a first stage, a tooth of a random chosen side - right or left - was extracted by conventional surgery, without LILT. The inflammatory process was measured at postoperative on the first, third and seventh days. This side was then called 'control side'. After 21 days, period in which the inflammatory process of the first surgery was terminated, the other side surgery took place, this time using LILT (4 J at four spots) at postoperative, first and third days. As the previous surgery, the inflammatory process was also measured at postoperative on the first, third and seventh days. This side was called 'experimental or lased side'. The inflammatory process was evaluated by measuring its four characteristic signs: swelling, pain, color and temperature. It was clearly observed a decrease for swelling, pain and color on the lased side which presented significant inference and descriptive statistics. It can be concluded that GaAlAs Low Intensity Laser ({lambda}=830 nm) can surely be used as an additional and important anti-inflammatory source on impacted lower third molar surgeries. (author)

  13. Nuevas aplicaciones decorativas de aleaciones a base de aluminio-molibdeno

    OpenAIRE

    V. H. Mesa-Laguna; C. D. Hernández-Pérez; M. A. Alvarez-Pérez; Guzmán, J; M. García-Hipólito; J. A. Juárez-Islas; González, C; O. Alvarez-Fregoso

    2005-01-01

    Las propiedades decorativas de aleaciones bimetálicas nanoestructuradas de aluminio molibdeno se han analizado en función de la composición química y los tratamientos térmicos aplicados. Sus aplicaciones decorativas se deben exclusivamente a que las aleaciones están nanoestructuradas. Las aleaciones se elaboraron a temperatura ambiente por la técnica de erosión catódica a magnetrón en atmósfera de argón, variando los tiempos de depósito para obtener diferentes grosores y composiciones element...

  14. Clinical evaluation of the low intensity laser antialgic action of GaAlAs ({lambda}=785 nm) in the treatment of the temporomandibular disorders; Avaliacao clinica da acao antialgica do laser em baixa intensidade de arseneto de galio e aluminio ({lambda}=785 nm) no tratamento das disfuncoes da articulacao temporo-mandibular

    Energy Technology Data Exchange (ETDEWEB)

    Sanseverino, Nelly Tichauer Maluf

    2001-07-01

    The therapy with laser emitting low intensity has been currently used in the most diverse fields of medicine as therapeutic conduct for pain. It is a non invasive, painless, non-thermal and aseptic type therapy, without any collateral effects, having a good cost/benefit relationship. However, for the therapy with low-intensity laser to result in positive effects, a correct diagnosis is fundamental, as well as a protocol of adequate application. n odontology, the majority of patients diagnosed with temporomandibular disorders (TMD), present pain and limitations in the movements of the jaw. In this work, a GaAlAs laser emitting low intensity, was used, {lambda}=785 nm, in patients having a dysfunction of the temporomandibular joint with a complaint of pain. Twenty patients were divided into two groups. The group treated received laser therapy in the temporomandibular articulations and in the muscles affected. The dose applied was 45 J/cm{sup 2}, while the ten patients in the control group received 0 J/cm{sup 2}, in a total of nine applications, carried out three times a week, during three weeks. he evaluation of the patients was made through clinical examinations of manual palpation of the masseter, temporal, cervical, posterior neck and sternocleidomastoid muscles, and measurements of opening and laterality of the mouth. The results obtained showed a diminishing of the pain and an increase of the mandibular mobility in the patients treated, when compared to the control group. These results point to this therapy as being an important tool in the treatment of pain in patients with a dysfunction in the TMJ, indicating this therapeutic modality as a co-adjuvant in these treatments. (author)

  15. Simulación y experimentación de laminación plana de placas de aluminio 6063

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    Teresa Robert

    2011-06-01

    Full Text Available An experimental methodology was generated for understanding the theoretical and practical concepts inherent to cold flat rolling. Aluminium slabs about 100 mm length, 9 mm thickness with different widths: 10 and 30 mm were rolled. A constant 0.3 mm thickness reduction step was performed in order to achieve a thickness reduction greater than 80 %. In the Abaqus® commercial software, a mathematical model was implemented in order to obtain a greater understanding concerning how the process variables affect the fields of stresses and strains that are not observed experimentally. It was found, by mathematical simulation, that a superficial hardening in the plates was produced and the deformation obtained is heterogeneous, which is corroborated physically. Keywords: Flat rolling; 6063 Aluminium; Data acquisition system; Simulation Se generó una metodología experimental para el entendimiento teórico-práctico de los conceptos del proceso de laminación plana en frío. Se laminaron placas de aluminio de aproximadamente 100 mm de longitud y 9 mm de espesor, a diferentes anchos: 10 y 30 mm. Se seleccionó una razón de reducción constante de 0.3 mm para cada paso de laminación, hasta lograr una reducción superior al 80 % en espesor. Se implementó un modelo matemático en el paquete comercial Abaqus® con el fin de obtener un mayor entendimiento sobre la influencia de las variables del proceso (fuerza aplicada y dimensiones de las probetas en los campos de esfuerzos y deformaciones que, experimentalmente, no se pueden observar. Se encontró, mediante la simulación matemática, que se produce un endurecimiento superficial en las placas y que la deformación obtenida es heterogénea, lo cual se corrobora físicamente.

  16. Desarrollo, análisis y caracterización de procesos de soldeo térmico de espumas de aluminio

    OpenAIRE

    Berenguer Monge, Oscar Manuel

    2012-01-01

    Uno de los retos actuales aún pendiente de lograr trabajando con espumas de aluminio, es el desarrollo de métodos de unión fácilmente reproducibles a nivel industrial que permitan la unión de espumas de aluminio entre sí o con otros componentes tipo pletinas, para así poder fabricar piezas de mayor tamaño o con formas complejas, a la vez que se conserven las propiedades y características principales de las espumas de aluminio, tanto en la zona principal de unión o cordón, como en la interfase...

  17. SÍNTESIS DE ÓXIDOS CONDUCTORES TRANSPARENTES DE ÓXIDO DE ZINC DOPADO CON ALUMINIO POR COPRECIPITACIÓN QUÍMICA

    Directory of Open Access Journals (Sweden)

    Silvia Maioco

    2013-01-01

    Full Text Available Los óxidos de zinc dopados con Al (AZO son promisorios reemplazantes de los óxidos de indio dopados con Sn (ITO pero sus películas delgadas muestran un amplio rango de propiedades fuertemente dependientes de las condiciones del proceso de deposición. Se examinan cerámicos de granulometría submicrométrica de óxido de zinc dopado con 1% de aluminio, preparados por coprecipitación en solución acuosa, a partir de Zn(NO32 y Al(NO33, sinterizados a 1200°C y subsecuentemente templados en atmósfera controlada de 10-16 atm de oxígeno, a 1000°C. La resistividad eléctrica disminuye en dos órdenes de magnitud en las primeras dos horas de templado y el coeficiente Seebeck cambia de -140 a -50 μV/K gradualmente en 8 h. Se concluye que el aumento de la movilidad domina sobre el de densidad de portadores, inducido por cambios de la estequiometria metal oxígeno.

  18. Microstructural and mechanical properties analysis of an aluminium matrix composite reinforced with the amorphous alloy Al{sub 87.5}Ni{sub 4}Sm{sub 8.5} consolidated by hot extrusion; Propriedades mecanicas e microestruturais de um composito com matrix de aluminio e reforco amorfo de Al{sub 87.5}Ni{sub 4}Sm{sub 8.5} consolidado por extrusao a quente por extrusao a quente

    Energy Technology Data Exchange (ETDEWEB)

    Aliaga, L.C.R.; Bolfarini, C.; Kiminami, C.S.; Botta, W.J. [Universidade Federal de Sao Carlos (DEMa/UFSCar), SP (Brazil). Dept. de Engenharia de Materiais; Peres, M.M., E-mail: peresmm@yahoo.com.b [Universidade Federal de Itajuba (UNIFEI), Itabira, MG (Brazil)

    2010-07-01

    The aim of this work is the microstructure and the mechanical properties analysis of an aluminium matrix composite reinforced with the Al{sub 87.5}Ni{sub 4}Sm{sub 8.5} amorphous alloy. The amorphous alloy was produced by melt-spinning and fragmented in powder particles by milling. Pure aluminium power was moistured with amorphous powder in a proportion of 80:20 (% weight) and processed by milling using 350 rpm during 30 minutes for the generation of a homogeneous composite powder. This product was consolidated by extrusion at 235 deg C, ram speed of 2mm/min and extrusion ratio of 7/1, generating a compact and cylindrical bar with 3 mm of width. The result sample was characterized by Scanning Electron Microscopy (SEM), Differential Scanning Calorimetry (DSC) and by X-Ray Diffraction (XRD). Microhardness and compression tests show an improvement on the mechanical properties. (author)

  19. Variación de las constantes elastomecánicas del aluminio puro deformado en frío por estirado

    Directory of Open Access Journals (Sweden)

    Lucena, M.

    1998-05-01

    Full Text Available The changes in the elastic constants at 298 K of polycrystalline samples of pure aluminium (99.5 % with different levels of cold-working have been determined. The deformation process has been carried out in a tension machine. The properties measured are: Young modulus, E, Poisson ratio, v, and yield strength, σ0,2. The Young modulus diminishes from 70 to 63 GPa for 0-2.5 % deformation (elongation and then increases with the successive cold-working passes. The Poisson ratio shows a similar behavior whereas the yield strength increases with cold-work. Pure aluminium behavior is similar to that obtained for pure iron (Armco and for F-1140 annealed steel.

    Se ha determinado, a 298 K, la variación de las constantes elásticas de muestras policristalinas de aluminio puro (99,5 % deformado en frío por estirado. El proceso de deformación se ha llevado a cabo en una máquina de tracción. Se han medido las siguientes propiedades: módulo de Young, E, coeficiente de Poisson, ν, y límite elástico del 0,2 % (σ0,2. El valor del módulo de Young disminuye entre el 0 y 2,5 % de deformación (alargamiento porcentual desde 70 GPa hasta 63 GPa y, después, se recupera alcanzando los valores del material original con el sucesivo trabajo en frío. Se ha observado un comportamiento similar para el coeficiente de Poisson, mientras que el límite elástico del 0,2 % se incrementa con el trabajo en frío, tal como cabía esperar. El comportamiento observado para el aluminio puro es similar al determinado previamente para el hierro puro (Armco y para el acero F-1140 recocido.

  20. Caracterización del aluminio para la fabricación de insertos de moldes de inyección de plásticos.

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    H. González Zulueta

    2008-09-01

    Full Text Available Se describe una investigación experimental realizada para estudiar el comportamiento en condiciones reales de insertos para cavidades fabricados con dos aleaciones de aluminio diferentes. Se fabricaron 1000 piezas (probetas para ensayo de plásticos de polipropileno, empleando un molde de diseño normalizado con insertos para la cavidad correspondiente, fabricados con cada una de las aleaciones a ensayar. Cada 250 piezas producidas, tanto las cavidades como la pieza elaborada fueron medidas en zonas previamente seleccionadas y estos resultados se emplearon para caracterizar el comportamiento de las aleaciones ensayadas. Las condiciones de presión y temperatura del proceso de inyección se seleccionaron atendiendo a los requerimientos industriales que corresponden al plástico utilizado.The behaviour of cavities in molds for plastic injection, manufactured with two different aluminium alloys under real conditions is described by experimental investigation. 1000 pieces (probes for testing mechanical properties of plastics were produced from polypropylene, using a normalized designed mold with specially manufactured cavities and the two tested alloys. For the produced pieces, the dimension (width of the cavities and the elaborated pieces were measured in previously selected areas, these results were used to characterize the behaviour of the tested alloys. The conditions of pressure and temperature for the injection process were selected according to the industrial requirements for the plastic used in the investigation.

  1. Hidro conversión de heptano sobre una bentonita colombiana y una saponita española pilarizadas con aluminio y activadas con ácido

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    Manuel Fredy Molina C.

    2011-03-01

    Full Text Available El presente trabajo estudia una arcilla tipo esmectita, una bentonita colombiana, la cual fue sometida a modificación por pilarización con especies de aluminio, y a modificación por tratamiento con ácido clorhídrico de diferentes concentraciones. Igualmente, se empleó una saponita española modificada por pilarización con Al y tratada con ácido clorhídrico de diferentes concentraciones, con el objetode establecer un paralelo entre los dos tipos de arcillas en su comportamiento frente a las modificaciones estudiadas.Los sólidos fueron caracterizados por técnicas convencionales, tales como análisis químico, capacidad de intercambio catiónico, difracción de rayos X, acidez total y análisis de textura. Los resultados indican que los dos tipos dearcilla fueron igualmente pilarizados con Al, independientemente del origen de la esmectita de partida.Los resultados catalíticos en la hidroconversión de heptano, obtenidos sobre catalizadores bifuncionales (arcilla modificada impregnada con Pt revelan que la AlP-saponita es más eficiente en la isomerización que la AIP-bentonita. Esta mayor eficiencia es atribuida a la presencia de sitios ácidos fuertes tipo Si-OH ... Al, los cuales están presentes únicamente en las esmectitas, donde las sustituciones isomórficas están localizadas en las láminas tetraédricas. En montmorillonitas (bentonita, estas sustituciones se encuentran presentes en las láminas octaédricas, de manera que este tipo de sitios ácidos son reducidos o simplemente están ausentes.

  2. Aplicación de la nanoindentación para la determinación de las propiedades mecánicas interfaciales en materiales compuestos de matriz de aluminio

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    Ureña, A.

    2005-12-01

    Full Text Available Present paper studies tbe application of a new mechanical test technique such us the nanoindention to determine the mechanical behaviour of the matrix-reinforcement interfaces present in the aluminium matrix composites. Tested composites were AA6061 reinforced with SiC particles and with carbon short fibres. Both kind of composites were manufactured using melting conditions which produced a high interaction between the molten aluminium matrix and the reactive reinforcements. To control the interface reactivity, different coating treatments were applied on both type of reinforcements (SiO2 by sohgel methods on the SiC particles and Cu by electroless on the carbon fibres. The characterization was carried out using a Nanoindenter XP, applying loads in the range of 0,5 to 150 mN with a Berkovich indenter. The residual impressions on the specimens surfaces were observed by SEM. The variation of elastic modulus and hardness through the interface and the failure mechanisms were obtained from the study of the load-displacements curves.

    El presente trabajo contempla la aplicación de la técnica de nanoindentación, para determinar el comportamiento mecánico de las intercaras matriz-refuerzo, presentes en materiales compuestos de matriz de aluminio. Los materiales ensayados han sido aleaciones de aluminio 6061 reforzadas tanto con partículas de SiC como con fibras cortas de grafito. Ambos tipos de materiales se fabricaron mediante técnicas de fusión que implican condiciones de alta reactividad entre la matriz de aluminio fundido con el refuerzo correspondiente. Para controlarla, se aplicaron diferentes recubrimientos sobre ambos tipos de refuerzo (SiO2 mediante sol-gel sobre el SiC y cobre por electroless sobre el grafito. La caracterización se realizó empleando un Nanoindenter XP, aplicando fuerzas comprendidas entre 0,5 y 150 mN con una pirámide de diamante tipo Berkovich, procediendo, posteriormente al

  3. Propiedades mecánicas de materiales compuestos de matriz de aluminio reforzados con intermetálicos

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    Torres, B.

    2001-04-01

    Full Text Available In this work 2124 aluminium matrix composites reinforced with Ni3Al, NiAl, MoSiO2 and Cr3Si intermetallic powder particles have been investigated. For comparision purposes, unreinforced 2124 and reinforced with SiC have also been studied. In all cases, the same powder metallurgy route was used, i.e. the 2124 alloy was obtained by rapid solidification and the intermetallic particles by self-propagating high-temperature synthesis (SHS. The matrix and the intermetallics were mechanically blended, cold compacted and finally hot extruded. Tensile tests were carried out in T1 and T4 treatments. Results indicate that mechanical properties depend strongly on the tendence to form new phases at the matrixintermetallic interface during procesing and/or futher thermal treatments. The materials which present better properties are those that present less reaction between matrix and intermetallic reinforcement, i.e. MoSiO2 and SiC reinforced composites.

    En este trabajo se estudia el comportamiento mecánico de varios materiales compuestos de matriz de aluminio 2124 reforzados con partículas de los intermetálicos, Ni3Al, NiAl, MoSiO2 y Cr3Si. Los resultados obtenidos se comparan con la aleación 2124 monolítica y con esa misma aleación reforzada con partículas del cerámico SiC. En todos los casos, se sigue la misma ruta de procesado pulvimetalúrgico a partir de polvos rápidamente solidificados, en el caso de la aleación 2124, y de la molienda mecánica de un tocho obtenido por síntesis autopropagada a temperatura elevada (SHS, para el refuerzo intermetálico. Matriz y reforzante se mezclan, mecánicamente, para, a continuación, compactar uniaxialmente en frío, procediéndose, finalmente, a la consolidación por extrusión. Las propiedades mecánicas se estudian mediante ensayos de tracción en estado T1 y T4. Los resultados obtenidos indican que las propiedades mec

  4. Simplificación del procesado de polvo de aluminio molido y estudio de las propiedades mecánicas de los compactos resultantes

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    Cintas, J.

    2001-04-01

    Full Text Available An alternative powder-metallurgy consolidation method of milled aluminium (M Al powder, consisting in a double cycle of cold pressing and vacuum sintering, has been developed. The aim of the present investigation is to simplify this consolidation method, from the original five steps to only three steps. This would be possible since milled powders soften during desassing, at high temperature. The mechanical properties of compacts (hardness at room and high temperature, ultimate tensile strength and elongation obtained by the three-step and the five-step processing are comparable. This process could be of special interest for the manufacturing of large series of small parts, such as are used in the automotive industry.

    Se ha desarrollado un nuevo método de consolidación pulvimetalúrgica de aluminio molido consistente en una desgasificación seguida de un doble ciclo de prensado y sinterización. El objetivo principal de este trabajo es reducir las anteriores 5 etapas de consolidación a sólo 3, valiéndose del reblandecimiento que sufre el polvo al desgasificarlo a temperatura elevada. Según los resultados obtenidos, las propiedades mecánicas de los compactos finales (dureza, resistencia a la tracción, alargamiento y dureza en caliente son comparables a las obtenidas por ciclo doble. Esta vía de consolidación puede ser de interés para la fabricación de grandes series de piezas pequeñas, como son típicas en la industria del automóvil.

  5. Estudio del mecanismo de reacción durante la refinación de magnesio de aleaciones de aluminio líquidas usando partículas de SiO2

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    Flores, A.

    2008-04-01

    Full Text Available An analysis of the results regarding the permanent contact reaction that occurs between the Mg dissolved in molten aluminum and SiO2 particles is presented. The experiments were carried out at constant temperature and molten metal stirring velocity. In the Scanning Electron Microscope, the crystallographic characteristics of the reaction products were determined using the Electron Backscattered Diffraction Technique, thus allowing to establish the stoichiometry and the mechanism of reaction. The results indicate that the mechanism of reaction is governed by Al, Mg, and Si ions diffusion through the layers of reaction products composed of MgAl2O4 and Al2O3 phases. It was found that during the process the composition of the reaction products changed as the concentration of Mg in the boundary layer diminished.

    Se presentan y discuten los resultados de un estudio acerca de la reacción de contacto permanente que ocurre entre partículas de sílice y el magnesio disuelto en una aleación de aluminio líquida, a temperatura y velocidad de agitación constantes. Se obtuvieron muestras en función del tiempo de contacto, siendo caracterizadas mediante Difracción de Electrones Retrodispersados (EBSD en el Microscopio Electrónico de Barrido. Esto, permitió definir la estructura cristalina de los compuestos que se forman durante las reacciones involucradas y como consecuencia determinar la estequiometría y el mecanismo de reacción. Los resultados indicaron que dicho mecanismo está gobernado por la difusión de los iones de aluminio, magnesio y silicio a través de la porosidad de las capas de MgAl2O4 y Al2O3 que se forman como productos de reacción, encontrándose, además, que la composición de dichos productos cambiaba conforme la concentración de magnesio en la interfase sólido (SiO2-fundido (Al-Mg disminuía.

  6. Autoprotección del aluminio anodizado sin sellar expuesto a la atmósfera

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    Escudero, E.

    2005-04-01

    Full Text Available To confirm or refute the widely held idea that the sealing operation is vital to guarantee the good resistance of anodised aluminium to atmospheric corrosion, unsealed anodised specimens with three different film thicknesses were exposed in 9 atmospheres in Iberoamérica with salinity values of between 3.9 and 684 mg m sup>-2 day-1 of chlorides. Using a wide variety of techniques, from scanning and transmission electron microscopy to direct measurements by gravimetry, and including indirect measurements by electrochemical techniques as well as standard sealing quality control tests, the self-sealing capacity of unsealed anodic coatings during atmospheric exposure is demonstrated. Surprisingly, unlike other types of protective coatings, the quality of anodic films improves with ageing. Keywords

    Para confirmar o rebatir la idea, muy difundida, de que la operación de sellado es imprescindible para garantizar una buena resistencia del aluminio anodizado a la corrosión atmosférica, se expusieron muestras de anodizados sin sellar, de tres espesores diferentes, en 9 atmósferas de Iberoamérica, con salinidades comprendidas entre 3,9 y 684 mg m-2 d-1 de cloruros. Por las más variadas técnicas, desde la microscopía electrónica de barrido o transmisión a la medida directa por gravimetría, pasando por los ensayos normalizados de control de calidad del sellado y la medida indirecta por técnicas electroquímicas, se demuestra la capacidad de autosellado, durante la exposición a la atmósfera, de los recubrimientos anódicos sin sellar. Sorprendentemente, a diferencia de lo que ocurre en recubrimientos protectores de otra naturaleza, la calidad de los anodizados mejora con el envejecimiento.

  7. Simulación y procesado de aleaciones de aluminio mediante estirado en canal angular constante (ECAD

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    Luis, C. J.

    2002-08-01

    Full Text Available In this work, the process called ECAD (Equal Channel Angular Drawing is studied. A material is passed through a die with a constant transverse section, which contains an angle, generally, between 90° and 135°. For this purpose, three aluminium alloys are processed: 1370, 6101 and the 6061 alloy by the routes A, B and C. The evolution of the microstructure is observed according to the number of passes (N and the thermal treatment. Observations by optical and SEM microscopy show the refinement in the grain size of these alloys in relation to the starting alloy. In addition, a simulation of the process with 90° and 120° angles by using Finite Elements Modelling (FEM is performed. Low friction conditions (µ = 0,01 and high friction conditions (µ = 0,4 are assumed in order to establish the friction conditions that lead to the highest deformation values and allow to obtain a high homogeneity. The results obtained with the 1370 alloy show grain sizes of 7 (m after the first passage of ECAD performed by the Route C. Hence, the processing of alloys by the ECAD process would have industrial applicability if a final passage through a calibrated die is performed in order to obtain a constant cross section of the processed alloys.

    En este trabajo se estudia el proceso denominado ECAD (Equal Channel Angular Drawing que consiste en hacer atravesar un material a través de una matriz de sección transversal constante, que presenta un ángulo comprendido, generalmente, entre 90º y 135º. Para ello, se han procesado tres aleaciones de aluminio: 1370, 6101 y la aleación 6061 mediante las rutas A, B y C. En ellas se observa la evolución de la microestructura según el número de pasadas realizadas (N y según el tratamiento térmico. Además, la microscopía óptica y SEM muestran la reducción en el tamaño de grano de las aleaciones procesadas respecto a la aleación de partida. Asimismo, se realiza simulación del proceso por

  8. Caracterización del aluminio para la fabricación de insertos de moldes de inyección de plásticos. // Aluminium alloys behaviour used in the manufacturing of cavities in molds for plastic injection process.

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    H. González Zulueta

    2008-09-01

    Full Text Available Se describe una investigación experimental realizada para estudiar el comportamiento en condiciones reales de insertospara cavidades fabricados con dos aleaciones de aluminio diferentes. Se fabricaron 1000 piezas (probetas para ensayo deplásticos de polipropileno, empleando un molde de diseño normalizado con insertos para la cavidad correspondiente,fabricados con cada una de las aleaciones a ensayar. Cada 250 piezas producidas, tanto las cavidades como la piezaelaborada fueron medidas en zonas previamente seleccionadas y estos resultados se emplearon para caracterizar elcomportamiento de las aleaciones ensayadas. Las condiciones de presión y temperatura del proceso de inyección seseleccionaron atendiendo a los requerimientos industriales que corresponden al plástico utilizado.Palabras claves: Moldes, cavidades, aluminio, experimento, inyección de plástico.__________________________________________________________________________Abstract:The behaviour of cavities in molds for plastic injection, manufactured with two different aluminium alloys under realconditions is described by experimental investigation. 1000 pieces (probes for testing mechanical properties of plastics wereproduced from polypropylene, using a normalized designed mold with specially manufactured cavities and the two testedalloys. For the produced pieces, the dimension (width of the cavities and the elaborated pieces were measured in previouslyselected areas, these results were used to characterize the behaviour of the tested alloys. The conditions of pressure andtemperature for the injection process were selected according to the industrial requirements for the plastic used in theinvestigation.Key words: Mold, cavity, aluminium, experiment.

  9. Regeneración ósea guiada utilizando membrana de óxido de aluminio en combinación con implantes oseointegrados Guided bone regeneration using aluminum oxide membrane in combination with osseointegrated implants

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    M. Isa Majluf

    2007-08-01

    Full Text Available La reabsorción ósea de los maxilares ha sido una de las mayores complicaciones al momento de rehabilitar a pacientes con implantes oseointegrados. El siguiente estudio evaluó la efectividad de la membrana de óxido de aluminio (alúmina, en la regeneración ósea de rebordes colapsados y alvéolos en los que se colocaron implantes. De un total de cinco pacientes seleccionados, se estudiaron siete sitios de los cuales tres correspondieron a un solo paciente. En cada sitio (alvéolo o reborde colapsado se colocó un implante de titanio del sistema HIS y una membrana no biodegradable de óxido de aluminio (Allumina®, la cual fue retirada a las 14 semanas. Todos los pacientes fueron sometidos al mismo procedimiento quirúrgico. La ganancia promedio en mm obtenidos en orden decreciente fue la siguiente: ANM: 1.7mm, ANME: 1.6mm, AND: 1.1mm, AV: 1.0mm, AP: 0.5mm. Los resultados radiográficos ratificaron los resultados clínicos en cuanto a neoformación ósea, observándose además una favorable densidad ósea periimplantaria. El análisis estadístico (basado en los resultados clínicos t-student fue significativo para todos los parámetros evaluados con excepción de AP.Alveolar bone loss has been a very important cause of complications in osseointegrated implant rehabilitation of edentulous patients. This paper evaluates the effectiveness of aluminum oxide membrane (Allumina in the collapsed alveolar ridge where implants were used. Seven sites were studied in 5 patients. In each of these sites a HIS implant plus a non-biodegradable oxide aluminum membrane (Allumina®, was placed for 14 weeks. All patients were treated with the same surgical protocol. The average gain (in mm obtained in decreasing order was as follows: ANM: 1.7 mm, ANME: 1.6 mm, AND: 1.1mm, AV: 1.0mm, AP: 0.5mm. The clinical results were radiographically verified and these showed bone neoformation, in addition to favorable peri-implant bone density. The t-Student statistical

  10. Influencia del tratamiento térmico sobre el endurecimiento por deformación y por velocidad de deformación en aleaciones de aluminio para aplicaciones aeronáuticas

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    Piris, N. M.

    2004-08-01

    Full Text Available The importance of aluminium sheet forming in aerospatial industry makes it necessary to study those parameters that control the behaviour of material during the process. Tensile properties, strain hardening exponent n and strain rate sensitivity m in 7075 aluminium alloy have been studied to relate forming behaviour with control parameters. Tests on O, W, and T6 tempers have been performed, to determine the influence of heat treating. Finally, both longitudinal and long transverse directions tensile specimens have been obtained to analyze the anisotropy.

    La importancia del conformado de chapas de aluminio en la industria aeronáutica y aeroespacial hace necesario un estudio de aquellos parámetros que controlan el comportamiento del material durante el proceso: características del material en tracción y cizalladura, exponente de endurecimiento por deformación, n, exponente de endurecimiento por velocidad de deformación, m, y factor de anisotropía, r, entre otros. Estas propiedades de las chapas metálicas varían en función del metal base, elementos de aleación presentes, tratamiento térmico, procesado previo y textura. Para relacionar el comportamiento durante el conformado con los parámetros que lo controlan, en función del tratamiento térmico, se procedió al estudio de las características en tracción, el parámetro n y el parámetro m para la aleación de aluminio 7075 en forma de chapa, de 1 y 2 mm de espesor, y en tres estados de tratamiento (O, W y T6. Finalmente, se estudió la posible anisotropía, obteniéndose las características tanto en dirección longitudinal como transversal.

  11. Lixiviación alcalina de las colas de la tecnología carbonato amoniacal para la extracción de aluminio

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    Carmen Hernández-Fernández

    2013-11-01

    Full Text Available Se estudió la termodinámica del proceso de lixiviación alcalina de las colas derivadas del proceso carbonato amoniacal para conocer la espontaneidad de las reacciones y comprobar la posibilidad de extracción del aluminio utilizando como agente lixiviante el hidróxido de sodio (NaOH. Las colas, una vez caracterizadas químicamente, se lixiviaron a escala de laboratorio aplicando un diseño experimental factorial completo. La variación de energía libre indica que es posible extraer aluminio de las colas, lixiviándolas con hidróxido de sodio; para un 45 % de sólido las mayores extracciones se obtienen a 200 ˚C y 30 min. El silicio y el magnesio también mostraron selectividad con el reactivo utilizado

  12. Tensiones residuales en uniones soldadas por FSW en aluminio 7075-T651 Residual stresses in 7075-T651 FSW joint

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    Leonardo N. Tufaro

    2012-12-01

    Full Text Available Las tensiones residuales pueden ser un aspecto de relevancia en la integridad estructural de componentes en servicio, pudiendo presentar una importante influencia sobre la vida a la fatiga, entre otros mecanismos de falla. El proceso de soldadura por fricción-agitación (FSW ha revolucionado en los últimos años el campo de la tecnología de la soldadura. Su mayor aplicación se ha dado en las aleaciones de aluminio, aunque hoy en día se utiliza para prácticamente todos los materiales. Una de las ventajas enunciadas de este proceso es el menor nivel de tensiones residuales resultantes, debido a que se produce en estado sólido por lo que los gradientes térmicos durante la soldadura son menores. Entre las aleaciones de aluminio de uso estructural, las aleaciones termoenvejecibles de la serie 7XXX se utilizan habitualmente en la industria aeronáutica y aeroespacial debido a su alta resistencia mecánica. El objetivo del presente trabajo es analizar el efecto de la velocidad de avance en FSW sobre las tensiones residuales en juntas de aluminio AA7075-T651, mediante la técnica de seccionamiento. Se soldaron probetas de dicha aleación de 150x150x4mm mediante FSW, variando la velocidad de avance entre 51 y 206 mm.min-1. Durante la soldadura se adquirieron los ciclos térmicos. Posteriormente se midieron las tensiones residuales longitudinales a distintas distancias del cordón de soldadura, en cada caso. A partir de los ciclos térmicos adquiridos se obtuvieron los gradientes térmicos en la zona de medición. Las tensiones residuales máximas se encontraron entre 52 y 78 MPa, correspondiente entre 10 y 15 % del límite de fluencia del material. Las mismas aumentaron con la velocidad de avance, consistentemente con un aumento en el gradiente térmico observado. Dichos valores de tensiones residuales son menores que los obtenidos para la soldadura de estos materiales mediante procesos del tipo GMAW.Residual stresses could be a relevant issue in

  13. ALTERACIONES CELULARES INDUCIDAS POR EL IÓN AL 3+ EN DOS VARIEDADES CUBANAS DE ARROZ (Oryza sativa L.

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    Idioleidys Alvarez

    2005-01-01

    Full Text Available Con el propósito de estudiar las modificaciones, que a nivel celular provoca el aluminio en el sistema radicular del arroz, se desarrolló un experimento, en el cual se emplearon diferentes dosis de AlCl3 para imponer la condición de estrés. Para el estudio los ápices radicales de las plántulas se procesaron por un método de disminución progresiva de la temperatura (PLT y se incluyeron en resina Lowicryl para su posterior seccionamiento y observación al microscopio de Contraste de Fase. Se apreciaron cambios en la orientación del crecimiento de células epidérmicas y corticales, lo cual contribuyó a la inhibición del alargamiento celular. Las paredes de algunas células se observaron engrosadas e irregulares y se evidenció un incremento en el tamaño de las vacuolas, fenómeno observado también en otras plantas ante la exposición con aluminio. Los resultados obtenidos demuestran que el aluminio provoca alteraciones en las células radicales del arroz, algunas de las cuales son responsables estructuralmente de cambios morfológicos como el engrosamiento y acortamiento de las raíces, hallados con anterioridad en nuestro laboratorio para el cultivo del arroz ante este estrés.

  14. Estudio Comparativo de Sulfato de Aluminio y Semillas de Moringa oleifera para la Depuración de Aguas con Baja Turbiedad Comparative Study of Aluminum Sulfate and Moringa oleifera seeds as Coagulants in the Clarification of Water with Low Turbidity

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    Patrícia G.S Lédo

    2009-01-01

    Full Text Available El presente trabajo tiene como objetivo investigar la eficiencia de dos coagulantes, el sulfato de aluminio y semillas de Moringa oleifera, para remoción de turbiedad en muestras del agua provenientes de la Laguna de Jiqui, estado del Rio Grande do Norte, Natal-Brasil. Las dosificaciones y pH de los coagulantes fueron variados entre límites establecidos. Se realizaron pruebas, en tubos de ensayo Jar-Test y medidas de movilidad electroforética para determinar el potencial Zeta y para determinar los posibles mecanismos involucrados en el proceso de coagulación. Los mecanismos de coagulación con semillas de Moringa oleifera son adsorción y neutralización de cargas y adsorción y formación de puentes. Los resultados sugieren que para aguas de baja turbiedad, las semillas de Moringa oleifera pueden ser un sustituto potencialmente viable al sulfato de aluminio para la clarificación de dichas aguas.The objective of the present work is to investigate the efficiency of a coagulant prepared from Moringa oleifera seeds, for clarifying water samples with low turbidity from the Jiqui Lake, in the State of Rio Grande do Norte, Natal-Brazil. The dosages and pH of the coagulants were changed within defined limits. Jar-test essays and measurements of electrophoretic mobility were done to determine the Zeta potential and the possible mechanisms involved in the coagulation process. The mechanisms of coagulation with Moringa oleifera are absorption and neutralization of charges and absorption and bridging. The results suggest that for low turbidity waters, Moringa oleifera seeds represent a potentially viable substitute of aluminum sulfate for water clarification.

  15. Evolución microestructural de la aleación de aluminio 6061 durante el proceso de soldadura MIG

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    Jaime Torres S.

    2002-01-01

    Full Text Available En este artículo se establece una correlación entre las variables del proceso de soldadura, como la intensidad de la corriente, la tensión, la velocidad de soldadura, las temperaturas pico, grados de microdureza alcanzadas y la evolución de la precipitación en la lámina de una aleación de aluminio 6061 a las distancias de 7, 13 y 20 mm del centro del cordón. Se utilizó un programa de elementos finitos de propósito general, para predecir el efecto del calor aportado en la soldadura GMAW sobre los valores de las propiedades mecánicas. Se encontró que el perfil de microdureza depende fuertemente de la distribución de los precipitados, y esta distribución depende, a su vez, de los ciclos térmicos que sufre el material durante el proceso de soldeo, siendo el ancho de la zona crítica más angosta cuanto más alta es la velocidad de aportación

  16. Evaluación de la capacidad de soporte de carga de recubrimientos duros depositados sobre la aleación de aluminio 7075-T6

    Directory of Open Access Journals (Sweden)

    Moreno, E. T.

    2007-12-01

    conjunto es sometido a cargas de indentación esférica. El sistema dúplex se obtuvo mediante la deposición de un recubrimiento autocatalítico electroless de Ni-11 % P sobre la aleación de aluminio y, posteriormente, la de un recubrimiento duro de ZrN (PVD sobre las muestras previamente recubiertas con EN. Se obtuvieron dos sistemas dúplex con intercapas de aproximadamente 30 y 60 mm de espesor. Se realizó la caracterización de los recubrimientos en términos de su morfología, espesor y dureza absoluta. Los ensayos de indentación esférica se realizaron empleando bolas de WC-6 Co de 6 mm diámetro y las cargas normales utilizadas fueron de 10, 15, 25, 50 y 75 N, respectivamente. Todas las indentaciones fueron simuladas mediante el programa Elastica 2.1., con la finalidad de determinar tanto el perfil de tensiones efectivas de von Mises, a través del espesor de las muestras como la carga crítica para el inicio de la deformación plástica en el substrato. Los resultados experimentales fueron validados con las predicciones teóricas, encontrándose que el sistema dúplex con una intercapa de 30 mm de espesor no ofrece un buen soporte de carga, al menos en las condiciones experimentales evaluadas. Sin embargo, cuando el espesor de la intercapa es de 60 mm, la deformación plástica del substrato no ocurre siempre y cuando el sistema recubierto sea sometido a cargas de indentación menores que la carga crítica obtenida para dicho sistema, cuyo valor es ~ 16 N.

  17. Síntesis coloidal de materiales nanoestructurados de Al-ZrAl3: Propiedades mecánicas mediante el ensayo miniatura de punzonado

    Directory of Open Access Journals (Sweden)

    Díaz, L. A.

    2009-08-01

    Full Text Available This work describes a new method to obtain Al-Zr intermetallic nanostructured materials by using a colloidal processing technique. The combination of Al powders and zirconium IV-propoxide (C12H28O4Zr under controlled conditions results in a metal matrix composite with a homogeneous dispersion of intermetallics. Synthesis was carried out in a tubular furnace under argon and by hot pressing under the same atmospheric conditions. XDR and SEM were used to identify the intermetallic nanoparticles. The Vickers hardness of the ZrAl3 nanocomposites and the mechanical behaviour by small punch test were studied.

    En este trabajo se describe un nuevo método de procesamiento coloidal para obtener materiales nanoestructurados de base aluminio con partículas intermetálicas ZrAl3. A partir de una mezcla controlada en alcohol, de polvos de aluminio con un alcóxido precursor de zirconio (C12H28O4Zr se obtiene, mediante un tratamiento térmico en un horno convencional con atmósfera controlada o por prensado uniaxial en caliente, un polvo nanoestructurado formado por cristales de aluminio sobre los que cristalizan, de forma homogénea, nanopartículas intermetálicas de ZrAl3. La identificación del intermetálico se efectuó por difracción de rayos X y microscopía electrónica de barrido. El comportamiento mecánico de los materiales nanoestructurados desarrollados se evaluó a partir de ensayos de dureza y mediante el ensayo miniatura de punzonado (EMP. Los resultados muestran que la presencia del intermetálico de zirconio hasta un 1,0 % (en peso de zirconio aumenta la dureza y rigidez de la matriz de aluminio, al tiempo que incrementa su resistencia mecánica (límite elástico y resistencia a la tracción.

  18. Aluminum as a risk factor for Alzheimer's disease Aluminio como factor de riesgo para la enfermedad de Alzheimer Alumínio como fator de risco para a doença de Alzheimer

    Directory of Open Access Journals (Sweden)

    Pricilla Costa Ferreira

    2008-02-01

    Full Text Available The purpose of the study was to condense existing scientific evidence about the relation between aluminum (Al exposure and risk for the development of Alzheimer's Disease (AD, evaluating its long-term effects on the population's health. A systematic literature review was carried out in two databases, MEDLINE and LILACS, between 1990 and 2005, using the uniterms: "Aluminum exposure and Alzheimer Disease" and "Aluminum and risk for Alzheimer Disease". After application of the Relevance Test, 34 studies were selected, among which 68% established a relation between Al and AD, 23.5% were inconclusive and 8.5% did not establish a relation between Al and AD. Results showed that Al is associated to several neurophysiologic processes that are responsible for the characteristic degeneration of AD. In spite of existing polemics all over the world about the role of Al as a risk factor for AD, in recent years, scientific evidence has demonstrated that Al is associated with the development of AD.El objetivo del estudio fue condensar la evidencia científica existente entre la exposición al aluminio (Al y el riesgo para el desarrollo de la Enfermedad de Alzheimer (EA, evaluando los efectos para la salud de la población a largo plazo. Una revisión sistemática de la literatura científica existente entre 1990 y 2005, fue realizada en dos bases de datos, MEDLINE y LILACS, utilizando los unitermos: "Aluminium exposure and Alzheimer Disease" y "Aluminium and risk for Alzheimer Disease". Fueron seleccionados 34 trabajos para la investigación, de los cuales 68% establecieron relação entre el Al y la EA, 23,5% no presentaron datos conclusivos y 8,5% no establecieron ninguna relación entre el Al y la EA. A partir de los resultados obtenidos, se verifica que el Al interviene en diversos procesos neurofisiológicos responsables por la degeneración característica de la EA. A pesar de la polémica existente en el médio científico, la evidencia cient

  19. Análisis experimental y numérico del proceso de perforación de aluminio en ensayos de punzonado dinámico

    OpenAIRE

    Funes Vecino, Iago

    2015-01-01

    En los últimos años, en muchos campos de la ingeniería se han realizado estudios exhaustivos sobre el comportamiento de las aleaciones de metales con los requisitos fundamentales de las propiedades de peso ligero y la integridad estructural. En particular, las aleaciones de aluminio están siendo ampliamente introducidas en los sectores automovilístico y aeronáutico. Por lo tanto, es necesario un análisis exhaustivo en términos de tensiones aplicadas y realizar predicciones de fallo en estruct...

  20. Caracterización superficial de nuevos pre-tratamientos a base de silanos aplicados sobre aluminio

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    Gener, M.

    2005-12-01

    Full Text Available Silane- based pre-treatments are an alternative process for the chrome-based corrosionpreventive commercial pre-treatments, without salubrity problems and that in initial exploratory studies have yielded promising results regarding corrosion protection and adhesion promotion. In the framework of the research about the anticorrosive capacity of these compounds that it's being undertaken for different silane and substrates, some preliminary results are presented in this paper. Specifically, the results of the surface characterisation through SEM-EDS (Scanning Electron Microscopy and XPS (X-Ray Photoelectron Spectroscopy for two silanes with different functional groups (3-aminopropyltriethoxysilane or γ-APS and 3-glycidyloxypropyltrimethoxysilane or γ-GPS, prepared at different pH and applied as primers on an aluminium substrate, are discussed.

    Un proceso alternativo a los pre-tratamientos comerciales anticorrosivos a base de cromo, sin problemas de salubridad y que en estudios exploratorios iniciales ha dado resultados prometedores en cuanto a la protección frente a la corrosión y la mejora de la adherencia, son los pre-tratamientos a base de silanos. En el marco de la investigación sobre la capacidad anticorrosiva de estos compuestos que se está realizando para diferentes silanos y substratos, se presentan en este artículo algunos de los resultados preliminares. En concreto, se discuten los resultados de la caracterización superficial mediante técnicas de SEM-EDS (Scanning Electron Microscopy y XPS (X-Ray Photoelectron Spectroscopy para dos silanos con distintos grupos funcionales (3-aminopropiltrietoxisilano o γ-APS y 3-glicidiloxipropiltrimetoxisilano o γ-GPS, preparados a distintos pH y aplicados como imprimación sobre un substrato de aluminio.

  1. Bioactive type glass-ceramics within incorporated aluminium; Vitroceramicos del tipo bioactivo con aluminio incorporado

    Energy Technology Data Exchange (ETDEWEB)

    Volzone, C.; Stabile, F.M.; Ortiga, J., E-mail: volzcris@netverk.com.ar [Centro de Tecnologia de Recursos Minerales y Ceramica (CETMIC), Buenos Aires (Argentina)

    2012-07-01

    Bioactive glass-ceramics are used as biomaterials for the reparation of bone tissue. They are prepared, generally, by bioglass of specific composition for each particular use. The aluminium addition in the formulation at very small quantities influences on the structural properties. Two glass-ceramics obtained by P{sub 2}O{sub 5}-Na{sub 2}O-CaO-SiO{sub 2} formulation within aluminium (0.5 % in Al{sub 2}O{sub 3} base) added through a reactive alumina and purified feldspar were analyzed. The results showed structural differences between both glass-ceramics. (author)

  2. Caracterización química de Andisoles repelentes al agua del oriente Antioqueño.

    Directory of Open Access Journals (Sweden)

    Jaramillo J. Daniel F.

    1999-12-01

    Full Text Available Se evaluaron algunas propiedades químicas de 76 Andisoles repelentes al agua, de lotes bajo cobertura de Pinus Patula muchas de las propiedades evaluadas presentaron coeficientes de variación con valores relativamente altos, mayores a 20%; sólo los pHs presentaron coeficientes de variación menores de 10%. Al interpretar los valores de las propiedades relacionadas con la fertilidad, puede decirse que estos suelos son de muy baja fertilidad, con muy bajos contenidos de nutrimientos, baja saturación con bases, alta saturación con aluminio, muy ácidos y con baja CICE.

  3. Materiales nanométricos para recubrimientos avanzados: el sistema Al2O3-TiO2

    OpenAIRE

    Villanueva Ibáñez, Regina

    2012-01-01

    En este trabajo se describe la síntesis de nanomateriales basados en óxidos de aluminio o de titanio, y sus mezclas, así como su posterior caracterización por técnicas adecuadas. La elección de estos materiales se ha basado en su potencial aplicabilidad en el sector de los recubrimientos avanzados. Debido a las excelentes propiedades mecánicas de la alúmina, a su estabilidad química y a su baja conductividad eléctrica, los recubrimientos de alúmina son candidatos para su uso en condicion...

  4. ALTERACIONES CELULARES INDUCIDAS POR EL IÓN AL 3+ EN DOS VARIEDADES CUBANAS DE ARROZ (Oryza sativa L.)

    OpenAIRE

    Idioleidys Alvarez; Ofelia Sam; Inés Reynaldo

    2005-01-01

    Con el propósito de estudiar las modificaciones, que a nivel celular provoca el aluminio en el sistema radicular del arroz, se desarrolló un experimento, en el cual se emplearon diferentes dosis de AlCl3 para imponer la condición de estrés. Para el estudio los ápices radicales de las plántulas se procesaron por un método de disminución progresiva de la temperatura (PLT) y se incluyeron en resina Lowicryl para su posterior seccionamiento y observación al microscopio de Contraste de Fase. Se ap...

  5. Relación entre los mecanismos de alimentación y el modo de solidificación en una aleación de aluminio 380 con distintos contenidos de hierro

    Directory of Open Access Journals (Sweden)

    Tovio, D. O.

    2003-08-01

    Full Text Available In the present work the effect of iron (0.15, 0.42 and 0.86 % content in feeding mechanisms for 380 aluminium alloy has been studied. The feeding capacity has been evaluted by a device that produces a barrier removable to allowing the movement of the interdendritic liquid. The results show the flow of different quantity of liquid, it depends of the temperature of opening the device and of the iron content. For minimun and maximun iron content, the interdendritic and burst feeding mechanisms are fundamently involved, for 0.42 % of iron the feeding mechanisms was the interdendritic.The authors establish this behavior by the solidification mode of alloy, which promotes the presence of particles of Si or plates of b-Al5FeSi phase, in the interdendritic channels and produce the different feeding mechanisms.

    En el presente trabajo ha sido estudiado el efecto del Fe (0,15, 0,40 y 0,85 % sobre los mecanismos de alimentación en una aleación de aluminio 380 (L-2630, EN-46.000. Se evaluó la capacidad de alimentación, mediante un dispositivo consistente en una barrera movible que permite escurrir al líquido interdendrítico. Los resultados muestran el escurrimiento de distinta cantidad de líquido, dependiendo de la temperatura de apertura del dispositivo y del contenido de Fe de la aleación. Para los contenidos mínimos y máximos de Fe, los mecanismos involucrados son fundamentalmente los de alimentación interdendrítica y forzada, y para el contenido medio de Fe se evidenció el de alimentación interdendrítica. Los autores justifican este comportamiento en función del modo de solidificación de la aleación, el cual promueve la presencia de partículas de Si o placas de fase b-Al5FeSi en los canales interdendríticos e inducen la actuación de distintos mecanismos de alimentación.

  6. Polvos de Al-Al3Ti obtenidos mediante aleado mecánico y tratamiento térmico

    Directory of Open Access Journals (Sweden)

    Gallardo, J. M.

    2005-12-01

    Full Text Available Mixed powders of aluminium and titanium (10 wt % have been mechanically alloyed in an Attritor mill. A metastable solution of titanium in an aluminium matrix is obtained. Changes produced on shape and particle size, structure and microstructure, have been studied when milling time varies between 2 and 10 h. The final processing is carried out for a milling time of 10 h, with approximately 9 wt % of titanium dissolved in the matrix. Finally, a heat treatment is carried out at different temperatures, up to a maximum of 625 °C, which produces the precipitation of different phases such as different structures of Al3Ti and Al4C3. The appearance of these second phases is characterized according to the selected heat treatment temperature.Polvos mezclados de aluminio y titanio (10 % en peso han sido aleados mecánicamente en un molino Attritor, obteniéndose una solución metaestable de titanio en la matriz de aluminio. Se han estudiado los cambios producidos en la forma y tamaño de las partículas, estructura y microestructura, al variar el tiempo de molienda entre 2 y 10 h. El procesado final se realiza para un tiempo de 10 h, habiéndose disuelto aproximadamente un 9 % en peso de titanio. Finalmente, se realiza un tratamiento térmico a diversas temperaturas, hasta un máximo de 625 °C, lo que produce la precipitación de diversas fases, como distintas estructuras de Al3Ti y Al4C3. La aparición de estas segundas fases es caracterizada en función de la temperatura de tratamiento utilizada.

  7. Estudio cinético de la eliminación de magnesio en las aleaciones de aluminio mediante la inyección de polvos de sílice

    Directory of Open Access Journals (Sweden)

    Escobedo, J. C.

    2003-06-01

    Full Text Available A kinetic study on the magnesium removal from molten aluminium alloys using submerged SiO2 powders injection is presented. The variables analysed were the chemical content and the particle size of the solid agents, the melt temperature and the injection rate. It was possible to decrease the magnesium content from 1.2 to 0.02wt %, with a low inclusions content. As the main mechanism of the magnesium removal process is of diffusive type, the global process rate increases as the temperature and the injection rate are increased, while decreasing particle size. In all the cases studied, a first order global process was determined and the global rate constants were also evaluated.

    Se presenta un estudio cinético de la eliminación de magnesio de una aleación base aluminio líquida, utilizando la técnica de inyección de agentes sólidos base SiO2 transportados por un gas inerte. Las variables estudiadas son: la composición de los agentes sólidos, la temperatura del baño metálico, la velocidad de inyección y el tamaño de partícula de los agentes sólidos. Se logró disminuir el contenido de magnesio en la aleación, desde 1,2 hasta 0,02 % en peso, encontrándose que, debido a que el mecanismo que gobierna la cinética de eliminación de magnesio es de carácter difusivo, la velocidad de reacción aumenta al incrementarse la temperatura y la velocidad de inyección y al disminuirse el tamaño de partícula. También, se determinó que el proceso de eliminación de magnesio es de primer orden, evaluándose, además, las constantes de velocidad del proceso global a las diferentes condiciones experimentales empleadas.

  8. Formación de porosidad durante la soldadura láser de Nd: YAG de onda continua en aleaciones de aluminio para aplicaciones automotrices

    Directory of Open Access Journals (Sweden)

    Pastor, Mario

    2000-04-01

    Full Text Available Pore formation is an important concern in laser welding of automotive aluminum alloys. This paper investigates the influence of the laser beam defocusing on pore formation during continuous wave Nd: YAG laser welding of aluminum automotive alloys 5182 and 5754. It was found that the instability of the keyhole during welding was a dominant cause of pore formation while hydrogen rejection played an insignificant role. The defocusing of the laser beam greatly affected the stability of the keyhole. Finally, the mechanism of the collapse of the keyhole and pore formation is proposed.

    La formación de poros es un aspecto de gran preocupación durante la soldadura láser de aleaciones de aluminio. En este trabajo se ha investigado la influencia del desenfoque del haz del láser sobre la formación de poros durante la soldadura láser (Nd: YAG de onda continua de las aleaciones de aluminio 5182 y 5754, las mismas que se usan en aplicaciones automotrices. Los resultados obtenidos indicaron que la causa dominante de formación de poros fue la inestabilidad de la cavidad de vapor o keyhole mientras que la influencia del hidrógeno fue prácticamente insignificante. El grado de desenfoque del láser tuvo gran influencia sobre la inestabilidad de la cavidad de vapor. Finalmente, en este artículo se propone el mecanismo de formación de poros a causa del colapso de la cavidad de vapor (keyhole.

  9. Determinación de la variación de entalpía de la interacción entre el herbicida glifosato, y los iones de calcio, zinc y aluminio en solución acuosa por calorimetría isotérmica de titulación.

    Directory of Open Access Journals (Sweden)

    Flavio Adriano Bastos

    2010-12-01

    Full Text Available El glifosato [N-(fosfonometil glicina] es una molécula no selectivo ampliamente utilizado en Brasil como un desecante en los cultivos sin labranza, entre las hileras de los cultivos perennes y para la eliminación de las malezas en ambientes acuáticos. Es el herbicida más usado en el mundo. Debido a la presencia de grupos amino, carboxílico y fosfónico en su molécula, este herbicida es capaz de formar complejos con metales fuertes. El objetivo de este trabajo fue la determinación de los parámetros de la termodinámica de las interacciones entre el glifosato y el calcio, cobre, zinc y aluminio por calorimetría isotérmica de titulación (ITC. Los experimentos se llevaron a cabo a 298,15 K en una solución acuosa de pH controlado y es igual a 2,00. El tratamiento de los datos se realizó por el Método de la Tangente. Los resultados para el cambio de entalpía (kJ.mol-1, la energía libre de Gibbs (kJ.mol-1 y cambio de entropía (J.mol-1K-1, fueron, respectivamente: Ca (II = + 0,07 ± 0,01; - 18,8 ± 0,5, 63,0 ± 2; Cu (II = + 6,24 ± 0,06, - 67,9 ± 0,5, 249 ± 2; Zn (II = + 0,25 ± 0,01, - 49,7 ± 0,5, 167 ± 2 e Al (III = + 6,84 ± 0,45, - 78,2 ± 0,5, 285 ± 2. Los complejos formados son entrópicamente impulsado, desde el punto de vista energético, las interacciones se presentan muy pobres, que pueden ser observadas por los valores positivos del cambio de entalpia. Esto se debe principalmente a la eliminación de las moléculas de agua de hidratación de los iones de metal para la mayor parte de la solución. Con la información actual, podemos concluir que la complejidad del herbicida con el ion de aluminio es más fuerte que con otro cationes.

  10. Materiales cerámicos policristalinos de Al2O3 y YAG con funcionalidad óptica

    OpenAIRE

    Suárez Menéndez, Marta

    2009-01-01

    En esta memoria se estudia la obtención de materiales policristalinos de alúmina y YAG (granate de itrio y aluminio) transparentes en el infrarrojo cercano y en el visible, empleando una ruta de procesamiento cerámico y evitando la introducción de segundas fases. La condición general que cualquier material no absorbente debe cumplir para evitar fenómenos de dispersión de luz y, por lo tanto, pérdidas de calidad óptica, es la homogeneidad espacial con respecto a sus propiedades dieléctricas. P...

  11. Reducción del tiempo y de la temperatura de sellado del aluminio anodizado con aditivos orgánicos

    Directory of Open Access Journals (Sweden)

    Bautista, A.

    1998-05-01

    Full Text Available Different sealing processes of anode coatings in aluminium oxide have been industrially used for more than 30 years. In two of the preceeding decades a great effort was realized to reduce costs in the traditional hydrothermal sealing process in deionized boiling water (SHT, a very expensive process due to its endurance and high temperature on which it develops. New sealing procedures are proposed, on which by means of the use of organic additives, the time or the temperature of the SHT is essentially reduced.

    Diferentes procesos de sellado de las capas anódicas de óxido de aluminio se han utilizado industrialmente desde hace más de 30 años. En los dos decenios precedentes se ha realizado un gran esfuerzo para reducir los costes de la operación del sellado hidrotérmico tradicional, en agua desionizada a ebullición (SHT, una operación muy costosa por su duración y la temperatura a la que se desarrolla. Se proponen nuevos procedimientos de sellado en los que, mediante la utilización de aditivos orgánicos, se reduce sustancialmente el tiempo del SHT o la temperatura del mismo.

  12. Comportamiento mecánico de compuestos de aluminio reforzados con partículas en función de la temperatura

    Directory of Open Access Journals (Sweden)

    Amigó, V.

    2001-04-01

    Full Text Available The aluminium matrix composites materials reinforced by ceramic particles can be elaborated by powder metallurgy techniques, with extrusion processes. These can provide new materials, with a better mechanical behaviour and moreover when we need those properties at higher temperatures. Aluminium alloy reinforced composites with silicon nitride particles by powder extrusion process was done. Their mechanical properties were characterised at room and elevated temperatures.

    La obtención de materiales compuestos de matriz de aluminio por técnicas pulvimetalúrgicas junto a procesos de extrusión, permite desarrollar materiales reforzados con partículas cerámicas, con propiedades mecánicas mejoradas y más si se demanda un trabajo a elevada temperatura. Se han desarrollado materiales reforzados con nitruro de silicio por extrusión de polvos, realizándose la caracterización de sus propiedades mecánicas a temperatura ambiente y elevada.

  13. Modelación matemática del mezclado en ollas (cucharas de aluminio equipadas con la técnica de desgasificación rotor-inyector

    Directory of Open Access Journals (Sweden)

    Ramírez-Argáez, M. A.

    2006-06-01

    Full Text Available In this work a fundamental Eulerian mathematical model was developed to study fluid flow and mixing phenomena in aluminum ladles equipped with impeller for deshidrogenization treatment. The effect of critical process parameters such as rotor speed, depth of immersion, gas flow rate, and type of rotor on the mixing behavior and vortex formation was analyzed with this model. The model simulates operation with and without gas injection and it was developed on the commercial CFD code PHOENICS 3.4 in order to solve all conservation equations governing the process, i.e. continuity, 3D turbulent Navier-Stokes and the k-e turbulence model for a two-phase fluid flow problem using the Inter Phase Slip Algorithm (IPSA. In order to realistically represent the process, shape of the furnace and three kinds of impellers were drawn by employing Body Fitted Coordinates (BFC. From the results it was concluded that mixing behavior is highly dependent on the rotor speed and on the rotor type. Mixing time is improved when: 1 Impeller is located at a depth of 0.229m into the aluminum bath, 2 By using high rotor speeds, 3 By using ladles with a high aspect ratio of Diameter to Height, and 4By using an impeller with notches.

    Se desarrolló un modelo matemático Euleriano para analizar el flujo de fluidos y el mezclado en ollas (cucharas de tratamiento de aluminio equipadas con rotor-inyector, variando parámetros del proceso como la velocidad de giro del rotor, la distancia de inmersión de la flecha, el flujo de gas, el tipo de rotor y el factor de forma de la olla (cuchara (relación altura/diámetro. El modelo matemático simula la operación, con y sin inyección de gas, a través del rotor, empleando el código comercial PHOENICS donde se resolvieron las ecuaciones de continuidad, momento, especies químicas y turbulencia, k-e, de forma simultánea, tanto para la fase líquida como para la gaseosa. El dominio se dibujó, realistamente, empleando coordenadas

  14. Propiedades mecánicas de materiales compuestos de matriz de aluminio reforzados con intermetálicos

    OpenAIRE

    B. Torres; García-Escorial, A.; J. Ibáñez; Lieblich, M.

    2001-01-01

    In this work 2124 aluminium matrix composites reinforced with Ni3Al, NiAl, MoSiO2 and Cr3Si intermetallic powder particles have been investigated. For comparision purposes, unreinforced 2124 and reinforced with SiC have also been studied. In all cases, the same powder metallurgy route was used, i.e. the 2124 alloy was obtained by rapid solidification and the intermetallic particles by self-propagating high-temperature synthe...

  15. Optimización de los tratamientos térmicos T5 y T6 para una aleación de aluminio A356 conformada por SLC

    OpenAIRE

    Fresno Abad, David

    2007-01-01

    La gran competencia que hay en el sector de la automoción y aeronàutica obliga a las industrias a producir nuevos componentes de aluminio con mejores propiedades mecánicas, menos defectos y encontrar fórmulas para reducir los costes de producción, esto se ha conseguido con las técnicas de conformación en semisólido. Los componentes conformados con estas técnicas pueden ver mejoradas sus propiedades mecánicas mediante tratamientos térmicos. Un tratamiento térmico es un proceso industrial...

  16. Estudio de las propiedades mecánicas en materiales compuestos de matriz aluminio pulvimetalúrgicos conformados mediante forja o extrusión

    Directory of Open Access Journals (Sweden)

    Busquets, D.

    2005-10-01

    Full Text Available We have developed composite materials from AA6061 aluminium alloy powders used as matrix and ceramics powders of boron carbide, silicon carbide and boron nitride, used as reinforcements in 2.5, 5.0, 1.5 and 10 % vol. by mechanical mixing and milling in planetary mill at 360 rpm vial velocity for 4 h followed of hot stamping and extrusion process on green compacts. Mechanical properties obtained from tensile tests are influenced by the heat treatment, reinforcement fractions and nature. Moreover, these mechanical characteristics are dependent from the processing route. Optical and Scanning Electron Microscopy analysis revealed the microstructure of materials and let describe the tripartite relation; structure-processing-properties, of the developed materials.

    Partiendo de polvos de aleación de aluminio AA6061 empleada como matriz y de polvos cerámicos de carburo de boro, carburo de silicio y nitruro de boro, utilizados como refuerzo en fracciones volumétricas de 2,5, 5,0, 7,5 y 10 %, se ban desarrollado materiales compuestos, mediante la mezcla y molienda mecánica de estos polvos, en molino planetario a 360 rpm durante 4 h y posterior estampación y extrusión en caliente de compactos en verde. Las propiedades mecánicas se determinaron mediante ensayos de tracción, observándose gran influencia del tratamiento térmico, contenido y naturaleza del refuerzo, sobre estas propiedades. Por otro lado, se encontró que estas características son igualmente dependientes de la ruta de producción de estos materiales. Los análisis llevados a cabo mediante microscopía óptica y microscopía electrónica de barrido, permitieron describir la relación tripartita, estructura-procesamiento-propiedades, de los materiales aquí desarrollados.

  17. Modificación superficial de aleaciones de base aluminio (anodizadas y no anodizadas mediante recubrimientos de sílice

    Directory of Open Access Journals (Sweden)

    García-Heras, M.

    2004-04-01

    Full Text Available Transparent and colourless silica coatings were deposited on anodising and non-anodising substrates of aluminium-base alloys (series 6063. Coatings were prepared by soLgel (dipping method from a silica alkoxide and a mixture of both silica alkoxide and silica alkylalkoxide. Preparations were optimised from viscosity, density, surface tension, and contact angle measurements. Densification was carried out at 60 and 120 °C. Reflectance attenuation of coated samples was analysed by UV-VIS-NIR spectroscopy. The results indicated that -10 % of attenuation is reached. Durability and resistance against degradation tests of the metal/coating system were undertaken by immersion into aqueous solutions. Electrochemical impedance measurements and potential corrosion of the metallic substrate for variable times were performed.

    Se han depositado recubrimientos transparentes e incoloros de sílice sobre sustratos anodizados y no anodizados de aleaciones de base aluminio (serie 6063. Los recubrimientos se prepararon por sol-gel (inmersión-extracción a partir de un alcóxido de silicio y de una mezcla de alcóxido y alquilalcóxido de silicio. La optimización de las fonnulaciones se basó en medidas de viscosidad, densidad, tensión superficial y ángulo de contacto. La densificación se llevó a cabo a 60 y 120 °C. La atenuación de la reflectancia luminosa de las muestras recubiertas se analizó por espectroscopia UV-VIS-IRP. Los resultados indicaron que se alcanza casi un 10 % de atenuación. Los ensayos de durabilidad y resistencia a la degradación del sistema metal/recubrimiento se realizaron por inmersión en disoluciones acuosas, aplicando medidas de impedancia electroquímica y del potencial de corrosión del sustrato metálico, para tiempos variables.

  18. Comportamiento a fatiga de uniones soldadas GMAW de la aleación de aluminio AA 7020

    Directory of Open Access Journals (Sweden)

    Bloem, C. A.

    2007-04-01

    Full Text Available The aim of this investigation is to evaluate the influence on the fatigue behavior by the finishing of the bulge in a welded aluminium-zinc-magnesium alloy AA7020. It was determined
    that total or partial elimination of the bulge has very little influence on its behavior, giving a very similar result on both cases, where one is better than the other by only 3%.

    El objetivo de la presente investigación es evaluar la influencia del acabado del sobrecordón en la respuesta a fatiga de las uniones soldadas realizadas sobre una aleación Al-ZnMg AA7020. Se determinó que la eliminación total o parcial del sobrecordón ejerce poca influencia en su comportamiento, obteniéndose en ambos casos una respuesta similar, donde la mejora de uno respecto del otro no es superior al 3%.

  19. Recristalización de bandas de aluminio procedentes de colada continua, laminadas en frío

    Directory of Open Access Journals (Sweden)

    Pérez-Ilzarbe Uriz, Javier

    2000-12-01

    Full Text Available This paper revises the literature on the problems in recrystallization of cold rolled cast strips. The phenomenon of the precipitation previous or simultaneous to recrystallization, that may affect the nucleation of the recrystallization, is explained. The use of TTT (Time, Temperature, Transformation curves to obtain the critical time and temperature without cutting the nose of the precipitation zone are examined for Al-Mn alloys it is also explained the obtainment of CTT (Concentration, Time, Temperature curves and "grain size diagrams" on the basis of heating rate and Mn in solid solution obtainment.

    Este artículo revisa la bibliografía existente sobre los problemas que la banda de colada continua, laminada en frío, presenta en su recristalización. Se examinan los impedimentos que presenta la precipitación de elementos de aleación o impurezas, previa o simultánea a la recristalización, para la nucleación de la recristalización y por tanto para ésta. Se explica el uso de las curvas TTT (Temperatura, Tiempo, Transformación para la determinación de temperatura y velocidad de calentamiento críticas para llegar a la recristalización sin pasar por la zona de precipitación. Se explica también la obtención de curvas CTT (Concentración, Tiempo, Transformación y "diagramas de tamaño de grano" para aleaciones Al-Mn en función de la velocidad de calentamiento y contenido de manganeso en solución sólida.

  20. Influencia de las mezclas de gases Ar-He y Ar-He-O2 en la soldabilidad de la aleación de aluminio AA5083-O usando Proceso GMAW-P automatizado

    Directory of Open Access Journals (Sweden)

    Enrique Esteban Niebles Nuñez

    2014-09-01

    Full Text Available La problemática en las empresas fabricantes de estructuras y construcciones soldadas en aluminio se centra en la disminución de las propiedades mecánicas de las uniones soldadas influenciada por el aporte térmico en las regiones de soldadura; así como, en los efectos de las discontinuidades y defectos, los altos costos de reparación de soldaduras y la baja productividad. El objetivo de este trabajo es evaluar la influencia de las mezclas de gases 80Ar20He (MG1, 60Ar40He (MG2, 80Ar19He1O2 (MG3, 60Ar39He1O2 (MG4, sobre la soldabilidad de la aleación de aluminio AA5083-O utilizando un material de aporte ER5183 y el proceso GMAW-P automatizado. La metodología incluyó una fase de parametrización de soldaduras, la caracterización del metal base y las regiones de soldadura. El análisis de resultados se llevó a cabo en términos de la evolución microestructural en las regiones de soldadura y evaluación de las propiedades como dureza, resistencia y elongación, así como la evaluación de discontinuidades y defectos de la unión, costos y velocidad de soldadura. Los resultados muestran que las mezclas de gas que contienen O2 favorecen significativamente la soldabilidad de la aleación en estudio.

  1. MICROSTRUCTURAL ANALYSIS OF Al-Mg-Si-Zn ALLOY

    Directory of Open Access Journals (Sweden)

    SERGIO VALADEZ

    2010-01-01

    Full Text Available En un esfuerzo por desarrollar una nueva aleación con aplicación estructural, se ha desarrollado una aleación base Aluminio aleada con magnesio, silicio y zinc. La investigación pretende correlacionar la microestructura y con el tratamiento térmico. La aleación AlMgSiZn, fue elegida para ese propósito debido a la presencia de precipitados tanto en la matriz del aAl, como en los límites de grano, los cuales permiten una excelente relación entre la dureza y la resistencia mecánica. En lo que respecta a la microestructura, esta fue caracterizada bajo condición de colada y después de ser tratada térmicamente por envejecimiento. Este tratamiento fue realizado en dos etapas, la primera a 450ºC durante 3 horas que corresponde al tratamiento de homogeneización: y la segunda al proceso de envejecimiento artificial llevado a cabo a 160ºC durante 1hr. Los resultados indican la presencia de dendritas de aAl, además un eutéctico binario y partículas de Mg7Zn3 adentro de las regiones interdendríticas. El eutéctico y las partículas fueron modificados por el tratamiento de envejecido. Las observaciones realizadas con el microscopio electrónico de transmisión en especímenes con y sin tratamientos térmicos, demostraron una distribución uniforme de precipitados con diversas morfologías, tales como cúbico, esférico y plaqueta: para la matriz de aAl, los cuales no fueron detectados durante las observaciones en el microscopio electrónico de barrido.

  2. Análisis estadístico de los registros de ruido electroquímico obtenidos en la corrosión del aluminio

    Directory of Open Access Journals (Sweden)

    Sánchez, A.

    2005-10-01

    , los cuales pueden reflejar cambios en el mecanismo de corrosión. Sobre todos estos parámetros destaca el uso de la resistencia de ruido. En este trabajo se ha llevado a cabo el tratamiento estadístico de los datos de ENM obtenidos cuando el aluminio es sometido a la acción a tres electrolitos diferentes, que provocan tres tipos distintos de corrosión: el agua destilada (pasividad, una disolución de cloruro de sodio (corrosión por picaduras y una disolución de hidróxido de sodio (corrosión generalizada o uniforme.

  3. Efecto de las heterogeneidades superficiales de las aleaciones de aluminio sobre el crecimiento y propiedades de las capas anódicas

    Directory of Open Access Journals (Sweden)

    Bartolomé, M. J.

    2007-08-01

    Full Text Available In the present work, X-ray photoelectron spectroscopy (XPS is used to study sealed and unsealed anodic coatings obtained on pure-Al and on Al-Cu, Al-Mg-Si and Al-Mg alloys. In general, the sealing process is seen to produce a significant increase in the O/Al ratio in the anodic coatings. This increase is more considerable with the Al-Cu and Al-Mg alloys than with the pure Al and the Al-Mg-Si alloy, perhaps due to the greater porosity of the coatings obtained on the former. An attempt is made to establish possible relationships between anodic film characteristics and surface heterogeneities, which also act in the phase prior to anodising. According to the results of this work, these heterogeneities affect the degree of dissolution of the metallic substrate during the anodising operation.

    En el presente trabajo se estudian, mediante el análisis XPS (espectroscopia fotoelectrónica de rayos-X, los recubrimientos de anodizado, sellados y sin sellar, obtenidos sobre Al-puro y aleaciones de Al-Cu, Al-Mg-Si y Al-Mg. En general, se observa un aumento significativo en las relaciones O/Al en el recubrimiento como resultado del proceso de sellado. En el caso de las aleaciones de Al-Cu y Al-Mg, se ha observado también un significativo aumento de la relación O/Al respecto al Al-puro y la aleación Al-Mg-Si, que puede estar asociado a una mayor porosidad de los recubrimientos obtenidos sobre las primeras. Se ha intentado así mismo establecer posibles relaciones entre las características de las capas anódicas y las heterogeneidades superficiales que también han actuado en la fase previa al anodizado. Según los resultados de este trabajo, estas mismas heterogeneidades afectan el grado de disolución del substrato metálico durante la operación de anodizado.

  4. Prediction of hardness of the Zn-Al-Cu alloys of agreement by composition in weight; Prediccion de la dureza de la aleacion Zn-Al-Cu de acuerdo a su composicion en peso

    Energy Technology Data Exchange (ETDEWEB)

    Villegas-Cardenas, Jose David; Camarillo-Villegas, Alejandra; Juanico-Loran, Antonio [Universidad Politecnica del Valle de Mexico, Tultitlan, Estado de Mexico (Mexico)]. E-mails: jdvc76@yahoo.com.mx; v_c_a_77@hotmail.com; ajuanico@yahoo.com.mx; Espinosa-Rojas, Raul [Universidad Autonoma Metropolitana, Unidad Azcapotzalco (Mexico)]. E-mail: rer21@hotmail.com; Camacho-Olguin, Carlos [Universidad Politecnica del Valle de Mexico, Tultitlan, Estado de Mexico (Mexico)]. E-mail: ccamacho@upvm.edu.mx

    2013-07-15

    Ten alloys Zn-Al-Cu were developed in two parts, in agreement to two zones presented in the isopleth diagrams (Villas et al., 1995). The percentage of Cu and Al was systematically varied. Subsequently, hardness measurements were performed. These measurements allowed establishing two equations that predict the hardness with an error lower than 5%. With these equations, it is possible to obtain alloys that replace Al base alloys by a Zn base alloy, having the same hardness. This implicates also the elimination of the volumetric change in the presence of e phase. [Spanish] Se desarrollaron diez aleaciones Zn-Al-Cu divididas en dos partes, de acuerdo a dos zonas presentadas en los diagramas isopleticos de Hans (Villas et al., 1995). Se incremento el porcentaje de Cu y Al paulatinamente. Posteriormente se desarrollaron pruebas de macrodureza y de ese analisis se obtuvieron dos ecuaciones que permiten pronosticar y disenar aleaciones de una dureza determinada de acuerdo a su porcentaje en peso de cada elemento, con un error menor que 5%. Como se demuestra en este trabajo, con estas ecuaciones es posible desarrollar aleaciones sustitutas base aluminio por una aleacion base zinc o viceversa, teniendo la misma dureza para cada tipo de aleacion y eliminando el problema del cambio volumetrico debido a la presencia de la fase e.

  5. Preparación y propiedades de una arcilla montmorillonita pilareada con polihidroxicationes de aluminio Preparation and properties of a montmorillonite clay pillared with aluminium polyhydroxications

    Directory of Open Access Journals (Sweden)

    Sibele B. C. Pergher

    1999-09-01

    Full Text Available Montmorillonite clay from Brazil was pillared with aluminium polyhydroxications. The influence of Al/Mont ratio and calcination temperature in the properties of the prepared materials was studied. Results showed that the pillarization process increases the basal spaces of the natural clay from 9,7 to 18,5Å and the superficial area from 41 to ~230m2/g. The calcination process at different temperatures showed that the pillared material was stable until 600oC but the adequate temperature for calcination was 450oC. Materials prepared with different Al/Mont ratios showed the maximum Al incorporation for ratios >10meq Al/g and a good distribution for rations >15meq Al/g.

  6. ALS - resources

    Science.gov (United States)

    Resources - ALS ... The following organizations are good resources for information on amyotrophic lateral sclerosis : Muscular Dystrophy Association -- mda.org/disease/amyotrophic-lateral-sclerosis National Amyotrophic Lateral Sclerosis (ALS) Registry -- ...

  7. Caracterización mecánica de recubrimientos de aluminio por CVD-FBR sobre aceros inoxidables y resistencia a la oxidación en vapor de agua

    Directory of Open Access Journals (Sweden)

    Diego Pérez-Muñoz

    2015-09-01

    Full Text Available Los recubrimientos de aluminio depositados sobre el acero inoxidable austenítico AISI 317 por Deposición Química de Vapor en Lecho Fluidizado (CVD-FBR presentan a altas temperaturas una reducción de la velocidad de corrosión de más de 80 veces. Se realizó la caracterización mecánica de los recubrimientos por medio de microdureza, nanoindentación, para conocer cómo se vieron afectas las propiedades mecánicas (en especial la dureza y el módulo de Young del recubrimiento y del sustrato luego de ser sometidos a la oxidación a alta temperatura. También se hicieron análisis por medio de Microscopia Electrónica de Barrido (MEB, para observar los cambios microestructurales, y de Microscopia de Fuerza Atómica (MFA, para observar cómo varía la topografía y el gradiente de rugosidad en función de la distancia recorrida por la punta del cantiléver durante los barridos.

  8. DESHIDROGENACIÓN OXIDATIVA DE PROPANO POR FOSFATOS DE TIERRAS RARAS SOPORTADOS SOBRE PILC-AL

    Directory of Open Access Journals (Sweden)

    Carolina De Los Santos

    2012-01-01

    Full Text Available Se presenta la actividad catalítica en la deshidrogenación oxidativa de propano de diferentes fosfatos de tierra rara LnPO 4 (donde Ln = La, Ce, Pr, Nd, Sm y de los mismos soportados sobre una arcilla pilareada con aluminio de alta superficie específica. Los sólidos fueron caracterizados por ATG, DR X, adsorción de nitrógeno y análisis inmediato post reacción para determinar la eventual formación de carbón superficial. Los ensayos catalíticos usando como mezcla de reacción C 3 H 8 /O 2 /Ar = 10/10/80 se hicieron a temperaturas entre 400ºC y 600ºC. Todos los catalizadores fuer on activos. Los principales productos de reacción fueron: H 2 , CO, CO 2 , CH 4 , C 2 H 4 y C 3 H 6 , no detectándose compuestos orgánicos oxigenados. Aunque todos los sistemas investigados fueron activos, los catalizadores soportados sobre PILC-Al presentaron una actividad mayor que los másicos, siendo el mayor efecto para el samario en que el rendimiento a 600oC aumenta del 4% al 10%. Este efecto fue atribuido al incremento en el área superficial específica.

  9. Comportamiento a la corrosión electroquímica de aleaciones MgAl con recubrimientos de materiales compuestos Al/SiCp mediante proyección térmica

    Directory of Open Access Journals (Sweden)

    Pardo, A.

    2010-04-01

    Full Text Available The corrosion protection of Mg-Al alloys by flame thermal spraying of Al/SiCp composite coatings was evaluated by electrochemical impedance spectroscopy in 3.5 wt.% NaCl solution. The volume fraction of SiC particles (SiCp varied between 5 and 30%. The as-sprayed Al/SiCp composite coatings revealed a high number of micro-channels, largely in the vicinity of the SiC particles, that facilitated the penetration of the electrolyte and the subsequent galvanic corrosion of the magnesium substrates. The application of a cold-pressing post-treatment reduced the degree of porosity of the coatings and improved the bonding at the coating/substrate and Al/SiC interfaces. This resulted in improved corrosion resistance of the coated specimens. The effectiveness of the coatings slightly decreased with the addition of 5-30 vol.% SiCp compared with the unreinforced thermal spray aluminium coatings.

    Se estudia, mediante espectroscopía de impedancia electroquímica en solución 3,5 % NaCl, la protección frente a la corrosión de aleaciones Mg-Al recubiertas por proyección térmica con materiales compuestos Al/SiCp. Se varió la fracción de volumen de las partículas de SiC (SiCp entre 5 y 30 %. Los recubrimientos efectuados por proyección térmica revelan un elevado número de microcanales, en la vecindad de las partículas de SiC, que facilitan la penetración del electrolito originando procesos de corrosión galvánica en los substratos de las aleaciones de magnesio. Un tratamiento posterior mediante la aplicación de una presión en frío reduce el grado de porosidad de los recubrimientos y mejora la unión, tanto entre el substrato y el recubrimiento como entre las partículas de aluminio y SiC, mejorando la resistencia a la corrosión de las aleaciones recubiertas. La efectividad de los recubrimientos disminuye ligeramente con la adición de SiCp cuando se comparan con los mismos recubrimientos de aluminio sin refuerzo.

  10. Recent developments of the aluminium-lithium system alloys for aircraft uses; Recentes desenvolvimentos das ligas do sistema aluminio-litio para fins aeronauticos

    Energy Technology Data Exchange (ETDEWEB)

    Goncalves, Marcelo; Plaut, Ronald Lesley

    1992-12-31

    A brief review is made of the latest developments in the production of Aluminium-Lithium alloys. The necessity for new materials in the field of aeronautics has speeded up research on metallic and non-metallic materials. Lately, a good part of the research in the field of metallic components has been directed at Al-Li alloys. More recently, with the development of quaternary alloys Al-Li-X-X, the old problem of low toughness was overcome. The finality of this study is to cover the developments of the mentioned alloys, including the fundamentals of physical metallurgy of the complex system recently developed Al-Li-Cu-Mg. (author) 27 refs., 2 figs., 4 tabs.

  11. Modificación de estrés sintéticos mediante la adición de líquidos iónicos próticos para la lubricación del contacto aluminio-acero

    OpenAIRE

    Soto García, Damián

    2013-01-01

    Las conclusiones que podemos obtener del presente proyecto son las que se expresan a continuación:  Se han utilizado y caracterizado nuevos líquidos iónicos próticos como aditivos del poliéster sintético propilenglicol dioleato, que se emplea en la lubricación de aleaciones de aluminio.  Se ha estudiado la miscibilidad de los aditivos a l 1% en peso en el aceite base PGDO. Se comprueba que los aditivos más solubles son los Lis próticos de cadena larga (MO, DO y DPa). En cambio, ...

  12. Influencia del contenido de Mg,Cu y Ni en la estructura y propiedades mecánicas de las aleaciones Al-7Si fundidas. // Mg,Cu and Nickel content influence in the structure and mechanical properties of Al-7Si casting alloys.

    Directory of Open Access Journals (Sweden)

    V. Lavaert

    2003-05-01

    Full Text Available El diseño de aleaciones de aluminio de alta calidad involucra la selección adecuada de los elementos de aleación y lacorrecta aplicación del tratamiento térmico, con la desventaja del necesario aumento del tiempo del proceso. En el presentetrabajo se analiza la influencia de la adición de diferentes elementos de aleación sobre la estructura y propiedadesmecánicas de la aleación base Al7SiMg (A356. Las propiedades fueron analizadas para la aleación en estado fundido,después de la modificación y con tratamiento térmico con el fin de evaluar la posibilidad de eliminar el tratamientoposterior mediante una correcta selección de los elementos de adición.Palabras claves: Aleaciones de aluminio, elementos de aleación, diseño de aleación, fundición, propiedadesmecánicas, tratamiento térmico.______________________________________________________________________________Abstract.The design of high quality aluminum alloys involves the appropriate selection of the alloy elements and the correct application of thethermal treatment, with the disadvantage of the necessary increase of time process. Presently work analyzed the influence of theaddition of different alloy elements on the structure and mechanical properties of the alloy Al7SiMg bases (A356. The properties wereanalyzed for the alloy in fused state after modification and with thermal treatment with the purpose of evaluating the possibility toeliminate the later treatment by means of a correct selection of the addition elements.Key words. Aluminum alloys, alloy design, mechanical properties, casting, thermal treatment.

  13. Modelización del perfil de soldadura y de la cavidad de vapor en la aleación de aluminio 5182 soldada con láser

    Directory of Open Access Journals (Sweden)

    Pastor, M.

    2001-12-01

    Full Text Available The purpose of this research is the study of the laser welding process of the aluminum alloy 5182 and the development of models by means of the COSMOS/M package, in order to predict the shape of the keyhole and the temperatures profile of the weld. Modeling has been done considering the degree of defocusing. The heat flow applied on the models was a Gauss flow, considering the condition of the focused face and the conditions of negative and positive defocusing. The validity of the models has been demonstrated comparing their results with those obtained by experimental tests. The extent of defocusing of laser beam affected the stability of the keyhole and welding geometry.

    El presente trabajo se introduce en el desarrollo de modelos para predecir la forma de la cavidad de vapor y el perfil de la aleación de aluminio 5182 con soldadura láser. Para el procesamiento del modelo se ha empleado el paquete profesional de Elementos Finitos COSMOS/M. La modelización de la soldadura se realizó considerando como variable el grado de desenfoque del haz de láser y la distribución del flujo de calor según un modelo Gaussiano, para las condiciones de haz enfocado y de desenfoque negativo y positivo. La validez de los resultados obtenidos se comprobó mediante la comparación con los resultados obtenidos en pruebas experimentales, concluyéndose que el grado de desenfoque del haz del láser afecta notablemente la estabilidad de la cavidad de vapor y la geometría de la soldadura.

  14. Comportamiento del acabado superficial de la pieza y el desgaste de la herramienta al fresar aluminio con altas velocidades de corte en fresadoras cnc convencionales. // Superficial finish behavior and tool wear in aluminium milling with high cutting spee

    Directory of Open Access Journals (Sweden)

    F. Martínez Aneiro

    2006-05-01

    Full Text Available La demanda de componentes mecánicos de alta calidad y gran exactitud para sistemas de elevado desempeño estaaumentando considerablemente en los últimos años a nivel mundial. Este hecho ha provocado el desarrollo de nuevastecnologías aplicadas a los procesos de corte.El desarrollo integral de las máquinas herramientas (controles, husillos de alta velocidad de las herramientas de corte(nuevos materiales para los substratos y capas y de la tecnología de maquinado posibilitó la aplicación del corte con altasvelocidades de corte (High speed Cutting HSC. El aumento de las velocidades de corte es una de las formas de aumentar laeficiencia de los procesos productivos a través de la reducción de los tiempos de fabricación. La reducción en varias vecesde los tiempos de fabricación, se logra no solo por los tiempos de maquinado sino también por la sustitución o minimizarotros procesos de elaboración que forman parte de la cadena productiva, los cuales en ocasiones son relativamente lentoscomo son la electroerosión, el acabado manual en la producción de moldes y troqueles así como los cambios deoperaciones de la pieza.Por ser un proceso relativamente nuevo, introduciéndose a partir de la década de los años 90 aun existen muchas cuestionestecnológicas que están sin respuesta. Es interés del presente trabajo, mostrar los efectos de las altas velocidades de cortesobre la vida útil de la herramienta y el acabado superficial en la pieza, trabajando en máquinas fresadoras de CNC¨convencionales¨. Los resultados muestran que dentro de los parámetros estudiados la durabilidad de la herramienta y elacabado superficial mejoran y que el comportamiento de la máquina es estable a pesar de no estar concebida para el nuevoconcepto de altas velocidades.Palabras Claves: Altas velocidades de corte, HSC, HSM desgaste, acabado superficial.______________________________________________________________________________Abstract.The demand of mechanical components of high quality and great accuracy for systems of high performance isincreasing considerably in the last years at world level. This fact has caused the development of new appliedtechnologies in cutting processes.The development of machine tools (control, high-speed spindle, the cutting tools (new materials, substrata and layers andthe technology of machining, facilitated the application of cut with high cutting speed (High speed Cutting HSC. Theincrease of cutting speeds increases the efficiency of the productive processes through the reduction of the manufacturingtimes. The reduction in several times of the manufacturing process, is not achieved alone for the time of machining but alsofor the substitution of other elaboration processes that are part of the productive chain that are relatively slow in occasionsas the electroerosion (spark erosion, the manual finishing in molds and dies production as well as the changes of spareoperations. Being a relatively new process introduced starting from the decade of the 90’s; many technological questionsare still without answer. This paper presents the benefit of the high cutting speeds HSC on the tool useful life and thesuperficial finishing in spares, working in conventional milling machines of CNC. The results stated, that within the studiedparameters, that the durability of the tool and the surface roughness improve and that the behavior of the machine is stablein spite of not being conceived for high speeds.Keywords: High speed cutting, HSC, HSM, Wear, surface roughness.

  15. Recrystallization behaviour of cold rolled aluminium from cast strips; Recristalizacion de bandas de aluminio procedentes de colada continua, laminadas en frio

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Ilzarbe, J.; Faustmann Salas, J.; Suarez Sandra, A.

    2000-07-01

    This paper revises the literature on the problems in recrystallization of cold rolled cast strips. The phenomenon of the precipitation previous or simultaneous to recrystallization, that may affect the nucleation of the recrystallization, is explained. The use of TTT (Time, Temperature, Transformation) curves to obtain the critical time and temperature without cutting the nose of the precipitation zone are examined For Al-Mn alloys it is also explained the obtainment of CTT (Concentration, Time, Temperature) curves and grain size diagrams on the basis of heating rate and Mn in solid solution obtainment. (Author) 47 refs.

  16. SÍNTESIS DE CATALIZADORES DE Ni/ZnO/Al2O3 PARA LA REACCIÓN WGS A TRAVÉS DEL ESTUDIO DE LAS PROPIEDADES ESTRUCTURALES Y CATALÍTICAS DE Ni/ZnO Y Ni/Al2O3

    Directory of Open Access Journals (Sweden)

    Edgardo Meza Fuentes

    2011-08-01

    Full Text Available El uso del hidrógeno para la generaciónde energía ha renovado el interés por lareacción WGS. Los catalizadores usadospara acelerar esta reacción requieren condicionesespeciales de reducción, lo quedificulta su aplicación en celdas combustiblespara la producción de energía. Eneste trabajo se sintetizaron catalizadoresde níquel soportado en óxido de cinc oaluminio usando un diseño factorial 32 enel caso de los materiales con cinc. Los resultadosobtenidos se emplearon en la síntesisde sólidos trimetálicos de níquel,cinc y aluminio en las condiciones máspropicias para garantizar mejor actividady selectividad. Los sólidos fueron caracterizadospor EDX, DRX, TPR y evaluadosen la reacción WGS a 260 °C. Se observóla incorporación de los cationesZn2+ y Al3+ en la red del NiO, lo que disminuyesu reducibilidad con hidrógeno.Los materiales que contenían cinc fueron100% selectivos para la reacción WGS.En la evaluación de los catalizadores conníquel y aluminio hubo formación de metano;sin embargo, este compuesto no fueobservado durante la evaluación catalíticade los sólidos trimetálicos. Los catalizadoresmás activos fueron aquellos calcinadosen temperaturas más bajas y conlas menores cantidades de cinc.: hidrógeno, níquel

  17. Direct reading spectrochemical determination of aluminium, iron and silicon in fluorite; Determinacion espectroquimica de lectura directa de aluminio, hierro y silicio en fluorita

    Energy Technology Data Exchange (ETDEWEB)

    Roca, M.

    1966-07-01

    A quantitative spectrochemical method for the determination of Al, Fe and Si in fluorite has been worked out. The sample was supported in a graphite electrode with crater of 5 mm. in diameter, 2,5 mm deep, and burned by a d.c. are in a direct reading spectrometer. The excitation of samples has been studied without dilution as well as using graphite powder as diluent in the ratios 1:1, 1:4, and 1:9; the latter factor was chosen. Ag, Ca, Co, Cr, Mo and Sn were tested as internal standards. It has not been found any significant inter element effect. It is necessary to use natural fluorite as base material for the standards. (Author) 5 refs.

  18. Estudio del comportamiento a la corrosión por picadura de materiales compuestos de matriz de aluminio (A3xx.x/SiCp

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    Pardo, A.

    2004-10-01

    Full Text Available The influence of the SiCp proportion on the pitting corrosion of A3xx.x/SiC/xxp composites was studied by means of potenciodinamic polarization and double cyclic polarization in saline environment at 25 °C. A360/SiC/xxp matrix does not contain copper, whereas the A380/SiC/xxp matrix contains l,39'l,44w %Ni and 3,13-3,45wt %Cu. The kinetic study was carried out by gravimetric measurements. The nature of corrosion products was analysed by low angle XRD and Scanning Electron Microscopy (SEM. The corrosion is due to nucleation and growth of Al2O3·3H2O on the material surface. The corrosion increases with the reinforcement proportion, chloride concentration and copper content.

    Se estudia la influencia de la proporción de SiCp, en la resistencia a la corrosión por picadura, de composites A3xx.x/SiC/xxp, mediante medidas de polarización potencio^ dinámica y de doble polarización cíclica cuando operan en ambiente salino a 25 °C. La matriz del material A360/SiC/xxp no contiene cobre, mientras que el material A380/SiC/xxp contiene 1,394,44 % Ni y 3,13-3,45 % Cu. El estudio cinético se realizó mediante medidas gravimétricas. La naturaleza de los productos de corrosión se estudió por difracción de rayos X de incidencia rasante y microscopía electrónica de barrido. La degradación está asociada a la nucleación y crecimiento de Al2O3·3H2O sobre la superficie de los materiales y aumenta con la proporción de refuerzo, la concentración de iones cloruro del medio y la concentración de cobre del material.

  19. Hydrogen-induced changes in the crystalline structure and mechanical properties of a Zn-Al eutectoid alloy rapidly solidified

    Energy Technology Data Exchange (ETDEWEB)

    Sandoval Jimenez, Alberto; Iturbe Garcia, Jose Luis [Instituto Nacional de Investigaciones Nucleares, Ocoyoacac, Estado de Mexico (Mexico)]. E-mail: alberto.sandoval@inin.gob.mx; asandovalj@correo.unam.mx; Negrete Sanchez, Jesus [Universidad Autonoma de San Luis Potosi, San Luis Potosi (Mexico); Torres Villasenor, Gabriel [Instituto de Investigaciones en Materiales, UNAM, Mexico D.F. (Mexico)

    2009-09-15

    Ribbon fractions of a zinc-aluminum eutectoid (Zn40.8Al%at.) alloy, obtained by rapid solidification using melt spinning technique, were submitted to a thermo-hydrogenation process by periods of 1, 6, 18, 24, 30, and 48 hours, to 200 degrees Celsius and 20 atmospheres. Thermo-hydrogenated samples were analyzed by transmission electron microscopy (TEM). Hydrogen-induced changes were produced, such as microstructure refining, development of crystalline defects, microhardness changes and modification of stable crystalline structures to {alpha}R meta-stable phase at room temperature. [Spanish] Fracciones de tiras de una aleacion eutectoide de zinc-aluminio (Zn40.8Al%at.), obtenidas mediante solidificacion rapida usando la tecnica de melt spinning, se sometieron a un proceso de termohidrogenacion por periodos de 1, 6, 18, 24, 30 y 48 horas, a 200 grados centigrados y 20 atmosferas. Las muestras termohidrogenadas se analizaron por microscopia electronica de transmision (MET). Se produjeron cambios inducidos por hidrogeno, tales como la refinacion de la microestructura, el desarrollo de defectos cristalinos, cambios de microdureza y modificacion de las estructuras cristalinas estables a fase metaestable {alpha}R a temperatura ambiente.

  20. AL Amyloidosis

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    Desport Estelle

    2012-08-01

    Full Text Available Abstract Definition of the disease AL amyloidosis results from extra-cellular deposition of fibril-forming monoclonal immunoglobulin (Ig light chains (LC (most commonly of lambda isotype usually secreted by a small plasma cell clone. Most patients have evidence of isolated monoclonal gammopathy or smoldering myeloma, and the occurrence of AL amyloidosis in patients with symptomatic multiple myeloma or other B-cell lymphoproliferative disorders is unusual. The key event in the development of AL amyloidosis is the change in the secondary or tertiary structure of an abnormal monoclonal LC, which results in instable conformation. This conformational change is responsible for abnormal folding of the LC, rich in β leaves, which assemble into monomers that stack together to form amyloid fibrils. Epidemiology AL amyloidosis is the most common type of systemic amyloidois in developed countries with an estimated incidence of 9 cases/million inhabitant/year. The average age of diagnosed patients is 65 years and less than 10% of patients are under 50. Clinical description The clinical presentation is protean, because of the wide number of tissues or organs that may be affected. The most common presenting symptoms are asthenia and dyspnoea, which are poorly specific and may account for delayed diagnosis. Renal manifestations are the most frequent, affecting two thirds of patients at presentation. They are characterized by heavy proteinuria, with nephrotic syndrome and impaired renal function in half of the patients. Heart involvement, which is present at diagnosis in more than 50% of patients, leading to restrictive cardiopathy, is the most serious complication and engages prognosis. Diagnostic methods The diagnosis relies on pathological examination of an involved site showing Congo red-positive amyloid deposits, with typical apple-green birefringence under polarized light, that stain positive with an anti-LC antibody by immunohistochemistry and

  1. Modelación del perfil de soldadura y de la cavidad de vapor en la aleación de aluminio 5182 soldada con láser. // Welding profile and steam cavity modelation in aluminum 5182 alloy welded with laser.

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    M. Pastor

    2002-09-01

    Full Text Available El presente trabajo incursiona en el desarrollo de modelos para predecir la forma de la cavidad de vapor y el perfil de laaleación de aluminio 5182 con soldadura láser, para lo cual ha sido empleado el paquete profesional de elementos finitosCOSMOS/M. La modelación de la soldadura ha sido realizada considerando como variable el grado de desenfoque del hazde láser, considerando el flujo de calor según un modelo Gaussiano, con un coeficiente de absorción de 0.24 para lacondición de haz enfocado y 0.16 para las condiciones de desenfoque negativo y positivo. La validez de los resultadosobtenidos se comprobó mediante los resultados obtenidos en pruebas experimentales.Palabras claves: Aleaciones de aluminio, láser de Nd:YAG._______________________________________________________________________AbstractThe purpose of this research is the study of laser welding process for the 5182 aluminum alloys and the development ofmodels by means of the COSMOS/M package, in order to predict the shape of the steam cavity and the weldingtemperatures profile. Modeling has been done considering the degree of defocusing. The heat flow applied on the modelswas a Gauss flow, with a coefficient of absorption of 0.24 for the condition of the focused face and 0.16 for the conditionsof negative and positive defocusing. The validity of the models has been demonstrated comparing their results with thoseobtained by experimental tests.Key words: Aluminum alloys, Nd: YAG laser.

  2. Metalografía a color en aleaciones Al-Si comerciales. Optimización de las técnicas de caracterización microestructural mediante microscopía óptica de reflexión

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    Vander-Voort, G. F.

    2010-10-01

    Full Text Available The present demand on alloy production with improved quality requires the optimization of the metallographic procedures used on its characterization. Traditional etching techniques commonly employed for phase identification by optical metallography in aluminium alloys are not always suitable for a detailed analysis of existing phases, nor to accurately predict the mechanisms that govern the solidification process in certain detail. This work explores the potential of colour metallography to reveal at its best as-cast microstructures in Al-Si 12 alloys. For this purpose a colour etching technique, specifically developed for aluminium alloys and based on the Weck reagent. The application of such etchant has allowed the qualitative characterization of the microstructure. And it has also shown the advantages of colour metallography over black and white (B&W etching techniques.La demanda de aleaciones con calidades optimizadas conlleva la mejora continua de estas calidades, lo que viene suscitando la necesidad de mejora y optimización permanentes de las técnicas de caracterización metalográfica. Las técnicas de ataque tradicionales, utilizadas en la observación microscópica de las aleaciones de aluminio, no permiten un análisis detallado de la evolución microestructural de las fases presentes ni de parte de los mecanismos que rigen la solidificación. En el presente trabajo, se explora el potencial de la metalografía en color aplicada a las estructuras de solidificación de aleaciones Al-Si 12. Se ha utilizado un procedimiento de ataque en color, basado en un reactivo desarrollado porWeck para aleaciones de aluminio. El empleo de esta técnica ha permitido la evaluación cualitativa de la microestructura. La técnica ha permitido revelar características microestructurales que los métodos de ataque en blanco-negro no revelan.

  3. Characterization of alumina obtained from the synthesis of gelatinous precipitates of aluminum hydroxide obtained from the reaction of aluminum sulfate and ammonium hydroxide in different temperatures; Caracterizacao de aluminas obtidas a partir da sintese de precipitados gelatinosos de hidroxido de aluminio obtidos pela reacao de sulfato de aluminio e hidroxido de amonio em diferentes temperaturas

    Energy Technology Data Exchange (ETDEWEB)

    Mercury, Jose Manuel Rivas [Centro Federal de Educacao Tecnologica do Maranhao (CEFET), Sao Luiz, MA (Brazil); Freitas Neves, R. de [Para Univ., Belem, Pa (Brazil). Dept. de Engenharia Quimica

    1996-07-01

    Aluminum hydroxide was obtained by synthesis through neutralization of solutions aluminum sulphate solutions with ammonium hydroxide at different level of temperatures of synthesis (30, 60, 90 deg C) on the molar [OH]/[Al{sup +3}] of 6,5. All products was burned at 950 deg C during two hours of dried aluminum hydroxide powder. Alumina obtained and A-16SG, APC-2011, produced by Alcoa Co. was characterized by Bulk Density, Tap density, Real Density, Particle Size Distribution, X-Ray Diffractions and Chemical Analysis and both compared. (author) 11 refs., 3 figs., 3 tabs.

  4. Comportamiento a tracción a temperaturas ambiente y elevadas de nuevos composites basados en aleaciones hipereutécticas de Al-Si

    Directory of Open Access Journals (Sweden)

    Valer, J.

    1997-02-01

    Full Text Available This work shows the improvement obtained on tensile stress at room and high temperatures of hypereutectic Al-Si alloys. These alloys are produced by a combination of spray-forming, extrusión and thixoforming process, in comparison with conventional casting alloys. Al-25%Si-5%Cu, Al- 25%Si-5%Cu-2%Mg and Al-30%Si-5%Cu alloys have been studied relating their microstructural parameters with tensile stress obtained and comparing them with conventional Al-20%Si, Al-36%Si and Al-50%Si alloys. Al-25%Si-5%Cu alloy was tested before and after semi-solid forming, in order to distinguish the different behaviour of this alloy due to the different microstructure. The properties obtained with these alloys were also related to Al-SiC composites formed by similar processes.

    En este trabajo se muestra la mejora obtenida en la resistencia a la tracción a temperatura ambiente y a elevadas temperaturas de aleaciones hipereutécticas de Al-Si producidas por una combinación de un proceso de solidificación rápida y del conformado en estado semisólido, en comparación con aleaciones obtenidas por procedimientos convencionales de inyección en estado líquido. Se han estudiado las aleaciones Al-25%Si-5%Cu, Al-25%Si-5%Cu-2%Mg y Al-30%Si-5%Cu, relacionando sus parámetros microestructurales con las resistencias a tracción obtenidas, y se han comparado con las aleaciones binarias Al-20%Si, Al-36%Si y Al-50%Si. La aleación Al-25%Si-5%Cu se ha ensayado antes y después del conformado en estado semisólido, lo que ha permitido conocer la diferencia en el comportamiento de la aleación como consecuencia de la distinta microestructura. También se comparan las propiedades obtenidas en estas aleaciones con las que presentan composites de aleaciones de aluminio reforzados con partículas de SiC y procesados por métodos similares.

  5. Description of hypoeutectic Al-Si-Cu alloys based on their known chemical compositions

    Directory of Open Access Journals (Sweden)

    Djurdjevic, M. B.

    2013-10-01

    interés durante las últimas décadas, y la cantidad de programas de simulación existentes en el mercado es un buen indicador del interés de la industria en este campo. La mayoría de los datos empleados en estos programas se basan en los diagramas de fase binarios, ternarios o incluso superiores. Desafortunadamente, excepto para los diagramas binarios, el ajuste de los datos no es lo suficiente bueno. Teniendo en cuenta que la mayoría de los sistemas binarios del aluminio están bien definidos se ha intentado convertir los sistemas multi-componentes en un pseudo binario sistema Al-Xi (en este caso el diagrama de fase Al-Si es el elegido como sistema de referencia. El nuevo algoritmo del Silicio Equivalente (SiEQ expresa la cantidad de los elementos de la aleación que son mayoritarios y minoritarios, a través de una cantidad “equivalente” de silicio. Este sistema puede emplearse para calcular varias características termo-físicas y de solidificación de sistemas multicomponentes, como las aleaciones de aluminio. Esto permite al modelo tener la capacidad de realizar predicciones de las características de la solidificación de las piezas fundidas, donde las velocidades de enfriamiento son bajas y las características del proceso de solidificación son bien conocidas, para evitar posibles problemas en la fundición. Este trabajo demuestra cómo el algoritmo del SiEQ puede ser empleado para el cálculo de las características de las temperaturas de solidificación de las aleaciones multi-componentes Al-Si, así como sus calores latentes y el factor de restricción del crecimiento del grano. El análisis estadístico de los resultados obtenidos en un amplio rango de composiciones químicas de la aleación, muestra una muy buena correlación entre los datos experimentales y los cálculos realizados con el SiEQ. La misma aproximación matemática podría ser aplicada para otros sistemas metálicos como el hierro y el magnesio, empleando el carbono equivalente en el

  6. Porous anodic film formation on an Al-3.5 wt % Cu alloy

    Directory of Open Access Journals (Sweden)

    Páez, M. A.

    2003-12-01

    Full Text Available The morphological development of porous anodic films in the initial stages is examined during anodizing an Al-3.5 wt % Cu alloy in phosphoric acid. Using transmission electron microscopy a sequence of ultramicrotomed anodic sections reveals the dynamic evolution of numerous features in the thickening film in the initial stages of anodizing. The morphological changes in the anodic oxide in the initial stages of its formation appears related to the formation of bubbles during film growth. From Rutherford backscattering spectroscopy (RBS analysis of the film, the formation of the bubbles is associated with the enrichment of copper in the alloy due to growth of the anodic oxide. On the other hand, during constant current anodizing of Al-Cu in phosphoric acid, the current efficiency is considerably less than that for anodizing superpure aluminium under similar conditions. From the contrasting results between the charge consumed calculated from RBS and the real charge consumed during anodizing, oxygen gas bubbles generation and copper oxidation seem to be of less importance on the low efficiency for film formation. It is apparent that the main cause of losing efficiency for film growth on Al-Cu is associated with generation of oxygen at residual second phase, with the development of stresses in the film and, the consequence of these effects on film cracking during film growth.

    En este trabajo se examinó el desarrollo morfológico de películas anódicas porosas en los estados iniciales de la anodización de una aleación de aluminio Al-3,5 % p/p Cu. La observación de una secuencia de secciones ultramicrotomadas del metal y su película anódica, por microscopía electrónica de transmisión, revela la evolución dinámica de numerosos detalles morfológicos durante los inicios del crecimiento de la película anódica. Los cambios morfológicos en el óxido anódico, en los inicios de su formación, aparecen relacionados a la formación de

  7. Deposición de películas de AlN como dispositivos semiconductores

    Directory of Open Access Journals (Sweden)

    Julio Cesar Caicedo

    2012-10-01

    Full Text Available Películas de AlN fueron depositados por la técnica de deposición por láser pulsado (PLD, utilizando un láser Nd: YAG con una longitud de onda de 1064 nm. Las películas fueron depositadas en una atmósfera de nitrógeno como gas de trabajo; como cátodo se usó aluminio de alta pureza (99,99%. Las películas fueron depositadas con una fluencia del láser de 2,28 J/cm2 durante 10 minutos sobre sustratos de silicio (100. La presión de trabajo fue de 9 x 10-3 mbar y la temperatura del sustrato se varió desde 200 °C a 630 °C. El espesor medido por perfilometría fue de 150 nm para todas las películas. Además se fabricaron los dispositivos de ondas acústicas de superficie (SAW con una configuración Mo/AlN/Si, empleando AlN-bufer y un canal de Mo. La morfología y la composición de las películas se estudiaron mediante microscopía electrónica de barrido (MEB y energía dispersiva de rayos X de análisis (EDX, respectivamente. Los espectros de reflectancia óptica y color de coordenadas de las películas se obtuvieron por la técnica óptica reflectometría espectral en el rango de 400-900 cm-1 por medio de un espectrofotómetro Ocean Optics 2000. En este trabajo se encontró una clara dependencia de las propiedades morfológicas, reflectancia, pureza dominante, longitud de onda del color, la respuesta de frecuencia y velocidad de la onda acústica en términos de la temperatura aplicada al sustrato. Se observó una reducción en la reflectancia de aproximadamente 30% y aumento de velocidad de la onda acústica de aproximadamente 1,3% cuando la temperatura se incrementó desde 200 °C a 630 °C.

  8. Corrosión de Aleaciones Aeronáuticas de Aluminio y sus Componentes Relacionada a la Expresión Proteica del Hongo Hormoconis resinae Corrosion of Aeronautical Aluminium Alloys and its Components Related to the Proteic Expression of the Fungus Hormoconis resinae

    Directory of Open Access Journals (Sweden)

    Raquel Araya

    2008-01-01

    Full Text Available Este artículo muestra que los requerimientos nutricionales de oligoelementos constituyen la fuerza impulsora de la corrosión influenciada microbiológicamente que produce Hormoconis resinae en aleaciones aeronáuticas de aluminio. Se compararon perfiles proteicos de biopelículas del hongo cultivado en turbocombustible aeronáutico mediante electroforesis en geles de poliacrilamida. Se caracterizó la morfología de ataque de las aleaciones y de sus componentes metálicos puros y el crecimiento de hifas sobre cada metal mediante microscopía electrónica de barrido ambiental. Se concluyó que la corrosión estaría asociada a aleantes que actuarían como oligoelementos para el microorganismo.This article shows that the metabolic needs of oligoelements constitute the driving force of the microbiologically influenced corrosion produced by Hormoconis resinae on aeronautical aluminium alloys. Protein profiles of biofilms generated by fungal strains cultivated in aeronautical fuel were compared by electrophoresis in poliacrylamide gels. The morphology attack of alloys, its component metals and the growth of hyphae in cultures were characterized by means of environmental scanning electronic microscopy. One of the main conclusions is that corrosion would be associated to alloying elements that would act as oligoelements for the microorganism.

  9. Microestructura y propiedades mecánicas de materiales compuestos de matriz Al-Mg-Si-Cu reforzada con AlNp, procesados por extrusión de polvos

    Directory of Open Access Journals (Sweden)

    Ortiz, José Luis

    2000-10-01

    Full Text Available This article presents an experimental investigation on the structure and mechanical properties of an Al-Mg-Si-Cu P/M alloy reinforced with 5 %, 10 % and 15 % aluminum nitride, produced by extrusión of cold compacted powders mixtures. Mechanical properties in "as extruded" and T6 conditions are compared. Differential Scanning Calorimetry and Dilatometric analysis were conducted to gain further insight into the precipitation process of these materials. Low cost 6061Al/AlNp composites can be produced with rare and small porosity by extrusión of cold compacted shapes without canning. The mechanical properties of the MMCs obtained by this process have limitations for high particles fractions because of clustering effects. All materials are always harder than the matrix and shows a similar behavior during aging processes but kinetics is changed. Potential applications of dilatometric techniques in the aging investigations of aluminum alloys and aluminum matrix composites have been established.

    Se presenta una investigación experimental sobre la relación entre la estructura y las propiedades mecánicas de materiales obtenidos mediante la extrusión en caliente de preformas de polvos compactados en frío y cuya matriz es una aleación Al-Mg-Si-Cu con composición cercana a la AA6061, reforzada con tres proporciones diferentes (5, 10 y 15 % en volumen de partículas de AlN. Se utilizó Calorimetría Diferencial de Barrido y Dilatometría sobre las muestras solubilizadas y templadas para complementar el estudio del efecto de las partículas sobre el envejecimiento de la aleación base. Se establece que es posible producir, a bajo costo, materiales compuestos de matriz metálica, MMCs, de matriz de aleación AA6061 reforzada con partículas de AlN con baja porosidad y buenas propiedades mecánicas, mediante la extrusión de mezclas de polvos compactados en frío, sin necesidad de enlatado. Sin embargo, las aglomeraciones de partículas, para

  10. Alteraciones auditivas en trabajadores expuestos al ruido industrial

    Directory of Open Access Journals (Sweden)

    Adel Hernández Díaz

    2007-09-01

    Full Text Available Motivados por la importancia del ruido como riesgo laboral en las actividades productivas de la Carpintería de Aluminio "Tomás Alvarez Breto" decidimos realizar un control audiométrico periódico de estos trabajadores con la finalidad de determinar el grado de exposición de los mismos y establecer las recomendaciones más importantes para su protección. Nos propusimos como objetivo determinar el grado de afectación auditiva por ruido en los trabajadores expuestos al riesgo, para lo cual se cuantificaron los niveles de ruido existentes en los diferentes puestos de trabajo, se confeccionaron las historias clínicas y se realizó un examen otoscópico y una prueba audiométrica en ambos oídos para definir el daño acústico y la presencia de hipoacusia profesional en los obreros estudiados. Al concluir el estudio pudimos comprobar que el ruido constituía un contaminante de gran importancia en esta industria. Este riesgo laboral se encontraba por encima del nivel de seguridad de 85 db(A en 9 de los 13 departamentos con que cuenta el centro y ha afectado la salud de los trabajadores ya que existían 77 casos (78,5% de hipoacusia atribuible al ruido y un gran número de trabajadores (30,6% expuestos a elevados niveles de ruido innecesariamente por la naturaleza de su labor. Por todo esto recomendamos tomar medidas que reduzcan el nivel de ruido en los puestos de trabajo donde existían niveles superiores a los permitidos, exigirse el uso de los medios de protección auditiva en los trabajadores expuestos y cumplirse estrictamente con los exámenes médicos preventivos, incluyendo las pruebas audiométricas anualmente.Motivated by the importance of the noise like labour risk in the productive activities of Aluminium Carpentry Tomas Alvarez Breto we decide to carry out a control periodic audiometric of these workers with the purpose of to determine the degree of exhibition of the same ones and to establish the most important recommendations for

  11. Strength and thermal stability of Cu-Al2O3 composite obtained by internal oxidation

    Directory of Open Access Journals (Sweden)

    Jovanovic, M. T.

    2010-12-01

    Full Text Available The objective of the work is to study the effects of the high-energy milling on strengthening, thermal stability and electrical conductivity of Cu-Al2O3 composite. The prealloyed copper powders, atomized in inert gas and containing 3 wt. % Al, were milled up to 20 h in the planetary ball mill to oxidize in situ aluminium with oxygen from the air. Composite compacts were obtained by hot-pressing in an argon atmosphere at 800 °C for 3 h under the pressure of 35MPa. The microstructural characterization was performed by the optical microscope, scanning electron microscope (SEM, transmission electron microscope (TEM and X-ray diffraction analysis (XRD. The microhardness, electrical conductivity and density measurements were also carried out. The effect of internal oxidation and high-energy milling on strengthening of Cu-Al2O3 composite was significant, The increase of the microhardness of composite compacts (292 HV is almost threefold comparing to compacts processed from the as-received Cu-3 wt. % Al powder (102 HV. The grain size of Cu-Al2O3 compacts processed from 5 and 20 h-milled powders was 75 and 45 nm, respectively. The small increase in the grain size and the small microhardness drop indicate the high thermal stability of Cu-Al2O3 composite during high-temperature exposure at 800 °C.El objetivo del trabajo es el estudio de los efectos de la pulverización con altas energías sobre la resistencia, estabilidad térmica y conductividad eléctrica del compuesto Cu-Al2O3. El polvo pre-aleado de cobre, obtenido a través de la atomización con gas inerte y con un contenido de 3wt. % Al, se molió durante 20 h en el molino planetario de bolas dando lugar a la oxidación in situ del aluminio con el oxígeno del aire. El compuesto compactado se ha obtenido mediante prensado en caliente en atmósfera de argón a 800 °C durante 3 h y a una presión de 35MPa. La caracterización microestructural se hizo a través de microscopia óptica, microscopia

  12. Amyotrophic Lateral Sclerosis (ALS)

    Science.gov (United States)

    ... benefit of 16 months before onset of severe respiratory failure. Other treatments are designed to relieve symptoms and ... of ALS. Most people with ALS die from respiratory failure, usually within 3 to 5 years from the ...

  13. Mechanical and electrical evaluation of a dilute aluminium alloy heat treated for application in electrical cables and wires; Avaliacao mecanica e eletrica de uma liga diluida de aluminio tratada termicamente para aplicacao em fios e cabos eletricos

    Energy Technology Data Exchange (ETDEWEB)

    Freitas, E.S. [Faculdade de Engenharia Mecanica - Unicamp - Campinas, SP (Brazil)], e-mail: manu@fem.unicamp.br; Kamizono, K.A.; Nogueira, P.; Nogueira, A.T.; Quaresma, Jose Maria do Vale [Universidade Federal do Para - UFPA, PA (Brazil)

    2010-07-01

    With the need to investigate new materials developed and presented to the market of non-ferrous materials and in particular those developed for the transmission and distribution of electricity, we conducted a study on a dilute alloy Al-EC-0, 7% Si, where from his previous characterization and thus knowing their good mechanical and electrical properties, we developed a new aluminum alloy in an attempt to know the properties of the alloy Al-EC-0, 7% Si in the presence of alloying elements, titanium. Being the new alloy under different thermal treatment temperature in order to observe their behavior under such mechanical and electrical conditions. (author)

  14. Al2O3 sintered pellets as thermoluminescent dosimeters Pastillas sinterizadas de Al2O3 como dosímetros termoluminiscentes

    Directory of Open Access Journals (Sweden)

    Amalia Osorio

    2012-06-01

    pico TL alrededor de los 165C, el cual puede ser usado para dosimetría. Los resultados muestran que las pastillas pueden serusadas en programas de control de calidad como dosímetro termoluminiscenteen el rango de dosis terapéuticas. La importancia de este trabajo radica en que el óxido de aluminio (−Al2O3 es una alternativa prometedora dentrode los materiales TL usados para dosimetría “in vivo”dentro de los programasde control de calidad.

  15. Development of solar cells with back surface field made by aluminum paste and belt furnace diffusion; Desenvolvimento de celulas solares com campo retrodifusor formado por pasta de aluminio e difusao em forno de esteira

    Energy Technology Data Exchange (ETDEWEB)

    Marcolino, Juliane Bernardes

    2011-01-15

    Photovoltaics is based on the direct conversion of solar energy into electricity and is a promising alternative to diversify the world's energy matrix. This work aims to develop and analyse the deposition of Al paste by screen printing and firing/diffusion in a belt furnace to produce a BSF region in monocrystalline Si wafers. The diffusion of Al into the substrate was implemented by two different processes. In the first process the diffusion/firing of the Al paste and the firing of the Ag paste was carried out in independent steps. In this case, solar cells with an average efficiency ({eta}{sub average}) of 11.5 % and a maximum of 12.0 % were produced, but with the formation Al clusters in the back surface of the devices. In the second process firing/diffusion of such pastes was done on the same step. In this case, the best results were obtained for a firing/diffusion temperature of 860 deg C and belt furnace speed (V{sub E}) of 150 cm/min and also for 890 deg C and 180 cm/min. For the former parameters, {eta}{sub average} was 12.4 % and the maximum was 12.8 %. For the later, {eta}{sub average} was 12.5 % and the maximum was 12.6 %. Considering a temperature of 900 deg C and V{sub E} of 190 cm/min, {eta}{sub average} was 12.4 %. It was observed that minority carriers diffusion lengths were smaller than the thickness of silicon wafers. Open circuit voltages were 30 mV lower than that from similar cells fabricated at NT-Solar by using high purity Al deposited by e-beam evaporation indicating that the developed process produced low quality BSF. (author)

  16. Volver al desarrollo

    Directory of Open Access Journals (Sweden)

    Jaime Ornelas Delgado

    2012-01-01

    Full Text Available El desarrollo, categoría empleada para expresar el crecimiento económico, surge durante la "guerra fría" y si bien fue propuesta por teóricos metropolitanos, se asumió en Latinoamérica como parte de los instrumentos disponibles para lograr el crecimiento y alternativa al socialismo. El desarrollo mantuvo su vigencia entre 1945 y 1975, cuando al advenimiento del neoliberalismo fue paulatinamente retirado de la agenda de las preocupaciones nacionales e internacionales. Al iniciarse el siglo xxi, el fracaso del mercado autorregulado trajo de nueva cuenta al debate los problemas del desarrollo, lo que obliga a revisarlo críticamente, tanto como al concepto mismo para mostrar su carácter colonial, si se quiere construir caminos ajenos al neoliberal y superar los problemas que han hecho de Latinoamérica una de las regiones más desiguales del mundo.

  17. Neutron activation analysis: study of primary interference on determination of aluminium, magnesium, manganese and sodium; Analise por ativacao neutronica: estudo de interferencias primarias nas determinacoes de aluminio, magnesio e sodio

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Leonardo Alves da

    2007-07-01

    The neutron activation (NAA) is an analytical technique for the determination of the elementary chemical composition. It is based on the induction of artificial radioactivity in a sample by neutrons and the resulting activity is usually measured, by gamma spectrometry. Its more relevant characteristics are the high sensibility ({mu}g.g{sup -1} - ng.g{sup -1}), accuracy and precision, capability of multi elementary analysis, low detection limits and its non destructive nature. These properties classify NAA as a very powerful analytical technique. In spite of being a versatile technique, the NAA presents limitations, one of them is related to the primary interference reactions that occur during the irradiation. The calculation of the concentration is usually based on the main reaction under thermal neutrons {sup n}X(n{sub th}, y){sup n+1}X but under fast flux, the reactions {sup n+1} Y(n{sub r}, p) {sup n+1}X e {sup n+4}Y(n{sub r}, {alpha}){sup n+1}X can take place. The consequence of this interference is that the final elemental concentration will be the sum of results of the reactions and it is not possible to distinguish the real concentration. Therefore, the impact of this interference depends on the contribution of the fast neutron flux on the total neutron flux in the local irradiation channel. It means that the interference depends on how much the irradiation channel is thermalized and it is a characteristic of the reactor. In this research, several interference reactions were studied: {sup 28}Si(n{sub f},p) Al on the aluminium determination; {sup 27}Al(n{sub f},p){sup 27}Mg, on the determination of magnesium; {sup 27}Al(n{sub f}, {alpha}) Na, on the determination of sodium and {sup 56}Fe(n{sub f},p){sup 56}Mn on the determination of manganese. Two procedures were adopted: Method I, in which using pure standards of the elements, the 'apparent' masses of Al, Mg, Mn and Na from interfering reactions were evaluated and a ratio between the interference

  18. Jalta als Heterotopie

    OpenAIRE

    Schmid, Ulrich

    2013-01-01

    Jalta ist ein Ort, der sich im europäischen Kulturgedächtnis sowohl historisch als auch literarisch als "radikal anderer Ort" - als " Heterotopie" - festgesetzt hat. An der Konferenz von Jalta wurde 1945 eine neue Weltordnung geschaffen in der Hoffnung auf eine bessere Welt. Auch in den Werken von Anton ?echov, vor allem in denjenigen, die in Jalta entstanden sind, wird von einer anderen und besseren Welt geträumt.

  19. Pornographie als Metapher

    OpenAIRE

    Caroline Schubarth

    2010-01-01

    In diesem Artikel werden unterschiedliche metaphorische Verwendungen des Pornografiebegriffs und deren Implikationen untersucht. Während die Existenz von Pornografie der feministischen Anti-Porno-Bewegung als Erklärung für die anhaltende Diskriminierung von Frauen in westlichen Gesellschaften dient, nutzen rechtskonservative Kräfte den Pornografievorwurf als Rechtfertigung für die Zensur von als deviant empfundenen Identitäten und sexuellen Praktiken.This article...

  20. Pornographie als Metapher

    Directory of Open Access Journals (Sweden)

    Caroline Schubarth

    2010-02-01

    Full Text Available In diesem Artikel werden unterschiedliche metaphorische Verwendungen des Pornografiebegriffs und deren Implikationen untersucht. Während die Existenz von Pornografie der feministischen Anti-Porno-Bewegung als Erklärung für die anhaltende Diskriminierung von Frauen in westlichen Gesellschaften dient, nutzen rechtskonservative Kräfte den Pornografievorwurf als Rechtfertigung für die Zensur von als deviant empfundenen Identitäten und sexuellen Praktiken.

  1. Corrosion behavior of Fe3Al intermetallics with addition of lithium, cerium and nickel in 2.5 % SO2+N2 at 900 °C

    Directory of Open Access Journals (Sweden)

    González-Rodríguez, J. G.

    2012-12-01

    Full Text Available The corrosion behavior of Fe3Al-type intermetallic alloys with addition of 1 at. % cerium, lithium and nickel at high temperature has been studied. The various alloys were exposed to an environment composed of 2.5 % SO2+N2 at 900 °C for 48 h. For all the intermetallic tested, the corrosion kinetics showed a parabolic behavior. The alloy, which showed less corrosion rate, was the Fe3AlNi alloy, being Fe3AlCeLi the alloy with the highest corrosion rate. For the various alloys, energy dispersive X-ray spectroscopy analysis, EDS, on the developed scale only detected aluminum, oxygen, and traces of iron and cerium, suggesting the formation of alumina as main component. The intermetallic alloys showed oxide cracking and spalling. The intermetallic chemical composition played an important role in defining the oxide scale morphology and the extent of damage.Se estudió el comportamiento a la corrosión a alta temperatura de intermetálicos tipo Fe3Al con adición de 1at. % de cerio, litio y níquel. Las diferentes aleaciones fueron expuestas bajo un ambiente compuesto de 2,5 % SO2+N2 a 900 °C durante 48 h. Para todos los intermetálicos ensayados, la cinética de corrosión presentó un comportamiento parabólico. La aleación que mostró la menor velocidad de corrosión fue el intermetálico Fe3AlNi, siendo el intermetálico Fe3AlCeLi el de mayor velocidad de corrosión. Los análisis mediante espectroscopía de dispersión de rayos X, EDS, sobre la costra formada identificaron únicamente aluminio, oxígeno y trazas de hierro y cerio, lo que sugiere la formación de alúmina como el componente principal. Los intermetálicos mostraron agrietamiento y desprendimiento de la costra de óxido. La composición química de los intermetálicos tuvo un papel importante en la definición de la morfología del óxido formado y el grado de daño.

  2. Gezondheid als marketinginstrument

    NARCIS (Netherlands)

    Vijver, van de L.P.L.; Berg, van den I.

    2008-01-01

    Is biologisch voedsel beter dan gangbaar? Hoe hard zijn de bewijzen daarvoor? En hoe sterk moet het bewijs zijn voordat je het als claim op een product mag zetten? In dit Biokennis bericht een overzicht van de wetenschappelijke conclusies en de mogelijkheden om biologisch te promoten als beter, neer

  3. Al-Anon/Alateen

    Science.gov (United States)

    Find an Al-Anon meeting Español | Français 2018 Int'l Convention Home About Group Meetings What If I'm not ready ... a meeting? What can I expect at an Al-Anon meeting? What was my first meeting like? ...

  4. Al - BASED CAST COMPOSITES

    Directory of Open Access Journals (Sweden)

    Rakesh Kumar Yadav

    2011-08-01

    Full Text Available The economy is very important feature nowadays in themarket. The researches are playing an important role inengineering field to increase the life of machine parts /components and decrease the cost. The compositematerials have the potential to replace widely used steeland aluminium due to their good characteristics withbetter performance. The Al-based composites have foundextensive applications in automobile industries andaerospace industries due to their increased stiffness,strength, thermal conductivity and wear resistanceproperties. A number of particulate phases have beenemployed in the Al-alloy matrix. The cast aluminiumceramicparticulate composites are finding applications inpistons, connecting rods, cylinder liner, engine cylinderblock, electrical contacts etc.The present investigation isbased on study of the effect of particulate phase on theSEM study, micro-hardness, elastic modulus, tensilestrength and the wear behaviour of Al-5 % SiC-7 % Fe,Al-10 % SiC-6 % Fe and Al-15 % SiC-5 % Fe composites.

  5. Relation between feeding mechanisms and solidification mode in 380 aluminium alloy with different iron contents; Relacion entre los mecanismos de alimentacion y el modo de solidificacion en una aleacion de aluminio 380 con distintos contenidos de hierro

    Energy Technology Data Exchange (ETDEWEB)

    Tovio, D. O.; Gonzalez, A.C.; Mugica, G. W.; Cuyas, J. C.

    2003-07-01

    In the present work the effect of iron (0.15, 0.42 and 0.86%) content in feeding mechanisms for 380 aluminium alloy has been studied. The feeding capacity has been evaluated by a device that produces a barrier removable to allowing the movement of the inter dendritic liquid. The results show the flow of different quantity of liquid, it depends of the temperature of operating the device and of the iron content. For minimum and maximum iron content, the inter dendritic and bursts feeding mechanisms are fundamentally involved, for 0.42% of iron the feeding mechanisms was the inter dendritic. The authors establish this behavior by the solidification mode of alloy, which promotes the presence of particles of Si or plates of b-Al{sub 3}FeDi phase, in the inter dendritic channels and produce the different feeding mechanisms. (Author) 15 refs.

  6. Sociale media als leermiddel

    NARCIS (Netherlands)

    Rubens, Wilfred

    2012-01-01

    Rubens, W. (2012, 5 juni). Sociale media als leermiddel. Presentatie over het gebruik van sociale media binnen het onderwijs, verzorgd tijdens een ouderraadbijeenkomst van de Katholieke Scholengemeenschap Etten-Leur, Etten-Leur, Nederland.

  7. MDA ALS Caregiver's Guide

    Science.gov (United States)

    ... R.D., C.N.S.D., L.D.N. Nutritionist MDA/ALS Center at Vanderbilt University Medical Center ... neurologists, physiatrists, therapists (physical, occupa- tional, speech, respiratory), nutritionists, social work- ers, pulmonologists, gastroenterologists and medical equipment ...

  8. Regionale Herkunft als Bonus

    OpenAIRE

    Kratochvil, Dr. Ruth

    2004-01-01

    Der Bio-Sektor durchlebt bewegte Zeiten. Die biologische Landwirtschaft hat sich aus der Nische herausbewegt und dafür an „Besonderheiten“ eingebüßt. Diese müssen als Zusatznutzen wiedergefunden werden.

  9. Partizipation als Ausnahmezustand

    OpenAIRE

    Korf, Benedikt

    2009-01-01

    In «Die Erfindung des Politischen» (1993) beschreibt Ulrich Beck Subpolitik als den Ort, an dem die Grenze zwischen Politik und Nichtpolitik verschwindet. Aus der zunehmenden Wirkkraft von Subpolitik erwächst die grundlegende Frage, mit welcher Legitimation diese Art von Subpolitik in die Sphäre der institutionalisierten Politik eindringt. Beck’s Subpolitik soll im Anschluss an theoretische Arbeiten von Chantal Mouffe und Giorgio Agamben als post-politische Aspiration bezeichnet werden, die e...

  10. Der Preis als Kaufbarriere?

    DEFF Research Database (Denmark)

    Mueller Loose, Simone

    2012-01-01

    Die Preispolitik hat eine herausragende Stellung im Marketing. Der Preis eines Produktes ist für Verbraucher ein direkter Kostenfaktor und für Unternehmen die Stellgröße im Mar-ketingmix, die den Umsatz am stärksten beeinflusst (vgl. Nieschlag et al. 2002). Wenn die Akzeptanz und der regelmäßige...... Verzehr gesunder Lebensmittel erhöht werden soll, ist es sowohl für die Verbraucherpolitik als auch für Lebensmittelproduzenten wichtig, den Ein-fluss des Preises auf die Kaufentscheidung zu verstehen. Aus Verbrauchersicht ist der Preis neben dem Geschmack die wichtigste Produkteigen-schaft beim Kauf von...... Lebensmitteln (vgl. Brunsø/Grunert 1998) und stellt eine Kaufbarrie-re für Lebensmittel mit gesundheitsfördernden Eigenschaften dar. Studien in den USA (vgl. Cassady et al. 2007), Frankreich (vgl. Drewnowski et al. 2004; Andrieu et al. 2005) und Deutschland (vgl. Karg et al. 2008) kommen übereinstimmend zu dem...

  11. Estructura y textura de la fase Al3CaZn en una chapa laminada de la aleación superplástica Al-5 % Ca-5 % Zn

    Directory of Open Access Journals (Sweden)

    Pérez-Pardo, M. T.

    1998-05-01

    Full Text Available The structure of the intermetallic phase Al3CaZn present in the superplastic sheet alloy Al-5 % Ca-5 % Zn has been determined by means of x-ray diffraction (XRD and electrón diffraction (TEM. Also, the texture of this phase has been studied by means of pole figures and the orientation distribution function (ODF. The Al-5 % Ca-5 % Zn alloy is formed by a fine grained aluminum matrix (d ≈ 2-3 μm and 20 % vol. of Al3CaZn in the form of round-shaped particles with 0.2-0.5 μm diameter. This alloy undergoes superplastic behavior in a wide range of strain rates and temperatures. It has been found in this work that the structure of the second phase is body-centered tetragonal, with lattice parameters a = b = 0.422 nm and c = 1.131 nm. The texture of the alloy is formed by the fiber <001>, i.e., the crystallites are oriented preferentially with the c-axis perpendicular to the rolling plane. The texture sharpens after severe annealings.

    En este trabajo se ha determinado la estructura de la fase Al3CaZn, presente en una chapa laminada de la aleación Al-5 % Ca-5 % Zn, mediante técnicas de difracción de rayos X (DRX y difracción de electrones (MET. Además, se ha estudiado su textura mediante figuras de polos y la función de distribución de orientaciones (FDO. La aleación Al-5 % Ca-5 % Zn objeto de este estudio consta de una matriz de aluminio de grano fino (d ≈ 2-3 μm y un 20 % vol. de la fase Al3CaZn. Esta segunda fase está presente en el material de partida en forma de partículas esferoidales de 0,2 - 0,5 μm de diámetro. La aleación presenta un comportamiento superplástico en un amplio intervalo tanto de velocidades de deformación como de temperaturas. Se ha encontrado que la fase Al3CaZn posee una estructura tetragonal centrada, con parámetros de red a = b= 0,422 nm y c = 1,131 nm. Presenta, además, una textura de fibra <001>, en la

  12. Modification of residual stress in Al-[AlBO]w/Al compound plate

    Institute of Scientific and Technical Information of China (English)

    姜传海; 吴建生; 王德尊

    2001-01-01

    The application of compound parts of Al-[AlBO]w/Al not only reduces the cost of the parts but also improves its properties. However, there is a large thermal residual stress between Al and [AlBO]w/Al, and it is harmful for practical application. From the theoretical analyses and experimental results, it was found that by the compressive pre-plastic deformation perpendicular to the interface between Al and [AlBO]w/Al, the interlayer residual stress of compound parts can be reduced, while the mechanical properties of compound parts can be improved.

  13. Fortschritt als Fortschrittsdiskurs

    Directory of Open Access Journals (Sweden)

    Rainer Schmid-Zartner

    2014-12-01

    Full Text Available Zur Erzielung gesellschaftlichen Fortschritts in demokratisch verfassten Gesellschaften soll die Möglichkeit am Fortschrittsdiskurs teilnehmen zu können für alle Mitglieder der Gesellschaft als selbstverständliche Prämisse gelten. Fortschritt wird also als Bewusstseinsbildung dem Fortschritt selbst gegenüber und als Entscheidungs- und Handlungsfähigkeit auf individueller und gesellschaftlicher Ebene definiert. Dies setzt entsprechende Maßnahmen zur Befähigung dazu voraus, die alle Mitglieder der Gesellschaft erfassen. Dabei ist der Bildungsbereich angesprochen, insbesondere der Schulunterricht. Neben dem in der aktuellen blidungspolitischen Debatte forcierten Fokus auf den Aspekt der Kompetenzorientierung, der hier nicht infrage gestellt wird, ist als notwendige Ergänzung ein reflexionsorientierter Schulunterricht in allen Bildungsfächern einzufordern und umzusetzen. Im Weiteren beschreibt der Text den Weg von der Brauchbarkeit zur Bedeutsamkeit von schulischem Wissen durch Relevanzreflexionsprovokationen im Schulunterricht, um Sinn und Bedeutung der vermittelten Bildungsinhalte zu verhandeln. Am Beispiel von Mathematik als Bildungsfach wird der Inhalt von reflexionsorientertem Unterricht verdeutlicht. Darüber hinaus beschreibt der Text eine Reihe von konkreten Fallbeispielen aus der aktuell versuchsweise durchgeführten Unterrichtspraxis in Mathematik.

  14. Reacciones en estado sólido para el sistema Al-MoO3 en la fabricación de materiales compuestos Al2O3-aluminuros de Mo

    Directory of Open Access Journals (Sweden)

    Marín, J.

    2002-02-01

    Full Text Available Ceramic matrix composites reinforced with metallic particles exhibit good mechanical properties. One research line has involved the fabrication of 3A (alumina-aluminide alloys composites via in situ consolidation of aluminum reactive powders mixed with a metallic oxide. In this paper the solid state reactions for the Al-MoO3 system and the effect of the precursor compositions for obtaining Al2O3 composites and intermetallic aluminides are studied. The reactions in vacuum for the 25 °C to 750 °C temperature range, and the microstructural evolution up to 1200 °C were studied. DTA-TG and DSC were used to determine that a heating rate of 1 °C/min at the critical range of 500-600 °C, resulted in controlled aluminothermic reactions. XRD and SEM showed that in the sintered composites a microstructure composed of an Al2O3 matrix and a Mo aluminide /metallic Mo dispersed phase was present. The precursor composition affects the dispersed phase in the composite (Mo aluminides and/or metallic Mo, the relative Al2O3 /second phase quantities, and the hardness of the composite sintered at 1450 °C.

    Los materiales compuestos de matriz cerámica (CMC's de Al2O3 reforzados con partículas metálicas tienen propiedades mecánicas muy atractivas. Un área de investigación emergente es la fabricación de compuestos 3A (Alumina-Aluminide-Alloys, mediante la formación in situ de Al2O3 reforzada con metal elemental y/o aluminuros del metal, partiendo de polvos de aluminio y de óxidos metálicos. En este trabajo se estudian las reacciones en estado sólido para el sistema Al-MoO3. Las reacciones de aluminotermia se estudian en vacío para el rango de temperaturas entre 25 °C y 750 °C y su evolución microestructural hasta 1.200 °C. Mediante análisis calorimétrico (DTA-TG y DSC se determinó que para una

  15. Pornographie als Metapher

    Directory of Open Access Journals (Sweden)

    Caroline Schubarth

    2010-03-01

    Full Text Available In diesem Artikel werden unterschiedliche metaphorische Verwendungen des Pornografiebegriffs und deren Implikationen untersucht. Während die Existenz von Pornografie der feministischen Anti-Porno-Bewegung als Erklärung für die anhaltende Diskriminierung von Frauen in westlichen Gesellschaften dient, nutzen rechtskonservative Kräfte den Pornografievorwurf als Rechtfertigung für die Zensur von als deviant empfundenen Identitäten und sexuellen Praktiken.This article examines different metaphorical uses of the term pornography and the resulting implications. While the existence of pornography for the feminist anti-porno movement serves as factor in the continuing discrimination of women in western societies, conservative powers on the right use the allegation of pornography as a justification for censorship of those identities and sexual practices deemed deviant.

  16. Fluoride ions sorption of the water using natural and modified hematite with aluminium hydroxide; Sorcion de iones fluoruro del agua utilizando hematita natural y hematita acondicionada con hidroxido de aluminio

    Energy Technology Data Exchange (ETDEWEB)

    Teutli S, E. A.

    2011-07-01

    Fluorine is a mineral known for its dental benefits, but fluoride ions can cause fluoro sis in excessive quantities. There are many epidemiological studies on possible adverse effects resulting from prolonged ingestion of fluoride through drinking water. These studies demonstrate that fluoride mainly affects the bone tissue (bones and teeth), may produce an adverse effect on tooth enamel and can cause mild dental fluoro sis at concentrations from 0.9 to 1.2 mg/L in drinking water. In several states of Mexico, water contaminated with fluoride ions can be found, such as Aguascalientes, Chihuahua, Coahuila, Durango, Guanajuato, Sonora, Zacatecas, San Luis Potosi and Jalisco, where the fluoride ions levels are higher than 1.5 mg/L, established by the Mexican Official Standard (NOM-127-Ssa-2000) which sets the permissible limits of water for human use and consumption. Currently, several technologies have been proposed to remove fluoride ions from water such as precipitation methods which are based on the addition of chemicals to water and sorption methods to removed fluoride ions by sorption or ion exchange reactions by some suitable substrate capable of regenerate and reuse. In this work, the sorption of fluoride ions using unmodified and modified hematite with aluminum hydroxide to remove fluoride ions from water by bath experiments was studied. The hematite was modified by treating it with aluminum hydroxide, NaOH and Al{sub 2}(SO{sub 4}){sub 3} solutions. The characterization of hematite before and after modification with aluminum hydroxide was studied by X-ray diffraction, scanning electron microscopy, EDS and Bet. The effect of ph, contact time, concentration of fluoride ions, and the dose of sorbent on the sorption of fluoride ions by the modified hematite were studied. Equilibrium was reached within 48 hours of contact time and the maximum sorption of fluoride ions were in the range pH{sub eq} between 2.3 and 6.2. Sorption capacities of fluoride ions as a

  17. Wikipedia als Referenzorgan

    OpenAIRE

    Voß, Jakob

    2006-01-01

    Wikipedia wird inzwischen von vielen Nutzern regelmäßig als Nachschlagewerk genutzt. Aufgrund des offenen Charakters der Online-Enzyklopädie, bei der sich jeder direkt beteiligen kann, ist jedoch zusätzliche Medienkompetenz notwendig, um die Qualität einzelner Wikipedia-Artikel einschätzen zu können. Im Vortrag sollen Methoden zur Beurteilung von Wikipedia-Artikeln dargestellt und die Frage beleuchtet werden, unter welchen Umständen Wikipedia als Referenzorgan geeignet ist.

  18. Carta al Editor

    Directory of Open Access Journals (Sweden)

    José Andrés Burgos Zuleta

    2010-06-01

    Full Text Available La medicina al basarse generalmente en la clínica, correlacionaexámenes complementarios y organiza un diagnóstico y tratamiento, es una disciplina donde es imprescindible saber recolectar, analizar, interpretar y concretar una respuesta adecuada, es así que la información que se recibe es esencial para el desempeño médico.La certeza es una realidad que se da en algunas situaciones y enotras las probabilidades establecen conclusiones. Lo normal muchas veces se define sobre la base de criterios estadísticos, basados en riesgos poblacionales que no necesariamente se aplican al caso boliviano.

  19. Calculation of interaction of AlCl, AlCl2 and AlCl3 on Al4C3 (001) Al4CO4 (001) and Al2CO (001) planes

    Institute of Scientific and Technical Information of China (English)

    段少飞; 陈秀敏; 杨斌; 郁青春; 徐宝强; 刘大春

    2015-01-01

    To make sure the intermediate products of the carbothermic reduction of Al2O3 process, such as Al4CO4, Al2CO and Al4C3, and the interaction of AlCl, AlCl2, AlCl3 with Al4CO4, Al2CO and Al4C3, respectively, thermodynamic analyses were used to study the chloride reaction production of them under the vacuum situation. The stable structures and electronic properties of AlCl, AlCl2 and AlCl3 adsorbed on Al4CO4, Al2CO and Al4C3 were calculated by first-principles calculations by the CASTEP module in the Materials Studio program. The results show that the AlCl3 and AlCl2 molecules have decomposed on the plane of Al4C3 (001), while there are no obvious decomposition of AlCl3 and AlCl2 on Al4CO4 (001) and Al2CO (001) planes. The adsorption of AlCl on the Al4CO4 (001) and Al2CO (001) planes is stronger than that on the Al4C3(001) plane. The interaction strength of AlCl3, as well as AlCl2, with Al4CO4, Al2CO and Al4C3 is in the sequence of Al4CO4Al2CO>Al4C3.

  20. Comentarios al Salto Social

    Directory of Open Access Journals (Sweden)

    Facultad de Ciencias Económicas

    1995-06-01

    Full Text Available 1. El Plan considera que la política social es un componente central de la estrategia macroeconómica. A diferencia de la administración Gaviria, lo social ha dejado de ser un asunto marginal, es consustancial al desarrollo y, por tanto, se le confiere una dimensión cualitativamente diferente.

  1. Slowenisch als fremdsprache

    Directory of Open Access Journals (Sweden)

    Jože Toporišič

    1981-12-01

    Full Text Available Nicht ganz zwei Millionen Menschen sprechen Slowenisch als Muttersprache. Wenige gibt es, die das Slowenische zwar spre­ chen oder zu sprechen versuchen, aber eine andere Muttersprache haben, vielleicht hunderttausend; für die ist Slowenisch also eine Fremdsprache.

  2. ALS insertion devices

    International Nuclear Information System (INIS)

    The Advanced Light Source (ALS), the first US third generation synchrotron radiation source, is currently under construction at the Lawrence Berkeley Laboratory. The low-emittance, 1.5 GeV electron storage ring and the insertion devices are specifically designed to produce high brightness beams in the UV to soft X-Ray range. The planned initial complement of insertion devices includes four 4.6 m long undulators, with period lengths of 3.9 cm, 5.0 cm (2) and 8.0 cm, and a 2.9 m long wiggler of 16 cm period length. Undulator design is well advanced and fabrication has begun on the 5.0 cm and 8.0 cm period length undulators. This paper discusses ALS insertion device requirements; general design philosophy; and design of the magnetic structure, support structure/drive systems, control system and vacuum system. 18 refs., 9 figs., 5 tabs

  3. De GPS al mapa

    Directory of Open Access Journals (Sweden)

    Esteban Dörries

    2016-03-01

    Full Text Available Las coordenadas Lambert obtenidas a partir de mediciones con equipos GPS de mano, llamados a veces navegadores, en ciertos casos confunden al usuario, por diferir claramente de su posición real al ser graficadas en un mapa del Instituto Geográfico Nacional (IGN: Esto puede resolverse con suficiente exactitud mediante una transformación de Molodensky, seguida de la correspondiente proyección cartográfica. Sin embargo, los tres parámetros necesarios para la transformación, supuestamente válidos para Costa Rica, se encuentran en muchas variantes y producen obviamente resultados diferentes. En este trabajo se analizan los fundamentos del problema y sus posibles soluciones, culminando con un estudio comparativo de ocho casos, que permite seleccionar los valores más adecuados para los parámetros.

  4. AL-IZDIWAJIYYAH AL-LUGHOWIYAH FII ISTIHDHAMI AL-LUGHOH AL-‘ARABIYAH

    OpenAIRE

    Imam Muslimin

    2011-01-01

    Al-Izdiwajiyyah (diglosia) is standardizing a specific language when there are two variants of language that live side by side in societal life and each variant has its own social function. Disglosia is related to the use of local languages variations of low language and high language in a community. In Arabic language, disglosia covers dialects among the speakers, for instance there are two variants of language that each has roles and functions. The use of the variant depends on the situatio...

  5. Carta al editor

    Directory of Open Access Journals (Sweden)

    Harry Pachajoa

    2012-02-01

    Full Text Available Recently, Valencia et al., published a very interesting article called «Lipid profile in a group of patients with Turner’s syndrome at Clínica Universitaria Bolivariana in the city of Medellín between 2000 and 2009". An article which evaluated lipid levels in patients withTurner syndrome in a Colombian clinic, the study associated results of lipid profile with karyotype and other risk factors for coronary heart disease.

  6. Carta al editor

    OpenAIRE

    Harry Pachajoa

    2012-01-01

    Recently, Valencia et al., published a very interesting article called «Lipid profile in a group of patients with Turner’s syndrome at Clínica Universitaria Bolivariana in the city of Medellín between 2000 and 2009". An article which evaluated lipid levels in patients withTurner syndrome in a Colombian clinic, the study associated results of lipid profile with karyotype and other risk factors for coronary heart disease.

  7. Estudio calorimétrico no isotérmico del proceso de precipitación en una aleación de Cu-10 % Ni-3 % Al

    Directory of Open Access Journals (Sweden)

    Donoso, E.

    2007-04-01

    Full Text Available Using differential scanning calorimetry (DSC, the precipitation process of nickel and aluminium atoms from a solid solution of Cu-Ni-Al were studied. Analysis of calorimetric traces displayed shows the presence of two exothermic reactions (stage 1 and 2, which were interpreted as the formation of two types of precipitates. The first stage corresponds to the formation of an equilibrium b (NiAl phase, whilst stage 2 corresponds to the formation of g’ precipitate with Ni3Al stoichiometric composition. It is observed the shift of the traces to lower temperatures while linear heating rate decrease. The activation reaction energies were evaluated from modified Kissinger’s method. Kinetic parameters were calculated by means Johnson-Mehl-Avrami formalism. The values obtained for parameter n were indicative of a particle nucleation process from pre-existent nucleus. Microhardness measurements and micrographies obtained by transmission electron microscopy were helpful to confirm the formation and the dissolution of the mentioned phases.

    Mediante calorimetría diferencial de barrido (DSC, se estudió el proceso de precipitación de átomos de níquel y aluminio a partir de una solución sólida de Cu-Ni-Al. El análisis de las curvas calorimétricas muestra la presencia de dos reacciones exotérmicas (etapas 1 y 2, que se interpretan como la formación de dos tipos de precipitados. La primera etapa corresponde a la formación de la fase de equilibrio b (NiAl, en tanto que la etapa 2 corresponde a la formación del precipitado g’ de composición estequiométrica Ni3Al. Además, se observa que las curvas se desplazan a temperaturas más bajas a medida que la velocidad de calentamiento lineal decrece. Las energías de activación de las reacciones fueron evaluadas a partir de un método de Kissinger modificado. Los parámetros cinéticos se calcularon mediante el formalismo de Johnson- Mehl-Avrami. Los valores de n obtenidos

  8. Modeling neuronal vulnerability in ALS.

    Science.gov (United States)

    Roselli, Francesco; Caroni, Pico

    2014-08-20

    Using computational models of motor neuron ion fluxes, firing properties, and energy requirements, Le Masson et al. (2014) reveal how local imbalances in energy homeostasis may self-amplify and contribute to neurodegeneration in ALS.

  9. AL-USRCRN Station Information

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Documentation of United States Alabama Regional Climate Reference Network (AL-USRCRN) installations in 2006. Installations documented are for AL-USRCRN pilot...

  10. ICT als medicijn tegen onveiligheid

    OpenAIRE

    Linders, Lilian; Steyaert, Jan

    2002-01-01

    Hoe verhoudt ICT zich tot veiligheid? SQM zou niet 'ict oplossingen voor sociale kwesties' als ondertitel hebben, als we geen aandacht gaven aan deze vraag. In de eerste Rode Draad Notitie verkent SQM dit thema.

  11. Gliricidia sepium al establecimiento

    Directory of Open Access Journals (Sweden)

    J. L. Valle

    2004-01-01

    Full Text Available Se asoció Cenchrus ciliaris (Cc y Gliricidia sepium (Gs para evaluar la producción de biomasa y la composición química de los forrajes en la fase de establecimiento, en el estado de Morelos, México, en condiciones de trópico seco. Se empleó un análisis de varianza con diseño en bloques al azar, en donde T1 fue pasto solo, T2 Cc más Gs con 5,000 plantas ha-1 y el T3 Cs más Gs con 14,285 plantas ha-1. Se midió la producción de forraje individual y asociado con materia seca (t MS/Ha, la altura (A en cm, la proteína cruda (PC%, las fracciones de fibra (FDN% y FDA% y la digestibilidad in vitro de la materia seca (DIVMS%. El T3 tuvo una mejor producción de biomasa (P0.05. La asociación de 14,285 plantas ha-1 de G. sepium con pasto Cenchrus ciliaris mejoró la producción de biomasa y la disponibilidad total de nutrientes por superficie cultivada al establecimiento

  12. Derivados vinculados al seguro.

    Directory of Open Access Journals (Sweden)

    De Paz Cobo, Sonia

    2003-01-01

    Full Text Available El presente trabajo tiene como objetivo la presentación de los derivados financieros como instrumentos de cobertura de los riesgos del seguro, así como de los principales proyectos que se desarrollan a través de los mismos, como por ejemplo los derivados sobre el clima. Hay que tener presente las pérdidas multimillonarias ocasionadas en casos como el de la banca Baring’s, o el de Orange County, por citar algunas, que si bien ciertos autores afirman que están en relación directa con el uso de estos productos, no podemos olvidar que los instrumentos derivados se desarrollaron con el objetivo principal de proteger al usuario de la posible volatilidad del activo subyacente. Ya en la industria aseguradora los derivados vinculados a tal actividad son instrumentos donde el pago se condiciona a la ocurrencia de su suceso de siniestro, o serie de sucesos múltiples que disparen las pérdidas. Tras el repaso efectuado y la descripción que este tipo de instrumentos puede tener en la gestión del riesgo por parte de la industria aseguradora, concluiremos con la exposición de las relaciones con el reaseguro tradicional así como una breve referencia al futuro de este tipo de instrumentos

  13. Corrosion behaviour of Al/SiC and Al/Al2O3 nanocomposites

    Directory of Open Access Journals (Sweden)

    Tamer Samir Mahmoud

    2012-12-01

    Full Text Available In the present investigation, the static immersion corrosion behavior of Al/Al2O3 and Al/SiC nanocomposites in 1 M HCl acidic solution was evaluated. The nanocomposites were fabricated using conventional powder metallurgy (P/M route. The effect of nanoparticulates size and volume fraction on the corrosion behavior of nanocomposites was studied. The durations of the corrosion tests ranged from 24 to 120 hours and the temperatures of the solution ranged from ambient to 75 ºC. The corrosion rates of the nanocomposites were calculated using the weight loss method. The results showed that both Al/SiC and Al/Al2O3 MMNCs have lower corrosion rates than the pure Al matrix. Such behavior was noticed at both ambient and higher temperatures. Generally, the Al/Al2O3 nanocomposites exhibited lower corrosion rates than the Al/SiC nanocomposites. The Al/Al2O3 (60 nm nanocomposites exhibited the highest corrosion resistance among all the investigated nanocomposites. The corrosion rate was found to be reduced by increasing of the exposure time and the volume fraction of the nanoparticulates, while it was found to be increased by increasing of the nanoparticulates size and the solution temperature.

  14. Doppelthydrophile Blockcopolymere als Mineralisationstemplate

    Science.gov (United States)

    Kasparova, Pavla

    2002-07-01

    Die vorliegende Arbeit beschäftigt sich mit der Synthese und den Eigenschaften von doppelthydrophilen Blockcopolymeren und ihrer Anwendung in einem biomimetischen Mineralisationsprozeß von Calciumcarbonat und Bariumsulfat. Doppelthydrophile Blockcopolymere bestehen aus einem hydrophilen Block, der nicht mit Mineralien wechselwirkt und einem zweiten Polyelektrolyt-Block, der stark mit Mineraloberflächen wechselwirkt. Diese Blockcopolymere wurden durch ringöffnende Polymerisation von N-carboxyanhydriden (NCA's) und a-methoxy-ω-amino[poly(ethylene glycol)] PEG-NH2 als Initiator hergestellt. Die hergestellten Blockcopolymere wurden als effektive Wachstumsmodifikatoren für die Kristallisation von Calciumcarbonat und Bariumsulfat Mineralien eingesetzt. Die so erhaltenen Mineralpartikel (Kugeln, Hantel, eiförmige Partikel) wurden durch Lichtmikroskopie in Lösung, SEM und TEM charakterisiert. Röntgenweitwinkelstreuung (WAXS) wurde verwendet, um die Modifikation von Calciumcarbonat zu ermitteln und die Größe der Calciumcarbonat- und Bariumsulfat-Nanopartikel zu ermitteln. This work describes the synthesis and characterization of double hydrophilic block copolymers and their use in a biomimetic mineralization process of Calcium Carbonate and Barium Sulfate. Double hydrophilic block copolymers consist of a hydrophilic block that does not interact with minerals and another hydrophilic polyelectrolyte block that strongly interacts with mineral surfaces. These polymers were synthesised via ring opening polymerisation of N-carboxyanhydride (NCA), and the first hydrophilic block a-methoxy-ω-amino[poly(ethylene glycol)] PEG-NH2 was used as an initiator. The prepared block copolymers were used as effective crystal growth modifiers to control the crystallization of Calcium Carbonate and Barium Sulfate minerals. The resulting mineral particles (spheres, dumbbells, egg-like particles) were characterised by light microscopy in solution, by SEM, and by TEM. X-Ray scattering

  15. COMENTARIO AL CASO PINOCHET

    Directory of Open Access Journals (Sweden)

    Alberto Contreras Clunes

    2002-01-01

    Full Text Available El fallo en el caso Pinochet tiene distintas formas de ser analizado. De partida, desde un punto de vista político, también constitucional, del derecho penal. Sin embargo, nos abocaremos al estudio desde el punto de vista procesal, en especial a lo referido al Debido Proceso. Para ello se analizará los presupuestos, la solución dada por la Excma. Corte Suprema y las consecuencias del mismo. Además, se criticará la solución dada, desde la óptica de las garantías procesales del imputado, contenidas en el nuevo proceso penal y lo dispuesto en la Constitución y la Convención Americana de Derechos Humanos. Finalmente, se argumentará en favor de una interpretación finalista y armónica de la Constitución y los tratados internacionales de derechos humanos.The verdict of the Pinochet Case has different ways of being analyzed: from the political, the constitutional, and the penal law points of view. However, we will approach this study from the legal point of view, especially to that referred to as the Proper Process. To do this, the budgets, the solution given by the Most Excellent Supreme Court, and its consequences will be analyzed. Furthermore, the given solution will be criticized from the point of view of the legal guarantees of the accused contained in the new penal process and what is contained in the Constitution and in the American Convention of Human Rights. In conclusion, we will argue in favor of a final and harmonious interpretation of the Constitution and the international agreement of human rights.

  16. Estudio del mecanismo de eliminación demagnesio de aleaciones Al-Si en estado líquido mediante inyección de minerales base sílice

    Directory of Open Access Journals (Sweden)

    Muñoz-Arroyo, R.

    2010-08-01

    Full Text Available In order to eliminate magnesium from an A 380 Al-Si alloy at 750°C, the submerged powder injection method, using an inert carrier gas (Ar, was applied. The injected powders in the liquid aluminum bath were zeolite, silica and mixtures of zeolite-silica minerals. For each experiment the response variables were: eliminated magnesium versus injection time and quantity of drosses produced. Chemical analysis by atomic absorption spectrometry showed that mixtures of silica-zeolite 66:34 wt% have the best results with regarding to the removal magnesium from 1 to 0.0066 wt%. During the elimination of magnesium complex stoichiometry compounds were formed due to the reactions among zeolite, water steam and liquid aluminum. These compounds were analyzed by XRD, SEM and TEM. The results obtained, along with using the FactSage 6 thermodynamic software, allowed to elucidate the reaction mechanism between the minerals used and liquid aluminum.

    Se empleó el método de inyección sumergida de polvos por medio de un gas de arrastre inerte (Ar con el fin de eliminar el magnesio de la aleación Al-Si A380 a 750 °C. Los polvos inyectados al baño de metal fundido fueron zeolita mineral, arena sílice y mezclas de ambas. Las variables de respuesta medidas fueron el contenido de magnesio en el baño metálico respecto al tiempo de inyección y las mermas de metal al final de cada experimento. En el análisis de resultados, la mezcla sílice:zeolita 66:34 % e.p. obtuvo la mayor eficiencia, lográndose una disminución en el contenido de magnesio en el baño metálico de 1 a 0.0066 % e.p. Los productos de reacción se analizaron por difracción de rayos-X, microscopía electrónica de barrido y de transmisión. Los resultados de estos análisis y el empleo del paquete termodinámico FactSage, versión 6, permitieron justificar el mecanismo de reacción entre los minerales y el aluminio líquido.

  17. Epitaxial growth of Al/Al2O3 multilayer structures

    International Nuclear Information System (INIS)

    In order to obtain Al-Al2O3 quantum effect devices, it is necessary to deposit epitaxially Al on Al2O3 and Al2O3 on Al. We have already obtained an epitaxial Al/Al2O3/Al structures on Si(111). In this paper, we have deposit Al/Al2O3/Al structures on Si(111), and investigated the crystallinity by using RBS. (author)

  18. Effect of AlN Particulate Size on Superplasticity of AlNp/6061 Al Composites

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Superplastic tensile tests of AlNp/606l Al Composites, fabricated by powder metallurgy techniques, were performed at strain rates ranging from 10-1-10-3S-1 and at temperatures from 833 to 893 K. Hot rolling after extrusion was employed to obtain a fine grained structure before \\superplastic testing. The superplastic behavior of AlNp/6061 Al Composites was compared with that of AlN particulate size. Differential scanning calorimeter was used to ascertain the possibility of any partial melting in the vicinity of optimum superplastic temperatures.

  19. Editorial: Cartas al Editor

    Directory of Open Access Journals (Sweden)

    Guillermo Llanos

    2006-06-01

    Full Text Available En todas las revistas biomédicas del mundo existe una sección habitual denominada como el título de este editorial y que en Colombia Médica la llamamos correspondencia. Este espacio tiene como objetivo fundamental que los lectores escriban a los autores (investigadores comentando los artículos que se han publicado en números anteriores de la revista. Las cartas son, entonces, breves comentarios de desacuerdo o acuerdo (conceptual, metodológico, interpretativo sobre falencias ubicadas por un lector alerta al tema debatido en cualquiera de las secciones como en los artículos originales, editoriales, revisiones, presentación de casos, etc. publicados previamente en la revista. Las cartas deben permitir el intercambio de opiniones y formas de pensar y analizar los problemas planteados entre los autores y los lectores. En ocasiones una serie de cartas motivadas por un artículo original puede ser tan o más interesante como el artículo que generó la correspondencia. Las cartas son también un formato adecuado para comunicar un hecho novedoso de una observación clínica juiciosa no descrita antes. Un ejemplo de ello es la carta de un gineco-obstetra australiano cuando informó a Lancet los primeros efectos adversos informados de la talidomida. Colombia Médica, a pesar de mantener vigente esta sección, no ha sido muy afortunada en establecer una buena cultura del envío de cartas al editor. Pero últimamente han llegado juiciosas observaciones a las cuales se les ha dado prioridad en su publicación. Toda carta que comenta los hallazgos de un artículo es enviada a los autores para su respuesta, porque ello genera el debate académico buscado, y luego se publican, tanto la carta como su respuesta. El Estilo Vancouver recomienda que la carta y su respuesta deban ser breve, no pasar de dos o tres párrafos y contener sólo cuatro o cinco referencias. En lo posible (a menos que sea indispensable no presentar ni cuadros ni gráficos. El t

  20. Malamih al-Ashwat al-'Arabiyyah wa Makharijaha

    Directory of Open Access Journals (Sweden)

    Amrah Muhammad Kasim

    2015-12-01

    Full Text Available This writing discusses on al-ashwat al-‘arabiyyah that is known with “phonetic” term. It talks and interprets makharij al-huruf or place for producing sounds and also processing production of sounds by parts of mouth in Arabic language. The problems of sounds and its systems in Arabic language have been conducted by the scholars of al-ashwat al-‘arabiyyah attractively, neatly, and detail and gotten ahead the phonetic western scholars. Part of their analysis results formulate the study about al-ashwat al-sakinah (al-Shamit is known with vocal and consonant sounds in research questions shawait – shawamit. Ibnu Jinni has formulated “harakat”(wowel in Arabic language and dimension of letter  mad and liyn on alif  letter - waw - ya’ (ا و ي, from these letters create  harakat fathah, dammah, and kasrah. Moreover, in this writing also exist the description of hija’i letters and its makhraj that are correct from parts of mouth and the unity of coordinative sounds that produce sounds in morphemes arrangement, in one word that produces meaning. The result of phonological study has divided al-ashwat to be kinds of sound like the pronounced sounds, produced sounds from mouth, and heard sound.

  1. AL-IZDIWAJIYYAH AL-LUGHOWIYAH FII ISTIHDHAMI AL-LUGHOH AL-‘ARABIYAH

    Directory of Open Access Journals (Sweden)

    Imam Muslimin

    2011-10-01

    Full Text Available Al-Izdiwajiyyah (diglosia is standardizing a specific language when there are two variants of language that live side by side in societal life and each variant has its own social function. Disglosia is related to the use of local languages variations of low language and high language in a community. In Arabic language, disglosia covers dialects among the speakers, for instance there are two variants of language that each has roles and functions. The use of the variant depends on the situation. The most important characteristic of diglosia is specifying the functions of wach language variant. For high level language variant is aimed for formal situations such as religious ceremony, lectures, news, or editorials of newspaper. On the contrary, the low level language variant is commonly used in less formal situation such as daily communication in the family, chat with friends, stories in radion, and folk literature. In Arabic language, diglosia can be identified when the speaker of the language use diction commonly used for daily communication (amiyah in a formal expression (fusha, and vice versa.

  2. Al versus Si competition in FeSiAl alloys

    Energy Technology Data Exchange (ETDEWEB)

    Legarra, E. [Dpto. Electricidad y Electronica, Facultad de Ciencia y Tecnologia, Universidad del Pais Vasco (UPV/EHU), CP 644, 48080 Bilbao (Spain)], E-mail: estibaliz.legarra@ehu.es; Apinaniz, E. [Dpto. Fisica Aplicada I, Escuela de Ingenieria Tecnica Superior, Universidad del Pais Vasco, Alameda de Urquijo s/n 48013 Bilbao (Spain); Plazaola, F. [Dpto. Electricidad y Electronica, Facultad de Ciencia y Tecnologia, Universidad del Pais Vasco (UPV/EHU), CP 644, 48080 Bilbao (Spain); Jimenez, J.A. [Centro Nacional de Investigaciones Metalurgicas (CENIM), Avda. Gregorio del amo 8, 28040 Madrid (Spain); Pierna, A.R. [Chemical Engineering and Environmental Department, UPV/EHU, Box 1379, 20008 San Sebastian (Spain)

    2008-10-15

    In FeSiAl alloys, when Si substitutes for Al, important changes take place in the magnetism as well as in the structural properties. Alloys in the two composition series Fe{sub 75}Al{sub 25-x}Si{sub x} (x=0, 7.5, 12.5, 17.5, 25) and Fe{sub 70}Al{sub 30-x}Si{sub x} (x=0, 9, 15, 21, 30) were prepared by induction melting; afterwards they were crushed and then annealed in order to recover the DO{sub 3} stable phase. The deformed FeAl samples show larger lattice parameters than the ordered ones; however, this difference ({delta}a) decreases when Si substitutes for Al until it becomes zero (i.e. until the ordered samples and the deformed ones have the same lattice parameters). This trend is the same for both sample series and does not depend on the Fe content of the alloy. However, the magnetization has a different behaviour depending on the Fe content. For deformed Fe{sub 75}Al{sub 25-x}Si{sub x} alloys the saturation magnetization decreases with increasing Si content while for Fe{sub 70}Al{sub 30-x}Si{sub x} deformed alloys the saturation magnetization has a plateau in which the saturation magnetization values do not vary.

  3. Undulators at the ALS

    International Nuclear Information System (INIS)

    At Lawrence Berkeley Laboratory's (LBL) Advanced Light Source (ALS), three 4.6 m long undulators have been completed, tested and installed. A fourth is under construction. The completed undulators include two 5.0 cm period length, 89 period devices (U5.0s) which achieve a 0.85 T effective field at a 14 mm minimum gap and a 8.0 cm period length, 55 period device (U8.0) that reaches a 1.2 T effective field at a 14 mm minimum gap. The undulator under construction is a 10.0 cm period length, 43 period device (U10.0) that is designed to achieve 0.98 T at a 23 mm gap. Undulator magnetic gap variation (rms) is within 25 microns over the periodic structure length. Reproducibility of the adjustable magnetic gap has been measured to be within +/- 5 microns. Gap adjusting range is from 14 mm to 210 mm, which can be scanned in one minute. The 5.1 m long vacuum chambers are flat in the vertical direction to within 0.74 mm and straight in the horizontal direction to within 0.08 mm over the 4.6 m magnetic structure sections. Vacuum chamber base pressures after UHV beam conditioning are. in the mid 10-11 Torr range and storage ring operating pressures with full current are in the low 10-10 Torr range. Measurements show that the uncorrelated magnetic field errors are 0.23%, and 0.20% for the two U5.Os and the U8.0 respectively and that the field integrals are small over the 1 cm by 6 cm beam aperture. Device description, fabrication, and measurements are presented

  4. Alexandria (Al Iskandariya), Egypt

    Science.gov (United States)

    2002-01-01

    This image of Alexandria was taken by astronauts on board the International Space Station in December 2000 using an Electronic Still Camera. A wider-angle view (STS088-739-90) taken from the Space Shuttle in December 1998 is available for context. Alexandria (Al Iskandariya) occupies a T-shaped peninsula and strip of land separating the Mediterranean from Lake Mariout. Originally the town was built upon a mole (stone breakwater) called Heptastadium, which joined the island of Pharos (see referenced website, below) to the mainland. Since then sedimentary deposits have widened the mole. Since 1905, when the 370,000 Alexandrians lived in an area of about 4 sq km between the two harbors, the city (population 4 million; see referenced website, below) has grown beyond its medieval walls and now occupies an area of about 300 sq km. The Mahmudiya Canal, connecting Alexandria with the Nile, runs to the south of the city and, by a series of locks, enters the harbor of the principal port of Egypt (note ships). The reddish and ochre polygons west of Lake Mariout are salt-evaporation, chemical-storage, and water-treatment ponds within the coastal lagoon. Reference Youssef Halim and Fatma Abou Shouk, 2000, Human impacts on Alexandria's marine environment: UNESCO, Coastal Regions and Small Islands Unit (CSI), Coastal Management Sourcebooks 2 (accessed December 20, 2000) Additional photographs taken by astronauts can be viewed at NASA-JSC's Gateway to Astronaut Photography of Earth. Image ISS001-ESC-5025 provided by the Earth Sciences and Image Analysis Laboratory, Johnson Space Center.

  5. Thermal Modeling of Al-Al and Al-Steel Friction Stir Spot Welding

    Science.gov (United States)

    Jedrasiak, P.; Shercliff, H. R.; Reilly, A.; McShane, G. J.; Chen, Y. C.; Wang, L.; Robson, J.; Prangnell, P.

    2016-09-01

    This paper presents a finite element thermal model for similar and dissimilar alloy friction stir spot welding (FSSW). The model is calibrated and validated using instrumented lap joints in Al-Al and Al-Fe automotive sheet alloys. The model successfully predicts the thermal histories for a range of process conditions. The resulting temperature histories are used to predict the growth of intermetallic phases at the interface in Al-Fe welds. Temperature predictions were used to study the evolution of hardness of a precipitation-hardened aluminum alloy during post-weld aging after FSSW.

  6. KWIN nu ook als app

    NARCIS (Netherlands)

    Rotgers, G.; Vermeij, I.

    2014-01-01

    KWIN, Kwantitatieve Informatie Veehouderij, verscheen de afgelopen 25 jaar als lijvig handboek, zowel op papier als digitaal. Dit najaar is daar een serie apps bij gekomen, waarmee adviseurs en veehouders zelf saldo- en kostprijsberekeningen kunnen maken. De apps zijn beschikbaar voor de pluimvee-,

  7. Philosophieren als Unterrichtsprinzip im Mathematikunterricht

    Science.gov (United States)

    Meerwaldt, Diana

    Philosophieren und Mathematik scheinen zunächst gegensätzliche Bereiche zu sein, die sich kaum vereinbaren lassen. Dies trifft für eine Auffassung zu, die Philosophieren als "Gerede" disqualifiziert und Mathematik als eine reine "Formelwissenschaft" begreift. Beide Auffassungen werden den Gegenständen nicht gerecht.

  8. El miedo al rey

    Directory of Open Access Journals (Sweden)

    François FORONDA

    2007-01-01

    Full Text Available La peur du roi. Sources et premières réflexions à propos d’une émotion aristocratique dans la Castille du XIVe siècleFace à un roi qui à présent pousse les effets de son ire jusqu’au meurtre pour faire le vide autour de lui et imposer sa différence souveraine, ses parents et les riches hommes, soit les principaux visés par cette politique de l’arbitraire qui enfreint les règles du jeu autant qu’elle contribue à les redéfinir, disent la peur (metus qu’ils ressentent, qu’ils utilisent aussi afin de donner à leur stratégie de pouvoir un fondement légitime. Et l’expression de cette émotion politique, qui tend à se muer en un stéréotype d’un discours aristocratique d’opposition, surtout présente dans les chroniques, mises ici en relation ici avec d’autres sources, notamment des correspondances, marque profondément l’histoire des relations souvent conflictuelles au sein de cette compagnie en définitive très étroite pendant un siècle, de la fin du XIIIe siècle à la fin du XIVe siècle. Cet article se propose d’ébaucher une première réflexion sur le sujet et d’en présenter les principales sources.El miedo al rey. Fuentes y primeras reflexiones acerca de una emoción aristocrática en la Castilla del siglo XIVFrente a un rey que ahora lleva hasta la muerte los efectos de su ira para hacer el vacío entorno a su persona e imponer su soberana, sus parientes y ricos hombres, o sea los principales afectados por esta política de la arbitrariedad que rompe las reglas del juego a la vez que contribuye a redefinirlas, dicen el miedo (metus que sienten, que utilizan también para darle a su estrategia de poder un fundamento legítimo. Y la expresión de esta emoción política, que tiende a convertirse en un estereotipo de un discurso aristocrático de oposición, sobre todo presente en la crónicas, aquí puestas en relación con otras fuentes, en particular cartas, marca profundamente la historia de

  9. Quantum dots formed in InSb/AlAs and AlSb/AlAs heterostructures

    Science.gov (United States)

    Abramkin, D. S.; Rumynin, K. M.; Bakarov, A. K.; Kolotovkina, D. A.; Gutakovskii, A. K.; Shamirzaev, T. S.

    2016-06-01

    The crystal structure of new self-assembled InSb/AlAs and AlSb/AlAs quantum dots grown by molecularbeam epitaxy has been investigated by transmission electron microscopy. The theoretical calculations of the energy spectrum of the quantum dots have been supplemented by the experimental data on the steady-state and time-resolved photoluminescence spectroscopy. Deposition of 1.5 ML of InSb or AlSb on the AlAs surface carried out in the regime of atomic-layer epitaxy leads to the formation of pseudomorphically strained quantum dots composed of InAlSbAs and AlSbAs alloys, respectively. The quantum dots can have the type-I and type-II energy spectra depending on the composition of the alloy. The ground hole state in the quantum dot belongs to the heavy-hole band and the localization energy of holes is much higher than that of electrons. The ground electron state in the type-I quantum dots belongs to the indirect X XY valley of the conduction band of the alloy. The ground electron state in the type-II quantum dots belongs to the indirect X valley of the conduction band of the AlAs matrix.

  10. Consoer et al PFOS dataset

    Data.gov (United States)

    U.S. Environmental Protection Agency — This ScienceHub entry was developed for the published paper: Consoer et al., 2016, Toxicokinetics of perfluorooctane sulfonate in rainow trout (Oncorhynchus...

  11. EKSKURSO AL CANGYAN-MONTO

    Institute of Scientific and Technical Information of China (English)

    Verkita; de; Li; Shijun

    1999-01-01

    La Pekina Esperanto-Asocio preskaǚ sta-rigis tradicion organizi ekskurson printempe kajaǚtune. En la pasinta jaro, ni ekskursis al In-terna Mongolio kaj habis agrablajn renkontiojnkun geesperantistoj en Huhehot kaj Baotou. i-

  12. DESAFÍOS AL ORDEN

    Directory of Open Access Journals (Sweden)

    Evangelina De los Rios

    2012-03-01

    Full Text Available Fradkin, Raúl y Gelman, Jorge (Compiladores, Desafíos al Orden. Política y sociedades rurales durante la Revolución de Independencia, Prohistoria ediciones, Rosario, 2008, 157 pp.

  13. Seltzer_et_al_2016

    Data.gov (United States)

    U.S. Environmental Protection Agency — This dataset supports the modeling study of Seltzer et al. (2016) published in Atmospheric Environment. In this study, techniques typically used for future air...

  14. Information als Gegenstand von Informationskompetenz

    OpenAIRE

    Ingold, Marianne

    2011-01-01

    Der Informationsbegriff als zentraler Gegenstand von Informationskompetenz wird in der bibliothekarischen Diskussion in der Regel nicht explizit thematisiert, sondern lässt sich aus Fachliteratur und Bibliothekspraxis nur implizit erschließen. Eine theoretische Beschäftigung mit dem Informationsbegriff ist jedoch unabdingbar, soll das Konzept "Informationskompetenz" auch außerhalb des bibliothekarischen Kontextes verständlich und nutzbar gemacht werden. Im vorliegenden Text, der sich als Beit...

  15. Influence of Y, Gd and Sm on the glass forming ability and thermal crystallization of aluminum based alloy; Efeito das terras raras Y, Gd e Sm na tendencia a formacao de amorfo e na cristalizacao termica em ligas a base de aluminio

    Energy Technology Data Exchange (ETDEWEB)

    Aliaga, L.C.R.; Bolfarini, C.; Kiminami, C.S.; Botta Filho, W.J., E-mail: aliaga@ufscar.b [Universidade Federal de Sao Carlos (DEMa/UFSCar), SP (Brazil). Dept. de Engenharia de Materiais; Danez, G.P. [Universidade Federal de Sao Carlos (PPG-CEMUFSCar), SP (Brazil). Programa de Pos-Graduacao em Ciencia e Engenharia de Materiais

    2010-07-01

    Al-based amorphous alloys represent an important family of metals and a great scientific activity has been devoted to determine the main features of both glass forming ability (GFA) and crystallization behavior in order to have a comprehensive framework aimed at potential technological applications. Nowadays, it is well known that the best Al-based amorphous alloys are formed in ternary systems such as Al- RE-TM, where RE is a rare earth and TM a transition metal. This paper presents results of research in Al{sub 85}Ni{sub 10}RE{sub 5} alloys (RE = Y, Gd and Sm). Amorphous ribbons were processed by melt-spinning under the same conditions and subsequently characterized by x-ray diffraction (XRD) and differential scanning calorimetry (DSC). Results show appreciable micro structural differences as function of the rare earth, thus crystal is obtained for Y, nano-glassy for Gd and, fully amorphous structure for Sm. (author)

  16. Strain sensing with sub-micron sized Al-AlOx-Al tunnel junctions

    OpenAIRE

    Koppinen, P. J.; Lievonen, J. T.; Ahlskog, M.; Maasilta, I. J.

    2009-01-01

    We demonstrate a local strain sensing method for nanostructures based on metallic Al tunnel junctions with AlOx barriers. The junctions were fabricated on top of a thin silicon nitride membrane, which was actuated with an AFM tip attached to a stiff cantilever. A large relative change in the tunneling resistance in response to the applied strain (gauge factor) was observed, up to a value 37. This facilitates local static strain variation measurements down to ~10^{-7}.

  17. Al clamor de les vuvuzeles

    Directory of Open Access Journals (Sweden)

    Javier Olivera Betrán

    2010-09-01

    Full Text Available El Mundial de Futbol de Sud-àfrica ha situat l’Àfrica al mapa mundial i ha mostrat al món el triomf de l’estil de futbol d’Espanya basat en la col·lectivitat, l’esperit d’equip, la humilitat, la cohesió interna i el joc bonic. L’organització africana, seriosa i eficaç, ha sabut mobilitzar i il·lusionar la població del país que ha participat en el mundial des de l’orgull de ser africà, amb l’esperit alegre, festiu i també reivindicatiu de la gent de l’Àfrica. Aquest esdeveniment suposa el llançament de la marca “Sud-àfrica” al món amb un avís clar d’optar a l’organització d’uns primers Jocs Olímpics a Àfrica (potser els de 2020. S’obre una finestra d’esperança al segle xxi per al continent perdut de la mà de l’esport espectacle tan universal, massiu, emocional i mercantil que també es juga a la canxa de la política i de l’economia.

  18. A united refinement technology for commercial pure Al by Al-10Ti and Al-Ti-C master alloys

    International Nuclear Information System (INIS)

    Because flake-like TiAl3 particles in Al-Ti-C master alloys prepared in a melt reaction method dissolve slowly when they are added into Al melt at 720 deg. C, Ti atoms cannot be released rapidly to play the assistant role of grain refinement, leading to a poor refinement efficiency of Al-Ti-C master alloys. A united refinement technology by Al-10Ti and Al-Ti-C master alloys was put forward in this paper. The rational combination of fine blocky TiAl3 particles in Al-10Ti and TiC particles in Al-Ti-C can improve the nucleation rate of α-Al. It not only improves the grain refinement efficiency of Al-Ti-C master alloys, but also reduces the consumption

  19. Conjuntivitis alérgica

    Directory of Open Access Journals (Sweden)

    Alejandro Tello Hernández

    2008-07-01

    Full Text Available La conjuntivitis alérgica es una de las causas más comunesde consulta externa en oftalmología y tiene una muy altarelación con las reacciones alérgicas sistémicas. Lafisiopatología de las reacciones de hipersensibilidad noshace entender los cuadros clínicos característicos de estapatología y sus diferentes grados de severidad. Eldiagnostico diferencial es amplio, sin embargo hay clavesdiagnosticas que nos orientan rápidamente al diagnosticocorrecto. El tratamiento se enfoca en las medidasfarmacológicas y no farmacológicas, utilizándolas enconjunto para disminuir la recurrencia del cuadro y prevenirsecuelas visuales.

  20. Electrowinning Al from Al2S3 in Molten Salt

    NARCIS (Netherlands)

    Xiao, Y.; Van der Plas, D.W.; Bohte, J.; Lans, S.C.; Van Sandwijk, A.; Reuter, M.A.

    2007-01-01

    In order to investigate an alternative process for the production of primary aluminum via a sulfide intermediate, the electrochemical behavior of Al2S3 in molten salt has been studied on a laboratory scale. The effects of electrolyte composition, temperature, and cell design on the cell performance

  1. ALS:A SAIRASTAVAN TOIMINTATERAPIA

    OpenAIRE

    Vuorinen, Johanna

    2013-01-01

    Amyotrofinen lateraali skleroosi on harvinainen, etenevä sairaus. Sairaus surkastuttaa edetessään potilaan tahdonalaisen lihaksiston. Sairauden oireet näkyvät yleensä ensin raajoissa, mutta myös nielun lihaksista alkava bulbaarinen taudinmuoto on mahdollinen. ALS voi myös aiheuttaa frontotemporaalista dementiaa. Sairaus etenee yksilöllisesti, mutta sen kesto on yleensä noin 3-5 vuotta. Keski-Suomen keskussairaalassa ALS:n sairastuneen kuntoutukseen osallistuu moniammatillinen työryhmä, j...

  2. Al-Qaeda Since 911

    OpenAIRE

    Brahimi, Alia

    2012-01-01

    Seconds after smiling at her local MP and shaking his hand, Roshonara Choudhry plunged a knife into his stomach. The attack on Stephen Timms in May 2010 was not the most high profile assault inspired by al- Qaeda, nor was it fatal. It did, however, offer a commentary on the changing nature of the terrorist threat since 9/11, al-Qaeda’s major impact on international relations as well as its major failure, and the intimate, perhaps inevitable, connection between the two.

  3. Utilización del mineral de manganeso (pirolusita) en la producción de aceros al carbono

    OpenAIRE

    Aerles Batista-Cabrera; Efraín Navas-Medina

    2003-01-01

    Los métodos tradicionales de producción de acero utilizan el ferromanganeso para obtener el porcentaje de Mn en la marca establecida según la norma cubana, pero este compuesto es altamente costoso. Se ensayó, en la producción del Ac 35, sustituir el ferromanganeso por el mineral pirolusita (MnO2) con el fin de reducir los costos. Se evaluaron dos variantes de sustitución: la primera consiste en añadir el mineral con virutas de aluminio y coque (o residuos de electrodos) sobre la escoria del m...

  4. Andalusian astronomy: al-Zij al-Muqtabis of Ibn al-Kammâd.

    Science.gov (United States)

    Chabás, J.; Goldstein, B. R.

    1994-12-01

    In the twelfth century the Arabic astronomer Ibn al-Kammâd, living in Islamic Spain, composed three sets of astronomical tables, called "zijes". The zijes were largely based on the work of predecessors, going back to Ptolemy on the one hand, and Hindu astronomers on the other. None of his zijes survived in the original Arabic, but a Latin manuscript contains a translation of an apparently complete zij, the "al-Zij al-Muqtabis". This paper examines the body of astronomical knowledge contained in this zij. Specifically, it is shown that one can gain valuable information on the solar theory of the Islamic astronomers from this translation. Furthermore, the theory of lunar and solar eclipses in the work is analyzed, and tables of mean planetary and solar motions are discussed. In addition, tables for the motion of the vernal equinox, star tables, and several topics of Islamic spherical astronomy are examined.

  5. ¿COLOMBIA DEBE APOSTARLE AL SOFTWARE LIBRE, AL DE FUENTE ABIERTA O AL PROPIETARIO?

    Directory of Open Access Journals (Sweden)

    Luis Alberto Girón Murillo

    2014-06-01

    Full Text Available Es complejo para gestores y administradores conocer las implicaciones que la adopción de modelos de desarrollo de software tendría para una región. Este artículo ofrece una evaluación de las implicaciones dinámicas que para el desarrollo de software de una región tendría el apostar de forma excluyente al software libre, al software de fuente abierta y al software propietario. Se desarrolló un modelo de simulación en Vensim de la dinámica de sistemas en donde se evaluaron 3 escenarios: uno en donde se adopta de forma excluyente el software libre, uno en donde se adopta el software propietario y uno en donde se adopta el software de fuente abierta. Se ofrecen descripciones y explicaciones de los resultados que sugieren las potencialidades de cada uno de los modelos de desarrollo evaluados.

  6. Dynamic Modeling of ALS Systems

    Science.gov (United States)

    Jones, Harry

    2002-01-01

    The purpose of dynamic modeling and simulation of Advanced Life Support (ALS) systems is to help design them. Static steady state systems analysis provides basic information and is necessary to guide dynamic modeling, but static analysis is not sufficient to design and compare systems. ALS systems must respond to external input variations and internal off-nominal behavior. Buffer sizing, resupply scheduling, failure response, and control system design are aspects of dynamic system design. We develop two dynamic mass flow models and use them in simulations to evaluate systems issues, optimize designs, and make system design trades. One model is of nitrogen leakage in the space station, the other is of a waste processor failure in a regenerative life support system. Most systems analyses are concerned with optimizing the cost/benefit of a system at its nominal steady-state operating point. ALS analysis must go beyond the static steady state to include dynamic system design. All life support systems exhibit behavior that varies over time. ALS systems must respond to equipment operating cycles, repair schedules, and occasional off-nominal behavior or malfunctions. Biological components, such as bioreactors, composters, and food plant growth chambers, usually have operating cycles or other complex time behavior. Buffer sizes, material stocks, and resupply rates determine dynamic system behavior and directly affect system mass and cost. Dynamic simulation is needed to avoid the extremes of costly over-design of buffers and material reserves or system failure due to insufficient buffers and lack of stored material.

  7. Un controesempio al Modus Ponens

    Directory of Open Access Journals (Sweden)

    Vann McGee

    2011-11-01

    Full Text Available La traduzione dell’articolo è stata resa possibile grazie al consenso dell’autore e del Journal of Philosophy. Riferimenti originali: Vann McGee (1985: “A Counterexample to Modus Ponens”, Journal of Philosophy, Vol. 82, No. 9 (Sep. 1985, pp. 462-47. [N.d.T.

  8. Derecho humano al agua y al saneamiento: derechos estrechamente vinculados al derecho a la vida

    OpenAIRE

    Fernández Aller, Maria Celia; Luis Romero, Elena de; Guzmán Acha, Cristina

    2013-01-01

    Los derechos humanos al agua y al saneamiento están íntimamente relacionados con otros derechos esenciales para la vida, como la alimentación o la salud. Su reconocimiento como derechos humanos en 2010 marca un hito importante en el respeto, protección y realización de estos derechos, que se encuentran seriamente vulnerados para una mayoría de población más vulnerable y empobrecida, sobre todo en el ámbito rural. Mucho camino queda aún para conseguir no sólo la disponibilidad de agua y saneam...

  9. First principles calculation of ac conductance for Al-BDT-Al and Al-Cn-Al systems

    Directory of Open Access Journals (Sweden)

    Jia-Ning Zhuang

    2011-12-01

    Full Text Available We perform first-principles calculation to investigate the dynamic conductance of atomic wires of the benzenedithiol (BDT as well as carbon chains with different length in contact with two Al(100 electrodes (Al-Cn-Al. Our calculation is based on the combination of the non-equilibrium Green's function and the density functional theory. For ac conductance, there are two theories that ensures the current conservation: (1. the global formula which is a phenomenological theory that partitions the total displacement current into each leads so that the current is conserved.(2. the local formula which is a microscopic theory that includes Coulomb interaction explicitly so that the current is conserved automatically. In this work, we use the local formula to calculate the dynamic conductance, especially the emittance. We give a detailed comparison and analysis for the results obtained from two theories. Our numerical results show that the global formula overestimates the emittance by two orders of magnitude. We also obtain an inequality showing that the emittance from global formula is greater than that from local formula for real atomic structures. For Al-Cn-Al structures, the oscillatory behavior as the number of carbon chain N varies from even to odd remains unchanged when local formula is used. However, the prediction of local formula gives rise to opposite response when N is odd (inductive-like as compared with that of global formula. Therefore, one should use the local formula for an accurate description of ac transport in nanoscale structures. In addition, the ‘size effect’ of the ac emittance is analyzed and can be understood by the kinetic inductance. Since numerical calculation using the global formula can be performed in orbital space while the local formula can only be used in real space, our numerical results indicate that the calculation using the local formula is extremely computational demanding.

  10. Personalidad y tolerancia al dolor

    Directory of Open Access Journals (Sweden)

    JESÚS M.ª CARRILLO

    2005-01-01

    Full Text Available Se examina la relación de algunas variables de personalidad -EPQ-A (Eysenck y Eysenck, 1975, NEO-PI (McCrae y Costa, 1988 y STA -personalidad esquizotípica- y STB -personalidad límite-, de Claridge y Broks (1984, con la tolerancia al dolor experimental inducido mediante agua fría (cold pressor test, según el procedimiento de Staats, Heckmat y Staats (1998 en una muestra filtrada mediante un cuestionario sobre dolor crónico, dolores de cabeza, de espalda, artritis, síndrome de Raynaud, y personas bajo medicación. La tolerancia al dolor experimental se evaluó mediante el Umbral del dolor (tiempo en segundos desde la introducción de la mano en el agua hasta el primer informe de dolor, Mantenimiento del dolor (duración en segundos de la inmersión de la mano desde la aparición del umbral hasta su retirada y Tolerancia al dolor (duración total en segundos de la inmersión de la mano desde su introducción hasta su retirada. Un análisis correlacional, factorial y de regresión por pasos mostraron un efecto cruzado entre medidas de ansiedad (tolerancia negativa al dolor y psicoticismo, siendo psicoticismo junto con control emocional predictores de tolerancia positiva al dolor. En cuanto a psicoticismo, parece que son sus elementos de naturaleza paranoide y de "dureza" los que afectan a una percepción atenuada del dolor.

  11. 76 FR 38700 - United States, et al.

    Science.gov (United States)

    2011-07-01

    ... Antitrust Division United States, et al. v. American Express Company, et al.; Public Comments and Response...), the United States hereby publishes below its Response to public comments received on the proposed Final Judgment in United States, et al. v. American Express Company, et al., Civil Action No....

  12. Large rectification magnetoresistance in nonmagnetic Al/Ge/Al heterojunctions.

    Science.gov (United States)

    Zhang, Kun; Li, Huan-Huan; Grünberg, Peter; Li, Qiang; Ye, Sheng-Tao; Tian, Yu-Feng; Yan, Shi-Shen; Lin, Zhao-Jun; Kang, Shi-Shou; Chen, Yan-Xue; Liu, Guo-Lei; Mei, Liang-Mo

    2015-09-21

    Magnetoresistance and rectification are two fundamental physical properties of heterojunctions and respectively have wide applications in spintronics devices. Being different from the well known various magnetoresistance effects, here we report a brand new large magnetoresistance that can be regarded as rectification magnetoresistance: the application of a pure small sinusoidal alternating-current to the nonmagnetic Al/Ge Schottky heterojunctions can generate a significant direct-current voltage, and this rectification voltage strongly varies with the external magnetic field. We find that the rectification magnetoresistance in Al/Ge Schottky heterojunctions is as large as 250% at room temperature, which is greatly enhanced as compared with the conventional magnetoresistance of 70%. The findings of rectification magnetoresistance open the way to the new nonmagnetic Ge-based spintronics devices of large rectification magnetoresistance at ambient temperature under the alternating-current due to the simultaneous implementation of the rectification and magnetoresistance in the same devices.

  13. Al/Au/n-Si/Al surface barrier detector

    International Nuclear Information System (INIS)

    Charged-particle detectors are required to be operated sometimes in ambient light for applications like alpha counting and range finding. Detectors like Al/p-Si surface barrier with aluminium on the front side are found quite suitable. Gold/n-Si surface barrier detectors are not usable because of their excessive background photo current. These detectors, we fabricate for use in nuclear experiments, were given an aluminium coating on their gold side for use in room light. The Au/n-Si/Al surface barrier diodes were characterized for their electrical properties and performance as alpha detectors. Detectors showing good energy resolution (∼ 50 KeV) were selected and provided with another thin reflecting coat of aluminium on their front sides

  14. Al-Anon and recovery.

    Science.gov (United States)

    Cermak, T L

    1989-01-01

    The history of Al-Anon and its current demographics are reviewed. In order to understand 12-step recovery and psychotherapy for family members of alcoholics, the concept of codependence is defined with a set of diagnostic criteria consistent with the DSM-III-R definition of personality traits and disorders. At the core of codependence are denial and an unrealistic relationship to willpower. The therapeutic implications of considering codependence as a personality disorder are explored, as are the characteristics that make codependence unique among personality disorders: the central role of denial and the existence of a self-help organization to facilitate recovery. The dynamics of working the 12 steps on codependent characteristics are outlined. A synergistic relationship between psychotherapy and the 12 steps is described. Special attention is given the emergence of Al-Anon adult children of alcoholic meetings, and the future of codependence is discussed.

  15. Sui controesempi al Modus Ponens

    Directory of Open Access Journals (Sweden)

    Giorgio Sbardolini

    2011-11-01

    Full Text Available In McGee (1985 si presentano tre controesempi al modus ponens (MP, e si argomenta di come esistano restrizioni alla validità di questa regola deduttiva. Nel presente articolo, intendo ridiscutere questi tre controesempi a MP mostrando perché non colgono il bersaglio, e presentare altri casi in cui l'applicazione di MP non sembra efficace.In [McGee, 1985] si presentano 3 controesempi al modus ponens (MP, e si argomenta di come esistano restrizioni alla validità di questa regola deduttiva. Nel presente articolo, intendo ridiscutere questi 3 controesempi a MP mostrando perché non colgono il bersaglio, e presentare altri casi in cui l'applicazione di MP non sembra efficace.

  16. Al Margen de las Cooperativas

    Directory of Open Access Journals (Sweden)

    Gutiérrez Estrada Julio

    1941-04-01

    Full Text Available El sistema Cooperativista, propiamente hablando, no viene a constituir una doctrina económica, es más bien una práctica, un modo de proceder en provecho de determinada agrupación de individuos que se asocian para defenderse de la usura del comercio y del intermediarismo parasitario. "El movimiento cooperativo es tan viejo como la revolución industrial, y ha crecido paralelamente a ella, podría decirse como una protesta en contra del sistema capitalista industrial. Generalmente se considera que tres principios fundamentales determinan su carácter distintivo. 1-Se esfuerza por dar "servido al costo" a sus miembros antes que beneficiarse del negocio con el público en general. El servicio de un grupo organizado se considera como un medio para obtener el máximum de eficacia con mínimo de desperdicio. 2-Insiste en que los beneficios pecuniarios se distribuyan al miembro como productor, después de deducir solamente el interés del capital al tipo que compite, y los salarios y jornales de los trabajadores. 3-Mantiene el control democrático del negocio por todos los participantes en él".

  17. Vormundschaftsrecht als Grundlage politischer Herrschaft

    Directory of Open Access Journals (Sweden)

    Arne Duncker

    2006-07-01

    Full Text Available In ihrer beachtlichen und sehr gewissenhaft dokumentierten Arbeit über vormundschaftliche Regentschaften im 16. und 17. Jahrhundert beschreibt Pauline Puppel unter ausführlichem Bezug auf zeitgenössische Literatur und Archivalien sowohl die allgemeine Rechtslage im damaligen Reich als auch die Anwendungsfälle in Hessen, wo zwischen 1500 und 1700 insgesamt viermal eine Landgräfin als Vormünderin des Fürsten zur Regentin ihres Landes wurde. Dies steht exemplarisch für eine bereits in der Frühen Neuzeit mögliche und nicht einmal ganz seltene Form politischer Frauenherrschaft, die bisher oft nicht hinreichend gewürdigt wurde. Puppels Untersuchung ist in zwei Hauptteile gegliedert. Der erste Teil (Das juristische Regelwerk“, S. 34-143 behandelt die zeitgenössischen Rahmenbedingungen der durch Frauen ausgeübten Vormundschaft und Regentschaft. Der zweite Abschnitt („Die Landgräfinnen von Hessen als Regentinnen“, S. 144-307 befasst sich mit der Ausfüllung dieser Regeln durch konkrete Fallbeispiele in Gestalt von Leben und Regentschaft der regierenden Landgräfinnen von Hessen.

  18. Microstructure of interaction interface between Al-Si, Zn-Al alloys and Al2O3p/6061Al composite

    Institute of Scientific and Technical Information of China (English)

    许志武; 闫久春; 吕世雄; 杨士勤

    2004-01-01

    Interaction behaviors between Al-Si, Zn-AI alloys and Al2O3p/6061AI composite at different heating temperatures were investigated. It is found that Al2O3p/6061Al composite can be wetted well by AlSi-1, AlSi-4 and Zn-Al alloys and an interaction layer forms between the alloy and composite during interaction. Little Al-Si alloys remain on the surface when they fully wet the composite and Si element in Al-Si alloy diffuses into composite entirely and assembles in the composite near the interface of Al-Si alloy/composite to form a Si-rich zone. The microstructure in interaction layer with Si penetration is still dense. Much more residual Zn-Al alloy exists on the surface of composite when it wets the composite, and porosities appear at the interface of Zn-Al alloy/composite. The penetration of elements Zn, Cu of Zn-Al alloy into composite leads to the generation of shrinkage cavities in the interaction layer and makes the microstructure of Al2 O3p/6061A1 composite loose.

  19. Armaflex in Burj al Arab; Armaflex im Burj al Arab

    Energy Technology Data Exchange (ETDEWEB)

    Steiner, B.

    2003-07-01

    This article describes the Burj al Arab in Dubai, the unique seven-star high-rise hotel. The construction of the hotel, that is built on 250 piles driven into the sand of an artificial island in the Persian Gulf, is described. In particular, various special materials used in the building are described, as are the luxurious fittings and furnishings of the hotel. The cooling and air-conditioning installations that are necessary as a result of the desert climate of Dubai are described and the use of 'Armaflex' elastomer insulating material for the insulation of refrigeration machines and cold-water piping is discussed.

  20. Memahami Tasawuf Ibnuu Arabi dan Ibnuu al Farid: Konsep al Hubb Illahi, Wahdat al Wujud, Wahdah al Syuhud dan Wahdat al Adyan

    Directory of Open Access Journals (Sweden)

    Muhammad Robith Fuadi

    2013-12-01

    Full Text Available Kaum sufi menapaki jalan yang berbeda untuk menuju hakikat, mereka tidak menggunakan akal dan rasio untuk sampai pada hakikat. Akan tetapi, akal bukan satu-satunya jalan untuk menuju hakikat. Karena kita sering melihat sesuatu yang di luar jangkauan akal dalam hidup ini. Jalan yang ditempuh kaum sufi untuk menuju hakikat seperti kasyf, dzauq, 'iyan, musyahadah dan sebagainya dinilai sebagai sesuatu yang samar, tidak mempunyai batasan dan kaidah pasti, bahkan sering kali bercampur dengan igauan, mimpi, khayalan dan angan-angan. Tapi yang perlu kita ingat adalah bahwa media-media tersebut telah mampu menuntun manusia untuk memecahkan sesuatu yang tidak bisa dipecahkan oleh akal dan hukum-hukum fisika. Tulisan ini akan mengkaji gagasan-gagasan dua tokoh tasawuf besar yaitu Ibnu Arabi dan Ibnu al-Farid yang hidup  pada abad keenam dan ketujuh Hijriah. Tulisan ini secara spesifik akan mengkaji tiga gagasan penting ke dua tokoh tersebut. Yaitu al hubb al Ilahi, wahdat al Wujud dan wahdat al adyan.

  1. Electrical conductivity of (Na3AlF6-40%K3AlF6)-AlF3-Al2O3 melts

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The effects of contents of AlF3 and Al2O3,and temperature on electrical conductivity of (Na3AlF6-40%K3AlF6)-AlF3-Al2O3 were studied by continuously varying cell constant (CVCC) technique.The results show that the conductivities of melts increase with the increase of temperature,but by different extents.Every increasing 10 ℃ results in an increase of 1.85×10-2,1.86×10-2,1.89×10-2 and 2.20×10-2 S/cm in conductivity for the (Na3AlF6-40%K3AlF6)-AlF3 melts containing 0%,20%,24%,and 30% AlF3,respectively.An increase of every 10 ℃ in temperature results an increase about 1.89×10-2,1.94×10-2,1.95×10-2,1.99×10-2 and 2.10×10-2 S/cm for (Na3AlF6-40%K3AlF6)-AlF3-Al2O3 melts containing 0%,1%,2%,3% and 4% A12O3,respectively.The activation energy of conductance was calculated based on Arrhenius equation.Every increasing 1% of AlF3 results in a decrease of 0.019 and 0.020 S/cm in conductivity for (Na3AlF6-40%K3AlF6)-AIF3 melts at 900 and 1 000 ℃,respectively.Every increase of 1% Al2O3 results in a decrease of 0.07 S/cm in conductivity for (Na3AlF6-40%K3AlF6)-AlF3-Al2O3 melts.The activation energy of conductance increases with the increase in content of AlF3 and Al2O3.

  2. United modification of Al-24Si alloy by Al-P and Al-Ti-C master alloys

    Institute of Scientific and Technical Information of China (English)

    韩延峰; 刘相法; 王海梅; 王振卿; 边秀房; 张均艳

    2003-01-01

    The modification effect of a new type of Al-P master alloy on Al-24Si alloys was investigated. It is foundthat excellent modification effect can be obtained by the addition of this new type of A1-P master alloy into Al-24Simelt and the average primary Si grain size is decreased below 47 μm from original 225 μm. It is also found that theTiC particles in the melt coming from Al8Ti2C can improve the modification effect of the Al-P master alloy. Whenthe content of TiC particles in the Al-24Si melt is 0.03 %, the improvement reaches the maximum and keeps steadywith increasing content of TiC particles. Modification effect occurs at 50 min after the addition of the Al-P master al-loy and TiC particles, and keeps stable with prolonging holding time.

  3. Ce对Al-Si-Cu合金中α(Al)-Al2Cu共晶形貌的影响%Effect of Ce on morphology ofα(Al)-Al2Cu eutectic in Al-Si-Cu alloy

    Institute of Scientific and Technical Information of China (English)

    Maja VONINA; Joef MEDVED; Tonica BONINA; Franc ZUPANI

    2014-01-01

    The effect of Ce addition on the morphology of the α(Al)-Al2Cu eutectic in Al-Si-Cu alloy was investigated using thermal analysis, light microscopy, scanning electron microscopy, focused ion beam and energy dispersive analysis. The results show that the eutectic α(Al)-Al2Cu forms within small space between dendrites, silicon and AlSiFeMn plates. Eutectic Al2Cu is not lamellar but degenerated. However, Al2Cu in Ce-modified alloys is more compact. Ce partially dissolves in Al2Cu, which is a viable reason for the formation of coarser Al2Cu. The addition of Ce also increases the microhardness of theα(Al)-Al2Cu eutectic by almost 10%compared with the basic Al-Si-Cu alloy.%采用热分析、光学显微镜技术、扫描电镜技术、聚焦离子束和能量色散谱分析方法研究Ce对Al-Si-Cu合金中α(Al)-Al2Cu共晶形貌的影响。结果表明,在枝晶、硅和AlSiFeMn之间较小空间内形成了α(Al)-Al2Cu共晶。Al2Cu为非层状的不规则共晶组织。Al2Cu在经Ce改性的合金中更加致密。部分Ce溶解于Al2Cu中,这是粗晶Al2Cu形成的原因。与基体Al-Si-Cu合金相比,Ce的加入能使α(Al)-Al2Cu共晶合金的显微硬度提高约10%。

  4. Electrocoagulación aplicada al tratamiento de efluentes generadospor empresas de mantenimiento de motores.

    OpenAIRE

    Alicia Guevara; Ernesto de la Torre; Eliana Manangon

    2011-01-01

    La electrocoagulación es una operación que desestabiliza una emulsión y permite altos porcentajes de remoción de demanda química de oxígeno (DQO) y turbiedad. En el presente trabajo se evaluó la electrocoagulación como técnica de tratamiento no convencional de efluentes generados por empresas de Mantenimiento de motores y para la evaluación de la operación se midieron los parámetros: DQO, tensoactivos, sólidos suspendidos y totales, turbiedad y concentración de aluminio, cobre y cinc. El eflu...

  5. Reply to Pachai et al.

    Science.gov (United States)

    Harrison, William J; Bex, Peter J

    2016-05-01

    Peripheral vision is fundamentally limited by the spacing between objects. When asked to report a target's identity, observers make erroneous reports that sometimes match the identity of a nearby distractor and sometimes match a combination of target and distractor features. The classification of these errors has previously been used to support competing 'substitution' [1] or 'averaging' [2] models of the phenomenon known as 'visual crowding'. We recently proposed a single model in which both classes of error occur because observers make their reports by sampling from a biologically-plausible population of weighted responses within a region of space around the target [3]. It is critical to note that there is no probabilistic substitution or averaging process in our model; instead, we argue that neither substitution nor averaging occur, but that these are misclassifications of the distribution of reports that emerge when a population response distribution is sampled. This is a fundamentally different way of thinking about crowding, and on this basis we claim to have provided a mechanism unifying categorically distinct perceptual errors. Our goal was not to model all crowding phenomena, such as the release from crowding when target and flanks differ in color or depth [4]. Pachai et al.[5] have suggested that our model is not unifying because it inaccurately predicts perceptual performance for a particular stimulus. Although we agree that our model does not predict their data, this specific demonstration overlooks the critical aspect of the model: perceptual reports are drawn from a weighted population code. We show that Pachai et al.'s [5] own data actually provide evidence for the population code we have described [3], and we suggest a biologically-plausible analysis of their stimuli that provides a computational basis for their 'grouping' account of crowding.

  6. Reply to Pachai et al.

    Science.gov (United States)

    Harrison, William J; Bex, Peter J

    2016-05-01

    Peripheral vision is fundamentally limited by the spacing between objects. When asked to report a target's identity, observers make erroneous reports that sometimes match the identity of a nearby distractor and sometimes match a combination of target and distractor features. The classification of these errors has previously been used to support competing 'substitution' [1] or 'averaging' [2] models of the phenomenon known as 'visual crowding'. We recently proposed a single model in which both classes of error occur because observers make their reports by sampling from a biologically-plausible population of weighted responses within a region of space around the target [3]. It is critical to note that there is no probabilistic substitution or averaging process in our model; instead, we argue that neither substitution nor averaging occur, but that these are misclassifications of the distribution of reports that emerge when a population response distribution is sampled. This is a fundamentally different way of thinking about crowding, and on this basis we claim to have provided a mechanism unifying categorically distinct perceptual errors. Our goal was not to model all crowding phenomena, such as the release from crowding when target and flanks differ in color or depth [4]. Pachai et al.[5] have suggested that our model is not unifying because it inaccurately predicts perceptual performance for a particular stimulus. Although we agree that our model does not predict their data, this specific demonstration overlooks the critical aspect of the model: perceptual reports are drawn from a weighted population code. We show that Pachai et al.'s [5] own data actually provide evidence for the population code we have described [3], and we suggest a biologically-plausible analysis of their stimuli that provides a computational basis for their 'grouping' account of crowding. PMID:27166690

  7. The Al-Al3Ni Eutectic Reaction: Crystallography and Mechanism of Formation

    Science.gov (United States)

    Fan, Yangyang; Makhlouf, Makhlouf M.

    2015-09-01

    The characteristics of the Al-Al3Ni eutectic structure are examined with emphasis on its morphology and crystallography. Based on these examinations, the mechanism of formation of this technologically important eutectic is postulated. It is found that a thin shell of α-Al forms coherently around each Al3Ni fiber. The excellent thermal stability of the Al-Al3Ni eutectic may be attributed to the presence of this coherent layer.

  8. Formaline of alternatieven als ontsmettingsmiddel voor broedeieren

    OpenAIRE

    Meijerhof, R.; Dijk, D. van

    1997-01-01

    Formaline wordt algemeen gezien als een goed middel om broedeieren te ontsmetten. Toch geeft ontsmetting met middelen als ozon en waterstofperoxyde vaak een iets beter broedresultaat. Een eventuele verklaring hiervoor is momenteel nog niet te geven.

  9. Grainreifnementlimit of commercialpureAl inoculatedbyAl-Ti-C(B)masteralloys

    Institute of Scientific and Technical Information of China (English)

    En-zhao Wang; Xiang-fa Liu

    2015-01-01

    The grain reifnement limits of commercial pure Al inoculated by Al-5Ti-1B, Al-5Ti-0.25C and Al-5Ti-0.3C-0.2B master al oys were studied, and the inlfuence of melting temperature on the grain reifning performance of these three master al oys was investigated using a high scope video microscope (HSVM), a ifeld-emission scanning electron microscope (FESEM), an electron probe micro-analyzer (EPMA) and X–ray diffraction (XRD) method. Results show that there is a grain reifnement limit of commercial pure Al reifned by these three master al oys; with the same addition level of 1.5% under the present experimental conditions, the grain reifnement limits (smal est average grain size) of commercial pure Al reifned by Al-5Ti-1B, Al-5Ti-0.25C and Al-5Ti-0.3C-0.2B master al oys are 50 µm, 80 µm and 80 µm, respectively. In addition, with an increase in the melting temperature of the pure Al, the grain reifning performance of Al-5Ti-1B and Al-5Ti-0.25C master al oys decreases, but the grain reifning performance of Al-5Ti-0.3C-0.2B changes little.

  10. Betaalde arbeid als verdringer van vrijwilligerswerk? Overbelasting als mogelijke verklaring

    Directory of Open Access Journals (Sweden)

    Angela Kok-Van Meer

    2014-06-01

    Full Text Available Do paid work activities displace volunteering? A potential explanation from role overload theoryRecent changes in Dutch society might lead to a shortage of volunteers. On the one hand, the demand for volunteers is increasing: in the social welfare domain because of governmental austerity policies and in other domains such as sports because of the higher supervision intensity of activities. On the other hand, the supply of volunteers is likely to decrease as more and more women and older workers are active in the labor market, which reduces the time that is available for volunteering. Role overload theory would suggest that the increasing labor participation rate of certain categories of workers goes along with a decline of participation in voluntary work. The secondary data analysis shows that various role loads (work, care for children living at home are associated with differences in participation in voluntary work. However, while a higher number of contractual work hours and hours spent on work-related training are negatively associated with volunteer work, care for children living at home is positively associated with volunteering. These results provide only limited support for role overload theory.Betaalde arbeid als verdringer van vrijwilligerswerk? Overbelasting als mogelijke verklaringDe afgelopen jaren hebben zich enkele maatschappelijke veranderingen voorgedaan, die wellicht tot schaarste op de Nederlandse vrijwilligersmarkt zouden kunnen leiden. Enerzijds neemt de vraag naar vrijwilligers toe doordat subsidieregelingen versoberen (bijvoorbeeld in zorg en welzijn en de begeleidingsintensiteit in bepaalde organisaties stijgt (bijvoorbeeld in sport. Anderzijds neemt het aanbod van vrijwilligers af doordat vrouwen en ouderen meer en langer op de arbeidsmarkt actief zijn, waardoor minder tijd beschikbaar is voor vrijwilligerswerk. In dit artikel wordt aan de hand van de role overload theorie nagegaan of het al dan niet deelnemen aan

  11. AlON-SiAlON复合材料的制备及特性%Preparation and properties of AlON-SiAlON composites

    Institute of Scientific and Technical Information of China (English)

    山下敬; 山口明良

    2003-01-01

    为提高AlON陶瓷材料的抗氧化性能,制备了AlON-SiAl7O2N7复相材料.在1750℃、0.5 MPa的N2气氛中,保温2 h烧成不同Al2O3/AlN/Si3N4配比的原料得到不同AlON/SiAl7O2N7比的复相材料.因为在烧结SiAl7O2N7的过程中,蒸发-凝聚的同时伴随着SiO气体的挥发,因此很难得到致密的AlON-SiAl7O2N7复相材料.研究了AlON-SiAl7O2N7复相材料在1300℃、空气中的抗氧化性能,同时作为比较,研究了相同条件下单相的AlON材料的抗氧化性能.结果表明,AlON-SiAl7O2N7复相材料显示了较之单相的AlON陶瓷材料更好的抗氧化性能,这是因为氧化过程中所形成的含玻璃相的表面氧化层抑制了氧的向内扩散所致.

  12. con bajo peso al nacer

    Directory of Open Access Journals (Sweden)

    Adriana Mora Antó

    2005-01-01

    Full Text Available Esta investigación dio cuenta de la relación entre el estilo de funcionamiento familiar, los patrones de crianza y las edades de desarrollo evolutivo en niños, nacidos con bajo peso. El estudio descriptivo correlacional se realizó con 41 niños y sus madres, aplicándose cuestionarios sobre funcionamiento familiar, prácticas de crianza y desarrollo infantil. Los resultados señalaron la existencia de un funcionamiento familiar caracterizado por una cohesión amalgamada y una adaptabilidad caótica, una disciplina complaciente, falta de control y de límites claros en la díada madre-hijo. Se trataba de familias monoparentales, donde la temprana edad de concepción, el madresolterismo y el apoyo de la familia extensa eran constantes. Las edades evolutivas registradas indicaron un desarrollo inferior a la edad cronológica, en la mayor parte de los casos; sin embargo, éstas tendieron a ser superiores al compararlas con la edades reales de los infantes. No se encontró una correlación estadísticamente significativa entre la edad de desarrollo y los diferentes factores del funcionamiento familiar para algunos de los rangos de edad considerados; sin embargo, no se lo descartó por completo, especialmente en lo referente al optimismo familiar

  13. Topiramat als Phasenprophylaktikum - ein Fallbericht

    Directory of Open Access Journals (Sweden)

    Letmaier M

    2001-01-01

    Full Text Available Topiramat ist ein neues Antiepileptikum mit einem breiten Wirkspektrum. Aktuelle klinische Studien geben Hinweise darauf, daß Topiramat stimmungsstabilisierende Eigenschaften besitzt und somit effizient in der Behandlung der bipolaren affektiven Störung sein könnte. Vor dem Hintergrund dieser Studienberichte, behandelten wir eine 41jährige, erstmals vor 10 Jahren erkrankte Patientin mit der Diagnose einer therapierefraktären, bipolaren affektiven Störung (Rapid-Cycling mit Topiramat. Im Rahmen ihrer Erkrankung wurde die Patientin insgesamt 12mal stationär aufgenommen und meist aufgrund von akuten manischen Episoden behandelt. Dabei kamen seit 1991 folgende Phasenprophylaktika zur Anwendung: Carbamazepin, Valproat und Lamotrigin ? zuletzt nur mit mäßigem Erfolg. Daraufhin wurde zu Beginn einer neuerlichen manischen Episode ambulant eine Therapie mit Topiramat begonnen. Acht Wochen nach Therapiestart kam die Patientin in stationäre Behandlung. Der Aufenthalt dauerte weniger als drei Wochen; Topiramat wurde von der Patientin gut vertragen. Infolge eines belastenden Lebensereignisses kam es unter kontinuierlicher Therapie mit Topiramat zu einer Destabilisierung des psychischen Zustandsbildes (manische Symptome. Durch eine ambulante Erhöhung der Topiramatdosis bei gleichzeitiger Gabe von Risperidon und Clonazepam konnte jedoch eine neuerliche manische Episode erstmals ambulant behandelt werden. Die Patientin erhält derzeit 200 mg Topiramat pro Tag und ist seit mehr als 20 Monaten nahezu beschwerdefrei.

  14. Nonstoichiometry of Al-Zr intermetallic phases

    Energy Technology Data Exchange (ETDEWEB)

    Radmilovic, V.; Thomas, G.

    1994-06-01

    Nonstoichiometry of metastable cubic {beta}{prime} and equilibrium tetragonal {beta} Al-Zr intermetallic phases of the nominal composition Al{sub 3}Zr in Al-rich alloys has been extensively studied. It is proposed that the ``dark contrast`` of {beta}{prime} core in {beta}{prime}/{sigma}{prime} complex precipitates, in Al-Li-Zr based alloys, is caused by incorporation of Al and Li atoms into the {beta}{prime} phase on Zr sublattice sites, forming nonstoichiometric Al-Zr intermetallic phases, rather than by Li partitioning only. {beta}{prime} particles contain very small amounts of Zr, approximately 5 at.%, much less than the stoichiometric 25 at.% in the Al{sub 3}Zr metastable phase. These particles are, according to simulation of high resolution images, of the Al{sub 3}(Al{sub 0.4}Li{sub 0.4}Zr{sub 0.2}) type. Nonstoichiometric particles of average composition Al{sub 4}Zr and Al{sub 6}Zr are observed also in the binary Al-Zr alloy, even after annealing for several hours at 600{degree}C.

  15. Electroplating Zn-Al Alloy Technology

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The method of controlling separating anode and separating power source was used to perform orthogonal optimization for the parameters in electroplating Zn-Al alloy.The electroplating Zn-Al alloy technology was decided, in which the content of Al is about 12%-15%.

  16. Cenomanian-Turonian biostratigraphy of the Jardas Al Abid area, Al Jabal Al Akhdar, northeast Libya

    Science.gov (United States)

    El Qot, Gamal M.; Abdulsamad, Esam O.

    2016-09-01

    The Upper Cenomanian-Turonian succession exposed at Jardas al'Abid area consists mainly of carbonates with siliciclastic intercalations. This succession is subdivided lithostratigraphically into: Qasr al'Abid (Late Cenomanian) and Al Baniyah (Late Cenomanian-Coniacian) formations. This sequence is relatively rich in macrofossil assemblages especially bivalves, gastropods, and echinoids with rare ammonites. Based on the first occurrence (FO) and last occurrence (LO) of some index species of these macrofossil groups, an integrated biostratigraphic framework has been constructed. The studied Cenomanian-Turonian sequence is subdivided biostratigraphically into three ammonite biozones; Pseudaspidoceras pseudonodosoides Total Range Zone, Choffaticeras segne Total Range Zone, and Coilopoceras requienianum Total Range Zone. Based on the rest of macrofossil assemblages other than the ammonites, eight biozones were recognized; Mecaster batnensis Total Range Zone, Ceratostreon flabellatum-Neithea dutrugei Acme Zone, Costagyra olisiponensis Acme Zone, Pycnodonte (Phygraea) vesicularis vesiculosa Acme Zone, Mytiloides labiatus Total Range Zone = Mecaster turonensis Acme Zone, Rachiosoma rectilineatum-Curvostrea rouvillei-Tylostoma (T.) globosum Assemblage Zone, Radiolites sp.-Apricardia? matheroni Total Range Zone, and Nerinea requieniana Total Range Zone. Most of the proposed biozones are recorded for the first time from Libya. The integration among these biozones as well as local and inter-regional correlation of the biozones have been discussed. The stage boundaries of the studied stratigraphic intervals are discussed, where the Cenomanian/Turonian boundary is delineated at the last occurrence (LO) of Pseudaspidoceras pseudonodosoides (Choffat), while the Turonian/Coniacian boundary is delineated arbitrary being agree with the LO of the Turonian fauna.

  17. Progresses in analyzing 26Al with SMCAMS

    International Nuclear Information System (INIS)

    Shanghai Mini-Cyclotron based Accelerator Mass Spectrometer (SMCAMS) was especially designed for analyzing 14C. In order to accelerate and analyze 26Al the accelerated orbit and beam optics in injection system were calculated and harmonic number and acceleration turns was optimized. Preliminary experiment was carried out. In which a beam current of 1.15 x 10-9A for 27Al- and 0.038 CPS background for 26Al were measured. The limited sensitivity of 26Al/27Al is 5.25 x 10-12. (authors)

  18. Trato verbal paterno al adolescente

    Directory of Open Access Journals (Sweden)

    Rodríguez Juan Carlos

    1995-06-01

    Full Text Available

    En alguna ocasión se ha escuchado una palabra, que causa un sentimiento y a la vez un recuerdo, que lleva a evocar la adolescencia o la infancia, se recuerda quien la pronunciaba y en que ocasión la decía. Este es el poder que tiene una palabra y más aún si es dicha por el padre, puesto que este es la figura significativa que se lleva en la memoria. De aquí nace el interés de realizar un estudio, en donde se describe y analice la percepción y el sentimiento del adolescente, quien en esta etapa es vulnerable al cambio, ya que está buscando su propia identidad; que con el trato verbal paterno la encontrara sin ninguna dificultad o por el contrario nunca la encontrará.

     

  19. Entscheidung als Häresie

    Directory of Open Access Journals (Sweden)

    Jaanus Sooväli

    2014-06-01

    Full Text Available Man könnte sagen, dass Aristoteles so etwas wie eine traditionelle und dominierende Auffassung der Entscheidung in der westlichen Philosophie gründet. Das Ziel dieses Aufsatzes ist es, diese Auffassung von Aristoteles zu entwerfen, einige ihrer wichtigsten Probleme anzusprechen, und sie damit zu kontrastieren, was ich Jacques Derridas häretische „Konzeptualisierung“ der Entscheidung nennen würde. Es wird gezeigt, dass diese häretische Thematisierung von Derrida nicht nur und einfach mit dem traditionellen aristotelischen Begriff bricht, sondern vielmehr auch zu Recht einige seiner wichtigsten Züge auf solcher Weise schärft, dass von diesem radikalisierten Standpunkt die Behandlung von Aristoteles als die Annullierung der Entscheidung zum Vorschein kommt. Es wird zudem impliziert, wie Derridas häretische Auffassung die Erneuerung der Ethik und Politik mit sich bringt.

  20. STUDY OF THE Al/GRAPHITE INTERFACE

    Institute of Scientific and Technical Information of China (English)

    LU HUA(陆华); SHEN DIAN-HONG(沈电洪); DENG XIN-FA(邓新发); XUE QI-KUN(薛其坤); N.FROUMIN; M.POLAK

    2001-01-01

    Thin Al films with a thickness of 20-30nm were prepared by ltra-high vacuum deposition of Al onto a graphite surface arallel to a (0001) basal plane. The samples were annealed up to 1070K. X-ray photoelectron spectroscopy analysis has shown that for temperatures just higher than 770K, a little carbide occurs in the Al film and only an AI-C phase is present at the Al/graphite interface. After nnealing at 970K, the Al4C3 phase can be observed, and the binding energy of the Al2p electrons increases continuously from 72.7 to 74.2eV with increasing temperature up to 1070K. Auger electron spectroscopy depth profiles are measured to investigate the phases existing in the Al film as well as at the Al/graphite interface. It is found that the Al4C3 hase at the interface is the final product of a series of Al carbides from the interfacial reaction between Al and graphite.

  1. AlON粉体的合成

    Institute of Scientific and Technical Information of China (English)

    赵小军; 茹红强; 张宁; 孙有政

    2009-01-01

    以α-Al2O3和AlN为原料,利用高温固相反应在氮气气氛下常压合成了AlON粉体。研究了成分配比、合成温度、保温时间对合成AlON粉体含量的影响,并通过热分析测试了合成过程热流和质量的变化。结果表明,当原料Al2O3和AlN的质量比为81:18、合成工艺为1750℃,2h时,得到AlON相的含量达到95%以上。

  2. Preparation and Characterization of Highly Flexible Al2O3/Al/Al2O3 Hybrid Composite

    Directory of Open Access Journals (Sweden)

    Zhijiang Wang

    2015-01-01

    Full Text Available The natural brittleness of oxide ceramics heavily inhibits their more extensive applications. In present research, a highly flexible Al2O3/Al/Al2O3 hybrid composite was fabricated by employing plasma electrolysis oxidation to in situ grow alumina layers on Al foil, in which an outside layer of nanostructured polycrystalline oxide ceramic was composed of nanosized grains with the size of around 17 nm. Due to shear band formation, nanosized circle bubbles prolonging the crack path, grain rotation, and deformation, the fabricated Al2O3/Al/Al2O3 hybrid composite contains no observable cracks even after being bent on a cylindrical bar with a curvature of 1.5 mm. The composite exhibits alumina stiffness at the elastic stage and aluminum ductility during plastic deformation, which provides high flexibility with the well-integrated properties of the components. In a synergistic interaction, the alumina on the outside exhibited a strain of 0.33% at room temperature, which was higher than optimum value of 0.25% presented by reported most flexible oxide ceramics. With the unique characteristics and properties, the Al2O3/Al/Al2O3 composite demonstrates a great potential for various engineering applications.

  3. MARTENSITIC TRANSFORMATION AND THERMAL STABILITY IN Cu-Al-Co AND Cu-Al-Zr ALLOYS

    Institute of Scientific and Technical Information of China (English)

    Y. Q. Ma; C.B. Jiang; H.B. Xu

    2003-01-01

    Cu-Al-Co and Cu-Al-Zr alloys were explored with Co or Zr additions in Cu-Al alloys for high temperature shape memory alloys. Samples were quenched after homogenized at 850℃ for 48h. It was found that both Cu-Al-Co and Cu-Al-Zr show AlCu3 martensitic phase at room temperature and exhibit martensitic transformation temperatures higher than 200℃, showing the potentials for developing as high temperature shape memory alloys. Thermal cycles were performed by DSC instrument on both Cu-Al-Co and Cu-Al-Zr alloys. The results show that Cu-Al-Co loses its martensitic transformation after five thermal cycles, and Cu-Al-Zr exhibits no martensitic transformation in the second thermal cycle.

  4. Friction Stir Welding of Al 5052 with Al 6061 Alloys

    Directory of Open Access Journals (Sweden)

    N. T. Kumbhar

    2012-01-01

    Full Text Available Friction stir welding (FSW, a solid-state joining technique, is being extensively used in similar as well as dissimilar joining of Al, Mg, Cu, Ti, and their alloys. In the present study, friction stir welding of two aluminium alloys—AA6061 and AA5052—was carried out at various combinations of tool rotation speeds and tool traverse speeds. The transverse cross-section of the weld was used for optical as well as electron microscopy observations. The microstructural studies were used to get an indication of the extent of material mixing both at the macro- and microscales. It was observed that, at the interface region, both materials exhibited similar texture despite the nonrigorous mixing of the materials in the nugget. The extent of interdiffusion of alloying elements at the interface was studied using electron probe microanalysis. The tensile testing evaluation of these specimens showed good mechanical properties. The interdiffusion of alloying elements and development of similar orientations in the nugget could have contributed to the better tensile properties of the friction-stir-welded AA5052-AA6061 specimens.

  5. Efficiency droop in high-Al-content AlGaN/AlGaN quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Tamulaitis, G.; Mickevicius, J.; Kazlauskas, K.; Zukauskas, A. [Institute of Applied Research and Department of Semiconductor Physics, Vilnius University, Sauletekio 9-III, 10222 Vilnius (Lithuania); Shur, M.S. [Department of ECE and CIE, Rensselaer Polytechnic Institute, 110 Eighth Street, Troy, NY 12180 (United States); Yang, J.; Gaska, R. [Sensor Electronic Technology Inc., 1195 Atlas Road, Columbia, SC 29209 (United States)

    2011-07-15

    Excitation power density dependence of photoluminescence (PL) efficiency is studied in the temperature range from 8 to 300 K for AlGaN multiple quantum well structures containing quantum wells of different width. PL efficiency droop is observed and dependence of the droop effect on the well width and lattice temperature is discussed. Photoluminescence band shape reveals strong carrier heating. It is shown that the heating effect has a substantial influence on the photoluminescence efficiency droop, especially at low lattice temperatures. Fitting of the temperature dependence of the PL band width with that obtained by the Monte Carlo simulation of carrier (exciton) hopping via localized states shows that (i) the potential fluctuations can be fairly accurately described using a double-scaled potential profile model, (ii) the localization becomes stronger in narrower quantum wells. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  6. Atomic structure and oxygen deficiency of the ultrathin aluminium oxide barrier in Al/AlOx/Al Josephson junctions

    OpenAIRE

    Lunjie Zeng; Dung Trung Tran; Cheuk-Wai Tai; Gunnar Svensson; Eva Olsson

    2016-01-01

    Al/AlOx/Al Josephson junctions are the building blocks of a wide range of superconducting quantum devices that are key elements for quantum computers, extremely sensitive magnetometers and radiation detectors. The properties of the junctions and the superconducting quantum devices are determined by the atomic structure of the tunnel barrier. The nanoscale dimension and disordered nature of the barrier oxide have been challenges for the direct experimental investigation of the atomic structure...

  7. Al-Si/Al2O3 in situ composite prepared by displacement reaction of CuO/Al system

    Directory of Open Access Journals (Sweden)

    Zhang Jing

    2010-02-01

    Full Text Available Al2O3 particle-reinforced ZL109 composite was prepared by in situ reaction between CuO and Al. The microstructure was observed by means of OM, SEM and TEM. The Al2O3 particles in sub-micron sizes distribute uniformly in the matrix, and the Cu displaced from the in situ reaction forms net-like alloy phases with other alloy elements. The hardness and the tensile strength of the composites at room temperature have a slight increase as compared to that of the matrix. However, the tensile strength at 350 ℃ has reached 90.23 MPa, or 16.92 MPa higher than that of the matrix. The mechanism of the reaction in the CuO/Al system was studied by using of differential scanning calorimetry(DSC and thermodynamic calculation. The reaction between CuO and Al involves two steps. First, CuO reacts with Al to form Cu2O and Al2O3 at the melting temperature of the matrix alloy, and second, Cu2O reacts with Al to form Cu and Al2O3 at a higher temperature. At ZL109 casting temperature of 750–780 ℃, the second step can also take place because of the effect of exothermic reaction of the first step.

  8. Heat losses estimation associated with the physical state of the thermal insulation of pipes vaporductos network in Cerro Prieto geothermal field; Estimacion de perdidas de calor asociadas al estado fisico del aislamiento termico de las tuberias de la red de vaporductos del campo geotermico Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Ovando Castelar, Rosember; Martinez Estrella, Juan Ignacio; Garcia Gutierrez, Alfonso [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: rovando@iie.org.mx; jime@iie.org.mx; aggarcia@iie.org.mx; Canchola Felix, Ismael; Miranda Herrera, Carlos; Jacobo Galvan, Paul [Campo Geotermico de Cerro Prieto, Comision Federal de Electricidad, Mexicali, B.C. (Mexico)

    2010-11-15

    The Cerro Prieto Geothermal Field (CPGF) steam transportation network is constituted by 140 km of pipes with diameters ranging from 8 to 48 inches, which transport the steam of 165 producing wells to 13 power plants which have a total installed capacity of 720 MWe. Originally, the pipes are thermally insulated with a mineral wool or fiber glass layer and an external aluminum or iron cover. Due to the insulation material has been exposed to weather conditions during the field operation it shows nowadays different grades of wear-out, or even it is lacking in some parts of the network, causing higher heat losses from the pipes to the environment. In this work, the magnitude of the heat losses related with the present condition of the thermal insulation throughout the pipeline network is assessed. This involved determining the longitude and diameter, as well as the insulation condition of each single pipeline section, and the calculation of the heat transfer coefficients for the different thermal insulation conditions defined for this study. [Spanish] La red de transporte de vapor del campo geotermico Cerro Prieto (CGCP) esta constituida por aproximadamente 140 km de tuberias de 8 a 48 pulgadas de diametro, las cuales conducen el vapor producido por 165 pozos hacia 13 plantas generadoras, cuya capacidad instalada es de 720 MWe. Originalmente, estas tuberias son aisladas termicamente con una capa de 2 pulgadas de material aislante a base de lana mineral o fibra de vidrio, y una proteccion exterior de aluminio o hierro. Debido principalmente al impacto de las condiciones meteorologicas durante el tiempo de operacion del campo, en algunas porciones de la red el aislante presenta actualmente distintos grados de deterioro, o incluso se encuentra ausente, lo cual se traduce en una mayor perdida de calor desde las tuberias hacia el medio ambiente. En el presente trabajo se evalua la magnitud de las perdidas de calor asociadas al estado fisico del aislamiento termico de las

  9. Study for obtaining a suppressor device of transients using the Al/SRO/Si structure; Estudio para la obtencion de un dispositivo supresor de transitorios utilizando la estructura Al/SRO/Si

    Energy Technology Data Exchange (ETDEWEB)

    Marin Ramos, Heriberto

    1999-06-01

    The circuits and electronic equipment use protective devices against voltage transients. In this work the Aluminium/Oxide structure rich in Silicon/Silicon is presented as another option in the field of transient suppressors devices. Some devices used in the suppression of voltage transients are: zinc oxide varistors, of silicon carbide varistors, selenium cells, and Zener diodes. The Al/SRO/Si structure presents conductive properties due to the presence of excess Silicon in the SRO film. Varying the reacting gases ratio (Ro=N{sub 2}O/SiH{sub 4}) during the growth of the film of Oxide Rich in Silicon (SRO), the conductivity of the material can be varied. The SRO turns out to be of great importance for the suppressor device of transients device that is pretended to be obtained in the present work due to its non-ohmic behavior. The Al/SRO/Si device behaves of several ways depending on the characteristics of the SRO and the silicon substrate. It has been found that one of these behaviors is as a of voltage transients suppressor. Verifying its behavior as transient suppressor, the effects of the film thickness, the area and the excess of silicon of the device were studied, for this purpose the characteristic I-V was obtained, and the obtention of some parameters in DC. In the present work the SRO was obtained by means of LPCVD (Low Pressure Chemical Vapor Deposition), initially a C-V characterization was made to obtain an indicative parameter of excess silicon, such as: permittivity of the SRO film. Also, the refraction index was obtained, which is an indicative parameter of the presence of excess Silicon. Once having the certainty of the presence of excess silicon it was proceed to obtain the I-V characteristic of the Al/SRO/Si structure as a device. The behavior of the Al/SRO/Si structure was analyzed with different parameters, such as: Ro, thickness of the SOR, areas. [Spanish] Los circuitos y equipos electronicos utilizan dispositivos de proteccion contra

  10. Entrevista al narrador Tommaso Pincio

    Directory of Open Access Journals (Sweden)

    Franco Zangrilli

    2016-07-01

    Full Text Available El autor Tommaso Pincio, seudónimo di Marco Colapietro (Roma, 1963, es sin lugar a dudas uno de los narradores de mayor proyección en el panorama literario de los últimos tiempos. Iniciada su carrera en 1999 con M., ha publicado títulos como Lo spazio sfinito (2000 y Un amore dell'altro mondo (2002, en el que narra la vida de Kurt Cobain, líder del grupo Nirvana, a través de la visión de un amigo imaginario. A estas dos novelas siguieron La ragazza che non era lei (2005, Gli alieni (2006 o Cinacittà. Memorie del mio delitto efferato (2008, ambientada en una Roma colonizada por los chinos y abandonada por los mismos romanos a causa de problemas medioambientales. Títulos como L'hotel a zero stelle (2011, un ensayo autobiográfico en el que plantea diálogos ficticios con algunos de los grandes nombres de la literatura o la más reciente Panorama (2015, le han hecho valerse un hueco provilegiado entre los nuevos narradores surgidos en estas primeras décadas de siglo. Justamente la publicación de esta última novela, Panorama, ha servido de excusa al profesor Franco Zangrilli, gran conocedor de su obra, a plantearle algunas preguntas sobre temas clave de su producción.

  11. Fabrication of TiAl3 coating on TiAl-based alloy by Al electrodeposition from dimethylsulfone bath and subsequent annealing

    OpenAIRE

    Miyake, Masao; Tajikara, Seiya; Hirato, Tetsuji

    2011-01-01

    TiAl3 coating was formed on TiAl alloy by Al electrodeposition from a dimethylsulfone (DMSO2) bath and subsequent annealing. Before the Al electrodeposition, anodic dissolution of TiAl substrate in the DMSO2 bath was conducted to remove the surface oxide layer of the TiAl substrate. By performing the Al electrodeposition immediately after the anodic dissolution, uniform Al films adherent to the TiAl substrate could be obtained. Annealing at 650–1000 °C yielded a single TiAl3 layer or two laye...

  12. Fabrication of AlN-TiC/Al composites by gas injection processing

    Institute of Scientific and Technical Information of China (English)

    YU Huashun; CHEN Hongmei; MA Rendian; MIN Guanghui

    2006-01-01

    The fabrication of AlN-TiC/Al composites by carbon-and nitrogen-containing gas injection into Al-Mg-Ti melts was studied. It was shown that AlN and TiC particles could be formed by the in situ reaction of mixture gas (N2+C2H2+NH3) with Al-Mg-Ti melts. The condition for the formation of AlN was that the treatment temperature must be higher than 1373 K, and the amounts of AlN and TiC increased with the increase of the treatment temperature and the gas injection time.It was considered that AlN was formed by the direct reaction of Al with nitrogen-containing gas at the interface of the gas bubble and the melt. However, the mechanism of TiC formation is a combination mechanism of solution-precipitation and solid-liquid reaction.

  13. Orientation relationship of eutectoid FeAl and FeAl2

    Science.gov (United States)

    Scherf, A.; Kauffmann, A.; Kauffmann-Weiss, S.; Scherer, T.; Li, X.; Stein, F.; Heilmaier, M.

    2016-01-01

    Fe–Al alloys in the aluminium range of 55–65 at.% exhibit a lamellar microstructure of B2-ordered FeAl and triclinic FeAl2, which is caused by a eutectoid decomposition of the high-temperature Fe5Al8 phase, the so-called ∊ phase. The orientation relationship of FeAl and FeAl2 has previously been studied by Bastin et al. [J. Cryst. Growth (1978 ▸), 43, 745] and Hirata et al. [Philos. Mag. Lett. (2008 ▸), 88, 491]. Since both results are based on different crystallographic data regarding FeAl2, the data are re-evaluated with respect to a recent re-determination of the FeAl2 phase provided by Chumak et al. [Acta Cryst. (2010 ▸), C66, i87]. It is found that both orientation relationships match subsequent to a rotation operation of 180° about a 〈112〉 crystallographic axis of FeAl or by applying the inversion symmetry of the FeAl2 crystal structure as suggested by the Chumak data set. Experimental evidence for the validity of the previously determined orientation relationships was found in as-cast fully lamellar material (random texture) as well as directionally solidified material (∼〈110〉FeAl || solidification direction) by means of orientation imaging microscopy and global texture measurements. In addition, a preferential interface between FeAl and FeAl2 was identified by means of trace analyses using cross sectioning with a focused ion beam. On the basis of these habit planes the orientation relationship between the two phases can be described by (01)FeAl || (114) and [111]FeAl || [10]. There is no evidence for twinning within FeAl lamellae or alternating orientations of FeAl lamellae. Based on the determined orientation and interface data, an atomistic model of the structure relationship of Fe5Al8, FeAl and FeAl2 in the vicinity of the eutectoid decomposition is derived. This model is analysed with respect to the strain which has to be accommodated at the interface of FeAl and FeAl2. PMID:27047304

  14. Electron channelling enhanced microanalysis on Ni-Al-Mn and Al-Mn-Si

    International Nuclear Information System (INIS)

    Atom location by channelling enhanced microanalysis (ALCHEMI) was performed for Ni-Al-Mn compounds and Al-Mn-Si quasicrystals. For Ni75Al25-xMnx (x=5,9) with the L12-type structure, an occupation fraction of Mn atoms at the Ni site was quantitatively determined using planar channelling conditions. The occupation fraction increases with the Mn concentration or by quenching the compound from high temperature. In quasicrystals of Al74Mn20Si6 and Al68Mn20Ru8Si4, axial channelling conditions were used to locate Si and Ru, respectively. It was shown that Si atoms occupy the Al site in Al74Mn20Si6 whereas Ru atoms occupy the site different from that of Al in Al68Mn20Ru8Si4. (author)

  15. A New Phase in ALS Research.

    Science.gov (United States)

    Chong, P Andrew; Forman-Kay, Julie D

    2016-09-01

    In this issue of Structure, Conicella et al. (2016) present evidence that the low complexity C-terminal region of TDP-43 undergoes liquid-liquid phase separation. ALS-associated mutations alter this phase separation process, providing a possible mechanism for the pathology caused by these TDP-43 mutations. The work is strongly supportive of toxic loss of RNA processing function in ALS. PMID:27602988

  16. The wobbler mouse, an ALS animal model

    OpenAIRE

    Moser, Jakob Maximilian; Bigini, Paolo; Schmitt-John, Thomas

    2013-01-01

    This review article is focused on the research progress made utilizing the wobbler mouse as animal model for human motor neuron diseases, especially the amyotrophic lateral sclerosis (ALS). The wobbler mouse develops progressive degeneration of upper and lower motor neurons and shows striking similarities to ALS. The cellular effects of the wobbler mutation, cellular transport defects, neurofilament aggregation, neuronal hyperexcitability and neuroinflammation closely resemble human ALS. Now,...

  17. Casting fabrication of in situ Al3Ti-Al composites and their wear behaviors

    Institute of Scientific and Technical Information of China (English)

    Chen Tijun; Li Jian; Hao Yuan

    2009-01-01

    The Al3li intermetallic reinforced pure Al, Al-13Si and Al-17Cu matrix composites were prepared by casting method. Their microstructures and dry sliding wear behaviors at room temperature and 100℃ were particularly investigated. The results indicated that the Al3Ti phases in these composites were all in flaky form. But the aspect ratio of the Al3Ti platelets decreased with the increase of Ti content in the pure AI, Al-Cu and Al-Si matrix composites, in order of effectiveness. The effect of Si on the Al3Ti morphology seemed to be greater than that of Cu. The distributions of the Al3Ti platelets were different in the different matrix composites, leading to different grain refining effects. Except for the sub-wear regime of adhesive wear, the plastic deformation induced wear was a dominant wear mechanism for all of the composites at room temperature and 100℃. Increasing the testing temperature, decreasing the Al3Ti content or the hardness of materials could enhance these two wear mechanisms, and thus increase the wear rate. The Al-Cu matrix composite had the best wear resistance, while the pure Al matrix composite showed the worst for the same Ti content. These differences or changes were attributed to the differences in materials' hardness or the strengthening effects of the Al3Ti platelets.

  18. Observaciones microestructurales en el composite Al-SiC-15p obtenido por el procedimiento de compocolado

    Directory of Open Access Journals (Sweden)

    Manzano-Ramírez, A.

    1996-12-01

    Full Text Available In order to study how the processing variables of the compocasting process, such as shear rate and solid fraction, influence the mechanical entrapment of SiCp in the aluminium matrix of the Al-SiC-xxp composite. In the present work, shear rate and solid fraction were varied (γ = 27, 120 and 219 s-1 and fs = 0.3, 0.4 and 0.5, respectively. In addition, the atomic force microscope (AFM was used to investigate the surface topography of the composite, with the purpose of determine, qualitatively, the degree of interfacial bonding between aluminium matrix and reinforcement elements. By using the Chemical facilities of SEM it was attempted to determine the composition of the second phase responsible of bonding between matrix and particulate. The results obtained in the AFM confirmed that the mechanical entrapment of the particles by the solid is more efficient at high solid fractions (fs > 0.4 and high shear rates (γ > 120 s-1. In contrast, at low fs (< 0.3 and low γ (< 27 s-1 such effect is poor. In addition, qualitative evidence, recorded by optical micrographs, illustrate the mechanism of dendritic fragmentation and change (from dendritic to globular of the primary-solid phase in the compocasting process. SEM results suggested that bonding could be established through the silicon phase nevertheless it is considered that more accurate analysis is needed.

    El propósito del presente trabajo es estudiar el efecto de las variables del procedimiento de compocolado (compocasting, velocidad de agitación y fracción de sólido, sobre el atrapamiento mecánico o incorporación de partículas de SiC a la matriz de aluminio del composite Al-SiC-15p. Para ello, se variaron la velocidad de corte, γ, y la fracción de sólido fs, (γ= 27, 120 y 213 s-1 y fs = 0,3, 0,4 y 0,5, respectivamente. Se utilizó el microscopio de fuerza atómica (AFM para observar la topografía del

  19. Groente- en fruitafvallen als veevoer : inventarisatie

    NARCIS (Netherlands)

    Vries, de A.

    1982-01-01

    Een onderzoek wat betreft hoeveelheden, bewaring, samenstelling, verteerbaarheid en eventueel aanwezige ongewenste stoffen van de bij- en afvalprodukten van groenten en fruit als veevoer voor herkauwers

  20. Genetics of Familial and Sporadic ALS

    Science.gov (United States)

    2016-03-21

    Amyotrophic Lateral Sclerosis (ALS); Familial Amyotrophic Lateral Sclerosis; Amyotrophic Lateral Sclerosis With Frontotemporal Dementia; Lou Gehrig's Disease; Motor Neuron Disease; Primary Lateral Sclerosis

  1. Growth of CdTe: Al films

    International Nuclear Information System (INIS)

    CdTe: AI films were grown by the close space vapor transport technique combined with free evaporation (CSVT-FE). The Aluminum (Al) evaporation was made by two kinds of sources: one made of graphite and the other of tantalum. The films were deposited on glass substrates. The Al source temperature was varied maintaining the CdTe source temperature fixed as well as the substrate temperature. The films were characterized by x-ray energy dispersive analysis (EDAX), x-ray diffraction and optical transmission. The results showed for the films grown with the graphite source for Al evaporation, the Al did not incorporate in the CdTe matrix, at least to the level of EDAX sensitivity; they maintained the same crystal structure and band gap. For the samples grown with the tantalum source, we were able to incorporate the Al. The x-ray diffraction patterns show that the films have a crystal structure that depends on Al concentration. They were cubic up to 2.16 at. % Al concentration; for 19.65 at. % we found a mixed phase; for Al concentration higher than 21 at. % the films were amorphous. For samples with cubic structure it was found that the lattice parameter decreases and the band gap increases with Al concentration. (Author)

  2. Influence of Al Composition on the Microstructure of B Alloyed Ni3Al Synthesized under Compression

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    It was shown by TEM and X-ray analysis that Ni3Al is the mainphase of the intermetallic synthesized under compression from the powder mixture of Ni with Al alloyed by B. The Ni3B is a secondary phase. The value of the lattice parameter of the intermetallic Ni3Al with and without B increases when the concentration of Al increases. The increase in Al concentration from 23.5 to 25.0 in the initial powder mixture leads to decreasing the solubility of B in the Ni3Al phase.

  3. 关于w-al-CL空间%On w-al-CL Spaces

    Institute of Scientific and Technical Information of China (English)

    林丽琼; 张云南

    2011-01-01

    给出w-al-CL空间的定义,比较几种CL性的关系,讨论w-al-CL空间的c0和与l1和的稳定性,并讨论C(K,X)空间的w-al-CL性.%Gives the definition of w-al-CL spaces, compare the relationship of some properties of CL, discusses the stability of c0 -sums and l1 -sums of w-al-CL spaces, and discusses the property of w-al-CL of C(K,X) spaces.

  4. Response to Signorovitch et al.

    Science.gov (United States)

    Flot, Jean-François; Debortoli, Nicolas; Hallet, Bernard; Van Doninck, Karine

    2016-08-22

    Signorovitch et al.[1] comment that an Oenothera-like meiosis [2] could produce a pattern similar to what we observed in our study of natural isolates of the bdelloid rotifer Adineta vaga, which we attributed to horizontal gene transfers (HGTs) [3]. Indeed, our HGT hypothesis appears at first sight difficult to conciliate with their observation of a congruent pattern of allele sharing at four large loci possibly located on different chromosomes [4]. However, one might imagine conditions under which massive horizontal gene transfer between bdelloid individuals could produce such a pattern, notably if the individuals involved had previously lost most of their heterozygosity because of their exposure to frequent desiccation (which produces DNA double-strand breaks [5]). In the published A. vaga genome the loss of heterozygosity due to large-scale gene conversion events or break-induced replication covers only about 10% of the genome [6], but this percentage may be much higher in environmental isolates that often experience dessication. Besides, if an Oenothera-like mode of meiosis occurs in bdelloids frequently enough to be detected in a single sampling of 29 individuals (as in [4]), one would expect males and meiosis to be observed at least occasionally, and instances of congruent allele sharing across loci should turn up frequently in genetic surveys. This was not the case in [3]: among the 82 A. vaga individuals sequenced for four nuclear markers, no trio of individuals presented congruent patterns of shared sequences at different loci. For these reasons, and in the absence of any direct evidence for an Oenothera-like meiosis in bdelloids, we still consider inter-bdelloid HGTs a more parsimonious explanation for our results. PMID:27554651

  5. Atomic structure and oxygen deficiency of the ultrathin aluminium oxide barrier in Al/AlOx/Al Josephson junctions.

    Science.gov (United States)

    Zeng, Lunjie; Tran, Dung Trung; Tai, Cheuk-Wai; Svensson, Gunnar; Olsson, Eva

    2016-01-01

    Al/AlOx/Al Josephson junctions are the building blocks of a wide range of superconducting quantum devices that are key elements for quantum computers, extremely sensitive magnetometers and radiation detectors. The properties of the junctions and the superconducting quantum devices are determined by the atomic structure of the tunnel barrier. The nanoscale dimension and disordered nature of the barrier oxide have been challenges for the direct experimental investigation of the atomic structure of the tunnel barrier. Here we show that the miniaturized dimension of the barrier and the interfacial interaction between crystalline Al and amorphous AlOx give rise to oxygen deficiency at the metal/oxide interfaces. In the interior of the barrier, the oxide resembles the atomic structure of bulk aluminium oxide. Atomic defects such as oxygen vacancies at the interfaces can be the origin of the two-level systems and contribute to decoherence and noise in superconducting quantum circuits. PMID:27403611

  6. Atomic structure and oxygen deficiency of the ultrathin aluminium oxide barrier in Al/AlOx/Al Josephson junctions

    Science.gov (United States)

    Zeng, Lunjie; Tran, Dung Trung; Tai, Cheuk-Wai; Svensson, Gunnar; Olsson, Eva

    2016-07-01

    Al/AlOx/Al Josephson junctions are the building blocks of a wide range of superconducting quantum devices that are key elements for quantum computers, extremely sensitive magnetometers and radiation detectors. The properties of the junctions and the superconducting quantum devices are determined by the atomic structure of the tunnel barrier. The nanoscale dimension and disordered nature of the barrier oxide have been challenges for the direct experimental investigation of the atomic structure of the tunnel barrier. Here we show that the miniaturized dimension of the barrier and the interfacial interaction between crystalline Al and amorphous AlOx give rise to oxygen deficiency at the metal/oxide interfaces. In the interior of the barrier, the oxide resembles the atomic structure of bulk aluminium oxide. Atomic defects such as oxygen vacancies at the interfaces can be the origin of the two-level systems and contribute to decoherence and noise in superconducting quantum circuits.

  7. Kritik al-Ghazali terhadap Kekekalan Alam

    Directory of Open Access Journals (Sweden)

    Sahidi Mustafa

    2015-12-01

    Full Text Available The concept of the creation of universe offered by Neo-Platonism philosopher such as al-Kindi, al-Farabi, and Ibnu Sina are philosophical concept existed and came as an early moment of development of Islamic philosophy interrelated to God, ultimately about his Existence and Characteristics. One of the topics is how God created the universe. According to al-Farabi and Ibnu Sina, God created this universe by way of emanation in order to prevent Himself from the new attitudes. Consequently, universe has eternal feature (qadim as God as well, in the case of everything overflowed from qadim is also qadim. Al-Ghazali refuted this theory because it contradicted with al Qur’an’s thought which clearly explained that God created the entire universe. The universe should not qadim and it means that God existed in the first, and then created universe later as we know today. On the contrary, in the view of Muslim philosopher, the universe should be qadim because God created it from all eternity. For them, it is impossible that God existed by Himself without any creation before. God, according to them is impossible to be changed, so that is impossible as well if God changed from did not create yet before and then creates. Al-Ghazali persistently opposed the concept of eternity. Al Ghazali saw if this universe is qadim so it is impossible that universe created by God. The concept of qadim will led to the conclusion that universe born by itself, it was not created by God. This critique has been written by al-Ghazali in Tahafut al-Falasifah. This paper will present the concept of eternity which was discussed by al-Farabi and Ibn Sina and al Ghazali’s critique toward it as well.

  8. Untersuchung der Nitridierung V/Al-intermetallischer Phasen

    OpenAIRE

    Lewalter, Hartmut Berthold

    2004-01-01

    Schichten V/Al-Intermetallischer Phasen und Schichten aus V(Al) (Schichtdicken 150- 300 nm) wurden durch Interdiffusion von V/Al- und V5Al8/V-Mehrfachschichten bei 400-800°C im Vakuum bei 3 x 10-8 mbar hergestellt. Des Weiteren wurden V5Al8-Schichten durch Sputtern einer V5Al8-Legierung erzeugt. Die Gesamtstöchiometrie der Schichten lag zwischen Al0,86V0,14 und Al0,19V0,81. Als Substrat dienten einkristalline (012) Saphirwafer. Die V/Al-Intermetallischen Phasen und V(Al) wurden im RTP-System ...

  9. Influence of AlN thickness on AlGaN epilayer grown by MOCVD

    Science.gov (United States)

    Jayasakthi, M.; Juillaguet, S.; Peyre, H.; Konczewicz, L.; Baskar, K.; Contreras, S.

    2016-10-01

    AlGaN/AlN layers were grown by metalorganic chemical vapor deposition (MOCVD) on sapphire substrates. The AlN buffer thickness was varied from 400 nm to 800 nm. The AlGaN layer thickness was 1000 nm. The crystalline quality, thickness and composition of AlGaN were determined using high resolution X-ray diffraction (HRXRD). The threading dislocation density (TDD) was found to decrease with increase of AlN layer thickness. Reciprocal space mapping (RSM) was used to estimate the strain and relaxation between AlGaN and AlN. The optical properties of AlGaN layers were investigated by temperature dependent photoluminescence (PL). PL intensities of AlGaN layers increases with increasing the AlN thickness. The surface morphology of AlGaN was studied by atomic force microscopy (AFM). Root mean square (RMS) roughness values were found to be decreased while increase of AlN thickness.

  10. The theory of the moon in the al-Zij al-Kamil fi-l-taalim of Ibn al-Ha'im

    OpenAIRE

    Puig i Tàrrech, Roser

    2000-01-01

    Al the beginning of Ihe thirteenth cenrury (60tH I 1204-1205) Abli Muhammad Abd al-Haqq al-Ghafiqi al-lshbiIi known as Ibn al-Ha'im composed his work entitled al-Zi] al-Kamil fi-l-Taalim in honour of the Caliph Abu Abd Allah Muhammad al-Nasir (who reigned from 1199- 1213). All we know of lbn al-Ha'im's live is that he came from Seville and that he appears to have worked in North Africa.

  11. Geluk als onderwerp van wetenschappelijk onderzoek

    NARCIS (Netherlands)

    R. Veenhoven (Ruut)

    1970-01-01

    textabstractAbstract in Dutch: Geluk wordt gedefinieerd als overwegende tevredenheid met het leven als geheel. Dit artikel geeft een overzicht van het onderzoek naar dat verschijnsel. Geluk blijkt deels afhankelijk van persoonlijke eigenschappen. Zo blijkt ondermeer dat gelukkige mensen over het alg

  12. 75 FR 62858 - United States, et al.

    Science.gov (United States)

    2010-10-13

    ... Antitrust Division United States, et al. v. American Express Company, et al.; Proposed Final Judgment and... been filed with the United States District Court for the Eastern District of New York in United States..., 2010, the United States and seven States filed a Complaint alleging that certain rules, policies,...

  13. Als je vrienden hebt dan win je

    NARCIS (Netherlands)

    Effing, R. (Robin); Huibers, T. (Theo); Krosse, de L. (Luc)

    2010-01-01

    Als je wint, heb je vrienden’ is een Nederlandse klassieker van Herman Brood en Henny Vrienten. Hiermee werd de gevoelige snaar bloot gelegd dat pas als je hebt gewonnen je vrienden hebt. Rijen dik, echte vrienden. In de politiek werkt het andersom; je moet vrienden (stemmen) hebben, ve

  14. Diana Al-Hadid: Identity and Heritage

    Science.gov (United States)

    Jungerberg, Tom; Smith, Anna; Borsh, Colleen

    2012-01-01

    Diana Al-Hadid's sculptures reflect the many locations, cultures, histories, and mythologies that have shaped her as an artist. In large-scale works which have the appearance of architectural ruins, Al-Hadid employs imagery drawn from many diverse interests including science and technology, history, and literature. She also incorporates images and…

  15. Kus on al-Zarqawi? / Aadu Hiietamm

    Index Scriptorium Estoniae

    Hiietamm, Aadu, 1954-

    2005-01-01

    Suurbritannia nädalalehe Sunday Times andmetel on Iraagi tagaotsituim mässaja, terrorivõrgustiku al Qaeda liitlane Abu-Musab al-Zarqawi pärast USA raketirünnakus haavatasaamist riigist põgenenud

  16. Al-Farabi dan Filsafat Kenabian

    Directory of Open Access Journals (Sweden)

    Qosim Nursheha Dzulhadi

    2014-03-01

    Full Text Available Artikel ini mengulas pemikiran al-Farabi tentang konsep kenabian dalam Islam. Masalah berawal dari adanya pemikiran yang menolak konsep kenabian pada umumnya dan kenabian Nabi Muhammad SAW khususnya. Sebagaimana yang dilontarkan oleh Muhammad Ahmad ibn al-Ruwandi. Ia mengatakan bahwa nabi sebenarnya tidak diperlukan manusia karena Tuhan telah mengaruniakan akal kepada manusia tanpa terkecuali. Dengan akal ini, manusia dapat mengetahui Tuhan beserta segala nikmat Nya dan dapat pula mengetahui perbuatan baik dan buruk, menerima suruhan dan larangan-Nya. Dengan demikian, nabi dengan segala fungsinya tidak diperlukan lagi. Bahkan, kitab suci pun tidak berguna untuk dibaca. Lebih berguna membaca buku filsafat Epicurus, Plato, Aristoteles, dan buku astronomi, logika, serta obat-obatan. Hal ini tentunya bertolak belakang dengan yang diajarkan dalam Islam. Beriman kepada nabi nabi merupakan hal inti dalam ajaran agama ini. Atas dasar itu al-Farabi bereaksi keras. Baginya, pandangan Ibn al-Ruwandi di atas tidak dapat dibenarkan, khususnya dari sisi akidah Islam. Sebagai al-Mu‘allim al-Tsani (Guru Kedua, karena prestasinya dalam menjelaskan dan mengulas-ulang filsafat Aristoteles, al-Farabi mengkritik secara sistematik pandangan menyimpang al-Ruwandi di atas.

  17. The role of inclusions in ALS pathogenesis

    NARCIS (Netherlands)

    V. van Dis (Vera)

    2012-01-01

    textabstractAmyotrophic lateral sclerosis (ALS) is a devastating neurodegenerative disease that primarily afflicts motor neurons, leading to paralysis and death within 3 to 5 years after diagnosis. Genetic studies have uncovered multiple genetic defects causing familial forms of ALS and mutations oc

  18. Data supporting Al-Abed et al., Environ. Sci.: Nano, 2016,

    Data.gov (United States)

    U.S. Environmental Protection Agency — Data files representing each of the Figures and Tables published in Al-Abed et al., Environ. Sci.: Nano, 2016, 3, 593. The data file names identify the Figure or...

  19. Effect of Al coating conditions on laser weldability of Al coated steel sheet

    Institute of Scientific and Technical Information of China (English)

    Jung-Han LEE; Jong-Do KIM; Jin-Seok OH; Seo-Jeong PARK

    2009-01-01

    Al coated steel sheets with excellent heat resistance, thermal reflection, and corrosion resistance are widely used in various applications. The laser weldability of the Al coated steel sheet for full penetration welding was reported. The phenomenon caused by intermixed aluminum and behavior of aluminum in the weld were investigated. Al coated steel sheets that have various thickness and coating mass were prepared for laser welding. The effects of parameters such as welding conditions and Al coating conditions were investigated. Al content mixed in the weld after laser welding was evaluated, and then a correlation between the mixed Al and mechanical properties was investigated. The results show that the Al-rich zones which have Fe-Al intermetallic compounds are found in the weld. The intermetallic compounds cause the decreased strength of the weld.

  20. Kinetic Monte Carlo of transport processes in Al/AlOx/Au-layers: Impact of defects

    Directory of Open Access Journals (Sweden)

    Benedikt Weiler

    2016-09-01

    Full Text Available Ultrathin films of alumina were investigated by a compact kMC-model. Experimental jV-curves from Al/AlOx/Au-junctions with plasma- and thermal-grown AlOx were fitted by simulated ones. We found dominant defects at 2.3-2.5 eV below CBM for AlOx with an effective mass mox∗=0.35 m0 and a barrier EB,Al/AlOx≈2.8 eV in agreement with literature. The parameterization is extended to varying defect levels, defect densities, injection barriers, effective masses and the thickness of AlOx. Thus, dominant charge transport processes and implications on the relevance of defects are derived and AlOx parameters are specified which are detrimental for the operation of devices.

  1. Konsepsi Ibnu Jarir Al-Tabari Tentang Al-Qur’an, Tafsir Dan Ta’wil

    Directory of Open Access Journals (Sweden)

    A.M Ismatulloh

    2012-12-01

    Full Text Available The objective of this research is to describe the concept of Ibnu Jarir al-Tabari about al-Qur’an, tafsir and ta’wil. Ibn Jarir al-Tabari is an outstanding expert in the classic Islamic tradition. His knowledge in hadits, fiqh, lughah, history, and tafseer is unquestionable. This study uses an analytical descriptive design. The findings show that: Firstly, in defining al-Qur’an, al-Tabari focused on the al-Qur’an as an Arabic language text, not in other language. Secondly, al-Qur’an is written in sab’ah ahruf. It means that there are 7 different kinds of language with the same meaning. Thirdly, al-Qur’an comes from seven heaven’s door. Fourthly, there is no different word between tafseer and ta’wil. They have same meaning. These concepts are different to other concepts proposed by other ulama.

  2. Thermoluminescence properties of AlN ceramics

    DEFF Research Database (Denmark)

    Trinkler, L.; Christensen, P.; Agersnap Larsen, N.;

    1998-01-01

    The paper describes thermoluminescence (TL) properties of AlN:Y2O3 ceramics irradiated with ionising radiation. A high TL sensitivity of AlN:Y2O3 ceramics to radiation encouraged a study of the AlN ceramics for application as a dosimetric material. The paper presents experimental data on: glow...... curve, emission spectrum, dose response, energy dependence, influence of heating rate and fading rate. The measured TL characteristics were compared with those of well-known, widely used TLDs, i.e. LiF:Mg,Ti, LiF:Mg,Cu,P and Al2O3:C. It is concluded that AlN:Y2O3 ceramics showing a radiation sensitivity...

  3. High temperature creep behaviour of Al-rich Ti-Al alloys

    Energy Technology Data Exchange (ETDEWEB)

    Sturm, D; Heilmaier, M; Saage, H [Otto von Guericke University Magdeburg, Institute for Materials and Joining Technology, PO Box 4120, D-39016 Magdeburg (Germany); Aguilar, J; Schmitz, G J; Drevermann, A [ACCESS e.V., Intzestrasse 5, D-52072 Aachen (Germany); Palm, M; Stein, F; Engberding, N [Max-Planck-Institut fuer Eisenforschung GmbH, Max-Planck-Str. 1, D-40237 Duesseldorf (Germany); Kelm, K; Irsen, S, E-mail: daniel.sturm@ovgu.d [Stiftung caesar, Electron Microscopy, Ludwig-Erhard-Allee 2, D-53175 Bonn (Germany)

    2010-07-01

    Compared to Ti-rich {gamma}-TiAl-based alloys Al-rich Ti-Al alloys offer an additional reduction of in density and a better oxidation resistance which are both due to the increased Al content. Polycrystalline material was manufactured by centrifugal casting. Microstructural characterization was carried out employing light-optical, scanning and transmission electron microscopy and XRD analyses. The high temperature creep of two binary alloys, namely Al{sub 60}Ti{sub 40} and Al{sub 62}Ti{sub 38} was comparatively assessed with compression tests at constant true stress in a temperature range between 1173 and 1323 K in air. The alloys were tested in the cast condition (containing various amounts of the metastable phases Al{sub 5}Ti{sub 3} and h-Al{sub 2}Ti) and after annealing at 1223 K for 200 h which produced (thermodynamically stable) lamellar {gamma}-TiAl + r-Al{sub 2}Ti microstructures. In general, already the as-cast alloys exhibit a reasonable creep resistance at 1173 K. Compared with Al{sub 60}Ti{sub 40}, both, the as-cast and the annealed Al{sub 62}Ti{sub 38} alloy exhibit better creep resistance up to 1323 K which can be rationalized by the reduced lamella spacing. The assessment of creep tests conducted at identical stress levels and varying temperatures yielded apparent activation energies for creep of Q = 430 kJ/mol for the annealed Al{sub 60}Ti{sub 40} alloy and of Q = 383 kJ/mol for the annealed Al{sub 62}Ti{sub 38} material. The latter coincides well with that of Al diffusion in {gamma}-TiAl, whereas the former can be rationalized by the instability of the microstructure containing metastable phases.

  4. MOSQUE ARCHITECTURE AS A SUSTAINABLE BUILDING IN URBAN (Case Study: Al Markas Al Islamic Mosque Makassar)

    OpenAIRE

    Imriyanti Imriyanti

    2014-01-01

    Abstract Mosque Architecture is a part of Islamic architecture. Mosque should be fused with elements of nature because its function as a place to pray to God who created the universe. Al Markas Al Islamic Makassar mosque is used as a center of Islamic aspirations of the people and the government to accommodate all the activities of moslems in Makassar. Through this function, the provision of Al Markas Al Islamic mosque began from the desire of Islamic societies in Makassar, which want...

  5. Corrosion Studies of 2195 Al-Li Alloy and 2219 Al Alloy with Differing Surface Treatments

    Science.gov (United States)

    Danford, M. D.; Mendrek, M. J.

    1998-01-01

    Corrosion studies of 2195 Al-Li and 2219 Al alloys have been conducted using the scanning reference electrode technique (SRET) and the polarization resistance (PR) technique. The SRET was used to study corrosion mechanisms, while corrosion rate measurements were studied with the PR technique. Plates of Al203 blasted, soda blasted and conversion coated 2219 Al were coated with Deft primer and the corrosion rates studied with the EIS technique. Results from all of these studies are presented.

  6. Japanese version of the ALS-FTD-Questionnaire (ALS-FTD-Q-J).

    Science.gov (United States)

    Watanabe, Yasuhiro; Beeldman, Emma; Raaphorst, Joost; Izumi, Yuishin; Yoshino, Hiide; Masuda, Michihito; Atsuta, Naoki; Ito, Satoru; Adachi, Tadashi; Adachi, Yoshiki; Yokota, Osamu; Oda, Masaya; Hanashima, Ritsuko; Ogino, Mieko; Ichikawa, Hiroo; Hasegawa, Kazuko; Kimura, Hideki; Shimizu, Toshio; Aiba, Ikuko; Yabe, Hayato; Kanba, Makoto; Kusumi, Kimiyoshi; Aoki, Tetsuya; Hiroe, Yu; Watanabe, Hirohisa; Nishiyama, Kazutoshi; Nomoto, Masahiro; Sobue, Gen; Nakashima, Kenji

    2016-08-15

    Amyotrophic lateral sclerosis (ALS) and frontotemporal dementia (FTD) share common clinical, genetic and neuropathological features. Some ALS patients have behavioral/personality changes, which could result in significant obstacles in the care provided by family members and caregivers. An easy screening tool would contribute greatly to the evaluation of these symptoms. We translated the ALS-FTD-Questionnaire, developed in the Netherlands, into Japanese (ALS-FTD-Q-J) and examined the clinimetric properties (internal consistency, construct and clinical validity). Patients with ALS and/or behavioral variant FTD (bvFTD) were evaluated alongside healthy controls in this multicenter study. All ALS patients, regardless of bvFTD status, were further evaluated by the frontal behavioral inventory (FBI) and for frontal/executive function, cognition, anxiety/depression, and motor functions. Data from 146 subjects were analyzed: ALS (92), ALS-bvFTD (6), bvFTD (16), and healthy controls (32). The internal consistency of the ALS-FTD-Q-J was good (Cronbach α=0.92). The ALS-FTD-Q-J showed construct validity as it exhibited a high correlation with the FBI (r=0.79). However, correlations were moderate with anxiety/depression and low with cognitive scales, in contrast to the original report, i.e. a moderate correlation with cognition and a low correlation with anxiety/depression. The ALS-FTD-Q-J discriminated ALS patients from (ALS-)bvFTD patients and controls. Thus, the ALS-FTD-Q-J is useful for evaluating Japanese ALS/FTD patients. PMID:27423564

  7. Japanese version of the ALS-FTD-Questionnaire (ALS-FTD-Q-J).

    Science.gov (United States)

    Watanabe, Yasuhiro; Beeldman, Emma; Raaphorst, Joost; Izumi, Yuishin; Yoshino, Hiide; Masuda, Michihito; Atsuta, Naoki; Ito, Satoru; Adachi, Tadashi; Adachi, Yoshiki; Yokota, Osamu; Oda, Masaya; Hanashima, Ritsuko; Ogino, Mieko; Ichikawa, Hiroo; Hasegawa, Kazuko; Kimura, Hideki; Shimizu, Toshio; Aiba, Ikuko; Yabe, Hayato; Kanba, Makoto; Kusumi, Kimiyoshi; Aoki, Tetsuya; Hiroe, Yu; Watanabe, Hirohisa; Nishiyama, Kazutoshi; Nomoto, Masahiro; Sobue, Gen; Nakashima, Kenji

    2016-08-15

    Amyotrophic lateral sclerosis (ALS) and frontotemporal dementia (FTD) share common clinical, genetic and neuropathological features. Some ALS patients have behavioral/personality changes, which could result in significant obstacles in the care provided by family members and caregivers. An easy screening tool would contribute greatly to the evaluation of these symptoms. We translated the ALS-FTD-Questionnaire, developed in the Netherlands, into Japanese (ALS-FTD-Q-J) and examined the clinimetric properties (internal consistency, construct and clinical validity). Patients with ALS and/or behavioral variant FTD (bvFTD) were evaluated alongside healthy controls in this multicenter study. All ALS patients, regardless of bvFTD status, were further evaluated by the frontal behavioral inventory (FBI) and for frontal/executive function, cognition, anxiety/depression, and motor functions. Data from 146 subjects were analyzed: ALS (92), ALS-bvFTD (6), bvFTD (16), and healthy controls (32). The internal consistency of the ALS-FTD-Q-J was good (Cronbach α=0.92). The ALS-FTD-Q-J showed construct validity as it exhibited a high correlation with the FBI (r=0.79). However, correlations were moderate with anxiety/depression and low with cognitive scales, in contrast to the original report, i.e. a moderate correlation with cognition and a low correlation with anxiety/depression. The ALS-FTD-Q-J discriminated ALS patients from (ALS-)bvFTD patients and controls. Thus, the ALS-FTD-Q-J is useful for evaluating Japanese ALS/FTD patients.

  8. Interfacial reactions in Al/Ni multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, F.; Greer, A.L. [Cambridge Univ. (United Kingdom). Dept. of Metallurgy and Materials Science

    1998-08-01

    In thin-film multilayers, the reactions at the interfaces can proceed quite differently from those in bulk samples because of the short diffusion distances involved. In the present work Al/Ni multilayers have been made by DC magnetron sputtering. The initial Ni and Al layers have strong (111) texture. The reactions taking place have been studied in relation to the layer thickness and film structure (grain size and texture). Also multilayers have been made with alloy layers Al/Ni(Al). Typically, differential scanning calorimetry shows a sequence of reactions on heating. X-ray diffraction, including texture goniometry, has been used to identify the compounds produced. In common with earlier work, it is found that Al{sub 3}Ni is the first phase to form, but the present results differ from those reported previously in that the Al{sub 3}Ni{sub 2} phase is not formed in the course of phase evolution. The difference from the earlier results is attributed to the sharper texture in the films in the present work. Thus it is concluded that for Al/Ni multilayers, reaction sequences can be affected by crystallographic orientation, as well as other factors. (orig.) 13 refs.

  9. Magnetism in bcc Fe-Al alloy

    Energy Technology Data Exchange (ETDEWEB)

    Elzain, M.E. [Sultan Qaboos Univ., Al-Khod (Oman). Dept. of Phys.; Yousif, A.A. [Sultan Qaboos Univ., Al-Khod (Oman). Dept. of Phys.

    1994-11-01

    The magnetic moment {mu}, hyperfine field B{sub hf} and isomer shift IS at the Fe site in bcc Fe-Al alloys were calculated from first principle. Contrary to the belief that Al atoms reside in the iron lattice as magnetic holes, it was found that the local magnetic moment of Fe is decreased when Al is at a nearest neighbour site (NN), while it increases if Al is at a next-nearest neighbour site (NNN). Consequently, the average {mu} per Fe atom was found to be, initially, independent of Al content. Assuming a linear dependence of {mu}{sub Fe} on the number of Al atoms at NN and NNN sites, we calculated the average {mu}, which was found to agree with experimental results of cold worked alloys for disordered Fe-Al alloy. On the other hand, antiferromagnetic coupling appears in the CsCl ordered structures. The average B{sub hf} was also calculated and compared to experimental data and the trends in the IS are considered. (orig.)

  10. WAHDAT AL WUJUD DALAM PEMIKIRAN IBNU ARABI

    Directory of Open Access Journals (Sweden)

    Abd Halim Rofi'ie

    2013-09-01

    Full Text Available Ibnu Arabi, the Grand Master of Islam, is a great thinker whose controversial thought, wahdat al-wujud, has significantly influenced the mystiques of Islam. The meaning of wahdat al-wujud is basically two folds, i.e. that Being is the only One which exists and that the universe is merely a manifestation of the One. The One Being here refers to Allah SWT. The One covers up all the existing phenomena and functions as a resource which emanates the entire universe. In this context, He is referred to as al-Haqiqat al-Muhammadiyah. He might also be viewed as both the Universal Soul for His being the source of cosmos that governs the universe and the Universal Body for His reflecting any actions on every single micro existence that forms the universe. Furthermore, when His existence is deemed as a jauhar (jewel that face-up any occurrences, He is typically known as al-haba’. The concept of wahdat al-wujud can actually be simplified into the principle of laa maujuda illa wujud al-wahid (no existence except the Existing One, the Being. The One might reveal His own existence into different martabat or levels: Martabat Ahadiyah, Martabat Wahidiyah, and Martabat Tajalli Syuhudi. Those standing points trigger Ibnu Arabi to believe that any kinds of realities or existences are nothing but a true reflection of the One.

  11. Arsenate uptake by Al nanoclusters and other Al-based sorbents during water treatment.

    Science.gov (United States)

    Mertens, Jasmin; Rose, Jérôme; Wehrli, Bernhard; Furrer, Gerhard

    2016-01-01

    In many parts of the world, arsenic from geogenic and anthropogenic sources deteriorates the quality of drinking water resources. Effective methods of arsenic removal include adsorption and coagulation with iron- and aluminum-based materials, of which polyaluminum chloride is widely employed as coagulant in water treatment due to its low cost and high efficiency. We compared the arsenic uptake capacity and the arsenic bonding sites of different Al-based sorbents, including Al nanoclusters, polyaluminum chloride, polyaluminum granulate, and gibbsite. Extended X-ray absorption fine structure (EXAFS) spectroscopy revealed that As(V) forms bidentate-binuclear complexes in interaction with all Al-based removal agents. The octahedral configuration of nanoclusters and the distribution of sorption sites remain the same in all types of removal agents consisting of nano-scale Al oxyhydroxide particles. The obtained distances for As(V)-O and As(V)-Al agreed with previously published data and were found to be 1.69 ± 0.02 Å and 3.17-3.21 Å, respectively. Our study suggests that As(V) binds to Al nanoclusters as strongly as to Al oxide surfaces. The As sorption capacity of Al nanoclusters was found to be very similar to that of Al clusters in a polyaluminum chloride. The most efficient Al-based sorbents for arsenic removal were Al nanoclusters, followed by polyaluminum granulate. PMID:26613179

  12. Tracing Al Shabaab’s Decision to Cooperate with Al Qaeda in Somalia (2008

    Directory of Open Access Journals (Sweden)

    Adlini Ilma Ghaisany Sjah

    2014-02-01

    Full Text Available 'Al Shabaab, a Somali insurgent with predominantly nationalistic causes (alongside transnational [global Jihad] and Islamic goals made the choice to fight on behalf of Al Qaeda in 2008. The decision to do so contrasted with Al Shabaab’s previous behaviour of actively denying cooperation and distancing itself from Al Qaeda. This study aims to uncover factors that contributed to Al Shabaab’s decision through the use of process-tracing. The results show that Al Shabaab’s declaration of cooperation with Al Qaeda in August 2008 was brought about by a series of events that traced back to four factors: public reactions to the implementation of a Salafi ideology, the shift to a radical leadership, Al Shabaab’s inability to maintain stability in areas under its control and its increasing attacks by Al Shabaab on the Somali public. Al Shabaab pursued cooperation with Al Qaeda after realizing that their nationalistic preference was no longer achievable in the near future.' ' '

  13. Electrical investigations of AlGaN/AlN structures for LEDs on Si(111)

    Energy Technology Data Exchange (ETDEWEB)

    Witte, H.; Rohrbeck, A.; Guenther, K.M.; Saengkaew, P.; Blaesing, J.; Dadgar, A.; Krost, A. [Department of Semiconductor Epitaxy, Institute of Experimental Physics, University of Magdeburg, 39106 Magdeburg (Germany)

    2011-07-15

    The carrier transport in AlGaN light emission diode (LED) structures on Si-substrates including an AlN multilayer (ML) buffer for reduction of defects was investigated using I-V-characteristics and admittance spectroscopy. Additionally, AlN on Si ML and AlN/AlGaN:Si on Si structures were grown and analyzed separately. The AlN-ML/AlGaN:Si heterojunction, and the pn-junction including the AlGaN/GaN multi quantum well (MQW)-structure were identified. As the main space charge regions (SCRs) controlling the carrier transport through the ultraviolet-light emission diode (UV-LED) structure the Si-substrate/AlN-ML heterojunctions pointed out. The I-V-characteristic of the LED structure is described by the series resistance of the AlN-ML and a parallel resistance with respect to the pn-junction. Interface defect states and/or deep defects impact the series resistance. The carrier transport through the LED structure is controlled by a tunnel process described by a Fowler-Nordheim (FN)-emission mainly through the AlN-ML buffer forming the series resistance. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  14. Kritik al-Ghazali terhadap Kekekalan Alam

    OpenAIRE

    Sahidi Mustafa

    2015-01-01

    The concept of the creation of universe offered by Neo-Platonism philosopher such as al-Kindi, al-Farabi, and Ibnu Sina are philosophical concept existed and came as an early moment of development of Islamic philosophy interrelated to God, ultimately about his Existence and Characteristics. One of the topics is how God created the universe. According to al-Farabi and Ibnu Sina, God created this universe by way of emanation in order to prevent Himself from the new attitudes. Consequently, univ...

  15. Amyotrofinen lateraaliskleroosi (ALS) ja potilaan ohjaus

    OpenAIRE

    Korkeaniemi, Lotta; Kaakinen, Leena

    2009-01-01

    Saimme opinnäytetyömme toimeksiantona Hyvinkään sairaalan sisätautien vuodeosastolta. Tavoitteena oli luoda ALS potilaille potilasopas trakeostomiasta ja sen kanssa elämisestä. Oppaan tarkoituksena on auttaa ALS potilaita päättämään, kuinka pitkälle he haluavat viedä heidän hengitystukihoitonsa. Samalla hoitajat saavat tuki materiaalia, jonka avulla he voivat käydä läpi hengitystukihoitoja ja erityisesti trakeostomiaan liittyviä asioita. ALS eli amyotrofinen lateraaliskleroosi on tahdona...

  16. The wobbler mouse, an ALS animal model

    DEFF Research Database (Denmark)

    Moser, Jakob Maximilian; Bigini, Paolo; Schmitt-John, Thomas

    2013-01-01

    This review article is focused on the research progress made utilizing the wobbler mouse as animal model for human motor neuron diseases, especially the amyotrophic lateral sclerosis (ALS). The wobbler mouse develops progressive degeneration of upper and lower motor neurons and shows striking...... similarities to ALS. The cellular effects of the wobbler mutation, cellular transport defects, neurofilament aggregation, neuronal hyperexcitability and neuroinflammation closely resemble human ALS. Now, 57 years after the first report on the wobbler mouse we summarize the progress made in understanding...

  17. Thermal diffusion in Ni/Al multilayer

    Energy Technology Data Exchange (ETDEWEB)

    Swain, M.; Bhattacharya, D.; Singh, S.; Basu, S. [Solid State Physics Division, Bhabha Atomic Research Center, Mumbai 400085 (India); Gupta, M. [UGC-DAE-Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452017 (India)

    2013-02-05

    Two Ni/Al multilayers deposited by ion beam sputtering of nominal design [Ni(200A)/Al(100A)] Multiplication-Sign 5 and [Ni(50A)/Al(227A)] Multiplication-Sign 5 on Si substrates were annealed at 200 Degree-Sign C. As-deposited and annealed samples were characterized by x-ray diffraction (XRD) and x-ray reflectometry (XRR). The effort was to study the path of alloying in the above two multilayers of same elements but of opposite stoichiometric ratio. We find distinct differences in alloying of these samples.

  18. Linija za transport Al-polizdelkov

    OpenAIRE

    Capl, Žiga

    2012-01-01

    V diplomski nalogi je predstavljena linija za transport Al-polizdelkov, ki je sestavljena iz dveh verižnih transporterjev in dveh manipulatorjev. Omenjeni transporterji morajo transportirati Al-polizdelke od sprejemnega mesta do poti v stiskalnico. V okviru diplomskega dela smo opravili analizo obstoječega ogrodja z naklonom, linije za transport Al-polizdelkov in podali možne rešitve za novo učinkovitejšo izvedbo. Na podlagi tehnično-tehnoloških zahtev smo izbrali najprimernejšo rešitev i...

  19. The Ni-Al-Hf Multiphase Diffusion

    Directory of Open Access Journals (Sweden)

    Romanowska J.

    2016-06-01

    Full Text Available The generalized Darken method was applied to simulate the diffusion between γ-Ni| γ’-Ni3Al and γ’-Ni3Al|β-NiAl interfaces. The results of calculations were compared with the experimental concentration’s profiles of nickel, aluminum and hafnium in aluminide and hafnium doped aluminide coatings deposited by the CVD and PVD methods on pure nickel. The method deals with the Wagner’s integral diffusion coefficients and thermodynamic data - activities of components. The experimental results agree with the simulated ones.

  20. Die Poetik als Teil des aristotelischen Organon

    OpenAIRE

    Wels, Volkhard

    2016-01-01

    Der Aufsatz umreißt die Wirkung von Averroes’ Bearbeitung der aristotelischen ‚Poetik‘ als argumentativer Disziplin. Beginnend mit Al-Farabi und Al-Gazali im zehnten Jahrhundert wird die ‚Poetik‘ den logischen Disziplinen des ‚Organon‘ zugerechnet. Während die Theorie eines ‚poetischen Syllogismus‘ nicht rezipiert worden ist, wurde der argumentative Status der Dichtung vom zwölften Jahrhundert an auch im lateinischen Westen bekannt. Mit unterschiedlichen Begründungen übernahmen Dominicus Gund...

  1. TAFSIR SEMANTIK TERHADAP SURAT AL-KAFIRUN

    Directory of Open Access Journals (Sweden)

    Imam Muslimin

    2011-10-01

    Full Text Available The problems about the reading of al-Qur’an is always interesting to be discussed, in which the use of Arabic includes sound or ‘nash’ is acrucial factor to understand the implicit meaning of the Arabic-written texts. Al-Qur’an discusses problem based on the society’s culture. Al-Kafirun discusses not only about the normative theology but more about sociological contexts in which it tends to show transparency, fight against fanaticism and regionalism. And all of the will bring to the first process of the making of the text meaning to the situational context that creates them.

  2. InAlN/AlN/GaN heterostructures for high electron mobility transistors

    Science.gov (United States)

    Usov, S. O.; Sakharov, A. V.; Tsatsulnikov, A. F.; Lundin, V. W.; Zavarin, E. E.; Nikolaev, A. E.; Yagovkina, M. A.; Zemlyakov, V. E.; Egorkin, V. I.; Ustinov, V. M.

    2016-08-01

    The results of development of InAlN/AlN/GaN heterostructures, grown on sapphire substrates by metal-organic chemical vapour deposition, and high electron mobility transistors (HEMTs) based on them are presented. The dependencies of the InAlN/AlN/GaN heterostructure properties on epitaxial growth conditions were investigated. The optimal indium content and InAlN barrier layer thicknesses of the heterostructures for HEMT s were determined. The possibility to improve the characteristics of HEMTs by in-situ passivation by Si3N4 thin protective layer deposited in the same epitaxial process was demonstrated. The InAlN/AlN/GaN heterostructure grown on sapphire substrate with diameter of 100 mm were obtained with sufficiently uniform distribution of sheet resistance. The HEMTs with saturation current of 1600 mA/mm and transconductance of 230 mS/mm are demonstrated.

  3. Oxidation of Al2O3 continuous fiber-reinforced/NiAl composites

    Science.gov (United States)

    Doychak, J.; Nesbitt, J. A.; Noebe, R. D.; Bowman, R. R.

    1992-01-01

    The 1200 C and 1300 C isothermal and cyclic oxidation behavior of Al2O3 continuous fiber-reinforced/NiAl composites were studied. Oxidation resulted in formation of Al2O3 external scales in a similar manner as scales formed on monolithic NiAl. The isothermal oxidation of an Al2O3/NiAl composite resulted in oxidation of the matrix along the fiber/matrix interface near the fiber ends. This oxide acted as a wedge between the fiber and the matrix, and, under cyclic oxidation conditions, led to further oxidation along the fiber lengths and eventual cracking of the composite. The oxidation behavior of composites in which the Al2O3 fibers were sputter coated with nickel prior to processing was much more severe. This was attributed to open channels around the fibers which formed during processing, most likely as a result of the diffusion of the nickel coating into the matrix.

  4. AlON粉体的合成%Synthesis of AlON Powder

    Institute of Scientific and Technical Information of China (English)

    赵小军; 茹红强; 张宁; 孙有政

    2009-01-01

    以α-Al_2O_3和AlN为原料,利用高温固相反应在氮气气氛下常压合成了AlON粉体.研究了成分配比、合成温度、保温时间对合成AlON粉体含量的影响,并通过热分析测试了合成过程热流和质量的变化.结果表明,当原料Al_2O_3和AlN的质量比为81:18、合成工艺为1750 ℃, 2 h时,得到AlON相的含量达到95%以上.

  5. A Rechargeable Al/S Battery with an Ionic-Liquid Electrolyte.

    Science.gov (United States)

    Gao, Tao; Li, Xiaogang; Wang, Xiwen; Hu, Junkai; Han, Fudong; Fan, Xiulin; Suo, Liumin; Pearse, Alex J; Lee, Sang Bok; Rubloff, Gary W; Gaskell, Karen J; Noked, Malachi; Wang, Chunsheng

    2016-08-16

    Aluminum metal is a promising anode material for next generation rechargeable batteries owing to its abundance, potentially dendrite-free deposition, and high capacity. The rechargeable aluminum/sulfur (Al/S) battery is of great interest owing to its high energy density (1340 Wh kg(-1) ) and low cost. However, Al/S chemistry suffers poor reversibility owing to the difficulty of oxidizing AlSx . Herein, we demonstrate the first reversible Al/S battery in ionic-liquid electrolyte with an activated carbon cloth/sulfur composite cathode. Electrochemical, spectroscopic, and microscopic results suggest that sulfur undergoes a solid-state conversion reaction in the electrolyte. Kinetics analysis identifies that the slow solid-state sulfur conversion reaction causes large voltage hysteresis and limits the energy efficiency of the system. PMID:27417442

  6. Characterization of AlInN/AlN/GaN Heterostructures with Different AlN Buffer Thickness

    Science.gov (United States)

    Çörekçi, S.; Dugan, S.; Öztürk, M. K.; Çetin, S. Ş.; Çakmak, M.; Özçelik, S.; Özbay, E.

    2016-07-01

    Two AlInN/AlN/GaN heterostructures with 280-nm- and 400-nm-thick AlN buffer grown on sapphire substrates by metal-organic chemical vapor deposition (MOCVD) have been investigated by x-ray diffraction (XRD), atomic force microscopy (AFM), photoluminescence (PL) and Hall-effect measurements. The symmetric (0002) plane with respect to the asymmetric (10bar{1}2) plane in the 280-nm-thick AlN buffer has a higher crystal quality, as opposed to the 400-nm-thick buffer. The thinner buffer improves the crystallinity of both (0002) and (10bar{1}2) planes in the GaN layers, it also provides a sizeable reduction in dislocation density of GaN. Furthermore, the lower buffer thickness leads to a good quality surface with an rms roughness of 0.30 nm and a dark spot density of 4.0 × 108 cm-2. The optical and transport properties of the AlInN/AlN/GaN structure with the relatively thin buffer are compatible with the enhancement in its structural quality, as verified by XRD and AFM results.

  7. Evolution of ConAl clusters and chemisorption of hydrogen on ConAl clusters

    International Nuclear Information System (INIS)

    The growth behavior of ConAl (n = 1–15) and the chemisorptions of hydrogen on the ground state geometries have been studied using the density functional theory (DFT) within the generalized gradient approximation (GGA). The growth pattern for ConAl is Al-substituted Con+1 clusters, and it keeps the similar frameworks of the most stable Con+1 clusters except for n = 2, 3, and 6. The Al atom substitutes the surface atom of the Con+1 clusters for n ≤ 13. Starting from n = 14, the Al atom completely falls into the center of the Co-frame. The dissociation energy, the second-order energy differences, and the HOMO–LUMO gaps indicate that the magic numbers of the calculated ConAl clusters are 7, 9, and 13, corresponding to the high symmetrical structures. To my knowledge, this is the first time that a systematic study of chemisorption of hydrogen on cobalt aluminum clusters. The twofold bridge site is identified to be the most favorable chemisorptions site for one hydrogen adsorption on ConAl (n = 1–6, 8, 10), and two hydrogen adsorption on ConAl (n = 1–7), while threefold hollow site is preferred for one hydrogen adsorption on ConAl (n = 7, 9, 11–15) and two hydrogen adsorption on ConAl (n = 8–10, 12–15) clusters. The ground state structure of two hydrogen adsorption on Co11Al is exceptional. In general, the binding energy of both H and 2H of ConAl (n = 1–12) is found to increase with the cluster size. And the result shows that large binding energies of the hydrogen atoms and large fragmentation energies for Co11AlH and Co12AlH make these species behaving like magic clusters.

  8. Wali Allah menurut al-Hakim al-Tirmidzi dan Ibnu Taimiyyah

    Directory of Open Access Journals (Sweden)

    Lilik Mursito

    2015-12-01

    Full Text Available The discussion about wali presented in the early time on the hand of al-Hakim al Tirmidzi, which reaps number of responses from Muslim scholar because of his misleading. One of them is Ibn Taimiyyah. Al-Hakim and Ibn Taymiyyah have their own view about wali with several distinctions. In the definition of wali, al-Hakim al-Tirmidzi used more general language than Ibn Taimiyyah, as well as characteristics, how to be wali, the classification, concept of karamah, and the concept of khatm al-awliya’. According to writer, al-Hakim al-Tirmidzi’s view about wali able to deepen our understanding about Sufism, meanwhile Ibn Taimiyyah’s view will led us to comprehend Sufism from modernist point of view. This paper conclude that: both of figures seen that wali of Allah are the servants submissive and obedient in running His command; according to al-Hakim al Tirmidzi, degree of wali can be reached purely from Allah’s bounty and the effort of servants themselves, while Ibn Taimiyyah seen that the degree could be reached in the way of faith and piety of the servant; al-Hakim al-Tirmidzi seen that karamah is the most urgent for wali, while Ibn Taimiyyah did not; al-Hakim al-Tirmidzi utilized the quality of deeds to measure the best people and purity of heart to measure the best wali, while Ibn Taymiyyah utilized the quality of deeds as the assessment standard to measure best people and wali.

  9. In Situ Fabrication of AlN Coating by Reactive Plasma Spraying of Al/AlN Powder

    Directory of Open Access Journals (Sweden)

    Mohammed Shahien

    2011-10-01

    Full Text Available Reactive plasma spraying is a promising technology for the in situ formation of aluminum nitride (AlN coatings. Recently, it became possible to fabricate cubic-AlN-(c-AlN based coatings through reactive plasma spraying of Al powder in an ambient atmosphere. However, it was difficult to fabricate a coating with high AlN content and suitable thickness due to the coalescence of the Al particles. In this study, the influence of using AlN additive (h-AlN to increase the AlN content of the coating and improve the reaction process was investigated. The simple mixing of Al and AlN powders was not suitable for fabricating AlN coatings through reactive plasma spraying. However, it was possible to prepare a homogenously mixed, agglomerated and dispersed Al/AlN mixture (which enabled in-flight interaction between the powder and the surrounding plasma by wet-mixing in a planetary mill. Increasing the AlN content in the mixture prevented coalescence and increased the nitride content gradually. Using 30 to 40 wt% AlN was sufficient to fabricate a thick (more than 200 µm AlN coating with high hardness (approximately 1000 Hv. The AlN additive prevented the coalescence of Al metal and enhanced post-deposition nitriding through N2 plasma irradiation by allowing the nitriding species in the plasma to impinge on a larger Al surface area. Using AlN as a feedstock additive was found to be a suitable method for fabricating AlN coatings by reactive plasma spraying. Moreover, the fabricated coatings consist of hexagonal (h-AlN, c-AlN (rock-salt and zinc-blend phases and certain oxides: aluminum oxynitride (Al5O6N, cubic sphalerite Al23O27N5 (ALON and Al2O3. The zinc-blend c-AlN and ALON phases were attributed to the transformation of the h-AlN feedstock during the reactive plasma spraying. Thus, the zinc-blend c-Al

  10. Pesticides Linked to Raised Risk of ALS

    Science.gov (United States)

    ... page: https://medlineplus.gov/news/fullstory_158737.html Pesticides Linked to Raised Risk of ALS One toxin ... MONDAY, May 9, 2016 (HealthDay News) -- Exposure to pesticides and other chemicals may increase the risk for ...

  11. Data used in Xu et al., 2016

    Data.gov (United States)

    U.S. Environmental Protection Agency — Mercury emissions data from anthropogenic sources as described in Xu et al., 2016. This dataset is associated with the following publication: Xu, X., N. Liu, M....

  12. Smoking Tied to Shorter Survival with ALS

    Science.gov (United States)

    ... page: https://medlineplus.gov/news/fullstory_161094.html Smoking Tied to Shorter Survival With ALS Tobacco use ... 22, 2016 WEDNESDAY, Sept. 21, 2016 (HealthDay News) -- Smoking may speed progression of Lou Gehrig's disease and ...

  13. Het Nederlandse bos als vorm van bodemgebruik

    NARCIS (Netherlands)

    Slangen, L.H.G.; Boven, van B.

    1983-01-01

    Behandeling van de oppervlakte en verdeling van het bos en de veranderingen die hierin zijn opgetreden, met de bedrijfsgrootte-struktuur als belangrijke invalshoek daarbij; de rol van de overheid: doeleinden, instrumenten en effekten van het beleid

  14. Thermal Conductivity of Al-Salt Composites

    Science.gov (United States)

    Li, Peng; Zhang, Mei; Wang, Lijun; Seetharaman, Seshadri

    2015-11-01

    With a view to examine the possibility of estimating the content of entrapped metallic aluminium in the salt cake from aluminium remelting, the thermal diffusivity of reference composites of KCl-NaCl-Al was measured as a function of aluminium metal content at room temperature. The thermal conductivity of the reference composites was found to increase with the metallic Al content. The lumped parameter model approach was carried out to discuss the influence of different geometry arrangements of each phase, viz. air, salts and metallic aluminium on the thermal conductivity. Application of the present results to industrial samples indicates that factors such as the interfacial condition of metallic Al particles have to be considered in order to estimate the amount of entrapped Al in the salt cake.

  15. Pesticides Linked to Raised Risk of ALS

    Science.gov (United States)

    ... nlm.nih.gov/medlineplus/news/fullstory_158737.html Pesticides Linked to Raised Risk of ALS One toxin ... MONDAY, May 9, 2016 (HealthDay News) -- Exposure to pesticides and other chemicals may increase the risk for ...

  16. Calcium platinum aluminium, CaPtAl

    Directory of Open Access Journals (Sweden)

    Charles Fon Abi

    2011-10-01

    Full Text Available A preliminary X-ray study of CaPtAl has been reported previously by Hulliger [J. Alloys Compd (1993, 196, 225–228] based on X-ray powder diffraction data without structure refinement. With the present single-crystal X-ray study, we confirm the assignment of the TiNiSi type for CaPtAl, in a fully ordered inverse structure. All three atoms of the asymmetric unit have .m. site symmetry. The structure features a ∞3[AlPt] open framework with a fourfold coordination of Pt by Al atoms and vice versa. The Ca atoms are located in the large channels of the structure.

  17. Stem Cells Deemed Safe for ALS Patients

    Science.gov (United States)

    ... page: https://medlineplus.gov/news/fullstory_159627.html Stem Cells Deemed Safe for ALS Patients But further research needed to see if injections into spine would provide any benefit, researchers say To use the sharing features on ...

  18. Preparation of TiAl/Ti2AlC Composites with Ti/Al/C Powders by In-situ Hot Pressing

    Institute of Scientific and Technical Information of China (English)

    MEI Bingchu; YAN Ming; ZHU Jiaoqun; ZHOU Weibing

    2006-01-01

    TiAl/Ti2AlC composites were prepared by in-situ hot pressing of Ti/Al/C powders mixtures and sintered at different temperatures were investigated by X-ray diffraction (XRD) of samples. The reaction procedure of Ti-Al-C system could be divided into three stages. Below 900 ℃, Ti reacts with Al to form TiAl intermetallics; above 900 ℃, C reacts with remain Ti to form TiC triggered by the exothermal reaction of Ti and Al; TiAl reacts with TiC to produce dense TiAl/Ti2AlC composites. In the holding stage, ternary Ti2AlC develops to layered polycrystal and composites pyknosis in the meanwhile. The mechanism of synthesis and microstructure was especially discussed.

  19. Del latín al rumano

    Directory of Open Access Journals (Sweden)

    Montes Giraldo José Joaquín

    2003-06-01

    Full Text Available

    Marius Sala, Del latín al rumano. Versión española de Valeria Neagu, París, Unión Latina - Bucarest, Univers enciclopedic, 2002. El texto se dirige al lector corriente, no especialista, y por eso el aparato técnico-bibliográfico no se presenta en el curso de la exposición.

  20. Effects of Al substitution on goethite formation

    OpenAIRE

    Premoli, Alessandra Maria; Melis, Pietro; Gessa, Carlo Emanuele; Deiana, Salvatore Andrea

    1984-01-01

    Goethites containing up to 32.7 mole % Al were synthesized and characterized through diffractometry, spectrometry, DSC and chemical techniques. Results indicate that crystal growth was favoured or hindered depending on the percentage of aluminum incorporated into the structure. Goethites to which 5-10 mole % Al were initially added crystallized best, as shown by the highest crystallite dimensions calculated from X-ray and Mössbauer analyses, and by the lowest surface areas values. Over suc...

  1. Information als Gegenstand von Informationskompetenz. Eine Begriffsanalyse

    OpenAIRE

    Ingold, Marianne

    2011-01-01

    Der Informationsbegriff als zentraler Gegenstand von Informationskompetenz wird in der bibliothekarischen Diskussion in der Regel nicht explizit thematisiert, sondern lässt sich aus Fachliteratur und Bibliothekspraxis nur implizit erschließen. Eine theoretische Beschäftigung mit dem Informationsbegriff ist jedoch unabdingbar, soll das Konzept "Informationskompetenz" auch außerhalb des bibliothekarischen Kontextes verständlich und nutzbar gemacht werden. Im vorliegenden Text, der sich als B...

  2. Anerkennung als Voraussetzung gesellschaftlicher und unternehmerischer Teilhabe

    OpenAIRE

    Eurich, Johannes; Brink, Alexander

    2003-01-01

    Angesichts des neuen Phänomens der sozialen Exklusion wird soziale Gerechtigkeit nicht mehr nur über die Verteilung von Gütern hergestellt, vielmehr spielt auch die Ebene der Partizipation eine Rolle. Anerkennung ist eine Grundvoraussetzung für Partizipation. Die Verfasser diskutieren Fragen der Unternehmensethik auf der Dimension der Anerkennung. Sie votieren für ein normatives Stakeholder-Management als freiwillige Verpflichtung, das auch strategischen Anforderungen gerecht werden kann. Als...

  3. Communication Support for People with ALS

    OpenAIRE

    David Beukelman; Susan Fager; Amy Nordness

    2011-01-01

    Almost all people with amyotrophic lateral sclerosis (ALS) experience a motor speech disorder, such as dysarthria, as the disease progresses. At some point, 80 to 9 5 % of people with ALS are unable to meet their daily communication needs using natural speech. Unfortunately, once intelligibility begins to decrease, speech performance often deteriorates so rapidly that there is little time to implement an appropriate augmentative and alternative communication (AAC) intervention; therefore, app...

  4. In situ (Al3Zr + Al2O3np)/2024Al metal matrix composite with novel reinforcement distributions fabricated by reaction hot pressing

    International Nuclear Information System (INIS)

    Highlights: •(Al3Zr + Al2O3np)/2024Al MMC with a novel network distribution was tailored. •Al3Zr and Al2O3np were in situ synthesized at 740 °C using the 2024Al–ZrO2 system. •The effect of sintering parameters on Al3Zr morphology was investigated. •Influence of Al3Zr morphology on tensile properties of the composite was studied. -- Abstract: In situ hybrid (Al3Zr + Al2O3np)/2024Al metal matrix composites with unique controlled reinforcement distributions were fabricated using low energy ball milling and reactive hot pressing. The reaction system between 2024Al and ZrO2 was studied using differential thermal analysis (DTA). In situ formed aluminium oxide (Al2O3) and zirconium tri-aluminide (Al3Zr) with varying morphology and sizes were produced under different fabricating conditions. Al3Zr with varying morphologies such as particle, plate and flakes were observed. With a total 10 vol.% of reinforcements, the composite containing a three-dimensional network of closely spaced in situ synthesized Al3Zr and Al2O3 particles had a YS of 175 MPa and a UTS of 261 MPa, effectively strengthening the 2024Al matrix. The effect of different sintering conditions on the microstructure and tensile properties of the composite was systematically investigated

  5. Thermodynamics and surface properties of liquid Al-Ga and Al-Ge alloys

    Energy Technology Data Exchange (ETDEWEB)

    Anusionwu, B.C. [Abdus Salam Int. Centre for Theoretical Physics, Trieste (Italy); Federal University of Technology, Department of Physics, Owerri (Nigeria); Adebayo, G.A. [Abdus Salam Int. Centre for Theoretical Physics, Trieste (Italy); University of Agriculture, Department of Physics, Abeokuta (Nigeria); Madu, C.A. [Federal University of Technology, Department of Physics, Owerri (Nigeria)

    2009-11-15

    The surface properties of Al-Ga and Al-Ge liquid alloys have been theoretically investigated at a temperature of 1100 K and 1220 K respectively. For the Al-Ga system, the quasi chemical model for regular alloy and a model for phase segregating alloy systems were applied, while for the Al-Ge system the quasi chemical model for regular and compound forming binary alloys were applied. In the case of Al-Ga, the models for the regular alloys and that for the phase segregating alloys produced the same value of order energy and same values of thermodynamic and surface properties, while for the Al-Ge system, the model for the regular alloy reproduced better the thermodynamic properties of the alloy. The model for the compound forming systems showed a qualitative trend with the measured values of the thermodynamic properties of the Al-Ge alloy and suggests the presence of a weak complex of the form Al{sub 2}Ge{sub 3}. The surface concentrations for the alloys show that Ga manifests some level of surface segregation in Al-Ga liquid alloy while the surface concentration of Ge in Al-Ge liquid alloy showed a near Roultian behavior below 0.8 atomic fraction of Ge. (orig.)

  6. Thermodynamics and surface properties of liquid Al-Ga and Al-Ge alloys

    Science.gov (United States)

    Anusionwu, B. C.; Adebayo, G. A.; Madu, C. A.

    2009-11-01

    The surface properties of Al-Ga and Al-Ge liquid alloys have been theoretically investigated at a temperature of 1100 K and 1220 K respectively. For the Al-Ga system, the quasi chemical model for regular alloy and a model for phase segregating alloy systems were applied, while for the Al-Ge system the quasi chemical model for regular and compound forming binary alloys were applied. In the case of Al-Ga, the models for the regular alloys and that for the phase segregating alloys produced the same value of order energy and same values of thermodynamic and surface properties, while for the Al-Ge system, the model for the regular alloy reproduced better the thermodynamic properties of the alloy. The model for the compound forming systems showed a qualitative trend with the measured values of the thermodynamic properties of the Al-Ge alloy and suggests the presence of a weak complex of the form Al2Ge3. The surface concentrations for the alloys show that Ga manifests some level of surface segregation in Al-Ga liquid alloy while the surface concentration of Ge in Al-Ge liquid alloy showed a near Roultian behavior below 0.8 atomic fraction of Ge.

  7. Heterogeneous nucleation of solid Al from the melt by Al 3 Ti : Molecular dynamics simulations

    KAUST Repository

    Wang, Junsheng

    2010-10-27

    It has been known experimentally for some time that Al3 Ti is a powerful nucleant for the solidification of aluminum from the melt; however, a full microscopic understanding is still lacking. To develop this understanding, we have performed molecular dynamics simulations of the nucleation and early stages of growth using published embedded atom method potentials for Al-Ti, but modified by us to stabilize the D 022 structure. We discover that Al3 Ti can indeed be very effective in promoting the growth of solid Al but the manner in which growth takes place depends sensitively on the surface on which the Al nucleates. In particular, complete growth of solid Al from the liquid on the (001) and (110) surfaces of Al3 Ti occurs at a lower temperature than on the (112) surface. This anisotropy agrees with observations in previous experiments. We explain this observation in terms of interfacial energies. On the preferential (111) surface of Al the solid-liquid interfacial energy is highest while the solid-vacuum energy is lowest. Our simulations also show that the extent of ordering taking place in liquid Al close to the Al 3 Ti substrate above the melting point correlates well with the effectiveness of the substrate as a nucleant below the melting temperature: this could provide a computationally efficient scheme to identify good nucleants. © 2010 The American Physical Society.

  8. Corrosion behavior of solid solution (Ti,Al)N as a function of Al concentration

    Energy Technology Data Exchange (ETDEWEB)

    Larijani, M.M.; Seyedi, H. [Nuclear Science and Technology Research Institute, P. O. Box 31485-498, Karaj (Iran, Islamic Republic of); Manouchehrian, M. [Department of Physics, Science Faculty, South Tehran Branch, Islamic Azad University, Tehran (Iran, Islamic Republic of); Yari, M. [Engineering Department Materials, Science and Research Branch, Islamic Azad University, Tehran (Iran, Islamic Republic of)

    2012-08-15

    In this work, a series of (Ti, Al) N coatings with different Al contents were deposited on 304 stainless steel substrates by Hollow Cathode Discharge (HCD) method. The coatings were grown on 304 stainless steel substrates at 400 C. The coatings were characterized using energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), atomic force microscopy (AFM), and microhardness test. The XRD confirmed the transition from TiN phase to (Ti, Al) N phase and then to AlN phase with increasing Al concentration in the solid solution. It was found that with increasing Al concentration the hardness of the coatings initially increased up to a maximum value of about 30 GPa at around 32 at.% of Al and then the coating hardness decreased rapidly with further increase of Al content (Al > 32 at.%). The potentiodynamic polarization analysis was carried out in 3.5 wt.% NaCl solutions to study the corrosion resistance of the coatings. From the corrosion test it can be inferred that the amount of Al atoms in the coatings plays an important role for reducing the corrosion. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  9. Clinical trials for neuroprotection in ALS.

    Science.gov (United States)

    Siciliano, G; Carlesi, C; Pasquali, L; Piazza, S; Pietracupa, S; Fornai, F; Ruggieri, S; Murri, L

    2010-07-01

    Owing to uncertainty on the pathogenic mechanisms underlying motor neuron degeneration in amyotrophic lateral sclerosis (ALS) riluzole remains the only available therapy, with only marginal effects on disease survival. Here we review some of the recent advances in the search for disease-modifying drugs for ALS based on their putative neuroprotective effetcs. A number of more or less established agents have recently been investigated also in ALS for their potential role in neuroprotection and relying on antiglutamatergic, antioxidant or antiapoptotic strategies. Among them Talampanel, beta-lactam antibiotics, Coenzyme Q10, and minocycline have been investigated. Progress has also been made in exploiting growth factors for the treatment of ALS, partly due to advances in developing effective delivery systems to the central nervous system. A number of new therapies have also been identified, including a novel class of compounds, such as heat-shock protein co-inducers, which upregulate cell stress responses, and agents promoting autophagy and mitochondriogenesis, such as lithium and rapamycin. More recently, alterations of mRNA processing were described as a pathogenic mechanism in genetically defined forms of ALS, as those related to TDP-43 and FUS-TLS gene mutations. This knowledge is expected to improve our understanding of the pathogenetic mechanism in ALS and developing more effective therapies. PMID:20406180

  10. DISTINGSI DAN DIASPORA TASAWUF ABÛ AL-HASAN AL-SHÂDHILÎ

    Directory of Open Access Journals (Sweden)

    Saifulah Saifulah

    2015-09-01

    Full Text Available This article discusses Shâdhilîyah, one of the most recognized sufi orders, which possesses quite distinct aspects in the conception of its mystical teachings. This sufi order was founded by Abû al-H}asan al-Shâdhilî, a sufi who has moderate and open view of the worldly life. Al-Shâdhilî explained about how a sufi should behave towards and deal with worldly matters. Although al-Shâdhilî asserted that a person who practice tasawwuf should not pay more adoration on the worldly matters (hubb al-dunyâ, the person does not have to abhor and leave such lively aspects as wealth and position behind. The most important thing to a sufi, according to al-Shadhili, is how he obeys the requirements of shar‘ by avoiding away from immoral deeds and at the same time recognizing God in his heart (ma‘rifat Allâh. Al-Shâdhilî initiated tasawuf ‘amalî which is affiliated to the Ahl al-Sunnah wa al-Jamâ‘ah school, an Islamic mystical thought that adheres to the principles of sharî‘ah based on the foundation of al-Qur’ân dan H}adîth. The concept of al-Shâdhilî’s tasawuf has been subsequently revealed into the great sufi order spectrum, namely al-Shâdhilîyah, where during its historical development this sufi order has led to the emergence of many branches with different names.Keywords: Shâdhilîyah, open view, hubb al-dunyâ, ma‘rifat Allâh.

  11. Al4C3 Hydration Thermochemical Analysis for Burned Carbon-containing Refractories with Al

    Institute of Scientific and Technical Information of China (English)

    YANG Ding'ao; YU Zhiming; FAN Liuwu

    2003-01-01

    In this paper, X-ray diffractogram analysis and SEM observation of Al4 C3 formed at high temperature from carbon-containing refractories with Al have been carried out.Aluminum added to carbon-containing refractories reacts with C(s)to form Al4 C3(s) gradually during heating from 600 ℃ to 1200℃.It is considered that the interlocked structure of Al4 C3 plate crystals promotes the outstanding increase of hot modulus of rupture of carbon-containing refractories with Al. The HMOR of carbon-containing refractories added with Al additive from 0 to 5wt% increases by 2.8 times being from 6.5MPa to 18.2MPa.After a thermochemical calculation for hydration reaction processes of Al4 C3 and H2O(g), the equilibrium partial pressure chart of H2O(g)in H2O-Al4C3-Al(OH)3 system vs various temperatures has been attained . The H2O (g) partial pressure in the air needed for the Al4 C3 hydration reaction is no more than 10~18 atm at the temperature below 120℃.It is considered that the burned carbon-containing refractories with Al is extremely easy to hydrate and the cracking of burned carbon-containing refractories is generated because that the hydration expansion is 2.11 times during transforming from Al4 C3 to Al(OH)3.The fundamental measure against hydration of the refractories is to insulate the refractories from H2O(g)by various means such as pitch impregnation or other sealing materials.

  12. Machinability of Al-SiC metal matrix composites using WC, PCD and MCD inserts

    Directory of Open Access Journals (Sweden)

    Beristain, Jokin

    2014-03-01

    Full Text Available The aim of this work is the study of the machinability of aluminium-silicon carbide Metal Matrix Composites (MMC in turning operations. The cutting tools used were hard metal (WC with and without coating, different grades and geometries of Poly-Crystalline Diamond (PCD and Mono-Crystalline Diamond (MCD. The work piece material was AMC225xe, composed of aluminium-copper alloy AA 2124 and 25% wt of SiC, being the size of the SiC particles around 3 μm. Experiments were conducted at various cutting speeds and cutting parameters in facing finishing operations, measuring the surface roughness, cutting forces and tool wear. The worn surface of the cutting tool was examined by Scanning Electron Microscope (SEM. It was observed that the Built Up Edge (BUE and stuck material is higher in the MCD tools than in the PCD tools. The BUE acts as a protective layer against abrasive wear of the tool.El objetivo de este trabajo es el estudio de la maquinabilidad del material compuesto de matriz metálica aluminio-carburo de silicio en operaciones de torneado. Las herramientas de corte utilizadas han sido de metal duro con y sin recubrimiento, diferentes grados de diamante policristalino (PCD y diamante monocristalino (MCD. El material mecanizado ha sido AMC225xe, compuesto de la aleación de aluminio AA 2124 con un 25% en peso de partículas de SiC con un tamaño medio de 3 μm. Los experimentos se han realizado con diferentes velocidades de corte en una operación de refrentado, midiendo la rugosidad superficial, las fuerzas y el desgaste de la herramienta. La superficie desgastada de la herramienta ha sido examinada en el microscopio electrónico (SEM. Se ha observado que el filo recrecido y el material adherido son mayores en el caso de las herramientas de MCD que en las de PCD. El filo recrecido actúa como una capa protectora contra la abrasión.

  13. Prinsip Pendidikan Karakter dalam Islam: Studi Komparasi Pemikiran Al-Ghazali dan Burhanuddin Al-Zarnuji

    Directory of Open Access Journals (Sweden)

    Agus Setiawan

    2014-06-01

    Full Text Available The impelemtantion of character education that is done by the Indonesian government recently has been provoked by al-Ghazali and Burhanuddin al-Zarnuji long ago. It was proven by some written thoughts of al-Ghazali and Burhanuddin al-Zarnuji. They were very famous scientists in their era and widely welknown as educational experts who produced some phenomenal thoughts many people use today. Al-Ghazali and Burhanuddin al-Zarnuji lived in the era of Bani Abbasiyah monarchy, but Both of them lived in different era. Al-Ghazali was born first, then Burhanuddin al-Zarnuji. They had different mazhab, al-Ghazali went to the traditional principle of mazhab Syafi’I and Burhanuddin al-Zarnuji went to the modern principle of mazhab Hanafi. The differences, of course, would create a different thought. Still, they might have a similar principle of Islamic character education. The thoughts of character education of al-Ghazali have been poured in the “Ayyuha Walad” focusing to the students’ character building characterized by religiously obedient, skillfull of general and religious knowledge, socially helpful, affectionate, generous, good citizen, and coloring the society. Some applicable thoughts of character education of Ayyuha al-Walad of al-Gazhali to the contemporary education are: the balance of the happiness purposes of the recent life and the life after death, qana’ah and tawakal, affectionate, caring other, patience, honesty, philanthrophy, social works, generousity, democratic, peace makers, and patriotic. Those characters are also directed in the islamic character education nowdays. So that, the thoughts of al-Ghazali positively and responsively are absorbed by the Indonesian government to build the national character widely implementing in the national curriculum based on the local wisdom and the Islamic values. In the end, the students are able to live happily based on the Islamic rules by implementing the good behavior. Similar to the al

  14. Morphology of phase separation in AlN-Al2OC and SiC-AlN ceramics

    International Nuclear Information System (INIS)

    Solid solutions in the AIN-Al2OC and SiC-AlN systems were fabricated by hot-pressing powder mixtures in graphite dies. X-ray diffraction showed the samples to be single phases of 2H structure. The samples were annealed between 1600 degrees and 1900 degrees C for up to 1000 h. In the SiC-AlN system, optical microscopy and X-ray diffraction failed to reveal microstructural or phase changes. However, electron microscopy showed that samples had decomposed. Streaking of diffraction spots occurred along directions orthogonal to [012] planes (∼43 degrees off the c axis), which is approximately the direction along which the elastic energy function is a minimum. The orientation-dependent Young's modulus was also a minimum along this direction. In AlN-Al2OC, optical microscopy and X-ray diffraction indicated the occurrence of decomposition. The precipitates were disk-shaped with [001] orthogonal to the disks. The occurrence of decomposition along the [001] direction suggests that it is the elastically soft direction

  15. 60Co gamma radiation effect on AlGaN/AlN/GaN HEMT devices

    Institute of Scientific and Technical Information of China (English)

    WANG Yan-Ping; LUO Yin-Hong; WANG Wei; ZHANG Ke-Ying; GUO Hong-Xia; GUO Xiao-Qiang; WANG Yuan-Ming

    2013-01-01

    The testing techniques and experimental methods of the 60Co gamma irradiation effect on AlGaN/AlN/GaN high electron mobility transistors (HEMTs) are established.The degradation of the electrical properties of the device under the actual radiation environment are analyzed theoretically,and studies of the total dose effects of gamma radiation on AlGaN/AlN/GaN HEMTs at three different radiation bias conditions are carried out.The degradation patterns of the main parameters of the AlGaN/AlN/GaN HEMTs at different doses are then investigated,and the device parameters that were sensitive to the gamma radiation induced damage and the total dose level induced device damage are obtained.

  16. Kinetic Monte Carlo of transport processes in Al/AlOx/Au-layers: Impact of defects

    Science.gov (United States)

    Weiler, Benedikt; Haeberle, Tobias; Gagliardi, Alessio; Lugli, Paolo

    2016-09-01

    Ultrathin films of alumina were investigated by a compact kMC-model. Experimental jV-curves from Al/AlOx/Au-junctions with plasma- and thermal-grown AlOx were fitted by simulated ones. We found dominant defects at 2.3-2.5 eV below CBM for AlOx with an effective mass mox ∗= 0.35 m0 and a barrier EB ,A l /A l O x≈2.8 eV in agreement with literature. The parameterization is extended to varying defect levels, defect densities, injection barriers, effective masses and the thickness of AlOx. Thus, dominant charge transport processes and implications on the relevance of defects are derived and AlOx parameters are specified which are detrimental for the operation of devices.

  17. Scattering induced by Al segregation in AlGaN/GaN heterostructures

    International Nuclear Information System (INIS)

    The effect of Al segregation near dislocations on the mobility of two-dimensional electron gas in AlGaN/GaN heterostructure-based high-electron-mobility transistors was investigated. Exponentially varied composition fluctuation was effective in describing Al segregation near dislocations when calculating scattering behavior. Mobility, which was limited by Al segregation surrounding dislocation lines, was calculated to be in the order of 103 cm2/Vs to 106 cm2/Vs. Results indicated that the mobility in AlGaN/GaN heterojunction was enhanced upon the reduction of dislocation density at low temperature. This study contributes to generating higher electron mobility in AlGaN/GaN heterojunctions

  18. Scattering induced by Al segregation in AlGaN/GaN heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xiwen; Lu, Yanwu, E-mail: ywlu@bjtu.edu.cn [Department of Physics, Beijing Jiaotong University, Beijing 100044 (China); Ji, Dong [School of Electrical, Computer and Energy Engineering, Arizona State University, Tempe, Arizona 85281 (United States)

    2015-08-17

    The effect of Al segregation near dislocations on the mobility of two-dimensional electron gas in AlGaN/GaN heterostructure-based high-electron-mobility transistors was investigated. Exponentially varied composition fluctuation was effective in describing Al segregation near dislocations when calculating scattering behavior. Mobility, which was limited by Al segregation surrounding dislocation lines, was calculated to be in the order of 10{sup 3} cm{sup 2}/Vs to 10{sup 6} cm{sup 2}/Vs. Results indicated that the mobility in AlGaN/GaN heterojunction was enhanced upon the reduction of dislocation density at low temperature. This study contributes to generating higher electron mobility in AlGaN/GaN heterojunctions.

  19. Determination of Al Composition in Strained AlGaN Layers

    Institute of Scientific and Technical Information of China (English)

    ZHOU Sheng-Qiang; WU Ming-Fang; YAO Shu-De

    2005-01-01

    @@ Alx Ga1-x N/GaN heterostructures are grown on c-sapphire with the Al composition x from 0.2 to 0.4 and thicknesses from 20nm to 30nm. The lattice parameters a and c are determined from 2θ/ω scan. The AlGaN layers are found to be under tensile strain by using x-ray diffraction. Vegard's law induces a large deviation in Al composition determination by only considering the linear relationship between one lattice parameter (a or c) and Al composition. The accurate determination of Al composition is only possible with consideration of both the lattice parameters a and c, by assuming the tetragonal distortion in the AlGaN layer. Additionally, the results obtained from x-ray diffraction are verified by Rutherford backscattering.

  20. Effects of Al(III and Nano-Al13 Species on Malate Dehydrogenase Activity

    Directory of Open Access Journals (Sweden)

    Rong Fu Chen

    2011-05-01

    Full Text Available The effects of different aluminum species on malate dehydrogenase (MDH activity were investigated by monitoring amperometric i-t curves for the oxidation of NADH at low overpotential using a functionalized multi-wall nanotube (MWNT modified glass carbon electrode (GCE. The results showed that Al(III and Al13 can activate the enzymatic activity of MDH, and the activation reaches maximum levels as the Al(III and Al13 concentration increase. Our study also found that the effects of Al(III and Al13 on the activity of MDH depended on the pH value and aluminum speciation. Electrochemical and circular dichroism spectra methods were applied to study the effects of nano-sized aluminum compounds on biomolecules.

  1. 60Co gamma radiation effect on AlGaN//AlN/GaN HEMT devices

    International Nuclear Information System (INIS)

    The testing techniques and experimental methods of the 60Co gamma irradiation effect on AlGaN/AlN/GaN high electron mobility transistors (HEMTs) are established. The degradation of the electrical properties of the device under the actual radiation environment are analyzed theoretically, and studies of the total dose effects of gamma radiation on AlGaN/AlN/GaN HEMTs at three different radiation bias conditions are carried out. The degradation patterns of the main parameters of the AlGaN/AlN/GaN HEMTs at different doses are then investigated, and the device parameters that were sensitive to the gamma radiation induced damage and the total dose level induced device damage are obtained. (authors)

  2. Microscopic Properties of Long-Period Ordering in Al-Rich TiAl Alloys

    Science.gov (United States)

    Hata, S.; Nakano, T.; Kuwano, N.; Itakura, M.; Matsumura, S.; Umakoshi, Y.

    2008-07-01

    The ordering mechanism of long-period superstructures (LPSs) in Al-rich TiAl alloys has been investigated by high-resolution transmission electron microscopy (HRTEM). The LPSs are classified in terms of arrangements of base clusters with different shapes and compositions formed in Ti-rich (002) layers of L10-TiAl matrix: square Ti4Al, fat rhombus Ti3Al, and lean rhombus Ti2Al type clusters. The HRTEM observations revealed that antiphase boundaries of long-range-ordered LPS domains and short-range-ordered microdomains are constructed by various space-filling arrangements of the base clusters. Such a microscopic property characterized by the base clusters and their arrangements is markedly analogous to that of the {left< {{text{1,1/2,0}}} rightrangle } * special-point ordering alloys such as Ni-Mo.

  3. Generation and evolution of nanoscale AlP and Al{sub 13}Fe{sub 4} particles in Al-Fe-P system

    Energy Technology Data Exchange (ETDEWEB)

    Qiao, Huan; Gao, Tong; Zhu, Xiangzhen; Wu, Yuying; Qian, Zhao; Liu, Xiangfa, E-mail: xfliu@sdu.edu.cn

    2015-02-15

    Highlights: • Diffusion and gradual solid reactions between Al and Fe{sub x}P phases in Al-Fe-P alloy were investigated. • Nanoscale AlP clusters are in-situ generated and evolve during the whole process. • This novel Al-Fe-P alloy has an excellent low-temperature refining performance on hypereutectic Al-Si alloy. - Abstract: In this paper, the gradual solid reactions between Al and Fe{sub x}P phases in Al-Fe-P alloy were investigated. The results show that the whole reaction process undergoes four main stages: the diffusion of Al atom, the generation of (Al, Fe, P) intermediate compound, the precipitation of nano AlP and Al{sub 13}Fe{sub 4} clusters and their growth to submicron particles. The microstructure of Fe-P particles evolves from the “egg-type”, the “sponge-type” to the “sesame-cake” structure. AlP and Al{sub 13}Fe{sub 4} nano phases have in-situ generated and evolved during the whole process. The gradual reaction mechanism has been discussed. Furthermore, a novel Al-Fe-P alloy which contains (Al, Fe, P) intermediate compounds and nano AlP particles has been synthesized and its low-temperature refining performance on A390 alloy has also been investigated.

  4. Grain refinement of hypoeutectic Al-Si alloy prepared with ELTA by Al-4B master alloy

    Institute of Scientific and Technical Information of China (English)

    WANG Ming-xing; MENG Xiang-yong; LIU Zhi-yong; LIU Zhong-xia; WENG Yong-gang; SONG Tian-fu; YANG Sheng

    2006-01-01

    Electrolytic low-titanium aluminum (ELTA) was produced by adding TiO2 powder to an industrial aluminum electrolyzer.The grain refining effect of Al-4B master alloy in the hypoeutectic Al-Si alloy prepared by using ELTA was investigated, and compared with those of Al-5Ti, Al-5Ti-1B and Al-4B master alloys in the similar alloy prepared by using pure Al. The results indicate that when Al-4B is added to the melt of the alloy prepared by using ELTA in terms of the Ti/B mass ratio of 5:1, the grain refining effect is better than those of Al-5Ti, Al-5Ti-1B and Al-4B master alloys. Thus, using Al-4B to refine the grain of Al-Si alloys prepared by using ELTA will possibly become a feasible way of obtaining Al-Si alloy with homogeneous and fine microstructure.

  5. In-Situ Synthesis of AlN Powders and Composite AlN Powders with Yttrium Addition

    Institute of Scientific and Technical Information of China (English)

    郑新和; 王群; 林志浪; 李春国; 周美玲

    2002-01-01

    Using Al-Mg and Al-Mg-Y alloys as raw materials and nitrogen as gas reactants, AlN powders and composite AlN powders by in-situ synthesis method were prepared. AlN lumps prepared by the nitriding of Al-Mg and Al-Mg-Y alloys have porous microstructure, which is favorable for pulverization. They have high purity, containing 1.23%(mass fraction) oxygen impurity, and consisted of AlN single phase. The average particle size of AlN powders is 6.78 μm. Composite AlN powders consist of AlN phases and rare earth oxide Y2O3 phase. The distribution of particle size of AlN powders shows two peaks. In view of packing factor, AlN powders with such size distribution can easily be sintered to high density.

  6. Observation of Electronic Shells and Characteristic Products from Mass Abundance Spectra of Al Cluster and Al-C Cluster Anions

    Institute of Scientific and Technical Information of China (English)

    LIU Bing-Chen; ZHAI Hua-Jin; ZHOU Ru-Fang; NI Guo-Quan; XU Zhi-Zhan

    2000-01-01

    Using a laser vaporization/pulsed molecular beam cluster source, Al cluster anions and Al-C mixed cluster anions are produced and recorded by a time of flight mass spectrometer. Mass abundance spectra of the Al cluster anions in the size range from Al2 to Al42 show that Al-13, Al23, Al35, and slightly, Al37 are local maxima, as predicted by the electronic jellium model. Mixed clusters Aln C- and Aln C2 are also shown, among which the most abundant species are Al3 C2 , Al6 C2 , Al7 C- and Al7 C2 in the small size range. The formation mechanism of these products is discussed.

  7. TEM characterization of oxidized AlGaAs/AlAs nonlinear optical waveguides

    OpenAIRE

    Guillotel, E; Langlois, C.; Ghiglieno, F.; Leo, G.; Ricolleau, C.

    2010-01-01

    Abstract The internal interfaces of multilayer Al x Ga 1-x As/AlAs nonlinear optical waveguides are investigated by high-angle annular-dark-field and energy-filtered scanning transmission electron microscopy, before and after partial wet oxidation of AlAs layers. Via a simple phenomenological model, the corresponding roughness parameters allow predicting the scattering-induced waveguide optical losses, which are in reasonable agreement with the experimental value of 0.5 cm -1. We also find...

  8. Two-Phase (TiAl+TiCrAl) Coating Alloys for Titanium Aluminides

    Science.gov (United States)

    Brady, Michael P. (Inventor); Smialek, James L. (Inventor); Brindley, William J. (Inventor)

    1998-01-01

    A coating for protecting titanium aluminide alloys, including the TiAl gamma + Ti3Al (alpha(sub 2)) class, from oxidative attack and interstitial embrittlement at temperatures up to at least 1000 C. is disclosed. This protective coating consists essentially of titanium, aluminum. and chromium in the following approximate atomic ratio: Ti(41.5-34.5)Al(49-53)Cr(9.5-12.5)

  9. Modified Mechanism of Eutectic Silicon in Al2O3/Al-Si Alloy

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Al2O3/Al-Si alloy composite was manufactured by squeeze casting. The morphology of the eutectic silicon in the composite was observed by scanning electronic microscope (SEM), and the modified mechanism of eutectic silicon in the composite was approached. The alumina fiber in the composite can trigger twin during the growth of Al-Si eutectic and lead to the modification of eutectic silicon near the fiber.

  10. Melt Processing and Characterization of Al-SiC Nanocomposite, Al, and Mg Foam Materials

    OpenAIRE

    Ahmed M. Nabawy; Khalil Abdelrazek Khalil; Al-Ahmari, Abdulrahman M.; Sherif, El-Sayed M.

    2016-01-01

    In the present work, metallic foams of Al, Mg and an Al-SiC nanocomposite (MMNC) have been fabricated using a new manufacturing technique by employing melt infiltration assisted with an electromagnetic force. The aim of this investigation was to study and to develop a reliable manufacturing technique consisting of different types of metallic foams. In this technique, an electromagnetic force was used to assist the infiltration of Al-SiC slurry and of pure liquid metal into a leachable pattern...

  11. Effect of the interface in laminated composites of Al-1100 and Al-2024

    International Nuclear Information System (INIS)

    Laminated composites consisting of alternating layers of Al-1100 and Al-2024 were produced by hot rolling, with 45% Al-2024 volume fraction. These composites were subjected to cyclic thermal treatment (various numbers of cycles) and to isothermal treatment (various numbers of cycles) and to isothermal treatment (at peak temperature and for times equivalent to those of the thermal cycles. Microhardness, tensile and fatigue crack arrester modes) were studied in the initial state and after treatments. (E.G.)

  12. Growth of CdTe: Al films; Crecimiento de peliculas de CdTe: Al

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez A, M.; Zapata T, M. [CICATA-IPN, 89600 Altamira, Tamaulipas (Mexico); Melendez L, M. [CINVESTAV-IPN, A.P. 14-740, 07000 Mexico D.F. (Mexico); Pena, J.L. [CINVESTAV-IPN, A.P. 73 Cordemex, 97310 Merida, Yucatan (Mexico)

    2006-07-01

    CdTe: AI films were grown by the close space vapor transport technique combined with free evaporation (CSVT-FE). The Aluminum (Al) evaporation was made by two kinds of sources: one made of graphite and the other of tantalum. The films were deposited on glass substrates. The Al source temperature was varied maintaining the CdTe source temperature fixed as well as the substrate temperature. The films were characterized by x-ray energy dispersive analysis (EDAX), x-ray diffraction and optical transmission. The results showed for the films grown with the graphite source for Al evaporation, the Al did not incorporate in the CdTe matrix, at least to the level of EDAX sensitivity; they maintained the same crystal structure and band gap. For the samples grown with the tantalum source, we were able to incorporate the Al. The x-ray diffraction patterns show that the films have a crystal structure that depends on Al concentration. They were cubic up to 2.16 at. % Al concentration; for 19.65 at. % we found a mixed phase; for Al concentration higher than 21 at. % the films were amorphous. For samples with cubic structure it was found that the lattice parameter decreases and the band gap increases with Al concentration. (Author)

  13. Strain Rates and Grain Growth in Al 5754 and Al 6061 Friction Stir Spot Welds

    Science.gov (United States)

    Gerlich, A.; Yamamoto, M.; North, T. H.

    2007-06-01

    The stir zone temperature and microstructures are compared in friction stir spot welds produced in Al 5754 and Al 6061 alloys. Electron backscattered diffraction was used to determine the relationship between tool rotation speed during welding and final stir zone grain size. Comparison of the grain sizes in rapidly quenched welds with those in air-cooled joints confirmed that grain growth occurred only in Al 6061 spot welds. There was no evidence of abnormal grain growth in the stir zones of Al 6061 welds; the final grain size could be represented using an Arrhenius equation. The strain rates during welding were determined by incorporating the stir zone temperature and average subgrain sizes in quenched spot welds in the Zener-Hollomon relation. When the tool rotation speed increased from 750 to 3000 RPM, the strain rate values ranged from 180 to 497 s-1 in Al 5754 spot welds and from 55 to 395 s-1 in Al 6061 spot welds. It is suggested that a no-slip boundary condition may be appropriate during numerical modeling of Al 5754 and 6061 friction stir spot welding. This is not the case during Al 7075, Al 2024, and Mg-alloy AZ91 spot welding because spontaneous melting facilitates slippage at the tool contact interface.

  14. Microstructure and thermal stability of mechanically alloyed Al3Ti/Al alloy

    Institute of Scientific and Technical Information of China (English)

    林建国; 魏浩岩; 黄正

    2001-01-01

    The microstructure stability of Al3Ti/Al alloy prepared by mechanical alloying (MA) was investigated in the simulating environment in which they may be used. The results show that the MA alloy possesses fine microstructure (the grain size is about 0.5  μm). After cycling loaded followed by heat exposure at 350  ℃ for 24  h, no microstructure coarsening of the alloy occurred, which means that the Al3Ti/Al alloy behaves good microstructure stability at high temperature. The compression yield strength of the alloy reaches up to 247  MPa at 350  ℃.

  15. AlN/IDT/AlN/Sapphire SAW Heterostructure for High-Temperature Applications.

    Science.gov (United States)

    Legrani, Ouarda; Aubert, Thierry; Elmazria, Omar; Bartasyte, Ausrine; Nicolay, Pascal; Talbi, Abdelkrim; Boulet, Pascal; Ghanbaja, Jaafar; Mangin, Denis

    2016-06-01

    Recent studies have evidenced that Pt/AlN/Sapphire surface acoustic wave (SAW) devices are promising for high-temperature high-frequency applications. However, they cannot be used above 700°C in air atmosphere as the Pt interdigital transducers (IDTs) agglomerate and the AlN layer oxidizes in such conditions. In this paper, we explore the possibility to use an AlN protective overlayer to concurrently hinder these phenomena. To do so, AlN/IDT/AlN/Sapphire heterostructures undergo successive annealing steps from 800°C to 1000°C in air atmosphere. The impact of each step on the morphology, microstructure, and phase composition of AlN and Pt films is evaluated using optical microscopy, scanning and transmission electron microscopy (SEM and TEM), X-ray diffraction (XRD), and secondary ion mass spectroscopy (SIMS). Finally, acoustical performance at room temperature of both protected and unprotected SAW devices are compared, as well as the effects of annealing on these performance. These investigations show that the use of an overlayer is one possible solution to strongly hinder the Pt IDTs agglomeration up to 1000°C. Moreover, AlN/IDT/AlN/Sapphire SAW heterostructures show promising performances in terms of stability up to 800°C. At higher temperatures, the oxidation of AlN is more intense and makes it inappropriate to be used as a protective layer. PMID:27076407

  16. Microstructure and mechanical properties of Al2O3/TiAl composite

    Institute of Scientific and Technical Information of China (English)

    AI Tao-tao; WANG Fen; ZHU Jian-feng

    2006-01-01

    Al2O3/TiAl composites were fabricated by PAXD (pressure-assisted exothermic dispersion) method. The effects of Nb2O5 content on the microstructure and mechanical properties of the composites were investigated. The results show that the ultimate phases of the composite consist of TiAl, Ti3Al, Al2O3 and a small amount of NbAl3. SEM reveals that a submicron γ+(α2/γ) dual phases structure can be presented after sintered at 1 200 ℃. Furthermore, with the increase of Nb2O5 content, the ratio of TiAl to Ti3Al phase decreases correspondingly, the grains of the composites are remarkably refined, and the produced Al2O3 particles are uniformly dispersed. When 6% Nb2O5 is added, the composite has the best comprehensive properties. It exhibits a Vickers hardness of 4.77 GPa and a bending strength of 642 MPa. Grain-refinement and dispersion-strengthening are the main strengthening mechanisms.

  17. Coating of a layer of Au on Al13 : The findings of icosahedral Al@Al12Au20- and Al12Au202- fullerenes using ab initio pseudopotential calculations

    Science.gov (United States)

    Kumar, Vijay

    2009-02-01

    We report results of ab initio pseudopotential calculations on the nanocoating of gold on an icosahedral Al13 cluster and the findings of icosahedrally symmetric endohedral Al@Al12Au20- and empty cage Al12Au202- compound fullerenes formed of metal atoms. Twelve Al atoms cap the pentagonal faces of a dodecahedral Au20 cage in which each Au atom has three Al atoms and three Au atoms as nearest neighbors. Mixing of Al13 and Au20 magic clusters leads to a large heat of formation of 0.55 eV/atom and high stability of the Al@Al12Au20 compound fullerene. The binding energies of Al12Au20 and Al@Al12Au20 are 3.017 and 3.007 eV/atom, respectively, which are much larger than 2.457 eV/atom for Au32 fullerene, leading to the possibility of their high abundance.

  18. Epistemologi Penafsiran Ilmiah al-Qur’an

    Directory of Open Access Journals (Sweden)

    Sujiat Zubaidi Saleh

    2011-04-01

    Full Text Available The main objective in interpretating al-Qur’an is to explain the will of God and the operationalization of the will in the field of faith, laws, or ethics. At the phase of Islamic civilization, when the linguistic and philosophy science codified, raises the various method (manhaj, and interpretation streams (ittijahat, exegesis school (madzhab of al-Qur’an. In addition, also found in various shades of interpretation such as: fiqhi, kalami, balaghi, and isyari/ sufi, even philosophical. It was also discovered methods of tafsir ‘ilmi oriented to the utilization of the discovering science in order to prove the truth of scientific fact. The last pattern was ignited pro and contra among scholars and mufassir. As we know that alQur’an was not descended in the condition of cultural vacuum but it is a form of dialectics and the response to the condition and social situation, politic, and religion. This is relevant to the characteristics of al-Qur’an which can be applied throughout the periods. As we understood that interpretation is one of reflections of thought and civilization products. It always developed and influenced by the dynamics of human civilization, so in its development, science and al-Qur’an can be brought together in dialogue, although with some prerequisites specified interpretation.

  19. Direct laser cooling Al+ ions optical clocks

    CERN Document Server

    Zhang, J; Luo, J; Lu, Z H

    2016-01-01

    Al$^+$ ions optical clock is a very promising optical frequency standard candidate due to its extremely small blackbody radiation shift. It has been successfully demonstrated with indirect cooled, quantum-logic-based spectroscopy technique. Its accuracy is limited by second-order Doppler shift, and its stability is limited by the number of ions that can be probed in quantum logic processing. We propose a direct laser cooling scheme of Al$^+$ ions optical clocks where both the stability and accuracy of the clocks are greatly improved. In the proposed scheme, two Al$^+$ ions traps are utilized. The first trap is used to trap a large number of Al$^+$ ions to improve the stability of the clock laser, while the second trap is used to trap a single Al$^+$ ions to provide the ultimate accuracy. Both traps are cooled with a continuous wave 167 nm laser. The expected clock laser stability can reach $9.0\\times10^{-17}/\\sqrt{\\tau}$. For the second trap, in addition to 167 nm laser Doppler cooling, a second stage pulsed ...

  20. Kerja Perspektif Al-Qur'an

    Directory of Open Access Journals (Sweden)

    Ahmad Munir

    2011-05-01

    Full Text Available The moslem ethics of life is based on movement as ex­pressed in certain terms like al-sharī’ah, al-tarīqah, al-sirāt, al-sabīl and al-manhaj, that make sense of way and teachings to achieve good life. Islam obliges and gives appreciation of the achievements of Mus­lims. The Qur’an uses several terms to refer to such work; ‘charity, kasb, juhd, ibtighâ’, sa ’yu and su ’âl. From this concept, the Qur’an considers work as nob­le, while begging is despicable. Work means thankful to God for the potential He bestows. The Qur’an promotes work not only because it is the way to achieve the wealth, but also because it possesses the its sacred value for the benefit of fulfilling livelihood. Therefore the work should also be done based on ethical values .

  1. ‘Uluww al-Isnad dalam Periwayatan Hadis Abu Muhammad al-Husain bin Mas‘ud al-Baghawi

    Directory of Open Access Journals (Sweden)

    Romlah Abubakar Askar

    2016-05-01

    Full Text Available Abu Muhammad al-Husayn Ibnu Mas’ud al-Baghawi (450-516H was one of the leading scholars in Tafsir (Quran exegesis, hadith (prophetic tradition, and fiqh (Islamic legal jurisprudence in his era. He was categorized as muta’akhirūn (scholars who came later on and was instrumental in the development of these three disciplines. In the field of exegesis, he was among the scholars who used al-Ma’tsūr, (commentary stylist, relying on the verses of the Qur’an, hadith, and the statements from the followers of the tabi’īn (the followers of the followers. This can be found in his recorded work Ma’ālim al Tanzīl. In the field of hadith, he preserved the narration method and presenting a new approach by merging some patterns of hadith narration from several books of hadith in his work known as ṭarīqah al-Jam’u (combination [amalgamation] method. This pattern will not occur unless there is the existence of other transmission lines as a second chain of narration used to produce ‘uluww al-Isnād (the noble sanad or nuzūl al-Isnād (descent sanad. It is recorded in his works: al-Jam’u baina al-Ṣaḥīḥain, Sharḥ al-Sunnah and Maṣābiḥ al-Sunnah. In the field of Jurisprudence, he was amongst those mujtahidin from the Shafiee school of thought, recorded in his Majmū’ ‘al-Fatāwā, al-Kifāyah fī al-Furū’ and Kitāb al-Tahdzīb. This paper aims to examine one of al-Baghawi’s skills in sanad collection which is the uluww al-isnād and nuzūl al-isnād, recorded from his two works Ma’ālim al-Tanzīl and Syarḥ al-Sunnah. The quantitative, qualitative and comparative approach has been used in this study to give an authentic description of the terms ‘uluww al-isnād, nuzūl al-isnād from al-Baghawi. Studies have found there are many examples of uluww al-Isnād and nuzūl al-isnāds contained in the patterns of al-Baghawi’s chain of narration towards the Ṣaḥīḥayn of al-Bukhari and Muslim as the mustakhrij

  2. MOSQUE ARCHITECTURE AS A SUSTAINABLE BUILDING IN URBAN (Case Study: Al Markas Al Islamic Mosque Makassar

    Directory of Open Access Journals (Sweden)

    Imriyanti Imriyanti

    2014-02-01

    Full Text Available Abstract Mosque Architecture is a part of Islamic architecture. Mosque should be fused with elements of nature because its function as a place to pray to God who created the universe. Al Markas Al Islamic Makassar mosque is used as a center of Islamic aspirations of the people and the government to accommodate all the activities of moslems in Makassar. Through this function, the provision of Al Markas Al Islamic mosque began from the desire of Islamic societies in Makassar, which wants the Islamic center to be equipped with facilities and infrastructure as well as architectural, monumental buildings and structures that can be last for hundreds of years (continuous, blend with the environment, and also can be used by the public. Having regard to the function of a mosque especially at the Al Markas Al Islamic Makassar mosque, then the problem that arise is how the Al Markas Al Islamic mosque can be survived/sustainable  in order  to function  as a place  of worship  and  as a center  of Islam.  This research  is a descriptive qualitative research that is trying to generate data in the form of systematic and accurate picture of the object of study. The sustaiprophetlity  of Al Markas AL Islamic mosque can be known through the concept of Islam  in accordance with the view of Islam as well as the sustaiprophetlity of the buildings that seen in the spatial pattern of the mosque, appearance, natural lighting, natural ventilation, and user behavior of the mosque. Keywords: mosque architecture, sustaiprophetlity, view of Islam     Abstrak Arsitektur masjid merupakan bagian dari arsitektur Islam. Bangunan masjid sebaiknya dapat menyatu dengan unsur alam karena masjid difungsikan sebagai wadah dalam bersujud/sembahyang  kepada Allah SWT yang menciptakan alam semesta ini. Masjid Al Markas Al Islamic Makassar merupakan kompleks kegiatan Islam yang digunakan sebagai pusat aspirasi masyarakat  dan pemerintahan  yang dapat menampung

  3. Melting Transition of Small Aluminium Clusters Al11-20

    Institute of Scientific and Technical Information of China (English)

    ZHANG Wei; ZHANG Feng-Shou; ZHU Zhi-Yuan

    2007-01-01

    Heat capacities of small aluminium clusters Al11-20 are investigated using MD simulation with empirical manybody Gupta potential. The heat capacities of some clusters Al11, Al12, Al13 and Al19 show well-defined peaks while the heat capacities of Al15-18 indicate a gradual melting transition. The spectra of isomers obtained by quenches along the MD trajectory give good interpretation for those results.

  4. Instability of TiC and TiAl3 compounds in Al-10Mg and Al-5Cu alloys by addition of Al-Ti-C master alloy

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The performance of Al-Ti-C master alloy in refining Al-10Mg and A1-5Cu alloys was studied by using electron probe micro-analyzer (EPMA) and X-ray diffractometer (XRD) analysis.The results indicate that there are obvious fading phenomena in both Al-10Mg and Al-5Cu alloys with the addition of Al-5Ti-0.4C refiner which contains TiC and TiAl3 compounds.Mg element has no influence on the stability of TiC and TiAl3, while TiC particles in Al-10Mg alloy react with Al to form Al4C3 particles, resulting in the refinement fading.However, TiC particles are relatively stable in Al-5Cu alloy, while TiAl3 phase reacts with Al2Cu to produce a new phase Ti(Al, Cu)2, which is responsible for the refinement fading in Al-5Cu alloy.These indicate that the refinement fading will not occur only when both the TiC particles and TiAl3 compound of Al-Ti-C refiner are stable in Al alloys.

  5. Al- Khwarizmi and axiomatic foundation of algebra

    International Nuclear Information System (INIS)

    This paper intends to investigate the axiomatic foundations of algebra, as they were presented in the book of algebra of al-Khwarizmi (9 th century), and as they were developed in many subsequent Arabic works. The paper gives also a description of algebra evolution towards a discipline independent ofgeometry and arithmetic: the two disciplines whosemarriage had led to its birth.By an in depth reading of some details in the text of al Khwarizmi , we concluded that this mathematician intended to lay down the axiomatic foundations of that new discipline. His resort to arithmetical and geometrical means was a way of making his theory more accessible. He used them to justify the axioms: those that were not explicitly introduced per se, and those that were remained implicit. The paper also relies on some unedited writingsof al-Khwarizmi's successors, which could shedlight on the ways they used to consolidate the foundations of algebra and improve its methods. (author)

  6. Moessbauer studies on Al-Co ferrites

    International Nuclear Information System (INIS)

    Moessbauer spectroscopy studies have been performed on the spinel CoAlxFe2-xO4 (.2≤x≤1.7) in the temperature range 77-750 K using either a liquid nitrogen bath cryostat or a furnace. The samples are magnetic at 77 K giving spectra that have magnetic sextets coexisting with a central line which increases in population with the Al-content indicating relaxation effects. The data shows that Al possesses no preference to either tetrahedral or octahedral sites of the ferrite over the whole range of concentration. The Moessbauer hyperfine interaction parameters and magnetic transition temperatures were determined. As expected the hyperfine field and Curie temperature decrease when the Al-content increases. (orig.)

  7. Thermal Properties of Al-50%Si Alloys

    Institute of Scientific and Technical Information of China (English)

    Akio Nishimoto; Katsuya Akamatsu; Kazuyoshi Nakao; Kazuo Ichii

    2004-01-01

    In order to prepare a hypereutectic Al-Si alloy with low coefficients of thermal expansion (CTE), Al-50was produced by powder metallurgy (P/M) and ingot metallurgy (I/M). P/M specimen was prepared by mechanical alloying(MA) and pulsed electric-current sintering (PECS). The microstructures of specimens were characterized by optical microscopy and scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDS). Vickers microhardness and CTE measurements were performed. The grains in the P/M specimen were refined with increasing MA time. Primary Si and eutectic Si in the I/M specimen were remarkably refined by adding minute amounts of Sr. The CTE of P/M and I/M specimens were estimated as 7.8×10-6 and 10.7×10-6, respectively. These values were as same as a CTE of Al2O3 ceramics.

  8. Autologous Stem Cell Transplant for AL Amyloidosis

    Directory of Open Access Journals (Sweden)

    Vivek Roy

    2012-01-01

    Full Text Available AL amyloidosis is caused by clonal plasma cells that produce immunoglobulin light chains which misfold and get deposited as amyloid fibrils. Therapy directed against the plasma cell clone leads to clinical benefit. Melphalan and corticosteroids have been the mainstay of treatment for a number of years and the recent availability of other effective agents (IMiDs and proteasome inhibitors has increased treatment options. Autologous stem cell transplant (ASCT has been used in the treatment of AL amyloidosis for many years. It is associated with high rates of hematologic response and improvement in organ function. However, transplant carries considerable risks. Careful patient selection is important to minimize transplant related morbidity and mortality and ensure optimal patient outcomes. As newer more affective therapies become available the role and timing of ASCT in the overall treatment strategy of AL amyloidosis will need to be continually reassessed.

  9. MgAl2O4–-Al2O3 solid solution interaction: mathematical framework and phase separation of -Al2O3 at high temperature

    Indian Academy of Sciences (India)

    Soumen Pal; A K Bandyopadhyay; S Mukherjee; B N Samaddar; P G Pal

    2011-07-01

    Although existence of MgAl2O4–-Al2O3 solid solution has been reported in the past, the detailed interactions have not been explored completely. For the first time, we report here a mathematical framework for the detailed solid solution interactions of -Al2O3 in MgAl2O4 (spinel). To investigate the solid solubility of -Al2O3 in MgAl2O4, Mg–Al spinel (MgO–Al2O3; = 1, 1.5, 3, 4.5 and an arbitrary high value 30) precursors have been heat treated at 1000°C. Presence of only non-stoichiometric MgAl2O4 phase up to = 4.5 at 1000°C indicates that alumina (as -Al2O3) present beyond stoichiometry gets completely accommodated in MgAl2O4 in the form of solid solution. → alumina phase transformation and its subsequent separation from MgAl2O4 has been observed in the Mg–Al spinel powders ( > 1) when the 1000°C heat treated materials are calcined at 1200°C. In the mathematical framework, unit cell of MgAl2O4 (Mg8Al16O32) has been considered for the solid solution interactions (substitution of Mg2+ ions by Al3+ ions) with -Al2O3. It is suggested that combination of unit cells of MgAl2O4 takes part in the interactions when > 5 (MgO–Al2O3).

  10. Kritik Terhadap Pemikiran Tasawuf Al-Raniri

    Directory of Open Access Journals (Sweden)

    Syaifan Nur

    2013-12-01

    Full Text Available Abstract : Al-Raniri is often positioned by some scholars as “superior” figure, which is contrasted to Hamzah Fansuri and Syamsuddin Sumaterani, and that is why they predicate him as one of pioneer of Islamic reformer in Malay- Indonesian archipelago. Anti-wujūdiyyah Sufism campaign by al-Raniri quite successful to some extent to amputate the rate of development of philosophical Sufism was brought by Fansuri and Sumaterani in the one hand, and strike off the nature of moral Sufism in the other, redeemed by bloodshed. This article discussed the “superiority” of al-Raniri’s thought of Sufism, viewed from a broader spectrum, either in relation to problems of faith or theology and politics surrounding the circumstance of his time.Keywords : Philosophical tasawuf, neo-sufism, panteism, tajalli, God’s attributeAbstrak : Al-Raniri oleh banyak kalangan seringkali diposisikan sebagai tokoh “superior” yang diperlawankan dengan Hamzah Fansuri dan Syamsuddin Sumaterani, dan itu sebabnya para ahli memberinya predikat sebagai seorang pelopor pembaru (mujaddid Islam di Nusantara. Anti tasawuf wujūdiyyah yang dikampanyekan oleh al-Raniri cukup berhasil mengamputasi laju perkembangan tasawuf falsafi yang dibawa oleh Fansuri dan Sumaterani di satu sisi, dan melancarkan laju corak tasawuf akhlaki di sisi lain, yang ditebus dengan cara pertumpahan darah. Tulisan ini mendiskusikan “superioritas” pemikiran tasawuf al-Raniri tersebut, dilihat dari spektrum yang lebih luas, baik menyangkut persoalan keyakinan atau teologi maupun politik yang mengitari situasi zamannya.Kata kunci : Tasawuf falsafi , neo-sufisme, panteisme, tajalli, sifat Tuhan

  11. Diffusion AlSi-MeCrAlY coatings obtained on intermetallic γ-TiAl phase

    Directory of Open Access Journals (Sweden)

    M. Góral

    2012-12-01

    Full Text Available Purpose: The development of new protective coatings for TiAl intermetallics was conducted. The MeCrAlYAlSi slurry was used with different amount of aluminium-silicon powder in the binder.Design/methodology/approach: The slurry consisting of aluminium and silicon powder with the addition of MeCrAlY powder were used during the procedure. The inorganic solution made from chromic and phosphoric acid was applied as a binder. The preliminary research of microstructure of obtained coatings was conducted.Findings: The obtained coating consisting of 3 or 4 zones (depending on chemical composition of the slurry was obtained during the annealing process (950°C/4h.Research limitations/implications: The research results revealed the possibility of obtaining coatings with complex phase and chemical composition.Practical implications: Many problems connected with sedimentation of heavier MeCrAlY powder were observed.Originality/value: The copletele new technologies was described in article

  12. Fabrication of Al-Al3Ti/Ti3Al Functionally Graded Materials under a Centrifugal Force

    Directory of Open Access Journals (Sweden)

    Yoshimi Watanabe

    2010-09-01

    Full Text Available Fabrication of Al-Al3Ti functionally graded materials (FGMs under the centrifugal force has recently attracted some attention. The controlled compositional gradient of the fabricated FGMs, the low cost of the process, and the good mold filling, are the main advantages of the centrifugal method (CM. Using the conventional CM techniques such as the centrifugal solid-particle method and centrifugal in-situ method, FGMs rings with gradually distributed properties could be achieved. As a more practical choice, the centrifugal mixed-powder method (CMPM was recently proposed to obtain FGMs containing nano-particles selectively dispersed in the outer surface of the fabricated parts. However, if a control of the particles morphology, compound formulas or sizes, is desired, another CM technique is favored. As a development of CMPM, our novel reaction centrifugal mixed-powder method (RCMPM has been presented. Using RCMPM, Al‑Al3Ti/Ti3Al FGMs with good surface properties and temperature controlled compositional gradient could be achieved. In this short review, this novel method will be discussed in detail and the effect of RCMPM processing temperature on the reinforcement particles morphology, size and distribution through the fabricated samples, will be reviewed.

  13. Total energy, equation of state and bulk modulus of AlP, AlAs and AlSb semiconductors

    Indian Academy of Sciences (India)

    A R Jivani; H J Trivedi; P J Gajjar; A R Jani

    2005-01-01

    Recently proposed model potential which combines both linear and quadratic types of interactions is employed for the investigation of some properties like the total energy, equation of state and bulk modulus of AlP, AlAs and AlSb semiconductor compounds using higher-order perturbation theory. The model potential parameter is determined using zero pressure condition. The ratio of the covalent bonding term E cov to the second-order term 2 is 6.77% to 11.85% which shows that contribution from higher order terms are important for zinc-blende-type crystals. The calculated numerical results of the total energy, energy band gap at Jones-zone face and bulk modulus of these compounds are in good agreement with the experimental data and found much better than other such theoretical findings. We have also studied pressure–volume relations of these compounds. The present study is carried out using six different screening functions along with latest screening function proposed by Sarkar et al. It is found from the present study that effect of exchange and correlation is clearly distinguishable.

  14. Simulations of the premelting of Al(110)

    DEFF Research Database (Denmark)

    Stoltze, Per

    1990-01-01

    The premelting of Al(110) is studied by molecular dynamics simulations using the potential for Al derived from effective medium theory. We find a progressive disordering of the surface region as the bulk melting point is approached. This disorder is mediated by the formation of adatom–vacancy pairs....... Based on the calculated radial distribution function and the analytical expression for the energy, it is demonstrated that the thermodynamics of disorder and melting is reflected in the single particle properties by a decrease in the number of nearest neighbors. The Debye temperature for the surface...

  15. Quadrupole scattering in PrAl2

    Science.gov (United States)

    Sablik, M. J.; Pureur, P.; Creuzet, G.; Fert, A.; Levy, P. M.

    1983-10-01

    We derive the spontaneous anisotropy of the resistivity of the ferromagnetic compound PrAl2 from magnetoresistance measurements on a single crystal of PrAl2. We ascribe this spontaneous anisotropy of the resistivity to scattering of the conduction electrons by the thermal quadrupole disorder and we account for our experimental results by using the theoretical model previously developed by us. We find that quadrupole scattering gives a very important contribution to the total magnetic disorder (spin and quadrupole) resistivity but that only a small part of this quadrupole contribution is anisotropic.

  16. Aspectos biopsicosociales asociados al embarazo adolescente

    OpenAIRE

    Regina Cogollo Jiménez

    2012-01-01

    Introducción: El embarazo en la adolescencia, es un evento inesperado, sorpresivo. Este artículo establece la importancia de identificar los aspectos biopsicosociales asociados al embarazo adolescente en las embarazadas asistentes al programa de Control Prenatal de una Empresa Social del Estado de nivel 1 en Montería en 2009, para comprender las actitudes y los comportamientos asociados a esta etapa tan temprana. Materiales y Métodos: Es un estudio descriptivo, cuantitativo, de corte transver...

  17. Amyotrofisen lateraaliskleroosin (ALS) fysioterapia : Systemaattinen kirjallisuuskatsaus

    OpenAIRE

    Finne, Ida

    2015-01-01

    Amyotrofinen lateraaliskleroosi eli ALS on harvinainen motoneuronisairaus, jonka ominaispiirteenä on selkäytimen, aivorungon ja aivokuoren motoneuroneiden etenevä degeneraatio ja tuhoutuminen. Tähän parantumattomaan sairauteen sairastuu Suomessa vuosittain noin 120–150 henkilöä. Keskimääräinen sairastumisikä on noin 60 vuotta ja elinikä diagnoosin saamisen jälkeen on noin 3 - 5 vuotta. Fysioterapia on tärkeä osa ALS-potilaan hoitoa ja kuntoutusta. Fysioterapian vaikutut-tavuutta on tästä ...

  18. Recent research highlights from the ALS OML

    OpenAIRE

    Yashchuk, Valeriy V.

    2013-01-01

    The main mission of the Optical Metrology Laboratory (OML) at the Advanced Light Source (ALS) is to ensure state-of-the-art performance of beamline optics. New beamlines and instruments laid out in the ALS strategic plan as well as the plan for New Generation Light Source (NGLS) facility all involve increasingly complex optical systems that need ultra-high precision optics to achieve the specifications and goals of their state-of-the art research programs. In order to manufacture, measure, tu...

  19. Semantische Merkmale als Mittel der Textkonstitution

    Directory of Open Access Journals (Sweden)

    Stojan Bračič

    2008-12-01

    Full Text Available Im folgenden Beitrag sollen semantische Relationen unter die Lupe genommen werden, die im text dazu beitragen, dass einzelne Textkomponenten miteinander verknüpft werden. Dabei geht es hauptsächlich um Relationen, die nicht satzthematisch sind - diese sind nämlich als textuelle Koreferenzketten ausreichend untersucht worden (vgl. u.a. Bračič/Fix/Greule 2007 - sondern um jene Relationen, die als Prädikationen einzelner textgrammatischer Einheiten (Sätze vorkommen und ebenfalls gewisse geordnete Strukturierungen aufweisen.

  20. Introducción al derecho

    OpenAIRE

    Collado Luis, Santiago

    2012-01-01

    Manual de la asignatura introducción al derecho. Nivel educativo: Grado El origen de este texto –materiales docentes- que lleva por título “Introducción al Derecho” ha sido escrito respondiendo a una estricta necesidad docente y por tanto necesariamente pedagógica. En efecto, era totalmente necesario que los alumnos, del Grado de Administración y Dirección de Empresas y otras titulaciones no jurídicas, contasen con un texto para facilitar el estudio de las principales categorías conceptual...

  1. Magnetic Properties of NdAl2

    DEFF Research Database (Denmark)

    Bak, P.

    1974-01-01

    The magnetic properties of NdAl2 are calculated using a Hamiltonian including crystal-field and isotropic exchange interaction terms. A two-dimensional mean-field theory is evaluated to calculate single-crystal magnetization curves. It is shown that the magnetic properties can be understood using...... the crystal-field parameters derived from the magnetic exciton spectrum measured by Houmann et al. by means of inelastic neutron scattering. The combined lambda -Schottky anomaly in the heat capacity is explained. No additional parameters are introduced....

  2. Metamagnetism in Ce(Ga,Al)2

    Indian Academy of Sciences (India)

    K G Suresh; S Radha; A K Nigam

    2002-05-01

    Effect of Al substitution on the magnetic properties of Ce(Ga1-Al)2 ( = 0, 0.1 and 0.5) system has been studied. The magnetic state of CeGa2 is found to be FM with a C of 8 K, whereas the compounds with =0.1 and 0.5 are AFM and possess N of about 9 K. These two compounds undergo metamagnetic transition and the critical fields are about 1.2 T and 0.5 T, respectively at 2 K. These variations are explained on the basis of helical spin structure in these compounds.

  3. Melting, Processing, and Properties of Disordered Fe-Al and Fe-Al-C Based Alloys

    Science.gov (United States)

    Satya Prasad, V. V.; Khaple, Shivkumar; Baligidad, R. G.

    2014-09-01

    This article presents a part of the research work conducted in our laboratory to develop lightweight steels based on Fe-Al alloys containing 7 wt.% and 9 wt.% aluminum for construction of advanced lightweight ground transportation systems, such as automotive vehicles and heavy-haul truck, and for civil engineering construction, such as bridges, tunnels, and buildings. The melting and casting of sound, porosity-free ingots of Fe-Al-based alloys was accomplished by a newly developed cost-effective technique. The technique consists of using a special flux cover and proprietary charging schedule during air induction melting. These alloys were also produced using a vacuum induction melting (VIM) process for comparison purposes. The effect of aluminum (7 wt.% and 9 wt.%) on melting, processing, and properties of disordered solid solution Fe-Al alloys has been studied in detail. Fe-7 wt.% Al alloy could be produced using air induction melting with a flux cover with the properties comparable to the alloy produced through the VIM route. This material could be further processed through hot and cold working to produce sheets and thin foils. The cold-rolled and annealed sheet exhibited excellent room-temperature ductility. The role of carbon in Fe-7 wt.% Al alloys has also been examined. The results indicate that Fe-Al and Fe-Al-C alloys containing about 7 wt.% Al are potential lightweight steels.

  4. Fabrication and Characterization of AL-AL4C3 Nanocomposite by Mechanical Alloying

    Science.gov (United States)

    Mohammad Sharifi, E.; Enayati, M. H.; Karimzadeh, F.

    Aluminum carbide (Al4C3) seems to be an ideal reinforcement for producing aluminum matrix composites. Al4C3 has high hardness and shear strength as well as a high melting point. The dispersion of Al4C3 particles in the matrix produces a pinning effect that reduces aluminum grain growth, which improves the mechanical properties. In this study, aluminum powders were mixed with 4.5 wt.% graphite and mechanically alloyed using a high-energy ball mill in order to produce Al-Al4C3 nanocomposite. The structural evaluation of powder particles after different milling times was studied by X-ray diffractometry, scanning electron microscopy and microhardness measurements. The aluminum crystallite size estimated with broadening of XRD peaks by Williamson-Hall formula. XRD results suggested that the grain size of aluminum decreased to nanometer range (30 nm) during ball milling. No Al4C3 formed during the mechanical alloying process. Milled powders were then annealed at 300-600 °C for 1 h under argon atmosphere. Annealing at temperatures higher than 300 °C led to formation of Al4C3 phase which increased as annealing temperature increased. Aluminum grain size remained in nanometer range after annealing process. The microhardness of powder particles increased after annealing. Both effects are due to the formation of nanosized Al4C3 particles.

  5. InAlGaAs/AlGaAs quantum wells: line widths, transition energies and segregation

    DEFF Research Database (Denmark)

    Jensen, Jacob Riis; Hvam, Jørn Märcher; Langbein, Wolfgang

    2000-01-01

    We investigate the optical properties of InAlCaAs/AlGaAs quantum wells pseudomorphically grown on GaAs using molecular beam epitaxy (MBE). The transition energies, measured with photoluminescence (PL), are modelled solving the Schrodinger equation, and taking into account segregation in the group...

  6. Directional Solidification and Mechanical Properties of NiAl-NiAlTa Alloys

    Science.gov (United States)

    Johnson, D. R.; Chen, X. F.; Oliver, B. F.; Noebe, R. D.; Whittenberger, J. D.

    1995-01-01

    Directional solidification of eutectic alloys is a promising technique for producing in-situ composite materials exhibiting a balance of properties. Consequently, the microstructure, creep strength and fracture toughness of directionally solidified NiAl-NiAlTa alloys were investigated. Directional solidification was performed by containerless processing techniques to minimize alloy contamination. The eutectic composition was found to be NiAl-15.5 at% Ta and well-aligned microstructures were produced at this composition. A near-eutectic alloy of NiAl-14.5Ta was also investigated. Directional solidification of the near-eutectic composition resulted in microstructures consisting of NiAl dendrites surrounded by aligned eutectic regions. The off-eutectic alloy exhibited promising compressive creep strengths compared to other NiAl-based intermetallics, while preliminary testing indicated that the eutectic alloy was competitive with Ni-base single crystal superalloys. The room temperature toughness of these two-phase alloys was similar to that of polycrystalline NiAl even with the presence of the brittle Laves phase NiAlTa.

  7. Thermodynamic Assessments of Al-In-Sb and Al-In-As Systems

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The experimental thermodynamic and phase diagram data of the Al-In-Sb and Al-In-As ternary systems were critically assessed.A set of self-consistent thermodynamic model parameters were obtained to describe the phase equilibria and the thermodynamic properties of two systems.In most cases,the calculated values agree very well with the experimental data.

  8. Ab initio phonon calculations for Ll(2) Ni3Al and B2NiAl

    NARCIS (Netherlands)

    Isaeva, E.I.; Lichtenstein, A.I.; Vekilov, Y.K.; Smirnova, E.A.; Abrikosov, I.A.; Simak, S.I.; Ahuja, R.; Johansson, B.

    2004-01-01

    The phonon spectra and phonon density of states of the Ni3Al and NiAl intermetallic compounds are calculated from first principles using the linear response method in conjunction with ultrasoft pseudopotentials. The calculated phonon dispersion curves are in good agreement with available experimenta

  9. Electronic circuits having NiAl and Ni.sub.3 Al substrates

    Energy Technology Data Exchange (ETDEWEB)

    Deevi, Seetharama C. (Midlothian, VA); Sikka, Vinod K. (Oak Ridge, TN)

    1999-01-01

    An electronic circuit component having improved mechanical properties and thermal conductivity comprises NiAl and/or Ni.sub.3 Al, upon which an alumina layer is formed prior to applying the conductive elements. Additional layers of copper-aluminum alloy or copper further improve mechanical strength and thermal conductivity.

  10. Electronic circuits having NiAl and Ni{sub 3}Al substrates

    Energy Technology Data Exchange (ETDEWEB)

    Deevi, S.C.; Sikka, V.K.

    1999-10-12

    An electronic circuit component having improved mechanical properties and thermal conductivity comprises NiAl and/or Ni{sub 3}Al, upon which an alumina layer is formed prior to applying the conductive elements. Additional layers of copper-aluminum alloy or copper further improve mechanical strength and thermal conductivity.

  11. Electronic states and spin-forbidden cooling transitions of AlH and AlF.

    Science.gov (United States)

    Wells, Nathan; Lane, Ian C

    2011-11-14

    The feasibility of laser cooling AlH and AlF is investigated using ab initio quantum chemistry. All the electronic states corresponding to the ground and lowest two excited states of the Al atom are calculated using multi-reference configuration interaction (MRCI) and the large AV6Z basis set for AlH. The smaller AVQZ basis set is used to calculate the valence electronic states of AlF. Theoretical Franck-Condon factors are determined for the A(1)Π→ X(1)Σ(+) transitions in both radicals and found to agree with the highly diagonal factors found experimentally, suggesting computational chemistry is an effective method for screening suitable laser cooling candidates. AlH does not appear to have a transition quite as diagonal as that in SrF (which has been laser cooled) but the A(1)Π→ X(1)Σ(+) transition transition of AlF is a strong candidate for cooling with just a single laser, though the cooling frequency is deep in the UV. Furthermore, the a(3)Π→ X(1)Σ(+) transitions are also strongly diagonal and in AlF is a practical method for obtaining very low final temperatures around 3 μK.

  12. Al-rich part phase relation in Al-Mg-Sc system at 430 ℃

    Institute of Scientific and Technical Information of China (English)

    夏长清; 曾凡浩; 古一

    2003-01-01

    Phase relation of the aluminium-magnesium-scandium system in the Al-rich range at 430 ℃ was investigated by means of multiphase diffusion couples along with electron probe microanalysis, X-ray diffraction and electron microscopy techniques. It consists of five single-phase fields, four 2-phase fields and one 3-phase field. The maximum solid solubilities of Mg and Sc in α(Al) solid solution at 430 ℃ are about 15.27%Mg(mole fraction) and 0.33%Sc, respectively. The maximum solid solubilities of Sc in Mg2Al3 and Mg17Al12 are about 1.08% and 0.03% at the same temperature. The diffusion path at 430 ℃ was constructed and interpreted by means of the Al-Mg-Sc equilibrium phase diagram assuming that local equilibrium is established at the phase boundaries.

  13. Serious Flaws in Korf et al.'s Analysis on Time Complexity of A*

    CERN Document Server

    Dinh, Hang

    2008-01-01

    Understanding the effect of a heuristic on the time complexity of the well-known A* search algorithm has been a subject of a large research body in AI. Among those researches is Korf et al.'s analysis (Korf & Reid, 1998; Korf et al., 2001; Korf, 2000a; Korf, 2000b), which concluded that the effect of a heuristic is to reduce the effective depth rather than effective branching factor. Since this conclusion conflicts with both previous analysis and recent analysis by other authors, we try to investigate the causes of such contradictions and finally find out that Korf et al.'s analysis has many serious flaws from which their main conclusion was drawn.

  14. FABRICATION OF Al/Al2O3 FGM ROTATING DISC

    Directory of Open Access Journals (Sweden)

    A. B. Sanuddin

    2012-06-01

    Full Text Available This study presents a method of fabricating a disc made of Al/Al2O3 functionally graded materials (FGM, using a powder metallurgy manufacturing process. The aim is to develop a processing method for a rotating disc made of FGM, by stacking the slurry, layer by layer in a radial direction. A three-layer functionally graded material of Al/Al2O3 is fabricated with compositions of 10, 20, 30 vol.% Al2O3. The ceramic composition increases from the discs inner (centre to the outer. The combination of these materials can offer the ability to withstand high temperature conditions whilst maintaining strength in extreme environments.

  15. In situ microscopy of rapidly heated nano-Al and nano-Al/WO3 thermites

    Science.gov (United States)

    Sullivan, Kyle T.; Chiou, Wen-An; Fiore, Richard; Zachariah, Michael R.

    2010-09-01

    The initiation and reaction mechanism of nano-Al and nano-Al thermites in rapid heating environments is investigated in this work. A semiconductor-based grid/stage was used, capable of in situ heating of a sample from room temperature to 1473 K, and at a rate of 106 K/s, inside an electron microscope. Nano-Al was rapidly heated in a transmission electron microscope, and before and after images indicate that the aluminum migrates through the shell, consistent with a diffusion-based mechanism. A nano-Al/WO3 composite was then heated in a scanning electron microscope. The results indicate that a reactive sintering mechanism is occurring for the nano-Al/WO3 thermite, as the products are found to be in surface contact and significantly deformed after the heating pulse.

  16. Surface phonon polariton characteristics of In(0.04)Al(0.06)Ga(0.90)N/AlN/Al(2)O(3) heterostructure.

    Science.gov (United States)

    Ng, S S; Lee, S C; Bakhori, S K Mohd; Hassan, Z; Abu Hassan, H; Yakovlev, V A; Novikova, N N; Vinogradov, E A

    2010-05-10

    Surface phonon polariton (SPP) characteristics of In(0.04)Al(0.06)Ga(0.90)N/AlN/Al(2)O(3) heterostructure are investigated by means of p-polarized infrared (IR) attenuated total reflection spectroscopy. Two absorption dips corresponding to In(0.04)Al(0.06)Ga(0.90)N SPP modes are observed. In addition, two prominent dips and one relatively weak and broad dip corresponding to the Al(2)O(3) SPP mode, In(0.04)Al(0.06)Ga(0.90)N/Al(2)O(3) interface mode, and Al(2)O(3) bulk polariton mode, respectively, are clearly seen. No surface mode feature originating from the AlN layer is observed because it is too thin. Overall, the observations are in good agreement with the theoretical predictions. PMID:20588890

  17. Microstructural defects modeling in the Al-Mo system

    International Nuclear Information System (INIS)

    In this work we have utilized computer simulation techniques to study microstructural defects, such as point defects and interfaces, in the Al-Mo alloy. Such alloy is taken as a model to study the Al(fcc)/U-Mo(bcc) interface. The EAM interatomic potential used has been fitted to the formation energy and lattice constant of the AlMo3 intermetallic. Formation of vacancies for both components Al and Mo and anti-sites, AlMo and MoAl, as well as vacancy migration was studied in this structure. We found that the lowest energy defect complex that preserves stoichiometry is the antisite pair AlMo+MoAl, in correspondence with other intermetallics of the same structure. Our results also suggest that the structure of the Al(fcc)/Mo(bcc) interface is unstable, while that of the Al(fcc)/Al5Mo interface is stable, as observed experimentally. (author)

  18. Production of Al nanocomposite reinforced by Fe-Al intermetallic, Al{sub 4}C{sub 3} and nano-Al{sub 2}O{sub 3} particles using wet milling in toluene

    Energy Technology Data Exchange (ETDEWEB)

    Razavi-Tousi, S.S., E-mail: ser105@mail.usask.ca [Islamic Azad University, Shahrood Branch, Shahrood (Iran, Islamic Republic of); Yazdani-Rad, R. [Materials and Energy Research Center, P.O. Box 31787/316, Karaj (Iran, Islamic Republic of); Manafi, S.A. [Islamic Azad University, Shahrood Branch, Shahrood (Iran, Islamic Republic of)

    2011-06-02

    Highlights: > Production of Al nanocomposite reinforced by Fe-Al intermetallic, Al{sub 4}C{sub 3} and nano-Al{sub 2}O{sub 3} particles using wet milling in toluene. > Production of Al{sub 4}C{sub 3} particles from mechanochemical reaction of Al with PCA. > Effect of second phase particles on sintering. - Abstract: Al matrix nanocomposites were produced by wet milling of Al and nano-alumina powders in a toluene media. X-ray diffraction patterns, inductively coupled plasma, carbon measurement analysis and scanning electron microscopy show that impurities introduced by decomposition of toluene and abrasion of balls and vials are uniformly dispersed in the Al matrix as Al{sub 4}C{sub 3} and Fe-Al intermetallic particles. Though producing homogenous nanocomposites, these second phase particles seem to have a retarding effect on densification of nanocomposite powders.

  19. The constitution of alloys in the Al-rich corner of the Al-Si-Sm ternary system

    International Nuclear Information System (INIS)

    The constitution of alloys and the liquidus surface in the Al-rich corner of the Al-Si-Sm ternary system were determined by the examination of controlled heated and cooled specimens, as well as heat-treated specimens by means of optical and scanning electron microscopy, energy-dispersive X-ray spectroscopy, differential thermal analysis and X-ray diffraction. The Al-rich corner of the Al-Si-Sm ternary system comprises five regions of primary crystallisation (αAl, βSi, Al3Sm, Al2Si2Sm and AlSiSm) with following characteristic invariant reaction sequences: ternary eutectic reaction L → αAl + βSi + Al2Si2Sm, and two liquidus transition reactions, i. e., L + Al3Sm → αAl + AlSiSm, and L + AlSiSm → αAl + Al2Si2Sm. Along with the position of ternary eutectic and both interstitial points in the Al-rich corner of the Al-Si-Sm ternary system, the temperatures for each reaction were determined. (orig.)

  20. Microscopic phase field study of the antisite defect of Ni3 Al in binary Ni-Al alloys

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The temporal evolution feature of a microscopic phase field model is utilized to study the antisite defects of L1 2-Ni 3 Al;this is quite different from other physicist’ interests.There are mainly two points in brief.Firstly,antisite defects Ni Al and Al Ni ,which are caused by the deviation from the stoichiometric Ni 3 Al,coexist in the Ni 3 Al phase.The surplus Ni atom in the Ni-rich side is prone to substitute Al thus producing the antisite defect Ni Al that maintains the stability of the L1 2 structure.In other case,the surplus Al atom in the Al-rich side is accommodated by a Ni sublattice consequently giving rise to antisite defect Al Ni .The calculated equilibrium occupancy probability of Ni Al is much higher than that of Al Ni .This point is generally in line with other theoretical and experimental works.Additionally,both Ni Al and Al Ni have a strong negative correlation to time step during the disorder-order transformation.Since the initial value of Ni Al and Al Ni on each site of the matrix is right at the concentration that we set,we can observe the decrease process of Ni Al and Al Ni from the initial disordered high anti-structure state to their respective equilibrium state,i.e.to the result of the ordering process further coarsening.

  1. TiAl-Nb melt interaction with AlN refractory crucibles

    Energy Technology Data Exchange (ETDEWEB)

    Kartavykh, A.V., E-mail: karta@girmet.ru [Institute of Chemical Problems for Microelectronics (IChPM), B. Tolmachevsky per. 5, 119017 Moscow (Russian Federation); Tcherdyntsev, V.V. [Moscow State Institute of Steel and Alloys (Technological University), Leninsky pr. 4, 119049 Moscow (Russian Federation); Zollinger, J. [ACCESS e.V., Intzestrasse 5, 52072 Aachen (Germany)

    2009-07-15

    The paper considers contamination of cast TiAl-based alloy, related microstructure evolution and chemical contact interaction when using refractory aluminium nitride crucibles/moulds as an alternative to the traditional Al{sub 2}O{sub 3}-, ZrO{sub 2}- and Y{sub 2}O{sub 3}-based oxide ceramics. A series of melting tests has been performed in resistive SiC electro-furnace with Ti-46Al-8Nb (at%) alloy in 99.99% purity AlN boat crucibles with fixed melt superheating times 5, 12 and 25 min at 1670 deg. C and consequent quenching with high-purity Ar gas flow. As-cast samples were examined by X-ray diffractometry, SEM, SIMS, EDX, EBSD and vacuum fusion analysis of O, N, C and S interstitials content with respect to the initial material. The key features of TiAl-Nb melt interaction with AlN ceramics are revealed. As a result of slow thermal dissociation AlN {yields} Al + N, and the reaction of nascent nitrogen with the melt, a solid continuous TiN-based reaction layer is formed up to 6.4 {mu}m in thickness, together with an enriched Al liquid film between it and the crucible wall. It causes perfect wetting of crucible with the melt and easy removal of the solidified sample. The partial suitability of AlN crucible is restricted by 12 min of the melt superheating from the point of view of invariable ({alpha}{sub 2} + {gamma})-microstructure and reasonable contamination of the as-cast samples.

  2. AlON的合成工艺%Synthesis technology of AlON

    Institute of Scientific and Technical Information of China (English)

    王习东; 李文超

    2001-01-01

    分析了合成AlON的各种方法。 用模式识别结 合神经网络对碳热还原氮化合成AlON工艺 进行了优化, 利用模式逆映射得到了理想的合成工艺参数。 对AlON体系进行了热力学初步 分析, 计算了温度为2  073  K时合成AlON的热力学参数状态图。 根据热力学参数状态图所确定的条件, 热压合成了AlON陶瓷。 对所合成的AlON试样进行了 X 射线衍射标定及部分物理性能的测定。 其密度为3.63  g/cm3, 约为其理论 密度的97.8%。%The synthesis technolog y of AlON ceramics was investigated. The program o f pattern recognition was used to optimize the parameters of AlON synthesi s process, and the proper parameters were obtained by inverse projection. The th ermodynamic properties of AlON were preliminary analyzed and estimate d, phase stability diagrams at 2  073  K were calculated. A lON ceramics was synthesized by hot-press sintering under the conditions given by phase stability diagram. The density of AlON is 3.63  g/cm3, about 97.8% of its th eoretic d ensity.

  3. Microstructure of Ni-Al powder and Ni-Al composite coatings prepared by twin-wire arc spraying

    Science.gov (United States)

    Wang, Ji-xiao; Wang, Gui-xian; Liu, Jing-shun; Zhang, Lun-yong; Wang, Wei; Li, Ze; Wang, Qi-xiang; Sun, Jian-fei

    2016-07-01

    Ni-Al powder and Ni-Al composite coatings were fabricated by twin-wire arc spraying (TWAS). The microstructures of Ni-5wt%Al powder and Ni-20wt%Al powder were characterized by scanning electronic microscopy (SEM) and energy dispersive spectroscopy (EDS). The results showed that the obtained particle size ranged from 5 to 50 μm. The morphology of the Ni-Al powder showed that molten particles were composed of Ni solid solution, NiAl, Ni3Al, Al2O3, and NiO. The Ni-Al phase and a small amount of Al2O3 particles changed the composition of the coating. The microstructures of the twin-wire-arc-sprayed Ni-Al composite coatings were characterized by SEM, EDS, X-ray diffraction (XRD), and transmission electron microscopy (TEM). The results showed that the main phase of the Ni-5wt%Al coating consisted of Ni solid solution and NiAl in addition to a small amount of Al2O3. The main phase of the Ni-20wt%Al coating mainly consisted of Ni solid solution, NiAl, and Ni3Al in addition to a small amount of Al and Al2O3, and NiAl and Ni3Al intermetallic compounds effectively further improved the final wear property of the coatings. TEM analysis indicated that fine spherical NiAl3 precipitates and a Ni-Al-O amorphous phase formed in the matrix of the Ni solid solution in the original state.

  4. Synthesis of Ti-Al porous perform

    Directory of Open Access Journals (Sweden)

    K. Naplocha

    2008-02-01

    Full Text Available Purpose: Article describes production method of intermetallic porous perform for reinforcing of composite materials. Usefulness of the high temperature self-propagating synthesis (SHS, with appropriate modification, to produce perform for production of composite was evaluated.Design/methodology/approach: Mixture of aluminum and titanium powder was cold isostatically pressed (CIPed and produced cylindrical pill was ignited in microwave field. Obtained structure usually have open porosity what enables for pressure infiltration with molten metal. The investigations of the structure of preforms on the scanning electron microscope (SEM were made.Findings: The produced performs in most cases reveal open porosity, uniform morphology and are suitable for infiltration process. After reaction Al-Ti compounds form partly globular structure with microhardness much higher than substratesResearch limitations/implications: In the actual stages of this work proposed method can be used for manufacturing of porous performs, which mainly contain Al3Ti. During reaction, mixture compacts with the molar ratio of Al/Ti=1 were transformed into inhomogeneous structure.Practical implications: Obtained perform can be widely used as the reinforcement to produce hybrid composite materials by the infiltration method. Aluminum casting alloys can be locally reinforced to improve hardness and resistance to oxidization at high temperature.Originality/value: Article is valuable for persons engaged in production of casting composite materials reinforced with porous perform. Proposed method allows to incorporate hard structures from Al-Ti compounds into aluminum casting.

  5. CALCULUL CINETOSTATIC AL MECANISMELOR PLANETARE CILINDRICE

    Directory of Open Access Journals (Sweden)

    Păun ANTONESCU

    2012-05-01

    Full Text Available În lucrare se prezintă o metodă analitică pentru calculul cinetostatic al mecanismului planetarmonomobil cu două roţi dinţate centrale. Se consideră mai întâi cazul general al schemelor cinematice cu douăroţi dinţate solidare tip satelit, în două variante practice (multiplicator şi reductor de turaţie. Este menţionatcazul particular al mecanismelor planetare cu o singură roată satelit cu angrenare dublă (exterioară şiinterioară. Pe baza modelului de analiză cinetostatică a mecanismului planetar monomobil cu două roţi dinţatecentrale, în finalul lucrării se abordează o problemă practică de calcul cinetostatic al unui mecanism planetarcilindric simplu folosit la capul de frezat pentru prelucrarea roţilor dinţate cilindrice cu dinţi curbi înhipocicloidă.

  6. Colombia frente al manejo del Presupuesto Nacional

    Directory of Open Access Journals (Sweden)

    Germán Enrique Reyes Forero

    2009-07-01

    Colombia pasa de 38 puntos en el 2007 a 46 puntos en el 2009, mejoría que no se corresponde con los múltiples escándalos de corrupción; ésta mejoría responde al manejo de tecnicismos como se intentará aclarar en el presente articulo.

  7. 75 FR 1420 - Alabama Disaster # AL-00025

    Science.gov (United States)

    2010-01-11

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00025 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a notice of an Administrative declaration of a disaster for the State of Alabama dated...

  8. 76 FR 29810 - Alabama Disaster #AL-00037

    Science.gov (United States)

    2011-05-23

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00037 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  9. 75 FR 26813 - Alabama Disaster #AL-00029

    Science.gov (United States)

    2010-05-12

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00029 AGENCY: Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for the State of Alabama...

  10. 78 FR 4967 - Alabama Disaster #AL-00046

    Science.gov (United States)

    2013-01-23

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00046 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a notice of an Administrative declaration of a disaster for the State of ALABAMA dated...

  11. 76 FR 62481 - Incapital LLC, et al.

    Science.gov (United States)

    2011-10-07

    ... From the Federal Register Online via the Government Publishing Office SECURITIES AND EXCHANGE COMMISSION Incapital LLC, et al.; Notice of Application September 30, 2011. AGENCY: Securities and Exchange Commission (``Commission''). ACTION: Notice of application for an order under section 12(d)(1)(J) of...

  12. 78 FR 22361 - Alabama Disaster #AL-00049

    Science.gov (United States)

    2013-04-15

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00049 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a notice of an Administrative declaration of a disaster for the State of Alabama dated...

  13. 78 FR 26100 - Alabama Disaster #AL-00050

    Science.gov (United States)

    2013-05-03

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00050 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a notice of an Administrative declaration of a disaster for the State of Alabama dated...

  14. 75 FR 3895 - Yale University, et al.;

    Science.gov (United States)

    2010-01-25

    ... notice at 74 FR 67851, December 21, 2009. Docket Number: 09-065. Applicant: U.S. Department of Homeland..., Quanta 200 FEG. Manufacturer: FEI Company, Czech Republic. Intended Use: See notice at 74 FR 67851... International Trade Administration Yale University, et al.; Notice of Consolidated Decision on Applications...

  15. 77 FR 7227 - Alabama Disaster #AL-00040

    Science.gov (United States)

    2012-02-10

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00040 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for the State of Alabama...

  16. 75 FR 474 - Alabama Disaster #AL-00026

    Science.gov (United States)

    2010-01-05

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00026 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  17. 76 FR 27141 - Alabama Disaster # AL-00036

    Science.gov (United States)

    2011-05-10

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00036 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for the State of Alabama...

  18. 77 FR 60003 - Alabama Disaster #AL-00044

    Science.gov (United States)

    2012-10-01

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00044 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  19. 75 FR 26814 - Alabama Disaster #AL-00031

    Science.gov (United States)

    2010-05-12

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Alabama Disaster AL-00031 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  20. The Science of al-Biruni

    CERN Document Server

    Sparavigna, Amelia Carolina

    2013-01-01

    Al-Biruni (973-1048) was one of the greatest scientists of all times. He was an astronomer, mathematician and philosopher, and studied physics and natural sciences. In this paper, we will discuss some of his experimental methods and some instruments he used.

  1. Creative Commons : Erfgoedinstelling als digitaal curator.

    NARCIS (Netherlands)

    Hoorn, Esther

    2008-01-01

    Zijn Creative Commons-licenties een ver-van-mijn-bed-show voor erfgoedinstellingen? Integendeel, betoogt Esther Hoorn. De instellingen kunnen ze gebruiken als ze rechthebbende zijn. Maar belangrijker nog: door het gebruik van deze licenties te stimuleren kunnen ze een spin in het web van netwerken r

  2. Management of respiratory symptoms in ALS.

    LENUS (Irish Health Repository)

    Hardiman, Orla

    2012-02-01

    Respiratory insufficiency is a frequent feature of ALS and is present in almost all cases at some stage of the illness. It is the commonest cause of death in ALS. FVC is used as important endpoint in many clinical trials, and in decision-making events for patients with ALS, although there are limitations to its predictive utility. There are multiple causes of respiratory muscle failure, all of which act to produce a progressive decline in pulmonary function. Diaphragmatic fatigue and weakness, coupled with respiratory muscle weakness, lead to reduced lung compliance and atelectasis. Increased secretions increase the risk of aspiration pneumonia, which further compromises respiratory function. Bulbar dysfunction can lead to nutritional deficiency, which in turn increases the fatigue of respiratory muscles. Early recognition of respiratory decline and symptomatic intervention, including non-invasive ventilation can significantly enhance both quality of life and life expectancy in ALS. Patients with respiratory failure should be advised to consider an advance directive to avoid emergency mechanical ventilation.

  3. Management of respiratory symptoms in ALS.

    LENUS (Irish Health Repository)

    Hardiman, Orla

    2011-03-01

    Respiratory insufficiency is a frequent feature of ALS and is present in almost all cases at some stage of the illness. It is the commonest cause of death in ALS. FVC is used as important endpoint in many clinical trials, and in decision-making events for patients with ALS, although there are limitations to its predictive utility. There are multiple causes of respiratory muscle failure, all of which act to produce a progressive decline in pulmonary function. Diaphragmatic fatigue and weakness, coupled with respiratory muscle weakness, lead to reduced lung compliance and atelectasis. Increased secretions increase the risk of aspiration pneumonia, which further compromises respiratory function. Bulbar dysfunction can lead to nutritional deficiency, which in turn increases the fatigue of respiratory muscles. Early recognition of respiratory decline and symptomatic intervention, including non-invasive ventilation can significantly enhance both quality of life and life expectancy in ALS. Patients with respiratory failure should be advised to consider an advance directive to avoid emergency mechanical ventilation.

  4. Al/Cl2 molten salt battery

    Science.gov (United States)

    Giner, J.

    1972-01-01

    Molten salt battery has been developed with theoretical energy density of 5.2 j/kg (650 W-h/lb). Battery, which operates at 150 C, can be used in primary mode or as rechargeable battery. Battery has aluminum anode and chlorine cathode. Electrolyte is mixture of AlCl3, NaCl, and some alkali metal halide such as KCl.

  5. Cryptanalysis on Cheng et al. protocol

    Science.gov (United States)

    Thakur, Tejeshwari

    2016-06-01

    Deployment of new node in any wireless sensor network is a sensitive task. This is the reason why, an Access Control Protocol is required in WSN. In this paper, we demonstrate that Access Control Protocol proposed by Cheng et al.[1] for Wireless Sensor Network is insecure. The reason is that this protocol fails to resist the active attack.

  6. Del desarrollo rural al desarrollo territorial

    OpenAIRE

    Moyano Estrada, Eduardo

    2010-01-01

    5 páginas.-- Trabajo presentado al Seminario Ruraland celebrado en Antequera (Málaga) el 26 de mayo de 2010.-- Presentado como ponencia a la Jornada de debate "El desarrollo rural en la U.E. despues de 2013" celebrado en Aracena (Huelva) el 10 de junio de 2010 (adjuntado Pdf).

  7. Wallada Bint al Mustakfi entre dos culturas

    Directory of Open Access Journals (Sweden)

    shreen Mahmoud Al Refai

    2013-10-01

    Full Text Available La princesa cordobesa Wallada Bint al Mustakfi bil-lah, hija del califa al Mustakfi Muhammad Ibn Abdel Rahman Ibn Obaidil-lah Ibn Al Nasir lidin Al-lah era una poetisa estimable, a quien los grandes poetas no podían superar. Era una mujer única, guapa y decente. Mantenía una relación sentimental con el  poeta y visir Ibn Zaydún. Dicha pasión, narrada por los poemas escritos por ambos amantes, se terminó por la separación debida a los celos, también de ambos;  al poeta le gustó la voz de una esclava de la princesa. Eso dio rabia a la última. Movido también por los celos, Ibn Zaydún dedicó una epístola satírica al visir Ibn Abdús, que estaba enamorado de Wallada. Tal hecho también irritó a la princesa. A pesar de tener amantes y admiradores, Wallada murió sin casarse al  día 2 de safar de 480 (o 484 de la Híjira pasando los ochenta años Me han llamado la atención el carácter tan culto, independiente y liberal de aquella mujer, su relación amorosa con Ibn Zaydún que no acabó felizmente y los muchos años que vivió sin casasre. Parece que la vida de la princesa hispano-musulmana llamó también la atención de muchos escritores árabes y españoles. Prueba de ello son varias obras literarias escritas en árabe y en español sobre Wallada e Ibn Zaydún. Por consiguiente, me resulta muy interesante realizar un estudio comparativo sobre este tema averiguando si, o no, la diferencia de culturas influiría en las opiniones  de los autores sobre la vida sentimental de aquella poetisa cordobesa.

  8. ELECTROLYSIS OF SWINE MANURE EFFLUENTS USING THREE DIFFERENT ELECTRODES Fe-Fe, Al-Al AND Fe-Al

    Directory of Open Access Journals (Sweden)

    S. Rahman

    2014-01-01

    Full Text Available Swine effluent with high organic strength need to be treated to make it suitable for applying to crop/pasture fields, or discharging to any waterways. Electrocoagulation is a relatively simpler and cheaper technique over biological and chemical treatment methods currently used to treat high-strength industrial and municipal wastewater. The performance of an electrocoagulation system mainly depends on the pH, Electrical Conductivity (EC of the medium, Chemical Oxygen Demand (COD loading rates and catalytic activity of the electrodes used. In this research, a study was conducted to compare the pollutant removal efficiencies of three electrodes (Fe-Fe, Al-Al and Fe-Al with three electric current levels (500, 1000 and 2000 mA while treating swine manure effluents. The electrochemical cell consisted of two parallel rectangular plates (90×25×1.5 mm of Iron (Fe-Fe, Aluminum (Al-Al and Iron-Aluminum (Fe-Al, later on described as hybrid electrodes; immersed in a beaker with 550 mL swine effluents and powered by a Direct Current (DC supply. All studies were conducted in batches at room temperature. In general, removal efficiencies were increased with increasing current densities and electrolysis times for electrodes evaluated. Aluminum electrodes outperformed iron and hybrid (iron-aluminum electrodes in removing Total Phosphorus (TP at all current density levels tested. Overall, use of hybrid electrodes resulted in better COD removal. For the same treatment times (1200 s at higher current density (21 mA cm-2, hybrid electrodes removed about 100% COD, which are about 1.9 and 1.3 times higher than those of aluminum and iron electrodes, respectively. Iron electrodes showed the highest removal efficiency (85% for Total Organic Carbon (TOC at 21 mA cm-2 current density and 1200 s treatment time. Overall, lower Specific Electrical Energy Consumptions (SEECs per kg of Pollutants (TP, COD and TOC were estimated for the aluminum

  9. Investigation Of Water Assisted Phase Transformation Process From AlPO4-5 to AlPO4-tridymite

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Suochang; Zhao, Zhenchao; Hu, Mary Y.; Han, Xiuwen; Hu, Jian Z.; Bao, Xinhe

    2016-03-15

    Water assisted phase transformation process from crystalized AlPO4-5 to AlPO4-tridymite was studied by the combination of X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and in situ multinuclear MAS NMR. It is found that water first activates the residue amorphous aluminophosphate in crystalized AlPO4-5 sample through hydrolysis and condensation reactions. Then the activated aluminophosphate species reassemble into AlPO4-tridymite crystalline. Meanwhile, AlPO4-5 transforms into orthorhombic phase during heating process. With further crystallization of AlPO4-tridymite, the amorphous phase is gradually consumed, and mass transportation between AlPO4-5 and AlPO4-tridymite is established through gradually amorphization of AlPO4-5. Finally, most of the AlPO4-5 transforms into the thermodynamically stable dense phase AlPO4-tridymite.

  10. Medien als Lernform und die Trimediale Redaktion

    Directory of Open Access Journals (Sweden)

    Wolf Hilzensauer

    2015-01-01

    Full Text Available Der vorliegende Artikel beschreibt ein Konzept für eine handlungsorientierte Medienpädagogik im Bildungsbereich. Im Mittelpunkt steht dabei die SO!-Campusredaktion, die als Methode für expansives Lernen die Möglichkeit bietet, unabhängig von Thema oder Medium die Verantwortung für den Lernprozess in die Hände der Lernenden zu legen. Der Dokumentation von Reflexion über den Lernprozess wird dabei eine besondere Bedeutung zugesprochen. Gleichzeitig werden unterschiedliche mediale Gestaltungsmöglichkeiten (Audio/Radio, Video/Fernsehen und Zeitung – sowohl als Print- als auch als Onlinemedium vorgestellt, die durch das Konzept BYOD – bring your own device – auch einfach und niederschwellig im Bildungskontext umsetzbar sind. Dadurch ergeben sich innovative Möglichkeiten, einen Lernprozess sichtbar zu machen und gleichzeitig eine Grundlage für eine alternative Leistungsbeurteilung anzubieten. Die SO!-Campusredaktion wird derzeit an der Pädagogischen Hochschule Salzburg in Kooperation mit dem Communitysender FS1 und der Radiofabrik entwickelt und erprobt. Community Medien nehmen als MedienpartnerInnen eine bedeutende Stellung ein: Durch ihren offenen Zugang zu Know How und Equipment sowie durch die Möglichkeit, Medienproduktionen über die verfügbaren Distibutionskanäle (Radiofrequenz oder Sendeplatz einer breiten Bevölkerung zugänglich zu machen, gewinnt die Medienpädagogik einen wichtigen Mehrwert in ihrer schulischen und außerschulischen Arbeit. (Dieser Artikel knüpft an den Artikel "BYOD, Smartphonefilme und webbasierte Videoschnittprogramme" der Medienimpulse, Ausgabe 2/2014, an.

  11. Evaluación de la corrosión por picadura en aluminio AA1050

    Directory of Open Access Journals (Sweden)

    Luis Garita-Arce

    2014-09-01

    Los ensayos realizados según la norma ASTM G100- 89 para las aleaciones consideradas no indicaron diferencias significativas, aunque sí se observó que la aleación AA1050 presenta mayor susceptibilidad a la picadura en ámbitos de un pH= 7 y con deformaciones elevadas.

  12. Estudio del comportamiento anticorrosivo del fosfosilicato de aluminio en una imprimación reactiva

    OpenAIRE

    Carbonari, Ricardo Obdulio

    2012-01-01

    En la escena internacional actual, el cuidado del medio ambiente es uno de los principales desafíos que enfrenta la industria, entre ellas, la dedicada a los recubrimientos orgánicos. Es por ello que todos los esfuerzos apuntan a la síntesis de productos que sean amigables con el medio ambiente. Esto significa que en el proceso de fabricación de las pinturas hay que identificar cuáles son los componentes verdaderamente inocuos y cuáles no, para lograr, de este modo, producir pinturas totalmen...

  13. A high degree of enhancement of strength of sputter deposited Al/Al2O3 multilayers upon post annealing

    International Nuclear Information System (INIS)

    We report here an order of magnitude enhancement of strength of sputter deposited Al/Al2O3 multilayers after annealing. The increase in strength is shown to be mostly associated with the precipitation of extremely fine γ-Al2O3, 5–10 nm in diameter, in Al layers. This provides a new method of achieving high strength in Al/Al2O3 multilayers that cannot be explained by the Koehler effect or modified Hall–Petch, which will lead to the growth and development of new generation of Al/Al2O3 multilayers. We also examine the fracture behavior of the post annealed Al/Al2O3 multilayered composites with TEM and density functional theory (DFT) simulations. DFT showed that the multilayers are not likely to delaminate at the Al/Al2O3 interface, consistent with the experimental observations. The simulations are also used to determine elastic constants for the γ-Al2O3 phase and to calculate a driving force for O transport from the γ-Al2O3 to the Al layers. The formation of these precipitates is consistent with DFT calculations, which predict an energetic driving force for the dissolution of O atoms from the γ-Al2O3 layers into the Al layers

  14. Spectroscopic analysis of the open 3d subshell transition metal aluminides: AlV, AlCr, and AlCo

    Science.gov (United States)

    Behm, Jane M.; Brugh, Dale J.; Morse, Michael D.

    1994-10-01

    Three open 3d subshell transition metal aluminides, AlV, AlCr, and AlCo, have been investigated by resonant two-photon ionization spectroscopy to elucidate the chemical bonding in these diatomic molecules. The open nature of the 3d subshell results in a vast number of excited electronic states in these species, allowing bond strengths to be measured by the observation of abrupt predissociation thresholds in a congested optical spectrum, giving D00(AlV)=1.489±0.010 eV, D00(AlCr)=2.272±0.009 eV, and D00(AlCo)=1.844±0.002 eV. At lower excitation energies the presence of discrete transitions has permitted determinations of the ground state symmetries and bond lengths of AlV and AlCo through rotationally resolved studies, giving r0` (AlV, Ω`=0)=2.620±0.004 Å and r0` (AlCo, Ω`=3)=2.3833±0.0005 Å. Ionization energies were also measured for all three species, yielding IE(AlV)=6.01±0.10 eV, IE(AlCr)=5.96±0.04 eV, and IE(AlCo)=6.99±0.17 eV. A discussion of these results is presented in the context of previous work on AlCu, AlNi, AlCa, and AlZn.

  15. In-situ synthesized (Al3Zr+Al2O3)p/A356 composites by direct melt reaction in Al-Zr-O system

    Institute of Scientific and Technical Information of China (English)

    赵玉涛; 李忠华; 程晓农; 戴起勋; 蔡兰

    2003-01-01

    A novel in-situ reaction system Al-Zr-O was developed. In situ Al3Zr and Al2O3 particulate reinforced A356 alloy matrix composites have been fabricated by direct melt reaction method. The results show that the maximum sizes of Al3Zr and Al2O3 particulates synthesized in the system ZrOCl2-A356 are 1 μm and 3 μm respectively, and they are well distributed in the matrix. The investigation shows that the Al3Zr crystal is in the shape of polyhedron and rectangle. There is a faceted growth phenomenon on Al3Zr crystal surface. It is firstly found that the Al3Zr crystal grows in the mechanism of twinning. The twinning plane is (1 1 4), and the twinning direction is [2 2 1]. The crystal morphology of in-situ α-Al2O3 particulate is rectangle or sphere. Furthermore, (Al3Zr+Al2O3)p/A356 composites have not only higher tensile strength at room temperature (376.2 MPa) but also higher yield strength (319.4 MPa) and higher tensile strength at elevated temperature (200 ℃) than those of the A356 alloy. The dry sliding wear test shows that the wear resistance of the (Al3Zr+Al2O3)p/A356 composites is greatly enhanced with increasing particulate volume fraction.

  16. Electrical defects in AlGaN and InAlN

    Science.gov (United States)

    Johnstone, D.; Leach, Jacob H.; Kovalskii, Vladimir A.; Fan, Qian; Xie, Jingqiao; Morkoç, Hadis

    2009-02-01

    Compound semiconductors based on GaN have multiple functional applications. Useful compositions include GaN, and ternary and quaternary compositions of (AlGaIn)N. Defects arising from lattice mismatch, point defects, or impurities may act as electrical trapping centers and degrade device efficiency. Current-voltage, capacitance-voltage, thermal admittance spectroscopy (TAS), and deep level transient spectroscopy (DLTS) measurements are applied to characterize the defects in Al0.40Ga0.80N and In0.18Al0.82N in this report. Broad peaks with a shoulder at high temperature dominate the DLTS spectra in each of the materials. An acceptor trap associated with a dislocation appears at 340 K in AlGaN. The defect has an energy of 0.2 eV and capture cross section of 10-21 cm2. A second trap at 0.35 eV, 10-14 cm2 appears in the TAS measurements in addition to the trap at 0.2 eV. Defects in InAlN are dominated by a peak near 150 K. Two traps appear in the TAS measurements. Both traps in the InAlN are acceptors, based on a lack of field dependent emission rates using double pulse DLTS (DDLTS). The two energy levels in InAlN appear to be coupled, with only one state occupied at a time.

  17. Thermoelectric Powers of Cells With NaF-AlF3-Al2O3 Melts

    Science.gov (United States)

    Flem, Belinda E.; Xu, Qian; Kjelstrup, Signe; Sterten, Åsmund

    2001-07-01

    A thermodynamic description of the Peltier heat at the aluminum and the oxygen electrode in the system NaF-AlF3-Al2O3 is given. The thermoelectric power in melts with molar ratios n NaF/n AlF3 from 3.0 to 1.0, saturated with alumina are measured. Seebeck coefficients for molten fluoride electrolytes saturated with alumina, electrolytes that are relevant for aluminum electrowinning electrolysis cells, are reported. The results allow determinations of Peltier heats of aluminum, oxygen and carbon electrodes in NaF-AlF3 electrolytes saturated with alumina. For molar ratios of n NaF/n AlF3 between 2.6 and 1.2, there is a Peltier heating of the aluminum cathode. This heating is in the same order of magnitude as the electrolyte Joule heat, when the current density is 0.7 A cm-2. For molar ratio n NaF/n AlF3 equal to 1.0 the Peltier effect at the aluminum electrode approaches zero. From theoretical considerations we expect a drop also for molar ratio 3.0. For the anode we report a Peltier cooling that is larger than the heat produced by the anodic overvoltage, in melts with NaF/AlF3 molar ratio between 2.6 and 1.2 saturated with alumina.

  18. PRECIPITATION HARDENING IN B2-ORDERED NiAl BY Ni2AlTiCOMPOUND

    Institute of Scientific and Technical Information of China (English)

    W.H. Tian; K. Ohishi; M. Nemoto

    2001-01-01

    Microstructural variations and correlated hardness changes in B2-ordered NiAl containing fine precipitation of Ni2AlTi have been investigated by means of transmission electron microscopy (TEM) and hardness tests. The amount of age hardening is not large as compared to the large microstructural variations during aging. TEM observations have revealed that the L21-type Ni2AlTi precipitates keep a lattice coherency with the NiAl matrix at the beginning of aging. By longer periods of aging Ni2AlTi precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. The temperature dependence of the yield strength of precipitate-containing B2-ordered NiAl was investigated by compression tests over the temperature range of 873-1273K. The fine precipitation of Ni2AlTi was found to enhance greatly the yield strength and the high-temperature strength is comparison with that of superalloy Mar-M200.``

  19. Fabrication and Mechanical Properties of Al_2O_3/TiAl Composites

    Institute of Scientific and Technical Information of China (English)

    AI Taotao

    2009-01-01

    Al_2O_3/TiAl composites were successfully fabricated by hot-press-assisted exother-mic dispersion method with elemental powder mixtures of Ti,Al TiO_2 and Nb_2O_5,and the micro-structure and mechanical properties were investigated.The results indicate the fine Al_2O_3 particles tend to disperse on the grain boundaries.The grain size of TiAl matrix decreases and the hardness increases with increasing Nb_2O_5 content.The bending strength and fracture toughness reach to a maximum when Nb_2O_5 content is 6 wt%,under 642 Mpa and 6.69 Mpa·m ~(1/2) ,respectively.Based on the fractography and the observation of crack propagation path,it is concluded that the strengthening and toughening of such composites at room temperature can be attributed to the refinement of the TiAl matrix,the de-flection behavior in the crack propagation and the dispersion of Al_2O_3 particles.

  20. Neutronic comparison of the nuclear fuels U3Si2/Al and U-Mo/Al

    International Nuclear Information System (INIS)

    The search for materials that allow the fabrication of nuclear fuels with higher uranium densities comes from the mid 50s. Today, a high density and low enriched nuclear fuel based on γ-UMo alloys is the most promising fuel to replace the U3Si2/Al dispersion fuel used worldwide in research and material test reactors. Alloys of uranium-molybdenum are prepared with 6 to 10% Mo addition and can be manufactured as dispersion or monolithic fuels. The aim of this paper is to compare the infinite multiplication factor (K∞), obtained through neutronic calculation with the code Scale 6, for aluminum coated plates reflected in all directions containing U3Si2/Al and U-Mo/Al dispersion fuels. The U3Si2/Al dispersion fuel used in the calculation has an uranium density of 4 gU/cm3 and the U-Mo-Al dispersion fuels have densities ranging from 4 to 7.52 gU/cm3 and 7 and 10% Mo addition. The results show that the K∞ calculated for U-Mo/Al fuels is lower than that for U3Si2/Al fuel and increases between the uranium densities of 4 and 5 gU/cm3 and decreases for higher uranium densities. (author)

  1. Microstructure of Ni-Al powder and Ni-Al composite coatings prepared by twin-wire arc spraying

    Institute of Scientific and Technical Information of China (English)

    Ji-xiao Wang; Gui-xian Wang; Jing-shun Liu; Lun-yong Zhang; Wei Wang; Ze Li; Qi-xiang Wang; Jian-fei Sun

    2016-01-01

    Ni–Al powder and Ni–Al composite coatings were fabricated by twin-wire arc spraying (TWAS). The microstructures of Ni-5wt%Al powder and Ni-20wt%Al powder were characterized by scanning electronic microscopy (SEM) and energy dispersive spec-troscopy (EDS). The results showed that the obtained particle size ranged from 5 to 50μm. The morphology of the Ni–Al powder showed that molten particles were composed of Ni solid solution, NiAl, Ni3Al, Al2O3, and NiO. The Ni–Al phase and a small amount of Al2O3 parti-cles changed the composition of the coating. The microstructures of the twin-wire-arc-sprayed Ni–Al composite coatings were characterized by SEM, EDS, X-ray diffraction (XRD), and transmission electron microscopy (TEM). The results showed that the main phase of the Ni-5wt%Al coating consisted of Ni solid solution and NiAl in addition to a small amount of Al2O3. The main phase of the Ni-20wt%Al coating mainly consisted of Ni solid solution, NiAl, and Ni3Al in addition to a small amount of Al and Al2O3, and NiAl and Ni3Al intermet-allic compounds effectively further improved the final wear property of the coatings. TEM analysis indicated that fine spherical NiAl3 pre-cipitates and a Ni–Al–O amorphous phase formed in the matrix of the Ni solid solution in the original state.

  2. Mechanical Properties and Microstructure of Neutron Irradiated Cold-worked Al-1050 and Al-6063 Alloys

    International Nuclear Information System (INIS)

    The impact of neutron irradiation on the internal microstructure, mechanical properties and fracture morphology of cold-worked Al-1050 and Al-6063 alloys was studied, using scanning and transmission electron microscopy, and tensile measurements. Specimens consisting of 50 mm long and 6 mm wide gauge sections, were punched out from Al-1050 and Al-6063 23% cold-worked tubes. They were exposed to prolonged neutron irradiation of up to 4.5x1025 and 8x1025 thermal neutrons/m2 (E -3 s-1. In general, the uniform and total elongation, the yield stress, and the ultimate tensile strength increase as functions of fluence. However, for Al-1050 a decrease in the ultimate tensile strength and yield stress was observed up to a fluence of 1x1025 thermal neutrons/m2 which then increase with thermal neutrons fluence. Metallographic examination and fractography for Al-6063 revealed a decrease in the local area reduction of the final fracture necking. This reduction is accompanied by a morphology transition from ductile transgranular shear rupture to a combination of transgranular shear with intergranular dimpled rupture. The intergranular rupture area increases with fluence. In contrast, for Al-1050, fracture morphology remains ductile transgranular shear rupture and the final local area reduction remains almost constant No voids could be observed in either alloy up to the maximum fluence. The dislocation density of cold-worked Al was found to decrease with the thermal neutron fluence. Prolonged annealing of unirradiated cold-worked Al-6063 at 52 degree led to similar results. Thus, it appears that, under our irradiation conditions, whereby the temperature encompassing the samples increases the exposure to this thermal field is the major factor influencing the mechanical properties and microstructure of aluminum alloys

  3. An Epidemiological Study of Cutaneous Leishmaniasis in Al-Jabal Al-Gharbi, Libya

    Science.gov (United States)

    Abdellatif, Manal Z. M.; El-Mabrouk, Khamis

    2013-01-01

    Cutaneous leishmaniasis (CL) is an endemic parasitic infection in the Mediterranean region, including Libya and its Al-jabal Al-gharbi province. We aimed at studying the occupational relevance as well as other epidemiological aspects of CL. We investigated 140 CL cases who attended at Gharyan outpatient polyclinic during a period of 6 months in 2009. CL infection was clinically diagnosed and confirmed by demonstration of Leishmania parasites on smears from lesions. Our findings showed that males were more affected than females (P=0.04), and people above 10-years were more affected than younger ones (P=0.0001). A significant percent of CL cases belonged to Al-Kawasem subprovince (P=0.0001). Farm-related activities were the most frequent occupations among CL cases (P=0.04). In addition to farm workers, housewives and students are at risk groups since they are engaged at farm activities. Moreover, those who have occupations that require staying outdoors for a part of night, e.g., policemen, are also at risk. Compared to children, adult CL patients had multiple lesions (P=0.001) that were more prevalent in their upper and lower extremities than the face (P=0.0001). We conclude that CL is a major health problem in Al-jabal Al-gharbi province of Libya. The presence of rodents and sandflies makes it a suitable environment for Leishmania to spread in an endemic epidemiological pattern. Being engaged in farming activities or outdoor occupations increases the risk of infection. Various clinical patterns of CL suggest the presence of more than 1 species of Leishmania at Al-jabal Al-gharbi province. We propose that the 2 species responsible for CL in this area are L. major and L. tropica. Further investigations to identify the leishmanial species responsible for CL at Al-jabal Al-gharbi together with adoption of preventive and control programs are needed. PMID:23467624

  4. An epidemiological study of cutaneous leishmaniasis in Al-jabal Al-gharbi, Libya.

    Science.gov (United States)

    Abdellatif, Manal Z M; El-Mabrouk, Khamis; Ewis, Ashraf A

    2013-02-01

    Cutaneous leishmaniasis (CL) is an endemic parasitic infection in the Mediterranean region, including Libya and its Al-jabal Al-gharbi province. We aimed at studying the occupational relevance as well as other epidemiological aspects of CL. We investigated 140 CL cases who attended at Gharyan outpatient polyclinic during a period of 6 months in 2009. CL infection was clinically diagnosed and confirmed by demonstration of Leishmania parasites on smears from lesions. Our findings showed that males were more affected than females (P=0.04), and people above 10-years were more affected than younger ones (P=0.0001). A significant percent of CL cases belonged to Al-Kawasem subprovince (P=0.0001). Farm-related activities were the most frequent occupations among CL cases (P=0.04). In addition to farm workers, housewives and students are at risk groups since they are engaged at farm activities. Moreover, those who have occupations that require staying outdoors for a part of night, e.g., policemen, are also at risk. Compared to children, adult CL patients had multiple lesions (P=0.001) that were more prevalent in their upper and lower extremities than the face (P=0.0001). We conclude that CL is a major health problem in Al-jabal Al-gharbi province of Libya. The presence of rodents and sandflies makes it a suitable environment for Leishmania to spread in an endemic epidemiological pattern. Being engaged in farming activities or outdoor occupations increases the risk of infection. Various clinical patterns of CL suggest the presence of more than 1 species of Leishmania at Al-jabal Al-gharbi province. We propose that the 2 species responsible for CL in this area are L. major and L. tropica. Further investigations to identify the leishmanial species responsible for CL at Al-jabal Al-gharbi together with adoption of preventive and control programs are needed.

  5. Two medieval Maghreb chronicles: Al-Ḏajira Al-Saniyya y el Rawd al-Qirtas

    Directory of Open Access Journals (Sweden)

    Lidia Fernández Fonfría

    2010-03-01

    Full Text Available In the present communication I intend to expose my conclusions on asmall comparative study between two of the earliest Maghreb chronicles throwing information about the North African tribe of Banu Mar÷n arrival to the throne in the thirteenth century Maghreb. With these common features, allowing a more complete picture of anera, which is undoubtedly the least known of the merinid period, their beginning. The similarities and influences between them are such that there are different theories about a possiblecommon authorship. After concluding the study and subsequent analysis of these works, can be extracted that there are substantial differences on a structural and stylistic level that hinder the possible absolute identification of author of the Dhakh÷ra al-Saniyyawith the author of RawÅ al-QirÐās.

  6. AlSb precipitate evolution during Sb implantation in Al: experiment and theory

    International Nuclear Information System (INIS)

    Precipitate evolution during ion implantation has been studied in the model system Sb-implanted Al. Transmission electron microscopy was used to determine the size distribution of AlSb crystallites as a function of fluence, flux, and sample temperature. There was a dramatic increase in average size, accompanied by a decrease in number density, for increasing fluence, for decreasing flux, and for increasing temperature. A new theoretical model for the evolution of the precipitate size distribution has been developed which incorporates both thermal processes and implantation effects. Numerical solutions for the AlSb system using physically realistic parameters agree qualitatively with the experimentally observed evolutions

  7. AL-HIKMAH AL-MUTA‘ÂLIYYAH PEMIKIRAN METAFISIKA EKSISTENSIALISTIK MULLA SHADRA

    Directory of Open Access Journals (Sweden)

    Sholihan Sholihan

    2015-04-01

    Full Text Available Among the meritorious figures that develop the illuminative thought initiated by Suhrawardi is Shadr al-Dîn  al-Shirazi, also known as Mulla Sadra. He is well known with his thought of al-Hikmah al-Muta'âliyyah or transcendent theosophy, an effort of harmonizing revelation, gnosis, and philosophy. He inflame an idea where the logic buried in the sea of light gnosis. He called the synthesis—one that he considered to be the particular basis of three major paths to truth for man, namely: revelation (wahy or shar', intellection ('aql, and mystical vission (Kashf—as al-Hikmah al-Muta‘âliyyah or transcendent theosophy. He has managed to make synthesis between deductive method of the Peripatetic, method of illumination, method of the odyssey of ‘irfân or Sufism, and method of Kalam. When his thought is compared with existentialistic thought of West, then there is a point of similarities among them not only in terms of technical language, but also in substantive matters.Abstract: Di antara tokoh yang berjasa mengembangkan pemikiran iluminatif dari Suhrawardi adalah Shadr al-Dîn  al-Syirâzî atau Mulla Shadra yang populer dengan pemikirannya tentang al-Hikmah al-Muta’âliyyah atau teosofi transenden, suatu upaya harmonisasi wahyu, gnosis, dan filsafat. Dia menggelorakan sebuah pemikiran di mana logika dibenamkan ke dalam lautan cahaya gnosis. Ia menyebut sintesisnya—yang ia anggap menjadi dasar khususnya tentang tiga jalan besar menuju kebenaran bagi manusia, yakni: wahyu (wahy atau syar’, intellection (‘aql, dan keterbukaan secara mistik (kasyf—dengan al-Hikmah al-Muta’âliyyah atau teosofi transenden. Dia telah berhasil melakukan sintesis antara metode deduktif dari peripatetik, metode illuminasi, metode pengembaraan dari ‘irfân atau sufisme, dan metode kalâm. Ketika pemikirannya diperbandingkan dengan pemikiran eksistensialistik Barat, maka ada titik kesamaan tidak saja dari segi teknis kebahasaan, melainkan juga pada

  8. Hardness Measurement of (TiB2-TiAl)/TiAl Symmetrically Function Gradient Materials

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    (TiB2-TiAl)/TiAl symmetrically function gradient materials (FGM) were prepared by spark plasma sintering (SPS). Owing to the difference of the thermal expansion coefficients between TiB2 and TiAl, a compressive surface stress was introduced to the FGM by the thermal expansion mismatch. The hardness values of the uniform materials and the FGM were tested, respectively. For the FGM with a compressive surface stress, hardness is obviously superior to that of the uniform material.When the FGM was subjected to heat treatment,the hardness decreased due to a partial relaxation of the compressive surface stress.

  9. A 25-year replication of Katz et al.'s (1988) metaphor norms.

    Science.gov (United States)

    Campbell, Spencer J; Raney, Gary E

    2016-03-01

    Research in metaphor processing has made extensive use of the normed metaphor database created by Katz, Paivio, Marschark, & Clark (Metaphor and Symbolic Activity, 3, 191-214, 1988). Because of the plasticity of figurative language, we conducted a renorming of selected metaphors from the database on a new student population. Correlations between Katz et al.'s and the present data showed that the pattern of responses has remained highly consistent across time and populations. The consistency of the normative ratings allows us to be confident in future research that will use the Katz et al. collection. PMID:25772671

  10. Influence of matrix characteristics on fracture toughness of high volume fraction Al2O3 / Al-AlN composites

    OpenAIRE

    Nagendra, N.; Jayaram, V

    2000-01-01

    The role of matrix microstructure on the fracture of Al-alloy composites with 60 % volume of alumina particulates has been studied. The matrix composition and microstructure were systematically varied by changing the infiltration temperature and heat treatment. Characterisation was carried out by a combination of metallography, hardness measurements and fracture studies conducted on compact tension (CT) specimens to study the fracture toughness and crack growth in the composites. The composit...

  11. Electrochemical corrosion behavior of arc sprayed Zn-Al coatings

    Institute of Scientific and Technical Information of China (English)

    LIU Yan; ZHU Zi-xin; CHEN Yong-xiong; XU Bin-shi; MA Shi-ning; LI Zhuo-xin

    2004-01-01

    Cored wires and high velocity arc spraying (HVAS) technique were applied to produce high Al content Zn-Al alloy coatings on low carbon steel substrates. The electrochemical corrosion behaviors of Zn, Al and Zn-Al coatings were studied with potentiodynamic measurement in 5 % NaCl solution. Compared with pure Zn, pure Al and Zn-15Al coatings, Zn-26Al coatings show a higher corrosion resistance in salt solution. The potentiodynamic polarization tests show that the corrosion resistance of Zn-Al coatings increases as Al content is raised. Pure Al coating exhibits different electrochemical behaviors with other coatings. The corrosion initiated at the micro-pores of the coating and the underlying corrosion mechanism is very similar to that of the pitting corrosion.

  12. Questioning of Authentication and Epistemology in Tafsir al-Jilani

    Directory of Open Access Journals (Sweden)

    Irwan Masduqi

    2012-06-01

    Full Text Available In this research, the author critically analyzes a biography of Shaikh ‘Abd al-Qadir al-Jilani containing sacred myths. The analyst of sacred myth about ‘Abd al-Qadir al-Jilani is based on the approach of applied anthropology to distinguish between the myths that have  positive and negative values for Muslim society. This research then analyzes the authenticity of Tafsir al-Jilani and the epistemology of his inter- pretation. ‘Abd al-Qadir al-Jilani is the founder of Qadiriyah. Qadiriyah doctrines has been widely accepted by traditional Muslim groups in Muslim world, so that the study of Tafsir al-Jilani is very meaningful for the followers of Qadiriyah in particu- lar and the lovers of Quranic studies in general to increase their knowledge about the teachings of ‘Abd al-Qadir al-Jilani.

  13. Oxidation Behaviour of Sputtered Ni-3Cr-20Al Alloy

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The oxidation behavior of sputtered Ni-3Cr-20Al coating at 900°C in air was investigated. A dense Al2O3 layer was formed on the sputtered Ni-3Cr-20Al coating after 200 h oxidation.However, owing to the segregation of Ni3Al during oxidation Focess at high temperature, the spinel NiAl2O4 was also formed in the Al2O3 layer. It was found that the formation of NiAl2O4had no detrimental effect on the oxidation resistance of the sputtered Ni-3Cr-20Al coating due to the excellent adhesion shown by the Al2O3 and NiAl2O4 complex oxide scale.

  14. Environmental embrittlement of intermetallic compounds in Fe-Al alloys

    Institute of Scientific and Technical Information of China (English)

    张建民; 张瑞林; S.H.YU; 余瑞璜

    1996-01-01

    First,it is proposed that hydrogen atoms occupy the interstitial sites in Fe3Al and FeAl.Then the environmental embrittlement of intermetallic compounds in Fe-Al alloys is studied in the light of calculated valence electron structures and bond energy of Fe3Al and FeAl containing hydrogen atoms.From the analyses it is found that the states of metal atoms will change,in which more lattice electrons will become covalent electrons to bond with hydrogen atoms when the atomic hydrogen diffuses into the intermetallic compounds in Fe-Al alloys,which will result in the decrease of local metallicity in Fe3Al and FeAl.Meanwhile,it is found that the crystal will easily cleave since solute hydrogen bonds with metal atoms and severely anisotropic bonds form.As a conclusion,these factors result in the environmental embrittlement of Fe3Al and FeAl.

  15. Gate length scaling effect on high-electron mobility transistors devices using AlGaN/GaN and AlInN/AlN/GaN heterostructures.

    Science.gov (United States)

    Liao, S Y; Lu, C C; Chang, T; Huang, C F; Cheng, C H; Chang, L B

    2014-08-01

    Compared to AlGaN/GaN HEMT with 0.15 μm T-gate length, the AlInN/AlN/GaN one exhibits much higher current density and transconductance of 1558 mA/mm at Vd = 2 V and 330 mS/mm, respectively. The high extrinsic ft and fmax of 82 GHz and 70 GHz are extracted from AlInN/AlN/GaN HEMT. Besides, we find that the transconductance roll-off is significant in AlGaN/GaN, but largely improved in AlInN/AlN/GaN HEMT, suggesting that the high carrier density and lattice-matched epitaxial heterostructure is important to reach both large RF output power and high operation frequency, especially for an aggressively gate length scaling.

  16. The Formation of γ—AlON Spinel in the Reaction of Al2O3—AlN—MgO System

    Institute of Scientific and Technical Information of China (English)

    LIYawei; YUANRunzhang; 等

    1997-01-01

    The stabilization of γ-aluminium oxyni-tride spinel(γ-AlON) has been investigated by addition of MgO,MgAl2O4,etc.,in reaction process.The results indicated that there are wider solid solution areas near ,Al2O3-rich side in AlN-Al2O3-MgO ternary systems,The content of stabilized AlON phase in samples is related to heating temperatures,additives,etc.The lattice parameters of their AlON phases could be well describedby the equation: a0=0.7900+0.0375[MgO]+0.015[AlN](nm)

  17. Properties of porous FeAlO/FeAl ceramic matrix composite influenced by mechanical activation of FeAl powder

    Indian Academy of Sciences (India)

    V Usoltsev; S Tikhov; A Salanov; V Sadykov; G Golubkova; O Lomovskii

    2013-12-01

    Porous ceramic matrix composites FeAlO/FeAl with incorporated metal inclusions (cermets) were synthesized by pressureless method, which includes hydrothermal treatment of mechanically alloyed FeAl powder followed by calcination. Their main structural, textural and mechanical features are described. Variation of FeAl powder alloying time results in non-monotonous changes of the porosity and mechanical strength. Details of the cermet microstructure and its relation to the mechanical properties are discussed.

  18. ALS1 and ALS3 gene expression and biofilm formation in Candida albicans isolated from vulvovaginal candidiasis

    Directory of Open Access Journals (Sweden)

    Shahla Roudbarmohammadi

    2016-01-01

    Conclusion: The results attained indicated that there is an association between the expression of ALS1 and ALS3 genes and fluconazole resistance in C. albicans. A considerable percent of the isolates expressing the ALS1 and ALS3 genes may have contributed to their adherence to vagina and biofilm formation.

  19. Spatial and temporal mapping of Al and AlO during oxidation in pulsed laser ablation of LaAlO3

    NARCIS (Netherlands)

    Orsel, K.; Groenen, R.; Bastiaens, H.M.J.; Koster, G.; Rijnders, G.; Boller, K-J.

    2013-01-01

    We present the first spatio-temporal mapping of two simultaneously present species in a plasma used for pulsed laser deposition. We apply laser induced fluorescence spectroscopy (LIF) to map ground state populations of Al and AlO in plasma plumes generated by ablation of LaAlO3 in an O2 or Ar atmosp

  20. The Byzantines in Medieval Arabic Poetry: Abu Firas’ "Al-Rumiyyat" and the Poetic Responses of al-Qaffal and Ibn Hazm to Nicephore Phocas’ "Al-Qasida al-Arminiyya al-Malʿuna" (The Armenian Cursed Ode

    Directory of Open Access Journals (Sweden)

    Nizar F. HERMES

    2009-10-01

    Full Text Available Up until the Crusades, it was al-Rūm who were universally seen by Arab writers and Arab poets in particular as the Other par excellence. Nowhere is this more conspicuous than in the sub-genre of Al-Rūmiyyat (poems about the Byzantines, namely as found in the Rūmiyyat of Abu Firas al-Hamdani(d.968, and in the poetic responses of al-Qaffal(d. 946 and Ibn Hazm(d. 1064 to what was described by several medieval Muslim chronicles as Al-Qasida al-Arminiyya al-Malʿuna (The Armenian Cursed Ode. By exploring the forgotten views of the Byzantines in medieval Arabic poetry, this article purports to demonstrate that contrary to the impression left after reading Edward Said’s groundbreaking Orientalism: Western Conceptions of the Orient (1978 and other postcolonial studies, Orientals have not existed solely to be ‘orientalized’. Perhaps even before this came to be so, they too had ‘occidentalized’ their Euro-Christian Other(s in a way that mirrored in reverse the subject/object relationship described as Orientalism.

  1. Fabrication of high-quality submicron Nb/Al-AlOx/Nb tunnel junctions

    Institute of Scientific and Technical Information of China (English)

    Yu Hai-Feng; Cao Wen-Hui; Zhu Xiao-Bo; Yang Hai-Fang; Yu Hong-Wei; Ren Yu-Feng; Gu Chang-Zhi; Chen Geng-Hua; Zhao Shi-Ping

    2008-01-01

    Nb/Al-AlOx/Nb tunnel junctions are often used in the studies of macroscopic quantum phenomena and supercon-ducting qubit applications of the Josepheon devices. In this work, we describe a convenient and reliable process using electron beam lithography for the fabrication of high-quality, submicron-sized Nb/Al-AlOx/Nb Josephson junctions.The technique follows the well-known selective Nb etching process and produces high-quality junctions with Vm=100 mV at 2.3 K for the typical critical current density of 2.2 kA/cm2, which can be adjusted by controlling the oxygen pressure and oxidation time during the formation of the tunnelling barrier. We present the results of the temperature depen-dence of the sub-gap current and in-plane magnetic-field dependence of the critical current, and compare them with the theoretical predictions.

  2. Evolutions during synthesis of Al-AlN-nanostructured composite powder by mechanical alloying

    Energy Technology Data Exchange (ETDEWEB)

    Abdoli, H. [Department of Materials Science and Engineering, Sharif University of Technology, P.O. Box 11365-9466, Azadi Avenue, 14588 Tehran (Iran, Islamic Republic of)], E-mail: habdoli@mehr.sharif.edu; Salahi, E. [Ceramic Department, Materials and Energy Research Center (MERC), P.O. Box 31787-316, Karaj (Iran, Islamic Republic of); Farnoush, H.; Pourazrang, K. [Department of Materials Science and Engineering, Sharif University of Technology, P.O. Box 11365-9466, Azadi Avenue, 14588 Tehran (Iran, Islamic Republic of)

    2008-08-11

    High-energy milling technique was used to synthesize Al-10 wt.%AlN-nanostructured composite powder in a planetary ball-mill under argon atmosphere up to 25 h. To show the role of AlN particles, process was conducted for monolithic aluminum. The changes in powder characteristics were investigated by time. Microstructure of powders was studied after different milling times by scanning electron microscope (SEM). The morphological evolutions showed that relative equiaxed powder could be synthesized after 25 h milling. Structural analysis was performed by X-ray diffraction method (XRD) to determine the grain sizes and lattice strain. Furthermore, particle size analysis (PSA) revealed the distribution curvatures. The compressibility behavior of milled powders was studied at different compaction pressures which involve the rearrangement and plastic deformation stages. The modified Heckel equation was used to consider the pressure effect on yield strength as well as reinforcing role of hard AlN particles.

  3. Effect of partial melting on superplasticity ofAlNp/6061Al composite

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    AlN particulate reinforced 6061 aluminum alloy composite was fabricated by powder metallurgy method and hot-rolled after extrusion. Tensile strength and elongation at elevated temperature were measured by tensile test at initial strain rates between 10-2 s-1 and 100 s-1. The AlNp/6061Al composite exhibits an m-value of 0.42 and a maximum elongation of 450% at 863?K. Differential scanning calorimeter was used to ascertain the possibility of any partial melting in the vicinity of optimum superplastic temperature. Partial melting resulting from solute segregation at interfaces has much influence on superplasticity of the composite. It is postulated that AlNp/matrix interface sliding occurs along with grain boundary in superplastic deformation.

  4. Characterization of Al30 in commercial poly-aluminum chlorohydrate by solid-state (27)Al NMR spectroscopy.

    Science.gov (United States)

    Phillips, Brian L; Vaughn, John S; Smart, Scott; Pan, Long

    2016-08-15

    Investigation of commercially produced hydrolysis salts of aluminum by solid-state (27)Al NMR spectroscopy and size-exclusion chromatography (SEC) reveals well-defined and distinct Al environments that can be related to physicochemical properties. (27)Al MAS and MQ-MAS NMR spectroscopic data show that the local structure of the solids is dominated by moieties that closely resemble the Al30 polyoxocation (Al30O8(OH)56(H2O)26(18+)), accounting for 72-85% of the total Al. These Al30-like clusters elute as several size fractions by SEC. Comparison of the SEC and NMR results indicates that the Al30-like clusters includes intact isolated clusters, moieties of larger polymers or aggregates, and possibly fragments resembling δ-Al13 Keggin clusters. The coagulation efficacy of the solids appears to correlate best with the abundance of intact Al30-like clusters and of smaller species available to promote condensation reactions. PMID:27232539

  5. Structure of molten Al-Si alloys

    International Nuclear Information System (INIS)

    The temperature variation of the structure and microstructure of molten eutectic Al1-xSix alloys (x = 0.122 and 0.20) have been studied by neutron diffraction and small-angle neutron scattering (SANS), as well as measurements performed on pure liquid Al. All measurements have been performed at five temperatures in a heating-cooling loop. The SANS results unambiguously show that for the eutectic alloy (x = 0.122) the microstructure changes with increasing temperature in a partly reversible way while for the hypereutectic (x = 0.20) alloy the change is almost completely irreversible. This change in microstructure also manifests itself in the shape of the static structure factor S(Q)

  6. Status of the AlCap experiment

    CERN Document Server

    Litchfield, R Phillip

    2015-01-01

    The AlCap experiment is a joint project between the COMET and Mu2e collaborations. Both experiments intend to look for the lepton-flavour violating conversion $\\mu + A \\rightarrow e + A$, using tertiary muons from high-power pulsed proton beams. In these experiments the products of ordinary muon capture in the muon stopping target are an important concern, both in terms of hit rates in tracking detectors and radiation damage to equipment. The goal of the AlCap experiment is to provide precision measurements of the products of nuclear capture on Aluminium, which is the favoured target material for both COMET and Mu2e. The results will be used for optimising the design of both conversion experiments, and as input to their simulations. Data was taken in December 2013 and is currently being analysed.

  7. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Viswanathan, S.; Santella, M.L. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, wire, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for: (1) high-strength castable composition for many applications that have been identified; (2) castability (mold type, fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) workability of cast or powder metallurgy product to sheet, bar, and wire. The four issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes the work completed to address some of these issues during FY 1996.

  8. Structure of molten Al-Si alloys

    Energy Technology Data Exchange (ETDEWEB)

    Dahlborg, U. [CNRS, Ecole des Mines, Nancy, France; Besser, M. [Ames Laboratory; Calvo-Dahlborg, M. [CNRS, Ecole des Mines, Nancy, France; Cuello, G. [Institut Laue-Langevin (ILL); Dewhurst, C. D. [Institut Laue-Langevin (ILL); Kramer, Matthew J. [Ames Laboratory; Morris, James R [ORNL; Sordelet, Daniel [Ames Laboratory

    2007-01-01

    The temperature variation of the structure and microstructure of molten eutectic Al{sub 1-x}Si{sub x} alloys (x = 0.122 and 0.20) have been studied by neutron diffraction and small-angle neutron scattering (SANS), as well as measurements performed on pure liquid Al. All measurements have been performed at five temperatures in a heating-cooling loop. The SANS results unambiguously show that for the eutectic alloy (x = 0.122) the microstructure changes with increasing temperature in a partly reversible way while for the hypereutectic (x = 0.20) alloy the change is almost completely irreversible. This change in microstructure also manifests itself in the shape of the static structure factor S(Q).

  9. Antiferromagnetic behaviour of Tb2Al alloy

    Science.gov (United States)

    Rojas, D. P.; André, G.; Rodríguez Fernández, J.; Sánchez Marcos, J.; Fernández Barquín, L.; Echevarria, C.

    2011-10-01

    The structural, thermal and magnetic properties ol the Tb2Al alloy have been investigated by AC/DC magnetic susceptibility, specific heat, X-ray and neutron diffraction measurements. DC and AC-magnetic susceptibility results are consistent with an AFM order at TN = 52 K. The specific heat data show a lambda anomaly associated to the magnetic transition with a peak at 52 K (cord = 99 J/molTbK). The analysis of thermodiffractograms of neutron diffraction patterns indicates that, below the ordering temperature, the magnetic reflections can be indexed with a commensurate lattice related to the crystallographic cell (Pmna) by a propagation vector k = (1/2, 1/2, 1/2). The results are compared with those reported for other magnetic rare earth alloys of R2Al-type (with R = Nd, Gd and Dy).

  10. Antiferromagnetic behaviour of Tb2Al alloy

    International Nuclear Information System (INIS)

    The structural, thermal and magnetic properties ol the Tb2Al alloy have been investigated by AC/DC magnetic susceptibility, specific heat, X-ray and neutron diffraction measurements. DC and AC-magnetic susceptibility results are consistent with an AFM order at TN = 52 K. The specific heat data show a lambda anomaly associated to the magnetic transition with a peak at 52 K (cord = 99 J/molTbK). The analysis of thermodiffractograms of neutron diffraction patterns indicates that, below the ordering temperature, the magnetic reflections can be indexed with a commensurate lattice related to the crystallographic cell (Pmna) by a propagation vector k = (1/2, 1/2, 1/2). The results are compared with those reported for other magnetic rare earth alloys of R2Al-type (with R = Nd, Gd and Dy).

  11. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Santella, M.L.; Alexander, D.J. [Oak Ridge National Laboratory, TN (United States)] [and others

    1995-05-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for (1)high-strength castable composition for turbochargers, furnace furniture, and hot-die applications; (2) castability (fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) hot fabricability of cast ingots. All of the issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes work completed to address some of these issues during the fourth quarter of FY 1994.

  12. [Communication with ALS patients: neurosurgical approach].

    Science.gov (United States)

    Yoshimine, Toshiki; Yanagisawa, Takufumi; Sawada, Jin-Ichi; Hazama, Takanori; Mochizuki, Hideki; Hirata, Masayuki

    2013-01-01

    By progression of the disease, motor neurons degenerate in patients with amyotrophic lateral sclerosis (ALS) eventually lose nearly all voluntary muscles in the body. They are awake and aware but cannot move or communicate (locked-in state). Since the function of the brain is preserved, one possible measure to support their communication is to interpret their motor intention by decoding (deciphering) brain signals and present it with external devices. This technology called "brain-machine interface (BMI)" is now close to clinical use in Japan and USA.In our system, we record electrocorticogram (ECoG) obtained with subudural electrodes during their motor imagery, decode it and determine the movement they intended. So far, one patient of ALS with severe paralysis, implanted with this electrodes, successfully operated the PC communication tool only by thinking.

  13. Léxico relativo al vestuario infantil

    OpenAIRE

    Torres Villaseñor, Hermila E.; Centro de Lingüística Hispánica, IIFL, UNAM

    2013-01-01

    Con base en el Cuestionario preparado por la Comisión de Lingüísticay Dialectología Iberoamericanas para el estudio del españolc ontemporáneo, preparé un cuestionario más amplio, con el cual he llevado a cabo una investigación sobre el léxico referente al vestido, según se emplea actualmente en la ciudad de México. Presento aquí los resultados de mi estudio en lo que respecta, únicamente, al vestuario de los niños menores de un año. Toda ladocumentación fue proporcionada por doce informantes ...

  14. Forging of FeAl intermetallic compounds

    Energy Technology Data Exchange (ETDEWEB)

    Flores, O.; Juarez, J.; Campillo, B.; Martinez, L. [UNAM, Cuernavaca (Mexico). Lab. de Cuernavaca; Schneibel, J.H. [Oak Ridge National Lab., TN (United States)

    1994-09-01

    Much activity has been concentrated on the development of intermetallic compounds with the aim of improving tensile ductility, fracture toughness and high notch sensitivity in order to develop an attractive combination of properties for high and low temperature applications. This paper reports experience in processing and forging of FeAl intermetallic of B2 type. During the experiments two different temperatures were employed, and the specimens were forged after annealing in air, 10{sup {minus}2} torr vacuum and argon. From the results it was learned that annealing FeAl in argon atmosphere prior to forging resulted in better deformation behavior than for the other two environments. For the higher forging temperature used in the experiments (700C), the as-cast microstructure becomes partially recrystallized.

  15. Communication Support for People with ALS

    Directory of Open Access Journals (Sweden)

    David Beukelman

    2011-01-01

    Full Text Available Almost all people with amyotrophic lateral sclerosis (ALS experience a motor speech disorder, such as dysarthria, as the disease progresses. At some point, 80 to 95% of people with ALS are unable to meet their daily communication needs using natural speech. Unfortunately, once intelligibility begins to decrease, speech performance often deteriorates so rapidly that there is little time to implement an appropriate augmentative and alternative communication (AAC intervention; therefore, appropriate timing of referral for AAC assessment and intervention continues to be a most important clinical decision-making issue. AAC acceptance and use have increased considerably during the past decade. Many people use AAC until within a few weeks of their deaths.

  16. Structure formation of AlMg2-AlN composite cast in electromagnetic field

    OpenAIRE

    M. Cholewa; M. Staszewski; M. Sozańska; B. Formanek

    2007-01-01

    Purpose: Basic material concept, technology and some results of studies on aluminum matrix composite with dispersive aluminum nitride reinforcement was shown. Studied composites were manufactured with use f ex-situ technique and powder metallurgy.Design/methodology/approach: Aluminum nitride powder was manufactured in process of self-evolving high-temperature synthesis SHS. Composite powder Al-AlN was obtained using mechanical alloying. Composite castings were manufactured in stir casting pro...

  17. HYDROGEN ADSORPTION ON β-TiAl (001) AND Ni/TiAl (001) SURFACES

    OpenAIRE

    A. A. KARIM MUBARAK; MAHMOUD ALELAIMI

    2014-01-01

    In this paper, we present first principles calculations of the energetic, electronic and magnetic properties of the variant termination of TiAl (001) and Ni/TiAl (001) surfaces with and without hydrogen atoms. The calculations have been performed within the density functional theory using full-potential linearized augmented plane wave method. The generalized gradient approximation (GGA) is utilized as the exchange-correlation energy. The octahedral site is the stable absorption site of H atom...

  18. Ni-Al and NiO-Al Composite Coatings by Combustion-Assisted Flame Spraying

    OpenAIRE

    Galina Xanthopoulou; Amalia Marinou; George Vekinis; Aggeliki Lekatou; Michalis Vardavoulias

    2014-01-01

    A new, cost-efficient and on-site-applicable thermal spraying process for depositing NiAl metallic overlay or bond-coat coatings for high temperature applications by synthesizing the desired intermetallic phases in-flight during oxy-acetylene flame spraying is presented. Base-metal powders were used for spraying and, by adjusting the spraying conditions, excellent NiAl-based coatings were achieved on various substrates, including mild steel, stainless steel and aluminium alloys. Expensive, pr...

  19. An Epidemiological Study of Cutaneous Leishmaniasis in Al-Jabal Al-Gharbi, Libya

    OpenAIRE

    Abdellatif, Manal Z. M.; El-Mabrouk, Khamis; Ewis, Ashraf A.

    2013-01-01

    Cutaneous leishmaniasis (CL) is an endemic parasitic infection in the Mediterranean region, including Libya and its Al-jabal Al-gharbi province. We aimed at studying the occupational relevance as well as other epidemiological aspects of CL. We investigated 140 CL cases who attended at Gharyan outpatient polyclinic during a period of 6 months in 2009. CL infection was clinically diagnosed and confirmed by demonstration of Leishmania parasites on smears from lesions. Our findings showed that ma...

  20. Magnetism of UPtAl and UIrAl; LDA+U calculations

    Energy Technology Data Exchange (ETDEWEB)

    Rusz, Jan [Department of Electronic Structures, Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, 121 16 Prague 2 (Czech Republic)]. E-mail: rusz@mag.mff.cuni.cz; Divis, Martin [Department of Electronic Structures, Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, 121 16 Prague 2 (Czech Republic)

    2005-04-15

    We report on electronic structure calculations of UPtAl and UIrAl ternary uranium based intermetallic compounds. Calculations were performed in the framework of density functional theory using LDA+U exchange correlation potential. Full relaxation of U and J parameters was performed with the aim of obtaining correct total magnetic moments on uranium site. These parameters are then used in subsequent analysis of magnetic moments (including spin and orbital components) and hybridization effects.

  1. Response to de la Iglesia et al.

    Science.gov (United States)

    Yetish, Gandhi; Kaplan, Hillard; Gurven, Michael; Wood, Brian; Pontzer, Herman; Manger, Paul R; Wilson, Charles; McGregor, Ronald; Siegel, Jerome M

    2016-04-01

    We wish to respond to the commentary of de la Iglesia et al. [1]. Studies comparing sleep in different communities have different goals. One frequent goal has been to determine how sleep is affected by manipulating specific 'modern' conditions. Many studies have investigated the effect of artificial light and electronic entertainment. Such studies have clearly shown that light, particularly blue light, delays sleep onset [2]. Studying the effect of artificial light on sleep was not a goal of our study.

  2. Globale Entwikclung als Lernbereich in den Naturwissenschaften

    OpenAIRE

    Härtig, Hendrik; Bernholt, Sascha; Schroeter, Burkhard

    2014-01-01

    Mit dem Orientierungsrahmen für den Lernbereich Globale Entwicklung wurden Anregungen gegeben, die Themen nachhaltige Entwicklung und globale Entwicklung im Unterricht in allen Schulfächern aufzugreifen. Die drei naturwissenschaftlichen Schulfächer Biologie, Chemie und Physik haben sich bislang sehr unterschiedlich auf das Thema eingelassen. In der Biologiedidaktik finden sich sowohl Forschungsarbeiten als auch Unterrichtsvorschläge; für Chemie und insbesondere Physik existieren hingegen nur ...

  3. Thaghut dalam Al-Qur’an

    Directory of Open Access Journals (Sweden)

    Laila Sari Masyhur

    2012-12-01

    Full Text Available Tulisan berikut membahas konsep thâghût dalam al-Qur’an dengan menggunakan pendekatan tafsir tematik. Term thâghût berasal dari akar kata thaghâ yang secara bahasa berarti melanggar batas, berbuat sewenang-wenang, kejam atau menindas, melebihi ketentuan yang ada, meninggi dan melampaui batas dalam hal pengingkaran. Penulis menelusuri ayat-ayat al-Quran yang berbicara topik thâghût, hasilnya menemukan bahwa dalam al-Qu’ran kata ini dengan berbagai derivasinya (isytiqaq diulang sebanyak 39 kali yang tersebar dalam 39 ayat dan 27 surat. Dilihat dari segi struktur atau bentuk pengungkapan, term thâghût yang tersebar di dalam al-Qur’an tersebut setidaknya muncul dalam lima bentuk kata jadian (isytiqaq yang masing-masing implikasi makna yang berbeda-beda. Tulisan berikut membahas sedikitnya sembilan macam pengungkapan thâghût dengan berbagai pemaknaan dengan tekanan yang beragam, seperti misalnya anjuran untuk tidak mempercayai thâghût; peringatan bahwa thâghût menuntun manusia pada kekufuran; mempersekutukan Allah dengan mengimani thâghût; pemberitaan tentang orang-orang yang berhukum pada thâghût; orang-orang yang berperang di jalan thâghût; balasan Allah terhadap penyembah thâghût; perintah menghindari penyembahan thâghût; kabar gembira bagi yang menghindari penyembahan thâghût; dan faktor-faktor yang membuat manusia bekerjasama dengan thâghût. Elaborasi dari topik-topik tersebut bermaksud untuk menegaskan larangan Islam terhadap thâghût dan hal-hal yang berkaitan dengannya.

  4. Psychosocial adjustment to ALS: a longitudinal study

    Directory of Open Access Journals (Sweden)

    Tamara eMatuz

    2015-09-01

    Full Text Available For the current study the Lazarian stress-coping theory and the appendant model of psychosocial adjustment to chronic illness and disabilities (Pakenham 1999 has shaped the foundation for identifying determinants of adjustment to ALS. We aimed to investigate the evolution of psychosocial adjustment to ALS and to determine its long-term predictors. A longitudinal study design with four measurement time points was therefore, used to assess patients’ quality of life, depression, and stress-coping model related aspects, such as illness characteristics, social support, cognitive appraisals and coping strategies during a period of two years. Regression analyses revealed that 55% of the variance of severity of depressive symptoms and 47% of the variance in quality of life at T2 was accounted for by all the T1 predictor variables taken together. On the level of individual contributions, protective buffering and appraisal of own coping potential accounted for a significant percentage in the variance in severity of depressive symptoms, whereas problem management coping strategies explained variance in quality of life scores. Illness characteristics at T2 did not explain any variance of both adjustment outcomes. Overall, the pattern of the longitudinal results indicated stable depressive symptoms and quality of life indices reflecting a successful adjustment to the disease across four measurement time points during a period of about two years.Empirical evidence is provided for the predictive value of social support, cognitive appraisals, and coping strategies, but not illness parameters such as severity and duration for adaptation to ALS. The current study contributes to a better conceptualization of adjustment, allowing us to provide evidence-based support beyond medical and physical intervention for people with ALS.

  5. Response to de la Iglesia et al.

    Science.gov (United States)

    Yetish, Gandhi; Kaplan, Hillard; Gurven, Michael; Wood, Brian; Pontzer, Herman; Manger, Paul R; Wilson, Charles; McGregor, Ronald; Siegel, Jerome M

    2016-04-01

    We wish to respond to the commentary of de la Iglesia et al. [1]. Studies comparing sleep in different communities have different goals. One frequent goal has been to determine how sleep is affected by manipulating specific 'modern' conditions. Many studies have investigated the effect of artificial light and electronic entertainment. Such studies have clearly shown that light, particularly blue light, delays sleep onset [2]. Studying the effect of artificial light on sleep was not a goal of our study. PMID:27046810

  6. Complementary and Alternative Therapies in ALS

    OpenAIRE

    Bedlack, Richard S.; Joyce, Nanette; Carter, Gregory T.; Pagononi, Sabrina; Karam, Chafic

    2015-01-01

    Given the severity of their illness and lack of effective disease modifying agents, it is not surprising that most patients with ALS consider trying complementary and alternative therapies. Some of the most commonly considered alternative therapies include special diets, nutritional supplements, cannabis, acupuncture, chelation and energy healing. This chapter reviews these in detail. We also describe 3 models by which physicians may frame discussions about alternative therapies: paternalism,...

  7. Die globale Finanzkrise als Kumulation von Dilemmastrukturen

    OpenAIRE

    Münch, Philipp Alexander

    2012-01-01

    Was als sogenannte „Subprime-Krise“ auf dem US-Immobilienmarkt begann, hat sich zu einer sehr ernsten Finanz-, Banken- und Staatsschuldenkrise mit hohen Vermögensverlusten, Konkursen, sozialem Elend und beträchtlichen Bürden für Steuerzahler weiterentwickelt. Sogar die Existenz der Europäischen Währungsunion steht auf dem Spiel. Zahlreiche Analysebeiträge behandeln eine Vielzahl von Verursachungsfaktoren. In vorliegender Arbeit werden ganze Pyramiden von Dilemmastrukturen unterschiedlicher hi...

  8. Entspannung als Wirkfaktor in der manuellen Stimmbehandlung

    OpenAIRE

    Lehnert, B.; Schlasze, H; Siebertz, S; Neuschaefer-Rube, C

    2010-01-01

    Hintergrund: Verschiedene Studien sprechen für eine Wirksamkeit der Manuellen Therapien (z. B. Osteopathie) nicht nur bei der sog. "Zervikogenen Dysphonie", sondern auch bei hyperfunktionellen Dysphonien. Unsere klinische Erfahrung zeigt, dass Patienten eine manuelle Behandlung der HWS als sehr entspannend empfinden. Uns sind keine Arbeiten bekannt, die den Anteil dieser allgemeinen Entspannung am Behandlungserfolg der Manuellen Therapien untersuchen. Wir stellen eine erste Studie zum Vergle...

  9. Fabrication and Characterization of Al/p-CuInAlSe2 Thin Film Schottky Diodes

    Directory of Open Access Journals (Sweden)

    Usha Parihar

    2013-05-01

    Full Text Available Al/p-CuInAlSe2 polycrystalline schottky diodes fabricated by flash evaporation method were undertaken for their electrical analysis at room temperature. Diode parameters of the undertaken diodes were then derived from the current-voltage (I-V as well as capacitance-voltage (C-V characteristics. It has been observed that the schottky barrier height deduced from the room temperature I-V is lower to that obtained from the C-V characteristics and is attributed to the fact that I-V analysis includes both the image force and dipole lowering effects and is also reduced by the tunneling and leakage currents. The slope variation of the frequency dependent C – 2-V characteristics for the Al/p-CuInAlSe2 Schottky diode at varying frequency values from 50 kHz to 1 MHz suggests a large density of slow traps or interface states at the M-S junction. As emerging from the parameters values energy band diagram of Al and P-CuInAlSe2 has been reconstructed.

  10. Nanoindentation studies of ex situ AlN/Al metal matrix nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Fale, Sandeep; Likhite, Ajay; Bhatt, Jatin, E-mail: jatinbhatt@mme.vnit.ac.in

    2014-12-05

    Highlights: • Formation of in-situ phases nucleated on AlN particles strengthens the matrix. • Formation of in-situ phases increases with AlN content in nanocomposites. • Stronger in-situ phases results in increased hardness and modulus of elasticity. - Abstract: Nanocrystalline Aluminium nitride (AlN) powder is dispersed in different weight ratio in Aluminum matrix to fabricate metal matrix nanocomposite (MMNC) using ex situ melt metallurgy process. The synthesized Al–AlN nanocomposites are studied for phase analysis using high resolution scanning electron microscopy (FEG-SEM) and for hardness behavior using microindentation and nanoindentation tests. Quantitative analysis of the oxide phases is calculated from thermodynamic data and mass balance equation using elemental data obtained from energy dispersive spectroscopy (EDS) results. Role of oxide phases in association with AlN particles is investigated to understand the mechanical behavior of composites using nanoindentation tester. Load–displacement profile obtained from nanoindentation test reveals distribution of oxide phases along with AlN particle and their effect on indent penetration.

  11. Softening Kinetics in High Al and High Al-Nb-Microalloyed Steels

    Science.gov (United States)

    Pereda, B.; Aretxabaleta, Z.; López, B.

    2015-03-01

    Double-hit torsion tests were performed in order to study the effect of high Al levels (up to 2 wt.%) and Nb microalloying (up to 0.07 wt.%) on the static softening kinetics of 0.2%C-2%Mn steels. The addition of 1%Al leads to a delay in the softening kinetics due to solute-drag effect, equivalent to that exerted by 0.027%Nb. For the 2%Al steels, at temperatures below 1000 °C, γ → α phase transformation occurs after deformation, resulting in a larger retardation of the softening kinetics. At temperatures higher than 1000 °C, Nb in solid solution also contributes to the retardation of the static softening kinetics, and at lower temperatures NbC strain-induced precipitation leads to incomplete softening for the 1%Al steel, and to a complex interaction between softening, phase transformation, and NbC strain-induced precipitation for the 2%Al-Nb steels. The effect of Al on the static softening kinetics was quantified and introduced in a model developed in previous works for the prediction of the austenite microstructural evolution. In order to validate the results of the model, multipass torsion tests were carried out at conditions representative of hot strip and plate rolling mills. Model predictions show reasonable agreement with the results obtained at different deformation conditions.

  12. Preparation of Al- AlN Bonded Corundum Based Refractories by in-situ Reaction

    Institute of Scientific and Technical Information of China (English)

    ZHU Boquan; FANG Binxiang; ZHANG Wenjie

    2008-01-01

    The Al-AlN bonded corundum based refractories was synthesized with the starting materials of fused alu-mina and metallic aluminium in nitrogen atmosphere through in-situ reaction. The study indicated that with the addition of 14% metallic aluminium (13% of Al powder and 1% of Al fiber) , the material nitridized at 1 100 ℃ for 3 h has excellent physical properties. It is found that a massive quantity of AlN in the forms of both whiskers" and hexagon pellet particles is formed, and a large quantity of Al remained in the matrix. This multiple bonding system resulted in the excellent me-chanical properties of the material. It is also found that the hydration tendency of the prepared material is inhib-ited, and the material exhibited excellent thermal shock resistance. The nature of protective oxidation of the bonding system is characterized. Thus, this material may become a new candidate of carbon-free sliding plate material for continuous casting.

  13. FeAl and NbAl3 Intermetallic-HVOF Coatings: Structure and Properties

    Science.gov (United States)

    Guilemany, J. M.; Cinca, N.; Dosta, S.; Cano, I. G.

    2009-12-01

    Transition metal aluminides in their coating form are currently being explored in terms of resistance to oxidation and mechanical behavior. This interest in transition metal aluminides is mainly due to the fact that their high Al content makes them attractive for high-temperature applications. This is also a reason to study their resistance to wear; they may be suitable for use in applications that produce a lot of wear in aggressive environments, thus replacing established coating materials. In this study, the microstructure, microhardness, and wear and oxidation performance of FeAl and NbAl3 coatings produced by high-velocity oxy-fuel spraying are evaluated with two main aims: (i) to compare these two coating systems—a commonly studied aluminide (FeAl) and, NbAl3, an aluminide whose deposition by thermal spraying has not been attempted to date—and (ii) to analyze the relationship between their microstructure, composition and properties, and so clarify their wear and oxidation mechanisms. In the present study, the higher hardness of niobium aluminide coatings did not correlate with a higher wear resistance and, finally, although pesting phenomena (disintegration in oxidizing environments) were already known of in bulk niobium aluminides, here their behavior in the coating form is examined. It was shown that such accelerated oxidation was inevitable with respect to the better resistance of FeAl, but further improvements are foreseen by addition of alloying elements in that alloy.

  14. Model for metabolic resistance against ALS inhibitors

    Directory of Open Access Journals (Sweden)

    Richter, Otto

    2014-02-01

    Full Text Available Due to herbicide selection pressure metabolic resistance has evolved in many weed species. In this paper we analyse the interaction between the branched chain amino acid (BBC pathway and detoxifying pathways for herbicide breakdown. The four phase detoxification pathway of herbicides comprising the action of P450, GST, glycosyltransferase and ABC transporter is modelled by a system of coupled enzyme kinetic reactions represented by nonlinear differential equations. The herbicide under consideration inhibits the enzyme ALS, which is the key enzyme for the biosynthesis of branched amino acids. For the kinetics of ALS a Monod approach is employed with a binding site for the inhibitor. Synthetic and detoxification pathways are coupled. The model is used to study the production of branched amino acids under the action of ALS inhibitors for different structures and modes of action of the detoxification pathway. The model is capable of generating typical dose response curves and their shift in dependence of the activity pattern of the enzymes of the detoxification pathway of the inhibitor.

  15. Keanekaragaman dalam al-Qur’an

    Directory of Open Access Journals (Sweden)

    Muhammad Chirzin

    2011-04-01

    Full Text Available The diversity of race, language, class, and culture is a wealth; basically, it is a beautiful gift in this life. However, the reality is precesely the social conflict among the society. This article explores the issue of diversity contained in al Qur’an. Some of the key themes included: diversity as sunnatullah, diversity in unity, religious and ethnic diversity, and diversity of professions. Al Qur’an has mentioned several groups of religious believers and provided guidance association order among religious believers. Religious diversity certainly makes Muslim necessitates acknowledging and respecting other religion save Islam. Al Qur’an has mentioned also a variety of occupations based on interests, talents, expertise, and particular skills. The fragmentation and understanding diversity have caused by egoism and truth claiming of each group and individual, but no one has knowledge covering everything from different sides or corners. Above all knowledge is the Almighty owner off all knowledge. With feeling most true someone or group tends to feel the best and have the right to insult any others. That is the base of the dispute and spiritual decline. Mukmin has to preserve the noble character in association, and keep away from bad manner. Among mukmin must love each other and maintain good manners. Finally, this study is intended to promote the establishment of harmony, peace and happiness of living together.

  16. De la vigilancia convencional al monitoreo participativo

    Directory of Open Access Journals (Sweden)

    Jaime Breilh

    2003-01-01

    Full Text Available La necesidad de transformar el monitoreo de la salud de un instrumento funcional al sistema dominante de poder en una herramienta del poder colectivo, y de negociación del desarrollo de la salud laboral y el bienestar, implica la urgente transformación de la vieja vigilancia epidemiológica en un monitoreo participativo. Debe superarse el sistema convencional de información en salud, que observa fundamentalmente los "factores de enfermedad" y sus efectos mórbidos aislados, invisibilizando los procesos de determinación integrales. Este trabajo analiza el proceso de derrota de los derechos sociales y laborales, lo cual sitúa el desafío planteado en un escenario de profundo retroceso social y asalto a los derechos conquistados por los/as trabajadores/as en años de lucha. Con el propósito de esclarecer dicho argumento, al autor comienza contrastando los modelos de vigilancia clásicos, algunas propuestas transicionales, hasta arribar al monitoreo participativo. La aplicación de la categoría "perfil epidemiológico" permite sistematizar los dominios y dimensiones del monitoreo y establecer los sujetos sociales de esa mirada crítica e intercultural del pueblo sobre su salud, mediante la construcción de una matriz de procesos críticos.

  17. L'Hemisferic: Una ventana al mundo

    Directory of Open Access Journals (Sweden)

    Calatrava Valls, Santiago

    2000-12-01

    Full Text Available The "Hemisféric-Planetario" building is located in the center line East-West of the "Ciudad de las Artes y las Ciencias" complex, flanked by two rectangular lakes, in the north and in the south, respectively. In the East side we can find a promenade between the Museum and its south lake. Nevertheless its West side is virtual. and located in the area of the "Hermanos Marista 's" viaducto The building is visited, daily, by about 3.000 people, distributed between its 8 duties. The showing room holds 321 seats, four of those for wheel-chairs. The building has a possible room of 999 people (at the same time.El edificio Hemisféric-Planetarío está situado sobre el eje Este-Oeste del complejo de la Ciudad de las Artes y las Ciencias; está flanqueado por dos estanques rectangulares, al Norte y al Sur, respectivamente. Por el Este, un paseo limita la parcela con el Museo y su estanque Sur. El limite Oeste, sin embargo. es virtual y se encuentra en la proyección del viaducto de Hermanos Maristas. Este edificio es visitado diariamente por unos 3.000 personas, distribuyéndose en 8 funciones. La sala de proyección dispone de 321 butacas, con posibilidad de alojar 4 sillas de ruedas. La capacidad de acogida del edificio (al mismo tiempo es de 999 personas.

  18. Diet and dietetics in al-Andalus.

    Science.gov (United States)

    Salas-Salvadó, Jordi; Huetos-Solano, Maria D; García-Lorda, Pilar; Bulló, Mònica

    2006-08-01

    Al-Andalus society (711-1492) based its idea of health on the wisdom of Classical Greece, the Hippocratic-Galenic theories, as well as the Persian and Hindu cultures. The twelfth century in al-Andalus is considered to be the most prolific period for works of a scientific and technical nature. At the time, the main treatises on dietetics were written and this science reached its widest expression with such leading figures as Ibn Wāfīd, Avenzoar, Averroes and Maimonides, whose works revealed the first scientific knowledge on the nutritional processes of the human body. Diet was regarded as being essential for health and the prevention of disease. Dietary guidelines were written for different age groups, different body types and different seasons of the year. The amount of food to be ingested, the number of meals recommended and the order in which the food should be consumed were all issues that were discussed. A variety of foods were thought to have medicinal properties, some of which are known today. The diet in al-Andalus was varied and very probably made a substantial contribution to the origin of the present-day Mediterranean diet, rich in olive oil, wholemeal cereals, fruit and vegetables, fish, lamb, poultry, nuts and spices. We also find that many of the terms in current use in diet and agriculture are a living testimony to the Arabic influence, as are many of the dishes of our varied Mediterranean gastronomy.

  19. Studies on Al Kidirate and Kapoeta meteorites

    Energy Technology Data Exchange (ETDEWEB)

    Gismelseed, A.M. [Sudan Atomic Energy Commission, Khartoum (Sudan); Khangi, F. [Sudan Atomic Energy Commission, Khartoum (Sudan); Ibrahim, A. [Sudan Atomic Energy Commission, Khartoum (Sudan); Yousif, A.A. [Coll. of Science, Sultan Qaboos Univ., Alkhoud (Oman); Worthing, M.A. [Coll. of Science, Sultan Qaboos Univ., Alkhoud (Oman); Rais, A. [Coll. of Science, Sultan Qaboos Univ., Alkhoud (Oman); Elzain, M.E. [Coll. of Science, Sultan Qaboos Univ., Alkhoud (Oman); Brooks, C.K. [Coll. of Science, Sultan Qaboos Univ., Alkhoud (Oman); Sutherland, H.H. [Coll. of Science, Sultan Qaboos Univ., Alkhoud (Oman)

    1994-11-01

    Moessbauer spectroscopy (20-300 K), magnetic susceptibility measurements (77-350 K), scanning electron microscopy and X-ray diffraction experiments have been performed on two meteorite samples: one from an old fall (Kapoeta) and another from a very recent fall (Al Kidirate). The two specimens differ in their mineralogy. Chondrules appear to be absent in Kapoeta and it is probably a pyroxene-plagioclase achondrite with ferrohypersthene as the most abundant mineral. On the other hand, the Al Kidirate meteorite is an ordinary chondrite and the specimen consists of olivine, orthopyroxene, troilite and kamacite. The Moessbauer measurements confirm the above characterization, showing a paramagnetic doublet for the Kapoeta sample and at least two paramagnetic doublets and magnetic sextets for the Al Kidirate specimens. The former were assigned to Fe in pyroxene sites, while the latter was assigned to Fe in pyroxene, olivine, Fe-S and Fe-Ni alloys. The difference in the mineralogy of the two meteorites has also been reflected in the temperature-dependent magnetic susceptibility. The magnetization and the hyperfine interaction parameters will be discussed in relation to the mineralogy. (orig.)

  20. Thermodynamic properties and mixing thermodynamic parameters of Ba-Al, Mg-Al, Sr-Al and Cu-Al metallic melts

    Institute of Scientific and Technical Information of China (English)

    张鉴

    2004-01-01

    Application of equations of mixing thermodynamic parameters formulated on the basis of the coexistence theory of metallic melts in Ba-Al, Mg-Al, Sr-A1 and Cu-Al melts leads to fruitful results that not only the evaluated mass action concentrations agree well with the measured activities, but also the calculated mixing thermodynamic parameters are quite coincident with the experimental values. Moreover, the calculated mass action concentrations strictly obey the mass action law. The evaluated mixing thermodynamic parameters have very fine regularity: the mixing free energy is composed of standard free formation energies of all compounds and chemical potentials of all structural units at equilibrium; the mixing enthalpy consists of standard formation enthalpies of all compounds; the mixing entropy is composed of standard entropies of all compounds and configuration entropies of all structural units at equilibrium. As the equations of mixing thermodynamic parameters formulated are widely applicable to metallic melts involving compound formation, they can be used as the second practical criterion to determine whether thermodynamic models of metallic melts are correctly formulated.