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Sample records for caii triplet spectroscopy

  1. Low Ionization Emission Lines in Quasars: Clues from OI 8446 and the CaII Triplet

    OpenAIRE

    Marziani, Paola; Martinez-Aldama, Mary Loli; Dultzin, Deborah; Sulentic, Jack

    2013-01-01

    The formation of low emission lines in quasars and active galactic nuclei is still an open issue. Aided by the organizing power of the 4D eigenvector 1 scheme, we review basic developments since the 1980s, devoting special attention to the CaII IR triplet and the OI 8446 emission lines. Coverage of these lines is cumbersome since they are shifted in an inconvenient IR domain already at modest redshifts (~ 0.2). Their detection is also difficult since they are faint and often buried in the Ca ...

  2. Low Ionization Emission Lines in Quasars: Clues from OI 8446 and the CaII Triplet

    CERN Document Server

    Marziani, Paola; Dultzin, Deborah; Sulentic, Jack

    2013-01-01

    The formation of low emission lines in quasars and active galactic nuclei is still an open issue. Aided by the organizing power of the 4D eigenvector 1 scheme, we review basic developments since the 1980s, devoting special attention to the CaII IR triplet and the OI 8446 emission lines. Coverage of these lines is cumbersome since they are shifted in an inconvenient IR domain already at modest redshifts (~ 0.2). Their detection is also difficult since they are faint and often buried in the Ca II absorption of the host galaxy. We discuss how these lines can provide unambiguous constraints on the physical conditions of the broad line emitting regions of quasars when detected in emission, and summarise preliminary results for a sample of luminous, intermediate redshift quasars.

  3. Automatic stellar spectra parameterisation in the IR CaII triplet region

    CERN Document Server

    Kordopatis, G; de Laverny, P; Bijaoui, A; Hill, V; Gilmore, G; Wyse, R F G; Ordenovic, C

    2011-01-01

    (Abridged) Galactic archaeology aims to determine the evolution of the Galaxy from the chemical and kinematical properties of its stars. The analysis of current large spectroscopic surveys (thousands of stars) and future ones (millions of stars) require automated analysis techniques to obtain robust estimates of the stellar parameters. Several on-going and planned spectroscopic surveys have selected their wavelength region to contain the IR CaII triplet and this paper focuses on the automatic analysis of such spectra. We investigated two algorithms, MATISSE and DEGAS, both of which compare the observed spectrum to a grid of synthetic spectra, but each uses a different mathematical approach for finding the optimum match and hence the best stellar parameters. We identified degeneracies in different regions of the HR diagram: hot dwarfs and giants share the same spectral signatures. Furthermore, the surface gravity of cooler dwarfs is difficult to determine accurately. These effects are intensified when the info...

  4. Study of the Sextans dwarf spheroidal galaxy from the DART CaII triplet survey

    CERN Document Server

    Battaglia, G; Helmi, A; Irwin, M; Parisi, P; Hill, V; Jablonka, P

    2010-01-01

    We use VLT/FLAMES intermediate resolution (R~6500) spectra of individual red giant branch stars in the near-infrared CaII triplet (CaT) region to investigate the wide-area metallicity properties and internal kinematics of the Sextans dwarf spheroidal galaxy (dSph). Our final sample consists of 174 probable members of Sextans with accurate line-of-sight velocities (+- 2 km/s) and CaT [Fe/H] measurements (+- 0.2 dex). We use the MgI line at 8806.8 \\AA\\, as an empirical discriminator for distinguishing between probable members of the dSph (giant stars) and probable Galactic contaminants (dwarf stars). Sextans shows a similar chemo-dynamical behaviour to other Milky Way dSphs, with its central regions being more metal rich than the outer parts and with the more metal-rich stars displaying colder kinematics than the more metal-poor stars. Hints of a velocity gradient are found along the projected major axis and along an axis at P.A.=191 deg, however a larger and more spatially extended sample may be necessary to p...

  5. A new synthetic library of the Near-Infrared CaII triplet indices. I.Index Definition, Calibration and Relations with stellar atmospheric parameters

    CERN Document Server

    Du, Wei; Zhao, Yong-Heng

    2011-01-01

    Adopting the SPECTRUM package, we have synthesized a set of 2,890 Near-InfraRed (NIR) synthetic spectra with a resolution and wavelength sampling similar to the SDSS and the forthcoming LAMOST spectra. During the synthesis, we have applied the `New grids of ATLAS9 Model Atmosphere' to provide a grid of local thermodynamic equilibrium (LTE) model atmospheres. This synthetic stellar library is composed of 1,350 solor scaled abundance (SSA) and 1,530 non-solar scaled abundance (NSSA) spectra, grounding on which we have defined a new set of NIR CaII triplet indices and an index CaT as the sum of the three. Then, these defined indices have been automatically measured on the synthetic spectra and calibrated with the indices computed on the observational spectra from the INDO-U.S. stellar library. In order to check the effect of alpha-element enhancement on the so-defined CaII indices, we have compared indices measured on the SSA spectra with those on the NSSA ones at the same terns of stellar parameters (Teff, log ...

  6. Triplet State Resonance Raman Spectroscopy

    DEFF Research Database (Denmark)

    Wilbrandt, Robert Walter; Jensen, N. H.; Pagsberg, Palle Bjørn;

    1978-01-01

    Makes the first report on the resonance Raman spectrum of a molecule in its triplet state generated by pulse radiolysis. A solution of 0.01 mol dm-3 of p-terphenyl in benzene was studied......Makes the first report on the resonance Raman spectrum of a molecule in its triplet state generated by pulse radiolysis. A solution of 0.01 mol dm-3 of p-terphenyl in benzene was studied...

  7. Temporal Evolution of the Scattering Polarization of the CaII IR Triplet in Hydrodynamical Models of the Solar Chromosphere

    CERN Document Server

    Carlin, E S; Bueno, J Trujillo

    2012-01-01

    Velocity gradients in a stellar atmospheric plasma have an impact on the anisotropy of the radiation field that illuminates each point within the medium, and this may in principle influence the scattering line polarization that results from the induced atomic level polarization. Here we analyze the emergent linear polarization profiles of the Ca II infrared triplet after solving the radiative transfer problem of scattering polarization in time-dependent hydrodynamical models of the solar chromosphere, taking into account the impact of the plasma macroscopic velocity on the atomic level polarization. We discuss the influence that the velocity and temperature shocks in the considered chromospheric models have on the temporal evolution of the scattering polarization signals of the Ca II infrared lines, as well as on the temporally averaged profiles. Our results indicate that the increase of the linear polarization amplitudes caused by macroscopic velocity gradients may be significant in realistic situations. We ...

  8. Precision spectroscopy with ultracold 87Rb2 triplet molecules

    International Nuclear Information System (INIS)

    In this thesis I report precision spectroscopy with ultracold 87Rb2 triplet molecules where we use lasers to couple the states in different molecular potentials. We study in detail states of the a 3 sum +u and (1) 3 sum +g potentials. These states are of great importance for transferring weakly bound molecules to the ro-vibrational triplet ground state via states of the excited potential. As most experiments start from molecules in their X 1 sum +g ground state, the triplet states were hard to access via dipole transitions and remained largely unexplored. The measurements presented in this thesis are the first detailed study of diatomic 87Rb2 molecules in these states. Our experiments start with an ultracold cloud of 87Rb atoms. We then load this cloud into an optical lattice where we use a magnetic Feshbach resonance at 1007.4 G to perform a Feshbach association. After we have removed all unbound atoms, we end up with a pure sample of weakly bound Feshbach molecules inside the optical lattice. The optical lattice prevents these molecules from colliding with each other which results in molecular lifetimes on the order of a few hundred milliseconds. In the first set of experiments, we use a laser coupling the Feshbach state to the excited (1) 3 sum +g triplet state to map out its low-lying vibrational (v = 0.. 15), rotational, hyperfine, and Zeeman structure. The experimental results are in good agreement with calculations done by Marius Lysebo and Prof. Leif Veseth. We then map out in detail the vibrational, rotational, hyperfine, and Zeeman structure of the a 3 sum +u triplet ground state using dark state spectroscopy with levels in the (1) 3 sum +g potential as an intermediate state. In this scheme we are able to access molecules in triplet states because our Feshbach state has strong triplet character. Interestingly, it happens that some deeply bound states which belong to the X 1 sum +g potential are close to levels in the a 3 sum +u potential. In these cases

  9. OI and CaII observations in intermediate redshift quasars

    CERN Document Server

    Martínez-Aldama, Mary Loli; Marziani, Paola; Sulentic, Jack W; Bressan, Alessandro; Chen, Yang; Stirpe, Giovanna M

    2015-01-01

    We present an unprecedented spectroscopic survey of the CaII triplet + OI for a sample of 14 luminous ($-$26 $\\gtrsim$ M$_V$ $\\gtrsim$ $-$29), intermediate redshift (0.85 $\\lesssim$ $z$ $\\lesssim$ 1.65) quasars. The ISAAC spectrometer at ESO VLT allowed us to cover the CaII NIR spectral region redshifted into the H and K windows. We describe in detail our data analysis which enabled us to detect CaII triplet emission in all 14 sources (with the possible exception of HE0048-2804) and to retrieve accurate line widths and fluxes of the triplet and OI $\\lambda$8446. The new measurements show trends consistent with previous lower $z$ observations, indicating that CaII and optical FeII emission are probably closely related. The ratio between the CaII triplet and the optical FeII blend at $\\lambda$4570 $\\AA$ is apparently systematically larger in our intermediate redshift sample relative to a low-$z$ control sample. Even if this result needs a larger sample for adequate interpretation, higher CaII/optical FeII shoul...

  10. Stepwise excitation and level-crossing spectroscopy of the triplet D states of helium-4

    International Nuclear Information System (INIS)

    The fine-structure intervals of the lowest two triplet D states of 4He have been obtained by a new method: Ground-state atoms are excited by a discharge to the triplet metastable state, which then undergoes a two-step optical excitation to the triplet D states, where level-crossing measurements are made. The experimental results for 3D1-3D3 (MHz) are 1400.67 plus-or-minus 0.29 and 591.25 plus-or-minus 0.14 for the 3 3D and 4 3D states, respectively; for 3D2-3D3 (MHz) they are 75.97 plus-or-minus 0.23 and 36.15 plus-or-minus 0.24 for 3 3D and 4 3D. These values are much more precise than the previously available data, obtained by optical, particle-bombardment level crossing, or beam-foil quantum-beat spectroscopy, and are consistent with the previous data except for one case, where a previous measurement of 3 3D2-3 3D3 by electron bombardment level-crossing spectroscopy is believed to be in error. These new experimental values for the fine structures of the triplet D state of 4He clearly indicate the inadequateness of existing theoretical calculations of these fine structures

  11. Precision spectroscopy with ultracold {sup 87}Rb{sub 2} triplet molecules

    Energy Technology Data Exchange (ETDEWEB)

    Strauss, Christoph

    2011-10-19

    In this thesis I report precision spectroscopy with ultracold {sup 87}Rb{sub 2} triplet molecules where we use lasers to couple the states in different molecular potentials. We study in detail states of the a {sup 3} sum {sup +}{sub u} and (1) {sup 3} sum {sup +}{sub g} potentials. These states are of great importance for transferring weakly bound molecules to the ro-vibrational triplet ground state via states of the excited potential. As most experiments start from molecules in their X {sup 1} sum {sup +}{sub g} ground state, the triplet states were hard to access via dipole transitions and remained largely unexplored. The measurements presented in this thesis are the first detailed study of diatomic {sup 87}Rb{sub 2} molecules in these states. Our experiments start with an ultracold cloud of {sup 87}Rb atoms. We then load this cloud into an optical lattice where we use a magnetic Feshbach resonance at 1007.4 G to perform a Feshbach association. After we have removed all unbound atoms, we end up with a pure sample of weakly bound Feshbach molecules inside the optical lattice. The optical lattice prevents these molecules from colliding with each other which results in molecular lifetimes on the order of a few hundred milliseconds. In the first set of experiments, we use a laser coupling the Feshbach state to the excited (1) {sup 3} sum {sup +}{sub g} triplet state to map out its low-lying vibrational (v = 0.. 15), rotational, hyperfine, and Zeeman structure. The experimental results are in good agreement with calculations done by Marius Lysebo and Prof. Leif Veseth. We then map out in detail the vibrational, rotational, hyperfine, and Zeeman structure of the a {sup 3} sum {sup +}{sub u} triplet ground state using dark state spectroscopy with levels in the (1) {sup 3} sum {sup +}{sub g} potential as an intermediate state. In this scheme we are able to access molecules in triplet states because our Feshbach state has strong triplet character. Interestingly, it

  12. Low ionization lines in high luminosity quasars: The calcium triplet

    OpenAIRE

    Martínez-Aldama, Mary Loli; Dultzin, Deborah; Marziani, Paola; Sulentic, Jack W.; Chen, Yang; Bressan, Alessandro; Stirpe, Giovanna M.

    2013-01-01

    In order to investigate where and how low ionization lines are emitted in quasars we are studying a new collection of spectra of the CaII triplet at $\\lambda$8498, $\\lambda$8542, $\\lambda$8662 observed with the Very Large Telescope (VLT) using the Infrared Spectrometer And Array Camera (ISAAC). Our sample involves luminous quasars at intermediate redshift for which CaII observations are almost nonexistent. We fit the CaII triplet and the OI $\\lambda$8446 line using the H$\\beta$ profile as a m...

  13. Low ionization lines in high luminosity quasars: The calcium triplet

    CERN Document Server

    Martínez-Aldama, Mary Loli; Marziani, Paola; Sulentic, Jack W; Chen, Yang; Bressan, Alessandro; Stirpe, Giovanna M

    2013-01-01

    In order to investigate where and how low ionization lines are emitted in quasars we are studying a new collection of spectra of the CaII triplet at $\\lambda$8498, $\\lambda$8542, $\\lambda$8662 observed with the Very Large Telescope (VLT) using the Infrared Spectrometer And Array Camera (ISAAC). Our sample involves luminous quasars at intermediate redshift for which CaII observations are almost nonexistent. We fit the CaII triplet and the OI $\\lambda$8446 line using the H$\\beta$ profile as a model. We derive constraints on the line emitting region from the relative strength of the CaII triplet, OI $\\lambda$8446 and H$\\beta$.

  14. Ca II triplet spectroscopy of RGB stars in NGC 6822: kinematics and metallicities

    CERN Document Server

    Swan, Jesse; Tolstoy, Eline; Irwin, Mike J

    2016-01-01

    We present a detailed analysis of the chemistry and kinematics of red giants in the dwarf irregular galaxy NGC 6822. Spectroscopy at 8500 Angstroms was acquired for 72 red giant stars across two fields using FORS2 at the VLT. Line of sight extinction was individually estimated for each target star to accommodate the variable reddening across NGC 6822. The mean radial velocity was found to be v_helio = (52.8 +/- 2.2) km/s with dispersion rms = 24.1 km/s, in agreement with other studies. Ca II triplet equivalent widths were converted into [Fe/H] metallicities using a V magnitude proxy for surface gravity. The average metallicity was [Fe/H] = (-0.84 +/- 0.04) with dispersion rms = 0.31 dex and interquartile range 0.48. Our assignment of individual reddening values makes our analysis more sensitive to spatial variations in metallicity than previous studies. We divide our sample into metal-rich and metal-poor stars; the former are found to cluster towards small radii with the metal-poor stars more evenly distribut...

  15. Ca II triplet spectroscopy of RGB stars in NGC 6822: kinematics and metallicities

    Science.gov (United States)

    Swan, J.; Cole, A. A.; Tolstoy, E.; Irwin, M. J.

    2016-03-01

    We present a detailed analysis of the chemistry and kinematics of red giants in the dwarf irregular galaxy NGC 6822. Spectroscopy at ≈8500 Å was acquired for 72 red giant stars across two fields using FORS2 at the VLT. Line-of-sight extinction was individually estimated for each target star to accommodate the variable reddening across NGC 6822. The mean radial velocity was found to be = -52.8 ± 2.2 km s-1 with dispersion σv = 24.1 km s-1, in agreement with other studies. Ca II triplet equivalent widths were converted into [Fe/H] metallicities using a V magnitude proxy for surface gravity. The average metallicity was = -0.84 ± 0.04 with dispersion σ = 0.31 dex and interquartile range 0.48. Our assignment of individual reddening values makes our analysis more sensitive to spatial variations in metallicity than previous studies. We divide our sample into metal-rich and metal-poor stars; the former were found to cluster towards small radii with the metal-poor stars more evenly distributed across the galaxy. The velocity dispersion of the metal-poor stars was found to be higher than that of the metal-rich stars (σ _{v_MP}=27.4 km s-1; σ _{v_MR}=21.1 km s-1); combined with the age-metallicity relation this indicates that the older populations have either been dynamically heated during their lifetimes or were born in a less disc-like distribution than the younger stars.. The low ratio vrot/σv suggests that within the inner 10 arcmin, NGC 6822's stars are dynamically decoupled from the H I gas, and possibly distributed in a thick disc or spheroid structure.

  16. Detecting luminescence from triplet states of organic semiconductors at room temperatures using delayed electroluminescence spectroscopy

    Science.gov (United States)

    Wang, Qi; Aziz, Hany

    2014-08-01

    We demonstrate a unique approach for detecting luminescence from triplet states of organic materials in the solid state at room temperatures. The technique is based on measuring delayed electroluminescence from the material. The approach overcomes limitations of conventional spectroscopic techniques, such as the need for cooling to cryogenic temperatures, and works for a wide range of organic materials. The underlying mechanisms behind observing materials phosphorescence using this technique are studied. The results show that using a low concentration of the target material doped in a host material and a large energy differences between triplet states of target and host materials are necessary for obtaining efficient phosphorescence at room temperatures.

  17. Triplet excitation dynamics of two keto-carotenoids in n-hexane and in methanol as studied by ns flash photolysis spectroscopy

    Science.gov (United States)

    Li, Li; Hu, Feng; Chang, Yu-Qiang; Zhou, Yan; Wang, Peng; Zhang, Jian-Ping

    2015-07-01

    Siphonaxanthin and siphonein are two keto-carotenoids. Upon anthracene-sensitizing, triplet excitation dynamics of these two carotenoids were studied in n-hexane and in methanol, respectively, by ns flash photolysis spectroscopy. In n-hexane, bleaching of the ground state absorption (GSB) and the excitation triplet (3Car*) absorption were observed. In methanol, upon the decay of the 3Car*, the cation dehydrodimer of carotenoid, #[Car]2+, generated by the same rate, while an additional GSB generated synchronously, a polar solvent assisted and anthracene-sensitized mechanism was addressed based on the discussion. The environment-sensitive triplet excitation dynamics imply their potential role in photo-protection in vivo.

  18. Observation of the lowest triplet state in silane by electron energy loss spectroscopy

    International Nuclear Information System (INIS)

    The electron energy loss spetra of silane was recorded at several impact energies and angles. It is concluded that the lowest triplet state of silane is formed from configuration mixing of the 4s Rydberg state with a valence state of the same symmetry

  19. CaII Κ Imaging to Understand UV Irradiance Variability

    Indian Academy of Sciences (India)

    R. Kariyappa

    2000-09-01

    To identify and understand the underlying physical mechanisms of total solar and UV irradiance variability and to estimate the contribution of various chromospheric features to UV irradiance, detailed analysis of spatially resolved data is required. The various chromospheric features have been segregated and different parameters have been derived from CaII Κ Spectroheliograms of NSO/Sac Peak and Kodaikanal Observatory and compared with UV irradiance flux measured in MgII h and k lines by NOAA 9 satellite. The important results of this detailed analysis of CaII Κ Images of 1992 together with UV irradiance data will be discussed in this paper.

  20. Triplet excited electronic state switching induced by hydrogen bonding: A transient absorption spectroscopy and time-dependent DFT study.

    Science.gov (United States)

    Ravi Kumar, Venkatraman; Ariese, Freek; Umapathy, Siva

    2016-03-21

    The solvent plays a decisive role in the photochemistry and photophysics of aromatic ketones. Xanthone (XT) is one such aromatic ketone and its triplet-triplet (T-T) absorption spectra show intriguing solvatochromic behavior. Also, the reactivity of XT towards H-atom abstraction shows an unprecedented decrease in protic solvents relative to aprotic solvents. Therefore, a comprehensive solvatochromic analysis of the triplet-triplet absorption spectra of XT was carried out in conjunction with time dependent density functional theory using the ad hoc explicit solvent model approach. A detailed solvatochromic analysis of the T-T absorption bands of XT suggests that the hydrogen bonding interactions are different in the corresponding triplet excited states. Furthermore, the contributions of non-specific and hydrogen bonding interactions towards differential solvation of the triplet states in protic solvents were found to be of equal magnitude. The frontier molecular orbital and electron density difference analysis of the T1 and T2 states of XT indicates that the charge redistribution in these states leads to intermolecular hydrogen bond strengthening and weakening, respectively, relative to the S0 state. This is further supported by the vertical excitation energy calculations of the XT-methanol supra-molecular complex. The intermolecular hydrogen bonding potential energy curves obtained for this complex in the S0, T1, and T2 states support the model. In summary, we propose that the different hydrogen bonding mechanisms exhibited by the two lowest triplet excited states of XT result in a decreasing role of the nπ(∗) triplet state, and are thus responsible for its reduced reactivity towards H-atom abstraction in protic solvents. PMID:27004870

  1. Triplet excited electronic state switching induced by hydrogen bonding: A transient absorption spectroscopy and time-dependent DFT study

    Science.gov (United States)

    Ravi Kumar, Venkatraman; Ariese, Freek; Umapathy, Siva

    2016-03-01

    The solvent plays a decisive role in the photochemistry and photophysics of aromatic ketones. Xanthone (XT) is one such aromatic ketone and its triplet-triplet (T-T) absorption spectra show intriguing solvatochromic behavior. Also, the reactivity of XT towards H-atom abstraction shows an unprecedented decrease in protic solvents relative to aprotic solvents. Therefore, a comprehensive solvatochromic analysis of the triplet-triplet absorption spectra of XT was carried out in conjunction with time dependent density functional theory using the ad hoc explicit solvent model approach. A detailed solvatochromic analysis of the T-T absorption bands of XT suggests that the hydrogen bonding interactions are different in the corresponding triplet excited states. Furthermore, the contributions of non-specific and hydrogen bonding interactions towards differential solvation of the triplet states in protic solvents were found to be of equal magnitude. The frontier molecular orbital and electron density difference analysis of the T1 and T2 states of XT indicates that the charge redistribution in these states leads to intermolecular hydrogen bond strengthening and weakening, respectively, relative to the S0 state. This is further supported by the vertical excitation energy calculations of the XT-methanol supra-molecular complex. The intermolecular hydrogen bonding potential energy curves obtained for this complex in the S0, T1, and T2 states support the model. In summary, we propose that the different hydrogen bonding mechanisms exhibited by the two lowest triplet excited states of XT result in a decreasing role of the nπ∗ triplet state, and are thus responsible for its reduced reactivity towards H-atom abstraction in protic solvents.

  2. Time sequence spectroscopy of AW UMa. The 518 nm Mg I triplet region analyzed with broadening functions

    Energy Technology Data Exchange (ETDEWEB)

    Rucinski, Slavek M., E-mail: rucinski@astro.utoronto.ca [Department of Astronomy and Astrophysics, University of Toronto, 50 St. George Street., Toronto, Ontario, M5S 3H4 (Canada)

    2015-02-01

    High-resolution spectroscopic observations of AW UMa, obtained on three consecutive nights with a median time resolution of 2.1 minutes, have been analyzed using the broadening function method in the spectral window of 22.75 nm around the 518 nm Mg i triplet region. Doppler images of the system reveal the presence of vigorous mass motions within the binary system; their presence puts into question the solid-body rotation assumption of the contact binary model. AW UMa appears to be a very tight, semi-detached binary; the mass transfer takes place from the more massive to the less massive component. The primary, a fast-rotating star with Vsini=181.4±2.5 km s{sup −1}, is covered with inhomogeneities: very slowly drifting spots and a dense network of ripples more closely participating in its rotation. The spectral lines of the primary show an additional broadening component (called the “pedestal”) that originates either in the equatorial regions, which rotate faster than the rest of the star by about 50 km s{sup −1}, or in an external disk-like structure. The secondary component appears to be smaller than predicted by the contact model. The radial velocity field around the secondary is dominated by accretion of matter transferred from (and possibly partly returned to) the primary component. The parameters of the binary are Asini=2.73±0.11 R{sub ⊙} and M{sub 1}sin{sup 3}i=1.29±0.15 M{sub ⊙}, M{sub 2}sin{sup 3}i=0.128±0.016 M{sub ⊙}. The mass ratio, q{sub sp}=M{sub 2}/M{sub 1}=0.099±0.003, while still the most uncertain among the spectroscopic elements, is substantially different from the previous numerous and mutually consistent photometric investigations which were based on the contact model. It should be studied why photometry and spectroscopy give such discrepant results and whether AW UMa is an unusual object or if only very high-quality spectroscopy can reveal the true nature of W UMa-type binaries.

  3. Ca II Triplet Spectroscopy of Small Magellanic Cloud Red Giants. III. Abundances and Velocities for a Sample of 14 Clusters

    CERN Document Server

    Parisi, M C; Clariá, J J; Villanova, S; Marcionni, N; Sarajedini, A; Grocholski, A J

    2015-01-01

    We obtained spectra of red giants in 15 Small Magellanic Cloud (SMC) clusters in the region of the CaII lines with FORS2 on the Very Large Telescope (VLT). We determined the mean metallicity and radial velocity with mean errors of 0.05 dex and 2.6 km/s, respectively, from a mean of 6.5 members per cluster. One cluster (B113) was too young for a reliable metallicity determination and was excluded from the sample. We combined the sample studied here with 15 clusters previously studied by us using the same technique, and with 7 clusters whose metallicities determined by other authors are on a scale similar to ours. This compilation of 36 clusters is the largest SMC cluster sample currently available with accurate and homogeneously determined metallicities. We found a high probability that the metallicity distribution is bimodal, with potential peaks at -1.1 and -0.8 dex. Our data show no strong evidence of a metallicity gradient in the SMC clusters, somewhat at odds with recent evidence from CaT spectra of a lar...

  4. Time-resolved photoelectron spectroscopy of a dinuclear Pt(II) complex: Tunneling autodetachment from both singlet and triplet excited states of a molecular dianion

    International Nuclear Information System (INIS)

    Time-resolved pump-probe photoelectron spectroscopy has been used to study the relaxation dynamics of gaseous [Pt2(μ-P2O5H2)4 + 2H]2− after population of its first singlet excited state by 388 nm femtosecond laser irradiation. In contrast to the fluorescence and phosphorescence observed in condensed phase, a significant fraction of the photoexcited isolated dianions decays by electron loss to form the corresponding monoanions. Our transient photoelectron data reveal an ultrafast decay of the initially excited singlet 1A2u state and concomitant rise in population of the triplet 3A2u state, via sub-picosecond intersystem crossing (ISC). We find that both of the electronically excited states are metastably bound behind a repulsive Coulomb barrier and can decay via delayed autodetachment to yield electrons with characteristic kinetic energies. While excited state tunneling detachment (ESETD) from the singlet 1A2u state takes only a few picoseconds, ESETD from the triplet 3A2u state is much slower and proceeds on a time scale of hundreds of nanoseconds. The ISC rate in the gas phase is significantly higher than in solution, which can be rationalized in terms of changes to the energy dissipation mechanism in the absence of solvent molecules. [Pt2(μ-P2O5H2)4 + 2H]2− is the first example of a photoexcited multianion for which ESETD has been observed following ISC

  5. Confirming the intrinsic abundance spread in the globular cluster NGC 6273 (M19) with calcium triplet spectroscopy

    Science.gov (United States)

    Yong, David; Da Costa, Gary S.; Norris, John E.

    2016-08-01

    We present metallicities for red giant stars in the globular cluster NGC 6273 based on intermediate resolution GMOS-S spectra of the calcium triplet region. For the 42 radial velocity members with reliable calcium triplet line strength measurements, we obtain metallicities, [Fe/H], using calibrations established from standard globular clusters. We confirm the presence of an intrinsic abundance dispersion identified by Johnson et al. The total range in [Fe/H] is ˜1.0 dex and after taking into account the measurement errors, the intrinsic abundance dispersion is σint[Fe/H] = 0.17 dex. Among the Galactic globular clusters, the abundance dispersion in NGC 6273 is only exceeded by ω Cen, which is regarded as the remnant of a disrupted dwarf galaxy, and M54, which is the nuclear star cluster of the Sagittarius dwarf galaxy. If these three globular clusters share the same formation mechanism, then NGC 6273 may also be the remnant nucleus of a disrupted dwarf galaxy.

  6. Confirming the intrinsic abundance spread in the globular cluster NGC 6273 (M 19) with calcium triplet spectroscopy

    CERN Document Server

    Yong, David; Norris, John E

    2016-01-01

    We present metallicities for red giant stars in the globular cluster NGC 6273 based on intermediate resolution GMOS-S spectra of the calcium triplet region. For the 42 radial velocity members with reliable calcium triplet line strength measurements, we obtain metallicities, [Fe/H], using calibrations established from standard globular clusters. We confirm the presence of an intrinsic abundance dispersion identified by Johnson et al. (2015). The total range in [Fe/H] is ~1.0 dex and after taking into account the measurement errors, the intrinsic abundance dispersion is \\sigma[Fe/H] = 0.17 dex. Among the Galactic globular clusters, the abundance dispersion in NGC 6273 is only exceeded by omega Cen, which is regarded as the remnant of a disrupted dwarf galaxy, and M 54, which is the nuclear star cluster of the Sagittarius dwarf galaxy. If these three globular clusters share the same formation mechanism, then NGC 6273 may also be the remnant nucleus of a disrupted dwarf galaxy.

  7. New constraints on the chemical evolution of the dwarf spheroidal galaxy LeoI from VLT spectroscopy

    CERN Document Server

    Gullieuszik, M; Saviane, I; Rizzi, L

    2009-01-01

    (Abridged) We present the spectroscopy of red giant stars in the dwarf spheroidal galaxy LeoI, aimed at further constraining its chemical enrichment history. Intermediate-resolution spectroscopy in the CaII triplet spectral region was obtained for 54 stars in LeoI using FORS2 at the ESO Very Large Telescope. The equivalent widths of CaII triplet lines were used to derive the metallicities of the target stars on the [Fe/H] scale of Carretta & Gratton, as well as on a scale tied to the global metal abundance, [M/H]. The metallicity distribution function for LeoI stars is confirmed to be very narrow, with mean value [M/H]~-1.2 and intrinsic dispersion, sigma_[M/H]=0.08. We find a few metal-poor stars (whose metallicity values depend on the adopted extrapolation of the existing calibrations), but in no case are stars more metal-poor than [Fe/H]=-2.6. Our measurements provide a hint of a shallow metallicity gradient of -0.27 dex/Kpc among LeoI red giants. By combining the metallicities of the target stars with...

  8. Time-resolved photoelectron spectroscopy of a dinuclear Pt(II) complex: Tunneling autodetachment from both singlet and triplet excited states of a molecular dianion

    Energy Technology Data Exchange (ETDEWEB)

    Winghart, Marc-Oliver, E-mail: marc-oliver.winghart@kit.edu; Unterreiner, Andreas-Neil [Institute of Physical Chemistry, Karlsruhe Institute of Technology, P.O. Box 6980, 76049 Karlsruhe (Germany); Yang, Ji-Ping [Institute of Physical Chemistry, Karlsruhe Institute of Technology, P.O. Box 6980, 76049 Karlsruhe (Germany); School of Sciences, Hefei University of Technology, Hefei 230009 (China); Vonderach, Matthias [Centre for Proteome Research, Institute of Integrative Biology, University of Liverpool, Liverpool L69 7ZB (United Kingdom); Huang, Dao-Ling; Wang, Lai-Sheng [Department of Chemistry, Brown University, Providence, Rhode Island 02912 (United States); Kruppa, Sebastian; Riehn, Christoph [Fachbereich Chemie und Landesforschungszentrum OPTIMAS, Technische Universität Kaiserslautern, Erwin-Schrödinger-Str. 52–54, 67663 Kaiserslautern (Germany); Kappes, Manfred M., E-mail: manfred.kappes@kit.edu [Institute of Physical Chemistry, Karlsruhe Institute of Technology, P.O. Box 6980, 76049 Karlsruhe (Germany); Institute of Nanotechnology, Karlsruhe Institute of Technology, P.O. Box 3640, 76021 Karlsruhe (Germany)

    2016-02-07

    Time-resolved pump-probe photoelectron spectroscopy has been used to study the relaxation dynamics of gaseous [Pt{sub 2}(μ-P{sub 2}O{sub 5}H{sub 2}){sub 4} + 2H]{sup 2−} after population of its first singlet excited state by 388 nm femtosecond laser irradiation. In contrast to the fluorescence and phosphorescence observed in condensed phase, a significant fraction of the photoexcited isolated dianions decays by electron loss to form the corresponding monoanions. Our transient photoelectron data reveal an ultrafast decay of the initially excited singlet {sup 1}A{sub 2u} state and concomitant rise in population of the triplet {sup 3}A{sub 2u} state, via sub-picosecond intersystem crossing (ISC). We find that both of the electronically excited states are metastably bound behind a repulsive Coulomb barrier and can decay via delayed autodetachment to yield electrons with characteristic kinetic energies. While excited state tunneling detachment (ESETD) from the singlet {sup 1}A{sub 2u} state takes only a few picoseconds, ESETD from the triplet {sup 3}A{sub 2u} state is much slower and proceeds on a time scale of hundreds of nanoseconds. The ISC rate in the gas phase is significantly higher than in solution, which can be rationalized in terms of changes to the energy dissipation mechanism in the absence of solvent molecules. [Pt{sub 2}(μ-P{sub 2}O{sub 5}H{sub 2}){sub 4} + 2H]{sup 2−} is the first example of a photoexcited multianion for which ESETD has been observed following ISC.

  9. R-matrix calculations of triplet gerade states of molecular hydrogen and their use for high-resolution spectroscopy

    Science.gov (United States)

    Oueslati, H.; Argoubi, F.; Bezzaouia, S.; Telmini, M.; Jungen, Ch.

    2014-03-01

    A variational R-matrix approach combined with multichannel quantum defect theory is used for a computational study of triplet gerade states of H2. Electron-ion reaction (quantum defect) matrices are calculated as functions of internuclear distance and energy for the bound and continuum ranges including singly and doubly excited configurations built on the 1σg (X+2Σg+) and 1σu (A+2Σu+) core states of the H2+ ion. It is shown how these matrices can be reduced to effective quantum defect functions adapted to the analysis of high-resolution spectra in the bound range. These R-matrix effective quantum defects are finally adjusted to the available experimental data [Sprecher et al., J. Phys. Chem. A 117, 9462 (2013), 10.1021/jp311793t], producing agreement with experiment to within 0.5 cm-1, nearly as good as obtained by Sprecher et al. In addition, the R-matrix calculations predict the evolution of the quantum defects for higher energies, in a range extending far into the electronic continuum.

  10. Ca II Triplet Spectroscopy of Small Magellanic Cloud Red Giants. III. Abundances and Velocities for a Sample of 14 Clusters

    Science.gov (United States)

    Parisi, M. C.; Geisler, D.; Clariá, J. J.; Villanova, S.; Marcionni, N.; Sarajedini, A.; Grocholski, A. J.

    2015-05-01

    We obtained spectra of red giants in 15 Small Magellanic Cloud (SMC) clusters in the region of the Ca ii lines with FORS2 on the Very Large Telescope. We determined the mean metallicity and radial velocity with mean errors of 0.05 dex and 2.6 km s-1, respectively, from a mean of 6.5 members per cluster. One cluster (B113) was too young for a reliable metallicity determination and was excluded from the sample. We combined the sample studied here with 15 clusters previously studied by us using the same technique, and with 7 clusters whose metallicities determined by other authors are on a scale similar to ours. This compilation of 36 clusters is the largest SMC cluster sample currently available with accurate and homogeneously determined metallicities. We found a high probability that the metallicity distribution is bimodal, with potential peaks at -1.1 and -0.8 dex. Our data show no strong evidence of a metallicity gradient in the SMC clusters, somewhat at odds with recent evidence from Ca ii triplet spectra of a large sample of field stars. This may be revealing possible differences in the chemical history of clusters and field stars. Our clusters show a significant dispersion of metallicities, whatever age is considered, which could be reflecting the lack of a unique age-metallicity relation in this galaxy. None of the chemical evolution models currently available in the literature satisfactorily represents the global chemical enrichment processes of SMC clusters.

  11. Ca II TRIPLET SPECTROSCOPY OF SMALL MAGELLANIC CLOUD RED GIANTS. II. ABUNDANCES FOR A SAMPLE OF FIELD STARS

    International Nuclear Information System (INIS)

    We have obtained metallicities of ∼360 red giant stars distributed in 15 Small Magellanic Cloud (SMC) fields from near-infrared spectra covering the Ca II triplet lines using the VLT + FORS2. The errors of the derived [Fe/H] values range from 0.09 to 0.35 dex per star, with a mean of 0.17 dex. The metallicity distribution (MD) of the whole sample shows a mean value of [Fe/H] = -1.00 ± 0.02, with a dispersion of 0.32 ± 0.01, in agreement with global mean [Fe/H] values found in previous studies. We find no evidence of a metallicity gradient in the SMC. In fact, on analyzing the MD of each field, we derived mean values of [Fe/H] = -0.99 ± 0.08 and [Fe/H] = -1.02 ± 0.07 for fields located closer and farther than 4 deg. from the center of the galaxy, respectively. In addition, there is a clear tendency for the field stars to be more metal-poor than the corresponding cluster they surround, independent of their positions in the galaxy and of the clusters' age. We argue that this most likely stems from the field stars being somewhat older and therefore somewhat more metal-poor than most of our clusters.

  12. Radial velocities and metallicities from infrared Ca II triplet spectroscopy of open clusters II. Berkeley 23, King 1, NGC 559, NGC 6603 and NGC 7245

    CERN Document Server

    Carrera, R; Ospina, N; Balaguer-Nuñez, L; Jordi, C; Monteagudo, L

    2015-01-01

    Context: Open clusters are key to studying the formation and evolution of the Galactic disc. However, there is a deficiency of radial velocity and chemical abundance determinations for open clusters in the literature. Aims: We intend to increase the number of determinations of radial velocities and metallicities from spectroscopy for open clusters. Methods: We acquired medium-resolution spectra (R~8000) in the infrared region Ca II triplet lines (~8500 AA) for several stars in five open clusters with the long-slit IDS spectrograph on the 2.5~m Isaac Newton Telescope (Roque de los Muchachos Observatory, Spain). Radial velocities were obtained by cross-correlation fitting techniques. The relationships available in the literature between the strength of infrared Ca II lines and metallicity were also used to derive the metallicity for each cluster. Results: We obtain = 48.6+/-3.4, -58.4+/-6.8, 26.0+/-4.3 and -65.3+/-3.2 km s-1 for Berkeley 23, NGC 559, NGC 6603 and NGC 7245, respectively. We found [Fe/H] =-0.25+...

  13. Spectroscopy of {sup 39}K{sup 85}Rb triplet excited states using ultracold a {sup 3}{sigma}{sup +} state molecules formed by photoassociation

    Energy Technology Data Exchange (ETDEWEB)

    Kim, J T; Wang, D; Eyler, E E; Gould, P L; Stwalley, W C [Physics Department, University of Connecticut, Storrs, CT 06269 (United States)], E-mail: w.stwalley@uconn.edu, E-mail: kimjt@chosun.ac.kr

    2009-05-15

    Convenient state-selective detection methods are proposed for exploring triplet Rydberg states from the metastable a {sup 3}{sigma}{sup +} state of ultracold KRb molecules by resonance-enhanced two-photon ionization and time-of-flight (TOF) mass spectroscopy. This would allow the first accurate determination of the ionization potential. Particularly suitable resonant intermediate states include the 2 {sup 3}{pi} {sub {omega}}, 3 {sup 3}{sigma}{sup +} and 4 {sup 3}{sigma}{sup +} states, and we report spectroscopic studies of these states. For the 2 {sup 3}{pi} {sub {omega}} state, the spin-orbit components ({omega} = 0{sup +}, 0{sup -}, 1 and 2) have been investigated and a shallow long-range state (5(0{sup +})) at {approx} 9.3 A has been observed. We compare our observations of these three states with predictions based on ab initio potential energy curves. Such studies may also permit the direct observation of autoionizing resonances leading to efficient formation of low-lying rovibrational levels of the {sup 2}{sigma}{sup +} ground state of KRb{sup +}, ideally in the v{sup +}= 0, N{sup +}= 0 level.

  14. Spectroscopy of proton-rich 66^Se up to J^{\\pi} = 6^+: isospin-breaking effect in the A = 66 isobaric triplet

    CERN Document Server

    Ruotsalainen, P; Bentley, M A; Auranen, K; Davies, P J; Grahn, T; Greenlees, P T; Henderson, J; Herzáň, A; Jakobsson, U; Joshi, P; Julin, R; Juutinen, S; Konki, J; Leino, M; Lotay, G; Nichols, A J; Obertelli, A; Pakarinen, J; Partanen, J; Peura, P; Rahkila, P; Sandzelius, M; Sarén, J; Scholey, C; Sorri, J; Stolze, S; Uusitalo, J; Wadsworth, R

    2013-01-01

    Candidates for three excited states in the 66^Se have been identified using the recoil-{\\beta} tagging method together with a veto detector for charged-particle evaporation channels. These results allow a comparison of mirror and triplet energy differences between analogue states across the A = 66 triplet as a function of angular momentum. The extracted triplet energy differences follow the negative trend observed in the f_7/2 shell. Shell-model calculations indicate a continued need for an additional isospin non-conserving interaction in addition to the Coulomb isotensor part as a function of mass.

  15. Radial velocities and metallicities from infrared Ca ii triplet spectroscopy of open clusters. II. Berkeley 23, King 1, NGC 559, NGC 6603, and NGC 7245

    Science.gov (United States)

    Carrera, R.; Casamiquela, L.; Ospina, N.; Balaguer-Núñez, L.; Jordi, C.; Monteagudo, L.

    2015-06-01

    Context. Open clusters are key to studying the formation and evolution of the Galactic disc. However, there is a deficiency of radial velocity and chemical abundance determinations for open clusters in the literature. Aims: We intend to increase the number of determinations of radial velocities and metallicities from spectroscopy for open clusters. Methods: We acquired medium-resolution spectra (R ~ 8000) in the infrared region Ca ii triplet lines (~8500 Å) for several stars in five open clusters with the long-slit IDS spectrograph on the 2.5 m Isaac Newton Telescope (Roque de los Muchachos Observatory, Spain). Radial velocities were obtained by cross-correlation fitting techniques. The relationships available in the literature between the strength of infrared Ca ii lines and metallicity were also used to derive the metallicity for each cluster. Results: We obtain ⟨Vr⟩ = 48.6 ± 3.4, -58.4 ± 6.8, 26.0 ± 4.3, and -65.3 ± 3.2 km s-1 for Berkeley 23, NGC 559, NGC 6603, and NGC 7245, respectively. We found [ Fe/H ] = -0.25 ± 0.14 and -0.15 ± 0.18 for NGC 559 and NGC 7245, respectively. Berkeley 23 has low metallicity, [ Fe/H ] = -0.42 ± 0.13, which is similar to other open clusters in the outskirts of the Galactic disc. In contrast, we derived high metallicity ([ Fe/H ] = +0.43 ± 0.15) for NGC 6603, which places this system among the most metal-rich known open clusters. To our knowledge, this is the first determination of radial velocities and metallicities from spectroscopy for these clusters, except NGC 6603, for which radial velocities had been previously determined. We have also analysed ten stars in the line of sight to King 1. Because of the large dispersion obtained in both radial velocity and metallicity, we cannot be sure that we have sampled true cluster members. Based on observations made with the 2.5 m Isaac Newton Telescope operated on the island of La Palma by the Isaac Newton Group in the Spanish Observatorio del Roque de los Muchachos of the

  16. Thiol-Activatable Triplet-Triplet Annihilation Upconversion with Maleimide-Perylene as the Caged Triplet Acceptor/Emitter.

    Science.gov (United States)

    Mahmood, Zafar; Zhao, Jianzhang

    2016-01-15

    Efficient thiol-activated triplet-triplet annihilation (TTA) upconversion system was devised with maleimide-caged perylene (Py-M) as the thiol-activatable triplet acceptor/emitter and with diiodoBodipy as the triplet photosensitizer. The photophysical processes were studied with steady-state UV-vis absorption spectroscopy, fluorescence spectroscopy, electrochemical properties, and nanosecond transient absorption spectroscopy. The triplet acceptor/emitter Py-M shows week fluorescence (ΦF = 0.8%), and no upconversion (ΦUC = 0%) was observed. The quenching of fluorescence of Py-M is due to photoinduced electron-transfer (PET) process from perylene to maleimide-caging unit, which quenches the singlet excited state of perylene. The fluorescence of Py-M was enhanced by 200-fold (ΦF = 97%) upon addition of thiols such as 2-mercaptoethanol, and the ΦUC was increased to 5.9%. The unique feature of this thiol-activated TTA upconversion is that the activation is based on addition reaction of the thiols with the caged acceptor/emitter, and no side products were formed. The previously reported cleavage approach gives side products which are detrimental to the TTA upconversion. With nanosecond transient absorption spectroscopy, we found that the triplet excited state of Py-M was not quenched by any PET process, which is different from singlet excited state (fluorescence) of Py-M. The results are useful for study of the triplet excited states of organic chromophores and for activatable TTA upconversion. PMID:26694534

  17. Toward Triplet Ground State NaLi Molecules

    Science.gov (United States)

    Ebadi, Sepehr; Jamison, Alan; Rvachov, Timur; Jing, Li; Son, Hyungmok; Jiang, Yijun; Zwierlein, Martin; Ketterle, Wolfgang

    2016-05-01

    The NaLi molecule is expected to have a long lifetime in the triplet ground-state due to its fermionic nature, large rotational constant, and weak spin-orbit coupling. The triplet state has both electric and magnetic dipole moments, affording unique opportunities in quantum simulation and ultracold chemistry. We have mapped the excited state NaLi triplet potential by means of photoassociation spectroscopy. We report on this and our further progress toward the creation of the triplet ground-state molecules using STIRAP. NSF, ARO-MURI, Samsung, NSERC.

  18. Direct observation of triplet energy transfer from semiconductor nanocrystals.

    Science.gov (United States)

    Mongin, Cédric; Garakyaraghi, Sofia; Razgoniaeva, Natalia; Zamkov, Mikhail; Castellano, Felix N

    2016-01-22

    Triplet excitons are pervasive in both organic and inorganic semiconductors but generally remain confined to the material in which they originate. We demonstrated by transient absorption spectroscopy that cadmium selenide semiconductor nanoparticles, selectively excited by green light, engage in interfacial Dexter-like triplet-triplet energy transfer with surface-anchored polyaromatic carboxylic acid acceptors, extending the excited-state lifetime by six orders of magnitude. Net triplet energy transfer also occurs from surface acceptors to freely diffusing molecular solutes, further extending the lifetime while sensitizing singlet oxygen in an aerated solution. The successful translation of triplet excitons from semiconductor nanoparticles to the bulk solution implies that such materials are generally effective surrogates for molecular triplets. The nanoparticles could thereby potentially sensitize a range of chemical transformations that are relevant for fields as diverse as optoelectronics, solar energy conversion, and photobiology. PMID:26798011

  19. The electronic field shift factor of the 4s2S1/2-4p2PJ transitions in CaII

    International Nuclear Information System (INIS)

    The isotope shifts (IS) of the resonance lines 4s2S1/2-4p2PJ in CaII (seven isotopes) have been measured by fast ion beam collinear laser spectroscopy (FIBCLS) with non-optical detection of the resonant laser-ion interaction. The electronic field shift factor F was derived from the experimental IS via a King plot procedure using the mean square nuclear charge radii from muon spectroscopy and electron scattering. The J-independent result F = -283(6) Mhz/fm2 was obtained. The F-value resulting from extensive many body perturbation theory (MBPT) calculations, recently performed by Maertensson-Pendrill et al., is in excellent agreement with the experimental value, confirming the reliability of the MBPT procedure. (orig.)

  20. Triplet exciton dynamics

    International Nuclear Information System (INIS)

    Results are presented of electron spin echo experiments combined with laser flash excitation on triplet states of aromatic molecules. Some of the theoretical and experimental aspects of the photoexcited triplet state are discussed in detail and the electron spin echo spectrometers and laser systems are described. All the experiments described in this thesis were performed at liquid helium temperatures. An account is given of the ESE experiments performed on the photoexcited, non-radiative, triplet state of pentacene in napthalene. This is an example of the ESE technique being used to ascertain the zero-field splitting parameters, the populating and depopulating rates, and the orientation of the pentacene molecules in the naphthalene host. A combination of high resolution laser flash excitation and electron-spin echoes in zero-magnetic field allowed the author to observe directly k(vector)→k(vector)' exciton scattering processes in the one-dimensional triplet excitons in tetrachlorobenzene for the first time. Additional experimental data about exciton scattering is provided and a study of the orientational dependence of the spin-lattice relaxation of the triplet excitons in an external magnetic field is described. (Auth.)

  1. Ca II Triplet Spectroscopy of Small Magellanic Cloud Red Giants. IV. Abundances for a Large Sample of Field Stars and Comparison with the Cluster Sample

    Science.gov (United States)

    Parisi, M. C.; Geisler, D.; Carraro, G.; Clariá, J. J.; Villanova, S.; Gramajo, L. V.; Sarajedini, A.; Grocholski, A. J.

    2016-09-01

    This paper represents a major step forward in the systematic and homogeneous study of Small Magellanic Cloud (SMC) star clusters and field stars carried out by applying the calcium triplet technique. We present in this work the radial velocity and metallicity of approximately 400 red giant stars in 15 SMC fields, with typical errors of about 7 km s‑1 and 0.16 dex, respectively. We added to this information our previously determined metallicity values for 29 clusters and approximately 350 field stars using the identical techniques. Using this enlarged sample, we analyze the metallicity distribution and gradient in this galaxy. We also compare the chemical properties of the clusters and of their surrounding fields. We find a number of surprising results. While the clusters, taken as a whole, show no strong evidence for a metallicity gradient (MG), the field stars exhibit a clear negative gradient in the inner region of the SMC, consistent with the recent results of Dobbie et al. For distances to the center of the galaxy less than 4°, field stars show a considerably smaller metallicity dispersion than that of the clusters. However, in the external SMC regions, clusters and field stars exhibit similar metallicity dispersions. Moreover, in the inner region of the SMC, clusters appear to be concentrated in two groups: one more metal-poor and another more metal-rich than field stars. Individually considered, neither cluster group presents an MG. Most surprisingly, the MG for both stellar populations (clusters and field stars) appears to reverse sign in the outer regions of the SMC. The difference between the cluster metallicity and the mean metallicity of the surrounding field stars turns out to be a strong function of the cluster metallicity. These results could be indicating different chemical evolution histories for these two SMC stellar populations. They could also indicate variations in the chemical behavior of the SMC in its internal and external regions.

  2. Lowest triplet (n, π*) electronic state of acrolein: Determination of structural parameters by cavity ringdown spectroscopy and quantum-chemical methods

    Science.gov (United States)

    Hlavacek, Nikolaus C.; McAnally, Michael O.; Drucker, Stephen

    2013-02-01

    The cavity ringdown absorption spectrum of acrolein (propenal, CH2=CH—CH=O) was recorded near 412 nm, under bulk-gas conditions at room temperature and in a free-jet expansion. The measured spectral region includes the 0^0_0 band of the T1(n, π*) ← S0 system. We analyzed the 0^0_0 rotational contour by using the STROTA computer program [R. H. Judge et al., J. Chem. Phys. 103, 5343 (1995)], 10.1063/1.470569, which incorporates an asymmetric rotor Hamiltonian for simulating and fitting singlet-triplet spectra. We used the program to fit T1(n, π*) inertial constants to the room-temperature contour. The determined values (cm-1), with 2σ confidence intervals, are A = 1.662 ± 0.003, B = 0.1485 ± 0.0006, C = 0.1363 ± 0.0004. Linewidth analysis of the jet-cooled spectrum yielded a value of 14 ± 2 ps for the lifetime of isolated acrolein molecules in the T1(n, π*), v = 0 state. We discuss the observed lifetime in the context of previous computational work on acrolein photochemistry. The spectroscopically derived inertial constants for the T1(n, π*) state were used to benchmark a variety of computational methods. One focus was on complete active space methods, such as complete active space self-consistent field (CASSCF) and second-order perturbation theory with a CASSCF reference function (CASPT2), which are applicable to excited states. We also examined the equation-of-motion coupled-cluster and time-dependent density function theory excited-state methods, and finally unrestricted ground-state techniques, including unrestricted density functional theory and unrestricted coupled-cluster theory with single and double and perturbative triple excitations. For each of the above methods, we or others [O. S. Bokareva et al., Int. J. Quantum Chem. 108, 2719 (2008)], 10.1002/qua.21803 used a triple zeta-quality basis set to optimize the T1(n, π*) geometry of acrolein. We find that the multiconfigurational methods provide the best agreement with fitted inertial

  3. Time-resolved resonance Raman spectroscopy of 1,3,5-hexatrienes in the lowest excited triplet state. The potential energy surface in T1

    OpenAIRE

    Wilbrandt, R; Langkilde, F.W.; Brouwer, A.M.; Negri, F; Orlandi, G.

    1990-01-01

    Time-resolved resonance Raman spectroscopy is applied to the study of the T1 state of 1,3,5-hexatriene and deuteriated and methylated derivatives in solution. The technique is described briefly. The experimentally obtained resonance Raman spectra are discussed in the light of theoretical Quantum Chemical Force Field calculations. Implications for the potential energy surface of the T1 state are discussed.

  4. Phasic Triplet Markov Chains.

    Science.gov (United States)

    El Yazid Boudaren, Mohamed; Monfrini, Emmanuel; Pieczynski, Wojciech; Aïssani, Amar

    2014-11-01

    Hidden Markov chains have been shown to be inadequate for data modeling under some complex conditions. In this work, we address the problem of statistical modeling of phenomena involving two heterogeneous system states. Such phenomena may arise in biology or communications, among other fields. Namely, we consider that a sequence of meaningful words is to be searched within a whole observation that also contains arbitrary one-by-one symbols. Moreover, a word may be interrupted at some site to be carried on later. Applying plain hidden Markov chains to such data, while ignoring their specificity, yields unsatisfactory results. The Phasic triplet Markov chain, proposed in this paper, overcomes this difficulty by means of an auxiliary underlying process in accordance with the triplet Markov chains theory. Related Bayesian restoration techniques and parameters estimation procedures according to the new model are then described. Finally, to assess the performance of the proposed model against the conventional hidden Markov chain model, experiments are conducted on synthetic and real data. PMID:26353069

  5. Phage inactivation by triplet acetone

    International Nuclear Information System (INIS)

    The exposure of lambda phage to triplet acetone is studied. The triplet acetone is obtained from aerobic oxidation of isobutanal catalysed by peroxidase. A decrease of lambda phage ability to infect Escherichia coli is reported, perhaps, partially due to the possible production of lesions in the phage genome. (M.A.C.)

  6. Formation of ultracold 7Li85Rb molecules in the lowest triplet electronic state by photoassociation and their detection by ionization spectroscopy

    International Nuclear Information System (INIS)

    We report the formation of ultracold 7Li85Rb molecules in the a3Σ+ electronic state by photoassociation (PA) and their detection via resonantly enhanced multiphoton ionization (REMPI). With our dual-species Li and Rb magneto-optical trap apparatus, we detect PA resonances with binding energies up to ∼62 cm−1 below the 7Li 2s 2S1/2 + 85Rb 5p 2P1/2 asymptote. In addition, we use REMPI spectroscopy to probe the a3Σ+ state and excited electronic 33Π and 43Σ+ states and identify a3Σ+ (v″ = 7–13), 33Π (vΠ′ = 0–10), and 43Σ+ (vΣ′ = 0–5) vibrational levels. Our line assignments agree well with ab initio calculations. These preliminary spectroscopic studies on previously unobserved electronic states are crucial to discovering transition pathways for transferring ultracold LiRb molecules created via PA to deeply bound rovibrational levels of the electronic ground state

  7. Formation of ultracold (7)Li(85)Rb molecules in the lowest triplet electronic state by photoassociation and their detection by ionization spectroscopy.

    Science.gov (United States)

    Altaf, Adeel; Dutta, Sourav; Lorenz, John; Pérez-Ríos, Jesús; Chen, Yong P; Elliott, D S

    2015-03-21

    We report the formation of ultracold (7)Li(85)Rb molecules in the a(3)Σ(+) electronic state by photoassociation (PA) and their detection via resonantly enhanced multiphoton ionization (REMPI). With our dual-species Li and Rb magneto-optical trap apparatus, we detect PA resonances with binding energies up to ∼62 cm(-1) below the (7)Li 2s (2)S1/2 + (85)Rb 5p (2)P1/2 asymptote. In addition, we use REMPI spectroscopy to probe the a(3)Σ(+) state and excited electronic 3(3)Π and 4(3)Σ(+) states and identify a(3)Σ(+) (v″ = 7-13), 3(3)Π (vΠ' = 0-10), and 4(3)Σ(+) (vΣ' = 0-5) vibrational levels. Our line assignments agree well with ab initio calculations. These preliminary spectroscopic studies on previously unobserved electronic states are crucial to discovering transition pathways for transferring ultracold LiRb molecules created via PA to deeply bound rovibrational levels of the electronic ground state. PMID:25796252

  8. Probing triplet-triplet annihilation zone and determining triplet exciton diffusion length by using delayed electroluminescence

    Science.gov (United States)

    Luo, Yichun; Aziz, Hany

    2010-05-01

    The literature shows that triplet-triplet annihilation (TTA) can provide a substantial contribution to the electroluminescence (EL) of fluorescent organic light-emitting devices (OLEDs). In this study, we utilized delayed EL measurements to probe the TTA emission zone of archetypical 8-hydroxyquinoline aluminum (Alq3) based OLEDs. The results demonstrate that the TTA emission zone of these devices is much larger than the prompt emission zone of singlet states that are formed in the electron-hole recombination. The larger TTA emission zone is attributed to the longer diffusion length of the Alq3 triplet states (60 nm) than that of Alq3 singlet states (20 nm).

  9. Observation of Two Triplet-Pair Intermediates in Singlet Exciton Fission.

    Science.gov (United States)

    Pensack, Ryan D; Ostroumov, Evgeny E; Tilley, Andrew J; Mazza, Samuel; Grieco, Christopher; Thorley, Karl J; Asbury, John B; Seferos, Dwight S; Anthony, John E; Scholes, Gregory D

    2016-07-01

    Singlet fission is an excitation multiplication process in molecular systems that can circumvent energy losses and significantly boost solar cell efficiencies; however, the nature of a critical intermediate that enables singlet fission and details of its evolution into multiple product excitations remain obscure. We resolve the initial sequence of events comprising the fission of a singlet exciton in solids of pentacene derivatives using femtosecond transient absorption spectroscopy. We propose a three-step model of singlet fission that includes two triplet-pair intermediates and show how transient spectroscopy can distinguish initially interacting triplet pairs from those that are spatially separated and noninteracting. We find that the interconversion of these two triplet-pair intermediates is limited by the rate of triplet transfer. These results clearly highlight the classical kinetic model of singlet fission and expose subtle details that promise to aid in resolving problems associated with triplet extraction. PMID:27281713

  10. Retinopathy of Prematurity in Triplets

    Directory of Open Access Journals (Sweden)

    Mehmet Ali Şekeroğlu

    2016-06-01

    Full Text Available Objectives: To investigate the incidence, severity and risk factors of retinopathy of prematurity (ROP in triplets. Materials and Methods: The medical records of consecutive premature triplets who had been screened for ROP in a single maternity hospital were analyzed and presence and severity of ROP; birth weight, gender, gestational age of the infant; route of delivery and the mode of conception were recorded. Results: A total of 54 triplets (40 males, 14 females who were screened for ROP between March 2010 and February 2013 were recruited for the study. All triplets were delivered by Caesarean section and 36 (66.7% were born following an assisted conception. During follow-up, seven (13% of the infants developed ROP of any stage and two (3.7% required laser photocoagulation. The mean gestational age of triplets with ROP was 27.6±1.5 (27-31 weeks whereas it was 32.0±1.5 (30-34 weeks in those without ROP (p=0.002. The mean birth weights of triplets with and without ROP were 1290.0±295.2 (970-1600 g and 1667.5±222.2 (1130-1960 g, respectively (p<0.001. The presence of ROP was not associated with gender (p=0.358 or mode of conception (p=0.674. Conclusion: ROP in triplets seems to be mainly related to low gestational age and low birth weight. Further prospective randomized studies are necessary to demonstrate risk factors of ROP in triplets and to determine if and how gemelarity plays a role in the development of ROP.

  11. Triplets pass their pressure test

    CERN Multimedia

    2007-01-01

    All the LHC inner triplets have now been repaired and are in position. The first ones have passed their pressure tests with flying colours. The repaired inner triplet at LHC Point 1, right side (1R). Ranko Ostojic (on the right), who headed the team responsible for repairing the triplets, shows the magnet to Robert Zimmer, President of the University of Chicago and of Fermi Research Alliance, who visited CERN on 20th August.Three cheers for the triplets! All the LHC inner triplets have now been repaired and are in position in the tunnel. Thanks to the mobilisation of a multidisciplinary team from CERN and Fermilab, assisted by the KEK Laboratory and the Lawrence Berkeley National Laboratory (LBNL), a solution has been found, tested, validated and applied. At the end of March this year, one of the inner triplets at Point 5 failed to withstand a pressure test. A fault was identified in the supports of two out of the three quadruple magne...

  12. Observational Searches for Chromospheric -Mode Oscillations from CaII H-Line Observations

    Indian Academy of Sciences (India)

    R. Kariyappa; L. Damé; K. M. Hiremath

    2006-06-01

    We have used a high spatial and temporal resolution of long time sequence of spectra in CaII H-line obtained at the Vacuum Tower Telescope (VTT) of the Sacramento Peak Observatory on a quiet region at the center of the solar disk over a large number of bright points and network elements to search for atmospheric (chromospheric) -mode oscillations. An important parameter of the H-line profile, intensity at H2V(IH2V), has been derived from a large number of line profiles. We derived the light curves of all the bright points and network elements. The light curves represent the main pulse with large intensity amplitude and followed by several follower pulses with lower intensity amplitudes. The light curves of these bright points would give an impression that one can as well draw curves towards and away from the highest peak (main pulse) showing an exponential growth and decay of the amplitudes. An exponential decaying function has been fitted for all the light curves of the bright points to determine the damping time of the modes that are more or less the same, and one value of the coefficient of exponent can represent reasonably well the decay for all the cases. The FFT analysis of temporal variation of both the bright points and the network elements indicates around 10-min periodicity. We speculate that this longer period of oscillation may be related to chromospheric -mode oscillations.

  13. Fetomaternal outcome in triplet pregnancy

    International Nuclear Information System (INIS)

    To determine maternal outcome as antenatal and postnatal complications and neonatal outcome as birth weight, morbidity and mortality in triplet gestation. All the patients with triplet pregnancy beyond 28 weeks gestation, who delivered at the study place during above period were included in the study. The primary outcome measures were frequency of maternal complications and neonatal birth, weight and morbidity. Secondary outcome measures included the frequency of assisted conception in the studied cohart. Eighteen women had triplet pregnancy beyond 28 weeks. Nine were booked, 6 non-booked and 3 of them were referred. Mean duration of gestation was 237.8 days (33.8 weeks). The antenatal complications were preterm delivery in 50%, hypertension in 50%, anemia in 44.4% and obstetric cholestasis in 5.6%. Eight patients (44.4%) suffered postpartum hemorrhage. One patient had peripartum hysterectomy and later expired in intensive care unit after three weeks. Maternal mortality ratio was 5.6%. Fifty five percent women had induction of ovulation with Clomiphene, while none had In Vitro Fertilization (IVF) or Intracytoplasmic Insemination (ICSI) or received gonadotrophins. Fifteen sets of triplets were delivered abdominally. Mean birth weights of 1st, 2nd and 3rd triplet were 1651, 1640 and 1443 grams respectively. Five sets of triplets (27.8%) had more than 25% discordance for birth weight. The mean Apgar scores of the babies at 1 and 10 minutes after birth were 6.0 and 8.0, 5.6 and 7.5; and 5.2 and 7.0 respectively. Of the 54 infants, 18 required Neonatal Intensive Care Unit (NICU) admission and 14 were admitted in nursery. Two died shortly after birth. Total perinatal mortalities were 13 including 4 cases of intra-uterine demise. Three babies suffered from jaundice, 7 had sepsis and 8 had respiratory distress syndrome. Triplet gestation had a high rate of fetomaternal complications. Majority had history of assisted conception. (author)

  14. SUGRA interactions within flavor triplets

    CERN Document Server

    Towe, J

    2005-01-01

    A specific new quark permits that flavor generations constitute a representation of the 3-dimensional SU(3) symmetry that characterizes the Z(3) orbifold. In this context, color and supergravity bind triplets and 4-tuplets into composite fields of spin 3/2 and spin 2; and the symmetry E(8) that characterizes (the observable sector of) 10-spacetime is interpreted as having reduced to SU(5)XSU(3), where SU(3) refers to the 3-dimensional symmetry described above and SU(5) consists of colors and of isotopic spin classes that are devoid of color and hypercharge. In this context, supergravity interactions occur to color bound quarks that are experiencing asymptotic freedom within triplets. Quark-lepton transitions are produced, but quickly reverse, preserving the triplets. The symmetry consisting of six quark classes and six lepton classes is also maintained because the predicted quark is an anomalous, left-handed version of the strange quark.

  15. Development of a Triplet-Triplet Absorption Ruler: DNA- and Chromatin-Mediated Drug Molecule Release from a Nanosurface.

    Science.gov (United States)

    Chakraborty, Sudeshna Das; Sau, Abhishek; Kuznetsov, Denis V; Banerjee, Amrita; Bardhan, Munmun; Bhattacharya, Maireyee; Dasgupta, Dipak; Basu, Samita; Senapati, Dulal

    2016-07-14

    Triplet-triplet (T-T) absorption spectroscopy has been used successfully as a molecular ruler to understand the actual release process of sanguinarine as a drug molecule from a gold nanoparticle surface in the presence of cell components, that is, DNA and chromatin. The obtained results have been verified by fluorescence and surface-enhanced Raman spectroscopy (SERS), and a plausible explanation has been put forward to describe the underestimation and overestimation of the percentage (%) of the release of drug molecules measured by fluorescence- and SERS-based techniques, respectively, over the highlighted T-T absorption spectroscopy. Because of the intrinsic nature of absorption, the reported T-T absorption spectroscopic assay overpowers fluorescence- and SERS-based assays, which are limited by the long-range interaction and nonlinear dependence of the concentration of analytes, respectively. PMID:27284775

  16. Interplay between singlet and triplet excited states in a conformationally locked donor–acceptor dyad

    KAUST Repository

    Filatov, Mikhail A.

    2015-10-13

    The synthesis and photophysical characterization of a palladium(II) porphyrin – anthracene dyad bridged via short and conformationally rigid bicyclo[2.2.2]octadiene spacer were achieved. A spectroscopic investigation of the prepared molecule in solution has been undertaken to study electronic energy transfer in excited singlet and triplet states between the anthracene and porphyrin units. By using steady-state and time-resolved photoluminescence spectroscopy it was shown that excitation of the singlet excited state of the anthracene leads to energy transfer to the lower-lying singlet state of porphyrin. Alternatively, excitation of the porphyrin followed by intersystem crossing to the triplet state leads to very fast energy transfer to the triplet state of anthracene. The rate of this energy transfer has been determined by transient absorption spectroscopy. Comparative studies of the dynamics of triplet excited states of the dyad and reference palladium octaethylporphyrin (PdOEP) have been performed.

  17. v-erbA overexpression is required to extinguish c-erbA function in erythroid cell differentiation and regulation of the erbA target gene CAII

    DEFF Research Database (Denmark)

    Disela, C; Glineur, C; Bugge, T; Sap, J; Stengl, G; Dodgson, J; Stunnenberg, H; Beug, H; Zenke, M

    1991-01-01

    The v-erbA oncoprotein represents a retrovirus-transduced oncogenic version of the thyroid hormone (T3/T4) receptor c-erbA (type alpha). It contributes to virus-induced erythroleukemia by efficiently arresting differentiation of red cell progenitors and by suppressing transcription of erythrocyte...... transient expression experiments and is a target for efficient down-regulation of CAII transcription by the v-erbA oncoprotein. In stably transformed erythroblasts coexpressing the v-erbA oncoprotein and the c-erbA/T3 receptor at an approximately equimolar ratio, c-erbA activity is dominant over v-erbA. T3...... efficiently induced erythroid differentiation in these cells, thus overcoming the v-erbA-mediated differentiation arrest. Likewise, T3 activated CAII transcription as well as transient expression of a T3-responsive reporter gene containing the CAII-specific erbA-binding site. The c-erbA-dependent activation...

  18. Tough Decisions for Premature Triplets.

    Science.gov (United States)

    Hurst, Ashley; Vergales, Brooke D; Paget-Brown, Alix; Mercurio, Mark; Lantos, John D

    2016-02-01

    When infants are born at the borderline of viability, doctors and parents have to make tough decisions about whether to institute intensive care or provide only palliative care. Often, these decisions are made in moments of profound emotional turmoil, and parents receive different information from different health professionals. Communication can become garbled. It may be difficult to tell when and whether the patient's clinical condition has changed enough so that certain choices that had once been permissible become impermissible. In this "Ethics Rounds," we present a case of triplets born at the borderline of viability. We sought comments from the triplets' parents, the doctors and ethicist who were caring for the infants, and a bioethicist/neonatologist from another hospital. PMID:26738882

  19. Predissociation and autoionization of triplet Rydberg states in molecular hydrogen

    OpenAIRE

    Dinu, L.; Picard, Y. J.; Van Der Zande, W. J.

    2004-01-01

    We present single-photon spectroscopy in molecular hydrogen starting from the metastable c(3)Pi(u)(-) state to a number of triplet nd-Rydberg states (v=0-4, n=12-20). Using fast beam spectroscopy both the autoionization channel and the predissociation channel are quantified, field free, as well as with small electric fields. Coupling with the i(3)Pi(g) state is assumed to be responsible for field-free predissociation of the v=0 Rydberg levels. The stronger observed predissociation channel of ...

  20. Higher triplet state of fullerene C70 revealed by electron spin relaxation

    International Nuclear Information System (INIS)

    Spin-lattice relaxation times T1 of photoexcited triplets 3C70 in glassy decalin were obtained from electron spin echo inversion recovery dependences. In the range 30–100 K, the temperature dependence of T1 was fitted by the Arrhenius law with an activation energy of 172 cm−1. This indicates that the dominant relaxation process of 3C70 is described by an Orbach-Aminov mechanism involving the higher triplet state t2 which lies 172 cm−1 above the lowest triplet state t1. Chemical modification of C70 fullerene not only decreases the intrinsic triplet lifetime by about ten times but also increases T1 by several orders of magnitude. The reason for this is the presence of a low-lying excited triplet state in 3C70 and its absence in triplet C70 derivatives. The presence of the higher triplet state in C70 is in good agreement with the previous results from phosphorescence spectroscopy

  1. Higher triplet state of fullerene C{sub 70} revealed by electron spin relaxation

    Energy Technology Data Exchange (ETDEWEB)

    Uvarov, Mikhail N., E-mail: uvarov@kinetics.nsc.ru [Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences, Institutskaya St. 3, 630090 Novosibirsk (Russian Federation); Behrends, Jan [Berlin Joint EPR Lab, Freie Universität Berlin, Arnimallee 14, 14195 Berlin (Germany); Kulik, Leonid V. [Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences, Institutskaya St. 3, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogova St. 2, Novosibirsk (Russian Federation)

    2015-12-28

    Spin-lattice relaxation times T{sub 1} of photoexcited triplets {sup 3}C{sub 70} in glassy decalin were obtained from electron spin echo inversion recovery dependences. In the range 30–100 K, the temperature dependence of T{sub 1} was fitted by the Arrhenius law with an activation energy of 172 cm{sup −1}. This indicates that the dominant relaxation process of {sup 3}C{sub 70} is described by an Orbach-Aminov mechanism involving the higher triplet state t{sub 2} which lies 172 cm{sup −1} above the lowest triplet state t{sub 1}. Chemical modification of C{sub 70} fullerene not only decreases the intrinsic triplet lifetime by about ten times but also increases T{sub 1} by several orders of magnitude. The reason for this is the presence of a low-lying excited triplet state in {sup 3}C{sub 70} and its absence in triplet C{sub 70} derivatives. The presence of the higher triplet state in C{sub 70} is in good agreement with the previous results from phosphorescence spectroscopy.

  2. Competition between singlet and triplet superconductivity

    OpenAIRE

    De Cao, Tian; Wang, Tie Bang

    2009-01-01

    The competition between singlet and triplet superconductivity is examined in consideration of correlations on an extended Hubbard model. It is shown that the triplet superconductivity may not be included in the common Hubbard model since the strong correlation favors the singlet superconductivity, and thus the triplet superconductivity should be induced by the electron-phonon interaction and the ferromagnetic exchange interaction. We also present a superconducting qualification with which mag...

  3. Influence of plasma chemistry on oxygen triplets

    OpenAIRE

    Milosavljevic, Vladimir; Ellingboe, Albert; Daniels, Stephen

    2011-01-01

    The plasma chemistry of fluorocarbon-oxygen-argon discharges and its influence on prominent oxygen triplets are studied. The oxygen 777 triplet is very important for the measurement of atomic oxygen in low pressure plasmas, since the 777.417 nm spectral line is frequently used for actinometry. In this paper we identify changes in the individual 777 triplet lines arising from cascade effects from higher energy levels of oxygen, and from resonant energy transfer from energetic carbon...

  4. Magnetic Field Effects on Triplet-Triplet Annihilation in Solutions: Modulation of Visible/NIR Luminescence

    OpenAIRE

    Mani, Tomoyasu; Vinogradov, Sergei A.

    2013-01-01

    Photon upconversion based on sensitized triplet-triplet annihilation (TTA) presents interest for such areas as photovoltaics and imaging. Usually energy upconversion is observed as p-type delayed fluorescence from molecules whose triplet states are populated via energy transfer from a suitable triplet donor, followed by TTA. Magnetic field effects (MFE) on delayed fluorescence in molecular crystals are well known; however, there exist only a few examples of MFE on TTA in solutions, and all of...

  5. Design and construction of triplet atmospheric cold plasma jet for sterilization

    Directory of Open Access Journals (Sweden)

    F. Sohbatzadeh

    2014-03-01

    Full Text Available In this paper, construction of triplet atmospheric plasma jet using argon, air, oxygen and nitrogen gases is reported. Bactericidal effect of the plasma jet is also investigated. To that end, longitudinal geometric configuration for the electrodes was chosen because it would increase the jet length. Electrical characteristics, jet length dependencies on the applied voltage and gas flow rate were decided, experimentally. Relative concentrations of chemical reactive species such as ozone, atomic oxygen, NOx compounds and hydroxyl were measured using optical emission spectroscopy. It was seen that atomic oxygen and ozone concentrations with triplet plasma jet are more than the concentration of single plasma jet. Triplet plasma jet was also used for sterilization of solid and liquid surfaces to disinfect gram-negative and gram-positive Escherichia coli and Streptococcus pyogenes bacteria. The results verified the effectiveness of the triplet plasma jet for killing bacteria.

  6. The large- and small-scale CaII K structure of the Milky Way from observations of Galactic and Magellanic sightlines

    CERN Document Server

    Smoker, J V; Fox, A J

    2015-01-01

    Aims: By utilising spectra of early-type stellar probes of known distances in the same region of the sky, the large and small-scale (pc) structure of the Galactic ISM can be investigated. This paper determines the variation in line strength of CaII at 3933.661 A, as a function of probe separation for a sample of stars, including many sightlines in the Magellanic Clouds. Methods: FLAMES-GIRAFFE data taken with the VLT towards early-type stars in 3 Galactic & 4 Magellanic open clusters in CaII are used to obtain the velocity, EW, column density and line width of IS Galactic Ca for a total of 657 stars, of which 443 are Magellanic sightlines. In each cluster there are 43-110 stars observed. Additionally, FEROS and UVES CaII & NaI spectra of 21 Galactic & 154 Magellanic early-type stars are presented and combined with data from the literature to study the Ca column density/parallax relationship. Results: For the four Magellanic clusters studied with FLAMES, the strength of the Galactic IS CaII K EW ov...

  7. Charge pumping due to triplet vector chirality in ferromagnet/triplet superconductor junctions

    OpenAIRE

    Yokoyama, Takehito

    2011-01-01

    We investigate charge pumping in ferromagnet/triplet superconductor junctions where the magnetization of the ferromagnet is inhomogeneous and dynamical. It is shown that charge current is pumped due to the coupling of the localized spin with triplet vector spin chirality, vector spin chirality formed by the triplet vector of Cooper pairing. Physical mechanism of the charge pumping is also discussed.

  8. Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hellman, Hal

    1968-01-01

    This booklet discusses spectroscopy, the study of absorption of radiation by matter, including X-ray, gamma-ray, microwave, mass spectroscopy, as well as others. Spectroscopy has produced more fundamental information to the study of the detailed structure of matter than any other tools.

  9. Spectroscopy

    CERN Document Server

    Walker, S

    1976-01-01

    The three volumes of Spectroscopy constitute the one comprehensive text available on the principles, practice and applications of spectroscopy. By giving full accounts of those spectroscopic techniques only recently introduced into student courses - such as Mössbauer spectroscopy and photoelectron spectroscopy - in addition to those techniques long recognised as being essential in chemistry teaching - sucha as e.s.r. and infrared spectroscopy - the book caters for the complete requirements of undergraduate students and at the same time provides a sound introduction to special topics for graduate students.

  10. Diphotons from an Electroweak Triplet-Singlet

    Energy Technology Data Exchange (ETDEWEB)

    Howe, Kiel [Fermilab; Knapen, Simon [UC, Berkeley; Robinson, Dean J. [UC, Berkeley

    2016-03-29

    The neutral component of a real pseudoscalar electroweak (EW) triplet can produce a diphoton excess at 750 GeV, if it is somewhat mixed with an EW singlet pseudoscalar. This triplet-singlet mixing allows for greater freedom in the diboson branching ratios than the singlet-only case, but it is still possible to probe the parameter space extensively with 300 fb$^{-1}$. The charged component of the triplet is pair-produced at the LHC, which results in a striking signal in the form of a pair of $W\\gamma$ resonances with an irreducible rate of 0.27 fb. Other signatures include multiboson final states from cascade decays of the triplet-singlet neutral states. A large class of composite models feature both EW singlet and triplet pseudo-Nambu Goldstone bosons in their spectrum, with the diboson couplings generated by axial anomalies.

  11. [2+2] Photocycloaddition reaction dynamics of triplet pyrimidines.

    Science.gov (United States)

    Yang, Chunfan; Yu, Youqing; Liu, Kunhui; Song, Di; Wu, Lidan; Su, Hongmei

    2011-06-01

    Taking the 266 nm excited pyrimidine (uracil or thymine) with cyclopentene as model reaction systems, we have examined the photoproduct formation dynamics from the [2 + 2] photocycloaddition reactions of triplet pyrimidines in solution and provided mechanistic insights into this important DNA photodamage reaction. By combining two compliment methods of nanosecond time-resolved transient IR and UV-vis laser flash-photolysis spectroscopy, the photoproduct formation dynamics as well as the triplet quenching kinetics are measured. Characteristic IR absorption bands due to photoproduct formation have been observed and product quantum yields are determined to be ∼0.91% for uracil and ∼0.41% for thymine. Compared to the measured large quenching rate constants of triplet uracil (1.5 × 10(9) M(-1)s(-1)) or thymine (0.6 × 10(9) M(-1)s(-1)) by cyclopentene, the inefficiency in formation of photoproducts indicates competitive physical quenching processes may exist on the route leading to photoproducts, resulting in very small product yields eventually. Such an energy wasting process is found to be resulted from T(1)/S(0) surface crossings by the hybrid density functional calculations, which compliments the experiments and reveals the reaction mechanism. PMID:21557584

  12. Singlet and triplet instability theorems

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, Tomonori; Hirata, So, E-mail: sohirata@illinois.edu [Department of Chemistry, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, Illinois 61801 (United States); CREST, Japan Science and Technology Agency, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan)

    2015-09-21

    A useful definition of orbital degeneracy—form-degeneracy—is introduced, which is distinct from the usual energy-degeneracy: Two canonical spatial orbitals are form-degenerate when the energy expectation value in the restricted Hartree–Fock (RHF) wave function is unaltered upon a two-electron excitation from one of these orbitals to the other. Form-degenerate orbitals tend to have isomorphic electron densities and occur in the highest-occupied and lowest-unoccupied molecular orbitals (HOMOs and LUMOs) of strongly correlated systems. Here, we present a mathematical proof of the existence of a triplet instability in a real or complex RHF wave function of a finite system in the space of real or complex unrestricted Hartree–Fock wave functions when HOMO and LUMO are energy- or form-degenerate. We also show that a singlet instability always exists in a real RHF wave function of a finite system in the space of complex RHF wave functions, when HOMO and LUMO are form-degenerate, but have nonidentical electron densities, or are energy-degenerate. These theorems provide Hartree–Fock-theory-based explanations of Hund’s rule, a singlet instability in Jahn–Teller systems, biradicaloid electronic structures, and a triplet instability during some covalent bond breaking. They also suggest (but not guarantee) the spontaneous formation of a spin density wave (SDW) in a metallic solid. The stability theory underlying these theorems extended to a continuous orbital-energy spectrum proves the existence of an oscillating (nonspiral) SDW instability in one- and three-dimensional homogeneous electron gases, but only at low densities or for strong interactions.

  13. Singlet and triplet instability theorems

    International Nuclear Information System (INIS)

    A useful definition of orbital degeneracy—form-degeneracy—is introduced, which is distinct from the usual energy-degeneracy: Two canonical spatial orbitals are form-degenerate when the energy expectation value in the restricted Hartree–Fock (RHF) wave function is unaltered upon a two-electron excitation from one of these orbitals to the other. Form-degenerate orbitals tend to have isomorphic electron densities and occur in the highest-occupied and lowest-unoccupied molecular orbitals (HOMOs and LUMOs) of strongly correlated systems. Here, we present a mathematical proof of the existence of a triplet instability in a real or complex RHF wave function of a finite system in the space of real or complex unrestricted Hartree–Fock wave functions when HOMO and LUMO are energy- or form-degenerate. We also show that a singlet instability always exists in a real RHF wave function of a finite system in the space of complex RHF wave functions, when HOMO and LUMO are form-degenerate, but have nonidentical electron densities, or are energy-degenerate. These theorems provide Hartree–Fock-theory-based explanations of Hund’s rule, a singlet instability in Jahn–Teller systems, biradicaloid electronic structures, and a triplet instability during some covalent bond breaking. They also suggest (but not guarantee) the spontaneous formation of a spin density wave (SDW) in a metallic solid. The stability theory underlying these theorems extended to a continuous orbital-energy spectrum proves the existence of an oscillating (nonspiral) SDW instability in one- and three-dimensional homogeneous electron gases, but only at low densities or for strong interactions

  14. Charge Carrier Generation Followed by Triplet State Formation, Annihilation, and Carrier Recreation in PBDTTT-C:PC 60 BM Photovoltaic Blends

    KAUST Repository

    Gehrig, Dominik W.

    2015-05-22

    Triplet state formation after photoexcitation of low-bandgap polymer:fullerene blends has recently been demonstrated, however, the precise mechanism and its impact on solar cell performance is still under debate. Here, we study exciton dissociation, charge carrier generation and triplet state formation in low-bandgap polymer PBDTTT-C:PC60BM bulk heterojunction photovoltaic blends by a combination of fs-µs broadband Vis-NIR transient absorption (TA) pump-probe spectroscopy and multivariate curve resolution (MCR) data analysis. We found sub-ps exciton dissociation and charge generation followed by sub-ns triplet state creation. The carrier dynamics and triplet state dynamics exhibited a very pronounced intensity dependence indicating non-geminate recombination of free carriers is the origin of triplet formation in these blends. Triplets were found to be the dominant state present on the nanosecond timescale. Surprisingly, the carrier population increased again on the ns-µs timescale. We attribute this to triplet-triplet annihilation and the formation of higher energy excited states that subsequently underwent charge transfer. This unique dip and recovery of the charge population is a clear indication that triplets are formed by non-geminate recombination, as such a kinetic is incompatible with a monomolecular triplet state formation process.

  15. Higgs triplets and limits from precision measurements

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Mu-Chun; /Fermilab; Dawson, Sally; Krupovnickas, Tadas; /Brookhaven

    2006-04-01

    In this letter, they present the results on a global fit to precision electroweak data in a Higgs triplet model. In models with a triplet Higgs boson, a consistent renormalization scheme differs from that of the Standard Model and the global fit shows that a light Higgs boson with mass of 100-200 GeV is preferred. Triplet Higgs bosons arise in many extensions of the Standard Model, including the left-right model and the Little Higgs models. The result demonstrates the importance of the scalar loops when there is a large mass splitting between the heavy scalars. It also indicates the significance of the global fit.

  16. Studies of energy transfer processes in triplet states using optically detected magnetic resonance

    Energy Technology Data Exchange (ETDEWEB)

    Lewellyn, M.T.

    1977-06-01

    The techniques of both continuous wave and pulsed-coherent optically detected magnetic resonance spectroscopy are used to study energy transfer processes in the lowest triplet states of two aromatic molecular crystals (1,2,4,5-tetrachlorobenzene and pyrimidine). Of particular interest are the effects of crystal dimensionality and isotopic trap states on the efficiency of the transfer process in these systems.

  17. The anaerobic photolysis of lens α-crystallin: evidence for triplet state mediated photodamage

    International Nuclear Information System (INIS)

    Anaerobic solutions of lens α-crystallin were subjected to near-UV (>295) irradiation, and the photoproducts were analyzed by fluorescence and room-temperature phosphorescence spectroscopy. This report is the first demonstration of a long-lived triplet state associated with a protein photolysis product. (author)

  18. The molecular photophysics of chlorophyl : a study of its triplet state

    NARCIS (Netherlands)

    Kleibeuker, J.F.

    1977-01-01

    The lowest excited triplet state T 0 of chlorophyll a , chlorophyll b , bacteriochlorophyll and corresponding pheophytins has been studied by magnetic resonance and optical spectroscopy. Zero field splitting (US) parameters D and E, populating rates, a

  19. Carborane-Based Carbonic Anhydrase Inhibitors: Insight into CAII/CAIX Specificity from a High-Resolution Crystal Structure, Modeling, and Quantum Chemical Calculations

    Directory of Open Access Journals (Sweden)

    Pavel Mader

    2014-01-01

    Full Text Available Carborane-based compounds are promising lead structures for development of inhibitors of carbonic anhydrases (CAs. Here, we report structural and computational analysis applicable to structure-based design of carborane compounds with selectivity toward the cancer-specific CAIX isoenzyme. We determined the crystal structure of CAII in complex with 1-methylenesulfamide-1,2-dicarba-closo-dodecaborane at 1.0 Å resolution and used this structure to model the 1-methylenesulfamide-1,2-dicarba-closo-dodecaborane interactions with CAIX. A virtual glycine scan revealed the contributions of individual residues to the energy of binding of 1-methylenesulfamide-1,2-dicarba-closo-dodecaborane to CAII and CAIX, respectively.

  20. Carborane-Based Carbonic Anhydrase Inhibitors: Insight into CAII/CAIX Specificity from a High-Resolution Crystal Structure, Modeling, and Quantum Chemical Calculations

    Science.gov (United States)

    Mader, Pavel; Pecina, Adam; Cígler, Petr; Lepšík, Martin; Šícha, Václav; Hobza, Pavel; Grüner, Bohumír; Fanfrlík, Jindřich; Brynda, Jiří; Řezáčová, Pavlína

    2014-01-01

    Carborane-based compounds are promising lead structures for development of inhibitors of carbonic anhydrases (CAs). Here, we report structural and computational analysis applicable to structure-based design of carborane compounds with selectivity toward the cancer-specific CAIX isoenzyme. We determined the crystal structure of CAII in complex with 1-methylenesulfamide-1,2-dicarba-closo-dodecaborane at 1.0 Å resolution and used this structure to model the 1-methylenesulfamide-1,2-dicarba-closo-dodecaborane interactions with CAIX. A virtual glycine scan revealed the contributions of individual residues to the energy of binding of 1-methylenesulfamide-1,2-dicarba-closo-dodecaborane to CAII and CAIX, respectively. PMID:25309911

  1. Dark Matter in Inert Triplet Models

    CERN Document Server

    Araki, Takeshi; Nagao, Keiko I

    2011-01-01

    We study the inert triplet models, in which the standard model (SM) is extended to have a new SU(2)L triplet scalar (Y=0 or 2) with an Z2 symmetry. We show that the neutral component of the triplet can be a good dark matter candidate. In particular, for the hypercharge Y=0 triplet model, the WMAP data favors the region where the dark matter mass is around 5.5 TeV, which is also consistent with the direct detection experiments. In contrast, for the Y=2 model, although dark matter with its mass around 2.8 TeV is allowed by WMAP, it is excluded by the direct detection experiments because the spin-independent cross section is enhanced by the Z mediated tree-level scattering process.

  2. Dark matter in inert triplet models

    International Nuclear Information System (INIS)

    We study the inert triplet models, in which the standard model is extended to have a new SU(2)L triplet scalar (Y=0 or 2) with an Z2 symmetry. We show that the neutral component of the triplet can be a good dark matter candidate. In particular, for the hypercharge Y=0 triplet model, the WMAP data favors the region where the dark matter mass is around 5.5 TeV, which is also consistent with the direct detection experiments. In contrast, for the Y=2 model, although dark matter with its mass around 2.8 TeV is allowed by WMAP, it is excluded by the direct detection experiments because the spin-independent cross section is enhanced by the Z-mediated tree-level scattering process.

  3. TRIO (Triplet Ionospheric Observatory) Mission

    Science.gov (United States)

    Lee, D.; Seon, J.; Jin, H.; Kim, K.; Lee, J.; Jang, M.; Pak, S.; Kim, K.; Lin, R. P.; Parks, G. K.; Halekas, J. S.; Larson, D. E.; Eastwood, J. P.; Roelof, E. C.; Horbury, T. S.

    2009-12-01

    Triplets of identical cubesats will be built to carry out the following scientific objectives: i) multi-observations of ionospheric ENA (Energetic Neutral Atom) imaging, ii) ionospheric signature of suprathermal electrons and ions associated with auroral acceleration as well as electron microbursts, and iii) complementary measurements of magnetic fields for particle data. Each satellite, a cubesat for ion, neutral, electron, and magnetic fields (CINEMA), is equipped with a suprathermal electron, ion, neutral (STEIN) instrument and a 3-axis magnetometer of magnetoresistive sensors. TRIO is developed by three institutes: i) two CINEMA by Kyung Hee University (KHU) under the WCU program, ii) one CINEMA by UC Berkeley under the NSF support, and iii) three magnetometers by Imperial College, respectively. Multi-spacecraft observations in the STEIN instruments will provide i) stereo ENA imaging with a wide angle in local times, which are sensitive to the evolution of ring current phase space distributions, ii) suprathermal electron measurements with narrow spacings, which reveal the differential signature of accelerated electrons driven by Alfven waves and/or double layer formation in the ionosphere between the acceleration region and the aurora, and iii) suprathermal ion precipitation when the storm-time ring current appears. In addition, multi-spacecraft magnetic field measurements in low earth orbits will allow the tracking of the phase fronts of ULF waves, FTEs, and quasi-periodic reconnection events between ground-based magnetometer data and upstream satellite data.

  4. Helium-like triplet diagnostics

    CERN Document Server

    Dubau, J; Dubau, Jacques; Porquet, Delphine

    2002-01-01

    The 1s2-1s2l lines are the most intense He-like ions lines. They are used as spectroscopic diagnostics for solar active regions as well as for different laboratory plasmas. Nowadays, it exits very high spectral resolution instruments and, for intense X-ray sources, one can do spectroscopic diagnostics from line ratios. With XMM (RGS) and Chandra (LETGS, HETGS) spectral resolutions and for several atomic elements, it is particularly possible to separate a 3 blended line set, the so-called He-like triplet: Resonance (r), Intercombination (i) and Forbidden (f), which are dominated respectively by lines issued from the following levels : 1s2p 1P1, 1s2p 3P1,2 and 1s2s 3S1. We shall show that the measurement of two different ratios between these 3 lines (R = f/i and G = (f + i)/r) give quantitative informations on the nature of the emitting plasma (photo-ionized or collisional) and on its electronic density and temperature. A more refined analysis must also include satellite line contributions.

  5. New Algorithms on Rooted Triplet Consistency

    OpenAIRE

    Tazehkand, Soheil Jahangiri; Hashemi, Seyed Naser; Poormohammadi, Hadi

    2012-01-01

    An evolutionary tree (phylogenetic tree) is a binary, rooted, unordered tree that models the evolutionary history of currently living species in which leaves are labeled by species. In this paper, we investigate the problem of finding the maximum consensus evolutionary tree from a set of given rooted triplets. A rooted triplet is a phylogenetic tree on three leaves and shows the evolutionary relationship of the corresponding three species. The mentioned problem is known to be APX-hard. We pre...

  6. Spectroscopy

    DEFF Research Database (Denmark)

    Berg, Rolf W.

    This introductory booklet covers the basics of molecular spectroscopy, infrared and Raman methods, instrumental considerations, symmetry analysis of molecules, group theory and selection rules, as well as assignments of fundamental vibrational modes in molecules.......This introductory booklet covers the basics of molecular spectroscopy, infrared and Raman methods, instrumental considerations, symmetry analysis of molecules, group theory and selection rules, as well as assignments of fundamental vibrational modes in molecules....

  7. Chemically induced dynamic electron polarization investigation of the triplet-radical system in the solution of the triplet quencher

    Institute of Scientific and Technical Information of China (English)

    LU, Tong-Xing; CUI, Zhi-Feng; XU, Xin-Sheng; ZHANG, Xian-Yi

    2000-01-01

    The chemically induced dynamic electron polariztiion (CIDEP) of the triplet molecule/triplet quencher/2,2,6,6-te tranethyl-1-piperidinyioxyl (TEMPO) systems were measured using the high time-resolved FESR spectrometer. The competi tion between the radical-triplet pair mechanism (RTPM) and triplet mechanism (TM) or radical pair mechanism (RPM) polarization in the solution of the triplet quencher was investi gated, and the relationship between reaction rate of the radi cal-triplet pair and quenching rate of triplet was deduced.

  8. Hyperfine structure constants of the CaII states 4s2S1/2 and 4p2P1/2,3/2 and the nuclear quadrupole moment of 43Ca

    International Nuclear Information System (INIS)

    The hyperfine structure splittings of the 4s2S1/2→4p2P1/2,3/2 transitions in 43CaII have been measured by fast ion beam collinear laser spectroscopy. The resonant laser interaction was observed using non-optical detection based on optical ground state depopulation pumping, state selective neutralization and charge state separated particle counting. The extracted magnetic dipole hyperfine structure constants for 43Ca A(2S1/2)=-805(2) MHz, A(2P1/2)=-145.5(1.0) MHz and A(2P3/2)=-31.9(0.2) MHz are in excellent agreement with relativistic many body perturbation theory predictions available for this alkali-like ion. The combined results are used to evaluate the semi-empirical analysis method. From the electrical quadrupole hyperfine structure constant B(2P3/2)=-6.7(1.4) MHz and the calculated B/Q value for this one valance electron configuration, the nuclear quadrupole moment Q(43Ca)=-0.043(9)b is derived. This result supports a previous evaluation based on the hyperfine structure of the two valence electron 3P configurations of CaI. (orig.)

  9. Triplet excited state spectra and dynamics of carotenoids from the thermophilic purple photosynthetic bacterium Thermochromatium tepidum

    Energy Technology Data Exchange (ETDEWEB)

    Niedzwiedzki, Dariusz; Kobayashi, Masayuki; Blankenship, R. E.

    2011-01-13

    Light-harvesting complex 2 from the anoxygenic phototrophic purple bacterium Thermochromatium tepidum was purified and studied by steady-state absorption, fluorescence and flash photolysis spectroscopy. Steady-state absorption and fluorescence measurements show that carotenoids play a negligible role as supportive energy donors and transfer excitation to bacteriochlorophyll-a with low energy transfer efficiency of ~30%. HPLC analysis determined that the dominant carotenoids in the complex are rhodopin and spirilloxanthin. Carotenoid excited triplet state formation upon direct (carotenoid) or indirect (bacteriochlorophyll-a Q{sub x} band) excitation shows that carotenoid triplets are mostly localized on spirilloxanthin. In addition, no triplet excitation transfer between carotenoids was observed. Such specific carotenoid composition and spectroscopic results strongly suggest that this organism optimized carotenoid composition in the light-harvesting complex 2 in order to maximize photoprotective capabilities of carotenoids but subsequently drastically suppressed their supporting role in light-harvesting process.

  10. Colored triplets with integral quantum numbers

    International Nuclear Information System (INIS)

    The systematics of low-lying hadron spectra and the relations between mass, cross-section and magnetic moment in terms of ''constituent'' quarks on one hand, and abstraction of the properties of hadronic weak and electromagnetic current in terms of ''current'' quarks on the other hand have been extremely useful. In the category of three triplet models, there are several versions with the varying degree of similarity and difference among them. These include; (1) the paraquarks of order three, (2) the three triplets with SU(3)' x SU(3)'' symmetry, (3) SUB version by Cabibbo et al., and (4) perfect ''color'' symmetry by Gell-Mann. The physical difference among these various versions of the three triplet models and their consequence are discussed with respect to some of the current theoretical and experimental topics. (Iwase, T.)

  11. Spin accumulation in triplet Josephson junction

    International Nuclear Information System (INIS)

    We employ a Hamiltonian method to study the equal-spin pairing triplet Josephson junction with different orbital symmetries of pair potentials. Both the spin/charge supercurrent and possible spin accumulation at the interface of the junction are analyzed by means of the Keldysh Green's function. It is found that a spontaneous angle-resolved spin accumulation can form at the junction's interface when the orbital symmetries of Cooper pairs in two triplet superconductors are different, the physical origin is the combined effect of the different orbital symmetries and different spin states of Cooper pairs due to the misalignment of two d vectors in triplet leads. An abrupt current reversal effect induced by misalignment of d vectors is observed and can survive in a strong interface barrier scattering because the zero-energy state appears at the interface of the junction. These properties of the p-wave Josephson junction may be helpful for identifying the order parameter symmetry.

  12. Triplet correlation functions in liquid water

    Energy Technology Data Exchange (ETDEWEB)

    Dhabal, Debdas; Chakravarty, Charusita, E-mail: charus@chemistry.iitd.ac.in [Department of Chemistry, Indian Institute of Technology-Delhi, New Delhi 110016 (India); Singh, Murari [School of Physical Sciences, Jawaharlal Nehru University, New Delhi 110067 (India); Wikfeldt, Kjartan Thor [Science Institute, University of Iceland, 107 Reykjavik (Iceland)

    2014-11-07

    Triplet correlations have been shown to play a crucial role in the transformation of simple liquids to anomalous tetrahedral fluids [M. Singh, D. Dhabal, A. H. Nguyen, V. Molinero, and C. Chakravarty, Phys. Rev. Lett. 112, 147801 (2014)]. Here we examine triplet correlation functions for water, arguably the most important tetrahedral liquid, under ambient conditions, using configurational ensembles derived from molecular dynamics (MD) simulations and reverse Monte Carlo (RMC) datasets fitted to experimental scattering data. Four different RMC data sets with widely varying hydrogen-bond topologies fitted to neutron and x-ray scattering data are considered [K. T. Wikfeldt, M. Leetmaa, M. P. Ljungberg, A. Nilsson, and L. G. M. Pettersson, J. Phys. Chem. B 113, 6246 (2009)]. Molecular dynamics simulations are performed for two rigid-body effective pair potentials (SPC/E and TIP4P/2005) and the monatomic water (mW) model. Triplet correlation functions are compared with other structural measures for tetrahedrality, such as the O–O–O angular distribution function and the local tetrahedral order distributions. In contrast to the pair correlation functions, which are identical for all the RMC ensembles, the O–O–O triplet correlation function can discriminate between ensembles with different degrees of tetrahedral network formation with the maximally symmetric, tetrahedral SYM dataset displaying distinct signatures of tetrahedrality similar to those obtained from atomistic simulations of the SPC/E model. Triplet correlations from the RMC datasets conform closely to the Kirkwood superposition approximation, while those from MD simulations show deviations within the first two neighbour shells. The possibilities for experimental estimation of triplet correlations of water and other tetrahedral liquids are discussed.

  13. Spontaneous Triplets Carried in a Uterus Didelphys

    OpenAIRE

    Jessica R. Jackson; Brittney Williams; James Thorp

    2014-01-01

    Background: Spontaneous triplets in a uterus didelphys are an extremely rare finding. Only four other cases are reported in the literature. Case: A 24 year old gravida 3 para 2-0-0-2 conceived spontaneous triplets in a uterine didelphys. She developed cervical insufficiency and underwent cerclage placement at 17 weeks. After spontaneous rupture of membranes at 29 weeks gestation, she underwent repeat cesarean section, with delivery of three viable fetuses. Mother and all three babies are c...

  14. Ultrabright fluorescent OLEDS using triplet sinks

    Science.gov (United States)

    Zhang, Yifan; Forrest, Stephen R; Thompson, Mark

    2013-06-04

    A first device is provided. The first device further comprises an organic light emitting device. The organic light emitting device further comprises an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer further comprises an organic host compound, an organic emitting compound capable of fluorescent emission at room temperature, and an organic dopant compound. The triplet energy of the dopant compound is lower than the triplet energy of the host compound. The dopant compound does not strongly absorb the fluorescent emission of the emitting compound.

  15. Ultrafast electronic and vibrational dynamics in brominated aluminum corroles: Energy relaxation and triplet formation

    Directory of Open Access Journals (Sweden)

    T. Stensitzki

    2016-07-01

    Full Text Available We combined femtosecond (fs VIS pump–IR probe spectroscopy with fs VIS pump–supercontinuum probe spectroscopy to characterize the photoreaction of the hexacoordinated Al(tpfc-Br8(py2 in a comprehensive way. Upon fs excitation at ∼400 nm in the Soret band, the excitation energy relaxes with a time constant of (250 ± 80 fs to the S2 and S1 electronic excited states. This is evident from the rise time of the stimulated emission signal in the visible spectral range. On the same time scale, narrowing of broad infrared signals in the C=C stretching region around 1500 cm−1 is observed. Energy redistribution processes are visible in the vibrational and electronic dynamics with time constants between ∼2 ps and ∼20 ps. Triplet formation is detected with a time constant of (95 ± 3 ps. This is tracked by the complete loss of stimulated emission. Electronic transition of the emerging triplet absorption band overlaps considerably with the singlet excited state absorption. In contrast, two well separated vibrational marker bands for triplet formation were identified at 1477 cm−1 and at 1508 cm−1. These marker bands allow a precise identification of triplet dynamics in corrole systems.

  16. Ultrafast electronic and vibrational dynamics in brominated aluminum corroles: Energy relaxation and triplet formation.

    Science.gov (United States)

    Stensitzki, T; Yang, Y; Berg, A; Mahammed, A; Gross, Z; Heyne, K

    2016-07-01

    We combined femtosecond (fs) VIS pump-IR probe spectroscopy with fs VIS pump-supercontinuum probe spectroscopy to characterize the photoreaction of the hexacoordinated Al(tpfc-Br8)(py)2 in a comprehensive way. Upon fs excitation at ∼400 nm in the Soret band, the excitation energy relaxes with a time constant of (250 ± 80) fs to the S2 and S1 electronic excited states. This is evident from the rise time of the stimulated emission signal in the visible spectral range. On the same time scale, narrowing of broad infrared signals in the C=C stretching region around 1500 cm(-1) is observed. Energy redistribution processes are visible in the vibrational and electronic dynamics with time constants between ∼2 ps and ∼20 ps. Triplet formation is detected with a time constant of (95 ± 3) ps. This is tracked by the complete loss of stimulated emission. Electronic transition of the emerging triplet absorption band overlaps considerably with the singlet excited state absorption. In contrast, two well separated vibrational marker bands for triplet formation were identified at 1477 cm(-1) and at 1508 cm(-1). These marker bands allow a precise identification of triplet dynamics in corrole systems. PMID:27226980

  17. Birth weight in a large series of triplets

    Directory of Open Access Journals (Sweden)

    van Beijsterveldt Catharina EM

    2011-04-01

    Full Text Available Abstract Background Triplets are often born premature and with a low birth weight. Because the incidence of triplet births is rare, there are relatively few studies describing triplet birth weight characteristics. Earlier studies are often characterized by small sample sizes and lack information on important background variables such as zygosity. The objective of this study is to examine factors associated with birth weight in a large, population-based sample of triplets registered with the Netherlands Twin Register (NTR. Methods In a sample of 1230 triplets from 410 families, the effects of assisted reproductive techniques, zygosity, birth order, gestational age, sex, maternal smoking and alcohol consumption during pregnancy on birth weight were assessed. The resemblance among triplets for birth weight was estimated as a function of zygosity. Birth weight discordance within families was studied by the pair-wise difference between triplets, expressed as a percentage of the birth weight of the heaviest child. We compare data from triplets registered with the NTR with data from population records, which include live births, stillbirths and children that have deceased within days after birth. Results There was no effect of assisted reproductive techniques on triplet birth weight. At gestational age 24 to 40 weeks triplets gained on average 130 grams per week; boys weighed 110 grams more than girls and triplets of smoking mothers weighted 104 grams less than children of non-smoking mothers. Monozygotic triplets had lower birth weights than di- and trizygotic triplets and birth weight discordance was smaller in monozygotic triplets than in di- and trizygotic triplets. The correlation in birth weight among monozygotic and dizygotic triplets was 0.42 and 0.32, respectively. In nearly two-thirds of the families, the heaviest and the lightest triplet had a birth weight discordance over 15%. The NTR sample is representative for the Dutch triplet

  18. Birth weight in a large series of triplets

    OpenAIRE

    van Beijsterveldt Catharina EM; Middeldorp Christel M; Lamb Diane J; Vink Jacqueline M; Haak Monique C; Boomsma Dorret I

    2011-01-01

    Abstract Background Triplets are often born premature and with a low birth weight. Because the incidence of triplet births is rare, there are relatively few studies describing triplet birth weight characteristics. Earlier studies are often characterized by small sample sizes and lack information on important background variables such as zygosity. The objective of this study is to examine factors associated with birth weight in a large, population-based sample of triplets registered with the N...

  19. Can the ''doublet-triplet splitting'' problem be solved without doublet-triplet splitting?

    International Nuclear Information System (INIS)

    We consider a new possible mechanism for the natural solution of the doublet-triplet splitting problem in SUSY GUTs. In contrast to the usually discussed scenarios, in our case the GUT symmetry breaking does not provide any splitting between the Higgs doublet and the triplet masses. The weak doublet and its colour triplet partner both remain light, but the triplet automatically occurs decoupled from the quark and lepton superfields and cannot induce proton decay. The advantage of the above scenarios is the absence at the GUT scale of the baryon number violating the tree level d = 5 and d = 6 operators via the colour-triple exchange. It is shown that in flipped SU(5) GUT they do not appear at any scale. In the SO(10) model, such operators can be induced after SUSY breaking but are strongly suppressed. (author). 22 refs, 2 figs

  20. Birth weight in a large series of triplets

    NARCIS (Netherlands)

    D.J. Lamb; C.M. Middeldorp; C.E.M. van Beijsterveldt; J.M. Vink; M.C. Haak; D.I. Boomsma

    2011-01-01

    Background: Triplets are often born premature and with a low birth weight. Because the incidence of triplet births is rare, there are relatively few studies describing triplet birth weight characteristics. Earlier studies are often characterized by small sample sizes and lack information on importan

  1. Spontaneous Josephson spin current in triplet superconductor/ferromagnet/triplet superconductor junctions

    International Nuclear Information System (INIS)

    This paper theoretically studies Josephson spin current through triplet superconductor/ferromagnet/triplet superconductor junctions. At the ferromagnet/superconductor interfaces, the ferromagnetic scattering potential gives rise to coupling between the Andreev bound states and lifts their spin degeneracy. These spin-split Andreev states carry the Josephson spin current through the junctions. The generated spin supercurrent can be controlled by the magnetization of a ferromagnetic thin layer and bias voltage across the junctions. (condensed matter: electronic structure, electrical, magnetic, and optical properties)

  2. Measurement of Nanomolar Dissociation Constants by Titration Calorimetry and Thermal Shift Assay – Radicicol Binding to Hsp90 and Ethoxzolamide Binding to CAII

    Directory of Open Access Journals (Sweden)

    Vilma Michailovienė

    2009-06-01

    Full Text Available The analysis of tight protein-ligand binding reactions by isothermal titration calorimetry (ITC and thermal shift assay (TSA is presented. The binding of radicicol to the N-terminal domain of human heat shock protein 90 (Hsp90aN and the binding of ethoxzolamide to human carbonic anhydrase (hCAII were too strong to be measured accurately by direct ITC titration and therefore were measured by displacement ITC and by observing the temperature-denaturation transitions of ligand-free and ligand-bound protein. Stabilization of both proteins by their ligands was profound, increasing the melting temperature by more than 10 ºC, depending on ligand concentration. Analysis of the melting temperature dependence on the protein and ligand concentrations yielded dissociation constants equal to 1 nM and 2 nM for Hsp90aN-radicicol and hCAII-ethoxzolamide, respectively. The ligand-free and ligand-bound protein fractions melt separately, and two melting transitions are observed. This phenomenon is especially pronounced when the ligand concentration is equal to about half the protein concentration. The analysis compares ITC and TSA data, accounts for two transitions and yields the ligand binding constant and the parameters of protein stability, including the Gibbs free energy and the enthalpy of unfolding.

  3. Long-Lived Triplet Excited States of Bent-Shaped Pentacene Dimers by Intramolecular Singlet Fission.

    Science.gov (United States)

    Sakuma, Takao; Sakai, Hayato; Araki, Yasuyuki; Mori, Tadashi; Wada, Takehiko; Tkachenko, Nikolai V; Hasobe, Taku

    2016-03-24

    Intramolecular singlet fission (ISF) is a promising photophysical process to construct more efficient light energy conversion systems as one excited singlet state converts into two excited triplet states. Herein we synthesized and evaluated bent-shaped pentacene dimers as a prototype of ISF to reveal intrinsic characters of triplet states (e.g., lifetimes of triplet excited states). In this study, meta-phenylene-bridged TIPS-pentacene dimer (PcD-3Ph) and 2,2'-bipheynyl bridged TIPS-pentacene dimer (PcD-Biph) were newly synthesized as bent-shaped dimers. In the steady-state spectroscopy, absorption and emission bands of these dimers were fully characterized, suggesting the appropriate degree of electronic coupling between pentacene moieties in these dimers. In addition, the electrochemical measurements were also performed to check the electronic interaction between two pentacene moieties. Whereas the successive two oxidation peaks owing to the delocalization were observed in a directly linked-pentacene dimer (PcD) by a single bond, the cyclic voltammograms in PcD-Biph and PcD-3Ph implied the weaker interaction compared to that of p-phenylene-bridged TIPS-pentacene dimer (PcD-4Ph) and PcD. The femtosecond and nanosecond transient absorption spectra clearly revealed the slower ISF process in bent-shaped pentacene dimers (PcD-Biph and PcD-3Ph), more notably, the slower relaxation of the excited triplet states in PcD-Biph and PcD-3Ph. Namely, the quantum yields of triplet states (ΦT) by ISF approximately remain constant (ca. 180-200%) in all dimer systems, whereas the lifetimes of the triplet excited states became much longer (up to 360 ns) in PcD-Biph as compared to PcD-4Ph (15 ns). Additionally, the lifetimes of the corresponding triplet states in PcD-Biph and PcD-3Ph were sufficiently affected by solvent viscosity. In particular, the lifetimes of PcD-Biph triplet state in THF/paraffin (1.0 μs) increased up to approximately three times as compared to that in THF

  4. Synthesis and Exciton Dynamics of Triplet Sensitized Conjugated Polymers

    KAUST Repository

    Andernach, Rolf

    2015-07-22

    We report the synthesis of a novel polythiophene-based host-guest copolymer incorporating a Pt-porphyrin complex (TTP-Pt) into the backbone for efficient singlet to triplet polymer exciton sensitization. We elucidated the exciton dynamics in thin films of the material by means of Transient Absorption Spectrosopcy (TAS) on multiple timescales and investigated the mechanism of triplet exciton formation. During sensitization, single exciton diffusion is followed by exciton transfer from the polymer backbone to the complex where it undergoes intersystem crossing to the triplet state of the complex. We directly monitored the triplet exciton back transfer from the Pt-porphyrin to the polymer and find that 60% of the complex triplet excitons are transferred with a time constant of 1087 ps. We propose an equilibrium between polymer and porphyrin triplet states as a result of the low triplet diffusion length in the polymer backbone and hence an increased local triplet population resulting in increased triplet-triplet annihilation. This novel system has significant implications for the design of novel materials for triplet sensitized solar cells and up-conversion layers.

  5. Nonextensive triplet in geological faults system

    CERN Document Server

    de Freitas, D B; Scheerer, T M; Vilar, C S; Silva, R

    2013-01-01

    The San Andreas fault (SAF) in the USA is one of the most investigated self-organizing systems in nature. In this paper, we studied some geophysical properties of the SAF system in order to analyze the behavior of earthquakes in the context of Tsallis's $q$--Triplet. To that end, we considered 134,573 earthquake events in magnitude interval $2\\leq m<8$, taken from the Southern Earthquake Data Center (SCEDC, 1932 - 2012). The values obtained ("$q$--Triplet"$\\equiv$$\\{$$q$$_{stat}$,$q$$_{sen}$,$q$$_{rel}$$\\}$) reveal that the $q_{stat}$--Gaussian behavior of the aforementioned data exhibit long-range temporal correlations. Moreover, $q_{sen}$ exhibits quasi-monofractal behavior with a Hurst exponent of 0.87.

  6. Triplet Higgs boson at hadron colliders

    International Nuclear Information System (INIS)

    The novel feature of a Higgs-triplet representation is a nonzero tree-level coupling of H+W-Z, which is absent in all Higgs-doublet models. We study the associated production of a singly-charged Higgs boson of the Higgs-triplet representation with a W or Z boson at hadron colliders, followed by the H+→W+Z decay. We find that the 2l+4j final state gives an interesting level of signal with a negligible background, plus it allows a full mass reconstruction of the charged-Higgs boson. The cover range of the charged-Higgs mass is between 110 and 200 GeV. (author)

  7. Electrochemical detection of DNA triplet repeat expansion

    Czech Academy of Sciences Publication Activity Database

    Fojta, Miroslav; Havran, Luděk; Vojtíšková, Marie; Paleček, Emil

    2004-01-01

    Roč. 126, č. 21 (2004), s. 6532-6533. ISSN 0002-7863 R&D Projects: GA AV ČR IAA4004402; GA AV ČR IBS5004355; GA AV ČR KJB4004302; GA AV ČR KSK4055109 Institutional research plan: CEZ:AV0Z5004920 Keywords : DNA triplet repeat expansion * PCR amplification * neurodegenerative diseases Subject RIV: BO - Biophysics Impact factor: 6.903, year: 2004

  8. Beam dynamics in magnetic quadrupole triplets

    International Nuclear Information System (INIS)

    The Frankfurt Neutron source at the Stern-Gerlach-Zentrum (FRANZ) will produce high intensity neutron pulses in the energy range of 1 to 500 keV at a very short repetition rate. The neutrons are gained from 7Li(p,n)7Be reactions induced by 2 MeV protons and will be used to examine the nucleosynthesis during the s-process as it occurs in stars, cross sections of neutron capture reactions as well as the behaviour of non-neutral plasmas. In the linear accelerator section, consisting of a 4-rod-radio-frequency-quadrupole and a H-type drift tube linac, the proton pulses are accelerated to 2.03 MeV. Inside the drift tube cavity a magnetic quadrupole triplet will be integrated, in order to compensate transversally defocussing effects and therefore avoid losses. Behind the linear accelerator section the proton beam ist rebunched in a 5-cell CH-rebuncher which is framed by two more quadrupole triplets. To investigate the beam dynamics inside the magnetic quadrupole triplets, various magnetostatic and particle tracking codes like CST Studio and LORASR were used to simulate the beam transport properties of the magnets and compare the individual magnetic field distributions with the ones measured at the magnet laboratory at GSI. In doing so, important aspects to be considered are the longitudinal and transversal fringe fields and the saturation effects which all possibly cause emittance growth and geometrical aberrations.

  9. Beam dynamics in magnetic quadrupole triplets

    Energy Technology Data Exchange (ETDEWEB)

    Claessens, Christine; Heilmann, Manuel; Meusel, Oliver; Podlech, Holger; Ratzinger, Ulrich; Wiesner, Christoph [IAP, Frankfurt University, Frankfurt am Main (Germany)

    2013-07-01

    The Frankfurt Neutron source at the Stern-Gerlach-Zentrum (FRANZ) will produce high intensity neutron pulses in the energy range of 1 to 500 keV at a very short repetition rate. The neutrons are gained from {sup 7}Li(p,n){sup 7}Be reactions induced by 2 MeV protons and will be used to examine the nucleosynthesis during the s-process as it occurs in stars, cross sections of neutron capture reactions as well as the behaviour of non-neutral plasmas. In the linear accelerator section, consisting of a 4-rod-radio-frequency-quadrupole and a H-type drift tube linac, the proton pulses are accelerated to 2.03 MeV. Inside the drift tube cavity a magnetic quadrupole triplet will be integrated, in order to compensate transversally defocussing effects and therefore avoid losses. Behind the linear accelerator section the proton beam ist rebunched in a 5-cell CH-rebuncher which is framed by two more quadrupole triplets. To investigate the beam dynamics inside the magnetic quadrupole triplets, various magnetostatic and particle tracking codes like CST Studio and LORASR were used to simulate the beam transport properties of the magnets and compare the individual magnetic field distributions with the ones measured at the magnet laboratory at GSI. In doing so, important aspects to be considered are the longitudinal and transversal fringe fields and the saturation effects which all possibly cause emittance growth and geometrical aberrations.

  10. Intra-Inter Triplet Object Interaction Mechanism in Triplet-Based Hierarchical Interconnection Network

    Directory of Open Access Journals (Sweden)

    Shahnawaz Talpur

    2013-07-01

    Full Text Available Object oriented languages usually avoid direct message passing, due to its complicated implementation, though that is the promising way to communicate in concurrently inherited objects. With the advancement in the high performance computing system, interaction between parallel application objects onto physical cores becomes one of the significant issues, which is not fully explored yet. In object oriented programming attribute data is included in objects and their state can be changed using the methods. Objects enable massage passing to other objects interacting with each other. Comprehensive problems can be molded by object-oriented methodology, and solves difficult program running object-oriented programs.Cores communicate with each other through communicator and groups in MPI, but in our reference architecture TBHIN (Triplet Based Hierarchical Interconnection Network, the cores are already faction in Triplets. We propose IITOIM Model to improve the performance with efficient intra-inter triplet cores communication mechanism between the objects in TBHIN

  11. T.C.G triplet in an antiparallel purine.purine.pyrimidine DNA triplex. Conformational studies by NMR.

    Science.gov (United States)

    Dittrich, K; Gu, J; Tinder, R; Hogan, M; Gao, X

    1994-04-12

    The antiparallel purine.purine.pyrimidine DNA triplex, RRY6, which contains a T.C.G inverted triplet in the center of the sequence, was examined by proton and phosphorous two-dimensional NMR spectroscopy. The local conformation of the T.C.G triplet (T4.C11.G18) and the effect of this triplet on the global helical structure were analyzed in detail. The formation of the T.C.G triplet is confirmed by a set of cross-strand NOEs, including unusual cross-strand NOEs between the third strand and the pyrimidine strand as opposed to the purine strand of the duplex. NMR data suggest that the T.C.G triplet may be present in an equilibrium between a non-hydrogen-bonded form and a T(O4)-C(NH2) hydrogen-bonded form and that there is a distortion of the in-plane alignment of the three bases. The flanking G.G.C base triplets are well-defined on the 5'-side of T4, but somewhat interrupted on the 3'-side of T4. The effect of the third strand binding on the Watson-Crick duplex was probed by an NMR study of the free duplex RY6. NMR parameters are affected mostly around the T.C.G inversion site. The perturbations extend to at least two adjacent base triplets on either side. The binding of the third purine strand and the accommodation of a central T.C.G inversion in RRY6 does not require a readjustment in sugar pucker, which remains in the range of C2'-endo. 31P resonances of RRY6 distribute over a range of 2.2 ppm. The H-P coupling patterns of the third strand differ from those of the duplex. General spectral patterns defined by the marker protons of the RRY and YRY triplexes are compared. PMID:8155628

  12. Lepton Flavor Violation in the singlet-triplet scotogenic model

    OpenAIRE

    Rocha-Moran, Paulina; Vicente, Avelino

    2016-01-01

    We investigate lepton flavor violation (LFV) in the the singlet-triplet scotogenic model in which neutrinos acquire non-zero masses at the 1-loop level. In contrast to the most popular variant of this setup, the singlet scotogenic model, this version includes a triplet fermion as well as a triplet scalar, leading to a scenario with a richer dark matter phenomenology. Taking into account results from neutrino oscillation experiments, we explore some aspects of the LFV phenomenology of the mode...

  13. Ca(II, Zn(II and Au(III sulfamethoxazole sulfa-drug complexes: Synthesis, spectroscopic and anticancer evaluation studies

    Directory of Open Access Journals (Sweden)

    Fatima A.I. Al-Khodir

    2015-09-01

    Full Text Available Herein in this article, three new Ca(II, Zn(II and Au(III complexes of sulfamethoxazole (SZ (sulfa-drug have been synthesized for the first time. The sulfa-drugs have a great attentions because of their therapeutic applications against bacterial infections. The SZ complexes were discussed with the help of elemental analyses, molar conductance and spectroscopic instruments e.g. IR, 1H-NMR, and electronic spectra. Investigations of the infrared spectra of the SZ and their metal complexes indicated the vibrations due to the sulfonamido (SO2 and –NH and isoxazole (C=N groups are shifted with respect to the free molecule in line with their coordination to the metal. In case of calcium(II an zinc(II complexes, the coordination site of SZ are the sulfonyl oxygen and SO2-NH sulfonamide nitrogen, but in gold(III complex, the gold metal ions coordinates through the sulfonyl oxygen and isoxazole nitrogen. These complexes are formulated as: [Ca(SZ(Cl2].8H2O (1, [Zn(SZ(Cl2].2H2O (2 and [Au(SZ(Cl2].Cl (3. The molar conductance data reveals that both Ca(II and Zn(II complexes are non-electrolyte but gold(III complex is electrolyte. The morphological nano structures of SZ complexes were checked using X-ray powder diffraction (XRD, scanning electron microscope (SEM and transmission electron microscopy (TEM. The gold(III complex was recorded good anticancer behavior against Human colon carcinoma (HCT-116 cells and human hepatocellular carcinoma (HepG-2 cells.

  14. Powering the High-Luminosity Triplets

    CERN Document Server

    Ballarino, A

    2015-01-01

    The powering of the magnets in the LHC High-Luminosity Triplets requires production and transfer of more than 150 kA of DC current. High precision power converters will be adopted, and novel High Temperature Superconducting (HTS) current leads and MgB2 based transfer lines will provide the electrical link between the power converters and the magnets. This chapter gives an overview of the systems conceived in the framework of the LHC High-Luminosity upgrade for feeding the superconducting magnet circuits. The focus is on requirements, challenges and novel developments.

  15. Structural basis for triplet repeat disorders

    DEFF Research Database (Denmark)

    Baldi, Pierre; Brunak, Søren; Chauvin, Yves; Pedersen, Anders Gorm

    1999-01-01

    ? Results: Using several different computational models of DNA structure, we show that the triplets involved in the pathological repeats generally fall into extreme classes. Thus, CAG/CTG repeats are particularly flexible, whereas GCC, CGG and GAA repeats appear to display both flexible and rigid (but...... curved) characteristics depending on the method of analysis. The fact that (1) trinucleotide repents often become increasingly unstable when they exceed a length of approximately 50 repeats, and (2) repented 12-mers display a similar increase in instability above 13 repeats, together suggest that......, which we predict to have very high flexibility, may play a role in the pathogenesis of the neurodegenerative disorder multiple system atrophy (MSA)....

  16. A new medium for triplet-triplet annihilated upconversion and photocatalytic application.

    Science.gov (United States)

    Ye, Changqing; Wang, Jingjing; Wang, Xiaomei; Ding, Ping; Liang, Zuoqin; Tao, Xutang

    2016-02-01

    Since the triplet-triplet annihilated upconversion (TTA-UC) materials work efficiently only in degassing organic solvents, it is of significance to find a new medium without toxicity and volatility and that promotes TTA-UC. Here, we firstly reported the effect of an OH-containing medium on low power upconversion and found that in alcohol solvent containing β-cyclodextrin (β-CD), the phosphorescence lifetime (τp) of the sensitizer (PdTPP) and the fluorescence quantum yield (Φf) of the acceptor (DPA) were enhanced with the increase in the number of OH-groups of the medium. A large triplet-triplet quenching constant (kq, 1.91 × 10(9) M(-1) s(-1)) and high upconversion efficiency (ΦUC, ∼ 36%) of PdTPP/DPA were obtained under the excitation of a diode laser (532 nm, 60 mW cm(-2)). Under our green-to-blue upconversion irradiation, in a demonstration experiment the photocurrent was recorded at 0.09 μA cm(-2), resulting from photocatalytic water splitting by a Cd0.7Zn0.3S photoanode and a Pt counter-electrode in a photoelectrochemical cell. The importance of this study suggests that upconversion-powered photoelectrochemistry possesses potential application for hydrogen generation from water under excitation of sun energy. PMID:26580451

  17. Triplet-Triplet Annihilation Photon Upconversion in Polymer Thin Film: Sensitizer Design.

    Science.gov (United States)

    Jiang, Xinpeng; Guo, Xinyan; Peng, Jiang; Zhao, Dahui; Ma, Yuguo

    2016-05-11

    Efficient visible-to-UV photon upconversion via triplet-triplet annihilation (TTA) is accomplished in polyurethane (PU) films by developing new, powerful photosensitizers fully functional in the solid-state matrix. These rationally designed triplet sensitizers feature a bichromophoric scaffold comprising a tris-cyclometalated iridium(III) complex covalently tethered to a suitable organic small molecule. The very rapid intramolecular triplet energy transfer from the former to the latter is pivotal for achieving the potent sensitizing ability, because this process out-competes the radiative and nonradiative decays inherent to the metal complex and produces long-lived triplet excitons localized with the acceptor moiety readily available for intermolecular transfer and TTA. Nonetheless, compared to the solution state, the molecular diffusion is greatly limited in solid matrices, which even creates difficulty for the Dexter-type intramolecular energy transfer. This is proven by the experimental results showing that the sensitizing performance of the bichromophoric molecules strongly depends on the spatial distance separating the donor (D) and acceptor (A) units and that incorporating a longer linker between the D and A evidently curbs the TTA upconversion efficiency in PU films. Using a rationally optimized sensitizer structure in combination with 2,7-di-tert-butylpyrene as the annihilator/emitter, the doped polyurethane (PU) films demonstrate effective visible-to-UV upconverted emission signal under noncoherent-light irradiation, attaining an upconversion quantum yield of 2.6%. Such quantum efficiency is the highest value so far reported for the visible-to-UV TTA systems in solid matrices. PMID:27082767

  18. The superconducting spin valve and triplet superconductivity

    Energy Technology Data Exchange (ETDEWEB)

    Garifullin, I.A., E-mail: ilgiz_garifullin@yahoo.com [Zavoisky Physical-Technical Institute, Kazan Scientific Center of Russian Academy of Sciences, 420029 Kazan (Russian Federation); Leksin, P.V.; Garif' yanov, N.N.; Kamashev, A.A. [Zavoisky Physical-Technical Institute, Kazan Scientific Center of Russian Academy of Sciences, 420029 Kazan (Russian Federation); Fominov, Ya.V. [L. D. Landau Institute for Theoretical Physics RAS, 119334 Moscow (Russian Federation); Moscow Institute of Physics and Technology, 141700 Dolgoprudny (Russian Federation); Schumann, J.; Krupskaya, Y.; Kataev, V.; Schmidt, O.G. [Leibniz Institute for Solid State and Materials Research IFW Dresden, D-01171 Dresden (Germany); Büchner, B. [Leibniz Institute for Solid State and Materials Research IFW Dresden, D-01171 Dresden (Germany); Institut für Festkörperphysik, Technische Universität Dresden, D-01062 Dresden (Germany)

    2015-01-01

    A review of our recent results on the spin valve effect is presented. We have used a theoretically proposed spin switch design F1/F2/S comprising a ferromagnetic bilayer (F1/F2) as a ferromagnetic component, and an ordinary superconductor (S) as the second interface component. Based on it we have prepared and studied in detail a set of multilayers CoO{sub x}/Fe1/Cu/Fe2/S (S=In or Pb). In these heterostructures we have realized for the first time a full spin switch effect for the superconducting current, have observed its sign-changing oscillating behavior as a function of the Fe2-layer thickness and finally have obtained direct evidence for the long-range triplet superconductivity arising due to noncollinearity of the magnetizations of the Fe1 and Fe2 layers. - Highlights: • We studied a spin switch design F1/F2/S. • We prepared a set of multilayers CoOx/Fe1/Cu/Fe2/S (S=In or Pb). • The full spin switch effect for the superconducting current was realized. • We observed its oscillating behavior as a function of the Fe2-layer thickness. • We obtained direct evidence for the long-range triplet superconductivity.

  19. Tetralogy of Fallot in monozygotic triplets

    Energy Technology Data Exchange (ETDEWEB)

    Victorica, B.E.; Kumar, A.; Zori, R.T. [Univ. of Florida, Gainesville, FL (United States)

    1994-09-01

    Tetralogy of Fallot (TOF), like most other congenital heart defects, is considered to be of multifactorial inheritance. Occasional families with multiple affected members in one or more generations above been described. A stronger genetic influence in the causation of isolated TOF is also supported by recent demonstration of microdeletions in chromosome 22q11 region. Deletions in this region are also responsible for DiGeorge and velocardiofacial syndrome as well as CHARGE association. We report a set of monozygotic triplets born to healthy parents at 35 weeks of gestation. There was no family history of congenital heart defects. All three had TOF with left aortic arch (documented by cardiac catheterization in 2 and echocardiography in all 3). The degree of right ventricular outflow obstruction varied from mild to complete atresia needing prostaglandin infusion and a subsequent Blalock-Taussig shunt in one. No features of DiGeorge syndrome or any other congenital defects were present. High resolution chromosome analysis of peripheral blood lymphocytes of these infants revealed normal 46,XY male karyotype. Fluorescent in situ hybridization (FISH) using probe D22S75, which maps to chromosome 22q11.2 did not detect any deletion. This pedigree suggests a de novo mutation causing TOF in all 3 monozygotic triplets. Although there is no deletion demonstrable in DiGeorge critical region, a smaller deletion or mutation in this region cannot be excluded.

  20. Heavy Vector Triplets: Bridging Theory and Data

    CERN Document Server

    Pappadopulo, Duccio; Torre, Riccardo; Wulzer, Andrea

    2014-01-01

    We introduce a model-independent strategy to study narrow resonances which we apply to a heavy vector triplet of the Standard Model (SM) group for illustration. The method is based on a simplified phenomenological Lagrangian which reproduces a large class of explicit models. Firstly, this allows us to derive robust model-independent phenomenological features and, conversely, to identify the peculiarities of different explicit realizations. Secondly, limits on cross-section times BR can be converted into bounds on a few relevant parameters in a fully analytic way, allowing for an interpretation in any given explicit model. Based on the available 8 TeV LHC analyses, we derive current limits and interpret them for vector triplets arising in weakly coupled (gauge) and strongly coupled (composite) extensions of the SM. We point out that a model-independent limit setting procedure must be based on purely on-shell quantities, like a cross-section times BR. Finite width effects altering the limits can be considerably...

  1. The neonatal outcome in twin versus triplet and quadruplet pregnancies

    Directory of Open Access Journals (Sweden)

    Fatemeh Nasseri

    2009-02-01

    Full Text Available

    • BACKGROUND: To assess the risk of neonatal mortality and morbidity in twin, triplet and quadruplet pregnancies.
    • METHODS: In a retrospective study, the neonatal outcome of all twin, triplet and quadruplet gestations delivered from October 2001 to September 2006 was reviewed. The neonatal outcome of triples and quadruplets was compared with a matched group of twins for gestational age.
    • RESULTS: During a 5-year period, 511 sets of twin pregnancies, 42 sets of triplet and 5 sets of quadruplet pregnancies were studied. The mean of gestational age for twins, triplets and quadruplets were 33.92 ± 3.5 weeks, 30.92 ± 3.8 weeks and 31.60 ± 2.0 weeks, respectively, (P = 0.0001. Triplets and quadruplets weighed less than twins, (P = 0.0001. Neonatal mortality was 13.5% for twins, 26.8% for triplets and 30% for quadruplets. In vitro fertilization, use of ovulation induction agents, and cesarean delivery in the women with triplet and quadruplet were significantly higher than in those with twin pregnancies, (P = 0.0001. The mean age of mothers with triplets and quadruplets was significantly higher than with twins (P = 0.026. There was not a significant difference in respiratory and non-respiratory short outcomes between triplets, quadruplets and twins when matched for gestational age. Apgar score at 1 and 5 minutes was significantly lower in triplets and quadruplets than twins. There was no influence of birth order on neonatal mortality of triplet pregnancy. Neonatal mortality of triplet births was significantly decreased over the 5 years of the study period.
    • CONCLUSIONS: Triplets and quadruplets have a similar neonatal outcome as twins when matched for gestational age. There is no influence of birth on the neonatal mortality of triplet pregnancy. It appears that outcome is mainly dependent on gestational age.
    • KEYWORDS: Neonatal

    • Reversible Triplet Energy Transfer between Neo- Alloocimene and Anthracene

      DEFF Research Database (Denmark)

      Gorman, A. A.; Hamblett, I.; Jensen, Niels-Henrik

      1984-01-01

      The rate constants for triplet energy transfer between neo-alloocimene and anthracene have been redetermined by a combination of pulsed laser photolysi......The rate constants for triplet energy transfer between neo-alloocimene and anthracene have been redetermined by a combination of pulsed laser photolysi...

    • Regularities of Twin, Triplet and Multiplet Prime Numbers

      OpenAIRE

      Weber, H. J.

      2011-01-01

      Classifications of twin primes are established and then applied to triplets that generalize to all higher multiplets. Mersenne and Fermat twins and triplets are treated in this framework. Regular prime number multiplets are related to quadratic and cubic prime number generating polynomials.

    • Triplet-triplet absorption of 2-(2'-hydroxyphenyl) benzoxazole (HBO) in polar solvents

      Science.gov (United States)

      Yang, Guoqiang; Morlet-Savary, Fabrice; Peng, Zhaokui; Wu, Shikang; Fouassier, Jean-Pierre

      1996-07-01

      The transient TT absorption spectra of 2-(2'-hydroxyphenyl) benzoxazole (HBO) have been measured in liquid polar solvents and in polymethylthacrylate. In non-protonic polar solvents the main TT absorption is from the keto form of the compound ( 3K ∗). With a triplet sensitizer the compound just gives a TT absorption of its enol from ( 3E ∗) after triplet energy transfer from the sensitizer to HBO. The excited state intramolecular proton transfer (ESIPT) from the enol form to keto form occurs just in the singlet state. The protonic solvent can break the intramolecular hydrogen bond of HBO and decrease the ESIPT process. In solid solution both 3E ∗ and 3K ∗ can be formed and the TT absorptions were detected because of the inhibition of the rotational conformation transfer.

    • Electron, Hole, Singlet, and Triplet Energy Transfer in Photoexcited Porphyrin-Naphthalenediimide Dyads.

      Science.gov (United States)

      Yushchenko, Oleksandr; Hangarge, Rahul V; Mosquera-Vazquez, Sandra; Boshale, Sheshanath V; Vauthey, Eric

      2015-06-18

      The excited-state dynamics of two molecular dyads, consisting of zinc (1) and free-base (2) porphyrin connected via a peptide linker to a core-substituted naphthalenediimide (NDI) have been investigated using optical spectroscopy. These dyads exhibit rich photophysics because of the large number of electronic excited states below 3 eV. In the case of 1 in apolar solvents, excitation energy transfer from the vibrationally hot singlet excited porphyrin to the NDI takes place with a 500 fs time constant. Electronic energy ends up in the NDI-localized triplet state, which decays to the ground state on a microsecond timescale. In polar solvents, ground-state recovery is faster by 5 orders of magnitude because of the occurrence of charge separation followed by recombination. On the other hand, excitation energy transfer in 2 takes place in the opposite direction, namely from the NDI to the porphyrin, which then undergoes intersystem crossing to the triplet state, followed by triplet energy transfer back to the NDI. Therefore, four distinct local electronic excited states are consecutively populated after excitation of the NDI unit of 2, with the energy shuttling between the two ends of the dyad. PMID:25418961

    • Nonextensive triplet in a geological faults system

      Science.gov (United States)

      de Freitas, D. B.; França, G. S.; Scherrer, T. M.; Vilar, C. S.; Silva, R.

      2013-05-01

      The San Andreas fault (SAF) in the USA is one of the most investigated self-organizing systems in Nature. In this paper, we studied some geophysical properties of the SAF system in order to analyze the behavior of earthquakes in the context of Tsallis's q-Triplet. To this end, we considered 134573 earthquake events in the magnitude interval 2\\leq m<8 , taken from the Southern Earthquake Data Center (SCEDC, 1932-2012). The values obtained (“q-Triplet”{}\\equiv\\{q_{\\textit{stat}},q_{\\textit{sen}},q_{\\textit{rel}}\\} ) reveal that the q_{\\textit{stat}} -Gaussian behavior of the aforementioned data exhibit long-range temporal correlations. Moreover, q_{\\textit{sen}} exhibits quasi-monofractal behavior with a Hurst exponent of 0.87.

    • Bright Solid State Source of Photon Triplets

      CERN Document Server

      Khoshnegar, Milad; Predojević, Ana; Dalacu, Dan; Prilmüller, Maximilian; Lapointe, Jean; Wu, Xiaohua; Tamarat, Philippe; Lounis, Brahim; Poole, Philip; Weihs, Gregor; Majedi, Hamed

      2015-01-01

      Producing advanced quantum states of light is a priority in quantum information technologies. While remarkable progress has been made on single photons and photon pairs, multipartite correlated photon states are usually produced in purely optical systems by post-selection or cascading, with extremely low efficiency and exponentially poor scaling. Multipartite states enable improved tests of the foundations of quantum mechanics as well as implementations of complex quantum optical networks and protocols. It would be favorable to directly generate these states using solid state systems, for better scaling, simpler handling, and the promise of reversible transfer of quantum information between stationary and flying qubits. Here we use the ground states of two optically active coupled quantum dots to directly produce photon triplets. The wavefunctions of photogenerated excitons localized in these ground states are correlated via molecular hybridization and Coulomb interactions. The formation of a triexciton leads...

    • Triplet to Singleton-A Successful Outcome

      Directory of Open Access Journals (Sweden)

      Priya Varshney

      2014-07-01

      Full Text Available We are presenting a case report of triplet pregnancy in a 25 years old lady, in whom single fetal reduction was done at 10 weeks. At 29 weeks, ultrasonography showed fetal demise of second twin. Conservative management was done, after evaluating the status of second twin. Maternal and fetal monitoring was done with PT INR, Ultrasound Doppler weekly till 33 weeks when an emergency cesarean was done due to preterm labour pains. A healthy baby of 1.8 kg was born along with a macerated IUD of 500 gms. Mother and baby are healthy on follow up till date. Hence conservative management should be followed in single fetus demise in twin pregnancy with proper monitoring.

    • Magnetic chains on a triplet superconductor.

      Science.gov (United States)

      Sacramento, P D

      2015-11-11

      The topological state of a two-dimensional triplet superconductor may be changed by an appropriate addition of magnetic impurities. A ferromagnetic magnetic chain at the surface of a superconductor with spin-orbit coupling may eliminate the edge states of a finite system giving rise to localized zero modes at the edges of the chain. The coexistence/competition between the two types of zero modes is considered. The reduction of the system to an effective 1d system gives partial information on the topological properties but the study of the two sets of zero modes requires a two-dimensional treatment. Increasing the impurity density from a magnetic chain to magnetic islands leads to a finite Chern number. At half-filling small concentrations are enough to induce chiral modes. PMID:26459719

    • TRIPLET CIRCULAR HOUGH TRANSFORM FOR CIRCLE DETECTION

      Institute of Scientific and Technical Information of China (English)

      Luo Daisheng; He Xiaohai; Teng Qizhi; Tao Qingchuan

      2002-01-01

      A new method, triplet circular Hough transform, is proposed for circle detection in image processing and pattern recognition. In the method, a curve in an image is first detected.Next, a sequence of three points on the curve are selected, a sequence of parameters (a,b,r)corresponding to the three points are calculated by solving the circle equation of the curve, and two 2-D accumulators A(a,b) and R(a,b) are accumulated with 1 and r, respectively. Then the parameters {(a, b, r)} of the circles fitting the curve are determined from A(a, b) and R(a, b) by searching for the local maximum over A(a,b). Because no computation loops over center (a, b)and/or radius r are needed, the method is faster than the basic and directional gradient methods.It needs also much smaller memory for accumulation.

    • Ground state of naphthyl cation: Singlet or triplet?

      Energy Technology Data Exchange (ETDEWEB)

      Dutta, Achintya Kumar; Vaval, Nayana, E-mail: np.vaval@ncl.res.in; Pal, Sourav, E-mail: s.pal@ncl.res.in [Physical Chemistry Division, CSIR-National Chemical Laboratory, Pune 411008 (India); Manohar, Prashant U. [Department of Chemistry, BITS Pilani, Pilani Campus (India)

      2014-03-21

      We present a benchmark theoretical investigation on the electronic structure and singlet-triplet(S-T) gap of 1- and 2-naphthyl cations using the CCSD(T) method. Our calculations reveal that the ground states of both the naphthyl cations are singlet, contrary to the results obtained by DFT/B3LYP calculations reported in previous theoretical studies. However, the triplet states obtained in the two structural isomers of naphthyl cation are completely different. The triplet state in 1-naphthyl cation is (π,σ) type, whereas in 2-naphthyl cation it is (σ,σ{sup ′}) type. The S-T gaps in naphthyl cations and the relative stability ordering of the singlet and the triplet states are highly sensitive to the basis-set quality as well as level of correlation, and demand for inclusion of perturbative triples in the coupled-cluster ansatz.

    • Left-right symmetric model with SU(2)-triplet fermions

      International Nuclear Information System (INIS)

      We consider an SU(3)c x SU(2)L x SU(2)R x U(1)B-L left-right symmetric model with three Higgs scalars including an SU(2)L doublet, an SU(2)R doublet and an SU(2)L x SU(2)R bidoublet. In addition to usual SU(2)-doublet fermions, our model contains SU(2)-triplet fermions with Majorana masses. The neutral components of the left-handed triplets can contribute a canonical seesaw while the neutral components of the right-handed triplets associated with the right-handed neutrinos can contribute a double/inverse-type seesaw. Our model can be embedded into an SO(10) grand unification theory where the triplets belong to the 45=(1,3,1,0)+(1,1,3,0)+... representations.

    • Development of Q-triplets for interdigital-H linac

      International Nuclear Information System (INIS)

      In the prototype facility of the Exotic-arena at INS, unstable nuclei with a charge-to-mass ratio greater than 1/10 is accelerated from 170 to 1046 keV/u by an interdigital-H linac. IH linac consists of four tanks and three Q-triplets placed between tanks. In this type, the length of Q-triplets should be as short as possible in order to obtain a large longitudinal acceptance. The Q-triplet with high gradient and compact size was designed by 2D and 3D computer codes. A prototype model of the Q-triplet was constructed. The field measurement with a hole probe, carried out. (author)

    • Stability constraints in triplet extension of MSSM

      CERN Document Server

      Das, Moumita; Roy, Sourov

      2015-01-01

      We study the stability constraints on the parameter space of a triplet extension of MSSM. Existence of unbounded from below directions in the potential can spoil successful Electroweak (EW) symmetry breaking by making the corresponding minimum unstable, and hence the model should be free from those directions. Avoiding those directions restricts the parameter space of the model. We derive four stability constraints, of which only three independent from each other. After scanning the model's parameter space for phenomenologically viable data points, we impose the stability constraints and find that only about a quarter of the data points features a stable EW minimum. At those data points featuring stability, $\\mu$ and the up Higgs soft mass turn out to be smaller than about a TeV in absolute value, which make the mass of the lightest chargino and neutralino smaller than about 700 GeV. Two relevant phenomenological consequences of lifting the unbounded from below directions are that the lightest Higgs boson dec...

    • Pair Triplet Association Rule Generation in Streams

      Directory of Open Access Journals (Sweden)

      Manisha Thool

      2013-08-01

      Full Text Available Many applications involve the generation and analysis of a new kind of data, called stream data, where data flows in and out of an observation platform or window dynamically. Such data streams have the unique features such as huge or possibly infinite volume, dynamically changing, flowing in or out in a fixed order, allowing only one or a small number of scans. An important problem in data stream mining is that of finding frequent items in the stream. This problem finds application across several domains such as financial systems, web traffic monitoring, internet advertising, retail and e-business. This raises new issues that need to be considered when developing association rule mining technique for stream data. The Space-Saving algorithm reports both frequent and top-k elements with tight guarantees on errors. We also develop the notion of association rules in streams of elements. The Streaming-Rules algorithm is integrated with Space-Saving algorithm to report 1-1 association rules with tight guarantees on errors, using minimal space, and limited processing per element and we are using Apriori algorithm for static datasets and generation of association rules and implement Streaming-Rules algorithm for pair, triplet association rules. We compare the top- rules of static datasets with output of stream datasets and find percentage of error.

    • Deconstructing triplet nucleon-nucleon scattering

      International Nuclear Information System (INIS)

      Nucleon-nucleon scattering in spin-triplet channels is analyzed within an effective field theory where one-pion exchange is treated nonperturbatively. Justifying this requires the identification of an additional low-energy scale in the strength of that potential. Short-range interactions are organized according to the resulting power counting, in which the leading term is promoted to significantly lower order than in the usual perturbative counting. In each channel there is a critical momentum above which the waves probe the singular core of the tensor potential and the new counting is necessary. When the effects of one- and two-pion exchange have been removed using a distorted-wave Born approximation, the residual scattering in waves with L≤2 is well described by the first three terms in the new counting. In contrast, the scattering in waves with L≥3 is consistent with the perturbative counting, at least for energies up to 300 MeV. This pattern is in agreement with estimates of the critical momenta in these channels

    • Triplet Higgs Collider Phenomenology after LHC

      CERN Document Server

      Englert, Christoph; Spannowsky, Michael

      2013-01-01

      ATLAS and CMS have discovered a Standard Model Higgs-like particle. One of the main discovery channels is the Higgs decay to two photons, which, at the moment, seems to be considerably enhanced over the Standard Model expectation. Models with additional charged matter coupling to the Higgs sector can enhance or decrease the Higgs to two photons branching ratio. We take this as motivation to confront the so-called Georgi-Machacek model of Higgs triplets with the results of recent searches for a SM Higgs boson performed at the LHC. We also investigate the model in regions of the allowed parameter space relevant for a SM-like phenomenology. The Georgi-Machacek model avoids tree-level issues of the T parameter, while offering a vastly modified Higgs phenomenology compared to the Standard Model. This comes at the price of introducing another fine-tuning problem related to electroweak precision measurements. We investigate the collider phenomenology of the Georgi-Machacek model in the light of existing collider con...

    • Triplet Pairing in pure neutron matter

      CERN Document Server

      Srinivas, Sarath

      2016-01-01

      We study the zero temperature BCS gaps for the triplet channel in pure neutron matter using Similarity Renormalization Group (SRG) evolved interactions. We use the dependence of the results on the SRG resolution scale, as a tool to analyze medium and many-body corrections. In particular, we study the effects of including the three-body interactions at leading order, which appear at N2LO in the Chiral EFT, as well as that of the first-order self-energy corrections on the zero temperature gap. In addition we also extract the transition temperature as a function of densities and verify the BCS scaling of the zero temperature gaps to the transition temperature. We observe that the self-energy effects are very crucial in order to reduce the SRG resolution scale dependence of the results, while the three-body effects at the leading order do not change the two-body resolution scale dependence. On the other hand, the results depend strongly on the three-body cut-off, emphasizing the importance of the missing higher-o...

    • TRIPLET CIRCULAR HOUGH TRANSFORM FOR CIRCLE DETECTION

      Institute of Scientific and Technical Information of China (English)

      LuoDaisheng; HeXiaohai; 等

      2002-01-01

      A new method,triplet circular Hough transform,is proposed for circle detection in image processing and pattern recognition.In the method,a curve in an image is first detected.Next,a sequence of three points on the curve are selected.a sequence of parameters(a,b,r)corresponding to the three points are calculated by solving the circle equation of the curve,and two 2-D accumulators A(a,b)and R(a,b)are accumulated with 1 and r,respectively,Then the parameters{(a,b,r)}of the circles fitting the curve are determined from A(a,b)and R(a,b) by searching for the local maximum over A(a,b).Because no computation loops over center(a,b) and/or radius r are needed,the method is faster than the basic and directional gradient methods It needs also much smaller memory for accumulation.

    • Coexistence of ferromagnetism and superconductivity in semimetals (Triplet pairing case)

      International Nuclear Information System (INIS)

      The possibility of coexistence of ferromagnetic ordering and superconductivity in a two-band model of a semimetal with an isotopic current carrier spectrum is investigated in detail. It is shown that for unequal electron and hole concentrations triplet electron-hole and triplet cooper pairings with weak electron coupling may coexist. In this case a nonvanishing mean magnetic moment appears. (author). 9 refs., 4 figs

  1. Triplet repeat length bias and variation in the human transcriptome

    OpenAIRE

    Molla, Michael; Delcher, Arthur; Sunyaev, Shamil; Cantor, Charles; Kasif, Simon

    2009-01-01

    Length variation in short tandem repeats (STRs) is an important family of DNA polymorphisms with numerous applications in genetics, medicine, forensics, and evolutionary analysis. Several major diseases have been associated with length variation of trinucleotide (triplet) repeats including Huntington's disease, hereditary ataxias and spinobulbar muscular atrophy. Using the reference human genome, we have catalogued all triplet repeats in genic regions. This data revealed a bias in noncoding D...

  2. Higher-Spin Triplet Fields and String Theory

    Directory of Open Access Journals (Sweden)

    D. Sorokin

    2010-01-01

    Full Text Available We review basic properties of reducible higher-spin multiplets, called triplets, and demonstrate how they naturally appear as part of the spectrum of String Field Theory in the tensionless limit. We show how in the frame-like formulation the triplet fields are endowed with the geometrical meaning of being components of higher-spin vielbeins and connections and present actions describing their free dynamics.

  3. Formylmethylene: the triplet ground state and the lowest singlet state

    OpenAIRE

    Guan, Jun; Randall, Katherine R.; Li, Huidong; Schaefer, Henry F. III

    2013-01-01

    The ground triplet state and lowest singlet state of formylmethylene have been proposed as important intermediates in the Wolff rearrangement of α-diazo ketones into ketenes. The ground triplet state of formylmethylene has been examined experimentally, but the lowest singlet state has yet to be observed. We predict equilibrium geometries, energies, bonding, dipole moments, and harmonic vibrational frequencies for these two lowest states of formylmethylene at the cc-pVQZ CCSD...

  4. Line absorption of He-like triplet lines by Li-like ions. Caveats of using line ratios of triplets for plasma diagnostics

    OpenAIRE

    Mehdipour, M.; Kaastra, J. S.; Raassen, A. J. J.

    2015-01-01

    He-like ions produce distinctive series of triplet lines under various astrophysical conditions. However, this emission can be affected by line absorption from Li-like ions in the same medium. We investigate this absorption of He-like triplets and present the implications for diagnostics of plasmas in photoionisation equilibrium using the line ratios of the triplets. Our computations were carried out for the O VI and Fe XXIV absorption of the O VII and Fe XXV triplet emission lines, respectiv...

  5. Broadband visible light-harvesting naphthalenediimide (NDI) triad: study of the intra-/intermolecular energy/electron transfer and the triplet excited state.

    Science.gov (United States)

    Wu, Shuang; Zhong, Fangfang; Zhao, Jianzhang; Guo, Song; Yang, Wenbo; Fyles, Tom

    2015-05-21

    A triad based on naphthalenediimides (NDI) was prepared to study the intersystem crossing (ISC), the fluorescence-resonance-energy-transfer (FRET), as well as the photoinduced electron transfer (PET) processes. In the triad, the 2-bromo-6-alkylaminoNDI moiety was used as singlet energy donor and the spin converter, whereas 2,6-dialkylaminoNDI was used as the singlet/triplet energy acceptor. This unique structural protocol and thus alignment of the energy levels ensures the competing ISC and FRET in the triad. The photophysical properties of the triad and the reference compounds were studied with steady-state UV-vis absorption spectra, fluorescence spectra, nanosecond transient absorption spectra, cyclic voltammetry, and DFT/TDDFT calculations. FRET was confirmed with steady-state UV-vis absorption and fluorescence spectroscopy. Intramolecular electron transfer was observed in polar solvents, demonstrated by the quenching of both the fluorescence and triplet state of the energy acceptor. Nanosecond transient absorption spectroscopy shows that the T1 state of the triad is exclusively localized on the 2,6-dialkylaminoNDI moiety in the triad upon selective photoexcitation into the energy donor, which indicates the intramolecular triplet state energy transfer. The intermolecular triplet state energy transfer between the two reference compounds was investigated with nanosecond transient absorption spectroscopy. The photophysical properties were rationalized by TDDFT calculations. PMID:25919420

  6. [Neonatal morbidity and hospital mortality of preterm triplets.

    Science.gov (United States)

    Lamshing-Salinas, Priscilla; Rend Ón-Macías, Mario Enrique; Iglesias-Leboreiro, José; Bernárdez-Zapata, Isabel; Braverman-Bronstein, Ariela

    2013-01-01

    Background: multiple gestations have caused an increase in vulnerable preterm births. Our objective was to analyze neonatal morbidity and mortality in preterm triplets. Methods: we analyzed a cohort of 30 triplets in an obstetrics and gynecology hospital. Data were obtained during pregnancy, childbirth and neonatal period: birth order, sex, weight, height, malformations, advanced resuscitation, assisted ventilation, intraventricular hemorrhage, necrotizing enterocolitis, sepsis, pulmonary hypertension, bronchopulmonary dysplasia, days of hospitalization, and death. Results: 90 infants were analyzed. There was an omphalopagus con-joined twins case; 42 (70 %) had between 30-33 weeks and six between 24-29; 19 (21 %) had low weight for gestational age, and 18 (30 %) had a major malformation; 27 % required ventilatory support, 33 % sepsis, 32 % necrotizing enterocolitis, 21 % pulmonary hypertension, 14 % bronchopulmonary dysplasia and 2 % intraventricular hemorrhage, without statistically significant differences related to the order, presentation at birth, sex and number of placentas and amniotic sacs. Eight 24-week triplets died, four over 28 weeks, and a siamese (p = 38). There was no difference in hospital days between triplets. Conclusions: the triplets mortality is low and mainly associated with extreme prematurity, intrauterine growth restriction and sepsis. PMID:24290011

  7. Rates and singlet/triplet ratios from TADF transients

    CERN Document Server

    Nelson, Mitchell C

    2016-01-01

    Thermally activated delayed fluorescence has been reported in a number of OLED emitter materials engineered to have low singlet-triplet energy gaps. Here we derive closed solutions for steady state and transient behaviors and apply these results to data provided in recent reports. Earlier work has used yields, rates and a supplied forward crossing rate to estimate the reverse crossing rate and then obtain the singlet-triplet energy gap in a log-linear fit. In this work we use only the system relaxation times and obtain all five of the system constants: the singlet and triplet relaxation rates, the forward and reverse crossing rates and the singlet-triplet energy gap. These are then used to calculate the fluorescent/phosphorescent ratio and the singlet/triplet population ratio. Good fits are obtained for data from 4CzIPN and from the excimer m-MTDATA:t-Bu-PBD and the results appear to be consistent with the reported behaviors of OLEDS using these materials.

  8. Long-Lived, Colour-Triplet Scalars from Unnaturalness

    CERN Document Server

    Barnard, James; Gherghetta, Tony; Spray, Andrew

    2015-01-01

    Long-lived, colour-triplet scalars are a generic prediction of unnatural, or split, composite Higgs models where the spontaneous global-symmetry breaking scale $f \\gtrsim 10$ TeV and an unbroken $SU(5)$ symmetry is preserved. Since the triplet scalars are pseudo Nambu-Goldstone bosons they are split from the much heavier composite-sector resonances and are the lightest exotic, coloured states. This makes them ideal to search for at colliders. Due to discrete symmetries the triplet scalar decays via a dimension-six term and given the large suppression scale $f$ is often metastable. We show that existing searches for collider-stable R-hadrons from Run-I at the LHC forbid a triplet scalar mass below 845 GeV, whereas with $300\\,\\mathrm{fb}^{-1}$ at 13 TeV triplet scalar masses up to 1.4 TeV can be discovered. For shorter lifetimes displaced-vertex searches provide a discovery reach of up to 1.8 TeV. In addition we present exclusion and discovery reaches of future hadron colliders as well as indirect limits that a...

  9. Photosensitized reactions initiated by 6-carboxypterin: singlet and triplet reactivity.

    Science.gov (United States)

    Tinel, L; Rossignol, S; Ciuraru, R; Dumas, S; George, C

    2016-06-22

    Pterins, derivatives of 2-aminopteridin-4(3H)-one, are natural photosensitizers, common to many biological systems. Indications that these photosensitizers are also present in the sea-surface microlayer motivated the study of the photophysical and photochemical properties of 6-carboxypterin (CPT), which was chosen as a model for this group of photoactive compounds. The kinetics of excited CPT in the singlet and triplet state in the presence of halides and organics were studied in aqueous solutions at neutral pH by means of steady-state fluorescence and laser-flash photolysis. The fluorescence of CPT was efficiently quenched by two halides (iodide and bromide) and by four carboxylic acids (lactic, malonic, propionic and citric acid) with reaction rates close to the diffusion-controlled limit. In the triplet state, the triplet absorption spectrum was measured and its pH dependence was studied. The triplet state of CPT showed relatively high reactivity towards iodide, but no reaction with bromide or chloride could be observed. No singlet or triplet state quenching in the presence of limonene could be measured. A reaction mechanism is proposed, initiated by electron transfer from the quencher to the excited photosensitizer. This type of photo-induced reaction in the sea-surface microlayer has the potential to trigger the production of many oxidized species, including halogen atoms, in the bulk and gaseous phases. PMID:27296228

  10. Manipulating rogue wave triplet in optical waveguides through tapering

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, Rama [Department of Physics, DAV University, Jalandhar 144008 (India); Kumar, C.N., E-mail: cnkumar@pu.ac.in [Department of Physics, Panjab University, Chandigarh 160014 (India); Vyas, Vivek M. [Institute of Mathematical Sciences, CIT Campus, Taramani, Chennai 600 113 (India); Panigrahi, Prasanta K., E-mail: pprasanta@iiserkol.ac.in [Indian Institute of Science Education and Research – Kolkata, Mohanpur, Nadia 741252 (India)

    2015-02-06

    Taking account of the results of the paper, published in [21] (Chabchoub and Akhmediev, 2013), containing experimental generation of rogue wave triplets in the water tank, we demonstrate a theoretical approach to coherently control the rogue wave triplet dynamics and spectral spread in a tapered index optical waveguide. The relative distance between the successive waves of the triplet, along both longitudinal and transverse axes, can be manipulated by modulating the tapering of the waveguide. This not only significantly enhances the possibility of observing these statistically rare events in the waveguide, but can also controllably amplify the intensity and spectral spread, the desired features for supercontinuum generation. The controlling of real Riccati parameter intrinsically arises from the allowed phase variation of the self-similar solutions of the nonlinear Schrödinger equation. - Highlights: • Manipulating rogue wave triplets in GNLSE using Riccati parameter is outlined. • Symmetric transformations used to scale mutual spacing in a triplet. • Results presented for sech{sup 2}-type tapered waveguides.

  11. [Investigation of the microstructure of biological systems by triplet label].

    Science.gov (United States)

    Kotel'niko, A I; Kuznetsov, S N; Fogel', V R; Likhtenshteĭn, G I

    1979-01-01

    A method for investigating the microstruct and dynamics of biological systems by means of triplet-excited molecules is suggested. The method is based on the phenomenon of triplet excitation disactivation by exchange-resonance triplet-triplet energy transfer to the acceptor or by intercombination conversion induced by interaction of an excited molecule with a paramagnetic center. The disactivation efficiency was measured by registrating the phosphorescense decay kinetics. The interaction of the triplet label eosin isothiocyanate, covalently coupled with albumine, lysozyme, sarcoplasmic reticulum membrane and Ca-Mg-dependent sarcoplasmic reticulum ATPase, with O2, the stable nitroxide radicals and ions of Mn2+ was investigated to analyse the potentialities of this method. As a model system the eosin phosphorescence quenching by the same quenchers in glycerine-aguaous solutions was studied. The method permits to investigate the microviscosity and microstructure of biological objects in the label attached region on interaction of the label with a sound-quencher with constants being 10(4) divided by 10(9) M-1 sec-1 and to measure the lateral diffusion of molecules in highly viscosity media (10 divided by 10(5) santypuas). PMID:223037

  12. Strong electroweak phase transition from Supersymmetric Custodial Triplets

    CERN Document Server

    Garcia-Pepin, Mateo

    2016-01-01

    The Supersymmetric Custodial Triplet Model, a supersymmetric generalization of the Georgi-Machacek model, has proven to be an interesting modification of the MSSM. It extends the MSSM Higgs sector by three extra SU(2)L triplets in such a way that approximate custodial invariance is preserved and rho-parameter deviations are kept under control. By means of a sizeable triplet contribution to electroweak breaking the model is able to generate a barrier at tree level between the false vacuum and the electroweak one. This will result in a strong first order phase transition for an important region of the parameter space. We also look at the gravitational waves that could be generated as a result of the phase transition and show how future interferometers could be used as a probe of the model.

  13. Ion-Pair States in Triplet Molecular Hydrogen

    Science.gov (United States)

    Setzer, W.; Baker, B. C.; Ashman, S.; Morgan, T. J.

    2016-05-01

    An experimental search is underway to observe the long range triplet ionic states H+ H- of molecular hydrogen. Resonantly enhanced multi-photon ionization of the metastable c 3∏u- 2 pπ state is used access to the R(1)nd1 n = 21 Rydberg state that serves as an intermediate stepping stone state to probe the energy region above the ionization limit with a second tunable laser photon. The metastable state is prepared by electron capture of 6 keV H2+ions in potassium in a molecular beam. Formation of the H+ H- triplet configuration involves triplet excited states of the H- ion, especially the 2p23Pe state, the second bound state of H- predicted to exist with a lifetime long compared to typical auto ionization lifetimes but not yet observed experimentally. Details of the experiment and preliminary results to date will be presented at the conference.

  14. Leptogenesis, radiative neutrino masses and inert Higgs triplet dark matter

    CERN Document Server

    Lu, Wen-Bin

    2016-01-01

    We extend the standard model by three types of inert fields including Majorana fermion singlets/triplets, real Higgs singlets/triplets and leptonic Higgs doublets. In the presence of a softly broken lepton number and an exactly conserved Z_2 discrete symmetry, these inert fields together can mediate a one-loop diagram for a Majorana neutrino mass generation. The heavier inert fields can decay to realize a successful leptogenesis while the lightest inert field can provide a stable dark matter candidate. As an example, we demonstrate the leptogenesis by the inert Higgs doublet decays. We also perform a systematic study on the inert Higgs triplet dark matter scenario where the interference between the gauge and Higgs portal interactions can significantly affect the dark matter properties.

  15. Leptogenesis, radiative neutrino masses and inert Higgs triplet dark matter

    Science.gov (United States)

    Lu, Wen-Bin; Gu, Pei-Hong

    2016-05-01

    We extend the standard model by three types of inert fields including Majorana fermion singlets/triplets, real Higgs singlets/triplets and leptonic Higgs doublets. In the presence of a softly broken lepton number and an exactly conserved Z2 discrete symmetry, these inert fields together can mediate a one-loop diagram for a Majorana neutrino mass generation. The heavier inert fields can decay to realize a successful leptogenesis while the lightest inert field can provide a stable dark matter candidate. As an example, we demonstrate the leptogenesis by the inert Higgs doublet decays. We also perform a systematic study on the inert Higgs triplet dark matter scenario where the interference between the gauge and Higgs portal interactions can significantly affect the dark matter properties.

  16. Spin current due to triplet superconductor - ferromagnet interfaces

    International Nuclear Information System (INIS)

    The interface between a superconductor and a ferromagnet is an ideal setting in which to study the complicated interplay of these two phases. Although the relevant physics is now very well understood for a spin singlet pairing state of the superconductor, qualitatively new phenomena can appear for a spin triplet pairing state due to the intrinsic spin structure of the superconductor. One such surprising result is the existence of a bulk spin supercurrent in the triplet superconductor due to spin-flip reflection of triplet Cooper pairs at the superconductor-ferromagnet interface. The resulting spin current displays strong similarities to the spontaneous charge current in a conventional Josephson junction. The dependence of the spin current on a number of relevant parameters is studied e.g. the orbital pairing state of the superconductor and the exchange splitting of the ferromagnet. The possibility of unconventional dynamics of the magnetization of the ferromagnet is discussed.

  17. Lepton Flavor Violation in the singlet-triplet scotogenic model

    CERN Document Server

    Rocha-Moran, Paulina

    2016-01-01

    We investigate lepton flavor violation (LFV) in the the singlet-triplet scotogenic model in which neutrinos acquire non-zero masses at the 1-loop level. In contrast to the most popular variant of this setup, the singlet scotogenic model, this version includes a triplet fermion as well as a triplet scalar, leading to a scenario with a richer dark matter phenomenology. Taking into account results from neutrino oscillation experiments, we explore some aspects of the LFV phenomenology of the model. In particular, we study the relative weight of the dipole operators with respect to other contributions to the LFV amplitudes and determine the most constraining observables. We show that in large portions of the parameter space, the most promising experimental perspectives are found for LFV 3-body decays and for coherent $\\mu-e$ conversion in nuclei.

  18. Optimization of Spin-Triplet Supercurrent in Ferromagnetic Josephson Junctions

    Science.gov (United States)

    Klose, Carolin; Khaire, Trupti S.; Wang, Yixing; Pratt, W. P., Jr.; Birge, Norman O.; McMorran, B. J.; Ginley, T. P.; Borchers, J. A.; Kirby, B. J.; Maranville, B. B.; Unguris, J.

    2012-03-01

    We have observed long-range spin-triplet supercurrents in Josephson junctions containing ferromagnetic (F) materials, which are generated by noncollinear magnetizations between a central Co/Ru/Co synthetic antiferromagnet and two outer thin F layers. Here we show that the spin-triplet supercurrent is enhanced up to 20 times after our samples are subject to a large in-plane field. This occurs because the synthetic antiferromagnet undergoes a “spin-flop” transition, whereby the two Co layer magnetizations end up nearly perpendicular to the magnetizations of the two thin F layers. We report direct experimental evidence for the spin-flop transition from scanning electron microscopy with polarization analysis and from spin-polarized neutron reflectometry. These results represent a first step toward experimental control of spin-triplet supercurrents.

  19. Mixed ligand complexes of alkaline earth metals: Part XII. Mg(II, Ca(II, Sr(II and Ba(II complexes with 5-chlorosalicylaldehyde and salicylaldehyde or hydroxyaromatic ketones

    Directory of Open Access Journals (Sweden)

    MITHLESH AGRAWAL

    2002-04-01

    Full Text Available The reactions of alkaline earth metal chlorides with 5-chlorosalicylaldehyde and salicylaldehyde, 2-hydroxyacetophenone or 2-hydroxypropiophenone have been carried out in 1 : 1 : 1 mole ratio and the mixed ligand complexes of the type MLL’(H2O2 (where M = Mg(II, Ca(II, Sr(II and Ba(II, HL = 5-chlorosalicylaldehyde and HL’ = salicylaldehyde, 2-hydroxyacetophenone or 2-hydroxypropiophenone have been isolated. These complexes were characterized by TLC, conductance measurements, IR and 1H-NMR spectra.

  20. Spin-lattice relaxation in phosphorescent triplet state molecules

    International Nuclear Information System (INIS)

    The present thesis contains the results of a study of spin-lattice relaxation (SLR) in the photo-excited triplet state of aromatic molecules, dissolved in a molecular host crystal. It appears that SLR in phosphorescent triplet state molecules often is related to the presence of so-called (pseudo) localized phonons in the molecular mixed crystals. These local phonons can be thought to correspond with vibrations (librations) of the guest molecule in the force field of the surrounding host molecules. Since the intermolecular forces are relatively weak, the frequencies corresponding with these vibrations are relatively low and usually are of the order of 10-30 cm-1. (Auth.)

  1. Effective t-J model of pairing: singlet versus triplet

    Directory of Open Access Journals (Sweden)

    J.Spałek

    2008-09-01

    Full Text Available The t-J model is regarded as a canonical model of spin-singlet pairing induced by the kinetic exchange interaction also responsible for an antiferromagnetic ordering in the strongly correlated narrow-band systems. In the orbitally degenerate systems both ferromagnetic and antiferromagnetic kinetic exchange interactions occur. I briefly review the analogy between the singlet and triplet types of pairing, as well as draw some general conclusions about the pairing induced by these exchange interactions. The general discussion is also illustrated with a concrete case of a two-dimensional lattice with the spin triplet pairing.

  2. Chromospheric Polarization in the Photospheric Solar Oxygen Infrared Triplet

    Science.gov (United States)

    Del Pino Alemán, Tanausú; Trujillo Bueno, Javier

    2015-07-01

    We present multilevel radiative transfer modeling of the scattering polarization observed in the solar O i infrared triplet around 777 nm. We demonstrate that the scattering polarization pattern observed on the solar disk forms in the chromosphere, far above the photospheric region where the bulk of the emergent intensity profiles originate. We investigate the sensitivity of the polarization pattern to the thermal structure of the solar atmosphere and to the presence of weak magnetic fields (10-2-100 G) through the Hanle effect, showing that the scattering polarization signals of the oxygen infrared triplet encode information on the magnetism of the solar chromosphere.

  3. Chromospheric Polarization in the Photospheric Solar Oxygen Infrared Triplet

    CERN Document Server

    Alemán, T del Pino

    2015-01-01

    We present multilevel radiative transfer modeling of the scattering polarization observed in the solar O I infrared triplet around 777 nm. We demonstrate that the scattering polarization pattern observed on the solar disk forms in the chromosphere, far above the photospheric region where the bulk of the emergent intensity profiles originates. We study the sensitivity of the polarization pattern to the thermal structure of the solar atmosphere and to the presence of weak magnetic fields (0.01 - 100 G) through the Hanle effect, showing that the scattering polarization signals of the oxygen infrared triplet encode information on the magnetism of the solar chromosphere.

  4. Spin-triplet supercurrent in planar geometry ferromagnetic Josephson junctions

    Science.gov (United States)

    Martinez, William M.; Pratt, W. P., Jr.; Birge, Norman O.

    2013-03-01

    The spin-triplet supercurrent in ferromagnetic Josephson junctions is obtained by surrounding the central ferromagnet with noncollinear ferromagnetic layers, F'. In metallic ferromagnets, the long-range nature of the spin-triplet supercurrent has only been tested to lengths of a few tens of nm. In this work, we are fabricating and measuring S/F'/F/F'/S junctions where the central F layer has a lateral geometry with lengths up to a few hundred nm. We will report on our recent progress. Supported by the DOE under grant DE-FG-02-06ER46341.

  5. Pyridine-2,6-diyl dinitroxides as room-temperature triplet ligands

    Energy Technology Data Exchange (ETDEWEB)

    Kawakami, Hinako; Tonegawa, Asato; Ishida, Takayuki, E-mail: takayuki.ishida@uec.ac.jp [Department of Engineering Science, The University of Electro-Communications, Tokyo (Japan)

    2016-02-01

    We have proposed tert-butyl 2-pyridyl nitroxide radicals as a promising paramagnetic chelating ligand, where the direct radical-metal bond leads to strong magnetic interaction. We successfully synthesized and isolated PyBN derivatives (pyridine-2,6-diyl bis(tert-butyl nitroxides)). The molecular and crystal structures of the target biradicals, MesPyBN, AntPyBN and tBuOPyBN were determined from the X-ray crystal structure analysis, which possess mesityl, 9-anthryl and tert-butoxy groups at the 5-position of the pyridine ring, respectively. The ground triplet state was characterized by means of SQUID susceptometry for each compound. On heating, the χ{sub m}T values of all the PyBN derivatives increased and reached a plateau at ca. 1.0 cm{sup 3} K mol{sup −1} at 300 K. It implies that biradicals behaved as triplet molecules even at room temperature, or 2J/k{sub B} >> 300 K. From the decay monitored in solution electron-spin resonance spectroscopy, MesPyBN was the most persistent, while tBuOPyBN was the most reactive, of the three.

  6. Pyridine-2,6-diyl dinitroxides as room-temperature triplet ligands

    Science.gov (United States)

    Kawakami, Hinako; Tonegawa, Asato; Ishida, Takayuki

    2016-02-01

    We have proposed tert-butyl 2-pyridyl nitroxide radicals as a promising paramagnetic chelating ligand, where the direct radical-metal bond leads to strong magnetic interaction. We successfully synthesized and isolated PyBN derivatives (pyridine-2,6-diyl bis(tert-butyl nitroxides)). The molecular and crystal structures of the target biradicals, MesPyBN, AntPyBN and tBuOPyBN were determined from the X-ray crystal structure analysis, which possess mesityl, 9-anthryl and tert-butoxy groups at the 5-position of the pyridine ring, respectively. The ground triplet state was characterized by means of SQUID susceptometry for each compound. On heating, the χmT values of all the PyBN derivatives increased and reached a plateau at ca. 1.0 cm3 K mol-1 at 300 K. It implies that biradicals behaved as triplet molecules even at room temperature, or 2J/kB >> 300 K. From the decay monitored in solution electron-spin resonance spectroscopy, MesPyBN was the most persistent, while tBuOPyBN was the most reactive, of the three.

  7. The Ca II triplet in red giant spectra: [Fe/H] determinations and the role of [Ca/Fe

    CERN Document Server

    Da Costa, G S

    2015-01-01

    Measurements are presented and analyzed of the strength of the Ca II triplet lines in red giants in Galactic globular and open clusters, and in a sample of red giants in the LMC disk that have significantly different [Ca/Fe] abundance ratios to the Galactic objects. The Galactic objects are used to generate a calibration between Ca II triplet line strength and [Fe/H], which is then used to estimate [Fe/H]_CaT for the LMC stars. The values are then compared with the [Fe/H]_spec determinations from high dispersion spectroscopy. After allowance for a small systematic offset the two abundance determinations are in excellent agreement. Further, as found in earlier studies, e.g., Battaglia et al. (2008), the difference is only a very weak function of the [Ca/Fe] ratio. For example, changing [Ca/Fe] from +0.3 to -0.2 causes the Ca II based abundance to underestimate [Fe/H]_spec by only ~0.15 dex, assuming a Galactic calibration. Consequently, the Ca II triplet approach to metallicity determinations can be used witho...

  8. Stability of singlet and triplet trions in carbon nanotubes

    DEFF Research Database (Denmark)

    Rønnow, Troels Frimodt; Pedersen, Thomas Garm; Cornean, Horia

    2009-01-01

    We investigate singlet and triplet trion states in semiconducting carbon nanotubes using a one-dimensional model. It is concluded that singlet trion states in bind up to 13.5% stronger than exciton states, and that they lower the optical transition energy with up to 50% of the tight binding band...

  9. Dark Matter from the Supersymmetric Custodial Triplet Model

    CERN Document Server

    Delgado, Antonio; Ostdiek, Bryan; Quiros, Mariano

    2015-01-01

    The Supersymmetric Custodial Triplet Model (SCTM) adds to the particle content of the MSSM three $SU(2)_L$ triplet chiral superfields with hypercharge $Y=(0,\\pm1)$. At the superpotential level the model respects a global $SU(2)_L \\otimes SU(2)_R$ symmetry only broken by the Yukawa interactions. The pattern of vacuum expectation values of the neutral doublet and triplet scalar fields depends on the symmetry pattern of the Higgs soft breaking masses. We study the cases where this symmetry is maintained in the Higgs sector, and when it is broken only by the two doublets attaining different vacuum expectation values. In the former case, the symmetry is spontaneously broken down to the vectorial subgroup $SU(2)_V$ and the $\\rho$ parameter is protected by the custodial symmetry. However in both situations the $\\rho$ parameter is protected at tree level, allowing for light triplet scalars with large vacuum expectation values. We find that over a large range of parameter space, a light neutralino can supply the corre...

  10. Odd-Frequency Triplet Josephson Current Through an Exchange Spring

    Science.gov (United States)

    Bill, Andreas; Baker, Thomas E.; Richie-Halford, Adam; Moke, Adam K.

    2013-03-01

    The existence of an odd-frequency long range triplet component in the order parameter of a proximity system with singlet superconductors is a recent prediction that has garnered great interest. The experimental fingerprint of this phenomenon is difficult to establish. We investigate a hybrid structure in which the emergence of the long range triplet component may be measured and identified. We consider a superconductor - exchange spring - superconductor Josephson junction as a function of increasing twist of the magnetic domain wall in the exchange spring. We show that as the domain wall is generated the long range triplet component emerges and modifies the current flowing through the Josephson junction. The critical temperature is also affected by the increased twist of the domain wall. The calculations lead us to propose an experiment where the long range triplet component can unequivocally be identified. We gratefully acknowledge the support of the National Science Foundation (DMR-0907242), the Army Research Laboratory, the Research Corporation, the Graduate Research Fellowship and RSCA at CSU Long Beach.

  11. Spin-triplet supercurrent in Co-based Josephson junctions

    International Nuclear Information System (INIS)

    In the past year several groups have reported experimental evidence for spin-triplet supercurrents in Josephson junctions containing strong ferromagnetic materials. In this paper we present several new experimental results that follow up on our previous work. We study Josephson junctions of the form S/X/N/SAF/N/X/S, where S is a superconductor (Nb), N is a normal metal, SAF is a synthetic antiferromagnet of the form Co/Ru/Co and X is an ferromagnetic layer necessary to induce spin-triplet correlations in the structure. Our work is distinguished by the fact that the generation of spin-triplet correlations is tuned by the type and thickness of the X layers. The most important new result reported here is the discovery that a conventional, strong ferromagnetic material, Ni, performs well as the X layer, if it is sufficiently thin. This discovery rules out our earlier hypothesis that out-of-plane magnetocrystalline anisotropy is an important attribute of the X layers. These results suggest that the spin-triplet correlations are most likely induced by noncollinear magnetization between the X layers and adjacent Co layers.

  12. Spin-triplet supercurrent in Co-based Josephson junctions

    Energy Technology Data Exchange (ETDEWEB)

    Khasawneh, Mazin A; Khaire, Trupti S; Klose, Carolin; Pratt, William P Jr; Birge, Norman O, E-mail: birge@pa.msu.edu [Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824-2320 (United States)

    2011-02-15

    In the past year several groups have reported experimental evidence for spin-triplet supercurrents in Josephson junctions containing strong ferromagnetic materials. In this paper we present several new experimental results that follow up on our previous work. We study Josephson junctions of the form S/X/N/SAF/N/X/S, where S is a superconductor (Nb), N is a normal metal, SAF is a synthetic antiferromagnet of the form Co/Ru/Co and X is an ferromagnetic layer necessary to induce spin-triplet correlations in the structure. Our work is distinguished by the fact that the generation of spin-triplet correlations is tuned by the type and thickness of the X layers. The most important new result reported here is the discovery that a conventional, strong ferromagnetic material, Ni, performs well as the X layer, if it is sufficiently thin. This discovery rules out our earlier hypothesis that out-of-plane magnetocrystalline anisotropy is an important attribute of the X layers. These results suggest that the spin-triplet correlations are most likely induced by noncollinear magnetization between the X layers and adjacent Co layers.

  13. Spin-triplet supercurrent in Co-based Josephson junctions

    Science.gov (United States)

    Khasawneh, Mazin A.; Khaire, Trupti S.; Klose, Carolin; Pratt, William P., Jr.; Birge, Norman O.

    2011-02-01

    In the past year several groups have reported experimental evidence for spin-triplet supercurrents in Josephson junctions containing strong ferromagnetic materials. In this paper we present several new experimental results that follow up on our previous work. We study Josephson junctions of the form S/X/N/SAF/N/X/S, where S is a superconductor (Nb), N is a normal metal, SAF is a synthetic antiferromagnet of the form Co/Ru/Co and X is an ferromagnetic layer necessary to induce spin-triplet correlations in the structure. Our work is distinguished by the fact that the generation of spin-triplet correlations is tuned by the type and thickness of the X layers. The most important new result reported here is the discovery that a conventional, strong ferromagnetic material, Ni, performs well as the X layer, if it is sufficiently thin. This discovery rules out our earlier hypothesis that out-of-plane magnetocrystalline anisotropy is an important attribute of the X layers. These results suggest that the spin-triplet correlations are most likely induced by noncollinear magnetization between the X layers and adjacent Co layers.

  14. Stability of singlet and triplet trions in carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Ronnow, Troels F. [Department of Physics and Nanotechnology, Skjernvej 4C, 9220 Aalborg Ost (Denmark)], E-mail: tfr@nanophysics.dk; Pedersen, Thomas G. [Department of Physics and Nanotechnology, Skjernvej 4C, 9220 Aalborg Ost (Denmark)], E-mail: tgp@nano.aau.dk; Cornean, Horia D. [Department of Mathematical Sciences, Frederik Bajers Vej 7G, 9220 Aalborg Ost (Denmark)], E-mail: cornean@math.aau.dk

    2009-04-06

    We investigate singlet and triplet trion states in semiconducting carbon nanotubes using a one-dimensional model. It is concluded that singlet trion states in bind up to 13.6% stronger than exciton states, and that they lower the optical transition energy with up to 50% of the tight binding band gap energy.

  15. Stability of singlet and triplet trions in carbon nanotubes

    International Nuclear Information System (INIS)

    We investigate singlet and triplet trion states in semiconducting carbon nanotubes using a one-dimensional model. It is concluded that singlet trion states in bind up to 13.6% stronger than exciton states, and that they lower the optical transition energy with up to 50% of the tight binding band gap energy.

  16. Triplet states at an O vacancy in alpha-quartz

    DEFF Research Database (Denmark)

    Lægsgaard, Jesper

    2002-01-01

    The energy landscape of an alpha-quartz O vacancy in the lowest triplet state is investigated. Four local minima are identified and geometries, total energies, and electron paramagnetic resonance (EPR) parameters are obtained. On the basis of calculated values for the magnetic dipole interaction...

  17. Spontaneous fluctuations of transition dipole moment orientation in OLED triplet emitters

    CERN Document Server

    Steiner, Florian; Vogelsang, Jan; Lupton, John M

    2015-01-01

    The efficiency of an organic light-emitting diode (OLED) depends on the microscopic orientation of transition dipole moments of the molecular emitters. The most effective materials used for light generation have threefold symmetry, which prohibit a priori determination of dipole orientation due to the degeneracy of the fundamental transition. Single-molecule spectroscopy reveals that the model triplet emitter tris(2-phenylisoquinoline)iridium(III) (Ir(piq)3) does not behave as a linear dipole, radiating with lower polarization anisotropy than expected. Spontaneous symmetry breaking occurs in the excited state, leading to a random selection of one of the three ligands to form a charge transfer state with the metal. This non-deterministic localization is revealed in switching of the degree of linear polarization of phosphorescence. Polarization scrambling likely raises out-coupling efficiency and should be taken into account when deriving molecular orientation of the guest emitter within the OLED host from ense...

  18. Resonance raman and absorption spectra of isomeric retinals in their lowest excited triplet states

    DEFF Research Database (Denmark)

    Wilbrandt, Robert Walter; Jensen, N.-H.; Houee-Levin, C.

    1985-01-01

    The triplet-triplet absorption spectra of 9-cis and all-trans-retinal as well as the time-resolved resonance Raman spectra of the lowest electronically excited triplet states of 9-cis-, 11-cis, 13-cis and all-trans-retinal in aromatic solvents at room temperature were obtained under conditions en...

  19. PROBE FOR THE FORMATION RATIO BETWEEN EXCITED TRIPLETS AND SINGLETS AS GENERATED IN POLYMER LIGHT-EMITTING DIODES

    Institute of Scientific and Technical Information of China (English)

    Jing-ying Zhang; Shi-dong Kan; Yu-guang Ma; Jia-cong Shen

    2001-01-01

    The electroluminescence (EL) produced by a highly luminescent phosphorescent dye Cu4(C≡CPh)4L2 (L = 1.8-bis(di-phenylphosphino)-3,6-dioxaoctane, Cu4) doped polymer as emitting layer is reported. The effects of the charge injection balance on the polymers, in particular, poly(N-vinylcarbazole) (PVK) have been studied by using photoluminescence and electroluminescence spectroscopy. Changes in the emission spectra demonstrate the influence of the charge injection balance on the formation ratio of triplet and singlet excitons. This provides a new technical approach to realize the color patterning in polymer LEDs.

  20. Heats of Formation of Triplet Ethylene, Ethylidene, and Acetylene

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, M.T.; Matus, M.H.; Lester Jr, W.A.; Dixon, David A.

    2007-06-28

    Heats of formation of the lowest triplet state of ethylene and the ground triplet state of ethylidene have been predicted by high level electronic structure calculations. Total atomization energies obtained from coupled-cluster CCSD(T) energies extrapolated to the complete basis set limit using correlation consistent basis sets (CBS), plus additional corrections predict the following heats of formation in kcal/mol: Delta H0f(C2H4,3A1) = 80.1 at 0 K and 78.5 at 298 K, and Delta H0f(CH3CH,3A") = 86.8 at 0 K and 85.1 at 298 K, with an error of less than +-1.0 kcal/mol. The vertical and adiabatic singlet-triplet separation energies of ethylene were calculated as Delta ES-T,vert = 104.1 and Delta ES-T,adia = 65.8 kcal/mol. These results are in excellent agreement with recent quantum Monte Carlo (DMC) values of 103.5 +- 0.3 and 66.4 +- 0.3 kcal/mol. Both sets of computational values differ from the experimental estimate of 58 +- 3 kcal/mol for the adiabatic splitting. The computed singlet-triplet gap at 0 K for acetylene is Delta ES-T,adia(C2H2) = 90.5 kcal/mol, which is in notable disagreement with the experimental value of 82.6 kcal/mol. The heat of formation of the triplet is Delta H0f(C2H2,3B2) = 145.3 kcal/mol. There is a systematic underestimation of the singlet-triplet gaps in recent photodecomposition experiments by ~;;7 to 8 kcal/mol. For vinylidene, we predict Delta H0f(H2CC,1A1) = 98.8 kcal/mol at 298 K (exptl. 100.3 +- 4.0), Delta H0f(H2CC,3B2) = 146.2 at 298 K, and an energy gap Delta ES-T-adia(H2CC) = 47.7 kcal/mol.

  1. Zero-field splitting of the ground and excited triplet states of 2-naphthylphenylcarbene studied by hole-burning on triplet-triplet fluorescence excitation spectra

    Science.gov (United States)

    Kozankiewicz, B.; Bernard, J.; Migirdicyan, E.; Orrit, M.; Platz, M. S.

    1995-11-01

    Spectral holes were burned in the two main lines of the triplet-triplet 0-0 fluorescence excitation spectrum of 2-napththylphenylcarbene in n-hexane at 1.8 K. For the line assigned to pseudo-E/trans conformer, the central hole at the frequency of burning light has several narrow components separated by 0.3 ± 0.05 and 1.0 ± 0.1 GHz and a satellite doublet line on the low energy side, 14.5 ± 0.5 and 15.5 ± 0.5 GHz away. For the line assigned to the psuedo-Z/cis conformer, the central hole is accompanied by holes burned on the low energy side, 0.8 ± 0.1, 5.2 ± 0.1, 11.9 ± 0.1 and 16.2 ± 0.1 GHz away. The hole-burning pattern is explained by a model taking into account the zero-field splitting (ZFS) of the ground T 0 and excited T 1 triplet states as well as the selectivity of excitation relaxation by the intersystem crossing channel. Analysis provides information about the ZFS parameters of the T 1 state. For the pseudo-E/trans 2-NPC they are: D0 = 0.47 ± 0.02 cm -1, E0 = 0.017 ± 0.003 cm -1, D1 = 0.038 ± 0.003 cm -1 and E1 = 0.005 ± 0.001 cm -1.

  2. Fine-Tuning of β-Substitution to Modulate the Lowest Triplet Excited States: A Bioinspired Approach to Design Phosphorescent Metalloporphyrinoids.

    Science.gov (United States)

    Ke, Xian-Sheng; Zhao, Hongmei; Zou, Xiaoran; Ning, Yingying; Cheng, Xin; Su, Hongmei; Zhang, Jun-Long

    2015-08-26

    Learning nature's approach to modulate photophysical properties of NIR porphyrinoids by fine-tuning β-substituents including the number and position, in a manner similar to naturally occurring chlorophylls, has the potential to circumvent the disadvantages of traditional "extended π-conjugation" strategy such as stability, molecular size, solubility, and undesirable π-π stacking. Here we show that such subtle structural changes in Pt(II) or Pd(II) cis/trans-porphodilactones (termed by cis/trans-Pt/Pd) influence photophysical properties of the lowest triplet excited states including phosphorescence, Stokes shifts, and even photosensitization ability in triplet-triplet annihilation reactions with rubrene. Prominently, the overall upconversion capability (η, η = ε·Φ(UC)) of Pd or Pt trans-complex is 10(4) times higher than that of cis-analogue. Nanosecond time-resolved infrared (TR-IR) spectroscopy experiments showed larger frequency shift of ν(C═O) bands (ca. 10 cm(-1)) of cis-complexes than those of trans-complexes in the triplet excited states. These spectral features, combining with TD-DFT calculations, suggest the strong electronic coupling between the lactone moieties and the main porphyrin chromophores and thus the importance of precisely positioning β-substituents by mimicking chlorophylls, as an alternative to "extended π-conjugation", in designing NIR active porphyrinoids. PMID:26247480

  3. On-chip generation of photon-triplet states.

    Science.gov (United States)

    Krapick, Stephan; Brecht, Benjamin; Herrmann, Harald; Quiring, Viktor; Silberhorn, Christine

    2016-02-01

    Efficient sources of many-partite non-classical states are key for the advancement of quantum technologies and for the fundamental testing of quantum mechanics. We demonstrate the generation of time-correlated photon triplets at telecom wavelengths via pulsed cascaded parametric down-conversion in a monolithically integrated source. By detecting the generated states with success probabilities of (6.25 ± 1.09) × 10(-11) per pump pulse at injected powers as low as 10 μW, we benchmark the efficiency of the complete system and deduce its high potential for scalability. Our source is unprecedentedly long-term stable, it overcomes interface losses intrinsically due to its monolithic architecture, and the photon-triplet states dominate uncorrelated noise significantly. These results mark crucial progress towards the proliferation of robust, scalable, synchronized and miniaturized quantum technology. PMID:26906852

  4. The N = 1 Triplet Vertex Operator Superalgebras: Twisted Sector

    Directory of Open Access Journals (Sweden)

    Drazen Adamovic

    2008-12-01

    Full Text Available We classify irreducible σ-twisted modules for the N = 1 super triplet vertex operator superalgebra SW(m introduced recently [Adamovic D., Milas A., Comm. Math. Phys., to appear, arXiv:0712.0379]. Irreducible graded dimensions of σ-twisted modules are also determined. These results, combined with our previous work in the untwisted case, show that the SL(2,Z-closure of the space spanned by irreducible characters, irreducible supercharacters and σ-twisted irreducible characters is (9m + 3-dimensional. We present strong evidence that this is also the (full space of generalized characters for SW(m. We are also able to relate irreducible SW(m characters to characters for the triplet vertex algebra W(2m + 1, studied in [Adamovic D., Milas A., Adv. Math. 217 (2008, 2664-2699, arXiv:0707.1857].

  5. Triplets of Quasars at high redshift I: Photometric data

    CERN Document Server

    Alonso, M Victoria; Sochting, Ilona; Bornancini, Carlos; Smith, Malcolm G; Lambas, Diego Garcia; Rest, Armin

    2008-01-01

    We have conducted an optical and infrared imaging in the neighbourhoods of 4 triplets of quasars. R, z', J and Ks images were obtained with MOSAIC II and ISPI at Cerro Tololo Interamerican Observatory. Accurate relative photometry and astrometry were obtained from these images for subsequent use in deriving photometric redshifts. We analyzed the homogeneity and depth of the photometric catalog by comparing with results coming from the literature. The good agreement shows that our magnitudes are reliable to study large scale structure reaching limiting magnitudes of R = 24.5, z' = 22.5, J = 20.5 and Ks = 19.0. With this catalog we can study the neighbourhoods of the triplets of quasars searching for galaxy overdensities such as groups and galaxy clusters.

  6. Triplet Josephson current modulated by Rashba spin-orbit coupling

    International Nuclear Information System (INIS)

    We study the Rashba spin-orbit coupling (RSOC) effect on the supercurrent in a clean triplet superconductor/two-dimensional electron gas/triplet superconductor (TS/2DEG/TS) junction, where RSOC is considered in the 2DEG region. Based on the Bogoliubov-de Gennes equation and quantum scattering method, we show that RSOC can lead to a 0-π oscillation of supercurrent and the abrupt current reversal effect. The current direction can be reversed by a tiny modulation of RSOC, and this is attributed to the equal spin pairing of the TS order parameter and the spin precession phase of the quasiparticle traveling in the RSOC region. The RSOC strength can be controlled by an electric field in experiments, thus our findings provide a purely electric means to modulate the supercurrent in TS Josephson junctions.

  7. Ultrafast photogeneration mechanisms of triplet states in para-hexaphenyl

    OpenAIRE

    Zenz, C.; Cerullo, G.; G. Lanzani; Graupner, W.; Meghdadi, F.; Leising, G.; Silvestri, S

    1999-01-01

    We present femtosecond pump-probe measurements, both conventional and electric field-assisted, on organic light-emitting devices based on para-hexaphenyl. The dominant triplet excition generation mechanism is assigned to nongeminate bimolecular recombination of photogenerated, spin-1/2 polarons. This process is active within a few hundred femtoseconds after photoexcitation and involves about 20% of the initially excited states. At higher photoexcitation densities, we observe an additional tri...

  8. Triplets of Quasars at high redshift I: Photometric data

    OpenAIRE

    Alonso, M. Victoria; Coldwell, Georgina V.; Sochting, Ilona; Bornancini, Carlos; Smith, Malcolm G.; Lambas, Diego Garcia; Rest, Armin

    2008-01-01

    We have conducted an optical and infrared imaging in the neighbourhoods of 4 triplets of quasars. R, z', J and Ks images were obtained with MOSAIC II and ISPI at Cerro Tololo Interamerican Observatory. Accurate relative photometry and astrometry were obtained from these images for subsequent use in deriving photometric redshifts. We analyzed the homogeneity and depth of the photometric catalog by comparing with results coming from the literature. The good agreement shows that our magnitudes a...

  9. Substrate Integrated Waveguide Diplexer Based on Circular Triplet Combline Filters

    OpenAIRE

    Sirci, Stefano; Martínez Pérez, Jorge Daniel; Vague Cardona, José Joaquín; Boria Esbert, Vicente Enrique

    2015-01-01

    The design of substrate integrated waveguide (SIW) diplexers, based on combline triplet sections with transmission zeros (TZs) placed below and above the passband, is presented. In order to control the location of the TZs, positive and negative couplings are conveniently provided. A highly compact implementation based on circular substrate integrated coaxial resonators is proposed. An X band diplexer with channel center frequencies at 9.5 and 10.5 GHz and absolute bandwidths of 400 MHz is ...

  10. Conjoined Twins in a Triplet Pregnancy: A Case Report

    OpenAIRE

    Smith, Graeme N.; Shepherd, Lynn J.

    2011-01-01

    Background. Conjoined twins are a rare complication of monozygotic twinning and are associated with high perinatal mortality. Case. Here we present a case of conjoined twins in a triplet pregnancy diagnosed at 13 of weeks gestation. With the aid of 3D ultrasound and MRI images, the parents were counseled regarding the management options, including continuation of pregnancy, termination of pregnancy, or selective fetocide. They chose selective fetocide of the conjoined twins and went on to del...

  11. Correlation-induced triplet superconductivity on the graphene lattice

    OpenAIRE

    Sahebsara, Peyman; Senechal, David

    2009-01-01

    We investigate the possibility of superconductivity on the graphene lattice within the repulsive Hubbard model using the variational cluster approximation (VCA). We find that singlet superconductivity is impossible; instead, triplet superconductivity is favored, with four solutions that are close to each other in energy and differ by their symmetry; one is f-wave, the other three p-wave, including a p+ip solution that breaks time-reversal invariance.

  12. Anomalous Josephson Hall effect in magnet/triplet superconductor junctions

    OpenAIRE

    Yokoyama, Takehito

    2015-01-01

    We investigate anomalous Hall effect in a magnet coupled to a triplet superconductor under phase gradient. It is found that the anomalous Hall supercurrent arises from non-trivial structure of the magnetization. The magnetic structure manifested in the Hall supercurrent is characterized by even order terms of the exchange coupling, essentially different from that discussed in the context of anomalous Hall effect, reflecting the disspationless nature of supercurrent. We also discuss a possible...

  13. Cascade Decays of Triplet Higgs Bosons at LEP2

    CERN Document Server

    Akeroyd, A G

    1998-01-01

    We study the Georgi-Machacek two triplet, one doublet model in the context of LEP2, and show that cascade decays of Higgs bosons to lighter Higgs bosons and a virtual vector boson may play a major role. Such decays would allow the Higgs bosons of this model to escape current searches, and in particular are of great importance for the members of the five-plet which will always decay to the three-plet giving rise to cascade signatures.

  14. Genome-specificity of triplet periodicity of prokaryotic genomes

    International Nuclear Information System (INIS)

    Authors have found that triplet periodicity (TP) is more similar inside genome than between genomes and that TP distribution inside genome corresponds to hypothesis which imply common TP pattern for majority of sequences inside a genome. To test the specificity of TP, the classification of the gene has been carried out to detect the belonging to one genome of the pair. For most pairs, the classification accuracy was more than 85%

  15. Signatures of Dark Matter in Inert Triplet Models

    CERN Document Server

    Araki, Takeshi; Nagao, Keiko I

    2011-01-01

    In this talk, we will review the signatures of dark matter in two inert triplet models. For the first model with the hypercharge Y=0, the dark matter mass around 5.5 TeV is favored by both the WMAP data and the direct detection. In contrast, for the second model of Y=2, it is excluded by the direct detection experiments although dark matter with its mass around 2.8 TeV is allowed by WMAP.

  16. Supersymmetric Custodial Higgs Triplets and the Breaking of Universality

    CERN Document Server

    Garcia-Pepin, Mateo; Quiros, Mariano; Vega, Roberto; Vega-Morales, Roberto; Yu, Tien-Tien

    2014-01-01

    Higgs triplet models are known to have difficulties obtaining agreement with electroweak precision data and in particular constraints on the $\\rho$ parameter. Either a global $SU(2)_L \\otimes SU(2)_R$ symmetry has to be imposed on the scalar potential at the electroweak scale, as done in the well-known Georgi-Machacek (GM) model, or the triplet vacuum expectation values must be very small. We construct a supersymmetric model that can satisfy constraints on the $\\rho$ parameter, even if these two conditions are not fulfilled. We supersymmetrize the GM model by imposing the $SU(2)_L \\otimes SU(2)_R$ symmetry at a scale $\\mathcal M$, which we argue should be at or above the messenger scale, where supersymmetry breaking is transmitted to the observable sector. We show that scales $\\mathcal M$ well above 100 TeV and sizable contributions from the triplets to electroweak symmetry breaking can be comfortably accommodated. We discuss the main phenomenological properties of the model and demonstrate that the departure...

  17. Sirenomelia in a Nigerian triplet: a case report

    Directory of Open Access Journals (Sweden)

    Wonodi Woroma

    2011-09-01

    Full Text Available Abstract Introduction Sirenomelia, also known as mermaid syndrome, is a very rare fatal congenital abnormality in which the legs are fused together, giving them the appearance of a mermaid's tail. It is commonly associated with abnormal kidney development, genital and rectal abnormalities. A handful of cases have been reported in other parts of the world, however, no cases have previously been reported in a Nigerian neonate. To the best of our knowledge, we believe that this is the first case reported from West Africa and in a triplet. Case presentation A 16-hour-old baby boy, the second of a set of Nigerian triplets, presented to our facility with fusion of the entire lower limbs, imperforate anus, indiscernible genital structures, single umbilical artery and a neural tube defect. His parents were from the Hausa ethnic group and not related. Conclusion Sirenomelia has not been previously described in a set of triplets, and it is hoped that this report from West Africa will give information about the non-racial predilection of this condition.

  18. Polaron pair mediated triplet generation in polymer/fullerene blends

    KAUST Repository

    Dimitrov, Stoichko D.

    2015-03-04

    Electron spin is a key consideration for the function of organic semiconductors in light-emitting diodes and solar cells, as well as spintronic applications relying on organic magnetoresistance. A mechanism for triplet excited state generation in such systems is by recombination of electron-hole pairs. However, the exact charge recombination mechanism, whether geminate or nongeminate and whether it involves spin-state mixing is not well understood. In this work, the dynamics of free charge separation competing with recombination to polymer triplet states is studied in two closely related polymer-fullerene blends with differing polymer fluorination and photovoltaic performance. Using time-resolved laser spectroscopic techniques and quantum chemical calculations, we show that lower charge separation in the fluorinated system is associated with the formation of bound electron-hole pairs, which undergo spin-state mixing on the nanosecond timescale and subsequent geminate recombination to triplet excitons. We find that these bound electron-hole pairs can be dissociated by electric fields.

  19. Spin and charge transport in hybrid triplet Josephson junctions

    International Nuclear Information System (INIS)

    We report a theoretical study on the spin and charge transport in hybrid triplet Josephson junctions, of which the triplet pair potentials could have both different orbital symmetries and spin states. Based on a lattice model and a Hamiltonian method, we find that the spin/charge supercurrent is proportional to sin2ψ with ψ being the macroscopic superconducting phase, coming from the second-order Josephson effect, when the orbital symmetries of pair potentials in the two triplet superconductors are orthogonal to each other. A dissipationless transverse spin current is also found flowing at the interface of the junction and its polarization points along the cross-product of two d vectors, which arises from the combined effect of the orthogonal orbital symmetries and misalignment of d vectors. In a special hybrid junction, where the zero-energy states are absent at the interface of the junction, there is no net spin supercurrent flowing through the junction although two d vectors can be perpendicular to each other, whereas a mode-resolved spin supercurrent is flowing in the system instead.

  20. Triplet-Polaron-Interaction-Induced Upconversion from Triplet to Singlet: a Possible Way to Obtain Highly Efficient OLEDs.

    Science.gov (United States)

    Obolda, Ablikim; Peng, Qiming; He, Chuanyou; Zhang, Tian; Ren, Jiajun; Ma, Hongwei; Shuai, Zhigang; Li, Feng

    2016-06-01

    Two D-A-type molecules, 4-N-[4-(9-phenylcarbazole)]-3,5-bis(4-diphenylamine)phenyl-4H-1,2,4-triazole and 4,4'-(9-(4-(1-phenyl-1H-phenanthro[9,10-d]imidazol-2-yl)phenyl)-9H-carbazole-3,6-diyl) bis-(N,N-diphenylaniline), are designed and synthesized. Organic lightemitting diodes based on them exhibit deep-blue emission and the singlet formation ratios are higher than the simple spin-statistics of 25%. A triplet-polaroninteraction-induced upconversion from triplet to singlet through a one-electron transfer mechanism is proposed, and is proven by magnetocurrent measurement and quantum-chemistry computation. PMID:27028509

  1. Synthesis, spectroscopic and thermal studies of Mg(II), Ca(II), Sr(II) and Ba(II) diclofenac sodium complexes as anti-inflammatory drug and their protective effects on renal functions impairment and oxidative stress

    Science.gov (United States)

    El-Megharbel, Samy M.; Hamza, Reham Z.; Refat, Moamen S.

    2015-01-01

    The main task of our present study is the preparation of newly complexes of Mg(II), Ca(II), Sr(II) and Ba(II) with diclofenac which succeeded to great extent in alleviating the side effects of diclofenac alone and ameliorating the kidney function parameters and antioxidant capacities with respect to diclofenac treated group alone. The Mg(II), Ca(II), Sr(II) and Ba(II) with diclofenac have been synthesized and characterized using infrared, electronic and 1H NMR spectral, thermogravimetric and conductivity measurements. The diclofenac ligand has been found to act as bidentate chelating agent. Diclofenac complexes coordinate through the oxygen's of the carboxyl group. The molar ratio chelation is 1:2 (M2+-dic) with general formula [M(dic)2(H2O)2]ṡnH2O. Antibacterial screening of the alkaline earth metal complexes against Escherichia coli (Gram - ve), Bacillus subtilis (Gram + ve) and anti-fungal (Asperagillus oryzae, Asperagillus niger, Asperagillus flavus) were investigated. The kidney functions in male albino rats were ameliorated upon treatment with metal complexes of dic, which are represented by decreasing the levels of urea and uric acid to be located within normal values. The other looks bright spot in this article is the assessment of antioxidant defense system including SOD, CAT and MDA with the help of Sr2+, Mg2+ and Ca2+-dic complexes. The hormones related to kidney functions and stresses have been greatly ameliorated in groups treated with dic complexes in comparable with dic treated group.

  2. Monochorionic triamniotic triplet pregnancy with a co-triplet fetus discordant for congenital cystic adenomatoid malformation of the lung

    Directory of Open Access Journals (Sweden)

    Ceylan Yavuz

    2005-04-01

    Full Text Available Abstract Background Spontaneous monochorionic triamniotic pregnancy is rare and is at increased risk for pregnancy complications. The presence of an anomalous fetus further complicates the management. Case presentation We present a case of monochorionic triamniotic triplet pregnancy diagnosed at 15 weeks of gestation with one fetus having developed a multicystic lung lesion, suggestive of congenital cystic adenomatoid malformation (CCAM. At 24 weeks, the largest cyst measured 10 mm in diameter. We managed the pregnancy conservatively and delivered three live male fetuses with birth weights 1560 g, 1580 g and 1590 g at 35 weeks of gestation. Two newborns were admitted to the neonatal intensive care unit with respiratory distress, the third one died due to sepsis 7 days postpartum. One of the newborns was discharged healthy at 24 days postpartum. The newborn with CCAM developed a pneumothorax on the right side, recovered after treatment, and was discharged after one month. Computerized tomography (CT of the infant at 3 months demonstrated two cystic lesions in the middle lobe of the right lung measuring 25 mm and 15 mm. A repeat CT of the infant at 6 months showed a 30 mm solitary cystic mass. Conclusion Monochorionic triamniotic triplet pregnancy with a co-triplet fetus discordant for CCAM, present rarely and can be managed conservatively. These findings may help in decision making and counselling of parents.

  3. Competition between triplet, singlet, and FFLO states in organic superconductors (TMTSF)2X under magnetic field

    International Nuclear Information System (INIS)

    We study the competition between triplet f-wave, singlet d-wave, and the FFLO state in a model for (TMTSF)2X using random phase approximation. The result suggests the possibility of singlet →FFLO→triplet transition upon increasing the magnetic field. The singlet →FFLO→triplet transition can appear in a large parameter regime on the space of the magnetic field and the off-site repulsions which induce the coexistence with 2kF charge and 2kF spin fluctuations, although decreasing the off-site repulsions suppresses the spin triplet f-wave pairing. We also show that the triplet component mixing increases in the FFLO state with increasing the magnetic field, and the off-site repulsions increase the mixing rate. The results seem to suggest that the large triplet mixing results in an enhanced tendency toward the FFLO state over the usual pairing state.

  4. Conjoined twins in a monochorionic triplet pregnancy after in vitro fertilization: a case report

    OpenAIRE

    Marzieh Talebian; Fatemeh Rahimi-Sharbaf; Mahboobeh Shirazi; Batool Teimoori; Narges Izadi-mood; Soheila Sarmadi

    2015-01-01

    Background: Monozygotic monochorionic triplet pregnancy with conjoined twins is a very rare condition and is associated with many complications. Case: In this study, we describe a monochorionic–diamniotic triplet pregnancy after in vitro fertilization with an intracytoplasmic sperm injection. At a gestational age of 6 weeks and 4 days of pregnancy one gestational sac was observed, and at a gestational age of 12 weeks and 2 days, triplets with conjoined twins were diagnosed. After consultin...

  5. Chirality and spin transformation of triplet Cooper pairs upon interaction with singlet condensate

    OpenAIRE

    Moor, Andreas; Volkov, Anatoly F.; Efetov, Konstantin B.

    2015-01-01

    We show that the fully polarized triplet s-wave component is characterized not only by the spin direction, but also by chirality. Interaction of a polarized triplet component and a singlet one results in creation of triplet Cooper pairs with opposite spin direction or of different chiralities. Such spin transformation leads to interesting phenomena in multiterminal magnetic Josephson junctions. We calculate the dc Josephson current $I_{\\text{J}}$ in a multiterminal Josephson contact of the S$...

  6. Excited triplet states as photooxidants in surface waters

    Science.gov (United States)

    Canonica, S.

    2012-12-01

    The chromophoric components of dissolved organic matter (DOM) are generally the main absorbers of sunlight in surface waters and therefore a source of transient reactants under irradiation. Such short-lived species can be relevant for the fate of various classes of chemical contaminants in the aquatic environment. The present contribution focuses on the role of excited triplet states of chromophoric DOM, 3CDOM*, as transient photooxidants initiating the transformation and degradation of organic chemical contaminants. An early study [1] indicated that 3CDOM* may play a dominant role in the photo-induced transformation of electron-rich phenols, a conclusion which was later fortified by the results of transient absorption investigations using aromatic ketones as model photosensitizers [2] and by a recent careful analysis of the effect of oxygen concentration on transformation rates [3]. The variety of aquatic contaminants shown to be affected by triplet-induced oxidation has kept increasing, phenylurea herbicides [4], sulfonamide antibiotics [5] and some phytoestrogens [6] being prominent examples. Recent research has shown that the triplet-induced transformation of specific contaminants, especially aromatic nitrogen compounds, could be inhibited by the presence of DOM, very probably due to its antioxidant moieties [7]. While such moieties are not relevant for the quenching of 3CDOM*, they are expected to react with it in a similar way as the studied contaminants. Analogous reactions can be postulated to occur in liquid or solid phases of the atmospheric environment, as demonstrated in the case of HONO formation [8]. References 1. Canonica, S.; Jans, U.; Stemmler, K.; Hoigné, J. Transformation kinetics of phenols in water: Photosensitization by dissolved natural organic material and aromatic ketones. Environ. Sci. Technol. 1995, 29 (7), 1822-1831. 2. Canonica, S.; Hellrung, B.; Wirz, J. Oxidation of phenols by triplet aromatic ketones in aqueous solution. J. Phys

  7. Semantic similarity: normative ratings for 185 Spanish noun triplets.

    Science.gov (United States)

    Moldovan, Cornelia D; Ferré, Pilar; Demestre, Josep; Sánchez-Casas, Rosa

    2015-09-01

    The present study introduces the first Spanish database with normative ratings of semantic similarity for 185 word triplets. Each word triplet is constituted by a target word (e.g., guisante [pea]) and two semantically related and nonassociatively related words: a word highly related in meaning to the target (e.g., judía [bean]), and a word less related in meaning to the target (e.g., patata [potato]). The degree of meaning similarity was assessed by 332 participants by using a semantic similarity rating task on a 9-point scale. Pairs having a value of semantic similarity ranging from 5 to 9 were classified as being more semantically related, whereas those with values ranging from 2 to 4.99 were considered as being less semantically related. The relative distance between the two pairs for the same target ranged from 0.48 to 5.07 points. Mean comparisons revealed that participants rated the more similar words as being significantly more similar in meaning to the target word than were the less similar words. In addition to the semantic similarity norms, values of concreteness and familiarity of each word in a triplet are provided. The present database can be a very useful tool for scientists interested in designing experiments to examine the role of semantics in language processing. Since the variable of semantic similarity includes a wide range of values, it can be used as either a continuous or a dichotomous variable. The full database is available in the supplementary materials. PMID:24984982

  8. Line-absorption of He-like triplet lines by Li-like ions: Caveats of using line ratios of triplets for plasma diagnostics

    CERN Document Server

    Mehdipour, M; Raassen, A J J

    2015-01-01

    He-like ions produce distinctive series of triplet lines under various astrophysical conditions. However, this emission can be affected by line-absorption from Li-like ions in the same medium. We investigate this absorption of He-like triplets and present the implications for diagnostics of plasmas in photoionisation equilibrium using the line ratios of the triplets. Our computations are carried out for the O VI and Fe XXIV absorption of the O VII and Fe XXV triplet emission lines, respectively. The fluorescent emission by the Li-like ions and continuum absorption of the He-like ion triplet lines are also investigated. We determine the absorption of the triplet lines as a function of Li-like ion column density and velocity dispersion of the emitting/absorbing medium. We find O VI line-absorption can significantly alter the O VII triplet line ratios in optically-thin plasmas, by primarily absorbing the intercombination lines and to lesser extent the forbidden line. Due to intrinsic line-absorption by O VI insi...

  9. H2 triplet states contribution to low-energy dissociative recombination of H2+

    International Nuclear Information System (INIS)

    Motivated by the observation of the predissociation of H2 triplet states in low vibrational levels, we evaluate the contribution of triplet dissociative states to the low-energy dissociative recombination of H2+ in vibrational levels where v = 0, 1. The triplet states contribute mainly via radial couplings between monoexcited Rydberg configurations without curve crossings. The total contribution of the six triplet states leading to dissociation in H(n = 1) + H(n = 2) is found to be smaller by at least one order of magnitude than the contribution of the lowest doubly excited singlet state, (2pσu)21 Σg+

  10. Competition between triplet, singlet and FFLO states in organic superconductors (TMTSF)2X under magnetic field

    International Nuclear Information System (INIS)

    We study the competition between triplet f-wave, singlet d-wave, and the FFLO state in a model for (TMTSF)2X using random phase approximation. The result suggests the possibility of the singlet→FFLO→triplet transition upon increasing the magnetic field. We also show that the triplet component mixing increases in the FFLO state with increasing the magnetic field, and the off-site repulsions increase the mixing rate. The results seem to suggest that the large triplet mixing results in an enhanced tendency toward the FFLO state over the usual pairing state.

  11. Capturing triplet emission in white organic light emitting devices

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Jai [Faculty of EHSE, School of Engineering and IT, B-purple-12, Charles Darwin University, Darwin, NT 0909 (Australia)

    2011-08-15

    The state-of-the art in the white organic light emitting devices (WOLEDs) is reviewed for further developments with a view to enhance the capture of triplet emission. In particular, applying the new exciton-spin-orbit-photon interaction operator as a perturbation, rates of spontaneous emission are calculated in a few phosphorescent materials and compared with experimental results. For iridium based phosphorescent materials the rates agree quite well with the experimental results. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  12. Quark fragmentation into spin-triplet $S$-wave quarkonium

    CERN Document Server

    Bodwin, Geoffrey T; Kim, U-Rae; Lee, Jungil

    2014-01-01

    We compute fragmentation functions for a quark to fragment to a quarkonium through an $S$-wave spin-triplet heavy quark-antiquark pair. We consider both color-singlet and color-octet heavy quark-antiquark ($Q\\bar Q$) pairs. We give results for the case in which the fragmenting quark and the quark that is a constituent of the quarkonium have different flavors and for the case in which these quarks have the same flavors. Our results for the sum over all spin polarizations of the $Q\\bar Q$ pairs confirm previous results. Our results for longitudinally polarized $Q\\bar Q$ pairs are new.

  13. Testing Higgs Triplet Model and Neutrino Mass Patterns

    CERN Document Server

    Chun, E J; Park, S C; Chun, Eung Jin; Lee, Kang Young; Park, Seong Chan

    2003-01-01

    The observed neutrino oscillation data might be explained by new physics at a TeV scale, which is testable in the future experiments. Among various possibilities, the low-energy Higgs triplet model is a prime candidate of such new physics since it predicts clean signatures of lepton flavor violating processes directly related to the neutrino masses and mixing. It is discussed how various neutrino mass patterns can be discriminated by examining the lepton flavor violating decays of charged leptons as well as the collider signatures of a doubly charged Higgs boson in the model.

  14. Triplet supercurrent in ferromagnetic Josephson junctions by spin injection

    Science.gov (United States)

    Mal'shukov, A. G.; Brataas, Arne

    2012-09-01

    We show that injecting nonequilibrium spins into the superconducting leads strongly enhances the stationary Josephson current through a superconductor-ferromagnet-superconductor junction. The resulting long-range supercurrent through a ferromagnet is carried by triplet Cooper pairs that are formed in s-wave superconductors by the combined effects of spin injection and exchange interaction. We quantify the exchange interaction in terms of Landau Fermi-liquid factors. The magnitude and direction of the long-range Josephson current can be manipulated by varying the angles of the injected polarizations with respect to the magnetization in the ferromagnet.

  15. Status of the LHC inner triplet quadrupole program at Fermilab

    CERN Document Server

    Andreev, N; Bauer, P; Bossert, R; Brandt, J; Carson, J; Caspi, S; Chichili, D R; Chiesa, L; Darve, C; Di Marco, J; Fehér, S; Ghosh, A; Glass, H; Huang, Y; Kerby, J S; Lamm, M J; Markarov, A A; McInturff, A D; Nicol, T H; Nobrega, A; Novitski, I; Ogitsu, T; Orris, D; Ozelis, J P; Page, T; Peterson, T; Rabehl, Roger Jon; Robotham, W; Sabbi, G L; Scanlan, R M; Schlabach, P; Sylvester, C D; Strait, J B; Tartaglia, M; Tompkins, J C; Velev, G V; Yadav, S; Zlobin, A V

    2001-01-01

    Fermilab, in collaboration with LBNL and BNL, is developing a quadrupole for installation in the interaction region inner triplets of the LHC. This magnet is required to have an operating gradient of 215 T/m across a 70 mm coil bore, and operates in superfluid helium at 1.9 K. A 2 m magnet program addressing mechanical, magnetic, quench protection, and thermal issues associated with the design was completed earlier this year, and production of the first full length, cryostatted prototype magnet is underway. This paper summarizes the conclusions of the 2 m program, and the design and status of the first full-length prototype magnet. (11 refs).

  16. Clarifying the mechanism of triplet-triplet annihilation in phosphorescent organic host-guest systems: A combined experimental and simulation study

    Science.gov (United States)

    Zhang, L.; van Eersel, H.; Bobbert, P. A.; Coehoorn, R.

    2016-05-01

    At high brightness, triplet-triplet annihilation (TTA) reduces the efficiency of organic light-emitting diodes. Triplet diffusion may considerably enhance this effect, which is otherwise limited by the rate of long-range interactions. Although its role can be clarified by studying the emissive dye concentration dependence of the TTA loss, we demonstrate here the practical applicability of a more direct method, requiring a study for only a single dye concentration. The method uses transient photoluminescence yield measurements, for a wide initial excitation density range. The analysis is applied to an iridium complex and is supported by the results of kinetic Monte Carlo simulations.

  17. Triplet Extended MSSM: Fine Tuning vs Perturbativity and Experiment

    CERN Document Server

    Bandyopadhyay, Priyotosh; Huitu, Katri; Keçeli, Aslı Sabancı

    2014-01-01

    In this study we investigate the phenomenological viability of the $Y=0$ Triplet Extended Supersymmetric Standard Model (TESSM) by comparing its predictions with the current Higgs data from ATLAS, CMS, and Tevatron, as well as the measured value of the $B_s\\to X_s \\gamma$ branching ratio. We scan numerically the parameter space for data points generating the measured particle mass spectrum and also satisfying current direct search constraints on new particles. We require all the couplings to be perturbative up to the scale $\\Lambda_{\\rm UV}=10^4$ TeV, by running them with newly calculated two loop beta functions, and find that TESSM retains perturbativity as long as $\\lambda$, the triplet coupling to the two Higgs doublets, is smaller than 1.34 in absolute value. For $|\\lambda|\\gtrsim 0.8$ we show that the fine-tuning associated to each viable data point can be greatly reduced as compared to values attainable in MSSM. Finally, we perform a fit by taking into account 58 Higgs physics observables along with $\\m...

  18. Efficient Design of Triplet Based Spike-Timing Dependent Plasticity

    CERN Document Server

    Azghadi, Mostafa Rahimi; Iannella, Nicolangelo; Abbott, Derek

    2012-01-01

    Spike-Timing Dependent Plasticity (STDP) is believed to play an important role in learning and the formation of computational function in the brain. The classical model of STDP which considers the timing between pairs of pre-synaptic and post-synaptic spikes (p-STDP) is incapable of reproducing synaptic weight changes similar to those seen in biological experiments which investigate the effect of either higher order spike trains (e.g. triplet and quadruplet of spikes), or, simultaneous effect of the rate and timing of spike pairs on synaptic plasticity. In this paper, we firstly investigate synaptic weight changes using a p-STDP circuit and show how it fails to reproduce the mentioned complex biological experiments. We then present a new STDP VLSI circuit which acts based on the timing among triplets of spikes (t-STDP) that is able to reproduce all the mentioned experimental results. We believe that our new STDP VLSI circuit improves upon previous circuits, whose learning capacity exceeds current designs due ...

  19. Mode of conception of triplets and high order multiple pregnancies.

    LENUS (Irish Health Repository)

    Basit, I

    2012-03-01

    A retrospective audit was performed of all high order multiple pregnancies (HOMPs) delivered in three maternity hospitals in Dublin between 1999 and 2008. The mode of conception for each pregnancy was established with a view to determining means of reducing their incidence. A total of 101 HOMPs occurred, 93 triplet, 7 quadruplet and 1 quintuplet. Information regarding the mode of conception was available for 78 (81%) pregnancies. Twenty eight (27.7%) were spontaneous, 34 (33.7%) followedlVF\\/ICSI\\/FET treatment (in-vitro fertilisation, intracytoplasmic sperm injection, frozen embryo transfer), 16 (15.8%) resulted from Clomiphene Citrate treatment and 6 (6%) followed ovulation induction with gonadotrophins. Triplet and HOMPs are a major cause of maternal, feta land neonatal morbidity. Many are iatrogenic, arising from fertility treatments including Clomiphene. Reducing the numbers of embryos transferred will address IVF\\/ICSI\\/FET-related multiple pregnancy rates and this is currently happening in Ireland. Clomiphene and gonadotrophins should only be prescribed when appropriate resources are available to monitor patients adequately.

  20. The Calcium Triplet metallicity calibration for galactic bulge stars

    CERN Document Server

    Vasquez, S; Hill, V; Gonzalez, O A; Saviane, I; Rejkuba, M; Battaglia, G

    2015-01-01

    We present a new calibration of the Calcium II Triplet equivalent widths versus [Fe/H], constructed upon K giant stars in the Galactic bulge. This calibration will be used to derive iron abundances for the targets of the GIBS survey, and in general it is especially suited for solar and supersolar metallicity giants, typical of external massive galaxies. About 150 bulge K giants were observed with the GIRAFFE spectrograph at VLT, both at resolution R~20,000 and at R~6,000. In the first case, the spectra allowed us to perform direct determination of Fe abundances from several unblended Fe lines, deriving what we call here high resolution [Fe/H] measurements. The low resolution spectra allowed us to measure equivalent widths of the two strongest lines of the near infrared Calcium II triplet at 8542 and 8662 A. By comparing the two measurements we derived a relation between Calcium equivalent widths and [Fe/H] that is linear over the metallicity range probed here, -1<[Fe/H]<+0.7. By adding a small second or...

  1. The impact of solvents on the singlet and triplet states of selected fluorine corroles - absorption, fluorescence, and optoacoustic studies.

    Science.gov (United States)

    Bursa, Bartosz; Wróbel, Danuta; Barszcz, Bolesław; Kotkowiak, Michał; Vakuliuk, Olena; Gryko, Daniel T; Kolanowski, Łukasz; Baraniak, Marek; Lota, Grzegorz

    2016-03-01

    This paper examines the influence of aprotic solvents on the spectroscopic properties as well as the energy deactivation of two free-base corrole dyes substituted with C6F5 and/or 4-NO2C6H4 groups. Absorption, fluorescence and laser-induced optoacoustic spectroscopy have been used to follow the singlet and triplet states of fluorine corroles belonging to the A2B and A3 type in toluene (TL), chloroform (CL), dimethylformamide (DMF), dimethyl sulfoxide (DMSO) and also in solvent mixtures. Changes in the absorption and fluorescence spectra are influenced by the type of solvent mixture. The fluorescence behaviors of the two investigated corroles were extremely different - fluorescence of the nitro-corrole in TL is dramatically quenched in the presence of DMF. In contrast, fluorescence quenching of fluorine corroles in DMF-TL mixtures is substantially weakened. Absorption, fluorescence, triplet population as well as singlet oxygen generation parameters are evaluated. The spectral experimental data are supported by quantum chemical calculations - time-dependent density functional theory (TD-DFT) and cyclic voltammetry experiments. The presented results are discussed from a viewpoint of aggregation, tautomerization, and deprotonation effects occurring in the corroles. PMID:26890961

  2. The role of triplet excitons in enhancing polymer solar cell efficiency: a photo-induced absorption study

    Science.gov (United States)

    Yang, Kai; Guha, Suchi

    2009-03-01

    Inclusion of heavy metal atoms in a polymer backbone allows transitions between the singlet and triplet manifolds. Interfacial dissociation of triplet excitons constitutes a viable mechanism for enhancing photovoltaic (PV) efficiencies in polymer heterojunction-based solar cells, which are now becoming feasible options for solar panels. The PV efficiency from polymer solar cells utilizing a ladder-type poly para phenylene polymer (PhLPPP) with trace quantity of Pd atoms and a fullerene derivative (PCBM) is almost 10 times more than its counterpart (MeLPPP) with no Pd atom. Evidence is presented for the formation of a weak ground-state charge-transfer complex (CTC) in the blended films of PhLPPP and PCBM, using photo- induced absorption (PIA) spectroscopy. Such complexes are not seen in the PIA spectrum of MeLPPP: PCBM blends. Possible mechanisms for the CTC state formation as well as the significance of this to the understanding and optimization of polymer blended solar cells will be discussed.

  3. Spectroscopic evidence for triplet excitation energy transfer among carotenoids in the LH2 complex from photosynthetic bacterium Rhodopseudomonas palustris

    Institute of Scientific and Technical Information of China (English)

    FENG Juan; WANG Qian; ZHANG Xujia; HUANG Youguo; AI Xicheng; ZHANG Xingkang; ZHANG Jianping

    2004-01-01

    The LH2 complex from Rhodopsudomonas (Rps.) palustris is unique in the heterogeneous carotenoid compositions. The dynamics of triplet excited state Carotenoids (3Car*) has been investigated by means of sub-microsecond time-resolved absorption spectroscopy both at physiological temperature (295 K) and at cryogenic temperature (77 K). Broad and asymmetric Tn←T1 transient absorption was observed at room temperature following the photo-excitation of Car at 532 nm, which suggests the contribution from various carotenoid compositions having different numbers of conjugated C=C double bonds (NC=C). The triplet absorption bands of different carotenoids, which superimposed at room temperature, could be clearly distinguished upon decreasing the temperature down to 77 K. At room temperature the shorter-wavelength side of the main Tn←T1 absorption band decayed rapidly to reach a spectral equilibration with a characteristic time constant of~1 μs, the same spectral dynamics, however, was not observed at 77 K. The aforementioned spectral dynamics can be explained in terms of the triplet-excitation transfer among heterogeneous carotenoid compositions. Global spectral analysis was applied to the time-resolved spectra at room temperature, which revealed two spectral components peaked at 545 and 565 nm, and assignable to the Tn←T1 absorption of Cars with NC=C=11 and NC=C=13, respectively. Surprisingly, the decay time constant of a shorter-con- jugated Car, I.e. 0.72 μs (aerobic) and 1.36 μs (anaerobic), is smaller than that of a longer-con- jugated Car, I.e. 2.12 μs (aerobic) and 3.75 μs (anaerobic), which is contradictory to the general rule of carotenoids and relative polyenes. The results are explained in terms of triplet-excitation transfer among different types of Cars. It is postulated that two Cars with different conjugation lengths coexist in an α,β-subunit in the LH2 complex.

  4. A top condensate model with a Higgs doublet and a Higgs triplet

    CERN Document Server

    Jora, Renata; Schechter, Joseph

    2013-01-01

    We reconsider top condensate models from the perspective that not only two quark composite fields can form but also four quark ones. We obtain a model which contains a Higgs doublet and a Higgs triplet, where one of the neutral components of the Higgs triplet identifies with the Higgs boson found at the LHC. We discuss some of the phenomenological consequences.

  5. Quenching of the triplet state of benzophenone by lanthanide 1,3-diketonate chelates in solutions

    International Nuclear Information System (INIS)

    The phosphorescence of benzophenone in benzene and acetonitrile was quenched by several lanthanide (Sm, Eu, Gd, Tb and Dy) acetylacetonate chelates. The results of Stern-Volmer analysis including the quenching of benzophenone triplet and sensitization of lanthanide emission indicate that the quenching process occurs by the energy transfer mechanism via the excited triplet state of the ligand. (Author)

  6. QUANTUM CHEMICAL STUDY GEOMETRICAL AND ELECTRONIC STRUCTURES AMINONITRENE IN SINGLET AND TRIPLET STATES

    OpenAIRE

    Ostapenko, Gennady; Troshina, Marina

    2014-01-01

    Ab initio methods MO LCAO SCF using wide basis sets (6-311G( 3d, 2p ), cc-pVTz) calculated geometric and electronic parameters of the singlet and triplet forms aminonitrene, force field parameters and values ​​of the oscillation frequency, as well as the thermodynamic parameters obtained stability of the singlet and triplet forms aminonitrene.

  7. Observation of rogue wave triplets in water waves

    Energy Technology Data Exchange (ETDEWEB)

    Chabchoub, A., E-mail: achabchoub@swin.edu.au [Centre for Ocean Engineering Science and Technology, Swinburne University of Technology, Hawthorn, Victoria 3122 (Australia); Department of Mechanical Engineering, Imperial College London, London SW7 2AZ (United Kingdom); Akhmediev, N. [Optical Sciences Group, Research School of Physics and Engineering, The Australian National University, Canberra, ACT 0200 (Australia)

    2013-11-15

    Doubly-localised breather solutions of the nonlinear Schrödinger equation (NLS) are considered to be appropriate models to describe rogue waves in water waves as well as in other nonlinear dispersive media such as fibre optics. Within the hierarchy of this type of formations, the Peregrine breather (PB) is the lowest-order rational solution. Higher-order solutions of this kind may be understood as a nonlinear superposition of fundamental Peregrine solutions. These superpositions are nontrivial and admit only a fixed well prescribed number of elementary breathers in each higher-order solution. Here, we report first observation of second-order solution which in reality is a triplet of rogue waves.

  8. Mother-daughter in vitro fertilization triplet surrogate pregnancy.

    Science.gov (United States)

    Michelow, M C; Bernstein, J; Jacobson, M J; McLoughlin, J L; Rubenstein, D; Hacking, A I; Preddy, S; Van der Wat, I J

    1988-02-01

    A successful triplet pregnancy has been established in a surrogate gestational mother following the transfer of five embryos fertilized in vitro. The oocytes were donated by her biological daughter, and the sperm obtained from the daughter's husband. The daughter's infertility followed a total abdominal hysterectomy performed for a postpartum hemorrhage as a result of a placenta accreta. Synchronization of both their menstrual cycles was obtained using oral contraceptive suppression for 2 months, followed by stimulation of both the surrogate gestational mother and her daughter such that embryo transfer would occur at least 48 hr after the surrogate gestational mother's own ovulation. This case raises a number of medical, social, psychological, and ethical issues. PMID:3367072

  9. Peripartum cardiomyopathy: a case of patient with triplet pregnancy.

    Science.gov (United States)

    Kotlica, B Kastratović; Cetković, A; Plesinac, S; Macut, D; Asanin, M

    2016-01-01

    Peripartum cardiomyopathy (PPCM) is a rare but potentially devastating complication of pregnancy associated with heart failure due to left ventricular systolic dysfunction occurring within the last month of pregnancy and five month postpartum with no obvious other cause of heart failure and no pre-existing heart disease. In the present case report the authors present a woman who developed PPCM on the day after she delivered by cesarean section in 35th weeks of gestation of triplet pregnancy conceived after ovarian stimulation and insemination. A treatment with diuretics, ACE inhibitors, antiarrhythmics, low weight heparin, antibiotics and bromocriptine was applied and resulted in complete recovery. In conclusion, timely detection and initiation of treatment are important factors for complete recovery of patients with PPCM. PMID:27132428

  10. Discovery of a tidal dwarf galaxy in the Leo Triplet

    International Nuclear Information System (INIS)

    We report the discovery of a dwarf galaxy in the Leo Triplet. Analysis of the neutral hydrogen distribution shows that it rotates independently of the tidal tail of NGC 3628, with a radial velocity gradient of 35-40 km s–1 over approximately 13 kpc. The galaxy has an extremely high neutral gas content, accounting for a large amount of its total dynamic mass and suggesting a low amount of dark matter. It is located at the tip of the gaseous tail, which strongly suggests a tidal origin. If this is the case, it would be one of the most confident and nearest (to the Milky Way) detections of a tidal dwarf galaxy and, at the same time, the object most detached from its parent galaxy (≈140 kpc) of this type.

  11. Model for Triplet State Engineering in Organic Light Emitting Diodes

    CERN Document Server

    Prodhan, Suryoday; Ramasesha, S

    2014-01-01

    Engineering the position of the lowest triplet state (T1) relative to the first excited singlet state (S1) is of great importance in improving the efficiencies of organic light emitting diodes and organic photovoltaic cells. We have carried out model exact calculations of substituted polyene chains to understand the factors that affect the energy gap between S1 and T1. The factors studied are backbone dimerisation, different donor-acceptor substitutions and twisted geometry. The largest system studied is an eighteen carbon polyene which spans a Hilbert space of about 991 million. We show that for reverse intersystem crossing (RISC) process, the best system involves substituting all carbon sites on one half of the polyene with donors and the other half with acceptors.

  12. Spin-triplet supercurrent through inhomogeneous ferromagnetic trilayers

    Science.gov (United States)

    Alidoust, Mohammad; Linder, Jacob

    2010-12-01

    Motivated by a recent experiment [J. W. A. Robinson, J. D. S. Witt, and M. G. Blamire, Science 329, 5987 (2010)10.1126/science.1189246], we report here the possibility of establishing a long-range spin-triplet supercurrent through an inhomogeneous ferromagnetic region consisting of a Ho∣Co∣Ho trilayer sandwiched between conventional s -wave superconducting leads. We utilize a full numerical solution in the diffusive regime of transport and study the behavior of the supercurrent for various experimentally realistic configurations of the ferromagnetic trilayer. We obtain qualitatively very good agreement with experimental data regarding the behavior of the supercurrent as a function of the width of the Co layer, LCo . Moreover, we find a synthesis of 0-π oscillations with superimposed rapid oscillations when varying the width of the Ho layers symmetrically, which pertain specifically to the spiral magnetization texture in Ho. Although we are not able to reproduce the anomalous sharp peaks in the supercurrent vs Ho-layer thickness observed experimentally in this regime, the results obtained are quite sensitive to the exact magnetization profile in the Ho layers. This might be the reason for the discrepancy between our results and the experimental reported data for this particular aspect. We also investigate the supercurrent in a system where the intrinsically inhomogeneous Ho ferromagnets are replaced with domain-wall ferromagnets and find similar behavior as in the Ho∣Co∣Ho case. Furthermore, we propose magnetic Josephson junctions including only a domain-wall ferromagnet and a homogeneous ferromagnetic layer. The hybrid structure not only is simple regarding the magnetization profile but also offers a tunable long-range spin-triplet supercurrent. Finally, we discuss some experimental aspects of our findings.

  13. Comment on "Triplet-to-Singlet Exciton Formation in poly(p-phenylene-vinylene) Light-Emitting Diodes"

    OpenAIRE

    Mazumdar, S.; Das, Mousumi; Ramasesha, S.

    2003-01-01

    The low-lying singlet and triplet spectrum in conjugated polymers clearly show that the mechanism proposed by Lin et al. to explain their electric field dependence of singlet to triplet yield ratios is wrong. This comment, from theoretical spectrum obtained for long polyenes, shows that the phonon bottleneck proposed by Lin et al. for triplets in polyenes cannot exist.

  14. Physicochemical impact studies of gamma rays on "aspirin" analgesics drug and its metal complexes in solid form: Synthesis, spectroscopic and biological assessment of Ca(II), Mg(II), Sr(II) and Ba(II) aspirinate complexes

    Science.gov (United States)

    Refat, Moamen S.; Sharshar, T.; Elsabawy, Khaled M.; Heiba, Zein K.

    2013-09-01

    Metal aspirinate complexes, M2(Asp)4, where M is Mg(II), Ca(II), Sr(II) or Ba(II) are formed by refluxed of aspirin (Asp) with divalent non-transition metal ions of group (II) and characterized by elemental analysis and spectroscopic measurements (infrared, electronic, 1H NMR, Raman, X-ray powder diffraction and scanning electron microscopy). Elemental analysis of the chelates suggests the stoichiometry is 1:2 (metal:ligand). Infrared spectra of the complexes agree with the coordination to the central metal atom through three donation sites of two oxygen atoms of bridge bidentate carboxylate group and oxygen atom of sbnd Cdbnd O of acetyl group. Infrared spectra coupled with the results of elemental analyzes suggested a distorted octahedral structure for the M(II) aspirinate complexes. Gamma irradiation was tested as a method for stabilization of aspirin as well as their complexes. The effect of gamma irradiation, with dose of 80 Gy, on the properties of aspirinate complexes was studied. The aspirinate chelates have been screened for their in vitro antibacterial activity against four bacteria, gram-positive (Bacillus subtilis and Staphylococcus aureus) and gram-negative (Escherichia coli and Pseudomonas aeruginosa) and two strains of fungus (Aspergillus flavus and Candida albicans). The metal chelates were shown to possess more antibacterial activity than the free aspirin chelate.

  15. Multi-Lepton Signatures of the Triplet Like Charged Higgs at the LHC

    CERN Document Server

    Bandyopadhyay, Priyotosh; Keceli, Asli Sabanci

    2014-01-01

    We study multi-lepton signatures of the triplet like charged Higgs at the LHC in the context of $Y=0$ triplet extended supersymmetric model (TESSM). In TESSM the $h_i^\\pm W^\\mp Z$ coupling appears at tree level when the triplet vacuum expectation value is nonzero, and because of the coupling the charged Higgs decay channels as well as the production channels can dramatically change at the LHC. We show that for the triplet dominated charged Higgs the main production channels are no longer through the top decay or $gg$ and $gb$ fusions since these are very suppressed due to the lack of triplet-SM fermion coupling. In the numerical analysis, we consider also other possible production channels some of which have additional contributions from the diagrams containing $h_i^\\pm W^\\mp Z$ vertex. We investigate the decay channels of a triplet like light charged Higgs ($m_{h_1^{\\pm}}\\leq 200$ GeV) and show that depending on the triplet component, the charged Higgs can substantially decay to $W^\\pm Z$. We further examine...

  16. Isolation of proximity-induced triplet pairing channel in a superconductor/ferromagnet spin valve

    OpenAIRE

    Leksin, P. V.; Garifyanov, N. N.; Kamashev, A. A.; Validov, A. A.; Fominov, Ya. V.; Schumann, J.; KATAEV V.; J. Thomas; Büchner, B.; Garifullin, I. A.

    2015-01-01

    We have studied the proximity-induced superconducting triplet pairing in CoO$_x$/Py1/Cu/Py2/Cu/Pb spin-valve structure (where Py = Ni$_{0.81}$Fe$_{0.19}$). By optimizing the parameters of this structure we found a triplet channel assisted full switching between the normal and superconducting states. To observe an "isolated" triplet spin-valve effect we exploited the oscillatory feature of the magnitude of the ordinary spin-valve effect $\\Delta T_c$ in the dependence of the Py2-layer thickness...

  17. Asymptomatic (Subclinical Meningitis in One of Premature Triplets with Simultaneous Enteroviral Meningitis: A Case Report

    Directory of Open Access Journals (Sweden)

    Ashish Gupta

    2012-11-01

    Full Text Available Most enterovirus infection in the neonate and young infant is asymptomatic, but serious disease may occur, especially if acquired perinatally. We report the first case, to our knowledge, of asymptomatic enterovirus aseptic meningitis, and of concurrent enterovirus aseptic meningitis in premature triplets. Ten-week-old, 31-week-estimated gestational age premature triplet boys were diagnosed with enterovirus aseptic meningitis on the same day. Two of the triplets developed symptoms on the day of admission, while the third remained symptom free throughout the infection. All three recovered completely and are healthy more than a decade later.

  18. Classical and quantum 'EPR'-spin correlations in the triplet state

    International Nuclear Information System (INIS)

    Quantum correlations and joint probabilities in the triplet state as well as the correlations of components of two correlated classical spin vectors, are evaluated. Correlations in the states with |Stotz|=1 are different from correlations in the state with Stotz=0 which may serve to distinguish different states of the triplet. As in the singlet case, we can reproduce quantum correlations by correlated classical spin vectors which also provide a precision of the notion of ''parallel spins''. Triplet state correlations could in principle be measured, for example, in the decay reaction J/ψ → e+e- for which there is a sufficiently large branching ratio. (author). 12 refs

  19. Orbifold Grand Unification: A Solution to the Doublet-Triplet Problem

    CERN Document Server

    Jia, Bei

    2014-01-01

    To solve the doublet-triplet splitting problem in SU(5) grand unified theories, we propose a four dimensional orbifold grand unified theory by acting Z2 on the SU(5) gauge group. Without an adjoint Higgs, the orbifold procedure breaks the SU(5) gauge symmetry down to the standard model gauge group, and removes the triplet component of the fundamental SU(5) Higgs. In the supersymmetric framework, we show that the orbifold procedure removes two triplet superfields of the Higgs multiplets and leaves us with the minimal supersymmetric standard model, which also solves the hierarchy problem and realizes gauge coupling unification. We also discuss possible UV completions of the orbifold theories.

  20. Formation of the O I resonance triplet and intercombination doublet in the solar chromosphere

    Science.gov (United States)

    Skelton, D. L.; Shine, R. A.

    1982-01-01

    Spectrum synthesis calculations are presented for the O I resonance triplet at 1304 A and the intercombination doublet at 1358 A for the solar atmosphere and several variants, allowing for triplet fluorescence by the Ly-beta emission of H I. Profiles, synthesized from a seven-level plus continuum O I atom are compared to observations taken with the high-resolution spectrometer on OSO 8. It is found that the O I triplet emission is dominated by the Ly-beta fluorescence and that the agreement between observations and profiles computed with current chromospheric models is much improved over earlier studies.

  1. A comparative study of caffeine and theophylline binding to Mg(II) and Ca(II) ions: studied by FTIR and UV spectroscopic methods

    Science.gov (United States)

    Nafisi, Shohreh; Shamloo, Delaram Sadraii; Mohajerani, Nasser; Omidi, Akram

    2002-08-01

    The interactions of calcium and magnesium ions with caffeine and theophylline have been investigated in aqueous solution at physiological pH. Fourier Transform infrared (FTIR) spectroscopy and absorption spectra were used to determine the cation binding mode and the association constants. Our spectroscopic results showed that calcium and magnesium ions do not complex with caffeine strongly and the weak interactions between caffeine and Mg 2+ and Ca 2+ might be via O6 atom. In Ca 2+-theophylline complex, binding between Ca 2+ with CO and N7 is observed, however in Mg 2+-theophylline complex, binding between Mg 2+ and N7 is more likely. The k values of these complexes are as follows: k(caffeine-Ca)=29.8 M -1, k(caffeine-Mg)=22.4 M -1, k(theophylline-Ca)=59.8 M -1 and k(theophylline-Mg)=33.8 M -1. These values are evidence for a weak cation interaction in these metal complexes.

  2. Singlet-Triplet Gaps of Cobalt Nitrosyls: Insights from Tropocoronand Complexes.

    Science.gov (United States)

    Hopmann, Kathrin H; Conradie, Jeanet; Tangen, Espen; Tonzetich, Zachary J; Lippard, Stephen J; Ghosh, Abhik

    2015-08-01

    A density functional theory (DFT) study of {CoNO}(8) cobalt nitrosyl complexes containing the [n,n]tropocoronand ligand (TC-n,n) has revealed a sharp reduction of singlet-triplet gaps as the structures change from near-square-pyramidal (for n = 3) to trigonal-bipyramidal with an equatorial NO (for n = 5, 6). An experimental reinvestigation of [Co(TC-3,3)(NO)] has confirmed that it is not paramagnetic, as originally reported, but diamagnetic, like all other {CoNO}(8) complexes. Furthermore, DFT calculations indicate a substantial singlet-triplet gap of about half an eV or higher for this complex. At the other end of the series, low-energy, thermally accessible triplet states are predicted for [Co(TC-6,6)(NO)]. Enhanced triplet-state reactivity may well provide a partial explanation for the failure to isolate this compound as a stable species. PMID:26203786

  3. The structure of strongly additive states and Markov triplets on the CAR algebra

    CERN Document Server

    Jencova, Anna

    2010-01-01

    We find a characterization of states satisfying equality in strong subadditivity of entropy and of Markov triplets on the CAR algebra. For even states, a more detailed structure of the density matrix is given.

  4. Conjoined twins in a monochorionic triplet pregnancy after in vitro fertilization: a case report

    Directory of Open Access Journals (Sweden)

    Marzieh Talebian

    2015-11-01

    Full Text Available Background: Monozygotic monochorionic triplet pregnancy with conjoined twins is a very rare condition and is associated with many complications. Case: In this study, we describe a monochorionic–diamniotic triplet pregnancy after in vitro fertilization with an intracytoplasmic sperm injection. At a gestational age of 6 weeks and 4 days of pregnancy one gestational sac was observed, and at a gestational age of 12 weeks and 2 days, triplets with conjoined twins were diagnosed. After consulting with the parents, they chose fetal reduction of the conjoined twins. Selective feticide was successfully performed by radiofrequency ablation at 16 weeks of pregnancy. Unfortunately, the day after the procedure, the membrane ruptured, and 1 week later, all fetuses and placenta were spontaneously aborted. Conclusion: Monochorionic triplet pregnancy with conjoined twins is very rare. These pregnancies are associated with very serious complications. Intra cytoplasmic sperm injection increases the rate of monozygotic twinning and conjoined twins. Counseling with parents before IVF is very important.

  5. Hadronic production of light color-triplet Higgs bosons: An alternative signature for grand unified theories

    International Nuclear Information System (INIS)

    The conventional signature for grand unified theories (GUTs) is proton decay. Recently, some models in extra dimensions or with specific discrete symmetries, which aim at solving the doublet-triplet problem, allow a color triplet in the TeV mass region by suppressing the Yukawa couplings of the triplets to matter fermions. We study the hadronic production and detection of these TeV colored Higgs bosons as an alternative signature for GUTs; they would behave like massive stable charged particles in particle detectors, producing the striking signature of a charged track in the central tracking system and being ionized in the outer muon chamber. We find that the CERN LHC is sensitive to a colored Higgs boson up to about 1.5 TeV. If the color triplets are stable on a cosmological time scale, they may constitute an interesting fraction of the dark matter

  6. Amplitude Control of the Spin-Triplet Supercurrent in S /F /S Josephson Junctions

    Science.gov (United States)

    Martinez, William M.; Pratt, W. P.; Birge, Norman O.

    2016-02-01

    Josephson junctions made with conventional s -wave superconductors and containing multiple layers of ferromagnetic materials can carry spin-triplet supercurrent in the presence of certain types of magnetic inhomogeneity. In junctions containing three ferromagnetic layers, the triplet supercurrent is predicted to be maximal when the magnetizations of the adjacent layers are orthogonal, and zero when the magnetizations of any two adjacent layers are parallel. Here we demonstrate on-off control of the spin-triplet supercurrent in such junctions, achieved by rotating the magnetization direction of one of the three layers by 90°. We obtain "on-off" ratios of 5, 7, and 19 for the supercurrent in the three samples that have been studied so far. These observations directly confirm one of the most salient predictions of the theory, and they pave the way for applications of spin-triplet Josephson junctions in the nascent area of "superconducting spintronics".

  7. Efficient photon triplet generation in integrated nanophotonic waveguides.

    Science.gov (United States)

    Moebius, Michael G; Herrera, Felipe; Griesse-Nascimento, Sarah; Reshef, Orad; Evans, Christopher C; Guerreschi, Gian Giacomo; Aspuru-Guzik, Alán; Mazur, Eric

    2016-05-01

    Generation of entangled photons in nonlinear media constitutes a basic building block of modern photonic quantum technology. Current optical materials are severely limited in their ability to produce three or more entangled photons in a single event due to weak nonlinearities and challenges achieving phase-matching. We use integrated nanophotonics to enhance nonlinear interactions and develop protocols to design multimode waveguides that enable sustained phase-matching for third-order spontaneous parametric down-conversion (TOSPDC). We predict a generation efficiency of 0.13 triplets/s/mW of pump power in TiO2-based integrated waveguides, an order of magnitude higher than previous theoretical and experimental demonstrations. We experimentally verify our device design methods in TiO2 waveguides using third-harmonic generation (THG), the reverse process of TOSPDC that is subject to the same phase-matching constraints. We finally discuss the effect of finite detector bandwidth and photon losses on the energy-time coherence properties of the expected TOSPDC source. PMID:27137604

  8. The 3-3-1 model with inert scalar triplet

    CERN Document Server

    Dong, P V; Soa, D V

    2013-01-01

    We show that the typical 3-3-1 models are only self-consistent if they contain interactions explicitly violating the lepton number. The 3-3-1 model with right-handed neutrinos can by itself work as an economical 3-3-1 model as a natural recognition of the above criteria while it also results an inert scalar triplet (\\eta) responsible for dark matter. This is ensured by a Z_2 symmetry (assigned so that only \\eta is odd while all other multiplets which perform the economical 3-3-1 model are even), which is not broken by the vacuum. The dark matter candidate (H_\\eta) contained in \\eta transforms as a singlet under the standard model symmetry and being naturally heavy. The H_\\eta relic density and direct detection cross-section will get right values when the H_\\eta mass is in TeV range as expected. The model predicts the H_\\eta mass m_{H_\\eta}=\\la_5 \\times 2 TeV and the H_\\eta-nucleon scattering cross-section \\sigma_{H_\\eta-N}=1.56 \\times 10^{-44} cm^2, provided that the new neutral Higgs boson is heavy enough th...

  9. Potential energy surface of triplet N2O2

    International Nuclear Information System (INIS)

    We present a global ground-state triplet potential energy surface for the N2O2 system that is suitable for treating high-energy vibrational-rotational energy transfer and collision-induced dissociation. The surface is based on multi-state complete-active-space second-order perturbation theory/minimally augmented correlation-consistent polarized valence triple-zeta electronic structure calculations plus dynamically scaled external correlation. In the multireference calculations, the active space has 14 electrons in 12 orbitals. The calculations cover nine arrangements corresponding to dissociative diatom-diatom collisions of N2, O2, and nitric oxide (NO), the interaction of a triatomic molecule (N2O and NO2) with the fourth atom, and the interaction of a diatomic molecule with a single atom (i.e., the triatomic subsystems). The global ground-state potential energy surface was obtained by fitting the many-body interaction to 54 889 electronic structure data points with a fitting function that is a permutationally invariant polynomial in terms of bond-order functions of the six interatomic distances

  10. Potential energy surface of triplet N2O2.

    Science.gov (United States)

    Varga, Zoltan; Meana-Pañeda, Rubén; Song, Guoliang; Paukku, Yuliya; Truhlar, Donald G

    2016-01-14

    We present a global ground-state triplet potential energy surface for the N2O2 system that is suitable for treating high-energy vibrational-rotational energy transfer and collision-induced dissociation. The surface is based on multi-state complete-active-space second-order perturbation theory/minimally augmented correlation-consistent polarized valence triple-zeta electronic structure calculations plus dynamically scaled external correlation. In the multireference calculations, the active space has 14 electrons in 12 orbitals. The calculations cover nine arrangements corresponding to dissociative diatom-diatom collisions of N2, O2, and nitric oxide (NO), the interaction of a triatomic molecule (N2O and NO2) with the fourth atom, and the interaction of a diatomic molecule with a single atom (i.e., the triatomic subsystems). The global ground-state potential energy surface was obtained by fitting the many-body interaction to 54 889 electronic structure data points with a fitting function that is a permutationally invariant polynomial in terms of bond-order functions of the six interatomic distances. PMID:26772574

  11. Antiferromagnetism in Pr3In: Singlet/triplet physics withfrustration

    Energy Technology Data Exchange (ETDEWEB)

    Christianson, A.D.; Lawrence, J.M.; Zarestky, J.L.; Suzuki, H.; Thompson, J.D.; Hundley, M.F.; Sarrao, J.L.; Booth, C.H.; Antonio, D.; Cornelius, A.L.

    2004-11-18

    We present neutron diffraction, magnetic susceptibility and specific heat data for a single-crystal sample of the cubic (Cu{sub 3}Au structure) compound Pr{sub 3}In. This compound is believed to have a singlet ({Lambda}{sub 1}) groundstate and a low-lying triplet ({Lambda}{sub 4}) excited state. In addition, nearest-neighbor antiferromagnetic interactions are frustrated in this structure. Antiferromagnetic order occurs below T{sub N} = 12K with propagation vector (0, 0, 0.5 {center_dot}{delta}) where {delta} {approx} 1/12. The neutron diffraction results can be approximated with the following model: ferromagnetic sheets from each of the three Pr sites alternate in sign along the propagation direction with a twelve-unit-cell square-wave modulation. The three moments of the unit cell of 1 {micro}{sub B} magnitude are aligned so as to sum to zero as expected for nearest-neighbor antiferromagnetic interactions on a triangle. The magnetic susceptibility indicates that in addition to the antiferromagnetic transition at 12K, there is a transition near 70K below which there is a small (0.005 {micro}{sub B}) ferromagnetic moment. There is considerable field and sample dependence to these transitions. The specific heat data show almost no anomaly at T{sub N} = 12K. This may be a consequence of the induced moment in the {Lambda}{sub 1} singlet, but may also be a sample-dependent effect.

  12. Radiative corrections to the Higgs couplings in the triplet model

    International Nuclear Information System (INIS)

    The feature of extended Higgs models can appear in the pattern of deviations from the Standard Model (SM) predictions in coupling constants of the SM-like Higgs boson (h). We can thus discriminate extended Higgs models by precisely measuring the pattern of deviations in the coupling constants of h, even when extra bosons are not found directly. In order to compare the theoretical predictions to the future precision data at the ILC, we must evaluate the theoretical predictions with radiative corrections in various extended Higgs models. In this paper, we give our comprehensive study for radiative corrections to various Higgs boson couplings of h in the minimal Higgs triplet model (HTM). First, we define renormalization conditions in the model, and we calculate the Higgs coupling; gγγ, hWW, hZZ and hhh at the one loop level. We then evaluate deviations in coupling constants of the SM-like Higgs boson from the predictions in the SM. We find that one-loop contributions to these couplings are substantial as compared to their expected measurement accuracies at the ILC. Therefore the HTM has a possibility to be distinguished from the other models by comparing the pattern of deviations in the Higgs boson couplings.

  13. An atlas of Calcium triplet spectra of active galaxies

    CERN Document Server

    Garcia-Rissmann, A; Asari, N V; Fernandes, R C; Schmitt, H; González-Delgado, R M; Storchi-Bergmann, T

    2005-01-01

    We present a spectroscopic atlas of active galactic nuclei covering the region around the 8498, 8542, 8662 Calcium triplet (CaT) lines. The sample comprises 78 objects, divided into 43 Seyfert 2s, 26 Seyfert 1s, 3 Starburst and 6 normal galaxies. The spectra pertain to the inner ~300 pc in radius, and thus sample the central kinematics and stellar populations of active galaxies. The data are used to measure stellar velocity dispersions (sigma_star) both with cross-correlation and direct fitting methods. These measurements are found to be in good agreement with each-other and with those in previous studies for objects in common. The CaT equivalent width is also measured. We find average values and sample dispersions of W_CaT of 4.6+/-2.0, 7.0 and 7.7+/-1.0 angstrons for Seyfert 1s, Seyfert 2s and normal galaxies, respectively. We further present an atlas of [SIII]\\lambda 9069 emission line profiles for a subset of 40 galaxies. These data are analyzed in a companion paper which addresses the connection between ...

  14. Noise filtering of composite pulses for singlet-triplet qubits.

    Science.gov (United States)

    Yang, Xu-Chen; Wang, Xin

    2016-01-01

    Semiconductor quantum dot spin qubits are promising candidates for quantum computing. In these systems, the dynamically corrected gates offer considerable reduction of gate errors and are therefore of great interest both theoretically and experimentally. They are, however, designed under the static-noise model and may be considered as low-frequency filters. In this work, we perform a comprehensive theoretical study of the response of a type of dynamically corrected gates, namely the supcode for singlet-triplet qubits, to realistic 1/f noises with frequency spectra 1/ω(α). Through randomized benchmarking, we have found that supcode offers improvement of the gate fidelity for α  1 and the improvement becomes exponentially more pronounced with the increase of the noise exponent in the range 1  α ≤ 3 studied. On the other hand, for small α, supcode will not offer any improvement. The δJ-supcode, specifically designed for systems where the nuclear noise is absent, is found to offer additional error reduction than the full supcode for charge noises. The computed filter transfer functions of the supcode gates are also presented. PMID:27383129

  15. Radiative corrections to the Higgs couplings in the triplet model

    CERN Document Server

    Kikuchi, Mariko

    2013-01-01

    The feature of extended Higgs models can appear in the pattern of deviations from the Standard Model (SM) predictions in coupling constants of the SM-like Higgs boson ($h$). We can thus discriminate extended Higgs models by precisely measuring the pattern of deviations in the coupling constants of $h$, even when extra bosons are not found directly. In order to compare the theoretical predictions to the future precision data at the ILC, we must evaluate the theoretical predictions with radiative corrections in various extended Higgs models. In this talk, we give our comprehensive study for radiative corrections to various Higgs boson couplings of $h$ in the minimal Higgs triplet model (HTM). First, we define renormalization conditions in the model, and we calculate the Higgs coupling; $g\\gamma\\gamma, hWW, hZZ$ and $hhh$ at the one loop level. We then evaluate deviations in coupling constants of the SM-like Higgs boson from the predictions in the SM. We find that one-loop contributions to these couplings are su...

  16. Autler-Townes multiplet spectroscopy

    CERN Document Server

    Ghafoor, Fazal

    2013-01-01

    We extend the concepts of the Autler-Townes doublet and triplet spectroscopy to quartuplet, quintuplet and suggest linkages in sodium atom in which to display these spectra. We explore the involved fundamental processes of quantum interference of the corresponding spectroscopy by examining the Laplace transform of the corresponding state-vector subjected to steady coherent illumination in the rotating wave approximation and Weisskopf-Wigner treatment of spontaneous emission as a simplest probability loss. In the quartuplet, four fields interact appropriately and resonantly with the five-level atom. The spectral profile of the single decaying level, upon interaction with three other levels, splits into four destructively interfering dressed states generating three dark lines in the spectrum. These dark lines divide the spectrum into four spectral components (bright lines) whose widths are effectively controlled by the relative strength of the laser fields and the relative width of the single decaying level. We...

  17. Sensitized Triplet Formation of Chlorophyll-A and beta-Carotene

    DEFF Research Database (Denmark)

    Jensen, Nina Mejlhede; Wilbrandt, Robert Walter; Pagsberg, Palle Bjørn

    1980-01-01

    The naphthalene-sensitized formation of triplet excited chlorophyll-a (Chl-a) and all-transß-carotene has been studied by pulse radiolysis. The rate constants for transfer of triplet energy from naphthalene to Chl-a and all-transß-carotene in benzene at 25°C are (3.6 ± 0.6)·109M-1 s-1 and (10.7 ±...

  18. Spin-triplet supercurrent carried by quantum Hall edge states through a Josephson junction

    OpenAIRE

    van Ostaay, J. A. M.; Akhmerov, A. R.; Beenakker, C. W. J.

    2011-01-01

    We show that a spin-polarized Landau level in a two-dimensional electron gas can carry a spin-triplet supercurrent between two spin-singlet superconductors. The supercurrent results from the interplay of Andreev reflection and Rashba spin-orbit coupling at the normal--superconductor (NS) interface. We contrast the current-phase relationship and the Fraunhofer oscillations of the spin-triplet and spin-singlet Josephson effect in the lowest Landau level, and find qualitative differences.

  19. Spin-triplet supercurrent carried by quantum Hall edge states through a Josephson junction

    Science.gov (United States)

    van Ostaay, J. A. M.; Akhmerov, A. R.; Beenakker, C. W. J.

    2011-05-01

    We show that a spin-polarized Landau level in a two-dimensional electron gas can carry a spin-triplet supercurrent between two spin-singlet superconductors. The supercurrent results from the interplay of Andreev reflection and Rashba spin-orbit coupling at the normal-superconductor (NS) interface. We contrast the current-phase relationship and the Fraunhofer oscillations of the spin-triplet and spin-singlet Josephson effect in the lowest Landau level and find qualitative differences.

  20. Damages induced in lambda phage DNA by enzyme-generated triplet acetone

    International Nuclear Information System (INIS)

    Exposure of lambda phage to triplet acetone, generated during the aerobic oxidation of isobutanal by peroxidase, leads to genome lesions. The majority of these lesions are detected as DNA single-strand breaks only in alkaline conditions, so true breaks were not observed. Also, no sites sensitive to UV-endonuclease from Micrococcus luteus were found in DNA from treated phage. The participation of triplet acetone in the generation of such DNA damage is discussed. (Author)

  1. Superfluid phases of triplet pairing and rapid cooling of the neutron star in Cassiopeia A

    OpenAIRE

    Leinson, Lev B.

    2014-01-01

    In a simple model it is demonstrated that the neutron star surface temperature evolution is sensitive to the phase state of the triplet superfluid condensate. A multicomponent triplet pairing of superfluid neutrons in the core of a neutron star with participation of several magnetic quantum numbers leads to neutrino energy losses exceeding the losses from the unicomponent pairing. A phase transition of the neutron condensate into the multicomponent state triggers more rapid cooling of superfl...

  2. The excited spin-triplet state of a charged exciton in quantum dots

    Science.gov (United States)

    Molas, M. R.; Nicolet, A. A. L.; Piętka, B.; Babiński, A.; Potemski, M.

    2016-09-01

    We report on spectroscopic studies of resonances related to ladder of states of a charged exciton in single GaAlAs/AlAs quantum dot structures. Polarization-resolved photoluminescence, photoluminescence excitation and photon-correlation measurements were performed at low (T  =  4.2 K) temperature also in magnetic field applied in Faraday configuration. The investigated resonances are assigned to three different configurations of a positively charged exciton. Together with a singlet ground state and a conventional triplet state (involving an electron from the ground state electronic s-shell), an excited triplet state, which involved an electron from the excited electronic p-shell was identified in single dots. The appearance of an emission line related to the latter complex is due to a partially suppressed electron relaxation in the investigated dots. An analysis of this emission line allows us to scrupulously determine properties of the excited triplet state and compare them with those of the conventional triplet state. Both triplets exhibit similar patterns of anisotropic fine structure and Zeeman splitting, however their amplitudes significantly differ for those two states. Presented results emphasize the role of the symmetry of the electronic state on the properties of the triplet states of two holes  +  electron excitonic complex.

  3. Employing Core-Shell Quantum Dots as Triplet Sensitizers for Photon Upconversion.

    Science.gov (United States)

    Okumura, Keisuke; Mase, Kazuma; Yanai, Nobuhiro; Kimizuka, Nobuo

    2016-06-01

    A new family of surface-functionalized CdSe/ZnS core-shell quantum dots (csQD) has been developed, which work as triplet sensitizers for triplet-triplet annihilation-based photon upconversion (TTA-UC). The surface modification of csQD with acceptor molecules plays a key role in the efficient relay of the excited energy of csQD to emitter molecules in the bulk solution, where the generated emitter triplets undergo triplet-triplet annihilation that leads to photon upconversion. Interestingly, improved UC properties were achieved with the core-shell QDs compared with core-only CdSe QDs (cQD). The threshold excitation intensity, which is defined as the necessary irradiance to achieve efficient TTA process, decreases by more than a factor of four. Furthermore, the total UC quantum yield is enhanced more than 50-fold. These enhancements should be derived from better optical properties of csQD, in which the non-radiative surface recombination sites are passivated by the shell layer with wider bandgap. PMID:27121225

  4. The excited spin-triplet state of a charged exciton in quantum dots.

    Science.gov (United States)

    Molas, M R; Nicolet, A A L; Piętka, B; Babiński, A; Potemski, M

    2016-09-14

    We report on spectroscopic studies of resonances related to ladder of states of a charged exciton in single GaAlAs/AlAs quantum dot structures. Polarization-resolved photoluminescence, photoluminescence excitation and photon-correlation measurements were performed at low (T  =  4.2 K) temperature also in magnetic field applied in Faraday configuration. The investigated resonances are assigned to three different configurations of a positively charged exciton. Together with a singlet ground state and a conventional triplet state (involving an electron from the ground state electronic s-shell), an excited triplet state, which involved an electron from the excited electronic p-shell was identified in single dots. The appearance of an emission line related to the latter complex is due to a partially suppressed electron relaxation in the investigated dots. An analysis of this emission line allows us to scrupulously determine properties of the excited triplet state and compare them with those of the conventional triplet state. Both triplets exhibit similar patterns of anisotropic fine structure and Zeeman splitting, however their amplitudes significantly differ for those two states. Presented results emphasize the role of the symmetry of the electronic state on the properties of the triplet states of two holes  +  electron excitonic complex. PMID:27391126

  5. The trouble with triplets in biodiversity informatics: a data-driven case against current identifier practices.

    Directory of Open Access Journals (Sweden)

    Robert Guralnick

    Full Text Available The biodiversity informatics community has discussed aspirations and approaches for assigning globally unique identifiers (GUIDs to biocollections for nearly a decade. During that time, and despite misgivings, the de facto standard identifier has become the "Darwin Core Triplet", which is a concatenation of values for institution code, collection code, and catalog number associated with biocollections material. Our aim is not to rehash the challenging discussions regarding which GUID system in theory best supports the biodiversity informatics use case of discovering and linking digital data across the Internet, but how well we can link those data together at this moment, utilizing the current identifier schemes that have already been deployed. We gathered Darwin Core Triplets from a subset of VertNet records, along with vertebrate records from GenBank and the Barcode of Life Data System, in order to determine how Darwin Core Triplets are deployed "in the wild". We asked if those triplets follow the recommended structure and whether they provide an easy and unambiguous means to track from specimen records to genetic sequence records. We show that Darwin Core Triplets are often riddled with semantic and syntactic errors when deployed and curated in practice, despite specifications about how to construct them. Our results strongly suggest that Darwin Core Triplets that have not been carefully curated are not currently serving a useful role for relinking data. We briefly consider needed next steps to overcome current limitations.

  6. Development of desolvation system for single-cell analysis using droplet injection inductively coupled plasma atomic emission spectroscopy

    International Nuclear Information System (INIS)

    With a view to enhance the sensitivity of analytical instruments used in the measurement of trace elements contained in a single cell, we have now equipped the previously reported micro-droplet injection system (M-DIS) with a desolvation system. This modified M-DIS was coupled to inductively coupled plasma atomic emission spectroscopy (ICP-AES) and evaluated for its ability to measure trace elements. A flow rate of 100 mL/min for the additional gas and a measurement point –7.5 mm above the load coil (ALC) have been determined to be the optimal parameters for recording the emission intensity of the Ca(II) spectral lines. To evaluate the influence of the desolvation system, we recorded the emission intensities of the Ca(I), Ca(II), and H-β spectral lines with and without inclusion of the desolvation system. The emission intensity of the H-β spectral line reduces and the magnitude of the Ca(II)/Ca(I) emission intensity ratio increases four-fold with inclusion of the desolvation system. Finally, the elements Ca, Mg, and Fe present in a single cell of Pseudococcomyxa simplex are simultaneously determined by coupling the M-DIS equipped with the desolvation system to ICP-AES. (author)

  7. π-Conjugated Organometallic Isoindigo Oligomer and Polymer Chromophores: Singlet and Triplet Excited State Dynamics and Application in Polymer Solar Cells.

    Science.gov (United States)

    Goswami, Subhadip; Gish, Melissa K; Wang, Jiliang; Winkel, Russell W; Papanikolas, John M; Schanze, Kirk S

    2015-12-01

    An isoindigo based π-conjugated oligomer and polymer that contain cyclometalated platinum(II) "auxochrome" units were subjected to photophysical characterization, and application of the polymer in bulk heterojunction polymer solar cells with PCBM acceptor was examined. The objective of the study was to explore the effect of the heavy metal centers on the excited state properties, in particular, intersystem crossing to a triplet (exciton) state, and further how this would influence the performance of the organometallic polymer in solar cells. The materials were characterized by electrochemistry, ground state absorption, emission, and picosecond-nanosecond transient absorption spectroscopy. Electrochemical measurements indicate that the cyclometalated units have a significant impact on the HOMO energy level of the chromophores, but little effect on the LUMO, which is consistent with localization of the LUMO on the isoindigo acceptor unit. Picosecond-nanosecond transient absorption spectroscopy reveals a transient with ∼100 ns lifetime that is assigned to a triplet excited state that is produced by intersystem crossing from a singlet state on a time scale of ∼130 ps. This is the first time that a triplet state has been observed for isoindigo π-conjugated chromophores. The performance of the polymer in bulk heterojunction solar cells was explored with PC61BM as an acceptor. The performance of the cells was optimum at a relatively high PCBM loading (1:6, polymer:PCBM), but the overall efficiency was relatively low with power conversion efficiency (PCE) of 0.22%. Atomic force microscopy of blend films reveals that the length scale of the phase separation decreases with increasing PCBM content, suggesting a reason for the increase in PCE with acceptor loading. Energetic considerations show that the triplet state in the polymer is too low in energy to undergo charge separation with PCBM. Further, due to the relatively low LUMO energy of the polymer, charge transfer

  8. Photophysics of Soret-Excited Tetrapyrroles in Solution. IV. Radiationless Decay and Triplet-Triplet Annihilation Investigated Using Tetraphenylporphinato Sn(IV)

    Science.gov (United States)

    Maiti, Manisankar; Danger, Brook R.; Steer, Ronald P.

    2009-09-01

    The S2 population decay rates and triplet-triplet annihilation efficiencies of Sn(IV)Cl2TPP have been measured in fluid solutions using its weak S2-S0 fluorescence as a metric. A detailed description of the excited-state photophysics of Sn(IV)Cl2TPP has allowed comparisons to be made between this rigid, D4h axially coordinated molecule and axially uncoordinated tetrapyrroles of greater flexibility and lower symmetry. S2-S1 internal conversion is the major S2 population decay path for Sn(IV)Cl2TPP as it is for the S2 states of all other d0 and d10 metalated tetrapyrroles. The S2 state of Sn(IV)Cl2TPP exhibits S2-S1 relaxation rates that follow the energy gap law of radiationless transition theory and are only slightly faster than those exhibited by MgTPP and the weak coupling limit. Differences in S2-S1 radiationless decay rates among the series MTPP (M = Mg, Zn, Cd, SnCl2) cannot be traced to differences in the displacements of the S2 and S1 potential surfaces. Instead, the most likely source of the large differences in S2-S1 radiationless decay rates between CdTPP and Sn(IV)Cl2TPP is the lower symmetry of the former (near C4v), which permits a much larger number of vibrations to participate in S2-S1 vibronic coupling. Triplet-triplet annihilation of the type 2T1 → S2 + S0 has been observed in Sn(IV)Cl2TPP for the first time, but is of substantially lower efficiency than seen in ZnTPP in noncoordinating solvents because of its shorter triplet lifetime and the shielding effects of its axial Cl ligands, which tend to block the short-range interaction needed for Dexter energy transfer.

  9. Competition between Singlet and Triplet Superconductivity in the Extended Hubbard Model with Exchange Interaction on a Square Lattice

    International Nuclear Information System (INIS)

    Phase boundary between spin singlet and triplet superconductivity in the extended Hubbard model with exchange interaction on a square lattice is calculated within meanfield approximation. Basically, antiferromagnetic exchange interaction J is advantageous for the singlet pairing, while ferromagnetic J prefers the triplet pairing. When off-site interaction V is repulsive, the singlet phase and the triplet phase are separated by normal state in the phase diagram against V and J. If V is effectively attractive, however, the singlet and triplet states can compete against each other. We calculate the phase boundary between singlet and triplet phase for various band filling. It is shown that the triplet phase penetrates rather deeply into antiferromagnetic exchange regime for lower band filling, whereas the penetration of the singlet phase is confined in a narrow range of ferromagnetic exchange regime.

  10. Laser flash photolysis study on 9-phenylxanthenium tetrafluoroborate: Identification of new features due to the triplet state

    Indian Academy of Sciences (India)

    Sanghamitra Banerjee; Anunay Samanta

    2011-01-01

    Laser flash photolysis study on highly fluorescent and stable salt of 9-phenylxanthenium cation in neutral condition has been carried out for the first time. A new transient absorption band of this extensively studied system that perhaps remained buried under the fluorescence envelope and hitherto undetected has been identified and attributed to the triplet state of the system. This oxygen-insensitive triplet-triplet absorption band in the 480-600 nm range is expected to trigger new studies exploring the reactivity of the triplet state of this system, which has so far received very little attention.

  11. Dissecting galaxy triplets in the Sloan Digital Sky Survey Data Release 10: I. Stellar populations and emission line analysis

    Science.gov (United States)

    Costa-Duarte, M. V.; O'Mill, A. L.; Duplancic, F.; Sodré, L.; Lambas, D. G.

    2016-04-01

    We identify isolated galaxy triplets in a volume-limited sample from the Sloan Digital Sky Survey Data Release 10. Our final sample has 80 galaxy systems in the redshift range 0.04≤z≤0.1, brighter than Mr = -20.5 + 5log h70. Spectral synthesis results and WHAN and BPT diagnostic diagrams were employed to classify the galaxies in these systems as star-forming, active nuclei, or passive/retired. Our results suggest that the brightest galaxies drive the triplet evolution, as evidenced by the strong correlations between properties as mass assembly and mean stellar population age with triplet properties. Galaxies with intermediate luminosity or the faintest one within the triplet seem to play a secondary role. Moreover, the relation between age and stellar mass of galaxies is similar for these galaxies but different for the brightest galaxy in the system. Most of the triplet galaxies are passive or retired, according to the WHAN classification. Low mass triplets present different fractions of WHAN classes when compared to higher mass triplets. A census of WHAN class combinations shows the dominance of star-forming galaxies in low mass triplets while retired and passive galaxies prevail in high-mass systems. We argue that these results suggest that the local environment, through galaxy interactions driven by the brightest galaxy, is playing a major role in triplet evolution.

  12. Dissecting galaxy triplets in the Sloan Digital Sky Survey Data Release 10 - I. Stellar populations and emission line analysis

    Science.gov (United States)

    Costa-Duarte, M. V.; O'Mill, A. L.; Duplancic, F.; Sodré, L.; Lambas, D. G.

    2016-07-01

    We identify isolated galaxy triplets in a volume-limited sample from the Sloan Digital Sky Survey Data Release 10. Our final sample has 80 galaxy systems in the redshift range 0.04 ≤ z ≤ 0.1, brighter than Mr = -20.5 + 5 log h70. Spectral synthesis results and WHAN and BPT diagnostic diagrams were employed to classify the galaxies in these systems as star-forming, active nuclei, or passive/retired. Our results suggest that the brightest galaxies drive the triplet evolution, as evidenced by the strong correlations between properties as mass assembly and mean stellar population age with triplet properties. Galaxies with intermediate luminosity or the faintest one within the triplet seem to play a secondary role. Moreover, the relation between age and stellar mass of galaxies is similar for these galaxies but different for the brightest galaxy in the system. Most of the triplet galaxies are passive or retired, according to the WHAN classification. Low-mass triplets present different fractions of WHAN classes when compared to higher mass triplets. A census of WHAN class combinations shows the dominance of star-forming galaxies in low-mass triplets while retired and passive galaxies prevail in high-mass systems. We argue that these results suggest that the local environment, through galaxy interactions driven by the brightest galaxy, is playing a major role in triplet evolution.

  13. Matrix genetics, part 1: permutations of positions in triplets and symmetries of genetic matrices

    CERN Document Server

    Petoukhov, Sergey V

    2008-01-01

    The hidden connection between the degeneracy of the vertebrate mitochondria genetic code and the positional permutations inside genetic triplets is described. The Kronecker family of the genetic matrices is investigated, which is based on the genetic matrix [C A; U G], where C, A, U, G are the letters of the genetic alphabet. The natural system of binary numeration of genetic multiplets in the genetic matrices is proposed. The matrix [C A; U G] in the third Kronecker power is the (8*8)-matrix, which contains 64 triplets. When 64 triplets in this matrix are numbered in accordance with the natural system, the coincidence with the famous table of 64 hexagrams of the ancient Chinese book "I Ching" arises. It is significant that peculiarities of the degeneracy of the vertebrate mitochondria genetic code are reflected in the symmetrical black-and-white mosaic of this genetic (8*8)-matrix of 64 triplets. This matrix is reformed into a new mosaic matrix when internal positions in all triplets are permuted simultaneou...

  14. Triplet State Formation in Photovoltaic Blends of DPP-Type Copolymers and PC71BM

    KAUST Repository

    Ochsmann, Julian R.

    2015-04-29

    The exciton dynamics in pristine films of two structurally related low-bandgap diketopyrrolopyrrole (DPP)-based donor–acceptor copolymers and the photophysical processes in bulk heterojunction solar cells using DPP copolymer:PC71BM blends are investigated by broadband transient absorption (TA) pump-probe experiments covering the vis–near-infrared spectral and fs–μs dynamic range. The experiments reveal surprisingly short exciton lifetimes in the pristine poly­mer films in conjunction with fast triplet state formation. An in-depth analysis of the TA data by multivariate curve resolution analysis shows that in blends with fullerene as acceptor ultrafast exciton dissociation creates charge carriers, which then rapidly recombine on the sub-ns timescale. Furthermore, at the carrier densities created by pulsed laser excitation the charge carrier recombination leads to a substantial population of the polymer triplet state. In fact, virtually quantitative formation of triplet states is observed on the sub-ns timescale. However, the quantitative triplet formation on the sub-ns timescale is not in line with the power conversion efficiencies of devices indicating that triplet state formation is an intensity-dependent process in these blends and is reduced under solar illumination conditions, as free charge carriers can be extracted from the photoactive layer in devices.

  15. Triplet excited state energies and phosphorescence spectra of (bacterio)chlorophylls.

    Science.gov (United States)

    Hartzler, Daniel A; Niedzwiedzki, Dariusz M; Bryant, Donald A; Blankenship, Robert E; Pushkar, Yulia; Savikhin, Sergei

    2014-07-01

    (Bacterio)Chlorophyll ((B)Chl) molecules play a major role in photosynthetic light-harvesting proteins, and the knowledge of their triplet state energies is essential to understand the mechanisms of photodamage and photoprotection, as the triplet excitation energy of (B)Chl molecules can readily generate highly reactive singlet oxygen. The triplet state energies of 10 natural chlorophyll (Chl a, b, c2, d) and bacteriochlorophyll (BChl a, b, c, d, e, g) molecules and one bacteriopheophytin (BPheo g) have been directly determined via their phosphorescence spectra. Phosphorescence of four molecules (Chl c2, BChl e and g, BPheo g) was characterized for the first time. Additionally, the relative phosphorescence to fluorescence quantum yield for each molecule was determined. The measurements were performed at 77K using solvents providing a six-coordinate environment of the Mg(2+) ion, which allows direct comparison of these (B)Chls. Density functional calculations of the triplet state energies show good correlation with the experimentally determined energies. The correlation determined computationally was used to predict the triplet energies of three additional (B)Chl molecules: Chl c1, Chl f, and BChl f. PMID:24896677

  16. Preorganized Chromophores Facilitate Triplet Energy Migration, Annihilation and Upconverted Singlet Energy Collection.

    Science.gov (United States)

    Mahato, Prasenjit; Yanai, Nobuhiro; Sindoro, Melinda; Granick, Steve; Kimizuka, Nobuo

    2016-05-25

    Photon upconversion (UC) based on triplet-triplet annihilation (TTA) has the potential to enhance significantly photovoltaic and photocatalytic efficiencies by harnessing sub-bandgap photons, but the progress of this field is held back by the chemistry problem of how to preorganize multiple chromophores for efficient UC under weak solar irradiance. Recently, the first maximization of UC quantum yield at solar irradiance was achieved using fast triplet energy migration (TEM) in metal-organic frameworks (MOFs) with ordered acceptor arrays, but at the same time, a trade-off between fast TEM and high fluorescence efficiency was also found. Here, we provide a solution for this trade-off issue by developing a new strategy, triplet energy migration, annihilation and upconverted singlet energy collection (TEM-UPCON). The porous structure of acceptor-based MOF crystals allows triplet donor molecules to be accommodated without aggregation. The surface of donor-doped MOF nanocrystals is modified with highly fluorescent energy collectors through coordination bond formation. Thanks to the higher fluorescence quantum yield of surface-bound collectors than parent MOFs, the implementation of the energy collector greatly improves the total UC quantum yield. The UC quantum yield maximization behavior at ultralow excitation intensity was retained because the TTA events take place only in the MOF acceptors. The TEM-UPCON concept may be generalized to collectors with various functions and would lead to quantitative harvesting of upconverted energy, which is difficult to achieve in common molecular diffusion-based systems. PMID:27163784

  17. Cooperative singlet and triplet exciton transport in tetracene crystals visualized by ultrafast microscopy

    Science.gov (United States)

    Wan, Yan; Guo, Zhi; Zhu, Tong; Yan, Suxia; Johnson, Justin; Huang, Libai

    2015-10-01

    Singlet fission presents an attractive solution to overcome the Shockley-Queisser limit by generating two triplet excitons from one singlet exciton. However, although triplet excitons are long-lived, their transport occurs through a Dexter transfer, making them slower than singlet excitons, which travel by means of a Förster mechanism. A thorough understanding of the interplay between singlet fission and exciton transport is therefore necessary to assess the potential and challenges of singlet-fission utilization. Here, we report a direct visualization of exciton transport in single tetracene crystals using transient absorption microscopy with 200 fs time resolution and 50 nm spatial precision. These measurements reveal a new singlet-mediated transport mechanism for triplets, which leads to an enhancement in effective triplet exciton diffusion of more than one order of magnitude on picosecond to nanosecond timescales. These results establish that there are optimal energetics of singlet and triplet excitons that benefit both singlet fission and exciton diffusion.

  18. Energy-donor phosphorescence quenching study of triplet–triplet energy transfer between UV absorbers

    International Nuclear Information System (INIS)

    The intermolecular triplet–triplet energy transfer from a photounstable UV-A absorber, 4-tert-butyl-4′-methoxydibenzoylmethane (BMDBM), to UV-B absorbers, 2-ethylhexyl 4-methoxycinnamate (octyl methoxycinnamate, OMC), octocrylene (OCR) and dioctyl 4-methoxybenzylidenemalonate (DOMBM) has been observed using a 355 nm laser excitation in rigid solutions at 77 K. The decay curves of the energy-donor phosphorescence in the presence of the UV-B absorbers deviate from the exponential decay at the initial stage of the decay. The Stern–Volmer formulation is not valid in rigid solutions because molecular diffusion is impossible. The experimental results indicate that the rate constant of triplet–triplet energy transfer from BMDBM to the UV-B absorbers, kT–T, decreases in the following order: kT–T (BMDBM–DOMBM)>kT–T (BMDBM–OMC)≥kT–T (BMDBM–OCR). The presence of DOMBM enhances the photostability of the widely used combination of UV-A and UV-B absorbers, BMDBM and OCR. The effects of the triplet–triplet energy transfer on the photostability of BMDBM are discussed. - Highlights: • The intermolecular triplet–triplet energy transfer between UV absorbers was observed. • The phosphorescence decay deviates from exponential at the initial stage of decay. • The effects of triplet–triplet energy transfer on the photostability are discussed

  19. Energy-donor phosphorescence quenching study of triplet–triplet energy transfer between UV absorbers

    Energy Technology Data Exchange (ETDEWEB)

    Kikuchi, Azusa; Nakabai, Yuya [Department of Chemistry, Graduate School of Engineering, Yokohama National University, Tokiwadai, Hodogaya-ku, Yokohama 240-8501 (Japan); Oguchi-Fujiyama, Nozomi; Miyazawa, Kazuyuki [Shiseido Research Center, Hayabuchi, Tsuzuki-ku, Yokohama 224-8558 (Japan); Yagi, Mikio, E-mail: yagimiki@ynu.ac.jp [Department of Chemistry, Graduate School of Engineering, Yokohama National University, Tokiwadai, Hodogaya-ku, Yokohama 240-8501 (Japan)

    2015-10-15

    The intermolecular triplet–triplet energy transfer from a photounstable UV-A absorber, 4-tert-butyl-4′-methoxydibenzoylmethane (BMDBM), to UV-B absorbers, 2-ethylhexyl 4-methoxycinnamate (octyl methoxycinnamate, OMC), octocrylene (OCR) and dioctyl 4-methoxybenzylidenemalonate (DOMBM) has been observed using a 355 nm laser excitation in rigid solutions at 77 K. The decay curves of the energy-donor phosphorescence in the presence of the UV-B absorbers deviate from the exponential decay at the initial stage of the decay. The Stern–Volmer formulation is not valid in rigid solutions because molecular diffusion is impossible. The experimental results indicate that the rate constant of triplet–triplet energy transfer from BMDBM to the UV-B absorbers, k{sub T–T}, decreases in the following order: k{sub T–T} (BMDBM–DOMBM)>k{sub T–T} (BMDBM–OMC)≥k{sub T–T} (BMDBM–OCR). The presence of DOMBM enhances the photostability of the widely used combination of UV-A and UV-B absorbers, BMDBM and OCR. The effects of the triplet–triplet energy transfer on the photostability of BMDBM are discussed. - Highlights: • The intermolecular triplet–triplet energy transfer between UV absorbers was observed. • The phosphorescence decay deviates from exponential at the initial stage of decay. • The effects of triplet–triplet energy transfer on the photostability are discussed.

  20. Sub-ns triplet state formation by non-geminate recombination in PSBTBT:PC 70 BM and PCPDTBT:PC 60 BM organic solar cells

    KAUST Repository

    Etzold, Fabian

    2015-03-02

    The solid-state morphology and photo-generated charge carrier dynamics in low-bandgap polymer:fullerene bulk heterojunction photovoltaic blends using the donor–acceptor type copolymers PCPDTBT or its silicon-substituted analogue PSBTBT as donors are compared by two-dimensional (2D) solid-state nuclear magnetic resonance (NMR) and femto-to microsecond broadband Vis-NIR transient absorption (TA) pump–probe spectroscopy. The 2D solid-state NMR experiments demonstrate that the film morphology of PCPDTBT:PC60BM blends processed with additives such as octanedithiol (ODT) are similar to those of PSBTBT:PC60BM blends in terms of crystallinity, phase segregation, and interfacial contacts. The TA experiments and analysis of the TA data by multivariate curve resolution (MCR) reveal that after exciton dissociation and free charge formation, fast sub-nanosecond non-geminate recombination occurs which leads to a substantial population of the polymer\\'s triplet state. The extent to which triplet states are formed depends on the initial concentration of free charges, which itself is controlled by the microstructure of the blend, especially in case of PCPDTBT:PC60BM. Interestingly, PSBTBT:PC70BM blends show a higher charge generation efficiency, but less triplet state formation at similar free charge carrier concentrations. This indicates that the solid-state morphology and interfacial structures of PSBTBT:PC70BM blends reduces non-geminate recombination, leading to superior device performance compared to optimized PCPDTBT:PC60BM blends.

  1. Theoretical study of the intensity of chemically induce dynamic electron polarization of radical-triplet pairs

    Institute of Scientific and Technical Information of China (English)

    XU Xin-sheng; ZHANG Xian-yi; ZHANG Wei-jun; CUI Zhi-feng; LU Tong-xing

    2003-01-01

    Considering the interaction between excited triplet molecule and doublet radical, based on the second-order perturbation theory and the motion equation of density matrix, the polarization intensity of RTPM were theoretically calculated with the overpopulated doublet spin states and quartet spin states of radical-triplet pairs as initial conditions respectively. The results of calculation indicate that the net emissive polarization and the net absorptive polarization on the radical result from the zero-field-splitting (zfs) and the multiplet A/E and E/A polarization result from hyperfine (hf) interactions of the triplet molecule. The hyperfine related A+A/E or E+E/A CIDEP on the radical were the overpopulation of the net absorptive or emissive polarization and multiplet A/E or E/A polarization..

  2. Dark matter and a suppression mechanism for neutrino masses in the Higgs triplet model

    CERN Document Server

    Kanemura, Shinya

    2012-01-01

    We extend the Higgs triplet model so as to include dark matter candidates and a simple suppression mechanism for the vacuum expectation value (v_Delta) of the triplet scalar field. The smallness of neutrino masses can be naturally explained with the suppressed value of v_Delta even when the triplet fields are at the TeV scale. The Higgs sector is extended by introducing Z_2-odd scalars (an SU(2)_L doublet eta and a real singlet s_2^0) in addition to a Z_2-even complex singlet scalar s_1^0 whose vacuum expectation value violates the lepton number conservation by a unit. In our model, v_Delta is generated by the one-loop diagram to which Z_2-odd particles contribute. The lightest Z_2-odd scalar boson can be a candidate for the dark matter. We briefly discuss a characteristic signal of our model at the LHC.

  3. Conditions for describing triplet states in reduced density matrix functional theory

    CERN Document Server

    Theophilou, Iris; Helbig, Nicole

    2016-01-01

    We consider necessary conditions for the one body-reduced density matrix (1RDM) to correspond to a triplet wave-function of a two electron system. The conditions concern the occupation numbers and are different for the high spin projections, $S_z=\\pm 1$, and the $S_z=0$ projection. We employ these conditions in reduced density matrix functional theory calculations for the triplet excitations of two electron systems. In addition, we propose that these conditions can be used in the calculation of triplet states of systems with more than two electrons by restricting the active space and assess this procedure in calculations for a few atomic and molecular systems. We show that the quality of the optimal 1RDMs improves by applying the conditions in all the cases we studied.

  4. Inelastic collisions of ultracold triplet Rb$_\\textbf{2}$ molecules in the rovibrational ground state

    CERN Document Server

    Drews, Björn; Jachymski, Krzysztof; Idziaszek, Zbigniew; Denschlag, Johannes Hecker

    2016-01-01

    Exploring inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. We present first experimental studies of inelastic collisions of metastable ultracold triplet molecules in the vibrational ground state. The measurements are performed with nonpolar Rb$_2$ dimers which are prepared in precisely-defined quantum states and trapped in an array of quasi-1D potential tubes. We investigate collisions of molecules in the lowest triplet energy level where any inelastic process requires a relaxation to the singlet state. These are compared to two sets of collision experiments, carried out either with triplet molecules that have two quanta of rotational angular momentum or with vibrationally highly excited Feshbach molecules. We find no evidence for suppression of the inelastic collisions due to the necessary spin-flip, shedding light on this so far unsettled issue. For each of the molecular states studied here, we extract the decay rate constant and compare t...

  5. Monochorionic triamniotic triplets following conventional in vitro fertilization and blastocyst transfer.

    Science.gov (United States)

    Gurunath, Sumana; Makam, Adinarayana; Vinekar, Sriprada; Biliangady, Reeta H

    2015-01-01

    Multiple pregnancy in in vitro fertilization (IVF) is on the decline with a reduction in number of embryos transferred. But the risk of monozygotic splitting persists. The risk of monozygotic twinning in women undergoing IVF is reported to be twice that of natural conception, and monochorionic triplets are even rarer at 100 times more than natural conception. We report a case of monochorionic triamniotic (MCTA) triplets following conventional IVF and blastocyst transfer without zona manipulation. This report highlights the possibility of zygotic splitting in IVF in young couples with no family history, in centers with good experience with blastocyst transfer. MCTA triplets carry a high risk of perinatal mortality and morbidity and need multidisciplinary care. Prevention and prediction of zygotic splitting ought to be realized with better reporting and identification of possible risk factors. PMID:25838751

  6. Monochorionic triamniotic triplets following conventional in vitro fertilization and blastocyst transfer

    Directory of Open Access Journals (Sweden)

    Sumana Gurunath

    2015-01-01

    Full Text Available Multiple pregnancy in in vitro fertilization (IVF is on the decline with a reduction in number of embryos transferred. But the risk of monozygotic splitting persists. The risk of monozygotic twinning in women undergoing IVF is reported to be twice that of natural conception, and monochorionic triplets are even rarer at 100 times more than natural conception. We report a case of monochorionic triamniotic (MCTA triplets following conventional IVF and blastocyst transfer without zona manipulation. This report highlights the possibility of zygotic splitting in IVF in young couples with no family history, in centers with good experience with blastocyst transfer. MCTA triplets carry a high risk of perinatal mortality and morbidity and need multidisciplinary care. Prevention and prediction of zygotic splitting ought to be realized with better reporting and identification of possible risk factors.

  7. Direct generation of photon triplets using cascaded photon-pair sources

    CERN Document Server

    Hübel, H; Fedrizzi, A; Ramelow, S; Resch, K J; Jennewein, T

    2010-01-01

    Non-classical states of light, such as entangled photon pairs and number states, are essential for fundamental tests of quantum mechanics and optical quantum technologies. The most widespread technique for creating these quantum resources is the spontaneous parametric down-conversion (SPDC) of laser light into photon pairs. Conservation of energy and momentum in this process, known as phase-matching, gives rise to strong correlations which are used to produce two-photon entanglement in various degrees of freedom. It has been a longstanding goal of the quantum optics community to realise a source that can produce analogous correlations in photon triplets, but of the many approaches considered, none have been technically feasible. In this paper we report the observation of photon triplets generated by cascaded down-conversion. Here each triplet originates from a single pump photon, and therefore quantum correlations will extend over all three photons in a way not achievable with independently created photon pai...

  8. Conditions for Describing Triplet States in Reduced Density Matrix Functional Theory.

    Science.gov (United States)

    Theophilou, Iris; Lathiotakis, Nektarios N; Helbig, Nicole

    2016-06-14

    We consider necessary conditions for the one-body reduced density matrix (1RDM) to correspond to a triplet wave function of a two-electron system. The conditions concern the occupation numbers and are different for the high spin projections, Sz = ±1, and the Sz = 0 projection. Hence, they can be used to test if an approximate 1RDM functional yields the same energies for both projections. We employ these conditions in reduced density matrix functional theory calculations for the triplet excitations of two-electron systems. In addition, we propose that these conditions can be used in the calculation of triplet states of systems with more than two electrons by restricting the active space. We assess this procedure in calculations for a few atomic and molecular systems. We show that the quality of the optimal 1RDMs improves by applying the conditions in all the cases we studied. PMID:27171683

  9. On the behaviour of the IR Ca II triplet in normal and active galaxies

    International Nuclear Information System (INIS)

    Ca II triplet in absorption at λλ8498,8542,8662 A is the strongest feature in the infrared spectrum of late-type stars and normal galaxies. Its strength has been found to be a good luminosity indicator for metal-rich stellar populations. We present high signal-to-noise near-IR spectroscopic data for the nuclear region of 42 normal and active galaxies. We have explored the behaviour of the Ca II triplet strength and found that it shows a small spread around a mean value of 7 A for our sample of normal galaxies. We also found that, in all the Seyfert type 2 galaxies measured and even in some Seyfert type 1, while the optical stellar features show substantial dilution, the strength of the IR Ca II triplet is equal to and in some cases larger than that in normal elliptical galaxies. (author)

  10. Neutrino masses, anomalous U(1) gauge symmetry and doublet-triplet splitting

    International Nuclear Information System (INIS)

    We propose an attractive scenario of grand unified theories in which doublet-triplet splitting is naturally realized in SO(10) unification using the Dimopoulos-Wilczek mechanism. The anomalous U(1)A gauge symmetry plays an essential role in the double-triplet splitting mechanism. It is interesting that the anomalous U(1)A charges determine the unification scale and mass spectrum of additional particles, as well as the order of the Yukawa couplings of quarks and leptons. For the neutrino sector, bi-maximal mixing angles are naturally obtained, and proton decay via dimension 5 operators is suppressed. It is suggestive that the anomalous U(1)A gauge symmetry motivated by superstring theory effectively solves the two biggest problems in grand unified theories, the fermion mass hierarchy problem and doublet-triplet splitting problem. (author)

  11. A Memristive Model Compatible with Triplet Rule for Spike-Timing-Dependent-Plasticity

    CERN Document Server

    Cai, Weiran; Ellinger, Frank

    2011-01-01

    In this paper, we propose an extended version of the memristive STDP model, which is one of the most important and exciting recent discoveries in neuromorphic engineering. The proposed model aims to claim compatibility with another importent STDP rule beyond the pair-based rule, known as the triplet STDP rule. This is an extension of the asynchronous memristive model of Linares-Barranco, et al., capable of explaining the pair-based rule based on the analogy of the synapse to the memristor. The proposed new model is compatible with both the pair-baed and triplet-based rule, by assuming a mechanism of variable thresholds adapting to synaptic potentiation and depression. The dynamical process is governed by ordinary differential equations. The model is an expression of Froemke's principle of suppression for triplet rules and reveals a similar time dependence with that in the suppression STDP model.

  12. Solid state photon upconversion utilizing thermally activated delayed fluorescence molecules as triplet sensitizer

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Tony C.; Congreve, Daniel N.; Baldo, Marc A., E-mail: baldo@mit.edu [Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2015-07-20

    The ability to upconvert light is useful for a range of applications, from biological imaging to solar cells. But modern technologies have struggled to upconvert incoherent incident light at low intensities. Here, we report solid state photon upconversion employing triplet-triplet exciton annihilation in an organic semiconductor, sensitized by a thermally activated-delayed fluorescence (TADF) dye. Compared to conventional phosphorescent sensitizers, the TADF dye maximizes the wavelength shift in upconversion due to its small singlet-triplet splitting. The efficiency of energy transfer from the TADF dye is 9.1%, and the conversion yield of sensitizer exciton pairs to singlet excitons in the annihilator is 1.1%. Our results demonstrate upconversion in solid state geometries and with non-heavy metal-based sensitizer materials.

  13. Formation of the O I resonance triplet and intercombination doublet in the solar chromosphere

    International Nuclear Information System (INIS)

    Spectrum synthesis calculations are presented for the O I resonance triplet at 1304 A and the intercombination doublet at 1358 A for the solar atmosphere of Vernazza, Avrett, and Loeser and several variants, allowing for triplet fluorescence by the Lyβ emission of H I. Profiles, synthesized from a seven-level plus continuum O I atom are compared to observations taken with the high-resolution spectrometer on OSO 8, calibrated with the irradiance measurements of Heroux and Higgins. We find tha the O I triplet emission is dominated by the Lyβ fluorescence and that the agreement between observations and profiles computed with current chromospheric models is much improved over earlier studies

  14. Ultrafast spectroscopy of linear carbon chains: the case of dinaphthylpolyynes

    Directory of Open Access Journals (Sweden)

    Negro M.

    2013-03-01

    Full Text Available The dynamics of excited streets in a special class of linear carbon chains, e.g. dinaphthyl polyynes, has been investigated by ultrafast transient absorption spectroscopy and DFT//TDDFT calculations. The ultrafast formation of a narrow photo-induced absorption band has been observed and assigned to an inter-system crossing event bringing to the formation of triplet excited streets.

  15. Carotenoid triplet states in photosystem II: coupling with low-energy states of the core complex.

    Science.gov (United States)

    Santabarbara, Stefano; Agostini, Alessandro; Casazza, Anna Paola; Zucchelli, Giuseppe; Carbonera, Donatella

    2015-02-01

    The photo-excited triplet states of carotenoids, sensitised by triplet-triplet energy transfer from the chlorophyll triplet states, have been investigated in the isolated Photosystem II (PSII) core complex and PSII-LHCII (Light Harvesting Complex II) supercomplex by Optically Detected Magnetic Resonance techniques, using both fluorescence (FDMR) and absorption (ADMR) detection. The absence of Photosystem I allows us to reach the full assignment of the carotenoid triplet states populated in PSII under steady state illumination at low temperature. Five carotenoid triplet ((3)Car) populations were identified in PSII-LHCII, and four in the PSII core complex. Thus, four (3)Car populations are attributed to β-carotene molecules bound to the core complex. All of them show associated fluorescence emission maxima which are relatively red-shifted with respect to the bulk emission of both the PSII-LHCII and the isolated core complexes. In particular the two populations characterised by Zero Field Splitting parameters |D|=0.0370-0.0373 cm(-1)/|E|=0.00373-0.00375 cm(-1) and |D|=0.0381-0.0385 cm(-1)/|E|=0.00393-0.00389 cm(-1), are coupled by singlet energy transfer with chlorophylls which have a red-shifted emission peaking at 705 nm. This observation supports previous suggestions that pointed towards the presence of long-wavelength chlorophyll spectral forms in the PSII core complex. The fifth (3)Car component is observed only in the PSII-LHCII supercomplex and is then assigned to the peripheral light harvesting system. PMID:25481107

  16. Triplet excited state properties in variable gap π-conjugated donor–acceptor–donor chromophores

    KAUST Repository

    Cekli, Seda

    2016-02-12

    A series of variable band-gap donor–acceptor–donor (DAD) chromophores capped with platinum(II) acetylide units has been synthesized and fully characterized by electrochemical and photophysical methods, with particular emphasis placed on probing triplet excited state properties. A counter-intuitive trend of increasing fluorescence quantum efficiency and lifetime with decreasing excited state energy (optical gap) is observed across the series of DAD chromophores. Careful study of the excited state dynamics, including triplet yields (as inferred from singlet oxygen sensitization), reveals that the underlying origin of the unusual trend in the fluorescence parameters is that the singlet–triplet intersystem crossing rate and yield decrease with decreasing optical gap. It is concluded that the rate of intersystem crossing decreases as the LUMO is increasingly localized on the acceptor unit in the DAD chromophore, and this result is interpreted as arising because the extent of spin–orbit coupling induced by the platinum heavy metal centers decreases as the LUMO is more localized on the acceptor. In addition to the trend in intersystem crossing, the results show that the triplet decay rates follow the Energy Gap Law correlation over a 1.8 eV range of triplet energy and 1000-fold range of triplet decay rates. Finally, femtosecond transient absorption studies for the DAD chromophores reveals a strong absorption in the near-infrared region which is attributed to the singlet excited state. This spectral band appears to be general for DAD chromophores, and may be a signature of the charge transfer (CT) singlet excited state.

  17. iTriplet, a rule-based nucleic acid sequence motif finder

    Directory of Open Access Journals (Sweden)

    Gunderson Samuel I

    2009-10-01

    Full Text Available Abstract Background With the advent of high throughput sequencing techniques, large amounts of sequencing data are readily available for analysis. Natural biological signals are intrinsically highly variable making their complete identification a computationally challenging problem. Many attempts in using statistical or combinatorial approaches have been made with great success in the past. However, identifying highly degenerate and long (>20 nucleotides motifs still remains an unmet challenge as high degeneracy will diminish statistical significance of biological signals and increasing motif size will cause combinatorial explosion. In this report, we present a novel rule-based method that is focused on finding degenerate and long motifs. Our proposed method, named iTriplet, avoids costly enumeration present in existing combinatorial methods and is amenable to parallel processing. Results We have conducted a comprehensive assessment on the performance and sensitivity-specificity of iTriplet in analyzing artificial and real biological sequences in various genomic regions. The results show that iTriplet is able to solve challenging cases. Furthermore we have confirmed the utility of iTriplet by showing it accurately predicts polyA-site-related motifs using a dual Luciferase reporter assay. Conclusion iTriplet is a novel rule-based combinatorial or enumerative motif finding method that is able to process highly degenerate and long motifs that have resisted analysis by other methods. In addition, iTriplet is distinguished from other methods of the same family by its parallelizability, which allows it to leverage the power of today's readily available high-performance computing systems.

  18. Charge Transfer and Triplet States in High Efficiency OPV Materials and Devices

    Science.gov (United States)

    Dyakonov, Vladimir

    2013-03-01

    The advantage of using polymers and molecules in electronic devices, such as light-emitting diodes (LED), field-effect transistors (FET) and, more recently, solar cells (SC) is justified by the unique combination of high device performance and processing of the semiconductors used. Power conversion efficiency of nanostructured polymer SC is in the range of 10% on lab scale, making them ready for up-scaling. Efficient charge carrier generation and recombination in SC are strongly related to dissociation of the primary singlet excitons. The dissociation (or charge transfer) process should be very efficient in photovoltaics. The mechanisms governing charge carrier generation, recombination and transport in SC based on the so-called bulk-heterojunctions, i.e. blends of two or more semiconductors with different electron affinities, appear to be very complex, as they imply the presence of the intermediate excited states, neutral and charged ones. Charge transfer states, or polaron pairs, are the intermediate states between free electrons/holes and strongly bound excitons. Interestingly, the mostly efficient OLEDs to date are based on the so-called triplet emitters, which utilize the triplet-triplet annihilation process. In SC, recent investigations indicated that on illumination of the device active layer, not only mobile charges but also triplet states were formed. With respect to triplets, it is unclear how these excited states are generated, via inter-system crossing or via back transfer of the electron from acceptor to donor. Triplet formation may be considered as charge carrier loss channel; however, the fusion of two triplets may lead to a formation of singlet excitons instead. In such case, a generation of charges by utilizing of the so far unused photons will be possible. The fundamental understanding of the processes involving the charge transfer and triplet states and their relation to nanoscale morphology and/or energetics of blends is essential for the

  19. Preferential Nucleosome Assembly at DNA Triplet Repeats from the Myotonic Dystrophy Gene

    Science.gov (United States)

    Wang, Yuh-Hwa; Amirhaeri, Sorour; Kang, Seongman; Wells, Robert D.; Griffith, Jack D.

    1994-07-01

    The expansion of CTG repeats in DNA occurs in or near genes involved in several human diseases, including myotonic dystrophy and Huntington's disease. Nucleosomes, the basic structural element of chromosomes, consist of 146 base pairs of DNA coiled about an octamer of histone proteins and mediate general transcriptional repression. Electron microscopy was used to examine in vitro the nucleosome assembly of DNA containing repeating CTG triplets. The efficiency of nucleosome formation increased with expanded triplet blocks, suggesting that such blocks may repress transcription through the creation of stable nucleosomes.

  20. Energy deposition studies for the High-Luminosity Large Hadron Collider inner triplet magnets

    CERN Document Server

    Mokhov, N V; Tropin, I S; Cerutti, F; Esposito, L S; Lechner, A

    2015-01-01

    A detailed model of the High Luminosity LHC inner triplet region with new large-aperture Nb3Sn magnets, field maps, corrector packages, and segmented tungsten inner absorbers was built and implemented into the FLUKA and MARS15 codes. In the optimized configuration, the peak power density averaged over the magnet inner cable width is safely below the quench limit. For the integrated luminosity of 3000 fb-1, the peak dose in the innermost magnet insulator ranges from 20 to 35 MGy. Dynamic heat loads to the triplet magnet cold mass are calculated to evaluate the cryogenic capability. In general, FLUKA and MARS results are in a very good agreement.

  1. Energy Deposition Studies for the Hi-Lumi LHC Inner Triplet Magnets

    CERN Document Server

    Mokhov, N V; Striganov, S I; Tropin, I S; Cerutti, F; Esposito, L; Lechner, A

    2015-01-01

    A detailed model of the High Luminosity LHC inner triplet region with new large-aperture Nb3Sn magnets, field maps, corrector packages, and segmented tungsten inner absorbers was built and implemented into the FLUKA and MARS15 codes. In the optimized configuration, the peak power density averaged over the magnet inner cable width is safely below the quench limit. For the integrated luminosity of 3000 fb -1, the peak dose in the innermost magnet insulator ranges from 20 to 35 MGy. Dynamic heat loads to the triplet magnet cold mass are calculated to evaluate the cryogenic capability. In general, FLUKA and MARS results are in a very good agreement.

  2. Characterization of the Triplet State of Tris(8-hydroxyquinoline)aluminium(III) in Benzene Solution

    OpenAIRE

    Burrows, Hugh D.; Fernandes, Mariana; Melo, J. Seixas de; Monkman, Andrew P.; NAVARATNAM, SUPPIAH

    2003-01-01

    The lowest triplet state of tris(8-hydroxyquinoline)aluminium(III) (Alq3) has been prepared by pulse radiolysis/energy transfer from appropriate donors in benzene solutions and has an absorption maximum around 510 nm with a lifetime of about 50 μs. It is quenched by molecular oxygen, leading to singlet oxygen formation. From flash photolysis and singlet oxygen formation measurements, a quantum yield of triplet formation of 0.24 was determined for direct photolysis of the complex. A value of 2...

  3. Spectrally tunable mollow triplet emission from a coherently excited quantum dot in a microcavity

    DEFF Research Database (Denmark)

    Ulrich, Sven M.; Ates, Serkan; Reitzenstein, Stephan;

    2010-01-01

    Resonance fluorescence of excitonic s-shell emission from a coherently pumped single InGaAs/GaAs quantum dot inside a micropillar cavity has been investigated in dependence on optical pump power and laser detuning, respectively. For strong purely resonant excitation, Mollow triplet spectra with l...... large Rabi splittings of j~­j » 60¹eV have been observed. Laser detuning-dependent series revealed the pronounced asymmetry of the emission triplet as predicted by theory. From our data, an electrical dipole moment of ¹ » 17:8§0:5 Debye could be derived for the excitonic state....

  4. Toward Singlet-Triplet Bistable Nonalternant Kekulé Hydrocarbons: Azulene-to-Naphthalene Rearrangement.

    Science.gov (United States)

    Das, Soumyajit; Wu, Jishan

    2015-12-01

    Recent developments of open-shell singlet diradicaloids motivated the search for stable singlet-triplet bistable nonalternant polycyclic hydrocarbons. During the synthesis of this type of molecule, such as the dibenzo-cyclohepta[def]fluorene 3, an unexpected azulene-to-naphthalene rearrangement was observed at room temperature, which resulted in new nonalternant hydrocarbons 8a/8b with a closed-shell singlet ground state. These studies provided insight into the unique chemistry of azulene and challenges for the synthesis of singlet-triplet bistable polycyclic hydrocarbons. PMID:26569547

  5. Multiphoton ionization through the triplet states of Mg by linearly and circularly polarized laser pulses

    CERN Document Server

    Buica, Gabriela; 10.1103/PhysRevA.79.013419

    2013-01-01

    We theoretically study multiphoton ionization through the triplet states of Mg by linearly polarized (LP) and circularly polarized (CP) fs laser pulses. After the construction of the atomic basis using the frozen-core Hartree-Fock potential (FCHFP) as well as the model potential (MP) approaches for both singlet and triplet series which show rather good agreements with the existing data in terms of state energies and dipole matrix elements, we solve time-dependent Schr\\"{o}dinger equations with $3s3p$ $^{3}P_{1}$ as an initial state, and calculate the total ionization yield and photoelectron energy spectra (PES).

  6. Signatures of Higgs-Triplet representations at TeV-e+e- colliders

    International Nuclear Information System (INIS)

    The authors investigate the potential of future TeV linear e+e- colliders to observe singly-charged Higgs bosons (H±) via the coupling H±W-+Z, which would signal the existence of exotic Higgs representations. In the context of a Higgs-triplet model compatible with the electroweak oblique parameters, they estimate the cross section for producing charged Higgs-triplet bosons that couple predominantly to W and Z bosons in 0.5-2 TeV-e+e- colliders. The principal backgrounds are evaluated and the viability of the signal is discussed and illustrated

  7. Triplet supercurrent due to spin-active zones in a Josephson junction

    Science.gov (United States)

    Linder, Jacob; Sudbø, Asle

    2010-07-01

    Motivated by a recent experiment evidencing triplet superconductivity in a ferromagnetic Josephson junction with a Cu2MnAl -Heusler barrier, we construct a theoretical model accounting for this observation. The key ingredients in our model which generate the triplet supercurrent are spin-active zones, characterized by an effective canted interface magnetic moment. Using a numerical solution of the quasiclassical equations of superconductivity with spin-active boundary conditions, we find qualitatively very good agreement with the experimentally observed supercurrent. Further experimental implications of the spin-active zones are discussed.

  8. Constraining Inert Triplet dark matter by the LHC and FermiLAT

    International Nuclear Information System (INIS)

    We study collider phenomenology of inert triplet scalar dark matter at the LHC. We discuss possible decay of Higgs boson to dark matter candidate and apply current experimental data for invisible Higgs decay and Rγγ to constrain parameter space of our model. We also investigate constraints on dark matter coming from forthcoming measurement, RZγ and mono-Higgs production. We analytically calculate the annihilation cross section of dark matter candidate into 2γ and Zγ and then use FermiLAT data to put constraints on parameter space of Inert Triplet Model. We found that this limit can be stronger than the constraints provided by LUX experiment for low mass DM

  9. Rydberg state Stark spectroscopy in plasma sheaths

    International Nuclear Information System (INIS)

    In this experiment, using optogalvanic methods, the authors investigated the Rydberg state Stark spectroscopy of the triplet states of atomic helium from n = 14 up to -- 44 to measure the electric-field profile in the cathode fall region of a dc and 15-kHz low pressure glow discharge as well as in a plasma double layer formed at a discharge constriction in the positive column dc discharge. The electric field values are obtained in several ways from the measured spectra, from the Stark splitting and the energy level shifts, allowed to forbidden transition intensity ratio, and from the series termination

  10. Light Absorption by Secondary Organic Aerosol Produced from Aqueous Reaction of Phenols with an Organic Excited Triplet State and Hydroxyl Radical

    Science.gov (United States)

    Smith, J.; Yu, L.; George, K.; Ruthenburg, T. C.; Dillner, A. M.; Zhang, Q.; Anastasio, C.

    2012-12-01

    Although reactions in atmospheric condensed phases can form and transform secondary organic aerosol (SOA), these reactions are not well represented in many air quality models. Previous experiments have focused on hydroxyl radical-mediated oxidation of low molecular weight precursors such as gyloxal and methylglyoxal. In our work we are examining aqueous SOA formed from phenols, which are emitted from biomass burning and formed from the oxidation of anthropogenic aromatics such as benzene and toluene. In this work we examine aqueous SOA production from oxidation of three phenols (phenol, guaiacol, syringol) and three benzene-diols (catechol, resorcinol, 1,4-hydroquinone) by hydroxyl radical (OH) and the triplet excited state of 3,4-dimethoxybenzaldehyde (DMB). Our focus is on light absorption by the reaction products, which we characterized by measuring UV-Vis spectra and calculating mass absorption coefficients. To understand the elemental and molecular composition of the SOA, we also analyzed the samples with high resolution mass spectrometry and infrared spectroscopy. Our results indicate that aqueous oxidation of phenols and benzene-diols via OH and triplet excited states efficiently produce SOA that is highly absorbing in the UV-A wavelengths, consists of both small and large molecular weight products, and is highly oxidized.

  11. Modeling the NeIX Triplet Spectral Region of Capella with the Chandra and XMM-Newton Gratings

    CERN Document Server

    Ness, J U

    2003-01-01

    High resolution X-ray spectroscopy with the diffraction gratings of Chandra and XMM-Newton offers new chances to study a large variety of stellar coronal phenomena. A popular X-ray calibration target is Capella, which has been observed with all gratings with significant exposure times. We gathered together all available data of the HETGS (155ks), LETGS (219ks), and RGS (53ks) for comparative analysis focusing on the NeIX triplet at around 13.5A, a region that is severely blended by strong iron lines. We identify 18 emission lines in this region of the HEG spectrum, including many from FeXIX, and find good agreement with predictions from a theoretical model constructed using the Astrophysical Plasma Emission Code (APEC). The model uses an emission measure distribution derived from FeXV to FeXXIV lines. While these 18 emission lines cannot be isolated in the LETGS or RGS spectra, their wavelengths and fluxes as measured with HEG are consistent with the lower resolution spectra. In the Capella model for HEG, the...

  12. Tri-P-LETS: Changing the Face of High School Computer Science

    Science.gov (United States)

    Sherrell, Linda; Malasri, Kriangsiri; Mills, David; Thomas, Allen; Greer, James

    2012-01-01

    From 2004-2007, the University of Memphis carried out the NSF-funded Tri-P-LETS (Three P Learning Environment for Teachers and Students) project to improve local high-school computer science curricula. The project reached a total of 58 classrooms in eleven high schools emphasizing problem solving skills, programming concepts as opposed to syntax,…

  13. Photoprotection and triplet energy transfer in higher plants: the role of electronic and nuclear fluctuations.

    Science.gov (United States)

    Cupellini, Lorenzo; Jurinovich, Sandro; Prandi, Ingrid G; Caprasecca, Stefano; Mennucci, Benedetta

    2016-04-20

    Photosynthetic organisms employ several photoprotection strategies to avoid damage due to the excess energy in high light conditions. Among these, quenching of triplet chlorophylls by neighboring carotenoids (Cars) is fundamental in preventing the formation of singlet oxygen. Cars are able to accept the triplets from chlorophylls by triplet energy transfer (TET). We have here studied TET rates in CP29, a minor light-harvesting complex (LHC) of the Photosystem II in plants. A fully atomistic strategy combining classical molecular dynamics of the LHC in its natural environment with a hybrid time-dependent density functional theory/polarizable MM description of the TET is used. We find that the structural fluctuations of the pigment-protein complex can largely enhance the transfer rates with respect to those predicted using the crystal structure, reducing the triplet quenching times in the subnanosecond scale. These findings add a new perspective for the interpretation of the photoprotection function and its relation with structural motions of the LHC. PMID:27052105

  14. Long-range spin-triplet proximity effect in Josephson junctions with multilayered ferromagnets

    International Nuclear Information System (INIS)

    We study theoretically the Josephson effect and pairing correlations in planar SF1F2S junctions that consist of conventional superconductors (S) connected through two metallic monodomain ferromagnets (F1 and F2) with transparent interfaces. We solve self-consistently the Eilenberger equations for arbitrary orientation of in-plane magnetizations in the clean limit and for moderate disorder in ferromagnets. Both singlet and triplet pair amplitudes and the Josephson current-phase relations are calculated numerically. It is shown that for equally thick ferromagnetic layers (symmetric junctions) the long-range spin-triplet correlations are not dominant: For thin ferromagnetic layers all amplitudes are equally large, while for thick layers the long range triplet amplitude is very small. It is shown that for noncollinear magnetizations the long-range proximity effect can be dominant in highly non-symmetric SF1F2S junctions with particularly thin F1 and thick F2 ferromagnetic layers. We find that dominant triplet correlations in Josephson junctions with ferromagnetic bilayer always give dominant second harmonics in current-phase relations at low temperatures.

  15. Efficient Algorithms for Computing the Triplet and Quartet Distance Between Trees of Arbitrary Degree

    DEFF Research Database (Denmark)

    Brodal, Gerth Stølting; Fagerberg, Rolf; Mailund, Thomas;

    2013-01-01

    ), respectively, and counting how often the induced topologies in the two input trees are different. In this paper we present efficient algorithms for computing these distances. We show how to compute the triplet distance in time O(n log n) and the quartet distance in time O(d n log n), where d is the maximal...... degree of any node in the two trees. Within the same time bounds, our framework also allows us to compute the parameterized triplet and quartet distances, where a parameter is introduced to weight resolved (binary) topologies against unresolved (non-binary) topologies. The previous best algorithm for...... computing the triplet and parameterized triplet distances have O(n2) running time, while the previous best algorithms for computing the quartet distance include an O(d9 n log n) time algorithm and an O(n2.688) time algorithm, where the latter can also compute the parameterized quartet distance. Since d ≤ n...

  16. Intra-molecular Triplet Energy Transfer is a General Approach to Improve Organic Fluorophore Photostability

    Science.gov (United States)

    Zheng, Qinsi; Jockusch, Steffen; Rodríguez-Calero, Gabriel G.; Zhou, Zhou; Zhao, Hong; Altman, Roger B.; Abruña, Héctor D.; Blanchard, Scott C.

    2015-01-01

    Bright, long-lasting and non-phototoxic organic fluorophores are essential to the continued advancement of biological imaging. Traditional approaches towards achieving photostability, such as the removal of molecular oxygen and the use of small-molecule additives in solution, suffer from potentially toxic side effects, particularly in the context of living cells. The direct conjugation of small-molecule triplet state quenchers, such as cyclooctatetraene (COT), to organic fluorophores has the potential to bypass these issues by restoring reactive fluorophore triplet states to the ground state through intra-molecular triplet energy transfer. Such methods have enabled marked improvement in cyanine fluorophore photostability spanning the visible spectrum. However, the generality of this strategy to chemically and structurally diverse fluorophore species has yet to be examined. Here, we show that the proximal linkage of COT increases the photon yield of a diverse range of organic fluorophores widely used in biological imaging applications, demonstrating that the intra-molecular triplet energy transfer mechanism is a potentially general approach for improving organic fluorophore performance and photostability. PMID:26700693

  17. Maternal and Fetal Outcomes of Triplet Gestation in a Tertiary Hospital in Oman

    Directory of Open Access Journals (Sweden)

    Maryam Al-Shukri

    2014-05-01

    Full Text Available Objectives: The aim of this study was to describe the fetal and maternal outcomes of triplet gestation and to report on the maternal characteristics of those pregnancies in a tertiary care centre in Oman. Methods: A retrospective study was undertaken of all triplet pregnancies delivered at Sultan Qaboos University Hospital, Muscat, Oman, between January 2009 and December 2011. Results: Over the three-year study period, there were 9,140 deliveries. Of these, there were 18 triplet pregnancies, giving a frequency of 0.2%. The mean gestational age at delivery was 31.0 ± 3.0 weeks, and the mean birth weight was 1,594 ± 460 g. The most common maternal complications were preterm labour in 13 pregnancies (72.2%, gestational diabetes in 7 (39% and gestational hypertension in 5 (28%. Of the total deliveries, there were 54 neonates. Neonatal complications among these included hyaline membrane disease in 25 neonates (46%, hyperbilirubinaemia in 24 (43%, sepsis in 18 (33% and anaemia in 8 (15%. The perinatal mortality rate was 55 per 1,000 births. Conclusion: The maternal and neonatal outcomes of triplet pregnancies were similar to those reported in other studies.

  18. Field Tolerances for the Triplet Quadrupoles of the LHC High Luminosity Lattice

    Energy Technology Data Exchange (ETDEWEB)

    Nosochkov, Yuri; Cai, Y.; Jiao, Y.; Wang, M-H.; /SLAC; Fartoukh, S.; Giovannozzi, M.; Maria, R.de; McIntosh, E.

    2012-06-25

    It has been proposed to implement the so-called Achromatic Telescopic Squeezing (ATS) scheme in the LHC high luminosity (HL) lattice to reduce beta functions at the Interaction Points (IP) up to a factor of 8. As a result, the nominal 4.5 km peak beta functions reached in the Inner Triplets (IT) at collision will be increased by the same factor. This, therefore, justifies the installation of new, larger aperture, superconducting IT quadrupoles. The higher beta functions will enhance the effects of the triplet quadrupole field errors leading to smaller beam dynamic aperture (DA). To maintain the acceptable DA, the effects of the triplet field errors must be re-evaluated, thus specifying new tolerances. Such a study has been performed for the so-called '4444' collision option of the HL-LHC layout version SLHCV3.01, where the IP beta functions are reduced by a factor of 4 in both planes with respect to a pre-squeezed value of 60 cm at two collision points. The dynamic aperture calculations were performed using SixTrack. The impact on the triplet field quality is presented.

  19. Detection of Ca II absorption triplet in a circumnuclear H II region of NGC 3310

    OpenAIRE

    Terlevich, Elena; Angeles I. Díaz; Pastoriza, Miriani G.; Terlevich, Roberto; Dottori, Horacio

    1990-01-01

    This is an electronic version of an article published in Monthly Notices of the Royal Astronomical Society. Terlevich, E., Díaz, A.I., Pastoriza, M.G., Terlevich, R. and H. Dottori. Detection of Ca II absorption triplet in a circumnuclear H II region of NGC 3310. Monthly Notices of the Royal Astronomical Society 242 (1990): 48-51

  20. On the behaviour of the IR Ca II triplet in normal and active galaxies

    OpenAIRE

    Terlevich, Elena; Angeles I. Díaz; Terlevich, Roberto

    1990-01-01

    This is an electronic version of an article published in Monthly Notices of the Royal Astronomical Society. Terlevich, E., Díaz, A.I., Terlevich, R. On the behaviour of the IR Ca II triplet in normal and active galaxies. Monthly Notices of the Royal Astronomical Society 242 (1990): 271-284

  1. Thermodynamic properties of the phase transitions in a class of spin-triplet ferromagnetic superconductors

    International Nuclear Information System (INIS)

    Magnetic susceptibility, entropy and specific heat are calculated at the equilibrium points of phase transition to a phase of coexistence of ferromagnetic order and superconductivity in a new class of spin-triplet ferromagnetic superconductors. The results are discussed in a view of application to metallic ferromagnets as UGe2, ZrZn2, URhGe. (authors)

  2. How disorder controls the kinetics of triplet charge recombination in semiconducting organic polymer photovoltaics.

    Science.gov (United States)

    Bittner, Eric R; Lankevich, Vladimir; Gélinas, Simon; Rao, Akshay; Ginger, David A; Friend, Richard H

    2014-10-14

    Recent experiments by Rao et al. (Nature, 2013, 500, 435-439) indicate that recombination of triplet charge-separated states is suppressed in organic polymer-fullerene based bulk-heterojunction (BHJ) photovoltaic cells exhibiting a high degree of crystallinity in the fullerene phase relative to systems with more disorder. In this paper, we use a series of Frenkel-exciton lattice models to rationalize these results in terms of wave-function localization, interface geometry, and density of states. In one-dimensional co-linear and co-facial models of the interface, increasing local energetic disorder in one phase localizes the interfacial triplet charge-transfer ((3)CT) states and increases the rate at which these states relax to form lower-energy triplet excitons. In two dimensional BHJ models, energetic disorder within the fullerene phase plays little role in further localizing states pinned to the interface. However, inhomogeneous broadening introduces strong coupling between the interfacial (3)CT and nearby fullerene triplet excitons and can enhance the decay of these states in systems with higher degrees of energetic disorder. PMID:24922118

  3. Early fetal reduction of dichorionic triplets to dichorionic twin or singleton pregnancies: a retrospective study.

    Science.gov (United States)

    Lin, Haiyan; Wen, Ya; Li, Yu; Chen, Xiaoli; Yang, Dongzi; Zhang, Qingxue

    2016-05-01

    A retrospective study conducted in an academic reproductive medicine centre evaluated the feasibility and safety of early fetal reduction in dichorionic triplets to dichorionic twin or singleton pregnancies. Thirty-three dichorionic triplets that underwent early transvaginal fetal reduction mechanically between 2002 and 2013 were included, of which 21 patients underwent fetal reduction to dichorionic twins (Group A) and 12 patients underwent fetal reduction to a singleton pregnancy (Group B). A further 84 patients with trichorionic triplets reduced to twins were included as the control group (Group C). The main outcome measures were live birth and preterm labour rates. Both early and late spontaneous abortion rates, were similar in group A compared with groups B and C. Gestational age at delivery was significantly lower in group C versus group A (P = 0.02). The preterm labour rate in group A, which was comparable with that in group C, was greater than in group B, but not significantly. Neonatal birth weight, low birth weight rate and neonatal body height were similar among groups. Small for gestational age rates were comparable. Live birth rates were similar among the groups. Early transvaginal fetal reduction for dichorionic triplets to dichorionic twins may be feasible and safe. PMID:26997475

  4. The Predicted Spectrum and Singlet-Triplet Interaction of the Hypermetallic Molecule SrOSr

    Science.gov (United States)

    Ostojić, B.; Jensen, Per; Schwerdtfeger, P.; Bunker, P. R.

    2013-10-01

    In accordance with previous studies in our group on Be, Mg, and Ca hypermetallic oxides, we find that SrOSr has a linear X-1Σg+ ground electronic state and a very low lying first excited -3Σu+ triplet electronic state. No gas-phase spectrum of this molecule has been assigned yet, and to encourage and assist in its discovery we present a complete ab initio simulation, with absolute intensities, of the infrared absorption spectrum for both electronic states. The three-dimensional potential energy surfaces and the electric dipole moment surfaces of the X-1Σg+ and -3Σu+ electronic states are calculated using a multireference configuration interaction (MRCISD) approach in combination with internally contracted multireference perturbation theory (RS2C) based on complete active space self-consistent field (CASSCF) wave functions applying a Sadlej pVTZ basis set for both O and Sr and the Stuttgart relativistic small-core effective core potential for Sr. The infrared spectra are simulated using the MORBID program system. We also calculate vertical excitation energies and transition moments for several excited singlet and triplet electronic states in order to predict the positions and intensities of the most prominent singlet and triplet electronic absorption bands. Finally, for this heavy molecule, we calculate the singlet-triplet interaction matrix elements between close-lying vibronic levels of the X- and - electronic states and find them to be very small.

  5. Long-range spin-triplet proximity effect in Josephson junctions with multilayered ferromagnets

    Energy Technology Data Exchange (ETDEWEB)

    Trifunovic, Luka [Department of Physics, University of Belgrade (RS); Department of Physics, University of Basel (Switzerland); Radovic, Zoran [Department of Physics, University of Belgrade (RS)

    2011-07-01

    We study theoretically the Josephson effect and pairing correlations in planar SF{sub 1}F{sub 2}S junctions that consist of conventional superconductors (S) connected through two metallic monodomain ferromagnets (F{sub 1} and F{sub 2}) with transparent interfaces. We solve self-consistently the Eilenberger equations for arbitrary orientation of in-plane magnetizations in the clean limit and for moderate disorder in ferromagnets. Both singlet and triplet pair amplitudes and the Josephson current-phase relations are calculated numerically. It is shown that for equally thick ferromagnetic layers (symmetric junctions) the long-range spin-triplet correlations are not dominant: For thin ferromagnetic layers all amplitudes are equally large, while for thick layers the long range triplet amplitude is very small. It is shown that for noncollinear magnetizations the long-range proximity effect can be dominant in highly non-symmetric SF{sub 1}F{sub 2}S junctions with particularly thin F{sub 1} and thick F{sub 2} ferromagnetic layers. We find that dominant triplet correlations in Josephson junctions with ferromagnetic bilayer always give dominant second harmonics in current-phase relations at low temperatures.

  6. Quadrupole Magnet Error Sensitivities for FODO-Cell and Triplet Lattices in the LCLS Undulator

    International Nuclear Information System (INIS)

    The error sensitivities of quadrupole magnets in the LCLS FEL undulator are compared for a FODO-cell lattice and for a triplet lattice. The comparisons are made at a radiation wavelength of 1.5 (angstrom), where electron-to-photon phase errors are very sensitive to small trajectory variations in misaligned quadrupoles between the undulator sections. The results show that the triplet lattice is extremely sensitive, with triplet pitch and yaw alignment tolerances of ∼100 (micro)rad. The FODO-cell lattice, with its shorter, weaker quadrupoles is much more error tolerant with pitch and yaw tolerances of ∼2.5 mrad. Several other magnet errors are examined and categorized as trajectory, phase slip, and beam size effects. In nearly all cases, the FODO-cell lattice is much less sensitive with technologically achievable tolerance levels, while the triplet lattice tolerances are, in many cases, near achievable limits and may not be sustainable over the long term. Table 2 presents a brief tolerance comparison for the two lattice types

  7. Isolation of proximity-induced triplet pairing channel in a superconductor/ferromagnet spin valve

    Science.gov (United States)

    Leksin, P. V.; Garif'yanov, N. N.; Kamashev, A. A.; Validov, A. A.; Fominov, Ya. V.; Schumann, J.; Kataev, V.; Thomas, J.; Büchner, B.; Garifullin, I. A.

    2016-03-01

    We have studied the proximity-induced superconducting triplet pairing in CoOx/Py1/Cu/Py2/Cu/Pb spin-valve structure (where Py = Ni0.81Fe0.19 ). By optimizing the parameters of this structure we found a triplet channel assisted full switching between the normal and superconducting states. To observe an "isolated" triplet spin-valve effect we exploited the oscillatory feature of the magnitude of the ordinary spin-valve effect Δ Tc in the dependence of the Py2-layer thickness dP y 2. We determined the value of dP y 2 at which Δ Tc caused by the ordinary spin-valve effect (the difference in the superconducting transition temperature Tc between the antiparallel and parallel mutual orientation of magnetizations of the Py1 and Py2 layers) is suppressed. For such a sample a "pure" triplet spin-valve effect which causes the minimum in Tc at the orthogonal configuration of magnetizations has been observed.

  8. All-electrical measurement of the relaxation time of a two-electron spin-triplet state in InAs quantum dots

    International Nuclear Information System (INIS)

    Many-particle spin states in self-assembled quantum dots (QDs) could serve as qubits in quantum information processing devices. However, in optical experiments always the excitonic states are measured, hence, electrical preparation and detection of pure excited many-particle states without electron-hole interaction are still missing. We demonstrate an all-electrical spectroscopy technique on an ensemble of InAs QDs. It allows us to prepare and detect the pure many-particle electron states with their spin-singlet and -triplet configurations, using a time-resolved measurement detection scheme via a 2DEG. This all-electrical measurement scheme enables us to determine the electron spin-relaxation time without an applied magnetic field and without optical excitation to 5 ms at 4 K. The spin relaxation time is independent on the applied magnetic field (up to 2 T) and slightly decreases down to 3 ms at 50 K.

  9. Parenting Stress, Infant Emotion Regulation, Maternal Sensitivity, and the Cognitive Development of Triplets: A Model for Parent and Child Influences in a Unique Ecology

    Science.gov (United States)

    Feldman, Ruth; Eidelman, Arthur I.; Rotenberg, Noa

    2004-01-01

    To examine the development of triplets, 23 sets of triplets were matched with 23 sets of twins and 23 singletons (N138). Maternal sensitivity was observed at newborn, 3, 6, and 12 months, and infants' cognitive and symbolic skills at 1 year. Triplets received lower maternal sensitivity across infancy and exhibited poorer cognitive competencies…

  10. Aqueous secondary organic aerosol (SOA) production from the oxidation of phenols by triplet excited state organics

    Science.gov (United States)

    Smith, J.; Yu, L.; Zhang, Q.; Anastasio, C.

    2011-12-01

    Recent literature has shown that atmospheric condensed-phase chemistry can play a significant role in the evolution of organic aerosols, including the formation of secondary organic aerosol (SOA). SOA formation from the oxidation of volatile organic compounds (VOCs) in the aqueous phase has largely focused on oxidations involving the hydroxyl radical and other oxidants, such as photochemically created triplet excited states, have not been fully investigated. Phenolic compounds are one of the primary carbon emission classes from biomass and wood combustion and have significant water solubility. Once in the aqueous phase, phenolic compounds can react with the triplet excited states of non-phenolic aromatic carbonyls (NPCs), particle-bound organics that are also emitted in large quantities from wood combustion. The oxidation of phenolic species in the condensed phase by triplet excited states can result in the production of SOA. A main goal of this study was to investigate bulk solution reaction kinetics under atmospherically relevant conditions in order to ascertain how these reactions can impact aqueous-phase SOA production. In our experiments, we studied the reactions of five phenols (phenol, guaiacol, syringol, catechol, and resorcinol) with the triplet state of 3,4-dimethoxybenzaldehyde (34-DMB) during simulated solar radiation. We have characterized the impacts of pH, ionic strength and reactant concentrations on the reaction behavior of this system. In addition, we analyzed the SOA formed using high-resolution aerosol mass spectrometry, ion chromatography, and liquid chromatography-mass spectrometry to infer the reaction mechanisms. Our evidence suggests that under atmospherically relevant conditions, triplet excited states can be the dominant oxidant of phenolics and contribute significantly to the total SOA budget.

  11. Observation of spin-triplet supercurrent in Co-based Josephson junctions

    Science.gov (United States)

    Birge, Norman

    2011-03-01

    When a superconductor (S) and a ferromagnet (F) are put into contact with each other, the combined S/F system may exhibit altogether new properties. There is a proximity effect where pair correlations from S penetrate into F, but these correlations decay over a very short distance due to the large exchange splitting between the spin-up and spin-down electron bands in F. Theory predicts that, under certain conditions, electron pair correlations can be generated with spin-triplet rather than spin-singlet symmetry. The two electrons in such a spin-triplet pair have parallel spins and are not subject to the exchange splitting in F; hence they propagate long distances. We have measured a long-range supercurrent in Josephson junctions of the form S/X/N/SAF/N/X/S, where S is a superconductor (Nb), N is a normal metal (Cu), SAF is a synthetic antiferromagnet of the form Co/Ru/Co, and X is a thin ferromagnetic layer necessary to induce spin-triplet correlations in the structure. Spin-triplet correlations are generated due to non-collinearity of the magnetizations in each X layer and the nearest Co layer. Using X = PdNi, CuNi, and Ni, we observe enhancements of the critical current of up to 300 times relative to similar samples lacking the X layers. We also observe a large additional enhancement of the spin-triplet supercurrent after the samples are magnetized in a large field. This result is counter-intuitive, since one would expect magnetizing the samples to suppress the occurrence of non-collinear magnetization. We will present a model of the SAF magnetization structure that explains these intriguing results. Work supported by the U.S. Dept. of Energy under grant DE-FG02-06ER46341.

  12. Quarkonium spectroscopy

    International Nuclear Information System (INIS)

    Recent experimental investigations of heavy quark-antiquark bound state systems are reviewed. Results from SPEAR on charmonium spectroscopy and from DORIS and CESR on bottomonium spectroscopy are presented. The current status of the search for top is also discussed

  13. Circular dichroism and UV melting studies on formation of an intramolecular triplex containing parallel T*A:T and G*G:C triplets: netropsin complexation with the triplex.

    OpenAIRE

    Gondeau, C.; Maurizot, J C; Durand, M

    1998-01-01

    We have used circular dichroism and UV absorption spectroscopy to characterize the formation and melting behaviour of an intramolecular DNA triple helix containing parallel T*A:T and G*G:C triplets. Our approach to induce and to stabilize a parallel triplex involves the oligonucleotide 5'-d(G4A4G4[T4]C4T4C4-[T4]G4T4G4) ([T4] represents a stretch of four thymine residues). In a 10 mM sodium cacodylate, 0.2 mM disodium EDTA (pH 7) buffer, we have shown the following significant results. (i) Whi...

  14. Microwave-optical double resonance spectroscopy. Progress report, February 1, 1975--January 31, 1976

    International Nuclear Information System (INIS)

    Zero-field and high-field optical detection of magnetic resonance (ODMR), electron paramagnetic resonance (EPR), and optical spectroscopy experiments were performed on several systems in order to further basic knowledge of the structure, reactions, and response to radiation of atoms, molecules, and ions. Results on the following studies are reported: the direct observation of level anticrossing and mixing effects in excited molecular triplet states; anomalous zero-field splittings in the lowest triplet state of 1-iodonaphthalene; evidence for second-order spin-orbit coupling and spin delocalization effects in the lowest triplet state of benzophenone; direct observation of the optical absorption spectra of reactive free radicals at room temperature; measurements of the activation and thermodynamic parameters of several cyclohexenyl and cyclohexanonyl radicals; complete analyses of the level anticrossing and cross relaxation spectra of oriented molecular triplet states; solutions to the spin Hamiltonian for S = 1, I = 5/2 systems in both zero-field and high-field, an improvement by a factor of ten in the resolution of ODMR experiments in high field; and measurements of the optical and magnetic resonance properties of a series of halogenated naphthalenes in their lowest triplet states

  15. Photophysical and photochemical properties of 4-thiouracil: time-resolved IR spectroscopy and DFT studies.

    Science.gov (United States)

    Zou, Xiaoran; Dai, Xiaojuan; Liu, Kunhui; Zhao, Hongmei; Song, Di; Su, Hongmei

    2014-06-01

    Intensified research interests are posed with the thionucleobase 4-thiouracil (4-TU), due to its important biological function as site-specific photoprobe to detect RNA structures and nucleic acid-nucleic acid contacts. By means of time-resolved IR spectroscopy and density functional theory (DFT) studies, we have examined the unique photophysical and photochemical properties of 4-TU. It is shown that 4-TU absorbs UVA light and results in the triplet formation with a high quantum yield (0.9). Under N2-saturated anaerobic conditions, the reactive triplet undergoes mainly cross-linking, leading to the (5-4)/(6-4) pyrimidine-pyrimidone product. In the presence of O2 under aerobic conditions, the triplet 4-TU acts as an energy donor to produce singlet oxygen (1)O2 by triplet-triplet energy transfer. The highly reactive oxygen species (1)O2 then reacts readily with 4-TU, leading to the products of uracil (U) with a yield of 0.2 and uracil-6-sulfonate (U(SO3)) that is fluorescent at ~390 nm. The product formation pathways and product distribution are well rationalized by the joint B3LYP/6-311+G(d,p) calculations. From dynamics and mechanistic point of views, these results enable a further understanding for 4-TU acting as reactive precursors for photochemical reactions relevant to (1)O2, which has profound implications for photo cross-linking, DNA photodamage, as well as photodynamic therapy studies. PMID:24820207

  16. Terahertz spectroscopy

    DEFF Research Database (Denmark)

    Jepsen, Peter Uhd

    2009-01-01

    In this presentation I will review methods for spectroscopy in the THz range, with special emphasis on the practical implementation of the technique known ad THz time-domain spectroscopy (THz-TDS). THz-TDS has revived the old field of far-infrared spectroscopy, and enabled a wealth of new...... activities that promise commercial potential for spectroscopic applications in the THz range. This will be illustrated with examples of spectroscopy of liquids inside their bottles as well as sensitive, quantitative spectroscopy in waveguides....

  17. Integrating a Triplet-triplet Annihilation Up-conversion System to Enhance Dye-sensitized Solar Cell Response to Sub-bandgap Light

    Science.gov (United States)

    Nattestad, Andrew; Cheng, Yuen Yap; MacQueen, Rowan W.; Wallace, Gordon G.; Schmidt, Timothy W.

    2014-01-01

    The poor response of dye-sensitized solar cells (DSCs) to red and infrared light is a significant impediment to the realization of higher photocurrents and hence higher efficiencies. Photon up-conversion by way of triplet-triplet annihilation (TTA-UC) is an attractive technique for using these otherwise wasted low energy photons to produce photocurrent, while not interfering with the photoanodic performance in a deleterious manner. Further to this, TTA-UC has a number of features, distinct from other reported photon up-conversion technologies, which renders it particularly suitable for coupling with DSC technology. In this work, a proven high performance TTA-UC system, comprising a palladium porphyrin sensitizer and rubrene emitter, is combined with a high performance DSC (utilizing the organic dye D149) in an integrated device. The device shows an enhanced response to sub-bandgap light over the absorption range of the TTA-UC sub-unit resulting in the highest figure of merit for up-conversion assisted DSC performance to date. PMID:25285452

  18. The vector resonance triplet with the direct coupling to the third quark generation

    CERN Document Server

    Gintner, Mikulas

    2013-01-01

    The effective Lagrangian with scalar and vector resonances that might result from new strong physics beyond the SM is formulated and studied. In particular, the scalar resonance representing the recently discovered 125-GeV boson is complemented with the SU(2)_{L+R} triplet of hypothetical vector resonances. Motivated by experimental and theoretical considerations, the vector resonance is allowed to couple directly to the third quark generation only. The coupling is chiral-dependent and the interaction of the right top quark can differ from that of the right bottom quark. To estimate the applicability range of the effective Lagrangian the unitarity of the gauge boson scattering amplitudes is analyzed. The experimental fits and limits on the free parameters of the vector resonance triplet are investigated.

  19. Using less Quantum Resource for Probabilistic Controlled Teleportation of a Triplet W State

    Directory of Open Access Journals (Sweden)

    Xian-Ming Wang

    2012-10-01

    Full Text Available In a recent paper [CHIN. PHYS. LETT. Vol.26,No.7(2009070306 ], DONG et al. proposed a scheme for probabilistic controlled teleportation of a triplet W state using combined non-maximally entangled channel of two Einstein–Podolsky–Rosen (EPR states and one Greenberger–Horne–Zeilinger (GHZ state. In this paper ,only using one Einstein–Podolsky–Rosen (EPR state and one Greenberger–Horne–Zeilinger (GHZ state,the scheme for probabilistic controlled teleportation of a triplet W state is presented. Furthermore, Comparing with the widely used Bell-State measurement, Alice performs orthogonal complete basis measurement in the current work. Then Bob can faithfully reconstruct the original state by performing relevant unitary transformations. The total probability of successful teleportation is only dependent on channel coefficients of EPR state and GHZ state.  

  20. TripNet: A Method for Constructing Phylogenetic Networks from Triplets

    CERN Document Server

    Tusserkani, Ruzbeh; Poormohammadi, Hadi; Azadi, Azin

    2011-01-01

    We present TripNet, a method for constructing phylogenetic networks from triplets. We will present the motivations behind our approach and its theoretical and empirical justification. To demonstrate the accuracy and efficiency of TripNet, we performed two simulations and also applied the method to five published data sets: Kreitman's data, a set of triplets from real yeast data obtained from the Fungal Biodiversity Center in Utrecht, a collection of 110 highly recombinant Salmonella multi-locus sequence typing sequences, and nrDNA ITS and cpDNA JSA sequence data of New Zealand alpine buttercups of Ranunculus sect. Pseudadonis. Finally, we compare our results with those already obtained by other authors using alternative methods. TripNet, data sets, and supplementary files are freely available for download at (www.bioinf.cs.ipm.ir/softwares/tripnet).

  1. Quench Limit Calculation for Steady State Heat Deposits in LHC Inner Triplet Magnets

    CERN Document Server

    Cerutti, F; Esposito, L S; Siemko, A; Bocian, D

    2012-01-01

    In hadron colliders such as the LHC, the energy deposited in the superconductors by the particles lost from the beams or coming from the collision debris may provoke quenches detrimental to the accelerator operation. A Network Model is used to simulate the thermodynamic behavior of the superconducting magnets. In previous papers the validations of network model with measurements performed in the CERN and Fermilab magnet test facilities were presented. This model was subsequently used for thermal analysis of the current LHC inner triplet quadrupole magnets for beam energy of 3.5 TeV and 7.0 TeV. The detailed study of helium cooling channels efficiency for energy deposits simulated with FLUKA was performed. The expected LHC inner triplet magnets quench limit is presented.

  2. He II Heat Exchanger Test Unit for the LHC Inner Triplet

    CERN Document Server

    Blanco-Viñuela, E; Huang, Y; Nicol, T H; Peterson, T; Van Weelderen, R

    2002-01-01

    The Inner Triplet Heat Exchanger Test Unit (IT-HXTU) is a 30-m long thermal model designed at Fermilab, built in US industry, fully automated and tested at CERN as part of the US LHC program to develop the LHC Interaction Region quadrupole system. The cooling scheme of the IT-HXTU is based on heat exchange between stagnant pressurized He II in the magnet cold mass and saturated He II (two-phase) flowing in a heat exchanger located outside of and parallel to the cold mass. The purposes of this test are, among others, to validate the proposed cooling scheme and to define an optimal control strategy to be implemented in the future LHC accelerator. This paper discusses the results for the heat exchanger test runs and emphasizes the thermal and hydraulic behavior of He II for the inner triplet cooling scheme.

  3. Superfluid phases of triplet pairing and rapid cooling of the neutron star in Cassiopeia A

    Directory of Open Access Journals (Sweden)

    Lev B. Leinson

    2015-02-01

    Full Text Available In a simple model it is demonstrated that the neutron star surface temperature evolution is sensitive to the phase state of the triplet superfluid condensate. A multicomponent triplet pairing of superfluid neutrons in the core of a neutron star with participation of several magnetic quantum numbers leads to neutrino energy losses exceeding the losses from the unicomponent pairing. A phase transition of the neutron condensate into the multicomponent state triggers more rapid cooling of superfluid core in neutron stars. This makes it possible to simulate an anomalously rapid cooling of neutron stars within the minimal cooling paradigm without employing any exotic scenarios suggested earlier for rapid cooling of isolated neutron star in Cassiopeia A.

  4. Does interchain stacking morphology contribute to the singlet-triplet interconversion dynamics in polymer heterojunctions?

    International Nuclear Information System (INIS)

    Time-dependent density functional theory (TD-DFT) is used to examine the effect of stacking in a model semiconducting polymer hetrojunction system consisting of two co-facially stacked oligomers. We find that the excited electronic states are highly sensitive to the alignment of the monomer units of the two chains. In the system we examined, the exchange energy is nearly identical to both the and band off-set at the heterojunction and to the exciton binding energy. Our results indicate that the triplet excitonic states are nearly degenerate with the singlet exciplex states opening the possibility for the interconversion of singlet and triplet electronic states at the heterojunction interface via spin-orbit coupling localized on the heteroatoms. Using Russell-Saunders theory, we estimate this interconversion rate to be approximately 700-800 ps, roughly a 5-10-fold increase compared to isolated organic polymer chains

  5. Does interchain stacking morphology contribute to the singlet-triplet interconversion dynamics in polymer heterojunctions?

    Science.gov (United States)

    Bittner, Eric R.; Burghardt, Irene; Friend, Richard H.

    2009-02-01

    Time-dependent density functional theory (TD-DFT) is used to examine the effect of stacking in a model semiconducting polymer hetrojunction system consisting of two co-facially stacked oligomers. We find that the excited electronic states are highly sensitive to the alignment of the monomer units of the two chains. In the system we examined, the exchange energy is nearly identical to both the and band off-set at the heterojunction and to the exciton binding energy. Our results indicate that the triplet excitonic states are nearly degenerate with the singlet exciplex states opening the possibility for the interconversion of singlet and triplet electronic states at the heterojunction interface via spin-orbit coupling localized on the heteroatoms. Using Russell-Saunders theory, we estimate this interconversion rate to be approximately 700-800 ps, roughly a 5-10-fold increase compared to isolated organic polymer chains.

  6. Triplet repeat DNA structures and human genetic disease: dynamic mutations from dynamic DNA

    Indian Academy of Sciences (India)

    Richard R Sinden; Vladimir N Potaman; Elena A Oussatcheva; Christopher E Pearson; Yuri L Lyubchenko; Luda S Shlyakhtenko

    2002-02-01

    Fourteen genetic neurodegenerative diseases and three fragile sites have been associated with the expansion of (CTG)n•(CAG)n, (CGG)n•(CCG)n, or (GAA)n•(TTC)n repeat tracts. Different models have been proposed for the expansion of triplet repeats, most of which presume the formation of alternative DNA structures in repeat tracts. One of the most likely structures, slipped strand DNA, may stably and reproducibly form within triplet repeat sequences. The propensity to form slipped strand DNA is proportional to the length and homogeneity of the repeat tract. The remarkable stability of slipped strand DNA may, in part, be due to loop-loop interactions facilitated by the sequence complementarity of the loops and the dynamic structure of three-way junctions formed at the loop-outs.

  7. Photopolymer material sensitized by xanthene dyes for holographic recording using forbidden singlet–triplet electronic transitions

    Science.gov (United States)

    Shelkovnikov, Vladimir; Vasiljev, Evgeny; Russkih, Vladimlen; Berezhnaya, Viktoria

    2016-07-01

    A new holographic photopolymer material is developed. The photopolymer material is sensitized by dyes of xanthene and thioxanthene series which contain iodine and bromine heavy atoms. Holographic recording was carried out during excitation of forbidden singlet–triplet electron transitions of dyes. Thioerythrosin triethylammonium was identified as the most effective sensitizer among a number of tested dyes. The spectral absorption area of the singlet–triplet electronic transition of the dye is conveyed in the red spectral range from 600 to 700 nm. The sensitivity of the photopolymer material to radiation with 633 nm wavelength is 180 mJ cm‑2. Optimization of concentration of the main components of the photopolymer compositions was carried out in order to achieve maximum efficiency of holographic recording.

  8. Beam Dynamics Requirements for the Powering Scheme of the HL-LHC Triplet

    CERN Document Server

    AUTHOR|(CDS)2075212; Fartoukh, Stephane; Giovannozzi, Massimo

    2015-01-01

    For the HL-LHC, β ∗ values as small as 15 cm are envisaged as baseline scenario for the high luminosity insertions IR1 and IR5, thus leading to an increase of the maximum β- functions in the inner triplet (IT). The larger beta-functions in the IT result in a higher sensitivity of the beam to any linear or non-linear, static or dynamic, field imperfections in the IT region. In this paper, we summarize accordingly the tolerances of the triplet power supplies in terms of current ripple, stability and reproducibility. Both the baseline IT powering scheme and other alternative schemes will be presented, the later reducing the tune shift caused by a current modulation and thus weakening its possible impact on the long term stability.

  9. The vector resonance triplet with the direct coupling to the third quark generation

    International Nuclear Information System (INIS)

    The effective Lagrangian with scalar and vector resonances that might result from new strong physics beyond the SM is formulated and studied. In particular, the scalar resonance representing the recently discovered 125-GeV boson is complemented with the SU(2)L+R triplet of hypothetical vector resonances. Motivated by experimental and theoretical considerations, the vector resonance is allowed to couple directly to the third quark generation only. The coupling is chiral-dependent and the interaction of the right top quark can differ from that of the right bottom quark. To estimate the applicability range of the effective Lagrangian the unitarity of the gauge boson scattering amplitudes is analyzed. The experimental fits and limits on the free parameters of the vector resonance triplet are investigated. (orig.)

  10. The vector resonance triplet with the direct coupling to the third quark generation

    Energy Technology Data Exchange (ETDEWEB)

    Gintner, Mikulas [University of Zilina, Physics Department, Zilina (Slovakia); Czech Technical University in Prague, Institute of Experimental and Applied Physics, Prague (Czech Republic); Juran, Josef [Czech Technical University in Prague, Institute of Experimental and Applied Physics, Prague (Czech Republic); Silesian University in Opava, Institute of Physics, Opava (Czech Republic)

    2013-10-15

    The effective Lagrangian with scalar and vector resonances that might result from new strong physics beyond the SM is formulated and studied. In particular, the scalar resonance representing the recently discovered 125-GeV boson is complemented with the SU(2){sub L+R} triplet of hypothetical vector resonances. Motivated by experimental and theoretical considerations, the vector resonance is allowed to couple directly to the third quark generation only. The coupling is chiral-dependent and the interaction of the right top quark can differ from that of the right bottom quark. To estimate the applicability range of the effective Lagrangian the unitarity of the gauge boson scattering amplitudes is analyzed. The experimental fits and limits on the free parameters of the vector resonance triplet are investigated. (orig.)

  11. Triplet superconductivity through quadrupolar exciton exchange in PrOs4Sb12

    International Nuclear Information System (INIS)

    Superconducting pair formation in heavy fermion (HF) compounds is usually attributed to the exchange of over-damped bosonic spin fluctuation modes in the itinerant quasiparticle system. A different mechanism based on the exchange of propagating CEF excitations, i.e., magnetic excitons has previously been identified for UPd2Al3 [Sato, et al., Nature 410 (2001) 340; McHale, et al., Phys. Rev. B 70 (2004) 014513]. We propose a similar model for the tetrahedral (Th) HF superconductor PrOs4Sb12. There low energy singlet-triplet CEF excitations exist which disperse into quadrupolar exciton bands as observed in inelastic neutron scattering (INS). Virtual exchange of these collective modes due to aspherical Coulomb scattering leads to Cooper pair formation. Calculations of the effective pairing interactions in non-retarded weak coupling approximation for the irreducible Th channels are presented. The triplet Tu symmetry is favored for the gap function

  12. Singlet-Triplet Transitions of a P(o)schl-Teller Quantum Dot

    Institute of Scientific and Technical Information of China (English)

    XIE Wen-Fang

    2006-01-01

    We study the energy spectra of a two-dimensional two-electron quantum dot (QD) with P(o)schl-Teller confining potential under the influence of perpendicular homogeneous magnetic field. Calculations are made by using the method of numerical diagonalization of Hamiltonian matrix within the effective-mass approximation. A ground-state behavior (spin singlet-triplet transitions) as a function of the strength of a magnetic field is found. We find that the dot radius R of a P(o)schl-Teller potential is important for the ground-state transition and the feature of ground-state for a P(o)schl-Teller QD and a parabolic QD is similar when R is larger. The larger the well depth, the higher the magnetic field for the singlet-triplet transition of the ground-state of two interacting electrons in a P(o)schl-Teller QD.

  13. Direct Observation of Triplet-State Population Dynamics in the RNA Uracil Derivative 1-Cyclohexyluracil.

    Science.gov (United States)

    Brister, Matthew M; Crespo-Hernández, Carlos E

    2015-11-01

    Investigation of the excited-state dynamics in nucleic acid monomers is an area of active research due to the crucial role these early events play in DNA and RNA photodamage. The dynamics and rate at which the triplet state is populated are key mechanistic pathways yet to be fully elucidated. Direct spectroscopic evidence is presented in this contribution for intersystem crossing dynamics in a uracil derivative, 1-cyclohexyluracil. It is shown that intersystem crossing to the triplet manifold occurs in one picosecond or less in acetonitrile solution-at least an order of magnitude faster than previously estimated experimentally. Broadband transient absorption measurements also reveal the primary electronic relaxation pathways of the uracil chromophore, including the absorption spectra of the (1)ππ*, (1)nπ*, and (3)ππ* states and the rates of vibrational cooling in the ground and (3)ππ* states. The experimental results are supported by density functional calculations. PMID:26538051

  14. Recent emergence of photon upconversion based on triplet energy migration in molecular assemblies.

    Science.gov (United States)

    Yanai, Nobuhiro; Kimizuka, Nobuo

    2016-04-01

    An emerging field of triplet energy migration-based photon upconversion (TEM-UC) is reviewed. Highly efficient photon upconversion has been realized in a wide range of chromophore assemblies, such as non-solvent liquids, ionic liquids, amorphous solids, gels, supramolecular assemblies, molecular crystals, and metal-organic frameworks (MOFs). The control over their assembly structures allows for unexpected air-stability and maximum upconversion quantum yield at weak solar irradiance that has never been achieved by the conventional molecular diffusion-based mechanism. The introduction of the "self-assembly" concept offers a new perspective in photon upconversion research and triplet exciton science, which show promise for numerous applications ranging from solar energy conversion to chemical biology. PMID:26947379

  15. Spin-triplet supercurrent in Co/Ni multilayer Josephson junctions with perpendicular anisotropy

    Science.gov (United States)

    Gingrich, E. C.; Quarterman, P.; Wang, Yixing; Loloee, R.; Pratt, W. P., Jr.; Birge, Norman O.

    2012-12-01

    We have measured spin-triplet supercurrent in Josephson junctions of the form S/F'/F/F'/S, where S is superconducting Nb, F' is a thin Ni layer with in-plane magnetization, and F is a Ni/[Co/Ni]n multilayer with out-of-plane magnetization. The supercurrent in these junctions decays very slowly with F-layer thickness and is much larger than in similar junctions not containing the two F' layers. Those two features are the characteristic signatures of spin-triplet supercurrent, which is maximized by the orthogonality of the magnetizations in the F and F' layers. Magnetic measurements confirm the out-of-plane anisotropy of the Co/Ni multilayers. These samples have their critical current optimized in the as-prepared state, which will be useful for future applications.

  16. Controllable generation of a spin-triplet supercurrent in a Josephson spin valve

    Science.gov (United States)

    Iovan, Adrian; Golod, Taras; Krasnov, Vladimir M.

    2014-10-01

    It has been predicted theoretically that an unconventional odd-frequency spin-triplet component of a superconducting order parameter can be induced in multilayered ferromagnetic structures with noncollinear magnetization. In this work, we study experimentally nanoscale devices, in which a ferromagnetic spin valve is embedded into a Josephson junction. We demonstrate two ways of in situ analysis of such Josephson spin valves: via magnetoresistance measurements and via in situ magnetometry based on flux quantization in the junction. We observe that supercurrent through the device depends on the relative orientation of magnetizations of the two ferromagnetic layers and is enhanced in the noncollinear state of the spin valve. We attribute this phenomenon to controllable generation of the spin-triplet superconducting component in a ferromagnet.

  17. Experimental triplet and quadruplet fluctuation densities and spatial distribution function integrals for liquid mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Ploetz, Elizabeth A.; Smith, Paul E. [Department of Chemistry, Kansas State University, 213 CBC Building, Manhattan, Kansas 66506 (United States)

    2015-03-07

    Kirkwood-Buff or Fluctuation Solution Theory can be used to provide experimental pair fluctuations, and/or integrals over the pair distribution functions, from experimental thermodynamic data on liquid mixtures. Here, this type of approach is used to provide triplet and quadruplet fluctuations, and the corresponding integrals over the triplet and quadruplet distribution functions, in a purely thermodynamic manner that avoids the use of structure factors. The approach is then applied to binary mixtures of water + methanol and benzene + methanol over the full composition range under ambient conditions. The observed correlations between the different species vary significantly with composition. The magnitude of the fluctuations and integrals appears to increase as the number of the most polar molecule involved in the fluctuation or integral also increases. A simple physical picture of the fluctuations is provided to help rationalize some of these variations.

  18. Effect of isoscalar spin-triplet pairings on spin-isospin responses in $sd-$ shell nuclei

    CERN Document Server

    Sagawa, H; Sasano, M

    2016-01-01

    The spin magnetic dipole transitions and the neutron-proton spin-spin correlations in $sd-$shell even-even nuclei with $N=Z$ are investigated using shell model wave functions. The isoscalar spin-triplet pairing correlation provides a substantial quenching effect on the spin magnetic dipole transitions, especially the isovector (IV) ones. Consequently, an enhanced isoscalar spin-triplet pairing interaction influences the proton-neutron spin-spin correlation deduced from the difference between the isoscalar (IS) and the IV sum rule strengths. The effect of the $\\Delta$ ($\\Delta_{33}$ resonance)-hole coupling is examined in the IV spin transition and the spin-spin correlations of the ground states.

  19. Transient Neutron Transport in Semi-Infinite Media for Pure-Triplet Scattering

    International Nuclear Information System (INIS)

    The transient neutron transport in a semi-infinite medium with pure-triplet scattering is presented. Case s eigenfunctions for this problem can be obtained for this high order anisotropic scattering and orthogonality relations of these eigenfunctions can be derived mathematically. The reflectivity at the boundary, radiant energy and net heat flux are computed for specular-reflecting boundary with angular-dependent externally-incident flux. For the sake of comparison, we use two different weight functions in our calculations

  20. Dicephalic parapagus tribrachius conjoined twins in a triplet pregnancy: a case report.

    OpenAIRE

    Mahbod Kaveh; Kamyar Kamrani; Mohsen Naseri; Morteza Danaeian; Farhad Asadi; Fatemeh Davari-Tanha

    2014-01-01

    Dicephalic parapagus tribrachius conjoined twin is a very rare condition. We present a case of 5-days-old male dicephalic parapagus conjoined twins. The conjoined twins were diagnosed in 4(th) month of pregnancy by ultrasonography. The pregnancy terminates at 36 weeks by cesarean section and triplets were born. The babies were male conjoined twins and another healthy male baby. Many congenital defects of interest can now be detected before birth. Sever form of this malformation precludes post...

  1. Triplet versus singlet entangled states in teaching the Einstein–Podolsky–Rosen paradox

    International Nuclear Information System (INIS)

    The Einstein–Podolsky–Rosen paradox is considered using spin- 1/2 singlet and triplet states prepared in the z-direction, after which measurements are made in a different direction, the x-direction, for example. An unexpected outcome and its usefulness for teaching is reported. The material will be of interest to upper-year undergraduate quantum mechanics instructors and students. (paper)

  2. Complex bilateral polysyndactyly featuring a triplet of delta phalanges in a syndactylised digit

    International Nuclear Information System (INIS)

    The delta phalanx is a rare congenital skeletal anomaly. An abnormal C-shaped epiphysis is usually responsible for a progressive angular digital deformity observed either in hands or feet. Solitary delta phalanges are usually described. We report a case of bilateral congenital hand malformations featuring a triplet of delta phalanges affecting a single digit on one hand, together with a concealed central polydactyly on the other. (orig.)

  3. Adler-type sum rule, charge symmetry and neutral current in general multi-triplet model

    International Nuclear Information System (INIS)

    We derive Adler-type sum rule extended to general multi-triplet model. Paying attention to roles of the colour degree of freedom, we discuss the charge symmetry property of the weak charged current and the structure functions for ν(ν-)+N→l(l-)+X, and also the structure of the neutral current. A comment is given on implications in our theory of Koike and Konuma's result on the neutral hadronic current. (auth.)

  4. Footprint of Triplet Scalar Dark Matter in Direct, Indirect Search and Invisible Higgs Decay

    CERN Document Server

    Ayazi, Seyed Yaser

    2015-01-01

    In this talk, we will review Inert Triplet Model (ITM) which provide candidate for dark matter (DM) particles. Then we study possible decays of Higgs boson to DM candidate and apply current experimental data for invisible Higgs decay to constrain parameter space of ITM. We also consider indirect search for DM and use FermiLAT data to put constraints on parameter space. Ultimately we compare this limit with constraints provided by LUX experiment for low mass DM and invisible Higgs decay.

  5. Beginning Chemistry Teachers Use of the Triplet Relationship During their First Three Years in the Classroom

    Science.gov (United States)

    Adams, Krista

    Pedagogical content knowledge (PCK) has been described as the knowledge teachers' use in the process of designing and implementing lessons to a particular group of students. This includes the most effective representations that make the content understandable to students, together with the preconceptions and misconceptions that students hold. For chemistry, students have been found to have difficulty with the discipline due to its reliance upon three levels of representation called the triplet: the macro, the submicro, and the symbolic. This study examines eight beginning chemistry teachers' depiction of the chemistry content through the triplet relationship and modifications as a result of considering students' understanding across the teacher's first three years in the classroom. The data collected included classroom observations, interviews, and artifacts for the purpose of triangulation. The analysis of the data revealed that beginning chemistry teachers utilized the abstract components, submicro and symbolic, primarily in the first year. However, the teachers began to engage more macro representations over time building a more developed instructional repertoire. Additionally, teachers' developed an awareness of and responded to their students' understanding of learning atomic structure during the second and third year teaching. The results of this study call for preservice and induction programs to help novice chemistry teachers build a beginning repertoire that focuses on the triplet relationship. In so doing, the teachers enter the classroom with a repertoire that allows them to address the needs of their students. Finally, the study suggests that the triplet relationship framework should be revisited to include an additional component that frames learning to account for socioscientific issues and historical contributions.

  6. Fusion Rules of the ${\\cal W}_{p,q}$ Triplet Models

    CERN Document Server

    Wood, Simon

    2009-01-01

    In this paper we determine the fusion rules of the logarithmic ${\\calW}_{p,q}$ triplet theory and construct the Grothendieck group with subgroups for which consistent product structures can be defined. The fusion rules are then used to determine projective covers. This allows us also to write down a candidate for a modular invariant partition function. Our results demonstrate that recent work on the ${\\cal W}_{2,3}$ model generalises naturally to arbitrary (p,q).

  7. Design and construction of triplet atmospheric cold plasma jet for sterilization

    OpenAIRE

    F. Sohbatzadeh; A. Hossienzadeh Colagar; S. Mirzanejhad; S. Motallebi; M Farhadi; M. Bagheri; H. Memariani; A. Valinataj; M Mortazavi

    2014-01-01

    In this paper, construction of triplet atmospheric plasma jet using argon, air, oxygen and nitrogen gases is reported. Bactericidal effect of the plasma jet is also investigated. To that end, longitudinal geometric configuration for the electrodes was chosen because it would increase the jet length. Electrical characteristics, jet length dependencies on the applied voltage and gas flow rate were decided, experimentally. Relative concentrations of chemical reactive species such as ozone, atomi...

  8. Photoinduced charge injection from excited triplet hypocrellin B into TiO2 colloid in ethanol

    Institute of Scientific and Technical Information of China (English)

    SHEN, Jian-Quan; SHEN, Tao; ZHANG, Man-Hua; LI, Wen; SONG, Ai-Min

    2000-01-01

    Photosensitization of TiO2 colloid by hypocrellin B (HB), a natural photodynamic pigment with extremely high plhotosta bility, has been studied by surface enhanced Raman spec troscorpy (SERS), laser flash photolysis and electron param agnetic resonance (EPR) techniques. The photosensitization of TiO2 occurred practically from the excited triplet dye and the electron injection rate constant is 1.3 × 106 s-1. The influ ences of donor and acceptor on the eleciron injection were in vestigated.

  9. Higgs(es) in triplet extended supersymmetric standard model at the LHC

    CERN Document Server

    Bandyopadhyay, Priyotosh; Keçeli, Aslı Sabancı

    2014-01-01

    The recent discovery of the $\\sim 125$ GeV Higgs boson by Atlas and CMS experiments has set strong constraints on parameter space of the minimal supersymmetric model (MSSM). However these constraints can be weakened by enlarging the Higgs sector by adding a triplet chiral superfield. In particular, we focus on the $Y=0$ triplet extension of MSSM, known as TESSM, where the electroweak contributions to the lightest Higgs mass are also important and comparable with the strong contributions. We discuss this in the context of the observed Higgs like particle around 125 GeV and also look into the status of other Higgs bosons in the model. We calculate the Br($B_s \\to X_s \\gamma$) in this model where three physical charged Higgs bosons and three charginos contribute. We show that the doublet-triplet mixing in charged Higgses plays an important role in constraining the parameter space. In this context we also discuss the phenomenology of light charged Higgs probing $H^\\pm_1-W^\\mp-Z$ coupling at the LHC.

  10. Numerical study of the singlet-triplet model for cuprate superconductors

    International Nuclear Information System (INIS)

    We perform a low-energy reduction of the three-band Hubbard Hamiltonian (H3b), keeping in the relevant Hilbert subspace not only local singlets (Zhang-Rice singlets), but also triple states between Cu holes and O holes at the Wannier function of the same site, with x2 - y2 symmetry. We solve exactly the resulting Hamiltonian in a system of 2 x 2 unit cells. We find that the local triplet states can be practically neglected for finite O-Cu on-site energy difference Δ, very large Cu on-site Coulomb repulsion Ud, and O-O hopping tpp=0. This fact is in contrast with the mapping of H3b to a one-band model using non-orthogonal singlets, which is very accurate when the Cu+ configuration can be neglected. Although the amount of local triplet states in the low-energy eigenstates is in general small, it increases with tpp and for large tpp it is necessary to introduce higher order corrections in the one-band model to accurately represent the low-energy physics. In all cases even when local triplets are not important, the t-J model should be supplemented with other terms, to describe the lowest energy levels. We also discuss briefly the effect of non-bonding O orbitals. (author). 25 refs, 7 figs

  11. Energy deposition studies for the high-luminosity Large Hadron Collider inner triplet magnets

    Science.gov (United States)

    Mokhov, N. V.; Rakhno, I. L.; Tropin, I. S.; Cerutti, F.; Esposito, L. S.; Lechner, A.

    2015-05-01

    A detailed model of the high-luminosity LHC inner triplet region with new large-aperture Nb3Sn magnets, field maps, corrector packages, and segmented tungsten inner absorbers was built and implemented into the fluka and mars15 codes. Detailed simulations have been performed coherently with the codes on the impact of particle debris from the 14-TeV center-of-mass pp-collisions on the short- and long-term stability of the inner triplet magnets. After optimizing the absorber configuration, the peak power density averaged over the magnet inner cable width is found to be safely below the quench limit at the luminosity of 5 ×1034 cm-2 s-1 . For the anticipated lifetime integrated luminosity of 3000 fb-1 , the peak dose calculated for the innermost magnet insulator ranges from 20 to 35 MGy, a figure close to the commonly accepted limit. Dynamic heat loads to the triplet magnet cold mass are calculated to evaluate the cryogenic capability. fluka and mars results on energy deposition are in very good agreement.

  12. Magnetic dipolar interaction between correlated triplets created by singlet fission in tetracene crystals

    CERN Document Server

    Wang, Rui; Zhang, Bo; Liu, Yunlong; Wang, Xiaoyong; Xiao, Min

    2015-01-01

    Singlet fission (SF) can potentially break the Shockley-Queisser efficiency limit in single-junction solar cells by splitting one photo-excited singlet exciton (S1) into two triplets (2T1) in organic semiconductors. A dark multi-exciton (ME) state has been proposed as the intermediate connecting S1 to 2T1. However, the exact nature of this ME state, especially how the doubly-excited triplets interact, remains elusive. Here, we report a quantitative study on the magnetic dipolar interaction between SF-induced correlated triplets in tetracene crystals by monitoring quantum beats relevant to the ME sublevels at room temperature. The resonances of ME sublevels approached by tuning an external magnetic field are observed to be avoided, which agrees well with the theoretical predictions considering a magnetic dipolar interaction of ~ 0.008 GHz. Our work paves a way to quantify the magnetic dipolar interaction in organic materials and marks an important step towards understanding the underlying physics of the ME sta...

  13. Experimental evidences of singlet to triplet transition in a spin cluster compound

    Energy Technology Data Exchange (ETDEWEB)

    Chakraborty, Tanmoy [Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur Campus, PO: BCKV Campus Main Office, Nadia, Mohanpur 741246, West Bengal (India); Experimental Physics III, Fakultät Physik, TU Dortmund, 44221 Dortmund (Germany); Singh, Harkirat [Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur Campus, PO: BCKV Campus Main Office, Nadia, Mohanpur 741246, West Bengal (India); Department of Condensed Matter Physics and Material Sciences, Tata Institute of Fundamental Research, Homi Bhabha Road, Colaba, Mumbai 400 005 (India); Mitra, Chiranjib, E-mail: chiranjib@iiserkol.ac.in [Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur Campus, PO: BCKV Campus Main Office, Nadia, Mohanpur 741246, West Bengal (India)

    2015-12-15

    Experimental realization of magnetic field induced singlet to triplet transition is reported for NH{sub 4}CuPO{sub 4}·H{sub 2}O, a two spin cluster material with isotropic Heisenberg interaction. Experimental magnetization and specific heat data have been collected as a function of temperature and magnetic field. Experimental data have been analyzed in terms of Heisenberg dimer model. Two quantum complementary observables representing local and non-local properties of the spins are constructed using the experimental data and a clear evidence of singlet to triplet transition is observed through partial quantum information sharing when the magnetic field is swept through a particular value. Signature of this transition has also been captured when specific heat is measured as a function of magnetic field. Furthermore, using the experimental specific heat data, magnetic energy values are calculated and their variations are captured as a function of magnetic field and temperature. - Highlights: • Magnetic field induced energy level crossing is reported for NH{sub 4}CuPO{sub 4}·H{sub 2}O. • Magnetic data are analyzed within the framework of spin 1/2 dimer model. • Singlet-triplet transition is captured employing quantum complementarity principle. • Field dependent specific heat data also provides the signature of the transition.

  14. Interplanetary medium and geomagnetic activity after compact flare triplets 1966-1981

    International Nuclear Information System (INIS)

    The interplanetary medium state and geomagnetic activity when the Earth is getting into this or that interplanetary disturbance zone after flare triplets, i.e. trains of three solar flares out of an active zone, are considered. There are the following conditionally differentiated zones in the interplanetary disturbance configuration: a forbidden (F), a perturbed (P) and a normal (N) zones of interplanetary disturbance. The interplanetary medium disturbances and geomagnetic activity after trains of three flares of class 2 and higher out of one of active zones depend on the following factors: the magnetic axis orientation of a bipolar group of active zone spots appeared after flares, time interval between the first and second flares in the train, flare intensity. The conditions of maximum disturbance occurrence pointed out. The interplanetary and geomagnetic disturbance intensity in the N zone is higher than that of the F and P zones (i.e. in the proximity of the great circle planes passing through the flares parallel with tha active zone magnetic axes), and it is higher after quasicompact rather than after compact triplets (i.e. it considerably grows when passing over the critical value of the time interval betwenn the first and second triplet flares, τ12=16 h)

  15. Non-Linear Advanced Control of the LHC Inner Triplet Heat Exchanger Test Unit

    CERN Document Server

    Blanco-Viñuela, E; De Prada-Moraga, C; Cristea, S

    2002-01-01

    The future Large Hadron Collider (LHC) at CERN will include eight interaction region final focus magnet systems, the so-called "Inner Triplet", one on each side of the four beam collision points. The Inner Triplets will be cooled in a static bath of pressurized He II nominally at 1.9 K. This temperature is a control parameter and has very severe constraints in order to avoid the transition from the superconducting to normal resistive state. The main difference in these special zones with respect to a regular LHC cell is higher dynamic heat load unevenly distributed which modifies largely the process characteristics and hence the controller performance. Several control strategies have already been tested at CERN in a pilot plant (LHC String Test) which reproduced a LHC half-cell. In order to validate a common control structure along the whole LHC ring, a Nonlinear Model Predictive Control (NMPC) has been developed and implemented in the Inner Triplet Heat Exchanger Unit (IT-HXTU) at CERN. Automation of the Inn...

  16. Analysis of Triplet Exciton Loss Pathways in PTB7:PC71BM Bulk Heterojunction Solar Cells

    Science.gov (United States)

    Kraus, Hannes; Heiber, Michael C.; Väth, Stefan; Kern, Julia; Deibel, Carsten; Sperlich, Andreas; Dyakonov, Vladimir

    2016-01-01

    A strategy for increasing the conversion efficiency of organic photovoltaics has been to increase the VOC by tuning the energy levels of donor and acceptor components. However, this opens up a new loss pathway from an interfacial charge transfer state to a triplet exciton (TE) state called electron back transfer (EBT), which is detrimental to device performance. To test this hypothesis, we study triplet formation in the high performing PTB7:PC71BM blend system and determine the impact of the morphology-optimizing additive 1,8-diiodoctane (DIO). Using photoluminescence and spin-sensitive optically detected magnetic resonance (ODMR) measurements at low temperature, we find that TEs form on PC71BM via intersystem crossing from singlet excitons and on PTB7 via EBT mechanism. For DIO blends with smaller fullerene domains, an increased density of PTB7 TEs is observed. The EBT process is found to be significant only at very low temperature. At 300 K, no triplets are detected via ODMR, and electrically detected magnetic resonance on optimized solar cells indicates that TEs are only present on the fullerenes. We conclude that in PTB7:PC71BM devices, TE formation via EBT is impacted by fullerene domain size at low temperature, but at room temperature, EBT does not represent a dominant loss pathway. PMID:27380928

  17. Experimental evidences of singlet to triplet transition in a spin cluster compound

    International Nuclear Information System (INIS)

    Experimental realization of magnetic field induced singlet to triplet transition is reported for NH4CuPO4·H2O, a two spin cluster material with isotropic Heisenberg interaction. Experimental magnetization and specific heat data have been collected as a function of temperature and magnetic field. Experimental data have been analyzed in terms of Heisenberg dimer model. Two quantum complementary observables representing local and non-local properties of the spins are constructed using the experimental data and a clear evidence of singlet to triplet transition is observed through partial quantum information sharing when the magnetic field is swept through a particular value. Signature of this transition has also been captured when specific heat is measured as a function of magnetic field. Furthermore, using the experimental specific heat data, magnetic energy values are calculated and their variations are captured as a function of magnetic field and temperature. - Highlights: • Magnetic field induced energy level crossing is reported for NH4CuPO4·H2O. • Magnetic data are analyzed within the framework of spin 1/2 dimer model. • Singlet-triplet transition is captured employing quantum complementarity principle. • Field dependent specific heat data also provides the signature of the transition

  18. A spin triplet supercurrent through the half-metallic ferromagnet CrO2

    Science.gov (United States)

    Keizer, R. S.; Goennenwein, S. T. B.; Klapwijk, T. M.; Miao, G.; Xiao, G.; Gupta, A.

    2006-02-01

    In general, conventional superconductivity should not occur in a ferromagnet, though it has been seen in iron under pressure. Moreover, theory predicts that the current is always carried by pairs of electrons in a spin singlet state, so conventional superconductivity decays very rapidly when in contact with a ferromagnet, which normally prohibits the existence of singlet pairs. It has been predicted that this rapid spatial decay would not occur if spin triplet superconductivity could be induced in the ferromagnet. Here we report a Josephson supercurrent through the strong ferromagnet CrO2, from which we infer that it is a spin triplet supercurrent. Our experimental set-up is different from those envisaged in the earlier predictions, but we conclude that the underlying physical explanation for our result is a conversion from spin singlet pairs to spin triplets at the interface. The supercurrent can be switched with the direction of the magnetization, analogous to spin valve transistors, and therefore could enable magnetization-controlled Josephson junctions.

  19. Quantum dynamics study of singlet-triplet transitions in s-trans-1,3-butadiene

    Science.gov (United States)

    Nikoobakht, Behnam; Köppel, Horst

    2016-05-01

    The intersystem crossing dynamics of s-trans-1,3-butadiene in its lowest singlet and triplet states is studied theoretically, employing a fully quantal approach for the first time. The electronic states 21Ag, 11Bu, 13Bu and 13Ag, which interact vibronically and via the spin-orbit coupling are treated in the calculation, thus covering the lowest spin-forbidden electronic transitions. Up to five nuclear degrees of freedom, including out-of-plane dihedral angles are included in our investigation. The calculation of potential energy surfaces relies on the CASPT2 method, and the evaluation of spin-orbit coupling matrix elements using the full two-electron Breit-Pauli Hamiltonian is performed by utilizing the MRCI wavefunction. The latter dependence on the nuclear coordinates is included for the first time. An electronic population transfer on the sub-picosecond time scale due to intersystem crossing is obtained, a mechanism that can contribute to the singlet-triplet transitions in the electron energy loss spectrum of s-trans-1, 3-butadiene. It is found that the dependence of the spin-orbit coupling on the out-of-plane coordinates plays a dominant role in these singlet-triplet transitions. The amount of population transfer to the 13Ag and 13Bu states is roughly of the same order of magnitude.

  20. Determining the electronic triplet-singlet transition probability in double quantum dots: Analogy with the double slit experiment

    OpenAIRE

    Domínguez, Fernando; Platero, Gloria

    2009-01-01

    We apply an elementary measurement scheme to calculate the electronic triplet-singlet transition mediated by hyperfine interaction in a double quantum dot. We show how the local character of the hyperfine interaction and the nuclear back-action process (flip-flop) are crucial to cancel destructive interferences of the triplet-singlet transition probability. It is precisely this cancellation which differentiates the hyperfine interaction from an anisotropic magnetic field which mixes the tripl...

  1. A cationic dye triplet as a unique "glue" that can connect fully matched termini of DNA duplexes.

    Science.gov (United States)

    Kashida, Hiromu; Hayashi, Takamitsu; Fujii, Taiga; Asanuma, Hiroyuki

    2011-02-25

    In this study, we propose that three consecutive cationic p-methylstilbazoles tethered on D-threoninols (Z residues) at 5' termini act as a unique "glue" connecting DNA duplexes by their interstrand cluster formation. Interstrand clustering of p-methylstilbazoles (ZZZ triplets) induces narrowing and hypsochromic shift of bands at 350 nm, which can be assigned to the absorption of p-methylstilbazole. However, single-stranded DNA conjugates involving a ZZZ triplet at the 5' terminus of 8-mer native nucleotides is found not to induce such large spectral changes, which implies that the intrinsic self-assembling property of ZZZ triplets is weak. Interestingly, when this conjugate is hybridized with a complementary 8-mer native oligonucleotide, a remarkable spectral change is observed, indicating the dimerization of a duplex through the interstrand clustering of ZZZ triplets. Dimerization of the duplex is also evidenced by cold-spray ionization mass spectrometry. This interstrand clustering is observed only when a ZZZ triplet is tethered to a 5' rather than 3' terminus. Furthermore, the stability of the interstrand cluster increases by increasing the number of nucleobases of the DNA portion, and when mismatched base pairs are incorporated or when a base next to the Z residue is deleted, the stability substantially drops. When we apply the ZZZ triplet to the formation of a nanowire using two complementary DNA conjugates, each of which has a ZZZ triplet at the 5' termini as overhang, we demonstrate the successful formation of a nanowire by native PAGE analysis. Since native sticky ends that have three nucleotides do not serve as "glue", ZZZ triplets with their unique glue-like properties are prime candidates for constructing DNA-based nanoarchitectures. PMID:21305625

  2. 3D phase-matching conditions for the generation of entangled triplets by chi(2) interlinked interactions

    OpenAIRE

    Bondani, Maria; Allevi, Alessia; Gevinti, Eleonora; Agliati, Andrea; Andreoni, Alessandra

    2006-01-01

    An analytical calculation of the interaction geometry of two interlinked second-order nonlinear processes fulfilling phase-matching conditions is presented. The method is developed for type-I uniaxial crystals and gives the positions on a screen beyond the crystal of the entangled triplets generated by the interactions. The analytical results are compared to experiments realized in the macroscopic regime. Preliminary tests to identify the triplets are also performed based on intensity correla...

  3. Gapped triplet p -wave superconductivity in strong spin-orbit-coupled semiconductor quantum wells in proximity to s -wave superconductor

    Science.gov (United States)

    Yu, T.; Wu, M. W.

    2016-05-01

    We show that gapped triplet superconductivity, i.e., a triplet superconductor with a triplet order parameter, can be realized in strong spin-orbit-coupled (100) quantum wells in proximity to an s -wave superconductor. It is revealed that in quantum wells with the singlet order parameter induced from the superconducting proximity effect, not only can the triplet pairings arise due to spin-orbit coupling, but the triplet order parameter can also be induced due to the repulsive effective electron-electron interaction, including the electron-electron Coulomb and electron-phonon interactions. This is a natural extension of the work of de Gennes, in which the repulsive-interaction-induced singlet order parameter arises in normal metal in proximity to an s -wave superconductor [Rev. Mod. Phys. 36, 225 (1964), 10.1103/RevModPhys.36.225]. Specifically, we derive the effective Bogoliubov-de Gennes equation, in which the self-energies due to the effective electron-electron interactions contribute to the singlet and triplet order parameters. It is further shown that for the singlet order parameter, it is efficiently suppressed due to this self-energy renormalization, whereas for the triplet order parameter it is the p -wave (px±i py ) one with the d vector parallel to the effective magnetic field due to the spin-orbit coupling. Finally, we perform a numerical calculation in InSb (100) quantum wells. Specifically, we reveal that the Coulomb interaction is much more important than the electron-phonon interaction at low temperature. Moreover, it is shown that with proper electron density, the minimum of the renormalized singlet and the maximum of the induced triplet order parameters are comparable, and hence they can be experimentally distinguished.

  4. Photo-assisted intersystem crossing: The predominant triplet formation mechanism in some isolated polycyclic aromatic molecules excited with pulsed lasers

    International Nuclear Information System (INIS)

    Naphthalene, anthracene, and phenanthrene are shown to have very long-lived triplet lifetimes when the isolated molecules are excited with nanosecond pulsed lasers resonant with the lowest singlet state. For naphthalene, triplet state populations are created only during the laser pulse, excluding the possibility of normal intersystem crossing at the one photon level, and all molecules have triplet lifetimes greater than hundreds of microseconds, similar to the behavior previously reported for phenylacetylene. Although containing 7-12 thousand cm-1 of vibrational energy, the triplet molecules have ionization thresholds appropriate to vibrationless T1 states. The laser power dependences (slopes of log-log power plots) of the excited singlet and triplet populations are about 0.7 for naphthalene and about 0.5 for anthracene. Kinetic modeling of the power dependences successfully reproduces the experimental results and suggests that the triplet formation mechanism involves an enhanced spin orbit coupling caused by sigma character in states at the 2-photon level. Symmetry Adapted Cluster-Configuration Interaction calculations produced excited state absorption spectra to provide guidance for estimating kinetic rates and the sigma character present in higher electronic states. It is concluded that higher excited state populations are significant when larger molecules are excited with pulsed lasers and need to be taken into account whenever discussing the molecular photodynamics

  5. Photo-assisted intersystem crossing: The predominant triplet formation mechanism in some isolated polycyclic aromatic molecules excited with pulsed lasers

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Philip M., E-mail: Philip.johnson@stonybrook.edu [Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400 (United States); Sears, Trevor J. [Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400 (United States); Department of Chemistry, Brookhaven National Laboratory, Upton, New York 11973 (United States)

    2015-07-28

    Naphthalene, anthracene, and phenanthrene are shown to have very long-lived triplet lifetimes when the isolated molecules are excited with nanosecond pulsed lasers resonant with the lowest singlet state. For naphthalene, triplet state populations are created only during the laser pulse, excluding the possibility of normal intersystem crossing at the one photon level, and all molecules have triplet lifetimes greater than hundreds of microseconds, similar to the behavior previously reported for phenylacetylene. Although containing 7–12 thousand cm{sup −1} of vibrational energy, the triplet molecules have ionization thresholds appropriate to vibrationless T{sub 1} states. The laser power dependences (slopes of log-log power plots) of the excited singlet and triplet populations are about 0.7 for naphthalene and about 0.5 for anthracene. Kinetic modeling of the power dependences successfully reproduces the experimental results and suggests that the triplet formation mechanism involves an enhanced spin orbit coupling caused by sigma character in states at the 2-photon level. Symmetry adapted cluster-configuration interaction calculations produced excited state absorption spectra to provide guidance for estimating kinetic rates and the sigma character present in higher electronic states. It is concluded that higher excited state populations are significant when larger molecules are excited with pulsed lasers and need to be taken into account whenever discussing the molecular photodynamics.

  6. Dissecting galaxy triplets in the Sloan Digital Sky Survey Data Release 10: I. Stellar populations and emission line analysis

    CERN Document Server

    Costa-Duarte, M V; Duplancic, F; Sodré, L; Lambas, D G

    2016-01-01

    We identify isolated galaxy triplets in a volume-limited sample from the Sloan Digital Sky Survey Data Release 10. Our final sample has 80 galaxy systems in the redshift range 0.04$\\le$z$\\le$0.1, brighter than $M_r = -20.5 + 5\\log h_{70}$. Spectral synthesis results and WHAN and BPT diagnostic diagrams were employed to classify the galaxies in these systems as star-forming, active nuclei, or passive/retired. Our results suggest that the brightest galaxies drive the triplet evolution, as evidenced by the strong correlations between properties as mass assembly and mean stellar population age with triplet properties. Galaxies with intermediate luminosity or the faintest one within the triplet seem to play a secondary role. Moreover, the relation between age and stellar mass of galaxies is similar for these galaxies but different for the brightest galaxy in the system. Most of the triplet galaxies are passive or retired, according to the WHAN classification. Low mass triplets present different fractions of WHAN c...

  7. Lutein is needed for efficient chlorophyll triplet quenching in the major LHCII antenna complex of higher plants and effective photoprotection in vivo under strong light

    Directory of Open Access Journals (Sweden)

    Havaux Michel

    2006-12-01

    Full Text Available Abstract Background Lutein is the most abundant xanthophyll in the photosynthetic apparatus of higher plants. It binds to site L1 of all Lhc proteins, whose occupancy is indispensable for protein folding and quenching chlorophyll triplets. Thus, the lack of a visible phenotype in mutants lacking lutein has been surprising. Results We have re-assessed the lut2.1 phenotypes through biochemical and spectroscopic methods. Lhc proteins from the lut2.1 mutant compensate the lack of lutein by binding violaxanthin in sites L1 and L2. This substitution reduces the capacity for regulatory mechanisms such as NPQ, reduces antenna size, induces the compensatory synthesis of Antheraxanthin + Zeaxanthin, and prevents the trimerization of LHCII complexes. In vitro reconstitution shows that the lack of lutein per se is sufficient to prevent trimerization. lut2.1 showed a reduced capacity for state I – state II transitions, a selective degradation of Lhcb1 and 2, and a higher level of photodamage in high light and/or low temperature, suggesting that violaxanthin cannot fully restore chlorophyll triplet quenching. In vitro photobleaching experiments and time-resolved spectroscopy of carotenoid triplet formation confirmed this hypothesis. The npq1lut2.1 double mutant, lacking both zeaxanthin and lutein, is highly susceptible to light stress. Conclusion Lutein has the specific property of quenching harmful 3Chl* by binding at site L1 of the major LHCII complex and of other Lhc proteins of plants, thus preventing ROS formation. Substitution of lutein by violaxanthin decreases the efficiency of 3Chl* quenching and causes higher ROS yield. The phenotype of lut2.1 mutant in low light is weak only because rescuing mechanisms of photoprotection, namely zeaxanthin synthesis, compensate for the ROS production. We conclude that zeaxanthin is effective in photoprotection of plants lacking lutein due to the multiple effects of zeaxanthin in photoprotection, including ROS

  8. The Complementarity of the Loop to the Stem in DNA Pseudoknots Gives Rise to Local TAT Base-Triplets.

    Science.gov (United States)

    Reiling-Steffensmeier, Calliste; Marky, Luis A

    2016-01-01

    Pseudoknots belong to an RNA structural motif that has significant roles in the biological function of RNA. An example is ribosomal frameshifting; in this mechanism, the formation of a local triplex changes the reading frame that allows for differences in the translation of mRNAs. In this work, we have used a combination of temperature-dependent UV spectroscopy and differential scanning calorimetry (DSC) to determine the unfolding thermodynamics of a set of DNA pseudoknots with the following sequence: d(TCTCTTnAAAAAAAAGAGAT5TTTTTTT), where "Tn" is a thymine loop with n=5 (PsK-5), 7 (PsK-7), 9 (PsK-9), or 11 (PsK-11). All four oligonucleotides form intramolecular pseudoknots, and the increase in the length of this loop yielded more stable pseudoknots due to higher transition temperatures and higher unfolding enthalpies. This indicates formation of one and three TAT/TAT stacks in PsK-9 and PsK-11, respectively. We have flipped one AT for a TA base pair in the core stem of these pseudoknots, preventing in this way the formation of these base-triplet stacks. The DSC curves of these pseudoknots yielded lower unfolding enthalpies, confirming the formation of a local triplex in PsK-9 and PsK-11. Furthermore, we have investigated the reaction of PsK-5 and PsK-9 with their partially complementary strands: directly by isothermal titration calorimetry and indirectly by creating a Hess cycle with the DSC data. Relative to the PsK-5 reaction, PsK-9 reacts with its complementary strand with less favorable free energy and enthalpy contributions; this indicates PsK-9 is more stable and more compact due to the formation of a local triplex. PMID:26794363

  9. An optical-near-IR study of a triplet of super star clusters in the starburst core of M82

    Energy Technology Data Exchange (ETDEWEB)

    Westmoquette, M. S. [European Southern Observatory, Karl-Schwarzschild-Str. 2, D-85748 Garching bei München (Germany); Bastian, N. [Excellence Cluster Universe, Boltzmannstrasse 2, D-85748 Garching bei München (Germany); Smith, L. J. [Space Telescope Science Institute and European Space Agency, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Seth, A. C. [University of Utah, Salt Lake City, UT 84112 (United States); Gallagher III, J. S.; Ryon, J. E. [Department of Astronomy, University of Wisconsin-Madison, 5534 Sterling, 475 North Charter Street, Madison, WI 53706 (United States); O' Connell, R. W. [Department of Astronomy, University of Virginia, P.O. Box 3818, Charlottesville, VA 22903 (United States); Silich, S.; Mayya, Y. D.; González, D. Rosa [Instituto Nacional de Astrofísica, Optica y Electronica, Luis Enrique Erro 1, Tonantzintla, C.P. 72840, Puebla (Mexico); Muñoz-Tuñón, C., E-mail: westmoquette@gmail.com [Instituto de Astrofísica de Canarias, C/vía Láctea s/n, E-38200 La Laguna, Tenerife (Spain)

    2014-07-10

    We present HST/STIS optical and Gemini/NIFS near-IR IFU spectroscopy and archival Hubble Space Telescope (HST) imaging of the triplet of super star clusters (A1, A2, and A3) in the core of the M82 starburst. Using model fits to the Space Telescope Imaging Spectrograph (STIS) spectra and the weakness of red supergiant CO absorption features (appearing at ∼6 Myr) in the NIFS H-band spectra, the ages of A2 and A3 are 4.5 ± 1.0 Myr. A1 has strong CO bands, consistent with our previously determined age of 6.4 ± 0.5 Myr. The photometric masses of the three clusters are 4-7 × 10{sup 5} M{sub ☉}, and their sizes are R{sub eff} = 159, 104, 59 mas (∼2.8, 1.8, 1.0 pc) for A1, A2, and A3. The STIS spectra yielded radial velocities of 320 ± 2, 330 ± 6, and 336 ± 5 km s{sup –1} for A1, A2, and A3, placing them at the eastern end of the x{sub 2} orbits of M82's bar. Clusters A2 and A3 are in high-density (800-1000 cm{sup –3}) environments, and like A1, are surrounded by compact H II regions. We suggest the winds from A2 and A3 have stalled, as in A1, due to the high ISM ambient pressure. We propose that the three clusters were formed in situ on the outer x{sub 2} orbits in regions of dense molecular gas subsequently ionized by the rapidly evolving starburst. The similar radial velocities of the three clusters and their small projected separation of ∼25 pc suggest that they may merge in the near future unless this is prevented by velocity shearing.

  10. Prediction of plant promoters based on hexamers and random triplet pair analysis

    Directory of Open Access Journals (Sweden)

    Noman Nasimul

    2011-06-01

    Full Text Available Abstract Background With an increasing number of plant genome sequences, it has become important to develop a robust computational method for detecting plant promoters. Although a wide variety of programs are currently available, prediction accuracy of these still requires further improvement. The limitations of these methods can be addressed by selecting appropriate features for distinguishing promoters and non-promoters. Methods In this study, we proposed two feature selection approaches based on hexamer sequences: the Frequency Distribution Analyzed Feature Selection Algorithm (FDAFSA and the Random Triplet Pair Feature Selecting Genetic Algorithm (RTPFSGA. In FDAFSA, adjacent triplet-pairs (hexamer sequences were selected based on the difference in the frequency of hexamers between promoters and non-promoters. In RTPFSGA, random triplet-pairs (RTPs were selected by exploiting a genetic algorithm that distinguishes frequencies of non-adjacent triplet pairs between promoters and non-promoters. Then, a support vector machine (SVM, a nonlinear machine-learning algorithm, was used to classify promoters and non-promoters by combining these two feature selection approaches. We referred to this novel algorithm as PromoBot. Results Promoter sequences were collected from the PlantProm database. Non-promoter sequences were collected from plant mRNA, rRNA, and tRNA of PlantGDB and plant miRNA of miRBase. Then, in order to validate the proposed algorithm, we applied a 5-fold cross validation test. Training data sets were used to select features based on FDAFSA and RTPFSGA, and these features were used to train the SVM. We achieved 89% sensitivity and 86% specificity. Conclusions We compared our PromoBot algorithm to five other algorithms. It was found that the sensitivity and specificity of PromoBot performed well (or even better with the algorithms tested. These results show that the two proposed feature selection methods based on hexamer frequencies

  11. Chemical spectroscopy

    International Nuclear Information System (INIS)

    The purpose of chemical spectroscopy with neutrons is to utilize the dependence of neutron scattering cross-sections on isotope and on momentum transfer (which probes the spatial extent of the excitation) to understand fundamental and applied aspects of the dynamics of molecules and fluids. Chemical spectroscopy is divided into three energy ranges: vibrational spectroscopy, 25-500 MeV, for which much of the work is done on Be-filter analyzer instruments; low energy spectroscopy, less than 25 MeV; and high resolution spectroscopy, less than 1 MeV, which typically is performed on backscattering spectrometers. Representative examples of measurements of the Q-depenence of vibrational spectra, higher energy resolution as well as extension of the Q-range to lower values at high energy transfers, and provisions of higher sensitivities in vibrational spectroscopy are discussed. High resolution, high sensitivity, and polarization analysis studies in low energy spectroscopy are discussed. Applications of very high resolution spectroscopy are also discussed

  12. MR spectroscopy

    International Nuclear Information System (INIS)

    MR has had a major impact on medicine over the past few years due to rapid advances in the application of the MR phenomena. The result has been a valuable new imaging modality. In the near future, MR spectroscopy will likely have an even greater impact on the practice of medicine. This is due to the ability of MR spectroscopy to provide a nondestructive and noninvasive means of monitoring body chemistry in humans. For example, P-31 MR spectroscopy can be used to monitor pH and metabolites involved in both bioenergetics and lipid metabolism. The results from pioneering studies in animals and humans provide evidence that P-31 MR spectroscopy will both contribute to the understanding of disease processes and provide a monitor of therapeutic response. Thus, MR spectroscopy promises to provide a new window of information to clinicians for use in the management of human diseases. In this refresher course, an introduction to MR spectroscopy methodology and the information contained in the MR spectrum is presented. In addition, an overview of areas in which MR spectroscopy may have a major impact on medicine is presented

  13. Laser spectroscopy

    CERN Document Server

    Demtröder, Wolfgang

    Keeping abreast of the latest techniques and applications, this new edition of the standard reference and graduate text on laser spectroscopy has been completely revised and expanded. While the general concept is unchanged, the new edition features a broad array of new material, e.g., ultrafast lasers (atto- and femto-second lasers) and parametric oscillators, coherent matter waves, Doppler-free Fourier spectroscopy with optical frequency combs, interference spectroscopy, quantum optics, the interferometric detection of gravitational waves and still more applications in chemical analysis, medical diagnostics, and engineering.

  14. Laser-Induced Magnetic Dipole Spectroscopy.

    Science.gov (United States)

    Hintze, Christian; Bücker, Dennis; Domingo Köhler, Silvia; Jeschke, Gunnar; Drescher, Malte

    2016-06-16

    Pulse electron paramagnetic resonance measurements of nanometer scale distance distributions have proven highly effective in structural studies. They exploit the magnetic dipole-dipole coupling between spin labels site-specifically attached to macromolecules. The most commonly applied technique is double electron-electron resonance (DEER, also called pulsed electron double resonance (PELDOR)). Here we present the new technique of laser-induced magnetic dipole (LaserIMD) spectroscopy based on optical switching of the dipole-dipole coupling. In a proof of concept experiment on a model peptide, we find, already at a low quantum yield of triplet excitation, the same sensitivity for measuring the distance between a porphyrin and a nitroxide label as in a DEER measurement between two nitroxide labels. On the heme protein cytochrome C, we demonstrate that LaserIMD allows for distance measurements between a heme prosthetic group and a nitroxide label, although the heme triplet state is not directly observable by an electron spin echo. PMID:27163749

  15. Josephson effect in multiterminal superconductor-ferromagnet junctions coupled via triplet components

    Science.gov (United States)

    Moor, Andreas; Volkov, Anatoly F.; Efetov, Konstantin B.

    2016-03-01

    On the basis of the Usadel equation we study a multiterminal Josephson junction. This junction is composed by "magnetic" superconductors Sm, which have singlet pairing and are separated from the normal n wire by spin filters so that the Josephson coupling is caused only by fully polarized triplet components. We show that there is no interaction between triplet Cooper pairs with antiparallel total spin orientations. The presence of an additional singlet superconductor S attached to the n wire leads to a finite Josephson current IQ with an unusual current-phase relation. The density of states in the n wire for different orientations of spins of Cooper pairs is calculated. We derive a general formula for the current IQ in a multiterminal Josephson contact and apply this formula for analysis of two four-terminal Josephson junctions of different structures. It is shown in particular that both the "nematic" and the "magnetic" cases can be realized in these junctions. In a two-terminal structure with parallel filter orientations and in a three-terminal structure with antiparallel filter orientations of the "magnetic" superconductors with attached additional singlet superconductor, we find a nonmonotonic temperature dependence of the critical current. Also, in these structures, the critical current shows a Riedel peak like dependence on the exchange field in the "magnetic" superconductors. Although there is no current through the S/n interface due to orthogonality of the singlet and triplet components, the phase of the order parameter in the superconuctor S is shown to affect the Josephson current in a multiterminal structure.

  16. Excited complexes in oxidation-reduction photoreactions of pigments. I. Spectral detection of triplet state exciplex in the chlorophyll oxidation reaction.

    Science.gov (United States)

    Andreeva, N E; Chibisov, A K

    1976-01-01

    Photooxidation of chlorophyll "a" with p-benzoquinone in toluene and dioxane is studied by the method of flash photolysis. It is shown that in nonpolar medium the triplet exiplex is the product of this reaction. The experiments on competitive quenching of chlorophyll triplet state with naphthacene prove the diffusion mechanism of exiplex formation. The spectrum of triplet-triplet absorption of the exiplex is presented and the rate constant of intercombination degradation equalling 1.103 sec(-1) is measured. Possible structure of the exiplex is discussed. PMID:1252529

  17. Relationship between dopant energy levels and device performances of triplet mixed host devices

    International Nuclear Information System (INIS)

    Device performances of phosphorescent organic light-emitting diodes (PHOLEDs) with triplet mixed host structure were correlated with dopant energy levels and mixed host composition. A mixed host of 4,4',4''-tris-(N-carbazolyl)triphenylamine (TCTA) and spirobifluorene type host (PH1) was used and three different dopants with different bandgap were doped in the mixed host. Optimum quantum efficiency was obtained in TCTA:PH1 (50:50) mixed host device in the case of green dopants, while the optimum host composition for red and orange dopants was TCTA:PH1 (25:75)

  18. Detection of Ca II absorption triplet in a circumnuclear H II region of NGC 3310

    International Nuclear Information System (INIS)

    We have obtained long slit spectrophotometry across NGC 3310, a luminous galaxy with circumnuclear bursts of star formation, covering the spectral range from λ3650 to 9700 A. In one giant star-forming region, the near-IR Ca II absorption lines (a signature of young supergiants) was detected with a strength similar to that of the nuclear region. This is, to our knowledge, the first detection of the IR Ca II triplet in an extragalactic giant H II region and confirms theoretical predictions that, after some 4 Myr, red supergiants should appear in bursts of star formation. (author)

  19. Rogue wave triplets in an ion-beam dusty plasma with superthermal electrons and negative ions

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Shimin, E-mail: gsm861@126.com [School of Mathematics and Statistics, Xi' an Jiaotong University, Xi' an, 710049 (China); Mei, Liquan, E-mail: lqmei@mail.xjtu.edu.cn [School of Mathematics and Statistics, Xi' an Jiaotong University, Xi' an, 710049 (China); Department of Chemical and Petroleum Engineering, Schulich School of Engineering, University of Calgary, Calgary, Alberta, T2N 1N4 (Canada); Shi, Weijuan [College of Mathematics and Information Science, Shaanxi Normal University, Xi' an, 710062 (China)

    2013-11-01

    A new dust ion-acoustic wave structure called ‘Rogue wave triplets’ is investigated in an unmagnetized plasma consisting of stationary negatively charged dust grains, charged positive and negative ions, and electrons obeying kappa distribution, which is penetrated by an ion beam. The reductive perturbation theory is used to derive the nonlinear Schrödinger equation governing the dynamics as well as the modulation of wave packets. The rogue wave triplets which are composed of three separate Peregrine breathers can be generated in the modulation instability region. It has been suggested that a laboratory experiment be performed to test the theory presented here.

  20. Long range triplet Josephson current and 0-π transitions in tunable domain walls

    Science.gov (United States)

    Baker, Thomas E.; Richie-Halford, Adam; Bill, Andreas

    2014-09-01

    The order parameter of superconducting pairs penetrating an inhomogeneous magnetic material can acquire a long range triplet component (LRTC) with non-zero spin projection. This state has been predicted and generated in proximity systems and Josephson junctions. We show, using a realistic domain wall of an exchange spring bilayer, how the LRTC emerges and can be tuned with the twisting of the magnetization. We also introduce a new kind of Josephson current reversal, the singlet-LRTC 0-π transition, that can be observed in one and the same system either by tuning the domain wall or by varying temperature.

  1. Dicephalic parapagus tribrachius conjoined twins in a triplet pregnancy: a case report.

    Science.gov (United States)

    Kaveh, Mahbod; Kamrani, Kamyar; Naseri, Mohsen; Danaeian, Morteza; Asadi, Farhad; Davari-Tanha, Fatemeh

    2014-06-01

    Dicephalic parapagus tribrachius conjoined twin is a very rare condition. We present a case of 5-days-old male dicephalic parapagus conjoined twins. The conjoined twins were diagnosed in 4(th) month of pregnancy by ultrasonography. The pregnancy terminates at 36 weeks by cesarean section and triplets were born. The babies were male conjoined twins and another healthy male baby. Many congenital defects of interest can now be detected before birth. Sever form of this malformation precludes postpartum life. It is supposed that with advances in screening methods for prenatal diagnosis these cases are terminated in first or second trimester of pregnancy. PMID:24971140

  2. Dicephalic parapagus tribrachius conjoined twins in a triplet pregnancy: a case report.

    Directory of Open Access Journals (Sweden)

    Mahbod Kaveh

    2014-06-01

    Full Text Available Dicephalic parapagus tribrachius conjoined twin is a very rare condition. We present a case of 5-days-old male dicephalic parapagus conjoined twins. The conjoined twins were diagnosed in 4(th month of pregnancy by ultrasonography. The pregnancy terminates at 36 weeks by cesarean section and triplets were born. The babies were male conjoined twins and another healthy male baby. Many congenital defects of interest can now be detected before birth. Sever form of this malformation precludes postpartum life. It is supposed that with advances in screening methods for prenatal diagnosis these cases are terminated in first or second trimester of pregnancy.

  3. Revisiting the nonequilibrium phase transition of the triplet-creation model

    Science.gov (United States)

    Cardozo, G. O.; Fontanari, J. F.

    2006-06-01

    The nonequilibrium phase transition in the triplet-creation model is investigated using critical spreading and the conservative diffusive contact process. The results support the claim that at high enough diffusion the phase transition becomes discontinuous. As the diffusion probability increases the critical exponents change continuously from the ordinary directed percolation (DP) class to the compact directed percolation (CDP). The fractal dimension of the critical cluster, however, switches abruptly between those two universality classes. Strong crossover effects in both methods make it difficult, if not impossible, to establish the exact location of the tricritical point.

  4. Quenching behaviour of quadrupole model magnets for the LHC inner triplets at Fermilab

    CERN Document Server

    Andreev, N; Bauer, P; Bossert, R; Brandt, J; Chichili, D R; Carson, J; Di Marco, J; Fehér, S; Glass, H; Kerby, J S; Lamm, M J; Makarov, A A; Nobrega, A; Novitski, I; Ogitsu, T; Orris, D; Ozelis, J P; Rabehl, Roger Jon; Robotham, W; Sabbi, G L; Schlabach, P; Sylvester, C D; Strait, J B; Tartaglia, M; Tompkins, J C; Yadav, S; Zlobin, A V; Caspi, S; McInturff, A D; Scanlan, R M; Ghosh, A

    2000-01-01

    The US-LHC Accelerator Project is responsible for the design and production of inner triplet high gradient quadrupoles for installation in the LHC Interaction Region. The quadrupoles are required to deliver a nominal field gradient of 215 T/m in a 70 mm bore, and operate in superfluid helium. As part of the magnet development program, a series of 2 m model magnets have been built and tested at Fermilab, with each magnet being tested over several thermal cycles. This paper summarizes the quench performance and analysis of the model magnets tested, including quench training, and the ramp rate and temperature of the magnet quench current. (7 refs).

  5. Desempenho comunicativo em trigêmeos prematuros Acquisition and development language in premature triplets

    Directory of Open Access Journals (Sweden)

    Amanda Tragueta Ferreira

    2008-03-01

    Full Text Available OBJETIVO: descrever habilidades do desenvolvimento de trigêmeos aos 18 meses e aos 29 meses de vida, enfocando a comunicação. MÉTODOS: irmãos trigêmeos dizigóticos do sexo masculino. Os procedimentos de avaliação englobaram: Anamnese, Observação do Comportamento Comunicativo e Escala de Desenvolvimento de Gesell e Amatruda (2000. As avaliações foram realizadas aos 18 e aos 29 meses. As crianças apresentaram atraso do desenvolvimento neuropsicomotor e eram expostas a multilingüismo. RESULTADOS: foi verificada alteração nos comportamentos comunicativos nas três crianças, tanto na primeira quanto na segunda avaliação, embora tenha sido observada melhora do desempenho, após as orientações recebidas pela família. Na segunda avaliação foi observada criptofasia. Dos comportamentos motor grosseiro, delicado, adaptativo, pessoal-social e de linguagem, o último foi o mais afetado para as três crianças, apesar de todos estarem alterados considerando a idade cronológica dos trigêmeos. CONCLUSÃO: as habilidades do desenvolvimento dos trigêmeos avaliados neste estudo estavam alteradas, acometendo todas as áreas. Ressalta-se maior comprometimento da linguagem tanto aos 18 como aos 29 meses.PURPOSE: to describe abilities of triplets' development by 18 months and the 29 months of life, focusing on communication. METHODS: dizygotic male sibling triplets. The evaluation procedures included history of disease, observing the communicative behavior and Escala de Desenvolvimento de Gesell e Amatruda (2000. The evaluations were accomplished by the 18 months and the 29 months. The children showed delay in the neuropshycomotor development and were exposed to multilingualism. RESULTS: alteration was verified in the communicative behaviors in the three children, both in the first as well as in the second evaluation, although an amelioration was shown in the performance, after the orientations received by the family. Cryptophasia was

  6. Triplet state and semiquinone free radical of 5-methoxyquinizarin : a laser flash photolysis and pulse radiolysis study

    International Nuclear Information System (INIS)

    The triplet(T) state properties like T-T absorption spectra, quantum yield, energy level and decay kinetics of 5-methoxyquinizarin (5-methoxy-1, 4-dihydroxy-9, 10-anthraquinone; MQZ) have been investigated in cyclohexane, acetonitrile and isopropyl alcohol using nanosecond laser flash photolysis technique. In isopropylalcohol, a neutral semiquinone radical is also formed which has been characterised by comparing the long lived transient spectra with the MQZ-semiquinone spectra obtained by pulse radiolysis of MQZ in the same solvent. A relatively small amount of a long lived transient formed in cyclohexane and acetonitrile, along with the triplet state of MQZ, could not be characterised unambiguously, but has been attributed to the semiquinone radical of MQZ, produced by the reaction of the excited states of the quinone with the solvent. The quantum yield of the semiquinone radical in isopropyl alcohol is considerably higher than the triplet quantum yield, showing that both the excited singlet and the triplet states of the quinone probably react with the solvent molecules to form the semiquinone radical. The photophysical properties of the triplet and the semiquinone radical of MQZ have been compared with those of simple 1,4-disubstituted anthraquinones. (author). 23 refs., 5 figs., 1 tab

  7. Singlet and triplet excited states and intersystem crossing in free-base porphyrin: TDDFT and DFT/MRCI study.

    Science.gov (United States)

    Perun, Serhiy; Tatchen, Jörg; Marian, Christel M

    2008-02-01

    Extensive time-dependent DFT (TDDFT) and DFT/multireference configuration interaction (MRCI) calculations are performed on the singlet and triplet excited states of free-base porphyrin, with emphasis on intersystem crossing processes. The equilibrium geometries, as well as the vertical and adiabatic excitation energies of the lowest singlet and triplet excited states are determined. Single and double proton-transfer reactions in the first excited singlet state are explored. Harmonic vibrational frequencies are calculated at the equilibrium geometries of the ground state and of the lowest singlet and triplet excited states. Furthermore, spin-orbit coupling matrix elements of the lowest singlet and triplet states and their numerical derivatives with respect to nuclear displacements are computed. It is shown that opening of an unprotonated pyrrole ring as well as excited-state single and double proton transfer inside the porphyrin cavity lead to crossings of the potential energy curves of the lowest singlet and triplet excited states. It is also found that displacements along out-of-plane normal modes of the first excited singlet state cause a significant increase of the , , and spin-orbit coupling matrix elements. These phenomena lead to efficient radiationless deactivation of the lowest excited states of free-base porphyrin via intercombination conversion. In particular, the S1-->T1 population transfer is found to proceed at a rate of approximately 10(7) s(-1) in the isolated molecule. PMID:18189251

  8. The Kinetics of Joined Action of Triplet-Triplet Annihilation and First-Order Decay of Molecules in T1 State in the Case of Nondominant First-Order Process: The Kinetic Model in the Case of Spatially Periodic Excitation

    Directory of Open Access Journals (Sweden)

    Paweł Borowicz

    2013-01-01

    Full Text Available In this paper the model developed for estimation of the diffusion coefficient of the molecules in the triplet state is presented. The model is based on the intuitive modification of the Smoluchowski equation for the time-dependent rate parameter. Since the sample is irradiated with the spatially periodic pattern nonexponential effects can be expected in the areas of the constructive interference of the exciting laser beams. This nonexponential effects introduce changes in the observed kinetics of the diffusion-controlled triplet-triplet annihilation. Due to irradiation with so-called long excitation pulse these non-exponential effects are very weak, so they can be described with introducing very simple correction to the kinetic model described in the first paper of this series. The values of diffusion coefficient of anthracene are used to calculate the annihilation radius from the data for spatially homogeneous excitation.

  9. Spectroscopy of Ferric Heme and Protoporphyrin IX Ions In Vacuo

    DEFF Research Database (Denmark)

    Wyer, Jean; Nielsen, Steen Brøndsted

    2013-01-01

    This chapter deals with gas-phase spectroscopy of protoporphyrin IX and heme ions, two important biochromophores in nature. These ions strongly absorb blue and green light, which accounts for e.g. the red colour of blood. We present absorption spectra of four-coordinate ferric heme cations at room...... conversion to the ground state. This is somewhat supported by spectroscopic characterisation of the long-lived states based on pump-probe experiments. Hence from one time spectrum (a one-laser experiment), triplet quantum yields can easily be estimated....

  10. Moessbauer spectroscopy

    International Nuclear Information System (INIS)

    This book is addressed to persons interested in learning about what has been done and what can be done with Moessbauer spectroscopy. In an introductory chapter the basic principle is explained and the general parameters governing Moessbauer spectroscopy are tabulated. For the following chapters various disciplines are chosen and the wide applicability of this measuring technique is demonstrated. The second chapter discusses a few representative examples of chemical interesting information being reflected by isomer shifts and quadrupole splittings, particularly with respect to bonding and structural properties. The third chapter deals with some applications of Moessbauer spectroscopy for characterizing magnetic compounds and its use for magnetic structure investigations, particularly by making use of polarized radiation. The fourth chapter describes the use of the Moessbauer spectroscopy for studying iron in biological molecules. As an example of recent applications to mineralogy and geology the results of the studies of lunar samples are reviewed in the fifth chapter. Finally, in the last chapter, work is described on the use of Moessbauer spectroscopy in physical metallurgy, particularly quantitative analyses which have enabled metallurgists to solve many old problems. (orig./FW)

  11. Anion photoelectron spectroscopy of radicals and clusters

    Energy Technology Data Exchange (ETDEWEB)

    Travis, Taylor R.

    1999-12-16

    Anion photoelectron spectroscopy is used to study free radicals and clusters. The low-lying {sup 2}{Sigma} and {sup 2}{Pi} states of C{sub 2n}H (n = 1--4) have been studied. The anion photoelectron spectra yielded electron affinities, term values, and vibrational frequencies for these combustion and astrophysically relevant species. Photoelectron angular distributions allowed the author to correctly assign the electronic symmetry of the ground and first excited states and to assess the degree of vibronic coupling in C{sub 2}H and C{sub 4}H. Other radicals studied include NCN and I{sub 3}. The author was able to observe the low-lying singlet and triplet states of NCN for the first time. Measurement of the electron affinity of I{sub 3} revealed that it has a bound ground state and attachment of an argon atom to this moiety enabled him to resolve the symmetric stretching progression.

  12. Third-order spontaneous parametric down-conversion in thin optical fibers as a photon-triplet source

    Energy Technology Data Exchange (ETDEWEB)

    Corona, Maria [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, apdo. postal 70-543, DF 04510 Mexico City (Mexico); Departamento de Optica, Centro de Investigacion Cientifica y de Educacion Superior de Ensenada, Apartado Postal 2732, BC 22860 Ensenada (Mexico); Garay-Palmett, Karina; U' Ren, Alfred B. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, apdo. postal 70-543, DF 04510 Mexico City (Mexico)

    2011-09-15

    We study the third-order spontaneous parametric down-conversion (TOSPDC) process, as a means to generate entangled photon triplets. Specifically, we consider thin optical fibers as the nonlinear medium to be used as the basis for TOSPDC in configurations where phase matching is attained through the use of more than one fiber transverse modes. Our analysis in this paper, which follows from our earlier paper [Opt. Lett. 36, 190-192 (2011)], aims to supply experimentalists with the details required in order to design a TOSPDC photon-triplet source. Specifically, our analysis focuses on the photon triplet state, on the rate of emission, and on the TOSPDC phase-matching characteristics for the cases of frequency-degenerate and frequency nondegenerate TOSPDC.

  13. Commissioning and First Operation of the Low-Beta Triplets and Their Electrical Feed Boxes at the Large Hadron Collider

    CERN Document Server

    Darve, C; Casas-Cubillos, J; Claudet, S; Feher, S; Ferlin, G; Kerby, J; Metral, L; Perin, A; Peterson, T; Prin, H; Rabehl, R; Vauthier, N; Wagner, U; van Weelderen, R

    2010-01-01

    The insertion regions located around the four interaction points of the Large Hadron Collider (LHC) are mainly composed of the low-b triplets, the separation dipoles and their respective electrical feed-boxes (DFBX). The low-b triplets are Nb-Ti superconductor quadrupole magnets, which operate at 215 T/m in superfluid helium at a temperature of 1.9 K. The commissioning and the first operation of these components have been performed. The thermo-mechanical behavior of the low-b triplets and DFBX were studied. Cooling and control systems were tuned to optimize the cryogenic operation of the insertion regions. Hardware commissioning also permitted to test the system response. This paper summarizes the performance results and the lessons learned.

  14. Implications of a Electroweak Triplet Scalar Leptoquark on the Ultra-High Energy Neutrino Events at IceCube

    CERN Document Server

    Mileo, Nicolas; Szynkman, Alejandro

    2016-01-01

    We study the production of scalar leptoquarks at IceCube, in particular, a particle transforming as a triplet under the weak interaction. The existence of electroweak-triplet scalars is highly motivated by models of grand unification and also within radiative seesaw models for neutrino mass generation. In our framework, we extend the Standard Model by a single colored electroweak-triplet scalar leptoquark and analyze its implications on the excess of ultra-high energy neutrino events observed by the IceCube collaboration. We consider only couplings between the leptoquark to first generation leptons and quarks and carry out a statistical analysis to determine the parameters that best describe the IceCube data as well as set $95\\%$ CL upper bounds. We analyze whether this study is still consistent with most up-to-date LHC data and various low energy observables.

  15. Scaling model for prediction of radionuclide activity in cooling water using a regression triplet technique

    International Nuclear Information System (INIS)

    The decommissioning of the nuclear power plant (NPP) A1 Jaslovske Bohunice (Slovakia) is a complicated set of problems that is highly demanding both technically and financially. The basic goal of the decommissioning process is the total elimination of radioactive materials from the nuclear power plant area, and radwaste treatment to a form suitable for its safe disposal. The initial conditions of decommissioning also include elimination of the operational events, preparation and transport of the fuel from the plant territory, radiochemical and physical-chemical characterization of the radioactive wastes. One of the problems was and still is the processing of the liquid radioactive wastes. Such media is also the cooling water of the long-term storage of spent fuel. A suitable scaling model for predicting the activity of hard-to-detect radionuclides 239,240Pu, 90Sr and summary beta in cooling water using a regression triplet technique has been built using the regression triplet analysis and regression diagnostics. (author)

  16. Gas-phase hydrolysis of triplet SO2: A possible direct route to atmospheric acid formation.

    Science.gov (United States)

    Donaldson, D James; Kroll, Jay A; Vaida, Veronica

    2016-01-01

    Sulfur chemistry is of great interest to the atmospheric chemistry of several planets. In the presence of water, oxidized sulfur can lead to new particle formation, influencing climate in significant ways. Observations of sulfur compounds in planetary atmospheres when compared with model results suggest that there are missing chemical mechanisms. Here we propose a novel mechanism for the formation of sulfurous acid, which may act as a seed for new particle formation. In this proposed mechanism, the lowest triplet state of SO2 ((3)B1), which may be accessed by near-UV solar excitation of SO2 to its excited (1)B1 state followed by rapid intersystem crossing, reacts directly with water to form H2SO3 in the gas phase. For ground state SO2, this reaction is endothermic and has a very high activation barrier; our quantum chemical calculations point to a facile reaction being possible in the triplet state of SO2. This hygroscopic H2SO3 molecule may act as a condensation nucleus for water, giving rise to facile new particle formation (NPF). PMID:27417675

  17. Stability of a spin-triplet nematic state near to a quantum critical point

    Science.gov (United States)

    Hannappel, G.; Pedder, C. J.; Krüger, F.; Green, A. G.

    2016-06-01

    We analyze a model of itinerant electrons interacting through a quadrupole density-density repulsion in three dimensions. At the mean-field level, the interaction drives a continuous Pomeranchuk instability towards d -wave, spin-triplet nematic order, which simultaneously breaks the SU(2) spin-rotation and spatial-rotation symmetries. This order is characterized by spin-antisymmetric, elliptical deformations of the Fermi surfaces of up and down spins. We show that the effects of quantum fluctuations are similar to those in metallic ferromagnets, rendering the nematic transition first order at low temperatures. Using the fermionic quantum order-by-disorder approach to self-consistently calculate fluctuations around possible modulated states, we show that the first-order transition is preempted by the formation of a helical spin-triplet d -density wave. Such a state is closely related to d -wave bond density wave order in square-lattice systems. Moreover, we show that it may coexist with a modulated, p -wave superconducting state.

  18. Efficient Hybrid White Organic Light-Emitting Diodes for Application of Triplet Harvesting with Simple Structure

    CERN Document Server

    Hwang, Kyo Min; Lee, Sungkyu; Yoo, Han Kyu; Baek, Hyun Jung; Kim, Jwajin; Yoon, Seung Soo; Kim, Young Kwan

    2016-01-01

    In this study, we fabricated hybrid white organic light-emitting diodes (WOLEDs) based on triplet harvesting with simple structure. All the hole transporting material and host in emitting layer (EML) of devices were utilized with same material by using N,N'-di-1-naphthalenyl-N,N'-diphenyl-[1,1':4',1":4",1"'-quaterphenyl]-4,4"'-diamine (4P-NPD) which were known to be blue fluorescent material. Simple hybrid WOLEDs were fabricated three color with blue fluorescent and green, red phosphorescent materials. We was investigated the effect of triplet harvesting (TH) by exciton generation zone on simple hybrid WOLEDs. Characteristic of simple hybrid WOLEDs were dominant hole mobility, therefore exciton generation zone was expected in EML. Additionally, we was optimization thickness of hole transporting layer and electron transporting layer was fabricated a simple hybrid WOLEDs. Simple hybrid WOLED exhibits maximum luminous efficiency of 29.3 cd/A and maximum external quantum efficiency of 11.2%. Commission Internatio...

  19. Accessing the Triplet State in Heavy-Atom-Free Perylene Diimides.

    Science.gov (United States)

    Yu, Zhenyi; Wu, Yishi; Peng, Qian; Sun, Chunlin; Chen, Jianwei; Yao, Jiannian; Fu, Hongbing

    2016-03-24

    Previous studies of perylenediimides (PDIs) mostly utilized the lowest singlet excited state S1 . Generation of a triplet excited state (T1 ) in PDIs is important for applications ranging from photodynamic therapy to photovoltaics; however, it remains a formidable task. Herein, we developed a heavy-atom-free strategy to prompt the T1 ←S1 intersystem crossing (ISC) by introducing electron-donating aryl (Ar) groups at the head positions of an electron-deficient perylenediimide (PDI) core. We found that the ISC efficiency increases from 8 to 54 % and then to 86 % by increasing the electron-donating ability of head-substituted aryl groups from phenyl (p-PDI) to methoxyphenyl (MeO-PDI) and then to methylthioxyphenyl (MeS-PDI). By enhancing the intramolecular charge-transfer (ICT) interaction from p-PDI to MeO-PDI, and then to MeS-PDI, singlet oxygen generation via energy-transfer reactions from T1 of PDIs to (3) O2 was demonstrated with the highest yield of up to 80 %. These results provide guidelines for developing new triplet-generating PDIs and related rylene diimides for optoelectronic applications. PMID:26853213

  20. Nematic versus ferromagnetic spin filtering of triplet Cooper pairs in superconducting spintronics

    Science.gov (United States)

    Moor, Andreas; Volkov, Anatoly F.; Efetov, Konstantin B.

    2015-11-01

    We consider two types of magnetic Josephson junctions (JJ). They are formed by two singlet superconductors S and magnetic layers between them so that the JJ is a heterostructure of the Sm/n /Sm type, where Sm includes two magnetic layers with noncollinear magnetization vectors. One layer is represented by a weak ferromagnet and another one—the spin filter—is either conducting strong ferromagnet (nematic or N -type JJ) or magnetic tunnel barrier with spin-dependent transparency (magnetic or M -type JJ). Due to spin filtering only a fully polarized triplet component penetrates the normal n wire and provides the Josephson coupling between the superconductors S. Although both filters let to pass triplet Cooper pairs with total spin S parallel to the filter axes, the behavior of nematic and magnetic JJs is completely different. Whereas in the nematic case the charge and spin currents, IQ and Isp, do not depend on mutual orientation of the filter axes, both currents vanish in magnetic JJ in the case of antiparallel filter axes, and change sign with reversal of the filter direction. The obtained expressions for IQ and Isp clearly show a duality between the superconducting phase φ and the angle α between the exchange fields in the weak magnetic layers.

  1. Dark matter versus h→γγ and h→γZ with supersymmetric triplets

    International Nuclear Information System (INIS)

    The Triplet extension of the MSSM (TMSSM) alleviates the little hierarchy problem and provides a significant enhancement of the loop-induced diphoton rate of the lightest CP-even Higgs h. In this paper we pursue the analysis of the TMSSM Higgs phenomenology by computing for the first time the h→Zγ decay. Interestingly we find that the rates of loop-induced decays are correlated and their signal strengths can rise up to 40%-60% depending on the channel. We furthermore study the dark matter phenomenology of the TMSSM. The lightest neutralino is a good dark matter candidate in two regions. The first one is related to the Higgs and Z resonances and the LSP is mostly Bino. The second one is achieved for a mass larger than 90 GeV and the LSP behaves as the well-tempered neutralino. An advantage of the triplet contribution is that the well-tempered neutralino can be a Bino-Triplino mixture, relieving the problem of achieving M2∝M1 in unified scenarios. The dark matter constraints strongly affect the Higgs phenomenology, reducing the potential enhancements of the diphoton and of the Zγ channels by 20% at most. These enhancements are however larger than the MSSM ones. In the near future, complementarity of dark matter direct searches and collider experiments will be crucial to probe most of the parameter space where the neutralino is the dark matter candidate.

  2. The Chemical Enrichment History of the Fornax Dwarf Spheroidal Galaxy from the Infrared Calcium Triplet

    CERN Document Server

    Pont, F; Gallart, C; Hardy, E; Winnick, R A; Pont, Frederic; Zinn, Robert; Gallart, Carme; Hardy, Eduardo; Winnick, Rebeccah

    2004-01-01

    Near infrared spectra were obtained for 117 red giants in the Fornax dwarf spheroidal galaxy with the FORS1 spectrograph on the VLT, in order to study the metallicity distribution of the stars and to lift the age-metallicity degeneracy of the red giant branch (RGB) in the color-magnitude diagram (CMD). Metallicities are derived from the equivalent widths of the infrared Calcium triplet lines at 8498, 8542, and 8662 A, calibrated with data from globular clusters, the open cluster M67 and the LMC. For a substantial portion of the sample, the strength of the Calcium triplet is unexpectedly high, clearly indicating that the main stellar population of Fornax is significantly more metal-rich than could be inferred from the position of its RGB in the CMD. We show that the relative narrowness of the RGB in Fornax is caused by the superposition of stars of very different ages and metallicities. The metallicity distribution in Fornax is centered at [Fe/H]= -0.9, with a metal-poor tail extending to [Fe/H] ~= -2. While t...

  3. Rectification and Robust Matching Using Oriented Image Triplets for Minimally Invasive Surgery

    Science.gov (United States)

    Conen, N.; Jepping, C.; Luhmann, T.; Maas, H.-G.

    2016-06-01

    Stereo endoscopes for minimally invasive surgery have been available on the market for several years and are well established in some areas. In practice, they offer a stereoscopic view to the surgeon but are not yet intended for 3D measurements. However, using current knowledge about the camera system and the difficult conditions in object space, it is possible to reconstruct a highly accurate surface model of the current endoscopic view. In particular for medical interventions, a highly reliable point cloud and real-time computation are required. To obtain good reliability, a miniaturised trinocular camera system is introduced that reduces the amount of outliers. To reduce computation time, an approach for generation of rectified image triplets and their corresponding interior and exterior camera parameters has been developed. With these modified and parameterised images it is possible to directly process 3D measurements in object space. Accordingly, an efficient semi-global optimisation is implemented by the authors. In this paper the special camera system, the rectification approach and the applied methodology of matching in rectified image triplets are explained. Finally, first results are presented. In conclusion, the trinocular camera system provides more reliable point clouds than a binocular one, especially for areas with repetitive or poor texture. Currently, the benefit of the third camera is not as great as desired.

  4. A CP-violating phase in a two Higgs triplet scenario : some phenomenological implications

    CERN Document Server

    Chaudhuri, Avinanda

    2016-01-01

    We consider a scenario where, along with the usual Higgs doublet, two scalar triplets are present. The extension of the triplet sector is required for the Type~II mechanism for the generation of neutrino masses, if this mechanism has to generate a neutrino mass matrix with two-zero texture. One CP-violating phase has been retained in the scalar potential of the model, and all parameters have been chosen consistently with the observed neutrino mass and mixing patterns. We find that a large phase ($\\gtrsim 60^{\\circ}$) splits the two doubly-charged scalar mass eigenstates wider apart, so that the decay $H_1^{++} \\rightarrow H_2^{++} h$ is dominant (with h being the $125$ GeV scalar). We identify a set of benchmark points where this decay dominates. This is complementary to the situation, reported in our earlier work, where the heavier doubly-charged scalar decays as $H_1^{++} \\rightarrow H_2^+ W^+$. We point out the rather spectacular signal, ensuing from $H_1^{++} \\rightarrow H_2^{++} h$, in the form of Higgs ...

  5. Preliminary Design of the HiLumi-LHC Triplet Area Beam Screen

    CERN Document Server

    Kersevan, R; Kos, N

    2014-01-01

    The so-called beam screen (BS) is a proven solution for intercepting the thermal loads caused by the circulating beams in the cryogenically-cooled sections of the LHC and minimizing dynamic vacuum effects [1]. The new triplet area foreseen for the HiLumi-LHC (HL-LHC) machine upgrade [2] has the additional feature of needing internal tungsten shields to reduce the amount of collision debris which is deflected by the high-gradient triplet magnets towards the superconducting magnets' cold masses and coils. The very aggressive optics design, based on large beam separations, calls for a maximum of physical space to remain available to the counter rotating beams in the common BS. This places severe constraints to the fabrication and installation tolerances of the BS itself, in addition to affecting the design and routing of the cryogenic lines in the area. The latest version of the BS design will be shown and discussed, together with future plans for testing materials, fabrication procedures, and installation.

  6. Elastic Scattering between Ultracold 23Na and 85Rb Atoms in the Triplet State

    Institute of Scientific and Technical Information of China (English)

    HU Qiu-Bo; ZHANG Yong-Sheng; SUN Jin-Feng; YU Ke

    2011-01-01

    @@ The elastic scattering Properties between ultracold 23Na and 85Rd atoms for the triplet state(a3∑u+ )are researched.The s-wave scattering lengts of 23Na and 85Rb are calculate by the Numerov ana semtc asstc method with two kinds of interatomic potentials, which are the interpolation potential and Lennard-Jones potential(LJ12,6)by the same phase 4φ Shape resonances appear clearly in the l= 5 partial waves for the a- Lu state.Moreover, the s-wave scattering cross section, total cross section and energy positions of shape resonances are also discussed.%The elastic scattering properties between ultracold 23Na and 85 Rb atoms for the triplet state (a3Σu+ ) are researched. The s-wave scattering lengths of 23Na and 85Rb are calculated by the Numerov and semiclassical method with two kinds of interatomic potentials, which are the interpolation potential and Lennard-Jones potential (LJ12,6) by the same phase φ. Shape resonances appear clearly in the l= 5 partial waves for the a3 Σu+state. Moreover, the s-wave scattering cross section, total cross section and energy positions of shape resonances are also discussed.

  7. C P -violating phase in a two Higgs triplet scenario: Some phenomenological implications

    Science.gov (United States)

    Chaudhuri, Avinanda; Mukhopadhyaya, Biswarup

    2016-05-01

    We consider a scenario where, along with the usual Higgs doublet, two scalar triplets are present. The extension of the triplet sector is required for the Type II seesaw mechanism for the generation of neutrino masses, if this mechanism has to generate a neutrino mass matrix with two-zero texture. One C P -violating phase has been retained in the scalar potential of the model, and all parameters have been chosen consistently with the observed neutrino mass and mixing patterns. We find that a large phase (≳6 0 ° ) splits the two doubly charged scalar mass eigenstates wider apart, so that the decay H1++→H2++h is dominant (with h being the 125 GeV scalar). We identify a set of benchmark points where this decay dominates. This is complementary to the situation, reported in our earlier work, where the heavier doubly charged scalar decays as H1++→H2+W+ . We point out the rather spectacular signal, ensuing from H1++→H2++h , in the form of Higgs plus the same-sign dilepton peak, which can be observed at the Large Hadron Collider.

  8. Enhanced efficiency in single-host white organic light-emitting diode by triplet exciton conversion

    International Nuclear Information System (INIS)

    The authors observe that the external quantum efficiency (EQE) of the Iridium (III) bis(4-phenylthieno [3,2-c]pyridinato-N,C2′)acetylacetonate (PO-01) based yellow organic light-emitting diode (OLED) is significantly increased by uniformly co-doping Iridium (III)bis[(4,6-difluorophenyl)-pyridinato-N,C2−] (FIrpic) and PO-01 into the same wide band-gap host of N,N′-dicarbazolyl-3, 5-benzene (mCP). Detailed investigation indicates that the efficiency enhancement is ascribed to effective triplet exciton gathering by FIrpic, followed by energy transfer to PO-01. Compared to the control device, which has maximum EQE of 10.5%, an improved maximum EQE of 13.2% is obtained in the optimization white device based on FIrpic and PO-01 emission according to this principle. This work makes it easier for a single host white OLED to simultaneously harvest high efficiency in both blue and yellow units. Comprehensive experimental results show that this phenomenon can also be found and utilized in other popular hosts to realize more efficient white devices. -- Highlights: • This work makes easier for a single host white OLED to harvest high efficiency in both blue and yellow units. • Efficiency enhancement is ascribed to effective triplet exciton gathering by FIrpic, followed by energy transfer to PO-01. • This phenomenon can also be found and utilized in other popular hosts to realize more efficient white devices

  9. Photosensitizing and Inhibitory Effects of Ozonated Dissolved Organic Matter on Triplet-Induced Contaminant Transformation.

    Science.gov (United States)

    Wenk, Jannis; Aeschbacher, Michael; Sander, Michael; von Gunten, Urs; Canonica, Silvio

    2015-07-21

    Dissolved organic matter (DOM) is both a promoter and an inhibitor of triplet-induced organic contaminant oxidation. This dual role was systematically investigated through photochemical experiments with three types of DOM of terrestrial and aquatic origins that were preoxidized to varying extents by ozonation. The inhibitory effect of DOM was assessed by determining the 4-carboxybenzophenone photosensitized transformation rate constants of two sulfonamide antibiotics (sulfamethoxazole and sulfadiazine) in the presence of untreated or preoxidized DOM. The inhibitory effect decreased with the increasing extent of DOM preoxidation, and it was correlated to the loss of phenolic antioxidant moieties, as quantified electrochemically, and to the loss of DOM ultraviolet absorbance. The triplet photosensitizing ability of preoxidized DOM was determined using the conversion of the probe compound 2,4,6-trimethylphenol (TMP), which is unaffected by DOM inhibition effects. The DOM photosensitized transformation rate constants of TMP decreased with increasing DOM preoxidation and were correlated to the concomitant loss of chromophores (i.e., photosensitizing moieties). The combined effects of DOM preoxidation on the inhibiting and photosensitizing properties were assessed by phototransformation experiments of the sulfonamides in DOM-containing solutions. At low extents of DOM preoxidation, the sulfonamide phototransformation rate constants remained either unchanged or slightly increased, indicating that the removal of antioxidant moieties had larger effects than the loss of photosensitizing moieties. At higher extents of DOM preoxidation, transformation rates declined, mainly reflecting the destruction of photosensitizing moieties. PMID:26091366

  10. Optical Spectroscopy

    DEFF Research Database (Denmark)

    Thyrhaug, Erling

    The work presented in this thesis is broadly concerned with how complexation reactions and molecular motion can be characterized with the standard techniques in optical spectroscopy. The thesis aims to show a relatively broad range of methods for probing physico-chemical properties in fluorophore...... information about chemical equilibria, kinetics and molecular motion by monitoring changes in optical properties of the system. The five presented research projects are largely unrelated to each other both in aim and in what property is probed, however they are all connected in that they are fluorophore...... containing systems and are characterized using techniques in optical spectroscopy. Of the standard techniques in optical spectroscopy, particular attention has been paid to those based on time-resolved measurements and polarization, which is reflected in the experiment design in the projects. Not all of the...

  11. Proximity induced vortices and long-range triplet supercurrents in ferromagnetic Josephson junctions and spin valves

    International Nuclear Information System (INIS)

    Using a spin-parameterized quasiclassical Keldysh-Usadel technique, we theoretically study supercurrent transport in several types of diffusive ferromagnetic (F)/superconducting (S) configurations with differing magnetization textures. We separate out the even- and odd-frequency components of the supercurrent within the low proximity limit and identify the relative contributions from the singlet and triplet channels. We first consider inhomogeneous one-dimensional Josephson structures consisting of a uniform bilayer magnetic S/F/F/S structure and a trilayer S/F/F/F/S configuration, in which case the outer F layers can have either a uniform or conical texture relative to the central uniform F layer. Our results demonstrate that for supercurrents flowing perpendicular to the F/F interfaces, incorporating a conical texture yields the most effective way to observe the signatures of long-ranged spin-triplet supercurrents. We also consider three different types of finite-sized two-dimensional magnetic structures subjected to an applied magnetic field normal to the junction plane: a S/F/S junction with uniform magnetization texture and two S/F/F/S configurations with differing F/F bilayer arrangements. In one case, the F/F interface is parallel with the S/F junction interfaces while in the other case, the F/F junction is oriented perpendicular to the S/F interfaces. We then discuss the proximity vortices and corresponding spatial maps of currents inside the junctions. For the uniform S/F/S junction, we analytically calculate the magnetic field induced supercurrent and pair potential in both the narrow and wide junction regimes, thus providing insight into the variations in the Fraunhofer diffraction patterns and proximity vortices when transitioning from a wide junction to a narrow one. Our extensive computations demonstrate that the induced long-range spin-triplet supercurrents can deeply penetrate uniform F/F bilayers when spin-singlet supercurrents flow parallel to the

  12. Nuclear spectroscopy

    CERN Document Server

    Ajzenberg-Selove, Fay

    1960-01-01

    Nuclear Spectroscopy, Part A deals with the experimental and theoretical techniques involved in nuclear spectroscopy.This book discusses the interactions of charged particles with matter, gaseous ionization detectors, and particular mass attenuation coefficients. The magnetic gamma-ray spectrometers for photo or internal-conversion electrons, general characteristics of cross-section variation with energy, and measurement of fast neutron spectra are also elaborated. This text likewise covers the elastic scattering of photons by nuclei and measurement of widths of gamma-radiating levels.This pub

  13. Optogalvanic spectroscopy

    International Nuclear Information System (INIS)

    Laser induced optogalvanic spectroscopy in a hollow cathode-produced plasma has been used to resolve the isotopic structure of some absorption lines in uranium. We have shown that the optogalvanic signal associated with any isotope can be related to the concentration of that isotope in a multi-isotopic sample. From the results we have obtained, optogalvanic spectroscopy of sputtered samples appears to be an interesting approach to the isotopic analysis of both natural and enriched uranium and could easily be applied to the analysis of other fissile elements, such as the plutonium isotopes

  14. Direct measurements of the current-phase relation in long-range spin-triplet SFS Josephson junctions

    Science.gov (United States)

    Hamilton, David; van Harlingen, Dale; Wang, Yixing; Birge, Norman

    2015-03-01

    We present direct measurements of the current-phase relation (CPR) of Josephson junctions which use multiple ferromagnetic layers to generate long-range spin-triplet pair correlations. Using a phase-sensitive Josephson interferometry technique, we obtain the phase and temperature dependence of this spin-triplet supercurrent. We also demonstrate the use of an inductive shunt to enhance this technique at higher critical currents. Our data suggest that the current-phase relation of these junctions is harmonic in character. Further measurements are planned in order to determine the ground state phase shift of these junctions.

  15. A spin triplet supercurrent in half metal ferromagnet/superconductor junctions with the interfacial Rashba spin-orbit coupling

    Science.gov (United States)

    Niu, ZhiPing

    2012-08-01

    dc Josephson currents in s-wave superconductor/half metal ferromagnet (HMF)/s-wave superconductor junctions are investigated. We propose the interfacial Rashba spin-orbit coupling as a possible mechanism giving rise to the spin flip Andreev reflection, which results in the singlet-triplet conversion at HMF/superconductor interfaces. When the magnetization direction of the HMF and that of the effective spin-orbit magnetic field are noncolinear, a long-ranged spin triplet supercurrent appears. The supercurrent strongly depends on the magnetization direction of the HMF and can be enhanced by the Rashba spin-orbit coupling strength.

  16. Helium-like triplet density diagnostics: Applications to CHANDRA--LETGS X-ray observations of Capella and Procyon

    OpenAIRE

    Ness, J. U.; Mewe, R.; Schmitt, J. H. M. M.; Raassen, A. J. J.; Porquet, D.; Kaastra, J. S.; Van Der Meer, R.L.J.; Burwitz, V.; Predehl, P.

    2000-01-01

    Electron density diagnostics based on the triplets of Helium-like CV, NVI, and OVII are applied to the X-ray spectra of Capella and Procyon measured with the Low Energy Transmission Grating Spectrometer (LETGS) on board the Chandra X-ray Observatory. New theoretical models for the calculation of the line ratios between the forbidden (f), intercombination (i), and the resonance (r) lines of the helium-like triplets are used. The derived densities are quite typical of densities found in the sol...

  17. Photoacoustic Spectroscopy

    Czech Academy of Sciences Publication Activity Database

    Zelinger, Zdeněk; Střižík, Michal

    Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA, 2008 - (Lackner, M.), s. 227-254 ISBN 978-3-527-31997-8 Institutional research plan: CEZ:AV0Z40400503 Keywords : lasers * chemistry * photoacoustic spectroscopy Subject RIV: CF - Physical ; Theoretical Chemistry

  18. The structure and stability of CaFe layered double hydroxides with various Ca:Fe ratios studied by Mössbauer spectroscopy, X-ray diffractometry and microscopic analysis

    Science.gov (United States)

    Sipiczki, M.; Kuzmann, E.; Homonnay, Z.; Megyeri, J.; Pálinkó, I.; Sipos, P.

    2013-07-01

    The effects of the Ca(II)/Fe(III) ratios on the structure and Fe microenvironments have been studied in layered double hydroxides comprising of Ca(II) and Fe(III) (CaFe-LDH) prepared by the co-precipitation method. The Ca(II)/Fe(III) ratios were varied systematically from 2 to 6 and for characterisation 57Fe Mössbauer spectroscopy, powder X-ray diffractometry and scanning electron microscopy were applied. XRD patterns of the samples at all Ca(II)/Fe(III) ratios exhibited reflections corresponding to CaFe-LDH and 57Fe Mössbauer measurements revealed that Fe(III) was in a high-spin, somewhat disordered octahedral environment. Above the Ca(II)/Fe(III) ratio of 2 the reflections of Ca(OH)2 also appeared. This phase was found to stabilise the LDH phase, while the phase-pure LDH decomposed on ageing.

  19. Synthesis, measurements, and theoretical analysis of carbazole derivatives with high-triplet-energy

    Energy Technology Data Exchange (ETDEWEB)

    Li Jianli; Mi Xiaoyun; Wan Yuchun [School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022 (China); Si Zhenjun, E-mail: szj@cust.edu.cn [School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022 (China); Institute of Organic Chemistry and Biochemistry, Czech Academy of Science, Praha 6 16610 (Czech Republic); Sun Haiying; Duan Qian [School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022 (China); He Xingquan [School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022 (China); Yan Dong; Wan Sha [School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022 (China)

    2012-05-15

    In order to obtain the blue light-emitting organic materials with high triplet state energy, two 3,5-diphenyl-4H-1,2,4-triazole (Tz) containing carbazole (Cz) derivatives of 9-(4-(3,5-diphenyl-4H-1,2,4-triazol-4-yl)phenyl)-9H-carbazole (TzCz1) and 3,6-di-tert-butyl-9-(4-(3,5-diphenyl-4H-1,2,4-triazol-4-yl)phenyl) -9H-carbazole (TzCz2) are synthesized using Cz acting as the starting material, as well as characterized by the {sup 1}H NMR spectra, ultraviolet-visible (UV-vis) absorption spectra, and the IR absorption spectra. The luminescence quantum yields (LQYs) of TzCz1 and TzCz2 are measured in CH{sub 2}Cl{sub 2} solution to be 32.1% and 47.5%, respectively. The electrochemical analysis and the photophysical measurements suggest that the triplet energy levels and the energy gaps of the highest-occupied orbital and the lowest-unoccupied orbital are 2.83 eV and 3.59 eV for TzCz1, and 2.80 eV and 3.43 eV for TzCz2. At last, the theoretical analyses of their ground state geometries and the simulated UV-vis absorption spectra are carried out at B3LYP1/6-31G Low-Asterisk level. The studies mentioned above indicate that both TzCz1 and TzCz2 are suitable for the host materials of blue light-emitting diodes. - Highlights: Black-Right-Pointing-Pointer Synthesis of two blue light-emitting Carbazole derivatives. Black-Right-Pointing-Pointer Photophysical and electrochemical properties are systematically studied. Black-Right-Pointing-Pointer Theoretical analysis of geometry of the ground states and the UV-vis absorption are performed with Firefly package. Black-Right-Pointing-Pointer The triplet energy levels are measured to be ca. 2.83 eV.

  20. Grain Spectroscopy

    Science.gov (United States)

    Allamandola, L. J.

    1992-01-01

    Our fundamental knowledge of interstellar grain composition has grown substantially during the past two decades thanks to significant advances in two areas: astronomical infrared spectroscopy and laboratory astrophysics. The opening of the mid-infrared, the spectral range from 4000-400 cm(sup -1) (2.5-25 microns), to spectroscopic study has been critical to this progress because spectroscopy in this region reveals more about a materials molecular composition and structure than any other physical property. Infrared spectra which are diagnostic of interstellar grain composition fall into two categories: absorption spectra of the dense and diffuse interstellar media, and emission spectra from UV-Vis rich dusty regions. The former will be presented in some detail, with the latter only very briefly mentioned. This paper summarized what we have learned from these spectra and presents 'doorway' references into the literature. Detailed reviews of many aspects of interstellar dust are given.

  1. The Scalar Triplet Contribution to Lepton Flavour Violation and Neutrinoless Double Beta Decay in Left-Right Symmetric Model

    CERN Document Server

    Bambhaniya, Gulab; Goswami, Srubabati; Mitra, Manimala

    2015-01-01

    We analyse in detail the scalar triplet contribution to the low-energy lepton flavour violating (LFV) and lepton number violating (LNV) processes within a TeV-scale left-right symmetric framework. We show that in both type-I and type-II seesaw dominance for the light neutrino masses, the triplet of comparable or smaller mass than the largest right-handed neutrino mass scale can give sizeable contribution to the LFV processes, except in the quasi-degenerate limit of light neutrino masses, where a suppression can occur due to cancellations. In particular, a moderate value of the heaviest neutrino to scalar triplet mass ratio $r\\lesssim {\\cal O}(1)$ is still experimentally allowed and can be explored in the future LFV experiments. Similarly, the contribution of a relatively light triplet to the LNV process of neutrinoless double beta decay could be significant, disfavouring a part of the model parameter space otherwise allowed by LFV constraints. Nevertheless, we find regions of parameter space consistent with b...

  2. Triplet repeat sequences in human DNA can be detected by hybridization to a synthetic (5'-CGG-3')17 oligodeoxyribonucleotide

    DEFF Research Database (Denmark)

    Behn-Krappa, A; Mollenhauer, J; Doerfler, W

    1993-01-01

    The seemingly autonomous amplification of naturally occurring triplet repeat sequences in the human genome has been implicated in the causation of human genetic disease, such as the fragile X (Martin-Bell) syndrome, myotonic dystrophy (Curshmann-Steinert), spinal and bulbar muscular atrophy...

  3. Singlet and Triplet Excitation Management in a Bichromophoric Near-Infrared-Phosphorescent BODIPY-Benzoporphyrin Platinum Complex

    KAUST Repository

    Whited, Matthew T.

    2011-01-12

    Multichromophoric arrays provide one strategy for assembling molecules with intense absorptions across the visible spectrum but are generally focused on systems that efficiently produce and manipulate singlet excitations and therefore are burdened by the restrictions of (a) unidirectional energy transfer and (b) limited tunability of the lowest molecular excited state. In contrast, we present here a multichromophoric array based on four boron dipyrrins (BODIPY) bound to a platinum benzoporphyrin scaffold that exhibits intense panchromatic absorption and efficiently generates triplets. The spectral complementarity of the BODIPY and porphryin units allows the direct observation of fast bidirectional singlet and triplet energy transfer processes (k ST(1BDP→1Por) = 7.8×1011 s-1, kTT(3Por→3BDP) = 1.0×1010 s-1, kTT(3BDP→ 3Por) = 1.6×1010 s-1), leading to a long-lived equilibrated [3BDP][Por]=[BDP][3Por] state. This equilibrated state contains approximately isoenergetic porphyrin and BODIPY triplets and exhibits efficient near-infrared phosphorescence (λem = 772 nm, φ = 0.26). Taken together, these studies show that appropriately designed triplet-utilizing arrays may overcome fundamental limitations typically associated with core-shell chromophores by tunable redistribution of energy from the core back onto the antennae. © 2010 American Chemical Society.

  4. Carbazolyldibenzofuran-type high-triplet-energy bipolar host material for blue phosphorescent organic light-emitting diodes

    International Nuclear Information System (INIS)

    A high-triplet-energy material, 9′-(4,4′-(phenylphosphoryl)bis(dibenzo[b,d]furan-6,2-diyl)) bis(9H-carbazole) (44DFCzPO), was synthesized as a bipolar host material for blue phosphorescent organic light-emitting diodes (PHOLEDs). 44DFCzPO was synthesized by the selective lithiation of the 4-position of a carbazole-modified dibenzofuran, followed by phosphorylation. 44DFCzPO showed a high triplet energy of 2.91 eV for energy transfer to a blue phosphorescent dopant, and bipolar charge transport properties for balanced hole and electron density in the emitting layer. A high quantum efficiency of 16.7% at a low doping concentration of 3% was obtained using 44DFCzPO as the host in blue PHOLEDs. -- Highlights: • High quantum efficiency and stable film morphology up to 110 °C. • High triplet energy of 2.91 eV for energy transfer to blue dopant. • Carbazolyldibenzofuran type high triplet energy host material

  5. Transient photocurrent in molecular junctions: singlet switching on and triplet blocking.

    Science.gov (United States)

    Petrov, E G; Leonov, V O; Snitsarev, V

    2013-05-14

    The kinetic approach adapted to describe charge transmission in molecular junctions, is used for the analysis of the photocurrent under conditions of moderate light intensity of the photochromic molecule. In the framework of the HOMO-LUMO model for the single electron molecular states, the analytic expressions describing the temporary behavior of the transient and steady state sequential (hopping) as well as direct (tunnel) current components have been derived. The conditions at which the current components achieve their maximal values are indicated. It is shown that if the rates of charge transmission in the unbiased molecular diode are much lower than the intramolecular singlet-singlet excitation/de-excitation rate, and the threefold degenerated triplet excited state of the molecule behaves like a trap blocking the charge transmission, a possibility of a large peak-like transient switch-on photocurrent arises. PMID:23676066

  6. Monozygotic Triplets and Dizygotic Twins following Transfer of Three Poor-Quality Cleavage Stage Embryos

    Directory of Open Access Journals (Sweden)

    Reshef Tal

    2012-01-01

    Full Text Available Background. Assisted reproductive technology has been linked to the increased incidence of monozygotic twinning. It is of clinical importance due to the increased risk of complications in multiple pregnancies in general and in monozygotic twins in particular. Case. A 29-year-old female, nulligravida underwent her first IVF cycle. Three poor-quality cleavage stage embryos were transferred resulting in monochorionic triamniotic triplets and dichorionic diamniotic twins. Selective embryo reduction was performed at 12 weeks leaving dichorionic twins. The patient underwent emergency cesarean section due to preterm labor and nonreassuring fetal heart tracing at 30 weeks of gestation. Conclusion. Our case emphasizes that even embryos with significant morphological abnormalities should be considered viable and the possibility of simultaneous spontaneous embryo splitting must be factored into determining number of embryos to transfer.

  7. 750-GeV Diphoton Resonance as the Singlet of Custodial Higgs Triplet Model

    CERN Document Server

    Chiang, Cheng-Wei

    2016-01-01

    The observation of diphoton excess around the mass of 750~GeV at the LHC motivates us to consider the singlet Higgs boson in the custodial Higgs triplet model as a good candidate. Based on an earlier study of comprehensive parameter scan for viable mass spectra, we show that the diphoton resonance data fall well within the allowed space. Moreover, we point out that a definite mass hierarchy emerges among the exotic Higgs bosons in the model. Further search channels for the singlet and those for the other exotic Higgs bosons in LHC Run-II are discussed. In particular, we present a simulation of distributions of two kinematic variables for the search of the doubly-charged Higgs boson.

  8. Permutation symmetry S3 and vacuum expectation value structure of flavor-triplet Higgs scalars

    International Nuclear Information System (INIS)

    A model with flavor-triplet Higgs scalars φi (i=1,2,3) is investigated under a permutation symmetry S3 and its symmetry breaking. A possible S3 breaking form of the Higgs potential whose vacuum expectation values vi=i> satisfy a relation v12+v22+v32=(2/3)(v1+v2+v3)2 is investigated, because if we suppose a seesaw-like mass matrix model Me=mM-1m with mij∝δijvi and Mij∝δij, such a model can lead to the well-known charged lepton mass relation me+mμ+mτ=(2/3)(√(me)+√(mμ)+√(mτ))2

  9. Domain walls and long-range triplet correlations in SFS Josephson junctions

    Science.gov (United States)

    Buzdin, A. I.; Mel'Nikov, A. S.; Pugach, N. G.

    2011-04-01

    We study the contribution of domain walls to the Josephson current through a ferromagnetic metal both in clean and diffusive limits. Our consideration of these limits is based on the quasiclassical version of the Bogoliubov-de Gennes equations and the Usadel theory, correspondingly. In the clean limit, the domain walls connecting superconducting leads are shown to be responsible for strong enhancement of the Josephson current, even for a domain structure with collinear magnetic moments. In the dirty limit, a noticeable increase in the critical current appears only for a system with noncollinear magnetic moments. We demonstrate that a thin domain wall in this case may serve as an efficient source of the long-range triplet proximity effect.

  10. New 2D Thermal Model Applied to an LHC Inner Triplet Quadrupole Magnet

    CERN Document Server

    Bielert, ER; Ten Kate, HHJ; Verweij, AP

    2011-01-01

    A newly developed numerical model is presented that enables to compute two-dimensional heat transfer and temperature distributions over the cross-section of superconducting accelerator magnets. The entire thermal path from strand-in-cable to heat sink, including helium channels is considered. Superfluid helium properties are combined with temperature- and field-dependent non-linear solid material properties. Interfacial interactions are also taken into account. The model is applied to the cross-section of an inner triplet quadrupole magnet featuring a new concept for the ground insulation. Beam loss profiles are implemented as main heat source. It is concluded that operational margins can be considerably increased by opening additional thermal paths, improving the cooling conditions.

  11. Singlet to triplet conversion of metastable He atoms during deexcitation at a Cs-covered surface

    International Nuclear Information System (INIS)

    Electron emission from a Cs monolayer on a Cu(110) surface by impact of metastable 3S He( atoms is caused by Auger deexcitation as demonstrated by identification of Cs 5p- and 6s-derived levels in the electron energy distribution curves. These curves recorded with 1S He( are almost identical, and it turns out that only a small fraction of the singlet atoms undergo direct Auger deexcitation while the major part is converted into the triplet state from where Auger deexcitation occurs. A novel mechanism for this spin-flip process is proposed; it is accompanied by the creation of an electron-hole pair in the target for conservation of energy and total spin

  12. Filter function formalism beyond pure dephasing and non-Markovian noise in singlet-triplet qubits

    Science.gov (United States)

    Barnes, Edwin; Rudner, Mark S.; Martins, Frederico; Malinowski, Filip K.; Marcus, Charles M.; Kuemmeth, Ferdinand

    2016-03-01

    The filter function formalism quantitatively describes the dephasing of a qubit by a bath that causes Gaussian fluctuations in the qubit energies with an arbitrary noise power spectrum. Here, we extend this formalism to account for more general types of noise that couple to the qubit through terms that do not commute with the qubit's bare Hamiltonian. Our approach applies to any power spectrum that generates slow noise fluctuations in the qubit's evolution. We demonstrate our formalism in the case of singlet-triplet qubits subject to both quasistatic nuclear noise and 1 /ωα charge noise and find good agreement with recent experimental findings. This comparison shows the efficacy of our approach in describing real systems and additionally highlights the challenges with distinguishing different types of noise in free induction decay experiments.

  13. ESR spin elimination research on reaction of triplet state of VK3 with nucleic acid derivatives

    International Nuclear Information System (INIS)

    In order to study the reaction of triplet state of VK3 with nucleic acid derivatives, the ESR (Electron spin resonance) spin elimination has been used with 4-oxo-TEMPO as spin trap. The reactivities of 3VK3* with nucleosides, nucleotides, and models of telomeric DNA, template of telomerase RNA and its L6-P6 region have been confirmed respectively. The results show that the tendency of reaction of 3VK3* with nucleosides is Gua>Ade>Cyt>Thy, meanwhile dGMP>dAMP>dCMP> TMP for reaction of 3VK3* with deoxy-nucleotides, and the one for reaction of 3VK3* with telomeric DNA is the highest in polynucleotides. This is highly accordant with both of their corresponding rate constants determined by laser flash photolysis and their oxidation-reduction potentials. It also shows that the reactivity of 3VK3* with polynucleotides is directly proportional to their G amount. (authors)

  14. Spin supercurrent and phase-tunable triplet Cooper pairs via magnetic insulators

    Science.gov (United States)

    Gomperud, Ingvild; Linder, Jacob

    2015-07-01

    We demonstrate theoretically that a dissipationless spin current can flow a long distance through a diffusive normal metal by using superconductors interfaced with magnetic insulators. The magnitude of this spin supercurrent is controlled via the magnetization orientation of the magnetic insulators. The spin supercurrent obtained in this way is conserved in the normal metal just like the charge current and interestingly has a term that is independent of the superconducting phase difference. The quantum state of the system can be switched between 0 and π by reversing the insulators from a parallel to antiparallel configuration with an external field. We show that the spin current is carried through the normal metal by superconducting triplet (odd-frequency) correlations and that the superconducting phase difference can be used to enhance these, leaving clear spectroscopic fingerprints in the density of states.

  15. Absence of the discontinuous transition in the one-dimensional triplet creation model.

    Science.gov (United States)

    Park, Su-Chan

    2009-12-01

    Although Hinrichsen in his unpublished work theoretically rebutted the possibility of the discontinuous transition in one-dimensional nonequilibrium systems unless there are additional conservation laws, long-range interactions, macroscopic currents, or special boundary conditions, we have recently observed the resurrection of the claim that the triplet creation (TC) model introduced by Dickman and Tomé [Phys. Rev. A 44, 4833 (1991)] would show the discontinuous transition. By extensive simulations, however, we find that the one-dimensional TC does belong to the directed percolation universality class even for larger diffusion constant than the suggested tricritical point in the literature. Furthermore, we find that the phase boundary is well described by the crossover from the mean field to the directed percolation, which supports the claim that the one-dimensional TC does not exhibit a discontinuous transition. PMID:20365114

  16. Conductivity estimates of spherical-particle suspensions based on triplet structure factors

    Science.gov (United States)

    Nguyen, Minh-Tan; Monchiet, Vincent; Bonnet, Guy; To, Quy-Dong

    2016-02-01

    In this paper, we present an estimation of the conductivity of composites constituted of identical spheres embedded in a host material. A family of polarization integral equations for the localization problem is constructed and the operator is then minimized to yield an optimal integral equation. As a result, the corresponding Neumann series converges with the fastest rate and can be used to estimate the effective conductivity. By combining this series and integral approximation, one can derive explicit expressions for the overall property using expansions in Fourier domain. For random hard-sphere systems, relations to structure factors and triplet structure factors have been made and Kirkwood superposition approximation is used to evaluate the effective conductivity, taking into account third-order correlations. This presents an original means to account for the statistical information up to third-order correlation when determining the effective properties of composite materials.

  17. Single Production of Doubly Charged Higgs Boson via e7 Collision in Higgs Triplet Model

    Institute of Scientific and Technical Information of China (English)

    苏雪松; 岳崇兴; 张娇; 王珏

    2011-01-01

    The Higgs triplet model (HTM) predicts the existence of a pair of doubly charged Higgs bosons H±±. Single production of H±± via e7 collision at the next generation e+ e- International Linear Collider (ILC) and the Large Hadron electron Collider (LHeC) is considered. The numerical results show that the production cross sections are very sensitive to the neutrino oscillation parameters. Their values for the inverted hierarchy mass spectrum are larger than those for the normal hierarchy mass spectrum at these two kinds of collider experiments. With reasonable values of the relevant free parameters, the possible signals of the doubly charged Higgs bosons predicted by the HTM might be detected in future ILC experiments.

  18. Assessment and Mitigation of the Proton-Proton Collision Debris Impact on the FCC Triplet

    CERN Document Server

    Besana, Maria Ilaria; Fartoukh, Stephane; Martin, Roman; Tomás, Rogelio

    2016-01-01

    The Future Circular hadron Collider (FCC-hh), which is designed to operate at a centre-of-mass energy of 100 TeV and to deliver ambitious targets in terms of both instantaneous and integrated luminosity, poses extreme challenges in terms of machine protection during operation and with respect to long-term damages. Energy deposition studies are a crucial ingredient for its design. One of the relevant radiation sources are collision debris particles, which de- posit their energy in the interaction region elements and in particular in the superconducting magnet coils of the final focus triplet quadrupoles, to be protected from the risk of quenching and deterioration. In this contribution, the collision debris will be characterised and expectations obtained with FLUKA will be presented, including magnet lifetime considerations. New techniques including crossing angle gymnastics for peak dose deposition mitigation (as recently introduced in the framework of the LHC operation), will be discussed.

  19. The SLUGGS Survey: Calcium Triplet-based Spectroscopic Metallicities for Over 900 Globular Clusters

    CERN Document Server

    Usher, Christopher; Brodie, Jean P; Foster, Caroline; Spitler, Lee R; Arnold, Jacob A; Romanowsky, Aaron J; Strader, Jay; Pota, Vincenzo

    2012-01-01

    Although the colour distribution of globular clusters in massive galaxies is well known to be bimodal, the spectroscopic metallicity distribution has been measured in only a few galaxies. After redefining the calcium triplet index-metallicity relation, we use our relation to derive the metallicity of 903 globular clusters in 11 early-type galaxies. This is the largest sample of spectroscopic globular cluster metallicities yet assembled. We compare these metallicities with those derived from Lick indices finding good agreement. In 6 of the 8 galaxies with sufficient numbers of high quality spectra we find bimodality in the spectroscopic metallicity distribution. Our results imply that most massive early-type galaxies have bimodal metallicity, as well as colour, distributions. This bimodality suggests that most massive galaxies early-type galaxies experienced two periods of star formation.

  20. High-fidelity singlet-triplet S -T- qubits in inhomogeneous magnetic fields

    Science.gov (United States)

    Wong, Clement H.; Eriksson, M. A.; Coppersmith, S. N.; Friesen, Mark

    2015-07-01

    We propose an optimized set of quantum gates for a singlet-triplet qubit in a double quantum dot with two electrons utilizing the S -T- subspace. Qubit rotations are driven by the applied magnetic field and a field gradient provided by a micromagnet. We optimize the fidelity of this qubit as a function of the magnetic fields, taking advantage of "sweet spots" where the rotation frequencies are independent of the energy level detuning, providing protection against charge noise. We simulate gate operations and qubit rotations in the presence of quasistatic noise from charge and nuclear spins as well as leakage to nonqubit states. Our results show that, for silicon quantum dots, gate fidelities greater than 99 % should be realizable, for rotations about two nearly orthogonal axes.

  1. Measurements of Ca II Infrared Triplet Lines of Young Stellar Objects

    CERN Document Server

    Moto'oka, Keiko

    2015-01-01

    Equivalent widths and line widths of Ca II infrared triplet emission lines were measured in high-resolution optical spectra of 39 young stellar objects.We found that the equivalent widths of the emission lines decrease with stellar evolution. It has been often claimed that strong chromospheric activity is generated by a dynamo process caused by fast rotation of the photosphere. However, we found no clear correlation between the strength of the Ca II lines and the stellar rotation velocity. Instead, we found that the objects with high mass accretion rates had stronger Ca II emission lines. This correlation supports the turbulent chromosphere model or the magnetic accretion theory for classical T Tauri stars. We also noticed that the equivalent widths of Ca II lines of transitional disk objects are one-tenth of those of classical T Tauri stars, even if the masses of the circumstellar disks are comparable.

  2. Empirical calibration of the near-IR Ca II triplet - III. Fitting functions

    CERN Document Server

    Cenarro, A J; Cardiel, N; Vazdekis, A; Peletier, R F

    2001-01-01

    Using a near-IR stellar library of 706 stars with a wide coverage of atmospheric parameters, we study the behaviour of the Ca II triplet strength in terms of effective temperature, surface gravity and metallicity. Empirical fitting functions for recently defined line-strength indices, namely CaT*, CaT and PaT, are provided. These functions can be easily implemented into stellar populations models to provide accurate predictions for integrated Ca II strengths. We also present a thorough study of the various error sources and their relation to the residuals of the derived fitting functions. Finally, the derived functional forms and the behaviour of the predicted Ca II are compared with those of previous works in the field.

  3. Area-dependence of spin-triplet supercurrent in ferromagnetic Josephson junctions

    International Nuclear Information System (INIS)

    In 2010, several experimental groups obtained compelling evidence for spin-triplet supercurrent in Josephson junctions containing strong ferromagnetic materials. Our own best results were obtained from large-area junctions containing a thick central Co/Ru/Co “synthetic antiferromagnet” and two thin outer layers made of Ni or PdNi alloy. Because the ferromagnetic layers in our samples are multi-domain, one would expect the sign of the local current-phase relation inside the junctions to vary randomly as a function of lateral position. Here we report measurements of the area dependence of the critical current in several samples, where we find some evidence for those random sign variations. When the samples are magnetized, however, the critical current becomes clearly proportional to the area, indicating that the current-phase relation has the same sign across the entire area of the junctions.

  4. Area-dependence of spin-triplet supercurrent in ferromagnetic Josephson junctions

    Science.gov (United States)

    Wang, Yixing; Pratt, W. P., Jr.; Birge, Norman O.

    2012-12-01

    In 2010, several experimental groups obtained compelling evidence for spin-triplet supercurrent in Josephson junctions containing strong ferromagnetic materials. Our own best results were obtained from large-area junctions containing a thick central Co/Ru/Co “synthetic antiferromagnet” and two thin outer layers made of Ni or PdNi alloy. Because the ferromagnetic layers in our samples are multi-domain, one would expect the sign of the local current-phase relation inside the junctions to vary randomly as a function of lateral position. Here we report measurements of the area dependence of the critical current in several samples, where we find some evidence for those random sign variations. When the samples are magnetized, however, the critical current becomes clearly proportional to the area, indicating that the current-phase relation has the same sign across the entire area of the junctions.

  5. Particle spectroscopy

    International Nuclear Information System (INIS)

    During the last years, particle spectroscopy has evolved into the spectroscopy of leptons and quarks. This era was initiated in 1974 by the discovery of J/psi mesons, quickly followed by new lepton Tau and finally Ypsilon mesons. In this report, talk is concentrated on one specific old hadrons, namely exotics. The main part is then devoted to the new quarks charm and beauty. As for the exotics, baryonium in its broad and narrow states, dibaryons, and exotic quantum numbers are described. There is no firm evidence for exotic quantum numbers so far. Consequently, both experiments and theory have to be improved. Next, new quark spectroscopy is described on quark charge, charm (charmonium, charm particles, F mesons), and beauty. Description of the beauty is further divided into Ypsilon parameters, event topology, quark jets, change of topology at the Ypsilon, other properties of events in the Ypsilon region, Ypsilon summary, and Ypsilon prime. As seen above, in addition to the charm quark, there is now ample evidence for the existence of a new heavy quark which is most probably of the 'beauty' type. To answer the question whether a 6th quark t would constitute perfect symmetry between leptons and quarks, again the answer can now only be: PETRA works and CESR and PEP will follow soon. (Wakatsuki, Y.)

  6. Tsallis q-triplet and Stock Market Indices: The cases of S & P 500 and TVIX

    Directory of Open Access Journals (Sweden)

    A. C. Iliopoulos

    2015-01-01

    Full Text Available In this study we present results of the evaluation of q − triplet of Tsallis non-extensive statistics concerning two time stock market time series, Standart & Poor’s 500 (S & P 500 and TVIX. The analysis of the results, support the hypothesis in which economic dynamics from physical point of view correspond to far from equilibrium spatial distributed non-linear dynamics. In particular, the analysis of the stock market time series revealed underlying complex dynamics, indicating clearly that the statistics of the dynamics in the multifractal phase space can be described by Tsallis distribution functions of power law and heavy tails forms. The non-extensive character of the underlying dynamics is related to the existence of long range interactions in space and time, as well as the interaction in many scales. In addition, the detailed analysis of S & P index unraveled the existence of non-equilibrium phase transitions depicted clearly in the variations of Tsallis q-triplet values. These phase transitions are connected with non-equilibrium stationary states of economical dynamics derived from processes of strong self organization which correspond to local maxima of Tsallis entropy, while the changes in the control parameters can induce new phase transitions and shifts to new metaequilibrium steady states of maximizing Tsallis entropy. These phase transitions lead to changes in Tsallis qtriplet values which correspond to multi-fractal changes in the formation of the phase state and an alteration in the phenomenology of the economical system. Finally, these characteristics also indicate the existence of fractional dynamics in the phase space which can be described through fractional Fokker-Planck equations and anomalous diffusion equations. The solutions of these equations are fractional spatiotemporal functions and non-Gaussian distributions functions which fall into the category of Levy distributions and Tsallis distributions.

  7. Laser spectroscopy

    CERN Document Server

    Demtröder, Wolfgang

    2008-01-01

    Keeping abreast of the latest techniques and applications, this new edition of the standard reference and graduate text on laser spectroscopy has been completely revised and expanded. While the general concept is unchanged, the new edition features a broad array of new material, e.g., frequency doubling in external cavities, reliable cw-parametric oscillators, tunable narrow-band UV sources, more sensitive detection techniques, tunable femtosecond and sub-femtosecond lasers (X-ray region and the attosecond range), control of atomic and molecular excitations, frequency combs able to synchronize independent femtosecond lasers, coherent matter waves, and still more applications in chemical analysis, medical diagnostics, and engineering.

  8. NMR spectroscopy

    International Nuclear Information System (INIS)

    The book reviews the applications of NMR-spectroscopy in medicine and biology. The first chapter of about 40 pages summarizes the history of development and explains the chemical and physical fundamentals of this new and non-invasive method in an easily comprehensible manner. The other chapters summarize diagnostic results obtained with this method in organs and tissues, so that the reader will find a systematic overview of the available findings obtained in the various organ systems. It must be noted, however, that ongoing research work and new insight quite naturally will necessitate corrections to be done, as is the case here with some biochemical interpretations which would need adjustment to latest research results. NMR-spectroscopy is able to measure very fine energy differences on the molecular level, and thus offers insight into metabolic processes, with the advantage that there is no need of applying ionizing radiation in order to qualitatively or quantitatively analyse the metabolic processes in the various organ systems. (orig./DG) With 40 figs., 4 tabs

  9. Simultaneous improvement of emission color, singlet-triplet energy gap, and quantum efficiency of blue thermally activated delayed fluorescent emitters using a 1-carbazolylcarbazole based donor.

    Science.gov (United States)

    Kim, Mounggon; Choi, Jeong Min; Lee, Jun Yeob

    2016-08-21

    Blue thermally activated delayed fluorescent (TADF) emitters having 1-carbazolylcarbazole based donor moieties were developed to resolve the low quantum efficiency and large singlet-triplet energy splitting issues of the linker free TADF emitters. Investigation of the 1-carbazolylcarbazole derived donors as the donor units of two blue TADF emitters in comparison with 3-carbazolylcarbazole demonstrated that the 1-carbazolylcarbazole based donors increased the triplet energy, decreased the singlet-triplet energy gap, blue-shifted the emission color, and enhanced the quantum efficiency of the blue TADF devices. PMID:27443818

  10. Amplitude control of spin-triplet supercurrent in superconductor/ferromagnet/superconductor Josephson junctions

    Science.gov (United States)

    Martinez, William M.

    When a conventional superconductor (S) is placed in contact with a ferromagnet (F), the decay length of the pair correlations in the ferromagnet is very short, on the order of a nm in a strong ferromagnet such as Co or Fe. This is due to the spin-polarized nature of the ferromagnet, whereas the spins of Cooper pairs in a conventional superconductor are anti-aligned in a spin-singlet state. However, in 2001, theorists predicted that long-range pair correlations in a spin-triplet state could be generated through magnetic inhomogeneity. With parallel spins, the decay length of these correlations extends in principle to that of a superconductor-normal metal system, which can be on the order of a micron at sufficiently low temperature. This effect has been observed experimentally by several groups, commonly through the use of extrinsic magnetic inhomogeneity in samples with multiple magnetic layers. Josephson junction measurements have demonstrated critical currents orders of magnitude larger in samples with this inhomogeneity compared to samples without. However, the ability to reliably control the spin-state of the pair correlations in a single sample has yet to be realized. The goal of this work is to perform measurements on Josephson junctions in which the inhomogeneity can be manipulated. Our approach is to fabricate S/F'/F/F"/S Josephson junctions where we can control the relative magnetization orientations of all three ferromagnetic layers. In order to realize this control, we first had to perform studies to characterize various magnetic materials, most notably a NiFe alloy similar to Permalloy and Co/Ru/Co, a synthetic antiferromagnet. Studies of the NiFe have demonstrated its ability to be used as a spin-triplet generator. Measurements have also been taken of NiFe films to determine how easily its magnetization direction can be rotated in an external field. We have also measured the magnetic hardness of Co/Ru/Co synthetic antiferromagnets as a function of the

  11. Hematite ``Blueberry`` Concretion Doublet and Triplets on Mars: Iron Oxide Twin Analogs From Utah

    Science.gov (United States)

    Chan, M. A.; Parry, W. T.; Park, A. S.

    2005-12-01

    Spherical concretions on Earth and Mars comprise a record of diagenetic history that may not otherwise be preserved in the more common host rock. Hematite spherules of Meridiani Planum show some joined forms of twos and threes. Joined iron oxide concretions making doublets and triplets also occur in the Jurassic Navajo Sandstone of southern Utah, and can serve as an analog to understanding why joined forms occur on Mars. The geometries of in situ Utah examples suggest two processes for creating connected forms. In one concretion growth mechanism, occasional coalescing of single forms may result from the growth of doublets or triplets in overly close proximity (typically less than 15% of a population). Joined concretions of roughly equal sizes can be aligned in a row; unequal size concretions take on the shapes of ``snowmen``, or attached ``satellites``. Where cementation is pervasive, individual concretions may grow and coalesce into a lumpy layer or cemented mass along preferential flow paths or preferential nucleation sites. In the second mechanism, nearly all (more than 75%) of the concretions form doublets that are conjoined. The occurrence of dominant twins indicates that these concretions are not coincidental as in the first mechanism. Dominant twin concretions occur regularly and evenly throughout fairly homogeneous host rock. More unusual twins show additional small twin warts suggesting duplicated nucleation and precipitation. Normally, iron oxide concretion precipitation begins when the oxide saturation reaches a precipitation threshold. Precipitation produces chemical gradients, and competition between reaction and diffusion rates determines the spacing between concretions. These factors in combination with reactant supply, competitive growth phenomena and a complex self-organizing processes may contribute to development of internal structure with varying layers of iron-depleted zones to resistant iron-cemented shells. The pervasive nature of sandstone

  12. Moessbauer spectroscopy

    International Nuclear Information System (INIS)

    The emission and absorption of photons taking place without changes in the frequency spectrum of the crystal lattice are known as the Moessbauer effect. It takes place in the low energy levels of heavy nuclei in solid lattices at low temperatures. On the basis of the hyperfine structure of Moessbauer spectra the notions are explained of isomer shift, quadrupole splitting and magnetic splitting. The principle and function are explained of Moessbauer spectrometers and the methods of graphical processing of spectra, also the use of the least square fit. Moessbauer spectroscopy is nondestructive, highly sensitive and selective and makes structural resolution possible. It is used for quantitative and qualitative analysis of compounds. Examples are given of the use of this method for mineralogical and crystallo-chemical analysis of lunar minerals and rocks, for analysis of corrosion products of iron and for phase analysis of alloys. (M.D.)

  13. Continuous Stochastic Neutron Transport for Pure-Triplet Scattering in Semi-Infinite Media using Gaussian Statistics

    International Nuclear Information System (INIS)

    The stationary solution of the one-speed neutron transport equation in a semi infinite stochastic medium with pure-triplet scattering is considered. The cross section function of the medium is assumed to be a continuous random function of position, with fluctuations about the mean taken as Gaussian distributed. The joint probability distribution function of these Gaussian random variables is used to calculate the ensemble-averaged solution for an arbitrary correlation function. The problem is solved at first in the deterministic case, then the solution is averaged using Gaussian joint probability distribution function. Numerical results are given for the radiant neutron energy and net neutron flux. Keywords: Neutron transport, Stochastic media, Gaussian statistics, Pure triplet scattering

  14. Effect of Triplet Harvesting on the Lifetime Based on Fluorescence and Phosphorescence in Hybrid White Organic Light Emitting Diodes.

    Science.gov (United States)

    Lee, Eun; Lee, Ho Won; Yang, Hyung Jin; Sun, Yong; Lee, Jae Woo; Hwang, Kyo Min; Kim, Woo Young; Kim, Young Kwan

    2016-03-01

    We investigated efficient hybrid white organic light emitting diodes (WOLEDs) apply to triplet harvesting (TH) concept based on three complementary colors by mixing containing blue fluorescent emitter with phosphorescent emitters. The TH is to transfer these triplet excitons from a fluorescence to a phosphorescence, where they can decay radiatively. We fabricated several hybrid WOLEDs, having various emitting layer structures with blue fluorescent emitter and red, green phosphorescent emitter. The WOLED exhibited maximum luminous efficiency of 9.02 cd/A, and a maximum external quantum efficiency of 4.17%. The WOLED showed a highly color-stable white emission with the Commission International de L'Éclairage chromaticity of (0.38, 0.36) at 1,000 cd/m2. PMID:27455693

  15. Strongly frustrated triangular spin lattice emerging from triplet dimer formation in honeycomb Li2IrO3

    Science.gov (United States)

    Nishimoto, Satoshi; Katukuri, Vamshi M.; Yushankhai, Viktor; Stoll, Hermann; Rößler, Ulrich K.; Hozoi, Liviu; Rousochatzakis, Ioannis; van den Brink, Jeroen

    2016-01-01

    Iridium oxides with a honeycomb lattice have been identified as platforms for the much anticipated Kitaev topological spin liquid: the spin-orbit entangled states of Ir4+ in principle generate precisely the required type of anisotropic exchange. However, other magnetic couplings can drive the system away from the spin-liquid phase. With this in mind, here we disentangle the different magnetic interactions in Li2IrO3, a honeycomb iridate with two crystallographically inequivalent sets of adjacent Ir sites. Our ab initio many-body calculations show that, while both Heisenberg and Kitaev nearest-neighbour couplings are present, on one set of Ir-Ir bonds the former dominates, resulting in the formation of spin-triplet dimers. The triplet dimers frame a strongly frustrated triangular lattice and by exact cluster diagonalization we show that they remain protected in a wide region of the phase diagram.

  16. Unraveling Triplet Excitons Photophysics in Hyper-Cross-Linked Polymeric Nanoparticles: Toward the Next Generation of Solid-State Upconverting Materials.

    Science.gov (United States)

    Monguzzi, Angelo; Mauri, Michele; Frigoli, Michel; Pedrini, Jacopo; Simonutti, Roberto; Larpent, Chantal; Vaccaro, Gianfranco; Sassi, Mauro; Meinardi, Francesco

    2016-07-21

    The technological application of sensitized upconversion based on triplet-triplet annihilation (TTA) requires the transition from systems operating in liquid solutions to solid-state materials. Here, we demonstrate that the high upconversion efficiency reported in hyper-cross-linked nanoparticles does not originate from residual mobility of the embedded dyes as it happens in soft hosts. The hyper-reticulation from one side blocks the dyes in fixed positions, but on the other one, it suppresses the nonradiative spontaneous decay of the triplet excitons, reducing intramolecular relaxations. TTA is thus enabled by an unprecedented extension of the triplet lifetime, which grants long excitons diffusion lengths by hopping among the dye framework and gives rise to high upconversion yield without any molecular displacement. This finding paves the way for the design of a new class of upconverting materials, which in principle can operate at excitation intensities even lower than those requested in liquid or in rubber hosts. PMID:27388582

  17. Synthesis of skeletally diverse alkaloid-like molecules: exploitation of metathesis substrates assembled from triplets of building blocks

    OpenAIRE

    Maurya, Sushil K.; Mark Dow; Stuart Warriner; Adam Nelson

    2013-01-01

    A range of metathesis substrates was assembled from triplets of unsaturated building blocks. The approach involved the iterative attachment of a propagating and a terminating building block to a fluorous-tagged initiating building block. Metathesis cascade chemistry was used to “reprogram” the molecular scaffolds. Remarkably, in one case, a cyclopropanation reaction competed with the expected metathesis cascade process. Finally, it was demonstrated that the metathesis products could be deriva...

  18. Protecting the primordial baryon asymmetry in the SU(2)L triplet Higgs model compatible with KamLAND and WMAP

    International Nuclear Information System (INIS)

    We find the condition that the primordial baryon asymmetry is not washed out in the SU(2)L triplet Higgs model by solving the Boltzmann equation. We further require that the model is compatible with the recent results of the neutrino oscillation experiments and the Wilkinson Microwave Anisotropy Probe, and the constraints on the ρ parameter imposed by the CERN LEP. We finally obtain the allowed region of the parameters in the model

  19. Interband coulomb interaction and horizontal line nodes in triplet superconductor Sr sub 2 RuO sub 4

    CERN Document Server

    Hasegawa, Y

    2003-01-01

    A possible mechanism for appearance of the horizontal line nodes in triplet superconductor, Sr sub 2 RuO sub 4 , is proposed. We consider the interlayer Coulomb interaction, as well as the on-site Coulomb repulsion, between electrons in different bands. In the second order perturbation of the interband interaction, the effective interaction becomes dependent on cos q sub z /2, resulting in horizontal line nodes. (author)

  20. Energy Landscapes of Dynamic Ensembles of Rolling Triplet Repeat Bulge Loops: Implications for DNA Expansion Associated with Disease States

    OpenAIRE

    Völker, Jens; Gindikin, Vera; Klump, Horst H.; Plum, G. Eric; Breslauer, Kenneth J.

    2012-01-01

    DNA repeat domains can form ensembles of canonical and noncanonical states, including stable and metastable DNA secondary structures. Such sequence-induced structural diversity creates complex conformational landscapes for DNA processing pathways, including those triplet expansion events that accompany replication, recombination, and/or repair. Here we demonstrate further levels of conformational complexity within repeat domains. Specifically, we show that bulge loop structures within an exte...

  1. Accurate luminosities from the oxygen 7771-4 A triplet and the fundamental parameters of F-G supergiants

    OpenAIRE

    Kovtyukh, V. V.; Gorlova, N.; Belik, S. I.

    2012-01-01

    The oxygen 7771-4 A triplet is a good indicator of luminosity in A-G supergiants. However, its strength also depends on other atmospheric parameters. In this study, we present the luminosity calibrations, where, for the first time, the effects of the effective temperature, microturbulent velocity, surface gravity, and the abundance have been disentangled. The calibrations are derived on the basis of a dataset of high-dispersion spectra of 60 yellow supergiants with highly reliable luminositie...

  2. Protecting the primordial baryon asymmetry in the $SU(2)_{L}$ triplet Higgs model compatible with KamLAND and WMAP

    OpenAIRE

    Hasegawa, K

    2004-01-01

    We find the condition that the primordial baryon asymmetry is not washed out in the $SU(2)_{L}$ triplet Higgs model by solving the Boltzmann equation. We further require that the model is compatible with the recent results of the neutrino oscillation experiments and WMAP, and the constraints on the $\\rho$ parameter imposed by the LEP. We finally obtain the allowed region of the parameters in the model.

  3. Photochemical reaction of triplet 9,10-anthraquinone with ethylbenzene in the presence of DPPH as a radical trapping agent

    International Nuclear Information System (INIS)

    DPPH was used as a scavenger of α-phenyl-ethyl radicals produced in the photochemical reaction between triplet anthraquinone (Qsup(T)) and ethylbenzene (RH2) in benzene solutions. The rate constant ratio ksub(2)/ksub(-1) was determined from the measurements of the quantum yield of scavenging against (RH2) and found to be (0.49+-0.015) M at 25 deg C. (author)

  4. LHC diphoton and Z+photon Higgs signals in the Higgs triplet model with Y = 0

    International Nuclear Information System (INIS)

    We study the implications of the LHC diphoton and Z+photon Higgs signals on the Higgs triplet model with Y=0, which predicts two neutral CP-even Higgs bosons h, H and a pair of charged Higgs H±. We discuss three different scenarios: (i) the observed boson is the light Higgs boson h; (ii) it is the heavy Higgs boson H; (iii) the observed signal is from the almost degenerate h and H. We find that the inclusive Higgs diphoton rates in the first two scenarios can be enhanced or suppressed compared to the SM value, which can respectively fit the ATLAS and CMS diphoton data within 1σ range. The inclusive ZZ∗ rates are suppressed, which are outside 1σ range of ATLAS data and within 1σ range of CMS data. Meanwhile, another CP-even Higgs boson production rate can be suppressed enough not to be observed at the collider. For the third scenario, the Higgs diphoton rate is suppressed, which is outside 1σ range of ATLAS data, and the ZZ∗ rate equals to SM value approximately. In addition, we find that the two rates of h→γγ and h→Zγ have the positive correlations for the three scenarios

  5. Experimental triplet and quadruplet fluctuation densities and spatial distribution function integrals for pure liquids

    Energy Technology Data Exchange (ETDEWEB)

    Ploetz, Elizabeth A.; Karunaweera, Sadish; Smith, Paul E. [Department of Chemistry, Kansas State University, 213 CBC Building, Manhattan, Kansas 66506 (United States)

    2015-01-28

    Fluctuation solution theory has provided an alternative view of many liquid mixture properties in terms of particle number fluctuations. The particle number fluctuations can also be related to integrals of the corresponding two body distribution functions between molecular pairs in order to provide a more physical picture of solution behavior and molecule affinities. Here, we extend this type of approach to provide expressions for higher order triplet and quadruplet fluctuations, and thereby integrals over the corresponding distribution functions, all of which can be obtained from available experimental thermodynamic data. The fluctuations and integrals are then determined using the International Association for the Properties of Water and Steam Formulation 1995 (IAPWS-95) equation of state for the liquid phase of pure water. The results indicate small, but significant, deviations from a Gaussian distribution for the molecules in this system. The pressure and temperature dependence of the fluctuations and integrals, as well as the limiting behavior as one approaches both the triple point and the critical point, are also examined.

  6. Potential energy surface of triplet N{sub 2}O{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Varga, Zoltan; Meana-Pañeda, Rubén; Song, Guoliang; Paukku, Yuliya; Truhlar, Donald G., E-mail: truhlar@umn.edu [Department of Chemistry, Chemical Theory Center, and Supercomputing Institute, University of Minnesota, Minneapolis, Minnesota 55455-0431 (United States)

    2016-01-14

    We present a global ground-state triplet potential energy surface for the N{sub 2}O{sub 2} system that is suitable for treating high-energy vibrational-rotational energy transfer and collision-induced dissociation. The surface is based on multi-state complete-active-space second-order perturbation theory/minimally augmented correlation-consistent polarized valence triple-zeta electronic structure calculations plus dynamically scaled external correlation. In the multireference calculations, the active space has 14 electrons in 12 orbitals. The calculations cover nine arrangements corresponding to dissociative diatom-diatom collisions of N{sub 2}, O{sub 2}, and nitric oxide (NO), the interaction of a triatomic molecule (N{sub 2}O and NO{sub 2}) with the fourth atom, and the interaction of a diatomic molecule with a single atom (i.e., the triatomic subsystems). The global ground-state potential energy surface was obtained by fitting the many-body interaction to 54 889 electronic structure data points with a fitting function that is a permutationally invariant polynomial in terms of bond-order functions of the six interatomic distances.

  7. Constraining Proton Lifetime in SO(10) with Stabilized Doublet-Triplet Splitting

    Energy Technology Data Exchange (ETDEWEB)

    Babu, K.S.; /Oklahoma State U.; Pati, Jogesh C.; /SLAC; Tavartkiladze, Zurab; /Oklahoma State U. /Tbilisi, Inst. Phys.

    2011-06-28

    We present a class of realistic unified models based on supersymmetric SO(10) wherein issues related to natural doublet-triplet (DT) splitting are fully resolved. Using a minimal set of low dimensional Higgs fields which includes a single adjoint, we show that the Dimopoulos-Wilzcek mechanism for DT splitting can be made stable in the presence of all higher order operators without having pseudo-Goldstone bosons and flat directions. The {mu} term of order TeV is found to be naturally induced. A Z{sub 2}-assisted anomalous U(1){sub A} gauge symmetry plays a crucial role in achieving these results. The threshold corrections to {alpha}{sub 3}(M{sub Z}), somewhat surprisingly, are found to be controlled by only a few effective parameters. This leads to a very predictive scenario for proton decay. As a novel feature, we find an interesting correlation between the d = 6 (p {yields} e{sup +}{pi}{sup 0}) and d = 5 (p {yields} {bar {nu}}K{sup +}) decay amplitudes which allows us to derive a constrained upper limit on the inverse rate of the e{sup +}{pi}{sup 0} mode. Our results show that both modes should be observed with an improvement in the current sensitivity by about a factor of five to ten.

  8. Spin-triplet electron transport in hybrid superconductor heterostructures with a composite ferromagnetic interlayer

    Energy Technology Data Exchange (ETDEWEB)

    Sheyerman, A. E., E-mail: karen@hitech.cplire.ru; Constantinian, K. Y.; Ovsyannikov, G. A.; Kislinskii, Yu. V.; Shadrin, A. V. [Russian Academy of Sciences, Kotelnikov Institute of Radio Engineering and Electronics (Russian Federation); Kalabukhov, A. V. [Chalmers University of Technology (Sweden); Khaydukov, Yu. N. [Max-Planck Institute for Solid State Research (Germany)

    2015-06-15

    Hybrid YBa{sub 2}Cu{sub 3}O{sub 7−x}/SrRuO{sub 3}/La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/Au-Nb superconductor mesastructures with a composite manganite-ruthenate ferromagnetic interlayer are studied using electrophysical, magnetic, and microwave methods. The supercurrent in the mesastructure is observed when the interlayer thickness is much larger than the coherence length of ferromagnetic materials. The peak on the dependence of the critical current density on the interlayer material thickness corresponds to the coherence length, which is in qualitative agreement with theoretical predictions for a system with spit-triplet superconducting correlations. The magnetic-field dependence of the critical current is determined by penetration of magnetic flux quanta and by the magnetic domain structure, as well as by the field dependence of disorientation of the magnetization vectors of the layers in the composite magnetic interlayer. It is found that the supercurrent exists in magnetic fields two orders of magnitude stronger than the field corresponding to entry of a magnetic flux quantum into the mesastructure. The current-phase relation (CPR) of the supercurrent of mesastructures is investigated upon a change in the magnetic field from zero to 30 Oe; the ratio of the second CPR harmonic to the first, determined from the dependence of the Shapiro steps on the microwave radiation amplitude, does not exceed 50%.

  9. Triplet singlet spin communication between DNA nucleotides serves the basis for quantum computing

    Science.gov (United States)

    Tulub, Alexander A.; Stefanov, Vassily E.

    2007-02-01

    The nature of spin communication between DNA nucleotide pairs is discussed. The results are based on CIU (2 × 10 6 configurations, 6-311G ∗∗ basis set) quantum chemistry computations at a constant temperature T = 310 K of complementary nucleotide pairs, guanosine-cytidine (G-C) and adenosine-thymidine (A-T) monophosphates, assembled into DNA fragments of different length. Calculations reveal alternation of low energy triplet-singlet (T-S) potential energy surfaces (PESs), assigned to individual nucleotides. In a narrow energy interval these PESs approach, showing repulsion and uncommon crossings. Complementary nucleotide pairing, a result of Watson-Crick hydrogen bonding, produces a global minimum in total energy, coming from the unique crossing between two singlet by nature PESs strictly around 310 K. Interaction between non-complementary nucleotides reveals no minima and points rather to system destabilization. Computations show that regularly organized DNA is a structure of similarly oriented spins along each of its two chains, so that the resultant spin of the whole structure is equal to zero. Disordering in spin structure produces coherent effects, appearing in spin flipping, which serves the basis for constructing DNA-based quantum computing.

  10. Experimental triplet and quadruplet fluctuation densities and spatial distribution function integrals for pure liquids.

    Science.gov (United States)

    Ploetz, Elizabeth A; Karunaweera, Sadish; Smith, Paul E

    2015-01-28

    Fluctuation solution theory has provided an alternative view of many liquid mixture properties in terms of particle number fluctuations. The particle number fluctuations can also be related to integrals of the corresponding two body distribution functions between molecular pairs in order to provide a more physical picture of solution behavior and molecule affinities. Here, we extend this type of approach to provide expressions for higher order triplet and quadruplet fluctuations, and thereby integrals over the corresponding distribution functions, all of which can be obtained from available experimental thermodynamic data. The fluctuations and integrals are then determined using the International Association for the Properties of Water and Steam Formulation 1995 (IAPWS-95) equation of state for the liquid phase of pure water. The results indicate small, but significant, deviations from a Gaussian distribution for the molecules in this system. The pressure and temperature dependence of the fluctuations and integrals, as well as the limiting behavior as one approaches both the triple point and the critical point, are also examined. PMID:25637990

  11. Walking Down the Chalcogenic Group of the Periodic Table: From Singlet to Triplet Organic Emitters.

    Science.gov (United States)

    Kremer, Adrian; Aurisicchio, Claudia; De Leo, Federica; Ventura, Barbara; Wouters, Johan; Armaroli, Nicola; Barbieri, Andrea; Bonifazi, Davide

    2015-10-19

    The synthesis, X-ray crystal structures, ground- and excited-state UV/Vis absorption spectra, and luminescence properties of chalcogen-doped organic emitters equipped on both extremities with benzoxa-, benzothia-, benzoselena- and benzotellurazole (1X and 2X ) moieties have been reported for the first time. The insertion of the four different chalcogen atoms within the same molecular skeleton enables the investigation of only the chalcogenic effect on the organisation and photophysical properties of the material. Detailed crystal-structure analyses provide evidence of similar packing for 2O -2Se , in which the benzoazoles are engaged in π-π stacking and, for the heavier atoms, in secondary X⋅⋅⋅X and X⋅⋅⋅N bonding interactions. Detailed computational analysis shows that the arrangement is essentially governed by the interplay of van der Waals and secondary bonding interactions. Progressive quenching of the fluorescence and concomitant onset of phosphorescence features with gradually shorter lifetimes are detected as the atomic weight of the chalcogen heteroatom increases, with the tellurium-doped derivatives exhibiting only emission from the lowest triplet excited state. Notably, the phosphorescence spectra of the selenium and tellurium derivatives can be recorded even at room temperature; this is a very rare finding for fully organic emitters. PMID:26471446

  12. Field quality of the LHC inner triplet quadrupoles being fabricated at Fermilab

    Energy Technology Data Exchange (ETDEWEB)

    Gueorgui V. Velev et al.

    2003-06-02

    Fermilab, as part of the US-LHC Accelerator Project, has designed and is producing superconducting low-beta quadrupole magnets for the Large Hadron Collider (LHC). These 70 mm bore, 5.5 m long magnets operate in superfluid helium at 1.9 K with a maximum operating gradient of 214 T/m. Two quadrupoles, combined with a dipole orbit corrector, form a single LQXB cryogenic assembly, the Q2 optical element of the final focus triplets in the LHC interaction regions. Field quality was measured at room temperature during fabrication of the cold masses as well as at superfluid helium temperature in two thermal cycles for the first LQXB cryogenic assembly. Integral cold measurements were made with a 7.1 m long rotating coil and with a 0.8 m long rotating coil at 8 axial positions and in a range of currents. In addition to the magnetic measurements, this paper reports on the quench performance of the cold masses and on the measurements of their internal alignment.

  13. Optimization of Triplet Quadrupoles Field Quality for the LHC High Luminosity Lattice at Collision Energy

    CERN Document Server

    Nosochkov, Y; Wang, MH; Fartoukh, S; Giovannozzi, M; de Maria, R; McIntosh, E

    2013-01-01

    Beta functions at two interaction points (IP) in the high luminosity LHC upgrade lattice (HL-LHC) at collision energy will be significantly reduced compared to the nominal LHC lattice. This will result in much higher beta functions in the inner triplet (IT) quadrupoles adjacent to these IPs. The consequences are a larger beam size in these quadrupoles, higher IT chromaticity, and stronger effects of the IT field errors on dynamic aperture (DA). The IT chromaticity will be compensated using the Achromatic Telescopic Squeezing scheme [1]. The increased IT beam size will be accommodated by installing large aperture Nb3Sn superconducting quadrupoles with 150 mm coil diameter. The stronger effects of the IT field errors can be remedied by optimizing the IT field error specifications. The latter must satisfy two conditions: provide an acceptable DA and be compatible with realistically achievable field quality. Optimization of the IT field errors was performed for the LHC upgrade layout version SLHCV3.01 with IT gra...

  14. Search for double charmonium decays of the P-wave spin-triplet bottomonium states

    CERN Document Server

    Shen, C P; Iijima, T

    2012-01-01

    Using a sample of 158 million $\\Upsilon(2S)$ events collected with the Belle detector, we search for the first time for double charmonium decays of the $P$-wave spin-triplet bottomonium states ($\\Upsilon(2S) \\to \\gamma \\chi_{bJ}$, $\\chi_{bJ} \\to \\jpsi \\jpsi$, $\\jpsi \\psp$, $\\psp \\psp$ for J=0, 1, and 2). No significant $\\chi_{bJ}$ signal is observed in the double charmonium mass spectra, and we obtain the following upper limits, $\\BR(\\chi_{bJ} \\to \\jpsi \\jpsi)<7.1\\times 10^{-5}$, $2.7\\times 10^{-5}$, $4.5\\times 10^{-5}$, $\\BR(\\chi_{bJ} \\to \\jpsi \\psp)<1.2\\times 10^{-4}$, $1.7\\times 10^{-5}$, $4.9\\times 10^{-5}$, $\\BR(\\chi_{bJ} \\to \\psp \\psp)<3.1\\times 10^{-5}$, $6.2\\times 10^{-5}$, $1.6\\times 10^{-5}$ for J=0, 1, and 2, respectively, at the 90% confidence level. These limits are significantly lower than the central values (with uncertainties of 50% to 70%) predicted using the light cone formalism but are consistent with calculations using the NRQCD factorization approach.

  15. Spin-triplet electron transport in hybrid superconductor heterostructures with a composite ferromagnetic interlayer

    Science.gov (United States)

    Sheyerman, A. E.; Constantinian, K. Y.; Ovsyannikov, G. A.; Kislinskii, Yu. V.; Shadrin, A. V.; Kalabukhov, A. V.; Khaydukov, Yu. N.

    2015-06-01

    Hybrid YBa2Cu3O7 - x /SrRuO3/La0.7Sr0.3MnO3/Au-Nb superconductor mesastructures with a composite manganite-ruthenate ferromagnetic interlayer are studied using electrophysical, magnetic, and microwave methods. The supercurrent in the mesastructure is observed when the interlayer thickness is much larger than the coherence length of ferromagnetic materials. The peak on the dependence of the critical current density on the interlayer material thickness corresponds to the coherence length, which is in qualitative agreement with theoretical predictions for a system with spit-triplet superconducting correlations. The magnetic-field dependence of the critical current is determined by penetration of magnetic flux quanta and by the magnetic domain structure, as well as by the field dependence of disorientation of the magnetization vectors of the layers in the composite magnetic interlayer. It is found that the supercurrent exists in magnetic fields two orders of magnitude stronger than the field corresponding to entry of a magnetic flux quantum into the mesastructure. The current-phase relation (CPR) of the supercurrent of mesastructures is investigated upon a change in the magnetic field from zero to 30 Oe; the ratio of the second CPR harmonic to the first, determined from the dependence of the Shapiro steps on the microwave radiation amplitude, does not exceed 50%.

  16. Spin-triplet electron transport in hybrid superconductor heterostructures with a composite ferromagnetic interlayer

    International Nuclear Information System (INIS)

    Hybrid YBa2Cu3O7−x/SrRuO3/La0.7Sr0.3MnO3/Au-Nb superconductor mesastructures with a composite manganite-ruthenate ferromagnetic interlayer are studied using electrophysical, magnetic, and microwave methods. The supercurrent in the mesastructure is observed when the interlayer thickness is much larger than the coherence length of ferromagnetic materials. The peak on the dependence of the critical current density on the interlayer material thickness corresponds to the coherence length, which is in qualitative agreement with theoretical predictions for a system with spit-triplet superconducting correlations. The magnetic-field dependence of the critical current is determined by penetration of magnetic flux quanta and by the magnetic domain structure, as well as by the field dependence of disorientation of the magnetization vectors of the layers in the composite magnetic interlayer. It is found that the supercurrent exists in magnetic fields two orders of magnitude stronger than the field corresponding to entry of a magnetic flux quantum into the mesastructure. The current-phase relation (CPR) of the supercurrent of mesastructures is investigated upon a change in the magnetic field from zero to 30 Oe; the ratio of the second CPR harmonic to the first, determined from the dependence of the Shapiro steps on the microwave radiation amplitude, does not exceed 50%

  17. A fluorescence detected magnetic resonance investigation of the carotenoid triplet states associated with Photosystem II of isolated spinach thylakoid membranes

    CERN Document Server

    Santabarbara, S; Carbonera, D; Heathcote, P

    2005-01-01

    The carotenoid triplet populations associated with the fluorescence emission chlorophyll forms of Photosystem II have been investigated in isolated spinach thylakoid membranes by means of fluorescence detected magnetic resonance in zero field (FDMR). The spectra collected in the 680-690 nm emission range, have been fitted by a global analysis procedure. At least five different carotenoid triplet states coupled to the terminal emitting chlorophyll forms of PS II, peaking at 682 nm, 687 nm and 692 nm, have been characterised. The triplets associated with the outer antenna emission forms, at 682 nm, have zero field splitting parameters D = 0.0385 cm/sup -1/, E = 0.00367 cm/sup -1/; D = 0.0404 cm/sup -1/, E = 0.00379 cm/sup -1/ and D = 0.0386 cm/sup -1/, E = 0.00406 cm/sup -1/ which are very similar to those previously reported for the xanthophylls of the isolated LHC II complex. Therefore the FDMR spectra recorded in this work provide insights into the organisation of the LHC II complex in the unperturbed enviro...

  18. A spectroscopic and computational study of the singlet and triplet excited states of synthetic β-functionalized chlorins

    Science.gov (United States)

    Brückner, Christian; McCarthy, Jason R.; Daniell, Heather W.; Pendon, Zeus D.; Ilagan, Robielyn P.; Francis, Tasha M.; Ren, Lei; Birge, Robert R.; Frank, Harry A.

    2003-11-01

    This paper presents a comparative investigation of the absorption, fluorescence, electron paramagnetic resonance (EPR), and transient triplet-triplet absorption spectroscopic properties and triplet state dynamics of two functionalized, synthetic, meso-phenylchlorins. The chromophores investigated are the novel 2-hydroxy-3-oxa-5,10,15,20-tetrakisphenylchlorin ( 3) and the known 2,3-dioxo-5,10,15,20-tetrakisphenylchlorin ( 4). In these chromophores, one peripheral CHCH bond of the parent porphyrin meso-tetrakisphenylporphyrin (TPP, 1) was formally replaced by a CH(OH)O (lactol) or a β-diketone moiety. The spectroscopic data are compared with results from investigations on the parent porphyrin TPP studied here and the parent chlorin 5,10,15,20-tetrakisphenylchlorin (TPC, 2) from the literature. The spectroscopic observables are examined both qualitatively within the framework of the four orbital model and quantitatively using MNDO-PSDCI methods. The results delineate the role of β-lactol and β-dicarbonyl moieties in controlling the electronic and spectroscopic properties of these chromophores. This investigation serves as the foundation from which to derive a general understanding of the effects of β-functionalization on the electronic properties of chlorin-type chromophores. This knowledge is required for the design and understanding of long-wavelength absorbing and fluorescing chromophores to be used in light harvesting systems and photomedicine.

  19. Physics design of Quadrupole magnet triplet between IH LINAC 4 and 5 for VECC RIB accelerator project

    International Nuclear Information System (INIS)

    An ISOL post-accelerator type of RIB facility is being developed at VECC. The post-acceleration scheme consists of RFQ, five IH LINACs and eight superconducting Quarter wave resonators (QWRs) along with other focusing and beam line elements. The final energy at the end of the complete acceleration scheme will be 2 MeV/u. This report presents the physics design of a quadrupole magnet triplet to be placed in between IH LINAC 4 and 5 for transverse focusing and acceptance matching. The 2-d design of this magnet triplet has been completed. Stringent dimension criteria along with lack of sufficient intertank space and need of very high magnetic field gradient make this design process quite challenging. The magnetic field gradient obtained from this design is about 6920 G/cm which is quite close to the value obtained from beam dynamics study. The field gradient uniformity is about 0.22% up to 60% of the magnet aperture. The outer diameter of the magnet has been kept only at 260 mm to cope well with the stringent transverse dimension requirement. The 2-d and 3-d design of this magnet triplet will be presented in this report. (author)

  20. Spin-Triplet Pairing State of Sr2RuO4 in the c-Axis Magnetic Field

    Science.gov (United States)

    Takamatsu, Shuhei; Yanase, Youichi

    2013-06-01

    We investigate the spin-triplet superconducting state of Sr2RuO4 in the magnetic field along the c-axis on the basis of the four-component Ginzburg--Landau (GL) model with a weak spin--orbit coupling. We consider superconducting states described by the d-vector parallel to the ab-plane (\\mbi{d}\\parallel ab), and find that three spin-triplet pairing states are stabilized in the magnetic field--temperature (H--T) phase diagram. Although a helical state is stable at low magnetic fields, a chiral II state is stabilized at high magnetic fields. A non-unitary spin-triplet pairing state appears near the transition temperature owing to the coupling of magnetic field and chirality. We elucidate synergistic and/or competing roles of the magnetic field, chirality, and spin--orbit coupling. It is shown that a fractional vortex lattice is stabilized in the chiral II phase owing to the spin--orbit coupling.