WorldWideScience

Sample records for cadmium base rides

  1. Research on the Effects of Hydropneumatic Parameters on Tracked Vehicle Ride Safety Based on Cosimulation

    Directory of Open Access Journals (Sweden)

    Shousong Han

    2017-01-01

    Full Text Available Ride safety of a tracked vehicle is the key focus of this research. The factors that affect the ride safety of a vehicle are analyzed and evaluation parameters with their criteria are proposed. A multibody cosimulation approach is used to investigate the effects of hydropneumatic parameters on the ride safety and aid with design optimization and tuning of the suspension system. Based on the cosimulation environment, the vehicle multibody dynamics (MBD model and the road model are developed using RecurDyn, which is linked to the hydropneumatic suspension model developed in Lab AMESim. Test verification of a single suspension unit is accomplished and the suspension parameters are implemented within the hydropneumatic model. Virtual tests on a G class road at different speeds are conducted. Effects of the accumulator charge pressure, damping diameter, and the track tensioning pressure on the ride safety are analyzed and quantified. This research shows that low accumulator charge pressure, improper damping diameter, and insufficient track tensioning pressure will deteriorate the ride safety. The results provide useful references for the optimal design and control of the parameters of a hydropneumatic suspension.

  2. Cadmium

    NARCIS (Netherlands)

    Meulenbelt, Jan

    2017-01-01

    Together with zinc and mercury, cadmium belongs to group IIb of the periodic table. It can be found in rocks, soil, water, coal, zinc ore, lead ore, and copper ore. In the environment, cadmium is present predominantly as the oxide or as the chloride, sulfide, or sulfate salt. It has no recognizable

  3. High-Order Sliding Mode Control for DFIG-Based Wind Turbine Fault Ride-Through

    OpenAIRE

    Benbouzid, Mohamed; Beltran, Brice; Amirat, Yassine; Gang, Yao; Jingang, Han; Mangel, Hervé

    2013-01-01

    International audience; This paper deals with the Fault Ride-Through (FRT) capability assessment of a Doubly-Fed Induction Generator (DFIG)-based Wind Turbine (WT) using High-Order Sliding Mode (HOSM) control. Indeed, it has been recently suggested that sliding mode control is a solution of choice to the FRT problem. In this context, this paper proposes HOSM as an improved solution that handle the classical sliding mode chattering problem. Indeed, the main and attractive features of HOSMs are...

  4. Low voltage ride-Through strategy based on virtual synchronous generator control

    Science.gov (United States)

    Guo, L.; Su, J. H.; Yu, L.; Lai, J. D.

    2017-06-01

    Inverters controlled in virtual synchronous generator(VSG) method is able to operate in both grid-connected mode and islanding mode. Due to this characteristic, this paper put forwards a low voltage ride-through(LVRT) strategy which is based on VSG control. If the grid voltage sags, VSG can limit the output current amplitude and meanwhile inject reactive power to the grid. Once the voltage drop time exceeds the maximum ride-through time, VSG would smoothly switch to islanding mode and continues to carry loads independently. The proposed strategy achieves a control algorithm unity between normal operating and grid voltage sag status in grid-connected mode. Simulations can support the validity of the strategy.

  5. RIDES: Robust Intrusion Detection System for IP-Based Ubiquitous Sensor Networks

    Directory of Open Access Journals (Sweden)

    Sungwon Lee

    2009-05-01

    Full Text Available TheIP-based Ubiquitous Sensor Network (IP-USN is an effort to build the “Internet of things”. By utilizing IP for low power networks, we can benefit from existing well established tools and technologies of IP networks. Along with many other unresolved issues, securing IP-USN is of great concern for researchers so that future market satisfaction and demands can be met. Without proper security measures, both reactive and proactive, it is hard to envisage an IP-USN realm. In this paper we present a design of an IDS (Intrusion Detection System called RIDES (Robust Intrusion DEtection System for IP-USN. RIDES is a hybrid intrusion detection system, which incorporates both Signature and Anomaly based intrusion detection components. For signature based intrusion detection this paper only discusses the implementation of distributed pattern matching algorithm with the help of signature-code, a dynamically created attack-signature identifier. Other aspects, such as creation of rules are not discussed. On the other hand, for anomaly based detection we propose a scoring classifier based on the SPC (Statistical Process Control technique called CUSUM charts. We also investigate the settings and their effects on the performance of related parameters for both of the components.

  6. RIDES: Robust Intrusion Detection System for IP-Based Ubiquitous Sensor Networks

    Science.gov (United States)

    Amin, Syed Obaid; Siddiqui, Muhammad Shoaib; Hong, Choong Seon; Lee, Sungwon

    2009-01-01

    The IP-based Ubiquitous Sensor Network (IP-USN) is an effort to build the “Internet of things”. By utilizing IP for low power networks, we can benefit from existing well established tools and technologies of IP networks. Along with many other unresolved issues, securing IP-USN is of great concern for researchers so that future market satisfaction and demands can be met. Without proper security measures, both reactive and proactive, it is hard to envisage an IP-USN realm. In this paper we present a design of an IDS (Intrusion Detection System) called RIDES (Robust Intrusion DEtection System) for IP-USN. RIDES is a hybrid intrusion detection system, which incorporates both Signature and Anomaly based intrusion detection components. For signature based intrusion detection this paper only discusses the implementation of distributed pattern matching algorithm with the help of signature-code, a dynamically created attack-signature identifier. Other aspects, such as creation of rules are not discussed. On the other hand, for anomaly based detection we propose a scoring classifier based on the SPC (Statistical Process Control) technique called CUSUM charts. We also investigate the settings and their effects on the performance of related parameters for both of the components. PMID:22412321

  7. RIDES: Robust Intrusion Detection System for IP-Based Ubiquitous Sensor Networks.

    Science.gov (United States)

    Amin, Syed Obaid; Siddiqui, Muhammad Shoaib; Hong, Choong Seon; Lee, Sungwon

    2009-01-01

    The IP-based Ubiquitous Sensor Network (IP-USN) is an effort to build the "Internet of things". By utilizing IP for low power networks, we can benefit from existing well established tools and technologies of IP networks. Along with many other unresolved issues, securing IP-USN is of great concern for researchers so that future market satisfaction and demands can be met. Without proper security measures, both reactive and proactive, it is hard to envisage an IP-USN realm. In this paper we present a design of an IDS (Intrusion Detection System) called RIDES (Robust Intrusion DEtection System) for IP-USN. RIDES is a hybrid intrusion detection system, which incorporates both Signature and Anomaly based intrusion detection components. For signature based intrusion detection this paper only discusses the implementation of distributed pattern matching algorithm with the help of signature-code, a dynamically created attack-signature identifier. Other aspects, such as creation of rules are not discussed. On the other hand, for anomaly based detection we propose a scoring classifier based on the SPC (Statistical Process Control) technique called CUSUM charts. We also investigate the settings and their effects on the performance of related parameters for both of the components.

  8. Solving the dial-a-ride problem using agent-based simulation

    Directory of Open Access Journals (Sweden)

    Campbell, Ian

    2016-11-01

    Full Text Available The ‘dial-a-ride problem’ (DARP requires a set of customers to be transported by a limited fleet of vehicles between unique origins and destinations under several service constraints, including within defined time windows. The problem is considered NP-hard, and has typically been solved using metaheuristic methods. An agent-based simulation (ABS model was developed, where each vehicle bids to service customers based on a weighted objective function that considers the cost to service the customer and the time quality of the service that would be achieved. The approach applied a pre- processing technique to reduce the search space, given the service time window constraints. Tests of the model showed significantly better customer transit and waiting times than the benchmark datasets. The ABS was able to obtain solutions for much larger problem sizes than the benchmark solutions, with this work being the first known application of ABS to the DARP.

  9. Mechanism of cadmium ion removal by base treated juniper fiber

    Science.gov (United States)

    Soo-Hong Min; J.K. Park; James S. Han; Eun Woo Shin

    2003-01-01

    Pinyon juniper, Juniperus Monosperma, is a small-diameter and underutilized (SDU) lignocellulosic material. Evaluated were efficacy of base-treated juniper fiber (BTJF) sample for cadmium (Cd 2+ ) sorption and the viability of juniper fiber as a sorbent for the removal of Cd 2+ from water. Fourier Transform Infrared Spectroscopy (FTIR) analysis indicated that...

  10. Vision-based measuring system for rider's pose estimation during motorcycle riding

    Science.gov (United States)

    Cheli, F.; Mazzoleni, P.; Pezzola, M.; Ruspini, E.; Zappa, E.

    2013-07-01

    Inertial characteristics of the human body are comparable with the vehicle ones in motorbike riding: the study of a rider's dynamic is a crucial step in system modeling. An innovative vision based system able to measure the six degrees of freedom of the driver with respect to the vehicle is proposed here: the core of the proposed approach is an image acquisition and processing technique capable of reconstructing the position and orientation of a target fixed on the rider's back. The technique is firstly validated in laboratory tests comparing measured and imposed target motion laws and successively tested in a real case scenario during track tests with amateur and professional drivers. The presented results show the capability of the technique to correctly describe the driver's dynamic, his interaction with the vehicle as well as the possibility to use the new measuring technique in the comparison of different driving styles.

  11. Z-Source Inverter Based Power Quality Compensator with Enhanced Ride-Through Capability

    DEFF Research Database (Denmark)

    Gajanayake, C.J.; Vilathgamuwa, D.M.; Loh, P.C.

    2007-01-01

    a Zsource inverter based power quality compensator and a control structure that supplies high quality voltage to the connected sensitive load in the presence of other non linear loads. The proposed topology consists of combination of shunt and series inverters connected to a common Z-source impedance...... network. The shunt inverter is controlled to maintain a quality voltage waveform at the load bus. Whereas the series inverter enhances the ride-through capability during grid faults, protects the shunt inverter by limiting the current and also controls the power delivered to the grid. The performance......Distributed generation has been gaining acceptance over the years and it has the potential to provide reliable power to sensitive loads. However, distributed networks are prone to unbalanced faults conditions. This makes single inverter DG systems unsuitable as UPS systems. This paper proposes...

  12. Developing a model-based decision support system for call-a-ride paratransit service problems.

    Science.gov (United States)

    2011-02-01

    Paratransit is the transportation service that supplements larger public transportation : systems by providing individualized rides without fixed routes or timetables. In 1990, : the Americans with Disabilities Act (ADA) was passed which allows passe...

  13. Coordinated Control Strategies of VSC-HVDC-Based Wind Power Systems for Low Voltage Ride Through

    Directory of Open Access Journals (Sweden)

    Xinyin Zhang

    2015-07-01

    Full Text Available The Voltage Source Converter-HVDC (VSC-HVDC system applied to wind power generation can solve large scale wind farm grid-connection and long distance transmission problems. However, the low voltage ride through (LVRT of the VSC-HVDC connected wind farm is a key technology issue that must be solved, and it is currently lacking an economic and effective solution. In this paper, a LVRT coordinated control strategy is proposed for the VSC-HVDC-based wind power system. In this strategy, the operation and control of VSC-HVDC and wind farm during the grid fault period is improved. The VSC-HVDC system not only provides reactive power support to the grid, but also effectively maintains the power balance and DC voltage stability by reducing wind-farm power output, without increasing the equipment investment. Correspondingly, to eliminate the influence on permanent magnet synchronous generator (PMSG-based wind turbine (WT systems, a hierarchical control strategy is designed. The speed and validity of the proposed LVRT coordinated control strategy and hierarchical control strategy were verified by MATLAB/Simulink simulations.

  14. Assessment of control strategies for fault ride through of SCIG-based wind energy conversion systems

    Directory of Open Access Journals (Sweden)

    Manaullah

    2016-01-01

    Full Text Available With increasing penetration of wind energy into the power grid, researchers have started focusing more on control and coordination of wind energy conversion systems (WECS with the other components at system level, especially during fault. It is important to implement a suitable fault ride through control strategy to avoid tripping of the generators when the power system is subjected to voltage dips normally below 90% of nominal voltage. The dips below 90% may lead to a significant loss of generation and frequency collapse, followed by a blackout. This article implements and assesses the methodologies to deal with such situations for squirrel cage induction generator-based wind energy conversion systems employing fully rated power electronic converters. Three distinct control techniques—namely, balanced positive sequence control, positive negative sequence control, and dual current control—have been simulated and applied to grid side converter of SCIG-based WECS. The performance of all the three control strategies has been compared and presented in this work. During this study, the system is subjected to the most common unsymmetrical line to ground (LG fault and most severe symmetrical LLL fault on grid for the purpose of anaysis.

  15. Negative Sequence Droop Method based Hierarchical Control for Low Voltage Ride-Through in Grid-Interactive Microgrids

    DEFF Research Database (Denmark)

    Zhao, Xin; Firoozabadi, Mehdi Savaghebi; Quintero, Juan Carlos Vasquez

    2015-01-01

    In highly microgrid (MG) integrated distribution systems, problems such as a sudden cut out of the MGs due to grid faults may lead to adverse effects to the grid. As a consequence, ancillary services provided by MGs are preferred since it can make the MG a contributor to ride through the faults....... In this paper, a voltage support strategy based on negative sequence droop control, which regulate the positive/negative sequence active and reactive power flow by means of sending proper voltage reference to the inner control loop, is proposed for the grid connected MGs to ride through voltage sags under...... complex line impedance conditions. In this case, the MGs should inject a certain amount of positive and negative sequence power to the grid so that the voltage quality at load side can be maintained at a satisfied level. A two layer hierarchical control strategy is proposed in this paper. The primary...

  16. Second-order sliding mode control for DFIG-based wind turbines fault ride-through capability enhancement.

    Science.gov (United States)

    Benbouzid, Mohamed; Beltran, Brice; Amirat, Yassine; Yao, Gang; Han, Jingang; Mangel, Hervé

    2014-05-01

    This paper deals with the fault ride-through capability assessment of a doubly fed induction generator-based wind turbine using a high-order sliding mode control. Indeed, it has been recently suggested that sliding mode control is a solution of choice to the fault ride-through problem. In this context, this paper proposes a second-order sliding mode as an improved solution that handle the classical sliding mode chattering problem. Indeed, the main and attractive features of high-order sliding modes are robustness against external disturbances, the grids faults in particular, and chattering-free behavior (no extra mechanical stress on the wind turbine drive train). Simulations using the NREL FAST code on a 1.5-MW wind turbine are carried out to evaluate ride-through performance of the proposed high-order sliding mode control strategy in case of grid frequency variations and unbalanced voltage sags. Copyright © 2014 ISA. Published by Elsevier Ltd. All rights reserved.

  17. Improved fault ride through capability of DFIG based wind turbines using synchronous reference frame control based dynamic voltage restorer.

    Science.gov (United States)

    Rini Ann Jerin, A; Kaliannan, Palanisamy; Subramaniam, Umashankar

    2017-09-01

    Fault ride through (FRT) capability in wind turbines to maintain the grid stability during faults has become mandatory with the increasing grid penetration of wind energy. Doubly fed induction generator based wind turbine (DFIG-WT) is the most popularly utilized type of generator but highly susceptible to the voltage disturbances in grid. Dynamic voltage restorer (DVR) based external FRT capability improvement is considered. Since DVR is capable of providing fast voltage sag mitigation during faults and can maintain the nominal operating conditions for DFIG-WT. The effectiveness of the DVR using Synchronous reference frame (SRF) control is investigated for FRT capability in DFIG-WT during both balanced and unbalanced fault conditions. The operation of DVR is confirmed using time-domain simulation in MATLAB/Simulink using 1.5MW DFIG-WT. Copyright © 2017 ISA. Published by Elsevier Ltd. All rights reserved.

  18. Ride Your Luck! A Field Experiment on Lottery-Based Incentives for Compliance

    NARCIS (Netherlands)

    M. Fabbri (Marco); P.N. Barbieri (Paolo); M. Bigoni (Maria)

    2016-01-01

    textabstractWe designed a natural-field experiment in the context of local public transportation to test whether rewards in the form of lottery prizes coupled with traditional sanctions efficiently reduce free-riding. We organized a lottery in a medium-size Italian city the participation in which is

  19. A Dynamic Consensus Algorithm based Low-Voltage Ride-Through Operation of Power Converters in Grid-Interactive Microgrids

    DEFF Research Database (Denmark)

    Zhao, Xin; Meng, Lexuan; Savaghebi, Mehdi

    2016-01-01

    The possibility of increasing penetration level of grid-interactive microgrids (MGs) has gained a great interest over the past decade. Thus, it is critical to investigate the performance of the MGs under voltage sags, since it may induce instability to the power grid. Negative sequence droop...... control based voltage support strategy has been proposed to aid MGs riding through three phase asymmetrical voltage sags. However, since the line impedance from each converter to the point of common coupling (PCC) is not identical, both positive sequence and negative sequence output current...

  20. Novel scheme for enhancement of fault ride-through capability of doubly fed induction generator based wind farms

    Energy Technology Data Exchange (ETDEWEB)

    Vinothkumar, K. [Department of Electrical and Electronics Engineering, National Institute of Technology, Tiruchirappalli, Tamilnadu 620015 (India); Selvan, M.P., E-mail: selvanmp@nitt.ed [Department of Electrical and Electronics Engineering, National Institute of Technology, Tiruchirappalli, Tamilnadu 620015 (India)

    2011-07-15

    enhancing the performance of DFIG based wind farms to fault ride-through.

  1. A Novel Wind Turbine Concept Based on an Electromagnetic Coupler and the Study of Its Fault Ride-through Capability

    Directory of Open Access Journals (Sweden)

    Rui You

    2013-11-01

    Full Text Available This paper presents a novel type of variable speed wind turbine with a new drive train different from the variable speed wind turbine commonly used nowadays. In this concept, a synchronous generator is directly coupled with the grid, therefore, the wind turbine transient overload capability and grid voltage support capability can be significantly improved. An electromagnetic coupling speed regulating device (EMCD is used to connect the gearbox high speed shaft and synchronous generator rotor shaft, transmitting torque to the synchronous generator, while decoupling the gearbox side and the synchronous generator, so the synchronous generator torque oscillations during a grid fault are not transmitted to the gearbox. The EMCD is composed of an electromagnetic coupler and a one quadrant operation converter with reduced capability and low cost. A control strategy for the new wind turbine is proposed and a 2 MW wind turbine model is built to study the wind turbine fault ride-through capability. An integrated simulation environment based on the aeroelastic code HAWC2 and software Matlab/Simulink is used to study its fault ride-through capability and the impact on the structural loads during grid three phase and two phase short circuit faults.

  2. FDI based on Artificial Neural Network for Low-Voltage-Ride-Through in DFIG-based Wind Turbine.

    Science.gov (United States)

    Adouni, Amel; Chariag, Dhia; Diallo, Demba; Ben Hamed, Mouna; Sbita, Lassaâd

    2016-09-01

    As per modern electrical grid rules, Wind Turbine needs to operate continually even in presence severe grid faults as Low Voltage Ride Through (LVRT). Hence, a new LVRT Fault Detection and Identification (FDI) procedure has been developed to take the appropriate decision in order to develop the convenient control strategy. To obtain much better decision and enhanced FDI during grid fault, the proposed procedure is based on voltage indicators analysis using a new Artificial Neural Network architecture (ANN). In fact, two features are extracted (the amplitude and the angle phase). It is divided into two steps. The first is fault indicators generation and the second is indicators analysis for fault diagnosis. The first step is composed of six ANNs which are dedicated to describe the three phases of the grid (three amplitudes and three angle phases). Regarding to the second step, it is composed of a single ANN which analysis the indicators and generates a decision signal that describes the function mode (healthy or faulty). On other hand, the decision signal identifies the fault type. It allows distinguishing between the four faulty types. The diagnosis procedure is tested in simulation and experimental prototype. The obtained results confirm and approve its efficiency, rapidity, robustness and immunity to the noise and unknown inputs. Copyright © 2016 ISA. Published by Elsevier Ltd. All rights reserved.

  3. Fault ride-through and grid support of permanent magnet synchronous generator-based wind farms with HVAC and VSC-HVDC transmission systems

    DEFF Research Database (Denmark)

    Liu, Hongzhi; Chen, Zhe

    2012-01-01

    This paper describes fault ride-through and grid support of offshore wind farms based on permanent magnet synchronous generator (PMSG) wind turbines connected to the onshore AC network through two alternative transmission systems: high voltage AC (HVAC) or high voltage DC (HVDC) based on voltage...

  4. Dial-a-Ride

    DEFF Research Database (Denmark)

    Jørgensen, Rene Munk

    2003-01-01

    to the problem. The metod used in this thesis is based on a clustering first insertion second technique developed at CRT in Canada in the mid 1980's. The algorithm is extended to include constraints imposed by a practical Dial-a-Ride problem at a Danish transportation operator. These constraints are mainly...... with a digitized road network. The user interface is developed as generically as possible making it reuseable in all sorts of Vehicle Routing problems. The foundation of the user interface is a database for storing customers, requests, routes etc. The digitized road map is included in the developed software by use...

  5. Sorption Kinetics for the Removal of Cadmium and Zinc onto Palm Kernel Shell Based Activated Carbon

    Directory of Open Access Journals (Sweden)

    Muhammad Muhammad

    2010-12-01

    Full Text Available The kinetics and mechanism of cadmium and zinc adsorption on palm kernel shell based activated carbons (PKSAC have been studied. A series of batch laboratory studies were conducted in order to investigate the suitability of palm kernel shell based activated carbon (PKSAC for the removal of cadmium (cadmium ions and zinc (zinc ions from their aqueous solutions. All batch experiments were carried out at pH 7.0 and a constant temperature of 30+-1°C using an incubator shaker that operated at 150 rpm. The kinetics investigated includes the pseudo first order, the pseudo-second order and the intraparticle diffusion models. The pseudo-second order model correlate excellently the experimental data, suggesting that chemisorption processes could be the rate-limiting step. Keywords: adsorption, cadmium, kinetics, palm kernel shell, zinc

  6. Differential Evolution Based IDWNN Controller for Fault Ride-Through of Grid-Connected Doubly Fed Induction Wind Generators.

    Science.gov (United States)

    Manonmani, N; Subbiah, V; Sivakumar, L

    2015-01-01

    The key objective of wind turbine development is to ensure that output power is continuously increased. It is authenticated that wind turbines (WTs) supply the necessary reactive power to the grid at the time of fault and after fault to aid the flowing grid voltage. At this juncture, this paper introduces a novel heuristic based controller module employing differential evolution and neural network architecture to improve the low-voltage ride-through rate of grid-connected wind turbines, which are connected along with doubly fed induction generators (DFIGs). The traditional crowbar-based systems were basically applied to secure the rotor-side converter during the occurrence of grid faults. This traditional controller is found not to satisfy the desired requirement, since DFIG during the connection of crowbar acts like a squirrel cage module and absorbs the reactive power from the grid. This limitation is taken care of in this paper by introducing heuristic controllers that remove the usage of crowbar and ensure that wind turbines supply necessary reactive power to the grid during faults. The controller is designed in this paper to enhance the DFIG converter during the grid fault and this controller takes care of the ride-through fault without employing any other hardware modules. The paper introduces a double wavelet neural network controller which is appropriately tuned employing differential evolution. To validate the proposed controller module, a case study of wind farm with 1.5 MW wind turbines connected to a 25 kV distribution system exporting power to a 120 kV grid through a 30 km 25 kV feeder is carried out by simulation.

  7. Differential Evolution Based IDWNN Controller for Fault Ride-Through of Grid-Connected Doubly Fed Induction Wind Generators

    Directory of Open Access Journals (Sweden)

    N. Manonmani

    2015-01-01

    Full Text Available The key objective of wind turbine development is to ensure that output power is continuously increased. It is authenticated that wind turbines (WTs supply the necessary reactive power to the grid at the time of fault and after fault to aid the flowing grid voltage. At this juncture, this paper introduces a novel heuristic based controller module employing differential evolution and neural network architecture to improve the low-voltage ride-through rate of grid-connected wind turbines, which are connected along with doubly fed induction generators (DFIGs. The traditional crowbar-based systems were basically applied to secure the rotor-side converter during the occurrence of grid faults. This traditional controller is found not to satisfy the desired requirement, since DFIG during the connection of crowbar acts like a squirrel cage module and absorbs the reactive power from the grid. This limitation is taken care of in this paper by introducing heuristic controllers that remove the usage of crowbar and ensure that wind turbines supply necessary reactive power to the grid during faults. The controller is designed in this paper to enhance the DFIG converter during the grid fault and this controller takes care of the ride-through fault without employing any other hardware modules. The paper introduces a double wavelet neural network controller which is appropriately tuned employing differential evolution. To validate the proposed controller module, a case study of wind farm with 1.5 MW wind turbines connected to a 25 kV distribution system exporting power to a 120 kV grid through a 30 km 25 kV feeder is carried out by simulation.

  8. Differential Evolution Based IDWNN Controller for Fault Ride-Through of Grid-Connected Doubly Fed Induction Wind Generators

    Science.gov (United States)

    Manonmani, N.; Subbiah, V.; Sivakumar, L.

    2015-01-01

    The key objective of wind turbine development is to ensure that output power is continuously increased. It is authenticated that wind turbines (WTs) supply the necessary reactive power to the grid at the time of fault and after fault to aid the flowing grid voltage. At this juncture, this paper introduces a novel heuristic based controller module employing differential evolution and neural network architecture to improve the low-voltage ride-through rate of grid-connected wind turbines, which are connected along with doubly fed induction generators (DFIGs). The traditional crowbar-based systems were basically applied to secure the rotor-side converter during the occurrence of grid faults. This traditional controller is found not to satisfy the desired requirement, since DFIG during the connection of crowbar acts like a squirrel cage module and absorbs the reactive power from the grid. This limitation is taken care of in this paper by introducing heuristic controllers that remove the usage of crowbar and ensure that wind turbines supply necessary reactive power to the grid during faults. The controller is designed in this paper to enhance the DFIG converter during the grid fault and this controller takes care of the ride-through fault without employing any other hardware modules. The paper introduces a double wavelet neural network controller which is appropriately tuned employing differential evolution. To validate the proposed controller module, a case study of wind farm with 1.5 MW wind turbines connected to a 25 kV distribution system exporting power to a 120 kV grid through a 30 km 25 kV feeder is carried out by simulation. PMID:26516636

  9. Coordinated control for low voltage ride-through of a PMSG-based wind power plant

    Directory of Open Access Journals (Sweden)

    Khagendra Thapa

    2016-01-01

    Full Text Available Wind turbine generators should be kept connected to a power grid, while supporting the voltage recovery in the case of a grid fault to meet low voltage ride-through requirement in some grid codes. This paper proposes a coordinated control scheme that prevents the increase in the DC-link voltage by reducing the active power in the machine side converter of permanent magnet synchronous generators (PMSGs in proportion to the voltage dip at the terminal of PMSGs. The proposed scheme changes the current priorities from the active current to the reactive current to inject more reactive power for a severe fault depending on the voltage dip. In addition, the grid-side converter operates in a voltage control mode with the slope, which is the ratio of reactive current capability to the voltage tolerance around a rated value. Moreover, during the fault, the slope is changed depending on the voltage dip to inject more reactive current. The performance of the proposed scheme is validated for a wind power plant consisting of 20 units of 5-MW PMSGs using an EMTP-RV simulator. The results demonstrate that the scheme enables the PMSGs not only to survive during the fault, but also to provide a dynamic reactive power support.

  10. Analytical Studies on Ride Quality and Ride Comfort in Chennai Mass Rapid Transit System (MRTS) Railroad Vehicle

    Science.gov (United States)

    Gangadharan, K. V.; Chandramohan, Sujatha

    2017-12-01

    In this paper analytical ride index studies and ISO 2631 based ride comfort analysis of a suburban MRTS railroad vehicle is presented. Track power spectral densities (PSDs) were used as inputs to a finite element (FE) model of the vehicle and track and the acceleration responses were computed using random vibration theory. From these responses, ride quality and ride comfort have been computed at different locations of the vehicle at different speeds in the vertical and lateral directions.

  11. Differences in urine cadmium associations with kidney outcomes based on serum creatinine and cystatin C

    Energy Technology Data Exchange (ETDEWEB)

    Weaver, Virginia M., E-mail: vweaver@jhsph.edu [Division of Occupational and Environmental Health, Department of Environmental Health Sciences, Johns Hopkins University Bloomberg School of Public Health, 615N. Wolfe St., Rm. 7041, Baltimore, MD 21205 (United States); Department of Medicine, Johns Hopkins University School of Medicine, Baltimore, MD (United States); Welch Center for Prevention, Epidemiology and Clinical Research, Johns Hopkins Medical Institutions, Baltimore, MD (United States); Kim, Nam-Soo; Lee, Byung-Kook [Institute of Industrial Medicine, SoonChunHyang University, Asan (Korea, Republic of); Parsons, Patrick J. [Laboratory of Inorganic and Nuclear Chemistry, Wadsworth Center, New York State Department of Health, Albany, NY (United States); Department of Environmental Health Sciences, School of Public Health, University at Albany, Albany, NY (United States); Spector, June [Department of Environmental and Occupational Health Sciences, University of Washington, Seattle, WA (United States); Fadrowski, Jeffrey [Welch Center for Prevention, Epidemiology and Clinical Research, Johns Hopkins Medical Institutions, Baltimore, MD (United States); Department of Pediatrics, Johns Hopkins School of Medicine, Baltimore, MD (United States); Jaar, Bernard G. [Department of Medicine, Johns Hopkins University School of Medicine, Baltimore, MD (United States); Welch Center for Prevention, Epidemiology and Clinical Research, Johns Hopkins Medical Institutions, Baltimore, MD (United States); Department of Epidemiology, Johns Hopkins University Bloomberg School of Public Health, Baltimore, MD (United States); Steuerwald, Amy J. [Laboratory of Inorganic and Nuclear Chemistry, Wadsworth Center, New York State Department of Health, Albany, NY (United States); Department of Environmental Health Sciences, School of Public Health, University at Albany, Albany, NY (United States); Todd, Andrew C. [Department of Preventive Medicine, Mount Sinai School of Medicine, New York, NY (United States); and others

    2011-11-15

    Cadmium is a well-known nephrotoxicant; chronic exposure increases risk for chronic kidney disease. Recently, however, associations between urine cadmium and higher creatinine-based estimated glomerular filtration rate (eGFR) have been reported. Analyses utilizing alternate biomarkers of kidney function allow evaluation of potential mechanisms for these observations. We compared associations of urine cadmium with kidney function measures based on serum cystatin C to those with serum creatinine in 712 lead workers. Mean (standard deviation) molybdenum-corrected urine cadmium, Modification of Diet in Renal Disease (MDRD) eGFR and multi-variable cystatin C eGFR were 1.02 (0.65) {mu}g/g creatinine, and 97.4 (19.2) and 112.0 (17.7) mL/min/1.73 m{sup 2}, respectively. The eGFR measures were moderately correlated (r{sub s}=0.5; p<0.001). After adjustment, ln (urine cadmium) was not associated with serum cystatin-C-based measures. However, higher ln (urine cadmium) was associated with higher creatinine-based eGFRs including the MDRD and an equation incorporating serum cystatin C and creatinine (beta-coefficient=4.1 mL/min/1.73 m{sup 2}; 95% confidence interval=1.6, 6.6). Urine creatinine was associated with serum creatinine-based but not cystatin-C-based eGFRs. These results support a biomarker-specific, rather than a kidney function, effect underlying the associations observed between higher urine cadmium and creatinine-based kidney function measures. Given the routine use of serum and urine creatinine in kidney and biomarker research, additional research to elucidate the mechanism(s) for these associations is essential.

  12. Defects and properties of cadmium oxide based transparent conductors

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Kin Man, E-mail: kinmanyu@cityu.edu.hk [Department of Physics and Materials Science, City University of Hong Kong, Kowloon (Hong Kong); Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Detert, D. M.; Dubon, O. D. [Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Department of Materials Science and Engineering, University of California, Berkeley, California 94720 (United States); Chen, Guibin [Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Physics Department and Jiangsu Key Laboratory for Chemistry of Low Dimensional Materials, Huaiyin Normal University, Jiangsu 223300 (China); Zhu, Wei [Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Department of Physics and The Center for Physical Experiments, University of Science and Technology of China, Hefei, Anhui 230026 (China); Liu, Chaoping [Department of Physics and Materials Science, City University of Hong Kong, Kowloon (Hong Kong); Grankowska, S. [Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Institute of Experimental Physics (IEP UW), Warsaw University, Warsaw (Poland); Hsu, L. [Department of Postsecondary Teaching and Learning, University of Minnesota, Minneapolis, Minnesota 55455 (United States); Walukiewicz, Wladek [Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

    2016-05-14

    Transparent conductors play an increasingly important role in a number of semiconductor technologies. This paper reports on the defects and properties of Cadmium Oxide, a transparent conducting oxide which can be potentially used for full spectrum photovoltaics. We carried out a systematic investigation on the effects of defects in CdO thin films undoped and intentionally doped with In and Ga under different deposition and annealing conditions. We found that at low growth temperatures (<200 °C), sputter deposition tends to trap both oxygen vacancies and compensating defects in the CdO film resulting in materials with high electron concentration of ∼2 × 10{sup 20}/cm{sup 3} and mobility in the range of 40–100 cm{sup 2}/V s. Thermal annealing experiments in different ambients revealed that the dominating defects in sputtered CdO films are oxygen vacancies. Oxygen rich CdO films grown by sputtering with increasing O{sub 2} partial pressure in the sputter gas mixture results in films with resistivity from ∼4 × 10{sup −4} to >1 Ω cm due to incorporation of excess O in the form of O-related acceptor defects, likely to be O interstitials. Intentional doping with In and Ga donors leads to an increase of both the electron concentration and the mobility. With proper doping CdO films with electron concentration of more than 10{sup 21 }cm{sup −3} and electron mobility higher than 120 cm{sup 2}/V s can be achieved. Thermal annealing of doped CdO films in N{sub 2} ambient can further improve the electrical properties by removing native acceptors and improving film crystallinity. Furthermore, the unique doping behavior and electrical properties of CdO were explored via simulations based on the amphoteric defect model. A comparison of the calculations and experimental results show that the formation energy of native donors and acceptors at the Fermi stabilization energy is ∼1 eV and that the mobility of sputtered deposited CdO is limited

  13. Fault Ride through Capability Improvement of Wind Turbine Based DFIG Considering an Optimized Crowbar Along with STATCOM under Grid Fault Condition

    OpenAIRE

    Alireza Zohoori; Ahad Kazemi; Rouhollah Shafaie

    2013-01-01

    Grid disturbances, especially grid faults, have very unfavorable effect on the performance of wind turbine based Doubly Fed Induction Generator (DFIG). In this study active and reactive powers control of DFIG with STATCOM has been carried out to improve Fault Ride Through (FRT) capability of a wind turbine. In order to excel improvement of the DFIG behavior under grid fault disturbances, an optimized crowbar protection method is also considered together with STATCOM. The optimized protection ...

  14. Improvement of cadmium ion removal by base treatment of juniper fiber

    Science.gov (United States)

    S.H. Min; J.S. Han; E.W. Shin; J.K. Park

    2004-01-01

    Juniper is a small-diameter underutilized lignocellulosic material. We evaluated the efficacy of base-treated juniper fiber (BTJF) for cadmium (Cd2+) sorption and the viability of juniper fiber as a sorbent for removing Cd2+ from water. Fourier transform infrared spectroscopy analysis indicated that carboxylate ion is a major functional group responsible for Cd2+...

  15. Healthy Ride Trip Data

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — A dataset that shows trips taken using the Healthy Ride system by quarter. The dataset includes bike number, membership type, trip start and end timestamp, and...

  16. Luminescence-based whole-cell-sensing systems for cadmium and lead using genetically engineered bacteria.

    Science.gov (United States)

    Shetty, Ranjit S; Deo, Sapna K; Shah, Puja; Sun, Yan; Rosen, Barry P; Daunert, Sylvia

    2003-05-01

    Whole-cell-based sensing systems that respond to cadmium and lead ions have been designed and developed using genetically engineered bacteria. These systems take advantage of the ability of certain bacteria to survive in environments polluted with cadmium and lead ions. The bacteria used in this investigation have been genetically engineered to produce reporter proteins in response to the toxic ions. This was achieved by modifying a strain of Escherichia colito harbor plasmids pYSC1 and pYS2/pYSG1. In these dual-plasmid-based sensing systems, the expression of the reporters beta-galactosidase and red-shifted green fluorescent protein (rs-GFP) was controlled by CadC, the regulatory protein of the cad operon. Regulation of the expression of the reporter proteins is related to the amount of cadmium and lead ions employed to induce the bacteria. The bacterial sensing systems were found to respond to cadmium, lead, and zinc ions, and had no significant response to nickel, copper, manganese, and cobalt.

  17. Effects of Capcitor Bank on Fault Ride Through Capibility of Induction Generator Based Wind Turbines

    DEFF Research Database (Denmark)

    Hu, Y; Chen, Zhe

    2010-01-01

    power system stability and supply security. Some existing wind turbines are still based on fixed speed induction generators, the effects of capacitor bank on such generators are discussed in this paper. The simulation study shows the capacitor bank may costeffectively improve the dynamic performance......Wind turbine installation is increasing rapidly. In some networks, wind power penetration is significantly high and the performance of wind turbine plays an important role in power system operation and control. Especially, the behavior of wind turbines during a power system disturbance would affect...... of the induction generators....

  18. Brief review of cadmium telluride-based photovoltaic technologies

    Science.gov (United States)

    Başol, Bülent M.; McCandless, Brian

    2014-01-01

    Cadmium telluride (CdTe) is the most commercially successful thin-film photovoltaic technology. Development of CdTe as a solar cell material dates back to the early 1980s when ˜10% efficient devices were demonstrated. Implementation of better quality glass, more transparent conductive oxides, introduction of a high-resistivity transparent film under the CdS junction-partner, higher deposition temperatures, and improved Cl-treatment, doping, and contacting approaches yielded >16% efficient cells in the early 2000s. Around the same time period, use of a photoresist plug monolithic integration process facilitated the demonstration of the first 11% efficient module. The most dramatic advancements in CdTe device efficiencies were made during the 2013 to 2014 time frame when small-area cell conversion efficiency was raised to 20% range and a champion module efficiency of 17% was reported. CdTe technology is attractive in terms of its limited life-cycle greenhouse gas and heavy metal emissions, small carbon footprint, and short energy payback times. Limited Te availability is a challenge for the growth of this technology unless Te utilization rates are greatly enhanced along with device efficiencies.

  19. Advanced fault ride-through control of DFIG based wind turbines including grid connection via VSC-HVDC

    Energy Technology Data Exchange (ETDEWEB)

    Feltes, Christian

    2012-07-01

    With the growing renewable energy share in the power generation mix it becomes inevitable that also these new generation technologies participate on the provision of grid services to guarantee stable operation of the grid, especially when one considers the decreasing number of conventional power plants in operation as a result of the expansion of wind based generation plants. These so-called ancillary services include frequency / active power control, voltage / reactive power control and fault ride-through (FRT) with fast voltage control and are stipulated in modern grid codes. In the context of this thesis advanced control algorithms have been developed for wind turbines based on doubly-fed induction generator (DFIG) to allow safe FRT during symmetrical and unsymmetrical faults. This covers the control for conventional AC grid connection as well as for the connection through voltage source converter (VSC) based high voltage direct current transmission (HVDC). Currently, the DFIG is the most used generator technology in modem wind turbines, since it combines a relatively simple slip-ring induction machine with a frequency converter rated to only approx. 30% of the total power. This makes the DFIG a cost-effective concept, which offers a variable speed range and a high degree of flexibility in control. However, due to the direct coupling of the generator stator circuit to the grid, grid faults are a special challenge for the frequency converter, its protection circuits and control algorithms. As base for the detailed evaluation of the impact of grid faults to the DFIG, this thesis contains the analytical derivation of the DFIG short circuit currents under consideration of frequency converter control. The DFIG concept presented in this thesis makes use of a DC chopper in the frequency converter, which allows safe FRT with grid voltage support through both converter sides. The developed control contains a new algorithm for a clear separation and control of positive

  20. PrivateRide: A Privacy-Preserving and Secure Ride-Hailing Service

    OpenAIRE

    Pham, Thi Van Anh; Dacosta Petrocelli, Italo Ivan; Jacot-Guillarmod, Bastien; Huguenin, Kévin; Hajar, Taha; Tramèr, Florian; Gligor, Virgil; Hubaux, Jean-Pierre

    2016-01-01

    In the past few years, we have witnessed a rise in the popularity of ride-hailing services (RHSs), as an online marketplace that enables accredited drivers to use their own cars to drive ride-hailing users. Unlike other transportation services, RHSs raise significant privacy concerns, as providers are able to track the precise mobility patterns of millions of riders worldwide. RHSs also raise concerns about the integrity of the fares of the trips, as the fares are computed based on informatio...

  1. Elevated guideway cost-ride quality studies for group rapid transit systems

    Science.gov (United States)

    1977-10-01

    A methodology is developed for relating cost to ride quality in elevated guideway : system design, based upon directly relating guideway structural properties and : construction tolerances to both cost and ride quality. It is illustrated in detail : ...

  2. Never Riding the Tide

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 13; Issue 10. Never Riding the Tide - Seymour Benzer–The Founder of Neurogenetics. K VijayRaghavan Veronica Rodrigues. General Article Volume 13 Issue 10 October 2008 pp 909-915 ...

  3. Comparative study of graphene nanosheet- and multiwall carbon nanotube-based electrochemical sensor for the sensitive detection of cadmium

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Lidong; Fu, Xiaochen; Liu, Huan; Li, Jincheng; Song, Yi, E-mail: wuld@cafs.ac.cn

    2014-12-03

    Graphical abstract: Schematic diagram of nanographene-based sensor detection of cadmium ions by stripping analysis. - Highlights: • A nanocomposite based on nanographene and Nafion is used as a platform for cadmium detection. • The performance of the nanographene-based sensor was compared with that of MWCNT. • It indicated that the nanographene-based sensor possessed significant advantages over MWCNT. • The nanographene-based sensor proved to be a reliable tool for rapid detection of cadmium. - Abstract: A novel nanocomposite was obtained through the controlled surface modification of graphene nanosheets (nanographene) with Nafion by ultrasonic oscillation. The composite was used as an ultrasensitive platform for the detection of cadmium ions (Cd{sup 2+}) by differential pulse anodic stripping voltammetry (DPASV) analysis. The performance of the nanographene-based sensor was systematically compared with that of a multiwall carbon nanotube (MWCNT)-modified sensor. The results indicate that the nanographene-based sensor exhibits significant advantages over the MWCNT-based sensor in terms of repeatability, sensitivity and limit of detection (LOD). The nanographene-based sensor displayed superior analytical performance over a linear range of Cd{sup 2+} concentrations from 0.25 μg L{sup −1} to 5 μg L{sup −1}, with a LOD of 3.5 ng L{sup −1}. This sensor was also used to systematically screen for 6 types of chemicals, including sodium salts, magnesium salts and zinc salts. It was observed that the sensor could successfully differentiate cadmium ions from interferents (magnesium salts, zinc salts, etc.). The nanographene-based sensor was also demonstrated to be a promising and reliable tool for the rapid detection of cadmium existing in tap water and for the rapid on-site analysis of critical pollution levels of cadmium.

  4. Ion imprinted polymer based potentiometric sensor for the trace determination of Cadmium (II ions

    Directory of Open Access Journals (Sweden)

    Seyyed Ahmad Rezvani Ivari

    2017-02-01

    Full Text Available A cadmium (II ion selective electrode (ISE based on an ion-imprinted polymer (IIP as a novel ionophore has been prepared and studied. The ion-selective electrode (ISE was prepared by dispersing cadmium (II IIP particles in 2-nitrophenyloctyl ether as a plasticizer and then embedding them in a polyvinylchloride polymeric matrix. The Cd(II ISE showed a nernstian response for cadmium (II over the dynamic concentration range of 2.0 × 10−7–1.0 × 10−2 mol L−1, with a slope of 29.9 mV per decade. The limit of detection was 1.0 × 10−7 M. The proposed electrode revealed good selectivity over a wide variety of other cations including alkali, alkaline earth, heavy and transition metals. The accuracy of the proposed electrode was checked through the analysis of spiked water samples.

  5. Parametric analysis of rail vehicle parameters influencing ride ...

    African Journals Online (AJOL)

    It is seen from parametric analysis that car body mass, secondary suspension vertical damping, primary suspension vertical damping and wheel base are the most sensitive parameters influencing vertical ride. While lateral ride is significantly influenced by car body mass, roll & yaw mass moment of inertia and secondary ...

  6. Laser-induced photodynamic effects at silica nanocomposite based on cadmium sulphide quantum dots.

    Science.gov (United States)

    Voznesenskiy, S S; Sergeev, A A; Galkina, A N; Kulchin, Yu N; Shchipunov, Yu A; Postnova, I V

    2014-01-27

    In this paper we study the laser-induced modification of optical properties of nanocomposite based on cadmium sulphide quantum dots encapsulated into thiomalic acid shell which were embedded into a porous silica matrix. We found red shift of luminescence of the nanocomposite when exposed to laser radiation at λ = 405 nm. Using pump-probe method and Small-Angle X-ray Scattering technique it was found that laser radiation at λ = 405 nm also increases the absorption coefficient of the nanocomposite in 15 times due to agglomeration of quantum dots. The modification of absorption properties is fully reversible.

  7. Motorcyclists' self-reported riding mileage versus actual riding mileage in the following year.

    Science.gov (United States)

    Williams, Vicki; McLaughlin, Shane; McCall, Robert; Buche, Tim

    2017-12-01

    Accurate motorcyclist mileage estimates are important because self-evaluation of riding experience is related to riding behavior, the relationship of self-reported to actual or future mileage is necessary in targeting training and considering survey responses, and motorcycle crash statistics require accurate travel data. This study collected real-world data from motorcyclists over the course of two months to two years per rider. This paper explores motorcyclists' self-reported annual riding mileage (obtained via pre-study surveys) and the actual amount of riding during the study (based upon odometer readings and GPS data). Of the 91 riders who had been riding for at least a year before the study, significantly more (73%) rode less the following year than reported for the previous year. The recorded annualized mileage averaged 89% of the reported mileage from the previous year. Analyses based on estimated average annual mileage were similar to those using the previous year estimation, and the pattern held regardless of age group, motorcycle type, or gender. The exception was novice or returning riders, who tended to either significantly underestimate or increase actual mileage as they began (or continued) to ride. Motorcyclists' estimation of riding experience expressed as mileage may not be indicative of current or future mileage. Reliance on self-reported mileage during training to categorize groups, for interpretation of studies, or to develop motorcycle travel data and safety statistics may be unrealistic. Certainly any use of self-reported mileage should incorporate the concept that mileage overestimation seems likely. Because questions about previous year and average annual mileage may elicit similar responses, motorcyclist surveys should be constructed to prompt the most thoughtful responses in terms of mileage estimations. In general, reported mileage should not be relied upon as an accurate predictor of future actual mileage. Copyright © 2017 Elsevier Ltd

  8. A Safe Ride to School; A Safe Ride Home.

    Science.gov (United States)

    Illinois State Board of Education, Springfield.

    Text and illustrations are used to teach safe school bus riding practices. The guide begins with instructions to parents or guardians to set a good example of safe behavior, and to help children learn safety rules and be on time. Instructions to children concern obeying the bus driver, boarding the bus, riding the bus, crossing the road, and using…

  9. Free Riding or Trust?

    DEFF Research Database (Denmark)

    Svendsen, Gert Tinggaard; Nilsson, Jerker

    2011-01-01

    It is often observed that members have little interest in monitoring their cooperatives. One explanation is that the members are free-riders, hoping that others will perform the task. Another explanation is that the weak member interest is a consequence of members having trust in the leadership. ...... have a subset of members who trusts the leadership so they do not read the annual reports....... conditions rule. These propositions get support from five studies of members’ readership of their cooperatives’ annual reports. In large and heterogeneous memberships there is free-riding behavior, which explains the members’ low interest in governing their cooperatives. To a limited extent a membership may...

  10. Cooperate or Free Ride?

    DEFF Research Database (Denmark)

    Hansen, Per H.

    2012-01-01

    In this article, I discuss the role of the three Scandinavian central banks in the establishment of the Bank for International Settlements (BIS) in 1930, and in the international lender of last resort operation towards Austria in 1931. I argue that small central banks were reluctant supporters...... of international cooperation. On the other hand, the evidence seems to confirm Kindleberger's hypothesis that small countries were free riding during the international financial crisis of 1931, and that therefore there is a need for some coordinating mechanism, or a hegemon, in such crises....

  11. Schiff bases as cadmium(II) selective ionophores in polymeric membrane electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, V.K. [Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee 247667 (India)]. E-mail: vinodfcy@iitr.ernet.in; Singh, A.K. [Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee 247667 (India); Gupta, Barkha [Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee 247667 (India)

    2007-02-05

    The construction and performance characteristics of polymeric membrane electrodes based on two neutral ionophores, N,N'-[bis(pyridin-2-yl)formylidene]butane-1,4-diamine (S{sub 1}) and N-(2-pyridinylmethylene)-1,2-benzenediamine (S{sub 2}) for quantification of cadmium ions, are described. The influences of membrane compositions on the potentiometric response of the electrodes have been found to substantially improve the performance characteristics. The best performance was obtained with the electrode having a membrane composition (w/w) of (S{sub 1}) (2.15%):PVC (32.2%):o-NPOE (64.5%):KTpClPB (1.07%). The proposed electrode exhibits Nernstian response in the concentration range of 7.9 x 10{sup -8} to 1.0 x 10{sup -1} M Cd{sup 2+} with limit of detection 5.0 x 10{sup -8} M, performs satisfactorily over wide pH range (2.0-8.0) with a fast response time (10 s). The sensor has been found to work satisfactorily in partially non-aqueous media up to 30% (v/v) content of methanol, ethanol and acetonitrile and could be used for a period of 2 months. The analytical usefulness of the proposed electrode has been evaluated by its application in the determination of cadmium in real samples. The practical utility of the membrane electrode has also been observed in the presence of surfactants.

  12. Schiff bases as cadmium(II) selective ionophores in polymeric membrane electrodes.

    Science.gov (United States)

    Gupta, V K; Singh, A K; Gupta, Barkha

    2007-02-05

    The construction and performance characteristics of polymeric membrane electrodes based on two neutral ionophores, N,N'-[bis(pyridin-2-yl)formylidene]butane-1,4-diamine (S1) and N-(2-pyridinylmethylene)-1,2-benzenediamine (S2) for quantification of cadmium ions, are described. The influences of membrane compositions on the potentiometric response of the electrodes have been found to substantially improve the performance characteristics. The best performance was obtained with the electrode having a membrane composition (w/w) of (S1) (2.15%):PVC (32.2%):o-NPOE (64.5%):KTpClPB (1.07%). The proposed electrode exhibits Nernstian response in the concentration range of 7.9x10(-8) to 1.0x10(-1) M Cd2+ with limit of detection 5.0x10(-8) M, performs satisfactorily over wide pH range (2.0-8.0) with a fast response time (10 s). The sensor has been found to work satisfactorily in partially non-aqueous media up to 30% (v/v) content of methanol, ethanol and acetonitrile and could be used for a period of 2 months. The analytical usefulness of the proposed electrode has been evaluated by its application in the determination of cadmium in real samples. The practical utility of the membrane electrode has also been observed in the presence of surfactants.

  13. Comparative study of graphene nanosheet- and multiwall carbon nanotube-based electrochemical sensor for the sensitive detection of cadmium.

    Science.gov (United States)

    Wu, Lidong; Fu, Xiaochen; Liu, Huan; Li, Jincheng; Song, Yi

    2014-12-03

    A novel nanocomposite was obtained through the controlled surface modification of graphene nanosheets (nanographene) with Nafion by ultrasonic oscillation. The composite was used as an ultrasensitive platform for the detection of cadmium ions (Cd(2+)) by differential pulse anodic stripping voltammetry (DPASV) analysis. The performance of the nanographene-based sensor was systematically compared with that of a multiwall carbon nanotube (MWCNT)-modified sensor. The results indicate that the nanographene-based sensor exhibits significant advantages over the MWCNT-based sensor in terms of repeatability, sensitivity and limit of detection (LOD). The nanographene-based sensor displayed superior analytical performance over a linear range of Cd(2+) concentrations from 0.25μgL(-1) to 5μgL(-1), with a LOD of 3.5ngL(-1). This sensor was also used to systematically screen for 6 types of chemicals, including sodium salts, magnesium salts and zinc salts. It was observed that the sensor could successfully differentiate cadmium ions from interferents (magnesium salts, zinc salts, etc.). The nanographene-based sensor was also demonstrated to be a promising and reliable tool for the rapid detection of cadmium existing in tap water and for the rapid on-site analysis of critical pollution levels of cadmium. Copyright © 2014 Elsevier B.V. All rights reserved.

  14. Examination of fault ride-through methods for off-shore wind farms connected to the grid through VSC-based HVDC transmission

    Energy Technology Data Exchange (ETDEWEB)

    Karaagac, U.; Mahseredjian, J.; Saad, H. [Ecole Polytechnique de Montreal, QC (Canada); Jensen, S.; Cai, L. [REpower Systems AG, Hamburg (Germany)

    2012-07-01

    The fault ride-through (FRT) performance of offshore wind farms (OWFs) is a challenging task when the OWF is connected to the onshore ac grid through a voltage source converter (VSC) based HVDC transmission system. The injected power from the OWF cannot be reduced by the offshore VSC during onshore ac faults and this causes a fast increase in the dc network voltage. Without any special FRT method, the dc network voltage may increase up to intolerable levels and cause operation of dc overvoltage protection. This paper compares various FRT methods based on fast reduction of power generation in OWFs. In addition, this paper proposes an improved FRT method based on controlled voltage drop for output power reduction in OWFs. The proposed improvement reduces mechanical stress on the wind turbine (WT) drive train, and electrical stress on the insulated gate bipolar transistors (IGBTs) of the HVDC and doubly-fed induction generator (DFIG) converters. Practical onshore ac fault scenarios are simulated for an OWF composed of DFIG type WTs and connected to a practical ac grid through a point-to-point modular multilevel converter (MMC) based HVDC system. (orig.)

  15. Cadmium Alternatives

    Science.gov (United States)

    2012-08-01

    using for commercial applications Other zinc alloys Zinc cobalt , tin zinc, zinc iron Passivation Cadmium, ZnNi, SnZn, ZnCo, ZnFe, and...for Change Cadmium passivated with hexavalent chromium has been in use for many decades Cadmium is toxic, and is classified as a priority...Executive Orders 13514 & 13423 DoD initiatives – Young memo (April 2009) DFAR restricting use of hexavalent chromium Allows the use of hexavalent

  16. Internet Plus Ride-Hailing

    National Research Council Canada - National Science Library

    2016-01-01

    ...,the U.S.ride-hailing company Uber and its Chinese counterparts Didi Chuxing,Yidao Yongche and Shenzhou Special Car Service are the four largest ridehailing companies in China.Apple Inc.'s recent...

  17. Fancy a ride?

    CERN Multimedia

    Anaïs Schaeffer

    2014-01-01

    This Sunday 7 September, don’t miss your chance to climb into a supercar, one of those exceptional machines that tear up the tracks and that you sometimes hear revving their engines on the motorway. The 2014 supercar experience day, organised by members of CERN, will allow car lovers to go for a ride in style and all for a good cause!   Supercars at the 2013 experience day. Photo: Kevin Mazzilli. If you have always dreamt of sitting in a Ferrari, feeling the vibrations of a Lamborghini, or losing yourself in the hushed calm of a classic car, don’t miss the supercar experience day taking place on Sunday, 7 September! This event has been organised by CERN’s own car enthusiasts, in collaboration with the charity Kumansansa – Children of Zambia, founded by two CERN members. It will take place for the third consecutive year in the car park of the Macumba leisure centre in Saint-Julien-en-Genevois (France). From 9.30 a.m. to 6 p.m., visitors old and young (c...

  18. Bioturbation effects on bioaccumulation of cadmium in the wetland plant Typha latifolia: A nature-based experiment.

    Science.gov (United States)

    Hoang, Trung Kien; Probst, Anne; Orange, Didier; Gilbert, Franck; Elger, Arnaud; Kallerhoff, Jean; Laurent, François; Bassil, Sabina; Duong, Thi Thuy; Gerino, Magali

    2017-11-11

    The development of efficient bioremediation techniques to reduce aquatic pollutant load in natural sediment is one of the current challenges in ecological engineering. A nature-based solution for metal bioremediation is proposed through a combination of bioturbation and phytoremediation processes in experimental indoor microcosms. The invertebrates Tubifex tubifex (Oligochaeta Tubificidae) was used as an active ecological engineer for bioturbation enhancement. The riparian plant species Typha latifolia was selected for its efficiency in phyto-accumulating pollutants from sediment. Phytoremediation efficiency was estimated by using cadmium as a conservative pollutant known to bio-accumulate in plants, and initially introduced in the overlying water (20μg Cd/L of cadmium nitrate - Cd(NO3)2·4H2O). Biological sediment reworking by invertebrates' activity was quantified using luminophores (inert particulates). Our results showed that bioturbation caused by tubificid worms' activity followed the bio-conveying transport model with a downward vertical velocity (V) of luminophores ranging from 16.7±4.5 to 18.5±3.9cm·year-1. The biotransport changed the granulometric properties of the surface sediments, and this natural process was still efficient under cadmium contamination. The highest value of Cd enrichment coefficient for plant roots was observed in subsurface sediment layer (below 1cm to 5cm depth) with tubificids addition. We demonstrated that biotransport changed the distribution of cadmium across the sediment column as well as it enhanced the pumping of this metal from the surface to the anoxic sediment layers, thereby increasing the bioaccumulation of cadmium in the root system of Typha latifolia. This therefore highlights the potential of bioturbation as a tool to be considered in future as integrated bioremediation strategies of metallic polluted sediment in aquatic ecosystems. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Cadmium exposure and endometrial cancer risk: A large midwestern U.S. population-based case-control study.

    Directory of Open Access Journals (Sweden)

    Jane A McElroy

    Full Text Available Estrogen-mimicking chemicals, such as cadmium, may be associated with increased susceptibility to hormone-dependent cancers, though supporting data are sparse, particularly for endometrial cancer. The Health and Environmental Exposure Research (HEER study worked with the Arkansas Central Cancer Registry, Iowa Cancer Registry and Missouri Cancer Registry to obtain names of women diagnosed with endometrial cancer who were willing to be contacted for participation in our case control study. Voter registration lists from Iowa and Missouri were used to randomly select similarly aged women as represented in the case population. Participants were interviewed by telephone to obtain information on known or suspected endometrial risk factors. Urine kits were sent to participants for home collection and returned for analysis. Our case-control study consisted of 631 incident cases of endometrial cancer diagnosed from January 2010 to October 2012 and 879 age-matched population-based controls, ages 18-81 years (mean age 65 years. We quantified cadmium amounts in urine and standardized these values through creatinine adjustment. Using data from all survey completers, we developed a multivariable model for endometrial cancer. Creatinine-adjusted cadmium concentration was added to this model. Odds ratio (OR and 95% confidence intervals (CIs for endometrial cancer were calculated. After multivariable adjustment, higher creatinine-adjusted cadmium exposure was associated with a statistically significant increase of endometrial cancer risk (OR: 1.22; 95% CI: 1.03-1.44. Our results provide evidence that cadmium may increase the risk of endometrial cancer, possibly through estrogenic effects.

  20. Fluorescently labelled multiplex lateral flow immunoassay based on cadmium-free quantum dots.

    Science.gov (United States)

    Beloglazova, Natalia V; Sobolev, Aleksander M; Tessier, Mickael D; Hens, Zeger; Goryacheva, Irina Yu; De Saeger, Sarah

    2017-03-01

    A sensitive tool for simultaneous qualitative detection of two mycotoxins based on use of non-cadmium quantum dots (QDs) is presented for the first time. QDs have proven themselves as promising fluorescent labels for biolabeling and chemical analysis. With an increasing global tendency to regulate and limit the use of hazardous elements, indium phosphide (InP) QDs are highlighted as environmentally-friendly alternatives to the highly efficient and well-studied, but potentially toxic Cd- and Pb-based QDs. Here, we developed water-soluble InP QDs-based fluorescent nanostructures. They consisted of core/shell InP/ZnS QDs enrobed in a silica shell that allowed the water solubility (QD@SiO2). Then we applied the QD@SiO2 as novel, silica shell-encapsulated fluorescent labels in immunoassays for rapid multiplexed screening. Two mycotoxins, zearalenone and deoxynivalenol, were simultaneously detected in maize and wheat, since the two QD@SiO2 labelled conjugates emit at two different, individually detectable wavelengths. The cutoff values for the simultaneous determination were 50 and 500μgkg(-1) for zearalenone and deoxynivalenol, respectively, in both maize and wheat. Liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS) was used to confirm the result. Copyright © 2017 Elsevier Inc. All rights reserved.

  1. Bull Riding Injuries In Central Queensland

    Directory of Open Access Journals (Sweden)

    Ryan James Livingston

    2012-07-01

    Full Text Available Background Bull riding is an increasingly popular and growing professional sport in Australia. This is the first national study that investigates bull riding-related injuries. Method A six-year retrospective study of patients admitted to Rockhampton Base Hospital with acute injuries sustained whilst bull riding. Patients were identified from the Rockhampton Hospital international coding system and surgical audit excel databases. Supporting information was found from patient chart review. Results Thirty-eight patients were admitted during the study. Injuries increased from 2008. The most common injuries were to limbs (52%, chest (15% and brain (10%. Life-threatening injuries were all caused by a direct kick or trampling by the bull; 5% of patients needed air transfer to Brisbane, and 10% to Rockhampton for their acute care. The only complication was infection of open wounds. The average hospital stay was 2.2 (range= 1-5, SD= 1.1 days and 64% of patients required operative intervention. Conclusion Patients that had been kicked or trampled should be identified as having potentially life-threatening injuries, and transferred for review at an appropriate facility. Due to the high risk of infection all contaminated wounds should be washed out formally and receive antibiotics. Protective equipment should be encouraged among riders.

  2. Ride comfort optimization of a multi-axle heavy motorized wheel dump truck based on virtual and real prototype experiment integrated Kriging model

    Directory of Open Access Journals (Sweden)

    Bian Gong

    2015-06-01

    Full Text Available The optimization of hydro-pneumatic suspension parameters of a multi-axle heavy motorized wheel dump truck is carried out based on virtual and real prototype experiment integrated Kriging model in this article. The root mean square of vertical vibration acceleration, in the center of sprung mass, is assigned as the optimization objective. The constraints are the natural frequency, the working stroke, and the dynamic load of wheels. The suspension structure for the truck is the adjustable hydro-pneumatic suspension with ideal vehicle nonlinear characteristics, integrated with elastic and damping elements. Also, the hydraulic systems of two adjacent hydro-pneumatic suspension are interconnected. Considering the high complexity of the engineering model, a novel kind of meta-model called virtual and real prototype experiment integrated Kriging is proposed in this article. The interpolation principle and the construction of virtual and real prototype experiment integrated Kriging model were elucidated. Being different from traditional Kriging, virtual and real prototype experiment integrated Kriging combines the respective advantages of actual test and Computer Aided Engineering simulation. Based on the virtual and real prototype experiment integrated Kriging model, the optimization results, obtained by experimental verification, showed significant improvement in the ride comfort by 12.48% for front suspension and 11.79% for rear suspension. Compared with traditional Kriging, the optimization effect was improved by 3.05% and 3.38% respectively. Virtual and real prototype experiment integrated Kriging provides an effective way to approach the optimal solution for the optimization of high-complexity engineering problems.

  3. Electrochemical supercapacitors of cobalt hydroxide nanoplates grown on conducting cadmium oxide base-electrodes

    Directory of Open Access Journals (Sweden)

    Kailas K. Tehare

    2017-05-01

    Full Text Available Dopant-free and cost-effective sprayed cadmium oxide (CdO conducting base-electrodes, obtained at different concentrations (0.5, 1 and 1.5 M, characterized for their structures, morphologies and conductivities by using X-ray diffraction, scanning electron microscopy and electrical conductivity measurements, respectively, are employed as base-electrodes for growing cobalt hydroxide (Co(OH2 nanoplates using a simple electrodeposition method which further are envisaged for electrochemical supercapacitor application. Polycrystalline nature and mushroom-like plane-views are confirmed from the structure and morphology analyses. Both CdO and CdO–Co(OH2 electrodes reveal specific capacitances as high as 312 F g−1 and 1119 F g−1, respectively, in 0.1 M KOH electrolyte at 10 mV s−1 sweep rate. Optimized Co(OH2–CdO configuration electrode demonstrates energy density of 98.83 W h kg−1 and power density of 0.75 kW kg−1. In order to investigate the charge transfer kinematics electrochemical impedance measurements are carried out and explored.

  4. Toxicological impact of cadmium-based quantum dots towards aquatic biota: Effect of natural sunlight exposure

    Energy Technology Data Exchange (ETDEWEB)

    Silva, B.F. [Department of Biology, Faculty of Science, University of Porto, Rua do Campo Alegre, 4169-007 Porto (Portugal); CIIMAR, Interdisciplinary Centre of Marine and Environmental Research, Rua dos Bragas, 289, 4050-123 Porto (Portugal); Andreani, T. [Centro de Investigação em Química da Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Department of Chemistry and Biochemistry, Faculty of Science, University of Porto, Rua do Campo Alegre, 4169-007 Porto (Portugal); CITAB − Centre for Research and Technology of Agro-Environmental and Biological Sciences, University of Trás-os-Montes e Alto Douro, UTAD, Vila Real (Portugal); Gavina, A., E-mail: anacsgavina@gmail.com [Department of Biology, Faculty of Science, University of Porto, Rua do Campo Alegre, 4169-007 Porto (Portugal); CIIMAR, Interdisciplinary Centre of Marine and Environmental Research, Rua dos Bragas, 289, 4050-123 Porto (Portugal); Vieira, M.N. [Department of Biology, Faculty of Science, University of Porto, Rua do Campo Alegre, 4169-007 Porto (Portugal); CIIMAR, Interdisciplinary Centre of Marine and Environmental Research, Rua dos Bragas, 289, 4050-123 Porto (Portugal); Pereira, C.M. [Centro de Investigação em Química da Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Department of Chemistry and Biochemistry, Faculty of Science, University of Porto, Rua do Campo Alegre, 4169-007 Porto (Portugal); Rocha-Santos, T. [Department of Chemistry and Centre for Environmental and Marine Studies (CESAM), University of Aveiro, Campus de Santiago, 3810-193 Aveiro (Portugal); and others

    2016-07-15

    Highlights: • Under sunlight exposure, all QDs form particle aggregates in the different media. • CdSeS/ZnS QDs showed lower toxic effects to V. fischeri before sunlight exposure. • Sunlight exposure decreased the toxicity of CdS 480 in all organisms. • Sunlight exposure increased the toxicity of CdS 380 QDs for D. magna. • Shell of QDs seemed to make them less harmful to aquatic organisms. - Abstract: Cadmium-based quantum dots (QDs) are increasingly applied in existent and emerging technologies, especially in biological applications due to their exceptional photophysical and functionalization properties. However, they are very toxic compounds due to the high reactive and toxic cadmium core. The present study aimed to determine the toxicity of three different QDs (CdS 380, CdS 480 and CdSeS/ZnS) before and after the exposure of suspensions to sunlight, in order to assess the effect of environmentally relevant irradiation levels in their toxicity, which will act after their release to the environment. Therefore, a battery of ecotoxicological tests was performed with organisms that cover different functional and trophic levels, such as Vibrio fischeri, Raphidocelis subcapitata, Chlorella vulgaris and Daphnia magna. The results showed that core-shell type QDs showed lower toxic effects to V. fischeri in comparison to core type QDs before sunlight exposure. However, after sunlight exposure, there was a decrease of CdS 380 and CdS 480 QD toxicity to bacterium. Also, after sunlight exposure, an effective decrease of CdSeS/ZnS and CdS 480 toxicity for D. magna and R. subcapitata, and an evident increase in CdS 380 QD toxicity, at least for D. magna, were observed. The results of this study suggest that sunlight exposure has an effect in the aggregation and precipitation reactions of larger QDs, causing the degradation of functional groups and formation of larger bulks which may be less prone to photo-oxidation due to their diminished surface area. The same

  5. Circular dichroism sensor based on cadmium sulfide quantum dots for chiral identification and detection of penicillamine.

    Science.gov (United States)

    Ngamdee, Kessarin; Puangmali, Theerapong; Tuntulani, Thawatchai; Ngeontae, Wittaya

    2015-10-22

    A new chemical sensor based on the measuring of circular dichroism signal (CD) was fabricated from cysteamine capped cadmium sulfide quantum dots (Cys-CdS QDs). The chiral-thiol molecules, d-penicillamine (DPA) and l-penicillamine (LPA), were used to evaluate potentials of this sensor. Basically, DPA and LPA provide very low CD signals. However, the CD signals of DPA and LPA can be enhanced in the presence of Cys-CdS QDs. The CD spectra of DPA and LPA exhibited a mirror image profile. Parameters affecting the determination of DPA and LPA were thoroughly investigated in details. Under the optimized condition, the CD signals of DPA and LPA displayed a linear relationship with the concentrations of both enantiomers, ranging from 1 to 35 μM. Detection limits of this sensor were 0.49 and 0.74 μM for DPA and LPA, respectively. To demonstrate a potential application of this sensor, the proposed sensor was used to determine DPA and LPA in real urine samples. It was confirmed that the proposed detection technique was reliable and could be utilized in a broad range of applications. Copyright © 2015 Elsevier B.V. All rights reserved.

  6. A Label-Free Aptamer-Based Fluorescent Assay for Cadmium Detection

    Directory of Open Access Journals (Sweden)

    Yunxia Luan

    2016-12-01

    Full Text Available Selective detection of ultratrace amounts of cadmium (Cd2+ is extremely important for food safety and environmental monitoring because of its toxicity and widespread use. In this work, we developed a facile, rapid, sensitive, and highly selective method for the detection of Cd2+ based on a label-free aptasensor using an unmodified double-stranded deoxyribonucleic acid-specific dye (PicoGreen. The linear range was 0.10–100 µg/mL, and the detection limit (0.038 ng/mL was lower than the guideline from the World Health Organization for Cd2+ in drinking water (3 ng/mL. The sensor exhibited excellent selectivity towards Cd2+ ions. We tested the aptasensor in application to a series of real water samples spiked with different concentrations of Cd2+. Compared with atomic absorption spectrometry, the results showed good tolerance to the matrix effect. The developed approach shows great potential for on-site and high-throughput analysis in routine monitoring.

  7. An individual-based, spatial foraging model for cadmium accumulation in diving ducks

    Energy Technology Data Exchange (ETDEWEB)

    Lovvorn, J.R.; Gillingham, M.P. [Univ. of Wyoming, Laramie, WY (United States). Dept. of Zoology and Physiology

    1994-12-31

    Contaminant studies of migratory birds include two main approaches: (1) collecting wild birds and analyzing their tissues, and (2) toxicity assays with captive birds. The first approach has shortcomings for these highly mobile animals--one seldom knows their length of stay in the area, and sites are often in urban environments where shooting is problematic. The second approach with captive birds ignores changes in food intake with varying activity and weather experienced by wild birds, and greater toxic consequences under multiple environmental stresses. Neither of these approaches alone can predict maximum allowable contaminant levels in foods that preclude toxic effects under different field conditions, or what body burdens accumulate during varying lengths of stay and affect the birds` biology at other places and times. To allow such predictions, the authors developed an individual-based model for intake of benthic foods by diving ducks for varying weather, water depth, food dispersion, and nutrient content of food. Food-intake estimates are combined with laboratory data on contaminant uptake as a function of food consumption and contaminant content. As an example, the authors estimate cadmium uptake by canvas back ducks foraging on below ground tubers of the submerged plant Vallisneria americans. They then show how their model can be used to include avian benthiovores in aquatic food web models for ecological risk assessment.

  8. Rank-based biomarker index to assess cadmium ecotoxicity on the earthworm Eisenia andrei.

    Science.gov (United States)

    Panzarino, O; Hyršl, P; Dobeš, P; Vojtek, L; Vernile, P; Bari, G; Terzano, R; Spagnuolo, M; de Lillo, E

    2016-02-01

    A proper soil risk assessment needs to estimate the processes that affect the fate and the behaviour of a contaminant, which are influenced by soil biotic and abiotic components. For this reason, the measurement of biomarkers in soil bioindicator organisms, such as earthworms, has recently received increasing attention. In this study, the earthworm Eisenia andrei was used to assess the pollutant-induced stress syndrome after exposure to sublethal concentrations of Cd (10 or 100 μg g(-1)) in OECD soil, after 14 d of exposure. Cadmium bioaccumulation and potential biomarkers such as catalase (CAT), hydrogen peroxide (H2O2), glutathione-S-transferase (GST), malondialdehyde (MDA), phenoloxidase (PO), metallothioneins (MTs) and genotoxic damage were determined. Results suggested that the exposure to 10 and 100 μg g(-1) Cd significantly increased Cd bioaccumulation, MTs and MDA; 100 μg g(-1) Cd contamination evidenced significantly higher values of H2O2 content and PO activity; CAT activity was inhibited at the higher concentration while GST and Comet assay did not show any significant differences from the control. Rank-based biomarker index showed that both different contaminated soils had an effect on the earthworms and allowed to validate the ecotoxicological relevance of this battery of biomarkers for a promising integrated multi-marker approach in soil monitoring and assessment. Copyright © 2015 Elsevier Ltd. All rights reserved.

  9. An omics based assessment of cadmium toxicity in the green alga Chlamydomonas reinhardtii

    Energy Technology Data Exchange (ETDEWEB)

    Jamers, An; Blust, Ronny; De Coen, Wim [Laboratory for Ecophysiology, Biochemistry and Toxicology, Department of Biology, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp (Belgium); Griffin, Julian L. [Department of Biochemistry, University of Cambridge, 80 Tennis Court Road, Cambridge CB2 2QA (United Kingdom); Jones, Oliver A.H., E-mail: oliver.jones@rmit.edu.au [School of Applied Sciences, RMIT University, GPO Box 2476, Melbourne, VIC 3001 (Australia)

    2013-01-15

    The effects of cadmium were assessed in the freshwater alga Chlamydomonas reinhardtii. Algae were exposed to concentrations of 0, 8.1 or 114.8 {mu}M of cadmium and growth rates, gene transcription and metabolite profiles were examined after 48 and 72 h of exposure. In algae exposed to 8.1 {mu}M Cd, several genes were differentially transcribed after 48 h but no adverse growth related effects were detected. A transient effect on both gene transcription patterns and metabolite profiles could be discerned after 48 h of exposure but the majority of these changes disappeared after 72 h. In contrast, all effects were more pronounced at the 114.8 {mu}M cadmium exposure. Here growth was clearly reduced and transcription of a large number of genes involved in oxidative stress defense mechanisms was differentially increased. Metabolites involved in the glutathione synthesis pathway (an important antioxidant defense) were also affected but the effects of cadmium were found to be more pronounced at the transcript level than in the metabolome, suggesting that the former exhibits greater sensitivity toward cadmium exposure.

  10. Protection of Multiterminal HVDC Grids based on Modular Multilevel Converters: DC Fault Ride-Through and AC Grid Support

    OpenAIRE

    Kontos, E.

    2018-01-01

    High Voltage DC (HVDC) grids provide an efficient solution for the transmission of bulk power over long distances between the energy production and consumption centers. Up to now, most of the implemented dc connections are point-to-point, creating dc links to strengthen the existing, predominantly ac, electricity grid. However, to optimize the use of assets and energy harvest, multi-terminal HVdc grids are envisioned. Based on recent research and industrial trends, the Multilevel Modular Conv...

  11. 14 CFR 23.1399 - Riding light.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Riding light. 23.1399 Section 23.1399... STANDARDS: NORMAL, UTILITY, ACROBATIC, AND COMMUTER CATEGORY AIRPLANES Equipment Lights § 23.1399 Riding light. (a) Each riding (anchor) light required for a seaplane or amphibian, must be installed so that it...

  12. 14 CFR 29.1399 - Riding light.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Riding light. 29.1399 Section 29.1399... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Equipment Lights § 29.1399 Riding light. (a) Each riding light required for water operation must be installed so that it can— (1) Show a white light for at least two...

  13. 14 CFR 25.1399 - Riding light.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Riding light. 25.1399 Section 25.1399... STANDARDS: TRANSPORT CATEGORY AIRPLANES Equipment Lights § 25.1399 Riding light. (a) Each riding (anchor) light required for a seaplane or amphibian must be installed so that it can— (1) Show a white light for...

  14. 14 CFR 27.1399 - Riding light.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Riding light. 27.1399 Section 27.1399... STANDARDS: NORMAL CATEGORY ROTORCRAFT Equipment Lights § 27.1399 Riding light. (a) Each riding light required for water operation must be installed so that it can— (1) Show a white light for at least two...

  15. Modeling and mapping of cadmium in soils based on qualitative and quantitative auxiliary variables in a cadmium contaminated area.

    Science.gov (United States)

    Cao, Shanshan; Lu, Anxiang; Wang, Jihua; Huo, Lili

    2017-02-15

    The aim of this study was to measure the improvement in mapping accuracy of spatial distribution of Cd in soils by using geostatistical methods combined with auxiliary factors, especially qualitative variables. Significant correlations between Cd content and correlation environment variables that are easy to obtain (such as topographic factors, distance to residential area, land use types and soil types) were analyzed systematically and quantitatively. Based on 398 samples collected from a Cd contaminated area (Hunan Province, China), we estimated the spatial distribution of Cd in soils by using spatial interpolation models, including ordinary kriging (OK), and regression kriging (RK) with each auxiliary variable, all quantitative variables (RKWQ) and all auxiliary variables (RKWA). Results showed that mapping with RK was more consistent with the sampling data of the spatial distribution of Cd in the study area than mapping with OK. The performance indicators (smaller mean error, mean absolute error, root mean squared error values and higher relative improvement of RK than OK) indicated that the introduction of auxiliary variables can improve the prediction accuracy of Cd in soils for which the spatial structure could not be well captured by point-based observation (nugget to sill ratio=0.76) and strong relationships existed between variables to be predicted and auxiliary variables. The comparison of RKWA with RKWQ further indicated that the introduction of qualitative variables improved the prediction accuracy, and even weakened the effects of quantitative factors. Furthermore, the significantly different relative improvement with similar R2 and varying spatial dependence showed that a reasonable choice of auxiliary variables and analysis of spatial structure of regression residuals are equally important to ensure accurate predictions. Copyright © 2016. Published by Elsevier B.V.

  16. Microorganism and Agricultural Based Biosorbents Towards Removal of Cadmium from Waste-Water: An Overview.

    Science.gov (United States)

    Pal, Souvik; Mukherjee, Subhankar; Bhattacharyya, Nabarun

    2017-01-01

    Non-degradable and persistent nature of Cadmium (Cd) poses high toxicity to human, plants and animals. Several industrial processes generated wastes are the main anthropogenic pathway through which Cd enters into the environment. Although, World Health Organization (WHO) has set the limit of Cd in drinking water is 0.005 mg L-1, the industrial activities release much higher concentrations of metal ions to the water stream than the prescribed limits, which leads to the increasing health hazards and environmental pollution. To address this issue, one of the major applicable solutions is the treatment or purification of contaminated water and effluents. The implantation of wastewater treatment systems aims to minimize environmental impacts, but ultimately generates waste materials, such as sewage sludge, which must be properly recycled. In this review, we focus on the research efforts being made towards the removal of Cd (II) from waste waters using biological means with a special emphasis on the microorganism and agricultural based biosorbents. Mechanistic pathway towards removal of Cd (II) ions from the wastewater, efficiency of the adsorbents and the factors affecting the process have been studied with specific examples. Also the recent patents related to this area have been taken into considerations to understand applicability of microorganism and agricultural based biosorbents. This overview presents various scientific reports towards low-cost microorganism and agricultural based biosorbents for efficient removal of Cd (II) by producing less toxic waste and the future perspective of the process. Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

  17. Computational and Pharmacological Evaluation of Ferrocene-Based Acyl Ureas and Homoleptic Cadmium Carboxylate Derivatives for Anti-diabetic Potential.

    Science.gov (United States)

    Bano, Shahar; Khan, Arif-Ullah; Asghar, Faiza; Usman, Muhammad; Badshah, Amin; Ali, Saqib

    2017-01-01

    We investigated possible anti-diabetic effect of ferrocene-based acyl ureas: 4-ferrocenyl aniline (PFA), 1-(4-chlorobenzoyl)-3-(4-ferrocenylphenyl) urea (DPC1), 1-(3-chlorobenzoyl)-3-(4-ferrocenylphenyl) urea (DMC1), 1-(2-chlorobenzoyl)-3-(4-ferrocenylphenyl) urea (DOC1) and homoleptic cadmium carboxylates: bis (diphenylacetato) cadmium (II) (DPAA), bis (4-chlorophenylacetato) cadmium (II) (CPAA), using in silico and in vivo techniques. PFA, DPC1, DMC1, DOC1, DPAA and CPAA exhibited high binding affinities (ACE ≥ -350 Kcal/mol) against targets: aldose reductase, peroxisome proliferator-activated receptor γ, 11β-hydroxysteroid dehydrogenase-1, C-alpha glucosidase and glucokinase, while showed moderate affinities (ACE ≥ -250 Kcal/mol) against N-alpha glucosidase, dipeptidyl peptidase-IV, phosphorylated-Akt, glycogen synthase kinase-3β, fructose-1,6-bisphosphatase and phosphoenolpyruvate carboxykinase, whereas revealed lower affinities (ACE diabetic mice, DPAA and DPC1 (1-10 mg/Kg) at day 1, 5, 10, 15, and 20th decreased blood glucose levels, compared to diabetic control group and improved the treated animals body weight. DPAA (10 mg/Kg) and DPC1 (5 mg/Kg) in time-dependent manner (30-120 min.) enhanced tolerance of oral glucose overload in mice. DPAA and DPCI dose-dependently at 1, 5, and 10 mg/Kg decreased glycosylated hemoglobin levels in diabetic animals, as caused by metformin. These results indicate that aforementioned derivatives of ferrocene and cadmium possess anti-diabetic potential.

  18. Hippotherapy and Therapeutic Riding Highlight!

    Science.gov (United States)

    Apel, Laura, Comp.

    2007-01-01

    Horses have always been appreciated by humans for their strength, beauty, and gentle demeanor. Children, especially, have gravitated toward them and many experience their first horseback riding lesson at a young age. However, horses can play a very different role in the lives of children and adults with disabilities. Hippotherapy is physical,…

  19. Dynamic energy-based modeling of uranium and cadmium joint toxicity to Caenorhabditis elegans.

    Science.gov (United States)

    Margerit, Adrien; Gomez, Elena; Gilbin, Rodolphe

    2016-03-01

    Toxicokinetic - toxicodynamic energy-based models offer new alternatives to the commonly used approaches for the analysis of mixture toxicity data. Based on the Dynamic Energy Budget theory, DEBtox models enable the description of several endpoints over time simultaneously under the same framework. However, such model still has to be faced with experimental data in a multi-contamination context. In this study, the predictive capacities of a DEBtox model to describe the uranium and cadmium joint toxicity over the entire growth and reproduction period of the soil nematode Caenorhabditis elegans was examined. The two reference additivity approaches, Concentration Addition and Response addition, implemented in the DEBtox model were tested. Assuming no interaction between the two toxicants through Response addition, the DEBtox model allowed a rather accurate fit of the U and Cd joint effects on the growth and reproduction of C. elegans: an interaction between the two metals at the toxicokinetic or toxicodynamic level seems thus unlikely or has only minor consequences. Interestingly, this study underlines that even if the compounds of a mixture share the same DEBtox physiological mode of action (in this case a decrease in assimilation), the Response addition approach may provide a better fit of joint toxicity data than the Concentration addition approach. Moreover, the present work highlighted limitations in the model predictions which are related to the simplifications of the DEBtox framework and its adaptations to the physiology of C. elegans and which lead to an overestimation of the U and Cd joint toxicity in some cases. Copyright © 2015 Elsevier Ltd. All rights reserved.

  20. Cadmium zinc telluride based infrared interferometry for X-ray detection

    Energy Technology Data Exchange (ETDEWEB)

    Lohstroh, A., E-mail: A.Lohstroh@surrey.ac.uk; Della Rocca, I. [Department of Physics, University of Surrey, Guildford GU2 7XH (United Kingdom); Parsons, S. [Department of Physics, University of Surrey, Guildford GU2 7XH (United Kingdom); AWE Aldermaston, Reading RG7 4PR (United Kingdom); Langley, A.; Shenton-Taylor, C.; Blackie, D. [AWE Aldermaston, Reading RG7 4PR (United Kingdom)

    2015-02-09

    Cadmium Zinc Telluride (CZT) is a wide band gap semiconductor for room temperature radiation detection. The electro-optic Pockels effect of the material has been exploited in the past to study electric field non-uniformities and their consequence on conventional detector signals in CZT, by imaging the intensity distribution of infrared (IR) light transmitted through a device placed between crossed polarizers. Recently, quantitative monitoring of extremely high intensity neutron pulses through the change of transmitted IR intensity was demonstrated, offering the advantage to place sensitive electronics outside the measured radiation field. In this work, we demonstrate that X-ray intensity can be deduced directly from measuring the change in phase of 1550 nm laser light transmitted through a 7 × 7 × 2 mm{sup 3} CZT based Pockels cell in a simple Mach Zehnder interferometer. X-rays produced by a 50 kVp Mo X-ray tube incident on the CZT cathode surface placed at 7 mm distance cause a linearly increasing phase shift above 0.3 mA tube current, with 1.58 ± 0.02 rad per mA for an applied bias of 500 V across the 2 mm thick device. Pockels images confirm that the sample properties are in agreement with the literature, exhibiting electric field enhancement near the cathode under irradiation, which may cause the non-linearity at low X-ray tube anode current settings. The laser used to probe the X-ray intensity causes itself some space charge, whose spatial distribution does not seem to be exclusively determined by the incident laser position, i.e., charge carrier generation location, with respect to the electrodes.

  1. Recommended Rice Intake Levels Based on Average Daily Dose and Urinary Excretion of Cadmium in a Cadmium-Contaminated Area of Northwestern Thailand.

    Science.gov (United States)

    La-Up, Aroon; Wiwatanadate, Phongtape; Pruenglampoo, Sakda; Uthaikhup, Sureeporn

    2017-10-01

    This study was performed to investigate the dose-response relationship between average daily cadmium dose (ADCD) from rice and the occurrence of urinary cadmium (U-Cd) in individuals eating that rice. This was a retrospective cohort designed to compare populations from two areas with different levels of cadmium contamination. Five-hundred and sixty-seven participants aged 18 years or older were interviewed to estimate their rice intake, and were assessed for U-Cd. The sources of consumed rice were sampled for cadmium measurement, from which the ADCD was estimated. Binary logistic regression was used to examine the association between ADCD and U-Cd (cut-off point at 2 μg/g creatinine), and a correlation between them was established. The lowest estimate was ADCD = 0.5 μg/kg bw/day [odds ratio (OR) = 1.71; with a 95% confidence interval (CI) 1.02-2.87]. For comparison, the relationship in the contaminated area is expressed by ADCD = 0.7 μg/kg bw/day, OR = 1.84; [95 % CI, 1.06-3.19], while no relationship was found in the non-contaminated area, meaning that the highest level at which this relationship does not exist is ADCD = 0.6 μg/kg bw/day [95% CI, 0.99-2.95]. Rice, as a main staple food, is the most likely source of dietary cadmium. Abstaining from or limiting rice consumption, therefore, will increase the likelihood of maintaining U-Cd within the normal range. As the recommended maximum ADCD is not to exceed 0.6 μg/kg bw/day, the consumption of rice grown in cadmium-contaminated areas should not be more than 246.8 g/day. However, the exclusion of many edible plants grown in the contaminated area from the analysis might result in an estimated ADCD that does not reflect the true level of cadmium exposure among local people.

  2. Alcohol vapor sensing by cadmium-doped zinc oxide thick films based chemical sensor

    Science.gov (United States)

    Zargar, R. A.; Arora, M.; Chackrabarti, S.; Ahmad, S.; Kumar, J.; Hafiz, A. K.

    2016-04-01

    Cadmium-doped zinc oxide nanoparticles were derived by simple chemical co-precipitation route using zinc acetate dihydrate and cadmium acetate dihydrate as precursor materials. The thick films were casted from chemical co-precipitation route prepared nanoparticles by economic facile screen printing method. The structural, morphological, optical and electrical properties of the film were characterized relevant to alcohol vapor sensing application by powder XRD, SEM, UV-VIS and DC conductivity techniques. The response and sensitivity of alcohol (ethanol) vapor sensor are obtained from the recovery curves at optimum working temperature range from 20∘C to 50∘C. The result shows that maximum sensitivity of the sensor is observed at 25∘C operating temperature. On varying alcohol vapor concentration, minor variation in resistance has been observed. The sensing mechanism of sensor has been described in terms of physical adsorption and chemical absorption of alcohol vapors on cadmium-doped zinc oxide film surface and inside film lattice network through weak hydrogen bonding, respectively.

  3. Dosimetric studies of cadmium free alloy used in compensator based intensity modulated radiotherapy

    Science.gov (United States)

    Kaushik, Sandeep; Punia, Rajesh; Tyagi, Atul; Singh, Mann P.

    2017-10-01

    Aim of this study was to investigate dosimetric properties of cadmium free alloy which is used in compensator based intensity modulated radiotherapy (cIMRT). A mixture of lead, bismuth and tin was used to prepare the alloy whose melting point is 90-95 °C. Slabs of different thicknesses ranging from 0.71 cm to 6.14 cm were prepared. Density of alloy was measured by Archimedes' principle using water. For six megavolt (6 MV) photon beam energy transmission, linear effective attenuation coefficient (μeff), tissue phantom ratio (TPR1020), beam hardening, surface dose (Ds), percentage depth dose (PDD) and effect of scatter has been measured and analyzed for different field sizes and different thickness of compensator. Effect of extended source to detector distance (SDD) on transmissions and μeff was measured. The density of alloy was found to be 9.5456 g/cm3. At SDD of 100 cm, μeff was observed 0.4253 cm-1 for a field size of 10×10 cm 2. Calculated TPR1020 was found to be within 3% of experimental TPR1020 . It was found to be increasing with increasing thickness of compensator. Ds was found to decrease with thickness of compensator and increase with wider collimator opening due to increased scattered dose. Compensator slabs of 1 cm, 1.98 cm and 4.16 cm decreased surface dose by 4.2%, 6.1% and 9.5% respectively for a field size of 10×10 cm2 at 100 cm SDD. For small field size of 3×3 cm2 and 5×5 cm2 PDDs are increased from 3.0% to 5.5% of open beam PDDs as compensator thickness increased from 1 cm to 6.14 cm at a depth of 10 cm in water while variation in PDD is insignificant in for larger field sizes 10×10 cm2 to 20×20 cm2. A high degree of intensity modulation is essential in cIMRT and it can be achieved with this compensator material. Dosimetric properties analyzed in this study establish this alloy as a reliable, reusable, optimally dense and cost effective compensator material.

  4. Evaluation of ride quality measurement procedures by subjective experiments using simulators

    Science.gov (United States)

    Klauder, L. T., Jr.; Clevenson, S. A.

    1975-01-01

    Since ride quality is, by definition, a matter of passenger response, there is need for a qualification procedure (QP) for establishing the degree to which any particular ride quality measurement procedure (RQMP) does correlate with passenger responses. Once established, such a QP will provide very useful guidance for optimal adjustment of the various parameters which any given RQMP contains. A QP is proposed based on use of a ride motion simulator and on test subject responses to recordings of actual vehicle motions. Test subject responses are used to determine simulator gain settings for the individual recordings such as to make all of the simulated rides equally uncomfortable to the test subjects. Simulator platform accelerations vs. time are recorded with each ride at its equal discomfort gain setting. The equal discomfort platform acceleration recordings are then digitzed.

  5. A proposal for revising TXDOT ride specification to account for ride quality improvement.

    Science.gov (United States)

    2017-03-01

    The objectives of this project were to i) develop a rational and financially justifiable pay adjustment system that incorporates new versus old ride quality and ii) evaluate the existing techniques to measure ride quality using Surface Te...

  6. ReRide: Performing Lower Back Rehabilitation While Riding Your Motorbike in Traffic

    DEFF Research Database (Denmark)

    Bagalkot, Naveen; Sokoler, Tomas; Baadkar, Suraj

    2016-01-01

    What if a person with lower back problem could perform prescribed exercises while riding a motorbike in city traffic? In this paper we present our ReRide design experiment. The ReRide interactive sketch uses a belt with embedded flex sensor to obtain back posture data, and a microprocessor...... be designed to help integrate physical rehabilitation with everyday activities....

  7. ReRide: Performing Lower Back Rehabilitation While Riding Your Motorbike in Traffic

    DEFF Research Database (Denmark)

    Bagalkot, Naveen; Sokoler, Tomas; Baadkar, Suraj

    2016-01-01

    What if a person with lower back problem could perform prescribed exercises while riding a motorbike in city traffic? In this paper we present our ReRide design experiment. The ReRide interactive sketch uses a belt with embedded flex sensor to obtain back posture data, and a microprocessor...

  8. Safety in Riding Programs: A Director's Guide.

    Science.gov (United States)

    Kpachavi, Teresa

    1996-01-01

    Camp riding programs should be examined regularly for liability and risk management issues. Elements of a basic safety assessment include requiring proper safety apparel, removing obstructions from riding rings, ensuring doors and gates are closed, requiring use of lead ropes, securing equine medications, banning smoking, posting written…

  9. The Theory of Dynamic Public Transit Priority with Dynamic Stochastic Park and Ride

    Directory of Open Access Journals (Sweden)

    Chengming Zhu

    2014-01-01

    Full Text Available Public transit priority is very important for relieving traffic congestion. The connotation of dynamic public transit priority and dynamic stochastic park and ride is presented. Based on the point that the travel cost of public transit is not higher than the travel cost of car, how to determine the level of dynamic public transit priority is discussed. The traffic organization method of dynamic public transit priority is introduced. For dynamic stochastic park and ride, layout principle, scale, and charging standard are discussed. Traveler acceptability is high through the analysis of questionnaire survey. Dynamic public transit priority with dynamic stochastic park and ride has application feasibility.

  10. Synthesis of bifunctional receptor for fluoride and cadmium based on calix[4]arene with thiourea moieties

    Science.gov (United States)

    Quiroga-Campano, C.; Gómez-Machuca, H.; Moris, S.; Jara, P.; De la Fuente, J. R.; Pessoa-Mahana, H.; Jullian, C.; Saitz, C.

    2017-08-01

    A new calix[4]arene thiourea derivative bearing a benzothiazolyl moiety (L) was synthetized and characterized by single crystal X-ray, NMR and ESI-TOF. The binding ability of the bifunctional receptor towards several ions was investigated in acetonitrile by means of UV-Visible and NMR spectroscopy. The UV-Vis studies of receptor L demonstrated a stoichiometry of 1:1 for all ions studied. Also, recognize selectively F- and Cd2+ with a detection limit of 97 and 37 μM, respectively. Also, 1H NMR titration of receptor L indicated that both thiourea bridge and phenolic hydroxyl functional groups played a critical role in the binding of F- and Cd2+ ions. 1H NMR spectrum showed that receptor L has a flattened-cone conformation in solution that changes to a cone conformation in the presence of fluoride while cadmium maintained the initial conformation.

  11. A COMPARATIVE ANALYSIS OF SILICON AND CADMIUM TELLURIDE BASED SOLAR CELLS

    Directory of Open Access Journals (Sweden)

    Amjad Al QASSEM

    2016-12-01

    Full Text Available A compartive analzsis of silicon solar cells and of those containing a CdTe thin film which are widely used in solar energetics, particullarilly, in photovoltaic modules fabrication, is brought in this paper. The silicon is largely used in solar cells fabrication due to the low cost of solar cells production related to the low cost of the semiconductor fabrication and to the advanced material processing technology, when at the same time cadmium telluride has the wide use due to the fact that its fundamental parameters can provide theoretically a high value of efficiency of solar energy conversion into electrical one of 30%. The structure and photoelectrical parameters of silicon solar cells and of those cotaining a thin cadmium telluride layer are considered.ANALIZA COMPARATIVĂ A CELULELOR SOLARE DIN SILICIU ŞI TELURURA DE CADMIUÎn lucrarea de faţă este prezentată analiza comparativă a celulelor solare fabricate din siliciu şi a celor cu strat subţire de CdTe, care sunt pe larg utilizate în energetica solară, în particular la producerea modulelor fotovoltaice. Siliciul este intens folosit în fabricarea celulelor solare datorită costului redus al materialului semiconductor şi tehnologiei avansate de procesare, pe când telurura de cadmiu are o utilizare tot mai largă care, datorită parametrilor fundamentali, poate asigura teoretic o valoare înaltă a eficienţei conversiei energiei solare în cea electrică de (30%. Sunt considerate structura şi parametrii fotoelectrici ai celulelor solare din siliciu şi ai celor cu strat subţire de telurură de cadmiu.

  12. Ionic liquid-based ultrasound-assisted dispersive liquid-liquid microextraction combined with electrothermal atomic absorption spectrometry for a sensitive determination of cadmium in water samples

    Science.gov (United States)

    Li, Shengqing; Cai, Shun; Hu, Wei; Chen, Hao; Liu, Hanlan

    2009-07-01

    A new method was developed for the determination of cadmium in water samples using ionic liquid-based ultrasound-assisted dispersive liquid-liquid microextraction (IL-based USA-DLLME) followed by electrothermal atomic absorption spectrometry (ETAAS). The IL-based USA-DLLME procedure is free of volatile organic solvents, and there is no need for a dispersive solvent, in contrast to conventional DLLME. The ionic liquid, 1-hexyl-3-methylimidazolium hexafluorophosphate (HMIMPF 6), was quickly disrupted by an ultrasonic probe for 1 min and dispersed in water samples like a cloud. At this stage, a hydrophobic cadmium-DDTC complex was formed and extracted into the fine droplets of HMIMPF 6. After centrifugation, the concentration of the enriched cadmium in the sedimented phase was determined by ETAAS. Some effective parameters of the complex formation and microextraction, such as the concentration of the chelating agent, the pH, the volume of the extraction solvent, the extraction time, and the salt effect, have been optimized. Under optimal conditions, a high extraction efficiency and selectivity were reached for the extraction of 1.0 ng of cadmium in 10.0 mL of water solution employing 73 µL of HMIMPF 6 as the extraction solvent. The enrichment factor of the method is 67. The detection limit was 7.4 ng L - 1 , and the characteristic mass ( m0, 0.0044 absorbance) of the proposed method was 0.02 pg for cadmium (Cd). The relative standard deviation (RSD) for 11 replicates of 50 ng L - 1 Cd was 3.3%. The method was applied to the analysis of tap, well, river, and lake water samples and the Environmental Water Reference Material GSBZ 50009-88 (200921). The recoveries of spiked samples were in the range of 87.2-106%.

  13. Cardiorespiratory and neuromuscular responses to motocross riding.

    Science.gov (United States)

    Konttinen, Tomi; Kyröläinen, Heikki; Häkkinen, Keijo

    2008-01-01

    The aim of the present study was to examine physiological and neuromuscular responses during motocross riding at individual maximal speed together with the riding-induced changes in maximal isometric force production. Seven A-level (group A) and 5 hobby-class (group H) motocross-riders performed a 30-minute riding test on a motocross track and maximal muscle strength and oxygen uptake (VO2max) tests in a laboratory. During the riding the mean (+/-SD) VO2 reduced in group A from 86 +/- 10% to 69 +/- 6% of the maximum (P physical stress and demands on both skill and physical capacity of the rider. Physical stress occurs as the result of handling of the bike when receiving continuous impacts in the situation requiring both aerobic and anaerobic metabolism. Our data suggest that both maximal capacity and strain during the ride should be measured to analyze the true physiological and neuromuscular demands of motocross ride. For the practice, this study strongly suggests to train not only aerobic and anaerobic capacity but also to use strength and power training for successful motocross riding.

  14. Cyclist's nodule: no smooth ride.

    Science.gov (United States)

    Stoneham, Adam; Thway, Khin; Messiou, Christina; Smith, Myles

    2016-03-10

    A fit and active amateur cyclist was referred by his general practitioner to a surgical oncology outpatient clinic with a slowly-growing perineal mass. Following clinical examination, the patient underwent imaging and biopsy at a tertiary soft tissue tumour centre, which diagnosed perineal nodular induration: a rare, benign tumour caused by repetitive trauma associated with 'saddle sports' such as cycling or horse riding. It is important to consider soft tissue tumours in patients who present with 'lumps and bumps'; they can occur anywhere in the body including the groin or perineum, where it is sometimes referred to as a 'third' or 'accessory' testicle in men. Although unusual, the case emphasises the importance of rapid specialist referral from primary care, and consideration of a patient's occupation and hobbies when formulating diagnoses. 2016 BMJ Publishing Group Ltd.

  15. Feedback inhibition by thiols outranks glutathione depletion: a luciferase-based screen reveals glutathione-deficient γ-ECS and glutathione synthetase mutants impaired in cadmium-induced sulfate assimilation.

    Science.gov (United States)

    Jobe, Timothy O; Sung, Dong-Yul; Akmakjian, Garo; Pham, Allis; Komives, Elizabeth A; Mendoza-Cózatl, David G; Schroeder, Julian I

    2012-06-01

    Plants exposed to heavy metals rapidly induce changes in gene expression that activate and enhance detoxification mechanisms, including toxic-metal chelation and the scavenging of reactive oxygen species. However, the mechanisms mediating toxic heavy metal-induced gene expression remain largely unknown. To genetically elucidate cadmium-specific transcriptional responses in Arabidopsis, we designed a genetic screen based on the activation of a cadmium-inducible reporter gene. Microarray studies identified a high-affinity sulfate transporter (SULTR1;2) among the most robust and rapid cadmium-inducible transcripts. The SULTR1;2 promoter (2.2 kb) was fused with the firefly luciferase reporter gene to quantitatively report the transcriptional response of plants exposed to cadmium. Stably transformed luciferase reporter lines were ethyl methanesulfonate (EMS) mutagenized, and stable M(2) seedlings were screened for an abnormal luciferase response during exposure to cadmium. The screen identified non-allelic mutant lines that fell into one of three categories: (i) super response to cadmium (SRC) mutants; (ii) constitutive response to cadmium (CRC) mutants; or (iii) non-response and reduced response to cadmium (NRC) mutants. Two nrc mutants, nrc1 and nrc2, were mapped, cloned and further characterized. The nrc1 mutation was mapped to the γ-glutamylcysteine synthetase gene and the nrc2 mutation was identified as the first viable recessive mutant allele in the glutathione synthetase gene. Moreover, genetic, HPLC mass spectrometry, and gene expression analysis of the nrc1 and nrc2 mutants, revealed that intracellular glutathione depletion alone would be insufficient to induce gene expression of sulfate uptake and assimilation mechanisms. Our results modify the glutathione-depletion driven model for sulfate assimilation gene induction during cadmium stress, and suggest that an enhanced oxidative state and depletion of upstream thiols, in addition to glutathione depletion

  16. ORide: A Privacy-Preserving yet Accountable Ride-Hailing Service

    OpenAIRE

    Pham, Anh; Dacosta, Italo; Endignoux, Guillaume; Troncoso-Pastoriza, Juan,; Huguenin, Kévin; Hubaux, Jean-Pierre

    2017-01-01

    International audience; In recent years, ride-hailing services (RHSs) have be- come increasingly popular, serving millions of users per day. Such systems, however, raise significant privacy concerns, because service providers are able to track the precise mobility patterns of all riders and drivers. In this paper, we propose ORide (Oblivious Ride), a privacy- preserving RHS based on somewhat-homomorphic en- cryption with optimizations such as ciphertext packing and transformed processing. Wit...

  17. The Theory of Dynamic Public Transit Priority with Dynamic Stochastic Park and Ride

    OpenAIRE

    Zhu, Chengming; Chen, Yanyan; Ma, Changxi

    2014-01-01

    Public transit priority is very important for relieving traffic congestion. The connotation of dynamic public transit priority and dynamic stochastic park and ride is presented. Based on the point that the travel cost of public transit is not higher than the travel cost of car, how to determine the level of dynamic public transit priority is discussed. The traffic organization method of dynamic public transit priority is introduced. For dynamic stochastic park and ride, layout principle, scal...

  18. Crystal structures and luminescence of two cadmium-carboxylate cluster-based compounds with mixed ligands

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Hui-Fang; Lei, Qian; Wang, Yu-Ling; Yin, Shun-Gao; Liu, Qing-Yan [College of Chemistry and Chemical Engineering and Key Lab. of Functional Small Organic Molecule of Ministry of Education, Jiangxi Normal Univ., Nanchang (China)

    2017-04-04

    Reactions of Cd(NO{sub 3}){sub 2}.4H{sub 2}O with 2-quinolinecarboxylic acid (H-QLC) in the presence of 1,4-benzenedicarboxylic acid (H{sub 2}-BDC) or 1,3,5-benzenetricarboxylic acid (H-BTC) in DMF/H{sub 2}O solvent afforded two compounds, namely, [Cd(QLC)(BDC){sub 1/2}(H{sub 2}O)]{sub n} (1) and [Cd(QLC)(BTC){sub 1/3}]{sub n} (2). Both compounds are two-dimensional (2D) frameworks but feature different cadmium-carboxylate clusters as a result of the presence of the polycarboxylate ligands with different geometries and coordination preference. The dinuclear Cd{sub 2}(QLC){sub 2} units in 1 are bridged by the pairs of bridging water ligands to give a one-dimensional (1D) chain, which is further linked by the second ligand of BDC{sup 2-} to form a 2D structure. Compound 2 is constructed from unique hexanuclear macrometallacyclic Cd{sub 6}(QLC){sub 6} clusters, which are linked by the surrounding BTC{sup 3-} ligands to generate a 2D structure. Photoluminescence studies showed both compounds exhibit ligand-centered luminescent emissions with emission maxima at 405 and 401 nm, respectively. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  19. Analysis of electrical parameters in heterojunctions based on poly 3-octylthiophene and cadmium sulfide thin films

    Energy Technology Data Exchange (ETDEWEB)

    Salinas, Oscar H.; Lopez-Mata, C.; Hu, Hailin [Centro de investigacion en Energia, UNAM, Av.Xochicalco S/N, Temixco, Morelos, 62580 (Mexico); Nicho, M.E. [CIICAp-UAEM, Cuernavaca, Morelos (Mexico)

    2006-09-22

    Planar hybrid heterojunctions were built with poly 3-octylthiophene (P3OT) and chemical bath-deposited cadmium sulfide (CdS) thin films on a conductive glass substrate. The organic material, P3OT, acts as a light absorber and the inorganic one, CdS, as the electron acceptor. Two types of CdS films had been used: one is as-deposited and the other doped with HgCl{sub 2}. Heterojunctions were formed by casting a chemically synthesized P3OT solution onto CdS films. The P3OT film thickness was also varied for heterojunction studies. Current vs. potential (I-V) characterizations under dark and illumination conditions were performed for the P3OT/CdS heterojunctions under 88mW/cm{sup 2} irradiance level, which show photovoltaic effect with different open circuit voltage (V{sub OC}) levels, being as high as 1V for some devices. A parametric analysis of I-V curves details the effect of CdS resistivity and P3OT film thickness on series and shunt resistance of the heterojunctions. (author)

  20. DNA methylation is differentially associated with environmental cadmium exposure based on sex and smoking status.

    Science.gov (United States)

    Virani, Shama; Rentschler, Katie M; Nishijo, Muneko; Ruangyuttikarn, Werawan; Swaddiwudhipong, Witaya; Basu, Niladri; Rozek, Laura S

    2016-02-01

    The adverse health effects of cadmium (Cd) are well known in human populations; however, much of what is known about biological mechanisms of Cd comes from in vitro and animal studies. The adverse health outcomes due to high levels of Cd exposure in the population of Mae Sot, Thailand have been extensively characterized. Here, for the first time, this population is being studied in an epigenetic context. The objective of this study was to characterize the association between DNA methylation markers and Cd exposure, taking into account sex and smoking differences, in an adult population at an increased risk of experiencing adverse health outcomes from high body burden of Cd. One hundred and sixty-nine residents from known exposure areas of Mae Sot, Thailand and one hundred residents from non-exposed areas nearby were surveyed in 2012. Urine and blood samples were collected for measurement of urinary Cd (UCd) and DNA methylation of Cd-related markers (DNMT3B, MGMT, LINE-1, MT2A). UCd levels were 7 times higher in the exposed compared to the unexposed populations (exposed median: 7.4 μg/L, unexposed median: 1.0 μg/L, p smoking status. In summary, environmental Cd exposure is associated with gene-specific DNA methylation in a sex and smoking dependent manner. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

  1. Properties of Cadmium-(bisdodecylthiolate and Polymeric Composites Based on It

    Directory of Open Access Journals (Sweden)

    Nadezhda Agareva

    2015-12-01

    Full Text Available We study the thermo-physical and photoluminescence (PL properties of cadmium-(bisdodecylthiolate (Cd(C12H25S2. Significant attention is drawn to characterization of Cd(C12H25S2 by different methods. The laser-induced PLs of Cd(C12H25S2 and Cd(C12H25S2/(polymethyl methacrylate (PMMA composites are studied. Samples of Cd(C12H25S2/PMMA are synthesized by the polymerization method. Ultraviolet (UV-pulsed laser irradiation of the samples under relatively small fluences leads to the formation of induced PL with the maximum near the wavelength of 600 nm. This process can be attributed to the transformation of Cd(C12H25S2 within the precursor grains. Another PL peak at 450–500 nm, which appears under the higher fluences, relies on the formation of CdS complexes with a significant impact of the polymer matrix.

  2. Coordinated Control of a Doubly-Fed Induction Generator-Based Wind Farm and a Static Synchronous Compensator for Low Voltage Ride-through Grid Code Compliance during Asymmetrical Grid Faults

    Directory of Open Access Journals (Sweden)

    Hua Geng

    2013-09-01

    Full Text Available This paper aims to explore a viable solution for a doubly-fed induction generator (DFIG-based wind farm to meet the reactive support requirement of the low voltage ride-through (LVRT grid code with safe grid-connected operation during asymmetrical grid faults. First, the control scheme for the DFIG-based wind energy conversion system (WECS is designed. Then, the controllability issue is analyzed by means of an optimal method, and the derived controllable regions indicate that the DFIG-based WECS can only remain controllable under mild asymmetrical fault situations. Afterwards, the static synchronous compensator (STATCOM is introduced as extra equipment to ensure that the DFIG-based wind farm remains controllable under severe asymmetrical fault situations. For this purpose, a voltage compensation control scheme and a corresponding capacity matching method for the STATCOM are proposed. The simulation results verify that, with the proposed coordinated control between the DFIG-based wind farm and the STATCOM, the required positive-sequence reactive current can be supplied to support the power grid. The oscillations on the electromagnetic torque and direct current (DC-link voltage of the DFIG-based WECS can also be eliminated. Therefore, the control scheme can be helpful to improve the reliability of both the wind farm and the power system during grid faults.

  3. Effects of alcohol on motorcycle riding skills

    Science.gov (United States)

    2007-12-01

    Alcohol is known to disrupt the effect of neurotransmitters and impair various psychomotor skills. Indeed, alcohol intoxication is a significant risk factor for fatal traffic crashes, especially when riding a motorcycle. At present, there is sparse r...

  4. Regional Park-n-Ride Facilities

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — The Southwestern Pennsylvania Commission maintains an inventory of the region’s park-n-ride facilities that contains detailed information for each of the more than...

  5. Cadmium bioavailability from vegetable and animal-based foods assessed with in vitro digestion/caco-2 cell model.

    Science.gov (United States)

    Chunhabundit, Rodjana; Srianujata, Songsak; Bunyaratvej, Ahnond; Kongkachuichai, Ratchanee; Satayavivad, Jutamadd; Kaojarern, Sming

    2011-02-01

    Chronic dietary cadmium (Cd) exposure results in kidney dysfunction and decrease in bone mineral density. To determine and compare the bioavailability of Cd from vegetable and animal-based foods. Caco-2 cells were exposed to Cd in boiled pig kidney, ark shell, kale, raw kale, mixed boiled pig kidney with raw kale and CdCl2 after in vitro digestion. Then cellular Cd uptake from the digests and reference CdCl2 solution was measured by atomic absorption spectrometry. Cd bioavailability from animal-based foods was higher than that from vegetable-based foods. In addition, raw kale exhibited an inhibitory effect on Cd bioavailability when mixed with boiled pig kidney. However Cd in kale was increasingly absorbed after boiling. Cd binding to different molecular species, other food components in vegetable and animal-based foods, food combination, as well as cooking processes influenced the uptake of dietary Cd. A relative bioavailability factor accounted for the food matrix might be necessary for exposure assessment and consequently for estimation and prevention of the risk of dietary Cd.

  6. NMR-based metabolomic studies on the toxicological effects of cadmium and copper on green mussels Perna viridis

    Energy Technology Data Exchange (ETDEWEB)

    Wu Huifeng [Section of Marine Ecology and Biotechnology, Division of Life Science, Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Kowloon (Hong Kong); Wang Wenxiong, E-mail: wwang@ust.hk [Section of Marine Ecology and Biotechnology, Division of Life Science, Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Kowloon (Hong Kong)

    2010-11-15

    Traditional toxicology studies have focused on selected biomarkers to characterize the biological stress induced by metals in marine organisms. In this study, a system biology tool, metabolomics, was applied to the marine mussel Perna viridis to investigate changes in the metabolic profiles of soft tissue as a response to copper (Cu) and cadmium (Cd), both as single metal and as a mixture. The major metabolite changes corresponding to metal exposure are related to amino acids, osmolytes, and energy metabolites. Following metal exposure for 1 week, there was a significant increase in the levels of branched chain amino acids, histidine, glutamate, glutamine, hypotaurine, dimethylglycine, arginine and ATP/ADP. For the Cu + Cd co-exposed mussels, the levels of lactate, branched chain amino acid, succinate, and NAD increased, whereas the levels of glucose, glycogen, and ATP/ADP decreased, indicating a different metabolic profile for the single metal exposure groups. After 2 weeks of exposure, the mussels showed acclimatization to Cd exposure based on the recovery of some metabolites. However, the metabolic profile induced by the metal mixture was very similar to that from Cu exposure, suggesting that Cu dominantly induced the metabolic disturbances. Both Cu and Cd may lead to neurotoxicity, disturbances in energy metabolism, and osmoregulation changes. These results demonstrate the high applicability and reliability of NMR-based metabolomics in interpreting the toxicological mechanisms of metals using global metabolic biomarkers.

  7. Toxicological effects induced by cadmium in gills of Manila clam ruditapes philippinarum using NMR-based metabolomics

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Linbao; Liu, Xiaoli; You, Liping; Zhou, Di [Key Laboratory of Coastal Zone Environment Processes, CAS, Shandong Provincial Key Laboratory of Coastal Zone Environment Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai (China); The Graduate School of Chinese Academy of Sciences, Beijing (China); Yu, Junbao; Zhao, Jianmin; Wu, Huifeng [Key Laboratory of Coastal Zone Environment Processes, CAS, Shandong Provincial Key Laboratory of Coastal Zone Environment Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai (China); Feng, Jianghua [Department of Electronic Science, Fujian Key Laboratory of Plasma and Magnetic Resonance, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen (China)

    2011-11-15

    Cadmium (Cd) has become an important heavy metal contaminant in the sediment and seawater along the Bohai Sea and been of great ecological risk due to its toxic effects to marine organisms. In this work, the toxicological effects caused by environmentally relevant concentrations (10 and 40 {mu}g L{sup -1}) of Cd were studied in the gill tissues of Manila clam Ruditapes philippinarum after exposure for 24, 48, and 96 h. Both low (10 {mu}g L{sup -1}) and high (40 {mu}g L{sup -1}) doses of Cd caused the disturbances in energy metabolism and osmotic regulation and neurotoxicity based on the metabolic biomarkers such as succinate, alanine, branched chain amino acids, betaine, hypotaurine, and glutamate in clam gills after 24 h of exposure. However, the recovery of toxicological effects of Cd after exposure for 96 h was obviously observed in clam to Cd exposures. Overall, these results indicated that NMR-based metabolomics was applicable to elucidate the toxicological effects of heavy metal contaminants in the marine bioindicator. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. Proteomic analysis provides insights into the molecular bases of hydrogen gas-induced cadmium resistance in Medicago sativa.

    Science.gov (United States)

    Dai, Chen; Cui, Weiti; Pan, Jincheng; Xie, Yanjie; Wang, Jin; Shen, Wenbiao

    2017-01-30

    Recently, molecular hydrogen (H2) has emerged as a bio-regulator both in animals and plants. Normally, functions of endogenous generated H2 could be mimicked by exogenously applied hydrogen-rich water (HRW) or hydrogen-rich saline (particularly in animals). Although alfalfa seedlings showed more cadmium (Cd) resistance after the administration with HRW, corresponding molecular mechanism is still elusive. To address this gap, iTRAQ-based quantitative proteomics was used. The results showed that a total of 2377 proteins were identified with Medicago sativa is a widely used forage around the world. Recently, hydrogen gas (H2) was suggested as a candidate of signal molecule, and found to effectively attenuate Cd-induced damage in alfalfa seedlings. However, the underlying molecular mechanism still needs to be further elucidated. In the present work, an iTRAQ-based quantitative proteomics was firstly carried out, and the results revealed the main molecular targets and metabolic processes associated with Cd resistance conferred by H2. This study may expand our understanding of hydrogen gas-medicated heavy metal tolerance in plants. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. PrivateRide: A Privacy-Enhanced Ride-Hailing Service

    Directory of Open Access Journals (Sweden)

    Pham Anh

    2017-04-01

    Full Text Available In the past few years, we have witnessed a rise in the popularity of ride-hailing services (RHSs, an online marketplace that enables accredited drivers to use their own cars to drive ride-hailing users. Unlike other transportation services, RHSs raise significant privacy concerns, as providers are able to track the precise mobility patterns of millions of riders worldwide. We present the first survey and analysis of the privacy threats in RHSs. Our analysis exposes high-risk privacy threats that do not occur in conventional taxi services. Therefore, we propose PrivateRide, a privacy-enhancing and practical solution that offers anonymity and location privacy for riders, and protects drivers’ information from harvesting attacks. PrivateRide lowers the high-risk privacy threats in RHSs to a level that is at least as low as that of many taxi services. Using real data-sets from Uber and taxi rides, we show that PrivateRide significantly enhances riders’ privacy, while preserving tangible accuracy in ride matching and fare calculation, with only negligible effects on convenience. Moreover, by using our Android implementation for experimental evaluations, we show that PrivateRide’s overhead during ride setup is negligible. In short, we enable privacy-conscious riders to achieve levels of privacy that are not possible in current RHSs and even in some conventional taxi services, thereby offering a potential business differentiator.

  10. Harvesting Energy from the Counterbalancing (Weaving Movement in Bicycle Riding

    Directory of Open Access Journals (Sweden)

    Shashank Priya

    2012-07-01

    Full Text Available Bicycles are known to be rich source of kinetic energy, some of which is available for harvesting during speedy and balanced maneuvers by the user. A conventional dynamo attached to the rim can generate a large amount of output power at an expense of extra energy input from the user. However, when applying energy conversion technology to human powered equipments, it is important to minimize the increase in extra muscular activity and to maximize the efficiency of human movements. This study proposes a novel energy harvesting methodology that utilizes lateral oscillation of bicycle frame (weaving caused by user weight shifting movements in order to increase the pedaling force in uphill riding or during quick speed-up. Based on the 3D motion analysis, we designed and implemented the prototype of an electro-dynamic energy harvester that can be mounted on the bicycle’s handlebar to collect energy from the side-to-side movement. The harvester was found to generate substantial electric output power of 6.6 mW from normal road riding. It was able to generate power even during uphill riding which has never been shown with other approaches. Moreover, harvesting of energy from weaving motion seems to increase the economy of cycling by helping efficient usage of human power.

  11. Harvesting energy from the counterbalancing (weaving) movement in bicycle riding.

    Science.gov (United States)

    Yang, Yoonseok; Yeo, Jeongjin; Priya, Shashank

    2012-01-01

    Bicycles are known to be rich source of kinetic energy, some of which is available for harvesting during speedy and balanced maneuvers by the user. A conventional dynamo attached to the rim can generate a large amount of output power at an expense of extra energy input from the user. However, when applying energy conversion technology to human powered equipments, it is important to minimize the increase in extra muscular activity and to maximize the efficiency of human movements. This study proposes a novel energy harvesting methodology that utilizes lateral oscillation of bicycle frame (weaving) caused by user weight shifting movements in order to increase the pedaling force in uphill riding or during quick speed-up. Based on the 3D motion analysis, we designed and implemented the prototype of an electro-dynamic energy harvester that can be mounted on the bicycle's handlebar to collect energy from the side-to-side movement. The harvester was found to generate substantial electric output power of 6.6 mW from normal road riding. It was able to generate power even during uphill riding which has never been shown with other approaches. Moreover, harvesting of energy from weaving motion seems to increase the economy of cycling by helping efficient usage of human power.

  12. Cadmium sulfide membranes

    Science.gov (United States)

    Spanhel, Lubomir; Anderson, Marc A.

    1991-10-22

    A method is described for the creation of novel q-effect cadmium sulfide membranes. The membranes are made by first creating a dilute cadmium sulfide colloid in aqueous suspension and then removing the water and excess salts therefrom. The cadmium sulfide membrane thus produced is luminescent at room temperature and may have application in laser fabrication.

  13. A circular dichroism sensor for Ni(2+) and Co(2+) based on L-cysteine capped cadmium sulfide quantum dots.

    Science.gov (United States)

    Tedsana, Wimonsiri; Tuntulani, Thawatchai; Ngeontae, Wittaya

    2015-03-31

    A new circular dichroism sensor for detecting Ni(2+) and Co(2+) was proposed for the first time using chiral chelating quantum dots. The detection principle was based on changing of circular dichroism signals of the chiral quantum dots when forming a chiral complex with Ni(2+) or Co(2+). L-Cysteine capped cadmium sulfide quantum dots (L-Cyst-CdS QDs) were proposed as a chiral probe. The CD spectrum of L-Cyst-CdS QDs was significantly changed in the presence of Ni(2+) and Co(2+). On the other hand, other studied cations did not alter the original CD spectrum. Moreover, when increasing the concentration of Ni(2+) or Co(2+), the intensity of the CD spectrum linearly increased as a function of concentration and could be useful for the quantitative analysis. The proposed CD sensor showed linear working concentration ranges of 10-60 μM and 4-80 μM with low detection limits of 7.33 μМ and 1.13 μM for the detection of Ni(2+) and Co(2+), respectively. Parameters possibly affected the detection sensitivity such as solution pH and incubation time were studied and optimized. The proposed sensor was applied to detect Ni(2+) and Co(2+) in real water samples, and the results agreed well with the analysis using the standard ICP-OES. Copyright © 2014 Elsevier B.V. All rights reserved.

  14. Bicycle riding and erectile dysfunction: a review.

    Science.gov (United States)

    Sommer, Frank; Goldstein, Irwin; Korda, Joanna Beate

    2010-07-01

    For many years, reports in the literature have implicated bicycle riding as causing increased risk of erectile dysfunction (ED). Perineal compression during cycling has been associated with the development of sexual complications. To review current literature on the rationale for ED from bicycle riding and outcome of bicycle riding on erectile function and to present available research on preventative measures specifically regarding bicycle riding. A systematic comprehensive literature review. There is a significant relationship between cycling-induced perineal compression leading to vascular, endothelial, and neurogenic dysfunction in men and the development of ED. Research on female bicyclists is very limited but indicates the same impairment as in male bicyclists. Preventative measures including use of a properly fitted bicycle, a riding style with a suitable seat position and an appropriate bicycle seat can help prevent impairment of erectile function. There is a need for further research on safe bicycle and bicycle seat design and investigations that address the underlying mechanisms leading to cycling-related sexual dysfunction in both male and female bicyclists.

  15. Crystal Growth, Characterization and Fabrication of Cadmium Zinc Telluride-based Nuclear Detectors

    Science.gov (United States)

    Krishna, Ramesh M.

    In today's world, nuclear radiation is seeing more and more use by humanity as time goes on. Nuclear power plants are being built to supply humanity's energy needs, nuclear medical imaging is becoming more popular for diagnosing cancer and other diseases, and control of weapons-grade nuclear materials is becoming more and more important for national security. All of these needs require high-performance nuclear radiation detectors which can accurately measure the type and amount of radiation being used. However, most current radiation detection materials available commercially require extensive cooling, or simply do not function adequately for high-energy gamma-ray emitting nuclear materials such as uranium and plutonium. One of the most promising semiconductor materials being considered to create a convenient, field-deployable nuclear detector is cadmium zinc telluride (CdZnTe, or CZT). CZT is a ternary semiconductor compound which can detect high-energy gamma-rays at room temperature. It offers high resistivity (≥ 1010 O-cm), a high band gap (1.55 eV), and good electron transport properties, all of which are required for a nuclear radiation detector. However, one significant issue with CZT is that there is considerable difficulty in growing large, homogeneous, defect-free single crystals of CZT. This significantly increases the cost of producing CZT detectors, making CZT less than ideal for mass-production. Furthermore, CZT suffers from poor hole transport properties, which creates significant problems when using it as a high-energy gamma-ray detector. In this dissertation, a comprehensive investigation is undertaken using a successful growth method for CZT developed at the University of South Carolina. This method, called the solvent-growth technique, reduces the complexity required to grow detector-grade CZT single crystals. It utilizes a lower growth temperature than traditional growth methods by using Te as a solvent, while maintaining the advantages of

  16. Chemical characterisation of zircon-cadmium sulfoselenide ceramic pigments; Caracterizacion quimica de pigmentos ceramicos a base de sulfoseleniuro de cadmio

    Energy Technology Data Exchange (ETDEWEB)

    Gazulla Barreda, M. F.; Rodrigo Edo, M.; Blasco Roca, E.; Orduna Cordero, M.

    2013-07-01

    The present paper addresses the development of a methodology that allows the complete chemical characterisation of zircon cadmium sulfoselenide ceramic pigments including minor and major elements. To develop the methodology, five zircon-cadmium sulfoselenide pigments with different hues were selected, studying the different measurement process steps, from sample preparation to the optimisation of the measurement of the different components of the pigments by spectroscopic techniques (WD-XRF and elemental analysis by combustion and IR detection). The chemical characterisation method developed was validated with synthetic standards prepared from the mixture of certified reference materials and pure oxides because no certified referenced materials of this type of pigments were commercially available. The developed method can be used for a complete chemical characterization of zircon-cadmium sulfoselenide ceramic pigments with a very low uncertainty for all the elements analysed. (Author)

  17. Slurry procedures for the determination of cadmium and lead in cereal-based products using electrothermal atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Vinas, P. (Dept. of Analytical Chemistry, Murcia Univ. (Spain)); Campillo, N. (Dept. of Analytical Chemistry, Murcia Univ. (Spain)); Lopez Garcia, I. (Dept. of Analytical Chemistry, Murcia Univ. (Spain)); Hernandez Cordoba, M. (Dept. of Analytical Chemistry, Murcia Univ. (Spain))

    1994-06-01

    Simple and rapid methods for the determination of cadmium and lead in biscuits, bread and cerealbased products using the slurry-ETAAS approach are discussed. Suspensions were prepared in a 20% v/v ethanol medium. Phosphate was used as a chemical modifier for lead determination. For cadmium determination both palladium and a copper plus ammonia mixture were used. In both cases platform atomization was used and calibration was performed using aqueous standards. Results for two reference materials confirmed the reliability of the procedures. Relative standard deviations were in the range of 2.5-6.5% for cadmium and 4.5-14% for lead. Detection limits were, respectively, 0.5 and 8 ng/g. (orig.)

  18. Novel Cadmium Resistance Determinant in Listeria monocytogenes.

    Science.gov (United States)

    Parsons, Cameron; Lee, Sangmi; Jayeola, Victor; Kathariou, Sophia

    2017-03-01

    Listeria monocytogenes is a foodborne pathogen that can cause severe disease (listeriosis) in susceptible individuals. It is ubiquitous in the environment and often exhibits resistance to heavy metals. One of the determinants that enables Listeria to tolerate exposure to cadmium is the cadAC efflux system, with CadA being a P-type ATPase. Three different cadA genes (designated cadA1 to cadA3) were previously characterized in L. monocytogenes A novel putative cadmium resistance gene (cadA4) was recently identified through whole-genome sequencing, but experimental confirmation for its involvement in cadmium resistance is lacking. In this study, we characterized cadA4 in L. monocytogenes strain F8027, a cadmium-resistant strain of serotype 4b. By screening a mariner-based transposon library of this strain, we identified a mutant with reduced tolerance to cadmium and that harbored a single transposon insertion in cadA4 The tolerance to cadmium was restored by genetic complementation with the cadmium resistance cassette (cadA4C), and enhanced cadmium tolerance was conferred to two unrelated cadmium-sensitive strains via heterologous complementation with cadA4C Cadmium exposure induced cadA4 expression, even at noninhibitory levels. Virulence assessments in the Galleria mellonella model suggested that a functional cadA4 suppressed virulence, potentially promoting commensal colonization of the insect larvae. Biofilm assays suggested that cadA4 inactivation reduced biofilm formation. These data not only confirm cadA4 as a novel cadmium resistance determinant in L. monocytogenes but also provide evidence for roles in virulence and biofilm formation.IMPORTANCEListeria monocytogenes is an intracellular foodborne pathogen causing the disease listeriosis, which is responsible for numerous hospitalizations and deaths every year. Among the adaptations that enable the survival of Listeria in the environment are the abilities to persist in biofilms, grow in the cold, and tolerate

  19. End-stage renal disease and low level exposure to lead, cadmium and mercury; a population-based, prospective nested case-referent study in Sweden

    Science.gov (United States)

    2013-01-01

    Background Cadmium (Cd), lead (Pb), and mercury (Hg) cause toxicological renal effects, but the clinical relevance at low-level exposures in general populations is unclear. The objective of this study is to assess the risk of developing end-stage renal disease in relation to Cd, Pb, and Hg exposure. Methods A total of 118 cases who later in life developed end-stage renal disease, and 378 matched (sex, age, area, and time of blood sampling) referents were identified among participants in two population-based prospective cohorts (130,000 individuals). Cd, Pb, and Hg concentrations were determined in prospectively collected samples. Results Erythrocyte lead was associated with an increased risk of developing end-stage renal disease (mean in cases 76 μg/L; odds ratio (OR) 1.54 for an interquartile range increase, 95% confidence interval (CI) 1.18-2.00), while erythrocyte mercury was negatively associated (2.4 μg/L; OR 0.75 for an interquartile range increase, CI 0.56-0.99). For erythrocyte cadmium, the OR of developing end-stage renal disease was 1.15 for an interquartile range increase (CI 0.99-1.34; mean Ery-Cd among cases: 1.3 μg/L). The associations for erythrocyte lead and erythrocyte mercury, but not for erythrocyte cadmium, remained after adjusting for the other two metals, smoking, BMI, diabetes, and hypertension. Gender-specific analyses showed that men carried almost all of the erythrocyte lead and erythrocyte cadmium associated risks. Conclusions Erythrocyte lead is associated with end-stage renal disease but further studies are needed to evaluate causality. Gender-specific analyses suggest potential differences in susceptibility or in exposure biomarker reliability. PMID:23343055

  20. Simultaneous determination of traces amounts of cadmium, zinc, and cobalt based on UV-Vis spectrometry combined with wavelength selection and partial least squares regression.

    Science.gov (United States)

    Xu, Deng; Fan, Wei; Lv, Huiying; Liang, Yizeng; Shan, Yang; Li, Gaoyang; Yang, Zhenyu; Yu, Ling

    2014-04-05

    The use of wavelength selection before partial least squares regression (PLSR) for simultaneous determination of divalent metal ions, cadmium, zinc and cobalt by UV-Vis spectrometry was investigated in this paper. The number of wavelengths selected by competitive adaptive reweighted sampling (CARS) for cadmium, zinc, and cobalt were 21, 13 and 7, respectively, from the 916 original wavelength points. The analytical system was based on the formation of the complexes with 2-(5-bromo-2-pyridylazo)-5-(diethylamino)phenol (Br-PADAP) in surfactant media. Compared with the results of full spectra calibration, the root mean squared error of prediction (RMSEP) reduced to 0.0110, 0.0098 and 0.0031 for cadmium, zinc and cobalt, respectively. Moreover, by using the selective wavelengths instead of the 916 original wavelengths, the latent variables of PLS models reduced to 3, 3 and 4. The results indicated that the PLS model established by selected wavelength could be used for simultaneous determination of divalent metal ions. Copyright © 2013 Elsevier B.V. All rights reserved.

  1. Supported liquid membrane based removal of lead(II) and cadmium(II) from mixed feed: Conversion to solid waste by precipitation

    Energy Technology Data Exchange (ETDEWEB)

    Bhatluri, Kamal Kumar; Manna, Mriganka Sekhar; Ghoshal, Aloke Kumar; Saha, Prabirkumar, E-mail: p.saha@iitg.ac.in

    2015-12-15

    Highlights: • Simultaneous removal of two heavy metals lead and cadmium. • Conversion of liquid waste to solid precipitation. • Precipitation facilitates the metals transportation through LM. • Solidification of liquid waste minimizes the final removal of waste. - Abstract: Simultaneous removal of two heavy metals, lead(II) and cadmium(II), from mixed feed using supported liquid membrane (SLM) based technique is investigated in this work. The carrier-solvent combination of “sodium salt of Di-2-ethylhexylphosphoric acid (D2EHPA) (4% w/w) in environmentally benign coconut oil” was immobilized into the pores of solid polymeric polyvinylidene fluoride (PVDF) support. Sodium carbonate (Na{sub 2}CO{sub 3}) was used as the stripping agent. Carbonate salts of lead(II) and cadmium(II) were formed in the stripping side interface and they were insoluble in water leading to precipitation inside the stripping solution. The transportation of solute is positively affected due to the precipitation. Lead(II) removal was found to be preferential due to its favorable electronic configuration. The conversion of the liquid waste to the solid one was added advantage for the final removal of hazardous heavy metals.

  2. Shared-Ride Taxi Service in Boston, MA

    Science.gov (United States)

    1985-03-01

    This report presents an evaluation of the Boston Shared-Ride Taxi Demonstration. The City of Boston's Traffic and Parking Department, the project grantee, designed a shared-ride service for Boston's Allston-Brighton neighborhood; Boston Cab Associati...

  3. Transcriptomic changes during maize roots development responsive to Cadmium (Cd) pollution using comparative RNAseq-based approach

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Hua [Key Laboratory of Biology and Genetic Improvement of Maize in Southwest Region, Ministry of Agriculture, Maize Research Institute, Sichuan Agricultural University, Wenjiang, Sichuan, 611130 (China); Sichuan Tourism College, Chengdu, 610000, Sichuan (China); He, Xiujing [Key Laboratory of Biology and Genetic Improvement of Maize in Southwest Region, Ministry of Agriculture, Maize Research Institute, Sichuan Agricultural University, Wenjiang, Sichuan, 611130 (China); Gao, Jian [Institute of Pathology and Southwest Cancer Center, Southwest Hospital, Third Military Medical University, Key Laboratory of Tumor Immunopathology, Ministry of Education of China, Chongqing (China); Ma, Haixia; Zhang, Zhiming; Shen, Yaou [Key Laboratory of Biology and Genetic Improvement of Maize in Southwest Region, Ministry of Agriculture, Maize Research Institute, Sichuan Agricultural University, Wenjiang, Sichuan, 611130 (China); Pan, Guangtang, E-mail: pangt@sicau.edu.cn [Key Laboratory of Biology and Genetic Improvement of Maize in Southwest Region, Ministry of Agriculture, Maize Research Institute, Sichuan Agricultural University, Wenjiang, Sichuan, 611130 (China); Lin, Haijian, E-mail: linhj521@gmail.com [Key Laboratory of Biology and Genetic Improvement of Maize in Southwest Region, Ministry of Agriculture, Maize Research Institute, Sichuan Agricultural University, Wenjiang, Sichuan, 611130 (China)

    2015-09-04

    The heavy metal cadmium (Cd), acts as a widespread environmental contaminant, which has shown to adversely affect human health, food safety and ecosystem safety in recent years. However, research on how plant respond to various kinds of heavy metal stress is scarcely reported, especially for understanding of complex molecular regulatory mechanisms and elucidating the gene networks of plant respond to Cd stress. Here, transcriptomic changes during Mo17 and B73 seedlings development responsive to Cd pollution were investigated and comparative RNAseq-based approach in both genotypes were performed. 115 differential expression genes (DEGs) with significant alteration in expression were found co-modulated in both genotypes during the maize seedling development; of those, most of DGEs were found comprised of stress and defense responses proteins, transporters, as well as transcription factors, such as thaumatin-like protein, ZmOPR2 and ZmOPR5. More interestingly, genotype-specific transcriptional factors changes induced by Cd stress were found contributed to the regulatory mechanism of Cd sensitivity in both different genotypes. Moreover, 12 co-expression modules associated with specific biological processes or pathways (M1 to M12) were identified by consensus co-expression network. These results will expand our understanding of complex molecular mechanism of response and defense to Cd exposure in maize seedling roots. - Highlights: • Transcriptomic changes responsive to Cd pollution using comparative RNAseq-based approach. • 115 differential expression genes (DEGs) were found co-modulated in both genotypes. • Most of DGEs belong to stress and defense responses proteins, transporters, transcription factors. • 12 co-expression modules associated with specific biological processes or pathways. • Genotype-specific transcriptional factors changes induced by Cd stress were found.

  4. [Advantages of ride therapy in different forms of infantile cerebral palsy (therapeutic riding)].

    Science.gov (United States)

    Ionatamishvili, N I; Tsverava, D M; Loriia, M Sh; Avaliani, L A

    2003-01-01

    One hundred children with cerebral palsy, aged 3-14 years, were divided into two equal groups, the first one including 50 children assigned to ride therapy and the second one--to Bobath therapeutic gymnastics. All the patients underwent a functional examination, which was rated using score system worked out by the authors, thus enabling a quantitative evaluation of treatment efficacy. In all the cases, physical rehabilitation resulted in a positive but not the same effect, with ride therapy being significantly (p gymnastics. Ride therapy provides an acquisition of new movement skills, spastics and hyperkinesis reduction and an extreme mobilization of compensatory abilities of developing children brain.

  5. Cadmium Exposure and Pancreatic Cancer in South Louisiana

    Directory of Open Access Journals (Sweden)

    Brian G. Luckett

    2012-01-01

    Full Text Available Cadmium has been hypothesized to be a pancreatic carcinogen. We test the hypothesis that cadmium exposure is a risk factor for pancreatic cancer with a population-based case-control study sampled from a population with persistently high rates of pancreatic cancer (south Louisiana. We tested potential dietary and nondietary sources of cadmium for their association with urinary cadmium concentrations which reflect long-term exposure to cadmium due to the accumulation of cadmium in the kidney cortex. Increasing urinary cadmium concentrations were significantly associated with an increasing risk of pancreatic cancer (2nd quartile OR = 3.34, 3rd = 5.58, 4th = 7.70; test for trend P≤0.0001. Potential sources of cadmium exposure, as documented in the scientific literature, found to be statistically significantly associated with increased risk of pancreatic cancer included working as a plumber, pipefitter or welder (OR = 5.88 and high consumption levels of red meat (4th quartile OR = 6.18 and grains (4th quartile OR = 3.38. Current cigarette smoking, at least 80 pack years of smoking, occupational exposure to cadmium and paints, working in a shipyard, and high consumption of grains were found to be statistically significantly associated with increased concentrations of urinary cadmium. This study provides epidemiologic evidence that cadmium is a potential human pancreatic carcinogen.

  6. 7 CFR 502.6 - Hunting, fishing, camping, horseback riding.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 6 2010-01-01 2010-01-01 false Hunting, fishing, camping, horseback riding. 502.6..., MARYLAND § 502.6 Hunting, fishing, camping, horseback riding. The use of BARC grounds for any form of hunting, fishing, camping, or horseback riding is prohibited. Further, the use of these grounds for...

  7. Cadmium stress assessment based on the electrocardiogram characteristics of zebra fish (Danio rerio): QRS complex could play an important role.

    Science.gov (United States)

    Xing, Na; Ji, Lizhen; Song, Jie; Ma, Jingchun; Li, Shangge; Ren, Zongming; Xu, Fei; Zhu, Jianping

    2017-10-01

    The electrocardiogram (ECG) of zebra fish (Danio rerio) expresses cardiac features that are similar to humans. Here we use sharp microelectrode measurements to obtain ECG characteristics in adult zebra fish and analyze the effects of cadmium chloride (CdCl 2 ) on the heart. We observe the overall changes of ECG parameters in different treatments (0.1 TU, 0.5 TU and 1.0 TU CdCl 2 ), including P wave, Q wave, R wave, S wave, T wave, PR interval (atrial contraction), QRS complex (ventricular depolarization), ST segment, and QT interval (ventricular repolarization). The trends of the ECG parameters showed some responses to the concentration and exposure time of CdCl 2 , but it was difficult to obtain more information about the useful indicators in water quality assessment depending on tendency analysis alone. A self-organizing map (SOM) showed that P values, R values, and T values were similar; R wave and T wave amplitude were similar; and most important, QRS value was similar to the CdCl 2 stress according to the classified data patterns including CdCl 2 stress (E) and ECG components based on the Ward linkage. It suggested that the duration of QRS complex was related to environmental stress E directly. The specification and evaluation of ECG parameters in Cd 2+ pollution suggested that there is a markedly significant correlation between QRS complex and CdCl 2 stress with the highest r (0.729) and the smallest p (0.002) among all ECG characteristics. In this case, it is concluded that QRS complex can be used as an indicator in the CdCl 2 stress assessment due to the lowest AIC data abased on the linear regression model between the CdCl 2 stress and ECG parameters. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Riding Third: Social Work in Ambulance Work

    Science.gov (United States)

    Campbell, Hilary; Rasmussen, Brian

    2012-01-01

    This research explored the possible role of social work alongside emergency ambulance services. An ethnographic study included semistructured interviews and direct observations collected over 300 hours while riding in ambulances in an urban setting. The data suggest that social work could play a role by providing needed psychosocial care during…

  9. Ride responses of macpherson suspension systems

    Directory of Open Access Journals (Sweden)

    Yu Cheng-Chi

    2017-01-01

    Full Text Available The main purpose of this study is to obtain more correct vehicle ride responses by using a nonlinear ride model considering the effect of Macpherson suspension geometry. Traditional ride model applied to analysis and controller design uses a two degree of freedom linear model, which includes sprung mass and unsprung mass and a spring and a damper vertically connect them. In fact, suspension components do not vertically position above the tire. The motions of body and tire are not going straight up and down. Therefore, the analysis results obtained by the simple model are often different from the experimental values of the actual vehicle. Because of the difference between simple model and actual vehicle, the control strategy almost cannot apply to actual vehicle. In order to understand the effect of suspension geometry on the vehicle ride responses and design a more practical control strategy, a nonlinear model including the geometric parameters of the suspension is constructed in this study. To estimate the initial equilibrium position of the suspension assembly under load, the static equilibrium analysis and mechanism motion analysis are synchronous implemented at the same time. The nonlinear model describes not only the relative position and velocity but also the force transmission between body and tire. Furthermore, by linearize this nonlinear model the development of control strategy for subsequent (semi active suspension system could be expected.

  10. Stay Safe Riding Bikes or Skating Outside

    Centers for Disease Control (CDC) Podcasts

    2011-02-02

    In this podcast for kids, the Kidtastics talk about safety when outside, riding bikes or skating.  Created: 2/2/2011 by National Center for Injury Prevention and Control (NCIPC).   Date Released: 2/2/2011.

  11. Sustainable Passenger Transportation: Dynamic Ride-Sharing

    NARCIS (Netherlands)

    N.A.H. Agatz (Niels); A. Erera (Alan); M.W.P. Savelsbergh (Martin); X. Wang (Xing)

    2010-01-01

    textabstractRide-share systems, which aim to bring together travelers with similar itineraries and time schedules, may provide significant societal and environmental benefits by reducing the number of cars used for personal travel and improving the utilization of available seat capacity. Effective

  12. Ride Motion Simulator Safety Assessment Report

    Science.gov (United States)

    2013-07-01

    20 5.4.3.1.3 Servo Control Unit and...machine interface development and soldier task-load and cognition research. In the mid-1990’s, TARDEC contracted with MTS Systems (Eden Prairie, MN...in the MTS Technical Report, entitled “Ride Motion Simulator Safety Assessment Report” [2], remains the best account of the maximum acceleration

  13. Riding Bikes: A Pastime for Every Child

    Science.gov (United States)

    Mathias, Michelle

    2011-01-01

    People have heard the expression "It's as easy as riding a bike." But the idea of a child with special needs balancing, steering, and pedaling a bike can seem out of reach for some; especially when he may be unable to walk unaided or hold his head up without support. Physical capabilities or stamina need not keep a child from this pleasurable…

  14. Kenojuak Ashevak: "Young Owl Takes a Ride."

    Science.gov (United States)

    Schwartz, Bernard

    1988-01-01

    Describes a lesson plan used to introduce K-3 students to a Canadian Inuit artist, to the personal and cultural context of the artwork, and to a simple printmaking technique. Includes background information on the artist, instructional strategies, and a print of the artist's "Young Owl Takes a Ride." (GEA)

  15. PrivateRide: A Privacy-Enhanced Ride-Hailing Service

    OpenAIRE

    Pham Anh; Dacosta Italo; Jacot-Guillarmod Bastien; Huguenin Kévin; Hajar Taha; Tramèr Florian; Gligor Virgil; Hubaux Jean-Pierre

    2017-01-01

    International audience; In the past few years, we have witnessed a rise in the popularity of ride-hailing services (RHSs), an on-line marketplace that enables accredited drivers to use their own cars to drive ride-hailing users. Unlike other transportation services, RHSs raise significant privacy concerns , as providers are able to track the precise mobility patterns of millions of riders worldwide. We present the first survey and analysis of the privacy threats in RHSs. Our analysis exposes ...

  16. [Cadmium and selenium interaction in mammals].

    Science.gov (United States)

    Lazarus, Maja

    2010-09-01

    Cadmium occurs in the environment naturally and as a pollutant. Its exposure is inevitable and may produce toxic effects in many organs and organ systems through binding to biological structures, accumulation in internal organs or induction of free radical production. Another important aspect of Cd toxicity is its interaction, often anthagonistic, with essential elements. Vice versa, additional intake of the essential elements may have beneficial influence on distribution and toxic effects of cadmium. Selenium is an essential microelement and a constituent of many selenoproteins with antioxidant properties that bind cadmium (and other toxic elements such as mercury or arsenic). This review summarizes results, to date, of cadmium toxicokinetics and toxicodinamics, selenium biokinetics and biodinamics, as well as mechanisms of cadmium-selenium interaction and their impact on the oxidative status derived from the studies based upon mainly on animal experiments and on limited number of human studies. The wide variety of different doses, dose ratios, element administration modes and exposure lenghts of cadmium and selenium often yielded contradictory results. Future studies should be focused on assessment of effects of cadmium and selenium interaction in sensitive population groups and mechanisms of that interaction. Regarding animal studies, doses and exposure should be adjusted to long-term low exposure levels that are usually found in human population.

  17. [Riding therapy in the rehabilitation of mobility-impaired children].

    Science.gov (United States)

    Mäenpää, Helena; Kela, Katri; Sätilä, Heli

    2016-01-01

    Riding therapy is a comprehensive and functional form of rehabilitation, in which the rehabilitee, the horse and the riding therapist collaborate in order to achieve individually assigned goals that support rehabilitation. In Finland, riding therapy is therapeutic rehabilitation carried out by riding therapists who have undergone approved training. The therapy is mainly implemented in an individual form, but small group working is also applied, e.g. in the form of pair therapy and therapeutic vaulting. In Europe, this form of rehabilitation has been divided into hippotherapy supporting motor functions and heilpedagogical riding therapy functioning in support of upbringing.

  18. Cadmium exposure via diet and its implication on the derivation of health-based soil screening values in China.

    Science.gov (United States)

    Zhong, Mao-Sheng; Jiang, Lin; Han, Dan; Xia, Tian-Xiang; Yao, Jue-Jun; Jia, Xiao-Yang; Peng, Chao

    2015-01-01

    The cadmium (Cd) intake rates via diet of adults from different regions in China were between 0.160 and 0.557 μg/(kg BW·day), which were less than the provisional tolerable monthly intake (0.833 μg/(kg BW·day)) issued by Food and Agriculture Organization/World Health Organization in 2010, but higher than the one (0.365 μg/(kg BW·day)) issued by the European Food Safety Authority in 2011, to protect children, vegetarians and people living in heavily contaminated regions, and the intake rate of children (1.007 μg/(kg BW·day)) at the national scale was higher than the values recommended by the above institutes and those of adults. Vegetables were the critical contributors, followed by rice, flour, meats and aquatic products. Cd concentration in vegetable was the most sensitive factor in calculating the intake rate, followed by its contents in rice and aquatic products, and the intake rate of flour, indicating that more attention should be given to these parameters in future total diet surveys. When dietary exposure was incorporated, the derived national screening value of Cd under commercial scenario was reduced from 825 to 458 mg/kg, while the values of the north, south, Beijing and Shanghai were reduced to 627, 365, 693 and 489 mg/kg, respectively, indicating that the hazard would be underestimated if dietary exposure was not taken into account, especially for the south. The great variance between the screening values was due to the varied Cd intake rates, which indicated that deriving a screening value for each specific area based on its corresponding exposure characteristics was more appropriate. The national screening level for the residential scenario derived theoretically based on the dietary exposure characteristics of children was a negative value, meaning that the dietary intake rate was above the tolerable value. The method used in the United Kingdom to derive soil guideline values when non-soil exposure accounted for more than half of

  19. The phylogeny of Little Red Riding Hood.

    Directory of Open Access Journals (Sweden)

    Jamshid J Tehrani

    Full Text Available Researchers have long been fascinated by the strong continuities evident in the oral traditions associated with different cultures. According to the 'historic-geographic' school, it is possible to classify similar tales into "international types" and trace them back to their original archetypes. However, critics argue that folktale traditions are fundamentally fluid, and that most international types are artificial constructs. Here, these issues are addressed using phylogenetic methods that were originally developed to reconstruct evolutionary relationships among biological species, and which have been recently applied to a range of cultural phenomena. The study focuses on one of the most debated international types in the literature: ATU 333, 'Little Red Riding Hood'. A number of variants of ATU 333 have been recorded in European oral traditions, and it has been suggested that the group may include tales from other regions, including Africa and East Asia. However, in many of these cases, it is difficult to differentiate ATU 333 from another widespread international folktale, ATU 123, 'The Wolf and the Kids'. To shed more light on these relationships, data on 58 folktales were analysed using cladistic, Bayesian and phylogenetic network-based methods. The results demonstrate that, contrary to the claims made by critics of the historic-geographic approach, it is possible to identify ATU 333 and ATU 123 as distinct international types. They further suggest that most of the African tales can be classified as variants of ATU 123, while the East Asian tales probably evolved by blending together elements of both ATU 333 and ATU 123. These findings demonstrate that phylogenetic methods provide a powerful set of tools for testing hypotheses about cross-cultural relationships among folktales, and point towards exciting new directions for research into the transmission and evolution of oral narratives.

  20. Using forecast information for storm ride-through control

    DEFF Research Database (Denmark)

    Barahona Garzón, Braulio; Trombe, Pierre-Julien; Vincent, Claire Louise

    2013-01-01

    Using probabilistic forecast information in control algorithms can improve the performance of wind farms during periods of extreme winds. This work presents a wind farm supervisor control concept that uses probabilistic forecast information to ride-through a storm with softer ramps of power. Wind...... speed forecasts are generated with a statistical approach (i.e. time series models). The supervisor control is based on a set of logical rules that consider point forecasts and predictive densities to ramp-down the power of the wind farm before the storm hits. The potential of this supervisor control...... information, and particularly weather radar images....

  1. Pricing Decision under Dual-Channel Structure considering Fairness and Free-Riding Behavior

    Directory of Open Access Journals (Sweden)

    Yongmei Liu

    2014-01-01

    Full Text Available Under dual-channel structure, the free-riding behavior based on different service levels between online channel and offline channel cannot be avoided, which would lead to channel unfairness. This study implies that the dual-channel supply chain is built up by online channel controlled by manufacturer and traditional channel controlled by retailer, respectively. Under this channel structure, we rebuild the linear demand function considering free-riding behavior and modify the pricing model based on channel fairness. Then the influences of fair factor and free-riding behavior on manufacturer and retailer pricing and performance are discussed. Finally, we propose some numerical analysis to provide some valuable recommendations for manufacturer and retailer improving channel management performance.

  2. The Medical Staff Ride: an education tool for military medical leadership development.

    Science.gov (United States)

    Bricknell, Martin C M

    2016-08-01

    This paper provides a description of the Medical Staff Ride as an educational tool for military medical leadership. It is based upon two Medical Staff Rides covering the Somme Campaign 1916 and the Normandy Campaign 1944. It describes the key educational activity 'The Stand' at which history and current issues are brought together through study of a particular location on the historical battlefield. The Medical Staff Ride can be divided into six distinct phases, each of which have common question sets for analysis by attendees. The Medical Staff Ride can be shown to have valuable educational outcomes that are efficient in time and cost, and effective in achieving personal learning. The supporting Readers for the two Medical Staff Rides covered by this paper are available as electronic supplement to this edition of the journal. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/

  3. One-step synthesis of DNA functionalized cadmium-free quantum dots and its application in FRET-based protein sensing

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Cuiling, E-mail: clzhang@chem.ecnu.edu.cn [Department of Chemistry, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241 (China); Ding, Caiping [Department of Chemistry, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241 (China); Zhou, Guohua [School of Chemistry and Chemical Engineering, Lingnan Normal University, Zhanjiang, 524048 (China); Xue, Qin [Department of Chemistry, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241 (China); Xian, Yuezhong, E-mail: yzxian@chem.ecnu.edu.cn [Department of Chemistry, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241 (China)

    2017-03-08

    DNA functionalized quantum dots (QDs) are promising nanoprobes for the fluorescence resonance energy transfer (FRET)-based biosensing. Herein, cadmium-free DNA functionalized Mn-doped ZnS (DNA-ZnS:Mn{sup 2+}) QDs were successfully synthesized by one-step route. As-synthesized QDs show excellent photo-stability with the help of PAA and DNA. Then, we constructed a novel FRET model based on the QDs and WS{sub 2} nanosheets as the energy donor-acceptor pairs, which was successfully applied for the protein detection through the terminal protection of small molecule-linked DNA assay. This work not only explores the potential bioapplication of the DNA-ZnS:Mn{sup 2+} QDs, but also provides a platform for the investigation of small molecule-protein interaction. - Highlights: • The stable and cadmium-free DNA functionalized ZnS:Mn{sup 2+} QDs were successfully synthesized through a facile one-step route. • We constructed a novel FRET system based on one-step synthesized DNA-ZnS:Mn{sup 2+} QDs (donor) and WS{sub 2} nanosheets (acceptor). • The FRET-based strategy was applied for the detection of streptavidin and folate receptor by combining TPSMLD and Exo III.

  4. Tissue specific responses to cadmium-based quantum dots in the marine mussel Mytilus galloprovincialis

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Thiago Lopes [CIMA, Faculty of Science and Technology, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Gomes, Tânia [CIMA, Faculty of Science and Technology, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Norwegian Institute for Water Research (NIVA), Gaustadalléen 21, NO-0349 Oslo (Norway); Mestre, Nélia C.; Cardoso, Cátia [CIMA, Faculty of Science and Technology, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Bebianno, Maria João, E-mail: mbebian@ualg.pt [CIMA, Faculty of Science and Technology, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal)

    2015-12-15

    Highlights: • Mussel gills are the main target for oxidative stress induced by Cd-based QDs. • Antioxidants responses induced by Cd-based QDs and dissolved Cd are mediated by different mechanisms. • CdTe QDs are more pro-oxidant Cd form when compared to dissolved Cd. • Differential tissue response indicated nano-specific effects. - Abstract: In recent years, Cd-based quantum dots (QDs) have generated interest from the life sciences community due to their potential applications in nanomedicine, biology and electronics. However, these engineered nanomaterials can be released into the marine environment, where their environmental health hazards remain unclear. This study investigated the tissue-specific responses related to alterations in the antioxidant defense system induced by CdTe QDs, in comparison with its dissolved counterpart, using the marine mussel Mytilus galloprovincialis. Mussels were exposed to CdTe QDs and dissolved Cd for 14 days at 10 μgCd L{sup −1} and biomarkers of oxidative stress [superoxide dismutase (SOD), catalase (CAT), glutathione peroxidases (total, Se-independent and Se-dependent GPx) and glutathione-S-transferase (GST) activities] were analyzed along with Cd accumulation in the gills and digestive gland of mussels. Results show that both Cd forms changed mussels’ antioxidant responses with distinct modes of action (MoA). There were tissue- and time-dependent differences in the biochemical responses to each Cd form, wherein QDs are more pro-oxidant when compared to dissolved Cd. The gills are the main tissue affected by QDs, with effects related to the increase of SOD, GST and GPx activities, while those of dissolved Cd was associated to the increase of CAT activity, Cd accumulation and exposure time. Digestive gland is a main tissue for accumulation of both Cd forms, but changes in antioxidant enzyme activities are smaller than in gills. A multivariate analysis revealed that the antioxidant patterns are tissue dependent

  5. Exposure dose response relationships of the freshwater bivalve Hyridella australis to cadmium spiked sediments

    Energy Technology Data Exchange (ETDEWEB)

    Marasinghe Wadige, Chamani P.M., E-mail: chamani.marasinghe.wadige@canberra.edu.au; Maher, William A.; Taylor, Anne M.; Krikowa, Frank

    2014-07-01

    organisms, which suggests that H. australis has some tolerance to cadmium. The metallothionein like protein fraction played an important role in the sequestration and detoxification of cadmium and the amount sequestered in this fraction increased with increased cadmium exposure. The highest percentage of biologically active cadmium was associated with the lysosome + microsome and mitochondrial fractions. Cadmium concentrations in these two fractions of cadmium exposed organisms were significantly higher with respect to controls. Total antioxidant capacity decreased with increased cadmium exposure and tissue dose. Lipid peroxidation increased and lysosomal membrane stability decreased significantly with increased cadmium exposure and tissue dose. Based on exposure–dose–response analysis in this study, H. australis would be a suitable organism for assessing cadmium sediment exposure and toxicity.

  6. A peptide-based fluorescent chemosensor for measuring cadmium ions in aqueous solutions and live cells.

    Science.gov (United States)

    Wang, Peng; Wu, Jiang; Liu, Lixuan; Zhou, Panpan; Ge, Yushu; Liu, Dan; Liu, Weisheng; Tang, Yu

    2015-11-07

    A novel peptide fluorescent chemosensor (H2L) with a lysine backbone and both -NH2 sites conjugated with cysteine and dansyl groups has been designed and synthesized by solid phase peptide synthesis with Fmoc chemistry. This chemosensor is a promising analytical tool for detecting Cd(2+) based on the photo-induced electron transfer (PET) effect by turn-on response in 100% aqueous solutions. As designed, H2L exhibits excellent cell permeation and low biotoxicity as well as displaying relatively high selectivity and sensitivity. The chemosensor penetrated live HeLa cells and detected intracellular Cd(2+) by turn-on response. The binding stoichiometry and affinity, interference test, pH sensitivity, fluorescence quantum yield, quantum mechanical calculations, lifetimes, and cytotoxicity of the chemosensor H2L to Cd(2+) were also investigated. Moreover, H2L exhibits low biotoxicity with a limit of detection (LOD) for Cd(2+) of about 52 nM, implying that H2L can be used as a highly selective and sensitive peptide fluorescent chemosensor in biological systems.

  7. A veterinary review of endurance riding as an international competitive sport.

    Science.gov (United States)

    Nagy, Annamaria; Dyson, Sue J; Murray, Jane K

    2012-12-01

    The popularity of competitive endurance riding is growing worldwide and this has led to considerable changes in the discipline (e.g., fitter and faster horses and different types of injuries), which create challenges to all involved in the sport, including veterinarians. During endurance competitions, horses are closely monitored by veterinarians throughout the ride, with the aim of removing from the competition animals whose welfare appears to be endangered. This close monitoring provides veterinarians with an insight into problems during competitions. However, there is a relatively small amount of clinically relevant, evidence-based data published on endurance horses, and this article reviews the evolution of the discipline, the published information on epidemiological data on endurance rides, the problems veterinarians face at competitions, and highlights those areas where research is warranted. Copyright © 2012 Elsevier Ltd. All rights reserved.

  8. Ride comfort characteristics with different tire pressure of passenger vehicle featuring MR damper

    Energy Technology Data Exchange (ETDEWEB)

    Lee, H G [Department of Automotive Engineering, Daeduk College, Daejeon 305-715 (Korea, Republic of); Sung, K G [Department of Mechanical Engineering, Yeungnam College of Science and Technology, Daegu 705-703 (Korea, Republic of); Choi, S B [Smart Structures and Systems Laboratory, Department of Mechanical Engineering, Inha University, Incheon 402-751 (Korea, Republic of)], E-mail: seungbok@inha.ac.kr

    2009-02-01

    This paper presents ride comfort characteristics of a quarter-vehicle magneto-rheological (MR) suspension system with respect to different tire pressure. As a first step, controllable MR damper is designed and manufactured based on the optimized damping force levels and mechanical dimensions required for a commercial mid-sized passenger vehicle. After experimentally evaluating dynamic characteristics of the manufactured MR damper, the quarter-vehicle suspension system consisting of sprung mass, spring, tire and the MR damper is constructed in order to investigate the ride comfort. After deriving the equations of the motion for the proposed quarter-vehicle MR suspension system, vertical tire stiffness with respect to different tire pressure is experimentally identified. The skyhook controller is then implemented for the realization of quarter-vehicle MR suspension system. Ride comfort characteristics such as vertical acceleration RMS of sprung mass are evaluated under bump road condition and presented in time domain.

  9. A new pneumatic suspension system with independent stiffness and ride height tuning capabilities

    Science.gov (United States)

    Yin, Zhihong; Khajepour, Amir; Cao, Dongpu; Ebrahimi, Babak; Guo, Konghui

    2012-12-01

    This paper introduces a new pneumatic spring for vehicle suspension systems, allowing independent tuning of stiffness and ride height according to different vehicle operating conditions and driver preferences. The proposed pneumatic spring comprises a double-acting pneumatic cylinder, two accumulators and a tuning subsystem. This paper presents a detailed description of the pneumatic spring and its working principle. The mathematical model is established based on principles of thermo and fluid dynamics. An experimental setup has been designed and fabricated for testing and evaluating the proposed pneumatic spring. The analytical and experimental results confirm the capability of the new pneumatic spring system for independent tuning of stiffness and ride height. The mathematical model is verified and the capabilities of the pneumatic spring are further proved. It is concluded that this new pneumatic spring provides a more flexible suspension design alternative for meeting various conflicting suspension requirements for ride comfort and performance.

  10. Synthesis, Crystal Structure, and Luminescent Properties of New Zinc(II and Cadmium(II Metal-Organic Frameworks Based on Flexible Bis(imidazol-1-ylalkane Ligands

    Directory of Open Access Journals (Sweden)

    Marina Barsukova

    2016-10-01

    Full Text Available New metal-organic frameworks (MOFs based on zinc and cadmium ions, terephthalic acid, and flexible ligands 1,5-bis(imidazol-1-ylpentane or 1,6-bis(imidazol-1-ylhexane were prepared and characterized by X-ray diffraction, thermorgavimetric analysis and IR spectroscopy. The imidazolyl ligands were prepared by a new robust procedure involving the reaction between imidazole and 1,5-dibromopentane or 1,6-dibromohexane in a superbasic medium (KOH in DMSO. MOFs based on 1,5-bis(imidazol-1-ylpentane had diamond topology (dia and are triply interpenetrated. Ligands with longer spacer 1,6-bis(imidazol-1-ylhexane, terephthalate ions and zinc(II ions formed five-fold interpenetrated metal-organic framework also with dia topology, while cadmium(II ions with the same ligands formed eight-connected uninodal net with a very rare self-penetrated topological type ilc and a point symbol 424.5.63. The influence of the chemical composition of MOFs on their photoluminescent properties is investigated and discussed in detail.

  11. Air riding seal for a turbine

    Energy Technology Data Exchange (ETDEWEB)

    Mills, Jacob A; Brown, Wesley D; Sexton, Thomas D; Jones, Russell B

    2016-07-19

    An air riding seal between a rotor and a stator in a turbine of a gas turbine engine, where an annular piston is movable in an axial direction within a housing that extends from the stator, and a bellows is secured to the annular piston to form a flexible air passageway from a compressed air inlet through the annular piston and into a cushion cavity that forms an air riding seal between the annular piston and the rotor sealing surface. In another embodiment, a flexible seal secured to and extending from the annular piston forms a sealing surface between the annular piston chamber and the annular piston to provide a seal and allow for axial movement.

  12. Air riding seal with purge cavity

    Energy Technology Data Exchange (ETDEWEB)

    Sexton, Thomas D; Mills, Jacob A

    2017-08-15

    An air riding seal for a turbine in a gas turbine engine, where an annular piston is axial moveable within an annular piston chamber formed in a stator of the turbine and forms a seal with a surface on the rotor using pressurized air that forms a cushion in a pocket of the annular piston. A purge cavity is formed on the annular piston and is connected to a purge hole that extends through the annular piston to a lower pressure region around the annular piston or through the rotor to an opposite side. The annular piston is sealed also with inner and outer seals that can be a labyrinth seal to form an additional seal than the cushion of air in the pocket to prevent the face of the air riding seal from overheating.

  13. Scaling Law of Urban Ride Sharing

    Science.gov (United States)

    Tachet, R.; Sagarra, O.; Santi, P.; Resta, G.; Szell, M.; Strogatz, S. H.; Ratti, C.

    2017-03-01

    Sharing rides could drastically improve the efficiency of car and taxi transportation. Unleashing such potential, however, requires understanding how urban parameters affect the fraction of individual trips that can be shared, a quantity that we call shareability. Using data on millions of taxi trips in New York City, San Francisco, Singapore, and Vienna, we compute the shareability curves for each city, and find that a natural rescaling collapses them onto a single, universal curve. We explain this scaling law theoretically with a simple model that predicts the potential for ride sharing in any city, using a few basic urban quantities and no adjustable parameters. Accurate extrapolations of this type will help planners, transportation companies, and society at large to shape a sustainable path for urban growth.

  14. Scaling Law of Urban Ride Sharing

    CERN Document Server

    Tachet, Remi; Santi, Paolo; Resta, Giovanni; Szell, Michael; Strogatz, Steven; Ratti, Carlo

    2016-01-01

    Sharing rides could drastically improve the efficiency of car and taxi transportation. Unleashing such potential, however, requires understanding how urban parameters affect the fraction of individual trips that can be shared, a quantity that we call shareability. Using data on millions of taxi trips in New York City, San Francisco, Singapore, and Vienna, we compute the shareability curves for each city, and find that a natural rescaling collapses them onto a single, universal curve. We explain this scaling law theoretically with a simple model that predicts the potential for ride sharing in any city, using a few basic urban quantities and no adjustable parameters. Accurate extrapolations of this type will help planners, transportation companies, and society at large to shape a sustainable path for urban growth.

  15. Nueva movilidad : Park & ride Les Planes

    OpenAIRE

    Guerrero Riveiro, Fermín Hernán

    2016-01-01

    El ejercicio nace con un extenso análisis sobre las realidades del Area Metropolitana de Barcelona que pone de manifiesto el déficit de estacionamientos de disuasión o "Parks and Rides" en torno a las estaciones de tren. Posteriormente se explora, a fondo, uno de estos puntos detectados (Les Planes) y se plantean una serie de intervenciones de mejora.

  16. Synthesis, crystal structures, and properties of two novel cadmium(II)-organic frameworks based on asymmetric dicarboxylate and N-donor ligands

    Science.gov (United States)

    Chen, Xiaoli; Gao, Loujun; Zhang, Xiaoge; Han, Xuhua; Wang, Yao; Sun, Rong

    2014-08-01

    Two novel cadmium(II)-organic frameworks with asymmetric dicarboxylate and N-donor ligands, namely [Cd(cpa)(phen)]n (1) and {[Cd2(cpa)2(bpy)1.5]·0.5H2O}n (2) (H2cpa = 3-(4-benzoic)propionic acid, phen = 1,10-phenanthroline, bpy = 4,4";-bipyridine) have been hydrothermally synthesized and characterized by elemental analyses, FT-IR spectra, single-crystal X-ray diffraction analyses, TGA, powder XRD and fluorescent measurements. 1 displays a double zigzag chain structure containing 8-number and 22-number circles. 2 Shows a 6-connected 3D polymer network based on tetranuclear cadmium cluster units. The most striking feature of 2 is that a pair of identical 3D networks are interlocked with each other to the form a 2-fold interpenetrated 3D α-Po structural topology. The diverse structures of two complexes indicate that the skeleton of N-donor ligands plays a great role in the assembly of such different frameworks. In addition, the thermal stabilities, XRD and photoluminescence properties of 1-2 were also studied.

  17. In silico design and construction of metal-binding hybrid proteins for specific removal of cadmium based on CS3 pili display on the surface of Escherichia coli.

    Science.gov (United States)

    Eskandari, Vajiheh; Yakhchali, Bagher; Sadeghi, Mehdi; Karkhane, Ali Asghar

    2013-01-01

    In this study, through a combination of bioinformatics and genetic engineering procedures, high-affinity metal-binding peptides were designed and expressed on the surface of Escherichia coli for selective Cd(2+) adsorption. Putative cadmium-binding motifs were identified by searches against the Prosite database and permissive sites in the major subunit (CstH) of the enterotoxigenic E. coli pili were predicted based on the data derived from modeling of 3D structures, secondary structure prediction and assignment, inspection of protein hydropathy and exposed regions, and also protein interaction sites. The metal-binding motifs were inserted into one permissive site of the CstH (amino acid 38) with the aid of the SOEing PCR technique. The capacity and selectivity of the recombinant bacteria displaying hybrid pili to adsorb cadmium were evaluated with the atomic absorption procedure. The levels of Cd(2+) accumulation in the recombinant E. coli strains were 13.9- and 11.33-fold higher than those in the control strain. Cd(2+) was selectively absorbed from a solution containing equal concentrations of four metals, resulting in more than 90% of the total adsorbed metals being Cd(2+) , showing a relatively high affinity for Cd(2+) over other coexisting metal ions. © 2013 International Union of Biochemistry and Molecular Biology, Inc.

  18. Mitigating Free Riding in Peer-To-Peer Networks: Game Theory ...

    African Journals Online (AJOL)

    The performance of peer-to-peer systems is based on the quality and quantity of resource contributions from participating peers. In most systems, users are assumed to be cooperative, but in reality, sharing in peer-to-peer systems is faced with the problem of free riding. In this paper, we model the interactions between peers ...

  19. Self-balancing air riding seal for a turbine

    Energy Technology Data Exchange (ETDEWEB)

    Mills, Jacob A.

    2017-08-15

    A turbine of a gas turbine engine has an air riding seal that forms a seal between a rotor and a stator of the turbine, the air riding seal including an annular piston movable in an axial direction under the influence of a pressure on one side with a pressure acting on an opposite side that self-balances the air riding seal during the steady state condition of the engine and lifts off the seal during engine transients.

  20. Cognitive motivations of free riding and cooperation and impaired strategic decision making in schizophrenia during a public goods game.

    Science.gov (United States)

    Chung, Dongil; Kim, Yang-Tae; Jeong, Jaeseung

    2013-01-01

    Schizophrenia is generally characterized by various positive and negative symptoms that are accompanied by significant social dysfunction. Various researchers investigated the functional impairments in schizophrenia including impaired theory of mind (TOM), poor integration of affective and cognitive information, and malfunctioning of adaptive and strategic learning process. However, most of the studies were limited to simplified cognitive tests or computerized choice games that exclude real social interaction. The aim of the current study was to investigate human strategies based on the incentives and particularly the cognitive and emotional motivations of free riding. We examined the decision patterns of 41 healthy subjects (HSs) and 37 schizophrenia patients (SZ) during the public goods game (PGG), one of the games simulating human cooperation and free riding in group interactions. Strategic decision processes during the iterative binary PGG were assessed in terms of cognitive understanding, loss sensitivity, and TOM. We found that greed and loss sensitivity both motivated free-riding behavior in the HS, but that they were more vulnerable to greedy incentives than to possible loss. More significantly, the SZ clearly displayed a lower prevalence of free riding and distinct decision patterns from HS. Nonstrategic and unexpectedly low free ridings in the SZ likely arise from poor integration of cognitive and affective information. We suggest that loss sensitivity and TOM as well as cognitive understanding are involved in regulation of the free riding and cooperative behavior.

  1. Cadmium Sulphide-Reduced Graphene Oxide-Modified Photoelectrode-Based Photoelectrochemical Sensing Platform for Copper(II) Ions.

    Science.gov (United States)

    Ibrahim, I; Lim, H N; Huang, N M; Pandikumar, A

    2016-01-01

    A photoelectrochemical (PEC) sensor with excellent sensitivity and detection toward copper (II) ions (Cu2+) was developed using a cadmium sulphide-reduced graphene oxide (CdS-rGO) nanocomposite on an indium tin oxide (ITO) surface, with triethanolamine (TEA) used as the sacrificial electron donor. The CdS nanoparticles were initially synthesized via the aerosol-assisted chemical vapor deposition (AACVD) method using cadmium acetate and thiourea as the precursors to Cd2+ and S2-, respectively. Graphene oxide (GO) was then dip-coated onto the CdS electrode and sintered under an argon gas flow (50 mL/min) for the reduction process. The nanostructured CdS was adhered securely to the ITO by a continuous network of rGO that also acted as an avenue to intensify the transfer of electrons from the conduction band of CdS. The photoelectrochemical results indicated that the ITO/CdS-rGO photoelectrode could facilitate broad UV-visible light absorption, which would lead to a higher and steady-state photocurrent response in the presence of TEA in 0.1 M KCl. The photocurrent decreased with an increase in the concentration of Cu2+ ions. The photoelectrode response for Cu2+ ion detection had a linear range of 0.5-120 μM, with a limit of detection (LoD) of 16 nM. The proposed PEC sensor displayed ultra-sensitivity and good selectivity toward Cu2+ ion detection.

  2. Calcium enhances cadmium tolerance and decreases cadmium ...

    African Journals Online (AJOL)

    These results suggest that cadmium uptake in lettuce plants is negatively associated with the presence of calcium in the culture medium, maybe due to a competition between these two cations for binding and absorption sites in roots. In conclusion, the results suggest that fertilization with Ca2+ appears to be a promising ...

  3. Cadmium induces transcription independently of intracellular calcium mobilization.

    Directory of Open Access Journals (Sweden)

    Brooke E Tvermoes

    Full Text Available BACKGROUND: Exposure to cadmium is associated with human pathologies and altered gene expression. The molecular mechanisms by which cadmium affects transcription remain unclear. It has been proposed that cadmium activates transcription by altering intracellular calcium concentration ([Ca(2+](i and disrupting calcium-mediated intracellular signaling processes. This hypothesis is based on several studies that may be technically problematic; including the use of BAPTA chelators, BAPTA-based fluorescent sensors, and cytotoxic concentrations of metal. METHODOLOGY/PRINCIPAL FINDING: In the present report, the effects of cadmium on [Ca(2+](i under non-cytotoxic and cytotoxic conditions was monitored using the protein-based calcium sensor yellow cameleon (YC3.60, which was stably expressed in HEK293 cells. In HEK293 constitutively expressing YC3.60, this calcium sensor was found to be insensitive to cadmium. Exposing HEK293::YC3.60 cells to non-cytotoxic cadmium concentrations was sufficient to induce transcription of cadmium-responsive genes but did not affect [Ca(2+](i mobilization or increase steady-state mRNA levels of calcium-responsive genes. In contrast, exposure to cytotoxic concentrations of cadmium significantly reduced intracellular calcium stores and altered calcium-responsive gene expression. CONCLUSIONS/SIGNIFICANCE: These data indicate that at low levels, cadmium induces transcription independently of intracellular calcium mobilization. The results also support a model whereby cytotoxic levels of cadmium activate calcium-responsive transcription as a general response to metal-induced intracellular damage and not via a specific mechanism. Thus, the modulation of intracellular calcium may not be a primary mechanism by which cadmium regulates transcription.

  4. Floating air riding seal for a turbine

    Energy Technology Data Exchange (ETDEWEB)

    Ebert, Todd A

    2016-08-16

    A floating air riding seal for a gas turbine engine with a rotor and a stator, an annular piston chamber with an axial moveable annular piston assembly within the annular piston chamber formed in the stator, an annular cavity formed on the annular piston assembly that faces a seal surface on the rotor, where the axial moveable annular piston includes an inlet scoop on a side opposite to the annular cavity that scoops up the swirling cooling air and directs the cooling air to the annular cavity to form an air cushion with the seal surface of the rotor.

  5. Calming the Waters or Riding the Waves?

    DEFF Research Database (Denmark)

    Rydén, Pernille; Kottika, Efthymia; Hossain, Muhammad Ismail

    that strengthens their brand. The consumers are empowered by ‘letting this anger out’, from which firms can gain huge attention. Companies can utilize such situations to inform people on their brands’ core values, and initiate discussions of larger societal relevance, which improves the brand awareness and value......Traditional consumer anger management tends to be compromising rather than empowering the brand. This paper conceptualizes and provides a case example on how consumer empowerment and negative emotions can in fact create opportunities for companies to ride the waves of consumer anger in a way...

  6. Synchrotron-based X-Ray Spectroscopy Studies for Redox-based Remediation of Lead, Zinc, and Cadmium in Mine Waste Materials.

    Science.gov (United States)

    Karna, Ranju R; Hettiarachchi, Ganga M; Newville, Matthew; Sun, ChengJun; Ma, Qing

    2016-11-01

    Several studies have examined the effect of submergence on the mobility of metals present in mine waste materials. This study examines the effect of organic carbon (OC) and sulfur (S) additions and submergence time on redox-induced biogeochemical transformations of lead (Pb), zinc (Zn), and cadmium (Cd) present in mine waste materials collected from the Tri-State mining district located in southeastern Kansas, southwestern Missouri, and northeastern Oklahoma. A completely randomized design, with a two-way treatment structure, was used for conducting a series of column experiments. Two replicates were used for each treatment combination. Effluent samples were collected at several time points, and soil samples were collected at the end of each column experiment. Because these samples are highly heterogeneous, we used a variety of synchrotron-based techniques to identify Pb, Zn, and Cd speciation at both micro- and bulk-scale. Spectroscopic analysis results from the study revealed that the addition of OC, with and without S, promoted metal-sulfide formation, whereas metal carbonates dominated in the nonamended flooded materials and in mine waste materials only amended with S. Therefore, the synergistic effect of OC and S may be more promising for managing mine waste materials disposed of in flooded subsidence mine pits instead of individual S or OC treatments. The mechanistic understanding gained in this study is also relevant for remediation of waste materials using natural or constructed wetland systems. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  7. Domain walls riding the wave.

    Energy Technology Data Exchange (ETDEWEB)

    Karapetrov, G.; Novosad, V.; Materials Science Division

    2010-11-01

    ferromagnetic wire is the preferred method, as it combines manipulation and readout of the domain-wall state. The electrons that take part in the process of readout and manipulation of the domain-wall structure in the nanowire do so through the so-called spin transfer torque: When spin-polarized electrons in the ferromagnet nanowire pass through the domain wall they experience a nonuniform magnetization, and they try to align their spins with the local magnetic moments. The force that the electrons experience has a reaction force counterpart that 'pushes' the local magnetic moments, resulting in movement of the domain wall in the direction of the electron flow through the spin-transfer torque. The forces between the electrons and the local magnetic moments in the ferromagnet also create additional electrical resistance for the electrons passing through the domain wall. By measuring resistance across a segment of the nanowire, one determines if a domain wall is present; i.e., one can read the stored information. The interaction of the spin-polarized electrons with the domain wall in the ferromagnetic nanowire is not very efficient. Even for materials achieving high polarization of the free electrons, it is very difficult to move the magnetic domain wall. Several factors contribute to this problem, with imperfections of the ferromagnetic nanowire that cause domain-wall pinning being the dominant one. Permalloy nanowires, one of the best candidates for domain-wall-based memory and logic devices, require current densities of the order of 10{sup 8} A/cm{sup 2} in order to move a domain wall from a pinning well. Considering that this current has to pass through a relatively long wire, it is not very difficult to imagine that most of the energy will go to Joule heating. The efficiency of the process - the ratio of the energy converted to domain-wall motion to the total energy consumed - is comparable to that of an incandescent light bulb converting electricity to light. A

  8. Cadmium Sulphide-Reduced Graphene Oxide-Modified Photoelectrode-Based Photoelectrochemical Sensing Platform for Copper(II Ions.

    Directory of Open Access Journals (Sweden)

    I Ibrahim

    Full Text Available A photoelectrochemical (PEC sensor with excellent sensitivity and detection toward copper (II ions (Cu2+ was developed using a cadmium sulphide-reduced graphene oxide (CdS-rGO nanocomposite on an indium tin oxide (ITO surface, with triethanolamine (TEA used as the sacrificial electron donor. The CdS nanoparticles were initially synthesized via the aerosol-assisted chemical vapor deposition (AACVD method using cadmium acetate and thiourea as the precursors to Cd2+ and S2-, respectively. Graphene oxide (GO was then dip-coated onto the CdS electrode and sintered under an argon gas flow (50 mL/min for the reduction process. The nanostructured CdS was adhered securely to the ITO by a continuous network of rGO that also acted as an avenue to intensify the transfer of electrons from the conduction band of CdS. The photoelectrochemical results indicated that the ITO/CdS-rGO photoelectrode could facilitate broad UV-visible light absorption, which would lead to a higher and steady-state photocurrent response in the presence of TEA in 0.1 M KCl. The photocurrent decreased with an increase in the concentration of Cu2+ ions. The photoelectrode response for Cu2+ ion detection had a linear range of 0.5-120 μM, with a limit of detection (LoD of 16 nM. The proposed PEC sensor displayed ultra-sensitivity and good selectivity toward Cu2+ ion detection.

  9. Cadmium Sulphide-Reduced Graphene Oxide-Modified Photoelectrode-Based Photoelectrochemical Sensing Platform for Copper(II) Ions

    Science.gov (United States)

    Ibrahim, I; Lim, H. N; Huang, N. M; Pandikumar, A

    2016-01-01

    A photoelectrochemical (PEC) sensor with excellent sensitivity and detection toward copper (II) ions (Cu2+) was developed using a cadmium sulphide-reduced graphene oxide (CdS-rGO) nanocomposite on an indium tin oxide (ITO) surface, with triethanolamine (TEA) used as the sacrificial electron donor. The CdS nanoparticles were initially synthesized via the aerosol-assisted chemical vapor deposition (AACVD) method using cadmium acetate and thiourea as the precursors to Cd2+ and S2-, respectively. Graphene oxide (GO) was then dip-coated onto the CdS electrode and sintered under an argon gas flow (50 mL/min) for the reduction process. The nanostructured CdS was adhered securely to the ITO by a continuous network of rGO that also acted as an avenue to intensify the transfer of electrons from the conduction band of CdS. The photoelectrochemical results indicated that the ITO/CdS-rGO photoelectrode could facilitate broad UV-visible light absorption, which would lead to a higher and steady-state photocurrent response in the presence of TEA in 0.1 M KCl. The photocurrent decreased with an increase in the concentration of Cu2+ ions. The photoelectrode response for Cu2+ ion detection had a linear range of 0.5–120 μM, with a limit of detection (LoD) of 16 nM. The proposed PEC sensor displayed ultra-sensitivity and good selectivity toward Cu2+ ion detection. PMID:27176635

  10. Application of Cold-Induced Aggregation Microextraction Based on Ionic Liquid for Determination of Trace Amount of Cadmium and Lead in Powder Milk Samples

    Directory of Open Access Journals (Sweden)

    Mostafa Delavar

    2014-06-01

    Full Text Available Background: cold-induced aggregation micro extraction based (CIAME based on ionic liquid was used as a rapid and simple method for determination trace amounts of cadmium and lead in milk powder by analysis with flame atomic absorption spectrometry (FAAS. Methods: Sample solution containing of Cd2+ and Pb2+ in dynamic range, phosphate buffer (pH = 9, 3 ml, diethyl dithiocarbamate (complexing agent, Triton X-100, NaPF6 ,[HMIM][PF6] (extraction solvent were transferred into conical bottom glass tube. Sample was kept in a thermostated bath and then ice bath; a cloudy solution was formed. Two phases separated by centrifugation. After removing of aqueous phase, IL-phase was dissolved in methanol and diluted was injected to the FAAS by microsampler introduction. Results: ILs, containing imidazoliumcation and hexafluoro phosphate anion, [HMIM][PF6](70mg, 200 mg NaPF6 ,0.01 mol.L-1 DDTC, 0.015% of Triton X-100 obtained, pH 9 and centrifuge time; 5 min (4000 rmp was chosen. Detection limit were obtained 0.12 µgL-1, 1.61µgL-1, RSD 0.95%, 2.2% and enrichment factor of 70, 67 for Cd and Pb, respectively. Conclusion: CIAME allows determination of cadmium and lead in real samples in a simple, rapid and safe method with only a small amount of ionic liquid was used. In comparison with the organic solvent extraction, CIAME is much safer and the determination of species in high ionic strength samples is possible.

  11. Removal of cadmium in urban wastewater with systems based on zeolite type clinoptilolite; Remocion de cadmio en aguas residuales urbanas con sistemas a base de zeolita tipo clinoptilolita

    Energy Technology Data Exchange (ETDEWEB)

    Barragan P, P.

    2016-07-01

    From an environmental issue detected in wastewater samples taken in a municipal wastewater collector in Nogales, Sonora, which is related to cadmium pollution, a research project came out where the principal aim was to implement a system to remove metallic ions of cadmium in wastewater, based on modified and unmodified natural zeolites. The zeolitic material used was natural clinoptilolite modified with NaCl and thiourea, sourced in El Cajon and Guaymas, Sonora. The materials were characterized with X-ray diffraction, Sem, Ft-IR spectra, and Bet analysis. The kinetics of four modified zeolites was investigated at ph=5 and initial concentration of 30 mgL{sup -1} of Cd{sup 2+}. The pseudo-first, the pseudo-second order, and Elovich models were applied to the experimental results. The results best fitted to pseudo-second order model. The maximum sorption capacity of modified zeolites was investigated through isotherms, The Langmuir model, Freundlich, and the combined Langmuir-Freundlich models were applied to the experimental results afterwards. ZGuayThio showed the highest sorption capacity, 11.60 mgg{sup -1}, with R{sup 2}=0.978 according to Langmuir-Freundlich model. Fixed-bed column adsorption experiments were carried out with ZGuayNa and ZGuayThio with three bed heights with 30 mgL{sup -1} solution of Cd{sup 2+}. influent at a flow rate of 1 mLmin{sup -1}, at ph=5. The Thomas, mass balance, and Bed Depth Service Time models were applied to the results. The dynamic adsorption capacity (No) and the constant of sorption velocity (K a) were determined, 28.67 gL{sup -1} and 0.072 Lg{sup -1}min{sup -1} respectively for ZGuayNa with R{sup 2}= 0.9954. Column experiments with municipal wastewater from Colinas del Yaqui sub-collector, previously characterized, were conducted using ZGuayNa and ZGuayThio. A mass transference model was applied to the results which accounted for K{sub p}= 0.815 m{sup 3}Kg{sup -}1 with R{sup 2}= 0.9789 for ZGuayNa, and K{sub p}= 3.1 m{sup 3}Kg

  12. Feasibility Testing for Dial-a-Ride Problems

    DEFF Research Database (Denmark)

    Haugland, Dag; Ho, Sin C.

    2010-01-01

    Hunsaker and Savelsbergh have proposed an algorithm for testing feasibility of a route in the solution to the dial-a-ride problem. The constraints that are checked are load capacity constraints, time windows, ride time bounds and wait time bounds. The algorithm has linear running time. By virtue ...

  13. Ride-sharing activities in the Richmond regional planning district.

    Science.gov (United States)

    1977-01-01

    This report gives the results of a survey made of industries in the Richmond Regional Planning District to determine the current and expected ride-sharing activities there and the type of information deemed most useful in planning ride-sharing progra...

  14. Examination of a University-Affiliated Safe Ride Program

    Science.gov (United States)

    Gieck, D. Joseph; Slagle, David M.

    2010-01-01

    A university-affiliated safe ride program was evaluated to determine whether these programs can reduce drunk-driving related costs. Data was collected from 187 safe ride passengers during three nights of operation. Among the passengers, 93% were enrolled at a local University, 31% were younger than 21, and 40% reported a prior alcohol-related…

  15. Feasibility testing for dial-a-ride problems

    DEFF Research Database (Denmark)

    Haugland, Dag; Ho, Sin C.

    Hunsaker and Savelsbergh have proposed an algorithm for testing feasibility of a route in the solution to the dial-a-ride problem. The constraints that are checked are load capacity constraints, time windows, ride time bounds and wait time bounds. The algorithm has linear running time. By virtue...

  16. Ride performance of a high speed rail vehicle using controlled semi active suspension system

    Science.gov (United States)

    Sharma, Sunil Kumar; Kumar, Anil

    2017-05-01

    The rail-wheel interaction in a rail vehicle running at high speed results in large amplitude vibration of carbody that deteriorates the ride comfort of travellers. The role of suspension system is crucial to provide an acceptable level of ride performance. In this context, an existing rail vehicle is modelled in vertical, pitch and roll motions of carbody and bogies. Additionally, nonlinear stiffness and damping parameters of passive suspension system are defined based on experimental data. In the secondary vertical suspension system, a magneto-rheological (MR) damper is included to improve the ride quality and comfort. The parameters of MR damper depend on the current, amplitude and frequency of excitations. At different running speeds, three semi-active suspension strategies with MR damper are analysed for periodic track irregularity and the resulting performance indices are juxtaposed with the nonlinear passive suspension system. The disturbance rejection and force tracking damper controller algorithms are applied to control the desired force of MR damper. This study reveals that the vertical vibrations of a vehicle can be reduced significantly by using the proposed semi-active suspension strategies. Moreover, it naturally results in improved ride quality and passenger’s comfort in comparison to the existing passive system.

  17. Mutagenic effect of cadmium on tetranucleotide repeats in human cells

    Energy Technology Data Exchange (ETDEWEB)

    Slebos, Robbert J.C. [Department of Cancer Biology, Vanderbilt-Ingram Cancer Center, Vanderbilt University School of Medicine, Nashville, TN 37232 (United States) and Department of Otolaryngology, Vanderbilt-Ingram Cancer Center, Vanderbilt University School of Medicine, Nashville, TN 37232 (United States)]. E-mail: r.slebos@vanderbilt.edu; Li Ming [Department of Biostatistics, Vanderbilt-Ingram Cancer Center, Vanderbilt University School of Medicine, Nashville, TN 37232 (United States); Evjen, Amy N. [Department of Cancer Biology, Vanderbilt-Ingram Cancer Center, Vanderbilt University School of Medicine, Nashville, TN 37232 (United States); Coffa, Jordy [Department of Cancer Biology, Vanderbilt-Ingram Cancer Center, Vanderbilt University School of Medicine, Nashville, TN 37232 (United States); Shyr, Yu [Department of Biostatistics, Vanderbilt-Ingram Cancer Center, Vanderbilt University School of Medicine, Nashville, TN 37232 (United States); Yarbrough, Wendell G. [Department of Cancer Biology, Vanderbilt-Ingram Cancer Center, Vanderbilt University School of Medicine, Nashville, TN 37232 (United States); Department of Otolaryngology, Vanderbilt-Ingram Cancer Center, Vanderbilt University School of Medicine, Nashville, TN 37232 (United States)

    2006-12-01

    Cadmium is a human carcinogen that affects cell proliferation, apoptosis and DNA repair processes that are all important to carcinogenesis. We previously demonstrated that cadmium inhibits DNA mismatch repair (MMR) in yeast cells and in human cell-free extracts (H.W. Jin, A.B. Clark, R.J.C. Slebos, H. Al-Refai, J.A. Taylor, T.A. Kunkel, M.A. Resnick, D.A. Gordenin, Cadmium is a mutagen that acts by inhibiting mismatch repair, Nat. Genet. 34 (3) (2003) 326-329), but cadmium also inhibits DNA excision repair. For this study, we selected a panel of three hypermutable tetranucleotide markers (MycL1, D7S1482 and DXS981) and studied their suitability as readout for the mutagenic effects of cadmium. We used a clonal derivative of the human fibrosarcoma cell line HT1080 to assess mutation levels in microsatellites after cadmium and/or N-methyl-N-nitro-N-nitrosoguanidine (MNNG) exposure to study effects of cadmium in the presence or absence of base damage. Mutations were measured in clonally expanded cells obtained by limiting dilution after exposure to zero dose, 0.5 {mu}M cadmium, 5 nM MNNG or a combination of 0.5 {mu}M cadmium and 5 nM MNNG. Exposure of HT1080-C1 to cadmium led to statistically significant increases in microsatellite mutations, either with or without concurrent exposure to MNNG. A majority of the observed mutant molecules involved 4-nucleotide shifts consistent with DNA slippage mutations that are normally repaired by MMR. These results provide evidence for the mutagenic effects of low, environmentally relevant levels of cadmium in intact human cells and suggest that inhibition of DNA repair is involved.

  18. Cycles of cooperation and free-riding in social systems

    Science.gov (United States)

    Ma, Y. P.; Gonçalves, S.; Mignot, S.; Nadal, J.-P.; Gordon, M. B.

    2009-10-01

    Basic evidences on non-profit making and other forms of benevolent-based organizations reveal a rough partition of members between some pure consumers of the public good (free-riders) and benevolent individuals (cooperators). We study the relationship between the community size and the level of cooperation in a simple model where the utility of joining the community is proportional to its size. We assume an idiosyncratic willingness to join the community ; cooperation bears a fixed cost while free-riding bears a (moral) idiosyncratic cost proportional to the fraction of cooperators. We show that the system presents two types of equilibria: fixed points (Nash equilibria) with a mixture of cooperators and free-riders and cycles where the size of the community, as well as the proportion of cooperators and free-riders, vary periodically.

  19. Solving the Dial-a-Ride Problem using Genetic Algorithms

    DEFF Research Database (Denmark)

    Jørgensen, Rene Munk; Larsen, Jesper; Bergvinsdottir, Kristin Berg

    2007-01-01

    In the Dial-a-Ride problem (DARP), customers request transportation from an operator. A request consists of a specified pickup location and destination location along with a desired departure or arrival time and capacity demand. The aim of DARP is to minimize transportation cost while satisfying...... customer service level constraints (Quality of Service). In this paper, we present a genetic algorithm (GA) for solving the DARP. The algorithm is based on the classical cluster-first, route-second approach, where it alternates between assigning customers to vehicles using a GA and solving independent...... routing problems for the vehicles using a routing heuristic. The algorithm is implemented in Java and tested on publicly available data sets. The new solution method has achieved solutions comparable with the current state-of-the-art methods....

  20. Coordination of Advertising Free Riding in Hybrid Channel Supply Chain

    Directory of Open Access Journals (Sweden)

    Jin Sha

    2016-01-01

    Full Text Available Advertising is a crucial tool for demand creation and market expansion; enterprises in supply chain use it widely to increase sales and improve profits. But the homogeneity of products sold in hybrid channel supply chain magnifies the positive externalities of advertising and leads to serious free-riding problem. To coordinate the supply chain effectively, firstly, this paper classifies hybrid channel supply chain based on the relationship between members and selects horizontally integrated, vertically integrated, and decentralized hybrid channel supply chains as research objects. Then, a demand function considering the common effect of price and advertising is proposed and coordination schemes for different types of supply chains are designed. Finally, a sensitivity analysis is performed to assess the impact of parameters on coordination using orthogonal experiment.

  1. Remediation of cadmium by Indian mustard (Brassica juncea L. from cadmium contaminated soil: a phytoextraction study

    Directory of Open Access Journals (Sweden)

    Rajeev Kumar Bhadkariya

    2014-05-01

    Full Text Available Cadmium is a toxic metal for living organisms and an environmental contaminant. Soils in many parts of the world are slightly too moderately contaminated by Cd due to long term use and disposal of Cd-contaminated wastes. Cost effective technologies are needed to remove cadmium from the contaminated sites. Soil phytoextraction is engineering based, low cost and socially accepted developing technology that uses plants to clean up contaminants in soils. This technology can be adopted as a remediation of cadmium from Cd-contaminated soils with the help of Brassica juncea plant. The objective of this work was to evaluate the cadmium (Cd accumulate and the tolerance of Brassica juncea. The Cd accumulates in all parts of plants (roots, stems and leaves. It was found that accumulating efficiency increased with the increase in the concentration of applied cadmium metal solution. Maximum accumulation of cadmium was found in roots than stem and leaves. Phytoextraction coefficient and translocation factor were highest to show the validity of the Brassica juncea species for hyperaccumulation of the Cd metal. These results suggested that Brassica juncea has a high ability to tolerate and accumulate Cd, so it might be a promising plant to be used for phytoextraction of Cd contaminated soil. DOI: http://dx.doi.org/10.3126/ije.v3i2.10533 International Journal of the Environment Vol.3(2 2014: 229-237

  2. Cadmium exposure and health risks: Recent findings

    Energy Technology Data Exchange (ETDEWEB)

    Elinder, C.G. [Huddinge Hospital (Sweden). Dept. of Renal Medicine; Jaerup, L. [Stockholm City Council (Sweden). Dept. of Environmental Health

    1996-08-01

    Environmental and/or occupational exposure to cadmium give rise to a tubular kidney dysfunction which may proceed to more generalized renal damage and bone disease if exposure has been high and prolonged. Recent scientific work shows that early renal effects develop at lower levels of exposure than previously anticipated. Previous risk assessments for cadmium were mainly based on studies on healthy male workers. The general population, however, also include particularly susceptible groups such as elderly and individuals with illnesses (e.g. diabetes) that may predispose to cadmium-induced health effects. A significant proportion of the general population displays early signs of toxicity already at urinary cadmium concentrations around 3 nmol mmol{sup -1} creatinine. In addition to early tubular effects, cadmium may exert direct or indirect effects on mineral metabolism and the mineralization of the skeleton at relatively low levels of exposure. This may have important health implications, as poor and easily fractured bone is a major problem among the elderly in all industrialized countries. 41 refs, 4 figs

  3. Correlations of urinary cadmium with hypertension and diabetes in persons living in cadmium-contaminated villages in northwestern Thailand: A population study

    Energy Technology Data Exchange (ETDEWEB)

    Swaddiwudhipong, Witaya, E-mail: swaddi@hotmail.com [Department of Community and Social Medicine, Mae Sot General Hospital, Tak 63110 (Thailand); Mahasakpan, Pranee [Department of Community and Social Medicine, Mae Sot General Hospital, Tak 63110 (Thailand); Limpatanachote, Pisit; Krintratun, Somyot [Department of Internal Medicine, Mae Sot General Hospital, Tak (Thailand)

    2010-08-15

    Risk for hypertension and diabetes has not been conclusively found to be a result of cadmium exposure. A population-based study was conducted in 2009 to examine the correlations of urinary cadmium, a good biomarker of long-term cadmium exposure, with hypertension and diabetes in persons aged 35 years and older who lived in the 12 cadmium-contaminated rural villages in northwestern Thailand. A total of 5273 persons were interviewed and screened for urinary cadmium, hypertension, and diabetes. The geometric mean level of urinary cadmium for women (2.4{+-}2.3 {mu}g/g creatinine) was significantly greater than that for men (2.0{+-}2.2 {mu}g/g creatinine). Hypertension was presented in 29.8% of the study population and diabetes was detected in 6.6%. The prevalence of hypertension significantly increased from 25.0% among persons in the lowest tertile of urinary cadmium to 35.0% in the highest tertile. In women, the rate of hypertension significantly increased with increasing urinary cadmium levels in both ever and never smokers, after adjusting for age, alcohol consumption, body mass index, and diabetes. In men, such association was less significantly found in never smokers. The study revealed no significant association between urinary cadmium and diabetes in either gender. Our study supports the hypothesis that environmental exposure to cadmium may increase the risk of hypertension. Risk for diabetes in relation to cadmium exposure remains uncertain in this exposed population.

  4. Share-A-Ride rideshare matching system (SARRMS). Systeme de coordination du covoiturage Share-A-Ride (SCCSAR)

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-01

    SARRMS (Share-A-Ride Rideshare Matching System) is an on-line, interactive system that produces up-to-date personalized matching information for rideshare applicants. SARRMS operates on microcomputers and is capable of handling a large number of requests with a high degree of accuracy and speed. The system is flexible enough to be used by employers, municipalities, and ridesharing agencies to provide rideshare matching service. It has been designed specifically for Canadian applications. The features of SARRMS are outlined, including the five software subsystems (Rideshare, Vanpool, Secondary File Maintenance, Report production in English or French, Purge, and Backup). Matching is done on basis of location, and a printout is obtained for the applicant which gives a list of possible pooling partners who have similar commuting characteristics, a list of vanpool operators and transit operators serving the applicant's zone, and a list of carpool parking lots based on commuting direction. A sample search is included.

  5. Cadmium verification measurements of HFIR shroud assembly 22

    Energy Technology Data Exchange (ETDEWEB)

    Chapman, J.A.; Schultz, F.J.

    1994-04-01

    This report discusses radiation-based nondestructive examination methods which have been used to successfully verify the presence of cadmium in High Flux Isotope Reactor (HFIR) spent-fuel shroud assembly number 22 (SA22). These measurements show, in part, that SA22 is certified to meet the criticality safety specifications for a proposed reconfiguration of the HFIR spent-fuel storage array. Measurement of the unique 558.6-keV gamma-ray from neutron radiative capture on cadmium provided conclusive evidence for the presence of cadmium in the outer shroud of the assembly. Cadmium verification in the center post and outer shroud was performed by measuring the degree of neutron transmission in SA22 relative to two calibration shroud assemblies. Each measurement was performed at a single location on the center post and outer shroud. These measurements do not provide information on the spatial distribution or uniformity of cadmium within an assembly. Separate measurements using analog and digital radiography were performed to (a) globally map the continuity of cadmium internal mass, and (b) locally determine the thickness of cadmium. Radiography results will be reported elsewhere. The measurements reported here should not be used to infer the thickness of cadmium in either the center post or outer shroud of an assembly.

  6. Cadmium Removal from Aqueous Solutions by Ground Pine Cone

    Directory of Open Access Journals (Sweden)

    H Izanloo, S Nasseri

    2005-01-01

    Full Text Available A study on the removal of cadmium ions from aqueous solutions by pine cone was conducted in batch conditions. Kinetic data and equilibrium removal isotherms were obtained. The influence of different experimental parameters such as contact time, initial concentration of cadmium, pine cone mass and particle size, and temperature on the kinetics of cadmium removal was studied. Results showed that the main parameters that played an important role in removal phenomenon were initial cadmium concentration, particle size and pine cone mass. The necessary time to reach equilibrium was between 4 and 7 hours based on the initial concentration of cadmium. The capacity of cadmium adsorption at equilibrium increased with the decrease of pine cone particle size. The capacity of cadmium adsorption at equilibrium by pine cone increased with the quantity of pine cone introduced (1–4 g/L. Temperature in the range of 20-30°C showed a restricted effect on the removal kinetics (13.56 mg/g at 20°C and a low capacity of adsorption about 11.48 mg/g at 30°C. The process followed pseudo second-order kinetics. The cadmium uptake of pine cone was quantitatively evaluated using adsorption isotherms. Results indicated that the Langmuir model gave a better fit to the experimental data in comparison with the Freundlich equation.

  7. Rapid identification of soil cadmium pollution risk at regional scale based on visible and near-infrared spectroscopy.

    Science.gov (United States)

    Chen, Tao; Chang, Qingrui; Clevers, J G P W; Kooistra, L

    2015-11-01

    Soil heavy metal pollution due to long-term sewage irrigation is a serious environmental problem in many irrigation areas in northern China. Quickly identifying its pollution status is an important basis for remediation. Visible-near-infrared reflectance spectroscopy (VNIRS) provides a useful tool. In a case study, 76 soil samples were collected and their reflectance spectra were used to estimate cadmium (Cd) concentration by partial least squares regression (PLSR) and back propagation neural network (BPNN). To reduce noise, six pre-treatments were compared, in which orthogonal signal correction (OSC) was first used in soil Cd estimation. Spectral analysis and geostatistics were combined to identify Cd pollution hotspots. Results showed that Cd was accumulated in topsoil at the study area. OSC can effectively remove irrelevant information to improve prediction accuracy. More accurate estimation was achieved by applying a BPNN. Soil Cd pollution hotspots could be identified by interpolating the predicted values obtained from spectral estimates. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Sensitive determination of cadmium in water samples by room temperature ionic liquid-based preconcentration and electrothermal atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Martinis, Estefania M. [Laboratory of Environmental Research and Services of Mendoza (LISAMEN), (CCT - CONICET - Mendoza), Av. Ruiz Leal S/N Parque General San Martin, C.C. 131, M 5502 IRA Mendoza (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET) (Argentina); Olsina, Roberto A. [Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET) (Argentina); Departamento de Quimica Analitica, Facultad de Quimica, Bioquimica y Farmacia, Universidad Nacional de San Luis (Argentina); Altamirano, Jorgelina C. [Laboratory of Environmental Research and Services of Mendoza (LISAMEN), (CCT - CONICET - Mendoza), Av. Ruiz Leal S/N Parque General San Martin, C.C. 131, M 5502 IRA Mendoza (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET) (Argentina); Instituto de Ciencias Basicas, Universidad Nacional de Cuyo, Mendoza (Argentina); Wuilloud, Rodolfo G. [Laboratory of Environmental Research and Services of Mendoza (LISAMEN), (CCT - CONICET - Mendoza), Av. Ruiz Leal S/N Parque General San Martin, C.C. 131, M 5502 IRA Mendoza (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET) (Argentina); Instituto de Ciencias Basicas, Universidad Nacional de Cuyo, Mendoza (Argentina)], E-mail: rwuilloud@mendoza-conicet.gov.ar

    2008-10-17

    A sensitive preconcentration methodology for Cd determination at trace levels in water samples was developed in this work. 1-Butyl-3-methylimidazolium hexafluorophosphate ([C{sub 4}MIM][PF{sub 6}]) room temperature ionic liquid (RTIL) was successfully used for Cd preconcentration, as cadmium-2-(5-bromo-2-pyridylazo)-5-diethylaminophenol complex [Cd-5-Br-PADAP]. Subsequently, Cd was back-extracted from the RTIL phase with 500 {mu}L of 0.5 mol L{sup -1} nitric acid and determined by electrothermal atomic absorption spectrometry (ETAAS). A preconcentration factor of 40 was achieved with 20 mL of sample. The limit of detection (LOD) obtained under optimum conditions was 3 ng L{sup -1} and the relative standard deviation (R.S.D.) for 10 replicates at 1 {mu}g L{sup -1} Cd{sup 2+} concentration level was 3.5%, calculated at peak heights. The calibration graph was linear from concentration levels near the detection limits up to at least 5 {mu}g L{sup -1}. A correlation coefficient of 0.9997 was achieved. Validation of the methodology was performed by standard addition method and analysis of certified reference material (CRM). The method was successfully applied to the determination of Cd in river and tap water samples.

  9. Watching Your Back While Riding Your Bike

    DEFF Research Database (Denmark)

    Sokoler, Tomas; Bagalkot, Naveen

    2017-01-01

    series of investigations looking into the broader notion of integrating measures for preventive self-care with existing everyday activities (e.g daily motorcycle commute) by means of digital technology. We are guided by the concept of embodied self-monitoring grounded in theories on the embodied...... encourage us to a) further elaborate our interactive sketches for motorbike commuting and b) further investigate more broadly the design of digital technology in support of preventive self-care as an integrated part of mundane activities such as, in the case at hand, the daily motorcycle commute....... for interaction design in the domain of preventive self-care. We report on the outcome of in-situ enactments performed by four motorbike riders as co-explorers engaging with our interactive soft&hardware sketches while actually riding in traffic. Insitu enactments and follow-up interviews with the riders...

  10. 30 CFR 56.16011 - Riding hoisted loads or on the hoist hook.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Riding hoisted loads or on the hoist hook. 56... Materials Storage and Handling § 56.16011 Riding hoisted loads or on the hoist hook. Persons shall not ride on loads being moved by cranes or derricks, nor shall they ride the hoisting hooks unless such method...

  11. 30 CFR 57.16011 - Riding hoisted loads or on the hoist hook.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Riding hoisted loads or on the hoist hook. 57... MINES Materials Storage and Handling § 57.16011 Riding hoisted loads or on the hoist hook. Persons shall not ride on loads being moved by cranes or derricks, nor shall they ride the hoisting hooks unless...

  12. Analyzing Forces on Amusement Park Rides with Mobile Devices

    Science.gov (United States)

    Vieyra, Rebecca E.; Vieyra, Chrystian

    2014-03-01

    Mobile device accelerometers are a simple and easy way for students to collect accurate and detailed data on an amusement park ride. The resulting data can be graphed to assist in the creation of force diagrams to help students explain their physical sensations while on the ride. This type of activity can help students overcome some of the conceptual difficulties often associated with understanding centripetal force and typical "elevator-type problems" that are inherent in so many amusement park rides that move, lift, and drop riders. This article provides some sample data and examples from a visit to Six Flags Great America.

  13. Recognition of Bike-Riding States with HMM Analysis

    Science.gov (United States)

    Thepvilojanapong, Niwat; Sugo, Keiji; Namiki, Yutaka; Tobe, Yoshito

    2011-06-01

    In this paper, we design and implement an sBike (Sensorized Bike) prototype to support cyclists by recognizing various riding states including going straight, turning right or left, meandering, and stopping. An Android phone, which is equipped with a gyro sensor, an accelerometer, and a GPS receiver, is mounted on the handle of bicycle to collect necessary data for analysis. Hidden Markov model (HMM) is adopted to recognize the riding states from raw sensor data. The experimental results show that the accuracy of recognition is as high as 98%. By knowing the riding states of cyclists, road conditions can be inferred and shared amongst users.

  14. Rider training, reasons for riding, and the social context of riding among young on-road motorcyclists in New Zealand.

    Science.gov (United States)

    Reeder, A I; Chalmers, D J; Langley, J D

    1996-08-01

    Serious injuries to young motorcyclists represent an important public health problem. Little is known about the opinions and behaviours of the young riders at risk. We document the training experiences of young motorcyclists, and their reasons for riding or discontinuing riding, and identify the role models and sources of disapproval of motorcycling. The research was part of a longitudinal study of health, development, attitudes and behaviours of a birth cohort. At age 18 years, cohort members who had ridden a motorcycle during the past year completed a comprehensive questionnaire. Initial riding instruction was rarely received from a qualified instructor but was usually informal, from a male friend or father, and occurred off the road, usually on a farm. The most commonly given reasons for riding were excitement and economy. Most motorcyclists who had ceased riding attributed this to the lack of access to a motorcycle, and few mentioned safety. Mothers were the main source of disapproval. The young riders were not a homogeneous group. More licensed than unlicensed riders said manoeuvrability in traffic and ease of parking were reasons for riding. Licensed motorcyclists had more friends who rode and were more likely than unlicensed riders to have received paternal instruction. Early informal training off the road may establish attitudes and behaviours inappropriate in a traffic context. The main reasons for motorcycling (excitement, economical and manoeuvrable transport, freedom from supervision) and for discontinuing riding (lack of access) indicate motivations that should be considered before implementation of injury prevention interventions.

  15. Toxicity of cadmium to grapevine

    Energy Technology Data Exchange (ETDEWEB)

    Rupp, D.; Ruehl, E.; Alleweldt, G.

    1985-01-01

    Cuttings of the cv. Riesling were cultivated in nutrient solutions with different amounts of cadmium. Cadmium inhibited the growth of shoot and of leaf area and produced chlorosis, necroses and leaf deformations. Old leaves showed no symptoms at all, but with high cadmium levels leaf fall occurred. The threshold of cadmium damage was beneath a level of 0.1 ppm Cd of the nutrient solution. The dry matter production of the plants was reduced by cadmium: 0.66 mg Cd/l of nutrient solution caused an inhibition of 50%. Cadmium reduced the chlorophyll content of the leaves. The transport of iron from roots to leaves was inhibited nearly completely by medium to high levels of cadmium (1.0, 3.0, 10.0 ppm). Iron was accumulated in the roots. Thus cadmium may have caused an iron deficiency chlorosis in grapevines. The uptake of cadmium showed a clear dependence on the amount of cadmium in the nutrient solution. Within the plants, decreasing amounts of cadmium were found following the pattern roots - stem - leaves.

  16. An efficient near infrared spectroscopy based on aquaphotomics technique for rapid determining the level of Cadmium in aqueous solution

    Science.gov (United States)

    Putra, Alfian; Vassileva, Maria; Santo, Ryoko; Tsenkova, Roumina

    2017-06-01

    Cadmium (Cd) is a common industrial pollutant with long biological half-life, which makes it as a cumulative toxicant. Near-infrared spectroscopy has been successfully used for quick and accurate assessment of Cd content in agricultural materials, but the development of a quick detection method for ground and drinking water samples is equal importance for pollution monitoring. Metals have no absorbance in the NIR spectral range, thus the methods developed so far have focused on detection of metal-organic complexes (move to intro). This study focuses on the use of Aquaphotomics technique to measure Cd in aqueous solutions by analyzing the changes in water spectra that occur due to water-metal interaction. Measurements were performed with Cd (II) in 0.1 M HNO3, in the 680-1090 nm (water second and third overtones) and 1110-1800 nm (water first overtone) spectral regions, and were subjected to partial least-square regression analysis. It was found/determined that A concentration of Cd from 1 mg L-1 to 10 mg L-1 could be predicted by this model with average prediction correlation coefficient of 0.897. The model was tested by perturbations with temperature and other metal presence in the solution. The regression coefficient showed consistent peaks at 728, 752, 770, 780, 1362, 1430,1444, 1472/1474 and 1484 nm under various perturbations, indicating that metal to influence the water spectra. The residual predictive deviation values (RPD) were greater than 2, indicating that the model is appropriate for practical use. The result suggested that this newly proposed approach is capable of detecting metal ion in a much simpler, rapid and reliable way.

  17. iTRAQ-based proteomic analysis reveals the mechanisms of silicon-mediated cadmium tolerance in rice (Oryza sativa) cells.

    Science.gov (United States)

    Ma, Jie; Sheng, Huachun; Li, Xiuli; Wang, Lijun

    2016-07-01

    Silicon (Si) can alleviate cadmium (Cd) stress in rice (Oryza sativa) plants, however, the understanding of the molecular mechanisms at the single-cell level remains limited. To address these questions, we investigated suspension cells of rice cultured in the dark environment in the absence and presence of Si with either short- (12 h) or long-term (5 d) Cd treatments using a combination of isobaric tags for relative and absolute quantitation (iTRAQ), fluorescent staining, and inductively coupled plasma mass spectroscopy (ICP-MS). We identified 100 proteins differentially regulated by Si under the short- or long-term Cd stress. 70% of these proteins were down-regulated, suggesting that Si may improve protein use efficiency by maintaining cells in the normal physiological status. Furthermore, we showed two different mechanisms for Si-mediated Cd tolerance. Under the short-term Cd stress, the Si-modified cell walls inhibited the uptake of Cd ions into cells and consequently reduced the expressions of glycosidase, cell surface non-specific lipid-transfer proteins (nsLTPs), and several stress-related proteins. Under the long-term Cd stress, the amount of Cd in the cytoplasm in Si-accumulating (+Si) cells was decreased by compartmentation of Cd into vacuoles, thus leading to a lower expression of glutathione S-transferases (GST). These results provide protein-level insights into the Si-mediated Cd detoxification in rice single cells. Copyright © 2016 Elsevier Masson SAS. All rights reserved.

  18. the crystal structures of two novel cadmium-picolinic acid complexes ...

    African Journals Online (AJOL)

    NICO

    2010-12-07

    hydrogen atoms were first refined isotropically followed by anisotropic refinement by full matrix least- squares calculations based on F2 using SHELX-97.10. All hydrogen atoms were positioned geometrically and allowed to ride ...

  19. Fabrication of a highly selective cadmium (II) sensor based on 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane as a supramolecular ionophore

    Energy Technology Data Exchange (ETDEWEB)

    Ghaemi, Arezoo, E-mail: arezooghaemi@yahoo.com; Tavakkoli, Haman; Mombeni, Tayebeh

    2014-05-01

    A new cadmium (II) ion selective sensor based on 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane (kryptofix5) as a supramolecular carrier has been developed. The membrane solutions containing polyvinyl chloride (PVC), plasticizer, sodium tetraphenylborate (NaTPB) as a lipophilic ionic additive and kryptofix5 as an ionophore were directly coated on the surface of graphite rods. The best composition of the coated membrane (w/w%) was found to be: 30.0% PVC, 61.0% dioctyl sebacate (DOS), 6.0% NaTPB and 3.0% kryptofix5. The sensor indicates a good linear response for Cd{sup 2+} cation over a wide concentration range from 1.0 × 10{sup −5} to 1.0 × 10{sup −1} M with a Nernstian slope of 29.8 ± 0.1 mV/decade and the detection limit is 8.4 × 10{sup −6} M. The response time of the sensor is 15 s and it can be used for 7 weeks without significant drift in potential. The sensor operates in the wide pH range of 1.0–6.0. This sensor reveals a very good selectivity toward Cd{sup 2+} ion over a wide range of alkali, transition and heavy metal cations. The sensor was used as an indicator electrode for potentiometric titration of Cd{sup 2+} using sodium fluoride and ethylenediaminetetraacetic acid (EDTA) solutions with a sharp potential change that occurred at the end point. In addition, the proposed sensor was successfully used for determination of Cd{sup 2+} cation in real water samples. - Graphical abstract: Fabrication of a highly selective cadmium (II) sensor based on 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane as a supramolecular ionophore. - Highlights: • Fabrication of a novel Cd{sup 2+} selective sensor with high sensitivity and selectivity • Using fabricated sensor in a wide pH range with fast response time • Replacing expensive techniques with this low cost sensor with low detection limit • Excellent capability of this sensor for measuring Cd{sup 2+} in real samples.

  20. 29 CFR 1910.1027 - Cadmium.

    Science.gov (United States)

    2010-07-01

    ... battery Plate making, plate preparation 50 All other processes 15 Zinc/Cadmium refining* Cadmium refining... as an airborne concentration of cadmium of 2.5 micrograms per cubic meter of air (2.5 µg/m3... air cadmium level to which an employee is exposed means the exposure to airborne cadmium that would...

  1. Port Authority of Allegheny County Park and Rides

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — This dataset includes the GIS shapefile for Port Authority of Allegheny County's Park and Ride facilities. This layer is updated annually or on an as-needed basis...

  2. NMR-based metabolomic investigations on the differential responses in adductor muscles from two pedigrees of Manila clam Ruditapes philippinarum to Cadmium and Zinc.

    Science.gov (United States)

    Wu, Huifeng; Liu, Xiaoli; Zhao, Jianmin; Yu, Junbao

    2011-01-01

    Manila clam Ruditapes philippinarum is one of the most important economic species in shellfishery in China due to its wide geographic distribution and high tolerance to environmental changes (e.g., salinity, temperature). In addition, Manila clam is a good biomonitor/bioindicator in "Mussel Watch Programs" and marine environmental toxicology. However, there are several pedigrees of R. philippinarum distributed in the marine environment in China. No attention has been paid to the biological differences between various pedigrees of Manila clams, which may introduce undesirable biological variation in toxicology studies. In this study, we applied NMR-based metabolomics to detect the biological differences in two main pedigrees (White and Zebra) of R. philippinarum and their differential responses to heavy metal exposures (Cadmium and Zinc) using adductor muscle as a target tissue to define one sensitive pedigree of R. philippinarum as biomonitor for heavy metals. Our results indicated that there were significant metabolic differences in adductor muscle tissues between White and Zebra clams, including higher levels of alanine, glutamine, hypotaurine, phosphocholine and homarine in White clam muscles and higher levels of branched chain amino acids (valine, leucine and isoleucine), succinate and 4-aminobutyrate in Zebra clam muscles, respectively. Differential metabolic responses to heavy metals between White and Zebra clams were also found. Overall, we concluded that White pedigree of clam could be a preferable bioindicator/biomonitor in marine toxicology studies and for marine heavy metals based on the relatively high sensitivity to heavy metals.

  3. NMR-Based Metabolomic Investigations on the Differential Responses in Adductor Muscles from Two Pedigrees of Manila Clam Ruditapes philippinarum to Cadmium and Zinc

    Science.gov (United States)

    Wu, Huifeng; Liu, Xiaoli; Zhao, Jianmin; Yu, Junbao

    2011-01-01

    Manila clam Ruditapes philippinarum is one of the most important economic species in shellfishery in China due to its wide geographic distribution and high tolerance to environmental changes (e.g., salinity, temperature). In addition, Manila clam is a good biomonitor/bioindicator in “Mussel Watch Programs” and marine environmental toxicology. However, there are several pedigrees of R. philippinarum distributed in the marine environment in China. No attention has been paid to the biological differences between various pedigrees of Manila clams, which may introduce undesirable biological variation in toxicology studies. In this study, we applied NMR-based metabolomics to detect the biological differences in two main pedigrees (White and Zebra) of R. philippinarum and their differential responses to heavy metal exposures (Cadmium and Zinc) using adductor muscle as a target tissue to define one sensitive pedigree of R. philippinarum as biomonitor for heavy metals. Our results indicated that there were significant metabolic differences in adductor muscle tissues between White and Zebra clams, including higher levels of alanine, glutamine, hypotaurine, phosphocholine and homarine in White clam muscles and higher levels of branched chain amino acids (valine, leucine and isoleucine), succinate and 4-aminobutyrate in Zebra clam muscles, respectively. Differential metabolic responses to heavy metals between White and Zebra clams were also found. Overall, we concluded that White pedigree of clam could be a preferable bioindicator/biomonitor in marine toxicology studies and for marine heavy metals based on the relatively high sensitivity to heavy metals. PMID:22131959

  4. Sexual dimorphism of cadmium-induced toxicity in rats: involvement of sex hormones.

    Science.gov (United States)

    Shimada, Hideaki; Hashiguchi, Takashi; Yasutake, Akira; Waalkes, Michael P; Imamura, Yorishige

    2012-09-01

    The toxic effect of cadmium varies with sex in experimental animals. Previous studies have demonstrated that pretreatment of male Fischer 344 (F344) rats with the female sex hormone progesterone markedly enhances the susceptibility to cadmium, suggesting a role for progesterone in the sexual dimorphism of cadmium toxicity. In the present study, we attempted to further elucidate the mechanism for sex differences in cadmium-induced toxicity in F344 rats. A single exposure to cadmium (5.0 mg Cd/kg, sc) was lethal in 10/10 (100 %) female compared with 6/10 (60 %) male rats. Using a lower dose of cadmium (3.0 mg Cd/kg), circulating alanine aminotransferase activity, indicative of hepatotoxicity, was highly elevated in the cadmium treated females but not in males. However, no gender-based differences occurred in the hepatic cadmium accumulation, metallothionein or glutathione levels. When cadmium (5.0 mg Cd/kg) was administered to young rats at 5 weeks of age, the sex-related difference in lethality was minimal. Furthermore, although ovariectomy blocked cadmium-induced lethality, the lethal effects of the metal were restored by pretreatment with progesterone (40 mg/kg, sc, 7 consecutive days) or β-estradiol (200 μg/kg, sc, 7 consecutive days) to ovariectomized rats. These results provide further evidence that female sex hormones such as progesterone and β-estradiol are involved in the sexual dimorphism of cadmium toxicity in rats.

  5. Stability of a Light Sail Riding on a Laser Beam

    OpenAIRE

    Manchester, Zachary; Loeb, Abraham

    2016-01-01

    The stability of a light sail riding on a laser beam is analyzed both analytically and numerically. Conical sails on Gaussian beams, which have been studied in the past, are shown to be unstable without active control or additional mechanical modifications. A new architecture for a passively stable sail and beam configuration is proposed. The novel spherical shell design for the sail is capable of "beam riding" without the need for active feedback control. Full three-dimensional ray-tracing s...

  6. Mechatronics, design, and modeling of a motorcycle riding simulator

    OpenAIRE

    ARIOUI, H; NEHAOUA, L; Hima, S; SEGUY, N; ESPIE, S

    2010-01-01

    International audience; This paper describes a new motorcycle riding simulator whose purpose is twofold: (1) it can be used as a training tool for new riders in different scenarios, such as a normal traffic environments or in dangerous riding situations (avoidance, emergency braking, nearly failing or slipping situations and bad weather conditions); and (2) it can be used to study cyclist behavior in such situations and rider-motorcycle interaction. Our studies have led to the development of ...

  7. Privately owned autonomous vehicles in a ride-sharing application

    OpenAIRE

    MOURAD, Abood; Puchinger, Jakob; Chu, Chengbin

    2017-01-01

    National audience; In this paper, we consider the planning of privately owned autonomous vehicles’ trips in a ride-sharing application. Emerging challenges, such as the finite oil supplies, rising gas prices and traffic congestion, going in hand with the environmental concerns have increased the interest in ride-sharing applications that can bring together travelers with similar time schedules [1]. Those arising challenges justify the need of new transport innovations, like autonomous (most l...

  8. Feasibility Testing for Dial-a-Ride Problems

    Science.gov (United States)

    Haugland, Dag; Ho, Sin C.

    Hunsaker and Savelsbergh have proposed an algorithm for testing feasibility of a route in the solution to the dial-a-ride problem. The constraints that are checked are load capacity constraints, time windows, ride time bounds and wait time bounds. The algorithm has linear running time. By virtue of a simple example, we show in this work that their algorithm is incorrect. We also prove that by increasing the time complexity by only a logarithmic factor, a correct algorithm is obtained.

  9. Vehicle Ride Height Change Due To Radial Expansion Of Tires

    Directory of Open Access Journals (Sweden)

    Čavoj Ondřej

    2015-11-01

    Full Text Available In general, tire deformations caused by wheel rotation are not taken into account when developing vehicle aerodynamics. On the road the tires radially expand as speed increases, which affects the actual ride height of a vehicle. In turn this often increases the real aerodynamic drag compared to values obtained using CFD or a wind tunnel as the mass flow across the relatively rough underbody increases with ground clearance. In this study, on-road ride heights were measured while running a vehicle in a straight line with fixed velocity whilst the aerodynamic lift of the vehicle was determined in a wind tunnel. Subsequently, the relationships between ride height and axle load were obtained by loading the vehicle at standstill with ballast. By comparing the ride heights at high and very low velocities with expected vertical displacement caused purely by aerodynamic lift force as computed according to the ride height - axle load equations, the ride height change due to tire radial expansion was determined.

  10. Fast Coordinated Control of DFIG Wind Turbine Generators for Low and High Voltage Ride-Through

    DEFF Research Database (Denmark)

    Wang, Yun; Wu, Qiuwei; Xu, Honghua

    2014-01-01

    (HVRT) capability of the DFIG WTGs. The characteristics of DFIG WTGs under voltage sags and swells were studied focusing on the DFIG WTG stator flux and rotor voltages during the transient periods of grid voltage changes. The protection schemes of the rotor crowbar circuit and the dc chopper circuit......This paper presents a fast coordinated control scheme of the rotor side converter (RSC), the DC chopper and the grid side converter (GSC) of doubly fed induction generator (DFIG) wind turbine generators (WTGs) which is to improve the low voltage ride through (LVRT) and high voltage ride through...... were proposed considering the characteristics of the DFIG WTGs during voltage changes. The fast coordinated control of RSC and GSC were developed based on the characteristic analysis in order to realize efficient LVRT and HVRT of the DFIG WTGs. The proposed fast coordinated control schemes were...

  11. Fast Coordinated Control of DFIG Wind Turbine Generators for Low and High Voltage Ride-Through

    Directory of Open Access Journals (Sweden)

    Yun Wang

    2014-06-01

    Full Text Available This paper presents a fast coordinated control scheme of the rotor side converter (RSC, the Direct Current (DC chopper and the grid side converter (GSC of doubly fed induction generator (DFIG wind turbine generators (WTGs to improve the low voltage ride through (LVRT and high voltage ride through (HVRT capability of the DFIG WTGs. The characteristics of DFIG WTGs under voltage sags and swells were studied focusing on the DFIG WTG stator flux and rotor voltages during the transient periods of grid voltage changes. The protection schemes of the rotor crowbar circuit and the DC chopper circuit were proposed considering the characteristics of the DFIG WTGs during voltage changes. The fast coordinated control of RSC and GSC were developed based on the characteristic analysis in order to realize efficient LVRT and HVRT of the DFIG WTGs. The proposed fast coordinated control schemes were verified by time domain simulations using Matlab-Simulink.

  12. Microwave assisted synthesis, characterization and biocidal activities of some new chelates of carbazole derived Schiff bases of cadmium and tin metals

    Science.gov (United States)

    Yadav, Manju; Mishra, Neelima; Sharma, Nutan; Chandra, Sulekh; Kumar, Dinesh

    2014-11-01

    This study is planned to report the advancement of green microwave approach in the fabrication of a new series of biologically potent (N^X, where X = O/S) donor Schiff bases and their cadmium(II) and tin(II) complexes. The ligands and their metal complexes have been characterized in terms of elemental analysis, molar ionic conductance, magnetic moment and spectral (IR, UV-Vis, NMR (1H, 119Sn), FAB-mass, thermal and XRD) data. The data revealed that the ligands coordinated to the metal center via nitrogen and oxygen/sulfur atoms and form an octahedral arrangement of the ligands around central metal atom. All compounds were evaluated for their in vitro antimicrobial activities against two pathogenic bacteria Bacillus subtilis and Escherichia coli and two fungi Aspergillus niger and Aspergillus flavus by standard disc diffusion method. The discs were stored in an incubator at 37 °C. The compounds were dissolved in DMF at 500 and 1000 ppm concentrations for screening biocidal activity. The compounds were dissolved in DMF to get the 100 and 200 ppm concentration of test solutions for screening fungicidal activity. The inhibition zone around each disc was measured (in mm) after 24 h and 96 h for biocidal and fungicidal activities respectively.

  13. Accumulation and distribution of arsenic and cadmium by tea plants*

    Science.gov (United States)

    Shi, Yuan-zhi; Ruan, Jian-yun; Ma, Li-feng; Han, Wen-yan; Wang, Fang

    2008-01-01

    It is important to research the rules about accumulation and distribution of arsenic and cadmium by tea plants, which will give us some scientific ideas about how to control the contents of arsenic and cadmium in tea. In this study, by field investigation and pot trial, we found that mobility of arsenic and cadmium in tea plants was low. Most arsenic and cadmium absorbed were fixed in feeding roots and only small amount was transported to the above-ground parts. Distribution of arsenic and cadmium, based on their concentrations of unit dry matter, in tea plants grown on un-contaminated soil was in the order: feeding roots>stems≈main roots>old leaves>young leaves. When tea plants were grown on polluted soils simulated by adding salts of these two metals, feeding roots possibly acted as a buffer and defense, and arsenic and cadmium were transported less to the above-ground parts. The concentration of cadmium in soil significantly and negatively correlated with chlorophyll content, photosynthetic rate, transpiration rate and biomass production of tea plants. PMID:18357630

  14. Annoyance rate evaluation method on ride comfort of vehicle suspension system

    Science.gov (United States)

    Tang, Chuanyin; Zhang, Yimin; Zhao, Guangyao; Ma, Yan

    2014-03-01

    The existing researches of the evaluation method of ride comfort of vehicle mainly focus on the level of human feelings to vibration. The level of human feelings to vibration is influenced by many factors, however, the ride comfort according to the common principle of probability and statistics and simple binary logic is unable to reflect these uncertainties. The random fuzzy evaluation model from people subjective response to vibration is adopted in the paper, these uncertainties are analyzed from the angle of psychological physics. Discussing the traditional evaluation of ride comfort during vehicle vibration, a fuzzily random evaluation model on the basis of annoyance rate is proposed for the human body's subjective response to vibration, with relevant fuzzy membership function and probability distribution given. A half-car four degrees of freedom suspension vibration model is described, subject to irregular excitations from the road surface, with the aid of software Matlab/Simulink. A new kind of evaluation method for ride comfort of vehicles is proposed in the paper, i.e., the annoyance rate evaluation method. The genetic algorithm and neural network control theory are used to control the system. Simulation results are obtained, such as the comparison of comfort reaction to vibration environments between before and after control, relationship of annoyance rate to vibration frequency and weighted acceleration, based on ISO 2631/1(1982), ISO 2631-1(1997) and annoyance rate evaluation method, respectively. Simulated assessment results indicate that the proposed active suspension systems prove to be effective in the vibration isolation of the suspension system, and the subjective response of human being can be promoted from very uncomfortable to a little uncomfortable. Furthermore, the novel evaluation method based on annoyance rate can further estimate quantitatively the number of passengers who feel discomfort due to vibration. A new analysis method of vehicle

  15. Cadmium hazard in silver brazing.

    Science.gov (United States)

    Gan, S L; Tan, S H; Pinnagoda, J; Tan, K T

    1995-03-01

    This study evaluates the usage of cadmium-containing silver brazing alloys in Singapore and the potential cadmium hazard from its use. Of the 137 factories which responded to the survey questionnaire, only 28 (20.4%) carried out brazing. Of these, only 7 factories used cadmium-containing filler alloys. One hundred and six out of 123 workers from one of these factories had cadmium-in-blood concentrations exceeding 10 mcg/l. Thirty-one (29.2%) of the workers with excessive cadmium absorption had urinary beta-2 microglobulin levels exceeding 28 mcg/g creat. Workers in the other factories who were intermittently exposed had cadmium-in-blood concentrations of 10 mcg/l and below.

  16. Self-assembly of luminescent alkynyl-based platinum-cadmium complexes containing auxiliary diimine or terpyridine ligands.

    Science.gov (United States)

    Berenguer, Jesús R; Gil, Belén; Fernández, Julio; Forniés, Juan; Lalinde, Elena

    2009-06-15

    Reaction of different "Cd(N-N)(2)(2+)" (N-N = bpy, dmbpy, phen) or "Cd(trpy)(2+)" fragments with cis- or trans- (5) dianionic bis(alkynyl)platinate substrates [Pt(C(6)F(5))(2)(C[triple bond]CR)(2)](2-) (R = Ph a, Tol b) leads to the generation of novel bimetallic neutral Platinum-Cadmium derivatives, which show photoluminescence (PL) strongly influenced by the structure and the media. In complexes [cis-Pt(C(6)F(5))(2)(C[triple bond]CR)(2)Cd(N-N)(2)] (N-N = bpy (1), dmbpy (2), phen (3)), the dianionic cis-bis(alkynyl)platinate fragment interacts with the "Cd(N-N)(2)(+2)" unit mainly through both the C(alpha) atoms (d(Cd-C(alpha)) = 2.417(5)-2.554(5) A) and the Pt center (d(Pt-Cd) approximately 3.10 A); while in complexes [cis-Pt(C(6)F(5))(2)(C[triple bond]CR)(2)Cd(trpy)] (4), probably because of the presence of only three Cd-N bonds, the Pt-Cd interaction is enhanced (d(Pt-Cd) approximately 3.00 A), the Cd(II) atom being additionally solvated with acetone or H(2)O. By contrast, in complexes [trans-Pt(C(6)F(5))(2)(C[triple bond]CR)(2)Cd(bpy)(2)] (6) the Cd center is found to be in a distorted trigonal-bipyramid coordination, interacting with one of the Pt-C(alpha) bonds of the platina-bis(alkynyl) unit with very short Cd-C(alpha) (2.376(10) A) and Pt-Cd (2.8931(6) A) bond distances. Bimetallic complexes 1-4, having cis-configured platinum fragments, exhibit, in solid state, blue and/or green phosphorescence with contribution of close emissive states of different natures: metal (Pt, Cd) perturbed pi pi* intraligand (alkynyl, polyimine) manifolds mixed, to a greater (trpy complexes 4) or lesser extent, with (Pt-Cd) charge transfer (MM'CT). In glassy state (2-MeTHF, 77 K), complexes 1b-4b exhibit structured emissions mainly ascribed to (diimine 1b-3b, trpy 4b) (3)pi pi phosphorescence, likely mixed with some ligand (alkyne) to ligand (imine) charge transfer ((3)LL'CT). Complexes 6 are not emissive in solid state at room temperature. At 77 K they display a high energy (3

  17. Cadmium in Sweden - environmental risks

    Energy Technology Data Exchange (ETDEWEB)

    Parkman, H.; Iverfeldt, Aa. [Swedish Environmental Research Inst. (Sweden); Borg, H.; Lithner, G. [Stockholm Univ. (Sweden). Inst. for Applied Environmental Research

    1998-03-01

    This report aims at assessing possible effects of cadmium in the Swedish environment. Swedish soils and soft freshwater systems are, due to a generally poor buffering capacity, severely affected by acidification. In addition, the low salinity in the Baltic Sea imply a naturally poor organism structure, with some important organisms living close to their limit of physiological tolerance. Cadmium in soils is mobilized at low pH, and the availability and toxicity of cadmium in marine systems are enhanced at low salinity. The Swedish environment is therefore extra vulnerable to cadmium pollution. The average concentrations of cadmium in the forest mor layers, agricultural soils, and fresh-waters in Sweden are enhanced compared to `back-ground concentrations`, with a general increasing trend from the north to the south-west, indicating strong impact of atmospheric deposition of cadmium originating from the central parts of Europe. In Swedish sea water, total cadmium concentrations, and the fraction of bio-available `free` cadmium, generally increases with decreasing salinity. Decreased emissions of cadmium to the environment have led to decreasing atmospheric deposition during the last decade. The net accumulation of cadmium in the forest mor layer has stopped, and even started to decrease. In northern Sweden, this is due to the decreased deposition, but in southern Sweden the main reason is increased leakage of cadmium from the topsoil as a consequence of acidification. As a result, cadmium in the Swedish environments is undergoing an extended redistribution between different soil compartments, and from the soils to the aquatic systems. 90 refs, 23 figs, 2 tabs. With 3 page summary in Swedish

  18. Cooperative control of VSC-HVDC connected offshore wind farm with Low-Voltage Ride-Through capability

    DEFF Research Database (Denmark)

    Liu, Yan; Wang, Xiongfei; Chen, Zhe

    2012-01-01

    The Low-Voltage Ride-Through (LVRT) has become an important grid requirement for offshore wind farms connecting with Voltage Source Converter based High Voltage Direct Current (VSC-HVDC) links. In this paper, a cooperative control strategy with LVRT ability is proposed for a VSC-HVDC connected...

  19. Speciation of Dissolved Cadmium

    DEFF Research Database (Denmark)

    Holm, Peter Engelund; Andersen, Sjur; Christensen, Thomas Højlund

    1995-01-01

    Equilibrium dialysis and ion exchange methods, as well as computer calculations (GEOCHEM), were applied for speciation of dissolved cadmium (Cd) in test solutions and leachate samples. The leachate samples originated from soil, compost, landfill waste and industrial waste. The ion exchange (IE...... leachates showed different Cd speciation patterns as expected. Some leachates were dominated by free divalent Cd (1-70%), some by inorganic complexes (1-87%), and some by organic complexes (7-98%)....

  20. Directional and sectional ride comfort estimation using an integrated human biomechanical-seat foam model

    Science.gov (United States)

    Mohajer, Navid; Abdi, Hamid; Nahavandi, Saeid; Nelson, Kyle

    2017-09-01

    In the methodology of objective measurement of ride comfort, application of a Human Biomechanical Model (HBM) is valuable for Whole Body Vibration (WBV) analysis. In this study, using a computational Multibody System (MBS) approach, development of a 3D passive HBM for a seated human is considered. For this purpose, the existing MBS-based HBMs of seated human are briefly reviewed first. The Equations of Motion (EoM) for the proposed model are then obtained and the simulation results are shown and compared with idealised ranges of experimental results suggested in the literature. The human-seat interaction is established using a nonlinear vibration model of foam with respect to the sectional behaviour of the seat foam. The developed system is then used for ride comfort estimation offered by a ride dynamic model. The effects of human weight, road class, and vehicle speed on the vibration of the human body segments in different directions are studied. It is shown that the there is a high correlation (more than 99.2%) between the vibration indices of the proposed HBM-foam model and the corresponding ISO 2631 WBV indices. In addition, relevant ISO 2631 indices that show a high correlation with the directional vibration of the head are identified.

  1. The workload of riding-school horses during jumping.

    Science.gov (United States)

    Sloet van Oldruitenborgh-Oosterbaan, M M; Spierenburg, A J; van den Broek, E T W

    2006-08-01

    As there are no reports on the real workload of horses that jump fences, this study was undertaken in riding-school horses. To compare the workload of horses jumping a course of fences with that of horses cantering over the same course at the same average speed without jumping fences. The workload variables included heart rate (HR), packed cell volume (PCV), acid-base balance (venous pH, pCO2, HCO3-) and blood lactate (LA), glucose, total protein and electrolyte concentrations. Eight healthy riding-school horses performed test A (a course of approximately 700 m with 12 jumps from 0.8-1.0 m high at an average speed of approximately 350 m/min) and test B (same course at the same speed, but without the rails) in a crossover study with at least 4 h between the 2 tests. Before each test the horses were fitted with a heart rate meter (Polar Electro). Blood samples were taken from the jugular vein at rest prior to the test, after warm-up before starting the course, immediately after the course and after recovery. All samples were analysed immediately. The mean +/- s.d maximal HR (beats/min) during the course (184 +/- 17 and 156 +/- 21, respectively) and the mean HR after recovery (75 +/- 6 and 63 +/- 7, respectively) were significantly higher in test A compared to test B (P = 0.001 and P = 0.007 respectively). The mean LA concentrations after the course and after recovery (mmol/l) were significantly higher in test A (3.6 +/- 2.7 and 1.0 +/- 0.9, respectively) compared to test B (0.9 +/- 0.5 and 0.3 +/- 0.1, respectively), (P = 0.016 and P = 0.048 respectively). The mean PCV (I/l) after the course and after recovery was also significantly different between tests A (0.48 +/- 0.04 and 0.39 +/- 0.03, respectively) and B (0.42 +/- 0.04 and 0.36 +/- 0.03, respectively) (PPspeed without fences. This study makes it clear that the extra workload of jumping fences should be taken into account in the training programmes of jumping horses. Further research with more experienced

  2. Sonochemical synthesis and DFT studies of nano novel Schiff base cadmium complexes: Green, efficient, recyclable catalysts and precursors of Cd NPs

    Science.gov (United States)

    Parsaee, Zohreh

    2017-10-01

    Novel asymmetric (N4) Schiff bases (Ln, n = 1-3) and their nanosized cadmium complexes derived of 4,4'-(pentylazanediyl) dibenzaldehyde and aminobenzaldehyde are synthesized by sonochemical method and characterized based on physicochemical analysis including 1H NMR, 13C NMR, SEM, TGA, Mass, FT-IR, UV-Vis spectroscopy, elemental analysis, magnetic moment and molar conductance measurements. According to the analytic results of the NMR, UV-Vis and magnetic moment studies, it is found that the geometrical structures of these complexes [CdII2LnCl4], (L = C45H40N5X, X = CH3, Cl, OH) are square planer. The synthesized complexes were so effective as nanocatalyst on the oxidation of primary and secondary alcohols. The oxidation reactions were carried out in ethyl-methyl-imidazolium ionic liquid in presence of NaOCl. In addition Cd NPs were synthesized through the thermal decomposition of mentioned complexes and characterized by using FT-IR, SEM, TEM, EDX and XRD methods, which indicated close accordance to the standard pattern of CdO nanoparticles and an acceptable size at the nanorange (22-27 nm). Furthermore geometrical optimization of the Cd2LnCl4 calculated using DFT/B3LYP with LanL2DZ/6-311+G (d,p) level. The electronic parameter including HOMO-LUMO orbitals, bond gap, chemical hardness-softness, electronegativity, electrophilicity, NMR chemical shifts and IR frequencies were calculated. The calculated NMR shifts and vibrational frequencies showed excellent agreement with experimental data.

  3. PERANCANGAN PURWARUPA KOMIK INTERAKTIF SAFETY RIDING BERKONSEP DIGITAL STORYTELLING

    Directory of Open Access Journals (Sweden)

    Godham Eko Saputro

    2016-12-01

    Full Text Available Abstrak Di Indonesia khususnya kota besar, kecelakaan yang disebabkan kendaraan bermotor menjadi persoalan yang serius. Salah satunya disebabkan kurangnya pemahaman tentang safety riding. Berbagai upaya kampanye safety riding pun telah dilaksanakan oleh polisi lalu lintas melalui talkshow, siaran radio, serta media leaflet bagi masyarakat yang dilakukan berulang-ulang. Hal itu mendorong peneliti dalam upaya menemukan strategi baru, salah satunya memanfaatkan perkembangan teknologi yang sangat pesat guna mengembangkan media pendukung kampanye safety riding yang tidak hanya dapat menyampaikan pesan, tetapi juga disukai dan bersifat menghibur. Data diperoleh melalui wawancara, observasi, serta studi literatur sebagai sumber konten purwarupa komik interaktif. Melalui pendekatan digital storytelling dan model komunikasi SMCR serta mengacu pada Penelitian Pengembangan, konsep purwarupa komik interaktif bisa dijabarkan lebih detail serta dapat diimplementasikan dalam perangkat mobile khususnya tablet PC. Diharapkan purwarupa ini dapat dikembangkan lebih lanjut sehingga benar-benar dapat dipublish secara umum sebagai media pendukung kampanye safety riding. Kata Kunci: komik, interaktif, safety riding, digital storytelling Abstract In Indonesia especially in big cities, the accident which caused by rider is still become serious issue. One factor which cause accident is the lack of knowledge about safety riding. A lot of efforts which have been carried by traffic policeman are talkshow, radio broadcast, and leaflet media for public society. On the other hand, it courage the researchers in effort to find new startegy, one of them is using the advance of technology to develop another media campaign which not only can deliver the messages, but also can entertain user. This research is an effort to find unconventional media for safety riding campaign. Data was obtained through interview, observation, and study of literature as sources of content for

  4. Isolation, Identification, and Characterization of Cadmium Resistant Pseudomonas sp. M3 from Industrial Wastewater

    Directory of Open Access Journals (Sweden)

    Syed Zaghum Abbas

    2014-01-01

    Full Text Available The present study deals with the isolation, identification, and characterization of the cadmium resistant bacteria from wastewater collected from industrial area of Penang, Malaysia. The isolate was selected based on high level of the cadmium and antibiotic resistances. On the basis of morphological, biochemical characteristics, 16S rDNA gene sequencing and phylogeny analysis revealed that the strain RZCd1 was authentically identified as Pseudomonas sp. M3. The industrial isolate showed more than 70% of the cadmium removal in log phase. The cadmium removal capacity of strain RZCd1 was affected by temperature and pH. At pH 7.0 and 35°C, strain RZCd1 showed maximum cadmium removal capacity. The minimal inhibitory concentration of strain RZCd1 against the cadmium was 550 µg/mL. The resistance against the cadmium was associated with resistance to multiple antibiotics: amoxicillin, penicillin, cephalexin, erythromycin, and streptomycin. The strain RZCd1 also gave thick bands of proteins in front of 25 kDa in cadmium stress condition after 3 h of incubation. So the identified cadmium resistant bacteria may be useful for the bioremediation of cadmium contaminated industrial wastewater.

  5. A far-infrared broadband (8.5-37 mu m) autocorrelator with sub-picosecond time resolution based on cadmium telluride

    NARCIS (Netherlands)

    Xu, J.; Knippels, G.M.H.; Oepts, D.; van der Meer, A. F. G.

    2001-01-01

    A background-free autocorrelator has been developed for measuring the duration of far-infrared laser pulses in the spectral range from 8.5 to 37 mum by using an 840-mum-long wedged cadmium telluride crystal as the second-harmonic generator. Typical intensity second-harmonic autocorrelation traces

  6. Dietary exposure to cadmium and health effects: impact of environmental changes.

    OpenAIRE

    Piscator, M

    1985-01-01

    Cadmium exposure, metabolism, and effects are described especially in relation to dietary intakes. Data on dietary intakes in several countries have been complied from studies using the duplicate diet method or fecal analysis. These two methods seem to give more accurate data than estimates based on cadmium concentrations in food classes and food consumption (composite method). The present data on absorption and retention of ingested cadmium indicate that normally less than 5% is ingested, bu...

  7. Cadmium in blood and hypertension

    Energy Technology Data Exchange (ETDEWEB)

    Eum, Ki-Do; Lee, Mi-Sun [Department of Environmental Health, Graduate School of Public Health and Institute of Health and Environment, Seoul National University, Seoul (Korea, Republic of); Paek, Domyung [Department of Environmental Health, Graduate School of Public Health and Institute of Health and Environment, Seoul National University, Seoul (Korea, Republic of)], E-mail: paekdm@snu.ac.kr

    2008-12-15

    Objectives:: This study is to examine the effect of cadmium exposure on blood pressure in Korean general population. Methods:: The study population consisted of 958 men and 944 women who participated in the 2005 Korean National Health and Nutrition Examination Survey (KNHANES), in which blood pressure and blood cadmium were measured from each participant. Results:: The mean blood cadmium level was 1.67 {mu}g/L (median level 1.55). The prevalence of hypertension was 26.2%. The blood cadmium level was significantly higher among those subjects with hypertension than those without (mean level 1.77 versus 1.64 {mu}g/dL). After adjusting for covariates, the odds ratio of hypertension comparing the highest to the lowest tertile of cadmium in blood was 1.51 (95% confidence interval 1.13 to 2.05), and a dose-response relationship was observed. Systolic, diastolic, and mean arterial blood pressure were all positively associated with blood cadmium level, and this effect of cadmium on blood pressure was markedly stronger when the kidney function was reduced. Conclusions:: Cadmium exposures at the current level may have increased the blood pressure of Korean general population.

  8. Diagnostic accuracy of cadmium-zinc-telluride-based myocardial perfusion SPECT: impact of attenuation correction using a co-registered external computed tomography.

    Science.gov (United States)

    Caobelli, Federico; Akin, Muharrem; Thackeray, James T; Brunkhorst, Thomas; Widder, Julian; Berding, Georg; Burchert, Ina; Bauersachs, Johann; Bengel, Frank M

    2016-09-01

    Computed tomography (CT)-based attenuation correction (AC) improves the accuracy of standard myocardial perfusion SPECT. Most dedicated cadmium-zinc-telluride (CZT) SPECT cameras are not equipped with an integrated CT component. We aimed to determine the impact of AC on diagnostic performance of CZT SPECT using co-registration with an external low-dose CT. Sixty patients underwent CZT SPECT (GE Discovery 530c) with (99m)Tc-sestamibi at rest and following regadenoson stress. Using commercial software, SPECT images were co-registered with a low-dose CT acquired on a separate system (GE Discovery 670NMCT). Attenuation corrected and non-corrected (NC) images were reconstructed using an iterative algorithm. Accuracy was measured in 44 patients who had undergone invasive angiography within 6 months. Normalcy was compared in the remaining 16 patients who had a low pre-test likelihood (<5%) of coronary artery disease (CAD). Summed stress and rest scores were significantly lower in AC images (9 ± 8 vs. 13 ± 9 and 6 ± 7 vs. 10 ± 9, P = 0.01), while summed difference score did not differ. According to angiography, 38 patients had significant CAD in 71 vascular territories. Attenuation correction improved accuracy globally (P = 0.03) and in RCA territory (P = 0.008). Specificity improved both globally (100 vs. 40%, P < 0.05) and in each individual territory (LAD: 63 vs. 36%, LCX: 70 vs. 33%, RCA: 81 vs. 19%, P < 0.01). Normalcy was 100% for AC and 62.5% for NC images (P < 0.05). Attenuation correction with a co-registered external CT is feasible using CZT cameras and improves diagnostic accuracy mostly by improving specificity over uncorrected images. Published on behalf of the European Society of Cardiology. All rights reserved. © The Author 2015. For permissions please email: journals.permissions@oup.com.

  9. Applying riding-posture optimization on bicycle frame design.

    Science.gov (United States)

    Hsiao, Shih-Wen; Chen, Rong-Qi; Leng, Wan-Lee

    2015-11-01

    Customization design is a trend for developing a bicycle in recent years. Thus, the comfort of riding a bike is an important factor that should be paid much attention to while developing a bicycle. From the viewpoint of ergonomics, the concept of "fitting object to the human body" is designed into the bicycle frame in this study. Firstly, the important feature points of riding posture were automatically detected by the image processing method. In the measurement process, the best riding posture was identified experimentally, thus the positions of feature points and joint angles of human body were obtained. Afterwards, according to the measurement data, three key points: the handlebar, the saddle and the crank center, were identified and applied to the frame design of various bicycle types. Lastly, this study further proposed a frame size table for common bicycle types, which is helpful for the designer to design a bicycle. Copyright © 2015 Elsevier Ltd and The Ergonomics Society. All rights reserved.

  10. Cadmium exposure in the Swedish environment

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This report gives a thorough description of cadmium in the Swedish environment. It comprises three parts: Cadmium in Sweden - environmental risks;, Cadmium in goods - contribution to environmental exposure;, and Cadmium in fertilizers, soil, crops and foods - the Swedish situation. Separate abstracts have been prepared for all three parts

  11. Improvement of Ride Quality of Railway Vehicle by Semiactive Secondary Suspension System on Roller Rig Using Magnetorheological Damper

    Directory of Open Access Journals (Sweden)

    Yu-Jeong Shin

    2014-07-01

    Full Text Available Ride quality became a very important factor in the performance of railway vehicles according to the expansion of high-speed railways and speedup of velocity of railway vehicles. In this study, the results of applying the MR (magnetorheological lateral damper on the secondary suspension to reduce the vibration of the car body, directly relating to the ride quality of railway vehicles, were mentioned. In order to verify the control performance of MR dampers, a 1/5 scaled railway vehicle model was constructed, and numerical simulation and experimental tests were conducted. The MR damper for the experimental tests was produced and was attached between the car body and bogie of a full scaled vehicle, and a vibration controlling test was performed to improve ride quality on a roller rig. The skyhook control algorithm was used as the controlling technique, and regarding the test results, the RMS (root mean square value was found by compensating the frequency of the lateral vibration based on the UIC 513 R Standard about the ride quality of railway vehicles. As a result of the test, it could be confirmed that vibration was reduced by approximately 24% when attaching the MR damper between the bogie and the car body compared to when applying a passive damper.

  12. Oral cadmium chloride intoxication in mice

    DEFF Research Database (Denmark)

    Andersen, O; Nielsen, J B; Svendsen, P

    1988-01-01

    Diethyldithiocarbamate (DDC) is known to alleviate acute toxicity due to injection of cadmium salts. However, when cadmium chloride was administered by the oral route, DDC enhanced rather than alleviated the acute toxicity; both oral and intraperitoneal (i.p.) administration of DDC had this effect....... Thus, orally administered DDC enhanced cadmium-induced duodenal and ileal tissue damage and inhibition of peristalsis, as indicated by an increased intestinal transit time. At low cadmium doses, the whole-body retention of cadmium was increased by oral DDC administration. Intraperitoneally administered...... DDC increased cadmium-induced acute mortality and testicular necrosis, and it enhanced cadmium-induced reduction of intestinal motility and increased the whole-body retention of cadmium, indicating increased intestinal cadmium absorption. Also, DDC changed the organ distribution of absorbed cadmium...

  13. Cadmium-induced oxidative stress and histological damage in the myocardium. Effects of a soy-based diet

    Energy Technology Data Exchange (ETDEWEB)

    Ferramola, Mariana L.; Pérez Díaz, Matías F.F. [Department of Biochemistry and Biological Sciences, Faculty of Chemistry, Biochemistry and Pharmacy, National University of San Luis, IMIBIO-SL, CONICET, San Luis (Argentina); Honoré, Stella M.; Sánchez, Sara S. [Department of Development Biology, INSIBIO, National University of Tucumán, CONICET-UNT, Tucumán (Argentina); Antón, Rosa I. [Department of Chemistry, Faculty of Chemistry, Biochemistry and Pharmacy, National University of San Luis, INQUISAL, CONICET, San Luis (Argentina); Anzulovich, Ana C. [Department of Biochemistry and Biological Sciences, Faculty of Chemistry, Biochemistry and Pharmacy, National University of San Luis, IMIBIO-SL, CONICET, San Luis (Argentina); Giménez, María S., E-mail: mgimenez@unsl.edu.ar [Department of Biochemistry and Biological Sciences, Faculty of Chemistry, Biochemistry and Pharmacy, National University of San Luis, IMIBIO-SL, CONICET, San Luis (Argentina)

    2012-12-15

    Cd exposure has been associated to an augmented risk for cardiovascular disease. We investigated the effects of 15 and 100 ppm of Cd on redox status as well as histological changes in the rat heart and the putative protective effect of a soy-based diet. Male Wistar rats were separated into 6 groups and treated during 60 days as follows: groups (1), (2) and (3) were fed a casein-based diet; groups (4), (5) and (6), a soy-based diet; (1) and (4) were given tap water; (2) and (5) tap water containing 15 ppm of Cd{sup 2+}; and (3) and (6) tap water containing 100 ppm of Cd{sup 2+}. Serum lipid peroxides increased and PON-1 activity decreased in group (3). Lipoperoxidation also increased in the heart of all intoxicated groups; however protein oxidation only augmented in (3) and reduced glutathione levels diminished in (2) and (3). Catalase activity increased in groups (3) and (6) while superoxide dismutase activity increased only in (6). Glutathione peroxidase activity decreased in groups (3) and (6). Nrf2 expression was higher in groups (3) and (6), and MTI expression augmented in (3). Histological examination of the heart tissue showed the development of hypertrophic and fusion of cardiomyocytes along with foci of myocardial fiber necrosis. The transmission electron microscopy analysis showed profound ultra-structural damages. No protection against tissue degeneration was observed in animals fed the soy-based diet. Our findings indicate that even though the intake of a soy-based diet is capable of ameliorating Cd induced oxidative stress, it failed in preventing cardiac damage. -- Highlights: ► Cd intoxication produces extracellular and ultrastructural damage in the myocardium. ► The intake of a soy-based diet ameliorated Cd-induced oxidative stress. ► Cd-induced myocardial damage wasn't prevented by the intake of a soy-based diet. ► Cd-induced myocardial degeneration may not be caused by oxidative stress generation. ► Histology evaluation is needed to

  14. Cadmium immobilization by hydroxyapatite

    Directory of Open Access Journals (Sweden)

    Smičiklas Ivana D.

    2003-01-01

    Full Text Available The contamination of air, soil and water by cadmium is a great environmental problem. If cadmium occurs in nature in ionic form, soluble in water, it easily enters into the food chain. Hydroxyapatite (HAP, Ca-o(POAe(OH2 is a sparingly soluble salt and an excellent matrix for the removal of heavy metals from solutions. Considerable research attention has been paid to the bond between Cc/2+ ions and synthetic hydroxyapatite of known composition. The sorption mechanism is complex. The dominant process is ion exchange, but surface adsorption, surface complexation and coprecipitation can also contribute to the overall mechanism. The sorption capacity depends on the characteristics of hydroxyapatite itself and on the experimental conditions. Under optimum conditions a maximum capacity of 0.8 mol Cd2+/mol HAP can be achieved. HAP is a potential sorbent for the remediation of contaminated water and soil, for industrial waste treatment, and it is also referenced as a material that can be used as a barrier around waste depositories.

  15. Cadmium colours: composition and properties

    Science.gov (United States)

    Paulus, J.; Knuutinen, U.

    The composition and the properties of cadmium aquarelle colours are discussed. The examined colours were 24 different aquarelle cadmium colours from six different manufacturers. The colours ranged from light, bright yellows to dark, deep-red tones. The aim of this research was to find out if the pigments contain cadmium salts: sulphides and/or selenides. This information will help in choosing watercolours in conservation processes. Today, aquarelle colours not containing cadmium pigments are being sold as cadmium colours; thus their properties might be different from actual cadmium colours. The aim of the research was to verify that the colour samples contained cadmium pigments and to estimate their compositions and ageing properties. Element analyses were performed from colour samples using micro-chemical tests and X-ray fluorescence measurements. Thin-layer chromatography was used for analysing gum Arabic as a possible binding medium in the chosen colour samples. Through ageing tests, the resistance of the colour samples to the exposure to light, heat and humidity was studied. Visible-light spectroscopy was used in determining the hues and hue changes of the aquarelle colour samples. The spectrophotometer used the CIE L*a*b* tone colour measuring system. From the colour measurements the changes in the lightness/darkness, the redness, the yellowness and the saturation of the samples were examined.

  16. A two-dimensional cadmium(II) coordination polymer based on 1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane and thiocyanate ligands.

    Science.gov (United States)

    Wang, Hui-Ting; Li, Qiang; Zhou, Lin

    2015-09-01

    A cadmium-thiocyanate complex, poly[(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κ(4)N)octakis-μ2-thiocyanato-κ(8)N:S;κ(8)S:N-tricadmium(II)], [Cd3(C8H14N3)2(NCS)8]n, was synthesized by the reaction of 1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride, cadmium nitrate tetrahydrate and potassium thiocyanide in aqueous solution. In the crystal structure, there are two independent types of Cd(II) cation (one on a centre of inversion and one in a general position) and both are in distorted octahedral coordination environments, coordinated by N and S atoms from different ligands. Neighbouring Cd(II) cations are linked together by thiocyanate bridges to form a two-dimensional network. Hydrogen-bonding interactions are involved in the formation of a three-dimensional supramolecular network.

  17. mitigating mitigating free riding in peer-to-peer networks

    African Journals Online (AJOL)

    eobe

    9. R. Krishnan, M. Smith, and Z. Tang, “The impact of free-riding. On peer-to-peer networks," in the 37th Annual Hawaii. International Conference on System Sciences, 2004, pp. 1-. 10. 10. P. Golle, K. Leyton-brown, I. Mironov, and M. Lillibridge,. “Incentives for Sharing in Peer-to-Peer Networks,". Electronic Commerce,, 2001.

  18. 76 FR 26923 - 50th Anniversary of the Freedom Rides

    Science.gov (United States)

    2011-05-09

    ... America, by virtue of the authority vested in me by the Constitution and the laws of the United States, do... discrimination, and to challenge the enforcement of local segregation laws and practices. The Freedom Rides... Freedom Riders also motivated and mobilized the next generation of civil rights leaders. The unflinching...

  19. Rural Midwestern Public College Safe Ride Program Case Study

    Science.gov (United States)

    Mohfeld, Kathy I.

    2017-01-01

    The central phenomenon researched in this case study was higher education administrators' decisions to institutionalize a safe ride program at a small, rural college. The purpose of this single/within-site case study was to describe the changes that happened at a rural public institution of higher education and the surrounding community in the…

  20. Hardness of Preemptive Finite Capacity Dial-a-Ride

    DEFF Research Database (Denmark)

    Gørtz, Inge Li

    2006-01-01

    In the Finite Capacity Dial-a-Ride problem the input is a metric space, a set of objects, each specifying a source and a destination, and an integer k---the capacity of the vehicle used for making the deliveries. The goal is to compute a shortest tour for the vehicle in which all objects can be d...

  1. Accreditation's Alchemy Hour: Riding the Wave of Innovation

    Science.gov (United States)

    Gaston, Paul L.

    2014-01-01

    This article was adapted from Paul L. Gaston's address to the 2014 annual meeting of the "Association of American Colleges and Universities." The panel session talk "Accreditation: Riding the Wave of Innovation--or Going Under?" addressed issues surrounding the many proposals for demolishing and rebuilding higher education…

  2. Effect of Health Education on the Riding Habits of Commercial ...

    African Journals Online (AJOL)

    BACKGROUND: The increasing number of motorcyclists in Nigeria has led to a rise in poor road safety practices leading to increased rate of accidents. This study was conducted to implement and evaluate the effect of safety education on riding habits of motorcyclists in Uyo, Nigeria. METHODS: The intervention study was ...

  3. Minimum Makespan Multi-vehicle Dial-a-Ride

    DEFF Research Database (Denmark)

    Gørtz, Inge Li; Nagarajan, Viswanath; Ravi, R.

    2009-01-01

    Dial-a-Ride problems consist of a set V of n vertices in a metric space (denoting travel time between vertices) and a set of m objects represented as source-destination pairs {(si,ti)}mi=1, where each object requires to be moved from its source to destination vertex. In the multi-vehicle Dial-a-R...

  4. Promoting bike-and-ride : the Dutch experience

    NARCIS (Netherlands)

    Martens, C.J.C.M.

    2007-01-01

    The number of policy initiatives to promote the use of bike-and-ride, or the combined use of bicycle and public trans-port for one trip, has grown considerably over the past decade as part of the search for more sustainable transport solu-tions. This paper discusses the experiences with, and impacts

  5. Minimum Makespan Multi-Vehicle Dial-a-Ride

    DEFF Research Database (Denmark)

    Gørtz, Inge Li; Nagarajan, Viswanath; Ravi, R.

    2015-01-01

    Dial-a-Ride problems consist of a set V of n vertices in a metric space (denoting travel time between vertices) and a set of m objects represented as source-destination pairs {(s(i), t(i))}(i-1)(m), where each object requires to be moved from its source to destination vertex. In the multi......-vehicle Dial-a-Ride problem, there are q vehicles, each having capacity k and where each vehicle j epsilon [q] has its own depot-vertex r(j) epsilon V. A feasible schedule consists of a capacitated route for each vehicle (where vehicle j originates and ends at its depot r(j)) that together move all objects...... of multi-vehicle Dial-a-Ride, in which an object may be left at intermediate vertices and transported by more than one vehicle, while being moved from source to destination. Our main results are an O(log(3) n)-approximation algorithm for preemptive multi-vehicle Dial-a-Ride, and an improved O(log t...

  6. Undoing Quantitative Easing: Janet Yellen's Tiger Ride

    Science.gov (United States)

    Niederjohn, M. Scott; Schug, Mark C.; Wood, William C.

    2014-01-01

    "One who rides a tiger is afraid to dismount," says a colorful proverb from an earlier time. This may be an apt saying for the situation facing the new head of the Federal Reserve, Janet L. Yellen, who takes over at a time when successive rounds of Fed policy have taken the central bank into uncharted territory. By historical standards,…

  7. A participatory sensing approach to characterize ride quality

    Science.gov (United States)

    Bridgelall, Raj

    2014-03-01

    Rough roads increase vehicle operation and road maintenance costs. Consequently, transportation agencies spend a significant portion of their budgets on ride-quality characterization to forecast maintenance needs. The ubiquity of smartphones and social media, and the emergence of a connected vehicle environment present lucrative opportunities for cost-reduction and continuous, network-wide, ride-quality characterization. However, there is a lack of models to transform inertial and position information from voluminous data flows into indices that transportation agencies currently use. This work expands on theories of the Road Impact Factor introduced in previous research. The index characterizes road roughness by aggregating connected vehicle data and reporting roughness in direct proportion to the International Roughness Index. Their theoretical relationships are developed, and a case study is presented to compare the relative data quality from an inertial profiler and a regular passenger vehicle. Results demonstrate that the approach is a viable alternative to existing models that require substantially more resources and provide less network coverage. One significant benefit of the participatory sensing approach is that transportation agencies can monitor all network facilities continuously to locate distress symptoms, such as frost heaves, that appear and disappear between ride assessment cycles. Another benefit of the approach is continuous monitoring of all high-risk intersections such as rail grade crossings to better understand the relationship between ride-quality and traffic safety.

  8. Optimizing itineraries in public transportation with walks between rides

    NARCIS (Netherlands)

    de Jonge, Bram; Teunter, Ruud H.

    We study the problem of finding an optimal itinerary to travel from a starting location to a destination location using public transport, where we allow travelers to alternate rides with (short) walks. The main difference with previous research is that we take all possible walks that a traveler can

  9. Science 101: How Do People Design Safe Amusement Park Rides?

    Science.gov (United States)

    Robertson, Bill

    2015-01-01

    To address the question of how people design safe amusement park rides, Bill Robertson focuses on the factors designers must consider so that human bodies don't experience too large an acceleration (any change in speed and/or direction) or "g-force" (the acceleration an object undergoes while freely falling, with no air resistance, under…

  10. Solid phase extraction and trace monitoring of cadmium ions in environmental water and food samples based on modified magnetic nanoporous silica

    Energy Technology Data Exchange (ETDEWEB)

    Omidi, Fariborz [Department of Occupational Health Engineering, School of Public Health, Shahroud University of Medical Sciences, Shahroud (Iran, Islamic Republic of); Behbahani, Mohammad, E-mail: mohammadbehbahai89@yahoo.com [Department of Chemistry, Shahid Beheshti University, Evin, Tehran (Iran, Islamic Republic of); Kalate Bojdi, Majid [Faculty of Chemistry, Kharazmi (Tarbiat Moallem) University, Tehran (Iran, Islamic Republic of); Shahtaheri, Seyed Jamaleddin [Department of Occupational Health Engineering, School of Public Health and Institute for Environmental Research, Tehran University of Medical Sciences, Tehran (Iran, Islamic Republic of)

    2015-12-01

    A new method has been developed for trace separation/preconcentration of cadmium ions using pyridine-functionalized magnetic nanoporous silica material (called Py-Fe{sub 3}O{sub 4}@MCM-41) as a new magnetic sorbent and their determination by flame atomic absorption spectrometry (FAAS). The Py-Fe{sub 3}O{sub 4}@MCM-41 sorbent was characterized by thermogravimetric analysis, differential thermal analysis, transmission electron microscopy, Fourier transform infrared spectrometry and X-ray diffraction. The modified Fe{sub 3}O{sub 4}@MCM-41 can be easily separated from an aqueous solution by applying an external magnetic field. Effects of pH, amount of functionalized Fe{sub 3}O{sub 4}@MCM-41, extraction time, type and quantity of eluent, desorption time, and interfering ions on the extraction efficiency were evaluated and optimized. Under the optimized conditions, the detection limit and relative standard deviation was 0.04 μg L{sup –1} and 2.9%, respectively and the maximum adsorption capacity of the synthesized sorbent for cadmium ions was 154 mg g{sup −1}. The proposed method has been applied to the determination of Cd ions at trace levels in real samples such as, rice, onion, carrot, lettuce, parsley, basil, tap water, river water and seawater with satisfactory results. - Highlights: • The introducing of modified magnetic mesoporous silica as a novel magnetic sorbent. • Trace monitoring of cadmium ions. • The limit of detection (LOD) by the proposed solid phase extraction method was 0.04 ng mL{sup −1} for the cadmium ions. • High surface areas and magnetic characteristic of the sorbent. • Maximum adsorption capacity of the sorbent was 154 mg g{sup −1}.

  11. Zinc to cadmium replacement in the A. thaliana SUPERMAN Cys₂ His₂ zinc finger induces structural rearrangements of typical DNA base determinant positions.

    Science.gov (United States)

    Malgieri, Gaetano; Zaccaro, Laura; Leone, Marilisa; Bucci, Enrico; Esposito, Sabrina; Baglivo, Ilaria; Del Gatto, Annarita; Russo, Luigi; Scandurra, Roberto; Pedone, Paolo V; Fattorusso, Roberto; Isernia, Carla

    2011-11-01

    Among heavy metals, whose toxicity cause a steadily increasing of environmental pollution, cadmium is of special concern due to its relatively high mobility in soils and potential toxicity at low concentrations. Given their ubiquitous role, zinc fingers domains have been proposed as mediators for the toxic and carcinogenic effects exerted by xenobiotic metals. To verify the structural effects of zinc replacement by cadmium in zinc fingers, we have determined the high resolution structure of the single Cys₂ His₂ zinc finger of the Arabidopsis thaliana SUPERMAN protein (SUP37) complexed to the cadmium ion by means of UV-vis and NMR techniques. SUP37 is able to bind Cd(II), though with a dissociation constant higher than that measured for Zn(II). Cd-SUP37 retains the ββα fold but experiences a global structural rearrangement affecting both the relative orientation of the secondary structure elements and the position of side chains involved in DNA recognition: among them Ser17 side chain, which we show to be essential for DNA binding, experiences the largest displacement. 2011 Wiley Periodicals, Inc.

  12. Determination of Cadmium Ions by Designing an Optode Based on Immobilization of Dithizone on a Triacetylecelluose Membrane in Polluted Soil and Water Samples

    Energy Technology Data Exchange (ETDEWEB)

    Tavallali, Hossein; Kazempourfard, Fatemeh [Payame Noor University, Shiraz (Iran, Islamic Republic of)

    2009-04-15

    An optode for cadmium ion determination has been designed by immobilization of dithizone on triacetylcellose membrane. When the optode membrane is introduced into a real samples containing cadmium, there is a color change from green to red, making it possible to use the change in absorbance at 611 nm as the analytical signal. The sensor could be used in the range of 0.3-3 μg ml{sup -1} (2.67-26.67 μM) of Cd{sup 2+} ions with a limit of detection of 0.025 μg ml{sup -1} (25 ng ml{sup -1}). The response time of optode is within 15 min depending on the concentration of Cd{sup 2+} ions. It can be easily and completely regenerated by dilute EDTA solution. The effect of different possible interfering species has been examined and was shown the optode has a good selectivity. The results obtained for the determination of cadmium ion in polluted soil and water samples using the proposed optode was found to be comparable with the well-established atomic absorption method.

  13. Numerical Simulation of the Performance Characteristics, Instability, and Effects of Band Gap Grading in Cadmium Telluride Based Photovoltaic Devices

    Energy Technology Data Exchange (ETDEWEB)

    Petersen, Michael David [Iowa State Univ., Ames, IA (United States)

    2001-05-01

    Using computer simulations, the performance of several CdTe based photovoltaic structures has been studied. The advantages and disadvantages of band gap grading, through the use of (Zn,Cd)Te, have also been investigated in these structures. Grading at the front interface between a CdS window layer and a CdTe absorber layer, can arise due to interdiffusion between the materials during growth or due to the intentional variation of the material composition. This grading has been shown to improve certain performance metrics, such as the open-circuit voltage, while degrading others, such as the fill factor, depending on the amount and distance of the grading. The presence of a Schottky barrier as the back contact has also been shown to degrade the photovoltaic performance of the device, resulting in a characteristic IV curve. However, with the appropriate band gap grading at the back interface, it has been shown that the performance can be enhanced through more efficient carrier collection. These results were then correlated with experimental observations of the performance degradation in devices subjected to light and heat stress.

  14. Numerical Simulation of the Performance Characteristics, Instability, and Effects of Band Gap Grading in Cadmium Telluride Based Photovoltaic Devices

    Energy Technology Data Exchange (ETDEWEB)

    Petersen, Michael David [Iowa State Univ., Ames, IA (United States)

    2001-01-01

    Using computer simulations, the performance of several CdTe based photovoltaic structures has been studied. The advantages and disadvantages of band gap grading, through the use of (Zn, Cd)Te, have also been investigated in these structures. Grading at the front interface between a CdS window layer and a CdTe absorber layer, can arise due to interdiffusion between the materials during growth or due to the intentional variation of the material composition. This grading has been shown to improve certain performance metrics, such as the open-circuit voltage, while degrading others, such as the fill factor, depending on the amount and distance of the grading. The presence of a Schottky barrier as the back contact has also been shown to degrade the photovoltaic performance of the device, resulting in a characteristic IV curve. However, with the appropriate band gap grading at the back interface, it has been shown that the performance can be enhanced through more efficient carrier collection. These results were then correlated with experimental observations of the performance degradation in devices subjected to light and heat stress.

  15. A simple method based on ICP-MS for estimation of background levels of arsenic, cadmium, copper, manganese, nickel, lead, and selenium in blood of the Brazilian population.

    Science.gov (United States)

    Nunes, Juliana A; Batista, Bruno L; Rodrigues, Jairo L; Caldas, Naise M; Neto, Jose A G; Barbosa, Fernando

    2010-01-01

    Throughout the world, biomonitoring has become the standard for assessing exposure of individuals to toxic elements as well as for responding to serious environmental public health problems. However, extensive biomonitoring surveys require rapid and simple analytical methods. Thus, a simple and high-throughput method is proposed for the determination of arsenic (As), cadmium (Cd), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), and selenium (Se) in blood samples by using inductively coupled plasma-mass spectrometry (ICP-MS). Prior to analysis, 200 microl of blood samples was mixed with 500 microl of 10% v/v tetramethylammonium hydroxide (TMAH) solution, incubated for 10 min, and subsequently diluted to 10 ml with a solution containing 0.05% w/v ethylenediamine tetraacetic acid (EDTA) + 0.005% v/v Triton X-100. After that, samples were directly analyzed by ICP-MS (ELAN DRC II). Rhodium was selected as an internal standard with matrix-matching calibration. Method detection limits were 0.08, 0.04, 0.5, 0.09, 0.12, 0.04, and 0.1 microg//L for As, Cd, Cu, Mn, Ni, Pb, and Se, respectively. Validation data are provided based on the analysis of blood samples from the trace elements inter-\\comparison program operated by the Institut National de Sante Publique du Quebec, Canada. Additional validation was provided by the analysis of human blood samples by the proposed method and by using electrothermal atomic absorption spectrometry (ETAAS). The method was subsequently applied for the estimation of background metal blood values in the Brazilian population. In general, the mean concentrations of As, Cd, Cu, Mn, Ni, Pb, and Se in blood were 1.1, 0.4, 890, 9.6, 2.1, 65.4, and 89.3 microg/L, respectively, and are in agreement with other global populations. Influences of age, gender, smoking habits, alcohol consumption, and geographical variation on the values were also considered. Smoking habits influenced the levels of Cd in blood. The levels of Cu, Mn, and Pb were

  16. Fault Ride-Through Capability Enhancement of VSC HVDC connected Offshore Wind Power Plants

    DEFF Research Database (Denmark)

    Sharma, Ranjan; Wu, Qiuwei; Cha, Seung-Tae

    2015-01-01

    This paper presents a feed forward direct current (DC) voltage control based fault ride-through (FRT) scheme for voltage source converter (VSC) high voltage DC (HVDC) connected offshore wind power plants (WPPs) in order to achieve active control of the WPP collector network AC voltage magnitude......, and to improve the FRT capability. During steady state operation, an open loop AC voltage control is implemented at the WPP side VSC of the HVDC system such that any possible control interactions between the WPP side VSC and the wind turbine VSC are minimized. Whereas during any grid faults, a dynamic AC voltage...

  17. Tour Planning and Ride Matching for an Urban Social Carpooling Service

    Directory of Open Access Journals (Sweden)

    Jamal J.

    2016-01-01

    Full Text Available SocialCar is a research project aiming at integrating carpooling with existing transportation systems in urban and peri-urban environments. The system, that also takes benefit from social network interactions, is based on tour planning and ride matching algorithms to suggest the users the available alternatives for their trips. In this paper we overview some approaches to model general public transportation networks and carpooling services. A route planning algorithm, able to integrate different types of public transportation, bike rentals and carpooling services is finally presented.

  18. Disability, Riding, and Identity: A Qualitative Study on the Influence of Riding on the Identity Construction of People with Disabilities

    Science.gov (United States)

    Lundquist Wanneberg, Pia

    2014-01-01

    Semi-structured face-to-face interviews were used to examine the influence of riding on the identity construction of people with disabilities. The 15 participants, three men and 12 women, were between 15 and 65 years old and have various physical disabilities. The data analysis derives from identity theory, a social-psychological theory that…

  19. Bioavailability of cadmium from linseed and cocoa

    DEFF Research Database (Denmark)

    Hansen, Max; Rasmussen, Rie Romme; Sloth, Jens Jørgen

    2014-01-01

    for the food authorities in order to give correct advises to the population. The aim of this study was to investigate the bioavailability of cadmium from whole linseed, crushed linseed, cocoa and cadmium chloride in rats. An experiment where 40 rats were divided into 4 groups and a control group and dosed...... with whole linseed, crushed linseed, cocoa and CdCl2 for 3 weeks was performed. Linseed or cocoa made up 10% of the feed (by weight) and was added as a replacement for carbohydrate source. The rats were dosed for 3 weeks and the cadmium content in the rats' kidneys was measured by ICPMS as a biomarker...... be measured in the kidney compared to the calculated total intake was as follows: Control 2.0 %, Crushed linseed 0.9 %, whole linseed, 1.5 %, cocoa 0.7 % and CdCl2 4.6 %. Based on this study it could not be concluded that the bioavailability in rats form whole linseed is lower that for crushed linseed...

  20. Acute fatal occupational cadmium poisoning by inhalation

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, K.; Ueda, M.; Kikuchi, H.; Hattori, H.; Hiraoka, Y.

    1983-01-01

    A 43-year-old male smelter was admitted to a hospital on account of severe dyspnea about 2 days after exposure to brownish-yellow smoke produced by melting of ''copper'' scrap. On admission pronounced hypoxemia was revealed, and an oxygen-enriched gas was administered after intubation. Although inspired oxygen concentration was gradually increased, hypoxemia progressed and he died on day 11 in hospital. The principal autopsy finding was chiefly confined to the lungs. Both lungs were heavy (the left weighing 1,470 g; the right 1,710 g) and firm to the touch. Histologically, no normal alveoli were found throughout the entire lung. Some alveolar spaces were occupied by pneumocytes, others by organized exudate with fibrosis. Interstitial fibrosis was present. Patchy areas of inflammatory cell infiltrations as well as intra-alveolar hemorrhages were observed. On the basis of the above findings a diagnosis of diffuse alveolar damage was made. Based on the available evidence (presence of cadmium in the ''copper'' scrap, feature of the smoke, clinical signs with latent time, and high cadmium concentration of the lung), the diffuse alveolar damage was considered to have been caused by inhaled cadmium. The pulmonary change of the present case was more advanced in pathologic stage in comparison with those reported in the literature.

  1. Environmental cadmium and lead exposure and anti-Müllerian hormone in pregnant women

    DEFF Research Database (Denmark)

    Christensen, P. S.; Bonde, J. P.; Bungum, L.

    2016-01-01

    -AMH. MATERIALS AND METHOD: The associations between serum-AMH and whole blood cadmium or lead were investigated by general linear models in a population-based sample of 117 pregnant women. RESULTS: The mean concentrations of blood cadmium and lead were 0.71μg/L and 17.4μg/L, respectively. The mean serum...

  2. Second-Order Free-Riding on Antisocial Punishment Restores the Effectiveness of Prosocial Punishment

    Directory of Open Access Journals (Sweden)

    Attila Szolnoki

    2017-10-01

    Full Text Available Economic experiments have shown that punishment can increase public goods game contributions over time. However, the effectiveness of punishment is challenged by second-order free-riding and antisocial punishment. The latter implies that noncooperators punish cooperators, while the former implies unwillingness to shoulder the cost of punishment. Here, we extend the theory of cooperation in the spatial public goods game by considering four competing strategies, which are traditional cooperators and defectors, as well as cooperators who punish defectors and defectors who punish cooperators. We show that if the synergistic effects are high enough to sustain cooperation based on network reciprocity alone, antisocial punishment does not deter public cooperation. Conversely, if synergistic effects are low and punishment is actively needed to sustain cooperation, antisocial punishment does is viable, but only if the cost-to-fine ratio is low. If the costs are relatively high, cooperation again dominates as a result of spatial pattern formation. Counterintuitively, defectors who do not punish cooperators, and are thus effectively second-order free-riding on antisocial punishment, form an active layer around punishing cooperators, which protects them against defectors that punish cooperators. A stable three-strategy phase that is sustained by the spontaneous emergence of cyclic dominance is also possible via the same route. The microscopic mechanism behind the reported evolutionary outcomes can be explained by the comparison of invasion rates that determine the stability of subsystem solutions. Our results reveal an unlikely evolutionary escape from adverse effects of antisocial punishment, and they provide a rationale for why second-order free-riding is not always an impediment to the evolutionary stability of punishment.

  3. Effects of Nano-zinc on Biochemical Parameters in Cadmium-Exposed Rats.

    Science.gov (United States)

    Hejazy, Marzie; Koohi, Mohammad Kazem

    2017-12-01

    Cadmium (Cd) is a toxic environmental and occupational pollutant with reported toxic effects on the kidneys, liver, lungs, bones, and the immunity system. Based on its physicochemical similarity to cadmium, zinc (Zn) shows protective effects against cadmium toxicity and cadmium accumulation in the body. Nano-zinc and nano-zinc oxide (ZnO), recently used in foods and pharmaceutical products, can release a great amount of Zn2+ in their environment. This research was carried out to investigate the more potent properties of the metal zinc among sub-acute cadmium intoxicated rats. Seventy-five male Wistar rats were caged in 15 groups. Cadmium chloride (CdCl2) was used in drinking water to induce cadmium toxicity. Different sizes (15, 20, and 30 nm) and doses of nano-zinc particles (3, 10, 100 mg/kg body weight [bw]) were administered solely and simultaneously with CdCl2 (2-5 mg/kg bw) for 28 days. The experimental animals were decapitated, and the biochemical biomarkers (enzymatic and non-enzymatic) were determined in their serum after oral exposure to nano-zinc and cadmium. Statistical analysis was carried out with a one-way ANOVA and t test. P nano-zinc-treated rats. AST, ALT, triglyceride, total cholesterol, LDL, and free fatty acids increased significantly in the cadmium- and nano-zinc-treated rats compared with the controls. However, albumin, total protein, and HDLc significantly decreased in the cadmium- and nano-zinc-treated rats compared with the controls (P nano-zinc, the smaller sizes with low doses and the larger sizes with high doses are more toxic than metallic zinc. In a few cases, an inverse dose-dependent relationship was seen as well. This research showed that in spite of larger sizes of zinc, smaller sizes of nano-zinc particles are not suitable for protection against cadmium intoxication.

  4. Equine Exercise in Younger and Older Adults: Simulated Versus Real Horseback Riding.

    Science.gov (United States)

    Kim, Min Joo; Kim, TaeYeong; Oh, Sejun; Yoon, BumChul

    2018-02-01

    Horseback riding is an effective exercise for improving postural control and balance. To reduce costs and improve accessibility, simulated horseback riding has been developed; but no differential effects of simulated and real horseback riding on muscle activation patterns in older adults have been studied. Thus, we compared muscle activation patterns for older and younger adults engaged in real and simulated horseback riding exercises, using surface electromyography recordings of the erector spinae, rectus abdominis, internal oblique abdominis, and rectus femoris muscles. We recorded muscle activity for three riding patterns: walk, slow trot, and fast trot. Muscle activation was uniformly higher for simulated (vs. real) horseback riding and increased from the walking pattern through slow and fast trot. There was no age effect, but among older participants, muscle activation was higher for simulated (vs. real) horseback riding across all gait types. Simulated and real riding produced a similar pattern of muscle activation of the thigh and trunk. These results demonstrate that simulated horseback riding can be an effective alternative to actual riding for increasing trunk and thigh muscle activation and improving postural control and balance, perhaps especially among older adults.

  5. Ride control of surface effect ships using distributed control

    Directory of Open Access Journals (Sweden)

    Asgeir J. Sørensen

    1994-04-01

    Full Text Available A ride control system for active damping of heave and pitch accelerations of Surface Effect Ships (SES is presented. It is demonstrated that distributed effects that are due to a spatially varying pressure in the air cushion result in significant vertical vibrations in low and moderate sea states. In order to achieve a high quality human comfort and crew workability it is necessary to reduce these vibrations using a control system which accounts for distributed effects due to spatial pressure variations in the air cushion. A mathematical model of the process is presented, and collocated sensor and actuator pairs are used. The process stability is ensured using a controller with appropriate passivity properties. Sensor and actuator location is also discussed. The performance of the ride control system is shown by power spectra of the vertical accelerations obtained from full scale experiments with a 35 m SES.

  6. Zinc-induced protection against cadmium

    Energy Technology Data Exchange (ETDEWEB)

    Early, J.L.; Schnell, R.C.

    1978-02-01

    Pretreatment of male rats with cadmium acetate potentiates the duration of hexobarbital hypnosis and inhibits the rate of hepatic microsomal drug metabolism. Pretreatment of rats with zinc acetate protects against these alterations in drug action elicited by cadmium.

  7. Safety riding program and motorcycle-related injuries in Thailand.

    Science.gov (United States)

    Woratanarat, Patarawan; Ingsathit, Atiporn; Chatchaipan, Pornthip; Suriyawongpaisal, Paibul

    2013-09-01

    A retrospective cohort study was conducted in Thailand from 2007 to 2009 to evaluate the efficacy of a safety riding program in preventing motorcycle-related injuries. A training group of motorcyclists were certified by the Asia-Pacific Honda Safety Riding Program in either 30-h instruction (teaching skills, riding demonstration) or 15-h license (knowledge, skills, and hazard perception) courses. The control group consisted of untrained motorcyclists matched on an approximately 1:1 ratio with the training group by region and date of licensure. In total, there were 3250 subjects in the training group and 2963 in the control group. Demographic data and factors associated with motorcycle-related injuries were collected. Motorcycle-related injuries were identified using the Road Injuries Victims Protection for injuries claims and inpatient diagnosis-related group datasets from the National Health Security Office. The capture-recapture technique was used to estimate the prevalence of injuries. Multivariate analysis was used to identify factors related to motorcycle-related injuries. The prevalence of motorcycle-related injuries was estimated to be 586 out of 6213 riders (9.4%) with a 95% confidence interval (CI): 460-790. The license course and the instruction course were significantly associated with a 30% and 29% reduction of motorcycle-related injuries, respectively (relative risk 0.70, 95% CI: 0.53-0.92 and 0.71, 95% CI: 0.42-1.18, respectively). Other factors associated with the injuries were male gender and young age. Safety riding training was effective in reducing injuries. These training programs differ from those in other developed countries but display comparable effects. Hazard perception skills might be a key for success. This strategy should be expanded to a national scale. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. High blood cadmium levels are not associated with consumption of traditional food among the Inuit of Nunavik

    Energy Technology Data Exchange (ETDEWEB)

    Rey, M. [Instituto Nacional de Cancerologia, Bogota (Colombia); Turcotte, F.; Lapointe, C. [Universite Laval, Quebec City (Canada)] [and others

    1997-09-01

    High levels of cadmium in the liver and kidneys of caribous and sea mammals of the Canadian Arctic have led to recommendations to remove such offal from the traditional diet. Blood cadmium levels have been found to be very high in samples of Inuit volunteers, hence the hypothesis that the Inuit might be exposed to cadmium through their diet. This survey of a population-based random sample of Nunavik residents (n = 518) confirms that blood cadmium of Inuit is indeed very high by comparison to published reports. Blood cadmium levels are closely associated with the current smoking status and are independent of dietary patterns among nonsmokers. Plasma omega-3 fatty acids concentrations have been used to assess the reliability of the dietary information collected by questionnaires and to test for any association of blood cadmium with the consumption of sea mammals. Blood cadmium levels are not related to the reported consumption of sea mammals. Blood cadmium levels are very high among smokers and are associated with levels of exposure to tobacco. Among nonsmoking Inuit, blood cadmium levels are comparable with those reported in nonsmokers elsewhere in the world. In reference to international standards, blood cadmium concentrations are high enough among the Inuit to warrant energetic public health interventions. 28 refs., 5 tabs.

  9. Phenols and phenol oxidases are involved in cadmium accumulation in the water plants Nymphoides peltata (Menyanthaceae) and Nymphaeae (Nymphaeaceae).

    Science.gov (United States)

    Lavid, N; Schwartz, A; Lewinsohn, E; Tel-Or, E

    2001-12-01

    This comparative study investigates the mechanism of cadmium accumulation in the semiaquatic plant Nymphoides peltata (Menyanthaceae) and the aquatic plant Nymphaea (Nymphaeaceae). It was conducted as part of an ongoing study of the use of water plants for phytoremediation. Epidermal structures, known as hydropotes, are located on the abaxial epidermis of the leaf laminae of Nymphoides peltata and are shown to contain phenols, peroxidase and polyphenol oxidase activities. When plants are subjected to 50 mg/l of cadmium in the growth medium, these hydropotes accumulate cadmium. Cadmium-induced increases in phenols, peroxidase and polyphenol oxidase activities were determined in plant extracts. Cadmium binding by polymerized phenols was demonstrated in vivo. In comparison with Nymphaeae epidermal glands, N. peltata hydropotes are larger, open, and create bigger crystal, the latter principally composed of calcium and, proportionally, less cadmium. Although both plants showed similar levels of cadmium accumulation, N. peltata was sensitive while Nymphaeae was resistant to this cadmium level. It is suggested that in these water plants the main mechanism for cadmium accumulation is based on the trapping of cadmium crystals by polymerized phenols in specialized epidermal structures and this is due to peroxidase and polyphenol oxidase activities. Nymphaeae, with greater peroxidase activity and more polyphenols, is more resistant to this heavy metal than N. peltata.

  10. Leisure riding horses: research topics versus the needs of stakeholders.

    Science.gov (United States)

    Janczarek, Iwona; Wilk, Izabela

    2017-07-01

    Horses intended for leisure riding do not undergo any selection and most often retired sports horses or defective horses are chosen, as a low selling price determines their purchase by a leisure riding center. Unfortunately, horses bought at low prices usually have low utility value, are difficult to handle, require a special or individual approach and do not provide satisfaction in riding. However, neither modern horse breeding nor scientific research address the need to breed horses for leisure activities. There is no clear definition of a model leisure horse and criteria or information for its selection are not readily available in scientific publications. A wide spectrum of research methods may be used to evaluate various performance traits in horses intended for leisure activities. The fact that the population of recreational horses and their riders outnumber sporting horses should attract the special attention of scientific research. Their utility traits need to be determined with modern technology and methods in the same way they are for sporting horses. Such a system of evaluation would be very helpful for riders. © 2017 Japanese Society of Animal Science.

  11. An adaptive Phase-Locked Loop algorithm for faster fault ride through performance of interconnected renewable energy sources

    DEFF Research Database (Denmark)

    Hadjidemetriou, Lenos; Kyriakides, Elias; Blaabjerg, Frede

    2013-01-01

    Interconnected renewable energy sources require fast and accurate fault ride through operation in order to support the power grid when faults occur. This paper proposes an adaptive Phase-Locked Loop (adaptive dαβPLL) algorithm, which can be used for a faster and more accurate response of the grid...... side converter control of a renewable energy source, especially under fault ride through operation. The adaptive dαβPLL is based on modifying the control parameters of the dαβPLL according to the type and voltage characteristic of the grid fault with the purpose of accelerating the performance...... results. Furthermore, the benefits of using the proposed adaptive PLL on the control of the GSC of RES are also demonstrated in this paper....

  12. Cadmium uptake by plants

    Energy Technology Data Exchange (ETDEWEB)

    Haghiri, F.

    1973-01-01

    Absorption of /sup 115m/Cd by soybean (Gylcine max l.) plants via foliar and root systems and translocation into the seed was determined. The uptake of /sup 115m/Cd by soybeans via the root system was more efficient than that of the foliar placement. Growth and Cd concentrations of soybean and wheat (Triticum aestivum l.) tops were influenced by soil-applied Cd. In both crops, the Cd concentration of plant tops increased while yield decreased with increasing levels of applied Cd. Cadmium toxicitiy began to occur in both crops at the lowest level of soil applied Cd (2.5 ppM). With soybean plants, Cd toxicity symptoms resembled fe chlorosis. For wheat plants there were no visual symptoms other than the studied growth. The relative concentration of Cd found in several vegetable crops varied depending on the plant species. The relative Cd concentration in descending order for various vegetables was lettuce (Lactuca sativa l.) > radish top (Raphanus sativus l.) > celery stalk (Apium graveolens l.) > celery leaves greater than or equal to green pepper (Capsicum frutescens l.) > radish roots.

  13. Bioavailability of cadmium from linseed and cocoa

    DEFF Research Database (Denmark)

    Hansen, Max; Sloth, Jens Jørgen; Rasmussen, Rie Romme

    In Denmark and EU the exposure of cadmium from food is at a level that is relatively close to the Tolerable Daily Intake (TDI). This report describes an investigation of the bioavailability of cadmium in selected food items known to contain high levels of cadmium. The purpose was to provide data ...... or crushed linseed nor the intake of cocoa and chocolate....

  14. Cadmium and membrane ion transport in a French urban male population

    Energy Technology Data Exchange (ETDEWEB)

    Hajem, S.; Moreau, T.; Lellouch, J.; Huel, G.; Girard, F.; Sahuquillo, J. (National Inst. of Health and Medical Research, Villejuif (France)); Hannaert, P.; Garay, R.P. (INSERM, Paris (France)); Orssaud, G.; Claude, J.R. (Social and Sanitary Dept. Labs., Paris (France))

    1991-12-01

    Toxic effects of cadmium upon cell membranes structures and function have been well documented. Experimental studies have shown that cadmium is a potent Na{sup +}-K{sup +} ATPase inhibitor. One report has confirmed these findings with the human Na{sup +}-K{sup +} ATPase. Based on the above observations, several authors have suggested that a Na{sup +}-K{sup +} ATPase-inhibitory action could be involved in health related cadmium toxicity. Therefore, the authors measured hair cadmium and red blood cell Na{sup +}-K{sup +} pump (physiological counterpart of the Na{sup +}-K{sup +} ATPase) in 129 urban caucasian males, without known occupational exposure to cadmium. In addition, four other ion transport pathways were measured in red blood cells. Hair cadmium was considered, as it is known as an indicator of cadmium body burden. A particular emphasis was placed in defining the smoking habits of the subjects since tobacco is known to be the main source of cadmium exposure in the general population.

  15. Haematological changes in Bufo maculatus treated with sublethal concentrations of Cadmium

    Directory of Open Access Journals (Sweden)

    Lawrence Ikechukwu Ezemonye

    2011-12-01

    Full Text Available Adult Bufo maculatus was exposed to sublethal cadmium concentrations of 0.25, 0.50, 1.00 and 2.00 mg/L. The toxicant from which the cadmium concentrations were prepared was cadmium chloride (CdCl2.H2O. There were three replicate tanks per treatment and three individuals per tank including control groups. The hematologic alterations based on the examination of blood indices during the 28 days of exposure showed that total erythrocyte count (TEC, hematocrit (Hct and hemoglobin (Hb concentration decreased (P<0.05 relative to controls. The decline was concentration- dependent as concentration of cadmium increased. The decline in hemoglobin and hematocrit in the experimental organism could be due to a decrease in the synthesis or release of erythrocytes into the circulation or an increase in the rate of erythrocyte destruction inflicted by cadmium toxicity. There was significant (P<0.05 elevation in total leuko- leukocyte count (TLC with increase in the concen- cyte concentration of cadmium. The increase in total leukocyte count observed in this study could be attributed to a stimulation of the immune system in response to tissue damage caused by cadmium toxicity. The study has shown that the exposure of the Bufo maculatus toad to cadmium can inflict alterations in the hematologic indices, which could induce unfavorable physiological changes in the amphibian, which may lead to death. There is, therefore, the need to protect amphibians in order to sustain the biodiversity in the Nigerian Niger Delta ecological zone.

  16. Studies on growth and nucleation kinetics of cadmium thiourea sulphate and magnesium cadmium thiourea sulphate

    Energy Technology Data Exchange (ETDEWEB)

    Daniel, Mekala [Quaid-e-Milleth College, Chennai 600002 (India)], E-mail: mekaladaniel@rediffmail.com; Malliga, M. Jeyarani [Bharathi Women College, Chennai 600108 (India); Sankar, R. [Kings Engineering College, Irungatukottai, Sriperumbudhur, Chennai 602105 (India); Jayaraman, D. [Presidency College, Chennai 600 004 (India)

    2009-03-15

    Semiorganic materials, in general possess high non-linear coefficient and mechanical strength which will be more applicable for device fabrication. Cadmium thiourea sulphate (CTS) and magnesium cadmium thiourea sulphate (MCTS) are better semiorganic materials which find applications in the field of optoelectronics. Single crystals of CTS and MCTS have been successfully grown from aqueous solution by slow evaporation technique using predetermined solubility data. The basic growth parameters of the crystal nuclei of the grown crystals of CTS and MCTS were evaluated based on the classical theory of homogeneous nucleation. The classical nucleation theory makes use of capillarity approximation which has certain limitations. A correction has to be applied for it and the classical nucleation theory has been suitably modified in order to calculate the critical nucleus parameters.

  17. Development of an experimental methodology to evaluate the influence of a bamboo frame on the bicycle ride comfort

    Science.gov (United States)

    Thite, A. N.; Gerguri, S.; Coleman, F.; Doody, M.; Fisher, N.

    2013-09-01

    In the current environment of increased emphasis on sustainable transport, there is manifold increase in the use of bicycles for urban transport. One concern which might restrict the use is the ride comfort and fatigue. There has been limited research in addressing the difficulty in bicycle ride comfort quantification. The current study aims to develop a methodology to quantify bicycle discomfort so that performance of bicycles constructed from bamboo and aluminium alloy can be compared. Experimentally obtained frequency response functions are used to establish a relation between the road input and the seat and rider response. A bicycle track input profile based on standard road profiles is created so as to estimate the acceleration responses. The whole-body-vibration frequency weighting is applied to quantify the perception of vibration intensity so that eventual discomfort ranking can be obtained. The measured frequency response functions provide an insight into the effect of frame dynamics on the overall resonant behaviour of the bicycles. The beneficial effect of frame compliance and damping on lower modes of vibration is very clear in the case of bamboo frame, in turn affecting seat and rider response. In the bamboo frame, because of multiple resonances, the frequency response of the handlebar is smaller at higher frequencies suggesting effective isolation. Further improvements may have come from the joints made from natural composites. Overall, based on the comparative analysis and the methodology developed, bamboo frame shows significant improvement in ride comfort performance compared with the aluminium frame.

  18. Comparing the impacts of hiking, skiing and horse riding on trail and vegetation in different types of forest.

    Science.gov (United States)

    Törn, A; Tolvanen, A; Norokorpi, Y; Tervo, R; Siikamäki, P

    2009-03-01

    Nature-based tourism in protected areas has increased and diversified dramatically during the last decades. Different recreational activities have a range of impacts on natural environments. This paper reports results from a comparison of the impacts of hiking, cross-country skiing and horse riding on trail characteristics and vegetation in northern Finland. Widths and depths of existing trails, and vegetation on trails and in the neighbouring forests were monitored in two research sites during 2001 and 2002. Trail characteristics and vegetation were clearly related to the recreational activity, research site and forest type. Horse trails were as deep as hiking trails, even though the annual number of users was 150-fold higher on the hiking trails. Simultaneously, cross-country skiing had the least effect on trails due to the protective snow cover during winter. Hiking trail plots had little or no vegetation cover, horse riding trail plots had lower vegetation cover than forest plots, while skiing had no impact on total vegetation cover. On the other hand, on horse riding trails there were more forbs and grasses, many of which did not grow naturally in the forest. These species that were limited to riding trails may change the structure of adjacent plant communities in the long run. Therefore, the type of activities undertaken and the sensitivity of habitats to these activities should be a major consideration in the planning and management of nature-based tourism. Establishment of artificial structures, such as stairs, duckboards and trail cover, or complete closure of the site, may be the only way to protect the most sensitive or deteriorated sites.

  19. Investigation on Motorcyclist Riding Behaviour at Curve Entry Using Instrumented Motorcycle

    Science.gov (United States)

    Yuen, Choon Wah; Karim, Mohamed Rehan; Saifizul, Ahmad

    2014-01-01

    This paper details the study on the changes in riding behaviour, such as changes in speed as well as the brake force and throttle force applied, when motorcyclists ride over a curve section road using an instrumented motorcycle. In this study, an instrumented motorcycle equipped with various types of sensors, on-board cameras, and data loggers, was developed in order to collect the riding data on the study site. Results from the statistical analysis showed that riding characteristics, such as changes in speed, brake force, and throttle force applied, are influenced by the distance from the curve entry, riding experience, and travel mileage of the riders. A structural equation modeling was used to study the impact of these variables on the change of riding behaviour in curve entry section. Four regression equations are formed to study the relationship between four dependent variables, which are speed, throttle force, front brake force, and rear brake force applied with the independent variables. PMID:24523660

  20. Investigation on Motorcyclist Riding Behaviour at Curve Entry Using Instrumented Motorcycle

    Directory of Open Access Journals (Sweden)

    Choon Wah Yuen

    2014-01-01

    Full Text Available This paper details the study on the changes in riding behaviour, such as changes in speed as well as the brake force and throttle force applied, when motorcyclists ride over a curve section road using an instrumented motorcycle. In this study, an instrumented motorcycle equipped with various types of sensors, on-board cameras, and data loggers, was developed in order to collect the riding data on the study site. Results from the statistical analysis showed that riding characteristics, such as changes in speed, brake force, and throttle force applied, are influenced by the distance from the curve entry, riding experience, and travel mileage of the riders. A structural equation modeling was used to study the impact of these variables on the change of riding behaviour in curve entry section. Four regression equations are formed to study the relationship between four dependent variables, which are speed, throttle force, front brake force, and rear brake force applied with the independent variables.

  1. Coordinated Low Voltage Ride through strategies for Permanent Magnet Direct Drive Synchronous Generators

    Directory of Open Access Journals (Sweden)

    Zhang Ge

    2016-01-01

    Full Text Available By analyzing the mechanism of the low voltage ride through on the permanent magnet direct drive synchronous wind power generating units, this paper proposes a coordinated control strategy for permanent magnet synchronous generator. In order to avoid over speed operation of the generation units, over voltage on DC capacitor and over current on convert, the improved pitch angle control and inverter control are used. When the grid voltage drops, the captured wind power is cut down by the variable pitch system, which limits the speed of the generator, the generator side converter keeps the DC capacitor voltage stabile; and the grid side converter provides reactive power to the grid to help the grid voltage recover. The control strategy does not require any additional hardware equipment, with existing control means, the unit will be able to realize low voltage ride through. Finally, based on Matlab/Simulink to build permanent magnet direct drive wind power generation system, the simulation results verify the correctness and effectiveness of the control strategy.

  2. Sequential Determination of Total Arsenic and Cadmium in Concentrated Cadmium Sulphate Solutions by Flow-Through Stripping Chronopotentiometry after Online Cation Exchanger Separation

    Directory of Open Access Journals (Sweden)

    Frantisek Cacho

    2012-01-01

    Full Text Available Flow-through stripping chronopotentiometry with a gold wire electrode was used for the determination of total arsenic and cadmium in cadmium sulphate solutions for cadmium production. The analysis is based on the online separation of arsenic as arsenate anion from cadmium cations by means of a cation exchanger. On measuring arsenate in the effluent, the trapped cadmium is eluted by sodium chloride solution and determined in a small segment of the effluent by making use of the same electrode. The elaborated protocol enables a full automatic measurement of both species in the same sample solution. The accuracy of the results was confirmed by atomic absorption spectrometry. The LOD and LOQ for Arsenic were found to be 0.9 μg dm-3 and 2.7 μg dm-3, respectively. A linear response range was observed in the concentration range of 1 to 300 μg dm-3 for sample volumes of 4 mL. The repeatability and reproducibility were found to be 2.9% and 5.2%, respectively. The linear response range for cadmium was found to be 0.5 to 60 g/L. The method was tested on samples from a cadmium production plant.

  3. Pensionäride probleemid jõuavad Euroopa Komisjoni / Arvo Einre ; interv. Asse Soomets

    Index Scriptorium Estoniae

    Einre, Arvo, 1931-2012

    2005-01-01

    Eesti Pensionäride Ühendus sai Euroopa Komisjoni eakate nõukojalt (The European Older People Platform) kutse 31. märtsil Brüsselis toimuvale AGE töökoosolekule, kus käsitletakse pensionäride olukorda EL-i liikmesriikides. Eesti esindajana sõidab üritusele Eesti Pensionäride Ühenduse aseesimees Arvo Einre

  4. Removal of cadmium from acidic phosphatic solutions

    Energy Technology Data Exchange (ETDEWEB)

    Frankenfeld, K.; Brodt, P.; Eich, G.; Ruschke, P.

    1985-01-08

    The invention is concerned with a process of removing cadmium from acid, especially P/sub 2/O/sub 5/-containing solutions by liquid/liquid extraction with the aid of alkyl amine salts that are dissolved in an inert, organic solvent. The cadmium ions are removed from the acid, aqueous phase and are enriched in the organic phase. The cadmium-containing organic phase, subsequently, is re-extracted with an aqueous salt solution, with the cadmium ions migrating from the organic phase into the aqueous phase. The process is particularly suitable for extracting cadmium from concentrated, highly acid aqueous solutions.

  5. Modified Ride-On Cars and Young Children with Disabilities: Effects of Combining Mobility and Social Training.

    Science.gov (United States)

    Huang, Hsiang-Han; Chen, Yi-Mei; Huang, Hsuan-Wen; Shih, Ming-Ke; Hsieh, Yu-Hsin; Chen, Chia-Ling

    2017-01-01

    Research has shown that the use of power mobility devices is safe and beneficial for motor and cognitive development in children with motor disabilities; nevertheless, strong evidence of the benefits for social skill development is limited. This study aimed to examine the effects of combining ride-on car training with an adult-directed, social interaction program in a hospital-based environment on mobility and social functions in young children with motor disabilities. This study used a prospective, nonequivalent pretest-posttest control group design. Twenty-nine young children with motor disabilities, aged between 1 and 3 years, were recruited from local hospitals in Taiwan. The treatment group ( n  = 15) underwent 2-h ride-on car training sessions twice per week for a total of 9 weeks in the hospital environment. The control group ( n  = 14) underwent a 9-week home education program (mean: 200 min/week) focusing on mobility and social skills training. The Chinese version of the Pediatric Evaluation of Disability Inventory, Parenting Stress Index, and Goal Attainment Scaling were administered to all participants before and after the intervention, and at the end of the 9-week follow-up phase. Mobility and social functions significantly improved in both groups after the 9-week intervention, but this improvement was not maintained at the follow-up phase. The treatment group showed significantly better improvement in social function, parenting stress levels, and goal achievement than the control group at posttest. This two-group design study showed the benefits of combining a ride-on car use with a family-centered, structured, social interaction program for positive impacts on mobility, social function, and parenting stress levels. The combination of a modified ride-on car and a social training program has the potential to enhance socialization in young children with motor disabilities. www.ClinicalTrials.gov, identifier NCT02527499.

  6. Bike Riding and the Art of Learning

    Science.gov (United States)

    Kraft, Robert G.

    1978-01-01

    Suggestions for becoming an effective teacher and motivating students to think creatively are proposed based on the author's personal experience and theories of Rogers, Dewey, Piaget, and Maslow. Maslow's hierarchy of human needs is adapted to stages of learning readiness. (LBH)

  7. Magnesium supplements affect selected cadmium toxic actions and uptake of repeated doses of cadmium

    Directory of Open Access Journals (Sweden)

    Grosicki Andrzej

    2015-12-01

    Full Text Available The importance of magnesium supplements on organ retention of cadmium and allometric parameters after repeated exposure to cadmium chloride were studied in male Wistar rats. Magnesium chloride was given via drinking water (500 mg Mg/L to rats exposed intragastrically to cadmium chloride (labelled with cadmium 109 at a daily dose corresponding to 25 mg/kg diet for 7, 14, 21, and 28 d. Supplements of magnesium temporarily decreased cadmium retention in the duodenum and liver. No significant differences in cadmium retention were evidenced in the kidneys and testicles. The supplements of magnesium also retain more of the body weight gains and restore the relative liver and testicle weight in rats intoxicated with cadmium. Comparison of the present results with earlier reports suggests a relationship between doses of magnesium and cadmium; higher doses of cadmium need more magnesium to overcome toxic action of the heavy metal.

  8. Isolation, identification and cadmium adsorption of a high cadmium ...

    African Journals Online (AJOL)

    GREGORY

    2010-09-27

    Sep 27, 2010 ... P. chrysosporium was used to biosorp cadmium (II), lead (II), copper (II) and the adsorption capacities reached 23.04, 69.77 and 20.33mg/g dry biomass, respectively (Say et al. 2001). The maximum experimental biosorption capacities for entrapped live and dead fungal mycelia of L. sajur-caju were found ...

  9. Phytoextraction potential of cadmium and lead contamination using ...

    African Journals Online (AJOL)

    aghomotsegin

    2014-12-31

    Dec 31, 2014 ... Lead accumulation in plant tissue impairs various morphological, physiological, and biochemical functions .... chlorophyll meter (based on light transmittance through leaves) was used as a non-destructive tool for .... of cadmium on the photosynthetic system cause several structural and functional disorders.

  10. Cadmium distribution in coastal sediments and mollusks of the US.

    Science.gov (United States)

    Apeti, Dennis A; Lauenstein, Gunnar G; Riedel, Gerhardt F

    2009-07-01

    Cadmium (Cd) concentrations in the coastal United States were assessed using the National Status and Trends (NS&T) Mussel Watch dataset, which is based on the analysis of sediments and bivalves collected from 280 sites since 1986. Using the 1997 sediment data, Pearson correlation (r=0.44, pmollusk Cd content were not well correlated.

  11. Influence of diethyldithiocarbamate on cadmium and copper toxicity ...

    African Journals Online (AJOL)

    drinie

    phenomena linked to the natural medium complexity and to evaluate the interactions between two heavy metals cadmium, (Cd) and copper (Cd), and a fungicide, diethyldithiocarbamate (DDTC). The choice of these three chemicals was based on the fact that Cd and Cu are common and worrying environmental pollutants ...

  12. Using an epiphytic moss to identify previously unknown sources of atmospheric cadmium pollution.

    Science.gov (United States)

    Donovan, Geoffrey H; Jovan, Sarah E; Gatziolis, Demetrios; Burstyn, Igor; Michael, Yvonne L; Amacher, Michael C; Monleon, Vicente J

    2016-07-15

    Urban networks of air-quality monitors are often too widely spaced to identify sources of air pollutants, especially if they do not disperse far from emission sources. The objectives of this study were to test the use of moss bio-indicators to develop a fine-scale map of atmospherically-derived cadmium and to identify the sources of cadmium in a complex urban setting. We collected 346 samples of the moss Orthotrichum lyellii from deciduous trees in December, 2013 using a modified randomized grid-based sampling strategy across Portland, Oregon. We estimated a spatial linear model of moss cadmium levels and predicted cadmium on a 50m grid across the city. Cadmium levels in moss were positively correlated with proximity to two stained-glass manufacturers, proximity to the Oregon-Washington border, and percent industrial land in a 500m buffer, and negatively correlated with percent residential land in a 500m buffer. The maps showed very high concentrations of cadmium around the two stained-glass manufacturers, neither of which were known to environmental regulators as cadmium emitters. In addition, in response to our findings, the Oregon Department of Environmental Quality placed an instrumental monitor 120m from the larger stained-glass manufacturer in October, 2015. The monthly average atmospheric cadmium concentration was 29.4ng/m(3), which is 49 times higher than Oregon's benchmark of 0.6ng/m(3), and high enough to pose a health risk from even short-term exposure. Both stained-glass manufacturers voluntarily stopped using cadmium after the monitoring results were made public, and the monthly average cadmium levels precipitously dropped to 1.1ng/m(3) for stained-glass manufacturer #1 and 0.67ng/m(3) for stained-glass manufacturer #2. Published by Elsevier B.V.

  13. CORSA: An Open Solution for Social Oriented Real-time Ride Sharing

    Directory of Open Access Journals (Sweden)

    Bonarrigo Simone

    2015-01-01

    Full Text Available The combination of the interest in environmental questions on one hand and the massive use of web based social networks on the other recently led to a revival of carpooling. In particular, the exploitation of social networks promotes the information spreading for an effective service (e.g. reducing the lack of confidence among users and endorses carpooling companies via viral marketing, finally acting as a basis for trust based users recommendation system In this work we outline CORSA, an open source solution for a real time ride sharing (RTRS carpooling service that endorses the role of social networks by using them as a conveying scenario for the virtual credits reward mechanism CORSA is based on.

  14. Cadmium-induced testicular injury.

    Science.gov (United States)

    Siu, Erica R; Mruk, Dolores D; Porto, Catarina S; Cheng, C Yan

    2009-08-01

    Cadmium (Cd) is an environmental toxicant and an endocrine disruptor in humans and rodents. Several organs (e.g., kidney, liver) are affected by Cd and recent studies have illustrated that the testis is exceedingly sensitive to Cd toxicity. More important, Cd and other toxicants, such as heavy metals (e.g., lead, mercury) and estrogenic-based compounds (e.g., bisphenols) may account for the recent declining fertility in men among developed countries by reducing sperm count and testis function. In this review, we critically discuss recent data in the field that have demonstrated the Cd-induced toxicity to the testis is probably the result of interactions of a complex network of causes. This is likely to involve the disruption of the blood-testis barrier (BTB) via specific signal transduction pathways and signaling molecules, such as p38 mitogen-activated protein kinase (MAPK). We also summarize current studies on factors that confer and/or regulate the testis sensitivity to Cd, such as Cd transporters and metallothioneins, the impact of Cd on the testis as an endocrine disruptor and oxidative stress inducer, and how it may disrupt the Zn(2+) and/or Ca(2+) mediated cellular events. While much work is needed before a unified mechanistic pathway of Cd-induced testicular toxicity emerges, recent studies have helped to identify some of the likely mechanisms and/or events that take place during Cd-induced testis injury. Furthermore, some of the recent studies have shed lights on potential therapeutic or preventive approaches that can be developed in future studies by blocking or minimizing the destructive effects of Cd to testicular function in men.

  15. Free-riding og showrooming: konsekvenser for detaljistene

    OpenAIRE

    Pettersen, Stine; Hansen, Kristine; Toft, Mia

    2016-01-01

    Denne oppgaven tar for seg begrepet showrooming, de som showroomer og forholdet mellom mobilbruk, service, lojalitet og showrooming. Free-riding ved showrooming er et relativt nytt begrep, men det blir stadig et større problem for detaljister med fysiske butikklokaler. Showrooming-begrepet beskriver situasjonen der forbrukeren besøker en fysisk butikk for å prøve eller undersøke en vare for så å kjøpe den billigere på internett, enten mens personen fremdeles er i butikken eller...

  16. Split ring floating air riding seal for a turbine

    Science.gov (United States)

    Mills, Jacob A

    2015-11-03

    A floating air riding seal for a gas turbine engine with a rotor and a stator, an annular piston chamber with an axial moveable annular piston assembly within the annular piston chamber, an annular cavity formed on the annular piston assembly that faces a seal surface on the rotor, and a central passage connecting the annular cavity to the annular piston chamber to supply compressed air to the seal face, where the annular piston assembly is a split piston assembly to maintain a tight seal as coning of the rotor disk occurs.

  17. Compression fractures of the vertebrae during a "bumpy" boat ride.

    LENUS (Irish Health Repository)

    Chukwunyerenwa, C K

    2012-01-31

    INTRODUCTION: Compression fracture of the vertebrae is common, often the result of falls from height and motor vehicle accidents in the younger age groups. It can occur following minor trauma in the elderly and in those with osteoporosis. MATERIALS AND METHODS: We present an interesting case of compression fracture of the vertebral bodies occurring simultaneously in a couple during a boat ride while on holiday. One individual had fracture of the T8, while the other fractured the L1 vertebrae. Both injuries were treated conservatively with Taylor braces. CONCLUSION: We highlight one of the potential hazards of this recreational activity, and the almost identical fracture pattern in this couple.

  18. The application of glyoxal-bis-(2-hydroxyanil to the determination of trace amounts of cadmium by spectrofluorimetry

    Directory of Open Access Journals (Sweden)

    Dong Yanjie

    2006-01-01

    Full Text Available The fluorescent reaction of the reagent glyoxal-bis-(2-hydroxyanil (GBHA with cadmium was studied. Based on this chelation reaction, a sensitive, rapid, direct spectrofluorimetric method for the determination of trace cadmium with GBHA has been developed. The reaction conditions for the fluorescence system of cadmium with GBHA were established. The cadmium ion can form a stable chelate with GBHA, having a ratio of 1:3 in the 12.0 -13.0 pH range. The maximum excitation and emission wavelengths are 227.4 nm and 320.0 nm for the cadmium chelate, respectively. The fluorescence intensity of the cadmium chelate remains stable from 20 to 150 min. Under the optimal experimental conditions the fluorescence intensity is a linear function of concentration in the range 1.0-10.0 ng mL-1 of cadmium and the detection limit is 0.65 ng mL-1 of cadmium. Interferences of foreign ions were studied. The method has been successfully applied to the determination of cadmium in the sewage.

  19. Modulation of Metabolism and Switching to Biofilm Prevail over Exopolysaccharide Production in the Response of Rhizobium alamii to Cadmium

    Science.gov (United States)

    Schue, Mathieu; Fekete, Agnes; Ortet, Philippe; Brutesco, Catherine; Heulin, Thierry; Schmitt-Kopplin, Philippe; Achouak, Wafa; Santaella, Catherine

    2011-01-01

    Heavy metals such as cadmium (Cd2+) affect microbial metabolic processes. Consequently, bacteria adapt by adjusting their cellular machinery. We have investigated the dose-dependent growth effects of Cd2+ on Rhizobium alamii, an exopolysaccharide (EPS)-producing bacterium that forms a biofilm on plant roots. Adsorption isotherms show that the EPS of R. alamii binds cadmium in competition with calcium. A metabonomics approach based on ion cyclotron resonance Fourier transform mass spectrometry has showed that cadmium alters mainly the bacterial metabolism in pathways implying sugars, purine, phosphate, calcium signalling and cell respiration. We determined the influence of EPS on the bacterium response to cadmium, using a mutant of R. alamii impaired in EPS production (MSΔGT). Cadmium dose-dependent effects on the bacterial growth were not significantly different between the R. alamii wild type (wt) and MSΔGT strains. Although cadmium did not modify the quantity of EPS isolated from R. alamii, it triggered the formation of biofilm vs planktonic cells, both by R. alamii wt and by MSΔGT. Thus, it appears that cadmium toxicity could be managed by switching to a biofilm way of life, rather than producing EPS. We conclude that modulations of the bacterial metabolism and switching to biofilms prevails in the adaptation of R. alamii to cadmium. These results are original with regard to the conventional role attributed to EPS in a biofilm matrix, and the bacterial response to cadmium. PMID:22096497

  20. Riding a tsunami in ocean science education

    Science.gov (United States)

    Reed, Donald L.

    1998-08-01

    An experiment began in late 1994 in which the WWW plays a critical role in the instruction of students in an oceanography course for non-majors. The format of the course consists of an equal blend of traditional lectures, tutorial-style exercises delivered from the course WWW site, classroom activities, such as poster presentations and group projects, and field excursions to local marine environments. The driving force behind the technology component of the course is to provide high-quality educational materials that can be accessed at the convenience of the student. These materials include course information and handouts, lecture notes, self-paced exercises, a virtual library of electronic resources, information on newsworthy marine events, and late-breaking oceanographic research that impacts the population of California. The course format was designed to partially meet the demands of today's students, involve students in the learning process, and prepare students for using technology in work following graduation. Students have reacted favorably to the use of the WWW and comments by peers have been equally supportive. Students are more focused in their efforts during the computer-based exercises than while listening to lecture presentations. The implementation of this form of learning, however, has not, as yet, reduced the financial cost of the course or the amount of instructor effort in providing a high quality education. Interactions between the instructor and students have increased significantly as the informality of a computer laboratory promotes individual discussions and electronic communication provides students with easy (and frequent) access to the instructor outside of class.

  1. Mechanisms of cadmium induced genomic instability

    Energy Technology Data Exchange (ETDEWEB)

    Filipic, Metka, E-mail: metka.filipic@nib.si [National Institute of Biology, Department for Genetic Toxicology and Cancer Biology, Ljubljana (Slovenia)

    2012-05-01

    Cadmium is an ubiquitous environmental contaminant that represents hazard to humans and wildlife. It is found in the air, soil and water and, due to its extremely long half-life, accumulates in plants and animals. The main source of cadmium exposure for non-smoking human population is food. Cadmium is primarily toxic to the kidney, but has been also classified as carcinogenic to humans by several regulatory agencies. Current evidence suggests that exposure to cadmium induces genomic instability through complex and multifactorial mechanisms. Cadmium dose not induce direct DNA damage, however it induces increase in reactive oxygen species (ROS) formation, which in turn induce DNA damage and can also interfere with cell signalling. More important seems to be cadmium interaction with DNA repair mechanisms, cell cycle checkpoints and apoptosis as well as with epigenetic mechanisms of gene expression control. Cadmium mediated inhibition of DNA repair mechanisms and apoptosis leads to accumulation of cells with unrepaired DNA damage, which in turn increases the mutation rate and thus genomic instability. This increases the probability of developing not only cancer but also other diseases associated with genomic instability. In the in vitro experiments cadmium induced effects leading to genomic instability have been observed at low concentrations that were comparable to those observed in target organs and tissues of humans that were non-occupationally exposed to cadmium. Therefore, further studies aiming to clarify the relevance of these observations for human health risks due to cadmium exposure are needed.

  2. Investigations of effects of magnesium, zinc and copper on cadmium excretion in rabbits

    Directory of Open Access Journals (Sweden)

    Bulat Zorica

    2012-01-01

    Full Text Available Cadmium (Cd is today one of the most significant metal poisons, both in the area of professional as well as of eco toxicology. In the organism, cadmium has a harmful effect on the kidneys, liver, bones, testicles, etc., and, based on evidence in humans that it causes lung carcinoma, it has been placed in the first group of carcinogens. In spite of numerous data in literature on the harmful effects of cadmium, the interactions between cadmium and bioelements as a significant mechanism for cadmium toxicity have still not been sufficiently explained. Since the data so far point to a positive effect of supplementation with certain bioelements regarding toxicity and cadmium content in the organism, the objective of this work was to investigate the effect of increased simultaneous intake of magnesium, zinc and copper on urinary elimination of cadmium in rabbits exposed to cadmium. Rabbits were divided into two groups: Cd group - for a period of 28 days the animals received per os 10 mg Cd/kg b.m/day and Cd+(Mg+Zn+Cu group - 10 mg Cd/kg b.m. + 40 mg Mg/kg b.m, 20 mg Zn/kg b.m. and 10 mg Cu/kg b.m/day. Daily urine was collected on days 0, 10, 15, 17, 19, 21, 23, 25, and 28 of the experiment. Following decomposition of urine samples with the help of concentrated HNO3 and HClO4 (4:1, the metal concentration was determined using the method of atomic absorption spectrophotometry. Supplementation with magnesium, zinc and copper did not result in significant changes in the elimination of cadmium through urine in animals poisoned with cadmium, in comparison with the animals that were administered only cadmium, while the concentration of all three applied bioelements in urine was significantly increased. It can be concluded that the simultaneous administration of increased doses of zinc, copper and magnesium does not have a positive effect on the elimination of cadmium in conditions when rabbits are poisoned with cadmium.

  3. Using an epiphytic moss to identify previously unknown sources of atmospheric cadmium pollution

    Energy Technology Data Exchange (ETDEWEB)

    Donovan, Geoffrey H., E-mail: gdonovan@fs.fed.us [USDA Forest Service, PNW Research Station, 620 SW Main, Suite 400, Portland, OR 97205 (United States); Jovan, Sarah E., E-mail: sjovan@fs.fed.us [USDA Forest Service, PNW Research Station, 620 SW Main, Suite 400, Portland, OR 97205 (United States); Gatziolis, Demetrios, E-mail: dgatziolis@fs.fed.us [USDA Forest Service, PNW Research Station, 620 SW Main, Suite 400, Portland, OR 97205 (United States); Burstyn, Igor, E-mail: igor.burstyn@drexel.edu [Dornsife School of Public Health, Drexel University, Nesbitt Hall, 3215 Market St, Philadelphia, PA 19104 (United States); Michael, Yvonne L., E-mail: ylm23@drexel.edu [Dornsife School of Public Health, Drexel University, Nesbitt Hall, 3215 Market St, Philadelphia, PA 19104 (United States); Amacher, Michael C., E-mail: mcamacher1@outlook.com [USDA Forest Service, Logan Forest Sciences Laboratory, 860 North 1200 East, Logan, UT 84321 (United States); Monleon, Vicente J., E-mail: vjmonleon@fs.fed.us [USDA Forest Service, PNW Research Station, 3200 SW Jefferson Way, Corvallis, OR 97331 (United States)

    2016-07-15

    Urban networks of air-quality monitors are often too widely spaced to identify sources of air pollutants, especially if they do not disperse far from emission sources. The objectives of this study were to test the use of moss bio-indicators to develop a fine-scale map of atmospherically-derived cadmium and to identify the sources of cadmium in a complex urban setting. We collected 346 samples of the moss Orthotrichum lyellii from deciduous trees in December, 2013 using a modified randomized grid-based sampling strategy across Portland, Oregon. We estimated a spatial linear model of moss cadmium levels and predicted cadmium on a 50 m grid across the city. Cadmium levels in moss were positively correlated with proximity to two stained-glass manufacturers, proximity to the Oregon–Washington border, and percent industrial land in a 500 m buffer, and negatively correlated with percent residential land in a 500 m buffer. The maps showed very high concentrations of cadmium around the two stained-glass manufacturers, neither of which were known to environmental regulators as cadmium emitters. In addition, in response to our findings, the Oregon Department of Environmental Quality placed an instrumental monitor 120 m from the larger stained-glass manufacturer in October, 2015. The monthly average atmospheric cadmium concentration was 29.4 ng/m{sup 3}, which is 49 times higher than Oregon's benchmark of 0.6 ng/m{sup 3}, and high enough to pose a health risk from even short-term exposure. Both stained-glass manufacturers voluntarily stopped using cadmium after the monitoring results were made public, and the monthly average cadmium levels precipitously dropped to 1.1 ng/m{sup 3} for stained-glass manufacturer #1 and 0.67 ng/m{sup 3} for stained-glass manufacturer #2. - Highlights: • Bio-indicators are a valid method for measuring atmospheric pollutants • We used moss to map atmospheric cadmium in Portland, Oregon • Using a spatial linear model, we identified two

  4. Preconcentration of cadmium (II) using synergistic extraction with dithizone and trioctylphosphine oxide

    Energy Technology Data Exchange (ETDEWEB)

    Akaiwa, H.; Kawamoto, H.; Koizumi, T.; Schindler, P.W. (Gunma Univ., Kiryu (Japan). Faculty of Technology)

    1982-04-01

    A preconcentration method for cadmium (II) in natural water based on synergistic extraction is described. Cadmium (II) is extracted as the ternary complex Cd (II)-dithizone-TOPO (trioctylphosphine oxide) from 2.5 dm/sup 3/ of a water sample into 25 cm/sup 3/ of carbon tetrachloride and back-extracted into 10 cm/sup 3/ of 0.2 mol dm/sup -3/ nitric acid. By using this method, cadmium (II) in natural water with levels below the ppb range could be determined by flame atomic absorption spectrometry.

  5. DIOSCÓRIDES RESCATADO POR LOS ÁRABES

    Directory of Open Access Journals (Sweden)

    Ricardo H Elía

    2009-01-01

    Full Text Available La historia oficial afirma que Occidente heredó directamente el legado cultural de Grecia y Roma. Pero si la mayoría de los manuscritos griegos y latinos fueron destruidos a partir del saqueo de la Biblioteca de Alejandría en 391, los archivos de Roma fueron devastados en sendas ocasiones entre 410 y 476 por visigodos y hérulos, y los escasos vestigios clásicos que quedaban en Atenas fueron arrasados por Justiniano I en 529, ¿cuál fue la conexión que logró transmitir esa literatura y pudo ser aprovechada en un período anterior al renacimiento? La salvación de las piezas literarias se realizó durante ochocientos afios de activa y responsable tarea de recopilación por parte de los árabes durante la línea de tiempo que oscila entre 650-1450 en la que fueron rescatados, traducidos y retransmitidos hacia los cuatro puntos cardinales. Los científicos árabes, al igual que Arquímedes o Herón, nunca se separaron del saber empírico, por el contrario, lo profundizaron. El movimiento científico árabe no sólo interpretó el saber de los antiguos sino desarrolló una nueva ciencia donde la razón sustentaba a la fe y viceversa. Esta fue la base esencial que permitió construir el Renacimiento y la Ilustración, que a su vez posibilitaron la Modernidad. En este contexto, fue de capital importancia la traducción al árabe de la obra de Dioscórides ya que no sólo fue de gran utilidad para la farmacología y medicina en el mundo musulmán sino que a través de éste las recetas del médico griego de Nerón reingresaron a la Europa latina donde fueron recibidas como una panacea.Official history affirms that the West directly inherited the cultural legacy of Greece and Rome. But if most of the Greek and latin manuscripts they were destroyed at the sacking of the Library of Alexandria in 391, the archives of Rome were devastated in several occasions between 410 and 476 by Visigoth and heruls, and the little classic vestiges that were in

  6. Factors associated with dust dispersed in the air of indoor riding arenas.

    Science.gov (United States)

    Lühe, T; Mielenz, N; Schulz, J; Dreyer-Rendelsmann, C; Kemper, N

    2017-01-01

    Environmental factors contribute to respiratory diseases in horses and man. During exercise, equine ventilation is increased, potentially increasing exposure of the airways to inhaled particulates. Currently, there is very little information on the quality of air in riding arenas. To evaluate air quality and dust particle concentrations in indoor riding arenas before and after use for riding. Longitudinal study. Air quality was assessed in 4 indoor riding arenas in Saxony-Anhalt, Germany on a monthly basis for 1 year. Concentrations of particles in 6 particle fractions from 0.3 to 5.0 μm were measured in air collected at 4 points in the riding arenas approximately at the height of the horses' (1.5 m) and riders' noses (2.5 m), before and after the arenas were used by one horse performing standardised riding session. There were significant differences in the numbers of particles between the arenas within months and between months within the arenas. Particle numbers were significantly influenced by the month and activities in the arenas before and after riding. The effect of the month on differences in the dust concentration may relate to surface watering. A significant increase in numbers of particles was observed after the riding session. Significant interactions were found between measuring heights and month within arena (Parenas and this appears to be influenced by footing material, direct connections between the arena and stables and season, possibly reflecting surface watering practices. © 2015 EVJ Ltd.

  7. Official Ride Board offers Virginia Tech students easy way to carpool

    OpenAIRE

    West, Hilary

    2010-01-01

    In days past, messages were hand written on ride boards. More recently, numerous carpool pages popped up on Facebook. Now, Virginia Tech's Alternative Transportation division has launched an online ride board that will become a central location for easy carpooling among students.

  8. Computer-aided complexity classification of dial-a-ride problems

    NARCIS (Netherlands)

    de Paepe, W.E.; Lenstra, J.K.; Sgall, J.; Sitters, R.A.; Stougie, L.

    2004-01-01

    In dial-a-ride problems, items have to be transported from a source to a destination. The characteristics of the servers involved as well as the specific requirements of the rides may vary. Problems are defined on some metric space, and the goal is to find a feasible solution that minimizes a

  9. Bioaccumulation of cadmium by growing Zygosaccharomyces rouxii and Saccharomyces cerevisiae.

    Science.gov (United States)

    Li, Chunsheng; Jiang, Wei; Ma, Ning; Zhu, Yinglian; Dong, Xiaoyan; Wang, Dongfeng; Meng, Xianghong; Xu, Ying

    2014-03-01

    Bioaccumulation via growing cells is a potential technique for heavy metal removal from food materials. The cadmium bioaccumulation characteristics by growing Zygosaccharomyces rouxii and Saccharomyces cerevisiae were investigated. Z. rouxii displayed powerful cadmium removal ability at low cadmium concentrations, which mainly depended on the intracellular cadmium bioaccumulation. The percentage of intracellular cadmium bioaccumulation of both yeasts obviously decreased with the increase of initial biomass and cadmium concentrations. Low pH and elevated concentrations of zinc and copper significantly decreased the intracellular cadmium bioaccumulation of both yeasts but improved the cadmium tolerance and the cell-surface cadmium bioaccumulation of Z. rouxii. Cadmium removal of Z. rouxii was improved by zinc and copper conditionally. Z. rouxii that possessed more powerful cadmium tolerance and removal ability at low pH and high concentration of competing ions can be developed into a potential cadmium removal agent using in complex food environment in future. Copyright © 2013 Elsevier Ltd. All rights reserved.

  10. Electromyographic analysis of riding posture during the bicycling start moment

    Directory of Open Access Journals (Sweden)

    Johnny Padulo

    Full Text Available Abstract Professional cyclists often adopt a competition-start standing posture, which has been shown to improve performance. The biomechanical basis of this is unclear, and might be due to a greater mechanical advantage or increased key muscle activity. Previous observations in steady state cycling showed greater activation of the tibialis anterior, erector spinae, and biceps brachii when adopting a standing vs. seated-riding posture. Little is known regarding the effect of riding posture on activation during a standing start. Eleven cyclists performed standing starts in seated and standing-postures using stationary-cycle and on the track. Electromyography of the gastrocnemius medialis, tibialis anterior, erector spinae, and biceps brachii was recorded during first and subsequent pedal strokes. Results showed that the gastrocnemius medialis did not modify activity. The tibialis anterior, erector spinae, and biceps brachii activity was increased during the standing posture compared to seated, only during the first pedal stroke. These increased activation intensities were accompanied by a corresponding 10% increase in bike speed during the first 5 meters following a standing start in the standing posture compared to the seated one. Adopting a standing posture during a standing start improves performance through greater initial acceleration.

  11. Physiological Indicators in the Welfare Assessment of Riding Horses

    Directory of Open Access Journals (Sweden)

    Silvana Popescu

    2012-10-01

    Full Text Available The welfare assessment of horses includes the evaluation of their ability to cope with the challenges of theirenvironment and of work given to them. The aim of this study was to evaluate the welfare of 12 clinically healthyhorses from a riding school, using physiological indicators. Double determinations were made (in winter and inspring of 2011 by a set of two tests each time, before and after physical effort. The clinical parameters (heart andrespiratory rate were in the normal range at 20 minutes after effort, decreasing towards the resting values. Slightlyhigher values were recorded in the spring comparing with the winter, but the differences were not statisticallysignificant (P>0.05. Even if were in the normal range, the results of the haematology tests and the blood sugarvalues showed clearly the response of the horses’ organisms to exercise. The serum cortisol concentrations presentedan effort dependent elevation and higher values of the basic level were observed in the spring than in winter. Theother stress-response indicator recorded, the neutrophyle-lymphocyte ratio, showed dynamics correlated with that ofthe cortisol level. The physiological indicators tested in this study proved their real value in the riding horses’welfare assessment.

  12. Bioaccumulation of Cadmium and Lead in Prickly Pen Shell in Seribu Archipelago

    Directory of Open Access Journals (Sweden)

    Etty Riani

    2017-04-01

    Full Text Available Jakarta Bay waters contaminated with heavy metals, so that the waters of the Thousand Islands are also potentially contaminated with heavy metals. The purpose of this study were to determine the condition of the water quality on the Panggang Island and Karya Island, analyze contamination of heavy metals (Cadmium and Lead in water, sediments and Prickly Pen Shell and then the correlation. Based on Ministry of Environment decree No. 51/2004, water quality in the Panggang Island and Karya Island tend toward to low category. Cadmium and lead concentration in the water on October exceed the quality standards. In the sediment on July and October at Karya Island, concentration of cadmium were exceed the quality standar by RNO. On the other hand, cadmium and lead concentration on Prickly Pen Shell still below standard quality from decree of Director General of POM RI No. 03725. We found highest positive correlation were found between cadmium and lead accumulation in the water and on the Prickly Pen Shell, then positive correlation between cadmium and lead in the water and in the sediment. For the heavy metal contamination, we found contamination of cadmium correlation were higher than lead contamination.

  13. Cadmium content of plants as affected by soil cadmium concentration

    Energy Technology Data Exchange (ETDEWEB)

    Lehoczky, E. [Pannon Univ. of Agricultural Sciences, Keszthely (Hungary); Szabados, I.; Marth, P. [Plant Health and Soil Conservation Station, Higany (Hungary)

    1996-12-31

    Pot experiments were conducted in greenhouse conditions to study the effects of increasing cadmium (Cd) levels on biomass production and Cd contents in corn, (Zea mays L.), garlic (Allium sativum L.), and spinach (Spinacia oleracea L.). Plants were grown in two soil types: Eutric cambisol soil and A gleyic luvisol soil. Spinach proved to be the most sensitive to Cd treatments as its biomass considerably decreased with the increasing Cd levels. Cadmium contents of the three crops increased with increasing levels of Cd applications. Statistical differences were observed in the Cd contents of crops depending on soil type. With the same Cd rates, Cd tissue concentration of test plants grown in the strongly acidic Gleyic luvisol soil were many times higher than that of plants grown in a neutral Eutric cambisol soil. 14 refs., 4 tabs.

  14. Study on the ride comfort of vehicles driven by in-wheel motors

    Directory of Open Access Journals (Sweden)

    Liqiang Jin

    2016-02-01

    Full Text Available Vehicles driven by in-wheel motors have received more and more attention. However, due to the introduction of in-wheel motors, the ratio between unsprung and sprung mass is increased. In this article, to study the influence of this change on ride comfort of vehicles driven by in-wheel motors, an 11 degrees of freedom of vehicle ride comfort model will be presented and studied with MATLAB/Simulink. Then, road tests will be conducted to corroborate the simulation results. It can be obtained that the vehicle ride comfort becomes poor with the increasing unsprung mass. Finally, semi-active air-suspension proportional–integral–derivative control system will be proposed to improve the vehicle ride comfort. Through the simulation results, one can come to a conclusion that the proportional–integral–derivative control system for air suspension is feasible and effective to improve the ride comfort of the vehicles driven by in-wheel motors.

  15. Cadmium and Cadmium/Zinc Ratios and Tobacco-Related Morbidities

    Science.gov (United States)

    Richter, Patricia; Faroon, Obaid; Pappas, R. Steven

    2017-01-01

    Metals are one of five major categories of carcinogenic or toxic constituents in tobacco and tobacco smoke. Cadmium is highly volatile and a higher percentage of the total tobacco cadmium content is efficiently transferred to mainstream tobacco smoke than many other toxic metals in tobacco. Inhaled cadmium bioaccumulates in the lungs and is distributed beyond the lungs to other tissues, with a total body biological half-life of one to two decades. Chronic cadmium exposure through tobacco use elevates blood and urine cadmium concentrations. Cadmium is a carcinogen, and an inducer of proinflammatory immune responses. Elevated exposure to cadmium is associated with reduced pulmonary function, obstructive lung disease, bronchogenic carcinoma, cardiovascular diseases including myocardial infarction, peripheral arterial disease, prostate cancer, cervical cancer, pancreatic cancer, and various oral pathologies. Cadmium and zinc have a toxicologically inverse relationship. Zinc is an essential element and is reportedly antagonistic to some manifestations of cadmium toxicity. This review summarizes associations between blood, urine, and tissue cadmium concentrations with emphasis on cadmium exposure due to tobacco use and several disease states. Available data about zinc and cadmium/zinc ratios and tobacco-related diseases is summarized from studies reporting smoking status. Collectively, data suggest that blood, urine, and tissue cadmium and cadmium/zinc ratios are often significantly different between smokers and nonsmokers and they are also different in smokers for several diseases and cancers. Additional biomonitoring data such as blood or serum and urine zinc and cadmium levels and cadmium/zinc ratios in smokers may provide further insight into the development and progression of diseases of the lung, cardiovascular system, and possibly other organs. PMID:28961214

  16. Cadmium and Cadmium/Zinc Ratios and Tobacco-Related Morbidities.

    Science.gov (United States)

    Richter, Patricia; Faroon, Obaid; Pappas, R Steven

    2017-09-29

    Metals are one of five major categories of carcinogenic or toxic constituents in tobacco and tobacco smoke. Cadmium is highly volatile and a higher percentage of the total tobacco cadmium content is efficiently transferred to mainstream tobacco smoke than many other toxic metals in tobacco. Inhaled cadmium bioaccumulates in the lungs and is distributed beyond the lungs to other tissues, with a total body biological half-life of one to two decades. Chronic cadmium exposure through tobacco use elevates blood and urine cadmium concentrations. Cadmium is a carcinogen, and an inducer of proinflammatory immune responses. Elevated exposure to cadmium is associated with reduced pulmonary function, obstructive lung disease, bronchogenic carcinoma, cardiovascular diseases including myocardial infarction, peripheral arterial disease, prostate cancer, cervical cancer, pancreatic cancer, and various oral pathologies. Cadmium and zinc have a toxicologically inverse relationship. Zinc is an essential element and is reportedly antagonistic to some manifestations of cadmium toxicity. This review summarizes associations between blood, urine, and tissue cadmium concentrations with emphasis on cadmium exposure due to tobacco use and several disease states. Available data about zinc and cadmium/zinc ratios and tobacco-related diseases is summarized from studies reporting smoking status. Collectively, data suggest that blood, urine, and tissue cadmium and cadmium/zinc ratios are often significantly different between smokers and nonsmokers and they are also different in smokers for several diseases and cancers. Additional biomonitoring data such as blood or serum and urine zinc and cadmium levels and cadmium/zinc ratios in smokers may provide further insight into the development and progression of diseases of the lung, cardiovascular system, and possibly other organs.

  17. Cadmium and Cadmium/Zinc Ratios and Tobacco-Related Morbidities

    Directory of Open Access Journals (Sweden)

    Patricia Richter

    2017-09-01

    Full Text Available Metals are one of five major categories of carcinogenic or toxic constituents in tobacco and tobacco smoke. Cadmium is highly volatile and a higher percentage of the total tobacco cadmium content is efficiently transferred to mainstream tobacco smoke than many other toxic metals in tobacco. Inhaled cadmium bioaccumulates in the lungs and is distributed beyond the lungs to other tissues, with a total body biological half-life of one to two decades. Chronic cadmium exposure through tobacco use elevates blood and urine cadmium concentrations. Cadmium is a carcinogen, and an inducer of proinflammatory immune responses. Elevated exposure to cadmium is associated with reduced pulmonary function, obstructive lung disease, bronchogenic carcinoma, cardiovascular diseases including myocardial infarction, peripheral arterial disease, prostate cancer, cervical cancer, pancreatic cancer, and various oral pathologies. Cadmium and zinc have a toxicologically inverse relationship. Zinc is an essential element and is reportedly antagonistic to some manifestations of cadmium toxicity. This review summarizes associations between blood, urine, and tissue cadmium concentrations with emphasis on cadmium exposure due to tobacco use and several disease states. Available data about zinc and cadmium/zinc ratios and tobacco-related diseases is summarized from studies reporting smoking status. Collectively, data suggest that blood, urine, and tissue cadmium and cadmium/zinc ratios are often significantly different between smokers and nonsmokers and they are also different in smokers for several diseases and cancers. Additional biomonitoring data such as blood or serum and urine zinc and cadmium levels and cadmium/zinc ratios in smokers may provide further insight into the development and progression of diseases of the lung, cardiovascular system, and possibly other organs.

  18. Relations between liver cadmium, cumulative exposure, and renal function in cadmium alloy workers.

    OpenAIRE

    Mason, H. J.; Davison, A G; Wright, A. L.; Guthrie, C J; Fayers, P M; Venables, K M; Smith, N J; Chettle, D R; Franklin, D M; Scott, M. C.

    1988-01-01

    Detailed biochemical investigations of renal function were made on 75 male workers exposed to cadmium and an equal number of referents matched for age, sex, and employment status. The exposed group consisted of current and retired workers who had been employed in the manufacture of copper-cadmium alloy at a single factory in the United Kingdom for periods of up to 39 years and for whom cumulative cadmium exposure indices could be calculated. In vivo measurements of liver and kidney cadmium bu...

  19. [Predicting the cadmium bioavailability in the soil of sugarcane field based on the diffusive gradients in thin films with binding phase of sodium polyacrylate].

    Science.gov (United States)

    Wang, Fang-Li; Song, Ning-Ning; Zhao, Yu-Jie; Zhang, Chang-Bo; Shen, Yue; Liu, Zhong-Qi

    2012-10-01

    The diffusive gradients in thin films (DGT) technique with solid-state binding phases has been widely used for in situ collection and measurement of available heavy metals in waters, soils or sediments, whereas DGT with liquid binding phase is primarily used in the in situ analysis of heavy metals in waters. In this paper, rhizosphere soils of sugarcane were collected in Guangxi and the concentrations of cadmium (Cd) were determined by DGT with a solid-state binding phase of chelex100 (chelex100-DGT) and modified DGT with a liquid binding phase of sodium polyacrylate (CDM-PAAS-DGT). The result showed that the Cd contents in soils measured by DGT with both binding phases and Cd in the roots, leaves and unpolished stems of sugarcane had significant positive correlation. The extraction ability of the CDM-PAAAS-DGT was much higher than that of the chelex100-DGT. In addition, multivariate analyses were used to assess the impact of pH, cation exchange capacity (CEC), soil organic matter (OM) and texture. Two principal components were extracted and the linear regression models were established. The Cd bioavailability in soils could be accurately predicted by the CDM-PAAAS-DGT technique, which expanded its applicable area.

  20. [Impact of therapeutic riding on gait and posture regulation].

    Science.gov (United States)

    Schwesig, R; Neumann, S; Richter, D; Kauert, R; Becker, S; Esperer, H D; Leuchte, S

    2009-06-01

    Hippotherapy has become an important therapeutic option in patients suffering from motoric dysfunction. The physiologic basis of this approach is the three-dimensional transmission of the horse's motion onto the patients body. These motion stimuli are believed to exert possitve effects on the patients's postural control systems. To test the hypothesis that hippotherapy has both positive short- and lang-term effects on gait and posture control of persons suffering from motoric disabilities. Twenty-two children and adolescents aged 9.69 +/- 4.01 years (range: 9.69 +/- 4.01 years) with motoric dysfunctions were included in a prospective matched control study. In each participant, gait and posture control were investigated on four different occasions (O1 - O4) using the Interactive balance system (IBS; Tetrax Inc., Ramat Gan, Israel) and the portable gait analysis sytem RehaWatch (Hasomed, Magdeburg, Germany). The dates of gait and posture analysis were defined as follows: O 1: immediately prior to first therapeutic riding session (TRS); O 2: immediately after first TRS; O 3: after the last day of an eight weeks period of daily TRS; O 4: seven weeks later after a TRS free interval. The following parameters were slightly improved (adjusted significance level of p < 0.003) after eight weeks of therapeutic riding: (O1 vs. O 3): (1) walking distance (p = 0.009, eta(2) = 0.339); (2) pace frequency (p = 0.007, eta(2) = 0.358); (3) walking speed (p = 0.006, eta(2) = 0.367), and (4) time of attachment (p = 0.007, eta(2) = 0.360). The only short-term effect observed was a significant decrease of the attachment phase (p = 0.002, eta(2) = 0.387). Interestingly, gait symmetry remained unaffected. Posturography (adjusted significance level of p < 0.01) at O 1 versus O 2 (short-term) showed a significant decrease of the performance of both the visual-nigrostriatal subsystem (p < 0.001) and the somato-sensory subsystem (p = 0.001). At O 1 versus O 3 (long-term), the following

  1. Cadmium resistance in Drosophila: a small cadmium binding substance

    Energy Technology Data Exchange (ETDEWEB)

    Jacobson, K.B.; Williams, M.W.; Richter, L.J.; Holt, S.E.; Hook, G.J.; Knoop, S.M.; Sloop, F.V.; Faust, J.B.

    1985-01-01

    A small cadmium-binding substance (CdBS) has been observed in adult Drosophila melanogaster that were raised for their entire growth cycle on a diet that contained 0.15 mM CdCl/sub 2/. Induction of CdBS was observed in strains that differed widely in their sensitivity of CdCl/sub 2/. This report describes the induction of CdBS and some of its characteristics. 17 refs., 4 figs., 1 tab.

  2. [Effects of cadmium on testis function].

    Science.gov (United States)

    Martynowicz, Helena; Skoczyńska, Anna; Karczmarek-Wdowiak, Beata; Andrzejak, Ryszard

    2005-01-01

    The deterioration of male fertility, reported in numerous epidemiological studies over past decades, can be connected with growing exposure to environmental toxins. Heavy metals, especially cadmium, is widely spread and extremely toxic. The mechanisms of cadmium toxic effects vary and involve the damage of vascular endothelium, intracellular junctions, germ cells, Leydig and Sertoli cells. Cadmium can increase activity of reactive oxygen species and induce changes in activity of enzymatic systems and inflammatory reactions. The morphological changes caused by cadmium included the necrosis of seminiferous tubiles and interstitial edema. This metal can reduce testosterone synthesis at various levels and deteriorate spermatogenesis. Cadmium is also acknowledged carcinogen with confirmed mutagenic and genotoxic activity. Increasing environmental exposure to cadmium, currently existing occupational exposure and the prevalence of tobacco smoking results in constant increase in the number of diagnosed fertility impairments.

  3. Improving Low Voltage Ride Through Capability of Wind Generators Using Dynamic Voltage Restorer

    Science.gov (United States)

    Sivasankar, Gangatharan; Suresh Kumar, Velu

    2014-08-01

    The increasing wind power integration with power grid has forced the situation to improve the reliability of wind generators for stable operation. One important problem with induction generator based wind farm is its low ride through capability to the grid voltage disturbance. Any disturbance such as voltage dip may cause wind farm outages. Since wind power contribution is in predominant percentage, such outages may lead to stability problem. The proposed strategy is to use dynamic voltage controller (DVR) to compensate the voltage disturbance. The DVR provides the wind generator the ability to remain connected in grid and improve the reliability. The voltage dips due to symmetrical and unsymmetrical faults are considered for analysis. The vector control scheme is employed for fault compensation which uses software phase locked loop scheme and park dq0 transformation technique. Extensive simulation results are included to illustrate the control and operation of DVR.

  4. Internal balance during low-voltage-ride-through of the modular multilevel converter statcom

    DEFF Research Database (Denmark)

    Tsolaridis, Georgios; Kontos, Epameinondas; Chaudhary, Sanjay K.

    2017-01-01

    Grid faults are common in power systems and can have a severe impact on the operation of the converters in the system. In this paper, the operation of a Modular Multilevel Converter (MMC)-based Static Synchronous Compensators (STATCOM) is investigated during grid faults. The study focuses...... on the challenging internal control of the converter to allow the independent control of the energy levels of each arm, with the goal to maintain internal balancing of the MMC during contingencies. Extensive experimental results highlight the need for a sophisticated internal control. Moreover, the experimental...... analysis verifies that, by using the proposed control structure, the MMC can effectively ride through a fault on the AC side without tripping, while injecting the necessary positive and negative sequence reactive current levels according to the most recent grid codes....

  5. Voltage Sags Ride-Through of Motion Sensorless Controlled PMSG for Wind Turbines

    DEFF Research Database (Denmark)

    Fatu, Marius; Lascu, Cristian; Andreescu, Gheorghe-Daniel

    2007-01-01

    is used to robustly estimate the grid voltage positivesequence for control in the case of asymmetric voltages. The paper investigates the ride-through performance of this system during asymmetric power grid voltage sags. Design details for various parts of the control system are presented, together...... with experimental results for single-, two-, and three-phase voltage source sags. Smooth transition through asymmetric voltage sags is demonstrated by all experiments........ The control system employs PI current controllers with crosscoupling decoupling for both inverters, an active power controller, and a DC link voltage controller. The PMSG rotor speed without using emf integration, and the line voltage frequency are estimated by two PLL based observers. A Dmodule filter...

  6. Advanced Control Strategy of DFIG Wind Turbines for Power System Fault Ride Through

    DEFF Research Database (Denmark)

    Yang, Lihui; Xu, Zhao; Ostergaard, Jacob

    2012-01-01

    This paper presents an advanced control strategy for the rotor and grid side converters of the doubly fed induction generator (DFIG) based wind turbine (WT) to enhance the low-voltage ride-through (LVRT) capability according to the grid connection requirement. Within the new control strategy...... the instantaneous DC-link current of the rotor side converter in order to smooth the DC-link voltage fluctuations during the grid fault. A major difference from other methods is that the proposed control strategy can absorb the additional kinetic energy during the fault conditions, and significantly reduce...... the oscillations in the stator and rotor currents and the DC bus voltage. The effectiveness of the proposed control strategy has been demonstrated through various simulation cases. Compared with conventional crowbar protection, the proposed control method can not only improve the LVRT capability of the DFIG WT...

  7. A Current Limiting Strategy to Improve Fault Ride-Through of Inverter Interfaced Autonomous Microgrids

    DEFF Research Database (Denmark)

    Sadeghkhani, Iman; Esmail Hamedani Golshan, Mohamad; Guerrero, Josep M.

    2017-01-01

    With high penetration of distributed energy resources (DER), fault management strategy is of great importance for the distribution network operation. The objective of this paper is to propose a current and voltage limiting strategy to enhance fault ride-through (FRT) capability of inverter......-based islanded microgrids (MGs) in which the effects of inverter control system and inverter topology (four/three-wire) are considered. A threephase voltage-sourced inverter (VSI) with multi-loop control system implemented in synchronous, stationary, and natural reference frames is employed in this study...... for both four- and three-wire configurations. The proposed strategy provides high voltage and current quality during overcurrent conditions, which is necessary for sensitive loads. Several time-domain simulation studies are conducted to investigate the FRT capability of the proposed strategy against both...

  8. Production of high purity granular metals: cadmium, zinc, lead

    Directory of Open Access Journals (Sweden)

    Shcherban A. P.

    2017-04-01

    Full Text Available Cadmium, zinc and lead are constituent components of many semiconductor compounds. The obtained high purity distillates and ingots are large-size elements, which is not always convenient to use, and thus require additional grinding, which does not always allow maintaining the purity of the original materials. For the growth of semiconductor and scintillation single crystals it is advisable to use "friable" granular high-purity distillates, which can be processed without the risk of contamination. For example, the European low-background experiment LUCIFER required more than 20 kg of high-purity granulated zinc, which was agreed to be supplied by NSC KIPT. This task was then extended to cadmium and lead. Motivated by these tasks, the authors of this paper propose complex processes of deep refining of cadmium, zinc and lead by vacuum distillation. A device producing granules has been developed. The process of granulation of high-purity metals is explored. The purity of produced granules for cadmium and zinc is >99,9999, and >99,9995% for lead granules. To prevent oxidation of metal granules during exposition to air, chemical methods of surface passivation were used. Organic solvent based on dimethylformamide used as a coolant improves the resistance of granules to atmospheric corrosion during the granulation of high purity Cd, Zn and Pb.

  9. Impact of cadmium on the ecdysteroids production in Gammarus fossarum.

    Science.gov (United States)

    Abidi, Sondes; Abbaci, Khedidja Tair; Geffard, Olivier; Boumaiza, Moncef; Dumet, Adeline; Garric, Jeanne; Mondy, Nathalie

    2016-07-01

    Gammarus fossarum is an important test organism which is currently used as a bio-indicator as well as in ecotoxicological tests. Nevertheless, data on ecdysteroids in endocrine toxicity test are not yet available for these species, despite its crucial role in molting and reproduction. In the present paper, ecdysteroids concentrations were studied during the molt cycle (in females) and embryonic development in G. fossarum (Crustacea, Amphipoda) in order to propose an ecdysteroids toxicity test. Ecdysteroids levels in G. fossarum showed a single peak during premolt at stage Dl-D2. In embryos, ecdysteroids levels progressively increased over stages 3 and 4, with peak levels at stage 4. A Cadmium toxicity test was proposed to examine if the molting and embryogenesis disturbances previously observed after cadmium exposure (Geffard et al. 2010) could be attributed to changes in ecdysteroids titers. Exposure to the different cadmium concentrations (3; 9; 300; 900 µg/l) increased ecdysteroids secretion by Y-organs in vitro, but it had no significant effect on exposed embryos (in vivo). Based on previous findings, we are led to conclude that the molting impairments in cadmium-exposed females of G. fossarum is connected to the changes in ecdysteroids concentrations.

  10. Metaheuristics for the dynamic stochastic dial-a-ride problem with expected return transports.

    Science.gov (United States)

    Schilde, M; Doerner, K F; Hartl, R F

    2011-12-01

    The problem of transporting patients or elderly people has been widely studied in literature and is usually modeled as a dial-a-ride problem (DARP). In this paper we analyze the corresponding problem arising in the daily operation of the Austrian Red Cross. This nongovernmental organization is the largest organization performing patient transportation in Austria. The aim is to design vehicle routes to serve partially dynamic transportation requests using a fixed vehicle fleet. Each request requires transportation from a patient's home location to a hospital (outbound request) or back home from the hospital (inbound request). Some of these requests are known in advance. Some requests are dynamic in the sense that they appear during the day without any prior information. Finally, some inbound requests are stochastic. More precisely, with a certain probability each outbound request causes a corresponding inbound request on the same day. Some stochastic information about these return transports is available from historical data. The purpose of this study is to investigate, whether using this information in designing the routes has a significant positive effect on the solution quality. The problem is modeled as a dynamic stochastic dial-a-ride problem with expected return transports. We propose four different modifications of metaheuristic solution approaches for this problem. In detail, we test dynamic versions of variable neighborhood search (VNS) and stochastic VNS (S-VNS) as well as modified versions of the multiple plan approach (MPA) and the multiple scenario approach (MSA). Tests are performed using 12 sets of test instances based on a real road network. Various demand scenarios are generated based on the available real data. Results show that using the stochastic information on return transports leads to average improvements of around 15%. Moreover, improvements of up to 41% can be achieved for some test instances.

  11. Metaheuristics for the dynamic stochastic dial-a-ride problem with expected return transports

    Science.gov (United States)

    Schilde, M.; Doerner, K.F.; Hartl, R.F.

    2011-01-01

    The problem of transporting patients or elderly people has been widely studied in literature and is usually modeled as a dial-a-ride problem (DARP). In this paper we analyze the corresponding problem arising in the daily operation of the Austrian Red Cross. This nongovernmental organization is the largest organization performing patient transportation in Austria. The aim is to design vehicle routes to serve partially dynamic transportation requests using a fixed vehicle fleet. Each request requires transportation from a patient's home location to a hospital (outbound request) or back home from the hospital (inbound request). Some of these requests are known in advance. Some requests are dynamic in the sense that they appear during the day without any prior information. Finally, some inbound requests are stochastic. More precisely, with a certain probability each outbound request causes a corresponding inbound request on the same day. Some stochastic information about these return transports is available from historical data. The purpose of this study is to investigate, whether using this information in designing the routes has a significant positive effect on the solution quality. The problem is modeled as a dynamic stochastic dial-a-ride problem with expected return transports. We propose four different modifications of metaheuristic solution approaches for this problem. In detail, we test dynamic versions of variable neighborhood search (VNS) and stochastic VNS (S-VNS) as well as modified versions of the multiple plan approach (MPA) and the multiple scenario approach (MSA). Tests are performed using 12 sets of test instances based on a real road network. Various demand scenarios are generated based on the available real data. Results show that using the stochastic information on return transports leads to average improvements of around 15%. Moreover, improvements of up to 41% can be achieved for some test instances. PMID:23543641

  12. Effect of Cadmium on the population growth of the marine diatom Chaetoceros gracilis Schutt

    Directory of Open Access Journals (Sweden)

    Giovana Vera

    2014-06-01

    Full Text Available Phytoplankton constitutes the base of the trophic webs in the marine environment, so it is important to know the possible effects of pollutants on the algal populations. In the present paper the effect of cadmium on the population growth of the diatom Chaetoceros gracilis was assessed. The microalgae were cultured in the a modified “f/2” Guillard medium, and were exposed to different concentrations of cadmium between 50 and 100000 µg.–1, which produced an inhibitory effect from 20% to 99% on the population growth of Chaetoceros gracilis. Based on the dose (cadmium-response (inhibition relationship, a mean effective concentration (EC50% equal to 591 µg.L–1 of cadmium was obtained.

  13. Electrodialytic Removal of Cadmium from Straw Ash

    DEFF Research Database (Denmark)

    Hansen, Henrik; Ottosen, Lisbeth M.; Villumsen, Arne

    1999-01-01

    A problem with flyash from straw and wood combustion is the high level of heavy metals, especially cadmium. Two electrodialytic remediation experiments were carried out on cadmium polluted flyash from straw combustion. The flyash could be cleaned to 1/3 of its initial level after 24 days of remed......A problem with flyash from straw and wood combustion is the high level of heavy metals, especially cadmium. Two electrodialytic remediation experiments were carried out on cadmium polluted flyash from straw combustion. The flyash could be cleaned to 1/3 of its initial level after 24 days...

  14. Interplay of calcium and cadmium in mediating cadmium toxicity.

    Science.gov (United States)

    Choong, Grace; Liu, Ying; Templeton, Douglas M

    2014-03-25

    The environmentally important toxic metal, cadmium, exists as the Cd(2+) ion in biological systems, and in this state structurally resembles Ca(2+). Thus, although cadmium exerts a broad range of adverse actions on cells by virtue of its propensity to bind to protein thiol groups, it is now well appreciated that Cd(2+) participates in a number of Ca(2+)-dependent pathways, attributable to its actions as a Ca(2+) mimetic, with a central role for calmodulin, and the Ca(2+)/calmodlin-dependent protein kinase II (CaMK-II) that mediates effects on cytoskeletal dynamics and apoptotic cell death. Cadmium interacts with receptors and ion channels on the cell surface, and with the intracellular estrogen receptor where it binds competitively to residues shared by Ca(2+). It increases cytosolic [Ca(2+)] through several mechanisms, but also decreases transcript levels of some Ca(2+)-transporter genes. It initiates mitochondrial apoptotic pathways, and activates calpains, contributing to mitochondria-independent apoptosis. However, the recent discovery of the role CaMK-II plays in Cd(2+)-induced cell death, and subsequent implication of CaMK-II in Cd(2+)-dependent alterations of cytoskeletal dynamics, has opened a new area of mechanistic cadmium toxicology that is a focus of this review. Calmodulin is necessary for induction of apoptosis by several agents, yet induction of apoptosis by Cd(2+) is prevented by CaMK-II block, and Ca(2+)-dependent phosphorylation of CaMK-II has been linked to increased Cd(2+)-dependent apoptosis. Calmodulin antagonism suppresses Cd(2+)-induced phosphorylation of Erk1/2 and the Akt survival pathway. The involvement of CaMK-II in the effects of Cd(2+) on cell morphology, and particularly the actin cytoskeleton, is profound, favouring actin depolymerization, disrupting focal adhesions, and directing phosphorylated FAK into a cellular membrane. CaMK-II is also implicated in effects of Cd(2+) on microtubules and cadherin junctions. A key question for

  15. Electroanalytical studies on cadmium(II) selective potentiometric sensors based on t-butyl thiacalix[4]arene and thiacalix[4]arene in poly(vinyl chloride)

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, Vinod K. [Department of Chemistry, Indian Institute of Technology, Roorkee 247667, Uttaranchal (India)], E-mail: vinodfcy@iitr.ernet.in; Jain, Ajay K. [Department of Chemistry, Indian Institute of Technology, Roorkee 247667, Uttaranchal (India); Ludwig, Rainer [Institute for Inorganic and Analytical Chemistry, Freie Universitaet, Berlin 14195 (Germany); Maheshwari, Gaurav [Department of Chemistry, Indian Institute of Technology, Roorkee 247667, Uttaranchal (India)

    2008-01-01

    Cd{sup 2+}-selective sensors have been fabricated from poly(vinyl chloride) (PVC) matrix membranes containing t-butyl thiacalix[4]arene (I) and thiacalix[4]arene (II) as electroactive materials. The addition of sodium tetraphenylborate and the plasticizer 2-nitrophenyl octyl ether has been found to improve the performance of the sensors substantially. The membranes of various compositions of the two thiacalixarenes have been investigated and it was found that the best performance was obtained for the membrane of composition II:PVC:NaTPB:NPOE in the ratio 5:120:3:150. The sensor shows a linear potential response for Cd{sup 2+} over a wide activity range 3.2 x 10{sup -6} to 1.0 x 10{sup -1} M with Nernstian compliance (29.5 mV decade{sup -1} of activity) in pH range 4.5-6.5 and a fast response time of {approx}8 s. The potentiometric selectivity coefficient values determined by matched potential method indicate excellent selectivity for Cd{sup 2+} ions over mono-, di- and trivalent interfering cations. The sensor exhibits adequate shelf life ({approx}3 months) with good reproducibility (S.D. {+-}0.2 mV) and can also be used in partially non-aqueous media having up to 20% (v/v) methanol, ethanol or acetone content with no significant change in the value of slope or working activity range. The sensor has been used in the potentiometric titration of Cd{sup 2+} with EDTA. The sensor could be successfully used for the quantification of cadmium in river water samples.

  16. Recent developments in cadmium mercury telluride infrared detectors

    Science.gov (United States)

    Charlton, D. E.

    1982-09-01

    A II-VI compound, cadmium mercury telluride, has dominated recent advances in the detection of infrared radiation. Although the main application is in thermal imaging, other applications include instrumentation and guidance. In this paper we describe the history of the development of cadmium mercury telluride as a detector material, with emphasis on the importance of material parameters and the role of the material scientist. High purity material, free from defects and of good crystal quality, is needed in order to ensure good minority carrier lifetime. Because of the segregation of impurities during solidification, material produced by the Bridgman technique offers considerable advantages over material produced by cast recrystallize techniques. Detectors based on a principle established by C.T. Elliott of the RSRE, Malvern, have led to families of thermal imagers that produce near perfect imagery. These detectors incorporate signal processing in the element by providing the time delay and integration functions that are normally performed off the focal plane in conventional serial scanned systems. A particular requirement of these SPRITE detectors is for long minority carrier lifetime. This has called for improvements in both material and fabrication technology which have led to an advanced technology that has benefited all aspects of the manufacture of cadmium mercury telluride detectors. Near background limited performance will be described in both the 8-14 and the 3-5 μm atmospheric transmission bands. There is, however, more image blurring in the 3-5 μm band than occurs in the 8-14 μm band. The direction of present work is towards detectors combining cadmium mercury telluride elements with advanced integrated circuits to provide more complex signal processing in the focal plane. This has been driven by the need to improve the sensitivity of thermal imaging systems where the scan rates are too low to allow useful time delay and integration in SPRITE detectors

  17. Toxic effects of nanomaterial-adsorbed cadmium on Daphnia magna.

    Science.gov (United States)

    Gao, Minling; Zhang, Ze; Lv, Mengting; Song, Wenhua; Lv, Yuhua

    2018-02-01

    Chemical immobilization technologies involving the use of chemical absorbents such as nanomaterials have been recommended for the remediation of Cd-contaminated water and soil. The impact of nanomaterials or nanomaterials coexisting with other contaminants on aquatic organisms has been reported, but information on the toxic effects of nanomaterial-adsorbed cadmium (Nano-Cd) on aquatic organisms is lacking. This study aimed to investigate the acute and sub-acute toxicity of Nano-Cd on Daphnia magna by using a method developed based on the standard Organisation for Economic Co-operation and Development (OECD) 202 guidelines. The toxicity of cadmium chloride (Cd 2+ ), nano-manganese dioxide-cadmium (nMnO 2 -Cd), 20nm nano-hydroxyapatite-cadmium (nHAP 20 -Cd), and 40nm nano-hydroxyapatite-cadmium (nHAP 40 -Cd) to D. magna was in the following order: Cd 2+ > nMnO 2 -Cd > nHAP 20 -Cd > nHAP 40 -Cd. Further, nMnO 2 -Cd, nHAP 20 -Cd, and nHAP 40 -Cd showed acute toxicity to D. magna of level II grade according to the Commission of the European Communities and OECD standards. Exposure to low and medium, but not high, Nano-Cd concentrations increased the activities of peroxidase, superoxide dismutase, catalase, and anti-superoxide anion. Thus, Nano-Cd, particularly at high concentrations, could exert oxidative damage in D. magna. An increase in Cd 2+ and Nano-Cd concentrations gradually increased the malondialdehyde content, indicating cell membrane damage caused by the production of excessive O 2 - . Thus, the use of nanomaterials after adsorption of Cd is associated with a potential risk to aquatic organisms. Copyright © 2017 Elsevier Inc. All rights reserved.

  18. Human pelvis motions when walking and when riding a therapeutic horse.

    Science.gov (United States)

    Garner, Brian A; Rigby, B Rhett

    2015-02-01

    A prevailing rationale for equine assisted therapies is that the motion of a horse can provide sensory stimulus and movement patterns that mimic those of natural human activities such as walking. The purpose of this study was to quantitatively measure and compare human pelvis motions when walking to those when riding a horse. Six able-bodied children (inexperienced riders, 8-12years old) participated in over-ground trials of self-paced walking and leader-paced riding on four different horses. Five kinematic measures were extracted from three-dimensional pelvis motion data: anteroposterior, superoinferior, and mediolateral translations, list angle about the anteroposterior axis, and twist angle about the superoinferior axis. There was generally as much or more variability in motion range observed between riding on the different horses as between riding and walking. Pelvis trajectories exhibited many similar features between walking and riding, including distorted lemniscate patterns in the transverse and frontal planes. In the sagittal plane the pelvis trajectory during walking exhibited a somewhat circular pattern whereas during riding it exhibited a more diagonal pattern. This study shows that riding on a horse can generate movement patterns in the human pelvis that emulate many, but not all, characteristics of those during natural walking. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. Riding the waves of culture understanding cultural diversity in business

    CERN Document Server

    Trompenaars, Fons

    1993-01-01

    The definitive guide to cross-cultural management--updated to help you lead effectively during a time of unprecedented globalization First published nearly 20 years ago, Riding the Waves of Culture became the standard guide to conducting business in an international context. Now, the third edition provides you with important new information and groundbreaking methods for leading effectively in the most globalized business landscape ever. Fons Trompenaars is a world expert on international management and founder and director of Trompenaars Hampden-Turner (THT), a consulting firm in the field of intercultural management. Charles Hampden-Turner is a Senior Research Associate at the Judge Business School at the University of Cambridge and cofounder and Director of Research and Development at the Trompenaars-Hampden-Turner Group.

  20. Detecting Triple-Vessel Disease with Cadmium Zinc Telluride-Based Single-Photon Emission Computed Tomography Using the Intensity Signal-to-Noise Ratio between Rest and Stress Studies

    Directory of Open Access Journals (Sweden)

    Yu-Hua Dean Fang

    2017-01-01

    Full Text Available The purpose of this study was to investigate if a novel parameter, the stress-to-rest ratio of the signal-to-noise ratio (RSNR obtained with a cadmium zinc telluride (CZT SPECT scanner, could be used to distinguish triple-vessel disease (TVD patients. Methods. One hundred and two patients with suspected coronary artery disease were retrospectively involved. Each subject underwent a Tl-201 SPECT scan and subsequent coronary angiography. Subjects were separated into TVD (n=41 and control (n=61 groups based on coronary angiography results using 50% as the stenosis cutoff. The RSNR was calculated by dividing the stress signal-to-noise ratio (SNR by the rest SNR. Summed scores were calculated using quantitative perfusion SPECT (QPS for all subjects. Results. The RSNR in the TVD group was found to be significantly lower than that in the control group (0.83 ± 0.15 and 1.06 ± 0.17, resp.; P<0.01. Receiver-operating characteristic (ROC analysis showed that RSNR can detect TVD more accurately than the summed difference score with higher sensitivity (85% versus 68%, higher specificity (90% versus 72%, and higher accuracy (88% versus 71%. Conclusion. The RSNR may serve as a useful index to assist the diagnosis of TVD when a fully automatic quantification method is used in CZT-based SPECT studies.

  1. Classification and management of the postoperative, high-riding nipple.

    Science.gov (United States)

    Spear, Scott L; Albino, Frank P; Al-Attar, Ali

    2013-06-01

    Postoperative nipple malposition can be an aesthetically devastating problem for patients and a formidable challenge for surgeons. The authors' aim was to identify the common antecedent events leading to high-riding nipples, provide a classification system for these problems, and discuss management. A retrospective review of medical records was conducted for patients who presented to the senior surgeon (S.L.S.) for management of a postoperative, excessively high nipple-areola complex over an 8-year period from January of 2004 to March of 2012. Demographic information, medical histories, operative details, and office records were reviewed for each patient. The high nipple-areola complex was classified as mild, moderate, or severe depending on the distance from the superior breast border to the top of the nipple-areola complex in relation to the vertical breast height. Twenty-five women met study criteria, with 41 breasts determined to have an excessively high nipple-areola complex. The average patient was aged 44.3 years and had undergone 2.5±1.3 operations before the development of a notably high nipple-areola complex, including nipple-sparing mastectomy (32 percent), augmentation/mastopexy (29 percent), augmentation (27 percent), mastopexy (10 percent), and skin-sparing mastectomy with nipple reconstruction (2 percent). Patients were classified as having mild (27 percent), moderate (56 percent), or severe (17 percent) nipple-areola complex displacement; surgical correction was attempted in 54 percent of cases. A high-riding nipple-areola complex can develop following aesthetic or reconstructive surgery. Although many patients may not need or choose correction, there are surgical options that may be helpful in improving the nipple-areola complex position.

  2. Bicycle Riding, Walking, and Weight Gain in Premenopausal Women

    Science.gov (United States)

    Lusk, Anne C.; Mekary, Rania A.; Feskanich, Diane; Willett, Walter C.

    2011-01-01

    Context No research has been conducted on bicycle riding and weight control in comparison to walking. Objective To assess the association between bicycle riding and weight control in premenopausal women. Design, Setting, and Participants This was a 16-year follow-up of 18, 414 women in the Nurses’ Health Study II. Main Outcome Measures Weight change between 1989 and 2005 was the primary outcome and odds of gaining >5% of baseline body weight (BBW) by 2005 the secondary outcome. Results At baseline, only 39% walked briskly while only 1.2% bicycled for ≥30 min/d. For a 30 min/d increase in activity between 1989 and 2005, weight gain was significantly less for brisk walking (−1.81 kg; 95% confidence interval (CI) = −2.05,−1.56), bicycling (−1.59 kg; 95%CI= −2.09, −1.08), and other activities (−1.45 kg; 95%CI= −1.66, −1.24) but not for slow walking (+0.06 kg; 95%CI= −0.22, 0.35). Women who reported no bicycling in 1989 and increased to as little as 5 minutes/day in 2005 gained less weight (−0.74 kg; 95%CI= −1.41, −0.07, P-trend5% of their BBW (Odds Ratio (OR) =0.74, 95%CI=0.56–0.98) compared with those who reported no bicycling; overweight/obese women had lower odds at 2–3 hours/week (OR=0.54, 95%CI=0.34–86). Conclusions Bicycling, similar to brisk walking, is associated with less weight gain and an inverse dose-response relationship exists, especially among overweight/obese women. Future research should focus on brisk walking but also on greater time spent bicycling. PMID:20585071

  3. External costs of cadmium emissions to soil: a drawback of phosphorus fertilizers

    DEFF Research Database (Denmark)

    Pizzol, Massimo; C.R. Smart, James; Thomsen, Marianne

    2014-01-01

    ammonium phosphate) and mineral fertilizer produced the lowest external health costs, followed by the fertilizer products wastewater sludge and pig manure. The external cost estimates produced in this study could be used to design economic policy instruments to encourage use of cleaner fertilizer products....... concentration to be calculated for each scenario. Human exposure was determined based on soil-crop bioconcentration factors for cadmium and dietary intake rates of Danish food crops. Updated dose-response functions linking lifetime cadmium intake to the probability of developing cadmium-induced renal disease...... and osteoporosis were applied. These impacts were converted into monetary values by using the EU standard value of a life-year adjusted for quality of life experience. Annualized cost per unit of phosphorus and cadmium are presented, discounted and undiscounted, for comparison. Application of struvite (magnesium...

  4. Kinetically controlled separation of cadmium(II) from zinc(II) with dithizone in the presence of nitrilotriacetic acid.

    Science.gov (United States)

    Itabashi, H; Yoshida, M; Kawamoto, H

    2001-11-01

    The extraction rates of cadmium(II) and zinc(II) with dithizone (H2dz) in the presence of nitrilotriacetic acid (NTA) were measured, and the possible kinetic separation of cadmium(II) from zinc(II) was investigated. Upon the addition of NTA, the difference in the extraction rate between cadmium(II) and zinc(II) became large. Based on the observed rate constant under the condition [NTA] = 1 x 10(-2) mol dm-3, [H2dz]org = 1 x 10(-3) mol dm-3, and pH = 7.0, the shaking time required for the quantitative separation of cadmium(II) from zinc(II) was calculated to be between 326 and 995 s. The experimental results agreed with the prediction, and the quantitative separation of cadmium(II) from zinc(II) was performed within the above-mentioned range of shaking times.

  5. Cadmium Toxicity Induced Alterations in the Root Proteome of Green Gram in Contrasting Response towards Iron Supplement

    Directory of Open Access Journals (Sweden)

    Sowbiya Muneer

    2014-04-01

    Full Text Available Cadmium signifies a severe threat to crop productivity and green gram is a notably iron sensitive plant which shows considerable variation towards cadmium stress. A gel-based proteomics analysis was performed with the roots of green gram exposed to iron and cadmium combined treatments. The resulting data show that twenty three proteins were down-regulated in iron-deprived roots either in the absence (−Fe/−Cd or presence (−Fe/+Cd of cadmium. These down-regulated proteins were however well expressed in roots under iron sufficient conditions, even in the presence of cadmium (+Fe/+Cd. The functional classification of these proteins determined that 21% of the proteins are associated with nutrient metabolism. The other proteins in higher quantities are involved in either transcription or translation regulation, and the rest are involved in biosynthesis metabolism, antioxidant pathways, molecular chaperones and stress response. On the other hand, several protein spots were also absent in roots in response to iron deprivation either in absence (−Fe/−Cd or presence (−Fe/+Cd of cadmium but were well expressed in the presence of iron (+Fe/+Cd. Results suggest that green gram plants exposed to cadmium stress are able to change the nutrient metabolic balance in roots, but in the mean time regulate cadmium toxicity through iron supplements.

  6. Zone refining of cadmium and related characterization

    Indian Academy of Sciences (India)

    Home; Journals; Bulletin of Materials Science; Volume 28; Issue 3. Zone refining of cadmium and related characterization. N R Munirathnam ... The boron impurity in cadmium can be avoided using quartz (GE 214 grade) boat in lieu of high pure graphite boat. The analytical results using inductively coupled plasma optical ...

  7. Cadmium Toxicity to Ringed Seals (Phoca hispida)

    DEFF Research Database (Denmark)

    Sonne, Christian; Dietz, R.; Riget, F. F.

    Cadmium concentrations in kidneys from ringed seals (Phoca hispida) from North West Greenland (Qaanaaq) are high. Concentrations range at level known to induce renal toxic effects (mainly tubulopathy) and demineralisation (osteopenia) of the skeletal system (Fanconi's Syndrome) in humans as well...... the absence of toxic effects of cadmium in ringed seal...

  8. Subcellular localization of cadmium in hyperaccumulator Populus ...

    African Journals Online (AJOL)

    ... of damage to organs of grey poplar was as follows: root > stem> leaves. It was suggested that the Populus × canescens as a renewable resource has the potential to decontaminate cadmium stress development, accumulation and distribution. Key words: Cadmium, phytoremediation, hyperaccumulator, grey poplar, organ.

  9. REMOVAL OF CADMIUM FROM AQUEOUS SOLUTION USING ...

    African Journals Online (AJOL)

    The uptake of cadmium from aqueous solution appeared to follow adsorption mechanism and not ion exchange as characteristic of many other divalent hexacyanoferrates. The sorption data were fitted with Langmuir adsorption isotherm. KEY WORDS: Cadmium removal, Potassium manganese hexacynoferrates(II)/(III) Bull.

  10. Zone refining of cadmium and related characterization

    Indian Academy of Sciences (India)

    Unknown

    Abstract. We present the zone refining results of cadmium using horizontal resistive zone refiner under constant flow of moisture free hydrogen gas. The boron impurity in cadmium can be avoided using quartz (GE 214 grade) boat in lieu of high pure graphite boat. The analytical results using inductively coupled plasma ...

  11. Dietary exposure to cadmium and health effects: impact of environmental changes.

    Science.gov (United States)

    Piscator, M

    1985-11-01

    Cadmium exposure, metabolism, and effects are described especially in relation to dietary intakes. Data on dietary intakes in several countries have been complied from studies using the duplicate diet method or fecal analysis. These two methods seem to give more accurate data than estimates based on cadmium concentrations in food classes and food consumption (composite method). The present data on absorption and retention of ingested cadmium indicate that normally less than 5% is ingested, but absorption may increase in women who have iron deficiency. Earlier estimates of the critical concentration in renal cortex being about 200 mg/kg wet weight still seem to be valid. New information is available on present renal levels and their distribution in the general population. The present margin of safety with regard to risk for renal effects is small. To predict future health risks from increases in dietary cadmium due to environmental changes such as acid deposition, it is necessary that the models used are based on correct assumptions. Of interest are the distributions of dietary intake, gastrointestinal absorption, and renal cadmium concentrations. These distributions are normal or lognormal, and since standard deviations are used when estimating risks, it is of paramount importance that the standard deviations are estimated as accurately as possible. At present it is not possible to quantify the effects attributed to acid rain only; account must be also be taken of cadmium added to, e.g., soil by use of sewage sludge and other fertilizers. In addition to risks to human health, cadmium also poses a threat to horses, which generally have renal cadmium concentrations several times higher than adult humans. It is recommended that horses should be monitored in areas when acid deposition is high. Such monitoring might provide valuable information about impact of acid rain.

  12. Ability of independently ambulant children with cerebral palsy to ride a two-wheel bicycle: a case-control study.

    Science.gov (United States)

    Toovey, Rachel; Reid, Susan M; Rawicki, Barry; Harvey, Adrienne R; Watt, Kerrianne

    2017-04-01

    Limited information exists on the ability of children with cerebral palsy (CP) to ride a two-wheel bicycle, an activity that may improve health and participation. We aimed to describe bicycle-riding ability and variables associated with ability to ride in children with CP (Gross Motor Functional Classification System [GMFCS] levels I-II) compared with children with typical development. This case-control study surveyed parents of 114 children with CP and 87 children with typical development aged 6 to 15 years (115 males, mean age 9y 11mo, standard deviation [SD] 2y 10mo). Kaplan-Meier methods were used to compare proportions able to ride at any given age between the two groups. Logistic regression was used to assess variables associated with ability to ride for children with CP and typical development separately. The proportion of children with CP able to ride at each level of bicycle-riding ability was substantially lower at each age than peers with typical development (pchildren with typical development were able to ride independently by 10 years of age, 51% of children with CP classified as GMFCS level I and 3% of those classified as GMFCS level II had obtained independent riding in the community by 15 years of age. Variables associated with ability to ride for children classified as GMFCS level I were age and parent-rated importance of their child being able to ride. Some independently ambulant children with CP can learn to ride a bicycle, in particular if they are classified as GMFCS level I. Variables associated with ability to ride deserve consideration in shaping future efforts for the majority of this population who are not yet able to ride. © 2016 Mac Keith Press.

  13. Sulphate, more than a nutrient, protects the microalga Chlamydomonas moewusii from cadmium toxicity

    Energy Technology Data Exchange (ETDEWEB)

    Mera, Roi; Torres, Enrique, E-mail: torres@udc.es; Abalde, Julio

    2014-03-01

    Highlights: • Sulphate effect on cadmium toxicity in the microalga Chlamydomonas moewusii Gerloff. • Cadmium increases the sulphur requirements in Chlamydomonas moewusii. • Kinetic coefficients for sulphate utilization and cadmium effect on them. • Sulphate and cadmium influence on the biosynthesis of low-molecular mass thiols. • Cadmium toxicity reduction by sulphate due to higher biosynthesis of thiols. - Abstract: Sulphur is an essential macroelement that plays important roles in living organisms. The thiol rich sulphur compounds, such as cysteine, γ-Glu–Cys, glutathione and phytochelatins participate in the tolerance mechanisms against cadmium toxicity. Plants, algae, yeasts and most prokaryotes cover their demand for reduced sulphur by reduction of inorganic sulphate. The aim of this study was to investigate, using a bifactorial experimental design, the effect of different sulphate concentrations in the nutrient solution on cadmium toxicity in the freshwater microalga Chlamydomonas moewusii. Cell growth, kinetic parameters of sulphate utilization and intracellular concentrations of low-molecular mass thiol compounds were determined. A mathematical model to describe the growth of this microalga based on the effects of sulphate and cadmium was obtained. An ANOVA revealed an interaction between them, 16% of the effect sizes was explained by this interaction. A higher amount of sulphate in the culture medium allowed a higher cadmium tolerance due to an increase in the thiol compound biosynthesis. The amount of low-molecular mass thiol compounds, mainly phytochelatins, synthesized by this microalga was significantly dependent on the sulphate and cadmium concentrations; the higher phytochelatin content was obtained in cultures with 4 mg Cd/L and 1 mM sulphate. The maximum EC{sub 50} value (based on nominal cadmium concentration) reached for this microalga was 4.46 ± 0.42 mg Cd/L when the sulphate concentration added to the culture medium was also 1 m

  14. Cadmium mobility and accumulation in soils of the European Communities

    NARCIS (Netherlands)

    Fraters B; van Beurden AUCJ

    1993-01-01

    In this overview of the effects of cadmium pollution on agricultural soils in the European Community, both the cadmium loads on agricultural land and the soil sensitivity to cadmium accumulation have been estimated. Cadmium loads have been estimated separately for arable land and grassland. The

  15. Temperature-controlled ionic liquid-based ultrasound-assisted microextraction for preconcentration of trace quantity of cadmium and nickel by using organic ligand in artificial saliva extract of smokeless tobacco products

    Science.gov (United States)

    Arain, Sadaf Sadia; Kazi, Tasneem Gul; Arain, Asma Jabeen; Afridi, Hassan Imran; Baig, Jameel Ahmed; Brahman, Kapil Dev; Naeemullah; Arain, Salma Aslam

    2015-03-01

    A new approach was developed for the preconcentration of cadmium (Cd) and nickel (Ni) in artificial saliva extract of dry snuff (brown and black) products using temperature-controlled ionic liquid-based ultrasound-assisted dispersive liquid-liquid microextraction (TIL-UDLLμE) followed by electrothermal atomic absorption spectrometry (ETAAS). The Cd and Ni were complexed with ammonium pyrrolidinedithiocarbamate (APDC), extracted in ionic liquid drops, 1-butyl-3-methylimidazolium hexafluorophosphate [C4MIM][PF6]. The multivariate strategy was applied to estimate the optimum values of experimental variables influence the % recovery of analytes by TIL-UDLLμE method. At optimum experimental conditions, the limit of detection (3s) were 0.05 and 0.14 μg L-1 while relative standard deviations (% RSD) were 3.97 and 3.55 for Cd and Ni respectively. After extraction, the enhancement factors (EF) were 87 and 79 for Cd and Ni, respectively. The RSD for six replicates of 10 μg L-1 Cd and Ni were 3.97% and 3.55% respectively. To validate the proposed method, certified reference material (CRM) of Virginia tobacco leaves was analyzed, and the determined values of Cd and Ni were in good agreement with the certified values. The concentration of Cd and Ni in artificial saliva extracts corresponds to 39-52% and 21-32%, respectively, of the total contents of both elements in dry brown and black snuff products.

  16. Fluorescent and colorimetric sensors for detection of lead, cadmium, and mercury ions.

    Science.gov (United States)

    Kim, Ha Na; Ren, Wen Xiu; Kim, Jong Seung; Yoon, Juyoung

    2012-04-21

    Exposure to even very low levels of lead, cadmium, and mercury ions is known to cause neurological, reproductive, cardiovascular, and developmental disorders, which are more serious problems for children particularly. Accordingly, great efforts have been devoted to the development of fluorescent and colorimetric sensors, which can selectively detect lead, cadmium, and mercury ions. In this critical review, the fluorescent and colorimetric sensors are classified according to their receptors into several categories, including small molecule based sensors, calixarene based chemosensors, BODIPY based chemosensors, polymer based chemosensors, DNA functionalized sensing systems, protein based sensing systems and nanoparticle based sensing systems (197 references). This journal is © The Royal Society of Chemistry 2012

  17. Low-Voltage Ride-Through Operation of Power Converters in Grid-Interactive Microgrids by Using Negative-Sequence Droop Control

    DEFF Research Database (Denmark)

    Zhao, Xin; Guerrero, Josep M.; Savaghebi, Mehdi

    2017-01-01

    Due to the increasing penetration level of microgrids (MGs), it becomes a critical issue for MGs to help sustaining power system stability. Therefore, ancillary services, such as the low-voltage ride-through (LVRT) capability should be incorporated in MGs in order to guarantee stable operation of......, while the secondary controller is based on a positive/negative sequence droop scheme which is able to coordinate the power injection during voltage sags. Experimental results are obtained to verify the effectiveness of the proposed control strategy....... of the utility grid during grid faults. In this paper, a LVRT control strategy based on positive/negative sequence droop control is proposed for grid-interactive MGs to ride-through voltage sags with not only inductive/resistive, but also complex line impedance. By using the proposed control strategy, MGs can...

  18. Validation of a Functional Pyelocalyceal Renal Model for the Evaluation of Renal Calculi Passage While Riding a Roller Coaster.

    Science.gov (United States)

    Mitchell, Marc A; Wartinger, David D

    2016-10-01

    The identification and evaluation of activities capable of dislodging calyceal renal calculi require a patient surrogate or validated functional pyelocalyceal renal model. To evaluate roller coaster facilitation of calyceal renal calculi passage using a functional pyelocalyceal renal model. A previously described adult ureteroscopy and renoscopy simulator (Ideal Anatomic) was modified and remolded to function as a patient surrogate. Three renal calculi of different sizes from the patient who provided the original computed tomographic urograph on which the simulator was based were used. The renal calculi were suspended in urine in the model and taken for 20 rides on the Big Thunder Mountain Railroad roller coaster at Walt Disney World in Orlando, Florida. The roller coaster rides were analyzed using variables of renal calculi volume, calyceal location, model position on the roller coaster, and renal calculi passage. Sixty renal calculi rides were analyzed. Independent of renal calculi volume and calyceal location, front seating on the roller coaster resulted in a passage rate of 4 of 24. Independent of renal calculi volume and calyceal location, rear seating on the roller coaster resulted in a passage rate of 23 of 36. Independent of renal calculi volume in rear seating, calyceal location differed in passage rates, with an upper calyceal calculi passage rate of 100%; a middle calyceal passage rate of 55.6%; and a lower calyceal passage rate of 40.0%. The functional pyelocalyceal renal model serves as a functional patient surrogate to evaluate activities that facilitate calyceal renal calculi passage. The rear seating position on the roller coaster led to the most renal calculi passages.

  19. Mathematical modelling of the secondary airspring suspension in railway vehicles and its effect on safety and ride comfort

    Science.gov (United States)

    Facchinetti, Alan; Mazzola, Laura; Alfi, Stefano; Bruni, Stefano

    2010-12-01

    The mathematical model of suspension components in a railway vehicle may have an important effect on the results of vehicle dynamics simulations and their accuracy in reproducing the actual vehicle behaviour. This paper aims to define and compare alternative mathematical modelling approaches for the secondary airspring suspension and to assess their effect on the accuracy of rail vehicle dynamics multibody simulation. To derive reliable models of the suspension, a quasi-static and dynamic characterisation of the suspension was performed by means of a full-scale laboratory experiment. Based on this, two different modelling approaches were developed for the airspring suspension: a quasi-static one, in which the frequency-dependent behaviour of the suspension is neglected, but the coupling between shear and roll stiffness is included, and a dynamic one in which additionally the frequency-dependent behaviour of the suspension in vertical direction is represented using a thermodynamic model, and additionally the dependency of lateral/roll stiffness parameters on the load is incorporated. The results of vehicle dynamics simulations in curved track and/or in the presence of crosswinds and the results of ride comfort calculations are presented, to assess the effect of the models developed, in comparison with a simpler model only reproducing the vertical and lateral stiffness of the suspension. It is demonstrated that the quasi-static coupling effect between shear and roll deformation in the airsprings can have a large effect on the simulation of load transfer effects in curved track and in the presence of crosswinds, and hence remarkably affect the assessment of ride safety and track loading, whereas the dynamic model of the airspring suspension appears to be required when wheel unloading under the action of crosswind is evaluated. Finally, it is shown that a dynamic model of the airspring is required to assess ride comfort correctly, especially when the pneumatic layout

  20. Ride Control Systems - Reduced Motions on the Cost of Increased Sectional Forces ?

    DEFF Research Database (Denmark)

    Folsø, R.; Nielsen, Ulrik Dam; Torti, F.

    2003-01-01

    domain limits on the angle of attack cannot be set. Since the lift coefficient is treated linearly the calculated lift force is severely overestimated in rough sea. Secondly the effect of including ride control systems in the calculations is demonstrated through comparisons of RMS values and of response......Implementation of passive and active ride control systems into both linear frequency and non-linear time domain strip theories is described. The ride control systems considered can consist of T-foils, fins or a combination of these. These appendages are taken into account by considering the lift...... by adding the lift forces to the exciting forces in the equations of motion. One of the advantages in the time domain is that the angle of attack can be limited easily, as is often the case in real full scale ride control systems. This way cavitation and finally stalling can be avoided. In the frequency...

  1. Influences of Carbody Vertical Flexibility on Ride Comfort of Railway Vehicles

    Directory of Open Access Journals (Sweden)

    Dumitriu Mădălina

    2017-06-01

    Full Text Available The article investigates the influence of the carbody vertical flexibility on the ride comfort of the railway vehicles. The ride comfort is evaluated via the comfort index calculated in three reference points of the carbody. The results of the numerical simulations bring attention to the importance of the carbody symmetrical vertical bending upon the dynamic response of the vehicle, mainly at high velocities. Another conclusion is that the ride comfort can be significantly affected as a function of the symmetrical bending frequency of the carbody. Similarly, there are improvement possibilities for the ride comfort when the best selection of the stiffness in the longitudinal traction system between the carbody and bogie and the vertical suspension damping is made.

  2. Control of Doubly-Fed Induction Generator to Ride-Through Recurring Grid Faults

    DEFF Research Database (Denmark)

    Chen, Wenjie; Xu, Dehong; Zhu, Nan

    2016-01-01

    The wind turbine system (WTS) is required to ride-through recurring grid faults by the new grid codes. Under single grid faults, the fault ride-through (FRT) strategy with rotor-side crowbar is normally used for the doubly-fed induction generator (DFIG) WTS. However, under recurring faults, larger...... system will be influenced. In this paper, an FRT strategy for the DFIG WTS to ride-through recurring symmetrical grid faults is investigated. An improved control strategy is introduced and it is applied during the voltage recovery of the grid faults. The decay of the stator natural flux can...... transient current and voltage may be produced, and the DFIG may fail to ride-through the second fault even with the rotor-side crowbar. The crowbar can be active again during the voltage recovery, but large electromagnetic torque (EM-torque) fluctuations will be introduced. The reliability of the mechanical...

  3. Cadmium, lead and bromine in beached microplastics.

    Science.gov (United States)

    Massos, Angelo; Turner, Andrew

    2017-08-01

    Samples of microplastic (n = 924) from two beaches in south west England have been analysed by field-portable-x-ray fluorescence (FP-XRF) spectrometry, configured in a low-density mode and with a small-spot facility, for the heavy metals, Cd and Pb, and the halogen, Br. Primary plastics in the form of pre-production pellets were the principal type of microplastic (>70%) on both beaches, with secondary, irregularly-shaped fragments representing the remainder of samples. Cadmium and Pb were detected in 6.9% and 7.5% of all microplastics, respectively, with concentrations of either metal that exceeded 103 μg g-1 usually encountered in red and yellow pellets or fragments. Respective correlations of Cd and Pb with Se and Cr were attributed to the presence of the coloured, inorganic pigments, cadmium sulphoselenide and lead chromate. Bromine, detected in 10.4% of microplastics and up to concentrations of about 13,000 μg g-1, was mainly encountered in neutrally-coloured pellets. Its strong correlation with Sb, whose oxides are effective fire suppressant synergists, suggests the presence of a variety of brominated flame retardants arising from the recycling of plastics originally used in casings for heat-generating electrical equipment. The maximum bioaccessible concentrations of Cd and Pb, evaluated using a physiological extraction based on the chemical characteristics of the proventriculus-gizzard of the northern fulmar, were about 50 μg g-1 and 8 μg g-1, respectively. These concentrations exceed those estimated for the diet of local seabirds by factors of about 50 and 4, respectively. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Environmental cadmium and lead exposure and anti-Müllerian hormone in pregnant women.

    Science.gov (United States)

    Christensen, P S; Bonde, J P; Bungum, L; Giwercman, A; Toft, G; Jönsson, B A G; Specht, I O

    2016-06-01

    Anti-Müllerian Hormone (AMH) has been suggested as a marker for ovarian function. Cadmium and lead have been suggested to reduce female fecundity. In this study we aimed to investigate whether environmental exposure to cadmium and lead was associated with alterations in serum-AMH. The associations between serum-AMH and whole blood cadmium or lead were investigated by general linear models in a population-based sample of 117 pregnant women. The mean concentrations of blood cadmium and lead were 0.71μg/L and 17.4μg/L, respectively. The mean serum-AMH was 17.3pmol/L. No association between lead and AMH was detected. In the cadmium analysis the adjusted mean AMH level (95% CI) in the highest exposure tertile was 12.4 (6.4;23.8) compared to 5.6 (2.7;11.4) in the lowest exposure tertile (p=0.06). The study provides suggestive evidence that environmental exposure to cadmium, but not lead, may alter the level of AMH. Copyright © 2016 Elsevier Inc. All rights reserved.

  5. Deletion of Phytochelatin Synthase Modulates the Metal Accumulation Pattern of Cadmium Exposed C. elegans

    Directory of Open Access Journals (Sweden)

    Yona J. Essig

    2016-02-01

    Full Text Available Environmental metal pollution is a growing health risk to flora and fauna. It is therefore important to fully elucidate metal detoxification pathways. Phytochelatin synthase (PCS, an enzyme involved in the biosynthesis of phytochelatins (PCs, plays an important role in cadmium detoxification. The PCS and PCs are however not restricted to plants, but are also present in some lower metazoans. The model nematode Caenorhabditis elegans, for example, contains a fully functional phytochelatin synthase and phytochelatin pathway. By means of a transgenic nematode strain expressing a pcs-1 promoter-tagged GFP (pcs-1::GFP and a pcs-1 specific qPCR assay, further evidence is presented that the expression of the C. elegans phytochelatin synthase gene (pcs-1 is transcriptionally non-responsive to a chronic (48 h insult of high levels of zinc (500 μM or acute (3 h exposures to high levels of cadmium (300 μM. However, the accumulation of cadmium, but not zinc, is dependent on the pcs-1 status of the nematode. Synchrotron based X-ray fluorescence imaging uncovered that the cadmium body burden increased significantly in the pcs-1(tm1748 knockout allele. Taken together, this suggests that whilst the transcription of pcs-1 may not be mediated by an exposure zinc or cadmium, it is nevertheless an integral part of the cadmium detoxification pathway in C. elegans.

  6. [A new method for quantitative measurement of the cadmium absorbed by chick embryos].

    Science.gov (United States)

    Gottofrey, J

    1984-01-01

    We attempted to determine the quantity of cadmium incorporated in hens eggs after immersion in cadmium solutions, and the cadmium concentration measured in embryos. We discussed equipment allowing simultaneous treatment of up to 42 samples, and called it " digestor ". It consisted of two gas-heated sand baths, two stands for cooling down solutions and an evacuation system for toxic vapours. Our method was based on wet mineralisation. It consisted of desintegrating experimental chick embryos in a HNO3/H2O2 mixed solution. After heating and evaporating, the quantity of cadmium in the remnant was determined by atomic absorption spectrophotometry. The reliability of such a technique was tested by studying as controls controls 17 days-old chick embryos injected with a known quantity of Cd(NO3). It showed no loss of cadmium. We also compared our procedure with a dry ashing method. The latter showed unacceptable losses and insufficient precision for the problems we wanted to investigate. Our method gave us much more precise results. The equipment we developed has functioned wholly satisfactorily and allowed us to investigate for instance cadmium distribution and concentration in embryonic organs of 17 days-old chicks. It could also be useful for researches concerning other biological samples analyzed for different heavy metals.

  7. Traumatic spinal cord injuries in horseback riding: a 35-year review.

    Science.gov (United States)

    Lin, Cindy Y; Wright, Jerry; Bushnik, Tamara; Shem, Kazuko

    2011-11-01

    Spinal cord injury (SCI) is a potentially disabling neurologic injury that can occur in horseback riding. To date, no published study has examined the epidemiology of SCI from horseback riding in the United States, and few international studies exist on this topic. Several studies have described traumatic brain injuries, spine fractures, and extremity injuries; however, SCI patterns and outcomes in horseback riders are poorly understood. This study was undertaken to characterize the demographics, SCI patterns, and neurologic outcomes of persons with SCIs related to horseback riding. Descriptive epidemiologic study. This is a retrospective review of 121 SCI cases from horseback riding in the National SCI Statistical Center database from 1973 to 2008. The treatment setting was 26 U.S. SCI Model Systems of Care. The number of injuries, gender, age, and SCI type for horseback riding were compared with other sports and activities. The level of preserved neurologic function, SCI completeness, American Spinal Injury Association classification, and mechanical ventilation use at discharge were examined in the horseback riding group. The mean age of injury was 37.8 years (standard deviation, 15.2). The majority of patients were white (88%) and female (50.4%). Compared with diving, motorcycle riding, football, and gymnastics, horseback riding involved a significantly higher number of women (P < .005), a higher mean age of injury, and an equal likelihood of resulting in paraplegia and tetraplegia. The most common levels of preserved neurologic function were C4-C6, T12, and L1. Spinal cord injury from horseback riding most commonly resulted in incomplete tetraplegia (41%) followed by complete paraplegia (24%). Only 4 patients required mechanical ventilation on discharge from acute inpatient rehabilitation. Spinal cord injury from horseback riding affects an equal proportion of women and men, has a wide age range, and most commonly results in incomplete tetraplegia followed by

  8. One-Dimensional Fast Transient Simulator for Modeling Cadmium Sulfide/Cadmium Telluride Solar Cells

    Science.gov (United States)

    Guo, Da

    Solar energy, including solar heating, solar architecture, solar thermal electricity and solar photovoltaics, is one of the primary alternative energy sources to fossil fuel. Being one of the most important techniques, significant research has been conducted in solar cell efficiency improvement. Simulation of various structures and materials of solar cells provides a deeper understanding of device operation and ways to improve their efficiency. Over the last two decades, polycrystalline thin-film Cadmium-Sulfide and Cadmium-Telluride (CdS/CdTe) solar cells fabricated on glass substrates have been considered as one of the most promising candidate in the photovoltaic technologies, for their similar efficiency and low costs when compared to traditional silicon-based solar cells. In this work a fast one dimensional time-dependent/steady-state drift-diffusion simulator, accelerated by adaptive non-uniform mesh and automatic time-step control, for modeling solar cells has been developed and has been used to simulate a CdS/CdTe solar cell. These models are used to reproduce transients of carrier transport in response to step-function signals of different bias and varied light intensity. The time-step control models are also used to help convergence in steady-state simulations where constrained material constants, such as carrier lifetimes in the order of nanosecond and carrier mobility in the order of 100 cm2/Vs, must be applied.

  9. Cadmium action in synapses in the brain

    Energy Technology Data Exchange (ETDEWEB)

    Minami, Akira; Takeda, Atsushi; Nishibaba, Daisuke; Tekefuta, Sachiyo; Oku, Naoto [Department of Radiobiochemistry, School of Pharmaceutical Sciences, University of Shizuoka, Shizuoka (Japan)

    2001-05-01

    Chronic exposure to cadmium causes central nervous system disorders, e.g., olfactory dysfunction. To clarify cadmium toxicity in synaptic neurotransmission in the brain, the movement and action of cadmium in the synapses was examined using in vivo microdialysis. One and 24 h after injection of {sup 109}CdCl{sub 2} into the amygdala of rats, {sup 109}Cd release into the extracellular space was facilitated by stimulation with high K{sup +}, suggesting that cadmium taken up in amygdalar neurons is released into the synaptic clefts in a calcium- and impulse-dependent manner. To examine the action of cadmium in the synapses, the amygdala was perfused with artificial cerebrospinal fluid containing 10-30 {mu}M CdCl{sub 2}. The release of excitatory neurotransmitters, i.e., glutamate and aspartate, into the extracellular space was decreased during perfusion with cadmium, while the release of inhibitory neurotransmitters, i.e., glycine and {gamma}-amino butyric acid (GABA), into the extracellular space was increased during the period. These results suggest that cadmium released from the amygdalar neuron terminals affects the degree and balance of excitation-inhibition in synaptic neurotransmission. (author)

  10. Response of Pleurotus ostreatus to cadmium exposure

    Energy Technology Data Exchange (ETDEWEB)

    Favero, N.; Bressa, G.; Costa, P. (Univ. of Padua (Italy))

    1990-08-01

    The possibility of utilizing agroindustrial wastes in the production of edible, high-quality products (e.g., mushrooms) implies the risk of bringing toxic substances, such as heavy metals, into the human food chain. Thus, growth in the presence of cadmium and cadmium accumulation limits have been studied in the industrially cultivated fungus P. ostreatus. Fruit body production is substantially unaffected in the presence of 25, 139, and 285 mg Cd/kg of dried substrate. Cadmium concentration in fruit bodies is related to cadmium substrate level, the metal being present at higher levels in caps (22-56 mg/kg dry wt) than in stems (13-36 mg/kg dry wt). Concentration factor (CF), very low in the controls (about 2), further decreases in treated specimens. The presence of a cadmium control mechanism in this fungi species is suggested. Fruit body cadmium levels could, however, represent a risk for P. ostreatus consumers, according to FAO/WHO limits related to weekly cadmium intake.

  11. Response of Saccharomyces cerevisiae to cadmium stress

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Luciana Mara Costa; Ribeiro, Frederico Haddad; Neves, Maria Jose [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil). Lab. de Radiobiologia], e-mail: luamatu@uol.com.br; Porto, Barbara Abranches Araujo; Amaral, Angela M.; Menezes, Maria Angela B.C. [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Lab. de Ativacao Neutronica], e-mail: menezes@cdtn.br; Rosa, Carlos Augusto [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Dept. de Microbiologia], e-mail: carlrosa@icb.ufmg

    2009-07-01

    The intensification of industrial activity has been greatly contributing with the increase of heavy metals in the environment. Among these heavy metals, cadmium becomes a serious pervasive environmental pollutant. The cadmium is a heavy metal with no biological function, very toxic and carcinogenic at low concentrations. The toxicity of cadmium and several other metals can be mainly attributed to the multiplicity of coordination complexes and clusters that they can form. Some aspects of the cellular response to cadmium were extensively investigated in the yeast Saccharomyces cerevisiae. The primary site of interaction between many toxic metals and microbial cells is the plasma membrane. Plasma-membrane permeabilisation has been reported in a variety of microorganisms following cadmium exposure, and is considered one mechanism of cadmium toxicity in the yeast. In this work, using the yeast strain S. cerevisiae W303-WT, we have investigated the relationships between Cd uptake and release of cellular metal ions (K{sup +} and Na{sup +}) using neutron activation technique. The neutron activation was an easy, rapid and suitable technique for doing these metal determinations on yeast cells; was observed the change in morphology of the strains during the process of Cd accumulation, these alterations were observed by Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM) during incorporation of cadmium. (author)

  12. Uma nova abordagem para o problema dial-a-ride A new approach for the dial-a-ride problem

    Directory of Open Access Journals (Sweden)

    Geraldo Regis Mauri

    2009-04-01

    Full Text Available Este trabalho descreve um modelo matemático geral e multiobjetivo para o problema dial-a-ride e uma aplicação do simulated annealing para resolvê-lo. O modelo trata a forma estática do problema e abrange vários casos distintos dos modelos mais comuns, tais como frota homogênea e heterogênea, garagens múltiplas ou únicas, e uma função de minimização multiobjetivo que trata os custos de transporte e a inconveniência dos clientes por meio de penalizações. A aplicação do simulated annealing é simples, porém, para a geração de novas soluções vizinhas, são utilizados três movimentos de troca selecionados de forma aleatória e uniformemente distribuída, e as rotas são roteirizadas e programadas separadamente por outros métodos heurísticos. Os resultados computacionais são obtidos com o uso de instâncias públicas disponíveis e comparados com outros métodos que apresentam o atual estado da arte em que o problema se encontra.This paper describes a general multi-objective mathematical model for the dial-a-ride problem approximately solved by Simulated Annealing. The model deals with a static problem and includes several distinct cases such as heterogeneous or homogeneous fleet of vehicles, multi or single depot and a multi-objective function that treats transportation costs and customer inconveniences by using penalties. The simulated annealing application is straightforward with three types of neighbors' moves that are randomly selected and equally distributed. The routes are clustered and scheduled in a separate way using specific heuristic methods. Computational results are performed over instances of the literature and the results are compared against current state of the art methods.

  13. Remote sensing applications in evaluation of cadmium pollution effects

    Science.gov (United States)

    Kozma-Bognar, Veronika; Martin, Gizella; Berke, Jozsef

    2013-04-01

    According to the 21st century developments in information technology the remote sensing applications open new perspectives to the data collection of our environment. Using the images in different spectral bands we get more reliable and accurate information about the condition, process and phenomena of the earth surface compared to the traditional aircraft image technologies (RGB images). The effects of particulate pollution originated from road traffic were analysed by the research team of Department of Meteorology and Water Management (University of Pannonia, Georgikon Faculty) with the application of visible, near infrared and thermal infrared remote sensing aircraft images. In the scope of our research was to detect and monitor the effects of heavy metal contamination in plant-atmosphere system under field experiments. The testing area was situated at Agro-meteorological Research Station in Keszthely (Hungary), where maize crops were polluted once a week (0,5 M concentration) by cadmium. In our study we simulated the effects of cadmium pollution because this element is one of the most common toxic heavy metals in our environment. During two growing seasons (2011, 2012) time-series analyses were carried out based on the remote sensing data and parallel collected variables of field measurement. In each phenological phases of plant we took aerial images, in order to follow the changes of the structure and intensity values of plots images. The spatial resolution of these images were under 10x10 cm, which allowed to use a plot-level evaluation. The structural and intensity based measurement evaluation methods were applied to examine cadmium polluted and control maize canopy after data pre-processing. Research activities also focused on the examination of the influence of the irrigation and the comparison of aerial and terrain parameters. As conclusion, it could be determined the quantification of cadmium pollution effects is possible on maize plants by using remote

  14. Integrating stochastic time-dependent travel speed in solution methods for the dynamic dial-a-ride problem

    Science.gov (United States)

    Schilde, M.; Doerner, K.F.; Hartl, R.F.

    2014-01-01

    In urban areas, logistic transportation operations often run into problems because travel speeds change, depending on the current traffic situation. If not accounted for, time-dependent and stochastic travel speeds frequently lead to missed time windows and thus poorer service. Especially in the case of passenger transportation, it often leads to excessive passenger ride times as well. Therefore, time-dependent and stochastic influences on travel speeds are relevant for finding feasible and reliable solutions. This study considers the effect of exploiting statistical information available about historical accidents, using stochastic solution approaches for the dynamic dial-a-ride problem (dynamic DARP). The authors propose two pairs of metaheuristic solution approaches, each consisting of a deterministic method (average time-dependent travel speeds for planning) and its corresponding stochastic version (exploiting stochastic information while planning). The results, using test instances with up to 762 requests based on a real-world road network, show that in certain conditions, exploiting stochastic information about travel speeds leads to significant improvements over deterministic approaches. PMID:25844013

  15. Low level determinations of environmental cadmium

    Energy Technology Data Exchange (ETDEWEB)

    Rosman, K.J.R.; De Laeter, J.R.

    1976-06-24

    An isotope dilution technique has been developed to measure the concentration of cadmium in aqueous solutions with a sensitivity of 0.003 micrograms per liter. The concentrations of cadmium in two river systems in Western Australia has been measured to establish an accurate set of low level reference determinations in a region which is relatively free of sources of industrial pollution. The results of the study demonstrate that the cadmium content in the two major river systems in western Australia is about 100 times lower than the World Health Organization limits. The data indicate that the cadmium content tends to decrease upstream from the mouth of the river, and that in the reservoir areas the content is as low as 0.02 micrograms per liter. These values are substantially lower than waterways in other parts of the world. 13 references, 1 figure, 1 table.

  16. Cadmium substituted high permeability lithium ferrite

    Indian Academy of Sciences (India)

    , 0.5 and 0.6 were prepared by a double sintering ceramic technique and characterized by X-ray diffraction and scanning electron microscopy (SEM). The lattice parameter is found to increase monotonically with the cadmium content.

  17. Market for nickel-cadmium batteries

    Science.gov (United States)

    Putois, F.

    Besides the lead/acid battery market, which has seen a tremendous development linked with the car industry, the alkaline rechargeable battery market has also been expanded for more than twenty years, especially in the field of portable applications with nickel-cadmium batteries. Today, nickel-cadmium batteries have to face newcomers on the market, such as nickel-metal hydride, which is another alkaline couple, and rechargeable lithium batteries; these new battery systems have better performances in some areas. This work illustrates the status of the market for nickel-cadmium batteries and their applications. Also, for two major applications—the cordless tool and the electric vehicles—the competitive situation of nickel-cadmium batteries; facing new systems such as nickel-metal hydride and lithium ion cells are discussed.

  18. Dietary Intake Estimates and Urinary Cadmium Levels in Danish Postmenopausal Women.

    Directory of Open Access Journals (Sweden)

    Caterina Vacchi-Suzzi

    Full Text Available Cadmium is a known carcinogen that can disrupt endocrine signalling. Cigarette smoking and food are the most common routes of non-occupational exposure to cadmium. Cadmium accumulates in the kidney and can be measured in urine, making urine cadmium (U-Cd a biomarker of long-term exposure. However dietary-cadmium (D-Cd intake estimates are often used as surrogate indicator of cadmium exposure in non-smoking subjects. It is therefore important to investigate the concordance between D-Cd estimates obtained with Food Frequency Questionnaires and U-Cd.U-Cd levels were compared with estimated dietary-cadmium (D-Cd intake in 1764 post-menopausal women from the Danish Diet, Cancer and Health cohort. For each participant, a food frequency questionnaire, and measures of cadmium content in standard recipes were used to judge the daily intake of cadmium, normalized by daily caloric intake. Cadmium was measured by ICP-MS in spot urine sampled at baseline and normalized by urinary creatinine. Information on diet, socio-demographics and smoking were self-reported at baseline.Linear regressions between U-Cd and D-Cd alone revealed minimal but significant positive correlation in never smokers (R2 = 0.0076, β = 1.5% increase per 1 ng Cd kcal(-1, p = 0.0085, n = 782, and negative correlation in current smokers (R2 = 0.0184, β = 7.1% decrease per 1 ng Cd kcal(-1 change, p = 0.0006, n = 584. In the full study population, most of the variability in U-Cd was explained by smoking status (R2 = 0.2450, n = 1764. A forward selection model revealed that the strongest predictors of U-Cd were age in never smokers (Δ R2 = 0.04, smoking duration in former smokers (Δ R2 = 0.06 and pack-years in current smokers (Δ R2 = 0.07. Food items that contributed to U-Cd were leafy vegetables and soy-based products, but explained very little of the variance in U-Cd.Dietary-Cd intake estimated from food frequency questionnaires correlates only minimally with U-Cd biomarker, and its use

  19. Low-Voltage Ride-Through Capability of a Single-Stage Single-Phase Photovoltaic System Connected to the Low-Voltage Grid

    Directory of Open Access Journals (Sweden)

    Yongheng Yang

    2013-01-01

    Full Text Available The progressive growing of single-phase photovoltaic (PV systems makes the Distribution System Operators (DSOs update or revise the existing grid codes in order to guarantee the availability, quality, and reliability of the electrical system. It is expected that the future PV systems connected to the low-voltage grid will be more active with functionalities of low-voltage ride-through (LVRT and the grid support capability, which is not the case today. In this paper, the operation principle is demonstrated for a single-phase grid-connected PV system in a low-voltage ride-through operation in order to map future challenges. The system is verified by simulations and experiments. Test results show that the proposed power control method is effective and the single-phase PV inverters connected to low-voltage networks are ready to provide grid support and ride-through voltage fault capability with a satisfactory performance based on the grid requirements for three-phase renewable energy systems.

  20. Cadmium leaching from thermal treated and gamma irradiated Mexican aluminosilicates

    Energy Technology Data Exchange (ETDEWEB)

    Davila-Rangel, J.I. [Departamento de Quimica, Instituto Nacional de Investigaciones Nucleares, Apdo. Postal 18-1027, Mexico 11801, D.F. (Mexico); Unidad Academica Centro Regional de Estudios Nucleares, Universidad Autonoma de Zacatecas Cipres 10, Frac. La Penuela, Zacatecas, Zacatecas 98068 (Mexico); Facultad de Ciencias, Universidad Autonoma del Estado de Mexico, Instituto Literario No. 100 Col. Centro C.P. 50000, Toluca, Edo. de Mexico (Mexico); Solache-Rios, M. [Departamento de Quimica, Instituto Nacional de Investigaciones Nucleares, Apdo. Postal 18-1027, Mexico 11801, D.F. (Mexico)], E-mail: msr@nuclear.inin.mx

    2008-10-15

    Thermal and radiation effects on the leaching of cadmium from two cadmium exchanged zeolitic tuffs and one clay were determined. The cadmium exchanged aluminosilicates were heated at different temperatures (500, 700, 900 and 1100 {sup o}C), and the materials were then treated with NaCl (1 M and 5 M) and HNO{sub 3} (0.001 M and 1 M) solutions to determine the leaching behaviour of cadmium from the materials. The stability of cadmium in the materials increased as the heating temperature was increased. Cadmium leaching from gamma irradiated and heated materials at 1100 {sup o}C was higher than leaching from non-irradiated samples.

  1. Risky riding: Naturalistic methods comparing safety behavior from conventional bicycle riders and electric bike riders.

    Science.gov (United States)

    Langford, Brian Casey; Chen, Jiaoli; Cherry, Christopher R

    2015-09-01

    As electric bicycles (e-bikes) have emerged as a new transportation mode, their role in transportation systems and their impact on users have become important issues for policy makers and engineers. Little safety-related research has been conducted in North America or Europe because of their relatively small numbers. This work describes the results of a naturalistic GPS-based safety study between regular bicycle (i.e., standard bicycle) and e-bike riders in the context of a unique bikesharing system that allows comparisons between instrumented bike technologies. We focus on rider safety behavior under four situations: (1) riding in the correct direction on directional roadway segments, (2) speed on on-road and shared use paths, (3) stopping behavior at stop-controlled intersections, and (4) stopping behavior at signalized intersections. We find that, with few exceptions, riders of e-bike behave very similarly to riders of bicycles. Violation rates were very high for both vehicles. Riders of regular bicycles and e-bikes both ride wrong-way on 45% and 44% of segments, respectively. We find that average on-road speeds of e-bike riders (13.3kph) were higher than regular bicyclists (10.4kph) but shared use path (greenway) speeds of e-bike riders (11.0kph) were lower than regular bicyclists (12.6kph); both significantly different at >95% confidence. At stop control intersections, both bicycle and e-bike riders violate the stop signs at the similar rate with bicycles violating stop signs at a slightly higher rate at low speed thresholds (∼80% violations at 6kph, 40% violations at 11kph). Bicycles and e-bikes violate traffic signals at similar rates (70% violation rate). These findings suggest that, among the same population of users, e-bike riders exhibit nearly identical safety behavior as regular bike riders and should be regulated in similar ways. Users of both technologies have very high violation rates of traffic control devices and interventions should occur to

  2. Antagonism between cadmium and magnesium: a possible role of magnesium in therapy of cadmium intoxication.

    Science.gov (United States)

    Matović, Vesna; Plamenac Bulat, Zorica; Djukić-Cosić, Danijela; Soldatović, Danilo

    2010-03-01

    One of the important mechanisms of cadmium (Cd) toxicity is its interactions with bioelements, including magnesium (Mg). Exposure to Cd leads to disturbances in Mg metabolism in the organism, while Mg supplementation has an adverse effect on Cd absorption, accumulation and toxicity. According to the available results, which indicate a protective role of Mg against Cd toxicity, it remains to be seen whether magnesium may influence the important unsolved problem of Cd intoxication therapy. In this review, the interactions between the toxic metal Cd and the bioelement Mg are discussed on the basis of the available literature and our own results. We discuss these interactions mainly based on experimental data because data from human studies are scarce.

  3. Therapeutic Effects of Horseback Riding Interventions: A Systematic Review and Meta-analysis.

    Science.gov (United States)

    Stergiou, Alexandra; Tzoufi, Meropi; Ntzani, Evangelia; Varvarousis, Dimitrios; Beris, Alexandros; Ploumis, Avraam

    2017-10-01

    Equine-assisted therapies, such as therapeutic riding and hippotherapy, are believed to have positive physical and emotional effects in individuals with neuromotor, developmental, and physical disabilities. The purpose of this review was to determine whether therapeutic riding and hippotherapy improve balance, motor function, gait, muscle symmetry, pelvic movement, psychosocial parameters, and the patients' overall quality of life. In this study, a literature search was conducted on MEDLINE, CINAHL, MBASE, SportDiscus, Cochrane Database of Systematic Reviews, Cochrane Controlled Trials Register, PEDro, DARE, Google Scholar, and Dissertation Abstracts. Only studies with a control/comparison group or self-controlled studies performing preintervention and postintervention assessment were included. Excluded were (1) studies not providing data on baseline score or end-point outcome, (2) single-subject studies, (3) studies providing only qualitative data, and (4) studies that used a mechanical horse. Sixteen trials were included. The methodologic quality of each study was evaluated using Downs and Black quality assessment tool. Most of the studies showed a trend toward a beneficial effect of therapeutic riding and hippotherapy on balance and gross motor function. The meta-analysis showed improvement in both the Berg Balance Scale and the Gross Motor Function Measure in therapeutic riding and hippotherapy programs. Programs such as therapeutic riding and hippotherapy are a viable intervention option for patients with balance, gait, and psychomotor disorders.

  4. The directors’ roles in containing the Robben Island Diversity Experience (RIDE

    Directory of Open Access Journals (Sweden)

    Frans Cilliers

    2012-01-01

    Full Text Available Orientation: Robben Island represents past denigration and present day liberation. The researchers report on their experiences of containing the learning, consciously and unconsciously, in the Robben Island Diversity Experience.Research purpose: The purpose of the research was to describe the experiences of the directors of RIDE in the last 10 years.Motivation for the study: Of the many and different diversity events that South African organisations present, RIDE is the only systems psycho-dynamically designed and presented event. This research was an effort to explore the nature of the directors’ roles in working with unconscious diversity dynamics in such a provocative venue.Research design, approach and method: The researchers conducted qualitative, descriptive and double hermeneutic research. The various RIDE events served as case studies. The data consisted of researcher field notes collected during the 10 years. Thematic analysis resulted in four themes, for which the researchers formulated working hypotheses. They integrated them into the research hypothesis.Main findings: Four themes emerged. They were the diversity characteristics of the directors as containers, working on the boundary between RIDE and the macro role players, attacks on the programme as container and challenges from participants.Practical/managerial implications: The research highlighted the important roles of directors’ authorisation as a resilience factor in containing RIDE.Contribution/value-add: The research contributed towards the awareness of intergroup relations between role players during diversity dynamic events and of how authorisation cements relationships.

  5. Concentration of cadmium in cacao beans and its relationship with soil cadmium in southern Ecuador.

    Science.gov (United States)

    Chavez, E; He, Z L; Stoffella, P J; Mylavarapu, R S; Li, Y C; Moyano, B; Baligar, V C

    2015-11-15

    Cadmium (Cd) content in cacao beans above a critical level (0.6 mg kg(-1)) has raised concerns in the consumption of cacao-based chocolate. Little is available regarding Cd concentration in soil and cacao in Ecuador. The aim of this study was to determine the status of Cd in both, soils and cacao plants, in southern Ecuador. Soil samples were collected from 19 farms at 0-5, 5-15, 15-30, and 30-50 cm depths, whereas plant samples were taken from four nearby trees. Total recoverable and extractable Cd were measured at the different soil depths. Total recoverable Cd ranged from 0.88 to 2.45 and 0.06 to 2.59, averaged 1.54 and 0.85 mg kg(-1), respectively in the surface and subsurface soils whereas the corresponding values for M3-extractable Cd were 0.08 to 1.27 and 0.02 to 0.33 with mean values of 0.40 and 0.10 mg kg(-1). Surface soil in all sampling sites had total recoverable Cd above the USEPA critical level for agricultural soils (0.43 mg kg(-1)), indicating that Cd pollution occurs. Since both total recoverable and M3-extractable Cd significantly decreased depth wise, anthropogenic activities are more likely the source of contamination. Cadmium in cacao tissues decreased in the order of beans>shell>leaves. Cadmium content in cacao beans ranged from 0.02 to 3.00, averaged 0.94 mg kg(-1), and 12 out of 19 sites had bean Cd content above the critical level. Bean Cd concentration was highly correlated with M3- or HCl-extractable Cd at both the 0-5 and 5-15 cm depths (r=0.80 and 0.82 for M3, and r=0.78 and 0.82 for HCl; P<0.01). These results indicate that accumulation of Cd in surface layers results in excessive Cd in cacao beans and M3- or HCl-extractable Cd are suitable methods for predicting available Cd in the studied soils. Copyright © 2015 Elsevier B.V. All rights reserved.

  6. Concentration of cadmium in cacao beans and its relationship with soil cadmium in southern Ecuador

    Energy Technology Data Exchange (ETDEWEB)

    Chavez, E. [University of Florida, Institute of Food and Agricultural Science, Indian River Research and Education Center, Fort Pierce, FL 34945 (United States); Escuela Superior Politecnica del Litoral, Centro de Investigaciones Biotecnologicas del Ecuador, Guayaquil, Guayas (Ecuador); He, Z.L., E-mail: zhe@ufl.edu [University of Florida, Institute of Food and Agricultural Science, Indian River Research and Education Center, Fort Pierce, FL 34945 (United States); Stoffella, P.J. [University of Florida, Institute of Food and Agricultural Science, Indian River Research and Education Center, Fort Pierce, FL 34945 (United States); Mylavarapu, R.S. [University of Florida, Institute of Food and Agricultural Science, Soil and Water Science Department, Gainesville, FL 33611 (United States); Li, Y.C. [University of Florida, Institute of Food and Agricultural Science, Tropical Research and Education Center, Homestead, FL 33031 (United States); Moyano, B. [Escuela Superior Politecnica del Litoral, Centro de Investigaciones Biotecnologicas del Ecuador, Guayaquil, Guayas (Ecuador); Baligar, V.C. [United State Department of Agriculture, ARS, Beltsville, MD 20705 (United States)

    2015-11-15

    Cadmium (Cd) content in cacao beans above a critical level (0.6 mg kg{sup −1}) has raised concerns in the consumption of cacao-based chocolate. Little is available regarding Cd concentration in soil and cacao in Ecuador. The aim of this study was to determine the status of Cd in both, soils and cacao plants, in southern Ecuador. Soil samples were collected from 19 farms at 0–5, 5–15, 15–30, and 30–50 cm depths, whereas plant samples were taken from four nearby trees. Total recoverable and extractable Cd were measured at the different soil depths. Total recoverable Cd ranged from 0.88 to 2.45 and 0.06 to 2.59, averaged 1.54 and 0.85 mg kg{sup −1}, respectively in the surface and subsurface soils whereas the corresponding values for M3-extractable Cd were 0.08 to 1.27 and 0.02 to 0.33 with mean values of 0.40 and 0.10 mg kg{sup −1}. Surface soil in all sampling sites had total recoverable Cd above the USEPA critical level for agricultural soils (0.43 mg kg{sup −1}), indicating that Cd pollution occurs. Since both total recoverable and M3-extractable Cd significantly decreased depth wise, anthropogenic activities are more likely the source of contamination. Cadmium in cacao tissues decreased in the order of beans > shell > > leaves. Cadmium content in cacao beans ranged from 0.02 to 3.00, averaged 0.94 mg kg{sup −1}, and 12 out of 19 sites had bean Cd content above the critical level. Bean Cd concentration was highly correlated with M3- or HCl-extractable Cd at both the 0–5 and 5–15 cm depths (r = 0.80 and 0.82 for M3, and r = 0.78 and 0.82 for HCl; P < 0.01). These results indicate that accumulation of Cd in surface layers results in excessive Cd in cacao beans and M3- or HCl-extractable Cd are suitable methods for predicting available Cd in the studied soils. - Highlights: • > 60% of the studied sites had a Cd content in cacao beans above the critical level. • Bean Cd concentration was closely correlated with available Cd in soil. • Soil

  7. Reviews of the environmental effects of pollutants: IV. Cadmium

    Energy Technology Data Exchange (ETDEWEB)

    Hammons, A.S.; Huff, J.E.; Braunstein, H.M.; Drury, J.S.; Shriner, C.R.; Lewis, E.B.; Whitfield, B.L.; Towill, L.E.

    1978-06-01

    This report is a comprehensive, multidisciplinary review of the health and environmental effects of cadmium and specific cadmium derivatives. More than 500 references are cited. The cadmium body burden in animals and humans results mainly from the diet. In the United States, the normal intake of cadmium for adult humans is estimated at about 50 ..mu..g per day. Tobacco smoke is a significant additional source of cadmium exposure. The kidneys and liver together contain about 50% of the total cadmium body burden. Acute cadmium poisoning is primarily an occupational problem, generally from inhalation of cadmium fumes or dusts. In the general population, incidents of acute poisoning by inhaled or ingested cadmium or its compounds are relatively rare. The kidney is the primary target organ for toxicity from prolonged low-level exposure to cadmium. No causal relationship has been established between cadmium exposure and human cancer, although a possible link between cadmium and prostate cancer has been indicated. Cadmium has been shown to be teratogenic in rats, hamsters, and mice, but no such effects have been proven in humans. Cadmium has been reported to increase the frequency of chromosomal aberrations in cultured Chinese hamster ovary cells and in human peripheral leukocytes. The major concern about environmental cadmium is the potential effects on the general population. There is no substantial evidence of hazard from current levels of cadmium in air, water, or food. However, because cadmium is a cumulative poison and because present intake provides a relatively small safety margin, there are adequate reasons for concern over possible future increases in background levels.

  8. Cadmium removal by Lemna minor and Spirodela polyrhiza.

    Science.gov (United States)

    Chaudhuri, Devaleena; Majumder, Arunabha; Misra, Amal K; Bandyopadhyay, Kaushik

    2014-01-01

    The present study investigates the ability of two genus of duckweed (Lemna minor and Spirodela polyrhiza) to phytoremediate cadmium from aqueous solution. Duckweed was exposed to six different cadmium concentrations, such as, 0.5,1.0,1.5, 2.0, 2.5, and 3.0 mg/L and the experiment was continued for 22 days. Water samples were collected periodically for estimation of residual cadmium content in aqueous solution. At the end of treatment period plant samples were collected and accumulated cadmium content was measured. Cadmium toxicity was observed through relative growth factor and changes in chlorophyll content Experimental results showed that Lemna minor and Spirodela polyrhiza were capable of removing 42-78% and 52-75% cadmium from media depending upon initial cadmium concentrations. Cadmium was removed following pseudo second order kinetic model Maximum cadmium accumulation in Lemna minor was 4734.56 mg/kg at 2 mg/L initial cadmium concentration and 7711.00 mg/kg in Spirodela polyrhiza at 3 mg/L initial cadmium concentration at the end of treatment period. Conversely in both cases maximum bioconcentration factor obtained at lowest initial cadmium concentrations, i.e., 0.5 mg/L, were 3295.61 and 4752.00 for Lemna minor and Spirodela polyrhiza respectively. The present study revealed that both Lemna minor and Spirodela polyrhiza was potential cadmium accumulator.

  9. Cigarette Smoke Cadmium Breakthrough from Traditional Filters: Implications for Exposure

    Science.gov (United States)

    Pappas, R. Steven; Fresquez, Mark R.; Watson, Clifford H.

    2015-01-01

    Cadmium, a carcinogenic metal, is highly toxic to renal, skeletal, nervous, respiratory, and cardiovascular systems. Accurate and precise quantification of mainstream smoke cadmium levels in cigarette smoke is important because of exposure concerns. The two most common trapping techniques for collecting mainstream tobacco smoke particulate for analysis are glass fiber filters and electrostatic precipitators. We observed that a significant portion of total cadmium passed through standard glass fiber filters that are used to trap particulate matter. We therefore developed platinum traps to collect the cadmium that passed through the filters and tested a variety of cigarettes with different physical parameters for quantities of cadmium that passed though the filters. We found less than 1% cadmium passed through electrostatic precipitators. In contrast, cadmium that passed through 92 mm glass fiber filters on a rotary smoking machine was significantly higher, ranging from 3.5% to 22.9% of total smoke cadmium deliveries. Cadmium passed through 44 mm filters typically used on linear smoking machines to an even greater degree, ranging from 13.6% to 30.4% of the total smoke cadmium deliveries. Differences in the cadmium that passed through from the glass fiber filters and electrostatic precipitator could be explained in part if cadmium resides in the smaller mainstream smoke aerosol particle sizes. Differences in particle size distribution could have toxicological implications and could help explain the pulmonary and cardiovascular cadmium uptake in smokers. PMID:25313385

  10. The Development of the Model for the Park and Ride System in the Major Lithuanian Cities

    Directory of Open Access Journals (Sweden)

    Vytautas Palevičius

    2014-10-01

    Full Text Available Park and Ride (P&R is the original transport system of public passengers, acting as a traditional supplement of public transport. The system is becoming widely popular in European cities. The central core of this system is composed of parking facilities in the specified parking areas at the approaches to the city with connections to public transport or special buses that allow people reach the city centre. The P&R system is based on a reduction in car density in the city centre as well as on a decrease in traffic noise, air and visual pollution. Furthermore, the P&R system is an economical and time-saving way to travel. This article has been prepared according to structural support provided by the European Union (EU for the purpose of developing the P&R system in five major Lithuanian cities – Vilnius, Kaunas, Klaipeda, Siauliai and Panevezys. Therefore, this paper is aimed at the development and application of the theoretical model of the P&R system to Lithuanian cities according to external good and bad practice.

  11. Exploring the Mode Change Behavior of Park-and-Ride Users

    Directory of Open Access Journals (Sweden)

    Shahi Taphsir Islam

    2015-01-01

    Full Text Available This paper investigates the mode change behavior of park-and-ride (P&R users, which is of considerable significance to analyze the effectiveness of P&R site on the commuters’ travel mode change as well as the increase of public transport mode share. Data from an intercept interview survey conducted at different P&R facilities in Metropolitan Melbourne is used. A questionnaire containing revealed preference (RP and stated preference (SP questions is used to interview the individuals who park at the facility and catch public transport to go to city. This study firstly aims to know the factors affecting current travel behavior using RP data and secondly to investigate the importance of the factors on influencing the commuters’ decision of travel mode choice using the SP data. The empirical models using multinomial logistic regression reveal that travel time taken by transit vehicle and transfer time at P&R stations are the primary factors affecting individuals’ decision on choosing public transport whereas parking fare is the additional factor affecting commuters’ choice of driving. Based on the results of this study, the effectiveness of P&R scheme on commuters’ travel mode change is evaluated which would be helpful to shed lights on the future construction of P&R sites.

  12. A Hyperheuristic for the Dial-a-Ride Problem with Time Windows

    Directory of Open Access Journals (Sweden)

    Enrique Urra

    2015-01-01

    Full Text Available The dial-a-ride problem with time windows (DARPTW is a combinatorial optimization problem related to transportation, in which a set of customers must be picked up from an origin location and they have to be delivered to a destination location. A transportation schedule must be constructed for a set of available vehicles, and several constraints have to be considered, particularly time windows, which define an upper and lower time bound for each customer request in which a vehicle must arrive to perform the service. Because of the complexity of DARPTW, a number of algorithms have been proposed for solving the problem, mainly based on metaheuristics such as Genetic Algorithms and Simulated Annealing. In this work, a different approach for solving DARPTW is proposed, designed, and evaluated: hyperheuristics, which are alternative heuristic methods that operate at a higher abstraction level than metaheuristics, because rather than searching in the problem space directly, they search in a space of low-level heuristics to find the best strategy through which good solutions can be found. Although the proposed hyperheuristic uses simple and easy-to-implement operators, the experimental results demonstrate efficient and competitive performance on DARPTW when compared to other metaheuristics from the literature.

  13. Association of blood cadmium with hypertension in the Korean general population: analysis of the 2008-2010 Korean National Health and Nutrition Examination Survey data.

    Science.gov (United States)

    Lee, Byung-Kook; Kim, Yangho

    2012-11-01

    We present data from the Korean National Health and Nutrition Examination Survey 2008-2010 regarding the association between blood cadmium levels and blood pressure in a representative sample of the adult South Korean population. We restricted the analysis to participants ≥20 years of age who completed the health examination survey, including blood cadmium measurements (n = 5,919). We performed multivariate linear regression analyses to estimate adjusted mean differences in diastolic and systolic blood pressure associated with doubling of, or quartiles of, cadmium levels after covariate adjustment. We calculated odds ratios (ORs) for hypertension and prehypertension for log-transformed blood cadmium levels and quartiles thereof after covariate adjustment. We observed a twofold increase in blood cadmium associated with 0.755 and 1.007 mmHg increases in diastolic pressure in women and men, respectively. We observed 2.243 and 1.975 mmHg increases in diastolic pressure in women and men, respectively, in the highest compared with the lowest quartile of blood cadmium. Systolic pressure showed results similar to those of diastolic pressure. Based on ORs, a doubling of blood cadmium resulted in 18.6% and 31.5% increases in the risk of hypertension in women and men, respectively. Doubling of blood cadmium resulted in a 23.5% and 22.9% increase in the risk of prehypertension in women and men, respectively. We found a significant association between blood cadmium levels and elevated blood pressure regardless of the type of variable (continuous or categorical) in women and men with a lower blood cadmium level compared to previous Korean studies. This study also showed that blood cadmium levels were robust risk factors for prehypertension in both women and men. Copyright © 2012 Wiley Periodicals, Inc.

  14. Dynamic of cadmium accumulation in the internal organs of rats after exposure to cadmium chloride and cadmium sulphide nanoparticules of various sizes

    Directory of Open Access Journals (Sweden)

    Apykhtina O.L.

    2017-06-01

    Full Text Available The article presents the results of study of cadmium accumulation in the internal organs of Wistar rats after prolonged intraperitoneal administration of cadmium chloride and cadmium sulphide nanoparticles of 4-6 nm and 9-11 nm in size in a dose of 0.08 mg /kg/day calculated as cadmium. Toxic effects were evaluated after 30 injections (1.5 months, 60 injections (3 months, and 1.5 months after the exposure has been ceased. The results of the study showed that the most intensive accumulation of cadmium was observed in the kidneys and liver of experimental animals, which is due to the peculiarities of the toxicokinetics and the route of administration of cadmium compounds. In the kidneys, spleen and thymus of animals exposed to cadmium sulphide nanoparticles, a greater concentration of cadmium than in the organs of animals exposed to cadmium chloride was found. Cadmium accumulated more intensively in the spleen after exposure to larger nanoparticles, than in the kidneys and thymus. In the liver, heart, aorta and brain significant accumulation was observed after cadmium chloride exposure.

  15. Cadmium exposure induces hematuria in Korean adults

    Energy Technology Data Exchange (ETDEWEB)

    Han, Seung Seok [Department of Internal Medicine, Seoul National University College of Medicine, Seoul 110-744 (Korea, Republic of); Kim, Myounghee, E-mail: dkkim73@gmail.com [Department of Dental Hygiene, College of Health Science, Eulji University, Gyeonggi-do 461-713 (Korea, Republic of); Lee, Su Mi [Department of Internal Medicine, Seoul National University College of Medicine, Seoul 110-744 (Korea, Republic of); Lee, Jung Pyo [Department of Internal Medicine, Seoul National University Boramae Medical Center, Seoul 156-707 (Korea, Republic of); Kim, Sejoong [Department of Internal Medicine, Seoul National University Bundang Hospital, Gyeonggi-do 463-707 (Korea, Republic of); Joo, Kwon Wook [Department of Internal Medicine, Seoul National University College of Medicine, Seoul 110-744 (Korea, Republic of); Lim, Chun Soo [Department of Internal Medicine, Seoul National University Boramae Medical Center, Seoul 156-707 (Korea, Republic of); Kim, Yon Su; Kim, Dong Ki [Department of Internal Medicine, Seoul National University College of Medicine, Seoul 110-744 (Korea, Republic of)

    2013-07-15

    Introduction: Toxic heavy metals have adverse effects on human health. However, the risk of hematuria caused by heavy metal exposure has not been evaluated. Methods: Data from 4701 Korean adults were obtained in the Korean National Health and Nutritional Examination Survey (2008–2010). Blood levels of the toxic heavy metals cadmium, lead, and mercury were measured. Hematuria was defined as a result of ≥+1 on a urine dipstick test. The odds ratios (ORs) for hematuria were measured according to the blood heavy metal levels after adjusting for multiple variables. Results: Individuals with blood cadmium levels in the 3rd and 4th quartiles had a greater OR for hematuria than those in the 1st quartile group: 3rd quartile, 1.35 (1.019–1.777; P=0.037); 4th quartile, 1.52 (1.140–2.017; P=0.004). When blood cadmium was considered as a log-transformed continuous variable, the correlation between blood cadmium and hematuria was significant: OR, 1.97 (1.224–3.160; P{sub trend}=0.005). In contrast, no significant correlations between hematuria and blood lead or mercury were found in the multivariate analyses. Discussion: The present study shows that high cadmium exposure is associated with a risk of hematuria. -- Highlights: • A high level of blood cadmium is associated with a high risk of hematuria. • This correlation is independent of several confounding factors. • Blood levels of lead and mercury are not associated with risk of hematuria. • This is the first study on the correlation between cadmium exposure and hematuria risk.

  16. Toxicity of cadmium to the developing lung

    Energy Technology Data Exchange (ETDEWEB)

    Daston, G.P.

    1981-01-01

    The effects of cadmium on the developing lung and pulmonary surfactant were studied. Pregnant rats received subcutaneous injections of cadmium chloride on days 12 to 15 of gestation and were sacrificed throughout late gestation. The treatment resulted in high embryonic mortality and growth regardation. Fetal lung weight was reduced 20 to 30% due to hypoplasia, as the number of lung cells (DNA/lung) but not cell size (protein/cell) was lowered. The ultrastructural development of alveolar epithelium was altered; cytodifferentiation was delayed; and the cytoplasmic inclusions which contain pulmonary surfactant, were reduced in the term fetus. Accumulation of phosphatidylcholine (PC), the major component of pulmonary surfactant, was diminished in the lungs of treated fetuses. The immediate cause of this lowered accumulation was a decreased rate of synthesis of PC from choline. Carbohydrates probably represent a major source of PC precursors and are present in large quantities in the fetal lung as glycogen. The pulmonary glycogen content of cadmium-exposed fetuses was diminished. It is postulated that this is a reason for the lowered rate of PC synthesis. Maternally administered cadmium did not pass through the placenta; thus, the mechanism of fetotoxicity was indirect. Maternal cadmium exposure did result in lowered fetal zinc levels. Coadministration of zinc with cadmium raised fetal zinc concentration to control values and alleviated all fetotoxicity. Fetal zinc deficiency is a possible mechanism for the toxic effects on the developing lung. Several dams were allowed to give birth and their offspring were observed for respiratory problems. Cadmium treatment delayed parturition by about a day. Symptoms of respiratory distress syndrome (RDS) were observed in 11% of the treated neonates. All but one of these individuals died and had lungs with hyaline membranes. This is the only known case of an environmental agent causing neonatal RDS.

  17. Uptake of cadmium from hydroponic solutions by willows ( Salix spp ...

    African Journals Online (AJOL)

    Salix integra 'Weishanhu') and Yizhibi (S. integra 'Yizhibi') were chosen as model plants to evaluate their potential for uptake of cadmium from hydroponic culture and relative uptake mechanism. Cadmium uptake showed a linear increase in the ...

  18. SUBSTITUTION OF CADMIUM CYANIDE ELECTROPLATING WITH ZINC CHLORIDE ELECTROPLATING

    Science.gov (United States)

    The study evaluated the zinc chloride electroplating process as a substitute for cadmium cyanide electroplating in the manufacture of industrial connectors and fittings at Aeroquip Corporation. The process substitution eliminates certain wastes, specifically cadmium and cyanide, ...

  19. Genotoxic Effect of Atrazine, Arsenic, Cadmium and Nitrate ...

    African Journals Online (AJOL)

    ATZ), Cadmium (Cd), Arsenic (As) and Nitrate (NO3) have both estrogenic activity and carcinogenic potential. Atrazine has clastogenic effects and may also act as tumor promoter as it induces the aromatase enzyme. Arsenic and Cadmium ...

  20. Hybrid column generation and large neighborhood search for the dial-a-ride problem

    Science.gov (United States)

    Parragh, Sophie N.; Schmid, Verena

    2013-01-01

    Demographic change towards an ever aging population entails an increasing demand for specialized transportation systems to complement the traditional public means of transportation. Typically, users place transportation requests, specifying a pickup and a drop off location and a fleet of minibuses or taxis is used to serve these requests. The underlying optimization problem can be modeled as a dial-a-ride problem. In the dial-a-ride problem considered in this paper, total routing costs are minimized while respecting time window, maximum user ride time, maximum route duration, and vehicle capacity restrictions. We propose a hybrid column generation and large neighborhood search algorithm and compare different hybridization strategies on a set of benchmark instances from the literature. PMID:23471127

  1. Fault Ride-Through of a Grid-connected Photovoltaic System with Quasi Z Source Inverter

    DEFF Research Database (Denmark)

    Al-Durra, Ahmed; Fayyad, Yara; Muyeen, S.M.

    2016-01-01

    This article presents fault ride-through schemes for a three-phase quasi Z source single-stage photovoltaic (PV) inverter that is connected to the grid after the distribution network. The quasi Z source inverter employs a unique LC network to couple the inverter main circuit to the input of the PV...... panel. By controlling the shoot-through duty cycle, the quasi Z source inverter can theoretically produce any desired output AC voltage, even greater than the line voltage. Three different control strategies to improve the low-voltage ride-through capability are proposed when there is voltage sag from...... the grid side so that the grid fault ride-through requirements can be fulfilled. Scheme A involves control modification in the system; Schemes B and C involve hardware modification in the circuit topology by adding a chopper circuit across the DC link in Scheme B and across the quasi Z source inverter...

  2. Histopathological assessment and inflammatory response in the digestive gland of marine mussel Mytilus galloprovincialis exposed to cadmium-based quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Thiago Lopes [CIMA, Faculty of Science and Technology, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Laboratory of Cellular Behavior, Biological Sciences Institute, Federal University of Goiás, Goiânia, Goiás (Brazil); Sabóia-Morais, Simone Maria Teixeira [Laboratory of Cellular Behavior, Biological Sciences Institute, Federal University of Goiás, Goiânia, Goiás (Brazil); Bebianno, Maria João, E-mail: mbebian@ualg.pt [CIMA, Faculty of Science and Technology, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal)

    2016-08-15

    Highlights: • Digestive gland of marine mussels is target for Cd-based QDs toxicity. • Both Cd forms increase the frequency of atrophic digestive tubules in a time dependent pattern. • QDs induce higher inflammatory responses when compared to dissolved Cd. • Multiparametric tissue-levels biomarkers show distinct mode of action in the digestive gland. - Abstract: Although tissue-level biomarkers have been widely applied in environmental toxicology studies, the knowledge using this approach in marine invertebrates exposed to engineered nanomaterials (ENMs) remains limited. This study investigated histopathological alterations and inflammatory responses induced by Cd-based quantum dots (QDs), in comparison with their dissolved counterparts, in the marine mussel Mytilus galloprovincialis. Mussels were exposed to CdTe QDs and dissolved Cd at the same concentration (10 μg Cd L{sup −1}) for 14 days and a total of 15 histopathological alterations and 17 histomorphometric parameters were analysed in the digestive gland along with the determination of histopathological condition indices (I{sub h}). A multivariate analysis showed that the mussel response to QDs was more related to exposure time, inflammatory conditions (frequency of haemocytic infiltration and granulocytomas) and changes of cell-type composition (especially the rate between basophilic and digestive cells) when compared to dissolved Cd, while the response to dissolved Cd was associated with histomorphometric parameters of the epithelium and lumen of digestive tubules and increase of the atrophic tubule frequency. Both Cd forms induced higher I{sub h} compared to unexposed mussels indicating a significant decrease in the health status of digestive gland in a Cd form and time-dependent pattern. Results indicate that the multiparametric tissue-level biomarkers in the digestive gland provide a suitable approach to assess the ecotoxicity and mode of action of metal-based ENMs in marine bivalves.

  3. Etude des conditions de confinement du plomb et du cadmium dans des verres à base de métaphosphates de zinc

    OpenAIRE

    El Hadrami, Abdelouahab

    2003-01-01

    This study fits into the investigation of new phosphate glasses with optimal physical and chemical properties as part of storage of heavy toxic metals such as Pb and Cd. Glasses using (100-x) (50P2O5-15ZnO-35PbO)-xFe2O3 and (100-z) [50P2O5-15ZnO-(35-y)PbO-yCdO]-zAl2O3, mol%, batch composition have been synthesized. The addition of iron and aluminium oxides in the based phosphate glasses induces an improvement of the properties, in particular the aqueous corrosion resistance, which is comparab...

  4. Studies on voltammetric determination of cadmium in samples containing native and digested proteins

    Energy Technology Data Exchange (ETDEWEB)

    Drozd, Marcin; Pietrzak, Mariusz, E-mail: mariusz@ch.pw.edu.pl; Malinowska, Elżbieta

    2014-03-01

    Highlights: • Proteins exhibit diverse impact on the DPASV cadmium signals. • Proteins subjected to HNO{sub 3} introduce less interference, than the native ones. • Optimal amount of SDS depends on the kind of protein. • Presence of thiolated coating agents of QDs do not influence the analysis. - Abstract: This work focuses on determination of cadmium ions using anodic stripping voltammetry (ASV) on thin film mercury electrode in conditions corresponding to those obtained after digestion of cadmium-based quantum dots and their conjugates. It presents the impact of selected proteins, including potential receptors and surface blocking agents on the voltammetric determination of cadmium. Experiments regarding elimination of interferences related to proteins presence using sodium dodecyl sulfate (SDS) are also shown. Effect of SDS on selected analytical parameters and simplicity of analyses carried out was investigated in the framework of current studies. The significant differences of influence among tested proteins on ASV cadmium determination, as well as the variability in SDS effectiveness as the antifouling agent were observed and explained. This work is especially important for those, who design new bioassays and biosensors with a use of quantum dots as electrochemical labels, as it shows what problems may arise from presence of native and digested proteins in tested samples.

  5. The social context of motorcycle riding and the key determinants influencing rider behavior: a qualitative investigation.

    Science.gov (United States)

    Tunnicliff, Deborah; Watson, Barry; White, Katherine M; Lewis, Ioni; Wishart, Darren

    2011-08-01

    Given the increasing popularity of motorcycle riding and heightened risk of injury or death associated with being a rider, this study explored rider behavior as a determinant of rider safety and, in particular, key beliefs and motivations that influence such behavior. To enhance the effectiveness of future education and training interventions, it is important to understand riders' own views about what influences how they ride. Specifically, this study sought to identify key determinants of riders' behaviors in relation to the social context of riding, including social and identity-related influences relating to the group (group norms and group identity) as well as the self (moral/personal norm and self-identity). Qualitative research was undertaken via group discussions with motorcycle riders (n = 41). The findings revealed that those in the group with which one rides represent an important source of social influence. Also, the motorcyclist (group) identity was associated with a range of beliefs, expectations, and behaviors considered to be normative. Exploration of the construct of personal norm revealed that riders were most cognizant of the "wrong things to do" when riding; among those issues raised was the importance of protective clothing (albeit for the protection of others and, in particular, pillion passengers). Finally, self-identity as a motorcyclist appeared to be important to a rider's self-concept and was likely to influence on-road behavior. Overall, the insight provided by the current study may facilitate the development of interventions including rider training as well as public education and mass media messages. The findings suggest that these interventions should incorporate factors associated with the social nature of riding in order to best align it with some of the key beliefs and motivations underpinning riders' on-road behaviors.

  6. Calling, texting, and searching for information while riding a motorcycle: A study of university students in Vietnam.

    Science.gov (United States)

    Truong, Long T; De Gruyter, Chris; Nguyen, Hang T T

    2017-08-18

    The objective of this study was to investigate the prevalence of calling, texting, and searching for information while riding a motorcycle among university students and the influences of sociodemographic characteristics, social norms, and risk perceptions on these behaviors. Students at 2 university campuses in Hanoi and Ho Chi Minh City, the 2 largest cities in Vietnam, were invited to participate in an anonymous online survey. Data collection was conducted during March and May 2016. There were 741 respondents, of whom nearly 90% of students (665) were motorcycle riders. Overall prevalence of mobile phone use while riding is 80.9% (95% confidence interval [CI], 77.9-83.9%) with calling having a higher level of prevalence than texting or searching for information while riding: 74% (95% CI, 70.7-77.3%) vs. 51.7% (95% CI, 47.9-55.5%) and 49.9% (95% CI, 46.1-53.7%), respectively. Random parameter ordered probit modeling results indicate that mobile phone use while riding is associated with gender, motorcycle license duration, perceived crash risk, perceived risk of mobile phone snatching, and perceptions of friends' mobile phone use while riding. Mobile phone use while riding a motorcycle is highly prevalent among university students. Educational programs should focus on the crash and economic risk of all types of mobile phone use while riding, including calling, texting, and searching for information. In addition, they should consider targeting the influence of social norms and peers on mobile phone use while riding.

  7. Are all-terrain vehicle riders willing to pay trail user fees to ride on public lands in the USA?

    Science.gov (United States)

    Stephanie A. Snyder; Robert A. Smail

    2009-01-01

    Some public lands in the USA offer opportunities for all-terrain vehicle (ATV) riding, but few charge trail use fees. In a case study in the US state of Wisconsin, the contingent valuation method was used to examine riders' willingness to pay (WTP) to ride on public lands. Information on riders' habits, preferences and responses to a dichotomous choice WTP...

  8. Outcomes of Home-Support Consultation on the Maintenance of Bicycle-Riding Skills for Youth with Autism Spectrum Disorder

    Science.gov (United States)

    Reynolds, Jennifer L.; Pitchford, E. Andrew; Hauck, Janet L.; Ketcheson, Leah R.; Ulrich, Dale A.

    2016-01-01

    Bicycle riding is a functional motor skill that increases physical activity opportunities, social interaction, and independence. However, bicycle riding is difficult for youth with autism spectrum disorder (ASD) to learn. This study examined the effectiveness of home-support consultation (HSC) on increasing the maintenance of independent bicycle…

  9. Subcellular partitioning kinetics, metallothionein response and oxidative damage in the marine mussel Mytilus galloprovincialis exposed to cadmium-based quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Thiago Lopes [CIMA, Faculty of Science and Technology, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Gomes, Tânia [CIMA, Faculty of Science and Technology, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Norwegian Institute for Water Research (NIVA), Gaustadalléen 21, NO-0349 Oslo (Norway); Durigon, Emerson Giuliani [CIMA, Faculty of Science and Technology, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Bebianno, Maria João, E-mail: mbebian@ualg.pt [CIMA, Faculty of Science and Technology, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal)

    2016-06-01

    The environmental health impact of metal-based nanomaterials is of emerging concern, but their metabolism and detoxification pathways in marine bioindicator species remain unclear. This study investigated the role of subcellular partitioning kinetics, metallothioneins (MTs) response and oxidative damage (lipid peroxidation – LPO) in the marine mussel Mytilus galloprovincialis exposed to CdTe quantum dots (QDs) in comparison with its dissolved counterpart. Mussels were exposed to QDs and dissolved Cd for 21 days at 10 μg Cd L{sup −1} followed by a 50 days depuration. Higher Cd concentrations were detected in fractions containing mitochondria, nucleus and lysosomes, suggesting potential subcellular targets of QDs toxicity in mussel tissues. Tissue specific metabolism patterns were observed in mussels exposed to both Cd forms. Although MT levels were directly associated with Cd in both forms, QDs subcellular partitioning is linked to biologically active metal (BAM), but no increase in LPO occurred, while in the case of dissolved Cd levels are in the biologically detoxified metal (BDM) form, indicating nano-specific effects. Mussel gills showed lower detoxification capability of QDs, while the digestive gland is the major tissue for storage and detoxification of both Cd forms. Both mussel tissues were unable to completely eliminate the Cd accumulated in the QDs form (estimated half-life time > 50 days), highlighting the potential source of Cd and QDs toxicity for human and environmental health. Results indicate tissue specific metabolism patterns and nano-specific effects in marine mussel exposed to QDs. - Highlights: • Subcellular partitioning and MT response are Cd form, tissue and time dependent. • Tissue specific metabolism of Cd-based quantum dots (QDs) in marine mussels. • QDs are slower biologically detoxified when compared to dissolved Cd. • Subcellular partitioning and biomarker responses indicate nano-specific effects. • Subcellular

  10. Non conventional psychiatric rehabilitation in schizophrenia using therapeutic riding: the FISE multicentre Pindar project

    Directory of Open Access Journals (Sweden)

    Stefania Cerino

    2011-12-01

    Full Text Available The FISE (Federazione Italiana Sport Equestri Pindar is a multicentre research project aimed at testing the potential effects of therapeutic riding on schizophrenic patients. Twenty-four subjects with a diagnosis of schizophrenia were enrolled for a 1 year-treatment involving therapeutic riding sessions. All subjects were tested at the beginning and at the end of treatment with a series of validated test batteries (BPRS and 8 items-PANSS. The results discussed in this paper point out an improvement in negative symptoms, a constant disease remission in both early onset and chronic disease subjects, as well as a reduced rate of hospitalization.

  11. A Comparison Study on the Assessment of Ride Comfort for LRT Passengers

    Science.gov (United States)

    Tengku Munawir, Tengku Imran; Abqari Abu Samah, Ahmad; Afiq Akmal Rosle, Muhammad; Azlis-Sani, Jalil; Hasnan, Khalid; Sabri, S. M.; Ismail, S. M.; Yunos, Muhammad Nur Annuar Mohd; Yen Bin, Teo

    2017-08-01

    Ride comfort in railway transportation is very mind boggling and it relies on different dynamic performance criteria as well as subjective observation from the train passengers. Vibration discomfort from different elements such as vehicle condition, track area condition and working condition can prompt poor ride comfort. However, there are no universal applicable standards to analyse the ride comfort. There are several factors including local condition, vehicle condition and the track condition. In this current work, level of ride comfort by previous Adtranz-Walker light rapid transit (LRT) passengers at Ampang line were analysed. A comparison was done via two possible methods which are BS EN 12299 (2009) and Sperling’s Ride Index equation. BS EN 12299 standard is used to measure and evaluate the ride comfort of seating (Nvd) and standing (Nva) of train passenger in three different routes. Next, Sperling’s ride comfort equation is used to conduct validation and comparison between the obtained data. The result indicates a higher extent of vibration in the vertical axis which impacts the overall result. The standing position demonstrates a higher exposure of vibration in all the three tested routes. Comparison of the ride comfort assessment of passenger in sitting and standing position for both methods indicates that all the track sections exceeds “pronounced but not unpleasant (medium)” limit range. Nevertheless, the seating position at track section AU did not exceed the limit and stayed at the comfortable zone. The highest discomfort level achieved for both methods for seating position are 3.34 m/s2 for Nva and 2.63 m/s2 respectively, which is at route C uptrack that is from Chan Sow Lin station to Sri Petaling station. Meanwhile, the highest discomfort level achieved for both methods for standing are 3.80 m/s2 for Nvd and 2.88 m/s2 for Wz respectively, at uptrack section which is from Sri Petaling station to Chan Sow Lin station. Thus, the highest

  12. Cadmium recycling in the United States in 2000

    Science.gov (United States)

    Plachy, Jozef

    2003-01-01

    Recycling of cadmium is a young and growing industry that has been influenced by environmental concerns and regulatory constraints. Domestic recycling of cadmium began in 1989 as a byproduct of processing of spent nickel-cadmium batteries. In 1995, International Metals Reclamation Co. Inc. expanded its operations by building a dedicated cadmium recycling plant. In 2000, an estimated 13 percent of cadmium consumption in the United States was sourced from recycled cadmium, which is derived mainly from old scrap or, to lesser degree, new scrap. The easiest forms of old scrap to recycle are small spent nickel-cadmium batteries followed by flue dust generated during recycling of galvanized steel and small amounts of alloys that contain cadmium. Most of new scrap is generated during manufacturing processes, such as nickel-cadmium battery production. All other uses of cadmium are in low concentrations and, therefore, difficult to recycle. Consequently, much of this cadmium is dissipated and lost. The amount of cadmium in scrap that was unrecovered in 2000 was estimated to be 2,030 metric tons, and an estimated 285 tons was recovered. Recycling efficiency was estimated to be about 15 percent.

  13. Cadmium uptake by the green alga Chlorella emersonii | Arikpo ...

    African Journals Online (AJOL)

    Investigations were carried out on the uptake of the heavy metal cadmium (Cd) by the green alga Chlorella emersonii with the aid of an ion selective electrode. Cadmium uptake by Chlorella was very rapid with 70% of total uptake occurring during the first 10 seconds. Uptake of cadmium by Chlorella showed a direct ...

  14. Cadmium affects the social behaviour of rainbow trout, Oncorhynchus mykiss

    Energy Technology Data Exchange (ETDEWEB)

    Sloman, Katherine A.; Scott, Graham R.; Diao Zhongyu; Rouleau, Claude; Wood, Chris M.; McDonald, D. Gord

    2003-10-29

    The present study investigated both the effects of cadmium on the social interactions of rainbow trout and the differential accumulation of waterborne cadmium among social ranks of fish. Fish exposed to waterborne cadmium concentrations of 2 {mu}g l{sup -1} for 24 h, followed by a 1, 2 or 3 day depuration period in clean water, had a decreased ability to compete with non-exposed fish. However, the competitive ability of exposed fish given a 5 day depuration period was not significantly impaired. Cadmium accumulated in the olfactory apparatus of fish exposed to waterborne cadmium for 24 h and decreased significantly only after 5 days depuration in clean water. Among groups of ten fish held in stream tanks, where all fish were exposed to cadmium, there were significant effects on social behaviour and growth rate. Dominance hierarchies formed faster among fish exposed to cadmium than among control fish, and overall growth rates were higher in the cadmium treatment. In groups of ten fish, social status also affected tissue accumulation of cadmium during waterborne exposure, with dominant fish accumulating more cadmium at the gill. In conclusion, exposure to low levels of cadmium, affects the social behaviour of fish, in part due to accumulation in the olfactory apparatus, and dominant fish accumulate more gill cadmium than subordinates during chronic waterborne exposure.

  15. Flame atomic absorption spectrometric determination of trace quantities of cadmium in water samples after cloud point extraction in Triton X-114 without added chelating agents

    Energy Technology Data Exchange (ETDEWEB)

    Afkhami, Abbas [Department of Chemistry, Faculty of Science, Bu-Ali Sina University, Hamadan (Iran, Islamic Republic of)]. E-mail: afkhami@basu.ac.ir; Madrakian, Tayyebeh [Department of Chemistry, Faculty of Science, Bu-Ali Sina University, Hamadan (Iran, Islamic Republic of); Siampour, Hajar [Department of Chemistry, Faculty of Science, Bu-Ali Sina University, Hamadan (Iran, Islamic Republic of)

    2006-11-16

    A new micell-mediated phase separation method for preconcentration of ultra-trace quantities of cadmium as a prior step to its determination by flame atomic absorption spectrometry has been developed. The method is based on the cloud point extraction (CPE) of cadmium in iodide media with Triton X-114 in the absence of any chelating agent. The optimal extraction and reaction conditions (e.g., acid concentration, iodide concentration, effect of time) were studied, and the analytical characteristics of the method (e.g., limit of detection, linear range, preconcentration, and improvement factors) were obtained. Linearity was obeyed in the range of 3-300 ng mL{sup -1} of cadmium. The detection limit of the method is 1.0 ng mL{sup -1} of cadmium. The interference effect of some anions and cations was also tested. The method was applied to the determination of cadmium in tap water, waste water, and sea water samples.

  16. Flame atomic absorption spectrometric determination of trace quantities of cadmium in water samples after cloud point extraction in Triton X-114 without added chelating agents.

    Science.gov (United States)

    Afkhami, Abbas; Madrakian, Tayyebeh; Siampour, Hajar

    2006-11-16

    A new micell-mediated phase separation method for preconcentration of ultra-trace quantities of cadmium as a prior step to its determination by flame atomic absorption spectrometry has been developed. The method is based on the cloud point extraction (CPE) of cadmium in iodide media with Triton X-114 in the absence of any chelating agent. The optimal extraction and reaction conditions (e.g., acid concentration, iodide concentration, effect of time) were studied, and the analytical characteristics of the method (e.g., limit of detection, linear range, preconcentration, and improvement factors) were obtained. Linearity was obeyed in the range of 3-300 ng mL(-1) of cadmium. The detection limit of the method is 1.0 ng mL(-1) of cadmium. The interference effect of some anions and cations was also tested. The method was applied to the determination of cadmium in tap water, waste water, and sea water samples.

  17. Horseback Riding Improves the Ability to Cause the Appropriate Action (Go Reaction) and the Appropriate Self-control (No-Go Reaction) in Children

    OpenAIRE

    Ohtani, Nobuyo; Kitagawa, Kenji; Mikami, Kinuyo; Kitawaki, Kasumi; Akiyama, Junko; Fuchikami, Maho; Uchiyama, Hidehiko; Ohta, Mitsuaki

    2017-01-01

    Background There are many obvious health benefits to riding, including developing a strong core and legs, but there are also many less obvious benefits, such as increased confidence and introspection. Few studies have addressed the effects of horseback riding on children and the mechanisms underlying how riding affects humans. We examined the effects of horseback riding on the ability to distinguish Go/No-go tasks and solve arithmetic problems in children. Methods The subjects were...

  18. Cobalt- and Cadmium-Based Metal-Organic Frameworks as High-Performance Anodes for Sodium Ion Batteries and Lithium Ion Batteries.

    Science.gov (United States)

    Dong, Caifu; Xu, Liqiang

    2017-03-01

    Two multifunctional metal-organic frameworks (MOFs) with the same coordination mode, [Co(L)(H2O)]n·2nH2O [defined as "Co(L) MOF"] and [Cd(L)(H2O)]n·2nH2O [defined as "Cd(L) MOF"] (L = 5-aminoisophthalic acid) have been fabricated via a simple and versatile scalable solvothermal approach at 85 °C for 24 h. The relationship between the structure of the electrode materials (especially the coordination water and different metal ions) and the electrochemical properties of MOFs have been investigated for the first time. And then the possible electrochemical mechanisms of the electrodes have been studied and proposed. In addition, MOFs/RGO hybrid materials were prepared via ball milling, which demonstrated better electrochemical performances than those of individual Co(L) MOF and Cd(L) MOF. For example, when Co(L) MOF/RGO was applied as anode for sodium ion batteries (SIBs), it retained 206 mA h g-1 after 330 cycles at 500 mA g-1 and 1185 mA h g-1 could be obtained after 50 cycles at 100 mA g-1 for lithium-ion batteries (LIBs). The high-discharge capacity, excellent cyclic stability combined with the facile synthesis procedure enable Co(L) MOF- and Cd(L) MOF-based materials to be prospective anode materials for SIBs and LIBs.

  19. Synthesis and characterization of bioactive zinc(II) and cadmium(II) complexes with new Schiff bases derived from 4-nitrobenzaldehyde and acetophenone with ethylenediamine.

    Science.gov (United States)

    Prakash, Anant; Singh, Bibhesh K; Bhojak, Narendar; Adhikari, Devjani

    2010-08-01

    The new Schiff bases N,N'-bis (4-nitro benzaldehyde) ethylenediamine (L(1)) and N,N'-bis (acetophenone) ethylenediamine (L(2)) and its Zn(II), Cd(II) complexes were synthesized and characterized by different physicochemical studies. Vibrational spectra indicate coordination of metal ion through azomethine nitrogen and acetate/nitrate ions. The presence of water molecule in all the complexes has been supported by TG/DTA studies. Mass spectrum explains the successive degradation of the molecular species in solution and justifies ML complexes. Kinetic and thermodynamic parameters were computed from the thermal data using Coats and Redfern method, which confirm first order kinetics. The bioefficacy of the ligands and their complexes have been examined against the growth of bacteria in vitro to evaluate their antimicrobial potential. The results indicate that the ligand and their metal complexes possess notable antimicrobial properties. X-ray powder diffraction determines the cell parameters of the complexes. Copyright 2010 Elsevier B.V. All rights reserved.

  20. Amalgam Electrode-Based Electrochemical Detector for On-Site Direct Determination of Cadmium(II) and Lead(II) from Soils.

    Science.gov (United States)

    Nejdl, Lukas; Kynicky, Jindrich; Brtnicky, Martin; Vaculovicova, Marketa; Adam, Vojtech

    2017-08-09

    Toxic metal contamination of the environment is a global issue. In this paper, we present a low-cost and rapid production of amalgam electrodes used for determination of Cd(II) and Pb(II) in environmental samples (soils and wastewaters) by on-site analysis using difference pulse voltammetry. Changes in the electrochemical signals were recorded with a miniaturized potentiostat (width: 80 mm, depth: 54 mm, height: 23 mm) and a portable computer. The limit of detection (LOD) was calculated for the geometric surface of the working electrode 15 mm² that can be varied as required for analysis. The LODs were 80 ng·mL-1 for Cd(II) and 50 ng·mL-1 for Pb(II), relative standard deviation, RSD ≤ 8% (n = 3). The area of interest (Dolni Rozinka, Czech Republic) was selected because there is a deposit of uranium ore and extreme anthropogenic activity. Environmental samples were taken directly on-site and immediately analysed. Duration of a single analysis was approximately two minutes. The average concentrations of Cd(II) and Pb(II) in this area were below the global average. The obtained values were verified (correlated) by standard electrochemical methods based on hanging drop electrodes and were in good agreement. The advantages of this method are its cost and time effectivity (approximately two minutes per one sample) with direct analysis of turbid samples (soil leach) in a 2 M HNO₃ environment. This type of sample cannot be analyzed using the classical analytical methods without pretreatment.

  1. Metallomics and NMR-based metabolomics of Chlorella sp. reveal the synergistic role of copper and cadmium in multi-metal toxicity and oxidative stress.

    Science.gov (United States)

    Zhang, Wenlin; Tan, Nicole G J; Fu, Baohui; Li, Sam F Y

    2015-03-01

    Industrial wastewaters often contain high levels of metal mixtures, in which metal mixtures may have synergistic or antagonistic effects on aquatic organisms. A combination of metallomics and nuclear magnetic resonance spectroscopy (NMR)-based metabolomics was employed to understand the consequences of multi-metal systems (Cu, Cd, Pb) on freshwater microalgae. Morphological characterization, cell viability and chlorophyll a determination of metal-spiked Chlorella sp. suggested synergistic effects of Cu and Cd on growth inhibition and toxicity. While Pb has no apparent effect on Chlorella sp. metabolome, a substantial decrease of sucrose, amino acid content and glycerophospholipid precursors in Cu-spiked microalgae revealed Cu-induced oxidative stress. Addition of Cd to Cu-spiked cultures induced more drastic metabolic perturbations, hence we confirmed that Cu and Cd synergistically influenced photosynthesis inhibition, oxidative stress and membrane degradation. Total elemental analysis revealed a significant decrease in K, and an increase in Na, Mg, Zn and Mn concentrations in Cu-spiked cultures. This indicated that Cu is more toxic to Chlorella sp. as compared to Cd or Pb, and the combination of Cu and Cd has a strong synergistic effect on Chlorella sp. oxidative stress induction. Oxidative stress is confirmed by liquid chromatography tandem mass spectrometry analysis, which demonstrated a drastic decrease in the GSH/GSSG ratio solely in Cu-spiked cultures. Interestingly, we observed Cu-facilitated Cd and Pb bioconcentration in Chlorella sp. The absence of phytochelatins and an increment of extracellular polymeric substances (EPS) yields in Cu-spiked cultures suggested that the mode of bioconcentration of Cd and Pb is through adsorption of free metals onto the algal EPS rather than intracellular chelation to phytochelatins.

  2. Preliminary evaluation of the cadmium concentration in seawater of the Salvador City, Brazil

    OpenAIRE

    Korn, Maria das Graças Andrade; Ferreira, Adriana Costa; Costa, Antonio Celso Spinola

    2004-01-01

    p. 77– 83 A method for preconcentration and determination of trace amounts of cadmium in high saline samples is described. It is based on the adsorption of the metal in the activated carbon as complex cadmium(II)–4-(2-pyridylazo-resorcinol) (PAR). The final determination was carried by flame atomic absorption spectrometry (FAAS). The optimization of extraction parameters such as the pH effect, PAR mass, activated carbon mass and shaking time was carried out using a two-level full factorial...

  3. ELECTROKINETIC REMEDIATION STUDY FOR CADMIUM CONTAMINATED SOIL

    Directory of Open Access Journals (Sweden)

    P. Bala Ramudu

    2007-09-01

    Full Text Available This paper presents the results of an experimental research undertaken to evaluate different purging solutions to enhance the removal of cadmium from spiked contaminated field soil by electrokinetic remediation. Three experiments were conducted when soil was saturated with deionised water and subsequently deionised water, ammonium citrate and sodium citrate were used as purging solutions at anode end. One experiment was conducted when the soil was saturated with ammonium citrate and itself was used as the purging solution. Results showed that 49% reduction of cadmium concentration was achieved in the case of soil saturated (washed with ammonium citrate as well as purging solution also was ammonium citrate. The soil pH and washing solutions were the most important factors in controlling the removal of cadmium in electrokinetic remediation process.

  4. Sulphate, more than a nutrient, protects the microalga Chlamydomonas moewusii from cadmium toxicity.

    Science.gov (United States)

    Mera, Roi; Torres, Enrique; Abalde, Julio

    2014-03-01

    Sulphur is an essential macroelement that plays important roles in living organisms. The thiol rich sulphur compounds, such as cysteine, γ-Glu-Cys, glutathione and phytochelatins participate in the tolerance mechanisms against cadmium toxicity. Plants, algae, yeasts and most prokaryotes cover their demand for reduced sulphur by reduction of inorganic sulphate. The aim of this study was to investigate, using a bifactorial experimental design, the effect of different sulphate concentrations in the nutrient solution on cadmium toxicity in the freshwater microalga Chlamydomonas moewusii. Cell growth, kinetic parameters of sulphate utilization and intracellular concentrations of low-molecular mass thiol compounds were determined. A mathematical model to describe the growth of this microalga based on the effects of sulphate and cadmium was obtained. An ANOVA revealed an interaction between them, 16% of the effect sizes was explained by this interaction. A higher amount of sulphate in the culture medium allowed a higher cadmium tolerance due to an increase in the thiol compound biosynthesis. The amount of low-molecular mass thiol compounds, mainly phytochelatins, synthesized by this microalga was significantly dependent on the sulphate and cadmium concentrations; the higher phytochelatin content was obtained in cultures with 4 mg Cd/L and 1mM sulphate. The maximum EC50 value (based on nominal cadmium concentration) reached for this microalga was 4.46 ± 0.42 mg Cd/L when the sulphate concentration added to the culture medium was also 1mM. An increase in the sulphate concentration, in deficient environments, could alleviate the toxic effect of this metal; however, a relative excess is also negative. The results obtained showed a substrate inhibition for this nutrient. An uncompetitive model for sulphate was chosen to establish the mathematical model that links both factors. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. Cadmium telluride quantum dots advances and applications

    CERN Document Server

    Donegan, John

    2013-01-01

    Optical Properties of Bulk and Nanocrystalline Cadmium Telluride, Núñez Fernández and M.I. VasilevskiyAqueous Synthesis of Colloidal CdTe Nanocrystals, V. Lesnyak, N. Gaponik, and A. EychmüllerAssemblies of Thiol-Capped CdTe Nanocrystals, N. GaponikFörster Resonant Energy Transfer in CdTe Nanocrystal Quantum Dot Structures, M. Lunz and A.L. BradleyEmission of CdTe Nanocrystals Coupled to Microcavities, Y.P. Rakovich and J.F. DoneganBiological Applications of Cadmium Telluride Semiconductor Quantum Dots, A. Le Cign

  6. Toxic effects of Cadmium on the garden snail (Helix aspersa)

    Energy Technology Data Exchange (ETDEWEB)

    Russell, L.K. (Northrop Services Inc., Corvallis, OR); DeHaven, J.I.; Botts, R.P.

    1981-05-01

    Spreading treated municipal wastes on agricultural and forest lands is becoming an established method of disposal. However, there is concern about the deleterious effects of toxicants, particularly cadmium, in the sludges. Cadmium concentrations in sewage sludge have been reported as high as 1500 ppM. The work reported here is a part of a larger project to investigate the ecological effects of municipal wastes on forest lands. Snails, Helix aspersa, were chosen to examine the entrance of cadmium into terrestrial food chains. This experiment was designed to determine cadmium accumulation, acute toxicity, and behavioral, reproductive and growth responses with increasing levels of cadmium.

  7. Cadmium-induced immune abnormality is a key pathogenic event in human and rat models of preeclampsia.

    Science.gov (United States)

    Zhang, Qiong; Huang, Yinping; Zhang, Keke; Huang, Yanjun; Yan, Yan; Wang, Fan; Wu, Jie; Wang, Xiao; Xu, Zhangye; Chen, Yongtao; Cheng, Xue; Li, Yong; Jiao, Jinyu; Ye, Duyun

    2016-11-01

    With increased industrial development, cadmium is an increasingly important environmental pollutant. Studies have identified various adverse effects of cadmium on human beings. However, the relationships between cadmium pollution and the pathogenesis of preeclampsia remain elusive. The objective of this study is to explore the effects of cadmium on immune system among preeclamptic patients and rats. The results showed that the cadmium levels in the peripheral blood of preeclamptic patients were significantly higher than those observed in normal pregnancy. Based on it, a novel rat model of preeclampsia was established by the intraperitoneal administration of cadmium chloride (CdCl2) (0.125 mg of Cd/kg body weight) on gestational days 9-14. Key features of preeclampsia, including hypertension, proteinuria, placental abnormalities and small foetal size, appeared in pregnant rats after the administration of low-dose of CdCl2. Cadmium increased immunoglobulin production, mainly angiotensin II type 1-receptor-agonistic autoantibodies (AT1-AA), by increasing the expression of activation-induced cytosine deaminase (AID) in B cells. AID is critical for the maturation of antibody and autoantibody responses. In addition, angiotensin II type 1-receptor-agonistic autoantibody, which emerged recently as a potential pathogenic contributor to PE, was responsible for the deposition of complement component 5 (C5) in kidneys of pregnant rats via angiotensin II type 1 receptor (AT1R) activation. C5a is a fragment of C5 that is released during C5 activation. Selectively interfering with C5a signalling by a complement C5a receptor-specific antagonist significantly attenuated hypertension and proteinuria in Cd-injected pregnant rats. Our results suggest that cadmium induces immune abnormalities that may be a key pathogenic contributor to preeclampsia and provide new insights into treatment strategies of preeclampsia. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Electromagnetic validation of fault-ride through capabilities of wind turbines

    DEFF Research Database (Denmark)

    Arana Aristi, Iván; Garcia-Valle, Rodrigo; Sharma, Ranjan

    2010-01-01

    Scope of the present project is the development and validation of electro-magnetic transient model of fixed-speed wind turbines. The research work is focused on the development of a fixed-speed wind turbine model with fault-ride through capabilities during transient over-voltages. The model...

  9. Edasi tänaste pensionäride kukil! / Janno Reiljan

    Index Scriptorium Estoniae

    Reiljan, Janno, 1951-2018

    2001-01-01

    Riigikogu ja ERL liige Janno Reiljan leiab, et kolmikliidu pensionipoliitika kohaselt hoitakse tulevaste pensionäride jaoks tänaste arvel kokku. Tabel ja diagrammid: SKP võrrelduna keskmise netopalgaga 1999-2008; Rahvaliidu ja kolmikliidu pensionipoliitika võrdlus. Autor: ERL. Parlamendisaadik

  10. The Share-a-Ride problem with stochastic travel times and stochastic delivery locations

    NARCIS (Netherlands)

    Li, Baoxiang; Krushinsky, Dmitry; Van Woensel, Tom; Reijers, Hajo A.

    2016-01-01

    We consider two stochastic variants of the Share-a-Ride problem: one with stochastic travel times and one with stochastic delivery locations. Both variants are formulated as a two-stage stochastic programming model with recourse. The objective is to maximize the expected profit of serving a set of

  11. Therapist-Designed Adaptive Riding in Children With Cerebral Palsy : Results of a Feasibility Study

    NARCIS (Netherlands)

    Angsupaisal, Mattana; Visser, Baudina; Alkema, Anne; Meinsma-van der Tuin, Marja; Maathuis, Carel G. B.; Reinders-Messelink, Heleen; Hadders-Algra, Mijna

    Background. It is debatable whether adaptive riding (AR) in children with cerebral palsy (CP) improves postural control and gross motor development. Objective. The study aim was to explore the feasibility of an extensive assessment protocol for a randomized controlled trial of therapist-designed

  12. Therapeutic Riding for a Student with Multiple Disabilities and Visual Impairment: A Case Study.

    Science.gov (United States)

    Lehrman, Jennifer; Ross, David B.

    2001-01-01

    A 9-year-old with multiple disabilities and visual impairments was the focus of a 10-week developmental therapeutic riding program incorporating hippotherapy. The program has led to increased mobility, an increase in visual attention span and fixation time, signs of greater verbal communication, and the acquisition of new functional signs.…

  13. Low Voltage Ride-Through of Variable Speed Wind Turbines with Permanent Magnet Synchronous Generator

    DEFF Research Database (Denmark)

    Hu, Weihao; Chen, Zhe; Wang, Yue

    2009-01-01

    This paper presents a simulation model of a MW-level variable speed wind turbine with a permanent magnet synchronous generator (PMSG) and a full-scale converter developed in the simulation tool of PSCAD/EMTDC. The low voltage ride-through (LVRT) capability of the wind turbine is investigated. A new...

  14. Travel at low energetic cost by swimming and wave-riding bottlenose dolphins.

    Science.gov (United States)

    Williams, T M; Friedl, W A; Fong, M L; Yamada, R M; Sedivy, P; Haun, J E

    1992-02-27

    Over the past 50 years there has been much speculation about the energetic cost of swimming and wave-riding by dolphins. When aligned properly in front of the bow of moving ships in the stern wake of small boats, on wind waves, and even in the wake of larger cetaceans, the animals appear to move effortlessly through the water without the benefit of propulsive strokes by the flukes. Theoretically, body streamlining as well as other anatomical and behavioural adaptations contribute to low transport costs in these animals. The economy of movement permitted by wave-riding has been perceived as an energetic advantage for the swimming dolphin, but has been hard to prove in the absence of physiological data for exercising cetaceans. Here we determine the aerobic and anaerobic costs of swimming and wave-riding in bottlenose dolphins and find that the minimum cost of transport for swimming dolphins is 1.29 +/- 0.05 J kg-1 m-1 at a cruising speed of 2.1 m s-1. Aerobic costs are nearly twice as high for swimming seals and sea lions, and 8-12 times higher for human swimmers. Wave-riding by dolphins provides additional benefits in terms of speed. The results indicate that behavioural, physiological and morphological factors make swimming an economical form of high-speed travel for dolphins.

  15. Acceleration and Rotation in a Pendulum Ride, Measured Using an iPhone 4

    Science.gov (United States)

    Pendrill, Ann-Marie; Rohlen, Johan

    2011-01-01

    Many modern cell phones have built-in sensors that may be used as a resource for physics education. Amusement rides offer examples of many different types of motion, where the acceleration leads to forces experienced throughout the body. A comoving 3D-accelerometer gives an electronic measurement of the varying forces acting on the rider, but a…

  16. Horses: An Introduction to Horses: Racing, Ranching, and Riding for Blind and Physically Handicapped Individuals.

    Science.gov (United States)

    Cylke, Frank Kurt, Ed.

    This annotated bibliography of materials focuses on horses, racing, ranching, and riding. Two articles are presented in full. They are: "Diary of a Blind Horseman: Confidence Springs from a Horse Named Sun" (Richard Vice and Steve Stone) and "Young Rider: Her Horses Show the Way" (Helen Mason). Each article tells the true story…

  17. Whole-body vibration exposure of occupational horseback riding in agriculture: A ranching example.

    Science.gov (United States)

    Zeng, Xiaoke; Trask, Catherine; Kociolek, Aaron M

    2017-02-01

    Horse riding is common in many occupations; however, there is currently no research evaluating exposure to whole-body vibration and mechanical shock on horseback. Whole-body vibration was measured on a cattle rancher during two 30 min horseback rides using a tri-axial accelerometer mounted on a western saddle. Vibration was summarized into standardized metrics, including the 8 hr equivalent root-mean-squared acceleration (A[8]) and the daily 4th power vibration dose value (VDV). The resulting exposures were compared to the exposure limit and action values provided by European Union Directive 2002/44/EC. The highest vibration for both rides was in the vertical axis, with average A(8) and VDV of 0.56 m/s 2 and 26.24 m/s 1.75 , respectively. The A(8) value indicated moderate risk while the VDV suggested high risk of harmful health effects. Exposure to whole-body vibration and mechanical shock during occupational horseback riding may pose deleterious health risks and increased susceptibility to low back pain. Am. J. Ind. Med. 60:215-220, 2017. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  18. Cardiorespiratory and Biomechanical Responses to Simulated Recreational Horseback Riding in Healthy Children

    Science.gov (United States)

    Rigby, Brandon R.; Papadakis, Zacharias; Bane, Annie A.; Park, Jin K.; Grandjean, Peter W.

    2015-01-01

    Purpose: The purpose of this study was to determine the reliability of cardiorespiratory and pelvic kinematic responses to simulated horseback riding (SHBR) and to characterize responses to SHBR relative to walking in apparently healthy children. Method: Fifteen healthy children (Mage = 9.5 ± 2.6 years) completed SHBR on a commercially available…

  19. Low voltage ride through strategies for SCIG wind turbines in distributed power generation systems

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Teodorescu, Remus; Rodriguez, Pedro

    2008-01-01

    Fulfilling the new grid codes constitutes one of the main challenges for the wind power industry, that is specially concerned about the new fault-ride-through requirements. Enhancing the operation of wind-turbines in front of grid faults is not only an important issue for new wind farms, but also...

  20. How challenging is a riding horse’s life? Field studies on fitness, workload and welfare

    NARCIS (Netherlands)

    Munsters, C.C.B.M.

    2013-01-01

    The objectives of this thesis were to evaluate in practice workload, fitness and welfare of riding horses under work and training conditions. Chapter II presents an overview of the parameters used in earlier studies on training, behaviour and equine welfare, and describes the evaluation of the

  1. Economic analysis of the organisation of a riding centre; application of the linear programming approach

    Directory of Open Access Journals (Sweden)

    Jaka ŽGAJNAR

    2015-12-01

    Full Text Available In this contribution, the economics of an equestrian centre, which in addition to a variety of riding school activities also includes breeding and livery, are analysed. We consider the conditions for a hypothetical holding operating in central Slovenia. Methods of mathematical programming are applied in order to attempt to optimise the holding’s activities. Their use may in the given situation facilitate the evaluation of development prospects from different perspectives and indicate the opportunities of increasing value-added. On the basis of maximizing the gross margin, we try to address the various questions and challenges that arise in managing and planning for such an equestrian centre. The obtained results indicate that breeding is unfavourable in the given price-cost ratio, both for the renewal of the working horses herd and for sale. This reflects the current adverse situation in the field of horse breeding. Livery is an important activity on such holdings and through opportunity perspective provides an optimal set of activities. Activities of the riding school for children are interesting in terms of income diversification, as well as an additional source of revenue. A riding school with one riding instructor and an indoor arena needs 4.6 horses in order to cover the costs of full-time employment.

  2. Overuse Injuries Associated with Mountain Biking: Is Single-Speed Riding a Predisposing Factor?

    Directory of Open Access Journals (Sweden)

    Michael T. Lebec

    2014-01-01

    Full Text Available Though mountain bikers are at significant risk for overuse injury, there is minimal quality research describing this relationship. Single-speed mountain biking, in which participants pedal a bike with only a single gear, may place riders at even greater risk for overuse problems due to the disproportionate physical effort associated with this type of riding. The focus of this study was to provide additional perspective on overuse injuries sustained by mountain bikers and to determine if single-speed mountain biking places participants at greater risk for overuse conditions. Four hundred and four (404 mountain bikers were surveyed concerning overuse injuries sustained during the previous year. Findings indicate that 63% of respondents reported an overuse injury affecting at least one area with the most commonly reported areas being the lumbar spine, knees, hand/wrist, and cervical spine. Individuals riding single-speed mountain bikes did not have a higher incidence of overuse injuries than riders of multiple-geared bikes. However, respondents who split time between riding single-speed and multiple-geared bikes were significantly more likely to report an overuse syndrome than those only riding single-speed or multiple-geared bikes (p = 0.0104. This group of riders may be at greater risk for overuse injury due to excessive fatigue and poor biomechanics.

  3. Models and algorithms for reliability-oriented Dial-a-Ride with autonomous electric vehicles

    NARCIS (Netherlands)

    Pimenta, Victor; Quilliot, Alain; Toussaint, Hélène; Vigo, D.

    2017-01-01

    We consider a static decision model related to the management of a Dial-a-Ride (DAR) system involving small autonomous electrical vehicles in a closed industrial site. Because of the specific features of the system, in this paper we concentrate on its reliability and propose a model that aims at

  4. An equine herpesvirus 1 (EHV1) abortion storm at a riding school

    NARCIS (Netherlands)

    Maanen, van C.; Willink, D.L.; Smeenk, L.A.J.; Brinkhof, J.; Terpstra, C.

    2000-01-01

    An outbreak of EHV1 abortions occurred at a riding school in the Netherlands in 1991. Seven of twelve pregnant mares aborted, and another foal died at 8 days of age. Six abortions occurred within 12 days in March after an initial abortion on 8 February. Four mares delivered live foals. Virological

  5. The Effectiveness of Simulated Developmental Horse-Riding Program in Children with Autism

    Science.gov (United States)

    Wuang, Yee-Pay; Wang, Chih-Chung; Huang, Mao-Hsiung; Su, Chwen-Yng

    2010-01-01

    This study investigated the effectiveness of a 20-week Simulated Developmental Horse-Riding Program (SDHRP) by using an innovative exercise equipment (Joba[R]) on the motor proficiency and sensory integrative functions in 60 children with autism (age: 6 years, 5 months to 8 years, 9 months). In the first phase of 20 weeks, 30 children received the…

  6. Motorcycle riding under the influence of alcohol: results from the SARTRE-4 survey.

    Science.gov (United States)

    Papadimitriou, Eleonora; Theofilatos, Athanasios; Yannis, George; Cestac, Julien; Kraïem, Sami

    2014-09-01

    Riding a motorcycle under the influence of alcohol is a dangerous activity, especially considering the high vulnerability of motorcyclists. The present research investigates the factors that affect the declared frequency of drink-riding among motorcyclists in Europe and explores regional differences. Data were collected from the SARTRE-4 (Social Attitudes to Road Traffic Risk in Europe) survey, which was conducted in 19 countries. A total sample of 4483 motorcyclists was interviewed by using a face-to-face questionnaire. The data were analyzed by means of multilevel ordered logit models. The results revealed significant regional differences (between Northern, Eastern and Southern European countries) in drink-riding frequencies in Europe. In general, declared drinking and riding were positively associated with gender (males), increased exposure, underestimation of risk, friends' behaviour, past accidents and alcohol ticket experience. On the other hand, it was negatively associated with underestimation of the amount of alcohol allowed before driving, and support for more severe penalties. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. User-Side Subsidies for Shared Ride Taxi Service in Danville, Illinois : Phase 1.

    Science.gov (United States)

    1977-06-01

    An UMTA Service and Methods Demonstration has been implemented in Danville, Illinois. The Purpose of the Demonstration is to test the use of a user-side subsidy on a shared ride taxi service for handicapped and elderly persons. This report presents t...

  8. Small City Transit : El Cajon, California : City-Wide Shared-Ride Taxi Service

    Science.gov (United States)

    1976-03-01

    El Cajon, California, is an illustration of a shared ride taxi service. This case study is one of thirteen examples of a transit service in a small community. The background of the community is discussed along with a description of the implementation...

  9. Dietary intake of heavy metals (cadmium, lead and mercury) by the Dutch population

    NARCIS (Netherlands)

    Winter-Sorkina R de; Bakker MI; Donkersgoed G van; Klaveren JD van; RIKILT Wageningen; SIR

    2003-01-01

    The exposure of the Dutch population to cadmium, lead and mercury via food is assessed based on concentration data from 1999-2002 and on consumption data from the third Dutch National Food Consumption Survey. To this end, the dietary intake estimation method using the MCRA (Monte Carlo Risk

  10. Simultaneous Atomic Absorption Spectrometry for Cadmium and Lead Determination in Wastewater: A Laboratory Exercise

    Science.gov (United States)

    Correia, Paulo R. M.; Oliveira, Pedro V.

    2004-01-01

    The simultaneous determination of cadmium and lead by multi-element atomic absorption spectrometry with electrochemical atomization is proposed by employing a problem-based approach. The reports indicate that the students assimilated the principles of the simultaneous atomic absorption spectrometry (SIMAAS), the role of the chemical modifier, the…

  11. Murine strain differences and the effects of zinc on cadmium concentrations in tissues after acute cadmium exposure

    Energy Technology Data Exchange (ETDEWEB)

    King, L.M. [ARS USDA, Germplasm and Gamete Physiology Lab., Beltsville, MD (United States); Anderson, M.B. [Dept. of Anatomy, Tulane Univ. School of Medicine, New Orleans, LA (United States); Sikka, S.C. [Dept. of Urology, Tulane Univ. School of Medicine, New Orleans, LA (United States); George, W.J. [Dept. of Pharmacology, Tulane Univ. School of Medicine, New Orleans, LA (United States)

    1998-10-01

    The role of strain differences in cadmium tissue distribution was studied using sensitive (129/J) and resistant (A/J) mice. These murine strains have previously been shown to differ in their susceptibility to cadmium-induced testicular toxicity. Cadmium concentration was measured in testis, epididymis, seminal vesicle, liver, and kidney at 24 h after cadmium chloride exposure (4, 10, and 20 {mu}mol/kg CdCl{sub 2}). The 129/J mice exhibited a significant increase in cadmium concentration in testis, epididymis, and seminal vesicle at all cadmium doses used, compared to A/J mice. However, cadmium concentrations in liver and kidney were not different between the strains, at any dose, indicating that cadmium uptake is similar in these organs at 24 h. These murine strains demonstrate similar hepatic and renal cadmium uptake but significantly different cadmium accumulation in the reproductive organs at 24 h. The mechanism of the protective effect of zinc on cadmium toxicity was studied by assessing the impact of zinc acetate (ZnAc) treatment on cadmium concentrations in 129/J mice after 24 h. Zinc pretreatment (250 {mu}mol/kg ZnAc), given 24 h prior to 20 {mu}mol/kg CdCl{sub 2} administration, significantly decreased the amount of cadmium in the testis, epididymis, and seminal vesicle of 129/J mice, and significantly increased the cadmium content of the liver after 24 h. Cadmium levels in the kidney were unaffected at this time. Zinc pretreatment also prevented the cadmium-induced decrease in testicular sperm concentration and epididymal sperm motility seen in 129/J mice. These findings suggest that the differences in the two murine strains may be attributed partly to the differential accumulation of cadmium in murine gonads. This may be caused by strain differences in the specificity of cadmium transport mechanisms. The protective role of zinc in cadmium-induced testicular toxicity in the sensitive strain may be due to an interference in the cadmium uptake by susceptible

  12. Unsafe riding practice among electric bikers in Suzhou, China: an observational study.

    Science.gov (United States)

    Yang, Jie; Hu, Yihe; Du, Wei; Powis, Brent; Ozanne-Smith, Joan; Liao, Yilan; Li, Ning; Wu, Ming

    2014-01-15

    Electric bike (E-bike)-related deaths have been increasing rapidly in China and such injuries may be partly attributable to unsafe riding practice. To describe potentially unsafe riding behaviours among electric bikers (E-bikers) and to investigate factors influencing these practices in China. In September 2012, a cross-sectional observation study including a speed measurement component was conducted in Wuzhong (an urban district) and Zhangjiagang (a rural district) of Suzhou, Jiangsu Province, China. Hand-held radar speed metres were used to read travelling speeds of E-bikes and a pro forma observation checklist was used to collect data on road riding practice. Mixed-effect logistic regressions were used to calculate adjusted ORs and 95% CIs for the association between speeding, road rule violations and helmet use and their influencing factors. Among 800 E-bikes with a speed reading, 70.9% exceeded the designed speed limit of 20 km/h. Among a further 20 647 E-bikers observed, 38.3% did not comply with the road rules when entering intersections; and only 2.2% wore helmets. No regional variation was identified between urban and rural areas. Male E-bikers were associated with more speeding and road rule violations, whereas riding a pedal-equipped E-bike was associated with less road rule violations and less helmet use. Unsafe riding practices such as speeding, road rule violations and lack of helmet use were commonplace among E-bikers, especially among men. The study findings indicate that measures aimed at improving E-bike safety are required in China.

  13. Different DMRT3 Genotypes Are Best Adapted for Harness Racing and Riding in Finnhorses.

    Science.gov (United States)

    Jäderkvist Fegraeus, Kim; Johansson, Lisa; Mäenpää, Minna; Mykkänen, Anna; Andersson, Lisa S; Velie, Brandon D; Andersson, Leif; Árnason, Thorvaldur; Lindgren, Gabriella

    2015-01-01

    Previous studies showed a positive effect of the DMRT3 "gait keeper" mutation on harness racing performance in Standardbreds, French-, and Nordic trotters. The mutation has also been shown to influence riding traits in multiple breeds. This study investigated the effect of the DMRT3 mutation on harness racing performance and riding traits in Finnhorses. Finnhorses used for harness racing (n = 180) and for riding (n = 59) were genotyped for the DMRT3 mutation. For the trotters the genotypes were evaluated for association with racing performance (number of starts, victories, placings, earnings, and race times). At 3-6 years of age the AA genotype was superior compared with the CA and CC genotypes. The AA horses had a significantly higher proportion of victories (P = 1.4×10(-6)) and placings (P = 4.1×10(-7)), better race times (P = 0.01), and earned more money (P = 0.009) compared with C-horses. For the Finnhorses used for riding the owners answered a questionnaire to score how well the horse performed the gaits walk, trot, and canter on a scale from 1 to 6. These scores were tested for association with the DMRT3 genotypes. Although AA horses were more successful as racehorses, the CC and CA horses appear more adapted for classical riding disciplines. The AA horses received significantly lower gait scores compared with C-horses for the majority of gaits. Except for rhythm in extended canter (P = 0.05), there were no significant differences between CA and CC horses. This study shows that there are different optimal genotypes for different disciplines and the DMRT3 mutation clearly influences gaits and performance in Finnhorses. © The American Genetic Association. 2015. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  14. Paediatric ride-on mower related injuries and plastic surgical management.

    LENUS (Irish Health Repository)

    Laing, T A

    2011-05-01

    Lawnmower related injuries cause significant morbidity in children and young teenagers. The \\'ride-on\\' mowers which are more powerful than the \\'walk behind\\' mowers are becoming increasingly popular. The incidence and severity of injuries from either type of lawnmower appears to be steadily rising as is the burden placed on local plastic surgical and emergency services in managing the care of these patients. The aims of the study were to demonstrate changing trends in lawnmower-related injuries to children presenting to a single unit over a ten-year period and to identify any association between injury severity and machine subtype (\\'ride-on\\' versus \\'walk-behind\\'). Hospital databases, theatre records and medical case notes were reviewed retrospectively of all patients under the age of 16 treated for lawnmower related injuries over a 10 year period from July 1998 to June 2008. Data gathered included patient demographics, injury site and severity, management (type and number of surgical procedures), length of hospital stay and outcome. Injury severity score was also calculated for each case. Controlling for estimated regional population changes, there was a significant increase in the number of ride-on mower related accidents in the time period 2003-2008, compared to the time period 1998-2003. Ride-on injuries had significantly higher injury severity scores, longer hospital stays and were more likely to involve amputations as compared with walk-behind injuries. Children can sustain significant injuries with unsafe lawnmower use. The current study demonstrates the increasing incidence of ride-on mower related injuries in children and identifies a greater morbidity associated with such injuries. Such presentations place intense demands on local plastic surgical services.

  15. All-terrain vehicle safety knowledge, riding behaviors and crash experience of Farm Progress Show attendees.

    Science.gov (United States)

    Jennissen, Charles A; Harland, Karisa K; Wetjen, Kristel; Hoogerwerf, Pamela; O'Donnell, Lauren; Denning, Gerene M

    2017-02-01

    Although all-terrain vehicles (ATVs) are very popular in rural areas for both recreation and work purposes, the epidemiology of agricultural ATV use remains largely unknown. Farm Progress Show attendees in 2012 (Boone, Iowa) and 2013 (Decatur, Illinois) were surveyed about ATVs, including riding behaviors, crash history, and safety knowledge. Descriptive and comparative analyses were performed (N=635 surveys). Over half of those surveyed lived on a farm and more than 90% had ridden on an ATV. Sixty-one percent rode at least once a week and 39% reported riding almost daily. Males and respondents who lived on farms were significantly more likely to be ATV riders. Regarding unsafe behaviors, >80% of ATV users had ridden with a passenger, 66% had ridden on a public road, and nearly one-half never or almost never wore a helmet. Nearly 40% reported having been in a crash. Multivariable logistic regression analysis of adult respondent's data showed males and younger adults were both more likely to report having crashed. In addition, those reporting riding on public roads (but not having ridden with passengers) were nearly five times more likely and respondents who reported both riding on public roads and having ridden with passengers were approximately eight times more likely to have been in a crash as compared to those not reporting these unsafe behaviors. Safety knowledge did not necessarily correspond with safer behaviors; 80% who knew there should be no passengers on an ATV still had ridden with extra riders. ATV use is prevalent in rural populations and most riders report engaging in unsafe riding behaviors. These findings may be used to inform ATV safety education and training programs targeted toward agricultural communities, with the goal of reducing occupational ATV-related deaths and injuries and their substantial economic costs. Copyright © 2016 Elsevier Ltd and National Safety Council. All rights reserved.

  16. Phytotoxicity of cadmium on peroxidation, superoxide dismutase ...

    African Journals Online (AJOL)

    The results indicated that Cd destroyed the balance of free radical metabolisms, which resulted in increasing malondialdehyde (MDA) content and the relative cell membrane permeability (RMP). The kernel yield and kernel rate per pot showed significant decrease under cadmium stress (P < 0.05). The varieties FengHua3 ...

  17. Combustion synthesis of cadmium sulphide nanomaterials for ...

    Indian Academy of Sciences (India)

    Anion-doped cadmium sulphide nanomaterials have been synthesized by using combustionmethod at normal atmospheric conditions. Oxidant/fuel ratios have been optimized in order to obtain CdS with best characteristics. Formation of CdS and size of crystallite were identified by X-ray diffraction and confirmed by ...

  18. Mobiliteit van cadmium in de bodem

    NARCIS (Netherlands)

    Chardon, W.J.

    1984-01-01

    The adsorption of cadmium by twelve Dutch soils was investigated under widely varying circumstances. The adsorption can be described with the Freundlich equation; the parameters of this equation can be predicted using the properties of the soil (pH, organic carbon and clay

  19. Cadmium versus phosphate in the world ocean

    NARCIS (Netherlands)

    Baar, Hein J.W. de; Saager, Paul M.; Nolting, Rob F.; Meer, Jaap van der

    1994-01-01

    Cadmium (Cd) is one of the best studied trace metals in seawater and at individual stations exhibits a more or less linear relation with phosphate. The compilation of all data from all oceans taken from over 30 different published sources into one global dataset yields only a broad scatterplot of Cd

  20. Enhanced Electrokinetic Remediation of Cadmium Contaminated Soil

    African Journals Online (AJOL)

    In an attempt to remediate contaminated soil, a new technique of purging cadmium from soil is examined by enhanced electrokinetic method. It involves the passage of low level direct current between two electrodes in the soil to remove contaminant. An apparatus consisting of four principal parts; soil cell, electrode ...

  1. ( Rattus norvegicus ) Fed with Dietary Cadmium

    African Journals Online (AJOL)

    Histological changes in the kidney tissues of albino rats (Rattus norvegicus) fed 100mg/kg body weight of cadmium sulphate incorporated as food material has been studied in vivo in an acute toxicological experiment. The behavioural pattern and physical changes in the rats were also investigated. Loss of weight and ...

  2. Combustion synthesis of cadmium sulphide nanomaterials for ...

    Indian Academy of Sciences (India)

    The observed enhanced photocatalytic activity of the CdS nanomaterials for the hydrogen production from water (2120 μmol/h) can be attributed to high crystallinity, low band gap and less exciton recombination due to the C and N doping. Keywords. Cadmium sulphide; combustion synthesis; anion doping; water splitting; ...

  3. REPRODUCTIVE EFFECTS OF TRANSGENERATIONAL CADMIUM EXPOSURE

    Science.gov (United States)

    Japanese medaka (Oryzias latipes) were used to compare the effects of environmentally relevant cadmium (Cd) exposure on reproduction in adult animals previously exposed in ovo or as hatchlings. Adults were raised either from eggs produced during a two week exposure to 0, 1, 5, o...

  4. PHYSIOLOGICAL EFFECTS OF TRANSGENERATIONAL CADMIUM EXPOSURE.

    Science.gov (United States)

    A series of assays were modified or developed to use with small fish species, specifically Japanese medaka (Oryzias latipes). These assays were used to compare the effects of environmentally relevant cadmium (Cd) exposure on indicators of endocrine function in adult animals previ...

  5. Characterization of nanocrystalline cadmium telluride thin films ...

    Indian Academy of Sciences (India)

    Unknown

    tion method, successive ionic layer adsorption and reaction (SILAR), are described. For deposition of CdTe thin films, cadmium ... By conducting several trials optimization of the adsorption, reaction and rinsing time duration for CdTe thin film deposition was ... 3.1 Reaction mechanism. CdTe thin films were grown on micro ...

  6. antioxidants, cadmium-induced toxicity, serum biochemical

    African Journals Online (AJOL)

    Daniel Owu

    (1.51/gm) and selenium (0.25mg) which on their own had little or no effects on the serum basal phosphatases, hormonal and histological stability caused a reversal of the cadmium-induced biochemical, hormonal and histological toxicities of the ..... accessory sex tissues atrophy such as the prostate. (Waalkes et al 1997a).

  7. Rising environmental cadmium levels in developing countries ...

    African Journals Online (AJOL)

    Summary: Cadmium (Cd) is a ubiquitous environmental pollutant of increasing worldwide concern. It is thought to be of greater concern to rapidly industrializing developing countries because of the increasing pace of industrial activities in these countries with increasing consumption and release into the environment.

  8. Cadmium-Free InP/ZnSeS/ZnS Heterostructure-Based Quantum Dot Light-Emitting Diodes with a ZnMgO Electron Transport Layer and a Brightness of Over 10 000 cd m(-2).

    Science.gov (United States)

    Wang, Hung Chia; Zhang, Heng; Chen, Hao Yue; Yeh, Han Cheng; Tseng, Mei Rurng; Chung, Ren Jei; Chen, Shuming; Liu, Ru Shi

    2017-04-01

    Cadmium-free thick-shelled InP/ZnSeS/ZnS quantum dot (QD) was synthesized using the heating-up approach. This quantum dots was used in inverted quantum dots light emitting diode (QLED) devices. The brightness of the inverted QLED device can reach a brightness of over 10 000 cd m(-2) , low turn-on voltage (2.2 V), and high power efficiency (4.32 lm W(-1) ). © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Spinal Cord Injuries in Wave-Riding Sports: The Influence of Environmental and Sport-Specific Factors.

    Science.gov (United States)

    Falconi, Audrey; Flick, David; Ferguson, Jason; Glorioso, John E

    2016-01-01

    Spinal cord injury is a nonfatal, catastrophic consequence of wave-riding sports. With surfing at the core, a multitude of activities have evolved that attempt to harness the power of ocean waves. The unique qualities of each wave-riding sport, in combination with the environmental factors of the ocean, define the risk for potential injuries. As wave-riding sports have become more advanced, athletes continue to push physical barriers. Taller waves are attempted while incorporating aerial maneuvers, all without protective equipment.

  10. Distributed Low Voltage Ride-Through Operation of Power Converters in Grid-Connected Microgrids under Voltage Sags

    DEFF Research Database (Denmark)

    Zhao, Xin; Meng, Lexuan; Dragicevic, Tomislav

    2015-01-01

    it can make the MG a contributor in smooth ride through the faults. In this paper, a reactive power support strategy using droop controlled converters is proposed to aid MG riding through three phase symmetrical voltage sags. In such a case, the MGs should inject reactive power to the grid to boost...... the voltage in all phases at AC common bus. However, since the line admittances from each converter to point of common coupling (PCC) are not identical, the injected reactive power may not be equally shared. In order to achieve low voltage ride through (LVRT) capability along with a good power sharing...

  11. Hepatoprotective activity of Moringa oleifera against cadmium toxicity in rats

    Directory of Open Access Journals (Sweden)

    Reetu Toppo

    2015-04-01

    Full Text Available Aim: The present investigation has been conducted to evaluate the hepatoprotective activity of Moringa oleifera against cadmium-induced toxicity in rats. Materials and Methods: For this study, 18 Wistar albino rats were taken. Control group, Group I rats were given cadmium chloride @ 200 ppm per kg and Group II rats were treated with M. oleifera extract @ 500 mg/kg along with cadmium chloride @ 200 ppm per kg (daily oral for 28 days. On 29th day, animals were slaughtered and various parameters were determined. Serum biomarkers, oxidative stress parameters, histomorphological examination were carried out with estimation of cadmium concentration in liver tissues. Results: Oral administration of cadmium chloride @ 200 ppm/kg for 28 days resulted in a significant increase in aspartate aminotransferase (AST, alanine transaminase (ALT, alkaline phosphatase (ALP, significant (p≤0.01 increase of lipid peroxidation (LPO and decrease in superoxide dismutase (SOD, and increase in cadmium accumulation in liver. Treatment with M. oleifera @ 500 mg/kg significantly (p<0.01 decreased the elevated ALP, AST, ALT, LPO levels and increase in SOD levels, and as compared to cadmium chloride treated group. However, there was no significant difference in cadmium concentration in liver when compared with cadmium chloride treated group. Conclusion: The study conclude that supplementation of M. oleifera (500 mg/kg, daily oral for 28 days has shown protection against cadmium-induced hepatotoxicity.

  12. A Magnetized Nanoparticle Based Solid-Phase Extraction Procedure Followed by Inductively Coupled Plasma Atomic Emission Spectrometry to Determine Arsenic, Lead and Cadmium in Water, Milk, Indian Rice and Red Tea.

    Science.gov (United States)

    Azimi, Salameh; Es'haghi, Zarrin

    2017-06-01

    A sensitive and simple method using magnetic multi-walled carbon nanotube (MWCNTs-Fe 3 O 4 MNP), as the adsorbent, has been successfully developed for extraction and pre-concentration of arsenic, lead and cadmium with detection by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The nanosorbent was characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction pattern (XRD), vibrating sample magnetometer (VSM) and transmission electron microscopy (TEM). The key factors affecting the signal intensity such as pH, adsorbent amount, etc. were investigated. Under optimal conditions, the limits of detection (three-time of signal to noise ratio, S/N 3) were 0.3, 0.6, 0.3 ng/mL for arsenic, lead and cadmium, respectively. Application of the adsorbent was investigated by the analysis of water, milk, Indian rice and red tea. The experimental data was analyzed and obeyed Langmuir and Freundlich adsorption models. The kinetic data was fitted to the pseudo-second-order model. Thermodynamic studies revealed the feasibility and exothermic nature of the system.

  13. 2D X-ray and FTIR micro-analysis of the degradation of cadmium yellow pigment in paintings of Henri Matisse

    Energy Technology Data Exchange (ETDEWEB)

    Pouyet, E. [European Synchrotron Radiation Facility, Grenoble (France); ARC-Nucleart - CEA/Grenoble, Grenoble Cedex 9 (France); Cotte, M. [European Synchrotron Radiation Facility, Grenoble (France); LAMS (Laboratoire d' Archeologie Moleculaire et Structurale) UMR-8220, Ivry-sur-Seine (France); Fayard, B.; Salome, M.; Kieffer, J.; Burghammer, M.; Sette, F. [European Synchrotron Radiation Facility, Grenoble (France); Meirer, F. [Utrecht University, Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht (Netherlands); Mehta, A. [SLAC National Accelerator Laboratory, Stanford Synchrotron radiation Lightsource, Menlo Park, CA (United States); Uffelman, E.S. [Washington and Lee University, Department of Chemistry and Biochemistry, Lexington, VA (United States); Hull, A. [University of Delaware, Department of Chemistry and Biochemistry, Newark, DE (United States); Vanmeert, F.; Janssens, K. [University of Antwerp, AXES Research Group, Department of Chemistry, Antwerp (Belgium); Mass, J. [Winterthur Museum, Scientific Research and Analysis Laboratory, Conservation Department, Winterthur, DE (United States)

    2015-11-15

    The chemical and physical alterations of cadmium yellow (CdS) paints in Henri Matisse's The Joy of Life (1905-1906, The Barnes Foundation) have been recognized since 2006, when a survey by portable X-ray fluorescence identified this pigment in all altered regions of the monumental painting. This alteration is visible as fading, discoloration, chalking, flaking, and spalling of several regions of light to medium yellow paint. Since that time, synchrotron radiation-based techniques including elemental and spectroscopic imaging, as well as X-ray scattering have been employed to locate and identify the alteration products observed in this and related works by Henri Matisse. This information is necessary to formulate one or multiple mechanisms for degradation of Matisse's paints from this period, and thus ensure proper environmental conditions for the storage and the display of his works. This paper focuses on 2D full-field X-ray Near Edge Structure imaging, 2D micro-X-ray Diffraction, X-ray Fluorescence, and Fourier Transform Infra-red imaging of the altered paint layers to address one of the long-standing questions about cadmium yellow alteration - the roles of cadmium carbonates and cadmium sulphates found in the altered paint layers. These compounds have often been assumed to be photo-oxidation products, but could also be residual starting reagents from an indirect wet process synthesis of CdS. The data presented here allow identifying and mapping the location of cadmium carbonates, cadmium chlorides, cadmium oxalates, cadmium sulphates, and cadmium sulphides in thin sections of altered cadmium yellow paints from The Joy of Life and Matisse's Flower Piece (1906, The Barnes Foundation). Distribution of various cadmium compounds confirms that cadmium carbonates and sulphates are photo-degradation products in The Joy of Life, whereas in Flower Piece, cadmium carbonates appear to have been a [(partially) unreacted] starting reagent for the yellow paint, a

  14. Interpretation of single and competitive adsorption of cadmium and zinc on activated carbon using monolayer and exclusive extended monolayer models.

    Science.gov (United States)

    Sellaoui, Lotfi; Dotto, Guilherme L; Lamine, Abdelmottaleb Ben; Erto, Alessandro

    2017-08-01

    In this work, a modeling analysis based on experimental tests of cadmium/zinc adsorption, in both single-compound and binary systems, was carried out. All the experimental tests were conducted at constant pH (around neutrality) and temperature (20 °C). The experimental results showed that the zinc adsorption capacity was higher than that of cadmium and it does not depend on cadmium presence in binary system. Conversely, cadmium adsorption is affected by zinc presence. In order to provide good understanding of the adsorption process, two statistical physics models were proposed. A monolayer and exclusive extended monolayer models were applied to interpret the single-compound and binary adsorption isotherms of zinc and cadmium on activated carbon. Based on these models, the modeling analysis demonstrated that zinc is dominant in solution and more favorably adsorbed on activated carbon surface. For instance, in single-compound systems, the number of ions bound per each receptor site was n (Zn2+) = 2.12 > n (Cd2+) = 0.98. Thus, the receptor sites of activated carbon are more selective for Zn2+ than for Cd2+. Moreover, the determination of adsorption energy through the adopted models confirmed that zinc is more favored for adsorption in single-compound system (adsorption energies equal to 12.12 and 7.12 kJ/mol for Zn and Cd, respectively) and its adsorption energy does not depend on the cadmium presence in binary system. Finally, the adsorption energy values suggested that single-compound and binary adsorption of zinc and cadmium is a physisorption.

  15. Enhanced cadmium phytoremediation of Glycine max L. through bioaugmentation of cadmium-resistant bacteria assisted by biostimulation.

    Science.gov (United States)

    Rojjanateeranaj, Pongsarun; Sangthong, Chirawee; Prapagdee, Benjaphorn

    2017-10-01

    This study examined the potential of three strains of cadmium-resistant bacteria, including Micrococcus sp., Pseudomonas sp. and Arthrobacter sp., to promote root elongation of Glycine max L. seedlings, soil cadmium solubility and cadmium phytoremediation in G. max L. planted in soil highly polluted with cadmium with and without nutrient biostimulation. Micrococcus sp. promoted root length in G. max L. seedlings under toxic cadmium conditions. Soil inoculation with Arthrobacter sp. increased the bioavailable fraction of soil cadmium, particularly in soil amended with a C:N ratio of 20:1. Pot culture experiments observed that the highest plant growth was in Micrococcus sp.-inoculated plants with nutrient biostimulation. Cadmium accumulation in the roots, stems and leaves of G. max L. was significantly enhanced by Arthrobacter sp. with nutrient biostimulation. A combined use of G. max L. and Arthrobacter sp. with nutrient biostimulation accelerated cadmium phytoremediation. In addition, cadmium was retained in roots more than in stems and leaves and G. max L. had the lowest translocation factor at all growth stages, suggesting that G. max L. is a phytostabilizing plant. We concluded that biostimulation-assisted bioaugmentation is an important strategy for improving cadmium phytoremediation efficiency. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Iron deficiency is associated with increased levels of blood cadmium in the Korean general population: Analysis of 2008-2009 Korean National Health and Nutrition Examination Survey data

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Byung-Kook [Institute of Environmental and Occupational Medicine, Soonchunhyang University, 646 Eupnae-ri, Shinchang-myun, Asan-si, Choongnam 336-745 (Korea, Republic of); Kim, Yangho, E-mail: yanghokm@nuri.net [Department of Occupational and Environmental Medicine, Ulsan University Hospital, University of Ulsan College of Medicine, 290-3 Cheonha-Dong, Dong-Gu, Ulsan 682-060 (Korea, Republic of)

    2012-01-15

    Introduction: We present data from the Korean National Health and Nutrition Examination Survey 2008-2009 on the distribution of blood cadmium levels and their association with iron deficiency in a representative sample of the adult Korean population. Methods: Serum ferritin was categorized into three levels: low (serum ferritin <15.0 {mu}g/L), low normal (15.0-30.0 {mu}g/L for women and 15.0-50.0 for men), and normal ({>=}30.0 {mu}g/L for women and {>=}50.0 for men), and its association with blood cadmium level was assessed after adjustment for various demographic and lifestyle factors. Results: Geometric means of blood cadmium in the low serum ferritin group in women, men, and all participants were significantly higher than in the normal group. Additionally, multiple regression analysis after adjusting for various covariates showed that blood cadmium was significantly higher in the low-ferritin group in women, men, and all participants compared with the normal group. We also found an association between serum ferritin and blood cadmium among never-smoking participants. Discussion: We found, similar to other recent population-based studies, an association between iron deficiency and increased blood cadmium in men and women, independent of smoking status. The results of the present study show that iron deficiency is associated with increased levels of blood cadmium in the general population.

  17. Fractionation of Stable Cadmium Isotopes in the Cadmium Tolerant Ricinus communis and Hyperaccumulator Solanum nigrum

    Science.gov (United States)

    Wei, Rongfei; Guo, Qingjun; Wen, Hanjie; Liu, Congqiang; Yang, Junxing; Peters, Marc; Hu, Jian; Zhu, Guangxu; Zhang, Hanzhi; Tian, Liyan; Han, Xiaokun; Ma, Jie; Zhu, Chuanwei; Wan, Yingxin

    2016-01-01

    Cadmium (Cd) isotopes provide new insights into Cd uptake, transport and storage mechanisms in plants. Therefore, the present study adopted the Cd-tolerant Ricinus communis and Cd-hyperaccumulator Solanum nigrum, which were cultured under controlled conditions in a nutrient solution with variable Cd supply, to test the isotopic fractionation of Cd during plant uptake. The Cd isotope compositions of nutrient solutions and organs of the plants were measured by multiple collector inductively coupled plasma mass spectrometry (MC-ICPMS). The mass balance of Cd isotope yields isotope fractionations between plant and Cd source (δ114/110Cdorgans-solution) of −0.70‰ to −0.22‰ in Ricinus communis and −0.51‰ to −0.33‰ in Solanum nigrum. Moreover, Cd isotope fractionation during Cd transport from stem to leaf differs between the Cd-tolerant and -hyperaccumulator species. Based on these results, the processes (diffusion, adsorption, uptake or complexation), which may induce Cd isotope fractionation in plants, have been discussed. Overall, the present study indicates potential applications of Cd isotopes for investigating plant physiology. PMID:27076359

  18. Assessment and management of risk to wildlife from cadmium

    Energy Technology Data Exchange (ETDEWEB)

    Burger, Joanna [Division of Life Sciences, Environmental and Occupational Health Sciences Institute, Consortium for Risk Evaluation with Stakeholder Participation, Rutgers University, Piscataway, New Jersey, 08854-8082 (United States)], E-mail: burger@biology.rutgers.edu

    2008-01-15

    Cadmium, a nonessential heavy metal that comes from natural and anthropogenic sources, is a teratogen, carcinogen, and a possible mutagen. Assessment of potential risk from cadmium requires understanding environmental exposure, mainly from ingestion, although there is some local exposure through inhalation. Chronic exposure is more problematic than acute exposure for wildlife. There is evidence for bioaccumulation, particularly in freshwater organisms, but evidence for biomagnification up the food chain is inconsistent; in some bird studies, cadmium levels were higher in species that are higher on the food chain than those that are lower. Some freshwater and marine invertebrates are more adversely affected by cadmium exposure than are birds and mammals. There is very little experimental laboratory research on the effects of cadmium in amphibians, birds and reptiles, and almost no data from studies of wildlife in nature. Managing the risk from cadmium to wildlife involves assessment (including ecological risk assessment), biomonitoring, setting benchmarks of effects, regulations and enforcement, and source reduction.

  19. Growth of cadmium oxide whiskers on cadmium sulphide single crystals with copper as growth activator

    Energy Technology Data Exchange (ETDEWEB)

    Koparanova, N.; Simov, S. (Bylgarska Akademiya na Naukite, Sofia. Inst. po Fizika na Tvyrdoto Tyalo); Genchev, D. (Bylgarska Akademiya na Naukite, Sofia. Inst. za Yadrena Izsledvaniya i Yadrena Energetika); Metchenov, G. (Research Inst. of Criminalistics and Criminology, Sofia (Bulgaria))

    1985-02-01

    Some results on the growth and morphology of cadmium oxide whiskers, obtained on cadmium sulphide single crystals with copper as a growth activator, are presented in this work. Cadmium oxide whiskers have been obtained on brace 112-bar0 brace faces of cadmium sulphide plates with a copper layer deposited in advance. The whiskers grew during the annealing of the plates in a weak stream of technically pure argon at temperatures 670 to 730 deg C for 15 min to 3.5 h. Details about the procedure have been given elsewhere. The composition and morphology of the whiskers have been studied by an X-ray microanalyser JEOL 35 DDS and a scanning electron microscope JEOL, JSM 35. The optical microscopic observations have shown that after annealing, a gray-black granular layer is formed on the cadmium sulphide single crystals and this layer can easily be separated from the crystal substrate. Under the granular layer the crystal is heavily damaged. The whiskers grow on the granular layer and they are coloured yellow-brown or red-brown. The maximum whisker length attains several hundreds of micrometres and in some cases up to 1 mm or more.

  20. The Effects of Hippotherapy and a Horse Riding Simulator on the Balance of Children with Cerebral Palsy

    OpenAIRE

    Lee, Chae-Woo; Kim, Seong Gil; Na, Sang Su

    2014-01-01

    [Purpose] We with respect to their effects on the compared hippotherapy with a horseback riding simulator (JOBA, Panasonic Inc. JP) static and dynamic balance of children with cerebral palsy (CP). [Subjects and Methods] Twenty-six children were randomly divided into two groups: a hippotherapy group that included 13 children, and a horseback riding simulator (JOBA, Panasonic Inc., Japan) group, which was also composed of 13 children. The two groups participated in 1 hour of exercise per day, 3...

  1. DETERMINATION OF ZINC, CADMIUM, LEAD AND COPPER IN SAMPLES OF COFFEE

    Directory of Open Access Journals (Sweden)

    E. Yu. Kupchik

    2015-12-01

    Full Text Available The potential pollutants which can get to the body using food products were explored in this work. The content of heavy metals such as zinc, cadmium, lead and copper are determined in coffee by inversion voltammetry. Sample preparation of samples was performed by oxidizing mineralization of paint sample in nitrate acid. It is shown that the method of inversion voltammetry can be successfully applied for the determination of zinc, cadmium, lead and copper at their combined presence in coffee. It is established that lead and zinc contain in all investigated samples, most of them contain cadmium and copper. Based on the analysis of experimental data discovered that the content of lead and cadmium don’t exceed permissible limits. It is noted that the average number of heavy metals increases in the order: coffee drinks- a soluble coffee – coffee beans and Grinded – green coffee. However, for an objective assessment of hair dyes quality, it is recommended to use a separate identification on each of heavy metals.

  2. An Evaluation of Kinetic Parameters of Cadmium and Copper Biosorption by Immobilized Cells

    Directory of Open Access Journals (Sweden)

    Nelly Georgieva

    2007-10-01

    Full Text Available Bioremediation is the use of living organisms to reduce or eliminate environmental hazards resulting from the accumulation of toxic chemicals and other hazardous wastes. This technology is based on the utilization of microorganisms to transform organic and inorganic compounds. The filamentous yeast Trichosporon cutaneum strain R57, immobilized and free cells was cultivated as batch culture on a liquid medium in the presence of various concentrations of cadmium and copper ions. The simultaneous uptake and accumulation of Cd2+ and Cu2+ ions by Tr. cutaneum cells depending on the initial concentration of Cd2+ and Cu2+ in the medium were studied. The potential use of the free and immobilized cells of Trichosporon cutaneum to remove cadmium and copper ions, from aqueous solutions was evaluated. Two important physicochemical aspects for the evaluation of the sorption process as a unit operation are the equilibrium of sorption and the kinetics. The Cd2+ and Cu2+ ions biosorption capacities of all tested adsorbent were presented as a function of the initial concentration of metal ions within the aqueous biosorption medium. The individual, as well as bicomponent sorption kinetics of copper and cadmium ions by immobilised cells of Trichosporon cutaneum R57 is presented. A second order kinetic model obtains kinetic parameters for the copper and cadmium ions.

  3. Association of Environmental Cadmium Exposure with Pediatric Dental Caries

    OpenAIRE

    Arora, Manish; Weuve, Jennifer Lynn; Schwartz, Joel David; Robert O Wright

    2008-01-01

    Background: Although animal experiments have shown that cadmium exposure results in severe dental caries, limited epidemiologic data are available on this issue. Objectives: We aimed to examine the relationship between environmental cadmium exposure and dental caries in children 6–12 years of age. Methods: We analyzed cross-sectional data, including urine cadmium concentrations and counts of decayed or filled tooth surfaces, from the Third National Health and Nutrition Examination Survey. We ...

  4. The effect of cannabis on regular cannabis consumers' ability to ride a bicycle.

    Science.gov (United States)

    Hartung, Benno; Schwender, Holger; Roth, Eckhard H; Hellen, Florence; Mindiashvili, Nona; Rickert, Annette; Ritz-Timme, Stefanie; Grieser, Almut; Monticelli, Fabio; Daldrup, Thomas

    2016-05-01

    To assess the effects of cannabis on the ability required to ride a bicycle, repetitive practical cycling tests and medical examinations were carried out before and after inhalative consumption of cannabis. A maximum of three joints with body weight-adapted THC content (300 μg THC per kg body weight) could be consumed by each test subject. Fourteen regular cannabis-consuming test subjects were studied (12 males, 2 females). In summary, only a few driving faults were observed even under the influence of very high THC concentrations. A defined THC concentration that leads to an inability to ride a bicycle cannot be presented. The test subjects showed only slight distinctive features that can be documented using a medical test routinely run for persons under suspicion of driving under the influence of alcohol or drugs.

  5. Taurine protects DNA of lymphocytes against oxidative alteration in riding horses

    DEFF Research Database (Denmark)

    Sokól, Janusz Leszek; Sawosz, Ewa; Niemiec, Tomasz

    2009-01-01

    The study aimed at evaluation the effect of dietary supplement of taurine on the oxidation-reduction status in riding horses, and especially on the extent of oxidative DNA degradation in lymphocytes. Ten Thoroughbred and half-bred geldings aged 6-13 years were classified according to breed....... The addition of taurine to feed caused smaller oxidative stress, manifested by lower concentration of TBA-RS in plasma and of 8-oxo-dG in lymphocytes. The taurine lowered the lipid peroxidation intensity that occurred in horses due to the oxidative stress caused by physical effort. Furthermore, taurine...... morphological and biochemical indicators were determined including the TBA-RS and 8-oxo-dG in lymphocyte DNA. It was found that physical effort of horses, being used for 30 days in recreation riding, affected homeostasis of redox status, and especially the rate of oxidative DNA degradation of lymphocytes...

  6. Low Voltage Ride-Through Capability Solutions for Permanent Magnet Synchronous Wind Generators

    Directory of Open Access Journals (Sweden)

    Victor F. Mendes

    2016-01-01

    Full Text Available Due to the increasing number of wind power plants, several countries have modified their grid codes to include specific requirements for the connection of this technology to the power system. One of the requirements is the ride-through fault capability (RTFC, i.e., the system capability to sustain operation during voltage sags. In this sense, the present paper intends to investigate the behavior of a full-converter wind generator with a permanent magnet synchronous machine during symmetrical and asymmetrical voltage sags. Two solutions to improve the low voltage ride-through capability (LVRT of this technology are analyzed: discharging resistors (brake chopper and resonant controllers (RCs. The design and limitations of these solutions and the others proposed in the literature are discussed. Experimental results in a 34 kW test bench, which represents a scaled prototype of a real 2 MW wind conversion system, are presented.

  7. Coordination between Fault-Ride-Through Capability and Overcurrent Protection of DFIG Generatorsfor Wind Farms

    DEFF Research Database (Denmark)

    Bak-Jensen, Birgitte; Kawady, Tamer A.; Abdel-Rahman, Mansour H.

    2009-01-01

    -Through (FRT) mainly aims to delay a disconnecting of the DFIG units during grid faults for a possible time to restore the system stability if the fault is cleared within a permissible time. This strategy may, however, affect the performance of related protective elements during fault periods. In this paper......, the Coor-dination between Fault Ride-Through Capability and Overcur-rent Protection of DFIG Wind Generators in MV Networks is in-vestigated. Simulation test cases using MATLAB-Simulink are implemented on a 345-MW wind farm in AL-Zaafarana, Egypt. The simulation results show the influence of FRT capability......Due to the increasing penetration of wind farms in power systems, stability issues arise strongly for power system operation. Doubly-Fed Induction Generators (DFIG) are charac-terized with some unique features during normal/abnormal op-erating conditions as compared with singly-fed ones. Fault ride...

  8. Fault ride through and voltage regulation for grid connected wind turbine

    Energy Technology Data Exchange (ETDEWEB)

    Kyaw, Min Min; Ramachandaramurthy, V.K. [Power Quality Research Group, Department of Electrical Power Engineering, Universiti Tenaga Nasional, Putrajaya Campus, 43009 Selangor (Malaysia)

    2011-01-15

    High penetration of wind generation challenges wind turbine operators to supply reliable power and extract optimum power from the wind. Hence, the fault ride through (FRT) capability of wind turbine together with the optimum power tracking and regulation of wind turbine output voltage due to fluctuating nature of the wind becomes essential. In this paper, a method is proposed to ensure that the double fed induction generator (DFIG) wind turbine continues to operate during severe grid faults and maintains a constant output voltage, irrespective of the fluctuating wind. The proposed controller also allows the DFIG wind turbine to track optimum power from the wind. Extensive simulation is performed using PSCAD/EMTDC software and results obtained show that the DFIG output voltage fulfills the grid code requirements. The results also show that the proposed method is able to track the optimum power, regulate the DFIG output voltage and perform fault ride through of wind turbine. (author)

  9. Resolution of sudden sensorineural hearing loss following a roller coaster ride.

    Science.gov (United States)

    Kumar, Aman; Sinha, Amrita; Al-Waa, Ahmad M

    2011-07-01

    We report a case of sudden unilateral sensorineural hearing loss of sudden onset during an aeroplane flight, which completely resolved during a roller coaster ride at Alton Towers theme park. A review of the literature concerning sudden idiopathic sensorineural hearing loss and spontaneous resolution are discussed. Initially, pure-tone audiometry showed a profound sensorineural hearing loss in the right ear and mild sensorineural hearing loss in the left ear (of note, the hearing was normal prior to the episode). Following resolution of the patient's symptoms during a roller coaster ride, pure-tone audiometry showed normal hearing thresholds in both ears. Sudden sensorineural hearing loss is a symptom of cochlear injury and the mechanism of the patient's symptoms was attributed to a patent cochlear aqueduct.

  10. Ride 2 Recovery's Project HERO: using cycling as part of rehabilitation.

    Science.gov (United States)

    Springer, Barbara A

    2013-05-01

    Ride 2 Recovery was founded in 2008 by a former world-class cycling competitor and coach to enhance the physical and psychological recovery of our nation's wounded, ill and injured service members and veterans through the sport of cycling. Ride 2 Recovery's most notable endeavor is Project HERO (Healing Exercise Rehabilitation Opportunity) which uses staff members and volunteers to promote cycling as an integral part of rehabilitation at select military facilities to enhance physical, psychological, spiritual and social recovery. Project HERO is directed by a retired military physical therapist that spent the last decade caring for service men and women wounded in Iraq and Afghanistan. This article describes all facets of the Project HERO initiative and highlights the profound impact it has had in the lives of US military members and veterans. Copyright © 2012 Elsevier Ltd. All rights reserved.

  11. Impact of fault ride-through requirements on fixed-speed wind turbine structural loads

    DEFF Research Database (Denmark)

    Hansen, Anca Daniela; Cutululis, Nicolaos Antonio; Markou, Helen

    2011-01-01

    simulation tools, which have expertise in different specialized wind turbines design areas. Two complimentary simulation tools are considered i.e. the detailed power system simulation tool PowerFactory from DIgSILENT and the advanced aeroelastic computer code HAWC2, in order to assess of the dynamic response...... by performing a rainflow and a statistical analysis for fatigue and ultimate structural loads, respectively. Two cases are compared i.e. one where the turbine is immediately disconnected from the grid when a grid fault occurs and one where the turbine is equipped with a fault ride-through controller...... faults. This article proposes a computer approach for the quantification of the wind turbines structural loads caused by the fault ride-through grid requirements. This approach, exemplified for the case of a 2MW active stall wind turbine, relies on the combination of knowledge from complimentary...

  12. Zinc and cadmium accumulation among and within populations of the pseudometalophytic species Arrhenatherum elatius: Implications for phytoextraction

    Energy Technology Data Exchange (ETDEWEB)

    Deram, A. [Universite Droit et Sante de Lille - EA 2690, Institut Lillois d' Ingenierie de la Sante, 42, rue Ambroise Pare 59 120 Loos (France)]. E-mail: annabelle.deram@univ-lille2.fr; Denayer, F.-O. [Universite Droit et Sante de Lille - EA 2690, Institut Lillois d' Ingenierie de la Sante, 42, rue Ambroise Pare 59 120 Loos (France); Dubourgier, H.-C. [Eesti Maauelikool, Pollumajandus-ja keskkonnainstituut, Kreutzwaldi 64, Tartu 51 014 (Estonia); Douay, F. [Institut Superieur d' Agriculture, Laboratoire Sols et Environnement, 48, Boulevard Vauban 59 046 Lille (France); Petit, D. [Laboratoire de Genetique et Evolutions des Populations Vegetales, UPRESA-CNRS 8016, Bat SN2, Universite des Sciences et Technologies de Lille, Villeneuve d' Ascq, 59 655 France (France); Van Haluwyn, C. [Universite Droit et Sante de Lille - EA 2690, Departement de Botanique, Faculte des Sciences Pharmaceutiques et Biologiques, 3, rue du Professeur Laguesse, B.P. 83, F-59 006 Lille cedex (France)

    2007-01-01

    The purpose of this study was to investigate, under standard conditions, the bioaccumulation of zinc and cadmium in Arrhenatherum elatius, a perennial grass with a high biomass production. Nine populations of three different origins were tested: three metallicolous populations (mpop); three non-metallicolous populations (nmpop) and three populations developing on soils moderately metal polluted (medpop). We have found that bioaccumulation differs among these populations, with nmpop accumulating significantly more zinc (p < 0.0001) and cadmium (p < 0.0001) than mpop. Indeed, we have observed a concentration of 325 mg kg{sup -1} of zinc and 52 mg kg{sup -1} of cadmium in A. elatius shoots from mpop, whereas in nmpop, the concentration reached on average 524 mg kg{sup -1} zinc and 83 mg kg{sup -1} cadmium. In the same way, medpop accumulated as much zinc but more cadmium than nmpop. Moreover, the standard deviation of medpop was larger than the one for mpop and nmpop. Indeed, some A. elatius samples from medpop presented a high metal content whereas, others presented low concentrations in their shoots (ranging from 60 to 210 mg kg{sup -1} cadmium). Hence, these medpop exhibited a large variability among and within populations in accumulating zinc and cadmium in their shoots. Based on these results, the possibility of selecting A. elatius plants with the best accumulating capacity from medpop was proposed. We concluded that if the accumulation capacity is genetically controlled in A. elatius, this species fulfils this necessary condition for efficiently increasing species bioaccumulation by crossbreeding A. elatius plants with the higher accumulation capacity.

  13. A case-control study of the association between urinary cadmium concentration and endometriosis in infertile Japanese women

    Energy Technology Data Exchange (ETDEWEB)

    Itoh, Hiroaki [Epidemiology and Prevention Division, Research Center for Cancer Prevention and Screening, National Cancer Center, 5-1-1 Tsukiji, Chuo-ku, Tokyo 104-0045 (Japan); Iwasaki, Motoki [Epidemiology and Prevention Division, Research Center for Cancer Prevention and Screening, National Cancer Center, 5-1-1 Tsukiji, Chuo-ku, Tokyo 104-0045 (Japan)], E-mail: moiwasak@gan2.res.ncc.go.jp; Nakajima, Yoshiaki; Endo, Yoko [Research Center for Occupational Poisoning, Tokyo Rosai Hospital, Japan Labour Health and Welfare Organization, 4-13-21 Omoriminami, Ohta-ku, Tokyo 143-0013 (Japan); Hanaoka, Tomoyuki [Epidemiology and Prevention Division, Research Center for Cancer Prevention and Screening, National Cancer Center, 5-1-1 Tsukiji, Chuo-ku, Tokyo 104-0045 (Japan); Sasaki, Hiroshi; Tanaka, Tadao; Yang, Bin [Department of Obstetrics and Gynecology, Jikei University School of Medicine 3-25-8, Nishi-Shimbashi, Minato-ku, Tokyo, 105-8461 (Japan); Tsugane, Shoichiro [Epidemiology and Prevention Division, Research Center for Cancer Prevention and Screening, National Cancer Center, 5-1-1 Tsukiji, Chuo-ku, Tokyo 104-0045 (Japan)

    2008-09-01

    Cadmium may act like an estrogen and be a potential risk factor for estrogen-related diseases such as breast cancer and endometriosis. Here, we tested the hypothesis that higher cadmium exposure is associated with endometriosis among infertile Japanese women in a hospital-based case-control study. We recruited consecutive female patients aged 20-45 years who had complained of infertility and presented to a university hospital in Tokyo. The subjects were interviewed and provided a urine sample prior to a laparoscopic diagnosis of endometriosis between January 2000 and December 2001. The severity of endometriosis was then dichotomized into controls (stage 0 and I) and cases (stage II-IV). We finally measured urinary total cadmium concentration in 54 cases and 74 controls as a biomarker of long-term cumulative exposure. Odds ratios were adjusted for average menstrual cycle length, body-mass index and smoking status using unconditional logistic regression. Results showed no association between endometriosis and urinary cadmium concentration. Medians (interquartile ranges) of urinary cadmium concentration in cases and controls were 0.53 (0.40-0.73) and 0.54 (0.34-0.76) {mu}g/g creatinine, respectively (P for difference = 0.88). Adjusted odds ratio (95% confidence interval) for the highest versus lowest tertile of urinary creatinine-adjusted cadmium concentration was 0.86 (0.30 to 2.49, P for trend = 0.79). Our results do not support the hypothesis that higher urinary cadmium concentration is associated with the risk of endometriosis.

  14. "Riding the Wave": Transforming Sport and Exercise Psychology within an Interdisciplinary Vision

    Science.gov (United States)

    Weiss, Maureen R.

    2008-01-01

    A metaphor of "riding the wave" is used as a means of envisioning the future of sport and exercise psychology given what we know about past and present waves in the field. First, I review the waves of the 1980s, 1990s, and 2000s to understand critical issues in the field and to evaluate the waves as smooth, choppy, or turbulent today. Second,…

  15. Associations between television watching and car riding behaviors and development of depressive symptoms: a prospective study.

    Science.gov (United States)

    Sui, Xuemei; Brown, Wendy J; Lavie, Carl J; West, Delia S; Pate, Russel R; Payne, Jonathan P W; Blair, Steven N

    2015-02-01

    To examine the longitudinal association between sedentary behaviors and risk of development of depressive symptoms. The study population consisted of 4802 participants in the Aerobics Center Longitudinal Study (1012 women and 3790 men) aged 18 to 80 years who did not report depressive moods when they completed a health survey during 1982 in which they reported their time spent watching television (TV) and riding in a car each week. All participants completed a follow-up health survey when they responded to the 10-item Center for Epidemiologic Studies Depression Scale. Those who scored 8 or more on the Center for Epidemiologic Studies Depression Scale were considered to have depressive symptoms. Among the 4802 participants, 568 reported depressive symptoms during a mean follow-up of 9.3 years. After multivariate adjustment including moderate- and vigorous-intensity physical activity, time riding in a car, time watching TV, and combined time spent in the 2 sedentary behaviors were positively associated with depressive symptoms (each Pdepressive symptoms than those who reported less than 5 h/wk, less than 5 h/wk, or less than 12 h/wk, respectively, after adjusting for baseline covariates and moderate- and vigorous-intensity physical activity. The positive association between time riding in a car or time watching TV and depressive symptoms was only observed among individuals who did not meet the current physical activity guidelines. More time reported in these 2 sedentary behaviors was positively associated with depressive symptoms. However, the direct associations between time spent in car riding and TV viewing and depressive symptoms were only significant among those who did not meet the current physical activity recommendations. Copyright © 2015 Mayo Foundation for Medical Education and Research. Published by Elsevier Inc. All rights reserved.

  16. Improving Fault Ride-Through Capability of Variable Speed Wind Turbines in Distribution Networks

    DEFF Research Database (Denmark)

    Mokryani, Geev; Siano, P.; Piccolo, Antonio

    2013-01-01

    In this paper, a fuzzy controller for improving the fault ride-through (FRT) capability of variable speed wind turbines (WTs) equipped with a doubly fed induction generator (DFIG) is presented. DFIGs can be used as reactive power sources to control the voltage at the point of common coupling (PCC...... on a real 37-bus weak distribution system confirmed that the proposed controller can enhance the FRT capability....

  17. Rüütel pensionäride elujärje garandina / Janno Reiljan

    Index Scriptorium Estoniae

    Reiljan, Janno, 1951-2018

    2006-01-01

    Ilmunud ka: Severnoje Poberezhje (2006) 17. aug., lk. 2, Meie Maa (2006) 18. aug., lk. 2, Nädaline (2006) 22. aug., lk. 2, Vooremaa (2006) 22. aug., lk. 2, Valgamaalane (2006) 24. aug., lk. 2. Autor selgitab Eesti pensionäride elujärje kujunemise näitel, miks Rahvaliit ja Keskerakond nimetasid oma koostöölepingu garandiks president Arnold Rüütli

  18. Bioremoval of cadmium by lemna minor in different aquatic conditions

    Energy Technology Data Exchange (ETDEWEB)

    Uysal, Yagmur [Dept. of Environmental Engineering, Kahramanmaras Sutcu Imam University, Kahramanmaras (Turkey); Taner, Fadime [Dept. of Environmental Engineering, Mersin University, Mersin (Turkey)

    2010-04-15

    This study was undertaken to determine the cadmium removal efficiency of Lemna minor when it was used for treatment of wastewater having different characteristics, i. e., pH, temperature and cadmium concentration. Plants were cultivated in different pH solutions (4.5-8.0) and temperatures (15-35 C) in the presence of cadmium (0.1-10.0 mg/L) for 168 h. The amount of biomass obtained in the study period, the concentrations of cadmium in the tissues and in the media and net uptake of cadmium by Lemna have been determined for each condition. The percentages of cadmium uptake (PMU) and bioconcentration factors (BCF) were also calculated. The highest accumulation was obtained for the highest cadmium concentration of 10.0 mg Cd/L as 11.668 mg Cd/g at pH 6.0, and as 38.650 mg Cd/g at 35 C and pH 5.0. The cadmium accumulation gradually increased with initial concentration of the medium, but the opposite trend was observed for the PMU. However, the maximum PMU was obtained as 52.2% in the solution with the lowest concentration of 0.1 mg Cd/L. A mathematical model was used to describe the cadmium uptake and the equation obtained was seen to fit the experimental data very well. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  19. Short Communication Acute toxicity of cadmium against catfish ...

    African Journals Online (AJOL)

    Short Communication Acute toxicity of cadmium against catfish Heteropneustes Fossilis (Siluriformes: Heteropneustidae) in static renewal bioassays. Rubi Rai, Diwakar Mishra, Sunil Kumar Srivastav, Ajai Kumar Srivastav ...

  20. Inactivation of cadmium in contaminated soils using synthetic zeolites.

    Science.gov (United States)

    Gworek, B

    1992-01-01

    The addition of synthetic zeolite pellets to soils contaminated with cadmium significantly reduced the concentrations of cadmium in the roots and shoots of a range of crop plants. Use of synthetic foyazite group zeolites types 4A and 13X, at application rates of 1% by soil weight, caused reductions in cadmium concentrations of up to 86% in leaves of lettuce grown in pots, compared to controls with no added zeolites. The potential of these substances to reduce cadmium entry into the food chain, and as a clean up method, is noted.