WorldWideScience

Sample records for c15 friauf-laves phase

  1. The effect of hydrogen absorption on the structural, electronic and magnetic properties of the C15 Friauf-Laves phase compounds CeFe2, CeRu2 and LaRu2 : an x-ray absorption spectroscopy (XAS) study

    International Nuclear Information System (INIS)

    Chaboy, J.; Garcia, J.; Marcelli, A.

    1995-08-01

    An x-ray absorption spectroscopy (XAS) investigation of the structural changes occurred upon hydriding in the Friauf-Laves phase compounds CeFe 2 , CeRu 2 and LaRu 2 compounds is presented. The analysis of the extended x-ray absorption spectroscopy (EXAFS) spectra at the L-edges of the rare-earth and at the Fe K-edge indicates that the hydrogenation process leads to the suppression of the long-range crystalline order in all the hydride derivates investigated, as well as the different influence of H 2 in both the rare earth and transition metal sublattices. The correlation between the structural and magnetic changes induced by the hydrogen in the lost matrix is discussed in terms of the modification of the electronic properties, i.e., intermediate-valence of Ce, and of the hybridization between the transition metal and rare-earth

  2. Site occupancies in ternary C15 ordered Laves phases

    International Nuclear Information System (INIS)

    Kotula, P.G.; Chu, F.; Thoma, D.J.; Mitchell, T.E.; Anderson, I.M.; Bentley, J.

    1996-01-01

    Site occupancies in three C15-structured AB 2 (X) Laves phases have been determined by Atom Location by CHanneling Enhanced MIcroanalysis (ALCHEMI). In NbCr 2 (V), the results were consistent with exclusive site occupancies of Nb for the A sublattice and Cr and V for the B sublattice. The B-site occupancy of V is not expected from atom size effects alone. In NbCr 2 (Ti), the results were consistent with Ti partitioning mostly to the A sites with some anti-site defects likely. In HfV 2 (Nb), the results were consistent with Nb partitioning between the A and B sites. The results of the ALCHEMI analyses of these ternary C15 Laves phase materials will be discussed with respect to previously determined phase diagrams and first-principles total energy and electronic structure calculations

  3. Elastic constants of a Laves phase compound: C15 NbCr2

    International Nuclear Information System (INIS)

    Ormeci, A.; Chu, F.; Wills, J.M.; Chen, S.P.; Albers, R.C.; Thoma, D.J.; Mitchell, T.E.

    1997-01-01

    The single-crystal elastic constants of C15 NbCr 2 have been computed by using a first-principles, self-consistent, full-potential total energy method. From these single-crystal elastic constants the isotropic elastic moduli are calculated using the Voigt and Reuss averages. The calculated values are in fair agreement with the experimental values. The implications of the results are discussed with regards to Poisson's ratio and the direction dependence of Young's modulus

  4. Elastic constants of a Laves phase compound: C15 NbCr{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Ormeci, A. [Koc Univ., Istanbul (Turkey)]|[Los Alamos National Lab., NM (United States); Chu, F.; Wills, J.M.; Chen, S.P.; Albers, R.C.; Thoma, D.J.; Mitchell, T.E. [Los Alamos National Lab., NM (United States)

    1997-04-01

    The single-crystal elastic constants of C15 NbCr{sub 2} have been computed by using a first-principles, self-consistent, full-potential total energy method. From these single-crystal elastic constants the isotropic elastic moduli are calculated using the Voigt and Reuss averages. The calculated values are in fair agreement with the experimental values. The implications of the results are discussed with regards to Poisson`s ratio and the direction dependence of Young`s modulus.

  5. Elastic constants of the C15 laves phase compound NbCr2

    International Nuclear Information System (INIS)

    Chu, F.; He, Y.; Thoma, D.J.; Mitchell, T.E.

    1995-01-01

    Elastic properties of a solid are important because they relate to various fundamental solid-state phenomena such as interatomic potentials, equations of state, and phonon spectra. Elastic properties are also linked thermodynamically with specific heat, thermal expansion, Debye temperature, and Gruneisen parameter. Most important, knowledge of elastic constants is essential for many practical applications related to the mechanical properties of a solid as well: load-deflection, thermoelastic stress, internal strain (residual stress), sound velocities, dislocation core structure, and fracture toughness. In order to understand better the physical properties and deformation behavior of the C15 compound NbCr 2 , the authors have studied its elastic properties in this paper. In Section 2, the experimental methods are described, including the preparation of the sample and the measurement of the elastic constants. In Section 3, the experimental results are presented and the implications of these experimental results are discussed. Conclusions are drawn in Section 4

  6. First-principles study of structural phase transition, electronic, elastic and thermodynamic properties of C15-type Laves phase TiCr2 under pressure

    Science.gov (United States)

    He, Li-Zhi; Zhu, Jun; Zhang, Lin

    2018-02-01

    Phase transition of TiCr2 in C15 (MgCu2), C36 (MgNi2), C14 (MgZn2) structures have been studied by using the projector augmented wave method. It is found that C15-type is the most stable structure, which agrees with the results of Chen et al. At 0 K, the phase boundary of C15 to C36 is 207.79 GPa, and the phase transition from C36 to C14 is 265.61 GPa. Both the transition pressures decrease with increasing temperature. Phonon dispersion and elastic constants are calculated and found that C15-type TiCr2 is mechanically stable according to the elastic stability criteria and phonon dispersion analysis. Moreover, the pressure and temperature dependence of the specific heat, Debye temperature and thermal expansion coefficient are discussed, among them our calculated Debye temperature is consistent with the report of A. sari et al., however, it is far from the results of B. Mayer et al. and Chen et al.

  7. Enhancement of a cyclic endurance of phase change memory by application of a high-density C15(Ge21Sb36Te43 film

    Directory of Open Access Journals (Sweden)

    J. H. Park

    2016-02-01

    Full Text Available The lower cyclic endurance of Phase Change Memory (PCM devices limits the spread of its applications for reliable memory. The findings reported here show that micro-voids and excess vacancies that are produced during the deposition process and the subsequent growth in sputtered carbon-doped GeSbTe films is one of the major causes of device failure in PCM with cycling. We found that the size of voids in C15(Ge21Sb36Te43 films increased with increasing annealing temperature and the activation energy for the growth rate of voids was determined to be 2.22 eV. The film density, which is closely related to voids, varies with the deposition temperature and sputtering power used. The lower heat of vaporization of elemental Sb and Te compared to that for elemental Ge and C is a major cause of the low density of the film. It was possible to suppress void formation to a considerable extent by optimizing the deposition conditions, which leads to a dramatic enhancement in cyclic endurance by 2 orders of magnitude in PCM devices prepared at 300oC-300W compared to one prepared at 240oC-500W without change of compositions.

  8. Thermoelectric properties of TbFe{sub 2} and TbCo{sub 2} in C15- laves phase: Spin-polarized DFT+U approach

    Energy Technology Data Exchange (ETDEWEB)

    Reshak, A.H., E-mail: maalidph@yahoo.co.uk [New Technologies - Research Centre, University of West Bohemia, Univerzitni 8, Pilsen 306 14 (Czech Republic); School of Material Engineering, University Malaysia Perlis, Kangar, Perlis 01007 (Malaysia)

    2017-01-15

    Thermoelectric properties of materials are intimately related to their electronic band structure. Combining first- and second-principles calculations, we have obtained the transport properties for the spin-up and spin-down electrons of the laves phase TbFe{sub 2} and TbCo{sub 2} compounds. The unique band structure feature and the density of states at Fermi level (E{sub F}) promote the E{sub F} to a point where carriers are in energetic proximity to these features. The non-zero density of states at E{sub F} for the spin-up (↑) and spin-down (↓) electrons leads to unusual transport properties because both the (↑) and (↓) densities contributes to the states at E{sub F}. The parabolic bands in the vicinity of E{sub F} enhance the carriers mobility and hence the transport properties of TbFe{sub 2} and TbCo{sub 2}. Calculations show that the spin-up/down transport coefficients are temperature-dependent. It has been found that TbCo{sub 2} possess larger Seebeck coefficient than that of TbFe{sub 2} and hence the power factor. The calculated Seebeck coefficient of TbCo{sub 2} agree well with the available experimental data. - Highlights: • The transport properties of TbFe{sub 2} and TbCo{sub 2} are obtained. • The non-zero density of states at E{sub F} leads to unusual transport properties. • Spin-up/down transport coefficients are temperature-dependent. • The calculated Seebeck coefficient of TbCo{sub 2} agree with the experimental data. • TbCo{sub 2} possesses larger Seebeck coefficient than that of TbFe{sub 2}.

  9. Phase diagram measurements by Heat-flux DSC and thermodynamic calculations of the mixture of the Esters Ethyl undecanoate (C13H26O2) and Ethyl tridecanoate (C15H30O2)

    NARCIS (Netherlands)

    Schaftenaar, H.P.C.

    2006-01-01

    In this report a phase diagram is determined by heat flux DSC of the binary mixture Ethyl undecanoate and Ethyl tridecanoate. Our hypothesis for equilibrium phase behaviour is that the components Ethyl undecanoate and Ethyl tridecanoate do have the same crystal form and they have restricted

  10. 40 CFR 721.6505 - Polymers of C13C15 oxoalcohol ethoxolates.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Polymers of C13C15 oxoalcohol... Specific Chemical Substances § 721.6505 Polymers of C13C15 oxoalcohol ethoxolates. (a) Chemical substance... polymers of C13C15 oxoalcohol ethoxolates (PMNs P-96-950/951) are subject to reporting under this section...

  11. 26 CFR 1.381(c)(15)-1 - Indebtedness of certain personal holding companies.

    Science.gov (United States)

    2010-04-01

    ... 26 Internal Revenue 4 2010-04-01 2010-04-01 false Indebtedness of certain personal holding companies. 1.381(c)(15)-1 Section 1.381(c)(15)-1 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES Insolvency Reorganizations § 1.381(c)(15...

  12. The CN/C15N isotopic ratio towards dark clouds

    Science.gov (United States)

    Hily-Blant, P.; Pineau des Forêts, G.; Faure, A.; Le Gal, R.; Padovani, M.

    2013-09-01

    Understanding the origin of the composition of solar system cosmomaterials is a central question, not only in the cosmochemistry and astrochemistry fields, and requires various approaches to be combined. Measurements of isotopic ratios in cometary materials provide strong constraints on the content of the protosolar nebula. Their relation with the composition of the parental dark clouds is, however, still very elusive. In this paper, we bring new constraints based on the isotopic composition of nitrogen in dark clouds, with the aim of understanding the chemical processes that are responsible for the observed isotopic ratios. We have observed and detected the fundamental rotational transition of C15N towards two starless dark clouds, L1544 and L1498. We were able to derive the column density ratio of C15N over 13CN towards the same clouds and obtain the CN/C15N isotopic ratios, which were found to be 500 ± 75 for both L1544 and L1498. These values are therefore marginally consistent with the protosolar value of 441. Moreover, this ratio is larger than the isotopic ratio of nitrogen measured in HCN. In addition, we present model calculations of the chemical fractionation of nitrogen in dark clouds, which make it possible to understand how CN can be deprived of 15N and HCN can simultaneously be enriched in heavy nitrogen. The non-fractionation of N2H+, however, remains an open issue, and we propose some chemical way of alleviating the discrepancy between model predictions and the observed ratios. Appendices are available in electronic form at http://www.aanda.orgThe reduced spectra (in FITS format) are available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/557/A65

  13. Synthesis of Novel C-2- or C-15-Labeled BODIPY—Estrone Conjugates

    Directory of Open Access Journals (Sweden)

    Ildikó Bacsa

    2018-04-01

    Full Text Available Novel BODIPY–estrone conjugates were synthesized via Cu(I-catalyzed azide–alkyne cycloaddition (CuAAC. Estrone-alkynes or an estrone-azide as starting compounds were synthesized via Michael addition or Sonogashira reaction as key steps. Fluorescent dyes based on BODIPY-core were provided by azide or alkyne functional groups. Fluorescent labeling of estrone was efficiently achieved at the C-2 or C-15 position. The newly-elaborated coupling procedures might have a broad applicability in the synthesis of fluorescent-labeled estrone conjugates suitable for biological assays.

  14. (13)C-(15)N correlation via unsymmetrical indirect covariance NMR: application to vinblastine.

    Science.gov (United States)

    Martin, Gary E; Hilton, Bruce D; Blinov, Kirill A; Williams, Antony J

    2007-12-01

    Unsymmetrical indirect covariance processing methods allow the derivation of hyphenated 2D NMR data from the component 2D spectra, potentially circumventing the acquisition of the much lower sensitivity hyphenated 2D NMR experimental data. Calculation of HSQC-COSY and HSQC-NOESY spectra from GHSQC, COSY, and NOESY spectra, respectively, has been reported. The use of unsymmetrical indirect covariance processing has also been applied to the combination of (1)H- (13)C GHSQC and (1)H- (15)N long-range correlation data (GHMBC, IMPEACH, or CIGAR-HMBC). The application of unsymmetrical indirect covariance processing to spectra of vinblastine is now reported, specifically the algorithmic extraction of (13)C- (15)N correlations via the unsymmetrical indirect covariance processing of the combination of (1)H- (13)C GHSQC and long-range (1)H- (15)N GHMBC to produce the equivalent of a (13)C- (15)N HSQC-HMBC correlation spectrum. The elimination of artifact responses with aromatic solvent-induced shifts (ASIS) is shown in addition to a method of forecasting potential artifact responses through the indirect covariance processing of the GHSQC spectrum used in the unsymmetrical indirect covariance processing.

  15. 26 CFR 31.3306(c)(15)-1 - Services in delivery or distribution of newspapers, shopping news, or magazines.

    Science.gov (United States)

    2010-04-01

    ... newspapers, shopping news, or magazines. 31.3306(c)(15)-1 Section 31.3306(c)(15)-1 Internal Revenue INTERNAL..., shopping news, or magazines. (a) Services of individuals under age 18. Services performed by an employee... magazines to ultimate consumers under an arrangement under which the newspapers or magazines are to be sold...

  16. Isolaurenidificin and Bromlaurenidificin, Two New C15-Acetogenins from the Red Alga Laurencia obtusa

    Directory of Open Access Journals (Sweden)

    Nahed O. Bawakid

    2017-05-01

    Full Text Available Chromatographic fractionation of the CH2Cl2/MeOH extract of the Red Sea red alga Laurencia obtusa gave two new hexahydrofuro[3,2-b]furan-based C15-acetogenins, namely, isolaurenidificin (1 and bromlaurenidificin (2. The chemical structures were elucidated based on extensive analyses of their spectral data. Compounds 1 and 2 showed no toxicity (LC50 > 12 mM using Artemia salina as test organism. Both compounds showed weak cytotoxicity against A549, HepG-2, HCT116, MCF-7, and PC-3 cells, however, they exhibited a relatively potent cytotoxic activity against peripheral blood neutrophils. This can be attributed partly to induction of apoptosis.

  17. Halogenated Terpenes and a C15-Acetogenin from the Marine Red Alga Laurencia saitoi

    Directory of Open Access Journals (Sweden)

    Xiao-Ming Li

    2008-11-01

    Full Text Available Seven parguerane diterpenes: 15-bromo-2,7,19-triacetoxyparguer-9(11-en-16-ol (1, 15-bromo-2,7,16,19-tetraacetoxyparguer-9(11-ene (2, 15-bromo-2,19-diacetoxyparguer-9(11-en-7,16-diol (3, 15-bromo-2,16,19-triacetoxyparguer-9(11-en-7-ol (4, 15-bromo-2,16-diacetoxyparguer-9(11-en-7-ol (5, 15-bromoparguer-9(11-en-16-ol (6, 15-bromoparguer-7-en-16-ol (7, two polyether triterpenes: thyrsiferol (8 and thyrsiferyl 23-acetate (9, and one C15-acetogenin, neolaurallene (10, were isolated from a sample of marine red alga Laurencia saitoi collected off the coast of Yantai. Their structures were established by detailed NMR spectroscopic analysis and comparison with literature data.

  18. Synthesis and biosynthesis of 13C, 15N labeled deoxynucleosides useful for biomolecular structural determinations

    International Nuclear Information System (INIS)

    Ashburn, D.A.; Garcia, K.; Hanners, J.L.; Silks, L.A. III; Unkefer, C.J.

    1994-01-01

    Currently, there is a great emphasis on elucidating the structure, function, and dynamics of DNA. Much of the research involved in this study utilizes nuclear magnetic resonance (NMR) spectroscopy. Effective use of NMR spectroscopy (more than 10,000 mw) in this arena requires stable isotope enrichment. Herein, the authors present strategies for the site-specific isotopic labeling of the purine bases adenosine and guanosine and the biosynthesis of [U- 13 C, 15 N] DNA from methylotrophic bacteria. With commercially available 6-chloropurine, an effective 2-step route leads to [6- 15 N]-2'-deoxadenosine (dA). The resulting [6- 15 N]-dA is used in a series of reactions to synthesize [2- 13 C, 1,2'- 15 N 2 ]-2'-deoxyguanosine or any combination thereof. An improved biosynthesis of labeled DNA has been accomplished using Methylobacterium extorquens AS1. Each liter of growth medium contains 4g of methanol to yield 1 gram of lyophilized cells. As much as 200 mg of RNA per liter of culture has been obtained. The authors are currently developing large scale isolation protocols. General synthetic pathways to oligomeric DNA are presented

  19. Synthesis and biosynthesis of 13C-, 15N-labeled deoxynucleosides useful for biomolecular structural determinations

    International Nuclear Information System (INIS)

    Ashburn, D.A.; Garcia, K.; Hanners, J.L.; Silks, L.A. III; Unkefer, C.J.

    1994-01-01

    Currently, there is a great emphasis on elucidating the structure, function, and dynamics of DNA. Much of the research involved in this study uses nuclear magnetic resonance (NMR) spectroscopy. Effective use of NMR spectroscopy for DNA molecules with mw > 10,000 requires stable isotope enrichment. We present strategies for site-specific isotopic labeling of the purine bases adenosine and guanosine and the biosynthesis of (U- 13 C, 15 N) DNA from methylotropic bacteria. With commercially available 6-chloropurine, an effective two-step route leads to 2'-deoxy-(amino- 15 N)adenosine (dA). The resulting d(amino- 15 N)A is used in a series of reactions to synthesize 2'-deoxy-(2- 13 C,1,amino- 15 N 2 )guanosine or any combination thereof. An improved biosynthesis of labeled DNA has been accomplished using Methylobacterium extorquens AS1. Each liter of growth medium contains 4 g of methanol to yield 1 g of lyophilized cells. As much as 200 mg of RNA per liter of culture has been obtained. We are currently developing large-scale isolation protocols. General synthetic pathways to oligomeric DNA will be presented

  20. Gas phase reactions of protonated 1,3-diphenylpropyne and some isomeric [C15H13]+ ions

    OpenAIRE

    Bäther, Wolfgang; Kuck, Dietmar; Grützmacher, Hans-Friedrich

    1985-01-01

    Metastable (3-phenyl-2-propynyl)benzenium ions, generated by electron impact induced fragmentation from the appropriately substituted 1,4-dihydrobenzoic acid, react by loss of ·CH3 and C6H6. The study of deuterated derivatives reveals that hydrogen/deuterium exchanges involving all hydrogen and deuterium atoms precede the fragmentations. The results suggest a skeletal rearrangement by electrophilic ring-closure reactions giving rise to protonated phenylindene and protonated 9,10-methano-9,10-...

  1. Cyclopentanone: A raw material for production of C15 and C17 fuel precursors

    International Nuclear Information System (INIS)

    Hronec, Milan; Fulajtárova, Katarína; Liptaj, Tibor; Štolcová, Magdaléna; Prónayová, Naďa; Soták, Tomáš

    2014-01-01

    The synthesis of diesel or jet fuels intermediates from furfural or 5-hydroxymethylfurfural (HMF) via aqueous aldol-condensation with cyclopentanone was studied. Cyclopentanone is the product of furfural rearrangement in an aqueous system. Since the aldol-condensation reaction is conducted in an aqueous solution all these biomass-derived reactants can be applied as water solutions formed in the processes of their preparation. The aldol condensation of furfural with cyclopentanone is at low concentration of base and molar ratio of reactants 2:1 highly selective and after 40–80 min of reaction at a temperature of 40–100 °C more than 95 mol% yield of 2,5-bis (2-furylmethylidene) cyclopentan-1-one (F 2 C) was obtained. When instead of furfural as a reactant HMF was used higher than 98 mol% yield of 2,5-bis (5-hydroxymethyl-2-furylmethylidene) cyclopentan-1-one was achieved. The final products of aldol condensation of furfural and HMF are exclusively corresponding dimers, what enables to obtain after subsequent hydrogenation/hydrodeoxygenation step dialkylcyclopentane type of diesel or jet fuels having C 15 or C 17 molecules. - Highlights: • The aldol condensation of biomass derived cyclopentanone with furfural and HMF. • More than 95 mol % yields of products are achieved. • The products are compounds having exclusively 15 or 17 carbon atoms in molecule. • Reactants can be used as diluted aqueous solutions. • The products are separated as solids insoluble in water

  2. Thermochemistry analyses for transformation of C6 glucose compound into C9, C12 and C15 alkanes using density functional theory

    Science.gov (United States)

    Verma, Anand Mohan; Kishore, Nanda

    2017-02-01

    The hydrolysis of cellulose fraction of biomass yields C6 glucose which further can be transformed into long-chain hydrocarbons by C-C coupling. In this study, C6 glucose is transformed into three chain alkanes, namely, C9, C12 and C15 using C-C coupling reactions under the gas and aqueous phase milieus. The geometry optimisation and vibrational frequency calculations are carried out at well-known hybrid-GGA functional, B3LYP with the basis set of 6-31+g(d,p) under the density functional theory framework. The single point energetics are calculated at M05-2X/6-311+g(3df,2p) level of theory. All thermochemical properties are calculated over a wide range of temperature between 300 and 900 K at an interval of 100 K. The thermochemistry suggested that the aqueous phase behaviour is suitable for the hydrolysis of sugar into long-chain alkanes compared to gas-phase environment. The hydrodeoxygenation reactions under each reaction pathway are found as most favourable reactions in both phases; however, aqueous phase dominates over gas phase in all discussed thermodynamic parameters.

  3. Microstructural observation on the composite Al-SiC-15p obtained by the compocasting process

    International Nuclear Information System (INIS)

    Manzano-Ramirez, A.; Ruiz, F.; Magallanes-Castaneda, A.

    1996-01-01

    In order to study how the processing variables of the compocasting process such as shear rate and solid fraction, influence the mechanical entrapment of SiCp in the aluminium matrix of the Al-SiC-xxp composite. In the present work, shear rate and solid fraction were varied (gamma=27, 120 and 219 s''-1 and fs=0.3, 0.4 and 0.5 respectively). In addition, the atomic force microscope (AFM) was used to investigate the surface topography of the composite, with the purpose of determine qualitatively, the chemical facilities of SEM it was attempted to determine the composition of the second phase responsible of bonding between matric and particulate. The results obtained in the AFM confirmed that the mechanical entrapment of the particles by the solid is more efficient at high solid fractions (fs>0.4) and high shear rates (gamma>120 s''-1). In contrast, at low fs(<0.3) and low gamma (<27 s''-1) such effect is poor. In addition, cualitative evidence, recorded by optical micrographs, illustrate the mechanism of dendritic fragmentation and change (from dendritic to globular) of the primary-solid phase in the compocasting process. SEM results suggested that bonding could be established through the silicon phase nevertheless it is considered that more accurate analysis are needed. (Author) 22 refs

  4. Experiments and strategies for the assignment of fully13 C/15N-labelled polypeptides by solid state NMR

    International Nuclear Information System (INIS)

    Straus, Suzana K.; Bremi, Tobias; Ernst, Richard R.

    1998-01-01

    High-resolution heteronuclear NMR correlation experiments and strategies are proposed for the assignment of fully 13 C/ 15 N-labelled polypeptides in the solid state. By the combination of intra-residue and inter-residue 13 C- 15 N correlation experiments with 13 C- 13 C spin-diffusion studies, it becomes feasible to partially assign backbone and side-chain resonances in solid proteins. The performance of sequences using 15 N instead of 13 C detection is evaluated regarding sensitivity and resolution for a labelled dipeptide (L-Val-L-Phe). The techniques are used for a partial assignment of the 15 N and 13 C resonances in human ubiquitin

  5. The complex transfer reaction (14C, 15O) on Ni, Zn and Ge targets: existence and mass of 69Ni

    International Nuclear Information System (INIS)

    Dessagne, P.; Bernas, M.; Langevin, M.; Pougheon, F.; Roussel, P.; Morrison, G.C.

    1984-01-01

    The ( 14 C, 15 O) complex transfer reaction has been studied at 72 MeV incident energy on 58 Ni, 60 Ni, 62 Ni, 64 Ni, 68 Zn, 70 Zn and 74 Ge, 76 Ge targets. Spectra and differential cross sections have been measured in a 5 0 angular range centred around a laboratory angle of 6 0 . The nucleus 69 Ni has been observed and its mass determined for the first time

  6. Properties of Surfactin C-15 Nanopeptide and Its Cytotoxic Effect on Human Cervix Cancer (HeLa Cell Line

    Directory of Open Access Journals (Sweden)

    Zahra Nozhat

    2012-01-01

    Full Text Available Surfactin is one of the most powerful biosurfactants that has been known so far. It is an acidic cyclic nonribosomal lipoheptapeptide that is produced by Bacillus subtilis. In this presentation we investigated different properties of surfactin C-15. The nanomicelle forming ability of surfactin C-15 in different aqueous environments with various ionic strengths was studied by scanning electron microscope. Surfactin second structure was investigated by Far-UV CD spectrum. Its hemolytic activity and cytotoxicity were measured by hemolysis and MTT assays, respectively. Surfactin formed spherical nanomicelles in distilled water and amorphous nanomicelles in PBS buffer . The hemolysis assay results indicated that HC50 of surfactin was 47 μM. Surfactin C-15 arrested growth of human cervix cancer HeLa cell line in a time- and dosage-dependent method, so that its IC50 at 16, 24, and 48h were 86.9, 73.1, and 50.2 μM, respectively.

  7. Application of unsymmetrical indirect covariance NMR methods to the computation of the (13)C (15)N HSQC-IMPEACH and (13)C (15)N HMBC-IMPEACH correlation spectra.

    Science.gov (United States)

    Martin, Gary E; Hilton, Bruce D; Irish, Patrick A; Blinov, Kirill A; Williams, Antony J

    2007-10-01

    Utilization of long-range (1)H--(15)N heteronuclear chemical shift correlation has continually grown in importance since the first applications were reported in 1995. More recently, indirect covariance NMR methods have been introduced followed by the development of unsymmetrical indirect covariance processing methods. The latter technique has been shown to allow the calculation of hyphenated 2D NMR data matrices from more readily acquired nonhyphenated 2D NMR spectra. We recently reported the use of unsymmetrical indirect covariance processing to combine (1)H--(13)C GHSQC and (1)H--(15)N GHMBC long-range spectra to yield a (13)C--(15)N HSQC-HMBC chemical shift correlation spectrum that could not be acquired in a reasonable period of time without resorting to (15)N-labeled molecules. We now report the unsymmetrical indirect covariance processing of (1)H--(13)C GHMBC and (1)H--(15)N IMPEACH spectra to afford a (13)C--(15)N HMBC-IMPEACH spectrum that has the potential to span as many as six to eight bonds. Correlations for carbon resonances long-range coupled to a protonated carbon in the (1)H--(13)C HMBC spectrum are transferred via the long-range (1)H--(15)N coupling pathway in the (1)H--(15)N IMPEACH spectrum to afford a much broader range of correlation possibilities in the (13)C--(15)N HMBC-IMPEACH correlation spectrum. The indole alkaloid vincamine is used as a model compound to illustrate the application of the method. (c) 2007 John Wiley & Sons, Ltd.

  8. Observaciones microestructurales en el composite Al-SiC-15p obtenido por el procedimiento de compocolado

    Directory of Open Access Journals (Sweden)

    Manzano-Ramírez, A.

    1996-12-01

    Full Text Available In order to study how the processing variables of the compocasting process, such as shear rate and solid fraction, influence the mechanical entrapment of SiCp in the aluminium matrix of the Al-SiC-xxp composite. In the present work, shear rate and solid fraction were varied (γ = 27, 120 and 219 s-1 and fs = 0.3, 0.4 and 0.5, respectively. In addition, the atomic force microscope (AFM was used to investigate the surface topography of the composite, with the purpose of determine, qualitatively, the degree of interfacial bonding between aluminium matrix and reinforcement elements. By using the Chemical facilities of SEM it was attempted to determine the composition of the second phase responsible of bonding between matrix and particulate. The results obtained in the AFM confirmed that the mechanical entrapment of the particles by the solid is more efficient at high solid fractions (fs > 0.4 and high shear rates (γ > 120 s-1. In contrast, at low fs (< 0.3 and low γ (< 27 s-1 such effect is poor. In addition, qualitative evidence, recorded by optical micrographs, illustrate the mechanism of dendritic fragmentation and change (from dendritic to globular of the primary-solid phase in the compocasting process. SEM results suggested that bonding could be established through the silicon phase nevertheless it is considered that more accurate analysis is needed.

    El propósito del presente trabajo es estudiar el efecto de las variables del procedimiento de compocolado (compocasting, velocidad de agitación y fracción de sólido, sobre el atrapamiento mecánico o incorporación de partículas de SiC a la matriz de aluminio del composite Al-SiC-15p. Para ello, se variaron la velocidad de corte, γ, y la fracción de sólido fs, (γ= 27, 120 y 213 s-1 y fs = 0,3, 0,4 y 0,5, respectivamente. Se utilizó el microscopio de fuerza atómica (AFM para observar la topografía del

  9. Benchmark fragment-based 1H, 13C, 15N and 17O chemical shift predictions in molecular crystals†

    Science.gov (United States)

    Hartman, Joshua D.; Kudla, Ryan A.; Day, Graeme M.; Mueller, Leonard J.; Beran, Gregory J. O.

    2016-01-01

    The performance of fragment-based ab initio 1H, 13C, 15N and 17O chemical shift predictions is assessed against experimental NMR chemical shift data in four benchmark sets of molecular crystals. Employing a variety of commonly used density functionals (PBE0, B3LYP, TPSSh, OPBE, PBE, TPSS), we explore the relative performance of cluster, two-body fragment, and combined cluster/fragment models. The hybrid density functionals (PBE0, B3LYP and TPSSh) generally out-perform their generalized gradient approximation (GGA)-based counterparts. 1H, 13C, 15N, and 17O isotropic chemical shifts can be predicted with root-mean-square errors of 0.3, 1.5, 4.2, and 9.8 ppm, respectively, using a computationally inexpensive electrostatically embedded two-body PBE0 fragment model. Oxygen chemical shieldings prove particularly sensitive to local many-body effects, and using a combined cluster/fragment model instead of the simple two-body fragment model decreases the root-mean-square errors to 7.6 ppm. These fragment-based model errors compare favorably with GIPAW PBE ones of 0.4, 2.2, 5.4, and 7.2 ppm for the same 1H, 13C, 15N, and 17O test sets. Using these benchmark calculations, a set of recommended linear regression parameters for mapping between calculated chemical shieldings and observed chemical shifts are provided and their robustness assessed using statistical cross-validation. We demonstrate the utility of these approaches and the reported scaling parameters on applications to 9-tertbutyl anthracene, several histidine co-crystals, benzoic acid and the C-nitrosoarene SnCl2(CH3)2(NODMA)2. PMID:27431490

  10. Benchmark fragment-based (1)H, (13)C, (15)N and (17)O chemical shift predictions in molecular crystals.

    Science.gov (United States)

    Hartman, Joshua D; Kudla, Ryan A; Day, Graeme M; Mueller, Leonard J; Beran, Gregory J O

    2016-08-21

    The performance of fragment-based ab initio(1)H, (13)C, (15)N and (17)O chemical shift predictions is assessed against experimental NMR chemical shift data in four benchmark sets of molecular crystals. Employing a variety of commonly used density functionals (PBE0, B3LYP, TPSSh, OPBE, PBE, TPSS), we explore the relative performance of cluster, two-body fragment, and combined cluster/fragment models. The hybrid density functionals (PBE0, B3LYP and TPSSh) generally out-perform their generalized gradient approximation (GGA)-based counterparts. (1)H, (13)C, (15)N, and (17)O isotropic chemical shifts can be predicted with root-mean-square errors of 0.3, 1.5, 4.2, and 9.8 ppm, respectively, using a computationally inexpensive electrostatically embedded two-body PBE0 fragment model. Oxygen chemical shieldings prove particularly sensitive to local many-body effects, and using a combined cluster/fragment model instead of the simple two-body fragment model decreases the root-mean-square errors to 7.6 ppm. These fragment-based model errors compare favorably with GIPAW PBE ones of 0.4, 2.2, 5.4, and 7.2 ppm for the same (1)H, (13)C, (15)N, and (17)O test sets. Using these benchmark calculations, a set of recommended linear regression parameters for mapping between calculated chemical shieldings and observed chemical shifts are provided and their robustness assessed using statistical cross-validation. We demonstrate the utility of these approaches and the reported scaling parameters on applications to 9-tert-butyl anthracene, several histidine co-crystals, benzoic acid and the C-nitrosoarene SnCl2(CH3)2(NODMA)2.

  11. Simple shearing flow of dry soap foams with tetrahedrally close-packed structure

    Energy Technology Data Exchange (ETDEWEB)

    Reinelt, Douglas A. [Department of Mathematics, Southern Methodist University, Dallas, Texas 75275-0156 (United States); Kraynik, Andrew M. [Engineering Sciences Center, Sandia National Laboratories, Albuquerque, New Mexico 87185-0834 (United States)

    2000-05-01

    The microrheology of dry soap foams subjected to quasistatic, simple shearing flow is analyzed. Two different monodisperse foams with tetrahedrally close-packed (TCP) structure are examined: Weaire-Phelan (A15) and Friauf-Laves (C15). The elastic-plastic response is evaluated by using the Surface Evolver to calculate foam structures that minimize total surface area at each value of strain. The foam geometry and macroscopic stress are piecewise continuous functions of strain. The stress scales as T/V{sup 1/3}, where T is surface tension and V is cell volume. Each discontinuity corresponds to large changes in foam geometry and topology that restore equilibrium to unstable configurations that violate Plateau's laws. The instabilities occur when the length of an edge on a polyhedral foam cell vanishes. The length can tend to zero smoothly or abruptly with strain. The abrupt case occurs when a small increase in strain changes the energy profile in the neighborhood of a foam structure from a local minimum to a saddle point, which can lead to symmetry-breaking bifurcations. In general, the new structure associated with each stable solution branch results from an avalanche of local topology changes called T1 transitions. Each T1 cascade produces different cell neighbors, reduces surface energy, and provides an irreversible, film-level mechanism for plastic yield behavior. Stress-strain curves and average stresses are evaluated by examining foam orientations that admit strain-periodic behavior. For some orientations, the deformation cycle includes Kelvin cells instead of the original TCP structure; but the foam does not remain perfectly ordered. Bifurcations during subsequent T1 cascades lead to disorder and can even cause strain localization. (c) 2000 Society of Rheology.

  12. General method of preparation of uniformly 13C, 15N-labeled DNA fragments for NMR analysis of DNA structures

    International Nuclear Information System (INIS)

    Rene, Brigitte; Masliah, Gregoire; Zargarian, Loussine; Mauffret, Olivier; Fermandjian, Serge

    2006-01-01

    Summary 13 C, 15 N labeling of biomolecules allows easier assignments of NMR resonances and provides a larger number of NMR parameters, which greatly improves the quality of DNA structures. However, there is no general DNA-labeling procedure, like those employed for proteins and RNAs. Here, we describe a general and widely applicable approach designed for preparation of isotopically labeled DNA fragments that can be used for NMR studies. The procedure is based on the PCR amplification of oligonucleotides in the presence of labeled deoxynucleotides triphosphates. It allows great flexibility thanks to insertion of a short DNA sequence (linker) between two repeats of DNA sequence to study. Size and sequence of the linker are designed as to create restriction sites at the junctions with DNA of interest. DNA duplex with desired sequence and size is released upon enzymatic digestion of the PCR product. The suitability of the procedure is validated through the preparation of two biological relevant DNA fragments

  13. Regional cerebral perfusion measurements: a comparative study of xenon-enhanced CT and C15O2 build-up using dynamic PET

    International Nuclear Information System (INIS)

    St Lawrence, K.S.; Bews, J.; Dunscombe, P.B.

    1992-01-01

    Regional cerebral perfusion can be determined by monitoring the uptake of a diffusable tracer concurrently in cerebral tissue and arterial blood. Two techniques based on this methodology are xenon-enhanced computed tomography (Xe CT) and C 15 O 2 build-up using dynamic positron emission tomography (C 15 O 2 PET). Serial images are used by both Xe CT and C 15 O 2 PET to characterize the uptake of the tracer in cerebral tissue. The noise present in these images will reduce the precision of the perfusion measurements obtained by either technique. Using Monte Carlo type computer simulations, the precision of the two techniques as a function of image noise has been examined. On the basis of their results, they conclude that the precision of the Xe CT technique is comparable to the precision of C 15 O 2 PET when realistic clinical protocols are employed for both. (author)

  14. The synthetic human beta-defensin-3 C15 peptide exhibits antimicrobial activity against Streptococcus mutans, both alone and in combination with dental disinfectants.

    Science.gov (United States)

    Ahn, Ki Bum; Kim, A Reum; Kum, Kee-Yeon; Yun, Cheol-Heui; Han, Seung Hyun

    2017-10-01

    Streptococcus mutans is a major etiologic agent of human dental caries that forms biofilms on hard tissues in the human oral cavity, such as tooth and dentinal surfaces. Human β-defensin-3 (HBD3) is a 45-amino-acid natural antimicrobial peptide that has broad spectrum antimicrobial activity against bacteria and fungi. A synthetic peptide consisting of the C-terminal 15 amino acids of HBD3 (HBD3-C15) was recently shown to be sufficient for its antimicrobial activity. Thus, clinical applications of this peptide have garnered attention. In this study, we investigated whether HBD3-C15 inhibits the growth of the representative cariogenic pathogen Streptococcus mutans and its biofilm formation. HBD3-C15 inhibited bacterial growth, exhibited bactericidal activity, and attenuated bacterial biofilm formation in a dose-dependent manner. HBD3-C15 potentiated the bactericidal and anti-biofilm activity of calcium hydroxide (CH) and chlorhexidine digluconate (CHX), which are representative disinfectants used in dental clinics, against S. mutans. Moreover, HBD3-C15 showed antimicrobial activity by inhibiting biofilm formation by S. mutans and other dentinophilic bacteria such as Enterococcus faecalis and Streptococcus gordonii, which are associated with dental caries and endodontic infection, on human dentin slices. These effects were observed for HBD3-C15 alone and for HBD3-C15 in combination with CH or CHX. Therefore, we suggest that HBD3-C15 is a potential alternative or additive disinfectant that can be used for the treatment of oral infectious diseases, including dental caries and endodontic infections.

  15. Methods for sequential resonance assignment in solid, uniformly 13C, 15N labelled peptides: Quantification and application to antamanide

    International Nuclear Information System (INIS)

    Detken, Andreas; Hardy, Edme H.; Ernst, Matthias; Kainosho, Masatsune; Kawakami, Toru; Aimoto, Saburo; Meier, Beat H.

    2001-01-01

    The application of adiabatic polarization-transfer experiments to resonance assignment in solid, uniformly 13 C- 15 N-labelled polypeptides is demonstrated for the cyclic decapeptide antamanide. A homonuclear correlation experiment employing the DREAM sequence for adiabatic dipolar transfer yields a complete assignment of the C α and aliphatic side-chain 13 C resonances to amino acid types. The same information can be obtained from a TOBSY experiment using the recently introduced P9 1 12 TOBSY sequence, which employs the J couplings as a transfer mechanism. A comparison of the two methods is presented. Except for some aromatic phenylalanine resonances, a complete sequence-specific assignment of the 13 C and 15 N resonances in antamanide is achieved by a series of selective or broadband adiabatic triple-resonance experiments. Heteronuclear transfer by adiabatic-passage Hartmann-Hahn cross polarization is combined with adiabatic homonuclear transfer by the DREAM and rotational-resonance tickling sequences into two- and three-dimensional experiments. The performance of these experiments is evaluated quantitatively

  16. Quality of Life in Patients With Brain Metastases Using the EORTC QLQ-BN20+2 and QLQ-C15-PAL

    International Nuclear Information System (INIS)

    Caissie, Amanda; Nguyen, Janet; Chen, Emily; Zhang Liying; Sahgal, Arjun; Clemons, Mark; Kerba, Marc; Arnalot, Palmira Foro; Danjoux, Cyril; Tsao, May; Barnes, Elizabeth; Holden, Lori; Danielson, Brita; Chow, Edward

    2012-01-01

    Purpose: The 20-item European Organisation for Research and Treatment of Cancer Quality of Life Questionnaire–Brain Neoplasm (QLQ-BN20) is a validated quality-of-life (QOL) questionnaire for patients with primary brain tumors. The European Organisation for Research and Treatment of Cancer Quality of Life Questionnaire–Core 15 Palliative (QLQ-C15-PAL) core palliative questionnaire is a 15-item version of the core 30-item QLQ-C30 and was developed to decrease the burden on patients with advanced cancer. The combination of the QLQ-BN20 and QLQ-C30 to assess QOL may be too burdensome for patients. The primary aim of this study was to assess QOL in patients before and after treatment for brain metastases using the QLQ-BN20+2 and QLQ-C15-PAL, a version of the QLQ-BN20 questionnaire with 2 additional questions assessing cognitive functioning that were not addressed in the QLQ-C15-PAL. Methods and Materials: Patients with brain metastases completed the QLQ-C15-PAL and QLQ-BN20+2 questionnaires to assess QOL before and 1 month after radiation. Linear regression analysis was used to assess changes in QOL scores over time, as well as to explore associations between the QLQ-BN20+2 and QLQ-C15-PAL scales, patient demographics, and clinical variables. Spearman correlation assessed associations between the QLQ-BN20+2 and QLQ-C15-PAL scales. Results: Among 108 patients, the majority (55%) received whole-brain radiotherapy only, with 65% of patients completing follow-up at 1 month after treatment. The most prominent symptoms at baseline were future uncertainty (QLQ-BN20+2) and fatigue (QLQ-C15-PAL). After treatment, significant improvement was seen for the QLQ-C15-PAL insomnia scale, as well as the QLQ-BN20+2 scales of future uncertainty, visual disorder, and concentration difficulty. Baseline Karnofsky Performance Status was negatively correlated to QLQ-BN20+2 motor dysfunction but positively related to QLQ-C15-PAL physical functioning and QLQ-BN20+2 cognitive functioning at

  17. Quality of Life in Patients With Brain Metastases Using the EORTC QLQ-BN20+2 and QLQ-C15-PAL

    Energy Technology Data Exchange (ETDEWEB)

    Caissie, Amanda; Nguyen, Janet; Chen, Emily; Zhang Liying [Rapid Response Radiotherapy Program, Odette Cancer Centre, Sunnybrook Health Sciences Centre, University of Toronto, Toronto, Ontario (Canada); Sahgal, Arjun [Rapid Response Radiotherapy Program, Odette Cancer Centre, Sunnybrook Health Sciences Centre, University of Toronto, Toronto, Ontario (Canada); Department of Radiation Oncology, Princess Margaret Hospital, University of Toronto, Toronto, Ontario (Canada); Clemons, Mark [Department of Medical Oncology, Ottawa Hospital Cancer Centre, Ottawa, Ontario (Canada); Kerba, Marc [Department of Radiation Oncology, Tom Baker Cancer Centre, Calgary, Alberta (Canada); Arnalot, Palmira Foro [Parc de Salut Mar Hospital de l' Esperanca, Barcelona (Spain); Danjoux, Cyril; Tsao, May; Barnes, Elizabeth; Holden, Lori [Rapid Response Radiotherapy Program, Odette Cancer Centre, Sunnybrook Health Sciences Centre, University of Toronto, Toronto, Ontario (Canada); Danielson, Brita [Department of Radiation Oncology, Cross Cancer Institute, Edmonton, Alberta (Canada); Chow, Edward, E-mail: edward.chow@sunnybrook.ca [Rapid Response Radiotherapy Program, Odette Cancer Centre, Sunnybrook Health Sciences Centre, University of Toronto, Toronto, Ontario (Canada)

    2012-07-15

    Purpose: The 20-item European Organisation for Research and Treatment of Cancer Quality of Life Questionnaire-Brain Neoplasm (QLQ-BN20) is a validated quality-of-life (QOL) questionnaire for patients with primary brain tumors. The European Organisation for Research and Treatment of Cancer Quality of Life Questionnaire-Core 15 Palliative (QLQ-C15-PAL) core palliative questionnaire is a 15-item version of the core 30-item QLQ-C30 and was developed to decrease the burden on patients with advanced cancer. The combination of the QLQ-BN20 and QLQ-C30 to assess QOL may be too burdensome for patients. The primary aim of this study was to assess QOL in patients before and after treatment for brain metastases using the QLQ-BN20+2 and QLQ-C15-PAL, a version of the QLQ-BN20 questionnaire with 2 additional questions assessing cognitive functioning that were not addressed in the QLQ-C15-PAL. Methods and Materials: Patients with brain metastases completed the QLQ-C15-PAL and QLQ-BN20+2 questionnaires to assess QOL before and 1 month after radiation. Linear regression analysis was used to assess changes in QOL scores over time, as well as to explore associations between the QLQ-BN20+2 and QLQ-C15-PAL scales, patient demographics, and clinical variables. Spearman correlation assessed associations between the QLQ-BN20+2 and QLQ-C15-PAL scales. Results: Among 108 patients, the majority (55%) received whole-brain radiotherapy only, with 65% of patients completing follow-up at 1 month after treatment. The most prominent symptoms at baseline were future uncertainty (QLQ-BN20+2) and fatigue (QLQ-C15-PAL). After treatment, significant improvement was seen for the QLQ-C15-PAL insomnia scale, as well as the QLQ-BN20+2 scales of future uncertainty, visual disorder, and concentration difficulty. Baseline Karnofsky Performance Status was negatively correlated to QLQ-BN20+2 motor dysfunction but positively related to QLQ-C15-PAL physical functioning and QLQ-BN20+2 cognitive functioning at

  18. Nitrogen Fertilizer and Straw Applications Affect Uptake of 13C,15N-Glycine by Soil Microorganisms in Wheat Growth Stages.

    Directory of Open Access Journals (Sweden)

    Lijie Yang

    Full Text Available This study investigated the influence of nitrogen (N fertilizer and straw on intact amino acid N uptake by soil microorganisms and the relationship between amino acid turnover and soil properties during the wheat growing season. A wheat pot experiment was carried out with three treatments: control (CK, N fertilizer (NF and N fertilizer plus rice straw (NS. We used stable isotope compound-specific analysis to determine the uptake of 13C,15N-glycine by soil microorganisms. In the NF treatment, microbial 13C,15N-glycine uptake was lower compared with CK, suggesting that inorganic N was the preferred N source for soil microorganisms. However, The application of straw with N fertilizer (in NS treatment increased microbial 13C,15N-glycine uptake even with the same amount of N fertilizer application. In this treatment, enzyme activities, soil microbial biomass C and microbial biomass N increased simultaneously because more C was available. Soil mineral N and plant N contents all decreased substantially. The increased uptake of intact 13C,15N-glycine in the NS treatment can be attributed to direct assimilation by soil microorganisms to satisfy the demand for N when inorganic N was consumed.

  19. 300C/15 kW power converter with AlGaN/GaN-Si MOS-HFETs for electric propulsion systems, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — Capitalizing on a strong expertise in III-Nitride epitaxy, GaN-Si power device designs, and wide-bandgap power electronics, researchers at GeneSiC Semiconductor...

  20. 15N NMR study on cyanide (C15N-) complex of cytochrome P-450cam. Effects of d-camphor and putidaredoxin on the iron-ligand structure

    International Nuclear Information System (INIS)

    Shiro, Yoshitsugu; Iizuka, Tetsutaro; Makino, Ryu; Ishimura, Yuzuru; Morishima, Isao

    1989-01-01

    The cyanide (C 15 N - ) complex of Pseudomonas putida cytochrome P-450 (P-450 cam ) exhibited well-resolved and hyperfine-shifted 15 N NMR resonances arising from the iron-bound C 15 N - at 423 and 500 ppm in the absence and presence of the substrate, d-camphor, respectively. The values were smaller than those for cyanide complexes of myoglobin and hemoglobin (∼ 1000 ppm) but fell into the same range as those for the cyanide complexes of peroxidases (∼ 500 ppm). The 15 N shift values of P-450 cam were not incompatible with the existence of anionic ligand, such as cysteinyl thiolate anion, at the fifth coordination site of heme iron. The difference in the 15 N chemical shift values between camphor-free and bound enzymes was inferred by the increase in the steric constraint to the Fe-C-N bond upon substrate binding

  1. Inelastic proton scattering at 800 MeV to the 12C 15.11-MeV state: A search for nuclear critical opalescence

    International Nuclear Information System (INIS)

    Haji-Saeid, M.; Glashausser, C.; Igo, G.; Cornelius, W.; Gazzaly, M.; Irom, F.; McClelland, J.; Moss, J.M.; Pauletta, G.; Thiessen, H.A.; Whitten, C.A. Jr.

    1980-01-01

    The differential cross section for the reaction 12 C(p,p') 12 C* (15.11 MeV, 1 + , T=1) has been measured at 800 MeV; the range of the angular distribution corresponds to momentum transfers of 0.7--2.4 fm -1 [(1-3.3)m/sub π/]. The cross section decreases almost exponentially at large angles; no maximum is observed in the region where nuclear critical opalescence might be expected

  2. The interest of the C15O2 method for the left to right cardiac shunts evaluation. A comparison with the sup(99m)Tc pertechnetate method

    International Nuclear Information System (INIS)

    Therain, F.; Gros, J.; Debrun, D.; Blond, M.T.; Valois, M.

    1982-01-01

    99mTc pertechnetate dilution method (TcM) is a reference for the left to right shunts (L→RS) evaluation as well as oxymetry is. Another radionuclide method using C 15 O 2 (CO 2 M) was compared with TcM. The results obtained with CO 2 M confirm the reliability of the CO 2 M for the L→RS investigation. Characteristics of both non invasive radionuclide methods are summarized. The advantages of CO 2 M are that it is always available even in presence of valvular insufficiency, severe congestive heart failure, multiple cardiac lesions and that it is always repeatable giving an intra assay control unaccessible to TcM and finally it produces a much lower radiation absorbed dose with a special interest for children investigations

  3. The fate of 13C15N labelled glycine in permafrost and surface soil at simulated thaw in mesocosms from high arctic and subarctic ecosystems

    DEFF Research Database (Denmark)

    Ravn, Nynne Marie Rand; Elberling, Bo; Michelsen, Anders

    2017-01-01

    Background and aim: Nutrient distribution and carbon fluxes upon spring thaw are compared in mesocosms from high arctic and subarctic ecosystems dominated by Cassiope tetragona or Salix hastata/Salix arctica, in order to evaluate the possibility of plant and microbial utilization of an organic...... compound in thawing permafrost and surface soil. Methods: Double labeled glycine (13C15N) was added to soil columns with vegetation and to permafrost. During thaw conditions ecosystem respiration 13C was measured and 13C and 15N distribution in the ecosystem pools was quantified one day and one month after...... glycine addition. Results: Near-surface soil microbes were more efficient in the uptake of intact glycine immediately upon thaw than plants. After one month plants had gained more 15N whereas microbes seemed to lose 15N originating from glycine. We observed a time lag in glycine degradation upon...

  4. Decomposition of 14C-15N straw incorporated at three depths in a red-yellow latosol at Pernambuco State, Brazil

    International Nuclear Information System (INIS)

    Sampaio, E.V.S.; Salcedo, I.H.; Bettany, J.

    1990-01-01

    The decomposition of 14 C- 15 N labelled straw, incorporated at three depths in a Red-yellow Latosol from the humid, coastal zone of Pernambuco State, Brazil, was measured during two years. The straw was ground, mixed with soil portions and placed in 400-mesh bags and replaced into the original field sites at 10, 30 and 60cm depth. The decomposition was also followed in the laboratory using soil from the superficial layer. Straw carbon losses in the field reached 52% during the first month and about 80% after two years. In the first 4 months mineralization was faster in the superficial layer, with no differences thereafter. In the laboratory, mineralization was slower than in the field, reaching 34 and 50% after one month and two years, respectively. During the first month, most of the soil microbial biomass was apparently formed from straw derived material but the contribution from the straw decrease to 15-30% after two months and to less than 1% after two years. Straw N losses reached 25% in the first month and 40-50% after two years, with significant differences among soil depths in the first six months when losses were higher in the deeper layers. There were no plants to absorb the mineral N which accumulated in the soil to a concentration of up to 32μg/g soil. The contribution of straw N to this mineral N decreased with incubation period but was always less than 12%. The C:N ratio of straw derived material ( 14 C- 15 N) decreased from 22:1 to 8-10:1, at all depths. (author)

  5. Cerebral blood flow and metabolism in a patient with motor aphasia by positron emission tomography using 15O2 and C15O2

    International Nuclear Information System (INIS)

    Kitamura, Shin; Terashi, Akiro; Kato, Toshiaki; Soeda, Toshiyuki; Iio, Masaaki.

    1986-01-01

    Cerebral blood flow and metabolism, in a patient with motor aphasia due to cerebral infarction of the left basal ganglionic region, were studied by positron emission tomography (PET) using 15 O 2 and C 15 O 2 . A 62-year-old woman, right handed, was admitted with a complaint of right hemiparesis. Motor aphasia developed on the following day of hospitalization. CT scan showed low density area in the left caduate nucleus, putamen, internal capsule, and centrum semiovale, but the cortex was intact on the images of CT scan. PET studies were performed 22 days and 92 days after onset of stroke. The first PET study revealed marked reduction of CBF (cerebral blood flow) in the left cortex and subcortex, but CMRO 2 (cerebral oxygen consumption) was relatively preserved and OEF (oxygen extraction fraction) increased. The second PET study showed recovery of CBF in the left cortex and increase of OEF vanished. CMRO 2 decreased in the left posterior frontal region and subcortex. Motor aphasia still continued at the time of the second PET study. Therefore, the left posterior frontal cortex lesion as well as the left subcortex lesion might be related to the occurrence of motor aphasia in this case. The thresholds of CBF and CMRO 2 for developing clinical symptoms are higher than those for developing low density on the images of CT scan. These results suggest the importance of the study of cerebral blood flow and metabolism in the study of the responsible lesion for aphasia. (author)

  6. Quantification of a Novel Photosensitizer of Chlorin e6-C15-Monomethyl Ester in Beagle Dog Plasma Using HPLC: Application to Pharmacokinetic Studies

    Directory of Open Access Journals (Sweden)

    Xiuxiu Li

    2017-04-01

    Full Text Available Chlorin e6-C15-monomethyl ester (CMME is a novel photosensitizer, which is synthetized from the degradation products of silkworm excrement. Preclinical studies on the promising photosensitizer CMME are necessary to determine its therapeutic efficacy and druglikeness. A high-performance liquid chromatography with UV detection (HPLC–UV method was established for the determination of CMME in beagle dog plasma. The sample preparation involved a protein-precipitation method with acetonitrile after the addition of tanshinone IIA as an internal standard (IS. CMME and the IS were separated on a Diamonsil C18 (2 column (100 mm × 4.6 mm, 5 μm with a isocratic system of methanol–water containing 20 mM ammonium acetate with 0.3% glacial acetic acid (85:15, v/v. The flow rate was 1.0 mL/min with UV detection using a wavelength of 400 nm. The method was sensitive enough with a lower limit of quantitation (LLOQ of 0.05 μg/mL and had a good linearity (r2 > 0.999 over the linear range of 0.05–5.00 μg/mL. The intra-day and inter-day accuracies ranged from 98.5% to 102.8% and precisions (RSD were within 6.8%. The validated method was successfully applied to the pharmacokinetic study of CMME after intravenous administration of single and multiple doses in beagle dogs.

  7. Rethinking Sensitized Luminescence in Lanthanide Coordination Polymers and MOFs: Band Sensitization and Water Enhanced Eu Luminescence in [Ln(C15H9O5)3(H2O)3]n (Ln = Eu, Tb).

    Science.gov (United States)

    Einkauf, Jeffrey D; Kelley, Tanya T; Chan, Benny C; de Lill, Daniel T

    2016-08-15

    A coordination polymer [Ln(C15H9O9)3(H2O)3]n (1-Ln = Eu(III), Tb(III)) assembled from benzophenonedicarboxylate was synthesized and characterized. The organic component is shown to sensitize lanthanide-based emission in both compounds, with quantum yields of 36% (Eu) and 6% (Tb). Luminescence of lanthanide coordination polymers is currently described from a molecular approach. This methodology fails to explain the luminescence of this system. It was found that the band structure of the organic component rather than the molecular triplet state was able to explain the observed luminescence. Deuterated (Ln(C15H9O9)3(D2O)3) and dehydrated (Ln(C15H9O9)3) analogues were also studied. When bound H2O was replaced by D2O, lifetime and emission increased as expected. Upon dehydration, lifetimes increased again, but emission of 1-Eu unexpectedly decreased. This reduction is reasoned through an unprecedented enhancement effect of the compound's luminescence by the OH/OD oscillators in the organic-to-Eu(III) energy transfer process.

  8. Simultaneous measurement of cerebral blood flow and oxygen extraction fraction by positron emission tomography: theoretical study and experimental evidence of cerebral blood flow measurement with the C15O2 continuous inhalation technique

    International Nuclear Information System (INIS)

    Steinling, M.

    1983-01-01

    The method of the continuous inhalation technique of oxygen-15 labelled CO 2 coupled with positron emission tomography for the measurement of cerebral blood flow (C.B.F.) is described. An indirect experimental verification that this technique allowed the measurement of C.B.F. has been carried out in baboons by showing the expected change in the measured parameter with variations in the PaCO 2 . A critical investigation of the C 15 O 2 model was performed. The amount of tracer present in the cerebral vascular pool has a negligible effect on C.B.F. value. The use of a mean brain-blood partition coefficient of water instead of that specific to gray or to white matter is commented upon, and its influence on the final C.B.F. value is studied. Lastly, the problem of the limited diffusion of water across the blood-brain-barrier is discussed. The study of the combined effects of gray-white mixing and limited wates extraction of the C.B.F. value shows that the C 15 O 2 technique tends to understimate real C.B.F., and that this error is more severe with high flows and even gray white mixing. These limitations do not depart from the possibility to estimate in the same brain locus not only C.B.F. but oxygen utilization as well by the consecutive inhalation of C 15 O 2 and 15 O 2 . The advantages of this possibility has already been shown in a number of clinical studies [fr

  9. Comparative study of the interaction of meso-tetrakis (N-para-trimethyl-anilium) porphyrin (TMAP) in its free base and Fe derivative form with oligo(dA.dT)15 and oligo(dG.dC)15.

    Science.gov (United States)

    Bathaie, S Zahra; Ajloo, Davood; Daraie, Marzieh; Ghadamgahi, Maryam

    2015-01-01

    Interaction between a cationic porphyrin and its ferric derivative with oligo(dA.dT)15 and oligo(dG.dC)15 was studied by UV-vis spectroscopy, resonance light scattering (RLS), and circular dichroism (CD) at different ionic strengths; molecular docking and molecular dynamics simulation were also used for completion. Followings are the observed changes in the spectral properties of meso-tetrakis (N-para-trimethyl-anilium) porphyrin (TMAP), as a free-base porphyrin with no axial ligand, and its Fe derivative (FeTMAP) upon interaction with oligo(dA.dT)15 and oligo(dG.dC)15: (1) the substantial red shift and hypochromicity at the Soret maximum in the UV-vis spectra; (2) the increased RLS intensity by increasing the ionic strength; and (3) an intense bisignate excitonic CD signal. All of them are the reasons for TMAP and FeTMAP binding to oligo(dA.dT)15 and oligo(dG.dC)15 with the outside binding mode, accompanied by the self-stacking of the ligands along the oligonucleotide helix. The CD results demonstrated a drastic change from excitonic in monomeric behavior at higher ionic strengths, which indicates the groove binding of the ligands with oligonucleotides. Molecular docking also confirmed the groove binding mode of the ligands and estimated the binding constants and energies of the interactions. Their interaction trend was further confirmed by molecular dynamics technique and structure parameters obtained from simulation. It showed that TMAP reduced the number of intermolecular hydrogen bonds and increased the solvent accessible surface area in the oligonucleotide. The self-aggregation of ligands at lower concentrations was also confirmed.

  10. High purity liquid phase epitaxial gallium arsenide nuclear radiation detector

    International Nuclear Information System (INIS)

    Alexiev, D.; Butcher, K.S.A.

    1991-11-01

    Surface barrier radiation detector made from high purity liquid phase epitaxial gallium arsenide wafers have been operated as X- and γ-ray detectors at various operating temperatures. Low energy isotopes are resolved including 241 Am at 40 deg C. and the higher gamma energies of 235 U at -80 deg C. 15 refs., 1 tab., 6 figs

  11. Polymorphism in the Laves-phase precipitates of a quinternary Nb-Mo-Cr-Al-Si alloy

    International Nuclear Information System (INIS)

    Hu Yanling; Vasiliev, Alexandre; Zhang Lichun; Song, Kai; Aindow, Mark

    2009-01-01

    Transmission electron microscopy has been used to study the precipitates that develop in the A2 phase of an Nb-Mo-Cr-Al-Si alloy upon heat treatment. The precipitates include a Laves-phase that adopts the cubic C15 structure initially and the hexagonal C14 structure in the later stages of precipitation. The morphologies, orientation relationships and defect microstructures indicate that the metastable C15 phase arises due to tensile coherency stresses and that a synchroshear polymorphic transformation to the equilibrium C14 phase occurs as these relax

  12. 1H, 13C and 13N chemical shifts and 1H-15N and 13C-15N heteronuclear spin-spin coupling constants n the NMR spectra of 5-substituted furfural oximes

    International Nuclear Information System (INIS)

    Popelis, Yu.Yu.; Liepin'sh, E.E.; Lukevits, E.Ya.

    1986-01-01

    The 1 H, 13 C, and 15 N NMR spectra of 15 N-enriched 5-substituted furfural oximes were investigated. It was shown that the chemical shifts of the ring atoms and the oxime group correlate satisfactorily with the F and R substituent constants, whereas their sensitivity to the effect of the substituents is lower than in monosubstituted furan derivatives. The constants of spin-spin coupling between the ring protons and the oxime group were determined. An analysis of the 1 H- 1 H spin-spin coupling constants (SSCC) on the basis of their stereospecificity indicates that the E isomers have primarily an s-trans conformation in polar dimethyl sulfoxide, whereas the Z isomers, on the other hand, have an s-cis conformation. The signs of the direct and geminal 13 C- 15 N SSCC were determined for 5-trimethylsilylfurfural oxime

  13. Electron concentration and phase stability in NbCr2-based Laves phase alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, J.H.; Liaw, P.K. [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Materials Science and Engineering; Liu, C.T. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1997-05-12

    Phase stability in NbCr{sub 2}-based transition-metal Laves phases was studied, based on the data reported for binary X-Cr, Nb-X, and ternary Nb-Cr-X phase diagrams. It was shown that when the atomic size ratios are kept identical, the average electron concentration factor, e/a, is the dominating factor in controlling the phase stability of NbCr{sub 2}-based transition-metal Laves phases. The e/a ratios for different Laves polytypes were determined as followed: with e/a < 5.76, the C15 structure is stabilized; at an e/a range of 5.88--7.53, the C14 structure is stabilized; with e/a > 7.65, the C15 structure is stabilized again. A further increase in the electron concentration factor (e/a > 8) leads to the disordering of the alloy. The electron concentration effect on the phase stability of Mg-based Laves phases and transition-metal A{sub 3}B intermetallic compounds is also reviewed and compared with the present observations in transition-metal Laves phases. In order to verify the e/a/phase stability relationship experimentally, additions of Cu (with e/a = 11) were selected to replace Cr in the NbCr{sub 2} Laves phase. Experimental results for the ternary Nb-Cr-Cu system are reported and discussed in terms of the correlation between the e/a ratio and phase stability in NbCr{sub 2}-based Laves phases. A new phase was found, which has an average composition of Nb-47Cr-3Cu. Within the solubility limit, the electron concentration and phase stability relationship is obeyed in the Nb-Cr-Cu system.

  14. Electron diffraction analysis of an AB{sub 2}-type Laves phase for hydrogen battery applications

    Energy Technology Data Exchange (ETDEWEB)

    Shi, Z.; Chumbley, S.; Laabs, F.C. [Iowa State Univ., Ames, IA (United States). Ames Lab.

    2000-11-16

    A multicomponent AB{sub 2} type nickel-metal hydride (Ni-MH) battery alloy prepared by high-pressure gas atomization (HPGA) was investigated by transmission electron microscopy (TEM) in both the as-atomized and heat treated condition. TEM examination showed a heavily faulted dendritic growth structure in as-atomized powder. Selected area diffraction (SAD) showed that this region consisted of both a cubic C15 structure with lattice constant a=7.03 A and an hexagonal C14 structure with lattice parameter a=4.97 A, c=8.11 A. The orientation relationship (OR) between the C14 and C15 structures was determined to be (111)[1 anti 10]{sub C15}//(0001)[11 anti 20]C{sub 14}. An interdendritic phase possessing the C14 structure was also seen. There was also a very fine grain region consisting of the C14 structure. Upon heat treatment, the faulted structure became more defined and appeared as intercalation layers within the grains. Spherical particles rich in Zr and Ni appeared scattered at the grain boundries instead of the C14 interdendritic phase. The polycrystalline region also changed to a mixture of C14 and C15 structures. The phase stability of the C15 and C14 structures based on a consideration of atomic size factor and the average electron concentration is discussed. (orig.)

  15. Triple resonance experiments for the simultaneous correlation of H6/H5 and exchangeable protons of pyrimidine nucleotides in 13C,15N-labeled RNA applicable to larger RNA molecules

    International Nuclear Information System (INIS)

    Woehnert, Jens; Goerlach, Matthias; Schwalbe, Harald

    2003-01-01

    Triple-resonance two-dimensional H6/H5(C4N)H and C6/C5(C4N)H experiments are described that provide through-bond H6/H5 or C6/C5 to imino/amino correlations in pyrimidine bases in 13 C, 15 N-labeled RNA. The experiments simultaneously transfer H6/H5 magnetization by an INEPT step to the C6/C5 nuclei and by homonuclear CC- and heteronuclear CN-TOCSY steps via the intervening C4 nucleus to the N3/N4 nuclei and then by a reverse INEPT step to the imino/amino hydrogens. The sensitivity of these experiments is high as demonstrated using a 30-nucleotide pyrimidine rich RNA at a concentration of 0.9 mM at temperatures of 10 deg. C and 25 deg. C. This indicates the general applicability of the experiments and the possibility to obtain correlations for imino resonances in non-canonical regions of the target RNA

  16. Critical points in the Bragg glass phase of a weakly pinned crystal of ...

    Indian Academy of Sciences (India)

    the dynamical annealing of the disordered bundles of vortices injected through the sample edges towards the destined ... weakly pinned crystals of the systems like, 2H-NbSe2 and the cubic (C15) CeRu2. [12]. ... systems. This in turn im- ..... We show in figure 6 an updated version of the vortex phase diagram in the given.

  17. Order-disorder phase transition in ZrV2Dsub(3.6)

    International Nuclear Information System (INIS)

    Didisheim, J.-J.; Yvon, K.; Tissot, P.

    1981-01-01

    The deuterated C15-type Laves phase ZrV 2 Dsub(3.6) undergoes a structural phase transition near room temperature (T of the order of 325 K). In the cubic high-temperature phase the deuterium atoms are disordered over two types of tetrahedral interstices, the centres of which are 1.3 A apart. In the tetragonal low-temperature phase the D atoms are ordered and occupy only the energetically more favourable interstices. The tetragonal structure is isotypic with the low-temperature phase of HfV 2 D 4 . The shortest D-D distance is 2.1 A. (author)

  18. Hyperfine spectroscopic study of Laves phase HfFe2

    International Nuclear Information System (INIS)

    Belosevic-Cavor, J.; Novakovic, N.; Cekic, B.; Ivanovic, N.; Manasijevic, M.

    2004-01-01

    Hyperfine fields in HfFe 2 were measured at 181 Ta probe using the time-differential perturbed angular correlation method (TDPAC) in the temperature range 78-1200 K. Analysis of the spectra revealed two interactions with hyperfine fields of 13.82(7) T and 8.0(2) T, at 293 K. First is ascribed to the interaction at the 8a position in the cubic C15 structure. The second can be assigned to a minor amount of hexagonal C14 phase, or to an irregular position of the probe in the C15 lattice. Results of calculations using LAPW-WIEN97 are in a good agreement with experiment

  19. Mixed phase in cubic and hexagonal HoMn2111Cd PAC and 119Sn, 57Fe Moessbauer studies

    International Nuclear Information System (INIS)

    Cottenier, S.; Meersschaut, J.; Demuynck, S.; Swinnen, B.; Rots, M.

    1998-01-01

    Hyperfine parameters on 57 Fe, 119 Sn and 111 Cd substituted into the Mn sublattice were measured by Moessbauer and PAC spectroscopies. From these results it is tentatively concluded that C15 and C14 HoMn 2 are mixed-phase compounds. In C14 HoMn 2 there is no (or small) moment on the 2a site. (orig.)

  20. High pressure studies of YMn{sub 2} Laves phase and its deuterides

    Energy Technology Data Exchange (ETDEWEB)

    Sugiura, H.; Paul-Boncour, V.; Percheron-Guegan, A.; Marchuk, I.; Hirata, T.; Filipek, S.M.; Dorogova, M

    2004-03-24

    The C15 Laves phase intermetallic YMn{sub 2} and its deuterides containing 1.15, 2, 3.4 and 4 deuterium (D) atoms per formula unit (pfu) (the structure of YMn{sub 2}D{sub 4} is rhombohedral whereas other three deuterides preserve the cubic C15 structure) were compressed up to 31 GPa by using diamond anvil cell (DAC). Parameters of equation of state (EOS) were derived for all phases investigated. The discontinuous change of bulk modulus under high pressure has been revealed for all samples investigated. Two deuterides, YMn{sub 2}D{sub 1.15} and YMn{sub 2}D{sub 2}, decomposed reversibly under pressure into two phases: poor and enriched in deuterium.

  1. Phase transitions

    CERN Document Server

    Sole, Ricard V; Solé, Ricard V; Solé, Ricard V; Sol, Ricard V; Solé, Ricard V

    2011-01-01

    Phase transitions--changes between different states of organization in a complex system--have long helped to explain physics concepts, such as why water freezes into a solid or boils to become a gas. How might phase transitions shed light on important problems in biological and ecological complex systems? Exploring the origins and implications of sudden changes in nature and society, Phase Transitions examines different dynamical behaviors in a broad range of complex systems. Using a compelling set of examples, from gene networks and ant colonies to human language and the degradation of diverse ecosystems, the book illustrates the power of simple models to reveal how phase transitions occur. Introductory chapters provide the critical concepts and the simplest mathematical techniques required to study phase transitions. In a series of example-driven chapters, Ricard Solé shows how such concepts and techniques can be applied to the analysis and prediction of complex system behavior, including the origins of ...

  2. Phase field

    International Nuclear Information System (INIS)

    Radhakrishnan, B.; Gorti, S.B.; Clarno, K.; Tonks, M.R.

    2015-01-01

    In this work, the phase-field method and its application to microstructure evolution in reactor fuel and clad are discussed. The examples highlight the capability of the phase-field method to capture evolution processes that are influenced by both thermal and elastic stress fields that are caused by microstructural changes in the solid-state. The challenges that need to be overcome before the technique can become predictive and material-specific are discussed. (authors)

  3. Phase Vocoder

    Directory of Open Access Journals (Sweden)

    J.L. Flanagan

    2013-08-01

    Full Text Available A vocoder technique is described in which speech signals are represented by their short-time phase and amplitude spectra. A complete transmission system utilizing this approach is simulated on a digital computer. The encoding method leads to an economy in transmission bandwidth and to a means for time compression and expansion of speech signals.

  4. Intermetallic phases in the iron-rich region of the Zr-Fe phase diagram

    Energy Technology Data Exchange (ETDEWEB)

    Granovsky, M.S. [Comision Nacional de Energia Atomica, Buenos Aires (Argentina). Dept. de Materiales; Arias, D. [Comision Nacional de Energia Atomica, Buenos Aires (Argentina). Dept. de Materiales

    1996-04-01

    Intermetallic phases in the Fe-rich region of the Zr-Fe system are studied by X-ray diffraction and optical and electron microscopy. The chemical composition of each phase has been quantitatively measured in a electron microprobe. The stable phases found in this region are ZrFe{sub 2}, Zr{sub 6}Fe{sub 23} and ({alpha}Fe). ZrFe{sub 2} is identified as a cubic Laves type phase (C15) and the ZrFe{sub 2}/ZrFe{sub 2}+Zr{sub 6}Fe{sub 23} boundary composition is 73{+-}1 at.% Fe. Zr{sub 6}Fe{sub 23} is a cubic phase of the Th{sub 6}Mn{sub 23} type and its composition is 80.0{+-}1.5 at.% Fe. The eutectic L{r_reversible}Zr{sub 6}Fe{sub 23}+{tau}-Fe transformation temperature and composition are 1325 C and 91{+-}1 at.% Fe, respectively. The solubility of Zr in {tau}-Fe at 1012 C is 500{+-}50 appm and 1000{+-}100 appm close to the eutectic temperature. (orig.).

  5. Intermetallic phases in the iron-rich region of the Zr-Fe phase diagram

    International Nuclear Information System (INIS)

    Granovsky, M.S.; Arias, D.

    1996-01-01

    Intermetallic phases in the Fe-rich region of the Zr-Fe system are studied by X-ray diffraction and optical and electron microscopy. The chemical composition of each phase has been quantitatively measured in a electron microprobe. The stable phases found in this region are ZrFe 2 , Zr 6 Fe 23 and (αFe). ZrFe 2 is identified as a cubic Laves type phase (C15) and the ZrFe 2 /ZrFe 2 +Zr 6 Fe 23 boundary composition is 73±1 at.% Fe. Zr 6 Fe 23 is a cubic phase of the Th 6 Mn 23 type and its composition is 80.0±1.5 at.% Fe. The eutectic L↔Zr 6 Fe 23 +τ-Fe transformation temperature and composition are 1325 C and 91±1 at.% Fe, respectively. The solubility of Zr in τ-Fe at 1012 C is 500±50 appm and 1000±100 appm close to the eutectic temperature. (orig.)

  6. Formation of the second organic phase during uranyl nitrate extraction from aqueous solution by 30% tributylphosphate solution in paraffin

    International Nuclear Information System (INIS)

    Yhrkin, V.G.

    1996-01-01

    For extraction systems aqueous solution of uranyl nitrate-30% solution of tributylphosphate in individual paraffins from C 13 to C 17 the influence of the second organic phase of uranyl nitrate concentration in aqueous and organic phases, the length of hydrocarbon chain of paraffin hydrocarbon and temperature from 25 to 50 deg C on formation conditions has been defected. A special method of achieving the conditions of organic phase stratification from three-phase region, involving definition of equilibrium phases composition by density and refractive index, has been elaborated for more precise definition of organic phase homogeneity region. It has been revealed that without addition of nitric acid to uranyl nitrate solution the organic phase homogeneity limits can be achieved solely on paraffins C 15 , C 16 and C 17 and only under conditions similar to equeous phase saturation in terms of uranyl nitrate. 16 refs., 2 figs

  7. Point Defects in Binary Laves-Phase Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Liaw, P.K.; Liu, C.T.; Pike, L.M.; Zhu, J.H.

    1999-01-11

    Point defects in the binary C15 NbCrQ and NbCoz, and C 14 NbFe2 systems on both sides of stoichiometry were studied by both bulk density and X-ray Iattiee parameter measurements. It was found that the vacancy concentrations in these systems after quenching from 1000"C are essentially zero. The constitutional defects on both sides of stoichiometry for these systems were found to be of the anti-site type in comparison with the model predictions. Thermal vacancies exhibiting a maximum at the stoichiometric composition were obtained in NbCr2 Laves phase alloys after quenching from 1400"C. However, there are essentially no thermal vacancies in NbFe2 alloys after quenching from 1300oC. Anti-site hardening was found on both sides of stoichiometry for all the tie Laves phase systems studied, while the thermal vacancies in NbCr2 alloys quenched from 1400'C were found to soften the Laves phase. The anti-site hardening of the Laves phases is similar to that of the B2 compounds and the thermal vacancy softening is unique to the Laves phase. Neither the anti-site defects nor the thermal vacancies affect the fracture toughness of the Laves phases significantly.

  8. Phase contrast image synthesis

    DEFF Research Database (Denmark)

    Glückstad, J.

    1996-01-01

    A new method is presented for synthesizing arbitrary intensity patterns based on phase contrast imaging. The concept is grounded on an extension of the Zernike phase contrast method into the domain of full range [0; 2 pi] phase modulation. By controlling the average value of the input phase funct...... function and by choosing appropriate phase retardation at the phase contrast filter, a pure phase to intensity imaging is accomplished. The method presented is also directly applicable in dark field image synthesis....

  9. Microstructures and mechanical properties of two-phase alloys based on NbCr{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Chen, K.C.; Kotula, P.G.; Cady, C.M.; Mauro, M.E.; Thoma, D.J.

    1999-07-01

    A two-phase, NbCrTi alloy (bcc + C15 Laves phase) has been developed using several alloy design methodologies. In efforts to understand processing-microstructure-property relationships, different processing routes were employed. The resulting microstructures and mechanical properties are discussed and compared. Plasma arc melted (PAM) samples served to establish baseline, as-cast properties. In addition, a novel processing technique, involving decomposition of a supersaturated and metastable precursor phase during hot isostatic pressing (HIP), was used to produce a refined, equilibrium two-phase microstructure. Quasi-static compression tests as a function of temperature were performed on both alloy types. Different deformation mechanisms were encountered based upon temperature and microstructure.

  10. Phase equilibrium engineering

    CERN Document Server

    Brignole, Esteban Alberto

    2013-01-01

    Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs. Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and

  11. Omega phase in materials

    International Nuclear Information System (INIS)

    Sikka, S.K.; Vohra, Y.K.; Chidambaram, R.

    1982-01-01

    The subject is reviewed under the headings: introduction; occurrence and some systematics of omega phase; crystallography; physical properties; kinetics of formation, synthesis and metastability of omega phase; electronic structure of omega phase; electronic basis for omega phase stability; omega phase formation under combined thermal and pressure treatment in alloys; transformation mechanisms and models for diffuse omega phase; conclusion. The following elements of nuclear interest (or their alloys) are included: Zr, Hf, Nb, V, Mo. (U.K.)

  12. Fourier phasing with phase-uncertain mask

    International Nuclear Information System (INIS)

    Fannjiang, Albert; Liao, Wenjing

    2013-01-01

    Fourier phasing is the problem of retrieving Fourier phase information from Fourier intensity data. The standard Fourier phase retrieval (without a mask) is known to have many solutions which cause the standard phasing algorithms to stagnate and produce wrong or inaccurate solutions. In this paper Fourier phase retrieval is carried out with the introduction of a randomly fabricated mask in measurement and reconstruction. Highly probable uniqueness of solution, up to a global phase, was previously proved with exact knowledge of the mask. Here the uniqueness result is extended to the case where only rough information about the mask’s phases is assumed. The exponential probability bound for uniqueness is given in terms of the uncertainty-to-diversity ratio of the unknown mask. New phasing algorithms alternating between the object update and the mask update are systematically tested and demonstrated to have the capability of recovering both the object and the mask (within the object support) simultaneously, consistent with the uniqueness result. Phasing with a phase-uncertain mask is shown to be robust with respect to the correlation in the mask as well as the Gaussian and Poisson noises. (paper)

  13. CrowdPhase: crowdsourcing the phase problem

    Energy Technology Data Exchange (ETDEWEB)

    Jorda, Julien; Sawaya, Michael R. [Institute for Genomics and Proteomics, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); Yeates, Todd O., E-mail: yeates@mbi.ucla.edu [Institute for Genomics and Proteomics, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); Molecular Biology Institute, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); University of California, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States)

    2014-06-01

    The idea of attacking the phase problem by crowdsourcing is introduced. Using an interactive, multi-player, web-based system, participants work simultaneously to select phase sets that correspond to better electron-density maps in order to solve low-resolution phasing problems. The human mind innately excels at some complex tasks that are difficult to solve using computers alone. For complex problems amenable to parallelization, strategies can be developed to exploit human intelligence in a collective form: such approaches are sometimes referred to as ‘crowdsourcing’. Here, a first attempt at a crowdsourced approach for low-resolution ab initio phasing in macromolecular crystallography is proposed. A collaborative online game named CrowdPhase was designed, which relies on a human-powered genetic algorithm, where players control the selection mechanism during the evolutionary process. The algorithm starts from a population of ‘individuals’, each with a random genetic makeup, in this case a map prepared from a random set of phases, and tries to cause the population to evolve towards individuals with better phases based on Darwinian survival of the fittest. Players apply their pattern-recognition capabilities to evaluate the electron-density maps generated from these sets of phases and to select the fittest individuals. A user-friendly interface, a training stage and a competitive scoring system foster a network of well trained players who can guide the genetic algorithm towards better solutions from generation to generation via gameplay. CrowdPhase was applied to two synthetic low-resolution phasing puzzles and it was shown that players could successfully obtain phase sets in the 30° phase error range and corresponding molecular envelopes showing agreement with the low-resolution models. The successful preliminary studies suggest that with further development the crowdsourcing approach could fill a gap in current crystallographic methods by making it

  14. CrowdPhase: crowdsourcing the phase problem

    International Nuclear Information System (INIS)

    Jorda, Julien; Sawaya, Michael R.; Yeates, Todd O.

    2014-01-01

    The idea of attacking the phase problem by crowdsourcing is introduced. Using an interactive, multi-player, web-based system, participants work simultaneously to select phase sets that correspond to better electron-density maps in order to solve low-resolution phasing problems. The human mind innately excels at some complex tasks that are difficult to solve using computers alone. For complex problems amenable to parallelization, strategies can be developed to exploit human intelligence in a collective form: such approaches are sometimes referred to as ‘crowdsourcing’. Here, a first attempt at a crowdsourced approach for low-resolution ab initio phasing in macromolecular crystallography is proposed. A collaborative online game named CrowdPhase was designed, which relies on a human-powered genetic algorithm, where players control the selection mechanism during the evolutionary process. The algorithm starts from a population of ‘individuals’, each with a random genetic makeup, in this case a map prepared from a random set of phases, and tries to cause the population to evolve towards individuals with better phases based on Darwinian survival of the fittest. Players apply their pattern-recognition capabilities to evaluate the electron-density maps generated from these sets of phases and to select the fittest individuals. A user-friendly interface, a training stage and a competitive scoring system foster a network of well trained players who can guide the genetic algorithm towards better solutions from generation to generation via gameplay. CrowdPhase was applied to two synthetic low-resolution phasing puzzles and it was shown that players could successfully obtain phase sets in the 30° phase error range and corresponding molecular envelopes showing agreement with the low-resolution models. The successful preliminary studies suggest that with further development the crowdsourcing approach could fill a gap in current crystallographic methods by making it

  15. Study of fatigue and fracture behavior of NbCr{sub 2}-based alloys: Phase stability in Nb-Cr-Ni ternary system

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, J.H.; Liaw, P.K. [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Materials Science and Engineering; Liu, C.T. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1997-12-01

    Phase stability in a ternary Nb-Cr-Ni Laves phase system was studied in this paper. Their previous study in NbCr{sub 2}-based transition-metal Laves phases has shown that the average electron concentration factor, e/a, is the dominating factor in controlling the phase stability of NbCr{sub 2}-based Laves phases when the atomic size ratios are kept identical. Since Ni has ten out-shell electrons, the substitution of Ni for Cr in NbCr{sub 2} will increase the average electron concentration of the alloy, thus leading to the change of the crystal structures from C15 to C14. In this paper, a number of pseudo-binary Nb(Cr,Ni){sub 2} alloys were prepared, and the crystal structures of the alloys after a long heat-treatment at 1000 C as a function of the Ni content were determined by the X-ray diffraction technique. The boundaries of the C15/C14 transition were determined and compared to their previous predictions. It was found that the electron concentration and phase stability correlation is obeyed in the Nb-Cr-Ni system. However, the e/a ratio corresponding to the C15/C14 phase transition was found to move to a higher value than the predicted one. The changes in the lattice constant, Vickers hardness and fracture toughness were also determined as a function of the Ni content, which were discussed in light of the phase stability difference of the alloys.

  16. Mixed phase in cubic and hexagonal HoMn{sub 2} {sup 111}Cd PAC and {sup 119}Sn, {sup 57}Fe Moessbauer studies

    Energy Technology Data Exchange (ETDEWEB)

    Cottenier, S.; Meersschaut, J.; Demuynck, S.; Swinnen, B.; Rots, M. [Leuven Univ. (Belgium). Inst. voor Kern- en Stralingsfysika; Krop, K.; Marzec, J.; Zukrowski, J.; Przewoznik, J.; Japa, E. [Dept. of Solid State Physics, Univ. of Mining and Metallurgy, Krakow (Poland)

    1998-01-01

    Hyperfine parameters on {sup 57}Fe, {sup 119}Sn and {sup 111}Cd substituted into the Mn sublattice were measured by Moessbauer and PAC spectroscopies. From these results it is tentatively concluded that C15 and C14 HoMn{sub 2} are mixed-phase compounds. In C14 HoMn{sub 2} there is no (or small) moment on the 2a site. (orig.) 6 refs.

  17. Generalized phase contrast:

    DEFF Research Database (Denmark)

    Glückstad, Jesper; Palima, Darwin

    Generalized Phase Contrast elevates the phase contrast technique not only to improve phase imaging but also to cross over and interface with diverse and seemingly disparate fields of contemporary optics and photonics. This book presents a comprehensive introduction to the Generalized Phase Contrast...

  18. Entropic stabilisation of topologically close-packed phases in binary transition-metal alloys

    Energy Technology Data Exchange (ETDEWEB)

    Hammerschmidt, Thomas; Fries, Suzana G.; Steinbach, Ingo; Drautz, Ralf [ICAMS, Ruhr-Universitaet Bochum, Bochum (Germany); Seiser, Bernhard; Pettifor, David G. [Department of Materials, University of Oxford, Oxford (United Kingdom)

    2010-07-01

    The formation of topologically close-packed (tcp) phases in Ni-based superalloys leads to the degradation of the mechanical properties of the alloys. The precipitation of the tcp phases is attributed to refractory elements that are added in low concentration to improve creep resistance. It is well known that the structural stability of the tcp phases A15, {sigma} and {chi} is driven by the average d-band filling. For a direct comparison to experimental phase diagrams, we carried out extensive density-functional theory (DFT) calculations of the tcp phases A15, C14, C15, C36, {mu}, {sigma}, and {chi} in tcp-forming binary transition-metal (TM) systems. We observe several systems such as W-Re with positive values of the heat of formation for all tcp phases although some of the phases are observed experimentally. By combining our DFT total energies with the CALPHAD methodology, we can demonstrate that configurational entropy can stabilise the tcp phases in these systems.

  19. High temperature phase equilibria and phase diagrams

    CERN Document Server

    Kuo, Chu-Kun; Yan, Dong-Sheng

    2013-01-01

    High temperature phase equilibria studies play an increasingly important role in materials science and engineering. It is especially significant in the research into the properties of the material and the ways in which they can be improved. This is achieved by observing equilibrium and by examining the phase relationships at high temperature. The study of high temperature phase diagrams of nonmetallic systems began in the early 1900s when silica and mineral systems containing silica were focussed upon. Since then technical ceramics emerged and more emphasis has been placed on high temperature

  20. Therapy Provider Phase Information

    Data.gov (United States)

    U.S. Department of Health & Human Services — The Therapy Provider Phase Information dataset is a tool for providers to search by their National Provider Identifier (NPI) number to determine their phase for...

  1. Micropatch Antenna Phase Shifting

    National Research Council Canada - National Science Library

    Thursby, Michael

    2000-01-01

    .... We have been looking at the ability of embedded element to adjust the phase shift seen by the element with the goal of being able to remove the phase shifting devices from the antenna and replace...

  2. Micropatch Antenna Phase Shifting

    National Research Council Canada - National Science Library

    Thursby, Michael

    1999-01-01

    .... We have been looking at the ability of embedded element to adjust the phase shift seen by the element wit the goal of being able to remove the phase shifting devices from the antenna and replace...

  3. Digital quadrature phase detection

    Science.gov (United States)

    Smith, J.A.; Johnson, J.A.

    1992-05-26

    A system for detecting the phase of a frequency or phase modulated signal that includes digital quadrature sampling of the frequency or phase modulated signal at two times that are one quarter of a cycle of a reference signal apart, determination of the arctangent of the ratio of a first sampling of the frequency or phase modulated signal to the second sampling of the frequency or phase modulated signal, and a determination of quadrant in which the phase determination is increased by 2[pi] when the quadrant changes from the first quadrant to the fourth quadrant and decreased by 2[pi] when the quadrant changes from the fourth quadrant to the first quadrant whereby the absolute phase of the frequency or phase modulated signal can be determined using an arbitrary reference convention. 6 figs.

  4. Gas phase ion chemistry

    CERN Document Server

    Bowers, Michael T

    1979-01-01

    Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry. The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase acidity scale. The text also describes the basis of the technique of chemical ionization mass spectrometry; the energetics and mechanisms of unimolecular reactions of positive ions; and the photodissociation

  5. Phased-array radars

    Science.gov (United States)

    Brookner, E.

    1985-02-01

    The operating principles, technology, and applications of phased-array radars are reviewed and illustrated with diagrams and photographs. Consideration is given to the antenna elements, circuitry for time delays, phase shifters, pulse coding and compression, and hybrid radars combining phased arrays with lenses to alter the beam characteristics. The capabilities and typical hardware of phased arrays are shown using the US military systems COBRA DANE and PAVE PAWS as examples.

  6. Computation of Phase Equilibrium and Phase Envelopes

    DEFF Research Database (Denmark)

    Ritschel, Tobias Kasper Skovborg; Jørgensen, John Bagterp

    formulate the involved equations in terms of the fugacity coefficients. We present expressions for the first-order derivatives. Such derivatives are necessary in computationally efficient gradient-based methods for solving the vapor-liquid equilibrium equations and for computing phase envelopes. Finally, we......In this technical report, we describe the computation of phase equilibrium and phase envelopes based on expressions for the fugacity coefficients. We derive those expressions from the residual Gibbs energy. We consider 1) ideal gases and liquids modeled with correlations from the DIPPR database...... and 2) nonideal gases and liquids modeled with cubic equations of state. Next, we derive the equilibrium conditions for an isothermal-isobaric (constant temperature, constant pressure) vapor-liquid equilibrium process (PT flash), and we present a method for the computation of phase envelopes. We...

  7. Omega phase in materials

    International Nuclear Information System (INIS)

    Sikka, S.K.; Vohra, Y.K.; Chidambaram, R.

    1982-01-01

    The subject is covered in sections, entitled: introduction; occurrence and some systematics of omega phase (omega phase in Ti, Zr and Hf under high pressures; omega phase in Group IV transition metal alloys; omega in other systems; omega embryos at high temperatures); crystallography (omega structure; relationship of ω-structure to bcc (β) and hcp (α) structures); physical properties; kinetics of formation, synthesis and metastability of omega phase (kinetics of α-ω transformation under high pressures; kinetics of β-ω transformation; synthesis and metastability studies); electronic structure of omega phase (electronic structure models; band structure calculations; theoretical results and experimental studies); electronic basis for omega phase stability (unified phase diagram; stability of omega phase); omega phase formation under combined thermal and pressure treatment in alloys (Ti-V alloys under pressure - a prototype case study; P-X phase diagrams for alloys; transformation mechanisms and models for diffuse omega phase (is omega structure a charge density distortion of the bcc phase; nature of incommensurate ω-structure and models for diffuse scattering); conclusion. (U.K.)

  8. Eigenstate Phase Transitions

    Science.gov (United States)

    Zhao, Bo

    Phase transitions are one of the most exciting physical phenomena ever discovered. The understanding of phase transitions has long been of interest. Recently eigenstate phase transitions have been discovered and studied; they are drastically different from traditional thermal phase transitions. In eigenstate phase transitions, a sharp change is exhibited in properties of the many-body eigenstates of the Hamiltonian of a quantum system, but not the thermal equilibrium properties of the same system. In this thesis, we study two different types of eigenstate phase transitions. The first is the eigenstate phase transition within the ferromagnetic phase of an infinite-range spin model. By studying the interplay of the eigenstate thermalization hypothesis and Ising symmetry breaking, we find two eigenstate phase transitions within the ferromagnetic phase: In the lowest-temperature phase the magnetization can macroscopically oscillate by quantum tunneling between up and down. The relaxation of the magnetization is always overdamped in the remainder of the ferromagnetic phase, which is further divided into phases where the system thermally activates itself over the barrier between the up and down states, and where it quantum tunnels. The second is the many-body localization phase transition. The eigenstates on one side of the transition obey the eigenstate thermalization hypothesis; the eigenstates on the other side are many-body localized, and thus thermal equilibrium need not be achieved for an initial state even after evolving for an arbitrary long time. We study this many-body localization phase transition in the strong disorder renormalization group framework. After setting up a set of coarse-graining rules for a general one dimensional chain, we get a simple "toy model'' and obtain an almost purely analytical solution to the infinite-randomness critical fixed point renormalization group equation. We also get an estimate of the correlation length critical exponent nu

  9. Single-Phase PLLs

    DEFF Research Database (Denmark)

    Golestan, Saeed; Guerrero, Josep M.; Quintero, Juan Carlos Vasquez

    2017-01-01

    Single-phase phase-locked loops (PLLs) are popular for the synchronization and control of single-phase gridconnected converters. They are also widely used for monitoring and diagnostic purposes in the power and energy areas. In recent years, a large number of single-phase PLLs with different stru......-PLLs). The members of each category are then described and their pros and cons are discussed. This work provides a deep insight into characteristics of different single-phase PLLs and, therefore, can be considered as a reference for researchers and engineers....

  10. Solid phase radioimmunoassays

    International Nuclear Information System (INIS)

    Wide, L.

    1977-01-01

    Solid phase coupled antibodies were introduced to facilitate the separation of bound and free labelled ligand in the competitive inhibition radioimmunoassay. Originally, the solid matrix used was in the form of small particles and since then a number of different matrices have been used such as very fine powder particles, gels, paper and plastic discs, magnetic particles and the inside surface of plastic tubes. The coupling of antibodies may be that of a covalent chemical binding, a strong physical adsorbtion, or an immunological binding to a solid phase coupled antigen. New principles of radioimmunoassay such as the solid phase sandwich techniques and the immunoradiometric assay were developped from the use of solid phase coupled antigens and antibodies. The solid phase sandwich techniques are reagent excess methods with a very wide applicability. Several of the different variants of solid phase techniques are suitable for automation. Advantages and disadvantages of solid phase radioimmunoassays when compared with those using soluble reagents are discussed. (orig.) [de

  11. Generalized Phase Contrast

    CERN Document Server

    Glückstad, Jesper

    2009-01-01

    Generalized Phase Contrast elevates the phase contrast technique not only to improve phase imaging but also to cross over and interface with diverse and seemingly disparate fields of contemporary optics and photonics. This book presents a comprehensive introduction to the Generalized Phase Contrast (GPC) method including an overview of the range of current and potential applications of GPC in wavefront sensing and phase imaging, structured laser illumination and image projection, optical trapping and manipulation, and optical encryption and decryption. The GPC method goes further than the restrictive assumptions of conventional Zernike phase contrast analysis and achieves an expanded range of validity beyond weak phase perturbations. The generalized analysis yields design criteria for tuning experimental parameters to achieve optimal performance in terms of accuracy, fidelity and light efficiency. Optimization can address practical issues, such as finding an optimal spatial filter for the chosen application, ...

  12. Structural electronic and mechanical properties of YM2 (M=Mn, Fe, Co) laves phase compounds: First principle calculations analyzed with datamining approach

    Science.gov (United States)

    Saidi, F.; Sebaa, N.; Mahmoudi, A.; Aourag, H.; Merad, G.; Dergal, M.

    2018-06-01

    We performed first-principle calculations to investigate structural, phase stability, electronic and mechanical properties for the Laves phases YM2 (M = Mn, Fe, Co) with C15, C14 and C36 structures. We used the density functional theory within the framework of both pseudo-potentials and plane wave basis using VASP (Vienna Ab Initio Software Package). The calculated equilibrium structural parameters are in accordance with available theoretical values. Mechanical properties were calculated, discussed, and analyzed with data mining approach in terms of structure stability. The results reveal that YCo2 is harder than YFe2 and YMn2.

  13. Quantum phase transitions

    International Nuclear Information System (INIS)

    Sachdev, S.

    1999-01-01

    Phase transitions are normally associated with changes of temperature but a new type of transition - caused by quantum fluctuations near absolute zero - is possible, and can tell us more about the properties of a wide range of systems in condensed-matter physics. Nature abounds with phase transitions. The boiling and freezing of water are everyday examples of phase transitions, as are more exotic processes such as superconductivity and superfluidity. The universe itself is thought to have passed through several phase transitions as the high-temperature plasma formed by the big bang cooled to form the world as we know it today. Phase transitions are traditionally classified as first or second order. In first-order transitions the two phases co-exist at the transition temperature - e.g. ice and water at 0 deg., or water and steam at 100 deg. In second-order transitions the two phases do not co-exist. In the last decade, attention has focused on phase transitions that are qualitatively different from the examples noted above: these are quantum phase transitions and they occur only at the absolute zero of temperature. The transition takes place at the ''quantum critical'' value of some other parameter such as pressure, composition or magnetic field strength. A quantum phase transition takes place when co-operative ordering of the system disappears, but this loss of order is driven solely by the quantum fluctuations demanded by Heisenberg's uncertainty principle. The physical properties of these quantum fluctuations are quite distinct from those of the thermal fluctuations responsible for traditional, finite-temperature phase transitions. In particular, the quantum system is described by a complex-valued wavefunction, and the dynamics of its phase near the quantum critical point requires novel theories that have no analogue in the traditional framework of phase transitions. In this article the author describes the history of quantum phase transitions. (UK)

  14. Gymnastics in Phase Space

    Energy Technology Data Exchange (ETDEWEB)

    Chao, Alexander Wu; /SLAC

    2012-03-01

    As accelerator technology advances, the requirements on accelerator beam quality become increasingly demanding. Facing these new demands, the topic of phase space gymnastics is becoming a new focus of accelerator physics R&D. In a phase space gymnastics, the beam's phase space distribution is manipulated and precision tailored to meet the required beam qualities. On the other hand, all realization of such gymnastics will have to obey accelerator physics principles as well as technological limitations. Recent examples of phase space gymnastics include Emittance exchanges, Phase space exchanges, Emittance partitioning, Seeded FELs and Microbunched beams. The emittance related topics of this list are reviewed in this report. The accelerator physics basis, the optics design principles that provide these phase space manipulations, and the possible applications of these gymnastics, are discussed. This fascinating new field promises to be a powerful tool of the future.

  15. Diffusionless phase transformations

    International Nuclear Information System (INIS)

    Vejman, K.M.

    1987-01-01

    Diffusionless phase transformations in metals and alloys in the process of which atomic displacements occur at the distances lower than interatomic ones and relative correspondence of neighbour atoms is preserved, are considered. Special attention is paid to the mechanism of martensitic transformations. Phenomenologic crystallographical theory of martensitic transformations are presented. Two types of martensitic transformations different from the energy viewpoint are pointed out - thermoelastic and non-thermoelastic ones - which are characterized by transformation hysteresis and ways of martensite - initial phase reverse transformation realization. Mechanical effect in the martensitic transformations have been analyzed. The problem of diffusionless formation of ω-phases and the effect of impurities and vacancies on the process are briefly discussed. The role of charge density waves in phase transformations of the second type (transition of initial phase into noncommensurate one) and of the first type (transition of noncommensurate phase into commensurate one) is considered

  16. Phase Contrast Imaging

    DEFF Research Database (Denmark)

    1996-01-01

    The invention relates to a method and a system for synthesizing a prescribed intensity pattern based on phase contrast imaging that is not based on the assumption of prior art methods that the pahase shift phi is less than 1 radian. An improved method based on a simple imaging operation...... phasors attain predetermined values for predetermined spatial frequencies, and the phasor value of the specific resolution element of the spatial phase mask corresponds to a distinct intensity level of the image of the resolution element in the intensity pattern, and a spatial phase filter for phase...... shifting of a part of the electromagntic radiation, in combination with an imaging system for generation of the intensity pattern by interference in the image plane of the imaging system between the part of the electromagnetic raidation that has been phase shifted by the phase filter and the remaining part...

  17. Phase behavior in diffraction

    International Nuclear Information System (INIS)

    Checon, A.

    1983-01-01

    Theoretical formulation of a straight edge diffraction shows a phase difference of π/2 between the incoming and diffracted waves. Experiments using two straight edges do not confirm the π/2 difference but suggest that the incoming wave is in phase with the wave diffracted into the shadowed region of the edge and out of phase by a factor of π with the wave diffracted into the illuminated region. (Author) [pt

  18. Cosmological phase transitions

    International Nuclear Information System (INIS)

    Kolb, E.W.

    1993-10-01

    If modern ideas about the role of spontaneous symmetry breaking in fundamental physics are correct, then the Universe should have undergone a series of phase transitions early in its history. The study of cosmological phase transitions has become an important aspect of early-Universe cosmology. In this lecture I review some very recent work on three aspects of phase transitions: the electroweak transition, texture, and axions

  19. Phase Holograms In PMMA

    Science.gov (United States)

    Maker, Paul D.; Muller, Richard E.

    1994-01-01

    Complex, computer-generated phase holograms written in thin films of poly(methyl methacrylate) (PMMA) by process of electron-beam exposure followed by chemical development. Spatial variations of phase delay in holograms quasi-continuous, as distinquished from stepwise as in binary phase holograms made by integrated-circuit fabrication. Holograms more precise than binary holograms. Greater continuity and precision results in decreased scattering loss and increased imaging efficiency.

  20. Thermodynamics of phase transitions

    International Nuclear Information System (INIS)

    Cofta, H.

    1972-01-01

    The phenomenology of the phase transitions has been considered. The definitions of thermodynamic functions and parameters, as well as those of the phase transitions, are given and some of the relations between those quantities are discussed. The phase transitions classification proposed by Ehrenfest has been described. The most important features of phase transitions are discussed using the selected physical examples including the critical behaviour of ferromagnetic materials at the Curie temperature and antiferromagnetic materials at the Neel temperature. Some aspects of the Ehrenfest's equations, that have been derived, for the interfacial lines and surfaces are considered as well as the role the notion of interfaces. (S.B.)

  1. Retroreflective Phase Retardation Prisms.

    Science.gov (United States)

    1981-06-01

    resonant cavity of a 1.064 Mm laser. This report shows that it is possible to coat the reflecting surfaces of a porro prism so that incident plane...with controlled phase retardation can be made by coating each reflecting surface of a porro prism with a single dielectric film. The amount of phase...of angle of incidence (n, < n2) S. Phase change on reflection as a function of angle of incidence (n" n ) [RL-0202-’R 6. Porro prism 7. Phase change

  2. Dual phase evolution

    CERN Document Server

    Green, David G; Abbass, Hussein A

    2014-01-01

    This book explains how dual phase evolution operates in all these settings and provides a detailed treatment of the subject. The authors discuss the theoretical foundations for the theory, how it relates to other phase transition phenomena and its advantages in evolutionary computation and complex adaptive systems. The book provides methods and techniques to use this concept for problem solving. Dual phase evolution concerns systems that evolve via repeated phase shifts in the connectivity of their elements. It occurs in vast range of settings, including natural systems (species evolution, landscape ecology, geomorphology), socio-economic systems (social networks) and in artificial systems (annealing, evolutionary computing).

  3. Modeling of liquid phases

    CERN Document Server

    Soustelle, Michel

    2015-01-01

    This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been given to the rigor of mathematical developments. This second volume in the set is devoted to the study of liquid phases.

  4. Photovoltaic Wire, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — This Small Business Innovation Research Phase I project will investigate a new architecture for photovoltaic devices based on nanotechnology: photovoltaic wire. The...

  5. Phases of Holographic QCD

    International Nuclear Information System (INIS)

    Lippert, Matthew

    2009-01-01

    We investigated the Sakai-Sugimoto model of large N QCD at nonzero temperature and baryon chemical potential and in the presence of background electric and magnetic fields. We studied the holographic representation of baryons and the deconfinement, chiral-symmetry breaking, and nuclear matter phase transitions. In a background electric field, chiral-symmetry breaking corresponds to an insulator-conductor transition. A magnetic field both catalyzes chiral-symmetry breaking and generates, in the confined phase, a pseudo-scalar gradient or, in the deconfined phase, an axial current. The resulting phase diagram is in qualitative agreement with studies of hot, dense QCD.

  6. Phase Contrast Imaging

    International Nuclear Information System (INIS)

    Menk, Ralf Hendrik

    2008-01-01

    All standard (medical) x-ray imaging technologies, rely primarily on the amplitude properties of the incident radiation, and do not depend on its phase. This is unchanged since the discovery by Roentgen that the intensity of an x-ray beam, as measured by the exposure on a film, was related to the relative transmission properties of an object. However, recently various imaging techniques have emerged which depend on the phase of the x-rays as well as the amplitude. Phase becomes important when the beam is coherent and the imaging system is sensitive to interference phenomena. Significant new advances have been made in coherent optic theory and techniques, which now promise phase information in medical imaging. The development of perfect crystal optics and the increasing availability of synchrotron radiation facilities have contributed to a significant increase in the application of phase based imaging in materials and life sciences. Unique source characteristics such as high intensity, monochromaticity, coherence and high collimating provide an ideal source for advanced imaging. Phase contrast imaging has been applied in both projection and computed tomography modes, and recent applications have been made in the field of medical imaging. Due to the underlying principle of X-ray detection conventional image receptors register only intensities of wave fields and not their phases. During the last decade basically five different methods were developed that translate the phase information into intensity variations. These methods are based on measuring the phase shift φ directly (using interference phenomena), the gradient ∇ φ , or the Laplacian ∇ 2 φ. All three methods can be applied to polychromatic X-ray sources keeping in mind that the native source is synchrotron radiation, featuring monochromatic and reasonable coherent X-ray beams. Due to the vast difference in the coefficients that are driven absorption and phase effects (factor 1,000-10,000 in the energy

  7. Sampler bias -- Phase 1

    International Nuclear Information System (INIS)

    Blanchard, R.J.

    1995-01-01

    This documents Phase 1 determinations on sampler induced bias for four sampler types used in tank characterization. Each sampler, grab sampler or bottle-on-a-string, auger sampler, sludge sampler and universal sampler, is briefly discussed and their physical limits noted. Phase 2 of this document will define additional testing and analysis to further define Sampler Bias

  8. Lunar Phases Planisphere

    Science.gov (United States)

    Shawl, Stephen J.

    2010-01-01

    This paper describes a lunar phases planisphere with which a user can answer questions about the rising and setting times of the Moon as well as questions about where the Moon will be at a given phase and time. The article contains figures that can be photocopied to make the planisphere. (Contains 2 figures.)

  9. Optical phase conjugation

    CERN Document Server

    Fisher, Robert A

    1983-01-01

    This book appears at a time of intense activity in optical phase conjugation. We chose not to await the maturation of the field, but instead to provide this material in time to be useful in its development. We have tried very hard to elucidate and interrelate the various nonlinear phenomena which can be used for optical phase conjugation.

  10. UPVG phase 2 report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    The Utility PhotoVoltaic Group (UPVG), supported by member dues and a grant from the US Department of Energy, has as its mission the acceleration of the use of cost-effective small-scale and emerging large-scale applications of photovoltaics for the benefit of electric utilities and their customers. Formed in October, 1992, with the support of the American Public Power Association, Edison Electric Institute, and the National Rural Electric Cooperative Association, the UPVG currently has 90 members from all sectors of the electric utility industry. The UPVG`s efforts as conceived were divided into four phases: Phase 0--program plan; Phase 1--organization and strategy development; Phase 2--creating market assurance; and Phase 3--higher volume purchases. The Phase 0 effort developed the program plan and was completed early in 1993. The Phase 1 goal was to develop the necessary background information and analysis to lead to a decision as to which strategies could be undertaken by utilities to promote greater understanding of PV markets and achieve increased volumes of PV purchases. This report provides the details of the UPVG`s Phase 2 efforts to initiate TEAM-UP, its multiyear, 50-MW hardware initiative.

  11. Simulation of phase structures

    International Nuclear Information System (INIS)

    Lawson, J.

    1995-01-01

    This memo outlines a procedure developed by the author to extract information from phase measurements and produce a simulated phase structure for use in modeling optical systems, including characteristic optics for the Beamlet and NIF laser systems. The report includes an IDL program listing

  12. UPVG phase 2 report

    International Nuclear Information System (INIS)

    1995-08-01

    The Utility PhotoVoltaic Group (UPVG), supported by member dues and a grant from the US Department of Energy, has as its mission the acceleration of the use of cost-effective small-scale and emerging large-scale applications of photovoltaics for the benefit of electric utilities and their customers. Formed in October, 1992, with the support of the American Public Power Association, Edison Electric Institute, and the National Rural Electric Cooperative Association, the UPVG currently has 90 members from all sectors of the electric utility industry. The UPVG's efforts as conceived were divided into four phases: Phase 0--program plan; Phase 1--organization and strategy development; Phase 2--creating market assurance; and Phase 3--higher volume purchases. The Phase 0 effort developed the program plan and was completed early in 1993. The Phase 1 goal was to develop the necessary background information and analysis to lead to a decision as to which strategies could be undertaken by utilities to promote greater understanding of PV markets and achieve increased volumes of PV purchases. This report provides the details of the UPVG's Phase 2 efforts to initiate TEAM-UP, its multiyear, 50-MW hardware initiative

  13. Smooth Phase Interpolated Keying

    Science.gov (United States)

    Borah, Deva K.

    2007-01-01

    Smooth phase interpolated keying (SPIK) is an improved method of computing smooth phase-modulation waveforms for radio communication systems that convey digital information. SPIK is applicable to a variety of phase-shift-keying (PSK) modulation schemes, including quaternary PSK (QPSK), octonary PSK (8PSK), and 16PSK. In comparison with a related prior method, SPIK offers advantages of better performance and less complexity of implementation. In a PSK scheme, the underlying information waveform that one seeks to convey consists of discrete rectangular steps, but the spectral width of such a waveform is excessive for practical radio communication. Therefore, the problem is to smooth the step phase waveform in such a manner as to maintain power and bandwidth efficiency without incurring an unacceptably large error rate and without introducing undesired variations in the amplitude of the affected radio signal. Although the ideal constellation of PSK phasor points does not cause amplitude variations, filtering of the modulation waveform (in which, typically, a rectangular pulse is converted to a square-root raised cosine pulse) causes amplitude fluctuations. If a power-efficient nonlinear amplifier is used in the radio communication system, the fluctuating-amplitude signal can undergo significant spectral regrowth, thus compromising the bandwidth efficiency of the system. In the related prior method, one seeks to solve the problem in a procedure that comprises two major steps: phase-value generation and phase interpolation. SPIK follows the two-step approach of the related prior method, but the details of the steps are different. In the phase-value-generation step, the phase values of symbols in the PSK constellation are determined by a phase function that is said to be maximally smooth and that is chosen to minimize the spectral spread of the modulated signal. In this step, the constellation is divided into two groups by assigning, to information symbols, phase values

  14. A phased translation function

    International Nuclear Information System (INIS)

    Read, R.J.; Schierbeek, A.J.

    1988-01-01

    A phased translation function, which takes advantage of prior phase information to determine the position of an oriented mulecular replacement model, is examined. The function is the coefficient of correlation between the electron density computed with the prior phases and the electron density of the translated model, evaluated in reciprocal space as a Fourier transform. The correlation coefficient used in this work is closely related to an overlap function devised by Colman, Fehlhammer and Bartels. Tests with two protein structures, one of which was solved with the help of the phased translation function, show that little phase information is required to resolve the translation problem, and that the function is relatively insensitive to misorientation of the model. (orig.)

  15. Digital Receiver Phase Meter

    Science.gov (United States)

    Marcin, Martin; Abramovici, Alexander

    2008-01-01

    The software of a commercially available digital radio receiver has been modified to make the receiver function as a two-channel low-noise phase meter. This phase meter is a prototype in the continuing development of a phase meter for a system in which radiofrequency (RF) signals in the two channels would be outputs of a spaceborne heterodyne laser interferometer for detecting gravitational waves. The frequencies of the signals could include a common Doppler-shift component of as much as 15 MHz. The phase meter is required to measure the relative phases of the signals in the two channels at a sampling rate of 10 Hz at a root power spectral density measurements in laser metrology of moving bodies. To illustrate part of the principle of operation of the phase meter, the figure includes a simplified block diagram of a basic singlechannel digital receiver. The input RF signal is first fed to the input terminal of an analog-to-digital converter (ADC). To prevent aliasing errors in the ADC, the sampling rate must be at least twice the input signal frequency. The sampling rate of the ADC is governed by a sampling clock, which also drives a digital local oscillator (DLO), which is a direct digital frequency synthesizer. The DLO produces samples of sine and cosine signals at a programmed tuning frequency. The sine and cosine samples are mixed with (that is, multiplied by) the samples from the ADC, then low-pass filtered to obtain in-phase (I) and quadrature (Q) signal components. A digital signal processor (DSP) computes the ratio between the Q and I components, computes the phase of the RF signal (relative to that of the DLO signal) as the arctangent of this ratio, and then averages successive such phase values over a time interval specified by the user.

  16. Phase transformation and diffusion

    CERN Document Server

    Kale, G B; Dey, G K

    2008-01-01

    Given that the basic purpose of all research in materials science and technology is to tailor the properties of materials to suit specific applications, phase transformations are the natural key to the fine-tuning of the structural, mechanical and corrosion properties. A basic understanding of the kinetics and mechanisms of phase transformation is therefore of vital importance. Apart from a few cases involving crystallographic martensitic transformations, all phase transformations are mediated by diffusion. Thus, proper control and understanding of the process of diffusion during nucleation, g

  17. Gas Phase Nanoparticle Synthesis

    Science.gov (United States)

    Granqvist, Claes; Kish, Laszlo; Marlow, William

    This book deals with gas-phase nanoparticle synthesis and is intended for researchers and research students in nanomaterials science and engineering, condensed matter physics and chemistry, and aerosol science. Gas-phase nanoparticle synthesis is instrumental to nanotechnology - a field in current focus that raises hopes for environmentally benign, resource-lean manufacturing. Nanoparticles can be produced by many physical, chemical, and even biological routes. Gas-phase synthesis is particularly interesting since one can achieve accurate manufacturing control and hence industrial viability.

  18. Martensitic phase transitions

    International Nuclear Information System (INIS)

    Petry, W.; Neuhaus, J.

    1996-01-01

    Many elements transform from a high temperature bcc phase to a more dense packed temperature phase. The great majority of these transitions are of 1st order, displacive and reconstructive. The lattice potentials which govern these martensitic transitions can be probed by inelastic neutron scattering, thereby answering fundamental questions like : Will the transition be announced by dynamical or static fluctuations? What are the trajectories for the displacements needed for the transformation? Does the vibrational entropy stabilize the high temperature phase? Are the unusual transport properties in these materials related to their ability to transform? (author) 17 figs., 1 tab., 46 refs

  19. Martensitic phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Petry, W; Neuhaus, J [Techn. Universitaet Muenchen, Physik Department E13, Munich (Germany)

    1996-11-01

    Many elements transform from a high temperature bcc phase to a more dense packed temperature phase. The great majority of these transitions are of 1st order, displacive and reconstructive. The lattice potentials which govern these martensitic transitions can be probed by inelastic neutron scattering, thereby answering fundamental questions like : Will the transition be announced by dynamical or static fluctuations? What are the trajectories for the displacements needed for the transformation? Does the vibrational entropy stabilize the high temperature phase? Are the unusual transport properties in these materials related to their ability to transform? (author) 17 figs., 1 tab., 46 refs.

  20. Preparation and thermal properties of Glauber’s salt-based phase-change materials for Qinghai-Tibet Plateau solar greenhouses

    Science.gov (United States)

    Jiang, Zipeng; Tie, Shengnian

    2017-07-01

    This paper reports the preparation and characterization of eutectic Glauber’s salt-based composite, phase-change materials (G-PCMs). PCMs were prepared using industrial-grade sodium sulfate decahydrate (Na2SO4 ṡ 10H2O) as the basic material. Other salts were added to obtain the eutectic Glauber’s salt-based PCMs with phase-change temperatures of 25∘C, 15∘C and 10∘C. The modification of the G-PCMs was designed using the same experimental method to select the efficient nucleating, thickening and thermal conductive agents. The results show that borax can be an effective nucleating agent, sodium carboxymethyl cellulose is an excellent thickener and carbon powder is a good thermal conductive agent. The phase-change temperature, latent heat and thermal conductivity of the three different PCMs are 23.9∘C, 15.4∘C and 9.5∘C; 179.6, 129 and 116.2 J/g; and 1.02, 1.10 and 1.23 W/(m K), respectively. These PCMs possess suitable phase-change temperature, high latent heat and good thermal conductivity, and can be used in Qinghai-Tibet Plateau agricultural solar greenhouses.

  1. Now entering phase two...

    CERN Multimedia

    Katarina Anthony

    2012-01-01

    Building on the success of their feasibility phase, the CLIC test facility, CTF3, has just launched into a five-year project development phase. This will involve detailed performance optimisation studies, marking the project’s transition from pure research and development to prototyping and construction.   CLIC accelerator modules under construction at CERN. “With the feasibility phase now complete, we have established that CLIC can be built,” says Roberto Corsini, CLIC Collaboration spokesperson. “Now we want to be sure that it can provide the luminosity and energy performance needed. We will be looking at the engineering, performance and cost of a real CLIC machine also seeing if we can reduce it.” CTF3’s second phase will focus on selected performance-related research areas for further investigation. The largest of these involves the construction and testing of several authentic CLIC accelerator modules that are currently being ...

  2. Phase transitions modern applications

    CERN Document Server

    Gitterman, Moshe

    2014-01-01

    This book provides a comprehensive review of the theory of phase transitions and its modern applications, based on the five pillars of the modern theory of phase transitions i.e. the Ising model, mean field, scaling, renormalization group and universality. This expanded second edition includes, along with a description of vortices and high temperature superconductivity, a discussion of phase transitions in chemical reaction and moving systems. The book covers a close connection between phase transitions and small world phenomena as well as scale-free systems such as the stock market and the Internet. Readership: Scientists working in different fields of physics, chemistry, biology and economics as well as teaching material for undergraduate and graduate courses.

  3. Theory of alloy phases

    International Nuclear Information System (INIS)

    Watson, R.E.; Ehrenreich, H.; Bennett, L.H.

    1977-01-01

    Various non-thermodynamic approaches to understanding and predicting phase diagrams are explored from the viewpoint of solid-state physics. The review is intended to indicate the scope of activity and some of the progress which has been made

  4. Phased array antenna control

    Science.gov (United States)

    Doland, G. D. (Inventor)

    1978-01-01

    Several new and useful improvements in steering and control of phased array antennas having a small number of elements, typically on the order of 5 to 17 elements are provided. Among the improvements are increasing the number of beam steering positions, reducing the possibility of phase transients in signals received or transmitted with the antennas, and increasing control and testing capacity with respect to the antennas.

  5. Two phase sampling

    CERN Document Server

    Ahmad, Zahoor; Hanif, Muhammad

    2013-01-01

    The development of estimators of population parameters based on two-phase sampling schemes has seen a dramatic increase in the past decade. Various authors have developed estimators of population using either one or two auxiliary variables. The present volume is a comprehensive collection of estimators available in single and two phase sampling. The book covers estimators which utilize information on single, two and multiple auxiliary variables of both quantitative and qualitative nature. Th...

  6. Phase Control in Nonlinear Systems

    Science.gov (United States)

    Zambrano, Samuel; Seoane, Jesús M.; Mariño, Inés P.; Sanjuán, Miguel A. F.; Meucci, Riccardo

    The following sections are included: * Introduction * Phase Control of Chaos * Description of the model * Numerical exploration of phase control of chaos * Experimental evidence of phase control of chaos * Phase Control of Intermittency in Dynamical Systems * Crisis-induced intermittency and its control * Experimental setup and implementation of the phase control scheme * Phase control of the laser in the pre-crisis regime * Phase control of the intermittency after the crisis * Phase control of the intermittency in the quadratic map * Phase Control of Escapes in Open Dynamical Systems * Control of open dynamical systems * Model description * Numerical simulations and heuristic arguments * Experimental implementation in an electronic circuit * Conclusions and Discussions * Acknowledgments * References

  7. Cosmological phase transitions

    International Nuclear Information System (INIS)

    Kolb, E.W.

    1987-01-01

    If the universe stated from conditions of high temperature and density, there should have been a series of phase transitions associated with spontaneous symmetry breaking. The cosmological phase transitions could have observable consequences in the present Universe. Some of the consequences including the formation of topological defects and cosmological inflation are reviewed here. One of the most important tools in building particle physics models is the use of spontaneous symmetry breaking (SSB). The proposal that there are underlying symmetries of nature that are not manifest in the vacuum is a crucial link in the unification of forces. Of particular interest for cosmology is the expectation that are the high temperatures of the big bang symmetries broken today will be restored, and that there are phase transitions to the broken state. The possibility that topological defects will be produced in the transition is the subject of this section. The possibility that the Universe will undergo inflation in a phase transition will be the subject of the next section. Before discussing the creation of topological defects in the phase transition, some general aspects of high-temperature restoration of symmetry and the development of the phase transition will be reviewed. 29 references, 1 figure, 1 table

  8. Electron microscope phase enhancement

    Science.gov (United States)

    Jin, Jian; Glaeser, Robert M.

    2010-06-15

    A microfabricated electron phase shift element is used for modifying the phase characteristics of an electron beam passing though its center aperture, while not affecting the more divergent portion of an incident beam to selectively provide a ninety-degree phase shift to the unscattered beam in the back focal plan of the objective lens, in order to realize Zernike-type, in-focus phase contrast in an electron microscope. One application of the element is to increase the contrast of an electron microscope for viewing weakly scattering samples while in focus. Typical weakly scattering samples include biological samples such as macromolecules, or perhaps cells. Preliminary experimental images demonstrate that these devices do apply a ninety degree phase shift as expected. Electrostatic calculations have been used to determine that fringing fields in the region of the scattered electron beams will cause a negligible phase shift as long as the ratio of electrode length to the transverse feature-size aperture is about 5:1. Calculations are underway to determine the feasibility of aspect smaller aspect ratios of about 3:1 and about 2:1.

  9. Electron Holography: phases matter.

    Science.gov (United States)

    Lichte, Hannes

    2013-06-01

    Essentially, all optics is wave optics, be it with light, X-rays, neutrons or electrons. The information transfer from the object to the image can only be understood in terms of waves given by amplitude and phase. However, phases are difficult to measure: for slowly oscillating waves such as sound or low-frequency electromagnetic waves, phases can be measured directly; for high frequencies this has to be done by heterodyne detection, i.e. superposition with a reference and averaging over time. In optics, this is called interferometry. Because interference is mostly very difficult to achieve, phases have often been considered 'hidden variables' seemingly pulling the strings from backstage, only visible by their action on the image intensity. This was almost the case in conventional Electron Microscopy with the phase differences introduced by an object. However, in the face of the urgent questions from solid state physics and materials science, these phases have to be determined precisely, because they encode the most dominant object properties, such as charge distributions and electromagnetic fields. After more than six decades of very patient advancement, electron interferometry and holography offer unprecedented analytical facilities down to an atomic scale. Akira Tonomura has prominently contributed to the present state.

  10. Vapor Compressor Driven Hybrid Two-Phase Loop, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — This Small Business Innovation Research Phase I project will demonstrate a vapor compressor driven hybrid two-phase loop technology. The hybrid two-phase loop...

  11. Elasticity of phase-Pi (Al3Si2O7(OH)3) - A hydrous aluminosilicate phase

    Science.gov (United States)

    Peng, Ye; Mookherjee, Mainak; Hermann, Andreas; Bajgain, Suraj; Liu, Songlin; Wunder, Bernd

    2017-08-01

    Phase-Pi (Al3Si2O7(OH)3) is an aluminosilicate hydrous mineral and is likely to be stable in hydrated sedimentary layers of subducting slabs. Phase-Pi is likely to be stable between the depths of 60 and 200 km and is likely to transport water into the Earth's interior. Here, we use first principles simulations based on density functional theory to explore the crystal structure at high-pressure, equation of state, and full elastic stiffness tensor as a function of pressure. We find that the pressure volume results could be described by a finite strain fit with V0 , K0 , and K0‧ being 310.3 Å3, 133 GPa, and 3.6 respectively. At zero pressure, the full elastic stiffness tensor shows significant anisotropy with the diagonal principal components C11 , C22 , and C33 being 235, 292, 266 GPa respectively, the diagonal shear C44 , C55 , and C66 being 86, 92, and 87 GPa respectively, and the off-diagonal stiffness C12 , C13 , C14 ,C15 , C16 , C23 , C24 , C25 , C26 , C34 , C35 , C36 , C45 , C46 , and C56 being 73, 78, 6, -30, 15, 61, 17, 2, 1, -13, -15, 6, 3, 1, and 3 GPa respectively. The zero pressure, shear modulus, G0 and its pressure derivative, G0 ‧ are 90 GPa and 1.9 respectively. Upon compression, hydrogen bonding in phase-Pi shows distinct behavior, with some hydrogen bonds weakening and others strengthening. The latter eventually undergo symmetrization, at pressure greater (>40 GPa) than the thermodynamic stability of phase-Pi. Full elastic constant tensors indicate that phase-Pi is very anisotropic with AVP ∼22.4% and AVS ∼23.7% at 0 GPa. Our results also indicate that the bulk sound velocity of phase-Pi is slower than that of the high-pressure hydrous aluminosilicate phase, topaz-OH.

  12. Aerospace Systems Monitor, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — Proposal Title: Aerospace Systems Monitor PHASE 1 Technical Abstract: This Phase II STTR project will continue development and commercialization of the Aerospace...

  13. Fimbrial phase variation

    DEFF Research Database (Denmark)

    Khandige, Surabhi; Møller-Jensen, Jakob

    2016-01-01

    Surface fimbriae of pathogenic Escherichia coli facilitate sensing, adhesion and even invasion of host epithelial cells. While it is known that the pathogen has the potential to express a plethora of fimbrial variants susceptible to rapid phase ON/OFF variation, it is an open question if the fimb......Surface fimbriae of pathogenic Escherichia coli facilitate sensing, adhesion and even invasion of host epithelial cells. While it is known that the pathogen has the potential to express a plethora of fimbrial variants susceptible to rapid phase ON/OFF variation, it is an open question...... if the fimbrial diversity seen at the population level is the product of random stochasticity or a concerted effort based on active communication. Here we discuss the possibility of a mechanism alternative to a stochastic fimbrial phase variation model affecting the dynamics of a heterogeneous population....

  14. Phase coexistence in nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Gulminelli, F

    2003-05-01

    In this work the general theory of first order phase transitions in finite systems is discussed, with a special emphasis to the conceptual problems linked to a thermodynamic description for small, short-lived systems de-exciting in the vacuum as nuclear samples coming from heavy ion collisions. After a short review of the general theory of phase transitions in the framework of information theory; we will present the different possible extensions to the field of finite systems. The concept of negative heat capacity, developed in the early seventies in the context of self-gravitating systems, will be reinterpreted in the general framework of convexity anomalies of thermo-statistical potentials. The connection with the distribution of the order parameter will lead us to a definition of first order phase transitions in finite systems based on topology anomalies of the event distribution in the space of observations. A careful study of the thermodynamic limit will provide a bridge with the standard theory of phase transitions and show that in a wide class of physical situations the different statistical ensembles are irreducibly inequivalent. In the second part of the paper we will apply the theoretical ideas developed in the first part to the possible observation of a liquid-to-gas-like phase transition in heavy ion collisions. The applicability of equilibrium concepts in a dynamical collisional process without boundary conditions will first be critically discussed. The observation of abnormally large partial energy fluctuations in carefully selected samples of collisions detected with the MULTICS-Miniball array will then be reported as a strong evidence of a first order phase transition with negative heat capacity in the nuclear equation of state. (author)

  15. Electroweak phase transitions

    International Nuclear Information System (INIS)

    Anderson, G.W.

    1991-01-01

    An analytic treatment of the one Higgs doublet, electroweak phase transition is given. The phase transition is first order, occurs by the nucleation of thin walled bubbles and completes at a temperature where the order parameter, left-angle φ right-angle T is significantly smaller than it is when the origin becomes absolutely unstable. The rate of anomalous baryon number violation is an exponentially function of left-angle φ right-angle T . In very minimal extensions of the standard model it is quite easy to increase left-angle φ right-angle T so that anomalous baryon number violation is suppressed after completion of the phase transition. Hence baryogenesis at the electroweak phase transition is tenable in minimal of the standard model. In some cases additional phase transitions are possible. For a light Higgs boson, when the top quark mass is sufficiently large, the state where the Higgs field has a vacuum expectation value left-angle φ right-angle = 246 GeV is not the true minimum of the Higgs potential. When this is the case, and when the top quark mass exceeds some critical value, thermal fluctuations in the early universe would have rendered the state left-angle φ right-angle = 246 GeV unstable. The requirement that the state left-angle φ right-angle = 246 GeV is sufficiently long lived constrains the masses of the Higgs boson and the top quark. Finally, we consider whether local phase transitions can be induced by heavy particles which act as seeds for deformations in the scalar field

  16. Compressive Phase Contrast Tomography

    International Nuclear Information System (INIS)

    Maia, Filipe; MacDowell, Alastair; Marchesini, Stefano; Padmore, Howard A.; Parkinson, Dula Y.; Pien, Jack; Schirotzek, Andre; Yang, Chao

    2010-01-01

    When x-rays penetrate soft matter, their phase changes more rapidly than their amplitude. Interference effects visible with high brightness sources creates higher contrast, edge enhanced images. When the object is piecewise smooth (made of big blocks of a few components), such higher contrast datasets have a sparse solution. We apply basis pursuit solvers to improve SNR, remove ring artifacts, reduce the number of views and radiation dose from phase contrast datasets collected at the Hard X-Ray Micro Tomography Beamline at the Advanced Light Source. We report a GPU code for the most computationally intensive task, the gridding and inverse gridding algorithm (non uniform sampled Fourier transform).

  17. Gas phase ion chemistry

    CERN Document Server

    Bowers, Michael T

    1979-01-01

    Gas Phase Ion Chemistry, Volume 1 covers papers on the advances of gas phase ion chemistry. The book discusses the advances in flow tubes and the measurement of ion-molecule rate coefficients and product distributions; the ion chemistry of the earth's atmosphere; and the classical ion-molecule collision theory. The text also describes statistical methods in reaction dynamics; the state selection by photoion-photoelectron coincidence; and the effects of temperature and pressure in the kinetics of ion-molecule reactions. The energy distribution in the unimolecular decomposition of ions, as well

  18. Solid phase transformations

    CERN Document Server

    Čermák, J

    2008-01-01

    This special-topic book, devoted to ""Solid Phase Transformations"" , covers a broad range of phenomena which are of importance in a number of technological processes. Most commercial alloys undergo thermal treatment after casting, with the aim of imparting desired compositions and/or optimal morphologies to the component phases. In spite of the fact that the topic has lain at the center of physical metallurgy for a long time, there are numerous aspects which are wide open to potential investigative breakthroughs. Materials with new structures also stimulate research in the field, as well as n

  19. Electronic phase transitions

    CERN Document Server

    Kopaev, YuV

    1992-01-01

    Electronic Phase Transitions deals with topics, which are presently at the forefront of scientific research in modern solid-state theory. Anderson localization, which has fundamental implications in many areas of solid-state physics as well as spin glasses, with its influence on quite different research activities such as neural networks, are two examples that are reviewed in this book. The ab initio statistical mechanics of structural phase transitions is another prime example, where the interplay and connection of two unrelated disciplines of solid-state theory - first principle ele

  20. Detecting phase synchronization between coupled non-phase-coherent oscillators

    International Nuclear Information System (INIS)

    Follmann, Rosangela; Macau, Elbert E.N.; Rosa, Epaminondas

    2009-01-01

    We compare two methods for detecting phase synchronization in coupled non-phase-coherent oscillators. One method is based on the locking of self-sustained oscillators with an irregular signal. The other uses trajectory recurrences in phase space. We identify the pros and cons of both methods and propose guidelines to detect phase synchronization in data series.

  1. Stochastic modelling of two-phase flows including phase change

    International Nuclear Information System (INIS)

    Hurisse, O.; Minier, J.P.

    2011-01-01

    Stochastic modelling has already been developed and applied for single-phase flows and incompressible two-phase flows. In this article, we propose an extension of this modelling approach to two-phase flows including phase change (e.g. for steam-water flows). Two aspects are emphasised: a stochastic model accounting for phase transition and a modelling constraint which arises from volume conservation. To illustrate the whole approach, some remarks are eventually proposed for two-fluid models. (authors)

  2. Black hole Berry phase

    NARCIS (Netherlands)

    de Boer, J.; Papadodimas, K.; Verlinde, E.

    2009-01-01

    Supersymmetric black holes are characterized by a large number of degenerate ground states. We argue that these black holes, like other quantum mechanical systems with such a degeneracy, are subject to a phenomenon which is called the geometric or Berry’s phase: under adiabatic variations of the

  3. Gas phase pulse radiolysis

    International Nuclear Information System (INIS)

    Jonah, C.D.; Andong Liu; Mulac, W.A.

    1987-01-01

    Gas phase pulse radiolysis, a technique which can be used to study many different phenomena in chemistry and physics, is discussed. As a source of small radicals, pulse radiolysis is important to the field of chemistry, particularly to combustion and atmospheric kinetics. The reactions of 1,3-butadiene, allene, ethylene and acetylene with OH are presented. 52 refs., 1 fig., 1 tab

  4. diffusive phase separation

    Directory of Open Access Journals (Sweden)

    Nobuyuki Kenmochi

    1996-01-01

    w is constrained to have double obstacles σ*≤w≤σ* (i.e., σ* and σ* are the threshold values of w. The objective of this paper is to discuss the semigroup {S(t} associated with the phase separation model, and construct its global attractor.

  5. Phase squeezed states

    International Nuclear Information System (INIS)

    Chizhov, A.V.; Paris, M.G.A.

    1998-01-01

    Phase squeezed states of a single mode radiation field have been introduced as eigenstates of a linear combination of lowering and raising operators. The explicit expression in the Fock basis has been obtained and some relevant properties have been illustrated. (author)

  6. Rolling Cylinder Phase 1

    DEFF Research Database (Denmark)

    Margheritini, Lucia; Taraborrelli, Valeria Taraborrelli

    Margheritini and Valeria Taraborrelli(valeria.taraborrelli@hotmail.it) with a total of 3 day visit from the developers. Laboratory tests in irregular waves will be performed by Lucia Margheritini. The report is aimed at the first stage testing of the Rolling Cylinder wave energy device. This phase includes...

  7. paraelectric phase transition

    Indian Academy of Sciences (India)

    The ferroelectric phase transition is diffuse in nature and broadening of the peak increases with La content. Keywords. PLZT ... Marssi et al (1998) concluded the PLZTs x/65/35 as a model. ∗ ... by analysing field cooled (FC) and zero field cooled (ZFC) dielectric ... material are fitted with universal dielectric behaviour within.

  8. Gas-Phase Thermolyses

    DEFF Research Database (Denmark)

    Carlsen, Lars; Egsgaard, Helge

    1982-01-01

    The unimolecular gas-phase thermolyses of 1,2,3-oxadithiolan 2-oxide and thiiran 1-oxide have been studied by the flash vacuum thermolysis–field ionization mass spectrometry (f.v.t.–f.i.m.s.) technique in the temperature range from 1 043 to 1 404 K. The reactions are rationalized in terms of sulp...

  9. Gas-Phase Thermolyses

    DEFF Research Database (Denmark)

    Carlsen, Lars; Egsgaard, Helge

    1982-01-01

    The unimolecular gas-phase thermolyses of the four methyl and ethyl monothioacetates (5)–(8) have been studied by the flash vacuum thermolysis–field ionization mass spectrometry technique in the temperature range 883–1 404 K. The types of reactions verified were keten formation, thiono–thiolo rea...

  10. ALMIP Phase I Report

    DEFF Research Database (Denmark)

    Boone, Aaron; de Rosnay, Patricia; Beljaars, Anton

      This report describes the experimental setup and results of the Phase 1 (i.e. the Regional Scale) of the AMMA (African Monsoon Multidisciplinary Analysis) Land surface Model Intercomparison Project (ALMIP). It is part of the AMMA-EU (European Union) and API  (Action Programmée Interorganisme...

  11. MAD Phasing with Krypton

    International Nuclear Information System (INIS)

    Cohen, A.

    2001-01-01

    Phasing of two proteins, the 17 kDa Fe protein myoglobin from sperm whale (P. catodon) and an 18 kDa protein (SP18) from green abalone (H. fulgens), using Kr-edge MAD with frozen crystals demonstrates the feasibility of this technique as a routine method for structure determination

  12. Phase transitions in nuclear physics

    Energy Technology Data Exchange (ETDEWEB)

    Moretto, L.G.; Phair, L.; Wozniak, G.J.

    1997-08-01

    A critical overview of the low energy phase transitions in nuclei is presented with particular attention to the 2nd (1st) order pairing phase transitions, and to the 1st order liquid-vapor phase transition. The role of fluctuations in washing out these transitions is discussed and illustrated with examples. A robust indicator of phase coexistence in multifragmentation is presented.

  13. Phase transitions in nuclear physics

    International Nuclear Information System (INIS)

    Moretto, L.G.; Phair, L.; Wozniak, G.J.

    1997-08-01

    A critical overview of the low energy phase transitions in nuclei is presented with particular attention to the 2nd (1st) order pairing phase transitions, and to the 1st order liquid-vapor phase transition. The role of fluctuations in washing out these transitions is discussed and illustrated with examples. A robust indicator of phase coexistence in multifragmentation is presented

  14. Phase II Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Schuknecht, Nate [Project Manager; White, David [Principle Investigator; Hoste, Graeme [Research Engineer

    2014-09-11

    The SkyTrough DSP will advance the state-of-the-art in parabolic troughs for utility applications, with a larger aperture, higher operating temperature, and lower cost. The goal of this project was to develop a parabolic trough collector that enables solar electricity generation in the 2020 marketplace for a 216MWe nameplate baseload power plant. This plant requires an LCOE of 9¢/kWhe, given a capacity factor of 75%, a fossil fuel limit of 15%, a fossil fuel cost of $6.75/MMBtu, $25.00/kWht thermal storage cost, and a domestic installation corresponding to Daggett, CA. The result of our optimization was a trough design of larger aperture and operating temperature than has been fielded in large, utility scale parabolic trough applications: 7.6m width x 150m SCA length (1,118m2 aperture), with four 90mm diameter × 4.7m receivers per mirror module and an operating temperature of 500°C. The results from physical modeling in the System Advisory Model indicate that, for a capacity factor of 75%: The LCOE will be 8.87¢/kWhe. SkyFuel examined the design of almost every parabolic trough component from a perspective of load and performance at aperture areas from 500 to 2,900m2. Aperture-dependent design was combined with fixed quotations for similar parts from the commercialized SkyTrough product, and established an installed cost of $130/m2 in 2020. This project was conducted in two phases. Phase I was a preliminary design, culminating in an optimum trough size and further improvement of an advanced polymeric reflective material. This phase was completed in October of 2011. Phase II has been the detailed engineering design and component testing, which culminated in the fabrication and testing of a single mirror module. Phase II is complete, and this document presents a summary of the comprehensive work.

  15. Phase estimation in optical interferometry

    CERN Document Server

    Rastogi, Pramod

    2014-01-01

    Phase Estimation in Optical Interferometry covers the essentials of phase-stepping algorithms used in interferometry and pseudointerferometric techniques. It presents the basic concepts and mathematics needed for understanding the phase estimation methods in use today. The first four chapters focus on phase retrieval from image transforms using a single frame. The next several chapters examine the local environment of a fringe pattern, give a broad picture of the phase estimation approach based on local polynomial phase modeling, cover temporal high-resolution phase evaluation methods, and pre

  16. Transient two-phase flow

    International Nuclear Information System (INIS)

    Hsu, Y.Y.

    1974-01-01

    The following papers related to two-phase flow are summarized: current assumptions made in two-phase flow modeling; two-phase unsteady blowdown from pipes, flow pattern in Laval nozzle and two-phase flow dynamics; dependence of radial heat and momentum diffusion; transient behavior of the liquid film around the expanding gas slug in a vertical tube; flooding phenomena in BWR fuel bundles; and transient effects in bubble two-phase flow. (U.S.)

  17. Measurement by phase severance

    International Nuclear Information System (INIS)

    Noyes, H.P.

    1987-03-01

    It is claimed that the measurement process is more accurately described by ''quasi-local phase severance'' than by ''wave function collapse''. The approach starts from the observation that the usual route to quantum mechanics starting from the Hamilton-Jacobi equations throws away half the degrees of freedom, namely, the classical initial state parameters. To overcome this difficulty, the full set of Hamilton-Jacobi equations is interpreted as operator equations acting on a state vector. The measurement theory presented is based on the conventional S-matrix boundary condition of N/sub A/ free particles in the distant past and N/sub B/ free particles in the distant future and taking the usual free particle wave functions, multiplied by phase factors

  18. Solid phase microextraction.

    Science.gov (United States)

    Pawliszyn, J

    2001-01-01

    Solid Phase Microextraction (SPME) uses a small volume of sorbent dispersed typically on the surface of small fibres, to isolate and concentrate analytes from sample matrix. After contact with sample, analytes are absorbed or adsorbed by the fibre phase (depending on the nature of the coating) until an equilibrium is reached in the system. The amount of an analyte extracted by the coating at equilibrium is determined by the magnitude of the partition coefficient of the analyte between the sample matrix and the coating material. After the extraction step, the fibres are transferred, with the help of a syringe-like handling device, to analytical instrument, for separation and quantitation of target analytes. This technique integrates sampling, extraction and sample introduction and is a simple way of facilitating on-site monitoring. Applications of this technique include environmental monitoring, industrial hygiene, process monitoring, clinical, forensic, food, flavour, fragrance and drug analyses, in laboratory and on-site analysis.

  19. ITER definition phase

    International Nuclear Information System (INIS)

    1989-01-01

    The International Thermonuclear Experimental Reactor (ITER) is envisioned as a fusion device which would demonstrate the scientific and technological feasibility of fusion power. As a first step towards achieving this goal, the European Community, Japan, the Soviet Union, and the United States of America have entered into joint conceptual design activities under the auspices of the International Atomic Energy Agency. A brief summary of the Definition Phase of ITER activities is contained in this report. Included in this report are the background, objectives, organization, definition phase activities, and research and development plan of this endeavor in international scientific collaboration. A more extended technical summary is contained in the two-volume report, ''ITER Concept Definition,'' IAEA/ITER/DS/3. 2 figs, 2 tabs

  20. Discommensurates and incommensurate phases

    International Nuclear Information System (INIS)

    Gordon, Mirta Beatriz

    1983-01-01

    In its first part, this research thesis reports the study of the commensurate-incommensurate (C-I) transition of single layers of rare gases adsorbed on graphite. The anharmonicity of the interaction between adatoms could explain experimental results corresponding to krypton. The author also studied the orientation instability of the single layer with respect to the chemical potential. Near the C-I transition, walls or discommensurates are oriented in substrate symmetry directions which are determined. The effect of substrate deformation on C-I transition is also studied. In the second part, the author studied the phase diagram at low temperature of the anisotropic Ising model with competing interactions for the approximation of the mean field. Finally, the author presents a phenomenological model of Cerium Antimony which reproduces a large part of its phase diagram [fr

  1. Phases, phase equilibria, and phase rules in low-dimensional systems

    International Nuclear Information System (INIS)

    Frolov, T.; Mishin, Y.

    2015-01-01

    We present a unified approach to thermodynamic description of one, two, and three dimensional phases and phase transformations among them. The approach is based on a rigorous definition of a phase applicable to thermodynamic systems of any dimensionality. Within this approach, the same thermodynamic formalism can be applied for the description of phase transformations in bulk systems, interfaces, and line defects separating interface phases. For both lines and interfaces, we rigorously derive an adsorption equation, the phase coexistence equations, and other thermodynamic relations expressed in terms of generalized line and interface excess quantities. As a generalization of the Gibbs phase rule for bulk phases, we derive phase rules for lines and interfaces and predict the maximum number of phases than may coexist in systems of the respective dimensionality

  2. Solid phase extraction membrane

    Science.gov (United States)

    Carlson, Kurt C [Nashville, TN; Langer, Roger L [Hudson, WI

    2002-11-05

    A wet-laid, porous solid phase extraction sheet material that contains both active particles and binder and that possesses excellent wet strength is described. The binder is present in a relatively small amount while the particles are present in a relatively large amount. The sheet material is sufficiently strong and flexible so as to be pleatable so that, for example, it can be used in a cartridge device.

  3. Phase controlled rectifier study

    International Nuclear Information System (INIS)

    Bronner, G.; Murray, J.G.

    1976-03-01

    This report introduces the results of an engineering study incorporating a computer program to determine the transient and steady-state voltage and current wave shapes for a 12-pulse rectifier system. Generally, rectifier engineering studies are completed by making simplified assumptions and neglecting many circuit parameters. The studies incorporate the 3-phase AC parameters including nonlinear source or generator, 3-winding transformer impedances, and shunt and series capacitors. It includes firing angle control, and DC filter circuits with inductive loads

  4. Phase Transitions in Geomorphology

    Science.gov (United States)

    Ortiz, C. P.; Jerolmack, D. J.

    2015-12-01

    Landscapes are patterns in a dynamic steady-state, due to competing processes that smooth or sharpen features over large distances and times. Geomorphic transport laws have been developed to model the mass-flux due to different processes, but are unreasonably effective at recovering the scaling relations of landscape features. Using a continuum approximation to compare experimental landscapes and the observed landscapes of the earth, one finds they share similar morphodynamics despite a breakdown of classical dynamical similarity between the two. We propose the origin of this effectiveness is a different kind of dynamic similarity in the statistics of initiation and cessation of motion of groups of grains, which is common to disordered systems of grains under external driving. We will show how the existing data of sediment transport points to common signatures with dynamical phase transitions between "mobile" and "immobile" phases in other disordered systems, particularly granular materials, colloids, and foams. Viewing landscape evolution from the lens of non-equilibrium statistical physics of disordered systems leads to predictions that the transition of bulk measurements such as particle flux is continuous from one phase to another, that the collective nature of the particle dynamics leads to very slow aging of bulk properties, and that the dynamics are history-dependent. Recent results from sediment transport experiments support these predictions, suggesting that existing geomorphic transport laws may need to be replaced by a new generation of stochastic models with ingredients based on the physics of disordered phase transitions. We discuss possible strategies for extracting the necessary information to develop these models from measurements of geomorphic transport noise by connecting particle-scale collective dynamics and space-time fluctuations over landscape features.

  5. Gas-Phase Thermolysis

    DEFF Research Database (Denmark)

    Carlsen, Lars; Egsgaard, Helge; Schaumann, Ernst

    1980-01-01

    The unimolecular gas-phase thermolytic decomposition of three silylated thionocarboxylic acid derivatives (2b), (3), and (8) have been studied by the flash vacuum thermolysis–field ionization mass spectrometry technique in the temperature range from 783 to 1 404 K in order to elucidate its possible...... applicability as a route to thioketens. Only very minor amounts of the expected thioketens were found, whereas the corresponding ketens were obtained as the major products. A possible mechanism for keten formation is discussed....

  6. Phases and phase transitions of S=1 bosons

    Indian Academy of Sciences (India)

    smukerjee

    Quantum phases and phase transitions of bosons. Subroto Mukerjee. Dept. of Physics & Centre for Quantum. Information and Quantum Computing (CQIQC). Indian Institute of Science, Bangalore. 77th annual meeting of the IAS, Nov. 20 2011, PRL Ahmedabad ...

  7. Qualitative behaviour of incompressible two-phase flows with phase ...

    Indian Academy of Sciences (India)

    Jan Prüss

    2017-11-07

    Nov 7, 2017 ... Qualitative behaviour of incompressible two-phase flows with phase ... Germany. 2Graduate School of Human and Environmental Studies, Kyoto University, ... Note that j is a dummy variable as it can be eliminated from the ...

  8. Phase separation and shape deformation of two-phase membranes

    International Nuclear Information System (INIS)

    Jiang, Y.; Lookman, T.; Saxena, A.

    2000-01-01

    Within a coupled-field Ginzburg-Landau model we study analytically phase separation and accompanying shape deformation on a two-phase elastic membrane in simple geometries such as cylinders, spheres, and tori. Using an exact periodic domain wall solution we solve for the shape and phase separating field, and estimate the degree of deformation of the membrane. The results are pertinent to preferential phase separation in regions of differing curvature on a variety of vesicles. (c) 2000 The American Physical Society

  9. Analyzing phase diagrams and phase transitions in networked competing populations

    Science.gov (United States)

    Ni, Y.-C.; Yin, H. P.; Xu, C.; Hui, P. M.

    2011-03-01

    Phase diagrams exhibiting the extent of cooperation in an evolutionary snowdrift game implemented in different networks are studied in detail. We invoke two independent payoff parameters, unlike a single payoff often used in most previous works that restricts the two payoffs to vary in a correlated way. In addition to the phase transition points when a single payoff parameter is used, phase boundaries separating homogeneous phases consisting of agents using the same strategy and a mixed phase consisting of agents using different strategies are found. Analytic expressions of the phase boundaries are obtained by invoking the ideas of the last surviving patterns and the relative alignments of the spectra of payoff values to agents using different strategies. In a Watts-Strogatz regular network, there exists a re-entrant phenomenon in which the system goes from a homogeneous phase into a mixed phase and re-enters the homogeneous phase as one of the two payoff parameters is varied. The non-trivial phase diagram accompanying this re-entrant phenomenon is quantitatively analyzed. The effects of noise and cooperation in randomly rewired Watts-Strogatz networks are also studied. The transition between a mixed phase and a homogeneous phase is identify to belong to the directed percolation universality class. The methods used in the present work are applicable to a wide range of problems in competing populations of networked agents.

  10. Phase sensitive multichannel OCT

    International Nuclear Information System (INIS)

    Trasischker, W.

    2015-01-01

    The main aim of this thesis was to develop and improve phase sensitive, multichannel methods for optical coherence tomography (OCT) using light in the 840 nm and 1040 nm regime. Conventional OCT provides purely structural information by illuminating the sample by one beam and recording the backscattered signal with one detection channel. Combination of this approach with a raster scan enables the acquisition of 2D and 3D structural information with a resolution in the micrometer regime. However, sometimes additional image contrast or information is desired. Amongst other approaches, this can be provided by a phase sensitive analysis of the interference pattern. Combining phase sensitivity with the illumination of the sample by more than one beam and/or by recording the data using more than one data acquisition channel allows for even more enhanced imaging. While phase sensitive OCT gives access to additional contrast and information, multichannel OCT can provide higher imaging speed, scan eld size and exible dierential measurements. Amongst the dierential, phase sensitive approaches, Doppler OCT (DOCT) and polarization sensitive OCT (PS-OCT) are two of the most promising OCT modalities. While the former targets information on the movement of backscattering particles, the latter measures alterations of the polarization state of the light induced by the sample. Both techniques provide additional image contrast and are, due to the non-invasive and fast character of OCT, well suited for in vivo imaging of the human eye. In the course of this thesis, two dierent multichannel, phase sensitive OCT systems will be presented. First, a D-OCT system with three dierent sampling beams is described. With a central wavelength of 840 nm these three beams are emitted by three individual laser sources. This eectively eliminates any cross talk and provides the full depth range for each channel. Furthermore, by illuminating the sample from three dierent directions, the absolute

  11. Phase change memory

    CERN Document Server

    Qureshi, Moinuddin K

    2011-01-01

    As conventional memory technologies such as DRAM and Flash run into scaling challenges, architects and system designers are forced to look at alternative technologies for building future computer systems. This synthesis lecture begins by listing the requirements for a next generation memory technology and briefly surveys the landscape of novel non-volatile memories. Among these, Phase Change Memory (PCM) is emerging as a leading contender, and the authors discuss the material, device, and circuit advances underlying this exciting technology. The lecture then describes architectural solutions t

  12. Solid phase assays

    International Nuclear Information System (INIS)

    Reese, M.G.; Johnson, L.R.; Ransom, D.K.

    1980-01-01

    In a solid phase assay for quantitative determination of biological and other analytes, a sample such as serum is contacted with a receptor for the analyte being assayed, the receptor being supported on a solid support. No tracer for the analyte is added to the sample before contacting with the receptor; instead the tracer is contacted with the receptor after unbound analyte has been removed from the receptor. The assay can be otherwise performed in a conventional manner but can give greater sensitivity. (author)

  13. Incommensurate phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Currat, R [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1996-11-01

    We review the characteristic aspects of modulated crystals from the point of view of inelastic neutron scattering. We discuss the phenomenological Landau theory of the normal-to-incommensurate displacive instability and its predictions concerning the fluctuation spectrum of the modulated phase. General results on the form of the normal-mode eigenvectors and on the inelastic scattering channels through which they couple to the probe are established using the superspace approach. We illustrate these results on a simple discrete model symmetry and we review available inelastic neutron scattering data on several displacively modulated compounds. (author) 21 figs., 73 refs.

  14. Selected cerium phase diagrams

    International Nuclear Information System (INIS)

    Gschneidner, K.A. Jr.; Verkade, M.E.

    1974-09-01

    A compilation of cerium alloy phase equilibria data based on the most reliable information available is presented. The binary systems selected are those of cerium with each of the following twenty nine elements which might be commonly found in steels: Al, Sb, As, Bi, Ca, C, Cr, Co, Nb, Cu, Fe, Pb, Mg, Mn, Mo, Ni, N, O, P, Se, Si, Ag, S, Te, Sn, Ti, W, and Zn. A brief discussion, a summary of crystal lattice parameters where applicable, and a list of references is included for each element surveyed. (U.S.)

  15. Microcellular foams via phase separation

    International Nuclear Information System (INIS)

    Young, A.T.

    1985-01-01

    A study of wide variety of processes for making plastic foams shows that phase separation processes for polymers from solutions offers the most viable methods for obtaining rigid plastic foams which met the physical requirements for fusion target designs. Four general phase separation methods have been shown to give polymer foams with densities less than 0.1 g/cm 3 and cell sizes of 30μm or less. These methods involve the utilization of non-solvent, chemical or thermal cooling processes to achieve a controlled phase separation wherein either two distinct phases are obtained where the polymer phase is a continuous phase or two bicontinuous phases are obtained where both the polymer and solvent are interpenetrating, continuous, labyrinthine phases. Subsequent removal of the solvent gives the final foam structure

  16. Indicators of Indiscipline. Phase 2

    National Research Council Canada - National Science Library

    Owens, S

    1991-01-01

    .... Phase 2 research was conducted to determine which of the indicators identified by the phase 1 study could successfully identify soldiers who cause accidents due to indiscipline and to field test...

  17. Advanced phase change materials and systems for solar passive heating and cooling of residential buildings

    Energy Technology Data Exchange (ETDEWEB)

    Salyer, I.O.; Sircar, A.K.; Dantiki, S.

    1988-01-01

    During the last three years under the sponsorship of the DOE Solar Passive Division, the University of Dayton Research Institute (UDRI) has investigated four phase change material (PCM) systems for utility in thermal energy storage for solar passive heating and cooling applications. From this research on the basis of cost, performance, containment, and environmental acceptability, we have selected as our current and most promising series of candidate phase change materials, C-15 to C-24 linear crystalline alkyl hydrocarbons. The major part of the research during this contract period was directed toward the following three objectives. Find, test, and develop low-cost effective phase change materials (PCM) that melt and freeze sharply in the comfort temperature range of 73--77{degree}F for use in solar passive heating and cooling of buildings. Define practical materials and processes for fire retarding plasterboard/PCM building products. Develop cost-effective methods for incorporating PCM into building construction materials (concrete, plasterboard, etc.) which will lead to the commercial manufacture and sale of PCM-containing products resulting in significant energy conservation.

  18. Phase diagrams of the elements

    International Nuclear Information System (INIS)

    Young, D.A.

    1975-01-01

    A summary of the pressure-temperature phase diagrams of the elements is presented, with graphs of the experimentally determined solid-solid phase boundaries and melting curves. Comments, including theoretical discussion, are provided for each diagram. The crystal structure of each solid phase is identified and discussed. This work is aimed at encouraging further experimental and theoretical research on phase transitions in the elements

  19. Exotic phases in neutron stars

    International Nuclear Information System (INIS)

    Li, A.; Burgio, G.F.; Lombardo, U.; Peng, G.X.

    2008-01-01

    The appearance of exotic phases in neutron stars is studied. The possible transition from hadron to quark phase is studied within the density dependent mass quark model, and the kaon condensation within the Nelson and Kaplan model. In both cases a microscopic approach is adopted for dense hadron matter. From the study of the possible coexistence between the two phases it is found that the hybrid phase may strongly hinder the onset of kaon condensation. (author)

  20. Phase Referencing in Optical Interferometry

    OpenAIRE

    Filho, Mercedes E.; Garcia, Paulo; Duvert, Gilles; Duchene, Gaspard; Thiebaut, Eric; Young, John; Absil, Olivier; Berger, Jean-Phillipe; Beckert, Thomas; Hoenig, Sebastian; Schertl, Dieter; Weigelt, Gerd; Testi, Leonardo; Tatuli, Eric; Borkowski, Virginie

    2008-01-01

    One of the aims of next generation optical interferometric instrumentation is to be able to make use of information contained in the visibility phase to construct high dynamic range images. Radio and optical interferometry are at the two extremes of phase corruption by the atmosphere. While in radio it is possible to obtain calibrated phases for the science objects, in the optical this is currently not possible. Instead, optical interferometry has relied on closure phase techniques to produce...

  1. The nuclear liquid gas phase transition and phase coexistence

    International Nuclear Information System (INIS)

    Chomaz, Ph.

    2001-01-01

    In this talk we will review the different signals of liquid gas phase transition in nuclei. From the theoretical side we will first discuss the foundations of the concept of equilibrium, phase transition and critical behaviors in infinite and finite systems. From the experimental point of view we will first recall the evidences for some strong modification of the behavior of hot nuclei. Then we will review quantitative detailed analysis aiming to evidence phase transition, to define its order and phase diagram. Finally, we will present a critical discussion of the present status of phase transitions in nuclei and we will draw some lines for future development of this field. (author)

  2. The nuclear liquid gas phase transition and phase coexistence

    Energy Technology Data Exchange (ETDEWEB)

    Chomaz, Ph

    2001-07-01

    In this talk we will review the different signals of liquid gas phase transition in nuclei. From the theoretical side we will first discuss the foundations of the concept of equilibrium, phase transition and critical behaviors in infinite and finite systems. From the experimental point of view we will first recall the evidences for some strong modification of the behavior of hot nuclei. Then we will review quantitative detailed analysis aiming to evidence phase transition, to define its order and phase diagram. Finally, we will present a critical discussion of the present status of phase transitions in nuclei and we will draw some lines for future development of this field. (author)

  3. Conformational analysis of capsaicin using 13C, 15N MAS NMR, GIAO DFT and GA calculations

    Science.gov (United States)

    Siudem, Paweł; Paradowska, Katarzyna; Bukowicki, Jarosław

    2017-10-01

    Capsaicin produced by plants from genus Capsicum exerts multiple pharmacological effects and has found applications in food and pharmaceutical industry. The alkaloid was studied by a combined approach: solid-state NMR, GA conformational search and GIAO DFT methods. The 13C CPMAS NMR spectra were recorded using variable contact time and dipolar dephasing experiments. The results of cross-polarization (CP) kinetics, such as TCP values and long T1ρH (100-200 ms), indicated that the capsaicin molecule is fairly mobile, especially at the end of the aliphatic chain. The15N MAS NMR spectrum showed one narrow signal at -255 ppm. Genetic algorithm (GA) search with multi modal optimization was used to find low-energy conformations of capsaicin. Theoretical GIAO DFT calculations were performed using different basis sets to characterize five selected conformations. 13C CPMAS NMR was used as a validation method and the experimental chemical shifts were compared with those calculated for selected stable conformers. Conformational analysis suggests that the side chain can be bent or extended. A comparison of the experimental and the calculated chemical shifts indicates that solid capsaicin does not have the same structure as those established by PWXRD.

  4. Phase-change materials handbook

    Science.gov (United States)

    Hale, D. V.; Hoover, M. J.; Oneill, M. J.

    1972-01-01

    Handbook describes relationship between phase-change materials and more conventional thermal control techniques and discusses materials' space and terrestrial applications. Material properties of most promising phase-change materials and purposes and uses of metallic filler materials in phase-change material composites are provided.

  5. Phase strength and super lattices

    Indian Academy of Sciences (India)

    Unknown

    much below the solubility limit, so that the short chain molecules do not behave as solvent molecules). Therefore enhanced phase separation and lesser incorporation of. C10-ol (which is however still higher than the value at point B) is responsible for the formation of relatively lesser βo phase and more βm phase at MR ...

  6. Solid-phase spectrophotometry

    International Nuclear Information System (INIS)

    Brykina, G.D.; Marchenko, D.Yu.; Shpigun, O.A.

    1995-01-01

    Solid-phase spectrophotometry (SPS), which is based on the direct measurement of light absorption of an ion exchanger containing a substance of interest, was reviewed. Since 1976, it has been known that aborbance of an ion exchanger is directly proportional to the concentration of a particular ion in solution. A similar dependence can also be followed for other sorbents, as well as for foams, membranes, films, etc., which do not exhibit ion exchange properties. One can use absorption, diffuse reflection, and luminescence spectra parameters as an analytical signal. Thus, SPS of ion exchangers is among the analytical techniques that combine the sorption concentration and surface determination of the substance of interest. This review summarizes the advancements in SPS over the last six years and demonstrates the prospects for its development. Special attention is paid to experimental methods for measuring solid-phase absorption and to the basic procedures of sample preparation, including new ones. These two facets are of great importance for obtaining precise results and extending the capabilities of SPS

  7. Phases of QCD

    Energy Technology Data Exchange (ETDEWEB)

    Roessner, Simon

    2009-04-09

    Quantum Chromodynamics (QCD) is the theory of the strong interaction within the Standard Model of elementary particles. Today's research in this area dedicates substantial resources to numeric solutions of the QCD field equations and experimental programs exploring the phases of QCD. This thesis proceeds along a complementary line - that of modelling QCD, with the aim of identifying its dominant degrees of freedom. This is possible by minimally coupling effective potentials for the Polyakov loop to Nambu-Jona-Lasinio models using temporal background fields to model chiral symmetry breaking respecting colour confinement. The fermion sign problem resulting from the minimal coupling is addressed in this work establishing a novel, systematically ordered approach. The modifications to the approximative order parameter of colour confinement, the Polyakov loop, are in direct connection with the fermion sign problem. Furthermore an effective coupling of quark densities of different flavours is induced. This mechanism, most likely also present in QCD, produces finite contributions to flavour off diagonal susceptibilities. Susceptibilities are amongst the most promising physical quantities for the experimental exploration of the phase transition at high temperatures and densities. (orig.)

  8. Phases of QCD

    International Nuclear Information System (INIS)

    Roessner, Simon

    2009-01-01

    Quantum Chromodynamics (QCD) is the theory of the strong interaction within the Standard Model of elementary particles. Today's research in this area dedicates substantial resources to numeric solutions of the QCD field equations and experimental programs exploring the phases of QCD. This thesis proceeds along a complementary line - that of modelling QCD, with the aim of identifying its dominant degrees of freedom. This is possible by minimally coupling effective potentials for the Polyakov loop to Nambu-Jona-Lasinio models using temporal background fields to model chiral symmetry breaking respecting colour confinement. The fermion sign problem resulting from the minimal coupling is addressed in this work establishing a novel, systematically ordered approach. The modifications to the approximative order parameter of colour confinement, the Polyakov loop, are in direct connection with the fermion sign problem. Furthermore an effective coupling of quark densities of different flavours is induced. This mechanism, most likely also present in QCD, produces finite contributions to flavour off diagonal susceptibilities. Susceptibilities are amongst the most promising physical quantities for the experimental exploration of the phase transition at high temperatures and densities. (orig.)

  9. EGEE enters second phase

    CERN Multimedia

    2006-01-01

    This month has seen the launch of the second two-year phase of the Enabling Grids for E-sciencE project (EGEE-II), with a transition meeting for the partners held at CERN on 12-13 April. Co-funded by the European Commission and coordinated by CERN, the EGEE project is providing an international Grid computing infrastructure - now numbering some 200 sites and 20 000 CPUs in 39 countries - to support the scientific community worldwide. 'We are all very happy about the smooth start of the second phase of EGEE,' said Project Director Bob Jones. 'The project builds on the successes of its first two years and we are now focussing on the stability of the deployed infrastructure. Growing beyond our pilot application areas of HEP and biomedicine, we now see increasing use by researchers from other fields. Recently we've added finance and fusion to the list of disciplines we support, and we are always looking for new users.' More information on EGEE can be found at www.eu-egee.org.

  10. Phase-step retrieval for tunable phase-shifting algorithms

    Science.gov (United States)

    Ayubi, Gastón A.; Duarte, Ignacio; Perciante, César D.; Flores, Jorge L.; Ferrari, José A.

    2017-12-01

    Phase-shifting (PS) is a well-known technique for phase retrieval in interferometry, with applications in deflectometry and 3D-profiling, which requires a series of intensity measurements with certain phase-steps. Usually the phase-steps are evenly spaced, and its knowledge is crucial for the phase retrieval. In this work we present a method to extract the phase-step between consecutive interferograms. We test the proposed technique with images corrupted by additive noise. The results were compared with other known methods. We also present experimental results showing the performance of the method when spatial filters are applied to the interferograms and the effect that they have on their relative phase-steps.

  11. Two-phase flow models

    International Nuclear Information System (INIS)

    Delaje, Dzh.

    1984-01-01

    General hypothesis used to simplify the equations, describing two-phase flows, are considered. Two-component and one-component models of two-phase flow, as well as Zuber and Findlay model for actual volumetric steam content, and Wallis model, describing the given phase rates, are presented. The conclusion is made, that the two-component model, in which values averaged in time are included, is applicable for the solving of three-dimensional tasks for unsteady two-phase flow. At the same time, using the two-component model, including values, averaged in space only one-dimensional tasks for unsteady two-phase flow can be solved

  12. Algorithmic phase diagrams

    Science.gov (United States)

    Hockney, Roger

    1987-01-01

    Algorithmic phase diagrams are a neat and compact representation of the results of comparing the execution time of several algorithms for the solution of the same problem. As an example, the recent results are shown of Gannon and Van Rosendale on the solution of multiple tridiagonal systems of equations in the form of such diagrams. The act of preparing these diagrams has revealed an unexpectedly complex relationship between the best algorithm and the number and size of the tridiagonal systems, which was not evident from the algebraic formulae in the original paper. Even so, for a particular computer, one diagram suffices to predict the best algorithm for all problems that are likely to be encountered the prediction being read directly from the diagram without complex calculation.

  13. Coloured phase singularities

    International Nuclear Information System (INIS)

    Berry, M.V.

    2002-01-01

    For illumination with white light, the spectra near a typical isolated phase singularity (nodal point of the component wavelengths) can be described by a universal function of position, up to linear distortion and a weak dependence on the spectrum of the source. The appearance of the singularity when viewed by a human observer is predicted by transforming the spectrum to trichromatic variables and chromaticity coordinates, and then rendering the colours, scaled to constant luminosity, on a computer monitor. The pattern far from the singularity is a white that depends on the source temperature, and the centre of the pattern is flanked by intensely coloured 'eyes', one orange and one blue, separated by red, and one of the eyes is surrounded by a bright white circle. Only a small range of possible colours appears near the singularity; in particular, there is no green. (author)

  14. Phase vocoder and beyond

    Directory of Open Access Journals (Sweden)

    Marco Liuni

    2013-08-01

    Full Text Available For a broad range of sound transformations, quality is measured according to the common expectation about the result: if a male’s voice has to be changed in a female’s one, there exists a common reference for the perceptive evaluation of the result; the same holds if an instrumental sound has to be made longer, or shorter. Following the argument in Röbel, “Between Physics and Perception: Signal Models for High Level Audio Processing”, a fundamental requirement for these transformation algorithms is their need of signal models that are strongly linked to perceptually relevant physical properties of the sound source. This paper is a short survey about the phase vocoder technique, together with its extensions and improvements relying on appropriate sound models, which have led to high level audio processing algorithms.

  15. Two-phase flow

    International Nuclear Information System (INIS)

    Olive, J.

    1990-01-01

    The design, operation and safety of nuclear components requires increasingly accurate knowledge of two-phase flows. This knowledge is also necessary for some studies related to electricity applications. The author presents some concrete examples showing the range of problems and the complexity of the phenomena involved in these types of flows. Then, the basic principles of their numerical modelling are explained, as well as the new tendency to use increasingly local and refined models. The newest computer codes developed at EDF are briefly presented. Experimental studies dealing with twophase flow are also referred to, and their connections to numerical modelling are explained. Emphasis is placed on the major efforts devoted to the development of new test rigs and instrumentation [fr

  16. Solid-phase microextraction

    DEFF Research Database (Denmark)

    Nilsson, Torben

    The objective of this study has been to develop new analytical methods using the rapid, simple and solvent-free extraction technique solid-phase microextraction (SPME) for the quantitative analysis of organic pollutants at trace level in drinking water and environmental samples. The dynamics...... of SPME were examined for halogenated and non-halogenated volatile hydrocarbons, and a standard method for their quantitative analysis in aqueous samples was developed and validated in inter-laboratory studies on the basis of reference material and in comparison with the traditional methods....... The influences of some possible interferences on the SPME process were examined, and new SPME probes were tested for the in situ monitoring of groundwater pollutants. Inter-laboratory studies were carried out also for the validation of SPME for the quantitative analysis of organochlorine, organonitrogen...

  17. Phase coexistence in multifragmentation?

    International Nuclear Information System (INIS)

    Moretto, L.G.; Phair, L.; Ghetti, R.; Tso, K.; Colonna, N.; Skulski, W.; Wozniak, G.J.; Bowman, D.R.; Carlin, N.; Chartier, M.; Gelbke, C.K.; Gong, W.G.; Hsi, W.C.; Kim, Y.D.; Lisa, M.A.; Lynch, W.G.; Peaslee, G.F.; Schwarz, C.; de Souza, R.T.; Tsang, M.B.; Zhu, F.

    1996-01-01

    The charge (Z) distributions from intermediate energy heavy-ion reactions depend upon the multiplicity n of intermediate mass fragments through a factor of the form e -cnZ . Experimentally c starts from zero at low values of the transverse energy E t and reaches a saturation value at high E t . In a liquid-gas phase diagram c=0 for the saturated vapor, while c approx-gt 0 for the unsaturated vapor. It is suggested that in the c≅0 regime the source evaporates down to a sizable remnant, while for c approx-gt 0 the source vaporizes completely. Percolation of finite systems and nuclear evaporation portray a behavior similar to that observed experimentally. copyright 1996 The American Physical Society

  18. Superconductivity in Chevrel phases

    International Nuclear Information System (INIS)

    Fischer, O.; Seeber, B.

    1979-01-01

    In the last years several ternary superconductors have been discovered, which possess unusual physical properties. Among them the molybdenum chalcogenides, which are often called Chevrel phases, have a special position. Some of these compounds have very high critical fields, which is of special interest for a technical application. In these substances the coexistence of magnetic ordering and superconductivity has been found for the first time, too. Recently it has become possible to prepare new compounds, which are interesting for superconductivity, by the appropriate coalescence of Mo 6 clusters. In the case of Tl 2 Mo 6 Se 6 (Tsub(c) = 3K) this development leads to a quasi-one-dimensional metallic system. (orig.)

  19. Options Study - Phase II

    Energy Technology Data Exchange (ETDEWEB)

    R. Wigeland; T. Taiwo; M. Todosow; W. Halsey; J. Gehin

    2010-09-01

    The Options Study has been conducted for the purpose of evaluating the potential of alternative integrated nuclear fuel cycle options to favorably address the issues associated with a continuing or expanding use of nuclear power in the United States. The study produced information that can be used to inform decisions identifying potential directions for research and development on such fuel cycle options. An integrated nuclear fuel cycle option is defined in this study as including all aspects of the entire nuclear fuel cycle, from obtaining natural resources for fuel to the ultimate disposal of used nuclear fuel (UNF) or radioactive wastes. Issues such as nuclear waste management, especially the increasing inventory of used nuclear fuel, the current uncertainty about used fuel disposal, and the risk of nuclear weapons proliferation have contributed to the reluctance to expand the use of nuclear power, even though it is recognized that nuclear power is a safe and reliable method of producing electricity. In this Options Study, current, evolutionary, and revolutionary nuclear energy options were all considered, including the use of uranium and thorium, and both once-through and recycle approaches. Available information has been collected and reviewed in order to evaluate the ability of an option to clearly address the challenges associated with the current implementation and potential expansion of commercial nuclear power in the United States. This Options Study is a comprehensive consideration and review of fuel cycle and technology options, including those for disposal, and is not constrained by any limitations that may be imposed by economics, technical maturity, past policy, or speculated future conditions. This Phase II report is intended to be used in conjunction with the Phase I report, and much information in that report is not repeated here, although some information has been updated to reflect recent developments. The focus in this Options Study was to

  20. Para-equilibrium phase diagrams

    International Nuclear Information System (INIS)

    Pelton, Arthur D.; Koukkari, Pertti; Pajarre, Risto; Eriksson, Gunnar

    2014-01-01

    Highlights: • A rapidly cooled system may attain a state of para-equilibrium. • In this state rapidly diffusing elements reach equilibrium but others are immobile. • Application of the Phase Rule to para-equilibrium phase diagrams is discussed. • A general algorithm to calculate para-equilibrium phase diagrams is described. - Abstract: If an initially homogeneous system at high temperature is rapidly cooled, a temporary para-equilibrium state may result in which rapidly diffusing elements have reached equilibrium but more slowly diffusing elements have remained essentially immobile. The best known example occurs when homogeneous austenite is quenched. A para-equilibrium phase assemblage may be calculated thermodynamically by Gibbs free energy minimization under the constraint that the ratios of the slowly diffusing elements are the same in all phases. Several examples of calculated para-equilibrium phase diagram sections are presented and the application of the Phase Rule is discussed. Although the rules governing the geometry of these diagrams may appear at first to be somewhat different from those for full equilibrium phase diagrams, it is shown that in fact they obey exactly the same rules with the following provision. Since the molar ratios of non-diffusing elements are the same in all phases at para-equilibrium, these ratios act, as far as the geometry of the diagram is concerned, like “potential” variables (such as T, pressure or chemical potentials) rather than like “normal” composition variables which need not be the same in all phases. A general algorithm to calculate para-equilibrium phase diagrams is presented. In the limit, if a para-equilibrium calculation is performed under the constraint that no elements diffuse, then the resultant phase diagram shows the single phase with the minimum Gibbs free energy at any point on the diagram; such calculations are of interest in physical vapor deposition when deposition is so rapid that phase

  1. Phase equilibria and phase structures of polymer blends

    International Nuclear Information System (INIS)

    Chalykh, Anatolii E; Gerasimov, Vladimir K

    2004-01-01

    Experimental, methodical and theoretical studies dealing with phase equilibria and phase structures of polymer blends are generalised. The general and specific features of the change in solubility of polymers with changes in the molecular mass and copolymer composition and upon the formation of three-dimensional cross-linked networks are described. The results of the effect of the prehistory on the phase structure and the non-equilibrium state of polymer blends are considered in detail.

  2. Simulation of Mission Phases

    Science.gov (United States)

    Carlstrom, Nicholas Mercury

    2016-01-01

    This position with the Simulation and Graphics Branch (ER7) at Johnson Space Center (JSC) provided an introduction to vehicle hardware, mission planning, and simulation design. ER7 supports engineering analysis and flight crew training by providing high-fidelity, real-time graphical simulations in the Systems Engineering Simulator (SES) lab. The primary project assigned by NASA mentor and SES lab manager, Meghan Daley, was to develop a graphical simulation of the rendezvous, proximity operations, and docking (RPOD) phases of flight. The simulation is to include a generic crew/cargo transportation vehicle and a target object in low-Earth orbit (LEO). Various capsule, winged, and lifting body vehicles as well as historical RPOD methods were evaluated during the project analysis phase. JSC core mission to support the International Space Station (ISS), Commercial Crew Program (CCP), and Human Space Flight (HSF) influenced the project specifications. The simulation is characterized as a 30 meter +V Bar and/or -R Bar approach to the target object's docking station. The ISS was selected as the target object and the international Low Impact Docking System (iLIDS) was selected as the docking mechanism. The location of the target object's docking station corresponds with the RPOD methods identified. The simulation design focuses on Guidance, Navigation, and Control (GNC) system architecture models with station keeping and telemetry data processing capabilities. The optical and inertial sensors, reaction control system thrusters, and the docking mechanism selected were based on CCP vehicle manufacturer's current and proposed technologies. A significant amount of independent study and tutorial completion was required for this project. Multiple primary source materials were accessed using the NASA Technical Report Server (NTRS) and reference textbooks were borrowed from the JSC Main Library and International Space Station Library. The Trick Simulation Environment and User

  3. The international phase 4 validation study of the EORTC QLQ-SWB32: a stand-alone measure of spiritual wellbeing (SWB) for people receiving palliative care for cancer

    OpenAIRE

    Vivat, B.; Young, T.; Winstanley, J.; Arraras, J.; Black, K.; Boyle, F.; Brédart, A.; Costantini, A.; Guo, J.; Irarrazaval, M. E.; Kobayashi, K.; Kruizinga, R.; Navarro, M.; Omidvari, S.; Rohde, G. E.

    2017-01-01

    The EORTC Quality of Life (QL) Group has just completed the final phase (field-testing and validation) of an international project to develop a stand-alone measure of spiritual wellbeing (SWB) for palliative cancer patients. Participants (n= 451) - from 14 countries on four continents; 54% female; 188 Christian, 50 Muslim, 156 with no religion - completed a provisional 36-item measure of SWB plus the EORTC QLQ-C15-PAL (PAL), then took part in a structured debriefing interview. All items showe...

  4. Crystalline liquids: the blue phases

    Science.gov (United States)

    Wright, David C.; Mermin, N. David

    1989-04-01

    The blue phases of cholesteric liquid crystals are liquids that exhibit orientational order characterized by crystallographic space-group symmetries. We present here a pedagogical introduction to the current understanding of the equilibrium structure of these phases accompanied by a general overview of major experimental results. Using the Ginzburg-Landau free energy appropriate to the system, we first discuss in detail the character and stability of the usual helical phase of cholesterics, showing that for certain parameter ranges the helical phase is unstable to the appearance of one or more blue phases. The two principal models for the blue phases are two limiting cases of the Ginzburg-Landau theory. We explore each limit and conclude with some general considerations of defects in both models and an exact minimization of the free energy in a curved three-dimensional space.

  5. Berry phase in entangled systems

    International Nuclear Information System (INIS)

    Bertlmann, R.A.; Hasegawa, Y.; Hiesmayr, B.C.; Durstberger, C.

    2005-01-01

    Full text: The influence of the geometric phase, in particular the Berry phase, on an entangled spin-1/2 system is studied. We discuss in detail the case, where the geometric phase is generated only by one part of the Hilbert space. We are able to cancel the effects of the dynamical phase by using the 'spin-echo' method. We analyze how the Berry phase affects the Bell angles and the maximal violation of a CHSH-Bell inequality. Furthermore, we suggest an experimental realization of our setup within neutron interferometry. It is possible to create entanglement between different degrees of freedom (spin and spatial degree of freedom) for a single neutron. The influence of the geometrical phase on the entangled neutron state is tested experimentally which is work in progress. (author)

  6. Structural, electronic and elastic properties of RERu{sub 2} (RE=Pr and Nd) Laves phase intermetallic compounds

    Energy Technology Data Exchange (ETDEWEB)

    Shrivastava, Deepika, E-mail: deepika89shrivastava@gmail.com; Sanyal, Sankar P. [Department of Physics, Barkatullah university, Bhopal, 462026 (India)

    2016-05-06

    We have performed the first-principles calculations to study the structural, electronic and elastic properties of RERu{sub 2} (RE = Pr and Nd) Laves phase intermetallic compounds using full-potential linearized augmented plane wave (FP-LAPW) method based on density functional theory (DFT) within the generalized gradient approximation (GGA) for exchange and correlation potential. The optimized lattices constant are in reasonable agreement with available experimental data. The electronic properties are analyzed in terms of band structures, total and partial density of states, which confirm their metallic character. The calculated elastic constants infer that these compounds are mechanically stable in C15 (MgCu{sub 2} type) structure and found to be ductile in nature.

  7. Modern windships. Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-01

    Knud E. Hansen A/S (KEH) has, partly funded by the Energy Research Programme, (EFP-95) investigated in the possibilities of using windships for transportation of cargo on long routes, i.e. across the Atlantic or Pacific Ocean. The task was to peruse experiences from projects made during the past 30 years and then, based on new materials and design principle to make proposals to modern wind driven ships to transportation of cargo - especially bulk carriers. KEH has thus prepared a suggestion for a 50,000 DWT wind driven bulk carrier on these terms. The bulk carrier in question is a modern rig inspired by the classical lugger and junk sail with a total sail area of abt. 10,000 m{sup 2}. The hull of the ship has been developed in order to limit wave resistance and drifting. Project Windship has, in contrast to earlier tests and projects, designed a bulk carrier based on a complete evaluation of ecology, safety, economy and reasonable transportation speed. The research project shows that international sea transportation, with wind as the primary source of energy, does not seem to run up against any obstacles as regards safety. The economical analyses show that windship transportation, with today`s oil prices, will be about 10% higher compared to the diesel driven transportation. In the light of the positive results of the research project the steering committee recommends that phase II of project `Modern Windships` is carried out. (EG)

  8. Modern windships. Phase 1

    International Nuclear Information System (INIS)

    1996-11-01

    Knud E. Hansen A/S (KEH) has, partly funded by the Energy Research Programme, (EFP-95) investigated in the possibilities of using windships for transportation of cargo on long routes, i.e. across the Atlantic or Pacific Ocean. The task was to peruse experiences from projects made during the past 30 years and then, based on new materials and design principle to make proposals to modern wind driven ships to transportation of cargo - especially bulk carriers. KEH has thus prepared a suggestion for a 50,000 DWT wind driven bulk carrier on these terms. The bulk carrier in question is a modern rig inspired by the classical lugger and junk sail with a total sail area of abt. 10,000 m 2 . The hull of the ship has been developed in order to limit wave resistance and drifting. Project Windship has, in contrast to earlier tests and projects, designed a bulk carrier based on a complete evaluation of ecology, safety, economy and reasonable transportation speed. The research project shows that international sea transportation, with wind as the primary source of energy, does not seem to run up against any obstacles as regards safety. The economical analyses show that windship transportation, with today's oil prices, will be about 10% higher compared to the diesel driven transportation. In the light of the positive results of the research project the steering committee recommends that phase II of project 'Modern Windships' is carried out. (EG)

  9. Phase change materials handbook

    Science.gov (United States)

    Hale, D. V.; Hoover, M. J.; Oneill, M. J.

    1971-01-01

    This handbook is intended to provide theory and data needed by the thermal design engineer to bridge the gap between research achievements and actual flight systems, within the limits of the current state of the art of phase change materials (PCM) technology. The relationship between PCM and more conventional thermal control techniques is described and numerous space and terrestrial applications of PCM are discussed. Material properties of the most promising PCMs are provided; the purposes and use of metallic filler materials in PCM composites are presented; and material compatibility considerations relevant to PCM design are included. The engineering considerations of PCM design are described, especially those pertaining to the thermodynamic and heat transfer phenomena peculiar to PCM design. Methods of obtaining data not currently available are presented. The special problems encountered in the space environment are described. Computational tools useful to the designer are discussed. In summary, each aspect of the PCM problem important to the design engineer is covered to the extent allowed by the scope of this effort and the state of the art.

  10. Kinetics of phase transformations

    International Nuclear Information System (INIS)

    Thompson, M.O.; Aziz, M.J.; Stephenson, G.B.

    1992-01-01

    This volume contains papers presented at the Materials Research Society symposium on Kinetics of Phase Transformations held in Boston, Massachusetts from November 26-29, 1990. The symposium provided a forum for research results in an exceptionally broad and interdisciplinary field. Presentations covered nearly every major class of transformations including solid-solid, liquid-solid, transport phenomena and kinetics modeling. Papers involving amorphous Si, a dominant topic at the symposium, are collected in the first section followed by sections on four major areas of transformation kinetics. The symposium opened with joint sessions on ion and electron beam induced transformations in conjunction with the Surface Chemistry and Beam-Solid Interactions: symposium. Subsequent sessions focused on the areas of ordering and nonlinear diffusion kinetics, solid state reactions and amorphization, kinetics and defects of amorphous silicon, and kinetics of melting and solidification. Seven internationally recognized invited speakers reviewed many of the important problems and recent results in these areas, including defects in amorphous Si, crystal to glass transformations, ordering kinetics, solid-state amorphization, computer modeling, and liquid/solid transformations

  11. Phased Array Feeds

    Science.gov (United States)

    Fisher, J. Richard; Bradley, Richard F.; Brisken, Walter F.; Cotton, William D.; Emerson, Darrel T.; Kerr, Anthony R.; Lacasse, Richard J.; Morgan, Matthew A.; Napier, Peter J.; Norrod, Roger D.; Payne, John M.; Pospieszalski, Marian W.; Symmes, Arthur; Thompson, A. Richard; Webber, John C.

    2009-03-01

    This white paper offers cautionary observations about the planning and development of new, large radio astronomy instruments. Complexity is a strong cost driver so every effort should be made to assign differing science requirements to different instruments and probably different sites. The appeal of shared resources is generally not realized in practice and can often be counterproductive. Instrument optimization is much more difficult with longer lists of requirements, and the development process is longer and less efficient. More complex instruments are necessarily further behind the technology state of the art because of longer development times. Including technology R&D in the construction phase of projects is a growing trend that leads to higher risks, cost overruns, schedule delays, and project de-scoping. There are no technology breakthroughs just over the horizon that will suddenly bring down the cost of collecting area. Advances come largely through careful attention to detail in the adoption of new technology provided by industry and the commercial market. Radio astronomy instrumentation has a very bright future, but a vigorous long-term R&D program not tied directly to specific projects needs to be restored, fostered, and preserved.

  12. Membrane fusion and inverted phases

    International Nuclear Information System (INIS)

    Ellens, H.; Siegel, D.P.; Alford, D.; Yeagle, P.L.; Boni, L.; Lis, L.J.; Quinn, P.J.; Bentz, J.

    1989-01-01

    We have found a correlation between liposome fusion kinetics and lipid phase behavior for several inverted phase forming lipids. N-Methylated dioleoylphosphatidylethanolamine (DOPE-Me), or mixtures of dioleoylphosphatidylethanolamine (DOPE) and dioleoylphosphatidylcholine (DOPC), will form an inverted hexagonal phase (HII) at high temperatures (above TH), a lamellar phase (L alpha) at low temperatures, and an isotropic/inverted cubic phase at intermediate temperatures, which is defined by the appearance of narrow isotropic 31 P NMR resonances. The phase behavior has been verified by using high-sensitivity DSC, 31 P NMR, freeze-fracture electron microscopy, and X-ray diffraction. The temperature range over which the narrow isotropic resonances occur is defined as delta TI, and the range ends at TH. Extruded liposomes (approximately 0.2 microns in diameter) composed of these lipids show fusion and leakage kinetics which are strongly correlated with the temperatures of these phase transitions. At temperatures below delta TI, where the lipid phase is L alpha, there is little or no fusion, i.e., mixing of aqueous contents, or leakage. However, as the temperature reaches delta TI, there is a rapid increase in both fusion and leakage rates. At temperatures above TH, the liposomes show aggregation-dependent lysis, as the rapid formation of HII phase precursors disrupts the membranes. We show that the correspondence between the fusion and leakage kinetics and the observed phase behavior is easily rationalized in terms of a recent kinetic theory of L alpha/inverted phase transitions. In particular, it is likely that membrane fusion and the L alpha/inverted cubic phase transition proceed via a common set of intermembrane intermediates

  13. Phase detection electronics for CLIC

    CERN Document Server

    Andersson, A

    2011-01-01

    The Compact Linear Collider (CLIC) requires very tight RF phase synchronisation in order to preserve high luminosity. The electronics required for processing the signals delivered from the phase pick-ups present a significant challenge. This paper discusses the strategy adopted to achieve a sufficiently accurate measurement of the phase. Performance measurements performed in the lab of some of the sub-systems are also presented.

  14. Hybrid Nanocomposite Photovoltaics, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — This Small Business Innovation Research Phase I project will develop an innovative solar cell design that combines nanotechnology with conducting polymer...

  15. Quantum computers in phase space

    International Nuclear Information System (INIS)

    Miquel, Cesar; Paz, Juan Pablo; Saraceno, Marcos

    2002-01-01

    We represent both the states and the evolution of a quantum computer in phase space using the discrete Wigner function. We study properties of the phase space representation of quantum algorithms: apart from analyzing important examples, such as the Fourier transform and Grover's search, we examine the conditions for the existence of a direct correspondence between quantum and classical evolutions in phase space. Finally, we describe how to measure directly the Wigner function in a given phase-space point by means of a tomographic method that, itself, can be interpreted as a simple quantum algorithm

  16. Qubit rotation and Berry phase

    International Nuclear Information System (INIS)

    Banerjee, D.; Bandyopadhyay, P.

    2005-11-01

    A quantized fermion is represented by a scalar particle encircling a magnetic flux line. It has the spinor structure which can be constructed from quantum gates and qubits. We have studied here the role of Berry phase in removing dynamical phase during one qubit rotation of a quantized fermion. The entanglement of two qubits inserting spin-echo to one of them results the trapped Berry phase to measure entanglement. Some effort is given to study the effect of noise on the Berry phase of spinors and their entangled states. (author)

  17. Magnetic resonance of phase transitions

    CERN Document Server

    Owens, Frank J; Farach, Horacio A

    1979-01-01

    Magnetic Resonance of Phase Transitions shows how the effects of phase transitions are manifested in the magnetic resonance data. The book discusses the basic concepts of structural phase and magnetic resonance; various types of magnetic resonances and their underlying principles; and the radiofrequency methods of nuclear magnetic resonance. The text also describes quadrupole methods; the microwave technique of electron spin resonance; and the Mössbauer effect. Phase transitions in various systems such as fluids, liquid crystals, and crystals, including paramagnets and ferroelectrics, are also

  18. Three phase spiral liver Scanning

    International Nuclear Information System (INIS)

    Kanyanja, T.A.

    2006-01-01

    The ability to perform rapid back-to-back spiral acquisitions is an important recent technical advantage of spiral CT. this allows imaging of the upper abdomen (liver) during peak arterial enhancement (arterial phase) and during peak hepatic parenchymal enhancement (portal venous phase). Breatheld spiral CT has completely replaced dynamic incremental CT for evaluation of the liver. in selected patients with hyper vascular metastasis (hepatoma, neuroendocrine tumors, renal cell carcinoma, etc.) a biphasic examination is performed with one spiral acquisition obtained during the hepatic arterial phase and a second acquisition during the portal venous phase

  19. Geometric phase from dielectric matrix

    International Nuclear Information System (INIS)

    Banerjee, D.

    2005-10-01

    The dielectric property of the anisotropic optical medium is found by considering the polarized photon as two component spinor of spherical harmonics. The Geometric Phase of a polarized photon has been evaluated in two ways: the phase two-form of the dielectric matrix through a twist and the Pancharatnam phase (GP) by changing the angular momentum of the incident polarized photon over a closed triangular path on the extended Poincare sphere. The helicity in connection with the spin angular momentum of the chiral photon plays the key role in developing these phase holonomies. (author)

  20. Electronically soft phases in manganites.

    Science.gov (United States)

    Milward, G C; Calderón, M J; Littlewood, P B

    2005-02-10

    The phenomenon of colossal magnetoresistance in manganites is generally agreed to be a result of competition between crystal phases with different electronic, magnetic and structural order; a competition which can be strong enough to cause phase separation between metallic ferromagnetic and insulating charge-modulated states. Nevertheless, closer inspection of phase diagrams in many manganites reveals complex phases where the two order parameters of magnetism and charge modulation unexpectedly coexist. Here we show that such experiments can be naturally explained within a phenomenological Ginzburg-Landau theory. In contrast to models where phase separation originates from disorder or as a strain-induced kinetic phenomenon, we argue that magnetic and charge modulation coexist in new thermodynamic phases. This leads to a rich diagram of equilibrium phases, qualitatively similar to those seen experimentally. The success of this model argues for a fundamental reinterpretation of the nature of charge modulation in these materials, from a localized to a more extended 'charge-density wave' picture. The same symmetry considerations that favour textured coexistence of charge and magnetic order may apply to many electronic systems with competing phases. The resulting 'electronically soft' phases of matter with incommensurate, inhomogeneous and mixed order may be general phenomena in correlated systems.

  1. Qubit rotation and Berry phase

    International Nuclear Information System (INIS)

    Banerjee, Dipti; Bandyopadhyay, Pratul

    2006-01-01

    A quantized fermion is represented by a scalar particle encircling a magnetic flux line. It has a spinor structure which can be constructed from quantum gates and qubits. We have studied here the role of Berry phase in removing dynamical phase during one qubit rotation of a quantized fermion. The entanglement of two qubits inserting spin-echo to one of them allows the trapped Berry phase to measure entanglement. Some effort is given to study the effect of noise on the Berry phase of spinors and their entangled states

  2. Savanna ecosystem project: phase I summary and phase II progress

    CSIR Research Space (South Africa)

    Huntely, BJ

    1978-07-01

    Full Text Available A summary of the results of the first phase (mid 1974 to mid 1976) of the South African Savanna Ecosystem Project being undertaken at Nylsvley in the northern Transvaal is presented. Phase I of this ten year study of the structure and functioning...

  3. High pressure phases of terbium: Possibility of a thcp phase

    International Nuclear Information System (INIS)

    Staun Olsen, J.; Steenstrup, S.; Gerward, L.

    1985-01-01

    High pressure phases of trivalent Tb studied by energy dispersive X-ray diffraction with synchrotron radiation exhibits the closed packed sequence (hcp -> Sm -> dhcp -> fcc) typical of the trivalent rare earth metals. Furthermore, a phase consistent with a triple hexagonal closed packed (thcp) structure was observed in a narrow pressure range around 30 GPa. (orig.)

  4. Environmental program. Phase 2

    International Nuclear Information System (INIS)

    1993-03-01

    The Norwegian Oil Industry Association (OLF) has between 1991 and 1993 conducted an environmental program. The objectives were to: Enhance the knowledge of emissions to air and discharges to sea from Norwegian offshore oil and gas production operations. Evaluate the technology and the associated costs for potential reduction of continuous emissions and discharges. Phase 2 of the program has in particular focused on the relationship between the cost and benefit of emission and discharge reduction measures. The purpose has been to identify the measures giving the largest reductions per unit cost. This has now been performed and is documented in 24 technical reports. Total production of oil and gas from the Norwegian sector was 130 million tons oil equivalents (toe) in 1992, most of which was exported to markets in Europe. All this will ultimately be consumed, primarily through energy conversion processes, with release of CO 2 and other greenhouse emission gases. The current gas production of 26 million toe per year will increase rapidly during the coming ten years, while the present increase in oil production is expected to culminate in the same period. Reduction of atmospheric emissions from the Norwegian oil and gas industry may be achieved primarily through energy efficiency measures. Approximately 2.5% of the fossil fuel energy is consumed in the production and transportation process. Different environmental standards between producing nations will primarily affect production cost. The competitiveness of the various producing regions, rather than the overall environmental impact of the petroleum industry and its products, will be effected. 36 refs., 61 figs., 33 tabs

  5. Phase transitions in surfactant monolayers

    International Nuclear Information System (INIS)

    Casson, B.D.

    1998-01-01

    Two-dimensional phase transitions have been studied in surfactant monolayers at the air/water interface by sum-frequency spectroscopy and ellipsometry. In equilibrium monolayers of medium-chain alcohols C n H 2n+1 OH (n = 9-14) a transition from a two-dimensional crystalline phase to a liquid was observed at temperatures above the bulk melting point. The small population of gauche defects in the solid phase increased only slightly at the phase transition. A model of the hydrocarbon chains as freely rotating rigid rods allowed the area per molecule and chain tilt in the liquid phase to be determined. The area per molecule, chain tilt and density of the liquid phase all increased with increasing chain length, but for each chain length the density was higher than in a bulk liquid hydrocarbon. In a monolayer of decanol adsorbed at the air/water interface a transition from a two-dimensional liquid to a gas was observed. A clear discontinuity in the coefficient of ellipticity as a function of temperature showed that the transition is first-order. This result suggests that liquid-gas phase transitions in surfactant monolayers may be more widespread than once thought. A solid-liquid phase transition has also been studied in mixed monolayers of dodecanol with an anionic surfactant (sodium dodecyl sulphate) and with a homologous series of cationic surfactants (alkyltrimethylammonium bromides: C n TABs, n = 12, 14, 16). The composition and structure of the mixed monolayers was studied above and below the phase transition. At low temperatures the mixed monolayers were as densely packed as a monolayer of pure dodecanol in its solid phase. At a fixed temperature the monolayers under-went a first-order phase transition to form a phase that was less dense and more conformationally disordered. The proportion of ionic surfactant in the mixed monolayer was greatest in the high temperature phase. As the chain length of the C n TAB increased the number of conformational defects

  6. 78 FR 33911 - Phased Retirement

    Science.gov (United States)

    2013-06-05

    ... to implement phased retirement, a new human resources tool that allows full-time employees to work a..., 582, 831, et al. Phased Retirement; Proposed Rule #0;#0;Federal Register / Vol. 78 , No. 108 / Wednesday, June 5, 2013 / Proposed Rules#0;#0; [[Page 33912

  7. Generalized definitions of phase transitions

    International Nuclear Information System (INIS)

    Chomaz, Ph.; Gulminelli, F.

    2001-09-01

    We define a first order phase transition as a bimodality of the event distribution in the space of observations and we show that this is equivalent to a curvature anomaly of the thermodynamical potential and that it implies the Yang Lee behavior of the zeros of the partition sum. Moreover, it allows to study phase transitions out of equilibrium. (authors)

  8. Beam phase space and emittance

    International Nuclear Information System (INIS)

    Buon, J.

    1990-12-01

    The classical and elementary results for canonical phase space, the Liouville theorem and the beam emittance are reviewed. Then, the importance of phase portraits to obtain a geometrical description of motion is emphasized, with examples in accelerator physics. Finally, a statistical point of view is used to define beam emittance, to study its law of approximate conservation and to treat two particular examples

  9. Multiphase flows with phase change

    Indian Academy of Sciences (India)

    Multiphase flows with phase change are ubiquitous in many industrial sectors ranging from energy and infra-structure to specialty chemicals and pharmaceuticals. My own interest in mul- tiphase flows with phase change started more than 15 years ago when I had initiated work on riser reactor for fluid catalytic cracking and ...

  10. Phase transitions in field theory

    International Nuclear Information System (INIS)

    Carvalho, C.A.A. de; Bollini, C.G.; Giambiagi, J.J.

    1984-01-01

    By means of an example for which the effective potential is explicitly calculable (up to the one loop approximation), it is discussed how a phase transition takes place as the temperature is increased and pass from spontaneously broken symmetry to a phase in which the symmetry is restored. (Author) [pt

  11. Moment Distributions of Phase Type

    DEFF Research Database (Denmark)

    Bladt, Mogens; Nielsen, Bo Friis

    2011-01-01

    Moment distributions of phase-type and matrix-exponential distributions are shown to remain within their respective classes. We provide a probabilistic phase-type representation for the former case and an alternative representation, with an analytically appealing form, for the latter. First order...

  12. Graphene based terahertz phase modulators

    Science.gov (United States)

    Kakenov, N.; Ergoktas, M. S.; Balci, O.; Kocabas, C.

    2018-07-01

    Electrical control of amplitude and phase of terahertz radiation (THz) is the key technological challenge for high resolution and noninvasive THz imaging. The lack of active materials and devices hinders the realization of these imaging systems. Here, we demonstrate an efficient terahertz phase and amplitude modulation using electrically tunable graphene devices. Our device structure consists of electrolyte-gated graphene placed at quarter wavelength distance from a reflecting metallic surface. In this geometry, graphene operates as a tunable impedance surface which yields electrically controlled reflection phase. Terahertz time domain reflection spectroscopy reveals the voltage controlled phase modulation of π and the reflection modulation of 50 dB. To show the promises of our approach, we demonstrate a multipixel phase modulator array which operates as a gradient impedance surface.

  13. Nanoscale phase change memory materials.

    Science.gov (United States)

    Caldwell, Marissa A; Jeyasingh, Rakesh Gnana David; Wong, H-S Philip; Milliron, Delia J

    2012-08-07

    Phase change memory materials store information through their reversible transitions between crystalline and amorphous states. For typical metal chalcogenide compounds, their phase transition properties directly impact critical memory characteristics and the manipulation of these is a major focus in the field. Here, we discuss recent work that explores the tuning of such properties by scaling the materials to nanoscale dimensions, including fabrication and synthetic strategies used to produce nanoscale phase change memory materials. The trends that emerge are relevant to understanding how such memory technologies will function as they scale to ever smaller dimensions and also suggest new approaches to designing materials for phase change applications. Finally, the challenges and opportunities raised by integrating nanoscale phase change materials into switching devices are discussed.

  14. Phase-sensitive flow cytometer

    Energy Technology Data Exchange (ETDEWEB)

    Steinkamp, J.A.

    1992-12-31

    This report describes phase-sensitive flow cytometer (FCM) which provides additional FCM capability to use the fluorescence lifetime of one or more fluorochromes bound to single cells to provide additional information regarding the cells. The resulting fluorescence emission can be resolved into individual fluorescence signals if two fluorochromes are present or can be converted directly to a decay lifetime from a single fluorochrome. The excitation light for the fluorochromes is modulated to produce an amplitude modulated fluorescence pulse as the fluorochrome is excited in the FCM. The modulation signal also forms a reference signal that is phase-shifted a selected amount for subsequent mixing with the output modulated fluorescence intensity signal in phase-sensitive detection circuitry. The output from the phase-sensitive circuitry is then an individual resolved fluorochrome signal or a single fluorochrome decay lifetime, depending on the applied phase shifts.

  15. Phase transition in finite systems

    International Nuclear Information System (INIS)

    Chomaz, Ph.; Duflot, V.; Duflot, V.; Gulminelli, F.

    2000-01-01

    In this paper we present a review of selected aspects of Phase transitions in finite systems applied in particular to the liquid-gas phase transition in nuclei. We show that the problem of the non existence of boundary conditions can be solved by introducing a statistical ensemble with an averaged constrained volume. In such an ensemble the microcanonical heat capacity becomes negative in the transition region. We show that the caloric curve explicitly depends on the considered transformation of the volume with the excitation energy and so does not bear direct informations on the characteristics of the phase transition. Conversely, partial energy fluctuations are demonstrated to be a direct measure of the equation of state. Since the heat capacity has a negative branch in the phase transition region, the presence of abnormally large kinetic energy fluctuations is a signal of the liquid gas phase transition. (author)

  16. 129I Interlaboratory comparison: phase I and phase II

    International Nuclear Information System (INIS)

    Caffee, M. W.; Roberts, M. L.

    1999-01-01

    An interlaboratory comparison exercise for 129 I was organized and conducted. Nine laboratories participated in the exercise to either a full or limited extent. In Phase I of the comparison, 11 samples were measured. The suite of samples contained both synthetic ''standard type'' materials (i.e., AgI) and environmental materials. The isotopic 129 I/ 127 I ratios of the samples varied from 10 -8 to 10 -14 . In this phase, each laboratory was responsible for its own chemical preparation of the samples. In Phase I, the 129 I AMS measurements for prepared AgI were in good agreement. However, large discrepancies were seen in 129 I AMS measurements of environmental samples. Because of the large discrepancies seen in the Phase I 129 I intercomparison, a subsequent study was conducted. In Phase II of the 129 I intercomparison, three separate laboratories prepared AgI from two environmental samples (IAEA 375 soil and maples leaves). Each laboratory used its own chemical preparation method with each of the methods being distinctly different. The resulting six samples (two sets of three) were then re-distributed to the participating 129 I AMS facilities and 129 I/ 127 I ratios measured. Results and discussion of both the Phase I and Phase II interlaboratory comparison are presented

  17. Phase conversion for fusion lasers

    International Nuclear Information System (INIS)

    Kessler, T.; Castle, W.; Sampat, N.; Skupsky, S.; Smith, D.; Swales, S.

    1988-01-01

    An essential requirement for direct drive laser fusion is the uniform irradiation of spherical targets that are located in the quasi-far field of a laser system. A major impediment to irradiation uniformity with high-power solid-state laser systems is the presence of a hot-spot structure at the target plane. The hot-spot intensity nonuniformities are caused by spatial variations in the near-field phase front of each laser beam. Although for many tabletop applications diffraction-limited laser performance can be obtained through static phase correction, adaptive optics, or phase conjugation, such approaches are either excessively expensive, difficult to implement, or not yet available for large-aperture, high-peak-power laser beams. An alternative to phase correcting a wavefront involves modifying the laser beam's coherence properties thereby changing its focusing characteristics. The method of induced spatial incoherence (ISI) involves a reduction in both spatial and temporal coherence. Other methods are based on modifications of only the spatial coherence of a laser beam. A phase conversion technology which incorporates a distribution of near-field phases to either perform static phase correction or induce spatial incoherence offers a route toward increasingly higher levels of irradiation uniformity

  18. Anisotropies of in-phase, out-of-phase,\

    Czech Academy of Sciences Publication Activity Database

    Hrouda, F.; Chadima, Martin; Ježek, J.; Kadlec, Jaroslav

    2018-01-01

    Roč. 62 (2018) ISSN 0039-3169 Institutional support: RVO:67985530 ; RVO:67985831 Keywords : anisotropy * out-of-phase susceptibility * frequency-dependent susceptibility Subject RIV: DB - Geology ; Mineralogy Impact factor: 0.764, year: 2016

  19. Flexible, Phase Change Fabric for Deployable Decelerators, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — SDMA proposes to develop a flexible fabric containing Phase Change Materials that is suitable for use on Deployable Decelerators. This technology will make...

  20. Gas hydrate phase equilibria measurement techniques and phase rule considerations

    International Nuclear Information System (INIS)

    Beltran, Juan G.; Bruusgaard, Hallvard; Servio, Phillip

    2012-01-01

    Highlights: → Inconsistencies found in hydrate literature. → Clarification to the number of variables needed to satisfy and justify equilibrium data. → Application of phase rule to mixed hydrate systems. → Thermodynamically consistent format to present data. - Abstract: A brief review of the Gibbs phase rule for non-reacting systems and its correct application to clathrate hydrates is presented. Clarification is provided for a common mistake found in hydrate phase-equilibria literature, whereby initial compositions are used as intensive variables to satisfy the Gibbs phase rule instead of the equilibrium values. The system of (methane + carbon dioxide + water) under (hydrate + liquid + vapor) equilibrium is used as a case study to illustrate key points and suggestions to improve experimental techniques are proposed.

  1. An absorbing phase transition from a structured active particle phase

    Energy Technology Data Exchange (ETDEWEB)

    Lopez, Cristobal [Instituto Mediterraneo de Estudios Avanzados IMEDEA (CSIC-UIB), Campus de la Universidad de las Islas Baleares, E-07122 Palma de Mallorca (Spain); Ramos, Francisco [Departamento de Electromagnetismo y Fisica de la Materia and Instituto de Fisica Teorica y Computacional Carlos I, Facultad de Ciencias, Universidad de Granada, 18071 Granada (Spain); Hernandez-GarcIa, Emilio [Instituto Mediterraneo de Estudios Avanzados IMEDEA (CSIC-UIB), Campus de la Universidad de las Islas Baleares, E-07122 Palma de Mallorca (Spain)

    2007-02-14

    In this work we study the absorbing state phase transition of a recently introduced model for interacting particles with neighbourhood-dependent reproduction rates. The novelty of the transition is that as soon as the active phase is reached by increasing a control parameter a periodically arranged structure of particle clusters appears. A numerical study in one and two dimensions shows that the system falls into the directed percolation universality class.

  2. Phase behavior and phase inversion for dispersant systems

    International Nuclear Information System (INIS)

    Solheim, A.; Brandvik, P.J.

    1991-06-01

    This report describes some preliminary phase behavior studies and phase inversion temperature measurements in seawater, bunker oil and dispersant. The objectives have been to find new ways of characterizing dispersants for dispersing oil spill at sea and, perhaps, to throw new lights on the mechanism of dispersion formation (oil-in-water emulsification). The work has been focussed on the relation to phase behavior and the existence of microemulsion in equilibrium with excess oil and water phases. The dispersing process is also compared to the recommended conditions for emulsion formation. When forming an oil-in-water emulsion in an industrial process, it is recommended to choose an emulsifier which gives a phase inversion temperature (PIT) which is 20 - 60 o C higher than the actual temperature for use. The emulsification process must take place close to the PIT which is the temperature at which the emulsion change from oil-in-water emulsion to water-in-oil emulsion when the system is stirred. This condition corresponds to the temperature where the phase behavior change character. The purpose has been to find out if the composition of the dispersants corresponds to the recommendations for oil-in-water emulsification. The amount of experimental work has been limited. Two kinds of experiments have been carried out. Phase behavior studies have been done for seawater, bunker oil and four different dispersants where one had an optimal composition. The phase behavior was hard to interpret and is not recommended for standard dispersants test. The other experimental technique was PIT-measurements by conductivity measurements versus temperature. 4 figs., 1 tab., 4 refs

  3. Phase Noise Tolerant QPSK Receiver Using Phase Sensitive Wavelength Conversion

    DEFF Research Database (Denmark)

    Da Ros, Francesco; Xu, Jing; Lei, Lei

    2013-01-01

    A novel QPSK receiver based on a phase noise reduction pre-stage exploiting PSA in a HNLF and balanced detection is presented. Receiver sensitivity improvement over a conventional balanced receiver is demonstrated.......A novel QPSK receiver based on a phase noise reduction pre-stage exploiting PSA in a HNLF and balanced detection is presented. Receiver sensitivity improvement over a conventional balanced receiver is demonstrated....

  4. Quantum mechanics in phase space

    DEFF Research Database (Denmark)

    Hansen, Frank

    1984-01-01

    A reformulation of quantum mechanics for a finite system is given using twisted multiplication of functions on phase space and Tomita's theory of generalized Hilbert algebras. Quantization of a classical observable h is achieved when the twisted exponential Exp0(-h) is defined as a tempered....... Generalized Weyl-Wigner maps related to the notion of Hamiltonian weight are studied and used in the formulation of a twisted spectral theory for functions on phase space. Some inequalities for Wigner functions on phase space are proven. A brief discussion of the classical limit obtained through dilations...

  5. Fundamentals of ultrasonic phased arrays

    CERN Document Server

    Schmerr, Lester W

    2014-01-01

    This book describes in detail the physical and mathematical foundations of ultrasonic phased array measurements.?The book uses linear systems theory to develop a comprehensive model of the signals and images that can be formed with phased arrays. Engineers working in the field of ultrasonic nondestructive evaluation (NDE) will find in this approach a wealth of information on how to design, optimize and interpret ultrasonic inspections with phased arrays. The fundamentals and models described in the book will also be of significant interest to other fields, including the medical ultrasound and

  6. A Phase Matching, Adiabatic Accelerator

    Energy Technology Data Exchange (ETDEWEB)

    Lemery, Francois [Hamburg U.; Flöttmann, Klaus [DESY; Kärtner, Franz [CFEL, Hamburg; Piot, Philippe [Northern Illinois U.

    2017-05-01

    Tabletop accelerators are a thing of the future. Reducing their size will require scaling down electromagnetic wavelengths; however, without correspondingly high field gradients, particles will be more susceptible to phase-slippage – especially at low energy. We investigate how an adiabatically-tapered dielectric-lined waveguide could maintain phase-matching between the accelerating mode and electron bunch. We benchmark our simple model with CST and implement it into ASTRA; finally we provide a first glimpse into the beam dynamics in a phase-matching accelerator.

  7. Covariant phase difference observables in quantum mechanics

    International Nuclear Information System (INIS)

    Heinonen, Teiko; Lahti, Pekka; Pellonpaeae, Juha-Pekka

    2003-01-01

    Covariant phase difference observables are determined in two different ways, by a direct computation and by a group theoretical method. A characterization of phase difference observables which can be expressed as the difference of two phase observables is given. The classical limits of such phase difference observables are determined and the Pegg-Barnett phase difference distribution is obtained from the phase difference representation. The relation of Ban's theory to the covariant phase theories is exhibited

  8. Composite Repair System, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — GTL has developed an innovative composite repair methodology known as the Composite Repair System (CRS). In this phase I effort, CRS is being developed for the...

  9. Non-equilibrium phase transitions

    CERN Document Server

    Henkel, Malte; Lübeck, Sven

    2009-01-01

    This book describes two main classes of non-equilibrium phase-transitions: (a) static and dynamics of transitions into an absorbing state, and (b) dynamical scaling in far-from-equilibrium relaxation behaviour and ageing. The first volume begins with an introductory chapter which recalls the main concepts of phase-transitions, set for the convenience of the reader in an equilibrium context. The extension to non-equilibrium systems is made by using directed percolation as the main paradigm of absorbing phase transitions and in view of the richness of the known results an entire chapter is devoted to it, including a discussion of recent experimental results. Scaling theories and a large set of both numerical and analytical methods for the study of non-equilibrium phase transitions are thoroughly discussed. The techniques used for directed percolation are then extended to other universality classes and many important results on model parameters are provided for easy reference.

  10. SGA Phase 2 Assessed Reaches

    Data.gov (United States)

    Vermont Center for Geographic Information — The stream geomorphic assessment (SGA) is a physical assessment competed by geomorphologists to determine the condition and sensitivity of a stream. The Phase 2 SGA...

  11. Phase transition in finite systems

    International Nuclear Information System (INIS)

    Chomaz, Ph.; Duflot, V.; Duflot, V.; Gulminelli, F.

    2000-01-01

    The general problem of the definition of a phase transition without employing the thermodynamical limit is addressed. Different necessary conditions are considered and illustrated with examples from different nuclear and general physics phenomenologies. (authors)

  12. Phase transitions and quantum entropy

    International Nuclear Information System (INIS)

    Arrachea, L.; Canosa, N.; Plastino, A.; Portesi, M.; Rossignoli, R.

    1990-01-01

    An examination is made of the possibility to predict phase transitions of the fundamental state of finite quantum system, knowing the quantum entropy of these states, defined on the basis of the information theory. (Author). 7 refs., 3 figs

  13. CLIC Drive Beam Phase Stabilisation

    CERN Document Server

    Gerbershagen, Alexander; Schulte, Daniel

    The thesis presents phase stability studies for the Compact Linear Collider (CLIC) and focuses in particular on CLIC Drive Beam longitudinal phase stabilisation. This topic constitutes one of the main feasibility challenges for CLIC construction and is an essential component of the current CLIC stabilisation campaign. The studies are divided into two large interrelated sections: the simulation studies for the CLIC Drive Beam stability, and measurements, data analysis and simulations of the CLIC Test Facility (CTF3) Drive Beam phase errors. A dedicated software tool has been developed for a step-by-step analysis of the error propagation through the CLIC Drive Beam. It uses realistic RF potential and beam loading amplitude functions for the Drive and Main Beam accelerating structures, complete models of the recombination scheme and compressor chicane as well as of further CLIC Drive Beam modules. The tool has been tested extensively and its functionality has been verified. The phase error propagation at CLIC h...

  14. Phase transition in finite systems

    Energy Technology Data Exchange (ETDEWEB)

    Chomaz, Ph.; Duflot, V. [Grand Accelerateur National d' Ions Lourds (GANIL), 14 - Caen (France); Duflot, V.; Gulminelli, F. [Laboratoire de Physique Corpusculaire, LPC-ISMRa, CNRS-IN2P3, 14 - Caen (France)

    2000-07-01

    The general problem of the definition of a phase transition without employing the thermodynamical limit is addressed. Different necessary conditions are considered and illustrated with examples from different nuclear and general physics phenomenologies. (authors)

  15. Berry's Phase and Fine Structure

    CERN Document Server

    Binder, B

    2002-01-01

    Irrational numbers can be assigned to physical entities based on iterative processes of geometric objects. It is likely that iterative round trips of vector signals include a geometric phase component. If so, this component will couple back to the round trip frequency or path length generating an non-linear feedback loop (i.e. induced by precession). In this paper such a quantum feedback mechanism is defined including generalized fine structure constants in accordance with the fundamental gravitomagnetic relation of spin-orbit coupling. Supported by measurements, the general relativistic and topological background allows to propose, that the deviation of the fine structure constant from 1/137 could be assigned to Berry's phase. The interpretation is straightforward: spacetime curvature effects can be greatly amplified by non-linear phase-locked feedback-loops adjusted to single-valued phase relationships in the quantum regime.

  16. Inequalities for scattering phase shifts

    International Nuclear Information System (INIS)

    Baumgartner, B.; Grosse, H.

    1985-01-01

    A recently developed method, which was used to derive bounds on energy levels, is applied to continuous spectra and gives relations between scattering phase shifts of various angular momenta. (Author)

  17. Berry phase in Heisenberg representation

    Science.gov (United States)

    Andreev, V. A.; Klimov, Andrei B.; Lerner, Peter B.

    1994-01-01

    We define the Berry phase for the Heisenberg operators. This definition is motivated by the calculation of the phase shifts by different techniques. These techniques are: the solution of the Heisenberg equations of motion, the solution of the Schrodinger equation in coherent-state representation, and the direct computation of the evolution operator. Our definition of the Berry phase in the Heisenberg representation is consistent with the underlying supersymmetry of the model in the following sense. The structural blocks of the Hamiltonians of supersymmetrical quantum mechanics ('superpairs') are connected by transformations which conserve the similarity in structure of the energy levels of superpairs. These transformations include transformation of phase of the creation-annihilation operators, which are generated by adiabatic cyclic evolution of the parameters of the system.

  18. Sustainable Water Purification, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Newly developed phase-engineered and low dimensional materials have opened the door to the design of materials structures that exhibit extremely efficient ionic...

  19. Phase holograms in polymethyl methacrylate

    Science.gov (United States)

    Maker, P. D.; Muller, R. E.

    1992-01-01

    A procedure is described for the fabrication of complex computer-generated phase holograms in polymethyl methacrylate (PMMA) by means of partial-exposure e-beam lithography and subsequent carefully controlled partial development. Following the development, the pattern appears (rendered in relief) in the PMMA, which then acts as the phase-delay medium. The devices fabricated were designed with 16 equal phase steps per retardation cycle, were up to 3 mm square, and consisted of up to 10 millions of 0.3-2.0-micron square pixels. Data files were up to 60 Mb-long, and the exposure times ranged to several hours. A Fresnel phase lens was fabricated with a diffraction-limited optical performance of 83-percent efficiency.

  20. High Performance Nanolauncher, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed Low Cost Nanolauncher (LCN) is an upper stage using a new, inexpensive propulsion system. The Phase I program will combine several technologies with a...

  1. SGA Phase 1 Assessed Reaches

    Data.gov (United States)

    Vermont Center for Geographic Information — The stream geomorphic assessment (SGA) is a physical assessment competed by geomorphologists to determine the condition and sensitivity of a stream. The Phase 1 SGA...

  2. Modern theories of phase transitions

    International Nuclear Information System (INIS)

    Rajaraman, R.

    1979-01-01

    Modern applications of the ideas of phase transitions to nuclear systems and the modern techniques as applied to familiar phase transitions in solid-state physics are discussed with illustrations. The phenomenon of pion condensation in nuclei and neutron stars, is presented as an example of phase transitions in nuclear systems. The central physical ideas behind this subject as well as techniques used to tackle it are broadly summarised. It is pointed out that unlike familiar examples of ferromagnetism or superconductivity, the order parameter here has spatial variation even in the ground state. Possible experimental consequences are discussed. As an example of the second category, the use of renormalisation group techniques in solid state physics is reviewed. The basic idea behind the renormalisation group in the infra-red (thermodynamic) limit is presented. The observed universality and scaling of critical exponents in second order phase transitions is explained in a model-independent way. (auth.)

  3. The density of cement phases

    International Nuclear Information System (INIS)

    Balonis, M.; Glasser, F.P.

    2009-01-01

    The densities of principal crystalline phases occurring in Portland cement are critically assessed and tabulated, in some cases with addition of new data. A reliable and self-consistent density set for crystalline phases was obtained by calculating densities from crystallographic data and unit cell contents. Independent laboratory work was undertaken to synthesize major AFm and AFt cement phases, determine their unit cell parameters and compare the results with those recorded in the literature. Parameters were refined from powder diffraction patterns using CELREF 2 software. A density value is presented for each phase, showing literature sources, in some cases describing limitations on the data, and the weighting attached to numerical values where an averaging process was used for accepted data. A brief discussion is made of the consequences of the packing of water to density changes in AFm and AFt structures.

  4. Strong coupling phase in QED

    International Nuclear Information System (INIS)

    Aoki, Ken-ichi

    1988-01-01

    Existence of a strong coupling phase in QED has been suggested in solutions of the Schwinger-Dyson equation and in Monte Carlo simulation of lattice QED. In this article we recapitulate the previous arguments, and formulate the problem in the modern framework of the renormalization theory, Wilsonian renormalization. This scheme of renormalization gives the best understanding of the basic structure of a field theory especially when it has a multi-phase structure. We resolve some misleading arguments in the previous literature. Then we set up a strategy to attack the strong phase, if any. We describe a trial; a coupled Schwinger-Dyson equation. Possible picture of the strong coupling phase QED is presented. (author)

  5. Licensee Performance Evaluation: Phase II

    International Nuclear Information System (INIS)

    Chakoff, H.E.; Speaker, D.M.; Thompson, S.R.; Cohen, S.C.

    1979-08-01

    This report details work performed during the second phase of a two-phase contract to develop methodology for Licensee Performance Evaluation. The Phase I report, NUREG/CR-0110 details initial efforts on the contract. The model developed in Phase I was used to evaluate nine additional facilities for this report. Performance indicators from noncompliance data were also evaluated. Methodology was developed employing the noncompliance indicators and used for 12 case studies. It was found that licensee event report indicators could be more easily identified and utilized than noncompliance indicators based on presently available data systems. However, noncompliance data, appropriately related to cause, could provide real insight into why performance was what it was

  6. Phase Coexistence in Insect Swarms

    Science.gov (United States)

    Sinhuber, Michael; Ouellette, Nicholas T.

    2017-10-01

    Animal aggregations are visually striking, and as such are popular examples of collective behavior in the natural world. Quantitatively demonstrating the collective nature of such groups, however, remains surprisingly difficult. Inspired by thermodynamics, we applied topological data analysis to laboratory insect swarms and found evidence for emergent, material-like states. We show that the swarms consist of a core "condensed" phase surrounded by a dilute "vapor" phase. These two phases coexist in equilibrium, and maintain their distinct macroscopic properties even though individual insects pass freely between them. We further define a pressure and chemical potential to describe these phases, extending theories of active matter to aggregations of macroscopic animals and laying the groundwork for a thermodynamic description of collective animal groups.

  7. Phasing multi-segment undulators

    International Nuclear Information System (INIS)

    Chavanne, J.; Elleaume, P.; Vaerenbergh, P. Van

    1996-01-01

    An important issue in the manufacture of multi-segment undulators as a source of synchrotron radiation or as a free-electron laser (FEL) is the phasing between successive segments. The state of the art is briefly reviewed, after which a novel pure permanent magnet phasing section that is passive and does not require any current is presented. The phasing section allows the introduction of a 6 mm longitudinal gap between each segment, resulting in complete mechanical independence and reduced magnetic interaction between segments. The tolerance of the longitudinal positioning of one segment with respect to the next is found to be 2.8 times lower than that of conventional phasing. The spectrum at all gaps and useful harmonics is almost unchanged when compared with a single-segment undulator of the same total length. (au) 3 refs

  8. Lunar Health Monitor, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — During the Phase II Lunar Health Monitor program, Orbital Research will develop a second generation wearable sensor suite for astronaut physiologic monitoring. The...

  9. High pressure phase transformations revisited.

    Science.gov (United States)

    Levitas, Valery I

    2018-04-25

    High pressure phase transformations play an important role in the search for new materials and material synthesis, as well as in geophysics. However, they are poorly characterized, and phase transformation pressure and pressure hysteresis vary drastically in experiments of different researchers, with different pressure transmitting media, and with different material suppliers. Here we review the current state, challenges in studying phase transformations under high pressure, and the possible ways in overcoming the challenges. This field is critically compared with fields of phase transformations under normal pressure in steels and shape memory alloys, as well as plastic deformation of materials. The main reason for the above mentioned discrepancy is the lack of understanding that there is a fundamental difference between pressure-induced transformations under hydrostatic conditions, stress-induced transformations under nonhydrostatic conditions below yield, and strain-induced transformations during plastic flow. Each of these types of transformations has different mechanisms and requires a completely different thermodynamic and kinetic description and experimental characterization. In comparison with other fields the following challenges are indicated for high pressure phase transformation: (a) initial and evolving microstructure is not included in characterization of transformations; (b) continuum theory is poorly developed; (c) heterogeneous stress and strain fields in experiments are not determined, which leads to confusing material transformational properties with a system behavior. Some ways to advance the field of high pressure phase transformations are suggested. The key points are: (a) to take into account plastic deformations and microstructure evolution during transformations; (b) to formulate phase transformation criteria and kinetic equations in terms of stress and plastic strain tensors (instead of pressure alone); (c) to develop multiscale continuum

  10. High pressure phase transformations revisited

    Science.gov (United States)

    Levitas, Valery I.

    2018-04-01

    High pressure phase transformations play an important role in the search for new materials and material synthesis, as well as in geophysics. However, they are poorly characterized, and phase transformation pressure and pressure hysteresis vary drastically in experiments of different researchers, with different pressure transmitting media, and with different material suppliers. Here we review the current state, challenges in studying phase transformations under high pressure, and the possible ways in overcoming the challenges. This field is critically compared with fields of phase transformations under normal pressure in steels and shape memory alloys, as well as plastic deformation of materials. The main reason for the above mentioned discrepancy is the lack of understanding that there is a fundamental difference between pressure-induced transformations under hydrostatic conditions, stress-induced transformations under nonhydrostatic conditions below yield, and strain-induced transformations during plastic flow. Each of these types of transformations has different mechanisms and requires a completely different thermodynamic and kinetic description and experimental characterization. In comparison with other fields the following challenges are indicated for high pressure phase transformation: (a) initial and evolving microstructure is not included in characterization of transformations; (b) continuum theory is poorly developed; (c) heterogeneous stress and strain fields in experiments are not determined, which leads to confusing material transformational properties with a system behavior. Some ways to advance the field of high pressure phase transformations are suggested. The key points are: (a) to take into account plastic deformations and microstructure evolution during transformations; (b) to formulate phase transformation criteria and kinetic equations in terms of stress and plastic strain tensors (instead of pressure alone); (c) to develop multiscale continuum

  11. Novel Quantum Phases at Interfaces

    Science.gov (United States)

    2014-12-12

    defined quasiparticle and the system cannot be adequately described by an electronic band structure. The chief theoretical challenges for the study of...electronic quasiparticle weight is proportional to the expectation value of the rotor field. The resulting theory typically has two dis- tinct stable phases...band structure is well defined, while in the strongly interacting phase the quasiparticle weight vanishes due to strong rotor fluc- tuations

  12. Phase transitions in two dimensions

    International Nuclear Information System (INIS)

    Henderson, D.

    1980-01-01

    Although a two-dimensional solid with long-range translational order cannot existin the thermodynamic limit (N → ∞, V →∞, N/V finite) macroscopic samples of two-dimensional solids can exist. In this work, stability of the phase was determined by the usuar method of equating the pressure and chemical potential of the phases. (A.C.A.S.) [pt

  13. Glare Spot Phase Doppler Anemometry

    OpenAIRE

    Hespel, Camille; Ren, Kuan Fang; Gréhan, Gérard; Onofri, Fabrice

    2006-01-01

    International audience; The Phase Doppler anemometry has been developed to measure simultaneously the velocity and the size of droplets. The measurement of the refractive index is also necessary since it depends on the temperature and the composition of the particle and its measurement permits both to increase the quality of the diameter measurement and to obtain information on the temperature and/or the composition of the droplets. In this paper, we introduce a Glare Spot Phase Doppler Anemo...

  14. Quantum Optics in Phase Space

    Science.gov (United States)

    Schleich, Wolfgang P.

    2001-04-01

    Quantum Optics in Phase Space provides a concise introduction to the rapidly moving field of quantum optics from the point of view of phase space. Modern in style and didactically skillful, Quantum Optics in Phase Space prepares students for their own research by presenting detailed derivations, many illustrations and a large set of workable problems at the end of each chapter. Often, the theoretical treatments are accompanied by the corresponding experiments. An exhaustive list of references provides a guide to the literature. Quantum Optics in Phase Space also serves advanced researchers as a comprehensive reference book. Starting with an extensive review of the experiments that define quantum optics and a brief summary of the foundations of quantum mechanics the author Wolfgang P. Schleich illustrates the properties of quantum states with the help of the Wigner phase space distribution function. His description of waves ala WKB connects semi-classical phase space with the Berry phase. These semi-classical techniques provide deeper insight into the timely topics of wave packet dynamics, fractional revivals and the Talbot effect. Whereas the first half of the book deals with mechanical oscillators such as ions in a trap or atoms in a standing wave the second half addresses problems where the quantization of the radiation field is of importance. Such topics extensively discussed include optical interferometry, the atom-field interaction, quantum state preparation and measurement, entanglement, decoherence, the one-atom maser and atom optics in quantized light fields. Quantum Optics in Phase Space presents the subject of quantum optics as transparently as possible. Giving wide-ranging references, it enables students to study and solve problems with modern scientific literature. The result is a remarkably concise yet comprehensive and accessible text- and reference book - an inspiring source of information and insight for students, teachers and researchers alike.

  15. Modulational instability of nematic phase

    Indian Academy of Sciences (India)

    2014-02-08

    Feb 8, 2014 ... all phases show MI, but at the same time it has also been found that for antiferro- magnetic phase, MI depends on the relative .... with wave functions, time and spatial coordinates are measured in the units of. (¯h/2mωz)−3/2, ω−1 ... The manipulation of the resulting matrix gives eigenvalues. From the form of ...

  16. Phase transitions in nuclear matter

    International Nuclear Information System (INIS)

    Glendenning, N.K.

    1984-11-01

    The rather general circumstances under which a phase transition in hadronic matter at finite temperature to an abnormal phase in which baryon effective masses become small and in which copious baryon-antibaryon pairs appear is emphasized. A preview is also given of a soliton model of dense matter, in which at a density of about seven times nuclear density, matter ceases to be a color insulator and becomes increasingly color conducting. 22 references

  17. Describing phase coexistence in systems with small phases

    International Nuclear Information System (INIS)

    Lovett, R

    2007-01-01

    Clusters of atoms can be studied in molecular beams and by computer simulation; 'liquid drops' provide elementary models for atomic nuclei and for the critical nuclei of nucleation theory. These clusters are often described in thermodynamic terms, but the behaviour of small clusters near a phase boundary is qualitatively different from the behaviour at a first order phase transition in idealized thermodynamics. In the idealized case the density and entropy show mathematically sharp discontinuities when the phase boundary is crossed. In large, but finite, systems, the phase boundaries become regions of state space wherein these properties vary rapidly but continuously. In small clusters with a large surface/volume ratio, however, the positive interfacial free energy makes it unlikely, even in states on phase boundaries, that a cluster will have a heterogeneous structure. What is actually seen in these states is a structure that fluctuates in time between homogeneous structures characteristic of the two sides of the phase boundary. That is, structural fluctuations are observed. Thermodynamics only predicts average properties; statistical mechanics is required to understand these fluctuations. Failure to distinguish thermodynamic properties and characterizations of fluctuations, particularly in the context of first order phase transitions, has led to suggestions that the classical rules for thermodynamic stability are violated in small systems and that classical thermodynamics provides an inconsistent description of these systems. Much of the confusion stems from taking statistical mechanical identifications of thermodynamic properties, explicitly developed for large systems, and applying them uncritically to small systems. There are no inconsistencies if thermodynamic properties are correctly identified and the distinction between thermodynamic properties and fluctuations is made clear

  18. Phase gradients in acceleration structures

    International Nuclear Information System (INIS)

    Decker, F.J.; Jobe, R.K.

    1990-05-01

    In linear accelerators with two or more bunches the beam loading of one bunch will influence the energy and energy spread the following bunches. This can be corrected by quickly changing the phase of a travelling wave structure, so that each bunch recieves a slightly different net phase. At the SLAC Linear Collider (SLC) three bunches, two (e + ,e - ) for the high energy collisions and one (e - -scavenger) for producing positrons should sit at different phases, due to their different tasks. The two e - -bunches are extracted from the damping ring at the same cycle time about 60 ns apart. Fast phase switching of the RF to the bunch length compressor in the Ring-To-Linac (RTL) section can produce the necessary advance of the scavenger bunch (about 6 degree in phase). This allows a low energy spread of this third bunch at the e + -production region at 2/3 of the linac length, while the other bunches are not influenced. The principles and possible other applications of this fast phase switching as using it for multi-bunches, as well as the experimental layout for the actual RTL compressor are presented

  19. Quantum disentanglement and phase measurements

    International Nuclear Information System (INIS)

    Buzek, V.; Hillery, M.

    1995-01-01

    A 50:50 beam splitter disentangles a two-mode squeezed vacuum state into two single-mode squeezed vacuum states. With the proper choice of parameters these two single-mode states will be identical. If one is passed through a device which shifts its phase, then the phases of the shifted and reference (unshifted) modes can be determined by the Vogel-Schleich technique. In this way the phase difference, i.e. the phase shift, can be measured to an accuracy of 1/N, where N is the total number of photons coming into the beam splitter. An improved scheme is also proposed involving the disentanglement of a shifted two-mode squeezed vacuum state. This leads to two shifted squeezed vacuum states at the output of the beam splitter. If one of these is passed through the phase shifter, then by performing homodyne measurements on the shifted and unshifted modes the phase shift can again be determined to an accuracy of 1/N. (author) 4 figs., 14 refs

  20. Phases and phase transitions in the algebraic microscopic shell model

    Directory of Open Access Journals (Sweden)

    Georgieva A. I.

    2016-01-01

    Full Text Available We explore the dynamical symmetries of the shell model number conserving algebra, which define three types of pairing and quadrupole phases, with the aim to obtain the prevailing phase or phase transition for the real nuclear systems in a single shell. This is achieved by establishing a correspondence between each of the pairing bases with the Elliott’s SU(3 basis that describes collective rotation of nuclear systems. This allows for a complete classification of the basis states of different number of particles in all the limiting cases. The probability distribution of the SU(3 basis states within theirs corresponding pairing states is also obtained. The relative strengths of dynamically symmetric quadrupole-quadrupole interaction in respect to the isoscalar, isovector and total pairing interactions define a control parameter, which estimates the importance of each term of the Hamiltonian in the correct reproduction of the experimental data for the considered nuclei.

  1. Glass phase expelling during liquid phase sintering of YSZ

    International Nuclear Information System (INIS)

    Souza, Milton Ferreira de; Souza, Dulcina Pinatti Ferreira de

    1998-01-01

    Expelling of the liquid phase during sintering of Zr O 2 -6.5 mol % Y 2 O 3 - 0.5 mol % Pr 2 O 3 ceramic was observed as a result of grain coarsening. ZrO 2 - 7.0 mol % Y 2 O 3 samples, without Pr 2 O 3 addition, do not show this effect under the same sintering conditions. The expelling process is caused by surface tension forces and attracting van der Waals forces between the grains, coupled with the existence of two glass phases on the grain boundaries. The amount of expelled glass phase increases with grain growth, but saturates above 16 μm average grain size. (author)

  2. Phase Difference Measurement Method Based on Progressive Phase Shift

    Directory of Open Access Journals (Sweden)

    Min Zhang

    2018-06-01

    Full Text Available This paper proposes a method for phase difference measurement based on the principle of progressive phase shift (PPS. A phase difference measurement system based on PPS and implemented in the FPGA chip is proposed and tested. In the realized system, a fully programmable delay line (PDL is constructed, which provides accurate and stable delay, benefitting from the feed-back structure of the control module. The control module calibrates the delay according to process, voltage and temperature (PVT variations. Furthermore, a modified method based on double PPS is incorporated to improve the resolution. The obtained resolution is 25 ps. Moreover, to improve the resolution, the proposed method is implemented on the 20 nm Xilinx Kintex Ultrascale platform, and test results indicate that the obtained measurement error and clock synchronization error is within the range of ±5 ps.

  3. Engineering Phase 2 and Phase 3 certification programs -- PUREX deactivation

    International Nuclear Information System (INIS)

    Walser, R.L.

    1994-01-01

    This document describes the training programs required to become a Phase 2 and Phase 3 certified engineer at PUREX during deactivation. With the change in mission, the PUREX engineering/certification training program is being revamped as discussed below. The revised program will be administered by PUREX Technical Training using existing courses and training materials. The program will comply with the requirements of the Department of Energy (DOE) order 5480.20A, ''Personnel Selection, Qualification, Training, and Staffing Requirements at DOE Reactor and Non-Reactor Nuclear Facilities.''

  4. Dynamic Modeling of Phase Crossings in Two-Phase Flow

    DEFF Research Database (Denmark)

    Madsen, Søren; Veje, Christian; Willatzen, Morten

    2012-01-01

    by a high resolution finite difference scheme due to Kurganov and Tadmore. The homogeneous formulation requires a set of thermodynamic relations to cover the entire range from liquid to gas state. This leads a number of numerical challenges since these relations introduce discontinuities in the derivative...... of the variables and are usually very slow to evaluate. To overcome these challenges, we use an interpolation scheme with local refinement. The simulations show that the method handles crossing of the saturation lines for both liquid to two-phase and two-phase to gas regions. Furthermore, a novel result obtained...

  5. Engineering Phase 2 and Phase 3 certification programs -- PUREX deactivation

    Energy Technology Data Exchange (ETDEWEB)

    Walser, R.L.

    1994-12-13

    This document describes the training programs required to become a Phase 2 and Phase 3 certified engineer at PUREX during deactivation. With the change in mission, the PUREX engineering/certification training program is being revamped as discussed below. The revised program will be administered by PUREX Technical Training using existing courses and training materials. The program will comply with the requirements of the Department of Energy (DOE) order 5480.20A, ``Personnel Selection, Qualification, Training, and Staffing Requirements at DOE Reactor and Non-Reactor Nuclear Facilities.``

  6. Phases definition in marketing export process

    OpenAIRE

    Rajković Dragan; Kokić Miljko

    2004-01-01

    The result of export marketing process depends on its five phases. The first phase-revision of export capacities, inner view on advantages and defects of company concerning export possibilities. The second phase-identification of export strategy market penetration. The forth phase-preparing for the marketing campaign (action). The fifth phase-carrying out the above mentioned activities. This study shows the structure and contents of the mentioned phases. At the end, export marketing analyzed ...

  7. Phases of cannibal dark matter

    Energy Technology Data Exchange (ETDEWEB)

    Farina, Marco [New High Energy Theory Center, Department of Physics, Rutgers University,136 Frelinghuisen Road, Piscataway, NJ 08854 (United States); Pappadopulo, Duccio; Ruderman, Joshua T.; Trevisan, Gabriele [Center for Cosmology and Particle Physics, Department of Physics, New York University,New York, NY 10003 (United States)

    2016-12-13

    A hidden sector with a mass gap undergoes an epoch of cannibalism if number changing interactions are active when the temperature drops below the mass of the lightest hidden particle. During cannibalism, the hidden sector temperature decreases only logarithmically with the scale factor. We consider the possibility that dark matter resides in a hidden sector that underwent cannibalism, and has relic density set by the freeze-out of two-to-two annihilations. We identify three novel phases, depending on the behavior of the hidden sector when dark matter freezes out. During the cannibal phase, dark matter annihilations decouple while the hidden sector is cannibalizing. During the chemical phase, only two-to-two interactions are active and the total number of hidden particles is conserved. During the one way phase, the dark matter annihilation products decay out of equilibrium, suppressing the production of dark matter from inverse annihilations. We map out the distinct phenomenology of each phase, which includes a boosted dark matter annihilation rate, new relativistic degrees of freedom, warm dark matter, and observable distortions to the spectrum of the cosmic microwave background.

  8. Parallel imaging with phase scrambling.

    Science.gov (United States)

    Zaitsev, Maxim; Schultz, Gerrit; Hennig, Juergen; Gruetter, Rolf; Gallichan, Daniel

    2015-04-01

    Most existing methods for accelerated parallel imaging in MRI require additional data, which are used to derive information about the sensitivity profile of each radiofrequency (RF) channel. In this work, a method is presented to avoid the acquisition of separate coil calibration data for accelerated Cartesian trajectories. Quadratic phase is imparted to the image to spread the signals in k-space (aka phase scrambling). By rewriting the Fourier transform as a convolution operation, a window can be introduced to the convolved chirp function, allowing a low-resolution image to be reconstructed from phase-scrambled data without prominent aliasing. This image (for each RF channel) can be used to derive coil sensitivities to drive existing parallel imaging techniques. As a proof of concept, the quadratic phase was applied by introducing an offset to the x(2) - y(2) shim and the data were reconstructed using adapted versions of the image space-based sensitivity encoding and GeneRalized Autocalibrating Partially Parallel Acquisitions algorithms. The method is demonstrated in a phantom (1 × 2, 1 × 3, and 2 × 2 acceleration) and in vivo (2 × 2 acceleration) using a 3D gradient echo acquisition. Phase scrambling can be used to perform parallel imaging acceleration without acquisition of separate coil calibration data, demonstrated here for a 3D-Cartesian trajectory. Further research is required to prove the applicability to other 2D and 3D sampling schemes. © 2014 Wiley Periodicals, Inc.

  9. An opsin shift in rhodopsin: retinal S0-S1 excitation in protein, in solution, and in the gas phase.

    Science.gov (United States)

    Bravaya, Ksenia; Bochenkova, Anastasia; Granovsky, Alexander; Nemukhin, Alexander

    2007-10-31

    We considered a series of model systems for treating the photoabsorption of the 11-cis retinal chromophore in the protonated Schiff-base form in vacuum, solutions, and the protein environment. A high computational level, including the quantum mechanical-molecular mechanical (QM/MM) approach for solution and protein was utilized in simulations. The S0-S1 excitation energies in quantum subsystems were evaluated by means of an augmented version of the multiconfigurational quasidegenerate perturbation theory (aug-MCQDPT2) with the ground-state geometry parameters optimized in the density functional theory PBE0/cc-pVDZ approximation. The computed positions of absorption bands lambdamax, 599(g), 448(s), and 515(p) nm for the gas phase, solution, and protein, respectively, are in excellent agreement with the corresponding experimental data, 610(g), 445(s), and 500(p) nm. Such consistency provides a support for the formulated qualitative conclusions on the role of the chromophore geometry, environmental electrostatic field, and the counterion in different media. An essentially nonplanar geometry conformation of the chromophore group in the region of the C14-C15 bond was obtained for the protein, in particular, owing to the presence of the neighboring charged amino acid residue Glu181. Nonplanarity of the C14-C15 bond region along with the influence of the negatively charged counterions Glu181 and Glu113 are found to be important to reproduce the spectroscopic features of retinal chromophore inside the Rh cavity. Furthermore, the protein field is responsible for the largest bond-order decrease at the C11-C12 double bond upon excitation, which may be the reason for the 11-cis photoisomerization specificity.

  10. Phase diagram of ammonium nitrate

    International Nuclear Information System (INIS)

    Dunuwille, Mihindra; Yoo, Choong-Shik

    2013-01-01

    Ammonium Nitrate (AN) is a fertilizer, yet becomes an explosive upon a small addition of chemical impurities. The origin of enhanced chemical sensitivity in impure AN (or AN mixtures) is not well understood, posing significant safety issues in using AN even today. To remedy the situation, we have carried out an extensive study to investigate the phase stability of AN and its mixtures with hexane (ANFO–AN mixed with fuel oil) and Aluminum (Ammonal) at high pressures and temperatures, using diamond anvil cells (DAC) and micro-Raman spectroscopy. The results indicate that pure AN decomposes to N 2 , N 2 O, and H 2 O at the onset of the melt, whereas the mixtures, ANFO and Ammonal, decompose at substantially lower temperatures. The present results also confirm the recently proposed phase IV-IV ′ transition above 17 GPa and provide new constraints for the melting and phase diagram of AN to 40 GPa and 400°C

  11. CERN openlab enters fifth phase

    CERN Multimedia

    Andrew Purcell

    2015-01-01

    CERN openlab is a unique public-private partnership between CERN and leading ICT companies. At the start of this year, openlab officially entered its fifth phase, which will run until the end of 2017. For the first time in its history, it has extended beyond the CERN community to include other major European and international research laboratories.   Founded in 2001 to develop the innovative ICT systems needed to cope with the unprecedented computing challenges of the LHC, CERN openlab unites science and industry at the cutting edge of research and innovation. In a white paper published last year, CERN openlab set out the main ICT challenges it will tackle during its fifth phase, namely data acquisition, computing platforms, data storage architectures, computer management and provisioning, networks and connectivity, and data analytics. As it enters its fifth phase, CERN openlab is expanding to include other research laboratories. "Today, research centres in other disciplines are also st...

  12. On photonic controlled phase gates

    International Nuclear Information System (INIS)

    Kieling, K; Eisert, J; O'Brien, J L

    2010-01-01

    As primitives for entanglement generation, controlled phase gates have a central role in quantum computing. Especially in ideas realizing instances of quantum computation in linear optical gate arrays, a closer look can be rewarding. In such architectures, all effective nonlinearities are induced by measurements. Hence the probability of success is a crucial parameter of such quantum gates. In this paper, we discuss this question for controlled phase gates that implement an arbitrary phase with one and two control qubits. Within the class of post-selected gates in dual-rail encoding with vacuum ancillas, we identify the optimal success probabilities. We construct networks that allow for implementation using current experimental capabilities in detail. The methods employed here appear specifically useful with the advent of integrated linear optical circuits, providing stable interferometers on monolithic structures.

  13. First order electroweak phase transition

    International Nuclear Information System (INIS)

    Buchmueller, W.; Fodor, Z.

    1993-01-01

    In this work, the authors have studied the phase transition in the SU(2)gauge theory at finite temperature. The authors' improved perturbative approach does not suffer from the infrared problems appearing in the ordinary loop expansion. The authors have calculated the effective potential up to cubic terms in the couplings. The higher order terms suggest that the method is reliable for Higgs masses smaller than 80 GeV. The authors have obtained a non-vanishing magnetic mass which further weakens the transitions. By use of Langer's theory of metastability, the authors have calculated the nucleation rate for critical bubbles and have discussed some cosmological consequences. For m H <80 GeV the phase transition is first order and proceeds via bubble nucleation and growth. The thin wall approximation is only marginally applicable. Since the phase transition is quite weak SM baryogenesis is unlikely. 8 refs., 5 figs

  14. Measurement of Phase Dependent Impedance for 3-phase Diode Rectifier

    DEFF Research Database (Denmark)

    Kwon, Jun Bum; Wang, Xiongfei; Bak, Claus Leth

    2016-01-01

    This paper presents a new method to measure the phase dependent impedance from an experimental set up. Though most of power electronics based system is gradually migrating to IGBT based voltage source converter due to their controllability, the rectifier composed of diode or thyristor components...

  15. Phase development and kinetics of high temperature Bi-2223 phase

    International Nuclear Information System (INIS)

    Yavuz, M.; Maeda, H.; Hua, K.L.; Shi, X.D.

    1998-01-01

    The two-dimensional nucleation (random)-growth mechanism were observed as a support for the related previous works, which is attributable to the growth of the Bi-2223 grain in the a-b plane direction of the Bi-2212 matrix is being much faster than in the c-direction, or that the early-formed plate-like 2212 phase confines the 2223 product. At the beginning of the reaction, the additional phases are partially melted. Because of the structure, composition and thermal fluctuation, the 2223 nucleates and grows in the phase boundary between the liquid phase and Bi-2212. It was shown here that the nucleation and the growth rate were relatively fast between 0 and 36 h. At the final stage, between 36 and 60 h, because of the impingement of the growth fronts of different nuclei, the high formation rate of 2223 is suppressed. The major reactant 2212 remains as a solid and its plate-like configuration determines the two dimensional nature of the reaction. The amount of liquid forms during reaction is small. (orig.)

  16. Scrutinizing the pion condensed phase

    Energy Technology Data Exchange (ETDEWEB)

    Carignano, Stefano; Mammarella, Andrea; Mannarelli, Massimo [INFN, Laboratori Nazionali del Gran Sasso, Assergi (Italy); Lepori, Luca [Universita di Padova, Dipartimento di Fisica e Astronomia, Padova (Italy); Universita dell' Aquila, Dipartimento di Scienze Fisiche e Chimiche, Coppito-L' Aquila (Italy); Pagliaroli, Giulia [INFN, Laboratori Nazionali del Gran Sasso, Assergi (Italy); Gran Sasso Science Institute, L' Aquila (Italy)

    2017-02-15

    When the isospin chemical potential exceeds the pion mass, charged pions condense in the zero-momentum state forming a superfluid. Chiral perturbation theory provides a very powerful tool for studying this phase. However, the formalism that is usually employed in this context does not clarify various aspects of the condensation mechanism and makes the identification of the soft modes problematic. We re-examine the pion condensed phase using different approaches within the chiral perturbation theory framework. As a first step, we perform a low-density expansion of the chiral Lagrangian valid close to the onset of the Bose-Einstein condensation. We obtain an effective theory that can be mapped to a Gross-Pitaevskii Lagrangian in which, remarkably, all the coefficients depend on the isospin chemical potential. The low-density expansion becomes unreliable deep in the pion condensed phase. For this reason, we develop an alternative field expansion deriving a low-energy Lagrangian analog to that of quantum magnets. By integrating out the ''radial'' fluctuations we obtain a soft Lagrangian in terms of the Nambu-Goldstone bosons arising from the breaking of the pion number symmetry. Finally, we test the robustness of the second-order transition between the normal and the pion condensed phase when next-to-leading-order chiral corrections are included. We determine the range of parameters for turning the second-order phase transition into a first-order one, finding that the currently accepted values of these corrections are unlikely to change the order of the phase transition. (orig.)

  17. Moving walls and geometric phases

    Energy Technology Data Exchange (ETDEWEB)

    Facchi, Paolo, E-mail: paolo.facchi@ba.infn.it [Dipartimento di Fisica and MECENAS, Università di Bari, I-70126 Bari (Italy); INFN, Sezione di Bari, I-70126 Bari (Italy); Garnero, Giancarlo, E-mail: giancarlo.garnero@uniba.it [Dipartimento di Fisica and MECENAS, Università di Bari, I-70126 Bari (Italy); INFN, Sezione di Bari, I-70126 Bari (Italy); Marmo, Giuseppe [Dipartimento di Scienze Fisiche and MECENAS, Università di Napoli “Federico II”, I-80126 Napoli (Italy); INFN, Sezione di Napoli, I-80126 Napoli (Italy); Samuel, Joseph [Raman Research Institute, 560080 Bangalore (India)

    2016-09-15

    We unveil the existence of a non-trivial Berry phase associated to the dynamics of a quantum particle in a one dimensional box with moving walls. It is shown that a suitable choice of boundary conditions has to be made in order to preserve unitarity. For these boundary conditions we compute explicitly the geometric phase two-form on the parameter space. The unboundedness of the Hamiltonian describing the system leads to a natural prescription of renormalization for divergent contributions arising from the boundary.

  18. Phase diagrams for surface alloys

    DEFF Research Database (Denmark)

    Christensen, Asbjørn; Ruban, Andrei; Stoltze, Per

    1997-01-01

    We discuss surface alloy phases and their stability based on surface phase diagrams constructed from the surface energy as a function of the surface composition. We show that in the simplest cases of pseudomorphic overlayers there are four generic classes of systems, characterized by the sign...... is based on density-functional calculations using the coherent-potential approximation and on effective-medium theory. We give self-consistent density-functional results for the segregation energy and surface mixing energy for all combinations of the transition and noble metals. Finally we discuss...

  19. Phase transitions in dense matter

    Science.gov (United States)

    Dexheimer, Veronica; Hempel, Matthias; Iosilevskiy, Igor; Schramm, Stefan

    2017-11-01

    As the density of matter increases, atomic nuclei disintegrate into nucleons and, eventually, the nucleons themselves disintegrate into quarks. The phase transitions (PT's) between these phases can vary from steep first order to smooth crossovers, depending on certain conditions. First-order PT's with more than one globally conserved charge, so-called non-congruent PT's, have characteristic differences compared to congruent PT's. In this conference proceeding we discuss the non-congruence of the quark deconfinement PT at high densities and/or temperatures relevant for heavy-ion collisions, neutron stars, proto-neutron stars, supernova explosions, and compact-star mergers.

  20. Solid-phase peptide synthesis

    DEFF Research Database (Denmark)

    Jensen, Knud Jørgen

    2013-01-01

    This chapter provides an introduction to and overview of peptide chemistry with a focus on solid-phase peptide synthesis. The background, the most common reagents, and some mechanisms are presented. This chapter also points to the different chapters and puts them into perspective.......This chapter provides an introduction to and overview of peptide chemistry with a focus on solid-phase peptide synthesis. The background, the most common reagents, and some mechanisms are presented. This chapter also points to the different chapters and puts them into perspective....

  1. Phase out of incandescent lamps

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    Since early 2007 almost all OECD and many non-OECD governments have announced policies aimed at phasing-out incandescent lighting within their jurisdictions. This study considers the implications of these policy developments in terms of demand for regulatory compliant lamps and the capacity and motivation of the lamp industry to produce efficient lighting products in sufficient volume to meet future demand. To assess these issues, it reviews the historic international screw-based lamp market, describes the status of international phase-out policies and presents projections of anticipated market responses to regulatory requirements to determine future demand for CFLs.

  2. Beam phase space and emittance

    International Nuclear Information System (INIS)

    Buon, J.

    1992-02-01

    The classical and elementary results for canonical phase space, the Liouville theorem and the beam emittance are reviewed. Then, the importance of phase portraits to obtain a geometrical description of motion is emphasized, with examples in accelerator physics. Finally, a statistical point of view is used to define beam emittance, to study its law of approximate conservation, with three particular examples, and to introduce a beam envelope-ellipse and the β-function, emphasing the statistical features of its properties. (author) 14 refs.; 11 figs

  3. Hydrodynamics and phases of flocks

    International Nuclear Information System (INIS)

    Toner, John; Tu Yuhai; Ramaswamy, Sriram

    2005-01-01

    We review the past decade's theoretical and experimental studies of flocking: the collective, coherent motion of large numbers of self-propelled 'particles' (usually, but not always, living organisms). Like equilibrium condensed matter systems, flocks exhibit distinct 'phases' which can be classified by their symmetries. Indeed, the phases that have been theoretically studied to date each have exactly the same symmetry as some equilibrium phase (e.g., ferromagnets, liquid crystals). This analogy with equilibrium phases of matter continues in that all flocks in the same phase, regardless of their constituents, have the same 'hydrodynamic'-that is, long-length scale and long-time behavior, just as, e.g., all equilibrium fluids are described by the Navier-Stokes equations. Flocks are nonetheless very different from equilibrium systems, due to the intrinsically nonequilibrium self-propulsion of the constituent 'organisms'. This difference between flocks and equilibrium systems is most dramatically manifested in the ability of the simplest phase of a flock, in which all the organisms are, on average moving in the same direction (we call this a 'ferromagnetic' flock; we also use the terms 'vector-ordered' and 'polar-ordered' for this situation) to exist even in two dimensions (i.e., creatures moving on a plane), in defiance of the well-known Mermin-Wagner theorem of equilibrium statistical mechanics, which states that a continuous symmetry (in this case, rotation invariance, or the ability of the flock to fly in any direction) can not be spontaneously broken in a two-dimensional system with only short-ranged interactions. The 'nematic' phase of flocks, in which all the creatures move preferentially, or are simply oriented preferentially, along the same axis, but with equal probability of moving in either direction, also differs dramatically from its equilibrium counterpart (in this case, nematic liquid crystals). Specifically, it shows enormous number fluctuations, which

  4. Small Business Innovation Research GRC Phase I, Phase II, and Post-Phase II Opportunity Assessment for 2015

    Science.gov (United States)

    Nguyen, Hung D.; Steele, Gynelle C.

    2016-01-01

    This report outlines the 2015 Small Business Innovation Research/Small Business Technology Transfer (SBIR/STTR) Phase I, Phase II, and Post-Phase II opportunity contract award results associated with NASA's Aeronautics Research Mission Directorate (ARMD), Human Exploration and Operations Mission Directorate (HEOMD), Science Mission Directorate (SMD), and Space Technology Mission Directorate (STMD) for NASA Glenn Research Center. The report also highlights the number of Phase I, Phase II, and Post-Phase II contracts awarded by mission directorate. The 2015 Phase I contract awards to companies in Ohio and their corresponding technologies are also discussed.

  5. Entropy-driven phase transitions

    NARCIS (Netherlands)

    Frenkel, D.

    1999-01-01

    Increase in visible order can be associated with an increase in microscopic disorder. This phenomenon leads to many counter-intuitive phenomena such as entropy driven crystallization and phase separation. I devote special attention to the entropic depletion interaction as a means to tune the range

  6. Ring diagrams and phase transitions

    International Nuclear Information System (INIS)

    Takahashi, K.

    1986-01-01

    Ring diagrams at finite temperatures carry most infrared-singular parts among Feynman diagrams. Their effect to effective potentials are in general so significant that one must incorporate them as well as 1-loop diagrams. The author expresses these circumstances in some examples of supercooled phase transitions

  7. Phase-quantum tunnel device

    International Nuclear Information System (INIS)

    Sugahara, M.; Ando, N.; Kaneda, H.; Nagai, M.; Ogawa, Y.; Yoshikawa, N.

    1985-01-01

    Theoretical and Experimental study on granular superconductors shows that they are classified into two groups; fixed-phase superconductor (theta-superconductor) and fixed-pair-number superconductor (N-superconductor) and that a new macroscopic quantum device with conjugate property to Josephson effect can be made by use of N-superconductors

  8. Phenomenology of cosmic phase transitions

    International Nuclear Information System (INIS)

    Kaempfer, B.; Lukacs, B.; Paal, G.

    1989-11-01

    The evolution of the cosmic matter from Planck temperature to the atomic combination temperature is considered from a phenomenological point of view. Particular emphasis is devoted to the sequence of cosmic phase transitions. The inflationary era at the temperature of the order of the grand unification energy scale and the quantum chromodynamic confinement transition are dealt with in detail. (author) 131 refs.; 26 figs

  9. Phase space quark counting rule

    International Nuclear Information System (INIS)

    Wei-gin, C.; Lo, S.

    1980-01-01

    A simple quark counting rule based on phase space consideration suggested before is used to fit all 39 recent experimental data points on inclusive reactions. Parameter free relations are found to agree with experiments. Excellent detail fits are obtained for 11 inclusive reactions

  10. Status of Gerda Phase II

    Energy Technology Data Exchange (ETDEWEB)

    Wagner, Victoria [Max-Planck-Institut fuer Kernphysik, Heidelberg (Germany); Collaboration: GERDA-Collaboration

    2016-07-01

    The GERDA experiment is designed to search for neutrinoless double beta (0νββ) decay of {sup 76}Ge. In Phase I of the experiment a background index (BI) of 10{sup -2} cts/(keV.kg.yr) was reached. No signal has been found and a lower limit on the half-life of 2.1.10{sup 25} yr (at 90% C.L.) is extracted. The aim of Phase II is to double the Ge mass and further reduce the BI by an order of magnitude to explore half-lives of about 10{sup 26} yr. Thirty new Broad Energy Germanium (BEGe) detectors have been produced. These detectors are distinct for their improved energy resolution and enhanced pulse shape discrimination of signal from background events. Further background reduction will be reached by an active veto to read out argon scintillation light. The Phase II commissioning showed that two of the major background components, external γ-rays from {sup 214}Bi and {sup 208}Tl decays, can be suppressed up to two orders of magnitude. This talk presents the current status of the GERDA Phase II upgrade.

  11. Super-resolution Phase Tomography

    KAUST Repository

    Depeursinge, Christian; Cotte, Yann; Toy, Fatih; Jourdain, Pascal; Boss, Daiel; Marquet, Pierre; Magistretti, Pierre J.

    2013-01-01

    Digital Holographic Microscopy (DHM) yields reconstructed complex wavefields. It allows synthesizing the aperture of a virtual microscope up to 2π, offering super-resolution phase images. Live images of micro-organisms and neurons with resolution less than 100 nm are presented.

  12. Quantum Shuttle in Phase Space

    DEFF Research Database (Denmark)

    Novotny, Tomas; Donarini, Andrea; Jauho, Antti-Pekka

    2003-01-01

    Abstract: We present a quantum theory of the shuttle instability in electronic transport through a nanostructure with a mechanical degree of freedom. A phase space formulation in terms of the Wigner function allows us to identify a crossover from the tunneling to the shuttling regime, thus...

  13. Phase transitions in finite systems

    Energy Technology Data Exchange (ETDEWEB)

    Chomaz, Ph. [Grand Accelerateur National d' Ions Lourds (GANIL), DSM-CEA / IN2P3-CNRS, 14 - Caen (France); Gulminelli, F. [Caen Univ., 14 (France). Lab. de Physique Corpusculaire

    2002-07-01

    In this series of lectures we will first review the general theory of phase transition in the framework of information theory and briefly address some of the well known mean field solutions of three dimensional problems. The theory of phase transitions in finite systems will then be discussed, with a special emphasis to the conceptual problems linked to a thermodynamical description for small, short-lived, open systems as metal clusters and data samples coming from nuclear collisions. The concept of negative heat capacity developed in the early seventies in the context of self-gravitating systems will be reinterpreted in the general framework of convexity anomalies of thermo-statistical potentials. The connection with the distribution of the order parameter will lead us to a definition of first order phase transitions in finite systems based on topology anomalies of the event distribution in the space of observations. Finally a careful study of the thermodynamical limit will provide a bridge with the standard theory of phase transitions and show that in a wide class of physical situations the different statistical ensembles are irreducibly inequivalent. (authors)

  14. Local coexistance of different phases

    International Nuclear Information System (INIS)

    Narnhofer, H.

    1982-01-01

    Under intuitively reasonable assumptions it is shown that in two dimensions different phases cannot exist locally. In three dimensions we discuss the possibility of local coexistance of districts with different magnetization for the Heisenberg ferromagnet and show that an interaction that breaks rotational invariance is necessary for this phenomenon. (Author)

  15. GPC and quantitative phase imaging

    DEFF Research Database (Denmark)

    Palima, Darwin; Banas, Andrew Rafael; Villangca, Mark Jayson

    2016-01-01

    shaper followed by the potential of GPC for biomedical and multispectral applications where we experimentally demonstrate the active light shaping of a supercontinuum laser over most of the visible wavelength range. Finally, we discuss how GPC can be advantageously applied for Quantitative Phase Imaging...

  16. PHARUS : PHased ARray Universal SAR

    NARCIS (Netherlands)

    Paquay, M.H.A.; Vermeulen, B.C.B.; Koomen, P.J.; Hoogeboom, P.; Snoeij, P.; Pouwels, H.

    1996-01-01

    In the Netherlands, a polarimetric C-band aircraft SAR (Synthetic Aperture Radar) has been developed. The project is called PHARUS, an acronm for PHased ARray Universal SAR. This instrument serves remote sensing applications. The antenna system contains 48 active modules (expandable to 96). A module

  17. Driven Phases of Quantum Matter

    Science.gov (United States)

    Khemani, Vedika; von Keyserlingk, Curt; Lazarides, Achilleas; Moessner, Roderich; Sondhi, Shivaji

    Clean and interacting periodically driven quantum systems are believed to exhibit a single, trivial ``infinite-temperature'' Floquet-ergodic phase. By contrast, I will show that their disordered Floquet many-body localized counterparts can exhibit distinct ordered phases with spontaneously broken symmetries delineated by sharp transitions. Some of these are analogs of equilibrium states, while others are genuinely new to the Floquet setting. I will show that a subset of these novel phases are absolutely stableto all weak local deformations of the underlying Floquet drives, and spontaneously break Hamiltonian dependent emergent symmetries. Strikingly, they simultaneously also break the underlying time-translation symmetry of the Floquet drive and the order parameter exhibits oscillations at multiples of the fundamental period. This ``time-crystallinity'' goes hand in hand with spatial symmetry breaking and, altogether, these phases exhibit a novel form of simultaneous long-range order in space and time. I will describe how this spatiotemporal order can be detected in experiments involving quenches from a broad class of initial states.

  18. Prediction of Chevrel superconducting phases

    International Nuclear Information System (INIS)

    Savitskij, E.M.; Kiseleva, N.N.

    1978-01-01

    Made is an attempt of predicting the possibility of formation of compounds of Mo 3 Se 4 type structure having critical temperatures of transition into superconducting state more than 4.2 K. Cybernetic method of teaching an electronic computer to form notions is used for prediction. Prediction system constructs logic dependence of forming Chevrel superconducting phase of the Asub(x)Bsub(6)Ssub(8) composition (A being an element of the periodic system; B=Cr, Mo, W, Re) and Asub(x)Bsub(6)Ssub(8) compounds having a critical temperature of more than 4.2 K on the properties of A and B elements. A conclusion is made that W, Re, Cr do not form Chevrel phases of the Asub(x)Bsub(6)Ssub(8) composition as B component. Be, Hg, Ra, B, Ac are the reserve for obtaining Asub(x)Mosub(6)Ssub(8) phases. Agsub(x)Mosub(6)Ssub(8) compound may have a high critical temperature. The ways of a critical temperature increase for Chevrel phases are connected with the search of optimal technological conditions for already known superconducting compounds and also with introduction of impurities fixing a distance between sulfur cubes

  19. Phase transitions in polymer monolayers

    NARCIS (Netherlands)

    Deschênes, Louise; Lyklema, J.; Danis, Claude; Saint-Germain, François

    2015-01-01

    In this paper we investigate the application of the two-dimensional Clapeyron law to polymer monolayers. This is a largely unexplored area of research. The main problems are (1) establishing if equilibrium is reached and (2) if so, identifying and defining phases as functions of the temperature.

  20. Multiple solid-phase microextraction

    NARCIS (Netherlands)

    Koster, EHM; de Jong, GJ

    2000-01-01

    Theoretical aspects of multiple solid-phase microextraction are described and the principle is illustrated with the extraction of lidocaine from aqueous solutions. With multiple extraction under non-equilibrium conditions considerably less time is required in order to obtain an extraction yield that

  1. New polymers for phase partitioning

    Science.gov (United States)

    Harris, J. M.

    1981-01-01

    The synthesizing of several polyethylene glycols having crown ethers attached is reported. This work led to the identification of three new polymer types which promise to be more effective at selectively binding specific cell types. Work was completed on identification of chemical properties of the new polymer crowns and on development of new techniques for determination of polymer-phase composition.

  2. Super-resolution Phase Tomography

    KAUST Repository

    Depeursinge, Christian

    2013-04-21

    Digital Holographic Microscopy (DHM) yields reconstructed complex wavefields. It allows synthesizing the aperture of a virtual microscope up to 2π, offering super-resolution phase images. Live images of micro-organisms and neurons with resolution less than 100 nm are presented.

  3. Crichton's phase-shift ambiguity

    NARCIS (Netherlands)

    Atkinson, D.; Johnson, P.W.; Mehta, N.; Roo, M. de

    1973-01-01

    A re-examination of the SPD phase-shift ambiguity is made with a view to understanding certain singular features of the elastic unitarity constraint. An explicit solution of Crichton's equations is presented, and certain features of this solution are displayed graphically. In particular, it is shown

  4. Phase transitions in light nuclei

    International Nuclear Information System (INIS)

    Dukelsky, J.; Poves, A.; Retamosa, J.

    1991-01-01

    The SU(3) Elliott model is used to study the thermal description of 20 Ne. This solvable model allows us to work in the canonical ensemble and still be able to define an order parameter, the expectation value of the intrinsic quadrupole moment, to investigate the occurrence of phase transitions

  5. Soliton bubbles and phase transformations

    International Nuclear Information System (INIS)

    Masperi, L.

    1989-01-01

    It is shown that no topological classical solutions in form of bubbles of a real scalar field theory with Lagrangian of quartet and sextet self interactions in 1+1 dimensions are responsible to discontinue transitions in the quantum problem between phases with degenerated and disordered excited level. (M.C.K.)

  6. Relativistic phase space: dimensional recurrences

    International Nuclear Information System (INIS)

    Delbourgo, R; Roberts, M L

    2003-01-01

    We derive recurrence relations between phase space expressions in different dimensions by confining some of the coordinates to tori or spheres of radius R and taking the limit as R→∞. These relations take the form of mass integrals, associated with extraneous momenta (relative to the lower dimension), and produce the result in the higher dimension

  7. Phase transitions in finite systems

    International Nuclear Information System (INIS)

    Chomaz, Ph.; Gulminelli, F.

    2002-01-01

    In this series of lectures we will first review the general theory of phase transition in the framework of information theory and briefly address some of the well known mean field solutions of three dimensional problems. The theory of phase transitions in finite systems will then be discussed, with a special emphasis to the conceptual problems linked to a thermodynamical description for small, short-lived, open systems as metal clusters and data samples coming from nuclear collisions. The concept of negative heat capacity developed in the early seventies in the context of self-gravitating systems will be reinterpreted in the general framework of convexity anomalies of thermo-statistical potentials. The connection with the distribution of the order parameter will lead us to a definition of first order phase transitions in finite systems based on topology anomalies of the event distribution in the space of observations. Finally a careful study of the thermodynamical limit will provide a bridge with the standard theory of phase transitions and show that in a wide class of physical situations the different statistical ensembles are irreducibly inequivalent. (authors)

  8. Liquid phase chromatography on microchips

    DEFF Research Database (Denmark)

    Kutter, Jörg Peter

    2012-01-01

    explosive development of, in particular, chromatographic separation systems on microchips, has, however, slowed down in recent years. This review takes a closer, critical look at how liquid phase chromatography has been implemented in miniaturized formats over the past several years, what is important...

  9. Optically Controlled Phased Array Antenna

    National Research Council Canada - National Science Library

    Garafalo, David

    1998-01-01

    .... The antenna is a 3-foot by 9 foot phased array capable of a scan angle of 120 degrees. The antenna was designed to be conformal to the cargo door of a large aircraft and is designed to operate in the frequency range of 830 - 1400 MHz with a 30...

  10. Geometric phases and quantum computation

    International Nuclear Information System (INIS)

    Vedral, V.

    2005-01-01

    Full text: In my lectures I will talk about the notion of the geometric phase and explain its relevance for both fundamental quantum mechanics as well as quantum computation. The phase will be at first introduced via the idea of Pancharatnam which involves interference of three or more light beams. This notion will then be generalized to the evolving quantum systems. I will discuss both pure and mixed states as well as unitary and non-unitary evolutions. I will also show how the concept of the vacuum induced geometric phase arises in quantum optics. A simple measurement scheme involving a Mach Zehnder interferometer will be presented and will be used to illustrate all the concepts in the lecture. Finally, I will expose a simple generalization of the geometric phase to evolving degenerate states. This will be seen to lead to the possibility of universal quantum computation using geometric effects only. Moreover, this contains a promise of intrinsically fault tolerant quantum information processing, whose prospects will be outlined at the end of the lecture. (author)

  11. Advances phase-lock techniques

    CERN Document Server

    Crawford, James A

    2008-01-01

    From cellphones to micrprocessors, to GPS navigation, phase-lock techniques are utilized in most all modern electronic devices. This high-level book takes a systems-level perspective, rather than circuit-level, which differentiates it from other books in the field.

  12. Product evaluation phase 1 report

    International Nuclear Information System (INIS)

    Kearsey, H.A.; Hornby, J.

    1984-01-01

    This report concerns the intermediate-level radioactive waste arisings from the reprocessing of irradiated nuclear fuel at BNFL Sellafield. Headings are: general introduction (origin of waste; current stocks and future arisings); characteristics of the waste stream; alternative matrices (for solidification of waste in form suitable for disposal); waste simulation; relevance of other Phase II studies. (U.K.)

  13. Nonclassicality in phase-number uncertainty relations

    International Nuclear Information System (INIS)

    Matia-Hernando, Paloma; Luis, Alfredo

    2011-01-01

    We show that there are nonclassical states with lesser joint fluctuations of phase and number than any classical state. This is rather paradoxical since one would expect classical coherent states to be always of minimum uncertainty. The same result is obtained when we replace phase by a phase-dependent field quadrature. Number and phase uncertainties are assessed using variance and Holevo relation.

  14. Nonclassicality in phase-number uncertainty relations

    Energy Technology Data Exchange (ETDEWEB)

    Matia-Hernando, Paloma; Luis, Alfredo [Departamento de Optica, Facultad de Ciencias Fisicas, Universidad Complutense, 28040 Madrid (Spain)

    2011-12-15

    We show that there are nonclassical states with lesser joint fluctuations of phase and number than any classical state. This is rather paradoxical since one would expect classical coherent states to be always of minimum uncertainty. The same result is obtained when we replace phase by a phase-dependent field quadrature. Number and phase uncertainties are assessed using variance and Holevo relation.

  15. Phase transformations im smart materials

    International Nuclear Information System (INIS)

    Newnham, R.E.

    1998-01-01

    One of the qualities that distinguishes living systems from inanimate matter is the ability to adapt to changes in the environment. Smart materials have the ability to perform both sensing and actuating functions and are, therefore, capable of imitating this rudimentary aspect of life. Four of the most widely used smart materials are piezoelectric Pb(Zr, Ti)O 3 , electrostrictive Pb(Mg, Nb)O 3 , magnetostrictive (Tb, Dy)Fe 2 and the shape-memory alloy NiTi. All four are ferroic with active domain walls and two phase transformations, which help to tune the properties of these actuator materials. Pb(Zr, Ti)O 3 is a ferroelectric ceramic which is cubic at high temperature and becomes ferroelectric on cooling through the Curie temperature. At room temperature, it is poised on a rhombohedral-tetragonal phase boundary which enhances the piezoelectric coefficients. Terfenol, (Tb, Dy)Fe 2 , is also cubic at high temperature and then becomes magnetic on cooling through its Curie temperature. At room temperature, it too is poised on a rhombohedral-tetragonal transition which enhances its magnetostriction coefficients. Pb(Mg, Nb)O 3 and nitinol (NiTi) are also cubic at high temperatures and on annealing transform to a partially ordered state. On further cooling, Pb(Mg, Nb)O 3 passes through a diffuse phase transformation at room temperature where it exhibits very large dielectric and electrostrictive coefficients. Just below room temperature, it transforms to a ferroelectric rhombohedral phase. The partially ordered shape-memory alloy NiTi undergoes an austenitic (cubic) to martensitic (mono-clinic) phase change just above room temperature. It is easily deformed in the martensitic state but recovers its original shape when reheated to austenite

  16. Phase transitions in solids under high pressure

    CERN Document Server

    Blank, Vladimir Davydovich

    2013-01-01

    Phase equilibria and kinetics of phase transformations under high pressureEquipment and methods for the study of phase transformations in solids at high pressuresPhase transformations of carbon and boron nitride at high pressure and deformation under pressurePhase transitions in Si and Ge at high pressure and deformation under pressurePolymorphic α-ω transformation in titanium, zirconium and zirconium-titanium alloys Phase transformations in iron and its alloys at high pressure Phase transformations in gallium and ceriumOn the possible polymorphic transformations in transition metals under pressurePressure-induced polymorphic transformations in АIBVII compoundsPhase transformations in AIIBVI and AIIIBV semiconductor compoundsEffect of pressure on the kinetics of phase transformations in iron alloysTransformations during deformation at high pressure Effects due to phase transformations at high pressureKinetics and hysteresis in high-temperature polymorphic transformations under pressureHysteresis and kineti...

  17. Phase transformations in intermetallic phases in zirconium alloys

    Energy Technology Data Exchange (ETDEWEB)

    Filippov, V. P., E-mail: vpfilippov@mephi.ru [National Research Nuclear University MEPhI (Moscow Engineering Physics Institute) (Russian Federation); Kirichenko, V. G. [Kharkiv National Karazin University (Ukraine); Salomasov, V. A. [National Research Nuclear University MEPhI (Moscow Engineering Physics Institute) (Russian Federation); Khasanov, A. M. [University of North Carolina – Asheville, Chemistry Department (United States)

    2017-11-15

    Phase change was analyzed in intermetallic compounds of zirconium alloys (Zr – 1.03 at.% Fe; Zr – 0.51 at.% Fe; Zr – 0.51 at.% Fe – M(M = Nb, Sn). Mössbauer spectroscopy on {sup 57}Fe nuclei in backscattering geometry with the registration of the internal conversion electrons and XRD were used. Four types of iron bearing intermetallic compounds with Nb were detected. A relationship was found between the growth process of intermetallic inclusions and segregation of these phases. The growth kinetics of inclusions possibly is not controlled by bulk diffusion, and a lower value of the iron atom’s activation energy of migration can be attributed to the existence of enhanced diffusion paths and interface boundaries.

  18. Phase-field modelling and synchrotron validation of phase transformations in martensitic dual-phase steel

    International Nuclear Information System (INIS)

    Thiessen, R.G.; Sietsma, J.; Palmer, T.A.; Elmer, J.W.; Richardson, I.M.

    2007-01-01

    A thermodynamically based method to describe the phase transformations during heating and cooling of martensitic dual-phase steel has been developed, and in situ synchrotron measurements of phase transformations have been undertaken to support the model experimentally. Nucleation routines are governed by a novel implementation of the classical nucleation theory in a general phase-field code. Physically-based expressions for the temperature-dependent interface mobility and the driving forces for transformation have also been constructed. Modelling of martensite was accomplished by assuming a carbon supersaturation of the body-centred-cubic ferrite lattice. The simulations predict kinetic aspects of the austenite formation during heating and ferrite formation upon cooling. Simulations of partial austenitising thermal cycles predicted peak and retained austenite percentages of 38.2% and 6.7%, respectively, while measurements yielded peak and retained austenite percentages of 31.0% and 7.2% (±1%). Simulations of a complete austenitisation thermal cycle predicted the measured complete austenitisation and, upon cooling, a retained austenite percentage of 10.3% while 9.8% (±1%) retained austenite was measured

  19. Phase noise reduction by self-phase locking in semiconductor lasers using phase conjugate feedback

    DEFF Research Database (Denmark)

    Petersen, Lykke; Gliese, Ulrik Bo; Nielsen, Torben Nørskov

    1994-01-01

    noise takes a finite-low value corresponding to a state of first-order self-phase locking of the laser. As a result, the spectral shape of the laser signal does not remain Lorentzian but collapses around the carrier to a delta function with a close to carrier noise level of less than -137 d...

  20. Multiphase, multicomponent phase behavior prediction

    Science.gov (United States)

    Dadmohammadi, Younas

    Accurate prediction of phase behavior of fluid mixtures in the chemical industry is essential for designing and operating a multitude of processes. Reliable generalized predictions of phase equilibrium properties, such as pressure, temperature, and phase compositions offer an attractive alternative to costly and time consuming experimental measurements. The main purpose of this work was to assess the efficacy of recently generalized activity coefficient models based on binary experimental data to (a) predict binary and ternary vapor-liquid equilibrium systems, and (b) characterize liquid-liquid equilibrium systems. These studies were completed using a diverse binary VLE database consisting of 916 binary and 86 ternary systems involving 140 compounds belonging to 31 chemical classes. Specifically the following tasks were undertaken: First, a comprehensive assessment of the two common approaches (gamma-phi (gamma-ϕ) and phi-phi (ϕ-ϕ)) used for determining the phase behavior of vapor-liquid equilibrium systems is presented. Both the representation and predictive capabilities of these two approaches were examined, as delineated form internal and external consistency tests of 916 binary systems. For the purpose, the universal quasi-chemical (UNIQUAC) model and the Peng-Robinson (PR) equation of state (EOS) were used in this assessment. Second, the efficacy of recently developed generalized UNIQUAC and the nonrandom two-liquid (NRTL) for predicting multicomponent VLE systems were investigated. Third, the abilities of recently modified NRTL model (mNRTL2 and mNRTL1) to characterize liquid-liquid equilibria (LLE) phase conditions and attributes, including phase stability, miscibility, and consolute point coordinates, were assessed. The results of this work indicate that the ϕ-ϕ approach represents the binary VLE systems considered within three times the error of the gamma-ϕ approach. A similar trend was observed for the for the generalized model predictions using

  1. Phase accuracy evaluation for phase-shifting fringe projection profilometry based on uniform-phase coded image

    Science.gov (United States)

    Zhang, Chunwei; Zhao, Hong; Zhu, Qian; Zhou, Changquan; Qiao, Jiacheng; Zhang, Lu

    2018-06-01

    Phase-shifting fringe projection profilometry (PSFPP) is a three-dimensional (3D) measurement technique widely adopted in industry measurement. It recovers the 3D profile of measured objects with the aid of the fringe phase. The phase accuracy is among the dominant factors that determine the 3D measurement accuracy. Evaluation of the phase accuracy helps refine adjustable measurement parameters, contributes to evaluating the 3D measurement accuracy, and facilitates improvement of the measurement accuracy. Although PSFPP has been deeply researched, an effective, easy-to-use phase accuracy evaluation method remains to be explored. In this paper, methods based on the uniform-phase coded image (UCI) are presented to accomplish phase accuracy evaluation for PSFPP. These methods work on the principle that the phase value of a UCI can be manually set to be any value, and once the phase value of a UCI pixel is the same as that of a pixel of a corresponding sinusoidal fringe pattern, their phase accuracy values are approximate. The proposed methods provide feasible approaches to evaluating the phase accuracy for PSFPP. Furthermore, they can be used to experimentally research the property of the random and gamma phase errors in PSFPP without the aid of a mathematical model to express random phase error or a large-step phase-shifting algorithm. In this paper, some novel and interesting phenomena are experimentally uncovered with the aid of the proposed methods.

  2. Phased Startup Initiative Phase 3 and 4 Test Procedure (OCRWM)

    International Nuclear Information System (INIS)

    PAJUNEN, A.L.

    2000-01-01

    The purpose of this test procedure is to safely operate the Fuel Retrieval System (FRS) and Integrated Water Treatment System (IWTS) with specific fuel canisters, and show that canisters containing fuel can be retrieved from the canister queue, decapped in the Canister Decapper, and loaded into the Primary Clean Machine (PCM) for fuel cleaning; and that fuel can be sorted on the Process Table, then loaded back into fuel canisters and relocated in basin storage. An option is included to load selected elements into multi-canister overpack (MCO) Fuel Baskets. Additional Data are collected during this test, beyond that collected during production operations. These data support qualifying the cleaning performance of the PCM, assessing the quantity of scrap generated during the cleaning, and evaluating the impact of fuel retrieval operations on the Basin water quality. The additional data collected primarily consist of weighing fuel and scrap at selected points in the operation, as well as photographing fuel and scrap as it is processed. The time to perform operations is also monitored for comparison with design predictions. Water quality data are collected to establish a baseline to predict the effectiveness of equipment design for control of contamination and visibility during production operation. The scope of this test procedure is to validate the operation of FRS and IWTS components as a complete system. Fuel canisters shall be processed in accordance with this test procedure such that fuel inspection results are clearly attributed to a particular set of PCM operating parameters. The Phase 3 test sequence processes a minimum of six canisters. Twenty-four contingency canisters have been identified, and will be processed if additional performance data are required. The Phase 4 test sequence processes a minimum of 29 specific canisters. Twenty-nine contingency canisters have been identified for Phase 4 activities and will be processed to complete process validation, if

  3. Three-phase Photovoltaic Systems

    DEFF Research Database (Denmark)

    Kerekes, Tamas; Sera, Dezso; Máthé, Lászlo

    2015-01-01

    , detailing the different photovoltaic inverter structures and topologies as well as discussing the different control layers within a grid-connected photovoltaic plant. Modulation schemes for various photovoltaic inverter topologies, grid synchronization, current control, active and reactive power control......Photovoltaic technology has experienced unprecedented growth in the last two decades, transforming from mainly off-grid niche generation to a major renewable energy technology, reaching approximately 180 GW of capacity worldwide at the end of 2014. Large photovoltaic power plants interfacing...... the grid through a three-phase power electronic converter are now well on the way to becoming a major player in the power system in many countries. Therefore, this article gives an overview of photovoltaic systems with a focus on three-phase applications, presenting these both from a hardware point of view...

  4. Nucleation phenomena at Suzuki phases

    International Nuclear Information System (INIS)

    Acosta-Najarro, D.; Jose Y, M.

    1982-01-01

    Crystal of NaCl doped with Mn present regions with an increase in nucleation densities when observed by surface gold decoration; this increase is related to the nucleation of the Suzuki phases which are induced by cooling of the crystal matrix. Calculations based on atomistic nucleation theory are developed to explain the increased nucleation density. Experiments were made to compare with the theoretical results. In particular the density of nuclei was measured as a function of the rate or arrival of atoms to the surface. Therefore, the changes in the nucleation densities are explained in terms of change in migration energies between the Suzuki phase and the NaCl matrix excluding the possibility of nucleation induced by point defects. (author)

  5. Scruncher phase and amplitude control

    International Nuclear Information System (INIS)

    DeHaven, R.A.; Morris, C.L.; Johnson, R.; Davis, J.; O'Donnell, J.M.

    1992-01-01

    The analog controller for phase and amplitude control of a 402.5 MHz super conducting cavity is described in this paper. The cavity is a single cell with niobium explosively bonded to a copper cavity. It is used as an energy compressor for pions at the Clinton P. Anderson Meson Physics Facility (LAMPF). The controller maintains cavity frequency to within 4 degrees in phase of the LAMPF beam frequency. Field amplitude is maintained to within 2 percent. This control is accomplished at critical coupling (Q load of 1 x 10 9 ) with the use of only a 30 watt rf amplifier for accelerating fields of 6 MV/m. The design includes the use of piezoelectric crystals for fast resonance control. Three types of control, self excited, VCO, and a reference frequency driven, were tried on this cavity and we present a comparison of their performance. (Author) 4 figs., ref

  6. Phase-space quantum control

    International Nuclear Information System (INIS)

    Fechner, Susanne

    2008-01-01

    The von Neumann-representation introduced in this thesis describes each laser pulse in a one-to-one manner as a sum of bandwidth-limited, Gaussian laser pulses centered around different points in phase space. These pulses can be regarded as elementary building blocks from which every single laser pulse can be constructed. The von Neumann-representation combines different useful properties for applications in quantum control. First, it is a one-to-one map between the degrees of freedom of the pulse shaper and the phase-space representation of the corresponding shaped laser pulse. In other words: Every possible choice of pulse shaper parameters corresponds to exactly one von Neumann-representation and vice versa. Moreover, since temporal and spectral structures become immediately sizable, the von Neumann-representation, as well as the Husimi- or the Wigner-representations, allows for an intuitive interpretation of the represented laser pulse. (orig.)

  7. SCRUNCHER phase and amplitude control

    International Nuclear Information System (INIS)

    DeHaven, R.A.; Morris, C.L.; Johnson, R.; Davis, J.; O'Donnell, J.M.

    1992-01-01

    The analog controller for phase and amplitude control of a 402.5 MHz super conducting cavity is described in this paper. The cavity is a single cell with niobium explosively bonded to a copper cavity. It is used as an energy compressor for pions at the Clinton P. Anderson Meson Physics Facility (LAMPF). The controller maintains cavity frequency to within 4 degrees in phase of the LAMPF beam frequency. Field amplitude is maintained to within 2 percent. This control is accomplished at critical coupling (Q loaded of 1 x 10 9 ) with the use of only a 30 watt rf amplifier for accelerating fields of 6 MV/m. The design includes the use of piezoelectric crystals for fast resonance control. Three types of control, self excited VCO, and a reference frequency driven, were tried on this cavity and we present a comparison of their performance

  8. Agent review phase one report.

    Energy Technology Data Exchange (ETDEWEB)

    Zubelewicz, Alex Tadeusz; Davis, Christopher Edward; Bauer, Travis LaDell

    2009-12-01

    This report summarizes the findings for phase one of the agent review and discusses the review methods and results. The phase one review identified a short list of agent systems that would prove most useful in the service architecture of an information management, analysis, and retrieval system. Reviewers evaluated open-source and commercial multi-agent systems and scored them based upon viability, uniqueness, ease of development, ease of deployment, and ease of integration with other products. Based on these criteria, reviewers identified the ten most appropriate systems. The report also mentions several systems that reviewers deemed noteworthy for the ideas they implement, even if those systems are not the best choices for information management purposes.

  9. Is the β phase maximal?

    International Nuclear Information System (INIS)

    Ferrandis, Javier

    2005-01-01

    The current experimental determination of the absolute values of the CKM elements indicates that 2 vertical bar V ub /V cb V us vertical bar =(1-z), with z given by z=0.19+/-0.14. This fact implies that irrespective of the form of the quark Yukawa matrices, the measured value of the SM CP phase β is approximately the maximum allowed by the measured absolute values of the CKM elements. This is β=(π/6-z/3) for γ=(π/3+z/3), which implies α=π/2. Alternatively, assuming that β is exactly maximal and using the experimental measurement sin(2β)=0.726+/-0.037, the phase γ is predicted to be γ=(π/2-β)=66.3 o +/-1.7 o . The maximality of β, if confirmed by near-future experiments, may give us some clues as to the origin of CP violation

  10. Phase 2 reentry in man

    DEFF Research Database (Denmark)

    Thomsen, P.E.B.; Jørgensen, R.M.; Kanters, J.K.

    2005-01-01

    -wave changes documented in the last sinus beat prior to ventricular extrasystoles are in agreement with phase 2 reentry, suggesting that this may be the responsible mechanism for ventricular extrasystoles and ventricular tachycardia/fibrillation. The phenomenon has been demonstrated in only animal experiments...... phase 2 reentry, demonstrated in animal experiments to initiate ventricular extrasystoles, ventricular tachycardia, and ventricular fibrillation, also plays a role in humans. METHODS We examined 18 patients with ventricular extrasystoles and/or ventricular tachycardia by signal averaging of the ECG...... patients undergoing radiofrequency ablation. Eight of the 11 patients had right ventricular outflow tract extrasystoles. RESULTS In six of the seven patients in group A, we demonstrated significant ST-elevation and/or T-wave changes in the sinus beat preceding ventricular extrasystoles compared...

  11. Dynamical constraints on phase transitions

    International Nuclear Information System (INIS)

    Morawetz, K.

    2000-01-01

    The numerical solutions of nonlocal and local Boltzmann kinetic equations for the simulation of central heavy ion reactions are parameterized in terms of time dependent thermodynamical variables in the Fermi liquid sense. This allows to discuss dynamical trajectories in phase space. The nonequilibrium state is characterized by non-isobaric, non-isochoric etc conditions, called iso-nothing conditions. Therefore a combination of thermodynamical observables is constructed which allows to locate instabilities and points of possible phase transition in a dynamical sense. We find two different mechanisms of instability, a short time surface - dominated instability and later a spinodal - dominated volume instability. The latter one occurs only if the incident energies are not exceeding much the Fermi energy and might be attributed to spinodal decomposition. Oppositely the fast surface explosion occurs far outside the spinodal and pertains also in the cases where the system develops too fast for suffering the spinodal decomposition and where the system approaches equilibrium outside the spinodal. (author)

  12. Quantitative phase imaging of arthropods

    Science.gov (United States)

    Sridharan, Shamira; Katz, Aron; Soto-Adames, Felipe; Popescu, Gabriel

    2015-11-01

    Classification of arthropods is performed by characterization of fine features such as setae and cuticles. An unstained whole arthropod specimen mounted on a slide can be preserved for many decades, but is difficult to study since current methods require sample manipulation or tedious image processing. Spatial light interference microscopy (SLIM) is a quantitative phase imaging (QPI) technique that is an add-on module to a commercial phase contrast microscope. We use SLIM to image a whole organism springtail Ceratophysella denticulata mounted on a slide. This is the first time, to our knowledge, that an entire organism has been imaged using QPI. We also demonstrate the ability of SLIM to image fine structures in addition to providing quantitative data that cannot be obtained by traditional bright field microscopy.

  13. Phase transitions and neutron scattering

    International Nuclear Information System (INIS)

    Shirane, G.

    1993-01-01

    A review is given of recent advances in neutron scattering studies of solid state physics. I have selected the study of a structural phase transition as the best example to demonstrate the power of neutron scattering techniques. Since energy analysis is relatively easy, the dynamical aspects of a transition can be elucidated by the neutron probe. I shall discuss in some detail current experiments on the 100 K transition in SrTiO 3 , the crystal which has been the paradigm of neutron studies of phase transitions for many years. This new experiment attempts to clarify the relation between the neutron central peak, observed in energy scans, and the two length scales observed in recent x-ray diffraction studies where only scans in momentum space are possible. (author)

  14. Phase transformations in engineering materials

    International Nuclear Information System (INIS)

    Bourke, M.A.M.; Lawson, A.C.; Dunand, D.C.

    1996-01-01

    Phase transformations in engineering materials are inevitably related to mechanical behavior and are often precursors to residual stress and distortion. Neutron scattering in general is a valuable tool for studying their effects, and pulsed neutrons are of special value, because of the inherently comprehensive crystallographic coverage they provide in each measurement. At the Manuel Lujan neutron scattering center several different research programs have addressed the relationships between phase transformation/mechanical behavior and residual strains. Three disparate examples are presented; (1) stress induced transformation in a NiTi shape memory alloy, (2) cryogenically induced transformation in a quenched 5180 steel, and (3) time resolved evolution of strain induced martensite in 304 stainless steel. In each case a brief description of the principle result will be discussed in the context of using neutrons for the measurement

  15. Cavity Voltage Phase Modulation MD

    CERN Document Server

    Mastoridis, Themistoklis; Molendijk, John; Timko, Helga; CERN. Geneva. ATS Department

    2016-01-01

    The LHC RF/LLRF system is currently configured for extremely stable RF voltage to minimize transient beam loading effects. The present scheme cannot be extended beyond nominal beam current since the demanded power would exceed the peak klystron power and lead to saturation. A new scheme has therefore been proposed: for beam currents above nominal (and possibly earlier), the cavity phase modulation by the beam will not be corrected (transient beam loading), but the strong RF feedback and One-Turn Delay feedback will still be active for loop and beam stability in physics. To achieve this, the voltage set point will be adapted for each bunch. The goal of this MD was to test a new algorithm that would adjust the voltage set point to achieve the cavity phase modulation that would minimize klystron forward power.

  16. Upgrades for GERDA Phase II

    Science.gov (United States)

    Heisel, Mark

    2014-09-01

    The Germanium Detector Array (GERDA) experiment is searching for the neutrinoless double beta decay (0 νββ) of 76Ge. It is a process that violates lepton number conservation and is predicted to occur in extensions of the standard model of particle physics. GERDA is located underground in the Gran Sasso National Laboratory (LNGS), Italy. An array of bare high-purity germanium detectors enriched in 76Ge is operated in a cryostat with 64 m3 of liquid argon supplemented by a 3 m thick shield of water. The experiment aims at exploring the 0 νββ decay up to a half life of 2 .1026 yr in two phases: Phase I of the experiment has been concluded last year. No signal is observed and the so far best limit is derived for the half life of the 0 νββ decay of 76Ge, T1/20ν GERDA) experiment is searching for the neutrinoless double beta decay (0 νββ) of 76Ge. It is a process that violates lepton number conservation and is predicted to occur in extensions of the standard model of particle physics. GERDA is located underground in the Gran Sasso National Laboratory (LNGS), Italy. An array of bare high-purity germanium detectors enriched in 76Ge is operated in a cryostat with 64 m3 of liquid argon supplemented by a 3 m thick shield of water. The experiment aims at exploring the 0 νββ decay up to a half life of 2 .1026 yr in two phases: Phase I of the experiment has been concluded last year. No signal is observed and the so far best limit is derived for the half life of the 0 νββ decay of 76Ge, T1/20 ν GERDA Collaboration.

  17. Final Report: Sensorpedia Phase 3

    Energy Technology Data Exchange (ETDEWEB)

    Gorman, Bryan L [ORNL; Resseguie, David R [ORNL

    2011-02-01

    This report is a summary of the Oak Ridge National Laboratory s (ORNL s) Phase 3 development of Sensorpedia, a sensor information sharing platform. Sensorpedia is ORNL s Wikipedia for Sensors. The overall goal of Sensorpedia is to enable global scale sensor information sharing for scientific research, national security and defense, public health and safety, emergency preparedness and response, and general community awareness and outreach.

  18. Disposal phase experimental program plan

    International Nuclear Information System (INIS)

    1997-01-01

    The Waste Isolation Pilot Plant (WIPP) facility comprises surface and subsurface facilities, including a repository mined in a bedded salt formation at a depth of 2,150 feet. It has been developed to safely and permanently isolate transuranic (TRU) radioactive wastes in a deep geological disposal site. On April 12, 1996, the DOE submitted a revised Resource Conservation and Recovery Act (RCRA) Part B permit application to the New Mexico Environment Department (NMED). The DOE anticipates receiving an operating permit from the NMED; this permit is required prior to the start of disposal operations. On October 29, 1996, the DOE submitted a Compliance Certification Application (CCA) to the US Environmental Protection Agency (EPA) in accordance with the WIPP land Withdrawal Act (LWA) of 1992 (Public Law 102-579) as amended, and the requirements of Title 40 of the Code of Federal Regulations (40 CFR) Parts 191 and 194. The DOE plans to begin disposal operations at the WIPP in November 1997 following receipt of certification by the EPA. The disposal phase is expected to last for 35 years, and will include recertification activities no less than once every five years. This Disposal Phase Experimental Program (DPEP) Plan outlines the experimental program to be conducted during the first 5-year recertification period. It also forms the basis for longer-term activities to be carried out throughout the 35-year disposal phase. Once the WIPP has been shown to be in compliance with regulatory requirements, the disposal phase gives an opportunity to affirm the compliance status of the WIPP, enhance the operations of the WIPP and the national TRU system, and contribute to the resolution of national and international nuclear waste management technical needs. The WIPP is the first facility of its kind in the world. As such, it provides a unique opportunity to advance the technical state of the art for permanent disposal of long-lived radioactive wastes

  19. Product evaluation phase 1 report

    International Nuclear Information System (INIS)

    Kearsey, H.A.; Page, R.J.

    1984-01-01

    This report concerns the intermediate-level radioactive waste arisings from the reprocessing of irradiated nuclear fuel at BNFL Sellafield. The graphite waste arises from the reprocessing of CAGR fuel assemblies. Headings are: introduction (origin of waste; future arisings); waste characterisation; initial evaluation of encapsulation options - evaluation of potential matrices for encapsulation of waste in form suitable for disposal; waste simulation; relevance to other phase II studies. (UK)

  20. Moment Distributions of Phase Type

    DEFF Research Database (Denmark)

    Bladt, Mogens; Nielsen, Bo Friis

    In this paper we prove that the class of distributions on the positive reals with a rational Laplace transform, also known as matrix-exponential distributions, is closed under formation of moment distributions. In particular, the results are hence valid for the well known class of phase-type dist...... alternative representation in terms of sub{intensity matrices. Finally we are able to nd explicit expressions for both the Lorenz curve and the Gini index....

  1. Phase characterization of precipitated zirconia

    International Nuclear Information System (INIS)

    Gutzov, S.; Ponahlo, J.; Lengauer, C.L.; Beran, A.

    1994-01-01

    The phase compositions of undoped and europium-doped zirconia samples, obtained by precipitation and thermal treatment from 350 to 1,000 C, have been investigated by powder X-ray diffractometry, infrared spectroscopy, and cathodoluminescence spectroscopy. The low-temperature stabilization of tetragonal zirconia is mainly controlled by the presence of anion additives, such as ammonium chloride. The influences of the crystallite size is less important. Cathodoluminescence spectra show a structural similarity between tetragonal and amorphous zirconia

  2. Multicolor Holography With Phase Shifting

    Science.gov (United States)

    Vikram, Chandra S.

    1996-01-01

    Prototype apparatus constructed to test feasibility of two-color holographic interferometric scheme in which data for reconstructing holographic wavefront obtained with help of phase-shifting technique. Provides two sets of data needed to solve equations for effects of temperature and concentration. Concept extended to holography at three or more wavelengths to measure three or more phenomena associated with significant variations in index of refraction

  3. Durability of lightweight concrete : Phase II : wetting and drying tests, Phase III : freezing and thawing tests.

    Science.gov (United States)

    1966-12-01

    This report describes a laboratory research program on the durability of lightweight concrete. Two phases of a three phase study are covered by this report, while the remaining phase is still under study. The two phases being reported are Phase II - ...

  4. The antiferroelectric phase in KCN

    International Nuclear Information System (INIS)

    Santos, R.R. dos; Koiller, B.; Weid, J.P. von der; Ribeiro, S.C.; Chaves, A.S.; Barreto, F.C.S.

    1976-01-01

    The 83 K phase transition in KCN based on a simple model Hamiltonian, in which the interactions between the CN - ions are of an electrostatic dipole-dipole nature is studied. This leads to an antiferroelectric state in the ordered phase, as suggested previously by experiment. Still with this model Hamiltonian, but within a mean field approximation, is obtained an expression for the order parameter (sub-lattice polarization) of the transition as a function both of temperature and the electric dipole moment of the CN - ion. The available experimental value for the electric dipole moment of CN - in KCL (p=0.07 eA) yields a transition temperature Tc = 31.2 K. As this value of p is not reliable for the KCN crystal we have used the value that fits the experimental transition temperature (Tc 2 = 83 K) in order to obtain the order parameter as a function of temperature, as well as the orientational energy levels both for the disordered phase and for 0 K

  5. New 'phase' of quantum gravity.

    Science.gov (United States)

    Wang, Charles H-T

    2006-12-15

    The emergence of loop quantum gravity over the past two decades has stimulated a great resurgence of interest in unifying general relativity and quantum mechanics. Among a number of appealing features of this approach is the intuitive picture of quantum geometry using spin networks and powerful mathematical tools from gauge field theory. However, the present form of loop quantum gravity suffers from a quantum ambiguity, owing to the presence of a free (Barbero-Immirzi) parameter. Following the recent progress on conformal decomposition of gravitational fields, we present a new phase space for general relativity. In addition to spin-gauge symmetry, the new phase space also incorporates conformal symmetry making the description parameter free. The Barbero-Immirzi ambiguity is shown to occur only if the conformal symmetry is gauge fixed prior to quantization. By withholding its full symmetries, the new phase space offers a promising platform for the future development of loop quantum gravity. This paper aims to provide an exposition, at a reduced technical level, of the above theoretical advances and their background developments. Further details are referred to cited references.

  6. Phase-preserved optical elevator.

    Science.gov (United States)

    Luo, Yuan; Zhang, Baile; Han, Tiancheng; Chen, Zhi; Duan, Yubo; Chu, Chia-Wei; Barbastathis, George; Qiu, Cheng Wei

    2013-03-25

    The unique superiority of transformation optics devices designed from coordinate transformation is their capability of recovering both ray trajectory and optical path length in light manipulation. However, very few experiments have been done so far to verify this dual-recovery property from viewpoints of both ray trajectory and optical path length simultaneously. The experimental difficulties arise from the fact that most previous optical transformation optics devices only work at the nano-scale; the lack of intercomparison between data from both optical path length and ray trajectory measurement in these experiments obscured the fact that the ray path was subject to a subwavelength lateral shift that was otherwise not easily perceivable and, instead, was pointed out theoretically [B. Zhang et al. Phys. Rev. Lett. 104, 233903, 2010]. Here, we use a simple macroscopic transformation optics device of phase-preserved optical elevator, which is a typical birefringent optical phenomenon that can virtually lift an optical image by a macroscopic distance, to demonstrate decisively the unique optical path length preservation property of transformation optics. The recovery of ray trajectory is first determined with no lateral shift in the reflected ray. The phase preservation is then verified with incoherent white-light interferometry without ambiguity and phase unwrapping.

  7. Substorms during different storm phases

    Directory of Open Access Journals (Sweden)

    N. Partamies

    2011-11-01

    Full Text Available After the deep solar minimum at the end of the solar cycle 23, a small magnetic storm occurred on 20–26 January 2010. The Dst (disturbance storm time index reached the minimum of −38 nT on 20 January and the prolonged recovery that followed the main phase that lasted for about 6 days. In this study, we concentrate on three substorms that took place (1 just prior to the storm, (2 during the main phase of the storm, and (3 at the end of the recovery of the storm. We analyse the solar wind conditions from the solar wind monitoring spacecraft, the duration and intensity of the substorm events as well as the behaviour of the electrojet currents from the ground magnetometer measurements. We compare the precipitation characteristics of the three substorms. The results show that the F-region electron density enhancements and dominant green and red auroral emission of the substorm activity during the storm recovery resembles average isolated substorm precipitation. However, the energy dissipated, even at the very end of a prolonged storm recovery, is very large compared to the typical energy content of isolated substorms. In the case studied here, the dissipation of the excess energy is observed over a 3-h long period of several consecutive substorm intensifications. Our findings suggest that the substorm energy dissipation varies between the storm phases.

  8. Phase diagram of ammonium nitrate

    Energy Technology Data Exchange (ETDEWEB)

    Dunuwille, Mihindra; Yoo, Choong-Shik, E-mail: csyoo@wsu.edu [Department of Chemistry and Institute for Shock Physics, Washington State University, Pullman, Washington 99164 (United States)

    2013-12-07

    Ammonium Nitrate (AN) is a fertilizer, yet becomes an explosive upon a small addition of chemical impurities. The origin of enhanced chemical sensitivity in impure AN (or AN mixtures) is not well understood, posing significant safety issues in using AN even today. To remedy the situation, we have carried out an extensive study to investigate the phase stability of AN and its mixtures with hexane (ANFO–AN mixed with fuel oil) and Aluminum (Ammonal) at high pressures and temperatures, using diamond anvil cells (DAC) and micro-Raman spectroscopy. The results indicate that pure AN decomposes to N{sub 2}, N{sub 2}O, and H{sub 2}O at the onset of the melt, whereas the mixtures, ANFO and Ammonal, decompose at substantially lower temperatures. The present results also confirm the recently proposed phase IV-IV{sup ′} transition above 17 GPa and provide new constraints for the melting and phase diagram of AN to 40 GPa and 400°C.

  9. Glare Spot Phase Doppler Anemometry

    Science.gov (United States)

    Hespel, Camille; Ren, Kuanfang; Gréhan, Gérard; Onofri, Fabrice

    2007-06-01

    The Phase Doppler anemometry has been developed to measure simultaneously the velocity and the size of droplets. The measurement of the refractive index would be also interesting since it depends on the temperature and the composition of the particle and its measurement permits both to increase the quality of the diameter measurement and to obtain information on the temperature and/or the composition of the droplets. In this paper, we introduce a Glare Spot Phase Doppler Anemometry which uses two large beams. In this case, the images of the particle formed by the reflected and refracted light, known as glare spots, are separated in space. When a particle passes in the probe volume, the two parts in a signal obtained by a detector in forward direction are then separated in time. If two detectors are used the phase differences between two signals, the distance and the intensity ratio of reflected and refracted parts can be obtained and they provide rich information about the particle diameter and its refractive index, as well as its velocity. This paper is devoted to the numerical study of such a configuration with two theoretical models: geometrical optics and rigorous electromagnetism solution.

  10. NIF optics phase gradient specfication

    International Nuclear Information System (INIS)

    Williams, W.; Auerbach, J.; Hunt, J.; Lawson, L.; Manes, K.; Orth, C.; Sacks, R.; Trenholme, J.; Wegner, P.

    1997-01-01

    A root-mean-square (rms) phase gradient specification seems to allow a good connection between the NIP optics quality and focal spot requirements. Measurements on Beamlet optics individually, and as a chain, indicate they meet the assumptions necessary to use this specification, and that they have a typical rms phase gradient of ∼80 angstrom/cm. This may be sufficient for NIP to meet the proposed Stockpile Stewardship Management Program (SSMP) requirements of 80% of a high- power beam within a 200-250 micron diameter spot. Uncertainties include, especially, the scale length of the optics phase noise, the ability of the adaptive optic to correct against pump-induced distortions and optics noise, and the possibility of finding mitigation techniques against whole-beam self-focusing (e.g. a pre- correction optic). Further work is needed in these areas to better determine the NIF specifications. This memo is a written summary of a presentation on this topic given by W. Williams 24 April 1997 to NIP and LS ampersand T personnel

  11. Non-equilibrium phase transition

    International Nuclear Information System (INIS)

    Mottola, E.; Cooper, F.M.; Bishop, A.R.; Habib, S.; Kluger, Y.; Jensen, N.G.

    1998-01-01

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). Non-equilibrium phase transitions play a central role in a very broad range of scientific areas, ranging from nuclear, particle, and astrophysics to condensed matter physics and the material and biological sciences. The aim of this project was to explore the path to a deeper and more fundamental understanding of the common physical principles underlying the complex real time dynamics of phase transitions. The main emphasis was on the development of general theoretical tools to deal with non-equilibrium processes, and of numerical methods robust enough to capture the time-evolving structures that occur in actual experimental situations. Specific applications to Laboratory multidivisional efforts in relativistic heavy-ion physics (transition to a new phase of nuclear matter consisting of a quark-gluon plasma) and layered high-temperature superconductors (critical currents and flux flow at the National High Magnetic Field Laboratory) were undertaken

  12. CERN openlab enters new phase

    CERN Multimedia

    Katarina Anthony

    2012-01-01

    The newest phase of CERN’s openlab framework was inaugurated this week during a meeting of the openlab partners. This phase will last three years and will bring together existing openlab partners and a new contributor: Huawei.   Group picture taken at the first CERN openlab IV annual Board of Sponsors meeting, in the presence of the CERN Director-General, the partners and the openlab team members. © Fons Rademakers (CERN Photo Club). Eleven years ago, the creation of the CERN openlab created a long-term link between industrial partners and the Organization. Its framework has allowed industry to carry out large-scale IT research and development in an open atmosphere – an “Open Lab”, if you will. For CERN, openlab has contributed to giving the computing centre and, more broadly, the LHC community, the opportunity to ensure that the next generation of services and products is suitable to their needs. Now entering its fourth phase, openlab will ...

  13. Phase contrast STEM for thin samples: Integrated differential phase contrast.

    Science.gov (United States)

    Lazić, Ivan; Bosch, Eric G T; Lazar, Sorin

    2016-01-01

    It has been known since the 1970s that the movement of the center of mass (COM) of a convergent beam electron diffraction (CBED) pattern is linearly related to the (projected) electrical field in the sample. We re-derive a contrast transfer function (CTF) for a scanning transmission electron microscopy (STEM) imaging technique based on this movement from the point of view of image formation and continue by performing a two-dimensional integration on the two images based on the two components of the COM movement. The resulting integrated COM (iCOM) STEM technique yields a scalar image that is linear in the phase shift caused by the sample and therefore also in the local (projected) electrostatic potential field of a thin sample. We confirm that the differential phase contrast (DPC) STEM technique using a segmented detector with 4 quadrants (4Q) yields a good approximation for the COM movement. Performing a two-dimensional integration, just as for the COM, we obtain an integrated DPC (iDPC) image which is approximately linear in the phase of the sample. Beside deriving the CTFs of iCOM and iDPC, we clearly point out the objects of the two corresponding imaging techniques, and highlight the differences to objects corresponding to COM-, DPC-, and (HA) ADF-STEM. The theory is validated with simulations and we present first experimental results of the iDPC-STEM technique showing its capability for imaging both light and heavy elements with atomic resolution and a good signal to noise ratio (SNR). Copyright © 2015 Elsevier B.V. All rights reserved.

  14. Nanoscale phase-change materials and devices

    International Nuclear Information System (INIS)

    Zheng, Qinghui; Wang, Yuxi; Zhu, Jia

    2017-01-01

    Phase-change materials (PCMs) that can reversibly transit between crystalline and amorphous phases have been widely used for data-storage and other functional devices. As PCMs scale down to nanoscale, the properties and transition procedures can vary, bringing both challenges and opportunities in scalability. This article describes the physical structures, properties and applications of nanoscale phase-change materials and devices. The limitations and performance of scaling properties in phase-change materials and the recent progress and challenges in phase-change devices are presented. At the end, some emerging applications related to phase-change materials are also introduced. (topical review)

  15. Stochastic Kuramoto oscillators with discrete phase states

    Science.gov (United States)

    Jörg, David J.

    2017-09-01

    We present a generalization of the Kuramoto phase oscillator model in which phases advance in discrete phase increments through Poisson processes, rendering both intrinsic oscillations and coupling inherently stochastic. We study the effects of phase discretization on the synchronization and precision properties of the coupled system both analytically and numerically. Remarkably, many key observables such as the steady-state synchrony and the quality of oscillations show distinct extrema while converging to the classical Kuramoto model in the limit of a continuous phase. The phase-discretized model provides a general framework for coupled oscillations in a Markov chain setting.

  16. Stochastic Kuramoto oscillators with discrete phase states.

    Science.gov (United States)

    Jörg, David J

    2017-09-01

    We present a generalization of the Kuramoto phase oscillator model in which phases advance in discrete phase increments through Poisson processes, rendering both intrinsic oscillations and coupling inherently stochastic. We study the effects of phase discretization on the synchronization and precision properties of the coupled system both analytically and numerically. Remarkably, many key observables such as the steady-state synchrony and the quality of oscillations show distinct extrema while converging to the classical Kuramoto model in the limit of a continuous phase. The phase-discretized model provides a general framework for coupled oscillations in a Markov chain setting.

  17. Phase alteration compensation in reflection digital holography

    International Nuclear Information System (INIS)

    Rincon, O; Amezquita, R; Monroy, F

    2011-01-01

    The phase maps obtained from digital holographic microscopy techniques carry information about the axial lengths of the object under study. Additionally, these phase maps have information of tilt and curvatures with origin in the off-axis geometry and the magnification lenses system, respectively. Only a complete compensation of these extra phases allows a correct interpretation of the phase information. In this article a numerical strategy to compensate for these alterations is designed, using a phase mask located in different planes. This strategy is applied in the measurement of a phase steps plate using a digital holography setup.

  18. Phases definition in marketing export process

    Directory of Open Access Journals (Sweden)

    Rajković Dragan

    2004-01-01

    Full Text Available The result of export marketing process depends on its five phases. The first phase-revision of export capacities, inner view on advantages and defects of company concerning export possibilities. The second phase-identification of export strategy market penetration. The forth phase-preparing for the marketing campaign (action. The fifth phase-carrying out the above mentioned activities. This study shows the structure and contents of the mentioned phases. At the end, export marketing analyzed DPV is given as the example.

  19. Ponderomotive phase plate for transmission electron microscopes

    Science.gov (United States)

    Reed, Bryan W [Livermore, CA

    2012-07-10

    A ponderomotive phase plate system and method for controllably producing highly tunable phase contrast transfer functions in a transmission electron microscope (TEM) for high resolution and biological phase contrast imaging. The system and method includes a laser source and a beam transport system to produce a focused laser crossover as a phase plate, so that a ponderomotive potential of the focused laser crossover produces a scattering-angle-dependent phase shift in the electrons of the post-sample electron beam corresponding to a desired phase contrast transfer function.

  20. Nanoscale phase-change materials and devices

    Science.gov (United States)

    Zheng, Qinghui; Wang, Yuxi; Zhu, Jia

    2017-06-01

    Phase-change materials (PCMs) that can reversibly transit between crystalline and amorphous phases have been widely used for data-storage and other functional devices. As PCMs scale down to nanoscale, the properties and transition procedures can vary, bringing both challenges and opportunities in scalability. This article describes the physical structures, properties and applications of nanoscale phase-change materials and devices. The limitations and performance of scaling properties in phase-change materials and the recent progress and challenges in phase-change devices are presented. At the end, some emerging applications related to phase-change materials are also introduced.

  1. Phases of Ca from first principles

    International Nuclear Information System (INIS)

    Qiu, S L; Marcus, P M

    2009-01-01

    Structures and properties of many of the phases of Ca under pressure are calculated from first principles by a systematic procedure that minimizes total energy E with respect to structure under the constraint of constant volume V. The minima of E are followed on successive sweeps of lattice parameters for 11 of 14 Bravais symmetries for one-atom-per-cell structures. The structures include the four orthorhombic phases. Also included are the hexagonal close-packed and cubic diamond phases with two atoms per primitive cell. No uniquely orthorhombic phases are found; all one-atom orthorhombic phases over a mega-bar pressure range are identical to higher-symmetry phases. The simple cubic phase is shown to be stable where it is the ground state. The number of distinct one-atom phases reduces to five plus the two two-atom phases. For each of these phases the Gibbs free energy at pressure p, G(p), is calculated for a non-vibrating lattice; the functions G(p) give the ground state at each p, the relative stabilities of all phases and the thermodynamic phase transition pressures for all phase transitions over a several-megabar range.

  2. Fermion condensation quantum phase transition versus conventional quantum phase transitions

    International Nuclear Information System (INIS)

    Shaginyan, V.R.; Han, J.G.; Lee, J.

    2004-01-01

    The main features of fermion condensation quantum phase transition (FCQPT), which are distinctive in several aspects from that of conventional quantum phase transition (CQPT), are considered. We show that in contrast to CQPT, whose physics in quantum critical region is dominated by thermal and quantum fluctuations and characterized by the absence of quasiparticles, the physics of a Fermi system near FCQPT or undergone FCQPT is controlled by the system of quasiparticles resembling the Landau quasiparticles. Contrary to the Landau quasiparticles, the effective mass of these quasiparticles strongly depends on the temperature, magnetic fields, density, etc. This system of quasiparticles having general properties determines the universal behavior of the Fermi system in question. As a result, the universal behavior persists up to relatively high temperatures comparatively to the case when such a behavior is determined by CQPT. We analyze striking recent measurements of specific heat, charge and heat transport used to study the nature of magnetic field-induced QCP in heavy-fermion metal CeCoIn 5 and show that the observed facts are in good agreement with our scenario based on FCQPT and certainly seem to rule out the critical fluctuations related with CQPT. Our general consideration suggests that FCQPT and the emergence of novel quasiparticles near and behind FCQPT and resembling the Landau quasiparticles are distinctive features intrinsic to strongly correlated substances

  3. Remark on Relations Between Different Non-integrable Phases

    International Nuclear Information System (INIS)

    Gu Zhiyu; Qian Shangwu

    2005-01-01

    There are three non-integrable phases in literatures: Berry phase, Aharonov-Anandan phase, and Yang phase. This article discusses the definitions and relations between these three non-integrable phases.

  4. Phase transitions and critical phenomena

    CERN Document Server

    Domb, Cyril

    2001-01-01

    The field of phase transitions and critical phenomena continues to be active in research, producing a steady stream of interesting and fruitful results. It has moved into a central place in condensed matter studies.Statistical physics, and more specifically, the theory of transitions between states of matter, more or less defines what we know about 'everyday' matter and its transformations.The major aim of this serial is to provide review articles that can serve as standard references for research workers in the field, and for graduate students and others wishing to obtain reliable in

  5. Gibbs measures and phase transitions

    CERN Document Server

    Georgii, Hans-Otto

    2011-01-01

    From a review of the first edition: ""This book […] covers in depth a broad range of topics in the mathematical theory of phase transition in statistical mechanics. […] It is in fact one of the author's stated aims that this comprehensive monograph should serve both as an introductory text and as a reference for the expert."" (F. Papangelou, Zentralblatt MATH) The second edition has been extended by a new section on large deviations and some comments on the more recent developments in the area.

  6. Product evaluation phase 1 report

    International Nuclear Information System (INIS)

    Kearsey, H.A.; Hornby, J.

    1984-01-01

    This report concerns the intermediate-level radioactive waste arisings from the reprocessing of irradiated nuclear fuel at BNFL Sellafield. The waste arises from the reprocessing of uranium from overseas PWR type reactors and is the solid dissolver waste remaining after the fuel has been extracted. Headings are: general introduction (origin, current stocks and future arisings); characteristics of the waste stream; alternative matrices - evaluation of potential matrices for encapsulation of waste in form suitable for disposal; waste simulation; relevance of other phase II studies. (U.K.)

  7. Phase transitions and critical phenomena

    CERN Document Server

    Domb, Cyril

    2000-01-01

    The field of phase transitions and critical phenomena continues to be active in research, producing a steady stream of interesting and fruitful results. No longer an area of specialist interest, it has acquired a central focus in condensed matter studies. The major aim of this serial is to provide review articles that can serve as standard references for research workers in the field, and for graduate students and others wishing to obtain reliable information on important recent developments.The two review articles in this volume complement each other in a remarkable way. Both deal with what m

  8. Phased operations and recovery options

    International Nuclear Information System (INIS)

    Mankamo, T.

    1989-01-01

    The event sequence diagram is extended with embedded state submodels. This allows process oriented modeling of phased missions, and flexible modeling of recovery from failure states. This also enhances the structured consideration of time dependences in process conditions, and earlier scenario of events. Operational decision alternatives can straightforwardly be included. In fact, the approach has been developed for the analysis of operational alternatives such as plant shutdown versus continued operation, in failure situations of standby safety systems, with the aim of realistic quantification of shutdown related transient risks

  9. Product evaluation phase 1 report

    International Nuclear Information System (INIS)

    Kearsey, H.A.; Page, R.J.

    1984-01-01

    This report concerns the intermediate-level radioactive waste arisings from the reprocessing of irradiated nuclear fuel at BNFL Sellafield. The waste arises from the reprocessing of CAGR fuel assemblies, which consist of fuel pins held inside a graphite sleeve by means of stainless steel support grids and braces. Headings are: introduction (origin of waste and future arisings); waste characterisation; initial evaluation of encapsulation options - evaluation of potential matrices for encapsulation of waste in form suitable for disposal; waste simulation; relevance of other phase II studies. (U.K.)

  10. Product evaluation phase 1 report

    International Nuclear Information System (INIS)

    Kearsey, H.A.; Hornby, J.

    1984-01-01

    This report concerns the intermediate-level radioactive waste arisings from the reprocessing of irradiated nuclear fuel at BNFL Sellafield. The waste arises from the reprocessing of uranium from overseas BWR type reactors and is the solid dissolver waste remaining after the fuel has been extracted. Headings are: general introduction (origin, current stocks and future arisings); characteristics of the waste stream; alternative matrices - evaluation of potential matrices for encapsulation of waste in form suitable for disposal; waste simulation; relevance of other phase II studies. (U.K.)

  11. Phase transformations in metallic glasses

    DEFF Research Database (Denmark)

    Jiang, Jianzhong

    2003-01-01

    Recent development of grain-size effect on phase transformations induced by pressure is reported. A thermodynamic theory is presented and three components: the ratio of volume collapses, the surface energy differences, and the internal energy differences, governing the change of transition pressure...... in nanocrystals were uncovered. They can be used to explain the results reported in the literature and to identify the main factor to the change of the transition pressure in nanocrystals. We demonstrated that the grain-size effect on the structural stability in nanocrystals with respect to transition pressure...

  12. Airborne electronically steerable phased array

    Science.gov (United States)

    1972-01-01

    The results are presented of the second stage of a program for the design and development of a phased array capable of simultaneous and separate transmission and reception of radio frequency signals at S-band frequencies. The design goals of this stage were the development of three major areas of interest required for the final prototype model. These areas are the construction and testing of the low-weight, full-scale 128-element array of antenna elements, the development of the RF manifold feed system, and the construction and testing of a working module containing diplexer and transmit and receive circuits.

  13. Spiral phases of doped antiferromagnets

    International Nuclear Information System (INIS)

    Shraiman, B.I.; Siggia, E.D.

    1990-01-01

    The dipole density field describing the holls in a doped antiferromagnet is considered for law hole density in the semiclassical limit. This yields a phase in which the order parameter is planar and spirals round a fixed direction. The single spiral state breaks the continuous spin rotational symmetry and exhibits long-range order at zero temperature. In it there is a global spin direction as rotation axis. The double spiral state, in which there are two perpendicular directions, is isotropic in both spin and real space. Several results of microscopic calculations, carried out to understand the electronic states, quantum fluctuations, lattice effects and normal mode dynamics, are recapitulated. 8 refs

  14. Passive longitudinal phase space linearizer

    Directory of Open Access Journals (Sweden)

    P. Craievich

    2010-03-01

    Full Text Available We report on the possibility to passively linearize the bunch compression process in electron linacs for the next generation x-ray free electron lasers. This can be done by using the monopole wakefields in a dielectric-lined waveguide. The optimum longitudinal voltage loss over the length of the bunch is calculated in order to compensate both the second-order rf time curvature and the second-order momentum compaction terms. Thus, the longitudinal phase space after the compression process is linearized up to a fourth-order term introduced by the convolution between the bunch and the monopole wake function.

  15. Light scattering near phase transitions

    CERN Document Server

    Cummins, HZ

    1983-01-01

    Since the development of the laser in the early 1960's, light scattering has played an increasingly crucial role in the investigation of many types of phase transitions and the published work in this field is now widely dispersed in a large number of books and journals.A comprehensive overview of contemporary theoretical and experimental research in this field is presented here. The reviews are written by authors who have actively contributed to the developments that have taken place in both Eastern and Western countries.

  16. Reliability in the design phase

    International Nuclear Information System (INIS)

    Siahpush, A.S.; Hills, S.W.; Pham, H.; Majumdar, D.

    1991-12-01

    A study was performed to determine the common methods and tools that are available to calculated or predict a system's reliability. A literature review and software survey are included. The desired product of this developmental work is a tool for the system designer to use in the early design phase so that the final design will achieve the desired system reliability without lengthy testing and rework. Three computer programs were written which provide the first attempt at fulfilling this need. The programs are described and a case study is presented for each one. This is a continuing effort which will be furthered in FY-1992. 10 refs

  17. Purification of biomaterials by phase partitioning

    Science.gov (United States)

    Harris, J. M.

    1984-01-01

    A technique which is particularly suited to microgravity environments and which is potentially more powerful than electrophoresis is phase partitioning. Phase partitioning is purification by partitioning between the two immiscible aqueous layers formed by solution of the polymers poly(ethylene glycol) and dextran in water. This technique proved to be very useful for separations in one-g but is limited for cells because the cells are more dense than the phase solutions thus tend to sediment to the bottom of the container before reaching equilibrium with the preferred phase. There are three phases to work in this area: synthesis of new polymers for affinity phase partitioning; development of automated apparatus for ground-based separations; and design of apparatus for performing simple phase partitioning space experiments, including examination of mechanisms for separating phases in the absence of gravity.

  18. Phase formation of physically associating polymer blends

    International Nuclear Information System (INIS)

    Tanaka, Fumihiko

    1993-01-01

    Polymers exhibit a variety of condensed phases when some of their segments are capable of forming weak bonds which can be created and destroyed by thermal motion. Transition from one phase to another caused by such 'segment association' is reversible by the change of the temperature and the concentration, so that it is called 'reversible phase transition'. What types of reversible phase formation are possible for a given associative interaction? What is the most fundamental laws which govern the competition between molecular association and phase separation? This paper surveys, as typical examples of reversible phases, macroscopic phase separation, microphase formation, solvation, gelation, etc. from the unified point of view, and explores the possibility of new condensed phases caused by their mutual interference. (author)

  19. Reversed phase propagation for hyperbolic surface waves

    DEFF Research Database (Denmark)

    Repän, Taavi; Novitsky, Andrey; Willatzen, Morten

    2018-01-01

    Magnetic properties can be used to control phase propagation in hyperbolic metamaterials. However, in the visible spectrum magnetic properties are difficult to obtain. We discuss hyperbolic surface waves allowing for a similar control over phase, achieved without magnetic properties....

  20. Phase-field model of eutectic growth

    International Nuclear Information System (INIS)

    Karma, A.

    1994-01-01

    A phase-field model which describes the solidification of a binary eutectic alloy with a simple symmetric phase diagram is introduced and the sharp-interface limit of this model is explored both analytically and numerically

  1. Some concepts in condensed phase chemical kinetics

    International Nuclear Information System (INIS)

    Adelman, S.A.

    1986-01-01

    Some concepts in condensed phase chemical kinetics which have emerged from a recent rigorous statistical mechanical treatment of condensed phase chemical reaction dynamics (S.A. Adelman, Adv. Chem. Phys.53:61 (1983)) are discussed in simple physical terms

  2. High-pressure modifications of CaZn2, SrZn2, SrAl2, and BaAl2: Implications for Laves phase structural trends

    International Nuclear Information System (INIS)

    Kal, Subhadeep; Stoyanov, Emil; Belieres, Jean-Philippe; Groy, Thomas L.; Norrestam, Rolf; Haeussermann, Ulrich

    2008-01-01

    High-pressure forms of intermetallic compounds with the composition CaZn 2 , SrZn 2 , SrAl 2 , and BaAl 2 were synthesized from CeCu 2 -type precursors (CaZn 2 , SrZn 2 , SrAl 2 ) and Ba 21 Al 40 by multi-anvil techniques and investigated by X-ray powder diffraction (SrAl 2 and BaAl 2 ), X-ray single-crystal diffraction (CaZn 2 ), and electron microscopy (SrZn 2 ). Their structures correspond to that of Laves phases. Whereas the dialuminides crystallize in the cubic MgCu 2 (C15) structure, the dizincides adopt the hexagonal MgZn 2 (C14) structure. This trend is in agreement with the structural relationship displayed by sp bonded Laves phase systems at ambient conditions. - Graphical abstract: CeCu 2 -type polar intermetallics can be transformed to Laves phases upon simultaneous application of pressure and temperature. The observed structures are controlled by the valence electron concentration

  3. Signature of Topological Phases in Zitterbewegung

    KAUST Repository

    Ghosh, Sumit; Manchon, Aurelien

    2016-01-01

    We have studied the Zitterbewegung effect on an infinite two-dimensional sheet with honeycomb lattice. By tuning the perpendicular electric field and the magnetization of the sheet, it can enter different topological phases. We have shown that the phase and magnitude of Zitterbewegung effect, i.e., the jittering motion of electron wavepackets, correlates with the various topological phases. The topological phase diagram can be reconstructed by analyzing these features. Our findings are applicable to materials like silicene, germanene, stanene, etc.

  4. Phase Space Exchange in Thick Wedge Absorbers

    Energy Technology Data Exchange (ETDEWEB)

    Neuffer, David [Fermi National Accelerator Lab. (FNAL), Batavia, IL (United States)

    2017-01-01

    The problem of phase space exchange in wedge absorbers with ionization cooling is discussed. The wedge absorber exchanges transverse and longitudinal phase space by introducing a position-dependent energy loss. In this paper we note that the wedges used with ionization cooling are relatively thick, so that single wedges cause relatively large changes in beam phase space. Calculation methods adapted to such “thick wedge” cases are presented, and beam phase-space transformations through such wedges are discussed.

  5. QPSK regeneration without active phase-locking

    DEFF Research Database (Denmark)

    Kjøller, Niels-Kristian; Da Ros, Francesco; Røge, Kasper Meldgaard

    2016-01-01

    QPSK regeneration without active phase stabilization is investigated in numerical simulations. We propose an improved scheme for phase-locking free QPSK regeneration showing significant improvements in the error vector magnitude of the signal.......QPSK regeneration without active phase stabilization is investigated in numerical simulations. We propose an improved scheme for phase-locking free QPSK regeneration showing significant improvements in the error vector magnitude of the signal....

  6. Signature of Topological Phases in Zitterbewegung

    KAUST Repository

    Ghosh, Sumit

    2016-09-02

    We have studied the Zitterbewegung effect on an infinite two-dimensional sheet with honeycomb lattice. By tuning the perpendicular electric field and the magnetization of the sheet, it can enter different topological phases. We have shown that the phase and magnitude of Zitterbewegung effect, i.e., the jittering motion of electron wavepackets, correlates with the various topological phases. The topological phase diagram can be reconstructed by analyzing these features. Our findings are applicable to materials like silicene, germanene, stanene, etc.

  7. Phase equilibria basic principles, applications, experimental techniques

    CERN Document Server

    Reisman, Arnold

    2013-01-01

    Phase Equilibria: Basic Principles, Applications, Experimental Techniques presents an analytical treatment in the study of the theories and principles of phase equilibria. The book is organized to afford a deep and thorough understanding of such subjects as the method of species model systems; condensed phase-vapor phase equilibria and vapor transport reactions; zone refining techniques; and nonstoichiometry. Physicists, physical chemists, engineers, and materials scientists will find the book a good reference material.

  8. Probing phase transitions via energetic nuclear collisions

    International Nuclear Information System (INIS)

    Lukacs, B.; Csernai, L.P.

    1983-07-01

    The possible effects of the nucleon-quark phase transition on the dynamics of heavy ion collisions are discussed. It is shown that the formation of the quark phase can be expected at recent experiments. Nevertheless, the compressibility of the two-phase mixture remains relatively low, thus the quark phase remains limited in both space and time, and the observables are not strongly affected. (author)

  9. Phase contrast STEM for thin samples: Integrated differential phase contrast

    International Nuclear Information System (INIS)

    Lazić, Ivan; Bosch, Eric G.T.; Lazar, Sorin

    2016-01-01

    It has been known since the 1970s that the movement of the center of mass (COM) of a convergent beam electron diffraction (CBED) pattern is linearly related to the (projected) electrical field in the sample. We re-derive a contrast transfer function (CTF) for a scanning transmission electron microscopy (STEM) imaging technique based on this movement from the point of view of image formation and continue by performing a two-dimensional integration on the two images based on the two components of the COM movement. The resulting integrated COM (iCOM) STEM technique yields a scalar image that is linear in the phase shift caused by the sample and therefore also in the local (projected) electrostatic potential field of a thin sample. We confirm that the differential phase contrast (DPC) STEM technique using a segmented detector with 4 quadrants (4Q) yields a good approximation for the COM movement. Performing a two-dimensional integration, just as for the COM, we obtain an integrated DPC (iDPC) image which is approximately linear in the phase of the sample. Beside deriving the CTFs of iCOM and iDPC, we clearly point out the objects of the two corresponding imaging techniques, and highlight the differences to objects corresponding to COM-, DPC-, and (HA) ADF-STEM. The theory is validated with simulations and we present first experimental results of the iDPC-STEM technique showing its capability for imaging both light and heavy elements with atomic resolution and a good signal to noise ratio (SNR). - Highlights: • First DPC-based atomic resolution images of potential and charge density are obtained. • This is enabled by integration and differentiation of 2D DPC signals, respectively. • Integrated DPC (iDPC) based on 4 quadrant imaging is compared to iCOM imaging. • Noise analysis and comparison with standard STEM imaging modes is provided. • iDPC allows direct imaging of light (C, N, O …) and heavy (Ga, Au …) atoms together.

  10. Phase contrast STEM for thin samples: Integrated differential phase contrast

    Energy Technology Data Exchange (ETDEWEB)

    Lazić, Ivan, E-mail: ivan.lazic@fei.com; Bosch, Eric G.T.; Lazar, Sorin

    2016-01-15

    It has been known since the 1970s that the movement of the center of mass (COM) of a convergent beam electron diffraction (CBED) pattern is linearly related to the (projected) electrical field in the sample. We re-derive a contrast transfer function (CTF) for a scanning transmission electron microscopy (STEM) imaging technique based on this movement from the point of view of image formation and continue by performing a two-dimensional integration on the two images based on the two components of the COM movement. The resulting integrated COM (iCOM) STEM technique yields a scalar image that is linear in the phase shift caused by the sample and therefore also in the local (projected) electrostatic potential field of a thin sample. We confirm that the differential phase contrast (DPC) STEM technique using a segmented detector with 4 quadrants (4Q) yields a good approximation for the COM movement. Performing a two-dimensional integration, just as for the COM, we obtain an integrated DPC (iDPC) image which is approximately linear in the phase of the sample. Beside deriving the CTFs of iCOM and iDPC, we clearly point out the objects of the two corresponding imaging techniques, and highlight the differences to objects corresponding to COM-, DPC-, and (HA) ADF-STEM. The theory is validated with simulations and we present first experimental results of the iDPC-STEM technique showing its capability for imaging both light and heavy elements with atomic resolution and a good signal to noise ratio (SNR). - Highlights: • First DPC-based atomic resolution images of potential and charge density are obtained. • This is enabled by integration and differentiation of 2D DPC signals, respectively. • Integrated DPC (iDPC) based on 4 quadrant imaging is compared to iCOM imaging. • Noise analysis and comparison with standard STEM imaging modes is provided. • iDPC allows direct imaging of light (C, N, O …) and heavy (Ga, Au …) atoms together.

  11. Sample Exchange Evaluation (SEE) Report - Phase II

    International Nuclear Information System (INIS)

    Winters, W.I.

    1994-01-01

    This report describes the results from Phase II of the Sample Exchange Evaluation (SEE) Program, a joint effort to compare analytical laboratory performance on samples from the Hanford Site's high-level waste tanks. In Phase II, the program has been expanded to include inorganic constituents in addition to radionuclides. Results from Phase II that exceeded 20% relative percent difference criteria are identified

  12. The OPAL phase III microvertex detector

    International Nuclear Information System (INIS)

    De Jong, S.

    1997-01-01

    A description of the OPAL Phase III microvertex detector is given. Special emphasis is put on problems that have been encountered in the installation and operation of the different phases of the OPAL microvertex detector leading to the present Phase III detector and their cures. A short description of the new OPAL radiation monitoring and beam dump system is also given. (orig.)

  13. Quantum phase transition with dissipative frustration

    Science.gov (United States)

    Maile, D.; Andergassen, S.; Belzig, W.; Rastelli, G.

    2018-04-01

    We study the quantum phase transition of the one-dimensional phase model in the presence of dissipative frustration, provided by an interaction of the system with the environment through two noncommuting operators. Such a model can be realized in Josephson junction chains with shunt resistances and resistances between the chain and the ground. Using a self-consistent harmonic approximation, we determine the phase diagram at zero temperature which exhibits a quantum phase transition between an ordered phase, corresponding to the superconducting state, and a disordered phase, corresponding to the insulating state with localized superconducting charge. Interestingly, we find that the critical line separating the two phases has a nonmonotonic behavior as a function of the dissipative coupling strength. This result is a consequence of the frustration between (i) one dissipative coupling that quenches the quantum phase fluctuations favoring the ordered phase and (ii) one that quenches the quantum momentum (charge) fluctuations leading to a vanishing phase coherence. Moreover, within the self-consistent harmonic approximation, we analyze the dissipation induced crossover between a first and second order phase transition, showing that quantum frustration increases the range in which the phase transition is second order. The nonmonotonic behavior is reflected also in the purity of the system that quantifies the degree of correlation between the system and the environment, and in the logarithmic negativity as an entanglement measure that encodes the internal quantum correlations in the chain.

  14. Sound speed during the QCD phase transition

    International Nuclear Information System (INIS)

    Nagasawa, Michiyasu; Yokoyama, Jun'ichi

    1998-01-01

    The Jeans scale is estimated during the coexistence epoch of quark-gluon and hadron phases in the first-order QCD phase transition. It is shown that, contrary to previous claims, reduction of the sound speed is so little that the phase transition does not affect evolution of cosmological density fluctuations appreciably. (author)

  15. Centrifuge workers study. Phase II, completion report

    Energy Technology Data Exchange (ETDEWEB)

    Wooten, H.D.

    1994-09-01

    Phase II of the Centrifuge Workers Study was a follow-up to the Phase I efforts. The Phase I results had indicated a higher risk than expected among centrifuge workers for developing bladder cancer when compared with the risk in the general population for developing this same type of cancer. However, no specific agent could be identified as the causative agent for these bladder cancers. As the Phase II Report states, Phase I had been limited to workers who had the greatest potential for exposure to substances used in the centrifuge process. Phase II was designed to expand the survey to evaluate the health of all employees who had ever worked in Centrifuge Program Departments 1330-1339 but who had not been interviewed in Phase I. Employees in analytical laboratories and maintenance departments who provided support services for the Centrifuge Program were also included in Phase II. In December 1989, the Oak Ridge Associated Universities (ORAU), now known as Oak Ridge Institute for Science and Education (ORISE), was contracted to conduct a follow-up study (Phase II). Phase H of the Centrifuge Workers Study expanded the survey to include all former centrifuge workers who were not included in Phase I. ORISE was chosen because they had performed the Phase I tasks and summarized the corresponding survey data therefrom.

  16. Centrifuge workers study. Phase II, completion report

    International Nuclear Information System (INIS)

    Wooten, H.D.

    1994-09-01

    Phase II of the Centrifuge Workers Study was a follow-up to the Phase I efforts. The Phase I results had indicated a higher risk than expected among centrifuge workers for developing bladder cancer when compared with the risk in the general population for developing this same type of cancer. However, no specific agent could be identified as the causative agent for these bladder cancers. As the Phase II Report states, Phase I had been limited to workers who had the greatest potential for exposure to substances used in the centrifuge process. Phase II was designed to expand the survey to evaluate the health of all employees who had ever worked in Centrifuge Program Departments 1330-1339 but who had not been interviewed in Phase I. Employees in analytical laboratories and maintenance departments who provided support services for the Centrifuge Program were also included in Phase II. In December 1989, the Oak Ridge Associated Universities (ORAU), now known as Oak Ridge Institute for Science and Education (ORISE), was contracted to conduct a follow-up study (Phase II). Phase H of the Centrifuge Workers Study expanded the survey to include all former centrifuge workers who were not included in Phase I. ORISE was chosen because they had performed the Phase I tasks and summarized the corresponding survey data therefrom

  17. Heavy truck rollover characterization (phase B).

    Science.gov (United States)

    2009-09-01

    The Heavy Truck Rollover Characterization Study - Phase-B builds on the results of prior phases of research. Phases 1 and 2 (Funded by Federal Highway Administration) involved heavy truck rollover characterization for a tractor and box-trailer; and P...

  18. Insights on some chiral smectic phases

    Indian Academy of Sciences (India)

    journal of. August 2003 physics pp. 285–295. Insights on some chiral ... Liquid crystals; smectics; chirality; frustrated phases; twist grain boundary phases. ... molecules are more or less packed in layers and smectic phases can be seen ..... (imaging plate or CCD camera) which was located at about 300 mm from the sample.

  19. Determination of the asymptotic normalization coefficients for C-14 + n - C-15,the C-14(n,gamma)C-15 reaction rate, and evaluation of a new method to determine spectroscopic factors

    Czech Academy of Sciences Publication Activity Database

    McCleskey, M.; Mukhamedzhanov, A. M.; Trache, L.; Tribble, R. E.; Banu, A.; Eremenko, V.; Goldberg, V. Z.; Lui, Y. W.; McCleskey, E.; Roeder, B. T.; Spiridon, A.; Carstoiu, F.; Burjan, Václav; Hons, Zdeněk; Thompson, I. J.

    2014-01-01

    Roč. 89, č. 4 (2014), 044605 ISSN 0556-2813 R&D Projects: GA MŠk(CZ) LH11001 Institutional support: RVO:61389005 Keywords : capture reactions * cross-section * asymptotic normalization coefficient Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 3.733, year: 2014

  20. Availability program: Phase I report

    International Nuclear Information System (INIS)

    Thomson, S.L.; Dabiri, A.; Keeton, D.C.; Riemer, B.W.; Waganer, L.M.

    1985-05-01

    An Availability Working Group was formed within the Office of Fusion Energy in March 1984 to consider the establishment of an availability program for magnetic fusion. The scope of this program is defined to include the development of (1) a comprehensive data base, (2) empirical correlations, and (3) analytical methods for application to fusion facilities and devices. The long-term goal of the availability program is to develop a validated, integrated methodology that will provide (1) projections of plant availability and (2) input to design decisions on maintainability and system reliability requirements. The Phase I study group was commissioned to assess the status of work in progress that is relevant to the availability program. The scope of Phase I included surveys of existing data and data collection programs at operating fusion research facilities, the assessment of existing computer models to calculate system availability, and the review of methods to predict and correlate data on component failure and maintenance. The results of these investigations are reported to the Availability Working Group in this document

  1. Liquid phase sintered superconducting cermet

    International Nuclear Information System (INIS)

    Ray, S.P.

    1990-01-01

    This patent describes a method of making a superconducting cermet having superconducting properties with improved bulk density, low porosity and in situ stabilization. It comprises: forming a structure of a superconducting ceramic material having the formula RM 2 Cu 3 O (6.5 + x) wherein R is one or more rare earth elements capable of reacting to form a superconducting ceramic, M is one or more alkaline earth metal elements selected from barium and strontium capable of reacting to form a superconducting ceramic, x is greater than 0 and less than 0.5; and a precious metal compound in solid form selected from the class consisting of oxides, sulfides and halides of silver; and liquid phase sintering the mixture at a temperature wherein the precious metal of the precious metal compound is molten and below the melting point of the ceramic material. The liquid phase sintering is carried out for a time less than 36 hours but sufficient to improve the bulk density of the cermet

  2. Phase transition stability within ceramics

    International Nuclear Information System (INIS)

    Wang, E.; Wang, D.

    1992-01-01

    Irreversible thermodynamics is applied to analyse nucleation, both in metals and ceramics, in order to distinguish the stability of metastable under cooled melts. The hypothesis of local equilibrium has been used to apply research results from equilibrium thermodynamics, for the study of irreversible processes. The under cooling equation for homogenous nucleation only depends on a coefficient which is not related to the melting point of the material. The calculated critical under cooling values for metals are compared with experimental data. The metastable phase formation of plasma-sprayed alumina and zircon coatings has been discussed based on irreversible thermodynamics. A critical under cooling parameter (β) is defined. The metastable phase formation of plasma-sprayed alumina and zircon has been discussed. The analysis shows that γ-Al 2 O 3 is first formed in the coating since it has a lower β value than α-Al 2 O 3 . Zircon dissociates into ZrO 2 and SiO 2 , and rapid quenching of plasma spraying prevents their re association. The cooling rate determines whether t-ZrO 2 or c-ZrO 2 will form in the sprayed coating. It can be confirmed by the experiments that the content of t-ZrO 2 will increase correspondingly as the sprayed particle size decreases. At high transition temperatures, c-ZrO 2 will be formed because of the anisotropic thermal expansion behaviour in the crystal structure. 22 refs., 2 tabs

  3. Solid phase syntheses of oligoureas

    Energy Technology Data Exchange (ETDEWEB)

    Burgess, K.; Linthicum, D.S.; Russell, D.H.; Shin, H.; Shitangkoon, A.; Totani, R.; Zhang, A.J.; Ibarzo, J. [Texas A& M Univ., College Station, TX (United States)

    1997-02-19

    Isocyanates 7 were formed from monoprotected diamines 3 or 6, which in turn can be easily prepared from commercially available N-BOC- or N-FMOC-protected amino acid derivatives. Isocyanates 7, formed in situ, could be coupled directly to a solid support functionalized with amine groups or to amino acids anchored on resins using CH{sub 2}Cl{sub 2} as solvent and an 11 h coupling time at 25 {degree}C. Such couplings afforded peptidomimetics with an N-phthaloyl group at the N-terminus. The optimal conditions identified for removal of the N-phthaloyl group were to use 60% hydrazine in DMF for 1-3 h. Several sequences of amino acids coupled to ureas (`peptidic ureas`) and of sequential urea units (`oligoureas`) were prepared via solid phase syntheses and isolated by HPLC. Partition coefficients were measured for two of these peptidomimetics, and their water solubilities were found to be similar to the corresponding peptides. A small library of 160 analogues of the YGGFL-amide sequence was prepared via Houghten`s tea bag methodology. This library was tested for binding to the anti-{beta}-endorphin monoclonal antibody. Overall, this paper describes methodology for solid phase syntheses of oligourea derivatives with side chains corresponding to some of the protein amino acids. The chemistry involved is ideal for high-throughput syntheses and screening operations. 51 refs., 3 figs., 2 tabs.

  4. SARCOPENIA: DESIGNING PHASE IIB TRIALS

    Science.gov (United States)

    CHUMLEA, WM.C.; CESARI, M.; EVANS, W.J.; FERRUCCI, L.; FIELDING, R.A.; PAHOR, M.; STUDENSKI, S.; VELLAS, B.

    2012-01-01

    Sarcopenia is the age-related involuntary loss of skeletal muscle mass and functionality that can lead to the development of disability, frailty and increased health care costs. The development of interventions aimed at preventing and/or treating sarcopenia is complex, requiring the adoption of assumptions and standards that are not well established scientifically or clinically. A number of investigators and clinicians (both from academia and industry) met in Rome (Italy) in 2009 to develop a consensus definition of sarcopenia. Subsequently, in Albuquerque (New Mexico, USA) in 2010, the same group met again to consider the complex issues necessary for designing Phase II clinical trials for sarcopenia. Current clinical trial data indicate that fat-free mass (FFM) parameters are responsive to physical activity/nutritional treatment modalities over short time periods, but pharmacological trials of sarcopenia have yet to show significant efficacy. In order to conduct a clinical trial within a reasonable time frame, groups that model or display accelerated aging and loss of FFM are necessary. Few studies have used acceptable designs for testing treatment effects, sample sizes or primary outcomes that could provide interpretable findings or effects across studies. Dual energy x ray absorptiometry (DXA) is the measure of choice for assessing FFM, but sufficient time is needed for changes to be detected accurately and reliably. A tool set that would allow clinical, basic and epidemiological research on sarcopenia to advance rapidly toward diagnosis and treatment phases should be those reflecting function and strength. PMID:21623466

  5. Blending of phased array data

    Science.gov (United States)

    Duijster, Arno; van Groenestijn, Gert-Jan; van Neer, Paul; Blacquière, Gerrit; Volker, Arno

    2018-04-01

    The use of phased arrays is growing in the non-destructive testing industry and the trend is towards large 2D arrays, but due to limitations, it is currently not possible to record the signals from all elements, resulting in aliased data. In the past, we have presented a data interpolation scheme `beyond spatial aliasing' to overcome this aliasing. In this paper, we present a different approach: blending and deblending of data. On the hardware side, groups of receivers are blended (grouped) in only a few transmit/recording channels. This allows for transmission and recording with all elements, in a shorter acquisition time and with less channels. On the data processing side, this blended data is deblended (separated) by transforming it to a different domain and applying an iterative filtering and thresholding. Two different filtering methods are compared: f-k filtering and wavefield extrapolation filtering. The deblending and filtering methods are demonstrated on simulated experimental data. The wavefield extrapolation filtering proves to outperform f-k filtering. The wavefield extrapolation method can deal with groups of up to 24 receivers, in a phased array of 48 × 48 elements.

  6. RIMNET moves to phase 2

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    RIMNET (Radioactive Incident Monitoring Network) is the key element in the British government's National Response Plan, which was established in the wake of the Chernobyl accident. It raises an alert if abnormal radioactivity increases are detected and provides a national communications system through which it is intended to give information and advice rapidly to the public, local authorities and other interested parties. In the event of an overseas nuclear accident with potential consequences for the UK, a technical co-ordination centre would be convened which would have at its disposal a pre-established database to hold the radiological data that would need to be collected at the time of the incident to assess its impact. Phase 1 of RIMET has been operating since 1988. It uses manually read radiation monitors. The second phase consists of: doubling the number of monitoring sites from 46 to 92; fully automating data analysis and collection; and providing more powerful information systems and friendly displays to help those advising and informing the public. Those supplying data to the system, for example on foodstuff analysis, will do so via portable computers, and only minimum manual intervention will be required from those using the system to support incident response. The end result should be one of the most advanced systems of its kind in the world, giving continuous automated monitoring of radioactivity levels throughout the UK and integrating the data with meteorological information to predict the effect of incidents. (author)

  7. Phase-exchange thermoacoustic engine

    Science.gov (United States)

    Offner, Avshalom; Meir, Avishai; Ramon, Guy Z.; WET Lab Team

    2017-11-01

    Phase-exchange thermoacoustic engines are reliable machines holding great promise in converting heat from low grade heat sources to mechanical or electrical power. In these engines the working fluid is a gas mixture containing one condensable component, decreasing the temperature difference required for ignition and steady state operation. Our experimental setup consists of a vertical acoustic resonator containing a mixture of air-water vapor. Water evaporates near the heat source, condenses at the heat sink and is drawn back down by gravity and capillary forces where it re-evaporates, sustaining a steady state closed thermodynamic cycle. We investigated the stability limit, namely the critical point at which temperature difference in the engine enables onset of self-excited oscillations, and the steady state of the engine. A simple theoretical model was derived, describing mechanisms of irreversible entropy generation and production of acoustic power in such engines. This model captures the essence in the differences between regular and phase-exchange thermoacoustic engines, and shows good agreement with experimental results of stability limit. Steady state results reveal not only a dramatic decrease in temperature difference, but also an increase in engine performances. The authors acknowledge the support from the Nancy and Stephen Grand Technion Energy Program (GTEP).

  8. Electrostatic Effects in Phase Transitions of Biomembranes between Cubic Phases and Lamellar Liquid-Crystalline (Lα) phase

    Science.gov (United States)

    Masum, Shah Md.; Li, Shu Jie; Tamba, Yukihiro; Yamashita, Yuko; Yamazaki, Masahito

    2004-04-01

    Elucidation of the mechanisms of transitions between cubic phase and liquid-crystalline (Lα) phase, and between different IPMS cubic phases, are essential for understanding of dynamics of biomembranes and topological transformation of lipid membranes. Recently, we found that electrostatic interactions due to surface charges of lipid membranes induce transition between cubic phase and Lα phase, and between different IPMS cubic phases. As electrostatic interactions increase, the most stable phase of a monoolein (MO) membrane changes: Q224 ⇒ Q229 ⇒ Lα. We also found that a de novo designed peptide partitioning into electrically neutral lipid membrane changed the phase stability of the MO membranes. As peptide-1 concentration increased, the most stable phase of a MO membrane changes: Q224 ⇒ Q229 ⇒Lα. In both cases, the increase in the electrostatic repulsive interaction greatly reduced the absolute value of spontaneous curvature of the MO monolayer membrane. We also investigated factors such as poly (L-lysine) and osmotic stress to control structure and phase stability of DOPA/MO membranes. Based on these results, we discuss the mechanism of the effect of electrostatic interactions on the stability of cubic phase.

  9. Symmetric Topological Phases and Tensor Network States

    Science.gov (United States)

    Jiang, Shenghan

    Classification and simulation of quantum phases are one of main themes in condensed matter physics. Quantum phases can be distinguished by their symmetrical and topological properties. The interplay between symmetry and topology in condensed matter physics often leads to exotic quantum phases and rich phase diagrams. Famous examples include quantum Hall phases, spin liquids and topological insulators. In this thesis, I present our works toward a more systematically understanding of symmetric topological quantum phases in bosonic systems. In the absence of global symmetries, gapped quantum phases are characterized by topological orders. Topological orders in 2+1D are well studied, while a systematically understanding of topological orders in 3+1D is still lacking. By studying a family of exact solvable models, we find at least some topological orders in 3+1D can be distinguished by braiding phases of loop excitations. In the presence of both global symmetries and topological orders, the interplay between them leads to new phases termed as symmetry enriched topological (SET) phases. We develop a framework to classify a large class of SET phases using tensor networks. For each tensor class, we can write down generic variational wavefunctions. We apply our method to study gapped spin liquids on the kagome lattice, which can be viewed as SET phases of on-site symmetries as well as lattice symmetries. In the absence of topological order, symmetry could protect different topological phases, which are often referred to as symmetry protected topological (SPT) phases. We present systematic constructions of tensor network wavefunctions for bosonic symmetry protected topological (SPT) phases respecting both onsite and spatial symmetries.

  10. Theoretical description of the properties of magnetization fluctuations in the vicinity of phase transition from paramagnetic phase to ferromagnetic phase with domain structure

    International Nuclear Information System (INIS)

    Wasilewski, W.

    1983-08-01

    This paper presents a theoretical description of the phase transition from a paramagnetic phase P to the homogeneous and domain structure ferromagnetic phases within the phenomenological theory of phase transitions

  11. The geometric phase in quantum physics

    International Nuclear Information System (INIS)

    Bohm, A.

    1993-03-01

    After an explanatory introduction, a quantum system in a classical time-dependent environment is discussed; an example is a magnetic moment in a classical magnetic field. At first, the general abelian case is discussed in the adiabatic approximation. Then the geometric phase for nonadiabatic change of the environment (Anandan--Aharonov phase) is introduced, and after that general cyclic (nonadiabatic) evolution is discussed. The mathematics of fiber bundles is introduced, and some of its results are used to describe the relation between the adiabatic Berry phase and the geometric phase for general cyclic evolution of a pure state. The discussion is restricted to the abelian, U(1) phase

  12. Measuring secondary phases in duplex stainless steels

    Science.gov (United States)

    Calliari, I.; Brunelli, K.; Dabalà, M.; Ramous, E.

    2009-01-01

    The use of duplex stainless steels is limited by their susceptibility to the formation of dangerous intermetallic phases resulting in detrimental effects on impact toughness and corrosion resistance. This precipitation and the quantitative determinations of the phases have received considerable attention and different precipitation sequences (σ phase, χ phase, and carbides) have been suggested. This study investigates the phase transformation during continuous cooling and isothermal treatments in commercial duplex stainless steel grades and the effects on alloy properties, and compares the most common techniques of analysis.

  13. Li-ion batteries: Phase transition

    International Nuclear Information System (INIS)

    Hou Peiyu; Zhang Yantao; Zhang Lianqi; Chu Geng; Gao Jian

    2016-01-01

    Progress in the research on phase transitions during Li + extraction/insertion processes in typical battery materials is summarized as examples to illustrate the significance of understanding phase transition phenomena in Li-ion batteries. Physical phenomena such as phase transitions (and resultant phase diagrams) are often observed in Li-ion battery research and already play an important role in promoting Li-ion battery technology. For example, the phase transitions during Li + insertion/extraction are highly relevant to the thermodynamics and kinetics of Li-ion batteries, and even physical characteristics such as specific energy, power density, volume variation, and safety-related properties. (topical review)

  14. Quantum phase from s-parametrized quasidistributions

    International Nuclear Information System (INIS)

    Perinova, V; Luks, A

    2005-01-01

    It is familiar that a well behaved operator of the harmonic oscillator phase does not exist. Therefore, Turski's phase operator and the operator of Garrison and Wong may be at most defined in an interesting fashion and yield useful quantum expectation values. In this paper we touch on a recent incomplete definition of a phase operator which has also failed in the respect that it can be completed only to a definition of an 'incomplete' phase operator. We discuss, however, a possibility of completion of the definition and a relationship to the phase operator from an s-parametrized quasidistribution

  15. Intermolecular interactions in the condensed phase

    DEFF Research Database (Denmark)

    Christensen, Anders S.; Kromann, Jimmy Charnley; Jensen, Jan Halborg

    2017-01-01

    To facilitate further development of approximate quantum mechanical methods for condensed phase applications, we present a new benchmark dataset of intermolecular interaction energies in the solution phase for a set of 15 dimers, each containing one charged monomer. The reference interaction energy...... and solution phases. As most approximate QM methods are parametrized and evaluated using data measured or calculated in the gas phase, the dataset represents an important first step toward calibrating QM based methods for application in the condensed phase where polarization and exchange repulsion need...

  16. Cell-cycle phase specificity of chloroethylnitrosoureas

    International Nuclear Information System (INIS)

    Linfoot, P.A.

    1986-01-01

    Although the cancer chemotherapeutic agent 1,3-bis(2-chloroethyl)-1-nitrosourea (BCNU) is considered a non-cell cycle phase specific drug, it has been shown to produce differential cell killing in G 1 , S, and G 2 /M phase cells, with S phase cells appearing relatively resistant. Studies of cell cycle phase specific cell killing produced by nitrosoureas with different chemical reactivities, clearly indicated that the ability of compounds to cross-link DNA was important in determining their phase specificity. Cells that lacked guanine O 6 -alkytransferase activity showed similar patterns of BCNU phase specificity regardless of their intrinsic sensitivity to BCNU. DNA inter-strand cross-linking, as measured by alkaline elution, was similar in cells exposed to BCNU in G 1 or S phase. 3 H [1-chloroethyl-1nitrosourea] binding to DNA was the same in G 1 , S and G 2 /M phase cells indicating that phase-specific differences in drug uptake and intracellular drug dose were not responsible for phase specific cell kill. These studies suggest that cross-link lesions, other than DNA inter-strand cross-links, and/or effects on DNA repair, other than guanine O 6 -alkyltransferase, are additional important determinants of BCNU phase specific cell killing

  17. Multiple topological phases in phononic crystals

    KAUST Repository

    Chen, Zeguo; Wu, Ying

    2017-01-01

    We report a new topological phononic crystal in a ring-waveguide acoustic system. In the previous reports on topological phononic crystals, there are two types of topological phases: quantum Hall phase and quantum spin Hall phase. A key point in achieving quantum Hall insulator is to break the time-reversal (TR) symmetry, and for quantum spin Hall insulator, the construction of pseudo-spin is necessary. We build such pseudo-spin states under particular crystalline symmetry (C-6v) and then break the degeneracy of the pseudo-spin states by introducing airflow to the ring. We study the topology evolution by changing both the geometric parameters of the unit cell and the strength of the applied airflow. We find that the system exhibits three phases: quantum spin Hall phase, conventional insulator phase and a new quantum anomalous Hall phase.

  18. The eigenvalue problem in phase space.

    Science.gov (United States)

    Cohen, Leon

    2018-06-30

    We formulate the standard quantum mechanical eigenvalue problem in quantum phase space. The equation obtained involves the c-function that corresponds to the quantum operator. We use the Wigner distribution for the phase space function. We argue that the phase space eigenvalue equation obtained has, in addition to the proper solutions, improper solutions. That is, solutions for which no wave function exists which could generate the distribution. We discuss the conditions for ascertaining whether a position momentum function is a proper phase space distribution. We call these conditions psi-representability conditions, and show that if these conditions are imposed, one extracts the correct phase space eigenfunctions. We also derive the phase space eigenvalue equation for arbitrary phase space distributions functions. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  19. Synthesizing lattice structures in phase space

    International Nuclear Information System (INIS)

    Guo, Lingzhen; Marthaler, Michael

    2016-01-01

    In one dimensional systems, it is possible to create periodic structures in phase space through driving, which is called phase space crystals (Guo et al 2013 Phys. Rev. Lett. 111 205303). This is possible even if for particles trapped in a potential without periodicity. In this paper we discuss ultracold atoms in a driven optical lattice, which is a realization of such a phase space crystals. The corresponding lattice structure in phase space is complex and contains rich physics. A phase space lattice differs fundamentally from a lattice in real space, because its coordinate system, i.e., phase space, has a noncommutative geometry, which naturally provides an artificial gauge (magnetic) field. We study the behavior of the quasienergy band structure and investigate the dissipative dynamics. Synthesizing lattice structures in phase space provides a new platform to simulate the condensed matter phenomena and study the intriguing phenomena of driven systems far away from equilibrium. (paper)

  20. Power inverter implementing phase skipping control

    Science.gov (United States)

    Somani, Utsav; Amirahmadi, Ahmadreza; Jourdan, Charles; Batarseh, Issa

    2016-10-18

    A power inverter includes a DC/AC inverter having first, second and third phase circuitry coupled to receive power from a power source. A controller is coupled to a driver for each of the first, second and third phase circuitry (control input drivers). The controller includes an associated memory storing a phase skipping control algorithm, wherein the controller is coupled to receive updating information including a power level generated by the power source. The drivers are coupled to control inputs of the first, second and third phase circuitry, where the drivers are configured for receiving phase skipping control signals from the controller and outputting mode selection signals configured to dynamically select an operating mode for the DC/AC inverter from a Normal Control operation and a Phase Skipping Control operation which have different power injection patterns through the first, second and third phase circuitry depending upon the power level.

  1. Multiple topological phases in phononic crystals

    KAUST Repository

    Chen, Zeguo

    2017-11-20

    We report a new topological phononic crystal in a ring-waveguide acoustic system. In the previous reports on topological phononic crystals, there are two types of topological phases: quantum Hall phase and quantum spin Hall phase. A key point in achieving quantum Hall insulator is to break the time-reversal (TR) symmetry, and for quantum spin Hall insulator, the construction of pseudo-spin is necessary. We build such pseudo-spin states under particular crystalline symmetry (C-6v) and then break the degeneracy of the pseudo-spin states by introducing airflow to the ring. We study the topology evolution by changing both the geometric parameters of the unit cell and the strength of the applied airflow. We find that the system exhibits three phases: quantum spin Hall phase, conventional insulator phase and a new quantum anomalous Hall phase.

  2. 13C, 15N Resonance Assignment of Parts of the HET-s Prion Protein in its Amyloid Form

    International Nuclear Information System (INIS)

    Siemer, Ansgar B.; Ritter, Christiane; Steinmetz, Michel O.; Ernst, Matthias; Riek, Roland; Meier, Beat H.

    2006-01-01

    The partial 15 N and 13 C solid-state NMR resonance assignment of the HET-s prion protein fragment 218-289 in its amyloid form is presented. It is based on experiments measured at MAS frequencies in the range of 20-40 kHz using exclusively adiabatic polarization-transfer schemes. The resonance assignment within each residue is based on two-dimensional 13 C-- 13 C correlation spectra utilizing the DREAM mixing scheme. The sequential linking of the assigned residues used a set of two- and three-dimensional 15 N-- 13 C correlation experiments. Almost all cross peaks visible in the spectra are assigned, but only resonances from 43 of the 78 amino-acid residues could be detected. The missing residues are thought to be highly disordered and/or highly dynamic giving rise to broad resonance lines that escaped detection in the experiments applied. The line widths of the observed resonances are narrow and comparable to line widths observed in micro-crystalline samples. The 43 assigned residues are located in two fragments of about 20 residues

  3. 15C-15F Charge Symmetry and the 14C(n,γ)15C Reaction Puzzle

    International Nuclear Information System (INIS)

    Timofeyuk, N.K.; Thompson, I.J.; Baye, D.; Descouvemont, P.; Kamouni, R.

    2006-01-01

    The low-energy reaction 14 C(n,γ) 15 C provides a rare opportunity to test indirect methods for the determination of neutron capture cross sections by radioactive isotopes versus direct measurements. It is also important for various astrophysical scenarios. Currently, puzzling disagreements exist between the 14 C(n,γ) 15 C cross sections measured directly, determined indirectly, and calculated theoretically. To solve this puzzle, we offer a strong test based on a novel idea that the amplitudes for the virtual 15 C→ 14 C+n and the real 15 F→ 14 O+p decays are related. Our study of this relation, performed in a microscopic model, shows that existing direct and some indirect measurements strongly contradict charge symmetry in the 15 C and 15 F mirror pair. This brings into question the experimental determinations of the astrophysically important (n,γ) cross sections for short-lived radioactive targets

  4. SU-F-18C-15: Model-Based Multiscale Noise Reduction On Low Dose Cone Beam Projection

    International Nuclear Information System (INIS)

    Yao, W; Farr, J

    2014-01-01

    Purpose: To improve image quality of low dose cone beam CT for patient positioning in radiation therapy. Methods: In low dose cone beam CT (CBCT) imaging systems, Poisson process governs the randomness of photon fluence at x-ray source and the detector because of the independent binomial process of photon absorption in medium. On a CBCT projection, the variance of fluence consists of the variance of noiseless imaging structure and that of Poisson noise, which is proportional to the mean (noiseless) of the fluence at the detector. This requires multiscale filters to smoothen noise while keeping the structure information of the imaged object. We used a mathematical model of Poisson process to design multiscale filters and established the balance of noise correction and structure blurring. The algorithm was checked with low dose kilo-voltage CBCT projections acquired from a Varian OBI system. Results: From the investigation of low dose CBCT of a Catphan phantom and patients, it showed that our model-based multiscale technique could efficiently reduce noise and meanwhile keep the fine structure of the imaged object. After the image processing, the number of visible line pairs in Catphan phantom scanned with 4 ms pulse time was similar to that scanned with 32 ms, and soft tissue structure from simulated 4 ms patient head-and-neck images was also comparable with scanned 20 ms ones. Compared with fixed-scale technique, the image quality from multiscale one was improved. Conclusion: Use of projection-specific multiscale filters can reach better balance on noise reduction and structure information loss. The image quality of low dose CBCT can be improved by using multiscale filters

  5. General aspects of the cyclotrons and radiochemical separation of: 11 C, 15 O, 18 F and 14 N

    International Nuclear Information System (INIS)

    Alanis M, J.

    1997-07-01

    The particle accelerators, as the cyclotrons, are extraordinarily important as tools for the radioisotope production and its application in the area of the medicine. In this time, another method exists for the production of artificial radioisotopes, based on the irradiation of samples with alpha particles or with neutrons coming from a natural radioisotope being obtained a neutron source (Ra + Be, Rn + Be, Po + Be). However, its can be obtained a great quantity of radioisotopes by means of cyclotrons in very short time, compared with other methods. After the second world war, artificial radioisotopes took place by means of reactors and its had many applications, not only medical and in little time the accelerators were manufactured that were more indispensable that the reactors to produce radioisotopes with medical aims. For this reason, the accelerators, in few years became in machines very important for the production of artificial radioisotopes and consequently its were developed techniques of radioactive traces progressively more sophisticated, since it is evident that the production of radioactive nuclei through nuclear reactors its cannot satisfy all the demands. In general terms, only the neutrons can be used as nuclear projectiles in reactors and as a result, the production spectra of radioisotopes is limited and as alternative it is unavoidable that the cyclotrons are a good tool for this end. The use of a cyclotron to produce radioisotopes, it can be justified, only if the following conditions are completed. 1. If the radioisotopes of an element produced in a reactor don't favor with the nuclear properties for the purposes of the traced studies, for example: if the half life is very short or very big, if the decay system not to suit him. 2. If the wanted radioisotope cannot produce in the reactor with enough specific activity. (Author)

  6. The development of the EORTC QLQ-C15-PAL: a shortened questionnaire for cancer patients in palliative care

    NARCIS (Netherlands)

    Groenvold, Mogens; Petersen, Morten Aa; Aaronson, Neil K.; Arraras, Juan I.; Blazeby, Jane M.; Bottomley, Andrew; Fayers, Peter M.; de Graeff, Alexander; Hammerlid, Eva; Kaasa, Stein; Sprangers, Mirjam A. G.; Bjorner, Jakob B.

    2006-01-01

    This study aimed at developing a shortened version of the EORTC QLQ-C30, one of the most widely used health-related quality of life questionnaires in oncology, for palliative care research. The study included interviews with 41 patients and 66 health care professionals in palliative care to

  7. Speedup of minimum discontinuity phase unwrapping algorithm with a reference phase distribution

    Science.gov (United States)

    Liu, Yihang; Han, Yu; Li, Fengjiao; Zhang, Qican

    2018-06-01

    In three-dimensional (3D) shape measurement based on phase analysis, the phase analysis process usually produces a wrapped phase map ranging from - π to π with some 2 π discontinuities, and thus a phase unwrapping algorithm is necessary to recover the continuous and nature phase map from which 3D height distribution can be restored. Usually, the minimum discontinuity phase unwrapping algorithm can be used to solve many different kinds of phase unwrapping problems, but its main drawback is that it requires a large amount of computations and has low efficiency in searching for the improving loop within the phase's discontinuity area. To overcome this drawback, an improvement to speedup of the minimum discontinuity phase unwrapping algorithm by using the phase distribution on reference plane is proposed. In this improved algorithm, before the minimum discontinuity phase unwrapping algorithm is carried out to unwrap phase, an integer number K was calculated from the ratio of the wrapped phase to the nature phase on a reference plane. And then the jump counts of the unwrapped phase can be reduced by adding 2K π, so the efficiency of the minimum discontinuity phase unwrapping algorithm is significantly improved. Both simulated and experimental data results verify the feasibility of the proposed improved algorithm, and both of them clearly show that the algorithm works very well and has high efficiency.

  8. Three-Phase and Six-Phase AC at the Lab Bench

    Science.gov (United States)

    Caplan, George M.

    2009-01-01

    Utility companies generate three-phase electric power, which consists of three sinusoidal voltages with phase angles of 0 degrees, 120 degrees, and 240 degrees. The ac generators described in most introductory textbooks are single-phase generators, so physics students are not likely to learn about three-phase power. I have developed a simple way…

  9. Adaptive ground implemented phase array

    Science.gov (United States)

    Spearing, R. E.

    1973-01-01

    The simulation of an adaptive ground implemented phased array of five antenna elements is reported for a very high frequency system design that is tolerant to the radio frequency interference environment encountered by a tracking data relay satellite. Signals originating from satellites are received by the VHF ring array and both horizontal and vertical polarizations from each of the five elements are multiplexed and transmitted down to ground station. A panel on the transmitting end of the simulation chamber contains up to 10 S-band RFI sources along with the desired signal to simulate the dynamic relationship between user and TDRS. The 10 input channels are summed, and desired and interference signals are separated and corrected until the resultant sum signal-to-interference ratio is maximized. Testing performed with this simulation equipment demonstrates good correlation between predicted and actual results.

  10. Beyond the random phase approximation

    DEFF Research Database (Denmark)

    Olsen, Thomas; Thygesen, Kristian S.

    2013-01-01

    We assess the performance of a recently proposed renormalized adiabatic local density approximation (rALDA) for ab initio calculations of electronic correlation energies in solids and molecules. The method is an extension of the random phase approximation (RPA) derived from time-dependent density...... functional theory and the adiabatic connection fluctuation-dissipation theorem and contains no fitted parameters. The new kernel is shown to preserve the accurate description of dispersive interactions from RPA while significantly improving the description of short-range correlation in molecules, insulators......, and metals. For molecular atomization energies, the rALDA is a factor of 7 better than RPA and a factor of 4 better than the Perdew-Burke-Ernzerhof (PBE) functional when compared to experiments, and a factor of 3 (1.5) better than RPA (PBE) for cohesive energies of solids. For transition metals...

  11. Multiparametric quantum symplectic phase space

    International Nuclear Information System (INIS)

    Parashar, P.; Soni, S.K.

    1992-07-01

    We formulate a consistent multiparametric differential calculus on the quadratic coordinate algebra of the quantum vector space and use this as a tool to obtain a deformation of the associated symplectic phase space involving n(n-1)/2+1 deformation parameters. A consistent calculus on the relation subspace is also constructed. This is achieved with the help of a restricted ansatz and solving the consistency conditions to directly arrive at the main commutation structures without any reference to the R-matrix. However, the non-standard R-matrices for GL r,qij (n) and Sp r,qij (2n) can be easily read off from the commutation relations involving coordinates and derivatives. (author). 9 refs

  12. Nuclear dynamics in phase space

    International Nuclear Information System (INIS)

    Di Toro, M.

    1984-07-01

    We present a unified semiclassical picture of nuclear dynamics, from collective states to heavy ion physics, based on a study of the time evolution of the Wigner distribution function. We discuss in particular the mean field dynamics, in this ''quantal'' phase space, which is ruled by the nuclear Vlasov equation. Simple approximate solutions are worked out for rotational and vibrational collective motions. Giant resonances are shown to be quite well described as scaling modes, which are equivalent to a lowest multipole (up to 1sub(max)=2) distortions of the momentum distribution. Applications are shown to heavy ion physics to study giant resonances on high spin states and dynamical collective effects in subthreshold π-production. Several possible extensions and in particular the inclusion of two-body collision terms are finally discussed

  13. Oscillatory two-phase flows

    International Nuclear Information System (INIS)

    Boure, J.A.

    1974-12-01

    Two-phase flow instabilities are classified according to three criteria: the static or dynamic nature of the phenomenon, the necessity or not of a triggering phenomenon, and the pure or compound character of the phenomenon. Tables give the elementary instability phenomena, and the practical types of instability. Flow oscillations (or dynamic instabilities) share a number of characteristics which are dealt with, they are caused by the dynamic interactions between the flow parameters (flow rate, density, pressure, enthalpy and their distributions). Oscillation types are discussed: pure oscillations are density wave oscillations, acoustic oscillations may also occur, various compound oscillations involve either the density wave or the acoustic wave mechanism, interacting with some of the boundary conditions in the device. The analysis of slow oscillations has been made either by means of a simplified model (prediction of the thresholds) or of computer codes. Numerous computer codes are available [fr

  14. Two phase titanium aluminide alloy

    Science.gov (United States)

    Deevi, Seetharama C.; Liu, C. T.

    2001-01-01

    A two-phase titanic aluminide alloy having a lamellar microstructure with little intercolony structures. The alloy can include fine particles such as boride particles at colony boundaries and/or grain boundary equiaxed structures. The alloy can include alloying additions such as .ltoreq.10 at % W, Nb and/or Mo. The alloy can be free of Cr, V, Mn, Cu and/or Ni and can include, in atomic %, 45 to 55% Ti, 40 to 50% Al, 1 to 5% Nb, 0.3 to 2% W, up to 1% Mo and 0.1 to 0.3% B. In weight %, the alloy can include 57 to 60% Ti, 30 to 32% Al, 4 to 9% Nb, up to 2% Mo, 2 to 8% W and 0.02 to 0.08% B.

  15. Polymers in phase change materials

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, M.C.; Brites, M.J.; Alexandre, J.H. [National Lab. for Energy and Geology, Lisbon (Portugal)

    2010-07-01

    Phase Change Materials (PCMs) which are the core of latent heat thermal energy storage systems are currently an area of investigation of increasing interest. Several substances differing in physical and chemical characteristics as well as in thermal behavior have been studied as PCMS{sup 1-3}. In order to meet the requisites of particular systems, auxiliary materials are often used with specific functions. This bibliographic survey shows that polymeric materials have been proposed either as the PCM itself in solid-liquid or solid-solid transitions or to perform auxiliary functions of shape stabilisation and microencapsulation for solid-liquid PCMs. The PCMs have an operating temperature ranging from around 0 C (for the system water/polyacrilamid) to around 127 C (for crosslinked HDPE). (orig.)

  16. Hydrogen atom in phase space

    International Nuclear Information System (INIS)

    Chetouani, L.; Hammann, T.F.

    1987-01-01

    The Hamiltonian of the three-dimensional hydrogen atom is reduced, in parabolic coordinates, to the Hamiltonians of two bidimensional harmonic oscillators, by doing several space-time transformations,separating the movement along the three parabolic directions (ξ,eta,phi), and introducing two auxiliary angular variables psi and psi', 0≤psi, psi'≤2π. The Green's function is developed into partial Green's functions, and expressed in terms of two Green's functions that describe the movements along both the ξ and eta axes. Introducing auxiliary Hamiltonians allows one to calculate the Green's function in the configurational space, via the phase-space evolution function of the two-dimensional harmonic oscillator. The auxiliary variables psi and psi' are eliminated by projection. The thus-obtained Green's function, save for a multiplicating factor, coincides with that calculated following the path-integral formalism

  17. Poisson's spot and Gouy phase

    Science.gov (United States)

    da Paz, I. G.; Soldati, Rodolfo; Cabral, L. A.; de Oliveira, J. G. G.; Sampaio, Marcos

    2016-12-01

    Recently there have been experimental results on Poisson spot matter-wave interferometry followed by theoretical models describing the relative importance of the wave and particle behaviors for the phenomenon. We propose an analytical theoretical model for Poisson's spot with matter waves based on the Babinet principle, in which we use the results for free propagation and single-slit diffraction. We take into account effects of loss of coherence and finite detection area using the propagator for a quantum particle interacting with an environment. We observe that the matter-wave Gouy phase plays a role in the existence of the central peak and thus corroborates the predominantly wavelike character of the Poisson's spot. Our model shows remarkable agreement with the experimental data for deuterium (D2) molecules.

  18. Phase I Final Scientific Report

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Xijia [National Energy Technology Lab. (NETL), Albany, OR (United States); Fetvedt, Jeremy [National Energy Technology Lab. (NETL), Albany, OR (United States); Dimmig, Walker [National Energy Technology Lab. (NETL), Albany, OR (United States)

    2017-10-15

    This Final Scientific Report addresses the accomplishments achieved during Phase I of DE- FE0023985, Coal Syngas Combustor Development for Supercritical CO2 Power Cycles. The primary objective of the project was to develop a coal syngas-fueled combustor design for use with high-pressure, high-temperature, oxy-fuel, supercritical CO2 power cycles, with particular focus given to the conditions required by the Allam Cycle. The primary goals, from the Statement of Project Objectives, were to develop: (1) a conceptual design of a syngas-fueled combustor-turbine block for a 300MWe high-pressure, oxy-fuel, sCO2 power plant; (2) the preliminary design of a 5MWt test combustor; and (3) the definition of a combustor test program. Accomplishments for each of these goals are discussed in this report.

  19. Machine Phase Fullerene Nanotechnology: 1996

    Science.gov (United States)

    Globus, Al; Chancellor, Marisa K. (Technical Monitor)

    1997-01-01

    NASA has used exotic materials for spacecraft and experimental aircraft to good effect for many decades. In spite of many advances, transportation to space still costs about $10,000 per pound. Drexler has proposed a hypothetical nanotechnology based on diamond and investigated the properties of such molecular systems. These studies and others suggest enormous potential for aerospace systems. Unfortunately, methods to realize diamonoid nanotechnology are at best highly speculative. Recent computational efforts at NASA Ames Research Center and computation and experiment elsewhere suggest that a nanotechnology of machine phase functionalized fullerenes may be synthetically relatively accessible and of great aerospace interest. Machine phase materials are (hypothetical) materials consisting entirely or in large part of microscopic machines. In a sense, most living matter fits this definition. To begin investigation of fullerene nanotechnology, we used molecular dynamics to study the properties of carbon nanotube based gears and gear/shaft configurations. Experiments on C60 and quantum calculations suggest that benzyne may react with carbon nanotubes to form gear teeth. Han has computationally demonstrated that molecular gears fashioned from (14,0) single-walled carbon nanotubes and benzyne teeth should operate well at 50-100 gigahertz. Results suggest that rotation can be converted to rotating or linear motion, and linear motion may be converted into rotation. Preliminary results suggest that these mechanical systems can be cooled by a helium atmosphere. Furthermore, Deepak has successfully simulated using helical electric fields generated by a laser to power fullerene gears once a positive and negative charge have been added to form a dipole. Even with mechanical motion, cooling, and power; creating a viable nanotechnology requires support structures, computer control, a system architecture, a variety of components, and some approach to manufacture. Additional

  20. Accelerated Adaptive MGS Phase Retrieval

    Science.gov (United States)

    Lam, Raymond K.; Ohara, Catherine M.; Green, Joseph J.; Bikkannavar, Siddarayappa A.; Basinger, Scott A.; Redding, David C.; Shi, Fang

    2011-01-01

    The Modified Gerchberg-Saxton (MGS) algorithm is an image-based wavefront-sensing method that can turn any science instrument focal plane into a wavefront sensor. MGS characterizes optical systems by estimating the wavefront errors in the exit pupil using only intensity images of a star or other point source of light. This innovative implementation of MGS significantly accelerates the MGS phase retrieval algorithm by using stream-processing hardware on conventional graphics cards. Stream processing is a relatively new, yet powerful, paradigm to allow parallel processing of certain applications that apply single instructions to multiple data (SIMD). These stream processors are designed specifically to support large-scale parallel computing on a single graphics chip. Computationally intensive algorithms, such as the Fast Fourier Transform (FFT), are particularly well suited for this computing environment. This high-speed version of MGS exploits commercially available hardware to accomplish the same objective in a fraction of the original time. The exploit involves performing matrix calculations in nVidia graphic cards. The graphical processor unit (GPU) is hardware that is specialized for computationally intensive, highly parallel computation. From the software perspective, a parallel programming model is used, called CUDA, to transparently scale multicore parallelism in hardware. This technology gives computationally intensive applications access to the processing power of the nVidia GPUs through a C/C++ programming interface. The AAMGS (Accelerated Adaptive MGS) software takes advantage of these advanced technologies, to accelerate the optical phase error characterization. With a single PC that contains four nVidia GTX-280 graphic cards, the new implementation can process four images simultaneously to produce a JWST (James Webb Space Telescope) wavefront measurement 60 times faster than the previous code.

  1. A Novel Phase-Locking-Free Phase Sensitive Amplifier based Regenerator

    DEFF Research Database (Denmark)

    Kjøller, Niels-Kristian; Røge, Kasper Meldgaard; Guan, Pengyu

    2016-01-01

    We propose a scheme for phase regeneration of optical binary phase-shift keying (BPSK) data signals based on phase sensitive amplification without active phase-locking. A delay interferometer (DI) is used to convert a BPSK signal impaired by noise to an amplitude modulated signal followed by cross......-locked pumps. As a result, active phase-stabilization is avoided. A proof-of-principle experiment is carried out with a dual-pump degenerate phase sensitive amplifier (PSA), demonstrating regeneration for a 10 Gb/s non-return-to-zero differential BPSK (NRZ-DPSK) data signal degraded by a sinusoidal phase...

  2. Measurement of phase interaction in dispersed gas-particle two-phase flow by phase-doppler anemometry

    Directory of Open Access Journals (Sweden)

    Mergheni Ali Mohamed

    2008-01-01

    Full Text Available For simultaneous measurement of size and velocity distributions of continuous and dispersed phases in a two-phase flow a technique phase-Doppler anemometry was used. Spherical glass particles with a particle diameter range from 102 up to 212 µm were used. In this two-phase flow an experimental results are presented which indicate a significant influence of the solid particles on the flow characteristics. The height of influence of these effects depends on the local position in the jet. Near the nozzle exit high gas velocity gradients exist and therefore high turbulence production in the shear layer of the jet is observed. Here the turbulence intensity in the two-phase jet is decreased compared to the single-phase jet. In the developed zone the velocity gradient in the shear layer is lower and the turbulence intensity reduction is higher. .

  3. Using the phase-space imager to analyze partially coherent imaging systems: bright-field, phase contrast, differential interference contrast, differential phase contrast, and spiral phase contrast

    Science.gov (United States)

    Mehta, Shalin B.; Sheppard, Colin J. R.

    2010-05-01

    Various methods that use large illumination aperture (i.e. partially coherent illumination) have been developed for making transparent (i.e. phase) specimens visible. These methods were developed to provide qualitative contrast rather than quantitative measurement-coherent illumination has been relied upon for quantitative phase analysis. Partially coherent illumination has some important advantages over coherent illumination and can be used for measurement of the specimen's phase distribution. However, quantitative analysis and image computation in partially coherent systems have not been explored fully due to the lack of a general, physically insightful and computationally efficient model of image formation. We have developed a phase-space model that satisfies these requirements. In this paper, we employ this model (called the phase-space imager) to elucidate five different partially coherent systems mentioned in the title. We compute images of an optical fiber under these systems and verify some of them with experimental images. These results and simulated images of a general phase profile are used to compare the contrast and the resolution of the imaging systems. We show that, for quantitative phase imaging of a thin specimen with matched illumination, differential phase contrast offers linear transfer of specimen information to the image. We also show that the edge enhancement properties of spiral phase contrast are compromised significantly as the coherence of illumination is reduced. The results demonstrate that the phase-space imager model provides a useful framework for analysis, calibration, and design of partially coherent imaging methods.

  4. Symmetry and Phase Transitions in Nuclei

    International Nuclear Information System (INIS)

    Iachello, F.

    2009-01-01

    Phase transitions in nuclei have received considerable attention in recent years, especially after the discovery that, contrary to expectations, systems at the critical point of a phase transition display a simple structure. In this talk, quantum phase transitions (QPT), i.e. phase transitions that occur as a function of a coupling constant that appears in the quantum Hamiltonian, H, describing the system, will be reviewed and experimental evidence for their occurrence in nuclei will be presented. The phase transitions discussed in the talk will be shape phase transitions. Different shapes have different symmetries, classified by the dynamic symmetries of the Interacting Boson Model, U(5), SU(3) and SO(6). Very recently, the concept of Quantum Phase Transitions has been extended to Excited State Quantum Phase Transitions (ESQPT). This extension will be discussed and some evidence for incipient ESQPT in nuclei will be presented. Systems at the critical point of a phase transition are called 'critical systems'. Approximate analytic formulas for energy spectra and other properties of 'critical nuclei', in particular for nuclei at the critical point of the second order U(5)-SO(6) transition, called E(5), and along the line of first order U(5)-SU(3) transitions, called X(5), will be presented. Experimental evidence for 'critical nuclei' will be also shown. Finally, the microscopic derivation of shape phase transitions in nuclei within the framework of density functional methods will be briefly discussed.(author)

  5. The phase diagram of ammonium nitrate

    Science.gov (United States)

    Chellappa, Raja S.; Dattelbaum, Dana M.; Velisavljevic, Nenad; Sheffield, Stephen

    2012-08-01

    The pressure-temperature (P-T) phase diagram of ammonium nitrate (AN) [NH4NO3] has been determined using synchrotron x-ray diffraction (XRD) and Raman spectroscopy measurements. Phase boundaries were established by characterizing phase transitions to the high temperature polymorphs during multiple P-T measurements using both XRD and Raman spectroscopy measurements. At room temperature, the ambient pressure orthorhombic (Pmmn) AN-IV phase was stable up to 45 GPa and no phase transitions were observed. AN-IV phase was also observed to be stable in a large P-T phase space. The phase boundaries are steep with a small phase stability regime for high temperature phases. A P-V-T equation of state based on a high temperature Birch-Murnaghan formalism was obtained by simultaneously fitting the P-V isotherms at 298, 325, 446, and 467 K, thermal expansion data at 1 bar, and volumes from P-T ramping experiments. Anomalous thermal expansion behavior of AN was observed at high pressure with a modest negative thermal expansion in the 3-11 GPa range for temperatures up to 467 K. The role of vibrational anharmonicity in this anomalous thermal expansion behavior has been established using high P-T Raman spectroscopy.

  6. Array Phase Shifters: Theory and Technology

    Science.gov (United States)

    Romanofsky, Robert R.

    2007-01-01

    While there are a myriad of applications for microwave phase shifters in instrumentation and metrology, power combining, amplifier linearization, and so on, the most prevalent use is in scanning phased-array antennas. And while this market continues to be dominated by military radar and tracking platforms, many commercial applications have emerged in the past decade or so. These new and potential applications span low-Earth-orbit (LEO) communications satellite constellations and collision warning radar, an aspect of the Intelligent Vehicle Highway System or Automated Highway System. In any case, the phase shifters represent a considerable portion of the overall antenna cost, with some estimates approaching 40 percent for receive arrays. Ferrite phase shifters continue to be the workhorse in military-phased arrays, and while there have been advances in thin film ferrite devices, the review of this device technology in the previous edition of this book is still highly relevant. This chapter will focus on three types of phase shifters that have matured in the past decade: GaAs MESFET monolithic microwave integrated circuit (MMIC), micro-electromechanical systems (MEMS), and thin film ferroelectric-based devices. A brief review of some novel devices including thin film ferrite phase shifters and superconducting switches for phase shifter applications will be provided. Finally, the effects of modulo 2 phase shift limitations, phase errors, and transient response on bit error rate degradation will be considered.

  7. Stereo 3D spatial phase diagrams

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Jinwu, E-mail: kangjw@tsinghua.edu.cn; Liu, Baicheng, E-mail: liubc@tsinghua.edu.cn

    2016-07-15

    Phase diagrams serve as the fundamental guidance in materials science and engineering. Binary P-T-X (pressure–temperature–composition) and multi-component phase diagrams are of complex spatial geometry, which brings difficulty for understanding. The authors constructed 3D stereo binary P-T-X, typical ternary and some quaternary phase diagrams. A phase diagram construction algorithm based on the calculated phase reaction data in PandaT was developed. And the 3D stereo phase diagram of Al-Cu-Mg ternary system is presented. These phase diagrams can be illustrated by wireframe, surface, solid or their mixture, isotherms and isopleths can be generated. All of these can be displayed by the three typical display ways: electronic shutter, polarization and anaglyph (for example red-cyan glasses). Especially, they can be printed out with 3D stereo effect on paper, and watched by the aid of anaglyph glasses, which makes 3D stereo book of phase diagrams come to reality. Compared with the traditional illustration way, the front of phase diagrams protrude from the screen and the back stretches far behind of the screen under 3D stereo display, the spatial structure can be clearly and immediately perceived. These 3D stereo phase diagrams are useful in teaching and research. - Highlights: • Stereo 3D phase diagram database was constructed, including binary P-T-X, ternary, some quaternary and real ternary systems. • The phase diagrams can be watched by active shutter or polarized or anaglyph glasses. • The print phase diagrams retains 3D stereo effect which can be achieved by the aid of anaglyph glasses.

  8. Phase 0 and phase III transport in various organs: combined concept of phases in xenobiotic transport and metabolism.

    Science.gov (United States)

    Döring, Barbara; Petzinger, Ernst

    2014-08-01

    The historical phasing concept of drug metabolism and elimination was introduced to comprise the two phases of metabolism: phase I metabolism for oxidations, reductions and hydrolyses, and phase II metabolism for synthesis. With this concept, biological membrane barriers obstructing the accessibility of metabolism sites in the cells for drugs were not considered. The concept of two phases was extended to a concept of four phases when drug transporters were detected that guided drugs and drug metabolites in and out of the cells. In particular, water soluble or charged drugs are virtually not able to overcome the phospholipid membrane barrier. Drug transporters belong to two main clusters of transporter families: the solute carrier (SLC) families and the ATP binding cassette (ABC) carriers. The ABC transporters comprise seven families with about 20 carriers involved in drug transport. All of them operate as pumps at the expense of ATP splitting. Embedded in the former phase concept, the term "phase III" was introduced by Ishikawa in 1992 for drug export by ABC efflux pumps. SLC comprise 52 families, from which many carriers are drug uptake transporters. Later on, this uptake process was referred to as the "phase 0 transport" of drugs. Transporters for xenobiotics in man and animal are most expressed in liver, but they are also present in extra-hepatic tissues such as in the kidney, the adrenal gland and lung. This review deals with the function of drug carriers in various organs and their impact on drug metabolism and elimination.

  9. Measurement of phase interaction in dispersed gas-particle two-phase flow by phase-doppler anemometry

    OpenAIRE

    Mergheni Ali Mohamed; Ben Ticha Hmaied; Sautet Jen-Charles; Godard Gille; Ben Nasrallah Sassi

    2008-01-01

    For simultaneous measurement of size and velocity distributions of continuous and dispersed phases in a two-phase flow a technique phase-Doppler anemometry was used. Spherical glass particles with a particle diameter range from 102 up to 212 µm were used. In this two-phase flow an experimental results are presented which indicate a significant influence of the solid particles on the flow characteristics. The height of influence of these effects depends on the local position in the jet. Near t...

  10. Phase ramping and modulation of reflectometer signals

    International Nuclear Information System (INIS)

    Conway, G.D.; Bartlett, D.V.; Stoff, P.E.

    1999-01-01

    The phase and amplitude signals of JET heterodyne reflectometers show varying levels of high frequency turbulence superimposed on a slow changing mean. The phase signal also shows multi-radian (> 1 fringe) variations with two quite different time scales (2-10 ms and sub-ms). In both cases the mean reflected power, together with turbulent phase and amplitude fluctuation levels, are modulated synchronously with the are modulated synchronously with the phase fringes. The slow fringes appear to result radial movement of the cutoff layer with the amplitude modulation possibly due to multiple reflection between plasma and wall. The fast fringes occur in intermittent bursts and appear to be phase runaway resulting from antenna misalignment. Using a 2-D physical optics simulation code it is possible to replicate the fast bursts of phase runaway from steady-state turbulence and misaligned antennas. This offers a possible alternative explanation for some of the observations of bursting turbulence seen in reflectometer signals. (authors)

  11. Two-dimensional phase fraction charts

    International Nuclear Information System (INIS)

    Morral, J.E.

    1984-01-01

    A phase fraction chart is a graphical representation of the amount of each phase present in a system as a function of temperature, composition or other variable. Examples are phase fraction versus temperature charts used to characterize specific alloys and as a teaching tool in elementary texts, and Schaeffler diagrams used to predict the amount of ferrite in stainless steel welds. Isothermal-transformation diagrams (TTT diagrams) are examples that give phase (or microconstituent) amount versus temperature and time. The purpose of this communication is to discuss the properties of two-dimensional phase fraction charts in more general terms than have been reported before. It is shown that they can represent multi-component, multiphase equilibria in a way which is easier to read and which contains more information than the isotherms and isopleths of multi-component phase diagrams

  12. Phase shifter for antenna beam steering

    Energy Technology Data Exchange (ETDEWEB)

    Jindal, Ravi, E-mail: rjindal21@gmail.com [Master’s(MS) in System Electronics and General Electrical, Ecole Polytechnique of university of Nantes France, IETR, Nantes (France); Razban, Tchanguiz, E-mail: tchanguiz.razban-haghighi@univ-nantes.fr [Electronics and Telecommunication Institute of Rennes (IETR-UMR 6164), Ecole Polytechnique of university of Nantes France, IETR, Nantes (France)

    2016-03-09

    Wide band Array Antenna operates in Ku-band (10.7-12.7 GHz) frequency composed of N×N radiating elements. This antenna aims at the reception of television satellite signals. The goal of this research is to provide better possibility of electronic beam control instead of manual or mechanical control, and design compact and low cost phase shifters to be inserted in the feeding network of this antenna. The electronic control of the phase shifter will allow the control of beam steering. The emphasis of this project will be done at the beginning on the design of a good phase shifter in Ku band. The aim of this research is to define, simulate, release and measure a continuous phase shifter. Better reflection loss, low transmission loss, low Cost of array antennas, large range of phase-shifter, phase flatness and bandwidth will be achieved by providing better gain.

  13. Weak-light phase locking for LISA

    International Nuclear Information System (INIS)

    McNamara, Paul W

    2005-01-01

    The long armlengths of the LISA interferometer, and the finite aperture of the telescope, lead to an optical power attenuation of ∼10 -10 of the transmitted to received light. Simple reflection at the end of the arm is therefore not an optimum interferometric design. Instead, a local laser is offset phase locked to the weak incoming beam, transferring the phase information of the incoming to the outgoing light. This paper reports on an experiment to characterize a weak-light phase-locking scheme suitable for LISA in which a diode-pumped, Nd:YAG, non-planar ring oscillator (NPRO) is offset phase locked to a low-power (13 pW) frequency stabilized master NPRO. Preliminary results of the relative phase noise of the slave laser shows shot noise limited performance above 0.4 Hz. Excess noise is observed at lower frequencies, most probably due to thermal effects in the optical arrangement and phase-sensing electronics

  14. Phase ramping and modulation of reflectometer signals

    International Nuclear Information System (INIS)

    Conway, G.; Bartlett, D.; Stott, P.

    1999-06-01

    The phase and amplitude signals of JET heterodyne reflectometers show varying levels of high frequency turbulence superimposed on a slow changing mean. The phase signal also shows multi-radian (>1 fringe) variations with two quite different time scales (2-10ms and sub-ms). In both cases the mean reflected power, together with turbulent phase and amplitude fluctuation levels, are modulated synchronously with the phase fringes. The slow fringes appear to result from radial movement of the cutoff layer with the amplitude modulation possibly due to multiple reflection between plasma and wall. The fast fringes occur in intermittent bursts and appear to be phase runaway resulting from antenna misalignment. Using a 2D physical optics simulation code it is possible to replicate the fast bursts of phase runaway from steady-state turbulence and misaligned antennas. This offers a possible alternative explanation for some of the observations of bursting turbulence seen in reflectometer signals. (author)

  15. Phases of Kaluza-Klein Black Holes

    DEFF Research Database (Denmark)

    Harmark, Troels; Obers, N. A.

    2005-01-01

    We review the latest progress in understanding the phase structure of static and neutral Kaluza-Klein black holes, i.e. static and neutral solutions of pure gravity with an event horizon that asymptote to a d-dimensional Minkowski-space times a circle. We start by reviewing the (mu,n) phase diagram...... and the split-up of the phase structure into solutions with an internal SO(d-1) symmetry and solutions with Kaluza-Klein bubbles. We then discuss the uniform black string, non-uniform black string and localized black hole phases, and how those three phases are connected, involving issues such as classical...... instability and horizon-topology changing transitions. Finally, we review the bubble-black hole sequences, their place in the phase structure and interesting aspects such as the continuously infinite non-uniqueness of solutions for a given mass and relative tension....

  16. Study of incommensurable phases in quantum chains

    International Nuclear Information System (INIS)

    Vollmer, J.

    1990-12-01

    The phases of quantum chains with spin-1/2 and spin-1-respresentations of the SU(2) algebra and the phases of a mixed spin-1/2 / spin-1 chain are reported and investigated. These chains are models with an XX-interaction in a magnetic field. In a certain range of the magnetic field the groundstate magnetisation depends continuously on the magnetic field and the energy gaps vanish, this is a so called 'floating phase'. Within this phase the energy spectrum is a conformal spectrum, comparable to the spectrum of the Gauss-model, but the momenta have a macroscopic part. These macroscopic momenta are connected to oscillating correlation functions, whose periods are determined by the magnetic field. The transition from the floating phase to an existing phase with constant groundstate magnetisation is a Pokrovsky-Talapov-transition, it is a universal transition in all three models. (orig.) [de

  17. Phase shifter for antenna beam steering

    International Nuclear Information System (INIS)

    Jindal, Ravi; Razban, Tchanguiz

    2016-01-01

    Wide band Array Antenna operates in Ku-band (10.7-12.7 GHz) frequency composed of N×N radiating elements. This antenna aims at the reception of television satellite signals. The goal of this research is to provide better possibility of electronic beam control instead of manual or mechanical control, and design compact and low cost phase shifters to be inserted in the feeding network of this antenna. The electronic control of the phase shifter will allow the control of beam steering. The emphasis of this project will be done at the beginning on the design of a good phase shifter in Ku band. The aim of this research is to define, simulate, release and measure a continuous phase shifter. Better reflection loss, low transmission loss, low Cost of array antennas, large range of phase-shifter, phase flatness and bandwidth will be achieved by providing better gain.

  18. Phase Noise Compensation for OFDM Systems

    Science.gov (United States)

    Leshem, Amir; Yemini, Michal

    2017-11-01

    We describe a low complexity method for time domain compensation of phase noise in OFDM systems. We extend existing methods in several respects. First we suggest using the Karhunen-Lo\\'{e}ve representation of the phase noise process to estimate the phase noise. We then derive an improved datadirected choice of basis elements for LS phase noise estimation and present its total least square counterpart problem. The proposed method helps overcome one of the major weaknesses of OFDM systems. We also generalize the time domain phase noise compensation to the multiuser MIMO context. Finally we present simulation results using both simulated and measured phased noise. We quantify the tracking performance in the presence of residual carrier offset.

  19. A wavelet phase filter for emission tomography

    International Nuclear Information System (INIS)

    Olsen, E.T.; Lin, B.

    1995-01-01

    The presence of a high level of noise is a characteristic in some tomographic imaging techniques such as positron emission tomography (PET). Wavelet methods can smooth out noise while preserving significant features of images. Mallat et al. proposed a wavelet based denoising scheme exploiting wavelet modulus maxima, but the scheme is sensitive to noise. In this study, the authors explore the properties of wavelet phase, with a focus on reconstruction of emission tomography images. Specifically, they show that the wavelet phase of regular Poisson noise under a Haar-type wavelet transform converges in distribution to a random variable uniformly distributed on [0, 2π). They then propose three wavelet-phase-based denoising schemes which exploit this property: edge tracking, local phase variance thresholding, and scale phase variation thresholding. Some numerical results are also presented. The numerical experiments indicate that wavelet phase techniques show promise for wavelet based denoising methods

  20. New applications using phased array techniques

    International Nuclear Information System (INIS)

    Erhard, A.; Schenk, G.; Hauser, Th.; Voelz, U.

    2001-01-01

    In general, the application of phased array techniques used to be limited to heavy components with large wall thicknesses, such as those in the nuclear power industry. With the improvement of the phased array equipment, including phased array search units, other application areas are now accessible for the phased array inspection technique, e.g. the inspection of turbine blade roots, weld inspection with a wall thickness ranging from 12 to 40 mm, inspection of aircraft components, inspection of spot welds and the inspection of concrete building components. The objective for the use of phased array techniques has not significantly changed since their first application, e.g. instant adjustment of the sound beam to the geometry of the test object by steering incidence angle, skew angle and/or sound field focusing. Because some new phased array technique applications are still in the experimental (laboratory) stage, this article will focus on some examples for practical, real-weld applications

  1. Operational geometric phase for mixed quantum states

    International Nuclear Information System (INIS)

    Andersson, O; Heydari, H

    2013-01-01

    The geometric phase has found a broad spectrum of applications in both classical and quantum physics, such as condensed matter and quantum computation. In this paper, we introduce an operational geometric phase for mixed quantum states, based on spectral weighted traces of holonomies, and we prove that it generalizes the standard definition of the geometric phase for mixed states, which is based on quantum interferometry. We also introduce higher order geometric phases, and prove that under a fairly weak, generically satisfied, requirement, there is always a well-defined geometric phase of some order. Our approach applies to general unitary evolutions of both non-degenerate and degenerate mixed states. Moreover, since we provide an explicit formula for the geometric phase that can be easily implemented, it is particularly well suited for computations in quantum physics. (paper)

  2. The CEBAF fiber optic phase reference system

    International Nuclear Information System (INIS)

    Crawford, K.; Simrock, S.; Hovater, C.; Krycuk, A.

    1995-01-01

    The specified phase stability of the CEBAF RF distribution system is 2.9 degree rms per linac. Stability is achieved through the use of a temperature and pressure regulated coaxial drive line. Purpose of the fiber optic phase reference system is to monitor the relative phase at the beginning and ending of this drive line, between linacs, injector and separator to determine drift due to ambient temperature fluctuations. The system utilizes an Ortel 1310 nm single mode laser driving Sumitumo optical fiber to distribute a reference signal at 1497 MHz. Phase of this reference signal is compared to the 1427 MHz (LO) and the 70 MHz (IF) via a 360 degree phase detector. The detected information is then routed to the CEBAF control system for display with a specified resolution of ±0.2 degree over a 20 degree phase delta

  3. Phase separation in an ionomer glass

    DEFF Research Database (Denmark)

    Pedersen, Malene Thostrup; Tian, K.V.; Dobó-Nagy, C.

    2015-01-01

    The G338 ionomer glass is a fluoro-alumino-silicate system, which is used as the powder component of glass ionomer cements (GICs) in dental applications. However, despite progress in understanding the nature of this glass, chemical identity of its separated amorphous phases has not yet been...... amorphous phases in G388 are Ca/Na-Al-Si-O, Ca-Al-F and Ca-P-O-F phases, respectively. However, the exact chemical compositions of the three phases still require further exploration. The results of this work are important for understanding the impact of phase separation within ionomer glasses on the setting...... conclusively determined. In this work, we identify these phases by performing differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analyses on both the as-received glass and heat-treated samples. We detected three glass transitions in the as-received G338 glass during DSC upscaning, implying...

  4. Ionospheric behaviour during storm recovery phase

    Science.gov (United States)

    Buresova, D.; Lastovicka, J.; Boska, J.; Sindelarova, T.; Chum, J.

    2012-04-01

    Intensive ionospheric research, numerous multi-instrumental observations and large-scale numerical simulations of ionospheric F region response to magnetic storm-induced disturbances during the last several decades were primarily focused on the storm main phase, in most cases covering only a few hours of the recovery phase following after storm culmination. Ionospheric behaviour during entire recovery phase still belongs to not sufficiently explored and hardly predictable features. In general, the recovery phase is characterized by an abatement of perturbations and a gradual return to the "ground state" of ionosphere. However, observations of stormy ionosphere show significant departures from the climatology also within this phase. This paper deals with the quantitative and qualitative analysis of the ionospheric behaviour during the entire recovery phase of strong-to-severe magnetic storms at middle latitudes for nowadays and future modelling and forecasting purposes.

  5. A Headspace Solid Phase Microextraction (HS-SPME method for the chromatographic determination of alkylpyrazines in cocoa samples

    Directory of Open Access Journals (Sweden)

    Pini Gláucia F.

    2004-01-01

    Full Text Available A Headspace Solid Phase Microextraction (HS-SPME procedure for isolation and determination of alkylpyrazines in cocoa liquor, using Gas Chromatography with Flame Ionization Detection (GC-FID for the separation and detection of the analytes, is presented here. The HS-SPME operational conditions were optimized using extractions of samples spiked with known amounts of alkylpyrazines typically found on cocoa products. The maximum extraction efficiency was obtained using SPME fibers coated with 65 µm Carbowax/divinylbenzene. Additionally, the best results were achieved with extraction temperature of 60 ºC, 15 min of sample/headspace equilibration time and 45 min extraction time. It was also observed that suspending the samples in saturated aqueous NaCl solution during extractions resulted in a significant increment on the peak areas. This procedure was found to be effective to determine the so-called pyrazinic ratios (quotient between peak areas of alkylpyrazines, which are useful as quality parameters for cocoa liquor.

  6. Hydrocarbon fuels from gas phase decarboxylation of hydrolyzed free fatty acid

    KAUST Repository

    Wang, Weicheng

    2012-01-01

    Gas phase decarboxylation of hydrolyzed free fatty acid (FFA) from canola oil has beeninvestigated in two fix-bed reactors by changing reaction parameters such as temperatures,FFA feed rates, and H 2-to-FFA molar ratios. FFA, which contains mostly C 18 aswell as a few C 16, C 20, C 22, and C 24 FFA, was fed into the boiling zone, evaporated, carriedby hydrogen flow at the rate of 0.5-20 ml/min, and reacted with the 5% Pd/C catalystin the reactor. Reactions were conducted atmospherically at 380-450 °C and the products,qualified and quantified through gas chromatography-flame ionization detector(GC-FID), showed mostly n-heptadecane and a few portion of n-C 15, n-C 19, n-C 21, n-C 23 as well as some cracking species. Results showed that FFA conversion increased withincreasing reaction temperatures but decreased with increasing FFA feed rates and H 2-to-FFA molar ratios. The reaction rates were found to decrease with higher temperatureand increase with higher H 2 flow rates. Highly selective heptadecane was achieved byapplying higher temperatures and higher H 2-to-FFA molar ratios. From the results, ascatalyst loading and FFA feed rate were fixed, an optimal reaction temperature of 415 °C as well as H 2-to-FFA molar ratio of 4.16 were presented. These results provided goodbasis for studying the kinetics of decarboxylation process. © 2012 American Society of Mechanical Engineers.

  7. Phase transitions of quadrupolar fluids

    International Nuclear Information System (INIS)

    OShea, S.F.; Dubey, G.S.; Rasaiah, J.C.

    1997-01-01

    Gibbs ensemble simulations are reported for Lennard-Jones particles with embedded quadrupoles of strength Q * =Q/(εσ 5 ) 1/2 =2.0 where ε and σ are the Lennard-Jones parameters. Calculations revealing the effect of the dispersive forces on the liquid endash vapor coexistence were carried out by scaling the attractive r -6 term in the Lennard-Jones pair potential by a factor λ ranging from 0 to 1. Liquid endash vapor coexistence is observed for all values of λ including λ=0 for Q * =2.0, unlike the corresponding dipolar fluid studied by van Leeuwen and Smit et al. [Phys. Rev. Lett. 71, 3991 (1993)] which showed no phase transition below λ=0.35 when the reduced dipole moment μ * =2.0. The simulation data are analyzed to estimate the critical properties of the quadrupolar fluid and their dependence on the strength λ of the dispersive force. The critical temperature and pressure show a clear quadratic dependence on λ, while the density is less confidently identified as being linear in λ. The compressibility is roughly linear in λ. copyright 1997 American Institute of Physics

  8. Quantum rewinding via phase estimation

    Science.gov (United States)

    Tabia, Gelo Noel

    2015-03-01

    In cryptography, the notion of a zero-knowledge proof was introduced by Goldwasser, Micali, and Rackoff. An interactive proof system is said to be zero-knowledge if any verifier interacting with an honest prover learns nothing beyond the validity of the statement being proven. With recent advances in quantum information technologies, it has become interesting to ask if classical zero-knowledge proof systems remain secure against adversaries with quantum computers. The standard approach to show the zero-knowledge property involves constructing a simulator for a malicious verifier that can be rewinded to a previous step when the simulation fails. In the quantum setting, the simulator can be described by a quantum circuit that takes an arbitrary quantum state as auxiliary input but rewinding becomes a nontrivial issue. Watrous proposed a quantum rewinding technique in the case where the simulation's success probability is independent of the auxiliary input. Here I present a more general quantum rewinding scheme that employs the quantum phase estimation algorithm. This work was funded by institutional research grant IUT2-1 from the Estonian Research Council and by the European Union through the European Regional Development Fund.

  9. Pure Phase Solubility Limits: LANL

    International Nuclear Information System (INIS)

    C. Stockman

    2001-01-01

    The natural and engineered system at Yucca Mountain (YM) defines the site-specific conditions under which one must determine to what extent the engineered and the natural geochemical barriers will prevent the release of radioactive material from the repository. Most important mechanisms for retention or enhancement of radionuclide transport include precipitation or co-precipitation of radionuclide-bearing solid phases (solubility limits), complexation in solution, sorption onto surfaces, colloid formation, and diffusion. There may be many scenarios that could affect the near-field environment, creating chemical conditions more aggressive than the conditions presented by the unperturbed system (such as pH changes beyond the range of 6 to 9 or significant changes in the ionic strength of infiltrated waters). For an extended period of time, the near-field water composition may be quite different and more extreme in pH, ionic strength, and CO 2 partial pressure (or carbonate concentration) than waters at some distance from the repository. Reducing conditions, high pH (up to 11), and low carbonate concentration may be present in the near-field after reaction of infiltrating groundwater with engineered barrier systems, such as cementitious materials. In the far-field, conditions are controlled by the rock-mass buffer providing a near-neutral, oxidizing, low-ionic-strength environment that controls radionuclide solubility limits and sorption capacities. There is the need for characterization of variable chemical conditions that affect solubility, speciation, and sorption reactions. Modeling of the groundwater chemistry is required and leads to an understanding of solubility and speciation of the important radionuclides. Because experimental studies cannot be performed under the numerous potential chemical conditions, solubility limitations must rely on geochemical modeling of the radionuclide's chemistry. Fundamental thermodynamic properties, such as solubility products

  10. Towards the QCD phase diagram

    CERN Document Server

    De Forcrand, Philippe; Forcrand, Philippe de; Philipsen, Owe

    2006-01-01

    We summarize our recent results on the phase diagram of QCD with N_f=2+1 quark flavors, as a function of temperature T and quark chemical potential \\mu. Using staggered fermions, lattices with temporal extent N_t=4, and the exact RHMC algorithm, we first determine the critical line in the quark mass plane (m_{u,d},m_s) where the finite temperature transition at \\mu=0 is second order. We confirm that the physical point lies on the crossover side of this line. Our data are consistent with a tricritical point at (m_{u,d},m_s) = (0,\\sim 500) MeV. Then, using an imaginary chemical potential, we determine in which direction this second-order line moves as the chemical potential is turned on. Contrary to standard expectations, we find that the region of first-order transitions shrinks in the presence of a chemical potential, which is inconsistent with the presence of a QCD critical point at small chemical potential. The emphasis is put on clarifying the translation of our results from lattice to physical units, and ...

  11. Viability of Dirac phase leptogenesis

    International Nuclear Information System (INIS)

    Anisimov, Alexey; Blanchet, Steve; Di Bari, Pasquale

    2008-01-01

    We discuss the conditions for a non-vanishing Dirac phase δ and mixing angle θ 13 , sources of CP violation in neutrino oscillations, to be uniquely responsible for the observed matter–antimatter asymmetry of the Universe through leptogenesis. We show that this scenario, that we call δ-leptogenesis, is viable when the degenerate limit for the heavy right-handed (RH) neutrino spectrum is considered. We derive an interesting joint condition on sinθ 13 and the absolute neutrino mass scale that can be tested in future neutrino oscillation experiments. In the limit of the hierarchical heavy RH neutrino spectrum, we strengthen the previous result that δ-leptogenesis is only very marginally allowed, even when the production from the two heavier RH neutrinos is taken into account. An improved experimental upper bound on sinθ 13 and/or an account of quantum kinetic effects could completely rule out this option in the future. Therefore, δ-leptogenesis can be also regarded as motivation for models with degenerate heavy neutrino spectrum

  12. SYNCHEM feasibility report: Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    1995-01-01

    Several Czech and US companies have entered into a development agreement for the purposes of determining the technical and economic feasibility and overall financeability of an integrated gasification combined cycle (IGCC) regional energy facility to be located adjacent to the Chemopetrol refinery in Litvinov, Czech Republic. The Project would use a feedstock comprised of coal supplied by Doly a upravny Komorany s.p. (DUK) coal mining company and mined from the Most/Litvinov area together with high sulfur residual oils from the Chemopetrol refinery. When gasified together with oxygen from an Air Products air separation plant, and based on an average yearly consumption of 2,100K metric tons per year of coal (as delivered) and 630K tonnes per year of oil, approximately 11 million normal cubic meters per day of syngas will be produced. At its current projected design capacity, when combusted in two General Electric advanced technology Frame 9FA gas turbines, the Project will produce approximately 690MW of electric power; 250 metric tons/hour of steam for process; and 135 thermal equivalent MW of district heat. The Feasibility Phase efforts described in this report indicate the real possibility for a successful and profitable IGCC Project for the Czech Republic. It is therefore incumbent upon all the Project Participants to review and evaluate the information contained herein such that a go/no-go decision can be reached by early next year.

  13. Cloud regimes as phase transitions

    Science.gov (United States)

    Stechmann, Samuel; Hottovy, Scott

    2017-11-01

    Clouds are repeatedly identified as a leading source of uncertainty in future climate predictions. Of particular importance are stratocumulus clouds, which can appear as either (i) closed cells that reflect solar radiation back to space or (ii) open cells that allow solar radiation to reach the Earth's surface. Here we show that these clouds regimes - open versus closed cells - fit the paradigm of a phase transition. In addition, this paradigm characterizes pockets of open cells (POCs) as the interface between the open- and closed-cell regimes, and it identifies shallow cumulus clouds as a regime of higher variability. This behavior can be understood using an idealized model for the dynamics of atmospheric water as a stochastic diffusion process. Similar viewpoints of deep convection and self-organized criticality will also be discussed. With these new conceptual viewpoints, ideas from statistical mechanics could potentially be used for understanding uncertainties related to clouds in the climate system and climate predictions. The research of S.N.S. is partially supported by a Sloan Research Fellowship, ONR Young Investigator Award N00014-12-1-0744, and ONR MURI Grant N00014-12-1-0912.

  14. Executive summary of phase 2

    International Nuclear Information System (INIS)

    1989-02-01

    The second phase of the Stripa project included the continued development of methods and techniques for repository site investigations. The crosshole investigations demonstrated that it is possible to characterize fractures in crystralline rock with a reliability and realism not obtained before. At the investigated site at Stripa, it was shown that groundwater flow is concentrated within a few major fractures that were idenfified by geophysical methods. The work at Stripa has shown that it is possible to collect and analyze data that enable one to determine the type of distribution and its parameters for each of the essential geometrical and hydraulic properties of the fracture system, and hence compare one site with another as part of experience builing in safety assessment studies. The migration experiment demonstrated that the groundwater flow could be very unevenly distributed in the rock. The hydrogeochemical investigations at Stripa also indicated that a new type of solute source must be considered - fluid inclusions in the host rock. The age of the solutes may be entirely different from the age of the groundwater. Sealing and redirection of the groundwater flow away from man made openings in the rock was tested at Stripa and found to be feasible as shown in the various plugging and sealing experiments. The use of Na bentonite in the form of suitably shaped blocks of highly compacted powder has been found to be very practical for sealing off boreholes, shafts and tunnels in repositories

  15. Pure Phase Solubility Limits: LANL

    Energy Technology Data Exchange (ETDEWEB)

    C. Stockman

    2001-01-26

    The natural and engineered system at Yucca Mountain (YM) defines the site-specific conditions under which one must determine to what extent the engineered and the natural geochemical barriers will prevent the release of radioactive material from the repository. Most important mechanisms for retention or enhancement of radionuclide transport include precipitation or co-precipitation of radionuclide-bearing solid phases (solubility limits), complexation in solution, sorption onto surfaces, colloid formation, and diffusion. There may be many scenarios that could affect the near-field environment, creating chemical conditions more aggressive than the conditions presented by the unperturbed system (such as pH changes beyond the range of 6 to 9 or significant changes in the ionic strength of infiltrated waters). For an extended period of time, the near-field water composition may be quite different and more extreme in pH, ionic strength, and CO{sub 2} partial pressure (or carbonate concentration) than waters at some distance from the repository. Reducing conditions, high pH (up to 11), and low carbonate concentration may be present in the near-field after reaction of infiltrating groundwater with engineered barrier systems, such as cementitious materials. In the far-field, conditions are controlled by the rock-mass buffer providing a near-neutral, oxidizing, low-ionic-strength environment that controls radionuclide solubility limits and sorption capacities. There is the need for characterization of variable chemical conditions that affect solubility, speciation, and sorption reactions. Modeling of the groundwater chemistry is required and leads to an understanding of solubility and speciation of the important radionuclides. Because experimental studies cannot be performed under the numerous potential chemical conditions, solubility limitations must rely on geochemical modeling of the radionuclide's chemistry. Fundamental thermodynamic properties, such as solubility

  16. Iodine removal from a gas phase

    International Nuclear Information System (INIS)

    Vikis, A. Ch.

    1982-01-01

    Iodine, e.g. radioactive iodine, present as one or more organic iodides, optionally with elemental iodine, in a gas phase (e.g. air) are removed by photochemically decomposing the organic iodides to elemental iodine, reacting the iodine produced, and any initially present with excess ozone, preferably photochemically produced in situ in the gas phase to produce solid iodine oxides, and removing the solid oxides from the gas phase. (author)

  17. Iodine removal from a gas phase

    International Nuclear Information System (INIS)

    Vikis, A.C.

    1984-01-01

    Iodine, e.g. radioactive iodine, present as one or more organic iodides, optionally with elemental iodine, in a gas phase (e.g. air) are removed by photochemically decomposing the organic iodides to elemental iodine, reacting the iodine produced, and any initially present with excess ozone, preferably photochemically produced in situ in the gas phase to produce solid iodine oxides, and removing the solid oxides from the gas phase

  18. Sample Exchange Evaluation (SEE) Report - Phase II

    Energy Technology Data Exchange (ETDEWEB)

    Winters, W.I.

    1994-09-28

    This report describes the results from Phase II of the Sample Exchange Evaluation (SEE) Program, a joint effort to compare analytical laboratory performance on samples from the Hanford Site`s high-level waste tanks. In Phase II, the program has been expanded to include inorganic constituents in addition to radionuclides. Results from Phase II that exceeded 20% relative percent difference criteria are identified.

  19. Military Family Coping Project - Phase II

    Science.gov (United States)

    2015-05-01

    Anxiety, Life Satisfaction , Addiction, Trauma 4 The Military Family Coping Project reflects two phases. The first consisted of a series of focus...need for and guided the work of the Military Family Coping Project Phase II funded by TATRC. The Military Family Coping Project Phase II was...solidarity. For the purposes of family functioning analyses, married and unmarried soldiers were analyzed separately because marital status affects

  20. A strictly hyperbolic equilibrium phase transition model

    International Nuclear Information System (INIS)

    Allaire, G; Faccanoni, G; Kokh, S.

    2007-01-01

    This Note is concerned with the strict hyperbolicity of the compressible Euler equations equipped with an equation of state that describes the thermodynamical equilibrium between the liquid phase and the vapor phase of a fluid. The proof is valid for a very wide class of fluids. The argument only relies on smoothness assumptions and on the classical thermodynamical stability assumptions, that requires a definite negative Hessian matrix for each phase entropy as a function of the specific volume and internal energy. (authors)